National Library of Energy BETA

Sample records for brown powder obtained

  1. Obtaining aluminas from the thermal decomposition of their different precursors: An {sup 27}Al MAS NMR and X-ray powder diffraction studies

    SciTech Connect (OSTI)

    Chagas, L.H.; De Carvalho, G.S.G.; San Gil, R.A.S.; Chiaro, S.S.X.; Leitão, A.A.; Diniz, R.

    2014-01-01

    Graphical abstract: - Highlights: • We synthesized three precursors of alumina from different methods. • The calcination of the precursors generated several alumina polymorphs. • XRD and NMR were used for structural investigation of the polymorphs. • The synthesis route determines the structural and textural properties of the solids. - Abstract: A commercial sample of Boehmite was used as precursor of alumina polymorphs. For comparison, three other precursors were synthesized from different methods. Particularly, the use of excess of urea promoted a very crystalline form of basic aluminum carbonate. The characteristics of the four precursors were investigated by thermal, vibrational and X-ray powder diffraction (XRD) analysis. Additionally, the nuclear magnetic resonance, with magic angle spinning ({sup 27}Al MAS NMR), was used to verify the coordination of aluminum cations. Each precursor was calcined at various temperatures generating alumina polymorphs, which were structurally analyzed by XRD and {sup 27}Al MAS NMR. Due to interest in catalysis supports, special attention was given to the ?-Al{sub 2}O{sub 3} phase, which in addition to structural investigation was subjected to textural analysis. The results showed that, from different synthesis procedures and common route of calcination, one can obtain materials with the same composition but with different structural and textural properties, which in turn can significantly influence the performance of a supported catalyst.

  2. Study of the microstructure of plasma sprayed coatings obtained from Al{sub 2}O{sub 3}–13TiO{sub 2} nanostructured and conventional powders

    SciTech Connect (OSTI)

    Góral, A.; ?órawski, W.; Lity?ska-Dobrzy?ska, L.

    2014-10-15

    The microstructure of coatings obtained from nanostructured or conventional Al{sub 2}O{sub 3}–13TiO{sub 2} powders and deposited by plasma spraying technique on low-carbon steel was examined by transmission electron microscopy techniques. The dominating phase in both coatings was ?-Al{sub 2}O{sub 3} phase. It has been observed that the grains of ?-Al{sub 2}O{sub 3} grew in various shapes and sizes, that are particularly visible in the case of coating sprayed from nanostructured powder. The coatings obtained from the fully melted conventional powders exhibited a typical lamellar microstructure, into which the strips of TiO{sub 2} phase were extended. The microstructure of coatings produced from agglomerates of nanostructured particles also revealed the regions consisting of partially melted ?-Al{sub 2}O{sub 3} powders surrounded by the net-like structure formed from fully melted oxides that improved the coating properties. Along with the observed morphology diversity some changes in the chemical composition on the cross sections of obtained coatings have been also noticed. - Highlights: • Plasma sprayed Al{sub 2}O{sub 3}–13TiO{sub 2} coatings reveal diversity of microstructure. • Microstructure of conventional coating was formed from fully melted crushed powders. • Nanostructured coating contains completely and partially melted initial agglomerates.

  3. Fermilab Today | Brown University Profile

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brown University April 29, 2010 NAME: Brown University HOME TOWN: Providence, Rhode Island MASCOT: Bruno the Bear SCHOOL COLORS: Seal brown and cardinal red PARTICLE PHYSICS...

  4. Ceramic oxide powders and the formation thereof

    DOE Patents [OSTI]

    Katz, Joseph L. (Baltimore, MD); Hung, Cheng-Hung (Baltimore, MD)

    1993-01-01

    Ceramic oxide powders and a method for their preparation. Ceramic oxide powders are obtained using a flame process whereby two or more precursors of ceramic oxides are introduced into a counterflow diffusion flame burner wherein said precursors are converted into ceramic oxide powders. The morphology, particle size, and crystalline form of the ceramic oxide powders are determined by process conditions.

  5. Ceramic oxide powders and the formation thereof

    DOE Patents [OSTI]

    Katz, J.L.; Chenghung Hung.

    1993-12-07

    Ceramic oxide powders and a method for their preparation. Ceramic oxide powders are obtained using a flame process whereby two or more precursors of ceramic oxides are introduced into a counterflow diffusion flame burner wherein said precursors are converted into ceramic oxide powders. The morphology, particle size, and crystalline form of the ceramic oxide powders are determined by process conditions. 14 figures.

  6. Energetic powder

    DOE Patents [OSTI]

    Jorgensen, Betty S. (Jemez Springs, NM); Danen, Wayne C. (Los Alamos, NM)

    2003-12-23

    Fluoroalkylsilane-coated metal particles. The particles have a central metal core, a buffer layer surrounding the core, and a fluoroalkylsilane layer attached to the buffer layer. The particles may be prepared by combining a chemically reactive fluoroalkylsilane compound with an oxide coated metal particle having a hydroxylated surface. The resulting fluoroalkylsilane layer that coats the particles provides them with excellent resistance to aging. The particles can be blended with oxidant particles to form energetic powder that releases chemical energy when the buffer layer is physically disrupted so that the reductant metal core can react with the oxidant.

  7. brown-99.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NCARARM Multiple Antenna Profiler W.O.J. Brown, S. A. Cohn, M. E. Susedik, C. L. Martin, G. Maclean, and D. B. Parsons National Center for Atmospheric Research Atmospheric...

  8. Conversation with Paul Brown | Open Energy Information

    Open Energy Info (EERE)

    Conversation with Paul Brown Jump to: navigation, search OpenEI Reference LibraryAdd to library Personal Communication: Conversation with Paul Brown Author Paul Brown Recipient...

  9. Powder treatment process

    DOE Patents [OSTI]

    Weyand, John D. (Greensburg, PA)

    1988-01-01

    (1) A process comprising spray drying a powder-containing slurry, the slurry containing a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, while reducing the tendency for oxidation of the constituent by including as a liquid constituent of the slurry an organic liquid; (2) a process comprising spray drying a powder-containing slurry, the powder having been pretreated to reduce content of a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, the pretreating comprising heating the powder to react the constituent; and (3) a process comprising reacting ceramic powder, grinding the reacted powder, slurrying the ground powder, spray drying the slurried powder, and blending the dried powder with metal powder.

  10. Powder treatment process

    DOE Patents [OSTI]

    Weyand, J.D.

    1988-02-09

    Disclosed are: (1) a process comprising spray drying a powder-containing slurry, the slurry containing a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, while reducing the tendency for oxidation of the constituent by including as a liquid constituent of the slurry an organic liquid; (2) a process comprising spray drying a powder-containing slurry, the powder having been pretreated to reduce content of a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, the pretreating comprising heating the powder to react the constituent; and (3) a process comprising reacting ceramic powder, grinding the reacted powder, slurrying the ground powder, spray drying the slurried powder, and blending the dried powder with metal powder. 2 figs.

  11. Silica powders for powder evacuated thermal insulating panel and method

    DOE Patents [OSTI]

    Harris, Michael T. (Knoxville, TN); Basaran, Osman A. (Oak Ridge, TN); Kollie, Thomas G. (Oak Ridge, TN); Weaver, Fred J. (Knoxville, TN)

    1994-01-01

    A powder evacuated thermal insulating panel using generally spherical and porous silica particles of a median size less than about 100 nanometers in diameter, a pour packing density of about 0.4 to 0.6 g/cm.sup.3 and an external surface area in the range of about 90 to 600 m.sup.2 /g is described. The silica powders are prepared by reacting a tetraakyl silicate with ammonia and water in an alcohol solvent, distilling the solution after the reaction to remove the ammonia and recover the alcohol. The resulting aqueous slurry was dried, ball-milled, and dried again to provide the silica particles with defined internal and external porosity. The nanometer size and the large external surface area of the silica particles along with the internal and external porosity of the silica particles provide powder evacuated thermal insulating panels with significantly higher R-values than obtainable using previously known silica powders.

  12. Silica powders for powder evacuated thermal insulating panel and method

    DOE Patents [OSTI]

    Harris, Michael T. (Knoxville, TN); Basaran, Osman A. (Oak Ridge, TN); Kollie, Thomas G. (Oak Ridge, TN); Weaver, Fred J. (Knoxville, TN)

    1995-01-01

    A powder evacuated thermal insulating panel using generally spherical and porous silica particles of a median size less than about 100 nanometers in diameter, a pour packing density of about 0.4 to 0.6 g/cm.sup.3 and an external surface area in the range of about 90 to 600 m.sup.2/ g is described. The silica powders are prepared by reacting a tetraakyl silicate with ammonia and water in an alcohol solvent, distilling the solution after the reaction to remove the ammonia and recover the alcohol. The resulting aqueous slurry was dried, ball-milled, and dried again to provide the silica particles with defined internal and external porosity. The nanometer size and the large external surface area of the silica particles along with the internal and external porosity of the silica particles provide powder evacuated thermal insulating panels with significantly higher R-values than obtainable using previously known silica powders.

  13. Silica powders for powder evacuated thermal insulating panel and method

    DOE Patents [OSTI]

    Harris, Michael T. (Knoxville, TN); Basaran, Osman A. (Oak Ridge, TN); Kollie, Thomas G. (Oak Ridge, TN); Weaver, Fred J. (Knoxville, TN)

    1996-01-01

    A powder evacuated thermal insulating panel using generally spherical and porous silica particles of a median size less than about 100 nanometers in diameter, a pour packing density of about 0.4 to 0.6 g/cm.sup.3 and an external surface area in the range of about 90 to 600 m.sup.2/ g is described. The silica powders are prepared by reacting a tetraakyl silicate with ammonia and water in an alcohol solvent, distilling the solution after the reaction to remove the ammonia and recover the alcohol. The resulting aqueous slurry was dried, ball-milled, and dried again to provide the silica particles with defined internal and external porosity. The nanometer size and the large external surface area of the silica particles along with the internal and external porosity of the silica particles provide powder evacuated thermal insulating panels with significantly higher R-values than obtainable using previously known silica powders.

  14. Silica powders for powder evacuated thermal insulating panel and method

    DOE Patents [OSTI]

    Harris, M.T.; Basaran, O.A.; Kollie, T.G.; Weaver, F.J.

    1996-01-02

    A powder evacuated thermal insulating panel using generally spherical and porous silica particles of a median size less than about 100 nanometers in diameter, a pour packing density of about 0.4 to 0.6 g/cm{sup 3} and an external surface area in the range of about 90 to 600 m{sup 2}/g is described. The silica powders are prepared by reacting a tetraalkyl silicate with ammonia and water in an alcohol solvent, distilling the solution after the reaction to remove the ammonia and recover the alcohol. The resulting aqueous slurry was dried, ball-milled, and dried again to provide the silica particles with defined internal and external porosity. The nanometer size and the large external surface area of the silica particles along with the internal and external porosity of the silica particles provide powder evacuated thermal insulating panels with significantly higher R-values than obtainable using previously known silica powders. 2 figs.

  15. Powder dispersion system

    DOE Patents [OSTI]

    Gorenz, Heather M. (Albuquerque, NM); Brockmann, John E. (Albuquerque, NM); Lucero, Daniel A. (Albuquerque, NM)

    2011-09-20

    A powder dispersion method and apparatus comprising an air eductor and a powder dispensing syringe inserted into a suction connection of the air eductor.

  16. NREL: Energy Analysis - Austin Brown

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Austin Brown Photo of Austin Brown Austin Brown is a member of the Washington D.C. Office in the Strategic Energy Analysis Center. Senior Analyst (Strategic Planning) On staff since 2010 Phone number: 202-488-2203 E-mail: austin.brown@nrel.gov Areas of expertise Crosscutting low-carbon strategies Clean transportation technologies and policies Primary research interests Clean energy research portfolio planning Energy and society Sustainable transportation systems Education and background training

  17. Systems and Professional Development - David Brown, Director...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems and Professional Development - David Brown, Director, Systems & Professional Development, OAPM Systems and Professional Development - David Brown, Director, Systems & ...

  18. Preparing titanium nitride powder

    DOE Patents [OSTI]

    Bamberger, Carlos E. (Oak Ridge, TN)

    1989-01-01

    A process for making titanium nitride powder by reaction of titanium phosphates with sodium cyanide.

  19. Preparation of titanium diboride powder

    DOE Patents [OSTI]

    Brynestad, Jorulf (Oak Ridge, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1985-01-01

    Finely-divided titanium diboride or zirconium diboride powders are formed by reacting gaseous boron trichloride with a material selected from the group consisting of titanium powder, zirconium powder, titanium dichloride powder, titanium trichloride powder, and gaseous titanium trichloride.

  20. brown-98.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Resolution Validation in the Shortwave: ASTI/LBLRTM QME P. D. Brown, S. A. Clough, and E. J. Mlawer Atmospheric and Environmental Research, Inc. Cambridge, Massachusetts T. R. Shippert Pacific Northwest National Laboratory Richland, Washington F. J. Murcray Denver University Denver, Colorado Introduction To assess our modeling capability in the shortwave and to resolve issues including those described by Cess et al. (1995) and others (Li and Moreau 1996; Arking 1996), a Quality Measurement

  1. Precision powder feeder

    DOE Patents [OSTI]

    Schlienger, M. Eric (Albuquerque, NM); Schmale, David T. (Albuquerque, NM); Oliver, Michael S. (Sandia Park, NM)

    2001-07-10

    A new class of precision powder feeders is disclosed. These feeders provide a precision flow of a wide range of powdered materials, while remaining robust against jamming or damage. These feeders can be precisely controlled by feedback mechanisms.

  2. brown-pd99.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D. Brown, E. J. Mlawer, and S. A. Clough Atmospheric and Environmental Research, Inc. Cambridge, Massachusetts T. R. Shippert Pacific Northwest National Laboratory Richland,...

  3. Brown County Wind | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name Brown County Wind Facility Brown County Wind Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Adams Electric...

  4. Multiple feed powder splitter

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Less, Richard M. (Los Alamos, NM)

    2002-01-01

    A device for providing uniform powder flow to the nozzles when creating solid structures using a solid fabrication system such as the directed light fabrication (DLF) process. In the DLF process, gas entrained powders are passed through the focal point of a moving high-power laser light which fuses the particles in the powder to a surface being built up in layers. The invention is a device providing uniform flow of gas entrained powders to the nozzles of the DLF system. The device comprises a series of modular splitters which are slidably interconnected and contain an integral flow control mechanism. The device can take the gas entrained powder from between one to four hoppers and split the flow into eight tubular lines which feed the powder delivery nozzles of the DLF system.

  5. Multiple feed powder splitter

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Less, Richard M. (Los Alamos, NM)

    2001-01-01

    A device for providing uniform powder flow to the nozzles when creating solid structures using a solid fabrication system such as the directed light fabrication (DLF) process. In the DLF process, gas entrained powders are passed through the focal point of a moving high-power laser light which fuses the particles in the powder to a surface being built up in layers. The invention is a device providing uniform flow of gas entrained powders to the nozzles of the DLF system. The device comprises a series of modular splitters which are slidably interconnected and contain an integral flow control mechanism. The device can take the gas entrained powder from between one to four hoppers and split the flow into eight tubular lines which feed the powder delivery nozzles of the DLF system.

  6. Jonathan Brown | Center for Gas SeparationsRelevant to Clean Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies | Blandine Jerome Jonathan Brown Previous Next List Brown Jonathan Brown Formerly: PhD Student, Department of Chemistry & Biochemistry University of California, Los Angeles BA in Chemistry, University of Southern California EFRC research: Metal Organic Frameworks (MOFs) are porous crystalline materials, containing organic links and metal oxide secondary building units. Varying the number of organic links can allow us to utilize the MTV principle and obtain specific ratios of

  7. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2003-08-05

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of ternary mixtures consisting of: Ni powder, Cu powder, and Al powder, Ni powder, Cr powder, and Al powder; Ni powder, W powder and Al powder; Ni powder, V powder, and Al powder; Ni powder, Mo powder, and Al powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  8. Counterflow diffusion flame synthesis of ceramic oxide powders

    DOE Patents [OSTI]

    Katz, J.L.; Miquel, P.F.

    1997-07-22

    Ceramic oxide powders and methods for their preparation are revealed. Ceramic oxide powders are obtained using a flame process whereby one or more precursors of ceramic oxides are introduced into a counterflow diffusion flame burner wherein the precursors are converted into ceramic oxide powders. The nature of the ceramic oxide powder produced is determined by process conditions. The morphology, particle size, and crystalline form of the ceramic oxide powders may be varied by the temperature of the flame, the precursor concentration ratio, the gas stream and the gas velocity. 24 figs.

  9. Counterflow diffusion flame synthesis of ceramic oxide powders

    DOE Patents [OSTI]

    Katz, Joseph L.; Miquel, Philippe F.

    1997-01-01

    Ceramic oxide powders and methods for their preparation are revealed. Ceramic oxide powders are obtained using a flame process whereby one or more precursors of ceramic oxides are introduced into a counterflow diffusion flame burner wherein the precursors are converted into ceramic oxide powders. The nature of the ceramic oxide powder produced is determined by process conditions. The morphology, particle size, and crystalline form of the ceramic oxide powders may be varied by the temperature of the flame, the precursor concentration ratio, the gas stream and the gas velocity.

  10. Pyrotechnic filled molding powder

    DOE Patents [OSTI]

    Hartzel, Lawrence W. (Dayton, OH); Kettling, George E. (Cincinnati, OH)

    1978-01-01

    The disclosure relates to thermosetting molding compounds and more particularly to a pyrotechnic filled thermosetting compound comprising a blend of unfilled diallyl phthalate molding powder and a pyrotechnic mixture.

  11. SSRL Powder Diffraction Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    workshop on Practical Aspects of X-ray Powder Diffraction Using Synchrotron Radiation Will be held at SSRL as a part of the 25th Annual Users' Conference Date: Wed., 21st Oct. 1998...

  12. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2004-09-14

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  13. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2003-08-26

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  14. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2004-09-28

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  15. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2005-01-25

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  16. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2003-07-29

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  17. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goval, Amit; Williams, Robert K.; Kroeger, Donald M.

    2005-06-07

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  18. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2003-08-19

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  19. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2005-05-10

    A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  20. brown out | OpenEI Community

    Open Energy Info (EERE)

    brown out Home Dc's picture Submitted by Dc(266) Contributor 31 October, 2014 - 10:58 What do you know about the grid? black out brown out bulk power system electricity grid future...

  1. Ultrafine hydrogen storage powders

    DOE Patents [OSTI]

    Anderson, Iver E. (Ames, IA); Ellis, Timothy W. (Doylestown, PA); Pecharsky, Vitalij K. (Ames, IA); Ting, Jason (Ames, IA); Terpstra, Robert (Ames, IA); Bowman, Robert C. (La Mesa, CA); Witham, Charles K. (Pasadena, CA); Fultz, Brent T. (Pasadena, CA); Bugga, Ratnakumar V. (Arcadia, CA)

    2000-06-13

    A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

  2. Fred L. Brown | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fred L. Brown About Us Fred L. Brown - Deputy Director of Office of Hearings & Appeals Fred L. Brown Administrative Judge Fred L. Brown is Deputy Director of the Office of Hearings and Appeals (OHA) of the U.S. Department of Energy (DOE). OHA is the quasi-judicial arm of DOE that conducts hearings and issues initial Departmental decisions with respect to any adjudicative proceedings which the Secretary may delegate. OHA's jurisdiction includes: deciding Freedom of Information and Privacy Act

  3. Water Outgassing from PBX-9502 powder by isoconversional thermal analysis

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Water Outgassing from PBX-9502 powder by isoconversional thermal analysis Citation Details In-Document Search Title: Water Outgassing from PBX-9502 powder by isoconversional thermal analysis Temperature programmed desorption/decomposition (TPD) were performed on PBX-9502 after 3 hours of vacuum pump. TPD data were analyzed by the technique of isoconversional analysis to obtain outgassing kinetics and moisture content of PBX-9502 powder as well as to

  4. Iowa Powder Atomization Technologies

    ScienceCinema (OSTI)

    None

    2013-03-01

    The same atomization effect seen in a fuel injector is being applied to titanium metal resulting in fine titanium powders that are less than half the width of a human hair. Titanium melts above 3,000°F and is highly corrosive therefore requiring specialized containers. The liquid titanium is poured through an Ames Laboratory - USDOE patented tube which is intended to increase the energy efficiency of the atomization process, which has the ability to dramatically decrease the cost of fine titanium powders. This novel process could open markets for green manufacturing of titanium components from jet engines to biomedical implants.

  5. Iowa Powder Atomization Technologies

    SciTech Connect (OSTI)

    2012-01-01

    The same atomization effect seen in a fuel injector is being applied to titanium metal resulting in fine titanium powders that are less than half the width of a human hair. Titanium melts above 3,000°F and is highly corrosive therefore requiring specialized containers. The liquid titanium is poured through an Ames Laboratory - USDOE patented tube which is intended to increase the energy efficiency of the atomization process, which has the ability to dramatically decrease the cost of fine titanium powders. This novel process could open markets for green manufacturing of titanium components from jet engines to biomedical implants.

  6. Alabama Nuclear Profile - Browns Ferry

    U.S. Energy Information Administration (EIA) Indexed Site

    Browns Ferry" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration date" 1,"1,101","8,072",83.7,"BWR","application/vnd.ms-excel","application/vnd.ms-excel"

  7. Method for synthesizing powder materials

    DOE Patents [OSTI]

    Buss, R.J.; Ho, P.

    1988-01-21

    A method for synthesizing ultrafine powder materials, for example, ceramic and metal powders, comprises admitting gaseous reactants from which the powder material is to be formed into a vacuum reaction chamber maintained at a pressure less than atmospheric and at a temperature less than about 400/degree/K (127/degree/C). The gaseous reactants are directed through a glow discharge provided in the vacuum reaction chamber to form the ultrafine powder material. 1 fig.

  8. Method to blend separator powders

    DOE Patents [OSTI]

    Guidotti, Ronald A. (Albuquerque, NM); Andazola, Arthur H. (Albuquerque, NM); Reinhardt, Frederick W. (Albuquerque, NM)

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  9. Preparation of superconductor precursor powders

    DOE Patents [OSTI]

    Bhattacharya, Raghunath (Littleton, CO)

    1998-01-01

    A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic and/or reduced particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of all metals in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity. Superconductors which can be formed from the precursor powder include pellet and powder-in-tube products.

  10. Jocelyn Brown-Saracino | Department of Energy

    Office of Environmental Management (EM)

    Jocelyn Brown-Saracino About Us Jocelyn Brown-Saracino - Environmental Research Manager, Wind and Water Power Technologies Office FullSizeRender.jpg.jpeg Jocelyn Brown-Saracino manages the environmental research portfolio for the U.S. Department of Energy's Wind and Water Power Technologies Office. In this role, she crafts the strategic direction of the environmental research portfolio and supervises projects aimed at measuring, mitigating, and sharing information on the environmental impacts of

  11. Women @ Energy: Nancy Brown | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Nancy Jeanne Brown is a Senior Scientist at the Lawrence Berkeley National Laboratory. Dr. Nancy Jeanne Brown is a Senior Scientist at the Lawrence Berkeley National Laboratory. Check out other profiles in the Women @ Energy series and share your favorites on Pinterest. Dr. Nancy Jeanne Brown is a Senior Scientist at the Lawrence Berkeley National Laboratory. Her research interests are atmospheric science, chemical kinetics, air quality and climate modeling, high performance computing, and

  12. CMI Education Partner: Brown University | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Education Partner: Brown University Brown University offers courses in several areas: Engineering School Institute of Environment and Study Brown University: Engineering School http://www.brown.edu/academics/engineering/undergraduate-study/courses ENGN 0030 - Introduction to Engineering: An introduction to various engineering disciplines, thought processes, and issues. Topics include computing in engineering, engineering design, optimization, and estimation. Case studies in engineering are used

  13. Preparation of superconductor precursor powders

    DOE Patents [OSTI]

    Bhattacharya, R.

    1998-08-04

    A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic and/or reduced particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of all metals in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity. Superconductors which can be formed from the precursor powder include pellet and powder-in-tube products. 7 figs.

  14. Preparation of superconductor precursor powders

    DOE Patents [OSTI]

    Bhattacharya, Raghunath (Littleton, CO); Blaugher, Richard D. (Evergreen, CO)

    1995-01-01

    A process for the preparation of a precursor metallic powder composition for use in the subsequent formation of a superconductor. The process comprises the steps of providing an electrodeposition bath comprising an electrolyte medium and a cathode substrate electrode, and providing to the bath one or more soluble salts of one or more respective metals, such as nitrate salts of thallium, barium, calcium, and copper, which are capable of exhibiting superconductor properties upon subsequent appropriate treatment. The bath is continually energized to cause the metallic particles formed at the electrode to drop as a powder from the electrode into the bath, and this powder, which is a precursor powder for superconductor production, is recovered from the bath for subsequent treatment. The process permits direct inclusion of thallium in the preparation of the precursor powder, and yields an amorphous product mixed on an atomic scale to thereby impart inherent high reactivity. Superconductors which can be formed from the precursor powder include pellet and powder-in-tube products.

  15. Method for molding ceramic powders

    DOE Patents [OSTI]

    Janney, Mark A. (Knoxville, TN)

    1990-01-01

    A method for molding ceramic powders comprises forming a slurry mixture including ceramic powder, a dispersant for the metal-containing powder, and a monomer solution. The monomer solution includes at least one multifunctional monomer, a free-radical initiator, and an organic solvent. The slurry mixture is transferred to a mold, and the mold containing the slurry mixture is heated to polymerize and crosslink the monomer and form a firm polymer-solvent gel matrix. The solid product may be removed from the mold and heated to first remove the solvent and subsequently remove the polymer, whereafter the product may be sintered.

  16. Method for molding ceramic powders

    DOE Patents [OSTI]

    Janney, M.A.

    1990-01-16

    A method for molding ceramic powders comprises forming a slurry mixture including ceramic powder, a dispersant for the metal-containing powder, and a monomer solution. The monomer solution includes at least one multifunctional monomer, a free-radical initiator, and an organic solvent. The slurry mixture is transferred to a mold, and the mold containing the slurry mixture is heated to polymerize and crosslink the monomer and form a firm polymer-solvent gel matrix. The solid product may be removed from the mold and heated to first remove the solvent and subsequently remove the polymer, where after the product may be sintered.

  17. Microsoft PowerPoint - 7 Kevin Brown

    Office of Environmental Management (EM)

    (CBP) Toolsets Kevin G. Brown Vanderbilt University and CRESP Cementitious Barriers Partnership Performance & Risk Assessment Community of Practice Technical Exchange Meeting December 11-12, 2014 Las Vegas NM Project Team Members Vanderbilt University & CRESP D. Kosson*, K.G. Brown*, S. Mahadevan, J. Branch, F. Sanchez Savannah River National Laboratory (SRNL) C. Langton*, G. Flach*, H. Burns*, R. Seitz, S. Marra Energy Research Centre of The Netherlands (ECN) & CRESP H. van der

  18. Rotary powder feed through apparatus

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Less, Richard M. (Los Alamos, NM)

    2001-01-01

    A device for increasing the uniformity of solids within a solids fabrication system, such as a direct light fabrication (DLF) system in which gas entrained powders are passed through the focal point of a moving high-power light which fuses the particles in the powder to a surface being built up in layers. The invention provides a feed through interface wherein gas entrained powders input from stationary input lines are coupled to a rotating head of the fabrication system. The invention eliminates the need to provide additional slack in the feed lines to accommodate head rotation, and therefore reduces feed line bending movements which induce non-uniform feeding of gas entrained powder to a rotating head.

  19. Neutron detectors comprising boron powder

    DOE Patents [OSTI]

    Wang, Zhehui; Morris, Christopher; Bacon, Jeffrey Darnell; Makela, Mark F; Spaulding, Randy Jay

    2013-05-21

    High-efficiency neutron detector substrate assemblies comprising a first conductive substrate, wherein a first side of the substrate is in direct contact with a first layer of a powder material comprising .sup.10boron, .sup.10boron carbide or combinations thereof, and wherein a conductive material is in proximity to the first layer of powder material; and processes of making said neutron detector substrate assemblies.

  20. Powder collection apparatus/method

    DOE Patents [OSTI]

    Anderson, I.E.; Terpstra, R.L.; Moore, J.A.

    1994-01-11

    Device for separating and collecting ultrafine atomized powder from the gas stream of a gas atomizing apparatus comprises a housing having an interior wall oriented at an angle relative to horizontal so as to form a downwardly converging, conical expansion chamber, an inlet conduit communicated to the expansion chamber proximate an upper region thereof for receiving the gas stream, and an outlet proximate a lower region of the expansion chamber. The inlet conduit is oriented at a compound inclined angle (with respect to horizontal) selected to promote separation and collection of powder from the gas stream in the expansion chamber. The compound angle comprises a first entrance angle that is greater than the angle of repose of the powder on the housing interior wall such that any powder accumulation in the inlet conduit tends to flow down the wall toward the outlet. The second angle is selected generally equal to the angle of the housing interior wall measured from the same horizontal plane so as to direct the gas stream into the expansion chamber generally tangent to the housing interior wall to establish a downward swirling gas stream flow in the expansion chamber. A powder collection container is communicated to the outlet of the expansion chamber to collect the powder for further processing. 4 figures.

  1. From: Doris Brown To: Congestion Study Comments Subject: NIETCs

    Office of Environmental Management (EM)

    Doris Brown To: Congestion Study Comments Subject: NIETCs Date: Monday, October 20, 2014 2:47:39 PM I am opposed to the establishment of National Interest Energy Transmission Corridors (NIETC's) Easements for the corridors will mainly have to be obtained through eminent domain. Compensation for the easements can only be "just" as required in the Bill of Rights if it reflects all the possibilities of what the easement may be used for. Utilities do not want to farm the land, so farming

  2. Craig Brown | Center for Gas SeparationsRelevant to Clean Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Craig Brown Previous Next List CraigBrown Craig Brown Team leader for crystallography and diffraction applications, Center for Neutron Research, National Institute of Standards and...

  3. Brown-Atchison E C A Inc | Open Energy Information

    Open Energy Info (EERE)

    Brown-Atchison E C A Inc Jump to: navigation, search Name: Brown-Atchison E C A Inc Place: Kansas Phone Number: 785-486-2117 Website: baelectric.com Outage Hotline: After Hours:...

  4. FIA-12-0009- In the Matter of Cynthia Brown

    Broader source: Energy.gov [DOE]

    Cynthia Brown filed an Appeal regarding a request she filed under the Freedom of Information Act. In December 2011, Ms. Brown filed a request for records regarding her late mother.

  5. Chelsea Brown | Center for Bio-Inspired Solar Fuel Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brown Graduate student Subtask 4 project: "Water Oxidation using Functionalized Porphyrin Chromophores and Iridium Catalyst"

  6. Polymer quenched prealloyed metal powder

    DOE Patents [OSTI]

    Hajaligol, Mohammad R.; Fleischhauer, Grier; German, Randall M.

    2001-01-01

    A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3 % Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

  7. L. A. Brown, M. C. Higuera

    Office of Scientific and Technical Information (OSTI)

    L. A. Brown, M. C. Higuera Prepared by Sandia National Laboratories Albuquerque, New Mexico 87185 and L b SANDlA REPORT SAND974017 0 UC-700 Unlimited Release Printed February i 998 Weapon Container Catalog Volumes 1 & 2 -_ Issued by Sandia National Laboratories, operated for the United States Department of Energy by Sandia Corporation. NOTICE: This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Govern- ment nor any

  8. Microsoft PowerPoint - 1 Kevin Brown

    Office of Environmental Management (EM)

    Program Update Interagency Steering Committee on Performance and Risk Assessment Community of Practice Annual Technical Exchange Meeting Richland, Washington December 15-16, 2015 Project Team Members Vanderbilt University & CRESP D. Kosson*, K.G. Brown*, A.C. Garrabrants, S. Mahadevan, J. Branch, F. Sanchez Savannah River National Laboratory (SRNL) C. Langton*; G. Flach*; H. Burns*; R. Seitz, S. Marra; F.G. Smith, III Energy Research Centre of The Netherlands (ECN) & CRESP H. van der

  9. Characteristics of alumina powders prepared by spray-drying of boehmite sol

    SciTech Connect (OSTI)

    Varma, H.K.; Mani, T.V.; Damodaran, A.D.; Warrier, K.G. ); Balachandran, U. . Energy Technology Div.)

    1994-06-01

    Boehmite sol prepared from aluminum nitrate has been spray-dried to obtain micrometer-size spherical particles consisting of submicrometer crystallites. The spray-dried powder was further washed with solvents of varying polarities such as acetone, 2-propanol, and 2-methyl-2-propanol. Particle-size distribution, morphology, density, compaction, and sintering characteristics of powders washed with different solvents are reported. The effect of post treatments on the boehmite-sol-derived powders toward reducing agglomeration and obtaining high-density bodies is discussed.

  10. Trends in powder processing equipment

    SciTech Connect (OSTI)

    Sheppard, L.M.

    1993-05-01

    Spray drying is the most widely used process for producing particles. It is used in industries other than ceramics including food, chemicals, and pharmaceutical. The process involves the atomization of a liquid feed stock into a spray of droplets and contacting the droplets with hot air in a drying chamber. The sprays are produced by either rotary or nozzle atomizers. Evaporation of moisture from the droplets and formation of dry particles proceed under controlled temperature and airflow conditions. Powder is then discharged continuously from the drying chamber. Spray drying equipment is being improved to handle an ever-increasing number of applications. Several developments in particle-size reduction equipment are also described.

  11. Browning: Email in Response to Smart Grid Request for Information |

    Energy Savers [EERE]

    Department of Energy Browning: Email in Response to Smart Grid Request for Information Browning: Email in Response to Smart Grid Request for Information Email from Stephen Browning explaing the two attachments submitted in response to the Smart Grid Request for Information on Addressing Policy and Logistical Challenges. PDF icon Smart Gird Policy Memo More Documents & Publications Power North America RFI Comments Pensacola Smart Grid RFI Addressing Policy and Logistical Challenges City

  12. High throughput screening of ligand binding to macromolecules using high resolution powder diffraction

    DOE Patents [OSTI]

    Von Dreele, Robert B.; D'Amico, Kevin

    2006-10-31

    A process is provided for the high throughput screening of binding of ligands to macromolecules using high resolution powder diffraction data including producing a first sample slurry of a selected polycrystalline macromolecule material and a solvent, producing a second sample slurry of a selected polycrystalline macromolecule material, one or more ligands and the solvent, obtaining a high resolution powder diffraction pattern on each of said first sample slurry and the second sample slurry, and, comparing the high resolution powder diffraction pattern of the first sample slurry and the high resolution powder diffraction pattern of the second sample slurry whereby a difference in the high resolution powder diffraction patterns of the first sample slurry and the second sample slurry provides a positive indication for the formation of a complex between the selected polycrystalline macromolecule material and at least one of the one or more ligands.

  13. MEMORANDUM FROM: THOMAS E. BROWN, DIRECTOR OFFICE OF CONTRACT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ,2008 MEMORANDUM FROM: THOMAS E. BROWN, DIRECTOR OFFICE OF CONTRACT MANAGEMENT OFFICE OF PROCUREMENT AND ASSISTANCE MANAGEMENT SUBJECT: Contract Change Order Administration of...

  14. Senior Obama Administration Officials to Join Governor Brown...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secretary Daniel Poneman will join California Governor Jerry Brown, Los Angeles Mayor Eric Garcetti and state, local and tribal leaders from across the country for a media...

  15. Flow Test At Fenton Hill HDR Geothermal Area (Brown, 1995) |...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At Fenton Hill HDR Geothermal Area (Brown, 1995) Exploration Activity Details Location...

  16. Flow Test At Fenton Hill HDR Geothermal Area (Brown, 1994) |...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At Fenton Hill HDR Geothermal Area (Brown, 1994) Exploration Activity Details Location...

  17. Process for the synthesis of iron powder

    DOE Patents [OSTI]

    Welbon, William W. (Belleair, FL)

    1983-01-01

    A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

  18. Process for the synthesis of iron powder

    DOE Patents [OSTI]

    Not Available

    1982-03-06

    A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

  19. Process for the synthesis of iron powder

    DOE Patents [OSTI]

    Welbon, W.W.

    1983-11-08

    A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder. 2 figs.

  20. Ultrafine Hydrogen Storage Powders - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Find More Like This Return to Search Ultrafine Hydrogen Storage Powders Ames Laboratory Contact AMES ...

  1. CHARACTERIZING THE BROWN DWARF FORMATION CHANNELS FROM THE INITIAL MASS FUNCTION AND BINARY-STAR DYNAMICS

    SciTech Connect (OSTI)

    Thies, Ingo; Pflamm-Altenburg, Jan; Kroupa, Pavel; Marks, Michael

    2015-02-10

    The stellar initial mass function (IMF) is a key property of stellar populations. There is growing evidence that the classical star-formation mechanism by the direct cloud fragmentation process has difficulties reproducing the observed abundance and binary properties of brown dwarfs and very-low-mass stars. In particular, recent analytical derivations of the stellar IMF exhibit a deficit of brown dwarfs compared to observational data. Here we derive the residual mass function of brown dwarfs as an empirical measure of the brown dwarf deficiency in recent star-formation models with respect to observations and show that it is compatible with the substellar part of the Thies-Kroupa IMF and the mass function obtained by numerical simulations. We conclude that the existing models may be further improved by including a substellar correction term that accounts for additional formation channels like disk or filament fragmentation. The term ''peripheral fragmentation'' is introduced here for such additional formation channels. In addition, we present an updated analytical model of stellar and substellar binarity. The resulting binary fraction and the dynamically evolved companion mass-ratio distribution are in good agreement with observational data on stellar and very-low-mass binaries in the Galactic field, in clusters, and in dynamically unprocessed groups of stars if all stars form as binaries with stellar companions. Cautionary notes are given on the proper analysis of mass functions and the companion mass-ratio distribution and the interpretation of the results. The existence of accretion disks around young brown dwarfs does not imply that these form just like stars in direct fragmentation.

  2. Systems and Professional Development - David Brown, Director, Systems &

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Professional Development, OAPM | Department of Energy Systems and Professional Development - David Brown, Director, Systems & Professional Development, OAPM Systems and Professional Development - David Brown, Director, Systems & Professional Development, OAPM Topics Discussed: Importance of Contracting in DOE Compared with Other Civilian Agencies Professional Workforce Workload DOE's Certified Workforce Acquisition Workload The Holy Grail of Contract and Project Management More...

  3. Hydrodesulfurization and hydrodenitrogenation catalysts obtained from coal mineral matter

    DOE Patents [OSTI]

    Liu, Kindtoken H. D. (Newark, DE); Hamrin, Jr., Charles E. (Lexington, KY)

    1982-01-01

    A hydrotreating catalyst is prepared from coal mineral matter obtained by low temperature ashing coals of relatively low bassanite content by the steps of: (a) depositing on the low temperature ash 0.25-3 grams of an iron or nickel salt in water per gram of ash and drying a resulting slurry; (b) crushing and sizing a resulting solid; and (c) heating the thus-sized solid powder in hydrogen.

  4. Novel Solvent System for Post Combustion CO{sub 2} Capture Brown...

    Office of Scientific and Technical Information (OSTI)

    COsub 2 Capture Brown, Alfred; Brown, Nathan 20 FOSSIL-FUELED POWER PLANTS Clean Coal Technology Coal - Environmental (Carbon Capture) Clean Coal Technology Coal -...

  5. Wet powder seal for gas containment

    DOE Patents [OSTI]

    Stang, Louis G. (Sayville, NY)

    1982-01-01

    A gas seal is formed by a compact layer of an insoluble powder and liquid filling the fine interstices of that layer. The smaller the particle size of the selected powder, such as sand or talc, the finer will be the interstices or capillary spaces in the layer and the greater will be the resulting sealing capacity, i.e., the gas pressure differential which the wet powder layer can withstand. Such wet powder seal is useful in constructing underground gas reservoirs or storage cavities for nuclear wastes as well as stopping leaks in gas mains buried under ground or situated under water. The sealing capacity of the wet powder seal can be augmented by the hydrostatic head of a liquid body established over the seal.

  6. Water Outgassing from PBX-9502 powder by isoconversional thermal...

    Office of Scientific and Technical Information (OSTI)

    Water Outgassing from PBX-9502 powder by isoconversional thermal analysis Citation Details In-Document Search Title: Water Outgassing from PBX-9502 powder by isoconversional ...

  7. Solid State Processing of New Low Cost Titanium Powders Enabling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processing of New Low Cost Titanium Powders Enabling Affordable Automotive Components Solid State Processing of New Low Cost Titanium Powders Enabling Affordable Automotive...

  8. Preparation and performances of nanosized Ta{sub 2}O{sub 5} powder photocatalyst

    SciTech Connect (OSTI)

    Zhu Yongfa . E-mail: zhuyf@chem.tsinghua.edu.cn; Yu Fang; Man, Yi; Tian, Qingyong; He Yu; Wu Nianzu

    2005-01-15

    Nanosized-Ta{sub 2}O{sub 5} powder photocatalyst was successfully synthesized by using sol-gel method via TaCl{sub 5} butanol solution as a precursor. Ta{sub 2}O{sub 5} species can be formed under 500 deg. C via the decomposition of the precursor. The crystalline phase of Ta{sub 2}O{sub 5} powder photocatalyst can be obtained after being calcined above 600 deg. C for 4h. The crystal size and particle size of Ta{sub 2}O{sub 5} powder photocatalyst was about 50nm. A good photocatalytic performance for the degradation of gaseous formaldehyde was obtained for the nanosized-Ta{sub 2}O{sub 5} powder. The Ta{sub 2}O{sub 5} powder formed at 700 deg. C for 4h and at 650 deg. C for 12h showed the best performance. The calcination temperature and time play an important role in the crystallization and photocatalytical performance of nanosized-Ta{sub 2}O{sub 5} powder.

  9. Powder Dropper | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The amount of powder or dust that is released is controlled by adjusting the amplitude and frequency of the vibration. No.: M-800 Inventor(s): A. L Roquemore Dennis K Mansfield...

  10. Synthesis and processing of monosized oxide powders

    DOE Patents [OSTI]

    Barringer, Eric A. (Waltham, MA); Fegley, Jr., M. Bruce (Waban, MA); Bowen, H. Kent (Belmont, MA)

    1985-01-01

    Uniform-size, high-purity, spherical oxide powders are formed by hydrolysis of alkoxide precursors in dilute alcoholic solutions. Under controlled conditions (concentrations of 0.03 to 0.2 M alkoxide and 0.2 to 1.5 M water, for example) oxide particles on the order of about 0.05 to 0.7 micron can be produced. Methods of doping such powders and forming sinterable compacts are also disclosed.

  11. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit (Knoxville, TN); Williams, Robert K. (Knoxville, TN)

    2001-01-01

    A biaxially textured alloy article comprises Ni powder and at least one powder selected from the group consisting of Cr, W, V, Mo, Cu, Al, Ce, YSZ, Y, Rare Earths, (RE), MgO, CeO.sub.2, and Y.sub.2 O.sub.3 ; compacted and heat treated, then rapidly recrystallized to produce a biaxial texture on the article. In some embodiments the alloy article further comprises electromagnetic or electro-optical devices and possesses superconducting properties.

  12. Synthesis and processing of monosized oxide powders

    DOE Patents [OSTI]

    Barringer, E.A.; Fegley, M.B. Jr.; Bowen, H.K.

    1985-09-24

    Uniform-size, high-purity, spherical oxide powders are formed by hydrolysis of alkoxide precursors in dilute alcoholic solutions. Under controlled conditions (concentrations of 0.03 to 0.2 M alkoxide and 0.2 to 1.5 M water, for example) oxide particles on the order of about 0.05 to 0.7 microns can be produced. Methods of doping such powders and forming sinterable compacts are also disclosed. 6 figs.

  13. Synthesis of nanoscale magnesium diboride powder

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Finnemore, D. K.; Marzik, J. V.

    2015-12-18

    A procedure has been developed for the preparation of small grained magnesium diboride (MgB2) powder by reacting nanometer size boron powder in a magnesium vapor. Plasma synthesized boron powder that had particle sizes ranging from 20 to 300nm was mixed with millimeter size chunks of Mg by rolling stoichiometric amounts of the powders in a sealed cylindrical container under nitrogen gas. This mixture then was placed in a niobium reaction vessel, evacuated, and sealed by e-beam welding. The vessel was typically heated to approximately 830°C for several hours. The resulting MgB2 particles have a grain size in the 200 nmmore » to 800 nm range. Agglomerates of loosely bound particles could be broken up by light grinding in a mortar and pestle. At 830°C, many particles are composed of several grains grown together so that the average particle size is about twice the average grain size. Furthermore, experiments were conducted primarily with undoped boron powder, but carbon-doped boron powder showed very similar results.« less

  14. Brown County, Ohio: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in Ohio. Its FIPS County Code is 015. It is classified as ASHRAE...

  15. Brown County, Indiana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in Indiana. Its FIPS County Code is 013. It is classified as ASHRAE...

  16. Brown County, Kansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in Kansas. Its FIPS County Code is 013. It is classified as ASHRAE...

  17. Brown County, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in Minnesota. Its FIPS County Code is 015. It is classified as...

  18. Brown County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in Texas. Its FIPS County Code is 049. It is classified as ASHRAE...

  19. Brown County, South Dakota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in South Dakota. Its FIPS County Code is 013. It is classified as...

  20. Brown County, Nebraska: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in Nebraska. Its FIPS County Code is 017. It is classified as...

  1. Brown County, Wisconsin: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in Wisconsin. Its FIPS County Code is 009. It is classified as...

  2. Brown County Rural Elec Assn | Open Energy Information

    Open Energy Info (EERE)

    Rural Elec Assn Jump to: navigation, search Name: Brown County Rural Elec Assn Place: Minnesota Phone Number: 1-800-658-2368 Website: www.browncountyrea.coop Outage Hotline:...

  3. Brown County, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Brown County is a county in Illinois. Its FIPS County Code is 009. It is classified as...

  4. 1,"Browns Ferry","Nuclear","Tennessee Valley Authority",3309...

    U.S. Energy Information Administration (EIA) Indexed Site

    Alabama" ,"Plant","Primary energy source","Operating company","Net summer capacity (MW)" 1,"Browns Ferry","Nuclear","Tennessee Valley Authority",3309.4 2,"James H Miller ...

  5. Brown Grease to Biodiesel Demonstration Project Report (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect SciTech Connect Search Results Technical Report: Brown Grease to Biodiesel Demonstration Project Report Citation Details In-Document Search Title: Brown Grease to Biodiesel Demonstration Project Report Municipal wastewater treatment facilities have typically been limited to the role of accepting wastewater, treating it to required levels, and disposing of its treatment residuals. However, a new view is emerging which includes wastewater treatment facilities as regional

  6. DOE - Office of Legacy Management -- Brown University - Metcalf Research

    Office of Legacy Management (LM)

    Lab - RI 01 Brown University - Metcalf Research Lab - RI 01 FUSRAP Considered Sites Site: Brown University (Metcalf Research Lab.) (RI.01 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Providence , Rhode Island RI.01-1 Evaluation Year: 1987 RI.01-1 Site Operations: Research/Development on the preparation of pure halides of heavy metals, Bench Scale Process, and Sample & Analysis. RI.01-1 Site Disposition: Eliminated -

  7. Craig Brown | Center for Gas SeparationsRelevant to Clean Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies | Blandine Jerome Craig Brown Previous Next List CraigBrown Craig Brown Team leader for crystallography and diffraction applications, Center for Neutron Research, National Institute of Standards and Technology Email: craig.brown [at] nist.gov Phone: (301) 975-5134 EFRC research: Craig Brown is an Associated Investigator involved in the characterization of MOFs with in-situ neutron scattering techniques. EFRC publications: Lee, Jason S.; Vlaisavljevich, Bess; Britt, David K.;

  8. Slip casting nano-particle powders for making transparent ceramics

    DOE Patents [OSTI]

    Kuntz, Joshua D. (Livermore, CA); Soules, Thomas F. (Livermore, CA); Landingham, Richard Lee (Livermore, CA); Hollingsworth, Joel P. (Oakland, CA)

    2011-04-12

    A method of making a transparent ceramic including the steps of providing nano-ceramic powders in a processed or unprocessed form, mixing the powders with de-ionized water, the step of mixing the powders with de-ionized water producing a slurry, sonifing the slurry to completely wet the powder and suspend the powder in the de-ionized water, separating very fine particles from the slurry, molding the slurry, and curing the slurry to produce the transparent ceramic.

  9. QER - Comment of Powder River Energy Corporation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Powder River Energy Corporation QER - Comment of Powder River Energy Corporation From: Mike Easley [mikee@precorp.coop] Sent: Wednesday, August 20, 2014 11:59 PM To: QERcomments Subject: Comment on the QER Public Meeting in Cheyenne, WY: Infrastructure Siting Attachment: Michael Easley CEO Powder River Energy Corporation - Statement.pdf Statement of Michael E Easley Panel 1-Electric Infrastructure Siting Best Regards, Mike Michael Easley CEO Powder River Energy Corporation Powder River Energy,

  10. Iowa Powder Atomization Technologies, Inc. | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Iowa Powder Atomization Technologies, Inc. America's Next Top Energy Innovator Challenge 6067 likes Iowa Powder Atomization Technologies, Inc. Ames Laboratory Iowa Powder Atomization Technologies, Inc. (IPAT) aims to become a leading domestic titanium powder producer allowing for a paradigm shift in the cost of titanium powders for metal injection molding (MIM) feedstock. Decreasing this cost will create vast opportunities for aerospace, military, biomedical, and consumer applications. Titanium

  11. Iowa Powder Atomization Technologies, Inc. | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iowa Powder Atomization Technologies, Inc. America's Next Top Energy Innovator Challenge 6067 likes Iowa Powder Atomization Technologies, Inc. Ames Laboratory Iowa Powder Atomization Technologies, Inc. (IPAT) aims to become a leading domestic titanium powder producer allowing for a paradigm shift in the cost of titanium powders for metal injection molding (MIM) feedstock. Decreasing this cost will create vast opportunities for aerospace, military, biomedical, and consumer applications. Titanium

  12. Die-target for dynamic powder consolidation

    DOE Patents [OSTI]

    Flinn, John E. (Idaho Falls, ID); Korth, Gary E. (Blackfoot, ID)

    1986-01-01

    A die/target is disclosed for consolidation of a powder, especially an atomized rapidly solidified metal powder, to produce monoliths by the dynamic action of a shock wave, especially a shock wave produced by the detonation of an explosive charge. The die/target comprises a rectangular metal block having a square primary surface with four rectangular mold cavities formed therein to receive the powder. The cavities are located away from the geometrical center of the primary surface and are distributed around such center while also being located away from the geometrical diagonals of the primary surface to reduce the action of reflected waves so as to avoid tensile cracking of the monoliths. The primary surface is covered by a powder retention plate which is engaged by a flyer plate to transmit the shock wave to the primary surface and the powder. Spawl plates are adhesively mounted on other surfaces of the block to act as momentum traps so as to reduce reflected waves in the block.

  13. Die-target for dynamic powder consolidation

    DOE Patents [OSTI]

    Flinn, J.E.; Korth, G.E.

    1985-06-27

    A die/target is disclosed for consolidation of a powder, especially an atomized rapidly solidified metal powder, to produce monoliths by the dynamic action of a shock wave, especially a shock wave produced by the detonation of an explosive charge. The die/target comprises a rectangular metal block having a square primary surface with four rectangular mold cavities formed therein to receive the powder. The cavities are located away from the geometrical center of the primary surface and are distributed around such center while also being located away from the geometrical diagonals of the primary surface to reduce the action of reflected waves so as to avoid tensile cracking of the monoliths. The primary surface is covered by a powder retention plate which is engaged by a flyer plate to transmit the shock wave to the primary surface and the powder. Spawl plates are adhesively mounted on other surfaces of the block to act as momentum traps so as to reduce reflected waves in the block. 4 figs.

  14. Biaxially textured articles formed by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit; Williams, Robert K.; Kroeger, Donald M.

    2003-10-21

    A strengthened, biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed, compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: Ni, Ag, Ag--Cu, Ag--Pd, Ni--Cu, Ni--V, Ni--Mo, Ni--Al, Ni--Cr--Al, Ni--W--Al, Ni--V--Al, Ni--Mo--Al, Ni--Cu--Al; and at least one fine metal oxide powder; the article having a grain size which is fine and homogeneous; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.

  15. Atomization methods for forming magnet powders

    DOE Patents [OSTI]

    Sellers, Charles H.; Branagan, Daniel J.; Hyde, Timothy A.

    2000-01-01

    The invention encompasses methods of utilizing atomization, methods for forming magnet powders, methods for forming magnets, and methods for forming bonded magnets. The invention further encompasses methods for simulating atomization conditions. In one aspect, the invention includes an atomization method for forming a magnet powder comprising: a) forming a melt comprising R.sub.2.1 Q.sub.13.9 B.sub.1, Z and X, wherein R is a rare earth element; X is an element selected from the group consisting of carbon, nitrogen, oxygen and mixtures thereof; Q is an element selected from the group consisting of Fe, Co and mixtures thereof; and Z is an element selected from the group consisting of Ti, Zr, Hf and mixtures thereof; b) atomizing the melt to form generally spherical alloy powder granules having an internal structure comprising at least one of a substantially amorphous phase or a substantially nanocrystalline phase; and c) heat treating the alloy powder to increase an energy product of the alloy powder; after the heat treatment, the alloy powder comprising an energy product of at least 10 MGOe. In another aspect, the invention includes a magnet comprising R, Q, B, Z and X, wherein R is a rare earth element; X is an element selected from the group consisting of carbon, nitrogen, oxygen and mixtures thereof; Q is an element selected from the group consisting of Fe, Co and mixtures thereof; and Z is an element selected from the group consisting of Ti, Zr, Hf and mixtures thereof; the magnet comprising an internal structure comprising R.sub.2.1 Q.sub.13.9 B.sub.1.

  16. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1994-01-01

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft.

  17. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1995-12-26

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft. 3 figs.

  18. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1994-12-06

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft. 3 figures.

  19. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1995-01-01

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft.

  20. Desensitizing nano powders to electrostatic discharge ignition

    SciTech Connect (OSTI)

    Steelman, Ryan; Clark, Billy; Pantoya, Michelle L.; Heaps, Ronald J.; Daniels, Michael A.

    2015-08-01

    Electrostatic discharge (ESD) is a main cause for ignition in powder media ranging from grain silos to fireworks. Nanoscale particles are orders of magnitude more ESD ignition sensitive than their micron scale counterparts. This study shows that at least 13 vol. % carbon nanotubes (CNT) added to nano-aluminum and nano-copper oxide particles (nAl + CuO) eliminates ESD ignition sensitivity. The CNT act as a conduit for electric energy and directs electric charge through the powder to desensitize the reactive mixture to ignition. For nanoparticles, the required CNT concentration for desensitizing ESD ignition acts as a diluent to quench energy propagation.

  1. Advanced NDE Technologies for Powder Metal Components

    SciTech Connect (OSTI)

    Martin, P; Haskins, J; Thomas, G; Dolan, K

    2003-05-01

    Nondestructive evaluation encompasses numerous technologies that assess materials and determine important properties. This paper demonstrates the applicability of several of these technologies to the field of powder metallurgy. The usual application of nondestructive evaluation is to detect and quantify defects in fully sintered product. But probably its most appealing role is to sense problems earlier in the manufacturing process to avoid making defects at all. Also nondestructive evaluation can be incorporated into the manufacturing processes to monitor important parameters and control the processes to produce defect free product. Nondestructive evaluation can characterize powders, evaluate components in the green state, monitor the sintering process, and inspect the final component.

  2. Synthesis of ultrafine powders by microwave heating

    DOE Patents [OSTI]

    Meek, Thomas T. (Knoxville, TN); Sheinberg, Haskell (Los Alamos, NM); Blake, Rodger D. (Santa Fe, NM)

    1988-01-01

    A method of synthesizing ultrafine powders using microwaves is described. A water soluble material is dissolved in water and the resulting aqueous solution is exposed to microwaves until the water has been removed. The resulting material is an ultrafine powder. This method can be used to make Al.sub.2 O.sub.3, NiO+Al.sub.2 O.sub.3 and NiO as well as a number of other materials including GaBa.sub.2 Cu.sub.3 O.sub.x.

  3. Synthesis of ultrafine powders by microwave heating

    DOE Patents [OSTI]

    Meek, T.T.; Sheinberg, H.; Blake, R.D.

    1987-04-24

    A method of synthesizing ultrafine powders using microwaves is described. A water soluble material is dissolved in water and the resulting aqueous solution is exposed to microwaves until the water has dissolved. The resulting material is an ultrafine powder. This method can be used to make Al/sub 2/O/sub 3/, NiO /plus/ Al/sub 2/O/sub 3/ and NiO as well as a number of other materials including GaBa/sub 2/Cu/sub 3/O/sub x/. 1 tab.

  4. High-Pressure and High-Temperature Powder Diffraction (Journal...

    Office of Scientific and Technical Information (OSTI)

    High-Pressure and High-Temperature Powder Diffraction Citation Details In-Document Search Title: High-Pressure and High-Temperature Powder Diffraction Authors: Fei, Yingwei ; Wang, ...

  5. Total-scattering pair-distribution function of organic material from powder electron diffraction data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gorelik, Tatiana E.; Billinge, Simon J. L.; Schmidt, Martin U.; Kolb, Ute

    2015-04-01

    This paper shows for the first time that pair-distribution function analyses can be carried out on organic and organo-metallic compounds from powder electron diffraction data. Different experimental setups are demonstrated, including selected area electron diffraction (SAED) and nanodiffraction in transmission electron microscopy (TEM) or nanodiffraction in scanning transmission electron microscopy (STEM) modes. The methods were demonstrated on organo-metallic complexes (chlorinated and unchlorinated copper-phthalocyanine) and on purely organic compounds (quinacridone). The PDF curves from powder electron diffraction data, called ePDF, are in good agreement with PDF curves determined from X-ray powder data demonstrating that the problems of obtaining kinematical scattering datamore » and avoiding beam-damage of the sample are possible to resolve.« less

  6. Total-scattering pair-distribution function of organic material from powder electron diffraction data

    SciTech Connect (OSTI)

    Gorelik, Tatiana E.; Billinge, Simon J. L.; Schmidt, Martin U.; Kolb, Ute

    2015-04-01

    This paper shows for the first time that pair-distribution function analyses can be carried out on organic and organo-metallic compounds from powder electron diffraction data. Different experimental setups are demonstrated, including selected area electron diffraction (SAED) and nanodiffraction in transmission electron microscopy (TEM) or nanodiffraction in scanning transmission electron microscopy (STEM) modes. The methods were demonstrated on organo-metallic complexes (chlorinated and unchlorinated copper-phthalocyanine) and on purely organic compounds (quinacridone). The PDF curves from powder electron diffraction data, called ePDF, are in good agreement with PDF curves determined from X-ray powder data demonstrating that the problems of obtaining kinematical scattering data and avoiding beam-damage of the sample are possible to resolve.

  7. Fabrication and characterization of hexagonal boron nitride powder by spray drying and calcining-nitriding technology

    SciTech Connect (OSTI)

    Shi Xiaoliang Wang Sheng; Yang Hua; Duan Xinglong; Dong Xuebin

    2008-09-15

    Hexagonal boron nitride (hBN) powder was fabricated prepared by the spray drying and calcining-nitriding technology. The effects of nitrided temperature on the phases, morphology and particle size distribution of hBN powder, were investigated. The synthesized powders were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), Fourier transformed infrared spectrum, ultraviolet-visible (UV-vis) spectrum and photoluminescence (PL) spectrum. UV-vis spectrum revealed that the product had one obvious band gap (4.7 eV) and PL spectrum showed that it had a visible emission at 457 nm ({lambda}{sub ex}=230 nm). FESEM image indicated that the particle size of the synthesized hBN was mainly in the range of 0.5-1.5 {mu}m in diameter, and 50-150 nm in thickness. The high-energy ball-milling process following 900 deg. C calcining process was very helpful to obtain fully crystallized hBN at lower temperature. - Graphical abstract: hBN powder was fabricated prepared by spray drying and calcining-nitriding technology. The results indicated that spray drying and calcining-nitriding technology assisted with high-energy ball-milling process following calcined process was a hopeful way to manufacture hBN powder with high crystallinity in industrial scale.

  8. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1992-04-21

    A free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7 [times] 10[sup [minus]3] to about 7 [times] 10[sup [minus]2] microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 9 figs.

  9. Ignition of THKP and TKP pyrotechnic powders :

    SciTech Connect (OSTI)

    Maharrey, Sean P.; Erikson, William W; Highley, Aaron M.; Wiese-Smith, Deneille; Kay, Jeffrey J

    2014-03-01

    We have conducted Simultaneous Thermogravimetric Modulated Beam Mass Spectrometry (STMBMS) experiments on igniter/actuator pyrotechnic powders to characterize the reactive processes controlling the ignition and combustion behavior of these materials. The experiments showed a complex, interactive reaction manifold involving over ten reaction pathways. A reduced dimensionality reaction manifold was developed from the detailed 10-step manifold and is being incorporated into existing predictive modeling codes to simulate the performance of pyrotechnic powders for NW component development. The results from development of the detailed reaction manifold and reduced manifold are presented. The reduced reaction manifold has been successfully used by SNL/NM modelers to predict thermal ignition events in small-scale testing, validating our approach and improving the capability of predictive models.

  10. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, James L. (Pleasanton, CA); Tran, Tri D. (Livermore, CA); Feikert, John H. (Livermore, CA); Mayer, Steven T. (San Leandro, CA)

    1997-01-01

    Fabrication of conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive dionization, and waste treatment. Electrodes fabricated from low surface area (<50 m.sup.2 /gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon compositives with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to be high surface area carbons, fuel cell electrodes can be produced.

  11. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1993-10-19

    Free flowing, conformable powder-like mix of silica particles and a phase change material (pcm) is disclosed. The silica particles have a critical size of about 7[times]10[sup [minus]3] to about 7[times]10[sup [minus]2] microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 10 figures.

  12. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, J.L.; Tran, T.D.; Feikert, J.H.; Mayer, S.T.

    1997-06-10

    Fabrication is described for conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive deionization, and waste treatment. Electrodes fabricated from low surface area (<50 m{sup 2}/gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon composites with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to high surface area carbons, fuel cell electrodes can be produced. 1 fig.

  13. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1993-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  14. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1994-02-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a PCM material. The silica-PCM mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 2 figures.

  15. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1994-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a PCM material. The silica-PCM mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  16. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1992-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  17. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1993-05-18

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7[times]10[sup [minus]3] to about 7[times]10[sup [minus]2] microns and the p.c.m. must be added to the silica in an amount of 80 wt. % or less p.c.m. per combined weight of silica and p.c.m. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a p.c.m. material. The silica-p.c.m. mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  18. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1993-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garmets, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  19. Full body powder antichip. Final report

    SciTech Connect (OSTI)

    1996-04-17

    Chipping is the major paint defect listed for automobile customer dissatisfaction. The improved chip resistance and smoother paint surfaces produced by full body powder antichip will result in greater customer satisfaction and greater demand for US-produced automobiles. Powder antichip contains virtually no solvent, thereby reducing the potential VOC emissions from Newark Assembly by more than 90 tons per year as compared to the solvent-borne material presently applied in most full body applications. Since Newark Assembly Plant is in a severe non-attainment air quality area, which must demonstrate a 15% reduction in emissions by 1996, projects such as this are crucial to the longevity of industry in this region. The liquid paint spray systems include incineration of the oven volatile organic compounds (VOC`s) at 1,500 F. Since there are minimal VOC`s in powder coatings and the only possible releases occur only during polymerization, incineration is not required. The associated annual savings resulting from the elimination of the incinerator utilized on the liquid spray system is 1.44 {times} 10{sup 10} BTU`s per unit installed. The annual cost savings is approximately $388 thousand, far below the original estimates.

  20. Powder Injection Molding of Titanium Components

    SciTech Connect (OSTI)

    Simmons, Kevin L.; Nyberg, Eric A.; Weil, K. Scott; Miller, Megan R.

    2005-01-01

    Powder injection molding (PIM) is a well-established, cost-effective method of fabricating small-to-moderate size metal components. Derived from plastic injection molding and employing a mixture of metal powder and plastic binder, the process has been used with great success in manufacturing a wide variety of metal products, including those made from stainless steel, nickel-based superalloys, and copper alloys. Less progress has been achieved with titanium and other refractory metal alloys because of problems with alloy impurities that are directly attributable to the injection molding process. Specifically, carbon, oxygen, and nitrogen are left behind during binder removal and become incorporated into the chemistry and microstructure of the material during densification. Even at low concentration, these impurities can cause severe degradation in the mechanical properties of titanium and its alloys. We have developed a unique blend of PIM constituents where only a small volume fraction of binder (~5 – 10 vol%) is required for injection molding; the remainder of the mixture consists of the metal powder and binder solvent. Because of the nature of decomposition in the binder system and the relatively small amount used, the binder is eliminated almost completely from the pre-sintered component during the initial stage of a two-step heat treatment process. Results will be presented on the first phase of this research, in which the binder, injection molding, de-binding and sintering schedule were developed. Additional data on the mechanical and physical properties of the material produced will be discussed.

  1. Mid-infrared followup of cold brown dwarfs: diversity in age, mass and metallicity

    SciTech Connect (OSTI)

    Saumon, Didier; Leggett, Sandy K; Burningham, Ben; Marley, Mark S; Waren, S J; Jones, H R A; Pinfield, D J; Smart, R L

    2009-01-01

    We present new Spitzer IRAC [3.6], [4.5], [5.8] and [8.0] photometry of nine very late-type T dwarfs. Combining this with previously published photometry, we investigate trends with type and color that are useful for both the planning and interpretation of infrared surveys designed to discover the coldest T or Y dwarfs. Brown dwarfs with effective temperature (T{sub eff}) below 700 K emit more than half their flux at wavelengths longer than 3 {micro}m, and the ratio of the mid-infrared flux to the near-infrared flux becomes very sensitive to T{sub eff} at these low temperatures. We confirm that the color H (1.6 {micro}m) - [4.5] is a good indicator of T{sub eff} with a relatively weak dependence on metallicity and gravity. Conversely, the colors H - K (2.2 {micro}m) and [4.5] - [5.8] are sensitive to metallicity and gravity. Thus near- and mid-infrared photometry provide useful indicators of the fundamental properties of brown dwarfs, and if temperature and gravity are known, then mass and age can be reliably determined from evolutionary models. There are twelve dwarfs currently known with H - [4.5] > 3.0, and {approx} 500 < T{sub eff} K {approx}< 800, which we examine in detail. The ages of the dwarfs in the sample range from very young (0.1 - 1.0 Gyr) to relatively old (3 - 12 Gyr). The mass range is possibly as low as 5 Jupiter masses to up to 70 Jupiter masses, i.e. near the hydrogen burning limit. The metallicities also span a large range, from [m/H]= -0.3 to [m/H]= +0.2. The small number of T8 - T9 dwarfs found in the UKIRT Infrared Deep Sky Survey to date appear to be predominantly young low-mass dwarfs. Accurate mid-infrared photometry of cold brown dwarfs is essentially impossible from the ground, and extensions to the mid-infrared space missions warm-Spitzer and WISE are desirable in order to obtain the vital mid-infrared data for cold brown dwarfs, and to discover more of these rare objects.

  2. FIA-12-0044 - In the Matter of Cynthia Brown | Department of Energy

    Office of Environmental Management (EM)

    4 - In the Matter of Cynthia Brown FIA-12-0044 - In the Matter of Cynthia Brown Cynthia Brown filed an Appeal regarding a request filed under the Freedom of Information Act. In March 2012, Ms. Brown filed a request for records regarding her late mother. In a July 2012 determination, the DOE's Office of Health, Safety and Security (HSS) issued a determination in response to Ms. Brown's request. In that determination, HSS reported the results of searches it had conducted 1) at Richland Operations

  3. Silicon nitride/silicon carbide composite densified materials prepared using composite powders

    DOE Patents [OSTI]

    Dunmead, S.D.; Weimer, A.W.; Carroll, D.F.; Eisman, G.A.; Cochran, G.A.; Susnitzky, D.W.; Beaman, D.R.; Nilsen, K.J.

    1997-07-01

    Prepare silicon nitride-silicon carbide composite powders by carbothermal reduction of crystalline silica powder, carbon powder and, optionally, crystalline silicon nitride powder. The crystalline silicon carbide portion of the composite powders has a mean number diameter less than about 700 nanometers and contains nitrogen. The composite powders may be used to prepare sintered ceramic bodies and self-reinforced silicon nitride ceramic bodies.

  4. A novel process route for the production of spherical SLS polymer powders

    SciTech Connect (OSTI)

    Schmidt, Jochen; Sachs, Marius; Blümel, Christina; Winzer, Bettina; Toni, Franziska; Wirth, Karl-Ernst; Peukert, Wolfgang

    2015-05-22

    Currently, rapid prototyping gradually is transferred to additive manufacturing opening new applications. Especially selective laser sintering (SLS) is promising. One drawback is the limited choice of polymer materials available as optimized powders. Powders produced by cryogenic grinding show poor powder flowability resulting in poor device quality. Within this account we present a novel process route for the production of spherical polymer micron-sized particles of good flowability. The feasibility of the process chain is demonstrated for polystyrene e. In a first step polymer microparticles are produced by a wet grinding method. By this approach the mean particle size and the particle size distribution can be tuned between a few microns and several 10 microns. The applicability of this method will be discussed for different polymers and the dependencies of product particle size distribution on stressing conditions and process temperature will be outlined. The comminution products consist of microparticles of irregular shape and poor powder flowability. An improvement of flowability of the ground particles is achieved by changing their shape: they are rounded using a heated downer reactor. The influence of temperature profile and residence time on the product properties will be addressed applying a viscous-flow sintering model. To further improve the flowability of the cohesive spherical polymer particles nanoparticles are adhered onto the microparticles’ surface. The improvement of flowability is remarkable: rounded and dry-coated powders exhibit a strongly reduced tensile strength as compared to the comminution product. The improved polymer powders obtained by the process route proposed open new possibilities in SLS processing including the usage of much smaller polymer beads.

  5. Large Bore Powder Gun Qualification (U)

    SciTech Connect (OSTI)

    Rabern, Donald A.; Valdiviez, Robert

    2012-04-02

    A Large Bore Powder Gun (LBPG) is being designed to enable experimentalists to characterize material behavior outside the capabilities of the NNSS JASPER and LANL TA-55 PF-4 guns. The combination of these three guns will create a capability to conduct impact experiments over a wide range of pressures and shock profiles. The Large Bore Powder Gun will be fielded at the Nevada National Security Site (NNSS) U1a Complex. The Complex is nearly 1000 ft below ground with dedicated drifts for testing, instrumentation, and post-shot entombment. To ensure the reliability, safety, and performance of the LBPG, a qualification plan has been established and documented here. Requirements for the LBPG have been established and documented in WE-14-TR-0065 U A, Large Bore Powder Gun Customer Requirements. The document includes the requirements for the physics experiments, the gun and confinement systems, and operations at NNSS. A detailed description of the requirements is established in that document and is referred to and quoted throughout this document. Two Gun and Confinement Systems will be fielded. The Prototype Gun will be used primarily to characterize the gun and confinement performance and be the primary platform for qualification actions. This gun will also be used to investigate and qualify target and diagnostic modifications through the life of the program (U1a.104 Drift). An identical gun, the Physics Gun, will be fielded for confirmatory and Pu experiments (U1a.102D Drift). Both guns will be qualified for operation. The Gun and Confinement System design will be qualified through analysis, inspection, and testing using the Prototype Gun for the majority of process. The Physics Gun will be qualified through inspection and a limited number of qualification tests to ensure performance and behavior equivalent to the Prototype gun. Figure 1.1 shows the partial configuration of U1a and the locations of the Prototype and Physics Gun/Confinement Systems.

  6. Laser production of articles from powders

    DOE Patents [OSTI]

    Lewis, G.K.; Milewski, J.O.; Cremers, D.A.; Nemec, R.B.; Barbe, M.R.

    1998-11-17

    Method and apparatus for forming articles from materials in particulate form in which the materials are melted by a laser beam and deposited at points along a tool path to form an article of the desired shape and dimensions. Preferably the tool path and other parameters of the deposition process are established using computer-aided design and manufacturing techniques. A controller comprised of a digital computer directs movement of a deposition zone along the tool path and provides control signals to adjust apparatus functions, such as the speed at which a deposition head which delivers the laser beam and powder to the deposition zone moves along the tool path. 20 figs.

  7. Laser production of articles from powders

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Milewski, John O. (Santa Fe, NM); Cremers, David A. (Los Alamos, NM); Nemec, Ronald B. (White Rock, NM); Barbe, Michael R. (White Rock, NM)

    1998-01-01

    Method and apparatus for forming articles from materials in particulate form in which the materials are melted by a laser beam and deposited at points along a tool path to form an article of the desired shape and dimensions. Preferably the tool path and other parameters of the deposition process are established using computer-aided design and manufacturing techniques. A controller comprised of a digital computer directs movement of a deposition zone along the tool path and provides control signals to adjust apparatus functions, such as the speed at which a deposition head which delivers the laser beam and powder to the deposition zone moves along the tool path.

  8. Scalable synthesis of nanoporous palladium powders.

    SciTech Connect (OSTI)

    Robinson, David B.; Tran, Kim L.; Clift, W. Miles; Arslan Ilke; Langham, Mary Elizabeth; Ong, Markus D.; Fares, Stephen James

    2009-03-01

    Nanoporous palladium powders are synthesized on milligram to gram scales by chemical reduction of tetrachloro complexes by ascorbate in a concentrated aqueous surfactant at temperatures between -20 and 30 C. Particle diameters are approximately 50 nm, and each particle is perforated by 3 nm pores, as determined by electron tomography. These materials are of potential value for storage of hydrogen isotopes and electrical charge; producing them at large scales in a safe and efficient manner will help realize this. A slightly modified procedure also results in nanoporous platinum.

  9. Production and degradation of oxalic acid by brown rot fungi

    SciTech Connect (OSTI)

    Espejo, E.; Agosin, E. )

    1991-07-01

    Our results show that all of the brown rot fungi tested produce oxalic acid in liquid as well as in semisolid cultures. Gloeophyllum trabeum, which accumulates the lowest amount of oxalic acid during decay of pine holocellulose, showed the highest polysaccharide-depolymerizing activity. Semisolid cultures inoculated with this fungus rapidly converted {sup 14}C-labeled oxalic acid to CO{sub 2} during cellulose depolymerization. The other brown rot fungi also oxidized {sup 14}C-labeled oxalic acid, although less rapidly. In contrast, semisolid cultures inoculated with the white rot fungus Coriolus versicolor did not significantly catabolize the acid and did not depolymerize the holocellulose during decay. Semisolid cultures of G. trabeum amended with desferrioxamine, a specific iron-chelating agent, were unable to lower the degree of polymerization of cellulose or to oxidize {sup 14}C-labeled oxalic acid to the extent or at the rate that control cultures did. These results suggest that both iron and oxalic acid are involved in cellulose depolymerization by brown rot fungi.

  10. Method for preparing metal powder, device for preparing metal powder, method for processing spent nuclear fuel

    DOE Patents [OSTI]

    Park, Jong-Hee (Clarendon Hills, IL)

    2011-11-29

    A method for producing metal powder is provided the comprising supplying a molten bath containing a reducing agent, contacting a metal oxide with the molten bath for a time and at a temperature sufficient to reduce the metal in the metal oxide to elemental metal and produce free oxygen; and isolating the elemental metal from the molten bath.

  11. Field Testing of Activated Carbon Injection Options for Mercury Control at TXU's Big Brown Station

    SciTech Connect (OSTI)

    John Pavlish; Jeffrey Thompson; Christopher Martin; Mark Musich; Lucinda Hamre

    2009-01-07

    The primary objective of the project was to evaluate the long-term feasibility of using activated carbon injection (ACI) options to effectively reduce mercury emissions from Texas electric generation plants in which a blend of lignite and subbituminous coal is fired. Field testing of ACI options was performed on one-quarter of Unit 2 at TXU's Big Brown Steam Electric Station. Unit 2 has a design output of 600 MW and burns a blend of 70% Texas Gulf Coast lignite and 30% subbituminous Powder River Basin coal. Big Brown employs a COHPAC configuration, i.e., high air-to-cloth baghouses following cold-side electrostatic precipitators (ESPs), for particulate control. When sorbent injection is added between the ESP and the baghouse, the combined technology is referred to as TOXECON{trademark} and is patented by the Electric Power Research Institute in the United States. Key benefits of the TOXECON configuration include better mass transfer characteristics of a fabric filter compared to an ESP for mercury capture and contamination of only a small percentage of the fly ash with AC. The field testing consisted of a baseline sampling period, a parametric screening of three sorbent injection options, and a month long test with a single mercury control technology. During the baseline sampling, native mercury removal was observed to be less than 10%. Parametric testing was conducted for three sorbent injection options: injection of standard AC alone; injection of an EERC sorbent enhancement additive, SEA4, with ACI; and injection of an EERC enhanced AC. Injection rates were determined for all of the options to achieve the minimum target of 55% mercury removal as well as for higher removals approaching 90%. Some of the higher injection rates were not sustainable because of increased differential pressure across the test baghouse module. After completion of the parametric testing, a month long test was conducted using the enhanced AC at a nominal rate of 1.5 lb/Macf. During the time that enhanced AC was injected, the average mercury removal for the month long test was approximately 74% across the test baghouse module. ACI was interrupted frequently during the month long test because the test baghouse module was bypassed frequently to relieve differential pressure. The high air-to-cloth ratio of operations at this unit results in significant differential pressure, and thus there was little operating margin before encountering differential pressure limits, especially at high loads. This limited the use of sorbent injection as the added material contributes to the overall differential pressure. This finding limits sustainable injection of AC without appropriate modifications to the plant or its operations. Handling and storage issues were observed for the TOXECON ash-AC mixture. Malfunctioning equipment led to baghouse dust hopper plugging, and storage of the stagnant material at flue gas temperatures resulted in self-heating and ignition of the AC in the ash. In the hoppers that worked properly, no such problems were reported. Economics of mercury control at Big Brown were estimated for as-tested scenarios and scenarios incorporating changes to allow sustainable operation. This project was funded under the U.S. Department of Energy National Energy Technology Laboratory project entitled 'Large-Scale Mercury Control Technology Field Testing Program--Phase II'.

  12. NanoComposite Stainless Steel Powder Technologies

    SciTech Connect (OSTI)

    DeHoff, R.; Glasgow, C. (MesoCoat, Inc.)

    2012-07-25

    Oak Ridge National Laboratory has been investigating a new class of Fe-based amorphous material stemming from a DARPA, Defense Advanced Research Projects Agency initiative in structural amorphous metals. Further engineering of the original SAM materials such as chemistry modifications and manufacturing processes, has led to the development of a class of Fe based amorphous materials that upon processing, devitrify into a nearly homogeneous distribution of nano sized complex metal carbides and borides. The powder material is produced through the gas atomization process and subsequently utilized by several methods; laser fusing as a coating to existing components or bulk consolidated into new components through various powder metallurgy techniques (vacuum hot pressing, Dynaforge, and hot isostatic pressing). The unique fine scale distribution of microstructural features yields a material with high hardness and wear resistance compared to material produced through conventional processing techniques such as casting while maintaining adequate fracture toughness. Several compositions have been examined including those specifically designed for high hardness and wear resistance and a composition specifically tailored to devitrify into an austenitic matrix (similar to a stainless steel) which poses improved corrosion behavior.

  13. Selection of powder factor in large diameter blastholes

    SciTech Connect (OSTI)

    Eloranta, J.

    1995-12-31

    This paper documents the relationship between material handling and processing costs compared to blasting cost. The old adage, The cheapest crushing is done in the pit, appears accurate in this case study. Comparison of the accumulated cost of: powder, selected wear materials and electricity; indicate a strong, inverse correlation with powder factor (lbs powder/long ton of rock). In this case, the increased powder cost is more than offset by electrical savings alone. Measurable, overall costs decline while shovel and crusher productivity rise by about 5% when powder factor rises by 15%. These trends were previously masked by the effects of: weather, ore grade fluctuations and accounting practices. Attempts to correlate increased powder factor to: wear materials in the crushing plant and to shovel hoist rope life have not shown the same benefit.

  14. Electrochemical cell with powdered electrically insulative material as a separator

    DOE Patents [OSTI]

    Mathers, James P.; Olszanski, Theodore W.; Boquist, Carl W.

    1978-01-01

    A secondary electrochemical cell includes electrodes separated by a layer of electrically insulative powder. The powder includes refractory materials selected from the oxides and nitrides of metals and metaloids. The powdered refractory material, blended with electrolyte particles, can be compacted in layers with electrode materials to form an integral electrode structure or separately assembled into the cell. The assembled cell is heated to operating temperature leaving porous layers of electrically insulative, refractory particles, containing molten electrolyte between the electrodes.

  15. Process for synthesizing compounds from elemental powders and product

    DOE Patents [OSTI]

    Rabin, Barry H. (Idaho Falls, ID); Wright, Richard N. (Idaho Falls, ID)

    1993-01-01

    A process for synthesizing intermetallic compounds from elemental powders. The elemental powders are initially combined in a ratio which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe.sub.3 Al and FeAl.

  16. Stabilized Lithium Metal Powder, Enabling Material and Revolutionary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation PDF icon es011yakovleva2011p.pdf More Documents & Publications Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy...

  17. Forming gas treatment of lithium ion battery anode graphite powders

    DOE Patents [OSTI]

    Contescu, Cristian Ion; Gallego, Nidia C; Howe, Jane Y; Meyer, III, Harry M; Payzant, Edward Andrew; Wood, III, David L; Yoon, Sang Young

    2014-09-16

    The invention provides a method of making a battery anode in which a quantity of graphite powder is provided. The temperature of the graphite powder is raised from a starting temperature to a first temperature between 1000 and 2000.degree. C. during a first heating period. The graphite powder is then cooled to a final temperature during a cool down period. The graphite powder is contacted with a forming gas during at least one of the first heating period and the cool down period. The forming gas includes H.sub.2 and an inert gas.

  18. Joining of parts via magnetic heating of metal aluminum powders

    SciTech Connect (OSTI)

    Baker, Ian

    2013-05-21

    A method of joining at least two parts includes steps of dispersing a joining material comprising a multi-phase magnetic metal-aluminum powder at an interface between the at least two parts to be joined and applying an alternating magnetic field (AMF). The AMF has a magnetic field strength and frequency suitable for inducing magnetic hysteresis losses in the metal-aluminum powder and is applied for a period that raises temperature of the metal-aluminum powder to an exothermic transformation temperature. At the exothermic transformation temperature, the metal-aluminum powder melts and resolidifies as a metal aluminide solid having a non-magnetic configuration.

  19. POWDERED ACTIVATED CARBON FROM NORTH DAKOTA LIGNITE: AN OPTION...

    Office of Scientific and Technical Information (OSTI)

    CARBON FROM NORTH DAKOTA LIGNITE: AN OPTION FOR DISINFECTION BY-PRODUCT CONTROL IN WATER TREATMENT PLANTS Citation Details In-Document Search Title: POWDERED ACTIVATED...

  20. Apparatus for producing nanoscale ceramic powders

    DOE Patents [OSTI]

    Helble, Joseph J. (Andover, MA); Moniz, Gary A. (Windham, NH); Morse, Theodore F. (Little Compton, RI)

    1995-09-05

    An apparatus provides high temperature and short residence time conditions for the production of nanoscale ceramic powders. The apparatus includes a confinement structure having a multiple inclined surfaces for confining flame located between the surfaces so as to define a flame zone. A burner system employs one or more burners to provide flame to the flame zone. Each burner is located in the flame zone in close proximity to at least one of the inclined surfaces. A delivery system disposed adjacent the flame zone delivers an aerosol, comprising an organic or carbonaceous carrier material and a ceramic precursor, to the flame zone to expose the aerosol to a temperature sufficient to induce combustion of the carrier material and vaporization and nucleation, or diffusion and oxidation, of the ceramic precursor to form pure, crystalline, narrow size distribution, nanophase ceramic particles.

  1. Apparatus for producing nanoscale ceramic powders

    DOE Patents [OSTI]

    Helble, Joseph J. (Andover, MA); Moniz, Gary A. (Windham, NH); Morse, Theodore F. (Little Compton, RI)

    1997-02-04

    An apparatus provides high temperature and short residence time conditions for the production of nanoscale ceramic powders. The apparatus includes a confinement structure having a multiple inclined surfaces for confining flame located between the surfaces so as to define a flame zone. A burner system employs one or more burners to provide flame to the flame zone. Each burner is located in the flame zone in close proximity to at least one of the inclined surfaces. A delivery system disposed adjacent the flame zone delivers an aerosol, comprising an organic or carbonaceous carrier material and a ceramic precursor, to the flame zone to expose the aerosol to a temperature sufficient to induce combustion of the carrier material and vaporization and nucleation, or diffusion and oxidation, of the ceramic precursor to form pure, crystalline, narrow size distribution, nanophase ceramic particles.

  2. Process for preparing titanium nitride powder

    DOE Patents [OSTI]

    Bamberger, C.E.

    1988-06-17

    A process for making titanium nitride powder by reaction of titanium phosphates with sodium cyanide. The process of this invention may comprise mixing one or more phosphates of Ti with a cyanide salt in the absence of oxygen and heating to a temperature sufficient to cause reaction to occur. In the preferred embodiment the ratio of cyanide salt to Ti should be at least 2 which results in the major Ti-containing product being TiN rather than sodium titanium phosphate byproducts. The process is an improvement over prior processes since the byproducts are water soluble salts of sodium which can easily be removed from the preferred TiN product by washing. 2 tabs.

  3. ATMOSPHERIC CIRCULATION OF BROWN DWARFS: JETS, VORTICES, AND TIME VARIABILITY

    SciTech Connect (OSTI)

    Zhang, Xi; Showman, Adam P.

    2014-06-10

    A variety of observational evidence demonstrates that brown dwarfs exhibit active atmospheric circulations. In this study we use a shallow-water model to investigate the global atmospheric dynamics in the stratified layer overlying the convective zone on these rapidly rotating objects. We show that the existence and properties of the atmospheric circulation crucially depend on key parameters including the energy injection rate and radiative timescale. Under conditions of strong internal heat flux and weak radiative dissipation, a banded flow pattern comprised of east-west jet streams spontaneously emerges from the interaction of atmospheric turbulence with the planetary rotation. In contrast, when the internal heat flux is weak and/or radiative dissipation is strong, turbulence injected into the atmosphere damps before it can self-organize into jets, leading to a flow dominated by transient eddies and isotropic turbulence instead. The simulation results are not very sensitive to the form of the forcing. Based on the location of the transition between jet-dominated and eddy-dominated regimes, we suggest that many brown dwarfs may exhibit atmospheric circulations dominated by eddies and turbulence (rather than jets) due to the strong radiative damping on these worlds, but a jet structure is also possible under some realistic conditions. Our simulated light curves capture important features from observed infrared light curves of brown dwarfs, including amplitude variations of a few percent and shapes that fluctuate between single-peak and multi-peak structures. More broadly, our work shows that the shallow-water system provides a useful tool to illuminate fundamental aspects of the dynamics on these worlds.

  4. Metastable phases in mechanically alloyed aluminum germanium powders

    SciTech Connect (OSTI)

    Yvon, P.J.; Schwarz, R.B.

    1993-03-01

    Aluminum and germanium form a simple eutectic system with no stable intermetallic phase, and limited mutual solubility. We report the formation of a metastable rhombohedral,{gamma}{sub 1} phase by mechanically alloying aluminum and germanium powders. This phase, which appears for compositions between 20 and 50 at. % germanium, has also been observed in rapidly quenched alloys, but there is disagreement as to its composition. By measuring the heat of crystallization as a function of composition, we determined the composition of the {gamma}{sub 1} phase to be Al{sub 70}Ge{sub 30}. We also produced Al{sub 70}Ge{sub 30} by arc melting the pure elements, followed by splat-quenching at a cooling rate in the range of 10{sup 8} K s{sup {minus}1}. This method produced two metastable phases, one of which was found to be the {gamma}{sub 1} phase obtained by mechanical alloying. The other was a monoclinic phase reported earlier in the literature as {gamma}{sub 2}.

  5. Three new cool brown dwarfs discovered with the wide-field infrared survey explorer (WISE) and an improved spectrum of the Y0 dwarf wise J041022.71+150248.4

    SciTech Connect (OSTI)

    Cushing, Michael C.; Kirkpatrick, J. Davy; Gelino, Christopher R.; Mace, Gregory N.; Skrutskie, Michael F.; Gould, Andrew

    2014-05-01

    As part of a larger search of Wide-field Infrared Survey Explorer (WISE) data for cool brown dwarfs with effective temperatures less than 1000 K, we present the discovery of three new cool brown dwarfs with spectral types later than T7. Using low-resolution, near-infrared spectra obtained with the NASA Infrared Telescope Facility and the Hubble Space Telescope, we derive spectral types of T9.5 for WISE J094305.98+360723.5, T8 for WISE J200050.19+362950.1, and Y0: for WISE J220905.73+271143.9. The identification of WISE J220905.73+271143.9 as a Y dwarf brings the total number of spectroscopically confirmed Y dwarfs to 17. In addition, we present an improved spectrum (i.e., higher signal-to-noise ratio) of the Y0 dwarf WISE J041022.71+150248.4 that confirms the Cushing et al. classification of Y0. Spectrophotometric distance estimates place all three new brown dwarfs at distances less than 12 pc, with WISE J200050.19+362950.1 lying at a distance of only 3.9-8.0 pc. Finally, we note that brown dwarfs like WISE J200050.19+362950.1 that lie in or near the Galactic plane offer an exciting opportunity to directly measure the mass of a brown dwarf via astrometric microlensing.

  6. Melting of Uranium Metal Powders with Residual Salts

    SciTech Connect (OSTI)

    Jin-Mok Hur; Dae-Seung Kang; Chung-Seok Seo

    2007-07-01

    The Advanced Spent Fuel Conditioning Process (ACP) of the Korea Atomic Energy Research Institute focuses on the conditioning of Pressurized Water Reactor spent oxide nuclear fuel. After the oxide reduction step of the ACP, the resultant metal powders containing {approx} 30 wt% residual LiCl-Li{sub 2}O should be melted for a consolidation of the fine metal powders. In this study, we investigated the melting behaviors of uranium metal powders considering the effects of a LiCl-Li{sub 2}O residual salt. (authors)

  7. Atomizing apparatus for making polymer and metal powders and whiskers

    DOE Patents [OSTI]

    Otaigbe, Joshua U. (Ames, IA); McAvoy, Jon M. (Moline, IL); Anderson, Iver E. (Ames, IA); Ting, Jason (Ames, IA); Mi, Jia (Pittsburgh, PA); Terpstra, Robert (Ames, IA)

    2003-03-18

    Method for making polymer particulates, such as spherical powder and whiskers, by melting a polymer material under conditions to avoid thermal degradation of the polymer material, atomizing the melt using gas jet means in a manner to form atomized droplets, and cooling the droplets to form polymer particulates, which are collected for further processing. Atomization parameters can be controlled to produce polymer particulates with controlled particle shape, particle size, and particle size distribution. For example, atomization parameters can be controlled to produce spherical polymer powders, polymer whiskers, and combinations of spherical powders and whiskers. Atomizing apparatus also is provided for atoomizing polymer and metallic materials.

  8. Rheological properties of water-coal slurries based on brown coal in the presence of sodium lignosulfonates and alkali

    SciTech Connect (OSTI)

    D.P. Savitskii; A.S. Makarov; V.A. Zavgorodnii

    2009-07-01

    The effect of the oxidized surface of brown coal on the structural and rheological properties of water-coal slurries was found. The kinetics of structure formation processes in water-coal slurries based on as-received and oxidized brown coal was studied. The effect of lignosulfonate and alkali additives on the samples of brown coal was considered.

  9. Enhanced Coal Bed Methane Recovery and CO2 Sequestration in the Powder River Basin

    SciTech Connect (OSTI)

    Eric P. Robertson

    2010-06-01

    Unminable coal beds are potentially large storage reservoirs for the sequestration of anthropogenic CO2 and offer the benefit of enhanced methane production, which can offset some of the costs associated with CO2 sequestration. The objective of this report is to provide a final topical report on enhanced coal bed methane recovery and CO2 sequestration to the U.S. Department of Energy in fulfillment of a Big Sky Carbon Sequestration Partnership milestone. This report summarizes work done at Idaho National Laboratory in support of Phase II of the Big Sky Carbon Sequestration Partnership. Research that elucidates the interaction of CO2 and coal is discussed with work centering on the Powder River Basin of Wyoming and Montana. Sorption-induced strain, also referred to as coal swelling/shrinkage, was investigated. A new method of obtaining sorption-induced strain was developed that greatly decreases the time necessary for data collection and increases the reliability of the strain data. As coal permeability is a strong function of sorption-induced strain, common permeability models were used to fit measured permeability data, but were found inadequate. A new permeability model was developed that can be directly applied to coal permeability data obtained under laboratory stress conditions, which are different than field stress conditions. The coal permeability model can be used to obtain critical coal parameters that can be applied in field models. An economic feasibility study of CO2 sequestration in unminable coal seams in the Powder River Basin of Wyoming was done. Economic analyses of CO2 injection options are compared. Results show that injecting flue gas to recover methane from CBM fields is marginally economical; however, this method will not significantly contribute to the need to sequester large quantities of CO2. Separating CO2 from flue gas and injecting it into the unminable coal zones of the Powder River Basin seam is currently uneconomical, but can effectively sequester over 86,000 tons (78,200 Mg) of CO2 per acre while recovering methane to offset costs. The cost to separate CO2 from flue gas was identified as the major cost driver associated with CO2 sequestration in unminable coal seams. Improvements in separations technology alone are unlikely to drive costs low enough for CO2 sequestration in unminable coal seams in the Powder River Basin to become economically viable. Breakthroughs in separations technology could aid the economics, but in the Powder River Basin, they cannot achieve the necessary cost reductions for breakeven economics without incentives.

  10. ATWS at Browns Ferry Unit One - accident sequence analysis

    SciTech Connect (OSTI)

    Harrington, R.M.; Hodge, S.A.

    1984-07-01

    This study describes the predicted response of Unit One at the Browns Ferry Nuclear Plant to a postulated complete failure to scram following a transient occurrence that has caused closure of all Main Steam Isolation Valves (MSIVs). This hypothetical event constitutes the most severe example of the type of accident classified as Anticipated Transient Without Scram (ATWS). Without the automatic control rod insertion provided by scram, the void coefficient of reactivity and the mechanisms by which voids are formed in the moderator/coolant play a dominant role in the progression of the accident. Actions taken by the operator greatly influence the quantity of voids in the coolant and the effect is analyzed in this report. The progression of the accident sequence under existing and under recommended procedures is discussed. For the extremely unlikely cases in which equipment failure and wrongful operator actions might lead to severe core damage, the sequence of emergency action levels and the associated timing of events are presented.

  11. ATWS analysis for Browns Ferry Nuclear Plant Unit 1

    SciTech Connect (OSTI)

    Dallman, R.J.; Jouse, W.C.

    1985-01-01

    Analyses of postulated Anticipated Transients Without Scram (ATWS) were performed at the Idaho National Engineering Laboratory (INEL). The Browns Ferry Nuclear Plant Unit 1 (BFNP1) was selected as the subject of this work because of the cooperation of the Tennessee Valley Authority (TVA). The work is part of the Severe Accident Sequence Analysis (SASA) Program of the US Nuclear Regulatory Commission (NRC). A Main Steamline Isolation Valve (MSIV) closure served as the transient initiator for these analyses, which proceeded a complete failure to scram. Results from the analyses indicate that operator mitigative actions are required to prevent overpressurization of the primary containment. Uncertainties remain concerning the effectiveness of key mitigative actions. The effectiveness of level control as a power reduction procedure is limited. Power level resulting from level control only reduce the Pressure Suppression Pool (PSP) heatup rate from 6 to 4F/min.

  12. RAMONA-3B application to Browns Ferry ATWS

    SciTech Connect (OSTI)

    Slovik, G.C.; Neymotin, L.; Cazzoli, E.; Saha, P.

    1984-01-01

    This paper discusses two preliminary MSIV clsoure ATWS calculations done using the RAMONA-3B code and the work being done to create the necessary cross section sets for the Browns Ferry Unit 1 reactor. The RAMONA-3B code employs a three-dimensional neutron kinetics model coupled with one-dimensional, four equation, nonhomogeneous, nonequilibrium thermal hydraulics. To be compatible with 3-D neutron kinetics, the code uses parallel coolant channels in the core. It also includes a boron transport model and all necessary BWR components such as jet pump, recirculation pump, steam separator, steamline with safety and relief valves, main steam isolation valve, turbine stop valve, and turbine bypass valve. A summary of RAMONA-3B neutron kinetics and thermal hydraulics models is presented in the Appendix.

  13. Process for synthesizing compounds from elemental powders and product

    DOE Patents [OSTI]

    Rabin, B.H.; Wright, R.N.

    1993-12-14

    A process for synthesizing intermetallic compounds from elemental powders is described. The elemental powders are initially combined in a ratio which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe[sub 3] Al and FeAl. 25 figures.

  14. Environmentally stable reactive alloy powders and method of making same

    DOE Patents [OSTI]

    Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

    1998-09-22

    Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloys needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

  15. Apparatus for making environmentally stable reactive alloy powders

    DOE Patents [OSTI]

    Anderson, I.E.; Lograsso, B.K.; Terpstra, R.L.

    1996-12-31

    Apparatus and method are disclosed for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment. 7 figs.

  16. Apparatus for making environmentally stable reactive alloy powders

    DOE Patents [OSTI]

    Anderson, Iver E. (Ames, IA); Lograsso, Barbara K. (Ames, IA); Terpstra, Robert L. (Ames, IA)

    1996-12-31

    Apparatus and method for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment.

  17. Environmentally stable reactive alloy powders and method of making same

    DOE Patents [OSTI]

    Anderson, Iver E. (Ames, IA); Lograsso, Barbara K. (Ames, IA); Terpstra, Robert L. (Ames, IA)

    1998-09-22

    Apparatus and method for making powder from a metallic melt by atomizing the melt to form droplets and reacting the droplets downstream of the atomizing location with a reactive gas. The droplets are reacted with the gas at a temperature where a solidified exterior surface is formed thereon and where a protective refractory barrier layer (reaction layer) is formed whose penetration into the droplets is limited by the presence of the solidified surface so as to avoid selective reduction of key reactive alloyants needed to achieve desired powder end use properties. The barrier layer protects the reactive powder particles from environmental constituents such as air and water in the liquid or vapor form during subsequent fabrication of the powder to end-use shapes and during use in the intended service environment.

  18. Quality experimental and calculated powder x-ray diffraction

    SciTech Connect (OSTI)

    Sullenger, D.B.; Cantrell, J.S.; Beiter, T.A.; Tomlin, D.W.

    1996-08-01

    For several years, we have submitted quality powder XRD patterns to the International Centre for Diffraction Data for inclusion as reference standards in their Powder Diffraction File. The procedure followed is described; examples used are {beta}-UH{sub 3}, {alpha}- BaT{sub 2}, alpha-lithium disilicate ({alpha}-Li{sub 2}Si{sub 2}O{sub 5}), and 2,2`,4,4`,6,6`hexanitroazobenzene-III (HNAB-III).

  19. Neutron detectors comprising ultra-thin layers of boron powder

    DOE Patents [OSTI]

    Wang, Zhehul; Morris, Christopher

    2013-07-23

    High-efficiency neutron detector substrate assemblies comprising a first conductive substrate, wherein a first side of the substrate is in direct contact with a first layer of a powder material having a thickness of from about 50 nm to about 250 nm and comprising .sup.10boron, .sup.10boron carbide or combinations thereof, and wherein a conductive material is in proximity to the first layer of powder material; and processes of making said neutron detector substrate assemblies.

  20. Compacting Plastic-Bonded Explosive Molding Powders to Dense Solids

    SciTech Connect (OSTI)

    B. Olinger

    2005-04-15

    Dense solid high explosives are made by compacting plastic-bonded explosive molding powders with high pressures and temperatures for extended periods of time. The density is influenced by manufacturing processes of the powders, compaction temperature, the magnitude of compaction pressure, pressure duration, and number of repeated applications of pressure. The internal density variation of compacted explosives depends on method of compaction and the material being compacted.

  1. Method for removing oxide contamination from titanium diboride powder

    DOE Patents [OSTI]

    Brynestad, Jorulf (Oak Ridge, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1984-01-01

    A method for removing oxide contamination from titanium diboride powder involves the direct chemical treatment of TiB.sub.2 powders with a gaseous boron halide, such as BCl.sub.3, at temperatures in the range of 500.degree.-800.degree. C. The BCl.sub.3 reacts with the oxides to form volatile species which are removed by the BCl.sub.3 exit stream.

  2. TITANIUM SHEET PRODUCTION FROM COMMERCIAL POWDERS (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect SciTech Connect Search Results Technical Report: TITANIUM SHEET PRODUCTION FROM COMMERCIAL POWDERS Citation Details In-Document Search Title: TITANIUM SHEET PRODUCTION FROM COMMERCIAL POWDERS Authors: Muth, Thomas R [1] ; Peter, William H [1] ; Yamamoto, Yukinori [1] ; Chen, Wei [1] ; Harper, David C [1] ; Harper, Kevin D [1] ; Cox, Gregory A [1] ; Lowe, Larry E [1] + Show Author Affiliations ORNL Publication Date: 2013-04-01 OSTI Identifier: 1072995 Report Number(s):

  3. Supercritical fluid molecular spray thin films and fine powders

    DOE Patents [OSTI]

    Smith, Richard D.

    1988-01-01

    Solid films are deposited, or fine powders formed, by dissolving a solid material into a supercritical fluid solution at an elevated pressure and then rapidly expanding the solution through a short orifice into a region of relatively low pressure. This produces a molecular spray which is directed against a substrate to deposit a solid thin film thereon, or discharged into a collection chamber to collect a fine powder. The solvent is vaporized and pumped away. Solution pressure is varied to determine, together with flow rate, the rate of deposition and to control in part whether a film or powder is produced and the granularity of each. Solution temperature is varied in relation to formation of a two-phase system during expansion to control porosity of the film or powder. A wide variety of film textures and powder shapes are produced of both organic and inorganic compounds. Films are produced with regular textural feature dimensions of 1.0-2.0 .mu.m down to a range of 0.01 to 0.1 .mu.m. Powders are formed in very narrow size distributions, with average sizes in the range of 0.02 to 5 .mu.m.

  4. Titanium Metal Powder Production by the Plasma Quench Process

    SciTech Connect (OSTI)

    R. A. Cordes; A. Donaldson

    2000-09-01

    The goals of this project included the scale-up of the titanium hydride production process to a production rate of 50 kg/hr at a purity level of 99+%. This goal was to be achieved by incrementally increasing the production capability of a series of reactor systems. This methodic approach was designed to allow Idaho Titanium Technologies to systematically address the engineering issues associated with plasma system performance, and powder collection system design and performance. With quality powder available, actual fabrication with the titanium hydride was to be pursued. Finally, with a successful titanium production system in place, the production of titanium aluminide was to be pursued by the simultaneously injection of titanium and aluminum precursors into the reactor system. Some significant accomplishments of the project are: A unique and revolutionary torch/reactor capable of withstanding temperatures up to 5000 C with high thermal efficiency has been operated. The dissociation of titanium tetrachloride into titanium powder and HC1 has been demonstrated, and a one-megawatt reactor potentially capable of producing 100 pounds per hour has been built, but not yet operated at the powder level. The removal of residual subchlorides and adsorbed HC1 and the sintering of powder to form solid bodies have been demonstrated. The production system has been operated at production rates up to 40 pounds per hour. Subsequent to the end of the project, Idaho Titanium Technologies demonstrated that titanium hydride powder can indeed be sintered into solid titanium metal at 1500 C without sintering aids.

  5. Treatment of biomass to obtain ethanol

    DOE Patents [OSTI]

    Dunson, Jr., James B. (Newark, DE); Elander, Richard T. (Evergreen, CO); Tucker, III, Melvin P. (Lakewood, CO); Hennessey, Susan Marie (Avondale, PA)

    2011-08-16

    Ethanol was produced using biocatalysts that are able to ferment sugars derived from treated biomass. Sugars were obtained by pretreating biomass under conditions of high solids and low ammonia concentration, followed by saccharification.

  6. Travis Brown and Kamran Baksh, Final Submission | OpenEI Community

    Open Energy Info (EERE)

    Travis Brown and Kamran Baksh, Final Submission Home > Groups > 2014 Geothermal Case Study Challenge CSM's picture Submitted by CSM(5) Member 14 May, 2014 - 21:59 Colorado School...

  7. Method for producing microcomposite powders using a soap solution

    DOE Patents [OSTI]

    Maginnis, Michael A. (Coker, AL); Robinson, David A. (Mobile, AL)

    1996-01-01

    A method for producing microcomposite powders for use in superconducting and non-superconducting applications. A particular method to produce microcomposite powders for use in superconducting applications includes the steps of: (a) preparing a solution including ammonium soap; (b) dissolving a preselected amount of a soluble metallic such as silver nitrate in the solution including ammonium soap to form a first solution; (c) adding a primary phase material such as a single phase YBC superconducting material in particle form to the first solution; (d) preparing a second solution formed from a mixture of a weak acid and an alkyl-mono-ether; (e) adding the second solution to the first solution to form a resultant mixture; (f) allowing the resultant mixture to set until the resultant mixture begins to cloud and thicken into a gel precipitating around individual particles of the primary phase material; (g) thereafter drying the resultant mixture to form a YBC superconducting material/silver nitrate precursor powder; and (h) calcining the YBC superconducting material/silver nitrate precursor powder to convert the silver nitrate to silver and thereby form a YBC/silver microcomposite powder wherein the silver is substantially uniformly dispersed in the matrix of the YBC material.

  8. Microstructural Development in Al-Si Powder During Rapid Solidification

    SciTech Connect (OSTI)

    Amber Lynn Genau

    2004-12-19

    Powder metallurgy has become an increasingly important form of metal processing because of its ability to produce materials with superior mechanical properties. These properties are due in part to the unique and often desirable microstructures which arise as a result of the extreme levels of undercooling achieved, especially in the finest size powder, and the subsequent rapid solidification which occurs. A better understanding of the fundamental processes of nucleation and growth is required to further exploit the potential of rapid solidification processing. Aluminum-silicon, an alloy of significant industrial importance, was chosen as a model for simple eutectic systems displaying an unfaceted/faceted interface and skewed coupled eutectic growth zone, Al-Si powder produced by high pressure gas atomization was studied to determine the relationship between microstructure and alloy composition as a function of powder size and atomization gas. Critical experimental measurements of hypereutectic (Si-rich) compositions were used to determine undercooling and interface velocity, based on the theoretical models which are available. Solidification conditions were analyzed as a function of particle diameter and distance from nucleation site. A revised microstructural map is proposed which allows the prediction of particle morphology based on temperature and composition. It is hoped that this work, by providing enhanced understanding of the processes which govern the development of the solidification morphology of gas atomized powder, will eventually allow for better control of processing conditions so that particle microstructures can be optimized for specific applications.

  9. AVLIS modified direct denitration: UO{sub 3} powder evaluation

    SciTech Connect (OSTI)

    Slagle, O.D.; Davis, N.C.; Parchen, L.J.

    1994-02-01

    The evaluation study demonstrated that AVLIS-enriched uranium converted to UO{sub 3} can be used to prepare UO{sub 3} pellets having densities in the range required for commercial power reactor fuel. Specifically, the program has demonstrated that MDD (Modified Direct Denitration)-derived UO{sub 2} powders can be reduced to sinterable UO{sub 2} powder using reduction techniques that allow control of the final powder characteristics; the resulting UO{sub 2} powders can be processed/sintered using standard powder preparation and pellet fabrication techniques to yield pellets with densities greater than 96% TD; pellet microstructures appear similar to those of power reactor fuel, and because of the high final pellet densities, it is expected that they would remain stable during in-reactor operation; the results of the present study confirm the results of a similar study carried out in 1982 (Davis and Griffin 1992). The laboratory processes were selected on the basis that they could be scaled up to standard commercial fuel processing. However, larger scale testing may be required to establish techniques compatible with commercial fuel fabrication techniques.

  10. Taking It from Brown to Green: Renewable Energy on Contaminated Lands |

    Energy Savers [EERE]

    Department of Energy Taking It from Brown to Green: Renewable Energy on Contaminated Lands Taking It from Brown to Green: Renewable Energy on Contaminated Lands This presentation, presented April 22, 2009, covered renewable energy on contaminated sites. Presenters included Otto Van Geet from the National Renewable Energy Laboratory, Brian K. Johnson from the New Mexico Energy Minerals and Natural Resources Department, and Pam Swingle from the U.S. Environmental Protection Agency. PDF icon

  11. RAMONA-3B application to Browns Ferry ATWS

    SciTech Connect (OSTI)

    Slovik, G.C.; Neymotin, L.Y.; Saha, P.

    1985-01-01

    The Anticipated Transient Without Scram (ATWS) is known to be a dominant accident sequence for possible core melt in a Boiling Water Reactor (BWR). A recent Probabilistic Risk Assessment (PRA) analysis for the Browns Ferry nuclear power plant indicates that ATWS is the second most dominant transient for core melt in BWR/4 with Mark I containment. The most dominant sequence being the failure of long term decay heat removal function of the Residual Heat Removal (RHR) system. Of all the various ATWS scenarios, the Main Steam Isolation Valve (MSIV) closure ATWS sequence was chosen for present analysis because of its relatively high frequency of occurrence and its challenge to the residual heat removal system and containment integrity. The objective of this paper is to discuss four MSIV closure ATWS calculations using the RAMONA-3B code. The paper is a summary of a report being prepared for the USNRC Severe Accident Sequence Analysis (SASA) program which should be referred to for details. 10 refs., 20 figs., 3 tabs.

  12. A fast route to obtain manganese spinel nanoparticles by reduction of K-birnessite

    SciTech Connect (OSTI)

    Giovannelli, F.; Chartier, T.; Autret-Lambert, C.; Delorme, F.; Zaghrioui, M.; Seron, A.

    2009-05-15

    The K-birnessite (K{sub x}MnO{sub 2}.yH{sub 2}O) reduction reaction has been tested in order to obtain manganese spinel nanoparticles. The addition of 0.25 weight percent of hydrazine hydrate, the reducing agent, during 24 hours is efficient to transform the birnessite powder in a hausmanite Mn{sub 3}O{sub 4} powder. Well crystallised square shape nanoparticles are obtained. Different birnessite precursors have been tested and the reaction kinetics is strongly correlated to the crystallinity and granulometry of the precursor. The effects of aging time and hydrazine hydrate amount have been studied. Well crystallised Mn{sub 3}O{sub 4} is obtained in one hour. The presence of feitknechtite (MnO(OH)) and amorphous nanorods has been detected as an intermediate phase during birnessite conversion into hausmanite. The conversion mechanism is discussed. - Graphical abstract: TEM image showing Mn{sub 3}O{sub 4} particle after treatment of birnessite with an addition of hydrazine during 24 hours.

  13. A simple procedure to prepare spherical {alpha}-alumina powders

    SciTech Connect (OSTI)

    Liu Hongyu [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China); Ning Guiling [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China)], E-mail: ninggl@dlut.edu.cn; Gan Zhihong; Lin Yuan [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China)

    2009-04-02

    Spherical {alpha}-alumina powders were prepared by the controlled hydrolysis of aluminum isopropoxide in a hydrolysis system consisting of octanol and acetonitrile. Diverse solvents to dissolve reactant formed diverse hydrolysis systems and affected particle shape of {alpha}-alumina powders. The precursors crystallized to {gamma}-alumina at 1000 deg. C and converted to {alpha}-alumina at 1150 deg. C without intermediate phases. The particle morphology of precursor was retained after it crystallized to {alpha}-alumina. The heating rate influenced the particle shape and the state of agglomeration during calcination process. The thermal properties of the precursors were characterized by thermal gravimetric and differential thermal analysis. X-ray diffraction technique was used to confirm the conversion of crystalline phase of alumina powders from amorphous to {alpha}-phase. Transmission electron microscopy was used to investigate the morphologies and size of the precursors and products.

  14. Method and apparatus for the production of metal oxide powder

    DOE Patents [OSTI]

    Harris, M.T.; Scott, T.C.; Byers, C.H.

    1992-06-16

    The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed. 2 figs.

  15. Method and apparatus for the production of metal oxide powder

    DOE Patents [OSTI]

    Harris, Michael T. (Knoxville, TN); Scott, Timothy C. (Knoxville, TN); Byers, Charles H. (Oak Ridge, TN)

    1992-01-01

    The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed.

  16. Method and apparatus for the production of metal oxide powder

    DOE Patents [OSTI]

    Harris, Michael T. (Knoxville, TN); Scott, Timothy C. (Knoxville, TN); Byers, Charles H. (Oak Ridge, TN)

    1993-01-01

    The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed.

  17. Aqueous slip casting of stabilized AlN powders

    SciTech Connect (OSTI)

    Groat, E.A.; Mroz, T.J. )

    1994-11-01

    Because of the interest in aluminum nitride (AlN) for various refractory and structural applications, methods are required to cost-effectively process a water-sensitive material into the required shapes. The existence of water-resistant AlN powders has allowed the consideration of aqueous processing of a material that previously required solvent-based formulation. The composition and procedures developed for aqueous slip-casting water-resistant AlN powders provide a manufacturing route for the fabrication of large and complex geometries. Technology to create aqueous dispersions of these powders also potentially enables other manufacturing processes, such as extrusion and spray drying, to utilize the cost advantages of aqueous processing.

  18. Densification of alkoxide-derived fine silica powder compact by ultra-high-pressure cold isostatic pressing

    SciTech Connect (OSTI)

    Kamiya, Hidehiro . Dept. of Chemical Engineering); Suzuki, Hisao ); Kato, Daisuke; Jimbo, Genji . Dept. of Chemical Engineering)

    1993-01-01

    Powder compacts of alkoxide-derived fine silica powders were consolidated into a highly dense and uniform structure by ultra-high-pressure cold isostatic pressing of granules with controlled structure. The diameters of spherical and nearly monosized amorphous silica particles, prepared from metal alkoxide, were successfully controlled in the range of 9 to 760 nm by varying the concentration of ammonia. Close-packed granules of these powders were produced by spray drying. These powders were isostatically pressed up to 1 GPa at room temperature. Although the average particle diameter was less than 100 nm, the maximum relative density of the compacts was more than 78% of theoretical density. The optimum particle size to obtain highly dense compacts was in the range of 30 to 300 nm at 1 GPa. Furthermore, the ratio of mode pore diameter in these compacts to particle diameter was less than 0.155, which corresponded to the minimum ratio of calculated three-particle pore channel radii for hexagonal close packing. Viscous deformation of particles under ultra-high isostatic pressure played an important role in the densification of the compacts.

  19. Mechanochemical synthesis of tungsten carbide nano particles by using WO{sub 3}/Zn/C powder mixture

    SciTech Connect (OSTI)

    Hoseinpur, Arman; Vahdati Khaki, Jalil; Marashi, Maryam Sadat

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ? Nano particles of WC are synthesized by mechanochemical process. ? Zn was used to reduce WO{sub 3}. ? By removing ZnO from the milling products with an acid leaching, WC will be the final products. ? XRD results showed that the reduction reactions were completed after 36 h. ? TEM and SEM images showed that the morphology of produced powder is nearly spherical like. -- Abstract: In this research we introduce a new, facile, and economical system for fabrication of tungsten carbide (WC) nano particle powder. In this system WO{sub 3}, Zn, and C have been ball-milled for several hours, which led to the synthesis of tungsten carbide nano particles. The synthesized WC can successfully be separated from the ball-milled product by subjecting the product powder to diluted HCl for removing ZnO and obtaining WC. X-ray diffraction (XRD) analysis indicates that the reduction of WO{sub 3} will be completed gradually by increasing milling time up to 36 h. Scanning electron microscope (SEM), and transmission electron microscope (TEM) images show that after 36 h of milling the particle size of the fabricated powder is nano metric (about 20 nm). Results have shown that this system can surmount some main problems occurred in previous similar WC synthesizing systems. For example carbothermic reduction reactions, which lead to the synthesis of W{sub 2}C instead of WC, would not be activated because in this system reactions take place gradually.

  20. Method of freeform fabrication by selective gelation of powder suspensions

    DOE Patents [OSTI]

    Baskaran, S.; Graff, G.L.

    1997-12-09

    The present invention is a novel method for freeform fabrication. Specifically, the method of solid freeform fabrication has the steps of: (a) preparing a slurry by mixing powder particles with a suspension medium and a gelling polysaccharide; (b) making a layer by depositing an amount of said powder slurry in a confined region; (c) hardening a selected portion of the layer by applying a gelling agent to the selected portion; and (d) repeating steps (b) and (c) to make successive layers and forming a layered object. In many applications, it is desirable to remove unhardened material followed by heating to remove gellable polysaccharide then sintering. 2 figs.

  1. Oxide-dispersion strengthening of porous powder metalurgy parts

    DOE Patents [OSTI]

    Judkins, Roddie R. (Knoxville, TN)

    2002-01-01

    Oxide dispersion strengthening of porous metal articles includes the incorporation of dispersoids of metallic oxides in elemental metal powder particles. Porous metal articles, such as filters, are fabricated using conventional techniques (extrusion, casting, isostatic pressing, etc.) of forming followed by sintering and heat treatments that induce recrystallization and grain growth within powder grains and across the sintered grain contact points. The result is so-called "oxide dispersion strengthening" which imparts, especially, large increases in creep (deformation under constant load) strength to the metal articles.

  2. Process for preparing fine grain titanium carbide powder

    DOE Patents [OSTI]

    Janney, M.A.

    1985-03-12

    A method for preparing finely divided titanium carbide powder in which an organotitanate is reacted with a carbon precursor polymer to provide an admixture of the titanium and the polymer at a molecular level due to a crosslinking reaction between the organotitanate and the polymer. The resulting gel is dried, pyrolyzed to drive off volatile components and provide carbon. The resulting solids are then heated at an elevated temperature to convert the titanium and carbon to high-purity titanium carbide powder in a submicron size range.

  3. Nano powders, components and coatings by plasma technique

    DOE Patents [OSTI]

    McKechnie, Timothy N. (Brownsboro, AL); Antony, Leo V. M. (Huntsville, AL); O'Dell, Scott (Arab, AL); Power, Chris (Guntersville, AL); Tabor, Terry (Huntsville, AL)

    2009-11-10

    Ultra fine and nanometer powders and a method of producing same are provided, preferably refractory metal and ceramic nanopowders. When certain precursors are injected into the plasma flame in a reactor chamber, the materials are heated, melted and vaporized and the chemical reaction is induced in the vapor phase. The vapor phase is quenched rapidly to solid phase to yield the ultra pure, ultra fine and nano product. With this technique, powders have been made 20 nanometers in size in a system capable of a bulk production rate of more than 10 lbs/hr. The process is particularly applicable to tungsten, molybdenum, rhenium, tungsten carbide, molybdenum carbide and other related materials.

  4. Method for forming biaxially textured articles by powder metallurgy

    DOE Patents [OSTI]

    Goyal, Amit (Knoxville, TN); Williams, Robert K. (Knoxville, TN); Kroeger, Donald M. (Knoxville, TN)

    2002-01-01

    A method of preparing a biaxially textured alloy article comprises the steps of preparing a mixture comprising Ni powder and at least one powder selected from the group consisting of Cr, W, V, Mo, Cu, Al, Ce, YSZ, Y, Rare Earths, (RE), MgO, CeO.sub.2, and Y.sub.2 O.sub.3 ; compacting the mixture, followed by heat treating and rapidly recrystallizing to produce a biaxial texture on the article. In some embodiments the alloy article further comprises electromagnetic or electro-optical devices and possesses superconducting properties.

  5. Method of freeform fabrication by selective gelation of powder suspensions

    DOE Patents [OSTI]

    Baskaran, Suresh (Kennewick, WA); Graff, Gordon L. (Kennewick, WA)

    1997-01-01

    The present invention is a novel method for freeform fabrication. Specifically, the method of solid freeform fabrication has the steps of: (a) preparing a slurry by mixing powder particles with a suspension medium and a gelling polysaccharide; (b) making a layer by depositing an amount of said powder slurry in a confined region; (c) hardening a selected portion of the layer by applying a gelling agent to the selected portion; and (d) repeating steps (b) and (c) to make successive layers and forming a layered object. In many applications, it is desirable to remove unhardened material followed by heating to remove gellable polysaccharide then sintering.

  6. Process for preparing fine grain titanium carbide powder

    DOE Patents [OSTI]

    Janey, Mark A. (Concord, TN)

    1986-01-01

    A method for preparing finely divided titanium carbide powder in which an organotitanate is reacted with a carbon precursor polymer to provide an admixture of the titanium and the polymer at a molecular-level due to a crosslinking reaction between the organotitanate and the polymer. The resulting gel is dried, pyrolyzed to drive off volatile components and provide carbon. The resulting solids are then heated at an elevated temperature to convert the titanium and carbon to high-purity titanium carbide powder in a submicron size range.

  7. Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Foltz, G.W.; Melius, C.F.

    1987-12-01

    A gas flow apparatus has been constructed and used to study the isotopic exchange reaction occurring between the solid and gas phases in hydrogen (deuterium) gas flows directed through packed-powder beds of ..beta..-phase palladium deuteride (hydride). Spontaneous Raman light scattering is employed to obtain a real-time analysis of the isotopic composition of the gas (H/sub 2/, D/sub 2/, HD) exiting from the bed. A parametric rate-equation model is described which depicts the time-dependent behavior of the isotopic exchange process. The exchange mechanism is assumed to be rate-limited by processes occurring on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas-phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with the experimental measurements and, using a literature value of ..cap alpha.. = 2.4, good agreement is obtained for p approx. = 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of a values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  8. Comparison of MELCOR and SCDAP/RELAP5 results for a low-pressure, short-term station blackout at Browns Ferry

    SciTech Connect (OSTI)

    Carbajo, J.J. [Oak Ridge National Lab., TN (United States)

    1995-12-31

    This study compares results obtained with two U.S. Nuclear Regulatory Commission (NRC)-sponsored codes, MELCOR version 1.8.3 (1.8PQ) and SCDAP/RELAP5 Mod3.1 release C, for the same transient - a low-pressure, short-term station blackout accident at the Browns Ferry nuclear plant. This work is part of MELCOR assessment activities to compare core damage progression calculations of MELCOR against SCDAP/RELAP5 since the two codes model core damage progression very differently.

  9. Explosively driven low-density foams and powders

    DOE Patents [OSTI]

    Viecelli, James A. (Orinda, CA); Wood, Lowell L. (Simi Valley, CA); Ishikawa, Muriel Y. (Livermore, CA); Nuckolls, John H. (Danville, CA); Pagoria, Phillip F. (Livermore, CA)

    2010-05-04

    Hollow RX-08HD cylindrical charges were loaded with boron and PTFE, in the form of low-bulk density powders or powders dispersed in a rigid foam matrix. Each charge was initiated by a Comp B booster at one end, producing a detonation wave propagating down the length of the cylinder, crushing the foam or bulk powder and collapsing the void spaces. The PdV work done in crushing the material heated it to high temperatures, expelling it in a high velocity fluid jet. In the case of boron particles supported in foam, framing camera photos, temperature measurements, and aluminum witness plates suggest that the boron was completely vaporized by the crush wave and that the boron vapor turbulently mixed with and burned in the surrounding air. In the case of PTFE powder, X-ray photoelectron spectroscopy of residues recovered from fragments of a granite target slab suggest that heating was sufficient to dissociate the PTFE to carbon vapor and molecular fluorine which reacted with the quartz and aluminum silicates in the granite to form aluminum oxide and mineral fluoride compounds.

  10. Mechanical Properties of a Metal Powder-Loaded Polyurethane Foam

    SciTech Connect (OSTI)

    C. L. Neuschwanger; L. L. Whinnery; S. H. Goods

    1999-04-01

    Quasi-static compression tests have been performed on polyurethane foam specimens. The modulus of the foam exhibited a power-law dependence with respect to density of the form: E* {proportional_to} {rho}*{sup n}, where n = 1.7. The modulus data is well described by a simple geometric model (attributed to the work of Gibson and Ashby) for closed-cell foam in which the stiffness of the foam is governed by the flexure of the cell struts and cell walls. The compressive strength of the foam is also found to follow a power-law behavior with respect to foam density. In this instance, Euler buckling is used to rationalize the density dependence. The modulus of the polyurethane foam was modified by addition of a gas atomized, spherical aluminum powder. Additions of 30 and 50 weight percent of the powder significantly increased the foam modulus. However, there were only slight increases in modulus with 5 and 10 weight percent additions of the metal powder. Strength was also slightly increased at high loading fractions of powder. This increase in modulus and strength could be predicted by combining the above geometric model with a well-known model describing the effect on modulus of a rigid dispersoid in a compliant matrix.

  11. Green strength of zirconium sponge and uranium dioxide powder compacts

    SciTech Connect (OSTI)

    Balakrishna, Palanki Murty, B. Narasimha; Sahoo, P.K.; Gopalakrishna, T.

    2008-07-15

    Zirconium metal sponge is compacted into rectangular or cylindrical shapes using hydraulic presses. These shapes are stacked and electron beam welded to form a long electrode suitable for vacuum arc melting and casting into solid ingots. The compact electrodes should be sufficiently strong to prevent breakage in handling as well as during vacuum arc melting. Usually, the welds are strong and the electrode strength is limited by the green strength of the compacts, which constitute the electrode. Green strength is also required in uranium dioxide (UO{sub 2}) powder compacts, to withstand stresses during de-tensioning after compaction as well as during ejection from the die and for subsequent handling by man and machine. The strengths of zirconium sponge and UO{sub 2} powder compacts have been determined by bending and crushing respectively, and Weibul moduli evaluated. The green density of coarse sponge compact was found to be larger than that from finer sponge. The green density of compacts from lightly attrited UO{sub 2} powder was higher than that from unattrited category, accompanied by an improvement in UO{sub 2} green crushing strength. The factors governing green strength have been examined in the light of published literature and experimental evidence. The methodology and results provide a basis for quality control in metal sponge and ceramic powder compaction in the manufacture of nuclear fuel.

  12. Oxide Dispersion Strengthened Iron Aluminide by CVD Coated Powders

    SciTech Connect (OSTI)

    Asit Biswas Andrew J. Sherman

    2006-09-25

    This I &I Category2 program developed chemical vapor deposition (CVD) of iron, aluminum and aluminum oxide coated iron powders and the availability of high temperature oxidation, corrosion and erosion resistant coating for future power generation equipment and can be used for retrofitting existing fossil-fired power plant equipment. This coating will provide enhanced life and performance of Coal-Fired Boilers components such as fire side corrosion on the outer diameter (OD) of the water wall and superheater tubing as well as on the inner diameter (ID) and OD of larger diameter headers. The program also developed a manufacturing route for readily available thermal spray powders for iron aluminide coating and fabrication of net shape component by powder metallurgy route using this CVD coated powders. This coating can also be applid on jet engine compressor blade and housing, industrial heat treating furnace fixtures, magnetic electronic parts, heating element, piping and tubing for fossil energy application and automotive application, chemical processing equipment , heat exchanger, and structural member of aircraft. The program also resulted in developing a new fabrication route of thermal spray coating and oxide dispersion strengthened (ODS) iron aluminide composites enabling more precise control over material microstructures.

  13. Process Simulation of Cold Pressing and Sintering of Armstrong CP-Ti Powders

    SciTech Connect (OSTI)

    Gorti, Sarma B; Sabau, Adrian S; Peter, William H; Nunn, Stephen D; Yamamoto, Yukinori; Chen, Wei

    2011-01-01

    A computational methodology is presented for the process simulation of cold pressing and sintering of Armstrong CP-Ti powders. Since the powder consolidation is governed by specific pressure-dependent constitutive equations, solution algorithms were developed for the ABAQUS user material subroutine, UMAT, for computing the plastic strain increments based on an implicit integration of the nonlinear yield function, flow rule, and hardening equations. Sintering was simulated using a model based on diffusional creep using the user subroutine CREEP. The initial mesh, stress, and density for the simulation of sintering were obtained from the results of the cold pressing simulation, minimizing the errors from decoupling the cold pressing and sintering simulations. Numerical simulation results are presented for the cold compaction followed by a sintering step of the Ti powders. The numerical simulation results for the relative density were compared to those measured from experiments before and after sintering, showing that the relative density can be accurately predicted. Notice: This manuscript has been authored by UT-Battelle, LLC, under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. ACKNOWLEDGEMENTS This research was sponsored by the U.S. DOE, and carried out at ORNL, under Contract DE-AC05-00OR22725 with UT-Battelle, LLC. This research was sponsored by the U.S. DOE, EERE Industrial Technology Program Office under CPS Agreement # 17881.

  14. A facile method for nickel catalyst immobilization on ultra fine Al{sub 2}O{sub 3} powders

    SciTech Connect (OSTI)

    Zhang, T.; Wen, G.; Huang, X.X.; Zhong, B.; Zhang, X.D.; Bai, H.W.; Yu, H.M.

    2010-07-15

    A pure nickel coating has been successfully plated on the surface of ultra fine Al{sub 2}O{sub 3} particles via a facile electroless plating method. Coating morphology and crystallite size can be tailored by pH values. Dense coating with the maximum crystallite size of 24 nm was obtained at pH 11.0 and porous coating with the minimum crystallite size of 15 nm was obtained at pH value 12.5. The plated powders have been demonstrated to be an effective catalyst for growing boron nitride nanotubes.

  15. A cost-effective process to prepare VO{sub 2} (M) powder and films with superior thermochromic properties

    SciTech Connect (OSTI)

    Xiao, Xiudi; Zhang, Hua; Chai, Guanqi; Sun, Yaoming; Yang, Tao; Cheng, Haoliang; Chen, Lihua; Miao, Lei; Xu, Gang

    2014-03-01

    Graphical abstract: Combining codeposition and short time post annealing, VO{sub 2} (M) with high quality and excellent phase transition performance is obtained. After mixing the VO{sub 2} powder with acrylic resin, the composite films deposited on glass show superior visible transmission and solar modulation, which can be used as an excellent candidate of low cost smart window in energy saving field. - Highlights: • The VO{sub 2} powder obtained by short time thermolysis method is high purity and crystallinity with superior phase transition performance. • The maximum decreasing efficiency of phase transition temperature is about ?30 K/at% with w = 0.4 at%. • After mixing VO{sub 2} powder with acrylic resin, the maximal visible transmission of the composite films is 48% and the transmission modulation at 2000 nm is 37.3% with phase transition temperature of 66.2 °C. • Though the phase transition performance is weakened by tungsten doping, the film prepared by 1.3 at% tungsten doped VO{sub 2} still show superior transmission modulation about 26.4%, which means that it is a potential candidate as smart windows. - Abstract: VO{sub 2} powder with superior phase transition performance was prepared by convenient thermolysis method. The results illustrated that VO{sub 2} powder show high purity and crystallinity. VO{sub 2} particles are transformed from cluster to quasi-sphere with the increase of annealing temperature. The DSC analysis proves that VO{sub 2} show superior phase transition performance around 68 °C. The phase transition temperature can be reduced to 33.5 °C by 1.8 at% tungsten doping. The maximum decreasing efficiency of phase transition temperature is about ?30 K/at% with w = 0.4 at%. After mixing VO{sub 2} powder with acrylic resin, the maximal visible transmission of the composite thin films on glass is 48% and the transmission modulation at 2000 nm is 37.3% with phase transition temperature of 66.2 °C. Though the phase transition performance is weakened by tungsten doping, the film prepared by 1.3 at% tungsten doped VO{sub 2} still show superior transmission modulation about 26.4% at 2000 nm, which means that it is a potential candidate as smart windows.

  16. Recyclability study on Inconel 718 and Ti-6Al-4V powders for...

    Office of Scientific and Technical Information (OSTI)

    that govern the powder reuse times. This work presents the results from a recyclability study conducted on Inconel 718 and Ti-6Al-4V powders. It has been found that the Inconel...

  17. Nonaqueous solution synthesis process for preparing oxide powders of lead zirconate titanate and related materials

    DOE Patents [OSTI]

    Voigt, J.A.; Sipola, D.L.; Tuttle, B.A.; Anderson, M.T.

    1999-06-01

    A process is disclosed for producing powders of perovskite-type compounds which comprises mixing a metal alkoxide solution with a lead acetate solution to form a homogeneous, clear metal solution, adding an oxalic acid/n-propanol solution to this metal solution to form an easily filterable, free-flowing precursor powder and then calcining this powder. This process provides fine perovskite-phase powders with ferroelectric properties which are particularly useful in a variety of electronic applications. 4 figs.

  18. Nonaqueous solution synthesis process for preparing oxide powders of lead zirconate titanate and related materials

    DOE Patents [OSTI]

    Voigt, James A. (Corrales, NM); Sipola, Diana L. (Albuquerque, NM); Tuttle, Bruce A. (Albuquerque, NM); Anderson, Mark T. (Woodbury, MN)

    1999-01-01

    A process for producing powders of perovskite-type compounds which comprises mixing a metal alkoxide solution with a lead acetate solution to form a homogeneous, clear metal solution, adding an oxalic acid/n-propanol solution to this metal solution to form an easily filterable, free-flowing precursor powder and then calcining this powder. This process provides fine perovskite-phase powders with ferroelectric properties which are particularly useful in a variety of electronic applications.

  19. Synthesis of nanostructured LiTi{sub 2}(PO{sub 4}){sub 3} powder by a Pechini-type polymerizable complex method

    SciTech Connect (OSTI)

    Mariappan, C.R.; Galven, C.; Crosnier-Lopez, M.-P.; Le Berre, F.; Bohnke, O. . E-mail: odile.bohnke@univ-lemans.fr

    2006-02-15

    The nanostructured NASICON-type LiTi{sub 2}(PO{sub 4}){sub 3} (LTP) material has been synthesized by Pechini-type polymerizable complex method. The use of water-soluble ammonium citratoperoxotitanate (IV) metal complex instead of alkoxides as precursor allows to prepare monophase material. Thermal analyses have been carried out on the powder precursor to check the weight loss and synthesis temperature. X-ray powder diffraction analysis (XRD) has been performed on the LTP powder obtained after heating the powder precursor over a temperature range from 550 to 1050 deg. C for 2 h. By varying the molar ratio of citric acid to metal ion (CA/Ti) and citric acid to ethylene glycol (CA/EG), the grain size of the LTP powder could be modified. The formation of small and well-crystalline grains, in the order of 50-125 nm in size, has been determined from the XRD patterns and confirmed by transmission electron microscopy.

  20. Study of the fast reaction characteristics of aluminized PETN explosive powders

    SciTech Connect (OSTI)

    Hu Dong; Sun Zhumei

    1996-05-01

    The fast reaction characteristics of aluminized PETN (pentaerythrite tetranitrate) explosive powders have been studied successfully by means of a spectrum-detecting and recovery technique. The results show that the appropriate particle size and content of aluminium powder in the aluminized PETN explosive powders are 44 {micro}m and 33%, respectively.

  1. Development of Metal/Polymer Mixtures for Micro Powder Injection Moulding

    SciTech Connect (OSTI)

    Quinard, C.; Barriere, T.; Gelin, J. C.

    2007-04-07

    Important research tasks at ENSMM/LMA are concerned for the development of mixtures of Fine powders associated to polymer binders dedicated to the powder injection moulding (PIM) and to the powder injection micro-moulding ({mu}PIM) in accordance with many works already carried out with different feedstock suppliers dedicated to the macro-components.

  2. The oxidation-reduction kinetics of palladium powder

    SciTech Connect (OSTI)

    Munir, Z.A.; Coombs, P.G.

    1983-03-01

    The cyclic oxidation-reduction of submicrometer sized palladium powder was investigated over the temperature range 848 to 923 K. The total oxygen uptake decreased with increasing number of cycles as a consequence of sintering. Sintering was restricted to the reduction steps in these cycles. The relationships for the rate constants of the oxidation and reduction processes are, respectively, (1.04)10/sup 6/ exp(-(74.1)10/sup 3//RT), and (7.63)10/sup 12/ exp(-(207.9)10/sup 3//RT). The activation energies for the oxidation of palladium powder and the reduction of palladium oxide are 74.1 and 207.9 kJ mol/sup -1/, respectively.

  3. Surface modification of silicon nitride powder with aluminum

    SciTech Connect (OSTI)

    Han, K.R.; Lim, C.S.; Hong, M.J.; Choi, S.K.; Kwon, S.H.

    1996-02-01

    Surface modification of Si{sub 3}N{sub 4} with alumina was tried. It was achieved by simply mixing Si{sub 3}N{sub 4} powder with an alumina sol up to {approximately}2 wt% as alumina in an aqueous medium, dried, and followed by calcination at 400 C for 1 h. A TEM micrograph showed a coating layer of {approximately} 15 nm thickness. The isoelectric point of the modified Si{sub 3}N{sub 4} powder with porous alumina was at 0H 7.8, which is different from 5.8 and 8.6 for Si{sub 3}N{sub 4} and amorphous alumina, respectively.

  4. A dry powder stump applicator for a feller-buncher.

    SciTech Connect (OSTI)

    Karsky, Richard, J.; Cram Michelle; Thistle, Harold

    1998-07-11

    Karsky, D., M. Cram, and H. Thistle. 1998. A dry powder borax stump applicator for a feller-buncher. Presented at the 1998 ASAE Annual International Meeting at Colorado Springs Resort, Orlando, Florida, July 11-16, 1998. Paper No. 987023. ASAE, 2950 Niles Road, St. Joseph, MI 49085-9659. Annosum root rot affects conifers throughout the Northern Hemisphere, infecting the roots and eventually killing the trees. An applicator attachment has been developed that mounts to the back of a feller-buncher saw head, that can reduce mortality from Heterobasidion annosum. The attachment applies a borax powder to a stump immediately after the tree has been cut. This document provides information on the design, development and testing of an applicator for applying dry borax on tree stumps at the time of harvesting to reduce future losses due to root rot.

  5. Mesoporous-silica films, fibers, and powders by evaporation

    DOE Patents [OSTI]

    Bruinsma, P.J.; Baskaran, S.; Bontha, J.R.; Liu, J.

    1999-07-13

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s). 24 figs.

  6. Mesoporous-silica films, fibers, and powders by evaporation

    DOE Patents [OSTI]

    Bruinsma, Paul J. (Kennewick, WA); Baskaran, Suresh (Kennewick, WA); Bontha, Jagannadha R. (Richland, WA); Liu, Jun (West Richland, WA)

    1999-01-01

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s).

  7. Mesoporous-silica films, fibers, and powders by evaporation

    DOE Patents [OSTI]

    Bruinsma, Paul J.; Baskaran, Suresh; Bontha, Jagannadha R.; Liu, Jun

    2008-05-06

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s).

  8. Stabilized Lithium Metal Powder, Enabling Material and Revolutionary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology for High Energy Li-ion Batteries | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es011_yakovleva_2011_p.pdf More Documents & Publications Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries Vehicle Technologies Office: 2010 Energy Storage R&D Annual Progress Report Modular Process Equipment for Low Cost Manufacturing

  9. Supercritical fluid molecular spray film deposition and powder formation

    DOE Patents [OSTI]

    Smith, Richard D.

    1986-01-01

    Solid films are deposited, or fine powders formed, by dissolving a solid material into a supercritical fluid solution at an elevated pressure and then rapidly expanding the solution through a short orifice into a region of relatively low pressure. This produces a molecular spray which is directed against a substrate to deposit a solid thin film thereon, or discharged into a collection chamber to collect a fine powder. Upon expansion and supersonic interaction with background gases in the low pressure region, any clusters of solvent are broken up and the solvent is vaporized and pumped away. Solute concentration in the solution is varied primarily by varying solution pressure to determine, together with flow rate, the rate of deposition and to control in part whether a film or powder is produced and the granularity of each. Solvent clustering and solute nucleation are controlled by manipulating the rate of expansion of the solution and the pressure of the lower pressure region. Solution and low pressure region temperatures are also controlled.

  10. Titanium Sheet Fabricated from Powder for Industrial Applications

    SciTech Connect (OSTI)

    Peter, William H; Muth, Thomas R; Chen, Wei; Yamamoto, Yukinori; Jolly, Brian C; Stone, Nigel; Cantin, G.M.D.; Barnes, John; Paliwal, Muktesh; Smith, Ryan; Capone, Joseph; Liby, Alan L; Williams, James C; Blue, Craig A

    2012-01-01

    In collaboration with Ametek and Commonwealth Scientific and Industrial Research Organization (CSIRO), Oak Ridge National Laboratory has evaluated three different methods for converting titanium hydride-dehydride (HDH) powder into thin gauge titanium sheet from a roll compacted preform. Methodologies include sintering, followed by cold rolling and annealing; direct hot rolling of the roll-compacted sheet; and hot rolling of multiple layers of roll compacted sheet that are encapsulated in a steel can. All three methods have demonstrated fully consolidated sheet, and each process route has the ability to produce sheet that meets ASTM B265 specifications. However, not every method currently provides sheet that can be highly formed without tearing. The degree of sintering between powder particles, post processing density, and the particle to particle boundary layer where compositional variations may exist, have a significant effect on the ability to form the sheet into useful components. Uniaxial tensile test results, compositional analysis, bend testing, and biaxial testing of the titanium sheet produced from hydride-dehydride powder will be discussed. Multiple methods of fabrication and the resulting properties can then be assessed to determine the most economical means of making components for industrial applications.

  11. Component Repair Times Obtained from MSPI Data

    SciTech Connect (OSTI)

    Eide, Steven A.

    2015-05-01

    Information concerning times to repair or restore equipment to service given a failure is valuable to probabilistic risk assessments (PRAs). Examples of such uses in modern PRAs include estimation of the probability of failing to restore a failed component within a specified time period (typically tied to recovering a mitigating system before core damage occurs at nuclear power plants) and the determination of mission times for support system initiating event (SSIE) fault tree models. Information on equipment repair or restoration times applicable to PRA modeling is limited and dated for U.S. commercial nuclear power plants. However, the Mitigating Systems Performance Index (MSPI) program covering all U.S. commercial nuclear power plants provides up-to-date information on restoration times for a limited set of component types. This paper describes the MSPI program data available and analyzes the data to obtain median and mean component restoration times as well as non-restoration cumulative probability curves. The MSPI program provides guidance for monitoring both planned and unplanned outages of trains of selected mitigating systems deemed important to safety. For systems included within the MSPI program, plants monitor both train UA and component unreliability (UR) against baseline values. If the combined system UA and UR increases sufficiently above established baseline results (converted to an estimated change in core damage frequency or CDF), a “white” (or worse) indicator is generated for that system. That in turn results in increased oversight by the US Nuclear Regulatory Commission (NRC) and can impact a plant’s insurance rating. Therefore, there is pressure to return MSPI program components to service as soon as possible after a failure occurs. Three sets of unplanned outages might be used to determine the component repair durations desired in this article: all unplanned outages for the train type that includes the component of interest, only unplanned outages associated with failures of the component of interest, and only unplanned outages associated with PRA failures of the component of interest. The paper will describe how component repair times can be generated from each set and which approach is most applicable. Repair time information will be summarized for MSPI pumps and diesel generators using data over 2003 – 2007. Also, trend information over 2003 – 2012 will be presented to indicate whether the 2003 – 2007 repair time information is still considered applicable. For certain types of pumps, mean repair times are significantly higher than the typically assumed 24 h duration.

  12. Sol-spray preparation, particulate characteristics, and sintering of alumina powders

    SciTech Connect (OSTI)

    Varma, H.K.; Mani, T.V.; Damodaran, A.D.; Warrier, K.G.K.; Balachandran, U.

    1993-07-01

    Fine alumina powders of spherical morphology and narrow particle-size distribution have been synthesized by a technique that uses precipitation/peptization/spray drying of boehmite sol prepared from aluminum nitrate. The spray-dried powder was further washed with solvents of varying polarities, such as acetone, isopropanol, and tert-butanol. This post-spray-drying treatment changed the powder`s particle-size distribution, morphology, density, and compaction characteristics. Microstructure, dielectric properties, and effect of post-treatment on the boehmite-sol-derived alumina powders in reducing agglomeration are discussed.

  13. Powder processing for fabricating Si{sub 3}N{sub 4} ceramics

    SciTech Connect (OSTI)

    Kamiya, Hidehiro; Naito, Makio; Hotta, Tadashi; Isomura, Kenji; Tsubaki, Junichiro; Uematsu, Keizo

    1997-10-01

    Usually, the densification of silicon nitride ceramics requires a sintering aid, e.g., alumina and yttria fine powders. Many types of dispersants have been used to obtain a uniform mixture of silicon nitride and sintering aid. These dispersants affect the microstructure and strength of the spray-dried granules. However, few studies have been made of the effects of the microstructure and strength of spray-dried granules. However, few studies have been made of the effects of the microstructure and strength of spray-dried granules on the sintered and mechanical properties of non-oxide ceramics. This article shows the effect of such intergranular porosity--controlled by the strength and structure of spray-dried granules--on the densification of green compacts during sintering. Furthermore, relationships between the fracture strength distribution of spray-dried granules and bending strength distributions of sintered bodies are discussed.

  14. Thermal analysis of pentaerythritol tetranitrate and development of a powder aging model

    SciTech Connect (OSTI)

    Brown, Geoffrey W; Sandstrom, Mary M; Giambra, Anna M; Archuleta, Jose G; Monroe, Deirde C

    2009-01-01

    We have applied a range of different physical and thermal analysis techniques to characterize the thermal evolution of the specific surface area of pentaerythritol tetranitrate (PETN) powders. Using atomic force microscopy we have determined that the mass transfer mechanism leading to powder coarsening is probably sublimation and redeposition of PETN. Using thermogravimetric analysis we have measured vapor pressures of PETN powders whose aging will be simulated in future work. For one specific powder we have constructed an empirical model of the coarsening that is fit to specific surface area measurements at 60 C to 70 C to provide predictive capability of that powder's aging. Modulated differential scanning calorimetry and mass spectroscopy measurements highlight some of the thermal behavior of the powders and suggest that homologue-based eutectics and impurities are localized in the powder particles.

  15. An electrochemical cell for in operando studies of lithium/sodium batteries using a conventional x-ray powder diffractometer

    SciTech Connect (OSTI)

    Shen, Yanbin; Pedersen, Erik E.; Christensen, Mogens; Iversen, Bo B.

    2014-10-15

    An electrochemical cell has been designed for powder X-ray diffraction studies of lithium ion batteries (LIB) and sodium ion batteries (SIB) in operando with high time resolution using a conventional powder X-ray diffractometer. The cell allows for studies of both anode and cathode electrode materials in reflection mode. The cell design closely mimics that of standard battery testing coin cells and allows obtaining powder X-ray diffraction patterns under representative electrochemical conditions. In addition, the cell uses graphite as the X-ray window instead of beryllium, and it is easy to operate and maintain. Test examples on lithium insertion/extraction in two spinel-type LIB electrode materials (Li{sub 4}Ti{sub 5}O{sub 12} anode and LiMn{sub 2}O{sub 4} cathode) are presented as well as first results on sodium extraction from a layered SIB cathode material (Na{sub 0.84}Fe{sub 0.56}Mn{sub 0.44}O{sub 2})

  16. Anisotropic hot deformed magnets prepared from Zn-coated MRE-Fe-B ribbon powder (MRE?=?Nd?+?Y?+?Dy)

    SciTech Connect (OSTI)

    Tang, W; Zhou, L; Sun, K W; Dennis, K W; Kramer, M J; Anderson, I E; McCallum, R W

    2014-05-07

    Milled melt-spun ribbon flake of MRE-Fe-B coated with Zn coating using a vapor transport technique was found to have significant increase in coercivity without degrading the magnetization when the Zn thickness and heat treatment were optimized. Magnetic measurements show that 0.5–1?wt.?% Zn coating increases the coercivity about 1?kOe over the initial ribbon powder. After vacuum hot deformation (VHD), the VHD magnet with Zn coating of 0.5?wt.?% results in a nearly 3?kOe higher coercivity than an un-coated alloy magnet. An optimized VHD magnet with 0.5?wt.?% Zn coating obtains a coercivity of 11.2?kOe and (BH)max of 23.0 MGOe, respectively. SEM and TEM microstructures analysis demonstrates that the Zn coating on the surface of ribbon powder has diffused along the intergranular boundaries after the ribbon powder was annealed at 750?°C for 30?min or was hot deformed at 700–750?°C.

  17. EIS-0435: Modification of the Groton Generation Station Interconnection Agreement, Brown County, South Dakota

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of a proposal for DOE's Western Area Power Administration to modify its Large Generator Connection Agreement for the Groton Generation Station in Brown County, South Dakota. The modification would allow Basin Electric Power Cooperative, which operates the generation station, to produce power above the current operating limit of 50 average megawatts.

  18. Martensitic transformation behaviors of rapidly solidified Ti–Ni–Mo powders

    SciTech Connect (OSTI)

    Kim, Yeon-wook

    2012-10-15

    For the fabrication of bulk near-net-shape shape memory alloys and porous metallic biomaterials, consolidation of Ti–Ni–Mo alloy powders is more useful than that of elemental powders of Ti, Ni and Mo. Ti{sub 50}Ni{sub 49.9}Mo{sub 0.1} shape memory alloy powders were prepared by gas atomization, and transformation temperatures and microstructures of those powders were investigated as a function of powder size. XRD analysis showed that the B2–R–B19 martensitic transformation occurred in powders smaller than 150 ?m. According to DSC analysis of the as-atomized powders, the B2–R transformation temperature (T{sub R}) of the 25–50 ?m powders was 18.4 °C. The T{sub R} decreased with increasing powder size, however, the difference in T{sub R} between 25–50 ?m powders and 100–150 ?m powders is only 1 °C. Evaluation of powder microstructures was based on SEM examination of the surface and the polished and etched powder cross sections and the typical images of the rapidly solidified powders showed cellular morphology. Porous cylindrical foams of 10 mm diameter and 1.5 mm length were fabricated by spark plasma sintering (SPS) at 800 °C and 5 MPa. Finally these porous TiNi alloy samples are heat-treated for 1 h at 850 °C, and then quenched in ice water. The bulk samples have 23% porosity and 4.6 g/cm{sup 3} density and their T{sub R} is 17.8 °C.

  19. Structural studies of magnesium nitride fluorides by powder neutron diffraction

    SciTech Connect (OSTI)

    Brogan, Michael A.; Hughes, Robert W.; Smith, Ronald I.; Gregory, Duncan H.

    2012-01-15

    Samples of ternary nitride fluorides, Mg{sub 3}NF{sub 3} and Mg{sub 2}NF have been prepared by solid state reaction of Mg{sub 3}N{sub 2} and MgF{sub 2} at 1323-1423 K and investigated by powder X-ray and powder neutron diffraction techniques. Mg{sub 3}NF{sub 3} is cubic (space group: Pm3m) and has a structure related to rock-salt MgO, but with one cation site vacant. Mg{sub 2}NF is tetragonal (space group: I4{sub 1}/amd) and has an anti-LiFeO{sub 2} related structure. Both compounds are essentially ionic and form structures in which nitride and fluoride anions are crystallographically ordered. The nitride fluorides show temperature independent paramagnetic behaviour between 5 and 300 K. - Graphical abstract: Definitive structures of the ternary magnesium nitride fluorides Mg{sub 3}NF{sub 3} and the lower temperature polymorph of Mg{sub 2}NF have been determined from powder neutron diffraction data. The nitride halides are essentially ionic and exhibit weak temperature independent paramagnetic behaviour. Highlights: Black-Right-Pointing-Pointer Definitive structures of Mg{sub 3}NF{sub 3} and Mg{sub 2}NF were determined by neutron diffraction. Black-Right-Pointing-Pointer Nitride and fluoride anions are crystallographically ordered in both structures. Black-Right-Pointing-Pointer Both compounds exhibit weak, temperature independent paramagnetic behaviour. Black-Right-Pointing-Pointer The compounds are essentially ionic with ionicity increasing with F{sup -} content.

  20. Production of films and powders for semiconductor device applications

    DOE Patents [OSTI]

    Bhattacharya, Raghu Nath (Littleton, CO); Noufi, Rommel (Golden, CO); Wang, Li (Golden, CO)

    1998-01-01

    A process for chemical bath deposition of selenide and sulfide salts as films and powders employable as precursors for the fabrication of solar cell devices. The films and powders include (1) Cu.sub.x Se.sub.n, wherein x=1-2 and n=1-3; (2) Cu.sub.x Ga.sub.y Se.sub.n, wherein x=1-2, y=0-1 and n=1-3; (3) Cu.sub.x In.sub.y Se.sub.n, wherein x=1-2.27, y=0.72-2 and n=1-3; (4) Cu.sub.x (InGa).sub.y Se.sub.n, wherein x=1-2.17, y=0.96-2 and n=1-3; (5) In.sub.y Se.sub.n, wherein y=1-2.3 and n=1-3; (6) Cu.sub.x S.sub.n, wherein x=1-2 and n=1-3; and (7) Cu.sub.x (InGa).sub.y (SeS).sub.n, wherein x=1-2, y=0.07-2 and n=0.663-3. A reaction vessel containing therein a substrate upon which will form one or more layers of semiconductor material is provided, and relevant solution mixtures are introduced in a sufficient quantity for a sufficient time and under favorable conditions into the vessel to react with each other to produce the resultant salt being prepared and deposited as one or more layers on the substrate and as a powder on the floor of the vessel. Hydrazine is present during all reaction processes producing non-gallium containing products and optionally present during reaction processes producing gallium-containing products to function as a strong reducing agent and thereby enhance reaction processes.

  1. Production of films and powders for semiconductor device applications

    DOE Patents [OSTI]

    Bhattacharya, R.N.; Noufi, R.; Li Wang

    1998-03-24

    A process is described for chemical bath deposition of selenide and sulfide salts as films and powders employable as precursors for the fabrication of solar cell devices. The films and powders include (1) Cu{sub x}Se{sub n}, wherein x=1--2 and n=1--3; (2) Cu{sub x}Ga{sub y}Se{sub n}, wherein x=1--2, y=0--1 and n=1--3; (3) Cu{sub x}In{sub y}Se{sub n}, wherein x=1--2.27, y=0.72--2 and n=1--3; (4) Cu{sub x}(InGa){sub y}Se{sub n}, wherein x=1--2.17, y=0.96--2 and n=1--3; (5) In{sub y}Se{sub n}, wherein y=1--2.3 and n=1--3; (6) Cu{sub x}S{sub n}, wherein x=1--2 and n=1--3; and (7) Cu{sub x}(InGa){sub y}(SeS){sub n}, wherein x=1--2, y=0.07--2 and n=0.663--3. A reaction vessel containing therein a substrate upon which will form one or more layers of semiconductor material is provided, and relevant solution mixtures are introduced in a sufficient quantity for a sufficient time and under favorable conditions into the vessel to react with each other to produce the resultant salt being prepared and deposited as one or more layers on the substrate and as a powder on the floor of the vessel. Hydrazine is present during all reaction processes producing non-gallium containing products and optionally present during reaction processes producing gallium-containing products to function as a strong reducing agent and thereby enhance reaction processes. 4 figs.

  2. Bulk synthesis of nanoporous palladium and platinum powders

    DOE Patents [OSTI]

    Robinson, David B. (Fremont, CA); Fares, Stephen J. (Pleasanton, CA); Tran, Kim L. (Livermore, CA); Langham, Mary E. (Pleasanton, CA)

    2012-04-17

    Disclosed is a method for providing nanoporous palladium and platinum powders. These materials were synthesized on milligram to gram scales by chemical reduction of tetrahalo-complexes with ascorbate in a concentrated aqueous surfactant at temperatures between -20.degree. C. and 30.degree. C. The prepared particles have diameters of approximately 50 nm, wherein each particle is perforated by pores having diameters of approximately 3 nm, as determined by electron tomography. These materials are of potential value for hydrogen and electrical charge storage applications.

  3. ECCENTRIC ROLLING OF POWDER AND BONDING AGENT INTO SPHERICAL PELLETS

    DOE Patents [OSTI]

    Patton, G. Jr.; Zirinsky, S.

    1961-06-01

    A machine is described for pelletizing powder and bonding agent into spherical pellets of high density and uniform size. In this device, the material to be compacted is added to a flat circular pan which is moved in a circular orbit in a horizontal plane about an axis displaced from that of the pan's central axis without rotating the pan about its central axis. This movement causes the material contained therein to roll around the outside wall of the container and build up pellets of uniform shape, size, and density.

  4. New coal dewatering technology turns sludge to powder

    SciTech Connect (OSTI)

    2009-03-15

    Virginian Tech's College of Engineering's Roe-Hoan Yoon and his group have developed a hyperbaric centrifuge that can dewater coal as fine as talcum powder. Such coal fines presently must be discarded by even the most advanced coal cleaning plants because of their high moisture content. The new technology can be used with the Microcel technology to remove ash, to re-mine the fine coal discarded to impoundments and to help minimize waste generation. Virginia Tech has received $1 million in funding from the US Department of State to also help the Indian coal industry produce a cleaner product. 1 photo.

  5. Bulk synthesis of nanoporous palladium and platinum powders

    DOE Patents [OSTI]

    Robinson, David B; Fares, Stephen J; Tran, Kim L; Langham, Mary E

    2014-04-15

    Disclosed is a method for providing nanoporous palladium and platinum powders. These materials were synthesized on milligram to gram scales by chemical reduction of tetrahalo-complexes with ascorbate in a concentrated aqueous surfactant at temperatures between -20.degree. C. and 30.degree. C. The prepared particles have diameters of approximately 50 nm, wherein each particle is perforated by pores having diameters of approximately 3 nm, as determined by electron tomography. These materials are of potential value for hydrogen and electrical charge storage applications.

  6. Carbon Dioxide Sorption Isotherms and Matrix Transport Rates for Non-Powdered Coal

    SciTech Connect (OSTI)

    Smith, D.H.; Jikich, S.; Seshadri, K.

    2007-05-01

    For enhanced coalbed methane/carbon dioxide sequestration field projects, carbon dioxide isotherms and the rate of diffusion of the carbon dioxide from the cleats into the matrix are important parameters for predicting how much carbon dioxide actually will be sequestered under various operating conditions. Manometric (or pressure swing) experiments on powdered coal provide a quick, simple, and relatively inexpensive method for measuring sorption isotherms. However, determination of the rate of transport from cleat into matrix from the rate of gas pressure drop is difficult, if not impossible. (The characteristic time constant for the transport depends on the cleat spacing as well as the rate of diffusion.) Manometric measurements often yield isotherms that are extremely problematic in the region of the carbon dioxide critical point; perhaps even worse, available data seem to indicate that the sorption isotherms measured for powders are much larger than the isotherms of coal cores. Measurements on centimeter-sized samples can take weeks or months to reach equilibrium; for such equilibration times gas leakage rates that would be of no significance in powdered-coal measurements can completely invalidate manometric measurements on coal cores. We have tested and used a simple, inexpensive method for measuring isotherms and carbon dioxide transport rates in coal cores. One or more cores are placed in a simple pressure vessel, and a constant pressure is maintained in the vessel by connecting it to a gas supply (which contains a very large amount of gas compared to amount that could leak over the course of the experiment). From time to time the gas supply is shut off, the sample is removed, and its weight is recorded at ambient pressure at frequent time intervals for a period of about one hour. The sample is then returned to the pressure vessel, the carbon dioxide pressure restored to its previous value, and the equilibration resumed until the next sample weighing. For a point on the isotherm, the process is repeated until the sample weight reaches a constant value (i.e., typically equilibration times of several weeks). The slope of a plot of sample weight vs. square root of elapsed desorption time gives a measurement for the rate of diffusion. In order to advance all three experimental methods, results from this “ambient-pressure gravimetry” method were compared with data obtained by conventional manometry and by computer tomography. The isotherm and “diffusion” rate measured for the core can be directly used in simulators for reservoir engineering studies of coalseam sequestration and enhanced coalbed methane production.

  7. Oxidation kinetics of calcium-doped palladium powders

    SciTech Connect (OSTI)

    Jain, S.; Kodas, T.T.; Hampden-Smith, M. [Univ. of New Mexico, Albuquerque, NM (United States)

    1997-04-01

    The oxidation kinetics of submicron Ca-containing Pd powders produced by spray pyrolysis were studied in the temperature range 600 to 675 C using thermogravimetric analysis. The oxidation of pure Pd powder had an activation energy of {approximately}230 kJ/mol in the region 27% < oxidation < 70% and 65 kJ/mol for oxidation > 70%. The activation energies for Pd particles containing 0.01 weight percent (w/o) and 0.4 w/o Ca in the region 27% < oxidation < 70% were {approximately}230 kJ/mol and {approximately}50 kJ/mol, respectively. Transmission electron microscopy suggested that the conversion of Pd to Pd{sup II}O (stoichiometric PdO) proceeds from the particle surface into the interior and not homogeneously throughout the particle. The predictions of a variety of models and rate laws (shrinking core, parabolic, cubic, logarithmic, and inverse logarithmic) were compared with the data. The comparison suggested a mechanism in which oxidation of pure Pd proceeds by chemisorption and diffusion of oxygen to form a substoichiometric oxide, followed by the conversion of substoichiometric PdO to Pd{sup II}O. Oxidation of pure Pd is then probably limited by the diffusion of oxygen through the substoichiometric PdO and/or Pd{sup II}O. The addition of Ca increased the oxidation resistance of Pd most likely by inhibiting oxygen diffusion through the metal oxide layers surrounding the Pd.

  8. Method for removing oxide contamination from silicon carbide powders

    DOE Patents [OSTI]

    Brynestad, J.; Bamberger, C.E.

    1984-08-01

    The described invention is directed to a method for removing oxide contamination in the form of oxygen-containing compounds such as SiO/sub 2/ and B/sub 2/O/sub 3/ from a charge of finely divided silicon carbide. The silicon carbide charge is contacted with a stream of hydrogen fluoride mixed with an inert gas carrier such as argon at a temperature in the range of about 200/sup 0/ to 650/sup 0/C. The oxides in the charge react with the heated hydrogen fluoride to form volatile gaseous fluorides such as SiF/sub 4/ and BF/sub 3/ which pass through the charge along with unreacted hydrogen fluoride and the carrier gas. Any residual gaseous reaction products and hydrogen fluoride remaining in the charge are removed by contacting the charge with the stream of inert gas which also cools the powder to room temperature. The removal of the oxygen contamination by practicing the present method provides silicon carbide powders with desirable pressing and sintering characteristics. 1 tab.

  9. Powder metallurgy processing and deformation characteristics of bulk multimodal nickel

    SciTech Connect (OSTI)

    Farbaniec, L.; Dirras, G.; Krawczynska, A.; Mompiou, F.; Couque, H.; Naimi, F.; Bernard, F.; Tingaud, D.

    2014-08-15

    Spark plasma sintering was used to process bulk nickel samples from a blend of three powder types. The resulting multimodal microstructure was made of coarse (average size ? 135 ?m) spherical microcrystalline entities (the core) surrounded by a fine-grained matrix (average grain size ? 1.5 ?m) or a thick rim (the shell) distinguishable from the matrix. Tensile tests revealed yield strength of ? 470 MPa that was accompanied by limited ductility (? 2.8% plastic strain). Microstructure observation after testing showed debonding at interfaces between the matrix and the coarse entities, but in many instances, shallow dimples within the rim were observed indicating local ductile events in the shell. Dislocation emission and annihilation at grain boundaries and twinning at crack tip were the main deformation mechanisms taking place within the fine-grained matrix as revealed by in-situ transmission electron microscopy. Estimation of the stress from loop's curvature and dislocation pile-up indicates that dislocation emission from grain boundaries and grain boundary overcoming largely contributes to the flow stress. - Highlights: • Bulk multi-modal Ni was processed by SPS from a powder blend. • Ultrafine-grained matrix or rim observed around spherical microcrystalline entities • Yield strength (470 MPa) and ductility (2.8% plastic strain) were measured. • Debonding was found at the matrix/microcrystalline entity interfaces. • In-situ TEM showed twinning, dislocation emission and annihilation at grain boundaries.

  10. GRADIENT INDEX SPHERES BY THE SEQUENTIAL ACCRETION OF GLASS POWDERS

    SciTech Connect (OSTI)

    MARIANO VELEZ

    2008-06-15

    The Department of Energy is seeking a method for fabricating mm-scale spheres having a refractive index that varies smoothly and continuously from the center to its surface [1]. The fabrication procedure must allow the creation of a range of index profiles. The spheres are to be optically transparent and have a refractive index differential greater than 0.2. The sphere materials can be either organic or inorganic and the fabrication technique must be capable of scaling to low cost production. Mo-Sci Corporation proposed to develop optical quality gradient refractive index (GRIN) glass spheres of millimeter scale (1 to 2 mm diameter) by the sequential accretion and consolidation of glass powders. Other techniques were also tested to make GRIN spheres as the powder-accretion method produced non-concentric layers and poor optical quality glass spheres. Potential ways to make the GRIN spheres were (1) by "coating" glass spheres (1 to 2 mm diameter) with molten glass in a two step process; and (2) by coating glass spheres with polymer layers.

  11. Double helix boron-10 powder thermal neutron detector

    DOE Patents [OSTI]

    Wang, Zhehui; Morris, Christopher L.; Bacon, Jeffrey D.

    2015-06-02

    A double-helix Boron-10 powder detector having intrinsic thermal neutron detection efficiency comparable to 36'' long, 2-in diameter, 2-bar Helium-3 detectors, and which can be used to replace such detectors for use in portal monitoring, is described. An embodiment of the detector includes a metallic plate coated with Boron-10 powder for generating alpha and Lithium-7 particles responsive to neutrons impinging thereon supported by insulators affixed to at least two opposing edges; a grounded first wire wound in a helical manner around two opposing insulators; and a second wire having a smaller diameter than that of the first wire, wound in a helical manner around the same insulators and spaced apart from the first wire, the second wire being positively biased. A gas, disposed within a gas-tight container enclosing the plate, insulators and wires, and capable of stopping alpha and Lithium-7 particles and generating electrons produces a signal on the second wire which is detected and subsequently related to the number of neutrons impinging on the plate.

  12. Developments in Die Pressing Strategies for Low-Cost Titanium Powders

    SciTech Connect (OSTI)

    Hovanski, Yuri; Weil, K. Scott; Lavender, Curt A.

    2009-05-01

    Recent developments in the production of low-cost titanium powders have rejuvenated interest in manufacturing titanium powder metallurgy components by direct press and sinter techniques. However excessive friction typically observed during titanium powder pressing operations leads to numerous problems ranging from non-homogeneous green densities of the compacted powder to excessive part ejection forces and reduced die life due to wear and galling. An instrumented double-acting die press was developed to both investigate the mechanics of titanium powder pressing (particularly for the new low-cost powder morphologies) and to screen potential lubricants that could reduce frictional effects. As will be discussed, the instrument was used to determine friction coefficients and to evaluate a number of candidate lubricants. These results were then used to optimize the lubricant system to reduce die-wall stresses and improve part density uniformity.

  13. Strain and particle size of palladium powders by time-of-flight neutron diffraction

    SciTech Connect (OSTI)

    Lawson, A.C.; Conant, J.W.; Talcott, C.L.; David, M.A.; Vaninetti, J.; Goldstone, J.A.; Williams, A.; Von Dreele, R.B.; Roof, R.B.; Hitterman, R.L.; Richardson, J.W. Jr.; Faber, J. Jr.

    1989-01-01

    We have determined the strain and particle size for several samples of palladium powder by time-of-flight neutron powder diffraction on two different diffractometers and by x-ray powder diffraction. The results are compared and found to be in fair agreement. The time-of-flight method gives good enough precision to reveal deficiencies in the simple models used for strain and particle size line broadening. 6 refs., 4 figs., 2 tabs.

  14. Method of preparing a powdered, electrically insulative separator for use in an electrochemical cell

    DOE Patents [OSTI]

    Cooper, Tom O. (Naperville, IL); Miller, William E. (Naperville, IL)

    1978-01-01

    A secondary electrochemical cell includes electrodes separated by a layer of electrically insulative powder. The powder includes refractory materials selected from the oxides and nitrides of metals and metaloids. The powdered refractory material, blended with electrolyte particles, is compacted as layers onto an electrode to form an integral electrode structure and assembled into the cell. The assembled cell is heated to its operating temperature leaving porous layers of electrically insulative, refractory particles, containing molten electrolyte between the electrodes.

  15. Metal oxide superconducting powder comprised of flake-like single crystal particles

    DOE Patents [OSTI]

    Capone, Donald W.; Dusek, Joseph

    1994-01-01

    Powder of a ceramic superconducting material is synthesized such that each particle of the powder is a single crystal having a flake-like, nonsymmetric morphology such that the c-axis is aligned parallel to the short dimension of the flake. Nonflake powder is synthesized by the normal methods and is pressed into pellets or other shapes and fired for excessive times to produce a coarse grained structure. The fired products are then crushed and ground producing the flake-like powder particles which exhibit superconducting characteristics when aligned with the crystal lattice.

  16. Metal oxide superconducting powder comprised of flake-like single crystal particles

    DOE Patents [OSTI]

    Capone, D.W.; Dusek, J.

    1994-10-18

    Powder of a ceramic superconducting material is synthesized such that each particle of the powder is a single crystal having a flake-like, nonsymmetric morphology such that the c-axis is aligned parallel to the short dimension of the flake. Nonflake powder is synthesized by the normal methods and is pressed into pellets or other shapes and fired for excessive times to produce a coarse grained structure. The fired products are then crushed and ground producing the flake-like powder particles which exhibit superconducting characteristics when aligned with the crystal lattice. 3 figs.

  17. Fabrication of Al{sub 2}O{sub 3}-20 vol.% Al nanocomposite powders using high energy milling and their sinterability

    SciTech Connect (OSTI)

    Zawrah, M.F.; Abdel-kader, H.; Elbaly, N.E.

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Al{sub 2}O{sub 3}/Al nanocomposite powders were prepared via high energy ball milling. After 20 h milling, the size of Al{sub 2}O{sub 3}-20 vol.% Al nanocomposite particles was in the range of 23-29 nm. A uniform distribution of nanosized Al reinforcement throughout the Al{sub 2}O{sub 3} matrix, coating the particles was successfully obtained. Black-Right-Pointing-Pointer There was no any sign of phase changes during the milling. A competition between the cold welding mechanism and the fracturing mechanism were found during milling and finally the above two mechanisms reached an equilibrium. Black-Right-Pointing-Pointer The highest value of relative density was obtained for the sintered bodies at 1500 Degree-Sign C. Black-Right-Pointing-Pointer The harness of the sintered composite was decreased while the fracture toughness was improved after addition Al into alumina. -- Abstract: In this study, alumina-based matrix nanocomposite powders reinforced with Al particles were fabricated and investigated. The sinterability of the prepared nanocomposite powder at different firing temperature was also conducted. Their mechanical properties in terms of hardness and toughness were tested. Alumina and aluminum powder mixtures were milled in a planetary ball mill for various times up to 30 h in order to produce Al{sub 2}O{sub 3}-20% Al nanocomposite. The phase composition, morphological and microstructural changes during mechanical milling of the nanocomposite particles were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscope (SEM) techniques, respectively. The crystallite size and internal strain were evaluated by XRD patterns using Scherrer methods. A uniform distribution of the Al reinforcement in the Al{sub 2}O{sub 3} matrix was successfully obtained after milling the powders. The results revealed that there was no any sign of phase changes during the milling. The crystal size decreased with the prolongation of milling times, while the internal strain increased. A simple model is presented to illustrate the mechanical alloying of a ductile-brittle component system. A competition between the cold welding mechanism and the fracturing mechanism were found during powder milling and finally the above two mechanisms reached an equilibrium. The maximum relative density was obtained at 1500 Degree-Sign C. The harness of the sintered composite was decreased while the fracture toughness was improved after addition Al into alumina.

  18. Palynostratigraphy of the Erkovtsy field of brown coal (the Zeya-Bureya sedimentary basin)

    SciTech Connect (OSTI)

    Kezina, T.V.; Litvinenko, N.D.

    2007-08-15

    The Erkovtsy brown coal field in the northwestern Zeya-Bureya sedimentary basin (129-130{sup o}E, 46-47{sup o}N) is structurally confined to southern flank of the Mesozoic-Cenozoic Belogor'e depression. The verified stratigraphic scheme of the coalfield sedimentary sequence is substantiated by palynological data on core samples from 18 boreholes sampled in the course of detailed prospecting and by paleobotanical analysis of sections in the Yuzhnyi sector of the coalfield (data of 1998 by M.A. Akhmetiev and S.P. Manchester). Sections of the Erkovtsy, Arkhara-Boguchan, and Raichikha brown-coal mines are correlated. Stratigraphic subdivisions distinguished in the studied sedimentary succession are the middle and upper Tsagayan subformations (the latter incorporating the Kivda Beds), Raichikha, Mukhino, Buzuli, and Sazanka formations.

  19. STATE OF CALIFORNIA - NATURAL RESOURCES AGENCY EDMUND G. BROWN JR., Governor

    Broader source: Energy.gov (indexed) [DOE]

    NATURAL RESOURCES AGENCY EDMUND G. BROWN JR., Governor CALIFORNIA ENERGY COMMISSION 1516 NINTH STREET SACRAMENTO, CA 95814-5512 WWIN.energy.ca.gov March 28, 2012 Lamont Jackson Office of Electricity Delivery and Energy Reliability Mail Code: OE-20 U.S. Department of Energy 1000 Independence Avenue SW Washington, DC 20585 Lamont.Jackson@hg.doe.gov Dear Mr. Jackson: The California Energy Commission staff thanks you for the opportunity to provide comments on DOE's Request for Information (RFI) on

  20. Methane, carbon monoxide, and ammonia in brown dwarfs and self-luminous giant planets

    SciTech Connect (OSTI)

    Zahnle, Kevin J.; Marley, Mark S. E-mail: Mark.S.Marley@NASA.gov

    2014-12-10

    We address disequilibrium abundances of some simple molecules in the atmospheres of solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics-based one-dimensional atmospheric chemistry model. Our approach is to use the full kinetics model to survey the parameter space with effective temperatures between 500 K and 1100 K. In all of these worlds, equilibrium chemistry favors CH{sub 4} over CO in the parts of the atmosphere that can be seen from Earth, but in most disequilibrium favors CO. The small surface gravity of a planet strongly discriminates against CH{sub 4} when compared to an otherwise comparable brown dwarf. If vertical mixing is like Jupiter's, the transition from methane to CO occurs at 500 K in a planet. Sluggish vertical mixing can raise this to 600 K, but clouds or more vigorous vertical mixing could lower this to 400 K. The comparable thresholds in brown dwarfs are 1100 ± 100 K. Ammonia is also sensitive to gravity, but, unlike CH{sub 4}/CO, the NH{sub 3}/N{sub 2} ratio is insensitive to mixing, which makes NH{sub 3} a potential proxy for gravity. HCN may become interesting in high-gravity brown dwarfs with very strong vertical mixing. Detailed analysis of the CO-CH{sub 4} reaction network reveals that the bottleneck to CO hydrogenation goes through methanol, in partial agreement with previous work. Simple, easy to use quenching relations are derived by fitting to the complete chemistry of the full ensemble of models. These relations are valid for determining CO, CH{sub 4}, NH{sub 3}, HCN, and CO{sub 2} abundances in the range of self-luminous worlds we have studied, but may not apply if atmospheres are strongly heated at high altitudes by processes not considered here (e.g., wave breaking).

  1. Dr. Benjamin L. Brown | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Benjamin L. Brown Deputy Director for Science Programs Deputy Director Home Mission & Functions Deputy Director Biography Organization Staff Presentations & Testimony Federal Advisory Committees Committees of Visitors Contact Information Deputy Director for Science Programs U.S. Department of Energy SC-2/Forrestal Building 1000 Independence Ave., SW Washington, DC 20585 P: (202) 586-5430 F: (202) 586-4120 E: Email Us U.S. Department of Energy SC-2/Germantown Building 1000 Independence

  2. From Meredith Brown <racer@lanl.gov> Subject: Blue Alert- Excavation Permits and Surveys

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    101122 -0700 From Meredith Brown <racer@lanl.gov> Subject: Blue Alert- Excavation Permits and Surveys Title: Blue Alert-Underground Cables Damaged during Excavation Work Identifier 2000-LA-LANL-ESH7-0001 Date 01/07/00 LESSONS LEARNED- Utility survey maps should be included with excavation permit paperwork to ensure that heavy equipment operators are aware of the exact areas included in the survey. Duplicate or triplicate excavation permit forms that generate exact copies should also be

  3. From Meredith Brown <racer@lanl.gov> Subject: Blue Alert- Unregistered Rad Sources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    05 Jan 2000 092137 -0700 From Meredith Brown <racer@lanl.gov> Subject: Blue Alert- Unregistered Rad Sources Title: Blue Alert- Unregistered Rad Sources Identifier 2000-KO-SNL-0001 Date January 5, 2000 Summary- 1. All rad sources, whether they are accountable or non-accountable, must be controlled as radioactive material in accordance with the requirements of SNL Radiation Protection Procedures Manual (MN471016), Chapter 9, "Radioactive Source Control." Failure to account for and

  4. From: Meredith Brown <racer@lanl.gov> Subject: Green Alert: Chemically Eliminate Asbestos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fri, 09 Jan 1998 16:52:55 -0800 From: Meredith Brown <racer@lanl.gov> Subject: Green Alert: Chemically Eliminate Asbestos This Project Hanford Lessons Learned Bulletin has potential for saving many thousands of dollars across the DOE complex. Few buildings at Hanford have the type of fireproofing discussed in this lessons learned so the actual cost saving potential at Hanford is minimal. It is forwarded to other DOE sites that may have buildings with sprayed on fireproofing. Please pass

  5. From: Meredith Brown <racer@lanl.gov> Subject: Green Alert: VPP Program Saves Lives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    24 Feb 1998 09:44:53 -0700 From: Meredith Brown <racer@lanl.gov> Subject: Green Alert: VPP Program Saves Lives Title: GREEN - VPP Program Saves Lives Identifier: INEEL Lessons Learned #98002 Date: January 8, 1998 Lessons Learned: The proactive safety practices and actively caring attitudes that are a part of DOE's VPP Program are designed to extend beyond the workplace into employees' personal lives. The positive behavioral changes can save lives. Summary of Success Story: An employee

  6. From: Meredith Brown <racer@lanl.gov> Subject: Yellow Alert: Heater Malfunction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mon, 05 Jan 1998 09:38:52 -0800 From: Meredith Brown <racer@lanl.gov> Subject: Yellow Alert: Heater Malfunction The attached Pacific Northwest National Laboratory Lessons Learned, Yellow/Caution, is an advisory about a recent incident involving new gas-fired unit heaters, and a resultant natural gas leak discovered during initial operations. If you have any questions or need further information, please contact Henry M. (Matt) Jones, PNNL, F&O Lessons Learned Coordinator, (509) 376-

  7. Preparation of lead-zirconium-titanium film and powder by electrodeposition

    DOE Patents [OSTI]

    Bhattacharya, Raghu N. (Littleton, CO); Ginley, David S. (Evergreen, CO)

    1995-01-01

    A process for the preparation of lead-zirconium-titanium (PZT) film and powder compositions. The process comprises the steps of providing an electrodeposition bath, providing soluble salts of lead, zirconium and titanium metals to this bath, electrically energizing the bath to thereby direct ions of each respective metal to a substrate electrode and cause formation of metallic particles as a recoverable film of PZT powder on the electrode, and also recovering the resultant film as a powder. Recovery of the PZT powder can be accomplished by continually energizing the bath to thereby cause powder initially deposited on the substrate-electrode to drop therefrom into the bath from which it is subsequently removed. A second recovery alternative comprises energizing the bath for a period of time sufficient to cause PZT powder deposition on the substrate-electrode only, from which it is subsequently recovered. PZT film and powder so produced can be employed directly in electronic applications, or the film and powder can be subsequently oxidized as by an annealing process to thereby produce lead-zirconium-titanium oxide for use in electronic applications.

  8. Preparation of lead-zirconium-titanium film and powder by electrodeposition

    DOE Patents [OSTI]

    Bhattacharya, R.N.; Ginley, D.S.

    1995-10-31

    A process is disclosed for the preparation of lead-zirconium-titanium (PZT) film and powder compositions. The process comprises the steps of providing an electrodeposition bath, providing soluble salts of lead, zirconium and titanium metals to this bath, electrically energizing the bath to thereby direct ions of each respective metal to a substrate electrode and cause formation of metallic particles as a recoverable film of PZT powder on the electrode, and also recovering the resultant film as a powder. Recovery of the PZT powder can be accomplished by continually energizing the bath to thereby cause powder initially deposited on the substrate-electrode to drop therefrom into the bath from which it is subsequently removed. A second recovery alternative comprises energizing the bath for a period of time sufficient to cause PZT powder deposition on the substrate-electrode only, from which it is subsequently recovered. PZT film and powder so produced can be employed directly in electronic applications, or the film and powder can be subsequently oxidized as by an annealing process to thereby produce lead-zirconium-titanium oxide for use in electronic applications. 4 figs.

  9. Synthesis of multi-hierarchical structured yttria-stabilized zirconia powders and their enhanced thermophysical properties

    SciTech Connect (OSTI)

    Cao, Fengmei; Gao, Yanfeng; Chen, Hongfei; Liu, Xinling; Tang, Xiaoping; Luo, Hongjie

    2013-06-01

    Multi-hierarchical structured yttria-stabilized zirconia (YSZ) powders were successfully synthesized by a hydrothermal-calcination process. The morphology, crystallinity, and microstructure of the products were characterized by SEM, XRD, TEM, and BET. A possible formation mechanism of the unique structure formed during hydrothermal processing was also investigated. The measured thermophysical results indicated that the prepared YSZ powders had a low thermal conductivity (0.63–1.27 W m?¹ K?¹), good short-term high-temperature stability up to 1300 °C. The influence of the morphology and microstructure on their thermophysical properties was briefly discussed. The unique multi-hierarchical structure makes the prepared YSZ powders candidates for use in enhanced applications involving thermal barrier coatings. - Graphical abstract: There are many tiny pores and grain boundaries in the multi-hierarchical structured yttria-stabilized zirconia (YSZ) powders,which greatly decrease the thermal conductivities of the YSZ powders. - Highlights: • Multi-hierarchical structured YSZ powders were successfully prepared. • The prepared YSZ powders had a low thermal conductivity (0.63–1.27 W m?¹ K?¹). • Improved high-temperature stability had been achieved for the prepared YSZ powders. • The influence of the morphology on their thermophysical properties was explored.

  10. Causal Factors of Weld Porosity in Gas Tungsten Arc Welding of Powder Metallurgy Produced Titanium Alloys

    SciTech Connect (OSTI)

    Muth, Thomas R; Yamamoto, Yukinori; Frederick, David Alan; Contescu, Cristian I; Chen, Wei; Lim, Yong Chae; Peter, William H; Feng, Zhili

    2013-01-01

    ORNL undertook an investigation using gas tungsten arc (GTA) welding on consolidated powder metallurgy (PM) titanium (Ti) plate, to identify the causal factors behind observed porosity in fusion welding. Tramp element compounds of sodium and magnesium, residual from the metallothermic reduction of titanium chloride used to produce the titanium, were remnant in the starting powder and were identified as gas forming species. PM-titanium made from revert scrap where sodium and magnesium were absent, showed fusion weld porosity, although to a lesser degree. We show that porosity was attributable to hydrogen from adsorbed water on the surface of the powders prior to consolidation. The removal / minimization of both adsorbed water on the surface of titanium powder and the residues from the reduction process prior to consolidation of titanium powders, are critical to achieve equivalent fusion welding success similar to that seen in wrought titanium produced via the Kroll process.

  11. Process and apparatus for obtaining silicon from fluosilicic acid

    DOE Patents [OSTI]

    Sancier, Kenneth M. (Menlo Park, CA)

    1985-07-16

    Process for producing low cost, high purity solar grade Si wherein a reduction reaction, preferably the reduction of SiF.sub.4, by an alkali metal (liquid Na preferred) is carried out essentialy continuously by injecting of reactants in substantially stoichiometric proportions into a reaction chamber having a controlled temperature thereby to form a mist or dispersion of reactants. The reactants being supplied at such a rate and temperature that the reaction takes place far enough away from the entry region to avoid plugging of reactants at the entry region, the reaction is completed and whereby essentially all reaction product solidifies and forms a free flowing powder before reaction product hits a reaction chamber wall. Thus, the reaction product does not adhere to the reaction chamber wall or pick up impurities therefrom. Separation of reaction products is easily carried out by either a leach or melt separation process.

  12. Rapid formation of phase-clean 110 K (Bi-2223) powders derived via freeze-drying process

    DOE Patents [OSTI]

    Balachandran, U.

    1996-06-04

    A process for the preparation of amorphous precursor powders for Pb-doped Bi{sub 2}Sr{sub 2} Ca{sub 2}Cu{sub 3}O{sub x} (2223) includes a freeze-drying process incorporating a splat-freezing step. The process generally includes splat freezing a nitrate solution of Bi, Pb, Sr, Ca, and Cu to form flakes of the solution without any phase separation; grinding the frozen flakes to form a powder; freeze-drying the frozen powder; heating the dried powder to form a dry green precursor powders; denitrating the green-powders; heating the denitrated powders to form phase-clean Bi-2223 powders. The grain boundaries of the 2223 grains appear to be clean, leading to good intergrain contact between 2223 grains. 11 figs.

  13. Rapid formation of phase-clean 110 K (Bi-2223) powders derived via freeze-drying process

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL)

    1996-01-01

    A process for the preparation of amorphous precursor powders for Pb-doped Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x (2223) includes a freeze-drying process incorporating a splat-freezing step. The process generally includes splat freezing a nitrate solution of Bi, Pb, Sr, Ca, and Cu to form flakes of the solution without any phase separation; grinding the frozen flakes to form a powder; freeze-drying the frozen powder; heating the dried powder to form a dry green precursor powders; denitrating the green-powders; heating the denitrated powders to form phase-clean Bi-2223 powders. The grain boundaries of the 2223 grains appear to be clean, leading to good intergrain contact between 2223 grains.

  14. Preparation of cuxinygazsen precursor films and powders by electroless deposition

    DOE Patents [OSTI]

    Bhattacharya, Raghu N.; Batchelor, Wendi Kay; Wiesner, Holm; Ramanathan, Kannan; Noufi, Rommel

    1999-01-01

    A method for electroless deposition of Cu.sub.x In.sub.y Ga.sub.z Se.sub.n (x=0-2, y=0-2, z=0-2, n=0-3) precursor films and powders onto a metallic substrate comprising: preparing an aqueous bath solution of compounds selected from the group consisting of: I) a copper compound, a selenium compound, an indium compound and gallium compound; II) a copper compound, a selenium compound and an indium compound; III) a selenium compound, and indium compound and a gallium compound; IV) a selenium compound and a indium compound; and V) a copper compound and selenium compound; each compound being present in sufficient quantity to react with each other to produce Cu.sub.x In.sub.y Ga.sub.z Se.sub.n (x=0-2, y=0-2, z=0-2, n=0-3); adjusting the pH of the aqueous bath solution to an acidic value by the addition of a dilute acid; and initiating an electroless reaction with an oxidizing counterelectrode for a sufficient time to cause a deposit of Cu.sub.x In.sub.y Ga.sub.z Se.sub.n (x=0-2, y=0-2, z=0-2, n=0-3) from the aqueous bath solution onto a metallic substrate.

  15. Method of making highly sinterable lanthanum chromite powder

    DOE Patents [OSTI]

    Richards, V.L.; Singhal, S.C.

    1992-09-01

    A highly sinterable powder consisting essentially of LaCrO[sub 3], containing from 5 weight % to 20 weight % of a chromite of dopant Ca, Sr, Co, Ba, or Mg and a coating of a chromate of dopant Ca, Sr, Co, Ba, or Mg; is made by (1) forming a solution of La, Cr, and dopant; (2) heating their solutions; (3) forming a combined solution having a desired ratio of La, Cr, and dopant and heating to reduce solvent; (4) forming a foamed mass under vacuum; (5) burning off organic components and forming a charred material; (6) grinding the charred material; (7) heating the char at from 590 C to 950 C in inert gas containing up to 50,000 ppm O[sub 2] to provide high specific surface area particles; (8) adding that material to a mixture of a nitrate of Cr and dopant to form a slurry; (9) grinding the particles in the slurry; (10) freeze or spray drying the slurry to provide a coating of nitrates on the particles; and (11) heating the coated particles to convert the nitrate coating to a chromate coating and provide a highly sinterable material having a high specific surface area of over 7 m[sup 2]/g. 2 figs.

  16. Method of making highly sinterable lanthanum chromite powder

    DOE Patents [OSTI]

    Richards, Von L. (Murrysville, PA); Singhal, Subhash C. (Murrysville, PA)

    1992-01-01

    A highly sinterable powder consisting essentially of LaCrO.sub.3, containing from 5 weight % to 20 weight % of a chromite of dopant Ca, Sr, Co, Ba, or Mg and a coating of a chromate of dopant Ca, Sr, Co, Ba, or Mg; is made by (1) forming a solution of La, Cr, and dopant; (2) heating their solutions; (3) forming a combined solution having a desired ratio of La, Cr, and dopant and heating to reduce solvent; (4) forming a foamed mass under vacuum; (5) burning off organic components and forming a charred material; (6) grinding the charred material; (7) heating the char at from 590.degree. C. to 950 C. in inert gas containing up to 50,000 ppm O.sub.2 to provide high specific surface area particles; (8) adding that material to a mixture of a nitrate of Cr and dopant to form a slurry; (9) grinding the particles in the slurry; (10) freeze or spray drying the slurry to provide a coating of nitrates on the particles; and (11) heating the coated particles to convert the nitrate coating to a chromate coating and provide a highly sinterable material having a high specific surface area of over 7 m.sup.2 /g.

  17. Numerical simulation of plasma heating of a composite powder particle

    SciTech Connect (OSTI)

    Demetriou, M.D.; Lavine, A.S.; Ghoniem, N.M.

    1999-07-01

    The use of fine composite powder particles (composed of a ceramic core and a metallic coating) in plasma spraying processes is desirable in developing thin film coatings that possess high abrasion as well as high fracture resistance. Quantitative knowledge of the thermal behavior of a composite particle in a plasma beam is essential in optimizing the process variables to achieve uniform melting of the coating material. In this work, a numerical model is developed to analyze the in-flight thermal behavior of a spherically symmetric WC-Co composite particle travelling in an argon arc-jet DC plasma under strongly unsteady plasma conditions. The model gives quantitative as well as qualitative information about the thermal response of the heated particle. The important features that are addressed are the temperature response of the particle; the history of the location of the melting and vaporization fronts; and the physical state of the particle at the end of its flight. For the conditions investigated, it was determined that the internal conduction resistance is negligible as compared to the net external resistance. However, the presence of the ceramic base was found to affect the transient heating process since its content in the particle composition determines the time constant of the process. Another interesting observation is that proper selection of the particle injection speed and injection location can be effective means for optimizing the heating process and achieving uniform melting of the coating material.

  18. Azine bridged silver coordination polymers: Powder X-ray diffraction route to crystal structure determination of silver benzotriazole

    SciTech Connect (OSTI)

    Rajeswaran, Manju . E-mail: manju.rajeswaran@kodak.com; Blanton, Thomas N.; Giesen, David J.; Whitcomb, David R.; Zumbulyadis, Nicholas; Antalek, Brian J.; Neumann, Marcus M.; Misture, Scott T.

    2006-04-15

    In continuation of our interest in solid-state structures of silver complexes of photographic importance, the structure for silver benzotriazole (AgBZT), has now been obtained. The preferred method for solving crystal structures is via single-crystal X-ray diffraction (XRD). However, for some materials, growing single crystals of appropriate size and quality is often difficult or even impossible. AgBZT is an example of such a silver complex with poor solubility. The usual routes to preparing single crystals using recrystallization from a cooperating solvent resulted in polycrystalline powder samples. We propose a crystal structure for AgBZT, solved from synchrotron X-ray powder diffraction data, using a direct-space Monte Carlo simulated annealing approach. AgBZT crystals are monoclinic (P2{sub 1} /c), with unit cell dimensions, a=14.8052(3) A, b=3.7498(4) A, c=12.3495(12) A, and {beta}=114.200(6){sup o}. The AgBZT complex is constructed from all three of the Benzotriazole (BZT) nitrogens bonding to a separate silver atom. As a consequence of this bonding mode, the structure is a highly cross-linked, coordination polymer.

  19. Speakers: Adam Sieminski, Deutsche Bank Stephen P. A. Brown, Resources for the Future

    Gasoline and Diesel Fuel Update (EIA)

    5: "Energy and the Economy" Speakers: Adam Sieminski, Deutsche Bank Stephen P. A. Brown, Resources for the Future Donald L. Paul, University of Southern California Energy Institute David Sandalow, DOE Christof Rühl, Group Chief Economist, BP [Note: Recorders did not pick up introduction of panel (see biographies for details on the panelists) or introduction of session.] Adam: Microphone. So, we've lost a little bit of time because of all of the sessions running a bit over, but here is

  20. Trenton strata in western Illinois Basin, Brown and Schuyler Counties, Illinois

    SciTech Connect (OSTI)

    Pochel, R.M.

    1984-12-01

    Trenton strata in the western Illinois basin are very good prospects for oil exploration. Much drilling has been done in the area but, as yet, no producing wells have been completed. Oil stains and some tars have been found in some samples from most wells. The Trenton in the area of Brown and Schuyler Counties is a fine-grained limestone that underlies the Maquoketa Shale at an average depth of 800 ft (244 m). Because of its position near the edge of the Illinois basin, the stratigraphy varies considerably and inconsistencies are present in most samples viewed.

  1. From Meredith Brown racer@lanl.gov Subject: Yellow Alert- Supplied Air Fitting Failure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 Jan 2000 130859 -0700 From Meredith Brown racer@lanl.gov Subject: Yellow Alert- Supplied Air Fitting Failure Title: Yellow Alert- Mechanical Failure of Supplied Air Fitting Identifier 2000-OH-WVDP-001 Date 1/12/00 Summary- The user is the last barrier to confirm the safety and effectiveness of personal protective equipment. In addition to performing a pre-use inspection, workers are instructed to exit the work area if they notice anything unusual or wrong with their PPE. Discussion- On

  2. From: Meredith Brown <racer@lanl.gov> Subject: Yellow Alert: Fall Results in Injury

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tue, 16 Jun 1998 13:57:16 -0500 From: Meredith Brown <racer@lanl.gov> Subject: Yellow Alert: Fall Results in Injury Title: Fall From Ladder Results in Fractured Vertebra Identifier: LLNL-1998-002 Date: January 5, 1998 Lesson Learned Statement: Work at elevated levels needs to be thoroughly evaluated. Discussion of Activities: A subcontractor employee was soldering a pipe while standing 2/3 of the way up a portable ten foot ladder when he lost his balance and fell six feet to the floor

  3. From: Meredith Brown <racer@lanl.gov> Subject: Yellow Alert: Small Bench Top Fire

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fri, 12 Jun 1998 17:03:23 -0500 From: Meredith Brown <racer@lanl.gov> Subject: Yellow Alert: Small Bench Top Fire Title: Bench Top Fire Involving Use of Alcohol and Burner Identifier: LLNL-1998-009 Date: 1/12/98 Lesson Learned Statement: Work requiring the use of alcohol, or other flammable liquids, and open flames should be performed only when the appropriate safeguards and constraints are in place. Discussion of Activities: A fire occurred in a laboratory facility that resulted from

  4. I. V. Khalzov, B. P. Brown, C. M. Cooper, D. B. Weisberg, and C. B. Forest

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimized boundary driven flows for dynamos in a sphere I. V. Khalzov, B. P. Brown, C. M. Cooper, D. B. Weisberg, and C. B. Forest Citation: Phys. Plasmas 19, 112106 (2012); doi: 10.1063/1.4764048 View online: http://dx.doi.org/10.1063/1.4764048 View Table of Contents: http://pop.aip.org/resource/1/PHPAEN/v19/i11 Published by the American Institute of Physics. Additional information on Phys. Plasmas Journal Homepage: http://pop.aip.org/ Journal Information:

  5. I. V. Khalzov, B. P. Brown, F. Ebrahimi, D. D. Schnack, and C. B. Forest

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulation of laminar plasma dynamos in a cylindrical von Kármán flow I. V. Khalzov, B. P. Brown, F. Ebrahimi, D. D. Schnack, and C. B. Forest Citation: Phys. Plasmas 18, 032110 (2011); doi: 10.1063/1.3559472 View online: http://dx.doi.org/10.1063/1.3559472 View Table of Contents: http://pop.aip.org/resource/1/PHPAEN/v18/i3 Published by the American Institute of Physics. Additional information on Phys. Plasmas Journal Homepage: http://pop.aip.org/ Journal Information:

  6. I. V. Khalzov, B. P. Brown, N. Katz, and C. B. Forest

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Parker instability in a rotating plasma screw pinch I. V. Khalzov, B. P. Brown, N. Katz, and C. B. Forest Citation: Phys. Plasmas 19, 022107 (2012); doi: 10.1063/1.3684240 View online: http://dx.doi.org/10.1063/1.3684240 View Table of Contents: http://pop.aip.org/resource/1/PHPAEN/v19/i2 Published by the American Institute of Physics. Additional information on Phys. Plasmas Journal Homepage: http://pop.aip.org/ Journal Information: http://pop.aip.org/about/about_the_journal Top downloads:

  7. STATE OF CALIFORNIA - THE NATURAL RESOURCES AGENCY EDMUND G. BROWN, JR., Governor

    Energy Savers [EERE]

    THE NATURAL RESOURCES AGENCY EDMUND G. BROWN, JR., Governor CALIFORNIA ENERGY COMMISSION 1516 Ninth Street, MS 14 Sacramento, California 95814 Main website: www.energy.ca.gov January 12, 2011 United States Department of Energy (DOE) Via e-mail: expartecommunications@hq.doe.gov RE: Ex parte communication of the California Energy Commission Docket No. EERE-2008-BT-STD-0005 To Whom It May Concern, On January 6, 2011, Mike Leaon, Harinder Singh, Ken Rider, and Dennis Beck of the California Energy

  8. CHARACTERIZATION OF THE NEARBY L/T BINARY BROWN DWARF WISE J104915.57-531906.1 AT 2 pc FROM THE SUN

    SciTech Connect (OSTI)

    Kniazev, A. Y.; Vaisanen, P.; Potter, S. B.; Crawford, S.; Gulbis, A. A. S.; Muzic, K.; Mehner, A.; Boffin, H. M. J.; Melo, C.; Ivanov, V. D.; Girard, J.; Mawet, D.; Schmidtobreick, L.; Kurtev, R.; Borissova, J.; Huelamo, N.; Minniti, D.; Ishibashi, K.; Beletsky, Y.; Buckley, D. A. H.; and others

    2013-06-20

    WISE J104915.57-531906.1 is a L/T brown dwarf binary located 2 pc from the Sun. The pair contains the closest known brown dwarfs and is the third closest known system, stellar or sub-stellar. We report comprehensive follow-up observations of this newly uncovered system. We have determined the spectral types of both components (L8 {+-} 1, for the primary, agreeing with the discovery paper; T1.5 {+-} 2 for the secondary, which was lacking spectroscopic type determination in the discovery paper) and, for the first time, their radial velocities (V{sub rad} {approx} 23.1, 19.5 km s{sup -1}) using optical spectra obtained at the Southern African Large Telescope and other facilities located at the South African Astronomical Observatory (SAAO). The relative radial velocity of the two components is smaller than the range of orbital velocities for theoretically predicted masses, implying that they form a gravitationally bound system. We report resolved near-infrared JHK{sub S} photometry from the Infrared Survey Facility telescope at the SAAO which yields colors consistent with the spectroscopically derived spectral types. The available kinematic and photometric information excludes the possibility that the object belongs to any of the known nearby young moving groups or associations. Simultaneous optical polarimetry observations taken at the SAAO 1.9 m give a non-detection with an upper limit of 0.07%. For the given spectral types and absolute magnitudes, 1 Gyr theoretical models predict masses of 0.04-0.05 M{sub Sun} for the primary, and 0.03-0.05 M{sub Sun} for the secondary.

  9. Brown - leaves

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Opportunities Low Income Energy Efficiency Workgroup November 6, 2014 Sarah F. Moore, Residential Lead Courtney Dale, Residential Weatherization B O N N E V I L L E P O W...

  10. Brown - leaves

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oct 14 th * Award decision by Nov 6 th * Presentation of New Program Thurs, Nov 13 th . * Utility opt-in Nov 7 - Dec 5 th * New program launch - April 1, 2015 12 B O N N E V I L L...

  11. DISCOVERY OF A ?250 K BROWN DWARF AT 2 pc FROM THE SUN

    SciTech Connect (OSTI)

    Luhman, K. L.

    2014-05-10

    Through a previous analysis of multi-epoch astrometry from the Wide-field Infrared Survey Explorer (WISE), I identified WISE J085510.83–071442.5 as a new high proper motion object. By combining astrometry from WISE and the Spitzer Space Telescope, I have measured a proper motion of 8.1 ± 0.1'' yr{sup –1} and a parallax of 0.454 ± 0.045'' (2.20{sub ?0.20}{sup +0.24} pc) for WISE J085510.83–071442.5, giving it the third highest proper motion and the fourth largest parallax of any known star or brown dwarf. It is also the coldest known brown dwarf based on its absolute magnitude at 4.5 ?m and its color in [3.6]-[4.5]. By comparing M {sub 4.5} with the values predicted by theoretical evolutionary models, I estimate an effective temperature of 225-260 K and a mass of 3-10 M {sub Jup} for the age range of 1-10 Gyr that encompasses most nearby stars.

  12. Relation between combustion heat and chemical wood composition during white and brown rot

    SciTech Connect (OSTI)

    Dobry, J.; Dziurzynski, A.; Rypacek, V.

    1986-01-01

    Samples of beech and spruce wood were incubated with the white rot fungi Pleurotus ostreatus and Lentinus tigrinus and the brown rot fungi Fomitopsis pinicola and Serpula lacrymans (S. lacrimans) for four months. Decomposition (expressed as percent weight loss) and amounts of holocellulose, lignin, humic acids (HU), hymatomelanic acids (HY) and fulvo acids (FU) were determined and expressed in weight percent. Combustion heat of holocellulose and lignin was determined in healthy wood and in specimens where decomposition was greater than 50%. During white rot decomposition, combustion heat was unchanged even at high decomposition and the relative amounts of holocellulose and lignin remained the same. Total amounts of HU, HY and FU increased during the initial stages and stabilized at 20%. The content of HU plus HY was negligible even at the highest degree of decomposition. During brown rot decomposition, combustion heat was unchanged only in the initial stages, it increased continously with increasing rot. Lignin content was unchanged in the initial stages and increased after 30% weight loss. Total amounts of HU, HY and FU increased continuously, reaching higher values than in white rot decomposition; there were differences between the two species. Biosynthesis of HU plus HY began when weight loss reached 30%; there were differences in absolute and relative amounts between species. 24 references.

  13. Isolation of laccase gene-specific sequences from white rot and brown rot fungi by PCR

    SciTech Connect (OSTI)

    D`Souza, T.M.; Boominathan, K.; Reddy, C.A.

    1996-10-01

    Degenerate primers corresponding to the consensus sequences of the copper-binding regions in the N-terminal domains of known basidiomycete laccases were used to isolate laccase gene-specific sequences from strains representing nine genera of wood rot fungi. All except three gave the expected PCR product of about 200 bp. Computer searches of the databases identified the sequences of each of the PCR product of about 200 bp. Computer searches of the databases identified the sequence of each of the PCR products analyzed as a laccase gene sequence, suggesting the specificity of the primers. PCR products of the white rot fungi Ganoderma lucidum, Phlebia brevispora, and Trametes versicolor showed 65 to 74% nucleotide sequence similarity to each other; the similarity in deduced amino acid sequences was 83 to 91%. The PCR products of Lentinula edodes and Lentinus tigrinus, on the other hand, showed relatively low nucleotide and amino acid similarities (58 to 64 and 62 to 81%, respectively); however, these similarities were still much higher than when compared with the corresponding regions in the laccases of the ascomycete fungi Aspergillus nidulans and Neurospora crassa. A few of the white rot fungi, as well as Gloeophyllum trabeum, a brown rot fungus, gave a 144-bp PCR fragment which had a nucleotide sequence similarity of 60 to 71%. Demonstration of laccase activity in G. trabeum and several other brown rot fungi was of particular interest because these organisms were not previously shown to produce laccases. 36 refs., 6 figs., 2 tabs.

  14. Combustion of Bulk 84% Fe/16% KCIO{sub 4} heat powder

    SciTech Connect (OSTI)

    Nissen, M.; Guidotti, R.A.; Berry, B.

    1996-05-01

    Fe/KClO{sub 4} pyrotechnic mixtures are used in thermal batteries to provide the heat necessary to bring the battery stack to operating temperatures of 550 to 600 C. This heat source is normally used as discs pressed from bulk powder. To evaluate the consequences associated with unexpected ignition of large amounts of heat powder, combustion of 84% Fe/16% KClO{sub 4} heat powders was conducted for various scenarios under controlled conditions and the response documented. Increasing amounts of heat powder--up to 8 lbs--were ignited in both unconfined and confined (sealed) containers in a remote area. The containers were thermocoupled and the resulting burning filmed with a standard video camera, high-speed (1,000 frames/s) film and video cameras, and an infrared video camera. A 20- minute video of the burning under the various conditions is presented.

  15. Spraying Powder Materials by the High-Enthalpy Laminar Plasma Flow

    SciTech Connect (OSTI)

    Khutsishvili, M.; Kikvadze, L.

    2008-03-19

    One of the most promising engineering solutions of the problem of spraying powder materials is the proposed method of plasma spraying by the laminar plasma jet. Laminar plasma flow is characterized by small jet angle divergence; the powder particles are penetrated and accelerated mainly in the axial direction. The molten powder particles are transported almost to the surface of a treated work-piece inside the laminar plasma flow in an atmosphere of the plasma-forming gas with the acceleration on the entire transfer area, which leads to an increase in the particles velocity, a decrease of their oxidability, an increase in the powder deposition efficiency, density, adhesion strength with the surface to be coated.

  16. Policy Flash 2013-24 Fee Determinations: Requirement to Obtain...

    Broader source: Energy.gov (indexed) [DOE]

    Requirement to Obtain Acquisition Executive's Input. Questions concerning this policy flash should be directed to Michael Righi of the Contract and Financial Assistance...

  17. An electroless approach to atomic layer deposition on noble metal powders.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: An electroless approach to atomic layer deposition on noble metal powders. Citation Details In-Document Search Title: An electroless approach to atomic layer deposition on noble metal powders. Abstract not provided. Authors: Cappillino, Patrick ; Robinson, David ; Sugar, Joshua Daniel ; El Gabaly Marquez, Farid ; Cai, Trevor ; Liu, Zhi ; Stickney, John Publication Date: 2014-03-01 OSTI Identifier: 1140790 Report Number(s): SAND2014-2265C 505441 DOE

  18. Atomic-Layer Deposition on Noble Metal Powders. (Conference) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Atomic-Layer Deposition on Noble Metal Powders. Citation Details In-Document Search Title: Atomic-Layer Deposition on Noble Metal Powders. Abstract not provided. Authors: Robinson, David ; Cappillino, Patrick. ; Salloum, Maher N. ; Sugar, Joshua Daniel ; El Gabaly Marquez, Farid ; Sheridan, Leah B. ; Jagannathan, Kaushik ; Benson, David M. ; Stickney, John L. Publication Date: 2014-10-01 OSTI Identifier: 1241747 Report Number(s): SAND2014-18364PE 537921 DOE Contract Number:

  19. Solid State Processing of New Low Cost Titanium Powders Enabling Affordable

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Components | Department of Energy Processing of New Low Cost Titanium Powders Enabling Affordable Automotive Components Solid State Processing of New Low Cost Titanium Powders Enabling Affordable Automotive Components Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon

  20. Moving to the Powder River Basin in search of the American dream

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2007-03-15

    As the Big Three American automakers cut jobs in Michigan, Wyoming's booming but isolated coal mining industry in the Powder River Basin is trying to lure some of these dissatisfied workers. DRM has attracted workers to the benefaction plant and P & H MinePro Services working on surface mining equipment has been successful, as have Peabody's Powder River coal subsidiary and Kiewitt's Buckshin mine. 2 photos.

  1. Preparation of powders suitable for conversion to useful .beta.-aluminas

    DOE Patents [OSTI]

    Morgan, Peter E. D. (Thousand Oaks, CA)

    1982-01-01

    A process for forming a precursor powder which, when suitably pressed and sintered forms highly pure, densified .beta.- or .beta."-alumina, comprising the steps of: (1) forming a suspension (or slurry) of Bayer-derived Al(OH).sub.3 in a water-miscible solvent; (2) adding an aqueous solution of a Mg compound, a Li compound, a Na compound or mixtures thereof to the Bayer-derived Al(OH).sub.3 suspension while agitating the mixture formed thereby, to produce a gel; (3) drying the gel at a temperature above the normal boiling point of water to produce a powder material; (4) lightly ball milling and sieving said powder material; and (5) heating the ball-milled and sieved powder material at a temperature of between 350.degree. to 900.degree. C. to form the .beta.- or .beta."-alumina precursor powder. The precursor powder, thus formed, may be subsequently isopressed at a high pressure and sintered at an elevated temperature to produce .beta.- or .beta."-alumina. BACKGROUND OF THE INVENTION

  2. Generator for gallium-68 and compositions obtained therefrom

    DOE Patents [OSTI]

    Neirinckx, Rudi D. (Medfield, MA); Davis, Michael A. (Westwood, MA)

    1981-01-01

    A generator for obtaining radioactive gallium-68 from germanium-68 bound in a resin containing unsubstituted phenolic hydroxyl groups. The germanium-68 is loaded into the resin from an aqueous solution of the germanium-68. A physiologically acceptable solution of gallium-68 having an activity of 0.1 to 50 millicuries per milliliter of gallium-68 solution is obtained. The solution is obtained from the bound germanium-68 which forms gallium-68 in situ by eluting the column with a hydrochloric acid solution to form an acidic solution of gallium-68. The acidic solution of gallium-68 can be neutralized.

  3. Terra-Gen Powers Coso Geothermal Facility Obtains Critical Federal...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Terra-Gen Powers Coso Geothermal Facility Obtains Critical Federal Permit to Increase Its...

  4. An important challenge in magnetic fusion research is to obtain...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control of edge transport barriers on Alcator C-Mod A crucial challenge in magnetic fusion is to obtain high energy confinement in a stationary plasma that is compatible with...

  5. Treatment of biomass to obtain a target chemical

    DOE Patents [OSTI]

    Dunson, Jr., James B. (Newark, DE); Tucker, III, Melvin P. (Lakewood, CO); Elander, Richard T. (Evergreen, CO); Hennessey, Susan Marie (Avondale, PA)

    2010-08-24

    Target chemicals were produced using biocatalysts that are able to ferment sugars derived from treated biomass. Sugars were obtained by pretreating biomass under conditions of high solids and low ammonia concentration, followed by saccharification.

  6. Common Approach to Obtaining Experimental Data for Developing Predictive

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx Absorber Models | Department of Energy Common Approach to Obtaining Experimental Data for Developing Predictive NOx Absorber Models Common Approach to Obtaining Experimental Data for Developing Predictive NOx Absorber Models 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_currier.pdf More Documents & Publications Pt-free, Perovskite-based Lean NOx Trap Catalysts Lean NOx Traps - Microstructural Studies of Real World and Model

  7. Effect of Cu addition on the martensitic transformation of powder metallurgy processed Ti–Ni alloys

    SciTech Connect (OSTI)

    Kim, Yeon-wook; Choi, Eunsoo

    2014-10-15

    Highlights: • M{sub s} of Ti{sub 50}Ni{sub 50} powders is 22 °C, while M{sub s} of SPS-sintered porous bulk increases up to 50 °C. • M{sub s} of Ti{sub 50}Ni{sub 40}Cu{sub 20} porous bulk is only 2 °C higher than that of the powders. • Recovered stain of porous TiNi and TiNiCu alloy is more than 1.5%. - Abstract: Ti{sub 50}Ni{sub 50} and Ti{sub 50}Ni{sub 30}Cu{sub 20} powders were prepared by gas atomization and their transformation behaviors were examined by means of differential scanning calorimetry and X-ray diffraction. One-step B2–B19’ transformation occurred in Ti{sub 50}Ni{sub 50} powders, while Ti{sub 50}Ni{sub 30}Cu{sub 20} powders showed B2–B19 transformation behavior. Porous bulks with 24% porosity were fabricated by spark plasma sintering. The martensitic transformation start temperature (50 °C) of Ti{sub 50}Ni{sub 50} porous bulk is much higher than that (22 °C) of the as-solidified powders. However, the martensitic transformation start temperature (35 °C) of Ti{sub 50}Ni{sub 30}Cu{sub 20} porous bulk is almost the same as that (33 °C) of the powders. When the specimens were compressed to the strain of 8% and then unloaded, the residual strains of Ti{sub 50}Ni{sub 50} and Ti{sub 50}Ni{sub 30}Cu{sub 20} alloy bulks were 3.95 and 3.7%, respectively. However, these residual strains were recovered up to 1.7% after heating by the shape memory phenomenon.

  8. Method development and validation for measuring the particle size distribution of pentaerythritol tetranitrate (PETN) powders.

    SciTech Connect (OSTI)

    Young, Sharissa Gay

    2005-09-01

    Currently, the critical particle properties of pentaerythritol tetranitrate (PETN) that influence deflagration-to-detonation time in exploding bridge wire detonators (EBW) are not known in sufficient detail to allow development of a predictive failure model. The specific surface area (SSA) of many PETN powders has been measured using both permeametry and gas absorption methods and has been found to have a critical effect on EBW detonator performance. The permeametry measure of SSA is a function of particle shape, packed bed pore geometry, and particle size distribution (PSD). Yet there is a general lack of agreement in PSD measurements between laboratories, raising concerns regarding collaboration and complicating efforts to understand changes in EBW performance related to powder properties. Benchmarking of data between laboratories that routinely perform detailed PSD characterization of powder samples and the determination of the most appropriate method to measure each PETN powder are necessary to discern correlations between performance and powder properties and to collaborate with partnering laboratories. To this end, a comparison was made of the PSD measured by three laboratories using their own standard procedures for light scattering instruments. Three PETN powder samples with different surface areas and particle morphologies were characterized. Differences in bulk PSD data generated by each laboratory were found to result from variations in sonication of the samples during preparation. The effect of this sonication was found to depend on particle morphology of the PETN samples, being deleterious to some PETN samples and advantageous for others in moderation. Discrepancies in the submicron-sized particle characterization data were related to an instrument-specific artifact particular to one laboratory. The type of carrier fluid used by each laboratory to suspend the PETN particles for the light scattering measurement had no consistent effect on the resulting PSD data. Finally, the SSA of the three powders was measured using both permeametry and gas absorption methods, enabling the PSD to be linked to the SSA for these PETN powders. Consistent characterization of other PETN powders can be performed using the appropriate sample-specific preparation method, so that future studies can accurately identify the effect of changes in the PSD on the SSA and ultimately model EBW performance.

  9. Enery Efficient Press and Sinter of Titanium Powder for Low-Cost Components in Vehicle Applications

    SciTech Connect (OSTI)

    Thomas Zwitter; Phillip Nash; Xiaoyan Xu; Chadwick Johnson

    2011-03-31

    This is the final technical report for the Department of Energy NETL project NT01931 Energy Efficient Press and Sinter of Titanium Powder for Low-Cost Components in Vehicle Applications. Titanium has been identified as one of the key materials with the required strength that can reduce the weight of automotive components and thereby reduce fuel consumption. Working with newly developed sources of titanium powder, Webster-Hoff will develop the processing technology to manufacture low cost vehicle components using the single press/single sinter techniques developed for iron based powder metallurgy today. Working with an automotive or truck manufacturer, Webster-Hoff will demonstrate the feasibility of manufacturing a press and sinter titanium component for a vehicle application. The project objective is two-fold, to develop the technology for manufacturing press and sinter titanium components, and to demonstrate the feasibility of producing a titanium component for a vehicle application. The lowest cost method for converting metal powder into a net shape part is the Powder Metallurgy Press and Sinter Process. The method involves compaction of the metal powder in a tool (usually a die and punches, upper and lower) at a high pressure (up to 60 TSI or 827 MPa) to form a green compact with the net shape of the final component. The powder in the green compact is held together by the compression bonds between the powder particles. The sinter process then converts the green compact to a metallurgically bonded net shape part through the process of solid state diffusion. The goal of this project is to expand the understanding and application of press and sinter technology to Titanium Powder applications, developing techniques to manufacture net shape Titanium components via the press and sinter process. In addition, working with a vehicle manufacturer, demonstrate the feasibility of producing a titanium component for a vehicle. This is not a research program, but rather a project to develop a process for press and sinter of net shape Titanium components. All of these project objectives have been successfully completed.

  10. Recyclability study on Inconel 718 and Ti-6Al-4V powders for use in electron beam melting

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nandwana, Peeyush; Peter, William H.; Lowe, Larry E.; Dehoff, Ryan R.; Medina, Francisco; Babu, Sudarsanam Suresh; Kirka, Michael M.

    2015-10-20

    In this study, powder bed based additive manufacturing technologies offer a big advantage in terms of reusability of the powders over multiple cycles that result in cost savings. However, currently there are no standards to determine the factors that govern the powder reuse times. This work presents the results from a recyclability study conducted on Inconel 718 and Ti-6Al-4V powders. It has been found that the Inconel 718 powders are chemically stable over a large number of cycles and their reuse time is limited by physical characteristics of powders such as flowability. Ti-6Al-4V, on the other hand, finds its reusemore » time governed by the oxygen pick up that occurs during and in between build cycles. The detailed results have been presented.« less

  11. Recyclability study on Inconel 718 and Ti-6Al-4V powders for use in electron beam melting

    SciTech Connect (OSTI)

    Nandwana, Peeyush; Peter, William H.; Lowe, Larry E.; Dehoff, Ryan R.; Medina, Francisco; Babu, Sudarsanam Suresh; Kirka, Michael M.

    2015-10-20

    In this study, powder bed based additive manufacturing technologies offer a big advantage in terms of reusability of the powders over multiple cycles that result in cost savings. However, currently there are no standards to determine the factors that govern the powder reuse times. This work presents the results from a recyclability study conducted on Inconel 718 and Ti-6Al-4V powders. It has been found that the Inconel 718 powders are chemically stable over a large number of cycles and their reuse time is limited by physical characteristics of powders such as flowability. Ti-6Al-4V, on the other hand, finds its reuse time governed by the oxygen pick up that occurs during and in between build cycles. The detailed results have been presented.

  12. Zero discharge organic coatings, powder paint - UV curable paint - E-coat. Volume 1. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    Leal, J.; Martin, D.R.; Spadafora, S.J.; Eng, A.T.; Stark, H.

    1995-06-01

    Zero Discharge Organic Coatings project developed powder paint, Ultraviolet (UV) curable paint, and electro- coating (E-coat) paint for military Applications. These technologies offer potential for high performance coatings with little or no volatile organic compound (VOC) emissions or hazardous waste generation. The ZDOC project focused on formulating non-toxic corrosion inhibitors into these coating technologies, and the applications development of powder coatings. Non-toxic replacements for traditional lead and chromate inhibitors were selected based on a previous NAWCADWAR investigation. Once incorporated, the performance of the coatings with and without inhibitors was compared. Also, the protective mechanisms of these inhibitors were studied. The applications development for powder coatings analyzed technologies to allow powder coating of non-conductive substrates and evaluated the use of IR energy to cure powder coatings. Inhibitors were successfully incorporated into electrocoatings and powder coatings, however corrosion performance results varied with coating formulation.

  13. Microstructure investigation of 13Cr-2Mo ODS steel components obtained by high voltage electric discharge compaction technique

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bogachev, Igor; Yudin, Artem; Grigoryev, Evgeniy; Chernov, Ivan; Staltsov, Maxim; Khasanov, Oleg; Olevsky, Eugene

    2015-11-02

    Refractory oxide dispersion strengthened 13Cr-2Mo steel powder was successfully consolidated to near theoretical density using high voltage electric discharge compaction. Cylindrical samples with relative density from 90% to 97% and dimensions of 10 mm in diameter and 10–15 mm in height were obtained. Consolidation conditions such as pressure and voltage were varied in some ranges to determine the optimal compaction regime. Three different concentrations of yttria were used to identify its effect on the properties of the samples. It is shown that the utilized ultra-rapid consolidation process in combination with high transmitted energy allows obtaining high density compacts, retaining themore » initial structure with minimal grain growth. The experimental results indicate some heterogeneity of the structure which may occur in the external layers of the tested samples due to various thermal and electromagnetic in-processing effects. As a result, the choice of the optimal parameters of the consolidation enables obtaining samples of acceptable quality.« less

  14. Self-powdering and nonlinear optical domain structures in ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3} crystals formed in glass

    SciTech Connect (OSTI)

    Tsukada, Y.; Honma, T.; Komatsu, T.

    2009-08-15

    Ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3}, (GMO), crystals are formed through the crystallization of 21.25Gd{sub 2}O{sub 3}-63.75MoO{sub 3}-15B{sub 2}O{sub 3} glass (mol%), and two scientific curious phenomena are observed. (1) GMO crystals formed in the crystallization break into small pieces with a triangular prism or pyramid shape having a length of 50-500 {mu}m spontaneously during the crystallizations in the inside of an electric furnace, not during the cooling in air after the crystallization. This phenomenon is called 'self-powdering phenomenon during crystallization' in this paper. (2) Each self-powdered GMO crystal grain shows a periodic domain structure with different refractive indices, and a spatially periodic second harmonic generation (SHG) depending on the domain structure is observed. It is proposed from polarized micro-Raman scattering spectra and the azimuthal dependence of second harmonic intensities that GMO crystals are oriented in each crystal grain and the orientation of (MoO{sub 4}){sup 2-} tetrahedra in GMO crystals changes periodically due to spontaneous strains in ferroelastic GMO crystals. - Graphical abstract: This figure shows the polarized optical photograph at room temperature for a particle (piece) obtained by a heat treatment of the glass at 590 deg. C for 2 h in an electric furnace in air. This particle was obtained through the self-powdering behavior in the crystallization of glass. The periodic domain structure is observed. Ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3} crystals are formed in the particle, and second harmonic generations are detected, depending on the domain structure.

  15. Method for molding ceramic powders using a water-based gel casting process

    DOE Patents [OSTI]

    Jenny, Mark A. (Knoxville, TN); Omalete, Ogbemi O. (Lagos, NG)

    1992-09-08

    A method for molding ceramic powders comprises forming a slurry mixture including ceramic powder, a dispersant, and a monomer solution. The monomer solution includes at least one monofunctional monomer and at least one difunctional monomer, a free-radical initiator, and a aqueous solvent. The slurry mixture is transferred to a mold, and the mold containing the slurry mixture is heated to polymerize and crosslink the monomer and form a firm polymer-solvent gel matrix. The solid product may be removed from the mold and heated to first remove the solvent and subsequently remove the polymer, whereafter the product may be sintered.

  16. Method for molding ceramic powders using a water-based gel casting

    DOE Patents [OSTI]

    Janney, Mark A. (Knoxville, TN); Omatete, Ogbemi O. (Lagos, NG)

    1991-07-02

    A method for molding ceramic powders comprises forming a slurry mixture including ceramic powder, a dispersant, and a monomer solution. The monomer solution includes at least one monofunctional monomer and at least one difunctional monomer, a free-radical initiator, and a aqueous solvent. The slurry mixture is transferred to a mold, and the mold containing the slurry mixture is heated to polymerize and crosslink the monomer and form a firm polymer-solvent gel matrix. The solid product any be removed from the mold and heated to first remove the solvent and subsequently remove the polymer, whereafter the product may be sintered.

  17. MnO spin-wave dispersion curves from neutron powder diffraction

    SciTech Connect (OSTI)

    Goodwin, Andrew L.; Dove, Martin T.; Tucker, Matthew G.; Keen, David A.

    2007-02-15

    We describe a model-independent approach for the extraction of spin-wave dispersion curves from powder neutron total scattering data. Our approach is based on a statistical analysis of real-space spin configurations to calculate spin-dynamical quantities. The RMCPROFILE implementation of the reverse Monte Carlo refinement process is used to generate a large ensemble of supercell spin configurations from MnO powder diffraction data collected at 100 K. Our analysis of these configurations gives spin-wave dispersion curves for MnO that agree well with those determined independently using neutron triple-axis spectroscopic techniques.

  18. Conversion method of powder inelastic scattering data for one-dimensional systems

    SciTech Connect (OSTI)

    Tomiyasu, Dr. Keisuke; Fujita, Prof. Masaki; Kolesnikov, Alexander I; Bewley, Robert I.; Bull, Dr. Martyn J.; Bennington, Dr. Stephen M.

    2009-01-01

    Extracting dispersive magnetic excitations from inelastic neutron scattering data usually requires large single crystals. We present a simple yet powerful method for extracting such information from polycrystalline or powder data for one-dimensional systems. We demonstrate the effectiveness of this data treatment by extracting dispersion curves from powder inelastic neutron scattering data on the one-dimensional spin-half systems: CuGeO3 and Rb2Cu2Mo3O12. For many such materials it is not possible to grow sufficiently large crystals and this method offers a quick and efficient way to study their magnetic excitations.

  19. Method of making metal oxide ceramic powders by using a combustible amino acid compound

    DOE Patents [OSTI]

    Pederson, L.R.; Chick, L.A.; Exarhos, G.J.

    1992-05-19

    This invention is directed to the formation of homogeneous, aqueous precursor mixtures of at least one substantially soluble metal salt and a substantially soluble, combustible co-reactant compound, typically an amino acid. This produces, upon evaporation, a substantially homogeneous intermediate material having a total solids level which would support combustion. The homogeneous intermediate material essentially comprises highly dispersed or solvated metal constituents and the co-reactant compound. The intermediate material is quite flammable. A metal oxide powder results on ignition of the intermediate product which combusts same to produce the product powder.

  20. Method of making metal oxide ceramic powders by using a combustible amino acid compound

    DOE Patents [OSTI]

    Pederson, Larry R. (Kennewick, WA); Chick, Lawrence A. (Richland, WA); Exarhos, Gregory J. (Richland, WA)

    1992-01-01

    This invention is directed to the formation of homogeneous, aqueous precursor mixtures of at least one substantially soluble metal salt and a substantially soluble, combustible co-reactant compound, typically an amino acid. This produces, upon evaporation, a substantially homogeneous intermediate material having a total solids level which would support combustion. The homogeneous intermediate material essentially comprises highly dispersed or solvated metal constituents and the co-reactant compound. The intermediate material is quite flammable. A metal oxide powder results on ignition of the intermediate product which combusts same to produce the product powder.

  1. Plasma synthesis of lithium based intercalation powders for solid polymer electrolyte batteries

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Pink, Robert J. (Pocatello, ID); Nelson, Lee O. (Idaho Falls, ID)

    2005-01-04

    The invention relates to a process for preparing lithium intercalation compounds by plasma reaction comprising the steps of: forming a feed solution by mixing lithium nitrate or lithium hydroxide or lithium oxide and the required metal nitrate or metal hydroxide or metal oxide and between 10-50% alcohol by weight; mixing the feed solution with O.sub.2 gas wherein the O.sub.2 gas atomizes the feed solution into fine reactant droplets, inserting the atomized feed solution into a plasma reactor to form an intercalation powder; and if desired, heating the resulting powder to from a very pure single phase product.

  2. In-situ Formation of Ti Alloys via Powder Injection Molding

    SciTech Connect (OSTI)

    Simmons, Kevin L.; Nyberg, Eric A.; Weil, K. Scott; Miller, Megan R.

    2005-01-01

    We have developed a unique blend of powder injection molding (PIM) feedstock materials in which only a small volume fraction of binder (< 8%) is required; the remainder of the mixture consists of the metal powder and a solid aromatic solvent. Because of the nature of the decomposition in the binder system and the relatively small amount used, the binder can be completely removed from the molded component during heat treatment. Here, we present results from an initial study on in-situ titanium alloy formation in near-net shape components manufactured by this novel PIM technique.

  3. Microstructure and Mechanical Properties of Titanium Components Fabricated by a New Powder Injection Molding Technique

    SciTech Connect (OSTI)

    Nyberg, Eric A.; Miller, Megan R.; Simmons, Kevin L.; Weil, K. Scott

    2005-05-01

    We have developed a powder injection molding (PIM) binder system for titanium that employs naphthalene as the primary constituent to facilitate easy binder removal and mitigate problems with carbon contamination. In the study presented here, we examined densification behavior, microstructure, and mechanical properties in specimens formed by this process. In general, we found that we could achieve tensile strengths comparable to wrought titanium in the PIM-formed specimens, but that maximum elongation was less than expected. Chemical and microstructural analyses suggest that use of higher purity powder and further process optimization will lead to significant improvements in ductility.

  4. A new binder for powder injection molding titanium and other reactive metals

    SciTech Connect (OSTI)

    Weil, K. Scott; Nyberg, Eric A.; Simmons, Kevin L.

    2006-06-26

    We have developed a new aromatic-based binder for powder injection molding (PIM) reactive metals, such as titanium, zirconium, niobium, tungsten, and molybdenum. Because of careful selection of the binder constituents, thermal removal is readily accomplished at low temperatures and short-times via vacuum sublimation. In this way the binder can be cleanly extracted from the green part prior to sintering to minimize the amount of residual carbon left in the final component. Rheological measurements indicate that powder loadings in the PIM feedstock as high as 67 vol% could be achieved using the new binder system, while still maintaining low mixing torques and injection molding pressures.

  5. Non-aqueous spray drying as a route to ultrafine ceramic powders

    SciTech Connect (OSTI)

    Armor, J.N. ); Fanelli, A.J.; Marsh, G.M. ); Zambri, P.M. )

    1988-09-01

    Spray drying imparts unique powder handling features to a wide variety of dried products and is usually carried out in a heated air stream while feeding an aqueous suspension of some solid material. The present work, however, describes non-aqueous spray drying as a means of preparing fine powders of metal oxides. In this case an alcohol solvent was used in place of water and the slurry sprayed under an inert atmosphere. Using the non-aqueous technique, the product consists of distinct but loosely aggregated primary particles. Such materials have potential for use as catalysts or catalyst supports.

  6. DOE - Office of Legacy Management -- Tyson Valley Powder Farm - MO 11

    Office of Legacy Management (LM)

    Tyson Valley Powder Farm - MO 11 FUSRAP Considered Sites Site: TYSON VALLEY POWDER FARM (MO.11) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: St. Louis County , Missouri MO.11-1 Evaluation Year: 1987 MO.11-2 Site Operations: Storage of C-Special material (residue from production of uranium metal). MO.11-1 MO.11-2 MO.11-3 Site Disposition: Eliminated - Referred to Army Corps of Engineers MO.11-2 Radioactive Materials Handled: Yes

  7. WEATHER ON THE NEAREST BROWN DWARFS: RESOLVED SIMULTANEOUS MULTI-WAVELENGTH VARIABILITY MONITORING OF WISE J104915.57–531906.1AB

    SciTech Connect (OSTI)

    Biller, Beth A.; Crossfield, Ian J. M.; Mancini, Luigi; Ciceri, Simona; Kopytova, Taisiya G.; Bonnefoy, Mickaël; Deacon, Niall R.; Schlieder, Joshua E.; Buenzli, Esther; Brandner, Wolfgang; Bailer-Jones, Coryn A. L.; Henning, Thomas; Goldman, Bertrand; Southworth, John; Allard, France; Homeier, Derek; Freytag, Bernd; Greiner, Jochen

    2013-11-20

    We present two epochs of MPG/ESO 2.2 m GROND simultaneous six-band (r'i'z' JHK) photometric monitoring of the closest known L/T transition brown dwarf binary WISE J104915.57–531906.1AB. We report here the first resolved variability monitoring of both the T0.5 and L7.5 components. We obtained 4 hr of focused observations on the night of 2013 April 22 (UT), as well as 4 hr of defocused (unresolved) observations on the night of 2013 April 16 (UT). We note a number of robust trends in our light curves. The r' and i' light curves appear to be anti-correlated with z' and H for the T0.5 component and in the unresolved light curve. In the defocused dataset, J appears correlated with z' and H and anti-correlated with r' and i', while in the focused dataset we measure no variability for J at the level of our photometric precision, likely due to evolving weather phenomena. In our focused T0.5 component light curve, the K band light curve displays a significant phase offset relative to both H and z'. We argue that the measured phase offsets are correlated with atmospheric pressure probed at each band, as estimated from one-dimensional atmospheric models. We also report low-amplitude variability in i' and z' intrinsic to the L7.5 component.

  8. Material to Efficiently and Economically Obtain Microorganism and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microalgae - Energy Innovation Portal Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Material to Efficiently and Economically Obtain Microorganism and Microalgae Ames Laboratory Contact AMES About This Technology Technology Marketing SummaryTechnology provides an economical and efficient process to harvest microorganisms like microalgae from its growth media.Description The interest in using algae as feedstock for biofuel

  9. Senior Obama Administration Officials to Join Governor Brown, Mayor Garcetti, Other Leaders in L.A. for Climate Task Force Meeting

    Broader source: Energy.gov [DOE]

    On Thursday, February 13th, senior Obama Administration officials will join California Governor Jerry Brown, Los Angeles Mayor Eric Garcetti and state, local and tribal leaders from across the country for a media availability at Los Angeles City Hall

  10. From: Meredith Brown <racer@lanl.gov> Subject: Red Alert: Contamination Spread Outside of RCAs by Fruit Flies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 Jan 1999 15:30:02 -0600 From: Meredith Brown <racer@lanl.gov> Subject: Red Alert: Contamination Spread Outside of RCAs by Fruit Flies The following Lessons Learned is cleared for public release. John Bickford, Project Hanford Lessons Learned Coordinator (509) 373-7664 http://www.hanford.gov/lessons/sitell/sitehome.htm ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ Project Hanford Lessons Learned Title: Contamination Spread Outside of Radiation Control Areas by

  11. Spitzer IRAC mid-infrared photometry of 500-750 brown dwarf

    SciTech Connect (OSTI)

    Saumon, Didier; Leggett, Sandy K; Albert, Loic; Artigau, Etienne; Burningham, Ben; Delfosse, Xavier; Delorme, Philippe; Forveille, Thierry; Lucas, Philip W; Marley, Mark S; Pinfield, David J; Reyle, Celine; Smart, Richard L; Warren, Stephen J

    2010-10-26

    Mid-infrared data, including Spitzer warm-IRAC [3.6] and [4.5] photometry, is critical for understanding the cold population of brown dwarfs now being found, objects which have more in common with planets than stars. As effective temperature (T{sub eff}) drops from 800K to 400K, the fraction of flux emitted beyond 3 {mu}m increases rapidly, from about 40% to > 75%. This rapid increase makes a color like H-[4.5] a very sensitive temperature indicator, and it can be combined with a gravity- and metallicity-sensitive color like H-K to constrain all three of these fundamental properties, which in turn gives us mass and age for these slowly cooling objects. Determination of mid-infrared color trends also allows better exploitation of the WISE mission by the community. We use new Spitzer Cycle 6 IRAC photometry, together with published data, to present trends of color with type for L0 to T10 dwarfs. We also use the atmospheric and evolutionary models of Saumon and Marley to investigate the masses and ages of 13 very late-type T dwarfs, which have H-[4.5] > 3.2 and T{sub eff} {approx} 500K to 750K.

  12. Effects of water hardness on the toxicity of manganese to developing brown trout (Salmo trutta)

    SciTech Connect (OSTI)

    Stubblefield, W.A.; Garrison, T.D.; Hockett, J.R.; Brinkman, S.F.; Davies, P.H.; McIntyre, M.W.

    1997-10-01

    Manganese is a common constituent of point and nonpoint discharges from mining and smelting activities. Available data indicate that Mn is acutely toxic at relatively high aqueous concentrations, when compared with trace metals, and its toxicity is affected by water hardness. Little information is available regarding the chronic toxicity of manganese. Early-life-stage (ELS) tests were conducted to determine the toxicity of manganese to brown trout (Salmo trutta) and to evaluate the extent to which water hardness (ranging from 30 to 450 mg/L as CaCO{sub 3}) affects the chronic toxicity of Mn. Water hardness of significantly affected Mn chronic toxicity, with toxicity decreasing with increasing hardness. Decreased survival was the predominant effect noted in the 30-mg/L hardness experiment, while significant effects on growth (as measured by changes in body weight) were observed in both the 150- and 450-mg/L hardness experiments. Twenty-five percent inhibition concentration (IC25) values, based on the combined endpoints (i.e., survival and body weight), were 4.67, 5.59, and 8.68 mg Mn/L (based on measured Mn concentration) at hardness levels of approximately 30, 150, and 450 mg/L as CaCO{sub 3}, respectively.

  13. Characterization of novel sorghum brown midrib mutants from an EMS-mutagenized population

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sattler, Scott E.; Saballos, Ana; Xin, Zhanguo; Funnell-Harris, Deanna L.; Vermerris, Wilfred; Pedersen, Jeffrey F.

    2014-09-02

    Reducing lignin concentration in lignocellulosic biomass can increase forage digestibility for ruminant livestock and saccharification yields of biomass for bioenergy. In sorghum (Sorghum bicolor (L.) Moench) and several other C4 grasses, brown midrib (bmr) mutants have been shown to reduce lignin concentration. Putative bmr mutants isolated from an EMS-mutagenized population were characterized and classified based on their leaf midrib phenotype and allelism tests with the previously described sorghum bmr mutants bmr2, bmr6, and bmr12. These tests resulted in the identification of additional alleles of bmr2, bmr6,and bmr12, and, in addition, six bmr mutants were identified that were not allelic tomore » these previously described loci. Further allelism testing among these six bmr mutants showed that they represented four novel bmr loci. Based on this study, the number of bmr loci uncovered in sorghum has doubled. The impact of these lines on agronomic traits and lignocellulosic composition was assessed in a 2-yr field study. Most of the identified bmr lines showed reduced lignin concentration of their biomass relative to wild-type (WT). Effects of the six new bmr mutants on enzymatic saccharification of lignocellulosic materials were determined, but the amount of glucose released from the stover was similar to WT in all cases. Like bmr2, bmr6, and bmr12, these mutants may affect monolignol biosynthesis and may be useful for bioenergy and forage improvement when stacked together or in combination with the three previously described bmr alleles.« less

  14. Structural and spectroscopic analyses of europium doped yttrium oxyfluoride powders prepared by combustion synthesis

    SciTech Connect (OSTI)

    Rakov, Nikifor; Guimarães, R. B.; Maciel, Glauco S.; Lozano B, W.

    2013-07-28

    A facile widely spread technique employed to produce low-cost high-yield oxide powders, combustion synthesis, was used to prepare yttrium oxyfluoride crystalline ceramic powders. The structure of the powders was analyzed by X-ray powder diffraction and Rietveld refinement. Samples heat treated at 700 °C had a predominance of vernier orthorhombic Y{sub 6}O{sub 5}F{sub 8} phase, while samples heat treated at 800 °C crystallized in stoichiometric rhombohedral YOF phase. The samples were doped with luminescent europium trivalent ions (Eu{sup 3+}) in different concentrations (1–15 wt.%) and Judd-Ofelt theory was used to probe the distortion from the inversion symmetry of the local crystal field and the degree of covalency between the rare-earth ion and the surrounding ligands. The luminescence lifetime was measured and the luminescence quantum efficiency (LQE) was estimated. We observed that Eu{sup 3+}:Y{sub 6}O{sub 5}F{sub 8} samples presented higher LQE in spite of the larger local crystal field anisotropy found for Eu{sup 3+}:YOF samples.

  15. Method of manufacturing iron aluminide by thermomechanical processing of elemental powders

    DOE Patents [OSTI]

    Deevi, Seetharama C. (Midlothian, VA); Lilly, Jr., A. Clifton (Chesterfield, VA); Sikka, Vinod K. (Oak Ridge, TN); Hajaligol, Mohammed R. (Richmond, VA)

    2000-01-01

    A powder metallurgical process of preparing iron aluminide useful as electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 20 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1 % rare earth metal, .ltoreq.1% oxygen, and/or .ltoreq.3% Cu. The process includes forming a mixture of aluminum powder and iron powder, shaping the mixture into an article such as by cold rolling the mixture into a sheet, and sintering the article at a temperature sufficient to react the iron and aluminum powders and form iron aluminide. The sintering can be followed by hot or cold rolling to reduce porosity created during the sintering step and optional annealing steps in a vacuum or inert atmosphere.

  16. Final Report: Si and Na-SG Powder Hydrogen Fuel Cells

    SciTech Connect (OSTI)

    Melack, John

    2013-07-15

    The primary project objective is to develop and demonstrate a controllable hydrogen generation system based on sodium silicide powder for portable fuel cell applications. This includes the development and demonstration of all balance of plant and reaction control components, which encompass water feeding, thermal management, and reaction site maximization. The appropriate manufacturing methods to readily scale production of sodium silicide will also be investigated.

  17. Critical current of the dispersion superconducting phase, obtained during aging

    SciTech Connect (OSTI)

    Romanov, Y.P.; Smirnov, L.V.; Sadovskiy, V.D.; Volkenshteyn, N.V.

    1983-12-01

    High critical parameters of plastic superconductors on a base of solid solutions are obtained as a result of plastic deformation and heat treatment. At the same time, the critical current and field of monocrystalline samples turn out to be significantly lower. The preservation of superconducting in high magnetic fields is conditioned by the presence of a dense network of very thin intersecting filaments, which remain superconducting during the conversion of the main mass of the material into the normal state with the help of an electron microscope. A lamellar threddike structure was determined which was conditioned by plastic deformation and the breakdown of a solid solution.

  18. How to obtain the National Energy Modeling System (NEMS)

    Reports and Publications (EIA)

    2013-01-01

    The National Energy Modeling System (NEMS) NEMS is used by the modelers at the U. S. Energy Information Administration (EIA) who understand its structure and programming. NEMS has only been used by a few organizations outside of the EIA, because most people that requested NEMS found out that it was too difficult or rigid to use. NEMS is not typically used for state-level analysis and is poorly suited for application to other countries. However, many do obtain the model simply to use the data in its input files or to examine the source code.

  19. Center for Nanophase Materials Sciences (CNMS) - Obtaining Entry to CNMS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facilities Obtaining Entry to CNMS Facilities Photo Identification - Effective March 30, 2015, ORNL has become fully compliant with the REAL ID Act of 2005. This Act requires that anyone accessing a Federal Facility, which ORNL is, must present a compliant form of identification. State-issued driver's licenses that are not REAL ID compliant will no longer be accepted as proof of identity at ORNL. If you are from one of the noncompliant states, you will need to provide another form of

  20. Solution based temperature of Perovskite-type oxide films and powders

    SciTech Connect (OSTI)

    McHale, J.M. Jr.

    1995-04-01

    Conventional solid state reactions are diffusion limited processes that require high temperatures and long reaction times to reach completion. In this work, several solution based methods were utilized to circumvent this diffusion limited reaction and achieve product formation at lower temperatures. The solution methods studied all have the common goal of trapping the homogeneity inherent in a solution and transferring this homogeneity to the solid state, thereby creating a solid atomic mixture of reactants. These atomic mixtures can yield solid state products through {open_quotes}diffusionless{close_quotes} mechanisms. The effectiveness of atomic mixtures in solid state synthesis was tested on three classes of materials, varying in complexity. A procedure was invented for obtaining the highly water soluble salt, titanyl nitrate, TiO(NO{sub 3}){sub 2}, in crystalline form, which allowed the production of titanate materials by freeze drying. The freeze drying procedures yielded phase pure, nanocrystalline BaTiO{sub 3} and the complete SYNROC-B phase assemblage after ten minute heat treatments at 600{degrees}C and 1100{degrees}C, respectively. Two novel methods were developed for the solution based synthesis of Ba{sub 2}YCu{sub 3}O{sub 7-x} and Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10}. Thin and thick films of Ba{sub 2}YCu{sub 3}O{sub 7-x} and Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} were synthesized by an atmospheric pressure, chemical vapor deposition technique. Liquid ammonia solutions of metal nitrates were atomized with a stream of N{sub 2}O and ignited with a hydrogen/oxygen torch. The resulting flame was used to coat a substrate with superconducting material. Bulk powders of Ba{sub 2}YCu{sub 3}O{sub 7-x} and Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} were synthesized through a novel acetate glass method. The materials prepared were characterized by XRD, TEM, SEM, TGA, DTA, magnetic susceptibility and electrical resistivity measurements.

  1. Solution based synthesis of perovskite-type oxide films and powders

    SciTech Connect (OSTI)

    McHale, J.M. Jr.

    1995-01-01

    Conventional solid state reactions are diffusion limited processes that require high temperatures and long reaction times to reach completion. In this work, several solution based methods were utilized to circumvent this diffusion limited reaction and achieve product formation at lower temperatures. The solution methods studied all have the common goal of trapping the homogeneity inherent in a solution and transferring this homogeneity to the solid state, thereby creating a solid atomic mixture of reactants. These atomic mixtures can yield solid state products through diffusionless mechanisms. The effectiveness of atomic mixtures in solid state synthesis was tested on three classes of materials, varying in complexity. A procedure was invented for obtaining the highly water soluble salt, titanyl nitrate, TiO(NO{sub 3}){sub 2}, in crystalline form, which allowed the production of titanate materials by freeze drying. The freeze drying procedures yielded phase pure, nanocrystalline BaTiO{sub 3} and the complete SYNROC-B phase assemblage after ten minute heat treatments at 600 C and 1,100 C, respectively. Two novel methods were developed for the solution based synthesis of Ba{sub 2}YCu{sub 3}O{sub 7{minus}x} and Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10}. Thin and thick films of Ba{sub 2}YCu{sub 3}O{sub 7{minus}x} and Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} were synthesized by an atmospheric pressure, chemical vapor deposition technique. Liquid ammonia solutions of metal nitrates were atomized with a stream of N{sub 2}O and ignited with a hydrogen/oxygen torch. The resulting flame was used to coat a substrate with superconducting material. Bulk powders of Ba{sub 2}YCu{sub 3}O{sub 7{minus}x} and Bi{sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10} were synthesized through a novel acetate glass method. The materials prepared were characterized by XRD, TEM, SEM, TGA, DTA, magnetic susceptibility and electrical resistivity measurements.

  2. Fabrication of metal matrix composite by semi-solid powder processing

    SciTech Connect (OSTI)

    Wu, Yufeng

    2012-11-28

    Various metal matrix composites (MMCs) are widely used in the automotive, aerospace and electrical industries due to their capability and flexibility in improving the mechanical, thermal and electrical properties of a component. However, current manufacturing technologies may suffer from insufficient process stability and reliability and inadequate economic efficiency and may not be able to satisfy the increasing demands placed on MMCs. Semi-solid powder processing (SPP), a technology that combines traditional powder metallurgy and semi-solid forming methods, has potential to produce MMCs with low cost and high efficiency. In this work, the analytical study and experimental investigation of SPP on the fabrication of MMCs were explored. An analytical model was developed to understand the deformation mechanism of the powder compact in the semi-solid state. The densification behavior of the Al6061 and SiC powder mixtures was investigated with different liquid fractions and SiC volume fractions. The limits of SPP were analyzed in terms of reinforcement phase loading and its impact on the composite microstructure. To explore adoption of new materials, carbon nanotube (CNT) was investigated as a reinforcing material in aluminum matrix using SPP. The process was successfully modeled for the mono-phase powder (Al6061) compaction and the density and density distribution were predicted. The deformation mechanism at low and high liquid fractions was discussed. In addition, the compaction behavior of the ceramic-metal powder mixture was understood, and the SiC loading limit was identified by parametric study. For the fabrication of CNT reinforced Al6061 composite, the mechanical alloying of Al6061-CNT powders was first investigated. A mathematical model was developed to predict the CNT length change during the mechanical alloying process. The effects of mechanical alloying time and processing temperature during SPP were studied on the mechanical, microstructural and compositional properties of the Al6061-CNT composites. A shear lag model was applied to predict the mechanical property (hardness) of the composite. This work demonstrated the promising potential of SPP in the fabrication of particle/fiber (nanotube) reinforced MMCs.

  3. Hybrid nuclear reactor grey rod to obtain required reactivity worth

    DOE Patents [OSTI]

    Miller, John V. (Munhall, PA); Carlson, William R. (Scott Township, Allegheny County, PA); Yarbrough, Michael B. (Hempfield Township, Westmoreland County, PA)

    1991-01-01

    Hybrid nuclear reactor grey rods are described, wherein geometric combinations of relatively weak neutron absorber materials such as stainless steel, zirconium or INCONEL, and relatively strong neutron absorber materials, such as hafnium, silver-indium cadmium and boron carbide, are used to obtain the reactivity worths required to reach zero boron change load follow. One embodiment includes a grey rod which has combinations of weak and strong neutron absorber pellets in a stainless steel cladding. The respective pellets can be of differing heights. A second embodiment includes a grey rod with a relatively thick stainless steel cladding receiving relatively strong neutron absorber pellets only. A third embodiment includes annular relatively weak netron absorber pellets with a smaller diameter pellet of relatively strong absorber material contained within the aperture of each relatively weak absorber pellet. The fourth embodiment includes pellets made of a homogeneous alloy of hafnium and a relatively weak absorber material, with the percentage of hafnium chosen to obtain the desired reactivity worth.

  4. Method of manufacturing aluminide sheet by thermomechanical processing of aluminide powders

    DOE Patents [OSTI]

    Hajaligol, Mohammad R.; Scorey, Clive; Sikka, Vinod K.; Deevi, Seetharama C.; Fleishhauer, Grier; Lilly, Jr., A. Clifton; German, Randall M.

    2003-12-09

    A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3% Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

  5. Method of manufacturing aluminide sheet by thermomechanical processing of aluminide powders

    DOE Patents [OSTI]

    Hajaligol, Mohammad R.; Scorey, Clive; Sikka, Vinod K.; Deevi, Seetharama C.; Fleischhauer, Grier; Lilly, Jr., A. Clifton; German, Randall M.

    2000-01-01

    A powder metallurgical process of preparing a sheet from a powder having an intermetallic alloy composition such as an iron, nickel or titanium aluminide. The sheet can be manufactured into electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 4 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.0.05% Zr.ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Ni, .ltoreq.0.75% C, .ltoreq.0.1% B, .ltoreq.1% submicron oxide particles and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, and/or .ltoreq.3% Cu. The process includes forming a non-densified metal sheet by consolidating a powder having an intermetallic alloy composition such as by roll compaction, tape casting or plasma spraying, forming a cold rolled sheet by cold rolling the non-densified metal sheet so as to increase the density and reduce the thickness thereof and annealing the cold rolled sheet. The powder can be a water, polymer or gas atomized powder which is subjecting to sieving and/or blending with a binder prior to the consolidation step. After the consolidation step, the sheet can be partially sintered. The cold rolling and/or annealing steps can be repeated to achieve the desired sheet thickness and properties. The annealing can be carried out in a vacuum furnace with a vacuum or inert atmosphere. During final annealing, the cold rolled sheet recrystallizes to an average grain size of about 10 to 30 .mu.m. Final stress relief annealing can be carried out in the B2 phase temperature range.

  6. Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats

    SciTech Connect (OSTI)

    Bass, V.; Gordon, C.J.; Jarema, K.A.; MacPhail, R.C.; Cascio, W.E.; Phillips, P.M.; Ledbetter, A.D.; Schladweiler, M.C.; Andrews, D.; Miller, D.; Doerfler, D.L.; Kodavanti, U.P.

    2013-12-15

    Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: • Air pollutants have been associated with increased diabetes in humans. • Acute ozone exposure produces profound metabolic alterations in rats. • Age influences metabolic risk factors in aging BN rats. • Acute metabolic effects are reversible and repeated exposure reduces these effects. • Ozone metabolic effects are only slightly exacerbated in geriatric rats.

  7. OBTAINING POTENTIAL FIELD SOLUTIONS WITH SPHERICAL HARMONICS AND FINITE DIFFERENCES

    SciTech Connect (OSTI)

    Toth, Gabor; Van der Holst, Bart; Huang Zhenguang

    2011-05-10

    Potential magnetic field solutions can be obtained based on the synoptic magnetograms of the Sun. Traditionally, a spherical harmonics decomposition of the magnetogram is used to construct the current- and divergence-free magnetic field solution. This method works reasonably well when the order of spherical harmonics is limited to be small relative to the resolution of the magnetogram, although some artifacts, such as ringing, can arise around sharp features. When the number of spherical harmonics is increased, however, using the raw magnetogram data given on a grid that is uniform in the sine of the latitude coordinate can result in inaccurate and unreliable results, especially in the polar regions close to the Sun. We discuss here two approaches that can mitigate or completely avoid these problems: (1) remeshing the magnetogram onto a grid with uniform resolution in latitude and limiting the highest order of the spherical harmonics to the anti-alias limit; (2) using an iterative finite difference algorithm to solve for the potential field. The naive and the improved numerical solutions are compared for actual magnetograms and the differences are found to be rather dramatic. We made our new Finite Difference Iterative Potential-field Solver (FDIPS) a publicly available code so that other researchers can also use it as an alternative to the spherical harmonics approach.

  8. Effect of addition of Ag nano powder on mechanical properties of epoxy/polyaminoamide adduct coatings filled with conducting polymer

    SciTech Connect (OSTI)

    Samad, Ubair Abdus; Khan, Rawaiz; Alam, Mohammad Asif; Al-Othman, Othman Y.; Al-Zahrani, Saeed M.

    2015-05-22

    In this study the effect of Ag Nano powder on mechanical properties of epoxy coatings filled with optimized ratio of conducting polymers (Polyaniline and Polyppyrole) was evaluated. Bisphenol A diglycidyl ether epoxy resin (DGEBA) along with polyaminoamide adduct (ARADUR 3282-1 BD) is used as curing agent under optimized stoichiometry values. Curing is performed at room temperature with different percentages of Nano filler. Glass and steel panels were used as coating substrate. Bird applicator was used to coat the samples in order to obtain thin film with wet film thickness (WFT) of about 70-90?µm. The samples were kept in dust free environment for about 7 days at room temperature for complete curing. The coated steel panels were used to evaluate the mechanical properties of coating such as hardness, scratch and impact tests whereas coated glass panels were used for measuring pendulum hardness of the coatings. To check the dispersion and morphology of Nano filler in epoxy matrix scanning electron microscopy (SEM) was used in addition Nano indentation was also performed to observe the effect of Nano filler on modulus of elasticity and hardness at Nano scale.

  9. Noise correction of turbulent spectra obtained from Acoustic Doppler Velocimeters

    SciTech Connect (OSTI)

    Durgesh, Vibhav; Thomson, Jim; Richmond, Marshall C.; Polagye, Brian

    2014-03-02

    Accurately estimated auto-spectral density functions are essential for characterization of turbulent flows, and they also have applications in computational fluid dynamics modeling, site and inflow characterization for hydrokinetic turbines, and inflow turbulence generation. The Acoustic Doppler Velocimeter (ADV) provides single-point temporally resolved data, that are used to characterize turbulent flows in rivers, seas, and oceans. However, ADV data are susceptible to contamination from various sources, including instrument noise, which is the intrinsic limit to the accuracy of acoustic velocity measurements. Due to the presence of instrument noise, the spectra obtained are altered at high frequencies. The focus of this study is to develop a robust and effective method for accurately estimating auto-spectral density functions from ADV data by reducing or removing the spectral contribution derived from instrument noise. For this purpose, the “Noise Auto-Correlation” (NAC) approach was developed, which exploits the correlation properties of instrument noise to identify and remove its contribution from spectra. The spectra estimated using the NAC approach exhibit increased fidelity and a slope of -5/3 in the inertial range, which is typically observed for turbulent flows. Finally, this study also compares the effectiveness of low-pass Gaussian filters in removing instrument noise with that of the NAC approach. For the data used in this study, both the NAC and Gaussian filter approaches are observed to be capable of removing instrument noise at higher frequencies from the spectra. However, the NAC results are closer to the expected frequency power of -5/3 in the inertial sub-range.

  10. Effect of calcium modification on the microstructure and oxidation property of submicron spherical palladium powders

    SciTech Connect (OSTI)

    Che, S.; Sakurai, O.; Funakubo, H.; Shinozaki, K.; Mizutani, N.

    1997-02-01

    Ca-modified spherical palladium particles were prepared from the mixed solution of Pd(NO{sub 3}){sub 2} and Ca(NO{sub 3}){sub 2} by ultrasonic spray pyrolysis. Pure palladium powder and that modified with less than 55 ppm Ca were composed of single crystal particles. However, Ca addition of more than 550 ppm resulted in polycrystalline particles. Crystallite size of the particles decreased with the increase of Ca addition and changed dramatically at the addition of some hundred ppm. Ca additive did not form solid solution with palladium but formed CaPd{sub 3}O{sub 4} on the surface and grain boundary of the particles. 50 ppm{endash}1{percent} of Ca addition significantly reduced the oxidization of palladium powder. More addition of Ca resulted in excess oxidation due to the reaction between palladium and calcium oxide. {copyright} {ital 1997 Materials Research Society.}

  11. Hydration mechanisms of ternary Portland cements containing limestone powder and fly ash

    SciTech Connect (OSTI)

    De Weerdt, K.; Haha, M. Ben; Le Saout, G.; Kjellsen, K.O.; Justnes, H.; Lothenbach, B.

    2011-03-15

    The effect of minor additions of limestone powder on the properties of fly ash blended cements was investigated in this study using isothermal calorimetry, thermogravimetry (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM) techniques, and pore solution analysis. The presence of limestone powder led to the formation of hemi- and monocarbonate and to a stabilisation of ettringite compared to the limestone-free cements, where a part of the ettringite converted to monosulphate. Thus, the presence of 5% of limestone led to an increase of the volume of the hydrates, as visible in the increase in chemical shrinkage, and an increase in compressive strength. This effect was amplified for the fly ash/limestone blended cements due to the additional alumina provided by the fly ash reaction.

  12. Advancements in Ti Alloy Powder Production by Close-Coupled Gas Atomization

    SciTech Connect (OSTI)

    Heidloff, Andy; Rieken, Joel; Anderson, Iver; Byrd, David

    2011-04-01

    As the technology for titanium metal injection molding (Ti-MIM) becomes more readily available, efficient Ti alloy fine powder production methods are required. An update on a novel close-coupled gas atomization system has been given. Unique features of the melting apparatus are shown to have measurable effects on the efficiency and ability to fully melt within the induction skull melting system (ISM). The means to initiate the melt flow were also found to be dependent on melt apparatus. Starting oxygen contents of atomization feedstock are suggested based on oxygen pick up during the atomization and MIM processes and compared to a new ASTM specification. Forming of titanium by metal injection molding (Ti-MIM) has been extensively studied with regards to binders, particle shape, and size distribution and suitable de-binding methods have been discovered. As a result, the visibility of Ti-MIM has steadily increased as reviews of technology, acceptability, and availability have been released. In addition, new ASTM specification ASTM F2885-11 for Ti-MIM for biomedical implants was released in early 2011. As the general acceptance of Ti-MIM as a viable fabrication route increases, demand for economical production of high quality Ti alloy powder for the preparation of Ti-MIM feedstock correspondingly increases. The production of spherical powders from the liquid state has required extensive pre-processing into different shapes thereby increasing costs. This has prompted examination of Ti-MIM with non-spherical particle shape. These particles are produced by the hydride/de-hydride process and are equi-axed but fragmented and angular which is less than ideal. Current prices for MIM quality titanium powder range from $40-$220/kg. While it is ideal for the MIM process to utilize spherical powders within the size range of 0.5-20 {mu}m, titanium's high affinity for oxygen to date has prohibited the use of this powder size range. In order to meet oxygen requirements the top size cut has traditionally been 45 {mu}m, and in some instances a bottom cut at +5 {mu}m is made to remove ultra-fine particles and reduce oxygen content. Predictably, use of irregular shaped or larger particle feedstock powder can reduce part quality as sintering shrinkage and part detail suffer. Thus, widespread production and technological use of Ti-MIM is limited due in large part to Ti alloy feedstock cost and availability, not MIM processing capability. Lower cost feedstock of fine, spherical Ti alloy powder with sufficient purity must be available in order to fully utilize the advantages of the Ti-MIM processing route allowing expansion of the market to small complex Ti parts in many high volume applications.

  13. A sol-powder coating technique for fabrication of yttria stabilised zirconia

    SciTech Connect (OSTI)

    Wattanasiriwech, Darunee . E-mail: darunee@mfu.ac.th; Wattanasiriwech, Suthee; Stevens, Ron

    2006-08-10

    Yttria stabilised zirconia has been prepared using a simple sol-powder coating technique. The polymeric yttria sol, which was prepared using 1,3 propanediol as a network modifier, was homogeneously mixed with nanocrystalline zirconia powder and it showed a dual function: as a binder which promoted densification and a phase modifier which stabilised zirconia in the tetragonal and cubic phases. Thermal analysis and X-ray diffraction revealed that the polymeric yttria sol which decomposed at low temperature into yttrium oxide could change the m {sup {yields}} t phase transformation behaviour of the zirconia, possibly due to the small particle size and very high surface area of both yttria and zirconia particles allowing rapid alloying. The sintered samples exhibited three crystalline phases: monoclinic, tetragonal and cubic, in which cubic and tetragonal are the major phases. The weight fractions of the individual phases present in the selected specimens were determined using quantitative Rietveld analysis.

  14. Method of making polymer powders and whiskers as well as particulate products of the method and atomizing apparatus

    DOE Patents [OSTI]

    Otaigbe, Joshua U.; McAvoy, Jon M.; Anderson, Iver E.; Ting, Jason; Mi, Jia; Terpstra, Robert

    2001-01-09

    Method for making polymer particulates, such as spherical powder and whiskers, by melting a polymer material under conditions to avoid thermal degradation of the polymer material, atomizing the melt using gas jet means in a manner to form atomized droplets, and cooling the droplets to form polymer particulates, which are collected for further processing. Atomization parameters can be controlled to produce polymer particulates with controlled particle shape, particle size, and particle size distribution. For example, atomization parameters can be controlled to produce spherical polymer powders, polymer whiskers, and combinations of spherical powders and whiskers. Atomizing apparatus also is provided for atoomizing polymer and metallic materials.

  15. Nuclear factor-?B is a common upstream signal for growth differentiation factor-5 expression in brown adipocytes exposed to pro-inflammatory cytokines and palmitate

    SciTech Connect (OSTI)

    Hinoi, Eiichi; Iezaki, Takashi; Ozaki, Kakeru; Yoneda, Yukio

    2014-10-03

    Highlights: • GDF5 expression is up-regulated by IL-1?, TNF-? and palmitate in brown pre-adipocytes. • NF-?B stimulates promoter activity and expression of GDF5 in brown pre-adipocytes. • Recruitment of NF-?B to the GDF5 promoter is facilitated in BAT from ob/ob mice. • An NF-?B inhibitor prevents upregulation of GDF5 expression in brown pre-adipocytes. - Abstract: We have previously demonstrated that genetic and acquired obesity similarly led to drastic upregulation in brown adipose tissue (BAT), rather than white adipose tissue, of expression of both mRNA and corresponding protein for the bone morphogenic protein/growth differentiation factor (GDF) member GDF5 capable of promoting brown adipogenesis. In this study, we evaluated expression profiles of GDF5 in cultured murine brown pre-adipocytes exposed to pro-inflammatory cytokines and free fatty acids (FFAs), which are all shown to play a role in the pathogenesis of obesity. Both interleukin-1? (IL-1?) and tumor necrosis factor-? (TNF-?) were effective in up-regulating GDF5 expression in a concentration-dependent manner, while similar upregulation was seen in cells exposed to the saturated FFA palmitate, but not to the unsaturated FFA oleate. In silico analysis revealed existence of the putative nuclear factor-?B (NF-?B) binding site in the 5?-flanking region of mouse GDF5, whereas introduction of NF-?B subunits drastically facilitated both promoter activity and expression of GDF5 in brown pre-adipocytes. Chromatin immunoprecipitation analysis confirmed significant facilitation of the recruitment of NF-?B to the GDF5 promoter in lysed extracts of BAT from leptin-deficient ob/ob obese mice. Upregulation o GDF5 expression was invariably inhibited by an NF-?B inhibitor in cultured brown pre-adipocytes exposed to IL-1?, TNF-? and palmitate. These results suggest that obesity leads to upregulation of GDF5 expression responsible for the promotion of brown adipogenesis through a mechanism relevant to activation of the NF-?B pathway in response to particular pro-inflammatory cytokines and/or saturated FFAs in BAT.

  16. Apparatus for and method of producing monodisperse submicron polymer powders from solution

    DOE Patents [OSTI]

    Noid, Donald W. (Knoxville, TN); Otaigbe, Joshua U. (Ames, IA); Barnes, Michael D. (Oak Ridge, TN); Sumpter, Bobby G. (Knoxville, TN); Kung, Chung-Yi (Tuscon, AZ)

    2002-01-01

    This invention describes a method of producing polymer powders from solution in a compatible solvent using a new device referred to as a microdroplets on demand generator (MODG). The embodiment of this invention is the MODG apparatus and its relevance as a method to extensive application in materials science and technology. Proof of concept is demonstrated using poly(ethylene) glycol polymer microparticles generated with the MODG and captured in a microparticle levitation device.

  17. Irradiation creep of nano-powder sintered silicon carbide at low neutron fluences

    SciTech Connect (OSTI)

    Koyanagi, Takaaki; Shimoda, Kazuya; Kondo, Sosuke; Hinoki, Tatsuya; Ozawa, Kazumi; Katoh, Yutai

    2014-12-01

    The irradiation creep behavior of nano-powder sintered silicon carbide was investigated using the bend stress relaxation method under neutron irradiation up to 1.9 dpa. The creep deformation was observed at all temperatures ranging from 380 to 1180 °C mainly from the irradiation creep but with the increasing contributions from the thermal creep at higher temperatures. Microstructural observation and data analysis were performed.

  18. Vacuum Attachment for Collection of Lithium Powder ---- Inventor(s) Hans

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Schneider and Stephan Jurczynski | Princeton Plasma Physics Lab Vacuum Attachment for Collection of Lithium Powder ---- Inventor(s) Hans Schneider and Stephan Jurczynski The Vacuum Attachment is part of an integrated system designed to collect Lithium (Li) Power for storage in mineral oil or to passivate it in Vinegar or Chilled Water. Major components are: Mister, Li Trap, Oil Trap or Combustion Chamber and Ash rated Shop Vacuum. The Mister provides a fine coating of mineral oil, vinegar or

  19. New Data for Aerosols Generated by Releases of Pressurized Powders and Solutions in Static Air

    SciTech Connect (OSTI)

    MY Ballinger; SL Sutter; WH Hodgson

    1987-04-01

    Pacific Northwest Laboratory conducted three sets of experiments to measure aerosols generated by pressurized releases. These aerosols are generated from releases of uranine pressurized with carbon dioxide, flashing sprays, and low-pressure depleted uranium dioxide powder releases. The purpose of these experiments was to supplement data from earlier experiments investigating the source term from pressurized releases. These experiments are part of a program to develop source-term estimation methods for analysis of accidents in nuclear fuel cycle facilities.

  20. A statistical analysis of seeds and other high-contrast exoplanet surveys: massive planets or low-mass brown dwarfs?

    SciTech Connect (OSTI)

    Brandt, Timothy D.; Spiegel, David S.; McElwain, Michael W.; Grady, C. A.; Turner, Edwin L.; Mede, Kyle; Kuzuhara, Masayuki; Schlieder, Joshua E.; Brandner, W.; Feldt, M.; Wisniewski, John P.; Abe, L.; Biller, B.; Carson, J.; Currie, T.; Egner, S.; Golota, T.; Guyon, O.; Goto, M.; Hashimoto, J.; and others

    2014-10-20

    We conduct a statistical analysis of a combined sample of direct imaging data, totalling nearly 250 stars. The stars cover a wide range of ages and spectral types, and include five detections (? And b, two ?60 M {sub J} brown dwarf companions in the Pleiades, PZ Tel B, and CD–35 2722B). For some analyses we add a currently unpublished set of SEEDS observations, including the detections GJ 504b and GJ 758B. We conduct a uniform, Bayesian analysis of all stellar ages using both membership in a kinematic moving group and activity/rotation age indicators. We then present a new statistical method for computing the likelihood of a substellar distribution function. By performing most of the integrals analytically, we achieve an enormous speedup over brute-force Monte Carlo. We use this method to place upper limits on the maximum semimajor axis of the distribution function derived from radial-velocity planets, finding model-dependent values of ?30-100 AU. Finally, we model the entire substellar sample, from massive brown dwarfs to a theoretically motivated cutoff at ?5 M {sub J}, with a single power-law distribution. We find that p(M, a)?M {sup –0.65} {sup ±} {sup 0.60} a {sup –0.85} {sup ±} {sup 0.39} (1? errors) provides an adequate fit to our data, with 1.0%-3.1% (68% confidence) of stars hosting 5-70 M {sub J} companions between 10 and 100 AU. This suggests that many of the directly imaged exoplanets known, including most (if not all) of the low-mass companions in our sample, formed by fragmentation in a cloud or disk, and represent the low-mass tail of the brown dwarfs.

  1. I. V. Khalzov, B. P. Brown, E. J. Kaplan, N. Katz, C. Paz-Soldan et al.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resistive and ferritic-wall plasma dynamos in a sphere I. V. Khalzov, B. P. Brown, E. J. Kaplan, N. Katz, C. Paz-Soldan et al. Citation: Phys. Plasmas 19, 104501 (2012); doi: 10.1063/1.4757219 View online: http://dx.doi.org/10.1063/1.4757219 View Table of Contents: http://pop.aip.org/resource/1/PHPAEN/v19/i10 Published by the American Institute of Physics. Additional information on Phys. Plasmas Journal Homepage: http://pop.aip.org/ Journal Information: http://pop.aip.org/about/about_the_journal

  2. Severe Accident Sequence Analysis Program: Anticipated transient without scram simulations for Browns Ferry Nuclear Plant Unit 1

    SciTech Connect (OSTI)

    Dallman, R J; Gottula, R C; Holcomb, E E; Jouse, W C; Wagoner, S R; Wheatley, P D

    1987-05-01

    An analysis of five anticipated transients without scram (ATWS) was conducted at the Idaho National Engineering Laboratory (INEL). The five detailed deterministic simulations of postulated ATWS sequences were initiated from a main steamline isolation valve (MSIV) closure. The subject of the analysis was the Browns Ferry Nuclear Plant Unit 1, a boiling water reactor (BWR) of the BWR/4 product line with a Mark I containment. The simulations yielded insights to the possible consequences resulting from a MSIV closure ATWS. An evaluation of the effects of plant safety systems and operator actions on accident progression and mitigation is presented.

  3. THE BROWN DWARF KINEMATICS PROJECT (BDKP). III. PARALLAXES FOR 70 ULTRACOOL DWARFS

    SciTech Connect (OSTI)

    Faherty, Jacqueline K.; Shara, Michael M.; Cruz, Kelle L.; Burgasser, Adam J.; Walter, Frederick M.; Van der Bliek, Nicole; Vrba, Frederick J.; Anglada-Escude, Guillem

    2012-06-10

    We report parallax measurements for 70 ultracool dwarfs (UCDs) including 11 late-M, 32 L, and 27 T dwarfs. In this sample, 14 M and L dwarfs exhibit low surface gravity features, 6 are close binary systems, and 2 are metal-poor subdwarfs. We combined our new measurements with 114 previously published UCD parallaxes and optical-mid-IR photometry to examine trends in spectral-type/absolute magnitude, and color-color diagrams. We report new polynomial relations between spectral type and M{sub JHK}. Including resolved L/T transition binaries in the relations, we find no reason to differentiate between a 'bright' (unresolved binary) and a 'faint' (single source) sample across the L/T boundary. Isolating early T dwarfs, we find that the brightening of T0-T4 sources is prominent in M{sub J} where there is a [1.2-1.4] mag difference. A similar yet dampened brightening of [0.3-0.5] mag happens at M{sub H} and a plateau or dimming of [-0.2 to -0.3] mag is seen in M{sub K} . Comparison with evolutionary models that vary gravity, metallicity, and cloud thickness verifies that for L into T dwarfs, decreasing cloud thickness reproduces brown dwarf near-IR color-magnitude diagrams. However we find that a near constant temperature of 1200 {+-}100 K along a narrow spectral subtype of T0-T4 is required to account for the brightening and color-magnitude diagram of the L-dwarf/T-dwarf transition. There is a significant population of both L and T dwarfs which are red or potentially 'ultra-cloudy' compared to the models, many of which are known to be young indicating a correlation between enhanced photospheric dust and youth. For the low surface gravity or young companion L dwarfs we find that 8 out of 10 are at least [0.2-1.0] mag underluminous in M{sub JH} and/or M{sub K} compared to equivalent spectral type objects. We speculate that this is a consequence of increased dust opacity and conclude that low surface gravity L dwarfs require a completely new spectral-type/absolute magnitude polynomial for analysis.

  4. Low Activation Joining of SiC/SiC Composites for Fusion Applications: Tape Casting TiC+Si Powders

    SciTech Connect (OSTI)

    Henager, Charles H.; Kurtz, Richard J.; Canfield, Nathan L.; Shin, Yongsoon; Luscher, Walter G.; Mansurov, Jirgal; Roosendaal, Timothy J.; Borlaug, Brennan A.

    2014-03-03

    This work discusses the latest developments in TiC + Si displacement reaction joining at PNNL based on new work to produce tape-cast powders for improved SiC-joints.

  5. Lithium cobalt(II) pyrophosphate, Li[subscript 1.86]CoP[subscript 2]O[subscript 7], from synchrotron X-ray powder data

    SciTech Connect (OSTI)

    Zhou, Hui; Upreti, Shailesh; Chernova, Natasha A.; Whittingham, M.Stanley

    2015-10-15

    Structure refinement of high-resolution X-ray powder diffraction data of the title compound gave the composition Li{sub 1.865}CoP{sub 2}O{sub 7}, which is also verified by the ICP measurement. Two Co sites exist in the structure: one is a CoO{sub 5} square pyramid and the other is a CoO{sub 6} octahedron. They share edges and are further interconnected through P{sub 2}O{sub 7} groups, forming a three-dimensional framework, which exhibits different kinds of intersecting tunnels containing Li cations and could be of great interest in Li ion battery chemistry. The structure also exhibits cation disorder with 13.5% Co residing at the lithium (Li1) site. Co seems to have an average oxidation state of 2.135, as obtained from the strutural stochiometry that closely supports the magnetic susceptibility findings.

  6. Gas atomized precursor alloy powder for oxide dispersion strengthened ferritic stainless steel

    SciTech Connect (OSTI)

    Rieken, Joel

    2011-12-13

    Gas atomization reaction synthesis (GARS) was employed as a simplified method for producing precursor powders for oxide dispersion strengthened (ODS) ferritic stainless steels (e.g., Fe-Cr-Y-(Ti,Hf)-O), departing from the conventional mechanical alloying (MA) process. During GARS processing a reactive atomization gas (i.e., Ar-O{sub 2}) was used to oxidize the powder surfaces during primary break-up and rapid solidification of the molten alloy. This resulted in envelopment of the powders by an ultra-thin (t < 150 nm) metastable Cr-enriched oxide layer that was used as a vehicle for solid-state transport of O into the consolidated microstructure. In an attempt to better understand the kinetics of this GARS reaction, theoretical cooling curves for the atomized droplets were calculated and used to establish an oxidation model for this process. Subsequent elevated temperature heat treatments, which were derived from Rhines pack measurements using an internal oxidation model, were used to promote thermodynamically driven O exchange reactions between trapped films of the initial Cr-enriched surface oxide and internal Y-enriched intermetallic precipitates. This novel microstructural evolution process resulted in the successful formation of nano-metric Y-enriched dispersoids, as confirmed using high energy X-ray diffraction and transmission electron microscopy (TEM), equivalent to conventional ODS alloys from MA powders. The thermal stability of these Y-enriched dispersoids was evaluated using high temperature (1200°C) annealing treatments ranging from 2.5 to 1,000 hrs of exposure. In a further departure from current ODS practice, replacing Ti with additions of Hf appeared to improve the Y-enriched dispersoid thermal stability by means of crystal structure modification. Additionally, the spatial distribution of the dispersoids was found to depend strongly on the original rapidly solidified microstructure. To exploit this, ODS microstructures were engineered from different powder particle size ranges, illustrating microstructural control as a function of particle solidification rate. The consolidation of ultra-fine powders (dia. ≤ 5μm) resulted in a significant reduction in dispersoid size and spacing, consistent with initial scanning electron microscopy studies on as-atomized cross-sectioned particles that suggested that these powders solidified above the threshold velocity to effectively solute trap Y within the α-(Fe,Cr) matrix. Interestingly, when the solidification velocity as a function of particle size was extracted from the aforementioned theoretical particle cooling curves, it could be offered as supporting evidence for these microstructure observations. Thermal-mechanical treatments also were used to create and evaluate the stability of a dislocation substructure within these alloys, using microhardness and TEM analysis of the alloy sub-grain and grain structure. Moreover, elevated temperature tensile tests up to 800°C were used to assess the initial mechanical strength of the ODS microstructure.

  7. Wall-slip of highly filled powder injection molding compounds: Effect of flow channel geometry and roughness

    SciTech Connect (OSTI)

    Hausnerova, Berenika; Sanetrnik, Daniel [Dept. of Production Engineering, Faculty of Technology, Tomas Bata University in Zlin, nám. T.G. Masaryka 5555, 760 01 Zlín, Czech Republic and Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Nad Ovc (Czech Republic); Paravanova, Gordana [Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Nad Ovcírnou 3685, 760 01 Zlín (Czech Republic)

    2014-05-15

    The paper deals with the rheological behavior of highly filled compounds proceeded via powder injection molding (PIM) and applied in many sectors of industry (automotive, medicine, electronic or military). Online rheometer equipped with slit dies varying in surface roughness and dimensions was applied to investigate the wall-slip as a rheological phenomenon, which can be considered as a parameter indicating the separation of compound components (polymer binder and metallic powder) during high shear rates when injection molded.

  8. The cost of silicon nitride powder: What must it be to compete?

    SciTech Connect (OSTI)

    Das, S.; Curlee, T.R.

    1992-02-01

    The ability of advanced ceramic components to compete with similar metallic parts will depend in part on current and future efforts to reduce the cost of ceramic parts. This paper examines the potential reductions in part cost that could result from the development of less expensive advanced ceramic powders. The analysis focuses specifically on two silicon nitride engine components -- roller followers and turbocharger rotors. The results of the process-cost models developed for this work suggest that reductions in the cost of advanced silicon nitride powder from its current level of about $20 per pound to about $5 per pound will not in itself be sufficient to lower the cost of ceramic parts below the current cost of similar metallic components. This work also examines if combinations of lower-cost powders and further improvements in other key technical parameters to which costs are most sensitive could push the cost of ceramics below the cost of metallics. Although these sensitivity analyses are reflective of technical improvements that are very optimistic, the resulting part costs are estimated to remain higher than similar metallic parts. Our findings call into question the widely-held notion that the cost of ceramic components must not exceed the cost of similar metallic parts if ceramics are to be competitive. Economic viability will ultimately be decided not on the basis of which part is less costly, but on an assessment of the marginal costs and benefits provided by ceramics and metallics. This analysis does not consider the benefits side of the equation. Our findings on the cost side of the equation suggest that the competitiveness of advanced ceramics will ultimately be decided by our ability to evaluate and communicate the higher benefits that advanced ceramic parts may offer.

  9. The cost of silicon nitride powder: What must it be to compete

    SciTech Connect (OSTI)

    Das, S.; Curlee, T.R.

    1992-02-01

    The ability of advanced ceramic components to compete with similar metallic parts will depend in part on current and future efforts to reduce the cost of ceramic parts. This paper examines the potential reductions in part cost that could result from the development of less expensive advanced ceramic powders. The analysis focuses specifically on two silicon nitride engine components -- roller followers and turbocharger rotors. The results of the process-cost models developed for this work suggest that reductions in the cost of advanced silicon nitride powder from its current level of about $20 per pound to about $5 per pound will not in itself be sufficient to lower the cost of ceramic parts below the current cost of similar metallic components. This work also examines if combinations of lower-cost powders and further improvements in other key technical parameters to which costs are most sensitive could push the cost of ceramics below the cost of metallics. Although these sensitivity analyses are reflective of technical improvements that are very optimistic, the resulting part costs are estimated to remain higher than similar metallic parts. Our findings call into question the widely-held notion that the cost of ceramic components must not exceed the cost of similar metallic parts if ceramics are to be competitive. Economic viability will ultimately be decided not on the basis of which part is less costly, but on an assessment of the marginal costs and benefits provided by ceramics and metallics. This analysis does not consider the benefits side of the equation. Our findings on the cost side of the equation suggest that the competitiveness of advanced ceramics will ultimately be decided by our ability to evaluate and communicate the higher benefits that advanced ceramic parts may offer.

  10. Structural Studies of Al:ZnO Powders and Thin Films | Stanford Synchrotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiation Lightsource Structural Studies of Al:ZnO Powders and Thin Films Monday, June 18, 2012 - 2:00pm SSRL Main Conference Room 137-322 Dr. Bridget Ingham, Associate Investigator, MacDiarmid Institute for Advanced Materials & Nanotechnology Al-doped ZnO (Al:ZnO) is a promising transparent conducting oxide. We have used complementary synchrotron and laboratory techniques to study the incorporation of Al within the ZnO lattice, and measure its effect on the crystallinity of thin films

  11. Magnetization and 13C NMR spin-lattice relaxation of nanodiamond powder

    SciTech Connect (OSTI)

    Levin, E.M.; Fang, X.W.; Bud'ko, S.L.; Straszheim, W.E.; McCallum, R.W.; Schmidt-Rohr, K.

    2008-02-15

    The bulk magnetization at temperatures of 1.8-400 K and in magnetic fields up to 70 kOe, the ambient temperature {sup 13}C NMR spin-lattice relaxation, T{sub 1,c}, and the elemental composition of three nanodiamond powder samples have been studied. The total magnetization of nanodiamond can be explained in terms of contributions from (1) the diamagnetic effect of carbon, (2) the paramagnetic effect of unpaired electrons present in nanodiamond grains, and (3) ferromagnetic-like and (4) superparamagnetic contributions from Fe-containing particles detected in spatially resolved energy-dispersive spectroscopy. Contributions (1) and (2) are intrinsic to nanodiamond, while contributions (3) and (4) arise from impurities naturally present in detonation nanodiamond samples. {sup 13}C NMR T{sub 1,c} relaxation would be unaffected by the presence of the ferromagnetic particles with the bulk magnetization of {approx} 0.01 emu/g at 300 K. Thus, a reduction of T{sub 1,c} by 3 orders of magnitude compared to natural and synthetic microdiamonds confirms the presence of unpaired electrons in the nanodiamond grains. The spin concentration in nanodiamond powder corresponds to {approx}30 unpaired electrons per {approx}4.6 nm diameter nanodiamond grain.

  12. Method of making supercritical fluid molecular spray films, powder and fibers

    DOE Patents [OSTI]

    Smith, Richard D.

    1988-01-01

    Solid films are deposited, or fine powders formed, by dissolving a solid material into a supercritical fluid solution at an elevated pressure and then rapidly expanding the solution through a heated nozzle having a short orifice into a region of relatively low pressure. This produces a molecular spray which is directed against a substrate to deposit a solid thin film thereon, or discharged into a collection chamber to collect a fine powder. In another embodiment, the temperature of the solution and nozzle is elevated above the melting point of the solute, which is preferably a polymer, and the solution is maintained at a pressure such that, during expansion, the solute precipitates out of solution within the nozzle in a liquid state. Alternatively, a secondary solvent mutually soluble with the solute and primary solvent and having a higher critical temperature than that of primary solvent is used in a low concentration (<20%) to maintain the solute in a transient liquid state. The solute is discharged in the form of long, thin fibers. The fibers are collected at sufficient distance from the orifice to allow them to solidify in the low pressure/temperature region.

  13. Nuclear forensic analysis of uranium oxide powders interdicted in Victoria, Australia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kristo, Michael Joseph; Keegan, Elizabeth; Colella, Michael; Williams, Ross; Lindvall, Rachel; Eppich, Gary; Roberts, Sarah; Borg, Lars; Gaffney, Amy; Plaue, Jonathan; et al

    2015-04-13

    Nuclear forensic analysis was conducted on two uranium samples confiscated during a police investigation in Victoria, Australia. The first sample, designated NSR-F-270409-1, was a depleted uranium powder of moderate purity (~1000 μg/g total elemental impurities). The chemical form of the uranium was a compound similar to K2(UO2)3O4·4H2O. While aliquoting NSR-F-270409-1 for analysis, the body and head of a Tineid moth was discovered in the sample. The second sample, designated NSR-F-270409-2, was also a depleted uranium powder. It was of reasonably high purity (~380 μg/g total elemental impurities). The chemical form of the uranium was primarily UO3·2H2O, with minor phases ofmore » U3O8 and UO2. While aliquoting NSR-F-270409-2 for analysis, a metal staple of unknown origin was discovered in the sample. The presence of 236U and 232U in both samples indicates that the uranium feed stocks for these samples experienced a neutron flux at some point in their history. The reactor burn-up calculated from the isotopic composition of the uranium is consistent with that of spent fuel from natural uranium (NU) fueled Pu production. These nuclear forensic conclusions allow us to categorically exclude Australia as the origin of the material and greatly reduce the number of candidate sources.« less

  14. Uranium silicide pellet fabrication by powder metallurgy for accident tolerant fuel evaluation and irradiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harp, Jason Michael; Lessing, Paul Alan; Hoggan, Rita Elaine

    2015-06-21

    In collaboration with industry, Idaho National Laboratory is investigating uranium silicide for use in future light water reactor fuels as a more accident resistant alternative to uranium oxide base fuels. Specifically this project was focused on producing uranium silicide (U3Si2) pellets by conventional powder metallurgy with a density greater than 94% of the theoretical density. This work has produced a process to consistently produce pellets with the desired density through careful optimization of the process. Milling of the U3Si2 has been optimized and high phase purity U3Si2 has been successfully produced. Results are presented from sintering studies and microstructural examinationsmore » that illustrate the need for a finely ground reproducible particle size distribution in the source powder. The optimized process was used to produce pellets for the Accident Tolerant Fuel-1 irradiation experiment. The average density of these pellets was 11.54 ±0.06 g/cm3. Additional characterization of the pellets by scaning electron microscopy and X-ray diffraction has also been performed. As a result, pellets produced in this work have been encapsulated for irradiation, and irradiation in the Advanced Test Reactor is expected soon.« less

  15. Uranium silicide pellet fabrication by powder metallurgy for accident tolerant fuel evaluation and irradiation

    SciTech Connect (OSTI)

    Harp, Jason Michael; Lessing, Paul Alan; Hoggan, Rita Elaine

    2015-06-21

    In collaboration with industry, Idaho National Laboratory is investigating uranium silicide for use in future light water reactor fuels as a more accident resistant alternative to uranium oxide base fuels. Specifically this project was focused on producing uranium silicide (U3Si2) pellets by conventional powder metallurgy with a density greater than 94% of the theoretical density. This work has produced a process to consistently produce pellets with the desired density through careful optimization of the process. Milling of the U3Si2 has been optimized and high phase purity U3Si2 has been successfully produced. Results are presented from sintering studies and microstructural examinations that illustrate the need for a finely ground reproducible particle size distribution in the source powder. The optimized process was used to produce pellets for the Accident Tolerant Fuel-1 irradiation experiment. The average density of these pellets was 11.54 ±0.06 g/cm3. Additional characterization of the pellets by scaning electron microscopy and X-ray diffraction has also been performed. As a result, pellets produced in this work have been encapsulated for irradiation, and irradiation in the Advanced Test Reactor is expected soon.

  16. Production of Diesel Engine Turbocharger Turbine from Low Cost Titanium Powder

    SciTech Connect (OSTI)

    Muth, T. R.; Mayer, R.

    2012-05-04

    Turbochargers in commercial turbo-diesel engines are multi-material systems where usually the compressor rotor is made of aluminum or titanium based material and the turbine rotor is made of either a nickel based superalloy or titanium, designed to operate under the harsh exhaust gas conditions. The use of cast titanium in the turbine section has been used by Cummins Turbo Technologies since 1997. Having the benefit of a lower mass than the superalloy based turbines; higher turbine speeds in a more compact design can be achieved with titanium. In an effort to improve the cost model, and develop an industrial supply of titanium componentry that is more stable than the traditional aerospace based supply chain, the Contractor has developed component manufacturing schemes that use economical Armstrong titanium and titanium alloy powders and MgR-HDH powders. Those manufacturing schemes can be applied to compressor and turbine rotor components for diesel engine applications with the potential of providing a reliable supply of titanium componentry with a cost and performance advantage over cast titanium.

  17. Niobium-titanium superconductors produced by powder metallurgy having artificial flux pinning centers

    DOE Patents [OSTI]

    Jablonski, Paul D. (Madison, WI); Larbalestier, David C. (Madison, WI)

    1993-01-01

    Superconductors formed by powder metallurgy have a matrix of niobium-titanium alloy with discrete pinning centers distributed therein which are formed of a compatible metal. The artificial pinning centers in the Nb-Ti matrix are reduced in size by processing steps to sizes on the order of the coherence length, typically in the range of 1 to 10 nm. To produce the superconductor, powders of body centered cubic Nb-Ti alloy and the second phase flux pinning material, such as Nb, are mixed in the desired percentages. The mixture is then isostatically pressed, sintered at a selected temperature and selected time to produce a cohesive structure having desired characteristics without undue chemical reaction, the sintered billet is reduced in size by deformation, such as by swaging, the swaged sample receives heat treatment and recrystallization and additional swaging, if necessary, and is then sheathed in a normal conducting sheath, and the sheathed material is drawn into a wire. The resulting superconducting wire has second phase flux pinning centers distributed therein which provide enhanced J.sub.ct due to the flux pinning effects.

  18. Early anisotropic hydrodynamics and thermalization and Hanbury-Brown-Twiss puzzles in the BNL Relativistic Heavy Ion Collider (RHIC)

    SciTech Connect (OSTI)

    Ryblewski, Radoslaw; Florkowski, Wojciech

    2010-08-15

    We address the problem of whether the early thermalization and Hanbury-Brown-Twiss (HBT) puzzles in relativistic heavy-ion collisions may be solved by the assumption that the early dynamics of the produced matter is locally anisotropic. The hybrid model describing the purely transverse hydrodynamic evolution followed by the perfect-fluid hydrodynamic stage is constructed. The transition from the transverse to perfect-fluid hydrodynamics is described by the Landau matching conditions applied at a fixed proper time {tau}{sub tr}. The global fit to the RHIC data reproduces the soft hadronic observables (the pion, kaon, and the proton spectra, the pion and kaon elliptic flow, and the pion HBT radii) with the accuracy of about 20%. These results indicate that the assumption of the very fast thermalization may be relaxed. In addition, the presented model suggests that a large part of the inconsistencies between the theoretical and experimental HBT results may be removed.

  19. Applications of the RELAP5 code to the station blackout transients at the Browns Ferry Unit One Plant

    SciTech Connect (OSTI)

    Schultz, R.R.; Wagoner, S.R.

    1983-01-01

    As a part of the charter of the Severe Accident Sequence Analysis (SASA) Program, station blackout transients have been analyzed using a RELAP5 model of the Browns Ferry Unit 1 Plant. The task was conducted as a partial fulfillment of the needs of the US Nuclear Regulatory Commission in examining the Unresolved Safety Issue A-44: Station Blackout (1) the station blackout transients were examined (a) to define the equipment needed to maintain a well cooled core, (b) to determine when core uncovery would occur given equipment failure, and (c) to characterize the behavior of the vessel thermal-hydraulics during the station blackout transients (in part as the plant operator would see it). These items are discussed in the paper. Conclusions and observations specific to the station blackout are presented.

  20. X-Ray Powder Diffraction Study of Synthetic Palmierite, K{sub 2}Pb(SO{sub 4}){sub 2}

    SciTech Connect (OSTI)

    TISSOT JR.,RALPH G.; RODRIGUEZ,MARK A.; SIPOLA,DIANA L.; VOIGT,JAMES A.

    2000-12-19

    Palmierite (K{sub 2}Pb(SO{sub 4}){sub 2}) has been prepared via a chemical synthesis method. Intensity differences were observed when X-ray powder data from the newly synthesized compound were compared to the published powder diffraction card (PDF) 29-1015 for Palmierite. Investigation of these differences indicated the possibility of preferred orientation and/or chemical inhomogeneity affecting intensities, particularly those of the basal (00{ell}) reflections. Annealing of the Palmierite was found to reduce the effects of preferred orientation. Electron microprobe analysis confirmed K:Pb:S as 2:1:2 for the annealed Palmierite powder. Subsequent least-squares refinement and Rietveld analysis of the annealed powder showed peak intensities very close to that of a calculated Palmierite pattern (based on single crystal data), yet substantially higher than many of the PDF 29-1015 published intensities. Further investigation of peak intensity variation via calculated patterns suggested that the intensity discrepancies between the annealed sample and those found in PDF 29-1015 were potentially due to chemical variation in the K{sub 2}Pb(SO{sub 4}){sub 2} composition. X-ray powder diffraction and crystal data for Palmierite are reported for the annealed sample. Palmierite is Trigonal/Hexagonal with unit cell parameters a = 5.497(1){angstrom}, c = 20.864(2) {angstrom}, space group R-3m (166), and Z = 3.

  1. Optical photon transport in powdered-phosphor scintillators. Part II. Calculation of single-scattering transport parameters

    SciTech Connect (OSTI)

    Poludniowski, Gavin G.; Evans, Philip M.

    2013-04-15

    Purpose: Monte Carlo methods based on the Boltzmann transport equation (BTE) have previously been used to model light transport in powdered-phosphor scintillator screens. Physically motivated guesses or, alternatively, the complexities of Mie theory have been used by some authors to provide the necessary inputs of transport parameters. The purpose of Part II of this work is to: (i) validate predictions of modulation transform function (MTF) using the BTE and calculated values of transport parameters, against experimental data published for two Gd{sub 2}O{sub 2}S:Tb screens; (ii) investigate the impact of size-distribution and emission spectrum on Mie predictions of transport parameters; (iii) suggest simpler and novel geometrical optics-based models for these parameters and compare to the predictions of Mie theory. A computer code package called phsphr is made available that allows the MTF predictions for the screens modeled to be reproduced and novel screens to be simulated. Methods: The transport parameters of interest are the scattering efficiency (Q{sub sct}), absorption efficiency (Q{sub abs}), and the scatter anisotropy (g). Calculations of these parameters are made using the analytic method of Mie theory, for spherical grains of radii 0.1-5.0 {mu}m. The sensitivity of the transport parameters to emission wavelength is investigated using an emission spectrum representative of that of Gd{sub 2}O{sub 2}S:Tb. The impact of a grain-size distribution in the screen on the parameters is investigated using a Gaussian size-distribution ({sigma}= 1%, 5%, or 10% of mean radius). Two simple and novel alternative models to Mie theory are suggested: a geometrical optics and diffraction model (GODM) and an extension of this (GODM+). Comparisons to measured MTF are made for two commercial screens: Lanex Fast Back and Lanex Fast Front (Eastman Kodak Company, Inc.). Results: The Mie theory predictions of transport parameters were shown to be highly sensitive to both grain size and emission wavelength. For a phosphor screen structure with a distribution in grain sizes and a spectrum of emission, only the average trend of Mie theory is likely to be important. This average behavior is well predicted by the more sophisticated of the geometrical optics models (GODM+) and in approximate agreement for the simplest (GODM). The root-mean-square differences obtained between predicted MTF and experimental measurements, using all three models (GODM, GODM+, Mie), were within 0.03 for both Lanex screens in all cases. This is excellent agreement in view of the uncertainties in screen composition and optical properties. Conclusions: If Mie theory is used for calculating transport parameters for light scattering and absorption in powdered-phosphor screens, care should be taken to average out the fine-structure in the parameter predictions. However, for visible emission wavelengths ({lambda} < 1.0 {mu}m) and grain radii (a > 0.5 {mu}m), geometrical optics models for transport parameters are an alternative to Mie theory. These geometrical optics models are simpler and lead to no substantial loss in accuracy.

  2. A Fully Coupled Simulation and Optimization Scheme for the Design of 3D Powder Injection Molding Processes

    SciTech Connect (OSTI)

    Ayad, G.; Barriere, T.; Gelin, J. C. [Femto-ST Institute/LMA, ENSMM, 26 Rue de l'Epitaphe, 25000 Besancon (France); Song, J. [Femto-ST Institute/LMA, ENSMM, 26 Rue de l'Epitaphe, 25000 Besancon (France); Department of Applied Mechanics and Engineering, Southwest Jiaotong University, 610031 Chengdu (China); Liu, B. [Department of Applied Mechanics and Engineering, Southwest Jiaotong University, 610031 Chengdu (China)

    2007-05-17

    The paper is concerned with optimization and parametric identification of Powder Injection Molding process that consists first in injection of powder mixture with polymer binder and then to the sintering of the resulting powders parts by solid state diffusion. In the first part, one describes an original methodology to optimize the injection stage based on the combination of Design Of Experiments and an adaptive Response Surface Modeling. Then the second part of the paper describes the identification strategy that one proposes for the sintering stage, using the identification of sintering parameters from dilatometer curves followed by the optimization of the sintering process. The proposed approaches are applied to the optimization for manufacturing of a ceramic femoral implant. One demonstrates that the proposed approach give satisfactory results.

  3. Variation of the shape and morphological properties of silica and metal oxide powders by electro homogeneous precipitation

    DOE Patents [OSTI]

    Harris, Michael T. (Knoxville, TN); Basaran, Osman A. (Oak Ridge, TN); Sisson, Warren G. (Oak Ridge, TN); Brunson, Ronald R. (Lenoir City, TN)

    1997-01-01

    The present invention provides a method for preparing irreversible linear aggregates (fibrils) of metal oxide powders by utilizing static or pulsed DC electrical fields across a relatively non-conducting liquid solvent in which organometal compounds or silicon alkoxides have been dissolved. The electric field is applied to the relatively non-conducting solution throughout the particle formation and growth process promoting the formation of either linear aggregates (fibrils) or spherical shaped particles as desired. Thus the present invention provides a physical method for altering the size, shape and porosity of precursor hydrous metal oxide or hydrous silicon oxide powders for the development of advanced ceramics with improved strength and insulating capacity.

  4. Powder processing for the fabrication of Si{sub 3}N{sub 4} ceramics. 1: Influence of spray-dried granule strength on pore size distribution in green compacts

    SciTech Connect (OSTI)

    Kamiya, Hidehiro; Isomura, Kenji; Jimbo, Genji; Junichiro, Tsubaki

    1995-01-01

    The effect of spray-dried granule strength on the microstructure of green compacts obtained by isostatic pressing was quantitatively analyzed. The fracture strength of single granules of Si{sub 3}N{sub 4} powder made with ultrafine Al{sub 2}O{sub 3} and Y{sub 2}O{sub 3} powders was measured directly by diametral compression. It was found that fracture strength increased notably with the increasing relative density of the granule and the decreasing size of agglomerates in suspension before spray-drying. Even when green bodies were prepared at an isostatic pressure of 200 MPa, intergranular pores, which negatively affected densification of the sintered bodies, occurred between unfractured granules. The volume and size of these pores in the green compacts increased with the increasing fracture strength of the granules. In the case of closely packed granules, an isostatic pressure of 800 MPa was required to completely collapse the intergranular pores. A simple equation was derived to calculate the isostatic pressure necessary for complete collapse of intergranular pores in the green compacts, and it was determined that granule strength must be kept as low as possible to obtain uniform green compacts.

  5. Sol-gel preparation of lead magnesium niobate (PMN) powders and thin films

    DOE Patents [OSTI]

    Boyle, T.J.

    1999-01-12

    A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films. 3 figs.

  6. Kinetics of Methane Hydrate Decomposition Studied via in Situ Low Temperature X-ray Powder Diffraction

    SciTech Connect (OSTI)

    Everett, Susan M; Rawn, Claudia J; Keffer, David J.; Mull, Derek L; Payzant, E Andrew; Phelps, Tommy Joe

    2013-01-01

    Gas hydrates are known to have a slowed decomposition rate at ambient pressure and temperatures below the melting point of ice termed self-preservation or anomalous preservation. As hydrate exothermically decomposes, gas is released and water of the clathrate cages transforms into ice. Two regions of slowed decomposition for methane hydrate, 180 200 K and 230 260 K, were observed, and the kinetics were studied by in situ low temperature x-ray powder diffraction. The kinetic constants for ice formation from methane hydrate were determined by the Avrami model within each region and activation energies, Ea, were determined by the Arrhenius plot. Ea determined from the data for 180 200 K was 42 kJ/mol and for 230 260 K was 22 kJ/mol. The higher Ea in the colder temperature range was attributed to a difference in the microstructure of ice between the two regions.

  7. Novel pre-alloyed powder processing of modified alnico 8: Correlation of microstructure and magnetic properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Anderson, I. E.; Kassen, A. G.; White, E. M. H.; Zhou, L.; Tang, W.; Palasyuk, A.; Dennis, K. W.; McCallum, R. W.; Kramer, M. J.

    2015-04-13

    Progress is reviewed on development of an improved near-final bulk magnet fabrication process for alnico 8, as a non-rare earth permanent magnet with promise for sufficient energy density and coercivity for electric drive motors. This study showed that alnico bulk magnets in near-final shape can be made by simple compression molding from spherical high purity gas atomized pre-alloyed powder. Dwell time at peak sintering temperature (1250°C) greatly affected grain size of the resulting magnet alloys. This microstructure transformation was demonstrated to be useful for gaining partially aligned magnetic properties and boosting energy product. While a route to increased coercivity wasmore » not identified by these experiments, manufacturability of bulk alnico magnet alloys in near-final shapes was demonstrated, permitting further processing and alloy modification experiments that can target higher coercivity and better control of grain anisotropy during grain growth.« less

  8. New alnico magnets fabricated from pre-alloyed gas-atomized powder through diverse consolidation techniques

    SciTech Connect (OSTI)

    Tang, W.; Zhou, L.; Kassen, A. G.; Palasyuk, A.; White, E. M.; Dennis, K. W.; Kramer, M. J.; McCallum, R. W.; Anderson, I. E.

    2015-05-25

    Fine Alnico 8 spherical powder produced by gas atomization was consolidated through hot pressing (HP), hot isostatic pressing (HIP), and compression molding and subsequent sintering (CMS) techniques. The effects of different fabrication techniques and processing parameters on microstructure and magnetic properties were analyzed and compared. The HP, HIP, and CMS magnets exhibited different features in microstructures and magnetic properties. Magnetically annealed at 840°C for 10 min and subsequently tempered at 650°C for 5h and 580°C for 15h, the HIP sample achieved the best coercivity (Hcj =1845 Oe) due to spinodally decomposed (SD) phases with uniform and well-faceted mosaic morphology. As a result, the CMS sample had a lower Hcj than HIP and HP samples, but a higher remanence and thus the best energy product (6.5 MGOe) due to preferential grain alignment induced by abnormal grain growth.

  9. Novel pre-alloyed powder processing of modified alnico 8: Correlation of microstructure and magnetic properties

    SciTech Connect (OSTI)

    Anderson, I. E.; Kassen, A. G.; White, E. M. H.; Zhou, L.; Tang, W.; Palasyuk, A.; Dennis, K. W.; McCallum, R. W.; Kramer, M. J.

    2015-04-13

    Progress is reviewed on development of an improved near-final bulk magnet fabrication process for alnico 8, as a non-rare earth permanent magnet with promise for sufficient energy density and coercivity for electric drive motors. This study showed that alnico bulk magnets in near-final shape can be made by simple compression molding from spherical high purity gas atomized pre-alloyed powder. Dwell time at peak sintering temperature (1250°C) greatly affected grain size of the resulting magnet alloys. This microstructure transformation was demonstrated to be useful for gaining partially aligned magnetic properties and boosting energy product. While a route to increased coercivity was not identified by these experiments, manufacturability of bulk alnico magnet alloys in near-final shapes was demonstrated, permitting further processing and alloy modification experiments that can target higher coercivity and better control of grain anisotropy during grain growth.

  10. Scale-up of Lithium Aluminate Pellet Manufacturing with a Flowable Powder

    SciTech Connect (OSTI)

    Hollenberg, Glenn W.; Bagaasen, Larry M.; Kurosky, Randal P.; Tonn, D.; Carty, W.

    2004-01-01

    Thin-walled, high-density lithium aluminate pellets are challenging to manufacture for nuclear reactor applications. The key to scale-up of production was the development of flowable, high density, lithium aluminate powder that permitted (1) automated isostatic pressing, (2) low compaction during pressing, (3) low shrinkage during firing, (4) elimination of chlorine-containing fumed alumina and (5) near-net shape forming. A triple spray drying process was developed that included: (I) a unique-feedstock blend cycle, (II) a post-calcination grinding cycle, and (III) a high-pH final cycle with high solids loading slurry that was spray dried into flowable high-density spheres with large, uniform diameters. Today, pellet manufacturing at a rate of more than 400,000 per year is possible.

  11. New alnico magnets fabricated from pre-alloyed gas-atomized powder through diverse consolidation techniques

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tang, W.; Zhou, L.; Kassen, A. G.; Palasyuk, A.; White, E. M.; Dennis, K. W.; Kramer, M. J.; McCallum, R. W.; Anderson, I. E.

    2015-05-25

    Fine Alnico 8 spherical powder produced by gas atomization was consolidated through hot pressing (HP), hot isostatic pressing (HIP), and compression molding and subsequent sintering (CMS) techniques. The effects of different fabrication techniques and processing parameters on microstructure and magnetic properties were analyzed and compared. The HP, HIP, and CMS magnets exhibited different features in microstructures and magnetic properties. Magnetically annealed at 840°C for 10 min and subsequently tempered at 650°C for 5h and 580°C for 15h, the HIP sample achieved the best coercivity (Hcj =1845 Oe) due to spinodally decomposed (SD) phases with uniform and well-faceted mosaic morphology. Asmore » a result, the CMS sample had a lower Hcj than HIP and HP samples, but a higher remanence and thus the best energy product (6.5 MGOe) due to preferential grain alignment induced by abnormal grain growth.« less

  12. Nanocrystalline BaTiO3 powder via ambient conditions sol process (Prop.2001-071)

    SciTech Connect (OSTI)

    Payzant, E Andrew; Wang, X.; Hu, Michael Z.; Blom, Douglas Allen

    2005-01-01

    Nanocrystalline BaTiO{sub 3} particles have been prepared by ambient condition sol (ACS) process starting from soluble precursors of barium and titanium yielding a mixed oxide/hydroxide gel. The gel was peptized and crystallized in water under a refluxing condition. Higher initial pH and Ba/Ti ratio led to smaller crystallite sizes of BaTiO{sub 3} powders. Organic mineralizer, tetramethylammonium hydroxide (TMAH), can adsorb on the BaTiO{sub 3} nuclei and inhibited further growth of the particles. Adding a polymer during BaTiO{sub 3} synthesis led to a smaller particle size and increased redispersibility of the particles in water.

  13. Powder River Basin Coalbed Methane Development and Produced Water Management Study

    SciTech Connect (OSTI)

    Advanced Resources International

    2002-11-30

    Coalbed methane resources throughout the entire Powder River Basin were reviewed in this analysis. The study was conducted at the township level, and as with all assessments conducted at such a broad level, readers must recognize and understand the limitations and appropriate use of the results. Raw and derived data provided in this report will not generally apply to any specific location. The coal geology in the basin is complex, which makes correlation with individual seams difficult at times. Although more than 12,000 wells have been drilled to date, large areas of the Powder River Basin remain relatively undeveloped. The lack of data obviously introduces uncertainty and increases variability. Proxies and analogs were used in the analysis out of necessity, though these were always based on sound reasoning. Future development in the basin will make new data and interpretations available, which will lead to a more complete description of the coals and their fluid flow properties, and refined estimates of natural gas and water production rates and cumulative recoveries. Throughout the course of the study, critical data assumptions and relationships regarding gas content, methane adsorption isotherms, and reservoir pressure were the topics of much discussion with reviewers. A summary of these discussion topics is provided as an appendix. Water influx was not modeled although it is acknowledged that this phenomenon may occur in some settings. As with any resource assessment, technical and economic results are the product of the assumptions and methodology used. In this study, key assumptions as well as cost and price data, and economic parameters are presented to fully inform readers. Note that many quantities shown in various tables have been subject to rounding; therefore, aggregation of basic and intermediate quantities may differ from the values shown.

  14. Nuclear forensic analysis of uranium oxide powders interdicted in Victoria, Australia

    SciTech Connect (OSTI)

    Kristo, Michael Joseph; Keegan, Elizabeth; Colella, Michael; Williams, Ross; Lindvall, Rachel; Eppich, Gary; Roberts, Sarah; Borg, Lars; Gaffney, Amy; Plaue, Jonathan; Knight, Kim; Loi, Elaine; Hotchkis, Michael; Moody, Kenton; Singleton, Michael; Robel, Martin; Hutcheon, Ian

    2015-04-13

    Nuclear forensic analysis was conducted on two uranium samples confiscated during a police investigation in Victoria, Australia. The first sample, designated NSR-F-270409-1, was a depleted uranium powder of moderate purity (~1000 μg/g total elemental impurities). The chemical form of the uranium was a compound similar to K2(UO2)3O4·4H2O. While aliquoting NSR-F-270409-1 for analysis, the body and head of a Tineid moth was discovered in the sample. The second sample, designated NSR-F-270409-2, was also a depleted uranium powder. It was of reasonably high purity (~380 μg/g total elemental impurities). The chemical form of the uranium was primarily UO3·2H2O, with minor phases of U3O8 and UO2. While aliquoting NSR-F-270409-2 for analysis, a metal staple of unknown origin was discovered in the sample. The presence of 236U and 232U in both samples indicates that the uranium feed stocks for these samples experienced a neutron flux at some point in their history. The reactor burn-up calculated from the isotopic composition of the uranium is consistent with that of spent fuel from natural uranium (NU) fueled Pu production. These nuclear forensic conclusions allow us to categorically exclude Australia as the origin of the material and greatly reduce the number of candidate sources.

  15. Hydrothermal synthesis and characteristics of anions-doped calcium molybdate red powder phosphors

    SciTech Connect (OSTI)

    Shi, Shikao; Zhang, Yan; Liu, Qing; Zhou, Ji

    2013-10-15

    Graphical abstract: - Highlights: • Four anion-doped CaMoO{sub 4}:Eu{sup 3+} red phosphors were prepared by hydrothermal approach. • Some samples exhibit nearly spherical morphology and well-distributed fine particles. • The red luminescence can be obviously enhanced after certain amount of anion doping. • The improved phosphor system is a potential candidate for white LED applications. - Abstract: Applying hydrothermal and subsequent heat-treatment process, CaMoO{sub 4}:Eu{sup 3+} was doped with four anions (SiO{sub 3}{sup 2?}, PO{sub 4}{sup 3?}, SO{sub 4}{sup 2?} and ClO{sub 3}{sup ?}) to prepare fine red powder phosphors. The introduction of small amount of anions into the host had little influence on the structure, which was confirmed by X-ray diffraction patterns. The anion-doped phosphor samples (except SiO{sub 3}{sup 2?}) exhibited nearly spherical morphology, and the particle sizes were in the range of 0.3–0.4 ?m for SO{sub 4}{sup 2?}-doped samples, and 0.8–1.2 ?m for PO{sub 4}{sup 3?} and ClO{sub 3}{sup ?}-doped samples. Excited with 395 nm near-UV light, all samples showed typical Eu{sup 3+} red emission at 615 nm, and PO{sub 4}{sup 3?}, SO{sub 4}{sup 2?} and ClO{sub 3}{sup ?}-doped samples enhanced the red luminescence as compared with the individual CaMoO{sub 4}:Eu{sup 3+} sample. In particular, relative emission intensity for optimum ClO{sub 3}{sup ?}-doped phosphors reached more than 6-fold that of the commercial red phosphor, which is highly desirable for the powder phosphors used in the solid-state lighting industry.

  16. Powder Metallurgy of Uranium Alloy Fuels for TRU-Burning Reactors Final Technical Report

    SciTech Connect (OSTI)

    Sean M. McDeavitt

    2011-04-29

    Overview Fast reactors were evaluated to enable the transmutation of transuranic isotopes generated by nuclear energy systems. The motivation for this was that TRU isotopes have high radiotoxicity and relatively long half-lives, making them unattractive for disposal in a long-term geologic repository. Fast reactors provide an efficient means to utilize the energy content of the TRUs while destroying them. An enabling technology that requires research and development is the fabrication metallic fuel containing TRU isotopes using powder metallurgy methods. This project focused upon developing a powder metallurgical fabrication method to produce U-Zr-transuranic (TRU) alloys at relatively low processing temperatures (500ºC to 600ºC) using either hot extrusion or alpha-phase sintering for charecterization. Researchers quantified the fundamental aspects of both processing methods using surrogate metals to simulate the TRU elements. The process produced novel solutions to some of the issues relating to metallic fuels, such as fuel-cladding chemical interactions, fuel swelling, volatility losses during casting, and casting mold material losses. Workscope There were two primary tasks associated with this project: 1. Hot working fabrication using mechanical alloying and extrusion • Design, fabricate, and assemble extrusion equipment • Extrusion database on DU metal • Extrusion database on U-10Zr alloys • Extrusion database on U-20xx-10Zr alloys • Evaluation and testing of tube sheath metals 2. Low-temperature sintering of U alloys • Design, fabricate, and assemble equipment • Sintering database on DU metal • Sintering database on U-10Zr alloys • Liquid assisted phase sintering on U-20xx-10Zr alloys Appendices Outline Appendix A contains a Fuel Cycle Research & Development (FCR&D) poster and contact presentation where TAMU made primary contributions. Appendix B contains MSNE theses and final defense presentations by David Garnetti and Grant Helmreich outlining the beginning of the materials processing setup. Also included within this section is a thesis proposal by Jeff Hausaman. Appendix C contains the public papers and presentations introduced at the 2010 American Nuclear Society Winter Meeting. Appendix A—MSNE theses of David Garnetti and Grant Helmreich and proposal by Jeff Hausaman A.1 December 2009 Thesis by David Garnetti entitled “Uranium Powder Production Via Hydride Formation and Alpha Phase Sintering of Uranium and Uranium-Zirconium Alloys for Advanced Nuclear Fuel Applications” A.2 September 2009 Presentation by David Garnetti (same title as document in Appendix B.1) A.3 December 2010 Thesis by Grant Helmreich entitled “Characterization of Alpha-Phase Sintering of Uranium and Uranium-Zirconium Alloys for Advanced Nuclear Fuel Applications” A.4 October 2010 Presentation by Grant Helmreich (same title as document in Appendix B.3) A.5 Thesis Proposal by Jeffrey Hausaman entitled “Hot Extrusion of Alpha Phase Uranium-Zirconium Alloys for TRU Burning Fast Reactors” Appendix B—External presentations introduced at the 2010 ANS Winter Meeting B.1 J.S. Hausaman, D.J. Garnetti, and S.M. McDeavitt, “Powder Metallurgy of Alpha Phase Uranium Alloys for TRU Burning Fast Reactors,” Proceedings of 2010 ANS Winter Meeting, Las Vegas, Nevada, USA, November 7-10, 2010 B.2 PowerPoint Presentation Slides from C.1 B.3 G.W. Helmreich, W.J. Sames, D.J. Garnetti, and S.M. McDeavitt, “Uranium Powder Production Using a Hydride-Dehydride Process,” Proceedings of 2010 ANS Winter Meeting, Las Vegas, Nevada, USA, November 7-10, 2010 B.4. PowerPoint Presentation Slides from C.3 B.5 Poster Presentation from C.3 Appendix C—Fuel cycle research and development undergraduate materials and poster presentation C.1 Poster entitled “Characterization of Alpha-Phase Sintering of Uranium and Uranium-Zirconium Alloys” presented at the Fuel Cycle Technologies Program Annual Meeting C.2 April 2011 Honors Undergraduate Thesis by William Sames, Research Fellow, entitled “Uranium Metal Powder Production, Particle Distribution Analysis, and Reaction Rate Studies of a Hydride-Dehydride Process” ?

  17. T-707: Apache Tomcat AJP Protocol Processing Bug Lets Remote Users Bypass Authentication or Obtain Information

    Broader source: Energy.gov [DOE]

    Apache Tomcat AJP protocol processing bug lets remote users bypass authentication or obtain information.

  18. Discerning Viable from Nonviable Yersinia pestis pgm- and Bacillus anthracis Sterne using Propidium Monoazide in the Presence of White Powders

    SciTech Connect (OSTI)

    Hess, Becky M.; Kaiser, Brooke LD; Sydor, Michael A.; Wunschel, David S.; Bruckner-Lea, Cindy J.; Hutchison, Janine R.

    2015-12-23

    ABSTRACT Aims To develop and optimize an assay to determine viability status of Bacillus anthracis Sterne and Yersinia pestis pgm- strains in the presence of white powders by coupling propidium monoazide (PMA) treatment with real-time PCR (qPCR) analysis. Methods and Results PMA selectively enters nonviable cells and binds DNA, thereby increasing qPCR assay cycle threshold (CT) values compared to untreated samples. Dye concentration, cell number and fitness, incubation time, inactivation methods, and assay buffer were optimized for B. anthracis Sterne and Y. pestis pgm-. Differences in CT values in nonviable cells compared to untreated samples were consistently > 9 for both B. anthracis Sterne vegetative cells and Y. pestis pgm- in the presence and absence of three different white powders. Our method eliminates the need for a DNA extraction step prior to detection by qPCR. Conclusions The developed assay enables simultaneous identification and viability assessment for B. anthracis Sterne and Y. pestis pgm- under laboratory conditions, even in the presence of white powders. Eliminating the DNA extraction step that is typically used reduces total assay time and labor requirements for sample analysis. Significance and Impact of the Study The method developed for simultaneous detection and viability assessment for B. anthracis and Y. pestis can be employed in forming decisions about the severity of a biothreat event or the safety of food. Keywords Bacillus anthracis, Yersinia pestis, Propidium Monoazide, qPCR, White Powders, Rapid Viability Detection

  19. Fabrication of TiO{sub 2} Thick Film for Photocatalyst from Commercial TiO{sub 2} Powder

    SciTech Connect (OSTI)

    Asteti, S. Fuji; Syarif, D. Gustaman

    2008-03-17

    Photocatalytic activity of TiO{sub 2} thick film ceramics made of commercial TiO{sub 2} powder has been studied. The TiO{sub 2} powder was nano sized one that was derived from dried TiO{sub 2} suspension. The TiO{sub 2} suspension was made by pouring some blended commercial TiO{sub 2} powder into some amount of water. The paste of TiO{sub 2} was made by mixing the nano sized TiO{sub 2} powder with organic vehicle and glass frit. The paste was spread on a glass substrate. The paste was dried at 100 deg. C and heated at different temperatures (400 deg. C and 500 deg. C) for 60 minutes to produce thick film ceramics. The photocatalytic activity of these films was evaluated by measuring the concentration of a solution of methylene blue where the thick films were inside after being illuminated by UV light at various periods of times. The initial concentration of the methylene blue solution was 5 ppm. Structural analyses were carried out by X-ray diffraction (XRD). The XRD analyses showed that the produced thick film ceramic had mainly crystal structure of anatase. According to the photocatalytical data, it was known that the produced thick film ceramics were photocatalyst which were capable of decomposing an organic compound such as the methylene blue.

  20. Oral administration of drugs with hypersensitivity potential induces germinal center hyperplasia in secondary lymphoid organ/tissue in Brown Norway rats, and this histological lesion is a promising candidate as a predictive biomarker for drug hypersensitivity occurrence in humans

    SciTech Connect (OSTI)

    Tamura, Akitoshi Miyawaki, Izuru; Yamada, Toru; Kimura, Juki; Funabashi, Hitoshi

    2013-08-15

    It is important to evaluate the potential of drug hypersensitivity as well as other adverse effects during the preclinical stage of the drug development process, but validated methods are not available yet. In the present study we examined whether it would be possible to develop a new predictive model of drug hypersensitivity using Brown Norway (BN) rats. As representative drugs with hypersensitivity potential in humans, phenytoin (PHT), carbamazepine (CBZ), amoxicillin (AMX), and sulfamethoxazole (SMX) were orally administered to BN rats for 28 days to investigate their effects on these animals by examinations including observation of clinical signs, hematology, determination of serum IgE levels, histology, and flow cytometric analysis. Skin rashes were not observed in any animals treated with these drugs. Increases in the number of circulating inflammatory cells and serum IgE level did not necessarily occur in the animals treated with these drugs. However, histological examination revealed that germinal center hyperplasia was commonly induced in secondary lymphoid organs/tissues in the animals treated with these drugs. In cytometric analysis, changes in proportions of lymphocyte subsets were noted in the spleen of the animals treated with PHT or CBZ during the early period of administration. The results indicated that the potential of drug hypersensitivity was identified in BN rat by performing histological examination of secondary lymphoid organs/tissues. Data obtained herein suggested that drugs with hypersensitivity potential in humans gained immune reactivity in BN rat, and the germinal center hyperplasia induced by administration of these drugs may serve as a predictive biomarker for drug hypersensitivity occurrence. - Highlights: • We tested Brown Norway rats as a candidate model for predicting drug hypersensitivity. • The allergic drugs did not induce skin rash, whereas D-penicillamine did so in the rats. • Some of allergic drugs increased inflammatory cells and IgE, but the others did not. • The allergic drugs commonly induced germinal center hyperplasia in lymphoid tissues. • Some of these allergic drugs transiently increased CD4{sup +}CD25{sup +} T cells in the spleen.

  1. BANYAN. V. A SYSTEMATIC ALL-SKY SURVEY FOR NEW VERY LATE-TYPE LOW-MASS STARS AND BROWN DWARFS IN NEARBY YOUNG MOVING GROUPS

    SciTech Connect (OSTI)

    Gagné, Jonathan; Lafrenière, David; Doyon, René; Malo, Lison; Artigau, Étienne

    2015-01-10

    We present the BANYAN All-Sky Survey (BASS) catalog, consisting of 228 new late-type (M4-L6) candidate members of nearby young moving groups (YMGs) with an expected false-positive rate of ?13%. This sample includes 79 new candidate young brown dwarfs and 22 planetary-mass objects. These candidates were identified through the first systematic all-sky survey for late-type low-mass stars and brown dwarfs in YMGs. We cross-matched the Two Micron All Sky Survey and AllWISE catalogs outside of the galactic plane to build a sample of 98,970 potential ?M5 dwarfs in the solar neighborhood and calculated their proper motions with typical precisions of 5-15 mas yr{sup –1}. We selected highly probable candidate members of several YMGs from this sample using the Bayesian Analysis for Nearby Young AssociatioNs II tool (BANYAN II). We used the most probable statistical distances inferred from BANYAN II to estimate the spectral type and mass of these candidate YMG members. We used this unique sample to show tentative signs of mass segregation in the AB Doradus moving group and the Tucana-Horologium and Columba associations. The BASS sample has already been successful in identifying several new young brown dwarfs in earlier publications, and will be of great interest in studying the initial mass function of YMGs and for the search of exoplanets by direct imaging; the input sample of potential close-by ?M5 dwarfs will be useful to study the kinematics of low-mass stars and brown dwarfs and search for new proper motion pairs.

  2. U-017: HP MFP Digital Sending Software Lets Local Users Obtain Potentially Sensitive Information

    Broader source: Energy.gov [DOE]

    A vulnerability was reported in HP MFP Digital Sending Software. A local user can obtain potentially sensitive information.

  3. Status Report: USGS coal assessment of the Powder River Basin, Wyoming

    SciTech Connect (OSTI)

    James A. Luppens; Timothy J. Rohrbacher; Jon E. Haacke; David C. Scott; Lee M. Osmonson

    2006-07-01

    This publication reports on the status of the current coal assessment of the Powder River Basin (PRB) in Wyoming and Montana. This slide program was presented at the Energy Information Agency's 2006 EIA Energy Outlook and Modeling Conference in Washington, DC, on March 27, 2006. The PRB coal assessment will be the first USGS coal assessment to include estimates of both regional coal resources and reserves for an entire coal basin. Extensive CBM and additional oil and gas development, especially in the Gillette coal field, have provided an unprecedented amount of down-hole geological data. Approximately 10,000 new data points have been added to the PRB database since the last assessment (2002) which will provide a more robust evaluation of the single most productive U.S. coal basin. The Gillette coal field assessment, including the mining economic evaluation, is planned for completion by the end of 2006. The geologic portion of the coal assessment work will shift to the northern and northwestern portions of the PRB before the end of 2006 while the Gillette engineering studies are finalized. 7 refs.

  4. DEVELOPMENT OF THE LARGE-BORE POWDER GUN FOR THE NEVADA TEST SITE

    SciTech Connect (OSTI)

    Jensen, B.J.; Esparza, J.

    2009-12-28

    Plate-impact experiments on single stage guns provide very planar loading conditions suitable for studying complex phenomena such as phase transitions and material strength, and provide important data useful for constraining and validating predictive models. The objective of the current work was to develop a large-bore (3.5'' or greater) powder gun capable of accelerating projectiles to moderately high velocities (greater than 2.25 km/s) for impact experiments at Nevada Test Site. This gun will span a performance gap between existing gun facilities and provide a means of examining phenomena over a wide range of stresses and time-scales. Advantages of the large-bore gun include the capability to load multiple samples simultaneously, the use of large diameter samples that significantly extend the time duration of the experiment, and minimal tilt (no bow). This new capability required the development of a disposable confinement system that used an explosively driven closure method to prevent contamination from moving up into the gun system. Experimental results for both the gun system and the explosive valve are presented.

  5. Developing of the large-bore powder gun for the Nevada test site

    SciTech Connect (OSTI)

    Jensen, Brian J; Esparza, James S

    2009-01-01

    Plate-impact experiments on single stage guns provide very planar loading conditions suitable for studying complex phenomena such as phase transitions and material strength, and provide important data useful for constraining and validating predictive models. The objective of the current work was to develop a large-bore (3.5-inches or greater) powder gun capable of accelerating projectiles to moderately high velocities (greater than 2.25 km/s) for impact experiments at Nevada Test Site. This gun will span a performance gap between existing gun facilities and provide a means of examining phenomena over a wide range of stresses and time-scales. Advantages of the large-bore gun include the capability to load multiple samples simultaneously, the use of large diameter samples that significantly extend the time duration of the experiment, and minimal tilt (no bow). This new capability required the development of a disposable confinement system that used an explosively driven closure method to prevent contamination from moving up into the gun system. Experimental results for both the gun system and the explosive valve are presented.

  6. Critical Experiments that Simulated Damp MOX Powders - Do They Meet the Need?

    SciTech Connect (OSTI)

    J. Blair Briggs; Dr. Ali Nouri; Dr. Claes Nordborg

    2005-09-01

    The OECD Nuclear Energy Agency (NEA) Working Party on Nuclear Criticality Safety (WPNCS) identified the MOX fuel manufacturing process as an area in which there is a need for additional integral benchmark data. The specific need focused on damp MOX powders. The WPNCS was ultimately asked by the NEA Nuclear Science Committee (NSC) to provide the framework for the selection and performance of new experiments that fill the identified need. A set of criteria was established to enable uniform comparison of experimental proposals with generic MOX application data. Criteria were established for five general characteristics: (1) neutronic parameters, (2) type of experiments, (3) financial aspects, (4) schedule, and (5) other considerations. Proposals were judged most importantly on their ability to match the neutronic parameters of predetermined MOX applications. The neutronic parameters that formed the basis for comparison included core average values (not local values) for flux, fission and capture rate; detailed balance data (fission and capture) for the main isotopes (Actinides, H and O); sensitivity coefficients to important nuclear reactions (fission, capture, elastic and inelastic scatter, nu-bar, mu-bar) for all uranium and plutonium isotopes, hydrogen, and oxygen; sensitivity profiles to the main nuclear reactions for uranium and plutonium isotopes; energy of average lethargy causing fission; and the average fission group energy. The focus of this paper is on the definition of the need; the neutronics criteria established to assess which, if any, of three proposed MOX experimental programs best meet the need; and the actual assessment of the proposed experimental programs.

  7. Preparation of Cu and Fly Ash Composite by Powder Metallurgy Technique

    SciTech Connect (OSTI)

    Chew, P. Y.; Lim, P. S.; Ng, M. C.; Zahi, S.; You, A. H.

    2011-03-30

    Cu and Fly Ash (FA) mixtures with different weight percentages were prepared. Pellets of the mixture powder were produced with the dimension of 17.7 mm in diameter and 10-15 mm in height. These different composites were compacted at a constant pressure of 280 MPa. One of the selected weight percentages was then compacted to form into pellet and sintered at different temperatures which were at 900, 950 and 1000 deg. C respectively for 2 hours. Density of green pellet was measured before sintered in furnace. After sintering, all the pellets with different temperatures were re-weighed and sintered density were calculated. The densification of the green and sintered pellets was required to be measured as one of the parameter in selection of the best material properties. Porosity of the pellet shall not be ignored in order to analyze the close-packed particles stacking in the pellet. SEM micrograph had been captured to observe the presence of pores and agglomeration of particles in the sample produced.

  8. Flux enhancement with powdered activated carbon addition in the membrane anaerobic bioreactor

    SciTech Connect (OSTI)

    Park, H.; Choo, K.H.; Lee, C.H.

    1999-10-01

    The effect of powdered activated carbon (PAC) addition on the performance of a membrane-coupled anaerobic bioreactor (MCAB) was investigated in terms of membrane filterability and treatability through a series of batch and continuous microfiltration (MF) experiments. In both batch and continuous MF of the digestion broth, a flux improvement with PAC addition was achieved, especially when a higher shear rate and/or a higher PAC dose were applied. Both the fouling and cake layer resistances decreased continuously with increasing the PAC dose up to 5 g/L. PAC played an important role in substantially reducing the biomass cake resistance due to its incompressible nature and higher backtransport velocities. PAC might have a scouring effect for removing the deposited biomass cake from the membrane surface while sorbing and/or coagulating dissolved organics and colloidal particles in the broth. The chemical oxygen demand and color in the effluent were much removed with PAC addition, and the system was also more stable against shock loading.

  9. Variation of the shape and morphological properties of silica and metal oxide powders by electro homogeneous precipitation

    DOE Patents [OSTI]

    Harris, M.T.; Basaran, O.A.; Sisson, W.G.; Brunson, R.R.

    1997-02-18

    The present invention provides a method for preparing irreversible linear aggregates (fibrils) of metal oxide powders by utilizing static or pulsed DC electrical fields across a relatively non-conducting liquid solvent in which organometal compounds or silicon alkoxides have been dissolved. The electric field is applied to the relatively non-conducting solution throughout the particle formation and growth process promoting the formation of either linear aggregates (fibrils) or spherical shaped particles as desired. Thus the present invention provides a physical method for altering the size, shape and porosity of precursor hydrous metal oxide or hydrous silicon oxide powders for the development of advanced ceramics with improved strength and insulating capacity. 3 figs.

  10. Thermoelectric properties of nano-meso-micro β-MnO₂ powders as a function of electrical resistance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hedden, Morgan; Francis, Nick; Haraldsen, Jason T.; Ahmed, Towfiq; Constantin, Costel

    2015-07-15

    Particle sizes of manganese oxide (β-MnO₂) powders were modified by using a mortar and pestle ground method for period of times that varied between 15–60 min. Particle size versus ground time clearly shows the existence of a size-induced regime transition (i.e., regime I and II). Thermoelectric properties of β-MnO₂ powders as a function of electrical resistance in the range of RP = 10 - 80Ω were measured. Based on the data presented, we propose a model for the β-MnO₂ system in which nanometer-scale MnO₂ crystallites bond together through weak van der Waals forces to form larger conglomerates that span inmore » size from nanometer to micrometer scale.« less

  11. Low Activation Joining of SiC/SiC Composites for Fusion Applications: Tape Casting TiC+Si Powders

    SciTech Connect (OSTI)

    Henager, Charles H.; Kurtz, Richard J.; Canfield, Nathan L.; Shin, Yongsoon; Luscher, Walter G.; Mansurov, Jirgal; Roosendaal, Timothy J.; Borlaug, Brennan A.

    2013-08-06

    The use of SiC composites in fusion environments likely requires joining of plates using reactive joining or brazing. One promising reactive joining method uses solid-state displacement reactions between Si and TiC to produce Ti3SiC2 + SiC. We continue to explore the processing envelope for this joint for the TITAN collaboration in order to produce optimal joints to undergo irradiation studies in HFIR. One noted feature of the joints produced using tape-calendared powders of TiC+Si has been the large void regions that have been apparently unavoidable. Although the produced joints are very strong, these voids are undesirable. In addition, the tapes that were made for this joining were produced about 20 years ago and were aging. Therefore, we embarked on an effort to produce some new tape cast powders of TiC and Si that could replace our aging tape calendared materials.

  12. Structural, negative thermal expansion and photocatalytic properties of ZrV{sub 2}O{sub 7}: a comparative study between fibers and powders

    SciTech Connect (OSTI)

    Liu, Qinqin; Yang, Juan; Rong, Xiaoqing; Sun, Xiujuan; Cheng, Xiaonong; Tang, Hua; Li, Haohua

    2014-10-15

    Novel ZrV{sub 2}O{sub 7} microfibers with diameters about 1–3 ?m were synthesized using a sol–gel technique. For comparison, ZrV{sub 2}O{sub 7} powders were prepared by the same method. The resultant structures were studied by X-ray diffraction, field-emission scanning electron microscopy and transmission electron microscopy. The results indicated that both the pure ZrV{sub 2}O{sub 7} microfibers and powders could be synthesized by the sol–gel technique. The thermal expansion property of the as-prepared ZrV{sub 2}O{sub 7} microfibers and powders was characterized by a thermal mechanical analyzer, both the fibers with cylindrical morphology and irregular powders with average size between 100 and 200 nm showed negative thermal expansion between 150 °C and 600 °C. The photocatalytic activity of the microfibers was compared to that of powders under UV radiations. The band gap of ZrV{sub 2}O{sub 7} microfibers decreased and its absorption edge exhibited red shift. The microfibers also had a higher surface area compared with the powders, resulting in considerably higher photocatalytic characteristics. The large surface area and the enhanced photocatalytic activity of the ZrV{sub 2}O{sub 7} microfibers also offer potential applications in sensors and inorganic ion exchangers. - Graphical abstract: (a and c) SEM photos of ZrV{sub 2}O{sub 7} powders and fibers. (b and d) TEM images of ZrV{sub 2}O{sub 7} powders and fibers. (e) Thermal expansion curves of ZrV{sub 2}O{sub 7} powders and fibers. (f) Degradation curves of ZrV{sub 2}O{sub 7} powders and ZrV{sub 2}O{sub 7} fibers. - Highlights: • Novel ZrV{sub 2}O{sub 7} fibers could be synthesized using sol–gel technique. • ZrV{sub 2}O{sub 7} powders with irregular shape are also prepared for comparison. • Both ZrV{sub 2}O{sub 7} microfibers and powders exhibit negative thermal expansion property. • ZrV{sub 2}O{sub 7} microfibers show outstanding photocatalytic activity under UV irradiation. • This synthesis technique can be easily extended to many other functional fibers.

  13. Characterization of novel sorghum brown midrib mutants from an EMS-mutagenized population

    SciTech Connect (OSTI)

    Sattler, Scott E.; Saballos, Ana; Xin, Zhanguo; Funnell-Harris, Deanna L.; Vermerris, Wilfred; Pedersen, Jeffrey F.

    2014-09-02

    Reducing lignin concentration in lignocellulosic biomass can increase forage digestibility for ruminant livestock and saccharification yields of biomass for bioenergy. In sorghum (Sorghum bicolor (L.) Moench) and several other C4 grasses, brown midrib (bmr) mutants have been shown to reduce lignin concentration. Putative bmr mutants isolated from an EMS-mutagenized population were characterized and classified based on their leaf midrib phenotype and allelism tests with the previously described sorghum bmr mutants bmr2, bmr6, and bmr12. These tests resulted in the identification of additional alleles of bmr2, bmr6,and bmr12, and, in addition, six bmr mutants were identified that were not allelic to these previously described loci. Further allelism testing among these six bmr mutants showed that they represented four novel bmr loci. Based on this study, the number of bmr loci uncovered in sorghum has doubled. The impact of these lines on agronomic traits and lignocellulosic composition was assessed in a 2-yr field study. Most of the identified bmr lines showed reduced lignin concentration of their biomass relative to wild-type (WT). Effects of the six new bmr mutants on enzymatic saccharification of lignocellulosic materials were determined, but the amount of glucose released from the stover was similar to WT in all cases. Like bmr2, bmr6, and bmr12, these mutants may affect monolignol biosynthesis and may be useful for bioenergy and forage improvement when stacked together or in combination with the three previously described bmr alleles.

  14. Proteomic and Functional Analysis of the Cellulase System Expressed by Postia placenta during Brown Rot of Solid Wood

    SciTech Connect (OSTI)

    Ryu, Jae San; Shary, Semarjit; Houtman, Carl J.; Panisko, Ellen A.; Korripally, Premsagar; St John, Franz J.; Crooks, Casey; Siika-aho, Matti; Magnuson, Jon K.; Hammel, Ken

    2011-11-01

    Abstract Brown rot basidiomycetes have an important ecological role in lignocellulose recycling and are notable for their rapid degradation of wood polymers via oxidative and hydrolytic mechanisms. However, most of these fungi apparently lack processive (exo-acting) cellulases, such as cellobiohydrolases, which are generally required for efficient cellulolysis. The recent sequencing of the Postia placenta genome now permits a proteomic approach to this longstanding conundrum. We grew P. placenta on solid aspen wood, extracted proteins from the biodegrading substrate, and analyzed tryptic digests by shotgun liquid chromatography-tandem mass spectrometry. Comparison of the data with the predicted P. placenta proteome revealed the presence of 34 likely glycoside hydrolases, but only four of these-two in glycoside hydrolase family 5, one in family 10, and one in family 12-have sequences that suggested possible activity on cellulose. We expressed these enzymes heterologously and determined that they all exhibited endoglucanase activity on phosphoric acid-swollen cellulose. They also slowly hydrolyzed filter paper, a more crystalline substrate, but the soluble/insoluble reducing sugar ratios they produced classify them as nonprocessive. Computer simulations indicated that these enzymes produced soluble/insoluble ratios on reduced phosphoric acid-swollen cellulose that were higher than expected for random hydrolysis, which suggests that they could possess limited exo activity, but they are at best 10-fold less processive than cellobiohydrolases. It appears likely that P. placenta employs a combination of oxidative mechanisms and endo-acting cellulases to degrade cellulose efficiently in the absence of a significant processive component.

  15. The Wyodak-Anderson coal assessment, Powder River Basin, Wyoming and Montana -- An ArcView project

    SciTech Connect (OSTI)

    Flores, R.M.; Gunther, G.; Ochs, A.; Ellis, M.E.; Stricker, G.D.; Bader, L.R.

    1998-12-31

    In 1997, more than 305 million short tons of clean and compliant coal were produced from the Wyodak-Anderson and associated coal beds and zones of the Paleocene Fort Union Formation in the Powder River Basin, Wyoming and Montana. To date, all coal produced from the Wyodak-Anderson, which averages 0.47 percent sulfur and 6.44 percent ash, has met regulatory compliance standards. Twenty-eight percent of the total US coal production in 1997 was from the Wyodak-Anderson coal. Based on the current consumption rates and forecast by the Energy Information Administration (1996), the Wyodak-Anderson coal is projected to produce 413 million short tons by the year 2016. In addition, this coal deposit as well as other Fort Union coals have recently been targeted for exploration and development of methane gas. New US Geological Survey (USGS) digital products could provide valuable assistance in future mining and gas development in the Powder River Basin. An interactive format, with querying tools, using ArcView software will display the digital products of the resource assessment of Wyodak-Anderson coal, a part of the USGS National Coal Resource Assessment of the Powder River Basin. This ArcView project includes coverages of the data point distribution; land use; surface and subsurface ownerships; coal geology, stratigraphy, quality and geochemistry; and preliminary coal resource calculations. These coverages are displayed as map views, cross sections, tables, and charts.

  16. Shock compression behavior of bi-material powder composites with disparate melting temperatures

    SciTech Connect (OSTI)

    Sullivan, Kyle T.; Swift, Damian; Barham, Matthew; Stölken, James; Kuntz, Joshua; Kumar, Mukul

    2014-01-14

    Laser driven experiments were used to investigate the shock compression behavior of powder processed Bismuth/Tungsten (Bi/W) composite samples. The constituents provide different functionality to the composite behavior as Bi could be shock melted at the pressures attained in this work, while the W could not. Samples were prepared by uniaxial pressing, and the relative density was measured as a function of particle size, applied pressure, and composition for both hot and cold pressing conditions. This resulted in sample densities between 73% and 99% of the theoretical maximum density, and also noticeable differences in microstructure in the hot and cold pressed samples. The compression waves were generated with a 1.3 × 1.3?mm square spot directly onto the surface of the sample, using irradiances between 10{sup 12} and 10{sup 13}?W/cm{sup 2}, which resulted in calculated peak pressures between 50 and 150?GPa within a few micrometers. Sample recovery and post-mortem analysis revealed the formation of a crater on the laser drive surface, and the depth of this crater corresponded to the depth to which the Bi had been melted. The melt depth was found to be primarily a function of residual porosity and composition, and ranged from 167 to 528??m. In general, a higher porosity led to a larger melt depth. Direct numerical simulations were performed, and indicated that the observed increase in melt depth for low-porosity samples could be largely attributed to increased heating associated with work done for pore collapse. However, the relative scaling was sensitive to composition, with low volume fraction Bi samples exhibiting a much stronger dependence on porosity than high Bi content samples. Select samples were repeated using an Al foil ablator, but there were no noticeable differences ensuring that the observed melting was indeed pressure-driven and was not a result of direct laser heating. The resultant microstructures and damage near the spall surface were also investigated qualitatively.

  17. Subsurface cross section of lower Paleozoic rocks, Powder River basin, Wyoming and Montana

    SciTech Connect (OSTI)

    Macke, D.L.

    1988-07-01

    The Powder River basin is one of the most actively explored Rocky Mountain basins for hydrocarbons, yet the lower Paleozoic (Cambrian through Mississippian) rocks of this interval remain little studied. As a part of a program studying the evolution of sedimentary basins, approximately 3200 km of cross section, based on more than 50 combined geophysical and lithologic logs, have been constructed covering an area of about 200,000 km/sup 2/. The present-day basin is a Cenozoic structural feature located between the stable interior of the North American craton and the Cordilleran orogenic belt. At various times during the early Paleozoic, the basin area was not distinguishable from either the stable craton, the Williston basin, the Central Montana trough, or the Cordilleran miogeocline. Both deposition and preservation in the basin have been greatly influenced by the relative uplift of the Transcontinental arch. Shows of oil and dead oil in well cuttings confirm that hydrocarbons have migrated through at least parts of the basin's lower Paleozoic carbonate section. These rocks may have been conduits for long-distance migration of hydrocarbons as early as Late Cretaceous, based on (1) the probable timing of thermal maturation of hydrocarbon-source rocks within the basin area and to the west, (2) the timing of Laramide structural events, (3) the discontinuous nature of the reservoirs in the overlying, highly productive Pennsylvanian-Permian Minnelusa Formation, and (4) the under-pressuring observed in some Minnelusa oil fields. Vertical migration into the overlying reservoirs could have been through deep fractures within the basin, represented by major lineament systems. Moreover, the lower Paleozoic rocks themselves may also be hydrocarbon reservoirs.

  18. Policy Flash 2013-24 Fee Determinations: Requirement to Obtain Acquisition

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Executive's Input | Department of Energy 4 Fee Determinations: Requirement to Obtain Acquisition Executive's Input Policy Flash 2013-24 Fee Determinations: Requirement to Obtain Acquisition Executive's Input Attached is Policy Flash 2013-24 Fee Determinations: Requirement to Obtain Acquisition Executive's Input. Questions concerning this policy flash should be directed to Michael Righi of the Contract and Financial Assistance Policy Division, Office of Policy, Office Acquisition and Project

  19. U-053: Linux kexec Bugs Let Local and Remote Users Obtain Potentially

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sensitive Information | Department of Energy 53: Linux kexec Bugs Let Local and Remote Users Obtain Potentially Sensitive Information U-053: Linux kexec Bugs Let Local and Remote Users Obtain Potentially Sensitive Information December 7, 2011 - 7:30am Addthis PROBLEM: Linux kexec Bugs Let Local and Remote Users Obtain Potentially Sensitive Information . PLATFORM: Red Hat Enterprise Linux Desktop (v. 6) Red Hat Enterprise Linux HPC Node (v. 6) Red Hat Enterprise Linux Server (v. 6) Red Hat

  20. Chemical Reduction of Nd 1.85 Ce 0.15 CuO 4− δ Powders in Supercritical Sodium Ammonia Solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dias, Yasmin; Wang, Hui; Zhou, Haiqing; Lin, Feng; Lan, Yucheng

    2015-01-01

    Nd 1.85 Ce 0.15 CuO 4− δ powders are chemically reduced in supercritical sodium ammonia solutions from room temperature to 350°C. The crystallographic structure of the reduced powders is investigated from Rietveld refinement of X-ray powder diffraction. The atomic positions are maintained constant within experimental errors while temperature factors of all atoms increase significantly after the chemical treatments, especially of Nd/Ce atoms. The ammonothermally reduced Nd 1.85 Ce 0.15 CuO 4− δ powders show diamagnetic below 24 K which is contributed to the lower oxygen content and higher temperature factors of atoms in the treated compound.more » The ammonothermal method paves a new way to reduce oxides in supercritical solutions near room temperature.« less

  1. Chemical Reduction of Nd1.85Ce0.15CuO4??Powders in Supercritical Sodium Ammonia Solutions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dias, Yasmin; Wang, Hui; Zhou, Haiqing; Lin, Feng; Lan, Yucheng

    2015-01-01

    Nd1.85Ce0.15CuO4??powders are chemically reduced in supercritical sodium ammonia solutions from room temperature to 350°C. The crystallographic structure of the reduced powders is investigated from Rietveld refinement of X-ray powder diffraction. The atomic positions are maintained constant within experimental errors while temperature factors of all atoms increase significantly after the chemical treatments, especially of Nd/Ce atoms. The ammonothermally reduced Nd1.85Ce0.15CuO4??powders show diamagnetic below 24?K which is contributed to the lower oxygen content and higher temperature factors of atoms in the treated compound. The ammonothermal method paves a new way to reduce oxides in supercritical solutions near room temperature.

  2. Enhanced hydrolysis and methane yield by applying microaeration pretreatment to the anaerobic co-digestion of brown water and food waste

    SciTech Connect (OSTI)

    Lim, Jun Wei; Wang, Jing-Yuan

    2013-04-15

    Highlights: ? Microaeration pretreatment was effective for brown water and food waste mixture. ? The added oxygen was consumed fully by facultative microorganisms. ? Enhanced solubilization, acidification and breakdown of SCFAs to acetate. ? Microaeration pretreatment improved methane yield by 10–21%. ? Nature of inoculum influenced the effects of microaeration. - Abstract: Microaeration has been used conventionally for the desulphurization of biogas, and recently it was shown to be an alternative pretreatment to enhance hydrolysis of the anaerobic digestion (AD) process. Previous studies on microaeration pretreatment were limited to the study of substrates with complex organic matter, while little has been reported on its effect on substrates with higher biodegradability such as brown water and food waste. Due to the lack of consistent microaeration intensities, previous studies were not comparable and thus inconclusive in proving the effectiveness of microaeration to the overall AD process. In this study, the role of microaeration pretreatment in the anaerobic co-digestion of brown water and food waste was evaluated in batch-tests. After a 4-day pretreatment with 37.5 mL-O{sub 2}/L{sub R}-d added to the liquid phase of the reactor, the methane production of substrates were monitored in anaerobic conditions over the next 40 days. The added oxygen was consumed fully by facultative microorganisms and a reducing environment for organic matter degradation was maintained. Other than higher COD solubilization, microaeration pretreatment led to greater VFA accumulation and the conversion of other short chain fatty acids to acetate. This could be due to enhanced activities of hydrolytic and acidogenic bacteria and the degradation of slowly biodegradable compounds under microaerobic conditions. This study also found that the nature of inoculum influenced the effects of microaeration as a 21% and 10% increase in methane yield was observed when pretreatment was applied to inoculated substrates, and substrates without inoculum, respectively.

  3. Method and apparatus for obtaining enhanced production rate of thermal chemical reactions

    DOE Patents [OSTI]

    Tonkovich, Anna Lee Y.; Wang, Yong; Wegeng, Robert S.; Gao, Yufei

    2003-09-09

    Reactors and processes are disclosed that can utilize high heat fluxes to obtain fast, steady-state reaction rates. Porous catalysts used in conjunction with microchannel reactors to obtain high rates of heat transfer are also disclosed. Reactors and processes that utilize short contact times, high heat flux and low pressure drop are described. Improved methods of steam reforming are also provided.

  4. Method and apparatus for obtaining enhanced production rate of thermal chemical reactions

    DOE Patents [OSTI]

    Tonkovich, Anna Lee Y.; Wang, Yong; Wegeng, Robert S.; Gao, Yufei

    2006-05-16

    Reactors and processes are disclosed that can utilize high heat fluxes to obtain fast, steady-state reaction rates. Porous catalysts used in conjunction with microchannel reactors to obtain high rates of heat transfer are also disclosed. Reactors and processes that utilize short contact times, high heat flux and low pressure drop are described. Improved methods of steam reforming are also provided.

  5. SIMP J2154–1055: A NEW LOW-GRAVITY L4? BROWN DWARF CANDIDATE MEMBER OF THE ARGUS ASSOCIATION

    SciTech Connect (OSTI)

    Gagné, Jonathan; Lafrenière, David; Doyon, René; Artigau, Étienne; Malo, Lison; Robert, Jasmin; Nadeau, Daniel

    2014-09-01

    We present SIMP J21543454–1055308, a new L4? brown dwarf identified in the SIMP survey that displays signs of low gravity in its near-infrared spectrum. Using BANYAN II, we show that it is a candidate member of the Argus association, albeit with a 21% probability that it is a contaminant from the field. Measurements of radial velocity and parallax will be needed to verify its membership. If it is a member of Argus (age 30-50 Myr), then this object would have a planetary mass of 10 ± 0.5 M {sub Jup}.

  6. Molecular Characterization of Brown Carbon (BrC) Chromophores in Secondary Organic Aerosol Generated From Photo-Oxidation of Toluene

    SciTech Connect (OSTI)

    Lin, Peng; Liu, Jiumeng; Shilling, John E.; Kathmann, Shawn M.; Laskin, Julia; Laskin, Alexander

    2015-09-28

    Atmospheric Brown carbon (BrC) is a significant contributor to light absorption and climate forcing. However, little is known about a fundamental relationship between the chemical composition of BrC and its optical properties. In this work, light-absorbing secondary organic aerosol (SOA) was generated in the PNNL chamber from toluene photo-oxidation in the presence of NOx (Tol-SOA). Molecular structures of BrC components were examined using nanospray desorption electrospray ionization (nano-DESI) and liquid chromatography (LC) combined with UV/Vis spectroscopy and electrospray ionization (ESI) high-resolution mass spectrometry (HRMS). The chemical composition of BrC chromophores and the light absorption properties of toluene SOA (Tol-SOA) depend strongly on the initial NOx concentration. Specifically, Tol-SOA generated under high-NOx conditions (defined here as initial NOx/toluene of 5/1) appears yellow and mass absorption coefficient of the bulk sample (MACbulk@365nm = 0.78 m2 g-1) is nearly 80 fold higher than that measured for the Tol-SOA sample generated under low-NOx conditions (NOx/toluene < 1/300). Fifteen compounds, most of which are nitrophenols, are identified as major BrC chromophores responsible for the enhanced light absorption of Tol-SOA material produced in the presence of NOx. The integrated absorbance of these fifteen chromophores accounts for 40-60% of the total light absorbance by Tol-SOA at wavelengths between 300 nm and 500 nm. The combination of tandem LC-UV/Vis-ESI/HRMS measurements provides an analytical platform for predictive understanding of light absorption properties by BrC and their relationship to the structure of individual chromophores. General trends in the UV/vis absorption by plausible isomers of the BrC chromophores were evaluated using theoretical chemistry calculations. The molecular-level understanding of BrC chemistry is helpful for better understanding the evolution and behavior of light absorbing aerosols in the atmosphere.

  7. T-652: Mozilla Thunderbird Bugs Let Remote Users Obtain Cookies and Execute Arbitrary Code

    Broader source: Energy.gov [DOE]

    Multiple vulnerabilities were reported in Mozilla Thunderbird. A remote user can cause arbitrary code to be executed on the target user's system. A remote user can obtain cookies from another domain in certain cases.

  8. U-118: Adobe Flash Player Bugs Let Remote Users Execute Arbitrary Code and Obtain Information

    Broader source: Energy.gov [DOE]

    Two vulnerabilities were reported in Adobe Flash Player. A remote user can cause arbitrary code to be executed on the target user's system. A remote user can obtain potentially information.

  9. Title 43 CFR 3204.5 How Can I Obtain a Noncompetitive Lease?...

    Open Energy Info (EERE)

    5 How Can I Obtain a Noncompetitive Lease? Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal Regulation: Title 43 CFR...

  10. Subtask 4.24 - Field Evaluation of Novel Approach for Obtaining Metal

    Office of Scientific and Technical Information (OSTI)

    Emission Data (Technical Report) | SciTech Connect Technical Report: Subtask 4.24 - Field Evaluation of Novel Approach for Obtaining Metal Emission Data Citation Details In-Document Search Title: Subtask 4.24 - Field Evaluation of Novel Approach for Obtaining Metal Emission Data Over the past two decades, emissions of mercury, nonmercury metals, and acid gases from energy generation and chemical production have increasingly become an environmental concern. On February 16, 2012, the U.S.

  11. Performance of powder-filled evacuated panel insulation in a manufactured home roof cavity: Tests in the Large Scale Climate Simulator

    SciTech Connect (OSTI)

    Petrie, T.W.; Kosny, J.; Childs, P.W.

    1996-03-01

    A full-scale section of half the top of a single-wide manufactured home has been studied in the Large Scale Climate Simulator (LSCS) at the Oak Ridge National Laboratory. A small roof cavity with little room for insulation at the eaves is often the case with single-wide units and limits practical ways to improve thermal performance. The purpose of the current tests was to obtain steady-state performance data for the roof cavity of the manufactured home test section when the roof cavity was insulated with fiberglass batts, blown-in rock wool insulation or combinations of these insulations and powder-filled evacuated panel (PEP) insulation. Four insulation configurations were tested: (A) a configuration with two layers of nominal R{sub US}-7 h {center_dot} ft{sup 2} {center_dot} F/BTU (R{sub SI}-1.2 m{sup 2} {center_dot} K/W) fiberglass batts; (B) a layer of PEPs and one layer of the fiberglass batts; (C) four layers of the fiberglass batts; and (D) an average 4.1 in. (10.4 cm) thick layer of blown-in rock wool at an average density of 2.4 lb/ft{sup 3} (38 kg/m{sup 3}). Effects of additional sheathing were determined for Configurations B and C. With Configuration D over the ceiling, two layers of expanded polystyrene (EPS) boards, each about the same thickness as the PEPs, were installed over the trusses instead of the roof. Aluminum foils facing the attic and over the top layer of EPS were added. The top layer of EPS was then replaced by PEPs.

  12. Effective atomic numbers of blue topaz at different gamma-rays energies obtained from Compton scattering technique

    SciTech Connect (OSTI)

    Tuschareon, S. Limkitjaroenporn, P. Kaewkhao, J.

    2014-03-24

    Topaz occurs in a wide range of colors, including yellow, orange, brown, pink-to-violet and blue. All of these color differences are due to color centers. In order to improve the color of natural colorless topaz, the most commonly used is irradiated with x- or gamma-rays, indicated that attenuation parameters is important to enhancements by irradiation. In this work, the mass attenuation coefficients of blue topaz were measured at the different energy of ?-rays using the Compton scattering technique. The results show that, the experimental values of mass attenuation coefficient are in good agreement with the theoretical values. The mass attenuation coefficients increase with the decrease in gamma rays energies. This may be attributed to the higher photon interaction probability of blue topaz at lower energy. This result is a first report of mass attenuation coefficient of blue topaz at different gamma rays energies.

  13. Pressure/temperature fluid cell apparatus for the neutron powder diffractometer instrument: Probing atomic structure in situ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Hsiu -Wen; Fanelli, Victor R.; Reiche, Helmut M.; Larson, Eric; Taylor, Mark A.; Xu, Hongwu; Zhu, Jinlong; Siewenie, Joan; Page, Katharine

    2014-12-24

    This contribution describes a new local structure compatible gas/liquid cell apparatus for probing disordered materials at high pressures and variable temperatures in the Neutron Powder Diffraction instrument at the Lujan Neutron Scattering Center, Los Alamos National Laboratory. The new sample environment offers choices for sample canister thickness and canister material type. Finite element modeling is utilized to establish maximum allowable working pressures of 414 MPa at 15 K and 121 MPa at 600 K. High quality atomic pair distribution function data extraction and modeling have been demonstrated for a calibration standard (Si powder) and for supercritical and subcritical CO2measurements. Asmore » a result, the new sample environment was designed to specifically target experimental studies of the local atomic structures involved in geologic CO2 sequestration, but will be equally applicable to a wide variety of energy applications, including sorption of fluids on nano/meso-porous solids, clathrate hydrate formation, catalysis, carbon capture, and H2 and natural gas uptake/storage.« less

  14. Pressure/temperature fluid cell apparatus for the neutron powder diffractometer instrument: Probing atomic structure in situ

    SciTech Connect (OSTI)

    Wang, Hsiu-Wen; Fanelli, Victor R.; Reiche, Helmut M.; Larson, Eric; Taylor, Mark A.; Siewenie, Joan; Xu, Hongwu; Zhu, Jinlong; Page, Katharine

    2014-12-15

    This contribution describes a new local structure compatible gas/liquid cell apparatus for probing disordered materials at high pressures and variable temperatures in the Neutron Powder Diffraction instrument at the Lujan Neutron Scattering Center, Los Alamos National Laboratory. The new sample environment offers choices for sample canister thickness and canister material type. Finite element modeling is utilized to establish maximum allowable working pressures of 414 MPa at 15 K and 121 MPa at 600 K. High quality atomic pair distribution function data extraction and modeling have been demonstrated for a calibration standard (Si powder) and for supercritical and subcritical CO{sub 2} measurements. The new sample environment was designed to specifically target experimental studies of the local atomic structures involved in geologic CO{sub 2} sequestration, but will be equally applicable to a wide variety of energy applications, including sorption of fluids on nano/meso-porous solids, clathrate hydrate formation, catalysis, carbon capture, and H{sub 2} and natural gas uptake/storage.

  15. Statistical evaluation of the effects of fall and winter flows on the spring condition of rainbow and brown trout in the green river downstream of Flaming Gorge Dam.

    SciTech Connect (OSTI)

    Magnusson, A. K.; LaGory, K. E.; Hayse, J. W.; Environmental Science Division

    2009-01-09

    Flaming Gorge Dam, a hydroelectric facility operated by the Bureau of Reclamation (Reclamation), is located on the Green River in Daggett County, northeastern Utah. In recent years, single peak releases each day or steady flows have been the operational pattern during the winter period. A double-peak pattern (two flow peaks each day) was implemented during the winter of 2006-2007 by Reclamation. Because there is no recent history of double-peaking at Flaming Gorge Dam, the potential effects of double-peaking operations on the body condition of trout in the dam's tailwater are not known. A study plan was developed that identified research activities to evaluate potential effects from double-peaking operations during winter months. Along with other tasks, the study plan identified the need to conduct a statistical analysis of existing data on trout condition and macroinvertebrate abundance to evaluate potential effects of hydropower operations. This report presents the results of this analysis. We analyzed historical data to (1) describe temporal patterns and relationships among flows, benthic macroinvertebrate abundance, and condition of brown trout (Salmo trutta) and rainbow trout (Oncorhynchus mykiss) in the tailwaters of Flaming Gorge Dam and (2) to evaluate the degree to which flow characteristics (i.e., flow volumes and flow variability) and benthic macroinvertebrate abundance affect the condition of trout in this area. This information, together with further analyses of size-stratified trout data, may also serve as baseline data to which the effects of potential future double-peaking flows can be compared. The condition (length, weight and/or relative weight) of rainbow trout (Oncorhynchus mykiss) at two sites in the Green River downstream of Flaming Gorge Dam (Tailrace and Little Hole) and weight of brown trout (Salmo trutta) at the Little Hole site has been decreasing since 1990 while the abundance of brown trout has been increasing at the two sites. At the same time, flow variability in the river has decreased and the abundance of total benthic macroinvertebrates at the Tailrace site has increased. The condition of trout in spring (averaged across all sampled trout) was positively correlated with fall and winter flow variability (including within-day skewness, within-season skewness and/or change in flow between days) at both locations. No negative correlations between trout condition and any measure of flow variability were detected. The length and weight of rainbow trout at the Little Hole site were negatively correlated with increasing fall and winter flow volume. The condition of brown trout at Little Hole and the condition of brown and rainbow trout at Tailrace were not correlated with flow volume. Macroinvertebrate variables during October were either positively correlated or not correlated with measures of trout condition at the Tailrace and Little Hole sites. With the exception of a positive correlation between taxa richness of macroinvertebrates in January and the relative weight of brown trout at Tailrace, the macroinvertebrate variables during January and April were either not correlated or negatively correlated with measures of trout condition. We hypothesize that high flow variability increased drift by dislodging benthic macroinvertebrates, and that the drift, in turn, resulted in mostly lower densities of benthic macroinvertebrates, which benefited the trout by giving them more feeding opportunities. This was supported by negative correlations between benthic macroinvertebrates and flow variability. Macroinvertebrate abundance (with the exception of ephemeropterans) was also negatively correlated with flow volume. The change in trout condition from fall to spring, as measured by the ratio of spring to fall relative weight, was evaluated to determine their usefulness as a standardized index to control for the initial condition of the fish as they enter the winter period. The ratio values were less correlated with the fall condition values than the spring condition values and did not show the same relationships to flows, to macroinvertebrates, or across years as the above-mentioned spring relative weight values. We found that the condition ratio of rainbow trout at Tailrace was positively correlated with within-day flow variability but was not correlated with flow volume, between-day-, or within-season flow variability. The condition ratios of rainbow trout at Little Hole and of both trout species at Tailrace were not correlated to any of the measured flow variables. The condition ratios of both trout species were positively correlated with the abundance of January benthic macroinvertebrates at the Little Hole site and with January dipterans (brown trout) or total coleopterans (rainbow trout) at the Tailrace site. The relationships among flows, macroinvertebrates, and trout condition were varied among species and locations.

  16. COMMENTS ON ANOMALOUS EFFECTS IN CHARGING OF PD POWDERS WITH HIGH DENSITY HYDROGEN ISOTOPES

    SciTech Connect (OSTI)

    Shanahan, K.

    2009-10-01

    In Kitamura, et al, Pd-containing materials are exposed to isotopes of hydrogen and anomalous results obtained. These are claimed to be a replication of another experiment conducted by Arata and Zhang. Erroneous basic assumptions are pointed out herein that alter the derived conclusions significantly. The final conclusion is that the reported results are likely normal chemistry combined with noise. Thus the claim to have proven that cold fusion is occurring in these systems is both premature and unlikely.

  17. Process For Cutting Polymers Electrolyte Multi-Layer Batteries And Batteries Obtained Thereby

    DOE Patents [OSTI]

    Gauthier, Michel (La Prairie, CA); Lessard, Ginette (Longueuil, CA); Dussault, Gaston (St-Benoit-de-Mirabel, CA); Rouillard, Roger (Beloeil, CA); Simoneau, Martin (Montreal, CA); Miller, Alan Paul (Woodbury, MN)

    2003-09-09

    A stacking of battery laminate is prepared, each battery consisting of anode, polymer electrolyte, cathode films and possibly an insulating film, under conditions suitable to constitute a rigid monoblock assembly, in which the films are unitary with one another. The assembly obtained is thereafter cut in predetermined shape by using a mechanical device without macroscopic deformation of the films constituting the assembly and without inducing permanent short circuits. The battery which is obtained after cutting includes at least one end which appears as a uniform cut, the various films constituting the assembly having undergone no macroscopic deformation, the edges of the films of the anode including an electronically insulating passivation film.

  18. Subtask 4.24 - Field Evaluation of Novel Approach for Obtaining Metal

    Office of Scientific and Technical Information (OSTI)

    Emission Data (Technical Report) | SciTech Connect Technical Report: Subtask 4.24 - Field Evaluation of Novel Approach for Obtaining Metal Emission Data Citation Details In-Document Search Title: Subtask 4.24 - Field Evaluation of Novel Approach for Obtaining Metal Emission Data × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit

  19. High-pressure shock behavior of WC and Ta2O5 powders.

    SciTech Connect (OSTI)

    Knudson, Marcus D. (Sandia National Laboratories, Albuquerque, NM); Reinhart, William Dodd (Sandia National Laboratories, Albuquerque, NM); Vogler, Tracy John; Root, Seth (Sandia National Laboratories, Albuquerque, NM)

    2011-10-01

    Planar shock experiments were conducted on granular tungsten carbide (WC) and tantalum oxide (Ta{sub 2}O{sub 5}) using the Z machine and a 2-stage gas gun. Additional shock experiments were also conducted on a nearly fully dense form of Ta{sub 2}O{sub 5}. The experiments on WC yield some of the highest pressure results for granular materials obtained to date. Because of the high distention of Ta{sub 2}O{sub 5}, the pressures obtained were significantly lower, but the very high temperatures generated led to large contributions of thermal energy to the material response. These experiments demonstrate that the Z machine can be used to obtain accurate shock data on granular materials. The data on Ta{sub 2}O{sub 5} were utilized in making improvements to the P-{lambda} model for high pressures; the model is found to capture the results not only of the Z and gas gun experiments but also those from laser experiments on low density aerogels. The results are also used to illustrate an approach for generating an equation of state using only the limited data coming from nanoindentation. Although the EOS generated in this manner is rather simplistic, for this material it gives reasonably good results.

  20. Process for production of solution-derived (Pb,La)(Nb,Sn,Zr,Ti)O{sub 3} thin films and powders

    DOE Patents [OSTI]

    Boyle, T.J.

    1999-01-12

    A simple and rapid process for synthesizing (Pb,La)(Nb,Sn,Zr,Ti)O{sub 3} precursor solutions and subsequent ferroelectric thin films and powders of the perovskite phase of these materials has been developed. This process offers advantages over standard methods, including: rapid solution synthesis (<10 minutes), use of commercially available materials, film production under ambient conditions, ease of lanthanum dissolution at high concentrations, and no heating requirements during solution synthesis. For lanthanum-doped ferroelectric materials, the lanthanum source can be added with total synthesis time less than 10 minutes. Films and powders are crystallized at approximately 650 C and exhibit ferroelectric properties comparable to films and powders produced by other techniques which require higher crystallization temperatures. 2 figs.

  1. Process for production of solution-derived (Pb,La)(Nb,Sn,Zr,Ti)O.sub.3 thin films and powders

    DOE Patents [OSTI]

    Boyle, Timothy J. (Albuquerque, NM)

    1999-01-01

    A simple and rapid process for synthesizing (Pb,La)(Nb,Sn,Zr,Ti)O.sub.3 precursor solutions and subsequent ferroelectric thin films and powders of the perovskite phase of these materials has been developed. This process offers advantages over standard methods, including: rapid solution synthesis (<10 minutes), use of commercially available materials, film production under ambient conditions, ease of lanthanum dissolution at high concentrations, and no heating requirements during solution synthesis. For lanthanum-doped ferroelectric materials, the lanthanum source can be added with total synthesis time less than 10 minutes. Films and powders are crystallized at approximately 650.degree. C. and exhibit ferroelectric properties comparable to films and powders produced by other techniques which require higher crystallization temperatures.

  2. A simple model of gas flow in a porous powder compact

    SciTech Connect (OSTI)

    Shugard, Andrew D.; Robinson, David B.

    2014-04-01

    This report describes a simple model for ideal gas flow from a vessel through a bed of porous material into another vessel. It assumes constant temperature and uniform porosity. Transport is treated as a combination of viscous and molecular flow, with no inertial contribution (low Reynolds number). This model can be used to fit data to obtain permeability values, determine flow rates, understand the relative contributions of viscous and molecular flow, and verify volume calibrations. It draws upon the Dusty Gas Model and other detailed studies of gas flow through porous media.

  3. An investigation on the influence of milling time and calcination temperature on the characterization of nano cerium oxide powder synthesized by mechanochemical route

    SciTech Connect (OSTI)

    Aminzare, M.; Amoozegar, Z.; Sadrnezhaad, S.K.

    2012-11-15

    Highlights: ? Synthesis of nanosized CeO{sub 2} was carried out using mechanochemical reactions plus sequential calcinations procedure. ? The effect of milling time and calcinations procedure on crystallite size and surface area of the as-synthesized powders was investigated. ? The extended milling times were exposed to result in the smaller crystallite size, and hence higher surface area for the as-synthesized powder. ? Higher calcinations temperatures, on the other hand, led to the as-synthesized powder with a larger crystallite size and therefore, lower surface area. ? Activation energy for nanocrystallite growth was calculated during the calcinations procedure and the aforementioned crystallite growth was found to be conducted in the light of interfacial reactions. -- Abstract: The synthesis of nano-sized CeO{sub 2} powder was investigated via mechanochemical reactions between hydrate cerium chloride and sodium hydroxide as the starting materials. The process was followed by a subsequent calcination procedure. Characterization of as-synthesized powder was performed using X-ray diffraction, FTIR spectroscopy, Brunner–Emmett–Teller (BET) nitrogen gas absorption, scanning electron microscopy (SEM) and particle size analyzer (PSA). The precursors were milled for different milling times and then were subjected to different heat treatment procedure at variable temperatures from 100 to 700 °C. According to the results, milling time and calcination temperatures induce paramountal effects on crystallite size and surface area of as-synthesized powders. In addition, the average activation energy for the growth of nanocrystals during calcination was determined to be about 12.53 kJ/mol, suggesting the influence of interfacial reactions on the crystallite growth during the calcination procedure.

  4. SPECKLE INTERFEROMETRY AT THE USNO FLAGSTAFF STATION: OBSERVATIONS OBTAINED IN 2008 AND NINE NEW ORBITS

    SciTech Connect (OSTI)

    Hartkopf, William I.; Mason, Brian D. E-mail: bdm@usno.navy.mil

    2011-08-15

    Results are presented for 299 speckle interferometric observations of double stars, obtained in 2008 at the USNO Flagstaff Station using the 1.55 m Kaj Strand Astrometric Reflector. Separations range from 0.''15 to 9.''88, with a median of 2.''22. This observing run concentrated on neglected systems, as well as systems in need of improved orbital elements; new orbital solutions have been determined for nine systems as a result.

  5. Electron beam method and apparatus for obtaining uniform discharges in electrically pumped gas lasers

    DOE Patents [OSTI]

    Fenstermacher, Charles A. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1986-01-01

    A method and apparatus for obtaining uniform, high-energy, large-volume electrical discharges in the lasing medium of a gas laser whereby a high-energy electron beam is used as an external ionization source to ionize substantially the entire volume of the lasing medium which is then readily pumped by means of an applied potential less than the breakdown voltage of the medium. The method and apparatus are particularly useful in CO.sub.2 laser systems.

  6. Lab obtains approval to begin design on new radioactive waste staging

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    facility New radioactive waste staging facility Lab obtains approval to begin design on new radioactive waste staging facility The 4-acre complex will include multiple staging buildings plus an operations center and a concrete pad for mobile waste characterization equipment. September 1, 2010 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience,

  7. Hydrodynamic equations for electrons in graphene obtained from the maximum entropy principle

    SciTech Connect (OSTI)

    Barletti, Luigi

    2014-08-15

    The maximum entropy principle is applied to the formal derivation of isothermal, Euler-like equations for semiclassical fermions (electrons and holes) in graphene. After proving general mathematical properties of the equations so obtained, their asymptotic form corresponding to significant physical regimes is investigated. In particular, the diffusive regime, the Maxwell-Boltzmann regime (high temperature), the collimation regime and the degenerate gas limit (vanishing temperature) are considered.

  8. Method for making graded I-III-VI.sub.2 semiconductors and solar cell obtained thereby

    DOE Patents [OSTI]

    Devaney, Walter E. (Seattle, WA)

    1987-08-04

    Improved cell photovoltaic conversion efficiencies are obtained by the simultaneous elemental reactive evaporation process of Mickelsen and Chen for making semiconductors by closer control of the evaporation rates and substrate temperature during formation of the near contact, bulk, and near junction regions of a graded I-III-VI.sub.2, thin film, semiconductor, such as CuInSe.sub.2 /(Zn,Cd)S or another I-III-VI.sub.2 /II-VI heterojunction.

  9. Two new frameworks of potassium saccharate obtained from acidic and alkaline solution

    SciTech Connect (OSTI)

    Lv, Yao-Kang; Feng, Yun-Long; Liu, Ji-Wei; Jiang, Zhan-Guo

    2011-05-15

    Two chiral K(I) complexes based on D-saccharic acid (H{sub 2}sac), [K(Hsac)]{sub n} (1) and [K{sub 2}(sac)]{sub n} (2) were obtained from acidic and alkaline solution. The 3D framework of 1 includes K(I) polyhedral rods and typical pairwise coaxial right- and left-handed helical chains, and displays binodal 6-connected pcu topology. 2 contains 2D polyhedral sheets consisting of left-handed helical chains, and generates 3D network with an unprecedented (7,11)-connected net. Cyclic voltammetry tests and charge-discharge tests indicate that the addition of complex 2 to the electrolyte could improve the electrochemical properties of the nickel hydroxide electrode. -- Graphical abstract: Two K(I) complexes based on D-saccharic acid (H{sub 2}sac), [K(Hsac)]{sub n} (1) and [K{sub 2}(sac)]{sub n} (2) were obtained and characterized. Electrochemical studies indicate the potential use of 2 in Ni-MH battery. Display Omitted highlights: > Two novel chiral K(I) frameworks based on D-saccharic acid were obtained. > The structure of 1 includes K(I) polyhedral rods and typical helical chains. > 2 contains 2D polyhedral sheets and generates an unprecedented (7,11)-connected net. > Addition of 2 to electrolyte could improve the nickel hydroxide electrode's property.

  10. Final Deactivation Project report on the Alpha Powder Facility, Building 3028, at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    1997-04-01

    This report documents the condition of the Alpha Powder Facility (APF), Building 3028, after completion of deactivation activities. Activities conducted to place the facility in a safe and environmentally sound condition for transfer to the U.S. Department of Energy (DOE) Office of Environmental Restoration (EM-40) program are outlined. A history and profile of the facility prior to commencing deactivation activities and a profile of the building after completion of deactivation activities are provided. Turnover items, such as the post-deactivation surveillance and maintenance (S&M) plan, remaining hazardous materials, radiological controls, safeguards and security, quality assurance, facility operations, and supporting documentation provided for in the DOE Nuclear Materials and Facility Stabilization Program (EM-60) turnover package are discussed.

  11. Ergonomics - Using Ergonomics to Enhance Safe Production at a Surface Coal Mine - A Case Study with Powder Crews

    SciTech Connect (OSTI)

    Torma-Krajewski, J.; Wiehagen, W.; Etcheverry, A.; Turin, F.; Unger, R.

    2009-07-01

    Job tasks that involve exposure to work-related musculoskeletal disorder (WMSD) risk factors may impact both the risk of injury and production downtime. Common WMSD risks factors associated with mining tasks include forceful exertions, awkward postures, repetitive motion, jolting and jarring, forceful gripping, contact stress, and whole body and segmental vibration. Mining environments that expose workers to temperature/humidity extremes, windy conditions, and slippery and uneven walking surfaces also contribute to injury risk. National Institute for Occupational Safety and Health (NIOSH) researchers worked with powder crew members from the Bridger Coal Company to identify and rank routine work tasks based on perceived exposure to WMSD risk factors. This article presents the process followed to identify tasks that workers believed involved the greatest exposure to risk factors and discusses risk reduction strategies. Specifically, the proposed prill truck design changes addressed cab ingress/egress, loading blast holes, and access to the upper deck of the prill truck.

  12. Calculations of single crystal elastic constants for yttria partially stabilised zirconia from powder diffraction data

    SciTech Connect (OSTI)

    Lunt, A. J. G. Xie, M. Y.; Baimpas, N.; Korsunsky, A. M.; Zhang, S. Y.; Kabra, S.; Kelleher, J.; Neo, T. K.

    2014-08-07

    Yttria Stabilised Zirconia (YSZ) is a tough, phase-transforming ceramic that finds use in a wide range of commercial applications from dental prostheses to thermal barrier coatings. Micromechanical modelling of phase transformation can deliver reliable predictions in terms of the influence of temperature and stress. However, models must rely on the accurate knowledge of single crystal elastic stiffness constants. Some techniques for elastic stiffness determination are well-established. The most popular of these involve exploiting frequency shifts and phase velocities of acoustic waves. However, the application of these techniques to YSZ can be problematic due to the micro-twinning observed in larger crystals. Here, we propose an alternative approach based on selective elastic strain sampling (e.g., by diffraction) of grain ensembles sharing certain orientation, and the prediction of the same quantities by polycrystalline modelling, for example, the Reuss or Voigt average. The inverse problem arises consisting of adjusting the single crystal stiffness matrix to match the polycrystal predictions to observations. In the present model-matching study, we sought to determine the single crystal stiffness matrix of tetragonal YSZ using the results of time-of-flight neutron diffraction obtained from an in situ compression experiment and Finite Element modelling of the deformation of polycrystalline tetragonal YSZ. The best match between the model predictions and observations was obtained for the optimized stiffness values of C11 = 451, C33 = 302, C44 = 39, C66 = 82, C12 = 240, and C13 = 50 (units: GPa). Considering the significant amount of scatter in the published literature data, our result appears reasonably consistent.

  13. Using corresponding state theory to obtain intermolecular potentials to calculate pure liquid shock Hugoniots

    SciTech Connect (OSTI)

    Hobbs, M.L.

    1997-12-01

    Determination of product species, equations-of-state (EOS) and thermochemical properties of high explosives and pyrotechnics remains a major unsolved problem. Although, empirical EOS models may be calibrated to replicate detonation conditions within experimental variability (5--10%), different states, e.g. expansion, may produce significant discrepancy with data if the basic form of the EOS model is incorrect. A more physically realistic EOS model based on intermolecular potentials, such as the Jacobs Cowperthwaite Zwisler (JCZ3) EOS, is needed to predict detonation states as well as expanded states. Predictive capability for any EOS requires a large species data base composed of a wide variety of elements. Unfortunately, only 20 species have known JCZ3 molecular force constants. Of these 20 species, only 10 have been adequately compared to experimental data such as molecular scattering or shock Hugoniot data. Since data in the strongly repulsive region of the molecular potential is limited, alternative methods must be found to deduce force constants for a larger number of species. The objective of the present study is to determine JCZ3 product species force constants by using a corresponding states theory. Intermolecular potential parameters were obtained for a variety of gas species using a simple corresponding states technique with critical volume and critical temperature. A more complex, four parameter corresponding state method with shape and polarity corrections was also used to obtain intermolecular potential parameters. Both corresponding state methods were used to predict shock Hugoniot data obtained from pure liquids. The simple corresponding state method is shown to give adequate agreement with shock Hugoniot data.

  14. Results of the 2013 UT modeling benchmark obtained with models implemented in CIVA

    SciTech Connect (OSTI)

    Toullelan, Gwénaël; Raillon, Raphaële; Chatillon, Sylvain; Lonne, Sébastien

    2014-02-18

    The 2013 Ultrasonic Testing (UT) modeling benchmark concerns direct echoes from side drilled holes (SDH), flat bottom holes (FBH) and corner echoes from backwall breaking artificial notches inspected with a matrix phased array probe. This communication presents the results obtained with the models implemented in the CIVA software: the pencilmodel is used to compute the field radiated by the probe, the Kirchhoff approximation is applied to predict the response of FBH and notches and the SOV (Separation Of Variables) model is used for the SDH responses. The comparison between simulated and experimental results are presented and discussed.

  15. Obtaining accurate amounts of mercury from mercury compounds via electrolytic methods

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1987-07-07

    A process is described for obtaining pre-determined, accurate rate amounts of mercury. In one embodiment, predetermined, precise amounts of Hg are separated from HgO and plated onto a cathode wire. The method for doing this involves dissolving a precise amount of HgO which corresponds to a pre-determined amount of Hg desired in an electrolyte solution comprised of glacial acetic acid and H[sub 2]O. The mercuric ions are then electrolytically reduced and plated onto a cathode producing the required pre-determined quantity of Hg. In another embodiment, pre-determined, precise amounts of Hg are obtained from Hg[sub 2]Cl[sub 2]. The method for doing this involves dissolving a precise amount of Hg[sub 2]Cl[sub 2] in an electrolyte solution comprised of concentrated HCl and H[sub 2]O. The mercurous ions in solution are then electrolytically reduced and plated onto a cathode wire producing the required, pre-determined quantity of Hg. 1 fig.

  16. Transient electron heat diffusivity obtained from trace impurity injection on TFTR

    SciTech Connect (OSTI)

    Kissick, M. W.; Fredrickson, E. D.; Callen, J. D.; Bush, C. E.; Chang, Z. Y.; Efthimion, P. C.; Hulse, R. A.; Mansfield, D. K.; Park, H. K.; Schivell, J.; Scott, S. D.; Synakowski, E. J.; Taylor, G.; Zarnstorff, M. C.

    1993-08-01

    A new method for obtaining a transient (``pulse``) electron heat diffusivity (?ep) in the radial region 0.38 < r/a < 0.56 in TFTR L-mode discharges is presented. Small electron temperature perturbations were caused by single bursts of injected impurities which radiated and cooled the plasma edge. An iron injection case by laser ablation was found to be more definitive than a supporting helium gas puff case. In this new ``cold pulse`` method, we concentrate on modeling just the electron temperature perturbations, tracked with ECE (electron cyclotron emission) diagnostics and on being able to justify separation in space and time from the cooling source. This ?ep is obtained for these two cases to be ?ep = (6.0m²/s ± 35%) ~ 4?e(power balance) which is consistent with, but more definitive than, results from other studies that are more susceptible to ambiguities in the source profile.

  17. Obtaining accurate amounts of mercury from mercury compounds via electrolytic methods

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

    1987-01-01

    A process for obtaining pre-determined, accurate rate amounts of mercury. In one embodiment, predetermined, precise amounts of Hg are separated from HgO and plated onto a cathode wire. The method for doing this involves dissolving a precise amount of HgO which corresponds to a pre-determined amount of Hg desired in an electrolyte solution comprised of glacial acetic acid and H.sub.2 O. The mercuric ions are then electrolytically reduced and plated onto a cathode producing the required pre-determined quantity of Hg. In another embodiment, pre-determined, precise amounts of Hg are obtained from Hg.sub.2 Cl.sub.2. The method for doing this involves dissolving a precise amount of Hg.sub.2 Cl.sub.2 in an electrolyte solution comprised of concentrated HCl and H.sub.2 O. The mercurous ions in solution are then electrolytically reduced and plated onto a cathode wire producing the required, pre-determined quantity of Hg.

  18. Heat-Rate Improvement Obtained by Retubing Power-Plant Condenser Enhanced Tubes

    Energy Science and Technology Software Center (OSTI)

    1994-01-21

    A utility will only retube a condenser with enhanced tubes if the incremental cost of the enhanced tubes can be offset with reduced fuel costs. The reduced fuel cost is obtained for some units because of the higher heat-transfer coefficient of enhanced tubes. They lead to improved condenser performance measured by a lower condenser pressure and therefore a more efficient power plant. However, the higher haet-transfer coefficients do not always guarantee that enhanced tubes willmore » be more cost effective. Other issues must be considered such as the cooling-water flow reduction due to the increased pressure drop, the low-pressure turbine heat-rate variation with backpressure, and the cooling-water pump and system characteristics. These and other parameters must be considered to calculate the efficiency improvement of the power plant as commonly measured by the quantity known as the heat rate. Knowing the heat-rate improvement, the fuel cost, and the incremental increase of the enhanced tubes from the supplier, the payback time can be determined. This program calculates the heat-rate improvement that can be obtained by retubing a power plant condenser with enhanced tubes of a particular type called Korodense LPD made by Wolverine Tube, Inc. The fuel savings are easily established knowing the heat-rate improvement. All electrical utilities are potential users because a condenser is used as the heat sink for every power plant.« less

  19. Quantitative Reflectance Spectra of Solid Powders as a Function of Particle Size

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Myers, Tanya L.; Brauer, Carolyn S.; Su, Yin-Fong; Blake, Thomas A.; Tonkyn, Russell G.; Ertel, Alyssa B.; Johnson, Timothy J.; Richardson, Robert L.

    2015-05-19

    We have recently developed vetted methods for obtaining quantitative infrared directional-hemispherical reflectance spectra using a commercial integrating sphere. In this paper, the effects of particle size on the spectral properties are analyzed for several samples such as ammonium sulfate, calcium carbonate, and sodium sulfate as well as one organic compound, lactose. We prepared multiple size fractions for each sample and confirmed the mean sizes using optical microscopy. Most species displayed a wide range of spectral behavior depending on the mean particle size. General trends of reflectance vs. particle size are observed such as increased albedo for smaller particles: for mostmore »wavelengths, the reflectivity drops with increased size, sometimes displaying a factor of 4 or more drop in reflectivity along with a loss of spectral contrast. In the longwave infrared, several species with symmetric anions or cations exhibited reststrahlen features whose amplitude was nearly invariant with particle size, at least for intermediate- and large-sized sample fractions; that is, > ~150 microns. Trends of other types of bands (Christiansen minima, transparency features) are also investigated as well as quantitative analysis of the observed relationship between reflectance vs. particle diameter.« less

  20. Establishment of Lipolexis oregmae (Hymenoptera: Aphidiidae) in a classical biological control program directed against the brown citrus aphid (Homoptera: Aphididae) in Florida

    SciTech Connect (OSTI)

    Persad, A.B.; Hoy, M.A.; Ru Nguyen

    2007-03-15

    The parasitoid Lipolexis oregmae Gahan (introduced as L. scutellaris Mackauer) was imported from Guam, evaluated in quarantine, mass reared, and released into citrus groves in Florida in a classical biological control program directed against the brown citrus aphid, Toxoptera citricida Kirkaldy. Releases of 20,200, 12,100, and 1,260 adults of L. oregmae were made throughout Florida during 2000, 2001, and 2002, respectively. To determine if L. oregmae had successfully established, surveys were conducted throughout the state beginning in the summer of 2001 and continuing through the summer of 2003. Parasitism during 2001 and 2002 was evaluated by holding brown citrus aphids in the laboratory until parasitoid adults emerged. Lipolexis oregmae was found in 10 sites in 7 counties and 4 sites in 3 counties with parasitism rates ranging from 0.7 to 3.3% in 2001 and 2002, respectively. Laboratory tests indicated that high rates of mortality occurred if field-collected parasitized aphids were held in plastic bags, so a molecular assay was used that allowed immature L. oregmae to be detected within aphid hosts immediately after collection. The molecular assay was used in 2003 with the brown citrus aphids and with other aphid species collected from citrus, weeds, and vegetables near former release sites; immatures of L. oregmae were detected in black citrus aphids, cowpea aphids, spirea aphids, and melon aphids, as well as in the brown citrus aphid, in 4 of 8 counties sampled, with parasitism ranging from 2.0 to 12.9%, indicating that L. oregmae is established and widely distributed. Samples taken in Polk County during Oct 2005 indicated that L. oregmae has persisted. The ability of L. oregmae to parasitize other aphid species on citrus, and aphids on other host plants, enhances the ability of L. oregmae to persist when brown citrus aphid populations are low. (author) [Spanish] El parasitoide Lipolexis oregmae Gahan (introducido como L. scutellaris Mackauer) fue importado de Guam, evaluado en cuarentena, criado en masa y liberado en huertos de citricos en un programa de control biologico clasico dirigido contra el afido pardo de citricos, Toxoptera citricida Kirkaldy. Se hicieron liberaciones de 20,200, 12,100, y 1,260 adultos de L. oregmae a traves de la Florida durante los anos de 2000, 2001, y 2002, respectivamente. Para determinar si L. oregmae ha logrado en establecer, se realizaron sondeos a traves del estado empezando en el verano del 2001 y continuando hasta el final del verano del 2003. El parasitismo durante 2001 y 2002 fue evaluado con el mantenimiento de individuos del afido pardo de los citricos en el laboratorio hasta que los adultos emergieron. Lipolexis oregmae fue encontrado en 10 sitios en 7 condados y con tasas de parasitismo en 4 sitios en 3 condados entre 0.7 a 3.3% en el 2001 y 2002, respectivamente. Las pruebas del laboratorio indicaron que las tasas altas de mortalidad fueron posibles si los afidos con parasitos recolectados en el campo fueron mantenidos en bolsas plasticas, entonces un ensayo molecular fue usado con lo que permitio la deteccion de inmaduros de L. oregmae dentro de los hospederos de afidos inmediatamente despues de la recoleccion. El ensayo molecular fue usado en el 2003 con individuos del afido pardo de los citricos y con otras especies de afidos recolectados sobre citricos, malezas y hortalizas cerca de los sitios donde los parasitoides fueron liberados anteriormente; inmaduros de L. oregmae fueron detectados en individuos del afido negro de los citricos, el afido del caupi, el afido spirea y el afido del melon, ademas del afido pardo de los citricos en 4 de los 8 condados muestreados, con la tasa del parasitismo entre 2.0 a12.9%, indicando que L. oregmae estaba estabecido y ampliamente distribuido. Las muestras tomadas en el Condado de Polk durante octobre del 2005 indicaron que L. oregmae ha persistido. La capacidad de L. oregmae para parasitar otras especies de afidos sobre citricos y otros afidos sobre otras plantas hospederas, incrementa la capacidad de L. oregmae para persistir cuand

  1. Process and apparatus for obtaining samples of liquid and gas from soil

    DOE Patents [OSTI]

    Rossabi, Joseph (105 Michael Ct., Aiken, SC 29801); May, Christopher P. (5002 Hesperus Dr., Columbia, MD 21044); Pemberton, Bradley E. (131 Glencarin Dr., Aiken, SC 29803); Shinn, Jim (Box 65, RFD. #1, South Royalton, VT 05068); Sprague, Keith (Box 234 Rte. 14, Brookfield, VT 05036)

    1999-01-01

    An apparatus and process for obtaining samples of liquid and gas from subsurface soil is provided having filter zone adjacent an external expander ring. The expander ring creates a void within the soil substrate which encourages the accumulation of soil-borne fluids. The fluids migrate along a pressure gradient through a plurality of filters before entering a first chamber. A one-way valve regulates the flow of fluid into a second chamber in further communication with a collection tube through which samples are collected at the surface. A second one-way valve having a reverse flow provides additional communication between the chambers for the pressurized cleaning and back-flushing of the apparatus.

  2. Process and apparatus for obtaining samples of liquid and gas from soil

    DOE Patents [OSTI]

    Rossabi, J.; May, C.P.; Pemberton, B.E.; Shinn, J.; Sprague, K.

    1999-03-30

    An apparatus and process for obtaining samples of liquid and gas from subsurface soil is provided having filter zone adjacent an external expander ring. The expander ring creates a void within the soil substrate which encourages the accumulation of soil-borne fluids. The fluids migrate along a pressure gradient through a plurality of filters before entering a first chamber. A one-way valve regulates the flow of fluid into a second chamber in further communication with a collection tube through which samples are collected at the surface. A second one-way valve having a reverse flow provides additional communication between the chambers for the pressurized cleaning and back-flushing of the apparatus. 8 figs.

  3. Composition and microstructure of zirconium and hafnium germanates obtained by different chemical routes

    SciTech Connect (OSTI)

    Utkin, A.V. Prokip, V.E.; Baklanova, N.I.

    2014-01-15

    The phase composition and morphology of zirconium and hafnium germanates synthesized by ceramic and co-precipitation routes were studied. The products were characterized using high-temperature X-ray diffraction analysis (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and thermal (TG/DTA) analysis. To investigate the phase composition and stoichiometry of compounds the unit cell parameters were refined by full-profile Rietveld XRD analysis. The morphology of products and its evolution during high-temperature treatment was examined by SEM analysis. It was stated that there is the strong dependence of the phase composition and morphology of products on the preparation route. The ceramic route requires a multi-stage high-temperature treatment to obtain zirconium and hafnium germanates of 95% purity or more. Also, there are strong diffusion limitations to obtain hafnium germanate Hf{sub 3}GeO{sub 8} by ceramic route. On the contrary, the co-precipitation route leads to the formation of nanocrystalline single phase germanates of stoichiometric composition at a relatively low temperatures (less than 1000 °C). The results of quantitative XRD analysis showed the hafnium germanates are stoichiometric compounds in contrast to zirconium germanates that form a set of solid solutions. This distinction may be related to the difference in the ion radii of Zr and Hf. - Graphical abstract: The phase composition and morphology of zirconium and hafnium germanates synthesized by ceramic and co-precipitation routes were studied. It was stated that there is the strong dependence of the phase composition and morphology of products on the preparation route. Display Omitted - Highlights: • Zr and Hf germanates were synthesized by ceramic and co-precipitation routes. • The morphology of products depends on the synthesis parameters. • Zirconium germanates forms a set of solid solutions. • Hafnium germanates are stoichiometric compounds.

  4. Analysis of the Quality of Information Obtained About Uterine Artery Embolization From the Internet

    SciTech Connect (OSTI)

    Tavare, Aniket N.; Alsafi, Ali Hamady, Mohamad S.

    2012-12-15

    Purpose: The Internet is widely used by patients to source health care-related information. We sought to analyse the quality of information available on the Internet about uterine artery embolization (UAE). Materials and Methods: We searched three major search engines for the phrase 'uterine artery embolization' and compiled the top 50 results from each engine. After excluding repeated sites, scientific articles, and links to documents, the remaining 50 sites were assessed using the LIDA instrument, which scores sites across the domains of accessibility, usability, and reliability. The Fleisch reading ease score (FRES) was calculated for each of the sites. Finally, we checked the country of origin and the presence of certification by the Health On the Net Foundation (HONcode) as well as their effect on LIDA and FRES scores.ResultsThe following mean scores were obtained: accessibility 48/60 (80%), usability 42/54 (77%), reliability 20/51 (39%), total LIDA 110/165 (67%), and FRES 42/100 (42%). Nine sites had HONcode certification, and this was associated with significantly greater (p < 0.05) reliability and total LIDA and FRES scores. When comparing sites between United Kingdom and United States, there was marked variation in the quality of results obtained when searching for information on UAE (p < 0.05). Conclusion: In general, sites were well designed and easy to use. However, many scored poorly on the reliability of their information either because they were produced in a non-evidence-based way or because they lacking currency. It is important that patients are guided to reputable, location-specific sources of information online, especially because prominent search engine rank does not guarantee reliability of information.

  5. Casingless down-hole for sealing an ablation volume and obtaining a sample for analysis

    DOE Patents [OSTI]

    Noble, Donald T. (Ames, IA); Braymen, Steven D. (Ames, IA); Anderson, Marvin S. (Ames, IA)

    1996-10-01

    A casing-less down hole sampling system for acquiring a subsurface sample for analysis using an inductively coupled plasma system is disclosed. The system includes a probe which is pushed into the formation to be analyzed using a hydraulic ram system. The probe includes a detachable tip member which has a soil point mad a barb, with the soil point aiding the penetration of the earth, and the barb causing the tip member to disengage from the probe and remain in the formation when the probe is pulled up. The probe is forced into the formation to be tested, and then pulled up slightly, to disengage the tip member and expose a column of the subsurface formation to be tested. An instrumentation tube mounted in the probe is then extended outward from the probe to longitudinally extend into the exposed column. A balloon seal mounted on the end of the instrumentation tube allows the bottom of the column to be sealed. A source of laser radiation is emitted from the instrumentation tube to ablate a sample from the exposed column. The instrumentation tube can be rotated in the probe to sweep the laser source across the surface of the exposed column. An aerosol transport system carries the ablated sample from the probe to the surface for testing in an inductively coupled plasma system. By testing at various levels in the down-hole as the probe is extracted from the soil, a profile of the subsurface formation may be obtained.

  6. Qualification of data obtained during a severe accident. Illustrative examples from TMI-2 evaluations

    SciTech Connect (OSTI)

    Rempe, Joy L.; Knudson, Darrell L.

    2015-02-01

    The accidents at the Three Mile Island Unit 2 (TMI-2) Pressurized Water Reactor (PWR) and the Daiichi Units 1, 2, and 3 Boiling Water Reactors (BWRs) provide unique opportunities to evaluate instrumentation exposed to severe accident conditions. Conditions associated with the release of coolant and the hydrogen burn that occurred during the TMI-2 accident exposed instrumentation to harsh conditions, including direct radiation, radioactive contamination, and high humidity with elevated temperatures and pressures. Post-TMI-2 instrumentation evaluation programs focused on data required by TMI-2 operators to assess the condition of the reactor and containment and the effect of mitigating actions taken by these operators. Prior efforts also focused on sensors providing data required for subsequent forensic evaluations and accident simulations. This paper provides additional details related to the formal process used to develop a qualified TMI-2 data base and presents data qualification details for three parameters: reactor coolant system (RCS) pressure; containment building temperature; and containment pressure. These selected examples illustrate the types of activities completed in the TMI-2 data qualification process and the importance of such a qualification effort. These details are described to facilitate implementation of a similar process using data and examinations at the Daiichi Units 1, 2, and 3 reactors so that BWR-specific benefits can be obtained.

  7. Casingless down-hole for sealing an ablation volume and obtaining a sample for analysis

    DOE Patents [OSTI]

    Noble, D.T.; Braymen, S.D.; Anderson, M.S.

    1996-10-01

    A casing-less down hole sampling system for acquiring a subsurface sample for analysis using an inductively coupled plasma system is disclosed. The system includes a probe which is pushed into the formation to be analyzed using a hydraulic ram system. The probe includes a detachable tip member which has a soil point and a barb, with the soil point aiding the penetration of the earth, and the barb causing the tip member to disengage from the probe and remain in the formation when the probe is pulled up. The probe is forced into the formation to be tested, and then pulled up slightly, to disengage the tip member and expose a column of the subsurface formation to be tested. An instrumentation tube mounted in the probe is then extended outward from the probe to longitudinally extend into the exposed column. A balloon seal mounted on the end of the instrumentation tube allows the bottom of the column to be sealed. A source of laser radiation is emitted from the instrumentation tube to ablate a sample from the exposed column. The instrumentation tube can be rotated in the probe to sweep the laser source across the surface of the exposed column. An aerosol transport system carries the ablated sample from the probe to the surface for testing in an inductively coupled plasma system. By testing at various levels in the down-hole as the probe is extracted from the soil, a profile of the subsurface formation may be obtained. 9 figs.

  8. Apparatus for transmitting power obtained by converting the exhaust energy of an engine

    SciTech Connect (OSTI)

    Miyajima, H.

    1988-08-30

    This patent describes an apparatus for transmitting power obtained by converting the exhaust energy of a primary engine, the primary engine having a crank shaft and an exhaust passage for passing exhaust gas from the engine. The apparatus consists of: an output turbine having an output shaft and an intake port coupled to the exhaust passage; a compressor mounted on the output shaft of the turbine and including an outlet port; a rotary type engine having a double jointed trochoidal shaped rotor housing, the housing having an expansion chamber with an intake port and an outlet port and a compression chamber, the engine further comprising an eccentrically rotatable generally triangular shaped rotor mounted within the housing and a rotor shaft coupled to the rotor. The outlet port of the compressor is coupled to the intake port of the expansion chamber, the outlet port of the expansion chamber being coupled to the intake port of the output turbine; and power transmitting means connected between the crank shaft of the primary engine and the rotor shaft of the rotary engine whereby auxiliary power is provided to the primary engine.

  9. Preparation of Al{sub 2}O{sub 3}/Mo nanocomposite powder via chemical route and spray drying

    SciTech Connect (OSTI)

    Lo, M.; Cheng, F.; Wei, W.J.

    1996-08-01

    A route to prepare nanometer-sized Mo particulates in Al{sub 2}O{sub 3} was attempted by a combination of solution reactions in molecular scale and forcing precipitation by a spray-drying technique. MoO{sub 3} was first dissolved in ammonia water and then added in the slurry with high purity, submicrometer Al{sub 2}O{sub 3} powder. Mixed suspension was spray-dried, and then the dried granules were reduced by hydrogen gas and further hot-pressing to a bulky composite at various temperatures. Dissolution of Mo oxide, adsorption reactions on alumina surface, and surface potential of alumina particles in homogeneous ammonia suspension were studied. Characterization of the granules, including compactability, flowing properties, surface morphology, grain growth of Mo and Al{sub 2}O{sub 3}, and mixing homogeneity, were examined. Homogeneity of the spray-dried granules was determined by the calculation of mixing index and the observation of the microstructure of sintered body. The existence of intergranular, intragranular, and nanosized Mo particulates within Al{sub 2}O{sub 3} grains was observed by transmission electron microscopy (TEM). All the evidences revealed that homogeneous composites with nanometer-sized Mo had been successfully prepared by this attempt with the proposed chemical route and following spray-drying process. {copyright}{ital 1996 Materials Research Society.}

  10. Health hazard evaluation report HETA 85-060-1670, City of Norwood, Norwood, Ohio. [Toner powder exposure

    SciTech Connect (OSTI)

    Ruhe, R.L.; Bennett, D.

    1986-02-01

    Following a request from the Health Commissioner of Norwood, Ohio, employee exposure to toner powder used in Norwood Senior High Media Center photocopying machine was investigated. Personal and area air samples for total particulates were collected on preweighed filters and total sample weights determined. Indicator tube sampling was done for carbon monoxide and ozone. Medical interviews were conducted with three media center workers to elicit work related symptomatology. Exposure to total particulate ranged from less than the detection limit to 0.02 mg/m/sup 3/. Carbon monoxide and ozone were nondetectable. Two employees reported no symptoms associated with work. After operating the copy machine for 3 weeks, the third employee developed hives on both hands progressing to the earlobes and right cheek. Her condition improved on weekends. She also had a cough and shortness of breath when working with the duplicator. No positive response to patch testing was seen, but the employee developed cough, tearing eyes, and itching 2 hours after patch application. The authors conclude that one employee suffered an allergic reaction precipitated by materials inhaled in the duplicator area. It is recommended that this employee not use this machine, and improved ventilation be provided for the entire media center.

  11. Evaluation of biological treatment of pharmaceutical waste water with PAC (powdered activated carbon) addition. Volume 1. Final report

    SciTech Connect (OSTI)

    Gardner, D.A.; Osantowski, R.A.

    1988-05-01

    A lack of information on applicable removal technologies for total chemical oxygen demand (TCOD) prevented promulgation of best available technology economically achievable (BAT) limitations and new source performance standards (NSPS) for TCOD for pharmaceutical manufacturing plants in 1983 (EPA/440/1-83/084). One technology that was evaluated was powdered activated carbon (PAC) addition to an activated-sludge system (PACT*). A viscous floating mass of mixed-liquor solids (VFMLS) developed in the PACT units and resulted in premature termination of the study. The purposes of the study were to: (1) attempt to find the cause of the formation of the VFMLS; (2) generate additional research data for TCOD removal from pharmaceutical waste water using the PACT process; (3) evaluate the efficiency of PACT in removing specific organics; (4) evaluate the effectiveness of PACT in reducing effluent aquatic toxicity and (5) evaluate the use of a selector to improve the settleability of the mixed liquor. One control unit, two PACT units and a unit equipped with a series of selector basins for improving the settling characteristics of the mixed-liquor suspended solids were operated.

  12. AB INITIO EQUATIONS OF STATE FOR HYDROGEN (H-REOS.3) AND HELIUM (He-REOS.3) AND THEIR IMPLICATIONS FOR THE INTERIOR OF BROWN DWARFS

    SciTech Connect (OSTI)

    Becker, Andreas; Lorenzen, Winfried; Schöttler, Manuel; Redmer, Ronald; Fortney, Jonathan J.; Nettelmann, Nadine

    2015-01-01

    We present new equations of state (EOSs) for hydrogen and helium covering a wide range of temperatures from 60 K to 10{sup 7} K and densities from 10{sup –10} g cm{sup –3} to 10{sup 3} g cm{sup –3}. They include an extended set of ab initio EOS data for the strongly correlated quantum regime with an accurate connection to data derived from other approaches for the neighboring regions. We compare linear mixing isotherms based on our EOS tables with available real mixture data. A first important astrophysical application of this new EOS data is the calculation of interior models for Jupiter and comparison with recent results. Second, mass-radius relations are calculated for Brown Dwarfs (BDs) which we compare with predictions derived from the widely used EOS of Saumon, Chabrier, and van Horn. Furthermore, we calculate interior models for typical BDs with different masses, namely, Corot-3b, Gliese-229b, and Corot-15b, and the giant planet KOI-889b. The predictions for the central pressures and densities differ by up to 10% dependent on the EOS used. Our EOS tables are made available in the supplemental material of this paper.

  13. Effects of Flaming Gorge Dam hydropower operations on sediment transport in the Browns Park reach of the Green River, Utah and Colorado

    SciTech Connect (OSTI)

    Williams, G.P.; Tomasko, D.; Cho, H.E.; Yin, S.C.L.

    1995-05-01

    Three methods for comparing sediment transport were applied to four proposed hydropower operational scenarios under study for Flaming Gorge Dam on the Green River in Utah. These methods were effective discharge, equilibrium potential, and cumulative sediment load with flow exceedance plots. Sediment loads transported by the Green River in the Browns Park reach were calculated with the Engelund-Hansen equation for three historical water years and four hydropower operational scenarios. A model based on the Engelund-Hansen equation was developed using site-specific information and validated by comparing predictions for a moderate water year with measured historical values. The three methods were used to assess the impacts of hydropower operational scenarios on sediment resources. The cumulative sediment load method provided the most useful information for impact evaluation. Effective discharge was not a useful tool because of the limited number of discrete flows associated with synthetic hydrographs for the hydropower operational scenarios. The equilibrium potential method was relatively insensitive to the variations in operating conditions, rendering it comparatively ineffective for impact evaluation.

  14. A NEW METHOD FOR OBTAINING THE STAR FORMATION LAW IN GALAXIES

    SciTech Connect (OSTI)

    Heiner, Jonathan S.; Allen, Ronald J.; Van der Kruit, Pieter C.

    2010-08-20

    We present a new observational method to evaluate the exponent of the star formation law as initially formulated by Schmidt, i.e., the power-law expression assumed to relate the rate of star formation in a volume of space to the local total gas volume density present there. Total volume densities in the gas clouds surrounding an OB association are determined with a simple model which considers the atomic hydrogen as a photodissociation product on the cloud surfaces. The photodissociating photon flux incident on the cloud is computed from the far-UV luminosity of the OB association and the geometry. As an example, we have applied this 'PDR Method' to a sample of star-forming regions in M33 using Very Large Array (VLA) 21 cm data for the H I and Galaxy Evolution Explorer (GALEX) imagery in the far-UV. With these two observables, our approach provides an estimate of the total volume density of hydrogen (atomic + molecular) in the gas clouds surrounding the young star cluster. A graph in logarithmic coordinates of the cluster UV luminosity versus the total density in the surrounding gas provides a direct measure of the exponent of the star formation law. However, we show that this plot is severely affected by observational selection, which renders large areas of the diagram inaccessible to the data. An ordinary least-squares regression fit to a straight line, therefore, gives a strongly biased result. In the present case, the slope of such a fit primarily reflects the boundary defined when the 21 cm line becomes optically thick and is no longer a reliable measure of the H I column density. We use a maximum likelihood statistical approach which can deal with truncated and skewed data, and also takes account of the large uncertainties in the total gas densities which we derive. The exponent we obtain for the Schmidt law in M33 is 1.4 {+-} 0.2.

  15. Development of a general method for obtaining the geometry of microfluidic networks

    SciTech Connect (OSTI)

    Razavi, Mohammad Sayed Salimpour, M. R.; Shirani, Ebrahim

    2014-01-15

    In the present study, a general method for geometry of fluidic networks is developed with emphasis on pressure-driven flows in the microfluidic applications. The design method is based on general features of network's geometry such as cross-sectional area and length of channels. Also, the method is applicable to various cross-sectional shapes such as circular, rectangular, triangular, and trapezoidal cross sections. Using constructal theory, the flow resistance, energy loss and performance of the network are optimized. Also, by this method, practical design strategies for the fabrication of microfluidic networks can be improved. The design method enables rapid prediction of fluid flow in the complex network of channels and is very useful for improving proper miniaturization and integration of microfluidic networks. Minimization of flow resistance of the network of channels leads to universal constants for consecutive cross-sectional areas and lengths. For a Y-shaped network, the optimal ratios of consecutive cross-section areas (A{sub i+1}/A{sub i}) and lengths (L{sub i+1}/L{sub i}) are obtained as A{sub i+1}/A{sub i} = 2{sup ?2/3} and L{sub i+1}/L{sub i} = 2{sup ?1/3}, respectively. It is shown that energy loss in the network is proportional to the volume of network. It is also seen when the number of channels is increased both the hydraulic resistance and the volume occupied by the network are increased in a similar manner. Furthermore, the method offers that fabrication of multi-depth and multi-width microchannels should be considered as an integral part of designing procedures. Finally, numerical simulations for the fluid flow in the network have been performed and results show very good agreement with analytic results.

  16. Additive Manufacturing/Diagnostics via the High Frequency Induction Heating of Metal Powders: The Determination of the Power Transfer Factor for Fine Metallic Spheres

    SciTech Connect (OSTI)

    Rios, Orlando; Radhakrishnan, Balasubramaniam; Caravias, George; Holcomb, Matthew

    2015-03-11

    Grid Logic Inc. is developing a method for sintering and melting fine metallic powders for additive manufacturing using spatially-compact, high-frequency magnetic fields called Micro-Induction Sintering (MIS). One of the challenges in advancing MIS technology for additive manufacturing is in understanding the power transfer to the particles in a powder bed. This knowledge is important to achieving efficient power transfer, control, and selective particle heating during the MIS process needed for commercialization of the technology. The project s work provided a rigorous physics-based model for induction heating of fine spherical particles as a function of frequency and particle size. This simulation improved upon Grid Logic s earlier models and provides guidance that will make the MIS technology more effective. The project model will be incorporated into Grid Logic s power control circuit of the MIS 3D printer product and its diagnostics technology to optimize the sintering process for part quality and energy efficiency.

  17. Neutron powder diffraction analysis of (Tm{sub 0.50}Ca{sub 0.50})MnO{sub 3}

    Office of Scientific and Technical Information (OSTI)

    and (Lu{sub 0.50}Ca{sub 0.50})MnO{sub 3} (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Neutron powder diffraction analysis of (Tm{sub 0.50}Ca{sub 0.50})MnO{sub 3} and (Lu{sub 0.50}Ca{sub 0.50})MnO{sub 3} Citation Details In-Document Search Title: Neutron powder diffraction analysis of (Tm{sub 0.50}Ca{sub 0.50})MnO{sub 3} and (Lu{sub 0.50}Ca{sub 0.50})MnO{sub 3} The crystal and magnetic structures of (Tm{sub 0.50}Ca{sub 0.50})MnO{sub 3} and (Lu{sub

  18. Zero discharge organic coatings, powder paint - UV curable paint - E-coat. Appendixes. Volume 2. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    1995-06-01

    ZDOC project funded under the Advanced Research Projects Agency (ARPA) includes an effort to evaluate and develop infrared curing techniques for powder coatings. IR curing is attractive because of increased throughput as compared to conventional thermal methods, and because it may offer certain advantages in specific applications. For example, IR curing might lead to less substrate heating, which is a concern with some high-performance materials (such as aluminum in heat-sensitive tempers) used in industry.

  19. Scale-Up of Palladium Powder Production Process for Use in the Tritium Facility at Westinghouse, Savannah River, SC/Summary of FY99-FY01 Results for the Preparation of Palladium Using the Sandia/LANL Process

    SciTech Connect (OSTI)

    David P. Baldwin; Daniel S. Zamzow; R. Dennis Vigil; Jesse T. Pikturna

    2001-08-24

    Palladium used at Savannah River (SR) for process tritium storage is currently obtained from a commercial source. In order to understand the processes involved in preparing this material, SR is supporting investigations into the chemical reactions used to synthesize this material. The material specifications are shown in Table 1. An improved understanding of the chemical processes should help to guarantee a continued reliable source of Pd in the future. As part of this evaluation, a work-for-others contract between Westinghouse Savannah River Company and Ames Laboratory (AL) was initiated. During FY98, the process for producing Pd powder developed in 1986 by Dan Grove of Mound Applied Technologies, USDOE (the Mound muddy water process) was studied to understand the processing conditions that lead to changes in morphology in the final product. During FY99 and FY00, the process for producing Pd powder that has been used previously at Sandia and Los Alamos National Laboratories (the Sandia/LANL process) was studied to understand the processing conditions that lead to changes in the morphology of the final Pd product. During FY01, scale-up of the process to batch sizes greater than 600 grams of Pd using a 20-gallon Pfaudler reactor was conducted by the Iowa State University (ISU) Chemical Engineering Department. This report summarizes the results of FY99-FY01 Pd processing work done at AL and ISU using the Sandia/LANL process. In the Sandia/LANL process, Pd is dissolved in a mixture of nitric and hydrochloric acids. A number of chemical processing steps are performed to yield an intermediate species, diamminedichloropalladium (Pd(NH{sub 3}){sub 2}Cl{sub 2}, or DADC-Pd), which is isolated. In the final step of the process, the Pd(NH{sub 3}){sub 2}Cl{sub 2} intermediate is subsequently redissolved, and Pd is precipitated by the addition of a reducing agent (RA) mixture of formic acid and sodium formate. It is at this point that the morphology of the Pd product is determined. During FY99 and FY00, a study of how the characteristics of the Pd are affected by changes in processing conditions including the RA/Pd molar ratio, Pd concentration, mole fraction of formic acid (mf-FA) in the RA solution, reaction temperature, and mixing was performed. These parameters all had significant effects on the resulting values of the tap density (TD), BET surface area (SA), and Microtrac particle size (PS) distribution for the Pd samples. These effects were statistically modeled and fit in order to determine ranges of predicted experimental conditions that resulted in material that meets the requirements for the Pd powder to be used at SR. Although not statistically modeled, the method and rate of addition of the RA and the method and duration of stirring were shown to be significant factors affecting the product morphology. Instead of producing an additional statistical fit and due to the likely changes anticipated during scale-up of this processing procedure, these latter conditions were incorporated into a reproducible practical method of synthesis. Palladium powder that met the SR specifications for TD, BET SA, and Microtrac PS was reliably produced at batch sizes ranging from 25-100 grams. In FY01, scale-up of the Sandia/LANL process was investigated by the ISU Chemical Engineering Department for the production of 600-gram batches of Pd. Palladium that meets the SR specifications for TD, BET SA, and Microtrac PS has been produced using the Pfaudler reactor, and additional processing batches will be done during the remainder of FY01 to investigate the range of conditions that can be used to produce Pd powder within specifications. Palladium product samples were analyzed at AL and SR to determine TD and at SR to determine BET SA, Microtrac PS distribution, and Pd nodule size and morphology by scanning electron microscopy (SEM).

  20. Doping and electronic properties of GaAs grown by close-spaced vapor transport from powder sources for scalable III–V photovoltaics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ritenour, Andrew J.; Boucher, Jason W.; DeLancey, Robert; Greenaway, Ann L.; Aloni, Shaul; Boettcher, Shannon W.

    2014-09-01

    We report the use of a simple close-spaced vapor transport technique for the growth of high-quality epitaxial GaAs films using potentially inexpensive GaAs powders as precursors. The free carrier type and density (1016 to 1019 cm–3) of the films were adjusted by addition of Te or Zn powder to the GaAs source powder. We show using photoelectrochemical and electron beam-induced current analyses that the minority carrier diffusion lengths of the n- and p-GaAs films reached ~3 μm and ~8 μm, respectively. Hall mobilities approach those achieved for GaAs grown by metal–organic chemical vapor deposition, 1000–4200 cm2 V–1 s–1 for n-GaAsmore » and 50–240 cm V–1 s–1 for p-GaAs depending on doping level. We conclude that the electronic quality of GaAs grown by close-spaced vapor transport is similar to that of GaAs made using conventional techniques and is thus sufficient for high-performance photovoltaic applications.« less

  1. Doping and electronic properties of GaAs grown by close-spaced vapor transport from powder sources for scalable III–V photovoltaics

    SciTech Connect (OSTI)

    Ritenour, Andrew J.; Boucher, Jason W.; DeLancey, Robert; Greenaway, Ann L.; Aloni, Shaul; Boettcher, Shannon W.

    2014-09-01

    We report the use of a simple close-spaced vapor transport technique for the growth of high-quality epitaxial GaAs films using potentially inexpensive GaAs powders as precursors. The free carrier type and density (1016 to 1019 cm–3) of the films were adjusted by addition of Te or Zn powder to the GaAs source powder. We show using photoelectrochemical and electron beam-induced current analyses that the minority carrier diffusion lengths of the n- and p-GaAs films reached ~3 ?m and ~8 ?m, respectively. Hall mobilities approach those achieved for GaAs grown by metal–organic chemical vapor deposition, 1000–4200 cm2 V–1 s–1 for n-GaAs and 50–240 cm V–1 s–1 for p-GaAs depending on doping level. We conclude that the electronic quality of GaAs grown by close-spaced vapor transport is similar to that of GaAs made using conventional techniques and is thus sufficient for high-performance photovoltaic applications.

  2. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    SciTech Connect (OSTI)

    Smith, V.E.; Merriam, N.W.

    1994-10-01

    Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

  3. U-163: PHP Command Parameter Bug Lets Remote Users Obtain Potentially Sensitive Information and Execute Arbitrary Code

    Broader source: Energy.gov [DOE]

    A vulnerability was reported in PHP. A remote user can obtain potentially sensitive information. A remote user can execute arbitrary code on the target system.

  4. HST Rotational Spectral Mapping Of Two L-Type Brown Dwarfs: Variability In And Out Of Water Bands Indicates High-Altitude Haze Layers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Hao; Apai, Dániel; Marley, Mark S.; Saumon, Didier; Morley, Caroline V.; Buenzli, Esther; Artigau, Étienne; Radigan, Jacqueline; Metchev, Stanimir; Burgasser, Adam J.; et al

    2014-12-17

    We present time-resolved near-infrared spectroscopy of two L5 dwarfs, 2MASS J18212815+1414010 and 2MASS J15074759-1627386, observed with the Wide Field Camera 3 instrument on the Hubble Space Telescope (HST). We study the wavelength dependence of rotation-modulated flux variations between 1.1 μm and 1.7 μm. We find that the water absorption bands of the two L5 dwarfs at 1.15 μm and 1.4 μm vary at similar amplitudes as the adjacent continuum. This differs from the results of previous HST observations of L/T transition dwarfs, in which the water absorption at 1.4 μm displays variations of about half of the amplitude at othermore » wavelengths. We find that the relative amplitude of flux variability out of the water band with respect to that in the water band shows a increasing trend from the L5 dwarfs toward the early T dwarfs. We utilize the models of Saumon & Marley (2008) and find that the observed variability of the L5 dwarfs can be explained by the presence of spatially varying high-altitude haze layers above the condensate clouds. Therefore, our observations show that the heterogeneity of haze layers - the driver of the variability - must be located at very low pressures, where even the water opacity is negligible. In the near future, the rotational spectral mapping technique could be utilized for other atomic and molecular species to probe different pressure levels in the atmospheres of brown dwarfs and exoplanets and uncover both horizontal and vertical cloud structures.« less

  5. Apparatus for coating powders

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Kerns, John A. (Livermore, CA); Alford, Craig S. (Tracy, CA); McKernan, Mark A. (Livermore, CA)

    2000-01-01

    A process and apparatus for coating small particles and fibers. The process involves agitation by vibrating or tumbling the particles or fibers to promote coating uniformly, removing adsorbed gases and static charges from the particles or fibers by an initial plasma cleaning, and coating the particles or fibers with one or more coatings, a first coating being an adhesion coating, and with subsequent coatings being deposited in-situ to prevent contamination at layer interfaces. The first coating is of an adhesion forming element (i.e. W, Zr, Re, Cr, Ti) of a 100-10,000 .ANG. thickness and the second coating or final coating of a multiple (0.1-10 microns) being Cu or Ag, for example for brazing processes, or other desired materials that defines the new surface related properties of the particles. An essential feature of the coating process is the capability to deposit in-situ without interruption to prevent the formation of a contaminated interface that could adversely affect the coating adhesion. The process may include screening of the material to be coated and either continuous or intermittent vibration to prevent agglomeration of the material to be coated.

  6. Photo-catalytic oxidation of acetone on a TiO2 powder: An in situ FTIR investigation

    SciTech Connect (OSTI)

    Szanyi, Janos; Kwak, Ja Hun

    2015-09-01

    In situ transmission infrared spectroscopy was used to investigate the photo-oxidation of acetone on a commercial, oxidized TiO2 (P25) powder catalyst under UV irradiation at ambient temperature, in the absence and presence of gas phase O2. The photochemistry of a number of organic molecules (1-butanone, methanol and acetic acid,) under the same conditions was also studied in order to identify reaction intermediates and products formed in the photo-oxidation of acetone. Under anaerobic conditions (in the absence of gas phase oxygen) limited extent of photo-oxidation of acetone took place on the oxidized TiO2 sample. In the presence of O2 in the gas phase, however, acetone was completely converted to acetates and formates, and ultimately CO2. The initial step in the sequence of photo-induced reactions is the ejection of a methyl radical, resulting in the formation of surface acetates (from the acetyl group) and formates (from the methyl radicals). Acetate ions are also converted to formates, that, in turn, photo-oxidized to CO2. Under the experimental conditions applied the accumulation of carbonates and bicarbonates were observed on the TiO2 surface as the photo-oxidation of acetone proceeded (this was also observed during the course of photo-oxidation of all the other organics studied here). When the initial radical ejection step produced hydrocarbons containing more than one C atoms (as in the case in 2-butanone and mesytil oxide), the formation of aldehydes on the catalyst surface was also observed as a result of secondary reactions. This work was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. JHK also acknowledges the support of this work by the 2014 Research Fund of UNIST (Ulsan National Institute of Science and Technology, Ulsan, Korea). The authors thank M.A. Henderson for the fruitful discussions on the photo-oxidation of organic molecules on TiO2.

  7. The effect of different annealing temperatures on tin and cadmium telluride phases obtained by a modified chemical route

    SciTech Connect (OSTI)

    Mesquita, Anderson Fuzer; Porto, Arilza de Oliveira; Magela de Lima, Geraldo; Paniago, Roberto; Ardisson, José Domingos

    2012-11-15

    Graphical abstract: Display Omitted Highlights: ? Synthesis of cadmium and tin telluride. ? Chemical route to obtain pure crystalline cadmium and tin telluride. ? Effect of the annealing temperature on the crystalline phases. ? Removal of tin oxide as side product through thermal treatment. -- Abstract: In this work tin and cadmium telluride were prepared by a modification of a chemical route reported in the literature to obtain metallacycles formed by oxidative addition of tin-tellurium bonds to platinum (II). Through this procedure it was possible to obtain tin and cadmium telluride. X-ray diffraction and X-ray photoelectron spectroscopy were used to identify the crystalline phases obtained as well as the presence of side products. In the case of tin telluride it was identified potassium chloride, metallic tellurium and tin oxide as contaminants. The tin oxidation states were also monitored by {sup 119}Sn Mössbauer spectroscopy. The annealing in hydrogen atmosphere was chosen as a strategy to reduce the tin oxide and promote its reaction with the excess of tellurium present in the medium. The evolution of this tin oxide phase was studied through the annealing of the sample at different temperatures. Cadmium telluride was obtained with high degree of purity (98.5% relative weight fraction) according to the Rietveld refinement of X-ray diffraction data. The modified procedure showed to be very effective to obtain amorphous tin and cadmium telluride and the annealing at 450 °C has proven to be useful to reduce the amount of oxide produced as side product.

  8. The effects of overwinter flowson the spring condition of rainbow and brown trout size classes in the Green River downstream of Flaming Gorge Dam, Utah.

    SciTech Connect (OSTI)

    Magnusson, A. K.; LaGory, K. E.; Hayse, J. W.; Environmental Science Division

    2010-06-25

    Flaming Gorge Dam, a hydroelectric facility operated by the Bureau of Reclamation (Reclamation), is located on the Green River in Daggett County, northeastern Utah. Until recently, and since the early 1990s, single daily peak releases or steady flows have been the operational pattern of the dam during the winter period. However, releases from Flaming Gorge Reservoir followed a double-peak pattern (two daily flow peaks) during the winters of 2006-2007 and 2008-2009. Because there is little recent long-term history of double-peaking at Flaming Gorge Dam, the potential effects of double-peaking operations on trout body condition in the dam's tailwater are not known. A study plan was developed that identified research activities to evaluate potential effects from winter double-peaking operations (Hayse et al. 2009). Along with other tasks, the study plan identified the need to conduct a statistical analysis of historical trout condition and macroinvertebrate abundance to evaluate the potential effects of hydropower operations. The results from analyses based on the combined size classes of trout (85-630 mm) were presented in Magnusson et al. (2008). The results of this earlier analysis suggested possible relationships between trout condition and flow, but concern that some of the relationships resulted from size-based effects (e.g., apparent changes in condition may have been related to concomitant changes in size distribution, because small trout may have responded differently to flow than large trout) prompted additional analysis of within-size class relationships. This report presents the results of analyses of three different size classes of trout (small: 200-299 mm, medium: 300-399 mm, and large: {ge}400 mm body length). We analyzed historical data to (1) describe temporal patterns and relationships among flows, benthic macroinvertebrate abundance, and condition of brown trout (Salmo trutta) and rainbow trout (Oncorhynchus mykiss) in the tailwaters of Flaming Gorge Dam, and to (2) evaluate the relative importance of the effects of flow (i.e., flow volumes and flow variability), trout abundance (catch per unit effort [CPUE]), and benthic macroinvertebrate abundance on trout condition for different size classes of trout.

  9. Detection of rare earth elements in Powder River Basin sub-bituminous coal ash using laser-induced breakdown spectroscopy (LIBS)

    SciTech Connect (OSTI)

    Tran, Phuoc

    2015-10-01

    We reported our preliminary results on the use of laser-induced breakdown spectroscopy to analyze the rare earth elements contained in ash samples from Powder River Basin sub-bituminous coal (PRB-coal). We have identified many elements in the lanthanide series (cerium, europium, holmium, lanthanum, lutetium, praseodymium, promethium, samarium, terbium, ytterbium) and some elements in the actinide series (actinium, thorium, uranium, plutonium, berkelium, californium) in the ash samples. In addition, various metals were also seen to present in the ash samples

  10. Superhydrophobic powder additives to enhance chemical agent resistant coating systems for military equipment for the U.S. Marine Corps (USMC) Corrosion Prevention and Control (CPAC) Program

    SciTech Connect (OSTI)

    Pawel, Steven J.; Armstrong, Beth L.; Haynes, James A.

    2015-07-01

    The primary goal of the CPAC program at ORNL was to explore the feasibility of introducing various silica-based superhydrophobic (SH) powder additives as a way to improve the corrosion resistance of US Department of Defense (DOD) military-grade chemical agent resistant coating (CARC) systems. ORNL had previously developed and patented several SH technologies of interest to the USMC, and one of the objectives of this program was to identify methods to incorporate these technologies into the USMC’s corrosion-resistance strategy. This report discusses findings of the CPAC and their application.

  11. Method and apparatus for obtaining stack traceback data for multiple computing nodes of a massively parallel computer system

    DOE Patents [OSTI]

    Gooding, Thomas Michael (Rochester, MN); McCarthy, Patrick Joseph (Rochester, MN)

    2010-03-02

    A data collector for a massively parallel computer system obtains call-return stack traceback data for multiple nodes by retrieving partial call-return stack traceback data from each node, grouping the nodes in subsets according to the partial traceback data, and obtaining further call-return stack traceback data from a representative node or nodes of each subset. Preferably, the partial data is a respective instruction address from each node, nodes having identical instruction address being grouped together in the same subset. Preferably, a single node of each subset is chosen and full stack traceback data is retrieved from the call-return stack within the chosen node.

  12. Studies on design of a process for organo-refining of coal to obtain super clean coal

    SciTech Connect (OSTI)

    Sharma, C.S.; Sharma, D.K.

    1999-08-01

    Organo-refining of coal results in refining the coal to obtain super clean coal and residual coal. Super clean coal may be used to obtain value added chemicals, products, and cleaner fuels from coal. In the present work, studies on the design of a semicontinuous process for organo-refining of one ton of coal have been made. The results are reported. This is only a cursory attempt for the design, and further studies may be required for designing this process for use in the development of a scaled-up process of organo-refining of coal.

  13. A versatile elevated-pressure reactor combined with an ultrahigh vacuum surface setup for efficient testing of model and powder catalysts under clean gas-phase conditions

    SciTech Connect (OSTI)

    Morfin, Franck; Piccolo, Laurent

    2013-09-15

    A small-volume reaction cell for catalytic or photocatalytic testing of solid materials at pressures up to 1000 Torr has been coupled to a surface-science setup used for standard sample preparation and characterization under ultrahigh vacuum (UHV). The reactor and sample holder designs allow easy sample transfer from/to the UHV chamber, and investigation of both planar and small amounts of powder catalysts under the same conditions. The sample is heated with an infrared laser beam and its temperature is measured with a compact pyrometer. Combined in a regulation loop, this system ensures fast and accurate temperature control as well as clean heating. The reaction products are automatically sampled and analyzed by mass spectrometry and/or gas chromatography (GC). Unlike previous systems, our GC apparatus does not use a recirculation loop and allows working in clean conditions at pressures as low as 1 Torr while detecting partial pressures smaller than 10{sup ?4} Torr. The efficiency and versatility of the reactor are demonstrated in the study of two catalytic systems: butadiene hydrogenation on Pd(100) and CO oxidation over an AuRh/TiO{sub 2} powder catalyst.

  14. Pressure/temperature fluid cell apparatus for the neutron powder diffractometer instrument: Probing atomic structure in situ

    SciTech Connect (OSTI)

    Wang, Hsiu -Wen; Fanelli, Victor R.; Reiche, Helmut M.; Larson, Eric; Taylor, Mark A.; Xu, Hongwu; Zhu, Jinlong; Siewenie, Joan; Page, Katharine

    2014-12-24

    This contribution describes a new local structure compatible gas/liquid cell apparatus for probing disordered materials at high pressures and variable temperatures in the Neutron Powder Diffraction instrument at the Lujan Neutron Scattering Center, Los Alamos National Laboratory. The new sample environment offers choices for sample canister thickness and canister material type. Finite element modeling is utilized to establish maximum allowable working pressures of 414 MPa at 15 K and 121 MPa at 600 K. High quality atomic pair distribution function data extraction and modeling have been demonstrated for a calibration standard (Si powder) and for supercritical and subcritical CO2measurements. As a result, the new sample environment was designed to specifically target experimental studies of the local atomic structures involved in geologic CO2 sequestration, but will be equally applicable to a wide variety of energy applications, including sorption of fluids on nano/meso-porous solids, clathrate hydrate formation, catalysis, carbon capture, and H2 and natural gas uptake/storage.

  15. ESTABLISHING SUSTAINABLE US HEV/PHEV MANUFACTURING BASE: STABILIZED LITHIUM METAL POWDER, ENABLING MATERIAL AND REVOLUTIONARY TECHNOLOGY FOR HIGH ENERGY LI-ION BATTERIES

    SciTech Connect (OSTI)

    Yakovleva, Marina

    2012-12-31

    FMC Lithium Division has successfully completed the project “Establishing Sustainable US PHEV/EV Manufacturing Base: Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries”. The project included design, acquisition and process development for the production scale units to 1) produce stabilized lithium dispersions in oil medium, 2) to produce dry stabilized lithium metal powders, 3) to evaluate, design and acquire pilot-scale unit for alternative production technology to further decrease the cost, and 4) to demonstrate concepts for integrating SLMP technology into the Li- ion batteries to increase energy density. It is very difficult to satisfy safety, cost and performance requirements for the PHEV and EV applications. As the initial step in SLMP Technology introduction, industry can use commercially available LiMn2O4 or LiFePO4, for example, that are the only proven safer and cheaper lithium providing cathodes available on the market. Unfortunately, these cathodes alone are inferior to the energy density of the conventional LiCoO2 cathode and, even when paired with the advanced anode materials, such as silicon composite material, the resulting cell will still not meet the energy density requirements. We have demonstrated, however, if SLMP Technology is used to compensate for the irreversible capacity in the anode, the efficiency of the cathode utilization will be improved and the cost of the cell, based on the materials, will decrease.

  16. Active wear and failure mechanisms of TiN-coated high speed steel and TiN-coated cemented carbide tools when machining powder metallurgically made stainless steels

    SciTech Connect (OSTI)

    Jiang, L.; Haenninen, H.; Paro, J.; Kauppinen, V.

    1996-09-01

    In this study, active wear and failure mechanisms of both TiN-coated high speed steel and TiN-coated cemented carbide tools when machining stainless steels made by powder metallurgy in low and high cutting speed ranges, respectively, have been investigated. Abrasive wear mechanisms, fatigue-induced failure, and adhesive and diffusion wear mechanisms mainly affected the tool life of TiN-coated high speed steel tools at cutting speeds below 35 m/min, between 35 and 45 m/min, and over 45 m/min, respectively. Additionally, fatigue-induced failure was active at cutting speeds over 45 m/min in the low cutting speed range when machining powder metallurgically made duplex stainless steel 2205 and austenitic stainless steel 316L. In the high cutting speed range, from 100 to 250 m/min, fatigue-induced failure together with diffusion wear mechanism, affected the tool life of TiN-coated cemented carbide tools when machining both 316L and 2205 stainless steels. It was noticed that the tool life of TiN-coated high speed steel tools used in the low cutting speed range when machining 2205 steel was longer than that when machining 316L steel, whereas the tool life of TiN-coated cemented carbide tools used in the high cutting speed range when machining 316L steel was longer than that when machining 2205 steel.

  17. Development of the laser isotope separation method (AVLIS) for obtaining weight amounts of highly enriched {sup 150}Nd isotope

    SciTech Connect (OSTI)

    Babichev, A P; Grigoriev, Igor' S; Grigoriev, A I; Dorovskii, A P; D'yachkov, Aleksei B; Kovalevich, S K; Kochetov, V A; Kuznetsov, V A; Labozin, Valerii P; Matrakhov, A V; Mironov, Sergei M; Nikulin, Sergei A; Pesnya, A V; Timofeev, N I; Firsov, Valerii A; Tsvetkov, G O; Shatalova, G G

    2005-10-31

    Results obtained at the first stage of development of the experimental technique for obtaining weight amounts of the highly enriched {sup 150}Nd isotope by laser photoionisation are presented. The vaporiser and the laser are designed, and various methods of irradiation of neodymium vapour and extraction of photoions are tested. The product yield {approx}40 mg h{sup -1} for the {approx}60% enrichment and 25 mg h{sup -1} for the {approx}65% enrichment is achieved for a vaporiser of length 27 cm. The cost of constructing the facility for preparing 50 kg of the {sup 150}Nd isotope, intended for determining the neutrino mass, is estimated. This estimate shows that the cost of production can be lowered by a factor of 5-7 compared to the electromagnetic method. (invited paper)

  18. Analysis of ocean current meter records obtained from a 1975 deployment off the Farallon Islands, California. Final report

    SciTech Connect (OSTI)

    Crabbs, D.E.

    1983-08-01

    Two bottom current records were obtained during August and September 1975 in the Farallon Islands low-level radioactive waste disposal area off San Francisco, California. This report presents the results of the data reduction and analysis of the current meter records, and interprets the results with respect to additional data collected in 1977. An effort is made to compare the patterns of current activity in the dumpsite area for the time periods measured.

  19. Validation and Comparison of Carbon Sequestration Project Cost Models with Project Cost Data Obtained from the Southwest Partnership

    SciTech Connect (OSTI)

    Robert Lee; Reid Grigg; Brian McPherson

    2011-04-15

    Obtaining formal quotes and engineering conceptual designs for carbon dioxide (CO{sub 2}) sequestration sites and facilities is costly and time-consuming. Frequently, when looking at potential locations, managers, engineers and scientists are confronted with multiple options, but do not have the expertise or the information required to quickly obtain a general estimate of what the costs will be without employing an engineering firm. Several models for carbon compression, transport and/or injection have been published that are designed to aid in determining the cost of sequestration projects. A number of these models are used in this study, including models by J. Ogden, MIT's Carbon Capture and Sequestration Technologies Program Model, the Environmental Protection Agency and others. This report uses the information and data available from several projects either completed, in progress, or conceptualized by the Southwest Regional Carbon Sequestration Partnership on Carbon Sequestration (SWP) to determine the best approach to estimate a project's cost. The data presented highlights calculated versus actual costs. This data is compared to the results obtained by applying several models for each of the individual projects with actual cost. It also offers methods to systematically apply the models to future projects of a similar scale. Last, the cost risks associated with a project of this scope are discussed, along with ways that have been and could be used to mitigate these risks.

  20. SU-E-I-53: Variation in Measurements of Breast Skin Thickness Obtained Using Different Imaging Modalities

    SciTech Connect (OSTI)

    Nguyen, U; Kumaraswamy, N; Markey, M

    2014-06-01

    Purpose: To investigate variation in measurements of breast skin thickness obtained using different imaging modalities, including mammography, computed tomography (CT), ultrasound, and magnetic resonance imaging (MRI). Methods: Breast skin thicknesses as measured by mammography, CT, ultrasound, and MRI were compared. Mammographic measurements of skin thickness were obtained from published studies that utilized standard positioning (upright) and compression. CT measurements of skin thickness were obtained from a published study of a prototype breast CT scanner in which the women were in the prone position and the breast was uncompressed. Dermatological ultrasound exams of the breast skin were conducted at our institution, with the subjects in the upright position and the breast uncompressed. Breast skin thickness was calculated from breast MRI exams at our institution, with the patient in the prone position and the breast uncompressed. Results: T tests for independent samples demonstrated significant differences in the mean breast skin thickness as measured by different imaging modalities. Repeated measures ANOVA revealed significant differences in breast skin thickness across different quadrants of the breast for some modalities. Conclusion: The measurement of breast skin thickness is significantly different across different imaging modalities. Differences in the amount of compression and differences in patient positioning are possible reasons why measurements of breast skin thickness vary by modality.