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Sample records for bryan mound brine

  1. Evaluation of brine disposal from the Bryan Mound site of the strategic petroleum reserve program. Final report

    SciTech Connect (OSTI)

    Case, Robert J.; Chittenden, Jr, Mark E.; Harper, Jr, Donald E.; Kelly, Jr, Francis J.; Loeblich, Laurel A.; McKinney, Larry D.; Minello, Thomas J.; Park, E. Taisoo; Randall, Robert E.; Slowey, J. Frank

    1981-01-01

    On March 10, 1980, the Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging the resulting brine into the coastal waters off Freeport, Texas. During the months of March and April, a team of scientists and engineers from Texas A and M University conducted an intensive environmental study of the area surrounding the diffuser site. A pipeline has been laid from the Bryan Mound site to a location 12.5 statute miles (20 km) offshore. The last 3060 ft (933 m) of this pipeline is a 52-port diffuser through which brine can be discharged at a maximum rate of 680,000 barrels per day. Initially, 16 ports were open which permitted a maximum discharge rate of 350,000 barrels per day and a continuous brine discharge was achieved on March 13, 1980. The purpose of this report is to describe the findings of the project team during the intensive postdisposal study period of March and April, 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management.

  2. Environmental assessment of the brine pipeline replacement for the Strategic Petroleum Reserve Bryan Mound Facility in Brazoria County, Texas

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0804, for the proposed replacement of a deteriorated brine disposal pipeline from the Strategic Petroleum Reserve (SPR) Bryan Mound storage facility in Brazoria County, Texas, into the Gulf of Mexico. In addition, the ocean discharge outfall would be moved shoreward by locating the brine diffuser at the end of the pipeline 3.5 miles offshore at a minimum depth of 30 feet. The action would occur in a floodplain and wetlands; therefore, a floodplain/wetlands assessment has been prepared in conjunction with this EA. Based on the analyses in the EA, DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969 (42 USC. 4321, et seg.). Therefore, the preparation of an Environmental Impact Statement (EIS) is not required, and the Department is issuing this Finding of No Significant Impact (FONSI). This FONSI also includes a Floodplain Statement of Findings in accordance with 10 CFR Part 1022.

  3. Sulphur Extraction at Bryan Mound

    SciTech Connect (OSTI)

    Kirby, Carolyn L; Lord, Anna C. Snider

    2015-08-01

    The Bryan Mound caprock was subjected to extens ive sulphur mining prior to the development of the Strategic Petroleum Reserve. Undoubtedl y, the mining has modified the caprock integrity. Cavern wells at Bryan Mound have been subject to a host of well integr ity concerns with many likely compromised by the cavernous capro ck, surrounding corrosive environment (H 2 SO 4 ), and associated elevated residual temperatures al l of which are a product of the mining activities. The intent of this study was to understand the sulphur mining process and how the mining has affected the stability of the caprock and how the compromised caprock has influenced the integrity of the cavern wells. After an extensiv e search to collect pert inent information through state agencies, literature sear ches, and the Sandia SPR librar y, a better understanding of the caprock can be inferred from the knowledge gaine d. Specifically, the discovery of the original ore reserve map goes a long way towards modeling caprock stability. In addition the gained knowledge of sulphur mining - subs idence, superheated corrosive wa ters, and caprock collapse - helps to better predict the post mi ning effects on wellbore integrity. This page intentionally left blank

  4. Evaluation of brine disposal from the Bryan Mound site of the Strategic Petroleum Reserve Program. Final report

    SciTech Connect (OSTI)

    Hann, R.W. Jr.; Randall, R.E.

    1980-12-01

    The purpose of this report is to describe the environmental conditions found by the principal investigators during the predisposal study conducted from September 1977 through February 1980 prior to the start of brine discharge in March 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management. Volume 1 describes the results of the predisposal study, and it is divided into eight chapters entitled: Physical Oceanography, Analysis of the Discharge Plume, Water and Sediment Quality, Nekton, Benthos, Zooplankton, Phytoplankton, and Data Management. Volume 2 consists of appendices which contain additional supporting data in the form of figures and tables.

  5. EIS-0001: Strategic Petroleum Reserve, Bryan Mound Salt Dome, Brazoria County, Texas

    Broader source: Energy.gov [DOE]

    The Strategic Petroleum Reserve prepared this SEIS to address the environmental impacts of construction and operation of two types of brine disposal systems and a new water supply system. This EIS supplements FES 76/77-6, Bryan Mound Storage Site.

  6. Bryan Mound SPR cavern 113 remedial leach stage 1 analysis. ...

    Office of Scientific and Technical Information (OSTI)

    Title: Bryan Mound SPR cavern 113 remedial leach stage 1 analysis. The U.S. Strategic Petroleum Reserve implemented the first stage of a leach plan in 2011-2012 to expand storage ...

  7. Strategic Petroleum Reserve (SPR) additional geologic site characterization studies, Bryan Mound Salt Dome, Texas

    SciTech Connect (OSTI)

    Neal, J.T.; Magorian, T.R.; Ahmad, S.

    1994-11-01

    This report revises the original report that was published in 1980. Some of the topics covered in the earlier report were provisional and it is now practicable to reexamine them using new or revised geotechnical data and that obtained from SPR cavern operations, which involves 16 new caverns. Revised structure maps and sections show interpretative differences as compared with the 1980 report and more definition in the dome shape and caprock structural contours, especially a major southeast-northwest trending anomalous zone. The original interpretation was of westward tilt of the dome, this revision shows a tilt to the southeast, consistent with other gravity and seismic data. This interpretation refines the evaluation of additional cavern space, by adding more salt buffer and allowing several more caverns. Additional storage space is constrained on this nearly full dome because of low-lying peripheral wetlands, but 60 MMBBL or more of additional volume could be gained in six or more new caverns. Subsidence values at Bryan Mound are among the lowest in the SPR system, averaging about 11 mm/yr (0.4 in/yr), but measurement and interpretation issues persist, as observed values are about the same as survey measurement accuracy. Periodic flooding is a continuing threat because of the coastal proximity and because peripheral portions of the site are at elevations less than 15 ft. This threat may increase slightly as future subsidence lowers the surface, but the amount is apt to be small. Caprock integrity may be affected by structural features, especially the faulting associated with anomalous zones. Injection wells have not been used extensively at Bryan Mound, but could be a practicable solution to future brine disposal needs. Environmental issues center on the areas of low elevation that are below 15 feet above mean sea level: the coastal proximity and lowland environment combined with the potential for flooding create conditions that require continuing surveillance.

  8. Conversion of the Bryan Mound geological site characterization reports to a three-dimensional model.

    SciTech Connect (OSTI)

    Stein, Joshua S.; Rautman, Christopher Arthur

    2005-04-01

    The Bryan Mound salt dome, located near Freeport, Texas, is home to one of four underground crude oil-storage facilities managed by the U. S. Department of Energy Strategic Petroleum Reserve (SPR) Program. Sandia National Laboratories, as the geotechnical advisor to the SPR, conducts site-characterization investigations and other longer-term geotechnical and engineering studies in support of the program. This report describes the conversion of two-dimensional geologic interpretations of the Bryan Mound site into three-dimensional geologic models. The new models include the geometry of the salt dome, the surrounding sedimentary units, mapped faults, and the 20 oil-storage caverns at the site. This work provides an internally consistent geologic model of the Bryan Mound site that can be used in support of future work.

  9. Offshore oceanographic and environmental monitoring services for the Strategic Petroleum Reserve. Volume I. Appendices. Annual report for the Bryan Mound Site, September 1982-August 1983

    SciTech Connect (OSTI)

    1984-03-01

    The Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging brine into the coastal waters offshore of Freeport, Texas on March 10, 1980. This report describes the findings of a team of Texas A and M University scientists and engineers who have conducted a study to evaluate the effects of the Bryan Mound brine discharge on the marine environment. The study addresses the areas of physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos and data management. It focuses on the period from September 1982 through August 1983. The ambient physical environment and its temporal and spatial variability were studied by means of continuously recording in situ current/conductivitiy/temperature meters and twelve, one-day synoptic hydrographic cruises. The quarterly water and sediment quality data show a small increase in salinity, sodium and chloride ions occurs in the bottom waters and sediment pore waters near the diffuser relative to those values measured at stations farther away. Data from the brine plume study for this reporting study show the largest areal extent within the +1 o/oo above ambient salinity contour was 40.0 km/sup 2/ which occurred on August 11, 1983. It appears that brine disposal at Bryan Mound has had neglible if any influence on the nekton community surrounding the diffuser. The benthic quarterly data from 26 stations, including 7 collections made after the diffuser outflow rate was increased to 1,000,000 barrels/day, show the total numbers of species at the diffuser station were higher than most other nearfield stations as well as many farfield stations in both the pre- and post-1,000,000 barrels/day brine flow periods. 138 references, 175 figures, 53 tables.

  10. Chemistry and mineralogy of samples from the strategic petroleum reserve Bryan Mound site

    SciTech Connect (OSTI)

    Bild, R. W.

    1980-08-01

    The goal of the Strategic Petroleum Reserve (SPR) program is to protect the United States from a temporary cutoff of imported crude oil by stockpiling a reserve of oil in caverns in Gulf Coast salt domes. Some suitable caverns already exist as a result of solution mining activities by commercial mining companies. Most of the caverns for the program, however, will be solution mined specifically for the SPR program. The tasks assigned to Sandia National Laboratories include conducting a geotechnical program and providing interim technical support for the leaching of the first five caverns in the Bryan Mound, Texas, salt dome. This report describes chemical, mineralogical and petrological work done at Sandia as of May 1, 1980 in support of Bryan Mound activities. Samples of Bryan Mound salt cores, sidewall samples and drill cuttings have been subjected to chemical, mineralogical and petrographic analysis. Halite (NaCl) was the major mineral in all samples with anhydrite (CaSO/sub 4/) a common accessory. Minor or trace sylvite (KCl) and quartz (SiO/sub 2/) were detected in some sidewall samples. Other minor minerals found in drill cuttings included quartz; mixed carbonates of Fe, Ca and Mg; and several iron oxides. Possibly the carbonates are reaction products with the basic drilling mud or possibly pieces of caprock which contaminated the cuttings. The iron oxides were probably produced by corrosion of the drill stem or bit. Densities of several core samples were determined and insoluble residue was counted for radioactivity.

  11. Bryan Wheeler

    Broader source: Energy.gov [DOE]

    Bryan Wheeler was an intern in the Energy Department’s Office of Science in the summer of 2011. He is currently a student at Johns Hopkins University

  12. William Bryan, OE-30

    Broader source: Energy.gov [DOE]

    Mr. Bryan is the Deputy Assistant Secretary for Infrastructure Security and Energy Restoration in the U.S. Department of Energy's (DOE) Office of Electricity Delivery and Energy Reliability (OE...

  13. A. Lawrence Bryan, Jr.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Copia 1999:107-113. Van Den Bussche, R., S.A. Harlan, R.J. Baker, A.L. Bryan, Jr., J.A. ... and trophic transfer of trace metals within the Tims Branch-Steed Pond tributary. ...

  14. Bryan Fry | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bryan Fry Bryan Fry Bryan Fry Graduate Student E-mail: bryanfry@mail.med.upenn.edu Website: University of Pennsylvania Graduate...

  15. Bryan Hannegan | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bryan Hannegan About Us Bryan Hannegan - Associate Lab Director, Energy Systems Integration, at the National Renewable Energy Laboratory Most Recent Energy Systems Integration Facility Delivering on Promise to Strengthen America's Clean Energy Innovation September 11

  16. Rice, Bryan Joseph

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The (4)He(gamma,dd) reaction at E(gamma) = 150--250 MeV Rice, Bryan Joseph ProQuest Dissertations and Theses; 1998; ProQuest Dissertations & Theses (PQDT) pg. n/a Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with

  17. Paul Bryan | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bryan About Us Paul Bryan - Biomass Program Manager, Office of Energy Efficiency & Renewable Energy Paul Bryan is Program Manager for the Office of Energy Efficiency and Renewable Energy's Biomass Program. Most Recent Producing Clean, Renewable Diesel from Biomass November 30 The How's and Why's of Replacing the Whole Barrel October 19 Billion-Ton Update: Home-Grown Energy Resources Across the Nation August 1

  18. Bryan Mound SPR cavern 113 remedial leach stage 1 analysis. ...

    Office of Scientific and Technical Information (OSTI)

    sonar surveys in order to aid in the analysis and offer projections of likely outcomes ... Sponsoring Org: USDOE National Nuclear Security Administration (NNSA) Country of ...

  19. Lightning strike at Bryan, Ohio

    SciTech Connect (OSTI)

    Nichols, B. E.

    1980-02-01

    A week before the 29 August 1979 dedication of the photovoltaic power system at daytime AM radio station WBNO, in Bryan, Ohio, a lightning superbolt struck the FM radio tower, one of two towers at the station. Minor damage to the station and to components of the photovoltaic system, the latter designed by MIT Lincoln Laboratory under US Department of Energy sponsorship, is described. This rare strike suggested the need for increased protection and more voltage-transient suppressors were added to those already in place as a preventive measure in the event that such a phenomenon reoccurs.

  20. Bryan County, Georgia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Number 2 Climate Zone Subtype A. Places in Bryan County, Georgia Pembroke, Georgia Richmond Hill, Georgia Retrieved from "http:en.openei.orgwindex.php?titleBryanCounty,Ge...

  1. Bryan Texas Utilities- SmartHOME Program

    Broader source: Energy.gov [DOE]

    The Bryan Texas Utilities (BTU) SmartHOME Programs offers incentives to owners of single- and multi-family homes for insulation, windows, and solar screens.The incentive amount may not be less than...

  2. Larry Bryan | Savannah River Ecology Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bryan Curriculum Vitae Faculty & Scientists SREL Home Larry Bryan Savannah River Ecology Laboratory P O Drawer E, Aiken, SC 29802 (803) 725-2907 office (803) 725-3309 fax lbryan(at)srel.uga.edu Research interests: Vertebrate ecology, habitat use, potential threats from contamination, rare species conservation. Current Research: Mycteria americana (endangered wood stork) Tracking large-scale movements via satellite telemetry Foraging ecology, behavior, and trophic position Breeding success

  3. City of Bryan, Texas (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    Texas (Utility Company) Jump to: navigation, search Name: City of Bryan Place: Texas Phone Number: (979) 821-5700 Website: www.btutilities.com Twitter: @CityofBryan Facebook:...

  4. Mound History and Information

    Office of Legacy Management (LM)

    The 306 acre facility is sited on a hill in the center of Miamisburg, Ohio. Construction of the Mound Plant began in 1946, and the site became operational in 1949. Mound, the ...

  5. CX-009718: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Brine Disposal System Header to Bryan Mound Brine Tank, GFE CX(s) Applied: B1.3 Date: 12/11/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  6. Mound Supports Galileo

    SciTech Connect (OSTI)

    Monsanto Research Corporation

    1986-01-01

    This video describes the invention of Radioisotope Thermoelectric Generators (RTGs) at Mound Laboratory, and radioisotope heat source production from 1 watt-thermal to 2400 watts-thermal. RTGs have been used in many space vehicles, but the RTG built for the Galileo mission to orbit Jupiter is the largest. This RTG unit will produce 4400 watts-thermal and convert to 300 watts-electric. The plutonium-238 heat source assembly and test at Mound is described. The RTGs are tested under simulated mission conditions. The RTG leakage radiation is carefully measured for background compensation for on-board radiation monitoring instruments.

  7. Mound, Ohio, Site Fact Sheet

    Office of Legacy Management (LM)

    Mound, Ohio, Site This fact sheet provides information about the Mound, Ohio, Site. These sites are managed by the U.S. Department of Energy Office of Legacy Management under the Comprehensive Environmental Response, Compensation, and Liability Act. Location of the Mound, Ohio, Site Site Description and History The Mound site 1 in Miamisburg, Ohio, named for a nearby Native American burial ground, is located approximately 10 miles southwest of Dayton, Ohio. The Great Miami River fows southwest

  8. Mound publications for 1991

    SciTech Connect (OSTI)

    Nowka, Stephen L.

    1992-05-01

    This document is a compilation of all Mound formal technical publications and oral presentations for calendar year 1991. It is intended to serve as an aid to personnel in obtaining or referring to specific publications by giving the proper complete reference for each information item published during the year. Some items, such as proceedings publications, may have issue dates or periods of coverage prior to 1991; however, they were formally published during 1991.

  9. Mound facility physical characterization

    SciTech Connect (OSTI)

    Tonne, W.R.; Alexander, B.M.; Cage, M.R.; Hase, E.H.; Schmidt, M.J.; Schneider, J.E.; Slusher, W.; Todd, J.E.

    1993-12-01

    The purpose of this report is to provide a baseline physical characterization of Mound`s facilities as of September 1993. The baseline characterizations are to be used in the development of long-term future use strategy development for the Mound site. This document describes the current missions and alternative future use scenarios for each building. Current mission descriptions cover facility capabilities, physical resources required to support operations, current safety envelope and current status of facilities. Future use scenarios identify potential alternative future uses, facility modifications required for likely use, facility modifications of other uses, changes to safety envelope for the likely use, cleanup criteria for each future use scenario, and disposition of surplus equipment. This Introductory Chapter includes an Executive Summary that contains narrative on the Functional Unit Material Condition, Current Facility Status, Listing of Buildings, Space Plans, Summary of Maintenance Program and Repair Backlog, Environmental Restoration, and Decontamination and Decommissioning Programs. Under Section B, Site Description, is a brief listing of the Site PS Development, as well as Current Utility Sources. Section C contains Site Assumptions. A Maintenance Program Overview, as well as Current Deficiencies, is contained within the Maintenance Program Chapter.

  10. Monsanto MOUND FACILITY

    Office of Legacy Management (LM)

    Monsanto . MOUND FACILITY Operated for the United States Department of Energy March 26, 1981 Dr. William E. Mott, Director Environmental and Safety Engineering Division U. S. Department of Energy Washington, D. C. 20545 Dear Bill: Enclosed please find the short-term radon/radon progeny screening report conducted at the Seneca Army Depot in Romulus, New York per your request. If you have any questions or comments, please feel free to contact me. Sincerely, WGY:mls Enclosure cc: R. Barber w/encl

  11. CX-011223: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Brine Disposal Pump Replacement (Install) CX(s) Applied: B5.2 Date: 10/28/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  12. CX-010711: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Brine Disposal Pump Replacement CX(s) Applied: B5.2 Date: 07/03/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  13. EIS-0014: Mound Facility, Miamisburg, Ohio

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared this EIS to assess the environmental implications of its continuing and future programs at the Mound Facility (formerly designated Mound Laboratory), located in Miamisburg, Ohio.

  14. Viscous heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1984-07-10

    Hydroxyethyl cellulose and a sequestrant are added to a heavy brine containing one or more salts selected from calcium chloride, calcium bromide, and zinc bromide to increase the viscosity of the brine. Preferably the brine contains zinc bromide, has a density in the range from about 14.2-19.2 pounds per gallon, and the sequestrant is a polyphosphonic acid or water soluble salt thereof.

  15. DOE - Office of Legacy Management -- Mound Site

    Office of Legacy Management (LM)

    Ohio Mound, Ohio, Site A CERCLA and/or RCRA Site Mound2014 Remediation of the Mound, Ohio, Site was conducted in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). The site long-term monitoring responsibility transferred to the Office of Legacy Management(LM) in 2010 and requires operation and maintenance of a pump and treatment system, groundwater monitoring, institutional controls monitoring, records-related activities, and stakeholder support.

  16. Microsoft Word - 20110322_MoundNotice.docx

    Office of Legacy Management (LM)

    Legal Notice for Mound Site 2011 CERCLA Five-Year Review has been removed from the LM website. This document is outdated and no longer neededrequired...

  17. Thickened heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1983-12-13

    A thickened brine solution useful as a well servicing fluid is prepared, said solution consisting essentially of water, at least 20% by weight zinc bromide, calcium bromide, and a viscosifying amount of hydroxyethyl cellulose.

  18. Mound Site Community Involvement Plan 2012

    Office of Legacy Management (LM)

    Involvement Plan for the U.S. Department of Energy Mound, Ohio, Site January 2015 LMS/MND/S02885-0.0 This page intentionally left blank U.S. Department of Energy Mound Community Involvement Plan January 2015 Doc. No. S02885-0.0 Page i Contents Abbreviations .................................................................................................................................. ii 1.0 Purpose and Introduction

  19. Reindustrialization Workshop Held at Mound Site

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) has partnered with local communities to determine the best reuse of land, assets, and facilities, and the Mound-site community is no exception. In May, DOE’s...

  20. Brine stability study

    SciTech Connect (OSTI)

    Gary Garland

    2015-04-15

    This is a study of the brine formulations that we were using in our testing were stable over time. The data includes charts, as well as, all of the original data from the ICP-MS runs to complete this study.

  1. Enforcement Letter, EG&G Mound Applied Technologies- August 22, 1996

    Broader source: Energy.gov [DOE]

    Issued to EG&G Mound Applied Technologies related to the Inadvertent Transfer of Radiological Contamination at the Mound Plant

  2. City of Blue Mound, Kansas (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    Mound, Kansas (Utility Company) Jump to: navigation, search Name: City of Blue Mound Place: Kansas Phone Number: (913) 756-2447 Outage Hotline: (913) 756-2447 References: EIA Form...

  3. DOE - Office of Legacy Management -- Mound Laboratory - OH 19

    Office of Legacy Management (LM)

    Mound Laboratory - OH 19 FUSRAP Considered Sites Site: Mound Laboratory (OH.19) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Mound, Ohio, Site Documents Related to Mound Laboratory Workshop presentations emphasized the challenges of reindustrializing former DOE sites and the importance of involving local government and the community

  4. "Conflict Between Economic Growth and Environmental Protection", Dr. Bryan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Czech, resident, Center for the Advancement of the Steady State of the Economy | Princeton Plasma Physics Lab 9, 2012, 4:15pm Colloquia MBG Auditorium "Conflict Between Economic Growth and Environmental Protection", Dr. Bryan Czech, resident, Center for the Advancement of the Steady State of the Economy Presentation: Office presentation icon Presentation Abstract: PDF icon Abstract Conflict Between Economic Growth and Environmental Protectio Colloquium Committee: The Princeton

  5. Mound site environmental report for calendar year 1991

    SciTech Connect (OSTI)

    Bauer, L.R.

    1992-06-01

    Mound is a government-owned facility operated by EG&G Mound Applied Technologies for the U.S. Department of Energy (DOE). This integrated production, development, and research site performs work in support of DOE`s weapon and energy related programs, with emphasis on explosive, nuclear, and energy technology. The purpose of this report is to inform the public about the impact of Mound`s operations on the population and the environment. This report summarizes data from the Environmental Monitoring Program, through which Mound maintains continuous surveillance of radiological and nonradiological substances released from the facility.

  6. Independent technical review of the Mound Plant

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This report documents an Independent Technical Review (ITR) of the facilities, organizations, plans, and activities required to transition particular elements of the Mound Plant from Defense Program (DP) funded operation as appropriate either to community developed reuse or safe deactivation leading to decontamination and decommissioning (D&D). The review was conducted at the request of the Dr. Willis Bixby, Deputy Assistant Secretary, U.S. Department of Energy EM-60, Office of Facility Transition and Management and is a consensus of the nine member ITR Team. Information for the review was drawn from documents provided to the ITR Team by the Miamisburg Area Office (MB) of the DOE, EG&G, the City of Miamisburg, and others; and from presentations, discussions, interviews, and facility inspections at the Mound Plant during the weeks of March 14 and March 28, 1994. During the week of April 25, 1994, the ITR Team met at Los Alamos, New Mexico to develop consensus recommendations. A presentation of the core recommendations was made at the Mound Plant on May 5, 1994. This is an independent assessment of information available to, and used by, the Mound Plant personnel. Repetition of the information is not meant to imply discovery by the ITR Team. Team members, however, acting as independent reviewers, frequently assess the information from a perspective that differs significantly from that of the Mound Plant personnel. The report is based on information obtained and conditions observed during the March 1994 review interval. The ITR process and normal site work often initiate rapid, beneficial changes in understanding and organization immediately following the review. These changes frequently alter conditions observed during the review, but the report does not address changes subsequent to the review interval.

  7. Investigation of the September 13, 2011, Fatality at the Strategic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound Site Investigation of the September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound ...

  8. Mound site environmental report for calendar year 1992

    SciTech Connect (OSTI)

    Bauer, L.R.

    1993-07-01

    The purpose of this report is to inform the public about the impact of Mound operations on the population and the environment. Mound is a government-owned facility operated by EG&G Mound Applied Technologies for the US Department of Energy (DOE). This integrated production, development, and research site performs work in support of DOE`s weapon and energy related programs, with emphasis on explosive, nuclear and energy technologies.

  9. Miamisburg Mound Community Improvement Corp | Open Energy Information

    Open Energy Info (EERE)

    finances; Manufacturing; Research and development; Trainining and education;Other:Economic Development Phone Number: 937-865-4462 Website: www.mound.com...

  10. Renewed Importance of the Mound Site Annual Institutional Controls...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual, routine IC inspections are conducted at many LM sites. However, inspections at the Mound site are anything but routine, due to its unique nature. 1862.jpg Collaboration ...

  11. Mound Museum Volunteers: Preserving a Laboratory’s Legacy

    Broader source: Energy.gov [DOE]

    The Mound Science and Energy Museum (MSEM) owes its success to dedicated volunteers and supporters. The MSEM currently has 40 active volunteers and 200 dues-paying members.

  12. Enforcement Letter-Mound-08/22/1996

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy (DOE) by EG&G Mound (EG&G) in the Noncompliance Tracking System (NTS). ... We also reviewed your Contamination Control Review Team investigation report which ...

  13. Gas evolution from geopressured brines

    SciTech Connect (OSTI)

    Matthews, C.S.

    1980-06-01

    The process of gas evolution from geopressured brine is examined using as a basis the many past studies of gas evolution from liquids in porous media. A discussion of a number of speculations that have been made concerning gas evolution from geopressured brines is provided. According to one, rapid pressure reduction will cause methane gas to evolve as when one opens a champagne bottle. It has been further speculated that evolved methane gas would migrate up to form an easily producible cap. As a result of detailed analyses, it can be concluded that methane gas evolution from geopressured brines is far too small to ever form a connected gas saturation except very near to the producing well. Thus, no significant gas cap could ever form. Because of the very low solubility of methaned in brine, the process of methane gas evolution is not at all analogous to evolution of carbon dioxide from champagne. A number of other speculations and questions on gas evolution are analyzed, and procedures for completing wells and testing geopressured brine reservoirs are discussed, with the conclusion that presently used procedures will provide adequate data to enable a good evaluation of this resource.

  14. Brine Sampling and Evaluation Program, 1991 report

    SciTech Connect (OSTI)

    Deal, D.E.; Abitz, R.J.; Myers, J.; Martin, M.L.; Milligan, D.J.; Sobocinski, R.W.; Lipponer, P.P.J.; Belski, D.S.

    1993-09-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plan (WIPP) during 1991. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. When excavations began at the WIPP in 1982, small brine seepages (weeps) were observed on the walls. Brine studies began as part of the Site Validation Program and were formalized as a program in its own right in 1985. During nine years of observations (1982--1991), evidence has mounted that the amount of brine seeping into the WIPP excavations is limited, local, and only a small fraction of that required to produce hydrogen gas by corroding the metal in the waste drums and waste inventory. The data through 1990 is discussed in detail and summarized by Deal and others (1991). The data presented in this report describes progress made during the calendar year 1991 and focuses on four major areas: (1) quantification of the amount of brine seeping across vertical surfaces in the WIPP excavations (brine ``weeps); (2) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes; (3) further characterization of brine geochemistry; and (4) preliminary quantification of the amount of brine that might be released by squeezing the underconsolidated clays present in the Salado Formation.

  15. CX-000482: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Project Number MS-09-116 - Structural Assessment of Big Hill Raw Water Intake Structure, Big Hill Brine Disposal Pump Pad and Bryan Mound Raw Water Intake StructureCX(s) Applied: B1.3Date: 12/29/2009Location(s): TexasOffice(s): Fossil Energy, Strategic Petroleum Reserve Field Office

  16. Environmental assessment for Mound Plant decontamination and decommissioning projects, Mound Plant, Miamisburg, Ohio

    SciTech Connect (OSTI)

    1995-05-01

    The U.S. Department of Energy (DOE) has prepared an Environmental Assessment (EA) for seven decontamination and decommissioning (D&D) projects at the Mound Plant in Miamisburg, Ohio, that have not been previously addressed in the Final Environmental Impact Statement for the Mound Facility (June 1979). Based on the information presented in the EA, the DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969. Therefore, the preparation of an Environmental Impact Statement (EIS) is not required and the Department is issuing this Finding of No Significant Impact (FONSI).

  17. Viscous heavy brine completion fluids. [Oil wells

    SciTech Connect (OSTI)

    Darlington, R.K.; Hunter, D.V.

    1982-01-01

    An activated hydroxyethyl cellulose (HEC) has been developed which will viscosify brines of any density up to 19.2 lb/gal containing calcium chloride, calcium bromide and/or zinc bromide. The use of activated hydroxyethyl cellulose allows preparation of viscosified brines at ambient emperature and without undissolved polymer solids. The time required to prepare a viscosified brine is greatly reduced. In addition, the rheology of brines viscosified with activated HEC can be accurately predicted allowing brines with equivalent solution rheology properties to be prepared batch after batch. 29 refs.

  18. Improved Water Flooding through Injection Brine Modification

    SciTech Connect (OSTI)

    Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman

    2003-01-01

    Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

  19. Blue Mounds, Wisconsin: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Blue Mounds is a village in Dane County, Wisconsin. It falls under Wisconsin's 2nd...

  20. Renewed Importance of the Mound Site Annual Institutional Controls Assessments

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) Office of Legacy Management (LM) completed its 2014 annual institutional controls (IC) assessment of the Mound site in Miamisburg, Ohio, and confirmed that the...

  1. EA-1239: Disposition of Mound Plant's South Property, Miamisburg, Ohio

    Broader source: Energy.gov [DOE]

    DOE prepared an EA for the proposed title transfer of 123 acres of land referred to as the “South Property” at the Miamisburg Environmental Management Project Mound Plant in Miamisburg, Ohio.

  2. EA-1001: Commercialization of the Mound Plant, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to commercialize surplus facilities such as the U.S. Department of Energy's Mound Plant in Miamisburg, Ohio.  Commercialization will make...

  3. Environmental assessment for commercialization of the Mound Plant

    SciTech Connect (OSTI)

    Not Available

    1994-10-26

    In November 1993 US DOE decided to phase out operations at the Mound Plant in Miamisburg, Ohio, with the goal of releasing the site for commercial use. The broad concept is to transform the plant into an advanced manufacturing center with the main focus on commercializing products and other technology. DOE proposes to lease portions of the Mound Plant to commercial enterprises. This Environmental Impact statement has a finding of no significant impact in reference to such action.

  4. Mounded LPG storage - Experience and developments

    SciTech Connect (OSTI)

    Barber, D.

    1988-01-01

    Liquefied petroleum gas (LPG) is stored after production, and for distribution and use, in pressure vessels which vary in size from a few kilogrammes to many thousands of tons. The types of LPG under consideration are commercial butane, commercial propane, or mixtures of the two gases in varying proportions. Mounded storage systems are becoming popular as an alternative to the better-known traditional systems. The most widely used and therefore best-known of the traditional systems are the above-ground pressure-vessel designs. These more commonly comprise factory-made cylinders which are installed horizontally, being supported on saddles at each end of the vessel. When such vessels are installed in an LPG terminal, depot, or filling plant, they are required in multiple units to facilitate the storage of more than one grade of product and to enable regular maintenance and inspection to be carried out. Today's safety regulations require such installations to be divided into sub-groups of six tanks, with all the tanks located at a safe distance from one another, and from other facilities in the immediate area. These safety distances are being increased as a result of experience, which means terminals now require large areas of land.

  5. Brine disposal process for Morcinek coal mine

    SciTech Connect (OSTI)

    Tait, J.H.

    1995-04-01

    This paper describes the work to develop a commercial brine disposal process for the Morcinek mine, located 45 km south of the city of Katowice in Poland. Currently, brine is discharged into the Odra river and methane from the mine is released into the atmosphere. The process would use the released methane and convert a large percentage of the brine into potable water for commercial use. Thus, the proposed process has two environmental benefits. The brine salinity is about 31,100 ppm. Major brine components are Na (10,300 ppm), Ca (1,170 ppm), Mg (460 ppm), Cl (18,500 ppm) and SO{sub 4}{sup 2-} (252 ppm). Present in smaller amounts are K, S, Sr, B, Ba and NO{sub 3}. The process integrates a reverse osmosis (RO) unit and a submerged combustion evaporator. Extensive studies made at the Lawrence Livermore National Laboratory established the pretreatment method of the brine before it enters the RO unit. Without adequate pretreatment, mineral phases in the brine would become super-saturated and would precipitate in the RO unit. The pretreatment consists of first adding sodium carbonate to increase both the pH and the carbonate concentration of the brine. This addition causes precipitation of carbonate solids containing Ca, Mg, Sr, and Ba. After filtration of these precipitates, the fluid is acidified with HCl to prevent precipitation in the RO unit as the brine increases in salinity.

  6. Brine Migration Experimental Studies for Salt Repositories

    Broader source: Energy.gov [DOE]

    Experiments were used to examine water content in Permian salt samples including impact of variation in thermal regime on water content of evaporites and other mineral species, behavior of brine inclusions in salt, and evolution of the gas/liquid brine/salt system.

  7. Modeling acid-gas generation from boiling chloride brines (Journal...

    Office of Scientific and Technical Information (OSTI)

    Modeling acid-gas generation from boiling chloride brines Citation Details In-Document Search Title: Modeling acid-gas generation from boiling chloride brines This study ...

  8. Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide, Brine, and Clay ...

  9. Summary Results for Brine Migration Modeling Performed by LANL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program Summary Results for Brine Migration Modeling Performed by LANL, LBNL and ...

  10. TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems...

    Office of Scientific and Technical Information (OSTI)

    Title: TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems Deep saline formations and oil and gas reservoirs often contain concentrated brine solutions of ionic ...

  11. Raft River Geothermal Field Well Head Brine Sample

    SciTech Connect (OSTI)

    Tim Lanyk

    2015-12-18

    Raw data and data workup of assay for real-world brine sample. Brine sample was taken at the well head.

  12. Environmental survey preliminary report, Mound Plant, Miamisburg, Ohio

    SciTech Connect (OSTI)

    Not Available

    1987-03-01

    This report presents the preliminary findings from the first phase of the Environmental Survey of the United States Department of Energy (DOE) Mound Plant, conducted August 18 through 29, 1986. The objective of the Survey is to identify environmental problems and areas of environmental risk associated with the Mound Plant. The Survey covers all environmental media and all areas of environmental regulation. It is being performed in accordance with the DOE Environmental Survey Manual. The on-site phase of the Survey involves the review of existing site environmental data, observations of the operations carried on at the Mound Plant, and interviews with site personnel. The Survey found no environmental problems at the Mound Plant that represent an immediate threat to human life. The environmental problems identified at the Mound Plant by the Survey confirm that the site is confronted with a number of environmental problems which are by and large a legacy from past practices at a time when environmental problems were less well understood. Theses problems vary in terms of their magnitude and risk, as described in this report. Although the sampling and analysis performed by the Mound Plant Survey will assist in further identifying environmental problems at the site, a complete understanding of the significance of some of the environmental problems identified requires a level of study and characterization that is beyond the scope of the Survey. Actions currently under way or planned at the site, particularly the Phase II activities of the Comprehensive Environmental Analysis and Response Program (CEARP) as developed and implemented by the Albuquerque Operations Office, will contribute toward meeting this requirement. 85 refs., 24 figs., 20 tabs.

  13. Test fire environmental testing operations at Mound Applied Technologies

    SciTech Connect (OSTI)

    1992-03-01

    This paper describes Mound Laboratory`s environmental testing operations. The function of environmental testing is to perform quality environmental (thermal, mechanical, spin, resistance, visual) testing/conditioning of inert/explosive products to assure their compliance with specified customer acceptance criteria. Capabilities, organization, equipment specifications, and test facilities are summarized.

  14. How temperature and pressure affect clear brines

    SciTech Connect (OSTI)

    Hubbard, J.T.

    1984-04-01

    The correct application of the expansivity and compressibility of brine fluids under the influence of temperature and pressure is needed to calculate the actual hydrostatic pressure in a well. Well operations can benefit by reducing unintentional overbalance, lessening fluid losses, and lowering recommended fluid densities, hence reducing fluid costs. Since the early 1970s, the effects of temperature and pressure on the density of clear brine fluids have been questioned. As early as 1973, studies were started to define density loss with increased temperature in zinc bromide brines. This article describes a continuing study, begun in 1978, which has characterized the expansivity and compressibility of single salt brine solutions, such as are used in workover and completion fluids.

  15. Property:BrineConstituents | Open Energy Information

    Open Energy Info (EERE)

    Chloride type brine, "The content of potassium and calcium are high, while that of lithium, boron and sulfate is very low", See table 1 of Izquierdo et al. (2006). + Chena...

  16. Integrated process for coalbed brine disposal

    SciTech Connect (OSTI)

    Brandt, H. |; Bourcier, W.L.; Jackson, K.J.

    1994-03-01

    A brine disposal process is described that converts the brine stream of a coalbed gas producing site into clean water for agricultural use, combustion products and water vapor that can be released into the atmosphere and dry solids that can be recycled for industrial consumption. The process uses a reverse osmosis unit, a submerged combustion evaporator and a pulse combustion dryer. Pretreatment of the brine feedstream is necessary to prevent fouling of the membranes of the reverse osmosis unit and to separate from the brine stream hazardous metal and other constituents that may make the permeate from the reverse osmosis unit unsuitable for agricultural or other use. A chemical modeling code is used to calculate the saturation states of solids that may precipitate and foul the reverse osmosis membranes. Sodium carbonate is added to the brine to precipitate carbonates of Ba, Ca, Mg and Sr prior to filtration, acidification, and passage into the reverse osmosis unit. Optimization of the process in terms of types and amounts of additives is possible with analysis using the modeling code. The minimum amounts of additives to prevent scaling are calculated. In a typical operation, a brine feedstream of 1,000 m{sup 3}/day (6,290 bpd) that may have a total dissolved salt concentration (TDS) of 7,000 ppm will be separated into a permeate stream of 750 m{sup 3}/day (4,718 bpd) with a TDS of 400 ppm and a concentrated brine stream of 250 m{sup 3}/day (1,573 bpd) with a TDS of 26,800 ppm. The submerged combustion evaporator will concentrate this latter stream to a concentration of 268,000 ppm and reduce the volume to 25 m{sup 3}/day (158 bpd). The pulse combustion dryer can dry the concentrated brine mixture to a low moisture salt. Energy costs to operate the reverse osmosis unit are primarily the pumping costs.

  17. Hydrocarbon content of geopressured brines. Final report

    SciTech Connect (OSTI)

    Osif, T.L.

    1985-08-01

    Design Well data (bottomhole pressure minus wellhead pressure, GWR, and hydrocarbon composition) is presented as a function of producing conditions. These are examined in conjunction with the following models to attempt to deduce the reservoir brine saturation level: (1) reservoir contains gas dispersed in the pores and the gas saturation is greater than critical; (2) reservoir brine is gas-saturated; (3) bubble point below hydrostatic pressure; and (4) bubble point between hydrostatic pressure and reservoir pressure. 24 figs., 10 tabs. (ACR)

  18. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  19. Portable brine evaporator unit, process, and system

    DOE Patents [OSTI]

    Hart, Paul John; Miller, Bruce G.; Wincek, Ronald T.; Decker, Glenn E.; Johnson, David K.

    2009-04-07

    The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

  20. Audit of Shutdown and Transition of the Mound Plant, IG-0408 | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Shutdown and Transition of the Mound Plant, IG-0408 Audit of Shutdown and Transition of the Mound Plant, IG-0408 Audit of Shutdown and Transition of the Mound Plant, IG-0408 (68.17 KB) More Documents & Publications EIS-0302: Notice of Intent to Prepare an Environmental Impact Statement EIS-0302: Withdrawal of Notice of Intent to Prepare an Environmental Impact Statement Semiannual Report to Congress: April 1 - September 30, 1997

  1. Enforcement Letter, CH2M Hill Mound, Inc- December 22, 2004

    Broader source: Energy.gov [DOE]

    Issued to CH2M Hill Mound, Inc. related to a Radioactive Contamination Event during Remediation Activities at the Miamisburg Closure Project

  2. Strategic Petroleum Reserve | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Crude oil pipes at SPR Bryan Mound site near Freeport, TX. Crude oil pipes at SPR Bryan Mound site near Freeport, TX. The Strategic Petroleum Reserve (SPR) is the world's largest...

  3. CX-004344: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Replace Interior and Exterior Entryway to Building 201CX(s) Applied: B1.3Date: 10/13/2010Location(s): Bryan Mound, TexasOffice(s): Fossil Energy, Strategic Petroleum Reserve Field Office

  4. Method of removing benzene from petroleum desalter brine

    SciTech Connect (OSTI)

    Hart, P.R.

    1993-08-17

    A method is described for removing benzene from petroleum refinery desalter effluent brine containing dispersed oil, solids, oily solids and benzene comprising contacting the brine with a sufficient amount for the purpose of flocculating oily solids of a combination of a aluminum chlorohydrate and a water soluble cationic polymer selected from the group consisting of polyamines and dialkyldiallylammonium polymers, in a ratio of from 1:10 to 100:1 at a temperature of about 250 F, separating the resulting floc from the brine; and thereafter contacting the brine with a sufficient amount for the purpose of reducing benzene levels in the brine of an oil solvent in combination with a demulsifier.

  5. Investigation of the September 13, 2011, Fatality at the Strategic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Reserve Bryan Mound Site | Department of Energy September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound Site Investigation of the September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound Site November 2011 On September 13, 2011, a recently-hired, untrained subcontractor employee struck three large elevated pipes while operating a front deck mower at the Cavern 5 area of the Strategic Petroleum Reserve Bryan Mound (SPR-BM) site. The employee

  6. Characteristics and origin of Earth-mounds on the Eastern Snake River Plain, Idaho

    SciTech Connect (OSTI)

    Tullis, J.A.

    1995-09-01

    Earth-mounds are common features on the Eastern Snake River Plain, Idaho. The mounds are typically round or oval in plan view, <0.5 m in height, and from 8 to 14 m in diameter. They are found on flat and sloped surfaces, and appear less frequently in lowland areas. The mounds have formed on deposits of multiple sedimentary environments. Those studied included alluvial gravel terraces along the Big Lost River (late Pleistocene/early Holocene age), alluvial fan segments on the flanks of the Lost River Range (Bull Lake and Pinedale age equivalents), and loess/slopewash sediments overlying basalt flows. Backhoe trenches were dug to allow characterization of stratigraphy and soil development. Each mound has features unique to the depositional and pedogenic history of the site; however, there are common elements to all mounds that are linked to the history of mound formation. Each mound has a {open_quotes}floor{close_quotes} of a sediment or basement rock of significantly different hydraulic conductivity than the overlying sediment. These paleosurfaces are overlain by finer-grained sediments, typically loess or flood-overbank deposits. Mounds formed in environments where a sufficient thickness of fine-grained sediment held pore water in a system open to the migration to a freezing front. Heaving of the sediment occurred by the growth of ice lenses. Mound formation occurred at the end of the Late Pleistocene or early in the Holocene, and was followed by pedogenesis. Soils in the mounds were subsequently altered by bioturbation, buried by eolian deposition, and eroded by slopewash runoff. These secondary processes played a significant role in maintaining or increasing the mound/intermound relief.

  7. Expected brine movement at potential nuclear waste repository salt sites

    SciTech Connect (OSTI)

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

  8. EIS-0075: Strategic Petroleum Reserve Phase III Development, Texoma and Seaway Group Salt Domes (West Hackberry and Bryan Mound Expansion, Big Hill Development) Cameron Parish, Louisiana, and Brazoria and Jefferson Counties, Texas

    Broader source: Energy.gov [DOE]

    Also see EIS-0021 and EIS-0029. The Strategic Petroleum Reserve (SPR) Office developed this EIS to assess the environmental impacts of expanding the existing SPR storage capacity from 538 million to 750 million barrels of storage and increasing the drawdown capability from 3.5 million to 4.5 million barrels per day. This EIS incorperates two previously issued EISs: DOE/EIS-0021, Seaway Group of Salt Domes, and DOE/EIS-0029, Texoma Group of Salt Domes.

  9. Overview of surface studies on high energy materials at Mound

    SciTech Connect (OSTI)

    Moddeman, W.E.; Collins, L.W.; Wang, P.S.; Haws, L.D.; Wittberg, T.N.

    1980-01-01

    Since 1975 Mound has been examining the surface structure of high energy materials and the interaction of these materials with various metal containers. The high energy materials that have been studied include: the pyrotechnic TiH/sub x//KClO/sub 4/, the Al/Cu/sub 2/O machinable thermite, the PETN, HMX and RDX explosives, and two plastic bonded explosives (PBX). Aluminum and alloys of Fe, Ni and Cr have been used as the containment materials. Two aims in this research are: (1) the elucidation of the mechanism of pyrotechnic ignition and (2) the compatibility of high energy materials with their surroundings. New information has been generated by coupling Auger electron spectroscopy (AES) and x-ray photoelectron spectroscopy (XPS) with thermal data. In particular, AES and XPS studies on the pyrotechnic materials and on thermites have shown the mechanism of ignition to be nearly independent of the type of oxidizer present but directly related to surface chemistry of the fuels. In studies on the two PBX's, PBX-9407 and LX-16, it was concluded that the Exon coating on 9407 was complete and greater than or equal to 100A; whereas in LX-16, the coating was < 100A or even incomplete. AES and scanning Auger have been used to characterize the surface composition and oxide thickness for an iron-nickel alloy and showed the thicker oxides to have the least propensity for atmospheric hydrocarbon adsorption. Data are presented and illustrations made which highlight this new approach to studying ignition and compatibility of high energy materials. Finally, the salient features of the X-SAM-800 purchased by Mound are discussed in light of future studies on high energy materials.

  10. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon ...

  11. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide ...

  12. Fate of Magnesium Chloride Brine Applied to Suppress Dust from...

    Office of Scientific and Technical Information (OSTI)

    Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests ...

  13. LEGAL NOTICE for Mound Site 2016 CERCLA Five-Year Review

    Office of Legacy Management (LM)

    Page 1 of 2 LEGAL NOTICE for Mound Site 2016 CERCLA Five-Year Review The U.S. Department of Energy (DOE) Office of Legacy Management (LM) is conducting the fourth Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Five-Year Review of the Mound Site in Miamisburg, Ohio. The Five-Year Review process ensures that the selected CERCLA remedies remain protective of human health and the environment. After the Mound Plant Site was placed on the CERCLA National Priority List

  14. Origin, distribution, and movement of brine in the Permian Basin (U. S. A. ). A model for displacement of connate brine

    SciTech Connect (OSTI)

    Bein, A.; Dutton, A.R. )

    1993-06-01

    Na-Cl, halite Ca-Cl, and gypsum Ca-Cl brines with salinities from 45 to >300 g/L are identified and mapped in four hydrostratigraphic units in the Permian Basin area beneath western Texas and Oklahoma and eastern New Mexico, providing spatial and lithologic constraints on the interpretation of the origin and movement of brine. Na-Cl brine is derived from meteoric water as young as 5-10 Ma that dissolved anhydrite and halite, whereas Ca-Cl brine is interpreted to be ancient, modified-connate Permian brine that now is mixing with, and being displaced by, the Na-Cl brine. Displacement fronts appear as broad mixing zones with no significant salinity gradients. Evolution of Ca-Cl brine composition from ideal evaporated sea water is attributed to dolomitization and syndepositional recycling of halite and bittern salts by intermittent influx of fresh water and sea water. Halite Ca-Cl brine in the evaporite section in the northern part of the basin differs from gypsum Ca-Cl brine in the south-central part in salinity and Na/Cl ratio and reflects segregation between halite- and gypsum-precipitating lagoons during the Permian. Ca-Cl brine moved downward through the evaporite section into the underlying Lower Permian and Pennsylvanian marine section that is now the deep-basin brine aquifer, mixing there with pre-existing sea water. Buoyancy-driven convection of brine dominated local flow for most of basin history, with regional advection governed by topographically related forces dominant only for the past 5 to 10 Ma. 71 refs., 11 figs.

  15. Reduce completion fluid costs with on-site brine tests

    SciTech Connect (OSTI)

    Thomas, D.C.; Darlington, R.K.; Kinney, W.R.; Lowell, J.L.

    1982-09-01

    A newly developed field kit makes on-site brine completion fluid testing practical. Simple titration procedures are used to analyze brine for calcium, zinc, chloride and bromide with an accuracy and repeatability that compares favorably with expensive laboratory techniques. This article describes the field testing theory and details analytical procedures used.

  16. Earth-mounded concrete bunker PLAP technical approach

    SciTech Connect (OSTI)

    Eng, R.

    1989-11-01

    Under the US DOE Prototype License Application Project (PLAP), Ebasco Services Incorporated was commissioned to develop a preliminary design of the Earth-Mounded Concrete Bunker (EMCB) concept for low-level radioactive waste (LLW) disposal. The EMCB disposal concept is of great interest because it represents the only engineered LLW disposal technology currently in use in the commercial sector. By definition, the EMCB disposal structure is located partially below grade and partially above grade. The concrete bunker is an engineered structure designed to be structurally stable for the prerequisite time horizon. The basic design parameters of the disposal facility were stipulated by US DOE, a northeast site location, representative waste, 30 year operational life, and a 250,000 ft{sup 3}/year disposal capacity. The design was developed to satisfy only US NRC Part 61 disposal requirements, not individual state requirements that may go beyond Part 61 requirements. The technical safety analysis of the preliminary design was documented according to the format specifications of NUREG-1199, to the extent practicable with quite limited resources.

  17. Cost estimate for muddy water palladium production facility at Mound

    SciTech Connect (OSTI)

    McAdams, R.K.

    1988-11-30

    An economic feasibility study was performed on the ''Muddy Water'' low-chlorine content palladium powder production process developed by Mound. The total capital investment and total operating costs (dollars per gram) were determined for production batch sizes of 1--10 kg in 1-kg increments. The report includes a brief description of the Muddy Water process, the process flow diagram, and material balances for the various production batch sizes. Two types of facilities were evaluated--one for production of new, ''virgin'' palladium powder, and one for recycling existing material. The total capital investment for virgin facilities ranged from $600,000 --$1.3 million for production batch sizes of 1--10 kg, respectively. The range for recycle facilities was $1--$2.3 million. The total operating cost for 100% acceptable powder production in the virgin facilities ranged from $23 per gram for a 1-kg production batch size to $8 per gram for a 10-kg batch size. Similarly for recycle facilities, the total operating cost ranged from $34 per gram to $5 per gram. The total operating cost versus product acceptability (ranging from 50%--100% acceptability) was also evaluated for both virgin and recycle facilities. Because production sizes studied vary widely and because scale-up factors are unknown for batch sizes greater than 1 kg, all costs are ''order-of-magnitude'' estimates. All costs reported are in 1987 dollars.

  18. Radionuclide transport in sandstones with WIPP brine

    SciTech Connect (OSTI)

    Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

    1981-02-01

    Retardation factors (R) have been measured for the transport of /sup 3/H, /sup 95m/Tc, and /sup 85/Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for /sup 85/Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for /sup 85/Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta.

  19. Technique for thermodynamic crystallization temperature of brine fluids

    SciTech Connect (OSTI)

    Clark, D.E.; Hubbard, J.T.

    1983-03-01

    The application of high density solids free brine fluids has proven to be technically and economically successful in hydrocarbon completion and workover operations. The use of inorganic salts such as calcium chloride, calcium bromide, zinc bromide, and sodium bromide has contributed to the development of complex salt systems. As the density and complexity of these systems becomes more detailed, the requirement for proper fluid design becomes increasingly important. When a brine solution is cooled sufficiently, a temperature is reached where the solution will be saturated. A further decrease in temperature will result in the precipitation of salt from the solution. The temperature at which this transpires, provided no super-cooling occurs, is the crystallization point of the solution. A correctly formulated solids free brine should have the optimum crystallization point for the temperature conditions it will encounter. A recently developed semiautomatic procedure constructs a cooling curve plot of each brine tested. This cooling curve plot allows the determination of the super-cooling potential, the Thermodynamic Crystallization Temperature, and the Last Crystal To Dissolve Temperature. The device provides a permanent record of the cooling curve with repeatable accuracy, which assists in the development of error free brine formulation tables, brine density, and/or crystallization point adjustments, and brine analysis.

  20. Concentration of Actinides in Plant Mounds at Safety Test Nuclear Sites in Nevada

    SciTech Connect (OSTI)

    David S. Shafer; Jenna Gommes

    2008-09-15

    Plant mounds or blow-sand mounds are accumulations of soil particles and plant debris around large shrubs and are common features in deserts in the southwestern United States. Believed to be an important factor in their formation, the shrubs create surface roughness that causes wind-suspended particles to be deposited and resist further suspension. Shrub mounds occur in some plant communities on the Nevada Test Site, the Nevada Test and Training Range (NTTR), and Tonopah Test Range (TTR), including areas of surface soil contamination from past nuclear testing. In the 1970s as part of early studies to understand properties of actinides in the environment, the Nevada Applied Ecology Group (NAEG) examined the accumulation of isotopes of Pu, {sup 241}Am, and U in plant mounds at safety test sites. The NAEG studies found concentrations of these contaminants to be greater in shrub mounds than in the surrounding areas of desert pavement. For example, at Project 57 on the NTTR, it was estimated that 15 percent of the radionuclide inventory of the site was associated with shrub mounds, which accounted for 17 percent of the surface area of the site, a ratio of inventory to area of 0.85. At Clean Slate III at the TTR, 29 percent of the inventory was associated with approximately 32 percent of the site covered by shrub mounds, a ratio of 0.91. While the total inventory of radionuclides in intershrub areas was greater, the ratio of radionuclide inventory to area was 0.40 and 0.38, respectively, at the two sites. The comparison between the shrub mounds and adjacent desert pavement areas was made for only the top 5 cm since radionuclides at safety test sites are concentrated in the top 5 cm of intershrub areas. Not accounting for radionuclides associated with the shrub mounds would cause the inventory of contaminants and potential exposure to be underestimated. As part of its Environmental Restoration Soils Subproject, the U.S. Department of Energy (DOE), National Nuclear

  1. Office of Inspector General report on audit of shutdown and transition of the Mound Plant

    SciTech Connect (OSTI)

    1997-06-24

    With the end of the Cold War, the Department of Energy (Department) has greatly reduced the production of nuclear weapons and redirected the capabilities and focus of the weapons complex. As part of this redirection, the Mound Plant was transferred from a Defense Program site to an Environmental Management site with emphasis on accelerated cleanup and transition of facilities and personal property to the local community. This audit was initiated to determine if the shutdown and transition of the Mound Plant was progressing effectively and efficiently. The Department prepared a Nonnuclear Consolidation Plan (NCP) designed to reduce its costs of operation by closing and consolidating facilities. In contrast to the goal of the NCP, the Department plans to keep a portion of the Mound Plant open solely to perform work for other Federal agencies. Specifically, the Department has decided to continue assembling and testing isotopic heat sources and radioisotope thermoelectric generators (HS/RTG) at the Mound Plant despite the transfer or planned transfer of all other production operations.The Office of Nuclear Energy, Science and Technology decided to continue its HS/RTG operations at the Mound Plant without adequately considering the overall economic goals of the Department. As a result, the Department may not achieve the savings envisioned by the NCP. Also, the Department may incur between $4 million and $8.5 million more than necessary each year to continue its HS/RTG operations at the Mound Plant. Additionally, if the HS/RTG operations stay at the Mound Plant, the Department will spend more than $3 million to consolidate these operations into one location.

  2. Formate brines -- New fluids for drilling and completions

    SciTech Connect (OSTI)

    Ramsey, M.S.; Shipp, J.A.

    1996-01-01

    The term ``formate brines`` refers broadly to three primary compounds dissolved in water -- sodium formate (NaCOOH), potassium formate (KCOOH) and cesium formate (CsCOOH). Each is chemically classified as an alkali-metal salt of formic acid. They offer properties that in many respects are superior to their predecessors, halide brines such as zinc bromide and calcium bromide, without the undesirable side effects of those more common halide brine systems. This article introduces the technology and provides an overview of published work to date regarding formates.

  3. Environmental assessment and planning at Mound - environmental monitoring capabilities and personnel profiles

    SciTech Connect (OSTI)

    1996-07-01

    Through its long experience with radioactive materials, Mound has developed a comprehensive, routine, offsite, environmental surveillance program to safeguard its employees, the physical plant, and the integrity of the surrounding environment from any potential adverse effects of its widely diverse operations. Effluent samples are analyzed for radiological and non-radiological parameters. The environment surrounding Mound Facility is continuously monitored - air, water, foodstuffs, vegetation, soil, and silt samples are analyzed to ensure that radioisotopic concentrations and other possible pollutants are well within the stringent standards adopted by the Department of Energy, the Environmental Protection Agencies (both federal and state), and various regional and local agencies. Moreover, this environmental surveillance program has been designed to ensure that the facility is designed, constructed, managed, operated, and maintained in a manner that continues to meet all federal, state, and local standards for environmental protection. Work in environmental science has been broadened to assess environmental factors associated with various aspects of the National Energy Plan. Both the management and staff at Mound have undertaken a firm commitment to make Mound`s environmental monitoring capabilities available to agencies that have the responsibility for the resolution of important environmental issues.

  4. From Hydrogen Fuel Cells to High-Altitude-Pilot Protection Suits— Mound Science and Energy Museum Programs Cover a Wide Range of Topics

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Mound Science and Energy Museum (MSEM) is an active, volunteer-led organization located at the former U.S. Department of Energy (DOE) Mound site in Miamisburg, Ohio. MSEM keeps the 60-year...

  5. Overview of the earth mounded concrete bunker prototype license application project: Objectives and approach

    SciTech Connect (OSTI)

    Conner, J.E.

    1989-11-01

    This paper presents an overview of the objectives and approach taken in developing the Earth-mounded Concrete Bunker Prototype License Application Project. The Prototype License Application Project was initiated by the Department of Energy`s National Low-Level Waste Management Program in early 1987 and completed in November 1988. As part of this project a prototype safety analysis report was developed. The safety analysis report evaluates the licensibility of an earth-mounded concrete bunker for a low-level radioactive waste (LLW) disposal facility located on a hypothetical site in the northeastern United States. The project required approximately five person-years and twenty months to develop.

  6. Marketing research for EE G Mound Applied Technologies' heat treatment process of high strength materials

    SciTech Connect (OSTI)

    Shackson, R.H.

    1991-10-09

    This report summarizes research conducted by ITI to evaluate the commercialization potential of EG G Mound Applied Technologies' heat treatment process of high strength materials. The remainder of the report describes the nature of demand for maraging steel, extent of demand, competitors, environmental trends, technology life cycle, industry structure, and conclusion. (JL)

  7. Actinide (III) solubility in WIPP Brine: data summary and recommendations

    SciTech Connect (OSTI)

    Borkowski, Marian; Lucchini, Jean-Francois; Richmann, Michael K.; Reed, Donald T.

    2009-09-01

    The solubility of actinides in the +3 oxidation state is an important input into the Waste Isolation Pilot Plant (WIPP) performance assessment (PA) models that calculate potential actinide release from the WIPP repository. In this context, the solubility of neodymium(III) was determined as a function of pH, carbonate concentration, and WIPP brine composition. Additionally, we conducted a literature review on the solubility of +3 actinides under WIPP-related conditions. Neodymium(III) was used as a redox-invariant analog for the +3 oxidation state of americium and plutonium, which is the oxidation state that accounts for over 90% of the potential release from the WIPP through the dissolved brine release (DBR) mechanism, based on current WIPP performance assessment assumptions. These solubility data extend past studies to brine compositions that are more WIPP-relevant and cover a broader range of experimental conditions than past studies.

  8. Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential...

    Office of Environmental Management (EM)

    Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential August 21, 2013 - 12:00am Addthis Utilizing a 1...

  9. Brine pH Modification Scale Control Technology. 2. A Review.pdf...

    Open Energy Info (EERE)

    Brine pH Modification Scale Control Technology. 2. A Review.pdf Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Brine pH Modification Scale...

  10. Uranium (VI) solubility in carbonate-free ERDA-6 brine

    SciTech Connect (OSTI)

    Lucchini, Jean-francois; Khaing, Hnin; Reed, Donald T

    2010-01-01

    When present, uranium is usually an element of importance in a nuclear waste repository. In the Waste Isolation Pilot Plant (WIPP), uranium is the most prevalent actinide component by mass, with about 647 metric tons to be placed in the repository. Therefore, the chemistry of uranium, and especially its solubility in the WIPP conditions, needs to be well determined. Long-term experiments were performed to measure the solubility of uranium (VI) in carbonate-free ERDA-6 brine, a simulated WIPP brine, at pC{sub H+} values between 8 and 12.5. These data, obtained from the over-saturation approach, were the first repository-relevant data for the VI actinide oxidation state. The solubility trends observed pointed towards low uranium solubility in WIPP brines and a lack of amphotericity. At the expected pC{sub H+} in the WIPP ({approx} 9.5), measured uranium solubility approached 10{sup -7} M. The objective of these experiments was to establish a baseline solubility to further investigate the effects of carbonate complexation on uranium solubility in WIPP brines.

  11. Durability of concrete materials in high-magnesium brine

    SciTech Connect (OSTI)

    Wakeley, L.D.; Poole, T.S.; Burkes, J.P.

    1994-03-01

    Cement pastes and mortars representing 11 combinations of candidate concrete materials were cast in the laboratory and monitored for susceptibility to chemical deterioration in high-magnesium brine. Mixtures were selected to include materials included in the current leading candidate concrete for seals at the Waste Isolation Pilot Plant (WIPP). Some materials were included in the experimental matrix to answer questions that had arisen during study of the concrete used for construction of the liner of the WIPP waste-handling shaft. Mixture combinations compared Class C and Class F fly ashes, presence or absence of an expansive component, and presence or absence of salt as a mixture component. Experimental conditions exposed the pastes and mortars to extreme conditions, those being very high levels of Mg ion and an effectively unlimited supply of brine. All pastes and mortars showed deterioration with brine exposure. In general, mortars deteriorated more extensively than the corresponding pastes. Two-inch cube specimens of mortar were not uniformly deteriorated, but showed obvious zoning even after a year in the brine, with a relatively unreacted zone remaining at the center of each cube. Loss of calcium from the calcium hydroxide of paste/aggregate interfaces caused measurable strength loss in the reacted zone comprising the outer portion of every mortar specimen. The current candidate mass concrete for WIPP seals includes salt as an initial component, and has a relatively closed initial microstructure. Both of these features contribute to its suitability for use in large placements within the Salado Formation.

  12. EIS-0302: Transfer of the Heat Source/Radioisotope Thermoelectric Generator Assembly and Test Operations From the Mound Site

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposed transfer of the Heat Source/Radioisotope Thermoelectric Generator (HS/RTG) operations at the Mound Site near Miamisburg, Ohio, to an alternative DOE site.

  13. Independent Review of the July 8, 2010 Fatality at the Strategic Petroleum

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reserve Bryan Mound Site - May 25, 2011 Addendum closing the Investigation based upon the Galveston County Medical Examiner's Report | Department of Energy Independent Review of the July 8, 2010 Fatality at the Strategic Petroleum Reserve Bryan Mound Site - May 25, 2011 Addendum closing the Investigation based upon the Galveston County Medical Examiner's Report Independent Review of the July 8, 2010 Fatality at the Strategic Petroleum Reserve Bryan Mound Site - May 25, 2011 Addendum closing

  14. Progress on radiometric dating of Wolfcamp brines using /sup 4/He and /sup 40/Ar

    SciTech Connect (OSTI)

    Zaikowski, A.; Kosanke, B.J.; Hubbard, N.

    1984-01-01

    Ground water samples (brines) from deep wells in the Palo Duro Basin, Texas are being analyzed for noble gases in an attempt to obtain radiometric ages for these brines. The brines contain radiogenic /sup 4/He and /sup 40/Ar produced from the radioactive decay of U, Th, and K. Consideration of hydrochemical data for the brines, various isotopic, chemical, and mineralogical data for the aquifer rocks and noble gas production rates allow estimating the age of the brines to be about 130 million years at two wells. At a third well interaquifer mixing has occurred and the age is presently indeterminate. 9 references, 3 figures, 1 table.

  15. Pre-operational safety appraisal Tritiated Scrap Recovery Facility, Mound facility

    SciTech Connect (OSTI)

    Dauby, J.J.; Flanagan, T.M.; Metcalf, L.W.; Rhinehammer, T.B.

    1996-07-01

    The purpose of this report is to identify, assess, and document the hazards which are associated with the proposed operation of the Tritiated Scrap Recovery Facility at Mound Facility. A Pre-operational Safety Appraisal is a requirement as stated in Department of Energy Order 5481.1, Safety Analysis and Review System. The operations to be conducted in the new Tritiated Scrap Waste Recovery Facility are not new, but a continuation of a prime mission of Mound`s i.e. recovery of tritium from waste produced throughout the DOE complex. The new facility is a replacement of an existing process started in the early 1960`s and incorporates numerous design changes to enhance personnel and environmental safety. This report also documents the safety of a one time operation involving the recovery of tritium from material obtained by the Department of Energy from the State of Arizona. This project will involve the processing of 240,000 curies of tritium contained in glass ampoules that were to be used in items such as luminous dial watches. These were manufactured by the now defunct American Atomics Corporation, Tucson, Arizona.

  16. Operating Experience Summary- 2012-02 – May 11, 2012

    Broader source: Energy.gov [DOE]

    Inside this issue: Improper Use of Dewar Carts Results in Serious Hand Injuries - Page 1 Strategic Petroleum Reserve Investigation Results - Fatality at the Bryan Mound Site - Page 5

  17. DEPARTMENT OF ENERGY Strategic Petroleum Reserve Annual Report

    Broader source: Energy.gov (indexed) [DOE]

    and planned projects for the Strategic Petroleum Reserve. ... Oil Inventory Status 18 Oil Acquisition Market ... 32 Bayou Choctaw Pipeline: 32 Bryan Mound Pipelines: 32 St. ...

  18. POTENTIAL IMPACT OF BLENDING RESIDUAL SOLIDS FROM TANKS 18/19 MOUNDS WITH TANK 7 OPERATIONS

    SciTech Connect (OSTI)

    Eibling, R; Erich Hansen, E; Bradley Pickenheim, B

    2007-03-29

    High level waste tanks 18F and 19F have residual mounds of waste which may require removal before the tanks can be closed. Conventional slurry pump technology, previously used for waste removal and tank cleaning, has been incapable of removing theses mounds from tanks 18F and 19F. A mechanical cleaning method has been identified that is potentially capable of removing and transferring the mound material to tank 7F for incorporation in a sludge batch for eventual disposal in high level waste glass by the Defense Waste Processing Facility. The Savannah River National Laboratory has been requested to evaluate whether the material transferred from tanks 18F/19F by the mechanical cleaning technology can later be suspended in Tank 7F by conventional slurry pumps after mixing with high level waste sludge. The proposed mechanical cleaning process for removing the waste mounds from tanks 18 and 19 may utilize a high pressure water jet-eductor that creates a vacuum to mobilize solids. The high pressure jet is also used to transport the suspended solids. The jet-eductor system will be mounted on a mechanical crawler for movement around the bottom of tanks 18 and 19. Based on physical chemical property testing of the jet-eductor system processed IE-95 zeolite and size-reduced IE-95 zeolite, the following conclusions were made: (1) The jet-eductor system processed zeolite has a mean and median particle size (volume basis) of 115.4 and 43.3 microns in water. Preferential settling of these large particles is likely. (2) The jet-eductor system processed zeolite rapidly generates settled solid yield stresses in excess of 11,000 Pascals in caustic supernates and will not be easily retrieved from Tank 7 with the existing slurry pump technology. (3) Settled size-reduced IE-95 zeolite (less than 38 microns) in caustic supernate does not generate yield stresses in excess of 600 Pascals in less than 30 days. (4) Preferential settling of size-reduced zeolite is a function of the amount of

  19. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect (OSTI)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  20. Pre-injection brine production for managing pressure in compartmentalized CO₂ storage reservoirs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO₂ storage that combines CO₂ injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO₂. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO₂ injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO₂ injection directly informs reservoir managers about CO₂ storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be usedmore » directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.« less

  1. Pre-injection brine production for managing pressure in compartmentalized CO₂ storage reservoirs

    SciTech Connect (OSTI)

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO₂ storage that combines CO₂ injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO₂. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO₂ injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO₂ injection directly informs reservoir managers about CO₂ storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be used directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.

  2. MLM-462 Contract Number AT-33-l-GtiN-53 MOUND LABORATCRY Operatsd By

    Office of Legacy Management (LM)

    This Doeumr;t Consists of 116 ?zges This is COPY of i.3 k MLM-462 Contract Number AT-33-l-GtiN-53 MOUND LABORATCRY Operatsd By MONSAmOC~ALGoMPANY MIAMISBURG, OHIO REPORT NO. 3 OF STIEUING CaW'M'B FOR DISPUSAL CF UNITS 111 AND IV (Completion Report for Disposal of UrLt IV, Runnymeade Road sr,d Dixon live. Dayton, Ohlo) . Date: April 17, 1950 Prepared By: -36L254- F. L. Halbach Chairnan., St33ricg Gcicmittes 1ssue.d: DISTRIHJTION copy 1. - Dr. Carroll A. Hochwalt copy 2. - Dr. M. M. Haring copy 3.

  3. The Mound site survey project for the characterization of radioactive materials in site soils

    SciTech Connect (OSTI)

    Stought, R.L.; Edling, D.A.; Draper, D.G.

    1988-05-16

    This report summarizes the results of a site survey project conducted at Monsanto Research Corporation's Mound Facility during 1982--1985. The objectives of the site survey were: To characterize the nineteen sites previously identified as having known levels of contamination; to identify and characterize by quantity and type of radionuclide(s) any additional major sites having levels of contamination exceeding 10 pCi/g (for Pu-238) of soil; to estimate the volume of contaminated soil; and to estimate the cost of stabilizing or removing the contaminated soil. This report provides information on objectives 1 and 2 above. A separate report will address objectives 3 and 4.

  4. The Mound site survey project for the characterization of radioactive materials in site soils

    SciTech Connect (OSTI)

    Stought, R.L.; Edling, D.A.; Draper, D.G.

    1988-05-16

    This report summarizes the results of a site survey project conducted at Monsanto Research Corporation`s Mound Facility during 1982--1985. The objectives of the site survey were: To characterize the nineteen sites previously identified as having known levels of contamination; to identify and characterize by quantity and type of radionuclide(s) any additional major sites having levels of contamination exceeding 10 pCi/g (for Pu-238) of soil; to estimate the volume of contaminated soil; and to estimate the cost of stabilizing or removing the contaminated soil. This report provides information on objectives 1 and 2 above. A separate report will address objectives 3 and 4.

  5. Simulation and economic evaluation of a solar evaporation system for concentrating sodium chloride brines

    SciTech Connect (OSTI)

    Smith, M.K.; Newell, T.A. )

    1991-01-01

    An hourly simulation program has been developed for detailed modelin of an evaporation surface (ES) and an evaporation pond (EP) for reconcentration of a solar pond's (SP's) surface brine. The results are relavant to other systems in which it is desirable to concentrate a brine. The simulation results are used in three ways: first, for general comparison of brine reconcentration performance for a variety of locations; second, development of an ES design method based on long term monthly averaged weather data; and third, an economic comparison between ESs and EPs. The results show that regions with moderate to high precipitation favor ESs over EPs. Dry climates will generally favor EPs for brine reconcentration.

  6. Focused risk assessment: Mound Plant, Miami-Erie Canal Operable Unit 4

    SciTech Connect (OSTI)

    Rogers, D.R.; Dunning, D.F.

    1994-09-29

    In 1969, an underground waste line at Mound Plant ruptured and released plutonium-238 in a dilute nitric acid solution to the surrounding soils. Most of the acid was neutralized by the native soils. The plutonium, which in a neutral solution is tightly sorbed onto clay particles, remained within the spill area. During remediation, a severe storm eroded some of the contaminated soil. Fine grained plutonium-contaminated clay particles were carried away through the natural drainage courses to the remnants of the Miami-Erie Canal adjacent to Mound Plant, and then into the Great Miami River. This focused risk assessment considers exposure pathways relevant to site conditions, including incidental ingestion of contaminated soils, ingestion of drinking water and fish, and inhalation of resuspended soils and sediments. For each potential exposure pathway, a simplified conceptual model and exposure scenarios have been used to develop conservative estimates of potential radiation dose equivalents and health risks. The conservatism of the dose and risk estimates provides a substantive margin of safety in assuring that the public health is protected.

  7. Community Geothermal Technology Program: Electrodeposition of minerals in geothermal brine

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    Objective was to study the materials electrodeposited from geothermal brine, from the HGP-A well in Puna, Hawaii. Due to limitations, only one good set of electrodeposited material was obtained; crystallography indicates that vaterite forms first, followed by calcite and then perhaps aragonite as current density is increased. While the cost to weight ratio is reasonable, the deposition rate is very slow. More research is needed, such as reducing the brittleness. The electrodeposited material possibly could be used as building blocks, tables, benches, etc. 49 figs, 4 tabs, 7 refs.

  8. An aerial radiological survey of the EG G Mound Applied Technologies and surrounding area, Miamisburg, Ohio

    SciTech Connect (OSTI)

    Not Available

    1992-11-01

    An aerial radiological survey was conducted over EG G Mound Applied Technologies, Miamisburg, Ohio, during the period of June 9--24, 1989. The purpose of the 41-square-kilometer (16-square-mile) survey was to document the terrestrial gamma environment of the plant and surrounding area. In addition, ground-based exposure rate measurements and soil samples were obtained to support the aerial data. An exposure rate contour map at 1 meter above ground level was.constructed from the gamma data and overlaid on an aerial photograph and map of the area. Exposure rates measured in the area typically ranged from 9 to 11 microroentgens per hour ([mu]R/h).

  9. A radioactive waste excavation at Mound Area 7 using INEL dig-face monitoring technology

    SciTech Connect (OSTI)

    Carpenter, M.V.; Josten, N.E.

    1996-12-31

    Dig-face characterization is a method to improve the safety and efficiency during hazardous waste retrieval. A dig-face characterization system consists of on-site hardware for collecting detailed information on the changing chemical, radiological, and physical conditions in the subsurface throughout a hazardous site excavation. The dig-face characterization concept originated at the Idaho National Engineering Laboratory where it has been under development since 1992. In August 1995, a prototype dig-face system was taken to Mound Laboratory, Ohio, to monitor a hazardous waste site excavation. Mound Area 7 was the site of previous disposal of {sup 232}Th, {sup 227}Ac, and other waste. The dig-face characterization system was used to monitor a 20-ft x 20-ft x 5-ft-deep excavation intended to remove the {sup 227}Ac contaminated soils. Radiological, geophysical, and topographical sensors were scanned across each of four successive excavated soil levels, each 1-ft to 2-ft thick. The radiation sensors produced highly detailed images showing the location of the contaminants {sup 232}Th and {sup 227}Ac, and the clear delineation between them. When combined into a single data set, the four levels of collected data produced a three dimensional image of the contamination. The radiation sensor data indicated that only a small portion of the excavated soil was actually contaminated. The information produced by the dig-face system was used to direct precise excavation activities in the area containing the {sup 227}Ac and to plan subsequent removal of the separate {sup 232}Th plume.

  10. Chemical-equilibrium calculations for aqueous geothermal brines

    SciTech Connect (OSTI)

    Kerrisk, J.F.

    1981-05-01

    Results from four chemical-equilibrium computer programs, REDEQL.EPAK, GEOCHEM, WATEQF, and SENECA2, have been compared with experimental solubility data for some simple systems of interest with geothermal brines. Seven test cases involving solubilities of CaCO/sub 3/, amorphous SiO/sub 2/, CaSO/sub 4/, and BaSO/sub 4/ at various temperatures from 25 to 300/sup 0/C and in NaCl or HCl solutions of 0 to 4 molal have been examined. Significant differences between calculated results and experimental data occurred in some cases. These differences were traced to inaccuracies in free-energy or equilibrium-constant data and in activity coefficients used by the programs. Although currently available chemical-equilibrium programs can give reasonable results for these calculations, considerable care must be taken in the selection of free-energy data and methods of calculating activity coefficients.

  11. Calculation of brine properties. [Above 80/sup 0/F and for salt...

    Office of Scientific and Technical Information (OSTI)

    Brine saturation pressure is calculated as a percentage of the pure water saturation ... temperature and pressure and are obtained from the ASME equation-of-state for pure water. ...

  12. Study of thermal-gradient-induced migration of brine inclusions in salt. Final report

    SciTech Connect (OSTI)

    Olander, D.R.

    1984-08-01

    Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed.

  13. Recovery of energy from geothermal brine and other hot water sources

    DOE Patents [OSTI]

    Wahl, III, Edward F.; Boucher, Frederic B.

    1981-01-01

    Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g. with respect to the design of such plates, number of plates employed, spacing between plates, area thereof, column diameter, and the like, are designed to achieve maximum throughput of brine or hot water and reduction in temperature differential at the respective stages or plates between the brine or hot water and the working fluid, and so minimize lost work and maximize efficiency, and minimize scale deposition from hot water containing fluid including salts, such as brine. Maximum throughput approximates minimum cost of electricity which can be produced by conversion of the recovered thermal energy to electrical energy.

  14. Certification of the Mound 1 kW package for shipping of plutonium dioxide source material

    SciTech Connect (OSTI)

    Annese, C.E.; Mount, M.K.

    1994-01-01

    The Department of Energy (DOE) has established procedures for obtaining certification of packagings used by DOE and its contractors for the transport of radioactive materials. Specifically, DOE Orders 5480.3 and 1540.2 provide references for other DOE Orders which must be followed when an applicant submits a Safety Analysis Report for Packaging (SARP). From the orders, Department EH of DOE, has internal oversight responsibility for transportation and Packaging safety; package certification falls under EH responsibility; transportation and packaging safety division in EH certifies packages for DOE; and use of DOE certified packages is authorized by DOT. An independent review of the SARP must confirm that the packaging designs and operations meet safety criteria at least equivalent to these standards. This paper will discuss the independent review process of the shielding section of the Mound 1 kW SARP; describe the geometry of the packaging and the load configurations; discuss the analysis of the various neutron and photon source terms that were used for the load configuration under analysis; and provide illustrations of the use of the monte-carlo code, COG{sup 3}, which was utilized to perform the shielding analysis.

  15. Dig-face monitoring during excavation of a radioactive plume at Mound Laboratory, Ohio

    SciTech Connect (OSTI)

    Josten, N.E.; Gehrke, R.J.; Carpenter, M.V.

    1995-12-01

    A dig-face monitoring system consists of onsite hardware for collecting information on changing chemical, radiological, and physical conditions in the subsurface soil during the hazardous site excavation. A prototype dig-face system was take to Mount Laboratory for a first trial. Mound Area 7 was the site of historical disposals of {sup 232}Th, {sup 227}Ac, and assorted debris. The system was used to monitor a deep excavation aimed at removing {sup 227}Ac-contaminated soils. Radiological, geophysical, and topographic sensors were used to scan across the excavation dig-face at four successive depths as soil was removed. A 3-D image of the contamination plumes was developed; the radiation sensor data indicated that only a small portion of the excavated soil volume was contaminated. The spatial information produced by the dig-face system was used to direct the excavation activities into the area containing the {sup 227}Ac and to evaluate options for handling the separate {sup 232}Th plume.

  16. West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume III. Biological oceanography. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J.

    1983-02-01

    The Department of Energy's Strategic Petroleum Reserve Program began discharging brine into the Gulf of Mexico from its West Hackberry site near Cameron, Louisiana in May 1981. The brine originates from underground salt domes being leached with water from the Intracoastal Waterway, making available vast underground storage caverns for crude oil. The effects of brine discharge on aquatic organisms are presented in this volume. The topics covered are: benthos; nekton; phytoplankton; zooplankton; and data management.

  17. Behavior of natural uranium, thorium, and radium isotopes in the Wolfcamp brine aquifers, Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1984-10-01

    Previously reported results for Palo Duro deep brines show that Ra is highly soluble and not retarded. Relative to Ra, U and Th are highly sorbed. Uranium, like thorium, is in the +4 valence state, indicating a reducing environment. Additional data reported here support these results. However, one Wolfcamp brine sample gives somewhat different results. Radium appears to be somewhat sorbed. Uranium is largely in the +6 valence state, indicating a less reducing condition. In all brines, kinetics for sorption (/sup 228/Th) and desorption (/sup 224/Ra) are rapid. This Wolfcamp brine was tested for the effects of colloids for Ra, U, and Th concentrations. No effects were found.

  18. Summary Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    The report summarizes laboratory and field observations and numerical modeling related to coupledprocesses involving brine and vapor migration in geologic salt, focusing on recent developments and...

  19. Silica separation from reinjection brines at Monte Amiata geothermal plants, Italy

    SciTech Connect (OSTI)

    Vitolo, S.; Cialdella, M.L. . Dipartimento di Ingegneria Chimica)

    1994-06-01

    A process for the separation of silica from geothermal reinjection brines is reported, in which the phases of coagulation, sedimentation and filtration of silica are involved. The effectiveness of lime and calcium chloride as coagulating agents has been investigated and the separating operations have been set out. Attention has been focused on Monte Amiata reinjection geothermal brines, whose scaling effect causes serious problems in the operation and maintenance of reinjection facilities. The study has been conducted using different amounts of added coagulants and at different temperatures, to determine optimal operating conditions. Though calcium chloride was revealed to be effective as a coagulant of the polymeric silica fraction, lime has also proved capable of removing monomeric dissolved silica at high dosages. Investigation on the behavior of coagulated brine has revealed the feasibility of separating the coagulated silica by sedimentation and filtration.

  20. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  1. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT STABILIZED BASIN 43 GROUNDWATER BRINE

    SciTech Connect (OSTI)

    COOKE GA; DUNCAN JB; LOCKREM LL

    2008-09-30

    This report is an initial report on the laboratory effort executed under RPP-PLAN-33338, Test Plan for the Assessment of Technetium Leachability in Cement-Stabilized Basin 43 Groundwater Brine. This report delineates preliminary data obtained under subcontract 21065, release 30, from the RJ Lee Group, Inc., Center for Laboratory Sciences. The report is predicated on CLS RPT-816, Draft Report: Assessment of Technetium Leachability in Cement Stabilized Basin 43 Groundwater Brine. This document will be revised on receipt of the final RJ Lee Group, Inc., Center for Laboratory Sciences report, which will contain data subjected to quality control and quality assurance criteria.

  2. Brine flow up a borehole caused by pressure perturbation from CO2 storage: Static and dynamic evaluations

    SciTech Connect (OSTI)

    Birkholzer, J.T.; Nicot, J.-P.; Oldenburg, C.M.; Zhou, Q.; Kraemer, S.; Bandilla, K.W.

    2011-05-01

    Industrial-scale storage of CO{sub 2} in saline sedimentary basins will cause zones of elevated pressure, larger than the CO{sub 2} plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards along these conduits and mix with groundwater resources. This paper discusses the potential for such brine leakage to occur in temperature- and salinity-stratified systems. Using static mass-balance calculations as well as dynamic well flow simulations, we evaluate the minimum reservoir pressure that would generate continuous migration of brine up a leaking wellbore into a freshwater aquifer. Since the brine invading the well is denser than the initial fluid in the wellbore, continuous flow only occurs if the pressure perturbation in the reservoir is large enough to overcome the increased fluid column weight after full invasion of brine into the well. If the threshold pressure is exceeded, brine flow rates are dependent on various hydraulic (and other) properties, in particular the effective permeability of the wellbore and the magnitude of pressure increase. If brine flow occurs outside of the well casing, e.g., in a permeable fracture zone between the well cement and the formation, the fluid/solute transfer between the migrating fluid and the surrounding rock units can strongly retard brine flow. At the same time, the threshold pressure for continuous flow to occur decreases compared to a case with no fluid/solute transfer.

  3. Performance of CRA in concentrated brines at 130 to 180 C -- Effect of H{sub 2}S, elemental sulfur and brine composition

    SciTech Connect (OSTI)

    Schmitt, G.; Pankoke, U.; Klemp, G.; Bruckhoff, W.; Siegmund, G.

    1997-08-01

    Failure analysis of localized corrosion at 28Cr32Ni (Alloy 28) tubing in a sour gas well prompted systematic investigations on the performance of relevant corrosion resistant alloys (CRA) in synthetic high salinity brines at high H{sub 2}S partial pressures in the absence and presence of elemental sulfur at 130 to 180 C. The CRAs included superaustenitic steels, nickel and nickel-cobalt base alloys and titanium alloys. CRAs with pitting resistance equivalents (PRE) of 39 and lower (including 28Cr32Ni) suffered in unbuffered brines from pitting and crevice corrosion already at 130 C. Alloy C276 and Ti Beta-C alloys proved complete resistance in all media tested up to 180 C. The effect of medium composition on CRA performance was studied at 130 C with respect to the presence of elemental sulfur, H{sub 2}S, iron sulfide, and CaCo{sub 3} in NaCl/CaCl{sub 2} brines with a total of 160 g/l chloride.

  4. Shaker Table Experiments with Rare Earth Elements Sorption from Geothermal Brine

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  5. RealGasBrine v1.0 option of TOUGH+ v1.5

    SciTech Connect (OSTI)

    Moridis, George

    2015-02-27

    RealGasBrine v1.0 is a numerical code that for the simulation of the behavior of gas-bearing porous and/fractured geologic media. It is an option of TOUGH+ v1.5 [Moridis, 2014], a successor to the TOUGH2 [Pruess et al., 1999; 2012] family of codes for multi-component, multiphase ?uid and heat ?ow developed at the Lawrence Berkeley National Laboratory. RealGasBrine v1.0 needs the TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRAN 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. RealGasBrine v1.0 describes the non-isothermal two- (for pure water) or three-phase (for brine) flow of an aqueous phase and a real gas mixture in a gas-bearing medium, with a particular focus in ultra-tight (such as tight-sand and shale gas) systems. Up to 12 individual real gases can be tracked, and salt can precipitate as solid halite. The capabilities of the code include coupled flow and thermal effects, real gas behavior, Darcy and non-Darcy flow, several isotherm options of gas sorption onto the grains of the porous media, complex fracture descriptions, gas solubility into water, and geomechanical effects on flow properties. RealGasBrine v1.0 allows the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in any problem involving the flow of gases in geologic media, including the geologic storage of greenhouse gas mixtures, the behavior of geothermal reservoirs with multi-component condensable (H2O and CO2) and non-condensable gas mixtures, the transport of water and released H2 in nuclear waste storage applications, etc.

  6. Disposal/recovery options for brine waters from oil and gas production in New York State. Final report

    SciTech Connect (OSTI)

    Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

    1996-03-01

    Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated.

  7. Field test of plutonium and thorium contaminated clay soils from the Mound Site using the ACT*DE*CON Process

    SciTech Connect (OSTI)

    Johnson, J.O.; Swift, N.A.; Church, R.H.; Neff, R.A.

    1998-12-31

    A treatability test was run during the summer and fall of 1997 to demonstrate the effectiveness of ACT*DE*CON for removing plutonium and thorium from the clay soils around Mound. ACT*DE*CON is a proprietary solution patented by Selentec. The process utilized a highly selective dissolution of the contaminants by the use of a chemical wash. The pilot scale process involved pretreatment of the soil in an attrition scrubber with ACT*DE*CON solution. This blended solution was then passed through a counter-current extraction chamber where additional contact with ACT*DE*CON solution occurred, followed by a rinse cycle. During this process sand was added to aid contact of the solution with the soil particles. The sand is removed during the rinse step and reused. The chelating agent is separated from the contaminant and recycled back into the process, along with the reverse osmosis permeate. The resulting solution can be further treated to concentrate the contaminant. Three different types of environmental soils were tested -- plutonium and thorium contaminated soils with the natural clay content, and plutonium contaminated soils with a high percentage of fine clay particles. The goal of these tests was to reduce the plutonium levels from several hundreds of pCi/g to between 25 and 75 pCi/g and the thorium from a couple hundred pCi/g to less than 5 pCi/g. The results of these four tests are presented along with a discussion of the operating parameters and the lessons learned relating to full scale implementation at Mound as well as other potential applications of this process.

  8. Mortality Among Mound Workers Exposed to Polonium-210 and Other Sources of Radiation, 1944–1979

    SciTech Connect (OSTI)

    Boice, John D.; Cohen, Sarah S.; Mumma, Michael T.; Ellis, Elizabeth Dupree; Cragle, Donna L.; Eckerman, Keith F.; Wallace, Phillip W.; Chadda, Bandana; Sonderman, Jennifer S.; Wiggs, Laurie D.; Richter, Bonnie S.; Leggett, Richard W.

    2014-02-14

    Polonium-210 is a naturally occurring radioactive element that decays by emitting an alpha particle. It is in the air we breathe and also a component of tobacco smoke. Polonium-210 is used as an anti-static device in printing presses and gained widespread notoriety in 2006 after the poisoning and subsequent death of a Russian citizen in London. More is known about the lethal effects of polonium-210 at high doses than about late effects from low doses. In this paper, cancer mortality was examined among 7,270 workers at the Mound nuclear facility near Dayton, OH where polonium-210 was used (1944–1972) in combination with beryllium as a source of neutrons for triggering nuclear weapons. Other exposures included external gamma radiation and to a lesser extent plutonium-238, tritium and neutrons. Vital status and cause of death was determined through 2009. Standardized mortality ratios (SMRs) were computed for comparisons with the general population. Lifetime occupational doses from all places of employment were sought and incorporated into the analysis. Over 200,000 urine samples were analyzed to estimate radiation doses to body organs from polonium and other internally deposited radionuclides. Cox proportional hazards models were used to evaluate dose-response relationships for specific organs and tissues. Vital status was determined for 98.7% of the workers of which 3,681 had died compared with 4,073.9 expected (SMR 0.90; 95% CI 0.88–0.93). The mean dose from external radiation was 26.1 mSv (maximum 939.1 mSv) and the mean lung dose from external and internal radiation combined was 100.1 mSv (maximum 17.5 Sv). Among the 4,977 radiation workers, all cancers taken together (SMR 0.86; 95% CI 0.79–0.93), lung cancer (SMR 0.85; 95% CI 0.74–0.98), and other types of cancer were not significantly elevated. Cox regression analysis revealed a significant positive dose-response trend for esophageal cancer [relative risk (RR) and 95% confidence interval at 100 mSv of 1

  9. Mortality Among Mound Workers Exposed to Polonium-210 and Other Sources of Radiation, 1944–1979

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boice, John D.; Cohen, Sarah S.; Mumma, Michael T.; Ellis, Elizabeth Dupree; Cragle, Donna L.; Eckerman, Keith F.; Wallace, Phillip W.; Chadda, Bandana; Sonderman, Jennifer S.; Wiggs, Laurie D.; et al

    2014-02-14

    Polonium-210 is a naturally occurring radioactive element that decays by emitting an alpha particle. It is in the air we breathe and also a component of tobacco smoke. Polonium-210 is used as an anti-static device in printing presses and gained widespread notoriety in 2006 after the poisoning and subsequent death of a Russian citizen in London. More is known about the lethal effects of polonium-210 at high doses than about late effects from low doses. In this paper, cancer mortality was examined among 7,270 workers at the Mound nuclear facility near Dayton, OH where polonium-210 was used (1944–1972) in combinationmore » with beryllium as a source of neutrons for triggering nuclear weapons. Other exposures included external gamma radiation and to a lesser extent plutonium-238, tritium and neutrons. Vital status and cause of death was determined through 2009. Standardized mortality ratios (SMRs) were computed for comparisons with the general population. Lifetime occupational doses from all places of employment were sought and incorporated into the analysis. Over 200,000 urine samples were analyzed to estimate radiation doses to body organs from polonium and other internally deposited radionuclides. Cox proportional hazards models were used to evaluate dose-response relationships for specific organs and tissues. Vital status was determined for 98.7% of the workers of which 3,681 had died compared with 4,073.9 expected (SMR 0.90; 95% CI 0.88–0.93). The mean dose from external radiation was 26.1 mSv (maximum 939.1 mSv) and the mean lung dose from external and internal radiation combined was 100.1 mSv (maximum 17.5 Sv). Among the 4,977 radiation workers, all cancers taken together (SMR 0.86; 95% CI 0.79–0.93), lung cancer (SMR 0.85; 95% CI 0.74–0.98), and other types of cancer were not significantly elevated. Cox regression analysis revealed a significant positive dose-response trend for esophageal cancer [relative risk (RR) and 95% confidence interval at 100 m

  10. CX-012731: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Windows of Bryan Mound Portal Building #281 CX(s) Applied: B1.3Date: 41884 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  11. CX-009509: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Power Monitoring, Communication and Control Upgrade at Bryan Mound Degas Plant (Install) CX(s) Applied: B1.7 Date: 10/31/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  12. CX-009792: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Video Inspection of Bryan Mound 36-inch Raw Water Pipeline CX(s) Applied: B1.3 Date: 01/07/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  13. CX-014467: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Clean Bryan Mound Crude Oil Tank, BMT-4 (BM-MM-738B) CX(s) Applied: B1.3Date: 11/11/2015 Location(s): Multiple LocationsOffices(s): Strategic Petroleum Reserve Field Office

  14. CX-009218: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Sparge Piping at Bryan Mound Raw Water Intake Structure CX(s) Applied: B1.3 Date: 09/20/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  15. CX-009212: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Replace Three Wood Poles-In-Kind at Bryan Mound West Gate CX(s) Applied: B1.3 Date: 08/23/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  16. Strategic Petroleum Reserve | Department of Energy

    Energy Savers [EERE]

    Strategic Petroleum Reserve Strategic Petroleum Reserve Crude oil pipes at the Bryan Mound site, the largest of the four SPR storage sites - near Freeport, TX. Crude oil pipes at ...

  17. CX-009511: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Alternate Source of Firewater at Bryan Mound CX(s) Applied: B5.2 Date: 11/05/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  18. CX-011848: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Upgrade Wood to Steel Light Poles CX(s) Applied: B1.3 Date: 02/14/2014 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  19. CX-008350: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Re-work Bryan Mound 30 Crude Oil Pipeline Mainline Valves CX(s) Applied: B1.3 Date: 04/10/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  20. CX-007513: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion for Driver Inspection of Bryan Mound 36 inch Raw Water Pipeline CX(s) Applied: B1.3 Date: 12/20/2011 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  1. CX-014288: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Dredging of Bryan Mound Raw Water Intake Structure Inlet Channel CX(s) Applied: B1.3Date: 09/28/2015 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  2. CX-013883: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Clean Bryan Mound Crude Oil Tank, BMT-4 CX(s) Applied: B1.3Date: 07/06/2015 Location(s): None ProvidedOffices(s): Strategic Petroleum Reserve Field Office

  3. CX-013886: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Remove Oil from Bryan Mound Crude Oil Tank BMT-4 Sump CX(s) Applied: B1.3Date: 07/06/2015 Location(s): None ProvidedOffices(s): Strategic Petroleum Reserve Field Office

  4. CX-014107: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Windows on Big Hill and Bryan Mound Entry Portal Buildings CX(s) Applied: B1.3Date: 08/03/2015 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  5. CX-006600: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Site Building Upgrades, Phase IICX(s) Applied: B1.3Date: 07/12/2011Location(s): Freeport, TexasOffice(s): Strategic Petroleum Reserve Field Office

  6. EIS-0075: Final Environmental Impact Statement

    Broader source: Energy.gov [DOE]

    Petroleum Reserve Phase III Development, Texoma and Seaway Group Salt Domes (West Hackberry and Bryan Mound Expansion, Big Hill Development) Cameron Parish, Louisiana, and Brazoria and Jefferson Counties, Texas

  7. Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration

    SciTech Connect (OSTI)

    Goddard, William

    2012-11-30

    To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

  8. West Hackberry Brine Disposal Project pre-discharge characterization. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.

    1982-01-01

    The physical, chemical and biological attributes are described for: (1) a coastal marine environment centered about a Department of Energy Strategic Petroleum Reserve (SPR) brine disposal site 11.4 km off the southwest coast of Louisiana; and (2) the lower Calcasieu and Sabine estuarine systems that provide leach waters for the SPR project. A three month sampling effort, February through April 1981, and previous investigations from the study area are integrated to establish baseline information for evaluation of impacts from brine disposal in the nearshore marine waters and from freshwater withdrawal from the coastal marsh of the Chenier Plain. January data are included for some tasks that sampled while testing and mobilizing their instruments prior to the February field effort. The study addresses the areas of physical oceanography, estuarine hydrology and hydrography, water and sediment quality, benthos, nekton, phytoplankton, zooplankton, and data management.

  9. Comparison of selected oil-field brines from fields in the Permian basin, West Texas-southeast New Mexico

    SciTech Connect (OSTI)

    White, H.G. III

    1992-04-01

    Stiff diagrams of oil-field brines from the west Texas Permian basin are identifiable within the geological framework. Plotted from a simple analysis of three cations and three anions, older Paleozoic waters can be categorized as either 'pristine' or modified, usually by a later influx of Permian or early Pennsylvanian water. These different plots can be segregated by geologic province. The Permian brines differ by age and also by environment (shelf, basin, etc.).

  10. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  11. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

  12. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extractionmore » control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing ‘Area of Review’, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.« less

  13. Ground-water hydraulics of the deep-basin brine aquifer, Palo Duro Basin, Texas panhandle

    SciTech Connect (OSTI)

    Smith, D.A.

    1985-01-01

    The Deep-Basin Brine aquifer of the Palo Duro Basin (Texas Panhandle) underlies thick Permian bedded evaporites that are being evaluated as a potential high-level nuclear waste isolation repository. Potentiometric surface maps of 5 units of the Deep-Basin Brine aquifer were drawn using drill-stem test (DST) pressure data, which were analyzed by a geostatistical technique (kriging) to smooth the large variation in the data. The potentiometric surface maps indicate that the Deep-Basin Brine aquifer could be conceptually modeled as 5 aquifer units; a Lower Permian (Wolfcamp) aquifer, upper and lower Pennsylvanian aquifers, a pre-Pennsylvanian aquifer, and a Pennsylvanian to Wolfcampian granite-wash aquifer. The hydraulic head maps indicate that ground-water flow in each of the units is west to east with a minor northerly component near the Amarillo Uplift, the northern structural boundary of the basin. The Wolfcamp potentiometric surface indicates the strongest component of northerly flow. Inferred flow direction in Pennsylvanian aquifers is easterly, and in the pre-Pennsylvanian aquifer near its pinch-out in the basin center, flow is inferred to be to the north. In the granite-wash aquifer the inferred flow direction is east across the northern edge of the basin and southeast along the Amarillo Uplift.

  14. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    SciTech Connect (OSTI)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at a proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ

  15. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore » proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir

  16. Strategic Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reserves » Strategic Petroleum Reserve Strategic Petroleum Reserve Crude oil pipes at the Bryan Mound site, the largest of the four SPR storage sites - near Freeport, TX. Crude oil pipes at the Bryan Mound site, the largest of the four SPR storage sites - near Freeport, TX. The Strategic Petroleum Reserve (SPR) is the world's largest supply of emergency crude oil. The federally-owned oil stocks are stored in huge underground salt caverns along the coastline of the Gulf of Mexico. Decisions to

  17. Operating Experience Summary - 2014-02 - April 23, 2014 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 4-02 - April 23, 2014 Operating Experience Summary - 2014-02 - April 23, 2014 April 23, 2014 OE Summary 2014-02 Inside this issue: Laboratory Worker Safety: Work Planning, Hazard Analysis, and Supervision - Page 1 Accident Investigation into Mower Fatality at the Bryan Mound Site - Page 13 Operating Experience Summary - 2014-02 - April 23, 2014 (3.61 MB) More Documents & Publications Investigation of the September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound

  18. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect (OSTI)

    David B. Burnett

    2005-09-29

    This study is developing a comprehensive study of what is involved in the desalination of oil field produced brine and the technical developments and regulatory changes needed to make the concept a commercial reality. It was originally based on ''conventional'' produced water treatment and reviewed (1) the basics of produced water management, (2) the potential for desalination of produced brine in order to make the resource more useful and available in areas of limited fresh water availability, and (3) the potential beneficial uses of produced water for other than oil production operations. Since we have begun however, a new area of interest has appeared that of brine water treatment at the well site. Details are discussed in this technical progress report. One way to reduce the impact of O&G operations is to treat produced brine by desalination. The main body of the report contains information showing where oil field brine is produced, its composition, and the volume available for treatment and desalination. This collection of information all relates to what the oil and gas industry refers to as ''produced water management''. It is a critical issue for the industry as produced water accounts for more than 80% of all the byproducts produced in oil and gas exploration and production. The expense of handling unwanted waste fluids draws scarce capital away for the development of new petroleum resources, decreases the economic lifetimes of existing oil and gas reservoirs, and makes environmental compliance more expensive to achieve. More than 200 million barrels of produced water are generated worldwide each day; this adds up to more than 75 billion barrels per year. For the United States, the American Petroleum Institute estimated about 18 billion barrels per year were generated from onshore wells in 1995, and similar volumes are generated today. Offshore wells in the United States generate several hundred million barrels of produced water per year. Internationally

  19. RealGasBrine v1.0 option of TOUGH+ v1.5

    Energy Science and Technology Software Center (OSTI)

    2015-02-27

    RealGasBrine v1.0 is a numerical code that for the simulation of the behavior of gas-bearing porous and/fractured geologic media. It is an option of TOUGH+ v1.5 [Moridis, 2014], a successor to the TOUGH2 [Pruess et al., 1999; 2012] family of codes for multi-component, multiphase ?uid and heat ?ow developed at the Lawrence Berkeley National Laboratory. RealGasBrine v1.0 needs the TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRANmore » 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. RealGasBrine v1.0 describes the non-isothermal two- (for pure water) or three-phase (for brine) flow of an aqueous phase and a real gas mixture in a gas-bearing medium, with a particular focus in ultra-tight (such as tight-sand and shale gas) systems. Up to 12 individual real gases can be tracked, and salt can precipitate as solid halite. The capabilities of the code include coupled flow and thermal effects, real gas behavior, Darcy and non-Darcy flow, several isotherm options of gas sorption onto the grains of the porous media, complex fracture descriptions, gas solubility into water, and geomechanical effects on flow properties. RealGasBrine v1.0 allows the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in any problem involving the flow of gases in geologic media, including the geologic storage of greenhouse gas mixtures, the behavior of geothermal reservoirs with multi-component condensable (H2O and CO2) and non-condensable gas mixtures, the transport of water and released H2 in nuclear waste storage applications, etc.« less

  20. Wet processing of palladium for use in the tritium facility at Westinghouse, Savannah River, SC. Preparation of palladium using the Mound Muddy Water process

    SciTech Connect (OSTI)

    Baldwin, D.P.; Zamzow, D.S.

    1998-11-10

    Palladium used at Savannah River for tritium storage is currently obtained from a commercial source. In order to better understand the processes involved in preparing this material, Savannah River is supporting investigations into the chemical reactions used to synthesize this material and into the conditions necessary to produce palladium powder that meets their specifications. This better understanding may help to guarantee a continued reliable source for this material in the future. As part of this evaluation, a work-for-others contract between Westinghouse Savannah River Company and the Ames Laboratory Metallurgy and Ceramics Program was initiated. During FY98, the process for producing palladium powder developed in 1986 by Dan Grove of Mound Applied Technologies (USDOE) was studied to understand the processing conditions that lead to changes in morphology in the final product. This report details the results of this study of the Mound Muddy Water process, along with the results of a round-robin analysis of well-characterized palladium samples that was performed by Savannah River and Ames Laboratory. The Mound Muddy Water process is comprised of three basic wet chemical processes, palladium dissolution, neutralization, and precipitation, with a number of filtration steps to remove unwanted impurity precipitates.

  1. Bryan Long (Acting) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    support; Project Management Office (PMO) support; and commodity IT services and infrastructure services supporting mission IT and corporate applications enterprise-wide. ...

  2. PILOT TESTING: PRETREATMENT OPTIONS TO ALLOW RE-USE OF FRAC FLOWBACK AND PRODUCED BRINE FOR GAS SHALE RESOURCE DEVELOPMENT

    SciTech Connect (OSTI)

    Burnett, David

    2012-12-31

    The goal of the A&M DOE NETL Project No. DE-FE0000847 was to develop a mobile, multifunctional water treatment capability designed specifically for “pre-treatment” of field waste brine. The project consisted of constructing s mobile “field laboratory” incorporating new technology for treating high salinity produced water and using the lab to conduct a side-by-side comparison between this new technology and that already existing in field operations. A series of four field trials were performed utilizing the mobile unit to demonstrate the effectiveness of different technology suitable for use with high salinity flow back brines and produced water. The design of the mobile unit was based on previous and current work at the Texas A&M Separation Sciences Pilot Plant. The several treatment techniques which have been found to be successful in both pilot plant and field tests had been tested to incorporate into a single multifunctional process train. Eight different components were evaluated during the trials, two types of oil and grease removal, one BTEX removal step, three micro-filters, and two different nanofilters. The performance of each technique was measured by its separation efficiency, power consumption, and ability to withstand fouling. The field trials were a success. Four different field brines were evaluated in the first trial in New York. Over 16,000 gallons of brine were processed. Using a power cost of $.10 per kWh, media pretreatment power use averaged $0.004 per barrel, solids removal $.04 per barrel and brine “softening” $.84 per barrel. Total power cost was approximately $1.00 per barrel of fluid treated. In Pennsylvania, brines collected from frac ponds were tested in two additional trials. Each of the brines was converted to an oil-free, solids-free brine with no biological activity. Brines were stable over time and would be good candidates for use as a make-up fluid in a subsequent fracturing fluid design. Reports on all of the field

  3. Geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro basin, Texas

    SciTech Connect (OSTI)

    Langmuir, D.; Melchior, D.

    1985-11-01

    The geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro Basin of north Texas, was studied to define geochemical controls on radionuclides such as /sup 90/Sr and /sup 226/Ra. Published solubility data for gypsum, anhydrite, celestite, barite and RaSO/sub 4/ were first reevaluated, in most cases using the ion interaction approach of Pitzer, to determine solubility products of the sulfates as a function of temperature and pressure. Ionic strengths of the brines were from 2.9 to 4.8 m, their temperatures and pressures up to 40/sup 0/C and 130 bars. Saturation indices of the sulfates were computed with the ion-interaction approach in one brine from the arkosic granite wash facies and four from the carbonate Wolfcamp Formation. All five brines are saturated with respect to gypsum, anhydrite and celestite, and three of the five with respect to barite. All are undersaturated by from 5 to 6 orders of magnitude with respect to pure RaSO/sub 4/. /sup 226/Ra concentrations in the brines, which ranged from 10/sup -11.3/ to 10/sup -12.7/ m, are not controlled by RaSO/sub 4/ solubility or adsorption, but possibly by the solubility of trace Ra solid solutions in sulfates including celestite and barite.

  4. The sup 36 Cl ages of the brines in the Magadi-Natron basin, east Africa

    SciTech Connect (OSTI)

    Kaufman, A.; Margaritz, M.A.; Hollos, G. ); Paul, M.; Boaretto, E. ); Hillaire-Marcel, C. ); Taieb, M. )

    1990-10-01

    The depression in the East African Rift which includes both Lake Magadi and Lake Natron forms a closed basin within which almost all the dissolved chloride originates in precipitation, since there is no important source of very ancient sedimentary chloride. This provides an ideal setting for the evaluation of the {sup 36}Cl methodology as a geochemical and hydrological tracer. The main source of recent water, as represented by the most dilute samples measured, is characterized by a {sup 36}Cl/Cl ratio of 2.5 {times} 10{sup {minus}14}, in agreement with the calculated value expected in precipitation. Surface evaporation increases the chlorinity of the local freshwater inflow by about a factor of 110 without changing the isotopic ratio, indicating that little chloride enters the system in the form of sediment leachate. A second type of brine found in the basin occurs in a hot deep groundwater reservoir and is characterized by lower {sup 36}Cl/Cl ratios (<1.2 {times} 10{sup {minus}14}). By comparing this value with the 2.5 {times} 10{sup {minus}14} in recent recharge, one obtains an approximate salt accumulation age of 760 Ka which is consistent with thee time of the first appearance of the lake. These older brines also have lower {sup 18}O and {sup 2}H values which indicate that they were recharged during a climatically different era. The {sup 36}Cl/Cl ratios in the inflowing waters and in the accumulated brine, together with the known age of the Lake Magadi basin, may be used to estimate the importance of the hypogene and epigene, as opposed to the meteoric, mode of {sup 36}Cl production. Such a calculation shows that the hypogene and epigene processes together contribute less than 6% of the total {sup 36}Cl present in the lake.

  5. Advanced biochemical processes for geothermal brines FY 1998 annual operating plan

    SciTech Connect (OSTI)

    1997-10-01

    As part of the overall Geothermal Energy Research which is aimed at the development of economical geothermal resources production systems, the aim of the Advanced Biochemical Processes for Geothermal Brines (ABPGB) effort is the development of economic and environmentally acceptable methods for disposal of geothermal wastes and conversion of by-products to useful forms. Methods are being developed for dissolution, separation and immobilization of geothermal wastes suitable for disposal, usable in inert construction materials, suitable for reinjection into the reservoir formation, or used for recovery of valuable metals.

  6. Brine migration test for Asse Mine, Federal Republic of Germany: final test plan

    SciTech Connect (OSTI)

    Not Available

    1983-07-01

    The United States and the Federal Republic of Germany (FRG) will conduct a brine migration test in the Asse Salt Mine in the FRG as part of the US/FRG Cooperative Radioactive Waste Management Agreement. Two sets of two tests each will be conducted to study both liquid inclusion migration and vapor migration in the two salt types chosen for the experiments: (1) pure salt, for its characteristics similar to the salt that might occur in potential US repositories, and (2) transitional salt, for its similarity to the salt that might occur in potential repositories in Germany.

  7. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  8. Sensitivity study of CO2 storage capacity in brine aquifers withclosed boundaries: Dependence on hydrogeologic properties

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Rutqvist, J.; Tsang, C-F.

    2007-02-07

    In large-scale geologic storage projects, the injected volumes of CO{sub 2} will displace huge volumes of native brine. If the designated storage formation is a closed system, e.g., a geologic unit that is compartmentalized by (almost) impermeable sealing units and/or sealing faults, the native brine cannot (easily) escape from the target reservoir. Thus the amount of supercritical CO{sub 2} that can be stored in such a system depends ultimately on how much pore space can be made available for the added fluid owing to the compressibility of the pore structure and the fluids. To evaluate storage capacity in such closed systems, we have conducted a modeling study simulating CO{sub 2} injection into idealized deep saline aquifers that have no (or limited) interaction with overlying, underlying, and/or adjacent units. Our focus is to evaluate the storage capacity of closed systems as a function of various reservoir parameters, hydraulic properties, compressibilities, depth, boundaries, etc. Accounting for multi-phase flow effects including dissolution of CO{sub 2} in numerical simulations, the goal is to develop simple analytical expressions that provide estimates for storage capacity and pressure buildup in such closed systems.

  9. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect (OSTI)

    David B. Burnett

    2004-09-29

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  10. Summary Results for Brine Migration Modeling Performed by LANL LBNL and SNL for the UFD Program.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L

    2014-09-01

    This report summarizes laboratory and field observations and numerical modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies conducted at Sandia, Los Alamos, and Berkeley National Laboratories. Interest into the disposal of heat-generating waste in salt has led to interest into water distribution and migration in both run-of-mine crushed and intact geologic salt. Ideally a fully coupled thermal-hydraulic-mechanical-chemical simulation is performed using numerical models with validated constitutive models and parameters. When mechanical coupling is not available, mechanical effects are prescribed in hydraulic models as source, boundary, or initial conditions. This report presents material associated with developing appropriate initial conditions for a non-mechanical hydrologic simulation of brine migration in salt. Due to the strong coupling between the mechanical and hydrologic problems, the initial saturation will be low for the excavation disturbed zone surrounding the excavation. Although most of the material in this report is not new, the author hopes it is presented in a format making it useful to other salt researchers.

  11. Brine migration test report: Asse Salt Mine, Federal Republic of Germany: Technical report

    SciTech Connect (OSTI)

    Coyle, A.J.; Eckert, J.; Kalia, H.

    1987-01-01

    This report presents a summary of Brine Migration Tests which were undertaken at the Asse mine of the Federal Republic of Germany (FRG) under a bilateral US/FRG agreement. This experiment simulates a nuclear waste repository at the 800-m (2624-ft) level of the Asse salt mine in the Federal Republic of Germany. This report describes the Asse salt mine, the test equipment, and the pretest properties of the salt in the mine and in the vicinity of the test area. Also included are selected test data (for the first 28 months of operation) on the following: brine migration rates, thermomechaical behavior of the salt (including room closure, stress reading, and thermal profiles), borehole gas pressures, and borehole gas analyses. In addition to field data, laboratory analyses of pretest salt properties are included in this report. The operational phase of these experiments was completed on October 4, 1985, with the commencement of cooldown and the start of posttest activities. 7 refs., 68 figs., 48 tabs.

  12. Fluid sampling and chemical modeling of geopressured brines containing methane. Final report, March 1980-February 1981

    SciTech Connect (OSTI)

    Dudak, B.; Galbraith, R.; Hansen, L.; Sverjensky, D.; Weres, O.

    1982-07-01

    The development of a flowthrough sampler capable of obtaining fluid samples from geopressured wells at temperatures up to 400/sup 0/F and pressures up to 20,000 psi is described. The sampler has been designed, fabricated from MP35N alloy, laboratory tested, and used to obtain fluid samples from a geothermal well at The Geysers, California. However, it has not yet been used in a geopressured well. The design features, test results, and operation of this device are described. Alternative sampler designs are also discussed. Another activity was to review the chemistry and geochemistry of geopressured brines and reservoirs, and to evaluate the utility of available computer codes for modeling the chemistry of geopressured brines. The thermodynamic data bases for such codes are usually the limiting factor in their application to geopressured systems, but it was concluded that existing codes can be updated with reasonable effort and can usefully explain and predict the chemical characteristics of geopressured systems, given suitable input data.

  13. Modeling Coupled THMC Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco Martin, Laura; Mukhopadhyay, Sumit; Houseworth, Jim; Birkholzer, Jens

    2014-08-14

    In this report, we present FY2014 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. LBNL’s work on the modeling of coupled THMC processes in salt was initiated in FY2012, focusing on exploring and demonstrating the capabilities of an existing LBNL modeling tool (TOUGH-FLAC) for simulating temperature-driven coupled flow and geomechanical processes in salt. This work includes development related to, and implementation of, essential capabilities, as well as testing the model against relevant information and published experimental data related to the fate and transport of water. we provide more details on the FY2014 work, first presenting updated tools and improvements made to the TOUGH-FLAC simulator, and the use of this updated tool in a new model simulation of long-term THM behavior within a generic repository in a salt formation. This is followed by the description of current benchmarking and validations efforts, including the TSDE experiment. We then present the current status in the development of constitutive relationships and the dual-continuum model for brine migration. We conclude with an outlook for FY2015, which will be much focused on model validation against field experiments and on the use of the model for the design studies related to a proposed heater experiment.

  14. THE ROLE OF LAND USE IN ENVIRONMENTAL DECISION MAKING AT THREE DOE MEGA-CLEANUP SITES FERNALD & ROCKY FLATS & MOUND

    SciTech Connect (OSTI)

    JEWETT MA

    2011-01-14

    This paper explores the role that future land use decisions have played in the establishment of cost-effective cleanup objectives and the setting of environmental media cleanup levels for the three major U.S. Department of Energy (DOE) sites for which cleanup has now been successfully completed: the Rocky Flats, Mound, and Fernald Closure Sites. At each site, there are distinct consensus-building histories throughout the following four phases: (1) the facility shut-down and site investigation phase, which took place at the completion of their Cold War nuclear-material production missions; (2) the decision-making phase, whereby stakeholder and regulatory-agency consensus was achieved for the future land-use-based environmental decisions confronting the sites; (3) the remedy selection phase, whereby appropriate remedial actions were identified to achieve the future land-use-based decisions; and (4) the implementation phase, whereby the selected remedial actions for these high-profile sites were implemented and successfully closed out. At each of the three projects, there were strained relationships and distrust between the local community and the DOE as a result of site contamination and potential health effects to the workers and local residents. To engage citizens and interested stakeholder groups - particularly in the role of final land use in the decision-making process, the site management teams at each respective site developed new public-participation strategies to open stakeholder communication channels with site leadership, technical staff, and the regulatory agencies. This action proved invaluable to the success of the projects and reaching consensus on appropriate levels of cleanup. With the implementation of the cleanup remedies now complete, each of the three DOE sites have become models for future environmental-remediation projects and associated decision making.

  15. Environmental Assessment for the Operation of the Glass Melter Thermal Treatment Unit at the US Department of Energy`s Mound Plant, Miamisburg, Ohio

    SciTech Connect (OSTI)

    1995-06-01

    The glass melter would thermally treat mixed waste (hazardous waste contaminated with radioactive constituents largely tritium, Pu-238, and/or Th-230) that was generated at the Mound Plant and is now in storage, by stabilizing the waste in glass blocks. Depending on the radiation level of the waste, the glass melter may operate for 1 to 6 years. Two onsite alternatives and seven offsite alternatives were considered. This environmental assessment indicates that the proposed action does not constitute a major Federal action significantly affecting the human environment according to NEPA, and therefore the finding of no significant impact is made, obviating the need for an environmental impact statement.

  16. Brine-in-crude-oil emulsions at the Strategic Petroleum Reserve.

    SciTech Connect (OSTI)

    Nemer, Martin B.; Lord, David L.; MacDonald, Terry L.

    2013-10-01

    Metastable water-in-crude-oil emulsion formation could occur in a Strategic Petroleum Reserve (SPR) cavern if water were to flow into the crude-oil layer at a sufficient rate. Such a situation could arise during a drawdown from a cavern with a broken-hanging brine string. A high asphaltene content (> 1.5 wt %) of the crude oil provides the strongest predictor of whether a metastable water-in-crude-oil emulsion will form. However there are many crude oils with an asphaltene content > 1.5 wt % that don't form stable emulsions, but few with a low asphaltene content that do form stable emulsions. Most of the oils that form stable emulsions are %E2%80%9Csour%E2%80%9D by SPR standards indicating they contain total sulfur > 0.50 wt %.

  17. Reduced order models for prediction of groundwater quality impacts from CO? and brine leakage

    SciTech Connect (OSTI)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO? storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO? and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO? leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highly efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO? and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO? storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO? storage projects.

  18. Evaluation of materials for systems using cooled, treated geothermal or high-saline brines

    SciTech Connect (OSTI)

    Suciu, D.F.; Wikoff, P.M.

    1982-09-01

    Lack of adequate quantities of clean surface water for use in wet (evaporative) cooling systems indicates the use of high-salinity waste waters, or cooled geothermal brines, for makeup purposes. High-chloride, aerated water represents an extremely corrosive environment. In order to determine metals suitable for use in such an environment, metal coupons were exposed to aerated, treated geothermal brine salted to a chloride concentration of 10,000 and 50,000 ppM (mg/L) for periods of up to 30 days. The exposed coupons were evaluated to determine the general, pitting, and crevice corrosion characteristics of the metals. The metals exhibiting corrosion resistance at 50,000 ppM chloride were then evaluated at 100,000 and 200,000 ppM chloride. Since these were screening tests to select materials for components to be used in a cooling system, with primary emphasis on condenser tubing, several materials were exposed for 4 to 10 months in pilot cooling tower test units with heat transfer for further corrosion evaluation. The results of the screening tests indicate that ferritic stainless steels (29-4-2 and SEA-CURE) exhibit excellent corrosion resistance at all levels of chloride concentration. Copper-nickel alloys (70/30 and Monel 400) exhibited excellent corrosion resistance in the high-saline water. The 70/30 copper-nickel alloy, which showed excellent resistance to general corrosion, exhibited mild pitting in the 30-day tests. This pitting was not apparent, however, after 6 months of exposure in the pilot cooling tower tests. The nickel-base alloys exhibited excellent corrosion resistance, but their high cost prevents their use unless no other material is found feasible. Other materials tested, although unsuitable for condenser tubing material, would be suitable as tube sheet material.

  19. Reduced order models for prediction of groundwater quality impacts from CO₂ and brine leakage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO₂ storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO₂ and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO₂ leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highlymore » efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO₂ and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO₂ storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO₂ storage projects.« less

  20. Multicomponent Seismic Analysis and Calibration to Improve Recovery from Algal Mounds: Application to the Roadrunner/Towaoc area of the Paradox Basin, UTE Mountain UTE Reservation, Colorado

    SciTech Connect (OSTI)

    Joe Hachey

    2007-09-30

    The goals of this project were: (1) To enhance recovery of oil contained within algal mounds on the Ute Mountain Ute tribal lands. (2) To promote the use of advanced technology and expand the technical capability of the Native American Oil production corporations by direct assistance in the current project and dissemination of technology to other Tribes. (3) To develop an understanding of multicomponent seismic data as it relates to the variations in permeability and porosity of algal mounds, as well as lateral facies variations, for use in both reservoir development and exploration. (4) To identify any undiscovered algal mounds for field-extension within the area of seismic coverage. (5) To evaluate the potential for applying CO{sub 2} floods, steam floods, water floods or other secondary or tertiary recovery processes to increase production. The technical work scope was carried out by: (1) Acquiring multicomponent seismic data over the project area; (2) Processing and reprocessing the multicomponent data to extract as much geological and engineering data as possible within the budget and time-frame of the project; (3) Preparing maps and data volumes of geological and engineering data based on the multicomponent seismic and well data; (4) Selecting drilling targets if warranted by the seismic interpretation; (5) Constructing a static reservoir model of the project area; and (6) Constructing a dynamic history-matched simulation model from the static model. The original project scope covered a 6 mi{sup 2} (15.6 km{sup 2}) area encompassing two algal mound fields (Towaoc and Roadrunner). 3D3C seismic data was to acquired over this area to delineate mound complexes and image internal reservoir properties such as porosity and fluid saturations. After the project began, the Red Willow Production Company, a project partner and fully-owned company of the Southern Ute Tribe, contributed additional money to upgrade the survey to a nine-component (3D9C) survey. The purpose

  1. Temporal Characterization of Hydrates System Dynamics beneath Seafloor Mounds. Integrating Time-Lapse Electrical Resistivity Methods and In Situ Observations of Multiple Oceanographic Parameters

    SciTech Connect (OSTI)

    Lutken, Carol; Macelloni, Leonardo; D'Emidio, Marco; Dunbar, John; Higley, Paul

    2015-01-31

    This study was designed to investigate temporal variations in hydrate system dynamics by measuring changes in volumes of hydrate beneath hydrate-bearing mounds on the continental slope of the northern Gulf of Mexico, the landward extreme of hydrate occurrence in this region. Direct Current Resistivity (DCR) measurements were made contemporaneously with measurements of oceanographic parameters at Woolsey Mound, a carbonate-hydrate complex on the mid-continental slope, where formation and dissociation of hydrates are most vulnerable to variations in oceanographic parameters affected by climate change, and where changes in hydrate stability can readily translate to loss of seafloor stability, impacts to benthic ecosystems, and venting of greenhouse gases to the water-column, and eventually, the atmosphere. We focused our study on hydrate within seafloor mounds because the structurally-focused methane flux at these sites likely causes hydrate formation and dissociation processes to occur at higher rates than at sites where the methane flux is less concentrated and we wanted to maximize our chances of witnessing association/dissociation of hydrates. We selected a particularly well-studied hydrate-bearing seafloor mound near the landward extent of the hydrate stability zone, Woolsey Mound (MC118). This mid-slope site has been studied extensively and the project was able to leverage considerable resources from the team’s research experience at MC118. The site exhibits seafloor features associated with gas expulsion, hydrates have been documented at the seafloor, and changes in the outcropping hydrates have been documented, photographically, to have occurred over a period of months. We conducted observatory-based, in situ measurements to 1) characterize, geophysically, the sub-bottom distribution of hydrate and its temporal variability, and 2) contemporaneously record relevant environmental parameters (temperature, pressure, salinity, turbidity, bottom currents) to

  2. Mound Transition Schedule

    Office of Legacy Management (LM)

  3. MOUND Environmental Restoration Program

    Office of Legacy Management (LM)

    ... C). .e J is questionable whether this 11lng :. x is applicable In tb case of ... meeting this need. &sit fall, when d8cu88lng pereonnel requlrem8nt8, It wae pointed out ...

  4. REE Sorption Study on sieved -50 +100 mesh fraction of Media #1 in Brine #1 with Different Starting pH's at 70C

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gary Garland

    2015-09-29

    This is a continuation of the REE sorption study for shaker bath tests on 2g media #1 in 150mL brine #1 with different starting pH's at 70C. In a previous submission we reported data for shaker bath tests for brine #1 with starting pH's of 3.5, 4.5 and 5.5. In this submission we these pH's compared to starting brine #1 pH's of 6, and 7.

  5. Radioactive waste isolation in salt: geochemistry of brine in rock salt in temperature gradients and gamma-radiation fields - a selective annotated bibliography

    SciTech Connect (OSTI)

    Hull, A.B.; Williams, L.B.

    1985-07-01

    Evaluation of the extensive research concerning brine geochemistry and transport is critically important to successful exploitation of a salt formation for isolating high-level radioactive waste. This annotated bibliography has been compiled from documents considered to provide classic background material on the interactions between brine and rock salt, as well as the most important results from more recent research. Each summary elucidates the information or data most pertinent to situations encountered in siting, constructing, and operating a mined repository in salt for high-level radioactive waste. The research topics covered include the basic geology, depositional environment, mineralogy, and structure of evaporite and domal salts, as well as fluid inclusions, brine chemistry, thermal and gamma-radiation effects, radionuclide migration, and thermodynamic properties of salts and brines. 4 figs., 6 tabs.

  6. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    SciTech Connect (OSTI)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additional wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in

  7. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additionalmore » wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7

  8. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    SciTech Connect (OSTI)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extraction control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing Area of Review, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.

  9. Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report

    SciTech Connect (OSTI)

    Alicia M. Wilson

    2009-11-30

    Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

  10. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    SciTech Connect (OSTI)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution features including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.

  11. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    SciTech Connect (OSTI)

    David B. Burnett; Mustafa Siddiqui

    2006-12-29

    Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes for the

  12. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution featuresmore » including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.« less

  13. GEOCHEMICAL INVESTIGATIONS OF CO₂-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO₂ injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO₂ and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  14. The implications of UIC and NPDES regulations on selection of disposal options for spent geothermal brine

    SciTech Connect (OSTI)

    1982-07-01

    This document reviews and evaluates the various options for the disposal of geothermal wastewater with respect to the promulgated regulations for the protection of surface and groundwaters. The Clean Water Act of 1977 and the Safe Drinking Water Act Amendments are especially important when designing disposal systems for geothermal fluids. The former promulgates regulations concerning the discharge of wastewater into surface waters, while the latter is concerned with the protection of ground water aquifers through the establishment of underground injection control (UIC) programs. There is a specific category for geothermal fluid discharge if injection is to be used as a method of disposal. Prior to February 1982, the UIC regulations required geothermal power plant to use Class III wells and direct use plants to use Class V wells. More stringent regulatory requirements, including construction specification and monitoring, are imposed on the Class III wells. On February 3, 1982, the classification of geothermal injection wells was changed from a Class III to Class V on the basis that geothermal wells do not inject for the extraction of minerals or energy, but rather they are used to inject brines, from which heat has been extracted, into formations from which they were originally taken. This reclassification implies that a substantial cost reduction will be realized for geothermal fluid injection primarily because well monitoring is no longer mandatory. The Clean Water Act of 1977 provides the legal basis for regulating the discharge of liquid effluent into the nation's surface waters, through a permitting system called the National Pollution Discharge Elimination System (NPDES) Discharge quantities, rates, concentrations and temperatures are regulated by the NPDES permits. These permits systems are based upon effluent guidelines developed by EPA on an industry by industry basis. For geothermal energy industry, effluent guidelines have not been formulated and are not

  15. Modifications of Carbonate Fracture Hydrodynamic Properties by CO{sub 2}-Acidified Brine Flow

    SciTech Connect (OSTI)

    Deng, Hang; Ellis, Brian R.; Peters, Catherine A.; Fitts, Jeffrey P.; Crandall, Dustin; Bromhal, Grant S.

    2013-08-01

    Acidic reactive flow in fractures is relevant in subsurface activities such as CO{sub 2} geological storage and hydraulic fracturing. Understanding reaction-induced changes in fracture hydrodynamic properties is essential for predicting subsurface flows such as leakage, injectability, and fluid production. In this study, x-ray computed tomography scans of a fractured carbonate caprock were used to create three dimensional reconstructions of the fracture before and after reaction with CO{sub 2}-acidified brine (Ellis et al., 2011, Greenhouse Gases: Sci. Technol., 1:248-260). As expected, mechanical apertures were found to increase substantially, doubling and even tripling in some places. However, the surface geometry evolved in complex ways including ‘comb-tooth’ structures created from preferential dissolution of calcite in transverse sedimentary bands, and the creation of degraded zones, i.e. porous calcite-depleted areas on reacted fracture surfaces. These geometric alterations resulted in increased fracture roughness, as measured by surface Z{sub 2} parameters and fractal dimensions D{sub f}. Computational fluid dynamics (CFD) simulations were conducted to quantify the changes in hydraulic aperture, fracture transmissivity and permeability. The results show that the effective hydraulic apertures are smaller than the mechanical apertures, and the changes in hydraulic apertures are nonlinear. Overestimation of flow rate by a factor of two or more would be introduced if fracture hydrodynamic properties were based on mechanical apertures, or if hydraulic aperture is assumed to change proportionally with mechanical aperture. The differences can be attributed, in part, to the increase in roughness after reaction, and is likely affected by contiguous transverse sedimentary features. Hydraulic apertures estimated by the 1D statistical model and 2D local cubic law (LCL) model are consistently larger than those calculated from the CFD simulations. In addition, a novel

  16. Evaporite Caprock Integrity. An experimental study of reactive mineralogy and pore-scale heterogeneity during brine-CO2 exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Sholokhova, Yelena; Hao, Yue; Carroll, Susan A.

    2012-07-25

    Characterization and geochemical data are presented from a core-flooding experiment on a sample from the Three Fingers evaporite unit forming the lower extent of caprock at the Weyburn-Midale reservoir, Canada. This low-permeability sample was characterized in detail using X-ray computed microtomography before and after exposure to CO 2-acidified brine, allowing mineral phase and voidspace distributions to be quantified in three dimensions. Solution chemistry indicated that CO 2-acidified brine preferentially dissolved dolomite until saturation was attained, while anhydrite remained unreactive. Dolomite dissolution contributed to increases in bulk permeability through the formation of a localized channel, guided by microfractures as well asmore » porosity and reactive phase distributions aligned with depositional bedding. An indirect effect of carbonate mineral reactivity with CO 2-acidified solution is voidspace generation through physical transport of anhydrite freed from the rock matrix following dissolution of dolomite. The development of high permeability fast pathways in this experiment highlights the role of carbonate content and potential fracture orientations in evaporite caprock formations considered for both geologic carbon sequestration and CO 2-enhanced oil recovery operations.« less

  17. Wetting behavior of selected crude oil/brine/rock systems. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Zhou, X.; Morrow, N.R.; Ma, S.

    1996-12-31

    Previous studies of crude oil/brine/rock (COBR) and related ensembles showed that wettability and its effect on oil recovery depend on numerous complex interactions. In the present work, the wettability of COBR ensembles prepared using Prudhoe Bay crude oil, a synthetic formation brine, and Berea Sandstone was varied by systematic change in initial water saturation and length of aging time at reservoir temperature (88 C). All displacement tests were run at ambient temperature. Various degrees of water wetness were achieved and quantified by a modified Amott wettability index to water, the relative pseudo work of imbibition, and a newly defined apparent advancing dynamic contact angle. Pairs of spontaneous imbibition (oil recovery by spontaneous imbibition of water) and waterflood (oil recovery vs. pore volumes of water injected) curves were measured for each of the induced wetting states. Several trends were observed. Imbibition rate, and hence water wetness, decreased with increase in aging time and with decrease in initial water saturation. Breakthrough recoveries and final oil recovery by waterflooding increased with decrease in water wetness. Correlations between water wetness and oil recovery by waterflooding and spontaneous imbibition are presented.

  18. REE Sorption Study for Media #1 and Media #2 in Brine #1 and #2 at different Liquid to Solid Ratio's at Ambient Temperature

    SciTech Connect (OSTI)

    Gary Garland

    2015-03-27

    This data set shows the different loading capacities of Media #1 and Media #2 in a high and low salt content brine matrix at different liquid to solid ratio's. These data sets are shaker bath tests on media #1 and media #2 in brine's #1 and #2 at 500mL-.5g(1000-1 ratio), 150mL-.75g(200-1 ratio), and 150mL-2.5g(60-1 ratio) at ambient temperature.

  19. REE Sorption Study of Sieved -50 +100 mesh Media #1 in Brine #1 with Different Starting pH's at 70C

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  20. Rare-earth elements in hot brines (165 to 190 degree C) from the Salton Sea geothermal field

    SciTech Connect (OSTI)

    Lepel, E.A.; Laul, J.C.; Smith, M.R.

    1988-01-01

    Rare-earth element (REE) concentrations are important indicators for revealing various chemical fractionation processes (water/rock interactions) and source region geochemistry. Since the REE patterns are characteristic of geologic materials (basalt, granite, shale, sediments, etc.) and minerals (K-feldspar, calcite, illite, epidote, etc.), their study in geothermal fluids may serve as a geothermometer. The REE study may also enable us to address the issue of groundwater mixing. In addition, the behavior of the REE can serve as analogs of the actinides in radioactive waste (e.g., neodymium is an analog of americium and curium). In this paper, the authors port the REE data for a Salton Sea Geothermal Field (SSGF) brine (two aliquots: port 4 at 165{degree}C and port 5 at 190{degree}C) and six associated core samples.

  1. Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot

    SciTech Connect (OSTI)

    Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

    2009-11-01

    To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

  2. Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

    SciTech Connect (OSTI)

    Beauheim, R.L. ); Saulnier, G.J. Jr.; Avis, J.D. )

    1991-08-01

    Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

  3. Strategic petroleum reserve site environmental report for calendar year 1995

    SciTech Connect (OSTI)

    1996-05-31

    The purpose of this Site Environmental Report (SER) is to characterize site environmental management performance, confirm compliance with environmental standards and requirements, and highlight significant programs and efforts. Included in this report is a description of each site`s environment, an overview of the Strategic Petroleum Reserve (SPR) environmental program, and a recapitulation of special environmental activities and events associated with each SPR site during 1995. Two of these highlights include decommissioning of 3 the weeks Island facility, involving the disposition of 11.6 million m{sup 3} (73 million barrels) of crude oil inventory, as well as the degasification of over 4.5 million m{sup 3} (30 million barrels) of crude oil inventory at the Bryan Mound and West Hackberry facilities. The decision to decommission the weeks Island facility is a result of diminishing mine integrity from ground water intrusion. Transfer of Weeks Island oil began in November, 1995 with 2.0 million m{sup 3} (12.5 million barrels) transferred by December 31, 1995. Degasifying the crude oil is a major pollution prevention initiative because it will reduce potentially harmful emissions that would occur during oil movements by three or more orders of magnitude. Spills to the environment, another major topic, indicates a positive trend. There were only two reportable oil and three reportable brine spills during 1995, down from a total of 10 reportable spills in 1994. Total volume of oil spilled in 1995 was 56.3 m{sup 3} (354 barrels), and the total volume of brine spilled was 131.1 m{sup 3} (825 barrels). The longer term trend for oil and brine spills has declined substantially from 27 in 1990 down to five in 1995. All of the spills were reported to appropriate agencies and immediately cleaned up, with no long term impacts observed.

  4. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  5. Microsoft PowerPoint - 8-Mound Connector Presentation for Mound...

    Office of Legacy Management (LM)

    delay WHY CHOOSE A ROUNDABOUT? * Miamisburg- Springboro Pike Construction Costs * 6,700,000 * Start construction in 2017 * Benner Road Construction Costs * 6,400,000 ...

  6. Bryan County, Oklahoma: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Oklahoma Bennington, Oklahoma Bokchito, Oklahoma Caddo, Oklahoma Calera, Oklahoma Colbert, Oklahoma Durant, Oklahoma Hendrix, Oklahoma Kemp, Oklahoma Kenefic, Oklahoma Mead,...

  7. REE Sorption Study of Seived -50 +100 Mesh Fraction of Media #1 in Brine #1 at Different Concentrations of REE at 70C

    SciTech Connect (OSTI)

    Gary Garland

    2015-06-29

    This dataset shows the sorption capacities of smaller grain size (-50 +100 mesh) of media #1 in brine #1 at different starting concentrations of REE's at elevated temperature of 70C. The experimental conditions are 2g of -50 +100 mesh media #1 to 150mL of REE solution at concentartions of .2ppm each, 2ppm each, and 20ppm each. The pH of the solution is 5.5, and the temperature was at 70C.

  8. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-14

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  9. 1989 Annual environmental report for the Strategic Petroleum Reserve

    SciTech Connect (OSTI)

    Not Available

    1990-06-01

    This report, provided annually, summarizes monitoring data collected to assess Strategic Petroleum Reserve (SPR) impacts on the environment. The report serves as a management tool for mitigating such impacts, thus serving the public interest by ensuring environmentally sound operation of the Strategic Petroleum Reserve (SPR). Included is a description of each site's environment, an overview of the SPR environmental program, and a recapitulation of special environmental activities and events associated with each SPR site during 1989. The active permits and the results of the environmental monitoring program (i.e., air, surface water, groundwater, and waste discharges) are discussed by site. The quality assurance program is presented which includes results from laboratory and field audits and studies performed internally and by regulatory agencies. In general, no significant adverse environmental impact resulted from SPR activities during 1989, except for a brine release from a pipeline perforation south of the Bryan Mound site adversely affecting a small area of marsh vegetation which is recovering at this time. 22 refs., 15 figs., 17 tabs.

  10. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    SciTech Connect (OSTI)

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

    2013-04-01

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

  11. CX-012334: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Install Single Split System Air Conditioning Unit in Bryan Mound Building No. 281 (BM-OM-1229) CX(s) Applied: B1.4 Date: 06/30/2014 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  12. CX-007508: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion for Rework Bryan Mound Seaway Dock Terminal Bypass Valve MOV-C308 CX(s) Applied: B1.3 Date: 11/16/2011 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  13. CX-013440: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion Determination to Replace Piping Header at Bryan Mound RWIS and RWIP (BM-MM-1027) CX(s) Applied: B1.3Date: 02/18/2015 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  14. CX-014462: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Oil Water Separators at Bryan Mound Caverns 1, 2, 4 and 5 - GFE (BM-MM-1203A) CX(s) Applied: B1.3Date: 12/15/2015 Location(s): Multiple LocationsOffices(s): Strategic Petroleum Reserve Field Office

  15. CX-014463: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Oil Water Separators at Bryan Mound Caverns 1, 2, 4 and 5 - Install (BM-MM-1203) CX(s) Applied: B1.3Date: 12/15/2015 Location(s): Multiple LocationsOffices(s): Strategic Petroleum Reserve Field Office

  16. DOE F 3304.2 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4.2 DOE F 3304.2 Form1 (146.9 KB) More Documents & Publications Investigation of the September 13, 2011, Fatality at the Strategic Petroleum Reserve Bryan Mound Site DOE F 241 5 Headquarters Facilities Master Security Plan - Chapter 17, Headquarters Security Officer Program

  17. CX-006881: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replacement of Obsolete Siemens S5-115H Programmable Logic ControllersCX(s) Applied: B1.3Date: 09/22/2011Location(s): Big Hill, Bryan Mound, West Hackberry, Louisiana, TexasOffice(s): Strategic Petroleum Reserve Field Office

  18. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  19. Finding of No Significant Impact and Final Environmental Assessment for the Future Location of Heat Source/Radioisotope Power System Assembly and Testing and Operations Currently Located at the Mound Site

    SciTech Connect (OSTI)

    N /A

    2002-08-30

    The U.S. Department of Energy (the Department) has completed an Environmental Assessment for the Future Location of the Heat Source/Radioisotope Power System Assembly and Test. Operations Currently Located at the Mound Site. Based on the analysis in the environmental assessment, the Department has determined that the proposed action, the relocation of the Department's heat source and radioisotope power system operations, does not constitute a major Federal action significantly affecting the quality of the human environment within the meaning of the ''National Environmental Policy Act'' of 1969 (NEPA). Therefore, the preparation of an Environmental Impact Statement is not required, and the Department is issuing this Finding of No Significant Impact (FONSI).

  20. International shipment of light weight radioisotopic heater units (LWRHU) using the USA/9516/B(U)F Mound 1 kW shipping package in support of the {open_quotes}Pluto Express{close_quotes} mission

    SciTech Connect (OSTI)

    Barklay, C.D.; Merten, C.W.

    1997-01-01

    Radioisotopes have provided heat that has been used to maintain specific operating environments within remote satellites and spacecraft. For the {open_quotes}Pluto Express{close_quotes} mission the {sup 238}PuO{sub 2} fueled light weight radioisotopic heater unit (LWRHU) will be used within the spacecraft. Since the current plan for the {open_quotes}Pluto Express{close_quotes} mission incorporates the use of a Russian launch platform for the spacecraft, the LWRHUs must be transported in an internationally certified shipping container. An internationally certified shipping package that is versatile enough to be reconfigured to transport the LWRHUs that will be required to support the {open_quotes}Pluto Express{close_quotes} mission is the Mound USA/9516/B(U)F. {copyright} {ital 1997 American Institute of Physics.}

  1. Strategic Petroleum Reserve Site Environmental Report for calendar year 1994

    SciTech Connect (OSTI)

    1995-05-31

    The purpose of this Site Environmental Report (SER) is to characterize site environmental management performance, confirm compliance with environmental standards and requirements, and highlight significant programs and efforts. The SER, provided annually in accordance with Department of Energy DOE Order 5400.1, serves the public by summarizing monitoring data collected to assess how the Strategic Petroleum Reserve (SPR) impacts the environment. This report (SER) provides a balanced synopsis of non-radiological monitoring and regulatory compliance data and affirms that the SPR has been operating within acceptable regulatory limits. Included in this report is a description of each site`s environment, an overview of the SPR environmental program, and a recapitulation of special environmental activities and events associated with each SPR site during 1994. Two of these highlights include decommissioning of the Weeks Island facility (disposition of 73 million barrels of crude oil inventory) as well as the degasification of up to 144 million barrels of crude oil inventory at the Bayou Choctaw, Big Hill, Bryan Mound, and West Hackberry facilities. The decision to decommission the Weeks Island facility is a result of diminishing mine integrity from ground water intrusion. Degasifying the crude oil is required to reduce potentially harmful emissions that would occur during oil movements. With regard to still another major environmental action, 43 of the original 84 environmental findings from the 1992 DOE Tiger Team Assessment were closed by the end of 1994. Spills to the environment, another major topic, indicates a positive trend. Total volume of oil spilled in 1994 was only 39 barrels, down from 232 barrels in 1993, and the total volume of brine spilled was only 90 barrels, down from 370 barrels in 1993. The longer term trend for oil and brine spills has declined substantially from 27 in 1990 down to nine in 1994.

  2. Accident Investigation of the February 7, 2013, Scissor Lift Accident in the West Hackberry Brine Tank-14 Resulting in Injury, Strategic Petroleum Reserve West Hackberry, LA

    Broader source: Energy.gov [DOE]

    On February 15, 2013, an Accident Investigation Board (the Board) was appointed to investigate an accident that resulted in serious injuries caused when a scissor lift tipped over in Brine Tank-14 (WHT-14) at the Strategic Petroleum Reserve, West Hackberry, Louisiana, site on February 7, 2013. The Board’s responsibilities have been completed with respect to this investigation. The analysis and the identification of the direct cause, root causes, contributing causes, and judgments of need resulting from this investigation were performed in accordance with the Department of Energy (DOE) Order 225.1B, Accident Investigations.

  3. Batteries from Brine

    Broader source: Energy.gov [DOE]

    Low-temp geothermal technologies are meeting a growing demand for strategic materials in clean manufacturing.

  4. Estimates of the solubilities of waste element radionuclides in waste isolation pilot plant brines: A report by the expert panel on the source term

    SciTech Connect (OSTI)

    Hobart, D.E.; Bruton, C.J.; Millero, F.J.; Chou, I.M.; Trauth, K.M.; Anderson, D.R.

    1996-05-01

    Evaluation of the long-term performance of the WIPP includes estimation of the cumulative releases of radionuclide elements to the accessible environment. Nonradioactive lead is added because of the large quantity expected in WIPP wastes. To estimate the solubilities of these elements in WIPP brines, the Panel used the following approach. Existing thermodynamic data were used to identify the most likely aqueous species in solution through the construction of aqueous speciation diagrams. Existing thermodynamic data and expert judgment were used to identify potential solubility-limiting solid phases. Thermodynamic data were used to calculate the activities of the radionuclide aqueous species in equilibrium with each solid. Activity coefficients of the radionuclide-bearing aqueous species were estimated using Pitzer`s equations. These activity coefficients were then used to calculate the concentration of each radionuclide at the 0.1 and 0.9 fractiles. The 0.5 fractile was chosen to represent experimental data with activity coefficient corrections as described above. Expert judgment was used to develop the 0.0, 0.25, 0.75, and 1.0 fractiles by considering the sensitivity of solubility to the potential variability in the composition of brine and gas, and the extent of waste contaminants, and extending the probability distributions accordingly. The results were used in the 1991 and 1992 performance assessment calculations. 68 refs.

  5. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-03-31

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite

  6. Alternative methods for dispoal of low-level radioactive wastes. Task 1. Description of methods and assessment of criteria. [Alternative methods are belowground vaults, aboveground vaults; earth mounded concrete bunkers, mined cavities, augered holes

    SciTech Connect (OSTI)

    Bennett, R.D.; Miller, W.O.; Warriner, J.B.; Malone, P.G.; McAneny, C.C.

    1984-04-01

    The study reported herein contains the results of Task 1 of a four-task study entitled Criteria for Evaluating Engineered Facilities. The overall objective of this study is to ensure that the criteria needed to evaluate five alternative low-level radioactive waste (LLW) disposal methods are available to the Nuclear Regulatory Commission (NRC) and the Agreement States. The alternative methods considered are belowground vaults, aboveground vaults, earth mounded concrete bunkers, mined cavities, and augered holes. Each of these alternatives is either being used by other countries for low-level radioactive waste (LLW) disposal or is being considered by other countries or US agencies. In this report the performance requirements are listed, each alternative is described, the experience gained with its use is discussed, and the performance capabilities of each method are addressed. Next, the existing 10 CFR Part 61 Subpart D criteria with respect to paragraphs 61.50 through 61.53, pertaining to site suitability, design, operations and closure, and monitoring are assessed for applicability to evaluation of each alternative. Preliminary conclusions and recommendations are offered on each method's suitability as an LLW disposal alternative, the applicability of the criteria, and the need for supplemental or modified criteria.

  7. Numerical modeling of regional ground-water flow in the deep-basin brine aquifer of the Palo Duro Basin, Texas Panhandle

    SciTech Connect (OSTI)

    Wirojanagud, P.; Kreitler, C.W.; Smith, D.A.

    1986-01-01

    Bedded Permian-age evaporite sequences in the Palo Duro Basin are being considered for a permanent nuclear waste repository by the U.S. Department of Energy. The purpose of this modeling study is to provide an understanding of regional ground-water flow in the formations beneath the Permian evaporite section. From this understanding, more detailed, smaller scale studies can be designed. This study is also intended to provide a better understanding of the boundary conditions and permeabilities of the aquifer and aquitard system as well as provide estimates of ground-water travel times across the basin. Numerical simulations were made of the Wolfcamp aquifer modeled as a single layer and of the entire Deep-Basin Brine aquifer system, including the Wolfcamp aquifer, modeled as a single layer.

  8. An objective rapid screening tool for surfactants used in foam-like dispersions of CO{sub 2} into Permian Basin brines

    SciTech Connect (OSTI)

    Horton, R.L.; Wicks, J.P.; Prieditis, J.; Turbeville, J.B.

    1995-11-01

    Foam-like dispersions of CO{sub 2} into brines can reduce the mobility of drive fluids in CO{sub 2} floods. To evaluate the effectiveness of such foam-like dispersions, time-consuming laboratory coreflood tests are routinely used. Because of the costliness of such coreflood tests, simple qualitative tests have long been employed to screen potential surfactants. Then only a few of the better candidates are subsequently evaluated in coreflood tests. There are a number of disadvantages of such qualitative tests; therefore the authors developed, instead, a quantitative screening process. Their quantitative process is based on two simple, quick laboratory tests and a neural network interpretation of the test data. The neural network predicted CO{sub 2} mobility reduction values which correlated well with the mobility reductions seen in coreflood tests.

  9. Preliminary performance assessment for the Waste Isolation Pilot Plant, December 1992. Volume 5, Uncertainty and sensitivity analyses of gas and brine migration for undisturbed performance

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    Before disposing of transuranic radioactive waste in the Waste Isolation Pilot Plant (WIPP), the United States Department of Energy (DOE) must evaluate compliance with applicable long-term regulations of the United States Environmental Protection Agency (EPA). Sandia National Laboratories is conducting iterative performance assessments (PAs) of the WIPP for the DOE to provide interim guidance while preparing for a final compliance evaluation. This volume of the 1992 PA contains results of uncertainty and sensitivity analyses with respect to migration of gas and brine from the undisturbed repository. Additional information about the 1992 PA is provided in other volumes. Volume 1 contains an overview of WIPP PA and results of a preliminary comparison with 40 CFR 191, Subpart B. Volume 2 describes the technical basis for the performance assessment, including descriptions of the linked computational models used in the Monte Carlo analyses. Volume 3 contains the reference data base and values for input parameters used in consequence and probability modeling. Volume 4 contains uncertainty and sensitivity analyses with respect to the EPA`s Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes (40 CFR 191, Subpart B). Finally, guidance derived from the entire 1992 PA is presented in Volume 6. Results of the 1992 uncertainty and sensitivity analyses indicate that, conditional on the modeling assumptions and the assigned parameter-value distributions, the most important parameters for which uncertainty has the potential to affect gas and brine migration from the undisturbed repository are: initial liquid saturation in the waste, anhydrite permeability, biodegradation-reaction stoichiometry, gas-generation rates for both corrosion and biodegradation under inundated conditions, and the permeability of the long-term shaft seal.

  10. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    SciTech Connect (OSTI)

    Myint, P. C.; Hao, Y.; Firoozabadi, A.

    2015-03-27

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO2) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data [1]. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi [2], and the CO2 activity coefficient model by Duan and Sun [3]. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO2, pure water, and both CO2-rich and aqueous (H2O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Suns model yields accurate results for the partial molar enthalpy of CO2. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H2O-CO2-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.