National Library of Energy BETA

Sample records for btu cu ft

  1. Btu)","per Building

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Number of Buildings (thousand)","Floorspace (million square feet)","Floorspace per Building (thousand square feet)","Total (trillion Btu)","per Building (million Btu)","per...

  2. First BTU | Open Energy Information

    Open Energy Info (EERE)

    that is consumed by the United States.3 References First BTU First BTU Green Energy About First BTU Retrieved from "http:en.openei.orgwindex.php?titleFirstBT...

  3. ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (Btu) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy Intensity (thousand Btu...

  4. BTU International Inc | Open Energy Information

    Open Energy Info (EERE)

    1862 Product: US-based manufacturer of thermal processing equipment, semiconductor packaging, and surface mount assembly. References: BTU International Inc1 This article is a...

  5. Microfabricated BTU monitoring device for system-wide natural...

    Office of Scientific and Technical Information (OSTI)

    Microfabricated BTU monitoring device for system-wide natural gas monitoring. Citation Details In-Document Search Title: Microfabricated BTU monitoring device for system-wide...

  6. ,"Total District Heat Consumption (trillion Btu)",,,,,"District...

    U.S. Energy Information Administration (EIA) Indexed Site

    Heat Consumption (trillion Btu)",,,,,"District Heat Energy Intensity (thousand Btusquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  7. ,"Total Natural Gas Consumption (trillion Btu)",,,,,"Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (trillion Btu)",,,,,"Natural Gas Energy Intensity (thousand Btusquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  8. NPB UPC-FT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NPB UPC-FT NPB UPC-FT Description This is the Berkeley Unified Parallel C (UPC) implementation of the NAS Parallel Benchmark FT. The transpose communication is implemented using...

  9. Property:Geothermal/CapacityBtuHr | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search This is a property of type Number. Pages using the property "GeothermalCapacityBtuHr" Showing 25 pages using this property. (previous 25) (next 25) 4 4 UR...

  10. Property:Geothermal/AnnualGenBtuYr | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search This is a property of type Number. Pages using the property "GeothermalAnnualGenBtuYr" Showing 25 pages using this property. (previous 25) (next 25) 4 4 UR...

  11. ,"Henry Hub Natural Gas Spot Price (Dollars per Million Btu)...

    U.S. Energy Information Administration (EIA) Indexed Site

    12:00:20 PM" "Back to Contents","Data 1: Henry Hub Natural Gas Spot Price (Dollars per Million Btu)" "Sourcekey","RNGWHHD" "Date","Henry Hub Natural Gas Spot Price (Dollars per ...

  12. Microfabricated BTU monitoring device for system-wide natural gas

    Office of Scientific and Technical Information (OSTI)

    monitoring. (Technical Report) | SciTech Connect Technical Report: Microfabricated BTU monitoring device for system-wide natural gas monitoring. Citation Details In-Document Search Title: Microfabricated BTU monitoring device for system-wide natural gas monitoring. The natural gas industry seeks inexpensive sensors and instrumentation to rapidly measure gas heating value in widely distributed locations. For gas pipelines, this will improve gas quality during transfer and blending, and will

  13. DYNAMIC MANUFACTURING ENERGY SANKEY TOOL (2010, UNITS: TRILLION BTU) |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Information Resources » Energy Analysis » DYNAMIC MANUFACTURING ENERGY SANKEY TOOL (2010, UNITS: TRILLION BTU) DYNAMIC MANUFACTURING ENERGY SANKEY TOOL (2010, UNITS: TRILLION BTU) About the Energy Data Use this diagram to explore (zoom, pan, select) and compare energy flows across U.S. manufacturing and key subsectors. Line widths indicate the volume of energy flow in trillions of British thermal units (TBtu). The 15 manufacturing subsectors together consume 95% of all

  14. NPB UPC-FT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NPB UPC-FT NPB UPC-FT Description This is the Berkeley Unified Parallel C (UPC) implementation of the NAS Parallel Benchmark FT. The transpose communication is implemented using both blocking functions (upc_memget) and nonblocking functions (upc_memput_nb). The default is nonblocking functions, which is defined in UPC description 3.1. If nonblocking functions are not supported on your system, it will switch to blocking functions automatically. Users are allowed to change the selection by

  15. EIS-0007: Low Btu Coal Gasification Facility and Industrial Park

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) prepared this draft environmental impact statement that evaluates the potential environmental impacts that may be associated with the construction and operation of a low-Btu coal gasification facility and the attendant industrial park in Georgetown, Scott County, Kentucky. DOE cancelled this project after publication of the draft.

  16. "Economic","per Employee","of Value Added","of Shipments" "Characteristic(a)","(million Btu)","(thousand Btu)","(thousand Btu)"

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Relative Standard Errors for Table 6.2;" " Unit: Percents." ,,,"Consumption" " ",,"Consumption","per Dollar" " ","Consumption","per Dollar","of Value" "Economic","per Employee","of Value Added","of Shipments" "Characteristic(a)","(million Btu)","(thousand Btu)","(thousand Btu)" ,"Total United States" "Value

  17. "Economic","per Employee","of Value Added","of Shipments" "Characteristic(a)","(million Btu)","(thousand Btu)","(thousand Btu)"

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Relative Standard Errors for Table 6.2;" " Unit: Percents." ,,,"Consumption" ,,"Consumption","per Dollar" ,"Consumption","per Dollar","of Value" "Economic","per Employee","of Value Added","of Shipments" "Characteristic(a)","(million Btu)","(thousand Btu)","(thousand Btu)" ,"Total United States" "Value of Shipments and

  18. A Requirement for Significant Reduction in the Maximum BTU Input Rate of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Decorative Vented Gas Fireplaces Would Impose Substantial Burdens on Manufacturers | Department of Energy A Requirement for Significant Reduction in the Maximum BTU Input Rate of Decorative Vented Gas Fireplaces Would Impose Substantial Burdens on Manufacturers A Requirement for Significant Reduction in the Maximum BTU Input Rate of Decorative Vented Gas Fireplaces Would Impose Substantial Burdens on Manufacturers Comment that a requirement to reduce the BTU input rate of existing decorative

  19. Sectoral combustor for burning low-BTU fuel gas

    DOE Patents [OSTI]

    Vogt, Robert L. (Schenectady, NY)

    1980-01-01

    A high-temperature combustor for burning low-BTU coal gas in a gas turbine is disclosed. The combustor includes several separately removable combustion chambers each having an annular sectoral cross section and a double-walled construction permitting separation of stresses due to pressure forces and stresses due to thermal effects. Arrangements are described for air-cooling each combustion chamber using countercurrent convective cooling flow between an outer shell wall and an inner liner wall and using film cooling flow through liner panel grooves and along the inner liner wall surface, and for admitting all coolant flow to the gas path within the inner liner wall. Also described are systems for supplying coal gas, combustion air, and dilution air to the combustion zone, and a liquid fuel nozzle for use during low-load operation. The disclosed combustor is fully air-cooled, requires no transition section to interface with a turbine nozzle, and is operable at firing temperatures of up to 3000.degree. F. or within approximately 300.degree. F. of the adiabatic stoichiometric limit of the coal gas used as fuel.

  20. Recent regulatory experience of low-Btu coal gasification. Volume III. Supporting case studies

    SciTech Connect (OSTI)

    Ackerman, E.; Hart, D.; Lethi, M.; Park, W.; Rifkin, S.

    1980-02-01

    The MITRE Corporation conducted a five-month study for the Office of Resource Applications in the Department of Energy on the regulatory requirements of low-Btu coal gasification. During this study, MITRE interviewed representatives of five current low-Btu coal gasification projects and regulatory agencies in five states. From these interviews, MITRE has sought the experience of current low-Btu coal gasification users in order to recommend actions to improve the regulatory process. This report is the third of three volumes. It contains the results of interviews conducted for each of the case studies. Volume 1 of the report contains the analysis of the case studies and recommendations to potential industrial users of low-Btu coal gasification. Volume 2 contains recommendations to regulatory agencies.

  1. Expanded standards and codes case limits combined buildings delivered energy to 21 quadrillion Btu by 2035

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Erin Boedecker, Session Moderator April 27, 2011 | Washington, DC Energy Demand. Efficiency, and Consumer Behavior 16 17 18 19 20 21 22 23 24 25 2005 2010 2015 2020 2025 2030 2035 2010 Technology Reference Expanded Standards Expanded Standards + Codes -7.6% ≈ 0 Expanded standards and codes case limits combined buildings delivered energy to 21 quadrillion Btu by 2035 2 Erin Boedecker, EIA Energy Conference, April 27, 2011 delivered energy quadrillion Btu Source: EIA, Annual Energy Outlook 2011

  2. Sandia Energy - SWiFT Operations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Operations Home Stationary Power Energy Conversion Efficiency Wind Energy SWiFT Facility & Testing SWiFT Operations SWiFT Operationscwdd2015-05-28T15:24:41+00:00 wind-turbines The...

  3. Low-Btu coal gasification in the United States: company topical. [Brick producers

    SciTech Connect (OSTI)

    Boesch, L.P.; Hylton, B.G.; Bhatt, C.S.

    1983-07-01

    Hazelton and other brick producers have proved the reliability of the commercial size Wellman-Galusha gasifier. For this energy intensive business, gas cost is the major portion of the product cost. Costs required Webster/Hazelton to go back to the old, reliable alternative energy of low Btu gasification when the natural gas supply started to be curtailed and prices escalated. Although anthracite coal prices have skyrocketed from $34/ton (1979) to over $71.50/ton (1981) because of high demand (local as well as export) and rising labor costs, the delivered natural gas cost, which reached $3.90 to 4.20/million Btu in the Hazelton area during 1981, has allowed the producer gas from the gasifier at Webster Brick to remain competitive. The low Btu gas cost (at the escalated coal price) is estimated to be $4/million Btu. In addition to producing gas that is cost competitive with natural gas at the Webster Brick Hazelton plant, Webster has the security of knowing that its gas supply will be constant. Improvements in brick business and projected deregulation of the natural gas price may yield additional, attractive cost benefits to Webster Brick through the use of low Btu gas from these gasifiers. Also, use of hot raw gas (that requires no tar or sulfur removal) keeps the overall process efficiency high. 25 references, 47 figures, 14 tables.

  4. Hawaii Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Hawaii Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,056 1,055 1,057 1,043 983 983 983 983 983 983 983 983 2014 947 946 947 947 947 947 951 978 990 968 974 962 2015 968 954 947 959 990 1,005 1,011 965 989 996 996 997 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  5. Ft Bidwell Space Heating Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Ft Bidwell Space Heating Low Temperature Geothermal Facility Jump to: navigation, search Name Ft Bidwell Space Heating Low Temperature Geothermal Facility Facility Ft Bidwell...

  6. SWiFT Software Quality Assurance Plan.

    SciTech Connect (OSTI)

    Berg, Jonathan Charles

    2016-01-01

    This document describes the software development practice areas and processes which contribute to the ability of SWiFT software developers to provide quality software. These processes are designed to satisfy the requirements set forth by the Sandia Software Quality Assurance Program (SSQAP). APPROVALS SWiFT Software Quality Assurance Plan (SAND2016-0765) approved by: Department Manager SWiFT Site Lead Dave Minster (6121) Date Jonathan White (6121) Date SWiFT Controls Engineer Jonathan Berg (6121) Date CHANGE HISTORY Issue Date Originator(s) Description A 2016/01/27 Jon Berg (06121) Initial release of the SWiFT Software Quality Assurance Plan

  7. Georgia Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Georgia Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,014 1,015 1,016 1,015 1,014 1,015 1,016 1,019 1,017 1,016 1,017 1,017 2014 1,018 1,018 1,018 1,018 1,021 1,022 1,023 1,023 1,027 1,026 1,026 1,025 2015 1,025 1,026 1,025 1,026 1,028 1,031 1,030 1,028 1,029 1,028 1,026 1,027 - = No Data Reported; -- = Not Applicable; NA = Not

  8. Delaware Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Delaware Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,050 1,049 1,046 1,048 1,041 1,049 1,058 1,054 1,065 1,064 1,067 1,057 2014 1,052 1,048 1,048 1,051 1,045 1,049 1,063 1,065 1,062 1,063 1,063 1,064 2015 1,061 1,061 1,062 1,051 1,055 1,055 1,044 1,044 1,043 1,051 1,051 1,049 - = No Data Reported; -- = Not Applicable; NA = Not

  9. Colorado Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Colorado Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,023 1,032 1,030 1,033 1,040 1,051 1,056 1,057 1,058 1,037 1,032 1,033 2014 1,030 1,036 1,038 1,041 1,051 1,050 1,048 1,048 1,050 1,055 1,042 1,051 2015 1,046 1,044 1,051 1,059 1,059 1,070 1,073 1,069 1,076 1,069 1,060 1,051 - = No Data Reported; -- = Not Applicable; NA = Not

  10. Florida Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Florida Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,016 1,015 1,016 1,015 1,016 1,015 1,016 1,016 1,017 1,017 1,018 1,018 2014 1,018 1,018 1,018 1,019 1,019 1,019 1,022 1,023 1,024 1,023 1,024 1,025 2015 1,024 1,025 1,024 1,024 1,026 1,026 1,026 1,024 1,024 1,023 1,023 1,023 - = No Data Reported; -- = Not Applicable; NA = Not

  11. Connecticut Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cubic Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Connecticut Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,018 1,025 1,011 1,022 1,028 1,024 1,032 1,028 1,030 1,030 1,026 1,024 2014 1,015 1,015 1,016 1,019 1,020 1,022 1,022 1,023 1,021 1,020 1,018 1,017 2015 1,017 1,026 1,029 1,026 1,049 1,027 1,027 1,026 1,026 1,028 1,027 1,026 - = No Data Reported; -- = Not Applicable;

  12. Iowa Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Iowa Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,025 1,029 1,029 1,030 1,031 1,030 1,030 1,027 1,028 1,032 1,033 1,032 2014 1,034 1,033 1,034 1,036 1,040 1,039 1,043 1,047 1,044 1,046 1,044 1,045 2015 1,045 1,047 1,047 1,051 1,054 1,060 1,059 1,059 1,058 1,058 1,057 1,056 - = No Data Reported; -- = Not Applicable; NA = Not

  13. U.S. Heat Content of Natural Gas Deliveries to Other Sectors Consumers (BTU

    U.S. Energy Information Administration (EIA) Indexed Site

    per Cubic Foot) Other Sectors Consumers (BTU per Cubic Foot) U.S. Heat Content of Natural Gas Deliveries to Other Sectors Consumers (BTU per Cubic Foot) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 1,029 1,026 1,028 1,028 1,027 1,027 1,025 2010's 1,023 1,022 1,025 1,028 1,032 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 02/29/2016 Next Release Date: 03/31/2016

  14. U.S. Total Consumption of Heat Content of Natural Gas (BTU per Cubic Foot)

    U.S. Energy Information Administration (EIA) Indexed Site

    Consumption of Heat Content of Natural Gas (BTU per Cubic Foot) U.S. Total Consumption of Heat Content of Natural Gas (BTU per Cubic Foot) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 1,028 1,026 1,028 1,028 1,027 1,027 1,025 2010's 1,023 1,022 1,024 1,027 1,032 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 02/29/2016 Next Release Date: 03/31/2016 Referring Pages:

  15. Louisiana Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cubic Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Louisiana Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,015 1,013 1,015 1,015 1,015 1,016 1,016 1,017 1,017 1,016 1,018 1,019 2014 1,017 1,016 1,018 1,021 1,028 1,025 1,029 1,029 1,031 1,034 1,037 1,038 2015 1,030 1,031 1,029 1,029 1,028 1,027 1,028 1,024 1,023 1,023 1,022 1,023 - = No Data Reported; -- = Not Applicable;

  16. Kansas Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Kansas Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,017 1,017 1,019 1,018 1,018 1,020 1,020 1,020 1,018 1,017 1,016 1,017 2014 1,017 1,017 1,019 1,023 1,022 1,023 1,025 1,025 1,027 1,025 1,028 1,025 2015 1,033 1,034 1,035 1,036 1,044 1,039 1,040 1,042 1,039 1,037 1,035 1,031 - = No Data Reported; -- = Not Applicable; NA = Not

  17. Kentucky Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Kentucky Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,023 1,022 1,023 1,025 1,026 1,027 1,028 1,030 1,031 1,028 1,028 1,033 2014 1,029 1,024 1,026 1,028 1,031 1,037 1,034 1,036 1,038 1,022 1,017 1,019 2015 1,023 1,018 1,015 1,016 1,023 1,021 1,024 1,015 1,020 1,024 1,021 1,024 - = No Data Reported; -- = Not Applicable; NA = Not

  18. Idaho Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Idaho Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,015 1,015 1,031 1,021 1,010 997 988 994 1,001 1,026 1,034 1,054 2014 1,048 1,036 1,030 1,022 1,006 993 984 996 1,005 1,019 1,046 1,039 2015 1,047 1,037 1,030 1,023 1,000 1,010 1,034 1,028 1,024 1,033 1,035 1,041 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  19. Illinois Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Illinois Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,013 1,013 1,014 1,015 1,015 1,014 1,015 1,015 1,016 1,017 1,019 1,018 2014 1,020 1,020 1,020 1,020 1,020 1,020 1,022 1,020 1,021 1,021 1,023 1,024 2015 1,027 1,030 1,029 1,028 1,029 1,027 1,027 1,027 1,028 1,028 1,030 1,030 - = No Data Reported; -- = Not Applicable; NA = Not

  20. Indiana Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Indiana Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,011 1,012 1,013 1,015 1,019 1,020 1,019 1,021 1,020 1,018 1,015 1,014 2014 1,016 1,017 1,019 1,019 1,023 1,023 1,025 1,030 1,028 1,027 1,025 1,029 2015 1,028 1,029 1,031 1,039 1,037 1,043 1,043 1,044 1,041 1,039 1,034 1,033 - = No Data Reported; -- = Not Applicable; NA = Not

  1. Minnesota Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cubic Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Minnesota Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,020 1,021 1,020 1,021 1,026 1,030 1,028 1,029 1,028 1,029 1,029 1,027 2014 1,031 1,027 1,033 1,034 1,038 1,042 1,042 1,051 1,046 1,040 1,038 1,040 2015 1,041 1,034 1,033 1,037 1,044 1,047 1,043 1,041 1,039 1,041 1,045 1,041 - = No Data Reported; -- = Not Applicable;

  2. Mississippi Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cubic Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Mississippi Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,013 1,013 1,014 1,014 1,015 1,018 1,018 1,021 1,022 1,025 1,020 1,020 2014 1,019 1,014 1,019 1,026 1,030 1,034 1,035 1,036 1,035 1,033 1,035 1,034 2015 1,036 1,033 1,031 1,037 1,032 1,030 1,030 1,029 1,031 1,028 1,029 1,030 - = No Data Reported; -- = Not Applicable;

  3. Missouri Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Missouri Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,015 1,014 1,014 1,013 1,014 1,013 1,017 1,015 1,016 1,019 1,013 1,014 2014 1,013 1,013 1,014 1,014 1,011 1,016 1,016 1,018 1,017 1,018 1,017 1,017 2015 1,017 1,020 1,025 1,026 1,024 1,026 1,026 1,026 1,026 1,025 1,024 1,023 - = No Data Reported; -- = Not Applicable; NA = Not

  4. Montana Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Montana Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,044 1,040 1,032 1,034 1,034 1,044 1,048 1,043 1,047 1,041 1,032 1,031 2014 1,034 1,030 1,030 1,027 1,032 1,030 1,038 1,036 1,040 1,031 1,026 1,030 2015 1,028 1,029 1,028 1,021 1,019 1,030 1,031 1,033 1,032 1,032 1,034 1,034 - = No Data Reported; -- = Not Applicable; NA = Not

  5. Maine Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Maine Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,037 1,032 1,027 1,032 1,028 1,031 1,033 1,030 1,031 1,037 1,032 1,029 2014 1,029 1,030 1,030 1,030 1,033 1,030 1,031 1,039 1,023 1,016 1,025 1,027 2015 1,033 1,035 1,030 1,025 1,022 1,020 1,020 1,018 1,019 1,026 1,025 1,027 - = No Data Reported; -- = Not Applicable; NA = Not

  6. Maryland Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Maryland Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,041 1,037 1,032 1,027 1,037 1,042 1,060 1,056 1,062 1,059 1,061 1,059 2014 1,053 1,048 1,045 1,049 1,047 1,052 1,051 1,051 1,049 1,052 1,057 1,057 2015 1,059 1,061 1,058 1,051 1,058 1,057 1,055 1,049 1,050 1,053 1,049 1,050 - = No Data Reported; -- = Not Applicable; NA = Not

  7. Massachusetts Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cubic Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Massachusetts Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,037 1,033 1,032 1,033 1,035 1,032 1,033 1,034 1,036 1,038 1,033 1,030 2014 1,035 1,032 1,031 1,030 1,030 1,031 1,030 1,029 1,029 1,028 1,029 1,028 2015 1,035 1,035 1,030 1,029 1,027 1,027 1,029 1,028 1,027 1,028 1,029 1,030 - = No Data Reported; -- = Not

  8. Michigan Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foot) Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Michigan Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic Foot) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 1,021 1,021 1,022 1,026 1,020 1,022 1,024 1,021 1,019 1,019 1,017 1,019 2014 1,019 1,021 1,021 1,017 1,020 1,019 1,015 1,028 1,022 1,023 1,026 1,029 2015 1,027 1,026 1,030 1,035 1,028 1,033 1,034 1,035 1,036 1,034 1,041 1,040 - = No Data Reported; -- = Not Applicable; NA = Not

  9. Enabling Clean Consumption of Low Btu and Reactive Fuels in Gas Turbines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels ADVANCED MANUFACTURING OFFICE Enabling Clean Combustion of Low-Btu and Reactive Fuels in Gas Turbines By enabling ultralow-emission, lean premixed combustion of a wide range of gaseous opportunity fuels, this unique, fuel- fexible catalytic combustor for gas turbines can reduce natural gas consumption in industry. Introduction Gas turbines are commonly used in industry for onsite power and heating needs because of their high

  10. "NAICS",,"per Employee","of Value Added","of Shipments" "Code(a)","Economic Characteristic(b)","(million Btu)","(thousand Btu)","(thousand Btu)"

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Relative Standard Errors for Table 6.3;" " Unit: Percents." ,,,,"Consumption" ,,,"Consumption","per Dollar" ,,"Consumption","per Dollar","of Value" "NAICS",,"per Employee","of Value Added","of Shipments" "Code(a)","Economic Characteristic(b)","(million Btu)","(thousand Btu)","(thousand Btu)" ,,"Total United States" "

  11. Table 2.2 Manufacturing Energy Consumption for All Purposes, 2006 (Trillion Btu )

    U.S. Energy Information Administration (EIA) Indexed Site

    Manufacturing Energy Consumption for All Purposes, 2006 (Trillion Btu ) NAICS 1 Code Manufacturing Group Coal Coal Coke and Breeze 2 Natural Gas Distillate Fuel Oil LPG 3 and NGL 4 Residual Fuel Oil Net Electricity 5 Other 6 Shipments of Energy Sources 7 Total 8 311 Food 147 1 638 16 3 26 251 105 (s) 1,186 312 Beverage and Tobacco Products 20 0 41 1 1 3 30 11 -0 107 313 Textile Mills 32 0 65 (s) (s) 2 66 12 -0 178 314 Textile Product Mills 3 0 46 (s) 1 Q 20 (s) -0 72 315 Apparel 0 0 7 (s) (s)

  12. Fuel injection staged sectoral combustor for burning low-BTU fuel gas

    DOE Patents [OSTI]

    Vogt, Robert L. (Schenectady, NY)

    1985-02-12

    A high-temperature combustor for burning low-BTU coal gas in a gas turbine is described. The combustor comprises a plurality of individual combustor chambers. Each combustor chamber has a main burning zone and a pilot burning zone. A pipe for the low-BTU coal gas is connected to the upstream end of the pilot burning zone: this pipe surrounds a liquid fuel source and is in turn surrounded by an air supply pipe: swirling means are provided between the liquid fuel source and the coal gas pipe and between the gas pipe and the air pipe. Additional preheated air is provided by counter-current coolant air in passages formed by a double wall arrangement of the walls of the main burning zone communicating with passages of a double wall arrangement of the pilot burning zone: this preheated air is turned at the upstream end of the pilot burning zone through swirlers to mix with the original gas and air input (and the liquid fuel input when used) to provide more efficient combustion. One or more fuel injection stages (second stages) are provided for direct input of coal gas into the main burning zone. The countercurrent air coolant passages are connected to swirlers surrounding the input from each second stage to provide additional oxidant.

  13. Fuel injection staged sectoral combustor for burning low-BTU fuel gas

    DOE Patents [OSTI]

    Vogt, Robert L. (Schenectady, NY)

    1981-01-01

    A high-temperature combustor for burning low-BTU coal gas in a gas turbine is described. The combustor comprises a plurality of individual combustor chambers. Each combustor chamber has a main burning zone and a pilot burning zone. A pipe for the low-BTU coal gas is connected to the upstream end of the pilot burning zone; this pipe surrounds a liquid fuel source and is in turn surrounded by an air supply pipe; swirling means are provided between the liquid fuel source and the coal gas pipe and between the gas pipe and the air pipe. Additional preheated air is provided by counter-current coolant air in passages formed by a double wall arrangement of the walls of the main burning zone communicating with passages of a double wall arrangement of the pilot burning zone; this preheated air is turned at the upstream end of the pilot burning zone through swirlers to mix with the original gas and air input (and the liquid fuel input when used) to provide more efficient combustion. One or more fuel injection stages (second stages) are provided for direct input of coal gas into the main burning zone. The countercurrent air coolant passages are connected to swirlers surrounding the input from each second stage to provide additional oxidant.

  14. FT Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Place: South Jordan, Utah Zip: 84095 Product: JV between Headwaters Technology Innovation Group and Rentech to focus on Fischer-Tropsch (FT) gas-to-liquids processes and...

  15. Carderock 3-ft Variable Pressure Cavitation Water Tunnel | Open...

    Open Energy Info (EERE)

    3-ft Variable Pressure Cavitation Water Tunnel Jump to: navigation, search Basic Specifications Facility Name Carderock 3-ft Variable Pressure Cavitation Water Tunnel Overseeing...

  16. 3-ft Wave Flume Facility | Open Energy Information

    Open Energy Info (EERE)

    ft Wave Flume Facility Jump to: navigation, search Basic Specifications Facility Name 3-ft Wave Flume Facility Overseeing Organization United States Army Corp of Engineers (ERDC)...

  17. 5-ft Wave Flume Facility | Open Energy Information

    Open Energy Info (EERE)

    ft Wave Flume Facility Jump to: navigation, search Basic Specifications Facility Name 5-ft Wave Flume Facility Overseeing Organization United States Army Corp of Engineers (ERDC)...

  18. 1.5-ft Wave Flume Facility | Open Energy Information

    Open Energy Info (EERE)

    .5-ft Wave Flume Facility Jump to: navigation, search Basic Specifications Facility Name 1.5-ft Wave Flume Facility Overseeing Organization United States Army Corp of Engineers...

  19. Sandia Energy - Wind Plant Optimization: SWiFT Restart Technical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plant Optimization: SWiFT Restart Technical Review Committee Home SWIFT Wind Energy Wind News Wind Plant Optimization: SWiFT Restart Technical Review Committee Previous Next Wind...

  20. Combined compressed air storage-low BTU coal gasification power plant

    DOE Patents [OSTI]

    Kartsounes, George T.; Sather, Norman F.

    1979-01-01

    An electrical generating power plant includes a Compressed Air Energy Storage System (CAES) fueled with low BTU coal gas generated in a continuously operating high pressure coal gasifier system. This system is used in coordination with a continuously operating main power generating plant to store excess power generated during off-peak hours from the power generating plant, and to return the stored energy as peak power to the power generating plant when needed. The excess coal gas which is produced by the coal gasifier during off-peak hours is stored in a coal gas reservoir. During peak hours the stored coal gas is combined with the output of the coal gasifier to fuel the gas turbines and ultimately supply electrical power to the base power plant.

  1. Table 3.1 Fossil Fuel Production Prices, 1949-2011 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Fossil Fuel Production Prices, 1949-2011 (Dollars per Million Btu) Year Coal 1 Natural Gas 2 Crude Oil 3 Fossil Fuel Composite 4 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Percent Change 7 1949 0.21 1.45 0.05 0.37 0.44 3.02 0.26 1.81 – – 1950 .21 1.41 .06 .43 .43 2.95 [R] .26 1.74 -3.6 1951 .21 1.35 .06 .40 .44 2.78 .26 1.65 -5.4 1952 .21 1.31 [R] .07 .45 .44 2.73 .26 1.63 -1.0 1953 .21 1.29 .08 .50 .46 2.86 .27 1.69 3.3 1954 .19 1.18 .09 .55 .48 2.94 .28 1.70 .7 1955

  2. Growth, characterization and electrochemical properties of hierarchical CuO nanostructures for supercapacitor applications

    SciTech Connect (OSTI)

    Krishnamoorthy, Karthikeyan; Kim, Sang-Jae

    2013-09-01

    Graphical abstract: - Highlights: Hierarchical CuO nanostructures were grown on Cu foil. Monoclinic phase of CuO was grown. XPS analysis revealed the presence of Cu(2p{sub 3/2}) and Cu(2p{sub 1/2}) on the surfaces. Specific capacitance of 94 F/g was achieved for the CuO using cyclic voltammetry. Impedance spectra show their pseudo capacitor applications. - Abstract: In this paper, we have investigated the electrochemical properties of hierarchical CuO nanostructures for pseudo-supercapacitor device applications. Moreover, the CuO nanostructures were formed on Cu substrate by in situ crystallization process. The as-grown CuO nanostructures were characterized using X-ray diffraction (XRD), Fourier transform-infra red spectroscopy (FT-IR), X-ray photoelectron spectroscopy and field emission-scanning electron microscope (FE-SEM) analysis. The XRD and FT-IR analysis confirm the formation of monoclinic CuO nanostructures. FE-SEM analysis shows the formation of leave like hierarchical structures of CuO with high uniformity and controlled density. The electrochemical analysis such as cyclic voltammetry and electrochemical impedance spectroscopy studies confirms the pseudo-capacitive behavior of the CuO nanostructures. Our experimental results suggest that CuO nanostructures will create promising applications of CuO toward pseudo-supercapacitors.

  3. Commercial demonstration of atmospheric medium BTU fuel gas production from biomass without oxygen the Burlington, Vermont Project

    SciTech Connect (OSTI)

    Rohrer, J.W.

    1995-12-31

    The first U.S. demonstration of a gas turbine operating on fuel gas produced by the thermal gasification of biomass occurred at Battelle Columbus Labs (BCL) during 1994 using their high throughput indirect medium Btu gasification Process Research Unit (PRU). Zurn/NEPCO was retained to build a commercial scale gas plant utilizing this technology. This plant will have a throughput rating of 8 to 12 dry tons per hour. During a subsequent phase of the Burlington project, this fuel gas will be utilized in a commercial scale gas turbine. It is felt that this process holds unique promise for economically converting a wide variety of biomass feedstocks efficiently into both a medium Btu (500 Btu/scf) gas turbine and IC engine quality fuel gas that can be burned in engines without modification, derating or efficiency loss. Others are currently demonstrating sub-commercial scale thermal biomass gasification processes for turbine gas, utilizing both atmospheric and pressurized air and oxygen-blown fluid bed processes. While some of these approaches hold merit for coal, there is significant question as to whether they will prove economically viable in biomass facilities which are typically scale limited by fuel availability and transportation logistics below 60 MW. Atmospheric air-blown technologies suffer from large sensible heat loss, high gas volume and cleaning cost, huge gas compressor power consumption and engine deratings. Pressurized units and/or oxygen-blown gas plants are extremely expensive for plant scales below 250 MW. The FERCO/BCL process shows great promise for overcoming the above limitations by utilizing an extremely high throughout circulation fluid bed (CFB) gasifier, in which biomass is fully devolitalized with hot sand from a CFB char combustor. The fuel gas can be cooled and cleaned by a conventional scrubbing system. Fuel gas compressor power consumption is reduced 3 to 4 fold verses low Btu biomass gas.

  4. Ft. Mojave Renewable Energy Feasibility Study

    Office of Environmental Management (EM)

    Renewable Energy Feasibility Study Ft. Mojave Renewable Energy Feasibility Study Presented by Bill Cyr and Russell Gum Presented by Bill Cyr and Russell Gum Overview Document possible renewable energy sources Evaluate their feasibility Develop a business plan for implementation of selected alternatives Location along Colorado river where Arizona, California and Nevada meet Participants Aha Machav Power Service Avi Kwa Ame Farm ERCC Analytics Objectives Business plan that will result in

  5. Table 2.9 Commercial Buildings Consumption by Energy Source, Selected Years, 1979-2003 (Trillion Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Commercial Buildings Consumption by Energy Source, Selected Years, 1979-2003 (Trillion Btu) Energy Source and Year Square Footage Category Principal Building Activity Census Region 1 All Buildings 1,001 to 10,000 10,001 to 100,000 Over 100,000 Education Food Sales Food Service Health Care Lodging Mercantile and Service Office All Other Northeast Midwest South West Major Sources 2 1979 1,255 2,202 1,508 511 [3] 336 469 278 894 861 1,616 1,217 1,826 1,395 526 4,965 1983 1,242 1,935 1,646 480 [3]

  6. SWiFT site atmospheric characterization

    SciTech Connect (OSTI)

    Kelley, Christopher Lee; Ennis, Brandon Lee

    2016-01-01

    Historical meteorological tall tower data are analyzed from the Texas Tech University 200 m tower to characterize the atmospheric trends of the Scaled Wind Farm Technologies (SWiFT) site. In this report the data are analyzed to reveal bulk atmospheric trends, temporal trends and correlations of atmospheric variables. Through this analysis for the SWiFT turbines the site International Electrotechnical Commission (IEC) classification is determined to be class III-C. Averages and distributions of atmospheric variables are shown, revealing large fluctuations and the importance of understanding the actual site trends as opposed to simply using averages. The site is significantly directional with the average wind speed from the south, and particularly so in summer and fall. Site temporal trends are analyzed from both seasonal (time of the year) to daily (hour of the day) perspectives. Atmospheric stability is seen to vary most with time of day and less with time of year. Turbulence intensity is highly correlated with stability, and typical daytime unstable conditions see double the level of turbulence intensity versus that experienced during the average stable night. Shear, veer and atmospheric stability correlations are shown, where shear and veer are both highest for stable atmospheric conditions. An analysis of the Texas Tech University tower anemometer measurements is performed which reveals the extent of the tower shadow effects and sonic tilt misalignment.

  7. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect (OSTI)

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  8. "NAICS",,"per Employee","of Value Added","of Shipments" "Code(a)","Economic Characteristic(b)","(million Btu)","(thousand Btu)","(thousand Btu)"

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Relative Standard Errors for Table 6.4;" " Unit: Percents." " "," ",,,"Consumption" " "," ",,"Consumption","per Dollar" " "," ","Consumption","per Dollar","of Value" "NAICS",,"per Employee","of Value Added","of Shipments" "Code(a)","Economic Characteristic(b)","(million Btu)","(thousand

  9. Table 3.3 Consumer Price Estimates for Energy by Source, 1970-2010 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Consumer Price Estimates for Energy by Source, 1970-2010 (Dollars 1 per Million Btu) Year Primary Energy 2 Electric Power Sector 11,12 Retail Electricity 13 Total Energy 9,10,14 Coal Natural Gas 3 Petroleum Nuclear Fuel Biomass 8 Total 9,10 Distillate Fuel Oil Jet Fuel 4 LPG 5 Motor Gasoline 6 Residual Fuel Oil Other 7 Total 1970 0.38 0.59 1.16 0.73 1.43 2.85 0.42 1.38 1.71 0.18 1.29 1.08 0.32 4.98 1.65 1971 .42 .63 1.22 .77 1.46 2.90 .58 1.45 1.78 .18 1.31 1.15 .38 5.30 1.76 1972 .45 .68 1.22

  10. Industrial co-generation through use of a medium BTU gas from biomass produced in a high throughput reactor

    SciTech Connect (OSTI)

    Feldmann, H.F.; Ball, D.A.; Paisley, M.A.

    1983-01-01

    A high-throughput gasification system has been developed for the steam gasification of woody biomass to produce a fuel gas with a heating value of 475 to 500 Btu/SCF without using oxygen. Recent developments have focused on the use of bark and sawdust as feedstocks in addition to wood chips and the testing of a new reactor concept, the so-called controlled turbulent zone (CTZ) reactor to increase gas production per unit of wood fed. Operating data from the original gasification system and the CTZ system are used to examine the preliminary economics of biomass gasification/gas turbine cogeneration systems. In addition, a ''generic'' pressurized oxygen-blown gasification system is evaluated. The economics of these gasification systems are compared with a conventional wood boiler/steam turbine cogeneration system.

  11. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    SciTech Connect (OSTI)

    Smith, V.E.; Merriam, N.W.

    1994-10-01

    Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

  12. Spherically symmetric static spacetimes in vacuum f(T) gravity

    SciTech Connect (OSTI)

    Ferraro, Rafael; Fiorini, Franco

    2011-10-15

    We show that Schwarzschild geometry remains as a vacuum solution for those four-dimensional f(T) gravitational theories behaving as ultraviolet deformations of general relativity. In the gentler context of three-dimensional gravity, we also find that the infrared-deformed f(T) gravities, like the ones used to describe the late cosmic speed up of the Universe, have as the circularly symmetric vacuum solution a Deser-de Sitter or a Banados, Teitelboim and Zanelli-like spacetime with an effective cosmological constant depending on the infrared scale present in the function f(T).

  13. Ft. Carson Army Base, Colorado Springs, Colorado | Department of Energy

    Office of Environmental Management (EM)

    Ft. Carson Army Base, Colorado Springs, Colorado Ft. Carson Army Base, Colorado Springs, Colorado Photo of High-Bay Aviation Maintenance Facility at Butts Army Airfield Fort Carson U.S. Army Base is located south of Colorado Springs, Colorado. It was the first Federal facility to install a "solar wall"-a solar ventilation air preheating system. The solar wall heats Ft. Carson's new high-bay aviation maintenance facility at Butts Army Airfield by pre-warming air as much as 54°F and

  14. Low NO{sub x} turbine power generation utilizing low Btu GOB gas. Final report, June--August 1995

    SciTech Connect (OSTI)

    Ortiz, I.; Anthony, R.V.; Gabrielson, J.; Glickert, R.

    1995-08-01

    Methane, a potent greenhouse gas, is second only to carbon dioxide as a contributor to potential global warming. Methane liberated by coal mines represents one of the most promising under exploited areas for profitably reducing these methane emissions. Furthermore, there is a need for apparatus and processes that reduce the nitrogen oxide (NO{sub x}) emissions from gas turbines in power generation. Consequently, this project aims to demonstrate a technology which utilizes low grade fuel (CMM) in a combustion air stream to reduce NO{sub x} emissions in the operation of a gas turbine. This technology is superior to other existing technologies because it can directly use the varying methane content gases from various streams of the mining operation. The simplicity of the process makes it useful for both new gas turbines and retrofitting existing gas turbines. This report evaluates the feasibility of using gob gas from the 11,000 acre abandoned Gateway Mine near Waynesburg, Pennsylvania as a fuel source for power generation applying low NO{sub x} gas turbine technology at a site which is currently capable of producing low grade GOB gas ({approx_equal} 600 BTU) from abandoned GOB areas.

  15. Philadelphia gas works medium-Btu coal gasification project: capital and operating cost estimate, financial/legal analysis, project implementation

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    This volume of the final report is a compilation of the estimated capital and operating costs for the project. Using the definitive design as a basis, capital and operating costs were developed by obtaining quotations for equipment delivered to the site. Tables 1.1 and 1.2 provide a summary of the capital and operating costs estimated for the PGW Coal Gasification Project. In the course of its Phase I Feasibility Study of a medium-Btu coal-gas facility, Philadelphia Gas Works (PGW) identified the financing mechanism as having great impact on gas cost. Consequently, PGW formed a Financial/Legal Task Force composed of legal, financial, and project analysis specialists to study various ownership/management options. In seeking an acceptable ownership, management, and financing arrangement, certain ownership forms were initially identified and classified. Several public ownership, private ownership, and third party ownership options for the coal-gas plant are presented. The ownership and financing forms classified as base alternatives involved tax-exempt and taxable financing arrangements and are discussed in Section 3. Project implementation would be initiated by effectively planning the methodology by which commercial operation will be realized. Areas covered in this report are sale of gas to customers, arrangements for feedstock supply and by-product disposal, a schedule of major events leading to commercialization, and a plan for managing the implementation.

  16. Low/medium Btu coal gasification assessment of central plant for the city of Philadelphia, Pennsylvania. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-02-01

    The objective of this study is to assess the technical and economic feasibility of producing, distributing, selling, and using fuel gas for industrial applications in Philadelphia. The primary driving force for the assessment is the fact that oil users are encountering rapidly escalating fuel costs, and are uncertain about the future availability of low sulfur fuel oil. The situation is also complicated by legislation aimed at reducing oil consumption and by difficulties in assuring a long term supply of natural gas. Early in the gasifier selection study it was decided that the level of risk associated with the gasification process sould be minimal. It was therefore determined that the process should be selected from those commercially proven. The following processes were considered: Lurgi, KT, Winkler, and Wellman-Galusha. From past experience and a knowledge of the characteristics of each gasifier, a list of advantages and disadvantages of each process was formulated. It was concluded that a medium Btu KT gas can be manufactured and distributed at a lower average price than the conservatively projected average price of No. 6 oil, provided that the plant is operated as a base load producer of gas. The methodology used is described, assumptions are detailed and recommendations are made. (LTN)

  17. Table 2.4 Household Energy Consumption by Census Region, Selected Years, 1978-2009 (Quadrillion Btu, Except as Noted)

    U.S. Energy Information Administration (EIA) Indexed Site

    Household 1 Energy Consumption by Census Region, Selected Years, 1978-2009 (Quadrillion Btu, Except as Noted) Census Region 2 1978 1979 1980 1981 1982 1984 1987 1990 1993 1997 2001 2005 2009 United States Total (does not include wood) 10.56 9.74 9.32 9.29 8.58 9.04 9.13 9.22 10.01 10.25 9.86 10.55 10.18 Natural Gas 5.58 5.31 4.97 5.27 4.74 4.98 4.83 4.86 5.27 5.28 4.84 4.79 4.69 Electricity 3 2.47 2.42 2.48 2.42 2.35 2.48 2.76 3.03 3.28 3.54 3.89 4.35 4.39 Distillate Fuel Oil and Kerosene 2.19

  18. System and process for the abatement of casting pollution, reclaiming resin bonded sand, and/or recovering a low BTU fuel from castings

    DOE Patents [OSTI]

    Scheffer, Karl D. (121 Governor Dr., Scotia, NY 12302)

    1984-07-03

    Air is caused to flow through the resin bonded mold to aid combustion of the resin binder to form a low BTU gas fuel. Casting heat is recovered for use in a waste heat boiler or other heat abstraction equipment. Foundry air pollution is reduced, the burned portion of the molding sand is recovered for immediate reuse and savings in fuel and other energy is achieved.

  19. System and process for the abatement of casting pollution, reclaiming resin bonded sand, and/or recovering a low Btu fuel from castings

    DOE Patents [OSTI]

    Scheffer, K.D.

    1984-07-03

    Air is caused to flow through the resin bonded mold to aid combustion of the resin binder to form a low Btu gas fuel. Casting heat is recovered for use in a waste heat boiler or other heat abstraction equipment. Foundry air pollutis reduced, the burned portion of the molding sand is recovered for immediate reuse and savings in fuel and other energy is achieved. 5 figs.

  20. Cosmological viability conditions for f(T) dark energy models

    SciTech Connect (OSTI)

    Setare, M.R.; Mohammadipour, N. E-mail: N.Mohammadipour@uok.ac.ir

    2012-11-01

    Recently f(T) modified teleparallel gravity where T is the torsion scalar has been proposed as the natural gravitational alternative for dark energy. We perform a detailed dynamical analysis of these models and find conditions for the cosmological viability of f(T) dark energy models as geometrical constraints on the derivatives of these models. We show that in the phase space exists two cosmologically viable trajectory which (i) The universe would start from an unstable radiation point, then pass a saddle standard matter point which is followed by accelerated expansion de sitter point. (ii) The universe starts from a saddle radiation epoch, then falls onto the stable matter era and the system can not evolve to the dark energy dominated epoch. Finally, for a number of f(T) dark energy models were proposed in the more literature, the viability conditions are investigated.

  1. Low-cost CuInSe[sub 2] submodule development

    SciTech Connect (OSTI)

    Basol, B.M.; Kapur, V.K.; Halani, A.; Leidholm, C. )

    1992-10-01

    Aim of this project is development and demonstration of processing steps necessary for fabrication of high efficiency CuInSe[sub 2] solar cells and sub-modules by the two-stage technique (also called the selenization method.) During this period, we have optimized the processing parameters of this method and demonstrated CuInSe[sub 2]/CdS/ZnO devices with a 1[endash]4 cm[sup 2] area and up to 12.4% active area efficiency. We have also developed a novel approach for the preparation of Cu/In precursors that improved the stoichiometric and morphological uniformity in these films. We have developed processing steps and tooling for handling up to 1 ft[sup 2] size substrates and as a result of these efforts demonstrated our first monolithically integrated sub-module of 1 ft[sup 2] area. 16 figs, 1 tab, 15 refs.

  2. Table A23. Quantity of Purchased Electricity, Steam, and Natural Gas by Type

    U.S. Energy Information Administration (EIA) Indexed Site

    3. Quantity of Purchased Electricity, Steam, and Natural Gas by Type" " of Supplier, Census Region, Industry Group, and Selected Industries, 1991" " (Estimates in Btu or Physical Units)" ,," Electricity",," Steam",," Natural Gas" ,," (Million kWh)",," (Billion Btu)",," (Billion cu ft)" ,," -------------------------",," -------------------------",,"

  3. Table A27. Quantity of Purchased Electricity, Steam, and Natural Gas by Type

    U.S. Energy Information Administration (EIA) Indexed Site

    Quantity of Purchased Electricity, Steam, and Natural Gas by Type" " of Supplier, Census Region, and Economic Characteristics of the Establishment," 1991 " (Estimates in Btu or Physical Units)" " "," Electricity",," Steam",," Natural Gas" ," (Million (kWh)",," (Billion Btu)",," (Billion cu ft)" ," -----------------------",," -----------------------",,"

  4. Generalized second law of thermodynamics in f(T) gravity

    SciTech Connect (OSTI)

    Karami, K.; Abdolmaleki, A. E-mail: AAbdolmaleki@uok.ac.ir

    2012-04-01

    We investigate the validity of the generalized second law (GSL) of gravitational thermodynamics in the framework of f(T) modified teleparallel gravity. We consider a spatially flat FRW universe containing only the pressureless matter. The boundary of the universe is assumed to be enclosed by the Hubble horizon. For two viable f(T) models containing f(T) = T+?{sub 1}((?T)){sup n} and f(T) = T??{sub 2}T(1?e{sup ?T{sub 0}/T}), we first calculate the effective equation of state and deceleration parameters. Then, (we investigate the null and strong energy conditions and conclude that a sudden future singularity appears in both models. Furthermore, using a cosmographic analysis we check the viability of two models. Finally, we examine the validity of the GSL and find that for both models it) is satisfied from the early times to the present epoch. But in the future, the GSL is violated for the special ranges of the torsion scalar T.

  5. Sandia Energy - New Facility Tool at SWiFT Makes Rotor Work More...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facility Tool at SWiFT Makes Rotor Work More Efficient Home Renewable Energy Energy SWIFT Facilities Partnership News Wind Energy News & Events New Facility Tool at SWiFT Makes...

  6. SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches Data for a number of...

  7. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: ...

  8. Technology development for iron F-T catalysts. Final report

    SciTech Connect (OSTI)

    Frame, R.R.; Gala, H.B.

    1994-08-01

    The objectives of this work were twofold. The first objective was to design and construct a pilot plant for preparing precipitated iron oxide F-T precursors and demonstrate that the rate of production from this plant is equivalent to 100 lbs/day of dried metal oxide. Secondly, these precipitates were to be used to prepare catalysts capable of achieving 88% CO + H{sub 2} conversion with {le} 5 mole percent selectivity to methane + ethane.

  9. A new day: SWiFT reaches rotor mounting milestone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    day: SWiFT reaches rotor mounting milestone - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste

  10. Cosmological perturbation in f(T) gravity revisited

    SciTech Connect (OSTI)

    Izumi, Keisuke; Ong, Yen Chin E-mail: ongyenchin@member.ams.org

    2013-06-01

    We perform detailed investigation of cosmological perturbations in f(T) theory of gravity coupled with scalar field. Our work emphasizes on the way to gauge fix the theory and we examine all possible modes of perturbations up to second order. The analysis includes pseudoscalar and pseudovector modes in addition to the usual scalar, vector, and tensor modes. We find no gravitational propagating degree of freedom in the scalar, pseudoscalar, vector, as well as pseudovector modes. In addition, we find that the scalar and tensor perturbations have exactly the same form as their counterparts in usual general relativity with scalar field, except that the factor of reduced Planck mass squared M{sub pl}{sup 2}?1/(8?G) that occurs in the latter has now been replaced by an effective time-dependent gravitational coupling ?2(df/dT)|{sub T=T{sub 0}}, with T{sub 0} being the background torsion scalar. The absence of extra degrees of freedom of f(T) gravity at second order linear perturbation indicates that f(T) gravity is highly nonlinear. Consequently one cannot conclusively analyze stability of the theory without performing nonlinear analysis that can reveal the propagation of the extra degrees of freedom.

  11. Can f(T) gravity theories mimic ?CDM cosmic history

    SciTech Connect (OSTI)

    Setare, M.R.; Mohammadipour, N. E-mail: N.Mohammadipour@uok.ac.ir

    2013-01-01

    Recently the teleparallel Lagrangian density described by the torsion scalar T has been extended to a function of T. The f(T) modified teleparallel gravity has been proposed as the natural gravitational alternative for dark energy to explain the late time acceleration of the universe. In order to reconstruct the function f(T) by demanding a background ?CDM cosmology we assume that, (i) the background cosmic history provided by the flat ?CDM (the radiation ere with ?{sub eff} = (1/3), matter and de Sitter eras with ?{sub eff} = 0 and ?{sub eff} = ?1, respectively) (ii) the radiation dominate in the radiation era with ?{sub 0r} = 1 and the matter dominate during the matter phases when ?{sub 0m} = 1. We find the cosmological dynamical system which can obey the ?CDM cosmic history. In each era, we find a critical lines that, the radiation dominated and the matter dominated are one points of them in the radiation and matter phases, respectively. Also, we drive the cosmologically viability condition for these models. We investigate the stability condition with respect to the homogeneous scalar perturbations in each era and we obtain the stability conditions for the fixed points in each eras. Finally, we reconstruct the function f(T) which mimics cosmic expansion history.

  12. Thermochemical process for recovering Cu from CuO or CuO.sub.2

    DOE Patents [OSTI]

    Richardson, deceased, Donald M. (late of Oak Ridge, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1981-01-01

    A process for producing hydrogen comprises the step of reacting metallic Cu with Ba(OH).sub.2 in the presence of steam to produce hydrogen and BaCu.sub.2 O.sub.2. The BaCu.sub.2 O.sub.2 is reacted with H.sub.2 O to form Cu.sub.2 O and a Ba(OH).sub.2 product for recycle to the initial reaction step. Cu can be obtained from the Cu.sub.2 O product by several methods. In one embodiment the Cu.sub.2 O is reacted with HF solution to provide CuF.sub.2 and Cu. The CuF.sub.2 is reacted with H.sub.2 O to provide CuO and HF. CuO is decomposed to Cu.sub.2 O and O.sub.2. The HF, Cu and Cu.sub.2 O are recycled. In another embodiment the Cu.sub.2 O is reacted with aqueous H.sub.2 SO.sub.4 solution to provide CuSO.sub.4 solution and Cu. The CuSO.sub.4 is decomposed to CuO and SO.sub.3. The CuO is decomposed to form Cu.sub.2 O and O.sub.2. The SO.sub.3 is dissolved to form H.sub.2 SO.sub.4. H.sub.2 SO.sub.4, Cu and Cu.sub.2 O are recycled. In another embodiment Cu.sub.2 O is decomposed electrolytically to Cu and O.sub.2. In another aspect of the invention, Cu is recovered from CuO by the steps of decomposing CuO to Cu.sub.2 O and O.sub.2, reacting the Cu.sub.2 O with aqueous HF solution to produce Cu and CuF.sub.2, reacting the CuF.sub.2 with H.sub.2 O to form CuO and HF, and recycling the CuO and HF to previous reaction steps.

  13. Level: National Data; Row: End Uses within NAICS Codes; Column: Energy Sources, including Net Electricity;

    Gasoline and Diesel Fuel Update (EIA)

    1 End Uses of Fuel Consumption, 2006; Level: National Data; Row: End Uses within NAICS Codes; Column: Energy Sources, including Net Electricity; Unit: Physical Units or Btu. Distillate Coal Fuel Oil (excluding Coal Net Residual and Natural Gas(d) LPG and Coke and Breeze) NAICS Total Electricity(b) Fuel Oil Diesel Fuel(c) (billion NGL(e) (million Other(f) Code(a) End Use (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) (trillion Btu) Total United States

  14. Level: National and Regional Data; Row: End Uses; Column: Energy Sources, including Net Electricity;

    Gasoline and Diesel Fuel Update (EIA)

    5 End Uses of Fuel Consumption, 2006; Level: National and Regional Data; Row: End Uses; Column: Energy Sources, including Net Electricity; Unit: Physical Units or Btu. Distillate Coal Fuel Oil (excluding Coal Net Residual and Natural Gas(c) LPG and Coke and Breeze) Total Electricity(a) Fuel Oil Diesel Fuel(b) (billion NGL(d) (million Other(e) End Use (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) (trillion Btu) Total United States TOTAL FUEL CONSUMPTION

  15. Table 2.1 Nonfuel (Feedstock) Use of Combustible Energy, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Nonfuel (Feedstock) Use of Combustible Energy, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Physical Units or Btu. Coke Residual Distillate Natural Gas(c) LPG and Coal and Breeze NAICS Total Fuel Oil Fuel Oil(b) (billion NGL(d) (million (million Other(e) Code(a) Subsector and Industry (trillion Btu) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) Total United States 311 Food 10 * * 4 Q 0 0 2 3112 Grain and

  16. Table 3.1 Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Fuel Consumption, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Physical Units or Btu. Coke Net Residual Distillate Natural Gas(d) LPG and Coal and Breeze NAICS Total Electricity(b) Fuel Oil Fuel Oil(c) (billion NGL(e) (million (million Other(f) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) Total United States 311 Food 1,158 75,407 2 4 563 1 8 * 99

  17. Table 4.1 Offsite-Produced Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Offsite-Produced Fuel Consumption, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Physical Units or Btu. Coke Residual Distillate Natural Gas(d) LPG and Coal and Breeze NAICS Total Electricity(b) Fuel Oil Fuel Oil(c) (billion NGL(e) (million (million Other(f) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) Total United States 311 Food 1,113 75,673 2 4

  18. Table 5.1 End Uses of Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    5.1 End Uses of Fuel Consumption, 2010; Level: National Data; Row: End Uses within NAICS Codes; Column: Energy Sources, including Net Electricity; Unit: Physical Units or Btu. Distillate Coal Fuel Oil (excluding Coal Net Residual and Natural Gas(d) LPG and Coke and Breeze) NAICS Total Electricity(b) Fuel Oil Diesel Fuel(c) (billion NGL(e) (million Other(f) Code(a) End Use (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) (trillion Btu) Total United States

  19. Table 5.5 End Uses of Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    5 End Uses of Fuel Consumption, 2010; Level: National and Regional Data; Row: End Uses; Column: Energy Sources, including Net Electricity; Unit: Physical Units or Btu. Distillate Coal Fuel Oil (excluding Coal Net Residual and Natural Gas(c) LPG and Coke and Breeze) Total Electricity(a) Fuel Oil Diesel Fuel(b) (billion NGL(d) (million Other(e) End Use (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) (trillion Btu) Total United States TOTAL FUEL CONSUMPTION

  20. Table 7.6 Quantity of Purchased Energy Sources, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Quantity of Purchased Energy Sources, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Physical Units or Btu. Coke Residual Distillate Natural Gas(c) LPG and Coal and Breeze NAICS Total Electricity Fuel Oil Fuel Oil(b) (billion NGL(d) (million (million Other(e) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) Total United States 311 Food 1,108 75,652 2 4

  1. Originally Released: July 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    Coke and Shipments Net Residual Distillate Natural Gas(e) LPG and Coal Breeze of Energy Sources NAICS Total(b) Electricity(c) Fuel Oil Fuel Oil(d) (billion NGL(f) (million (million Other(g) Produced Onsite(h) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) (trillion Btu) Total United States 311 Food 1,186 73,440 4 3 620 1 7 * 105 * 3112 Grain and Oilseed Milling 318 15,464 * * 117 * 5 0 29 *

  2. Originally Released: July 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    Coke and Shipments Net Residual Distillate Natural Gas(e) LPG and Coal Breeze of Energy Sources NAICS Total(b) Electricity(c) Fuel Oil Fuel Oil(d) (billion NGL(f) (million (million Other(g) Produced Onsite(h) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) (trillion Btu) Total United States 311 Food 1,186 73,440 4 3 620 1 7 * 105 * 3112 Grain and Oilseed Milling 318 15,464 * * 117 * 5 0 29 *

  3. Originally Released: July 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Nonfuel (Feedstock) Use of Combustible Energy, 2006 Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources Unit: Physical Units or Btu. Coke Residual Distillate Natural Gas(c) LPG and Coal and Breeze NAICS Total Fuel Oil Fuel Oil(b) (billion NGL(d) (million (million Other(e) Code(a) Subsector and Industry (trillion Btu) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) Total United States 311 Food 3 0 * 2 * 0 * * 3112 Grain and Oilseed

  4. Originally Released: July 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Fuel Consumption, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources Unit: Physical Units or Btu Coke Net Residual Distillate Natural Gas(d) LPG and Coal and Breeze NAICS Total Electricity(b) Fuel Oil Fuel Oil(c) (billion NGL(e) (million (million Other(f) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) Total United States 311 Food 1,186 73,440 4 3 618 1 7 * 107

  5. Originally Released: July 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    4.1 Offsite-Produced Fuel Consumption, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Physical Units or Btu. Coke Residual Distillate Natural Gas(d) LPG and Coal and Breeze NAICS Total Electricity(b) Fuel Oil Fuel Oil(c) (billion NGL(e) (million (million Other(f) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) short tons) (trillion Btu) Total United States 311 Food 1,124 73,551 4 3

  6. table2.1_02.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Nonfuel (Feedstock) Use of Combustible Energy, 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Physical Units or Btu. Coke Residual Distillate Natural LPG and Coal and Breeze NAICS Total Fuel Oil Fuel Oil(b) Gas(c) NGL(d) (million (million Other(e) Code(a) Subsector and Industry (trillion Btu) (million bbl) (million bbl) (billion cu ft) (million bbl) short tons) short tons) (trillion Btu) Total United States RSE Column Factors: 1.4 0.4 1.6 1.2 1.2 1.1

  7. table4.1_02.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Offsite-Produced Fuel Consumption, 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Physical Units or Btu. Coke Residual Distillate Natural LPG and Coal and Breeze RSE NAICS Total Electricity(b) Fuel Oil Fuel Oil(c) Gas(d) NGL(e) (million (million Other(f) Row Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) (billion cu ft) (million bbl) short tons) short tons) (trillion Btu) Factors Total United States RSE Column

  8. table5.1_02

    U.S. Energy Information Administration (EIA) Indexed Site

    1 End Uses of Fuel Consumption, 2002; Level: National Data; Row: End Uses within NAICS Codes; Column: Energy Sources, including Net Electricity; Unit: Physical Units or Btu. Distillate Fuel Oil Coal Net Residual and Natural LPG and (excluding Coal RSE NAICS Total Electricity(b) Fuel Oil Diesel Fuel(c) Gas(d) NGL(e) Coke and Breeze) Other(f) Row Code(a) End Use (trillion Btu) (million kWh) (million bbl) (million bbl) (billion cu ft) (million bbl) (million short tons) (trillion Btu) Factors Total

  9. table5.5_02

    U.S. Energy Information Administration (EIA) Indexed Site

    5 End Uses of Fuel Consumption, 2002; Level: National and Regional Data; Row: End Uses; Column: Energy Sources, including Net Electricity; Unit: Physical Units or Btu. Distillate Fuel Oil Coal Net Residual and Natural LPG and (excluding Coal RSE Total Electricity(a) Fuel Oil Diesel Fuel(b) Gas(c) NGL(d) Coke and Breeze) Other(e) Row End Use (trillion Btu) (million kWh) (million bbl) (million bbl) (billion cu ft) (million bbl) (million short tons) (trillion Btu) Factors Total United States RSE

  10. table7.6_02.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Quantity of Purchased Energy Sources, 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Physical Units or Btu. Coke Residual Distillate Natural LPG and Coal and Breeze RSE NAICS Total Electricity Fuel Oil Fuel Oil(b) Gas(c) NGL(d) (million (million Other(e) Row Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) (billion cu ft) (million bbl) short tons) short tons) (trillion Btu) Factors Total United States RSE Column

  11. Table 1.13 U.S. Government Energy Consumption by Agency and Source, Fiscal Years 2003, 2010, and 2011 (Trillion Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    3 U.S. Government Energy Consumption by Agency and Source, Fiscal Years 2003, 2010, and 2011 (Trillion Btu) Resource and Fiscal Years Agriculture Defense Energy GSA 1 HHS 2 Interior Justice NASA 3 Postal Service Trans- portation Veterans Affairs Other 4 Total Coal 2003 (s) 15.4 2.0 0.0 (s) (s) 0.0 0.0 0.0 0.0 0.2 0.0 17.7 2010 (s) 15.5 4.5 .0 0.0 0.0 .0 .0 (s) .0 .1 .0 20.1 2011 P 0.0 14.3 4.2 .0 .0 .0 .0 .0 (s) .0 .1 .0 18.6 Natural Gas 5 2003 1.4 76.6 7.0 7.6 3.7 1.3 8.6 2.9 10.4 .7 15.6 4.2

  12. Table 3.4 Consumer Price Estimates for Energy by End-Use Sector, 1970-2010 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Consumer Price Estimates for Energy by End-Use Sector, 1970-2010 (Dollars 1 per Million Btu) Year Residential Commercial Industrial Transportation Natural Gas 2 Petroleum Retail Electricity 3 Total 4 Natural Gas 2 Petroleum 5 Retail Electricity 3 Total 6,7 Coal Natural Gas 2 Petroleum 5 Biomass 8 Retail Electricity 3 Total 7,9 Petroleum 5 Total 7,10 1970 1.06 1.54 6.51 2.10 0.75 0.90 [R] 6.09 1.97 0.45 0.38 0.98 1.59 2.99 0.84 2.31 2.31 1971 1.12 1.59 6.80 2.24 .80 1.02 6.44 2.15 .50 .41 1.05

  13. Commercial low-Btu coal-gasification plant. Feasibility study: General Refractories Company, Florence, Kentucky. Volume I. Project summary. [Wellman-Galusha

    SciTech Connect (OSTI)

    1981-11-01

    In response to a 1980 Department of Energy solicitation, the General Refractories Company submitted a Proposal for a feasibility study of a low Btu gasification facility for its Florence, KY plant. The proposed facility would substitute low Btu gas from a fixed bed gasifier for natural gas now used in the manufacture of insulation board. The Proposal from General Refractories was prompted by a concern over the rising costs of natural gas, and the anticipation of a severe increase in fuel costs resulting from deregulation. The proposed feasibility study is defined. The intent is to provide General Refractories with the basis upon which to determine the feasibility of incorporating such a facility in Florence. To perform the work, a Grant for which was awarded by the DOE, General Refractories selected Dravo Engineers and Contractors based upon their qualifications in the field of coal conversion, and the fact that Dravo has acquired the rights to the Wellman-Galusha technology. The LBG prices for the five-gasifier case are encouraging. Given the various natural gas forecasts available, there seems to be a reasonable possibility that the five-gasifier LBG prices will break even with natural gas prices somewhere between 1984 and 1989. General Refractories recognizes that there are many uncertainties in developing these natural gas forecasts, and if the present natural gas decontrol plan is not fully implemented some financial risks occur in undertaking the proposed gasification facility. Because of this, General Refractories has decided to wait for more substantiating evidence that natural gas prices will rise as is now being predicted.

  14. SWiFT Turbines Full Dynamic Characterization Opens Doors for Research in

    Energy Savers [EERE]

    the Dynamics of Coupled Systems | Department of Energy SWiFT Turbines Full Dynamic Characterization Opens Doors for Research in the Dynamics of Coupled Systems SWiFT Turbines Full Dynamic Characterization Opens Doors for Research in the Dynamics of Coupled Systems March 31, 2014 - 11:19am Addthis Research conducted at the Scaled Wind Farm Technology Facility (SWiFT) in Lubbock, Texas, drew a lot of interest from attendees at the International Modal Analysis Conference held in Orlando,

  15. Attrition Resistant Iron-Based Catalysts For F-T SBCRs

    SciTech Connect (OSTI)

    Adeyinka A. Adeyiga

    2006-01-31

    The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+ H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. The use of iron-(FE) based catalysts is attractive not only due to their low cost and ready availability, but also due to their high water-gas shift activity which makes it possible to use these catalysts with low H{sub 2}/CO ratios. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment; makes the separation of catalyst from the oil/wax product very difficult, if not impossible; and results in a steady loss of catalyst from the reactor. Under a previous Department of Energy (DOE)/University Research Grant (UCR) grant, Hampton University reported, for the first time, the development of demonstrably attrition-resistant Fe F-T synthesis catalysts having good activity, selectivity, and attrition resistance. These catalysts were prepared by spray drying Fe catalysts with potassium (K), copper (Cu), and silica (SiO{sub 2}) as promoters. SiO{sub 2} was also used as a binder for spray drying. These catalysts were tested for activity and selectivity in a laboratory-scale fixed-bed reactor. Fundamental understanding of attrition is being addressed by incorporating suitable binders into the catalyst recipe. This has resulted in the preparation of a spray dried HPR-43 catalyst having average particle size (aps) of 70 {micro}m with high attrition resistance. This HPR-43 attrition resistant, active and selective catalyst gave 95% CO conversion through 125 hours of testing in a fixed-bed at 270 C, 1.48 MPa, H{sub 2}/CO=0.67 and 2.0 NL/g-cat/h with C{sub 5+} selectivity of >78% and methane selectivity of less than 5% at an {alpha} of 0.9. Research is proposed to enable further development and optimization of these catalysts by (1) better understanding the role and interrelationship of various catalyst composition and preparation parameters on attrition resistance, activity, and selectivity of these catalysts, (2) the presence of sulfide ions on a precipitated iron catalyst, and (3) the effect of water on sulfided iron F-T catalysts for its activity, selectivity, and attrition. Catalyst preparations will be based on spray drying. The research employed, among other measurements, attrition testing and F-T synthesis at high pressure. Catalyst activity and selectivity is evaluated using a small fixed-bed reactor and a continuous stirred tank reactor (CSTR). The catalysts were prepared by co-precipitation, followed by binder addition and spray drying at 250 C in a 1-m-diameter, 2-m-tall spray dryer. The binder silica content was varied from 0 to 20 wt%. The results show that the use of small amounts of precipitated SiO{sub 2} alone in spray-dried Fe catalysts can result in good attrition resistance. All catalysts investigated with SiO2 wt% {le} 12 produced fines less than 10 wt% during the jet cup attrition test, making them suitable for long-term use in a slurry bubble column reactor. Thus, concentration rather than the type of SiO{sub 2} incorporated into catalyst has a more critical impact on catalyst attrition resistance of spray-dried Fe catalysts. Lower amounts of SiO{sub 2} added to a catalyst give higher particle densities and therefore higher attrition resistances. In order to produce a suitable SBCR catalyst, however, the amount of SiO{sub 2} added has to be optimized to provide adequate surface area, particle density, and attrition resistance. Two of the catalysts with precipitated and binder silica were tested in Texas A&M University's CSTR (Autoclave Engineers). The two catalysts were also tested at The Center for Applied Energy Research in Lexington, Kentucky of the University of Kentucky. Spray-dried catalysts with compositions 100 Fe/5 Cu/4.2 K/11 (P) SiO{sub 2} and

  16. Sandia Energy - Power Production Started on All Three SWiFT Turbines

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power Production Started on All Three SWiFT Turbines Home Renewable Energy Energy SWIFT Facilities Partnership News Wind Energy News & Events Power Production Started on All Three...

  17. Violation of the first law of black hole thermodynamics in f(T) gravity

    SciTech Connect (OSTI)

    Miao, Rong-Xin; Li, Miao; Miao, Yan-Gang E-mail: mli@itp.ac.cn

    2011-11-01

    We prove that, in general, the first law of black hole thermodynamics, ?Q = T?S, is violated in f(T) gravity. As a result, it is possible that there exists entropy production, which implies that the black hole thermodynamics can be in non-equilibrium even in the static spacetime. This feature is very different from that of f(R) or that of other higher derivative gravity theories. We find that the violation of first law results from the lack of local Lorentz invariance in f(T) gravity. By investigating two examples, we note that f''(0) should be negative in order to avoid the naked singularities and superluminal motion of light. When f''(T) is small, the entropy of black holes in f(T) gravity is approximatively equal to f'(T)/4 A.

  18. Well cored to 9,800 ft in Paraguay

    SciTech Connect (OSTI)

    Gunn, K.B. )

    1991-05-13

    The mining industry's slim hole drilling rigs have proven applicable to primary oil exploration. These machines are smaller than conventional drilling rigs and can be transported with relative ease to remote locations. A typical rig drills an entire well by coring, with the cores retrieved by wire line without tripping the pipe. The core drilling system is specially suited to drilling hard rock formations. This paper reports on the project which evaluated the geological aspects of the Parana basin and determined the applicability of slim hole, core drilling techniques as an exploration tool. The Parana basin is found in the eastern third of Paraguay, part of northeastern Argentina, and part of southern Brazil. Much of the basin is overlaid by basalt flows up to 5,000-ft thick, and there are numerous igneous intrusions and dikes within the sedimentary section. This combination makes seismic quality poor and interpretation extremely difficult. The formations are relatively old, with Triassic red beds occurring only a few feet below the surface or immediately below the basalt. Beneath the Triassic are Permian marine deposits, Permo-Carboniferous tillites, and then Devonian, Silurian, and Ordovician deposits to the basement. The section outcrops 100 miles west of the Mallorquin Well No. 1 site. The Parana basin has been only randomly explored. To date, success has been limited to a minor gas find near Sao Paulo, Brazil.

  19. Alvord (3000-ft Strawn) LPG flood: design and performance evaluation

    SciTech Connect (OSTI)

    Frazier, G.D.; Todd, M.R.

    1982-01-01

    Mitchell Energy Corporation has implemented a LPG-dry gas miscible process in the Alvord (3000 ft Strawn) Unit in Wise County, Texas utilizing the DOE tertiary incentive program. The field had been waterflooded for 14 years and was producing near its economic limit at the time this project was started. This paper presents the results of the reservoir simulation study that was conducted to evaluate pattern configuration and operating alternatives so as to maximize LPG containment and oil recovery performance. Several recommendations resulting from this study were implemented for the project. Based on the model prediction, tertiary oil recovery is expected to be between 100,000 and 130,000 bbls, or about 7 percent of th oil originally in place in the Unit. An evaluation of the project performance to date is presented. In July of 1981 the injection of a 16% HPV slug of propane was completed. Natural gas is being used to drive the propane slug. A peak oil response of 222 BOPD was achieved in August of 1981 and production has since been declining. The observed performance of the flood indicates that the actual tertiary oil recovered will reach the predicted value, although the project life will be longer than expected. The results presented in this paper indicate that, without the DOE incentive program, the economics for this project would still be uncertain at this time.

  20. Low-cost CuInSe{sub 2} submodule development. Final subcontract report, 9 July 1990--31 January 1992

    SciTech Connect (OSTI)

    Basol, B.M.; Kapur, V.K.; Halani, A.; Leidholm, C.

    1992-10-01

    Aim of this project is development and demonstration of processing steps necessary for fabrication of high efficiency CuInSe{sub 2} solar cells and sub-modules by the two-stage technique (also called the selenization method.) During this period, we have optimized the processing parameters of this method and demonstrated CuInSe{sub 2}/CdS/ZnO devices with a 1{endash}4 cm{sup 2} area and up to 12.4% active area efficiency. We have also developed a novel approach for the preparation of Cu/In precursors that improved the stoichiometric and morphological uniformity in these films. We have developed processing steps and tooling for handling up to 1 ft{sup 2} size substrates and as a result of these efforts demonstrated our first monolithically integrated sub-module of 1 ft{sup 2} area. 16 figs, 1 tab, 15 refs.

  1. Hydrodynamic evolution and jet energy loss in Cu + Cu collisions

    SciTech Connect (OSTI)

    Schenke, Bjoern; Jeon, Sangyong; Gale, Charles

    2011-04-15

    We present results from a hybrid description of Cu + Cu collisions using (3 + 1)-dimensional hydrodynamics (music) for the bulk evolution and a Monte Carlo simulation (martini) for the evolution of high-momentum partons in the hydrodynamical background. We explore the limits of this description by going to small system sizes and determine the dependence on different fractions of wounded nucleon and binary collisions scaling of the initial energy density. We find that Cu + Cu collisions are well described by the hybrid description at least up to 20% central collisions.

  2. cu | OpenEI Community

    Open Energy Info (EERE)

    ancient building system architect biomimicry building technology cooling cu daylight design problem energy use engineer fred andreas geothermal green building heat transfer...

  3. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Comparison to Reference Methods | Department of Energy Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_lake.pdf More Documents & Publications Reductant Utilization in a LNT + SCR System Spatiotemporal Distribution of NOx

  4. Application of glucose as a green capping agent and reductant to fabricate CuI micro/nanostructures

    SciTech Connect (OSTI)

    Tavakoli, Farnosh; Salavati-Niasari, Masoud; Ghanbari, Davood; Saberyan, Kamal; Hosseinpour-Mashkani, S. Mostafa

    2014-01-01

    Graphical abstract: - Highlights: CuI nanostructures were prepared via a simple precipitation method. Glucose as a green capping agent and reductant was applied. The effect of glucose concentration on the morphology of CuI was investigated. According to XRD results, pure cubic phase CuI have been formed by using glucose. - Abstract: In this work, CuI micro/nanostructures have been successfully prepared via a simple precipitation route at room temperature. By using glucose as a clean reducing agent with different concentrations, CuI micro/nanostructures with various morphologies were obtained. Besides glucose, Na{sub 2}SO{sub 3}, KBH{sub 4} and N{sub 2}H{sub 4}H{sub 2}O have been applied as reductant. X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectroscopy, X-ray energy dispersive spectroscopy (EDS) and Fourier transformed infrared (FT-IR) spectroscopy were used to characterize the as-produced CuI micro/nanostructures. According to the XRD results, it was found that pure cubic phase CuI have been formed by using glucose.

  5. BTU LLC | Open Energy Information

    Open Energy Info (EERE)

    Small start-up with breakthrough technology seeking funding to prove commercial feasibility Coordinates: 45.425788, -122.765754 Show Map Loading map......

  6. Photocatalytic performances and activities of Ag-doped CuFe{sub 2}O{sub 4} nanoparticles

    SciTech Connect (OSTI)

    Zhu, Zhengru; Li, Xinyong; Zhao, Qidong; Li, Yonghua; Sun, Caizhi; Cao, Yongqiang

    2013-08-01

    Graphical abstract: - Highlights: CuFe{sub 2}O{sub 4} nanocrystals were synthesized by a co-precipitation method. Ag/CuFe{sub 2}O{sub 4} catalyst was prepared by the wetness impregnation strategy. The structural properties of Ag/CuFe{sub 2}O{sub 4} were investigated by XRD, TEM, DRS, and XPS techniques. Ag/CuFe{sub 2}O{sub 4} has higher photocatalytic activity. - Abstract: In this work, CuFe{sub 2}O{sub 4} nanoparticles were synthesized by a chemical co-precipitation route. The Ag/CuFe{sub 2}O{sub 4} catalyst was prepared based on the CuFe{sub 2}O{sub 4} nanoparticles by the incipient wetness impregnation strategy, which showed excellent photoelectric property and catalytic activity. The structural properties of these samples were systematically investigated by X-ray powder diffraction (XRD), transmission electronic microscopy (TEM), UVvis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR) techniques. The photo-induced charge separation in the samples was demonstrated by surface photovoltage (SPV) measurement. The photocatalytic degradation of 4-CP by the Ag/CuFe{sub 2}O{sub 4} and CuFe{sub 2}O{sub 4} samples were comparatively studied under xenon lamp irradiation. The results indicate that the Ag/CuFe{sub 2}O{sub 4} sample exhibited the higher efficiency for the degradation of 4-CP.

  7. Science DMZ Implemented at CU Boulder

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CU Science Engagement Move your data Programs & Workshops Science Requirements Reviews Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ @ UF Science DMZ @ CU...

  8. Table 1.1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2010; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and Shipments Net Residual Distillate Natural Gas(e) LPG and Coal Breeze of Energy Sources NAICS Total(b) Electricity(c) Fuel Oil Fuel Oil(d) (billion NGL(f) (million (million Other(g) Produced Onsite(h) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) cu ft) (million

  9. M4FT-15LL0806062-LLNL Thermodynamic and Sorption Data FY15 Progress Report

    SciTech Connect (OSTI)

    Zavarin, M.; Wolery, T. J.

    2015-08-31

    This progress report (Milestone Number M4FT-15LL0806062) summarizes research conducted at Lawrence Livermore National Laboratory (LLNL) within Work Package Number FT-15LL080606. The focus of this research is the thermodynamic modeling of Engineered Barrier System (EBS) materials and properties and development of thermodynamic databases and models to evaluate the stability of EBS materials and their interactions with fluids at various physicochemical conditions relevant to subsurface repository environments. The development and implementation of equilibrium thermodynamic models are intended to describe chemical and physical processes such as solubility, sorption, and diffusion.

  10. Opportunities for the Early Production of Fischer-Tropsch (F-T) Fuels in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the U.S. -- An Overview | Department of Energy for the Early Production of Fischer-Tropsch (F-T) Fuels in the U.S. -- An Overview Opportunities for the Early Production of Fischer-Tropsch (F-T) Fuels in the U.S. -- An Overview 2002 DEER Conference Presentation: U.S. Department of Energy PDF icon 2002_deer_shen.pdf More Documents & Publications Coal-Derived Liquids to Enable HCCI Technology WA_99_018_TEXACO_ENERGY_SYSTEMS_Waiver_of_Domestic_and_Forei.pdf Advanced Fuels in HDV Applications

  11. FT-IR Study of CO2 Interaction with Na-rich Montmorillonite (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect FT-IR Study of CO2 Interaction with Na-rich Montmorillonite Citation Details In-Document Search Title: FT-IR Study of CO2 Interaction with Na-rich Montmorillonite Carbon capture, utilization and storage (CCUS) in saline reservoirs in sedimentary formations has the potential to reduce the impact of fossil fuel combustion on climate change by reducing CO2 emissions to the atmosphere and storing the CO2 in geologic formations in perpetuity. At pressure and temperature

  12. SEMI-ANNUAL REPORTS FOR DOWNEAST LNG, INC. - FT DKT. NO. 14-172-LNG - ORDER

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NO. 3600 (FTA) | Department of Energy DOWNEAST LNG, INC. - FT DKT. NO. 14-172-LNG - ORDER NO. 3600 (FTA) SEMI-ANNUAL REPORTS FOR DOWNEAST LNG, INC. - FT DKT. NO. 14-172-LNG - ORDER NO. 3600 (FTA) No Reports Received More Documents & Publications SEMI-ANNUAL REPORTS FOR - STROM, INC. - FE DKT. NO. 14-56-LNG - ORDER NO 3537 SEMI-ANNUAL REPORTS FOR TEXAS LNG - TEXAS LNG - FTA - FE DKT. NO. 13-160-LNG - 3443 SEMI-ANNUAL REPORTS - TEXAS LNG BROWNSVILLE LLC - FE DKT. 15-62-LNG - Order 3716 FTA

  13. SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches Data for a number of regulated emissions and ethanol using the SESAM FT-IR compare favorably with standard emissions analyzers. PDF icon p-07_frazee.pdf More Documents & Publications 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods Urea SCR and DPF

  14. Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project

    SciTech Connect (OSTI)

    Stephen P. Bergin

    2006-06-30

    The objective of the DOE-NETL Fischer-Tropsch (F-T) Production and Demonstration Program was to produce and evaluate F-T fuel derived from domestic natural gas. The project had two primary phases: (1) fuel production of ultra-clean diesel transportation fuels from domestic fossil resources; and (2) demonstration and performance testing of these fuels in engines. The project also included a well-to-wheels economic analysis and a feasibility study of small-footprint F-T plants (SFPs) for remote locations such as rural Alaska. During the fuel production phase, ICRC partnered and cost-shared with Syntroleum Corporation to complete the mechanical design, construction, and operation of a modular SFP that converts natural gas, via F-T and hydro-processing reactions, into hydrogensaturated diesel fuel. Construction of the Tulsa, Oklahoma plant started in August 2002 and culminated in the production of over 100,000 gallons of F-T diesel fuel (S-2) through 2004, specifically for this project. That fuel formed the basis of extensive demonstrations and evaluations that followed. The ultra-clean F-T fuels produced had virtually no sulfur (less than 1 ppm) and were of the highest quality in terms of ignition quality, saturation content, backend volatility, etc. Lubricity concerns were investigated to verify that commercially available lubricity additive treatment would be adequate to protect fuel injection system components. In the fuel demonstration and testing phase, two separate bus fleets were utilized. The Washington DC Metropolitan Area Transit Authority (WMATA) and Denali National Park bus fleets were used because they represented nearly opposite ends of several spectra, including: climate, topography, engine load factor, mean distance between stops, and composition of normally used conventional diesel fuel. Fuel evaluations in addition to bus fleet demonstrations included: bus fleet emission measurements; F-T fuel cold weather performance; controlled engine dynamometer lab evaluation; cold-start test-cell evaluations; overall feasibility, economics, and efficiency of SFP fuel production; and an economic analysis. Two unexpected issues that arose during the project were further studied and resolved: variations in NOx emissions were accounted for and fuel-injection nozzle fouling issues were traced to the non-combustible (ash) content of the engine oil, not the F-T fuel. The F-T fuel domestically produced and evaluated in this effort appears to be a good replacement candidate for petroleum-based transportation fuels. However, in order for domestic F-T fuels to become a viable cost-comparable alternative to petroleum fuels, the F-T fuels will need to be produced from abundant U.S. domestic resources such as coal and biomass, rather than stranded natural gas.

  15. Microwave-assisted synthesis and photovoltaic measurements of CuInS{sub 2} nanoparticles prepared by using metalorganic precursors

    SciTech Connect (OSTI)

    Hosseinpour-Mashkani, S. Mostafa; Mohandes, Fatemeh; Salavati-Niasari, Masoud; Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P.O. Box 87317-51167, Islamic Republic of Iran ; Venkateswara-Rao, K.

    2012-11-15

    Highlights: ? CuInS{sub 2} nanoparticles were prepared using complexes via a microwave-assisted method. ? The effect of preparation parameters on the morphology of CuInS{sub 2} was investigated. ? The as-deposited CdS/CuInS{sub 2} films were used for the photovoltaic measurements. -- Abstract: In this work, CuInS{sub 2} (CIS) nanoparticles have been synthesized with the aid of (1,8-diamino-3,6-dioxaoctan)copper(II) sulfate ([Cu(DADO)]SO{sub 4}) and bis(propylenediamine)copper(II) sulfate ([Cu(pn){sub 2}]SO{sub 4}) complexes as copper precursor in the presence of microwave irradiation. Besides, L-cystine, InCl{sub 3}, and sodium dodecyl sulfate (SDS) were applied as sulfur source, indium precursor, and capping agent, respectively. To investigate the effect of preparation parameters like microwave power and irradiation time on the morphology and particle size of CuInS{sub 2}, the experiment was carried out at different conditions. The as-synthesized CuInS{sub 2} nanoparticles were characterized by XRD, FT-IR, PL, SEM, TEM, and EDS. The XRD results showed that pure tetragonal CuInS{sub 2} could be only obtained after annealing at 400 C for 2 h. The SEM images indicated that with decreasing the microwave power and irradiation time, particle size of CuInS{sub 2} nanoparticles decreased. To fabricate a solar cell, CdS film was directly deposited on top of the CIS film prepared by Doctor's blade method through chemical bath deposition. The as-deposited CdS/CuInS{sub 2} films were used for the photovoltaic measurements.

  16. Utility Assessment Report for SPIDERS Phase 2: Ft. Carson (Rev 1.0)

    SciTech Connect (OSTI)

    Barr, Jonathan L.; Tuffner, Francis K.; Hadley, Mark D.; Schneider, Kevin P.

    2014-01-01

    This document contains the Utility Assessment Report (UAR) for the Phase 2 operational Demonstration (OD) of the Smart Power Infrastructure Demonstration for Energy Reliability and Security (SPIDERS) Joint Capability Technology Demonstration (JCTD). The UAR for Phase 2 shows that the SPIDERS system was able to meet the requirements of the Implementation Directive at Ft. Carson.

  17. Property:NEPA CU Document | Open Energy Information

    Open Energy Info (EERE)

    CU Document Jump to: navigation, search Property Name NEPA CU Document Property Type Page Description CU files for NEPA Docs. Typically Casual Use Documentation consists of a...

  18. Shape selective catalysts for F-T chemistry. Interim report : January 2001 - December 2002.

    SciTech Connect (OSTI)

    Cronauer, D. C.

    2003-01-29

    Argonne National Laboratory (ANL) is carrying out a research program to create, prepare, and evaluate catalysts to promote Fischer-Tropsch (F-T) chemistry, specifically the reaction of hydrogen with carbon monoxide to form long-chain hydrocarbons. In addition to F-T catalysts needing high activity, it is desirable that they have high selectivity and stability with respect to both mechanical strength and aging properties. In this project, selectivity is directed toward the production of diesel fraction components and avoiding excess yields of both light hydrocarbons and heavy waxes. Shape-selective catalysts have the potential to both limit the formation of long-chain products and yet retain the active metal sites in a protected ''cage.'' This cage also restricts their loss by attrition during use in slurry-bed reactors. Experimentation has included evaluation of samples of (1) iron-based F-T catalysts prepared at Argonne National Laboratory, (2) iron-based F-T catalysts prepared by B.H. Davis of the Center of Applied Energy Research (CAER), (3) the Davis catalyst that were sized by differential gravity separation, and (4) the Davis catalyst onto which inorganic or catalytic ''shells'' were deposited. The ANL-prepared samples had a wide range of particle size and were irregular in shape. A sizeable portion of the samples provided by Davis were spherical, because they had been prepared by spray-drying. To compare the catalytic activities of the samples, we used a micro-scale fixed-bed reactor system for F-T runs of low conversion to avoid thermal and mass transfer effects. In summary, the highest activity was that of the original Davis catalyst; additional research must be carried out to generate more permeable surface cages. A number of approaches that have been published for other applications will be tested.

  19. "Table A49. Average Prices of Purchased Electricity, Steam, and Natural Gas"

    U.S. Energy Information Administration (EIA) Indexed Site

    9. Average Prices of Purchased Electricity, Steam, and Natural Gas" " by Type of Supplier, Census Region, and Economic Characteristics of the" " Establishment, 1991" " (Estimates in Dollars per Physical Units)" ," Electricity",," Steam",," Natural Gas" ," (Million kWh)",," (Billion Btu)",," (1000 cu ft)"

  20. Table 8.3a Useful Thermal Output at Combined-Heat-and-Power Plants: Total (All Sectors), 1989-2011 (Sum of Tables 8.3b and 8.3c; Billion Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    a Useful Thermal Output at Combined-Heat-and-Power Plants: Total (All Sectors), 1989-2011 (Sum of Tables 8.3b and 8.3c; Billion Btu) Year Fossil Fuels Renewable Energy Other 7 Total Coal 1 Petroleum 2 Natural Gas 3 Other Gases 4 Total Biomass Total Wood 5 Waste 6 1989 323,191 95,675 461,905 92,556 973,327 546,354 30,217 576,571 39,041 1,588,939 1990 362,524 127,183 538,063 140,695 1,168,465 650,572 36,433 687,005 40,149 1,895,619 1991 351,834 112,144 546,755 148,216 1,158,949 623,442 36,649

  1. Table 8.3c Useful Thermal Output at Combined-Heat-and-Power Plants: Commercial and Industrial Sectors, 1989-2011 (Subset of Table 8.3a; Billion Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    c Useful Thermal Output at Combined-Heat-and-Power Plants: Commercial and Industrial Sectors, 1989-2011 (Subset of Table 8.3a; Billion Btu) Year Fossil Fuels Renewable Energy Other 7 Total Coal 1 Petroleum 2 Natural Gas 3 Other Gases 4 Total Biomass Total Wood 5 Waste 6 Commercial Sector 8<//td> 1989 13,517 3,896 9,920 102 27,435 145 10,305 10,450 – 37,885 1990 14,670 5,406 15,515 118 35,709 387 10,193 10,580 – 46,289 1991 15,967 3,684 20,809 118 40,578 169 8,980 9,149 1 49,728 1992

  2. Variability of biomass chemical composition and rapid analysis using FT-NIR techniques

    SciTech Connect (OSTI)

    Liu, Lu [University of Tennessee, Knoxville (UTK); Ye, Philip [University of Tennessee, Knoxville (UTK); Womac, A.R. [University of Tennessee; Sokhansanj, Shahabaddine [ORNL

    2010-04-01

    A quick method for analyzing the chemical composition of renewable energy biomass feedstock was developed by using Fourier transform near-infrared (FT-NIR) spectroscopy coupled with multivariate analysis. The study presents the broad-based model hypothesis that a single FT-NIR predictive model can be developed to analyze multiple types of biomass feedstock. The two most important biomass feedstocks corn stover and switchgrass were evaluated for the variability in their concentrations of the following components: glucan, xylan, galactan, arabinan, mannan, lignin, and ash. A hypothesis test was developed based upon these two species. Both cross-validation and independent validation results showed that the broad-based model developed is promising for future chemical prediction of both biomass species; in addition, the results also showed the method's prediction potential for wheat straw.

  3. Application of Printed Circuit Board Technology to FT-ICR MS Analyzer Cell Construction and Prototyping

    SciTech Connect (OSTI)

    Leach, Franklin E.; Norheim, Randolph V.; Anderson, Gordon A.; Pasa-Tolic, Ljiljana

    2014-12-01

    Although Fourier transform ion cyclotron resonance mass spectrometry (FT-ICRMS) remains themass spectrometry platform that provides the highest levels of performance for mass accuracy and resolving power, there is room for improvement in analyzer cell design as the ideal quadrupolar trapping potential has yet to be generated for a broadband MS experiment. To this end, analyzer cell designs have improved since the field’s inception, yet few research groups participate in this area because of the high cost of instrumentation efforts. As a step towards reducing this barrier to participation and allowing for more designs to be physically tested, we introduce a method of FT-ICR analyzer cell prototyping utilizing printed circuit boards at modest vacuum conditions. This method allows for inexpensive devices to be readily fabricated and tested over short intervals and should open the field to laboratories lacking or unable to access high performance machine shop facilities because of the required financial investment.

  4. Practical Analysis of materials with depth varying compositions using FT-IR photoacoustic spectroscopy (PAS)

    SciTech Connect (OSTI)

    J.F. McClelland; R.W. Jones; Siquan Luo

    2004-09-30

    FT-IR photoacoustic spectroscopy (PAS) is discussed as a nondestructive method to probe the molecular composition of materials versus depth on the basis of the analysis of layers of experimentally controllable thickness, which are measured from the sample surface to depths of some tens of micrometers, depending on optical and thermal properties. Computational methods are described to process photoacoustic amplitude and phase spectra for both semi-quantitative and quantitative depth analyses. These methods are demonstrated on layered and gradient samples.

  5. Manufacturable CuIn(Ga)Se{sub 2}-based solar cells via development of co-sputtered CuInSe{sub 2} absorber layers

    SciTech Connect (OSTI)

    Dr. Ingrid Eisgruber

    1999-03-20

    Yield and reproducibility remain issues in CuIn(Ga)Se{sub 2} (CIGS) photovoltaic module fabrication. While small-area cells (<1 cm{sup 2}) over 18% efficient have been reported, the best large-area manufactured devices (>1 ft{sup 2}) are 11% efficient with about 60% yield. If improvements in large-area manufacturing can accomplish 15% efficiency and 90% yield, the result is a doubling in throughput leading to a reduction in cost per watt of over 50%. The challenge now facing the photovoltaics industry is to bring the efficiencies of small-area cells and large-area industrial modules closer together and to raise manufacturing yields.

  6. Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments;

    Gasoline and Diesel Fuel Update (EIA)

    Coke and Shipments Net Residual Distillate Natural LPG and Coal Breeze of Energy Sources NAICS Total(b) Electricity(c) Fuel Oil Fuel Oil(d) Gas(e) NGL(f) (million (million Other(g) Produced Onsite(h) Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) (billion cu ft) (million bbl) short tons) short tons) (trillion Btu) (trillion Btu) Total United States RSE Column Factors: 0.9 1 1.2 1.8 1 1.6 0.8 0.9 1.2 0.4 311 Food 1,123 67,521 2 3 567 1 8 * 89 0 311221 Wet

  7. table1.1_02

    U.S. Energy Information Administration (EIA) Indexed Site

    Coke and Shipments Net Residual Distillate Natural LPG and Coal Breeze of Energy Sources RSE NAICS Total(b) Electricity(c) Fuel Oil Fuel Oil(d) Gas(e) NGL(f) (million (million Other(g) Produced Onsite(h) Row Code(a) Subsector and Industry (trillion Btu) (million kWh) (million bbl) (million bbl) (billion cu ft) (million bbl) short tons) short tons) (trillion Btu) (trillion Btu) Factors Total United States RSE Column Factors: 0.9 1 1.2 1.8 1 1.6 0.8 0.9 1.2 0.4 311 Food 1,123 67,521 2 3 567 1 8 *

  8. DE-AT26-97FT34342 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterizing Arctic Hydrates (Canadian Test Well and Alaskan "Wells of Opportunity") photo of drilling rig at Mallik 2L-38 location Rig at Mallik 2L-38 location courtesy Geological Survey of Canada DE-AT26-97FT34342 Project Goal The purpose of this project is to assess the recoverability and potential production characteristics of the onshore natural gas hydrate and associated free-gas accumulations in the Arctic of North America Performer United States Geological Survey, Denver,

  9. DE-AT26-97FT34344 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Resolution Sidescan Sonar and Multibeam Bathymetric Data Collection and Processing, Atwater Canyon, Gulf of Mexico DE-AT26-97FT34344 photo of DTAGS seismic source being deployed DTAG seismic source being deployed. Courtesy Naval Research Laboratory Project Goal During February 14-18, 2005, a scientific cruise was conducted using the R/V Pelican to obtain high-resolution sidescan sonar and multibeam bathymetric data of Mounds D and F in the Atwater Valley area of the Gulf of Mexico, to

  10. ft. n. Both, Ohtef, RarourQb DWrion,Oak Ridgo

    Office of Legacy Management (LM)

    _ ,' .' ft. n. Both, Ohtef, RarourQb DWrion,Oak Ridgo hwt 2% w9 s. P. Morgan, Aar' t, Pimotor; Produotlon Dirirloa, i BY00 sniwm! OP Zr T~BIDm 1 . It ir axpeat tbt 4alivery of @air wteri8.l will be maa on orbaforo leptcmwrl, lg4g. Idantifioatioii my&ml "2416" haa been wr@md to thlr ahip nent and all related dauuuentr, aat ma&or Watlr Br n&R 1 ::_,, : ; .,. . . . ,~,-,.", :;> .

  11. I CLASSiFtCArlON CHANiED FAIJC-ABC-286

    Office of Legacy Management (LM)

    Y ~L.ho-I . I CLASSiFtCArlON CHANiED FAIJC-ABC-286 : This dooumetlt consists 0.f 3 pages E end p. t' &ures. No. a of &copies. a Seriee A. 7 Novembar 6, 1944 Subject: Visit to Fansteel Netallurgical Corporaticn, North Chicago, Novembar 4, 1944 - AwAlabilityof~lnmbium!kkl Chapin, Simmons end I discussed witb~. C. N. B&e (ResearchDirector) . end LIr. F.L.Hunter (Chief&ineer, TanteInmDivision) availability, purity, and @co of columbiwn,metel. columbium metal is of particular interest

  12. Phase transformation between Cu(In,Sn){sub 2} and Cu{sub 2}(In,Sn) compounds formed on single crystalline Cu substrate during solid state aging

    SciTech Connect (OSTI)

    Tian, Feifei; Liu, Zhi-Quan Guo, Jingdong

    2014-01-28

    Interfacial reactions between eutectic SnIn and single crystalline Cu during solid-state aging at low temperature were investigated systematically. Three types of phase transformations between Cu(In,Sn){sub 2} layer and Cu{sub 2}(In,Sn) layer were observed, which are Cu(In,Sn){sub 2} grows and Cu{sub 2}(In,Sn) consumes at 40?C, Cu(In,Sn){sub 2} and Cu{sub 2}(In,Sn) grow simultaneously at 60?C, as well as Cu(In,Sn){sub 2} consumes and Cu{sub 2}(In,Sn) grows at 80 and 100?C. According to physicochemical approach, the chemical reactions at Cu/Cu{sub 2}(In,Sn)/Cu(In,Sn){sub 2}/SnIn interfaces were discussed in detail. It was concluded that the diffusion ability of Cu and In atoms dominated different phase transformations. When diffusion constants k{sub 1In2}?>?8/3k{sub 1Cu2} Cu(In,Sn){sub 2} will grow, and if k{sub 1Cu2}???k{sub 1In2} Cu{sub 2}(In,Sn) will grow. Both Cu(In,Sn){sub 2} and Cu{sub 2}(In,Sn) can grow in the condition of k{sub 1In2} ? k{sub 1Cu2}. The values of k{sub 1Cu2} and k{sub 1In2} at different temperatures on (100)Cu and (111)Cu substrate were also calculated or estimated by analyzing the growth kinetics of the compound layers.

  13. Hydrodynamic evolution and jet energy loss in Cu + Cu collisions (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | DOE PAGES Hydrodynamic evolution and jet energy loss in Cu + Cu collisions « Prev Next » Title: Hydrodynamic evolution and jet energy loss in Cu + Cu collisions Authors: Schenke, Björn ; Jeon, Sangyong ; Gale, Charles Publication Date: 2011-04-18 OSTI Identifier: 1100252 Type: Publisher's Accepted Manuscript Journal Name: Physical review C. Nuclear physics Additional Journal Information: Journal Volume: 83; Journal Issue: 4; Journal ID: ISSN 0556-2813 Publisher: American

  14. Hydrodynamic evolution and jet energy loss in Cu + Cu collisions (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Hydrodynamic evolution and jet energy loss in Cu + Cu collisions Citation Details In-Document Search Title: Hydrodynamic evolution and jet energy loss in Cu + Cu collisions Authors: Schenke, Björn ; Jeon, Sangyong ; Gale, Charles Publication Date: 2011-04-18 OSTI Identifier: 1100252 Type: Publisher's Accepted Manuscript Journal Name: Physical review C. Nuclear physics Additional Journal Information: Journal Volume: 83; Journal Issue: 4; Journal ID: ISSN 0556-2813

  15. Cu

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    o u n d t o CCQ E (la r ge , r a t e o f Q E) 2 5 % o f t o t a l e ve n t r a t e Eve n t Se le ct io n 3 s u b e ve n t s - & + , - e - , + + e + 1...

  16. Performance and mix measurements of indirect drive Cu doped Be...

    Office of Scientific and Technical Information (OSTI)

    Performance and mix measurements of indirect drive Cu doped Be implosions Citation Details In-Document Search Title: Performance and mix measurements of indirect drive Cu doped Be...

  17. Origins of optical absorption characteristics of Cu2+ complexes...

    Office of Scientific and Technical Information (OSTI)

    Origins of optical absorption characteristics of Cu2+ complexes in solutions Citation Details In-Document Search Title: Origins of optical absorption characteristics of Cu2+ ...

  18. Rolling Thunder -- Integration of the Solo 161 Stirling engine with the CPG-460 solar concentrator at Ft. Huachuca

    SciTech Connect (OSTI)

    Diver, R.B.; Moss, T.A.; Goldberg, V.; Thomas, G.; Beaudet, A.

    1998-09-01

    Project Rolling Thunder is a dish/Stirling demonstration project at Ft. Huachuca, a US Army fort in southeastern Arizona (Huachuca means rolling thunder in Apache). It has been supported by the Strategic Environmental Research and Development Program (SERDP), a cooperative program between the Department of Defense (DoD) and the Department of Energy (DOE). As part of a 1992 SERDP project, Cummins Power Generation, Inc. (CPG) installed a CPG 7 kW(c) dish/Stirling system at the Joint Interoperability Test Command (JITC) in Ft. Huachuca, Arizona. The primary objective of the SERDP Dish/Stirling for DoD Applications project was to demonstrate a CPG 7-kW(c) dish/Stirling system at a military facility. Unfortunately, Cummins Engine Company decided to divest its solar operations. As a direct result of Ft. Huachuca`s interest in the Cummins dish/Stirling technology, Sandia explored the possibility of installing a SOLO 161 Stirling power conversion unit (PCU) on the Ft. Huachuca CPG-460. In January 1997, a decision was made to retrofit a SOLO 161 Stirling engine on the CPG-460 at Ft. Huachuca. Project Rolling Thunder. The SOLO 161 Demonstration at Ft. Huachuca has been a challenge. Although, the SOLO 161 PCU has operated nearly flawlessly and the CPG-460 has been, for the most part, a solid and reliable component, integration of the SOLO PCU with the CPG-460 has required significant attention. In this paper, the integration issues and technical approaches of project Rolling Thunder are presented. Lessons of the project are also discussed.

  19. FT-IR microscopical analysis with synchrotron radiation: The microscope optics and system performance

    SciTech Connect (OSTI)

    Reffner, J.A.; Martoglio, P.A.; Williams, G.P.

    1995-01-01

    When a Fourier transform infrared (FT-IR) microspectrometer was first interfaced with the National Synchrotron Light Source (NSLS) in September 1993, there was an instant realization that the performance at the diffraction limit had increased 40-100 times. The synchrotron source transformed the IR microspectrometer into a true IR microprobe, providing high-quality IR spectra for probe diameters at the diffraction limit. The combination of IR microspectroscopy and synchrotron radiation provides a powerful new tool for molecular spectroscopy. The ability to perform IR microspectroscopy with synchrotron radiation is still under development at Brookhaven National Laboratory, but several initial studies have been completed that demonstrate the broad-ranging applications of this technology and its potential for materials characterization.

  20. ?CDM model in f(T) gravity: reconstruction, thermodynamics and stability

    SciTech Connect (OSTI)

    Salako, I.G.; Kpadonou, A.V.; Houndjo, M.J.S.; Tossa, J.; Rodrigues, M.E. E-mail: esialg@gmail.com E-mail: sthoundjo@yahoo.fr

    2013-11-01

    We investigate some cosmological features of the ?CDM model in the framework of the generalized teleparallel theory of gravity f(T) where T denotes the torsion scalar. Its reconstruction is performed giving rise to an integration constant Q and other input parameters according to which we point out more analysis. Thereby, we show that for some values of this constant, the first and second laws of thermodynamics can be realized in the equilibrium description, for the universe with the temperature inside the horizon equal to that at the apparent horizon. Moreover, still within these suitable values of the constant, we show that the model may be stable using the de Sitter and Power-Law cosmological solutions.

  1. In-situ FT-IR diagnostics for monitoring and control of fossil fuel combustion

    SciTech Connect (OSTI)

    Bonanno, A.S.; Wojtowicz, M.A.; Serio, M.A.; Nelson, C.M.; Solomon, P.R.

    1995-12-31

    This paper describes the development and testing of a prototype fourier transform infrared (FT-IR) based measurement system for continuous emission monitoring (CEM) and process control in fossil fuel-fired power plants. On several occasions, prototype systems have been transported and assembled at full-scale and pilot-scale fossil fuel-fired combustors. The in-situ version of the prototype is able to measure NH{sub 3} and HCl concentrations, which are difficult to measure extractively, as well as CO, CO{sub 2}, NO{sub x}, H{sub 2}O, and SO{sub x} concentrations. The results of recent tests will be presented which involve in-situ monitoring of selective non-catalytic reduction (SNCR) of NO{sub x} based on simultaneous measurement of NO, NH{sub 3} and CO.

  2. Coiled tubing velocity string set at record 20,500 ft

    SciTech Connect (OSTI)

    Adams, L.S. )

    1992-04-13

    This paper reports that coiled tubing, set at record depth, significantly reduced costs and posed lower mechanical failure risk for recompleting a gas well in the Delaware basin of West Texas. Alternative completions such as replacing the existing tubing string with smaller diameter conventional API production tubing was deemed less economical and effective. The gas well, George M. Shelton No. 2, was recompleted on July 18, 1991, by Chevron U.S.A. Production Co. The gas is produced from the deep, low-pressure Ellenburger formation in the Gomez field. The hang-off depth of 20,500 ft set a world record for the deepest permanently installed coiled tubing. The 1-1/2 in. coiled tubing velocity string, run within the existing 4-1/2 and 4-in. tapered production tubing string, consists of seven segments that vary in wall thickness from 0.087 to 0.156 in.

  3. Sandia Wake Imaging System Field Test Report: 2015 Deployment at the Scaled Wind Farm Technology (SWiFT) Facility.

    SciTech Connect (OSTI)

    Naughton, Brian Thomas; Herges, Thomas

    2015-10-01

    This report presents the objectives, configuration, procedures, reporting , roles , and responsibilities and subsequent results for the field demonstration of the Sandia Wake Imaging System (SWIS) at the Sandia Scaled Wind Farm Technology (SWiFT) facility near Lubbock, Texas in June and July 2015.

  4. Technology development for cobalt F-T catalysts. Quarterly technical progress report, October 1, 1995--December 31, 1995. No. 13

    SciTech Connect (OSTI)

    Singleton, A.H.

    1996-09-05

    The goal of this project is the development of a commercially viable, cobalt-based Fischer-Tropsch (F-T) catalyst for use in a slurry bubble column reactor. Cobalt-based catalysts have long been known as being active for F-T synthesis. They typically possess greater activity than iron-based catalysts, historically the predominant catalyst being used commercially for the conversion of syngas based on coal, but possess two disadvantages that somewhat lessen its value: (1) cobalt tends to make more methane than iron does, and (2) cobalt is less versatile with low H{sub 2}/CO ratio syngas due to its lack of water-gas shift activity. Therefore, the major objectives of this work are (1) to develop a cobalt-based F-T catalyst with low (< 5 %) methane selectivity, (2) to develop a cobalt-based F-T catalyst with water-gas shift activity, and (3) to combine both these improvements into one catalyst. It will be demonstrated that these catalysts have the desired activity, selectivity, and life, and can be made reproducibly. Following this experimental work, a design and a cost estimate will be prepared for a plant to produce sufficient quantities of catalyst for scale-up studies.

  5. Cu-Cu direct bonding achieved by surface method at room temperature

    SciTech Connect (OSTI)

    Utsumi, Jun [Advanced Technology Research Center, Mitsubishi Heavy Industries, Ltd., 1-8-1 Sachiura, Kanazawa-ku, Yokohama 236-8515 (Japan); Ichiyanagi, Yuko, E-mail: yuko@ynu.ac.jp [Department of Physics, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya, Yokohama 240-8501 (Japan)

    2014-02-20

    The metal bonding is a key technology in the processes for the microelectromechanical systems (MEMS) devices and the semiconductor devices to improve functionality and higher density integration. Strong adhesion between surfaces at the atomic level is crucial; however, it is difficult to achieve close bonding in such a system. Cu films were deposited on Si substrates by vacuum deposition, and then, two Cu films were bonded directly by means of surface activated bonding (SAB) at room temperature. The two Cu films, with the surface roughness Ra about 1.3nm, were bonded by using SAB at room temperature, however, the bonding strength was very weak in this method. In order to improve the bonding strength between the Cu films, samples were annealed at low temperatures, between 323 and 473 K, in air. As the result, the Cu-Cu bonding strength was 10 times higher than that of the original samples without annealing.

  6. Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, X.; Kattel, S.; Xiong, K.; Mudiyanselage, K.; Rykov, S.; Senanayake, S. D.; Rodriguez, J. A.; Liu, P.; Stacchiola, D. J.; Chen, J. G.

    2015-07-17

    Direct propylene epoxidation by O2 is a challenging reaction because of the strong tendency for complete combustion. Results from the current study demonstrate the feasibility to tune the epoxidation selectivity by generating highly dispersed and stabilized Cu+ active sites in a TiCuOx mixed oxide. The TiCuOx surface anchors the key surface intermediate, oxametallacycle, leading to higher selectivity for epoxidation of propylene.

  7. Theoretical study on the CuH + H. -->. Cu + H/sub 2/ reaction pathway

    SciTech Connect (OSTI)

    Ruiz, M.E.; Garcia-Prieto, J.; Poulain, E.; Ozin, G.A.; Poirier, R.A.; Matta, S.M.; Czismadia, I.G.; Gracie, C.; Novaro, O.

    1986-01-16

    Quite recently, experimental results on the CuH + H ..-->.. Cu + H/sub 2/ thermal matrix phase reaction were reported, indicating that it proceeds with no activation barrier, and no evidence exists for an intermediate CuH/sub 2/ species at 10-13 K. Here the authors present a theoretical study of this reaction using variational and perturbational configuration interaction calculations with a relativistic pseudopotential (PSHONDO-CIPSI) set of programs. The results confirm the lack of a barrier and provide an explanation as to why the CuH/sub 2/ species may not be observed. 11 references, 3 figures, 3 tables.

  8. Analysis of Debris Trajectories at the Scaled Wind Farm Technology (SWiFT) Facility

    SciTech Connect (OSTI)

    White, Jonathan R.; Burnett, Damon J.

    2016-01-01

    Sandia National Laboratories operates the Scaled Wind Farm Technology Facility (SWiFT) on behalf of the Department of Energy Wind and Water Power Technologies Office. An analysis was performed to evaluate the hazards associated with debris thrown from one of SWiFT’s operating wind turbines, assuming a catastrophic failure. A Monte Carlo analysis was conducted to assess the complex variable space associated with debris throw hazards that included wind speed, wind direction, azimuth and pitch angles of the blade, and percentage of the blade that was separated. In addition, a set of high fidelity explicit dynamic finite element simulations were performed to determine the threshold impact energy envelope for the turbine control building located on-site. Assuming that all of the layered, independent, passive and active engineered safety systems and administrative procedures failed (a 100% failure rate of the safety systems), the likelihood of the control building being struck was calculated to be less than 5/10,000 and ballistic simulations showed that the control building would not provide passive protection for the majority of impact scenarios. Although options exist to improve the ballistic resistance of the control building, the recommendation is not to pursue them because there is a low probability of strike and there is an equal likelihood personnel could be located at similar distances in other areas of the SWiFT facility which are not passively protected, while the turbines are operating. A fenced exclusion area has been created around the turbines which restricts access to the boundary of the 1/100 strike probability. The overall recommendation is to neither relocate nor improve passive protection of the control building as the turbine safety systems have been improved to have no less than two independent, redundant, high quality engineered safety systems. Considering this, in combination with a control building strike probability of less than 5/10,000, the overall probability of turbine debris striking the control building is less than 1/1,000,000.

  9. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 Alaska - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S2. Summary statistics for natural gas - Alaska, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 269 277 185 R 159 170 Production (million cubic feet) Gross Withdrawals From Gas Wells 127,417 112,268

  10. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 Connecticut - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S7. Summary statistics for natural gas - Connecticut, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil

  11. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 District of Columbia - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S9. Summary statistics for natural gas - District of Columbia, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells

  12. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 Indiana - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S16. Summary statistics for natural gas - Indiana, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 620 914 819 R 921 895 Production (million cubic feet) Gross Withdrawals From Gas Wells 6,802 9,075

  13. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 Maryland - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S22. Summary statistics for natural gas - Maryland, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 7 8 9 7 7 Production (million cubic feet) Gross Withdrawals From Gas Wells 43 34 44 32 20 From Oil

  14. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    4 Massachusetts - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S23. Summary statistics for natural gas - Massachusetts, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0

  15. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 Minnesota - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S25. Summary statistics for natural gas - Minnesota, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil

  16. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 Nebraska - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S29. Summary statistics for natural gas - Nebraska, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 276 322 270 R 357 310 Production (million cubic feet) Gross Withdrawals From Gas Wells 2,092 1,854

  17. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 New Hampshire - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S31. Summary statistics for natural gas - New Hampshire, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0

  18. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 North Carolina - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S35. Summary statistics for natural gas - North Carolina, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0

  19. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    50 North Dakota - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S36. Summary statistics for natural gas - North Dakota, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 188 239 211 200 200 Production (million cubic feet) Gross Withdrawals From Gas Wells

  20. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 South Carolina - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S42. Summary statistics for natural gas - South Carolina, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0

  1. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 Washington - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S49. Summary statistics for natural gas - Washington, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil

  2. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    80 Wisconsin - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S51. Summary statistics for natural gas - Wisconsin, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil

  3. Catalytic reactor for low-Btu fuels

    DOE Patents [OSTI]

    Smith, Lance (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Karim, Hasan (Simpsonville, SC); Pfefferle, William C. (Madison, CT)

    2009-04-21

    An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area. Lastly, at least a portion of the first flow path defines a catalytically active surface.

  4. Distributed computing strategies for processing of FT-ICR MS imaging datasets for continuous mode data visualization

    SciTech Connect (OSTI)

    Smith, Donald F.; Schulz, Carl; Konijnenburg, Marco; Kilic, Mehmet; Heeren, Ronald M.

    2015-03-01

    High-resolution Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry imaging enables the spatial mapping and identification of biomolecules from complex surfaces. The need for long time-domain transients, and thus large raw file sizes, results in a large amount of raw data (big data) that must be processed efficiently and rapidly. This can be compounded by largearea imaging and/or high spatial resolution imaging. For FT-ICR, data processing and data reduction must not compromise the high mass resolution afforded by the mass spectrometer. The continuous mode Mosaic Datacube approach allows high mass resolution visualization (0.001 Da) of mass spectrometry imaging data, but requires additional processing as compared to featurebased processing. We describe the use of distributed computing for processing of FT-ICR MS imaging datasets with generation of continuous mode Mosaic Datacubes for high mass resolution visualization. An eight-fold improvement in processing time is demonstrated using a Dutch nationally available cloud service.

  5. Technology development for cobalt F-T catalysts. Quarterly technical progress report No. 12, July 1, 1995--September 30, 1995

    SciTech Connect (OSTI)

    Singleton, A.H.

    1996-03-21

    The investigation of the effect of certain promoters (Fe, Pd, and Ru) on the deactivation characteristics of Co catalysts during F-T synthesis was continued during this reporting period. All catalysts were tested first at 220{degrees}C, then at higher temperatures from 240 to 280{degrees}C, while monitoring their deactivation. The choice of these promoters was based on their intrinsic ability to enhance the hydrogenation reactions while slowing down the Boudouard reaction under the conditions used in F-T synthesis. Olefin hydrogenation and CO dissociation reactions were used individually to investigate further the nature of the deactivation process of these catalyst during F-T synthesis. Hydrogenation of isobutene (IB) was carried out in the presence of CO between 120 and 180{degrees}C and atmospheric pressure. CO dissociation activities of the catalysts were measured using a pulse technique at 2.5 atm and at temperatures between 180 and 280{degrees}C with intermittent H{sub 2} bracketing at 350{degrees}C. Promotion with high loadings of Fe or Pd resulted in catalysts with relatively lower activity and higher methane selectivity. The deactivation process and rate for catalysts containing Pd or Fe were similar to those of the non-promoted or Ru-promoted alumina-supported Co catalysts tested previously. The only exception was Co.068 with 1% Pd which had adequate activity and selectivity as well as lower deactivation rate at the various temperatures tested.

  6. Science DMZ Implemented at CU Boulder

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CU Science Engagement Move your data Programs & Workshops Science Requirements Reviews Case Studies OSCARS Case Studies Science DMZ Case Studies Science DMZ @ UF Science DMZ @ CU Science DMZ @ Penn & VTTI Science DMZ @ NOAA Science DMZ @ NERSC Science DMZ @ ALS Multi-facility Workflow Case Study Contact Us Technical Assistance: 1 800-33-ESnet (Inside US) 1 800-333-7638 (Inside US) 1 510-486-7600 (Globally) 1 510-486-7607 (Globally) Report Network Problems: trouble@es.net Provide Web Site

  7. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 Alabama - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S1. Summary statistics for natural gas - Alabama, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 7,026 7,063 6,327 R 6,165 6,118 Production (million cubic feet) Gross Withdrawals From Gas Wells

  8. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 Arkansas - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S4. Summary statistics for natural gas - Arkansas, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 7,397 8,388 8,538 R 9,843 10,150 Production (million cubic feet) Gross Withdrawals From Gas Wells

  9. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 California - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S5. Summary statistics for natural gas - California, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 1,580 1,308 1,423 R 1,335 1,118 Production (million cubic feet) Gross Withdrawals From Gas

  10. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 Colorado - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S6. Summary statistics for natural gas - Colorado, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 28,813 30,101 32,000 R 32,468 38,346 Production (million cubic feet) Gross Withdrawals From Gas

  11. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 Florida - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S10. Summary statistics for natural gas - Florida, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 17,182 16,459 19,742

  12. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 Georgia - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S11. Summary statistics for natural gas - Georgia, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil Wells

  13. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 Illinois - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S15. Summary statistics for natural gas - Illinois, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 50 40 40 R 34 36 Production (million cubic feet) Gross Withdrawals From Gas Wells E 1,697 2,114

  14. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 Iowa - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S17. Summary statistics for natural gas - Iowa, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil Wells 0 0 0

  15. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    4 Kansas - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S18. Summary statistics for natural gas - Kansas, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 22,145 25,758 24,697 R 23,792 24,354 Production (million cubic feet) Gross Withdrawals From Gas Wells

  16. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 Kentucky - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S19. Summary statistics for natural gas - Kentucky, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 17,670 14,632 17,936 R 19,494 19,256 Production (million cubic feet) Gross Withdrawals From Gas

  17. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 Louisiana - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S20. Summary statistics for natural gas - Louisiana, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 19,137 21,235 19,792 R 19,528 19,251 Production (million cubic feet) Gross Withdrawals From Gas

  18. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 Maine - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S21. Summary statistics for natural gas - Maine, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil Wells 0 0

  19. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 Michigan - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S24. Summary statistics for natural gas - Michigan, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 10,100 11,100 10,900 R 10,550 10,500 Production (million cubic feet) Gross Withdrawals From Gas

  20. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 Mississippi - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S26. Summary statistics for natural gas - Mississippi, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 1,979 5,732 1,669 R 1,967 1,645 Production (million cubic feet) Gross Withdrawals From Gas

  1. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 Missouri - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S27. Summary statistics for natural gas - Missouri, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 53 100 R 26 28 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 R 8 8 From

  2. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    4 Montana - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S28. Summary statistics for natural gas - Montana, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 6,059 6,477 6,240 5,754 5,754 Production (million cubic feet) Gross Withdrawals From Gas Wells

  3. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 Nevada - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S30. Summary statistics for natural gas - Nevada, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 R 4 4 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 3 From Oil Wells

  4. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 New Jersey - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S32. Summary statistics for natural gas - New Jersey, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil

  5. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    4 New Mexico - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S33. Summary statistics for natural gas - New Mexico, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 44,748 32,302 28,206 R 27,073 27,957 Production (million cubic feet) Gross Withdrawals From

  6. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 New York - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S34. Summary statistics for natural gas - New York, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 6,736 6,157 7,176 R 6,902 7,119 Production (million cubic feet) Gross Withdrawals From Gas Wells

  7. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 Ohio - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S37. Summary statistics for natural gas - Ohio, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 34,931 46,717 35,104 R 32,664 32,967 Production (million cubic feet) Gross Withdrawals From Gas Wells

  8. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    4 Oklahoma - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S38. Summary statistics for natural gas - Oklahoma, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 44,000 41,238 40,000 39,776 40,070 Production (million cubic feet) Gross Withdrawals From Gas

  9. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 Oregon - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S39. Summary statistics for natural gas - Oregon, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 26 24 27 R 26 28 Production (million cubic feet) Gross Withdrawals From Gas Wells 1,407 1,344 770 770

  10. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 Pennsylvania - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S40. Summary statistics for natural gas - Pennsylvania, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 44,500 54,347 55,136 R 53,762 70,400 Production (million cubic feet) Gross Withdrawals

  11. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 Rhode Island - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S41. Summary statistics for natural gas - Rhode Island, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From

  12. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    6 Tennessee - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S44. Summary statistics for natural gas - Tennessee, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 230 210 212 R 1,089 1,024 Production (million cubic feet) Gross Withdrawals From Gas Wells 5,144

  13. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 Texas - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S45. Summary statistics for natural gas - Texas, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 95,014 100,966 96,617 97,618 98,279 Production (million cubic feet) Gross Withdrawals From Gas Wells

  14. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    0 Utah - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S46. Summary statistics for natural gas - Utah, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 6,075 6,469 6,900 R 7,030 7,275 Production (million cubic feet) Gross Withdrawals From Gas Wells 328,135

  15. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    2 Vermont - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S47. Summary statistics for natural gas - Vermont, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 0 0 0 0 0 Production (million cubic feet) Gross Withdrawals From Gas Wells 0 0 0 0 0 From Oil Wells

  16. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    4 Virginia - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S48. Summary statistics for natural gas - Virginia, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 7,470 7,903 7,843 R 7,956 7,961 Production (million cubic feet) Gross Withdrawals From Gas Wells

  17. Million Cu. Feet Percent of National Total

    Gasoline and Diesel Fuel Update (EIA)

    8 West Virginia - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S50. Summary statistics for natural gas - West Virginia, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 52,498 56,813 50,700 R 54,920 60,000 Production (million cubic feet) Gross Withdrawals

  18. OPERATIONS AND PERFORMANCE OF RHIC AS A CU-CU COLLIDER.

    SciTech Connect (OSTI)

    PILAT, R.; AHRENS, L.; BAI, M.; BARTON, D.S.; ET AL.

    2005-05-16

    The 5th year of RHIC operations, started in November 2004 and expected to last till June 2005, consists of a physics run with Cu-Cu collisions at 100 GeV/u followed by one with polarized protons (pp) at 100 GeV [l]. We will address here the overall performance of the RHIC complex used for the first time as a Cu-Cu collider, and compare it with previous operational experience with Au, PP and asymmetric d-Au collisions. We will also discuss operational improvements, such as a {beta}* squeeze to 85cm in the high luminosity interaction regions from the design value of 1m, system improvements, machine performance and limitations, and address reliability and uptime issues.

  19. Level: National Data; Row: End Uses within NAICS Codes; Column: Energy Sources, including Net Demand for Electricity;

    Gasoline and Diesel Fuel Update (EIA)

    Next MECS will be conducted in 2010 Table 5.3 End Uses of Fuel Consumption, 2006; Level: National Data; Row: End Uses within NAICS Codes; Column: Energy Sources, including Net Demand for Electricity; Unit: Physical Units or Btu. Distillate Coal Fuel Oil (excluding Coal Net Demand Residual and Natural Gas(d) LPG and Coke and Breeze) NAICS for Electricity(b) Fuel Oil Diesel Fuel(c) (billion NGL(e) (million Code(a) End Use (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons)

  20. Level: National and Regional Data; Row: End Uses; Column: Energy Sources, including Net Demand for Electricity;

    Gasoline and Diesel Fuel Update (EIA)

    7 End Uses of Fuel Consumption, 2006; Level: National and Regional Data; Row: End Uses; Column: Energy Sources, including Net Demand for Electricity; Unit: Physical Units or Btu. Distillate Coal Fuel Oil (excluding Coal Net Demand Residual and Natural Gas(c) LPG and Coke and Breeze) for Electricity(a) Fuel Oil Diesel Fuel(b) (billion NGL(d) (million End Use (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) Total United States TOTAL FUEL CONSUMPTION 977,338 40 22 5,357 21

  1. Table 5.3 End Uses of Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    3 End Uses of Fuel Consumption, 2010; Level: National Data; Row: End Uses within NAICS Codes; Column: Energy Sources, including Net Demand for Electricity; Unit: Physical Units or Btu. Distillate Coal Fuel Oil (excluding Coal Net Demand Residual and Natural Gas(d) LPG and Coke and Breeze) NAICS for Electricity(b) Fuel Oil Diesel Fuel(c) (billion NGL(e) (million Code(a) End Use (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) Total United States 311 - 339 ALL

  2. Table 5.7 End Uses of Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    7 End Uses of Fuel Consumption, 2010; Level: National and Regional Data; Row: End Uses; Column: Energy Sources, including Net Demand for Electricity; Unit: Physical Units or Btu. Distillate Coal Fuel Oil (excluding Coal Net Demand Residual and Natural Gas(c) LPG and Coke and Breeze) for Electricity(a) Fuel Oil Diesel Fuel(b) (billion NGL(d) (million End Use (million kWh) (million bbl) (million bbl) cu ft) (million bbl) short tons) Total United States TOTAL FUEL CONSUMPTION 845,727 13 22 5,064 18

  3. Table 7.1 Average Prices of Purchased Energy Sources, 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    Average Prices of Purchased Energy Sources, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: All Energy Sources Collected; Unit: U.S. Dollars per Physical Units. Coal NAICS TOTAL Acetylene Breeze Total Anthracite Code(a) Subsector and Industry (million Btu) (cu ft) (short tons) (short tons) (short tons) Total United States 311 Food 9.12 0.26 0.00 53.43 90.85 3112 Grain and Oilseed Milling 6.30 0.29 0.00 51.34 50.47 311221 Wet Corn Milling 4.87 0.48 0.00 47.74 50.47 31131 Sugar

  4. table5.3_02

    U.S. Energy Information Administration (EIA) Indexed Site

    3 End Uses of Fuel Consumption, 2002; Level: National Data; Row: End Uses within NAICS Codes; Column: Energy Sources, including Net Demand for Electricity; Unit: Physical Units or Btu. Distillate Net Demand Fuel Oil Coal for Residual and Natural LPG and (excluding Coal RSE NAICS Electricity(b) Fuel Oil Diesel Fuel(c) Gas(d) NGL(e) Coke and Breeze) Row Code(a) End Use (million kWh) (million bbl) (million bbl) (billion cu ft) (million bbl) (million short tons) Factors Total United States 311 - 339

  5. table5.7_02.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    End Uses of Fuel Consumption, 2002; Level: National and Regional Data; Row: End Uses; Column: Energy Sources, including Net Demand for Electricity; Unit: Physical Units or Btu. Distillate Net Demand Fuel Oil Coal for Residual and Natural LPG and (excluding Coal RSE Electricity(a) Fuel Oil Diesel Fuel(b) Gas(c) NGL(d) Coke and Breeze) Row End Use (million kWh) (million bbl) (million bbl) (billion cu ft) (million bbl) (million short tons) Factors Total United States RSE Column Factors: 0.3 2.4

  6. table7.1_02.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Average Prices of Purchased Energy Sources, 2002; Level: National and Regional Data; Row: NAICS Codes; Column: All Energy Sources Collected; Unit: U.S. Dollars per Physical Units. Bituminous and Coal Subbituminous Coal Petroleum NAICS TOTAL Acetylene Breeze Total Anthracite Coal Lignite Coke Coke Code(a) Subsector and Industry (million Btu) (cu ft) (short tons) (short tons) (short tons) (short tons) (short tons) (short tons) (gallons) Total United States RSE Column Factors: 1.1 2.1 0.6 1 0.6

  7. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 0 Average Electricity Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total 81.6 65.3 142.5 38 17 30.3 11 625 0.29 500 178 Census Region and Division

  8. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 1 Average Electricity Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total 83.1 66.1 144.2 37 17 29.1 10 678 0.31 539 192 Census Region and Division

  9. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 2 Average Electricity Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total 83.7 66.0 142.2 36 16 28.0 10 708 0.33 558 204 Census Region and Division

  10. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 4 Average Electricity Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total 86.3 67.4 144.3 37 17 28.8 11 808 0.38 632 234 Census Region and Division

  11. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 7 Average Electricity Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total 90.5 70.4 156.8 39 18 30.5 12 875 0.39 680 262 Census Region and Division

  12. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 97 Average Electricity Residential Buildings Consumption Expenditures Total per Floor- per Square per per per Total Total space (1) Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total 101.4 83.2 168.8 42 21 35.0 13 1,061 0.52 871 337 Census Region and

  13. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 2001 Average Electricity Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total 107.0 85.2 211.2 46 18 36.0 14 1,178 0.48 938 366 Census Region and Division

  14. Bi-Se doped with Cu, p-type semiconductor

    DOE Patents [OSTI]

    Bhattacharya, Raghu Nath; Phok, Sovannary; Parilla, Philip Anthony

    2013-08-20

    A Bi--Se doped with Cu, p-type semiconductor, preferably used as an absorber material in a photovoltaic device. Preferably the semiconductor has at least 20 molar percent Cu. In a preferred embodiment, the semiconductor comprises at least 28 molar percent of Cu. In one embodiment, the semiconductor comprises a molar percentage of Cu and Bi whereby the molar percentage of Cu divided by the molar percentage of Bi is greater than 1.2. In a preferred embodiment, the semiconductor is manufactured as a thin film having a thickness less than 600 nm.

  15. Viability of the matter bounce scenario in F(T) gravity and Loop Quantum Cosmology for general potentials

    SciTech Connect (OSTI)

    Haro, Jaume; Amors, Jaume E-mail: jaume.amoros@upc.edu

    2014-12-01

    We consider the matter bounce scenario in F(T) gravity and Loop Quantum Cosmology (LQC) for phenomenological potentials that at early times provide a nearly matter dominated Universe in the contracting phase, having a reheating mechanism in the expanding or contracting phase, i.e., being able to release the energy of the scalar field creating particles that thermalize in order to match with the hot Friedmann Universe, and finally at late times leading to the current cosmic acceleration. For these potentials, numerically solving the dynamical perturbation equations we have seen that, for the particular F(T) model that we will name teleparallel version of LQC, and whose modified Friedmann equation coincides with the corresponding one in holonomy corrected LQC when one deals with the flat Friedmann-Lematre-Robertson-Walker (FLRW) geometry, the corresponding equations obtained from the well-know perturbed equations in F(T) gravity lead to theoretical results that fit well with current observational data. More precisely, in this teleparallel version of LQC there is a set of solutions which leads to theoretical results that match correctly with last BICEP2 data, and there is another set whose theoretical results fit well with Planck's experimental data. On the other hand, in the standard holonomy corrected LQC, using the perturbed equations obtained replacing the Ashtekar connection by a suitable sinus function and inserting some counter-terms in order to preserve the algebra of constrains, the theoretical value of the tensor/scalar ratio is smaller than in the teleparallel version, which means that there is always a set of solutions that matches with Planck's data, but for some potentials BICEP2 experimental results disfavours holonomy corrected LQC.

  16. Method of producing .sup.67 Cu

    DOE Patents [OSTI]

    O'Brien, Jr., Harold A. (Los Alamos, NM); Barnes, John W. (Los Alamos, NM); Taylor, Wayne A. (Los Alamos, NM); Thomas, Kenneth E. (Los Alamos, NM); Bentley, Glenn E. (Los Alamos, NM)

    1984-01-01

    A method of producing carrier-free .sup.67 Cu by proton spallation combined with subsequent chemical separation and purification is disclosed. A target consisting essentially of pressed zinc oxide is irradiated with a high energy, high current proton beam to produce a variety of spallogenic nuclides, including .sup.67 Cu and other copper isotopes. The irradiated target is dissolved in a concentrated acid solution to which a palladium salt is added. In accordance with the preferred method, the spallogenic copper is twice coprecipitated with palladium, once with metallic zinc as the precipitating agent and once with hydrogen sulfide as the precipitating agent. The palladium/copper precipitate is then dissolved in an acid solution and the copper is separated from the palladium by liquid chromatography on an anion exchange resin.

  17. Accelerated Aging of BKC 44306-10 Rigid Polyurethane Foam: FT-IR Spectroscopy, Dimensional Analysis, and Micro Computed Tomography

    SciTech Connect (OSTI)

    Gilbertson, Robert D.; Patterson, Brian M.; Smith, Zachary

    2014-01-02

    An accelerated aging study of BKC 44306-10 rigid polyurethane foam was carried out. Foam samples were aged in a nitrogen atmosphere at three different temperatures: 50 C, 65 C, and 80 C. Foam samples were periodically removed from the aging canisters at 1, 3, 6, 9, 12, and 15 month intervals when FT-IR spectroscopy, dimensional analysis, and mechanical testing experiments were performed. Micro Computed Tomography imaging was also employed to study the morphology of the foams. Over the course of the aging study the foams the decreased in size by a magnitude of 0.001 inches per inch of foam. Micro CT showed the heterogeneous nature of the foam structure likely resulting from flow effects during the molding process. The effect of aging on the compression and tensile strength of the foam was minor and no cause for concern. FT-IR spectroscopy was used to follow the foam chemistry. However, it was difficult to draw definitive conclusions about the changes in chemical nature of the materials due to large variability throughout the samples.

  18. Technology development for cobalt F-T catalysts. Topical report No.1, Effects of supports and promoters on cobalt F-T catalyst behavior in fixed bed vs. slurry bubble column reactors

    SciTech Connect (OSTI)

    Oukaci, R.; Marcelin, G.; Goodwin, J.G. Jr.

    1995-01-17

    A series of cobalt-based F-T catalysts supported on alumina, silica, or titania were prepared with Ru and/or ZrO{sub 2} as promoters. All catalysts were extensively characterized by different methods. The catalysts were evaluated in terms of their activity and selectivity both in fixed bed and slurry bubble column reactors. Similar trends were observed in both reactors for support effects. However, this was not the case for the effects of promoters. Noble metal promotion effects were much more accentuated in the fixed bed reactor than under slurry bubble column reaction conditions, while the opposite seemed to hold true in the case of ZrO{sub 2} promotion effects, at least for SiO{sub 2}-supported Co catalysts.

  19. Magnetic dipole moments of {sup 57,58,59}Cu

    SciTech Connect (OSTI)

    Cocolios, T. E.; Andreyev, A. N.; Bastin, B.; Bree, N.; Buescher, J.; Elseviers, J.; Gentens, J.; Huyse, M.; Kudryavtsev, Yu.; Pauwels, D.; Bergh, P. Van den; Van Duppen, P.; Sonoda, T.

    2010-01-15

    In-gas-cell laser spectroscopy of the isotopes {sup 57,58,59,63,65}Cu has been performed at the LISOL facility using the 244.164-nm optical transition from the atomic ground state of copper. A detailed discussion on the hyperfine structure of {sup 63}Cu is presented. The magnetic dipole moments of the isotopes {sup 57,58,59,65}Cu are extracted based on that of {sup 63}Cu. The new value mu=+0.479(13)mu{sub N} is proposed for {sup 58}Cu, consistent with that of a pip{sub 3/2} x nup{sub 3/2} ground-state configuration. Spin assignments for the radioactive isotopes {sup 57,58,59}Cu are confirmed. The isotope shifts between the different isotopes are also given and discussed.

  20. The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrothermal Agingon a Commercial Cu SCR Catalyst The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst Examines the effect of hydrothermal aging on the Nox reduction over a commercial Cu-zeolite SCR catalyst. PDF icon deer11_lee.pdf More Documents & Publications CLEERS Aftertreatment Modeling and Analysis Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon

  1. Understanding NOx SCR Mechanism and Activity on Cu/Chabazite...

    Office of Scientific and Technical Information (OSTI)

    Book: Understanding NOx SCR Mechanism and Activity on CuChabazite Structures throughout the Catalyst Life Cycle Citation Details In-Document Search Title: Understanding NOx SCR...

  2. New Resolved Resonance Region Evaluation for 63Cu and 65Cu for Nuclear Criticality Safety Program

    SciTech Connect (OSTI)

    Sobes, Vladimir; Leal, Luiz C; Guber, Klaus H; Forget, Benoit; Kopecky, S.; Schillebeeckx, P.; Siegler, P.

    2014-01-01

    A new resolved resonance region evaluation of 63Cu and 65Cu was done in the energy region from 10-5 eV to 99.5 keV. The R-Matrix SAMMY method using the Reich-Moore approximation was used to create a new set of consistent resonance parameters. The new evaluation was based on three experimental transmission data sets; two measured at ORELA and one from MITR, and two radiative capture experimental data sets from GELINA. A total of 141 new resonances were identied for 63Cu and 117 for 65Cu. The corresponding set of external resonances for each isotope was based on the identied resonances above 99.5 keV from the ORELA transmission data. The negative external levels (bound levels) were determined to match the dierential thermal cross section measured at the MITR. Double dierential elastic scattering cross sections were calculated from the new set of resonance parameters. Benchmarking calculations were carried out on a set of ICSBEP benchmarks. This work is in support of the DOE Nuclear Criticality Safety Program.

  3. [Purification of {sup 67}Cu]. Progress report

    SciTech Connect (OSTI)

    DeNardo, S.J.

    1994-09-01

    This report documents progress made in several areas of research and describes results which have not yet been published. These areas include: Purification of {sup 67}Cu; Macrocyclic chelates for targeted therapy; Studies of biologic activation associated with molecular receptor increase and tumor response in ChL6/L6 protocol patients; Lym-1 single chain genetically engineered molecules; Analysis of molecular genetic coded messages to enhance tumor response; Human dosimetry and therapeutic human use radiopharmaceuticals; studies in phantoms; Quantitative SPECT; Preclinical studies; and Clinical studies.

  4. Unexpected crystal and magnetic structures in MnCu4In and MnCu4Sn

    SciTech Connect (OSTI)

    Provino, A.; Paudyal, D.; Fornasini, ML; Dhiman, I.; Dhar, SK.; Das, A.; Mudryk, Y.; Manfrinetti, P.; Pecharsky, VK

    2013-01-29

    We discovered a new compound MnCu4In with its own hexagonal structure type (hP12-P63mc, ternary ordered derivative of the hexagonal MgZn2-type) that becomes ferromagnetic at TC = 540 K. This transition temperature is higher than that found in the MnCu2In and MnCu2Sn alloys. In contrast, the homologous compound MnCu4Sn, which crystallizes in the cubic MgCu4Sn-type, orders antiferromagnetically with TN = 110 K. The neutron diffraction studies show ferromagnetic spin orientation in the {1 0 1} plane in MnCu4In with a magnetic moment of 4.5 ?B/Mn at 22 K, and a corresponding value of 4.7 ?B/Mn in the antiferromagnetic MnCu4Sn with propagation vector View the MathML source. The first-principles electronic structure calculations show that the unexpected difference in both magnetic and crystal structures of MnCu4In and MnCu4Sn is due to the difference in the Mn-3d bands and exchange interactions relating to different crystal anisotropy, coordination numbers, and interatomic distances.

  5. Non-uniform Aging on Super Duty Diesel Truck Aged Urea Cu/Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    uniform Aging on Super Duty Diesel Truck Aged Urea CuZeolite SCR Catalysts Non-uniform Aging on Super Duty Diesel Truck Aged Urea CuZeolite SCR Catalysts CuZeolite SCR catalysts ...

  6. Antiferromagnetism in EuCu2As2 and EuCu1.82Sb2 single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Anand, V. K.; Johnston, D. C.

    2015-05-07

    Single crystals of EuCu2As2 and EuCu2Sb2 were grown from CuAs and CuSb self-flux, respectively. The crystallographic, magnetic, thermal, and electronic transport properties of the single crystals were investigated by room-temperature x-ray diffraction (XRD), magnetic susceptibility χ versus temperature T, isothermal magnetization M versus magnetic field H, specific heat Cp(T), and electrical resistivity ρ(T) measurements. EuCu2As2 crystallizes in the body-centered tetragonal ThCr2Si2-type structure (space group I4/mmm), whereas EuCu2Sb2 crystallizes in the related primitive tetragonal CaBe2Ge2-type structure (space group P4/nmm). The energy-dispersive x-ray spectroscopy and XRD data for the EuCu2Sb2 crystals showed the presence of vacancies on the Cu sites, yielding themore » actual composition EuCu1.82Sb2. The ρ(T) and Cp(T) data reveal metallic character for both EuCu2As2 and EuCu1.82Sb2. Antiferromagnetic (AFM) ordering is indicated from the χ(T),Cp(T), and ρ(T) data for both EuCu2As2 (TN = 17.5 K) and EuCu1.82Sb2 (TN = 5.1 K). In EuCu1.82Sb2, the ordered-state χ(T) and M(H) data suggest either a collinear A-type AFM ordering of Eu+2 spins S = 7/2 or a planar noncollinear AFM structure, with the ordered moments oriented in the tetragonal ab plane in either case. This ordered-moment orientation for the A-type AFM is consistent with calculations with magnetic dipole interactions. As a result, the anisotropic χ(T) and isothermal M(H) data for EuCu2As2, also containing Eu+2 spins S = 7/2, strongly deviate from the predictions of molecular field theory for collinear AFM ordering and the AFM structure appears to be both noncollinear and noncoplanar.« less

  7. Accelerating Fatigue Testing for Cu Ribbon Interconnects | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Accelerating Fatigue Testing for Cu Ribbon Interconnects Accelerating Fatigue Testing for Cu Ribbon Interconnects Presented at the 2013 Photovoltaic Module Reliability Workshop; 26-27 February 2013; Denver, Colorado PDF icon 58369.pdf More Documents & Publications Thermal Cycling Combined with Dynamic Mechanical Load: Preliminary Report Physics of Failure of Electrical Interconnects Reliability of Electrical Interconnects

  8. Detailed chemical kinetic models for large n-alkanes and iso-alkanes found in conventional and F-T diesel fuels

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Curran, H J; Mehl, M

    2008-12-15

    Detailed chemical kinetic models are needed to simulate the combustion of current and future transportation fuels. These models should represent the various chemical classes in these fuels. Conventional diesel fuels are composed of n-alkanes, iso-alkanes, cycloalkanes and aromatics (Farrell et al. 2007). For future fuels, there is a renewed interest in Fischer-Tropsch (F-T) processes which can be used to synthesize diesel and other transportation fuels from biomass, coal and natural gas. F-T diesel fuels are expected to be similar to F-T jet fuels which are commonly comprised of iso-alkanes with some n-alkanes (Smith and Bruno, 2008). Thus, n-alkanes and iso-alkanes are common chemical classes in these conventional and future fuels. This paper reports on the development of chemical kinetic models of large n-alkanes and iso-alkanes to represent these chemical classes in conventional and future fuels. Two large iso-alkanes are 2,2,4,4,6,8,8-heptamethylnonane, which is a primary reference fuel for diesel, and isooctane, a primary reference fuel for gasoline. Other iso-alkanes are branched alkanes with a single methyl side chain, typical of most F-T fuels. The chemical kinetic models are then used to predict the effect of these fuel components on ignition characteristics under conditions found in internal combustion engines.

  9. Application of cluster-plus-glue-atom model to barrierless CuNiTi and CuNiTa films

    SciTech Connect (OSTI)

    Li, Xiaona, E-mail: lixiaona@dlut.edu.cn; Ding, Jianxin; Wang, Miao; Dong, Chuang [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Chu, Jinn P. [Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China)

    2014-11-01

    To improve the thermal stability of copper and avoid its diffusion into surrounding dielectrics or interfacial reactions with them, the authors applied the cluster-plus-glue-atom model to investigate barrierless CuNiM (M?=?Ti or Ta) seed layers. The dissolution of the third element (Ti or Ta) in the Cu lattice with the aid of Ni significantly improved the thermal stability of the Cu seed layer. The appropriate M/Ni (M?=?Ti or Ta) ratio was selected to obtain a low resistivity: the resistivity was as low as 2.5??? cm for the (Ti{sub 1.5/13.5}Ni{sub 12/13.5}){sub 0.3}Cu{sub 99.7} film and 2.8??? cm for the (Ta{sub 1.1/13.1}Ni{sub 12/13.1}){sub 0.4}Cu{sub 99.6} film after annealing at 500?C for 1?h. After annealing at 500?C for 40?h, the two films remained stable without forming a Cu{sub 3}Si compound. The authors confirmed that the range of applications of the cluster-plus-glue-atom model could be extended. Therefore, a third element M with negative enthalpies of mixing with both Cu and Ni could be selected, under the premise that the mixing enthalpy of MNi is more negative than that of MCu.

  10. Photoelectrochemistry, Electronic Structure, and Bandgap Sizes of Semiconducting Cu(I)-Niobates and Cu(I)-Tantalates

    SciTech Connect (OSTI)

    Maggard, Paul A.

    2013-11-14

    Semiconducting metal-oxides have remained of intense research interest owing to their potential for achieving efficient solar-driven photocatalytic reactions in aqueous solutions that occur as a result of their bandgap excitation. The photocatalytic reduction of water or carbon dioxide to generate hydrogen or hydrocarbon fuels, respectively, can be driven on p-type (photocathodic) electrodes with suitable band energies. However, metal-oxide semiconductors are typically difficult to dope as p-type with a high mobility of carriers. The supported research led to the discovery of new p-type Cu(I)-niobate and Cu(I)-tantalate film electrodes that can be prepared on FTO glass. New high-purity flux syntheses and the full structural determination of several Cu(I)-containing niobates and tantalates have been completed, as well as new investigations of their optical and photoelectrochemical properties and electronic structures via density-functional theory calculations. For example, CuNbO3, Cu5Ta11O30 and CuNb3O8 were prepared in high purity and their structures were characterized by both single-crystal and powder X-ray diffraction techniques. These two classes of Cu(I)-containing compounds exhibit optical bandgap sizes ranging from ~1.3 eV to ~2.6 eV. Photoelectrochemical measurements of these compounds show strong photon-driven cathodic currents that confirm the p-type semiconductor behavior of CuNbO3, CuNb3O8, and Cu5Ta11O30. Incident-photon-to-current efficiencies are measured that approach greater than ~1%. Electronic-structure calculations based on density functional theory reveal the visible-light absorption stems from a nearly-direct bandgap transition involving a copper-to-niobium or tantalum (d10 to d0) charge-transfer excitations.

  11. Structure and electrochemical properties of nanometer Cu substituted ?-nickel hydroxide

    SciTech Connect (OSTI)

    Bao, Jie; Zhu, Yanjuan; Zhang, Zhongju; Xu, Qingsheng; Zhao, Weiren; Chen, Jian; Zhang, Wei; Han, Quanyong

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ? Cu substituted ?-nickel hydroxide was prepared by ultrasonic assisted precipitation. ? The XRD peaks are anisotropic broadening. ? The electrode for 0.9 wt.% Cu has the highest capacity of 310 mAh/g at 0.2 C. -- Abstract: Nanometer Cu-substituted ?-nickel hydroxide was synthesized by means of ultrasonic-assisted precipitation. Particle size distribution (PSD) measurement, X-ray diffraction (XRD), and high-resolution transmission electron microscope (HR-TEM) were used to characterize the physical properties of the synthesized samples. The results indicate that the average particle size of the samples is about 96110 nm and the XRD diffraction peaks are anisotropic broadening. The crystal grains are mainly polycrystal structure with columnar or needle-like morphology, containing many defects. With increase of Cu content, the shape of primary particles transform from columnar to needle-like. The influences of doping amounts of Cu on the electrochemical performance were investigated through constant current charge/discharge and cyclic voltammetric measurements. The specific capacity increases initially and then decreases with increasing Cu-doping ratio, the electrode C containing 0.9 wt.% Cu shows the maximum discharge capacity of 310 mAh/g at 0.2 C, and it has the lowest charging voltage, higher discharge voltage plateau, better cycle performance and larger proton diffusion coefficient than the other electrodes.

  12. Coupled skyrmion sublattices in Cu2OSeO3

    SciTech Connect (OSTI)

    Langner, M.C.; Roy,, S.; Mishra, S. K.; Lee, J. C. T.; Shi,, X. W.; Hossain, M. A.; Chuang, Y.-D.; Seki, S.; Tokura, Y.; Kevan, S. D.; Schoenlein, R. W.

    2014-04-18

    We report the observation of a skyrmion lattice in the chiral multiferroic insulator Cu2OSeO3 using Cu L3-edge resonant soft x-ray diffraction. We observe the unexpected existence of two distinct skyrmion sub-lattices that arise from inequivalent Cu sites with chemically identical coordination numbers but different magnetically active orbitals . The skyrmion sublattices are rotated with respect to each other implying a long wavelength modulation of the lattice. The modulation vector is controlled with an applied magnetic field, associating this Moir'e-like phase with a continuous phase transition. Our findings will open a new class of science involving manipulation of quantum topological states.

  13. Crystallization of Zr2PdxCu(1-x) and Zr2NixCu(1-x) Metallic Glass

    SciTech Connect (OSTI)

    Min Xu

    2008-08-18

    One interesting aspect of rretallic glasses is the numerous instances of the deviation of the phase selection from the amorphous state to thermodynamically stable phases during the crystallization process. Their devitrification pathways allow us to study the relationship between the original amorphous structure and their crystalline counter parts. Among the various factors of phase selections, size and electronic effects have been most extensively studied. Elucidating the phase selection process of a glassy alloy will be helpful to fill in the puzzle of the changes from disordered to ordered structures. In this thesis, Two model Zr{sub 2}Pd{sub x}Cu{sub (1-x)} and Zr{sub 2}Ni{sub x}Cu{sub (1-x)} (x = 0, 0.25, 0.5, 0.75 and 1) glassy systems were investigated since: (1) All of the samples can be made into a homogenous metallic glass; (2) The atomic radii differ from Pd to Cu is by 11%, while Ni has nearly the identical atomic size compare to Cu. Moreover, Pd and Ni differ by only one valence electron from Cu. Thus, these systems are ideal to test the idea of the effects of electronic structure and size factors; (3) The small number of components in these pseudo binary systems readily lend themselves to theoretical modeling. Using high temperature X-ray diffraction {HTXRD) and thermal analysis, topological, size, electronic, bond and chemical distribution factors on crystallization selections in Zr{sub 2}Pd{sub x}Cu{sub (1-x)} and Zr{sub 2}Ni{sub x}Cu{sub (1-x)} metallic glass have been explored. All Zr{sub 2}Pd{sub x}Cu{sub (1-x)} compositions share the same Cu11b phase with different pathways of meta-stable, icosahedral quasicrystalline phase (i-phase), and C16 phase formations. The quasicrystal phase formation is topologically related to the increasing icosahedral short range order (SRO) with Pd content in Zr{sub 2}Pd{sub x}Cu{sub (1·x)} system. Meta-stable C16 phase is competitive with C11b phase at x = 0.5, which is dominated by electronic structure rather than size effects. Cu-rich and Ni-rich compositions in Zr{sub 2}Ni{sub x}Cu{sub (1-x)} trend to divitrify to C11b or C16 phases respectively. In the proposed pseudo binary phase diagram, the domain of C16, C11b and co-existence phases are mainly related with the topology in the amorphous structure and formation enthalpies of crystalline phases.

  14. Understanding the Deactivation Mechanisms of Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zeolite SCR Catalysts in Diesel Application To understand the durability of CuZeolite urea-SCR catalysts in diesel applications, the effects of engine and lab aging on catalyst...

  15. Improving properties of Mg with AlCu additions

    SciTech Connect (OSTI)

    Rashad, Muhammad; Pan, Fusheng; Asif, Muhammad; Hussain, Shahid; Saleem, Muhammad

    2014-09-15

    The present work reports improvement in tensile properties of the Mg matrix reinforced with micron-sized copperaluminum particulate hybrids. The AlCu particulate hybrids were incorporated into the Mg matrix through powder metallurgy method. The synthesized alloys exhibited homogeneously dispersed Mg{sub 2}Cu particles in the matrix, therefore leading to a 110% increase in yield strength (221 MPa) and a 72% enhancement in ultimate tensile strength (284 MPa) by addition of 1.0 wt.%Al0.6 wt.%Cu particle hybrids. Optical microscopy, scanning election microscopy, transmission electron microscopy and X-ray diffraction were used to investigate the microstructure and intermetallic phases of the synthesized alloys. - Highlights: Mg matrix is reinforced with AlCu particulate hybrids. Powder metallurgic method is used to fabricate the alloys. Tensile strength and ductility were increased simultaneously.

  16. High resolution FT-ICR mass spectral analysis of bio-oil and residual water soluble organics produced by hydrothermal liquefaction of the marine microalga Nannochloropsis salina

    SciTech Connect (OSTI)

    Sudasinghe, Nilusha; Dungan, Barry; Lammers, Peter; Albrecht, Karl O.; Elliott, Douglas C.; Hallen, Richard T.; Schaub, Tanner

    2014-03-01

    We report a detailed compositional characterization of a bio-crude oil and aqueous by-product from hydrothermal liquefaction of Nannochloropsis salina by direct infusion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) in both positive- and negative-ionization modes. The FT-ICR MS instrumentation approach facilitates direct assignment of elemental composition to >7000 resolved mass spectral peaks and three-dimensional mass spectral images for individual heteroatom classes highlight compositional diversity of the two samples and provide a baseline description of these materials. Aromatic nitrogen compounds and free fatty acids are predominant species observed in both the bio-oil and aqueous fraction. Residual organic compounds present in the aqueous fraction show distributions that are slightly lower in both molecular ring and/or double bond value and carbon number relative to those found in the bio-oil, albeit with a high degree of commonality between the two compositions.

  17. Arizona - Natural Gas 2014 Million Cu. Feet Percent of

    Gasoline and Diesel Fuel Update (EIA)

    4 Arizona - Natural Gas 2014 Million Cu. Feet Percent of National Total Million Cu. Feet Percent of National Total Total Net Movements: - Industrial: Dry Production: Vehicle Fuel: Deliveries to Consumers: Residential: Electric Power: Commercial: Total Delivered: Table S3. Summary statistics for natural gas - Arizona, 2010-2014 2010 2011 2012 2013 2014 Number of Producing Gas Wells at End of Year 5 5 5 5 5 Production (million cubic feet) Gross Withdrawals From Gas Wells 183 168 117 72 106 From

  18. Characteristics of Cu stabilized Nb3Al strands with low Cu ratio

    SciTech Connect (OSTI)

    Kikuchi, A.; Yamada, R.; Barzi, E.; Kobayashi, M.; Lamm, M.; Nakagawa, K.; Sasaki, K.; Takeuchi, T.; Turrioni, D.; Zlobin, A.V.; /NIMC, Tsukuba /Fermilab /Hitachi, Tsuchiura Works /KEK, Tsukuba

    2008-12-01

    Characteristics of recently developed F4-Nb{sub 3}Al strand with low Cu ratio are described. The overall J{sub c} of the Nb{sub 3}Al strand could be easily increased by decreasing of the Cu ratio. Although the quench of a pulse-like voltage generation is usually observed in superconducting unstable conductor, the F4 strand with a low Cu ratio of 0.61 exhibited an ordinary critical transition of gradual voltage generation. The F4 strand does not have magnetic instabilities at 4.2 K because of the tantalum interfilament matrix. The overall J{sub c} of the F4 strand achieved was 80-85% of the RRP strand. In the large mechanical stress above 100 MPa, the overall J{sub c} of the F4 strand might be comparable to that of high J{sub c} RRP-Nb{sub 3}Sn strands. The Rutherford cable with a high packing factor of 86.5% has been fabricated using F4 strands. The small racetrack magnet, SR07, was also fabricated by a 14 m F4 cable. The quench current, I{sub q}, of SR07 were obtained 22.4 kA at 4.5 K and 25.2 kA at 2.2 K. The tantalum matrix Nb{sub 3}Al strands are promising for the application of super-cooled high-field magnets as well as 4.2 K operation magnets.

  19. Cu--Pd--M hydrogen separation membranes

    DOE Patents [OSTI]

    Do{hacek over }an, Omer N; Gao, Michael C; Young, Rongxiang Hu; Tafen, De Nyago

    2013-12-17

    The disclosure provides an H2 separation membrane comprised of an allow having the composition Cu.Sub.(100-x-y)Pd.sub.xM.sub.y, where x is from about 35 to about 50 atomic percent and where y is from greater than 0 to about 20 atomic percent, and where M consists of magnesium, yttrium, aluminum, titanium, lanthanum, or combinations thereof. The M elements act as strong stabilizers for the B2 phase of the allow, and extend the critical temperature of the alloy for a given hydrogen concentration and pressure. Due to the phase stabilization and the greater temperature range over which a B2 phase can be maintained, the allow is well suited for service as a H2 separation membrane, particularly when applicable conditions are established or cycled above about 600.degree. C. over the course of expected operations. In certain embodiments, the B2 phase comprises at least 60 estimated volume percent of the allow at a steady-state temperature of 400.degree. C. The B2 phase stability is experimentally validated through HT-XRD.

  20. Modified Ni-Cu catalysts for ethanol steam reforming

    SciTech Connect (OSTI)

    Dan, M.; Mihet, M.; Almasan, V.; Borodi, G.; Katona, G.; Muresan, L.; Lazar, M. D.

    2013-11-13

    Three Ni-Cu catalysts, having different Cu content, supported on ?-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150C amorphous carbon was evidenced, while at 350C crystalline, filamentous carbon is formed.

  1. Analysis of the structure, configuration, and sizing of Cu and Cu oxide nanoparticles generated by fs laser ablation of solid target in liquids

    SciTech Connect (OSTI)

    Santillan, J. M. J.; Videla, F. A.; Schinca, D. C.; Scaffardi, L. B.; Fernandez van Raap, M. B.

    2013-04-07

    We report on the analysis of structure, configuration, and sizing of Cu and Cu oxide nanoparticles (Nps) produced by femtosecond (fs) laser ablation of solid copper target in liquids. Laser pulse energy ranged between 500 {mu}J and 50 {mu}J. Water and acetone were used to produce the colloidal suspensions. The study was performed through optical extinction spectroscopy using Mie theory to fit the full experimental spectra, considering free and bound electrons size dependent contributions to the metal dielectric function. Raman spectroscopy and AFM technique were also used to characterize the sample. Considering the possible oxidation of copper during the fabrication process, two species (Cu and Cu{sub 2}O) arranged in two structures (bare core or core-shell) and in two configuration types (Cu-Cu{sub 2}O or Cu{sub 2}O-Cu) were considered for the fitting depending on the laser pulse energy and the surrounding media. For water at high energy, it can be observed that a Cu-Cu{sub 2}O configuration fits the experimental spectra of the colloidal suspension, while for decreasing energy and below a certain threshold, a Cu{sub 2}O-Cu configuration needs to be included for the optimum fit. Both species coexist for energies below 170 {mu}J for water. On the other hand, for acetone at high energy, optimum fit of the full spectrum suggests the presence a bimodal Cu-Cu{sub 2}O core-shell Nps distribution while for decreasing energy and below a 70 {mu}J threshold energy value, Cu{sub 2}O-Cu core-shell Nps must be included, together with the former configuration, for the fit of the full spectrum. We discuss possible reasons for the changes in the structural configuration of the core-shell Nps.

  2. Ab initio molecular dynamics simulations of short-range order in Zr50Cu45Al5 and Cu50Zr45Al5 metallic glasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Yuxiang; Huang, Li; Wang, C. Z.; Kramer, M. J.; Ho, K. M.

    2016-02-01

    In this study, comparative analysis between Zr-rich Zr50Cu45Al5 and Cu-rich Cu50Zr45Al5 metallic glasses (MGs) is extensively performed to locate the key structural motifs accounting for their difference of glass forming ability. Here we adopt ab initio molecular dynamics simulations to investigate the local atomic structures of Zr50Cu45Al5 and Cu50Zr45Al5 MGs. A high content of icosahedral-related (full and distorted) orders was found in both samples, while in the Zr-rich MG full icosahedrons <0,0,12,0> is dominant, and in the Cu-rich one the distorted icosahedral orders, especially <0,2,8,2> and <0,2,8,1>, are prominent. And the <0,2,8,2> polyhedra in Cu50Zr45Al5 MG mainly originate from Al-centeredmore » clusters, while the <0,0,12,0> in Zr50Cu45Al5 derives from both Cu-centered clusters and Al-centered clusters. These difference may be ascribed to the atomic size difference and chemical property between Cu and Zr atoms. The relatively large size of Zr and large negative heat of mixing between Zr and Al atoms, enhancing the packing density and stability of metallic glass system, may be responsible for the higher glass forming ability of Zr50Cu45Al5.« less

  3. Hydrothermal Liquefaction Oil and Hydrotreated Product from Pine Feedstock Characterized by Heteronuclear Two-Dimensional NMR Spectroscopy and FT-ICR Mass Spectrometry

    SciTech Connect (OSTI)

    Sudasinghe, Nilusha; Cort, John R.; Hallen, Richard T.; Olarte, Mariefel V.; Schmidt, Andrew J.; Schaub, Tanner

    2014-12-01

    Hydrothermal liquefaction (HTL) crude oil and hydrotreated product from pine tree farm waste (forest product residual, FPR) have been analyzed by direct infusion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) in both positive- and negative-ionization modes and high-resolution twodimensional heteronuclear 1H-13C NMR spectroscopy. FT-ICR MS resolves thousands of compounds in complex oils and provides unparalleled compositional details for individual molecules for identification of compound class (heteroatom content), type (number of rings plus double bonds to carbon or double bond equivalents (DBE) and carbon number (degree of alkylation). Heteronuclear 1H-13C NMR spectroscopy provides one-bond and multiple-bond correlations between pairs of 1H and 13C chemical shifts that are characteristic of different organic functional groups. Taken together this information provides a picture of the chemical composition of these oils. Pyrolysis crude oil product from pine wood was characterized for comparison. Generally, pyrolysis oil is comprised of a more diverse distribution of heteroatom classes with higher oxygen number relative to HTL oil as shown by both positive- and negative-ion ESI FT-ICR MS. A total of 300 N1, 594 O1 and 267 O2 compounds were observed as products of hydrotreatment. The relative abundance of N1O1, N1O2, N1O3, N2, N2O1, N2O2 and O3 compounds are reduced to different degrees after hydrotreatment and other higher heteroatom containing species (O4-O10, N1O4, N1O5 and N2O3) are completely removed by hydrotreatment.

  4. Itinerant magnetism in metallic CuFe2Ge2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shanavas, K. V.; Singh, David J.; He, Ruihua

    2015-03-25

    Theoretical calculations are performed to understand the electronic structure and magnetic properties of CuFe2Ge2. The band structure reveals large electron density N(EF) at the Fermi level suggesting a strong itinerant character of magnetism. The Fermi surface is dominated by two dimensional sheet like structures, with potentially strong nesting between them. The magnetic ground state appears to be ferromagnetic along a and antiferromagnetic in other directions. The results show that CuFe2Ge2 is an antiferromagnetic metal, with similarities to the Fe-based superconductors; such as magnetism with substantial itinerant character and coupling between magnetic order and electrons at the Fermi energy.

  5. Pb-free Sn-Ag-Cu ternary eutectic solder

    DOE Patents [OSTI]

    Anderson, Iver E. (Ames, IA); Yost, Frederick G. (Cedar Crest, NM); Smith, John F. (Ames, IA); Miller, Chad M. (Ames, IA); Terpstra, Robert L. (Ames, IA)

    1996-06-18

    A Pb-free solder includes a ternary eutectic composition consisting essentially of about 93.6 weight % Sn-about 4.7 weight % Ag-about 1.7 weight % Cu having a eutectic melting temperature of about 217.degree. C. and variants of the ternary composition wherein the relative concentrations of Sn, Ag, and Cu deviate from the ternary eutectic composition to provide a controlled melting temperature range (liquid-solid "mushy" zone) relative to the eutectic melting temperature (e.g. up to 15.degree. C. above the eutectic melting temperature).

  6. Origins of optical absorption characteristics of Cu2+ complexes in

    Office of Scientific and Technical Information (OSTI)

    solutions (Journal Article) | SciTech Connect Origins of optical absorption characteristics of Cu2+ complexes in solutions Citation Details In-Document Search Title: Origins of optical absorption characteristics of Cu2+ complexes in solutions Authors: Qiu, S R ; Wood, B C ; Ehrmann, P R ; Demos, S G ; Miller, P E ; Schaffers, K I ; Suratwala, T I Publication Date: 2015-02-27 OSTI Identifier: 1234585 Report Number(s): LLNL-JRNL-668007 DOE Contract Number: AC52-07NA27344 Resource Type: Journal

  7. Pb-free Sn-Ag-Cu ternary eutectic solder

    DOE Patents [OSTI]

    Anderson, I.E.; Yost, F.G.; Smith, J.F.; Miller, C.M.; Terpstra, R.L.

    1996-06-18

    A Pb-free solder includes a ternary eutectic composition consisting essentially of about 93.6 weight % Sn-about 4.7 weight % Ag-about 1.7 weight % Cu having a eutectic melting temperature of about 217 C and variants of the ternary composition wherein the relative concentrations of Sn, Ag, and Cu deviate from the ternary eutectic composition to provide a controlled melting temperature range (liquid-solid ``mushy`` zone) relative to the eutectic melting temperature (e.g. up to 15 C above the eutectic melting temperature). 5 figs.

  8. Distinct oxygen hole doping in different layers of Sr₂CuO4-δ/La₂CuO₄ superlattices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smadici, S.; Lee, J. C. T.; Rusydi, A.; Logvenov, G.; Bozovic, I.; Abbamonte, P.

    2012-03-28

    X-ray absorption in Sr₂CuO4-δ/La₂CuO₄ (SCO/LCO) superlattices shows a variable occupation with doping of a hole state different from holes doped for x≲xoptimal in bulk La2-xSrxCuO₄ and suggests that this hole state is on apical oxygen atoms and polarized in the a-b plane. Considering the surface reflectivity gives a good qualitative description of the line shapes of resonant soft x-ray scattering. The interference between superlattice and surface reflections was used to distinguish between scatterers in the SCO and the LCO layers, with the two hole states maximized in different layers of the superlattice.

  9. Nanoporous Cu-C composites based on carbon-nanotube aerogels...

    Office of Scientific and Technical Information (OSTI)

    Nanoporous Cu-C composites based on carbon-nanotube aerogels Citation Details In-Document Search Title: Nanoporous Cu-C composites based on carbon-nanotube aerogels Current ...

  10. High Chalcocite Cu2S: A Solid-Liquid Hybrid Phase (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    High Chalcocite Cu2S: A Solid-Liquid Hybrid Phase Prev Next Title: High Chalcocite Cu2S: A Solid-Liquid Hybrid Phase Authors: Wang, Lin-Wang Publication Date: 2012-02-24 OSTI...

  11. Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x (Technical...

    Office of Scientific and Technical Information (OSTI)

    Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x Citation Details In-Document Search Title: Broken Symmetry in the Pseudogap State of YBa2Cu3O6+x You are accessing a...

  12. The structure of oxygen on Cu(100) at low and high coverages...

    Office of Scientific and Technical Information (OSTI)

    The structure of oxygen on Cu(100) at low and high coverages Citation Details In-Document Search Title: The structure of oxygen on Cu(100) at low and high coverages No abstract ...

  13. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 3.45 2.15 1.89 2.03 2.25 2.20 2.19 2.49 2.88 3.07 3.01 2.35 1998 2.09 2.23 2.24 2.43 2.14 2.17 2.17 1.85 2.02 1.91 2.12...

  14. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.001 1.720 2.433 2.463 2.231 2.376 2000's 4.304 4.105 3.441 5.497 6.417 9.186 7.399 7.359 9.014 4.428 2010's 4.471 4.090 2.926 3.775 4.236 2.684

  15. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1994 2.188 2.232 2.123 2.136 1.999 2.130 2.021 1.831 1.881 1.961 1.890 1.709 1995 1.457 1.448 1.595 1.718 1.770 1.685 1.525 1.630 1.805 1.870 1.936 2.200 1996 2.177 2.175 2.205 2.297 2.317 2.582 2.506 2.120 2.134 2.601 2.862 3.260 1997 2.729 2.016 1.954 2.053 2.268 2.171 2.118 2.484 2.970 3.321 3.076 2.361 1998 2.104 2.293 2.288 2.500 2.199 2.205 2.164 1.913 2.277 2.451 2.438 1.953 1999 1.851 1.788 1.829 2.184 2.293 2.373 2.335 2.836 2.836

  16. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 1994-Jan 01/14 2.113 01/21 2.159 01/28 2.233 1994-Feb 02/04 2.303 02/11 2.230 02/18 2.223 02/25 2.197 1994-Mar 03/04 2.144 03/11 2.150 03/18 2.148 03/25 2.095 1994-Apr 04/01 2.076 04/08 2.101 04/15 2.137 04/22 2.171 04/29 2.133 1994-May 05/06 2.056 05/13 2.017 05/20 1.987 05/27 1.938 1994-Jun 06/03 2.023 06/10 2.122 06/17 2.173 06/24 2.118 1994-Jul 07/01 2.182 07/08 2.119

  17. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.039 1.739 2.350 2.418 2.290 2.406 2000's 4.217 4.069 3.499 5.466 6.522 9.307 7.852 7.601 9.141 4.669 2010's 4.564 4.160 3.020 3.822 4.227 2.739

  18. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1994 2.116 2.168 2.118 2.139 2.038 2.150 2.083 2.031 2.066 2.037 1.873 1.694 1995 1.490 1.492 1.639 1.745 1.801 1.719 1.605 1.745 1.883 1.889 1.858 1.995 1996 1.964 2.056 2.100 2.277 2.307 2.572 2.485 2.222 2.272 2.572 2.571 2.817 1997 2.393 1.995 1.978 2.073 2.263 2.168 2.140 2.589 3.043 3.236 2.803 2.286 1998 2.110 2.312 2.312 2.524 2.249 2.234 2.220 2.168 2.479 2.548 2.380 1.954 1999 1.860 1.820 1.857 2.201 2.315 2.393 2.378 2.948 2.977

  19. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 1994-Jan 01/21 2.055 01/28 2.133 1994-Feb 02/04 2.189 02/11 2.159 02/18 2.174 02/25 2.163 1994-Mar 03/04 2.127 03/11 2.136 03/18 2.141 03/25 2.103 1994-Apr 04/01 2.085 04/08 2.105 04/15 2.131 04/22 2.175 04/29 2.149 1994-May 05/06 2.076 05/13 2.045 05/20 2.034 05/27 1.994 1994-Jun 06/03 2.078 06/10 2.149 06/17 2.172 06/24 2.142 1994-Jul 07/01 2.187 07/08 2.143 07/15 2.079

  20. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 1.906 2.054 1.746 2.270 2.363 2.332 2.418 2000's 4.045 4.103 3.539 5.401 6.534 9.185 8.238 7.811 9.254 4.882 2010's 4.658 4.227 3.109 3.854 4.218 2.792

  1. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1993 1.906 1994 2.012 2.140 2.120 2.150 2.081 2.189 2.186 2.168 2.079 1.991 1.843 1.672 1995 1.519 1.541 1.672 1.752 1.810 1.763 1.727 1.826 1.886 1.827 1.770 1.844 1996 1.877 1.985 2.040 2.245 2.275 2.561 2.503 2.293 2.296 2.436 2.317 2.419 1997 2.227 1.999 1.987 2.084 2.249 2.194 2.274 2.689 2.997 2.873 2.532 2.204 1998 2.124 2.324 2.333 2.533 2.289 2.291 2.428 2.419 2.537 2.453 2.294 1.940 1999 1.880 1.850 1.886 2.214 2.331 2.429 2.539

  2. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 1993-Dec 12/24 1.869 12/31 1.943 1994-Jan 01/07 1.935 01/14 1.992 01/21 2.006 01/28 2.088 1994-Feb 02/04 2.133 02/11 2.135 02/18 2.148 02/25 2.149 1994-Mar 03/04 2.118 03/11 2.125 03/18 2.139 03/25 2.113 1994-Apr 04/01 2.107 04/08 2.120 04/15 2.140 04/22 2.180 04/29 2.165 1994-May 05/06 2.103 05/13 2.081 05/20 2.076 05/27 2.061 1994-Jun 06/03 2.134 06/10 2.180 06/17 2.187

  3. Microfabricated BTU monitoring device for system-wide natural...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Sandia National Laboratories Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 03 NATURAL GAS; COMBUSTION; EFFICIENCY; FEEDBACK; ...

  4. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Sep Oct Nov Dec 1994 2.188 2.232 2.123 2.136 1.999 2.130 2.021 1.831 1.881 1.961 1.890 1.709 1995 1.457 1.448 1.595 1.718 1.770 1.685 1.525 1.630 1.805 1.870 1.936 2.200 1996 2.177...

  5. Natural Gas Futures Contract 1 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 1.934 1.692 2.502 2.475 2.156 2.319 2000's 4.311 4.053 3.366 5.493 6.178 9.014 6.976 7.114 8.899 4.159 2010's 4.382 4.026 2.827 3.731 4.262 2.627

  6. Natural Gas Futures Contract 1 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 1994-Jan 01/14 2.231 01/21 2.297 01/28 2.404 1994-Feb 02/04 2.506 02/11 2.369 02/18 2.330 02/25 2.267 1994-Mar 03/04 2.178 03/11 2.146 03/18 2.108 03/25 2.058 1994-Apr 04/01 2.065 04/08 2.092 04/15 2.127 04/22 2.126 04/29 2.097 1994-May 05/06 2.025 05/13 1.959 05/20 1.933 05/27 1.855 1994-Jun 06/03 1.938 06/10 2.052 06/17 2.128 06/24 2.065 1994-Jul 07/01 2.183 07/08 2.087

  7. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Week Of Mon Tue Wed Thu Fri 1994 Jan-10 to Jan-14 2.130 2.072 2.139 1994 Jan-17 to Jan-21 2.196 2.131 2.115 2.148 2.206 1994 Jan-24 to Jan-28 2.283 2.134 2.209 2.236 2.305 1994 Jan-31 to Feb- 4 2.329 2.388 2.352 2.252 2.198 1994 Feb- 7 to Feb-11 2.207 2.256 2.220 2.231 2.236 1994 Feb-14 to Feb-18 2.180 2.189 2.253 2.240 2.254 1994 Feb-21 to Feb-25 2.220 2.168 2.179 2.221 1994 Feb-28 to Mar- 4 2.165 2.146 2.139 2.126 2.144 1994 Mar- 7 to Mar-11 2.149 2.168 2.160 2.144 2.132 1994 Mar-14 to Mar-18

  8. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Week Of Mon Tue Wed Thu Fri 1994 Jan-17 to Jan-21 2.019 2.043 2.103 1994 Jan-24 to Jan-28 2.162 2.071 2.119 2.128 2.185 1994 Jan-31 to Feb- 4 2.217 2.258 2.227 2.127 2.118 1994 Feb- 7 to Feb-11 2.137 2.175 2.162 2.160 2.165 1994 Feb-14 to Feb-18 2.140 2.145 2.205 2.190 2.190 1994 Feb-21 to Feb-25 2.180 2.140 2.148 2.186 1994 Feb-28 to Mar- 4 2.148 2.134 2.122 2.110 2.124 1994 Mar- 7 to Mar-11 2.129 2.148 2.143 2.135 2.125 1994 Mar-14 to Mar-18 2.111 2.137 2.177 2.152 2.130 1994 Mar-21 to Mar-25

  9. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    Week Of Mon Tue Wed Thu Fri 1993 Dec-20 to Dec-24 1.894 1.830 1.859 1.895 1993 Dec-27 to Dec-31 1.965 1.965 1.943 1.901 1994 Jan- 3 to Jan- 7 1.883 1.896 1.962 1.955 1.980 1994 Jan-10 to Jan-14 1.972 2.005 2.008 1.966 2.010 1994 Jan-17 to Jan-21 2.006 1.991 1.982 2.000 2.053 1994 Jan-24 to Jan-28 2.095 2.044 2.087 2.088 2.130 1994 Jan-31 to Feb- 4 2.157 2.185 2.157 2.075 2.095 1994 Feb- 7 to Feb-11 2.115 2.145 2.142 2.135 2.140 1994 Feb-14 to Feb-18 2.128 2.125 2.175 2.160 2.155 1994 Feb-21 to

  10. Kansas Heat Content of Natural Gas Deliveries to Consumers (BTU...

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 1,018 1,034 1,019 2010's 1,019 1,020 1,022 1,020 1,021...

  11. Natural Gas Futures Contract 1 (Dollars per Million Btu)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Week Of Mon Tue Wed Thu Fri 1994 Jan-10 to Jan-14 2.194 2.268 1994 Jan-17 to Jan-21 2.360 2.318 2.252 2.250 2.305 1994 Jan-24 to Jan-28 2.470 2.246 2.359 2.417 2.528 1994 Jan-31 to Feb- 4 2.554 2.639 2.585 2.383 2.369 1994 Feb- 7 to Feb-11 2.347 2.411 2.358 2.374 2.356 1994 Feb-14 to Feb-18 2.252 2.253 2.345 2.385 2.418 1994 Feb-21 to Feb-25 2.296 2.232 2.248 2.292 1994 Feb-28 to Mar- 4 2.208 2.180 2.171 2.146 2.188 1994 Mar- 7 to Mar-11 2.167 2.196 2.156 2.116 2.096 1994 Mar-14 to Mar-18 2.050

  12. ,"Henry Hub Natural Gas Spot Price (Dollars per Million Btu)...

    U.S. Energy Information Administration (EIA) Indexed Site

    Daily","3212016" ,"Release Date:","3232016" ,"Next Release Date:","3302016" ,"Excel File Name:","rngwhhdd.xls" ,"Available from Web Page:","http:tonto.eia.govdnavnghist...

  13. ,"Henry Hub Natural Gas Spot Price (Dollars per Million Btu)...

    U.S. Energy Information Administration (EIA) Indexed Site

    Monthly","22016" ,"Release Date:","3232016" ,"Next Release Date:","3302016" ,"Excel File Name:","rngwhhdm.xls" ,"Available from Web Page:","http:tonto.eia.govdnavnghist...

  14. ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    in this table do not include enclosed malls and strip malls. In the 1999 CBECS, total fuel oil consumption in malls was not statistically significant. (*)Value rounds to zero...

  15. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Week Of Mon Tue Wed Thu Fri 1997 Jan- 6 to Jan-10 3.82 3.80 3.61 3.92 1997 Jan-13 to Jan-17 4.00 4.01 4.34 4.71 3.91 1997 Jan-20 to Jan-24 3.26 2.99 3.05 2.96 2.62 1997 Jan-27 to ...

  16. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Year-Month Week 1 Week 2 Week 3 Week 4 Week 5 End Date Value End Date Value End Date Value End Date Value End Date Value 1997-Jan 0110 3.79 0117 4.19 0124 2.98 0131 2.91 ...

  17. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.49 2.09 2.27 2000's 4.31 3.96 3.38 5.47 5.89 8.69 6.73 6.97 8.86 3.94 2010's 4.37 4.00 2.75 ...

  18. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 3.45 2.15 1.89 2.03 2.25 2.20 2.19 2.49 2.88 3.07 3.01 2.35 1998 2.09 2.23 2.24 2.43 2.14 2.17 2.17 1.85 2.02 1.91 2.12 ...

  19. Natural Gas Futures Contract 1 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1994 2.347 2.355 2.109 2.111 1.941 2.080 1.963 1.693 1.619 1.721 1.771 1.700 1995 1.426 1.439 1.534 1.660 1.707 1.634 1.494...

  20. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel Application PDF icon deer09_cheng.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite

  1. High strength-high conductivity Cu--Fe composites produced by powder compaction/mechanical reduction

    DOE Patents [OSTI]

    Verhoeven, John D. (Ames, IA); Spitzig, William A. (Ames, IA); Gibson, Edwin D. (Ames, IA); Anderson, Iver E. (Ames, IA)

    1991-08-27

    A particulate mixture of Cu and Fe is compacted and mechanically reduced to form an "in-situ" Cu-Fe composite having high strength and high conductivity. Compaction and mechanical reduction of the particulate mixture are carried out at a temperature and time at temperature selected to avoid dissolution of Fe into the Cu matrix particulates to a harmful extent that substantially degrades the conductivity of the Cu-Fe composite.

  2. High strength-high conductivity Cu-Fe composites produced by powder compaction/mechanical reduction

    DOE Patents [OSTI]

    Verhoeven, J.D.; Spitzig, W.A.; Gibson, E.D.; Anderson, I.E.

    1991-08-27

    A particulate mixture of Cu and Fe is compacted and mechanically reduced to form an ''in-situ'' Cu-Fe composite having high strength and high conductivity. Compaction and mechanical reduction of the particulate mixture are carried out at a temperature and time at temperature selected to avoid dissolution of Fe into the Cu matrix particulates to a harmful extent that substantially degrades the conductivity of the Cu-Fe composite. 5 figures.

  3. Deactivation Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrothermal Aging | Department of Energy Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive Hydrothermal Aging Deactivation Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive Hydrothermal Aging Better control for preventing catalyst deactivation resulted from study of and proposed mechanism for deactivation of Cu/zeolite under rich conditions. PDF icon deer08_huang.pdf More Documents & Publications Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts in Diesel

  4. Effects of annealing on antiwear and antibacteria behaviors of TaN-Cu nanocomposite thin films

    SciTech Connect (OSTI)

    Hsieh, J. H.; Cheng, M. K.; Chang, Y. K.; Li, C.; Chang, C. L.; Liu, P. C.

    2008-07-15

    TaN-Cu nanocomposite films were deposited by reactive cosputtering on Si and tool steel substrates. The films were then annealed using rapid thermal annealing (RTA) at 400 deg. C for 2, 4, and 8 min, respectively, to induce the nucleation and growth of Cu particles in TaN matrix and on film surface. Field emission scanning electron microscopy was applied to characterize Cu nanoparticles emerged on the surface of TaN-Cu thin films. The effects of annealing on the antiwear and antibacterial properties of these films were studied. The results reveal that annealing by RTA can cause Cu nanoparticles to form on the TaN surface. Consequently, the tribological behaviors, as well as the antibacterial behavior may vary depending on particle size, particle distribution, and total exposed Cu amount. For the samples with large Cu particles, the reduction of averaged friction and wear rate is obvious. Apparently, it is due to the smeared Cu particles adhered onto the wear tracks. This Cu layer may act as a solid lubricant. From the antibacterial testing results, it is found that both Cu particle size and total exposed Cu amount are critical in making short-term antibacterial effect. Overall, all the annealed TaN-Cu samples can reach >99% antibacterial efficiency in 24 h, with respect to uncoated Si substrate.

  5. Local structure order in Pd??Cu?Si?? liquid

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, G. Q.; Iowa State Univ., Ames, IA; Zhang, Y.; Sun, Y.; Shen, B.; Dong, F.; Wang, Z. Y.; Zhang, R. J.; Zheng, Y. X.; Kramer, M. J.; et al

    2015-02-05

    The short-range order (SRO) in Pd??Cu?Si?? liquid was studied by high energy x-ray diffraction and ab initio molecular dynamics (MD) simulations. The calculated pair correlation functions at different temperatures agree well with the experimental results. The partial pair correlation functions from ab intio MD simulations indicate that Si atoms prefer to be uniformly distributed while Cu atoms tend to aggregate. By performing structure analysis using Honeycutt-Andersen index, Voronoi tessellation, and atomic cluster alignment method, we show that the icosahedron and face-centered cubic SRO increase upon cooling. The dominant SRO is the Pd-centered Pd?Si? motif, namely the structure of which motifmoreis similar to the structure of Pd-centered clusters in the Pd?Si? crystal. The study further confirms the existence of trigonal prism capped with three half-octahedra that is reported as a structural unit in Pd-based amorphous alloys. The majority of Cu-centered clusters are icosahedra, suggesting that the presence of Cu is benefit to promote the glass forming ability.less

  6. Hydrogen isotope trapping in Al-Cu binary alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chao, Paul; Karnesky, Richard A.

    2016-02-03

    In this study, the trapping mechanisms for hydrogen isotopes in Al–X Cu (0.0 at. % < X < 3.5 at. %) alloys were investigated using thermal desorption spectroscopy (TDS), electrical conductivity, and differential scanning calorimetry. Constant heating rate TDS was used to determine microstructural trap energies and occupancies. In addition to the trapping states in pure Al reported in the literature (interstitial lattice sites, dislocations, and vacancies), a trap site due to Al–Cu intermetallic precipitates is observed. The binding energy of this precipitate trap is (18 ± 3) kJ•mol–1 (0.19 ± 0.03 eV). Typical occupancy of this trap is high;more » for Al–2.6 at. % Cu (a Cu composition comparable to that in AA2219) charged at 200 °C with 130 MPa D2 for 68 days, there is ca. there is 3.15×10–7 mol D bound to the precipitate trap per mol of Al, accounting for a third of the D in the charged sample.« less

  7. An in-situ phosphorus source for the synthesis of Cu3P and the subsequent conversion to Cu3PS4 nanoparticle clusters

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sheets, Erik J.; Stach, Eric A.; Yang, Wei -Chang; Balow, Robert B.; Wang, Yunjie; Walker, Bryce C.; Agrawal, Rakesh

    2015-09-20

    The search for alternative earth abundant semiconducting nanocrystals for sustainable energy applications has brought forth the need for nanoscale syntheses beyond bulk synthesis routes. Of particular interest are metal phosphides and derivative I-V-VI chalcogenides including copper phosphide (Cu3P) and copper thiophosphate (Cu3PS4). Herein, we report a one-pot, solution-based synthesis of Cu3P nanocrystals utilizing an in-situ phosphorus source: phosphorus pentasulfide (P2S5) in trioctylphosphine (TOP). By injecting this phosphorus source into a copper solution in oleylamine (OLA), uniform and size controlled Cu3P nanocrystals with a phosphorous-rich surface are synthesized. The subsequent reaction of the Cu3P nanocrystals with decomposing thiourea forms nanoscale Cu3PS4more » particles having p-type conductivity and an effective optical band gap of 2.36 eV.« less

  8. NO Chemisorption on Cu/SSZ-13: a Comparative Study from Infrared Spectroscopy and DFT Calculations

    SciTech Connect (OSTI)

    Zhang, Renqin; McEwen, Jean-Sabin; Kollar, Marton; Gao, Feng; Wang, Yilin; Szanyi, Janos; Peden, Charles HF

    2014-11-07

    The locations and energies of Cu ions in a Cu/SSZ-13 zeolite catalyst were investigated by density functional theory (DFT) calculations. For 'naked' Cu2+ ions (i.e., Cu2+ ions with no ligands in their coordination spheres other than zeolite lattice oxygen atoms), the more energetically favorable sites are within a 6-membered ring. However, with the presence of various adsorbates, the energy difference between 6- and 8-membered ring locations greatly diminishes. Specifically, Cu2+ ions are substantially stabilized by -OH ligands (as [CuII(OH)]+), making the extra-framework sites in an 8-membered ring energetically more favorable than 6-membered ring sites. Under fully dehydrated high vacuum conditions with different Si/Al and Cu/Al ratios, three chemisorbed NO species coexist upon exposure of NO to Cu/SSZ-13: NO+, Cu2+-NO and Cu+-NO. The relative signal intensities for these bands vary greatly with Si/Al ratios. The vibrational frequency of chemisorbed NO was found to be very sensitive to the location of Cu2+ ions. On the one hand, with the aid from DFT calculations, the nature for these vibrations can be assigned in detail. On the other hand, the relative intensities for various Cu2+-NO species provide a good measure of the nature of Cu2+ ions as functions of Si/Al and Cu/Al ratios and the presence of humidity. These new findings cast doubt on the generally accepted proposal that only Cu2+ ions located in 6-membered rings are catalytically active for NH3-SCR.

  9. Influence of Al/CuO reactive multilayer films additives on exploding foil initiator

    SciTech Connect (OSTI)

    Zhou Xiang; Shen Ruiqi; Ye Yinghua; Zhu Peng; Hu Yan; Wu Lizhi

    2011-11-01

    An investigation on the influence of Al/CuO reactive multilayer films (RMFs) additives on exploding foil initiator was performed in this paper. Cu film and Cu/Al/CuO RMFs were produced by using standard microsystem technology and RF magnetron sputtering technology, respectively. Scanning electron microscopy characterization revealed the distinct layer structure of the as-deposited Al/CuO RMFs. Differential scanning calorimetry was employed to ascertain the amount of heat released in the thermite reaction between Al films and CuO films, which was found to be 2024 J/g. Electrical explosion tests showed that 600 V was the most matching voltage for our set of apparatus. The explosion process of two types of films was observed by high speed camera and revealed that compared with Cu film, an extra distinct combustion phenomenon was detected with large numbers of product particles fiercely ejected to a distance of about six millimeters for Cu/Al/CuO RMFs. By using the atomic emission spectroscopy double line technique, the reaction temperature was determined to be about 6000-7000 K and 8000-9000 K for Cu film and Cu/Al/CuO RMFs, respectively. The piezoelectricity of polyvinylidene fluoride film was employed to measure the average velocity of the slapper accelerated by the explosion of the films. The average velocities of the slappers were calculated to be 381 m/s and 326 m/s for Cu film and Cu/Al/CuO RMFs, respectively, and some probable reasons were discussed with a few suggestions put forward for further work.

  10. Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O

    SciTech Connect (OSTI)

    Yang, X.; Kattel, S.; Xiong, K.; Mudiyanselage, K.; Rykov, S.; Senanayake, S. D.; Rodriguez, J. A.; Liu, P.; Stacchiola, D. J.; Chen, J. G.

    2015-07-17

    Direct propylene epoxidation by O2 is a challenging reaction because of the strong tendency for complete combustion. Results from the current study demonstrate the feasibility to tune the epoxidation selectivity by generating highly dispersed and stabilized Cu+ active sites in a TiCuOx mixed oxide. The TiCuOx surface anchors the key surface intermediate, oxametallacycle, leading to higher selectivity for epoxidation of propylene.

  11. Thermochemical and kinetic aspects of the sulfurization of Cu-Sb and Cu-Bi thin films

    SciTech Connect (OSTI)

    Colombara, Diego; Peter, Laurence M.; Rogers, Keith D.; Hutchings, Kyle

    2012-02-15

    CuSbS{sub 2} and Cu{sub 3}BiS{sub 3} are being investigated as part of a search for new absorber materials for photovoltaic devices. Thin films of these chalcogenides were produced by conversion of stacked and co-electroplated metal precursor layers in the presence of elemental sulfur vapour. Ex-situ XRD and SEM/EDS analyses of the processed samples were employed to study the reaction sequence with the aim of achieving compact layer morphologies. A new 'Time-Temperature-Reaction' (TTR) diagram and modified Pilling-Bedworth coefficients have been introduced for the description and interpretation of the reaction kinetics. For equal processing times, the minimum temperature required for CuSbS{sub 2} to appear is substantially lower than for Cu{sub 3}BiS{sub 3}, suggesting that interdiffusion across the interfaces between the binary sulfides is a key step in the formation of the ternary compounds. The effects of the heating rate and sulfur partial pressure on the phase evolution as well as the potential losses of Sb and Bi during the processes have been investigated experimentally and the results related to the equilibrium pressure diagrams obtained via thermochemical computation. - Graphical Abstract: Example of 3D plot showing the equilibrium pressure surfaces of species potentially escaping from chalcogenide films as a function of temperature and sulfur partial pressure. Bi{sub (g)}, Bi{sub 2(g)}, and BiS{sub (g)} are the gaseous species in equilibrium with solid Bi{sub 2}S{sub 3(s)} considered in this specific example. The pressure threshold plane corresponds to the pressure limit above which the elemental losses from 1 {mu}m thick films exceeds 10% of the original content per cm{sup 2} area of film and dm{sup 3} capacity of sulfurization furnace under static atmosphere conditions. The sulfurization temperature/sulfur partial pressure boundaries required to minimise the elemental losses below a given value can be easily read from the 2D projection of the intersection curves into the T-p{sub S2} plane. Highlights: Black-Right-Pointing-Triangle Sulfurization of Sb-Cu and Bi-Cu metal precursors for thin film PV applications. Black-Right-Pointing-Triangle Kinetics shows the rate determining step to be the interdiffusion of binary sulfides. Black-Right-Pointing-Triangle Phase evolution is consistent with Pilling-Bedworth coefficients of Cu, Sb and Bi. Black-Right-Pointing-Triangle Elemental losses can be minimised via the use of equilibrium pressure diagrams.

  12. Long-term leaching test of incinerator bottom ash: Evaluation of Cu partition

    SciTech Connect (OSTI)

    Lin, Cheng-Fang Wu, Chung-Hsin; Liu, Yen-Chiun

    2007-07-01

    Two types of leaching tests were performed on the bottom ash from municipal solid waste incinerators. A short-term batch test specified by the America Nuclear Society (ANS) and long-term column tests with acetic acid (pH 5.2) as leaching solution were used to evaluate copper leachability. The Cu leaching after the 5-d ANS test is about 1% of the original Cu content of 5300 mg/kg. Upon addition of a stabilizing agent, the Cu leaching quantity is reduced; the extent of reduction depends on the type of chemical used (phosphate, carbonate and sulfide). The 1.6% Na{sub 2}S addition showed negligible Cu leaching, and Na{sub 2}S was, therefore, used in subsequent column tests. The 30-d column test indicates a steady increase of Cu leaching amount with time and reaches about 1.5% of the original Cu content after 30 d. A 180-d column test further increased the Cu leaching to about 5.1% of the original Cu content, whereas no appreciable Cu leaching was found with the addition of 1.6% Na{sub 2}S. A sequential extraction was conducted on the raw ash, ash with the addition of Na{sub 2}S and the residue ash after 30 d of operation to characterize Cu affinity for different solid fractions. The data were used to evaluate the fate of Cu through these interactions.

  13. Effect of CNTs dispersion on the thermal and mechanical properties of Cu/CNTs nanocomposites

    SciTech Connect (OSTI)

    Muhsan, Ali Samer E-mail: faizahmad@petronas.com.my; Ahmad, Faiz E-mail: faizahmad@petronas.com.my; Yusoff, Puteri Sri Melor Megat Bt; Mohamed, Norani M.; Raza, M. Rafi

    2014-10-24

    Modified technique of metal injection molding (MIM) was used to fabricate multiwalled carbon nanotube (CNT) reinforced Cu nanocomposites. The effect of adding different amount of CNTs (0-10 vol.%) on the thermal and mechanical behaviour of the fabricated nanocomposites is presented. Scanning electron microscope analysis revealed homogenous dispersion of CNTs in Cu matrices at different CNTs contents. The experimentally measured thermal conductivities of Cu/CNTs nanocomposites showed extraordinary increase (76% higher than pure sintered Cu) with addition of 10 vol.% CNTs. As compared to the pure sintered Cu, increase in modulus of elasticity (Young's modulus) of Cu/CNTs nanocomposites sintered at 1050C for 2.5 h was measured to be 48%. However, in case of 7.5 vol.% CNTs, Young's modulus was increased significantly about 51% compared to that of pure sintered Cu.

  14. Utility of reactively sputtered CuN{sub x} films in spintronics devices

    SciTech Connect (OSTI)

    Fang Yeyu; Persson, J.; Zha, C.; Willman, J.; Miller, Casey W.; Aakerman, Johan

    2012-04-01

    We have studied nitrified copper (CuN{sub x}) thin films grown by reactive sputtering in the context of spintronic devices. The Ar-to-N{sub 2} flow ratio enables tunability of the electrical resistivity and surface roughness of the CuN{sub x} films, with the former increasing to nearly 20 times that of Cu, and the latter reduced to the atomic scale. Incorporating this into a Ta/CuN{sub x}/Ta seed stack for spin valves improves the current-in-plane (CIP) magnetoresistance; maximum magnetoresistance results with CuN{sub x} seed layer and Cu interlayer. Finally, finite element modeling results are presented that suggest the use of CuN{sub x} in nanocontact spin torque oscillators can enhance current densities by limiting the current spread through the device. This may positively impact threshold currents, power requirements, and device reliability.

  15. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 0 Average Electricity Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 94.0 74.2 169.2 124 54 98.1 38 1,485 0.65 1,172 450 Census

  16. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 3 Average Electricity Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 96.6 76.4 181.2 43 18 34.0 13 1,061 0.45 840 321 Census Region

  17. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 0 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 15.4 11.6 29.7 131 51 99.0 36 1,053 0.41 795 287 Census

  18. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 1 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 14.6 11.0 28.9 116 44 87.9 32 1,032 0.39 781 283 Census

  19. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 2 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 15.5 12.2 30.0 98 40 77.1 27 829 0.34 650 231 Census

  20. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 4 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 17.5 13.8 32.0 91 39 71.9 27 697 0.30 550 203 Census

  1. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 7 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 17.4 14.0 33.3 87 37 70.3 27 513 0.22 414 156 Census

  2. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 90 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 16.3 13.5 33.2 77 31 63.9 23 609 0.25 506 181 Census

  3. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 3 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 13.8 11.6 29.8 92 36 77.5 28 604 0.23 506 186 Census

  4. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 7 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures Total per Floor- per Square per per per Total Total space (1) Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 13.2 11.0 23.2 97 46 81.1 31 694 0.33 578 224 Census

  5. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires Fuel Oil/Kerosene, 2001 Average Fuel Oil/Kerosene Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 11.2 9.4 26.0 80 29 67.1 26 723 0.26

  6. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 0 Average LPG Residential Buildings Consumption Expenditures per Total per Square per per per Total Total Floorspace Building Foot per Household per Square per Household Households Number (billion (million (thousand Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) Btu) Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 7.7 7.4 12.1 47 29 45.6 16 379 0.23 365 125 Census Region and Division

  7. Residential Buildings Historical Publications reports, data and housing

    Gasoline and Diesel Fuel Update (EIA)

    questionnaires 0 Average of Major Energy Sources Residential Buildings Consumption Expenditures Total per per per per Total Total Floorspace per Square per Household per Square per Household Households Number (billion Building Foot Household Member Building Foot Household Member Characteristics (million) (million) sq. ft.) (million Btu) (thousand Btu) (million Btu) (million Btu) (dollars) (dollars) (dollars) (dollars) Total U.S. Households 81.6 65.4 142.5 143 65 114.1 41 1,156 0.53 926 330

  8. Comparative Study of the Defect Point Physics and Luminescence of the Kesterites Cu2ZnSnS4 and Cu2ZnSnSe4 and Chalcopyrite Cu(In,Ga)Se2: Preprint

    SciTech Connect (OSTI)

    Romero, M. J.; Repins, I.; Teeter, G.; Contreras, M.; Al-Jassim, M.; Noufi, R.

    2012-08-01

    In this contribution, we present a comparative study of the luminescence of the kesterites Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) and their related chalcopyrite Cu(In,Ga)Se2 (CIGSe). Luminescence spectroscopy suggests that the electronic properties of Zn-rich, Cu-poor kesterites (both CZTS and CZTSe) and Cu-poor CIGSe are dictated by fluctuations of the electrostatic and chemical potentials. The large redshift in the luminescence of grain boundaries in CIGSe, associated with the formation of a neutral barrier is clearly observed in CZTSe, and, to some extent, in CZTS. Kesterites can therefore replicate the fundamental electronic properties of CIGSe.

  9. Milestone M3FT-15OR0203112. Build redesigned HFIR rabbit capsules and make ready for insertion for irradiation in HFIR

    SciTech Connect (OSTI)

    Howard, Richard H; McDuffee, Joel Lee; Okuniewski, Maria A.

    2015-09-01

    This report details the fabrication and delivery of two Fuel Cycle Research and Development irradiation capsules (FCRP20 and FCRP03), with associated quality assurance documentation, to the High Flux Isotope Reactor. The capsules and documentation were delivered by September 30, 2015, thus meeting the deadline for milestone M3FT-15OR0203112. These irradiation experiments irradiate metal parallelepiped specimens that may consist of various compositions including uranium metal, steel, etc. This document contains a copy of the completed capsule fabrication request sheets, which detail all constituent components, pertinent drawings, etc., along with a detailed summary of the capsule assembly process performed by the Thermal Hydraulics and Irradiation Engineering Group (THIEG) in the Reactor and Nuclear Systems Division. A complete fabrication package record is maintained by THIEG and is available upon request.

  10. Solidification behavior and structure of Al-Cu alloy welds

    SciTech Connect (OSTI)

    Brooks, J.A.; Li, M.; Yang, N.C.Y.

    1997-09-01

    The microsegregation behavior of electron beam (EB) and gas tungsten arc (GTA) welds of Al-Cu alloys covering a range from 0.19 to 7.74 wt% Cu were characterized for dendrite core concentrations and fraction eutectic solidification. Although a single weld speed of 12.7 mm/sec was used, some differences were observed in the segregation behavior of the two weld types. The microsegregation behavior was also modeled using a finite differences technique considering dendrite tip and eutectic undercooling and solid state diffusion. Fairly good agreement was observed between measured and calculated segregation behavior although differences between the two weld types could not be completely accounted for. The concept of dendrite tip undercooling was used to explain the formation of a single through thickness centerline grain in the higher alloy content GTA welds.

  11. CuC1 thermochemical cycle for hydrogen production

    DOE Patents [OSTI]

    Fan, Qinbai; Liu, Renxuan

    2012-01-03

    An electrochemical cell for producing copper having a dense graphite anode electrode and a dense graphite cathode electrode disposed in a CuCl solution. An anion exchange membrane made of poly(ethylene vinyl alcohol) and polyethylenimine cross-linked with a cross-linking agent selected from the group consisting of acetone, formaldehyde, glyoxal, glutaraldehyde, and mixtures thereof is disposed between the two electrodes.

  12. Impedance analysis of MnCoCuO NTC ceramic

    SciTech Connect (OSTI)

    Song, S.G. . E-mail: song-ph0@wpmail.paisley.ac.uk; Ling, Z.; Placido, F.

    2005-07-12

    Impedance spectroscopy is often used to analyse the electrical properties of ceramic materials having high-resistive grain boundaries, such as ZnO and SrTiO{sub 3}. Fewer attempts have been made at using this technique for the analysis of inhomogeneous electronic ceramics consisting of grains with differing composition, such as those occurring in negative temperature coefficient (NTC) thermistors. In this study, we have attempted to adopt ac impedance spectroscopy together with other techniques to analyse an NTC thermistor ceramic material. An Mn, Co and Cu multielements transition metal oxide (MnCoCuO) ceramic was prepared by using homogeneous precipitation employing oxalic acid. This material displayed a typical NTC effect, showing an electrical resistance decrease with temperature when dc electrical measurement was performed. The ac impedance spectroscopy analysis showed that there were two peaks in impedance and conductance versus frequency plot. By using an alternative representation of impedance spectra Z'/f versus Z', three distinct relaxation frequency ranges were identified. They are believed to originate, respectively, from the electrode, phase 1 (rich-Cu phase) and phase 2 (poor-Cu phase) grains existing in this ceramic. SEM observation and EDX analysis clearly showed existence of two distinct phase grains. The resistance values were derived from phases 1 and 2 grains based on ac impedance data. The sum of the resistance values was in good agreement with that from dc measurement in the temperature range of 30-95 deg. C. The material constant, B, for the two phases was also calculated, giving 3100 and 3600 K for phases 1 and 2, respectively.

  13. Synthesis of BiPbSrCaCuO superconductor

    DOE Patents [OSTI]

    Hults, William L.; Kubat-Martin, Kimberly A.; Salazar, Kenneth V.; Phillips, David S.; Peterson, Dean E.

    1994-01-01

    A process and a precursor composition for preparing a lead-doped bismuth-strontium-calcium-copper oxide superconductor of the formula Bi.sub.a Pb.sub.b Sr.sub.c Ca.sub.d Cu.sub.e O.sub.f wherein a is from about 1.7 to about 1.9, b is from about 0.3 to about 0.45, c is from about 1.6 to about 2.2, d is from about 1.6 to about 2.2, e is from about 2.97 to about 3.2 and f is 10.+-.z by reacting a mixture of Bi.sub.4 Sr.sub.3 Ca.sub.3 Cu.sub.4 O.sub.16.+-.z, an alkaline earth metal cuprate, e.g., Sr.sub.9 Ca.sub.5 Cu.sub.24 O.sub.41, and an alkaline earth metal plumbate, e.g., Ca.sub.2-x Sr.sub.x PbO.sub.4 wherein x is about 0.5, is disclosed.

  14. Synthesis of BiPbSrCaCuO superconductor

    DOE Patents [OSTI]

    Hults, W.L.; Kubat-Martin, K.A.; Salazar, K.V.; Phillips, D.S.; Peterson, D.E.

    1994-04-05

    A process and a precursor composition for preparing a lead-doped bismuth-strontium-calcium-copper oxide superconductor of the formula Bi[sub a]Pb[sub b]Sr[sub c]Ca[sub d]Cu[sub e]O[sub f] wherein a is from about 1.7 to about 1.9, b is from about 0.3 to about 0.45, c is from about 1.6 to about 2.2, d is from about 1.6 to about 2.2, e is from about 2.97 to about 3.2 and f is 10[+-]z by reacting a mixture of Bi[sub 4]Sr[sub 3]Ca[sub 3]Cu[sub 4]O[sub 16[+-]z], an alkaline earth metal cuprate, e.g., Sr[sub 9]Ca[sub 5]Cu[sub 24]O[sub 41], and an alkaline earth metal plumbate, e.g., Ca[sub 2[minus]x]Sr[sub x]PbO[sub 4] wherein x is about 0.5, is disclosed.

  15. Effects of Cu Diffusion from ZnTe:Cu/Ti Contacts on Carrier Lifetime of CdS/CdTe Thin Film Solar Cells: Preprint

    SciTech Connect (OSTI)

    Gessert, T. A.; Metzger, W. K.; Asher, S. E.; Young, M. R.; Johnston, S.; Dhere, R. G.; Duda, A.

    2008-05-01

    We study the performance of CdS/CdTe thin film PV devices processed with a ZnTe:Cu/Ti contact to investigate how carrier lifetime in the CdTe layer is affected by Cu diffusion from the contact.

  16. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Hyun You; Liu, Ping

    2015-09-21

    Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film supported on Cu(111), CuTiOx/Cu(111), during CO oxidation was explored using density functional theory (DFT). The unique structural frame of CuTiOx is able to stabilize and isolate a single Cu+ site on the terrace, which is previously proposed active for CO oxidation. Furthermore, it is not the case, where the reaction via both the Langmuir–Hinshelwood (LH) and the Mars-van Krevelen (M-vK) mechanisms are hindered on such single Cu+ site. Upon the formation ofmore » step-edges, the synergy among Cuδ+ sites, TiOx matrix, and Cu(111) is able to catalyze the reaction well. Depending on temperatures and partial pressure of CO and O2, the surface structure varies, which determines the dominant mechanism. In accordance with our results, the Cuδ+ ion alone does not work well for CO oxidation in the form of single sites, while the synergy among multiple active sites is necessary to facilitate the reaction.« less

  17. Systematic study of azimuthal anisotropy in Cu + Cu and Au + Au collisions at √sNN = 62.4 and 200 GeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adare, A.

    2015-09-23

    We have studied the dependence of azimuthal anisotropy v2 for inclusive and identified charged hadrons in Au+Au and Cu+Cu collisions on collision energy, species, and centrality. The values of v2 as a function of transverse momentum pT and centrality in Au+Au collisions at √sNN=200 and 62.4 GeV are the same within uncertainties. However, in Cu+Cu collisions we observe a decrease in v2 values as the collision energy is reduced from 200 to 62.4 GeV. The decrease is larger in the more peripheral collisions. By examining both Au+Au and Cu+Cu collisions we find that v2 depends both on eccentricity and themore » number of participants, Npart. We observe that v2 divided by eccentricity (ε) monotonically increases with Npart and scales as N1/3part. Thus, the Cu+Cu data at 62.4 GeV falls below the other scaled v2 data. For identified hadrons, v2 divided by the number of constituent quarks nq is independent of hadron species as a function of transverse kinetic energy KET=mT–m between 0.1T/nq<1 GeV. Combining all of the above scaling and normalizations, we observe a near-universal scaling, with the exception of the Cu+Cu data at 62.4 GeV, of v2/(nq∙ε∙N1/3part) vs KET/nq for all measured particles.« less

  18. Oxygen-induced Y surface segregation in a CuPdY ternary alloy

    SciTech Connect (OSTI)

    Tafen, D. N.; Miller, J. B.; Dogan, O. N.; Baltrus, J. P.; Kondratyuk, P.

    2013-01-01

    We present a comprehensive theoretical and experimental study of the segregation behavior of the ternary alloy CuPdY in vacuum (i.e., the clean surface) and in the presence of oxygen. Theoretical prediction shows that for clean surface, yttrium will substitute first for Cu and then for Pd at the subsurface lattice site before segregating to the surface where it substitutes for Cu. XRD characterization of the surface of CuPdY indicates the presence of two major phases, B2 CuPd and Pd{sub 3}Y. In the presence of adsorbed oxygen, theory predicts that Y preferentially occupies surface sites due to its stronger oxygen affinity compared to Cu and Pd. XPS experiments confirm the computational results in the adsorbed oxygen case, showing that surface segregation of yttrium is induced by the formation of Y-oxides at the top-surface of the alloy.

  19. Adsorbate-driven morphological changes on Cu(111) nano-pits

    SciTech Connect (OSTI)

    Mudiyanselage, K.; Xu, F.; Hoffmann, F. M.; Hrbek, J.; Waluyo, I.; Boscoboinik, J. A.; Stacchiola, D. J.

    2015-01-01

    Adsorbate-driven morphological changes of pitted-Cu(111) surfaces have been investigated following the adsorption and desorption of CO and H. The morphology of the pitted-Cu(111) surfaces, prepared by Ar+ sputtering, exposed a few atomic layers deep nested hexagonal pits of diameters from 8 to 38 nm with steep step bundles. The roughness of pitted-Cu(111) surfaces can be healed by heating to 450-500 K in vacuum. Adsorption of CO on the pitted-Cu(111) surface leads to two infrared peaks at 2089-2090 and 2101-2105 cm-1 for CO adsorbed on under-coordinated sites in addition to the peak at 2071 cm-1 for CO adsorbed on atop sites of the close-packed Cu(111) surface. CO adsorbed on under-coordinated sites is thermally more stable than that of atop Cu(111) sites. Annealing of the CO-covered surface from 100 to 300 K leads to minor changes of the surface morphology. In contrast, annealing of a H covered surface to 300 K creates a smooth Cu(111) surface as deduced from infrared data of adsorbed CO and scanning tunnelling microscopy (STM) imaging. The observation of significant adsorbate-driven morphological changes with H is attributed to its stronger modification of the Cu(111) surface by the formation of a sub-surface hydride with a hexagonal structure, which relaxes into the healed Cu(111) surface upon hydrogen desorption. These morphological changes occur ~150 K below the temperature required for healing of the pitted-Cu(111) surface by annealing in vacuum. In contrast, the adsorption of CO, which only interacts with the top-most Cu layer and desorbs by 160 K, does not significantly change the morphology of the pitted-Cu(111) surface.

  20. Adsorbate-driven morphological changes on Cu(111) nano-pits

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mudiyanselage, K.; Xu, F.; Hoffmann, F. M.; Hrbek, J.; Waluyo, I.; Boscoboinik, J. A.; Stacchiola, D. J.

    2014-12-09

    Adsorbate-driven morphological changes of pitted-Cu(111) surfaces have been investigated following the adsorption and desorption of CO and H. The morphology of the pitted-Cu(111) surfaces, prepared by Ar+ sputtering, exposed a few atomic layers deep nested hexagonal pits of diameters from 8 to 38 nm with steep step bundles. The roughness of pitted-Cu(111) surfaces can be healed by heating to 450-500 K in vacuum. Adsorption of CO on the pitted-Cu(111) surface leads to two infrared peaks at 2089-2090 and 2101-2105 cm-1 for CO adsorbed on under-coordinated sites in addition to the peak at 2071 cm-1 for CO adsorbed on atop sitesmore » of the close-packed Cu(111) surface. CO adsorbed on under-coordinated sites is thermally more stable than that of atop Cu(111) sites. Annealing of the CO-covered surface from 100 to 300 K leads to minor changes of the surface morphology. In contrast, annealing of a H covered surface to 300 K creates a smooth Cu(111) surface as deduced from infrared data of adsorbed CO and scanning tunnelling microscopy (STM) imaging. The observation of significant adsorbate-driven morphological changes with H is attributed to its stronger modification of the Cu(111) surface by the formation of a sub-surface hydride with a hexagonal structure, which relaxes into the healed Cu(111) surface upon hydrogen desorption. These morphological changes occur ~150 K below the temperature required for healing of the pitted-Cu(111) surface by annealing in vacuum. In contrast, the adsorption of CO, which only interacts with the top-most Cu layer and desorbs by 160 K, does not significantly change the morphology of the pitted-Cu(111) surface.« less

  1. Adsorbate-driven morphological changes on Cu(111) nano-pits

    SciTech Connect (OSTI)

    Mudiyanselage, K.; Xu, F.; Hoffmann, F. M.; Hrbek, J.; Waluyo, I.; Boscoboinik, J. A.; Stacchiola, D. J.

    2014-12-09

    Adsorbate-driven morphological changes of pitted-Cu(111) surfaces have been investigated following the adsorption and desorption of CO and H. The morphology of the pitted-Cu(111) surfaces, prepared by Ar+ sputtering, exposed a few atomic layers deep nested hexagonal pits of diameters from 8 to 38 nm with steep step bundles. The roughness of pitted-Cu(111) surfaces can be healed by heating to 450-500 K in vacuum. Adsorption of CO on the pitted-Cu(111) surface leads to two infrared peaks at 2089-2090 and 2101-2105 cm-1 for CO adsorbed on under-coordinated sites in addition to the peak at 2071 cm-1 for CO adsorbed on atop sites of the close-packed Cu(111) surface. CO adsorbed on under-coordinated sites is thermally more stable than that of atop Cu(111) sites. Annealing of the CO-covered surface from 100 to 300 K leads to minor changes of the surface morphology. In contrast, annealing of a H covered surface to 300 K creates a smooth Cu(111) surface as deduced from infrared data of adsorbed CO and scanning tunnelling microscopy (STM) imaging. The observation of significant adsorbate-driven morphological changes with H is attributed to its stronger modification of the Cu(111) surface by the formation of a sub-surface hydride with a hexagonal structure, which relaxes into the healed Cu(111) surface upon hydrogen desorption. These morphological changes occur ~150 K below the temperature required for healing of the pitted-Cu(111) surface by annealing in vacuum. In contrast, the adsorption of CO, which only interacts with the top-most Cu layer and desorbs by 160 K, does not significantly change the morphology of the pitted-Cu(111) surface.

  2. Mitigation of the Impact of Pt Contamination on Cu-Zeolite SCR Catalyst

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance | Department of Energy the Impact of Pt Contamination on Cu-Zeolite SCR Catalyst Performance Mitigation of the Impact of Pt Contamination on Cu-Zeolite SCR Catalyst Performance Investigates operating conditions under which PGM elements get volatilized and transferred onto the downstream SCR catalyst, resulting in loss of NOx reduction performance PDF icon deer12_chen.pdf More Documents & Publications The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst Function

  3. Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyst | Department of Energy Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_henry.pdf More Documents & Publications The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst Vehicle Technologies Office Merit

  4. Understanding the Deactivation Mechanisms of Cu/Zeolite SCR Catalysts in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Application | Department of Energy Deactivation Mechanisms of Cu/Zeolite SCR Catalysts in Diesel Application Understanding the Deactivation Mechanisms of Cu/Zeolite SCR Catalysts in Diesel Application To understand the durability of Cu/Zeolite urea-SCR catalysts in diesel applications, the effects of engine and lab aging on catalyst reactivity and material properties were investigated. PDF icon deer08_cheng.pdf More Documents & Publications Deactivation Mechanisms of Base

  5. Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System | Department of Energy Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System Sulfur Effect and Performance Recovery of a DOC + CSF + Cu-Zeolite SCR System effect and performance recovery studies at system level with typical diesel emission control consisting of diesel oxidation catalyst, catalyzed soot filter, and selective catalytic reduction PDF icon deer11_tang.pdf More Documents & Publications Investigation of Sulfur Deactivation on Cu/Zeolite SCR

  6. Supported Au-CuO Catalysts for Low Temperature CO Oxidation | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Supported Au-CuO Catalysts for Low Temperature CO Oxidation Supported Au-CuO Catalysts for Low Temperature CO Oxidation Catalytic properties of Au-CuOx/SiO2 are investigated in removing pollutants from simulated automotive exhaust to meet an increasing demand for high emissions control at low temperatures. PDF icon p-02_bauer.pdf More Documents & Publications Low Temperature Emission Control Vehicle Technologies Office Merit Review 2014: Low Temperature Emission Control to Enable

  7. Method of fabricating high-efficiency Cu(In,Ga)(Se,S){sub 2} thin films for solar cells

    DOE Patents [OSTI]

    Noufi, R.; Gabor, A.M.; Tuttle, J.R.; Tennant, A.L.; Contreras, M.A.; Albin, D.S.; Carapella, J.J.

    1995-08-15

    A process for producing a slightly Cu-poor thin film of Cu(In,Ga)(Se,S){sub 2} comprises depositing a first layer of (In,Ga){sub x} (Se,S){sub y} followed by depositing just enough Cu+(Se,S) or Cu{sub x} (Se,S) to produce the desired slightly Cu-poor material. In a variation, most, but not all, (about 90 to 99%) of the (In,Ga){sub x} (Se,S){sub y} is deposited first, followed by deposition of all the Cu+(Se,S) or Cu{sub x} (Se,S) to go near stoichiometric, possibly or even preferably slightly Cu-rich, and then in turn followed by deposition of the remainder (about 1 to 10%) of the (In,Ga){sub x} (Se,S){sub y} to end with a slightly Cu-poor composition. In yet another variation, a small portion (about 1 to 10%) of the (In,Ga){sub x} (Se,S){sub y} is first deposited as a seed layer, followed by deposition of all of the Cu+(Se,S) or Cu{sub x} (Se,S) to make a very Cu-rich mixture, and then followed deposition of the remainder of the (In,Ga){sub x} (Se,S){sub y} to go slightly Cu-poor in the final Cu(In,Ga)(Se,S){sub 2} thin film. 5 figs.

  8. Method of fabricating high-efficiency Cu(In,Ga)(SeS).sub.2 thin films for solar cells

    DOE Patents [OSTI]

    Noufi, Rommel; Gabor, Andrew M.; Tuttle, John R.; Tennant, Andrew L.; Contreras, Miguel A.; Albin, David S.; Carapella, Jeffrey J.

    1995-01-01

    A process for producing a slightly Cu-poor thin film of Cu(In,Ga)(Se,S).sub.2 comprises depositing a first layer of (In,Ga).sub.x (Se,S).sub.y followed by depositing just enough Cu+(Se,S) or Cu.sub.x (Se,S) to produce the desired slightly Cu-poor material. In a variation, most, but not all, (about 90 to 99%) of the (In,Ga).sub.x (Se,S).sub.y is deposited first, followed by deposition of all the Cu+(Se,S) or Cu.sub.x (Se,S) to go near stoichiometric, possibly or even preferably slightly Cu-rich, and then in turn followed by deposition of the remainder (about 1 to 10%) of the (In,Ga).sub.x (Se,S).sub.y to end with a slightly Cu-poor composition. In yet another variation, a small portion (about 1 to 10%) of the (In,Ga).sub.x (Se,S).sub.y is first deposited as a seed layer, followed by deposition of all of the Cu+(Se,S) or Cu.sub.x (Se,S) to make a very Cu-rich mixture, and then followed deposition of the remainder of the (In,Ga).sub.x (Se,S).sub.y to go slightly Cu-poor in the final Cu(In,Ga)(Se,S).sub.2 thin film.

  9. In-situ surface composition measurements of CuGaSe{sub 2} thin films

    SciTech Connect (OSTI)

    Fons, P.; Yamada, A.; Niki, S.; Oyanagi, H.

    1998-12-31

    Two CuGaSe{sub 2} films were grown by molecular beam epitaxy onto GaAs (001) substrates with varying Cu/Ga flux ratios under Se overpressure conditions. Growth was interrupted at predetermined times and the surface composition was measured using Auger electron spectroscopy after which growth was continued. After growth, the film composition was analyzed using voltage dependent electron microprobe spectroscopy. Film structure and morphology were also analyzed using x-ray diffraction and atomic force microscopy. The film with a Cu/Ga ratio larger than unity showed evidence of surface segregation of a second Cu-rich phase with a Cu/Se composition ratio slightly greater than unity. A second CuGaSe{sub 2} film with a Cu/Ga ratio of less than unity showed no change in surface composition with time and was also consistent with bulk composition measurements. Diffraction measurements indicated a high concentration of twins as well as the presence of domains with mixed c and a axes in the Ga-rich film. The Cu-rich films by contrast were single domain and had a narrower mosaics. High sensitivity scans along the [001] reciprocal axis did not exhibit any new peaks not attributable to either the substrate or the CuGaSe{sub 2} thin film.

  10. Deactivation Mechanism of Cu/Zeolite SCR Catalyst Due to Reductive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Deactivation Mechanisms of CuZeolite SCR Catalysts in Diesel Application Deactivation Mechanisms of Base MetalZeolite Urea Selective Catalytic Reduction Materials...

  11. Structural, optical and ethanol sensing properties of Cu-doped SnO{sub 2} nanowires

    SciTech Connect (OSTI)

    Johari, Anima Sharma, Manish; Johari, Anoopshi; Bhatnagar, M. C.

    2014-04-24

    In present work, one-dimensional nanostructure of Cu-doped Tin oxide (SnO{sub 2}) was synthesized by using thermal evaporation method in a tubular furnace under Nitrogen (N{sub 2}) ambience. The growth was carried out at atmospheric pressure. SEM and TEM images reveal the growth of wire-like nanostructures of Cu-doped SnO{sub 2} on Si substrate. The XRD analysis confirms that the synthesized SnO{sub 2} nanowires have tetragonal rutile structure with polycrystalline nature and X-ray diffraction pattern also showed that Cu gets incorporated into the SnO{sub 2} lattice. EDX spectra confirm the doping of Cu into SnO{sub 2} nanowires and atomic fraction of Cu in nanowires is ? 0.5 at%. The Vapor Liquid Solid (VLS) growth mechanism for Cu-doped SnO{sub 2} nanowires was also confirmed by EDX spectra. The optical properties of as grown Cu-doped SnO{sub 2} nanowires were studied by using UV-vis spectra which concludes the band gap of about 3.7 eV. As synthesized single Cu-doped SnO{sub 2} nanowire based gas sensor exhibit relatively good performance to ethanol gas. This sensing behaviour offers a suitable application of the Cu-doped SnO{sub 2} nanowire sensor for detection of ethanol gas.

  12. Method of forming superconducting Tl-Ba-Ca-Cu-O films

    DOE Patents [OSTI]

    Wessels, Bruce W. (Wilmette, IL); Marks, Tobin J. (Evanston, IL); Richeson, Darrin S. (Evanston, IL); Tonge, Lauren M. (Sanford, MI); Zhang, Jiming (Chicago, IL)

    1993-01-01

    A method of forming a superconducting Tl-Ba-Ca-Cu-O film is disclosed, which comprises depositing a Ba-Ca-Cu-O film on a substrate by MOCVD, annealing the deposited film and heat-treating the annealed film in a closed circular vessel with TlBa.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x and cooling to form said superconducting film of TlO.sub.m Ba.sub.2 Ca.sub.n-1 Cu.sub.n O.sub.2n+2, wherein m=1,2 and n=1,2,3.

  13. Microstructure and Corrosion Behavior of the Cu-Pd-X Ternary...

    Office of Scientific and Technical Information (OSTI)

    Microstructure and Corrosion Behavior of the Cu-Pd-X Ternary Alloys for Hydrogen Separation Membranes Citation Details In-Document Search Title: Microstructure and Corrosion...

  14. Earth-Abundant Cu-based Chalcogenide Materials as Photovoltaic Absorbers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photovoltaic (PV) conversion is demonstrated for the first time in Cu 3 PSe 4 , a member of the Cu 3 MCh 4 (Ch = S,Se; M = P, As, Sb) materials family, identified using the inverse design method as absorber candidates that have stronger solar absorption than CuInSe 2 . Significance and Impact The Cu 3 MCh 4 materials family provides a unique opportunity for addressing needs in single- and multijunction cells for both PV and photo-electrochemical water splitting with a single, inexpensive set of

  15. Recrystallization method to selenization of thin-film Cu(In,Ga)Se.sub.2 for semiconductor device applications

    DOE Patents [OSTI]

    Albin, David S. (Denver, CO); Carapella, Jeffrey J. (Evergreen, CO); Tuttle, John R. (Denver, CO); Contreras, Miguel A. (Golden, CO); Gabor, Andrew M. (Boulder, CO); Noufi, Rommel (Golden, CO); Tennant, Andrew L. (Denver, CO)

    1995-07-25

    A process for fabricating slightly Cu-poor thin-films of Cu(In,Ga)Se.sub.2 on a substrate for semiconductor device applications includes the steps of forming initially a slightly Cu-rich, phase separated, mixture of Cu(In,Ga)Se.sub.2 :Cu.sub.x Se on the substrate in solid form followed by exposure of the Cu(In,Ga)Se.sub.2 :Cu.sub.x Se solid mixture to an overpressure of Se vapor and (In,Ga) vapor for deposition on the Cu(In,Ga)Se.sub.2 :Cu.sub.x Se solid mixture while simultaneously increasing the temperature of the solid mixture toward a recrystallization temperature (about 550.degree. C.) at which Cu(In,Ga)Se.sub.2 is solid and Cu.sub.x Se is liquid. The (In,Ga) flux is terminated while the Se overpressure flux and the recrystallization temperature are maintained to recrystallize the Cu.sub.x Se with the (In, Ga) that was deposited during the temperature transition and with the Se vapor to form the thin-film of slightly Cu-poor Cu.sub.x (In,Ga).sub.y Se.sub.z. The initial Cu-rich, phase separated large grain mixture of Cu(In,Ga)Se.sub.2 :Cu.sub.x Se can be made by sequentially depositing or co-depositing the metal precursors, Cu and (In, Ga), on the substrate at room temperature, ramping up the thin-film temperature in the presence of Se overpressure to a moderate anneal temperature (about 450.degree. C.) and holding that temperature and the Se overpressure for an annealing period. A nonselenizing, low temperature anneal at about 100.degree. C. can also be used to homogenize the precursors on the substrates before the selenizing, moderate temperature anneal.

  16. Low thermal budget photonic processing of highly conductive Cu interconnects based on CuO nanoinks. Potential for flexible printed electronics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rager, Matthew S.; Aytug, Tolga; Veith, Gabriel M.; Joshi, Pooran C.

    2015-12-31

    The developing field of printed electronics nanoparticle based inks such as CuO show great promise as a low-cost alternative to other metal-based counterparts (e.g., silver). In particular, CuO inks significantly eliminate the issue of particle oxidation, before and during the sintering process, that is prevalent in Cu-based formulations. We report here the scalable and low-thermal budget photonic fabrication of Cu interconnects employing a roll-to-roll compatible pulse-thermal-processing (PTP) technique that enables phase reduction and subsequent sintering of inkjet-printed CuO patterns onto flexible polymer templates. Detailed investigations of curing and sintering conditions were performed to understand the impact of PTP system conditionsmore » on the electrical performance of the Cu patterns. Specifically, the impact of energy and power of photonic pulses on print conductivity was systematically studied by varying the following key processing parameters: pulse intensity, duration and sequence. Through optimization of such parameters, highly conductive prints in < 1 s with resistivity values as low as 100 n m has been achieved. We also observed that the introduction of an initial ink-drying step in ambient atmosphere, after the printing and before sintering, leads to significant improvements in mechanical integrity and electrical performance of the printed Cu patterns. Moreover, the viability of CuO reactive inks, coupled with the PTP technology and pre ink-drying protocols, has also been demonstrated for the additive integration of a low-cost Cu temperature sensor onto a flexible polymer substrate.« less

  17. Cu-Ni-Fe anodes having improved microstructure

    DOE Patents [OSTI]

    Bergsma, S. Craig; Brown, Craig W.

    2004-04-20

    A method of producing aluminum in a low temperature electrolytic cell containing alumina dissolved in an electrolyte. The method comprises the steps of providing a molten electrolyte having alumina dissolved therein in an electrolytic cell containing the electrolyte. A non-consumable anode and cathode is disposed in the electrolyte, the anode comprised of Cu--Ni--Fe alloys having single metallurgical phase. Electric current is passed from the anode, through the electrolyte to the cathode thereby depositing aluminum on the cathode, and molten aluminum is collected from the cathode.

  18. La??xSrxCuO? superconductor nanowire devices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Litombe, N. E.; Bollinger, A. T.; Hoffman, J. E.; Bozovic, I.

    2014-07-02

    La??xSrxCuO? nanowire devices have been fabricated and characterized using electrical transport measurements. Nanowires with widths down to 80 nm are patterned using high-resolution electron beam lithography. However, the narrowest nanowires show incomplete superconducting transitions with some residual resistance at T = 4 K. Here, we report on refinement of the fabrication process to achieve narrower nanowire devices with complete superconducting transitions, opening the path to the study of novel physics arising from dimension-limited superconductivity on the nanoscale.

  19. Effect of gamma irradiation on electrical properties of Cu nanowires

    SciTech Connect (OSTI)

    Rana, Pallavi Gehlawat, Devender Chauhan, R. P.

    2014-04-24

    Metallic nanowires are of great interest due to their unique electrical, optical, chemical and magnetic properties. Characterization and explanations of electronic properties of nanowires are extremely important due to their potential applications in the field of nanoelectronics and optoelectronics. In the present study, we synthesized the copper nanowires of different diameters (80nm, 100nm and 200nm) and exposed them with gamma rays of 100 KGy and 150 KGy doses. The I-V characteristics of different diameter of Cu nanowires before and after the irradiation were recorded.

  20. Fermi surface measurements in YBa sub 2 Cu sub 3 O sub 7-x and La sub 1. 874 Sr sub. 126 CuO sub 4

    SciTech Connect (OSTI)

    Howell, R.H.; Sterne, P.A.; Solal, F.; Fluss, M.J. ); Haghighi, H.; Kaiser, J.H.; Rayner, S.L.; West, R.N. ); Liu, J.Z; Shelton, R. ); Kojima, H. ); Kitazawa, K. )

    1991-06-25

    We report new, ultra high precision measurements of the electron-positron momentum spectra of YBa{sub 2}Cu{sub 3}O{sub 7-x} and La{sub 1.874}Sr{sub 126}CuO{sub 4}. The YBCO experiments were performed on twin free, single crystals and show discontinuities with the symmetry of the Fermi surface of the CuO chain bands. Conduction band and underlying features in LSCO share the same symmetry and can only be separated with the aid of LDA calculations. 5 refs., 3 figs.

  1. Initial activity of reduced chromia/alumina catalyst in n-butane dehydrogenation monitored by on-line FT-IR gas analysis

    SciTech Connect (OSTI)

    Hakuli, A.; Kytoekivi, A.; Suntola, T.

    1996-06-01

    The initial activity of chromia/alumina catalyst (13 wt% Cr) in n-butane dehydrogenation was studied in a flow reactor at 853 K. The initial activity was determined by on-line FT-IR gas analysis, which enabled sampling of the gaseous product mixture at a time resolution of seconds. The catalysts were processed in repeated cycles of oxidation, reduction, and dehydrogenation using n-butane, methane, hydrogen, or carbon monoxide as reducing agents. With n-butane, methane, and hydrogen and dehydrogenation activity was associated with Cr{sup 3+} species apparently formed in the reduction of high-valence Cr species. The catalyst reduced with carbon monoxide at 853 K showed poor initial selectivity for butenes and, relative to the other catalysts. Simultaneous data relating the initial activity, coke content, and some of the physicochemical properties of the catalyst indicated that the surfaces of all catalysts were modified to some extent by the successive reaction cycles. 33 refs., 7 figs., 2 tabs.

  2. Dynamics of Propane in Silica Mesopores Formed upon PropyleneHydrogenation over Pt Nanoparticles by Time-Resolved FT-IRSpectroscopy

    SciTech Connect (OSTI)

    Waslylenko, Walter; Frei, Heinz

    2007-01-31

    Propylene hydrogenation over Pt nanoparticles supported onmesoporous silica type SBA-15 was monitored by time-resolved FT-IRspectroscopy at 23 ms resolution using short propylene gas pulses thatjoined a continuous flow of hydrogen in N2 (1 atm total pressure).Experiments were conducted in the temperature range 323-413 K. Propanewas formed within 100 milliseconds or faster. The CH stretching regionrevealed distinct bands for propane molecules emerging inside thenanoscale channels of the silica support. Spectral analysis gave thedistribution of the propane product between support and surrounding gasphase as function of time. Kinetic analysis showed that the escape ofpropane molecules from the channels occurred within hundreds ofmilliseconds (3.1 + 0.4 s-1 at 383 K). A steady state distribution ofpropane between gas phase and mesoporous support is established as theproduct is swept from the catalyst zone by the continuous flow ofhydrogen co-reactant. This is the first direct spectroscopic observationof emerging products of heterogeneous catalysis on nanoporous supportsunder reaction conditions.

  3. Shock-induced consolidation and spallation of Cu nanopowders

    SciTech Connect (OSTI)

    Huang, L.; Han, W. Z.; Luo, S. N.; An, Q.; Goddard, W. A. III

    2012-01-01

    A useful synthesis technique, shock synthesis of bulk nanomaterials from nanopowders, is explored here with molecular dynamics simulations. We choose nanoporous Cu ({approx}11 nm in grain size and 6% porosity) as a representative system, and perform consolidation and spallation simulations. The spallation simulations characterize the consolidated nanopowders in terms of spall strength and damage mechanisms. The impactor is full density Cu, and the impact velocity (u{sub i}) ranges from 0.2 to 2 km s{sup -1}. We present detailed analysis of consolidation and spallation processes, including atomic-level structure and wave propagation features. The critical values of u{sub i} are identified for the onset plasticity at the contact points (0.2 km s{sup -1}) and complete void collapse (0.5 km s{sup -1}). Void collapse involves dislocations, lattice rotation, shearing/friction, heating, and microkinetic energy. Plasticity initiated at the contact points and its propagation play a key role in void collapse at low u{sub i}, while the pronounced, grain-wise deformation may contribute as well at high u{sub i}. The grain structure gives rise to nonplanar shock response at nanometer scales. Bulk nanomaterials from ultrafine nanopowders ({approx}10 nm) can be synthesized with shock waves. For spallation, grain boundary (GB) or GB triple junction damage prevails, while we also observe intragranular voids as a result of GB plasticity.

  4. J/psi production at high transverse momenta in p+p and Cu+Cu collisions at sqrt sNN = 200 GeV

    SciTech Connect (OSTI)

    STAR Collaboration; Abelev, B. I.

    2009-10-27

    The STAR collaboration at RHIC presents measurements of J/{psi} {yields} e{sup +}e{sup -} at mid-rapidity and high transverse momentum (p{sub T} > 5 GeV/c) in p+p and central Cu+Cu collisions at {radical}sNN = 200 GeV. The inclusive J/{psi} production cross section for Cu+Cu collisions is found to be consistent at high p{sub T} with the binary collision-scaled cross section for p+p collisions, in contrast to previous measurements at lower p{sub T}, where a suppression of J/{psi} production is observed relative to the expectation from binary scaling. Azimuthal correlations of J/{psi} with charged hadrons in p+p collisions provide an estimate of the contribution of B-meson decays to J/{psi} production of 13% {+-} 5%.

  5. Ultrasound-assisted synthesis of CuO nanostructures templated by cotton fibers

    SciTech Connect (OSTI)

    Zou, Yunling; Li, Yan; Guo, Ying; Zhou, Qingjun; An, Dongmin

    2012-11-15

    Highlights: ? Flower-like and corn-like CuO nanostructures were synthesized by a simple method. ? Cotton fibers purchased from commercially are used as template. ? The concentration of Cu(NO{sub 3}){sub 2} solution is an important parameter. -- Abstract: Flower-like and corn-like CuO nanostructures composed of CuO nanoparticles were successfully synthesized via ultrasound-assisted template method, respectively, by controlling the initial concentration of Cu(NO{sub 3}){sub 2} solution. Here, cotton fibers were used as template agent. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), field-emission scanning electron microscopy (FE-SEM) and energy-dispersive spectroscopy (EDS), respectively. The results demonstrated that the initial concentration of Cu(NO{sub 3}){sub 2} solution was an important parameter for determining whether CuO nanoparticles assembled into flower-like structures or corn-like structures. The mechanism of forming different nanostructures of CuO was discussed.

  6. Development of a Low Cost Insulated Foil Substrate for Cu(InGaSe)2 Photovoltaics

    SciTech Connect (OSTI)

    ERTEN ESER

    2012-01-22

    The project validated the use of stainless steel flexible substrate coated with silicone-based resin dielectric, developed by Dow Corning Corporation, for Cu(InGa)Se2 based photovoltaics. The projects driving force was the high performance of Cu(InGa)Se2 based photovoltaics coupled with potential cost reduction that could be achieved with dielectric coated SS web substrate.

  7. Electronic and structural properties at the interface between CuPc and graphene

    SciTech Connect (OSTI)

    Tao, Yongsheng; Mao, Hongying; He, Pimo

    2015-01-07

    The electronic and structural properties at Copper phthalocyanine (CuPc)/graphene have been studied using ultraviolet photoemission spectroscopy and first-principles density function theory calculation. The five emission features ?, ?, ?, ?, and ? originating from the CuPc molecules locate at 1.48, 3.66, 4.98, 6.90, and 9.04?eV, respectively. These features shift in binding energy with the increasing CuPc coverage. The feature ? is mostly deriving from Cu 3d orbital with some contributions from C 2p orbital. Further theoretical calculation indicates that the adsorption of CuPc on a top site is the most favorable configuration, and the separation between the adsorbate and graphene is about 3.47?. According to the density of states before and after CuPc adsorption, the LUMO of CuPc is slightly occupied, while the Dirac point of graphene slightly shift towards higher energy, suggesting that a small amount of electron transfer from graphene to CuPc upon contact.

  8. Interaction of CuS and sulfur in Li-S battery system

    SciTech Connect (OSTI)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, under a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.

  9. Preferential Cu precipitation at extended defects in bcc Fe: An atomistic study

    SciTech Connect (OSTI)

    Zhang, Yongfeng; Millett, Paul C.; Tonks, Michael R.; Bai, Xian-Ming; Biner, S. Bulent

    2015-04-01

    As a starting point to understand Cu precipitation in RPV alloys, molecular dynamics and Metropolis Monte-Carlo simulations are carried out to study the effect of lattice defects on Cu precipitation by taking Fe-Cu system as a model alloy. Molecular dynamics simulations show that owing to the high heat of mixing and positive size mismatch, Cu is attracted by vacancy type defects such as vacancies and voids, and tensile stress fields. In accordance, preferential precipitation of Cu is observed in Metropolis Monte-Carlo simulations at dislocations, prismatic loops and voids. The interaction of Cu with a stress field, e.g., that associated with a dislocation or a prismatic loop, is dominated by elastic effect and can be well described by the linear-elasticity theory. For prismatic loops, the attraction to Cu is found to be size-dependent with opposite trends displayed by vacancy and interstitial loops. The size-dependences can be explained by considering the stress fields produced by these loops. The current results will be useful for understanding the effect of neutron irradiation on Cu precipitation in reactor-pressure-vessel steels.

  10. Ab-initio study of donor-acceptor codoping for n-type CuO

    SciTech Connect (OSTI)

    Peng, Yuan; Wang, Junling, E-mail: jlwang@ntu.edu.sg [School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Zheng, Jianwei [Institute of High Performance Computing, 1 Fusionopolis Way, #16-16 Connexis, Singapore 138632 (Singapore); Wu, Ping [Engineering Product Development, Singapore University of Technology and Design, 20 Dover Drive, Singapore 138682 (Singapore)

    2014-10-28

    Single n-type dopant in CuO has either a deep donor level or limited solubility, inefficient in generating free electrons. We have performed ab-initio study of the donor-acceptor codoping to obtain n-type CuO. Our results show that N codoping can slightly improve the donor level of Zr and In by forming shallower n-type complexes (Zr{sub Cu}-N{sub O} and 2In{sub Cu}-N{sub O}), but their formation energies are too high to be realized in experiments. However, Li codoping with Al and Ga is found to be relatively easy to achieve. 2Al{sub Cu}-Li{sub Cu} and 2Ga{sub Cu}-Li{sub Cu} have shallower donor levels than single Al and Ga by 0.14?eV and 0.08?eV, respectively, and their formation energies are reasonably low to act as efficient codopants. Moreover, Li codoping with both Al and Ga produce an empty impurity band just below the host conduction band minimum, which may reduce the donor ionization energy at high codoping concentrations.

  11. Growth and magnetic property of antiperovskite manganese nitride films doped with Cu by molecular beam epitaxy

    SciTech Connect (OSTI)

    Yu, Fengmei; Ren, Lizhu; Meng, Meng; Wang, Yunjia; Yang, Mei; Wu, Shuxiang; Li, Shuwei

    2014-04-07

    Manganese nitrides thin films on MgO (100) substrates with and without Cu-doping have been fabricated by plasma assisted molecular beam epitaxy. Antiperovskite compounds Mn{sub 3.6}Cu{sub 0.4}N have been grown in the case of Cu-doping, and the pure Mn{sub 3}N{sub 2} single crystal has been obtained without Cu-doping. The Mn{sub 3.6}Cu{sub 0.4}N exhibits ferrimagnetism, and the magnetization of Mn{sub 3.6}Cu{sub 0.4}N increases upon the temperature decreasing from 300 K to 5 K, similar to Mn{sub 4}N. The exchange bias (EB) effects emerge in the Mn{sub 3.6}Cu{sub 0.4}N films. The EB behavior is originated from the interfaces between ferrimagnetic Mn{sub 3.6}Cu{sub 0.4}N and antiferromagnetic metal Mn, which is verified to be formed by the data of x-ray photoelectron spectroscopy. The present results not only provide a strategy for producing functional antiperovskite manganese nitrides, but also shed promising light on fabricating the exchange bias part of spintronic devices.

  12. Interaction of CuS and sulfur in Li-S battery system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, undermore » a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.« less

  13. Fundamental studies of high-temperature corrosion reactions. Sixth annual progress report. [Cu-6% Ni

    SciTech Connect (OSTI)

    Rapp, R.A.

    1981-02-01

    Research was conducted on the sulfidation of pure Mo by sulfur gases at 700 to 950/sup 0/C and on the in-situ oxidation of metals and alloys in the hot-stage SEM. Results on the in-situ oxidation of Cu, Ni, Fe, and Cu-6% Ni up to 930/sup 0/C are reported in detail. 21 figures.

  14. Measurement of K0S and K*0 in p+p, d+Au, and Cu+Cu collisions at sqrt SNN = 200 GeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adare, A.; Aidala, C.

    2014-11-01

    The PHENIX experiment at the Relativistic Heavy Ion Collider has performed a systematic study of K0S and K*0 meson production at midrapidity in p+p, d+Au, and Cu+Cu collisions at sqrt SNN = 200 GeV. The K0S and K*0 mesons are reconstructed via their K0S and π0(→γγ)π0 (→γγ) and K*0 → K ±#25;π± decay modes, respectively. The measured transverse-momentum spectra are used to determine the nuclear modification factor of K0S and K*0 mesons in d+Au and Cu+Cu collisions at different centralities. In the d+Au collisions, the nuclear modification factor of K0S and K*0 mesons is almost constant as a function ofmore »transverse momentum and is consistent with unity showing that cold-nuclear-matter effects do not play a significant role in the measured kinematic range. In Cu+Cu collisions, within the uncertainties no nuclear modification is registered in peripheral collisions. In central collisions, both mesons show suppression relative to the expectations from the p+p yield scaled by the number of binary nucleon-nucleon collisions in the Cu+Cu system. In the pT range 2–5 GeV/c, the strange mesons ( K0S, K*0) similarly to the #30;Φ meson with hidden strangeness, show an intermediate suppression between the more suppressed light quark mesons (π0) and the nonsuppressed baryons (p, p-bar). At higher transverse momentum, pT > 5 GeV/c, production of all particles is similarly suppressed by a factor of ≈2. (auth)« less

  15. Measurement of K0S and K*0 in p+p, d+Au, and Cu+Cu collisions at sqrt SNN = 200 GeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adare, A.; Aidala, C.

    2014-11-01

    The PHENIX experiment at the Relativistic Heavy Ion Collider has performed a systematic study of K0S and K*0 meson production at midrapidity in p+p, d+Au, and Cu+Cu collisions at sqrt SNN = 200 GeV. The K0S and K*0 mesons are reconstructed via their K0S and π0(→γγ)π0 (→γγ) and K*0 → K ±#25;π± decay modes, respectively. The measured transverse-momentum spectra are used to determine the nuclear modification factor of K0S and K*0 mesons in d+Au and Cu+Cu collisions at different centralities. In the d+Au collisions, the nuclear modification factor of K0S and K*0 mesons is almost constant as a function ofmore » transverse momentum and is consistent with unity showing that cold-nuclear-matter effects do not play a significant role in the measured kinematic range. In Cu+Cu collisions, within the uncertainties no nuclear modification is registered in peripheral collisions. In central collisions, both mesons show suppression relative to the expectations from the p+p yield scaled by the number of binary nucleon-nucleon collisions in the Cu+Cu system. In the pT range 2–5 GeV/c, the strange mesons ( K0S, K*0) similarly to the #30;Φ meson with hidden strangeness, show an intermediate suppression between the more suppressed light quark mesons (π0) and the nonsuppressed baryons (p, p-bar). At higher transverse momentum, pT > 5 GeV/c, production of all particles is similarly suppressed by a factor of ≈2. (auth)« less

  16. Magnetic order tuned by Cu substitution in Fe1.1–zCuzTe

    SciTech Connect (OSTI)

    Wen, Jinsheng; Xu, Zhijun; Xu, Guangyong; Lumsden, M. D.; Valdivia, P. N.; Bourret-Courchesne, E.; Gu, Genda; Lee, Dung-Hai; Tranquada, J. M.; Birgeneau, R. J.

    2012-07-02

    We study the effects of Cu substitution in Fe₁.₁Te, the nonsuperconducting parent compound of the iron-based superconductor, Fe₁₊yTe₁₋xSex, utilizing neutron scattering techniques. It is found that the structural and magnetic transitions, which occur at ~60 K without Cu, are monotonically depressed with increasing Cu content. By 10% Cu for Fe, the structural transition is hardly detectable, and the system becomes a spin glass below 22 K, with a slightly incommensurate ordering wave vector of (0.5–δ, 0, 0.5) with δ being the incommensurability of 0.02, and correlation length of 12 Å along the a axis and 9 Å along the c axis. With 4% Cu, both transition temperatures are at 41 K, though short-range incommensurate order at (0.42, 0, 0.5) is present at 60 K. With further cooling, the incommensurability decreases linearly with temperature down to 37 K, below which there is a first-order transition to a long-range almost-commensurate antiferromagnetic structure. A spin anisotropy gap of 4.5 meV is also observed in this compound. Our results show that the weakly magnetic Cu has a large effect on the magnetic correlations; it is suggested that this is caused by the frustration of the exchange interactions between the coupled Fe spins.

  17. CuInSe/sub 2/-based photoelectrochemical cells: their use in characterization of thin CuInSe/sub 2/ films, and as photovoltaic cells per se

    SciTech Connect (OSTI)

    Cahen, D.; Chen, Y.W.; Ireland, P.J.; Noufi, R.; Turner, J.A.; Rincon, C.; Bachmann, K.J.

    1984-05-01

    Photoelectrochemistry has been employed to characterize the p-CuInSe/sub 2/ component of the CdS/CuInSe/sub 2/ on-metal and a nonaqueous electrolyte containing a redox couple not specifically adsorbed onto the semiconductor, we can test the films for photovoltaic activity and obtain effective electronic properties of them, before CdS deposition, in a nondestructive manner. Electrochemical decomposition of CuInSe/sub 2/ was investigated in acetonitrile solutions to determine the mechanism of decomposition (n and p) in the dark and under illumination. Electrochemical, solution chemical and surface analyses confirmed at the light-assisted decomposition of CuInSe/sub 2/ resulted in metal ions and elemental chalcogen. On the basis of the results from the electrochemical decomposition, and studies on the solid state chemistry of the (Cu/sub 2/Se)/sub x/(In/sub 2/Se/sub 3/)/sub 1-x/ system and surface analyses, the CuInSe/sub 2//polyiodide interface was stabilized and up to 11.7% conversion efficiencies were obtained.

  18. Identified high-pT spectra in Cu+Cu collisions at sqrt sNN=200 GeV

    SciTech Connect (OSTI)

    STAR Collaboration; Abelev, Betty

    2010-07-05

    We report new results on identified (anti)proton and charged pion spectra at large transverse momenta (3 < p{sub T} < 10 GeV/c) from Cu+Cu collisions at {radical}s{sub NN} = 200 GeV using the STAR detector at the Relativistic Heavy Ion Collider (RHIC). This study explores the system size dependence of two novel features observed at RHIC with heavy ions: the hadron suppression at high-p{sub T} and the anomalous baryon to meson enhancement at intermediate transverse momenta. Both phenomena could be attributed to the creation of a new form of QCD matter. The results presented here bridge the system size gap between the available pp and Au+Au data, and allow the detailed exploration for the on-set of the novel features. Comparative analysis of all available 200 GeV data indicates that the system size is a major factor determining both the magnitude of the hadron spectra suppression at large transverse momenta and the relative baryon to meson enhancement.

  19. Enhanced quality thin film Cu(In,Ga)Se.sub.2 for semiconductor device applications by vapor-phase recrystallization

    DOE Patents [OSTI]

    Tuttle, John R. (Denver, CO); Contreras, Miguel A. (Golden, CO); Noufi, Rommel (Golden, CO); Albin, David S. (Denver, CO)

    1994-01-01

    Enhanced quality thin films of Cu.sub.w (In,Ga.sub.y)Se.sub.z for semiconductor device applications are fabricated by initially forming a Cu-rich, phase-separated compound mixture comprising Cu(In,Ga):Cu.sub.x Se on a substrate to form a large-grain precursor and then converting the excess Cu.sub.x Se to Cu(In,Ga)Se.sub.2 by exposing it to an activity of In and/or Ga, either in vapor In and/or Ga form or in solid (In,Ga).sub.y Se.sub.z. Alternatively, the conversion can be made by sequential deposition of In and/or Ga and Se onto the phase-separated precursor. The conversion process is preferably performed in the temperature range of about 300.degree.-600.degree. C., where the Cu(In,Ga)Se.sub.2 remains solid, while the excess Cu.sub.x Se is in a liquid flux. The characteristic of the resulting Cu.sub.w (In,Ga).sub.y Se.sub.z can be controlled by the temperature. Higher temperatures, such as 500.degree.-600.degree. C., result in a nearly stoichiometric Cu(In,Ga)Se.sub.2, whereas lower temperatures, such as 300.degree.-400.degree. C., result in a more Cu-poor compound, such as the Cu.sub.z (In,Ga).sub.4 Se.sub.7 phase.

  20. Enhanced quality thin film Cu(In,Ga)Se[sub 2] for semiconductor device applications by vapor-phase recrystallization

    DOE Patents [OSTI]

    Tuttle, J.R.; Contreras, M.A.; Noufi, R.; Albin, D.S.

    1994-10-18

    Enhanced quality thin films of Cu[sub w](In,Ga[sub y])Se[sub z] for semiconductor device applications are fabricated by initially forming a Cu-rich, phase-separated compound mixture comprising Cu(In,Ga):Cu[sub x]Se on a substrate to form a large-grain precursor and then converting the excess Cu[sub x]Se to Cu(In,Ga)Se[sub 2] by exposing it to an activity of In and/or Ga, either in vapor In and/or Ga form or in solid (In,Ga)[sub y]Se[sub z]. Alternatively, the conversion can be made by sequential deposition of In and/or Ga and Se onto the phase-separated precursor. The conversion process is preferably performed in the temperature range of about 300--600 C, where the Cu(In,Ga)Se[sub 2] remains solid, while the excess Cu[sub x]Se is in a liquid flux. The characteristic of the resulting Cu[sub w](In,Ga)[sub y]Se[sub z] can be controlled by the temperature. Higher temperatures, such as 500--600 C, result in a nearly stoichiometric Cu(In,Ga)Se[sub 2], whereas lower temperatures, such as 300--400 C, result in a more Cu-poor compound, such as the Cu[sub z](In,Ga)[sub 4]Se[sub 7] phase. 7 figs.

  1. Three 3D hybrid networks based on octamolybdates and different Cu{sup I}/Cu{sup II}-bis(triazole) motifs

    SciTech Connect (OSTI)

    Zhang, Chun-Jing; Pang, Hai-Jun; Tang, Qun; Wang, Hui-Yuan; Chen, Ya-Guang

    2010-12-15

    Three 3D compounds based on octamolybdate clusters and various Cu{sup I}/Cu{sup II}-bis(triazole) motifs, [Cu{sup I}{sub 2}btb][{beta}-Mo{sub 8}O{sub 26}]{sub 0.5} (1), [Cu{sup I}{sub 2}btpe][{beta}-Mo{sub 8}O{sub 26}]{sub 0.5} (2), and [Cu{sup II}(btpe){sub 2}][{beta}-Mo{sub 8}O{sub 26}]{sub 0.5} (3) [btb=1,4-bis(1,2,4-triazol-1-yl)butane, btpe=1,5-bis(1,2,4-triazol-1-yl)pentane], were isolated via tuning flexible ligand spacer length and metal coordination preferences. In 1, the copper(I)-btb motif is a one-dimensional (1D) chain which is further linked by hexadentate {beta}-[Mo{sub 8}O{sub 26}]{sup 4-} clusters via coordinating to Cu{sup I} cations giving a 3D structure. In 2, the copper(I)-btpe motif exhibits a 'stairs'-like [Cu{sup I}{sub 2}btpe]{sup 2+} sheet, and the tetradentate {beta}-[Mo{sub 8}O{sub 26}]{sup 4-} clusters interact with two neighboring [Cu{sup I}{sub 2}btpe]{sup 2+} sheets constructing a 3D framework. In 3, the copper(II)-btpe motif possesses a novel (2D{yields}3D) interdigitated structure, which is further connected by the tetradentate {beta}-[Mo{sub 8}O{sub 26}]{sup 4-} clusters forming a 3D framework. The thermal stability and luminescent properties of 1-3 are investigated in the solid state. -- Graphical abstract: Three 3D compounds based on {beta}-[Mo{sub 8}O{sub 26}]{sup 4-} clusters with different Cu{sup I}/Cu{sup II}-bis(triazole) motifs were synthesized by regularly tuning flexible ligand spacer length and metal coordination preferences. Display Omitted

  2. Microsoft PowerPoint - ft

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    &3;&27;09072&4;3&4;3&4;&3;,&3;'&4;,-&4;0&3;,9&4;&3;94 08&4;&4;&4;03.0&3;,9&3;&28;&5;,8.,&4;0 &29;7,3&4;&3;&30;:0&4;&4;07 &27;059 &3;41&3;&26;425:907&3;.&4;03.0 &31;479&4;&3;&26;,74&4;&4;3,&3;9,90&3;&3&4;;078&4;9&5; &15; 08&4;&4;&4;03.0&3;&4;3&3;&2;&26; &7; &2;&26;&1;&3;&14; &4; &14; &4;&3;3408...

  3. SWiFT Research Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Program - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear

  4. Technology development for cobalt F-T catalysts. Topical report No.3, Zirconia promotion of Fischer-Tropsch cobalt catalysts: Behavior in fixed-bed and slurry bubble column reactors

    SciTech Connect (OSTI)

    Oukaci, R.; Marcelin, G.; Goodwin, J.G. Jr.

    1995-01-17

    A series of cobalt-based F-T catalysts supported on alumina and silica were prepared with different loadings of Zr and different sequences of impregnation of Co and Zr. All catalysts were extensively characterized by different methods. The catalysts were evaluated in terms of their activity and selectivity both in fixed bed and slurry bubble column reactors. Addition of ZrO{sub 2} to both Co/SiO{sub 2} and Co/Al{sub 2}O{sub 3} catalysts resulted in at least a twofold increase in the catalyst activity for F-T synthesis in the fixed bed reactor. In the slurry bubble column reactor, a similar promotion effect was observed for the SiO{sub 2}-supported catalysts, while the addition of Zr to a cobalt/alumina catalyst had a less significant effect.

  5. Kondo interactions from band reconstruction in YbInCu?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jarrige, I.; Kotani, A.; Yamaoka, H.; Tsujii, N.; Ishii, K.; Upton, M.; Casa, D.; Kim, J.; Gog, T.; Hancock, J. N.

    2015-03-27

    We combine resonant inelastic X-ray scattering (RIXS) and model calculations in the Kondo lattice compound YbInCu?, a system characterized by a dramatic increase in Kondo temperature and associated valence fluctuations below a first-order valence transition at T?42 K. The bulk-sensitive, element-specific, and valence-projected charge excitation spectra reveal an unusual quasi-gap in the Yb-derived state density which drives an instability of the electronic structure and renormalizes the low-energy effective Hamiltonian at the transition. Our results provide long-sought experimental evidence for a link between temperature-driven changes in the low-energy Kondo scale and the higher-energy electronic structure of this system.

  6. In situ visualization of metallurgical reactions in nanoscale Cu/Sn diffusion couples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yin, Qiyue; Stach, Eric A.; Gao, Fan; Zhou, Guangwen; Gu, Zhiyong

    2015-02-10

    The Cu–Sn metallurgical soldering reaction in two-segmented Cu–Sn nanowires is visualized by in-situ transmission electron microscopy. By varying the relative lengths of Cu and Sn segments, we show that the metallurgical reaction starts at ~ 200 ° with the formation of a Cu–Sn solid solution for the Sn/Cu length ratio smaller than 1:5 while the formation of Cu–Sn intermetallic compounds (IMCs) for larger Sn/Cu length ratios. Upon heating the nanowires up to ~ 500 °C, two phase transformation pathways occur, η-Cu₆Sn₅ → ε-Cu₃Sn → δ-Cu₄₁Sn₁₁ for nanowires with a long Cu segment and η-Cu₆Sn₅ → ε-Cu₃Sn → γ-Cu₃Sn with amore » short Cu segment. The dynamic in situ TEM visualization of the evolution of Kirkendall voids demonstrates that Cu diffuses faster both in Sn and IMCs than that of Sn in Cu₃ and IMCs, which is the underlying cause of the dependence of the IMC formation and associated phase evolution on the relative lengths of the Cu and Sn segments.« less

  7. Single-crystalline CuGeO{sub 3} nanorods: Synthesis, characterization and properties

    SciTech Connect (OSTI)

    Wang, Fangfang; Xing, Yan; Su, Zhongmin; Song, Shuyan

    2013-07-15

    Graphical abstract: - Highlights: Single crystalline CuGeO{sub 3} nanorods were prepared via a hydrothermal route. The material exhibits greatly enhanced activity in photocatalytic degradation of dyes. The magnetic susceptibility measurements indicate spin-Peierls transition properties. CuGeO{sub 3} nanorods may be of potential application in future integrated optical devices. - Abstract: Single crystalline CuGeO{sub 3} nanorods with a diameter of 2035 nm and a length up to 1 ?m have been prepared via a facile hydrothermal route with the assistance of ethylenediamine. Some influencing factors such as the reaction time, reaction temperature, the volume of ethylenediamine were revealed to play crucial roles in the formation of the CuGeO{sub 3} nanorods. A possible growth mechanism was proposed based on the experimental results. Significantly, this is the first time that CuGeO{sub 3} was used as a photocatalyst for organic pollutant degradation under UV light irradiation. The reaction constant (k) of CuGeO{sub 3} nanorods was five times that of the sample prepared by solid-state reaction under UV light irradiation. Additionally, the optical and magnetic properties of CuGeO{sub 3} nanorods were systematically studied.

  8. Characterization and device performance of (AgCu)(InGa)Se2 absorber layers

    SciTech Connect (OSTI)

    Hanket, Gregory; Boyle, Jonathan H.; Shafarman, William N.

    2009-06-08

    The study of (AgCu)(InGa)Se2 absorber layers is of interest in that Ag-chalcopyrites exhibit both wider bandgaps and lower melting points than their Cu counterparts. (AgCu)(InGa)Se2 absorber layers were deposited over the composition range 0 < Ag/(Ag+Cu) < 1 and 0.3 < Ga/(In+Ga) < 1.0 using a variety of elemental co-evaporation processes. Films were found to be singlephase over the entire composition range, in contrast to prior studies. Devices with Ga content 0.3 < Ga/(In+Ga) <0.5 tolerated Ag incorporation up to Ag/(Ag+Cu) = 0.5 without appreciable performance loss. Ag-containing films with Ga/(In+Ga) = 0.8 showed improved device characteristics over Cu-only control samples, in particular a 30-40% increase in short-circuit current. An absorber layer with composition Ag/(Ag+Cu) = 0.75 and Ga/(In+Ga) = 0.8 yielded a device with VOC = 890 mV, JSC = 20.5mA/cm2, fill factor = 71.3%, and ? = 13.0%.

  9. Isothermal Solid-State Transformation Kinetics Applied to Pd/Cu Alloy Membrane Fabrication

    SciTech Connect (OSTI)

    Pomerantz, Natalie L; Payzant, E Andrew; Ma, Yi Hua

    2010-01-01

    In this work, time-resolved, in situ high-temperature X-ray diffraction (HT-XRD) was used to study the solid-state transformation kinetics of the formation of the fcc Pd/Cu alloy from Pd/Cu bi-layers for the purpose of fabricating sulfur tolerant Pd/Cu membranes for H2 separation. Thin layers of Pd and Cu (total ~15 wt% Cu) were deposited on porous stainless steel (PSS) with the electroless deposition method and annealed in H2 at 500, 550 and 600 C. The kinetics of the annealing process were successfully described by the Avrami nucleation and growth model showing that the annealing process was diffusion controlled and one dimensional. The activation energy for the solid-state transformation was 175 kJ/mol, which was similar to the activation energy of Pd-Cu bulk interdiffusion. Furthermore, the Avrami model was able to successfully describe the changes in permeance and activation energy observed in Pd/Cu alloy membranes during characterization as they were annealed at high temperatures.

  10. Thermal chemistry of the Cu-KI5 atomic layer deposition precursor on a copper surface

    SciTech Connect (OSTI)

    Ma, Qiang; Zaera, Francisco

    2015-01-01

    The thermal chemistry of a Cu(I) ketoiminate complex, Cu-KI5, resulting from the modification of the known Air Products CupraSelect{sup } copper CVD precursor Cu(hfac)(tmvs) designed to tether the two ligands via an isopropoxide linker, was studied under ultrahigh vacuum on a Cu(110) single-crystal surface by using a combination of temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy. Adsorption at low temperatures was determined to take place via the displacement of the vinyl ligand by the surface. Molecular desorption was seen at 210?K, and the evolution of Cu(II)-KI5{sub 2} was established to take place at 280?K, presumably from a disproportionation reaction that also leads to the deposition of Cu(0). Other sets of desorption products were seen at 150, 250, and 430?K, all containing copper atoms and small organic moieties with molecular masses below 100 amu. The latter TPD peak in particular indicates significant fragmentation of the ligands, likely at the CN bond that holds the vinylsilane-isopropoxide moiety tethered to the ketoimine fragment, and possibly also at the union between the vinylsilane and the alkoxide linker. The 430?K temperature measured for this chemistry may set an upper limit for clean Cu film deposition, but since reactivity on the surface was also found to be inhibited at higher surface coverages, it may be delayed to higher temperatures under atomic layer deposition conditions.

  11. Magnetic Dipole Moment of {sup 57,59}Cu Measured by In-Gas-Cell Laser Spectroscopy

    SciTech Connect (OSTI)

    Cocolios, T. E.; Andreyev, A. N.; Bastin, B.; Bree, N.; Buescher, J.; Elseviers, J.; Gentens, J.; Huyse, M.; Kudryavtsev, Yu.; Pauwels, D.; Van den Bergh, P.; Van Duppen, P.; Sonoda, T.

    2009-09-04

    For the first time, in-gas-cell laser spectroscopy study of the {sup 57,59,63,65}Cu isotopes has been performed using the 244.164 nm optical transition from the atomic ground state of copper. The nuclear magnetic dipole moments for {sup 57,59,65}Cu relative to that of {sup 63}Cu have been extracted. The new value for {sup 57}Cu of mu({sup 57}Cu)=+2.582(7)mu{sub N} is in strong disagreement with the previous literature value but in good agreement with recent theoretical and systematic predictions.

  12. Crystal structure and magnetic properties of NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl

    SciTech Connect (OSTI)

    Jin Tengteng; Liu Wei; Chen Shuang; Prots, Yurii; Schnelle, Walter; Zhao Jingtai; Kniep, Ruediger; Hoffmann, Stefan

    2012-08-15

    A new copper(II) oxide phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], has been synthesized by flux synthesis. Single-crystal X-ray diffraction data show that the title compound crystallizes in the monoclinic system, space group P2{sub 1}/c (No. 14), with lattice parameters a=8.392(2) A, b=6.3960(10) A, c=16.670(2) A, {beta}=109.470(10) Degree-Sign , V=843.6(3) A{sup 3}, Z=4. The crystal structure is characterized by a complex chain of copper-centered polyhedra running along [0 1 0] which are connected by phosphate tetrahedra. The resulting three-dimensional polyhedra framework exhibits channels filled by additional copper and sodium atoms. Field and temperature dependent measurements of the specific heat and the magnetic susceptibility reveal low-dimensional magnetic behavior. The compound starts to decompose at 700 K under release of oxygen and evaporation of Cu{sup I}Cl as shown by simultaneous thermogravimetry and mass spectrometry. - Graphical abstract: The crystal structure of the new copper(II) phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], exhibits linear chains of copper tetrahedra which show low-dimensional magnetic behavior proven by specific heat and magnetic susceptibility measurements. Highlights: Black-Right-Pointing-Pointer A new copper(II) oxide phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], has been synthesized by flux synthesis. Black-Right-Pointing-Pointer The crystal structure comprises chains of Cu{sub 4}O tetrahedra. Black-Right-Pointing-Pointer Low-dimensional behavior has been proven by magnetic and specific heat measurements. Black-Right-Pointing-Pointer On heating, Cu{sup I}Cl and oxygen are released shown by simultaneous thermogravimetry and mass spectrometry.

  13. Structural evolution in Ti-Cu-Ni metallic glasses during heating

    SciTech Connect (OSTI)

    Gargarella, P.; Pauly, S.; Stoica, M.; Khn, U.; Vaughan, G.; Afonso, C. R. M.; Eckert, J.

    2015-01-01

    The structural evolution of Ti{sub 50}Cu{sub 43}Ni{sub 7} and Ti{sub 55}Cu{sub 35}Ni{sub 10} metallic glasses during heating was investigated by in-situ synchrotron X-ray diffraction. The width of the most intense diffraction maximum of the glassy phase decreases slightly during relaxation below the glass transition temperature. Significant structural changes only occur above the glass transition manifesting in a change in the respective peak positions. At even higher temperatures, nanocrystals of the shape memory B2-Ti(Cu,Ni) phase precipitate, and their small size hampers the occurrence of a martensitic transformation.

  14. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Citation Details In-Document Search This content will become publicly available on September 21, 2016 Title: Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film

  15. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum

    Office of Scientific and Technical Information (OSTI)

    annealing (Journal Article) | SciTech Connect Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing Citation Details In-Document Search Title: Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+δ thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship

  16. Non-uniform Aging on Super Duty Diesel Truck Aged Urea Cu/Zeolite SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysts | Department of Energy uniform Aging on Super Duty Diesel Truck Aged Urea Cu/Zeolite SCR Catalysts Non-uniform Aging on Super Duty Diesel Truck Aged Urea Cu/Zeolite SCR Catalysts Cu/Zeolite SCR catalysts aged for 50k miles on a Super Duty diesel truck PDF icon deer10_cheng.pdf More Documents & Publications Deactivation Mechanisms of Base Metal/Zeolite Urea Selective Catalytic Reduction Materials, and Development of Zeolite-Based Hydrocarbon Adsorber Materials Deactivation

  17. Mixed-sputter deposition of Ni-Ti-Cu shape memory films

    SciTech Connect (OSTI)

    Krulevitch, P.; Ramsey, P.B.; Makowiecki, D.M.; Lee, A.P.; Northrup, M.A.; Johnson, G.C.

    1994-05-01

    Ni-Ti-Cu shape memory films were mixed-sputter deposited from separate nickel, titanium, and copper targets, providing increased compositional flexibility. Shape memory characteristics, examined for films with 7 at. % Cu and 41--51 at. % Tl, were determined with temperature controlled substrate curvature measurements, and microstructure was studied with transmission electron microscopy. The Ni-Ti-Cu films were found to have shape memory properties comparable to bulk materials, with transformation temperatures between 20 and 62{degree}C, a 10--13{degree}C hysteresis, and up to 330 MPa recoverable stress.

  18. Y-Ba-Cu-O films prepared by a paint-on method

    SciTech Connect (OSTI)

    Shih, I.; Qiu, C.X.

    1988-02-29

    Polycrystalline films of Y-Ba-Cu-O with a thickness of about 20--40 ..mu..m have been prepared on alumina substrates using a paint-on method. The liquid source used was obtained by mixing powder of Y/sub 2/O/sub 3/, BaCO/sub 3/, and CuO in liquid triethanolamine. Several Y-Ba-Cu-O films with an onset temperature of about 100 K and a zero resistance temperature of 85 K have been obtained after a short heat treatment at 1000 /sup 0/C in flowing O/sub 2/.

  19. Phosphorescence quenching by mechanical stimulus in CaZnOS:Cu

    SciTech Connect (OSTI)

    Tu, Dong; Kamimura, Sunao; Xu, Chao-Nan; Fujio, Yuki; Sakata, Yoshitaro; Ueno, Naohiro

    2014-07-07

    We have found that phosphorescence intensity of CaZnOS:Cu decreased visibly under an applied load. This mechanical quenching (MQ) of phosphorescence in CaZnOS:Cu corresponded to the mechanical stimuli. We have thus demonstrated that the MQ of CaZnOS:Cu could be used for visualizing stress distributions in practical applications. We propose that MQ arises from non-radiative recombination due to electron-transfer from trap levels to non-radiative centers as a result of the mechanical load.

  20. Microsoft Word - Gas Order Form.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IND., R20 NITROGEN, IND., 90 CU FT NITROGEN, IND., 220 CU FT NITROGEN, UHP, 5.0, SIZE 200 NITROGEN, PREPURIFIED 4.8 SIZE 200 NITROUS OXIDE, 64, SIZE 200 ...

  1. Kansas Proved Nonproducing Reserves

    Gasoline and Diesel Fuel Update (EIA)

    Lease Condensate (million bbls) 0 0 0 0 4 12 1998-2014 Total Gas (billion cu ft) 132 236 283 277 486 764 1996-2014 Nonassociated Gas (billion cu ft) 128 235 244 218 314 489...

  2. Cuba: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Country Profile Name Cuba Population 11,210,064 GDP 78,694,000,000 Energy Consumption 0.42 Quadrillion Btu 2-letter ISO code CU 3-letter ISO code CUB Numeric ISO...

  3. A Theoretical Study of Methanol Synthesis from CO(2) Hydrogenation on Metal-doped Cu(111) Surfaces

    SciTech Connect (OSTI)

    Liu P.; Yang, Y.; White, M.G.

    2012-01-12

    Density functional theory (DFT) calculations and Kinetic Monte Carlo (KMC) simulations were employed to investigate the methanol synthesis reaction from CO{sub 2} hydrogenation (CO{sub 2} + 3H{sub 2} {yields} CH{sub 3}OH + H{sub 2}O) on metal-doped Cu(111) surfaces. Both the formate pathway and the reverse water-gas shift (RWGS) reaction followed by a CO hydrogenation pathway (RWGS + CO-Hydro) were considered in the study. Our calculations showed that the overall methanol yield increased in the sequence: Au/Cu(111) < Cu(111) < Pd/Cu(111) < Rh/Cu(111) < Pt/Cu(111) < Ni/Cu(111). On Au/Cu(111) and Cu(111), the formate pathway dominates the methanol production. Doping Au does not help the methanol synthesis on Cu(111). Pd, Rh, Pt, and Ni are able to promote the methanol production on Cu(111), where the conversion via the RWGS + CO-Hydro pathway is much faster than that via the formate pathway. Further kinetic analysis revealed that the methanol yield on Cu(111) was controlled by three factors: the dioxomethylene hydrogenation barrier, the CO binding energy, and the CO hydrogenation barrier. Accordingly, two possible descriptors are identified which can be used to describe the catalytic activity of Cu-based catalysts toward methanol synthesis. One is the activation barrier of dioxomethylene hydrogenation, and the other is the CO binding energy. An ideal Cu-based catalyst for the methanol synthesis via CO{sub 2} hydrogenation should be able to hydrogenate dioxomethylene easily and bond CO moderately, being strong enough to favor the desired CO hydrogenation rather than CO desorption but weak enough to prevent CO poisoning. In this way, the methanol production via both the formate and the RWGS + CO-Hydro pathways can be facilitated.

  4. Structural and thermal properties of nanocrystalline CuO synthesized by reactive magnetron sputtering

    SciTech Connect (OSTI)

    Verma, M.; Gupta, V. K.; Gautam, Y. K.; Dave, V.; Chandra, R.

    2014-01-28

    Recent research has shown immense application of metal oxides like CuO, MgO, CaO, Al{sub 2}O{sub 3}, etc. in different areas which includes chemical warfare agents, medical drugs, magnetic storage media and solar energy transformation. Among the metal oxides, CuO nanoparticles are of special interest because of their excellent gas sensing and catalytic properties. In this paper we report structural and thermal properties of CuO synthesized by reactive magnetron DC sputtering. The synthesized nanoparticles were characterized by X-ray diffractometer. The XRD result reveals that as DC power increased from 30W to 80W, size of the CuO nanoparticles increased. The same results have been verified through TEM analysis. Thermal properties of these particles were studied using thermogravimetry.

  5. Method of synthesizing and growing copper-indium-diselenide (CuInSe/sub 2/) crystals

    DOE Patents [OSTI]

    Ciszek, T.F.

    1984-11-29

    A process for preparing CuInSe/sub 2/ crystals includes melting a sufficient quantity of B/sub 2/O/sub 2/ along with stochiometric quantities of Cu, In, and Se in a crucible in a high-pressure atmosphere of inert gas to encapsulate the CuInSe/sub 2/ melt and confine the Se to the crucible. Additional Se in the range of 1.8 to 2.2% over the stochiometric quantity is preferred to make up for small amounts of Se lost in the process. The melt can then be cooled slowly to form the crystal as direct solidification, or the crystal can be grown by inserting a seed crystal through the B/sub 2/O/sub 3/ encapsulate into contact with the CuInSe/sub 2/ melt and withdrawing the seed upwardly to grow the crystal thereon from the melt.

  6. Measurement of cross sections for the Cu-63(alpha,gamma)Ga-67...

    Office of Scientific and Technical Information (OSTI)

    Title: Measurement of cross sections for the Cu-63(alpha,gamma)Ga-67 reaction from 5.9-8.7 MeV Authors: Basunia, M S ; Norman, E B ; Shugart, H A ; Smith, A R ; Dolinski, M J ; ...

  7. Method of synthesizing and growing copper-indium-diselenide (CuInSe.sub.2) crystals

    DOE Patents [OSTI]

    Ciszek, Theodore F. (Evergreen, CO)

    1987-01-01

    A process for preparing CuInSe.sub.2 crystals includes melting a sufficient quantity of B.sub.2 O.sub.3 along with stoichiometric quantities of Cu, In, and Se in a crucible in a high pressure atmosphere of inert gas to encapsulate the CuInSe.sub.2 melt and confine the Se to the crucible. Additional Se in the range of 1.8 to 2.2 percent over the stoichiometric quantity is preferred to make up for small amounts of Se lost in the process. The crystal is grown by inserting a seed crystal through the B.sub.2 O.sub.3 encapsulate into contact with the CuInSe.sub.2 melt and withdrawing the seed upwardly to grow the crystal thereon from the melt.

  8. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and...

    Office of Scientific and Technical Information (OSTI)

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+ thin films. The transition temperature after each annealing step has been ...

  9. Hidden Itinerant-Spin Phase in Heavily Overdoped La2-xSrxCuO4...

    Office of Scientific and Technical Information (OSTI)

    Hidden Itinerant-Spin Phase in Heavily Overdoped La2-xSrxCuO4 Superconductors Revealed by Dilute Fe Doping: A Combined Neutron Scattering and Angle-Resolved Photoemission Study...

  10. Magnetization of underdoped YBa 2 Cu 3 O y above the irreversibility...

    Office of Scientific and Technical Information (OSTI)

    Title: Magnetization of underdoped YBa 2 Cu 3 O y above the irreversibility field Authors: Yu, Jing Fei ; Ramshaw, B. J. ; Kokanovi, I. ; Modic, K. A. ; Harrison, N. ; Day, James ...

  11. Non-Equilibrium Superconductivity and Quasiparticle Dynamics in YBaCuO

    SciTech Connect (OSTI)

    Siders, J.L.W.; Jacobs, R.N.; Siders, C.W.; Trugman, S.A.; Taylor, A.J.

    1999-05-21

    The authors use optical pump, coherent terahertz probe spectroscopy to transiently excite nonequilibrium populations of quasiparticles in YBa{sub 2}Cu{sub 3}O{sub 7.{delta}} and monitor, with picosecond resolution, the superfluid and quasiparticle dynamics.

  12. Ordered structures in YBa/sub 2/Cu/sub 3/O/sub 7-y/, La/sub 2-x/Sr/sub x/CuO/sub 4-par. delta/ and related perovskites

    SciTech Connect (OSTI)

    Mitchell, T.E.; Roy, T.; Fisk, Z.; Smith, J.L.

    1988-01-01

    Electron microscopy and electron diffraction studies have been performed on the superconducting oxides YBa/sub 2/Cu/sub 3/O/sub 7-y/, GdBa/sub 2/Cu/sub 3/O/sub 7-y/ and La/sub 2-x/Sr/sub x/CuO/sub 4-par. delta/ as well as the related perovskites La/sub 2/CuO/sub 4/, Eu/sub 2/CuO/sub 4/ and Gd/sub 2/CuO/sub 4/. Extra reflections are commonly observed in all the cases. For example, in the 123 compounds, in situ heating leads to transformations from orthorhombic to tetragonal with a loss of twin structure; on cooling the oxygen vacancies re-order in the basal plane to give 1/3(100)* or 1/4(110)* diffraction spots. In tetragonal Eu/sub 2/CuO/sub 4/ and Gd/sub 2/CuO/sub 4/, the (001) diffraction patterns often have extra spots at 1/2(110)* or at 1/4(110)* positions. Extra spots are also observed in La/sub 2/CuO/sub 4/ (orthorhombic) but this is probably due to the space group being primitive rather than centered. These observations are discussed in terms of the ordering of oxygen vacancies in the Cu-O planes of the various perovskite structures. 6 figs.

  13. Doping Cu{sub 2}O in Electrolyte Solution: Dopant Incorporation, Atomic Structures and Electrical Properties

    SciTech Connect (OSTI)

    Tao, Meng; Zhang, Qiming

    2013-11-24

    We have pursued a number of research activities between April 2010 and April 2011: ? A detailed study on n-type doping in Cu2O by Br; ? An analysis of natural resource limitations to terawatt-scale solar cells; ? Attempt to achieve a 1.4-eV direct band gap in Ni sulfides (NiSx); ? First-principles studies of doping in Cu2O and electronic structures of NiSx.

  14. Understanding NOx SCR Mechanism and Activity on Cu/Chabazite Structures throughout the Catalyst Life Cycle

    SciTech Connect (OSTI)

    Ribeiro, Fabio; Delgass, Nick; Gounder, Rajmani; Schneider, William F.; Miller, Jeff; Yezerets, Aleksey; McEwen, Jean-Sabin; Peden, Charles HF; Howden, Ken

    2014-12-09

    Oxides of nitrogen (NOx) compounds contribute to acid rain and photochemical smog and have been linked to respiratory ailments. NOx emissions regulations continue to tighten, driving the need for high performance, robust control strategies. The goal of this project is to develop a deep, molecular level understanding of the function of Cu-SSZ-13 and Cu-SAPO-34 materials that catalyze the SCR of NOx with NH3.

  15. Potassium-induced effect on structure and chemical activity of CuxO/Cu(111)

    Office of Scientific and Technical Information (OSTI)

    (x≤2) surface: A combined scanning tunneling microscopy and density functional theory study (Journal Article) | SciTech Connect Potassium-induced effect on structure and chemical activity of CuxO/Cu(111) (x≤2) surface: A combined scanning tunneling microscopy and density functional theory study Citation Details In-Document Search This content will become publicly available on October 16, 2016 Title: Potassium-induced effect on structure and chemical activity of CuxO/Cu(111) (x≤2)

  16. Thin-film polycrystalline n-ZnO/p-CuO heterojunction

    SciTech Connect (OSTI)

    Lisitski, O. L.; Kumekov, M. E.; Kumekov, S. E. Terukov, E. I.

    2009-06-15

    Results of X-ray diffraction and spectral-optical studies of n-ZnO and p-CuO films deposited by gas-discharge sputtering with subsequent annealing are presented. It is shown that, despite the difference in the crystal systems, the polycrystallinity of n-ZnO and p-CuO films enables fabrication of a heterojunction from this pair of materials.

  17. Stability and amorphization of Cu-Nb interfaces during severe plastic

    Office of Scientific and Technical Information (OSTI)

    deformation: Molecular dynamics simulations of simple shear (Journal Article) | SciTech Connect Stability and amorphization of Cu-Nb interfaces during severe plastic deformation: Molecular dynamics simulations of simple shear Citation Details In-Document Search Title: Stability and amorphization of Cu-Nb interfaces during severe plastic deformation: Molecular dynamics simulations of simple shear Authors: Zhou, J ; Averback, R. S. ; Bellon, P. Publication Date: 2014-01-01 OSTI Identifier:

  18. CU-CBR-1-I Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    CBR-1-I Wholesale Power Rate Schedule CU-CBR-1-I Wholesale Power Rate Schedule Area: Big Rivers and Henderson, KY System: CU This rate schedule shall be available to Big Rivers Electric Corporation and includes the City of Henderson, Kentucky. This rate schedule shall be applicable to electric capacity and energy available from the Dale Hollow, Center Hill, Wolf Creek, Cheatham, Old Hickory, Barkley, J. Percy Priest, and Cordell Hull Projects (all of such projects being hereinafter called

  19. CU-CC-1-J Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    CC-1-J Wholesale Power Rate Schedule CU-CC-1-J Wholesale Power Rate Schedule Area: Duke Energy Progress, Western Division System: CU This rate schedule shall be available to public bodies and cooperatives served through the facilities of Duke Energy Progress (formerly known as Carolina Power & Light Company), Western Division (hereinafter called the Customers). This rate schedule shall be applicable to electric capacity and energy available from the Dale Hollow, Center Hill, Wolf Creek,

  20. CU-CEK-1-I Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    CEK-1-I Wholesale Power Rate Schedule CU-CEK-1-I Wholesale Power Rate Schedule Area: East Kentucky System: CU This rate schedule shall be available to East Kentucky Power Cooperative (hereinafter called the Customer). This rate schedule shall be applicable to electric capacity and energy available from the Dale Hollow, Center Hill, Wolf Creek, Cheatham, Old Hickory, Barkley, J. Percy Priest, and Cordell Hull Projects (all of such projects being hereinafter called collectively the

  1. CU-CK-1-I Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    CK-1-I Wholesale Power Rate Schedule CU-CK-1-I Wholesale Power Rate Schedule Area: Kentucky Utilities System: CU This rate schedule shall be available to public bodies served through the facilities of Kentucky Utilities Company, (hereinafter called the Customers.) This rate schedule shall be applicable to electric capacity and energy available from the Dale Hollow, Center Hill, Wolf Creek, Cheatham, Old Hickory, Barkley, J. Percy Priest, and Cordell Hull Projects (all of such projects being

  2. CU-CM-1-I Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    CM-1-I Wholesale Power Rate Schedule CU-CM-1-I Wholesale Power Rate Schedule Area: MEAM, MDEA, and SMEPA System: CU This rate schedule shall be available to the South Mississippi Electric Power Association, Municipal Energy Agency of Mississippi, and Mississippi Delta Energy Agency. This rate schedule shall be applicable to electric capacity and energy available from the Dale Hollow, Center Hill, Wolf Creek, Cheatham, Old Hickory, Barkley, J. Percy Priest, and Cordell Hull Projects (all of such

  3. CU-CSI-1-I Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    CSI-1-I Wholesale Power Rate Schedule CU-CSI-1-I Wholesale Power Rate Schedule Area: Southern Illinois System: CU This rate schedule shall be available to Southern Illinois Power Cooperative (hereinafter the Customer). This rate schedule shall be applicable to electric capacity and energy available from the Dale Hollow, Center Hill, Wolf Creek, Cheatham, Old Hickory, Barkley, J. Percy Priest, and Cordell Hull Projects (all of such projects being hereinafter called collectively the

  4. CU-CTV-1-I Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    CTV-1-I Wholesale Power Rate Schedule CU-CTV-1-I Wholesale Power Rate Schedule Area: Tennessee Valley Authority System: CU This rate schedule shall be available to the Tennessee Valley Authority (hereinafter called TVA). This rate schedule shall be applicable to electric capacity and energy generated at the Dale Hollow, Center Hill, Wolf Creek, Old Hickory, Cheatham, Barkley, J. Percy Priest, and Cordell Hull Projects (all of such projects being hereafter called collectively the "Cumberland

  5. CU-Replacement-3 Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    Replacement-3 Wholesale Power Rate Schedule CU-Replacement-3 Wholesale Power Rate Schedule Area: Virginia, North Carolina, Tennessee, Georgia, Alabama, Mississippi, Kentucky, southern Illinois System: CU This rate schedule shall be available to public bodies and cooperatives ( any one of whom is hereinafter called the Customer) in Virginia, North Carolina, Tennessee, Georgia, Alabama, Mississippi, Kentucky and southern Illinois to whom power is provided pursuant to contracts between the

  6. The magnetic structure of EuCu2Sb2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ryan, D. H.; Cadogan, J. M.; Anand, V. K.; Johnston, D. C.; Flacau, R.

    2015-05-06

    Antiferromagnetic ordering of EuCu2Sb2 which forms in the tetragonal CaBe2Ge2-type structure (space group P4/nmm #129) has been studied using neutron powder diffraction and 151Eu Mössbauer spectroscopy. The room temperature 151Eu isomer shift of –12.8(1) mm/s shows the Eu to be divalent, while the 151Eu hyperfine magnetic field (Bhf) reaches 28.7(2) T at 2.1 K, indicating a full Eu2+ magnetic moment. Bhf(T) follows a smoothmore » $$S=\\frac{7}{2}$$ Brillouin function and yields an ordering temperature of 5.1(1) K. Refinement of the neutron diffraction data reveals a collinear A-type antiferromagnetic arrangement with the Eu moments perpendicular to the tetragonal c-axis. As a result, the refined Eu magnetic moment at 0.4 K is 7.08(15) μB which is the full free-ion moment expected for the Eu2+ ion with $$S=\\frac{7}{2}$$ and a spectroscopic splitting factor of g = 2.« less

  7. Metallic glass alloys of Zr, Ti, Cu and Ni

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Peker, Atakan (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1997-01-01

    At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM.sub.1-x Ti.sub.x).sub.a Cu.sub.b (Ni.sub.1-y Co.sub.y).sub.c wherein x is from 0.1 to 0.3, y.cndot.c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b.

  8. Electrochemical synthesis of Nb3Sn coatings on Cu substrates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Franz, S.; Barzi, E.; Turrioni, D.; Glionna, L.; Bestetti, M.

    2015-09-11

    This study aims at contributing to the development of superconducting Nb3Sn thin films for possible applications, as for instance in superconducting radio frequency (SRF) cavities. The synthesis of Nb-Sn coatings was carried out on copper substrates by electrodeposition from 1-Butyl-3-methylimidazolium chloride (BMIC) ionic liquids containing SnCl2 and NbCl5. Cyclic voltammetric curves were recorded to identify the reduction potentials of Nb and Sn ionic species. Electrodeposition was performed at 40 and 400 mA/cm2 and 130°C. The CV demonstrated that BMIC has a suitable potential window for co-deposition of Nb and Sn. The electrodeposited coatings showed a cubic Nb3Sn phase with (211)more » preferred orientation, a disordered orthorhombic NbSn2 phase and Sn-Cu phases. Film thickness was from 200 to 750 nm. These results suggest that electrodeposition of Nb-Sn coatings on copper substrates could be a suitable route to one day replace the current expensive Nb SRF cavities.« less

  9. Magnetic order tuned by Cu substitution in Fe1.1–zCuzTe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wen, Jinsheng; Xu, Zhijun; Xu, Guangyong; Lumsden, M. D.; Valdivia, P. N.; Bourret-Courchesne, E.; Gu, Genda; Lee, Dung-Hai; Tranquada, J. M.; Birgeneau, R. J.

    2012-07-02

    We study the effects of Cu substitution in Fe₁.₁Te, the nonsuperconducting parent compound of the iron-based superconductor, Fe₁₊yTe₁₋xSex, utilizing neutron scattering techniques. It is found that the structural and magnetic transitions, which occur at ~60 K without Cu, are monotonically depressed with increasing Cu content. By 10% Cu for Fe, the structural transition is hardly detectable, and the system becomes a spin glass below 22 K, with a slightly incommensurate ordering wave vector of (0.5–δ, 0, 0.5) with δ being the incommensurability of 0.02, and correlation length of 12 Å along the a axis and 9 Å along the cmore » axis. With 4% Cu, both transition temperatures are at 41 K, though short-range incommensurate order at (0.42, 0, 0.5) is present at 60 K. With further cooling, the incommensurability decreases linearly with temperature down to 37 K, below which there is a first-order transition to a long-range almost-commensurate antiferromagnetic structure. A spin anisotropy gap of 4.5 meV is also observed in this compound. Our results show that the weakly magnetic Cu has a large effect on the magnetic correlations; it is suggested that this is caused by the frustration of the exchange interactions between the coupled Fe spins.« less

  10. Enhanced thermoelectric performance in Cd doped CuInTe{sub 2} compounds

    SciTech Connect (OSTI)

    Cheng, N.; Liu, R.; Bai, S.; Shi, X. Chen, L.

    2014-04-28

    CuIn{sub 1?x}Cd{sub x}Te{sub 2} materials (x?=?0, 0.02, 0.05, and 0.1) are prepared using melting-annealing method and the highly densified bulk samples are obtained through Spark Plasma Sintering. The X-ray diffraction data confirm that nearly pure chalcopyrite structures are obtained in all the samples. Due to the substitution of Cd at In sites, the carrier concentration is greatly increased, leading to much enhanced electrical conductivity and power factor. The single parabolic band model is used to describe the electrical transport properties of CuInTe{sub 2} and the low temperature Hall mobility is also modeled. By combing theoretical model and experiment data, the optimum carrier concentration in CuInTe{sub 2} is proposed to explain the greatly enhanced power factors in the Cd doped CuInTe{sub 2}. In addition, the thermal conductivity is reduced by extra phonon scattering due to the atomic mass and radius fluctuations between Cd and In atoms. The maximum zTs are observed in CuIn{sub 0.98}Cd{sub 0.02}Te{sub 2} and CuIn{sub 0.9}Cd{sub 0.1}Te{sub 2} samples, which are improved by over 100% at room temperature and around 20% at 600?K.

  11. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    SciTech Connect (OSTI)

    Kim, Hyun You; Liu, Ping

    2015-09-21

    Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film supported on Cu(111), CuTiOx/Cu(111), during CO oxidation was explored using density functional theory (DFT). The unique structural frame of CuTiOx is able to stabilize and isolate a single Cu+ site on the terrace, which is previously proposed active for CO oxidation. Furthermore, it is not the case, where the reaction via both the LangmuirHinshelwood (LH) and the Mars-van Krevelen (M-vK) mechanisms are hindered on such single Cu+ site. Upon the formation of step-edges, the synergy among Cu?+ sites, TiOx matrix, and Cu(111) is able to catalyze the reaction well. Depending on temperatures and partial pressure of CO and O2, the surface structure varies, which determines the dominant mechanism. In accordance with our results, the Cu?+ ion alone does not work well for CO oxidation in the form of single sites, while the synergy among multiple active sites is necessary to facilitate the reaction.

  12. Hydrodechlorination of 1,2-Dichloroethane Catalyzedby Dendrimer-Derived Pt-Cu/SiO2 Catalysts

    SciTech Connect (OSTI)

    Xie, Hong; Howe, Jane Y; Schwartz, Viviane; Monnier, J. R.; Williams, Christopher T.; Ploehn, Harry J.

    2008-01-01

    Dendrimer-metal-nanocomposites (DMNs) were used as precursors to prepare SiO2 supported monometallic Pt, Cu and bimetallic Pt-Cu catalysts with Pt/Cu atomic ratios of 1:1 (Pt50Cu50) and 1:3 (Pt25Cu75). After impregnation of these DMNs onto the support, the catalysts were thermally treated and activated following an optimized protocol. Scanning transmission electron microscopy (STEM) shows that the metal nanoparticles in dendrimer-derived SiO2-supported catalysts are smaller and have a more narrow size distribution than those in conventional catalysts prepared using corresponding metal salts via the wet impregnation method. Slow deactivation was observed for hydrodechlorination of 1,2-dichloroethane over monometallic Cu catalysts, which showed an activity about one to two orders of magnitude lower than that of the Pt-containing catalysts. Hydrodechlorination of 1,2-dichloroethane over Pt and Pt50Cu50 catalysts mainly produces ethane and the selectivity towards ethane increases with temperature. For Pt25Cu75 catalyst, the selectivity towards ethane decreases in favor of ethylene. The overall activity decreases with increasing Cu loading in the catalysts. Activity based on surface Pt sites suggests the formation of bi-functional surfaces in Pt25Cu75 catalyst favoring C-Cl bond scission on Cu sites and hydrogenation of intermediate .CH2CH2. on Pt sites. Furthermore, kinetic analyses suggest different reaction mechanisms for hydrodechlorination of 1,2-dichloroethane over Pt and Cu-enriched surfaces in the Pt-Cu bimetallic catalysts.

  13. Novel Approaches to Wide Bandgap CuInSe2 Based Absorbers

    SciTech Connect (OSTI)

    William N. Shafarman

    2011-04-28

    This project targeted the development of high performance wide bandgap solar cells based on thin film alloys of CuInSe2 to relax constraints on module design and enable tandem solar cell structures. This addressed goals of the Solar Energy Technologies Program for Next Generation PV to develop technology needed for higher thin film module efficiency as a means to reduce costs. Specific objectives of the research project were: 1) to develop the processes and materials required to improve the performance of wide bandgap thin film solar cells based on alloys of CuInSe2, and 2) to provide the fundamental science and engineering basis for the material, electronic, and device properties required to effectively apply these processes and materials to commercial manufacture. CuInSe2-based photovoltaics have established the highest efficiencies of the thin film materials at both the cell and module scales and are actively being scaled up to commercialization. In the highest efficiency cells and modules, the optical bandgap, a function of the CuInSe2-based alloy composition, is relatively low compared to the optimum match to the solar spectrum. Wider bandgap alloys of CuInSe2 produce higher cell voltages which can improve module performance and enable the development of tandem solar cells to boost the overall efficiency. A focus for the project was alloying with silver to form (AgCu)(InGa)Se2 pentenary thin films deposited by elemental co-evaporation which gives the broadest range of control of composition and material properties. This alloy has a lower melting temperature than Ag-free, Cu-based chalcopyrite compounds, which may enable films to be formed with lower defect densities and the (AgCu)(InGa)Se2 films give improved material properties and better device performance with increasing bandgap. A comprehensive characterization of optical, structural, and electronic properties of (AgCu)(InGa)Se2 was completed over the complete compositional range 0 ? Ga/(In+Ga) ? 1 and 0 ? Ag/(Ag+Cu) ? 1. Evidence of improved material quality includes reduced sub-bandgap optical absorption, sharper bandtails, and increased grain size with Ag addition. The Ag alloying was shown to increase the range of bandgaps over which solar cells can be fabricated without any drop-off in performance. With bandgap greater than 1.6 eV, in the range needed for tandem solar cells, (AgCu)(InGa)Se2 gave higher efficiency than other CuInSe2-based alloys. Using a simple single-stage co-evaporation process, a solar cell with 17.6% efficiency using a film with bandgap = 1.3 eV was achieved, demonstrating the viability of (AgCu)(InGa)Se2 for high efficiency devices. With a three-stage co-evaporation process for (AgCu)(InGa)Se2 deposition a device with efficiency = 13.0 % and VOC = 890 mV with JSC = 20.5 mA/cm2, FF = 71.3% was achieved. This surpasses the performance of other wide bandgap CuInSe2-based solar cells. Detailed characterization of the electronic properties of the materials and devices including the application of advanced admittance-based easements was completed.

  14. Virginia Proved Nonproducing Reserves

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    0 0 0 0 1996-2014 Lease Condensate (million bbls) 0 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 839 67 800 697 471 806 1996-2014 Nonassociated Gas (billion cu ft) 839 67 800 697 471 806 1996-2014 Associated Gas (billion cu ft) 0 0 0 0 0 0

  15. Alabama Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    0 1 2 2 15 1996-2014 Lease Condensate (million bbls) 0 0 0 0 1 0 1998-2014 Total Gas (billion cu ft) 126 162 102 40 73 36 1996-2014 Nonassociated Gas (billion cu ft) 126 162 101 38 71 26 1996-2014 Associated Gas (billion cu ft) 0 0 1 2 2 1

  16. Michigan Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    6 0 0 0 4 3 1996-2014 Lease Condensate (million bbls) 8 4 4 5 0 0 1998-2014 Total Gas (billion cu ft) 556 314 147 95 63 49 1996-2014 Nonassociated Gas (billion cu ft) 535 311 146 95 48 34 1996-2014 Associated Gas (billion cu ft) 21 3 1 0 15 1

  17. Miscellaneous Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    7 5 7 12 9 6 1996-2014 Lease Condensate (million bbls) 0 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 102 62 120 92 48 42 1996-2014 Nonassociated Gas (billion cu ft) 102 62 120 89 48 42 1996-2014 Associated Gas (billion cu ft) 0 0 0 3 0 0

  18. Mississippi Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    117 94 90 82 73 85 1996-2014 Lease Condensate (million bbls) 1 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 257 207 220 127 143 204 1996-2014 Nonassociated Gas (billion cu ft) 255 207 219 127 143 200 1996-2014 Associated Gas (billion cu ft) 2 0 1 0 0 4

  19. Montana Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    2 74 59 95 104 155 1996-2014 Lease Condensate (million bbls) 0 0 0 1 0 0 1998-2014 Total Gas (billion cu ft) 127 146 81 124 80 125 1996-2014 Nonassociated Gas (billion cu ft) 104 91 50 48 30 29 1996-2014 Associated Gas (billion cu ft) 23 55 31 76 50 9

  20. TX, RRC District 3 Onshore Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    26 37 19 118 163 189 1996-2014 Lease Condensate (million bbls) 14 15 14 25 13 19 1998-2014 Total Gas (billion cu ft) 798 879 714 671 735 709 1996-2014 Nonassociated Gas (billion cu ft) 685 739 627 556 502 527 1996-2014 Associated Gas (billion cu ft) 113 140 87 115 233 182

  1. TX, RRC District 7B Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    8 8 13 19 12 16 1996-2014 Lease Condensate (million bbls) 0 1 0 0 0 0 1998-2014 Total Gas (billion cu ft) 737 897 890 857 629 464 1996-2014 Nonassociated Gas (billion cu ft) 714 890 878 840 617 407 1996-2014 Associated Gas (billion cu ft) 23 7 12 17 12 5

  2. TX, RRC District 8A Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    413 418 419 433 367 361 1996-2014 Lease Condensate (million bbls) 6 11 5 6 0 0 1998-2014 Total Gas (billion cu ft) 376 369 360 336 309 258 1996-2014 Nonassociated Gas (billion cu ft) 2 1 1 1 1 1 1996-2014 Associated Gas (billion cu ft) 374 368 359 335 308 25

  3. TX, State Offshore Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    0 0 1 0 0 0 1996-2014 Lease Condensate (million bbls) 2 0 1 0 1 0 1998-2014 Total Gas (billion cu ft) 61 29 29 24 15 10 1996-2014 Nonassociated Gas (billion cu ft) 59 29 25 22 13 10 1996-2014 Associated Gas (billion cu ft) 2 0 4 2 2 0

  4. CA, Coastal Region Onshore Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    51 199 248 293 280 281 1996-2014 Lease Condensate (million bbls) 0 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 22 35 20 242 123 225 1996-2014 Nonassociated Gas (billion cu ft) 0 1 0 0 0 0 1996-2014 Associated Gas (billion cu ft) 22 34 20 242 123 225

  5. CA, Los Angeles Basin Onshore Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    29 66 69 55 60 45 1996-2014 Lease Condensate (million bbls) 0 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 12 21 23 16 16 11 1996-2014 Nonassociated Gas (billion cu ft) 0 0 0 0 0 0 1996-2014 Associated Gas (billion cu ft) 12 21 23 16 16 11

  6. CA, San Joaquin Basin Onshore Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    146 210 163 226 214 216 1996-2014 Lease Condensate (million bbls) 0 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 401 359 319 81 96 55 1996-2014 Nonassociated Gas (billion cu ft) 311 253 265 36 61 37 1996-2014 Associated Gas (billion cu ft) 90 106 54 45 35 18

  7. CA, State Offshore Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    46 47 62 53 52 46 1996-2014 Lease Condensate (million bbls) 0 0 2 1 0 0 1998-2014 Total Gas (billion cu ft) 25 26 33 21 13 12 1996-2014 Nonassociated Gas (billion cu ft) 3 0 2 1 0 0 1996-2014 Associated Gas (billion cu ft) 22 26 31 20 13 12

  8. California Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    272 522 542 627 606 588 1996-2014 Lease Condensate (million bbls) 0 0 2 1 0 0 1998-2014 Total Gas (billion cu ft) 460 441 395 360 248 303 1996-2014 Nonassociated Gas (billion cu ft) 314 254 267 37 61 37 1996-2014 Associated Gas (billion cu ft) 146 187 128 323 187 266

  9. Federal Offshore, Pacific (California) Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    12 13 13 25 17 18 1996-2014 Lease Condensate (million bbls) 2 2 2 2 0 0 1998-2014 Total Gas (billion cu ft) 36 35 42 46 16 14 1996-2014 Nonassociated Gas (billion cu ft) 2 0 0 0 0 0 1996-2014 Associated Gas (billion cu ft) 34 35 42 46 16 14

  10. Florida Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    2 2 4 3 9 6 1996-2014 Lease Condensate (million bbls) 0 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 0 0 4 0 14 0 1996-2014 Nonassociated Gas (billion cu ft) 0 0 4 0 14 0 1996-2014 Associated Gas (billion cu ft) 0 0 0 0 0 0

  11. Illinois Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    4 15 0 0 0 0 1996-2005 Lease Condensate (million bbls) 0 0 0 0 0 1998-2004 Total Gas (billion cu ft) 1 1 0 0 0 1996-2004 Nonassociated Gas (billion cu ft) 0 0 0 0 0 1996-2004 Associated Gas (billion cu ft) 1 1

  12. Indiana Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    0 0 0 0 0 0 1996-2005 Lease Condensate (million bbls) 0 0 0 0 0 1998-2004 Total Gas (billion cu ft) 2 6 0 0 0 1996-2004 Nonassociated Gas (billion cu ft) 2 6 0 0 0 1996-2004 Associated Gas (billion cu ft) 0 0

  13. Kentucky Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    0 0 0 1 0 1996-2014 Lease Condensate (million bbls) 0 0 0 0 0 0 1998-2014 Total Gas (billion cu ft) 149 106 75 6 3 6 1996-2014 Nonassociated Gas (billion cu ft) 149 106 75 6 3 6 1996-2014 Associated Gas (billion cu ft) 0 0 0 0 0 0

  14. LA, State Offshore Proved Nonproducing Reserves

    U.S. Energy Information Administration (EIA) Indexed Site

    12 9 19 13 16 1996-2014 Lease Condensate (million bbls) 6 4 2 3 1 0 1998-2014 Total Gas (billion cu ft) 284 209 70 98 91 44 1996-2014 Nonassociated Gas (billion cu ft) 143 177 57 62 74 28 1996-2014 Associated Gas (billion cu ft) 141 32 13 36 17 16

  15. Modeling Cu Migration in CdTe Solar Cells Under Device-Processing and Long-Term Stability Conditions: Preprint

    SciTech Connect (OSTI)

    Teeter, G.; Asher, S.

    2008-05-01

    An impurity migration model for systems with material interfaces is applied to Cu migration in CdTe solar cells. In the model, diffusion fluxes are calculated from the Cu chemical potential gradient. Inputs to the model include Cu diffusivities, solubilities, and segregation enthalpies in CdTe, CdS and contact materials. The model yields transient and equilibrium Cu distributions in CdTe devices during device processing and under field-deployed conditions. Preliminary results for Cu migration in CdTe photovoltaic devices using available diffusivity and solubility data from the literature show that Cu segregates in the CdS, a phenomenon that is commonly observed in devices after back-contact processing and/or stress conditions.

  16. Preparation and structure characterization of SmCo{sub 5}(0001) epitaxial thin films grown on Cu(111) underlayers

    SciTech Connect (OSTI)

    Ohtake, Mitsuru; Nukaga, Yuri; Futamoto, Masaaki; Kirino, Fumiyoshi

    2009-04-01

    SmCo{sub 5}(0001) epitaxial films were prepared on Cu(111) single-crystal underlayers formed on Al{sub 2}O{sub 3}(0001) substrates at 500 deg. C. The nucleation and growth mechanism of (0001)-oriented SmCo{sub 5} crystal on Cu(111) underlayer is investigated and a method to control the nucleation is proposed. The SmCo{sub 5} epitaxial thin film formed directly on Cu underlayer consists of two types of domains whose orientations are rotated around the film normal by 30 deg. each other. By introducing a thin Co seed layer on the Cu underlayer, a SmCo{sub 5}(0001) single-crystal thin film is successfully obtained. Nucleation of SmCo{sub 5} crystal on Cu underlayer seems controllable by varying the interaction between the Cu underlayer and the SmCo{sub 5} layer.

  17. Metallic glass alloys of Zr, Ti, Cu and Ni

    DOE Patents [OSTI]

    Lin, X.; Peker, A.; Johnson, W.L.

    1997-04-08

    At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3} K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM{sub 1{minus}x}Ti{sub x}){sub a} Cu{sub b} (Ni{sub 1{minus}y}Co{sub y}){sub c} wherein x is from 0.1 to 0.3, y{center_dot}c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b. 2 figs.

  18. Highly-enhanced reflow characteristics of sputter deposited Cu alloy thin films for large scale integrated interconnections

    SciTech Connect (OSTI)

    Onishi, Takashi; Mizuno, Masao; Yoshikawa, Tetsuya; Munemasa, Jun; Mizuno, Masataka; Kihara, Teruo; Araki, Hideki; Shirai, Yasuharu

    2011-08-01

    An attempt to improve the reflow characteristics of sputtered Cu films was made by alloying the Cu with various elements. We selected Y, Sb, Nd, Sm, Gd, Dy, In, Sn, Mg, and P for the alloys, and ''the elasto-plastic deformation behavior at high temperature'' and ''the filling level of Cu into via holes'' were estimated for Cu films containing each of these elements. From the results, it was found that adding a small amount of Sb or Dy to the sputtered Cu was remarkably effective in improve the reflow characteristics. The microstructure and imperfections in the Cu films before and after high-temperature high-pressure annealing were investigated by secondary ion micrographs and positron annihilation spectroscopy. The results imply that the embedding or deformation mechanism is different for the Cu-Sb alloy films compared to the Cu-Dy alloy films. We consider that the former is embedded by softening or deformation of the Cu matrix, which has a polycrystalline structure, and the latter is embedded by grain boundary sliding.

  19. Effects of competing magnetic interactions on the electronic transport properties of CuCrSe{sub 2}

    SciTech Connect (OSTI)

    Tewari, Girish C.; Jawaharlal Nehru University, New Delhi 110067 ; Karppinen, Maarit; Rastogi, Ashok K.

    2013-02-15

    We have synthesized single-phase samples of the CuCrSe{sub 2} phase that exhibits hexagonal-rhombohedral layered crystal structure with space group R3m. Here we present a detailed study of electronic transport and magnetic properties of CuCrSe{sub 2}. We moreover investigate the heat capacity of CuCrSe{sub 2} in comparison to that of CuCrS{sub 2}. The electrical resistivity of CuCrSe{sub 2} shows metallic-like behavior down to 2 K, while the thermoelectric power is large around 100 {mu}V K{sup -1} at 300 K. A weak anomaly in resistivity and a rounded maximum in magnetic susceptibility are observed around 55 K. No sharp transition at 55 K is observed in the heat capacity of CuCrSe{sub 2}, rather a visible maximum is seen. At low temperatures from 2 to 14 K, the magnetic heat capacity follows T{sup 2}-dependence. We tentatively believe this behavior of CuCrSe{sub 2} to be due to competing magnetic interactions between intralayer Cr atoms. The ferromagnetic Cr-Se-Cr indirect exchange among intralayer Cr atoms is enhanced in the selenide compound (that is more metallic than the sulfide compound), and competes with the antiferromagnetic Cr-Cr direct interactions. The interlayer antiferromagnetic exchange through Cu atoms leads to magnetic ordering at low temperature at T{sub N}=55 K. - Graphical abstract: Comparison of magnetic properties of CuCrSe{sub 2} and CuCrS{sub 2} indicates a sharp cusp-like anomaly in magnetic susceptibility at the antiferromagnetic transition of CuCrS{sub 2} while the maximum of CuCrSe{sub 2} is well rounded. Magnetization is reversible after field-cooling (FC) and zero-field-cooling (ZFC) for both compounds. Highlights: Black-Right-Pointing-Pointer Layered CuCrSe{sub 2} can be synthesized in both fully and partially cation-ordered forms. Black-Right-Pointing-Pointer Contrary to previously believed insulating nature the cation-ordered phase is metallic. Black-Right-Pointing-Pointer Magnetic property of CuCrSe{sub 2} is somewhat different from that of CuCrS{sub 2}. Black-Right-Pointing-Pointer Magnetization and heat capacity data suggest complex short-range ordering for CuCrSe{sub 2}.

  20. Influence of lattice orientation on growth and structure of graphene on Cu(001)

    SciTech Connect (OSTI)

    Wofford, Joseph M.; Nie, Shu; Thrmer, Konrad; McCarty, Kevin F.; Dubon, Oscar D.

    2015-03-31

    We have used low-energy electron microscopy (LEEM) and diffraction (LEED) to examine the significance of lattice orientation in graphene growth on Cu(0 0 1). Individual graphene domains undergo anisotropic growth on the Cu surface, and develop into lens shapes with their long axes roughly aligned with Cu <1 0 0> in-plane directions. Furthermore, the long axis of a lens-shaped domain is only rarely oriented along a C <1 1> direction, suggesting that carbon attachment at zigzag graphene island edges is unfavorable. A kink-mediated adatom attachment process is consistent with the behavior observed here and reported in the literature. Likewise, the details of the ridged moir pattern formed by the superposition of the graphene lattice on the (0 0 1) Cu surface also evolve with the graphene lattice orientation, and are predicted well by a simple geometric model. Managing the kink-mediated growth mode of graphene on Cu(0 0 1) will be necessary for the continued improvement of this graphene synthesis technique.

  1. Kondo-lattice formation in cubic-phase YbCu{sub 5}

    SciTech Connect (OSTI)

    Tsujii, N.; He, J.; Amita, F.; Yoshimura, K.; Kosuge, K.; Michor, H.; Hilscher, G.; Goto, T.

    1997-10-01

    The YbCu{sub 5} phase with C15b structure has been prepared by a high-pressure technique, and its physical properties have been investigated. The temperature dependence of magnetic susceptibility, electrical resistivity, and specific heat show Kondo-lattice formation. Furthermore, a heavy Fermi-liquid state without magnetic ordering down to 2.0 K is found to evolve below about 6 K. The electronic specific heat coefficient {gamma} is enhanced to values as large as to 550 mJ/molthinspK{sup 2}. The magnetization measured up to 40 T at 1.6 K has a field dependence which is expected for a Kondo system when the total angular momentum is J{gt}1. All results are in good agreement with the extrapolation of the previous results of YbCu{sub 5{minus}x}Ag{sub x} (0.125{le}x{le}1.0) for x{r_arrow}0. The concentration dependence of characteristic temperatures of YbCu{sub 5{minus}x}Ag{sub x} can be quantitatively explained by the chemical pressure effect within the compressible Kondo model for the full range of Ag concentration ( 0.0{le}x{le}1.0). The origins of Kondo-lattice formation in YbCu{sub 4}Ag and the valence transition in YbCu{sub 4}In are discussed. {copyright} {ital 1997} {ital The American Physical Society}

  2. Structure and Bonding of Tungsten Oxide Clusters on Nanostructured Cu-O Surfaces

    SciTech Connect (OSTI)

    Wagner, Margareta; Surnev, Svetlozar; Ramsey, Michael; Barcaro, Giovanni; Sementa, Luca; Negreiros, Fabio R.; Fortunelli, Alessandro; Dohnalek, Zdenek; Netzer, Falko P.

    2011-12-01

    (WO3)3 gas-phase clusters generated via vacuum sublimation are deposited under UHV and low temperature (5 K) conditions on a Cu(110) 'stripe' phase consisting of alternating Cu-O (2x1) and clean Cu regions. STM imaging shows that the clusters adsorb as intact units on both substrates, and the suggested adsorption geometries are confirmed by density-functional (DF) simulations. On the clean surface the overall distortion is minor and we are able to image the nodal structure of an individual molecular orbital in the STM at low bias, whereas on the Cu-O surface both the clusters and the substrate are significantly distorted, due to the strong oxygen affinity of W atoms. On both surfaces cluster and Cu electronic states are appreciably mixed, and electron charge is donated by the surface to the cluster. The experimentally STS-determined DOS signature of the adsorption complex consists in two peaks across the Fermi energy and is well reproduced by the DF calculations.

  3. Density functional study of CaN mono and bilayer on Cu(001)

    SciTech Connect (OSTI)

    Zahedifar, Maedeh; Hashemifar, S. Javad, E-mail: hashemifar@cc.iut.ac.ir; Akbarzadeh, Hadi [Department of Physics, Isfahan University of Technology, Isfahan, 84156-83111 (Iran, Islamic Republic of)] [Department of Physics, Isfahan University of Technology, Isfahan, 84156-83111 (Iran, Islamic Republic of)

    2014-01-15

    Density functional - pseudopotential calculations are performed to provide first-principles insights into magnetic behaviour of bulk CaN and CaN monolayers on Cu(001) in the rock-salt (RS) and zinc-blende (ZB) structures. Our results indicate that both RS- and ZB-CaN exhibit half-metallic ferromagnetism originated from the incomplete 2p shell of the nitrogen ion. In contrast to the bulk CaN, the CaN monolayers on Cu(001) generally favor ZB structure. We argue that the more stable ZB-CaN thin films on Cu(001) are nonmagnetic, because of strong Cu-N bonding at the interface, while the less stable Ca terminated ZB-CaN thin films exhibit half-metallic ferromagnetism. The transition path between the high energy ferromagnetic and the stable nonmagnetic configurations of the ZB-CaN monolayer on Cu(001) are studied by using the nudged elastic band method. We observe a two stages transition and an activation barrier of about 1.18 eV in the minimum energy path of this transition.

  4. Exponentially decaying magnetic coupling in sputtered thin film FeNi/Cu/FeCo trilayers

    SciTech Connect (OSTI)

    Wei, Yajun Akansel, Serkan; Thersleff, Thomas; Brucas, Rimantas; Lansaker, Pia; Leifer, Klaus; Svedlindh, Peter; Harward, Ian; Celinski, Zbigniew; Ranjbar, Mojtaba; Dumas, Randy K.; Jana, Somnath; Pogoryelov, Yevgen; Karis, Olof; Åkerman, Johan

    2015-01-26

    Magnetic coupling in trilayer films of FeNi/Cu/FeCo deposited on Si/SiO{sub 2} substrates have been studied. While the thicknesses of the FeNi and FeCo layers were kept constant at 100 Å, the thickness of the Cu spacer was varied from 5 to 50 Å. Both hysteresis loop and ferromagnetic resonance results indicate that all films are ferromagnetically coupled. Micromagnetic simulations well reproduce the ferromagnetic resonance mode positions measured by experiments, enabling the extraction of the coupling constants. Films with a thin Cu spacer are found to be strongly coupled, with an effective coupling constant of 3 erg/cm{sup 2} for the sample with a 5 Å Cu spacer. The strong coupling strength is qualitatively understood within the framework of a combined effect of Ruderman-Kittel-Kasuya-Yosida and pinhole coupling, which is evidenced by transmission electron microscopy analysis. The magnetic coupling constant surprisingly decreases exponentially with increasing Cu spacer thickness, without showing an oscillatory thickness dependence. This is partially connected to the substantial interfacial roughness that washes away the oscillation. The results have implications on the design of multilayers for spintronic applications.

  5. Energetics of the formation of CuAg coreshell nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chandross, Michael

    2014-10-06

    Our work presents molecular dynamics and Monte Carlo simulations aimed at developing an understanding of the formation of coreshell CuAg nanoparticles. The effects of surface and interfacial energies were considered and used to form a phenomenological model that calculates the energy gained upon the formation of a coreshell structure from two previously distinct, non-interacting nanoparticles. In most cases, the coreshell structure was found to be energetically favored. Specifically, the difference in energy as a function of the radii of the individual Cu and Ag particles was examined, with the assumption that a coreshell structure forms. In general, it was foundmorethat the energetic gain from forming such a structure increased with increasing size of the initial Ag particle. This result was interpreted as a result of the reduction in surface energy. Moreover, for two separate particles, both Cu and Ag contribute to the surface energy; however, for a coreshell structure, the only contribution to the surface energy is from the Ag shell and the Cu contribution is changed to a CuAg interfacial energy, which is always smaller.less

  6. Influence of lattice orientation on growth and structure of graphene on Cu(001)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wofford, Joseph M.; Nie, Shu; Thürmer, Konrad; McCarty, Kevin F.; Dubon, Oscar D.

    2015-03-31

    We have used low-energy electron microscopy (LEEM) and diffraction (LEED) to examine the significance of lattice orientation in graphene growth on Cu(0 0 1). Individual graphene domains undergo anisotropic growth on the Cu surface, and develop into lens shapes with their long axes roughly aligned with Cu <1 0 0> in-plane directions. Furthermore, the long axis of a lens-shaped domain is only rarely oriented along a C <1 1> direction, suggesting that carbon attachment at “zigzag” graphene island edges is unfavorable. A kink-mediated adatom attachment process is consistent with the behavior observed here and reported in the literature. Likewise, themore » details of the ridged moiré pattern formed by the superposition of the graphene lattice on the (0 0 1) Cu surface also evolve with the graphene lattice orientation, and are predicted well by a simple geometric model. Managing the kink-mediated growth mode of graphene on Cu(0 0 1) will be necessary for the continued improvement of this graphene synthesis technique.« less

  7. Enhanced irreversibility by crystal defects in the Bi-Sr-Ca-Cu-O system

    SciTech Connect (OSTI)

    Salem-Sugui, S. Jr.; Shi, Donglu; McFarland, S.E.

    1991-04-01

    We measured magnetic irreversibility, H*(T), in liquid-quenched Bi-Sr-Ca-Cu-O samples with various microstructures at high applied field (up to 7 T). We found that H*(T) is considerably increased in the Bi{sub 2}Sr{sub 2}Ca{sub 3}Cu{sub 4}O{sub x} (2234) sample with a large amount of crystal defects, including severe lattice distortion and calcium and copper rich precipitates. We argue that the lattice distortion may affect the degree of anisotropy and the Josephson coupling between the Cu-O layers, which in turn enhance the irreversibility in the Bi-Sr-Ca-Cu-O system. A critical current density, J{sub c}, of 8 {times} 10{sup 4} A/cm{sup 2} at 8 kG and 40 K was obtained in the 2234 sample with many defects, while the J{sub c} dropped significantly at the same temperature and field in the near stoichiometry Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} (2223) sample with a uniform microstructure.

  8. Theoretical calculation of the melting curve of Cu-Zr binary alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gunawardana, K. G.S.H.; Wilson, S. R.; Mendelev, M. I.; Song, Xueyu

    2014-11-14

    Helmholtz free energies of the dominant binary crystalline solids found in the Cu-Zr system at high temperatures close to the melting curve are calculated. This theoretical approach combines fundamental measure density functional theory (applied to the hard-sphere reference system) and a perturbative approach to include the attractive interactions. The studied crystalline solids are Cu(fcc), Cu51Zr14(β), CuZr(B2), CuZr2(C11b), Zr(hcp), and Zr(bcc). The calculated Helmholtz free energies of crystalline solids are in good agreement with results from molecular-dynamics (MD) simulations. Using the same perturbation approach, the liquid phase free energies are calculated as a function of composition and temperature, from which themore » melting curve of the entire composition range of this system can be obtained. Phase diagrams are determined in this way for two leading embedded atom method potentials, and the results are compared with experimental data. Furthermore, theoretical melting temperatures are compared both with experimental values and with values obtained directly from MD simulations at several compositions.« less

  9. Theoretical calculation of the melting curve of Cu-Zr binary alloys

    SciTech Connect (OSTI)

    Gunawardana, K. G.S.H.; Wilson, S. R.; Mendelev, M. I.; Song, Xueyu

    2014-11-14

    Helmholtz free energies of the dominant binary crystalline solids found in the Cu-Zr system at high temperatures close to the melting curve are calculated. This theoretical approach combines fundamental measure density functional theory (applied to the hard-sphere reference system) and a perturbative approach to include the attractive interactions. The studied crystalline solids are Cu(fcc), Cu51Zr14(β), CuZr(B2), CuZr2(C11b), Zr(hcp), and Zr(bcc). The calculated Helmholtz free energies of crystalline solids are in good agreement with results from molecular-dynamics (MD) simulations. Using the same perturbation approach, the liquid phase free energies are calculated as a function of composition and temperature, from which the melting curve of the entire composition range of this system can be obtained. Phase diagrams are determined in this way for two leading embedded atom method potentials, and the results are compared with experimental data. Furthermore, theoretical melting temperatures are compared both with experimental values and with values obtained directly from MD simulations at several compositions.

  10. Impact of sulfation and desulfation on NOx reduction using Cu-chabazite SCR catalysts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brookshear, Daniel William; Nam, Jeong -Gil; Nguyen, Ke; Toops, Todd J.; Binder, Andrew J.

    2015-06-05

    This bench reactor study investigates the impact of gaseous sulfur on the NOx reduction activity of Cu-chabazite SCR (Cu-CHA) catalysts at SO2 concentrations representative of marine diesel engine exhaust. After two hours of 500 ppm SO2 exposure at 250 and 400 °C in the simulated diesel exhaust gases, the NOx reduction activity of the sulfated Cu-CHA SCR catalysts is severely degraded at evaluation temperatures below 250 °C; however, above 250 °C the impact of sulfur exposure is minimal. EPMA shows that sulfur is located throughout the washcoat and along the entire length of the sulfated samples. Interestingly, BET measurements revealmore » that the sulfated samples have a 20% decrease in surface area. Moreover, the sulfated samples show a decrease in NOx/nitrate absorption during NO exposure in a DRIFTS reactor which suggests that Cu sites in the catalyst are blocked by the presence of sulfur. SO2 exposure also results in an increase in NH3 storage capacity, possibly due to the formation of ammonium sulfate species in the sulfated samples. In all cases, lean thermal treatments as low as 500 °C reverse the effects of sulfur exposure and restore the NOx reduction activity of the Cu-CHA catalyst to that of the fresh condition.« less

  11. Impact of Sulfation and Desulfation on NOx Reduction Using Cu-Chabazite SCR Catalysts

    SciTech Connect (OSTI)

    Brookshear, Daniel W; Nam, Jeong-Gil; Nguyen, Ke; Toops, Todd J; Binder, Andrew J

    2015-01-01

    This bench reactor study investigates the impact of gaseous sulfur on the NOx reduction activity of Cu-chabazite SCR (Cu-CHA) catalysts at SO2 concentrations representative of marine diesel engine exhaust. After two hours of 500 ppm SO2 exposure at 250 and 400 C in the simulated diesel exhaust gases, the NOx reduction activity of the sulfated Cu-CHA SCR catalysts is severely degraded at evaluation temperatures below 250 C; however, above 250 C the impact of sulfur exposure is minimal. EPMA shows that sulfur is located throughout the washcoat and along the entire length of the sulfated samples. Interestingly, BET measurements reveal that the sulfated samples have a 20% decrease in surface area. Furthermore, the sulfated samples show a decrease in NOx/nitrate absorption during NO exposure in a DRIFTS reactor which suggests that Cu sites in the catalyst are blocked by the presence of sulfur. SO2 exposure also results in an increase in NH3 storage capacity, possibly due to the formation of ammonium sulfate species in the sulfated samples. In all cases, lean thermal treatments as low as 500 C reverse the effects of sulfur exposure and restore the NOx reduction activity of the Cu-CHA catalyst to that of the fresh condition.

  12. Significant enhancement of the strength-to-resistivity ratio by using nanotwins in epitaxial Cu films

    SciTech Connect (OSTI)

    Misra, Amit; Ronningh, Filip; Anderoglu, Osman; Zhang, X

    2008-01-01

    Epitaxial nanotwinned Cu films, with an average twin spacing ranging from 7 to 16 nm, exhibit a high ratio of strength-to-electrical resisitivity, -400 MPa({mu}{Omega}cm){sup -1}. The hardness of these Cu films approaches 2.8 GPa, and their electrical resistivities are comparable to that of oxygen-free high-conductivity Cu. Compared to high-angle grain boundaries, coherent twin interfaces possess inherently high resistance to the transmission of single dislocations, and yet an order of magnitude lower electron scattering coefficient, determined to be 1.5-5 x 10{sup -7} {mu}{Omega}cm{sup 2} at room temperature. Analytical studies as well as experimental results show that, in polycrystalline Cu, grain refinement leads to a maximum of the strength-to-resistivity ratio, -250 MPa({mu}{Omega}cm){sup -1}, when grain size is comparable to the mean-free path of electrons. However, in twinned Cu, such a ratio increases continuously with decreasing twin spacing down to a few nanometers. Hence nanoscale growth twins are more effective to achieve a higher strength-to-resistivity ratio than high-angle grain boundaries.

  13. A reactive magnetron sputtering route for attaining a controlled core-rim phase partitioning in Cu{sub 2}O/CuO thin films with resistive switching potential

    SciTech Connect (OSTI)

    Ogwu, A. A.; Darma, T. H.

    2013-05-14

    The achievement of a reproducible and controlled deposition of partitioned Cu{sub 2}O/CuO thin films by techniques compatible with ULSI processing like reactive magnetron sputtering has been reported as an outstanding challenge in the literature. This phase partitioning underlies their performance as reversible resistive memory switching devices in advanced microelectronic applications of the future. They are currently fabricated by thermal oxidation and chemical methods. We have used a combination of an understanding from plasma chemistry, thermo-kinetics of ions, and rf power variation during deposition to successfully identify a processing window for preparing partitioned Cu{sub 2}O/CuO films. The production of a core rich Cu{sub 2}O and surface rich Cu{sub 2}O/CuO mixture necessary for oxygen migration during resistive switching is confirmed by XRD peaks, Fourier transform infra red Cu (I)-O vibrational modes, XPS Cu 2P{sub 3/2} and O 1S peak fitting, and a comparison of satellite peak ratio's in Cu 2P{sub 3/2} fitted peaks. We are proposing based on the findings reported in this paper that an XPS satellite peak intensity(I{sub s}) to main peak intensity ratio (I{sub m}) {<=} 0.45 as an indicator of a core rich Cu{sub 2}O and surface rich Cu{sub 2}O/CuO formation in our prepared films. CuO is solely responsible for the satellite peaks. This is explained on the basis that plasma dissociation of oxygen will be limited to the predominant formation of Cu{sub 2}O under certain plasma deposition conditions we have identified in this paper, which also results in a core-rim phase partitioning. The deposited films also followed a Volmer-Weber columnar growth mode, which could facilitate oxygen vacancy migration and conductive filaments at the columnar interfaces. This is further confirmed by optical transmittance and band-gap measurements using spectrophotometry. This development is expected to impact on the early adoption of copper oxide based resistive memory electronic switching devices in advanced electronic devices of the future. The relative abundance of copper is another major complementary driver for the interest in copper oxide films.

  14. Structural and magnetic phase transitions in CeCu6-xTx (T = Ag,Pd)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Poudel, Lekhanath N.; De la cruz, Clarina; Payzant, E. Andrew; Koehler, Michael R.; May, Andrew F.; Garlea, Vasile O.; Taylor, Alice E.; Parker, David S.; Cao, Huibo B.; McGuire, Michael A.; et al

    2015-12-15

    The structural and the magnetic properties of CeCu6-xAgx (0 ≤ x ≤ 0.85) and CeCu6-xPdx (0 ≤ x ≤ 0.4) have been studied using neutron diffraction, resonant ultrasound spectroscopy (RUS), x-ray diffraction measurements, and first principles calculations. The structural and magnetic phase diagrams of CeCu6-xAgx and CeCu6-xPdx as a function of Ag/Pd composition are reported. The end member, CeCu6, undergoes a structural phase transition from an orthorhombic (Pnma) to a monoclinic (P21/c) phase at 240 K. In CeCu6-xAgx, the structural phase transition temperature (Ts) decreases linearly with Ag concentration and extrapolates to zero at xS ≈ 0.1. The structural transitionmore » in CeCu6-xPdx remains unperturbed with Pd substitution within the range of our study. The lattice constant b slightly decreases with Ag/Pd doping, whereas a and c increase with an overall increase in the unit cell volume. Both systems, CeCu6-xAgx and CeCu6-xPdx, exhibit a magnetic quantum critical point (QCP), at x ≈ 0.2 and x ≈ 0.05, respectively. Near the QCP, long range antiferromagnetic ordering takes place at an incommensurate wave vector (δ1 0 δ2), where δ1 ~ 0.62, δ2 ~ 0.25, x = 0.125 for CeCu6-xPdx and δ1 ~ 0.64, δ2 ~ 0.3, x = 0.3 for CeCu6-xAgx. As a result, the magnetic structure consists of an amplitude modulation of the Ce moments which are aligned along the c axis of the orthorhombic unit cell.« less

  15. Stable N-CuInSe.sub.2 /iodide-iodine photoelectrochemical cell

    DOE Patents [OSTI]

    Cahen, David (Rehovot, IL); Chen, Yih W. (Lakewood, CO)

    1985-01-01

    In a photoelectrochemical solar cell, stable output and solar efficiency in excess of 10% are achieved with a photoanode of n-CuInSe.sub.2 electrode material and an iodine/iodide redox couple used in a liquid electrolyte. The photoanode is prepared by treating the electrode material by chemical etching, for example in Br.sub.2 /MeOH; heating the etched electrode material in air or oxygen; depositing a surface film coating of indium on the electrode material after the initial heating; and thereafter again heating the electrode material in air or oxygen to oxidize the indium. The electrolyte is treated by the addition of Cu.sup.+ or Cu.sup.2+ salts and In.sup.3+ salts.

  16. Stable n-CuInSe/sub 2/iodide-iodine photoelectrochemical cell

    DOE Patents [OSTI]

    Cahen, D.; Chen, Y.W.

    1984-09-20

    In a photoelectrochemical solar cell, stable output and solar efficiency in excess of 10% are achieved with a photoanode of n-CuInSe/sub 2/ electrode material and an iodine/iodide redox couple used in a liquid electrolyte. The photoanode is prepared by treating the electrode material by chemical etching, for example in Br/sub 2//MeOH; heating the etched electrode material in air or oxygen; depositing a surface film coating of indium on the electrode material after the initial heating; and thereafter again heating the electrode material in air or oxygen to oxidize the indium. The electrolyte is treated by the addition of Cu/sup +/ or Cu/sup 2 +/ salts and in In/sup 3 +/ salts.

  17. Interpretation of thermoelectric properties of Cu substituted LaCoO{sub 3} ceramics

    SciTech Connect (OSTI)

    Choudhary, K. K.; Kaurav, N.; Sharma, U.; Ghosh, S. K.

    2014-04-24

    The thermoelectric properties of LaCo{sub 1?x}Cu{sub x}O{sub 3??} is theoretically analyzed, it is observed that thermoelectric figure of merit ZT (=S{sup 2}?T/?) is maximized by Cu substitution in LaCoO{sub 3} Ceramics at x=0.15. The lattice thermal conductivity and thermoelectric power were estimated by the scattering of phonons with defects, grain boundaries, electrons and phonons to evaluate the thermoelectric properties. We found that Cu substitution increase the phonon scattering with grain boundaries and defects which significantly increase the thermoelectric power and decrease the thermal conductivity. The present numerical analysis will help in designing more efficient thermoelectric materials.

  18. Optical and quantum efficiency analysis of (Ag,Cu)(In,Ga)Se2 absorber layers

    SciTech Connect (OSTI)

    Boyle, Jonathan; Hanket, Gregory; Shafarman, William

    2009-06-09

    (Ag,Cu)(In,Ga)Se2 thin films have been deposited by elemental co-evaporation over a wide range of compositions and their optical properties characterized by transmission and reflection measurements and by relative shift analysis of quantum efficiency device measurements. The optical bandgaps were determined by performing linear fits of (?h?)2 vs. h?, and the quantum efficiency bandgaps were determined by relative shift analysis of device curves with fixed Ga/(In+Ga) composition, but varying Ag/(Cu+Ag) composition. The determined experimental optical bandgap ranges of the Ga/(In+Ga) = 0.31, 0.52, and 0.82 groups, with Ag/(Cu+Ag) ranging from 0 to 1, were 1.19-1.45 eV, 1.32-1.56 eV, and 1.52-1.76 eV, respectively. The optical bowing parameter of the different Ga/(In+Ga) groups was also determined.

  19. Role of polycrystallinity in CdTe and CuInSe sub 2 photovoltaic cells

    SciTech Connect (OSTI)

    Sites, J.R. )

    1991-01-01

    The polycrystalline nature of thin-film CdTe and CuInSe{sub 2} solar cells continues to be a major factor in several individual losses that limit overall cell efficiency. This report describes progress in the quantitative separation of these losses, including both measurement and analysis procedures. It also applies these techniques to several individual cells to help document the overall progress with CdTe and CuInSe{sub 2} cells. Notably, CdTe cells from Photon Energy have reduced window photocurrent losses to 1 mA/Cm{sup 2}; those from the University of South Florida have achieved a maximum power voltage of 693 mV; and CuInSe{sub 2} cells from International Solar Electric Technology have shown a hole density as high as 7 {times} 10{sup 16} cm{sup {minus}3}, implying a significant reduction in compensation. 9 refs.

  20. Enhanced spin Hall effect by electron correlations in CuBi alloys

    SciTech Connect (OSTI)

    Gu, Bo Xu, Zhuo; Mori, Michiyasu; Maekawa, Sadamichi; Ziman, Timothy

    2015-05-07

    A recent experiment in CuBi alloys obtained a large spin Hall angle (SHA) of ?0.24 (Niimi et al., Phys. Rev. Lett. 109, 156602 (2012)). We find that the SHA can be dramatically enhanced by Bi impurities close to the Cu surface. The mechanisms of this enhancement are two-fold. One is that the localized impurity state on surface has a decreased hybridization and combined with Coulomb correlation effect. The other comes from the low-dimensional state of conduction electrons on surface, which results in a further enhancement of skew scattering by impurities. Furthermore, we note that a discrepancy in sign of SHA between the experiment and previous theories is simply caused by different definitions of SHA. This re-establishes skew scattering as the essential mechanism underlying the spin Hall effect in CuBi alloys.

  1. Effect of Cu addition on the martensitic transformation of powder metallurgy processed TiNi alloys

    SciTech Connect (OSTI)

    Kim, Yeon-wook; Choi, Eunsoo

    2014-10-15

    Highlights: M{sub s} of Ti{sub 50}Ni{sub 50} powders is 22 C, while M{sub s} of SPS-sintered porous bulk increases up to 50 C. M{sub s} of Ti{sub 50}Ni{sub 40}Cu{sub 20} porous bulk is only 2 C higher than that of the powders. Recovered stain of porous TiNi and TiNiCu alloy is more than 1.5%. - Abstract: Ti{sub 50}Ni{sub 50} and Ti{sub 50}Ni{sub 30}Cu{sub 20} powders were prepared by gas atomization and their transformation behaviors were examined by means of differential scanning calorimetry and X-ray diffraction. One-step B2B19 transformation occurred in Ti{sub 50}Ni{sub 50} powders, while Ti{sub 50}Ni{sub 30}Cu{sub 20} powders showed B2B19 transformation behavior. Porous bulks with 24% porosity were fabricated by spark plasma sintering. The martensitic transformation start temperature (50 C) of Ti{sub 50}Ni{sub 50} porous bulk is much higher than that (22 C) of the as-solidified powders. However, the martensitic transformation start temperature (35 C) of Ti{sub 50}Ni{sub 30}Cu{sub 20} porous bulk is almost the same as that (33 C) of the powders. When the specimens were compressed to the strain of 8% and then unloaded, the residual strains of Ti{sub 50}Ni{sub 50} and Ti{sub 50}Ni{sub 30}Cu{sub 20} alloy bulks were 3.95 and 3.7%, respectively. However, these residual strains were recovered up to 1.7% after heating by the shape memory phenomenon.

  2. Method of producing superconducting fibers of YBA2CU30X

    DOE Patents [OSTI]

    Schwartzkopf, Louis A. (Mankato, MN); Ostenson, Jerome E. (Ames, IA); Finnemore, Douglas K. (Ames, IA)

    1990-11-13

    Fibers of YBa.sub.2 Cu.sub.3 O.sub.x have been produce by pendant drop melt extraction. This technique involves the end of a rod of YBa.sub.2 Cu.sub.3 O.sub.x melted with a hydrogen-oxygen torch, followed by lowering onto the edge of a spinning wheel. The fibers are up to 10 cm in length with the usual lateral dimensions, ranging from 20 .mu.m to 125 .mu.m. The fibers require a heat treatment to make them superconducting.

  3. Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation

    SciTech Connect (OSTI)

    Grabow, Lars C.; Mavrikakis, Manos

    2011-03-04

    We present a comprehensive mean-field microkinetic model for the methanol synthesis and water-gas-shift (WGS) reactions that includes novel reaction intermediates, such as formic acid (HCOOH) and hydroxymethoxy (CH?O?) and allows for the formation of formic acid (HCOOH), formaldehyde (CH?O), and methyl formate (HCOOCH?) as byproducts. All input model parameters were initially derived from periodic, self-consistent, GGA-PW91 density functional theory calculations on the Cu(111) surface and subsequently fitted to published experimentalmethanol synthesis rate data, which were collected under realistic conditions on a commercial Cu/ZnO/Al?O? catalyst. We find that the WGS reaction follows the carboxyl (COOH)-mediated path and that both CO and CO? hydrogenation pathways are active for methanol synthesis. Under typical industrial methanol synthesis conditions, CO? hydrogenation is responsible for ?2/3 of the methanol produced. The intermediates of the CO? pathway for methanol synthesis include HCOO*, HCOOH*, CH?O?*, CH?O*, and CH?O*. The formation of formate (HCOO*) from CO?* and H* on Cu(111) does not involve an intermediate carbonate (CO?*) species, and hydrogenation of HCOO* leads to HCOOH* instead of dioxymethylene (H?CO?*). The effect of CO is not only promotional; CO* is also hydrogenated in significant amounts to HCO*, CH?O *, CH?O*, and CH?OH*. We considered two possibilities for CO promotion: (a) removal of OH* via COOH* to form CO? and hydrogen (WGS), and (b) CO-assisted hydrogenation of various surface intermediates, with HCO* being the H-donor. Only the former mechanism contributes to methanol formation, but its effect is small compared with that of direct CO hydrogenation to methanol. Overall, methanol synthesis rates are limited by methoxy (CH?O*) formation at low CO?/(CO+CO?) ratios and by CH?O* hydrogenation in CO?-rich feeds. CH?O* hydrogenation is the common slow step for both the CO and the CO? methanol synthesis routes; the relative contribution of each route is determined by their respective slow steps HCO*+H*?CH?O*+* and HCOOH*+H*?CH?O?*+* as well as by feed composition and reaction conditions. An analysis of the fitted parameters for a commercial Cu/ZnO/Al?O? catalyst suggests that a more open Cu surface, for example, Cu(110), Cu(100), and Cu(211) partially covered by oxygen, may provide a better model for the active site of methanol synthesis, but our studies cannot exclude a synergistic effect with the ZnO support.

  4. Origin of Novel Diffusions of Cu and Ag in Semiconductors: The Case of CdTe

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Origin of Novel Diffusions of Cu and Ag in Semiconductors: The Case of CdTe « Prev Next » Title: Origin of Novel Diffusions of Cu and Ag in Semiconductors: The Case of CdTe Authors: Ma, Jie ; Wei, Su-Huai Publication Date: 2013-06-04 OSTI Identifier: 1102795 Type: Publisher's Accepted Manuscript Journal Name: Physical Review Letters Additional Journal Information: Journal Volume: 110; Journal Issue: 23; Journal ID: ISSN 0031-9007 Publisher: American Physical

  5. Performance and mix measurements of indirect drive Cu doped Be implosions

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Performance and mix measurements of indirect drive Cu doped Be implosions Citation Details In-Document Search Title: Performance and mix measurements of indirect drive Cu doped Be implosions Authors: Casey, D T ; Woods, T ; Smalyuk, V A ; Hurricane, O A ; Glebov, V Y ; Stoeckl, C ; Theobald, W ; Wallace, R ; Nikroo, A ; Shuldberg, C ; Wu, K J ; Frenje, J A ; Perez, F ; Landen, O L ; Remington, B ; Glendinning, G Publication Date: 2014-09-18 OSTI

  6. High-power Laser Interaction With Low-density C-Cu Foams (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect High-power Laser Interaction With Low-density C-Cu Foams Citation Details In-Document Search Title: High-power Laser Interaction With Low-density C-Cu Foams Authors: Perez, F ; Colvin, J D ; May, M J ; Charnvanichborikarn, S ; Kucheyev, S O ; Felter, T E ; Fournier, K B Publication Date: 2015-08-24 OSTI Identifier: 1234590 Report Number(s): LLNL-JRNL-677081 DOE Contract Number: AC52-07NA27344 Resource Type: Journal Article Resource Relation: Journal Name: Physics of

  7. Magnetization of underdoped YBa 2 Cu 3 O y above the irreversibility field

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Magnetization of underdoped YBa 2 Cu 3 O y above the irreversibility field Citation Details In-Document Search This content will become publicly available on November 22, 2016 Title: Magnetization of underdoped YBa 2 Cu 3 O y above the irreversibility field Authors: Yu, Jing Fei ; Ramshaw, B. J. ; Kokanović, I. ; Modic, K. A. ; Harrison, N. ; Day, James ; Liang, Ruixing ; Hardy, W. N. ; Bonn, D. A. ; McCollam, A. ; Julian, S. R. ; Cooper, J. R.

  8. Measurement of Cross Sections for the 63Cu(alpha,gamma)67Ga Reaction from

    Office of Scientific and Technical Information (OSTI)

    5.9-8.7 MeV (Conference) | SciTech Connect Conference: Measurement of Cross Sections for the 63Cu(alpha,gamma)67Ga Reaction from 5.9-8.7 MeV Citation Details In-Document Search Title: Measurement of Cross Sections for the 63Cu(alpha,gamma)67Ga Reaction from 5.9-8.7 MeV Authors: Basunia, M S ; Norman, E B ; Shugart, H A ; Smith, A R ; Dolinski, M J ; Quiter, B J Publication Date: 2004-09-16 OSTI Identifier: 15014568 Report Number(s): UCRL-PROC-206626 DOE Contract Number: W-7405-ENG-48

  9. Measurement of cross sections for the Cu-63(alpha,gamma)Ga-67 reaction from

    Office of Scientific and Technical Information (OSTI)

    5.9-8.7 MeV (Journal Article) | SciTech Connect Journal Article: Measurement of cross sections for the Cu-63(alpha,gamma)Ga-67 reaction from 5.9-8.7 MeV Citation Details In-Document Search Title: Measurement of cross sections for the Cu-63(alpha,gamma)Ga-67 reaction from 5.9-8.7 MeV Authors: Basunia, M S ; Norman, E B ; Shugart, H A ; Smith, A R ; Dolinski, M J ; Quiter, B J Publication Date: 2005-02-24 OSTI Identifier: 15020440 Report Number(s): UCRL-JRNL-210075 DOE Contract Number:

  10. Competing charge, spin, and superconducting orders in underdoped YBa 2 Cu 3

    Office of Scientific and Technical Information (OSTI)

    O y (Journal Article) | SciTech Connect YBa 2 Cu 3 O y Citation Details In-Document Search Title: Competing charge, spin, and superconducting orders in underdoped YBa 2 Cu 3 O y Authors: Hücker, M. ; Christensen, N. B. ; Holmes, A. T. ; Blackburn, E. ; Forgan, E. M. ; Liang, Ruixing ; Bonn, D. A. ; Hardy, W. N. ; Gutowski, O. ; Zimmermann, M. v. ; Hayden, S. M. ; Chang, J. Publication Date: 2014-08-21 OSTI Identifier: 1180599 Grant/Contract Number: AC02-06CH11357; AC02-98CH10886 Type:

  11. Competing charge, spin, and superconducting orders in underdoped YBa2Cu3Oy

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect YBa2Cu3Oy Citation Details In-Document Search Title: Competing charge, spin, and superconducting orders in underdoped YBa2Cu3Oy Authors: Huecker M. ; Christensen, N. B. ; Holmes, A. T. ; Blackburn, E. ; Forgan, E. M. ; Liang, Ruixing ; Bonn, D. A. ; Hardy, W. N. ; Gutowski, O. ; v Zimmermann, M. ; Hayden, S. M. ; Chang, J. Publication Date: 2014-08-01 OSTI Identifier: 1178217 Report Number(s): BNL--106215-2014-JA R&D Project: PO010; KC0201060 DOE

  12. Multiscale twin hierarchy in NiMnGa shape memory alloys with Fe and Cu

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Multiscale twin hierarchy in NiMnGa shape memory alloys with Fe and Cu Citation Details In-Document Search Title: Multiscale twin hierarchy in NiMnGa shape memory alloys with Fe and Cu Authors: Barabash, Rozaliya I. ; Barabash, Oleg M. ; Popov, Dmitry ; Shen, Guoyin ; Park, Changyong ; Yang, Wenge [1] ; ORNL) [2] ; CIW) [2] ; CHPSTAR- China) [2] + Show Author Affiliations (Tennessee-K) ( Publication Date: 2015-04-01 OSTI Identifier:

  13. Yb-Zn-Al ternary system: CaCu{sub 5}-type derived compounds in the

    Office of Scientific and Technical Information (OSTI)

    zinc-rich corner (Journal Article) | SciTech Connect Yb-Zn-Al ternary system: CaCu{sub 5}-type derived compounds in the zinc-rich corner Citation Details In-Document Search Title: Yb-Zn-Al ternary system: CaCu{sub 5}-type derived compounds in the zinc-rich corner As part of a study of the Yb-Zn-Al system, this first article reports the synthesis and crystal structure of four compounds. The crystal structures were determined by single crystal diffractometer data for three of them: Yb{sub

  14. Electronic band structure imaging of three layer twisted graphene on single crystal Cu(111)

    SciTech Connect (OSTI)

    Marquez Velasco, J.; Department of Physics, National Technical University of Athens, Athens ; Kelaidis, N.; Xenogiannopoulou, E.; Tsoutsou, D.; Tsipas, P.; Speliotis, Th.; Pilatos, G.; Likodimos, V.; Falaras, P.; Dimoulas, A.; Raptis, Y. S.

    2013-11-18

    Few layer graphene (FLG) is grown on single crystal Cu(111) by Chemical Vapor Deposition, and the electronic valence band structure is imaged by Angle-Resolved Photo-Emission Spectroscopy. It is found that graphene essentially grows polycrystalline. Three nearly ideal Dirac cones are observed along the Cu ?{sup }K{sup } direction in k-space, attributed to the presence of ?4 twisted three layer graphene with negligible interlayer coupling. The number of layers and the stacking order are compatible with Raman data analysis demonstrating the complementarity of the two techniques for a more accurate characterization of FLG.

  15. Molecular dynamics simulations of organic SIMS with Cu{sub n} (n=1-3) clusters

    SciTech Connect (OSTI)

    Townes, J. A.; White, A. K.; Krantzman, K. D.; Garrison, B. J.

    1999-06-10

    Molecular dynamics simulations have been performed to study the effect of cluster size on the emission yield and damage cross section in organic SIMS. A model system composed of a monolayer of biphenyl molecules on a Cu(001) substrate was bombarded with Cu{sub n} (n=1-3) projectiles at kinetic energies of 0.100 keV per atom. The yield increases with cluster size, but a nonlinear enhancement in yield is not observed. The yield-to-damage ratio, on the other hand, increases with the use of clusters, indicating that clusters have the potential to improve the sensitivity of SIMS.

  16. Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | DOE PAGES Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system Title: Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system Authors: Dhar, S. K. [1] ; Provino, A. [2] ; Manfrinetti, P. [2] ; Kulkarni, R. [1] ; Goyal, Neeraj [1] ; Paudyal, D. [3] + Show Author Affiliations Department of Condensed Matter Physics & Materials Science, T.I.F.R., Homi Bhabha Road, Colaba, Mumbai, 400005, India Department of Chemistry, University of Genova, Via Dodecaneso 31, 16146

  17. Synthesis of highly phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor

    DOE Patents [OSTI]

    Dorris, Stephen E. (La Grange Park, IL); Poeppel, Roger B. (Glen Ellyn, IL); Prorok, Barton C. (Harrisville, PA); Lanagan, Michael T. (Woodridge, IL); Maroni, Victor A. (Naperville, IL)

    1994-01-01

    An article and method of manufacture of (Bi,Pb)-Sr-Ca-Cu-O superconductor. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi,Pb)-Sr-Ca-Cu-O superconductor.

  18. Synthesis of highly phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor

    DOE Patents [OSTI]

    Dorris, S.E.; Poeppel, R.B.; Prorok, B.C.; Lanagan, M.T.; Maroni, V.A.

    1994-10-11

    An article and method of manufacture of (Bi,Pb)-Sr-Ca-Cu-O superconductor are disclosed. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi,Pb)-Sr-Ca-Cu-O superconductor. 5 figs.

  19. Semiconductor bridge, SCB, ignition studies of Al/CuO thermite

    SciTech Connect (OSTI)

    Bickes, R.W. Jr.; Wackerbarth, D.E.; Mohler, J.H.

    1997-04-01

    The authors briefly summarize semiconductor bridge operation and review their ignition studies of Al/CuO thermite as a function of the capacitor discharge unit (CDU) firing set capacitance, charge holder material and morphology of the CuO. Ignition thresholds were obtained using a brass charge holder and a non-conducting fiber-glass-epoxy composite material, G10. At - 18 C and a charge voltage of 50V, the capacitance thresholds were 30.1 {mu}F and 2.0 {mu}F respectively. They also present new data on electrostatic discharge (ESD) and radio frequency (RF) vulnerability tests.

  20. Healthcare Energy: Spotlight on Chiller Plants | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chiller Plants Healthcare Energy: Spotlight on Chiller Plants The Building Technologies Office conducted a healthcare energy end-use monitoring project in partnership with two hospitals. See below for a few highlights from monitoring chiller plant energy. Image of a chiller plant. Chiller Energy Annual site energy use intensities (EUIs) for chiller energy were estimated to be 27.7 kBtu/ft2-yr for the the Massachusetts General Hospital (MGH) Gray Building and 26.8 kBtu/ft2-yr for the State