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Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj  

E-Print Network [OSTI]

-butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

Al-Arfaj, Muhammad A.

2

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

3

Ethers have good gasoline-blending attributes  

SciTech Connect (OSTI)

Because of their compatibility with hydrocarbon gasoline-blending components, their high octane blending values, and their low volatility blending values, ethers will grow in use as gasoline blending components. This article discusses the properties of ethers as blending components, and environmental questions.

Unzelman, G.H.

1989-04-10T23:59:59.000Z

4

The Effect of the Di-Tertiary Butyl Peroxide (DTBP) additive on HCCI Combustion of Fuel Blends of Ethanol and Diethyl Ether  

E-Print Network [OSTI]

Ignition Using Isooctane, Ethanol and Natural Gas - AModel for High Temperature Ethanol Oxidation," Internationalof Bio-Derived Carbon from Ethanol-in-Diesel Blends in the

Mack, John Hunter; Buchholz, Bruce A; Flowers, Daniel L; Dibble, Robert W

2005-01-01T23:59:59.000Z

5

Atmospheric chemistry of diethyl ether and ethyl tert-butyl ether  

SciTech Connect (OSTI)

The mechanisms for the Cl-initiated and OH-initiated atmospheric oxidation of diethyl ether and ethyl tert-butyl ether (ETBE) have been determined. For diethyl ether the products are ethyl formate and formaldehyde and its atmospheric oxidation can be represented by C{sub 2}H{sub 5}OC{sub 2}H{sub 5} + OH + 2NO {yields} C{sub 2}H{sub 5}OC(O)H + HCHO + 2NO{sub 2} + HO{sub 2}. The mechanism for the atmospheric oxidation of ETBE is more complex, with 80% of the reaction being accounted for in terms of tert-butyl formate and formaldehyde. The remaining 20% the authors ascribe to 2-ethoxy-2-methylpropanal. The atmospheric oxidation of ETBE can be represented by ETBE + OH + 1.8NO {yields} 0.8HCOOC(CH{sub 3}){sub 3} + 0.2C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + HO{sub 2} + 0.8HCHO + 1.8NO{sub 2}. THe subsequent atmospheric chemistry of 2-ethoxy-2-methylpropanal the authors estimate to be represented by C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + OH + 3NO {yields} CO{sub 2} + H{sub 2}CO + C{sub 2}H{sub 5}OC(O)CH{sub 3} + HO{sub 2} + 3NO{sub 2}. These results are discussed in terms of the reactivity of these compounds in urban atmospheres.

Wallington, T.J.; Japar, S.M. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

6

Separation of methyl t-butyl ether from close boiling C[sub 5] hydrocarbons by extractive distillation  

SciTech Connect (OSTI)

A method for recovering methyl t-butyl ether from a mixture of methyl t-butyl ether and 1-pentene which comprises distilling a mixture of methyl t-butyl ether and 1-pentene in the presence of about one part of an extractive agent per part of methyl t-butyl ether -- 1-pentene mixture, recovering the 1-pentene as overhead product and obtaining the methyl t-butyl ether and the extractive agent from the still pot, wherein said extractive agent consists of one material selected from the group consisting of sulfolane, nitroethane, t-butanol, ethylene glycol diacetate, 1-methoxy-2-propanol acetate, methyl isoamyl ketone, ethylene glycol methyl ether, propylene glycol phenyl ether and diethyl malonate.

Berg, L.

1993-07-20T23:59:59.000Z

7

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network [OSTI]

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

8

Properties Investigation of Sulfonated Poly(ether ether ketone)/Polyacrylonitrile Acid–Base Blend Membrane for Vanadium Redox Flow Battery Application  

Science Journals Connector (OSTI)

Acid–base blend membrane prepared from sulfonated poly(ether ether ketone) (SPEEK) and polyacrylonitrile (PAN) was detailedly evaluated for vanadium redox flow battery (VRFB) application. SPEEK/PAN blend membrane exhibited dense and homogeneous cross-...

Zhaohua Li; Wenjing Dai; Lihong Yu; Le Liu; Jingyu Xi; Xinping Qiu; Liquan Chen

2014-10-15T23:59:59.000Z

9

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network [OSTI]

Sato, and N. Kato. 2003. Propane monooxygenase and NAD + -alcohol dehydrogenase in propane metabolism by Gordonia sp.tert-butyl ether by propane-grown Mycobacterium vaccae JOB5.

2007-01-01T23:59:59.000Z

10

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity  

Science Journals Connector (OSTI)

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity ... However, smaller internal rates inside the column that result from lower reboiler and condenser duty could increase the potential risk of flooding in the column and reduce the availability of reactants in the reactive section. ... Column simulations performed using both Pro/II and SpeedUp showed excellent agreement with previously published exptl. ...

Budi H. Bisowarno; Moses O. Tadé

2000-05-09T23:59:59.000Z

11

Detection and Quantification of Methyl tert-Butyl Ether-Degrading Strain PM1 by Real-Time TaqMan PCR  

Science Journals Connector (OSTI)

...purification Fresh Water microbiology Geologic...Polymerase metabolism Water Pollution, Chemical...bioremediation detection ethers ground water hydrocarbons methyl tert-butyl...pollutants pollution remediation sampling water resources...

Krassimira R. Hristova; Christian M. Lutenegger; Kate M. Scow

2001-11-01T23:59:59.000Z

12

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network [OSTI]

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

13

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network [OSTI]

because of its low cost and blending characteristics. Depending on the season, reformulated gasoline of reactor per hour, a value comparable to other gasoline constituents. Such high performance could enhancer in gasoline. The use of MTBE increased rapidly after the 1990 Clean Air Act Amendments required

14

Effect of use of low oxygenate gasoline blends upon emissions from California vehicles. Final report  

SciTech Connect (OSTI)

The objective of this project was to investigate the emissions effects of low-oxygenate gasoline blends on exhaust and evaporative emissions from a test fleet of California certified light-duty autos. Thirteen vehicles were procured and tested using four gasoline-oxygenate blends over three test cycles. The four gasoline blends were: Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and 'match' and 'splash' blends of ethanol (in the 'match' blend the fuel Reid Vapor Pressure (RVP) is held constant, while in the 'splash' blend the fuel RVP is allowed to increase). Hydrocarbon and carbon monoxide exhaust emissions were generally reduced for the oxygenated blends, the exception being the 'splash-blended' ethanol gasoline which showed mixed results. Older technology vehicles (e.g., non-catalyst and oxidation catalyst) showed the greatest emissions reductions regardless of gasoline blend, while later technology vehicles showed the smallest reductions. Evaporative emissions and toxics were generally reduced for ETBE, while results for the other blends were mixed.

Born, G.L.; Lucas, S.V.; Scott, R.D.; DeFries, T.H.; Kishan, S.

1994-02-01T23:59:59.000Z

15

Performance and Emissions of a Compression-Ignition Engine Fueled with Dimethyl Ether and Rapeseed Oil Blends  

Science Journals Connector (OSTI)

Sorenson and Mikkelsen2 had studied DME in a modified diesel engine, and their results showed that the engine could achieve ultralow-emission prospects without a fundamental change in combustion systems. ... Meanwhile, these parameters are compared with those of pure diesel fuel in order to clarify the effect of blends on the combustion and emission of engines (a CI engine cannot run for much longer of a period with pure DME fuel, so a comparison is only made with pure diesel fuel). ... Moreover, owing to the lower calorific value of the blend compared to diesel fuel, the fuel supply amount per cycle for blend operation is enlarged by increasing the plunger stroke of the fuel pump in order to make the power and torque output of the blends approach those of the corresponding diesel engine. ...

Wang Ying; Zhou Longbao

2007-04-20T23:59:59.000Z

16

Experimental investigation on thermal barrier coated diesel engine fueled with diesel-biodiesel-ethanol-diethyl ether blends  

Science Journals Connector (OSTI)

In the present work diesel-biodiesel-ethanol (DBE) and diesel-biodiesel-diethyl ether (DBD) fuels are tested with normal diesel engine and the diesel engine coated with the layers of aluminum oxide (Al 2O3) of 0.3?mm and yttria-stabilized zirconia of 0.2?mm. The various performance and emission parameters are analyzed and determined. The experimental work was carried out in a single cylinder water cooled engine coupled with eddy current dynamometer. The AVL make five gas analyzer and smoke meter were used to measure the different exhaust pollutants. The result shows that the brake thermal efficiency of coated engine is more than that of base diesel at high loads. The thermal barrier coated engine using fuel as diesel biodiesel and ethanol (TDBE) produces the lowest carbon monoxide (CO) emissions among all the fuels that are selected. In addition it produces the lowest carbon dioxide (CO2) at higher loads. Both the thermal barrier coated engine using fuel as diesel biodiesel and diethyl ether (TDBD) and TDBE have higher NOx emissions among almost all the fuels used. The TDBE and TDBD have higher smoke emissions at initial loads but eventually show lower smoke emissions at higher loads. The thermal barrier coated diesel engine fueled with DBE and DBD shows an increase in engine power and specific fuel consumption as well as significant improvements in exhaust gas emissions except NOx.

2013-01-01T23:59:59.000Z

17

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

18

Use of ethers as high-octane components of gasolines  

SciTech Connect (OSTI)

This article reports on a study of the possible utilization of methyl tert-amyl ether (MTAE) as an automotive gasoline component, both by itself and in combination with methyl tert-butyl ether (MTBE). The naphtha used in these studies consisted of 80% reformer naphtha produced under severe conditions and 20% straight-run IBP-62/sup 0/C cut. The physicochemical properties of the MTAE, the MTBE, and the naphtha base stock are given. It is determined that MTAE, which has a slightly poorer knock resistance than MTBE, is fully equal to MTBE in all other respects and can be used as an automotive gasoline component; that a gasoline blend prepared from 89% naphtha base stock, 5.5% MTAE, and 5.5% MTBE meets all of the requirements of the standard GOST 2084-77 for Grade AI-93 gasoline; and that the use of MTAE offers a means for expanding the resources of high-octane components, lowering the toxicity of the gasolines and the exhaust gas (in comparison with organometallic antiknock agents), and bringing non-petroleum raw materials into the fuel production picture.

Gureev, A.A.; Baranova, G.N.; Korotkov, I.V.; Levinson, G.I.

1984-01-01T23:59:59.000Z

19

Ditertiary butyl peroxide recovery  

SciTech Connect (OSTI)

A process is described wherein a feed material comprising significant amounts of tertiary butyl hydroperoxide and tertiary butyl alcohol and minor amounts of ditertiary butyl peroxide and other impurities is charged to a reactor together with propylene and a soluble epoxidation catalyst. At least a portion of the tertiary butyl hydroperoxide is reacted in the reactor with the propylene to form a reaction product composed of unreacted feed components, propylene oxide, an additional quantity of tertiary butyl alcohol, and impurities, including a minor amount of ditertiary butyl peroxide. The improvement for recovering substantially pure ditertiary butyl peroxide from the reaction product after the reaction product is discharged from the reactor comprises the steps of: charging the reaction product to a first distillation zone and separating therein a first unreacted propylene distillate recycle fraction, charging the remaining heavier components of the reaction product from the first distillation zone to a second distillation zone and separating a second propylene oxide distillate product fraction therein charging the heavier components from the second distillation zone to a third distillation zone and separating a third distillate fraction comprising a major amount of tertiary butyl alcohol and a minor amount of ditertiary butyl peroxide, and recovering the second propylene oxide distillate fraction, the heavier tertiary butyl alcohol product fraction and the ditertiary butyl peroxide raffinate fraction.

Sanderson, J.R.; Meyer, R.A.; Smith, W.A.; Marquis, E.T.

1989-03-07T23:59:59.000Z

20

Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers  

Science Journals Connector (OSTI)

Vapour pressures of methyl propyl, isopropyl methyl, butyl methyl, ethyl propyl, t-butyl methyl, dipropyl, di-isopropyl, di-t-butyl, and decyl methyl ethers were measured at pressures up to 205 kPa. The measured values were fitted by Antoine and by Chebyshev equations, values already published from this laboratory for three aromatic ethers were recomputed uniformly with the present results, and published values for four additional compounds were incorporated in a scheme for correlation of the vapour pressures of ethers. Estimates were made of the vapour pressures of 10 other ethers. Between 5 and 200 kPa the vapour pressures of ethers may be represented by a single equation in which carbon number or an effective carbon number is a parameter. Chebyshev equations are given for interpolation between the upper bounds of the measurements and the critical pressures of 11 ethers for which this property has been previously determined.

D Ambrose; J.H Ellender; C.H.S Sprake; R Townsend

1976-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Thermogravimetric analysis and differential scanning calorimetric studies on nanoclay-filled TPU/PP blends  

Science Journals Connector (OSTI)

Thermal stability of ester-thermoplastic polyurethane (TPU)/polypropylene (PP) and ether-TPU/PP blends was evaluated by thermogravimetric studies. Thermal studies were made as a function of blend ratio. Effect...

Murugasamy Kannan; S. S. Bhagawan…

2013-06-01T23:59:59.000Z

22

Production of methyl tert-alkyl ethers  

SciTech Connect (OSTI)

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

23

Numerical study of the effect of oxygenated blending compounds on soot formation in shock tubes  

SciTech Connect (OSTI)

This numerical study deals with the influence of blends on the amount of soot formed in shock tubes, which were simulated by assuming a homogeneous plug flow reactor model. For this purpose, first, the reaction model used here was validated against experimental results previously obtained in the literature. Then, the soot volume fractions of various mixtures of methyl tert-butyl ether (MTBE)-benzene, isobutene-benzene, methanol-benzene, and ethanol-benzene diluted in argon were simulated and compared to the results of benzene-argon pyrolysis at 1721 K and 5.4 MPa. For MTBE, isobutene, methanol, and ethanol, small amounts of additives to benzene-argon mixtures promoted soot formation, for the shock tube model assumed, while higher concentrations of these additives led to smaller soot volume fractions in comparison to pure benzene-argon pyrolysis. The most significant soot promotion effect was found for the additives MTBE and isobutene. The channel for MTBE decomposition producing isobutene and methanol is very effective at temperatures beyond 1200 K. Thus, both MTBE-benzene and isobutene-benzene mixtures diluted in argon showed rather similar behavior in regard to soot formation. Special emphasis was directed toward the causes for the concentration-dependent influence of the blends on the amount of soot formed. Aromatic hydrocarbons and acetylene were identified as key gas-phase species that determine the trends in the formation of soot of various mixtures. From reaction flux analysis for phenanthrene, it was deduced that the combinative routes including phenyl species play a major role in forming PAHs, especially at early reaction times. It is found that the additives play an important role in providing material to grow side chains, such as by reaction channels including phenylacetylene or benzyl, which are confirmed to form aromatic hydrocarbons and thus to influence the amount of soot formed, particularly when the concentrations of the blends are increased. (author)

Boehm, H. [Physikalische Chemie I, Universitaet Bielefeld (Germany); Braun-Unkhoff, M. [Deutsches Zentrum fuer Luft- und Raumfahrt e.V., Stuttgart (Germany)

2008-04-15T23:59:59.000Z

24

E-Print Network 3.0 - alkyl-tert alkyl ethers Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: of ProtonatedAlkyl tert-ButylEthers RO(H)C(CH&+ (To.6 Values in meV...

25

Reaction Pathways and Energetics of Etheric C?O Bond Cleavage Catalyzed by Lanthanide Triflates  

SciTech Connect (OSTI)

Efficient and selective cleavage of etheric C?O bonds is crucial for converting biomass into platform chemicals and liquid transportation fuels. In this contribution, computational methods at the DFT B3LYP level of theory are employed to understand the efficacy of lanthanide triflate catalysts (Ln(OTf)3, Ln = La, Ce, Sm, Gd, Yb, and Lu) in cleaving etheric C?O bonds. In agreement with experiment, the calculations indicate that the reaction pathway for C?O cleavage occurs via a C?H ? O?H proton transfer in concert with weakening of the C?O bond of the coordinated ether substrate to ultimately yield a coordinated alkenol. The activation energy for this process falls as the lanthanide ionic radius decreases, reflecting enhanced metal ion electrophilicity. Details of the reaction mechanism for Yb(OTf)3-catalyzed ring opening are explored in depth, and for 1-methyl-d3-butyl phenyl ether, the computed primary kinetic isotope effect of 2.4 is in excellent agreement with experiment (2.7), confirming that etheric ring-opening pathway involves proton transfer from the methyl group alpha to the etheric oxygen atom, which is activated by the electrophilic lanthanide ion. Calculations of the catalytic pathway using eight different ether substrates indicate that the more rapid cleavage of acyclic versus cyclic ethers is largely due to entropic effects, with the former C?O bond scission processes increasing the degrees of freedom/particles as the transition state is approached.

Assary, Rajeev S.; Atesin, Abdurrahman C.; Li, Zhi; Curtiss, Larry A.; Marks, Tobin J.

2013-07-15T23:59:59.000Z

26

Propenyl ether monomers for photopolymerization  

DOE Patents [OSTI]

Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of the above formula together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Crivello, J.V.

1996-10-22T23:59:59.000Z

27

The influence of propylene glycol ethers on base diesel properties and emissions from a diesel engine  

Science Journals Connector (OSTI)

Abstract The oxygenated additives propylene glycol methyl ether (PGME), propylene glycol ethyl ether (PGEE), dipropylene glycol methyl ether (DPGME) were studied to determine their influence on both the base diesel fuel properties and the exhaust emissions from a diesel engine (CO, NOx, unburnt hydrocarbons and smoke). For diesel blends with low oxygen content (?4.0 wt.%), the addition of these compounds to base diesel fuel decreases aromatic content, kinematic viscosity, cold filter plugging point and Conradson carbon residue. Also, each compound modifies the distillation curve at temperatures below the corresponding oxygenated compound boiling point, the distillate percentage being increased. The blend cetane number depends on the type of propylene glycol ether added, its molecular weight, and the oxygen content of the fuel. The addition of PGME decreased slightly diesel fuel cetane number, while PGEE and DPGME increased it. Base diesel fuel-propylene glycol ether blends with 1.0 and 2.5 wt.% oxygen contents were used in order to determine the performance of the diesel engine and its emissions at both full and medium loads and different engine speeds (1000, 2500 and 4000 rpm). In general, at full load and in comparison with base diesel fuel, the blends show a slight reduction of oxygen-free specific fuel consumption. CO emissions are reduced appreciably for 2.5 wt.% of oxygen blends, mainly for PGEE and DPGME. \\{NOx\\} emissions are reduced slightly, but not the smoke. Unburnt hydrocarbon emissions decrease at 1000 and 2500 rpm, but not at 4000 rpm. At medium load, the effect of the additives is much less significant, due to the fact that the ratio oxygen from additive/oxygen from air is much lower.

F. Gómez-Cuenca; M. Gómez-Marín; M.B. Folgueras-Díaz

2013-01-01T23:59:59.000Z

28

Use of superconductor type catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide  

SciTech Connect (OSTI)

In a method wherein a solution of a tertiary butyl hydroperoxide charge stock in tertiary butyl alcohol is brought into contact with a catalytically effective amount of a hydroperoxide decomposition catalyst in a hydroperoxide decomposition reaction zone in liquid phase with agitation to convert said tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol, the improvement is described which comprises: (a) using a superconductor as said hydroperoxide decomposition catalyst, and (b) recovering tertiary butyl alcohol from the products of said hydroperoxide decomposition reaction.

Sanderson, J.R.; Stockton, M.E.

1993-08-17T23:59:59.000Z

29

Process for producing high purity isoolefins and dimers thereof by dissociation of ethers  

DOE Patents [OSTI]

Alkyl tertiary butyl ether or alkyl tertiary amyl ether is dissociated by vapor phase contact with a cation acidic exchange resin at temperatures in the range of 150 to 250 F at LHSV of 0.1 to 20 to produce a stream consisting of unreacted ether, isobutene or isoamylene and an alcohol corresponding to the alkyl radical. After the alcohol is removed, the ether/isoolefin stream may be fractionated to obtain a high purity isoolefin (99+%) or the ether/isoolefin stream can be contacted in liquid phase with a cation acidic exchange resin to selectively dimerize the isoolefin in a highly exothermic reaction, followed by fractionation of the dimerization product to produce high purity diisoolefin (97+%). In the case where the alkyl is C[sub 3] to C[sub 6] and the corresponding alcohol is produced on dissociation of the ether, combined dissociation-distillation may be carried out such that isoolefin is the overhead product and alcohol the bottom. 2 figs.

Smith, L.A. Jr.; Jones, E.M. Jr.; Hearn, D.

1984-05-08T23:59:59.000Z

30

Truck loading rack blending  

SciTech Connect (OSTI)

Blending, the combining of two or more components to make a single product, has become widely used in most loading rack applications. Blending should not be confused with additive injection, which is the injection of very small doses of enhancers, detergents and dyes into a product stream. Changes in the environmental protection laws in the early 90`s have put increasing demands on marketing terminals with regards to reformulated fuels and environmental protection concerns. As a result of these new mandates, terminals have turned to blending at the loading rack as an economical and convenient means in meeting these new requirements. This paper will discuss some of these mandates and how loading rack blending is used for different applications. Various types of blending will also be discussed along with considerations for each method.

Boubenider, E. [Daniel Flow Products, Inc., Houston, TX (United States)

1995-12-01T23:59:59.000Z

31

Accelerated aging of EPDM and butyl elastomers  

SciTech Connect (OSTI)

This study was composed of three parts: a post cure study to optimize final properties of an ethylene-propylene-diene (EPDM) formulation, an accelerated aging study to compare the stress relaxation behavior of a butyl and an EPDM elastomer under compression, and a cursory evaluation of a new 70 Shore A EPDM. The optimum postcure for the EPDM was found to be 2 to 4 hours at 182{degrees}C in a vacuum. The EPDM was also shown to have superior aging characteristics compared to the butyl and is recommended for use instead of the butyl material. The physical properties for new 70 Shore A EPDM are satisfactory, and the stress relaxation behavior was only slightly inferior to the other EPDM.

Wilson, M.H.

1996-06-01T23:59:59.000Z

32

Sandia National Laboratories: blending feedstock varieties  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

blending feedstock varieties Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks On February 26, 2013, in Biofuels,...

33

E-Print Network 3.0 - alkyl tert-butyl ether Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: .S.Patent 5,091,590,1992. 0 1995American Chemical Society...

34

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network [OSTI]

Tank (LUFT) remediation programme. A recent USGS study has estimated that as many as 9000 community, remediation actions are implemented at costs usually 10± 30% higher than those at sites without MTBE contamina- tion. The evaluation of innovative and cost-effective treatment such as bioremediation for MTBE spills

35

Biodegradation of Methyl tert-Butyl Ether by a Pure Bacterial Culture  

Science Journals Connector (OSTI)

...identify cost-effective remediation technologies. Relatively...treated with ENV735 as a remediation biocatalyst, but the strain...through the Small Business Innovative Research program (grant...situ bioaugmentation for remediation of chlorinated solvents in...

Paul B. Hatzinger; Kevin McClay; Simon Vainberg; Marina Tugusheva; Charles W. Condee; Robert J. Steffan

2001-12-01T23:59:59.000Z

36

Treatment of Methyl tert-Butyl Ether Contaminated Water Using a Dense  

E-Print Network [OSTI]

discharge of organic compounds require that new, innovative tech- nologies and methods of remediation dioxide, making the DMP reactor a promising tool in the future remediation of water. Chemical and physical is transformed into a more toxic material or a substance that is more difficult to remediate, the treatment

Dandy, David

37

Alternative Fuels Data Center: Biodiesel Blends  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blends to Blends to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blends on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blends on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blends on Google Bookmark Alternative Fuels Data Center: Biodiesel Blends on Delicious Rank Alternative Fuels Data Center: Biodiesel Blends on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blends on AddThis.com... More in this section... Biodiesel Basics Blends Production & Distribution Specifications Related Links Benefits & Considerations Stations Vehicles Laws & Incentives Biodiesel Blends Biodiesel can be blended and used in many different concentrations, including B100 (pure biodiesel), B20 (20% biodiesel, 80% petroleum diesel),

38

High octane ethers from synthesis gas-derived alcohols. Final technical report, September 25, 1990--December 24, 1993  

SciTech Connect (OSTI)

The objective of the research was to develop the methodology for the catalytic synthesis of ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from alcohol mixtures that are rich in methanol and 2-methyl-1-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been previously demonstrated by us to occur over superacid catalysts to yield MIBE and smaller amounts of MTBE at moderate pressures and a mixture of methanol and isobutene at low pressures. A wide range of organic resin catalysts and inorganic oxide and zeolite catalysts have been investigated for activity and selectivity in directly coupling alcohols, principally methanol and isobutanol, to form ethers and in the dehydration of isobutanol to isobutene in the presence of methanol. All of these catalysts are strong acids, and it was found that the organic and inorganic catalysts operate in different, but overlapping, temperature ranges, i.e. mainly 60--120{degrees}C for the organic resins and 90--175{degrees}C for the inorganic catalysts. For both types of catalysts, the presence of strong acid centers is required for catalytic activity, as was demonstrated by lack of activity of fully K{sup +} ion exchanged Nafion resin and zirconia prior to being sulfated by treatment with sulfuric acid.

Klier, K.; Herman, R.G.

1994-05-01T23:59:59.000Z

39

Ethanol-blended Fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ethanol-Blended Ethanol-Blended Fuels A Study Guide and Overview of: * Ethanol's History in the U.S. and Worldwide * Ethanol Science and Technology * Engine Performance * Environmental Effects * Economics and Energy Security The Curriculum This curriculum on ethanol and its use as a fuel was developed by the Clean Fuels Development Coalition in cooperation with the Nebraska Ethanol Board. This material was developed in response to the need for instructional materials on ethanol and its effects on vehicle performance, the environment, and the economy. As a renewable alternative energy source made from grain and other biomass resources, ethanol study serves as an excellent learning opportunity for students to use in issue clarification and problem-solving activities. Ethanol illustrates that science and technology can provide us with new

40

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network [OSTI]

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Mid-Level Ethanol Blends  

Energy Savers [EERE]

Mid-Level Ethanol Blends Test Program DOE, NREL, and ORNL Team Presented by Keith Knoll Work supported by DOEEERE Vehicle Technologies Program Annual Merit Review and Peer...

42

Near-Infrared Electrochromism in Electroactive Pentacenediquinone-Containing Poly(aryl ether)s  

E-Print Network [OSTI]

Near-Infrared Electrochromism in Electroactive Pentacenediquinone-Containing Poly(aryl etherVed October 21, 2005 The synthesis and near-infrared electrochromic properties of pentacenediquinone-infrared electrochromic properties of pentacenediquinone-containing poly(aryl ether)s were studied

Wan, Xin-hua

43

Kinetics of liquid phase catalytic dehydration of methanol to dimethyl ether  

SciTech Connect (OSTI)

This paper reports the kinetics of the liquid phase catalytic dehydration of methanol to dimethyl ether investigated. The experiments were carried out under low concentrations of feed in a 1-L stirred autoclave, according to a statistical experimental design. The inert liquid phase used for this investigation was a 78:22 blend of paraffinic and naphthenic mineral oils. A complete thermodynamic analysis was carried out in order to determine the liquid phase concentrations of the dissolved species. A global kinetic model was developed for the rate of dimethyl ether synthesis in terms of the liquid phase concentration of methanol. The activation energy of the reaction was found to be 18,830 cal/gmol. Based on a step-wise linear regression analysis of the kinetic data, the order of the reaction which gave the best fit was 0.28 with respect to methanol.

Gogate, M.R.; Lee, B.G.; Lee, S. (Akron Univ., OH (USA). Dept. of Chemical Engineering); Kulik, C.J. (Electric Power Research Inst., Palo Alto, CA (USA))

1990-01-01T23:59:59.000Z

44

Alternative Fuels Data Center: Ethanol Blends  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blends to Blends to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blends on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blends on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blends on Google Bookmark Alternative Fuels Data Center: Ethanol Blends on Delicious Rank Alternative Fuels Data Center: Ethanol Blends on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blends on AddThis.com... More in this section... Ethanol Basics Blends E15 E85 Specifications Production & Distribution Feedstocks Related Links Benefits & Considerations Stations Vehicles Laws & Incentives Ethanol Blends Ethanol is blended with gasoline in various amounts for use in vehicles. E10 E10 is a low-level blend composed of 10% ethanol and 90% gasoline. It is

45

E-Print Network 3.0 - ammoniated glycyrrhizin butylated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ammoniated glycyrrhizin butylated Search Powered by Explorit Topic List Advanced Search Sample search results for: ammoniated glycyrrhizin butylated Page: << < 1 2 3 4 5 > >> 1...

46

Crown Ethers in Graphene Bring Strong, Selective Binding | ornl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Characterization Crown Ethers in Graphene Bring Strong, Selective Binding November 14, 2014 Schematic showing a graphene sheet containing an array of ideal crown ethers....

47

Purification of aqueous cellulose ethers  

SciTech Connect (OSTI)

Manufacture of cellulose ethers usually involves high amounts of salt by-products. For application of the product, salt must be removed. In this work, we have studied the injection of high-pressure CO{sub 2} into an aqueous polymer-salt solution; we find that upon addition of isopropanol in addition to CO{sub 2}, the solution separates into two phases. One phase is rich in polymer and water, and the other phase contains mostly isopropanol, water and CO{sub 2}. The salt distributes between the two phases, thereby offering interesting possibilities for development of a new purification process for water-soluble polymers. This work presents experimental phase-equilibrium data for hydroxyethyl cellulose and sodium carboxymethyl cellulose with sodium acetate and potassium sulfate, respectively, in the region 40{degree}C and 30 to 80 bar. Based on these data, we suggest a process for the manufacture and purification of water-soluble cellulose ethers. 15 refs., 14 figs., 9 tabs.

Bartscherer, K.A.; de Pablo, J.J.; Bonnin, M.C.; Prausnitz, J.M.

1990-07-01T23:59:59.000Z

48

Alternative Fuels Data Center: Ethanol Blend Definition  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blend Blend Definition to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Definition on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Definition on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Definition on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Definition on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Definition on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Definition An ethanol blend is defined as a blended motor fuel containing ethyl alcohol that is at least 99% pure, derived from agricultural products, and

49

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

50

Vehicle Technologies Office: Intermediate Ethanol Blends  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intermediate Ethanol Intermediate Ethanol Blends to someone by E-mail Share Vehicle Technologies Office: Intermediate Ethanol Blends on Facebook Tweet about Vehicle Technologies Office: Intermediate Ethanol Blends on Twitter Bookmark Vehicle Technologies Office: Intermediate Ethanol Blends on Google Bookmark Vehicle Technologies Office: Intermediate Ethanol Blends on Delicious Rank Vehicle Technologies Office: Intermediate Ethanol Blends on Digg Find More places to share Vehicle Technologies Office: Intermediate Ethanol Blends on AddThis.com... Just the Basics Hybrid & Vehicle Systems Energy Storage Advanced Power Electronics & Electrical Machines Advanced Combustion Engines Fuels & Lubricants Fuel Effects on Combustion Lubricants Natural Gas Research Biofuels End-Use Research

51

Alternative Fuels Data Center: Biodiesel Blend Standards  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Biodiesel Blend Standards to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Standards on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Standards on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Standards on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Standards on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Standards on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Standards on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Standards Biodiesel blends are considered compliant with Texas Low Emissions Diesel Fuel (TxLED) regulations if the diesel fuel is compliant with TxLED

52

Alternative Fuels Data Center: Ethanol Blending Regulation  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blending Ethanol Blending Regulation to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blending Regulation on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blending Regulation on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blending Regulation on Google Bookmark Alternative Fuels Data Center: Ethanol Blending Regulation on Delicious Rank Alternative Fuels Data Center: Ethanol Blending Regulation on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blending Regulation on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blending Regulation Gasoline suppliers who provide fuel to distributors in the state must offer gasoline that is suitable for blending with fuel alcohol. Suppliers may not

53

Alternative Fuels Data Center: Ethanol Blend Requirement  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blend Ethanol Blend Requirement to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Requirement on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Requirement on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Requirement on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Requirement on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Requirement on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Requirement Suppliers that import gasoline for sale in North Carolina must offer fuel that is not pre-blended with fuel alcohol but that is suitable for future

54

Alternative Fuels Data Center: Ethanol Blend Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blend Mandate Ethanol Blend Mandate to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Mandate on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Mandate on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Mandate on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Mandate on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Mandate on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Mandate All gasoline offered for sale at retail stations within the state must contain 10% ethanol (E10). This requirement is waived only if a distributor is unable to purchase ethanol or ethanol-blended gasoline at the same or

55

DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Their strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The bulk of the efforts over the past year were focused on the conversion of the campus shuttle bus. This process, started in August 2001, took until April 2002 to complete. The process culminated in an event to celebrate the launching of the shuttle bus on DME-diesel operation on April 19, 2002. The design of the system on the shuttle bus was patterned after the system developed in the engine laboratory, but also was subjected to a rigorous failure modes effects analysis (FMEA, referred to by Air Products as a ''HAZOP'' analysis) with help from Dr. James Hansel of Air Products. The result of this FMEA was the addition of layers of redundancy and over-pressure protection to the system on the shuttle bus. The system became operational in February 2002. Preliminary emissions tests and basic operation of the shuttle bus took place at the Pennsylvania Transportation Institute's test track facility near the University Park airport. After modification and optimization of the system on the bus, operation on the campus shuttle route began in early June 2002. However, the work and challenges continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. In late June 2002, the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head was installed on the system to alleviate this problem and the shuttle bus operated successfully on DME blends from 10-25 vol% on the shuttle bus loop until September 30, 2002. During the period of operation on the campus loop, the bus was pulled from service, operated at the PTI test track and real-time emissions measurements were obtained using an on-board emissions analyzer from Clean Air Technologies International, Inc. Particulate emissions reductions of 60% and 80% were observed at DME blend ratios of 12 vol.% and 25 vol.%, respectively, as the bus was operated over the Orange County driving cycle. Increases in NOx, CO and HC emissions were observed, however. In summary, the conversion of the shuttle bus was successfully accomplished, particulate emissions reductions were observed, but there were operational challenges in the field. Nonetheless, they were able to demonstrate reliable operation of the shuttle bus on DME-diesel blends.

Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

2003-04-01T23:59:59.000Z

56

Method to blend separator powders  

DOE Patents [OSTI]

A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

Guidotti, Ronald A. (Albuquerque, NM); Andazola, Arthur H. (Albuquerque, NM); Reinhardt, Frederick W. (Albuquerque, NM)

2007-12-04T23:59:59.000Z

57

Sandia National Laboratories: Biofuels Blend Right In: Researchers...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends...

58

Alternative Fuels Data Center: Ethanol Blend Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blend Mandate Blend Mandate to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Mandate on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Mandate on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Mandate on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Mandate on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Mandate on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Mandate Within one year after the Montana Department of Transportation has certified that ethanol producers in the state have produced a total of 40 million gallons of denatured ethanol and have maintained that level of

59

Alternative Fuels Data Center: Biofuel Blend Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blend Mandate Blend Mandate to someone by E-mail Share Alternative Fuels Data Center: Biofuel Blend Mandate on Facebook Tweet about Alternative Fuels Data Center: Biofuel Blend Mandate on Twitter Bookmark Alternative Fuels Data Center: Biofuel Blend Mandate on Google Bookmark Alternative Fuels Data Center: Biofuel Blend Mandate on Delicious Rank Alternative Fuels Data Center: Biofuel Blend Mandate on Digg Find More places to share Alternative Fuels Data Center: Biofuel Blend Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biofuel Blend Mandate All Gasoline sold or offered for sale in Minnesota must contain at least: 10% corn-based ethanol by volume or the maximum percent by volume of corn-based ethanol authorized in a waiver issued by the U.S. Environmental

60

Alternative Fuels Data Center: Biodiesel Blend Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Biodiesel Blend Mandate to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Mandate on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Mandate on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Mandate on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Mandate on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Mandate on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Mandate All diesel fuel sold to state agencies, political subdivisions of the state, and public schools for use in on-road motor vehicles must contain at

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Alternative Fuels Data Center: Biodiesel Blend Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Biodiesel Blend Mandate to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Mandate on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Mandate on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Mandate on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Mandate on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Mandate on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Mandate In September 2013, the commissioners of the Minnesota Department of Agriculture, Department of Commerce, and Pollution Control Agency determined that all conditions had been satisfied to implement a 10%

62

Alternative Fuels Data Center: Biodiesel Blend Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Biodiesel Blend Mandate to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Mandate on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Mandate on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Mandate on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Mandate on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Mandate on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Mandate Pursuant to state law, all diesel motor vehicle fuel and all other liquid fuel used to operate motor vehicle diesel engines in Massachusetts must

63

Interaction blending equations enhance reformulated gasoline profitability  

SciTech Connect (OSTI)

The interaction approach to gasoline blending gives refiners an accurate, simple means of re-evaluating blending equations and increasing profitability. With reformulated gasoline specifications drawing near, a detailed description of this approach, in the context of reformulated gasoline is in order. Simple mathematics compute blending values from interaction equations and interaction coefficients between mixtures. A timely example of such interactions is: blending a mixture of catalytically cracked gasoline plus light straight run (LSR) from one tank with alkylate plus reformate from another. This paper discusses blending equations, using interactions, mixture interactions, other blending problems, and obtaining equations.

Snee, R.D. (Joiner Associates, Madison, WI (United States)); Morris, W.E.; Smith, W.E.

1994-01-17T23:59:59.000Z

64

Hybrid Time Formulation for Diesel Blending and Distribution Scheduling  

Science Journals Connector (OSTI)

Hybrid Time Formulation for Diesel Blending and Distribution Scheduling ... Schematic of diesel in-line blending and distribution infrastructure. ...

Sérgio M. S. Neiro; Valéria V. Murata; José M. Pinto

2014-06-13T23:59:59.000Z

65

The Fusibility of Blended Coal Ash  

Science Journals Connector (OSTI)

Ash fusibility temperatures (AFT) of coal ash are found at temperatures below the predicted liquidus temperature and, for ashes from blended coals, are generally nonlinear with respect to the blend proportion. ... ashing. ...

G. W. Bryant; G. J. Browning; H. Emanuel; S. K. Gupta; R. P. Gupta; J. A. Lucas; T. F. Wall

2000-02-25T23:59:59.000Z

66

Biodegradation of Methyl tert-Butyl Ether and Other Fuel Oxygenates by a New Strain, Mycobacterium austroafricanum IFP 2012  

Science Journals Connector (OSTI)

...and the O2 consumption rate was measured with a 12-mm...France). The measured rates were corrected for endogenous...Cells were broken by three passes through a French press...from 105 to 200C at a rate of 10C/min. Helium...flushed with a Spectra-Physics SCM 400 vacuum flusher...

Alan François; Hugues Mathis; Davy Godefroy; Pascal Piveteau; Françoise Fayolle; Frédéric Monot

2002-06-01T23:59:59.000Z

67

Induction of Methyl Tertiary Butyl Ether (MTBE)-Oxidizing Activity in Mycobacterium vaccae JOB5 by MTBE  

Science Journals Connector (OSTI)

...directly from the culture vessels. In experiments that followed...time course of organic acid consumption as well as MTBE oxidation...determine the extent of MTBE consumption and the accumulation of TBA...detectable growth or MTBE consumption occurred when cells were incubated...

Erika L. Johnson; Christy A. Smith; Kirk T. O'Reilly; Michael R. Hyman

2004-02-01T23:59:59.000Z

68

Enhancing Transport of Hydrogenophaga flava ENV735 for Bioaugmentation of Aquifers Contaminated with Methyl tert-Butyl Ether  

Science Journals Connector (OSTI)

...column was washed with the surfactant solution. d The sand was prewashed with the surfactant solution, and the cells...washed with BSM without surfactant. This work was supported...bacteria through a sandy soil. Appl. Environ. Microbiol...

Sheryl H. Streger; Simon Vainberg; Hailiang Dong; Paul B. Hatzinger

2002-11-01T23:59:59.000Z

69

Treatment of methyl t-butyl ether contaminated water using a dense medium plasma reactor, a mechanistic and kinetic investigation  

E-Print Network [OSTI]

, a mechanistic and kinetic investigation Derek C. Johnson1 , Vasgen A. Shamamian2 , John H. Callahan2 , Ferencz S in the future remediation of water. Chemical and physical mechanisms, together with carbon balances, are used

Dandy, David

70

Effects of Gasoline Formulation on Methyl tert-Butyl Ether (MTBE) Contamination in Private Wells near Gasoline Stations  

Science Journals Connector (OSTI)

New York State Department of Health, Bureau of Environmental Exposure Investigation, 547 River Street, Room 300, Troy, New York 12180, and New York State Department of Health, Wadsworth Center for Laboratories and Research, P.O. ... Wells with contamination of ?20 ?g/L were scheduled for periodic or follow-up sampling by local county health departments or scheduled for remedial action, as appropriate. ... (13)?Delzer, G. C.; Zogorski, J. S.; Lopes, T. J.; Bosshart, R. L. Occurrence of the gasoline Oxygenate MTBE and BTEX compounds in urban stormwater in the United States, 1991?1995; U.S. Geologic Survey Water-Resources Investigations Report, WRIR 96-4145, Rapid City, SD, 1996. ...

Daniel P. Lince; Lloyd R. Wilson; Gordon A. Carlson; Anthony Bucciferro

2001-02-10T23:59:59.000Z

71

Enhancing Transport of Hydrogenophaga flava ENV735 for Bioaugmentation of Aquifers Contaminated with Methyl tert-Butyl Ether  

Science Journals Connector (OSTI)

...National Science Foundation Small Business Innovative Research (SBIR) program (award no...Ontario, Canada. Ground Water Monit. Remediation 18: 113-122. 52 Scholl, M. A...evaluation of in situ bioaugmentation for remediation of chlorinated solvents in groundwater...

Sheryl H. Streger; Simon Vainberg; Hailiang Dong; Paul B. Hatzinger

2002-11-01T23:59:59.000Z

72

Measurement of Trihalomethanes and Methyl Tertiary-Butyl Ether in Tap Water Using Solid-Phase Microextraction GC-MS  

Science Journals Connector (OSTI)

......ductive age living in Corpus Christi, Texas and Cobb...micro extraction with gas chromatography-mass...determinations using gas chromatog- raphy...of fulvic acids in natural waters. Env. Sci...trihalomethane by headspace-gas chromatog- raphy......

Frederick L. Cardinali; David L. Ashley; John C. Morrow; Deborah M. Moll; Benjamin C. Blount

2004-04-01T23:59:59.000Z

73

The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol  

Science Journals Connector (OSTI)

...The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol G. R. Freeman The two modes of decomposition of ethanol at 525 degrees C, namely dehydration and dehydrogenation, are affected...

1958-01-01T23:59:59.000Z

74

Process for making propenyl ethers and photopolymerizable compositions containing them  

DOE Patents [OSTI]

Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} (V) wherein n is an integer from one to six and A is selected from cyclic ethers, polyether, and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Crivello, J.V.

1996-01-23T23:59:59.000Z

75

Alternative Fuels Data Center: Biofuel Blend Dispenser Labeling Requirement  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biofuel Blend Biofuel Blend Dispenser Labeling Requirement to someone by E-mail Share Alternative Fuels Data Center: Biofuel Blend Dispenser Labeling Requirement on Facebook Tweet about Alternative Fuels Data Center: Biofuel Blend Dispenser Labeling Requirement on Twitter Bookmark Alternative Fuels Data Center: Biofuel Blend Dispenser Labeling Requirement on Google Bookmark Alternative Fuels Data Center: Biofuel Blend Dispenser Labeling Requirement on Delicious Rank Alternative Fuels Data Center: Biofuel Blend Dispenser Labeling Requirement on Digg Find More places to share Alternative Fuels Data Center: Biofuel Blend Dispenser Labeling Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biofuel Blend Dispenser Labeling Requirement

76

Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Fuel Blend Ethanol Fuel Blend Dispensing Regulations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Fuel Blend Dispensing Regulations

77

Alternative Fuels Data Center: Biodiesel Blend Purchase Requirement  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blend Blend Purchase Requirement to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Purchase Requirement on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Purchase Requirement on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Purchase Requirement on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Purchase Requirement on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Purchase Requirement on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Purchase Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Purchase Requirement Diesel fuel that the New Hampshire Department of Transportation

78

Alternative Fuels Data Center: Ethanol Blend Infrastructure Grant Program  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blend Ethanol Blend Infrastructure Grant Program to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Infrastructure Grant Program on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Infrastructure Grant Program on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Infrastructure Grant Program on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Infrastructure Grant Program on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Infrastructure Grant Program on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Infrastructure Grant Program on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Infrastructure Grant Program

79

Radiation effects on polypropylene/polybutylene blends  

SciTech Connect (OSTI)

Polymer blends of polypropylene and polybutylene have been found to exhibit substantial maintenance of structural integrity after exposure to ionizing radiation. This radiation resistance has been found to be related to processing conditions and the resulting morphology of the blend. This article discusses (a) the processing conditions and the resulting mechanical properties after irradiation and (b) the role of morphology in this unexpected blend property.

Rolando, R.J. (3M Engineering Systems and Technology, St. Paul, MN (United States))

1993-06-01T23:59:59.000Z

80

Performance of Biofuels and Biofuel Blends  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Complete 4 Relevance Objective: Solve technical problems that are preventing expanded markets for current and future biofuels and biofuel blends Necessary to achieve MYPP...

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Renewable Oxygenate Blending Effects on Gasoline Properties  

Science Journals Connector (OSTI)

Renewable Oxygenate Blending Effects on Gasoline Properties ... National Renewable Energy Laboratory, Golden, Colorado 80401, United States ... Energy Fuels, 2011, 25 (10), ...

Earl Christensen; Janet Yanowitz; Matthew Ratcliff; Robert L. McCormick

2011-08-16T23:59:59.000Z

82

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Inputs & Utilization Inputs & Utilization Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Barrel A unit of volume equal to 42 U.S. gallons. Blending Plant A facility which has no refining capability but is either capable of producing finished motor gasoline through mechanical blending or blends oxygenates with motor gasoline.

83

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Ethanol Plant Production Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up to 10 percent by volume anhydrous ethanol (200 proof) (commonly referred to as the "gasohol waiver"). Methanol: Blends of methanol and gasoline-grade tertiary butyl alcohol (GTBA) such that the total oxygen content does not exceed 3.5 percent by weight and the ratio of methanol to GTBA is less than or equal to 1. It is also specified that this blended fuel must meet ASTM volatility specifications (commonly referred to as the "ARCO" waiver).

84

Alternative Fuels Data Center: Biofuel Blending Capability Requirements and  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biofuel Blending Biofuel Blending Capability Requirements and Regulations to someone by E-mail Share Alternative Fuels Data Center: Biofuel Blending Capability Requirements and Regulations on Facebook Tweet about Alternative Fuels Data Center: Biofuel Blending Capability Requirements and Regulations on Twitter Bookmark Alternative Fuels Data Center: Biofuel Blending Capability Requirements and Regulations on Google Bookmark Alternative Fuels Data Center: Biofuel Blending Capability Requirements and Regulations on Delicious Rank Alternative Fuels Data Center: Biofuel Blending Capability Requirements and Regulations on Digg Find More places to share Alternative Fuels Data Center: Biofuel Blending Capability Requirements and Regulations on AddThis.com... More in this section...

85

EffectsIntermediateEthanolBlends.pdf | Department of Energy  

Office of Environmental Management (EM)

ctsIntermediateEthanolBlends.pdf More Documents & Publications Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009...

86

Intermediate Ethanol Blends: Plans and Status | Department of...  

Energy Savers [EERE]

Intermediate Ethanol Blends: Plans and Status Intermediate Ethanol Blends: Plans and Status Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008...

87

Effects of Intermediate Ethanol Blends on Legacy Vehicles and...  

Office of Environmental Management (EM)

Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

88

Mid-Blend Ethanol Fuels - Implementation Perspectives | Department...  

Broader source: Energy.gov (indexed) [DOE]

Mid-Blend Ethanol Fuels - Implementation Perspectives Mid-Blend Ethanol Fuels - Implementation Perspectives Breakout Session 2: Frontiers and Horizons Session 2-B: End Use and Fuel...

89

Advancing Biorefining of Distiller's Grain and Corn Stover Blends...  

Broader source: Energy.gov (indexed) [DOE]

Advancing Biorefining of Distiller's Grain and Corn Stover Blends Advancing Biorefining of Distiller's Grain and Corn Stover Blends This fact sheet summarizes a U.S. Department of...

90

Effect of Biodiesel Blends on NOx Emissions | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Biodiesel Blends on NOx Emissions Effect of Biodiesel Blends on NOx Emissions Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007)....

91

Green emitting phosphors and blends thereof  

DOE Patents [OSTI]

Phosphor compositions, blends thereof and light emitting devices including white light emitting LED based devices, and backlights, based on such phosphor compositions. The devices include a light source and a phosphor material as described. Also disclosed are phosphor blends including such a phosphor and devices made therefrom.

Setlur, Anant Achyut (Niskayuna, NY); Siclovan, Oltea Puica (Rexford, NY); Nammalwar, Prasanth Kumar (Bangalore, IN); Sathyanarayan, Ramesh Rao (Bangalore, IN); Porob, Digamber G. (Goa, IN); Chandran, Ramachandran Gopi (Bangalore, IN); Heward, William Jordan (Saratoga Springs, NY); Radkov, Emil Vergilov (Euclid, OH); Briel, Linda Jane Valyou (Niskayuna, NY)

2010-12-28T23:59:59.000Z

92

PAIRWISE BLENDING OF HIGH LEVEL WASTE (HLW)  

SciTech Connect (OSTI)

The primary objective of this study is to demonstrate a mission scenario that uses pairwise and incidental blending of high level waste (HLW) to reduce the total mass of HLW glass. Secondary objectives include understanding how recent refinements to the tank waste inventory and solubility assumptions affect the mass of HLW glass and how logistical constraints may affect the efficacy of HLW blending.

CERTA, P.J.

2006-02-22T23:59:59.000Z

93

Performance and Emissions of a Compression Ignition Engine Fueled with Diesel/Oxygenate Blends for Various Fuel Delivery Advance Angles  

Science Journals Connector (OSTI)

State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an, People's Republic of China ... In the application of pure oxygenated fuels, Fleisch et al.,1 Kapus and Ofner,2 and Sorenson and Mikkelsen3 have studied dimethyl ether (DME) in a modified diesel engine, and their results showed that the engine could achieve ultralow-emission prospects without a fundamental change in combustion systems. ... Although some previous work has revealed the characteristics of diesel/ethanol blends in a compression ignition engine (Satge de Caro et al.,14 Ali et al.15), there, however, is still much work that needs to be done in regard to the application of diesel/methanol blends in compression ignition engines, especially in clarifying the basic combustion and emission. ...

Zuohua Huang; Hongbing Lu; Deming Jiang; Ke Zeng; Bing Liu; Junqiang Zhang; Xibin Wang

2005-02-02T23:59:59.000Z

94

Crown Ethers Flatten in Graphene for Strong, Specific Binding...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crown Ethers Flatten in Graphene for Strong, Specific Binding ORNL discovery holds potential for separations, sensors, batteries, biotech and more This sheet of graphene contains...

95

Investigation of HCCI Combustion of Diethyl Ether and Ethanol Mixtures Using Carbon 14 Tracing and Numerical Simulations  

SciTech Connect (OSTI)

Despite the rapid combustion typically experienced in Homogeneous Charge Compression Ignition (HCCI), components in fuel mixtures do not ignite in unison or burn equally. In our experiments and modeling of blends of diethyl ether (DEE) and ethanol (EtOH), the DEE led combustion and proceeded further toward completion, as indicated by {sup 14}C isotope tracing. A numerical model of HCCI combustion of DEE and EtOH mixtures supports the isotopic findings. Although both approaches lacked information on incompletely combusted intermediates plentiful in HCCI emissions, the numerical model and {sup 14}C tracing data agreed within the limitations of the single zone model. Despite the fact that DEE is more reactive than EtOH in HCCI engines, they are sufficiently similar that we did not observe a large elongation of energy release or significant reduction in inlet temperature required for light-off, both desired effects for the combustion event. This finding suggests that, in general, HCCI combustion of fuel blends may have preferential combustion of some of the blend components.

Mack, J H; Dibble, R W; Buchholz, B A; Flowers, D L

2004-01-16T23:59:59.000Z

96

Alternative Fuels Data Center: Biodiesel Blend Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Tax Biodiesel Blend Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Tax Credit on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Tax Credit on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Tax Credit Licensed biodiesel blenders are eligible for a tax credit for special fuel, including diesel, blended with biodiesel to create a biodiesel blend. The

97

Alternative Fuels Data Center: Ethanol Blended Fuel Definition  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blended Fuel Ethanol Blended Fuel Definition to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blended Fuel Definition on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blended Fuel Definition on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blended Fuel Definition on Google Bookmark Alternative Fuels Data Center: Ethanol Blended Fuel Definition on Delicious Rank Alternative Fuels Data Center: Ethanol Blended Fuel Definition on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blended Fuel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blended Fuel Definition Ethanol blended fuel, such as gasohol, is defined as any gasoline blended with 10% or more of anhydrous ethanol. (Reference Idaho Statutes 63-240

98

Densities and isobaric vapor-liquid equilibria for the mixtures formed by four butyl esters and 1-butanol  

SciTech Connect (OSTI)

Densities of 298.15 K and the vapor-liquid equilibria for 1-butanol + butyl methanoate, + butyl ethanoate, + butyl propanoate, and + butyl butanoate have been measured at 101.32 kPa in small capacity ebulliometer. All results were found to be thermodynamically consistent with a point-to-point test. The mixtures containing butyl methanoate and butyl ethanoate show azeotropes at T = 379.14 K, x = 0.871 and T = 389.64 K, x = 0.222, respectively. Different group-contribution methods were applied to these mixtures.

Gonzalez, E.; Ortega, J. [Univ. of Las Palmas de Gran Canaria (Spain)] [Univ. of Las Palmas de Gran Canaria (Spain)

1996-01-01T23:59:59.000Z

99

A Blended Space for Tourism: Genesee Village Country & Museum  

E-Print Network [OSTI]

A Blended Space for Tourism: Genesee Village Country & Museum Abstract Blended spaces are spaces on this enables us to provide general guidance and framework on the design of blended spaces for digital tourism. Author Keywords Design, Tourism, Blended Spaces, User Experience ACM Classification Keywords H.5.2 User

Deussen, Oliver

100

Alternative Fuels Data Center: Biodiesel Production and Blending Equipment  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Production Biodiesel Production and Blending Equipment Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Production and Blending Equipment Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Production and Blending Equipment Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Production and Blending Equipment Tax Credit on Google Bookmark Alternative Fuels Data Center: Biodiesel Production and Blending Equipment Tax Credit on Delicious Rank Alternative Fuels Data Center: Biodiesel Production and Blending Equipment Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Production and Blending Equipment Tax Credit on AddThis.com... More in this section... Federal State

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Alternative Fuels Data Center: Biofuels Blend Use Requirement  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biofuels Blend Use Biofuels Blend Use Requirement to someone by E-mail Share Alternative Fuels Data Center: Biofuels Blend Use Requirement on Facebook Tweet about Alternative Fuels Data Center: Biofuels Blend Use Requirement on Twitter Bookmark Alternative Fuels Data Center: Biofuels Blend Use Requirement on Google Bookmark Alternative Fuels Data Center: Biofuels Blend Use Requirement on Delicious Rank Alternative Fuels Data Center: Biofuels Blend Use Requirement on Digg Find More places to share Alternative Fuels Data Center: Biofuels Blend Use Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biofuels Blend Use Requirement Whenever possible, governmental entities and state educational institutions must fuel diesel vehicles with biodiesel blends containing at least 2%

102

Alternative Fuels Data Center: Biodiesel Blending Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blending Tax Blending Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Google Bookmark Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Delicious Rank Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blending Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blending Tax Credit A biodiesel blender located in Indiana may receive a credit of $0.02 per gallon of blended biodiesel produced at a facility located in Indiana. The

103

Alternative Fuels Data Center: Diesel Fuel Blend Tax Exemption  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Diesel Fuel Blend Tax Diesel Fuel Blend Tax Exemption to someone by E-mail Share Alternative Fuels Data Center: Diesel Fuel Blend Tax Exemption on Facebook Tweet about Alternative Fuels Data Center: Diesel Fuel Blend Tax Exemption on Twitter Bookmark Alternative Fuels Data Center: Diesel Fuel Blend Tax Exemption on Google Bookmark Alternative Fuels Data Center: Diesel Fuel Blend Tax Exemption on Delicious Rank Alternative Fuels Data Center: Diesel Fuel Blend Tax Exemption on Digg Find More places to share Alternative Fuels Data Center: Diesel Fuel Blend Tax Exemption on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Diesel Fuel Blend Tax Exemption The biodiesel or ethanol portion of blended fuel containing taxable diesel

104

Alternative Fuels Data Center: Biodiesel Blend Tax Exemption  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Tax Biodiesel Blend Tax Exemption to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Tax Exemption on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Tax Exemption on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Tax Exemption on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Tax Exemption on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Tax Exemption on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Tax Exemption on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Tax Exemption Biodiesel blends of at least 20% (B20) that are used for personal, noncommercial use by the individual that produced the biodiesel portion of

105

Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blend Ethanol Blend Dispenser Requirement to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Dispenser Requirement An ethanol retailer selling a blend of 10% ethanol by volume or higher must

106

Alternative Fuels Data Center: Biodiesel Blending Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blending Tax Blending Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Google Bookmark Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Delicious Rank Alternative Fuels Data Center: Biodiesel Blending Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blending Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blending Tax Credit Businesses and individuals are eligible for a tax credit of up to 15% of the cost of qualified equipment used for storing or blending biodiesel with

107

Alternative Fuels Data Center: Biodiesel Blend Retailer Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Biodiesel Blend Retailer Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Retailer Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Retailer Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Retailer Tax Credit on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Retailer Tax Credit on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Retailer Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Retailer Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Retailer Tax Credit Retailers whose total diesel sales consist of at least 50% biodiesel blends

108

Alternative Fuels Data Center: Ethanol Blend Labeling Requirements  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blend Labeling Ethanol Blend Labeling Requirements to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Labeling Requirements on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Labeling Requirements on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Labeling Requirements on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Labeling Requirements on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Labeling Requirements on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Labeling Requirements on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Labeling Requirements Pumps that dispense ethanol-blended gasoline available for purchase must be

109

Alternative Fuels Data Center: Biofuel Blending Equipment Tax Exemption  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Blending Blending Equipment Tax Exemption to someone by E-mail Share Alternative Fuels Data Center: Biofuel Blending Equipment Tax Exemption on Facebook Tweet about Alternative Fuels Data Center: Biofuel Blending Equipment Tax Exemption on Twitter Bookmark Alternative Fuels Data Center: Biofuel Blending Equipment Tax Exemption on Google Bookmark Alternative Fuels Data Center: Biofuel Blending Equipment Tax Exemption on Delicious Rank Alternative Fuels Data Center: Biofuel Blending Equipment Tax Exemption on Digg Find More places to share Alternative Fuels Data Center: Biofuel Blending Equipment Tax Exemption on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biofuel Blending Equipment Tax Exemption Qualified equipment used for storing and blending petroleum-based fuel with

110

BLENDING PROBLEM A refinery blends four petroleum components into three grades of  

E-Print Network [OSTI]

BLENDING PROBLEM A refinery blends four petroleum components into three grades of gasoline/day $/barrel #1 5,000 $9.00 #2 2,400 7.00 #3 4,000 12.00 #4 1,500 6.00 Blending formulas and selling price 4,000 x4R + x4P + x4L 1,500 #12;blending: (1) x1R / (x1R + x2R + x3R + x4R) .40 or x1R .40(x1R

Shier, Douglas R.

111

Mid-Blend Ethanol Fuels ? Implementation Perspectives  

Broader source: Energy.gov (indexed) [DOE]

Wall" * E15 is the answer to the question nobody asked * E85 has no market penetration * GHG Rulemaking removes incentives for OEMs to produce FFV vehicles Page 15 Mid Blend...

112

Intermediate Ethanol Blends: Plans and Status  

Energy Savers [EERE]

* 60,000 E85 stations vs 1,200 today. Background * DOE intermediate ethanol blend test plan development began March 2007 - DOE funding: 14.6M (2007 & 2008) - Organizational...

113

Imaginative play with blended reality characters  

E-Print Network [OSTI]

The idea and formative design of a blended reality character, a new class of character able to maintain visual and kinetic continuity between the fully physical and fully virtual; the technical underpinnings of its unique ...

Robert, David Yann

2011-01-01T23:59:59.000Z

114

Biodiesel Production and Blending Tax Credit (Kentucky)  

Broader source: Energy.gov [DOE]

blended biodiesel does not qualify. The biodiesel tax credit is applied against the corporation income tax imposed under KRS 141.040 and/or the limited liability entity tax (LLET) imposed under KRS...

115

Continuous blending of dry pharmaceutical powders  

E-Print Network [OSTI]

Conventional batch blending of pharmaceutical powders coupled with long quality analysis times increases the production cycle time leading to strained cash flows. Also, scale-up issues faced in process development causes ...

Pernenkil, Lakshman

2008-01-01T23:59:59.000Z

116

Storage Stability of Biodiesel and Biodiesel Blends  

Science Journals Connector (OSTI)

Storage Stability of Biodiesel and Biodiesel Blends ... The biodiesels were selected to represent unstable material (D) with an induction time of 0.5 h and moderately stable material (B) with an induction time of 3.1 h. ...

Robert L. McCormick; Steven R. Westbrook

2009-10-16T23:59:59.000Z

117

Vehicle Technologies Office: Intermediate Ethanol Blends  

Broader source: Energy.gov [DOE]

Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline). The Renewable Fuels Standard (under the Energy...

118

Solvent Effects on Metal Complexation with Crown Ethers from Liquid to Supercritical Fluids (DE-FG07-98ER 149 13)  

SciTech Connect (OSTI)

The purpose of this project is to study the salvation effects of metal-crown ether complexation in different solvents. It has been suggested in the literature that supercritical fluid carbon dioxide (SF-CO2) is a tunable solvent because its salvation environment can be varied with the fluid density. In this project, spectroscopic techniques including nuclear magnetic resonance (NMR) and Fourier Transform Infrared (FTIR) were used to evaluate salvation effects of metal crown complexation in organic solvents and in SF-CO2. In most solvent extraction systems, water is often involved in the extraction processes. We have carried out extensive studies of water-crown ether interactions in different solvents and in SF-CO2 using NMR and FTIR techniques. Water molecules can be attached to crown ethers through hydrogen bonding of H-0-H to the oxygen atoms of crown ether cavities. This type of interaction is like a Lewis acid-Lewis base complexation. During the course of this project, we noticed that some CO2 soluble Lewis base such as tri-n-butyl-phosphate (TBP) can also form such Lewis acid-Lewis base complexes with water and other inorganic acids including nitric acid and hydrochloric acid. Inorganic acids (e.g. nitric acid) are normally not soluble in SF-CO2. However, because TBP is highly soluble in SF-CO2, an inorganic acid bound to TBP via hydrogen bonding becomes CO2 soluble. This Lewis acid-Lewis base complex approach provides a method of introducing inorganic acids into supercritical fluid CO2 for chemical reactions.

Wai, C.M.

2002-06-01T23:59:59.000Z

119

WI Biodiesel Blending Progream Final Report  

SciTech Connect (OSTI)

The Wisconsin State Energy Office�¢����s (SEO) primary mission is to implement cost�¢���effective, reliable, balanced, and environmentally�¢���friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

Redmond, Maria E; Levy, Megan M

2013-04-01T23:59:59.000Z

120

Crown Ethers in Nonaqueous Electrolytes for Lithium/Air Batteries  

SciTech Connect (OSTI)

The effects of three crown ethers, 12-crown-4, 15-crown-5, and 18-crown-6, as additives and co-solvents in non-aqueous electrolytes on the cell performance of primary Li/air batteries operated in a dry air environment were investigated. Crown ethers have large effects on the discharge performance of non-aqueous electrolytes in Li/air batteries. A small amount (normally less than 10% by weight or volume in electrolytes) of 12-Crown-4 and 15-crown-5 reduces the battery performance and a minimum discharge capacity appears at the crown ether content of ca. 5% in the electrolytes. However, when the content increases to about 15%, both crown ethers improve the capacity of Li/air cells by about 28% and 16%, respectively. 15-Crown-5 based electrolytes even show a maximum discharge capacity in the crown ether content range from 10% to 15%. On the other hand, the increase of 18-crown-6 amount in the electrolytes continuously lowers of the cell performance. The different battery performances of these three crown ethers in electrolytes are explained by the combined effects from the electrolytes’ contact angle, oxygen solubility, viscosity, ionic conductivity, and the stability of complexes formed between crown ether molecules and lithium ions.

Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

2010-02-04T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper and lower critical consolute points  

E-Print Network [OSTI]

has been measured for a two-component critical liquid system, butyl cellosolve-water, in the region to report measurements of the shear viscosity of critical binary mixture butyl cello- solve (2-n353 Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper

Boyer, Edmond

122

Alternative Fuels Data Center: Ethanol Fuel Blend Use Requirement  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Fuel Blend Use Ethanol Fuel Blend Use Requirement to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Blend Use Requirement on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Blend Use Requirement on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Use Requirement on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Use Requirement on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Blend Use Requirement on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Blend Use Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Fuel Blend Use Requirement State government agencies and universities owning or operating motor

123

Alternative Fuels Data Center: Biodiesel Blend Use Requirement  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Use Biodiesel Blend Use Requirement to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Use Requirement on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Use Requirement on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Use Requirement on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Use Requirement on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Use Requirement on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Use Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Use Requirement Any diesel-powered vehicle the state, county or local government, school district, community college, public college or university, or mass transit

124

Alternative Fuels Data Center: Biodiesel Blend Distribution Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blend Biodiesel Blend Distribution Mandate to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blend Distribution Mandate on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blend Distribution Mandate on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blend Distribution Mandate on Google Bookmark Alternative Fuels Data Center: Biodiesel Blend Distribution Mandate on Delicious Rank Alternative Fuels Data Center: Biodiesel Blend Distribution Mandate on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blend Distribution Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blend Distribution Mandate All state-owned diesel fueling facilities must provide fuel containing at

125

Alternative Fuels Data Center: Ethanol Fuel Blend Tax Rate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Fuel Blend Tax Ethanol Fuel Blend Tax Rate to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Blend Tax Rate on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Blend Tax Rate on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Tax Rate on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Tax Rate on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Blend Tax Rate on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Blend Tax Rate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Fuel Blend Tax Rate The tax rate on fuel containing ethanol is $0.06 per gallon less than the tax rate on other motor fuels in certain geographic areas. This reduced

126

Alternative Fuels Data Center: Ethanol Blend Retailer Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blend Retailer Ethanol Blend Retailer Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Retailer Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Retailer Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Retailer Tax Credit on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Retailer Tax Credit on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Retailer Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Retailer Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Retailer Tax Credit The Ethanol Promotion Tax Credit is available to any fuel retailer for up

127

Alternative Fuels Data Center: Biofuel Blending Contract Regulation  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biofuel Blending Biofuel Blending Contract Regulation to someone by E-mail Share Alternative Fuels Data Center: Biofuel Blending Contract Regulation on Facebook Tweet about Alternative Fuels Data Center: Biofuel Blending Contract Regulation on Twitter Bookmark Alternative Fuels Data Center: Biofuel Blending Contract Regulation on Google Bookmark Alternative Fuels Data Center: Biofuel Blending Contract Regulation on Delicious Rank Alternative Fuels Data Center: Biofuel Blending Contract Regulation on Digg Find More places to share Alternative Fuels Data Center: Biofuel Blending Contract Regulation on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biofuel Blending Contract Regulation Any provision in a contract between a fuel wholesaler and a refiner or

128

Alternative Fuels Data Center: Ethanol Fuel Blend Standard  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Fuel Blend Ethanol Fuel Blend Standard to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Blend Standard on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Blend Standard on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Standard on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Standard on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Blend Standard on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Blend Standard on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Fuel Blend Standard At least 85% of gasoline supplied to a retailer or sold in Hawaii must contain a minimum of 10% ethanol (E10), unless the Director determines that

129

Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Blend Ethanol Blend Dispenser Requirement to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Google Bookmark Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Delicious Rank Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blend Dispenser Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Blend Dispenser Requirement A retail motor fuel dispenser that dispenses fuel containing more than 10%

130

Alternative Fuels Data Center: Biodiesel Blending Facility Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Blending Biodiesel Blending Facility Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blending Facility Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blending Facility Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blending Facility Tax Credit on Google Bookmark Alternative Fuels Data Center: Biodiesel Blending Facility Tax Credit on Delicious Rank Alternative Fuels Data Center: Biodiesel Blending Facility Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blending Facility Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Blending Facility Tax Credit A tax credit is available for up to 30% of the cost of purchasing or

131

Atmospheric and combustion chemistry of dimethyl ether  

SciTech Connect (OSTI)

It has been demonstrated that dimethyl ether (DME) is an ideal diesel fuel alternative. DME, CH{sub 3}OCH{sub 3}, combines good fuel properties with low exhaust emissions and low combustion noise. Large scale production of this fuel can take place using a single step catalytic process converting CH{sub 4} to DME. The fate of DME in the atmosphere has previously been studied. The atmospheric degradation is initiated by the reaction with hydroxyl radicals, which is also a common feature of combustion processes. Spectrokinetic investigations and product analysis were used to demonstrate that the intermediate oxy radical, CH{sub 3}OCH{sub 2}O, exhibits a novel reaction pathway of hydrogen atom ejection. The application of tandem mass spectrometry to chemi-ions based on supersonic molecular beam sampling has recently been demonstrated. The highly reactive ionic intermediates are sampled directly from the flame and identified by collision activation mass spectrometry and ion-molecule reactions. The mass spectrum reflects the distribution of the intermediates in the flame. The atmospheric degradation of DME as well as the unique fuel properties of a oxygen containing compound will be discussed.

Nielsen, O.J.; Egsgaard, H.; Larsen, E.; Sehested, J. [Risoe National Lab., Roskilde (Denmark); Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States)

1997-12-31T23:59:59.000Z

132

Mid-Level Ethanol Blends | Department of Energy  

Office of Environmental Management (EM)

2009 -- Washington D.C. ft05knoll.pdf More Documents & Publications Mid-Level Ethanol Blends Test Program Intermediate Ethanol Blends: Plans and Status Biofuels Quality Surveys...

133

Quality Assessment of Biodiesel and Biodiesel Blends | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Quality Assessment of Biodiesel and Biodiesel Blends Quality Assessment of Biodiesel and Biodiesel Blends The results of a quality survey of B20 fuel in the United States were...

134

Mid-Level Ethanol Blends Test Program | Department of Energy  

Office of Environmental Management (EM)

Blends Test Program Mid-Level Ethanol Blends Test Program 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 --...

135

Blending Hydrogen into Natural Gas Pipeline Networks: A Review...  

Energy Savers [EERE]

Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues The United States has 11...

136

Alternative Fuels Data Center: Biodiesel Production and Blending Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Production Biodiesel Production and Blending Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Production and Blending Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Production and Blending Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Production and Blending Tax Credit on Google Bookmark Alternative Fuels Data Center: Biodiesel Production and Blending Tax Credit on Delicious Rank Alternative Fuels Data Center: Biodiesel Production and Blending Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Production and Blending Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Production and Blending Tax Credit

137

Alternative Fuels Data Center: Advanced Ethanol Fuel Blend Research Grants  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Advanced Ethanol Fuel Advanced Ethanol Fuel Blend Research Grants to someone by E-mail Share Alternative Fuels Data Center: Advanced Ethanol Fuel Blend Research Grants on Facebook Tweet about Alternative Fuels Data Center: Advanced Ethanol Fuel Blend Research Grants on Twitter Bookmark Alternative Fuels Data Center: Advanced Ethanol Fuel Blend Research Grants on Google Bookmark Alternative Fuels Data Center: Advanced Ethanol Fuel Blend Research Grants on Delicious Rank Alternative Fuels Data Center: Advanced Ethanol Fuel Blend Research Grants on Digg Find More places to share Alternative Fuels Data Center: Advanced Ethanol Fuel Blend Research Grants on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Advanced Ethanol Fuel Blend Research Grants

138

The viscoelastic properties of linear-star blends  

E-Print Network [OSTI]

In order to understand the nature of polydispersity and characterize the effect of branching architecture, the model blend of linear and star polymer, which is the simplest branched polymer, is contrived. In this blend system, chain dynamics...

Lee, Jung Hun

2000-01-01T23:59:59.000Z

139

Emission of Nanosize Particles in the Process of Nanoclay Blending  

Science Journals Connector (OSTI)

Blending is one of the dustiest operations in the process of developing new fire-safe polyurethane foams. This paper presents the results of an investigation of the emission of nanosize particles released Nanofil®5 nanoclay is blended. Ten 5–20 ... Keywords: nanoclay, blending, emission of nanosize particles

Elzbieta Jankowska; Wojciech Zatorski

2009-02-01T23:59:59.000Z

140

Lyapunov-based Optimizing Control of Nonlinear Blending Process  

E-Print Network [OSTI]

. I. INTRODUCTION Blending processes arise in a wide range of industries, for example gasoline1 Lyapunov-based Optimizing Control of Nonlinear Blending Process Tor A. Johansen£ , Daniel Sb. ££ Department of Electrical Engineering, University of Concepci´on, Concepci´on, Chile. Abstract Blending

Johansen, Tor Arne

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Lyapunov-based Optimizing Control of Nonlinear Blending Processes  

E-Print Network [OSTI]

processes arise in a wide range of industries, for example gasoline blending [1], [2], [3], [4], food1 Lyapunov-based Optimizing Control of Nonlinear Blending Processes Tor A. Johansen , Daniel Sb. Department of Electrical Engineering, University of Concepci´on, Concepci´on, Chile. Abstract Blending

Johansen, Tor Arne

142

HEU to LEU conversion and blending facility: Metal blending alternative to produce LEU oxide for disposal  

SciTech Connect (OSTI)

US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. The nuclear material is converted to a form more proliferation- resistant than the original form. Blending HEU (highly enriched uranium) with less-enriched uranium to form LEU has been proposed as a disposition option. Five technologies are being assessed for blending HEU. This document provides data to be used in environmental impact analysis for the HEU-LEU disposition option that uses metal blending with an oxide waste product. It is divided into: mission and assumptions, conversion and blending facility descriptions, process descriptions and requirements, resource needs, employment needs, waste and emissions from plant, hazards discussion, and intersite transportation.

NONE

1995-09-01T23:59:59.000Z

143

Decomposition method for the Multiperiod Blending Problem  

E-Print Network [OSTI]

· Flows between which tanks in which time periods · Inventories/concentrations for tanks in each period for many applications 4 · Gasoline and crude oil blending · Raw material feed scheduling · Storage. "no bounds" on concentration total inventory mass balance in tanks inventory mass balance by component

Grossmann, Ignacio E.

144

Decomposition method for the Multiperiod Blending Problem  

E-Print Network [OSTI]

problem is a general model for many applications, and it is difficult to solve · Gasoline and crude oil tanks in which time periods · Inventories/concentrations for tanks in each period · Maximum total profit total inventory mass balance in tanks inventory mass balance by component in blending tanks

Grossmann, Ignacio E.

145

BIODIESEL BLENDS IN SPACE HEATING EQUIPMENT.  

SciTech Connect (OSTI)

Biodiesel is a diesel-like fuel that is derived from processing vegetable oils from various sources, such as soy oil, rapeseed or canola oil, and also waste vegetable oils resulting from cooking use. Brookhaven National laboratory initiated an evaluation of the performance of blends of biodiesel and home heating oil in space heating applications under the sponsorship of the Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL). This report is a result of this work performed in the laboratory. A number of blends of varying amounts of a biodiesel in home heating fuel were tested in both a residential heating system and a commercial size boiler. The results demonstrate that blends of biodiesel and heating oil can be used with few or no modifications to the equipment or operating practices in space heating. The results also showed that there were environmental benefits from the biodiesel addition in terms of reductions in smoke and in Nitrogen Oxides (NOx). The latter result was particularly surprising and of course welcome, in view of the previous results in diesel engines where no changes had been seen. Residential size combustion equipment is presently not subject to NOx regulation. If reductions in NOx similar to those observed here hold up in larger size (commercial and industrial) boilers, a significant increase in the use of biodiesel-like fuel blends could become possible.

KRISHNA,C.R.

2001-12-01T23:59:59.000Z

146

Exciting careers blending engineering, science, and ecology  

E-Print Network [OSTI]

Exciting careers blending engineering, science, and ecology New Opportunities Making the world://bee.oregonstate.edu/ecoe Ecological Engineering is: · Ecosystem restoration and habitat design at multiple scales · Watershed · Phytoremediation and bioremediation · Industrial ecology · Constructed wetlands and tidal marshlands · Mitigation

Tullos, Desiree

147

Table S1. Fuel Properties. JP-8 Blend-1 FT-1 Blend-2 FT-2  

E-Print Network [OSTI]

58 45 51 H Content (% mass) 13.6 14.5 15.5 14.3 15.1 Heat of Combust. (MJ/kg) 43.3 43.8 44.4 43.8 441 Table S1. Fuel Properties. JP-8 Blend-1 FT-1 Blend-2 FT-2 Feedstock Petroleum Petroleum & Natural Gas Natural Gas Petroleum & Coal Coal Sulfur (ppm by mass) 1148 699 19 658 22 Alkanes (% vol.) 50

Meskhidze, Nicholas

148

Alternative Fuels Data Center: Supply of Petroleum Products for Blending  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Supply of Petroleum Supply of Petroleum Products for Blending with Biofuels to someone by E-mail Share Alternative Fuels Data Center: Supply of Petroleum Products for Blending with Biofuels on Facebook Tweet about Alternative Fuels Data Center: Supply of Petroleum Products for Blending with Biofuels on Twitter Bookmark Alternative Fuels Data Center: Supply of Petroleum Products for Blending with Biofuels on Google Bookmark Alternative Fuels Data Center: Supply of Petroleum Products for Blending with Biofuels on Delicious Rank Alternative Fuels Data Center: Supply of Petroleum Products for Blending with Biofuels on Digg Find More places to share Alternative Fuels Data Center: Supply of Petroleum Products for Blending with Biofuels on AddThis.com... More in this section... Federal

149

Kinetic mechanism of dimethyl ether production process using syngas from integrated gasification combined cycle power plant  

Science Journals Connector (OSTI)

In a 1-step synthesis gas-to-dimethyl ether process, synthesis gas is converted into dimethyl ether (DME) in a single reactor. Three reactions are involved in this process: methanol synthesis, methanol dehydra...

Hee-Woo Park; Jin-Kuk Ha; Euy Soo Lee

2014-07-01T23:59:59.000Z

150

Hydrogen Generation from Dimethyl Ether for Fuel Cell Auxiliary Power Units  

Science Journals Connector (OSTI)

Hydrogen Generation from Dimethyl Ether for Fuel Cell Auxiliary Power Units ... Vehicle manufacturers are rushing ahead with research into alternative fuels such as dimethyl ether (DME), biodiesel, methanol, ethanol, and hydrogen. ...

Marita Nilsson; Lars J. Pettersson; Bård Lindström

2006-07-29T23:59:59.000Z

151

Effects of simulant mixed waste on EPDM and butyl rubber  

SciTech Connect (OSTI)

The authors have developed a Chemical Compatibility Testing Program for the evaluation of plastic packaging components which may be used in transporting mixed waste forms. In this program, they have screened 10 plastic materials in four liquid mixed waste simulants. These plastics were butadiene-acrylonitrile copolymer (Nitrile) rubber, cross-linked polyethylene, epichlorohydrin rubber, ethylene-propylene (EPDM) rubber, fluorocarbons (Viton and Kel-F{trademark}), polytetrafluoro-ethylene (Teflon), high-density polyethylene, isobutylene-isoprene copolymer (Butyl) rubber, polypropylene, and styrene-butadiene (SBR) rubber. The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; and (4) a mixture of ketones. The screening testing protocol involved exposing the respective materials to approximately 3 kGy of gamma radiation followed by 14-day exposures to the waste simulants at 60 C. The rubber materials or elastomers were tested using Vapor Transport Rate measurements while the liner materials were tested using specific gravity as a metric. The authors have developed a chemical compatibility program for the evaluation of plastic packaging components which may be incorporated in packaging for transporting mixed waste forms. From the data analyses performed to date, they have identified the thermoplastic, polychlorotrifluoroethylene, as having the greatest chemical compatibility after having been exposed to gamma radiation followed by exposure to the Hanford Tank simulant mixed waste. The most striking observation from this study was the poor performance of polytetrafluoroethylene under these conditions. In the evaluation of the two elastomeric materials they have concluded that while both materials exhibit remarkable resistance to these environmental conditions, EPDM has a greater resistance to this corrosive simulant mixed waste.

Nigrey, P.J.; Dickens, T.G.

1997-11-01T23:59:59.000Z

152

RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE  

E-Print Network [OSTI]

AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

153

Role of Volatilization in Changing TBA and MTBE Concentrations at  

E-Print Network [OSTI]

a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

154

Water Research 37 (2003) 37563766 Seasonal and daily variations in concentrations of methyl-  

E-Print Network [OSTI]

by volume to gasoline from November to February, and blending 11% MTBE by volume during the rest of the year; accepted 24 March 2003 Abstract Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE

Toran, Laura

155

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

2003-01-01T23:59:59.000Z

156

Vehicle Technologies Office: Effects of Intermediate Ethanol Blends on  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Effects of Intermediate Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 to someone by E-mail Share Vehicle Technologies Office: Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 on Facebook Tweet about Vehicle Technologies Office: Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 on Twitter Bookmark Vehicle Technologies Office: Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 on Google Bookmark Vehicle Technologies Office: Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 on Delicious Rank Vehicle Technologies Office: Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 on Digg

157

Fact Sheet: Effects of Intermediate Ethanol Blends | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Effects of Intermediate Ethanol Blends Effects of Intermediate Ethanol Blends Fact Sheet: Effects of Intermediate Ethanol Blends October 7, 2008 - 4:14pm Addthis In August 2007, the U.S. Department of Energy (DOE) initiated a test program to assess the potential impacts of higher intermediate ethanol blends on conventional vehicles and other engines that rely on gasoline. The test program focuses specifically on the effects of intermediate blends of E15 and E20-gasoline blended with 15 and 20 percent ethanol, respectively-on emissions, catalyst and engine durability, drivability or operability, and materials associated with these vehicles and engines. This DOE test program includes technical expertise from DOE's National Renewable Energy Laboratory (NREL) and Oak Ridge National Laboratory.

158

Report on intermediate ethanol blends research published | ornl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Final report on intermediate ethanol blends research published February 01, 2012 Mileage accumulation dynamometers at subcontractor facilities were used to "age" many of the...

159

Water Content in Biodiesel, Diesel, and Biodiesel–Diesel Blends  

Science Journals Connector (OSTI)

Water Content in Biodiesel, Diesel, and Biodiesel–Diesel Blends ... In what concerns road transportation, biodiesel is being considered a good alternative to conventional diesels. ...

Patricia Bogalhos Lucente Fregolente; Leonardo Vasconcelos Fregolente; Maria Regina Wolf Maciel

2012-05-17T23:59:59.000Z

160

Heavy Alcohols as a Fuel Blending Agent for Compression Ignition...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Applications Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations p-21ramirez.pdf More Documents & Publications HD...

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Meet changing fuel requirements with online blend optimization  

SciTech Connect (OSTI)

Compania Espanola de Petroleos (CEPSA) embarked on an overall refinery automation program, with state-of-the-art gasoline blending being one of the highest priorities. The result of this effort is a sophisticated computerized gasoline blending system using offline LPs for initial optimal recipe calculation, an online LP for real-time blend recipe reformulation using online analyzers for blending model adjustment, complete automation of blending sequence startup and shutdown, generation of end of blend quality performance reports, and real-time integration between lab, tank gauging, plant information, and blending systems. The entry of Spain in the EEC brought with it the need to quickly adapt to the requirements of an openly competitive marketplace emphasizing no lead, oxygenated, high performance gasolines and ISO 9000 quality standards. The blending system allowed CEPSA to produce lowest cost, minimum giveaway gasolines, while having the flexibility to produce a wide variety of modern gasolines serving the Western European market. The paper describes the blender architecture, optimizer linear programming, man machine interface, and results from the blending system.

Diaz, A. [Compania Espanola de Petroleos, S.A., Cadiz (Spain). Algeciras Refinery; Barsamian, J.A. [ABB Simcon Inc., Bloomfield, NJ (United States)

1996-02-01T23:59:59.000Z

162

Properties, performance and emissions of biofuels in blends with gasoline.  

E-Print Network [OSTI]

??The emission performance of fuels and their blends in modern combustion systems have been studied with the purpose of reducing regulated and unregulated emissions, understanding… (more)

Eslami, Farshad

2013-01-01T23:59:59.000Z

163

HASKELL & WHITE CORPORATEREPORTING & GOVERNANCE CONFERENCE SERIES Blending Theory with Practice  

E-Print Network [OSTI]

HASKELL & WHITE CORPORATEREPORTING & GOVERNANCE CONFERENCE SERIES Blending Theory with Practice The 13th Haskell & White Corporate Reporting & Governance conference is intended to provide opportunities

de Lijser, Peter

164

Purification Testing for HEU Blend Program  

SciTech Connect (OSTI)

The Savannah River Site (SRS) is working to dispose of the inventory of enriched uranium (EU) formerly used to make fuel for production reactors. The Tennessee Valley Authority (TVA) has agreed to take the material after blending the EU with either natural or depleted uranium to give a {sup 235}U concentration of 4.8 percent low-enriched uranium will be fabricated by a vendor into reactor fuel for use in TVA reactors. SRS prefers to blend the EU with existing depleted uranium (DU) solutions, however, the impurity concentrations in the DU and EU are so high that the blended material may not meet specifications agreed to with TVA. The principal non-radioactive impurities of concern are carbon, iron, phosphorus and sulfur. Neptunium and plutonium contamination levels are about 40 times greater than the desired specification. Tests of solvent extraction and fuel preparation with solutions of SRS uranium demonstrate that the UO{sub 2} prepared from these solutions will meet specifications for Fe, P and S, but may not meet the specifications for carbon. The reasons for carbon remaining in the oxide at such high levels is not fully understood, but may be overcome either by treatment of the solutions with activated carbon or heating the UO{sub 3} in air for a longer time during the calcination step of fuel preparation.Calculations of the expected removal of Np and Pu from the solutions show that the specification cannot be met with a single cycle of solvent extraction. The only way to ensure meeting the specification is dilution with natural U which contains no Np or Pu. Estimations of the decontamination from fission products and daughter products in the decay chains for the U isotopes show that the specification of 110 MEV Bq/g U can be met as long as the activities of the daughters of U- 235 and U-238 are excluded from the specification.

Thompson, M.C. [Westinghouse Savannah River Company, AIKEN, SC (United States); Pierce, R.A.

1998-06-01T23:59:59.000Z

165

Synthesis of grafted polyamide/polyglutarimide blends  

SciTech Connect (OSTI)

Polyglutarimides are high Tg thermoplastics, prepared by a reactive extrusion process involving polymethylmethacrylate and primary amines in a plasticating extruder at high pressures and temperatures. The resulting polymers can be synthesized with various levels of carboxylic acid and/or anhydride functionality as part of the polyglutarimide polymer. In a recent discovery, these polymers can be grafted to polyamides in a highly efficient manner by means of a reactive extrusion process. This talk will discuss the synthesis of these blends and techniques for their analysis. Partial fractionation, and spectroscopic analysis of these materials was used to monitor the reaction. The effects of extrusion temperature and catalyst level will be presented.

Hallden-Abberton, M. [Rohm and Haas Corp., Bristol, PA (United States)

1993-12-31T23:59:59.000Z

166

California's Move Toward E10 (released in AEO2009)  

Reports and Publications (EIA)

In Annual Energy Outlook 2009, (AEO) E10–a gasoline blend containing 10% ethanol–is assumed to be the maximum ethanol blend allowed in California erformulated gasoline (RFG), as opposed to the 5.7% blend assumed in earlier AEOs. The 5.7% blend had reflected decisions made when California decided to phase out use of the additive methyl tertiary butyl ether in its RFG program in 2003, opting instead to use ethanol in the minimum amount that would meet the requirement for 2.0% oxygen content under the Clean Air Act provisions in effect at that time.

2009-01-01T23:59:59.000Z

167

Synthesis of Medium Ring Ethers. 5. The Synthesis of (+)-Laurencin  

Science Journals Connector (OSTI)

The eight-membered medium ring ether natural product (+)-laurencin 1 is the prototypical member of a growing family of marine natural product cyclic ethers isolated from red algae and those marine organisms which feed on Laurencia species. ... The reaction mixture immediately became yellow and gradually turned dark red as gas was evolved. ... We thank the Engineering and Physical Sciences Research Council (EPSRC) UK for a research grant, Pfizer Central Research, and Corpus Christi College Cambridge for the award of a studentship and a Junior Research Fellow ship (J.W.B.), the Cambridge European Overseas Trust, Ciba (Novartis) and the Swiss Foundation for Gifted Students (scholarship to S.D.), and the Commission of the European Communities (TMR award to T.C.S.) for generous financial support. ...

Jonathan W. Burton; J. Stephen Clark; Sam Derrer; Thomas C. Stork; Justin G. Bendall; Andrew B. Holmes

1997-08-13T23:59:59.000Z

168

The Impact of Low Octane Hydrocarbon Blending Streams on "E85...  

Broader source: Energy.gov (indexed) [DOE]

Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization deer12szybist.pdf More Documents &...

169

Proton NMR characterization of gasoline–ethanol blends  

Science Journals Connector (OSTI)

Abstract Nuclear magnetic resonance (NMR) can be conveniently used for accurate measurement of water and ethanol concentrations in gasoline–ethanol fuel blends. The spectra also contain information on proton exchange rates. In addition, NMR pulsed-field-gradient diffusion measurement allows estimation of ethanol–water clusters and viscosity of the fuel blends.

A. Turanov; A.K. Khitrin

2014-01-01T23:59:59.000Z

170

Effect of Ethanol on Blending Stability and Diesel Engine Emissions  

Science Journals Connector (OSTI)

Effect of Ethanol on Blending Stability and Diesel Engine Emissions ... Industrial & Engineering Chemistry Research2013 52 (44), 15504-15508 ... This article describes the effects of hydroxylated biodiesel (castor oil methyl ester – COME) on the properties, combustion, and emissions of butanol–diesel blends used within compression ignition engines. ...

Magín Lapuerta; Octavio Armas; Reyes García-Contreras

2009-07-28T23:59:59.000Z

171

Blend lines in the polarized spectrum of the Sun  

Science Journals Connector (OSTI)

......July 2012 research-article Papers Blend lines in the polarized spectrum of the Sun K...Astrophysics, Bangalore 560034, India Blend lines form an integral part of the theoretical...Their interaction with other spectral lines needs to be explored and understood before......

K. Sowmya; K. N. Nagendra; M. Sampoorna

2012-07-01T23:59:59.000Z

172

First International Conference on E-Learning and Blended Education  

E-Print Network [OSTI]

at the conference will appear in its proceedings. The Conference's academic committee will also select some highFirst International Conference on E-Learning and Blended Education as a Strategic Choice for Arab Universities ICELBE 2012 : 13­11 ()2112 #12;First International Conference on E-Learning and Blended

173

Blended language learning in tertiary education  

Science Journals Connector (OSTI)

This paper examines the supporting and enhancing role of technology in language learning and teaching in a higher education institution in Slovenia. Despite the fact that the vast majority of foreign language teaching is still carried out in face-to-face environments, a growing extent of foreign language teaching in a number of tertiary education institutions has moved, at least partly, online. In this paper, the development of e-learning practices in Slovenia is described first, together with the evolution of computer technologies – from multimedia to the internet – and their potential for language learning and teaching purposes. Against this background, the practical application of the Blended Language Learning (BLL) experience at the Faculty of Management Koper is discussed. The paper also addresses the changing role of teachers in blended language teaching/learning environments and analyses the opinions of students who participated in a combination of Face-to-Face (F2F) and Computer-Assisted Language Learning (CALL) courses and expressed their opinions on the BLL experience in a questionnaire.

Igor Riznar

2009-01-01T23:59:59.000Z

174

Dimethyl Ether Autoignition at Engine-Relevant Conditions  

Science Journals Connector (OSTI)

† Key Laboratory for Power Machinery and Engineering of M.O.E., Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China ... The autoignition of dimethyl ether (DME), an alternative diesel engine fuel, has been studied at elevated pressures. ... In addition to studies aimed at ascertaining the performance of compression–ignition internal combustion engines fuel with DME,(2, 3) there have been a number of studies focused on experimental characterization of fundamental combustion properties for DME. ...

Zhenhua Li; Weijing Wang; Zhen Huang; Matthew A. Oehlschlaeger

2013-04-01T23:59:59.000Z

175

2' and 3' Carboranyl uridines and their diethyl ether adducts  

DOE Patents [OSTI]

There is disclosed a process for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. Said carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of said compounds in methods for boron neutron capture therapy in mammalian tumor cells.

Soloway, Albert H. (Worthington, OH); Barth, Rolf F. (Columbus, OH); Anisuzzaman, Abul K. (Columbus, OH); Alam, Fazlul (Anaheim, CA); Tjarks, Werner (Columbus, OH)

1992-01-01T23:59:59.000Z

176

Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water  

E-Print Network [OSTI]

Dipalladiumtris(dibenzylideneacetone)/tris(tert-butyl)phosphonium tetrafluoroborate/potassium fluoride dihydrate [Pd2(dba)3/[HP(t-Bu)3]BF4/KF?2?H2O] serves as a mild, robust, and user-friendly method for the efficient ...

Lou, Sha

177

The interactions of water and perfluorodiethyl ether on Ru(100)  

SciTech Connect (OSTI)

We have studied the interactions of water and perfluorodiethyl ether on Ru(100) in order to model the effects of surface structure and humidity on the bonding and decomposition of perfluoroalkyl ether lubricants with metal surfaces. In order to understand the interactions on Ru(100), we have first investigated the interactions of each of these adsorbates alone on the clean surface. The interactions of water with Ru(100) have been studied using both thermal desorption spectroscopy (TDS) and electron energy loss spectroscopy (EELS). From these studies we conclude that a small amount of water dissociates on this surface (5--10% of a monolayer), but water is adsorbed in a predominantly molecular form on this surface with an increasing degree of hydrogen-bonding with increasing coverage. The effects of hydrogen and oxygen coadsorption on the interactions of water with this surface have also been studied using TDS. Finally, the interactions of coadsorbed water and perfluorodiethyl ether on Ru(100) have been investigated using TDS.

Leavitt, P.

1990-09-21T23:59:59.000Z

178

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Imports & Exports Imports & Exports Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Barrel A unit of volume equal to 42 U.S. gallons. Conventional Blendstock for Oxygenate Blending (CBOB) Motor gasoline blending components intended for blending with oxygenates to produce finished conventional motor gasoline. Conventional Gasoline Finished motor gasoline not included in the oxygenated or reformulated gasoline categories. Excludes reformulated gasoline blendstock for oxygenate blending (RBOB) as well as other blendstock.

179

Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis  

SciTech Connect (OSTI)

The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

T.A. Semelsberger

2004-10-01T23:59:59.000Z

180

E-Print Network 3.0 - allyl glycidyl ether Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science 15 () Trichloromethane ()1,1,2,2-1,1,2,2-Tetrachloroethane Summary: ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

POLYCHLORINATED BIPHENYLS AND POLYBROMINATED DIPHENYL ETHERS IN GALAPAGOS SEA LIONS (ZALOPHUS WOLLEBAEKI)  

E-Print Network [OSTI]

), polybrominated diphenyl ethers (PBDEs), polychlorinated dibenzo-p- dioxins (PCDDs), and polychlorinated dibenzo-p-dioxins (PCDDs), and polychlorinated dibenzofurans (PCDFs) repre- sent persistent

Gobas, Frank

182

Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Alternative Fuels lDimethyl Ether Rheology and Materials Studies Liquid Fuels from Biomass BiodieselFuelManagementBestPracticesReport.pdf...

183

Differences in the Physical Characteristics of Diesel PM with Increasing Biofuel Blend Level  

Broader source: Energy.gov [DOE]

Measure physical characteristics, carbon state, and surface bound oxygen of soot from biodiesel blends.

184

Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications  

Broader source: Energy.gov [DOE]

Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations

185

Polybrominated diphenyl ether flame retardants in the antarctic environment  

E-Print Network [OSTI]

, the historical record of dioxins, PCBs and DDTs in the same cores showed a decreasing trend. At present, PBDEs are recognized as a worldwide pollution problem since they have reached remote areas such as the deep ocean, the Arctic and Antarctica (de Boer et al... that cheerful and warm Brazilian spirit. You are my Aggie family! viii NOMENCLATURE #1; critical value of a statistical test used to reject the null hypothesis ANOVA Analysis of Variance BDE Brominated Diphenyl Ether BFR Brominated Flame Retardant DC...

Yogui, Gilvan Takeshi

2009-05-15T23:59:59.000Z

186

Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

New New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) to someone by E-mail Share Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) on Facebook Tweet about Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) on Twitter Bookmark Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) on Google Bookmark Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing

187

Extraction of Plutonium into 30 Percent Tri-Butyl Phosphate from Nitric Acid Solution Containing Fluoride, Aluminum, and Boron  

SciTech Connect (OSTI)

This work consists of experimental batch extraction data for plutonium into 30 volume-percent tri-butyl phosphate at ambient temperature from such a solution matrix and a model of this data using complexation constants from the literature.

Kyser, E.A.

2000-01-06T23:59:59.000Z

188

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO2(111) Model Catalysts  

SciTech Connect (OSTI)

The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

F Calaza; T Chen; D Mullins; S Overbury

2011-12-31T23:59:59.000Z

189

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO(2)(111) Model Catalysts  

SciTech Connect (OSTI)

The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

Calaza, Florencia C [ORNL; Chen, Tsung-Liang [ORNL; Mullins, David R [ORNL; Overbury, Steven {Steve} H [ORNL

2011-01-01T23:59:59.000Z

190

Aging of Weapon Seals – An Update on Butyl O-ring Issues  

SciTech Connect (OSTI)

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings on several programs. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Engineering judgment was that under curing is detrimental and could possibly lead to sub-optimum performance or, in the worst case, premature seal failure. An aging study was undertaken to ensure that suspect o-rings installed in the stockpile will retain sufficient sealing force for a minimum ten-year service life. A new prediction model developed for this study indicates suspect o-rings do not need to be replaced before the ten-year service life. Long-term testing results are reported on a yearly basis to validate the prediction model. This report documents the aging results for the period September 2002 to January 2011.

Wilson, Mark H.

2011-07-13T23:59:59.000Z

191

Conversion and Blending Facility highly enriched uranium to low enriched uranium as metal. Revision 1  

SciTech Connect (OSTI)

The mission of this Conversion and Blending Facility (CBF) will be to blend surplus HEU metal and alloy with depleted uranium metal to produce an LEU product. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The blended LEU will be produced as a waste suitable for storage or disposal.

NONE

1995-07-05T23:59:59.000Z

192

Biodiesel Production and Blending Tax Credit (Kentucky) | Open Energy  

Open Energy Info (EERE)

Production and Blending Tax Credit (Kentucky) Production and Blending Tax Credit (Kentucky) No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Last modified on February 12, 2013. EZFeed Policy Place Kentucky Name Biodiesel Production and Blending Tax Credit (Kentucky) Policy Category Financial Incentive Policy Type Corporate Tax Incentive Affected Technologies Biomass/Biogas Active Policy Yes Implementing Sector State/Province Primary Website http://energy.ky.gov/biofuels/Pages/biofuelsIncentives.aspx Summary blended biodiesel does not qualify. The biodiesel tax credit is applied against the corporation income tax imposed under KRS 141.040 and/or the limited liability entity tax (LLET) imposed under KRS 141.0401. The amount

193

Time phased alternate blending of feed coals for liquefaction  

DOE Patents [OSTI]

The present invention is directed to a method for reducing process performance excursions during feed coal or process solvent changeover in a coal hydroliquefaction process by blending of feedstocks or solvents over time. ,

Schweigharett, Frank (Allentown, PA); Hoover, David S. (New Tripoli, PA); Garg, Diwaker (Macungie, PA)

1985-01-01T23:59:59.000Z

194

Settling of rubber particles in asphalt-rubber blends  

E-Print Network [OSTI]

Traditional asphalt-rubber binders have faced problems ics. in pavement compaction, due to phase separation or sedimentation of undissolved rubber. A homogeneous asphalt-rubber binder is desirable for alleviating this problem. In addition, a blend...

Wattanachai, Piyachat

1998-01-01T23:59:59.000Z

195

Toughened blends of poly(butylene terephthalate) and BPA polycarbonate  

Science Journals Connector (OSTI)

The morphologies of melt blends of poly(butylene terephthalate) (PBT) and bisphenol A polycarbonate (PC) toughened with a core/shell impact modifier have been characterized by transmission and scanning electro...

S. Y. Hobbs; M. E. J. Dekkers; V. H. Watkins

1988-04-01T23:59:59.000Z

196

Toughened blends of poly(butylene terephthalate) and BPA polycarbonate  

Science Journals Connector (OSTI)

The toughening mechanisms of blends of poly(butylene terephthalate) (PBT) and bisphenol-A polycarbonate (PC) toughened with core/shell impact modifier have been studied by transmission electron microscopy, not...

M. E. J. Dekkers; S. Y. Hobbs; V. H. Watkins

1988-04-01T23:59:59.000Z

197

Eco-Friendly Complex Blends into Desert | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Eco-Friendly Complex Blends into Desert Eco-Friendly Complex Blends into Desert Eco-Friendly Complex Blends into Desert October 7, 2010 - 11:58am Addthis Paul Lester Communications Specialist, Office of Energy Efficiency and Renewable Energy What does this project do? Rooftop solar panels provide 27 percent of the facility's energy. Maricopa County officials estimate the complex is 42 percent more energy efficient than many modern day buildings. Next month, hikers marveling at the sun bathed canyons and ridges of White Tank Mountain in the Sonoran Desert will see something on the horizon - if they look hard. Built to blend into the desert landscape, the new 29,000 square-foot White Tank Library and Nature Center in Surprise, Ariz., is set to open on Nov. 13. Rooftop solar panels provide 27 percent of the facility's energy.

198

Reverse osmosis performance with solutions containing tri-n-butyl phosphate  

SciTech Connect (OSTI)

Tests were conducted to determine whether the reverse osmosis (RO) units at the F/H Effluent Treatment Facility (ETF) at the Savannah River could be made to process solutions containing tri-n-butyl phosphate (TBP). It was desired to test whether operation at a feed pH other than neutral would improve performance. Test results are discussed in this report and indicate that little improvement in the water flux can be expected at other pH values.

Siler, J.L.

1991-10-22T23:59:59.000Z

199

Batch polymerization of styrene initiated by n-butyl lithium in a cyclohexane solvent  

E-Print Network [OSTI]

anionic mechanism. A mathematical model is de- veloped and the predicted values are compared with their corresponding experimental values. Initiator and monomer concentrations are varied and their conversion time profiles are studied. A G&el... and Storage Vessels Purification of Monomer Purification of Solvent Polymerization Reaction Scavenger Level Analysis o f Butyl Lithium Analysis of Molecular Weight Distributions by the Use of Gel Permeation Technique 10 19 19 ZO Zl ZZ 24 25 25...

Landon, Thomas Rodman

1971-01-01T23:59:59.000Z

200

Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis  

E-Print Network [OSTI]

1 Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis of Single-phase thermal decomposition of ethanol and dimethyl ether (DME) at typical SWNT growth conditions using to the predicted decomposition mechanism. Signature peak intensities indicated concentrations of both ethanol

Maruyama, Shigeo

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Composition and Digestibility of the Ether Extract of Hays and Fodders.  

E-Print Network [OSTI]

556-712-5m TEXAS AGRICULTURAL EXPERIMENT STATIONS. BULLETIN NO . 150 AUGUST , 1912. Division o f Chemistry TECHNICAL BULLETIN Composition and Digestibility of the Ether Extract of Hays and Fodders By G S. FRAPS and J. B. RATHER POSTOFFICE... Digestibility of the Constituents............................................................. 23 Summary and Conclusions.......................................................................29 BLANK PAGE IN ORIGINAL Composition and Digestibility of the Ether...

Fraps, G. S.; Rather, J. B.

1912-01-01T23:59:59.000Z

202

Proton-conducting polymer electrolyte membranes based on fluoropolymers incorporating perfluorovinyl ether sulfonic acids and fluoroalkenes  

E-Print Network [OSTI]

acids. A novel synthetic route describing the preparation of perfluorovinyl ether monomer containing. The radical (co) and terpolymerization of 4-[(,,-trifluorovinyl)oxy]benzene sulfonyl chloride (TFVOBSC) with 1,1-difluoroethylene (or vinylidene fluoride, VDF), hexafluoropropene (HFP), and perfluoromethyl vinyl ether (PMVE

Paris-Sud XI, Université de

203

Modelling the fate of polybrominated diphenyl ethers (PBDEs) during the municipal sewage treatment process  

Science Journals Connector (OSTI)

Sewage treatment plants (STPs) are an important source to the environment for many chemicals of concern (COCs). Polybrominated diphenyl ethers (PBDEs) are one such group of COCs of present day concern for which studies on fate and transport during the ... Keywords: chemical fate and transport, mass balance model, polybrominated diphenyl ethers, risk assessment, sewage treatment, water and wastewater management

Kerry N. McPhedran; Rajesh Seth

2007-08-01T23:59:59.000Z

204

Droplet combustion studies of hydrocarbon-monopropellant blends  

Science Journals Connector (OSTI)

Abstract An experimental investigation was conducted to characterize the monopropellant droplet combustion of pure and blended isopropyl nitrate (IPN), suspended on quartz fibers in a quiescent atmosphere. The blends were prepared by mixing varying percentages by weight of IPN with less viscous n-heptane, as well as highly viscous desensitizer dibutyl sebacate (DBS). Ignition was achieved by using a heated 60 ?m Nichrome wire. The dependence of the burning rate constant of pure IPN on initial droplet diameter was investigated in the droplet size range of 0.79–1.97 mm. The blended IPN studies were carried out with initial droplet diameters of 2 and 1.5 mm for IPN-n-heptane and IPN-DBS blends respectively, to characterize the effect of gravimetric composition. The experiments revealed a strong dependence of IPN burning rate on droplet size. The IPN-DBS blends were characterized by severe micro-explosions, further atomizing the droplet, governed by the preferential evaporation of IPN over DBS. However, micro-explosions were conspicuously absent in case of IPN-n-heptane blends due to simultaneous gasification of both components.

Anirudha Ambekar; Arindrajit Chowdhury; Suryanarayana Challa; D. Radhakrishna

2014-01-01T23:59:59.000Z

205

Morphological studies on block copolymer modified PA 6 blends  

SciTech Connect (OSTI)

Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

Poindl, M., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de [Institut für Kunststofftechnik, University of Stuttgart (Germany)

2014-05-15T23:59:59.000Z

206

Comb-shaped single ion conductors based on polyacrylate ethers and lithium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comb-shaped single ion conductors based on polyacrylate ethers and lithium Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Title Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Publication Type Journal Article Year of Publication 2005 Authors Sun, Xiao-Guang, Jun Hou, and John B. Kerr Journal Electrochimica Acta Volume 50 Pagination 1139-1147 Keywords ionic conductivity, plasticizer, polyacrylate ethers, single ion conductor Abstract Comb-shaped single ion conductors have been synthesized by sulfonation of small molecule chloroethyleneglycols, which, after ion exchange to the Li+ salt were then converted to the acrylate by reaction with acryloyl chloride and copolymerized with polyethylene glycol monomethyl ether acrylate (Mn = 454, n = 8) (PAE8-co-E3SO3Li);

207

Kinetic measurements of the gas-phase reactions of OH radicals with hydroxy ethers, hydroxy ketones, and keto ethers  

SciTech Connect (OSTI)

Absolute rate constants were determined for the gas-phase reactions of hydroxyl radicals with a series of hydroxy ethers as well as the simplest hydroxy ketone and keto ether with use of the flash photolysis resonance fluorescence technique. At 298 K, the measured rate constants were as follows (in units of 10{sup {minus}12} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}): 2-methoxyethanol, 12.5 {plus minus} 0.7; 2-ethoxyethanol, 18.7 {plus minus} 2.0; 2-butoxyethanol, 23.1 {plus minus} 0.9; 3-ethoxy-1-propanol, 22.0 {plus minus} 1.3; 3-methoxy-l-butanol, 23.6 {plus minus} 1.6; acetol, 3.0 {plus minus} 0.3; and methoxyacetone, 6.8 {plus minus} 0.6. The kinetic data for 2-methoxyethanol obtained between 240 and 440 K were used to derive the following Arrhenius expression: k{sub 1} = (4.5 {plus minus} 1.4) {times} 10{sup {minus}12} exp((325 {plus minus} 100)/T) (cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}). The results for all seven reactants are discussed in terms of the prediction of OH rate constants for oxygenated organic compounds.

Dagaut, P.; Liu, R.; Wallington, T.J.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1989-11-16T23:59:59.000Z

208

Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002  

SciTech Connect (OSTI)

Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R. [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)] [Savannah River National Laboratory, Aiken. S.C., 29808 (United States)

2013-07-01T23:59:59.000Z

209

Blending Of Radioactive Salt Solutions In Million Gallon Tanks  

SciTech Connect (OSTI)

Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

2012-12-10T23:59:59.000Z

210

Test of Orientation/Stretch-Induced Reduction of Friction via Primitive Chain Network Simulations for Polystyrene, Polyisoprene, and Poly(n-butyl acrylate)  

Science Journals Connector (OSTI)

Test of Orientation/Stretch-Induced Reduction of Friction via Primitive Chain Network Simulations for Polystyrene, Polyisoprene, and Poly(n-butyl acrylate) ...

Yuichi Masubuchi; Yumi Matsumiya; Hiroshi Watanabe

2014-09-24T23:59:59.000Z

211

Synthesis and Evaluation of 3',5'-Di-tert-butyl-4'-hydroxyflavones as Potential Inhibitors of Low Density Lipoprotein (LDL) Oxidation  

Science Journals Connector (OSTI)

Synthesis and Evaluation of 3',5'-Di-tert-butyl-4'-hydroxyflavones as Potential Inhibitors of Low Density Lipoprotein (LDL) Oxidation ...

Guy Lewin; Yves Rolland; Sylvie Privat; Christine Breugnot; Albert Lenaers; Jean Paul Vilaine; Jean-Pierre Baltaze; Jacques Poisson

1995-12-01T23:59:59.000Z

212

Batch polymerization of styrene and isoprene by n-butyl lithium initiator  

E-Print Network [OSTI]

-20). Analysis of products consists of determining the point at which no free lithium alkyl remains. Thus if a butyl lithium initiated polymerization were terminated with water, butane would be evolved as long as the initiator were present. The butane...? agent were evaporated under a hood. Finally the polymer. was dried in a vacuum oven at about 50'C and under a vacuum of 30 inches of gg for about 30 hours. The weight of polymer formed was determined by final weighing. 25 The monomer conversion...

Hasan, Sayeed

1970-01-01T23:59:59.000Z

213

Isobaric vapor-liquid equilibria in the system methyl propanoate + n-butyl alcohol  

SciTech Connect (OSTI)

Isobaric vapor-liquid equilibria were determined at 74.66, 101.32, and 127.99 kPa for binary mixtures containing methyl propanoate + n-butyl alcohol by using a dynamic still with vapor and liquid circulation. No azeotrope was detected. The data were found to be thermodynamically consistent according to the point to point test. Application of the group-contribution models ASOG, UNIFAC, and modified UNIFAC to the activity coefficients at the three pressures studied gives average errors of less than 10%, 11%, and 3%, respectively.

Susial, P.; Ortega, J. (Univ. de Las Palmas de Gran Canaria, Canary Islands (Spain). Lab. de Termodinamica y Fisicoquimica)

1993-10-01T23:59:59.000Z

214

Certification of alternative aviation fuels and blend components  

SciTech Connect (OSTI)

Aviation turbine engine fuel specifications are governed by ASTM International, formerly known as the American Society for Testing and Materials (ASTM) International, and the British Ministry of Defence (MOD). ASTM D1655 Standard Specification for Aviation Turbine Fuels and MOD Defence Standard 91-91 are the guiding specifications for this fuel throughout most of the world. Both of these documents rely heavily on the vast amount of experience in production and use of turbine engine fuels from conventional sources, such as crude oil, natural gas condensates, heavy oil, shale oil, and oil sands. Turbine engine fuel derived from these resources and meeting the above specifications has properties that are generally considered acceptable for fuels to be used in turbine engines. Alternative and synthetic fuel components are approved for use to blend with conventional turbine engine fuels after considerable testing. ASTM has established a specification for fuels containing synthesized hydrocarbons under D7566, and the MOD has included additional requirements for fuels containing synthetic components under Annex D of DS91-91. New turbine engine fuel additives and blend components need to be evaluated using ASTM D4054, Standard Practice for Qualification and Approval of New Aviation Turbine Fuels and Fuel Additives. This paper discusses these specifications and testing requirements in light of recent literature claiming that some biomass-derived blend components, which have been used to blend in conventional aviation fuel, meet the requirements for aviation turbine fuels as specified by ASTM and the MOD. The 'Table 1' requirements listed in both D1655 and DS91-91 are predicated on the assumption that the feedstocks used to make fuels meeting these requirements are from approved sources. Recent papers have implied that commercial jet fuel can be blended with renewable components that are not hydrocarbons (such as fatty acid methyl esters). These are not allowed blend components for turbine engine fuels as discussed in this paper.

Wilson III, George R. (Southwest Research Institute, 6220 Culebra Road, San Antonio, Texas 78238 (United States)); Edwards, Tim; Corporan, Edwin (United States Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433 (United States)); Freerks, Robert L. (Rentech, Incorporated, 1331 17th Street, Denver, Colorado 80202 (United States))

2013-01-15T23:59:59.000Z

215

Evaluation of Ethanol Blends for PHEVs using Simulation andEngine...  

Broader source: Energy.gov (indexed) [DOE]

Evaluation of Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop Evaluation of Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop 2011 DOE Hydrogen and...

216

Behaviour and effects of alcohol-blended petrol in the subsurface  

Science Journals Connector (OSTI)

...Science of the Total Environment , 339 , 117-126...blends. Biomass and Bioenergy , 33 , 1175-1181...C.A. 2001. A review of the environmental...ethanol-blended gasoline in the environment. A literature review and transport modeling...

Philip Morgan; Simon Firth; Beate Hildenbrand

217

Nanoclay effect on transport properties of thermoplastic polyurethane/polypropylene (TPU/PP) blends  

Science Journals Connector (OSTI)

In this paper the diffusion of water through the nanoclay filled TPU/PP blends was investigated at ... The effect of blend ratio, compatibilisation and nanoclay addition on the transport properties was studied .....

Murugasamy Kannan; S. S. Bhagawan; Sabu Thomas…

2013-07-01T23:59:59.000Z

218

A Review of Chromatographic Characterization Techniques for Biodiesel and Biodiesel Blends  

Science Journals Connector (OSTI)

......determination of the biodiesel content of...blends of biodiesel in conventional...Sciences and Engineering Division...characterization of biodiesel and its blends...addressed. Introduction Biodiesel...commercial fuels. These fuels......

R. E. Pauls

2011-05-01T23:59:59.000Z

219

On-line RVP analysis improves gas blending  

SciTech Connect (OSTI)

New government regulations on gasoline quality are making gasoline blending an increasingly important aspect of refining. The Environmental Protection Agency volatility regulations that establish maximum summertime commercial gasoline volatility levels provide that gasoline Reid Vapor Pressor starting in 1989 may not exceed 10.5, or 9.0 psi. Additionally, beginning in 1992, it may not exceed either 9.0 or 7.8 psi, depending on the area of the country and the month. This article discusses the on-line analysis of gas blending to minimize the volatile organic compounds released to the air.

Lo, P.T. [BP Oil Alliance Refinery, Belle Chasse, LA (United States)

1994-09-01T23:59:59.000Z

220

Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels  

Broader source: Energy.gov [DOE]

Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

E-Print Network 3.0 - acid-labile cholesterol-vinyl ether-peg...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crystallization of Recombinant Crithidia fasciculata Tryparedoxin Summary: of 30% polyethylene glycol monomethyl ether (PEG MME) 2000, 0.1 M TrisHCl, pH 8.2, 1% dimethyl Source:...

222

Polybrominated diphenyl ethers in combusted residues and soils from an open burning site of electronic wastes  

Science Journals Connector (OSTI)

Polybrominated diphenyl ethers (PBDEs) are ubiquitous environmental contaminants due to their extensive use. Combusted residue from electronic waste (e-waste) combustion is one of the contamination sources ... tr...

Qian Luo; Ming Hong Wong; Zijian Wang; Zongwei Cai

2013-08-01T23:59:59.000Z

223

Solvent Effects on Cesium Complexation with Crown Ethers from Liquid to Supercritical Fluids  

SciTech Connect (OSTI)

Nuclear magnetic resonance (NMR) techniques were used to study crown ether-water interactions in solvents of low dielectric constants such as chloroform and carbon tetrachloride. Water forms a 1:1 complex with a number of crown ethers including 12-crown-4, 15-crown-5, 18-crown-6, dicyclohexano-18=crown-6, dicyclohexano-24-crown 8, and dibenzl-24-crown-8 in chloroform. Among these crown ethers, the 18-crown-6-H2 complex has the largest equilibrium constant (K=545) and 97% of the crown is complexed to water in chloroform. Addition of carbon tetrachloride to chloroform lowers the equilibrium constants of the crown-water complexes. The partition coefficients of crown ethers (D=crown in water/crown in solvent) between water and organic solvent also vary with solvent composition.

Chien M. Wai; Anne Rustenholtz; Shaofen Wang; Su-Chen Lee; Jamie Herman; Richard A. Porter

2004-03-15T23:59:59.000Z

224

Total Refinery Net Input of Crude Oil and Petroleum Products  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids Pentanes Plus Liquefied Petroleum Gases Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Conventional MGBC - CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components (net) Alaskan Crude Oil Receipts Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

225

Refinery & Blenders Net Input of Crude Oil  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Reformulated, GTAB MGBC - Conventional MGBC - CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components (net) Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

226

Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines*  

E-Print Network [OSTI]

Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines* Kyung vehicles (FFVs) can operate on a blend of gasoline and ethanol in any concentration of up to 85% ethanol for gasoline-ethanol blends is, thus, necessary for the purpose of air-to-fuel ratio control. In this paper, we

Stefanopoulou, Anna

227

A Fast Spatial Patch Blending Algorithm for Artefact Reduction in Pattern-based Image Inpainting  

E-Print Network [OSTI]

A Fast Spatial Patch Blending Algorithm for Artefact Reduction in Pattern-based Image Inpainting Mar´echal Juin, 14050 Caen/France Figure 1: Illustration of our proposed spatial patch blending propose a fast and generic spatial patch blending technique that can be embedded within any kind

Paris-Sud XI, Université de

228

HEU to LEU Conversion and Blending Facility: UNH blending alternative to produce LEU UNH for commercial use  

SciTech Connect (OSTI)

US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. The nuclear material is converted to a form that is more proliferation-resistant than the original form. Examining options for increasing the proliferation resistance of highly enriched uranium (HEU) is part of this effort. Five technologies for blending HEU will be assessed. This document provides data to be used in the environmental impact analysis for the UNH blending HEU disposition option. Process requirements, resource needs, employment needs, waste/emissions from plant, hazards, accident scenarios, and intersite transportation are discussed.

NONE

1995-09-01T23:59:59.000Z

229

100% Pet coke or pet coke blends combustion  

SciTech Connect (OSTI)

Information is outlined on the combustion of 100 percent petroleum coke or petroleum coke blends. Data are presented on NISCO overviews; fuel (coke) characteristics; delayed coke analysis (1995-96); limestone characteristics/effects; limestone preparation; ash characteristics; vortex finders; agglomerization; and NISCO performance results.

Swindle, D.L.

1996-12-31T23:59:59.000Z

230

Blending world map projections with Flex Projector Bernhard Jennya  

E-Print Network [OSTI]

Projector and then documents the new approaches to projection blending. The integration of the three methods into Flex Projector makes creating new projections simple and easy to control and allows the user.flexprojector.com) is a free, open- source, cross-platform application with a graphical user interface for designing world map

Jenny, Bernhard

231

Fuel and fuel blending components from biomass derived pyrolysis oil  

DOE Patents [OSTI]

A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

2012-12-11T23:59:59.000Z

232

Atmospheric chemistry of automotive fuel additives: Diisopropyl ether  

SciTech Connect (OSTI)

To quantify the atmospheric reactivity of diisopropyl ether (DIPE), we have conducted a study of the kinetics and mechanism of reaction 1: OH + DIPE {r_arrow} products. Kinetic measurements of reaction 1 were made using both relative (at 295 K) and absolute techniques (over the temperature range 240-440 K). Rate data from both techniques can be represented by the following: k{sub 1} = (2.2{sub -0.8}{sup +14}) x 10{sup -12} exp[(445 {plus_minus} 145)/T] cm{sup 3} molecule{sup -1}s{sup -1}. At 298 K, k{sub 1} = 9.8 x 10{sup -12} cm{sup 3} molecule{sup -1}s{sup -1}. The products of the simulated atmospheric oxidation of DIPE were identified using FT-IR spectroscopy; isopropyl acetate and HCHO were the main products. The atmospheric oxidation of DIPE can be represented by i-C{sub 3}H{sub 7}O-i-C{sub 3}H{sub 7} + OH + 2NO {r_arrow} HCHO + i-C{sub 3}H{sub 7}OC(O)CH{sub 3} + HO{sub 2} + 2NO{sub 2}. Our kinetic and mechanistic data were incorporated into a 1-day simulation of atmospheric chemistry to quantify the relative incremental reactivity of DIPE. Results are compared with other oxygenated fuel additives. 30 refs., 9 figs.

Wallington, T.J.; Andino, J.M.; Potts, A.R. [Ford Motor Company, Dearborn, MI (United States)] [and others

1993-01-01T23:59:59.000Z

233

Diesel vehicle performance on unaltered waste soybean oil blended with petroleum fuels  

Science Journals Connector (OSTI)

Interest in using unaltered vegetable oil as a fuel in diesel engines has experienced an increase due to uncertainty in the crude oil market supply and the detrimental effects petroleum fuels have on the environment. Unaltered vegetable oil blended with petroleum fuels is less expensive, uses less energy to produce and is more environmentally friendly compared to petroleum diesel or biodiesel. Here we investigate the engine performance of unaltered waste soybean oil blended with petroleum diesel and kerosene for three vehicles. Five biofuel blends ranging from 15% to 50% oil by volume were tested on a 2006 Jeep Liberty CRD, a 1999 Mercedes E300 and a 1984 Mercedes 300TD. A DynoJet 224x chassis dynamometer was used to test vehicle engine performance for horsepower and torque through a range of RPMs. Results for the Jeep showed a modest decrease in horsepower and torque compared to petroleum diesel ranging from 0.9% for the 15% oil blend to 5.0% lower for the 50% oil blend. However, a 30% oil blend showed statistically better performance (P < 0.05) compared to petroleum diesel. For the 1999 Mercedes, horsepower performance was 1.1% lower for the 15% oil blend to 6.4% lower for the 50% oil blend. Engine performance for a 30% blend was statistically the same (P < 0.05) compare to diesel. Finally, horsepower performance was 1.1% lower for the 15% oil blend to 4.7% lower for the 50% oil blend for the 1984 Mercedes. Overall, the performance on these oil blended fuels was excellent and, on average 1.1% lower than petroleum diesel for blends containing 40% or lower waste soybean oil content. The more significant decrease in power between the 40% and 50% oil blends indicates that oil content in these blended fuels should be no more than 40%.

Eugene P. Wagner; Patrick D. Lambert; Todd M. Moyle; Maura A. Koehle

2013-01-01T23:59:59.000Z

234

HIGH PERFORMANCE BLENDS AND COMPOSITES: PART (I) CLAY AEROGEL/POLYMER COMPOSITES PART (II) MECHANISTIC INVESTIGATION OF COLOR GENERATION IN PET/MXD6 BARRIER BLENDS.  

E-Print Network [OSTI]

??High performance in polymer blends and composites can be achieved through the addition of a strong filler component into a polymer matrix. The overall physical… (more)

Bandi, Suneel A

2006-01-01T23:59:59.000Z

235

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, Terje (East Patchogue, NY)

1984-01-01T23:59:59.000Z

236

Comparative Study on Engine Performance and Diesel Emissions with European Diesel Fuel (DF)?Diethylene Glycol Dimethyl Ether (DGM) and Fischer?Tropsch (FT)?DGM Blends  

Science Journals Connector (OSTI)

† Department of Energy and Process Engineering ... The general picture of the methyl- and methylene-related vibrations in the DF used here confirms the results of the GC analyses; i.e., that the DF resembles a n-alkane-dominated hydrocarbon mixture. ... To investigate influences of fuel design on regulated and non-regulated emissions of heavy-duty diesel engines, a Mercedes-Benz OM 906 Euro 3 engine was run with common diesel fuel (DF), first- and second-generation alternative fuels (Gas-to-liq. ...

Md. Nurun Nabi; Rudolf Schmid; Johan Einar Hustad

2010-03-30T23:59:59.000Z

237

Nonlinear viscoelastic response of carbon black-filled butyl rubber and implications for o-ring aging  

SciTech Connect (OSTI)

Butyl rubber, unfortunately, has pronounced nonlinear viscoelastic behavior, which may be modelled by a separable KBKZ formalism. While these effects seem to have minimal impact on accelerated sealing force measurements, they do severely impact compression set tests. Therefore, a new test is suggested for evaluating field-return o-rings which is free from such confounding effects.

Adolf, D.

1997-11-01T23:59:59.000Z

238

Rate dependent finite deformation stressstrain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl  

E-Print Network [OSTI]

Rate dependent finite deformation stress­strain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl acrylate copolymer S. Deschanel a,*, B.P. Greviskes a , K. Bertoldi a , S dependence a b s t r a c t The large strain deformation behaviors of an ethylene methacrylic acid (EMAA

239

Conversion and Blending Facility highly enriched uranium to low enriched uranium as oxide. Revision 1  

SciTech Connect (OSTI)

This Conversion and Blending Facility (CBF) will have two missions: (1) convert HEU materials into pure HEU oxide and (2) blend the pure HEU oxide with depleted and natural uranium oxide to produce an LWR grade LEU product. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. To the extent practical, the chemical and isotopic concentrations of blended LEU product will be held within the specifications required for LWR fuel. Such blended LEU product will be offered to the United States Enrichment Corporation (USEC) to be sold as feed material to the commercial nuclear industry. Otherwise, blended LEU will be produced as a waste suitable for storage or disposal.

NONE

1995-07-05T23:59:59.000Z

240

Alternative Fuels Data Center: Prohibition of the Sale of Ethanol-Blended  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Prohibition of the Prohibition of the Sale of Ethanol-Blended Gasoline to someone by E-mail Share Alternative Fuels Data Center: Prohibition of the Sale of Ethanol-Blended Gasoline on Facebook Tweet about Alternative Fuels Data Center: Prohibition of the Sale of Ethanol-Blended Gasoline on Twitter Bookmark Alternative Fuels Data Center: Prohibition of the Sale of Ethanol-Blended Gasoline on Google Bookmark Alternative Fuels Data Center: Prohibition of the Sale of Ethanol-Blended Gasoline on Delicious Rank Alternative Fuels Data Center: Prohibition of the Sale of Ethanol-Blended Gasoline on Digg Find More places to share Alternative Fuels Data Center: Prohibition of the Sale of Ethanol-Blended Gasoline on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Review Of Rheology Models For Hanford Waste Blending  

SciTech Connect (OSTI)

The area of rheological property prediction was identified as a technology need in the Hanford Tank Waste - waste feed acceptance initiative area during a series of technical meetings among the national laboratories, Department of Energy-Office of River Protection, and Hanford site contractors. Meacham et al. delivered a technical report in June 2012, RPP-RPT-51652 ''One System Evaluation of Waste Transferred to the Waste Treatment Plant'' that included estimating of single shell tank waste Bingham plastic rheological model constants along with a discussion of the issues inherent in predicting the rheological properties of blended wastes. This report was selected as the basis for moving forward during the technical meetings. The report does not provide an equation for predicting rheological properties of blended waste slurries. The attached technical report gives an independent review of the provided Hanford rheological data, Hanford rheological models for single tank wastes, and Hanford rheology after blending provided in the Meacham report. The attached report also compares Hanford to SRS waste rheology and discusses some SRS rheological model equations for single tank wastes, as well as discussing SRS experience with the blending of waste sludges with aqueous material, other waste sludges, and frit slurries. Some observations of note: Savannah River Site (SRS) waste samples from slurried tanks typically have yield stress >1 Pa at 10 wt.% undissolved solids (UDS), while core samples largely have little or no yield stress at 10 wt.% UDS. This could be due to how the waste has been processed, stored, retrieved, and sampled or simply in the differences in the speciation of the wastes. The equations described in Meacham's report are not recommended for extrapolation to wt.% UDS beyond the available data for several reasons; weak technical basis, insufficient data, and large data scatter. When limited data are available, for example two to three points, the equations are not necessarily satisfactory (justified) for interpolations, due to the number of unknown variables equal the number of known data points, resulting in a coefficient of determination of one. SRS has had some success predicting the rheology of waste blends for similar waste types using rheological properties of the individual wastes and empirical blending viscosity equations. Both the Kendall-Monroe and Olney-Carlson equations were used. High accuracy was not obtained, but predictions were reasonable compared to measured flow curves. Blending SRS processed waste with frit slurry (much larger particles and the source of SRS glass formers) is a different sort of problem than that of two similar slurries of precipitated waste particles. A different approach to rheology prediction has had some success describing the incorporation of large frit particles into waste than the one used for blending two wastes. In this case, the Guth-Simha equation was used. If Hanford waste is found to have significant particles in the >100 ?m diameter range, then it might be necessary to handle those particles differently from broadly distributed waste particles that are primarily <30 ?m in diameter. The following are recommendations for the Hanford tank farms: Investigate the impact of large-scale mixing operations on yield stress for one or more Hanford tanks to see if Hanford waste rheological properties change to become more like SRS waste during both tank retrieval and tank qualification operations; Determine rheological properties of mobilized waste slurries by direct measurement rather than by prediction; Collect and characterize samples during the waste feed qualification process for each campaign; o From single source tanks that feed the qualification tanks; o Blends from the qualification tanks; Predictive rheological models must be used with caution, due to the lack of data to support such models and the utilization of the results that come from these models in making process decisions (e.g. the lack of actual operation experience). As experience is ga

Koopman, D. C.; Stone, M.

2013-09-26T23:59:59.000Z

242

Liquid phase oxidation of thiophene compounds by tert-butyl hydroperoxide  

SciTech Connect (OSTI)

Oxidative instability problems in both shale and petroleum-derived middle distillate fuels are related to the presence of hydroperoxides. Although a good body of knowledge exists concerning the formation of peroxides in the liquid phase, relatively little is known about the reaction/decomposition pathways when other functional groups are present. One of the significant and undesirable problems is the formation of solid deposits which can plug nozzles and filters and coal heat exchanger surfaces. Deposit formation in fuels is triggered by autoxidation reactions and is closely associated with elemental oxygen and/or hydroperoxide concentration. This paper reports on the reaction between a primary autoxidation product, a hydroperoxide, and sulfur compounds of the type present in petroleum-derived middle distillate fuels. Specifically, we examine the t-butyl hydroperoxide oxidation of thiophene, 2, 5-dimethylthiophene, tetrahydrothiophene and benzothiophene in a deaerated model fuel, tetradecane, at 120{degree}C.

Mushrush, G.W.; Watkins, J.M. Jr.; Hazlett, R.N.; Hardy, D.R.; Eaton, H.G. (Naval Research Laboratory, Washington, DC (USA))

1987-08-01T23:59:59.000Z

243

Fuel instability studies; Liquid phase oxidation of tetrahydrothiophene by tert-butyl hydroperoxide  

SciTech Connect (OSTI)

The reactions that lead to fuel instability are the subject of conflicting reports in the literature. Confusion results from the difficulty in relating differences in fuel composition, temperature, surface effects and dissolved oxygen content that comprise the multitude of reported studies. Model studies offer a means by chic the mechanism of an individual reaction can be related to a simple system and then extended to the more complex fuel media. This paper reports a model oxidation study of a species, t-butyl hydroperoxide under mild reaction conditions, 120{degrees}C, in a tetradecane model fuel. The major oxidation product was tetrahydrothiophene sulfoxide from the sulfide and t-butanol from the hydroperoxide. The complete suite of products is reported.

Mushrush, G.W.; Pellenbarg, R.E.; Hazlett, R.N.; Morris, R.E.; Hardy, D.R. (Fuels Section, Code 6180, Naval Research Lab., Washington, DC (US))

1991-01-01T23:59:59.000Z

244

Tests for mutagenic effects of ammoniated glycyrrhizin, butylated hydroxytoluene, and gum arabic in roden germ cells  

SciTech Connect (OSTI)

Ammoniated glycyrrhizin, butylated hydroxytoluene, and gum Arabic are generally recognized as safe (GRAS) substances that are used primarily as additives in foods. These substances were incorporated into rodent diets and fed to male rats and mice for 10 and 8 wk, respectively. The treated male mice and rats were then tested for dominant lethal effects. The mice were also tested for induced heritable translocation. Results of the rat studies indicated a statistically significant dominant lethal effect of each of the compounds tested; however, the biological significance of this response is not known. Results of the mouse dominant lethal and heritable translocation studies, on the other hand, indicated no adverse effects of the compounds tested.

Sheu, C.W.; Cain, K.T.; Rushbrook, C.J.; Jorgenson, T.A.; Generoso, W.M.

1986-01-01T23:59:59.000Z

245

Butyl rubber O-ring seals: Revision of test procedures for stockpile materials  

SciTech Connect (OSTI)

Extensive testing showed little correlation between test slab and O-ring performance. New procedures, comparable to those used with the traditional test slabs, were defined for hardness, compression set, and tensile property testing on sacrificial O-ring specimens. Changes in target performance values were made as needed and were, in one case, tightened to reflect the O-ring performance data. An additional study was carried out on O-ring and slab performance vs cure cycle and showed little sensitivity of material performance to large changes in curing time. Aging and spectra of certain materials indicated that two sets of test slabs from current vendor were accidently made from EPDM rather than butyl rubber. Random testing found no O-rings made from EPDM. As a result, and additional spectroscope test will be added to the product acceptance procedures to verify the type of rubber compound used.

Domeier, L.A.; Wagter, K.R.

1996-12-01T23:59:59.000Z

246

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect (OSTI)

In a review of the safety basis for solvent extraction processes at the Department of Energy's Savannah River Site, a question was raised concerning the safety margin associated with a postulated accident involving a runaway tri-n-butyl phosphate (TBP)/nitric acid reaction due to the inadvertent heating of a tank. The safety margin was based on studies which showed the maximum temperature would not exceed 128 degrees Celsius compared to 130 degrees Celsius, the minimum initiation temperature for runaway reaction established in the 1950's following damaging incidents at the Savannah River and Hanford Sites. The reviewers were concerned the minimum temperature was not conservative since data for solutions containing 20 wt percent dissolved solids showed initiation temperatures at or below 130 degrees Celsius and process solutions normally contain some dissolved solids.

Rudisill, T.S.

2001-09-14T23:59:59.000Z

247

A thermodynamic model of nitric acid extraction by tri-n-butyl phosphate  

SciTech Connect (OSTI)

A thermodynamic model is presented for nitric acid extraction by tri-n-butyl phosphate (TBP). This model is based on the formation of the organic phase species: TBP.HNO/sub 3/ and (TBP)/sub 2/.HNO/sub 3/. The model works successfully at TBP concentrations of 5 to 100 vol% and was found to be effective at predicting the extraction of HNO/sub 3/ from HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ solutions. Within the TBP concentration range of 5 to 30%, a single set of extraction constants was sufficient to fit extraction data. Stoichiometric activity coefficients of nitric acid in HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ mixtures were calculated using a model developed by Bromley.

Chaiko, D.J.; Vandegrift, G.F.

1988-07-01T23:59:59.000Z

248

Cathodic disbondment resistance with reactive ethylene terpolymer blends and composite coatings  

E-Print Network [OSTI]

capability of organo-modified nanoclay offered significantnBA n-butyl acrylate NC natural nanoclay NR natural rubberOC organically modified nanoclay PA6 polyamide 6 (nylon 6)

Love, Corey T.

2008-01-01T23:59:59.000Z

249

Fueling Infrastructure Polymer Materials Compatibility to Ethanol-blended  

Open Energy Info (EERE)

Fueling Infrastructure Polymer Materials Compatibility to Ethanol-blended Fueling Infrastructure Polymer Materials Compatibility to Ethanol-blended Gasoline Dataset Summary Description These data files contain volume, mass, and hardness changes of elastomers and plastics representative exposed to gasoline containing various levels of ethanol. These materials are representative of those used in gasoline fuel storage and dispensing hardware. All values are compared to the original untreated condition. The data sets include results from specimens exposed directly to the fuel liquid and also a set of specimens exposed only to the fuel vapors. Source Mike Kass, Oak Ridge National Laboratory Date Released August 16th, 2012 (2 years ago) Date Updated August 16th, 2012 (2 years ago) Keywords compatibility elastomers ethanol gasoline

250

Application of the distributed activation energy model to blends devolatilisation  

Science Journals Connector (OSTI)

In this study, an investigation was carried out into the thermal behaviour of coal, petcoke and their blend as a generic feedstock in combustion and IGCC plants for energy production. The samples were pyrolysed in a TG analyzer in nitrogen atmosphere (constant flow of 0.0335 m/s) at several heating rates with temperatures ranging from 300 to 1223 K. The distributed activation energy model was applied to study the effects of heating rates on the reactions of single solids. The results obtained were used in the calculation of curves mass loss vs. temperature at more realistic heating rates. The algorithm used to obtain the distribution of reactivities for single solids was successfully implemented to allow the prediction of blends performance.

M.V. Navarro; A. Aranda; T. Garcia; R. Murillo; A.M. Mastral

2008-01-01T23:59:59.000Z

251

Sulfur meter for blending coal at Plant Monroe: Final report  

SciTech Connect (OSTI)

An on-line sulfur analyzer, installed at the Detroit Edison, Monroe Power station, was placed into service and evaluated for coal blending optimization to minimize the cost of complying with changing stack gas sulfur dioxide regulations. The project involved debugging the system which consisted of an /open quotes/as-fired/close quotes/ sampler and nuclear source sulfur analyzer. The system was initially plagued with mechanical and electronic problems ranging from coal flow pluggages to calibration drifts in the analyzer. Considerable efforts were successfully made to make the system reliable and accurate. On-line testing showed a major improvement in control of sulfur dioxide emission rates and fuel blending optimization equivalent to as much as $6 million in fuel costs at the time of the evaluation. 7 refs., 14 figs., 12 tabs.

Trentacosta, S.D.; Yurko, J.O.

1988-04-01T23:59:59.000Z

252

Course redesign for blended learning: modern optics for technical professionals  

Science Journals Connector (OSTI)

Philips Centre for Technical Training (CTT) is responsible for the on-going professional education of scientific staff in Philips Research Laboratories worldwide. This article addresses the ''why'' and ''how'' of an evolution toward more flexible learning at the CTT in which various models for blended learning supported by a web-based course-management system are being piloted and evaluated, and describes one of the courses in more detail. The ''why'' relates to CTT's challenge to give more participants at distant locations access to its courses. The ''how'' has to be appropriate to the very specific situation in which CTT functions the transfer of Philips' highly technical knowledge and experience to relatively small numbers of scientific staff within Philips. This knowledge and experience is being refreshed continuously so the contents of the learning also are in steady change. The blended learning models evolving at the CTT are grounded in these characteristics.

Betty Collis; Huib Bruijstens; Jan Kees van der Veen

2003-01-01T23:59:59.000Z

253

Effect of n-Butanol Blending with a Blend of Diesel and Biodiesel on Performance and Exhaust Emissions of a Diesel Engine  

Science Journals Connector (OSTI)

Effect of n-Butanol Blending with a Blend of Diesel and Biodiesel on Performance and Exhaust Emissions of a Diesel Engine ... Mechanical Engineering, Batman University, Batman 72100, Turkey ... Diesel engines are widely used for transportation, energy production, and agricultural and industrial applications because of their high fuel conversion efficiencies and durability. ...

S?ehmus Altun; Cengiz O?ner; Fevzi Yas?ar; Hamit Adin

2011-06-22T23:59:59.000Z

254

Achieving High Chilled Water Delta T Without Blending Station  

E-Print Network [OSTI]

Achieving High Chilled Water Delta T without Blending Station Zhan Wang, Gang Wang, Ke Xu, Yuebin Yu and Mingsheng Liu Energy System Laboratory, Department of Architectural Engineering University of Nebraska-Lincoln, Omaha, NE 68182, USA...-12?C) after all 3-way control valves in the system were converted to 2-way valves. It seems that the use of 3-way control valves is accused of the lower chilled water temperature differential. Wang [2006] investigated the cooling coil performance...

Wang, Z.; Wang, G.; Xu, K.; Yu, Y.; Liu, M.

2007-01-01T23:59:59.000Z

255

Properties and Performance of Levulinate Esters as Diesel Blend Components  

Science Journals Connector (OSTI)

The esters were treated with the cetane-enhancing compound 2-ethyl hexyl nitrate and were tested as blends with diesel fuel in a 2008 model year Cummins ISB engine with the measurement of regulated pollutant emissions over the federal heavy duty diesel transient cycle. ... The various approaches to biomass conversion can be divided into two general types: thermochemical (gasification, pyrolysis, acid hydrolysis, combustion, and liquefaction) and biochemical (fermentation, enzymatic hydrolysis, and anaerobic and aerobic digestion). ...

Earl Christensen; Aaron Williams; Stephen Paul; Steve Burton; Robert L. McCormick

2011-10-05T23:59:59.000Z

256

Ab initio calculations of various protonation sites in perfluorodiethyl ether: Models for high temperature lubricant decomposition?  

SciTech Connect (OSTI)

Although perfluoropolyether (PFPE) lubricants have found successful application in spacecraft mechanisms and computer hard drives, there eventual breakdown is irksome, and the mechanism of decomposition is the subject of much scrutiny. However, very little notice is taken of the monomer ethers on which the polymer lubricants are based. Recently, concerted studies of the Lewis base properties of various fluorinated ethers have been performed, both from an experimental and a theoretical viewpoint. As an extension of the theoretical work, this study presents ab initio theoretical consideration of the multiple potential basic sites within perfluorodiethyl ether, (CF{sub 3}CF{sub 2}){sub 2}O, by way of the proton affinity of the molecule at various possible protonation sites (i.e., oxygen and fluorine atoms). The results indicate that although protonation at the oxygen is more energetically favored, protonation at the fluorine is not much higher in energy and provides for formation of an excellent leaving group, HF.

Ball, D.W. [Cleveland State Univ., OH (United States). Dept. of Chemistry

1995-04-01T23:59:59.000Z

257

Catalyst system and process for benzyl ether fragmentation and coal liquefaction  

DOE Patents [OSTI]

Dibenzyl ether can be readily cleaved to form primarily benzaldehyde and toluene as products, along with minor amounts of bibenzyl and benzyl benzoate, in the presence of a catalyst system comprising a Group 6 metal, preferably molybdenum, a salt, and an organic halide. Although useful synthetically for the cleavage of benzyl ethers, this cleavage also represents a key model reaction for the liquefaction of coal; thus this catalyst system and process should be useful in coal liquefaction with the advantage of operating at significantly lower temperatures and pressures.

Zoeller, Joseph Robert (Kingsport, TN)

1998-04-28T23:59:59.000Z

258

The Total Fatty Acids and Other Ether-Soluable Constituents of Feedstuffs.  

E-Print Network [OSTI]

586-914-10m TEXAS AGRICULTURAL EXPERIMENT STATION BULLETIN NO. 169 SEPTEMBER, 19I4 DIVISION OF CHEMISTRY The Total Fatty Acids and Other Ether-Soluble Constituents of Feedstuffs BY J. B. RATHER Assistant Chemist POSTOFFICE COLLEGE STATION... IS T .* In previous publications of this Experiment Station (Fraps and Bather, Bulletins Nos. 150 and 162) it has been shown that the un? saponifiable matter in the ether extract of hays and fodders averages about 58 per cent. Of the total extract, and is of much...

Rather, J. B. (James Burness)

1914-01-01T23:59:59.000Z

259

Toxicity of polychlorinated diphenyl ethers in Hydra attenuata and in rat whole embryo culture  

E-Print Network [OSTI]

TOXICITY OF POLYCHLORINATED DIPHENYL ETHERS IN HYDRA A?TENUATA AND IN RAT WHOLE EMBRYO CULTURE A Thesis by MARION CAROL BECKER Submitted to the Office of Graduate Studies of Texas A8cM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1991 Major Subject: Toxicology TOXICITY OF POLYCHLORINATED DIPHENYL ETHERS IN HYDRA A1TENUATA AND IN RAT WHOLE EMBRYO CULTURE by MARION CAROL BECKER Approved as to style and content by: Stephen H. S (Ca...

Becker, Marion Carol

2012-06-07T23:59:59.000Z

260

Source: Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol Blends.  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

A1: Tank Manufacturer Compatibility with Ethanol Blends. September 2013. A1: Tank Manufacturer Compatibility with Ethanol Blends. September 2013. Tank Manufacturer Compatibility with Ethanol Blends Manufacturer Compatibility Statement Fiberglass 1 Containment Solutions Tanks manufactured after January 1, 1995 are all compatible with ethanol blends up to 100% (E100) (UL Listed) Owens Corning Single Wall Tanks Tanks manufactured between 1965 and 1994 are approved to store up to 10% ethanol (E10) Double Wall Tanks Tanks manufactured between 1965 and July 1, 1990 are approved to store up to 10% ethanol (E10) Tanks manufactured between July 2, 1990 and December 31, 1994 were warrantied to store any ethanol blend Xerxes Single Wall Tanks Tanks manufactured prior to 1981 are not compatible with ethanol blends Tanks manufactured from February 1981 through June 2005 are

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Total Stocks Total Stocks Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

262

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Weekly Supply Estimates Weekly Supply Estimates Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

263

Hydrolysis of cellulose to produce glucose with solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) with sequential water addition  

Science Journals Connector (OSTI)

Selective glucose production by cellulose hydrolysis with initial or sequential water addition in the presence of solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) under microwave irra...

Kaori Ishida; Shiho Matsuda; Masaru Watanabe…

2014-12-01T23:59:59.000Z

264

Comparative Study of Thermomechanical Properties of Indigenous Blended Clay and Clay of Ukraine  

Science Journals Connector (OSTI)

This paper investigates the particle size distribution chemical composition fired modulus of rupture (MOR) and apparent porosity of blended clay utilizing clays available in Bikaner region and comparison with a imported Ukrainian clay. The blended clay B2 presents good white buff fired colour higher fired modulus of rupture and low porosity. The blend is suitable for Traditional Indian ceramic industries and a substitute of Ukrainian clay in India.

M. S. Shekhawat; S. K. Tak; R. Mangal; A. K. Gupta

2010-01-01T23:59:59.000Z

265

A new blending agent and its effects on methanol-gasoline fuels  

SciTech Connect (OSTI)

The major difficulty encountered with the use of methanol-gasoline blends as SI engine fuel is their tendency to phase separation due to the hydrophilic properties of methanol. Phase separation can lead to some utilization problems. Using a blending agent for the methanol-gasoline system is the common approach taken towards solving the phase separation problem. In this study introduces fraction of molasses fuel oil as an effective new blending agent for methanol-gasoline fuel.

Karaosmanoglu, F.; Isigiguer-Erguedenler, A.; Aksoy, H.A.

2000-04-01T23:59:59.000Z

266

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network [OSTI]

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

267

E-Print Network 3.0 - alternatives blending private Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for mixing as polymer feedstock. This feedstock was melt-blended with high- density polyethylene... mechanical properties and thermal properties of paintHDPE and paintPMMA...

268

E-Print Network 3.0 - anti-d rh1 blend Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Metallocene Summary: -Natta and Metallocene Hexene Linear Low-Density Polyethylene Blends with Low-Density Polyethylene Ibnelwaleed A. Hussein... and mechanical...

269

E-Print Network 3.0 - anhydride ternary blend Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

13 Phase Structure and Properties of Poly(ethylene terephthalate)High-Density Polyethylene Based on Summary: 1 (NCO stretching) disappeared in the blends,...

270

Effects of bio-diesel fuel blends on the performance and emissions of diesel engine.  

E-Print Network [OSTI]

??This study presents an experimental investigation into the effects of running biodiesel fuel blends on conventional diesel engines. Bio fuels provide a way to produce… (more)

Bastiani, Sergio.

2008-01-01T23:59:59.000Z

271

Multi-scale analysis and simulation of powder blending in pharmaceutical manufacturing  

E-Print Network [OSTI]

A Multi-Scale Analysis methodology was developed and carried out for gaining fundamental understanding of the pharmaceutical powder blending process. Through experiment, analysis and computer simulations, microscopic ...

Ngai, Samuel S. H

2005-01-01T23:59:59.000Z

272

Evaluation of the Effects of Nanofil® Nanoclays in the Blending of Polypropylene and Polystyrene.  

E-Print Network [OSTI]

??This study evaluated the effects of Nanofil® nanoclay on morphology development of an immiscible polymer blend of polypropylene (PP) and polystyrene (PS). The hypothesis that… (more)

Opalko, Robert J.

2008-01-01T23:59:59.000Z

273

HASKELL & WHITE CORPORATE REPORTING & GOVERNANCE CONFERENCE SERIES Blending Theory with Practice  

E-Print Network [OSTI]

HASKELL & WHITE CORPORATE REPORTING & GOVERNANCE CONFERENCE SERIES Blending Theory with Practice Pinnell, Managing Partner of Haskell & White. GUIDELINES FOR PAPER SUBMISSION Papers are invited from

de Lijser, Peter

274

Effect of PCI blending on combustion characteristics for iron-making.  

E-Print Network [OSTI]

??The PCI technology is well established for reducing the consumption of economic and environmentally expensive coke in blast furnace iron-making. Often, coal blends show unexpected… (more)

Gill, Trilochan Singh

2009-01-01T23:59:59.000Z

275

The Effects of Ethanol/Gasoline Blends on Advanced Combustion Strategies in Internal Combustion Engines.  

E-Print Network [OSTI]

??This dissertation presents the effects of blending ethanol with gasoline on advanced combustion strategies in internal combustion engines. The unique chemical, physical and thermal properties… (more)

Fatouraie, Mohammad

2014-01-01T23:59:59.000Z

276

Total Blender Net Input of Petroleum Products  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Input Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquid Petroleum Gases Normal Butane Isobutane Other Liquids Oxygenates/Renewables Methyl Tertiary Butyl Ether (MTBE) Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Reformulated, GTAB MGBC - Conventional MGBC - Conventional, CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

277

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

1999-01-01T23:59:59.000Z

278

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect (OSTI)

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

279

Thorium ions transport across Tri-n-butyl phosphate-benzene based supported liquid membranes  

SciTech Connect (OSTI)

Transport of Th(IV) ions across tri-n-butyl phosphate (TBP) benzene based liquid membranes supported in microporous hydrophobic polypropylene film (MHPF) has been studied. Various parameters such as variation of nitric acid concentration in the feed, TBP concentration in the membrane, and temperature on the given metal ions transport have been investigated. The effects of nitric acid and TBP concentrations on the distribution coefficient were also studied, and the data obtained were used to determine the Th ions-TBP complex diffusion coefficient in the membrane. Permeability coefficients of Th(IV) ions were also determined as a function of the TBP and nitric acid concentrations. The optimal conditions for the transport of Th(IV) ions across the membrane are 6 mol{sm_bullet}dm{sup -3} HNO{sub 3} concentration, 2.188 mol {center_dot} dm{sup -3} TBP concentration, and 25{degrees}C. The stoichiometry of the chemical species involved in chemical reaction during the transport of Th(IV) ions has also been studied.

Rasul, G.; Chaudry, M.A. [Pakistan Institute of Nuclear Chemistry, Islamabad (Pakistan); Afzal, M. [Quaid-I-Azam Univ., Islamabad (Pakistan)

1995-12-01T23:59:59.000Z

280

Dimethyl ether (DME) from coal as a household cooking fuel in China  

E-Print Network [OSTI]

technologies. Given China's rich coal resources, the production and use of coal-derived DME as a cooking fuelDimethyl ether (DME) from coal as a household cooking fuel in China Eric D. Larson Princeton gas (LPG) as a household cooking fuel. As such, DME is an attractive fuel for clean cooking. DME can

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Nuclear magnetic relaxation dispersion investigations1 of water retention mechanism by cellulose ethers in mortars2  

E-Print Network [OSTI]

Nuclear magnetic relaxation dispersion investigations1 of water retention mechanism by cellulose : 10.1016/j.cemconres.2012.06.002 #12;2 ABSTRACT22 23 We show how nuclear magnetic spin-lattice relaxation dispersion of protons-water24 (NMRD) can be used to elucidate the effect of cellulose ethers

Boyer, Edmond

282

Single Stage Contactor Testing Of The Next Generation Solvent Blend  

SciTech Connect (OSTI)

The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility at the Savannah River Site (SRS) is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent to increase the cesium decontamination factor. To support this integration of NGS into the MCU facility the Savannah River National Laboratory (SRNL) performed testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing utilized a blend of BOBCalixC6 based solvent and the NGS with the new extractant, MaxCalix, as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 liquid-to-liquid centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. The results indicate that hydraulically, the NGS solvent performed hydraulically similar to the current solvent which was expected. For the organic carryover 93% of the solvent is predicted to be recovered from the stripping operation and 96% from the extraction operation. As for the mass transfer, the NGS solvent significantly improved the cesium DF by at least an order of magnitude when extrapolating the One-stage results to actual Seven-stage extraction operation with a stage efficiency of 95%.

Herman, D. T.; Peters, T. B.; Duignan, M. R.; Williams, M. R.; Poirier, M. R.; Brass, E. A.; Garrison, A. G.; Ketusky, E. T.

2014-01-06T23:59:59.000Z

283

Experimental Study of Biodiesel Blends’ Effects on Diesel Injection Processes  

Science Journals Connector (OSTI)

It can be said that a lot of studies performed with biodiesel are mere emissions and performances comparisons against a standard diesel fuel using multicylinder engines and fundamental combustion and overall injections aspects are not being completely addressed yet. ... Emissions variations from 2 different engine models and 2 driving cycles were also obsd. ... Lujan, J. M.; Tormos, B.; Salvador, F. J.; Gargar, K. Comparative analysis of a DI diesel engine fuelled with biodiesel blends during the European MVEG-A cycle: Preliminary study (I). ...

José M. Desantes; Raúl Payri; Antonio García; Julien Manin

2009-05-13T23:59:59.000Z

284

Emissions mitigation of blended coals through systems optimization  

SciTech Connect (OSTI)

For coal fired power stations, such as those located in the US, that have installed NOx and SOx emissions abatement equipment substantial carbon dioxide reduction could be achieved by shifting from pure PRB coal to blended coals with local bituminous coal. Don Labbe explains how. The article is based on a presentation at Power-Gen Asia 2009, which takes place 7-9 October in Bangkok, Thailand and an ISA POWID 2009 paper (19th Annual Joint ISA POWID/EPRI Controlls and Instrumentation Conference, Chicago, Illinois, May 2009). 4 refs., 3 figs.

Don Labbe [IOM Invensys Operations Management (United States)

2009-10-15T23:59:59.000Z

285

Linking Low-Level Stable Isotope Fractionation to Expression of the Cytochrome P450 Monooxygenase-Encoding ethB Gene for Elucidation of Methyl tert-Butyl Ether Biodegradation in Aerated Treatment Pond Systems  

Science Journals Connector (OSTI)

...application of CSIA in field investigations to detect biodegradation...52). An alternative remedial strategy could be the use...application of CSIA in field investigations to detect biodegradation may lead to...application of CSIA in field investigations to detect biodegradation...

Sven Jechalke; Mònica Rosell; Paula M. Martínez-Lavanchy; Paola Pérez-Leiva; Thore Rohwerder; Carsten Vogt; Hans H. Richnow

2010-12-10T23:59:59.000Z

286

Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 ? Updated Feb 2009  

Broader source: Energy.gov [DOE]

Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 ? Updated Feb 2009

287

Puddle Dynamics and Air-to-Fuel Ratio Compensation for Gasoline-Ethanol Blends in  

E-Print Network [OSTI]

1 Puddle Dynamics and Air-to-Fuel Ratio Compensation for Gasoline-Ethanol Blends in Flex-Fuel Engines* Kyung-ho Ahn, Anna G. Stefanopoulou, and Mrdjan Jankovic Abstract--Ethanol is being increasingly flexible fuel vehicles (FFVs) can operate on a blend of gasoline and ethanol in any concentration of up

Stefanopoulou, Anna

288

Exhaust emissions and mutagenic effects of diesel fuel, biodiesel and biodiesel blends  

Science Journals Connector (OSTI)

Abstract The replacement of petroleum-derived fuels by renewable biogenic fuels has become of worldwide interest with the environmental effects being scientifically investigated. Biodiesel has been proven to be a suitable alternative to petrodiesel and blending up to 20% biodiesel with petrodiesel is policy promoted in the USA and the EU. To investigate the influence of blends on the exhaust emissions and possible health effects, we performed a series of studies with several engines (Euro 0, III and IV) using blends of rapeseed-derived biodiesel and petrodiesel. Regulated and non-regulated exhaust compounds were measured and their mutagenic effects were determined using the Bacterial Reverse Mutation Assay (Ames-Test) according to OECD Guideline 471. Exhaust emissions of blends were approximately linearly dependent on the blend composition, particularly when considering regulated emissions. However, a negative effect of blends was observed with respect to mutagenicity of the exhaust emissions. In detail, an increase of the mutagenic potential was found for blends with the maximum observed for B20. From this point of view, B20 must be considered as a critical blend when petrodiesel and biodiesel are used as binary mixtures.

Olaf Schröder; Jürgen Bünger; Axel Munack; Gerhard Knothe; Jürgen Krahl

2013-01-01T23:59:59.000Z

289

Aerodynamically Optimal Regional Aircraft Concepts: Conventional and Blended Wing-Body Designs  

E-Print Network [OSTI]

Aerodynamically Optimal Regional Aircraft Concepts: Conventional and Blended Wing-Body Designs aircraft such as those that serve regional routes. We thus explore the optimal aerodynamic shape of both a blended wing-body and conventional tube-and-wing regional aircraft through high-fidelity aerodynamic shape

Zingg, David W.

290

Shear-induced shift of spinodal line in entangled polymer blends  

Science Journals Connector (OSTI)

We study the shear-flow effects on phase separation of entangled polymer blends by incorporating into the chemical potential a nonequilibrium contribution due to the flow. The results are compared with those of a previous analysis by other authors which did not modify the chemical potential but used a different assumption for the stress tensor of the blend.

M. Criado-Sancho; D. Jou; J. Casas-Vázquez; L. F. del Castillo

2002-12-30T23:59:59.000Z

291

"Performance, Emission and Particle distribution of Diesel Engines Fueled with Diesel-Dimethoxymethane (DMM) Blends"  

E-Print Network [OSTI]

Xibin Wang "Performance, Emission and Particle distribution of Diesel Engines Fueled with Diesel-Dimethoxymethane (DMM) Blends" Abstract : Combustion, performance and emission were studied for DI diesel engine fuelled with DMM/diesel fuel blends for DMM content from 0 to 50%. Results showed that, for diesel engine with fuel

292

Enhanced Miscibility of Low-Molecular-Weight Polystyrene/Polyisoprene Blends in Supercritical CO2  

E-Print Network [OSTI]

with nitrogen decouple the plasticization efficacy of CO2 from free-volume compression due to hydrostaticEnhanced Miscibility of Low-Molecular-Weight Polystyrene/Polyisoprene Blends in Supercritical CO2 solution temperature (UCST) polymer blend in the presence of supercritical carbon dioxide (scCO2

Raghavan, Srinivasa

293

Synergistic Effect of coal blends on thermoplasticity evaluated using a temperature-variable dynamic viscoelastic measurement  

SciTech Connect (OSTI)

To maximize the conversion of low-quality coal into good coke, we investigated the thermoplasticity of various binary blends of caking coals with slightly or noncaking coals using a dynamic viscoelastic technique with a temperature-variable rheometer. Coal blend samples were prepared by mixing two coals (1:1 by weight), which were heated from room temperature to 600 C at a rate of 3-80{sup o}C/min. At the slow rate of 3{sup o}C/min, the blends had a tan {delta} that was generally lower than the calculated value, showing that a negative interaction caused a loss of thermoplasticity. In contrast, at the rapid heating rate of 80{sup o}C/min, the tan {delta} of some blends was higher than the calculated value, indicating a positive interaction that enhanced the thermoplasticity. With rapid heating, the thermoplasticity of each coal itself increased, and their thermoplastic temperature ranges widened with rapid heating. Therefore, rapid heating was effective at converting these coal blends into good cokes. Moreover, even with slow heating, when a combination of coals (Gregory:Enshu, 1:1) showing some thermoplasticity in nearly the same temperature range was blended, a desirable synergistic effect of the blend was obtained. This suggests that blending coal with an overlapping thermoplastic temperature range is important for the synergistic effect, regardless of the heating rate. 15 refs., 9 figs., 2 tabs.

Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito; Kensuke Masaki; Atsushi Dobashi; Kiyoshi Fukada [National Institute of Advanced Industrial Science and Technology, Tsukuba (Japan)

2006-12-15T23:59:59.000Z

294

Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends  

SciTech Connect (OSTI)

Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

2008-05-15T23:59:59.000Z

295

Combustion Characteristics of Coal and Biomass Blends and Thermal Dynamic Analysis  

Science Journals Connector (OSTI)

By using TGA technology, the combustion characteristics under different conditions of hard coal and biomass blends has been discussed. The combustion curves of blends exhibited the characteristics with two peaks. Results also exhibited that there was ... Keywords: coal, biomass, thermal analysis, combustion characteristics

Haizhen Huang; Haibo Chen; Guohua Wang; Jun Liu

2009-10-01T23:59:59.000Z

296

Compatibilizing Poly(vinylidene fluoride)/Nylon-6 Blends with Nanoclay  

Science Journals Connector (OSTI)

Blends of poly(vinylidene fluoride)/nylon-6 (PVDF/N6) 30:70 were melt compounded with various organoclays directly or sequentially. The morphology, thermal, and mechanical properties of the blend nanocomposites were investigated. It was determined that ...

Loan T. Vo; Emmanuel P. Giannelis

2007-10-04T23:59:59.000Z

297

Conformational properties of blends of cyclic and linear polymer melts  

Science Journals Connector (OSTI)

An adapted version of the annealing algorithm to identify primitive paths of a melt of ring polymers is presented. This algorithm ensures that the primitive path length becomes zero for nonconcatenated rings, and that no entanglements are observed. The bond-fluctuation model was used to simulate ring-linear blends with N=150 and 300 monomers. The primitive path length and the average number of entanglements of the linear component were found to be independent of the blend composition. In contrast, the primitive path length and the average number of entanglements on a ring molecule increased approximately linearly with the fraction of linear chains, and for large N, they approached values comparable with linear chains. Threading of ring molecules by linear chains, and ring-ring interactions were observed only in the presence of linear chains. It is conjectured that for large N, these latter interactions facilitate the formation of a percolating entangled network, thereby resulting in a disproportionate retardation of the dynamical processes.

Gopinath Subramanian and Sachin Shanbhag

2008-01-14T23:59:59.000Z

298

JV Task 112-Optimal Ethanol Blend-Level Investigation  

SciTech Connect (OSTI)

Highway Fuel Economy Test (HWFET) and Federal Test Procedure 75 (FTP-75) tests were conducted on four 2007 model vehicles; a Chevrolet Impala flex-fuel and three non-flex-fuel vehicles: a Ford Fusion, a Toyota Camry, and a Chevrolet Impala. This investigation utilized a range of undenatured ethanol/Tier II gasoline blend levels from 0% to 85%. HWFET testing on ethanol blend levels of E20 in the flex fuel Chevrolet Impala and E30 in the non-flex-fuel Ford Fusion and Toyota Camry resulted in miles-per-gallon (mpg) fuel economy greater than Tier 2 gasoline, while E40 in the non-flex-fuel Chevrolet Impala resulted in an optimum mpg based on per-gallon fuel Btu content. Exhaust emission values for non-methane organic gases (NMOG), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) obtained from both the FTP-75 and the HWFET driving cycles were at or below EPA Tier II, Light-Duty Vehicles, Bin 5 levels for all vehicles tested with one exception. The flex-fuel Chevrolet Impala exceeded the NMOG standard for the FTP-75 on E-20 and Tier II gasoline.

Richard Shockey; Ted Aulich; Bruce Jones; Gary Mead; Paul Steevens

2008-01-31T23:59:59.000Z

299

DOE Hydrogen Analysis Repository: Ethanol-Diesel Blends in Buses and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ethanol-Diesel Blends in Buses and Tractors Ethanol-Diesel Blends in Buses and Tractors Project Summary Full Title: Fuel-Cycle Energy and Emission Impacts of Ethanol-Diesel Blends in Urban Buses and Farming Tractors Project ID: 86 Principal Investigator: Michael Wang Brief Description: This project studied the full fuel-cycle energy and emissions effects of ethanol-diesel blends relative to those of petroleum diesel when used in urban transit buses and farming tractors. Keywords: Ethanol; diesel; emissions; well-to-wheels (WTW) Purpose Numerous studies have been conducted to evaluate the fuel-cycle energy and greenhouse gas (GHG) emission effects of ethanol-gasoline blends relative to those of gasoline for applications in spark- ignition engine vehicles. Those studies did not address the energy and emission effects of

300

Relationship between coking pressure generated by coal blends and the composition of their primary tars  

Science Journals Connector (OSTI)

Four coals that develop different pressures during the coking process were selected together with 10 blends (7 binary and 3 ternary) prepared with the same coals. Their semicoke contraction/expansion was measured by means of two tests (the Koppers-INCAR and the sole heated oven) and the variation in coking pressure during coking was determined in a movable wall oven. The coals and blends were then pyrolysed and the tars were analysed by gas chromatography (GC-FID–MS). The additivity law was applied to the properties used to evaluate the dangerousness of the blends and to the composition of the tar produced from the blends. Afterwards, the composition of the tar was studied in relation to contraction/expansion and the coking pressure generated by the coals and blends.

C. Barriocanal; M.A. Díez; R. Alvarez; M.D. Casal

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Effect of compatibilizer on impact and morphological analysis of recycled HDPE/PET blends  

SciTech Connect (OSTI)

Blends based on recycled high density polyethylene (rHDPE) and recycled polyethylene terephthalate (rPET) were prepared using a corotating twin screw extruder. PET and HDPE are incompatible polymers and their blends showed poor properties. Compatibilization is a step to obtain blends with good mechanical properties and in this work, ethylene glycidyl methacrylate copolymer (E-GMA) was used as a compatibilizing agent. The effect of blends based on rHDPE and rPET with and without a compatibilizer, E-GMA were examined. From the studies clearly showed that the addition of 5% E-GMA increased the impact strength. SEM analysis of rHDPE/rPET blends confirmed the morphological interaction and improved interfacial bonding between two phases.

Salleh, Mohd Nazry [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia and School of Materials Engineering, Universiti Malaysia Perlis, 02600 Jejawi, Perlis (Malaysia); Ahmad, Sahrim; Ghani, Mohd Hafizuddin Ab; Chen, Ruey Shan [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

2013-11-27T23:59:59.000Z

302

Chapter 30 - Biofuel Economics and Policy: The Renewable Fuel Standard, the Blend Wall, and Future Uncertainties  

Science Journals Connector (OSTI)

Abstract Biofuels are currently in a state of flux. The main operative policy for biofuels in the United States is the Renewable Fuel Standard (RFS). It specifies a minimum quantity of four different types of biofuels that must be blended each year in the United States through 2022. However, the United States also faces what is called the blend wall, which is a physical limit on blending given that the United States blends at a 10% rate. The blend wall upper limit is now below the RFS lower limit for corn ethanol, and that is causing problems with the administration of the RFS. This chapter explains how the RFS functions and then examines alternatives to the current administration of the RFS. The RFS is critical for cellulosic biofuels and biodiesel, and its elimination would likely end use of those fuels. Corn ethanol, however, is now much less expensive than gasoline and would continue.

Wallace E. Tyner

2015-01-01T23:59:59.000Z

303

MTBE Production Economics (Released in the STEO April 2001)  

Reports and Publications (EIA)

The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

2001-01-01T23:59:59.000Z

304

Insight into the Molecular Arrangement of High-Density Polyethylene Polymer Chains in Blends of Polystyrene/High-  

E-Print Network [OSTI]

Insight into the Molecular Arrangement of High-Density Polyethylene Polymer Chains in Blends of Polystyrene/High- Density Polyethylene from Differential Scanning Calorimetry and Raman Techniques JAYANT/high-density polyethylene (PS/HDPE) blends were synthe- sized by melt blending in a single screw extruder. Co

305

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents [OSTI]

A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

1996-04-02T23:59:59.000Z

306

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents [OSTI]

A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

Diebold, James P. (Lakewood, CO); Scahill, John W. (Evergreen, CO); Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO); Rejai, Bahman (Lakewood, CO); Bain, Richard L. (Golden, CO); Overend, Ralph P. (Lakewood, CO)

1996-01-01T23:59:59.000Z

307

Soluble, Infrared-Absorbing Croconate Dyes from 2,6-Di-tert-butyl-4-methylchalcogenopyrylium Salts  

Science Journals Connector (OSTI)

1 Although many squarylium dyes have limited solubility in organic solvents or in coated organic films, squarylium dyes 1 (Chart 1) derived from 2,6-di-tert-butyl-4-methylchalcogenopyrylium salts (2)3 are soluble and have been coated in organic thin films for a variety of applications. ... The croconates are readily prepared, are soluble in organic solvents, and have absorption maxima that cover a broad range of laser emission lines from gallium?arsenide diode lasers (?820 nm) to the neodinium-YAG laser (1064 nm). ... The reaction mixture was poured into water (50 mL), and the product was extracted with hexanes (3 × 25 mL). ...

Todd P. Simard; Jian H. Yu; Jennifer M. Zebrowski-Young; Neil F. Haley; Michael R. Detty

2000-03-03T23:59:59.000Z

308

Flow boundary conditions for chain-end adsorbing polymer blends  

E-Print Network [OSTI]

Using the phenol-terminated polycarbonate blend as an example, we demonstrate that the hydrodynamic boundary conditions for a flow of an adsorbing polymer melt are extremely sensitive to the structure of the epitaxial layer. Under shear, the adsorbed parts (chain ends) of the polymer melt move along the equipotential lines of the surface potential whereas the adsorbed additives serve as the surface defects. In response to the increase of the number of the adsorbed additives the surface layer becomes thinner and solidifies. This results in a gradual transition from the slip to the no-slip boundary condition for the melt flow, with a non-monotonic dependence of the slip length on the surface concentration of the adsorbed ends.

X. Zhou; D. Andrienko; L. Delle Site; K. Kremer

2005-07-18T23:59:59.000Z

309

Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion  

SciTech Connect (OSTI)

We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

2012-08-14T23:59:59.000Z

310

2[prime] and 3[prime] Carboranyl uridines and their diethyl ether adducts  

DOE Patents [OSTI]

A process is described for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. The carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of the compounds in methods for boron neutron capture therapy in mammalian tumor cells. No Drawings

Soloway, A.H.; Barth, R.F.; Anisuzzaman, A.K.; Alam, F.; Tjarks, W.

1992-12-15T23:59:59.000Z

311

Effect of solvents on the radiation-induced polymerization of ethyl and isopropyl vinyl ethers  

SciTech Connect (OSTI)

The effect of solvents on the radiation-induced cationic polymerization of ethyl and isopropyl vinyl ethers (EVE and IPVE, respectively) was investigated. EVE and IPVE polymerizations were carried out in bulk and in solution under superdry conditions in which polar impurities, especially water, have been reduced to negligible levels. This was accomplished by means of a sodium mirror technique using joint free baked out glass equipment and high vacuum. Plots of the monomer conversions and irradiation times were obtained for EVE and IPVE polymerizations in bulk and in benzene solution at constant monomer concentrations. The monomer concentration dependence of the polymerization rate was studied for EVE polymerization in bulk and in benzene, diethlyl ether, diglyme and methylene chloride, and for IPVE polymerization in bulk and in benzene. Solvent effect on the estimated propagating rate constants was examined for EVE and IPVE polymerization in bulk and in solution. The effect of temperature on the polymerization rate was also investigated for EVE polymerization in bulk ad in benzene, diethyl and diisopropyl ethers, methylene chloride and nitromethane, and for IPVE ploymerization in bulk and in benzene.

Hsieh, W.C.

1981-01-01T23:59:59.000Z

312

Refinery Stocks of Crude Oil and Petroleum Products  

Gasoline and Diesel Fuel Update (EIA)

Product: Crude Oil and Petroleum Products Crude Oil Petroleum Products Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils Heavy Gas Oils Residuum Motor Gasoline Blending Components MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - RBOB for Blending with Alcohol* MGBC - RBOB for Blending with Ether* MGBC - Conventional MGBC - Conventional CBOB MGBC - Conventional GTAB MGBC - Conventional Other Aviation Gasoline Blending Components Finished Motor Gasoline Reformulated Reformulated Blended with Fuel Ethanol Reformulated, Other Conventional Gasoline Conventional Gasoline Blended with Fuel Ethanol Conventional Gasoline Blended with Fuel Ethanol, Ed55 and Lower Conventional Other Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Distillate Fuel Oil, 15 ppm and Under Distillate Fuel Oil, Greater than 15 ppm to 500 ppm Distillate Fuel Oil, Greater than 500 ppm Residual Fuel Oil Less than 0.31 Percent Sulfur 0.31 to 1.00 Percent Sulfur Greater than 1.00 Percent Sulfur Petrochemical Feedstocks Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Marketable Coke Asphalt and Road Oil Miscellaneous Products Period-Units: Monthly-Thousand Barrels Annual-Thousand Barrels

313

Conversion and Blending Facility highly enriched uranium to low enriched uranium as uranyl nitrate hexahydrate. Revision 1  

SciTech Connect (OSTI)

This Conversion and Blending Facility (CBF) will have two missions: (1) convert HEU materials to pure HEU uranyl nitrate (UNH) and (2) blend pure HEU UNH with depleted and natural UNH to produce HEU UNH crystals. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. To the extent practical, the chemical and isotopic concentrations of blended LEU product will be held within the specifications required for LWR fuel. Such blended LEU product will be offered to the United States Enrichment Corporation (USEC) to be sold as feed material to the commercial nuclear industry. Otherwise, blended LEU Will be produced as a waste suitable for storage or disposal.

NONE

1995-07-05T23:59:59.000Z

314

HEU to LEU Conversion and Blending Facility: UF{sub 6} blending alternative to produce LEU UF{sub 6} for commercial use  

SciTech Connect (OSTI)

US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials; the nuclear material will be converted to a form more proliferation- resistant than the original form. Examining options for increasing the proliferation resistance of highly enriched uranium (HEU) is part of this effort. Five technologies for blending HEU will be assessed; blending as UF{sub 6} to produce a UF{sub 6} product for commercial use is one of them. This document provides data to be used in the environmental impact analysis for the UF{sub 6} blending HEU disposition option. Resource needs, employment needs, waste and emissions from plant, hazards, accident scenarios, and intersite transportation are discussed.

NONE

1995-09-01T23:59:59.000Z

315

Melt blend studies of nanoclay-filled polypropylene (PP)–high-density polyethylene (HDPE) composites  

Science Journals Connector (OSTI)

The objective of this work is to study how the rheological factors of unfilled and nanoclay-filled HDPE–PP blend series influence the ... 100 wt % HDPE), with and without nanoclay, was prepared by using melt-mixi...

T. P. Mohan; K. Kanny

2013-12-01T23:59:59.000Z

316

Morphology development in nanoclay filled rubber compounds and rubber blends detected by online measured electrical conductance  

Science Journals Connector (OSTI)

The online measured electrical conductance (OMEC) during the rubber mixing process has been used as a novel method to characterize the dispersion of organoclay in rubber compounds and blends. This method was a...

Z. Ali; H. H. Le; S. Ilisch; H.-J. Radusch

2009-12-01T23:59:59.000Z

317

A Design Experiment for Blending Knowledge Community And Inquiry in Secondary School Science  

E-Print Network [OSTI]

A Design Experiment for Blending Knowledge Community And Inquiry:00-1:15 Education Building 2010 Abstract. This presentation describes a design experiment objectives. Drawing on data from two design cycles, I examine the validity

Stanford, Kyle

318

Solid State Blending of Poly(ethylene terephthalate) with Polystyrene: Extent of PET Amorphization and  

E-Print Network [OSTI]

state via cryogenic mechanical attrition (CMA) and in the melt through conventional twin-screw extrusion of compatibilization was previously deter- mined to be both higher than that of extruded blends and also dependent upon

Mitchell, Brian S.

319

The morphology and deformation behavior of poly(butylene terephthalate)/BPA polycarbonate blends  

Science Journals Connector (OSTI)

In this communication the results of a series of recent studies of the morphology and deformation behavior of toughened poly(butylene terephthalate) (PBT)/BPA polycarbonate (PC) blends are briefly summarized....

S. Y. Hobbs; M. E. J. Dekkers; V. H. Watkins

1987-04-01T23:59:59.000Z

320

A Blended Soundproof-to-Compressible Numerical Model for Small- to Mesoscale Atmospheric Dynamics  

Science Journals Connector (OSTI)

A blended model for atmospheric flow simulations is introduced that enables seamless transition from fully compressible to pseudo-incompressible dynamics. The model equations are written in nonperturbation form and integrated using a well-balanced ...

Tommaso Benacchio; Warren P. O’Neill; Rupert Klein

2014-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

E-Print Network 3.0 - administration blending initiative Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TPW.... 2 History Began with a 1998 grant to CIRA to use AMSU... Microwave Sounding Unit. Weather and Forecasting, 15, 476-483. 12;22 Jan 2007 Blended TPW.... 3 ... Source:...

322

A Review of Chromatographic Characterization Techniques for Biodiesel and Biodiesel Blends  

Science Journals Connector (OSTI)

......June 2011 385 I. General References Several...presence can impact engine performance and emissions...method Outline I. General References. II...of B100 Content of Diesel Blends VI. Determination...esters (FAME) for diesel engines--Requirements......

R. E. Pauls

2011-05-01T23:59:59.000Z

323

Blended Straight-Run Gasolines with Composite Additives Containing Watery Ethanol  

Science Journals Connector (OSTI)

Cranking and antiknock properties of gasoline-alcohol blends based on straight-run gasoline with additives containing watery ethanol and other ... components are studied. The composition of the gasoline-alcohol b...

Yu. O. Beiko; A. P. Pavlovskii; O. A. Beiko

2014-01-01T23:59:59.000Z

324

Development of Kinetics and Mathematical Models for High Pressure Gasification of Lignite-Switchgrass Blends  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Kinetics and Mathematical Kinetics and Mathematical Models for High Pressure Gasification of Lignite-Switchgrass Blends Background Significant progress has been made in recent years in controlling emissions resulting from coal-fired electricity generation in the United States through the research, development, and deployment of innovative technologies such as gasification. Gasification is a process that converts solid feedstocks such as coal, biomass, or blends

325

Empirical Study of the Stability of Biodiesel and Biodiesel Blends: Milestone Report  

SciTech Connect (OSTI)

The objective of this work was to develop a database that supports specific proposals for a stability test and specification for biodiesel and biodiesel blends. B100 samples from 19 biodiesel producers were obtained in December of 2005 and January of 2006 and tested for stability. Eight of these samples were then selected for additional study, including long-term storage tests and blending at 5% and 20% with a number of ultra-low sulfur diesel fuels.

McCormick, R. L.; Westbrook, S. R.

2007-05-01T23:59:59.000Z

326

A Study on Coal Properties and Combustion Characteristics of Blended Coals in Northwestern China  

Science Journals Connector (OSTI)

Because of the tight supply situation and rising price of coals, the actual coals used in coal-fired power plants of China are usually significantly different from the design coal, which may seriously deteriorate the safety and economy of power plants. ... Accurate prediction of coal characteristics of blended coals from those of individual coals is quite significant to ensure the reliable and economic operation of a blended-coal-fired power plant. ...

Chang’an Wang; Yinhe Liu; Xiaoming Zhang; Defu Che

2011-07-11T23:59:59.000Z

327

Profit and policy implications of producing biodiesel–ethanol–diesel fuel blends to specification  

Science Journals Connector (OSTI)

A nonlinear optimization model is developed in this work to analyze biodiesel–ethanol–diesel (BED) ternary blending processes. The model establishes optimal blends to improve the system profitability given production costs, market demand, and fuel prices while meeting multiple property criteria such as kinematic viscosity, density, lower heating value, cloud point, cetane number, fuel stability and sulfur content. Pertinent fuel mixing rules for predicting the fuel properties of BED blends were extrapolated from previous works and applied as constraints to the present model. Several dynamic and/or uncertainty factors were explored in further depth to quantify their impacts on the fuel composition of BED blends including petro-diesel supply reduction, diesel production cost, diesel blends market retail price, and policy changes on bio-fuel subsidies. By examining key optimization sensitivity analysis such as shadow prices and opportunity costs, the crucial limits or constraints on fuel specifications can be identified and used to proactively identify and promote the development of potential additives. The model also suggests the government policy of simultaneously implementing bio-fuel tax credits and mandates may not have a higher contribution to promoting bio-fuel production than the case only with tax credits for the firms with the goal of profit maximization. The firms enable 5–8% increase of the optimal profit from BED blends by utilizing ethanol derived from food waste feedstocks instead of edible biomass.

Jiefeng Lin; Gabrielle Gaustad; Thomas A. Trabold

2013-01-01T23:59:59.000Z

328

Hybrid Dynamic Density Functional Theory for Polymer Melts and Blends  

E-Print Network [OSTI]

We propose a high-speed and accurate hybrid dynamic density functional theory for the computer simulations of the phase separation processes of polymer melts and blends. The proposed theory is a combination of the dynamic self-consistent field (SCF) theory and a time-dependent Ginzburg-Landau type theory with the random phase approximation (GRPA). The SCF theory is known to be accurate in evaluating the free energy of the polymer systems in both weak and strong segregation regions although it has a disadvantage of the requirement of a considerable amount of computational cost. On the other hand, the GRPA theory has an advantage of much smaller amount of required computational cost than the SCF theory while its applicability is limited to the weak segregation region. To make the accuracy of the SCF theory and the high-performance of the GRPA theory compatible, we adjust the chemical potential of the GRPA theory by using the SCF theory every constant time steps in the dynamic simulations. The performance of the GRPA and the hybrid theories is tested by using several systems composed of an A/B homopolymer, an AB diblock copolymer, or an ABC triblock copolymer. Using the hybrid theory, we succeeded in reproducing the metastable complex phase-separated domain structures of an ABC triblock copolymer observed by experiments.

Takashi Honda; Toshihiro Kawakatsu

2006-09-05T23:59:59.000Z

329

A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames  

SciTech Connect (OSTI)

The oxidation of dimethyl ether (DME) is studied in low-pressure flames using new molecular beam mass spectrometer and laser diagnostics. Two 30.0-Torr, premixed DME/oxygen/argon flames are investigated with stoichiometries of 0.98 and 1.20. The height above burner profiles of nine stable species and two radicals are measured. These results are compared to the detailed chemical reaction mechanism of Curran and coworkers. Generally good agreement is found between the model and data. The largest discrepancies are found for the methyl radical profiles where the model predicts qualitatively different trends in the methyl concentration with stoichiometry than observed in the experiment.

Andrew McIlroy; Toby D. Hain; Hope A. Michelsen; Terrill A. Cool

2000-12-15T23:59:59.000Z

330

High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993  

SciTech Connect (OSTI)

The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

1993-07-01T23:59:59.000Z

331

Tailoring key fuel properties of diesel–biodiesel–ethanol blends for diesel engine  

Science Journals Connector (OSTI)

Alternative fuel research for the profusely growing number of diesel run automotive has intensified due to environmental reasons and turmoil in petroleum market. Government initiatives all around the world, their energy policies and steps to emphasis the use of biodiesel; proved biodiesel as a number one renewable substitute for No. 2 diesel fuels. Among all biodiesel feedstock, palm oil is a potential source with higher yield rate without much fertilizer use especially in tropical region. However, the application of transesterified palm biodiesel is objected by many auto-manufacturers due to adverse effects on engine in long term operation. The aim of this study was to modify the key fuel properties of palm biodiesel which causes engine fouling in long term operation. A significant amount of work is devoted to mix biodiesel and diesel at arbitrary percentages and test engine performance. Numerous fuel additives are developed for biodiesels automotive use. In this study, chemical properties of biodiesel are tailored by ethanol and an optimum formulation is derived mathematically. Ethanol is used at a controlled proportion (6%) with palm oil methyl ester (POME) as additive to reduce the higher viscosity of POME. This optimum palm biodiesel–ethanol blend was mixed at varying proportions (i.e. 0–30%) with No. 2 diesel to produce ternary blends of diesel–palm biodiesel–ethanol. Cold flow properties (such as, could point, pour point) of these ternary blends has improved and minute percentage of ethanol adding did not adversely affect the oxidation stability and corrosiveness of the fuel blend. Ethanol has significantly reduces the flash point, but the flammability of ternary blends is classified as Class II; similar to that of diesel. Cetane number is reduced in ternary blends by ethanol. So, palm biodiesel with minute percentage of anhydrous ethanol as additive in the ternary blend significantly improved key fuel properties significantly.

Md. Jayed Hussan; Masjuki Hj. Hassan; Md. Abul Kalam; Liaquat Ali Memon

2013-01-01T23:59:59.000Z

332

Degradation studies on acid–base blends for both LT and intermediate T fuel cells  

Science Journals Connector (OSTI)

Abstract In this study the ex-situ and in-situ behavior of acid–base blend membranes from sulfonated polyethersulfone and a partially fluorinated sulfonated polymer (prepared by condensation of decafluorobipenyl with bisphenol AF, followed by sulfonation of the obtained polymer) and two different polybenzmidazoles (F6-PBI and PBIOO®) was investigated. Two types of acid–base blend membranes from the abovementioned polymers were prepared and characterized: acid–base blend membranes with a molar excess of acidic blend component for low-T H2 fuel cells (LT-FC) where the proton conductivity is overtaken by the sulfonic acid groups, and blend membranes comprising a molar excess of basic blend component which were subsequently doped with phosphoric acid for the usage in intermediate-T H2 fuel cells (IT-FC) where the network of phosphoric acid molecules in the membrane provides the proton conduction. For elucidation of the radical stability of the membranes, the membranes were subjected to Fenton's Reagent and were operated in a H2-PEMFC. After these tests, the membranes were investigated via SEC for molecular weight degradation. As a result, correlations could be found between degradation of the blend membranes in the fuel cell and after Fenton's test. Moreover, at IT-FC membranes, a correlation could be found between doping degree and fuel cell performance which are discussed in this paper. One of the membranes, a H3PO4-doped base-excess membrane from sPSU and PBIOO showed an excellent performance in an IT-FC at 180 °C of 0.85 A/cm2@0.5 V without pressurization of the reactant gases.

A. Chromik; J.A. Kerres

2013-01-01T23:59:59.000Z

333

Synthesis and Characterization of Surface Relaxations of Macrocyclic Polystyrenes and Interfacial Segregation in Blends with Linear Polystyrenes.  

E-Print Network [OSTI]

??The effects of a topology with no chain ends on interfacial segregation in binary polymer blends and the surface fluctuations of films of macrocycles were… (more)

Wang, Shih-fan

2011-01-01T23:59:59.000Z

334

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process. Peroxide formation of dimethyl ether in methanol mixtures  

SciTech Connect (OSTI)

Organic peroxides could form when dimethyl ether in methanol is stored for three to six months at a time. The objective of this work was to determine the level of peroxide formation from dimethyl ether in reagent grade methanol and raw methanol at room temperature under 3 atmospheres (45 psig) of air. Raw methanol is methanol made from syngas by the LPMEOH Process without distillation. Aliphatic ethers tend to react slowly with oxygen from the air to form unstable peroxides. However, there are no reports on peroxide formation from dimethyl ether. After 172 days of testing, dimethyl ether in either reagent methanol or raw methanol at room temperature and under 60--70 psig pressure of air does not form detectable peroxides. Lack of detectable peroxides suggests that dimethyl ether or dimethyl ether and methanol may be stored at ambient conditions. Since the compositions of {approximately} 1.3 mol% or {approximately} 4.5 mol% dimethyl ether in methanol do not form peroxides, these compositions can be considered for diesel fuel or an atmospheric turbine fuel, respectively.

Waller, F.J.

1997-11-01T23:59:59.000Z

335

Flash photolysis resonance fluorescence investigation of the gas-phase reactions of hydroxyl radicals with cyclic ethers  

SciTech Connect (OSTI)

Absolute rate constants were measured for the gas-phase reactions of hydroxyl radicals with a series of dioxanes and other cyclic ethers by using the flash photolysis resonance fluorescence technique. Kinetic data for 1,3-dioxane and 1,4-dioxane, reactions 1 and 2, over the temperature range 240-440 K were used to derive the Arrhenius expressions. These results are compared to our earlier measurements for aliphatic ethers and are discussed in terms of reaction mechanisms and the prediction of reaction rates for such compounds from group reactivity values.

Dagaut, P.; Liu, R.; Wallington, T.J.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1990-03-08T23:59:59.000Z

336

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions  

DOE Patents [OSTI]

A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

2001-01-01T23:59:59.000Z

337

SAVANNAH RIVER SITE INCIPIENT SLUDGE MIXING IN RADIOACTIVE LIQUID WASTE STORAGE TANKS DURING SALT SOLUTION BLENDING  

SciTech Connect (OSTI)

This paper is the second in a series of four publications to document ongoing pilot scale testing and computational fluid dynamics (CFD) modeling of mixing processes in 85 foot diameter, 1.3 million gallon, radioactive liquid waste, storage tanks at Savannah River Site (SRS). Homogeneous blending of salt solutions is required in waste tanks. Settled solids (i.e., sludge) are required to remain undisturbed on the bottom of waste tanks during blending. Suspension of sludge during blending may potentially release radiolytically generated hydrogen trapped in the sludge, which is a safety concern. The first paper (Leishear, et. al. [1]) presented pilot scale blending experiments of miscible fluids to provide initial design requirements for a full scale blending pump. Scaling techniques for an 8 foot diameter pilot scale tank were also justified in that work. This second paper describes the overall reasons to perform tests, and documents pilot scale experiments performed to investigate disturbance of sludge, using non-radioactive sludge simulants. A third paper will document pilot scale CFD modeling for comparison to experimental pilot scale test results for both blending tests and sludge disturbance tests. That paper will also describe full scale CFD results. The final paper will document additional blending test results for stratified layers in salt solutions, scale up techniques, final full scale pump design recommendations, and operational recommendations. Specifically, this paper documents a series of pilot scale tests, where sludge simulant disturbance due to a blending pump or transfer pump are investigated. A principle design requirement for a blending pump is UoD, where Uo is the pump discharge nozzle velocity, and D is the nozzle diameter. Pilot scale test results showed that sludge was undisturbed below UoD = 0.47 ft{sup 2}/s, and that below UoD = 0.58 ft{sup 2}/s minimal sludge disturbance was observed. If sludge is minimally disturbed, hydrogen will not be released. Installation requirements were also determined for a transfer pump which will remove tank contents, and which is also required to not disturb sludge. Testing techniques and test results for both types of pumps are presented.

Leishear, R.; Poirier, M.; Lee, S.; Steeper, T.; Fowley, M.; Parkinson, K.

2011-01-12T23:59:59.000Z

338

Pilot plant assessment of blend properties and their impact on critical power plant components  

SciTech Connect (OSTI)

A series of tests were performed to determine the effects of blending eastern bituminous coals with western subbituminous coals on utility boiler operation. Relative to the baseline bituminous coal, the testing reported here indicated that there were significant impacts to boiler performance due to the blending of the eastern and western coals. Results indicated that fuel blending can be used to adequately control flue gas emissions of both SO{sub 2} and NO{sub x} at the expense of reduced milling efficiency, increased sootblowing in the high-temperature and low-temperature regions of the boiler and, to a lesser extent, decreased collection efficiency for an electrostatic precipitator. The higher reactivity of the subbituminous coal increased the overall combustion efficiency, which may tend to decrease the impact of milling efficiency losses. The extent of these impacts was directly related to the percentage of subbituminous coal in the blends. At the lowest blend ratios of subbituminous coal, the impacts were greatly reduced.

NONE

1996-10-01T23:59:59.000Z

339

Concentration fluctuations in miscible polymer blends: Influence of temperature and chain rigidity  

SciTech Connect (OSTI)

In contrast to binary mixtures of small molecule fluids, homogeneous polymer blends exhibit relatively large concentration fluctuations that can strongly affect the transport properties of these complex fluids over wide ranges of temperatures and compositions. The spatial scale and intensity of these compositional fluctuations are studied by applying Kirkwood-Buff theory to model blends of linear semiflexible polymer chains with upper critical solution temperatures. The requisite quantities for determining the Kirkwood-Buff integrals are generated from the lattice cluster theory for the thermodynamics of the blend and from the generalization of the random phase approximation to compressible polymer mixtures. We explore how the scale and intensity of composition fluctuations in binary blends vary with the reduced temperature ? ? (T ? T{sub c})/T (where T{sub c} is the critical temperature) and with the asymmetry in the rigidities of the components. Knowledge of these variations is crucial for understanding the dynamics of materials fabricated from polymer blends, and evidence supporting these expectations is briefly discussed.

Dudowicz, Jacek; Freed, Karl F. [The James Franck Institute and the Department of Chemistry, The University of Chicago, Chicago, Illinois 60637 (United States)] [The James Franck Institute and the Department of Chemistry, The University of Chicago, Chicago, Illinois 60637 (United States); Douglas, Jack F. [The James Franck Institute and the Department of Chemistry, The University of Chicago, Chicago, Illinois 60637 (United States) [The James Franck Institute and the Department of Chemistry, The University of Chicago, Chicago, Illinois 60637 (United States); Materials Science and Engineering Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States)

2014-05-21T23:59:59.000Z

340

ESS 2012 Peer Review - Acid Based Blend Membranes for Redox Flow Batteries - Alan Cisar, Lynntech  

Broader source: Energy.gov (indexed) [DOE]

Acid Based Blend Membranes for Redox Flow Batteries Acid Based Blend Membranes for Redox Flow Batteries DOE Grant No: DE-SC0006306 Alan Cisar* and Chris Rhodes Lynntech, Inc., 2501 Earl Rudder Freeway South, College Station, TX 77845 *E-mail: alan.cisar@lynntech.com, Phone: 979.764.2311 Prof. Arumugam Manthiram University of Texas, Austin, TX 78712 Prof. Fuqiang Liu University of Texas Arlington, Arlington, TX 76019 Conclusions Lynntech, in conjunction with the University of Texas and the University of Texas at Arlington, developed a new series of low-cost polymer blend membranes with high proton conductivity and ultralow vanadium ion permeability. The proton conductivity and physical properties of these membranes are tunable by adjusting the ratio of acid and base components. Membrane conductivity was found to be more critical to

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren  

Broader source: Energy.gov (indexed) [DOE]

Citizens Advisory Board's Eco Fair Blends Fun and Facts for Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren near Paducah Site Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren near Paducah Site June 1, 2012 - 12:00pm Addthis Lone Oak Middle School sixth-graders pet a mallard hen at the third annual Eco Fair May 15 in West Kentucky Wildlife Management Area. Lone Oak Middle School sixth-graders pet a mallard hen at the third annual Eco Fair May 15 in West Kentucky Wildlife Management Area. Ralph Young of Recycle Now! explains to Eco Fair attendees the value of recycling. Young is chairman of the Paducah Citizens Advisory Board, which advises the Department of Energy regarding cleanup issues at the Paducah site. Ralph Young of Recycle Now! explains to Eco Fair attendees the value of

342

Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Blending Hydrogen into Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues M. W. Melaina, O. Antonia, and M. Penev Technical Report NREL/TP-5600-51995 March 2013 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues M. W. Melaina, O. Antonia, and M. Penev Prepared under Task No. HT12.2010 Technical Report NREL/TP-5600-51995 March 2013 NOTICE This report was prepared as an account of work sponsored by an agency of the United States government.

343

The effects of blending hydrogen with methane on engine operation, efficiency, and emissions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-01-0474 -01-0474 The effects of blending hydrogen with methane on engine operation, efficiency, and emissions Thomas Wallner and Henry K. Ng Argonne National Laboratory Robert W. Peters University of Alabama at Birmingham Copyright © 2007 SAE International ABSTRACT Hydrogen is considered one of the most promising future energy carriers and transportation fuels. Because of the lack of a hydrogen infrastructure and refueling stations, widespread introduction of vehicles powered by pure hydrogen is not likely in the near future. Blending hydrogen with methane could be one solution. Such blends take advantage of the unique combustion properties of hydrogen and, at the same time, reduce the demand for pure hydrogen. In this paper, the authors analyze the combustion properties of hydrogen/methane

344

Drive cycle analysis of butanol/diesel blends in a light-duty vehicle.  

SciTech Connect (OSTI)

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests.

Miers, S. A.; Carlson, R. W.; McConnell, S. S.; Ng, H. K.; Wallner, T.; LeFeber, J.; Energy Systems; Esper Images Video & Multimedia

2008-10-01T23:59:59.000Z

345

Performance of a direct diesel engine using aviation fuels blended with biodiesel  

Science Journals Connector (OSTI)

In this study, jet fuel (JF) and railroad fuel (D2) with SME blends (5%, 20%, 50%) were used in a four-cylinder, naturally aspirated, direct (DI) diesel engine. The engine was operated under full load and tested at various speeds to determine the engine's performance and exhaust emission characteristics. The experimental results show that as the SME ratio of the fuels increases, the break specific fuel consumption (BSFC) and exhaust temperature increase; the SME and its blends show a slight drop in engine performance. In this experiment, carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx) and smoke opacity values were measured for each fuel. The results of the emission tests revealed that the oxygen content of SME provided a significant reduction in CO and smoke opacity emissions. However, when the test engine was fuelled by SME and its blends, NOx emissions increased.

Burak Gökalp; Hakan Serhad Soyhan; Halil ?brahim Sarac

2012-01-01T23:59:59.000Z

346

The relationship between the thermoplastic behavior of blends and their component coals  

SciTech Connect (OSTI)

The thermoplastic behaviors of a number of coking coal blends were measured using proton magnetic resonance thermal analysis (PMRTA) to determine to what extent they were affected by interactions between the component coals. Most blends showed evidence that at temperatures near their temperatures of maximum fluidity the extent to which they fused was different to that expected if the coals did not interact. Only blends of coking coals of different rank fused to a greater extent than expected in the absence of interactions. Semi-anthracite, low rank coals and charcoal reduced the extent of fusion of coking coals to values below those expected if they were acting as inert diluents. These interactions are interpreted as being mediated by transfer of volatile material between the coals on heating.

Sakurovs, R.

1999-07-01T23:59:59.000Z

347

Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren  

Broader source: Energy.gov (indexed) [DOE]

Citizens Advisory Board's Eco Fair Blends Fun and Facts for Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren near Paducah Site Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren near Paducah Site June 1, 2012 - 12:00pm Addthis Lone Oak Middle School sixth-graders pet a mallard hen at the third annual Eco Fair May 15 in West Kentucky Wildlife Management Area. Lone Oak Middle School sixth-graders pet a mallard hen at the third annual Eco Fair May 15 in West Kentucky Wildlife Management Area. Ralph Young of Recycle Now! explains to Eco Fair attendees the value of recycling. Young is chairman of the Paducah Citizens Advisory Board, which advises the Department of Energy regarding cleanup issues at the Paducah site. Ralph Young of Recycle Now! explains to Eco Fair attendees the value of

348

Sample Results From The Extraction, Scrub, And Strip Test For The Blended NGS Solvent  

SciTech Connect (OSTI)

This report summarizes the results of the extraction, scrub, and strip testing for the September 2013 sampling of the Next Generation Solvent (NGS) Blended solvent from the Modular Caustic Side-Solvent Extraction Unit (MCU) Solvent Hold Tank. MCU is in the process of transitioning from the BOBCalixC6 solvent to the NGS Blend solvent. As part of that transition, MCU has intentionally created a blended solvent to be processed using the Salt Batch program. This sample represents the first sample received from that blended solvent. There were two ESS tests performed where NGS blended solvent performance was assessed using either the Tank 21 material utilized in the Salt Batch 7 analyses or a simulant waste material used in the V-5/V-10 contactor testing. This report tabulates the temperature corrected cesium distribution, or DCs values, step recovery percentage, and actual temperatures recorded during the experiment. This report also identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. The calculated extraction DCs values using the Tank 21H material and simulant are 59.4 and 53.8, respectively. The DCs values for two scrub and three strip processes for the Tank 21 material are 4.58, 2.91, 0.00184, 0.0252, and 0.00575, respectively. The D-values for two scrub and three strip processes for the simulant are 3.47, 2.18, 0.00468, 0.00057, and 0.00572, respectively. These values are similar to previous measurements of Salt Batch 7 feed with lab-prepared blended solvent. These numbers are considered compatible to allow simulant testing to be completed in place of actual waste due to the limited availability of feed material.

Washington, A. L. II; Peters, T. B.

2014-03-03T23:59:59.000Z

349

Title: Decomposition of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes  

E-Print Network [OSTI]

of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes Author list: Bo Hou (single-walled carbon nanotubes) was investigated. Gas-phase thermal decomposition of ethanol and DME ethanol and DME decomposition, confirming expected reaction trends and primary byproducts. Peak

Maruyama, Shigeo

350

Environmental actions of agrochemicals 2. Histological effects of the herbicide/insecticide dinoseb-acetate (2-sec-butyl-4,6-dinitrophenyl acetate) on the spider miteTetranychus urticae (Acari: Tetranychidae) reared on herbicidetreatedPhaseolus vulgaris  

Science Journals Connector (OSTI)

The pure herbicidal compound dinoseb-acetate (2-sec-butyl-4,6-dinitrophenyl acetate) and its commercial formulation Aretit® were tested for their effects on the spider miteTetranychus urticae L. (Acari, Tetranych...

Ursula Mothes-Wagner; Harald K. Reitze…

1990-10-01T23:59:59.000Z

351

Small-Angle X-ray Scattering from Blends of PE and SBS. Observation of a Novel Kind of Deviation from Porod's Law  

Science Journals Connector (OSTI)

In the SAXS of modified poly(ethylene) (blends) a peculiar and reproducible deviation from Porod's law is found. The strength of this effect is a function of blend composition.

Stribeck, N.

1997-10-01T23:59:59.000Z

352

Numerical Model Investigation for Potential Methane Explosion and Benzene Vapor Intrusion Associated with High-Ethanol Blend  

E-Print Network [OSTI]

Associated with High-Ethanol Blend Releases Jie Ma, Hong Luo, George E. DeVaull,§ William G. Rixey, and Pedro ABSTRACT: Ethanol-blended fuel releases usually stimulate methanogenesis in the subsurface, which could conditions exist. Ethanol- derived methane may also increase the vapor intrusion potential of toxic fuel

Alvarez, Pedro J.

353

Effects of the blends containing low ratios of alternative fuels on the performance and emission characteristics of a diesel engine  

Science Journals Connector (OSTI)

The aim of this study is to experimentally investigate the effects of blends containing various alternative fuels and diesel fuel on the performance and emissions of a diesel engine. The considered parameters are brake power, specific fuel consumption and thermal efficiency as well as carbon monoxide, hydrocarbon and nitrogen oxide emissions. Blends of biodiesel, ethanol, methanol and vegetable oil with diesel fuel, each containing 15% alternative fuel in volume, were prepared. Then, these blends were tested in a naturally aspirated, direct injection diesel engine. The test results obtained with these blends were compared with those obtained with diesel fuel. It was found that the tested blends yielded usually different performance and emission characteristics compared to diesel fuel. The biodiesel blend resulted in performance parameters very close to those obtained in the use of diesel fuel. Ethanol and methanol blends yielded lower brake power, while they resulted in higher specific fuel consumption and lower carbon monoxide emissions. On the other hand, the vegetable oil blend yielded lower carbon monoxide emissions, while it caused only slight changes in the performance parameters.

Murat Karabektas; Gokhan Ergen; Murat Hosoz

2013-01-01T23:59:59.000Z

354

Photo-Curable Polymer Blend Dielectrics for Advancing Organic Field-Effect Transistor Applications  

SciTech Connect (OSTI)

A solution method of photo-curable and -patternable polymer gate dielectrics was introduced by using blend solutions of poly(4-dimethylsilyl styrene) (PDMSS) and poly(melamine-co-formaldehyde) acrylate (PMFA). The fabrication was optimized to produce a smooth hydrophobic gate dielectric with good insulating and solvent-resistant properties. On the optimized PDMSS/PMFA blend gate dielectric, pentacene could grow into highly ordered structure, showing high electric performances for the resulting OFETs, as well as PTCDI-C13 and TES-ADT.

S Kim; K Hong; M Jang; J Jang; J Anthony; H Yang; C Park

2011-12-31T23:59:59.000Z

355

Surface-induced First Order Transition in Athermal Polymer/Nanoparticle Blends  

E-Print Network [OSTI]

We investigate the phase behavior of athermal polymer/nanoparticle blends near a hard substrate. We apply the density functional theory of Tripathi and Chapman to these blends. We find a first order phase transition where the nanoparticles expel the polymer from the surface to form a monolayer. The transition density depends on the polymer length and the system bulk density. The effect is due to the packing entropy of the species and configurational entropy of the polymer. The simplicity of the system allows us to understand the so-called ``entropic-push'' observed in experiments.

E. S. McGarrity; A. L. Frischknecht; L. J. D. Frink; M. E. Mackay

2007-10-31T23:59:59.000Z

356

Prediction of metallurgical coke strength from the petrographic composition of coal blends  

SciTech Connect (OSTI)

Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

2009-07-01T23:59:59.000Z

357

Densities and isobaric vapor-liquid equilibria of butyl esters (methanoate to butanoate) with ethanol at 101.32 kPa  

SciTech Connect (OSTI)

Vapor-liquid equilibrium and densities at 101.32 kPa have been determined for the binary systems formed by four butyl esters (from methanoate to butanoate) with ethanol. The four systems exhibit positive deviations from ideal behavior, and all data (p-T-x-y) were found to be thermodynamically consistent. The activity coefficients and the dimensionless function G{sup E}/RT of the solution were correlated with its concentration by different equations. Am azeotrope was found in the mixture butyl methanoate (1) + ethanol (2) at T = 350.9 K and x{sub 1} = y{sub 1} = 0.088. The group contribution models ASOG and modified UNIFAC gave fair predictions.

Gonzalez, E.; Ortega, J. [Univ. of Las Palmas de Gran Canaria (Spain)

1995-11-01T23:59:59.000Z

358

Direct hydro-liquefaction of sawdust in petroleum ether and comprehensive bio-oil products analysis  

Science Journals Connector (OSTI)

Abstract The effect of temperature, time, hydrogen pressure and amount of catalyst on production distribution and the bio-oil yield obtained from the direct liquefaction of sawdust in the petroleum ether (60–90 °C) are investigated. The highest sawdust conversion obtained was 72.32% with a bio-oil yield of 47.69% were obtained at 370 °C, 40 min and 5wt.% catalyst content with the initial H2 pressure of 3.0 MPa. Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) approach was utilized to analyze the non-volatile fraction. In this study, the composition of bio-oil could be analyzed in an unprecedented detail through a combination of GC–MS and FT-ICR MS techniques.

Dong Liu; Linhua Song; Pingping Wu; Yan Liu; Qingyin Li; Zifeng Yan

2014-01-01T23:59:59.000Z

359

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents [OSTI]

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, D.; Waller, F.J.

1998-04-28T23:59:59.000Z

360

Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process  

DOE Patents [OSTI]

The present invention pertains to a process for the coproduction of methanol and dimethyl ether (DME) directly from a synthesis gas in a single step (hereafter, the "single step DME process"). In this process, the synthesis gas comprising hydrogen and carbon oxides is contacted with a dual catalyst system comprising a physical mixture of a methanol synthesis catalyst and a methanol dehydration catalyst. The present invention is an improvement to this process for providing an active and stable catalyst system. The improvement comprises the use of an aluminum phosphate based catalyst as the methanol dehydration catalyst. Due to its moderate acidity, such a catalyst avoids the coke formation and catalyst interaction problems associated with the conventional dual catalyst systems taught for the single step DME process.

Peng, Xiang-Dong (Allentown, PA); Parris, Gene E. (Coopersburg, PA); Toseland, Bernard A. (Allentown, PA); Battavio, Paula J. (Allentown, PA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents [OSTI]

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, Dorai (Allentown, PA); Waller, Francis Joseph (Allentown, PA)

1998-01-01T23:59:59.000Z

362

Using Heteropolyacids in the Anode Catalyst Layer of Dimethyl Ether PEM Fuel Cells  

SciTech Connect (OSTI)

In this study, polarization experiments were performed on a direct dimethyl ether fuel cell (DMEFC). The experimental setup allowed for independent control of water and DME flow rates. Thus the DME flow rate, backpressure, and water flow rate were optimized. Three heteropoly acids, phosphomolybdic acid (PMA), phosphotungstic acid (PTA), and silicotungstic acid (STA) were incorporated into the anode catalyst layer in combination with Pt/C. Both PTA-Pt and STA-Pt showed higher performance than the Pt control at 30 psig of backpressure. Anodic polarizations were also performed, and Tafel slopes were extracted from the data. The trends in the Tafel slope values are in agreement with the polarization data. The addition of phosphotungstic acid more than doubled the power density of the fuel cell, compared to the Pt control.

Ferrell III, J. R.; Turner, J. A.; Herring, A. M.

2008-01-01T23:59:59.000Z

363

Comparison of blends of conventional diesel fuel and CRBO containing high levels of FFA in a DI diesel engine  

Science Journals Connector (OSTI)

This work attempts to analyse the ability of high free fatty acid (FFA) crude rice bran oil (CRBO) in replacing diesel partially in a compression ignition (CI) engine. It was observed that the delay period and the maximum rate of pressure rise for CRBO blends are lower than diesel and is almost inversely proportional to FFA content. Maximum heat release rate for CRBO blends are lower and occur earlier than that of diesel. CRBO blends require longer duration to release 90% of heat than diesel and it decreases with increase in FFA content of CRBO. When operating with CRBO blends, all emission parameters were decreased significantly with a marginal increase in CO emission than that of diesel without affecting the brake thermal efficiency of the engine. It is concluded that higher FFA of CRBO blends does not inhibit its ability to be utilised as a fuel in CI engines.

S. Saravanan; G. Lakshmi Narayana Rao; S. Sampath; G. Nagarajan

2012-01-01T23:59:59.000Z

364

Thermochemical and trace element behavior of coal gangue, agricultural biomass and their blends during co-combustion  

Science Journals Connector (OSTI)

Abstract The thermal decomposition behavior of coal gangue, peanut shell, wheat straw and their blends during combustion were determined via thermogravimetric analysis. The coal gangue/agricultural biomass blends were prepared in four weight ratios and oxidized under dynamic conditions from room temperature to 1000 °C by various heating rates. Kinetic models were carried out to evaluate the thermal reactivity. The overall mass balance was performed to assess the partition behavior of coal gangue, peanut shell and their blends during combustion in a fixed bed reactor. The decomposition processes of agricultural biomass included evaporation, release of volatile matter and combustion as well as char oxidation. The thermal reactivity of coal gangue could be improved through the addition of agricultural biomass in suitable proportion and subsequent appropriate heating rate during combustion. In combination with the heating value and base/acid ratio limitations, a blending ratio of 30% agricultural biomass is conservatively selected as optimum blending.

Chuncai Zhou; Guijian Liu; Siwei Cheng; Ting Fang; Paul Kwan Sing Lam

2014-01-01T23:59:59.000Z

365

Use of ferric sulfate: acid media for the desulfurization of model compounds of coal. [Dibenzothiophene, diphenyl sulfide, di-n-butyl sulfide  

SciTech Connect (OSTI)

The objective of this work has been to investigate the ability of ferric sulfate-acid leach systems to oxidize the sulfur in model compounds of coal. Ferric iron-acid leach systems have been shown to be quite effective at removal of inorganic sulfur in coal. In this study, the oxidative effect of ferric iron in acid-leach systems was studied using dibenzothiophene, diphenyl sulfide, and di-n-butyl sulfide as models of organic sulfur groups in coal. Nitrogen and oxygen, as well as various transition metal catalysts and oxidants, were utilized in this investigation. Dibenzothiophene was found to be quite refractory to oxidation, except in the case where metavanadate was added, where it appears that 40% oxidation to sulfone could have occurred per hour at 150/sup 0/C and mild oxygen pressure. Diphenyl sulfide was selectively oxidized to sulfoxide and sulfone in an iron and oxygen system. Approximately 15% conversion to sulfone occurred per hour under these conditions. Some of the di-n-butyl sulfide was cracked to 1-butene and 1-butanethiol under similar conditions. Zinc chloride and ferric iron were used at 200/sup 0/C in an attempt to desulfonate dibenzothiophene sulfone, diphenyl sulfone, and di-n-butyl sulfone. Di-n-butyl sulfone was completely desulfurized on one hour and fragmented to oxidized parafins, while dibenzothiophene sulfone and diphenyl sulfone were unaffected. These results suggest that an iron-acid leach process could only selectively oxidize aryl sulfides under mild conditions, representing only 20% of the organic sulfur in coal (8% of the total sulfur). Removal through desulfonation once selective sulfur oxidation had occurred was only demonstrated for alkyl sulfones, with severe oxidation of the fragmented paraffins also occurring in one hour.

Clary, L.R.; Vermeulen, T.; Lynn, S.

1980-12-01T23:59:59.000Z

366

Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).  

SciTech Connect (OSTI)

Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

2013-02-01T23:59:59.000Z

367

Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)  

Reports and Publications (EIA)

The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

1998-01-01T23:59:59.000Z

368

Behaviour and effects of alcohol-blended petrol in the subsurface  

Science Journals Connector (OSTI)

...and gasoline blends. Biomass and Bioenergy , 33 , 1175-1181. McDowell...93-104. Staples, C.A. 2001. A review of the environmental fate and aquatic...gasoline in the environment. A literature review and transport modeling . Report...

Philip Morgan; Simon Firth; Beate Hildenbrand

369

Rapid Monitoring of Hydrocarbon Blending Stocks in Modified Aviation Turbine Fuels  

Science Journals Connector (OSTI)

......JP-4 jet fuel. For JP-4 turbine fuel, the analysis is relatively...blending stocks in JP-4 aviation turbine fuel. Introduction High resolution...principal Air Force aviation turbine fuel, and the incorporation...Scientific). The column's efficiency was measured and found to be......

P.C. Hayes; Jr.; E.W. Pitzer

1984-10-01T23:59:59.000Z

370

Co-firing of coal and biomass fuel blends M. Sami, K. Annamalai*, M. Wooldridge1  

E-Print Network [OSTI]

Co-firing of coal and biomass fuel blends M. Sami, K. Annamalai*, M. Wooldridge1 Department; accepted 6 June 2000 Abstract This paper reviews literature on co-firing of coal with biomass fuels. Here, the term biomass includes organic matter produced as a result of photosynthesis as well as municipal

Wooldridge, Margaret S.

371

Wood plastic composites based on microfibrillar blends of high density polyethylene/poly(ethylene terephthalate)  

E-Print Network [OSTI]

Wood plastic composites based on microfibrillar blends of high density polyethylene January 2010 Keywords: Wood plastic composites Poly(ethylene terephthalate) Polyethylene Extrusion a b into wood plastic composites through a two-step reactive extrusion technology. Wood flour was added into pre

372

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, T.

1984-09-28T23:59:59.000Z

373

Relatively low-cost solutions could improve reliability while making biodiesel blends an affordable option.  

E-Print Network [OSTI]

is vehicle stalling caused by fuel filter clogging, which prevents fuel from reaching the engine. ResearchRelatively low-cost solutions could improve reliability while making biodiesel blends an affordable option. While biodiesel has very low production costs and the potential to displace up to 10

374

Combined Impact of Branching and Unsaturation on the Autoignition of Binary Blends in a Motored Engine  

Science Journals Connector (OSTI)

From this test condition, a homogeneous charge of fuel and intake air can be achieved. ... The test fuels were prepared by addition of 5–20 vol % diisobutylene into n-heptane and isooctane. ... The 15 and 20 vol % blends of diisobutylene in isooctane were not able to reach high temperature heat release in the CFR engine system under these test conditions. ...

Dongil Kang; Stephen Kirby; John Agudelo; Magín Lapuerta; Khalid Al-Qurashi; André L. Boehman

2014-09-29T23:59:59.000Z

375

Enhanced Activated Carbon Cathode Performance for Microbial Fuel Cell by Blending Carbon Black  

E-Print Network [OSTI]

Enhanced Activated Carbon Cathode Performance for Microbial Fuel Cell by Blending Carbon Black-based materials that have good catalytic activity, but the electrical conductivity of the AC is poor compared as a binder, as opposed to Nafion with Pt, which greatly reduces the cost of the cathode materials. AC

376

NO Reduction in Decoupling Combustion of Biomass and Biomass?Coal Blend  

Science Journals Connector (OSTI)

NO Reduction in Decoupling Combustion of Biomass and Biomass?Coal Blend ... Biomass is a form of energy that is CO2-neutral. ... However, NOx emissions in biomass combustion are often more than that of coal on equal heating-value basis. ...

Li Dong; Shiqiu Gao; Wenli Song; Jinghai Li; Guangwen Xu

2008-12-09T23:59:59.000Z

377

Adaptive microbial population shifts in response to a continuous ethanol blend release increases biodegradation potential  

E-Print Network [OSTI]

Adaptive microbial population shifts in response to a continuous ethanol blend release increases 2013 Accepted 28 March 2013 Keywords: Pyrosequencing Ethanol Microbial diversity Temperature a b s t r a pilot- scale continuous release (10 months) of a 10% v:v ethanol solution mixed with benzene and toluene

Alvarez, Pedro J.

378

Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity  

DOE Patents [OSTI]

There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

Skotheim, Terje (East Patchogue, NY)

1986-01-01T23:59:59.000Z

379

Spatial patch blending for artefact reduction in pattern-based inpainting techniques  

E-Print Network [OSTI]

Spatial patch blending for artefact reduction in pattern-based inpainting techniques Maxime Daisy Juin, 14050 Caen/France, {maxime.daisy,david.tschumperle,olivier.lezoray}@ensicaen.fr Abstract. Patch regions in images, by iteratively du- plicating blocks of known image data (patches) inside the area

Lezoray, Olivier

380

Hypocholesterolemic effect of some plants and their blend as studied on albino rats  

Science Journals Connector (OSTI)

This work was carried out to evaluate the hypocholesterolemia effect of esparto grass leaves, fenugreek seeds powder, myrrh resin and their blend (prepared using equal amounts of each) on albino rats. Half, fenugreek and the blend were added to basal diet at 5% and 10%, while myrrh added at 2.5% and 5% hypercholesterolemia raised serum TC, TG, LDL and VLDL while HDL declined. Feeding on mentioned plants reversed the mentioned change provided that efficacy was different where the blend mostly came first, being of highest effect (indicating a synergistic action) and fenugreek of lowest effect. Fenugreek seeds powder showed 34.50-43.75% decrease of AI compared to control (+). Serum glucose showed 31.25% increase due to hypercholesterolemia, and decreased from 141.13 mg dl?1 (control+) to 97.1-127.0 mg dl?1 by experimental diets; in this concern the blend diet was of highest effect. More studies are needed to confirm the effect of myrrh as overweight and obesity controller agent.

Nadia Saleh Al-Amoudi

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Interfacial morphology and friction properties of thin PEO and PEO/PAA blend films  

Science Journals Connector (OSTI)

The scanning force microscope (SFM) was used to investigate morphology of poly(ethylene oxide) (PEO) and poly(acrylic acid) (PAA) blend. The effect of solvent and dewetting in surface structure of PEO film was reported. The results manifested that the crystallization of PEO could be suppressed completely in ultrathin region via using chloroform as a solvent, and the branched-like crystallization was recovered after dewetting. Also, the effect of thickness, the ratio of PEO/PAA and dewetting in surface morphology of PEO–PAA blend films were investigated. These results showed that the crystallization was highly dependent on the ratio of PEO/PAA and the thickness of blend film. Furthermore, we assembled the PEO/PAA layer-by-layer film by spin-casting method for the first time, which exhibited highly efficiency. As a complementary tool, we also used lateral force microscopy (LFM) to explore surface information of these films. The result was indicative of interfacial constraints in ultrathin region, and also was supported by the results showing the spin-casting PEO/PAA blends rather than heterogeneous mixture.

Xianke Gu; Guojian Wang

2011-01-01T23:59:59.000Z

382

Improvement of the Coal Ash Slagging Tendency by Coal Washing and Additive Blending with Mullite Generation  

Science Journals Connector (OSTI)

Four typical coals and two pretreatment methods were investigated to prevent slagging by facilitating mullite formation in coal ash at a high temperature. ... Both security and economy in power plant can be improved substantially as long as ash deposition and slagging tendency alleviated. ... Pilot-projects about coal washing and coal blending economic benefit are looking forward to put into practice. ...

Zhenyu Huang; Yan Li; Dan Lu; Zhijun Zhou; Zhihua Wang; Junhu Zhou; Kefa Cen

2013-03-11T23:59:59.000Z

383

Behaviour and effects of alcohol-blended petrol in the subsurface  

Science Journals Connector (OSTI)

...Lahvis, M.A. 2003. Evaluation of small-volume releases...J.J. 2013 a. Microbial processes influencing the transport...B. 1999. Screening model evaluation of the effects of ethanol...groundwater contaminated with a biodiesel blend (B20). Biodegradation...

Philip Morgan; Simon Firth; Beate Hildenbrand

384

NUCLEAR ISOTOPIC DILUTION OF HIGHLY ENRICHED URANIUM BY DRY BLENDING VIA THE RM-2 MILL TECHNOLOGY  

SciTech Connect (OSTI)

DOE has initiated numerous activities to focus on identifying material management strategies to disposition various excess fissile materials. In particular the INEEL has stored 1,700 Kg of offspec HEU at INTEC in CPP-651 vault facility. Currently, the proposed strategies for dispositioning are (a) aqueous dissolution and down blending to LEU via facilities at SRS followed by shipment of the liquid LEU to NFS for fabrication into LWR fuel for the TVA reactors and (b) dilution of the HEU to 0.9% for discard as a waste stream that would no longer have a criticality or proliferation risk without being processed through some type of enrichment system. Dispositioning this inventory as a waste stream via aqueous processing at SRS has been determined to be too costly. Thus, dry blending is the only proposed disposal process for the uranium oxide materials in the CPP-651 vault. Isotopic dilution of HEU to typically less than 20% by dry blending is the key to solving the dispositioning issue (i.e., proliferation) posed by HEU stored at INEEL. RM-2 mill is a technology developed and successfully tested for producing ultra-fine particles by dry grinding. Grinding action in RM-2 mill produces a two million-fold increase in the number of particles being blended in a centrifugal field. In a previous study, the concept of achieving complete and adequate blending and mixing (i.e., no methods were identified to easily separate and concentrate one titanium compound from the other) in remarkably short processing times was successfully tested with surrogate materials (titanium dioxide and titanium mono-oxide) with different particle sizes, hardness and densities. In the current project, the RM-2 milling technology was thoroughly tested with mixtures of natural uranium oxide (NU) and depleted uranium oxide (DU) stock to prove its performance. The effects of mill operating and design variables on the blending of NU/DU oxides were evaluated. First, NU and DU both made of the same oxide, UO{sub 3}, was used in the testing. Next, NU made up of UO{sub 3} and DU made up of UO{sub 2} was used in the test work. In every test, the blend achieved was characterized by spatial sampling of the ground product and analyzing for {sup 235}U concentration. The test work proved that these uranium oxide materials can be blended successfully. The spatial concentration was found to be uniform. Next, sintered thorium oxide pellets were used as surrogate for light water breeder reactor pellets (LWBR). To simulate LWBR pellet dispositioning, the thorium oxide pellets were first ground to a powder form and then the powder was blended with NU. In these tests also the concentration of {sup 235}U and {sup 232}Th in blended products fell within established limits proving the success of RM-2 milling technology. RM-2 milling technology is applicable to any dry radioactive waste, especially brittle solids that can be ground up and mixed with the non-radioactive stock.

Raj K. Rajamani; Sanjeeva Latchireddi; Vikas Devrani; Harappan Sethi; Roger Henry; Nate Chipman

2003-08-01T23:59:59.000Z

385

Sulfobutyl Ether b-Cyclodextrin (SBE-b-CD) in Eyedrops Improves the Tolerability of a Topically Applied Pilocarpine Prodrug in Rabbits  

E-Print Network [OSTI]

The effects of a novel, modified ?-cyclodextrin (SBE4-?-CD; a variably substituted sulfobutyl ether with an average degree of substitution of four) on eye irritation and miotic response of an ophthalmically applied pilocarpine ...

Stella, Valentino J.; Jä rvinen, Tomi; Jä rvinen, Kristina; Thompson, Diame; Urtti, Arto

1995-01-01T23:59:59.000Z

386

Influence of coal thermoplastic properties on coking pressure generation: Part 2 – A study of binary coal blends and specific additives  

Science Journals Connector (OSTI)

A number of coal blends and pitch/coal blends were evaluated using rheometry, thermogravimetric analysis and microscopy to confirm and further elucidate the coking pressure mechanism previously proposed by Duffy et al. (2007) [1]. We confirm that blending a low rank, high fluidity, low coking pressure coal, with a high rank, low fluidity, high coking pressure coal can significantly reduce the coking pressure associated with the latter. Interestingly, blending does not necessarily result in a fluidity that is midway between that of the two coals; sometimes the fluidity of the blend is less than that of the low fluidity coal, especially when the coals are significantly different in rank. This occurs because the increase in complex viscosity (?*) through resolidification of the low rank, high fluidity coal counteracts the reduction in ?* resulting from softening of the high rank, low fluidity coal. It has also been confirmed that the ?* of the resultant blend can be estimated from the ?* of each component coal using a logarithmic additivity rule commonly employed for polymer blends. Polarised light microscopy has indicated that the degree of mixing between coals of different rank is minimal, with fusion restricted to the particle surface. It is therefore inappropriate to think of such a coal blend in the same way as a single coal, since each component coal behaves relatively independently. This limited fusion is important for understanding the coking pressure mechanism for blends. It is proposed here that the lower rank coal, which softens at lower temperature, is able to expand into the interparticle voids between the high rank coal that is yet to soften, and these voids can create channels for volatiles to traverse. Then, and importantly, when the high rank coal begins to expand, the pore structure developed in the resolidified structures of the low rank coal can facilitate removal of volatiles, while the resolidified material may also act as a suitable sorbent for volatile matter. This is considered to be the primary mechanism by which coal blending is able to alleviate coking pressure, and applies to addition of inert material also. Addition of a coal tar pitch was found to increase fluidity but also to extend the thermoplastic range to lower temperatures. This caused an increase in the swelling range, which was accompanied by a long plateau in ?*, a feature which has previously been observed for certain high fluidity, high pressure coals. Elasticity and ?* at the onset of expansion were also higher for both the pitch impregnated coals and the high pressure blends, which supports previous findings for singly charged high pressure coals, and confirms the potential use of such criteria for identifying potentially dangerous coals/blends.

John J. Duffy; Merrick R. Mahoney; Karen M. Steel

2010-01-01T23:59:59.000Z

387

Experimental and Theoretical Investigation of the Effects of Gasoline Blends on Single-Cylinder Diesel Engine Performance and Exhaust Emissions  

Science Journals Connector (OSTI)

Experiments presented in this study for gasoline blends and experiments of Bilgin et al. for ethanol blends have been performed in a single-cylinder diesel engine at Karadeniz Technical University, Engineering Faculty, Mechanical Engineering Department, Internal Combustion Engines Laboratory. ... However, to determine the most favorable blend ratio for any vehicle diesel engine, to achieve general results, and to give general recommendations, more systematic experimental and theoretical studies for actual vehicle diesel engines must be performed. ... Union of Chambers of Turkish Engineers and Architects, Chamber of Mechanical Engineer, 1991; Vol. 383, pp 18? 29 (in Turkish). ...

Z. ?ahin

2008-08-16T23:59:59.000Z

388

Solid-State NMR Molecular Dynamics Characterization of aHighly Chlorine-Resistant Disulfonated Poly(arylene ether sulfone) Random Copolymer Blended with Poly(ethylene glycol) Oligomers for Reverse Osmosis Applications  

Science Journals Connector (OSTI)

(3) However, PAs show a critical weakness to chlorine (e.g., NaOCl) that is added as an oxidizing biocide to remove microorganisms that accumulate on the membrane surface, blocking water flux. ... (6, 10, 11) Hence, BPS-20K, a relatively low DS material, was considered as an alternative RO membrane material owing to its excellent NaCl separation property being similar to that of commercial PA (>99%). ...

Chang Hyun Lee; Justin Spano; James E. McGrath; Joseph Cook; Benny D. Freeman; Sungsool Wi

2011-05-11T23:59:59.000Z

389

Air and oxy-fuel combustion behaviour of petcoke/lignite blends  

Science Journals Connector (OSTI)

The pyrolysis and combustion behaviour of a petroleum coke (petcoke), an indigenous lignite and their 70/30 wt.% blend in air and oxy-fuel conditions were investigated by using non-isothermal thermo-gravimetric method (TGA) coupled with Fourier transform infrared (FTIR) spectrometer. Blend samples were prepared by mixing lignite, which has low calorific value, high ash and moisture contents with petcoke that has high calorific value, low ash and moisture content, in the proportion of 70:30. Pyrolysis tests were carried out in nitrogen and carbon dioxide environments which are the main diluting gases of air and oxy-fuel environments, respectively. Pyrolysis curves of parent fuels and their blend reveal close resemblance up to 700 °C in both N2 and CO2 environments. At higher temperatures, further weight loss taking place in N2 and CO2 atmospheres is attributed to calcite decomposition and CO2-char gasification reaction, respectively. Gasification reaction leads to significant increase in CO and COS formation as observed in FTIR evolution profiles. Almost identical experimental and theoretical pyrolysis profiles of the blend samples show that there is no synergy between the parent fuels of the blend in both pyrolysis environments. Combustion experiments were carried out in four different atmospheres; air, oxygen-enriched air environment (30% O2–70% N2), oxy-fuel environment (21% O2–79% CO2) and oxygen-enriched oxy-fuel environment (30% O2–70% CO2). Combustion experiments show that replacing nitrogen in the gas mixture by the same concentration of CO2 leads to delay in combustion (lower maximum rate of weight loss and higher burnout temperatures). Overall comparison of derivative thermogravimetry (DTG) profiles shows that effect of oxygen content on combustion characteristics is more significant than that of diluting gas in the combustion environment. At elevated oxygen levels, profiles shift through lower temperature zone, peak and burnout temperatures decrease, weight loss rate increases significantly and complete combustion is achieved at lower temperatures and shorter times. Theoretical and experimental combustion profiles of the blend mainly display different trends, which indicate synergistic interactions between lignite and petcoke during their combustion in different environments.

Nur Sena Yuzbasi; Nevin Selçuk

2012-01-01T23:59:59.000Z

390

Research on viscosity-reduction technology by electric heating and blending light oil in ultra-deep heavy oil wells  

Science Journals Connector (OSTI)

In the Tahe oilfield in China, heavy oil is commonly lifted using the light oil blending technology. However, due to the lack of light oil, the production of heavy oil has been seriously limited. Thus, a new c...

Mo Zhu; Haiquan Zhong; Yingchuan Li…

2014-07-01T23:59:59.000Z

391

An integrated video- and weight-monitoring system for the surveillance of highly enriched uranium blend down operations  

SciTech Connect (OSTI)

An integrated video-surveillance and weight-monitoring system has been designed and constructed for tracking the blending down of weapons-grade uranium by the US Department of Energy. The instrumentation is being used by the International Atomic Energy Agency in its task of tracking and verifying the blended material at the Portsmouth Gaseous Diffusion Plant, Portsmouth, Ohio. The weight instrumentation developed at the Oak Ridge National Laboratory monitors and records the weight of cylinders of the highly enriched uranium as their contents are fed into the blending facility while the video equipment provided by Sandia National Laboratory records periodic and event triggered images of the blending area. A secure data network between the scales, cameras, and computers insures data integrity and eliminates the possibility of tampering. The details of the weight monitoring instrumentation, video- and weight-system interaction, and the secure data network is discussed.

Lenarduzzi, R.; Castleberry, K. [Oak Ridge National Lab., TN (United States); Whitaker, M. [Lockheed Martin Energy Systems, Oak Ridge, TN (United States); Martinez, R. [Sandia National Labs., Albuquerque, NM (United States)

1998-11-01T23:59:59.000Z

392

Effect of idling on fuel consumption and emissions of a diesel engine fueled by Jatropha biodiesel blends  

Science Journals Connector (OSTI)

Abstract An engine running at low load and low rated speed is said to be subject to high idling conditions, a mode which represents one of the major problems currently the transport industry is facing. During this time, the engine can not work at peak operating temperature. This leads to incomplete combustion and emissions level increase due to having fuel residues in the exhaust. Also, idling results in increase in fuel consumption. The purpose of this study is to evaluate fuel consumption and emissions parameters under high idling conditions when diesel blended with Jatropha curcas biodiesel is used to operate a diesel engine. Although biodiesel–diesel blends decrease carbon monoxide and hydrocarbon emissions, they increase nitrogen oxides emissions in high idling modes. Compared to pure diesel fuel, fuel consumption also increases under all high idling conditions for biodiesel–diesel blends, with a further increase occurring as blend percentage rises.

S.M. Ashrafur Rahman; H.H. Masjuki; M.A. Kalam; M.J. Abedin; A. Sanjid; S. Imtenan

2014-01-01T23:59:59.000Z

393

Combustion and emission characteristics of a turbo-charged common rail diesel engine fuelled with diesel-biodiesel-DEE blends  

Science Journals Connector (OSTI)

The combustion and emission characteristics of a turbo-charged, common rail diesel engine fuelled with diesel-biodiesel-DEE blends were investigated. The study reports that the brake-specific fuel consumption of ...

Ni Zhang; Zuohua Huang; Xiangang Wang; Bin Zheng

2011-03-01T23:59:59.000Z

394

Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated  

SciTech Connect (OSTI)

Intended for policymakers and others who make decisions about, and set guidelines for, the proper use of intermediate ethanol blends such as E20 in both vehicle engines and other engine types.

Knoll, K.; West, B.; Clark, W.; Graves, R.; Orban, J.; Przesmitzki, S.; Theiss, T.

2009-02-01T23:59:59.000Z

395

Application and modeling of near-infrared frequency domain photon migration for monitoring pharmaceutical powder blending operations  

E-Print Network [OSTI]

of blending. A simulation method was developed which consisted of (i) dynamic simulation for generating the powder structure; (ii) the completely-randommixture model for predicting the spatial distribution of API particles within the powder bed; and (iii...

Pan, Tianshu

2006-10-30T23:59:59.000Z

396

Organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends  

E-Print Network [OSTI]

The organic gas emissions from a stoichiometric direct injection spark ignition engine operating on ethanol/gasoline blends have been assessed under warmed-up and cold idle conditions. The speciated emissions show that the ...

Kar, Kenneth

397

Particulate Matter Emissions from a Direct Injection Spark Ignition Engine under Cold Fast Idle Conditions for Ethanol-Gasoline Blends  

E-Print Network [OSTI]

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under ...

Dimou, Iason

398

Melt Strength Behaviour of Polyethylenes and Polyethylene Blends and its Relation to Bubble Stability in Film Blowing  

Science Journals Connector (OSTI)

Melt strength data are presented on the three major classes of commercial polyethylenes (LDPE, LLDPE and HDPE) and some of their binary blend systems. Melt strength was assessed from uniaxial tensile experiments ...

A. Ghijsels; J. J. S. M. Ente; J. Raadsen

1988-01-01T23:59:59.000Z

399

An Experimental Study into the Ignition of Methane and Ethane Blends in a New Shock-tube Facility  

E-Print Network [OSTI]

AN EXPERIMENTAL STUDY INTO THE IGNITION OF METHANE AND ETHANE BLENDS IN A NEW SHOCK-TUBE FACILITY A Thesis by CHRISTOPHER JOSEPH ERIK AUL Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE December 2009 Major Subject: Mechanical Engineering AN EXPERIMENTAL STUDY INTO THE IGNITION OF METHANE AND ETHANE BLENDS IN A NEW SHOCK-TUBE FACILITY A Thesis...

Aul, Christopher Joseph Erik

2011-02-22T23:59:59.000Z

400

Evaluation of Fuel Properties of Butanol?Biodiesel?Diesel Blends and Their Impact on Engine Performance and Emissions  

Science Journals Connector (OSTI)

Values of specific fuel consumption of engine when fueled with different blends and pure diesel at different speeds are shown in Figure 4. ... Chandra, R.; Kumar, R. Fuel properties of some stable alcohol?diesel microemulsions for their use in compression ignition engines Energy Fuels 2007, 21, 3410– 3414 ... Liu, B.; Huang, Z.; Miao, H.; Di, Y.; Jiang, D.; Zeng, K. Combustion and emissions of a DI diesel engine fuelled with diesel?oxygenate blends Fuel 2008, 87, 2691– 2697 ...

Rakhi N. Mehta; Mousumi Chakraborty; Pinakeswar Mahanta; Parimal A. Parikh

2010-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Effect of Bioethanol Blended Diesel Fuel and Engine Load on Spray, Combustion, and Emissions Characteristics in a Compression Ignition Engine  

Science Journals Connector (OSTI)

Yan et al.(8) investigated the combustion and emission characteristics of diesel engines fueled with ethanol–diesel blended fuel in a single cylinder diesel engine. ... Figure 11 shows the indicated specific fuel consumption (ISFC) characteristics of diesel–bioethanol blended fuels at various engine loads. ... Tests on the engine fuelled with diesel only were made, and the performance evaluated to form a basis for comparison for those of ethanol-diesel dual fuelling. ...

Su Han Park; In Mo Youn; Yunsung Lim; Chang Sik Lee

2012-07-03T23:59:59.000Z

402

Physical and chemical characteristics of an interesterified blend of butterfat and cottonseed oil with possible industrial applications  

E-Print Network [OSTI]

: dilatometry, glyceride compositional analysis, thin layer chromatography, gas liquid chromatography, mass spectrometry, and pancreatic lipase hydrolysis. physical/Chemical properties of the Modified pats Use of official methods of the American Oil... butterfat, cottonseed oil, the blend, the interesterified blend, and cheese. The following tests were conducted: Free fatty acids A. O. C. S. official method Ca 5a-40 was used. The molten samples were well mixed and a sample size of 28. 2 g of each...

Rashidi, Nabil

2012-06-07T23:59:59.000Z

403

Impact of Biofuel Blending on Diesel Soot Oxidation: Implications for Aftertreatment  

SciTech Connect (OSTI)

Control strategies for diesel particulate filters (DPFs) remain one of the most important aspects of aftertreatment research and understanding the soot oxidation mechanism is key to controlling regeneration. Currently, most DPF models contain simple, first order heterogeneous reactions oxidation models with empirically fit parameters. This work improves the understanding of fundamental oxidation kinetics necessary to advance the capabilities of predictive modeling, by leading to better control over regeneration of the device. This study investigated the effects of blending soybean-derived biodiesel fuel on diesel particulate emissions under conventional combustion from a 1.7L direct injection, common rail diesel engine. Five biofuel blend levels were investigated and compared to conventional certification diesel for the nanostructure, surface chemistry and major constituents of the soluble organic fraction (SOF) of diesel particulate matter (PM), and the relationship between these properties and the particulate oxidation kinetics.

Strzelec, Andrea [ORNL; Toops, Todd J [ORNL; Lewis Sr, Samuel Arthur [ORNL; Daw, C Stuart [ORNL; Foster, David [University of Wisconsin; Rutland, Prof. Christopher J. [University of Wisconsin; Vander Wal, Dr. Randy [NASA-Glenn Research Center, Cleveland

2009-01-01T23:59:59.000Z

404

Polyethylene-supported polyvinylidene fluoride–cellulose acetate butyrate blended polymer electrolyte for lithium ion battery  

Science Journals Connector (OSTI)

The polyethylene (PE)-supported polymer membranes based on the blended polyvinylidene fluoride (PVDF) and cellulose acetate butyrate (CAB) are prepared for gel polymer electrolyte (GPE) of lithium ion battery. The performances of the prepared membranes and the resulting \\{GPEs\\} are investigated by scanning electron microscopy, electrochemical impedance spectroscopy, linear potential sweep, and charge–discharge test. The effect of the ratio of PVDF to CAB on the performance of the prepared membranes is considered. It is found that the GPE based on the blended polymer with PVDF:CAB = 2:1 (in weight) has the largest ionic conductivity (2.48 × 10?3 S cm?1) and shows good compatibility with anode and cathode of lithium ion battery. The LiCoO2/graphite battery using this GPE exhibits superior cyclic stability at room temperature, storage performance at elevated temperature, and rate performance.

Jiansheng Liu; Weishan Li; Xiaoxi Zuo; Shengqi Liu; Zhao Li

2013-01-01T23:59:59.000Z

405

Solvent Extraction Behavior of Neptunium (IV) Ions between Nitric Acid and Diluted 30% Tri-butyl Phosphate in the Presence of Simple Hydroxamic Acids  

SciTech Connect (OSTI)

Formo- and aceto-hydroxamic acids are very effective reagents for stripping tetravalent actinide ions such as Np(IV) and Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Np(IV) in the presence of these hydroxamate ions have now been accumulated and trends established. Stability constants for aceto-hydroxamate complexes of Np(IV) and Np(V) ions have also been determined in a perchlorate medium, and these reaffirm the affinity of hydroxamate ligands for actinide (IV) ions over actinyl (V,VI) ions.

Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.; May, Iain

2008-01-15T23:59:59.000Z

406

An evaluation of the 3M Organic Vapor Monitor #3500 as a short term exposure limit sampling device for acetone, methyl ethyl ketone, and methyl iso butyl ketone  

E-Print Network [OSTI]

. An exploded view of the monitor is illustrated in Figure 1. The theory of diffusive sampling considers a concentration gra- dient between the ambient air and the adsorbent to be the driving force for sampling. For the adsorption to be controlled by diffu...AN EVALUATION OF THE 3M ORGANIC VAPOR MONITOR 43500 AS A SHOR'I TERM EXPOSURE LIMIT SAMPLING DEVICE FOR ACETONE, METHYL ETHYL KETONE, AND METHYL ISO BUTYL KETONE A Thesis by LLOYD B. ANDREW III Submitted to the Graduate College of Texas ASM...

Andrew, Lloyd B.

2012-06-07T23:59:59.000Z

407

A New Flow Control Technique Using Diluted Epinephrine in the N-butyl-2-cyanoacrylate Embolization of Visceral Artery Pseudoaneurysms Secondary to Chronic Pancreatitis  

SciTech Connect (OSTI)

Although n-butyl-2-cyanoacrylate (NBCA) has been used as an effective liquid embolization material, its indication for pseudoaneurysms has seemingly been limited because of the technical difficulties of using NBCA, such as reflux to the parent artery and causing significant infarction. Thus, considerable skill in using NBCA or a device to control blood flow during its polymerization is required to achieve embolization without severe complications. We report our new technique for controlling blood flow using diluted epinephrine in transcatheter arterial NBCA embolization of five pseudoaneurysms in four cases secondary to hemosuccus pancreaticus.

Morishita, Hiroyuki, E-mail: hmorif@koto.kpu-m.ac.jp [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Yamagami, Takuji [Kyoto Prefectural University of Medicine, Department of Radiology, Graduate School of Medical Science (Japan); Takeuchi, Yoshito [National Cancer Center, Division of Diagnostic Radiology (Japan); Matsumoto, Tomohiro; Asai, Shunsuke; Masui, Koji [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Sato, Hideki [Japan Red Cross Kyoto Daiichi Hospital, Department of Gastroenterology (Japan); Taniguchi, Fumihiro [Japan Red Cross Kyoto Daiichi Hospital, Department of Surgery (Japan); Sato, Osamu [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Nishimura, Tsunehiko [Kyoto Prefectural University of Medicine, Department of Radiology, Graduate School of Medical Science (Japan)

2012-08-15T23:59:59.000Z

408

Conformational free energy of melts of ring-linear polymer blends  

Science Journals Connector (OSTI)

The conformational free energy of ring polymers in a blend of ring and linear polymers is investigated using the bond-fluctuation model. Previously established scaling relationships for the free energy of a ring polymer are shown to be valid only in the mean-field sense, and alternative functional forms are investigated. It is shown that it may be difficult to accurately express the total free energy of a ring polymer by a simple scaling argument, or in closed form.

Gopinath Subramanian and Sachin Shanbhag

2009-10-21T23:59:59.000Z

409

The Pittsburg & Midway Coal Mining Co. Kemmerer Mine coal blending facility  

SciTech Connect (OSTI)

The Pittsburg & Midway Coal Mining Company`s Kemmerer Mine recently completed a new coal processing facility for blending the mine`s low, medium, and high sulfur coals to meet the needs of our customers. This article will discuss the geology; mining and market conditions that led to the need for this facility; design considerations; the construction; and the system`s controls and performance.

Mulhall, K.; Crank, G. [Pittsburg & Midway Coal Mining Co., Kemmerer, WY (United States)

1995-08-01T23:59:59.000Z

410

Ab initio study of phase transition of boron nitride between zinc-blende and rhombohedral structures  

SciTech Connect (OSTI)

Boron nitride has polymorphs such as zinc-blende (c-BN), wurtzite (w-BN), rhombohedral (r-BN), and graphite-like (h-BN) forms. We simulate the direct conversion of r-BN to c-BN through electronic excitation. In our calculation, the conversion is made possible by increasing the hole concentration to over 0.06/atom. This conversion should be experimentally possible by hole-doping via an electric double layer transistor (EDLT) or capacitor.

Nishida, S.; Funashima, H.; Sato, K.; Katayama-Yoshida, H. [Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan)

2013-12-04T23:59:59.000Z

411

Peer Evaluation of Video Lab Reports in a Blended Introductory Physics Course  

E-Print Network [OSTI]

The Georgia Tech blended introductory calculus-based mechanics course emphasizes scientific communication as one of its learning goals, and to that end, we gave our students a series of four peer-evaluation assignments intended to develop their abilities to present and evaluate scientific arguments. Within these assignments, we also assessed students' evaluation abilities by comparing their evaluations to a set of expert evaluations. We summarize our development efforts and describe the changes we observed in student evaluation behavior.

Douglas, Scott S; Aiken, John M; Thoms, Brian D; Greco, Edwin F; Caballero, Marcos D; Schatz, Michael F

2014-01-01T23:59:59.000Z

412

Hydrothermal Treatment of a Sub-bituminous Coal and Its Use in Coking Blends  

Science Journals Connector (OSTI)

Crucible coking determinations suggest that hydrothermal treatment can greatly increase the coke strength and the particle coke strength after reaction toward CO2 and decrease the coke reactivity when the hydrothermally treated coals were used in the coal blends instead of the raw coal. ... While the cokes from the crucible coking experiments were subjected to 800 rotations at a speed of 25 rpm, the weight percent of coke particles (>0.2 ... The coal charges were coked in the lab. ...

Hengfu Shui; Ye Wu; Zhicai Wang; Zhiping Lei; Changhui Lin; Shibiao Ren; Chunxiu Pan; Shigang Kang

2012-11-26T23:59:59.000Z

413

Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends  

SciTech Connect (OSTI)

Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

Storey, John Morse [ORNL] [ORNL; Lewis Sr, Samuel Arthur [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL; Barone, Teresa L [ORNL] [ORNL; Eibl, Mary A [ORNL] [ORNL; Nafziger, Eric J [ORNL] [ORNL; Kaul, Brian C [ORNL] [ORNL

2014-01-01T23:59:59.000Z

414

In-cylinder pressure characteristics of a CI engine using blends of diesel fuel and methyl esters of beef tallow  

SciTech Connect (OSTI)

A Cummins N14-410 diesel engine was operated on 12 fuels produced by blending methyl tallowate, methyl soyate, and ethanol with no. 2 diesel fuel. Engine in-cylinder pressure data were used to evaluate engine performance. Peak cylinder pressures for each fuel blend at all engine speeds were lower than peak pressure for diesel fuel with the exception of the 80% diesel, 13% methyl tallowate, and 7% ethanol; and the 80% diesel, 6.5% methyl tallowate, 6.5% methyl soyate and 7% ethanol blends. The indicated mean effective pressure (IMEP) values for all fuel blends were less than for diesel fuel. The differences in IMEP values correlated with differences in power output of the engine. Similarly, maximum rates of pressure rise for most fuel blends were less than for diesel fuel. It was concluded that the fuel blends used in this study would have no detrimental long-term effects on engine performance, wear, and knock. 6 refs., 4 figs., 7 tabs.

Ali, Y.; Hanna, M.A.; Borg, J.E. [Univ. of Nebraska, Lincoln, NE (United States)

1996-05-01T23:59:59.000Z

415

Investigation on combustion characteristics of crude rice bran oil methyl ester blend as a heavy duty automotive engine fuel  

Science Journals Connector (OSTI)

In the present work, an attempt was made to test the suitability of crude rice bran oil methyl ester (CRBME) blend as a heavy duty automotive engine fuel. A four stroke, six cylinder direct injection 117.6 kW turbo-charged compression ignition (CI) engine was used for the work. The operation of the engine with CRBME blend showed that the peak pressure increased with lower maximum rate of pressure rise and maximum heat release rate with shorter delay period. Burning rate of the CRBME blend was slower and required a higher crank angle to complete the combustion cycle when compared to diesel. The brake thermal efficiency of the CRBME blend was lower than that of diesel at all speeds except at 2300rpm. As the measured combustion and performance parameters for CRBME blend differs only by a smaller magnitude when compared with diesel, this investigation ensures the suitability of the CRBME blend as fuel for heavy duty automotive engine without any design modifications [Received: August 12, 2010; Accepted: August 29, 2010

S. Saravanan; G. Nagarajan; S. Sampath

2011-01-01T23:59:59.000Z

416

Recovery and Blend-Down Uranium for Beneficial use in Commercial Reactors - 13373  

SciTech Connect (OSTI)

In April 2001 the Department of Energy (DOE) and the Tennessee Valley Authority (TVA) signed an Interagency Agreement to transfer approximately 33 MT of off-specification (off-spec) highly enriched uranium (HEU) from DOE to TVA for conversion to commercial reactor fuel. Since that time additional surplus off-spec HEU material has been added to the program, making the total approximately 46 MT off-spec HEU. The disposition path for approximately half (23 MT) of this 46 MT of surplus HEU material, was down blending through the H-canyon facility at the Savannah River Site (SRS). The HEU is purified through the H-canyon processes, and then blended with natural uranium (NU) to form low enriched uranium (LEU) solution with a 4.95% U-235 isotopic content. This material was then transported to a TVA subcontractor who converted the solution to uranium oxide and then fabricated into commercial light water reactor (LWR) fuel. This fuel is now powering TVA reactors and supplying electricity to approximately 1 million households in the TVA region. There is still in excess of approximately 10 to 14 MT of off-spec HEU throughout the DOE complex or future foreign and domestic research reactor returns that could be recovered and down blended for use in either currently designed light water reactors, ?5% enriched LEU, or be made available for use in subsequent advanced 'fast' reactor fuel designs, ?19% LEU. (authors)

Magoulas, Virginia [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)

2013-07-01T23:59:59.000Z

417

Methylal and Methylal-Diesel Blended Fuels from Use In Compression-Ignition Engines  

SciTech Connect (OSTI)

Gas-to-liquids catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude derived fuels. Methylal (CH{sub 3}-O-CH{sub 2}-O-CH{sub 3}) also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins 85.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions. Substantial reductions of particulate matter emissions h ave been demonstrated 3r IO to 30% blends of methylal in diesel fuel. This research indicates that methylal may be an effective blendstock for diesel fuel provided design changes are made to vehicle fuel handling systems.

Keith D. Vertin; James M. Ohi; David W. Naegeli; Kenneth H. Childress; Gary P. Hagen; Chris I. McCarthy; Adelbert S. Cheng; Robert W. Dibble

1999-05-05T23:59:59.000Z

418

Source: Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol Blends.  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

A2: Manufacturer Compatibility with Ethanol Blends (Other Equipment). September 2013. A2: Manufacturer Compatibility with Ethanol Blends (Other Equipment). September 2013. Manufacturer Compatibility with Ethanol Blends (Other Equipment) Manufacturer Product Model Ethanol Compatibility Bravo Systems Fiberglass Fittings Series F, FF, FPE, FR, F Retrofit- S, RPE Retrofit-Si, F BLR, F D-BLR-S, TBF E0-E100 Bravo Systems Spill Buckets B3XX E0-E100 Bravo Systems Tank Sumps & Covers B4XX E0-E100 Bravo Systems Transition Sumps (planter, walkover, H-20 rated) B5XX, B6XX, B7XX, B8XX E0-E100 Bravo Systems Transition Sumps B8XX E0-E100 Bravo Systems Under Dispenser Contain- ment Sumps B7XXX, B8XXX, B9XXX E0-E100 Brugg Pipes FLEXWELL-HL, SECON-X, NIROFLEX, LPG E0-E100 KPS Petrol Pipe Systems Pipes and Associated Products All single- and double-wall plastic pipes, flexible

419

Role of dopant counter-anion functionality in polyaniline salts/blends and implications to morphology  

SciTech Connect (OSTI)

In this paper, wide and small angle X-ray scattering techniques (i.e., WAXS and SAXS) and light microscopy are used to characterize the influence of the dopant`s structure on the morphology of both polyaniline salt and blend. In an attempt to modify the morphology of the PANI-ES, the authors have evaluated a number of doping acids (i.e., methane sulfonic acid (HMSA), butane sulfonic acid (HBSA), dodecyl benzene sulfonic acid (HDBSA) and camphor sulfonic acid (HCSA)) that vary in size and polarity to better understand the role of the acid in PANI-ES`s morphology and the resulting electrical conductivity. These salts were solution blended with polycaprolactam using hexafluoro-2-propanol (HFIP) as a solvent. The other goal was to investigate the effect of the counter-anion structure on the nature of the phase separated PANI-ES network. The shape of the PANI-ES network in the host polycaprolactam has important implications on the nature of conduction behavior and the final electrical conductivity of the blend.

Hopkins, A.R.; Rasmussen, P.G. [Univ. of Michigan, Ann Arbor, MI (United States); Basheer, R.A. [General Motors Research and Development Center, Warren, MI (United States). Polymers Dept.; Annis, B.K.; Wignall, G.D. [Oak Ridge National Lab., TN (United States)

1997-03-01T23:59:59.000Z

420

NMOG Emissions Characterization and Estimation for Vehicles Using Ethanol-Blended Fuels  

SciTech Connect (OSTI)

Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were applied to the measured NMHC emissions from the mid-level ethanol blends testing program and the results compared against the measured NMOG emissions. The results show that the composite FTP NMOG emissions estimate has an error of 0.0015 g/mile {+-}0.0074 for 95% of the test results. Estimates for the individual phases of the FTP are also presented with similar error levels. A limited number of tests conducted using the LA92, US06, and highway fuel economy test cycles show that the FTP correlation also holds reasonably well for these cycles, though the error level relative to the measured NMOG value increases for NMOG emissions less than 0.010 g/mile.

Sluder, Scott [ORNL; West, Brian H [ORNL

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Ethoxyresorufin O-deethylase induction of polychlorinated diphenyl ethers in H4IIE cells  

SciTech Connect (OSTI)

The ethoxyresorufin O-deethylase (EROD) induction potencies of 29 polychlorinated diphenyl ethers were determined in the rat hepatoma H4IIE cell bioassay and compared with that of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). Two polychlorinated biphenyls (PCBs) were included as additional reference substances. PCDE congeners tested were PCDEs 47, 66, 77, 85, 99, 105, 118, 126, 128, 137, 138, 140, 147, 153, 154, 156, 157, 167, 170, 180, 181, 182, 190, 194, 195, 196, 197, 203 and 206. The purity of these congeners was > 99%. Because several of these congeners induced EROD activity when tested at high concentrations, the amount of PCDD and PCDF impurities of these active PCDEs was determined by gas chromatography/mass spectrometry. The activity of the active PCDEs was concluded to be mainly due to contamination with 2,3,7,8-chloro substituted PCDFS, because after an additional clean-up on a Florisil column, which removes PCDDs and PCDFs, only three PCDEs (156, 180, 194) remained active. The potencies of PCDEs 156, 180 and 194 (TEF {approximately} 10{sup {minus}6}), however, were about 100-fold less than that of PCB 77 (TEF {approximately} 10{sup {minus}4}). The poor induction potencies of the non- and mono-ortho-PCDEs indicates that PCDEs do not have structure-activity relationships analogous to those of PCBs. If the authors use EROD inducing potency in H4IIE cells as a relative measure of potential Ah receptor-mediated toxic potency, the PCDEs in the study would be expected to be less toxic than analogous PCBs and considerably less-toxic than certain PCDDs and PCDFs.

Koistinen, J.; Sanderson, J.T.; Giesy, J.P. [Michigan State Univ., East Lansing, MI (United States); Nevalainen, T.; Paasivirta, J. [Univ. of Jyvaskyla (Finland)

1995-12-31T23:59:59.000Z

422

Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization  

SciTech Connect (OSTI)

Carbon-oxygen bonds are the primary inter-monomer linkages lignin polymers in plant cell walls, and as such, catalyst development to cleave these linkages is of paramount importance to deconstruct biomass to its constituent monomers for the production of renewable fuels and chemicals. For many decades, acid catalysis has been used to depolymerize lignin. Lignin is a primary component of plant cell walls, which is connected primarily by aryl-ether linkages, and the mechanism of its deconstruction by acid is not well understood, likely due to its heterogeneous and complex nature compared to cellulose. For effective biomass conversion strategies, utilization of lignin is of significant relevance and as such understanding the mechanisms of catalytic lignin deconstruction to constituent monomers and oligomers is of keen interest. Here, we present a comprehensive experimental and theoretical study of the acid catalysis of a range of dimeric species exhibiting the b-O-4 linkage, the most common inter-monomer linkage in lignin. We demonstrate that the presence of a phenolic species dramatically increases the rate of cleavage in acid at 150 degrees C. Quantum mechanical calculations on dimers with the para-hydroxyl group demonstrate that this acid-catalyzed pathway differs from the nonphenolic dimmers. Importantly, this result implies that depolymerization of native lignin in the plant cell wall will proceed via an unzipping mechanism wherein b-O-4 linkages will be cleaved from the ends of the branched, polymer chains inwards toward the center of the polymer. To test this hypothesis further, we synthesized a homopolymer of b-O-4 with a phenolic hydroxyl group, and demonstrate that it is cleaved in acid from the end containing the phenolic hydroxyl group. This result suggests that genetic modifications to lignin biosynthesis pathways in plants that will enable lower severity processes to fractionate lignin for upgrading and for easier access to the carbohydrate fraction of the plant cell wall.

Sturgeon, M. R.; Kim, S.; Chmely, S. C.; Foust, T. D.; Beckham, G. T.

2013-01-01T23:59:59.000Z

423

The lightness of being: mass, ether, and unification of the forces  

SciTech Connect (OSTI)

How can an electron be both a wave and a particle? At the same time? Because it is a quantum field. That key insight seems to be underappreciated, given the awe and mysticism that permeate most nontechnical discussions of modern physics. Perhaps the root of the problem is that most popularizations of quantum mechanics and of particle physics shy away from quantized fields, the natural language for microscopic phenomena. In 'The Lightness of Being: Mass, Ether, and the Unification of Forces', Frank Wilczek confronts quantum field theory head on, demystifying not only wave-particle duality but also the origin of mass for hadrons (that is, everyday matter). Wilczek is the Herman Feshbach Professor of Physics at MIT and a co-recipient of the 2004 Nobel Prize in Physics. His research has spanned almost all aspects of theoretical particle physics, with significant forays into condensed-matter physics and dense nuclear matter (condensed quark matter, one might say). Recurring themes are the richness of quantum chromodynamics (QCD) and the alluring ideas of unification. His breadth and depth make him a sought after speaker for colloquia and public lectures. Wilczek also contributes an occasional Reference Frame column to 'Physics Today'. The material in 'The Lightness of Being' reflects the scope of the author's research. The book consists of three parts: the quantum fields of QCD (the ether that makes mass), gravitation (the ether that feels mass), and unification. Part 1, which traces notions of mass from Isaac Newton's time through theoretical and computational results of the past 40 years, is the most substantial and original; it is rich, modern, and rooted in observed phenomena. Part 2 continues in the same vein as it connects gravity, also an observed phenomenon, to QCD. Part 3 is more conventional, for a popularization of particle physics, in its focus on speculative ideas that (still) await direct experimental tests. Readers of 'Physics Today' will know that Wilczek can write with wit, grace, and an uncanny facility for using lightweight language to express heavy-duty ideas. They will find much of that kind of writing in 'The Lightness of Being'. Wilczek addresses subtle ideas with vim and vigor. He avoids some of the jargon of quantum field theory; for example, he calls the vertex in a Feynman diagram a hub. In more ambitious terminology, he refers to space-filling, everfluctuating quantum fields--be they electrons, quarks, gluons, or gravity--as 'the Grid'. The term is supposed to be short and familiar, evoking the ubiquitous electric grid (and soon-to-beubiquitous computing grid). It also, for the expert, cleverly alludes to lattice gauge theory. Indeed, after vividly explaining how the dynamics of QCD and the constraints of Heisenberg uncertainty conspire to create mass from the Grid, Wilczek emphasizes that the picture is backed by lattice QCD computations of 'heroic' proportions. Unfortunately, too much of 'The Lightness' is laden with clunky affectation: silly names (a pulsed electron accelerator is called the 'ultrastroboscopic nanomicroscope'), sophomoric jokes ('hadron' is 'not a typo'), references to pop culture (Wilczek might have called quantum fields 'the Matrix, but the sequels tarnished that candidate'), and many pointless footnotes. In a public lecture the audience may guffaw at such jokes, but on the printed page they fall flat. Wilczek explains physics so well that the inappropriate humor is the biggest unexplained puzzle of the book. It is fine to be silly, even crude, as long as the reader's path to understanding is made easier. A joke can inform with an unexpected perspective or simply give the mind a pause to refresh. Some of the humor achieves such aims, but too many gags impede the pace of the otherwise fine exposition. Three appendices, a glossary, and a set of endnotes are crisp and sober. They are excellent. 'The Lightness of Being' is not unbearable, but it is weighed down with too much clutter to rank as a masterpiece. It's a pity: Wilczek's best writing--some of it in this book--is l

Kronfeld, Andreas S.

2009-03-01T23:59:59.000Z

424

Emissions and engine performance from blends of soya and canola methyl esters with ARB {number_sign}2 diesel in a DCC 6V92TA MUI engine  

SciTech Connect (OSTI)

A Detroit Diesel 6V92TA MUI engine was operated on several blends of EPA No. 2 diesel, California ARB No. 2 diesel, soya methyl ester (SME) and canola methyl ester (CME). Various fuels and fuel blend characteristics were determined and engine emissions from these fuels and blends were compared. Increasing percentages of SME and CME blended with either ARB or EPA diesels led to increased emissions of NO{sub x}, CO{sub 2} and soluble particulate matter. Also noted were reductions in total hydrocarbons, CO and insoluble particulate matter. Chassis dynamometer tests conducted on a 20/80 SME/ARB blend showed similar emissions trends. The data suggest that certain methyl ester/No. 2 diesel blends in conjunction with delays in engine timing and technologies that reduce the soluble fraction of particulate emissions merit further exploration as emissions reducing fuel options for North American mass transits (except in California, which mandates ARB diesel).

Spataru, A.; Romig, C.

1995-12-31T23:59:59.000Z

425

Emissions and engine performance from blends of soya and canola methyl esters with ARB No. 2 diesel in a DDC 6V92TA MUI engine  

SciTech Connect (OSTI)

A Detroit Diesel 6V92TA MUI engine was operated on several blends of EPA No. 2 diesel, soya methyl ester (SME) and canola methyl ester (CME). Various fuels and fuel blend characteristics were determined and engine emissions from these fuels and blends were compared. Increasing percentages of SME and CME blended with either ARB or EPA diesels led to increased emissions of NO{sub x}, CO{sub 2} and soluble particulate matter. Also noted were reductions in total hydrocarbons, CO and insoluble particulate matter. Chassis dynamometer tests conducted on a 20/80 SME/ARB blend showed similar emission trends. The data suggest that certain methyl ester/No. 2 diesel blends in conjunction with technologies that reduce the soluble fraction of particulate emissions merit further exploration as emissions reducing fuel options for North American mass transit sectors (except California, which mandates ARB diesel).

Spataru, A.; Romig, C. [ADEPT Group, Inc., Los Angeles, CA (United States)

1995-11-01T23:59:59.000Z

426

Optimization of combustion bowl geometry for the operation of kapok biodiesel – Diesel blends in a stationary diesel engine  

Science Journals Connector (OSTI)

Abstract The purpose of this research work is to optimize the combustion bowl geometry of a single cylinder stationary diesel engine for the effective operation of KME (kapok methyl ester) – diesel blends. Considering that the reported design modification would render the benefit of adaptation of higher blends of KME, in this study, two different combustion chamber geometries such as TRCC (trapezoidal combustion chamber) and TCC (toroidal combustion chamber) were chosen in addition to the convention design of HCC (hemispherical combustion chamber). In the experimental investigation, suitable blends such as B25 (25% KME + 75% diesel), B50 (50% KME + 50% diesel), B75 (75% KME + 25% diesel) and B100 (100% KME) were tested in a diesel engine with various combustion chamber geometries as mentioned above. Based on the results obtained from this study, TCC was shown to exhibit better performance and emission than TRCC and HCC for all test blends. Further, when compared to diesel, B25 and B50 were found to be the optimum blends with HCC and TCC, respectively, while TRCC seldom evinced better engine characteristics for any of the blends. Categorically, B50 showed a 5.2% increase in BTE (brake thermal efficiency) than diesel with TCC, whereas emissions such as CO (carbon monoxide) and smoke were reduced by 15.7% and 7.8%, respectively, with a comparable NOX (nitrogen oxides) emission with diesel. Similarly, combustion for B50 with TCC was found to be better than diesel, manifesting an increase in maximum heat release rate that that of diesel. Conclusively, from the experimental study, TCC was recognized as an ideal choice of combustion chamber design for the operation of blends up to B50 in a diesel engine.

S. Vedharaj; R. Vallinayagam; W.M. Yang; C.G. Saravanan; P.S. Lee

2015-01-01T23:59:59.000Z

427

Distribution of glycerol ether lipids in the oxygen minimum zone of the Eastern Tropical North Pacific Ocean  

Science Journals Connector (OSTI)

Abstract The distributions of microbial glycerol ether lipids in suspended particulate matter in the oxygen minimum zone (OMZ) of the Eastern Tropical North Pacific Ocean (ETNP) were investigated. Nine groups of glycerol ether core lipids were detected and quantified: isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) (iso-GDGTs), isoprenoid glycerol dialkanol diethers (iso-GDDs) and hydroxylated isoprenoid \\{GDGTs\\} and \\{GDDs\\} (OH-GDGTs and OH-GDDs) of archaeal origin; branched glycerol dialkyl glycerol tetraethers (br-GDGTs) of bacterial origin and overly branched \\{GDGTs\\} (OB-GDGTs), sparsely branched \\{GDGTs\\} (SB-GDGTs), hybrid isoprenoid/branched \\{GDGTs\\} (IB-GDGTs) and a tentatively assigned H-shaped GDGT (H-1020) of unknown biological origin. The archaeal iso-GDGTs were the most abundant core lipids (89% of total), followed by iso-GDDs (4%), br-GDGTs (2%) and OH-GDGTs (1%). Archaeal intact polar \\{GDGTs\\} (IP GDGTs), including both mono- and diglycosidic iso-GDGTs, had depth profiles similar to OH-GDGTs and OH-GDDs, with a maximum concentration in the upper OMZ and secondary peaks in the mid and lower OMZ, suggesting similar but multiple planktonic sources. Core lipids of iso-GDGTs and other glycerol ethers showed deviating concentration profiles compared with IP \\{GDGTs\\} and OH-GDGTs and were most abundant in the mid OMZ. This is the first report of OH-GDDs, OB-GDGTs, SB-GDGTs, IB-GDGTs and H-1020 in the marine water column and the distribution patterns of these “orphan lipids” suggest that anaerobic planktonic microbes are their main source.

Sitan Xie; Xiao-Lei Liu; Florence Schubotz; Stuart G. Wakeham; Kai-Uwe Hinrichs

2014-01-01T23:59:59.000Z

428

E-Print Network 3.0 - allyl methacrylate styrene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetrachloroethylene () Cyclohexanol () Cyclohexanone ()1- 1-Butyl alcohol ()2... ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

429

TABLE33.CHP:Corel VENTURA  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

430

TABLE34.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

431

Selection of best biodiesel blend for IC engines: an integrated approach with FAHP-TOPSIS and FAHP-VIKOR  

Science Journals Connector (OSTI)

The aim of this study is to select the best blend using multi-criteria decision-making (MCDM) technique. The six alternative fuel blends diesel, B20, B40, B60, B80 and B100 are prepared by varying the amount of diesel in biodiesel. Brake thermal efficiency (BTE), exhaust gas temperature (EGT), oxides of nitrogen (NOx), smoke, hydrocarbon (HC), carbon monoxide (CO) and carbon dioxide (CO2) are considered as evaluation criteria. A single cylinder, constant speed, direct injection diesel engine (4.4 kW) was used for exploratory analysis of evaluation criteria at different load conditions. Two models fuzzy analytical hierarchy process-technique for order preference by similarity to ideal solution (FAHP-TOPSIS) and VlseKriterijumska Optimizacija I Kompromisno Resenje (FAHP-VIKOR, in Serbian) are proposed to evaluate the best blend. Here, the FAHP is used to analyse the structure of best blend selection and to determine the weights of the criteria. The TOPSIS and VIKOR are used to obtain the final ranking of the blend. [Received: July 10, 2012; Accepted: October 16, 2012].

G. Sakthivel; M. Ilangkumaran; G. Nagarajan; P. Shanmugam

2013-01-01T23:59:59.000Z

432

Motor Gasoline Outlook and State MTBE Bans  

Gasoline and Diesel Fuel Update (EIA)

Motor Gasoline Outlook Motor Gasoline Outlook and State MTBE Bans Tancred Lidderdale Contents 1. Summary 2. MTBE Supply and Demand 3. Ethanol Supply 4. Gasoline Supply 5. Gasoline Prices A. Long-Term Equilibrium Price Analysis B. Short-Term Price Volatility 6. Conclusion 7. Appendix A. Estimating MTBE Consumption by State 8. Appendix B. MTBE Imports and Exports 9. Appendix C. Glossary of Terms 10. End Notes 11. References 1. Summary The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending State bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year. Three impending State bans on MTBE blending could significantly affect gasoline

433

Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .  

SciTech Connect (OSTI)

The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

Wallner, T. (Energy Systems)

2011-08-01T23:59:59.000Z

434

Study on ash deposition under oxyfuel combustion of coal/biomass blends  

Science Journals Connector (OSTI)

Combustion in an O2/CO2 mixture (oxyfuel) has been recognized as a promising technology for CO2 capture as it produces a high CO2 concentration flue gas. Furthermore, biofuels in general contribute to CO2 reduction in comparison with fossil fuels as they are considered CO2 neutral. Ash formation and deposition (surface fouling) behavior of coal/biomass blends under O2/CO2 combustion conditions is still not extensively studied. Aim of this work is the comparative study of ash formation and deposition of selected coal/biomass blends under oxyfuel and air conditions in a lab scale pulverized coal combustor (drop tube). The fuels used were Russian and South African coals and their blends with Shea meal (cocoa). A horizontal deposition probe, equipped with thermocouples and heat transfer sensors for on line data acquisition, was placed at a fixed distance from the burner in order to simulate the ash deposition on heat transfer surfaces (e.g. water or steam tubes). Furthermore, a cascade impactor (staged filter) was used to obtain size distributed ash samples including the submicron range at the reactor exit. The deposition ratio and propensity measured for the various experimental conditions were higher in all oxyfuel cases. The SEM/EDS and ICP analyses of the deposit and cascade impactor ash samples indicate K interactions with the alumina silicates and to a smaller extend with Cl, which was all released in the gas phase, in both the oxyfuel and air combustion samples. Sulfur was depleted in both the air or oxyfuel ash deposits. S and K enrichment was detected in the fine ash stages, slightly increased under air combustion conditions. Chemical equilibrium calculations were carried out to facilitate the interpretation of the measured data; the results indicate that temperature dependence and fuels/blends ash composition are the major factors affecting gaseous compounds and ash composition rather than the combustion environment, which seems to affect the fine ash (submicron) ash composition, and the ash deposition mechanisms.

L. Fryda; C. Sobrino; M. Cieplik; W.L. van de Kamp

2010-01-01T23:59:59.000Z

435

Optical transitions in semiconductor superlattices with zinc-blende structure in the k?p approximation  

Science Journals Connector (OSTI)

Transition-matrix elements for superlattices consisting of materials with the zinc-blende structure are presented in analytical form in the k?p approximation including the ?6, ?7, and ?8 bands. The resulting selection rules for cases where the magnetic field is absent, and where the magnetic field is applied perpendicular to the superlattice layers, are discussed. The results can be used for type-I, -II, and -III superlattices. They can also be used for other systems, such as a single quantum well.

H. Luo and J. K. Furdyna

1990-03-15T23:59:59.000Z

436

Combustion and Emissions Characterization of Biodiesel Blends in a City-Car Engine  

Science Journals Connector (OSTI)

Whereas in the available literature, most of the researches addressed the multicylinders diesel engine of large displacement;(7, 22-27) only some works have investigated the light duty engines, designed for agricultural purpose and mainly tested for a fixed value of the engine speed. ... Rakopoulos, C. D.; Antonopoulos, K. A.; Rakopoulos, D. C.; Hountalas, D. T.; Giakoumis, E. G.Comparative performance and emissions study of a direct injection Diesel engine using blends of diesel fuel with vegetable oils or bio-diesels of various origins Energy Convers. ... Heywood, J. B. Internal combustion engine fundamentals; Mcgraw-Hill: New York, 1988. ...

Giancarlo Chiatti; Ornella Chiavola; Fulvio Palmieri; Stefano Albertini

2014-07-06T23:59:59.000Z

437

Preliminary report on blending strategies for inert-matrix fuel recycling in LWRs.  

SciTech Connect (OSTI)

Various recycle strategies have been proposed to manage the inventory of transuranics in commercial spent nuclear fuel (CSNF), with a particular goal of increasing the loading capacity of spent fuel and reprocessing wastes in the Yucca Mountain repository. Transuranic recycling in commercial LWRs can be seen as a viable means of slowing the accumulation of transuranics in the nationwide CSNF stockpile. Furthermore, this type of approach is an important first step in demonstrating the benefits of a nuclear fuel cycle which incorporates recycling, such as envisioned for Generation-IV reactor systems under development. Recycling strategies of this sort are not proposed as an attempt to eliminate the need of a geologic nuclear waste repository, but as a means to enhance the usefulness of the repository currently under construction in the U.S., perhaps circumventing the need for a second facility. A US-DOE Secretarial recommendation on the need for the construction of a second geologic repository is required by 2010. The Advanced Fuel Cycle Initiative (AFCI) has supported a breadth of work to evaluate the ideal transuranic separation and recycle strategy. Previous AFCI studies of LWR-based transmutation have considered the benefits of homogeneously recycling plutonium, plutonium and neptunium, and all transuranic (TRU) species. A study of a wide range of hypothetical separation schemes (Pu, Pu+Np, Pu+Np+Am, etc.) with multi-recycling has also been performed, focusing on the proliferation resistance of the various fuel cycles and fuel handling issues. The direct recycle of the recovered TRU from spent inert-matrix fuel (IMF) into new IMF was found to be quite limited due to the rapid burndown of the fissile plutonium. The IMF is very effective at destroying the fissile fraction of the TRU with destruction rates in excess of 80% of the fissile material without recycling the IMF. Blending strategies have been proposed to mitigate the rapid burndown of the fissile plutonium by mixing high fissile feed from new sources (e.g., spent UO{sub 2} pins) with the low fissile material recovered from the recycled transmutation fuel. The blending of the fuels is anticipated to aid the multi-recycle of the transuranics. A systematic study of blending strategies (for both IMF and MOX) has been initiated and is currently ongoing. This work extends the previous study that considered separation strategies for plutonium, neptunium, and americium recycling in MOX, CORAIL, and IMF{sub 6} by considering blending schemes and approach to continuous recycle. Plutonium and americium are recycled in order to reduce the intermediate term (100 to 1500 years after spent fuel irradiation) decay heat of the disposed waste which accounts for the bulk of the repository heating. Since the long-term released dose from the repository is dominated by neptunium, it is sensible to consume it by transmutation in a reactor, as well. Curium accounts for {approx}0.6% of the TRU mass in spent UO{sub 2} fuel ({approx}0.008% of the heavy metal), but does constitute significantly higher fractions in spent transmutation fuels. This initial evaluation will focus on blending strategies for the multirecycling of Pu+Np+Am. The impact of curium recycle will be investigated as part of the systematic study of blending strategies. The initial study focuses on understanding a simple strategy for IMF recycle and blending. More complex strategies (i.e., heterogeneous assemblies) will be evaluated later in the year, including enriched uranium support options. Currently, a preliminary study of a serial blending strategy has been performed in order to evaluate the impact of blending on the performance of the IMF recycle and to evaluate the potential for continuous or infinite recycle. The continuous recycle of Pu+Np+Am in IMF would allow for complete destruction of all heat contributing actinides in the same LWRs that originally produced them. The only transuranics sent to the repository would be those lost in reprocessing and curium if it is not eventually recycled.

Hoffman, E. A.; Nuclear Engineering Division

2005-04-29T23:59:59.000Z

438

The Use of Triangular-Shaped PV Arrays to Better Blend into Historical Structures  

Broader source: Energy.gov [DOE]

When considering the installation of a solar PV array on a designated historical structure, placement of each solar panel requires extra attention to aesthetic considerations. If the solar array cannot be installed behind the structure or “hidden” on a roof plane that is not visible from the public street or sidewalk, it can sometimes be installed as an architectural feature that blends into the historical structure. One way to do this is to utilize triangular-shaped PV panels that conform with the building’s roof lines.

439

Phase identification and interfacial transitions in ternary polymer blends by ToF-SIMS  

Science Journals Connector (OSTI)

Abstract Phase identification and the study of the interphase region in multi-component polymer blends with a chemically similar structure using conventional techniques is a challenge. In this work, the detailed morphological analysis of such systems is examined. A ternary blend comprised of poly butylene succinate (PBS); poly lactic acid (PLA); and polycaprolactone (PCL) with a partial wetting morphology is carefully selected since all three components are polyesters with low interfacial tensions. It will be shown that a novel technique by applying multivariate analysis (MVA) on time-of-flight secondary ion mass spectrometry (ToF-SIMS) data can effectively identify the complex phase structure, especially in blends with chemically similar components. Furthermore, for the first time for such systems, this technique provides detailed information about interfacial thicknesses and transitions. By employing the principal component analysis (PCA) method on the ToF-SIMS data of pure polymers, specific peaks with a certain molecular ion mass related to each polymer are determined. Using overlaid mappings on the surface of the blend by ToF-SIMS and selected ion masses to identify each polymer results in the differentiation of the various phases represented as a morphological image. In a second step, the multivariate curve resolution (MCR) method is used as a “self modeling curve resolution” for the recovery of pure components from a multi-component mixture when little or no prior information is available. Total pseudo-color RGB images of PBS/PLA/PCL show that PLA droplets unambiguously partially wet the PBS and PCL phases. Since each pixel from the analysis in the high lateral resolution image represents a 200 nm diameter, the interfacial transitions can also be studied for both PLA/PBS and PLA/PCL interfaces. The results show the concentration variation of phases across the interfaces. A complete trace line across the two interfaces (PLA/PBS and PLA/PCL) allows for the quantitative determination of interfacial thickness for the first time for such systems.

Sepehr Ravati; Suzie Poulin; Konstantinos Piyakis; Basil D. Favis

2014-01-01T23:59:59.000Z

440

Performance Synergies between Low-Temperature and High-Temperature Fischer?Tropsch Diesel Blends  

Science Journals Connector (OSTI)

With both LTFT and HTFT diesels being nontraditional, alternative diesel fuels that can be used directly in the current fuelling infrastructure, the objective of this study was to investigate the potential synergies in fuel properties with blends of LTFT diesel and HTFT DHT diesel. ... Regulated exhaust emissions measured over the engine dynamometer test cycle in grams of pollutant per unit of mechanical energy delivered by the engine (g/kW h) included total hydrocarbon (THC), generally referred to as HC, CO, carbon dioxide (CO2), NOx, and PM. ... However, the general consumer should most probably not be able to notice the difference in volumetric fuel consumption. ...

Delanie Lamprecht; Luis P. Dancuart; Kaveer Harrilall

2007-08-31T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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441

Powertrain Component Inspection from Mid-Level Blends Vehicle Aging Study  

SciTech Connect (OSTI)

The Energy Independence and Security Act of 2007 calls on the nation to significantly increase its use of renewable fuels to meet its transportation energy needs. The law expands the renewable fuel standard to require use of 36 billion gallons of renewable fuel by 2022. Given that ethanol is the most widely used renewable fuel in the U.S. market, ethanol will likely make up a significant portion of the 36-billion-gallon requirement. The vast majority of ethanol used in the United States is blended with gasoline to create E10-gasoline with up to 10% ethanol. The remaining ethanol is sold in the form of E85 - a gasoline blend with as much as 85% ethanol that can only be used in flexible-fuel vehicles (FFVs). Consumption of E85 is at present limited by both the size of the FFV fleet and the number of E85 fueling stations. Gasoline consumption in the United States is currently about 140 billion gallons per year; thus the maximum use of ethanol as E10 is only about 14 billion gallons. While the U.S. Department of Energy (DOE) remains committed to expanding the E85 infrastructure, that market represented less than 1% of the ethanol consumed in 2010 and will not be able to absorb projected volumes of ethanol in the near term. Because of these factors, DOE and others have been assessing the viability of using mid-level ethanol blends (E15 or E20) as a way to accommodate growing volumes of ethanol. The DOE Mid-Level Ethanol Blends Test Program has been under way since 2007, supported jointly by the Office of the Biomass Program and the Vehicle Technologies Program. One of the larger projects, the Catalyst Durability Study, or Vehicle Aging Study, will be completed early in calendar year 2011. The following report describes a subproject of the Vehicle Aging Study in which powertrain components from 18 of the vehicles were examined at Southwest Research Institute under contract to Oak Ridge National Laboratory (ORNL).

Shoffner, Brent [Southwest Research Institute, San Antonio; Johnson, Ryan [Southwest Research Institute, San Antonio; Heimrich, Martin J. [Southwest Research Institute, San Antonio; Lochte, Michael [Southwest Research Institute, San Antonio

2010-11-01T23:59:59.000Z

442

Exhaust particle characterization for lean and stoichiometric DI vehicles operating on ethanol-gasoline blends  

SciTech Connect (OSTI)

Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.

Storey, John Morse [ORNL] [ORNL; Barone, Teresa L [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL; Huff, Shean P [ORNL] [ORNL

2012-01-01T23:59:59.000Z

443

Use of Nonionic Poly(Ethylene glycol) p-Isooctyl-Phenyl Ether (Triton X-100) Surfactant Mobile Phases in the Thin-Layer Chromatography of Heavy-Metal Cations  

Science Journals Connector (OSTI)

......Article The analytical potential of poly(ethylene glycol) p-isooctyl-phenyl ether...40, March 2002 Use of Nonionic Poly(Ethylene glycol) p-Isooctyl-Phenyl Ether...Bidlingmeyer, S.N. Deming, W.P. Price, B. Sachok, and M. Petrusek. Retention......

Ali Mohammad; Eram Iraqi; Iftkhar Alam Khan

2002-03-01T23:59:59.000Z

444

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons  

Science Journals Connector (OSTI)

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons ... (1, 3-6) Methanol and derived dimethyl ether (DME) are also excellent fuels in internal combustion engines (ICE) and in a new generation of direct oxidation methanol fuel cells (DMFC), as well as convenient starting materials for producing light olefins (ethylene and propylene) and subsequently practically any derived hydrocarbon product. ... Methanol produced this way was used in the 19th century for lighting, cooking, and heating purposes but was later replaced by cheaper fuels, especially kerosene. ...

George A. Olah; Alain Goeppert; G. K. Surya Prakash

2008-12-08T23:59:59.000Z

445

Modeling of the simultaneous extraction of nitric acid and uranyl nitrate with tri-n-butyl phosphate. Application to extraction operation  

SciTech Connect (OSTI)

A mathematical model developed for the equilibrium HNO{sub 3}-UO{sub 2}(NO{sub 3}){sub 2}-tri-n-butyl phosphate (TBP)-diluent is the basis of the computation of distribution isotherms. The isotherms are used to study the influence of TBP concentration on two chosen operation parameters, distribution coefficients and number of theoretical stages, for the selected flow sheets. It is established that an increase in TBP concentration leads to a decrease in the number of theoretical stages for the extraction flow sheets but to their increase for the striping flow sheets. Given diagrams can be used to determine the efficiency of extraction processes. Agreement with available literature calculations on the number of theoretical stages supports the use of the model in the computation of distribution isotherms, of the system quoted above, in a wide range of nitric acid, uranyl nitrate, and TBP concentrations.

Comor, J.J.; Tolic, A.S.; Kopecni, M.M.; Petkovic, D.M. [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.] [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.

1999-01-01T23:59:59.000Z

446

Measurement of Turbulent Flame Speeds of Hydrogen and Natural Gas Blends (C1-C5 Alkanes) using a Newly Developed Fan-Stirred Vessel  

E-Print Network [OSTI]

in displacement speeds were observed for blends of NG2/H_(2) and CH_(4)/H_(2), thus validating the newly established experimental technique. Additionally, turbulent flame speeds of hydrogen and a generic, high-hydrogen-content syngas blend (50:50 H_(2):CO) were...

Ravi, Sankaranarayana

2014-05-06T23:59:59.000Z

447

Enzymatic Hydrolysis of Poly(lactide)s:? Effects of Molecular Weight, l-Lactide Content, and Enantiomeric and Diastereoisomeric Polymer Blending  

Science Journals Connector (OSTI)

Nonblended poly(l-lactide) (PLLA) films having different molecular weights and nonblended poly(lactide) (PLA) films, enantiomeric blend films from PLLA and poly(d-lactide) (PDLA), and diastereoisomeric blend films of poly(dl-lactide) (PDLLA) with either ...

Hideto Tsuji; Shinya Miyauchi

2001-04-24T23:59:59.000Z

448

A blending problem (Taha, Example 2.3-7, almost) An oil refinery has three stages of production: a distillation tower, which  

E-Print Network [OSTI]

of feedstock; and a blender unit which blends feedstock and gasoline stock (at no loss). (Note that "ONA blending problem (Taha, Example 2.3-7, almost) An oil refinery has three stages of production in feedstock (maximum 200,000 bbl/day) and produces gasoline stock with 98 ON at a rate of .5 bbl per bbl

Galvin, David

449

Morphological origin for the stratification of P3HT:PCBM blend film studied by neutron reflectometry  

SciTech Connect (OSTI)

Understanding the origin for the film stratification of electron donor/acceptor blend is crucial for high efficiency organic photovoltaic cell. In this study, P3HT:PCBM blend is deposited onto hydrophilic and hydrophobic substrate to examine the film stratifications. The neutron reflectivity results show that, on the different surfaces, PCBM diffuses toward the two interfacial regions in an identical fashion during thermal annealing. This evidences that the film stratification is not affected by the substrates. Instead, since P3HT remains more amorphous in the interfacial regions and PCBM is miscible with amorphous P3HT, PCBM preferentially diffuses to the interfacial regions, resulting in the stratification.

Keum, Jong Kahk [Neutron Science Directorate, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States) [Neutron Science Directorate, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Center for Nanophase Material Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Browning, James F.; Halbert, Candice E. [Neutron Science Directorate, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Neutron Science Directorate, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Xiao, Kai; Shao, Ming; Hong, Kunlun [Center for Nanophase Material Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Center for Nanophase Material Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2013-11-25T23:59:59.000Z

450

Narrow spectral linewidth of single zinc-blende GaN/AlN self-assembled quantum dots  

SciTech Connect (OSTI)

We study by microphotoluminescence the optical properties of single self-assembled zinc-blende GaN/AlN quantum dots grown by plasma-assisted molecular beam epitaxy. As opposed to previous reports, the high quality of such zinc-blende GaN quantum dots allows us to evidence a weak acoustic phonon sideband as well as a limited spectral diffusion. As a result, we report on resolution-limited quantum dot linewidths as narrow as 500 ± 50 ?eV. We finally confirm the fast radiative lifetime and high-temperature operation of such quantum dots.

Sergent, S. [Institute for Nano Quantum Information Electronics, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan)] [Institute for Nano Quantum Information Electronics, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan); Kako, S. [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan)] [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan); Bürger, M.; As, D. J. [Department Physik, Universität Paderborn, Warburger Str. 100, 33098 Paderborn (Germany)] [Department Physik, Universität Paderborn, Warburger Str. 100, 33098 Paderborn (Germany); Arakawa, Y. [Institute for Nano Quantum Information Electronics, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan) [Institute for Nano Quantum Information Electronics, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan); Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan)

2013-10-07T23:59:59.000Z

451

Role of dopant counter-anion functionality in polyaniline salts/blends and implications to morphology  

SciTech Connect (OSTI)

Polyanilines are of particular current interest primarily due to their relative ease of synthesis, low cost and stable conductivity in air. The insulating, polyaniline emeraldine base (PANI-EB) form becomes electrically conducting by preferential protonation or doping the imine nitrogen sites to yield an electrically conducting polyaniline emeraldine salt (PANI-ES). In this paper, wide and small angle X-ray scattering techniques (i.e., WAXS and SAXS) and light microscopy are used to characterize the influence of the dopant`s structure on the morphology of both polyaniline salt and blend. In an attempt to modify the morphology of the PANI-ES, the authors have evaluated a number of doping acids (i.e., methane sulfonic acid (HMSA), butane sulfonic acid (HBSA), dodecyl benzene sulfonic acid (HDBSA) and camphor sulfonic acid (HCSA)) that vary in size and polarity to better understanding the role of the acid in PANI-ES`s morphology and the resulting electrical conductivity. The other goal was to investigate the effect of the counter-anion structure on the nature of the phase separated PANI-ES network. The shape of the PANI-ES network in the host polycaprolactam has important implications on the nature of conduction behavior and the final electrical conductivity of the blend.

Hopkins, A.R.; Rasmussen, P.G. [Univ. of Michigan, Ann Arbor, MI (United States); Basheer, R.A. [General Motors Research and Development Center, Warren, MI (United States). Polymers Dept.; Annis, B.K.; Wignall, G.D. [Oak Ridge National Lab., TN (United States)

1997-04-01T23:59:59.000Z

452

(2/94)(2-4,9/95)(7/97)(11,12/98)(1,9,11/99) Neuman Chapter 3 Haloalkanes, Alcohols, Ethers, and Amines  

E-Print Network [OSTI]

, Ethers, and Amines from Organic Chemistry by Robert C. Neuman, Jr. Professor of Chemistry, emeritus://web.chem.ucsb.edu/~neuman/orgchembyneuman/> Chapter Outline of the Book ************************************************************************************** I. Foundations 1. Organic Molecules and Chemical Bonding 2. Alkanes and Cycloalkanes 3. Haloalkanes

Reed, Christopher A.

453

Role of Endocytosis in the Action of Ether Lipids on WEHI-3B, HL60, and FDCP-Mix A4 Cells  

Science Journals Connector (OSTI)

...Lipid by WEHI-3B Cells Has an Energy- dependent and an Energy-independent Component. Uptake...protective agents, suggested that the energy-dependent component of ether...of ET-18-OCH., by FDCP-mix A4 cells was measured, it was...

G. W. Bazill and T. M. Dexter

1990-12-01T23:59:59.000Z

454

Reactions of 15-crown-5 and bis-15-crown-5 ethers with metal acetylacetonate ions in the gas phase  

SciTech Connect (OSTI)

A study was carried out on the ion-molecule reactions of ions arising in the dissociation of ferric, cobaltic, chromic, manganous, neodymium(II), gallium(III), and indium(III) acetylacetonates upon electron impact with 15-crown-5 and bis-15-crown-5. The ratio of the yields of (acac)x-1 /SUP M+L/ ions is determined by the case of reduction of M /SUP x+1+/ to M /SUP x+/ and for (acac)/sub 3/M complexes, this ratio decreases in the series Nd, In, GA > Cr > Fe, Co. The rate constant for the formation of acacCoL/sup +/ ions is greater than for acacFeL/sup +/ ions. The possibility of fixing transition metals in unstable oxidation states by crown ethers is demonstrated in the case of nickel.

Timofeev, O.S.; Bogatskii, A.V.; Gren, A.I.; Lobach, A.V.; Nekarsov, Y.S.; Zagorevskii, D.V.

1985-05-20T23:59:59.000Z

455

Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report  

SciTech Connect (OSTI)

The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

2013-11-26T23:59:59.000Z

456

Single-Step Syngas-to-Dimethyl Ether Processes for Optimal Productivity, Minimal Emissions, and Natural Gas-Derived Syngas  

Science Journals Connector (OSTI)

Single-step conversion of synthesis gas (syngas, H2/CO mixture) to dimethyl ether (DME, CH3OCH3) is very attractive as a route for indirect coal liquefaction, natural gas utilization, and production of synthetic liquid fuels, fuel additives, and chemicals. ... The main driving force for developing a single-step syngas-to-DME process is to produce DME at a cost lower than that from the commercially available two-step process, namely, syngas-to-methanol followed by methanol dehydration in sequential reactors. ... Furthermore, the composition of most commercially available syngas (except that produced by a CO2?methane reformer) is not the optimal composition (1:1 H2:CO) for the syngas-to-DME reactor. ...

X. D. Peng; A. W. Wang; B. A. Toseland; P. J. A. Tijm

1999-09-28T23:59:59.000Z

457

Relationship between the technical parameters of cokes produced from blends of three Polish coals of different coking ability  

Science Journals Connector (OSTI)

The demand for metallurgical coke for blast furnaces is forcing the coking industry to look for new sources of coking coals. The physical and chemical parameters of coals used in coking blends determine the quality (reactivity and strength) of the finished cokes. This study examines the technical properties of the cokes produced from various blends of three Polish coals with different coking. These coals were collected from three mines: Zofiówka, Szczyg?owice, and Krupi?ski (Upper Silesian Coal Basin, Poland). The coal charges were coked in the laboratory scale, at temperatures of up to 1000 °C, in an inert atmosphere. The coke reactivity (index CRI) and the coke strength after reaction (CSR) were measured and correlated to the properties of parent coals using statistical analysis. The result of this study shows strong relationships between the concentration of the best coking coal (Zofiówka) in the blend and the CRI and CSR of the resulting coke. The CRI and CSR parameters for cokes obtained from single coals and from their blends show the additive character. This study also confirms the linear relationship between CRI and CSR parameters of the cokes.

A. Koszorek; M. Krzesi?ska; S. Pusz; B. Pilawa; B. Kwieci?ska

2009-01-01T23:59:59.000Z

458

Experiences from a Novel Sensor for Fireside Corrosion Monitoring during Grate Combustion of Corn Stover/Wood Chip Blends  

Science Journals Connector (OSTI)

The operation of a pilot-scale online corrosion sensor system was studied at VTT’s 100 kW grate pilot plant. The feedstock composition in tests was varied from 100% wood chips to a blend that also contained 40 en-% d.b. corn stover. The mass flow of ...

Timo J. Leino; Martti J. Aho; S. Juhani Gynther; Tommi A. Ruuskanen; Matti H. Häkkinen

2013-08-27T23:59:59.000Z

459

AFM/LFM surface studies of a ternary polymer blend cast on substrates covered by a self-assembled monolayer  

E-Print Network [OSTI]

AFM/LFM surface studies of a ternary polymer blend cast on substrates covered by a self force microscopy; Friction; Self-assembly; Surface thermodynamics (including phase transitions); Growth are of utmost current interest. In many practical appli- cations films of incompatible mixtures are pre- pared

Zbigniew, Postawa

460

Modeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels: Effect of ethanol content  

E-Print Network [OSTI]

Modeling the natural attenuation of benzene in groundwater impacted by ethanol-blended fuels: Effect of ethanol content on the lifespan and maximum length of benzene plumes Diego E. Gomez1 and Pedro 10 March 2009. [1] A numerical model was used to evaluate how the concentration of ethanol

Alvarez, Pedro J.

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Overview of Two Hydrogen Energy Storage Studies: Wind Hydrogen in California and Blending in Natural Gas Pipelines (Presentation)  

SciTech Connect (OSTI)

This presentation provides an overview of two NREL energy storage studies: Wind Hydrogen in California: Case Study and Blending Hydrogen Into Natural Gas Pipeline Networks: A Review of Key Issues. The presentation summarizes key issues, major model input assumptions, and results.

Melaina, M. W.

2013-05-01T23:59:59.000Z

462

By Earle B. Amey Tungsten's unique high-temperature in Metal Bulletin (London). ferrotungsten, carbide powder blends, and  

E-Print Network [OSTI]

). ferrotungsten, carbide powder blends, and properties can be utilized advantageously in the As a result properties of its carbide continue to scrap, and sodium tungstate and away from the provide important items increased in all imported tungsten materials. the cemented carbide end-use sectors that A summary

463

Key Aspects Blended Library draw strength by building on users'pre-existing knowledge of the everyday, non-digital  

E-Print Network [OSTI]

Key Aspects » Blended Library draw strength by building on users'pre-existing knowledge University of Konstanz http://hci.uni-konstanz.de/blendedlibrary Contact: Roman Rädle Tel. +49 7531 88-2868 Fax +49 7531 88-4772 roman.raedle@uni-konstanz.de Caused by the proceeding digitalization, real

Reiterer, Harald

464

Evaluation of dry-solids-blend material source for grouts containing 106-AN waste: September 1990 progress report  

SciTech Connect (OSTI)

Stabilization/solidification (S/S) is the most widely used technology for the treatment and ultimate disposal of both radioactive and chemically hazardous wastes. Such technology is being utilized in a Grout Treatment Facility (GTF) by the Westinghouse Hanford Company (WHC) for the disposal of various wastes, including 106-AN wastes, located on the Hanford Reservation. The WHC personnel have developed a grout formula for 106-AN disposal that is designed to meet stringent performance requirements. This formula consists of a dry-solids blend containing 40 wt % limestone, 28 wt % granulated blast furnace slag (BFS), 28 wt % ASTM Class F fly ash, and 4 wt % Type I-II-LA Portland cement. The blend is mixed with 106-AN waste at a ratio of 9 lb of dry-solids blend per gallon of waste. This report documents progress made to date on efforts at Oak Ridge National Laboratory (ORNL) in support of WHC`s Grout Technology Program to assess the effects of the source of the dry-solids-blend materials on the resulting grout formula.

Gilliam, T.M.; Osborne, S.C.; Francis, C.L.; Scott, T.C.

1993-09-01T23:59:59.000Z

465

Properties and performance of cotton seed oil–diesel blends as a fuel for compression ignition engines  

Science Journals Connector (OSTI)

This paper presents the evaluation of properties of straight vegetable cotton seed oil (CSO) and its blends with diesel fuel in various proportions to evaluate the performance and emission characteristics of a single cylinder compression ignition (CI) engine at constant speed of 1500 rev ? min . Diesel and CSO oil fuel blends (10% 30% 50% and 70%) were used to conduct engine performance and smoke emission tests at varying loads of 0% 20% 40% 60% 80% and 100% of full load in addition to their straight CSO and diesel fuel. The performance parameters of brake specific energy consumption (BSFC) brake thermal efficiency (BTE) mechanical efficiency (ME) exhaust gas temperature (EGT) and exhaust emission (smoke) were evaluated to find the optimum CSO and diesel fuel blend. From the experimental results the CSO10D90 blend fuel showed 3.7% reduction in BSFC 1.7% increase in BTE 6.7% increase in ME and 21.7% reduction in the smoke emissions in comparison with conventional diesel operated engine. Finally it is concluded that CSO10D90 can be used straight away in CI engines without any major modifications to the engine as it showed good performance and improved emission compared to all other fuels tested for the entire range of engine operation in comparison with diesel.

B. Murali Krishna; J. M. Mallikarjuna

2009-01-01T23:59:59.000Z

466

Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst  

SciTech Connect (OSTI)

Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL; Fisher, Galen [University of Michigan] [University of Michigan; West, Brian H [ORNL] [ORNL

2014-01-01T23:59:59.000Z

467

Amon Millner draft short paper submitted to the Interaction Design and Children 2011 conference Modkit: Blending and Extending Approachable Platforms  

E-Print Network [OSTI]

programming environment and the Arduino platform. The demonstration will feature the current Modkit components, activities, and projects that illustrate how the toolkit blends Scratch and Arduino platforms to extend what). General Terms Design, Human Factors, Languages. Keywords Modkit, Scratch, Arduino, informal learning

468

Preparation and properties of chitosan–soybean trypsin inhibitor blend film with anti-Aspergillus flavus activity  

Science Journals Connector (OSTI)

The chitosan-based blend films were prepared from chitosan, soybean trypsin inhibitor extract (STI)/wild soybean trypsin inhibitor extract (WTI) and glycerol (Gly) solutions, the properties of which were also investigated, including thickness, mechanical property, water vapor transmission, optical transmittance, and solubility. In addition, the resulting films were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The result of SEM images showed the surface and cross-section of chitosan–STI/WTI–Gly blend film had more smooth and dense morphology than pure chitosan film, which suggested there was a better compatibility among the three components. XRD and FTIR spectra indicated that the possible interaction force among the components might be the hydrogen bonds of NH?OC and OH?OC. Furthermore, the antifungal activity against A. flavus by the prepared blend films had been investigated. The facts that the germination and growth of A. flavus were strongly inhibited by chitosan–STI/WTI–Gly film indicated the blend films might be useful as potential bio-control packaging against A. flavus during the peanuts and other cereals storage.

Bin Zhang; Dong-Feng Wang; Hai-Yan Li; Ying Xu; Li Zhang

2009-01-01T23:59:59.000Z

469

Development of decision support system to select the best fuel blend in IC engines to enhance the energy efficiency  

Science Journals Connector (OSTI)

This paper describes an application of hybrid MCDM technique for the selection of optimum blend in fish oil biodiesel among the six alternative fuel blends diesel, B20, B40, B60, B80 and B100 which is prepared by varying the amount of diesel with biodiesel. Brake thermal efficiency (BTE), exhaust gas temperature (EGT), oxides of nitrogen (NOx), smoke, hydrocarbon (HC), carbon monoxide (CO), carbon dioxide (CO2), ignition delay (ID), combustion duration (CD) and maximum rate of pressure rise (MRPR) are considered as evaluation criteria. A single cylinder, constant speed and direct injection diesel engine with a rated output of 4.4 kW was used for exploratory analysis of evaluation criteria at different load conditions. The proposed model, fuzzy analytical hierarchy process (FAHP) is integrated with elimination et and choice translating reality (ELECTRE) to evaluate the optimum blend. Here the FAHP is used to determine the relative weights of the criteria, whereas ELECTRE is used for obtaining the final ranking of alternative blends.

G. Sakthivel; M. Ilangkumaran

2013-01-01T23:59:59.000Z

470

IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS  

Office of Scientific and Technical Information (OSTI)

Annual Technical Progress Report for Project Entitled "Impact Annual Technical Progress Report for Project Entitled "Impact of DME-Diesel Fuel Blend Properties on Diesel Fuel Injection Systems" May 16, 2002 - May 15, 2003 Elana M. Chapman, Andre Boehman, Kimberly Wain, Wallis Lloyd, Joseph M. Perez, Donald Stiver, Joseph Conway Report Issue Date: June 2003 DOE Award Number: DE-FC26-01NT41115 The Pennsylvania State University The Energy Institute University Park, PA 16802 ii DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus,

471

Results of Research Engine and Vehicle Drive Cycle Testing during Blended Hydrogen/Methane Operation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Results of Research Engine and Results of Research Engine and Vehicle Drive Cycle Testing during Blended Hydrogen/Methane Operation Thomas Wallner, Henning Lohse-Busch, Henry Ng Argonne National Laboratory Robert Peters University of Alabama at Birmingham NHA Annual Hydrogen Conference 2007 San Antonio/Texas March 19 th - 22 nd 2007 DOE-Sponsors: Lee Slezak, Gurpreet Singh Government license The submitted manuscript was developed by the UChicago Argonne LLC as Operator of Argonne National Laboratory ("Argonne") under Contract No. DE-AC-02-06CH11357 with DOE. The U.S. Government retains for itself, and others acting on its behalf, a paid-up, nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on

472

Production and characterization of natural rubber–Ca/P blends for biomedical purposes  

Science Journals Connector (OSTI)

Abstract This study presents the development of natural rubber–Ca/P blends, as promising candidates for biomedical purposes. The specific objective was the incorporation of Ca/P into a natural rubber polymeric matrix. Ca/P crystalline phases were synthesized by the sol–gel method and the polymeric matrices were produced using natural rubber extracted from latex of the Hevea brasiliensis. The shape and size of natural rubber particles present in the NR membrane, as well as, the way the Ca/P powder grains aggregate in the polymeric matrix were investigated, giving information about the interactions between the Ca/P and the natural rubber particles. Confocal fluorescence scanning microscopy measurements allowed us to propose a structure where the Ca/P grains are surrounded by natural rubber particles. This structure may mediate Ca2 + release for tissue regeneration. The system investigated may open new horizons for development of a bandage which provides the controlled-release of biomaterials.

R.M. Nascimento; F.L. Faita; D.L.S. Agostini; A.E. Job; F.E.G. Guimarães; I.H. Bechtold

2014-01-01T23:59:59.000Z

473

Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate.  

SciTech Connect (OSTI)

Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines.

Herbinet, O; Pitz, W J; Westbrook, C K

2009-07-21T23:59:59.000Z

474

Susceptibility of Aluminum Alloys to Corrosion in Simulated Fuel Blends Containing Ethanol  

SciTech Connect (OSTI)

The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined was accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

Thomson, Jeffery K [ORNL; Pawel, Steven J [ORNL; Wilson, Dane F [ORNL

2013-01-01T23:59:59.000Z

475

Performance of a spark ignition engine fueled with methanol or methanol-gasoline blends  

SciTech Connect (OSTI)

Engine torque and specific energy consumption of an automotive engine were studied under steady state condition using gasoline, methanol gasoline blends and straight methanol as fuel. At first the engine was run without any modification. Next the diameters of metering orifices in carburetor were modified to give the same excess air factor regardless of fuel type under each fixed engine operating condition. Finally the engine was run with 15% mixture methanol in gasoline by volume using the carburetor modified to have approximately 10% larger fuel flow area than the production carburetor. From the results of this study the effects of using methanol on engine torque and specific energy consumption can be explained on the basis of change in stoichiometry caused by the use of methanol.

You, B.C.

1983-11-01T23:59:59.000Z

476

PUBLIC AND REGULATORY ACCEPTANCE OF BLENDING OF RADIOACTIVE WASTE VS DILUTION  

SciTech Connect (OSTI)

On April 21, 2009, the Energy Facilities Contractors Group (EFCOG) Waste Management Working Group (WMWG) provided a recommendation to the Department of Energy's Environmental Management program (DOE-EM) concerning supplemental guidance on blending methodologies to use to classify waste forms to determine if the waste form meets the definition of Transuranic (TRU) Waste or can be classified as Low-Level Waste (LLW). The guidance provides specific examples and methods to allow DOE and its Contractors to properly classify waste forms while reducing the generation of TRU wastes. TRU wastes are much more expensive to characterize at the generator's facilities, ship, and then dispose at the Waste Isolation Pilot Plant (WIPP) than Low-Level Radioactive Waste's disposal. Also the reduction of handling and packaging of LLW is inherently less hazardous to the nuclear workforce. Therefore, it is important to perform the characterization properly, but in a manner that minimizes the generation of TRU wastes if at all possible. In fact, the generation of additional volumes of radioactive wastes under the ARRA programs, this recommendation should improve the cost effective implementation of DOE requirements while properly protecting human health and the environment. This paper will describe how the message of appropriate, less expensive, less hazardous blending of radioactive waste is the 'right' thing to do in many cases, but can be confused with inappropriate 'dilution' that is frowned upon by regulators and stakeholders in the public. A proposal will be made in this paper on how to communicate this very complex and confusing technical issue to regulatory bodies and interested stakeholders to gain understanding and approval of the concept. The results of application of the proposed communication method and attempt to change the regulatory requirements in this area will be discussed including efforts by DOE and the NRC on this very complex subject.

Goldston, W.

2010-11-30T23:59:59.000Z

477

Analysis of synthetic cannabinoids in herbal blends by means of nano-liquid chromatography  

Science Journals Connector (OSTI)

In this study, a rapid and simultaneous separation of 12 synthetic cannabinoids and ?9-tetrahydrocannabinol (?9-THC) in herbal blends was obtained by means of nano-liquid chromatography (nano-LC). The nano-LC experiments were performed in a 100 ?m i.d. capillary column packed with Cogent® bidentate C18 silica particles for 25.0 cm. All compounds were resolved using an isocratic elution mode in less than 30 min. A mobile phase containing ACN/MeOH/H2O/formic acid 69/5/25/1 (v/v/v/v) was employed for the chromatographic separation. The developed analytical method was validated in terms of precision, linearity, sensitivity and accuracy. Under optimal nano-LC–UV conditions, the resulting RSD percentages for intra-day and inter-day repeatability, related to retention time and peak area, were below 2.98 and 6.40%, respectively. Limits of detection and quantification were 0.2 and 0.5 ?g/mL, respectively, for all the studied compounds. Linearity was assessed in the concentration range of interest for all analytes with determination coefficients r2 ? 0.9975. The method was then applied to the determination of synthetic cannabinoids in herbal blends. Quantitative analyses of the cannabimimetic compounds in six products showed that there was a wide difference in the concentration of the studied compounds among different products. Further, the nano-LC system was coupled with a mass spectrometer measuring the MS and MS–MS spectra to unequivocally identify the cannabinoids present in smoking mixtures.

Gustavo Merola; Zeineb Aturki; Giovanni D’Orazio; Rossella Gottardo; Teodora Macchia; Franco Tagliaro; Salvatore Fanali

2012-01-01T23:59:59.000Z

478

Ethynyl terminated ethers. Synthesis and thermal characterization of 2,2 bis (ethynyl-4-phenylcarbonyl-4-phenoxy-4-phenyl) propane and 2,2 bis (ethynyl-4-phenylsulfonyl-4-phenoxy-4-phenyl) propane  

Science Journals Connector (OSTI)

Two ethynyl end-capped ethers 2,2 Bis [ethynyl-4-phenylsulfonyl-4-phenoxy-4-phenyl] propane and 2,2 Bis [ethynyl-4-phenylcarbonyl-4-phenoxy-4-phenyl] propane have been prepared by a three steps...

Georges Lucotte; Laurent Cormier; Bruno Delfort

1990-12-01T23:59:59.000Z

479

Efficient production of 5-hydroxymethylfurfural through the dehydration of sugars with caprolactam hydrogen sulfate ([CPL]HSO4) ionic liquid catalyst in a water/proprylene glycol monomethyl ether mixed solvent  

Science Journals Connector (OSTI)

Efficient production of 5-hydroxymethylfurfural (HMF) through the dehydration of sugars...4) ionic liquid or using metal halide as the co-catalyst in a new water/proprylene glycol monomethyl ether solvent system....

Pingzhen Huang; Aijuan Gu; Jinxing Wang

2014-04-01T23:59:59.000Z

480

Fluctuating micro-heterogeneity in water–tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

SciTech Connect (OSTI)

Water–tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with x{sub TBA} ? 0.03–0.07. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at x{sub TBA} ? 0.05. We note that “islands” of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak nonlinearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, x{sub TBA} ? 0.45, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Banerjee, Saikat; Furtado, Jonathan; Bagchi, Biman, E-mail: bbagchi@sscu.iisc.ernet.in [SSCU, Indian Institute of Science, Bangalore 560012 (India)] [SSCU, Indian Institute of Science, Bangalore 560012 (India)

2014-05-21T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether blends" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Transport study of hafnium(IV) and zirconium(IV) ions mutual separation by using Tri-n-butyl phosphate-xylene-based supported liquid membranes  

SciTech Connect (OSTI)

A Hf transport study through supported liquid membranes has been carried out to determine flux and permeability data for this metal ion. Tri-n-butyl phosphate (TBP)-xylene-based liquid membranes supported in polypropylene hydrophobic microporous film have been used. These data for hafnium and the previous data for zirconium have furnished the Zr to Hf flux ratio (S) as a function of nitric acid and TBP concentrations of the order of 12 in a single stage at room temperature. Optimum conditions for the separation of these two metal ions appear to 5-6 TBP mol/dm{sup 3} HNO{sub 3}, concentrations {le} 2.93 mol/dm{sup 3}, and 10C. The value of S from an aqueous solution containing 2.4% Hf with respect to Zr has been found to be >125 at 10C and 1.78 mol/dm{sup 3} TBP concentration in the membrane. The technique appears to be feasible for purification of Zr respect to Hf or vice versa.

Chaudry, M.A.; Ahmed, B. (Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan))

1992-02-01T23:59:59.000Z

482

Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia  

SciTech Connect (OSTI)

Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?°C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?°C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

2014-03-15T23:59:59.000Z

483

Fluctuating micro-heterogeneity in water - tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

E-Print Network [OSTI]

Water - tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with $x_{\\text{TBA}} \\approx 0.03 - 0.07$. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at $x_{\\text{TBA}} \\approx 0.05$. We note that "islands" of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak non-linearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, $x_{\\text{TBA}} \\approx 0.45$, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Saikat Banerjee; Jonathan Furtado; Biman Bagchi

2014-02-20T23:59:59.000Z

484

Advances in the design of co-poly(ether-imide) membranes for CO2 separations. Influence of aromatic rigidity on crystallinity, phase segregation and gas transport  

Science Journals Connector (OSTI)

Abstract In our previous works, it was observed a clear relationship between the structure and the properties for different copoly(ether-imide)s, besides a good relation was found between SAXS characterization and permeability results. Here, a series of aliphatic aromatic copoly(ether-imide)s, based on an aromatic diamine (ODA), a diamine terminated poly(ethylene oxide) (PEO2000) of a molecular weight of 2000 g/mol and different aromatic dianhydrides (BPDA, BKDA (or BTDA) and PMDA) has been synthesized and characterized. The permeability for O2, N2, CO2 and CH4, increased with the rigidity of the monomers (BKDA CO2/N2 separation. This work gives indications on how to design advanced materials for this separation with the increasing possibilities of controlled structure and properties.

Alberto Tena; Ángel Marcos-Fernández; Mónica de la Viuda; Laura Palacio; Pedro Prádanos; Ángel E. Lozano; Javier de Abajo; Antonio Hernández

2015-01-01T23:59:59.000Z

485

Experimental study on the performance, emission and combustion characteristics of rubber seed oil-diesel blends in a DI diesel engine  

Science Journals Connector (OSTI)

In the present work, experiments have been carried out to assess the suitability of rubber seed oil and its blends with diesel in a diesel engine. Tests were conducted with different blends of R80-D20 (80% of rubber seed oil and 20% of diesel by volume) and R70-D30 (70% of rubber seed oil and 30% of diesel by volume). Experimental results indicate that the brake thermal efficiency increases from 26.5% to 27.7% with the optimum blend of R70-D30. There is a reduction in emissions is also observed except NOx level at all loads. Smoke emission reduces drastically from 6.1 to 4.7 BSU. Combustion parameters indicated a decrease in ignition delay and combustion duration compared with neat RSO. This will also contribute to higher heat release rate in the premixed combustion phase. Current investigations reveal that the performance of R70-D30 blend is closer to diesel.

V. Edwin Geo; G. Nagarajan; B. Nagalingam

2011-01-01T23:59:59.000Z

486

Characteristics of the performance and emissions of a HSDI diesel engine running with cottonseed oil or its methyl ester and their blends with diesel fuel  

Science Journals Connector (OSTI)

An experimental study has been conducted to evaluate the use of various blends of cottonseed oil or its methyl ester (bio-diesel) with diesel fuel, in