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1

Improved Water Flooding through Injection Brine Modification  

SciTech Connect (OSTI)

Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman; (U of Wyoming)

2003-01-01T23:59:59.000Z

2

Case Study of Water-Soluble Metal Containing Organic Constituents...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Case Study of Water-Soluble Metal Containing Organic Constituents of Biomass Burning Aerosol. Case Study of Water-Soluble Metal Containing Organic Constituents of Biomass Burning...

3

Recovery of energy from geothermal brine and other hot water sources  

DOE Patents [OSTI]

Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g. with respect to the design of such plates, number of plates employed, spacing between plates, area thereof, column diameter, and the like, are designed to achieve maximum throughput of brine or hot water and reduction in temperature differential at the respective stages or plates between the brine or hot water and the working fluid, and so minimize lost work and maximize efficiency, and minimize scale deposition from hot water containing fluid including salts, such as brine. Maximum throughput approximates minimum cost of electricity which can be produced by conversion of the recovered thermal energy to electrical energy.

Wahl, III, Edward F. (Claremont, CA); Boucher, Frederic B. (San Juan Capistrano, CA)

1981-01-01T23:59:59.000Z

4

Numerical simulations of lab-scale brine-water mixing experiments.  

SciTech Connect (OSTI)

Laboratory-scale experiments simulating the injection of fresh water into brine in a Strategic Petroleum Reserve (SPR) cavern were performed at Sandia National Laboratories for various conditions of injection rate and small and large injection tube diameters. The computational fluid dynamic (CFD) code FLUENT was used to simulate these experiments to evaluate the predictive capability of FLUENT for brine-water mixing in an SPR cavern. The data-model comparisons show that FLUENT simulations predict the mixing plume depth reasonably well. Predictions of the near-wall brine concentrations compare very well with the experimental data. The simulated time for the mixing plume to reach the vessel wall was underpredicted for the small injection tubes but reasonable for the large injection tubes. The difference in the time to reach the wall is probably due to the three-dimensional nature of the mixing plume as it spreads out at the air-brine or oil-brine interface. The depth of the mixing plume as it spreads out along the interface was within a factor of 2 of the experimental data. The FLUENT simulation results predict the plume mixing accurately, especially the water concentration when the mixing plume reaches the wall. This parameter value is the most significant feature of the mixing process because it will determine the amount of enhanced leaching at the oil-brine interface.

Khalil, Imane; Webb, Stephen Walter

2006-10-01T23:59:59.000Z

5

Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines  

E-Print Network [OSTI]

Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines Zhenhao, 2007 A thermodynamic model calculating the solubility of hydrogen sulfide (H2S) in pure water phase. With this specific interaction approach, this model is able to predict H2S solubility in other

Zhu, Chen

6

Analysis of hydrocarbon removal methods for the management of oilfield brines and produced waters  

E-Print Network [OSTI]

and globally, the petroleum industries challenge has been to develop a high-tech and cost effective method to purify the large volumes of oilfield brines and produced water. Currently, most of the produced water requires several pre- and post- treatment methods...

Furrow, Brendan Eugene

2005-11-01T23:59:59.000Z

7

Evidence for ground-water circulation in the brine-filled aquitard, Oak Ridge, Tennessee  

SciTech Connect (OSTI)

Various geologic, hydrologic, and geochemical methods were used to assess active ground-water circulation in a brine-filled, deep (> 50 m below land surface) aquitard underlying the Oak Ridge Reservation, Tennessee. In places, the brine which was presumed to be stagnant in the past, contains various contaminants. If ground-water circulation is viable in the brine-containing formations, then remediation or containment of the deep-seated contaminants should be considered a high priority. Data used to determine this included (1) spatial and temporal pressures and hydraulic heads measured in the aquitard, (2) hydraulic parameters of the formations in question, (3) vertical temperature gradients, and (4) spatial and temporal chemical and isotopic composition of the saline ground water. Conclusions suggest that the saline water contained at depth is not isolated (in terms of recharge and discharge) from the overlying active and fresh-water-(< 500 mg/l) bearing units. Consequently, influx of young water (and contamination) from land surface does occur. Potential discharge into the shallow aquifers was assumed where the hydraulic head of the saline water was higher than that in the shallow aquifers, accounting for temperature and salinity anomalies observed close to land surface. The confined water (and dissolved solutes) move along open conduits at relatively high velocity into adjacent, more permeable units.

Nativ, R. [Hebrew Univ. of Jerusalem (Israel). Dept. of Soil and Water Sciences; Halleran, A.; Hunley, A. [Oak Ridge National Lab., TN (United States). Environmental Sciences Div.

1997-07-01T23:59:59.000Z

8

Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine  

SciTech Connect (OSTI)

This study is developing a comprehensive study of what is involved in the desalination of oil field produced brine and the technical developments and regulatory changes needed to make the concept a commercial reality. It was originally based on ''conventional'' produced water treatment and reviewed (1) the basics of produced water management, (2) the potential for desalination of produced brine in order to make the resource more useful and available in areas of limited fresh water availability, and (3) the potential beneficial uses of produced water for other than oil production operations. Since we have begun however, a new area of interest has appeared that of brine water treatment at the well site. Details are discussed in this technical progress report. One way to reduce the impact of O&G operations is to treat produced brine by desalination. The main body of the report contains information showing where oil field brine is produced, its composition, and the volume available for treatment and desalination. This collection of information all relates to what the oil and gas industry refers to as ''produced water management''. It is a critical issue for the industry as produced water accounts for more than 80% of all the byproducts produced in oil and gas exploration and production. The expense of handling unwanted waste fluids draws scarce capital away for the development of new petroleum resources, decreases the economic lifetimes of existing oil and gas reservoirs, and makes environmental compliance more expensive to achieve. More than 200 million barrels of produced water are generated worldwide each day; this adds up to more than 75 billion barrels per year. For the United States, the American Petroleum Institute estimated about 18 billion barrels per year were generated from onshore wells in 1995, and similar volumes are generated today. Offshore wells in the United States generate several hundred million barrels of produced water per year. Internationally, three barrels of water are produced for each barrel of oil. Production in the United States is more mature; the US average is about 7 barrels of water per barrel of oil. Closer to home, in Texas the Permian Basin produces more than 9 barrels of water per barrel of oil and represents more than 400 million gallons of water per day processed and re-injected.

David B. Burnett

2005-09-29T23:59:59.000Z

9

Disposal/recovery options for brine waters from oil and gas production in New York State. Final report  

SciTech Connect (OSTI)

Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated.

Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

1996-03-01T23:59:59.000Z

10

Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine  

SciTech Connect (OSTI)

Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

David B. Burnett

2004-09-29T23:59:59.000Z

11

Ground-water hydraulics of the deep-basin brine aquifer, Palo Duro Basin, Texas panhandle  

SciTech Connect (OSTI)

The Deep-Basin Brine aquifer of the Palo Duro Basin (Texas Panhandle) underlies thick Permian bedded evaporites that are being evaluated as a potential high-level nuclear waste isolation repository. Potentiometric surface maps of 5 units of the Deep-Basin Brine aquifer were drawn using drill-stem test (DST) pressure data, which were analyzed by a geostatistical technique (kriging) to smooth the large variation in the data. The potentiometric surface maps indicate that the Deep-Basin Brine aquifer could be conceptually modeled as 5 aquifer units; a Lower Permian (Wolfcamp) aquifer, upper and lower Pennsylvanian aquifers, a pre-Pennsylvanian aquifer, and a Pennsylvanian to Wolfcampian granite-wash aquifer. The hydraulic head maps indicate that ground-water flow in each of the units is west to east with a minor northerly component near the Amarillo Uplift, the northern structural boundary of the basin. The Wolfcamp potentiometric surface indicates the strongest component of northerly flow. Inferred flow direction in Pennsylvanian aquifers is easterly, and in the pre-Pennsylvanian aquifer near its pinch-out in the basin center, flow is inferred to be to the north. In the granite-wash aquifer the inferred flow direction is east across the northern edge of the basin and southeast along the Amarillo Uplift.

Smith, D.A.

1985-01-01T23:59:59.000Z

12

Mercury Species and Other Selected Constituent Concentrations in Water, Sediment, and Biota of  

E-Print Network [OSTI]

Mercury Species and Other Selected Constituent Concentrations in Water, Sediment, and Biota Data Series 658 #12;#12;Mercury Species and Other Selected Constituent Concentrations in Water.J., 2012, Mercury species and other selected constituent concentrations in water, sediment, and biota

13

Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations  

SciTech Connect (OSTI)

Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes for the removal of hydrocarbons from produced water. The results of these experiments show that hydrocarbons from produced water can be reduced from 200 ppm to below 29 ppm level. Experiments were also done to remove the dissolved solids (salts) from the pretreated produced water using desalination membranes. Produced water with up to 45,000 ppm total dissolved solids (TDS) can be treated to agricultural water quality water standards having less than 500 ppm TDS. The Report also discusses the results of field testing of various process trains to measure performance of the desalination process. Economic analysis based on field testing, including capital and operational costs, was done to predict the water treatment costs. Cost of treating produced water containing 15,000 ppm total dissolved solids and 200 ppm hydrocarbons to obtain agricultural water quality with less than 200 ppm TDS and 2 ppm hydrocarbons range between $0.5-1.5 /bbl. The contribution of fresh water resource from produced water will contribute enormously to the sustainable development of the communities where oil and gas is produced and fresh water is a scarce resource. This water can be used for many beneficial purposes such as agriculture, horticulture, rangeland and ecological restorations, and other environmental and industrial application.

David B. Burnett; Mustafa Siddiqui

2006-12-29T23:59:59.000Z

14

Membrane Desalination of Agricultural Drainage Water: Water Recovery Enhancement and Brine Minimization  

E-Print Network [OSTI]

Pilot-scale testing of reverse osmosis using conventionalY. Cohen, High- Recovery Reverse Osmosis Using IntermediateUltra-Low Pressure Reverse Osmosis for Surface Water

Cohen, Yoram

2008-01-01T23:59:59.000Z

15

Biochemical solubilization of toxic salts from residual geothermal brines and waste waters  

DOE Patents [OSTI]

A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

Premuzic, E.T.; Lin, M.S.

1994-11-22T23:59:59.000Z

16

Biochemical solubilization of toxic salts from residual geothermal brines and waste waters  

DOE Patents [OSTI]

A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

1994-11-22T23:59:59.000Z

17

Brine contamination of ground water and streams in the Baxterville Oil Field Area, Lamar and Marion Counties, Mississippi. Water resources investigation  

SciTech Connect (OSTI)

The report defines the extent of oil-field-brine contamination in ground water and streams in the Baxterville oil field area. The report is based largely on data collected during the period October 1984 through November 1985. Water samples were collected from streams and wells in the study area. Data from a previous study conducted in the vicinity of the nearby Tatum Salt Dome were used for background water-quality information. Natural surface-water quality was determined by sampling streamflow from a nearby basin having no oil field activities and from samples collected in an adjacent basin during a previous study.

Kalkhoff, S.J.

1993-12-31T23:59:59.000Z

18

Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

1993-07-01T23:59:59.000Z

19

Water quality in the vicinity of Mosquito Creek Lake, Trumbull County, Ohio, in relation of the chemistry of locally occurring oil, natural gas, and brine  

SciTech Connect (OSTI)

The purpose of this report is to describe current water quality and the chemistry of oil, natural gas, and brine in the Mosquito Creek Lake area. Additionally, these data are used to characterize water quality in the Mosquito Creek Lake area in relation to past oil and natural gas well drilling and production. To meet the overall objective, several goals for this investigation were established. These include (1) collect water-quality and subsurface-gas data from shallow sediments and rock that can be used for future evaluation of possible effects of oil and natural gas well drilling and production on water supplies, (2) characterize current surface-water and ground-water quality as it relates to the natural occurrence and (or) release of oil, gas, and brine (3) sample and chemically characterize the oil in the shallow Mecca Oil Pool, gas from the Berea and Cussewago Sandstone aquifers, and the oil, gas, and brine from the Clinton sandstone, and (4) identify areas where aquifers are vulnerable to contamination from surface spills at oil and natural gas drilling and production sites.

Barton, G.J.; Burruss, R.C.; Ryder, R.T.

1998-12-31T23:59:59.000Z

20

Hydrogeologic aspects of brine disposal in the East Poplar oil field, Fort Peck Indian Reservation, northeastern Montana  

SciTech Connect (OSTI)

The East Poplar Oil Field encompasses about 70 square miles in the south-central part of the Fort Peck Indian Reservation. Oil production began in 1952 from the Mississippian Madison Group. Production depths range from about 5,500 to 6,000 feet below land surface. Large quantities of brine (water having a dissolved-solids concentration greater than 35,000 milligrams per liter) have been produced with the oil. The brine has a dissolved-solids concentration of as much as 160,000 milligrams per liter. Most of the brine has been disposed of by injection into shallower subsurface formations (mainly the Lower Cretaceous Dakota Sandstone at depths of about 3,300 feet and the Upper Cretaceous Judith River Formation at depths of about 1,000 feet). Smaller quantities of brine have been directed to storage and evaporation pits. Handling, transport, and disposal of the brine have resulted in its movement into and migration through shallow Quaternary alluvial and glacial deposits along the Poplar River valley. Locally, domestic water supplies are obtained from these deposits. The major point, sources of shallow ground-water contamination probably is leakage of brine from corroded disposal-well casing and pipelines. Using electromagnetic geophysical techniques and auger drilling, three saline-water plumes in alluvial deposits and one plum in glacial deposits have been delineated. Dominant constituents in plume areas are sodium and chloride, whereas those in nonplume areas are sodium and bicarbonate.

Craigg, S.D.; Thamke, J.N. (Geological Survey, Helena, MT (United States))

1993-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Property:BrineConstituents | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformationInyo County, California | Open EnergyAuthor JumpBoundingCoordinatesSW Jump

22

Oil production enhancement through a standardized brine treatment. Final report  

SciTech Connect (OSTI)

In order to permit the environmentally safe discharge of brines produced from oil wells in Pennsylvania to the surface waters of the Commonwealth and to rapidly brings as many wells as possible into compliance with the law, the Pennsylvania Oil and Gas Association (POGAM) approached the Pennsylvania State University to develop a program designed to demonstrate that a treatment process to meet acceptable discharge conditions and effluent limitations can be standardized for all potential stripper wells brine discharge. After the initial studies, the first phase of this project was initiated. A bench-scale prototype model was developed for conducting experiments in laboratory conditions. The experiments pursued in the laboratory conditions were focused on the removal of ferrous iron from synthetically made brine. Iron was selected as the primary heavy metals for studying the efficiency of the treatment process. The results of a number of experiments in the lab were indicative of the capability of the proposed brine treatment process in the removal of iron. Concurrent with the laboratory experiments, a comprehensive and extensive kinetic study was initiated. This study was necessary to provide the required data base for process modeling. This study included the investigation of the critical pH as well as the rate and order of reactions of the studied elements: aluminum, lead, zinc, and copper. In the second phase of this project, a field-based prototype was developed to evaluate and demonstrate the treatment process effectiveness. These experiments were conducted under various conditions and included the testing on five brines from different locations with various dissolved constituents. The outcome of this research has been a software package, currently based on iron`s reactivity, to be used for design purposes. The developed computer program was refined as far as possible using the results from laboratory and field experiments.

Adewumi, A.; Watson, R.; Tian, S.; Safargar, S.; Heckman, S.; Drielinger, I.

1995-08-01T23:59:59.000Z

23

Assessment of Brine Management for Geologic Carbon Sequestration  

E-Print Network [OSTI]

brine  management  or   extracted  water  management  infrastructure  or  where  nearby  fresh  water  resources  need  to  be   carefully  monitored  for  later  contamination.  

Breunig, Hanna M.

2014-01-01T23:59:59.000Z

24

The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine  

E-Print Network [OSTI]

Thermodynamic property calculations of mixtures containing carbon dioxide (CO$_2$) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi, and the CO$_2$ activity coefficient model by Duan and Sun. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO$_2$, pure water, and both CO$_2$-rich and aqueous (H$_2$O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Sun's model yields accurate results for the partial molar enthalpy of CO$_2$. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H$_2$O-CO$_2$-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

P. C. Myint; Y. Hao; A. Firoozabadi

2015-04-20T23:59:59.000Z

25

Summary Results for Brine Migration Modeling Performed by LANL...  

Office of Environmental Management (EM)

BrineMigrationModeling More Documents & Publications Coupled Model for Heat and Water Transport in a High Level Waste Repository in Salt Establishing the Technical Basis for...

26

Isothermal vapor-liquid equilibria for water + 2-aminoethanol + dimethyl sulfoxide and its constituent three binary systems  

SciTech Connect (OSTI)

Isothermal vapor-liquid equilibria were measured for the ternary system water + 2-aminoethanol + dimethyl sulfoxide and its three constituent binary mixtures at 363.15 K. The apparatus used was a modified Rogalski-Malanoski equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

Tochigi, Katsumi; Akimoto, Kentarou; Ochi, Kenji [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry] [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Liu, Fangyhi; Kawase, Yasuhito [Nippon Refine Co., Ltd., Tokyo (Japan)] [Nippon Refine Co., Ltd., Tokyo (Japan)

1999-05-01T23:59:59.000Z

27

Biological removal of organic constituents in quench water from a slagging, fixed-bed coal-gasification pilot plant  

SciTech Connect (OSTI)

This study is part of an effort to assess the efficiency of activated-sludge treatment for removal of organic constituents from high-Btu coal-gasification pilot-plant quench waters. A sample of raw-gas quench water was obtained from the Grand Forks Energy and Technology Center's pilot plant, which employs the slagging, fixed-bed gasification process. The quench water generated in the processing of Indian Head lignite was pretreated to reduce ammonia and alkalinity, and then diluted and subjected to long-term biological treatment, followed by detailed characterization and analysis of organic constituents. The pretreated (influent) and treated (effluent) samples were extracted using a methylene chloride, pH-fractionation method to obtain acid, base, and neutral fractions, which were analyzed by capillary-column gas chromatography/mass spectrometry (GC/MS). Over 99% of the total extractable and chromatographable organic material in the influent acid fraction was composed of phenol and alkylated phenols. Biological treatment removed these compounds almost completely. Major components of the influent base fraction were alkylated pyridines, anilines, aminopyrroles, imidazoles and/or pyrazoles, diazines, and quinolines. Removal efficiency of these compounds ranged between 90 and 100%. The influent neutral fraction was composed mainly of cycloalkanes, cycloalkenes, naphthalene, indole, acetophenone, and benzonitrile. Alkylated benzenes were generally absent. Removal efficiencies of these compounds were generally very good, except for certain alkylated cycloalkanes and cycloalkenes. Results are compared with those of a similar study on HYGAS coal-gasification quench water.

Stamoudis, V C; Luthy, R G

1980-02-01T23:59:59.000Z

28

Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot  

SciTech Connect (OSTI)

To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

2009-11-01T23:59:59.000Z

29

Cathodic protection in oilfield brine  

SciTech Connect (OSTI)

In this paper the use of cathodic protection (CP) to mitigate internal and corrosion-related failures that occur in the produced brine phase of oilfield tanks and production vessels is discussed. Unique considerations covered include brine properties, CP system selection, installation details, monitoring, and coatings.

Turnipseed, S.P. (Chevron U.S.A. Inc., Houston, TX (US))

1991-12-01T23:59:59.000Z

30

Emplacement and release of brines from subsurface  

E-Print Network [OSTI]

Groundwater contamination by dense brines is addressed fromgroundwater contamination where dense brines might have beenbrines can become long-term sources of groundwater contamination

Hunt, James R; Flowers, Tracey C

2004-01-01T23:59:59.000Z

31

Integrated process for coalbed brine and methane disposal  

SciTech Connect (OSTI)

This paper describes a technology and project to demonstrate and commercialize a brine disposal process for converting the brine stream of a coalbed gas producing site into clean water for agricultural use and dry solids that can be recycled for industrial consumption. The process also utilizes coalbed methane (CBM) released from coal mining for the combustion process thereby substantially reducing the potential for methane emissions to the atmosphere. The technology is ideally suited for the treatment and disposal of produced brines generated from the development of coal mines and coalbed methane resources worldwide. Over the next 10 to 15 years, market potential for brine elimination equipment and services is estimated to be in the range of $1 billion.

Byam, J.W. Jr.; Tait, J.H.; Brandt, H.

1996-12-31T23:59:59.000Z

32

Biological removal of organic constituents in quench waters from high-Btu coal-gasification pilot plants  

SciTech Connect (OSTI)

Studies were initiated to assess the efficiency of bench-scale, activated-sludge treatment for removal of organic constituents from coal-gasification process effluents. Samples of pilot-plant, raw-gas quench waters were obtained from the HYGAS process of the Institute of Gas Technology and from the slagging, fixed-bed (SFB) process of the Grand Forks Energy Technology Center. The types of coal employed were Bituminous Illinois No. 6 for the HYGAS and Indian Head lignite for the SFB process. These pilot-plant quench waters, while not strictly representative of commercial condensates, were considered useful to evaluate the efficiency of biological oxidation for the removal of organics. Biological-reactor influent and effluent samples were extracted using a methylene chloride pH-fractionation method into acid, base, and neutral fractions, which were analyzed by capillary-column gas-chromatography/mass-spectrometry. Influent acid fractions of both HYGAS and SFB condensates showed that nearly 99% of extractable and chromatographable organic material comprised phenol and alkylated phenols. Activated-sludge treatment removed these compounds almost completely. Removal efficiency of base-fraction organics was generally good, except for certain alkylated pyridines. Removal of neutral-fraction organics was also good, except for certain alkylated benzenes, certain polycyclic aromatic hydrocarbons, and certain cycloalkanes and cycloalkenes, especially at low influent concentrations.

Stamoudis, V C; Luthy, R G

1980-02-01T23:59:59.000Z

33

A cost-effective statistical screening method to detect oilfield brine contamination  

SciTech Connect (OSTI)

A statistical screening method has been developed using Tolerance Limits for barium (Ba{sup +2}) to identify contamination of a fresh-water aquifer by oilfield brines. The method requires an understanding of the local hydrochemistry of oilfield brines, inexpensive, Publicly available hydrochemical data, a single sample analysis from the suspect well and the application of a simple statistical procedure. While this method may not provide absolute evidence of oilfield brine contamination of a fresh-water aquifer, it does identify conditions where brine contamination is a strong probability over other possible sources of chlorides.

Alyanak, N.; Grace, J.T.; Campbell, M.D. [United Resources International, Houston, TX (United States)

1995-12-01T23:59:59.000Z

34

Case Study of Water-Soluble Metal Containing Organic Constituents of Biomass Burning Aerosol  

SciTech Connect (OSTI)

Natural and prescribed biomass fires are a major source of atmospheric aerosols that can persist in the atmosphere for long periods of time. Biomass burning aerosols (BBA) can be associated with long range transport of water soluble N?, S?, P?, and metal?containing species. In this study, BBA samples were collected using a particle?into?liquid sampler (PILS) from laboratory burns of vegetation collected on military bases in the southeastern and southwestern United States. The samples were then analyzed using high resolution electrospray ionization mass spectrometry (ESI/HR?MS) that enabled accurate mass measurements for hundreds of species with m/z values between 70 and 1000 and assignment of probable elemental formulae. Mg, Al, Ca, Cr, Mn, Fe, Ni, Cu, Zn, and Ba?containing organometallic species were identified. The results suggest that the biomass may have accumulated metal?containing species that were reemitted during biomass burning. Further research into the sources, persistence, and dispersion of metal?containing aerosols as well as their environmental effects is needed.

Chang-Graham, Alexandra L.; Profeta, Luisa Tm; Johnson, Timothy J.; Yokelson, Robert J.; Laskin, Alexander; Laskin, Julia

2011-01-10T23:59:59.000Z

35

Don Juan Pond, Antarctica: Near-surface CaCl2-brine feeding Earth's most saline  

E-Print Network [OSTI]

Don Juan Pond, Antarctica: Near-surface CaCl2-brine feeding Earth's most saline lake for RSL formation, CaCl2 brines and chloride deposits in basins may provide clues to the origin of ancient,2,10­14 , the composition of the brine is unlike any other body of water in the world, as ,90% of the salt is CaCl2 1

Marchant, David R.

36

Strontium isotopic study of subsurface brines from Illinois basin  

SciTech Connect (OSTI)

The abundance of the radiogenic isotope /sup 87/Sr in a subsurface brine can be used as a tracer of brine origin, evolution, and diagenetic effects. The authors have determined the /sup 87/Sr//sup 86/Sr ratios of over 60 oil-field waters from the Illinois basin, where brine origin is perplexing because of the absence of any significant evaporite strata. Initially, they analyzed brines from 15 petroleum-producing sandstone and carbonate units; waters from Ordovician, Silurian, Devonian, and Mississippian strata have /sup 87/Sr//sup 86/Sr ratios in the range 0.7079-0.7108. All but those from the Ste. Genevieve Limestone (middle Mississippian) are more radiogenic in /sup 87/Sr//sup 86/Sr than seawater values for this interval of geologic time. The detrital source of the more radiogenic /sup 87/Sr may be the New Albany Shale group, considered to be a major petroleum source rock in the basin. The /sup 87/Sr//sup 86/Sr ratios of Ste. Genevieve brines apparently evolved without a contribution from fluid-shale interaction.

hetherington, E.A.; Stueber, A.M.; Pushkar, P.

1986-05-01T23:59:59.000Z

37

Brining studies at Pepper Products Inc.  

E-Print Network [OSTI]

of Department) A. B. Childers (Member) V. E. Sweat (Member) December 1988 Abstract Optimum brining conditions, causes of secondary fermentation, and salt fluctuation were investigated. Jalapeno peppers held in brine solution undergo lactic acid... fermentation, controlled by level of acidification and concentration of salt. Only brining at 7. 5% NaCl, with no added acetic acid, resulted in loss of all fermentable sugars. However, salt concentration fluctuated widely in this sample. Brining in 25...

Okoro, John Daniel

2012-06-07T23:59:59.000Z

38

Brine Sampling and Evaluation Program, 1991 report  

SciTech Connect (OSTI)

The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plan (WIPP) during 1991. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. When excavations began at the WIPP in 1982, small brine seepages (weeps) were observed on the walls. Brine studies began as part of the Site Validation Program and were formalized as a program in its own right in 1985. During nine years of observations (1982--1991), evidence has mounted that the amount of brine seeping into the WIPP excavations is limited, local, and only a small fraction of that required to produce hydrogen gas by corroding the metal in the waste drums and waste inventory. The data through 1990 is discussed in detail and summarized by Deal and others (1991). The data presented in this report describes progress made during the calendar year 1991 and focuses on four major areas: (1) quantification of the amount of brine seeping across vertical surfaces in the WIPP excavations (brine ``weeps); (2) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes; (3) further characterization of brine geochemistry; and (4) preliminary quantification of the amount of brine that might be released by squeezing the underconsolidated clays present in the Salado Formation.

Deal, D.E.; Abitz, R.J.; Myers, J.; Martin, M.L.; Milligan, D.J.; Sobocinski, R.W.; Lipponer, P.P.J. [International Technology Corp., Albuquerque, NM (United States)] [International Technology Corp., Albuquerque, NM (United States); Belski, D.S. [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.] [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.

1993-09-01T23:59:59.000Z

39

Consolidation and permeability of salt in brine  

SciTech Connect (OSTI)

The consolidation and loss of permeability of salt crystal aggregates, important in assessing the effects of water in salt repositories, has been studied as a function of several variables. The kinetic behavior was similar to that often observed in sintering and suggested the following expression for the time dependence of the void fraction: phi(t) = phi(0) - (A/B)ln(1 + Bt/z(0)/sup 3/), where A and B are rate constants and z(0) is initial average particle size. With brine present, A and phi(0) varied linearly with stress. The initial void fraction was also dependent to some extent on the particle size distribution. The rate of consolidation was most rapid in brine and least rapid in the presence of only air as the fluid. A brine containing 5 m MgCl/sub 2/ showed an intermediate rate, presumably because of the greatly reduced solubility of NaCl. A substantial wall effect was indicated by an observed increase in the void fraction of consolidated columns with distance from the top where the stress was applied and by a dependence of consolidation rate on the column height and radius. The distance through which the stress fell by a factor of phi was estimated to change inversely as the fourth power of the column diameter. With increasing temperature (to 85/sup 0/C), consolidation proceeded somewhat more rapidly and the wall effect was reduced. The permeability of the columns dropped rapidly with consolidation, decreasing with about the sixth power of the void fraction. In general, extrapolation of the results to repository conditions confirms the self-sealing properties of bedded salt as a storage medium for radioactive waste.

Shor, A.J.; Baes, C.F. Jr.; Canonico, C.M.

1981-07-01T23:59:59.000Z

40

Brine Sampling and Evaluation Program, 1990 report  

SciTech Connect (OSTI)

The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plant (WIPP) during 1990. When excavations began in 1982, small brine seepages (weeps) were observed on the walls. These brine occurrences were initially described as part of the Site Validation Program. Brine studies were formalized in 1985. The BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. The brine chemistry is important because it assists in understanding the origin of the brine and because it may affect possible chemical reactions in the buried waste after sealing the repository. The volume of brine and the hydrologic system that drives the brine seepage also need to be understood to assess the long-term performance of the repository. After more than eight years of observations (1982--1990), no credible evidence exists to indicate that enough naturally occurring brine will seep into the WIPP excavations to be of practical concern. The detailed observations and analyses summarized herein and in previous BSEP reports confirm the evidence apparent during casual visits to the underground workings -- that the excavations are remarkably dry.

Deal, D.E.; Abitz, R.J.; Myers, J.; Case, J.B.; Martin, M.L.; Roggenthen, W.M. [International Technology Corp., Albuquerque, NM (United States)] [International Technology Corp., Albuquerque, NM (United States); Belski, D.S. [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.] [Westinghouse Electric Corp., Carlsbad, NM (United States). Waste Isolation Div.

1991-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume III. Biological oceanography. Final report  

SciTech Connect (OSTI)

The Department of Energy's Strategic Petroleum Reserve Program began discharging brine into the Gulf of Mexico from its West Hackberry site near Cameron, Louisiana in May 1981. The brine originates from underground salt domes being leached with water from the Intracoastal Waterway, making available vast underground storage caverns for crude oil. The effects of brine discharge on aquatic organisms are presented in this volume. The topics covered are: benthos; nekton; phytoplankton; zooplankton; and data management.

DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J. (eds.)

1983-02-01T23:59:59.000Z

42

Weeks Island brine diffuser site study: baseline conditions and environmental assessment technical report  

SciTech Connect (OSTI)

This technical report presents the results of a study conducted at two alternative brine diffuser sites (A and B) proposed for the Weeks Island salt dome, together with an analysis of the potential physical, chemical, and biological effects of brine disposal for this area of the Gulf of Mexico. Brine would result from either the leaching of salt domes to form or enlarge oil storage caverns, or the subsequent use of these caverns for crude oil storage in the Strategic Petroleum Reserve (SPR) program. Brine leached from the Weeks Island salt dome would be transported through a pipeline which would extend from the salt dome either 27 nautical miles (32 statute miles) for Site A, or 41 nautical miles (47 statute miles) for Site B, into Gulf waters. The brine would be discharged at these sites through an offshore diffuser at a sustained peak rate of 39 ft/sup 3//sec. The disposal of large quantities of brine in the Gulf could have a significant impact on the biology and water quality of the area. Physical and chemical measurements of the marine environment at Sites A and B were taken between September 1977 and July 1978 to correlate the existing environmental conditions with the estimated physical extent of tthe brine discharge as predicted by the MIT model (US Dept. of Commerce, 1977a). Measurements of wind, tide, waves, currents, and stratification (water column structure) were also obtained since the diffusion and dispersion of the brine plume are a function of the local circulation regime. These data were used to calculate both near- and far-field concentrations of brine, and may also be used in the design criteria for diffuser port configuration and verification of the plume model. Biological samples were taken to characterize the sites and to predict potential areas of impact with regard to the discharge. This sampling focused on benthic organisms and demersal fish. (DMC)

None

1980-12-12T23:59:59.000Z

43

The brine underlying the Oak Ridge Reservation, Tennessee, USA: Characterization, genesis, and environmental implications  

SciTech Connect (OSTI)

The deep hydrogeologic system underlying the Oak Ridge Atomic Reservation contains brine. Its origin was assessed using existing and newly acquired chemical and isotopic data. The proposed model which best fits the data is modification of residual brine from which halite has been precipitated. Potential sources for this brine are in the Appalachian Mountains in the east, where bedded halite is documented, and where the hydraulic gradient needed to move the residual brine exists. Other models, such as ultrafiltration and halite dissolution, were also evaluated. In places, contaminants such as radionuclides, heavy metals, nitrates, and organic compounds have reached the deep system. The chemical and isotopic features of the brine were examined with respect to its potential discharge, contaminated in places, into shallow, freshwater systems. The observations suggest that whereas the origin of the salts in the brine may be very old, influx of recent water takes place. Consequently, the brine is not isolated (in terms of recharge and discharge) from the overlying active and fresh-water-bearing units. 78 refs., 8 figs., 1 tab.

Nativ, R. [Hebrew Univ. of Jerusalem, Rehovot (Israel)] [Hebrew Univ. of Jerusalem, Rehovot (Israel)

1996-03-01T23:59:59.000Z

44

Formation and character of an ancient 19-m ice cover and underlying trapped brine in an ``ice-sealed'' east  

E-Print Network [OSTI]

Formation and character of an ancient 19-m ice cover and underlying trapped brine in an ``ice bed year-round. New ice-core analysis and tempera- ture data show that beneath 19 m of ice is a water°C. The ice cover thickens at both its base and surface, sealing concentrated brine beneath. The ice

Priscu, John C.

45

Modeling acid-gas generation from boiling chloride brines  

SciTech Connect (OSTI)

This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

2009-11-16T23:59:59.000Z

46

Fate of Brine Applied to Unpaved Roads at a Radioactive Waste Subsurface Disposal Area  

SciTech Connect (OSTI)

Between 1984 and 1993, MgCl2 brine was used to suppress dust on unpaved roads at a radioactive waste subsurface disposal area. Because Cl– might enhance corrosion of buried metals in the waste, we investigated the distribution and fate of Cl– in the vadose zone using pore water samples collected from suction lysimeters and soluble salt concentrations extracted from sediment samples. The Cl/Br mass ratio and the total dissolved Cl– concentration of pore water show that brine contamination occurs primarily within 13 m of treated roads, but can extend as much as 30 m laterally in near-surface sedimentary deposits. Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests formation of perched water and horizontal transport during periods of high recharge. In a few locations, brine migrated to depths of 67 m within 3 to 5 yr. Elevated Cl– concentrations were found to depths of 2 m in roadbed material. In drainage ditches along roads, where runoff accumulates and recharge of surface water is high, Cl– was flushed from the sediments in 3 to 4 yr. In areas of lower recharge, Cl– remained in the sediments after 5 yr. Vertical brine movement is directly related to surface recharge through sediments. The distribution of Cl– in pore water and sediments is consistent with estimates of vadose zone residence times and spatial distribution of surface water recharge from other investigations at the subsurface disposal area.

Larry C. Hull; Carolyn W. Bishop

2004-02-01T23:59:59.000Z

47

The Brine Shrimp's Butterfly Stroke  

E-Print Network [OSTI]

We investigate the fluid dynamics of brine shrimp larvae swimming in this gallery of fluid motion video. Time resolved particle image velocimetry was performed using nano-particles as seeding material to measure the time dependent velocity and vorticity fields. The Reynolds number of the flow was roughly 8 and the Womerseley number (ratio of periodic forcing to viscous forcing) was about 5. Vorticity dynamics reveals the formation of a vortex ring structure at the tip of each arm at the beginning of the power stroke. This two vortex system evolves dramatically with time as the stroke progresses. The outer circulation is noted to weaken while the inner circulation strengthens over the power stroke. The gaining strength of the inner vortex correlates with the acceleration and forward movement of the larvae.

Johnson, Brennan; Dasi, Lakshmi Prasad

2011-01-01T23:59:59.000Z

48

Norm removal from frac water  

DOE Patents [OSTI]

A method for treating low barium frac water includes contacting a frac water stream with a radium selective complexing resin to produce a low radium stream, passing the low radium stream through a thermal brine concentrator to produce a concentrated brine; and passing the concentrated brine through a thermal crystallizer to yield road salt.

Silva, James Manio; Matis, Hope; Kostedt, IV, William Leonard

2014-11-18T23:59:59.000Z

49

Study of thermal-gradient-induced migration of brine inclusions in salt. Final report  

SciTech Connect (OSTI)

Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed.

Olander, D.R.

1984-08-01T23:59:59.000Z

50

Exposure and effects of oilfield brine discharges on western sandpipers (Calidris mauri) in Nueces Bay, Texas  

SciTech Connect (OSTI)

Discharge of oilfield brines into fresh and estuarine waters is a common disposal practice in Texas. Petroleum crude oil (PCO) extraction from underground stores includes the removal of a significant amount of water along with the oil. Several methods may be used to separate the oil and water fractions, including tank batteries, heat separation, and skimming ponds. Disposal of the resultant produced water (oilfield brine) may be accomplished by deep-well injection or discharge to surface waters. In Texas, an estimated 766,000 barrels of oilfield brine were discharged daily into tidal waters in 1979. The maximum concentration for oil and grease in these discharges permitted by the Texas Railroad Commission is 25 ppm. Several studies have shown that oilfield brines are toxic to a wide range of marine life, yet little is known about their effects on birds and mammals. Exposure to petroleum in oilfield wastes could evoke toxicological effects in some waterbird species. Avian responses to PCO exposure are highly variable, including cessation of growth, osmoregulatory impairment, endocrine dysfunction, hemolytic anemia, altered blood chemistry, cytochrome P450 induction, reduced reproductive success, and mortality. Oilfield brine discharges may soon be the largest and most pervasive source of contaminants entering Texas estuaries. Migratory and resident birds feeding in the vicinity of discharge sites may be ingesting food items contaminated with petroleum hydrocarbons, heavy metals and salts in sufficient quantities to evoke toxicity. The present study of wintering western sandpipers (Calidris mauri) that feed and roost near discharge sites sought to examine oilfield brine exposure and effects through quantification of contaminant burdens, morphological characteristics, and cytochrome P450-associated monooxygenase activities. 20 refs., 2 tabs.

Rattner, B.A.; Melancon, M.J. [National Biological Survey, Laurel, MD (United States); Capizzi, J.L. [Texas A& M Univ., College Station, TX (United States); King, K.A. [Fish and Wildlife Service, Phoenix, AZ (United States); LeCaptain, L.J. [Fish and Wildlife Service, Spokane, WA (United States)

1995-05-01T23:59:59.000Z

51

SCS-2002-10 Description of Water Analysis Parameters  

E-Print Network [OSTI]

of laboratories often lack basic descriptions for terminology, potential sources of contaminates or parameters-field brine, sea water, industrial brine, and reclaimed effluent water, etc. Issues Moderate amounts of sodium

52

Brine flow in heated geologic salt.  

SciTech Connect (OSTI)

This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

Kuhlman, Kristopher L.; Malama, Bwalya

2013-03-01T23:59:59.000Z

53

Investigation of oil injection into brine for the Strategic Petroleum Reserve : hydrodynamics and mixing experiments with SPR liquids.  

SciTech Connect (OSTI)

An experimental program was conducted to study a proposed approach for oil reintroduction in the Strategic Petroleum Reserve (SPR). The goal was to assess whether useful oil is rendered unusable through formation of a stable oil-brine emulsion during reintroduction of degassed oil into the brine layer in storage caverns. An earlier report (O'Hern et al., 2003) documented the first stage of the program, in which simulant liquids were used to characterize the buoyant plume that is produced when a jet of crude oil is injected downward into brine. This report documents the final two test series. In the first, the plume hydrodynamics experiments were completed using SPR oil, brine, and sludge. In the second, oil reinjection into brine was run for approximately 6 hours, and sampling of oil, sludge, and brine was performed over the next 3 months so that the long-term effects of oil-sludge mixing could be assessed. For both series, the experiment consisted of a large transparent vessel that is a scale model of the proposed oil-injection process at the SPR. For the plume hydrodynamics experiments, an oil layer was floated on top of a brine layer in the first test series and on top of a sludge layer residing above the brine in the second test series. The oil was injected downward through a tube into the brine at a prescribed depth below the oil-brine or sludge-brine interface. Flow rates were determined by scaling to match the ratio of buoyancy to momentum between the experiment and the SPR. Initially, the momentum of the flow produces a downward jet of oil below the tube end. Subsequently, the oil breaks up into droplets due to shear forces, buoyancy dominates the flow, and a plume of oil droplets rises to the interface. The interface was deflected upward by the impinging oil-brine plume. Videos of this flow were recorded for scaled flow rates that bracket the equivalent pumping rates in an SPR cavern during injection of degassed oil. Image-processing analyses were performed to quantify the penetration depth and width of the oil jet. The measured penetration depths were shallow, as predicted by penetration-depth models, in agreement with the assumption that the flow is buoyancy-dominated, rather than momentum-dominated. The turbulent penetration depth model overpredicted the measured values. Both the oil-brine and oil-sludge-brine systems produced plumes with hydrodynamic characteristics similar to the simulant liquids previously examined, except that the penetration depth was 5-10% longer for the crude oil. An unexpected observation was that centimeter-size oil 'bubbles' (thin oil shells completely filled with brine) were produced in large quantities during oil injection. The mixing experiments also used layers of oil, sludge, and brine from the SPR. Oil was injected at a scaled flow rate corresponding to the nominal SPR oil injection rates. Injection was performed for about 6 hours and was stopped when it was evident that brine was being ingested by the oil withdrawal pump. Sampling probes located throughout the oil, sludge, and brine layers were used to withdraw samples before, during, and after the run. The data show that strong mixing caused the water content in the oil layer to increase sharply during oil injection but that the water content in the oil dropped back to less than 0.5% within 16 hours after injection was terminated. On the other hand, the sediment content in the oil indicated that the sludge and oil appeared to be well mixed. The sediment settled slowly but the oil had not returned to the baseline, as-received, sediment values after approximately 2200 hours (3 months). Ash content analysis indicated that the sediment measured during oil analysis was primarily organic.

Castaneda, Jaime N.; Cote, Raymond O.; Torczynski, John Robert; O'Hern, Timothy John

2004-05-01T23:59:59.000Z

54

Portable brine evaporator unit, process, and system  

DOE Patents [OSTI]

The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

Hart, Paul John (Indiana, PA); Miller, Bruce G. (State College, PA); Wincek, Ronald T. (State College, PA); Decker, Glenn E. (Bellefonte, PA); Johnson, David K. (Port Matilda, PA)

2009-04-07T23:59:59.000Z

55

Fate of Magnesium Chloride Brine Applied to Suppress Dust from Unpaved Roads at the INEEL Subsurface Disposal Area  

SciTech Connect (OSTI)

Between 1984 and 1993, MgCl2 brine was used to suppress dust on unpaved roads at a radioactive waste subsurface disposal area. Because Cl– might enhance corrosion of buried metals in the waste, we investigated the distribution and fate of Cl– in the vadose zone using pore water samples collected from suction lysimeters and soluble salt concentrations extracted from sediment samples. The Cl/Br mass ratio and the total dissolved Cl– concentration of pore water show that brine contamination occurs primarily within 13 m of treated roads, but can extend as much as 30 m laterally in near-surface sedimentary deposits. Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests formation of perched water and horizontal transport during periods of high recharge. In a few locations, brine migrated to depths of 67 m within 3 to 5 yr. Elevated Cl– concentrations were found to depths of 2 m in roadbed material. In drainage ditches along roads, where runoff accumulates and recharge of surface water is high, Cl– was flushed from the sediments in 3 to 4 yr. In areas of lower recharge, Cl– remained in the sediments after 5 yr. Vertical brine movement is directly related to surface recharge through sediments. The distribution of Cl– in pore water and sediments is consistent with estimates of vadose zone residence times and spatial distribution of surface water recharge from other investigations at the subsurface

Larry Hull; Carolyn Bishop

2004-02-01T23:59:59.000Z

56

Expected brine movement at potential nuclear waste repository salt sites  

SciTech Connect (OSTI)

The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

McCauley, V.S.; Raines, G.E.

1987-08-01T23:59:59.000Z

57

Models of Geothermal Brine Chemistry  

SciTech Connect (OSTI)

Many significant expenses encountered by the geothermal energy industry are related to chemical effects. When the composition, temperature of pressure of the fluids in the geological formation are changed, during reservoir evolution, well production, energy extraction or injection processes, the fluids that were originally at equilibrium with the formation minerals come to a new equilibrium composition, temperature and pressure. As a result, solid material can be precipitated, dissolved gases released and/or heat lost. Most geothermal energy operations experience these phenomena. For some resources, they create only minor problems. For others, they can have serious results, such as major scaling or corrosion of wells and plant equipment, reservoir permeability losses and toxic gas emission, that can significantly increase the costs of energy production and sometimes lead to site abandonment. In future operations that exploit deep heat sources and low permeability reservoirs, new chemical problems involving very high T, P rock/water interactions and unknown injection effects will arise.

Nancy Moller Weare; John H. Weare

2002-03-29T23:59:59.000Z

58

West Hackberry Brine Disposal Project pre-discharge characterization. Final report  

SciTech Connect (OSTI)

The physical, chemical and biological attributes are described for: (1) a coastal marine environment centered about a Department of Energy Strategic Petroleum Reserve (SPR) brine disposal site 11.4 km off the southwest coast of Louisiana; and (2) the lower Calcasieu and Sabine estuarine systems that provide leach waters for the SPR project. A three month sampling effort, February through April 1981, and previous investigations from the study area are integrated to establish baseline information for evaluation of impacts from brine disposal in the nearshore marine waters and from freshwater withdrawal from the coastal marsh of the Chenier Plain. January data are included for some tasks that sampled while testing and mobilizing their instruments prior to the February field effort. The study addresses the areas of physical oceanography, estuarine hydrology and hydrography, water and sediment quality, benthos, nekton, phytoplankton, zooplankton, and data management.

DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C. (eds.) [eds.

1982-01-01T23:59:59.000Z

59

PILOT TESTING: PRETREATMENT OPTIONS TO ALLOW RE-USE OF FRAC FLOWBACK AND PRODUCED BRINE FOR GAS SHALE RESOURCE DEVELOPMENT  

SciTech Connect (OSTI)

The goal of the A&M DOE NETL Project No. DE-FE0000847 was to develop a mobile, multifunctional water treatment capability designed specifically for “pre-treatment” of field waste brine. The project consisted of constructing s mobile “field laboratory” incorporating new technology for treating high salinity produced water and using the lab to conduct a side-by-side comparison between this new technology and that already existing in field operations. A series of four field trials were performed utilizing the mobile unit to demonstrate the effectiveness of different technology suitable for use with high salinity flow back brines and produced water. The design of the mobile unit was based on previous and current work at the Texas A&M Separation Sciences Pilot Plant. The several treatment techniques which have been found to be successful in both pilot plant and field tests had been tested to incorporate into a single multifunctional process train. Eight different components were evaluated during the trials, two types of oil and grease removal, one BTEX removal step, three micro-filters, and two different nanofilters. The performance of each technique was measured by its separation efficiency, power consumption, and ability to withstand fouling. The field trials were a success. Four different field brines were evaluated in the first trial in New York. Over 16,000 gallons of brine were processed. Using a power cost of $.10 per kWh, media pretreatment power use averaged $0.004 per barrel, solids removal $.04 per barrel and brine “softening” $.84 per barrel. Total power cost was approximately $1.00 per barrel of fluid treated. In Pennsylvania, brines collected from frac ponds were tested in two additional trials. Each of the brines was converted to an oil-free, solids-free brine with no biological activity. Brines were stable over time and would be good candidates for use as a make-up fluid in a subsequent fracturing fluid design. Reports on all of the field trials and subcontractor research have been summarized in this Final Report. Individual field trial reports and research reports are contained in the companion volume titled “Appendices”

Burnett, David

2012-12-31T23:59:59.000Z

60

Radionuclide transport in sandstones with WIPP brine  

SciTech Connect (OSTI)

Retardation factors (R) have been measured for the transport of /sup 3/H, /sup 95m/Tc, and /sup 85/Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for /sup 85/Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for /sup 85/Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta.

Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

1981-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Geochemistry of Aluminum in High Temperature Brines  

SciTech Connect (OSTI)

The objective ofthis research is to provide quantitative data on the equilibrium and thermodynamic properties of aluminum minerals required to model changes in permeability and brine chemistry associated with fluid/rock interactions in the recharge, reservoir, and discharge zones of active geothermal systems. This requires a precise knowledge of the thermodynamics and speciation of aluminum in aqueous brines, spanning the temperature and fluid composition rangesencountered in active systems. The empirical and semi-empirical treatments of the solubility/hydrolysis experimental results on single aluminum mineral phases form the basis for the ultimate investigation of the behavior of complex aluminosilicate minerals. The principal objective in FY 1998 was to complete the solubility measurements on boehmite (AIOOH) inNaC1 media( 1 .O and 5.0 molal ionic strength, IOO-250°C). However, additional measurements were also made on boehmite solubility in pure NaOH solutions in order to bolster the database for fitting in-house isopiestic data on this system. Preliminary kinetic Measurements of the dissolution/precipitation of boehmite was also carried out, although these were also not planned in the earlier objective. The 1999 objectives are to incorporate these treatments into existing codes used by the geothermal industry to predict the chemistry ofthe reservoirs; these calculations will be tested for reliability against our laboratory results and field observations. Moreover, based on the success of the experimental methods developed in this program, we intend to use our unique high temperature pH easurement capabilities to make kinetic and equilibrium studies of pH-dependent aluminosilicate transformation reactions and other pH-dependent heterogeneous reactions.

Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.

1999-05-18T23:59:59.000Z

62

Hydrological and geochemical monitoring for a CO2 sequestration pilot in a brine formation  

SciTech Connect (OSTI)

Hydrological and geochemical monitoring are key components of site characterization and CO2 plume monitoring for a pilot test to inject CO2 into a brine-bearing sand of the fluvial-deltaic Frio formation in the upper Texas Gulf Coast. In situ, injected CO2 forms a supercritical phase that has gas-like properties (low density and viscosity) compared to the surrounding brine, while some CO2 dissolves in the brine. The pilot test employs one injection well and one monitor well, with continuous pressure and flow-rate monitoring in both wells, and continuous surface fluid sampling and periodic down-hole fluid sampling from the monitor well. Pre-injection site-characterization includes pump tests with pressure-transient analysis to estimate single-phase flow properties, establish hydraulic connectivity between the wells, determine appropriate boundary conditions, and analyze ambient phase conditions within the formation. Additionally, a pre-injection tracer test furnishes estimates of kinematic porosity and the geometry of flow paths between injection and monitor wells under single-phase conditions. Pre-injection geochemical sampling provides a baseline for subsequent geochemical monitoring and helps determine the optimal tracers to accompany CO2 injection. During CO2 injection, hydrological monitoring enables estimation of two-phase flow properties and helps track the movement of the injected CO2 plume, while geochemical sampling provides direct evidence of the arrival of CO2 and tracers at the monitor well. Furthermore, CO2-charged water acts as a weak acid, and reacts to some extent with the minerals in the aquifer, producing a distinct chemical signature in the water collected at the monitor well. Comparison of breakthrough curves for the single-phase tracer test and the CO2 (and its accompanying tracers) illuminates two-phase flow processes between the supercritical CO2 and native brine, an area of current uncertainty that must be better understood to effectively sequester CO2 in saline aquifers.

Doughty, Christine; Pruess, Karsten; Benson, Sally M.; Freifeld, Barry M.; Gunter, William D.

2004-05-17T23:59:59.000Z

63

The feasibility of deep well injection for brine disposal  

E-Print Network [OSTI]

feasibility. The methodology is utilized to make a preliminary evaluation of a proposed brine injection project in the Dove Creek area of King and Stonewall Counties, North Central Texas. Four known deep aquifers are modeled, using the SWIFT/486 software...

Spongberg, Martin Edward

1994-01-01T23:59:59.000Z

64

ABSORBING WIPP BRINES: A TRU WASTE DISPOSAL STRATEGY  

SciTech Connect (OSTI)

Los Alamos National Laboratory (LANL) has completed experiments involving 15 each, 250- liter experimental test containers of transuranic (TRU) heterogeneous waste immersed in two types of brine similar to those found in the underground portion of the Waste Isolation Pilot Plant (WIPP). To dispose of the waste without removing the brine from the test containers, LANL added commercially available cross-linked polyacrylate granules to absorb the 190 liters of brine in each container, making the waste compliant for shipping to the WIPP in a Standard Waste Box (SWB). Prior to performing the absorption, LANL and the manufacturer of the absorbent conducted laboratory and field tests to determine the ratio of absorbent to brine that would fully absorb the liquid. Bench scale tests indicated a ratio of 10 parts Castile brine to one part absorbent and 6.25 parts Brine A to one part absorbent. The minimum ratio of absorbent to brine was sought because headspace in the containers was limited. However, full scale testing revealed that the ratio should be adjusted to be about 15% richer in absorbent. Additional testing showed that the absorbent would not apply more than 13.8 kPa pressure on the walls of the vessel and that the absorbent would still function normally at that pressure and would not degrade in the approximately 5e-4 Sv/hr radioactive field produced by the waste. Heat generation from the absorption was minimal. The in situ absorption created a single waste stream of 8 SWBs whereas the least complicated alternate method of disposal would have yielded at least an additional 2600 liters of mixed low level liquid waste plus about two cubic meters of mixed low level solid waste, and would have resulted in higher risk of radiation exposure to workers. The in situ absorption saved $311k in a combination of waste treatment, disposal, material and personnel costs compared to the least expensive alternative and $984k compared to the original plan.

Yeamans, D. R.; Wrights, R. S.

2002-02-25T23:59:59.000Z

65

Absorbing WIPP brines : a TRU waste disposal strategy.  

SciTech Connect (OSTI)

Los Alamos National Laboratory (LANL) has completed experiments involving 15 each, 250-liter experimental test containers of transuranic (TRU) heterogeneous waste immersed in two types of brine similar to those found in the underground portion of the Waste Isolation Pilot Plant (WIPP). To dispose of the waste without removing the brine from the test containers, LANL added commercially available cross-linked polyacrylate granules to absorb the 190 liters of brine in each container, making the waste compliant for shipping to the WlPP in a Standard Waste Box (SWB). Prior to performing the absorption, LANL and the manufacturer of the absorbent conducted laboratory and field tests to determine the ratio of absorbent to brine that would fully absorb the liquid. Bench scale tests indicated a ratio of 10 parts Castile brine to one part absorbent and 6.25 parts Brine A to one part absorbent. The minimum ratio of absorbent to brine was sought because headspace in the containers was limited. However, full scale testing revealed that the ratio should be adjusted to be about 15% richer in absorbent. Additional testing showed that the absorbent would not apply more than 13.8 kPa pressure on the walls of the vessel and that the absorbent would still function normally at that pressure and would not degrade in the approximately 5e-4 Sv/hr radioactive field produced by the waste. Heat generation from the absorption was minimal. The in situ absorption created a single waste stream of 8 SWBs whereas the least complicated alternate method of disposal would have yielded at least an additional 2600 liters of mixed low level liquid waste plus about two cubic meters of mixed low level solid waste, and would have resulted in higher risk of radiation exposure to workers. The in situ absorption saved $3 1 lk in a combination of waste treatment, disposal, material and personnel costs compared to the least expensive alternative and $984k compared to the original plan.

Yeamans, D. R. (David R.); Wright, R. (Robert)

2002-01-01T23:59:59.000Z

66

West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume II. Physical and chemical oceanography. Final report  

SciTech Connect (OSTI)

This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which is located in southwestern Louisiana, and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Contents of Volume II include: introduction; physical oceanography; estuarine hydrology and hydrography; analysis of discharge plume; and water and sediment quality.

DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J. (eds.)

1983-02-01T23:59:59.000Z

67

Determination of imidazoline and amido-amine type corrosion inhibitors in both crude oil and produced brine from oilfield production  

SciTech Connect (OSTI)

The classical method for the determination of corrosion inhibitors in oilfield brines is the dye transfer method. Within this method are many variations which the analyst may use to determine the amount of corrosion inhibitor in either water or crude oil. These methods, however, suffer from many interferences which result in both false positive and negatives for corrosion inhibitor content. These methods essentially detect all amines as corrosion inhibitors. Improved high pressure liquid chromatography (HPLC) methods have been developed for the analysis of quaternary salt type corrosion inhibitors in brine waters, however, these methods do not appear to work in crude oil or for other forms of corrosion inhibitors such as the imidazolines, and amido-amines. This paper presents a method for the quantitative analysis of the imidazoline and amido-amine type corrosion inhibitors in both oilfield water and crude oil samples by HPLC. The corrosion inhibitor of interest is first separated from the matrix on a small column, then derivatized to form a product which is both sensitive and selective on a fluorescence detector. Detection limits for imidazolines are around 0.2 mg/L, amides and amines are similar. The advantage of this procedure is it can be used to determine the amount of corrosion inhibitor in both oil and brine water phases as well as on solid surfaces.

Matherly, R.M.; Jiao, J. [Baker Performance Chemicals, Houston, TX (United States); Blumer, D.J. [ARCO Alaska Inc., Anchorage, AK (United States); Ryman, J.S. [Baker Performance Chemicals, Anchorage, AK (United States)

1995-12-01T23:59:59.000Z

68

Brian G. Rahm, Ph.D. NYS Water Resources Institute  

E-Print Network [OSTI]

of groundwater contamination. He then moved to New Zealand and spent a year engaged in climate change policy: Brine & frac fluid ­ Also known as flowback and produced water, includes water used for hydraulic by the relatively dry shale bed. Once the well is in production, relatively low volumes of "produced water" or brine

Danforth, Bryan Nicholas

69

Actinide (III) solubility in WIPP Brine: data summary and recommendations  

SciTech Connect (OSTI)

The solubility of actinides in the +3 oxidation state is an important input into the Waste Isolation Pilot Plant (WIPP) performance assessment (PA) models that calculate potential actinide release from the WIPP repository. In this context, the solubility of neodymium(III) was determined as a function of pH, carbonate concentration, and WIPP brine composition. Additionally, we conducted a literature review on the solubility of +3 actinides under WIPP-related conditions. Neodymium(III) was used as a redox-invariant analog for the +3 oxidation state of americium and plutonium, which is the oxidation state that accounts for over 90% of the potential release from the WIPP through the dissolved brine release (DBR) mechanism, based on current WIPP performance assessment assumptions. These solubility data extend past studies to brine compositions that are more WIPP-relevant and cover a broader range of experimental conditions than past studies.

Borkowski, Marian; Lucchini, Jean-Francois; Richmann, Michael K.; Reed, Donald T.

2009-09-01T23:59:59.000Z

70

Brine-in-crude-oil emulsions at the Strategic Petroleum Reserve.  

SciTech Connect (OSTI)

Metastable water-in-crude-oil emulsion formation could occur in a Strategic Petroleum Reserve (SPR) cavern if water were to flow into the crude-oil layer at a sufficient rate. Such a situation could arise during a drawdown from a cavern with a broken-hanging brine string. A high asphaltene content (> 1.5 wt %) of the crude oil provides the strongest predictor of whether a metastable water-in-crude-oil emulsion will form. However there are many crude oils with an asphaltene content > 1.5 wt % that don't form stable emulsions, but few with a low asphaltene content that do form stable emulsions. Most of the oils that form stable emulsions are %E2%80%9Csour%E2%80%9D by SPR standards indicating they contain total sulfur > 0.50 wt %.

Nemer, Martin B.; Lord, David L.; MacDonald, Terry L.

2013-10-01T23:59:59.000Z

71

Wetting behavior of selected crude oil/brine/rock systems. Topical report, March 1, 1995--March 31, 1996  

SciTech Connect (OSTI)

Previous studies of crude oil/brine/rock (COBR) and related ensembles showed that wettability and its effect on oil recovery depend on numerous complex interactions. In the present work, the wettability of COBR ensembles prepared using Prudhoe Bay crude oil, a synthetic formation brine, and Berea Sandstone was varied by systematic change in initial water saturation and length of aging time at reservoir temperature (88 C). All displacement tests were run at ambient temperature. Various degrees of water wetness were achieved and quantified by a modified Amott wettability index to water, the relative pseudo work of imbibition, and a newly defined apparent advancing dynamic contact angle. Pairs of spontaneous imbibition (oil recovery by spontaneous imbibition of water) and waterflood (oil recovery vs. pore volumes of water injected) curves were measured for each of the induced wetting states. Several trends were observed. Imbibition rate, and hence water wetness, decreased with increase in aging time and with decrease in initial water saturation. Breakthrough recoveries and final oil recovery by waterflooding increased with decrease in water wetness. Correlations between water wetness and oil recovery by waterflooding and spontaneous imbibition are presented.

Zhou, X.; Morrow, N.R.; Ma, S.

1996-12-31T23:59:59.000Z

72

West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume IV. Bibliography and supporting data for physical oceanography. Final report. [421 references  

SciTech Connect (OSTI)

This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which is located in southwestern Louisiana and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Volume IV contains the following: bibliography; appendices for supporting data for physical oceanography, and summary of the physical oceanography along the western Louisiana coast.

DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J. (eds.) [eds.

1983-02-01T23:59:59.000Z

73

Geochemical evidence for possible natural migration of Marcellus Formation brine to  

E-Print Network [OSTI]

as the potential for contamination from toxic substances in hydraulic fracturing fluid and/or pro- duced brinesGeochemical evidence for possible natural migration of Marcellus Formation brine to shallow of stray gas, metal-rich formation brines, and hydrau- lic fracturing and/or flowback fluids to drinking

74

Pressure Buildup and Brine Migration During CO2 Storage in Multilayered Aquifers  

E-Print Network [OSTI]

leakage of brine into shallow groundwater resources. Pressurized brine can also be pushed into overlying. Introduction Carbon dioxide capture combined with geologic stor- age (CCS) in suitable subsurface formations of resident brine caused by CCS operations require modeling/analysis tools of considerable complexity (Celia

Zhou, Quanlin

75

Advanced biochemical processes for geothermal brines: Current developments  

SciTech Connect (OSTI)

A research program at Brookhaven National Laboratory (BNL) which deals with the development and application of processes for the treatment of geothermal brines and sludges has led to the identification and design of cost-efficient and environmentally friendly treatment methodology. Initially the primary goal of the processing was to convert geothermal wastes into disposable materials whose chemical composition would satisfy environmental regulations. An expansion of the r and D effort identified a combination of biochemical and chemical processes which became the basis for the development of a technology for the treatment of geothermal brines and sludges. The new technology satisfies environmental regulatory requirements and concurrently converts the geothermal brines and sludges into commercially promising products. Because the chemical composition of geothermal wastes depends on the type of the resource, the emerging technology has to be flexible so that it can be readily modified to suit the needs of a particular type of resource. Recent conceptional designs for the processing of hypersaline and low salinity brines and sludges will be discussed.

Premuzic, E.T.; Lin, M.S.; Bohenek, M. [Brookhaven National Lab., Upton, NY (United States). Energy Science and Technology Div.; Bajsarowicz, V. [CET Environmental Services, Inc., Richmond, CA (United States); McCloud, M. [C.E. Holt/California Energy, Pasadena, CA (United States)

1997-07-07T23:59:59.000Z

76

Water Treatment using Electrocoagulation Ritika Mohan  

E-Print Network [OSTI]

Reverse Osmosis (HEROTM). Semiconductor industrial waste water amounts to approximately 105 ­ 106 gal of brine amounting to almost 103 104 gal/day water. The difference between conventional Reverse Osmosis

Fay, Noah

77

Evaluation of brine disposal from the Bryan Mound site of the strategic petroleum reserve program. Final report  

SciTech Connect (OSTI)

On March 10, 1980, the Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging the resulting brine into the coastal waters off Freeport, Texas. During the months of March and April, a team of scientists and engineers from Texas A and M University conducted an intensive environmental study of the area surrounding the diffuser site. A pipeline has been laid from the Bryan Mound site to a location 12.5 statute miles (20 km) offshore. The last 3060 ft (933 m) of this pipeline is a 52-port diffuser through which brine can be discharged at a maximum rate of 680,000 barrels per day. Initially, 16 ports were open which permitted a maximum discharge rate of 350,000 barrels per day and a continuous brine discharge was achieved on March 13, 1980. The purpose of this report is to describe the findings of the project team during the intensive postdisposal study period of March and April, 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management.

Case, Robert J.; Chittenden, Jr, Mark E.; Harper, Jr, Donald E.; Kelly, Jr, Francis J.; Loeblich, Laurel A.; McKinney, Larry D.; Minello, Thomas J.; Park, E. Taisoo; Randall, Robert E.; Slowey, J. Frank

1981-01-01T23:59:59.000Z

78

Results of brine flow testing and disassembly of a crushed salt/bentonite block seal at the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

The Small-Scale Seal Performance Tests, Series C, a set of in situ experiments conducted at the Waste Isolation Pilot Plant, are designed to evaluate the performance of various seal materials emplaced in large (0.9-m-diameter) boreholes. This report documents the results of fluid (brine) flow testing and water and clay content analyses performed on one emplaced seal comprised of 100% salt blocks and 50%/50% crushed salt/bentonite blocks and disassembled after nearly three years of brine injection testing. Results from the water content analyses of 212 samples taken from within this seal show uniform water content throughout the 50%/50% salt/bentonite blocks with saturations about 100%. Clay content analyses from the 100% salt endcaps of the seal show a background clay content of about 1% by weight uniformly distributed, with the exception of samples taken at the base of the seal at the borehole wall interface. These samples show clay contents up to 3% by weight, which suggests some bentonite may have migrated under pressure to that interface. Results of the brine-flow testing show that the permeability to brine for this seal was about 2 to 3 {times} 10{sup {minus}4} darcy (2 to 3 {times} 10{sup {minus}16} m{sup 2}).

Finley, R.E. [Sandia National Labs., Albuquerque, NM (United States); Jones, R.L. [Tech. Reps., Inc., Albuquerque, NM (United States)

1994-03-01T23:59:59.000Z

79

Report on design, construction, and testing of CO/sub 2/ breakout system for geothermal brines  

SciTech Connect (OSTI)

A skid mounted test facility has been built for determining conditions at which CO/sub 2/ flashes from geothermal brines. The system has been checked and operated at one geothermal plant. It performed as designed. The equipment is designed to operate at temperatures and pressures typical of wells near Heber, California. (Nominally 180/sup 0/C and 300 to 500 psig). It has heat exchangers which can cool the brine to less than 70/sup 0/C. (The cooling water is recirculated after being cooled by a forced air heat exchanger). Breakout pressures can be determined for any temperature between 70/sup 0/C and wellhead temperature. An adjustable orifice provides final control on pressure required to initiate flashing. The orifice is at the bottom of a sight glass. A light beam shines through the sight glass and focuses on a photoelectric cell. The presence of bubbles scatters light and decreases the output of the cell. Results using the cell were more reproducible than those using the naked eye. Results from one test show a smooth curve over the temperature range 75/sup 0/C to 165/sup 0/C. Agreement between the experimental values and calculated ones is discussed.

Robertus, R.J.; Shannon, D.W.; Sullivan, R.G.

1984-03-01T23:59:59.000Z

80

Summary Results for Brine Migration Modeling Performed by LANL LBNL and SNL for the UFD Program  

SciTech Connect (OSTI)

This report summarizes laboratory and field observations and numerical modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies conducted at Sandia, Los Alamos, and Berkeley National Laboratories. Interest into the disposal of heat-generating waste in salt has led to interest into water distribution and migration in both run-of-mine crushed and intact geologic salt. Ideally a fully coupled thermal-hydraulic-mechanical-chemical simulation is performed using numerical models with validated constitutive models and parameters. When mechanical coupling is not available, mechanical effects are prescribed in hydraulic models as source, boundary, or initial conditions. This report presents material associated with developing appropriate initial conditions for a non-mechanical hydrologic simulation of brine migration in salt. Due to the strong coupling between the mechanical and hydrologic problems, the initial saturation will be low for the excavation disturbed zone surrounding the excavation. Although most of the material in this report is not new, the author hopes it is presented in a format making it useful to other salt researchers.

Kuhlman, Kristopher L.

2014-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Development of a flow injection analysis method for the determination of acrylamide copolymers in oilfield brines  

SciTech Connect (OSTI)

An automated method for the determination of acrylamide polymers by flow injection analysis (FIA) has been developed and optimized for routine use. The method has been extensively tested for interferences common in oilfield brines. Potential interferences were examined from Na{sup +}, Ca{sup 2+}, Cr{sup 3+}, Al{sup 3+}, Zr{sup 3+}, NH{sub 4}{sup +}, Cl{sup {minus}}, OH{sup {minus}}, CO{sub 3}{sup 2{minus}}, sample coloration, and commonly used surfactants. The analysis is specific for amides, and the sensitivity to concentration of amide groups in the polymer was shown to be constant as the degree of polymer hydrolysis was varied. The range of the method is 0.1 to 100 mg/L. Sample throughput is 30 samples/h with triplicate analysis. Relative standard deviations of 0.2% are readily obtained from standard solutions and 0.5% from complex samples (at 50 mg/L). The method is applicable to the determination of aqueous, acrylamide-based polymers in process streams, surface waters and oilfield brines.

Taylor, K.C.; Burke, R.A.; Schramm, L.L. [Petroleum Recovery Inst., Calgary, Alberta (Canada); Nasr-El-Din, H.A. [Saudi Aramco, Dhahran (Saudi Arabia)

1995-11-01T23:59:59.000Z

82

Modeling Coupled THMC Processes and Brine Migration in Salt at High Temperatures  

SciTech Connect (OSTI)

In this report, we present FY2014 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. LBNL’s work on the modeling of coupled THMC processes in salt was initiated in FY2012, focusing on exploring and demonstrating the capabilities of an existing LBNL modeling tool (TOUGH-FLAC) for simulating temperature-driven coupled flow and geomechanical processes in salt. This work includes development related to, and implementation of, essential capabilities, as well as testing the model against relevant information and published experimental data related to the fate and transport of water. we provide more details on the FY2014 work, first presenting updated tools and improvements made to the TOUGH-FLAC simulator, and the use of this updated tool in a new model simulation of long-term THM behavior within a generic repository in a salt formation. This is followed by the description of current benchmarking and validations efforts, including the TSDE experiment. We then present the current status in the development of constitutive relationships and the dual-continuum model for brine migration. We conclude with an outlook for FY2015, which will be much focused on model validation against field experiments and on the use of the model for the design studies related to a proposed heater experiment.

Rutqvist, Jonny; Blanco Martin, Laura; Mukhopadhyay, Sumit; Houseworth, Jim; Birkholzer, Jens

2014-08-14T23:59:59.000Z

83

24/02/2012 12:49SPE Projects, Facilities & Construction -CO2/Brine Surface Dissolution and Injection: CO2 Storage Enhancement Page 1 of 1http://www.spe.org/ejournals/jsp/journalapp.jsp?pageType=Preview&jid=EFC&pdfChronicleId=090147628022501b&mid=SPE-12471  

E-Print Network [OSTI]

of reducing atmospheric emissions of greenhouse gases from coal or gas-fired power plants. The upward buoyancy or supercritical phase, as water-alternating-gas cycles, or as carbonated brine. These result in different

Haszeldine, Stuart

84

Evaluation of materials for systems using cooled, treated geothermal or high-saline brines  

SciTech Connect (OSTI)

Lack of adequate quantities of clean surface water for use in wet (evaporative) cooling systems indicates the use of high-salinity waste waters, or cooled geothermal brines, for makeup purposes. High-chloride, aerated water represents an extremely corrosive environment. In order to determine metals suitable for use in such an environment, metal coupons were exposed to aerated, treated geothermal brine salted to a chloride concentration of 10,000 and 50,000 ppM (mg/L) for periods of up to 30 days. The exposed coupons were evaluated to determine the general, pitting, and crevice corrosion characteristics of the metals. The metals exhibiting corrosion resistance at 50,000 ppM chloride were then evaluated at 100,000 and 200,000 ppM chloride. Since these were screening tests to select materials for components to be used in a cooling system, with primary emphasis on condenser tubing, several materials were exposed for 4 to 10 months in pilot cooling tower test units with heat transfer for further corrosion evaluation. The results of the screening tests indicate that ferritic stainless steels (29-4-2 and SEA-CURE) exhibit excellent corrosion resistance at all levels of chloride concentration. Copper-nickel alloys (70/30 and Monel 400) exhibited excellent corrosion resistance in the high-saline water. The 70/30 copper-nickel alloy, which showed excellent resistance to general corrosion, exhibited mild pitting in the 30-day tests. This pitting was not apparent, however, after 6 months of exposure in the pilot cooling tower tests. The nickel-base alloys exhibited excellent corrosion resistance, but their high cost prevents their use unless no other material is found feasible. Other materials tested, although unsuitable for condenser tubing material, would be suitable as tube sheet material.

Suciu, D.F.; Wikoff, P.M.

1982-09-01T23:59:59.000Z

85

Characterization of a soil contaminated by oilfield brine  

SciTech Connect (OSTI)

Brine contamination of soil is a common environmental problem associated with the onshore production of oil and gas. A site of extensive contamination in Oklahoma has been characterized using conductimetry, direct potentiometry (pH- and chloride-selective electrodes), and atomic absorption spectrophotometry (for Na{sup +} and Ca{sup 2+}) to determine the extent of the contamination and the efficacy of various remediation technologies.

Al-Mutairi, K.; Harris, T. [Univ. of Tulsa, OH (United States)

1995-12-01T23:59:59.000Z

86

2 INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 EXPERIMENTAL STUDY OF CRUDE/BRINE/ROCK INTERACTION AT  

E-Print Network [OSTI]

as the temperature increased. The aging of low permeability cores saturated with oil had little effect in the rate44 2 INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 EXPERIMENTAL STUDY OF CRUDE in this section and expand the understanding of the interactions of the Spraberry reservoir rock, oil and brine

Schechter, David S.

87

1. Constituents of rainwater 2. pH and pKa  

E-Print Network [OSTI]

Acid Rain Outline: 1. Constituents of rainwater 2. pH and pKa 3. Sources of acid rain 4. Adverse e#11;ects of acid rain 5. Controls 1: Constituents of rainwater #15; Gases are soluble in water: Henry. Strong acids formed upon dissolving: H 2 SO 4 and H 2 SO 3 . #12; Chemistry of Acid Rain #15; NO 2

Schofield, Jeremy

88

Foot-conditioned phonotactics and prosodic constituency  

E-Print Network [OSTI]

constituency by Ryan T. Bennett There has been a recurrentin LINGUISTICS by Ryan T. Bennett September 2012 TheDissertation of Ryan T. Bennett is approved: Professor Junko

Bennett, Ryan Thomas

2012-01-01T23:59:59.000Z

89

Apparatus and method for separating constituents  

DOE Patents [OSTI]

A centrifugal separator apparatus and method for improving the efficiency of the separation of constituents in a fluid stream. A cyclone separator includes an assembly for separately discharging both constituents through the same end of the separator housing. A rotary separator includes a rotary housing having a baffle disposed therein for minimizing the differential rotational velocities of the constituents in the housing, thereby decreasing turbulence, and increasing efficiency. The intensity of the centrifugal force and the time which the constituents reside within the housing can be independently controlled to improve efficiency of separation.

Maronde, Carl P. (McMurray, PA); Killmeyer, Jr., Richard P. (Pittsburgh, PA)

1992-01-01T23:59:59.000Z

90

RIS-M-2260 HEAT GRADIENT INDUCED MIGRATION OF BRINE INCLUSIONS IN ROCK SALT  

E-Print Network [OSTI]

RISŘ-M-2260 HEAT GRADIENT INDUCED MIGRATION OF BRINE INCLUSIONS IN ROCK SALT Mathematical treatment project. Abstract. A mathematical model for the brine migration in rock salt around an infinite line heat source is set up. The tempera- ture field around the time dependent heat source is calculated by use

91

Brine fluxes from growing sea ice A. J. Wells,1,2  

E-Print Network [OSTI]

. Introduction [2] The spatiotemporal distribution of the liquid phase within sea ice, a porous array of iceBrine fluxes from growing sea ice A. J. Wells,1,2 J. S. Wettlaufer,1,2,3 and S. A. Orszag2] It is well known that brine drainage from growing sea ice has a controlling influence on its mechanical

Wettlaufer, John S.

92

Brine flow up a borehole caused by pressure perturbation from CO2 storage: Static and dynamic evaluations  

E-Print Network [OSTI]

brine in the wellbore up to the base of the freshwater aquifer and would thereby lead to contamination.

Birkholzer, J.T.

2012-01-01T23:59:59.000Z

93

In cooperation with Fort Peck Tribes Office of Environmental Protection Delineation of Brine Contamination in and near the  

E-Print Network [OSTI]

;#12;Delineation of Brine Contamination in and near the East Poplar Oil Field, Fort Peck Indian Reservation citation: Thamke, J.N., and Smith, B.D., 2014, Delineation of brine contamination in and near the EastIn cooperation with Fort Peck Tribes Office of Environmental Protection Delineation of Brine

Torgersen, Christian

94

Using a multiphase flow code to model the coupled effects of repository consolidation and multiphase brine and gas flow at the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

Long-term repository assessment must consider the processes of (1) gas generation, (2) room closure and expansions due to salt creep, and (3) multiphase (brine and gas) fluid flow, as well as the complex coupling between these three processes. The mechanical creep closure code SANCHO was used to simulate the closure of a single, perfectly sealed disposal room filled with water and backfill. SANCHO uses constitutive models to describe salt creep, waste consolidation, and backfill consolidation, Five different gas-generation rate histories were simulated, differentiated by a rate multiplier, f, which ranged from 0.0 (no gas generation) to 1.0 (expected gas generation under brine-dominated conditions). The results of the SANCHO f-series simulations provide a relationship between gas generation, room closure, and room pressure for a perfectly sealed room. Several methods for coupling this relationship with multiphase fluid flow into and out of a room were examined. Two of the methods are described.

Freeze, G.A. [INTERA Inc., Albuquerque, NM (United States); Larson, K.W.; Davies, P.B.; Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States)

1995-10-01T23:59:59.000Z

95

SOLVENT EXTRACTION OF PHENOLS FROM WATER  

E-Print Network [OSTI]

coking (Wurm, 1968) • Phenols are also the principal organic constituents in con- densate waters formed during coal

Greminger, Douglas C.

2012-01-01T23:59:59.000Z

96

Probing the Constituent Structure of Black Holes  

E-Print Network [OSTI]

We calculate the cross section for scattering processes between graviton emitters on the near side of a Schwarzschild surface and absorbers on its far side, that is black hole constituents. We show that these scatterings allow to directly extract structural observables such as the momentum distribution of black hole constituents. For this we employ a quantum bound state description originally developed in quantum chromodynamics and recently applied to general relativity that allows to consider black holes in a relativistic Hartree like framework.

Lukas Gruending; Stefan Hofmann; Sophia Müller; Tehseen Rug

2014-12-12T23:59:59.000Z

97

Sustainable development through beneficial use of produced water for the oil and gas industry  

E-Print Network [OSTI]

Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced...

Siddiqui, Mustafa Ashique

2002-01-01T23:59:59.000Z

98

Oil removal for produced water treatment and micellar cleaning of ultrafiltration membranes  

E-Print Network [OSTI]

a research project that evaluated the treatment of brine generated in oil fields (produced water) with ultrafiltration membranes. The characteristics of various ultrafiltration membranes for oil and suspended solids removal from produced water were...

Beech, Scott Jay

2006-10-30T23:59:59.000Z

99

Removing Radium-226 Contamination From Ion Exchange Resins Used in Drinking Water Treatment  

E-Print Network [OSTI]

Removing Radium-226 Contamination From Ion Exchange Resins Used in Drinking Water Treatment P r o b of groundwater containing high levels of radium-226 activity (Objective 1) were regenerated with prescribed brine that the concentration of salt in the brine cleaning solution was the most influential factor in the resin regeneration

100

Hybrid electrodialysis reverse osmosis system design and its optimization for treatment of highly saline brines  

E-Print Network [OSTI]

The demand is rising for desalination technologies to treat highly saline brines arising from hydraulic fracturing processes and inland desalination. Interest is growing in the use of electrical desalination technologies ...

McGovern, Ronan Killian

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Efficacy of Ultraviolet Light and Antimicrobials to Reduce Listeria monocytogenes in Chill Brines.  

E-Print Network [OSTI]

??Chill brines used in ready-to-eat meat processing may be an important source of post-processing contamination by Listeria monocytogenes. The purpose of this study was to… (more)

Parikh, Priti P.

2007-01-01T23:59:59.000Z

102

Remediation of brine-contaminated soil using calcium nitrate, gypsum, and straw.  

E-Print Network [OSTI]

??Salt-affected soils from point source brine contamination are common in the active oil field in SE Saskatchewan. A remediation process that included dewatering by sub-surface… (more)

Nielsen, Jennifer I.

2013-01-01T23:59:59.000Z

103

Behavior of type 304 and type 316 austenitic stainless in 55% lithium bromide heavy brine environments  

SciTech Connect (OSTI)

Cylindrical tensile specimens of AISI type 304 (UNS S30400) and type 316 (UNS S31600) stainless steels (SS) were tested under constant-load conditions in 55% lithium bromide (LiBr) heavy brines at temperatures of 120 C and 140 C. Elongation and open-circuit potential (OCP) were recorded during the tensile test. Potentiodynamic polarization measurements were conducted, and the failed surface fractures were examined by scanning electron microscopy. The tested SS were subjected to stress corrosion under the test environments. Sensitivity was affected strongly by pH values. In LiBr brine of pH = 11.6, the passivation processes were more effective than in brine of pH = 6 [approximately] 8. Because of effective passivation behavior in brine of pH = 11.6, lower values of [delta]l[sub 0] were measured, indicating lower dislocation relaxation processes and high resistance to stress corrosion cracking.

Itzhak, D.; Elias, O. (Ben-Gurion Univ., Beer-Sheva (Israel). Dept. of Materials Engineering)

1994-02-01T23:59:59.000Z

104

E-Print Network 3.0 - acartia tonsa brine Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for: acartia tonsa brine Page: << < 1 2 3 4 5 > >> 1 Vol. 114: 203-208,1994 MARINE ECOLOGY PROGRESS SERIES Summary: . divergens attacking it. Ingestion rates of P, cf....

105

Seizing a species : the story of the Great Salt Lake brine shrimp harvest  

E-Print Network [OSTI]

In the early 1950s, C.C. "Sparkplug" Sanders began harvesting brine shrimp from Utah's Great Salt Lake. Sanders built up a small business selling their eggs, called "cysts, to aquarium stores across the country. During the ...

Wotipka, Samuel Alex

2014-01-01T23:59:59.000Z

106

Soils and Brine Geochemistry and Mineralogy of Hyperarid Desert Playa, Ouargla Basin,  

E-Print Network [OSTI]

Soils and Brine Geochemistry and Mineralogy of Hyperarid Desert Playa, Ouargla Basin, Algerian. The chemical and mineralogical specificity of this hyperarid ecosystem has been compared to other areas under

Ahmad, Sajjad

107

New Energy Efficient Method for Cleaning Oilfield Brines with Carbon Dioxide  

E-Print Network [OSTI]

NEW ENERGY EFFICIENT METHOD FOR CLEANING OILFIELD BRINES WITH CARBON DIOXIDE C. T. LITTLE A. F. SEIBERT Research Engineer Technical Manager Amoco Oil Company Separations Research Program Naperville, Illinois The University of Texas Austin... dioxide to clean oilfield brines. The new treatment method, described in this work, is actually an enhancement of existing gas flotation technology. The enhancement results from the use of carbon dioxide as the sweeping gas combined with its ability...

Little, C. T.; Seibert, A. F.; Bravo, J. L.; Fair, J. R.

108

Hard-bottom macrofauna of the East Flower Garden brine seep: impact of a long term, point-source brine discharge  

E-Print Network [OSTI]

canyon transect were sta- tions R6 and R7, both of which were on top of Cottonwick Rock, ap- proximately 2 m above the canyon floor. Figure 5 (p. 12) shows that salinity and sulfide at these stations were at normal marine levels. Though the total...HARD-BOT1'OM MACROFAUNA OF THE EAST FLOWER GARDEN BRINE SEEP: IMPACT OF A LONG TERM, POINT-SOURCE BRINE DISCHARGE A Thesis by STEPHEN REED GITTINGS Submitted to the Graduate College of Texas A&M University in partial fulfillment...

Gittings, Stephen Reed

1983-01-01T23:59:59.000Z

109

Brine Sampling and Evaluation Program 1992--1993 report and summary of BSEP data since 1982  

SciTech Connect (OSTI)

This report is the last one that is currently scheduled in the sequence of reports of new data, and therefore, also includes summary comments referencing important data obtained by BSEP since 1983. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the (WIPP) Waste Isolation Pilot Plant. A project concern is that enough brine might be present after sealing and closure to generate large quantities of hydrogen gas by corroding the metal in the waste drums and waste inventory. This report describes progress made during the calendar years 1992 and 1993 and focuses on four major areas: (1) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes from the underground drifts; (2) observations of weeps in the Air Intake Shaft (AIS); (3) further characterization of brine geochemistry; and (4) additional characterization of the hydrologic conditions in the fractured zone beneath the excavations.

Deal, D.E.; Abitz, R.J. [I. T. Corp., Carlsbad, NM (United States); Belski, D.S. [USDOE Albuquerque Operations Office, Carlsbad, NM (United States). Waste Isolation Pilot Plant Project Office

1995-04-01T23:59:59.000Z

110

Marketing water  

E-Print Network [OSTI]

management, water conservation programs Story by Kathy Wythe tx H2O | pg. 17 public information programs and materials that increase awareness about regional water issues. The company recently opened the TecH2O, a water resource learning center...tx H2O | pg. 16 W ith rapid population growth and the memory of the worst drought in 50 years, cities and groups are promoting programs that educate their constituents about water quality, water conservation, and landscape management. Many...

Wythe, Kathy

2008-01-01T23:59:59.000Z

111

Membrane Desalination of Agricultural Drainage Water: Water Recovery Enhancement and Brine Minimization  

E-Print Network [OSTI]

electrode (Cole Parmer Instrument Company, Vernon Hill, IL)cartridge (Cole-Parmer Instrument Company, Vernon Hills,cartridge (Cole-Parmer Instrument Company, Vernon Hills, IL)

Cohen, Yoram

2008-01-01T23:59:59.000Z

112

Volatile constituents in a wood pyrolysis oil  

E-Print Network [OSTI]

Science VOLATILE CONSTITUTENTS IN A WOOD PYROLYSIS OIL A Thesis SHIH-CHIEN LIN Appro d as to style and content by: (Chairman of Committee) Head of epa tmen (Member Member Nay 1978 442936 ABSTRACT Volatile Constituents in a Wood Pyrolysis Oil.../120 Supelcoport. Other trace constituents of volatile acid were also 'dentifi="' by trap- ping the substances from the C. C. column into i: n;- 0-sh ped capillary tube and subjecting to mass spectrometry. The corrosivity of pyrolysis oil and it, volati'e acids...

Lin, Shih-Chien

1978-01-01T23:59:59.000Z

113

Sorption of cesium and strontium from concentrated brines by backfill barrier materials  

SciTech Connect (OSTI)

The sorption of radionuclides from potentially intruding groundwater at a nuclear waste repository is a major chemical function of backfill barriers. In this study, various materials (including clays, zeolites and an inorganic ion exchanger) were screened for the sorption of the fission products cesium and strontium in concentrated brines. Representative brines A and B for the Waste Isolation Pilot Plant (WIPP), a proposed radioactive waste repository and test facility in bedded salt were used. Sorption properties were quantified using empirical distribution coefficients, k/sub d/. Of the materials examined, sodium titanate had the highest k/sub d/ for the sorption of Sr(II) in both brine A (k/sub d/ = 125 ml/g) and brine B(k/sub d/ = 500 to 600 ml/g). A mordenite-type zeolite was the most effective getter for Cs(I) in brine A (k/sub d = 27 ml/g), while illite yielded the highest k/sub d/ for Cs(I) in brine B (k/sub d/ = 115 ml/g). The relative merit of these k/sub d/ values is evaluated in terms of calculated estimates of breakthrough times for a backfill barrier containing the getter. Results show that a backfill mixture containing these getters is potentially an effective barrier to the migration of Sr(II) and Cs(I), although further study (especially for the sorption of cesium from brine A) is recommended. Initial mechanistic studies revealed competing ion effects which would support an ion exchange mechanism. K/sub d/'s were constant over a Sr(II) concentration range of 10/sup -11/ to 10/sup -5/ M and a Cs(I) concentration range of 10/sup -8/ to 10/sup -5/ M, supporting the choice of a linear sorption isotherm as a model for the results. Constant batch composition was shown to be attained within one week.

Winslow, C D

1981-03-01T23:59:59.000Z

114

The depth of the oil/brine interface and crude oil leaks in SPR caverns  

SciTech Connect (OSTI)

Monitoring wellhead pressure evolution is the best method of detecting crude oil leaks in SPR caverns while oil/brine interface depth measurements provide additional insight. However, to fully utilize the information provided by these interface depth measurements, a thorough understanding of how the interface movement corresponds to cavern phenomena, such as salt creep, crude oil leakage, and temperature equilibration, as well as to wellhead pressure, is required. The time evolution of the oil/brine interface depth is a function of several opposing factors. Cavern closure due to salt creep and crude oil leakage, if present, move the interface upward. Brine removal and temperature equilibration of the oil/brine system move the interface downward. Therefore, the relative magnitudes of these factors determine the net direction of interface movement. Using a mass balance on the cavern fluids, coupled with a simplified salt creep model for closure in SPR caverns, the movement of the oil/brine interface has been predicted for varying cavern configurations, including both right-cylindrical and carrot-shaped caverns. Three different cavern depths and operating pressures have been investigated. In addition, the caverns were investigated at four different points in time, allowing for varying extents of temperature equilibration. Time dependent interface depth changes of a few inches to a few feet were found to be characteristic of the range of cases studied. 5 refs, 19 figs., 1 tab.

Heffelfinger, G.S.

1991-06-01T23:59:59.000Z

115

Assessment of Brine Management for Geologic Carbon Sequestration  

E-Print Network [OSTI]

for  Geologic  Carbon  Sequestration. ”   International  of  Energy.  “Carbon  Sequestration  Atlas  of  the  Water  Extracted  from  Carbon  Sequestration  Projects."  

Breunig, Hanna M.

2014-01-01T23:59:59.000Z

116

Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau  

SciTech Connect (OSTI)

Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

2013-04-01T23:59:59.000Z

117

Modeling gas and brine migration for assessing compliance of the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

At the request of the WIPP Project Integration Office (WPIO) of the DOE, the WIPP Performance Assessment (PA) Department of Sandia National Laboratories (SNL) has completed preliminary uncertainty and sensitivity analyses of gas and brine migration away from the undisturbed repository. This paper contains descriptions of the numerical model and simulations, including model geometries and parameter values, and a summary of major conclusions from sensitivity analyses. Because significant transport of contaminants can only occur in a fluid (gas or brine) medium, two-phase flow modeling can provide an estimate of the distance to which contaminants can migrate. Migration of gas or brine beyond the RCRA ``disposal-unit boundary`` or the Standard`s accessible environment constitutes a potential, but not certain, violation and may require additional evaluations of contaminant concentrations.

Vaughn, P. [Applied Physics, Inc., Albuquerque, NM (United States); Butcher, B. [Sandia National Labs., Albuquerque, NM (United States); Helton, J. [Arizona State Univ., Tempe, AZ (United States); Swift, P. [Tech. Reps., Inc., Albuquerque, NM (United States)

1993-10-01T23:59:59.000Z

118

Drinking Water Problems: Nitrates  

E-Print Network [OSTI]

. 7). Nitrate ions are drawn through the membrane pores with elec- trical currents. The nitrate is pulled from the water into a brine waste stream. Ni trate-contaminated water Treated water Nitrate Chloride or hydroxide Exchange resin Figure 6. Ion... and Extension Agricultural Engineer, Texas Cooperative Extension, The Texas A&M University System B-6184 3-08 ' the safe levels of chemicals for U.S. drinking water. The EPA conducts research to determine the level of a contaminant in drinking water...

Dozier, Monty; Melton, Rebecca; Hare, Michael; Hopkins, Janie; Lesikar, Bruce J.

2008-03-28T23:59:59.000Z

119

Technology transfer report: feasibility study for the use of geothermal brine in the Ashdod area, Israel  

SciTech Connect (OSTI)

The hydrothermal potential of the Ashdod area, Israel, was evaluated to determine its suitability as the low grade energy source required to operate the Ashdod desalination plant. An estimated 1250 cubic meters per hour of 120/sup 0/C brine would be adequate to supply the hot water necessary for operating the desalination plant. Considerable interest in oil exploration in the Ashdod area resulted in the drilling of six wells into the Jurassic formations by Oil Exploration (Investments) Ltd. (OEL) in 1976-1980. A small amount of oil was found in two wells, Ashdod 2 and 5. The remaining wells were abandoned as ''dry holes''. Evaluation of the drill cuttings, cores, and the electric logs defined two lithologic units of potential interest for hydrothermal exploitation, the Zohar and Shderot Dolomites. Investigation of the hydrothermal potential of the Jurassic formations underlying the Ashdod area has revealed that the aquifer temperatures range between 85 and 92/sup 0/C. The hydrologic parameters are not well defined; however the matrix permeability of the dolomites and limestones is probably between 1 and 10 md. This is insufficient permeability for a large scale pumping operation such as the one required to operate the desalination plant. Therefore, successful utilization of the resource requires the presence of significant fractures and/or connected vugs in the formation. The very low well productivity and formation plugging may indicate that permeability of the fracture zones may easily be impaired, suggesting that the fracture zones are not suitable production intervals. Until a test is conducted on a properly completed well, it is not possible to evaluate the deliverability of wells tapping these aquifers. 14 refs., 8 figs.

Benson, S.M.

1984-08-01T23:59:59.000Z

120

Baryon Spectroscopy and the Constituent Quark Model  

SciTech Connect (OSTI)

We explore further the idea that the lattice QCD data for hadron properties in the region m[^2][_pi] > 0.2GeV^2 can be described by the constituent quark model. This leads to a natural explanation of the fact that nucleon excited states are generally stable for pion masses greater than their physical excitation energies. Finally, we apply these same ideas to the problem of how pentaquarks might behave in lattice QCD, with interesting conclusions.

A.W. Thomas; R.D. Young

2005-07-26T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Hybrid States from Constituent Glue Model  

E-Print Network [OSTI]

The hybrid meson is one of the most interesting new hadron specie beyond the naive quark model. It acquire a great attention both from the theoretical and experimental efforts. Many good candidates have been claimed to be observed, but there is no absolute confirmation about existence of hybrid mesons. In the present work we propose new calculations of the masses and decay widths of the hybrid mesons in the context of constituent gluon model.

F. Iddir; L. Semlala

2007-10-29T23:59:59.000Z

122

Repassivation of 13% Cr steel dependent on brine pH  

SciTech Connect (OSTI)

A joint laboratory project, involving an oil production and oil well service company, investigated repassivation of martensitic 13% Cr steel. The rate at which this alloy is repassivated after losing its protective passive oxide layer to hydrochloric acid (HCI) depended on the pH of the spent acid returns. Test samples of 13% Cr cut from oilfield tubing were subjected to a fluid sequence of (1) initial brine, (2) HCI, (3) spent acid, and (4) final brine. In 9 days, the samples regained their passive oxide layers. When spent acid was taken out of the fluid sequence, the samples regained passive oxide layers in 3 days.

Skogsberg, J.W.; Walker, M.L.

2000-02-01T23:59:59.000Z

123

Brine transport studies in the bedded salt of the Waste Isolation Pilot Plant (WIPP)  

SciTech Connect (OSTI)

Brine flow has been measured to unheated boreholes for periods of a few days and to heated holes for two years in the WIPP facility. It is suggested that Darcy flow may dominate the observed influx of brine. Exact solutions to a linearized model for one-dimensional, radial flow are evaluated for conditions approximating the field experiments. Flow rates of the correct order of magnitude are calculated for permeabilities in the range 10/sup -21/ to 10/sup -20/ m/sup 2/ (1 to 10 nanodarcy) for both the unheated and heated cases. 20 refs., 3 figs., 1 tab.

McTigue, D.F.; Nowak, E.J.

1987-01-01T23:59:59.000Z

124

Estimation of interstitial water in porous medium by capillary pressure measurements at various temperatures  

E-Print Network [OSTI]

water to remove the salt. Ten pore volumes of distilled water were flushed through each core and diaphragm. They were then dried in the oven overnight and oooled. Finally they were saturated with kerosene. Run V was made at 75 F with the cores... saturated with kerosene. In this run kerosene was the wetting fluid instead of brine. A standard Du Nouy Tensiometer was used to measure surface tension of the brine solution at 75'F, 150'F and 200'F. Surface tension of kerosene, and brine solution...

Gupta, Mahesh Chander

1968-01-01T23:59:59.000Z

125

Formation of Thetis Deep metal-rich sediments in the absence of brines, Red Sea M.C. Pierret a  

E-Print Network [OSTI]

Formation of Thetis Deep metal-rich sediments in the absence of brines, Red Sea M.C. Pierret a , N October 2009 Available online 23 October 2009 Keywords: Pb­Sr­Nd isotopes REE Metal-rich sediments-rich sediments covered by brine pools. It is generally agreed that these metal-rich deposits precipitated from

Demouchy, Sylvie

126

Brine flow up a borehole caused by pressure perturbation from CO2 storage: Static and dynamic evaluations  

SciTech Connect (OSTI)

Industrial-scale storage of CO{sub 2} in saline sedimentary basins will cause zones of elevated pressure, larger than the CO{sub 2} plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards along these conduits and mix with groundwater resources. This paper discusses the potential for such brine leakage to occur in temperature- and salinity-stratified systems. Using static mass-balance calculations as well as dynamic well flow simulations, we evaluate the minimum reservoir pressure that would generate continuous migration of brine up a leaking wellbore into a freshwater aquifer. Since the brine invading the well is denser than the initial fluid in the wellbore, continuous flow only occurs if the pressure perturbation in the reservoir is large enough to overcome the increased fluid column weight after full invasion of brine into the well. If the threshold pressure is exceeded, brine flow rates are dependent on various hydraulic (and other) properties, in particular the effective permeability of the wellbore and the magnitude of pressure increase. If brine flow occurs outside of the well casing, e.g., in a permeable fracture zone between the well cement and the formation, the fluid/solute transfer between the migrating fluid and the surrounding rock units can strongly retard brine flow. At the same time, the threshold pressure for continuous flow to occur decreases compared to a case with no fluid/solute transfer.

Birkholzer, J.T.; Nicot, J.-P.; Oldenburg, C.M.; Zhou, Q.; Kraemer, S.; Bandilla, K.W.

2011-05-01T23:59:59.000Z

127

Validation of classical density-dependent solute transport theory for stable, high-concentration-gradient brine displacements in  

E-Print Network [OSTI]

-concentration-gradient brine displacements in coarse and medium sands S.J. Watson a,1 , D.A. Barry a,1 , R.J. Schotting b,*, S.M. Hassanizadeh b a School of Civil and Environmental Engineering, Contaminated Land Assessment and Remediation by a brine solution, under either constant head or constant volume flux conditions. The experimental data

Hassanizadeh, S. Majid

128

Diagnosis of "fizz-gas" and gas reservoirs in deep-water environment De-hua Han, X RPL, Houston Unversity  

E-Print Network [OSTI]

pressure (shallow depth gas modulus is much less than 0.1 GPa. Even few percent volume fraction are a result of complicated geological processes which form a reservoir. Introduction "Fizz-water" or "Fizz-gasMixture of brine (50000ppm) & gas (0.78) 0 500 1000 1500 2000 2500 3000 3500 0 20 40 60 80 10 Brine Volume

129

Brine release based on structural calculations of damage around an excavation at the Waste Isolation Pilot Plant (WIPP)  

SciTech Connect (OSTI)

In a large in situ experimntal circular room, brine inflow was measured over 5 years. After correcting for evaporation losses into mine ventilation air, the measurements gave data for a period of nearly 3 years. Predicted brine accumulation based on a mechanical ``snow plow`` model of the volume swept by creep-induced damage as calculated with the Multimechanism Deformation Coupled Fracture model was found to agree with experiment. Calculation suggests the damage zone at 5 years effectively exends only some 0.7 m into the salt around the room. Also, because the mecahnical model of brine release gives an adequate explanation of the measured data, the hydrological process of brine flow appears to be rapid compared to the mechanical process of brine release.

Munson, D.E.; Jensen, A.L.; Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States); DeVries, K.L. [RE/SPEC, Inc., Rapid City, SD (United States)

1996-02-01T23:59:59.000Z

130

Ambient methods and apparatus for rapid laser trace constituent analysis  

DOE Patents [OSTI]

A method and apparatus are disclosed for measuring trace amounts of constituents in samples by using laser induced breakdown spectroscopy and laser induced fluorescence under ambient conditions. The laser induced fluorescence is performed at a selected wavelength corresponding to an absorption state of a selected trace constituent. The intensity value of the emission decay signal which is generated by the trace constituent is compared to calibrated emission intensity decay values to determine the amount of trace constituent present.

Snyder, Stuart C. (Idaho Falls, ID); Partin, Judy K. (Idaho Falls, ID); Grandy, Jon D. (Idaho Falls, ID); Jeffery, Charles L. (Blackfoot, ID)

2002-01-01T23:59:59.000Z

131

Instantons and Constituent Monopoles, nine years later Pierre van Baal  

E-Print Network [OSTI]

-called holon- omy) is non-trivial. They reveal more clearly the monopole constituent nature of these calorons

van Baal, Pierre

132

Nonlinear Thermal Transport and Brine Convection in First Year Sea Ice  

E-Print Network [OSTI]

Nonlinear Thermal Transport and Brine Convection in First Year Sea Ice M.J. McGuinness \\Lambda , H a programme recently set up to directly measure the thermal conductivity of young sea ice. An array of thermistors frozen into first­year Antarctic sea ice provides temperature against depth data, which is fitted

133

NUMERICAL INVESTIGATION OF TEMPERATURE EFFECTS DURING THE INJECTION OF CARBON DIOXIDE INTO BRINE  

E-Print Network [OSTI]

NUMERICAL INVESTIGATION OF TEMPERATURE EFFECTS DURING THE INJECTION OF CARBON DIOXIDE INTO BRINE for the simulation of carbon dioxide injection into geological formations is currently an intensive field of research for the balance of thermal energy, we can investigate numerically the effects of temperature variations during

Cirpka, Olaf Arie

134

West Hackberry Strategic Petroleum Reserve site brine disposal monitoring, Year I report. Volume V. Supporting data for estuarine hydrology, discharge plume analysis, chemical oceanography, biological oceanography, and data management. Final report  

SciTech Connect (OSTI)

This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which located in southwestern Louisiana, and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Volume V contains appendices for the following: supporting data for estuarine hydrology and hydrography; supporting data analysis of discharge plume; supporting data for water and sediment chemistry; CTD/DO and pH profiles during biological monitoring; supporting data for nekton; and supporting data for data management.

DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J. (eds.)

1983-02-01T23:59:59.000Z

135

Distribution, formation, and seasonal variability of Okhotsk Sea Mode Water  

E-Print Network [OSTI]

in the deep Ohkotsk Sea of dense shelf water (DSW) produced in the Okhotsk Sea polynyas. Isopycnal analysis to depths greater than 200 m, in the southern Kuril Basin also produces freezing water with density greater of ventilation at 26.7­27.0 sq is dense shelf water (DSW) produced by brine rejection in coastal polynyas during

Talley, Lynne D.

136

Evaluations of Radionuclides of Uranium, Thorium, and Radium Associated with Produced Fluids, Precipitates, and Sludges from Oil, Gas, and Oilfield Brine Injection Wells in Mississippi  

SciTech Connect (OSTI)

There is an unsurpassed lack of scientific data with respect to the concentrations and isotopic compositions of uranium, thorium, and radium in the produced formation fluids (brine), precipitates, and sludges generated with the operation of oil and gas wells in Mississippi. These radioactive elements when contained in the formation fluids have been given the term NORM, which is an acronym for naturally occurring radioactive materials. When they are technologically enhanced during oil and gas production activities resulting in the formation of scale (precipitates) and sludges they are termed TENORM (technologically enhanced naturally occurring radioactive materials). As used in this document, NORM and TENORM will be considered equivalent terms and the occurrence of NORM in the oilfield will be considered the result of production operations. As a result of the lack of data no scientifically sound theses may be developed concerning the presence of these radionuclides in the fluid brine, precipitate (scale), or sludge phases. Over the period of just one year, 1997 for example, Mississippi produced over 39,372,963,584 liters (10,402,368,186 gallons or 247,675,433 barrels) of formation water associated with hydrocarbon production from 41 counties across the state.

Ericksen, R.L.

1999-10-28T23:59:59.000Z

137

Laboratory studies of imbibition flooding using carbonated brine  

E-Print Network [OSTI]

and pressures was a major part of the phase II studies. A high pressure core holder was developed and set inside a temperature regulated in-house constructed oven for this purpose. The core face flushing method was developed for conducting imbibition... and the field for improving oil recovery. The most common techniques used to increase oil recovery include water injection, steam injection, in-situ combustion, carbon dioxide (CO&) injection, chemical flooding and caustic injection. Currently, however, due...

Sharif, Qamar Javaid

1991-01-01T23:59:59.000Z

138

The effect of stratigraphic dip on brine inflow and gas migration at the Waste Isolation Pilot Plant  

SciTech Connect (OSTI)

The natural dip of the Salado Formation at the Waste Isolation Pilot Plant (WIPP), although regionally only about 111, has the potential to affect brine inflow and gas-migration distances due to buoyancy forces. Current models, including those in WIPP Performance Assessment calculations, assume a perfectly horizontal repository and stratigraphy. With the addition of buoyancy forces due to the dip, brine and gas flow patterns can be affected. Brine inflow may increase due to countercurrent flow, and gas may preferentially migrate up dip. This scoping study has used analytical and numerical modeling to evaluate the impact of the dip on brine inflow and gas-migration distances at the WIPP in one, two, and three dimensions. Sensitivities to interbed permeabilities, two-phase curves, gas-generation rates, and interbed fracturing were studied.

Webb, S.W. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States); Larson, K.W. [INTERA, Inc., Albuquerque, NM (United States)] [INTERA, Inc., Albuquerque, NM (United States)

1996-02-01T23:59:59.000Z

139

Method and apparatus for tritiated water separation  

DOE Patents [OSTI]

The present invention is a membrane method and apparatus for separating isotopic water constituents from light water. The method involves providing a supported membrane of an aromatic polyphosphazene and pressurizing the water on one side of the membrane thereby forcing the light water through the supported membrane while isotopic water constituents are retained or vice versa. The apparatus of the present invention includes an aromatic polyphosphazene placed on a porous support and means for pressurizing water through the membrane while certain isotopic water constituents are retained. 1 fig.

Nelson, D.A.; Duncan, J.B.; Jensen, G.A.

1995-09-19T23:59:59.000Z

140

Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration  

SciTech Connect (OSTI)

To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

Goddard, William

2012-11-30T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Sulfate Removal from Reject Brined in Inland Desalination with Zero Liquid Discharge  

E-Print Network [OSTI]

SULFATE REMOVAL FROM REJECT BRINED IN INLAND DESALINATION WITH ZERO LIQUID DISCHARGE A Thesis by DEMA ALMASRI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... and help. I am thankful for my colleagues for their inspiration and assistance throughout the years in Texas A&M at Qatar. I am also grateful to my exceptional friends that were always there during my ups and downs. I am thankful for my irreplaceable...

Almasri, Dema A

2013-07-03T23:59:59.000Z

142

Salt Brine Blending to Optimize Deicing and Anti-icing Performance and Cost  

E-Print Network [OSTI]

Chloride (MgCl2) w/additives ·Envirotech Serv., Scotwood Ind., NA Salt ·Calcium Chloride (CaCl2) ·Tiger 135% 90% 115% Thawrox Gold Treated MgCl2 150% 120% 115% Ice Slicer CaCl2 130% 95% 70% Ice Bite @ 3 gal to Salt Brine Material Base @ 12 F @20 F @ 28 F Calcium Chloride CaCl2 160% 185% 135% RGP-8 CaCl2 170% 80

Minnesota, University of

143

Montana Water Resources Research Center Annual Technical Report  

E-Print Network [OSTI]

drinking water supplies, a Prairie County sugar beet grower contemplating the possible impacts of coal-bed, drying streams and falling reservoir levels were the norm throughout Montana in FY 2003. But drought methane brines on soil and water, or a Madison County fishing guide coping with the effects of whirling

144

Minimum Ultraviolet Light Dose Determination and Characterization of Stress Responses that Affect Dose for Listeria monocytogenes Suspended in Distilled Water, Fresh Brine, and Spent Brine.  

E-Print Network [OSTI]

??Foodborne illnesses caused by Listeria monocytogenes have long been associated with ready-to-eat (RTE) meats contaminated after the primary thermal process has been applied. It is… (more)

McKinney, Julie

2008-01-01T23:59:59.000Z

145

Field Validation of Toxicity Tests to Evaluate the Potential for Beneficial Use of Produced Water  

SciTech Connect (OSTI)

This study investigated potential biological effects of produced water contamination derived from occasional surface overflow and possible subsurface intrusion at an oil production site along the shore of Skiatook Lake, Oklahoma. We monitored basic chemistry and acute toxicity to a suite of standard aquatic test species (fathead minnow-Pimephales promelas, Daphnia pulex, Daphnia magna, and Ceriodaphnia dubia) in produced water and in samples taken from shallow groundwater wells on the site. Toxicity identification evaluations and ion toxicity modeling were used to identify toxic constituents in the samples. Lake sediment at the oil production site and at a reference site were also analyzed for brine intrusion chemically and by testing sediment toxicity using the benthic invertebrates, Chironomus dilutus, and Hyallela azteca. Sediment quality was also assessed with in situ survival and growth studies with H. azteca and the Asian clam, Corbicula fluminea, and by benthic macroinvertebrate community sampling. The produced water was acutely toxic to the aquatic test organisms at concentrations ranging from 1% to 10% of the whole produced water sample. Toxicity identification evaluation and ion toxicity modeling indicated major ion salts and hydrocarbons were the primary mixture toxicants. The standardized test species used in the laboratory bioassays exhibited differences in sensitivity to these two general classes of contaminants, which underscores the importance of using multiple species when evaluating produced water toxicity. Toxicity of groundwater was greater in samples from wells near a produced water injection well and an evaporation pond. Principle component analyses (PCA) of chemical data derived from the groundwater wells indicated dilution by lake water and possible biogeochemical reactions as factors that ameliorated groundwater toxicity. Elevated concentrations of major ions were found in pore water from lake sediments, but toxicity from these ions was limited to sediment depths of 10 cm or greater, which is outside of the primary zone of biological activity. Further, exposure to site sediments did not have any effects on test organisms, and macroinvertebrate communities did not indicate impairment at the oil production site as compared to a reference site. In situ experiments with H. azteca and C. fluminea, indicated a sublethal site effect (on growth of both species), but these could not be definitively linked with produced water infiltration. Severe weather conditions (drought followed by flooding) negatively influenced the intensity of lake sampling aimed at delineating produced water infiltration. Due to the lack of clear evidence of produced water infiltration into the sub-littoral zone of the lake, it was not possible to assess whether the laboratory bioassays of produced water effectively indicate risk in the receiving system. However, the acutely toxic nature of the produced water and general lack of biological effects in the lake at the oil production site suggest minimal to no produced water infiltration into surficial lake sediments and the near-shore water column. This study was able to demonstrate the utility of ion toxicity modeling to support data from toxicity identification evaluations aimed at identifying key toxic constituents in produced water. This information could be used to prioritize options for treating produced water in order to reduce toxic constituents and enhance options for reuse. The study also demonstrated how geographic information systems, toxicity modeling, and toxicity assessment could be used to facilitate future site assessments.

Joseph Bidwell; Jonathan Fisher; Naomi Cooper

2008-03-31T23:59:59.000Z

146

Advanced biochemical processes for geothermal brines FY 1998 annual operating plan  

SciTech Connect (OSTI)

As part of the overall Geothermal Energy Research which is aimed at the development of economical geothermal resources production systems, the aim of the Advanced Biochemical Processes for Geothermal Brines (ABPGB) effort is the development of economic and environmentally acceptable methods for disposal of geothermal wastes and conversion of by-products to useful forms. Methods are being developed for dissolution, separation and immobilization of geothermal wastes suitable for disposal, usable in inert construction materials, suitable for reinjection into the reservoir formation, or used for recovery of valuable metals.

NONE

1997-10-01T23:59:59.000Z

147

Innovative MIOR Process Utilizing Indigenous Reservoir Constituents  

SciTech Connect (OSTI)

This research program is directed at improving the knowledge of reservoir ecology and developing practical microbial solutions for improving oil production. The goal is to identify indigenous microbial populations which can produce beneficial metabolic products and develop a methodology to stimulate those select microbes with nutrient amendments to increase oil recovery. This microbial technology has the capability of producing multiple oil-releasing agents. Experimental laboratory work is underway. Microbial cultures have been isolated from produced water samples. Comparative laboratory studies demonstrating in situ production of microbial products as oil recovery agents were conducted in sand packs with natural field waters with cultures and conditions representative of oil reservoirs. Field pilot studies are underway.

D. O. Hitzman; A. K. Stepp; D. M. Dennis; L. R. Graumann

2003-03-31T23:59:59.000Z

148

Fluid sampling and chemical modeling of geopressured brines containing methane. Final report, March 1980-February 1981  

SciTech Connect (OSTI)

The development of a flowthrough sampler capable of obtaining fluid samples from geopressured wells at temperatures up to 400/sup 0/F and pressures up to 20,000 psi is described. The sampler has been designed, fabricated from MP35N alloy, laboratory tested, and used to obtain fluid samples from a geothermal well at The Geysers, California. However, it has not yet been used in a geopressured well. The design features, test results, and operation of this device are described. Alternative sampler designs are also discussed. Another activity was to review the chemistry and geochemistry of geopressured brines and reservoirs, and to evaluate the utility of available computer codes for modeling the chemistry of geopressured brines. The thermodynamic data bases for such codes are usually the limiting factor in their application to geopressured systems, but it was concluded that existing codes can be updated with reasonable effort and can usefully explain and predict the chemical characteristics of geopressured systems, given suitable input data.

Dudak, B.; Galbraith, R.; Hansen, L.; Sverjensky, D.; Weres, O.

1982-07-01T23:59:59.000Z

149

Brine migration test report: Asse Salt Mine, Federal Republic of Germany: Technical report  

SciTech Connect (OSTI)

This report presents a summary of Brine Migration Tests which were undertaken at the Asse mine of the Federal Republic of Germany (FRG) under a bilateral US/FRG agreement. This experiment simulates a nuclear waste repository at the 800-m (2624-ft) level of the Asse salt mine in the Federal Republic of Germany. This report describes the Asse salt mine, the test equipment, and the pretest properties of the salt in the mine and in the vicinity of the test area. Also included are selected test data (for the first 28 months of operation) on the following: brine migration rates, thermomechaical behavior of the salt (including room closure, stress reading, and thermal profiles), borehole gas pressures, and borehole gas analyses. In addition to field data, laboratory analyses of pretest salt properties are included in this report. The operational phase of these experiments was completed on October 4, 1985, with the commencement of cooldown and the start of posttest activities. 7 refs., 68 figs., 48 tabs.

Coyle, A.J.; Eckert, J.; Kalia, H.

1987-01-01T23:59:59.000Z

150

INNOVATIVE MIOR PROCESS UTILIZING INDIGENOUS RESERVOIR CONSTITUENTS  

SciTech Connect (OSTI)

This research program was directed at improving the knowledge of reservoir ecology and developing practical microbial solutions and technologies for improving oil production. The goal was to identify and utilize indigenous microbial populations which can produce beneficial metabolic products and develop a methodology to stimulate those select microbes with nutrient amendments to increase oil recovery. This microbial technology has the capability of producing multiple oil-releasing agents. Experimental laboratory work in model sandpack cores was conducted using microbial cultures isolated from produced water samples. Comparative laboratory studies demonstrating in situ production of microbial products as oil recovery agents were conducted in sand packs with natural field waters using cultures and conditions representative of oil reservoirs. Increased oil recovery in multiple model sandpack systems was achieved and the technology and results were verified by successful field studies. Direct application of the research results has lead to the development of a feasible, practical, successful, and cost-effective technology which increases oil recovery. This technology is now being commercialized and applied in numerous field projects to increase oil recovery. Two field applications of the developed technology reported production increases of 21% and 24% in oil recovery.

D.O. Hitzman; A.K. Stepp; D.M. Dennis; L.R. Graumann

2003-09-01T23:59:59.000Z

151

Brine and Gas Flow Patterns Between Excavated Areas and Disturbed Rock Zone in the 1996 Performance Assessment for the Waste Isolation Pilot Plant for a Single Drilling Intrusion that Penetrates Repository and Castile Brine Reservoir  

SciTech Connect (OSTI)

The Waste Isolation Pilot Plant (WIPP), which is located in southeastern New Mexico, is being developed for the geologic disposal of transuranic (TRU) waste by the U.S. Department of Energy (DOE). Waste disposal will take place in panels excavated in a bedded salt formation approximately 2000 ft (610 m) below the land surface. The BRAGFLO computer program which solves a system of nonlinear partial differential equations for two-phase flow, was used to investigate brine and gas flow patterns in the vicinity of the repository for the 1996 WIPP performance assessment (PA). The present study examines the implications of modeling assumptions used in conjunction with BRAGFLO in the 1996 WIPP PA that affect brine and gas flow patterns involving two waste regions in the repository (i.e., a single waste panel and the remaining nine waste panels), a disturbed rock zone (DRZ) that lies just above and below these two regions, and a borehole that penetrates the single waste panel and a brine pocket below this panel. The two waste regions are separated by a panel closure. The following insights were obtained from this study. First, the impediment to flow between the two waste regions provided by the panel closure model is reduced due to the permeable and areally extensive nature of the DRZ adopted in the 1996 WIPP PA, which results in the DRZ becoming an effective pathway for gas and brine movement around the panel closures and thus between the two waste regions. Brine and gas flow between the two waste regions via the DRZ causes pressures between the two to equilibrate rapidly, with the result that processes in the intruded waste panel are not isolated from the rest of the repository. Second, the connection between intruded and unintruded waste panels provided by the DRZ increases the time required for repository pressures to equilibrate with the overlying and/or underlying units subsequent to a drilling intrusion. Third, the large and areally extensive DRZ void volumes is a significant source of brine to the repository, which is consumed in the corrosion of iron and thus contributes to increased repository pressures. Fourth, the DRZ itself lowers repository pressures by providing storage for gas and access to additional gas storage in areas of the repository. Fifth, given the pathway that the DRZ provides for gas and brine to flow around the panel closures, isolation of the waste panels by the panel closures was not essential to compliance with the U.S. Environment Protection Agency's regulations in the 1996 WIPP PA.

ECONOMY,KATHLEEN M.; HELTON,JON CRAIG; VAUGHN,PALMER

1999-10-01T23:59:59.000Z

152

PII S0016-7037(01)00901-2 Effect of light and brine shrimp on skeletal 13  

E-Print Network [OSTI]

PII S0016-7037(01)00901-2 Effect of light and brine shrimp on skeletal 13 C in the Hawaiian coral, University of Pennsylvania, 240 South 33rd Street, Philadelphia, PA 19104-6316, USA (Received June 7, 2001 skeletal 13 C values decreased when solar intensity was reduced, and increased in the absence

Grottoli, Andréa G.

153

Predicting PVT data for CO2brine mixtures for black-oil simulation of CO2 geological storage  

E-Print Network [OSTI]

Predicting PVT data for CO2­brine mixtures for black-oil simulation of CO2 geological storage efficiency of the black-oil approach promote application of black-oil simulation for large-scale geological into geological formations has been considered as a potential method to mitigate climate change. Accurate

Santos, Juan

154

Energy optimization in ice hockey halls I. The system COP as a multivariable function, brine and design choices  

E-Print Network [OSTI]

This work is the first of a series of articles addressing the energy optimization in ice hockey halls. Here we outline an analytic method to predict in which design and operating conditions the COP of the entire cooling system (refrigerator and cooling tower) ${\\rm COP}_{sys}$ is maximum. ${\\rm COP}_{sys}$ is investigated as a function of several variables, like electric consumption and brine physical properties. With this method, the best configuration and brine choices for the system can therefore be determined in advance. We estimate the optimal design of an average-sized ice rink, including pipe diameter, depth and brine type (ethylene glycol and ammonia). We also single out an optimal brine density and show the impact of the electric consumption of the pump on ${\\rm COP}_{sys}$. Our theoretical predictions are validated with heat flow measurement data obtained at an ice hockey hall in Finland. They are also confronted with technical and cost-related constraints, and implemented by simulations with the pr...

Ferrantelli, Andrea; Räikkönen, Miska; Viljanen, Martti

2012-01-01T23:59:59.000Z

155

Macro-and Microscale Waterflooding Performances of Crudes which form w/o Emulsions upon Mixing with Brines  

E-Print Network [OSTI]

Macro- and Microscale Waterflooding Performances of Crudes which form w/o Emulsions upon Mixing with Brines N. Rezaei and A. Firoozabadi*,, Reservoir Engineering Research Institute, 595 Lytton Avenue, Palo ABSTRACT: We study the micro- and macroscale waterflooding performances of unusual crudes which naturally

Firoozabadi, Abbas

156

2. INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 STUDY OF WATERFLOODING PROCESS IN NATURALLY FRACTURED  

E-Print Network [OSTI]

, followed by waterflooding, were performed at reservoir conditions to investigate rock wettability. A two Berea and Spraberry cores at reservoir conditions to illustrate the actual process of waterflooding- 31 - 2. INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 STUDY OF WATERFLOODING PROCESS

Schechter, David S.

157

Methods of using adsorption media for separating or removing constituents  

DOE Patents [OSTI]

Methods of using an adsorption medium to remove at least one constituent from a feed stream. The method comprises contacting an adsorption medium with a feed stream comprising at least one constituent and removing the at least one constituent from the feed stream. The adsorption medium comprises a polyacrylonitrile (PAN) matrix and at least one metal hydroxide homogenously dispersed therein. The adsorption medium may comprise from approximately 15 wt % to approximately 90 wt % of the PAN and from approximately 10 wt % to approximately 85 wt % of the at least one metal hydroxide. The at least one metal hydroxide may be selected from the group consisting of ferric hydroxide, zirconium hydroxide, lanthanum hydroxide, cerium hydroxide, titanium hydroxide, copper hydroxide, antimony hydroxide, and molybdenum hydroxide.

Tranter, Troy J. (Idaho Falls, ID); Herbst, R. Scott (Idaho Falls, ID); Mann, Nicholas R. (Blackfoot, ID); Todd, Terry A. (Aberdeen, ID)

2011-10-25T23:59:59.000Z

158

Sustaining Industrial Energy Efficiency in Process Cooling in a Potentially Water-Short Future  

E-Print Network [OSTI]

by Energy-Intensive Plants* Source: Anonymous US petrochemical company *Includes refineries and ethylene plants ESL-IE-14-05-18 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 Estimated Water Use... Sources Strategy: Education on New(er) Technologies and Approaches • Barriers to Use of Unconventional Water Sources (sea water, brackish water or brine water) – High pipeline costs; Need to address upgrades to metallurgy as well as minimizing...

Ferland, K.

2014-01-01T23:59:59.000Z

159

A Simple Mixture Theory for ? Newtonian and Generalized Newtonian Constituents  

E-Print Network [OSTI]

] based on the following notations L(?) = gradv?(x, t) D(?) = 1 2 ( L(?) + L T (?) ) q = ?? ?=1 q? Q = 1 ?m ?? ?=1 ??Q? ? = 1 ?m ?? ?=1 ????(x, t) pi = ?pi1 = pi2 (2.39) 13 In which q is heat flux, Q is heat supply, ? and ?? are entropy densities... of the mixture and the constituents. We begin with the entropy inequality ?m D? Dt + div (q ? ) ? ? Q ? ? 0 (2.40) We have assumed that entropy due to heat flux q? is q? ? where ? is the common temperature of the constituents and the entropy due to heat supply Q?...

Powell, Michael Joseph

2012-08-31T23:59:59.000Z

160

Use of data obtained from core tests in the design and operation of spent brine injection wells in geopressured or geothermal systems  

SciTech Connect (OSTI)

The effects of formation characteristics on injection well performance are reviewed. Use of data acquired from cores taken from injection horizons to predict injectivity is described. And methods for utilizing data from bench scale testing of brine and core samples to optimize injection well design are presented. Currently available methods and equipment provide data which enable the optimum design of injection wells through analysis of cores taken from injection zones. These methods also provide a means of identifying and correcting well injection problems. Methods described in this report are: bulk density measurement; porosity measurement; pore size distribution analysis; permeability measurement; formation grain size distribution analysis; core description (lithology) and composition; amount, type and distribution of clays and shales; connate water analysis; consolidatability of friable reservoir rocks; grain and pore characterization by scanning electron microscopy; grain and pore characterization by thin section analysis; permeability damage and enhancement tests; distribution of water-borne particles in porous media; and reservoir matrix acidizing effectiveness. The precise methods of obtaining this information are described, and their use in the engineering of injection wells is illustrated by examples, where applicable. (MHR)

Jorda, R.M.

1980-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Hypercentral Constituent Quark Model with a Meson Cloud  

E-Print Network [OSTI]

The results for the elastic nucleon form factors and the electromagnetic transition amplitudes to the Delta(1232) resonance, obtained with the Hypercentral Constituent Quark Model with the inclusion of a meson cloud correction are briefly presented. The pion cloud effects are explicitly discussed.

D. Y. Chen; Y. B. Dong; M. M. Giannini; E. Santopinto

2006-11-07T23:59:59.000Z

162

Method for verification of constituents of a process stream  

DOE Patents [OSTI]

This invention is comprised of a method for validating a process stream for the presence or absence of a substance of interest such as a chemical warfare agent; that is, for verifying that a chemical warfare agent is present in an input line for feeding the agent into a reaction vessel for destruction, or, in a facility for producing commercial chemical products, that a constituent of the chemical warfare agent has not been substituted for the proper chemical compound. The method includes the steps of transmitting light through a sensor positioned in the feed line just before the chemical constituent in the input line enters the reaction vessel, measuring an optical spectrum of the chemical constituent from the light beam transmitted through it, and comparing the measured spectrum to a reference spectrum of the chemical agent and preferable also reference spectra of surrogates. A signal is given if the chemical agent is not entering a reaction vessel for destruction, or if a constituent of a chemical agent is added to a feed line in substitution of the proper chemical compound.

Baylor, L.C.; Buchanan, B.R.; O`Rourke, P.E.

1993-01-01T23:59:59.000Z

163

DRAFT FOR COMMENT ONLY NOT A SOLICITATION FOR PROPOSALS October 26, 2010 1  

E-Print Network [OSTI]

are required: for environmentally benign disposition of brines and waste streams from desalination and water reclamation projects; for low-cost methods for removal of emerging contaminants from wastewater streams of concentrated brine discharge from reverse osmosis plants limit deployment as permitting is a major constituent

Magee, Joseph W.

164

Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report  

SciTech Connect (OSTI)

Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

Alicia M. Wilson

2009-11-30T23:59:59.000Z

165

Removal of Radionuclides from Waste Water at Fukushima Daiichi Nuclear Power Plant: Desalination and Adsorption Methods - 13126  

SciTech Connect (OSTI)

Waste water containing high levels of radionuclides due to the Fukushima Daiichi Nuclear Power Plant accident, has been treated by the adsorption removal and reverse-osmosis (RO) desalination to allow water re-use for cooling the reactors. Radionuclides in the waste water are collected in the adsorbent medium and the RO concentrate (RO brine) in the water treatment system currently operated at the Fukushima Daiichi site. In this paper, we have studied the behavior of radionuclides in the presently applied RO desalination system and the removal of radionuclides in possible additional adsorption systems for the Fukushima Daiichi waste water treatment. Regarding the RO desalination system, decontamination factors (DFs) of the elements present in the waste water were obtained by lab-scale testing using an RO unit and simulated waste water with non-radioactive elements. The results of the lab-scale testing using representative elements showed that the DF for each element depended on its hydrated ionic radius: the larger the hydrated ionic radius of the element, the higher its DF is. Thus, the DF of each element in the waste water could be estimated based on its hydrated ionic radius. For the adsorption system to remove radionuclides more effectively, we studied adsorption behavior of typical elements, such as radioactive cesium and strontium, by various kinds of adsorbents using batch and column testing. We used batch testing to measure distribution coefficients (K{sub d}s) for cesium and strontium onto adsorbents under different brine concentrations that simulated waste water conditions at the Fukushima Daiichi site. For cesium adsorbents, K{sub d}s with different dependency on the brine concentration were observed based on the mechanism of cesium adsorption. As for strontium, K{sub d}s decreased as the brine concentration increased for any adsorbents which adsorbed strontium by intercalation and by ion exchange. The adsorbent titanium oxide had higher K{sub d}s and it was used for the column testing to obtain breakthrough curves under various conditions of pH and brine concentration. The breakthrough point had a dependency on pH and the brine concentration. We found that when the pH was higher or the brine concentration was lower, the longer it took to reach the breakthrough point. The inhibition of strontium adsorption by alkali earth metals would be diminished for conditions of higher pH and lower brine concentration. (authors)

Kani, Yuko; Kamosida, Mamoru; Watanabe, Daisuke [Hitachi Research Laboratory, Hitachi, Ltd., 7-2-1 Omika-cho, Hitachi, Ibaraki, 319-1221 (Japan)] [Hitachi Research Laboratory, Hitachi, Ltd., 7-2-1 Omika-cho, Hitachi, Ibaraki, 319-1221 (Japan); Asano, Takashi; Tamata, Shin [Hitachi Works, Hitachi-GE Nuclear Energy, Ltd. (Japan)] [Hitachi Works, Hitachi-GE Nuclear Energy, Ltd. (Japan)

2013-07-01T23:59:59.000Z

166

Effect of debonded interfaces on corrosion of mild steel composites in supercritical CO2-saturated brines  

SciTech Connect (OSTI)

The geologic sequestration of CO{sub 2} is a proposed method to limit greenhouse gas emissions and has been the subject of many studies in the last decade. Wellbore systems achieve isolation of the storage reservoir through a combination of steel (generally carbon steel) and Portland cement. CO{sub 2} leakage along the steel-cement interface has the potential to accelerate corrosion. We conduct experiments to assess the corrosion risk at cement-steel interface under in situ wellbore conditions. Wellbore interfaces were simulated by assemblies constructed of J55 mild steel and Portland class G (Epoxy was used in this study to separate) cement and corrosion was investigated in supercritical CO{sub 2} saturated brines, (NaCl = 1 wt%) at T = 50 C, pCO{sub 2} = 1200 psi with interface gap size = 100 {micro}m and {infinity} (open surface). The experiments were carried out in a high-pressure, 1.8 L autoclave. The corrosion kinetics were measured employing electrochemical techniques including linear polarization resistance and electrochemical impedance spectroscopy techniques. The corrosion scales were analyzed using secondary electron microscopy, back scattering electron microscopy, energy dispersive spectroscopy and x-ray diffraction. Corrosion rates decreased as time with or without interface gap. In this case corrosion rates are controlled by scale protectivity through the interface gap. Scaled steel corrosion rates were two orders of magnitude less compared with fresh steel. The corrosion scale is pseudo crystalline at the open interface. Well-crystallized scale was observed at interface gap sizes 100 {micro}m. All corrosion scales were composed of iron carbonates.

John, Han [Los Alamos National Laboratory; Carey, James W [Los Alamos National Laboratory; Zhang, Jinsuo [Los Alamos National Laboratory

2010-10-07T23:59:59.000Z

167

Computational studies of two-phase cement-CO2-brine interaction in wellbore environments  

SciTech Connect (OSTI)

Wellbore integrity is essential to ensuring long-term isolation of buoyant supercritical CO{sub 2} during geologic sequestration of CO{sub 2}. In this report, we summarize recent progress in numerical simulations of cement-brine-CO{sub 2} interactions with respect to migration of CO{sub 2} outside of casing. Using typical values for the hydrologic properties of cement, caprock (shale) and reservoir materials, we show that the capillary properties of good quality cement will prevent flow of CO{sub 2} into and through cement. Rather, CO{sub 2}, if present, is likely to be confined to the casing-cement or cement-formation interfaces. CO{sub 2} does react with the cement by diffusion from the interface into the cement, in which case it produces distinct carbonation fronts within the cement. This is consistent with observations of cement performance at the CO{sub 2}-enhanced oil recovery SACROC Unit in West Texas (Carey et al. 2007). For poor quality cement, flow through cement may occur and would produce a pattern of uniform carbonation without reaction fronts. We also consider an alternative explanation for cement carbonation reactions as due to CO{sub 2} derived from caprock. We show that carbonation reactions in cement are limited to surficial reactions when CO{sub 2} pressure is low (< 10 bars) as might be expected in many caprock environments. For the case of caprock overlying natural CO{sub 2} reservoirs for millions of years, we consider Scherer and Huet's (2009) hypothesis of diffusive steady-state between CO{sub 2} in the reservoir and in the caprock. We find that in this case, the aqueous CO{sub 2} concentration would differ little from the reservoir and would be expected to produce carbonation reaction fronts in cements that are relatively uniform as a function of depth.

Carey, James William [Los Alamos National Laboratory; Lichtner, Peter C [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

168

Impacts of Shale Gas Wastewater Disposal on Water Quality in Western Pennsylvania  

E-Print Network [OSTI]

Impacts of Shale Gas Wastewater Disposal on Water Quality in Western Pennsylvania Nathaniel R. In Pennsylvania, oil and gas wastewater is sometimes treated at brine treatment facilities and discharged to local bioaccumulation in localized areas of shale gas wastewater disposal. INTRODUCTION The safe disposal of large

Jackson, Robert B.

169

Calculation of size for bound-state constituents  

E-Print Network [OSTI]

Elements are given of a calculation that identifies the size of a proton in the Schroedinger equation for lepton-proton bound states, using the renormalization group procedure for effective particles (RGPEP) in quantum field theory, executed only up to the second order of expansion in powers of the coupling constant. Already in this crude approximation, the extraction of size of a proton from bound-state observables is found to depend on the lepton mass, so that the smaller the lepton mass the larger the proton size extracted from the same observable bound-state energy splitting. In comparison of Hydrogen and muon-proton bound-state dynamics, the crude calculation suggests that the difference between extracted proton sizes in these two cases can be a few percent. Such values would match the order of magnitude of currently discussed proton-size differences in leptonic atoms. Calculations using the RGPEP of higher order than second are required for a precise interpretation of the energy splittings in terms of the proton size in the Schroedinger equation. Such calculations should resolve the conceptual discrepancy between two conditions: that the renormalization group scale required for high accuracy calculations based on the Schroedinger equation is much smaller than the proton mass (on the order of a root of the product of reduced and average masses of constituents) and that the energy splittings due to the physical proton size can be interpreted ignoring corrections due to the effective nature of constituents in the Schr\\"odinger equation.

Stanislaw D. Glazek

2014-06-01T23:59:59.000Z

170

Summary Results for Brine Migration Modeling Performed by LANL, LBNL, and SNL for the Used Fuel Disposition Program  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of Energy Strain Rate4 Recovery Act/BuySummary Max TotalResults for Brine

171

Remediation of Risks in Natural Gas Storage Produced Waters: The Potential Use of Constructed Wetland Treatment Systems.  

E-Print Network [OSTI]

??Natural gas storage produced waters (NGSPWs) are generated in large volumes, vary in composition, and often contain constituents in concentrations and forms that are toxic… (more)

Johnson, Brenda

2006-01-01T23:59:59.000Z

172

Modifications of Carbonate Fracture Hydrodynamic Properties by CO{sub 2}-Acidified Brine Flow  

SciTech Connect (OSTI)

Acidic reactive flow in fractures is relevant in subsurface activities such as CO{sub 2} geological storage and hydraulic fracturing. Understanding reaction-induced changes in fracture hydrodynamic properties is essential for predicting subsurface flows such as leakage, injectability, and fluid production. In this study, x-ray computed tomography scans of a fractured carbonate caprock were used to create three dimensional reconstructions of the fracture before and after reaction with CO{sub 2}-acidified brine (Ellis et al., 2011, Greenhouse Gases: Sci. Technol., 1:248-260). As expected, mechanical apertures were found to increase substantially, doubling and even tripling in some places. However, the surface geometry evolved in complex ways including ‘comb-tooth’ structures created from preferential dissolution of calcite in transverse sedimentary bands, and the creation of degraded zones, i.e. porous calcite-depleted areas on reacted fracture surfaces. These geometric alterations resulted in increased fracture roughness, as measured by surface Z{sub 2} parameters and fractal dimensions D{sub f}. Computational fluid dynamics (CFD) simulations were conducted to quantify the changes in hydraulic aperture, fracture transmissivity and permeability. The results show that the effective hydraulic apertures are smaller than the mechanical apertures, and the changes in hydraulic apertures are nonlinear. Overestimation of flow rate by a factor of two or more would be introduced if fracture hydrodynamic properties were based on mechanical apertures, or if hydraulic aperture is assumed to change proportionally with mechanical aperture. The differences can be attributed, in part, to the increase in roughness after reaction, and is likely affected by contiguous transverse sedimentary features. Hydraulic apertures estimated by the 1D statistical model and 2D local cubic law (LCL) model are consistently larger than those calculated from the CFD simulations. In addition, a novel ternary segmentation method was devised to handle the degraded zones, allowing for a bounding analysis of the effects on hydraulic properties. We found that the degraded zones account for less than 15% of the fracture volume, but cover 70% to 80% of the fracture surface. When the degraded zones are treated as part of the fracture, the fracture transmissivities are two to four times larger because the fracture surfaces after reaction are not as rough as they would be if one considers the degraded zone as part of the rock. Therefore, while degraded zones created during geochemical reactions may not significantly increase mechanical aperture, this type of feature cannot be ignored and should be treated with prudence when predicting fracture hydrodynamic properties.

Deng, Hang; Ellis, Brian R.; Peters, Catherine A.; Fitts, Jeffrey P.; Crandall, Dustin; Bromhal, Grant S.

2013-08-01T23:59:59.000Z

173

Direct releases to the surface and associated complementary cumulative distribution functions in the 1996 performance assessments for the Waste Isolation Pilot Plant: Direct brine release  

SciTech Connect (OSTI)

The following topics related to the treatment of direct brine releases to the surface environment in the 1996 performance assessment for the Waste Isolation Pilot Plant (WIPP) are presented (1) mathematical description of models, (2) uncertainty and sensitivity analysis results arising from subjective (i.e., epistemic) uncertainty for individual releases, (3) construction of complementary cumulative distribution functions (CCDFs) arising from stochastic (i.e., aleatory) uncertainty, and (4) uncertainty and sensitivity analysis results for CCDFs. The presented analyses indicate that direct brine releases do not constitute a serious threat to the effectiveness of the WIPP as a disposal facility for transuranic waste. Even when the effects of uncertain analysis inputs are taken into account, the CCDFs for direct brine releases fall substantially to the left of the boundary line specified in the US Environmental Protection Agency's standard for the geologic disposal of radioactive waste (4O CFR 191.40 CFR 194).

STOELZEL,D.M.; O'BRIEN,D.G.; GARNER,J.W.; HELTON,JON CRAIG; JOHNSON,J.D.; SCOTT,L.N.

2000-05-19T23:59:59.000Z

174

Environmental assessment of the brine pipeline replacement for the Strategic Petroleum Reserve Bryan Mound Facility in Brazoria County, Texas  

SciTech Connect (OSTI)

The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0804, for the proposed replacement of a deteriorated brine disposal pipeline from the Strategic Petroleum Reserve (SPR) Bryan Mound storage facility in Brazoria County, Texas, into the Gulf of Mexico. In addition, the ocean discharge outfall would be moved shoreward by locating the brine diffuser at the end of the pipeline 3.5 miles offshore at a minimum depth of 30 feet. The action would occur in a floodplain and wetlands; therefore, a floodplain/wetlands assessment has been prepared in conjunction with this EA. Based on the analyses in the EA, DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969 (42 USC. 4321, et seg.). Therefore, the preparation of an Environmental Impact Statement (EIS) is not required, and the Department is issuing this Finding of No Significant Impact (FONSI). This FONSI also includes a Floodplain Statement of Findings in accordance with 10 CFR Part 1022.

Not Available

1993-09-01T23:59:59.000Z

175

Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water  

SciTech Connect (OSTI)

Isothermal vapor-liquid equilibria were measured for the ternary system methanol + ethanol + water and its constituent binary systems of methanol + water and ethanol + water at 323.15, 328.15, and 333.15 K. The apparatus that was used made it possible to control the measured temperature and total pressure by computer. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

Kurihara, Kiyofumi; Takeda, Kouichi; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Minoura, Tsuyoshi [Mitui Engineering and Shipbuilding Co., Ltd., Tokyo (Japan)

1995-05-01T23:59:59.000Z

176

EVALUATIONS OF RADIONUCLIDES OF URANIUM, THORIUM, AND RADIUM ASSOCIATED WITH PRODUCED FLUIDS, PRECIPITATES, AND SLUDGES FROM OIL, GAS, AND OILFIELD BRINE INJECTION WELLS IN MISSISSIPPI  

SciTech Connect (OSTI)

Naturally occurring radioactive materials (NORM) are known to be produced as a byproduct of hydrocarbon production in Mississippi. The presence of NORM has resulted in financial losses to the industry and continues to be a liability as the NORM-enriched scales and scale encrusted equipment is typically stored rather than disposed of. Although the NORM problem is well known, there is little publically available data characterizing the hazard. This investigation has produced base line data to fill this informational gap. A total of 329 NORM-related samples were collected with 275 of these samples consisting of brine samples. The samples were derived from 37 oil and gas reservoirs from all major producing areas of the state. The analyses of these data indicate that two isotopes of radium ({sup 226}Ra and {sup 228}Ra) are the ultimate source of the radiation. The radium contained in these co-produced brines is low and so the radiation hazard posed by the brines is also low. Existing regulations dictate the manner in which these salt-enriched brines may be disposed of and proper implementation of the rules will also protect the environment from the brine radiation hazard. Geostatistical analyses of the brine components suggest relationships between the concentrations of {sup 226}Ra and {sup 228}Ra, between the Cl concentration and {sup 226}Ra content, and relationships exist between total dissolved solids, BaSO{sub 4} saturation and concentration of the Cl ion. Principal component analysis points to geological controls on brine chemistry, but the nature of the geologic controls could not be determined. The NORM-enriched barite (BaSO{sub 4}) scales are significantly more radioactive than the brines. Leaching studies suggest that the barite scales, which were thought to be nearly insoluble in the natural environment, can be acted on by soil microorganisms and the enclosed radium can become bioavailable. This result suggests that the landspreading means of scale disposal should be reviewed. This investigation also suggests 23 specific components of best practice which are designed to provide a guide to safe handling of NORM in the hydrocarbon industry. The components of best practice include both worker safety and suggestions to maintain waste isolation from the environment.

Charles Swann; John Matthews; Rick Ericksen; Joel Kuszmaul

2004-03-01T23:59:59.000Z

177

Transformations of inorganic coal constituents in combustion systems  

SciTech Connect (OSTI)

The technical objectives of this project are: (a) To (1) define the partitioning of inorganic constituents associated with raw coal particles among products (including vapors, aerosols, and residual char/ash particles) formed under conditions representative of pulverized coal flames as a function of the specific (intrinsic and extrinsic) characteristics of the raw coal and the environment in which the transformations occur; and (2) to characterize the resultant spectrum of products in detail; (b) To elucidate and quantify the fundamental processes (involving basic principles of physics, chemistry, thermodynamics) by which transformations of the inorganic constituents occur; and (c) To develop, based on the information required in a. and b. above, a tractable process model capable of predicting the significant features of the transformation process, most importantly, the distribution and nature of products. This report represents work accomplished in the tenth quarter of performance on the contract. The authors specifically highlight work accomplished: at the California Institute of Technology (CalTech) on developing and constructing a thermophoretic sampling probe, for submicron fume particle sampling; at MIT on (1) completion of the baseline ash particle size distribution measurements for seven program coals (five US and two Australian), and (2) analysis of the fragmentation model results in terms of a closed-form solution for a simplified case; at the University of Arizona, on obtaining detailed ash particle and submicron fume chemistry for four program coals; and at PSI Technology Company (PSIT) on concluding data analysis and describing mineral interaction trends observed during combustion of two program coals. Individual progress reports have been indexed separately for inclusion on the data base.

Boni, A.A.; Helble, J.J.; Srinivasachar, S. (PSI Technology Co., Andover, MA (USA)); Flagan, R.C. (California Inst. of Tech., Pasadena, CA (USA)); Huffman, G.P.; Huggins, F.E. (Kentucky Univ., Lexington, KY (USA)); Peterson, T.W.; Wendt, J.O.L. (Arizona Univ., Tucson, AZ (USA)); Sarofim, A.F. (Massachusetts Inst. of Tech., Cambridge, MA (USA))

1989-05-01T23:59:59.000Z

178

Engineered Treatment of As-laden Regeneration Brine from Ion Exchange Processes .  

E-Print Network [OSTI]

??Arsenic (As) contamination of drinking water sources has been one of the most challenging global environmental issues. In the United States, the newly revised maximum… (more)

STEINWINDER, THOMAS

2006-01-01T23:59:59.000Z

179

Assessment of Injection Well Construction and Operation for Water Injection Wells and Salt Water Disposal Wells  

E-Print Network [OSTI]

) that use this process (minus the evaporation) to provide a brine solution for oilfield applications

180

Effect of Brine on Hydrate Antiagglomeration J. Dalton York and Abbas Firoozabadi*,  

E-Print Network [OSTI]

production lines often favor formation of crystalline inclusion compounds known as gas hydrates. Water, 2008. ReVised Manuscript ReceiVed March 19, 2009 Natural gas production poses a risk of flow-line hydrate blockage from coproduced water and hydrate- forming species. Our previous studies have focused

Firoozabadi, Abbas

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Fundamental Mechanisms of Copper CMP – Passivation Kinetics of Copper in CMP Slurry Constituents  

E-Print Network [OSTI]

Tribochemical Mechanisms of Copper Chemical MechanicalE06-02 Fundamental Mechanisms of Copper CMP – PassivationKinetics of Copper in CMP Slurry Constituents Shantanu

Tripathi, Shantanu; Doyle, F M; Dornfeld, David

2009-01-01T23:59:59.000Z

182

Total Matrix Intercomparison: A Method for Determining the Geometry of Water-Mass Pathways  

E-Print Network [OSTI]

Ocean tracer distributions have long been used to decompose the deep ocean into constituent water masses, but previous inverse methods have generally been limited to just a few water masses that have been defined by a ...

Gebbie, Geoffrey

183

Recovery of constituent spectra using non-negative matrix factorization  

E-Print Network [OSTI]

, mineral exploration, vegetation mapping, hazardous material remediation, and water quality control. #12 to produce spectra across a large number of wavelengths/bands (> 30 bands). Typical wavelength ranges

Parra, Lucas C.

184

(Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only commercially active lithium mine in the United States was a brine  

E-Print Network [OSTI]

94 LITHIUM (Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only commercially active lithium mine in the United States was a brine operation in Nevada. The mine's production capacity was expanded in 2012, and a new lithium hydroxide plant opened in North

185

Potential for the localized corrosion of alloy 22 Waste Packages in Multiple-Salt Deliquescent Brines in the Yucca Mountain Repository  

SciTech Connect (OSTI)

It has been postulated that the deliquescence of multiple-salt systems in dust deposits and the consequent localized corrosion in high-temperature brines could lead to premature failure of the Alloy 22 waste packages in the Yucca Mountain repository. EPRI has developed a decision tree approach to determine if the various stages leading to waste package failure are possible and whether the safety of the repository system could be compromised as a result. Through a series of arguments, EPRI has shown that it is highly unlikely that the multiple-salt deliquescent brines will form in the first place and, even if they did, that they would not be thermodynamically stable, that the postulated brines are not corrosive and would not lead to the initiation of localized corrosion of Alloy 22, that even if localized corrosion did initiate that the propagation would stifle and cease long before penetration of the waste package outer barrier, and that even if premature waste package failures did occur from this cause that the safety of the overall system would not be compromised. EPRI concludes, therefore, that the postulated localized corrosion of the waste packages due to high-temperature deliquescent brines is neither a technical nor a safety issue of concern for the Yucca Mountain repository. (authors)

King, F. [Integrity Corrosion Consulting, Ltd., Calgary, AB (Canada); Arthur, R.; Apted, M. [Monitor Scientific LLC, Denver, CO (United States); Kessler, J.H. [Electric Power Research Institute, Charlotte, NC (United States)

2007-07-01T23:59:59.000Z

186

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry  

E-Print Network [OSTI]

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico Keywords: Methane flux Mass spectrometer Brine pool Methane oxidation Gulf of Mexico a b s t r a c t Deep heterogeneity. In particular, biogeochemical fluxes of volatiles such as methane remain largely unconstrained

Girguis, Peter R.

187

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network [OSTI]

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

188

Transformations of inorganic coal constituents in combustion systems  

SciTech Connect (OSTI)

The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles What determines their composition Whether or not particles deposit How combustion conditions, including reactor size, affect these processes remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

Helble, J.J. (ed.); Srinivasachar, S.; Wilemski, G.; Boni, A.A. (PSI Technology Co., Andover, MA (United States)); Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. (Massachusetts Inst. of Tech., Cambridge, MA (United States)); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. (Arizona Univ., Tucson, AZ (United States)); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. (Kentucky Univ., Lexingt

1992-11-01T23:59:59.000Z

189

Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report  

SciTech Connect (OSTI)

Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

Beauheim, R.L. (Sandia National Labs., Albuquerque, NM (United States)); Saulnier, G.J. Jr.; Avis, J.D. (INTERA, Inc., Austin, TX (United States))

1991-08-01T23:59:59.000Z

190

The effect of some dissolved constituents on the redox potential of water  

E-Print Network [OSTI]

4Laa&Xs?4 esSygea ~ashS?tgasa, Xaa&41&t&Iy' b&fes? e&als1- Lag ths ieaLN~ Swa a?&mt&4 aa4 ih& yg aa4 ssLXXLeali s?&4Laga?eea ebs&La&4 fecss ih& So&be?a a?tee, The ebsyeeok to ih& esssyle bobble eaa i&&b&L Tb&eeqysa Li &&a fLXX&4 &a4 yose4it&4 ic... R IAI IS D o Ial 0 Sl Sl NUMERICAL VALUES INDICATE pH 0 Zg0 300 400 SOO 800 700 Eh, mv. 50 The s44itiea of tbe ferrio iea to the se4i~ ohlori4e solatiea iaoreases tbo re4cec yoteatial of the solntiea. At a yU valse of 7, 00 the re4oa...

Wales, Robert David

2012-06-07T23:59:59.000Z

191

Provenance of Corexit-related chemical constituents found in nearshore and inland Gulf Coast waters  

E-Print Network [OSTI]

of the watershed including Orange Beach), upland forest, and agriculture. There are major timber companies Company. Additionally, fa

Clement, Prabhakar

192

Case Study of Water-Soluble Metal Containing Organic Constituents of  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Health Services > Return toBiomass

193

Mercury, Methylmercury, and Other Constituents in Sediment and Water from Seasonal and Permanent  

E-Print Network [OSTI]

Wetlands in the Cache Creek Settling Basin and Yolo Bypass, Yolo County, California, 2005-06 Open File Creek Settling Basin and Yolo Bypass, Yolo County, California, 2005-06 By Mark Marvin and permanent wetlands in the Cache Creek Settling Basin and Yolo Bypass, Yolo County, California, 2005-06: U

194

EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2  

SciTech Connect (OSTI)

EGS using CO2 as a working fluid will likely involve hydro-shearing low-permeability hot rock reservoirs with a water solution. After that process, the fractures will be flushed with CO2 that is maintained under supercritical conditions (> 70 bars). Much of the injected water in the main fracture will be flushed out with the initial CO2 injection; however side fractures, micro fractures, and the lower portion of the fracture will contain connate water that will interact with the rock and the injected CO2. Dissolution/precipitation reactions in the resulting scCO2/brine/rock systems have the potential to significantly alter reservoir permeability, so it is important to understand where these precipitates form and how are they related to the evolving ‘free’ connate water in the system. To examine dissolution / precipitation behavior in such systems over time, we have conducted non-stirred batch experiments in the laboratory with pure minerals, sandstone, and basalt coupons with brine solution spiked with MnCl2 and scCO2. The coupons are exposed to liquid water saturated with scCO2 and extend above the water surface allowing the upper portion of the coupons to be exposed to scCO2 saturated with water. The coupons were subsequently analyzed using SEM to determine the location of reactions in both in and out of the liquid water. Results of these will be summarized with regard to significance for EGS with CO2 as a working fluid.

Earl D. Mattson; Travis L. McLing; William Smith; Carl Palmer

2013-02-01T23:59:59.000Z

195

APPLIED PHYTO-REMEDIATION TECHNIQUES USING HALOPHYTES FOR OIL AND BRINE SPILL SCARS  

SciTech Connect (OSTI)

Produced salt water from historical oil and gas production was often managed with inadequate care and unfortunate consequences. In Kansas, the production practices in the 1930's and 1940's--before statewide anti-pollution laws--were such that fluids were often produced to surface impoundments where the oil would segregate from the salt water. The oil was pumped off the pits and the salt water was able to infiltrate into the subsurface soil zones and underlying bedrock. Over the years, oil producing practices were changed so that segregation of fluids was accomplished in steel tanks and salt water was isolated from the natural environment. But before that could happen, significant areas of the state were scarred by salt water. These areas are now in need of economical remediation. Remediation of salt scarred land can be facilitated with soil amendments, land management, and selection of appropriate salt tolerant plants. Current research on the salt scars around the old Leon Waterflood, in Butler County, Kansas show the relative efficiency of remediation options. Based upon these research findings, it is possible to recommend cost efficient remediation techniques for slight, medium, and heavy salt water damaged soil. Slight salt damage includes soils with Electrical Conductivity (EC) values of 4.0 mS/cm or less. Operators can treat these soils with sufficient amounts of gypsum, install irrigation systems, and till the soil. Appropriate plants can be introduced via transplants or seeded. Medium salt damage includes soils with EC values between 4.0 and 16 mS/cm. Operators will add amendments of gypsum, till the soil, and arrange for irrigation. Some particularly salt tolerant plants can be added but most planting ought to be reserved until the second season of remediation. Severe salt damage includes soil with EC values in excess of 16 mS/cm. Operators will add at least part of the gypsum required, till the soil, and arrange for irrigation. The following seasons more gypsum will be added and as the soil EC is reduced, plants can be introduced. If rapid remediation is required, a sufficient volume of topsoil, or sand, or manure can be added to dilute the local salinity, the bulk amendments tilled into the surface with added gypsum, and appropriate plants added. In this case, irrigation will be particularly important. The expense of the more rapid remediation will be much higher.

M.L. Korphage; Bruce G. Langhus; Scott Campbell

2003-03-01T23:59:59.000Z

196

Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration  

SciTech Connect (OSTI)

Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 ?g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

2013-09-16T23:59:59.000Z

197

Calcite dissolution kinetics and solubility in Na-Ca-Mg-Cl brines of geologically relevant composition at 0.1 to 1 bar pCO2 and 25 to 80°C  

E-Print Network [OSTI]

Sedimentary basins can contain close to 20% by volume pore fluids that are commonly classified as brines. These fluids can become undersaturated with respect to calcite as a result of processes such as migration, dispersive mixing, or anthropogenic...

Gledhill, Dwight Kuehl

2006-08-16T23:59:59.000Z

198

The waste water free coke plant  

SciTech Connect (OSTI)

Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

Schuepphaus, K.; Brink, N. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany)

1995-12-01T23:59:59.000Z

199

E-Print Network 3.0 - active constituents isolated Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

subsystems towards in- tegrated systems having numerous... . 2 12;2 Definition of Terms and Problem Statement A coupled model M consists of N constituent1... models--or...

200

Texas County Extension Agents Perceptions of the Effectiveness of Using Facebook to Communicate with Constituents  

E-Print Network [OSTI]

, and perceptions using social media, Facebook in particular, to communicate with constituents. The participants in the study were a randomly selected group of Texas extension agents. A web-based questionnaire was used to measure the perceived level of confidence...

Lewis, Lacey

2014-01-08T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Method and apparatus for the removal of bioconversion of constituents of organic liquids  

DOE Patents [OSTI]

A method and apparatus for the removal or conversion of constituents from bulk organic liquids. A countercurrent biphasic bioreactor system is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the constituent. Two transient, high-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the constituent to produce a product which is then removed from the bioreactor in the aqueous phase or retained in the organic phase. The organic liquid, now free of the original constituents, is ready for immediate use or further processing.

Scott, Timothy (Knoxville, TN); Scott, Charles D. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

202

Method and apparatus for the removal or bioconversion of constituents of organic liquids  

DOE Patents [OSTI]

A method and apparatus are disclosed for the removal or conversion of constituents from bulk organic liquids. A countercurrent biphasic bioreactor system is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the constituent. Two transient, high-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the constituent to produce a product which is then removed from the bioreactor in the aqueous phase or retained in the organic phase. The organic liquid, now free of the original constituents, is ready for immediate use or further processing. 1 fig.

Scott, T.; Scott, C.D.

1994-10-25T23:59:59.000Z

203

Semi-analytical model of brine and CO2 leakage through an abandoned plugged well. Applications for determining an Area of Review and CO2 leakage rate  

E-Print Network [OSTI]

Semi-analytical model of brine and CO2 leakage through an abandoned plugged well. Applications for determining an Area of Review and CO2 leakage rate Arnaud Réveillère, Jérémy Rohmer, Frédéric Wertz / contact the leak, and of CO2,g as a first approach. Compared to the state of the art, it adds the possibility

Paris-Sud XI, Université de

204

Client perceptions of university computing services from the faculty computing skills constituency perspective  

E-Print Network [OSTI]

in perceived effectiveness based on differences in computing skill constituencies. The other area of interest relative to this research was in the applied area of providing computing support. The data suggests that the providers of computing services need...CLIENT PERCEPTIONS OF UNIVERSII Y COMPUTING SERVICES FROM THE FACULTY COMPUTING SKILLS CONSTITUENCY PERSPECTIVE A Thesis C. KAY CLAYBOURN Submitted to the Office of Graduate Studies of Texas A8 M Universi!y in partia! fulfillment ot...

Claybourn, C. Kay

1990-01-01T23:59:59.000Z

205

Fresh Water Generation from Aquifer-Pressured Carbon Storage: Annual Report FY09  

SciTech Connect (OSTI)

This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine is reinjected into the formation at net volume reduction, such that the volume of fresh water extracted balances the volume of CO{sub 2} injected into the formation. This process provides additional CO{sub 2} storage capacity in the aquifer, reduces operational risks (cap-rock fracturing, contamination of neighboring fresh water aquifers, and seismicity) by relieving overpressure in the formation, and provides a source of low-cost fresh water to offset costs or operational water needs. This multi-faceted project combines elements of geochemistry, reservoir engineering, and water treatment engineering. The range of saline formation waters is being identified and analyzed. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations. Computer modeling is being used to evaluate processes in the storage aquifer, including the evolution of the pressure field. Water treatment costs are being evaluated by comparing the necessary process facilities to those in common use for seawater RO. There are presently limited brine composition data available for actual CCS sites by the site operators including in the U.S. the seven regional Carbon Sequestration Partnerships (CSPs). To work around this, we are building a 'catalog' of compositions representative of 'produced' waters (waters produced in the course of seeking or producing oil and gas), to which we are adding data from actual CCS sites as they become available. Produced waters comprise the most common examples of saline formation waters. Therefore, they are expected to be representative of saline formation waters at actual and potential future CCS sites. We are using a produced waters database (Breit, 2002) covering most of the United States compiled by the U.S. Geological Survey (USGS). In one instance to date, we have used this database to find a composition corresponding to the brine expected at an actual CCS site (Big Sky CSP, Nugget Formation, Sublette County, Wyoming). We have located other produced waters databases, which are usually of regional scope (e.g., NETL, 2005, Rocky Mountains basins).

Wolery, T; Aines, R; Hao, Y; Bourcier, W; Wolfe, T; Haussman, C

2009-11-25T23:59:59.000Z

206

Stability of SiC-Matrix Microencapsulated Fuel Constituents at Relevant LWR Conditions  

SciTech Connect (OSTI)

This paper addresses certain key feasibility issues facing the application of SiC-matrix microencapsulated fuels for light water reactor application. Issues addressed are the irradiation stability of the SiC-based nano-powder ceramic matrix under LWR-relevant irradiation conditions, the presence or extent of reaction of the SiC matrix with zirconium-based cladding, the stability of the inner and outer pyrolytic graphite layers of the microencapsulated (TRISO) particle at this uncharacteristically low irradiation temperature, and the state of the particle-matrix interface following irradiation which could possibly effect thermal transport. In the process of determining these feasibility issues microstructural evolution and change in dimension and thermal conductivity was studied. As a general finding the SiC matrix was found to be quite stable with behavior similar to that of CVD SiC. In magnitude the irradiation-induced swelling of the matrix material was slightly higher and irradiation-degraded thermal conductivity was slightly lower as compared to CVD SiC. No significant reaction of this SiC-based nano-powder ceramic matrix material with Zircaloy was observed. Irradiation of the TRISO in the 320-360 C range to a maximum dose of 7.7 1025 n/m2 (E > 0.1 MeV) did not have significant negative impact on the constituent layers of the TRISO fuel. At the highest dose studied layer structure and interface integrity remained essentially unchanged with good apparent thermal transport through the microsphere to the surrounding matrix.

Terrani, Kurt A [ORNL] [ORNL; Katoh, Yutai [ORNL] [ORNL; Leonard, Keith J [ORNL] [ORNL; Perez-Bergquist, Alex G [ORNL] [ORNL; Silva, Chinthaka M [ORNL] [ORNL; Snead, Lance Lewis [ORNL] [ORNL

2014-01-01T23:59:59.000Z

207

Results of investigations at the Zunil geothermal field, Guatemala: Well logging and brine geochemistry  

SciTech Connect (OSTI)

The well logging team from Los Alamos and its counterpart from Central America were tasked to investigate the condition of four producing geothermal wells in the Zunil Geothermal Field. The information obtained would be used to help evaluate the Zunil geothermal reservoir in terms of possible additional drilling and future power plant design. The field activities focused on downhole measurements in four production wells (ZCQ-3, ZCQ-4, ZCQ-5, and ZCQ-6). The teams took measurements of the wells in both static (shut-in) and flowing conditions, using the high-temperature well logging tools developed at Los Alamos National Laboratory. Two well logging missions were conducted in the Zunil field. In October 1988 measurements were made in well ZCQ-3, ZCQ-5, and ZCQ-6. In December 1989 the second field operation logged ZCQ-4 and repeated logs in ZCQ-3. Both field operations included not only well logging but the collecting of numerous fluid samples from both thermal and nonthermal waters. 18 refs., 22 figs., 7 tabs.

Adams, A.; Dennis, B.; Van Eeckhout, E.; Goff, F.; Lawton, R.; Trujillo, P.E.; Counce, D.; Archuleta, J. (Los Alamos National Lab., NM (USA)); Medina, V. (Instituto Nacional de Electrificacion, Guatemala City (Guatemala). Unidad de Desarollo Geotermico)

1991-07-01T23:59:59.000Z

208

Radiation induced redox reactions and fragmentation of constituent ions in ionic liquids II. Imidazolium cations.  

SciTech Connect (OSTI)

In part 1 of this study, radiolytic degradation of constituent anions in ionic liquids (ILs) was examined. The present study continues the themes addressed in part 1 and examines the radiation chemistry of 1,3-dialkyl substituted imidazolium cations, which currently comprise the most practically important and versatile class of ionic liquid cations. For comparison, we also examined 1,3-dimethoxy- and 2-methyl-substituted imidazolium and 1-butyl-4-methylpyridinium cations. In addition to identification of radicals using electron paramagnetic resonance spectroscopy (EPR) and selective deuterium substitution, we analyzed stable radiolytic products using {sup 1}H and {sup 13}C nuclear magnetic resonance (NMR) and tandem electrospray ionization mass spectrometry (ESMS). Our EPR studies reveal rich chemistry initiated through 'ionization of the ions': oxidation and the formation of radical dications in the aliphatic arms of the parent cations (leading to deprotonation and the formation of alkyl radicals in these arms) and reduction of the parent cation, yielding 2-imidazolyl radicals. The subsequent reactions of these radicals depend on the nature of the IL. If the cation is 2-substituted, the resulting 2-imidazolyl radical is relatively stable. If there is no substitution at C(2), the radical then either is protonated or reacts with the parent cation forming a C(2)-C(2) {sigma}{sigma}*-bound dimer radical cation. In addition to these reactions, when methoxy or C{sub {alpha}}-substituted alkyl groups occupy the N(1,3) positions, their elimination is observed. The elimination of methyl groups from N(1,3) was not observed. Product analyses of imidazolium liquids irradiated in the very-high-dose regime (6.7 MGy) reveal several detrimental processes, including volatilization, acidification, and oligomerization. The latter yields a polymer with m/z of 650 {+-} 300 whose radiolytic yield increases with dose (0.23 monomer units per 100 eV for 1-methyl-3-butylimidazolium trifluorosulfonate). Gradual generation of this polymer accounts for the steady increase in the viscosity of the ILs upon irradiation. Previous studies at lower dose have missed this species due to its wide mass distribution (stretching out to m/z 1600) and broad NMR lines, which make it harder to detect at lower concentrations. Among other observed changes is the formation of water immiscible fractions in hydrophilic ILs and water miscible fractions in hydrophobic ILs. The latter is due to anion fragmentation. The import of these observations for use of ILs as extraction solvents in nuclear cycle separations is discussed.

Shkrob, I. A.; Marin, T. W.; Chemerisov, S. D.; Hatcher, J.; Wishart, J. (Chemical Sciences and Engineering Division); (BNL)

2011-04-14T23:59:59.000Z

209

Purge water management system  

DOE Patents [OSTI]

A purge water management system is described for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

Cardoso-Neto, J.E.; Williams, D.W.

1995-01-01T23:59:59.000Z

210

Purge water management system  

DOE Patents [OSTI]

A purge water management system for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

Cardoso-Neto, Joao E. (North Augusta, SC); Williams, Daniel W. (Aiken, SC)

1996-01-01T23:59:59.000Z

211

Apparatus for the field determination of concentration of radioactive constituents in a medium  

DOE Patents [OSTI]

The instant invention is an apparatus for determining the concentration of radioactive constituents in a test sample; such as surface soils, via rapid real-time analyses, and direct readout on location utilizing a probe made up of multiple layers of detection material used in combination with an analyzer and real-time readout unit. This is accomplished by comparing the signal received from the probe, which can discriminate between types of radiation and energies with stored patterns that are based upon experimental results. This comparison can be used in the calibration of a readout display that reads out in real-time the concentrations of constituents per given volume. For example, the concentration of constituents such as Cs-137, Sr-90, U-238 in the soil, and noble gas radionuclides such as Kr-85 in the atmosphere, can be measured in real-time, on location, without the need for laboratory analysis of samples. 14 figs.

Perkins, R.W.; Schilk, A.J.; Warner, R.A.; Wogman, N.A.

1995-08-15T23:59:59.000Z

212

Non-destructive method for determining neutron exposure and constituent concentrations of a body  

DOE Patents [OSTI]

A non-destructive method for determination of neutron exposure and constituent concentrations in an object, such as reactor pressure vessel, is based on the observation of characteristic gamma-rays emitted by activation products in the object by using a unique continuous gamma-ray spectrometer. The spectrometer views the object through appropriate collimators to determine the absolute emission rate of these characteristic gamma-rays, thereby ascertaining the absolute activity of given activation products in the object. These data can then be used to deduce the spatial and angular dependence of neutron exposure or the spatial constituent concentration at regions of interest within the object.

Gold, Raymond (Richland, WA); McElroy, William N. (Richland, WA)

1986-01-01T23:59:59.000Z

213

Non-destructive method for determining neutron exposure and constituent concentrations of a body  

DOE Patents [OSTI]

A non-destructive method for determination of neutron exposure and constituent concentrations in an object, such as a reactor pressure vessel, is based on the observation of characteristic gamma-rays emitted by activation products in the object by using a unique continuous gamma-ray spectrometer. The spectrometer views the object through appropriate collimators to determine the absolute emission rate of these characteristic gamma-rays, thereby ascertaining the absolute activity of given activation products in the object. These data can then be used to deduce the spatial and angular dependence of neutron exposure or the spatial constituent concentrations at regions of interest within the object.

Gold, R.; McElroy, W.N.

1984-02-22T23:59:59.000Z

214

Constituent quark masses obtained from hadron masses with contributions of Fermi-Breit and Glozman-Riska hyperfine interactions  

SciTech Connect (OSTI)

We use the color-spin and flavor-spin interaction Hamiltonians with SU(3) flavor symmetry breaking to obtain meson and baryon mass formulas. Adjusting these masses with experimental masses we determine the constituent quark masses. We discuss the constituent quark masses obtained from meson and baryon mass fits. The results for constituent quark masses are very similar in the case of two different phenomenological models: Fermi-Breit and Glozman-Riska hyperfine interactions.

Borka Jovanovic, V.; Borka, D. [Laboratory of Physics (010), Vinca Institute of Nuclear Sciences, University of Belgrade, P.O. Box 522, 11001 Belgrade (Serbia); Ignjatovic, S. R. [Department of Physics, Faculty of Science, University of Banja Luka, Mladena Stojanovica 2, 78000 Banja Luka (Bosnia and Herzegowina); Jovanovic, P. [Astronomical Observatory, Volgina 7, 11060 Belgrade (Serbia)

2010-12-01T23:59:59.000Z

215

Comparative laboratory selection and field testing of polymers for selective control of water production in gas wells  

SciTech Connect (OSTI)

Intensive comparative feasibility studies were performed in different laboratories in order to select the most promising polymer based technology for water control in gas production and storage wells exhibiting low matrix permeability, high temperature and high produced brine salinity. Core flow experiments performed under reservoir conditions with different commercially available chemical systems have pointed to the superiority of two relatively low-molecular-weight vinyl sulfonated/vinyl amide/acrylamide terpolymers over other polymers to decrease selectively and effectively the water permeability without affecting the gas flow. These polymers have excellent compatibility with all types of reservoir brines and good thermal stability up to 150 C. Furthermore, because of their high shear resistance, and excellent injectability even in low permeability cores, solutions of these polymers can be pumped at high injection rates with a moderate wellhead pressure.

Ranjbar, M. [Technical Univ., Clausthal (Germany); Czolbe, P. [DBI-GUT, Freiberg (Germany); Kohler, N. [IFP, Rueil-Malmaison (France)

1995-11-01T23:59:59.000Z

216

Constituent Particle Break-up during Hot Rolling of AA 5182 Nicolas Moulin(1)  

E-Print Network [OSTI]

Constituent Particle Break-up during Hot Rolling of AA 5182 Nicolas Moulin(1) , Estelle Parra hot reversible rolling of AA5182 alloy sheets has been analysed. The sizes and shapes of intermetallic particles in as-cast and industrially hot rolled AA5182 alloys sheets were characterized by 3D X ray

Paris-Sud XI, Université de

217

Chemical Constituents of the New Endophytic Fungus Mycosphaerella sp. nov. and Their Anti-Parasitic Activity  

E-Print Network [OSTI]

Chemical Constituents of the New Endophytic Fungus Mycosphaerella sp. nov. and Their Anti of California San Diego, La Jolla, California 92093 Abstract Chemical investigation of a new endophytic fungus­6 were not active in these assays at a concentration of 10 g/mL. Keywords Endophytic fungus

Coley, Phyllis

218

Air Pollution: History Air Pollution: Any atmospheric constituent present as a result of  

E-Print Network [OSTI]

Air Pollution: History Air Pollution: Any atmospheric constituent present as a result, or materials. Before 1200 AD · Air pollution results from wood burning, tanning, decaying trash, smelting with carbon PbO + C -> Pb + CO Pollutants Produced: CO, SO2 ·Hong, et al., Greenland ice evidence

Weber, Rodney

219

Responses in Milk Constituents to Intravascular Administration of Two Mixtures of Amino Acids to Dairy Cows  

E-Print Network [OSTI]

to inves- tigate the effects of intravascular infusions of AA mixtures on milk constituents. Cows were infusion, followed by a 5-djugular infusion of a mixture of AA. Two mixtures of AA were used in a crossover (total AA); this mixture was infused at 400 g of M d . The other mixture represented the essential AA

Bequette, Brian J.

220

Water Resources Water Quality and Water Treatment  

E-Print Network [OSTI]

Water Resources TD 603 Lecture 1: Water Quality and Water Treatment CTARA Indian Institute of Technology, Bombay 2nd November, 2011 #12;OVERVIEW Water Quality WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TRE OVERVIEW OF THE LECTURE 1. Water Distribution Schemes Hand Pump

Sohoni, Milind

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Compilation of data to estimate groundwater migration potential for constituents in active liquid discharges at the Hanford Site  

SciTech Connect (OSTI)

A preliminary characterization of the constituents present in the 33 liquid waste streams at the US Department of Energy's Hanford Site has been completed by Westinghouse Hanford Company. In addition, Westinghouse Hanford has summarized the soil characteristics based on drill logs collected at each site that receives these liquid wastes. Literature searches were conducted and available Hanford-specific data were tabulated and reviewed. General literature on organic chemicals present in the liquid waste streams was also reviewed. Using all of this information, Pacific Northwest Laboratory has developed a best estimate of the transport characteristics (water solubility and soil adsorption properties) for those radionuclides and inorganic and organic chemicals identified in the various waste streams. We assume that the potential for transport is qualified through the four geochemical parameters: solubility, distribution coefficient, persistence (radiogenic or biochemical half-life), and volatility. Summary tables of these parameters are presented for more than 50 inorganic and radioactive species and more than 50 organic compounds identified in the liquid waste streams. Brief descriptions of the chemical characteristics of Hanford sediments, solubility, and adsorption processes, and of how geochemical parameters are used to estimate migration in groundwater-sediment environments are also presented. Groundwater monitoring data are tabulated for wells neighboring the facilities that receive the liquid wastes. 91 refs., 16 figs., 23 tabs.

Ames, L.L.; Serne, R.J.

1991-03-01T23:59:59.000Z

222

Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1  

SciTech Connect (OSTI)

The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite sorption sites proving to be of secondary importance. The Groundwater Geochemistry ROM was developed using nonlinear regression to fit the response surface with a quadratic polynomial. The goodness of fit was excellent for the CO2 flux to the atmosphere, and very good for predicting the volumes of groundwater exceeding the pH, TDS, As, Cd and Pb threshold values.

Bacon, Diana H.

2013-03-31T23:59:59.000Z

223

Constituent Quarks and Gluons, Polyakov loop and the Hadron Resonance Gas Model  

E-Print Network [OSTI]

Based on first principle QCD arguments, it has been argued in arXiv:1204.2424[hep-ph] that the vacuum expectation value of the Polyakov loop can be represented in the hadron resonance gas model. We study this within the Polyakov-constituent quark model by implementing the quantum and local nature of the Polyakov loop hep-ph/0412308, hep-ph/0607338. The existence of exotic states in the spectrum is discussed.

E. Megias; E. Ruiz Arriola; L. L. Salcedo

2013-07-29T23:59:59.000Z

224

Supporting Nepal’s Peace Process: From Conflict to Constituent Assembly  

E-Print Network [OSTI]

Supporting Nepal’s Peace Process: From Conflict to Constituent Assembly a special evening talk by Ian Martin chaired by Professor Surya Subedi, OBE 7-9pm, room B102 at SOAS Thursday, 18 March, 2010 Nepal’s political... FOCUSED MISSION: NOT SO LIMITED DURATION 4 complicated by persistent delays of the election as well as ambivalence surrounding the extent to which Nepali in- terlocutors required the technical assistance that UNMIN provided. Like UNMIN’s office of civil...

Martin, Ian

2010-03-18T23:59:59.000Z

225

Initial eccentricity and constituent quark number scaling of elliptic flow in ideal and viscous dynamics  

E-Print Network [OSTI]

In the Israel-Stewart's theory of dissipative hydrodynamics, we study the scaling properties elliptic flow in Au+Au collisions. Initial energy density of the fluid was fixed to reproduce STAR data on $\\phi$ meson multiplicity in 0-5% Au+Au collisions, such that irrespective of fluid viscosity, entropy at the freeze-out is similar in ideal or in viscous evolution. Initial eccentricity or constituent quark number scaling is only approximate in ideal or minimally viscous ($\\eta/s=1/4\\pi$) fluid. Eccentricity scaling become nearly exact in more viscous fluid ($\\eta/s \\geq$0.12). However, in more viscous fluid, constituent quark number scaled elliptic flow for mesons and baryons split into separate scaling functions. Simulated flows also do not exhibit 'universal scaling' i.e. elliptic flow scaled by the constituent quark number and charged particles $v_2$ is not a single function of transverse kinetic energy scaled by the quark number. From a study of violation of universal scaling, we obtain an estimate of QGP viscosity, $\\eta/s=0.12 \\pm 0.03$.

A. K. Chaudhuri

2010-03-23T23:59:59.000Z

226

MODIFIED REVERSE OSMOSIS SYSTEM FOR TREATMENT OF PRODUCED WATERS  

SciTech Connect (OSTI)

This final report of ''Modified Reverse Osmosis System for Treatment of Produced Water,'' DOE project No. DE-FC26-00BC15326 describes work performed in the third year of the project. Several good results were obtained, which are documented in this report. The compacted bentonite membranes were replaced by supported bentonite membranes, which exhibited the same salt rejection capability. Unfortunately, it also inherited the clay expansion problem due to water invasion into the interlayer spaces of the compacted bentonite membranes. We noted that the supported bentonite membrane developed in the project was the first of its kind reported in the literature. An {alpha}-alumina-supported MFI-type zeolite membrane synthesized by in-situ crystallization was fabricated and tested. Unlike the bentonite clay membranes, the zeolite membranes maintained stability and high salt rejection rate even for a highly saline solution. Actual produced brines from gas and oil fields were then tested. For gas fields producing brine, the 18,300 ppm TDS (total dissolved solids) in the produced brine was reduced to 3060 ppm, an 83.3% rejection rate of 15,240 ppm salt rejection. For oilfield brine, while the TDS was reduced from 181,600 ppm to 148,900 ppm, an 18% rejection rate of 32,700 ppm reduction, the zeolite membrane was stable. Preliminary results show the dissolved organics, mainly hydrocarbons, did not affect the salt rejection. However, the rejection of organics was inconclusive at this point. Finally, the by-product of this project, the {alpha}-alumina-supported Pt-Co/Na Y catalytic zeolite membrane was developed and demonstrated for overcoming the two-step limitation of nonoxidation methane (CH{sub 4}) conversion to higher hydrocarbons (C{sub 2+}) and hydrogen (H{sub 2}). Detailed experiments to obtain quantitative results of H{sub 2} generation for various conditions are now being conducted. Technology transfer efforts included five manuscripts submitted to peer-reviewed journals and five conference presentations.

Robert L. Lee; Junghan Dong

2004-06-03T23:59:59.000Z

227

(Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only active lithium carbonate plant in the United States was a brine operation in  

E-Print Network [OSTI]

94 LITHIUM (Data in metric tons of lithium content unless otherwise noted) Domestic Production and Use: The only active lithium carbonate plant in the United States was a brine operation in Nevada. Two companies produced a large array of downstream lithium compounds in the United States from domestic or South

228

An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and temporal flow variations in CO2/brine/rock systems  

Broader source: Energy.gov [DOE]

Project objectives: Generate and characterize mineral dissolution/precipitation reactions in supercritical CO2/brine/rock systems under pressure-temperature-chemistry conditions resembling CO2injection into EGS. Characterize three-dimensional spatial and temporal distributions of rock structures subject to mineral dissolution/precipitation processes by X-ray tomography, SEM imaging, and Microprobe analysis.

229

Impact-driven pressure management via targeted brine extraction Conceptual studies of CO2 storage in saline formations  

E-Print Network [OSTI]

of CO 2 Storage for Full-Scale Deployment, Ground Water, 48(connect the storage formation with the ground surface. ToStorage Systems—Application of a New Analytical Solution, submitted to Ground

Birkholzer, J.T.

2013-01-01T23:59:59.000Z

230

The effect of surface active agents on the relative permeability of brine and gas in porous media  

SciTech Connect (OSTI)

All oil and gas producing wells produce hydrocarbon at some residual water saturation. Therefore, the relative permeability to the hydrocarbon at the effective water saturation dictates performance and not the absolute permeability of the formation. Surface active agents are included in most aqueous treating fluids to improve the compatibility of aqueous fluids with the hydrocarbon containing reservoir. A review of the literature indicates very little core flow data to describe the effects to be expected. Traditionally, it is believed that the reduced surface tension will reduce capillary pressure and enhance the recovery of water after the treatment. The reduced water saturation is then believed to result in higher effective gas saturation and higher relative permeability to gas after the treatment. The principal emphasis of this study has been the development of non-damaging stimulation fluids to improve the production of methane from coalbed methane and other low permeability gas reservoirs.

Conway, M.W. [STIM-LAB, Inc., Duncan, OK (United States); Schraufnagel, R.A. [Gas Research Inst., Chicago, IL (United States); Smith, K.; Thomas, T.

1995-11-01T23:59:59.000Z

231

Dewetting of silica surfaces upon reactions with supercritical CO2 and brine: Pore-scale studies in micromodels  

E-Print Network [OSTI]

of the Gas-Crude Oil-Reservoir Water System. J Chem Eng Datain Naturally Fractured Oil Reservoirs. Energ Fuel 2010, 24,CO 2 injected into depleted oil reservoirs may have faster

Kim, Y.

2013-01-01T23:59:59.000Z

232

Effects of fine particulate matter and its constituents on low birth weight among full-term infants in California  

SciTech Connect (OSTI)

Relationships between prenatal exposure to fine particles (PM{sub 2.5}) and birth weight have been observed previously. Few studies have investigated specific constituents of PM{sub 2.5}, which may identify sources and major contributors of risk. We examined the effects of trimester and full gestational prenatal exposures to PM{sub 2.5} mass and 23 PM{sub 2.5} constituents on birth weight among 646,296 term births in California between 2000 and 2006. We used linear and logistic regression models to assess associations between exposures and birth weight and risk of low birth weight (LBW; <2500 g), respectively. Models were adjusted for individual demographic characteristics, apparent temperature, month and year of birth, region, and socioeconomic indicators. Higher full gestational exposures to PM{sub 2.5} mass and several PM{sub 2.5} constituents were significantly associated with reductions in term birth weight. The largest reductions in birth weight were associated with exposure to vanadium, sulfur, sulfate, iron, elemental carbon, titanium, manganese, bromine, ammonium, zinc, and copper. Several of these PM{sub 2.5} constituents were associated with increased risk of term LBW. Reductions in birth weight were generally larger among younger mothers and varied by race/ethnicity. Exposure to specific constituents of PM{sub 2.5}, especially traffic-related particles, sulfur constituents, and metals, were associated with decreased birth weight in California. -- Highlights: • Examine full gestational and trimester fine particle and its constituents on term birth weight. • Fine particles and several of its constituents associated with birth weight reductions. • Largest reductions for traffic-related particles, sulfur constituents, and metals. • Greater birth weight reductions for younger mothers, and varied by race/ethnicity.

Basu, Rupa, E-mail: Rupa.Basu@oehha.ca.gov [California Office of Environmental Health Hazard Assessment, Air Pollution Epidemiology Section, Oakland, CA (United States)] [California Office of Environmental Health Hazard Assessment, Air Pollution Epidemiology Section, Oakland, CA (United States); Harris, Maria [School of Public Health, Boston University, Boston, MA (United States)] [School of Public Health, Boston University, Boston, MA (United States); Sie, Lillian [School of Public Health, University of California, Berkeley, CA (United States)] [School of Public Health, University of California, Berkeley, CA (United States); Malig, Brian; Broadwin, Rachel; Green, Rochelle [California Office of Environmental Health Hazard Assessment, Air Pollution Epidemiology Section, Oakland, CA (United States)] [California Office of Environmental Health Hazard Assessment, Air Pollution Epidemiology Section, Oakland, CA (United States)

2014-01-15T23:59:59.000Z

233

A Comparison of the Corrosion Resistance of Iron-Based Amorphous Metals and Austenitic Alloys in Synthetic Brines at Elevated Temperature  

SciTech Connect (OSTI)

Several hard, corrosion-resistant and neutron-absorbing iron-based amorphous alloys have now been developed that can be applied as thermal spray coatings. These new alloys include relatively high concentrations of Cr, Mo, and W for enhanced corrosion resistance, and substantial B to enable both glass formation and neutron absorption. The corrosion resistances of these novel alloys have been compared to that of several austenitic alloys in a broad range of synthetic brines, with and without nitrate inhibitor, at elevated temperature. Linear polarization and electrochemical impedance spectroscopy have been used for in situ measurement of corrosion rates for prolonged periods of time, while scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDAX) have been used for ex situ characterization of samples at the end of tests. The application of these new coatings for the protection of spent nuclear fuel storage systems, equipment in nuclear service, steel-reinforced concrete will be discussed.

Farmer, J C

2008-11-25T23:59:59.000Z

234

Preliminary performance assessment for the Waste Isolation Pilot Plant, December 1992. Volume 5, Uncertainty and sensitivity analyses of gas and brine migration for undisturbed performance  

SciTech Connect (OSTI)

Before disposing of transuranic radioactive waste in the Waste Isolation Pilot Plant (WIPP), the United States Department of Energy (DOE) must evaluate compliance with applicable long-term regulations of the United States Environmental Protection Agency (EPA). Sandia National Laboratories is conducting iterative performance assessments (PAs) of the WIPP for the DOE to provide interim guidance while preparing for a final compliance evaluation. This volume of the 1992 PA contains results of uncertainty and sensitivity analyses with respect to migration of gas and brine from the undisturbed repository. Additional information about the 1992 PA is provided in other volumes. Volume 1 contains an overview of WIPP PA and results of a preliminary comparison with 40 CFR 191, Subpart B. Volume 2 describes the technical basis for the performance assessment, including descriptions of the linked computational models used in the Monte Carlo analyses. Volume 3 contains the reference data base and values for input parameters used in consequence and probability modeling. Volume 4 contains uncertainty and sensitivity analyses with respect to the EPA`s Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes (40 CFR 191, Subpart B). Finally, guidance derived from the entire 1992 PA is presented in Volume 6. Results of the 1992 uncertainty and sensitivity analyses indicate that, conditional on the modeling assumptions and the assigned parameter-value distributions, the most important parameters for which uncertainty has the potential to affect gas and brine migration from the undisturbed repository are: initial liquid saturation in the waste, anhydrite permeability, biodegradation-reaction stoichiometry, gas-generation rates for both corrosion and biodegradation under inundated conditions, and the permeability of the long-term shaft seal.

Not Available

1993-08-01T23:59:59.000Z

235

STUDIES ON THE USE OF CARBON DIOXIDE DISSOLVED IN REFRIGERATED BRINE FOR THE PRESERVATION OF WHOLE FISH  

E-Print Network [OSTI]

of water by species of low oil content, such as sole and cod, and an increase in total salt. Con- trolling, NO. Z, 1971. Use of carbon dioxide gas dissolved in re- frigerated seawater seemed promising as an in experiments on holding fish in tanks, carbon dioxide decreased the rate at which their quality was degraded

236

Discharge indices for water quality loads Richard M. Vogel  

E-Print Network [OSTI]

: effective discharge, transport, sediment, constituents, rating curve, half-load Citation: Vogel, R. M., J. RDischarge indices for water quality loads Richard M. Vogel Department of Civil and Environmental load is ultimately the quantity of interest, we define a new index, the half-load discharge, which

Vogel, Richard M.

237

Isothermal vapor-liquid equilibria for benzene + cyclohexane + 1-propanol and for three constituent binary systems  

SciTech Connect (OSTI)

Isothermal vapor-liquid equilibria were measured for the ternary system of benzene + cyclohexane + 1-propanol and its constituent binary systems of benzene + cyclohexane, cyclohexane + 1-propanol, and benzene + 1-propanol at 323.15 and 333.15 K, using the apparatus proposed in a previous study. The experimental binary data were correlated using the NRTL equation. The ternary system was predicted using the binary NRTL parameters. The average absolute percent deviations between the predicted and experimental ternary total pressures are 0.5% at 323.15 K and 0.4% at 333.15 K.

Kurihara, Kiyofumi; Uchiyama, Masanori; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry] [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry

1997-01-01T23:59:59.000Z

238

Nucleon shape and electromagnetic form factors in the chiral constituent quark model  

SciTech Connect (OSTI)

The electromagnetic form factors are the most fundamental quantities to describe the internal structure of the nucleon and the shape of a spatially extended particle is determined by its intrinsic quadrupole moment which can be related to the charge radii. We have calculated the electromagnetic form factors, nucleon charge radii and the intrinsic quadrupole moment of the nucleon in the framework of chiral constituent quark model. The results obtained are comparable to the latest experimental studies and also show improvement over some theoretical interpretations.

Dahiya, Harleen; Sharma, Neetika [Department of Physics, Dr. B.R. Ambedkar National Institute of Technology, Jalandhar, Punjab-144 011 (India)

2010-08-05T23:59:59.000Z

239

Nucleon shape and electromagnetic form factors in the chiral constituent quark model  

E-Print Network [OSTI]

The electromagnetic form factors are the most fundamental quantities to describe the internal structure of the nucleon and the shape of a spatially extended particle is determined by its intrinsic quadrupole moment which can be related to the charge radii. We have calculated the electromagnetic form factors, nucleon charge radii and the intrinsic quadrupole moment of the nucleon in the framework of chiral constituent quark model. The results obtained are comparable to the latest experimental studies and also show improvement over some theoretical interpretations.

Harleen Dahiya; Neetika Sharma

2010-01-27T23:59:59.000Z

240

Treating Coalbed Natural Gas Produced Water for Beneficial Use By MFI Zeolite Membranes  

SciTech Connect (OSTI)

Desalination of brines produced from oil and gas fields is an attractive option for providing potable water in arid regions. Recent field-testing of subsurface sequestration of carbon dioxide for climate management purposes provides new motivation for optimizing efficacy of oilfield brine desalination: as subsurface reservoirs become used for storing CO{sub 2}, the displaced brines must be managed somehow. However, oilfield brine desalination is not economical at this time because of high costs of synthesizing membranes and the need for sophisticated pretreatments to reduce initial high TDS and to prevent serious fouling of membranes. In addition to these barriers, oil/gas field brines typically contain high concentrations of multivalent counter cations (eg. Ca{sup 2+} and SO{sub 4}{sup 2-}) that can reduce efficacy of reverse osmosis (RO). Development of inorganic membranes with typical characteristics of high strength and stability provide a valuable option to clean produced water for beneficial uses. Zeolite membranes have a well-defined subnanometer pore structure and extreme chemical and mechanical stability, thus showing promising applicability in produced water purification. For example, the MFI-type zeolite membranes with uniform pore size of {approx}0.56 nm can separate ions from aqueous solution through a mechanism of size exclusion and electrostatic repulsion (Donnan exclusion). Such a combination allows zeolite membranes to be unique in separation of both organics and electrolytes from aqueous solutions by a reverse osmosis process, which is of great interest for difficult separations, such as oil-containing produced water purification. The objectives of the project 'Treating Coalbed Natural Gas Produced Water for Beneficial Use by MFI Zeolite Membranes' are: (1) to conduct extensive fundamental investigations and understand the mechanism of the RO process on zeolite membranes and factors determining the membrane performance, (2) to improve the membranes and optimize operating conditions to enhance water flux and ion rejection, and (3) to perform long-term RO operation on tubular membranes to study membrane stability and to collect experimental data necessary for reliable evaluations of technical and economic feasibilities. Our completed research has resulted in deep understanding of the ion and organic separation mechanism by zeolite membranes. A two-step hydrothermal crystallization process resulted in a highly efficient membrane with good reproducibility. The zeolite membranes synthesized therein has an overall surface area of {approx}0.3 m{sup 2}. Multichannel vessels were designed and machined for holding the tubular zeolite membrane for water purification. A zeolite membrane RO demonstration with zeolite membranes fabricated on commercial alpha-alumina support was established in the laboratory. Good test results were obtained for both actual produced water samples and simulated samples. An overall 96.9% ion rejection and 2.23 kg/m{sup 2}.h water flux was achieved in the demonstration. In addition, a post-synthesis modification method using Al{sup 3+}-oligomers was developed for repairing the undesirable nano-scale intercrystalline pores. Considerable enhancement in ion rejection was achieved. This new method of zeolite membrane modification is particularly useful for enhancing the efficiency of ion separation from aqueous solutions because the modification does not need high temperature operation and may be carried out online during the RO operation. A long-term separation test for actual CBM produced water has indicated that the zeolite membranes show excellent ion separation and extraordinary stability at high pressure and produced water environment.

Robert Lee; Liangxiong Li

2008-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface...

242

Assessing effects of highway bridge deck runoff on near-by recieving waters in coastal margins using remote monitoring techniques  

E-Print Network [OSTI]

different pollutant loading by sampling the receiving water body (Clear Creek). The collected samples were analyzed for total suspended solids, toxic metals, and other relevant constituents of concerns. The results illustrated that the runoff from... the bridge deck iv exhibited low total suspended solids concentr ations (which were highest in the creek). However, other metal constituents like the zi nc and cooper concentration were high and above standards. The phosphate concentrations...

Nwaneshiudu, Oke

2005-02-17T23:59:59.000Z

243

Statistical Origin of Constituent-Quark Scaling in the QGP hadronization  

E-Print Network [OSTI]

Nonextensive statistics in a Blast-Wave model (TBW) is implemented to describe the identified hadron production in relativistic p+p and nucleus-nucleus collisions. Incorporating the core and corona components within the TBW formalism allows us to describe simultaneously some of the major observations in hadronic observables at the Relativistic Heavy-Ion Collider (RHIC): the Number of Constituent Quark Scaling (NCQ), the large radial and elliptic flow, the effect of gluon saturation and the suppression of hadron production at high transverse momentum (pT) due to jet quenching. In this formalism, the NCQ scaling at RHIC appears as a consequence of non-equilibrium process. Our study also provides concise reference distributions with a least chi2 fit of the available experimental data for future experiments and models.

Zebo Tang; Li Yi; Lijuan Ruan; Ming Shao; Hongfang Chen; Cheng Li; Bedangadas Mohanty; Paul Sorensen; Aihong Tang; Zhangbu Xu

2011-07-07T23:59:59.000Z

244

The hypercentral Constituent Quark Model and its application to baryon properties  

E-Print Network [OSTI]

The hypercentral Constituent Quark Model (hCQM) for the baryon structure is reviewed and its applications are systematically discussed. The model is based on a simple form of the quark potential, which contains a Coulomb-like interaction and a confinement, both expressed in terms of a collective space coordinate, the hyperradius. The model has only three free parameters, determined in order to describe the baryon spectrum. Once the parameters have been fixed, the model, in its non relativistic version, is used to predict various quantities of physical interest, namely the elastic nucleon form factors, the photocouplings and the helicity amplitudes for the electromagnetic excitation of the baryon resonances. In particular, the $Q^2$ dependence of the helicity amplitude is quite well reproduced, thanks to the Coulomb-like interaction. The model is reformulated in a relativistic version by means of the Point Form hamilton dynamics. While the inclusion of relativity does not alter the results for the helicity amp...

Giannini, M M

2015-01-01T23:59:59.000Z

245

Optical methods and systems for detecting a constituent in a gas containing oxygen in harsh environments  

DOE Patents [OSTI]

A method for detecting a gas phase constituent such as carbon monoxide, nitrogen dioxide, hydrogen, or hydrocarbons in a gas comprising oxygen such as air, includes providing a sensing material or film having a metal embedded in a catalytically active matrix such as gold embedded in a yttria stabilized zirconia (YSZ) matrix. The method may include annealing the sensing material at about 900.degree. C., exposing the sensing material and gas to a temperature above 400.degree. C., projecting light onto the sensing material, and detecting a change in the absorption spectrum of the sensing material due to the exposure of the sensing material to the gas in air at the temperature which causes a chemical reaction in the sensing material compared to the absorption spectrum of the sensing material in the absence of the gas. Systems employing such a method are also disclosed.

Carpenter, Michael A. (Scotia, NY); Sirinakis, George (Bronx, NY)

2011-01-04T23:59:59.000Z

246

Water Intoxication  

E-Print Network [OSTI]

2008, May 14). Too much water raises seizure risk in babies.id=4844 9. Schoenly, Lorry. “Water Intoxication and Inmates:article/246650- overview>. 13. Water intoxication alert. (

Lingampalli, Nithya

2013-01-01T23:59:59.000Z

247

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of desalination research. The primary technological method of generating additional water supplies is through desalination and enhanced water reuse and recycling technologies....

248

The effect of freezing on the sulfate-chloride and density-chloride ratios of sea-water  

E-Print Network [OSTI]

in the sulphate-chloride ratio would be expected to have a corresponi- ingly larger effect, on density than would one of the less abundant iona. CHAPTER II LITERATURE REVIEW Evidence for Sulphate Enricl ment in Ice The sulphate-chloride ratio was studied... as early as 1907 vhen Ringer performed laboratory freezing experiments vith sea-vater in which he cooled sea-water until solid salts began to freeze out. of solution. l Portions of the ice and the brine below the ice vere collected and analyzed...

Burkhalter, Albert Charles

1967-01-01T23:59:59.000Z

249

Maintenance of high TDS in pore waters above the New Albany Shale of the Illinois Basin  

SciTech Connect (OSTI)

The TDS content of interstitial waters above the Upper Devonian New Albany Shale of the Illinois Basin, mostly sodium and chloride, increases at an average rate of 15 wt%km[sup [minus]1]. Roughly 200 My have elapsed since the youngest marine rocks of wide horizontal extent [Pennsylvania] were deposited. Regardless of the original brine-forming mechanism, the maintenance of high TDS for such a long time span is problematic because upward diffusion above the New Albany Shale should have lowered TDS if no salt dissolved above the New Albany Shale. Groundwater flow at even small rates would have lowered TDS faster than the process of diffusion alone. Calculations which take into account the effects of vertical diffusion show that the present-day salinity gradient of waters above the New Albany Shale can be explained if: (1) the salinity gradient 200 My b.p. was at least thrice as high as at the present, or (2) salt dissolved above the New Albany Shale at an average rate of about 12 m of halite column over 200 My. The code PORFLOW was used to simulate flushing of brines in a generic basin 500 km wide, 1.5 km deep [the maximum depth of the New Albany Shale], with a low basin-wide topographic gradient of 0.06%.

Ranganathan, V. (Indiana Univ., Bloomington, IN (United States). Dept. of Geological Sciences)

1992-01-01T23:59:59.000Z

250

Higher twists in polarized DIS and the size of the constituent quark  

SciTech Connect (OSTI)

The spontaneous breaking of chiral symmetry implies the presence of a short-distance scale in the QCD vacuum, which phenomenologically may be associated with the ''size'' of the constituent quark, rho {approx} 0.3 fm. We discuss the role of this scale in the matrix elements of the twist-4 and 3 quark-gluon operators determining the leading power (1/Q{sup 2}-) corrections to the moments of the nucleon spin structure functions. We argue that the flavor-nonsinglet twist-4 matrix element, f{sub 2}{sup u-d}, has a sizable negative value of the order rho{sup -2}, due to the presence of sea quarks with virtualities {approx} rho{sup -2} in the proton wave function. The twist-3 matrix element, d{sub 2}, is not related to the scale rho{sup -2}. Our arguments support the results of previous calculations of the matrix elements in the instanton vacuum model. We show that this qualitative picture is in agreement with the phenomenological higher-twist correction extracted from an NLO QCD fit to the world data on g{sub 1}{sup p} and g{sub 1}{sup n}, which include recent data from the Jefferson Lab Hall A and COMPASS experiments. We comment on the implications of the short-distance scale rho for quark-hadron duality and the x-dependence of higher-twist contributions.

Alexander Sidorov; Christian Weiss

2006-02-15T23:59:59.000Z

251

The hypercentral Constituent Quark Model and its application to baryon properties  

E-Print Network [OSTI]

The hypercentral Constituent Quark Model (hCQM) for the baryon structure is reviewed and its applications are systematically discussed. The model is based on a simple form of the quark potential, which contains a Coulomb-like interaction and a confinement, both expressed in terms of a collective space coordinate, the hyperradius. The model has only three free parameters, determined in order to describe the baryon spectrum. Once the parameters have been fixed, the model, in its non relativistic version, is used to predict various quantities of physical interest, namely the elastic nucleon form factors, the photocouplings and the helicity amplitudes for the electromagnetic excitation of the baryon resonances. In particular, the $Q^2$ dependence of the helicity amplitude is quite well reproduced, thanks to the Coulomb-like interaction. The model is reformulated in a relativistic version by means of the Point Form hamilton dynamics. While the inclusion of relativity does not alter the results for the helicity amplitudes, a good description of the nucleon elastic form factors is obtained.

M. M. Giannini; E. Santopinto

2015-01-15T23:59:59.000Z

252

Transformations of inorganic coal constituents in combustion systems. Volume 1, sections 1--5: Final report  

SciTech Connect (OSTI)

The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles? What determines their composition? Whether or not particles deposit? How combustion conditions, including reactor size, affect these processes? remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

Helble, J.J. [ed.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. [PSI Technology Co., Andover, MA (United States); Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. [Arizona Univ., Tucson, AZ (United States); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. [Kentucky Univ., Lexington, KY (United States)

1992-11-01T23:59:59.000Z

253

Methods of chemical analysis for organic waste constituents in radioactive materials: A literature review  

SciTech Connect (OSTI)

Most of the waste generated during the production of defense materials at Hanford is presently stored in 177 underground tanks. Because of the many waste treatment processes used at Hanford, the operations conducted to move and consolidate the waste, and the long-term storage conditions at elevated temperatures and radiolytic conditions, little is known about most of the organic constituents in the tanks. Organics are a factor in the production of hydrogen from storage tank 101-SY and represent an unresolved safety question in the case of tanks containing high organic carbon content. In preparation for activities that will lead to the characterization of organic components in Hanford waste storage tanks, a thorough search of the literature has been conducted to identify those procedures that have been found useful for identifying and quantifying organic components in radioactive matrices. The information is to be used in the planning of method development activities needed to characterize the organics in tank wastes and will prevent duplication of effort in the development of needed methods.

Clauss, S.A.; Bean, R.M.

1993-02-01T23:59:59.000Z

254

Summary Report on CO2 Geologic Sequestration & Water Resources Workshop  

E-Print Network [OSTI]

10 th Annual Conference on Carbon Capture and Sequestration,2 saturated brines. In 10th Carbon Capture and SequestrationIn: 9 th Annual Carbon Capture & Sequestration Meeting,

Varadharajan, C.

2013-01-01T23:59:59.000Z

255

Performance Demonstration Program Plan for RCRA Constituent Analysis of Solidified Wastes  

SciTech Connect (OSTI)

The Performance Demonstration Program (PDP) for Resource Conservation and Recovery Act (RCRA) constituents distributes test samples for analysis of volatile organic compounds (VOCs), semivolatile organic compounds (SVOCs), and metals in solid matrices. Each distribution of test samples is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD; DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department. The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the RCRA PDP. Participating laboratories demonstrate acceptable performance by successfully analyzing single- blind performance evaluation samples (subsequently referred to as PDP samples) according to the criteria established in this plan. PDP samples are used as an independent means to assess laboratory performance regarding compliance with the WAP quality assurance objectives (QAOs). The concentrations of analytes in the PDP samples address levels of regulatory concern and encompass the range of concentrations anticipated in waste characterization samples. The WIPP requires analyses of homogeneous solid wastes to demonstrate compliance with regulatory requirements. These analyses must be performed by laboratories that demonstrate acceptable performance in this PDP. These analyses are referred to as WIPP analyses, and the samples on which they are performed are referred to as WIPP samples. Participating laboratories must analyze PDP samples using the same procedures used for WIPP samples.

Carlsbad Field Office

2006-09-21T23:59:59.000Z

256

An Innovative System for the Efficient and Effective Treatment of Non-Traditional Waters for Reuse in Thermoelectric Power Generation  

SciTech Connect (OSTI)

This study assessed opportunities for improving water quality associated with coal-fired power generation including the use of non-traditional waters for cooling, innovative technology for recovering and reusing water within power plants, novel approaches for the removal of trace inorganic compounds from ash pond effluents, and novel approaches for removing biocides from cooling tower blowdown. This research evaluated specifically designed pilot-scale constructed wetland systems for treatment of targeted constituents in non-traditional waters for reuse in thermoelectric power generation and other purposes. The overall objective of this project was to decrease targeted constituents in non-traditional waters to achieve reuse criteria or discharge limitations established by the National Pollutant Discharge Elimination System (NPDES) and Clean Water Act (CWA). The six original project objectives were completed, and results are presented in this final technical report. These objectives included identification of targeted constituents for treatment in four non-traditional water sources, determination of reuse or discharge criteria for treatment, design of constructed wetland treatment systems for these non-traditional waters, and measurement of treatment of targeted constituents in non-traditional waters, as well as determination of the suitability of the treated non-traditional waters for reuse or discharge to receiving aquatic systems. The four non-traditional waters used to accomplish these objectives were ash basin water, cooling water, flue gas desulfurization (FGD) water, and produced water. The contaminants of concern identified in ash basin waters were arsenic, chromium, copper, mercury, selenium, and zinc. Contaminants of concern in cooling waters included free oxidants (chlorine, bromine, and peroxides), copper, lead, zinc, pH, and total dissolved solids. FGD waters contained contaminants of concern including arsenic, boron, chlorides, selenium, mercury, chemical oxygen demand (COD), and zinc. Similar to FGD waters, produced waters contained contaminants of concern that are predominantly inorganic (arsenic, cadmium, chlorides, chromium, copper, lead, mercury, nickel, sulfide, zinc, total dissolved solids), but also contained some organics (benzene, PAHs, toluene, total organic carbon, total suspended solids, and oil and grease). Constituents of concern that may cause chemical scaling, biofouling and corrosion, such as pH, hardness and ionic strength, and nutrients (P, K, and N) may also be found in all four non-traditional waters. NPDES permits were obtained for these non-traditional waters and these permit limits are summarized in tabular format within this report. These limits were used to establish treatment goals for this research along with toxicity values for Ceriodaphnia dubia, water quality criteria established by the US EPA, irrigation standards established by the United States Department of Agriculture (USDA), and reuse standards focused on minimization of damage to the power plant by treated waters. Constructed wetland treatment systems were designed for each non-traditional water source based on published literature reviews regarding remediation of the constituents of concern, biogeochemistry of the specific contaminants, and previous research. During this study, 4 non-traditional waters, which included ash basin water, cooling water, FGD water and produced water (PW) were obtained or simulated to measure constructed wetland treatment system performance. Based on data collected from FGD experiments, pilot-scale constructed wetland treatment systems can decrease aqueous concentrations of elements of concern (As, B, Hg, N, and Se). Percent removal was specific for each element, including ranges of 40.1% to 77.7% for As, 77.6% to 97.8% for Hg, 43.9% to 88.8% for N, and no measureable removal to 84.6% for Se. Other constituents of interest in final outflow samples should have aqueous characteristics sufficient for discharge, with the exception of chlorides (<2000 mg/L). Based on total dissolved solids, co-

John Rodgers; James Castle

2008-08-31T23:59:59.000Z

257

Electronic conduction in shock-compressed water P. M. Celliers,1  

E-Print Network [OSTI]

, 91680 Bruye`res-le-Cha^tel, France 6 Imperial College, London, United Kingdom 7 Central Laser Facility isentrope above 150 GPa. © 2004 American Institute of Physics. DOI: 10.1063/1.1758944 Water is one of the most abundant molecules in the solar system, ubiquitous in biology, and a fundamental constituent

Lee, Kanani K. M.

258

Appendix A. ASA's WQMAP WQMAP (Water Quality Mapping and Analysis Program) is a proprietary  

E-Print Network [OSTI]

-based personal computer. Color graphics and animation are used to display model prediction. The system-dimensional conservation of water mass, momentum, salt and energy equations on a spherical, non-orthogonal, boundary, energy, dissolved constituents, turbulent #12;294 kinetic energy, and turbulent dissipation. Implicit

Chen, Changsheng

259

A model of reduced oxidation kinetics using constituents and species: Iso-octane and its mixtures with n-pentane, iso-hexane and n-heptane  

SciTech Connect (OSTI)

A previously described methodology for deriving a reduced kinetic mechanism for alkane oxidation and tested for n-heptane is here shown to be valid, in a slightly modified version, for iso-octane and its mixtures with n-pentane, iso-hexane and n-heptane. The model is still based on partitioning the species into lights, defined as those having a carbon number smaller than 3, and heavies, which are the complement in the species ensemble, and mathematically decomposing the heavy species into constituents which are radicals. For the same similarity variable found from examining the n-heptane LLNL mechanism in conjunction with CHEMKIN II, the appropriately scaled total constituent molar density still exhibits a self-similar behavior over a very wide range of equivalence ratios, initial pressures and initial temperatures in the cold ignition regime. When extended to larger initial temperatures than for cold ignition, the self-similar behavior becomes initial temperature dependent, which indicates that rather than using functional fits for the enthalpy generation due to the heavy species' oxidation, an ideal model based on tabular information extracted from the complete LLNL kinetics should be used instead. Similarly to n-heptane, the oxygen and water molar densities are shown to display a quasi-linear behavior with respect to the similarity variable, but here their slope variation is no longer fitted and instead, their rate equations are used with the ideal model to calculate them. As in the original model, the light species ensemble is partitioned into quasi-steady and unsteady species; the quasi-steady light species mole fractions are computed using the ideal model and the unsteady species are calculated as progress variables using rates extracted from the ideal model. Results are presented comparing the performance of the model with that of the LLNL mechanism using CHEMKIN II. The model reproduces excellently the temperature and species evolution versus time or versus the similarity variable, with the exception of very rich mixtures, where the predictions are still very good but the multivalued aspect of these functions at the end of oxidation is not captured in the reduction. The ignition time is predicted within percentages of the LLNL values over a wide range of equivalence ratios, initial pressures and initial temperatures. (author)

Harstad, Kenneth; Bellan, Josette [California Institute of Technology, Jet Propulsion Laboratory, 4800 Oak Grove Drive, M/S 125-109, Pasadena, CA 91109-8099 (United States)

2010-11-15T23:59:59.000Z

260

Effect of humic constituents on the transformation of chlorinated phenols and anilines in the presence of oxidoreductive enzymes or birnessite  

SciTech Connect (OSTI)

Chlorinated phenols and anilines are transformed and detoxified in soil through oxidative coupling reactions mediated by enzymes or metal oxides. The reactions may be influences by humic constituents, such as syringaldehyde or catechol, that originate from lignin decomposition and are also subject to oxidative coupling. In this study, the effect of humic constituents on xenobiotic transformation was evaluated in vitro based on the determination of unreacted chlorophenols and chloroanilines. In experiments with peroxidase, laccase, and birnessite, the transformation of most chlorophenols was considerably enhanced by the addition of syringaldehyde. Less enhancement was observed using 4-hydroxybenzoic acid, and the addition of catechol resulted in a reduction of most transformations. The opposite was observed in experiments with tyrosinase, in which case catechol caused considerable enhancement of chlorophenol transformation. The varying effect of catechol can be explained by different transformation mechanisms involving either o-quinone coupling or free radical coupling. Regardless of the agent used to mediate the reactions, chloroanilines seemed to undergo nucleophilic addition to quinone oligomers, which resulted from coupling of the humic constituents. Catechol, which readily forms quinones and quinone oligomers, was most efficient in enhancing these reactions.

Park, J.W.; Dec, J.; Bollag, J.M. (Pennsylvania State Univ., University Park, PA (United States)); Kim, J.E. (Kyngpook National Univ., Taegu (Korea, Republic of). Dept. of Agricultural Chemistry)

1999-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Polymerization of styrene in microemulsions and water-in-oil-in-water emulsions  

SciTech Connect (OSTI)

Two types of emulsion polymerization media were studied in the formation of polystyrene: two O/W microemulsions and a WOW emulsion. The microemulsions and isolated polystyrene were studied using photon correlation spectroscopy and time-averaged light scattering. GPC verified the polymer's size distribution and FTIR determined the polymer's end groups. Photomicroscopy was used to size the WOW emulsion droplets. The effect of an oil-soluble, azoisobisbutyronitrile (AIBN), versus water-soluble, potassium persulfate (KPS), free-radical generator in the polymerization of styrene in microemulsions was investigated. The microemulsions contained styrene, brine, sodium dodecyl sulfate (SDS), and pentanol. Under the dilute conditions the microemulsions and lattices were stable and the droplets independent of each other. Both AIBN and KPS produced polystyrene containing two different size fractions; the molecular weight of the two fractions were of the order of magnitude of 10{sup 5} and 10{sup 6}. End group analysis indicated that initiator fragments and alcohol fragments were present in the polystyrene. The WOW emulsions contained styrene, water, Tween 80, and Span 80. The multiple phase emulsion had a polydisperse droplet size distribution with globule diameters ranging from 1 {mu}m to 190 {mu}m. Both single and multiple phase globules were present in the emulsion due to < 100% yield. WOW emulsion polymerization was slower than microemulsion polymerization and the reaction never reached completion. The isolated polymer showed a wide size distribution with an average molecular weight of {approximately} 4.6 {times} 10{sup 5}.

Johnson, P.L.

1984-01-01T23:59:59.000Z

262

Chemical Constituents in Sediment in Lake Pontchartrain and in Street Mud  

E-Print Network [OSTI]

. Burkhardt, Kent A. Elrick, Barbara J. Mahler, James J. Smith, and Steven D. Zaugg National Water-USGS World Wide Web: http://www.usgs.gov/ Any use of trade, product, or firm names is for descriptive ...................................................................................................................4 Chlorinated Hydrocarbons and Polycyclic Aromatic Hydrocarbons ........................4 Urban

263

DUSEL Facility Cooling Water Scaling Issues  

SciTech Connect (OSTI)

Precipitation (crystal growth) in supersaturated solutions is governed by both kenetic and thermodynamic processes. This is an important and evolving field of research, especially for the petroleum industry. There are several types of precipitates including sulfate compounds (ie. barium sulfate) and calcium compounds (ie. calcium carbonate). The chemical makeup of the mine water has relatively large concentrations of sulfate as compared to calcium, so we may expect that sulfate type reactions. The kinetics of calcium sulfate dihydrate (CaSO4 {center_dot} 2H20, gypsum) scale formation on heat exchanger surfaces from aqueous solutions has been studied by a highly reproducible technique. It has been found that gypsum scale formation takes place directly on the surface of the heat exchanger without any bulk or spontaneous precipitation in the reaction cell. The kinetic data also indicate that the rate of scale formation is a function of surface area and the metallurgy of the heat exchanger. As we don't have detailed information about the heat exchanger, we can only infer that this will be an issue for us. Supersaturations of various compounds are affected differently by temperature, pressure and pH. Pressure has only a slight affect on the solubility, whereas temperature is a much more sensitive parameter (Figure 1). The affect of temperature is reversed for calcium carbonate and barium sulfate solubilities. As temperature increases, barium sulfate solubility concentrations increase and scaling decreases. For calcium carbonate, the scaling tendencies increase with increasing temperature. This is all relative, as the temperatures and pressures of the referenced experiments range from 122 to 356 F. Their pressures range from 200 to 4000 psi. Because the cooling water system isn't likely to see pressures above 200 psi, it's unclear if this pressure/scaling relationship will be significant or even apparent. The most common scale minerals found in the oilfield include calcium carbonates (CaCO3, mainly calcite) and alkaline-earth metal sulfates (barite BaSO4, celestite SrSO4, anhydrite CaSO4, hemihydrate CaSO4 1/2H2O, and gypsum CaSO4 2H2O or calcium sulfate). The cause of scaling can be difficult to identify in real oil and gas wells. However, pressure and temperature changes during the flow of fluids are primary reasons for the formation of carbonate scales, because the escape of CO2 and/or H2S gases out of the brine solution, as pressure is lowered, tends to elevate the pH of the brine and result in super-saturation with respect to carbonates. Concerning sulfate scales, the common cause is commingling of different sources of brines either due to breakthrough of injected incompatible waters or mixing of two different brines from different zones of the reservoir formation. A decrease in temperature tends to cause barite to precipitate, opposite of calcite. In addition, pressure drops tend to cause all scale minerals to precipitate due to the pressure dependence of the solubility product. And we can expect that there will be a pressure drop across the heat exchanger. Weather or not this will be offset by the rise in pressure remains to be seen. It's typically left to field testing to prove out. Progress has been made toward the control and treatment of the scale deposits, although most of the reaction mechanisms are still not well understood. Often the most efficient and economic treatment for scale formation is to apply threshold chemical inhibitors. Threshold scale inhibitors are like catalysts and have inhibition efficiency at very low concentrations (commonly less than a few mg/L), far below the stoichiometric concentrations of the crystal lattice ions in solution. There are many chemical classes of inhibitors and even more brands on the market. Based on the water chemistry it is anticipated that there is a high likelihood for sulfate compound precipitation and scaling. This may be dependent on the temperature and pressure, which vary throughout the system. Therefore, various types and amounts of scaling may occur at different

Daily, W D

2011-04-05T23:59:59.000Z

264

Total reflection infrared spectroscopy of water-ice and frozen aqueous NaCl solutions  

SciTech Connect (OSTI)

Liquid-like and liquid water at and near the surface of water-ice and frozen aqueous sodium chloride films were observed using attenuated total reflection infrared spectroscopy (ATR-IR). The concentration of NaCl ranged from 0.0001 to 0.01 M and the temperature varied from the melting point of water down to 256 K. The amount of liquid brine at the interface of the frozen films with the germanium ATR crystal increased with salt concentration and temperature. Experimental spectra are compared to reflection spectra calculated for a simplified morphology of a uniform liquid layer between the germanium crystal and the frozen film. This morphology allows for the amount of liquid observed in an experimental spectrum to be converted to the thickness of a homogenous layer with an equivalent amount of liquid. These equivalent thickness ranges from a nanometer for water-ice at 260 K to 170 nm for 0.01 M NaCl close to the melting point. The amounts of brine observed are over an order of magnitude less than the total liquid predicted by equilibrium thermodynamic models, implying that the vast majority of the liquid fraction of frozen solutions may be found in internal inclusions, grain boundaries, and the like. Thus, the amount of liquid and the solutes dissolved in them that are available to react with atmospheric gases on the surfaces of snow and ice are not well described by thermodynamic equilibrium models which assume the liquid phase is located entirely at the surface.

Walker, Rachel L.; Searles, Keith; Willard, Jesse A.; Michelsen, Rebecca R. H., E-mail: RMichelsen@rmc.edu [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)] [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)

2013-12-28T23:59:59.000Z

265

UNL WATER CENTER WATER CURRENT  

E-Print Network [OSTI]

................ Sidney Area Deals with Drought 6................ Water and Electricity Are Inseparable 10's East Campus. "Consolidating administration,faculty and staff and facilities is costeffectiveandper or commercial products constitute endorsement by the U.S. Government. WATER CURRENT Water Center University

Nebraska-Lincoln, University of

266

UNL WATER CENTER WATER CURRENT  

E-Print Network [OSTI]

INSIDE UNL WATER CENTER WATER CURRENT PROTECTING NEBRASKAĂ­S WATER RESOURCES THROUGH RESEARCH with a vision, thereĂ­s an untapped market using resources right under our feet,Ă® the University of Nebraska outdoors in India, Bangladesh, China and Viet- nam. Thousands of them have been grown to harvest

Nebraska-Lincoln, University of

267

Modeling brine-rock interactions in an enhanced geothermal systemdeep fractured reservoir at Soultz-Sous-Forets (France): a joint approachusing two geochemical codes: frachem and toughreact  

SciTech Connect (OSTI)

The modeling of coupled thermal, hydrological, and chemical (THC) processes in geothermal systems is complicated by reservoir conditions such as high temperatures, elevated pressures and sometimes the high salinity of the formation fluid. Coupled THC models have been developed and applied to the study of enhanced geothermal systems (EGS) to forecast the long-term evolution of reservoir properties and to determine how fluid circulation within a fractured reservoir can modify its rock properties. In this study, two simulators, FRACHEM and TOUGHREACT, specifically developed to investigate EGS, were applied to model the same geothermal reservoir and to forecast reservoir evolution using their respective thermodynamic and kinetic input data. First, we report the specifics of each of these two codes regarding the calculation of activity coefficients, equilibrium constants and mineral reaction rates. Comparisons of simulation results are then made for a Soultz-type geothermal fluid (ionic strength {approx}1.8 molal), with a recent (unreleased) version of TOUGHREACT using either an extended Debye-Hueckel or Pitzer model for calculating activity coefficients, and FRACHEM using the Pitzer model as well. Despite somewhat different calculation approaches and methodologies, we observe a reasonably good agreement for most of the investigated factors. Differences in the calculation schemes typically produce less difference in model outputs than differences in input thermodynamic and kinetic data, with model results being particularly sensitive to differences in ion-interaction parameters for activity coefficient models. Differences in input thermodynamic equilibrium constants, activity coefficients, and kinetics data yield differences in calculated pH and in predicted mineral precipitation behavior and reservoir-porosity evolution. When numerically cooling a Soultz-type geothermal fluid from 200 C (initially equilibrated with calcite at pH 4.9) to 20 C and suppressing mineral precipitation, pH values calculated with FRACHEM and TOUGHREACT/Debye-Hueckel decrease by up to half a pH unit, whereas pH values calculated with TOUGHREACT/Pitzer increase by a similar amount. As a result of these differences, calcite solubilities computed using the Pitzer formalism (the more accurate approach) are up to about 1.5 orders of magnitude lower. Because of differences in Pitzer ion-interaction parameters, the calcite solubility computed with TOUGHREACT/Pitzer is also typically about 0.5 orders of magnitude lower than that computed with FRACHEM, with the latter expected to be most accurate. In a second part of this investigation, both models were applied to model the evolution of a Soultz-type geothermal reservoir under high pressure and temperature conditions. By specifying initial conditions reflecting a reservoir fluid saturated with respect to calcite (a reasonable assumption based on field data), we found that THC reservoir simulations with the three models yield similar results, including similar trends and amounts of reservoir porosity decrease over time, thus pointing to the importance of model conceptualization. This study also highlights the critical effect of input thermodynamic data on the results of reactive transport simulations, most particularly for systems involving brines.

Andre, Laurent; Spycher, Nicolas; Xu, Tianfu; Vuataz,Francois-D.; Pruess, Karsten.

2006-12-31T23:59:59.000Z

268

Water Conservation and Water Use Efficiency (Wisconsin)  

Broader source: Energy.gov [DOE]

Wisconsin has several statutes that promote water conservation and controlled water use, and this legislation establishes mandatory and voluntary programs in water conservation and water use...

269

Arnold Schwarzenegger WATER HEATERS AND HOT WATER  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor WATER HEATERS AND HOT WATER DISTRIBUTION SYSTEMS: Lutz J.D. (Lawrence Berkeley National Laboratory). 2008. Water Heaters and Hot Water Distribution

270

Ground Water Ground Sky Sky Water Vegetation Ground Vegetation Water  

E-Print Network [OSTI]

Bear Snow Vegetation RhinoWater Vegetation Ground Water Ground Sky Sky Rhino Water Vegetation Ground Vegetation Water Rhino Water Vegetation Ground Rhino Water Rhino Water Ground Ground Vegetation Water Rhino Vegetation Rhino Vegetation Ground Rhino Vegetation Ground Sky Rhino Vegetation Ground Sky

Chen, Tsuhan

271

SOLAR ENERGY PROGRAM. CHAPTER FROM THE ENERGY AND ENVIRONMENT ANNUAL REPORT 1978  

E-Print Network [OSTI]

energy sources such as solar heated industrial waste heat, geothermal water, brines, and ocean thermal

authors, Various

2011-01-01T23:59:59.000Z

272

SOLAR ENERGY PROGRAM: CHAPTER FROM THE ENERGY AND ENVIRONMENT ANNUAL REPORT 1979  

E-Print Network [OSTI]

energy sources such as solar heated water, indus- trial waste heat, geothermal brines, and ocean thermal

Authors, Various

2010-01-01T23:59:59.000Z

273

TREATMENT OF PRODUCED OIL AND GAS WATERS WITH SURFACTANT-MODIFIED ZEOLITE  

SciTech Connect (OSTI)

Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. It is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some must be treated to remove organic constituents before the water is discharged. Current treatment options are successful in reducing the organic content; however, they cannot always meet the levels of current or proposed regulations for discharged water. Therefore, an efficient, cost-effective treatment technology is needed. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. This report summarizes the work and results of this four-year project. We tested the effectiveness of surfactant-modified zeolite (SMZ) for removal of BTEX with batch and column experiments using waters with BTEX concentrations that are comparable to those of produced waters. The data from our experimental investigations showed that BTEX sorption to SMZ can be described by a linear isotherm model, and competitive effects between compounds were not significant. The SMZ can be readily regenerated using air stripping. We field-tested a prototype SMZ-based water treatment system at produced water treatment facilities and found that the SMZ successfully removes BTEX from produced waters as predicted by laboratory studies. When compared to other existing treatment technologies, the cost of the SMZ system is very competitive. Furthermore, the SMZ system is relatively compact, does not require the storage of potentially hazardous chemicals, and could be readily adapted to an automated system.

Lynn E. Katz; R.S. Bowman; E.J. Sullivan

2003-11-01T23:59:59.000Z

274

Computerized Waters  

E-Print Network [OSTI]

- ing 2002?2005 and documented in TWRI?s Technical Report 284 released in January 2006, include: ? Capabilities for short-term reliability analyses based on current storage conditions (Or what is the likelihood of meeting water needs in the near... System Reference Manual. TWRI Technical Report 255, Second Edition, April 2005. ? Water Rights Analysis Package Modeling System Users Manual. TWRI Technical Report 256, Second Edition, April 2005. ? Fundamentals of Water Availability Modeling...

Wythe, Kathy

2006-01-01T23:59:59.000Z

275

Questions About Your Cooling Water System That You Need To Ask  

E-Print Network [OSTI]

TO BE TREATED? Yes, yes, yes. Two bad th ings happen to water in cooling systems. The impurities in the water concentrate due to evaporation, and the impurities in the air are scrubbed into the water. These impurities, without treatment, would foul... and corrode the system rapidly. HOW CAN I DETERMINE WHAT TREATMENT I NEED? First, you must have tests performed on the water. The chemical constituents must be identified. Your system must be defined in terms of its sca1 ing and foul ing tendencies by a...

Matson, J. V.

1984-01-01T23:59:59.000Z

276

Dynamics of a relativistic Rankine vortex for a two-constituent superfluid in a weak perturbation of cylindrical symmetry  

E-Print Network [OSTI]

From a recent study of a stationary cylindrical solution for a relativistic two-constituent superfluid at low temperature limit, we propose to specify this solution under the form of a relativistic generalisation of a Rankine vortex (Potential vortex whose the core has a solid body rotation).Then we establish the dynamics of the central line of this vortex by supposing that the deviation from the cylindrical configuration is weak in the neighbourhood of the core of the vortex. In "stiff" material the Nambu-Goto equations are obtained.

B. Boisseau

1999-01-18T23:59:59.000Z

277

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which can lead to public health problems. * MtBE (Methyl tert Butyl Ether), a gasoline additive, has begun to contaminate ground water supplies. * Similarly, perchlorate has...

278

Water Management  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water Management This department applies multi-disciplinary science and technology-based modeling to assess complex environmental systems. It integrates ecology, anthropology, and...

279

Please cite this article in press as: Birkholzer, J.T., et al., Brine flow up a well caused by pressure perturbation from geologic carbon sequestration: Static and dynamic evaluations. Int. J. Greenhouse Gas Control (2011), doi:10.1016/j.ijggc.2011.01.003  

E-Print Network [OSTI]

by pressure perturbation from geologic carbon sequestration: Static and dynamic evaluations. Int. J.elsevier.com/locate/ijggc Brine flow up a well caused by pressure perturbation from geologic carbon sequestration: Static carbon sequestration (GCS) has drawn increasing con- sideration as a promising method to mitigate

Zhou, Quanlin

280

Red tide detection and tracing using MODIS fluorescence data: A regional example in SW Florida coastal waters  

E-Print Network [OSTI]

Red tide detection and tracing using MODIS fluorescence data: A regional example in SW Florida-time data from the MODIS satellite sensor was used to detect and trace a harmful algal bloom (HAB), or red to interferences of other water constituents. The red tide that formed from November to December 2004 off SW

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction  

SciTech Connect (OSTI)

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ?375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (?Sr SW = +13.8 to +41.6, where ?Sr SW is the deviation of the 87Sr/86Sr ratio from that of seawater in parts per 104); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

Elizabeth C. Chapman,† Rosemary C. Capo,† Brian W. Stewart,*,† Carl S. Kirby,‡ Richard W. Hammack,§

2012-02-24T23:59:59.000Z

282

Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction  

SciTech Connect (OSTI)

Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of 375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (?{sub Sr}{sup SW} = +13.8 to +41.6, where ?{sub Sr}{sup SW} is the deviation of the {sup 87}Sr/{sup 86}Sr ratio from that of seawater in parts per 10{sup 4}); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

Chapman, Elizabeth C; Capo, Rosemary C.; Stewart, Brian W.; Kirby, Carl S.; Hammack, Richard W.; Schroeder, Karl T.; Edenborn, Harry M.

2012-03-20T23:59:59.000Z

283

Investigating Water  

E-Print Network [OSTI]

........................................................................................... 193 Lesson 11 Water and Pollution........................................................................................................................ 195 Activity 11.1, Pollution, Pollution, Everywhere...! ............................................................................. 205 Record Sheet 11.1, Pollution, Pollution, Everywhere! ..................................................................... 207 Activity 11.2, Pollution at Its Source...

Howard Jr., Ronald A.

2002-01-02T23:59:59.000Z

284

Water Privatisation   

E-Print Network [OSTI]

This dissertation deals with the policy issues of large-scale, urban water privatisation projects in the face of uncertainty and variability. The main objective is to evaluate whether a single policy approach, namely privatisation associated...

Zölls, Elisa

2011-08-17T23:59:59.000Z

285

In Situ Infrared Spectroscopic Study of Brucite Carbonation in Dry to Water-Saturated Supercritical Carbon Dioxide  

SciTech Connect (OSTI)

In geologic carbon sequestration, while part of the injected carbon dioxide will dissolve into host brine, some will remain as neat to water saturated super critical CO2 (scCO2) near the well bore and at the caprock, especially in the short-term life cycle of the sequestration site. Little is known about the reactivity of minerals with scCO2 containing variable concentrations of water. In this study, we used high-pressure infrared spectroscopy to examine the carbonation of brucite (Mg(OH)2) in situ over a 24 hr reaction period with scCO2 containing water concentrations between 0% and 100% saturation, at temperatures of 35, 50, and 70 °C, and at a pressure of 100 bar. Little or no detectable carbonation was observed when brucite was reacted with neat scCO2. Higher water concentrations and higher temperatures led to greater brucite carbonation rates and larger extents of conversion to magnesium carbonate products. The only observed carbonation product at 35 °C was nesquehonite (MgCO3 • 3H2O). Mixtures of nesquehonite and magnesite (MgCO3) were detected at 50 °C, but magnesite was more prevalent with increasing water concentration. Both an amorphous hydrated magnesium carbonate solid and magnesite were detected at 70 °C, but magnesite predominated with increasing water concentration. The identity of the magnesium carbonate products appears strongly linked to magnesium water exchange kinetics through temperature and water availability effects.

Loring, John S.; Thompson, Christopher J.; Zhang, Changyong; Wang, Zheming; Schaef, Herbert T.; Rosso, Kevin M.

2012-04-25T23:59:59.000Z

286

TREATMENT OF PRODUCED WATERS USING A SURFACTANT MODIFIED ZEOLITE/VAPOR PHASE BIOREATOR SYSTEM  

SciTech Connect (OSTI)

Co-produced water from the oil and gas industry is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some of them must be treated to remove organic constituents before the water is discharged. An efficient, cost-effective treatment technology is needed to remove these constituents. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. Our previous DOE research work (DE-AC26-99BC15221) demonstrated that SMZ could successfully remove BTEX compounds from the produced water. In addition, SMZ could be regenerated through a simple air sparging process. The primary goal of this project is to develop a robust SMZ/VPB treatment system to efficiently remove the organic constituents from produced water in a cost-effective manner. This report summarizes work of this project from March 2003 through September 2003. We have continued our investigation of SMZ regeneration from our previous DOE project. Ten saturation/stripping cycles have been completed for SMZ columns saturated with BTEX compounds. The results suggest that BTEX sorption capacity is not lost after ten saturation/regeneration cycles. The composition of produced water from a site operated by Crystal Solutions Ltd. in Wyoming has been characterized and was used to identify key semi-volatile components. Isotherms with selected semi-volatile components have been initiated and preliminary results have been obtained. The experimental vapor phase bioreactors for this project have been designed and assembled to treat the off-gas from the SMZ regeneration process. These columns will be used both in the laboratory and in the proposed field testing to be conducted next year. Innocula for the columns that degrade all of the BTEX columns have been developed.

LYNN E. KATZ; KERRY A. KINNEY; R.S. BOWMAN; E.J. SULLIVAN

2003-10-01T23:59:59.000Z

287

Dolomitization by ground-water flow systems in carbonate platforms  

SciTech Connect (OSTI)

Dolomite occurs throughout the subsurface of modern carbonate platforms such as the Bahamas. Groundwater flow systems must be responsible for delivery of reactants needed for dolomitization. Reflux, freshwater lens flows, and thermal convection are large-scale flow systems that may be widespread in active platforms. The author has evaluated some aspects of the dynamics and characteristics of these processes with ground-water flow theory and by scaled sandbox experiments. Reflux is not restricted to hypersaline brines, but can occur with bankwaters of only slightly elevated salinity such as those found on the Bahama Banks today (42%). The lack of evaporites in a stratigraphic section, therefore, does not rule out the possibility that reflux may have operated. Flows associated with freshwater lenses include flow in the lens, in the mixing zone, and in the seawater beneath and offshore of the lens. Upward transfer of seawater through the platform margins occurs when surrounding cold ocean water migrates into the platform and is heated. This type of thermal convection (Kohout convection) has been studied by Francis Kohout in south Florida. The ranges of mass flux of magnesium in these processes are all comparable and are all sufficient to account for young dolomites beneath modern platforms. Each process yields dolomitized zones of characteristic shape and location and perhaps may be distinguishable in ancient rocks. The concepts presented here may have application to exploration for dolomite reservoirs in the Gulf Coast and elsewhere.

Simms, M.

1984-09-01T23:59:59.000Z

288

Water Heaters and Hot Water Distribution Systems  

E-Print Network [OSTI]

24 Figure 7. Comparison of Daily Water Heater28 Figure 8. Monitored Field Efficiency of Tankless Water28 Figure 9. Monitored Lab Efficiency of Tankless Water

Lutz, Jim

2012-01-01T23:59:59.000Z

289

Water Heaters and Hot Water Distribution Systems  

E-Print Network [OSTI]

Gas-fired Storage Water Heater .. 418 Assess California’s Small Gas Storage Water Heaters Small Gas Storage Water Heater Market The objective of

Lutz, Jim

2012-01-01T23:59:59.000Z

290

Laboratory Report on Performance Evaluation of Key Constituents during Pre-Treatment of High Level Waste Direct Feed  

SciTech Connect (OSTI)

The analytical capabilities of the 222-S Laboratory are tested against the requirements for an optional start up scenario of the Waste Treatment and Immobilization Plant on the Hanford Site. In this case, washed and in-tank leached sludge would be sent directly to the High Level Melter, bypassing Pretreatment. The sludge samples would need to be analyzed for certain key constituents in terms identifying melter-related issues and adjustment needs. The analyses on original tank waste as well as on washed and leached material were performed using five sludge samples from tanks 241-AY-102, 241-AZ-102, 241-AN-106, 241-AW-105, and 241-SY-102. Additionally, solid phase characterization was applied to determine the changes in mineralogy throughout the pre-treatment steps.

Huber, Heinz J.

2013-06-24T23:59:59.000Z

291

Water Rights: Surface Water (Indiana)  

Broader source: Energy.gov [DOE]

The Indiana Department of Natural Resources regulates the use and diversion of surface waters. An entity that creates additional stream volumes by releases from impoundments built and financed by...

292

EXTENSION WATER SUMMIT PRIORITY: WATER CONSERVATION  

E-Print Network [OSTI]

programs) · Audience: homeowners Outcome 4: Increase water reuse and recycling programs · Example program: Water harvesting ­ rain barrels and cisterns · Audience: home owners #12;: Water conservation. Conserve Florida's finite water resources by teaching rural, suburban and urban

Kane, Andrew S.

293

Arnold Schwarzenegger WATER HEATERS AND HOT WATER  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor WATER HEATERS AND HOT WATER DISTRIBUTION SYSTEMS;#12;Appendices Appendix A. Multifamily Water Heating Construction Practices, Pricing and Availability Survey Report Appendix B. Multifamily Water Heating Controls Performance Field Report Appendix C. Pipe

294

Household Water Quality Home Water Quality Problems  

E-Print Network [OSTI]

in water heater. Scale buildup in pipes and re duced water flow. Hard water due to calcium and magnesiumHousehold Water Quality Home Water Quality Problems­ Causes and Treatments Blake Ross, Extension Many areas have water containing impurities from natural or artificial sources. These impurities may

Liskiewicz, Maciej

295

Grabbing water  

E-Print Network [OSTI]

We introduce a novel technique for grabbing water with a flexible solid. This new passive pipetting mechanism was inspired by floating flowers and relies purely on the coupling of the elasticity of thin plates and the hydrodynamic forces at the liquid interface. Developing a theoretical model has enabled us to design petal-shaped objects with maximum grabbing capacity.

P. M. Reis; J. Hure; S. Jung; J. W. M. Bush; C. Clanet

2012-07-16T23:59:59.000Z

296

Baseline risk assessment of ground water contamination at the inactive uriniferous lignite ashing site near Belfield, North Dakota  

SciTech Connect (OSTI)

This Baseline Risk Assessment of Ground Water Contamination at the Inactive Uraniferous Lignite Ashing Site Near Belfield, North Dakota, evaluates potential impacts to public health or the environment resulting from ground water contamination at the site where coal containing uranium was burned to produce uranium. The US Department of Energy`s Uranium Mill Tailings Remedial Action (UMTRA) Project is evaluating plans to remedy soil and ground water contamination at the site. Phase I of the UMTRA Project consists of determining the extent of soil contamination. Phase II of the UMTRA Project consists of evaluating ground water contamination. Under Phase II, results of this risk assessment will help determine what remedial actions may be necessary for contaminated ground water at the site. This risk assessment evaluates the potential risks to human health and the environment resulting from exposure to contaminated ground water as it relates to historic processing activities at the site. Potential risk is quantified for constituents introduced from the processing activities, and not for those constituents naturally occurring in water quality in the site vicinity. Background ground water quality has the potential to cause adverse health effects from exposure through drinking. Any risks associated with contaminants attributable to site activities are incremental to these risks from background ground water quality. This incremental risk from site-related contaminants is quantified in this risk assessment. The baseline risk from background water quality is incorporated only into the assessment of potential chemical interactions and the definition of the overall site condition.

NONE

1994-08-01T23:59:59.000Z

297

Problems #3, Math 204, Dr. M. Bohner. Sep 10, 2003. Due Sep 15, 11 am. 12. A tank has ten gallons of water in which two pounds of salt has been dissolved. Brine with  

E-Print Network [OSTI]

Problems #3, Math 204, Dr. M. Bohner. Sep 10, 2003. Due Sep 15, 11 am. 12. A tank has ten gallons through the supplementary homework problems for Chapters 1­2: 1, 3 of Section 1.1; 1 of Section 1.2; 1-8, 14, 15, 17, 19, 21, 25, 26 of Section 1.3; 1, 3, 4, 13­17, 21, 26, 29 of Section 2.1; 1, 4­8, 9, 11

Bohner, Martin

298

Ordovician carbonate formation waters in the Illinois Basin: Chemical and isotopic evolution beneath a regional aquitard  

SciTech Connect (OSTI)

Formation waters from carbonate reservoirs in the upper Ordovician Galena Group of the Illinois Basin have been analyzed geochemically to study origin of salinity, chemical and isotopic evolution, and relation to paleohydrologic flow systems. These carbonate reservoirs underlie the Maquoketa Shale Group of Cincinnatian age, which forms a regional aquitard. Cl-Br relations and Na/Br-Cl/Br systematics indicate that initial brine salinity resulted from subaerial evaporation of seawater to a point not significantly beyond halite saturation. Subsequent dilution in the subsurface by meteoric waters is supported by delta D-delta O-18 covariance. Systematic relations between Sr-87/Sr-86 and 1/Sr suggest two distinct mixing events: introduction of a Sr-87 enriched fluid from a siliciclastic source, and a later event which only affected reservoir waters from the western shelf of the basin. The second mixing event is supported by covariance between Sr-87/Sr-86 and concentrations of cations and anions; covariance between Sr and O-D isotopes suggests that the event is related to meteoric water influx. Systematic geochemical relations in ordovician Galena Group formation waters have been preserved by the overlying Maquoketa shale aquitard. Comparison with results from previous studies indicates that waters from Silurian-Devonian carbonate strata evolved in a manner similar to yet distinct from that of the Ordovician carbonate waters, whereas waters from Mississippian-Pennsylvanian strata that overlie the New Albany Shale Group regional aquitard are marked by fundamentally different Cl-Br-Na and Sr isotope systematics. Evolution of these geochemical formation-water regimes apparently has been influenced significantly by paleohydrologic flow systems.

Stueber, A.M. (Illinois Univ., Edwardsville, IL (United States)); Walter, L.M. (Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Geological Sciences)

1992-01-01T23:59:59.000Z

299

Resource Conservation and Recovery Act ground-water monitoring projects for Hanford facilities: Progress report for the period October 1 to December 31, 1989  

SciTech Connect (OSTI)

This is Volume 1 of a two-volume document that describes the progress of 15 Hanford Site ground-water monitoring projects for the period October 1 to December 31, 1989. This volume discusses the projects. The work described in this document is conducted by the Pacific Northwest Laboratory under the management of Westinghouse Hanford Company for the US Department of Energy. Concentrations of ground-water constituents are compared to federal drinking water standards throughout this document for reference purposes. All drinking water supplied from the samples aquifer meets regulatory standards for drinking water quality. 51 refs., 35 figs., 86 tabs.

Smith, R.M.; Bates, D.J.; Lundgren, R.E. (eds.)

1990-03-01T23:59:59.000Z

300

The mutagenic potential of soil and runoff water from land treatment of three hazardous industrial wastes  

E-Print Network [OSTI]

of agricultural chemicals and the performance of hazardous waste land treatment facilities. This study used a bioassay directed chemical analysis protocol to monitor the environmental fate of mutagenic constituents from a simulated land treatment demonstration...THE MUTAGENIC POTENTIAL OF SOIL AND RUNOFF WATER FROM LAND TREATMENT OF THREE HAZARDOUS INDUSTRIAL WASTES A Thesis by PHEBE DAYOL Submitted to the Graduate College of Te xa s ASM Un i ver s i ty in partial fulfillment of the requirement...

Davol, Phebe

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Management of water extracted from carbon sequestration projects  

SciTech Connect (OSTI)

Throughout the past decade, frequent discussions and debates have centered on the geological sequestration of carbon dioxide (CO{sub 2}). For sequestration to have a reasonably positive impact on atmospheric carbon levels, the anticipated volume of CO{sub 2} that would need to be injected is very large (many millions of tons per year). Many stakeholders have expressed concern about elevated formation pressure following the extended injection of CO{sub 2}. The injected CO{sub 2} plume could potentially extend for many kilometers from the injection well. If not properly managed and monitored, the increased formation pressure could stimulate new fractures or enlarge existing natural cracks or faults, so the CO{sub 2} or the brine pushed ahead of the plume could migrate vertically. One possible tool for management of formation pressure would be to extract water already residing in the formation where CO{sub 2} is being stored. The concept is that by removing water from the receiving formations (referred to as 'extracted water' to distinguish it from 'oil and gas produced water'), the pressure gradients caused by injection could be reduced, and additional pore space could be freed up to sequester CO{sub 2}. Such water extraction would occur away from the CO{sub 2} plume to avoid extracting a portion of the sequestered CO{sub 2} along with the formation water. While water extraction would not be a mandatory component of large-scale carbon storage programs, it could provide many benefits, such as reduction of pressure, increased space for CO{sub 2} storage, and potentially, 'plume steering.' Argonne National Laboratory is developing information for the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) to evaluate management of extracted water. If water is extracted from geological formations designated to receive injected CO{sub 2} for sequestration, the project operator will need to identify methods for managing very large volumes of water most of which will contain large quantities of salt and other dissolved minerals. Produced water from oil and gas production also typically contains large quantities of dissolved solids. Therefore, many of the same practices that are established and used for managing produced water also may be applicable for extracted water. This report describes the probable composition of the extracted water that is removed from the formations, options for managing the extracted water, the pros and cons of those options, and some opportunities for beneficial use of the water. Following the introductory material in Chapter 1, the report is divided into chapters covering the following topics: (Chapter 2) examines the formations that are likely candidates for CO{sub 2} sequestration and provides a general evaluation of the geochemical characteristics of the formations; (Chapter 3) makes some preliminary estimates of the volume of water that could be extracted; (Chapter 4) provides a qualitative review of many potential technologies and practices for managing extracted water and for each technology or management practice, pros and cons are provided; (Chapter 5) explores the potential costs of water management; and (Chapter 6) presents the conclusions.

Harto, C. B.; Veil, J. A. (Environmental Science Division)

2011-03-11T23:59:59.000Z

302

Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead  

SciTech Connect (OSTI)

Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL confirmed the feasibility of the process. However, researchers at BCT were unable to develop equipment suitable for continuous operation and demonstration of the process in the field was not attempted. The significant achievements of the research area: Bench-scale batch results using carbon dioxide indicate >40% of the feed water to the hydrate formation reactor was converted to hydrate in a single pass; The batch results also indicate >23% of the feed water to the hydrate formation reactor (>50% of the hydrate formed) was converted to purified water of a quality suitable for discharge; Continuous discharge and collection of hydrates was achieved at atmospheric pressure. Continuous hydrate formation and collection at atmospheric conditions was the most significant achievement and preliminary economics indicate that if the unit could be made operable, it is potentially economic. However, the inability to continuously separate the hydrate melt fraction left the concept not ready for field demonstration and the project was terminated after Phase Two research.

BC Technologies

2009-12-30T23:59:59.000Z

303

Modeling CO{sub 2}-Brine-Rock Interaction Including Mercury and H{sub 2}S Impurities in the Context of CO{sub 2} Geologic Storage  

SciTech Connect (OSTI)

This study uses modeling and simulation approaches to investigate the impacts on injectivity of trace amounts of mercury (Hg) in a carbon dioxide (CO{sub 2}) stream injected for geologic carbon sequestration in a sandstone reservoir at ~2.5 km depth. At the range of Hg concentrations expected (7-190 ppbV, or ~ 0.06-1.6 mg/std.m{sup 3}CO{sub 2}), the total volumetric plugging that could occur due to complete condensation of Hg, or due to complete precipitation of Hg as cinnabar, results in a very small porosity change. In addition, Hg concentration much higher than the concentrations considered here would be required for Hg condensation to even occur. Concentration of aqueous Hg by water evaporation into CO{sub 2} is also unlikely because the higher volatility of Hg relative to H{sub 2}O at reservoir conditions prevents the Hg concentration from increasing in groundwater as dry CO{sub 2} sweeps through, volatilizing both H{sub 2}O and Hg. Using a model-derived aqueous solution to represent the formation water, batch reactive geochemical modeling show that the reaction of the formation water with the CO{sub 2}-Hg mixture causes the pH to drop to about 4.7 and then become buffered near 5.2 upon reaction with the sediments, with a negligible net volume change from mineral dissolution and precipitation. Cinnabar (HgS(s)) is found to be thermodynamically stable as soon as the Hg-bearing CO{sub 2} reacts with the formation water which contains small amounts of dissolved sulfide. Liquid mercury (Hg(l)) is not found to be thermodynamically stable at any point during the simulation. Two-dimensional radial reactive transport simulations of CO{sub 2} injection at a rate of 14.8 kg/s into a 400 m-thick formation at isothermal conditions of 106°C and average pressure near 215 bar, with varying amounts of Hg and H{sub 2}S trace gases, show generally that porosity changes only by about ±0.05% (absolute, i.e., new porosity = initial porosity ±0.0005) with Hg predicted to readily precipitate from the CO{sub 2} as cinnabar in a zone mostly matching the single-phase CO{sub 2} plume. The precipitation of minerals other than cinnabar, however, dominates the evolution of porosity. Main reactions include the replacement of primarily Fe-chlorite by siderite, of calcite by dolomite, and of K-feldspar by muscovite. Chalcedony is also predicted to precipitate from the dissolution of feldspars and quartz. Although the range of predicted porosity change is quite small, the amount of dissolution and precipitation predicted for these individual minerals is not negligible. These reactive transport simulations assume that Hg gas behaves ideally. To examine effects of non-ideality on these simulations, approximate calculations of the fugacity coefficient of Hg in CO{sub 2} were made. Results suggest that Hg condensation could be significantly overestimated when assuming ideal gas behavior, making our simulation results conservative with respect to impacts on injectivity. The effect of pressure on Henry’s constant for Hg is estimated to yield Hg solubilities about 10% lower than when this effect is not considered, a change that is considered too small to affect the conclusions of this report. Although all results in this study are based on relatively mature data and modeling approaches, in the absence of experimental data and more detailed site-specific information, it is not possible to fully validate the results and conclusions.

Spycher, N.; Oldenburg, C.M.

2014-01-01T23:59:59.000Z

304

Cleaner, Safer Water through Water Safety Plans  

E-Print Network [OSTI]

CS232615A Cleaner, Safer Water through Water Safety Plans National Center for Environmental Health). Water Safety Plans A Water Safety Plan (WSP) is a preventive management approach used to manage threats to a drinking water system--from catchment to consumer. It helps in the · Management of activities

305

Ground water provides drinking water, irrigation for  

E-Print Network [OSTI]

Ground water provides drinking water, irrigation for crops and water for indus- tries. It is also connected to surface waters, and maintains the flow of rivers and streams and the level of wetlands- tion of those along Lake Michigan, most communi- ties, farms and industries still rely on ground water

Saldin, Dilano

306

Regional Water Management: Adapting to Uncertain Water  

E-Print Network [OSTI]

Regional Water Management: Adapting to Uncertain Water Supply and Demand Jim Schneider, Ph · How Nebraska manages water · Dealing with uncertain water supplies: adaptive management #12;Regional-wide, systematic approach · Flexible--Adaptive Management Adaptive Manageme nt #12;Integrated Water Management

Nebraska-Lincoln, University of

307

Innovative Water Management Technology to Reduce Environment Impacts of Produced Water  

SciTech Connect (OSTI)

Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobic biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post-reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or ?footprint? of a full-size CWTS for a given inflow rate of produced water.

Castle, James; Rodgers, John; Alley, Bethany; Coffey, Ruthanne; Jurinko, Kristen; Pardue, Michael; Ritter, Tina; Spacil, Michael

2013-05-15T23:59:59.000Z

308

Innovative Water Management Technology to Reduce Environmental Impacts of Produced Water  

SciTech Connect (OSTI)

Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobic biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post-reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or ?footprint? of a full-size CWTS for a given inflow rate of produced water.

Castle, James; Rodgers, John; Alley, Bethany; Beebe, Alex; Coffey, Ruthanne; Jurinko, Kristen; Pardue, Michael; Ritter, Tina; Spacil, Michael

2013-05-15T23:59:59.000Z

309

Mineralogical and physical considerations related to the separation and recovery of constituents from aluminum smelter by-products and wastes  

SciTech Connect (OSTI)

Several by-products and waste products of aluminum smelting were characterized mineralogically and physically, in order to evaluate the potential for their decontamination or separation and recovery into valuable products using mineral processing techniques. The test samples were selected from among Bayer process red mud, bath-alumina mixture, cleaned anode butts, anode recycle residues, spent potlining, saltcake and fluorogypsum. Several of these materials were shown to be composed either of highly liberated, potentially separable mineral phases, or of locked minerals which could be partially liberated by grinding to smaller but practical particle sizes. An analysis of specific physical properties of the liberated constituent mineral phases was accompanied by preliminary experimental evaluation of their separability. An assessment was made of potential mineral processing techniques including size and form differentiation, gravitational and magnetic field separation, flotation, separation based on surface charging phenomena or work function, and pneumatic tabling. The results confirmed the suitability of low-cost physical separation techniques for the treatment of some by-products and wastes. This paper presents results of a preliminary evaluation of two smelter products. The conference paper will analyze and discuss in more detail the potential for the mineral processing of these and other smelter by-products and wastes.

Plumpton, A.J.; Wilhelmy, J.F.; Blackburn, D.; Caouette, J.L. [Centre de Recherches Minerales, Sainte-Foy, Quebec (Canada)

1996-10-01T23:59:59.000Z

310

Elastic free-energy of the edge of an open lipid bilayer based on the interactions of its constituent molecules  

E-Print Network [OSTI]

Lipid-bilayers are the fundamental constituents of the walls of most living cells and lipid vesicles, giving them shape and compartment. The formation and growing of pores in a lipid bilayer have attracted considerable attention from an energetic point of view in recent years. Such pores permit targeted delivery of drugs and genes to the cell, and regulate the concentration of various molecules within the cell. The formation of such pores is caused by various reasons such as changes in cell environment, mechanical stress or thermal fluctuations. Understanding the energy and elastic behaviour of a lipid-bilayer edge is crucial for controlling the formation and growth of such pores. In the present work, the interactions in the molecular level are used to obtain the free energy of the edge of an open lipid bilayer. The resulted free-energy density includes terms associated with flexural and torsional energies of the edge, in addition to a line-tension contribution. The line tension, elastic moduli, and spontaneous normal and geodesic curvatures of the edge are obtained as functions of molecular distribution, molecular dimensions, cutoff distance, and the interaction strength. These parameters are further analyzed by implementing a soft-core interaction potential in the microphysical model. The dependence of the elastic free-energy of the edge to the size of the pore is reinvestigated through an illustrative example, and the results are found to be in agreement with the previous observations.

Meisam Asgari; Aisa Biria

2015-02-17T23:59:59.000Z

311

Acoustic-wave sensor apparatus for analyzing a petroleum-based composition and sensing solidification of constituents therein  

DOE Patents [OSTI]

An acoustic-wave sensor apparatus and method are disclosed. The apparatus for analyzing a normally liquid petroleum-based composition includes at least one acoustic-wave device in contact with the petroleum-based composition for sensing or detecting the presence of constituents (e.g. paraffins or petroleum waxes) therein which solidify upon cooling of the petroleum-based composition below a cloud-point temperature. The acoustic-wave device can be a thickness-shear-mode device (also termed a quartz crystal microbalance), a surface-acoustic-wave device, an acoustic-plate-mode device or a flexural plate-wave device. Embodiments of the present invention can be used for measuring a cloud point, a pour point and/or a freeze point of the petroleum-based composition, and for determining a temperature characteristic of each point. Furthermore, measurements with the acoustic-wave sensor apparatus can be made off-line by using a sample having a particular petroleum-based composition; or in-situ with the petroleum-based composition contained within a pipeline or storage tank. The acoustic-wave sensor apparatus has uses in many different petroleum technology areas, including the recovery, transport, storage, refining and use of petroleum and petroleum-based products. 7 figs.

Spates, J.J.; Martin, S.J.; Mansure, A.J.

1997-08-26T23:59:59.000Z

312

Acoustic-wave sensor apparatus for analyzing a petroleum-based composition and sensing solidification of constituents therein  

DOE Patents [OSTI]

An acoustic-wave sensor apparatus and method. The apparatus for analyzing a normally liquid petroleum-based composition includes at least one acoustic-wave device in contact with the petroleum-based composition for sensing or detecting the presence of constituents (e.g. paraffins or petroleum waxes) therein which solidify upon cooling of the petroleum-based composition below a cloud-point temperature. The acoustic-wave device can be a thickness-shear-mode device (also termed a quartz crystal mircrobalance), a surface-acoustic-wave device, an acoustic-plate-mode device or a flexural plate-wave device. Embodiments of the present invention can be used for measuring a cloud point, a pour point and/or a freeze point of the petroleum-based composition, and for determining a temperature characteristic of each point. Furthermore, measurements with the acoustic-wave sensor apparatus can be made off-line by using a sample having a particular petroleum-based composition; or in-situ with the petroleum-based composition contained within a pipeline or storage tank. The acoustic-wave sensor apparatus has uses in many different petroleum technology areas, including the recover transport, storage, refining and use of petroleum and petroleum-based products.

Spates, James J. (Albuquerque, NM); Martin, Stephen J. (Albuquerque, NM); Mansure, Arthur J. (Albuquerque, NM)

1997-01-01T23:59:59.000Z

313

Baseline risk assessment of ground water contamination at the inactive uriniferous lignite ashing site near Belfield, North Dakota. Revision 1  

SciTech Connect (OSTI)

This risk assessment evaluates the potential for impacts to public health or the environment from contaminated ground water at this site caused by the burning of coal containing uranium to produce uranium. Potential risk is quantified for constituents introduced from the processing activities and not for those constituents naturally occurring in background ground water in the site vicinity. Because background ground water quality has the potential to cause adverse health effects from exposure through drinking, any risks associated with contaminants attributable to site activities are incremental to these risks from background. The incremental risk from site-related contaminants is quantified in this risk assessment. The baseline risk from background water quality is incorporated only into the assessment of potential chemical interactions and the definition of the overall site condition. The US Department of Energy`s (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is developing plans to remedy soil and ground water contamination at the site. The UMTRA Surface Project consists of determining the extent of soil contamination and disposing of the contaminated soils in an engineered disposal cell. The UMTRA Ground Water Project consists of evaluating ground water contamination. Under the UMTRA Ground Water Project, results of this risk assessment will help determine what ground water compliance strategy may be applied at the site.

NONE

1994-09-01T23:59:59.000Z

314

Baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota  

SciTech Connect (OSTI)

This baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota, evaluates the potential impacts to public health or the environment from contaminated ground water at this site. This contamination is a result of the uraniferous lignite ashing process, when coal containing uranium was burned to produce uranium. Potential risk is quantified only for constituents introduced by the processing activities and not for the constituents naturally occurring in background ground water in the site vicinity. Background ground water, separate from any site-related contamination, imposes a percentage of the overall risk from ground water ingestion in the Bowman site vicinity. The US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is developing plans to address soil and ground water contamination at the site. The UMTRA Surface Project involves the determination of the extent of soil contamination and design of an engineered disposal cell for long-term storage of contaminated materials. The UMTRA Ground Water Project evaluates ground water contamination. Based on results from future site monitoring activities as defined in the site observational work plan and results from this risk assessment, the DOE will propose an approach for managing contaminated ground water at the Bowman site.

Not Available

1994-11-01T23:59:59.000Z

315

Water Management Act (Massachusetts)  

Broader source: Energy.gov [DOE]

This Act regulates and registers water withdrawals in the Commonwealth of Massachusetts to enable effective planning and management of water use and conservation. The Act establishes a Water...

316

Protected Water Sources (Iowa)  

Broader source: Energy.gov [DOE]

This chapter designates protected water sources, which are subject to additional special conditions regarding water use. Permit applications for water withdrawals from these sources may still be...

317

Storm Water Analytical Period  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Storm Water Analytical Period Storm Water Analytical Period The Individual Permit authorizes the discharge of storm water associated with historical industrial activities at LANL...

318

Water Permits (Louisiana)  

Broader source: Energy.gov [DOE]

The Water Permits Division authorizes permits administered under the Water Quality Regulations. Louisiana's Water Quality Regulations require permits for the discharge of pollutants from any point...

319

Light Water Reactor Sustainability  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 Light Water Reactor Sustainability Program ACCOMPLISHMENTS REPORT 2013 Accomplishments Report | Light Water Reactor Sustainability 2 T he mission of the Light Water Reactor...

320

Light Water Reactor Sustainability  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 Light Water Reactor Sustainability ACCOMPLISHMENTS REPORT 2014 Accomplishments Report | Light Water Reactor Sustainability 2 T he mission of the Light Water Reactor...

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Efficient Water Use & Management  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Goals Water Use Goal 4: Efficient Water Use & Management Aware of the arid climate of northern New Mexico, water reduction and conservation remains a primary concern at LANL....

322

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and Materials Disposition InformationInteractionsWater

323

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption byAbout Printable VersionProtectiveWaste to beswim WatchingWaterW

324

Integrated hydrothermal model for proposed deep crustal borehole on Texas Gulf Coast - origins of geopressured brines and lead-zinc, uranium, hydrocarbon, and cap-rock deposits  

SciTech Connect (OSTI)

Sediment accumulation over Jurassic salt in the Gulf coast has resulted in an interrelated sequential development of salt domes and diagenetic, hydrothermal, and hydrocarbon generation zones. Primary anhydrites within the salt with high /sup 87/Sr//sup 86/Sr ratios suggest early generation of underlying fluids rich in radiogenic strontium that were incorporated in the salt during its diapiric rise to the surface. Subsequently, late-stage, hydrocarbon-rich, saline hydrothermal fluids migrated up the margins of the salt domes, and caused precipitation of several generation of calcite cements, followed by uranium and Mississippi Valley-type lead-zinc-barite deposits near or at salt dome rims. Present fluids in the lower Frio (deeper than 4270 m or 14,000 ft) at the Pleasant Bayou geopressured-geothermal test well (Brazoria County, Texas) are highly saline and enriched in iron, manganese, lead, zinc, and carbon dioxide, and are saturated in methane. These lower Frio waters must have migrated into the area recently because they are not in isotopic equilibrium with diagenetic albite cements formed at temperatures greater than 120/sup 0/C (248/sup 0/F) less than 7.5 million years ago. Isotopic and geochemical data suggest that the fluids trapped by geopressure in the lower Frio at the Pleasant Bayou well are the parent fluids of those causing salt dome cap-rock mineralization.

Light, M.P.R.; Posey, H.H.

1986-05-01T23:59:59.000Z

325

Drinking Water Problems: Lead  

E-Print Network [OSTI]

Lead in drinking water can damage the brain, kidneys, nervous system and red blood cells. This publication explains how lead can enter drinking water, how to have your water tested, and how to eliminate lead from drinking water....

Dozier, Monty; McFarland, Mark L.

2004-02-20T23:59:59.000Z

326

ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

Cadeddu, Maria

327

Water watch  

SciTech Connect (OSTI)

The Hydropower Generation Report provides generation figures for the largest hydropower producers in each of six regions in the US. The report compares, for each month, the amount of hydroelectricity generated (in thousands of megawatt-hours) by each producers in the last two years to the ten-year average for that month. This database is used to figure long-term generation averages and percent of averages. The producers regularly provide current generation data to update the database. This issue of [open quotes]Water Watch[close quotes] focuses on winter snow conditions across the US as of mid-January. In addition, the department provides an outlook of spring flood potential. The information presented is based on data from the US Geological Survey, the National Weather Service, and the Soil Conservation Service.

Not Available

1991-02-01T23:59:59.000Z

328

Atomizing, continuous, water monitoring module  

DOE Patents [OSTI]

A system for continuously analyzing volatile constituents of a liquid is described. The system contains a pump for continuously pumping the liquid to be tested at a predetermined flow rate into an extracting container through a liquid directing tube having an orifice at one end and positioned to direct the liquid into the extracting container at a flow rate sufficient to atomize the liquid within the extracting container. A continuous supply of helium carrier gas at a predetermined flow rate is directed through a tube into the extracting container and co-mingled with the atomized liquid to extract the volatile constituents contained within the atomized liquid. The helium containing the extracted volatile constituents flows out of the extracting container into a mass spectrometer for an analysis of the volatile constituents of the liquid.

Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

1997-01-01T23:59:59.000Z

329

Atomizing, continuous, water monitoring module  

DOE Patents [OSTI]

A system for continuously analyzing volatile constituents of a liquid is described. The system contains a pump for continuously pumping the liquid to be tested at a predetermined flow rate into an extracting container through a liquid directing tube having an orifice at one end and positioned to direct the liquid into the extracting container at a flow rate sufficient to atomize the liquid within the extracting container. A continuous supply of helium carrier gas at a predetermined flow rate is directed through a tube into the extracting container and co-mingled with the atomized liquid to extract the volatile constituents contained within the atomized liquid. The helium containing the extracted volatile constituents flows out of the extracting container into a mass spectrometer for an analysis of the volatile constituents of the liquid. 3 figs.

Thompson, C.V.; Wise, M.B.

1997-07-08T23:59:59.000Z

330

Water Resources Policy & Economics  

E-Print Network [OSTI]

Water Resources Policy & Economics FOR 4984 Selected Course Topics · Appropriative and riparian water institutions · Incentives for conservation · Water rights for in-stream environmental use · Surface water-groundwater management · Water quality regulations · Water markets · Economic and policy

Buehrer, R. Michael

331

Water Sustainability Program Challenges to Sustainable Water  

E-Print Network [OSTI]

· Drought, Climate Change · Growth and the need for additional supplies · Water and Energy · Water the Southwest, nation, semi-arid and arid regions, and the world. · Today's program provides just a glimpse to and utilization of renewable supplies · Transboundary water issues · The surface water/groundwater interface

Cushing, Jim. M.

332

Vapor-liquid equilibria of n-hexane + cyclohexane + n-heptane and the three constituent binary systems at 101. 0 kPa  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data for the title ternary system and the three constituent binary systems have been measured at 101.0 kPa by using a dynamic equilibrium still. The binary data were tested for thermodynamic consistency and were correlated by the Wilson, NRTL, and UNIQUAC equations. Predictions for the ternary system by these equations have been compared with the experimental data.

Jan, D.S.; Shiau, H.Y.; Tsai, F.N. (National Cheng Kung Univ., Tainan (Taiwan, Province of China). Dept. of Chemical Engineering)

1994-07-01T23:59:59.000Z

333

Water Footprint | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Footprint Blue water represents water withdrawn from surface water and groundwater for feedstock irrigation and refinery processing. Blue water represents water withdrawn from...

334

In-Situ, Real-Time Measurement of Melt Constituents in the Aluminum, Glass, and Steel Industries  

SciTech Connect (OSTI)

Energy Research Company (ERCo), with support from DOE’s Industrial Technologies Program, Sensors and Automation has developed a Laser Induced Breakdown Spectroscopy (LIBS) probe to measure, in real time and in-situ, the composition of an aluminum melt in a furnace at an industrial plant. The compositional data is provided to the operator continuously allowing the operator to adjust the melt composition, saving energy, increasing production, and maintaining tighter compositional tolerances than has been previously possible. The overall objectives of this project were to: -- design, develop, fabricate, test and project future costs of the LIBS probe on bench-size experiments; - test the unit in a pilot-scaled aluminum furnace under varying operating conditions of temperature and melt constituents; -- determine the instruments needed for use in industrial environment; -- compare LIBS Probe data to readings traditionally taken on the furnace; -- get full-scale data to resolve if, and how, the LIBS Probe design should be modified for operator acceptance. Extensive laboratory tests have proven the concept feasibility. Elemental concentrations below 0.1% wt. have been accurately measured. Further, the LIBS system has now been installed and is operating at a Commonwealth Aluminum plant in Ohio. The technology is crosscutting as it can be used in a wide variety of applications. In the Sensors and Automation Program the application was for the secondary aluminum industry. However, this project spawned a number of other applications, which are also reported here for completeness. The project was effective in that two commercial systems are now operating; one at Commonwealth Aluminum and another at a PPG fiberglass plant. Other commercial installations are being negotiated as of this writing. This project led to the following conclusions: 1. The LIBS System has been developed for industrial applications. This is the first time this has been accomplished. In addition, two commercial installations have been completed; one at Commonwealth and another at PPG. 2. The system is easy to operate and requires no operator training. Calibration is not required. It is certified as eye safe. 3. The system is crosscutting and ERCo is evaluating seven applications, as reported in this report, and other applications to be reported later. 4. A business plan is being completed for each of the near term markets. ERCo is committed to achieving continued commercial success with the LIBS System. 5. A world wide patent has been issued. 6. The energy savings is substantial. The annual energy savings, by 2010, for each industry is estimated as follows: o Secondary Aluminum – 1.44 trillion Btu’s o Glass – 17 to 45 trillion Btu’s o Steel – Up to 26 trillion Btu’s

Robert De Saro

2006-05-18T23:59:59.000Z

335

Arkansas Water Resources Center  

E-Print Network [OSTI]

Chapter 14 Water Pollution #12;Factory-style hog farms in North Carolina Each pig produces, September 1999. #12;Hogs killed by flooding #12; Water pollution Common water pollutants Treating water pollution Wastewater treatment and renovation Learning Objectives #12; Water pollution refers

Soerens, Thomas

336

Water Basins Civil Engineering  

E-Print Network [OSTI]

Water Basins Civil Engineering Objective · Connect the study of water, water cycle, and ecosystems with engineering · Discuss how human impacts can effect our water basins, and how engineers lessen these impacts: · The basic concepts of water basins are why they are important · To use a topographic map · To delineate

Provancher, William

337

Grains, Water Introduction  

E-Print Network [OSTI]

Grains, Water & Wet Sand Onno Bokhove Introduction Dry Granular Chute Flows: Cantilever Water Waves: Bores Near the Shore Surf Induced Sand Dynamics Discussion Dry Granular Flows, Water Waves & Surf, Water & Wet Sand Onno Bokhove Introduction Dry Granular Chute Flows: Cantilever Water Waves: Bores Near

Wirosoetisno, Djoko

338

Water Heaters and Hot Water Distribution Systems  

E-Print Network [OSTI]

heat loss testing; part load performance curves for instantaneous gas water heaters; and pressure loss calculationsheat loss testing; part load performance curves for instantaneous gas water heaters; and pressure loss calculations

Lutz, Jim

2012-01-01T23:59:59.000Z

339

Water Usage Law, Major Water Users (Missouri)  

Broader source: Energy.gov [DOE]

Any water user with the capability to withdraw or divert 100,000 gallons or more per day from any stream, river, lake, well, spring or other water source must register and file for a permit for...

340

WATER RESOURCES NEBRASKA WATER RESOURCES RESEARCH INSTITUTE  

E-Print Network [OSTI]

current pricing policies and legal structures. In analyzing energy-water relationships, wasteful may be obscured by others such as energy, environment, and quality of life, but in the long run of water to all major social issues is finally driven home. The energy crisis is a case in point. Water

Nebraska-Lincoln, University of

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

The Role of Basis Set Superposition Error in Water Addition Reactions to Ln(III) Cations  

SciTech Connect (OSTI)

Our goal in this work was to characterize the importance of basis set superposition error (BSSE) in the reaction energetics of water addition to highly charged metal ions that exhibit strong ion-dipole interactions with water. The gas phase water addition reactions, M(H?O)ł+N + H?O ? M(H?O)ł+N ? ? [M = La(III), Lu(III); N = 0–8] have been studied, with a particular emphasis on a posteriori methods for calculating BSSE and its constituent energetic components as a function of M(H?O) ł+N cluster size and water basis set. Because of accumulation of BSSE within the subclusters in the reaction series, the successive reaction counterpoise method for determining the BSSE correction interaction energies is advocated.

Kvamme, Brandon; Wander, Matthew C F.; Clark, Aurora E.

2009-06-01T23:59:59.000Z

342

Water Rights (Texas)  

Broader source: Energy.gov [DOE]

The Texas Commission on Environmental Quality regulates the water rights for the state of Texas. Water and state water may be appropriated, stored, or diverted in the state of Texas for beneficial...

343

Reduction of Water Consumption  

E-Print Network [OSTI]

Cooling systems using water evaporation to dissipate waste heat, will require one pound of water per 1,000 Btu. To reduce water consumption, a combination of "DRY" and "WET" cooling elements is the only practical answer. This paper reviews...

Adler, J.

344

Water and Energy Interactions  

E-Print Network [OSTI]

power plants, water withdrawals for electricity generationelectricity generation in 2009 (33). Water used in thermal electric power plantsplant with CCS technologies requires roughly 1,000 gallons of water for every megawatt-hour of electricity generation (

McMahon, James E.

2013-01-01T23:59:59.000Z

345

Water Use Permitting (Wisconsin)  

Broader source: Energy.gov [DOE]

Withdrawers in the Great Lakes Basin who withdraw water in quantities that average 100,000 gallons per day or more in any 30-day period are required to get a water use permit. Two types of water...

346

Lawn Water Management  

E-Print Network [OSTI]

Water is a limited resource in Texas. This booklet explains how homeowners can establish a water management program for a home lawn that both maintains a healthy sod and also conserves water. The publication discusses soil types, grass varieties...

McAfee, James

2006-06-26T23:59:59.000Z

347

Saving Water Saves Energy  

E-Print Network [OSTI]

H. , Groves D. California Water 2030: An Efficient Future,Preemption of California’s Water Conservation Standards for2Epdf Biermayer P. Potential Water and Energy Savings from

McMahon, James E.; Whitehead, Camilla Dunham; Biermayer, Peter

2006-01-01T23:59:59.000Z

348

Review: Globalization of Water  

E-Print Network [OSTI]

Review: Globalization of Water: Sharing the Planet’sAshok K. Globalization of Water: Sharing the Planet’s140) liters of virtual water (p. 15). This is one of the

Tennant, Matthew Aaron

2009-01-01T23:59:59.000Z

349

Effect of water in salt repositories. Final report  

SciTech Connect (OSTI)

Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

1983-09-01T23:59:59.000Z

350

Integrated regional water management: Collaboration or water politics as usual?  

E-Print Network [OSTI]

types of water management organizations, environmental NGOs,environmental policy and integrated water management hasenvironmental and water infrastructure stakeholders involved in Bay Area water management.

Lubell, Mark N.; Lippert, Lucas

2010-01-01T23:59:59.000Z

351

Integrated regional water management: Collaboration or water politics as usual?  

E-Print Network [OSTI]

environmental policy and integrated water management hastypes of water management organizations, environmental NGOs,environmental and water infrastructure stakeholders involved in Bay Area water management.

Lubell, Mark N.; Lippert, Lucas

2010-01-01T23:59:59.000Z

352

Water World: Success Stories and Tools for Water Use Reduction...  

Energy Savers [EERE]

Water World: Success Stories and Tools for Water Use Reduction in Your Building Portfolio Water World: Success Stories and Tools for Water Use Reduction in Your Building Portfolio...

353

Interfacial water on crystalline silica: A comparative molecular dynamics simulation study  

SciTech Connect (OSTI)

All-atom molecular dynamics simulations were conducted to study the dynamics of aqueous electrolyte solutions confined in slit-shaped silica nanopores of various degrees of protonation. Five degrees of protonation were prepared by randomly removing surface hydrogen atoms from fully protonated crystalline silica surfaces. Aqueous electrolyte solutions containing NaCl or CsCl salt were simulated at ambient conditions. In all cases, the ionic concentration was 1 M. The results were quantified in terms of atomic density distributions within the pores, and the self-diffusion coefficient along the direction parallel to the pore surface. We found evidence for ion-specific properties that depend on ion surface, water ion, and only in some cases ion ion correlations. The degree of protonation strongly affects the structure, distribution, and the dynamic behavior of confined water and electrolytes. Cl ions adsorb on the surface at large degrees of protonation, and their behavior does not depend significantly on the cation type (either Na+ or Cs+ ions are present in the systems considered). The cations show significant ion-specific behavior. Na+ ions occupy different positions within the pore as the degree of protonation changes, while Cs+ ions mainly remain near the pore center at all conditions considered. For a given degree of protonation, the planar self-diffusion coefficient of Cs+ is always greater than that of Na+ ions. The results are useful for better understanding transport under confinement, including brine behavior in the subsurface, with important applications such as environmental remediation.

Ho, Tuan A. [University of Oklahoma, Norman; Argyris, D. [University of Oklahoma, Norman; Cole, David [Ohio State University; Striolo, Alberto [Oklahoma University

2011-01-01T23:59:59.000Z

354

Microbial communities in flowback water impoundments from hydraulic fracturing for recovery of shale gas  

SciTech Connect (OSTI)

Hydraulic fracturing for natural gas extraction from shale produces waste brine known as flowback that is impounded at the surface prior to reuse and/or disposal. During impoundment, microbial activity can alter the fate of metals including radionuclides, give rise to odorous compounds, and result in biocorrosion that complicates water and waste management and increases production costs. Here, we describe the microbial ecology at multiple depths of three flowback impoundments from the Marcellus shale that were managed differently. 16S rRNA gene clone libraries revealed that bacterial communities in the untreated and biocide-amended impoundments were depth dependent, diverse, and most similar to species within the taxa [gamma]-proteobacteria, [alpha]-proteobacteria, ?-proteobacteria, Clostridia, Synergistetes, Thermotogae, Spirochetes, and Bacteroidetes. The bacterial community in the pretreated and aerated impoundment was uniform with depth, less diverse, and most similar to known iodide-oxidizing bacteria in the [alpha]-proteobacteria. Archaea were identified only in the untreated and biocide-amended impoundments and were affiliated to the Methanomicrobia class. This is the first study of microbial communities in flowback water impoundments from hydraulic fracturing. The findings expand our knowledge of microbial diversity of an emergent and unexplored environment and may guide the management of flowback impoundments.

Mohan, Arvind Murali; Hartsock, Angela; Hammack, Richard W.; Vidic, Radisav D; Gregory, Kelvin B.

2013-12-01T23:59:59.000Z

355

What's your water footprint?  

E-Print Network [OSTI]

tx H2O | pg. 21 What?s your water footprint? When it comes to your water use, do you tread lightly or are you an H2O Sasquatch? How much water do you think you consume every day? You might initially consider the length of your daily shower... water footprint is the amount of water you directly or indirectly consume. This includes ?virtual water??the amount of water needed to produce everyday things such as food, clothing, and energy. ] What?s your water footprint? tx H2O | pg. 22...

Jordan, Leslie

2009-01-01T23:59:59.000Z

356

Water Efficiency Goal Guidance  

Broader source: Energy.gov [DOE]

The Council on Environmental Quality (CEQ) issued water efficiency goal guidance in Federal Agency Implementation of Water Efficiency and Management Provisions of Executive Order 13514. This...

357

Drinking Water Problems: Copper  

E-Print Network [OSTI]

High levels of copper in drinking water can cause health problems. This publication explains the effects of copper in water and methods of removing it. 4 pp....

Dozier, Monty; McFarland, Mark L.; Lesikar, Bruce J.

2006-01-25T23:59:59.000Z

358

It's The Fluids SEG Honorary Lecture  

E-Print Network [OSTI]

.7 A #12;Water + Ions (usually NaCl) ClNa Dickerson et al., 1970 #12;Heavy Oil Water Wet silicaSilica Heavy information please visit: #12;·WATER and BRINE (BRINE = H2O + Salt) ·HYDROCARBONS Oil Gas TYPES of PORE FLUIDS = Porosity = Density sat = 0 (1- ) + f Density: #12;·WATER and BRINE (BRINE = H2O + Salt) ·HYDROCARBONS Oil

359

Water-heating dehumidifier  

DOE Patents [OSTI]

A water-heating dehumidifier includes a refrigerant loop including a compressor, at least one condenser, an expansion device and an evaporator including an evaporator fan. The condenser includes a water inlet and a water outlet for flowing water therethrough or proximate thereto, or is affixed to the tank or immersed into the tank to effect water heating without flowing water. The immersed condenser design includes a self-insulated capillary tube expansion device for simplicity and high efficiency. In a water heating mode air is drawn by the evaporator fan across the evaporator to produce cooled and dehumidified air and heat taken from the air is absorbed by the refrigerant at the evaporator and is pumped to the condenser, where water is heated. When the tank of water heater is full of hot water or a humidistat set point is reached, the water-heating dehumidifier can switch to run as a dehumidifier.

Tomlinson, John J. (Knoxville, TN)

2006-04-18T23:59:59.000Z

360

6, 70757091, 2006 precipitation in brine  

E-Print Network [OSTI]

be produced on the frozen surface of sea ice (Adams et al., 2002), this source would quickly be exhausted in polar regions over recently formed sea ice, we can model successfully the transformation of inert sea of already activated bromine (Borken, 1996; Sander et al., 1997), or artificially acidified the model aerosol

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Development Operations Hypersaline Geothermal Brine Utilization...  

Open Energy Info (EERE)

California Abstract NA Authors Whitescarver and Olin D. Published U.S. Department of Energy, 1984 Report Number NA DOI Not Provided Check for DOI availability: http:...

362

CHEMISTRY OF SILICA IN CERRO PRIETO BRINES  

E-Print Network [OSTI]

lfuen operated w:l.thout sludge recirculation, this pilotcould lead to problems with sludge accumulation there. Ifby recirculation of part of the sludge coming out of the

Weres, O.

2012-01-01T23:59:59.000Z

363

Chemistry of Silica in Cerro Prieto Brines  

E-Print Network [OSTI]

1975). When operated without sludge r e c i r c u l a t i ot o c o l l o i d a l silica. sludge accumulation there. thel a t i o n of part of the sludge coming out of The l a r g

Weres, Oleh

2012-01-01T23:59:59.000Z

364

Chemistry of Silica in Cerro Prieto Brines  

E-Print Network [OSTI]

1975). When operated without sludge r e c i r c u l a t i ot o c o l l o i d a l silica. sludge accumulation there. thel a t i o n of part of the sludge coming out of The l a r g

Weres, O.

2010-01-01T23:59:59.000Z

365

Batteries from Brine | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: Top Five EERE BlogAttachmentFlash2011-21FAQs BEDES|of Energy

366

Development Operations Hypersaline Geothermal Brine Utilization Imperial  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6 No revision has Type Term Title AuthorEnergy

367

Subsurface Drip Irrigation As a Methold to Beneficiallly Use Coalbed Methane Produced Water: Initial Impacts to Groundwater, Soil Water, and Surface Water  

SciTech Connect (OSTI)

Coalbed methane (CBM) currently accounts for >8% of US natural gas production. Compared to traditional sources, CBM co-produces large volumes of water. Of particular interest is CBM development in the Powder River Basin of Wyoming and Montana, the 2nd largest CBM production field in the US, where CBM produced waters exhibit low to moderate TDS and relatively high sodium-adsorption ratio (SAR) that could potentially impact the surface environment. Subsurface drip irrigation (SDI) is an emerging technology for beneficial use of pre-treated CBM waters (injectate) which are emitted into the root zone of an agricultural field to aid in irrigation. The method is designed to minimize environmental impacts by storing potentially detrimental salts in the vadose zone. Research objectives include tracking the transport and fate of the water and salts from the injected CBM produced waters at an SDI site on an alluvial terrace, adjacent to the Powder River, Johnson County, Wyoming. This research utilizes soil science, geochemical, and geophysical methods. Initial results from pre-SDI data collection and the first 6-months of post-SDI operation will be presented. Substantial ranges in conductivity (2732-9830 {micro}S/cm) and dominant cation chemistry (Ca-SO{sub 4} to Na-SO{sub 4}) have been identified in pre-SDI analyses of groundwater samples from the site. Ratios of average composition of local ground water to injectate demonstrate that the injectate contains lower concentrations of most constituents except for Cr, Zn, and Tl (all below national water quality standards) but exhibits a higher SAR. Composition of soil water varies markedly with depth and between sites, suggesting large impacts from local controls, including ion exchange and equilibrium with gypsum and carbonates. Changes in chemical composition and specific conductivity along surface water transects adjacent to the site are minimal, suggesting that discharge to the Powder River from groundwater underlying the SDI fields is negligible. Findings from this project provide a critical understanding of water and salt dynamics associated with SDI systems using CBM produced water. The information obtained can be used to improve SDI and other CBM produced water use/disposal technologies in order to minimize adverse impacts.

Engle, M.A.: Bern, C: Healy, R: Sams, J: Zupancic, J.: Schroeder, K.

2009-10-18T23:59:59.000Z

368

Arkansas Water Resources Center  

E-Print Network [OSTI]

, effectiveness of best management practices and trends in water quality. SCOPE This report is for continued water Bridge site is a full storm-water sampling station with auto- sampler and data sonde. The Portland site. Garret Bridge site. 2 #12;Figure 2 Portland site. METHODS The Garrett Bridge site is a full storm-water

Soerens, Thomas

369

Water Waves Roger Grimshaw  

E-Print Network [OSTI]

,2) provide a kinematic description of water waves, which to this point means that the conditionsWater Waves Roger Grimshaw May 7, 2003 Abstract A short review of the theory of weakly nonlinear water waves, prepared for the forthcoming Encyclopedia of Nonlinear Science 1 Introduction Water waves

370

Vadose zone water fluxmeter  

DOE Patents [OSTI]

A Vadose Zone Water Fluxmeter (WFM) or Direct Measurement WFM provides direct measurement of unsaturated water flow in the vadose zone. The fluxmeter is a cylindrical device that fits in a borehole or can be installed near the surface, or in pits, or in pile structures. The fluxmeter is primarily a combination of tensiometers and a porous element or plate in a water cell that is used for water injection or extraction under field conditions. The same water pressure measured outside and inside of the soil sheltered by the lower cylinder of the fluxmeter indicates that the water flux through the lower cylinder is similar to the water flux in the surrounding soil. The fluxmeter provides direct measurement of the water flow rate in the unsaturated soils and then determines the water flux, i.e. the water flow rate per unit area.

Faybishenko, Boris A.

2005-10-25T23:59:59.000Z

371

Environmental assessment of ground water compliance activities at the Uranium Mill Tailings Site, Spook, Wyoming. Revision 0  

SciTech Connect (OSTI)

This document is an environmental assessment of the Spook, Wyoming, Uranium Mill Tailings Remedial Action (UMTRA) Project site. It analyzes the impacts of the U.S. Department of Energy (DOE) proposed action for ground water compliance. The proposed action is to comply with the U.S. Environmental Protection Agency (EPA) standards for the UMTRA Project sites (40 CFR Part 192) by meeting supplemental standards based on the limited use ground water at the Spook site. This proposed action would not require site activities, including ground water monitoring, characterization, or institutional controls. Ground water in the uppermost aquifer was contaminated by uranium processing activities at the Spook site, which is in Converse County, approximately 48 miles (mi) (77 kilometers [km]) northeast of Casper, Wyoming. Constituents from the site infiltrated and migrated into the uppermost aquifer, forming a plume that extends approximately 2500 feet (ft) (800 meters [m]) downgradient from the site. The principal site-related hazardous constituents in this plume are uranium, selenium, and nitrate. Background ground water in the uppermost aquifer at the site is considered limited use. It is neither a current nor a potential source of drinking water because of widespread, ambient contamination that cannot be cleaned up using treatment methods reasonably employed in public water supply systems (40 CFR {section} 192.11 (e)). Background ground water quality also is poor due to first, naturally occurring conditions (natural uranium mineralization associated with an alteration front), and second, the effects of widespread human activity not related to uranium milling operations (uranium exploration and mining activities). There are no known exposure pathways to humans, animals, or plants from the contaminated ground water in the uppermost aquifer because it does not discharge to lower aquifers, to the surface, or to surface water.

NONE

1996-03-01T23:59:59.000Z

372

The Separation of Tritiated Water Using Supported Polyphosphazene Membranes  

SciTech Connect (OSTI)

Carboxylated poly(diaryloxy)phosphazene was examined as the active constituent of the composite membranes to separate tritiated water (HTO) from light water. These membranes were tested with water containing 10 800 pCi/l and 3 mu-Ci/l of tritiated water, respectively, under cross-flow filtration conditions. Reductions in the permeate of nearly 30% HTO were observed with these tritium concentrations. Low temperature (5 degrees C), low pressure (137.9-551.6 kPa), and high pH (near 10 or above) were required to obtain such reductions (rejection). Salt species (Na2SO4, CaCl2 and CaSO4) at various concentrations and pressures, within a 137.9-551.6 kPa range, did not appear to affect the HTO separation efficiency. Mass balances performed during these experiments indicate an unaccounted small amount of tritium (0.5-2.2%). Sorption experiments with the polyphosphazene suggest that the membrane does not operate by an ion exchange mechanism; that is, tritium accumulation within the membrane.

Duncan, James B. (CHEMMET LTD); Nelson, David A. (BATTELLE (PACIFIC NW LAB))

1998-12-01T23:59:59.000Z

373

Reactor water cleanup system  

DOE Patents [OSTI]

A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling. 1 figure.

Gluntz, D.M.; Taft, W.E.

1994-12-20T23:59:59.000Z

374

Reactor water cleanup system  

DOE Patents [OSTI]

A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling.

Gluntz, Douglas M. (San Jose, CA); Taft, William E. (Los Gatos, CA)

1994-01-01T23:59:59.000Z

375

Water resources data, Kentucky. Water year 1991  

SciTech Connect (OSTI)

Water resources data for the 1991 water year for Kentucky consist of records of stage, discharge, and water quality of streams and lakes; and water-levels of wells. This report includes daily discharge records for 115 stream-gaging stations. It also includes water-quality data for 38 stations sampled at regular intervals. Also published are 13 daily temperature and 8 specific conductance records, and 85 miscellaneous temperature and specific conductance determinations for the gaging stations. Suspended-sediment data for 12 stations (of which 5 are daily) are also published. Ground-water levels are published for 23 recording and 117 partial sites. Precipitation data at a regular interval is published for 1 site. Additional water data were collected at various sites not involved in the systematic data-collection program and are published as miscellaneous measurement and analyses. These data represent that part of the National Water Data System operated by the US Geological Survey and cooperation State and Federal agencies in Kentucky.

McClain, D.L.; Byrd, F.D.; Brown, A.C.

1991-12-31T23:59:59.000Z

376

WATER RESOURCES NEBRASKA WATER RESOURCES RESEARCH INSTITUTE  

E-Print Network [OSTI]

WATER RESOURCES NEBRASKA WATER RESOURCES RESEARCH INSTITUTE 212 AGRICULTURAL ENGINEERING BUILDING.m~ Mondays, 206 Agricultural Engihee~1n~Build1ng January 2~ January 31' Februar;"'7 February 14 " February 21 Irrigation Development and Implications Recreational Potential Economic Importance of the Sandhills Film

Nebraska-Lincoln, University of

377

NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS  

SciTech Connect (OSTI)

The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information, (2) a web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries, (3) a fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water, and (4) a corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project has been focused on creating the water quality databases for produced water and surface water, along with collection of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 4000 entries for southeast New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the accuracy and speed of water quality data entry. (4) Acquisition of ground water data from the New Mexico State Engineer's office, including chloride content and TDS (Total Dissolved Solids) for over 30,000 data points in southeast New Mexico. (5) Creation of a web-based scale prediction tool, again with a web-based interface, that uses two common scaling indices (Stiff-Davis and Oddo-Thomson) to predict the likelihood of scaling. This prediction tool can either run from user input data, or the user can select samples from the water analysis database. (6) Creation of depth-to-groundwater maps for the study area. (7) Analysis of water quality data by formation. (8) Continuation of efforts to collect produced water quality information from operators in the southeast New Mexico area. (9) Qualitative assessment of produced water from various formations regarding corrosivity. (10) Efforts at corrosion education in the region through operator visits. Future work on this project will include: (11) Development of an integrated web and GIS interface for all the information collected in this effort. (12) Continued development of a fuzzy logic spill risk assessment tool that was initially developed prior to this project. Improvements will include addition of parameters found to be significant in determining the impact of a brine spill at a specific site. (13) Cleanup and integration of water quality databases. (14) Compilation of both hard copy and online corrosion toolkit material.

Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung; Naomi Davidson; Ajeet Kumar Reddy; Mingzhen Wei

2003-04-01T23:59:59.000Z

378

Endothelial cell permeability to water and antipyrine  

SciTech Connect (OSTI)

The endothelium provides a structural barrier between plasma constituents and the tissues. The permeability characteristics of the the endothelial cells regulate the transcellular movement of materials across this barrier while other movement is paracellular. In this study the permeability of the endothelial cells to tritiated water (/sup 3/HHO) and /sup 14/C-labeled antipyrine (AP) was investigated. The cells were isolated non-enzymatically from calf pulmonary artery and were maintained in culture and used between the seventh and fifteenth passage. The cells were removed from the T-flasks with a rubber policeman, titurated with a 22g needle and centrifuged. The cells were mixed with an extracellular marker, drawn into polyethylene tubing and packed by centrifugation for use in the linear diffusion technique. All measurements were made at 37 C. The diffusion coefficients for /sup 3/HHO through the packed cells (D), the intracellular material (D/sub 2/), and the extracellular material (D/sub 1/) were 0.682, 0.932 and 2.45 x 10/sup -5/ cm/sup 2/ s/sup -1/ and for AP were 0.273, 0.355 and 1.13 x 10/sup -5/ cm/sup 2/ s/sup -1/ respectively. The permeability coefficient calculated by the series-parallel pathway model for /sup 3/HHO was higher than that for AP and for both /sup 3/HHO and AP were lower than those calculated for isolated lung cells and erythrocytes.

Garrick, R.A.

1986-03-05T23:59:59.000Z

379

NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS  

SciTech Connect (OSTI)

The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) Databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information. (2) A web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries. (3) A fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water. (4) A corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project was focused on creating the water quality databases for produced water and surface water, along with collecting of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 7000 entries for New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the accuracy and speed of water quality data entry. (4) Acquisition of ground water data from the New Mexico State Engineer's office, including chloride content and TDS (Total Dissolved Solids) for over 30,000 data points in southeast New Mexico. (5) Creation of a web-based scale prediction tool, again with a web-based interface, that uses two common scaling indices to predict the likelihood of scaling. This prediction tool can either run from user input data, or the user can select samples from the water analysis database. (6) Creation of depth-to-groundwater maps for the study area. (7) Analysis of water quality data by formation. (8) Continuation of efforts to collect produced water quality information from operators in the southeast New Mexico area. (9) Qualitative assessment of produced water from various formations regarding corrosivity. (10) Efforts at corrosion education in the region through operator visits. Future work on this project will include: (1) Development of an integrated web and GIS interface for all the information collected in this effort. (2) Continued development of a fuzzy logic spill risk assessment tool that was initially developed prior to this project. Improvements will include addition of parameters found to be significant in determining the impact of a brine spill at a specific site. (3) Compilation of both hard copy and online corrosion toolkit material.

Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung

2003-09-24T23:59:59.000Z

380

Federal Water Use Indices  

Broader source: Energy.gov [DOE]

FEMP provides water use indices as a guide for Federal agencies. Note that each is a rough estimate of water usage at different types of sites. Your site may vary considerably.

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Drinking Water Problems: Benzene  

E-Print Network [OSTI]

Drinking water in Texas sometimes contains potentially harmful chemicals, including benzene. Well owners can learn how to treat their well water to remove these chemicals. 4 pages, 3 images...

Dozier, Monty; Lesikar, Bruce J.

2009-04-16T23:59:59.000Z

382

General Water Quality (Oklahoma)  

Broader source: Energy.gov [DOE]

The purpose of this water quality rule is to protect, maintain and improve the quality of waters of the State. Any applicant for a federal license, permit or project to conduct any activity...

383

Water Pollution Control (Indiana)  

Broader source: Energy.gov [DOE]

The Indiana Department of Environmental Management and the Water Pollution Control Board are tasked with the prevention of pollution in the waters of the state. The Board may adopt rules and...

384

Outdoor Water Conservation  

E-Print Network [OSTI]

L-438 Outdoor Water Conservation The City of OKLAHOMA CITY UTILITIES DEPARTMENT Oklahoma.JustinQ.Moss 1 #12;2 SEVEN PRINCIPLES FOR CREATING A WATER CONSERVING LANDSCAPE 1. GOOD LANDSCAPE PLANNING

Balasundaram, Balabhaskar "Baski"

385

A gathering of water  

E-Print Network [OSTI]

The act of immersion is a powerful catalyst for the affirmation or transformation of identity. How we place ourselves in water expresses cultural valuations of our bodies, water, and social relations, as well as categories ...

Horowitz, Naomi Leah, 1970-

2005-01-01T23:59:59.000Z

386

Drinking Water Problems: Perchlorate  

E-Print Network [OSTI]

Perchlorate is a potential contaminate of well water that can have harmful effects on human health. Methods of removing perchlorate from water are described and illustrated. There is information to help well owners select and maintain treatment...

Dozier, Monty; Melton, Rebecca; Hare, Michael; Porter, Dana; Lesikar, Bruce J.

2005-11-18T23:59:59.000Z

387

State Water Quality (Virginia)  

Broader source: Energy.gov [DOE]

It is the policy of the Commonwealth of Virginia to: (1) protect existing high quality state waters and restore the quality of all other state waters to permit all reasonable public uses and...

388

Water Quality (Oklahoma)  

Broader source: Energy.gov [DOE]

The Water Quality Act establishes cumulative remedies to prevent, abate and control the pollution of the waters of the state. The act establishes responsibilities of the Oklahoma Department of...

389

California's Water Energy Relationship  

E-Print Network [OSTI]

.........................................................................................................................7 THE ENERGY INTENSITY OF THE WATER USE CYCLE.........................................................................................9 ENERGY INTENSITY IN NORTHERN AND SOUTHERN CALIFORNIA1 CALIFORNIA ENERGY COMMISSION California's Water ­ Energy Relationship Prepared in Support

390

Walking on water  

E-Print Network [OSTI]

The ingenious methods employed by insects and spiders to move across a water surface rely on microphysics that is of little use to larger water walkers but of considerable interest to the microfluidics community.

Bush, John W. M.

391

Water Conservation Tips  

E-Print Network [OSTI]

Spinach Beets Bush, Pole Beans Carrots Cucumbers Eggplant Peas Peppers Summer Squash Pumpkins Tomatoes Watermelon Winter Squash Water

Brown, Martha

2008-01-01T23:59:59.000Z

392

Be Water Smart  

E-Print Network [OSTI]

of native or non-invasive adapted trees, shrubs, grasses and flowers that can tolerate temporary wet conditions. A layer of mulch prevents weed growth and aids in filtration. These low spots fill with water during periods of heavy rain, helping...W aterSmart, a water conservation program, uses a unique approach to protect and conserve water quality and quantity in upper Texas Gulf Coast urban landscapes. Part of the Texas Coastal Watershed Program (TCWP), WaterSmart is creating rain...

Swyden, Courtney

2006-01-01T23:59:59.000Z

393

Water and Energy Interactions  

E-Print Network [OSTI]

birds, the overall water requirements are minimal and exist only for washing the blades of wind turbines

McMahon, James E.

2013-01-01T23:59:59.000Z

394

Innovative Water Reuse  

E-Print Network [OSTI]

management 1.Rain gardens 2.Porous pavement 3.Green roofs Hydrologic Cycle ISSUES ? Water Conservation ? Is there enough? ? Can conservation make a difference? ? Water Quality ? Contamination/pollution due to runoff Eagle...-drought conditions ? A breakdown of energy use by department shows that the Austin Water Utility uses 60% of the total amount of energy used by the City of Austin. What Can We Do? ? Water Conservation ? Indoors ? Bathrooms ? Kitchen ? Showers ? Laundry...

Jaber, F. H.

2011-01-01T23:59:59.000Z

395

Water and Energy Interactions  

E-Print Network [OSTI]

Hydroelectricity for agriculture and hydroelectricity. Large volumes of waterElectricity Production Hydroelectricity The most common type

McMahon, James E.

2013-01-01T23:59:59.000Z

396

Water Management Best Practices  

E-Print Network [OSTI]

and Energy Star Programs ? www.epa.gov/watersense www.energystar.gov ? Conserve Florida Water Clearinghouse ? http://www.conservefloridawater.org/ ? Arizona Department of Water Resources ? www.azwater.gov/conservation The True Cost of Water... Future Demands Municipal Manufacturing Mining Steam Electric Agriculture New Codes & Standards Green Certification& Labeling Programs ? Green Restaurants, Hotels, etc. ? Green Guide for Health Care ? LEED ? GBI ? EPA Water Sense ? EPA...

Hoffman, W.

2011-01-01T23:59:59.000Z

397

Water Transport Within the STack: Water Transport Exploratory...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Within the STack: Water Transport Exploratory Studies Water Transport Within the STack: Water Transport Exploratory Studies Part of a 100 million fuel cell award announced by DOE...

398

Carbon and Water Resource Management for Water Distribution Systems  

E-Print Network [OSTI]

the embodied energy in drinking water supply systems: a caselosses to 5% of total drinking water supply for threeResearch Council. Drinking Water Distribution Systems:

Hendrickson, Thomas Peter

2013-01-01T23:59:59.000Z

399

Water treatment method  

DOE Patents [OSTI]

A method for reducing the concentration of any undesirable metals dissolved in contaminated water, such as waste water. The method involves uniformly reacting the contaminated water with an excess amount of solid particulate calcium sulfite to insolubilize the undesirable metal ions, followed by removal thereof and of the unreacted calcium sulfite.

Martin, Frank S. (Farmersville, OH); Silver, Gary L. (Centerville, OH)

1991-04-30T23:59:59.000Z

400

Energy-Water Nexus  

SciTech Connect (OSTI)

Conclusions of this presentation are: (1) energy and water are interconnected; (2) new energy sources will place increased demands on water supplies; (3) existing energy sources will be subjected to increasing restrictions on their water use; and (4) integrated decision support tools will need to be developed to help policy makers decide which policies and advanced technologies can address these issues.

Horak, W.

2010-07-26T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Arkansas Water Resources Center  

E-Print Network [OSTI]

of best management practices and trends in water quality. SCOPE This project is a cooperative effort Bridge, AR and near Portland, AR. The Garret Bridge site is a full storm-water sampling station with auto;METHODS The Garret Bridge site is a full storm-water sampling station. It uses an automatic sampler

Soerens, Thomas

402

Water treatment method  

DOE Patents [OSTI]

A method is described for reducing the concentration of any undesirable metals dissolved in contaminated water, such as waste water. The method involves uniformly reacting the contaminated water with an excess amount of solid particulate calcium sulfite to insolubilize the undesirable metal ions, followed by removal thereof and of the unreacted calcium sulfite.

Martin, F.S.; Silver, G.L.

1991-04-30T23:59:59.000Z

403

PROCEEDINGS Stockholm Water Symposium  

E-Print Network [OSTI]

-0127 The Joint Conference 7th Stockholm Water Symposium1 3rd InternationalConference a11 tlie Enviro~~mnent;~l Ma.A.G.M, a Systematic Approach to Lake Water Pollution Assessment, - Eindhoven: University of Technology, Eindhoven Assessment, Water Pollution in the Catchment of Lake Victoria, Dares Salaam, Tanzania, August, 1994

Boynton, Walter R.

404

Water Resources Milind Sohoni  

E-Print Network [OSTI]

-photosynthesis, energy transfer in animals, and so on. Life as we know it is water-centric (and organic carbon 20, 2012 6 / 17 #12;Water availability Total renewable (defined using the water cycle) per-capita, per year. Country cu. m. Congo 275,000 Canada 94,000 Brazil 48,000 Mongolia, Indonesia 13,000 Japan

Sohoni, Milind

405

STORM WATER Residential  

E-Print Network [OSTI]

STORM WATER QUALITY HOTLINE UCSC Residential Car Washing http THAT MAY CAUSE ENVIRONMENTAL HARM TO THE STORM WATER QUALITY HOTLINE: (831) 459-2553. LIKE US ON FACEBOOK AT UCSC STORM WATER MANAGEMENT PROGRAM! DID YOU KNOW? PRACTICAL SOLUTIONS > USE A COMMERCIAL CAR WASH

California at Santa Cruz, University of

406

Summary Report on CO{sub 2} Geologic Sequestration & Water Resources Workshop  

SciTech Connect (OSTI)

The United States Environmental Protection Agency (EPA) and Lawrence Berkeley National Laboratory (LBNL) jointly hosted a workshop on “CO{sub 2} Geologic Sequestration and Water Resources” in Berkeley, June 1–2, 2011. The focus of the workshop was to evaluate R&D needs related to geological storage of CO{sub 2} and potential impacts on water resources. The objectives were to assess the current status of R&D, to identify key knowledge gaps, and to define specific research areas with relevance to EPA’s mission. About 70 experts from EPA, the DOE National Laboratories, industry, and academia came to Berkeley for two days of intensive discussions. Participants were split into four breakout session groups organized around the following themes: Water Quality and Impact Assessment/Risk Prediction; Modeling and Mapping of Area of Potential Impact; Monitoring and Mitigation; Wells as Leakage Pathways. In each breakout group, participants identified and addressed several key science issues. All groups developed lists of specific research needs; some groups prioritized them, others developed short-term vs. long-term recommendations for research directions. Several crosscutting issues came up. Most participants agreed that the risk of CO{sub 2} leakage from sequestration sites that are properly selected and monitored is expected to be low. However, it also became clear that more work needs to be done to be able to predict and detect potential environmental impacts of CO{sub 2} storage in cases where the storage formation may not provide for perfect containment and leakage of CO{sub 2}–brine might occur.

Varadharajan, C.; Birkholzer, J.; Kraemer, S.; Porse, S.; Carroll, S.; Wilkin, R.; Maxwell, R.; Bachu, S.; Havorka, S.; Daley, T.; Digiulio, D.; Carey, W.; Strasizar, B.; Huerta, N.; Gasda, S.; Crow, W.

2012-02-15T23:59:59.000Z

407

Water Quality Control Act (Tennessee)  

Broader source: Energy.gov [DOE]

The Water Quality Control Act (WQCA) establishes the water pollution control program. The WQCA identifies the responsibilities and extent of authority for the Commissioner of the Water Quality...

408

Ground Water Management Act (Virginia)  

Broader source: Energy.gov [DOE]

Under the Ground Water Management Act of 1992, Virginia manages ground water through a program regulating the withdrawals in certain areas called Ground Water Management Areas (GWMA). Currently,...

409

Planning Water Use in California  

E-Print Network [OSTI]

the University of Maryland Water Policy Collaborative, 2006.FURTH ER READ ING California Department of Water Resources.California Water Plan Update 2005: A Framework for Action.

Eisenstein, William; Kondolf, G. Mathias

2008-01-01T23:59:59.000Z

410

Year Project Title USGS contact(s) Published paper, data source,  

E-Print Network [OSTI]

information Keywords 1 2003-present Delineation of brine contamination in and near the East Poplar oil field_poplar/index.html Project assesses brine contamination to the shallow aquifers and surface water. Energy Development, Williston Basin, Brine contamination, Groundwater, Surface Water, East Poplar oil field, Fort Peck Indian

Torgersen, Christian

411

FOOD PRESERVATION SERIES hOW TO STORE  

E-Print Network [OSTI]

from raw meat so that meat juices do not contaminate it. Wash hands before and after handling fresh-green or wilted. Prepare the brine by adding 4 teaspoons salt to 1 gallon water. Immerse broccoli in the brine

412

Geothermal Water Use: Life Cycle Water Consumption, Water Resource Assessment, and Water Policy Framework  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

This report examines life cycle water consumption for various geothermal technologies to better understand factors that affect water consumption across the life cycle (e.g., power plant cooling, belowground fluid losses) and to assess the potential water challenges that future geothermal power generation projects may face. Previous reports in this series quantified the life cycle freshwater requirements of geothermal power-generating systems, explored operational and environmental concerns related to the geochemical composition of geothermal fluids, and assessed future water demand by geothermal power plants according to growth projections for the industry. This report seeks to extend those analyses by including EGS flash, both as part of the life cycle analysis and water resource assessment. A regional water resource assessment based upon the life cycle results is also presented. Finally, the legal framework of water with respect to geothermal resources in the states with active geothermal development is also analyzed.

Schroeder, Jenna N.

413

Geothermal Water Use: Life Cycle Water Consumption, Water Resource Assessment, and Water Policy Framework  

SciTech Connect (OSTI)

This report examines life cycle water consumption for various geothermal technologies to better understand factors that affect water consumption across the life cycle (e.g., power plant cooling, belowground fluid losses) and to assess the potential water challenges that future geothermal power generation projects may face. Previous reports in this series quantified the life cycle freshwater requirements of geothermal power-generating systems, explored operational and environmental concerns related to the geochemical composition of geothermal fluids, and assessed future water demand by geothermal power plants according to growth projections for the industry. This report seeks to extend those analyses by including EGS flash, both as part of the life cycle analysis and water resource assessment. A regional water resource assessment based upon the life cycle results is also presented. Finally, the legal framework of water with respect to geothermal resources in the states with active geothermal development is also analyzed.

Schroeder, Jenna N.

2014-06-10T23:59:59.000Z

414

Using solubility and Henry`s law constant data for ketones in water  

SciTech Connect (OSTI)

When a chemical spill occurs in water, the extent of chemical contamination is determined by the chemical`s solubility in the water. If contaminated water comes into contact with air, such as in a pond or a storage vessel, the contaminant`s emissions into the air can be determined based upon Henry`s law constant for that particular constituent. A high Henry`s law constant value translates into a greater emissions level. The engineering design and operation of strippers to remove contaminants from water require data for both water solubility and Henry`s law constant. A new correlation developed by researchers at Lamar University provides reliable values down to very, very low concentrations for the solubility of ketones in water. The correlation is based on the boiling point temperature of the ketone and can be used for engineering studies involving health, safety and environmental considerations. Results for water solubility and Henry`s law constant are provided here for a wide variety of ketones. Representative values are about 249,000 parts per million (ppm) per weight (wt) for methyl ethyl ketone (C{sub 4}H{sub 8}O) and 360 ppm/wt for 5-nonanone (C{sub 9}H{sub 18}O).

Yaws, C.L.; Sheth, S.D.; Han, M. [Lamar Univ., Beaumont, TX (United States)

1998-02-01T23:59:59.000Z

415

Water Quality and Quantity Concerns Population growth, increasing water demands,  

E-Print Network [OSTI]

systems, private water well screening, and soil nutrient management. Water conservation programs of Agri, efficient use, sustainable practices, watershed management and environmental stewardship. Through 660 and utilizing water-conservation practices will be essential to sustain the state's water supply

416

CEE 692 ENVIRONMENTAL AND WATER RESOURCES ENGINEERING SEMINAR SPRING 2011  

E-Print Network [OSTI]

April 22 Removal of Contaminants from Waste Ion Exchange Regenerant Brine Reaction of secondary effluent Park Associate Professor, Konkuk University April 8 Wastewater Reuse & Trace Contaminants Dr. Ben April 29 Wachusett Reservoir Contaminant Spill Modeling Using CE-QUAL W2 Remote Sensing Models

Mountziaris, T. J.

417

Water Data Report: An Annotated Bibliography  

E-Print Network [OSTI]

Table 5: Public supply water withdrawals, 2000. water withdrawals, 2000. water withdrawals, 2000.

Dunham Whitehead, Camilla; Melody, Moya

2007-01-01T23:59:59.000Z

418

SA Water Centre for Water Management and Reuse  

E-Print Network [OSTI]

SA Water Centre for Water Management and Reuse #12;' Our Mission The SA Water Centre for Water Management and Reuse aims to advance the science and technology of sustainable water management through fundamental and applied research. Our Vision To be Australia's leading research centre for water reuse

Li, Jiuyong "John"

419

SA Water Centre for Water Management and Reuse  

E-Print Network [OSTI]

SA Water Centre for Water Management and Reuse #12;2 The SA Water Centre for Water Management and Reuse was established in 2004 as a joint venture between the South Australian Water Corporation and the University of South Australia (UniSA), adding significant expertise to the water research capability in South

Li, Jiuyong "John"

420

WATER RESOURCES PLANNING ACT Q:\\COMP\\WATER1\\WRPA  

E-Print Network [OSTI]

103 WATER RESOURCES PLANNING ACT Q:\\COMP\\WATER1\\WRPA December 29, 2000 #12;Q:\\COMP\\WATER1\\WRPA December 29, 2000 #12;105 WATER RESOURCES PLANNING ACT [As Amended Through P.L. 106­580, Dec. 29, 2000 planning of water and related land resources, through the establishment of a water resources council

US Army Corps of Engineers

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Surface Water Management Areas (Virginia)  

Broader source: Energy.gov [DOE]

This legislation establishes surface water management areas, geographically defined surface water areas in which the State Water Control Board has deemed the levels or supply of surface water to be...

422

Gas Water Heater Energy Losses  

E-Print Network [OSTI]

Input Screens SCREEN D1: WATER HEATER SPECIFICATIONS 1. Tankthe house. Supply pipe – this is the water heater inlet pipewith refills the water heater with cold water Note: The TANK

Biermayer, Peter

2012-01-01T23:59:59.000Z

423

Chemical and Isotopic Composition and Gas Concentrations of Ground Water and Surface Water from Selected Sites At and Near the Idaho National Engineering and Environmental Laboratory, Idaho, 1994-97  

SciTech Connect (OSTI)

>From May 1994 through May 1997, the US Geological Survey, in cooperation with the US Department of Energy, collected water samples from 86 wells completed in the Snake River Plain aquifer at and near the Idaho National Engineering and Environmental Laboratory. The samples were analyzed for a variety of chemical constituents including all major elements and 22 trace elements. Concentrations of scandium, yttrium, and the lanthanide series were measured in samples from 11 wells and 1 hot spring. The data will be used to determine the fraction of young water in the ground water. The fraction of young water must be known to calculate the ages of ground water using chlorofluorocarbons. The concentrations of the isotopes deuterium, oxygen-18, carbon-13, carbon-14, and tritium were measured in many ground water, surface-water and spring samples. The isotopic composition will provide clues to the origin and sources of water in the Snake River Plain aquifer. Concentrations ! of helium-3 , helium-4, total helium, and neon were measured in most groundwater samples, and the results will be used to determine the recharge temperature, and to date the ground waters.

E. Busenberg; L. N. Plummer; M. W. Doughten; P. K. Widman; R. C. Bartholomay (USGS)

2000-05-30T23:59:59.000Z

424

Mitigation, Adaptation, Uncertainty -- Growing Water  

E-Print Network [OSTI]

system for harvesting and returning clean water to Lakeharvesting for landscape and species health, and surface water and

Felsen, Martin; Dunn, Sarah

2008-01-01T23:59:59.000Z

425

(Data in metric tons of yttrium oxide (Y2O3) content, unless noted) Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network [OSTI]

Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

426

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnsite  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnäsite at Mountain Pass, CA, but was not recovered as a separate element during processing. Bastnäsite, a rare-earth Number Normal Trade Relations 12/31/02 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth

427

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network [OSTI]

Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth.20.0000 Free Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805

428

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite,  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed

429

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral  

E-Print Network [OSTI]

Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5

430

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the  

E-Print Network [OSTI]

Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth/31/96 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

431

(Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite,  

E-Print Network [OSTI]

Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth/31/98 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium

432

(Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite  

E-Print Network [OSTI]

Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite at Mountain Pass, CA, but was not recovered as a separate element during processing. Bastnasite, a rare-earth Number Normal Trade Relations 12/31/01 Thorium ores and concentrates (monazite) 2612.20.0000 Free. Rare-earth

433

Arsenic removal from water  

DOE Patents [OSTI]

Methods for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical methods for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A method for continuous removal of arsenic from water is provided. Also provided is a method for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

Moore, Robert C. (Edgewood, NM); Anderson, D. Richard (Albuquerque, NM)

2007-07-24T23:59:59.000Z

434

Selecting a new water heater  

SciTech Connect (OSTI)

This fact sheet describes the types of water heaters available (storage water heaters, demand water heaters, heat pump water heaters, tankless coil and indirect water heaters, and solar water heaters). The criteria for selection are discussed. These are capacity, efficiency rating, and cost. A resource list is provided for further information.

NONE

1995-03-01T23:59:59.000Z

435

The Mystery of Water  

SciTech Connect (OSTI)

Water is essential for our existence on this planet - critical to countless physical, biological, geological and chemical processes - it has defied scientific understanding. Exhibiting peculiar properties such as increased density upon melting and high surface tension, water is one of the most intriguing problems in condensed matter and chemical physics. Current research at SSRL, however, is illuminating the nature of H-bonding, presenting exciting new avenues of research and challenging existing models of water's structure.

Nilsson, Anders

2005-11-21T23:59:59.000Z

436

Drinking Water Problems: MTBE  

E-Print Network [OSTI]

. This compound belongs to a chemical family of fuel oxygenates that enhance gaso- line combustion by increasing oxygen available for the process. Added to gasoline, MTBE has reduced carbon monoxide and ozone emissions by promoting more complete burning.... Texas follows the EPA drinking water advisory of 20 to 40 micrograms per liter. How can MTBE be Removed from Well Water? MTBE requires a specific treatment process for removal from water. Well owners can use granular activated carbon or charcoal...

Dozier, Monty; Lesikar, Bruce J.

2008-08-28T23:59:59.000Z

437

Water purification in Borexino  

SciTech Connect (OSTI)

Astroparticle Physics and Underground experiments searching for rare nuclear events, need high purity materials to act as detectors or detector shielding. Water has the advantage of being cheap, dense and easily available. Most of all, water can be purified to the goal of obatining a high level of radiopurity. Water Purification can be achieved by means of a combination of processes, including filtration, reverse osmosis, deionization and gas stripping. The Water Purification System for the Borexino experiment, will be described together with its main performances.

Giammarchi, M. [Infn Milano (Italy)] [Infn Milano (Italy); Balata, M.; Ioannucci, L.; Nisi, S. [Laboratori Nazionali del Gran Sasso (Italy)] [Laboratori Nazionali del Gran Sasso (Italy); Goretti, A.; Ianni, A. [Princeton University (United States)] [Princeton University (United States); Miramonti, L. [Dip. di Fisica dell'Universitŕ di Milano e Infn (Italy)] [Dip. di Fisica dell'Universitŕ di Milano e Infn (Italy)

2013-08-08T23:59:59.000Z

438

Water and Energy Interactions  

E-Print Network [OSTI]

energy intensive of the four types—consume 2,951 kWh of electricity per million gallons (3.8 million liters) of treated water

McMahon, James E.

2013-01-01T23:59:59.000Z

439

Water Conservation Best Practices  

Broader source: Energy.gov [DOE]

Federal sites across the country are incorporating water efficiency measures as part of their overall comprehensive UESC projects. As it becomes more difficult to secure internal funding for...

440

Water Pollution Fee (Michigan)  

Broader source: Energy.gov [DOE]

The Groundwater Program regulates discharge to groundwater under Part 31, Water Resources Protection, of the Natural Resources and Environmental Protection Act, 1994 PA 451 and Part 22 Rules....

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Water Pollution (Illinois)  

Broader source: Energy.gov [DOE]

This article states regulations for water quality standards, effluent standards, monitoring and reporting methods, sewer discharge criteria and information about permits. It is the purpose of...

442

Cooling water distribution system  

DOE Patents [OSTI]

A passive containment cooling system for a nuclear reactor containment vessel. Disclosed is a cooling water distribution system for introducing cooling water by gravity uniformly over the outer surface of a steel containment vessel using an interconnected series of radial guide elements, a plurality of circumferential collector elements and collector boxes to collect and feed the cooling water into distribution channels extending along the curved surface of the steel containment vessel. The cooling water is uniformly distributed over the curved surface by a plurality of weirs in the distribution channels.

Orr, Richard (Pittsburgh, PA)

1994-01-01T23:59:59.000Z

443

What's In My Water?  

E-Print Network [OSTI]

.The salts in conductivity levels are conductivity levels. allow for too much water to evaporate water are not just table high, evaluate other from the surface, or where soils are salt, but are often a individual characteristics naturally high in salts...- tive safety margin. You can have your water analyzed by a government agency or a private company. 13 Salt: an organic or inorganic com- pound that is subject to dissociation when water is added, resulting in a dis- tinct increase in specific anions...

Provin, Tony; Pitt, John L.

2003-04-21T23:59:59.000Z

444

Water and Energy Interactions  

E-Print Network [OSTI]

solar thermal production facilities are those with power towers,tower where water or molten salt is flowing to absorb the solar

McMahon, James E.

2013-01-01T23:59:59.000Z

445

Arkansas Water Resources Center  

E-Print Network [OSTI]

Involved in the Selection of Alternatives.. 7 Gasification/liquefaction with Subsequent Transportation. 7 of the Slurry Waste- water as a Function of Residence T

Soerens, Thomas

446

Effects of buoyancy source composition on multiphase plume behavior in stratification  

E-Print Network [OSTI]

Experiments are performed where a dense multiphase plume is released vertically in a salinity stratified ambient. The constituent phase composition of the initial buoyancy flux can be dense brine, particles, or a mixture ...

Chow, Aaron C. (Aaron Chunghin), 1978-

2004-01-01T23:59:59.000Z

447

Effect of various solvents on core behavior  

E-Print Network [OSTI]

-Section of Core Holder with Core 12 6. Effect of Dri-Film on Sessile Drop Ratios of Kerosene on Silica Crystals in Brine 7. Bar Graph Showing Results of Water Flood Test 8. Plot of Resistivity vs. Brine Saturation for Tests No. 1, 4, 7, 9 and 14 27 9. Plot... Resistance Measurements at Various Brine Saturations For Displacement of Brine with Kerosene 35 III. Electrical Resistance Measurements at Various Brine Saturations for Displacement of Brine with East Texas Crude-Kerosene Mixture 36 ABSTRACT Recently...

Irby, Tom L

1956-01-01T23:59:59.000Z

448

Well Owner's Guide To Water Supply  

E-Print Network [OSTI]

's groundwater and guidelines, including national drinking water standards, to test well water to insure safe drinking water in private wells. National drinking water standards and common methods of home water .....................22 Contaminants in Water........................................23 Drinking Water Guidelines

Fay, Noah

449

Climate Change Impacts for the Conterminous USA: An Integrated Assessment Part 4. Water Resources  

SciTech Connect (OSTI)

Global warming will impact the hydrologic cycle by increasing the capacity of the atmosphere to hold moisture. Anticipated impacts are generally increased evaporation at low latitudes and increased precipitation at middle and high latitudes. The impacts on specific regions will depend on changes in weather patterns and are certain to be complex. Here we apply a suite of 12 potential climate change scenarios that could occur over the next century as atmospheric CO2 concentrations reach double the pre-industrial level to the Hydrologic Unit Model of the United States (HUMUS) to simulate water supply in the conterminous United States. In Part 4 we examine the sufficiency of this water supply to meet changing demands of irrigated agriculture. General Circulation Models (GCMs) used to simulate climate disagree on whether the US as a whole and its constituent regions will receive more or less precipitation as global warming occurs. The changes in water yield driven by changes in climate will likely be most consequential in the semi-arid western parts of the country where water yield is currently scarce and the resource is intensively managed. Changes of greater than +/-50% with respect to present day water yield are projected in parts of the Midwest and Southwest US. Interannual variability is likely to increase with reduced water yield but decrease with wetter conditions.

Thomson, Allison M.; Brown, Robert A.; Rosenberg, Norman J.; Srinivasan, Ragahvan; Izaurralde, Roberto C.

2005-04-01T23:59:59.000Z

450

Analysis of water and soil from the wetlands of Upper Three Runs Creek. Volume 2A, Analytical data packages September--October 1991 sampling  

SciTech Connect (OSTI)

Shallow water and soils along Upper Three Runs Creek (UTRC) and associated wetlands between SRS Road F and Cato Road were sampled for nonradioactive and radioactive constituents. The sampling program is associated with risk evaluations being performed for various regulatory documents in these areas of the Savannah River Site (SRS). WSRC selected fifty sampling sites bordering the Mixed Waste Management Facility (MWMF), F- and H-Area Seepage Basins (FHSB), and the Sanitary Landfill (SL). The analytical results from this study provided information on the water and soil quality in UTRC and its associated wetlands. The analytical results from this investigation indicated that the primary constituents and radiological indicators detected in the shallow water and soils were tritium, gross alpha, radium 226, total radium and strontium 90. This investigation involved the collection of shallow water samples during the Fall of 1991 and the Spring of 1992 at fifty (50) sampling locations. Sampling was performed during these periods to incorporate high and low water table periods. Samples were collected from three sections along UTRC denoted as Phase I (MWMF), Phase II (FHSB) and Phase III (SL). One vibracored soil sample was also collected in each phase during the Fall of 1991. This document is compiled solely of experimental data obtained from the sampling procedures.

Haselow, L.A.; Rogers, V.A. [Westinghouse Savannah River Co., Aiken, SC (United States); Riordan, C.J. [Metcalf and Eddy, Inc. (United States); Eidson, G.W.; Herring, M.K. [Normandeau Associates, Inc. (United States)

1992-08-01T23:59:59.000Z

451

Tidal-Fluvial and Estuarine Processes in the Lower Columbia River: I. Along-channel Water Level Variations, Pacific Ocean to Bonneville Dam  

SciTech Connect (OSTI)

This two-part paper provides comprehensive time and frequency domain analyses and models of along-channel water level variations in the 234km-long Lower Columbia River and Estuary (LCRE) and documents the response of floodplain wetlands thereto. In Part I, power spectra, continuous wavelet transforms, and harmonic analyses are used to understand the influences of tides, river flow, upwelling and downwelling, and hydropower operations ("power-peaking") on the water level regime. Estuarine water levels are influenced primarily by astronomical tides and coastal processes, and secondarily by river flow. The importance of coastal and tidal influences decreases in the landward direction, and water levels are increasingly controlled by river flow variations at periods from ?1day to years. Water level records are only slightly non-stationary near the ocean, but become increasingly irregular upriver. Although astronomically forced tidal constituents decrease above the estuary, tidal fortnightly and overtide variations increase for 80-200km landward, both relative to major tidal constituents and in absolute terms.

Jay, D. A.; Leffler, K.; Diefenderfer, Heida L.; Borde, Amy B.

2014-06-07T23:59:59.000Z

452

Light hadron spectra in the constituent quark model with the Kobayashi-Kondo-Maskawa-'t Hooft effective U {sub A} (1) symmetry breaking interaction  

SciTech Connect (OSTI)

We make a critical comparison of several versions of instanton-induced interactions present in the literature, all based on ITEP group's extension to three colours and flavours of 't Hooft's effective lagrangian, with the predictions of the phenomenological Kobayashi-Kondo-Maskawa (KKM) chiral quark lagrangian. We analyze the effects of all versions of the effective U {sub A} (1) symmetry breaking interactions on light hadron spectra in the non-relativistic constituent quark model. We show that the KKMT force, when used as a residual hyperfine interaction reproduces the correct ordering of pseudoscalar and vector mesons even without explicitly taking chiral symmetry into account. Moreover, the nucleon spectra are also correctly reproduced, only the Roper resonance remains too high, albeit lower than usual, at 1660 MeV. The latter's lower than expected mass is not due to a small excitation energy, as in the Glozman-Riska (GR) model, but to a combination of colour, flavour, and spatial wave function properties that enhance the relevant matrix elements. The KKMT interaction explicitly depends on flavour and spin of the quarks, but unlike the GR flavour-spin one it has a firm footing in QCD. In the process we provide several technical advances, in particular we show the first explicit derivation of the three-body Fierz transformation and apply it to the KKM interaction. We also discuss the ambiguities associated with the colour degree of freedom.

Dmitrasinovic, V. [Vinca Institute of Nuclear Sciences, P.O. Box 522, 11001 Belgrade (Serbia and Montenegro) and Research Center for Nuclear Physics, Osaka University, Ibaraki, Osaka 567-0047 (Japan)]. E-mail: dmitrasin@yahoo.com; Toki, H. [Vinca Institute of Nuclear Sciences, P.O. Box 522, 11001 Belgrade (Serbia and Montenegro); Research Center for Nuclear Physics, Osaka University, Ibaraki, Osaka 567-0047 (Japan)

2006-02-15T23:59:59.000Z

453

Arkansas Water Resources Center  

E-Print Network [OSTI]

officials on the new Phase II Storm Water NPDES regulations and Best Management Practices available requirements. In addition, they are typically unaware of Best Management Practices (BMPs) that are availableArkansas Water Resources Center STORMWATER POLLUTION PREVENTION BMP WORKSHOP, DEMONSTRATION

Soerens, Thomas

454

Secondary condenser Cooling water  

E-Print Network [OSTI]

Receiver Secondary condenser LC LC Reboiler TC PC Cooling water PC FCPC Condenser LC XC Throttling valve ¨ mx my l© ª y s § y m «¬ ly my wx l n® ® x np © ¯ Condenser Column Compressor Receiver Super-heater Decanter Secondary condenser Reboiler Throttling valve Expansion valve Cooling water

Skogestad, Sigurd

455

Water Waves and Integrability  

E-Print Network [OSTI]

The Euler's equations describe the motion of inviscid fluid. In the case of shallow water, when a perturbative asymtotic expansion of the Euler's equations is taken (to a certain order of smallness of the scale parameters), relations to certain integrable equations emerge. Some recent results concerning the use of integrable equation in modeling the motion of shallow water waves are reviewed in this contribution.

Rossen I. Ivanov

2007-07-12T23:59:59.000Z

456

Arkansas Water Resources Center  

E-Print Network [OSTI]

states. Recycling of nutrients and organic matter is essential in reducing the need for fertilization closely with colleges, universities and other organizations in Arkansas to address the states water Descriptors: animal waste, feed additive, water quality, land application, non-point source pollution

Soerens, Thomas

457

Watering the Sun Corridor  

E-Print Network [OSTI]

Watering the Sun Corridor Managing Choices in Arizona's Megapolitan Area #12;#12;Managing ChoicesSored by Printing generously provided by SRP. Watering the Sun Corridor Tom Buschatzke, City of Phoenix Peter Culp i C y | 5 Introduction............................................7 I. The Sun Corridor

Hall, Sharon J.

458

Development of Polymer Gel Systems to Improve Volumetric Sweep and Reduce Producing Water/Oil Ratios  

SciTech Connect (OSTI)

Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of the third year of a 42 month research program that is aimed at an understanding of gelation chemistry and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work focused on a widely applied system in the field, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. Pre-gel aggregates form and grow as reactions between chromium acetate and polyacrylamide proceed. A mathematical model that describes uptake and crosslinking reactions as a function of time was derived. The model was probability based and provides molecular-weight averages and molecular-weight distributions of the pre-gel aggregates as a function of time and initial system conditions. A liquid chromatography apparatus to experimentally measure the size and molecular weight distributions of polymer samples was developed. The method worked well for polymer samples without the chromium crosslinker. Sample retention observed during measurements of gelant samples during the gelation process compromised the results. Other methods will be tested to measure size distributions of the pre-gel aggregates. Dissolution of carbonate minerals during the injection of gelants causes the pH of the gelant to increase. Chromium precipitates from solution at the higher pH values robbing the gelant of crosslinker. Experimental data on the transport of chromium acetate solutions through dolomite cores were obtained. A mathematical model that describes the transport of brine and chromium acetate solutions through rocks containing carbonate minerals was used to simulate the experimental results.

G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Feiyan Chen

2005-04-03T23:59:59.000Z

459

Hardness of water.  

E-Print Network [OSTI]

This project is helpful to those people who live in the coastal based and they are suffering every year with problem of safe drinking water and not available throughout the year. It has given ideas, technology and economical way of solution for water crisis and it’s also solving problem of scare by use of different methods to development evelopment new water source in water scare area of Saurashtra and Kutch in Gujarat. Saurashtra land is containing of different types of minerals specially bauxite, calcite, fluoride so many mineral based industries are developed here and those who continuous nuous need this as raw materials and they used many mines and processes units. These minerals are creating problem to polluted ground water some are melting and increasing TDS more than 6000 mg/l and

Rahul Oza

460

INEEL Source Water Assessment  

SciTech Connect (OSTI)

The Idaho National Engineering and Environmental Laboratory (INEEL) covers approximately 890 mi2 and includes 12 public water systems that must be evaluated for Source water protection purposes under the Safe Drinking Water Act. Because of its size and location, six watersheds and five aquifers could potentially affect the INEEL’s drinking water sources. Based on a preliminary evaluation of the available information, it was determined that the Big Lost River, Birch Creek, and Little Lost River Watersheds and the eastern Snake River Plain Aquifer needed to be assessed. These watersheds were delineated using the United States Geologic Survey’s Hydrological Unit scheme. Well capture zones were originally estimated using the RESSQC module of the Environmental Protection Agency’s Well Head Protection Area model, and the initial modeling assumptions and results were checked by running several scenarios using Modflow modeling. After a technical review, the resulting capture zones were expanded to account for the uncertainties associated with changing groundwater flow directions, a thick vadose zone, and other data uncertainties. Finally, all well capture zones at a given facility were merged to a single wellhead protection area at each facility. A contaminant source inventory was conducted, and the results were integrated with the well capture zones, watershed and aquifer information, and facility information using geographic information system technology to complete the INEEL’s Source Water Assessment. Of the INEEL’s 12 public water systems, three systems rated as low susceptibility (EBR-I, Main Gate, and Gun Range), and the remainder rated as moderate susceptibility. No INEEL public water system rated as high susceptibility. We are using this information to develop a source water management plan from which we will subsequently implement an INEEL-wide source water management program. The results are a very robust set of wellhead protection areas that will protect the INEEL’s public water systems yet not too conservative to inhibit the INEEL from carrying out its missions.

Sehlke, Gerald

2003-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "brine constituents water" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

WATER RESOURCES NEWS NEBRASKA WATER RESOURCES RESEARCH INSTITUTE  

E-Print Network [OSTI]

WATER RESOURCES NEWS NEBRASKA WATER RESOURCES RESEARCH INSTITUTE 212 AGRICULTURAL ENGINEERING OF THE DIRECTOR . . . April 1973 NEBRASKA AND THE NATIONAL WATER COMMISSION REPORT The National Water Commission grew out of con t r-ovc rey over water resource deve lopment in the Colorado River Basin. Rp

Nebraska-Lincoln, University of

462

Achievements and Outlook 2012 SA Water Centre for Water  

E-Print Network [OSTI]

Achievements and Outlook 2012 SA Water Centre for Water Management and Reuse #12;Contents Our Breaking News 35 SA Water Centre for Water Management and Reuse University of South Australia Mawson Lakes Campus Mawson Lakes SA 5095 Telephone: +61 (08) 8302 3338 Fax: +61 (08) 8302 3386 Web: unisa.edu.au/water

Mayer, Wolfgang

463

WATER RESOURCES NEWS NEBRASKA WATER RESOURCES RESEARCH INSTITUTE  

E-Print Network [OSTI]

WATER RESOURCES NEWS NEBRASKA WATER RESOURCES RESEARCH INSTITUTE 212 AGRICULTURAL ENGINEERING . . . July 1973 The final report of the National Water Commission entitled Water Policies for the Future has been issued. Because its con- cluslons -a-rid -re-commend-atlOnsmay have far-reaching effects on water

Nebraska-Lincoln, University of

464

Water Management in A PEMFC: Water Transport Mechanism and Material  

E-Print Network [OSTI]

Water Management in A PEMFC: Water Transport Mechanism and Material Degradation in Gas Diffusion on the water management of the PEMFC, namely the transport of product water (both liquid and vapor its water management performance and func- tion as indicators of the degradation of GDL material

Kandlikar, Satish

465

Selected Abstracts & Bibliography of International Oil Spill Research, through 1998  

E-Print Network [OSTI]

contamination, environment, environmental impact, environmental pollution, model, oil spill, storage facility, tank, water pollution, wave (water), additive, administration, barrier, book, brine,

Louisiana Applied Oil Spill Research & Development Program Electronic Bibliography

1998-01-01T23:59:59.000Z

466

Research Portfolio Accomplishment Report Unconventional Oil ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of brines brings added regulatory scrutiny; therefore, achievement of even partial removal of salts from produced water-a process called demineralization-can improve water...

467

Selecting activated carbon for water and wastewater treatability studies  

SciTech Connect (OSTI)

A series of follow-up investigations were performed to produce data for improving the four-indicator carbon selection method that we developed to identify high-potential activated carbons effective for removing specific organic water pollutants. The carbon's pore structure and surface chemistry are dependent on the raw material and the activation process. Coconut carbons have relatively more small pores than large pores; coal and apricot nutshell/walnut shell fruit carbons have the desirable pore structures for removing adsorbates of all sizes. Chemical activation, excessive activation, and/or thermal reactivation enlarge small pores, resulting in reduced phenol number and higher tannic acid number. Activated carbon's phenol, iodine, methylene blue, and tannic acid numbers are convenient indicators of its surface area and pore volume of pore diameters < 10, 10-15, 15-28, and > 28 angstrom, respectively. The phenol number of a carbon is also a good indicator of its surface acidity of oxygen-containing organic functional groups that affect the adsorptive capacity for aromatic and other small polar organics. The tannic acid number is an indicator of carbon's capacity for large, high-molecular-weight natural organic precursors of disinfection by-products in water treatment. The experimental results for removing nitrobenzene, methyl-tert-butyl ether, 4,4-bisphenol, humic acid, and the organic constituents of a biologically treated coking-plant effluent have demonstrated the effectiveness of this capacity-indicator-based method of carbon selection.

Zhang, W.; Chang, Q.G.; Liu, W.D.; Li, B.J.; Jiang, W.X.; Fu, L.J.; Ying, W.C. [East China University of Chemical Technology, Shanghai (China)

2007-10-15T23:59:59.000Z

468

A relativistic constituent quark model  

SciTech Connect (OSTI)

We investigate the predictive power of a relativistic quark model formulated on the light-front. The nucleon electromagnetic form factors, the semileptonic weak decays of the hyperons and the magnetic moments of both baryon octet and decuplet are calculated and found to be in excellent agreement with experiment.

Schlumpf, F.

1993-08-01T23:59:59.000Z

469

Water's Hydrogen Bond Strength  

E-Print Network [OSTI]

Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

Martin Chaplin

2007-06-10T23:59:59.000Z