Sample records for btu coke residual

  1. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs 

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  2. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  3. Accurate BTU Measurement

    E-Print Network [OSTI]

    Hosseini, S.; Rusnak, J. J.

    1 represents a typical arrangement in which heat is supplied to, or absorbed by the difference in temperatures of a working fluid, generally water. (See Ref. 1). Supply (TIl- Supply (Tl1 E E Heat (BTU) He.' ~ Exchange Exchange Relurn (T2... rate (BTU/unit time) ? m Mass flow rate (lb/unit time) hI' h2 = Specific enthalpy of supply and return liquid (BTU/lb) BTU C p - Average specific heat (--~----) IboF Equations 1, 2 are instantaneous values for heat flow or energy transferred...

  4. Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    generally lead to increased coking potential of coals characterised in the resulting cokes by large sizes equivalent to natural coking coals, since the cokes from these residues are always made of smaller MOD than those obtained for coking coals. For comparison, a similar characterisation, carried out

  5. BTU Accounting for Industry

    E-Print Network [OSTI]

    Redd, R. O.

    1979-01-01T23:59:59.000Z

    , salesmen cars, over the highway trucks, facilities startup, waste used as fuel and fuels received for storage. This is a first step in the DOE's effort to establish usage guidelines for large industrial users and, we note, it requires BTU usage data...-generated electricity, heating, ventilating, air conditioning, in-plant transportation, ore hauling, raw material storage and finished product warehousing. Categories which are excluded are corporate and divisional offices, basic research, distribution centers...

  6. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  7. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  8. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

    1995-12-01T23:59:59.000Z

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  9. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R. [Teck Corp. (Canada); Price, J.T.; Gransden, J.F. [CANMET Energy Technology Centre, Ottawa, Ontario (Canada)

    1997-12-31T23:59:59.000Z

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  10. Met coke world summit 2005

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

  11. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

    1986-01-01T23:59:59.000Z

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  12. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

  13. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10T23:59:59.000Z

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  14. Design and construction of coke battery 1A at Radlin coke plant, Poland

    SciTech Connect (OSTI)

    A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

  15. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M. [Krupp Koppers GmbH, Essen (Germany)

    1996-12-31T23:59:59.000Z

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  16. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

    1981-01-01T23:59:59.000Z

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  17. Process for treatment of residual gas

    SciTech Connect (OSTI)

    Nolden, K.

    1980-01-01T23:59:59.000Z

    A process is disclosed for the treatment of the residual gases which are produced when hydrogen sulfide is reduced, by combustion, to elementary sulfur by the Claus process. The residual gases are fed through a heated conduit and gas scrubber, wherein the temperature of those residual gases are maintained above the melting point of sulfur. A portion of the raw coke oven gas condensate is admitted to the gas scrubber to be returned to the coke oven battery main from the flushing liquid separator as flushing liquor. The residual gases are then conducted through the coke oven gas purification process equipment along with the raw coke oven gas where the residual gases are intermixed with the raw coke oven gas prior to tar separation.

  18. New coke-sorting system at OAO Koks

    SciTech Connect (OSTI)

    B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

  19. A Requirement for Significant Reduction in the Maximum BTU Input...

    Energy Savers [EERE]

    A Requirement for Significant Reduction in the Maximum BTU Input Rate of Decorative Vented Gas Fireplaces Would Impose Substantial Burdens on Manufacturers A Requirement for...

  20. Trends in the automation of coke production

    SciTech Connect (OSTI)

    R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

  1. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16T23:59:59.000Z

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  2. Method and apparatus for quenching coke

    SciTech Connect (OSTI)

    Calderon, A.

    1980-07-22T23:59:59.000Z

    A method is described for controlling pollutions during the discharge of coke from a coke oven having a pusher side and a coke discharge opening. The method comprises the steps of moving a carriage into alignment with the coke discharge opening, pushing a body of hot coke out of the discharge opening of the oven, guiding the coke pushed from the oven into a chamber supported on said carriage, quenching the coke by directing liquid at coke which is pushed into said chamber for dropping the temperature of the coke, confining steam and vapor generated during the dropping of the temperature of the coke in the chamber for building a positive pressure within the chamber, forcing the steam and vapors generated from the quenching of the coke out of the chamber through a venturi-like opening by means of the positive pressure built up in the chamber, and spraying liquid at the gases forced through said venturi-like opening by the positive pressure in the chamber for cleaning the gases.

  3. Environmental Permitting of a Low-BTU Coal Gasification Facility

    E-Print Network [OSTI]

    Murawczyk, C.; Stewart, J. T.

    1983-01-01T23:59:59.000Z

    that merits serious consideration since only relatively small modifications to the existing oil or gas burner system may be required, and boiler derating can be minimized. The environmental permitting and planning process for a low-Btu coal gasification...

  4. Environmental Permitting of a Low-BTU Coal Gasification Facility 

    E-Print Network [OSTI]

    Murawczyk, C.; Stewart, J. T.

    1983-01-01T23:59:59.000Z

    that merits serious consideration since only relatively small modifications to the existing oil or gas burner system may be required, and boiler derating can be minimized. The environmental permitting and planning process for a low-Btu coal gasification...

  5. Production of low BTU gas from biomass 

    E-Print Network [OSTI]

    Lee, Yung N.

    1981-01-01T23:59:59.000Z

    for combustion is simple relative to the gasification or pyrolysis and construc- tion and operation of the necessary equipment should also be easier. However, the final product of com- bustion, steam energy, cannot be stored for long periods of time.... Lee, B. S. , Washington University, St. Louis, Mo. Chairman of Advisory Committee: Dr. R. G. Anthony An experimental study was conducted to examine the gasification of agricultural residues as an alter- nate energy source. The agricultural residues...

  6. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01T23:59:59.000Z

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  7. Converting Petroleum Coke to Electricity 

    E-Print Network [OSTI]

    Pavone, A.

    1992-01-01T23:59:59.000Z

    will compete economically with conventional coal and nature gas, both of which are currently experiencing low prices. Pipeline quality natural gas at the well is selling on average for $1.50 IM- Btu, while cleaned coal at the mine is under $1.00/M... pneumatically into the firebox. Supplementary fuel (10%) would be necessary to ignite the process. and be required continuously to maintain flame stability Firebox temperatues would average 2000-2500 degF. Air would be introduced at several different stages...

  8. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31T23:59:59.000Z

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  9. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31T23:59:59.000Z

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  10. Estimating Coke and Pepsi's price and advertising strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry; Perloff, Jeffrey M.

    1999-01-01T23:59:59.000Z

    No. 789 ESTIMATING COKE AND PEPSI’ PRICE S AND ADVERTISINGAdvertising Strategies: Coke and Pepsi) by Amos Golan, LarryMarch 1999 Estimating Coke and Pepsi’s Price and Advertising

  11. New designs in the reconstruction of coke-sorting systems

    SciTech Connect (OSTI)

    A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

  12. Property:Geothermal/CapacityBtuHr | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal PwerPerkins County, Nebraska:PrecourtOid Jump to:Docket Number JumpAnnualGenBtuYrCapacityBtuHr

  13. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E. [British Steel plc, Scunthorpe (United Kingdom). Scunthorpe Works

    1995-12-01T23:59:59.000Z

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  14. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31T23:59:59.000Z

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  15. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01T23:59:59.000Z

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  16. EIS-0007: Low Btu Coal Gasification Facility and Industrial Park

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared this environmental impact statement which evaluates the potential environmental impacts that may be associated with the construction and operation of a low-Btu coal gasification facility and the attendant industrial park in Georgetown, Scott County, Kentucky.

  17. Heat treatment of exchangers to remove coke

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-20T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating the furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas containing molecular oxygen at a sufficient temperature below 800{degrees}F (427{degrees}C) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of five thousand pounds per square inch.

  18. Delayed coking of decant oil and coal in a laboratory-scale coking unit

    SciTech Connect (OSTI)

    Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

    2006-08-15T23:59:59.000Z

    In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

  19. New and revised standards for coke production

    SciTech Connect (OSTI)

    G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

  20. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15T23:59:59.000Z

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  1. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany)

    1995-12-01T23:59:59.000Z

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  2. Method for processing coke oven gas

    SciTech Connect (OSTI)

    Flockenhaus, C.; Meckel, J.F.; Wagener, D.

    1980-11-25T23:59:59.000Z

    Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO2-containing gas, with a steam reforming catalyst.

  3. Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

  4. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B. [Hoogovens IJmuiden B.V. (Netherlands)

    1995-12-01T23:59:59.000Z

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  5. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

    2009-05-15T23:59:59.000Z

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  6. Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar

    SciTech Connect (OSTI)

    Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

    2006-10-15T23:59:59.000Z

    In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

  7. Initial coke deposition on a NiMo/{gamma}-Al{sub 2}O{sub 3} bitumen hydroprocessing catalyst

    SciTech Connect (OSTI)

    Richardson, S.M.; Nagaishi, Hiroshi; Gray, M.R. [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering] [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering

    1996-11-01T23:59:59.000Z

    Athabasca bitumen was hydrocracked over a commercial NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst in two reactors, a microbatch reactor and a 1-L continuous stirred tank reactor (CSTR). Coke deposition on catalyst was measured as a function of hydrogen pressure, time on stream, and liquid composition by measuring the carbon content of the cleaned spent catalyst. The carbon content ranged from 11.3% to 17.6% over the pressure range 6.9--15.2 MPa in CSTR experiments. Batch and CSTR experiments showed a rapid approach to a constant coke content with increasing oil/catalyst ratio. Coke deposition was independent of product composition for residue concentrations ranging from 8% to 32% by weight. Removal of the coke by tetralin at reaction conditions suggested reversible adsorption of residue components on the catalyst surface. A physical model based on clearance of coke by hydrogen in the vicinity of metal crystallites is presented for the coke deposition behavior during the first several hours of hydrocracking use. This model gives good agreement with experimental data, including the effect of reaction time, the ratio of total feed weight to catalyst weight, hydrogen pressure, and feed composition, and it agrees with general observations from industrial usage. The model implies that except at the highest coke levels, the active surfaces of the metal crystallites remain exposed. Severe mass-transfer limitations are caused by the overall narrowing of the pore structure, which in {gamma}-Al{sub 2}O{sub 3} would give very low effective diffusivity for residuum molecules in micropores.

  8. Property:Geothermal/AnnualGenBtuYr | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal PwerPerkins County, Nebraska:PrecourtOid Jump to:Docket Number JumpAnnualGenBtuYr Jump to:

  9. BTU International DUK International JV | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation in Carbon CaptureAtria PowerAxeonBCHP ScreeningBLMBSABTBTR NewBTU

  10. Coke oven gas desulfurization: at Republic Steel's New Coking Facility, Warren, OH

    SciTech Connect (OSTI)

    Boak, S.C.; Prucha, D.G.; Turic, H.L.

    1981-01-01T23:59:59.000Z

    Our performance test indicates that the Sulfiban process is an effective method for removing H/sub 2/S from coke-oven gas. The process is able to handle variations in coke-oven gas flow and composition. Continuing efforts are underway to maintain optimum desulfurization conditions while trying to reduce waste production and MEA consumption. The problems which have prevented us from operating continuously have given us a better understanding of the process. This has contributed to better plant operations and greater equipment reliability for us to obtain continuous coke-oven gas desulfurization. 2 figures, 1 table.

  11. Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE

    E-Print Network [OSTI]

    Karp, Larry S.

    Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE AND ADVERTISING STRATEGIES (formerly Estimating Firms'Mixed Price and Advertising Strategies: Coke and Pepsi) by Amos Golan, Larry S. Karp. #12;Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M

  12. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

    2003-02-07T23:59:59.000Z

    The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

  13. High Btu gas from peat. Existing social and economic conditions

    SciTech Connect (OSTI)

    Not Available

    1981-08-01T23:59:59.000Z

    In 1980, the Minnesota Gas Company (Minnegasco) submitted a proposal to the US Department of Energy entitled, A Feasibility Study - High Btu Gas from Peat. The proposed study was designed to assess the overall viability of the design, construction and operation of a commercial facility for the production of high-Btu substitute natural gas (SNG) from Minnesota peat. On September 30, 1980, Minnegasco was awarded a grant by the Department of Energy to perform the proposed study. In order to complete the study, Minnegasco assembled an experienced project team with the wide range of expertise required. In addition, the State of Minnesota agreed to participate in an advisory capacity. The items to be investigated by the project team during the feasibility study include peat harvesting, dewatering, gasification process design, economic and risk assessment, site evaluation, environmental and socioeconomic impact assessment. Ertec (The Earth Technology Corporation) was selected to conduct the site evaluation and environmental assessment portions of the feasibility study. The site evaluation was completed in March of 1981 with the submittal of the first of several reports to Minnegasco. This report describes the existing social and economic conditions of the proposed project area in northern Minnesota. The baseline data presented will be used to assess the significance of potential project impacts in subsequent phases of the feasibility study. Wherever possible, the data base was established using 1980 Bureau of Census statistics. However, where the 1980 data were not yet available, the most recent information is presented. 11 figures, 46 tables.

  14. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect (OSTI)

    T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  15. Water protection in coke-plant design

    SciTech Connect (OSTI)

    G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

  16. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01T23:59:59.000Z

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  17. The Mansfield Two-Stage, Low BTU Gasification System: Report of Operations 

    E-Print Network [OSTI]

    Blackwell, L. T.; Crowder, J. T.

    1983-01-01T23:59:59.000Z

    The least expensive way to produce gas from coal is by low Btu gasification, a process by which coal is converted to carbon monoxide and hydrogen by reacting it with air and steam. Low Btu gas, which is used near its point of production, eliminates...

  18. Vol. 30 no. 14 2014, pages 20912092 BIOINFORMATICS MESSAGE FROM THE ISCB doi:10.1093/bioinformatics/btu117

    E-Print Network [OSTI]

    Radivojac, Predrag

    .1093/bioinformatics/btu117 Advance Access publication March 3, 2014 The automated function prediction SIG looks back

  19. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  20. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P. [BHP Research, Mulgrave (Australia). Melbourne Labs.; Cunningham, R.; Hockings, K. [BHP Steel, Pt Kembla, New South Wales (Australia). Coal and Coke Technical Development Group

    1997-12-31T23:59:59.000Z

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  1. Subtask 3.16 - Low-BTU Field Gas Application to Microturbines

    SciTech Connect (OSTI)

    Darren Schmidt; Benjamin Oster

    2007-06-15T23:59:59.000Z

    Low-energy gas at oil production sites presents an environmental challenge to the sites owners. Typically, the gas is managed in flares. Microturbines are an effective alternative to flaring and provide on-site electricity. Microturbines release 10 times fewer NOx emissions than flaring, on a methane fuel basis. The limited acceptable fuel range of microturbines has prevented their application to low-Btu gases. The challenge of this project was to modify a microturbine to operate on gases lower than 350 Btu/scf (the manufacturer's lower limit). The Energy & Environmental Research Center successfully operated a Capstone C30 microturbine firing gases between 100-300 Btu/scf. The microturbine operated at full power firing gases as low as 200 Btu/scf. A power derating was experienced firing gases below 200 Btu/scf. As fuel energy content decreased, NO{sub x} emissions decreased, CO emissions increased, and unburned hydrocarbons remained less than 0.2 ppm. The turbine was self-started on gases as low as 200 Btu/scf. These results are promising for oil production facilities managing low-Btu gases. The modified microturbine provides an emission solution while returning valuable electricity to the oilfield.

  2. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  3. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  4. The methods of steam coals usage for coke production

    SciTech Connect (OSTI)

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01T23:59:59.000Z

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  5. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  6. Environmental and economic evaluation of energy recovery from agricultural and forestry residues

    SciTech Connect (OSTI)

    None

    1980-09-01T23:59:59.000Z

    Four conversion methods and five residues are examined in this report, which describes six model systems: hydrolysis of corn residues, pyrolysis of corn residues, combustion of cotton-ginning residues, pyrolysis of wheat residues, fermentation of molasses, and combustion of pulp and papermill wastes. Estimates of material and energy flows for those systems are given per 10/sup 12/ Btu of recovered energy. Regional effects are incorporated by addressing the regionalized production of the residues. A national scope cannot be provided for every residue considered because of the biological and physical constraints of crop production. Thus, regionalization of the model systems to the primary production region for the crop from which the residue is obtained has been undertaken. The associated environmental consequences of residue utilization are then assessed for the production region. In addition, the environmental impacts of operating the model systems are examined by quantifying the residuals generated and the land, water, and material requirements per 10/sup 12/ Btu of energy generated. On the basis of estimates found in the literature, capital, operating, and maintenance cost estimates are given for the model systems. These data are also computed on the basis of 10/sup 12/ Btu of energy recovered. The cost, residual, material, land, and water data were then organized into a format acceptable for input into the SEAS data management program. The study indicates that the most serious environmental impacts arise from residue removal rather than from conversion.

  7. The Mansfield Two-Stage, Low BTU Gasification System: Report of Operations

    E-Print Network [OSTI]

    Blackwell, L. T.; Crowder, J. T.

    1983-01-01T23:59:59.000Z

    the high costs of oxygen and methanation required to produce gas that can be transmitted over long distance. Standard low Btu fixed bed gasifiers have historically been plagued by three constraints; namely, the production of messy tars and oils...

  8. Recent regulatory experience of low-Btu coal gasification. Volume III. Supporting case studies

    SciTech Connect (OSTI)

    Ackerman, E.; Hart, D.; Lethi, M.; Park, W.; Rifkin, S.

    1980-02-01T23:59:59.000Z

    The MITRE Corporation conducted a five-month study for the Office of Resource Applications in the Department of Energy on the regulatory requirements of low-Btu coal gasification. During this study, MITRE interviewed representatives of five current low-Btu coal gasification projects and regulatory agencies in five states. From these interviews, MITRE has sought the experience of current low-Btu coal gasification users in order to recommend actions to improve the regulatory process. This report is the third of three volumes. It contains the results of interviews conducted for each of the case studies. Volume 1 of the report contains the analysis of the case studies and recommendations to potential industrial users of low-Btu coal gasification. Volume 2 contains recommendations to regulatory agencies.

  9. Sectoral combustor for burning low-BTU fuel gas

    DOE Patents [OSTI]

    Vogt, Robert L. (Schenectady, NY)

    1980-01-01T23:59:59.000Z

    A high-temperature combustor for burning low-BTU coal gas in a gas turbine is disclosed. The combustor includes several separately removable combustion chambers each having an annular sectoral cross section and a double-walled construction permitting separation of stresses due to pressure forces and stresses due to thermal effects. Arrangements are described for air-cooling each combustion chamber using countercurrent convective cooling flow between an outer shell wall and an inner liner wall and using film cooling flow through liner panel grooves and along the inner liner wall surface, and for admitting all coolant flow to the gas path within the inner liner wall. Also described are systems for supplying coal gas, combustion air, and dilution air to the combustion zone, and a liquid fuel nozzle for use during low-load operation. The disclosed combustor is fully air-cooled, requires no transition section to interface with a turbine nozzle, and is operable at firing temperatures of up to 3000.degree. F. or within approximately 300.degree. F. of the adiabatic stoichiometric limit of the coal gas used as fuel.

  10. Dry purification of aspirational air in coke-sorting systems with wet slaking of coke

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

  11. Syncrude coke burned in bubbling fluidized bed

    SciTech Connect (OSTI)

    Not Available

    1987-03-01T23:59:59.000Z

    Syncrude Canada Ltd.'s byproduct coke is high in sulfur (7%) and vanadium (0.2%), and moderate in ash (5.9%). It contains a high proportion of unreactive forms of carbon and is low in volatiles, 6.6%. It is unsuitable for combustion by established technologies, and at present the entire production of over 2000 tons per day is being stockpiled. Experiments with atmospheric fluidized bed combustion (AFBC) are described. The AFBC provides abatement of SO/sub 2/ emissions by means of limestone sorbent fed to the combustor together with the fuel. The pilot plant, combustion efficiency, and sulfur capture are discussed. 3 figures.

  12. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-12-01T23:59:59.000Z

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  13. TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies during Pulverized Coal Injection (PCI) at High Rates

    SciTech Connect (OSTI)

    Veena Sahajwalla; Sushil Gupta

    2005-04-15T23:59:59.000Z

    Combustion behavior of pulverized coals (PC), gasification and thermal annealing of cokes were investigated under controlled environments. Physical and chemical properties of PCI, coke and carbon residues of blast furnace dust/sludge samples were characterized. The strong influence of carbon structure and minerals on PCI reactivity was demonstrated. A technique to characterize char carryover in off gas emissions was established.

  14. Vol. 30 ISMB 2014, pages i9i18 BIOINFORMATICS doi:10.1093/bioinformatics/btu259

    E-Print Network [OSTI]

    Moret, Bernard

    Vol. 30 ISMB 2014, pages i9­i18 BIOINFORMATICS doi:10.1093/bioinformatics/btu259 Evaluating synteny

  15. New process for coke-oven gas desulfurization

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-10-01T23:59:59.000Z

    With the EPA reclassifying spent iron oxide as a hazardous waste material in 1990, an alternative technology was sought for desulfurizing coke-oven gas. Vacasulf technology was adopted for reasons that included: producing of coke battery heating gas without further polishing and high-quality elemental sulfur; lowest operating cost in comparison with other methods; no waste products; and integrates with existing ammonia destruction facility. Vacasulf requires a single purchased material, potassium hydroxide, that reacts with carbon dioxide in coke-oven gas to form potassium carbonate which, in turn, absorbs hydrogen sulfide. Operation of the system has been successful following the resolution of relatively minor start-up problems.

  16. Method for removal of furfural coke from metal surfaces

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-27T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating ship furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas with a total pressure of less than 100 psig containing molecular oxygen. The gas being at a sufficient temperature below 800{degrees}F. (427{degrees}C.) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of about 5000 psi.

  17. Coke profile and effect on methane/ethylene conversion process

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    with distance along the reactor, and therefore the coke distribution should follow a similar pattern. A distribution of coke deposits along the reactor was also observed by Noda er al. (1974) in a study of iso-pentane isomerization. In this case the coke..., methane, ethane, ethylene, propane, iso-butane, butane, iso-pentane, pentane and hexanes. Also, the flow rate of the effluent stream is measured using the bubble meter. The mole percentages of methane and ethylene are subtracted of the effluent stream...

  18. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01T23:59:59.000Z

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  19. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany). Inst. for Cokemaking and Fuel Technology; Hofherr, K. [Thyssen Stahl AG, Duisburg (Germany)

    1995-12-01T23:59:59.000Z

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  20. Estimating Coke and Pepsi's Price and Advertising Strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry S.; Perloff, Jeffrey M.

    1998-01-01T23:59:59.000Z

    2b: GME-Nash Estimates of Pepsi’s Strategies (First QuarterStrategy Distributions for Pepsi (First Quarter 1977) a)789 ESTIMATING COKE AND PEPSI'S PRICE ADVERTISING STRATEGIES

  1. Problem of improving coke oven gas purification systems

    SciTech Connect (OSTI)

    Goldin, I.A.

    1982-01-01T23:59:59.000Z

    A discussion of the problems of improving desulfurization processes of coke oven gas was presented. Of particular interest were control systems and increasing capacity of the coke ovens. Included in the discussion were the vacuum-carbonate and arsenic-soda sulfur removal systems. Problems involved with these systems were the number of treatment operations, the volume of the reagents used, and the operation of equipment for naphthalene and cyanide removal.

  2. Priorities in the design of chemical shops at coke plants

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

  3. An analytical investigation of primary zone combustion temperatures and NOx production for turbulent jet flames using low-BTU fuels 

    E-Print Network [OSTI]

    Carney, Christopher Mark

    1995-01-01T23:59:59.000Z

    The objective of this research project was to identify and determine the effect of jet burner operating variables that influence combustion of low-BTU gases. This was done by simulating the combustion of a low-BTU fuel in a jet flame and predicting...

  4. An analytical investigation of primary zone combustion temperatures and NOx production for turbulent jet flames using low-BTU fuels

    E-Print Network [OSTI]

    Carney, Christopher Mark

    1995-01-01T23:59:59.000Z

    The objective of this research project was to identify and determine the effect of jet burner operating variables that influence combustion of low-BTU gases. This was done by simulating the combustion of a low-BTU fuel in a jet flame and predicting...

  5. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  6. An Evaluation of Low-BTU Gas from Coal as an Alternate Fuel for Process Heaters

    E-Print Network [OSTI]

    Nebeker, C. J.

    1982-01-01T23:59:59.000Z

    As the price gap between oil and natural gas and coal continues to widen, Monsanto has carefully searched out and examined opportunities to convert fuel use to coal. Preliminary studies indicate that the low-btu gas produced by fixed-bed, air blown...

  7. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect (OSTI)

    Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

    2009-07-01T23:59:59.000Z

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  8. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  9. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio [Mitsubishi Chemical Corp., Yokohama (Japan); Tanioka, Seiichi [Mitsubishi Chemical Corp., Sakaide (Japan)

    1997-12-31T23:59:59.000Z

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  10. Determination of performance characteristics of a one-cylinder diesel engine modified to burn low-Btu (lignite) gas

    E-Print Network [OSTI]

    Blacksmith, James Richard

    1979-01-01T23:59:59.000Z

    DETERMINATION OF PERFORMANCE CHARACTERISTICS OF A ONE-CYLINDER DIESEL ENGINE MODIFIED TO BURN LOW-BTU (LIGNITE) GAS A Thesis JAMES RICHARD BLACKSMITH Submitted to the Graduate College of Texas A86YI University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1979 Major Subject: Mechanical Engineering DETERMINATION OF PERFORMANCE CHARACTERISTICS OF A ONE-CYLINDER DIESEL ENGINE MODIFIED TO BURN LOW-BTU (LIGNITE) GAS A Thesis by JAMES RICHARD BLACKSMITH...

  11. Low/medium-Btu coal-gasification assessment program for specific sites of two New York utilities

    SciTech Connect (OSTI)

    Not Available

    1980-12-01T23:59:59.000Z

    The scope of this study is to investigate the technical and economic aspects of coal gasification to supply low- or medium-Btu gas to the two power plant boilers selected for study. This includes the following major studies (and others described in the text): investigate coals from different regions of the country, select a coal based on its availability, mode of transportation and delivered cost to each power plant site; investigate the effects of burning low- and medium-Btu gas in the selected power plant boilers based on efficiency, rating and cost of modifications and make recommendations for each; and review the technical feasibility of converting the power plant boilers to coal-derived gas. The following two coal gasification processes have been used as the basis for this Study: the Combustion Engineering coal gasification process produces a low-Btu gas at approximately 100 Btu/scf at near atmospheric pressure; and the Texaco coal gasification process produces a medium-Btu gas at 292 Btu/scf at 800 psig. The engineering design and economics of both plants are described. Both plants meet the federal, state, and local environmental requirements for air quality, wastewater, liquid disposal, and ground level disposal of byproduct solids. All of the synthetic gas alternatives result in bus bar cost savings on a yearly basis within a few years of start-up because the cost of gas is assumed to escalate at a lower rate than that of fuel oil, approximately 4 to 5%.

  12. Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas

    SciTech Connect (OSTI)

    V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

  13. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01T23:59:59.000Z

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  14. Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan*

    E-Print Network [OSTI]

    Lansky, Joshua

    Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M strategies in prices and advertising for Coca-Cola and Pepsi-Cola. Separate strategies for each firm theory. We use these methods to estimate the pricing and adver- tising strategies of Coca-Cola and Pepsi

  15. Coke profile and effect on methane/ethylene conversion process 

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were...

  16. Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy

    SciTech Connect (OSTI)

    S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

    2009-03-15T23:59:59.000Z

    Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

  17. Understanding Utility Rates or How to Operate at the Lowest $/BTU

    E-Print Network [OSTI]

    Phillips, J. N.

    . The lower the energy rating (KW/Ton or KW/HP or KW/BTU) the more efficient the equipment and the less demand draw on the electric power plants, thereby reducing the need to build new power plants. To encourage DSM, utilities give rebates for high...: Bob Allwein, Oklahoma Natural Gas Company. Dick Landry, Gulf States Utility. Curtis Williford, Entex Gas Company. Bret McCants, Central Power and Light Company. Frank Tanner, Southern Union. Patric Coon, West Texas utilities. ESL-IE-93...

  18. U.S. Heat Content of Natural Gas Deliveries to Other Sectors Consumers (BTU

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 34 44Year Jan Feb Mar Apr MayNov-14 Dec-14 Jan-15 Feb-15(BTU perper

  19. Coke oven gas desulphurization by the Carl Still process

    SciTech Connect (OSTI)

    Knight, R.E.

    1981-01-01T23:59:59.000Z

    The Steubenville East Coke Plant need a desulfurization process that would desulfurize an eventual 95 million standard cubic feet per day of coke oven gas from an inlet of 450 gr/DSCF to an outlet of 45 gr/DSCF of hydrogen sulfide. The Dravo/Still plant process was selected, due to the use of ammonia which was available in the gas, as the absorbing agent. It was also a proven process. Dravo/Still also was capable of building a sulfuric acid plant. The desulfurization efficiency of the plant has consistently provided an average final gas sulfur loading below the guaranteed 45 gr/DSCF. This removal efficiency has enabled production of an average of 4615 tons per day of 66/sup 0/Be acid. Also SO/sub 2/ to SO/sub 3/ conversion has averaged 98%. 3 figures. (DP)

  20. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01T23:59:59.000Z

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  1. Pipeline charging of coke ovens with a preheated charge

    SciTech Connect (OSTI)

    Karpov, A.V.; Khadzhioglo, A.V.; Kuznichenko, V.M.

    1983-01-01T23:59:59.000Z

    Work to test a pipeline charging method was conducted at the Konetsk Coke Works (a PK-2K coke oven system with a single gas main, oven width 407 mm, height 4300 mm, effective column 20.0 cm/sub 3/). This method consists of transporting the heated coal charge to the ovens through a pipe by means of steam. the charge is transported by high pressure chamber groups, and loaded by means of systems equipped with devices for separation, withdrawal and treatment of the spent steam. The principal goal of the present investigation was to test technical advances in the emission-free charging of preheated charges. The problem was, first, to create a reliable technology for separation of the steam from the charge immediately before loading it into the oven and, second, to provide a total elimination of emissions, thereby protecting the environment against toxic substances.

  2. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  3. New environmental concepts in the chemical and coke industries

    SciTech Connect (OSTI)

    A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

    2007-05-15T23:59:59.000Z

    We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

  4. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31T23:59:59.000Z

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  5. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01T23:59:59.000Z

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  6. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro [Kobe Steel Ltd. (Japan). Kobe Works

    1997-12-31T23:59:59.000Z

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  7. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31T23:59:59.000Z

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  8. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31T23:59:59.000Z

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  9. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01T23:59:59.000Z

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  10. High btu gas from peat. A feasibility study. Part 1. Executive summary. Final report

    SciTech Connect (OSTI)

    Not Available

    1984-01-01T23:59:59.000Z

    In September, 1980, the US Department of Energy (DOE) awarded a Grant (No. DE-FG01-80RA50348) to the Minnesota Gas Company (Minnegasco) to evaluate the commercial viability - technical, economic and environmental - of producing 80 million standard cubic feet per day (SCFD) of substitute natural gas (SNG) from peat. The proposed product, high Btu SNG would be a suitable substitute for natural gas which is widely used throughout the Upper Midwest by residential, commercial and industrial sectors. The study team consisted of Dravo Engineers and Constructors, Ertec Atlantic, Inc., The Institute of Gas Technology, Deloitte, Haskins and Sells and Minnegasco. Preliminary engineering and operating and financial plans for the harvesting, dewatering and gasification operations were developed. A site in Koochiching County near Margie was chosen for detailed design purposes only; it was not selected as a site for development. Environmental data and socioeconomic data were gathered and reconciled. Potential economic data were gathered and reconciled. Potential impacts - both positive and negative - were identified and assessed. The peat resource itself was evaluated both qualitatively and quantitatively. Markets for plant by-products were also assessed. In summary, the technical, economic, and environmental assessment indicates that a facility producing 80 billion Btu's per day SNG from peat is not commercially viable at this time. Minnegasco will continue its efforts into the development of peat and continue to examine other options.

  11. Markets for low- and medium-Btu coal gasification: an analysis of 13 site specific studies

    SciTech Connect (OSTI)

    Not Available

    1981-09-01T23:59:59.000Z

    In 1978 the US Department of Energy (DOE), through its Office of Resource Applications, developed a commercialization plan for low- and medium-Btu coal gasification. Several initial steps have been taken in that process, including a comprehensive study of industrial markets, issuance of a Notice of Program Interest, and funding of proposals under the Alternate Fuels Legislation (P.L. 96-126). To assist it in the further development and administration of the commercialization plan, the Office of Resource Applications has asked Booz, Allen and Hamilton to assess the market prospects for low- and medium-Btu coal gasification. This report covers the detailed findings of the study. Following the introduction which discusses the purpose of the study, approach used for the assignment and current market attitudes on coal gasification, there are three chapters on: systems configurations and applications; economic and finanical attractiveness; and summary of management decisions based on feasibility study results. The final chapter briefly assesses the management decisions. The general consensus seems to be that coal gasification is a technology that will be attractive in the future but is marginal now. 6 figures, 5 tables.

  12. Fuel injection staged sectoral combustor for burning low-BTU fuel gas

    DOE Patents [OSTI]

    Vogt, Robert L. (Schenectady, NY)

    1985-02-12T23:59:59.000Z

    A high-temperature combustor for burning low-BTU coal gas in a gas turbine is described. The combustor comprises a plurality of individual combustor chambers. Each combustor chamber has a main burning zone and a pilot burning zone. A pipe for the low-BTU coal gas is connected to the upstream end of the pilot burning zone: this pipe surrounds a liquid fuel source and is in turn surrounded by an air supply pipe: swirling means are provided between the liquid fuel source and the coal gas pipe and between the gas pipe and the air pipe. Additional preheated air is provided by counter-current coolant air in passages formed by a double wall arrangement of the walls of the main burning zone communicating with passages of a double wall arrangement of the pilot burning zone: this preheated air is turned at the upstream end of the pilot burning zone through swirlers to mix with the original gas and air input (and the liquid fuel input when used) to provide more efficient combustion. One or more fuel injection stages (second stages) are provided for direct input of coal gas into the main burning zone. The countercurrent air coolant passages are connected to swirlers surrounding the input from each second stage to provide additional oxidant.

  13. Fuel injection staged sectoral combustor for burning low-BTU fuel gas

    DOE Patents [OSTI]

    Vogt, Robert L. (Schenectady, NY)

    1981-01-01T23:59:59.000Z

    A high-temperature combustor for burning low-BTU coal gas in a gas turbine is described. The combustor comprises a plurality of individual combustor chambers. Each combustor chamber has a main burning zone and a pilot burning zone. A pipe for the low-BTU coal gas is connected to the upstream end of the pilot burning zone; this pipe surrounds a liquid fuel source and is in turn surrounded by an air supply pipe; swirling means are provided between the liquid fuel source and the coal gas pipe and between the gas pipe and the air pipe. Additional preheated air is provided by counter-current coolant air in passages formed by a double wall arrangement of the walls of the main burning zone communicating with passages of a double wall arrangement of the pilot burning zone; this preheated air is turned at the upstream end of the pilot burning zone through swirlers to mix with the original gas and air input (and the liquid fuel input when used) to provide more efficient combustion. One or more fuel injection stages (second stages) are provided for direct input of coal gas into the main burning zone. The countercurrent air coolant passages are connected to swirlers surrounding the input from each second stage to provide additional oxidant.

  14. The effects of ash and maceral composition of Azdavay and Kurucasile (Turkey) coals on coking properties

    SciTech Connect (OSTI)

    Toroglu, I. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Engineering

    2006-07-01T23:59:59.000Z

    In this study, investigations were made as to the effect of the maceral compositions and mineral matter content of Azdavay and Kurucasile coals on the coking property. Chemical and maceral analyses and coking properties were determined for the products of the float-sink procedure. The coking properties were established on the basis of free swelling index and Ruhr dilatometer tests. Maceral analyses showed that as the ash content of a coal containing both high and medium volatile matter increases, its effective maceral proportion decreases, and the coking property is affected in an unfavorable way.

  15. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01T23:59:59.000Z

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  16. X-ray evaluation of coke-oven gas line deposits

    SciTech Connect (OSTI)

    Swain, Y.T.

    1983-08-01T23:59:59.000Z

    Control of coke-oven gas pipeline deposits has been facilitated through the use of an X-ray technique that provides quantitative data without disrupting plant operations.

  17. Process for dissolving coke oven deposits comprising atomizing a composition containing N-methyl-2-pyrrolidone into the gas lines

    SciTech Connect (OSTI)

    Stafford, M.L.; Nicholson, G.M.

    1993-07-06T23:59:59.000Z

    A method is described for cleaning gas lines in coke oven batteries comprising atomizing a composition into the gas lines of coke oven batteries, where the composition comprises N-methyl-2-pyrrolidone.

  18. Takahax-Hirohax process for coke oven gas desulfurization

    SciTech Connect (OSTI)

    Gastwirth, H.; Miner, R.; Stengle, W.

    1981-01-01T23:59:59.000Z

    This paper describes the Takahax-Hirohax process to desulfurize coke oven gas and to produce an ammonium sulfate end product. A review is also made of current operating experience and recent technical developments. The Takahax-Hirohax process is extremely useful when the COG contains a suitable ammonia to sulfur ratio and when ammonium sulfate is a desirable end product. No contaminated effluent streams are emitted from the process. The process is simple, reliable, flexible, and responds easily to COG variations. 4 figures, 3 tables. (DP)

  19. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect (OSTI)

    G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

    2007-07-01T23:59:59.000Z

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  20. Analytical input-output and supply chain study of China's coke and steel sectors

    E-Print Network [OSTI]

    Li, Yu, 1976-

    2004-01-01T23:59:59.000Z

    I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

  1. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31T23:59:59.000Z

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  2. Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau (CPM)

    E-Print Network [OSTI]

    Boyer, Edmond

    - 1 - Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau with thermomechanical modelling of a coke oven heating wall. The objective is to define the safe limits of coke oven of walls, roof and larry car, pre-stresses (anchoring system), lateral pressure due to coal pushing A 3D

  3. Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast

    E-Print Network [OSTI]

    Leu, Tzong-Shyng "Jeremy"

    of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

  4. Bethlehem Steel announces plans to control coke oven air and water pollution

    SciTech Connect (OSTI)

    Not Available

    1989-08-01T23:59:59.000Z

    Bethlehem Steel Corporation and the Maryland Department of the Environment have announced an agreement under which Bethlehem will spend an estimated $92-million at its Sparrows Points, Md., plant for technologically-advanced controls to further reduce air and water pollution, mainly from the plant's coke ovens. The two major systems include one to treat by-product coke oven gas and chemicals, and another to upgrade existing pushing emission controls on two older coke oven batteries. One of the new systems will replace most of the existing equipment that cleans gas and treats chemicals created by the coking process at the plant's three coke oven batteries. Because this system has the potential to greatly reduce sulfur dioxide and other pollutants, the United States Department of Energy (DOE) in September announced that its installation qualified for funding as part of the nationwide Innovative Clean Coal Technology Program.

  5. Desulphurization of coke oven gas by the Stretford Process

    SciTech Connect (OSTI)

    Plenderleith, J.

    1981-01-01T23:59:59.000Z

    The Stretford process is probably the most effective means available for removing hydrogen sulphide from gas streams. For streams which do not contain hydrogen cyanide or excessive oxygen it should be nearly ideal. However, the large volume of waste liquor generated by fixation of hydrogen cyanide has prevented its widespread adoption for coke oven gas treatment. Investigations of various proposals for treating the waste liquor indicate that the only practicable way of dealing with it is by reductive incineration. Although attempts to apply the Peabody-Holmes reductive incineration process have been disappointing, significant progress in overcoming some of its deficiencies has been made. The Zimpro wet oxidation process will provide a convenient method of treating the HCN scrubber effluent at No. 1 Plant. However, it will not treat the sodium based liquor from the Stretford plant. Its application to Stretford waste treatment is limited to situations where ammonium liquors and ammonium sulphate recovery facilities are available. Commissioning of this plant has been delayed while a defect in the air compressor supplied for the plant is being remedied. When the problem of liquid effluent disposal has been overcome, and if reagent chemicals continue to be available at reasonable prices, the Stretford process will be a good choice for coke oven gas desulphurization. 8 figures.

  6. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  7. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01T23:59:59.000Z

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  8. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01T23:59:59.000Z

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  9. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  10. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A. (National Research Council of Canada, Ottawa, ON (Canada). Div. of Chemistry)

    1989-01-01T23:59:59.000Z

    Ash reduction of the cokes and fly ash samples derived from the Athabasca oil sands bitumen was attempted by dissolving the mineral matter in acids. The samples used for this investigation included Syncrude fluid coking coke, Suncor delayed coking coke and the two fly ash samples obtained from the combustion of these cokes. All samples were analyzed for C,H,N,O, and S before and after acid demineralization and the analyses results compared. Further, the ash from the samples before and after acid demineralization was analyzed for silica, alumina, iron titanium, nickel and vanadium to assess the acid leaching of these elements. CP/MAS, /sup 13/C NMR spectroscopic study of the demineralized coke and fly ash samples was also attempted.

  11. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect (OSTI)

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

    2009-05-15T23:59:59.000Z

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  12. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka [Kawasaki Steel Corp., Mizushima, Kurashiki (Japan). Mizushima Works

    1997-12-31T23:59:59.000Z

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  13. Method for removing hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Ritter, H.

    1982-08-03T23:59:59.000Z

    An improved sulfur-ammonia process is disclosed for removing hydrogen sulfide from coke oven gases. In the improved process, a concentrator formerly used for standby operation is used at all normal times as an ammonia scrubber to improve the efficiency of gas separation during normal operation and is used as a concentrator for its intended standby functions during the alternative operations. In its normal function, the concentrator/scrubber functions as a scrubber to strip ammonia gas from recirculating liquid streams and to permit introduction of an ammonia-rich gas into a hydrogen sulfide scrubber to increase the separation efficiency of that unit. In the standby operation, the same concentrator/scrubber serves as a concentrator to concentrate hydrogen sulfide in a ''strong liquor'' stream for separate recovery as a strong liquor.

  14. Energy efficiency of alternative coke-free metallurgical technologies

    SciTech Connect (OSTI)

    V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov [Ural State Technical University - Ural Polytechnic Institute, Yekaterinburg (Russian Federation)

    2009-02-15T23:59:59.000Z

    Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

  15. The effect of CO? on the flammability limits of low-BTU gas of the type obtained from Texas lignite 

    E-Print Network [OSTI]

    Gaines, William Russell

    1983-01-01T23:59:59.000Z

    Chairman of Advisory Committee: Dr. W. N. Heffington An experimental study was conducted to determine if relatively large amounts of CO in a low-BTU gas of the type 2 derived from underground gasification of Texas lignite would cause significant... time when I was in need. Finally, the Center for Energy and Mineral Resources and the Texas Engineering Experiment Station for support related to this research. TABLE OF CONTENTS PAGE ABSTRACT ACKNOWLEDGEMENTS LIST OF TABLES LIST OF FIGURES V1...

  16. Commercial demonstration of atmospheric medium BTU fuel gas production from biomass without oxygen the Burlington, Vermont Project

    SciTech Connect (OSTI)

    Rohrer, J.W. [Zurn/NEPCO, South Portland, MA (United States); Paisley, M. [Battelle Laboratories, Columbus, OH (United States)

    1995-12-31T23:59:59.000Z

    The first U.S. demonstration of a gas turbine operating on fuel gas produced by the thermal gasification of biomass occurred at Battelle Columbus Labs (BCL) during 1994 using their high throughput indirect medium Btu gasification Process Research Unit (PRU). Zurn/NEPCO was retained to build a commercial scale gas plant utilizing this technology. This plant will have a throughput rating of 8 to 12 dry tons per hour. During a subsequent phase of the Burlington project, this fuel gas will be utilized in a commercial scale gas turbine. It is felt that this process holds unique promise for economically converting a wide variety of biomass feedstocks efficiently into both a medium Btu (500 Btu/scf) gas turbine and IC engine quality fuel gas that can be burned in engines without modification, derating or efficiency loss. Others are currently demonstrating sub-commercial scale thermal biomass gasification processes for turbine gas, utilizing both atmospheric and pressurized air and oxygen-blown fluid bed processes. While some of these approaches hold merit for coal, there is significant question as to whether they will prove economically viable in biomass facilities which are typically scale limited by fuel availability and transportation logistics below 60 MW. Atmospheric air-blown technologies suffer from large sensible heat loss, high gas volume and cleaning cost, huge gas compressor power consumption and engine deratings. Pressurized units and/or oxygen-blown gas plants are extremely expensive for plant scales below 250 MW. The FERCO/BCL process shows great promise for overcoming the above limitations by utilizing an extremely high throughout circulation fluid bed (CFB) gasifier, in which biomass is fully devolitalized with hot sand from a CFB char combustor. The fuel gas can be cooled and cleaned by a conventional scrubbing system. Fuel gas compressor power consumption is reduced 3 to 4 fold verses low Btu biomass gas.

  17. Fusion Residues

    E-Print Network [OSTI]

    Kenneth Intriligator

    1991-08-19T23:59:59.000Z

    We discuss when and how the Verlinde dimensions of a rational conformal field theory can be expressed as correlation functions in a topological LG theory. It is seen that a necessary condition is that the RCFT fusion rules must exhibit an extra symmetry. We consider two particular perturbations of the Grassmannian superpotentials. The topological LG residues in one perturbation, introduced by Gepner, are shown to be a twisted version of the $SU(N)_k$ Verlinde dimensions. The residues in the other perturbation are the twisted Verlinde dimensions of another RCFT; these topological LG correlation functions are conjectured to be the correlation functions of the corresponding Grassmannian topological sigma model with a coupling in the action to instanton number.

  18. Producing and controlling of the pollutant in the coal`s coking process

    SciTech Connect (OSTI)

    Li, S. [Shanxi Environmental Protection Bureau (China); Fan, Z. [Shanxi Central Environmental Monitoring Station (China)

    1997-12-31T23:59:59.000Z

    In the process of heating and coke shaping, different pollutants and polluting factors will be produced and lost to the environment due to the different coking methods. The paper analyzes the production mechanism, type, emission, average quantity, and damage to the environment of the major pollutants and polluting factors produced in several kinds of coking processes in China at the present. Then, the paper concludes that an assessment for any coking method should include a comprehensive beneficial assessment of economical benefit, environmental benefit and social benefit. The items in the evaluation should consist of infrastructure investment, which includes production equipment and pollution control equipment, production cost, benefit and profit produced by one ton coal, whether the pollution complies with the environmental requirement, extent of the damage, influence to the social development, and etc.

  19. Current developments at Giprokoks for coke-battery construction and reconstruction

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

  20. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D. [Centre de Pyrolyse de Marienau, Forbach (France)

    1997-12-31T23:59:59.000Z

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  1. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite 

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    45 Figure 9. Relationship between enhanced coke formation with increasing yields of paraffins and diminishing yields of olefins 46 Figure 10. Gas chromatogram of the concentrated carbon tetrachloride extract of spent catalyst pellets . . . 49...THE NATURE ABD FORMATION OF COKE IB THE REACTIOB OF METHANOL TO HIDROCARBOBS OVER CHABAZITE A Thesis KENNETH WOOT MCLAUGHLLN Submitted to the Graduate College of Texas AAM Univers ty partial. fulfillment nf the req~nt fo~he degree of MASTER...

  2. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01T23:59:59.000Z

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  3. Effect of thermal treatment on coke reactivity and catalytic iron mineralogy

    SciTech Connect (OSTI)

    Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

    2009-07-15T23:59:59.000Z

    Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

  4. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

    2009-04-15T23:59:59.000Z

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  5. High-temperature turbine technology program. Turbine subsystem design report: Low-Btu gas

    SciTech Connect (OSTI)

    Horner, M.W.

    1980-12-01T23:59:59.000Z

    The objective of the US Department of Energy High-Temperature Turbine Technology (DOE-HTTT) program is to bring to technology readiness a high-temperature (2600/sup 0/F to 3000/sup 0/F firing temperature) turbine within a 6- to 10-year duration, Phase II has addressed the performance of component design and technology testing in critical areas to confirm the design concepts identified in the earlier Phase I program. Based on the testing and support studies completed under Phase II, this report describes the updated turbine subsystem design for a coal-derived gas fuel (low-Btu gas) operation at 2600/sup 0/F turbine firing temperature. A commercial IGCC plant configuration would contain four gas turbines. These gas turbines utilize an existing axial flow compressor from the GE product line MS6001 machine. A complete description of the Primary Reference Design-Overall Plant Design Description has been developed and has been documented. Trends in overall plant performance improvement at higher pressure ratio and higher firing temperature are shown. It should be noted that the effect of pressure ratio on efficiency is significally enhanced at higher firing temperatures. It is shown that any improvement in overall plant thermal efficiency reflects about the same level of gain in Cost of Electricity (COE). The IGCC concepts are shown to be competitive in both performance and cost at current and near-term gas turbine firing temperatures of 1985/sup 0/F to 2100/sup 0/F. The savings that can be accumulated over a thirty-year plant life for a water-cooled gas turbine in an IGCC plant as compared to a state-of-the-art coal-fired steam plant are estimated. A total of $500 million over the life of a 1000 MW plant is projected. Also, this IGCC power plant has significant environmental advantages over equivalent coal-fired steam power plants.

  6. Sorption characteristics of polycyclic aromatic hydrocarbons in aluminum smelter residues

    SciTech Connect (OSTI)

    Gijs D. Breedveld; Emilien Pelletier; Richard St. Louis; Gerard Cornelissen [Norwegian Geotechnical Institute, Oslo (Norway)

    2007-04-01T23:59:59.000Z

    High temperature carbon oxidation in primary aluminum smelters results in the release of polycyclic aromatic hydrocarbons (PAH) into the environment. The main source of PAH are the anodes, which are composed of petroleum coke (black carbon, BC) and coal tar pitch. To elucidate the dominant carbonaceous phase controlling the environmental fate of PAH in aluminum smelter residues (coke BC and/or coal tar), the sorptive behavior of PAHs has been determined, using passive samplers and infinite-sink desorption methods. Samples directly from the wet scrubber were studied as well as ones from an adjacent 20-year old storage lagoon and roof dust from the smelter. Carbon-normalized distribution coefficients of native PAHs were 2 orders of magnitude higher than expected based on amorphous organic carbon (AOC)/water partitioning, which is in the same order of magnitude as reported literature values for soots and charcoals. Sorption isotherms of laboratory-spiked deuterated phenanthrene showed strong (about 100 times stronger than AOC) but nonetheless linear sorption in both fresh and aged aluminum smelter residues. The absence of nonlinear behavior typical for adsorption to BC indicates that PAH sorption in aluminum smelter residues is dominated by absorption into the semi-solid coal tar pitch matrix. Desorption experiments using Tenax showed that fresh smelter residues had a relatively large rapidly desorbing fraction of PAH (35-50%), whereas this fraction was strongly reduced (11-16%) in the lagoon and roof dust material. Weathering of the coal tar residue and/or redistribution of PAH between coal tar and BC phases could explain the reduced availability in aged samples. 38 refs., 5 figs., 1 tab.

  7. High Btu gas from peat. A feasibility study. Part 2. Management plans for project continuation. Task 10. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-01-01T23:59:59.000Z

    The primary objective of this task, which was the responsibility of the Minnesota Gas Company, was to determine the needs of the project upon completion of the feasibility study and determine how to implement them most effectively. The findings of the study do not justify the construction of an 80 billion Btu/day SNG from peat plant. At the present time Minnegasco will concentrate on other issues of peat development. Other processes, other products, different scales of operation - these are the issues that Minnegasco will continue to study. 3 references.

  8. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect (OSTI)

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01T23:59:59.000Z

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  9. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

    1995-12-01T23:59:59.000Z

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  10. Dale Coke: Coke Farm

    E-Print Network [OSTI]

    Farmer, Ellen

    2010-01-01T23:59:59.000Z

    the right place to get compost, or how you get the beststerilized or pasteurized our compost before we put it out.

  11. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L. [Bethlehem Steel Corp., Burns Harbor, IN (United States); [Bethlehem Steel Corp., PA (United States)

    1997-12-31T23:59:59.000Z

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  12. Use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Popov, A.A.; Rezunenko, Yu.I.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution which show that the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be recovered in the form of ethylenethiourea - a marketable byproduct.

  13. Design, construction and start-up of a modern coke plant

    SciTech Connect (OSTI)

    Williams, A.E.

    1983-05-01T23:59:59.000Z

    The planning and design of a 60-oven, 6m replacement coke battery and associated by-products plant for Republic Steel Corp, Chicago, are described together with the constructional methods used and problems experienced through start-up of the facility. Pushing emission control is achieved with a Mitsubishi-type land-based system and changing emission control with a Nippon Steel combination car and land-based system. A Takahax-Hirohax coke-oven gas desulphurization unit is included in the by-product plant. Construction began in March 1979 with the first push in December 1981.

  14. The use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Rezunenko, Y.I.; Popov, A.A.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution showed the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be used in the form of ethylenethiourea - a marketable byproduct.

  15. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A. [National Steel Corp., Granite City, IL (United States). Granite City Div.

    1995-12-01T23:59:59.000Z

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  16. Utilizing secondary heat to heat wash oil in the coke-oven gas desulfurization division

    SciTech Connect (OSTI)

    Volkov, E.L.

    1981-01-01T23:59:59.000Z

    Removal of hydrogen sulfide from the coke-oven gas by the vacuum-carbonate method involves significant energy costs, comprising about 47% of the total costs of the process. This is explained by the significant demand of steam for regeneration of the wash oil, the cost of which exceeds 30% of the total operating costs. The boiling point of the saturated wash oil under vacuum does not exceed 70/sup 0/C, thus the wash oil entering the regenerator can be heated either by the direct coke-oven gas or by the tar supernatant from the gas collection cycle. Utilizing the secondary heat of the direct coke-oven gas and the tar supernatant liquor (the thermal effect is approximately the same) to heat the wash oil from the gas desulfurization shops significantly improves the industrial economic indices. Heating the wash oil from gas desulfurization shops using the vacuum-carbonate method by the heat of the tar supernatant liquor may be adopted at a number of coking plants which have a scarcity of thermal resources and which have primary coolers with vertical tubes.

  17. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01T23:59:59.000Z

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  18. Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore Torquatob)

    E-Print Network [OSTI]

    Torquato, Salvatore

    Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore of a Brownian particle diffusing among a, digitized lattice-based domain of traps. Following the first, the inverse of the trapping rate, is obtained for a variety of configurations involving digitized spheres

  19. Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report

    SciTech Connect (OSTI)

    Not Available

    1994-05-24T23:59:59.000Z

    This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

  20. Final environmental information volume for the coke oven gas cleaning project at the Bethlehem Steel Corporation Sparrows Point Plant

    SciTech Connect (OSTI)

    Not Available

    1990-04-24T23:59:59.000Z

    Bethelehem Steel Corporation (BSC) is planning to conduct a demonstration project involving an integrated system that can be retrofitted into coke oven gas handling systems to address a variety of environmental and operational factors in a more cost-effective manner. Successful application of this technology to existing US coke plants could: (1) reduce emissions of sulfur dioxide, cyanide, and volatile organic compounds (including benzene) (2) reduce the cost and handling of processing feed chemicals, (3) disposal costs of nuisance by-products and (4) increase reliability and reduce operation/maintenance requirements for coke oven gas desulfurization systems. The proposed system will remove sulfur from the coke oven gas in the form of hydrogen sulfide using the ammonia indigenous to the gas as the primary reactive chemical. Ammonia and hydrogen cyanide are also removed in this process. The hydrogen sulfide removed from the coke oven gas in routed to a modified Claus plant for conversion to a saleable sulfur by-product. Ammonia and hydrogen cyanide will be catalytically converted to hydrogen, nitrogen, carbon dioxide, and carbon monoxide. The tail gas from the sulfur recovery unit is recycled to the coke oven gas stream, upstream of the new gas cleaning system. The proposed demonstration project will be installed at the existing coke oven facilities at BSC's Sparrows Point Plant. This volume describes the proposed actions and the resulting environmental impacts. 21 refs., 19 figs., 9 tabs.

  1. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01T23:59:59.000Z

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  2. Valorization of Automotive Shredder Residues in metallurgical furnaces Project REFORBA

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ) and the electric arc furnace (EAF) routes, P1 could be used as substitute for coal or coke, and P2 could replace with raw materials cheaper than coke. As additional potential benefits the amount of CO2 generated

  3. Coke oven doors: Historical methods of emission control and evaluation of current designs

    SciTech Connect (OSTI)

    Pettrey, J.O.; Greene, D.E. (Armco Steel Co., Middletown, OH (United States))

    1993-01-01T23:59:59.000Z

    The containment of oven door leakage has presented challenges to coke producers for many years as the requirements of environmental regulatory agencies have become increasingly stringent. A description and evaluation of past door modifications, leakage control methodologies and luting practices on Armco Steel Company, L.P.'s Ashland No. 4 Battery is detailed to provide a background for recent work, and to expand the industry's technology base. The strict door leakage standards of the 1990 amendments to the USA Clean Air Act has prompted additional technical studies. Both a joint Armco committee's evaluation of successful systems world wide and test door installations at Ashland were incorporated to determine compliance strategy. The eventual installation of Ikio Model II coke oven doors, along with modifications to ancillary equipment, has resulted in door leakage rates approaching zero. Associated methods, problems, results and evaluations are discussed.

  4. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31T23:59:59.000Z

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  5. Choosing a coke-oven gas desulfurization system: a review of current technology

    SciTech Connect (OSTI)

    Lynch, P.A.

    1982-12-01T23:59:59.000Z

    Installation of coke-oven gas desulphurizing systems is primarily the result of air pollution control regulations. Although not currently profitable, operating costs can be minimized by choosing the technology most suited to the particular application. The Stretford Holmes, Takahax/Hirohax, Koppers Vacuum Carbonate, Sulfiban and Dravo/Still processes are discussed, together with criteria for economic analysis based on technical and by-product market evaluations.

  6. Method of washing hydrogen sulfide from coke oven gas by the ammonium sulfide method

    SciTech Connect (OSTI)

    Ritter, H.

    1985-05-21T23:59:59.000Z

    An improved coke oven gas washing process for removing hydrogen sulfide is proposed wherein the coke oven gas is treated in a hydrogen sulfide scrubber by counterflow with an aqueous ammonia wash water. A stream of aqueous weak ammonia liquor is cooled and sprayed through nozzles in the mid-region of the hydrogen sulfide scrubber. A quantity of aqueous ammonia liquor, corresponding to the quantity which is sprayed through the said nozzles, is withdrawn from the hydrogen sulfide scrubber at a level below the nozzles and is introduced into the top of the said hydrogen sulfide scrubber. Ammonia vapor released at the nozzles has a higher partial pressure than the ammonia partial pressure of the coke oven gas in the region of the nozzle. The aqueous ammonia liquor from the deacidifier is the source of the cooled aqueous ammonia liquor which is introduced through the nozzles. A portion of the aqueous ammonia liquor from the deacidifier is introduced directly into the top of the hydrogen sulfide scrubber as a portion of the required aqueous ammonia wash water.

  7. Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel

    SciTech Connect (OSTI)

    Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W. [Geneva Steel, Provo, UT (United States)

    1996-02-01T23:59:59.000Z

    The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

  8. Health-hazard evaluation report No. HETA-88-377-2120, Armco Coke Oven, Ashland Kentucky

    SciTech Connect (OSTI)

    Kinnes, G.M.; Fleeger, A.K.; Baron, S.L.

    1991-06-01T23:59:59.000Z

    In response to a request from the Oil, Chemical and Atomic Workers International Union, a study was made of possible hazardous working conditions at ARMCO Coke Oven (SIC-3312), Ashland, Kentucky. The facility produces about 1,000,000 tons of coke annually. Of the approximately 400 total employees at the coke oven site, 55 work in the by products area. Air quality sampling results indicated overexposure to both benzene (71432) and coal tar pitch volatiles (CTPVs). Airborne levels of benzene ranged as high as 117 parts per million (ppm) with three of 17 samples being above the OSHA limit of 1ppm. Airborne concentrations of CTPVs ranged as high as 0.38mg/cu m with two of six readings being above OSHA limit of 0.2mg/cu m. Several polynuclear aromatic hydrocarbons were also detected. The authors conclude that by products area workers are potentially overexposed to carcinogens, including benzene, CTPVs, and polynuclear aromatic hydrocarbons. An epidemiologic study is considered unlikely to yield meaningful information at this time, due to the small number of workers and the short follow up period. The authors recommend specific measures for reducing potential employee exposures, including an environmental sampling program, a preventive maintenance program, improved housekeeping procedures, and reducing exposure in operators' booths.

  9. System and process for the abatement of casting pollution, reclaiming resin bonded sand, and/or recovering a low BTU fuel from castings

    DOE Patents [OSTI]

    Scheffer, Karl D. (121 Governor Dr., Scotia, NY 12302)

    1984-07-03T23:59:59.000Z

    Air is caused to flow through the resin bonded mold to aid combustion of the resin binder to form a low BTU gas fuel. Casting heat is recovered for use in a waste heat boiler or other heat abstraction equipment. Foundry air pollution is reduced, the burned portion of the molding sand is recovered for immediate reuse and savings in fuel and other energy is achieved.

  10. System and process for the abatement of casting pollution, reclaiming resin bonded sand, and/or recovering a low Btu fuel from castings

    DOE Patents [OSTI]

    Scheffer, K.D.

    1984-07-03T23:59:59.000Z

    Air is caused to flow through the resin bonded mold to aid combustion of the resin binder to form a low Btu gas fuel. Casting heat is recovered for use in a waste heat boiler or other heat abstraction equipment. Foundry air pollutis reduced, the burned portion of the molding sand is recovered for immediate reuse and savings in fuel and other energy is achieved. 5 figs.

  11. Low NO{sub x} turbine power generation utilizing low Btu GOB gas. Final report, June--August 1995

    SciTech Connect (OSTI)

    Ortiz, I.; Anthony, R.V.; Gabrielson, J.; Glickert, R.

    1995-08-01T23:59:59.000Z

    Methane, a potent greenhouse gas, is second only to carbon dioxide as a contributor to potential global warming. Methane liberated by coal mines represents one of the most promising under exploited areas for profitably reducing these methane emissions. Furthermore, there is a need for apparatus and processes that reduce the nitrogen oxide (NO{sub x}) emissions from gas turbines in power generation. Consequently, this project aims to demonstrate a technology which utilizes low grade fuel (CMM) in a combustion air stream to reduce NO{sub x} emissions in the operation of a gas turbine. This technology is superior to other existing technologies because it can directly use the varying methane content gases from various streams of the mining operation. The simplicity of the process makes it useful for both new gas turbines and retrofitting existing gas turbines. This report evaluates the feasibility of using gob gas from the 11,000 acre abandoned Gateway Mine near Waynesburg, Pennsylvania as a fuel source for power generation applying low NO{sub x} gas turbine technology at a site which is currently capable of producing low grade GOB gas ({approx_equal} 600 BTU) from abandoned GOB areas.

  12. An example of alkalization of SiO{sub 2} in a blast furnace coke

    SciTech Connect (OSTI)

    S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

    2007-09-15T23:59:59.000Z

    Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

  13. Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks

    SciTech Connect (OSTI)

    S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

  14. Experience and results of new heating control system of coke oven batteries at Rautaruukki Oy Raahe Steel

    SciTech Connect (OSTI)

    Swanljung, J.; Palmu, P. [Rautaruukki Oy Raahe Steel (Finland)

    1997-12-31T23:59:59.000Z

    The latest development and results of the heating control system at Raahe Steel are presented in this paper. From the beginning of coke production in Rautaruukki Oy Raahe Steel (October 1987) the heating control systems have been developed. During the first stage of development work at the coking plant (from year 1987 to 1992), when only the first coke oven battery consisting of 35 ovens was in production, the main progress was in the field of process monitoring. After commissioning of the second stage of the coking plant (November 1992), the development of the new heating control model was started. Target of the project was to develop a dynamic control system which guides the heating of batteries through the various process conditions. Development work took three years and the heating control system was commissioned in the year 1995. Principle of the second generation system is an energy balance calculation, coke end temperature determination and dynamic oven scheduling system. The control is based on simultaneous feedforward and feedback control. The fuzzy logic components were added after about one year experience.

  15. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A.

    1988-06-01T23:59:59.000Z

    Today's commercially proved technology to recover oil from the Athabasca oil sands, as practiced by Suncor and Syncrude, involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil. Significant amounts of petroleum coke are produced during the bitumen upgrading process. Suncor burns the bulk of its petroleum coke in boilers to fulfill the energy requirements of the entire operation, still meeting government regulations restricting the amount of sulfur dioxide that can be released to the environment. In contrast, Syncrude is able to burn only 20% of its coke production because of high sulphur dioxide emissions from elsewhere in its operations. The boiler ash (Fly ash) which contains appreciable amounts of metals, such as vanadium, nickel, titianium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke fired steam generation plants. There has been relatively little effort made towards the understanding of the chemical or physical nature of these materials. Knowledge of the physico-chemical properties of these materials will be helpful in assessing their beneficiation and potential use as fuel or metallurigcal coke and the feasibility of extracting some metals, especially Ni and V. In this communication the authors report studies of acid demineralization as a means of reducing ash content of these materials for /sup 13/C NMR spectroscopic investigations.

  16. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

    2009-09-15T23:59:59.000Z

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  17. Reduction of NO[sub x] emissions coke oven gas combustion process

    SciTech Connect (OSTI)

    Terza, R.R. (USS Clairton Works, PA (United States)); Sardesai, U.V. (Westfield Engineering and Services, Inc., Houston, TX (United States))

    1993-01-01T23:59:59.000Z

    The paper describes by-product processing at Clairton Works which uses a unique cryogenic technology. Modifications to the desulfurization facility, nitrogen oxide formation in combustion processes (both thermal and fuel NO[sub x]), and the boilers plants are described. Boilers were used to study the contribution of fuel NO[sub x] formation during the combustion of coke oven gas. Results are summarized. The modifications made to the desulfurization facility resulted in the overall H[sub 2]S emission being reduced by 2-4 grains/100scf and the NO[sub x] emission being reduced by 21-42% in the boiler stacks.

  18. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J. [Magnitogorsk Integrated Iron and Steel Works, (Russian Federation); Gross, M. [Krupp Koppers GmbH, Essen (Germany)

    1995-12-01T23:59:59.000Z

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  19. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J. [Wheeling-Pittsburgh Steel Corp., Follansbee, WV (United States)

    1995-12-01T23:59:59.000Z

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  20. Operating temperature effects on nozzle coking in a cottonseed oil fueled diesel engine

    E-Print Network [OSTI]

    Yarbrough, Charles Michael

    1984-01-01T23:59:59.000Z

    J/'CA] volume rate of change [m /'CA) ? apparent rate of heat release [kJ/'CA] fuel air ratio [kg/kg] heat transfer coefficient [kJ/m 'K sec] ratio of specific heats connecting rod length [m] fuel lower heating value [kJ/kg] total mass of combustion gas...OPERATING TEMPERATURE EFFECTS ON NOZZLE COKING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis CHARLES MICHAEL YARBROUGH Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree cf...

  1. REDUCTION OF PHASE RESIDUALS TO TIME UNITS Larry R. D'Addario

    E-Print Network [OSTI]

    Groppi, Christopher

    , the predicted uplink delay was * *bTu, and at the time of downlink reception the predicted downlink delay transmission, and downlink rece* *ption, respectively, as: ug(t)= sin[!u(t + bTu)] (1) us(t)= sin[!u(t + bTu- Tu)] (2

  2. Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine

    SciTech Connect (OSTI)

    Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

    2007-03-15T23:59:59.000Z

    The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

  3. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  4. Method of operating a coal predrying and heating plant in connection with a coking plant

    SciTech Connect (OSTI)

    Bocsanczy, J.; Knappstein, J.; Stalherm, D.

    1981-01-27T23:59:59.000Z

    A method of preparing and delivering coal to a coking plant comprises conveying the coal to the plant on a moving conveyor while an inert combustion gas is directed over the coal being conveyed. The combustion gas is generated by burning a fuel with air to produce a substantially inert combustion gas which is passed over the coal during its conveying and, thereafter, passed through a cooler for removing the moisture which has been picked up from the coal by the gas. The heating and predrying inert gases are advantageously generated by the direct combustion of air and fuel which are passed through flash dryer tubes and one or more separate separator systems and then delivered into a conveyor pipeline through which the coal is conveyed. A portion of the gases which are generated are also directed with a return gas to a filter for removal of any coal therefrom and to a cooler for removing the moisture picked up from the coal and then back into the stream for delivery to the conveyor for the coal. The inert gas may also be a gas which is circulated in heat exchange relationship with combustion gases which are generated by a combustion of the coal itself. In such a system, a portion of the combustion gases generated are also passed through a condenser or cooler and the cooled and dried waste gases are circulated over the coal being conveyed to the coking oven or its bunkers.

  5. Recovery of flexible polyurethane foam from shredder residue.

    SciTech Connect (OSTI)

    Daniels, E. J.; Jody, b. J.

    1999-06-29T23:59:59.000Z

    Argonne National Laboratory has developed a patented, continuous process for the recovery of flexible polyurethane foam (PUF) from auto shredder residue (ASR). To test the process, Argonne researchers conceived of, designed, and built a continuous foam washing and drying system that was pilot-tested at a shredder facility for six months. Economic analysis of the process, using manufacturers' quotes and operating data from Argonne's pilot plant, indicates a payback of less than two years for a plant producing about 1,000 ton/yr of foam. Samples of clean foam were shipped to three major foam reprocessors; all three indicated that the quality of the PUF recovered by the Argonne process met their requirements. Tests of the recovered foam by an independent testing laboratory showed that the recycled foam met the specifications for several automotive applications, including carpet padding, headliner, and sound-suppression support materials. Recovery of foam reduces the mass and the volume of material going to the landfill by about 5% and 30%, respectively. Annually, recovery will save about 1.2 x 10{sup 12} Btu of energy, cut the amount of solid waste being landfilled by about 150,000 tons, and eliminate the emission of about 250 tons of volatile organic compounds (VOCs) into the air.

  6. Petroleum Coke

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventionalMississippi"site. IfProved(MillionPrice (Percent)82,516 82,971 84,053 85,190

  7. Petroleum Coke

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office(BillionYearPricePrice (Percent)theCity

  8. Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking

    SciTech Connect (OSTI)

    Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

    2007-09-15T23:59:59.000Z

    1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

  9. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15T23:59:59.000Z

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  10. Summing up of discussion on improvement trends in coke-oven gas purification flowsheets

    SciTech Connect (OSTI)

    Zemblevskii, K.K.

    1983-01-01T23:59:59.000Z

    Reference is made to a previously published article that included flowsheets for purification of coke-oven gas. It is concluded that the flowsheets for a process using arsenic-soda and vacuum-carbonate methods of sulfur removal in which the gas is cooled to 303-308/sup 0/K are seriously in error. Schemes involving minor refrigeration, sulfur removal by the circulating ammonia method and ammonia recovery as ammonia liquor are seen as promising but in need of further improvement. One scheme discussed (the VUKhIN scheme) involves ammonia recovery by the circulating phosphate method and sulfur removal by the circulating ammonia method is seen as a replacement for the minor refrigeration method. Since liquid ammonia consumption in agriculture is continually increasing, schemes that result in production of liquid ammonia rather than ammonia liquor should be seriously considered.

  11. Method of recovering sulfur from the hydrogen sulfide contained in coke oven gases

    SciTech Connect (OSTI)

    Laufhutte, D.

    1985-04-30T23:59:59.000Z

    Ammonia and hydrogen sulfide are washed out of the coke oven gas and stripped from the wash liquor in the form of gases and fumes or vapors. The ammonia is decomposed in a nickel catalyzer and a small part of the decomposition gases is supplied directly to a combustion furnace, while the larger part of the combustion gases is first cooled and freed from condensate, and only then supplied to the combustion furnace. In the combustion furnace, the proportion of H/sub 2/S/SO/sub 2/ needed for the Claus process is adjusted by a partial combustion of the decomposition gases. The gases from the combustion furnace are then processed in the Claus plant to sulfur.

  12. Cyanide leaching from soil developed from coking plant purifier waste as influenced by citrate

    SciTech Connect (OSTI)

    Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar [Ruhr-University Bochum, Bochum (Germany). Soil Science and Soil Ecology Group, Faculty of Geosciences

    2004-07-01T23:59:59.000Z

    Soils in the vicinity of manufactured gas plants and coal coking plants are often highly contaminated with cyanides in the form of the compound Prussian blue. The objective of this study was to investigate the influence of citrate on the leaching of iron-cyanide complexes from an extremely acidic soil (pH 2.3) developed from gas purifier waste near a former coking plant. The soil contained 63 g kg{sup -1} CN, 148 g kg{sup -1} Fe, 123 g kg{sup -1} S, and 222 g kg{sup -1} total C. Analysis of the soil by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy revealed the presence of Prussian blue, gypsum, elemental sulfur, jarosite, and hematite. For column leaching experiments, air-dried soil was mixed with purified cristabolite sand at a ratio of 1:3 and packed into chromatography columns. The soil was leached with dilute (0.1 or 1 mM) CaCl{sub 2} solutions and the effluent was collected and analyzed for total and dissolved CN, Ca, Fe, SO{sub 4}, pH, and pe. In the absence of citrate, the total dissolved CN concentration in the effluent was always below current drinking water limits (< 1.92 {mu}M), indicating low leaching potential. Adding citrate at a concentration of 1 mM had little effect on the CN concentrations in the column effluent. Addition of 10 or 100 mM citrate to the influent solution resulted in strong increases in dissolved and colloidal CN concentrations in the effluent.

  13. Innovative coke oven gas cleaning system for retrofit applications. Environmental Monitoring program. Volume 1 - sampling progrom report. Baseline Sampling Program report

    SciTech Connect (OSTI)

    Stuart, L.M.

    1994-05-27T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This innovative coke oven gas cleaning system combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE provided cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct and Environmental Monitoring Plan for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. It also requires the preparation of a final report on the results of the Baseline Compliance and Supplemental Sampling Programs that are part of the EMP and which were conducted prior to the startup of the innovative coke oven gas cleaning system. This report is the Baseline Sampling Program report.

  14. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 1, January 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  15. SOLOX coke-oven gas desulfurization ppm levels -- No toxic waste

    SciTech Connect (OSTI)

    Platts, M. (Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)); Tippmer, K. (Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany))

    1994-09-01T23:59:59.000Z

    For sulfur removal from coke-oven gas, the reduction/oxidation processes such as Stretford are the most effective, capable of removing the H[sub 2]S down to ppm levels. However, these processes have, in the past, suffered from ecological problems with secondary pollutant formation resulting from side reactions with HCN and O[sub 2]. The SOLOX gas desulfurization system is a development of the Stretford process in which the toxic effluent problems are eliminated by installing a salt decomposition process operating according to the liquid-phase hydrolysis principle. In this process, the gaseous hydrolysis products H[sub 2]S, NH[sub 3] and CO[sub 2] are returned to the untreated gas, and the regenerated solution is recycled to the absorption process. The blowdown from the absorption circuit is fed into a tube reactor where the hydrolysis process takes place. The toxic salts react with water, producing as reaction products the gases H[sub 2]S, NH[sub 3] and CO[sub 2], and the nontoxic salt Na[sub 2]SO[sub 4]. From the hydrolysis reactor the liquid stream flows into a fractionating crystallization plant. This plant produces a recycle stream of regenerated absorption solution and a second stream containing most of the Na[sub 2]SO[sub 4]. This second stream comprises the net plant waste and can be disposed of with the excess ammonia liquor or sprayed onto the coal.

  16. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

    2008-05-15T23:59:59.000Z

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  17. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01T23:59:59.000Z

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  18. Residuals, Sludge, and Composting (Maine)

    Broader source: Energy.gov [DOE]

    The Maine Department of Environmental Protection's Residuals, Sludge, and Composting program regulates the land application and post-processing of organic wastes, including sewage sludge, septage,...

  19. Innovative coke oven gas cleaning system for retrofit applications. Quarterly technical progress report No. 4, October 1, 1990 to December 31, 1990

    SciTech Connect (OSTI)

    Kwasnoski, D.

    1993-10-22T23:59:59.000Z

    Work on this coke oven gas cleaning demonstration project (CCT-II) this quarter has been focused on Phase IIB tasks, and include engineering, procurement, construction, and training. Additionally, plans for changes in the operating schedule of the coke plant that affect the demonstration project are described. Engineering efforts are nearly complete. Remaining to be finalized is an assessment of electrical heat tracing/insulation needs for pipe lines, assessment of fire protection requirements, and instrument modifications. Procurement of all major equipment items is complete, except for possible additions to fire fighting capabilities. Major focus is on expediting pipe and structural steel to the project site. Civil construction is complete except for minor pads and bases as required for pipe supports, etc. Erection of the hydrogen sulfide and ammonia scrubber vessels is complete. Installation of scrubber vessel internals is underway. A subcontractor has been retained to develop a computerized program for operations and maintenance training for the coke oven gas treatment plant. Recent developments in the coke plant operating plans will result in reductions in the rate of production of coke oven gas to be processed in the demonstration project.

  20. 7-55E An office that is being cooled adequately by a 12,000 Btu/h window air-conditioner is converted to a computer room. The number of additional air-conditioners that need to be installed is to be determined.

    E-Print Network [OSTI]

    Bahrami, Majid

    7-20 7-55E An office that is being cooled adequately by a 12,000 Btu/h window air-conditioner is converted to a computer room. The number of additional air-conditioners that need to be installed/h. Then noting that each available air conditioner provides 4,000 Btu/h cooling, the number of air- conditioners

  1. Development and introduction of methods for extracting hydrogen sulfide and hydrogen cyanide from coke-oven gas

    SciTech Connect (OSTI)

    Litvinenko, M.S.; Zaichenko, V.M.

    1980-01-01T23:59:59.000Z

    The progress between 1933 and the present in desulfurizing coal gas from coke ovens and making use of the by-products to produce sulfuric acid, thioyanates, etc. is described. The vacuum carbonate process and the monoethanolamine method are apparently now preferred, but some plants are still using modified arsenic-soda processes. More recently additional by-products have been thiocyanates (for producing acrylonitrile fiber) and hydrogen xanthanates. The production of other organic sulfur and cyanide compounds has been investigated for use as herbicides, corrosion inhibitors, etc. (LTN)

  2. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-08-01T23:59:59.000Z

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  3. Catalytic cracking of residual petroleum fractions

    SciTech Connect (OSTI)

    Moore, H.F.; Mayo, S.L.; Goolsby, T.L. (Research and Development Dept., Ashland Petroleum Co., Ashland, KY (US))

    1991-01-01T23:59:59.000Z

    This paper reports on Arabian Light crude oil vacuum bottoms fractionated into five high-boiling fractions by wiped film evaporation, and the fractions subjected to catalytic cracking in a fixed-fluidized bed using a commercial equilibrium cracking catalyst. Density, aromaticity, and heteroatom content generally increased with boiling point, as did metals content except for vanadium and iron which demonstrated possible bimodal distributions. The cracking response of these fractions showed increasing yields of dry gas and coke, with decreasing gasoline yields, as a function of increasing apparent boiling point as would normally be expected. Surprisingly, however, local maxima were observed for wet gas yield and total conversion, with local minima for cycle oil and slurry yields, in the region of the 1200-1263{degrees}F (650-680{degrees}C) middle fraction. All fractions showed significant response to cracking, with coke yields generally being the only negative factor observed.

  4. Chemical Characterization of Individual Particles and Residuals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Individual Particles and Residuals of Cloud Droplets and Ice Crystals Collected On Board Research Chemical Characterization of Individual Particles and Residuals of Cloud Droplets...

  5. DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES

    SciTech Connect (OSTI)

    Kyser, E

    2009-01-12T23:59:59.000Z

    This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

  6. Startup and initial operation of a DFGD and pulse jet fabric filter system on Cokenergy's Indiana Harbor coke oven off gas system

    SciTech Connect (OSTI)

    Morris, W.J.; Gansley, R.R.; Schaddell, J.G.

    1999-07-01T23:59:59.000Z

    This paper describes the design, initial operation and performance testing of a Dry Flue Gas Desulfurization (DFGD) and Modular Pulse Jet Fabric Filter (MPJFF) system installed at Cokenergy's site in East Chicago, Indiana. The combined flue gas from the sixteen (16) waste heat recovery boilers is processed by the system to control emissions of sulfur dioxide and particulates. These boilers recover energy from coke oven off gas from Indiana Harbor Coke Company's coke batteries. The DFGD system consists of two 100% capacity absorbers. Each absorber vessel uses a single direct drive rotary atomizer to disperse the lime slurry for SO{sub 2} control. The MPJFF consists of thirty two (32) modules arranged in twin sixteen-compartment (16) units. The initial start up of the DFGD/MPJFF posed special operational issues due to the low initial gas flows through the system as the four coke oven batteries were cured and put in service for the first time. This occurred at approximately monthly intervals beginning in March 1998. A plan was implemented to perform a staged startup of the DFGD and MPJFF to coincide with the staged start up of the coke batteries and waste heat boilers. Operational issues that are currently being addressed include reliability of byproduct removal. Performance testing was conducted in August and September 1998 at the inlet of the system and the outlet stack. During these tests, particulate, SO{sub 2}, SO{sub 3}, and HCI emissions were measured simultaneously at the common DFGD inlet duct and the outlet stack. Measurements were also taken for average lime, water, and power consumption during the tests as well as system pressure losses. These results showed that all guarantee parameters were achieved during the test periods. The initial operation and performance testing are described in this paper.

  7. Influence of technological factors on statics of hydrogen sulfide absorption from coke-oven gas by the ammonia process

    SciTech Connect (OSTI)

    Nazarov, V.G.; Kamennykh, B.M.; Rus'yanov, N.D.

    1983-01-01T23:59:59.000Z

    The basic technological factors that determine the effectiveness of hydrogen sulfide absorption from coke-oven gas by the cyclic ammonia process are the initial H/sub 2/S content of the gas, the degree of purification, the absorption temperature and the NH/sub 3/ and CO/sub 2/ contents of the absorbent solution. The effects of these factors on the statics of hydrogen sulfide absorption are studied. The investigation is based on the phase-equilibrium distributions of components in the absorption-desorption gas-cleaning cycle. The mathematical model is presented which includes the solution of a system of chemical equilibrium equations for reactions in the solution, material balances, and electrical neutrality. 4 references, 5 figures, 1 table.

  8. First BTU | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdf Jump to:ar-80m.pdfFillmore County, Minnesota:Island, NewFirmGreen

  9. BTU LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovation in Carbon CaptureAtria PowerAxeonBCHP ScreeningBLMBSABTBTR

  10. Residual activation of accelerator components

    SciTech Connect (OSTI)

    Rakhno, I.L.; Mokhov, N.V.; Striganov, S.I.; /Fermilab

    2008-02-01T23:59:59.000Z

    A method to calculate residual activation of accelerator components is presented. A model for residual dose estimation for thick objects made of arbitrary composite materials for arbitrary irradiation and cooling times is employed in this study. A scaling procedure is described to apply the model to thin objects with linear dimensions less than a fraction of a nuclear interaction length. The scaling has been performed for various materials and corresponding factors have been determined for objects of certain shapes (slab, solid and hollow cylinder) that can serve as models for beam pipes, magnets and collimators. Both contact residual dose and dose attenuation in the air outside irradiated objects are considered. A relation between continuous and impulse irradiation is accounted for as well.

  11. Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products

    SciTech Connect (OSTI)

    Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2007-07-01T23:59:59.000Z

    A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

  12. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2005-12-01T23:59:59.000Z

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  13. Transforms for prediction residuals in video coding

    E-Print Network [OSTI]

    Kam??l?, Fatih

    2010-01-01T23:59:59.000Z

    Typically the same transform, the 2-D Discrete Cosine Transform (DCT), is used to compress both image intensities in image coding and prediction residuals in video coding. Major prediction residuals include the motion ...

  14. Influence of low and high temperature coking of H-GaMFI propane aromatization catalyst on its surface and catalytic properties

    SciTech Connect (OSTI)

    Choudhary, V.R.; Kinage, A.K.; Devadas, P. [National Chemical Lab., Pune (India)] [and others] [National Chemical Lab., Pune (India); and others

    1997-03-01T23:59:59.000Z

    H-Gallosilicate (MFI) (i.e., H-GaMFI) zeolite shows high activity/selectivity in the aromatization of lower alkanes, which is processes of treat practical importance. The high aromatization activity of this catalyst is attributed to its high dehydrogenation activity due to the presence of high dispersed nonframework Ga-oxide species (which are formed during hydrothermal synthesis and/or pretreatments to the zeolite) along with the zeolitic acid sites (or framework Ga), resulting in a bifunctional catalyst. However, this zeolite undergoes fast catalyst deactivation in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization at 500-550{degrees}C for a short time-on-stream (10 h). It is interesting to know the effect of catalyst deactivation due to coking in the propane aromatization for much longer periods both at low (at 400{degrees}C) and high (at 550{degrees}C) temperatures on the product selectivity and also on the surface (viz., sorption capacity, acidity/acid strength distribution) and catalytic properties of the zeolite. The present investigation was undertaken for this purpose. 16 refs., 1 fig., 3 tabs.

  15. Residual Stresses in Weldments by Neutron Diffraction

    E-Print Network [OSTI]

    Bandara, Arosha

    Rectors and Pressurised Water Reactors Source of Problem · Internal Residual Stress · Material propertiesResidual Stresses in Weldments by Neutron Diffraction Shanmukha Rao M, Jon James, Shirley Northover of Residual Stress inside Materials Material: 3 Pass Weld Austenitic Stainless Steel Working Principle

  16. DRAINED RESIDUAL STRENGTH OF COHESIVE SOILSa

    E-Print Network [OSTI]

    that the residual friction angle is independent of the original shear strength, water content, and liquidity indexDRAINED RESIDUAL STRENGTH OF COHESIVE SOILSa Discussion by Robert W. Day,3 Fellow, ASCE The authors have preparcd an important paper on the drained residual shear strength of cohesive soil. The authors

  17. Reduction of COD in leachate from a hazardous waste landfill adjacent to a coke-making facility

    SciTech Connect (OSTI)

    Banerjee, K.; O`Toole, T.J. [Chester Environmental, Moon Township, PA (United States)

    1995-12-01T23:59:59.000Z

    A hazardous waste landfill adjacent to a coke manufacturing facility was in operation between July 1990 and December 1991. A system was constructed to collect and treat the leachate from the landfill prior to discharge to the river. Occasionally, the discharge from the treatment facility exceeded the permit limitations for Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), and Total Organic Carbon (TOC). The objectives of this study were to determine treatment methods which would enable compliance with the applicable discharge limits; to establish the desired operating conditions of the process; and to investigate the effect of various parameters such as pH, catalyst dosage, and reaction time on the COD destruction efficiency. The characteristics of the landfill leachate in question were significantly variable in terms of chemical composition. A review of the influent quality data suggests that the COD concentration ranges between 80 and 390 mg/l. The oxidation processes using Fenton`s reagent or a combination of UV/hydrogen peroxide/catalyst are capable of reducing the COD concentration of the leachate below the discharge limitation of 35 mg/l. The estimated capital cost associated with the Fenton`s reagent process is approximately $525,000, and the annual operating and maintenance cost is $560,000. The estimated capital cost for the UV/hydrogen peroxide/catalyst treatment system is $565,000. The annual operating and maintenance cost of this process would be approximately $430,000.

  18. Process to recycle shredder residue

    DOE Patents [OSTI]

    Jody, Bassam J. (Chicago, IL); Daniels, Edward J. (Oak Lawn, IL); Bonsignore, Patrick V. (Channahon, IL)

    2001-01-01T23:59:59.000Z

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  19. Particulate residue separators for harvesting devices

    SciTech Connect (OSTI)

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  20. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  1. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10T23:59:59.000Z

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  2. Contributions to the development of residual discretizations

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Contributions to the development of residual discretizations for hyperbolic conservation laws with application to shallow water flows Manuscript submitted in fulfillment of the requirements for the obtention;Contents 1 Overview 9 1.1 Residual schemes for hyperbolic conservation laws

  3. Asymptotics for GARCH Squared Residual Correlations

    E-Print Network [OSTI]

    Kokoszka, Piotr

    Asymptotics for GARCH Squared Residual Correlations Istv'an Berkes \\Lambda A. R'enyi Institute a GARCH(p; q) model. Denoting by â?? r n (k); k â?? 1; these autocorrelations computed from a realization words and phrases: GARCH(p; q) sequence, quasi--maximum likelihood esti­ mator, squared residuals

  4. University of Pittsburgh Residual Funds on

    E-Print Network [OSTI]

    Sibille, Etienne

    University of Pittsburgh Residual Funds on FINANCIAL GUIDELINE Subject: Sponsored Projects I by the sponsor. Funds cannot be unilaterally retained by the University. Failure to return residual funds related funds on sponsored grants and contracts on the financial accounting records of the University

  5. Data Conversion in Residue Number System

    E-Print Network [OSTI]

    Zilic, Zeljko

    for direct conversion when interaction with the real analog world is required. We first develop two efficient schemes for direct analog-to-residue conversion. Another efficient scheme for direct residue analogique réel est nécessaire. Nous dévelopons deux systèmes efficaces pour la conversion directe du domaine

  6. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 3, January 1, 1991--December 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  7. Process for separating, especially in multiple stages, acid components such as CO/sub 2/, HCN and specifically H/sub 2/S, from gases, especially from coke oven gases, by means of ammonia recirculation scrubbing

    SciTech Connect (OSTI)

    Bauer, H.K.; Otte, E.A.W.

    1984-10-16T23:59:59.000Z

    A process of separating in multiple stages acid components in coke oven gas such as CO/sub 2/, HCN and particularly H/sub 2/S by ammonia scrubbing wherein the ammonia used in scrubbing is deacidified to remove the acid components and is recirculated to the scrubbing process at least in part as substantially pure liquid ammonia.

  8. Arabian crude-oil residues evaluated

    SciTech Connect (OSTI)

    Ali, M.F.; Bukhari, A.; Hasan, M.; Saleem, M.

    1985-08-12T23:59:59.000Z

    This article evaluates detailed physical and chemical characteristics for four important Saudi Arabian resids. Petroleum residues are composed of a mixture of large and complex hydrocarbon molecules along with one or more heteroatoms such as sulfur, oxygen, nitrogen, vanadium, and nickel. The amount of residue and its physical and chemical composition depend on the source of the crude oil and methods of processing. Residues from four Saudi Arabian crude oils produced by the Arabian American Oil Co. (Aramco) were evaluated. The crude oils are 38.5 degrees API Arabian Extra Light, 33.8 degrees API Arabian Light, 30.4 degrees Api Arabian Medium, and 28.03 degrees API Arabian Heavy. Results are presented and residue preparation, and physical and chemical characteristics are analyzed.

  9. California: Agricultural Residues Produce Renewable Fuel | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Logos Technologies and EERE partnered with EdeniQ of Visalia, California, to construct a pilot plant that processes 1.2 tons per day of agricultural residues, such as corn stover...

  10. Residual stress in nanocrystalline nickel tungsten electrodeposits

    E-Print Network [OSTI]

    Ziebell, Tiffany D. (Tiffany Dawn)

    2011-01-01T23:59:59.000Z

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We employ a three-dimensional ...

  11. Residual Toxicities of Insecticides to Cotton Insects.

    E-Print Network [OSTI]

    Hightower, B. G.; Gaines, J. C.

    1960-01-01T23:59:59.000Z

    Summary Results of experiments conducted to determine leafworm, the salt-marsh caterpillar and the garden the effect of natural or simulated climatic conditions webworm. on the residual toxicities of several chlorinated hydro- carbon... variety of weathering conditions. Based on residual properties alone, toxaphene and dieldrin ranked with endrin and Sevin, but the initial toxicities of dieldrin and endrin to the boll weevil were appreciably greater than those of toxaphene...

  12. Residual Toxicities of Insecticides to Cotton Insects. 

    E-Print Network [OSTI]

    Hightower, B. G.; Gaines, J. C.

    1960-01-01T23:59:59.000Z

    Summary Results of experiments conducted to determine leafworm, the salt-marsh caterpillar and the garden the effect of natural or simulated climatic conditions webworm. on the residual toxicities of several chlorinated hydro- carbon... variety of weathering conditions. Based on residual properties alone, toxaphene and dieldrin ranked with endrin and Sevin, but the initial toxicities of dieldrin and endrin to the boll weevil were appreciably greater than those of toxaphene...

  13. ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues...

    Energy Savers [EERE]

    ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues In a Densified Large Square Bale Format ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues In a...

  14. Sustainable System for Residual Hazards Management

    SciTech Connect (OSTI)

    Kevin M. Kostelnik; James H. Clarke; Jerry L. Harbour

    2004-06-01T23:59:59.000Z

    Hazardous, radioactive and other toxic substances have routinely been generated and subsequently disposed of in the shallow subsurface throughout the world. Many of today’s waste management techniques do not eliminate the problem, but rather only concentrate or contain the hazardous contaminants. Residual hazards result from the presence of hazardous and/or contaminated material that remains on-site following active operations or the completion of remedial actions. Residual hazards pose continued risk to humans and the environment and represent a significant and chronic problem that require continuous longterm management (i.e. >1000 years). To protect human health and safeguard the natural environment, a sustainable system is required for the proper management of residual hazards. A sustainable system for the management of residual hazards will require the integration of engineered, institutional and land-use controls to isolate residual contaminants and thus minimize the associated hazards. Engineered controls are physical modifications to the natural setting and ecosystem, including the site, facility, and/or the residual materials themselves, in order to reduce or eliminate the potential for exposure to contaminants of concern (COCs). Institutional controls are processes, instruments, and mechanisms designed to influence human behavior and activity. System failure can involve hazardous material escaping from the confinement because of system degradation (i.e., chronic or acute degradation) or by externalintrusion of the biosphere into the contaminated material because of the loss of institutional control. An ongoing analysis of contemporary and historic sites suggests that the significance of the loss of institutional controls is a critical pathway because decisions made during the operations/remedial action phase, as well as decisions made throughout the residual hazards management period, are key to the longterm success of the prescribed system. In fact, given that society has become more reliant on and confident of engineered controls, there may be a growing tendency to be even less concerned with institutional controls.

  15. Experimental program for the development of peat gasification. Process designs and cost estimates for the manufacture of 250 billion Btu/day SNG from peat by the PEATGAS Process. Interim report No. 8

    SciTech Connect (OSTI)

    Arora, J.L.; Tsaros, C.L.

    1980-02-01T23:59:59.000Z

    This report presents process designs for the manufacture of 250 billion Btu's per day of SNG by the PEATGAS Process from peats. The purpose is to provide a preliminary assessment of the process requirements and economics of converting peat to SNG by the PEATGAS Process and to provide information needed for the Department of Energy (DOE) to plan the scope of future peat gasification studies. In the process design now being presented, peat is dried to 35% moisture before feeding to the PEATGAS reactor. This is the basic difference between the Minnesota peat case discussed in the current report and that presented in the Interim Report No. 5. The current design has overall economic advantages over the previous design. In the PEATGAS Process, peat is gasified at 500 psig in a two-stage reactor consisting of an entrained-flow hydrogasifier followed by a fluidized-bed char gasifier using steam and oxygen. The gasifier operating conditions and performance are necessarily based on the gasification kinetic model developed for the PEATGAS reactor using the laboratory- and PDU-scale data as of March 1978 and April 1979, respectively. On the basis of the available data, this study concludes that, although peat is a low-bulk density and low heating value material requiring large solids handling costs, the conversion of peat to SNG appears competitive with other alternatives being considered for producing SNG because of its very favorable gasification characteristics (high methane formation tendency and high reactivity). As a direct result of the encouraging technical and economic results, DOE is planning to modify the HYGAS facility in order to begin a peat gasification pilot plant project.

  16. BY HOW MUCH CAN RESIDUAL MINIMIZATION ACCELERATE THE CONVERGENCE OF ORTHOGONAL RESIDUAL METHODS?

    E-Print Network [OSTI]

    Gutknecht, Martin H.

    . Examples of such pairs are the conjugate gradient (CG) and the conjugate residual (CR) methods, the full-minimal residual (QMR) methods. Also the pairs consisting of the (bi)conjugate gradient squared (CGS, iterative method, Krylov space method, conjugate gradient method, biconjugate gradient method, CG, CGNE

  17. Residual dust charges in discharge afterglow

    SciTech Connect (OSTI)

    Coueedel, L.; Mikikian, M.; Boufendi, L.; Samarian, A. A. [GREMI - Groupe de Recherches sur l'Energetique des Milieux Ionises, CNRS/Universite d'Orleans, 14 rue d'Issoudun, 45067 Orleans Cedex 2 (France); School of Physics A28, University of Sydney, NSW 2006 (Australia)

    2006-08-15T23:59:59.000Z

    An on-ground measurement of dust-particle residual charges in the afterglow of a dusty plasma was performed in a rf discharge. An upward thermophoretic force was used to balance the gravitational force. It was found that positively charged, negatively charged, and neutral dust particles coexisted for more than 1 min after the discharge was switched off. The mean residual charge for 200-nm-radius particles was measured. The dust particle mean charge is about -5e at a pressure of 1.2 mbar and about -3e at a pressure of 0.4 mbar.

  18. Residual oil conversion in Ashland FCC Units

    SciTech Connect (OSTI)

    Barger, D.F.; Miller, C.B.

    1983-03-01T23:59:59.000Z

    Ashland Petroleum Company is a production-poor refining and marketing company. A company must have refining flexibility to compete in today's crude and marketing situation. Ashland has adopted a dual approach to achieving the required refining flexibility: development and construction of the RCC process, and development of techniques to practice residual oil conversion in Ashland FCC units. This paper discusses the operating techniques Ashland has used to allow residual oil conversion to be practiced in their present day FCC's and shows some of the yields which have been achieved.

  19. Chemical Stabilization of Hanford Tank Residual Waste

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Um, Wooyong; Williams, Benjamin D.; Bowden, Mark E.; Gartman, Brandy N.; Lukens, Wayne W.; Buck, Edgar C.; Mausolf, Edward J.

    2014-03-01T23:59:59.000Z

    Three different chemical treatment methods were tested for their ability to stabilize residual waste from Hanford tank C-202 for reducing contaminant release (Tc, Cr, and U in particular). The three treatment methods tested were lime addition [Ca(OH)2], an in-situ Ceramicrete waste form based on chemically bonded phosphate ceramics, and a ferrous iron/goethite treatment. These approaches rely on formation of insoluble forms of the contaminants of concern (lime addition and ceramicrete) and chemical reduction followed by co-precipitation (ferrous iron/goethite incorporation treatment). The results have demonstrated that release of the three most significant mobile contaminants of concern from tank residual wastes can be dramatically reduced after treatment compared to contact with simulated grout porewater without treatment. For uranium, all three treatments methods reduced the leachable uranium concentrations by well over three orders of magnitude. In the case of uranium and technetium, released concentrations were well below their respective MCLs for the wastes tested. For tank C-202 residual waste, chromium release concentrations were above the MCL but were considerably reduced relative to untreated tank waste. This innovative approach has the potential to revolutionize Hanford’s tank retrieval process, by allowing larger volumes of residual waste to be left in tanks while providing an acceptably low level of risk with respect to contaminant release that is protective of the environment and human health. Such an approach could enable DOE to realize significant cost savings through streamlined retrieval and closure operations.

  20. Innovative Self- Generating Projects 

    E-Print Network [OSTI]

    Kelly, L.

    2013-01-01T23:59:59.000Z

    furnaces ? Flat rolled and tubular steel ESL-IE-13-05-06 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 ? 2013 CLEAResult ? All rights reserved. By-Product Gas Flow COG = Coke Oven Gas BFG...-Product Gas Heat Content Heat Content Compared to Natural Gas Amount available (mmBTU/hr) Coke Oven Gas 475 BTU/scf 55% lower 40.4 Blast Furnace Gas 83 BTU/scf 91% lower 43.2 ESL-IE-13-05-06 Proceedings of the Thrity-Fifth Industrial Energy Technology...

  1. Production of low BTU gas from biomass

    E-Print Network [OSTI]

    Lee, Yung N.

    1981-01-01T23:59:59.000Z

    on gasification as far back as the 1930's. Some of the early work was done using fixed bed gasifiers with wood as the feed mate- In the 1960's, coal was proposed as another possible feed material. Most of the coal gasification was done using moving bed... of downdraft fixed bed, updraft fixed bed or moving bed gasifiers. Most of the work on fluidized bed opera- tion has been concentrated on catalytic cracking units. However, several researchers have used fluidized bed reactors for the gasification process...

  2. Catalytic reactor for low-Btu fuels

    DOE Patents [OSTI]

    Smith, Lance (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Karim, Hasan (Simpsonville, SC); Pfefferle, William C. (Madison, CT)

    2009-04-21T23:59:59.000Z

    An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area. Lastly, at least a portion of the first flow path defines a catalytically active surface.

  3. BTU International Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass Conversions Inc JumpIM 2011-003 Jump to: JumpBPL Global JumpBSST LLCBTMBTU

  4. Directional wavelet transforms for prediction residuals in video coding

    E-Print Network [OSTI]

    Kamisli, Fatih

    Various directional transforms have been developed recently to improve image compression. In video compression, however, prediction residuals of image intensities, such as the motion compensation residual or the resolution ...

  5. 1-D Transforms for the Motion Compensation Residual

    E-Print Network [OSTI]

    Kamisli, Fatih

    Transforms used in image coding are also commonly used to compress prediction residuals in video coding. Prediction residuals have different spatial characteristics from images, and it is useful to develop transforms that ...

  6. In-Situ Method for Treating Residual Sodium

    DOE Patents [OSTI]

    Sherman, Steven R.; Henslee, S. Paul

    2005-07-19T23:59:59.000Z

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  7. Fluidized bed gasification of agricultural residue 

    E-Print Network [OSTI]

    Groves, John David

    1979-01-01T23:59:59.000Z

    is the only energy derived from such a system. The biomass energy project, of' which this re- search into gasification is a part, was designed to investi- gate both combustion and gasification as means to recover energy from agricultural wastes...FLUIDIZED BED GASIFICATION OF AGRICULTURAL RESIDUES A Thesis by JOHN DAVID GROVES Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1979 Major...

  8. Thin layer chromatography residue applicator sampler

    DOE Patents [OSTI]

    Nunes, Peter J. (Danville, CA); Kelly, Fredrick R. (Modesto, CA); Haas, Jeffrey S. (San Ramon, CA); Andresen, Brian D. (Livermore, CA)

    2007-07-24T23:59:59.000Z

    A thin layer chromatograph residue applicator sampler. The residue applicator sampler provides for rapid analysis of samples containing high explosives, chemical warfare, and other analyses of interest under field conditions. This satisfied the need for a field-deployable, small, hand-held, all-in-one device for efficient sampling, sample dissolution, and sample application to an analytical technique. The residue applicator sampler includes a sampling sponge that is resistant to most chemicals and is fastened via a plastic handle in a hermetically sealed tube containing a known amount of solvent. Upon use, the wetted sponge is removed from the sealed tube and used as a swiping device across an environmental sample. The sponge is then replaced in the hermetically sealed tube where the sample remains contained and dissolved in the solvent. A small pipette tip is removably contained in the hermetically sealed tube. The sponge is removed and placed into the pipette tip where a squeezing-out of the dissolved sample from the sponge into the pipette tip results in a droplet captured in a vial for later instrumental analysis, or applied directly to a thin layer chromatography plate for immediate analysis.

  9. REVIEW ARTICLE Impacts of calcium water treatment residue

    E-Print Network [OSTI]

    Ma, Lena

    REVIEW ARTICLE Impacts of calcium water treatment residue on the soil-water-plant system in citrus of calcium water treatment residue (Ca-WTR) for stabilizing Cu in soil and its subsequent influence on Cu. Keywords Calcium water treatment residue . Citrus production . Copper contamination . Soil pH . Remediation

  10. UNCORRECTEDPROOF Effect of channel bifurcation on residual estuarine circulation

    E-Print Network [OSTI]

    Voulgaris, George

    western channel. This is the result of the fact that the magnitude of residual flow scales with the water throughout the water column of the channel while in the adjacent shoals the residual flow is directedUNCORRECTEDPROOF Effect of channel bifurcation on residual estuarine circulation: Winyah Bay, South

  11. Welding residual stresses in ferritic power plant steels

    E-Print Network [OSTI]

    Cambridge, University of

    REVIEW Welding residual stresses in ferritic power plant steels J. A. Francis*1 , H. K. D. H require therefore, an accounting of residual stresses, which often are introduced during welding. To do in the estimation of welding residual stresses in austenitic stainless steels. The progress has been less convincing

  12. PUFF TOO: a residual stress experiment

    SciTech Connect (OSTI)

    Smith, C.W.

    1980-04-01T23:59:59.000Z

    Following the passage of the dynamic effects in a contained explosive detonation, there remains a strong compressive stress field in the material about the cavity. In this experiment, a 454-kg (1000 lb) sphere of high explosive was detonated in saturated ashfall tuff. Instrumentation measured peak stresses over the range of 0.1 to 6.0 GPa (1 to 6 kbar) and the complete stress-time waveform, including the so-called residual stress, at the 0.1 GPa (1 kbar) peak stress range. Mineback revealed detonation-induced fractures and fractures induced by postevent work.

  13. Harvesting Residuals-Economic Energy Link

    E-Print Network [OSTI]

    Owens, E. T.; Curtis, D. B.

    HARVESTING RESIDUALS-ECONOMIC ENERGY LINK E.T. Owens, R.P.F. Research and Productivity Council, Fredericton, N.B. D.B. Curtis, P.Eng. Dept. Forests, Mines and ABSTRACT A description of systems used in integrated harvesting of quality...-for-energy. economics INTRODUCTION The conventional wisdom in efficient harvesting Was to leave the non-merchantable and marginal trees because they had no economic value in the market place. Current technology and a change in the relative values of energy from...

  14. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Dale, L; Opilla, R; Surles, T

    1980-09-01T23:59:59.000Z

    Technologies available for the production of ethanol from whole corn are reviewed. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. The use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - is reviewed as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. The environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass are covered. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  15. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Opilla, R.; Dale, L.; Surles, T.

    1980-05-01T23:59:59.000Z

    A variety of carbohydrate sources can be used as raw material for the production of ethanol. Section 1 is a review of technologies available for the production of ethanol from whole corn. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. Section 2 is a review of the use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. Section 3 deals with the environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  16. Combination process for upgrading residual oils

    SciTech Connect (OSTI)

    Busch, L.E.; Walters, P.W.; Zandona, O.

    1990-01-16T23:59:59.000Z

    This patent describes a method for upgrading high boiling residual portions of crude oils comprising metal contaminants, porphyrins, asphaltenes and high molecular weight multi-ring hydrocarbon material. It comprises: charging a high boiling residual portion of crude oil admixed with diluent in contact with suspended upflowing substantially inert fluidizable solids particulate material at an elevated thermal visbreaking temperature in a riser contact zone for a time sufficient to recover therefrom a vaporous hydrocarbon product higher boiling than gasoline partially decarbonized and demetallized to a lower contaminating metals level, quenching the vaporous product of thermal visbreaking below its dew point after separation from solids, charging quenched thermally modified high boiling hydrocarbon product with a crystalline zeolite cracking catalyst under cracking conditions for a hydrocarbon residence time in a riser cracking zone; recovering a hydrocarbon conversion product; separating a combined C{sub 4} minus wet gas product stream of the visbreaking and zeolite catalyst cracking operating to recover a C{sub 3}-C{sub 4} rich fraction separately from a C{sub 2} minus dry gas product fraction, and regenerating the crystalline zeolite contcontaining catalyst.

  17. Morphing of Geometric Composites via Residual Swelling

    E-Print Network [OSTI]

    Matteo Pezzulla; Steven A. Shillig; Paola Nardinocchi; Douglas P. Holmes

    2015-04-12T23:59:59.000Z

    Understanding and controlling the shape of thin, soft objects has been the focus of significant research efforts among physicists, biologists, and engineers in the last decade. These studies aim to utilize advanced materials in novel, adaptive ways such as fabricating smart actuators or mimicking living tissues. Here, we present the controlled growth-like morphing of 2D sheets into 3D shapes by introducing a new class of geometric composite structures that deform by residual swelling. The morphing of these geometric composites is dictated by both swelling and geometry, with diffusion controlling the swelling-induced actuation, and geometric confinement dictating the structure's deformed shape. Building on a simple mechanical analog, we develop an analytical model that quantitatively describes how the Gaussian and mean curvatures of a thin disk are affected by the interplay among geometry, mechanics, and swelling. This model is in excellent agreement with our experiments and numerics. We show that the dynamics of residual swelling is dictated by a competition between two characteristic diffusive length scales governed by geometry. Our results provide the first 2D analog of Timoshenko's classical formula for the thermal bending of bimetallic beams - our generalization explains how the Gaussian curvature of a 2D geometric composite is affected by geometry and elasticity. The understanding conferred by these results suggests that the controlled shaping of geometric composites may provide a simple complement to traditional manufacturing techniques.

  18. Combustion turbine deposition observations from residual and simulated residual oil studies

    SciTech Connect (OSTI)

    Whitlow, G.A.; Cohn, A.; Lee, S.Y.; Mulik, P.R.; Sherlock, T.P.; Wenglarz, R.A.

    1983-01-01T23:59:59.000Z

    Burning residual oil in utility combustion turbines and the consequent deposition on blades and vanes may adversely affect reliability and operation. Corrosion and deposition data for combustion turbine materials have been obtained through dynamic testing in pressurized passages. The deposition produced by the 1900/sup 0/F (1038/sup 0/C) combustion gases from a simulated and a real residual oil on cooled Udimet 500 surfaces is described. Higher deposition rates for the doped fuel than for the real residual oil raised questions of whether true simulation with this approach can be achieved. Particles 4-8..mu.. m in diameter predominated in the gas stream, with some fraction in the 0.1-12 ..mu.. m range. Deposition rates seemed to be influenced by thermophoretic delivery of small molten particles, tentatively identified as magnesium pyro and metavanadates and free vanadium pentoxide, which may act to bond the larger solid particles arriving by inertial impaction to turbine surfaces. Estimated maintenance intervals for current utility turbines operating with washed and treated residual oil agreed well with field experience.

  19. Method For Characterizing Residual Stress In Metals

    DOE Patents [OSTI]

    Jacobson, Loren A. (Santa Fe, NM); Michel, David J. (Alexandria, VA); Wyatt, Jeffrey R. (Burke, VA)

    2002-12-03T23:59:59.000Z

    A method is provided for measuring the residual stress in metals. The method includes the steps of drilling one or more holes in a metal workpiece to a preselected depth and mounting one or more acoustic sensors on the metal workpiece and connecting the sensors to an electronic detecting and recording device. A liquid metal capable of penetrating into the metal workpiece placed at the bottom of the hole or holes. A recording is made over a period of time (typically within about two hours) of the magnitude and number of noise events which occur as the liquid metal penetrates into the metal workpiece. The magnitude and number of noise events are then correlated to the internal stress in the region of the workpiece at the bottom of the hole.

  20. Recovery of gallium from aluminum industry residues

    SciTech Connect (OSTI)

    Carvalho, M.S.; Neto, K.C.M.; Nobrega, A.W.; Medeiros, J.A.

    2000-01-01T23:59:59.000Z

    A procedure is proposed to recover gallium from flue dust aluminum residues produced in plants by using solid-phase extraction with a commercial polyether-type polyurethane foam (PUF). Gallium can be separated from high concentrations of aluminum, iron, nickel, titanium, vanadium, copper, zinc, sulfate, fluoride, and chloride by extraction with PUF from 3 M sulfuric acid and 3 M sodium chloride concentration medium with at least a 92% efficiency. Gallium backextraction was fast and quantitative with ethanol solution. In all recovery steps commercial-grade reagents could be used, including tap water. The recovered gallium was precipitated with sodium hydroxide solution, purified by dissolution and precipitation, calcinated, and the final oxide was 98.6% pure.

  1. Process converts incineration slag into stabilized residue

    SciTech Connect (OSTI)

    Thauront, J.; Deneux-Mustin, S. (EMC-Services, Paris (France)); Durecu, S. (EMC-Services, Vandoeuvre-Les Nancy (France)); Fraysse, G. (EMC-Services, Saint-Vulbas (France)); Berthelin, J. (Centre de Pedologie Biologique, Vandoeuvre-Les Nancy (France))

    1994-12-01T23:59:59.000Z

    During 1973 and 1974, EMC-Services designed and built a physico-chemical treatment plant in Hombourg, in France's Alsatian region. The plant is still in operation. Since then, EMC-Services has developed substantial experience in environmental projects, becoming one of the top companies internationally with experience and practice in designing, building and operating hazardous waste treatment plants. EMC-Services operates in France in Salaise, Strasbourg, Mitry-Mory, and Saint-Vulbas, where eight incinerators treat solid, liquid, highly halogenated and nonhazardous industrial waste. The incinerators, built or updated by EMC-Services, have a total capacity of about 200,000 tons per year. In the new process, incineration of special industrial wastes produces non-volatilized solid residue or slag, which is sent for disposal, in compliance with regulations, to special disposal plants. Future European regulations will incorporate landfilling criteria requiring such slag to be stabilized.

  2. Bioassays of weathered residues of several organic phosphorus insecticides

    E-Print Network [OSTI]

    Hightower, Billie Gene

    1959-01-01T23:59:59.000Z

    at high temperatures on the residual toxicities of Gut hi on, Sevin, and toxaphene to the boll weevil, Anthonomus grandis Boh........................ . . . . ........ 3^ 3? The effects of simulated wind on the residual toxicities of Guthion, dieldrin..., and toxaphene dusts to the boll weevil, Anthonomus grandis Boh. 36 The effects of high temperatures on the residual toxicities of methyl parathion, malathion, and toxaphene to the boll weevil, Anthonomus grandis Boh...................... 3$ 5. The effects...

  3. Bioassays of weathered residues of several organic phosphorus insecticides 

    E-Print Network [OSTI]

    Hightower, Billie Gene

    1959-01-01T23:59:59.000Z

    at high temperatures on the residual toxicities of Gut hi on, Sevin, and toxaphene to the boll weevil, Anthonomus grandis Boh........................ . . . . ........ 3^ 3? The effects of simulated wind on the residual toxicities of Guthion, dieldrin..., and toxaphene dusts to the boll weevil, Anthonomus grandis Boh. 36 The effects of high temperatures on the residual toxicities of methyl parathion, malathion, and toxaphene to the boll weevil, Anthonomus grandis Boh...................... 3$ 5. The effects...

  4. antimicrobial residue monitoring: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The...

  5. acs residual ischemic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The...

  6. acetamido trideoxyhexose residue: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this...

  7. autophosphorylated residues required: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The...

  8. abradable coating residual: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this...

  9. A Practical Model for Mobile, Residual, and Entrapped NAPL in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    phase. Residual NAPL is defined as immobile, nonwater entrapped NAPL that does not drain from the pore spaces and is conceptualized as being either continuous or...

  10. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22T23:59:59.000Z

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  11. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices," source for backcast estimates prior to January 1983. 19. U.S. Refiner Residual Fuel Oil Prices 36 Energy Information Administration Petroleum Marketing Annual 1997...

  12. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices," source for backcast estimates prior to January 1983. 19. U.S. Refiner Residual Fuel Oil Prices 36 Energy Information Administration Petroleum Marketing Annual 1996...

  13. active site residue: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in human transferrin and Tyr Oksana Lockridge 2008-01-01 140 RESEARCH ARTICLE Benefits of organic residues and chemical fertilizer Biology and Medicine Websites Summary: RESEARCH...

  14. active site residues: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in human transferrin and Tyr Oksana Lockridge 2008-01-01 140 RESEARCH ARTICLE Benefits of organic residues and chemical fertilizer Biology and Medicine Websites Summary: RESEARCH...

  15. acid residues determine: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tomihiro Takano; Yasuhiro Kojima; Tetsufumi Ohno 2013-01-01 206 EFFECTIVE RESIDUE-TILLAGE-MANURE Biology and Medicine Websites Summary: AS POSSIBLE KEEP RECORDS 12;SPREADER...

  16. Water dynamics clue to key residues in protein folding

    SciTech Connect (OSTI)

    Gao, Meng [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Zhu, Huaiqiu, E-mail: hqzhu@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Yao, Xin-Qiu [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China) [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Department of Biophysics, Kyoto University, Sakyo Kyoto 606-8502 (Japan); She, Zhen-Su, E-mail: she@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)

    2010-01-29T23:59:59.000Z

    A computational method independent of experimental protein structure information is proposed to recognize key residues in protein folding, from the study of hydration water dynamics. Based on all-atom molecular dynamics simulation, two key residues are recognized with distinct water dynamical behavior in a folding process of the Trp-cage protein. The identified key residues are shown to play an essential role in both 3D structure and hydrophobic-induced collapse. With observations on hydration water dynamics around key residues, a dynamical pathway of folding can be interpreted.

  17. Residual Stresses for Structural Analysis and Fatigue Life Prediction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stresses for Structural Analysis and Fatigue Life Prediction in Vehicle Components: Success stories from the High Temperature Materials Laboratory (HTML) User Program Residual...

  18. Process for the elimination of waste water produced upon the desulfurization of coking oven gas by means of wash solution containing organic oxygen-carrier, with simultaneous recovery of elemental sulfur

    SciTech Connect (OSTI)

    Diemer, P.; Brake, W.; Dittmer, R.

    1985-04-16T23:59:59.000Z

    A process is disclosed for the elimination of waste water falling out with the desulfurization of coking oven gas by means of an organic oxygen carrier-containing washing solution with simultaneous recovery of elemental sulfur. The waste water is decomposed in a combustion chamber in a reducing atmosphere at temperatures between about 1000/sup 0/ and 1100/sup 0/ C. under such conditions that the mole ratio of H/sub 2/S:SO/sub 2/ in the exhaust gas of the combustion chamber amounts to at least 2:1. Sulfur falling out is separated and the sensible heat of the exhaust gas is utilized for steam generation. The cooled and desulfurized exhaust gas is added to the coking oven gas before the pre-cooling. Sulfur falling out from the washing solution in the oxidizer is separated out and lead into the combustion chamber together with the part of the washing solution discharged as waste water from the washing solution circulation. Preferred embodiments include that the sulfur loading of the waste water can amount to up to about 370 kg sulfur per m/sup 3/ waste water; having the cooling of sulfur-containing exhaust gas leaving the combustion chamber follow in a waste heat boiler and a sulfur condenser heated by pre-heated boiler feed water, from which condenser sulfur is discharged in liquid state.

  19. RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES

    E-Print Network [OSTI]

    Nairn, John A.

    RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES JOHN A. NAIRN ABSTRACT Because composites and adhesive joints are made from different phases with different thermal expansion coefficients, they inevitably develop residual thermal stresses. When designing composites or adhesive joints, it is important

  20. Randomized Quantile Residuals Peter K. Dunn and Gordon K. Smyth

    E-Print Network [OSTI]

    Smyth, Gordon K.

    . Keywords: deviance residual; exponential regression; generalized linear model; lo- gistic regression, play a central role in the checking of statistical models. In normal linear regression the residuals are normally distributed and can be standardized to have equal variances. In non-normal regression situations

  1. Minimization of welding residual stress and distortion in large structures

    E-Print Network [OSTI]

    Michaleris, Panagiotis

    1 Minimization of welding residual stress and distortion in large structures P. Michaleris at Champaign Urbana, Urbana, IL Abstract Welding distortion in large structures is usually caused by buckling due to the residual stress. In cases where the design is fixed and minimum weld size requirements

  2. Modeling Sustainable Agricultural Residue Removal at the Subfield Scale

    SciTech Connect (OSTI)

    Muth, D.J.; McCorkle, D.S.; Koch, J.B.; Bryden, K.M.

    2012-05-02T23:59:59.000Z

    This study developed a computational strategy that utilizes data inputs from multiple spatial scales to investigate how variability within individual fields can impact sustainable residue removal for bioenergy production. Sustainable use of agricultural residues for bioenergy production requires consideration of the important role that residues play in limiting soil erosion and maintaining soil C, health, and productivity. Increased availability of subfield-scale data sets such as grain yield data, high-fidelity digital elevation models, and soil characteristic data provides an opportunity to investigate the impacts of subfield-scale variability on sustainable agricultural residue removal. Using three representative fields in Iowa, this study contrasted the results of current NRCS conservation management planning analysis with subfield-scale analysis for rake-and-bale removal of agricultural residue. The results of the comparison show that the field-average assumptions used in NRCS conservation management planning may lead to unsustainable residue removal decisions for significant portions of some fields. This highlights the need for additional research on subfield-scale sustainable agricultural residue removal including the development of real-time variable removal technologies for agricultural residue.

  3. Original article Residues in wax and honey after Apilife VAR®

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Residues in wax and honey after Apilife VAR® treatment Stefan Bogdanov Anton and foundation were exposed to the air during storage. © Inra/DIB/AGIB/Elsevier, Paris honey / wax / residue to accumulation of these substances in beeswax and less so in honey [1, 17]. The accumulation in wax depends

  4. Computing Symmetrized Weight Enumerators for Lifted Quadratic Residue Codes

    E-Print Network [OSTI]

    Duursma, Iwan M.

    Computing Symmetrized Weight Enumerators for Lifted Quadratic Residue Codes I. M. Duursma Dept for the computation of structural parameters for ring-linear codes. This article therefore presents a method to eĂ?ciently compute weight enumerators of linear codes over primary integer residue rings. For the lifted QR-codes

  5. Residual Energy-Aware Cooperative Transmission (REACT) in Wireless Networks

    E-Print Network [OSTI]

    Leung, Kin K.

    Residual Energy-Aware Cooperative Transmission (REACT) in Wireless Networks Erwu Liu, Qinqing Zhang the lifetime of the network and we call the selection method a residual energy-aware cooperative transmission- works, where energy efficiency is a critical design consideration. We assume that multiple relay nodes

  6. Parallel FPGA Implementation of RSA with Residue Number Systems

    E-Print Network [OSTI]

    Parallel FPGA Implementation of RSA with Residue Number Systems --- Can side­channel threats Multiplication based on Residue Num­ ber Systems. Thanks to RNS, we develop a design able to perform an RSA signature in parallel on a set of identical and independent copro­ cessors. Of independent interest, we

  7. Parallel FPGA Implementation of RSA with Residue Number Systems

    E-Print Network [OSTI]

    Parallel FPGA Implementation of RSA with Residue Number Systems -- Can side-channel threats Multiplication based on Residue Num- ber Systems. Thanks to RNS, we develop a design able to perform an RSA signature in parallel on a set of identical and independent copro- cessors. Of independent interest, we

  8. Conversion of direct process high-boiling residue to monosilanes

    DOE Patents [OSTI]

    Brinson, Jonathan Ashley (Vale of Glamorgan, GB); Crum, Bruce Robert (Madison, IN); Jarvis, Jr., Robert Frank (Midland, MI)

    2000-01-01T23:59:59.000Z

    A process for the production of monosilanes from the high-boiling residue resulting from the reaction of hydrogen chloride with silicon metalloid in a process typically referred to as the "direct process." The process comprises contacting a high-boiling residue resulting from the reaction of hydrogen chloride and silicon metalloid, with hydrogen gas in the presence of a catalytic amount of aluminum trichloride effective in promoting conversion of the high-boiling residue to monosilanes. The present process results in conversion of the high-boiling residue to monosilanes. At least a portion of the aluminum trichloride catalyst required for conduct of the process may be formed in situ during conduct of the direct process and isolation of the high-boiling residue.

  9. Phase Chemistry of Tank Sludge Residual Components

    SciTech Connect (OSTI)

    J.L. Krumhansl

    2002-04-02T23:59:59.000Z

    The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate nearby groundwaters with radionuclides and RCRA metals. Performance assessment (PA) calculations must be carried out prior to closing the tanks. This requires developing radionuclide release models from the sludges so that the PA calculations can be based on credible source terms. These efforts continued to be hindered by uncertainties regarding the actual nature of the tank contents and the distribution of radionuclides among the various phases. In particular, it is of vital importance to know what radionuclides are associated with solid sludge components. Experimentation on actual tank sludges can be difficult, dangerous and prohibitively expensive. The research funded under this grant for the past three years was intended to provide a cost-effective method for developing the needed radionuclide release models using non-radioactive artificial sludges. Insights gained from this work will also have more immediate applications in understanding the processes responsible for heel development in the tanks and in developing effective technologies for removing wastes from the tanks.

  10. DDT RESIDUES IN SEAWATER AND PARTICULATE MATTER IN THE CALIFORNIA CURRENT SYSTEM

    E-Print Network [OSTI]

    DDT RESIDUES IN SEAWATER AND PARTICULATE MATTER IN THE CALIFORNIA CURRENT SYSTEM JAMES L. COX in the California current system were analyzed for DDT residues. DDT residue concentrations in whole seawater are discussed in relation to mechanisms of land-sea DDT residue transfer. DDT residue concentrations

  11. Coking Coal Import Costs - EIA

    Gasoline and Diesel Fuel Update (EIA)

    Import Costs for Selected Countries U.S. Dollars per Metric Ton1 (Average Unit Value, CIF2) Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Belgium 48.67 46.59 49.25 78.98...

  12. Converting Petroleum Coke to Electricity

    E-Print Network [OSTI]

    Pavone, A.

    Changes in oil refining technology and economics are driving refiners to utilize thermal processes to maximize the conversion of heavy crude oil components to clean products. Since the primary unit operation to accomplish this objective...

  13. Single-well experimental design for studying residual trapping of superciritcal carbon dioxide

    E-Print Network [OSTI]

    Zhang, Y.

    2010-01-01T23:59:59.000Z

    nonaqueous phase liquid and water residual. Environ. Sci.plume near residual saturation; and (4) water injection intoboth a water-saturated system and a system with residual gas

  14. Evaluation of approaches to quantify total residual oxidants in ballast water management systems employing chlorine for disinfection

    E-Print Network [OSTI]

    Zimmer-Faust, AG; Ambrose, RF; Ambrose, RF; Tamburri, MN

    2014-01-01T23:59:59.000Z

    quantify total residual oxidants in ballast water managementand discharge (residual concentrations) during ballast waterquantifying residual chlorine levels in natural waters (e.g.

  15. Residual zonal flows in tokamaks and stellarators at arbitrary wavelengths

    E-Print Network [OSTI]

    Monreal, P; Sánchez, E; Parra, F I; Bustos, A; Könies, A; Kleiber, R; Görler, T

    2015-01-01T23:59:59.000Z

    In the linear collisionless limit, a zonal potential perturbation in a toroidal plasma relaxes, in general, to a non-zero residual value. Expressions for the residual value in tokamak and stellarator geometries, and for arbitrary wavelengths, are derived. These expressions involve averages over the lowest order particle trajectories, that typically cannot be evaluated analytically. In this work, an efficient numerical method for the evaluation of such expressions is reported. It is shown that this method is faster than direct gyrokinetic simulations. Calculations of the residual value in stellarators are provided for much shorter wavelengths than previously available in the literature. Electrons must be treated kinetically in stellarators because, unlike in tokamaks, kinetic electrons modify the residual value even at long wavelengths. This effect, that had already been predicted theoretically, is confirmed by gyrokinetic simulations.

  16. An urban infill : a residual site in Boston

    E-Print Network [OSTI]

    Savvides, Andreas L. (Andreas Loucas)

    1996-01-01T23:59:59.000Z

    This thesis is concerned with the treatment of residual sites in the context of the urban environment and in particular with the wounds inflicted by the passage of the Massachusetts Turnpike through the city of Boston. The ...

  17. Residual dust charges in an afterglow plasma , M. Mikikian

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    plasma was performed in a rf discharge. An upward thermophoretic force was used to balance]. For the study concerning residual charges, the top electrode was cooled. An upward thermophoretic force

  18. Minimizing High Spatial Frequency Residual in Active Space Telescope Mirrors

    E-Print Network [OSTI]

    . Miller June 2008 SSL # 4-08 #12;#12;Minimizing High Spatial Frequency Residual in Active Space Telescope Mirrors Thomas Gray, David W. Miller June 2008 SSL # 4-08 This work is based on the unaltered text

  19. RetroFILL : residual spaces as urban infill

    E-Print Network [OSTI]

    Kobel, Marika

    2010-01-01T23:59:59.000Z

    In any city there are small slivers and chunks of awkward spaces - in between buildings, occupying edge conditions, not large enough to warrant many forms of traditional use - which can be termed residual. These areas of ...

  20. Residual stress in electrodeposited nanocrystalline nickel-tungsten coatings

    E-Print Network [OSTI]

    Ziebell, Tiffany D.

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We use a three-dimensional ...

  1. Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification 

    E-Print Network [OSTI]

    Georgeson, Adam

    2012-02-14T23:59:59.000Z

    Gasification is a thermo-chemical process which transforms biomass into valuable synthesis gas. Integrated with a biorefinery it can address the facility’s residue handling challenges and input demands. A number of feedstock, technology, oxidizer...

  2. Asphalt landscape after all : residual suburban surface as public infrastructure

    E-Print Network [OSTI]

    O'Connor, Joseph Michael, M. Arch. Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    The thesis proposes a hybridized commercial retail strip inserted into a residual suburban condition as a manner of investigating the latent potential of suburban logic, both its constituent elements and its formal rules ...

  3. Cracking blends of gas oil and residual oil

    SciTech Connect (OSTI)

    Myers, G.D.

    1988-03-01T23:59:59.000Z

    In a catalytic cracking process unit wherein a gas oil feed is cracked in a cracking zone at an elevated temperature in the presence of a cracking catalyst, the cracking catalyst is regenerated in a regeneration zone by burning coke of the catalyst, and catalyst is circulated between the cracking zone and the regeneration zone. The improvement is described for obtaining a naphtha product of improved octane number comprising introducing sufficient of a nickel and vanadium metals-containing heavy feedstock with the gas oil feed introduced into the cracking zone to deposit nickel and vanadium metals on the catalyst and raise the nickel and metals-content of the catalyst to a level ranging from about 1500 to about 6000 parts per million of the metals expressed as equivalent nickel, based on the weight of the catalyst, and maintaining the nickel and vanadium metals level on the catalyst by withdrawing high nickel and vanadium metals containing catalyst and adding low nickel and vanadium metals-containing catalyst to the regeneration zone.

  4. An investigation of residual stress in welded joints

    E-Print Network [OSTI]

    Moffat, William Hugh

    1951-01-01T23:59:59.000Z

    . flummery and Conclusions VII. '-. &uggested Procedure for I"uture Investigation 18 o i' VIII. ? . Ppendix IX. Bibliography LIST OP EIGURES Ro. Title Page 1. 'welded Plates snd Gptical Gage Used by Soulton and Martin ~ ~ 6 2. Dr. Rao~s Method... AN INVESTIGATION OF RESIDUAL STRESS IN WELDED JOINTS INTRODUCTION The object of the research reported in this paper was to investigate the magnitude of transverse and longi- tudial residual stress in a welded Joint. These are the stresses in a direction...

  5. An investigation of residual stress in welded joints 

    E-Print Network [OSTI]

    Moffat, William Hugh

    1951-01-01T23:59:59.000Z

    . flummery and Conclusions VII. '-. &uggested Procedure for I"uture Investigation 18 o i' VIII. ? . Ppendix IX. Bibliography LIST OP EIGURES Ro. Title Page 1. 'welded Plates snd Gptical Gage Used by Soulton and Martin ~ ~ 6 2. Dr. Rao~s Method... AN INVESTIGATION OF RESIDUAL STRESS IN WELDED JOINTS INTRODUCTION The object of the research reported in this paper was to investigate the magnitude of transverse and longi- tudial residual stress in a welded Joint. These are the stresses in a direction...

  6. GEOCHEMICAL TESTING AND MODEL DEVELOPMENT - RESIDUAL TANK WASTE TEST PLAN

    SciTech Connect (OSTI)

    CANTRELL KJ; CONNELLY MP

    2010-03-09T23:59:59.000Z

    This Test Plan describes the testing and chemical analyses release rate studies on tank residual samples collected following the retrieval of waste from the tank. This work will provide the data required to develop a contaminant release model for the tank residuals from both sludge and salt cake single-shell tanks. The data are intended for use in the long-term performance assessment and conceptual model development.

  7. Residue disposal from waste-to-energy facilities

    SciTech Connect (OSTI)

    Walsh, P.; O'Leary, P.; Cross, F.

    1987-05-01T23:59:59.000Z

    When considering a waste-to-energy project, some local officials believe that waste-to-energy is a complete alternative to landfilling. While these projects can reduce waste volume substantially, the process will still produce residues that must be properly handled in order to protect the environment. All systems produce fly ash and bottom ash, and some systems also produce wastewater. This article discusses alternative methods for addressing these residue control problems.

  8. Residual stresses and stress corrosion cracking in pipe fittings

    SciTech Connect (OSTI)

    Parrington, R.J.; Scott, J.J.; Torres, F.

    1994-06-01T23:59:59.000Z

    Residual stresses can play a key role in the SCC performance of susceptible materials in PWR primary water applications. Residual stresses are stresses stored within the metal that develop during deformation and persist in the absence of external forces or temperature gradients. Sources of residual stresses in pipe fittings include fabrication processes, installation and welding. There are a number of methods to characterize the magnitude and orientation of residual stresses. These include numerical analysis, chemical cracking tests, and measurement (e.g., X-ray diffraction, neutron diffraction, strain gage/hole drilling, strain gage/trepanning, strain gage/section and layer removal, and acoustics). This paper presents 400 C steam SCC test results demonstrating that residual stresses in as-fabricated Alloy 600 pipe fittings are sufficient to induce SCC. Residual stresses present in as-fabricated pipe fittings are characterized by chemical cracking tests (stainless steel fittings tested in boiling magnesium chloride solution) and by the sectioning and layer removal (SLR) technique.

  9. Measuring depth profiles of residual stress with Raman spectroscopy

    SciTech Connect (OSTI)

    Enloe, W.S.; Sparks, R.G.; Paesler, M.A.

    1988-12-01T23:59:59.000Z

    Knowledge of the variation of residual stress is a very important factor in understanding the properties of machined surfaces. The nature of the residual stress can determine a part`s susceptibility to wear deformation, and cracking. Raman spectroscopy is known to be a very useful technique for measuring residual stress in many materials. These measurements are routinely made with a lateral resolution of 1{mu}m and an accuracy of 0.1 kbar. The variation of stress with depth; however, has not received much attention in the past. A novel technique has been developed that allows quantitative measurement of the variation of the residual stress with depth with an accuracy of 10nm in the z direction. Qualitative techniques for determining whether the stress is varying with depth are presented. It is also demonstrated that when the stress is changing over the volume sampled, errors can be introduced if the variation of the stress with depth is ignored. Computer aided data analysis is used to determine the depth dependence of the residual stress.

  10. DDT residues in human milk samples from Delhi, India

    SciTech Connect (OSTI)

    Zaidi, S.S.A.; Bhatnagar, V.K.; Banerjee, B.D.; Balakrishnan, G.; Shah, M.P.

    1989-03-01T23:59:59.000Z

    The widespread use of DDT in India has resulted in increased levels of the insecticide in the ecosystem and, therefore, the potential possible health hazards has been voiced. DDT-residues excreted in milk have been reported from different parts of the world; however, very few reports did appear from India. In fact, there is no report on DDT-content in human milk from Delhi area where higher levels of DDT and BHC in human adipose tissues and blood have already been reported. Higher bioaccumulation of DDT might reflect the higher excretion of residues in milk. The authors have, therefore, attempted a systematic study to monitor DDT-residues in human milk samples collected from various hospitals of Delhi (India).

  11. Residual strain mapping of Roman styli from Iulia Concordia, Italy

    SciTech Connect (OSTI)

    Salvemini, Filomena, E-mail: floriana.salvemini@fi.isc.cnr.it [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy); Universitŕ degli Studi di Firenze, Dipartimento di Scienze della Terra (Italy); Grazzi, Francesco [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy); Angelini, Ivana [Universitŕ degli Studi di Padova, Dipartimento di Geoscienze (Italy); Davydov, Vadim; Vontobel, Peter [Paul Scherrer Institut, SINQ Spallation Neutron Source, Villigen (Switzerland); Vigoni, Alberto [Dedalo s.n.c., Vicolo dei Conti 6, I-35122 Padua (Italy); Artioli, Gilberto [Universitŕ degli Studi di Padova, Dipartimento di Geoscienze (Italy); Zoppi, Marco [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy)

    2014-05-01T23:59:59.000Z

    Iulia Concordia is an important Roman settlement known for the production of iron objects and weapons during the Roman Empire. A huge number of well-preserved styli were found in the past century in the bed of an old channel. In order to shed light about the production processes used by Roman for stylus manufacturing, a neutron diffraction residual strain analysis was performed on the POLDI materials science diffractometer at the Paul Scherrer Institut in Switzerland. Here, we present results from our investigation conducted on 11 samples, allowing to define, in a non-invasive way, the residual strain map related to the ancient Roman working techniques. - Highlights: • We examined 11 Roman styli from the settlement of Iulia Concordia, Italy. • We performed a neutron diffraction residual strain analysis on POLDI at PSI (CH). • We identified the production processes used by Roman for stylus manufacturing. • We clarified the way and direction of working applied for different classes of styli.

  12. Wave induced residual pore-water pressures in sandbeds

    E-Print Network [OSTI]

    DeVries, Jack Walter

    1986-01-01T23:59:59.000Z

    Subject: Ocean Engineering WAVE INDUCED RESIDUAL PORE-WATER PRESSURES IN SANDBEDS A Thesis by Jack W. Deyries Approved as to style and content by: J. B. Her bich (Chairman of Committee) Y. K. Lou (Member) W. A. Dunlap (Member) R. O. Reid (Member... on a buried pipel1ne using both analytical and numerical approaches. Also, a few attempts have been made at describing the generation of residual pore-water pressures using numerical methods. These attempts do not have a data base to work from...

  13. The determination of thru-thickness residual bending stresses

    E-Print Network [OSTI]

    Rinehart, Adam James

    2000-01-01T23:59:59.000Z

    by Bidirectional Bending for the Case y?, & y, , 110 5-1 Finite Elemenl, Mesh Used in Study 116 5-2 Comparison ol Percent Deviation of 100 and 200 Element. FE Models from Exact Solution, 800 k-in Released Moment, No Initial Stresses 123 5-3 Comparison of 200... Elcmcnt FE Solution to Exact Solution for Residual Stress Distribution Produced by 800 k-in Released Momem. in an Initially Stress Free Cross Section, . 124 5-4 Residual Stress Distributions for Increasing Levels of Released Moment, Initially Stress...

  14. Wood residuals find big uses in small pieces

    SciTech Connect (OSTI)

    Glenn, J.

    1996-12-01T23:59:59.000Z

    With a history of finding economic uses for leftovers, the wood industry explores sustainable options for creating higher value products. Years ago, companies saw the use - any use - of residues as a sound, economic business practice. Today, many companies are looking to go beyond low value products such as mulch, animal bedding and fuel, and market to higher value end users. Additionally, with so much material from the primary industries already accounted for, consumers of wood residue are in need of additional supply from sources such as secondary mills (furniture manufacturers, etc.), as wells as the C&D and MSW streams. This paper discusses these products and markets.

  15. A Residual Mass Ballistic Testing Method to Compare Armor Materials or Components (Residual Mass Ballistic Testing Method)

    SciTech Connect (OSTI)

    Benjamin Langhorst; Thomas M Lillo; Henry S Chu

    2014-05-01T23:59:59.000Z

    A statistics based ballistic test method is presented for use when comparing multiple groups of test articles of unknown relative ballistic perforation resistance. The method is intended to be more efficient than many traditional methods for research and development testing. To establish the validity of the method, it is employed in this study to compare test groups of known relative ballistic performance. Multiple groups of test articles were perforated using consistent projectiles and impact conditions. Test groups were made of rolled homogeneous armor (RHA) plates and differed in thickness. After perforation, each residual projectile was captured behind the target and its mass was measured. The residual masses measured for each test group were analyzed to provide ballistic performance rankings with associated confidence levels. When compared to traditional V50 methods, the residual mass (RM) method was found to require fewer test events and be more tolerant of variations in impact conditions.

  16. PROPERTIES OF RESIDUALS FOR SPATIAL POINT PROCESSES A. BADDELEY,

    E-Print Network [OSTI]

    Baddeley, Adrian

    PROPERTIES OF RESIDUALS FOR SPATIAL POINT PROCESSES A. BADDELEY, University of Western Australia J. MŘLLER, University of Aalborg A.G. PAKES, University of Western Australia Abstract For any point process & Statistics M019, University of Western Australia, 35 Stirling Highway, Nedlands WA 6009, Australia Postal

  17. AIAA-2001-0025 SPECTRUM FATIGUE LIFETIME AND RESIDUAL STRENGTH

    E-Print Network [OSTI]

    on a typical fiberglass laminate configuration turbine blade fiberglass material has been undertaken under at various fractions of the lifetime turbine blade materials.. are consistent with the residual strength of fiberglass spectrum have been studied. Data have been obtained for materials produce results that may

  18. Prompt optical emission from residual collisions in GRB outflows

    E-Print Network [OSTI]

    Zhuo Li; Eli Waxman

    2008-01-03T23:59:59.000Z

    The prompt gamma-ray emission in gamma-ray bursts is believed to be produced by internal shocks within a relativistic unsteady outflow. The recent detection of prompt optical emission accompanying the prompt gamma-ray emission appears to be inconsistent with this model since the out flowing plasma is expected to be highly optically thick to optical photons. We show here that fluctuations in flow properties on short, ~ 1 ms, time scale, which drive the gamma-ray producing collisions at small radii, are expected to lead to "residual" collisions at much larger radii, where the optical depth to optical photons is low. The late residual collisions naturally account for the relatively bright optical emission. The apparent simultaneity of gamma-ray and optical emission is due to the highly relativistic speed with which the plasma expands. Residual collisions may also account for the X-ray emission during the early "steep decline" phase, where the radius is inferred to be larger than the gamma-ray emission radius. Finally, we point out that inverse-Compton emission from residual collisions at large radii is expected to contribute significantly to the emission at high energy, and may therefore "smear" the pair production spectral cut-off.

  19. RESIDUAL TYPE A POSTERIORI ERROR ESTIMATES FOR ELLIPTIC OBSTACLE PROBLEMS

    E-Print Network [OSTI]

    Nochetto, Ricardo H.

    to double obstacle problems are briefly discussed. Key words. a posteriori error estimates, residual Science Foundation under the grant No.19771080 and China National Key Project ``Large Scale Scientific\\Gamma satisfies / Ÿ 0 on @ and K is the convex set of admissible displacements K := fv 2 H 1 0(\\Omega\\Gamma : v

  20. Computer aided analysis for residual stress measurement using ultrasonic techniques

    E-Print Network [OSTI]

    Kypa, Jagan Mohan

    1999-01-01T23:59:59.000Z

    to detect travel-times with a precision of 0. l nanoseconds and an accuracy of less than 2.5 nanoseconds. A residual stress reference standard developed for previous research was used as the sample to measure travel-times. The sample was designed...

  1. COMMUNICATION Are Residues in a Protein Folding Nucleus

    E-Print Network [OSTI]

    Dai, Yang

    COMMUNICATION Are Residues in a Protein Folding Nucleus Evolutionarily Conserved? Yan Yuan Tseng is the hallmark of life. It is important to understand how protein folding and evolution influence each other in protein folding nucleus as measured by experi- mental f-value and selection pressure as measured by v

  2. A PROBABILISTIC FINITE ELEMENT ANALYSIS OF RESIDUAL STRESS FORMATION

    E-Print Network [OSTI]

    Grujicic, Mica

    A PROBABILISTIC FINITE ELEMENT ANALYSIS OF RESIDUAL STRESS FORMATION IN SHRINK-FIT CERAMIC shrink fitting of the jacket over the lining is studied using a probabilistic finite element analysis structural analysis approach, known as the Advanced Mean Value (AMV) method, is used which enables

  3. FIXED PRICE RESIDUAL FUNDS POLICY Policy dated March 29, 1999

    E-Print Network [OSTI]

    Weston, Ken

    FIXED PRICE RESIDUAL FUNDS POLICY Policy dated March 29, 1999 After completion of all deliverables required under a fixed-price award, after costs in fulfilling the requirements of the award have been of the University. The request will be approved if the project is consistent with broader University priorities

  4. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11T23:59:59.000Z

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  5. Residual stresses in weld overlay tubes: A finite element study

    SciTech Connect (OSTI)

    Taljat, B.; Zacharia, T.; Wang, X.L.; Keiser, J.R. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.; Feng, Z. [Edison Welding Inst., Columbus, OH (United States); Jirinec, M.J. [Welding Services, Inc., Norcross, GA (United States)

    1997-01-03T23:59:59.000Z

    Residual stresses and strains in a tube with circumferential weld overlay were analyzed by the finite element (FE) method. The objective of this work was to develop and verify a FE model, to determine the magnitude and distribution of residual stresses in the weld overlay tube, and to evaluate the significance of two contributing factors to residual stress: (1) difference in material properties between tube and weld material, and (2) thermal gradients in the weld. An axisymmetric FE model was developed to simulate the circumferential two-layer welding process of alloy 625 overlay on SA210 tube. The first layer was modeled as a gas metal arc welding process with filler metal, whereas the autogenous gas tungsten arc welding process was modeled for the second layer. Neutron diffraction technique was used to experimentally determine residual elastic strains in the weld overlay tube. Comparison with the FE results shows overall good agreement. Both the experimental and FE results show high compressive stresses at the inside tube surface and high tensile stresses in the weld overlay. This suggests that weld overlay may be used to relieve tensile or produce compressive stresses at the inside tube surface, which is significant for applications where crack initiation is found at the root pass of the joining weld.

  6. Ammonia volatilization from soils with surface rice straw residue

    E-Print Network [OSTI]

    Barghassa, Peyam

    1995-01-01T23:59:59.000Z

    rice residue and related factors on NH3 volatilization from an acid Beaumont clay (pH 5.4) and an alkaline Lake Charles clay (pH 7.4). The treatments in the greenhouse and lab consisted of all possible combinations of the following variables: surface...

  7. Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification

    E-Print Network [OSTI]

    Georgeson, Adam

    2012-02-14T23:59:59.000Z

    . .............................................................................. 7 Table 2. Components Used in Simulation. ...................................................................... 20 Table 3. Composition of Biomass Feedstock to Biorefinery. ......................................... 43 Table 4. Operating... for optimizing gasification plant design from an economic perspective. Specifically, the problem addressed in this work is stated as follows: Given are: ? A set of biomass feedstocks {i|i = 1,2,?,I } which includes fresh as well as residue biomass ? A set...

  8. New Techniques for the Construction of Residue Potentials for Protein

    E-Print Network [OSTI]

    Neumaier, Arnold

    New Techniques for the Construction of Residue Potentials for Protein Folding Arnold Neumaier­lattice protein folding studies. Our potential is a function of the amino acid labels and of the distances between­ rium geometries can determine the true effective potential energy function. Keywords. protein folding

  9. CARBON ENRICHMENT IN RESIDUAL AUSTENITE DURING MARTENSITIC TRANSFORMATION

    E-Print Network [OSTI]

    Cambridge, University of

    179 CARBON ENRICHMENT IN RESIDUAL AUSTENITE DURING MARTENSITIC TRANSFORMATION S. W. Ooi1 , Y. R, retained austenite, autotempering and low carbon steel. Abstract Carbon enrichment of austenite and carbide enrich with carbon [9-11] and there has been recent work to exploit this process in the design of `quench

  10. VLSI implementation of output convertors for ASIC architectures based on the residual number system: an overview

    E-Print Network [OSTI]

    Godbole, Rajesh

    1992-01-01T23:59:59.000Z

    , . For example, 5 bit residues occupy only 32 locations with a word length equal to [log sM] = 18. The key to this output conversion is a quotient-remainder representation for the summands s?such that 0 & s, & M. If a particular modulus m~ is singled out... Systems 5. Mixed Radix Systems 6. Properties of Weighted and Residual Number Systems B. Algebra of Residue Classes 1. Residue Representation 2. Example: Calculation of Integer Values k Residue Digits 3. Identities Involving Residues and Integer...

  11. Residual Stresses in 21-6-9 Stainless Steel Warm Forgings

    SciTech Connect (OSTI)

    Everhart, Wesley A.; Lee, Jordan D.; Broecker, Daniel J.; Bartow, John P.; McQueen, Jamie M.; Switzner, Nathan T.; Neidt, Tod M.; Sisneros, Thomas A.; Brown, Donald W.

    2012-11-14T23:59:59.000Z

    Forging residual stresses are detrimental to the production and performance of derived machined parts due to machining distortions, corrosion drivers and fatigue crack drivers. Residual strains in a 21-6-9 stainless steel warm High Energy Rate Forging (HERF) were measured via neutron diffraction. The finite element analysis (FEA) method was used to predict the residual stresses that occur during forging and water quenching. The experimentally measured residual strains were used to calibrate simulations of the three-dimensional residual stress state of the forging. ABAQUS simulation tools predicted residual strains that tend to match with experimental results when varying yield strength is considered.

  12. Residual stresses in dielectrics caused by metallization lines and pads

    SciTech Connect (OSTI)

    He, M.Y.; Lipkin, J.; Clarke, D.R. [Univ. of California, Santa Barbara, CA (United States). Materials Dept.] [Univ. of California, Santa Barbara, CA (United States). Materials Dept.; Evans, A.G. [Harvard Univ., Cambridge, MA (United States). Div. of Applied Sciences] [Harvard Univ., Cambridge, MA (United States). Div. of Applied Sciences; Tenhover, M. [Carborundum Co., Niagara Falls, NY (United States)] [Carborundum Co., Niagara Falls, NY (United States)

    1996-06-01T23:59:59.000Z

    Residual stresses in dielectrics and semiconductors induced by metal lines, pads and vias can have detrimental effects on the performance of devices and electronic packages. Analytical and numerical calculations of these stresses have been performed for two purposes. (1) To illustrate how these stresses relate to the residual stress in the metallization and its geometry; (2) to calibrate a piezo-spectroscopic method for measuring these stresses with high spatial resolution. The results of the calculations have been presented using non-dimensional parameters that both facilitate scaling and provide connections to the stresses in the metal, with or without yielding. Preliminary experimental results obtained for Au/Ge eutectic pads illustrate the potential of the method and the role of the stress analysis.

  13. Classification of lepton mixing matrices from finite residual symmetries

    E-Print Network [OSTI]

    Renato M. Fonseca; Walter Grimus

    2014-08-19T23:59:59.000Z

    Assuming that neutrinos are Majorana particles, we perform a complete classification of all possible mixing matrices which are fully determined by residual symmetries in the charged-lepton and neutrino mass matrices. The classification is based on the assumption that the residual symmetries originate from a finite flavour symmetry group. The mathematical tools which allow us to accomplish this classification are theorems on sums of roots of unity. We find 17 sporadic cases plus one infinite series of mixing matrices associated with three-flavour mixing, all of which have already been discussed in the literature. Only the infinite series contains mixing matrices which are compatible with the data at the 3 sigma level.

  14. Structural group analysis of residues from Athabasca bitumen

    SciTech Connect (OSTI)

    Gray, M.R.; Choi, J.H.K.; Egiebor, N.O. (Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical Engineering); Kirchen, R.P.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, AB (Canada))

    1989-01-01T23:59:59.000Z

    Although the processability of bitumen from tar sand is dependent on its chemical composition, the details of this relationship are poorly understood. In this study, residue fractions from Athabasca bitumen (topped at different temperatures) and hydrocracker and coker residues were analyzed in detail. Separated class fractions were subjected to elemental analysis, NMR and IR spectroscopy, and potentiometric titration. These data were combined mathematically to obtain a structural profile of each oil. This analysis defines the structural changes in asphaltene precipitates due to distillation and processing, as well as the quantitative changes in the overall structural composition of the oil. Hydrocarbon structures such as paraffinic chains and naphthenes show definite trends with distillation and processing.

  15. Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation

    SciTech Connect (OSTI)

    Garg, D.

    1986-08-19T23:59:59.000Z

    A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

  16. THE METHOD OF CONJUGATE RESIDUALS FOR SOLVING THE GALERKIN EQUATIONS ASSOCIATED WITH SYMMETRIC

    E-Print Network [OSTI]

    Plato, Robert

    kind integral equations, conjugate gradient type methods, Galerkin method, regularization schemesTHE METHOD OF CONJUGATE RESIDUALS FOR SOLVING THE GALERKIN EQUATIONS ASSOCIATED WITH SYMMETRIC, the method of conjugate residuals is consid- ered. An a posteriori stopping rule is introduced

  17. Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford and P. Westerhoff

    E-Print Network [OSTI]

    Hall, Sharon J.

    Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford to global warming. Biofuel from phototrophic microbes like algae and bacteria provides a viable substitute improves biofuel sustainability by refining phosphorus recycling. Biomass Production Residual Biomass

  18. The Dissolution of Desicooler Residues in H-Canyon Dissolvers

    SciTech Connect (OSTI)

    Gray, J.H.

    2003-06-23T23:59:59.000Z

    A series of dissolution and characterization studies has been performed to determine if FB-Line residues stored in desicooler containers will dissolve using a modified H-Canyon processing flowsheet. Samples of desicooler materials were used to evaluate dissolving characteristics in the low-molar nitric acid solutions used in H-Canyon dissolvers. The selection for the H-Canyon dissolution of desicooler residues was based on their high-enriched uranium content and trace levels of plutonium. Test results showed that almost all of the enriched uranium will dissolve from the desicooler materials after extended boiling in one molar nitric acid solutions. The residue that contained uranium after completion of the extended boiling cycle consisted of brown solids that had agglomerated into large pieces and were floating on top of the dissolver solution. Addition of tenth molar fluoride to a three molar nitric acid solution containing boron did not dissolve remaining uranium from the brown solids. Only after boiling in an eight molar nitric acid-tenth molar fluoride solution without boron did remaining uranium and aluminum dissolve from the brown solids. The amount of uranium associated with brown solids would be approximately 1.4 percent of the total uranium content of the desicooler materials. The brown solids that remain in the First Uranium Cycle feed will accumulate at the organic/aqueous interface during solvent extraction operations. Most of the undissolved white residue that remained after extended boiling was aluminum oxide containing additional trace quantities of impurities. However, the presence of mercury used in H-Canyon dissolvers should complete the dissolution of these aluminum compounds.

  19. Type Ia supernova Hubble residuals and host-galaxy properties

    SciTech Connect (OSTI)

    Kim, A. G.; Aldering, G.; Aragon, C.; Bailey, S.; Fakhouri, H. K. [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Antilogus, P.; Bongard, S.; Canto, A.; Cellier-Holzem, F.; Fleury, M.; Guy, J. [Laboratoire de Physique Nucléaire et des Hautes Énergies, Université Pierre et Marie Curie Paris 6, Université Paris Diderot Paris 7, CNRS-IN2P3, 4 place Jussieu, F-75252 Paris Cedex 05 (France); Baltay, C. [Department of Physics, Yale University, New Haven, CT 06250-8121 (United States); Buton, C.; Feindt, U.; Greskovic, P.; Kowalski, M. [Physikalisches Institut, Universität Bonn, Nußallee 12, D-53115 Bonn (Germany); Childress, M. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Chotard, N.; Copin, Y.; Gangler, E. [Université de Lyon, F-69622 Lyon (France); Université de Lyon 1, Villeurbanne (France); CNRS/IN2P3, Institut de Physique Nucléaire de Lyon (France); and others

    2014-03-20T23:59:59.000Z

    Kim et al. introduced a new methodology for determining peak-brightness absolute magnitudes of type Ia supernovae from multi-band light curves. We examine the relation between their parameterization of light curves and Hubble residuals, based on photometry synthesized from the Nearby Supernova Factory spectrophotometric time series, with global host-galaxy properties. The K13 Hubble residual step with host mass is 0.013 ± 0.031 mag for a supernova subsample with data coverage corresponding to the K13 training; at <<1?, the step is not significant and lower than previous measurements. Relaxing the data coverage requirement of the Hubble residual step with the host mass is 0.045 ± 0.026 mag for the larger sample; a calculation using the modes of the distributions, less sensitive to outliers, yields a step of 0.019 mag. The analysis of this article uses K13 inferred luminosities, as distinguished from previous works that use magnitude corrections as a function of SALT2 color and stretch parameters: steps at >2? significance are found in SALT2 Hubble residuals in samples split by the values of their K13 x(1) and x(2) light-curve parameters. x(1) affects the light-curve width and color around peak (similar to the ?m {sub 15} and stretch parameters), and x(2) affects colors, the near-UV light-curve width, and the light-curve decline 20-30 days after peak brightness. The novel light-curve analysis, increased parameter set, and magnitude corrections of K13 may be capturing features of SN Ia diversity arising from progenitor stellar evolution.

  20. Ultrasonic detection of residual stress in a turbine disk 

    E-Print Network [OSTI]

    Pathak, Nitin

    1992-01-01T23:59:59.000Z

    in temperature and stresses during welding. Adapted from [4] . . Cracked steam turbine rotor disk segments. Adapted from [6] . . . . 5 Electrical block diagram of Barkhausen apparatus. Adapted from [11] 10 Snell's Law. 15 Stress field and speeds of plane... International B. Effects in Engineering Design Residual stresses may be introduced into materials in a variety of ways, e. g. , in manu- facturing and repairing processes such as casting, machining, or welding. The casting process has a high probability...

  1. The effect of magnetic flutter on residual flow

    SciTech Connect (OSTI)

    Terry, P. W.; Pueschel, M. J.; Carmody, D. [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)] [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); Nevins, W. M. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)] [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)

    2013-11-15T23:59:59.000Z

    The hypothesis that stochastic magnetic fields disrupt zonal flows associated with ion temperature gradient turbulence saturation is investigated analytically with a residual flow calculation in the presence of magnetic flutter. The calculation starts from the time-asymptotic zero-beta residual flow of Rosenbluth and Hinton [Phys. Rev. Lett. 80, 724 (1998)] with the sudden application of an externally imposed, fixed magnetic field perturbation. The short-time electron response from radial charge loss due to magnetic flutter is calculated from the appropriate gyrokinetic equation. The potential evolution has quadratic behavior, with a zero crossing at finite time. The crossing time and its parametric dependencies are compared with numerical results from a gyrokinetic simulation of residual flow in the presence of magnetic flutter. The numerical and analytical results are in good agreement and support the hypothesis that the high-beta runaway of numerical simulations is a result of the disabling of zonal flows by finite-beta charge losses associated with magnetic flutter.

  2. Residuals in steel products -- Impacts on properties and measures to minimize them

    SciTech Connect (OSTI)

    Emi, Toshihiko [Tohoku Univ., Sendai (Japan). Inst. for Advanced Materials Processing; Wijk, O. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Process Metallurgy

    1996-12-31T23:59:59.000Z

    The effect of major residual elements on the properties of steel products is summarized. Measures to minimize these elements are discussed including the pretreatment of raw materials, innovative refining processes and environmental issues. This paper addresses (1) scrap situation, (2) upper limit of residual concentrations acceptable for processing and product quality, (3) possible means to reduce the residuals, and (4) consideration on the practicable measures to solve the residuals problem in a systematic way. 52 refs.

  3. Single-well experimental design for studying residual trapping of superciritcal carbon dioxide

    E-Print Network [OSTI]

    Zhang, Y.

    2010-01-01T23:59:59.000Z

    Theory and design. J. Can. Petrol. Technol. 30 (3), Tomich,residual oil saturation. J. Petrol. Technol. 25 (2), 211–

  4. Sensitivity study of the residue method for the detection of aerosols from space-borne sensors

    E-Print Network [OSTI]

    Stoffelen, Ad

    Sensitivity study of the residue method for the detection of aerosols from space-borne sensors Martin de Graaf April 2002 #12;Sensitivity study of the residue method for the detection of aerosols from of aerosol parameters on residue 3 2.1 Standard aerosol and atmosphere parameters

  5. A Gaussian-chain model for treating residual chargecharge interactions in the

    E-Print Network [OSTI]

    Weston, Ken

    . According to Coulomb's law, two charged residues fully solvated in water have an interaction energy U0 332 rA Gaussian-chain model for treating residual charge­charge interactions in the unfolded state. Here I present a simple theoretical method for treating residual charge­charge interactions

  6. NOBOB-S: Salinity/Brine Exposure as a Biocide for Application to NOBOB Residuals

    E-Print Network [OSTI]

    , eggs and spores of many taxa within the sediments and residual water of their ballast tanks (Niimi a voluntary "best management practices" approach for residual ballast water and sediment for NOBOB vesselsNOBOB-S: Salinity/Brine Exposure as a Biocide for Application to NOBOB Residuals Primary

  7. Residues, Duality, and the Fundamental Class of a scheme-map

    E-Print Network [OSTI]

    2011-05-15T23:59:59.000Z

    Mar 26, 2011 ... Page 1 ... So don't bother taking notes. Joseph Lipman (Purdue ... 4 Residues, integrals and duality: the Residue Theorem. 5 Closing ..... Now here is the main result, expressing via residues and integrals a canonical ... In what went before, ? was the sheaf of regular differentials, and c f was just the ...

  8. Microstructure, residual stress, and fracture of sputtered TiN films Liqiang Zhang a

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Microstructure, residual stress, and fracture of sputtered TiN films Liqiang Zhang a , Huisheng Keywords: TiN films Residual stress Hardness Fracture toughness Morphology, structure, residual stress, hardness, and fracture toughness of magnetron sputtered titanium nitride (TiN) thin films, deposited at 300

  9. Prediction of Protein Interaction Sites From Sequence Profile and Residue Neighbor List

    E-Print Network [OSTI]

    Weston, Ken

    Prediction of Protein Interaction Sites From Sequence Profile and Residue Neighbor List Huan Protein­protein interaction sites are predicted from a neural network with sequence profiles correctly predicted residues account for 65% of the 11,805 residues making up the 129 interfaces. The main

  10. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Plant - without coking (lb/hr) Feed Coal* Hydrogen YieldsCoking Summary Cost Estimates for Solvent Refining of Five U.S. CoalsCoal Handling and Preparation Preheaters and Dissolvers Mineral Separation (Filters) Solvent Recovery Gas Recovery Mineral Residue Processing and Storage Coking

  11. Lowest Pressure Steam Saves More BTU's Than You Think

    E-Print Network [OSTI]

    Vallery, S. J.

    Steam is the most common and economical way of transferring heat from one location to another. But most steam systems use the header pressure steam to do the job. The savings are substantially more than just the latent heat differences between...

  12. POTENTIAL MARKETS FOR HIGH-BTU GAS FROM COAL

    SciTech Connect (OSTI)

    Booz, Allen, and Hamilton, Inc.,

    1980-04-01T23:59:59.000Z

    It has become increasilngly clear that the energy-related ilemna facing this nation is both a long-term and deepening problem. A widespread recognition of the critical nature of our energy balance, or imbalance, evolved from the Arab Oil Embargo of 1973. The seeds of this crisis were sown in the prior decade, however, as our consumption of known energy reserves outpaced our developing of new reserves. The resultant increasing dependence on foreign energy supplies hs triggered serious fuel shortages, dramatic price increases, and a pervsive sense of unertainty and confusion throughout the country.

  13. Natural Gas Futures Contract 1 (Dollars per Million Btu)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparency VisitSilver Toyota1Resourceloading new table Home

  14. Natural Gas Futures Contract 1 (Dollars per Million Btu)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparency VisitSilver Toyota1Resourceloading new table HomeYear Jan

  15. Natural Gas Futures Contract 1 (Dollars per Million Btu)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparency VisitSilver Toyota1Resourceloading new table HomeYear

  16. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688ElectricityLess than 200Decade Year-0YearThousand

  17. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688ElectricityLess than 200Decade Year-0YearThousandYear Jan

  18. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14 Dec-14 Jan-15LiquidBG 0 20Year Jan Feb Mar68 4.50

  19. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14 Dec-14 Jan-15LiquidBG 0 20Year Jan Feb Mar68 4.50Week

  20. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14 Dec-14 Jan-15LiquidBG 0 20Year Jan Feb Mar68

  1. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office of(Millionthrough 1996) inthrough 1996)Nov-14Year Jan

  2. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office of(Millionthrough 1996) inthrough 1996)Nov-14YearYear

  3. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office of(Millionthrough 1996) inthroughYear Jan Feb Mar Apr

  4. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYearperHOW

  5. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYearperHOWYear-Month Week 1 Week 2 Week 3

  6. Natural Gas Futures Contract 1 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:Deployment Activities Printable80 mPilotDataGlossary AWeek Of

  7. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYear Janthrough 1996)through2009 2010 2011 2012

  8. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYear Janthrough 1996)through2009 2010 2011

  9. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYear Janthrough 1996)through2009 2010 2011Decade

  10. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYear Janthrough 1996)through2009 2010

  11. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYear Janthrough 1996)through2009 2010Decade Year-0

  12. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYear Janthrough 1996)through2009 2010Decade

  13. Henry Hub Natural Gas Spot Price (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventionalMississippi"site. If youEIA-906 &Stocks

  14. Natural Gas Futures Contract 2 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventionalMississippi"site. IfProved Reservesthrough 1996)

  15. Natural Gas Futures Contract 3 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventionalMississippi"site. IfProved Reservesthrough 1996)Year-Month Week 1 Week 2 WeekYear

  16. Natural Gas Futures Contract 4 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventionalMississippi"site. IfProved Reservesthrough 1996)Year-Month Week 1 Week 2DecadeYear

  17. Submillimeter residual losses in high-{Tc} superconductors

    SciTech Connect (OSTI)

    Miller, D.

    1993-09-01T23:59:59.000Z

    Bolometry was used obtain accurate submillimeter residual loss data for epitaxial films of YBa{sub 2}Cu{sub 3}O{sub 7} (YBCO), Tl{sub 2}Ca{sub 2}Ba{sub 2}Cu{sub 3}O{sub 10}, Tl{sub 2}CaBa{sub 2}Cu{sub 2}O{sub 8} (TCBCO), and Ba{sub 0.6}K{sub 0.4}BiO{sub 3} (BKBO). We were able to fit the absorptivity measured for Nb films to an Eliashberg strong coupling calculation; excellent agreement resulted between parameters from best fits and measured Residual Resistivity Ratio. Microwave surface resistance measurements made on the same YBCO and TCBCO films are in excellent agreement with submillimeter measurements. Absorptivities for all YBCO films studied are qualitatively similar, increasing smoothly with frequency, with no gap-like features below the well known absorption edge at 450 cm{sup {minus}1}. Losses in YBCO films were fit to a weakly coupled grain model for the a-b plane conductivity. Strong phonon structure was observed in TCBCO films between 60 and 700 cm{sup {minus}1} (2 THz and 23 THz); these losses could not be fitted to the simple weakly coupled grain model, in contrast to the case for other high-{Tc} superconductors where phonon structure observed in ceramics are is absent in epitaxial oriented films and crystals because of electronic screening due to high conductivity of a-b planes. Absorptivity data for the BKBO films all show a strong absorption onset near the BCS tunneling gap of 3.5 k{sub B}{Tc}. Comparison with strong coupling Eliashberg predictions and of a Kramers-Kronig analysis indicate that the absorption onset is consistent with a superconducting energy gap. Effects of magnetic field on residual losses in YBCO films show a resonant absorption feature in vicinity of predicted

  18. Enhanced residual entropy in high-density nanoconfined bilayer ice

    E-Print Network [OSTI]

    Fabiano Corsetti; Jon Zubeltzu; Emilio Artacho

    2015-06-15T23:59:59.000Z

    A novel kind of crystal order in high-density nanoconfined bilayer ice is proposed from molecular dynamics and density-functional theory simulations. A first-order transition is observed between a low-temperature proton-ordered solid and a high-temperature proton-disordered solid. The latter is shown to possess crystalline order for the oxygen positions, arranged on a close-packed triangular lattice with AA stacking. Uniquely amongst the ice phases, the triangular bilayer is characterized by two levels of disorder (for the bonding network and for the protons) which results in a residual entropy twice that of bulk ice.

  19. Dual-axis hole-drilling ESPI residual stress measurements

    SciTech Connect (OSTI)

    Steinzig, Michael [Los Alamos National Laboratory; Schajer, Gary [UNIV OF BRITISH COLUMBIA

    2008-01-01T23:59:59.000Z

    A novel dual-axis ESPI hole-drilling residual stress measurement method is presented. The method enables the evaluation of all the in-plane normal stress components with similar response to measurement errors, significantly lower than with single-axis measurements. A numerical method is described that takes advantage of, and compactly handles, the additional optical data that are available from the second measurement axis. Experimental tests were conducted on a calibrated specimen to demonstrate the proposed method, and the results supported theoretical expectations.

  20. Alternative cooling resource for removing the residual heat of reactor

    SciTech Connect (OSTI)

    Park, H. C.; Lee, J. H.; Lee, D. S.; Jung, C. Y.; Choi, K. Y. [Korea Hydro and Nuclear Power Co., Ltd., 260 Naa-ri Yangnam-myeon Gyeongju-si, Gyeonasangbuk-do, 780-815 (Korea, Republic of)

    2012-07-01T23:59:59.000Z

    The Recirculated Cooling Water (RCW) system of a Candu reactor is a closed cooling system which delivers demineralized water to coolers and components in the Service Building, the Reactor Building, and the Turbine Building and the recirculated cooling water is designed to be cooled by the Raw Service Water (RSW). During the period of scheduled outage, the RCW system provides cooling water to the heat exchangers of the Shutdown Cooling System (SDCS) in order to remove the residual heat of the reactor, so the RCW heat exchangers have to operate at all times. This makes it very hard to replace the inlet and outlet valves of the RCW heat exchangers because the replacement work requires the isolation of the RCW. A task force was formed to prepare a plan to substitute the recirculated water with the chilled water system in order to cool the SDCS heat exchangers. A verification test conducted in 2007 proved that alternative cooling was possible for the removal of the residual heat of the reactor and in 2008 the replacement of inlet and outlet valves of the RCW heat exchangers for both Wolsong unit 3 and 4 were successfully completed. (authors)

  1. Quarry residuals RI/FS scoping document. [Weldon Spring quarry

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    The purpose of this document is to serve as a planning tool for the implementation of the Quarry Residual Remedial Investigation/Feasibility Study (RI/FS) process and to provide direct input to revising and updating the 1988 Work Plan for the Weldon Spring Site Remedial Action Project (WSSRAP) Remedial Investigation/Feasibility Study-Environmental Impact Statement for the Weldon Spring Site (RI/FS-EIS) (Peterson et al. 1988) for this effort. The scoping process is intended to outline the tasks necessary to develop and implement activities in compliance with the Comprehensive Environmental Response, Compensation and Liability Act-National Environmental Policy Act (CERCLA-NEPA) process from detailed planning through the appropriate decision document. In addition to scoping the entire process, this document will serve as the primary tool for planning and accomplishing all activities to be developed in the Quarry Residual RI/FS Work Plan. Subsequent tasks are difficult to plan at this time. 10 refs., 5 figs., 5 tabs.

  2. Estimating Residual Solids Volume In Underground Storage Tanks

    SciTech Connect (OSTI)

    Clark, Jason L.; Worthy, S. Jason; Martin, Bruce A.; Tihey, John R.

    2014-01-08T23:59:59.000Z

    The Savannah River Site liquid waste system consists of multiple facilities to safely receive and store legacy radioactive waste, treat, and permanently dispose waste. The large underground storage tanks and associated equipment, known as the 'tank farms', include a complex interconnected transfer system which includes underground transfer pipelines and ancillary equipment to direct the flow of waste. The waste in the tanks is present in three forms: supernatant, sludge, and salt. The supernatant is a multi-component aqueous mixture, while sludge is a gel-like substance which consists of insoluble solids and entrapped supernatant. The waste from these tanks is retrieved and treated as sludge or salt. The high level (radioactive) fraction of the waste is vitrified into a glass waste form, while the low-level waste is immobilized in a cementitious grout waste form called saltstone. Once the waste is retrieved and processed, the tanks are closed via removing the bulk of the waste, chemical cleaning, heel removal, stabilizing remaining residuals with tailored grout formulations and severing/sealing external penetrations. The comprehensive liquid waste disposition system, currently managed by Savannah River Remediation, consists of 1) safe storage and retrieval of the waste as it is prepared for permanent disposition; (2) definition of the waste processing techniques utilized to separate the high-level waste fraction/low-level waste fraction; (3) disposition of LLW in saltstone; (4) disposition of the HLW in glass; and (5) closure state of the facilities, including tanks. This paper focuses on determining the effectiveness of waste removal campaigns through monitoring the volume of residual solids in the waste tanks. Volume estimates of the residual solids are performed by creating a map of the residual solids on the waste tank bottom using video and still digital images. The map is then used to calculate the volume of solids remaining in the waste tank. The ability to accurately determine a volume is a function of the quantity and quality of the waste tank images. Currently, mapping is performed remotely with closed circuit video cameras and still photograph cameras due to the hazardous environment. There are two methods that can be used to create a solids volume map. These methods are: liquid transfer mapping / post transfer mapping and final residual solids mapping. The task is performed during a transfer because the liquid level (which is a known value determined by a level measurement device) is used as a landmark to indicate solids accumulation heights. The post transfer method is primarily utilized after the majority of waste has been removed. This method relies on video and still digital images of the waste tank after the liquid transfer is complete to obtain the relative height of solids across a waste tank in relation to known and usable landmarks within the waste tank (cooling coils, column base plates, etc.). In order to accurately monitor solids over time across various cleaning campaigns, and provide a technical basis to support final waste tank closure, a consistent methodology for volume determination has been developed and implemented at SRS.

  3. A Multi-Factor Analysis of Sustainable Agricultural Residue Removal Potential

    SciTech Connect (OSTI)

    Jared Abodeely; David Muth; Paul Adler; Eleanor Campbell; Kenneth Mark Bryden

    2012-10-01T23:59:59.000Z

    Agricultural residues have significant potential as a near term source of cellulosic biomass for bioenergy production, but sustainable removal of agricultural residues requires consideration of the critical roles that residues play in the agronomic system. Previous work has developed an integrated model to evaluate sustainable agricultural residue removal potential considering soil erosion, soil organic carbon, greenhouse gas emission, and long-term yield impacts of residue removal practices. The integrated model couples the environmental process models WEPS, RUSLE2, SCI, and DAYCENT. This study uses the integrated model to investigate the impact of interval removal practices in Boone County, Iowa, US. Residue removal of 4.5 Mg/ha was performed annually, bi-annually, and tri-annually and were compared to no residue removal. The study is performed at the soil type scale using a national soil survey database assuming a continuous corn rotation with reduced tillage. Results are aggregated across soil types to provide county level estimates of soil organic carbon changes and individual soil type soil organic matter content if interval residue removal were implemented. Results show interval residue removal is possible while improving soil organic matter. Implementation of interval removal practices provide greater increases in soil organic matter while still providing substantial residue for bioenergy production.

  4. Caspase-3 binds diverse P4 residues in peptides as revealed by crystallography and structural modeling.

    SciTech Connect (OSTI)

    Fang, Bin; Fu, Guoxing; Agniswamy, Johnson; Harrison, Robert W.; Weber, Irene T.; (GSU)

    2009-03-31T23:59:59.000Z

    Caspase-3 recognition of various P4 residues in its numerous protein substrates was investigated by crystallography, kinetics, and calculations on model complexes. Asp is the most frequent P4 residue in peptide substrates, although a wide variety of P4 residues are found in the cellular proteins cleaved by caspase-3. The binding of peptidic inhibitors with hydrophobic P4 residues, or no P4 residue, is illustrated by crystal structures of caspase-3 complexes with Ac-IEPD-Cho, Ac-WEHD-Cho, Ac-YVAD-Cho, and Boc-D(OMe)-Fmk at resolutions of 1.9-2.6 {angstrom}. The P4 residues formed favorable hydrophobic interactions in two separate hydrophobic regions of the binding site. The side chains of P4 Ile and Tyr form hydrophobic interactions with caspase-3 residues Trp206 and Trp214 within a non-polar pocket of the S4 subsite, while P4 Trp interacts with Phe250 and Phe252 that can also form the S5 subsite. These interactions of hydrophobic P4 residues are distinct from those for polar P4 Asp, which indicates the adaptability of caspase-3 for binding diverse P4 residues. The predicted trends in peptide binding from molecular models had high correlation with experimental values for peptide inhibitors. Analysis of structural models for the binding of 20 different amino acids at P4 in the aldehyde peptide Ac-XEVD-Cho suggested that the majority of hydrophilic P4 residues interact with Phe250, while hydrophobic residues interact with Trp206, Phe250, and Trp214. Overall, the S4 pocket of caspase-3 exhibits flexible adaptation for different residues and the new structures and models, especially for hydrophobic P4 residues, will be helpful for the design of caspase-3 based drugs.

  5. Finite element residual stress analysis of induction heating bended ferritic steel piping

    SciTech Connect (OSTI)

    Kima, Jong Sung [Sunchon National University, 255 Jungang-ro, Sucheon, Jeonnam (Korea, Republic of); Kim, Kyoung-Soo; Oh, Young-Jin; Chang, Hyung-Young; Park, Heung-Bae [KEPCO E and C, Co., Ltd., 188, Kumi-ro, Seongnam, Kyounggi (Korea, Republic of)

    2014-10-06T23:59:59.000Z

    Recently, there is a trend to apply the piping bended by induction heating process to nuclear power plants. Residual stress can be generated due to thermo-mechanical mechanism during the induction heating bending process. It is well-known that the residual stress has important effect on crack initiation and growth. The previous studies have focused on the thickness variation. In part, some studies were performed for residual stress evaluation of the austenitic stainless steel piping bended by induction heating. It is difficult to find the residual stresses of the ferritic steel piping bended by the induction heating. The study assessed the residual stresses of induction heating bended ferriticsteel piping via finite element analysis. As a result, it was identified that high residual stresses are generated on local outersurface region of the induction heating bended ferritic piping.

  6. Quantification of residual stress from photonic signatures of fused silica

    SciTech Connect (OSTI)

    Cramer, K. Elliott; Yost, William T. [NASA Langley Research Center, Hampton, VA 23681 (United States); Hayward, Maurice [College of William and Mary, Williamsburg, VA 23185 (United States)

    2014-02-18T23:59:59.000Z

    A commercially available grey-field polariscope (GFP) instrument for photoelastic examination is used to assess impact damage inflicted upon the outer-most pane of Space Shuttle windows made from fused silica. A method and apparatus for calibration of the stress-optic coefficient using four-point bending is discussed. The results are validated on known material (acrylic) and are found to agree with literature values to within 6%. The calibration procedure is then applied to fused-silica specimens and the stress-optic coefficient is determined to be 2.43 ± 0.54 × 10{sup ?12} Pa{sup ?1}. Fused silica specimens containing impacts artificially made at NASA’s Hypervelocity Impact Technology Facility (HIT-F), to simulate damage typical during space flight, are examined. The damage sites are cored from fused silica window carcasses and examined with the GFP. The calibrated GFP measurements of residual stress patterns surrounding the damage sites are presented.

  7. Residual energy in magnetohydrodynamic turbulence and in the solar wind

    E-Print Network [OSTI]

    Stanislav Boldyrev; Jean Carlos Perez; Vladimir Zhdankin

    2011-08-30T23:59:59.000Z

    Recent observations indicate that kinetic and magnetic energies are not in equipartition in the solar wind turbulence. Rather, magnetic fluctuations are more energetic and have somewhat steeper energy spectrum compared to the velocity fluctuations. This leads to the presence of the so-called residual energy E_r=E_v-E_b in the inertial interval of turbulence. This puzzling effect is addressed in the present paper in the framework of weak turbulence theory. Using a simple model of weakly colliding Alfv\\'en waves, we demonstrate that the kinetic-magnetic equipartition indeed gets broken as a result of nonlinear interaction of Alfv\\'en waves. We establish that magnetic energy is indeed generated more efficiently as a result of these interactions, which proposes an explanation for the solar wind observations.

  8. Erk phosphorylates threonine 42 residue of ribosomal protein S3

    SciTech Connect (OSTI)

    Kim, Hag Dong [Laboratory of Biochemistry, School of Life Sciences and Biotechnology, and BioInstitute, Korea University, Seoul 136-701 (Korea, Republic of); Lee, Jae Yung [Department of Biology, Mokpo National University, Chonnam 534-729 (Korea, Republic of); Kim, Joon [Laboratory of Biochemistry, School of Life Sciences and Biotechnology, and BioInstitute, Korea University, Seoul 136-701 (Korea, Republic of)]. E-mail: joonkim@korea.ac.kr

    2005-07-22T23:59:59.000Z

    The ribosomal protein S3 (rpS3) is involved in ribosome biogenesis as a member of ribosomal small subunit and also plays a role in the repair of damaged DNA. Extracellular signal-regulated kinase (Erk), a MAP kinase, is known to play important roles in the regulation of cell growth, differentiation, and apoptosis. In this study, the sequence analysis of rpS3 protein revealed that this protein has a putative FXFP motif which is believed to be an Erk binding site. Indeed, the motif was demonstrated as an Erk binding site by co-immunoprecipitation. In addition to this, it was revealed that Erk specifically phosphorylated Thr 42 residue of rpS3 in vitro and in vivo using the various mutants of rpS3. Taken together, rpS3 appears to be phosphorylated by activated Erk in proliferating cells, resulting in the decreased interaction between two proteins.

  9. Description of the prototype diagnostic residual gas analyzer for ITER

    SciTech Connect (OSTI)

    Younkin, T. R., E-mail: tyounkin@gatech.edu [Fusion and Materials for Nuclear Systems Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6169 (United States); Georgia Institute of Technology, Woodruff School of Mechanical Engineering – Nuclear and Radiological Engineering Program, Atlanta, Georgia 30332 (United States); Biewer, T. M.; Klepper, C. C.; Marcus, C. [Fusion and Materials for Nuclear Systems Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6169 (United States)

    2014-11-15T23:59:59.000Z

    The diagnostic residual gas analyzer (DRGA) system to be used during ITER tokamak operation is being designed at Oak Ridge National Laboratory to measure fuel ratios (deuterium and tritium), fusion ash (helium), and impurities in the plasma. The eventual purpose of this instrument is for machine protection, basic control, and physics on ITER. Prototyping is ongoing to optimize the hardware setup and measurement capabilities. The DRGA prototype is comprised of a vacuum system and measurement technologies that will overlap to meet ITER measurement requirements. Three technologies included in this diagnostic are a quadrupole mass spectrometer, an ion trap mass spectrometer, and an optical penning gauge that are designed to document relative and absolute gas concentrations.

  10. Evaluation of the residue from microset on various metal surfaces.

    SciTech Connect (OSTI)

    Brumbach, Michael Todd

    2011-04-01T23:59:59.000Z

    Fast-curing impression materials are sometimes used to cast negative-mold replications of physical defects on material surfaces. The negative-mold impressions can then be used for further measurements to record the nature of the defect. These impression materials have been designed to cure quickly, and with very low adhesion, so that they can be easily removed from the surface leaving little residual contamination. Unfortunately, some contaminant is retained by the substrate material. This investigation seeks to identify the composition and quantity of the remaining material upon removal of Microset Synthetic Rubber Replicating Compound from several material surfaces. Coe-Flex was used as a relative comparison to Microset. On fifteen different substrate materials the Microset leaves no visible trace of contaminant, however, X-ray photoelectron spectroscopy shows evidence of a thin silicone-based contaminant film of approximately 2 nm thickness.

  11. Cost Methodology for Biomass Feedstocks: Herbaceous Crops and Agricultural Residues

    SciTech Connect (OSTI)

    Turhollow Jr, Anthony F [ORNL; Webb, Erin [ORNL; Sokhansanj, Shahabaddine [ORNL

    2009-12-01T23:59:59.000Z

    This report describes a set of procedures and assumptions used to estimate production and logistics costs of bioenergy feedstocks from herbaceous crops and agricultural residues. The engineering-economic analysis discussed here is based on methodologies developed by the American Society of Agricultural and Biological Engineers (ASABE) and the American Agricultural Economics Association (AAEA). An engineering-economic analysis approach was chosen due to lack of historical cost data for bioenergy feedstocks. Instead, costs are calculated using assumptions for equipment performance, input prices, and yield data derived from equipment manufacturers, research literature, and/or standards. Cost estimates account for fixed and variable costs. Several examples of this costing methodology used to estimate feedstock logistics costs are included at the end of this report.

  12. Estimators and characteristics of logging residue in California. Forest Service research paper

    SciTech Connect (OSTI)

    Howard, J.O.; Bulgrin, J.K.

    1986-03-01T23:59:59.000Z

    Ratios are presented for estimating volume and characteristics of logging residue. The ratios relate cubic-foot volume of residue to thousand board feet of timber harvested and to acres harvested. Tables show gross and net volume of residue with and without bark, by diameter and length classes, by number of pieces per acre, by softwoods and hardwoods, by percent soundness, and by degree of slope and distance to roads.

  13. E-Print Network 3.0 - acid residues required Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering, Columbia University Collection: Engineering ; Biology and Medicine 13 Protein folding with stochastic L-systems Gemma Danks1 Summary: 70 amino acid residues to 1000s...

  14. alters less-conserved residues: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this...

  15. Neutron scattering residual stress measurements on gray cast iron brake discs

    SciTech Connect (OSTI)

    Spooner, S.; Payzant, E.A.; Hubbard, C.R. [and others

    1996-11-01T23:59:59.000Z

    Neutron diffraction was used to investigate the effects of a heat treatment designed to remove internal residual stresses in brake discs. It is believed that residual stresses may change the rate of deformation of the discs during severe braking conditions when the disc temperature is increased significantly. Neutron diffraction was used to map out residual strain distributions in a production disc before and after a stress-relieving heat treatment. Results from these neutron diffraction experiments show that some residual strains were reduced by as much as 400 microstrain by stress relieving. 5 refs., 5 figs., 1 tab.

  16. Effect of the Basic Residue on the Energetics, Dynamics and Mechanisms...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    surface-induced dissociation (SID) of singly protonated peptides with the N-terminal arginine residue and their analogs, in which arginine is replaced with less basic...

  17. Table 42. Residual Fuel Oil Prices by PAD District and State

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1999 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  18. Table 42. Residual Fuel Oil Prices by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 1998 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  19. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) - Continued...

  20. Table 42. Residual Fuel Oil Prices by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration Petroleum Marketing Annual 1995 245 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  1. The effects of drainage and amendments on the physical and chemical properties of bauxite residue 

    E-Print Network [OSTI]

    Thompson, Thomas Lee

    1987-01-01T23:59:59.000Z

    on the properties of the residue were studied. The objective was to improve the properties of the residue before adding it to sandy soils. The CEC increased with pH, as would be expected with variable-charge minerals, and the adsorption of phosphate decreased...), or into the ocean (Baseden, 1976). Baseden (1976) reported that seawater could be mixed with the residue, reducing the pH of the residue by precipitating Ca and Ng carbonates. The resulting supernatant solution was then pumped into the ocean. This method...

  2. Gas Generation Test Support for Transportation and Storage of Plutonium Residue Materials - Part 1: Rocky Flats Sand, Slag, and Crucible Residues

    SciTech Connect (OSTI)

    Livingston, R.R.

    1999-08-24T23:59:59.000Z

    The purpose of this report is to present experimental results that can be used to establish one segment of the safety basis for transportation and storage of plutonium residue materials.

  3. POST-OPERATIONAL TREATMENT OF RESIDUAL NA COOLLANT IN EBR-2 USING CARBONATION

    SciTech Connect (OSTI)

    Sherman, S.; Knight, C.

    2011-03-08T23:59:59.000Z

    At the end of 2002, the Experimental Breeder Reactor Two (EBR-II) facility became a U.S. Resource Conservation and Recovery Act (RCRA) permitted site, and the RCRA permit1 compelled further treatment of the residual sodium in order to convert it into a less reactive chemical form and remove the by-products from the facility, so that a state of RCRA 'closure' for the facility may be achieved (42 U.S.C. 6901-6992k, 2002). In response to this regulatory driver, and in recognition of project budgetary and safety constraints, it was decided to treat the residual sodium in the EBR-II primary and secondary sodium systems using a process known as 'carbonation.' In early EBR-II post-operation documentation, this process is also called 'passivation.' In the carbonation process (Sherman and Henslee, 2005), the system containing residual sodium is flushed with humidified carbon dioxide (CO{sub 2}). The water vapor in the flush gas reacts with residual sodium to form sodium hydroxide (NaOH), and the CO{sub 2} in the flush gas reacts with the newly formed NaOH to make sodium bicarbonate (NaHCO{sub 3}). Hydrogen gas (H{sub 2}) is produced as a by-product. The chemical reactions occur at the exposed surface of the residual sodium. The NaHCO{sub 3} layer that forms is porous, and humidified carbon dioxide can penetrate the NaHCO{sub 3} layer to continue reacting residual sodium underneath. The rate of reaction is controlled by the thickness of the NaHCO{sub 3} surface layer, the moisture input rate, and the residual sodium exposed surface area. At the end of carbonation, approximately 780 liters of residual sodium in the EBR-II primary tank ({approx}70% of original inventory), and just under 190 liters of residual sodium in the EBR-II secondary sodium system ({approx}50% of original inventory), were converted into NaHCO{sub 3}. No bare surfaces of residual sodium remained after treatment, and all remaining residual sodium deposits are covered by a layer of NaHCO{sub 3}. From a safety standpoint, the inventory of residual sodium in these systems was greatly reduced by using the carbonation process. From a regulatory standpoint, the process was not able to achieve deactivation of all residual sodium, and other more aggressive measures will be needed if the remaining residual sodium must also be deactivated to meet the requirements of the existing environmental permit. This chapter provides a project history and technical summary of the carbonation of EBR-II residual sodium. Options for future treatment are also discussed.

  4. An Integrated Model for Assessment of Sustainable Agricultural Residue Removal Limits for Bioenergy Systems

    SciTech Connect (OSTI)

    D. Muth; K. M. Bryden

    2003-12-01T23:59:59.000Z

    Agricultural residues have been identified as a significant potential resource for bioenergy production, but serious questions remain about the sustainability of harvesting residues. Agricultural residues play an important role in limiting soil erosion from wind and water and in maintaining soil organic carbon. Because of this, multiple factors must be considered when assessing sustainable residue harvest limits. Validated and accepted modeling tools for assessing these impacts include the Revised Universal Soil Loss Equation Version 2 (RUSLE2), the Wind Erosion Prediction System (WEPS), and the Soil Conditioning Index. Currently, these models do not work together as a single integrated model. Rather, use of these models requires manual interaction and data transfer. As a result, it is currently not feasible to use these computational tools to perform detailed sustainable agricultural residue availability assessments across large spatial domains or to consider a broad range of land management practices. This paper presents an integrated modeling strategy that couples existing datasets with the RUSLE2 water erosion, WEPS wind erosion, and Soil Conditioning Index soil carbon modeling tools to create a single integrated residue removal modeling system. This enables the exploration of the detailed sustainable residue harvest scenarios needed to establish sustainable residue availability. Using this computational tool, an assessment study of residue availability for the state of Iowa was performed. This study included all soil types in the state of Iowa, four representative crop rotation schemes, variable crop yields, three tillage management methods, and five residue removal methods. The key conclusions of this study are that under current management practices and crop yields nearly 26.5 million Mg of agricultural residue are sustainably accessible in the state of Iowa, and that through the adoption of no till practices residue removal could sustainably approach 40 million Mg. However, when considering the economics and logistics of residue harvest, yields below 2.25 Mg ha-1 are generally considered to not be viable for a commercial bioenergy system. Applying this constraint, the total agricultural residue resource available in Iowa under current management practices is 19 million Mg. Previously published results have shown residue availability from 22 million Mg to over 50 million Mg in Iowa.

  5. The influence of quench sensitivity on residual stresses in the aluminium alloys 7010 and 7075

    SciTech Connect (OSTI)

    Robinson, J.S., E-mail: jeremy.robinson@ul.ie [Materials and Surface Science Institute, University of Limerick (Ireland); Tanner, D.A. [Materials and Surface Science Institute, University of Limerick (Ireland); Truman, C.E. [Department of Mechanical Engineering, University of Bristol (United Kingdom); Paradowska, A.M. [ISIS Facility, Rutherford Appleton Laboratory, Didcot (United Kingdom); Wimpory, R.C. [Helmholtz Centre Berlin for Materials and Energy, Hahn Meitner Platz 1, Berlin (Germany)

    2012-03-15T23:59:59.000Z

    The most critical stage in the heat treatment of high strength aluminium alloys is the rapid cooling necessary to form a supersaturated solid solution. A disadvantage of quenching is that the thermal gradients can be sufficient to cause inhomogeneous plastic deformation which in turn leads to the development of large residual stresses. Two 215 mm thick rectilinear forgings have been made from 7000 series alloys with widely different quench sensitivity to determine if solute loss in the form of precipitation during quenching can significantly affect residual stress magnitudes. The forgings were heat treated and immersion quenched using cold water to produce large magnitude residual stresses. The through thickness residual stresses were measured by neutron diffraction and incremental deep hole drilling. The distribution of residual stresses was found to be similar for both alloys varying from highly triaxial and tensile in the interior, to a state of biaxial compression in the surface. The 7010 forging exhibited larger tensile stresses in the interior. The microstructural variation from surface to centre for both forgings was determined using optical and transmission electron microscopy. These observations were used to confirm the origin of the hardness variation measured through the forging thickness. When the microstructural changes were accounted for in the through thickness lattice parameter, the residual stresses in the two forgings were found to be very similar. Solute loss in the 7075 forging appeared to have no significant effect on the residual stress magnitudes when compared to 7010. - Highlights: Black-Right-Pointing-Pointer Through thickness residual stress measurements made on large Al alloy forgings. Black-Right-Pointing-Pointer Residual stress characterised using neutron diffraction and deep hole drilling. Black-Right-Pointing-Pointer Biaxial compressive surface and triaxial subsurface residual stresses. Black-Right-Pointing-Pointer Quench sensitivity of 7075 promotes significant microstructural differences to 7010. Black-Right-Pointing-Pointer When precipitation is accounted for, residual stress in both forgings are similar.

  6. Hydrodesulfurization and hydrodemetallization of different origin vacuum residues: New modeling approach

    E-Print Network [OSTI]

    Boyer, Edmond

    impurities, such as sulfur or metals. Residue hydrotreatment in fixed beds, under high hydrogen pressure can processes, fixed bed hydrotreatment units are the most frequently used. The residue fixed bed hydrotreatment process, Hyvahl TM developed by IFPEN in 1982 [2], consists of several trickle bed reactors in series

  7. Management of high sulfur coal combustion residues, issues and practices: Proceedings

    SciTech Connect (OSTI)

    Chugh, Y.P.; Beasley, G.A. [eds.

    1994-10-01T23:59:59.000Z

    Papers presented at the following sessions are included in this proceedings: (1) overview topic; (2) characterization of coal combustion residues; (3) environmental impacts of residues management; (4) materials handling and utilization, Part I; and (5) materials handling and utilization, Part II. Selected paper have been processed separately for inclusion in the Energy Science and Technology Database.

  8. Ma,BonzongoandGao/UniversityofFlorida Characterization and Leachability of Coal Combustion Residues

    E-Print Network [OSTI]

    Ma, Lena

    Ma,BonzongoandGao/UniversityofFlorida Characterization and Leachability of Coal Combustion Residues an important solid waste in Florida, i.e., coal combustion residues (CCR) detailed in #2-4 of the current simulating ash slurry stored in ash ponds. Our research should greatly benefit FDEP, the public and utility

  9. Justification of RHIC EBIS vacuum system. 1. Requirements to the pressure of residual gas inside the

    E-Print Network [OSTI]

    volume, the influx and accumulation of residual gas ions reduces the number of working ions in a trap for internal elements, technology of processing and equipment should be adequate. The components of the gasJustification of RHIC EBIS vacuum system. A. Pikin 1. Requirements to the pressure of residual gas

  10. A NEW ON-LINE DETECTING APPARATUS OF THE RESIDUAL CHLORINE IN DISINFECTANT

    E-Print Network [OSTI]

    A NEW ON-LINE DETECTING APPARATUS OF THE RESIDUAL CHLORINE IN DISINFECTANT FOR FRESH-CUT VEGETABLES of residual chlorine is 0~300ppm. Key words: e-government, knowledge management, frameworks, e-governance 1 is chlorine molecule, hypochlorous acid or calcium hypochlorite. Chloric disinfectant hydrolysis in water

  11. Application of conservative residual distribution schemes to the solution of the shallow water equations on

    E-Print Network [OSTI]

    Abgrall, RĂ©mi

    Application of conservative residual distribution schemes to the solution of the shallow water. Keywords: Conservative schemes; Residual distribution; Shallow water equations; Lake at rest solution solution of the shallow water equations on unstructured grids. We focus on flows over wet areas

  12. STANDARD ADDITION METHOD FOR THE DETERMINATION OF1 PHARMACEUTICAL RESIDUES IN DRINKING WATER BY SPE-2

    E-Print Network [OSTI]

    Boyer, Edmond

    STANDARD ADDITION METHOD FOR THE DETERMINATION OF1 PHARMACEUTICAL RESIDUES IN DRINKING WATER BY SPE-MS/MS is a powerful23 analytical tool often used to determine pharmaceutical residues at trace level in water.24 compounds in drinking or waste22 water processes has become very popular in recent years. LC

  13. Speciation of Sb in airborne particulate matter, vehicle brake linings, and brake pad wear residues

    E-Print Network [OSTI]

    Short, Daniel

    Speciation of Sb in airborne particulate matter, vehicle brake linings, and brake pad wear residues: XAS XANES EXAFS Antimony Particulate matter Brake linings a b s t r a c t Insights into the speciation of Sb in samples of brake linings, brake pad wear residues, road dust, and atmospheric particulate

  14. UPTAKE, ASSIMILATION, AND LOSS OF DDT RESIDUES BY Euphausia pacifica, A EUPHAUSIID SHRIMP

    E-Print Network [OSTI]

    UPTAKE, ASSIMILATION, AND LOSS OF DDT RESIDUES BY Euphausia pacifica, A EUPHAUSIID SHRIMP ABSTRACT acquire sufficient DDT residue from its food to account for amounts found in its tissues. Assimilation effii- ciencies for DDT in ingested food are similar to published figures for assimilation of carbon

  15. Measuring the Residual Ferrite Content of Rapidly Solidified Stainless Steel Alloys-

    E-Print Network [OSTI]

    Eagar, Thomas W.

    -Gage and ferrite meters have been developed to measure the amount of residual ferrite in duplex stainless steel) ) Measuring the Residual Ferrite Content of Rapidly Solidified Stainless Steel Alloys. Electron beam welds, laser beam welds and rapidly solidified stainless steel alloys have small physical

  16. Prediction of catalytic residues in proteins using machine-learning techniques

    E-Print Network [OSTI]

    Prediction of catalytic residues in proteins using machine-learning techniques Natalia V. Petrova) and prediction of protein function using various properties of proteins and amino acids (2). Prediction of the functional residues is a challenging and interesting task. The results of such prediction could

  17. Prediction of Interface Residues in ProteinProtein Complexes by a Consensus Neural Network Method: Test

    E-Print Network [OSTI]

    Weston, Ken

    Prediction of Interface Residues in Protein­Protein Complexes by a Consensus Neural Network Method important information for predicting struc- tures of new protein complexes. This motivated us to develop the PPISP method for predicting inter- face residues in protein­protein complexes. In PPISP, sequence

  18. MALATHION RESIDUES IN GREEK HONEY Andreas T. THRASYVOULOU Michael D. IFANTIDIS Nikos L. PAPPAS*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    -1982 were analyzed for malathion residues. Residues were extracted with acetonitrile/water solution, parti the north, the south, and some Greek islands as well. Reagents Acetonitrile - Nanograde (Mallinckrodt, Inc. Fifty ml of a 10/90 wa- ter/acetonitrile solution was added and the funnel shaken vigorously until

  19. Petroleum Coke: A Viable Fuel for Cogeneration 

    E-Print Network [OSTI]

    Dymond, R. E.

    1992-01-01T23:59:59.000Z

    . Increasing environmental concerns could disrupt historic markets and threaten coker operations. This would create opportunities for alternate end-uses such as cogeneration projects. The Pace Consultants Inc. continuously monitors and reports on the petroleum...

  20. Coking Coal Prices for Industry - EIA

    Gasoline and Diesel Fuel Update (EIA)

    Prices for Industry for Selected Countries1 U.S. Dollars per Metric Ton2 Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Argentina NA NA NA NA NA 37.24 NA NA NA Austria NA NA...

  1. Petroleum Coke: A Viable Fuel for Cogeneration

    E-Print Network [OSTI]

    Dymond, R. E.

    ; buy sulfur dioxide credits on the open market; install FGD; or switch to clean coal technology such as circulating fluidized bed combustion and gasification. Current trends in utility modernization are to utilize new clean coal technologies...

  2. Table 16. U.S. Coke Exports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oilAll Tables133,477 133,5910. Average3.5.6.

  3. Table 21. U.S. Coke Imports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oilAll Tables133,477 133,5910.9. Average1.

  4. Application of neutron diffraction to measure residual strains in high temperature composites

    SciTech Connect (OSTI)

    Saigal, A. (Tufts Univ., Medford, MA (USA). Dept. of Mechanical Engineering); Kupperman, D.S. (Argonne National Lab., IL (USA))

    1991-01-01T23:59:59.000Z

    An experimental neutron diffraction technique was used to measure residual thermal strains developed in high temperature composites during postfabrication cooling. Silicon carbide fiber-reinforced titanium aluminide (over the temperature range 20--950{degree}C) and tungsten and saphikon fiber-reinforced nickel aluminide composites (at room temperature) were investigated. As a result of thermal expansion mismatch, compressive residual strains and stresses were generated in the silicon carbide fibers during cooldown. The axial residual strains were tensile in the matrix and were lower in nickel aluminide matrix as compared to those in titanium aluminide matrix. The average transverse residual strains in the matrix were compressive. Liquid-nitrogen dipping and thermal-cycling tend to reduce the fabrication-induced residual strains in silicon carbide fiber-reinforced titanium aluminide matrix composite. However, matrix cracking can occur as a result of these processes. 10 refs., 5 figs., 2 tabs.

  5. Neutron diffraction measurements of residual stresses in friction stir welding: a review

    SciTech Connect (OSTI)

    Woo, Wan Chuck [ORNL; Feng, Zhili [ORNL; Wang, Xun-Li [ORNL; David, Stan A [ORNL

    2011-01-01T23:59:59.000Z

    Significant amounts of residual stresses are often generated during welding and result in critical degradation of the structural integrity and performance of components. Neutron diffraction has become a well established technique for the determination of residual stresses in welds because of the unique deep penetration, three-dimensional mapping capability, and volume averaged bulk measurements characteristic of the scattering neutron beam. Friction stir welding has gained prominence in recent years. The authors reviewed a number of neutron diffraction measurements of residual stresses in friction stir welds and highlighted examples addressing how the microstructures and residual stresses are correlated with each other. An example of in situ neutron diffraction measurement result shows the evolution of the residual stresses during welding.

  6. Structural group analysis of residues from Athabasca bitumen

    SciTech Connect (OSTI)

    Gray, M.R.; Choi, J.H.K.; Egiebor, N.O.; Kirchen, R.P.; Sanford, E.C.

    1988-06-01T23:59:59.000Z

    Non-distillable fractions of hydrocarbons such as bitumen are a challenge for analysis because of their molecular complexity and high heteroatom content. One method for characterizing their composition is by analysis for a relatively small number of structures expected to predominate in the mixture, i.e. for the significant structural groups. Because NMR spectroscopy can give quantitative data on the distribution of hydrogen and carbon types, it is an ideal method for group-based analysis. This study uses a structural group formalism which combines data from several analytical methods into a single profile. Residue fractions derived from Athabasca bitumen were investigated to determine the different chemical structures which could have an impact on subsequent processing. Structural analysis is the identification of key structures from analytical data that characterize a complex mixture. Higher accuracy data, from elemental, /sup 1/H-NMR, IR and titration analyses, are used to construct balance equations which must be satisfied. The spectral envelope of /sup 13/C-NMR is more difficult to resolve quantatitively, and hence /sup 13/C-NMR data are used as constraints to compute the concentrations of structural groups. The mathematical notation and methods have been presented previously. The structural analysis transforms the spectrometric data into a more useable form; the maximum number of groups that can be calculated is limited to the number of useful analytical measurements.

  7. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, Wen Y. (Houston, TX)

    1984-01-01T23:59:59.000Z

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them (46, 53, 61, 69) with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide (63) to precipitate silicon constituents, the pH of the resultant solution is increased (81), preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated (84) to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process (86, 18, 17) where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  8. Tidal Residual Eddies and their Effect on Water Exchange in Puget Sound

    SciTech Connect (OSTI)

    Yang, Zhaoqing; Wang, Taiping

    2013-08-30T23:59:59.000Z

    Tidal residual eddies are one of the important hydrodynamic features in tidally dominant estuaries and coastal bays, and they could have significant effects on water exchange in a tidal system. This paper presents a modeling study of tides and tidal residual eddies in Puget Sound, a tidally dominant fjord-like estuary in the Pacific Northwest coast, using a three-dimensional finite-volume coastal ocean model. Mechanisms of vorticity generation and asymmetric distribution patterns around an island/headland were analyzed using the dynamic vorticity transfer approach and numerical experiments. Model results of Puget Sound show that a number of large twin tidal residual eddies exist in the Admiralty Inlet because of the presence of major headlands in the inlet. Simulated residual vorticities near the major headlands indicate that the clockwise tidal residual eddy (negative vorticity) is generally stronger than the anticlockwise eddy (positive vorticity) because of the effect of Coriolis force. The effect of tidal residual eddies on water exchange in Puget Sound and its sub-basins were evaluated by simulations of dye transport. It was found that the strong transverse variability of residual currents in the Admiralty Inlet results in a dominant seaward transport along the eastern shore and a dominant landward transport along the western shore of the Inlet. A similar transport pattern in Hood Canal is caused by the presence of tidal residual eddies near the entrance of the canal. Model results show that tidal residual currents in Whidbey Basin are small in comparison to other sub-basins. A large clockwise residual circulation is formed around Vashon Island near entrance of South Sound, which can potentially constrain the water exchange between the Central Basin and South Sound.

  9. In: . Proceedings of the 91st Annual Meeting (held June 14-18 in San Diego, CA), Air and Waste Management Association, Pittsburgh, Pennsylvania, June 1998 (CD-ROM). 1998 H.C. Frey

    E-Print Network [OSTI]

    Frey, H. Christopher

    natural gas, petroleum residuals, petroleum coke, refinery wastes, and coal as inputs. In recent years 27695-7908 ABSTRACT Gasification systems, such as coal-based integrated gasification combined cycle there is currently a lack of high-value markets for low-value liquid residues and coke.(2) Integrated Gasification

  10. Auto shredder residue recycling: Mechanical separation and pyrolysis

    SciTech Connect (OSTI)

    Santini, Alessandro [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Passarini, Fabrizio, E-mail: fabrizio.passarini@unibo.it [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Vassura, Ivano [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Serrano, David; Dufour, Javier [Department of Chemical and Energy Technology, ESCET, Universidad Rey Juan Carlos, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Instituto IMDEA Energy, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Morselli, Luciano [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy)

    2012-05-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

  11. Sustainable Agricultural Residue Removal for Bioenergy: A Spatially Comprehensive National Assessment

    SciTech Connect (OSTI)

    D. Muth, Jr.; K. M. Bryden; R. G. Nelson

    2013-02-01T23:59:59.000Z

    This study provides a spatially comprehensive assessment of sustainable agricultural residue removal potential across the United States. Earlier assessments determining the quantity of agricultural residue that could be sustainably removed for bioenergy production at the regional and national scale faced a number of computational limitations. These limitations included the number of environmental factors, the number of land management scenarios, and the spatial fidelity and spatial extent of the assessment. This study utilizes integrated multi-factor environmental process modeling and high fidelity land use datasets to perform a spatially comprehensive assessment of sustainably removable agricultural residues across the conterminous United States. Soil type represents the base spatial unit for this study and is modeled using a national soil survey database at the 10 – 100 m scale. Current crop rotation practices are identified by processing land cover data available from the USDA National Agricultural Statistics Service Cropland Data Layer database. Land management and residue removal scenarios are identified for each unique crop rotation and crop management zone. Estimates of county averages and state totals of sustainably available agricultural residues are provided. The results of the assessment show that in 2011 over 150 million metric tons of agricultural residues could have been sustainably removed across the United States. Projecting crop yields and land management practices to 2030, the assessment determines that over 207 million metric tons of agricultural residues will be able to be sustainably removed for bioenergy production at that time.

  12. Effects of weld residual stresses on crack-opening area analysis of pipes for LBB applications

    SciTech Connect (OSTI)

    Dong, P.; Rahman, S.; Wilkowski, G. [and others

    1997-04-01T23:59:59.000Z

    This paper summarizes four different studies undertaken to evaluate the effects of weld residual stresses on the crack-opening behavior of a circumferential through-wall crack in the center of a girth weld. The effect of weld residual stress on the crack-opening-area and leak-rate analyses of a pipe is not well understood. There are no simple analyses to account for these effects, and, therefore, they are frequently neglected. The four studies involved the following efforts: (1) Full-field thermoplastic finite element residual stress analyses of a crack in the center of a girth weld, (2) A comparison of the crack-opening displacements from a full-field thermoplastic residual stress analysis with a crack-face pressure elastic stress analysis to determine the residual stress effects on the crack-opening displacement, (3) The effects of hydrostatic testing on the residual stresses and the resulting crack-opening displacement, and (4) The effect of residual stresses on crack-opening displacement with different normal operating stresses.

  13. Microstructure and residual stress evaluation of ductile cast iron using the critically refracted longitudinal (Lcr) wave propagation technique 

    E-Print Network [OSTI]

    Bennett, Robert Jeffrey

    1993-01-01T23:59:59.000Z

    Residual stress and microstructure evaluation of ductile cast iron using a nondestructive method (Critically Refracted Longitudinal Ultrasonic Wave Technique) was approached. Residual stresses, both good and bad graphite nodules, and different...

  14. Injection, flow, and mixing of CO2 in porous media with residual gas.

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Doughty, C.A.

    2010-09-01T23:59:59.000Z

    Geologic structures associated with depleted natural gas reservoirs are desirable targets for geologic carbon sequestration (GCS) as evidenced by numerous pilot and industrial-scale GCS projects in these environments world-wide. One feature of these GCS targets that may affect injection is the presence of residual CH{sub 4}. It is well known that CH{sub 4} drastically alters supercritical CO{sub 2} density and viscosity. Furthermore, residual gas of any kind affects the relative permeability of the liquid and gas phases, with relative permeability of the gas phase strongly dependent on the time-history of imbibition or drainage, i.e., dependent on hysteretic relative permeability. In this study, the effects of residual CH{sub 4} on supercritical CO{sub 2} injection were investigated by numerical simulation in an idealized one-dimensional system under three scenarios: (1) with no residual gas; (2) with residual supercritical CO{sub 2}; and (3) with residual CH{sub 4}. We further compare results of simulations that use non-hysteretic and hysteretic relative permeability functions. The primary effect of residual gas is to decrease injectivity by decreasing liquid-phase relative permeability. Secondary effects arise from injected gas effectively incorporating residual gas and thereby extending the mobile gas plume relative to cases with no residual gas. Third-order effects arise from gas mixing and associated compositional effects on density that effectively create a larger plume per unit mass. Non-hysteretic models of relative permeability can be used to approximate some parts of the behavior of the system, but fully hysteretic formulations are needed to accurately model the entire system.

  15. Community-wide benefits of targeted indoor residual spray for malaria control in the Western Kenya Highland

    E-Print Network [OSTI]

    Zhou, Guofa; Githeko, Andrew K; Minakawa, Noboru; Yan, Guiyun

    2010-01-01T23:59:59.000Z

    ecological settings [4]. Among those control measures, insecticide- treated bed nets (ITNs) and indoor residual-house

  16. The effect of cooking preparations on the residual sulfite concentrations in shrimp

    E-Print Network [OSTI]

    Lally, Audrey Ann

    1987-01-01T23:59:59.000Z

    of this study was, therefore, to determine the effect of various types of cook- ing preparations on the residual sulfite in shrimp. The specific obgectives were: 1. To determine the residual sulfite when shrimp were boiled in water shell-on and shell-off. 2.... (1978). This may be due to the difference in brine concentrations and a possible increase of diffusion rate in shrimp versus beans. The Effect of Processing Procedures on Residual Sulfites in ~Shrim The different cooking procedures affected the rate...

  17. Onsager's symmetry relation and the residual parallel Reynolds stress in a magnetized plasma with electrostatic turbulence

    SciTech Connect (OSTI)

    Zuo, Yang, E-mail: yangzustc@gmail.com; Wang, Shaojie [Department of Modern Physics, University of Science and Technology of China, Hefei 230026 (China)

    2014-09-15T23:59:59.000Z

    The physics of the residual parallel Reynolds stress in a rotating plasma with electrostatic turbulence is explicitly identified by using the transport formulation of the gyrokinetic turbulence. It is clarified that the residual stress consists of four terms, among which are the cross terms due to the pressure gradient and the temperature gradient and the terms related to the turbulent acceleration impulse and the turbulent heating rate. The last two terms are identified for the first time, and are shown to cause analogous residual term in the heat flux. Meanwhile, the transport matrix reveals diffusion in the phase space. The transport matrix is demonstrated to satisfy the Onsager's symmetry relation.

  18. Evaluation of low-residue soldering for military and commercial applications: A report from the Low-Residue Soldering Task Force

    SciTech Connect (OSTI)

    Iman, R.L.; Anderson, D.J. [Sandia National Labs., Albuquerque, NM (United States); Burress, R.V. [SEHO (United States)] [and others

    1995-06-01T23:59:59.000Z

    The LRSTF combined the efforts of industry, military, and government to evaluate low-residue soldering processes for military and commercial applications. These processes were selected for evaluation because they provide a means for the military to support the presidential mandate while producing reliable hardware at a lower cost. This report presents the complete details and results of a testing program conducted by the LRSTF to evaluate low-residue soldering for printed wiring assemblies. A previous informal document provided details of the test plan used in this evaluation. Many of the details of that test plan are contained in this report. The test data are too massive to include in this report, however, these data are available on disk as Excel spreadsheets upon request. The main purpose of low-residue soldering is to eliminate waste streams during the manufacturing process.

  19. On the residual entropy of the BlumeEmeryGri#ths Gastao A. Braga and Paulo C. Lima

    E-Print Network [OSTI]

    Lima, Paulo C.

    of residual entropy was pointed out by Linus Pauling [3] to describe water ice, which is an exampleOn the residual entropy of the Blume­Emery­Gri#ths model Gast�ao A. Braga and Paulo C. Lima Abstract By means of a transfer matrix method, we show that the residual entropy S of the two dimensional

  20. Residual Fertilizer Nitrogen in a Flooded Rice Soil1 K. R. REDDY AND W. H. PATRICK, JR. 2

    E-Print Network [OSTI]

    Florida, University of

    in the soil-water-plant system was measured. Approxi- Residual effects of 15 N-labelled fertilizer (ammoniumResidual Fertilizer Nitrogen in a Flooded Rice Soil1 K. R. REDDY AND W. H. PATRICK, JR. 2 ABSTRACT) to majntain jts identity in the soil during the top dressing. The uptake of residual labelled N (that present

  1. Polybrominated dibenzo-p-dioxins/dibenzofurans and polybrominated diphenyl ethers in soil, vegetation, workshop-floor dust, and electronic shredder residue from an electronic waste recycling facility and in soils from a chemical industrial complex in eastern China

    SciTech Connect (OSTI)

    Jing Ma; Rudolf Addink; Sehun Yun; Jinping Cheng; Wenhua Wang; Kurunthachalam Kannan [Shanghai Jiao Tong University, Shanghai (China). School of Environmental Science and Engineering

    2009-10-01T23:59:59.000Z

    In this study, 11 2,3,7,8-substituted PBDD/Fs and 10 polybrominated diphenyl ether (PBDE) congeners were determined in electronic shredder waste, workshop-floor dust, soil, and leaves (of plants on the grounds of the facility) from a large-scale electronic wastes (e-waste) recycling facility and in surface soil from a chemical-industrial complex (comprising a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) as well as agricultural areas in eastern China. Total PBDD/F concentrations in environmental samples were in the range of 113-818 pg/g dry wt (dw) for leaves, 392-18,500 pg/g dw for electronic shredder residues, 716-80,0000 pg/g dw for soil samples, and 89,600-14,3000 pg/g dw for workshop-floor dust from the e-waste recycling facility and in a range from nondetect (ND) to 427 pg/g dw in soil from the chemical-industrial complex. The highest mean concentrations of total PBDD/Fs were found in soil samples and workshop-floor dust from the e-waste recycling facility. The dioxin-like toxic equivalent (measured as TEQ) concentrations of PBDD/Fs were greater than the TEQs of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) reported in our previous study for the same set of samples. The concentrations of PBDFs were several orders of magnitude higher than the concentrations of PBDDs in samples from the e-waste facility or from soil from the chemical-industrial complex. A significant correlation was found between the concentrations of {Sigma}PBDD/Fs and {Sigma}PBDEs (r = 0.769, p < 0.01) and between SPBDD/Fs and the previously reported SPCDD/F concentrations (r = 0.805, p < 0.01). The estimated daily human intakes of TEQs contributed by PBDD/Fs via soil/dust ingestion and dermal exposures in e-waste recycling facilities were higher than the intakes of TEQs contributed by PCDD/Fs, calculated in our previous study. 45 refs., 2 figs., 2 tabs.

  2. E-Print Network 3.0 - acid residues responsible Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    King Fahd University of Petroleum and Minerals Collection: Fossil Fuels 4 Protein folding with stochastic L-systems Gemma Danks1 Summary: 70 amino acid residues to 1000s...

  3. US Apple Association Having an Impact Insecticide Residues in Apple Juice

    E-Print Network [OSTI]

    Ginzel, Matthew

    weeks ago we would have said two weeks early, right now we're saying maybe a week early. The cool syrup, soybeans, and milk for residues of a number of different pesticides. While I hate to bore you

  4. A Weighted Residual Framework for Formulation and Analysis of Direct Transcription Methods for Optimal Control 

    E-Print Network [OSTI]

    Singh, Baljeet

    2012-02-14T23:59:59.000Z

    In the past three decades, numerous methods have been proposed to transcribe optimal control problems (OCP) into nonlinear programming problems (NLP). In this dissertation work, a unifying weighted residual framework is developed under which most...

  5. Absorbing Aerosol Index (AAI) The residue method for the detection of aerosols

    E-Print Network [OSTI]

    Graaf, Martin de

    Absorbing Aerosol Index (AAI) The residue method for the detection of aerosols from space reflection and absorption Surface Rayleigh atmosphere #12;TOA Multiple scattering Multiple scattering Aerosol layer satellite Surface reflection and absorption Surface Rayleigh atmosphere Rayleigh atmophere Aerosol

  6. Analysis of one-dimensional transforms in coding motion compensation prediction residuals for video applications

    E-Print Network [OSTI]

    Zhang, Harley (Harley H.)

    2011-01-01T23:59:59.000Z

    In video coding, motion compensation prediction provides significant increases in overall compression efficiency. The prediction residuals are typically treated as images and compressed by applying two-dimensional transforms ...

  7. Vehicle Technologies Office Merit Review 2014: Residual Stress of Bimetallic Joints and Characterization

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about residual stress...

  8. Hanford Tank 241-S-112 Residual Waste Composition and Leach Test Data

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Lindberg, Michael J.; Arey, Bruce W.; Schaef, Herbert T.

    2008-08-29T23:59:59.000Z

    This report presents the results of laboratory characterization and testing of two samples (designated 20406 and 20407) of residual waste collected from tank S-112 after final waste retrieval. These studies were completed to characterize the residual waste and assess the leachability of contami¬nants from the solids. This is the first report from this PNNL project to describe the composition and leach test data for residual waste from a salt cake tank. All previous PNNL reports (Cantrell et al. 2008; Deutsch et al. 2006, 2007a, 2007b, 2007c) describing contaminant release models, and characterization and testing results for residual waste in single-shell tanks were based on samples from sludge tanks.

  9. Ultrasonic measurement of residual stress relaxation in welded steel plates using critically refracted longitudinal waves

    E-Print Network [OSTI]

    Chance, Brent Houston

    2000-01-01T23:59:59.000Z

    This study investigates whether or not there is a measurable amount of residual transverse stress relaxation in welded steel. This was determined by using two different methods of stress measurement. These methods involved strain gauges...

  10. Minimizing Actuator-Induced Residual Error in Active Space Telescope Primary Mirrors

    E-Print Network [OSTI]

    . Smith, David W. Miller September 2010 SSL #12-10 #12;#12;Minimizing Actuator-Induced Residual Error in Active Space Telescope Primary Mirrors Matthew W. Smith, David W. Miller September 2010 SSL #12

  11. The influence of calcium on the inhibition of arsenic desorption from treatment residuals in extreme environments

    E-Print Network [OSTI]

    Camacho, Julianna G.

    2006-04-12T23:59:59.000Z

    the surface properties of the oxy-hydroxide solid in solution. Results show that calcium enhances the removal by iron oxides and prevents the leaching of arsenic from the residuals. Isotherm experiments show that arsenic adsorption can be described...

  12. Ultrasonic measurement of residual stress relaxation in welded steel plates using critically refracted longitudinal waves 

    E-Print Network [OSTI]

    Chance, Brent Houston

    2000-01-01T23:59:59.000Z

    This study investigates whether or not there is a measurable amount of residual transverse stress relaxation in welded steel. This was determined by using two different methods of stress measurement. These methods involved strain gauges...

  13. Characterization of residual stress relaxation in welded steel plate using TAP-NDE and wavelets 

    E-Print Network [OSTI]

    Jhun, Choon-Sik

    2001-01-01T23:59:59.000Z

    This thesis presents the characterization of residual stress relaxation in a welded ASTM 1018 steel plate by using the Thermo-Acousto-Photonic Nondestructive Evaluation (TAP-NDE) technique and the Gabor Wavelet Transform (GWT) which together produce...

  14. Table 42. Residual Fuel Oil Prices by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    45.5 49.2 W W 44.5 45.4 See footnotes at end of table. 42. Residual Fuel Oil Prices by PAD District and State Energy Information Administration Petroleum...

  15. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Gasoline and Diesel Fuel Update (EIA)

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  16. Table 42. Residual Fuel Oil Prices by PAD District and State

    U.S. Energy Information Administration (EIA) Indexed Site

    55.1 47.1 W W 55.1 46.2 See footnotes at end of table. 42. Residual Fuel Oil Prices by PAD District and State Energy Information Administration Petroleum...

  17. Variation in energy expenditures between growing steers with divergent residual feed intakes 

    E-Print Network [OSTI]

    White, Monte Blaine III

    2006-04-12T23:59:59.000Z

    Objectives of this study were to determine if variation in energy expenditures contributed to differences in feed efficiency between low and high RFI steers. Nine steers with the lowest and highest residual feed intakes ...

  18. Roles of key active-site residues in flavocytochrome P450 BM3

    E-Print Network [OSTI]

    Noble, Michael A.; Miles, Caroline S.; Chapman, Stephen K.; Lysek, Dominikus A.; MacKay, Angela C.; Reid, Graeme A.; Hanzlik, Robert P.; Munro, Andrew W.

    1999-01-01T23:59:59.000Z

    The effects of mutation of key active-site residues (Arg-47, Tyr-51, Phe-42 and Phe-87) in Bacillus megaterium flavocytochrome P450 BM3 were investigated. Kinetic studies on the oxidation of laurate and arachidonate showed ...

  19. Residual stress and self-assembly during deposition and etching of MEMS 

    E-Print Network [OSTI]

    Mani, Sathyanarayanan

    2002-01-01T23:59:59.000Z

    General relations are provided for the work rate and complementary work rate on a body containing evolving boundaries, residual stresses, and stresses due to boundary tractions. Closed-form solutions are provided for three simple examples...

  20. Relationships Between Residual Feed Intake and Performance of Heifers of Diverse Breedtypes and Brahman Cows 

    E-Print Network [OSTI]

    Loyd, Andrea N.

    2010-10-12T23:59:59.000Z

    et al., 1990) and can be manipulated to influence reproductive performance. Residual feed intake reflects differences in how cattle use nutrients for life processes such as maintenance, growth, gestation and lactation (Kennedy et al., 1993). As a...

  1. Evaluation of Residual Stress Levels in Plasma Electrolytic Oxidation Coatings using a Curvature Method

    E-Print Network [OSTI]

    Dean, J.; Gu, T.; Clyne, T. W.

    2014-11-09T23:59:59.000Z

    Experimental estimates have been made of typical levels of residual stress in plasma electrolytic oxidation (PEO) coatings formed on aluminium and magnesium alloy substrates. This has been done via measurement of the curvature exhibited by thin...

  2. Sources of biological variation in residual feed intake in growing and finishing steers 

    E-Print Network [OSTI]

    Brown, Erin Gwen

    2006-04-12T23:59:59.000Z

    Objectives of this research were to characterize residual feed intake (RFI) in growing and finishing steers and examine phenotypic correlations between performance, feed efficiency, carcass, digestib ility, and physiological ...

  3. Control of residual aluminum from conventional treatment to improve reverse osmosis performance

    E-Print Network [OSTI]

    Gabelich, C J; Ishida, K P; Gerringer, F W; Evangelista, R; Kalyan, M; Suffet, I H

    2006-01-01T23:59:59.000Z

    2005. The Role of Dissolved Aluminum in Silica Chemistry forDraft Public Health Goal for Aluminum in Drinking Water .1994. Control of Residual Aluminum in Filtered Water . AWWA,

  4. Root cause analysis of solder flux residue incidence in the manufacture of electronic power modules

    E-Print Network [OSTI]

    Jain, Pranav

    2011-01-01T23:59:59.000Z

    This work investigates the root causes of the incidence of solder flux residue underneath electronic components in the manufacture of power modules. The existing deionized water-based centrifugal cleaning process was ...

  5. A New Analytical Method to Quantify Residual Fluid Cleanup in Hydraulic Fractures

    E-Print Network [OSTI]

    Zarrin, Tahira

    2014-04-17T23:59:59.000Z

    hydraulic fracturing fluid has always been a major issue, and is believed to drastically undermine the performance of hydraulically fractured wells. Several attempts have been made to quantify the damage associated with residual fluid, with varying level...

  6. Growth response of selected vegetable species to plant residue of guar (Cyamopsis tetragonoloba (L.) Taub.)

    E-Print Network [OSTI]

    Reid, Debbie John

    1992-01-01T23:59:59.000Z

    GROWTH RESPONSE OF SELECTED VEGETABLE SPECIES TO PLANT RESIDUE OF GUAR (Cyamopsis tetragonoloba (L. ) Taub. ) A Thesis by DEBBIE JOHN REID Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1992 Major Subject: Horticulture GROWTH RESPONSE OF SELECTED VEGETABLE SPECIES TO PLANT RESIDUE OF GUAR (Cyamopsis tetragonoloba (L. ) Taub. ) A Thesis by DEBBIE JOHN REID Approved as to style...

  7. Experimental study of the residual stress-induced self-assembly of MEMS structures during deposition

    E-Print Network [OSTI]

    Kim, Sang-Hyun

    2005-11-01T23:59:59.000Z

    three layers (b doped Si, Ge, B doped Si) to deform (or ?roll up?) into cylinders with radii of curvature from 0.3 to 2 micrometers. 9 It would be useful if intrinsic stresses could be used to enable a structure to assemble itself during processing... of [29]. 10 II. ANALYTICAL MODELING The possibility of usefully using residual (or intrinsic) stresses as a means of self- assembling MEMS during material deposition is analytically investigated. A. Self-Assembly and Residual Stress Suppose...

  8. Deformations associated with relaxation of residual stresses in the Barre Granite of Vermont

    E-Print Network [OSTI]

    Nichols, Thomas Chester

    1972-01-01T23:59:59.000Z

    DEFORMATIONS ASSOCIATED WITH RELAXATION OF RESIDUAL STRESSES IN THE BARRE GRANITE OF VERMONT A Thesis by THOMAS CHESTER NICHOLS, JR. Submitted to the Graduate College of Texas AfM University in Partial fulfillment of the requirements... for the degree of MASTER QF SCIENCE May, 1972 Major Subject: Geology DEFORMATIONS ASSOCIATED WITH RELAXATION OF RESIDUAL STRESSES IN THE BARRE GRANITE OF VERMONT A Thesis THOMAS CHESTER NICHOLS, JR. Approved as to style and content by: airman o Committee...

  9. Incineration of Residue from Paint Stripping Operations Using Plastic Media Blasting

    E-Print Network [OSTI]

    Helt, J. E.; Mallya, N.

    i INCINERATION OF RESIDUE FROH PAINT STRIPPING OPERATIONS USING PLASTIC MEDIA BLASTING J. E. HELT N. MALLYA Group Leader Chemist Chemical Technology Division Chemical Technology Division Argonne National Laboratory Argonne National... potentially be classified as a hazardous waste. One possible alternative to depositing the waste residue directly into a hazardous waste landfill is inciner ation. Incineration would provide desirable volume reduction. However. the fate of heavy metals...

  10. Pharmacokinetics and tissue residue depletion of fenbendazole in healthy and bronchopneumonic calves

    E-Print Network [OSTI]

    Weise, Dale Wade

    1991-01-01T23:59:59.000Z

    PHARMACOKINETICS AND TISSUE RESIDUE DEPLETION OF FENBENDAZOLE IN HEALTHY AND BRONCHOPNEUMONIC CALVES A Thesis by DALE WADE WEISE Submitted to the Office of Graduate Studies Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1991 Major Subject: Veterinary Physiology PHARMACOKINETICS AND TISSUE RESIDUE DEPLETION OF FENBENDAZOLE IN HEALTHY AND BRONCHOPNEUMONIC CALVES A Thesis by DALE WADE WEISE Approved as to style and content by...

  11. Polymorphisms at amino acid residues 141 and 154 influence conformational variation in ovine PrP

    E-Print Network [OSTI]

    Yang, Sujeong; Thackray, Alana M.; Hopkins, Lee; Monie, Tom P.; Burke, David F.; Bujdoso, Raymond

    2014-07-14T23:59:59.000Z

    of helix-2, and the N- terminal region of helix-3. This central core is bound by an intramolecular disulphide bond between amino acid residues in helix-2 and helix-3. Characterisation of the protein folding events that occur during the conformational change... requirements of the particular protein fold or to particular functions mediated by interactions with other molecules. Crescendo conservation scores associated with every amino acid residue was assigned to the three-dimensional coordi- nate of the atommost...

  12. Residual thermal stresses in an unsymmetrical cross-ply graphite/epoxy laminate 

    E-Print Network [OSTI]

    Harper, Brian Douglas

    1980-01-01T23:59:59.000Z

    RESIDUAL THERMAL STRESSES IN AN UNSYMMETRICAL CROSS-PLY GRAPHITE/EPOXY LAMINATE A Thesis by BRIAN DOUGLAS HARPER Submitted to the Graduate College of Texas A&M University in parrial fulfillment of the requirement for the degree of MASTER... OF SCIENCE August 1980 Major Subject: Mechanical Engineering RESIDUAL THERMAL STRESSES IN AN UNSYMMETRICAL CROSS-PLY GRAPHITE/EPOXY LAMINATE A Thesis by BRIAN DOUGLAS HARPER Approved as to style and content by: r. Y. N itsman (Chair of Committee) Dr...

  13. Determine metrics and set targets for soil quality on agriculture residue and energy crop pathways

    SciTech Connect (OSTI)

    Ian Bonner; David Muth

    2013-09-01T23:59:59.000Z

    There are three objectives for this project: 1) support OBP in meeting MYPP stated performance goals for the Sustainability Platform, 2) develop integrated feedstock production system designs that increase total productivity of the land, decrease delivered feedstock cost to the conversion facilities, and increase environmental performance of the production system, and 3) deliver to the bioenergy community robust datasets and flexible analysis tools for establishing sustainable and viable use of agricultural residues and dedicated energy crops. The key project outcome to date has been the development and deployment of a sustainable agricultural residue removal decision support framework. The modeling framework has been used to produce a revised national assessment of sustainable residue removal potential. The national assessment datasets are being used to update national resource assessment supply curves using POLYSIS. The residue removal modeling framework has also been enhanced to support high fidelity sub-field scale sustainable removal analyses. The framework has been deployed through a web application and a mobile application. The mobile application is being used extensively in the field with industry, research, and USDA NRCS partners to support and validate sustainable residue removal decisions. The results detailed in this report have set targets for increasing soil sustainability by focusing on primary soil quality indicators (total organic carbon and erosion) in two agricultural residue management pathways and a dedicated energy crop pathway. The two residue pathway targets were set to, 1) increase residue removal by 50% while maintaining soil quality, and 2) increase soil quality by 5% as measured by Soil Management Assessment Framework indicators. The energy crop pathway was set to increase soil quality by 10% using these same indicators. To demonstrate the feasibility and impact of each of these targets, seven case studies spanning the US are presented. The analysis has shown that the feedstock production systems are capable of simultaneously increasing productivity and soil sustainability.

  14. Residual stress in laser welded dissimilar steel tube-to-tube joints

    SciTech Connect (OSTI)

    Sun, Zheng (Technical Research Centre of Finland, Espoo (Finland). Lab. of Production Engineering)

    1993-09-01T23:59:59.000Z

    Austenitic-ferritic dissimilar steel joints are widely used in power generation systems. Their utilization has proved to be efficient in terms of satisfactory properties and the economics. These types of joints have usually been produced using conventional welding processes, such as tungsten inert gas (TIG) welding. With the rapid development of high power lasers, laser welding has received considerable attention. Laser welding offers many advantages over conventional welding processes, e.g. low heat input, small heat-affected zone (HAZ), small distortion, and welding in an exact and reproducible manner. Residual stress distribution in laser welds may also differ from those made by conventional welding processes due to its special features. Residual stress, particularly tensile residual stress in the weld, can be very important factor in controlling the quality and service life of the welded structure. The formation of tensile residual stress in the weld may result in the initiation of fatigue cracking, stress corrosion cracking or other types of fractures. It is useful, therefore, to understand the distribution of residual stress in austenitic-ferritic laser welds, and thus evaluate the quality of the joints. Although residual stress distribution in the welded joints has been extensively investigated, little data are available for the residual stress distribution in laser welds. The aim of the work was to examine residual stress distribution along laser welds of dissimilar steel tube-to-tube joints, which were made by both autogeneous welding and welding with filler wire. The results were also compared with the joints made by plasma arc and TIG welding.

  15. MODELING OF PLUTONIUM RECOVERY AND DISCARD PROCESSES FOR THE PURPOSE OF SELECTING OPTIMUM (MINIMUM WASTE, COST AND DOSE) RESIDUE DISPOSITIONS

    SciTech Connect (OSTI)

    M. A. ROBINSON; M. B. KINKER; ET AL

    2001-04-01T23:59:59.000Z

    Researchers have developed a quantitative basis for disposition of actinide-bearing process residues. Research included the development of a technical rationale for determining when residues could be considered unattractive for proliferation purposes, and establishing plutonium-concentration-based discard ceilings of unimmobilized residues and richer discard ceilings for immobilized monolithic waste forms. Further quantitative analysis (process modeling) identifies the plutonium (Pu) concentration at which residues should be discarded to immobilization in order to minimize the quantifiable negative consequences of residue processing (cost, waste, dose). Results indicate that optimum disposition paths can be identified by process modeling, and that across-the-board discard decisions maximize negative consequences.

  16. DISPOSAL OF EMPTY CHEMICAL CONTAINERS Empty chemical containers can contain residual amounts of chemicals. In an effort to ensure that this residue is

    E-Print Network [OSTI]

    Maroncelli, Mark

    containers or any plastic containers, plastic tubing, or plastic beakers that do not meet the recyclingDISPOSAL OF EMPTY CHEMICAL CONTAINERS Empty chemical containers can contain residual amounts or properly dispose of these containers, the following procedure has been developed by EHS in conjunction

  17. INDUST: An Industrial Data Base

    E-Print Network [OSTI]

    Wilfert, G. L.; Moore, N. L.

    .5% of the natural gas consump tion, 98.1% of the fuel oil consumption, 99.2% of the coal/coke consumption, and 99.7% of a class of fuels called "other" fuels. Within these 13 indus try groups, INDUST addresses a wide variety of energy-intense industries... the manufac turing sector, Table 1 shows the latest EIA pro visional estimate of energy consumption (in trillion Btu) for 1985. The EIA reports fuel consumption according to five categories: electricity, fuel oil, natural gas, coal and coke, and other...

  18. All auto shredding: evaluation of automotive shredder residue generated by shredding only vehicles.

    SciTech Connect (OSTI)

    Duranceau, C. M.; Spangenberger, J. S. (Energy Systems); (Vehicle Recycling Partnership, LLC); (American Chemistry Counsel, Plastics Division)

    2011-09-26T23:59:59.000Z

    A well developed infrastructure exists for the reuse and recycling of automotive parts and materials. At the end of a vehicle's useful life many parts are removed and sold for reuse and fluids are recovered for recycling or proper disposal. What remains is shredded, along with other metal bearing scrap such as home appliances, demolition debris and process equipment, and the metals are separated out and recycled. The remainder of the vehicle materials is call shredder residue which ends up in the landfill. As energy and natural resources becomes more treasured, increased effort has been afforded to find ways to reduce energy consumption and minimize the use of our limited resources. Many of the materials found in shredder residue could be recovered and help offset the use of energy and material consumption. For example, the energy content of the plastics and rubbers currently landfilled with the shredder residue is equivalent to 16 million barrels of oil per year. However, in the United States, the recovered materials, primarily polymers, cannot be recycled due to current regulatory barriers which preclude the re-introduction into commerce of certain materials because of residual contamination with substances of concern (SOCs) such as polychlorinated biphenyls (PCBs). The source of the PCBs is not well understood. Old transformers, capacitors, white goods and ballasts from lighting fixtures are likely contributing factors. The project was designed to evaluate whether vehicles of varying age and manufacturing origin contribute to the PCB content in shredder residue. Additionally, the project was designed to determine if there are any trends in material composition of the shredder residue from varied age and manufacturing groups. This information would aid in future material recovery facility strategy and design. The test utilized a newly installed shredder plant to shred four categories of automobiles. The categories were defined by vehicle age and the manufacturing company and location. Each category of vehicles was processed individually through the shredder plant and the resulting shredder residue was analyzed for its materials composition and presence of PCBs and leachable metals. The results show that shredder residue from all vehicle categories tested are not significant contributors of PCBs and leachable metals. It was evident that leachable cadmium levels have decreased in newer vehicles. The composition of the shredder residue from each of the four categories is similar to the others. In addition, these compositions are approximately equal to the composition of typical shredder residues, not limited to automotive materials.

  19. Measurement of residual stress in quenched 1045 steel by the nanoindentation method

    SciTech Connect (OSTI)

    Zhu Lina, E-mail: zhulina84@gmail.com [School of Engineering and Technology, China University of Geosciences, Beijing 100083 (China); National Key Laboratory for Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072 (China); Xu Binshi; Wang Haidou [National Key Laboratory for Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072 (China); Wang Chengbiao [School of Engineering and Technology, China University of Geosciences, Beijing 100083 (China)

    2010-12-15T23:59:59.000Z

    In this paper, the residual stress in quenched AISI 1045 steel was measured by a recently developed nanoindentation technique. Depth control mode was adopted to measure the residual stress. It was found that residual compressive stress was generated in the quenched steel. The material around nanoindents exhibits significant pile-up deformation. A new method was proposed to determine the real contact area for pile-up material on the basis of invariant pile-up morphology of the loaded or unloaded states. The results obtained by the new method were in good agreement with the residual stresses measured by the classical X-ray diffraction (XRD) method. - Research Highlights: {yields} A new method was proposed to measure the real contact area for pile-up materials. {yields} The real contact depth is defined as the sum of h{sub max} and the pile-up height h{sub p}. {yields} The value of residual stress measured by the nanoindentation method was in good agreement with that by the XRD method.

  20. Non-matrix corrected organic sulfur determination by energy dispersive X-ray spectroscopy for western Kentucky coals and residues

    SciTech Connect (OSTI)

    Clark, C.P.; Freeman, G.B.; Hower, J.C.

    1984-01-01T23:59:59.000Z

    A method for non-matrix corrected organic sulfur analysis by energy dispersive X-ray spectroscopy has been developed using petroleum coke standards. Typically, electron beam microanalysis is a rapid, nondestructive analytical technique to quantitatively measure organic sulfur in coal. The results show good correlation to ASTM values for numerous well characterized coals with a wide range in total and pyritic sulfur content. This direct analysis is capable of reducing error commonly associated with the present ASTM method which relies on an indirect measure of organic sulfur by difference. The precision of the organic sulfur values determined in the present study is comparable to that obtained by ZAF matrix corrected microanalysis. The energy dispersive microanalysis is capable of measuring micro as well as bulk organic sulfur levels.

  1. Research in Industrial Combustion Systems - Current and Future R&D

    E-Print Network [OSTI]

    Rebello, W. J.; Keller, J. G.

    combustor with its high pressure gain is attractive for use in the process to make Portland cement where energy is needed to heat the raw materials (coal or petroleum coke) and additional power is required for particle separation (electricity.... INTRODUCTION The total energy consumption in the U.S. in 1977 was about 76 Quads (quadrillion BTU). Of this amount, about 28 Quads were consumed by the industrial sector in the form of coal, petroleum, natural gas and electri city. The manufacturing...

  2. Energy Efficiency Improvement by Measurement and Control: A Case Study of Reheating Furnaces in the Steel Industry

    E-Print Network [OSTI]

    Martensson, A.

    , April 22-23, 1992 Table I. Furnace energy use in Sweden, 1989. Source: Jemkontoret, Stockholm, Sweden. Fuel Energy use a [GWh) ([10 9 Btu)) aI 1680 (5732) Propane 1272 (4340) Natural gas 48 (164) Coke oven gas 400 (1365) Electricity (induction...ENERGY EFFICIENCY IMPROVEMENT BY MEASUREMENT AND CONTROL A case study of reheating furnaces in the steel industry Anders Mlirtensson Department of Environmental and Energy Systems Studies Lund University S-22362 Lund Sweden ABSTRACT...

  3. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and. TABLE43.PDF

  4. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and. TABLE43.PDF 1995

  5. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and. TABLE43.PDF 1995

  6. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and. TABLE43.PDF

  7. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and. TABLE43.PDF..........

  8. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and.

  9. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and........... 76.4

  10. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and...........

  11. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and........... 1995

  12. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and...........

  13. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and.....................

  14. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and.....................

  15. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and.....................

  16. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and.....................

  17. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and.....................

  18. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and..................... |

  19. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and.....................

  20. U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources and Shipments; Unit: Physical Units or Btu. Coke and.....................