National Library of Energy BETA

Sample records for brine constituents water

  1. Property:BrineConstituents | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII JumpQuarterly SmartDB-2,InformationAwardee JumpBrineConstituents Jump to:

  2. Improved Water Flooding through Injection Brine Modification

    SciTech Connect (OSTI)

    Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman

    2003-01-01

    Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

  3. Recovery of energy from geothermal brine and other hot water sources

    DOE Patents [OSTI]

    Wahl, III, Edward F. (Claremont, CA); Boucher, Frederic B. (San Juan Capistrano, CA)

    1981-01-01

    Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g. with respect to the design of such plates, number of plates employed, spacing between plates, area thereof, column diameter, and the like, are designed to achieve maximum throughput of brine or hot water and reduction in temperature differential at the respective stages or plates between the brine or hot water and the working fluid, and so minimize lost work and maximize efficiency, and minimize scale deposition from hot water containing fluid including salts, such as brine. Maximum throughput approximates minimum cost of electricity which can be produced by conversion of the recovered thermal energy to electrical energy.

  4. Analysis of hydrocarbon removal methods for the management of oilfield brines and produced waters 

    E-Print Network [OSTI]

    Furrow, Brendan Eugene

    2005-11-01

    and globally, the petroleum industries challenge has been to develop a high-tech and cost effective method to purify the large volumes of oilfield brines and produced water. Currently, most of the produced water requires several pre- and post- treatment methods...

  5. Viscous heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1984-07-10

    Hydroxyethyl cellulose and a sequestrant are added to a heavy brine containing one or more salts selected from calcium chloride, calcium bromide, and zinc bromide to increase the viscosity of the brine. Preferably the brine contains zinc bromide, has a density in the range from about 14.2-19.2 pounds per gallon, and the sequestrant is a polyphosphonic acid or water soluble salt thereof.

  6. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    SciTech Connect (OSTI)

    David B. Burnett; Mustafa Siddiqui

    2006-12-29

    Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes for the removal of hydrocarbons from produced water. The results of these experiments show that hydrocarbons from produced water can be reduced from 200 ppm to below 29 ppm level. Experiments were also done to remove the dissolved solids (salts) from the pretreated produced water using desalination membranes. Produced water with up to 45,000 ppm total dissolved solids (TDS) can be treated to agricultural water quality water standards having less than 500 ppm TDS. The Report also discusses the results of field testing of various process trains to measure performance of the desalination process. Economic analysis based on field testing, including capital and operational costs, was done to predict the water treatment costs. Cost of treating produced water containing 15,000 ppm total dissolved solids and 200 ppm hydrocarbons to obtain agricultural water quality with less than 200 ppm TDS and 2 ppm hydrocarbons range between $0.5-1.5 /bbl. The contribution of fresh water resource from produced water will contribute enormously to the sustainable development of the communities where oil and gas is produced and fresh water is a scarce resource. This water can be used for many beneficial purposes such as agriculture, horticulture, rangeland and ecological restorations, and other environmental and industrial application.

  7. Thickened heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1983-12-13

    A thickened brine solution useful as a well servicing fluid is prepared, said solution consisting essentially of water, at least 20% by weight zinc bromide, calcium bromide, and a viscosifying amount of hydroxyethyl cellulose.

  8. Membrane Desalination of Agricultural Drainage Water: Water Recovery Enhancement and Brine Minimization

    E-Print Network [OSTI]

    Cohen, Yoram

    2008-01-01

    Report for Buena Vista Water Storage District, (2003). S.of low-salinity brackish water: Integration of acceleratedagricultural drainage water, Desalination, A. Rahardianto,

  9. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

  10. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  11. PII S0016-7037(00)00369-0 Ra isotopes and Rn in brines and ground waters of the Jordan-Dead Sea Rift Valley

    E-Print Network [OSTI]

    Yehoshua, Kolodny

    , yet enrichment in water sources is most often not associated with anomalously high uranium or thorium Rift Valley: Enrichment, retardation, and mixing TAMAR MOISE, ABRAHAM STARINSKY, AMITAI KATZ surrounding rocks into the brine end member. 228 Ra/226 Ra ratios are exceptionally low 0.07 to 0.9, mostly

  12. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    E-Print Network [OSTI]

    P. C. Myint; Y. Hao; A. Firoozabadi

    2015-04-20

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO$_2$) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi, and the CO$_2$ activity coefficient model by Duan and Sun. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO$_2$, pure water, and both CO$_2$-rich and aqueous (H$_2$O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Sun's model yields accurate results for the partial molar enthalpy of CO$_2$. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H$_2$O-CO$_2$-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  13. Sandstone ? Brine + GH Sandstone ? Brine 200 200 Sandstone ...

    E-Print Network [OSTI]

    santos@gauss ()

    Sandstone ? Brine + GH. Sandstone ? Brine. 200. 200. Sandstone ? Brine. x. z. 800. Vp=2200 m/s. Vs=1250 m/sSigma=1 S/m. Vp=4100 m/s. Vs=2300 ...

  14. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    E-Print Network [OSTI]

    Myint, P C; Firoozabadi, A

    2015-01-01

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO$_2$) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi, and the CO$_2$ activity coefficient model by Duan and Sun. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO$_2$, pure water, and both CO$_2$-rich and aqueous (H$_2$O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spy...

  15. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    SciTech Connect (OSTI)

    Myint, P. C.; Hao, Y.; Firoozabadi, A.

    2015-03-27

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO2) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data [1]. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi [2], and the CO2 activity coefficient model by Duan and Sun [3]. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO2, pure water, and both CO2-rich and aqueous (H2O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Sun’s model yields accurate results for the partial molar enthalpy of CO2. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H2O-CO2-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  16. Dense water formation on the northwestern shelf of the Okhotsk Sea: 1. Direct observations of brine rejection

    E-Print Network [OSTI]

    Talley, Lynne D.

    , this cold, oxygen-rich, but relatively fresh water is advected southward along the coast of Sakhalin island

  17. Brine stability study

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gary Garland

    2015-04-15

    This is a study of the brine formulations that we were using in our testing were stable over time. The data includes charts, as well as, all of the original data from the ICP-MS runs to complete this study.

  18. Fate of Magnesium Chloride Brine Applied to Suppress Dust from...

    Office of Scientific and Technical Information (OSTI)

    mass ratio and the total dissolved Cl- concentration of pore water show that brine contamination occurs primarily within 13 m of treated roads, but can extend as much as 30 m...

  19. RECREATIONAL CONSTITUENTS

    E-Print Network [OSTI]

    RECREATIONAL FISHERIES CONSTITUENTS ECONOMICS WORKSHOP Photo credit: Will Satterthwaite U-handed in giving both criticism and credit for a job well done. In the next section, we provide a brief summary

  20. A Critical Analysis of Technological Innovation and Economic Development in Southern California's Urban Water Reuse And Recycling Industry

    E-Print Network [OSTI]

    Pilip-Florea, Shadrach Jay

    2012-01-01

    seawater pumping, brine removal, water treatment, and membrane desalinationseawater and discharged brine, which it received from an adjacent desalination

  1. Formate brines -- New fluids for drilling and completions

    SciTech Connect (OSTI)

    Ramsey, M.S.; Shipp, J.A.

    1996-01-01

    The term ``formate brines`` refers broadly to three primary compounds dissolved in water -- sodium formate (NaCOOH), potassium formate (KCOOH) and cesium formate (CsCOOH). Each is chemically classified as an alkali-metal salt of formic acid. They offer properties that in many respects are superior to their predecessors, halide brines such as zinc bromide and calcium bromide, without the undesirable side effects of those more common halide brine systems. This article introduces the technology and provides an overview of published work to date regarding formates.

  2. Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot

    SciTech Connect (OSTI)

    Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

    2009-11-01

    To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

  3. Deep convection and brine rejection in the Japan Sea Lynne D. Talley

    E-Print Network [OSTI]

    Talley, Lynne D.

    Deep convection and brine rejection in the Japan Sea Lynne D. Talley Scripps Institution groups. Japan Sea deep convection apparently occurs every winter, but massive renewal of bottom waters. Salyuk, P. Tishchenko, I. Zhabin, and S. Riser, Deep convection and brine rejection in the Japan Sea

  4. Scaling control during membrane distillation of coal seam gas reverse osmosis brine

    E-Print Network [OSTI]

    Scaling control during membrane distillation of coal seam gas reverse osmosis brine Hung C. Duong during membrane distillation (MD) of brine from reverse osmosis (RO) treatment of coal seam gas (CSG. During CSG production, both gas and water are extracted to the surface. Gas is commonly separated from

  5. Laboratory studies of imbibition flooding using carbonated brine 

    E-Print Network [OSTI]

    Sharif, Qamar Javaid

    1991-01-01

    & Technology, Pakistan. Chair of Advisory Committee: Dr. Steven W. Poston The objective of this research was to blend both, COq injection and water imbibition methods and develop a technique best suitable for enhancing oil recovery from low permeability... drive, was induced at the end of 48 hours. Studies have shown that increase in carbonated brine concentration increased total oil recovery at 70 F. With 5. 5 % carbonated brine, 62. 2 % of OOIP was recovered at 150 F as compared to 73. 7 % of OOIP...

  6. Brining studies at Pepper Products Inc. 

    E-Print Network [OSTI]

    Okoro, John Daniel

    1988-01-01

    of Department) A. B. Childers (Member) V. E. Sweat (Member) December 1988 Abstract Optimum brining conditions, causes of secondary fermentation, and salt fluctuation were investigated. Jalapeno peppers held in brine solution undergo lactic acid... fermentation, controlled by level of acidification and concentration of salt. Only brining at 7. 5% NaCl, with no added acetic acid, resulted in loss of all fermentable sugars. However, salt concentration fluctuated widely in this sample. Brining in 25...

  7. Brine Sampling and Evaluation Program, 1991 report

    SciTech Connect (OSTI)

    Deal, D.E.; Abitz, R.J.; Myers, J.; Martin, M.L.; Milligan, D.J.; Sobocinski, R.W.; Lipponer, P.P.J.; Belski, D.S.

    1993-09-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plan (WIPP) during 1991. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. When excavations began at the WIPP in 1982, small brine seepages (weeps) were observed on the walls. Brine studies began as part of the Site Validation Program and were formalized as a program in its own right in 1985. During nine years of observations (1982--1991), evidence has mounted that the amount of brine seeping into the WIPP excavations is limited, local, and only a small fraction of that required to produce hydrogen gas by corroding the metal in the waste drums and waste inventory. The data through 1990 is discussed in detail and summarized by Deal and others (1991). The data presented in this report describes progress made during the calendar year 1991 and focuses on four major areas: (1) quantification of the amount of brine seeping across vertical surfaces in the WIPP excavations (brine ``weeps); (2) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes; (3) further characterization of brine geochemistry; and (4) preliminary quantification of the amount of brine that might be released by squeezing the underconsolidated clays present in the Salado Formation.

  8. Viscous heavy brine completion fluids. [Oil wells

    SciTech Connect (OSTI)

    Darlington, R.K.; Hunter, D.V.

    1982-01-01

    An activated hydroxyethyl cellulose (HEC) has been developed which will viscosify brines of any density up to 19.2 lb/gal containing calcium chloride, calcium bromide and/or zinc bromide. The use of activated hydroxyethyl cellulose allows preparation of viscosified brines at ambient emperature and without undissolved polymer solids. The time required to prepare a viscosified brine is greatly reduced. In addition, the rheology of brines viscosified with activated HEC can be accurately predicted allowing brines with equivalent solution rheology properties to be prepared batch after batch. 29 refs.

  9. Radionuclides, inorganic constituents, organic compounds, and bacteria in water from selected wells and springs from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman Area, Idaho, 1990

    SciTech Connect (OSTI)

    Bartholomay, R.C.; Edwards, D.D. [Geological Survey, Idaho Falls, ID (United States); Campbell, L.J. [State of Idaho, Dept. of Water Resources (United States)

    1992-03-01

    The US Geological Survey and the Idaho Department of Water Resources, in response to a request from the US Department of Energy, sampled 19 sites as part of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering Laboratory to the Hagerman area. Water samples were collected and analyzed for manmade pollutants and naturally occurring constituents. The samples were collected from seven irrigation wells, five domestic wells, two springs, one stock well, two dairy wells, one observation well, and one commercial well. Two quality assurance samples also were collected and analyzed. The water samples were analyzed for selected radionuclides, inorganic constituents, organic compounds, and bacteria. None of the radionuclides, inorganic constituents, or organic compounds exceeded the established maximum contaminant levels for drinking water. Most of the radionuclide and inorganic constituent concentrations exceeded their respective reporting levels. All samples analyzed for surfactants and dissolved organic carbon had concentrations that exceeded their reporting level. Toluene concentrations exceeded the reporting level in one water sample. Two samples contained fecal coliform bacteria counts that exceeded established maximum contaminant levels for drinking water.

  10. Batteries from Brine | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    technologies that extract these strategic materials from geothermal brines at a mining operation -- a first-of-its-kind achievement. Simbol estimates that the mineral-rich...

  11. THE MECHANISM OF INTRAGRANULAR MIGRATION OF BRINE INCLUSIONS IN SALT

    E-Print Network [OSTI]

    Machiels, A.J.

    2010-01-01

    of Brine Inclusions in a Salt Repository", ORM. -5526 (JulyOF BRINE INCLUSIONS IN SALT A.J. Machiels, S. Yagnik, D.R.OF BRINE INCLUSIONS IN SALT by A.J. Machiels S. Yagnik D.R.

  12. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect (OSTI)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

  13. Norm removal from frac water

    DOE Patents [OSTI]

    Silva, James Manio; Matis, Hope; Kostedt, IV, William Leonard

    2014-11-18

    A method for treating low barium frac water includes contacting a frac water stream with a radium selective complexing resin to produce a low radium stream, passing the low radium stream through a thermal brine concentrator to produce a concentrated brine; and passing the concentrated brine through a thermal crystallizer to yield road salt.

  14. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    seawater,  industrial  waste,   and  brine  desalination  and  seawater  concentrate  disposal  alternatives."   Desalination  

  15. Study of thermal-gradient-induced migration of brine inclusions in salt. Final report

    SciTech Connect (OSTI)

    Olander, D.R.

    1984-08-01

    Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed.

  16. How temperature and pressure affect clear brines

    SciTech Connect (OSTI)

    Hubbard, J.T.

    1984-04-01

    The correct application of the expansivity and compressibility of brine fluids under the influence of temperature and pressure is needed to calculate the actual hydrostatic pressure in a well. Well operations can benefit by reducing unintentional overbalance, lessening fluid losses, and lowering recommended fluid densities, hence reducing fluid costs. Since the early 1970s, the effects of temperature and pressure on the density of clear brine fluids have been questioned. As early as 1973, studies were started to define density loss with increased temperature in zinc bromide brines. This article describes a continuing study, begun in 1978, which has characterized the expansivity and compressibility of single salt brine solutions, such as are used in workover and completion fluids.

  17. Investigation of oil injection into brine for the Strategic Petroleum Reserve : hydrodynamics and mixing experiments with SPR liquids.

    SciTech Connect (OSTI)

    Castaneda, Jaime N.; Cote, Raymond O.; Torczynski, John Robert; O'Hern, Timothy John

    2004-05-01

    An experimental program was conducted to study a proposed approach for oil reintroduction in the Strategic Petroleum Reserve (SPR). The goal was to assess whether useful oil is rendered unusable through formation of a stable oil-brine emulsion during reintroduction of degassed oil into the brine layer in storage caverns. An earlier report (O'Hern et al., 2003) documented the first stage of the program, in which simulant liquids were used to characterize the buoyant plume that is produced when a jet of crude oil is injected downward into brine. This report documents the final two test series. In the first, the plume hydrodynamics experiments were completed using SPR oil, brine, and sludge. In the second, oil reinjection into brine was run for approximately 6 hours, and sampling of oil, sludge, and brine was performed over the next 3 months so that the long-term effects of oil-sludge mixing could be assessed. For both series, the experiment consisted of a large transparent vessel that is a scale model of the proposed oil-injection process at the SPR. For the plume hydrodynamics experiments, an oil layer was floated on top of a brine layer in the first test series and on top of a sludge layer residing above the brine in the second test series. The oil was injected downward through a tube into the brine at a prescribed depth below the oil-brine or sludge-brine interface. Flow rates were determined by scaling to match the ratio of buoyancy to momentum between the experiment and the SPR. Initially, the momentum of the flow produces a downward jet of oil below the tube end. Subsequently, the oil breaks up into droplets due to shear forces, buoyancy dominates the flow, and a plume of oil droplets rises to the interface. The interface was deflected upward by the impinging oil-brine plume. Videos of this flow were recorded for scaled flow rates that bracket the equivalent pumping rates in an SPR cavern during injection of degassed oil. Image-processing analyses were performed to quantify the penetration depth and width of the oil jet. The measured penetration depths were shallow, as predicted by penetration-depth models, in agreement with the assumption that the flow is buoyancy-dominated, rather than momentum-dominated. The turbulent penetration depth model overpredicted the measured values. Both the oil-brine and oil-sludge-brine systems produced plumes with hydrodynamic characteristics similar to the simulant liquids previously examined, except that the penetration depth was 5-10% longer for the crude oil. An unexpected observation was that centimeter-size oil 'bubbles' (thin oil shells completely filled with brine) were produced in large quantities during oil injection. The mixing experiments also used layers of oil, sludge, and brine from the SPR. Oil was injected at a scaled flow rate corresponding to the nominal SPR oil injection rates. Injection was performed for about 6 hours and was stopped when it was evident that brine was being ingested by the oil withdrawal pump. Sampling probes located throughout the oil, sludge, and brine layers were used to withdraw samples before, during, and after the run. The data show that strong mixing caused the water content in the oil layer to increase sharply during oil injection but that the water content in the oil dropped back to less than 0.5% within 16 hours after injection was terminated. On the other hand, the sediment content in the oil indicated that the sludge and oil appeared to be well mixed. The sediment settled slowly but the oil had not returned to the baseline, as-received, sediment values after approximately 2200 hours (3 months). Ash content analysis indicated that the sediment measured during oil analysis was primarily organic.

  18. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  19. THERMAL GRADIENT MIGRATION OF BRINE INCLUSIONS IN SALT

    E-Print Network [OSTI]

    Yagnik, S.K.

    2010-01-01

    OF BRINE INCLUSIONS IN SALT Suresh K. Yagnik February 1982 TOF BRINE INCLUSIONS IN SALT by Suresh K. Yagnik Materialsb u i l t in future. The salt deposits, however, are known

  20. Portable brine evaporator unit, process, and system

    DOE Patents [OSTI]

    Hart, Paul John (Indiana, PA); Miller, Bruce G. (State College, PA); Wincek, Ronald T. (State College, PA); Decker, Glenn E. (Bellefonte, PA); Johnson, David K. (Port Matilda, PA)

    2009-04-07

    The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

  1. High Recovery Desalination of Brackish Water by Chemically-Enhanced Seeded Precipitation

    E-Print Network [OSTI]

    McCool, Brian Carey

    2012-01-01

    for quality water supply and waste water disposal.disposal. Management of agricultural drainage water quality,brine disposal) at the optimal recovery a . AD Water Quality

  2. Expected brine movement at potential nuclear waste repository salt sites

    SciTech Connect (OSTI)

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

  3. New Energy Efficient Method for Cleaning Oilfield Brines with Carbon Dioxide 

    E-Print Network [OSTI]

    Little, C. T.; Seibert, A. F.; Bravo, J. L.; Fair, J. R.

    1991-01-01

    METHOD FOR CLEANING OILFIELD BRINES WITH CARBON DIOXIDE C. T. LITTLE A. F. SEIBERT Research Engineer Technical Manager Amoco Oil Company Separations Research Program Naperville, Illinois The University of Texas Austin, Texas ABSTRACT Water... are used to purify these waters. However, if stricter discharge limits are imposed by the Environmental Protection Agency, the gas flotation method is likely to be inadequate. A new process was developed which utilizes carbon dioxide to clean oilfield...

  4. Technical and economic feasibility of salt-gradient solar ponds at the Truscott Brine Lake of the Red River Chloride Control Project. A report to the House-Senate Committee on Appropriations of the Ninety-Seventh Congress

    SciTech Connect (OSTI)

    Not Available

    1982-09-01

    The Truscott Brine Lake is being constructed to impound highly brackish water from a number of sources which would normally flow into the Wichita River, a tributary of the Red River in Knox County, Texas. A 35.4-km (22-mile) pipeline is being constructed to carry the brines from their primary source to the Truscott Brine Lake site. The reservoir is designed to contain 100 years of brine emissions from three chloride emission areas in the Wichita River Basin. The solar ponds and power generating facilities would be located in the Bluff Creek Arm of Truscott Brine Lake. The Truscott Brine Lake study includes: survey of suitability of Truscott Lake site, review of solar pond technology, preconceptual design of solar salt pond power plant, and economic evaluation.

  5. PII S0016-7037(01)00579-8 The origin and evolution of base metal mineralising brines and hydrothermal fluids,

    E-Print Network [OSTI]

    Banks, David

    that the major element chemistry of these fluids is comparable with that of evolved oil-field brines, and fluids of mineralising palaeoflu- ids is a complex function of the basin chemistry, subsequent modifications due to water by the evaporation of seawater or a seawater­meteoric water mixture past the point of halite precipitation. The major

  6. Summary Results for Brine Migration Modeling Performed by LANL...

    Energy Savers [EERE]

    modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies conducted at Sandia, Los Alamos, and...

  7. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Molecular Simulation of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of...

  8. PILOT TESTING: PRETREATMENT OPTIONS TO ALLOW RE-USE OF FRAC FLOWBACK AND PRODUCED BRINE FOR GAS SHALE RESOURCE DEVELOPMENT

    SciTech Connect (OSTI)

    Burnett, David

    2012-12-31

    The goal of the A&M DOE NETL Project No. DE-FE0000847 was to develop a mobile, multifunctional water treatment capability designed specifically for “pre-treatment” of field waste brine. The project consisted of constructing s mobile “field laboratory” incorporating new technology for treating high salinity produced water and using the lab to conduct a side-by-side comparison between this new technology and that already existing in field operations. A series of four field trials were performed utilizing the mobile unit to demonstrate the effectiveness of different technology suitable for use with high salinity flow back brines and produced water. The design of the mobile unit was based on previous and current work at the Texas A&M Separation Sciences Pilot Plant. The several treatment techniques which have been found to be successful in both pilot plant and field tests had been tested to incorporate into a single multifunctional process train. Eight different components were evaluated during the trials, two types of oil and grease removal, one BTEX removal step, three micro-filters, and two different nanofilters. The performance of each technique was measured by its separation efficiency, power consumption, and ability to withstand fouling. The field trials were a success. Four different field brines were evaluated in the first trial in New York. Over 16,000 gallons of brine were processed. Using a power cost of $.10 per kWh, media pretreatment power use averaged $0.004 per barrel, solids removal $.04 per barrel and brine “softening” $.84 per barrel. Total power cost was approximately $1.00 per barrel of fluid treated. In Pennsylvania, brines collected from frac ponds were tested in two additional trials. Each of the brines was converted to an oil-free, solids-free brine with no biological activity. Brines were stable over time and would be good candidates for use as a make-up fluid in a subsequent fracturing fluid design. Reports on all of the field trials and subcontractor research have been summarized in this Final Report. Individual field trial reports and research reports are contained in the companion volume titled “Appendices”

  9. Reduce completion fluid costs with on-site brine tests

    SciTech Connect (OSTI)

    Thomas, D.C.; Darlington, R.K.; Kinney, W.R.; Lowell, J.L.

    1982-09-01

    A newly developed field kit makes on-site brine completion fluid testing practical. Simple titration procedures are used to analyze brine for calcium, zinc, chloride and bromide with an accuracy and repeatability that compares favorably with expensive laboratory techniques. This article describes the field testing theory and details analytical procedures used.

  10. Technique for thermodynamic crystallization temperature of brine fluids

    SciTech Connect (OSTI)

    Clark, D.E.; Hubbard, J.T.

    1983-03-01

    The application of high density solids free brine fluids has proven to be technically and economically successful in hydrocarbon completion and workover operations. The use of inorganic salts such as calcium chloride, calcium bromide, zinc bromide, and sodium bromide has contributed to the development of complex salt systems. As the density and complexity of these systems becomes more detailed, the requirement for proper fluid design becomes increasingly important. When a brine solution is cooled sufficiently, a temperature is reached where the solution will be saturated. A further decrease in temperature will result in the precipitation of salt from the solution. The temperature at which this transpires, provided no super-cooling occurs, is the crystallization point of the solution. A correctly formulated solids free brine should have the optimum crystallization point for the temperature conditions it will encounter. A recently developed semiautomatic procedure constructs a cooling curve plot of each brine tested. This cooling curve plot allows the determination of the super-cooling potential, the Thermodynamic Crystallization Temperature, and the Last Crystal To Dissolve Temperature. The device provides a permanent record of the cooling curve with repeatable accuracy, which assists in the development of error free brine formulation tables, brine density, and/or crystallization point adjustments, and brine analysis.

  11. Radionuclide transport in sandstones with WIPP brine

    SciTech Connect (OSTI)

    Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

    1981-02-01

    Retardation factors (R) have been measured for the transport of /sup 3/H, /sup 95m/Tc, and /sup 85/Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for /sup 85/Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for /sup 85/Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta.

  12. TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems

    E-Print Network [OSTI]

    Xu, Tianfu

    2008-01-01

    High Ionic Strength Brine Sandstone Systems Tianfu Xu Earthwith H2S and SO2 in a sandstone formation, Chemical Geology,system using a Gulf Coast sandstone saline formation. 2.

  13. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extractionmore »control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing ‘Area of Review’, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.« less

  14. Water purification using organic salts

    DOE Patents [OSTI]

    Currier, Robert P.

    2004-11-23

    Water purification using organic salts. Feed water is mixed with at least one organic salt at a temperature sufficiently low to form organic salt hydrate crystals and brine. The crystals are separated from the brine, rinsed, and melted to form an aqueous solution of organic salt. Some of the water is removed from the aqueous organic salt solution. The purified water is collected, and the remaining more concentrated aqueous organic salt solution is reused.

  15. 2 INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 EXPERIMENTAL STUDY OF CRUDE/BRINE/ROCK INTERACTION AT

    E-Print Network [OSTI]

    Schechter, David S.

    44 2 INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 EXPERIMENTAL STUDY OF CRUDE in this section and expand the understanding of the interactions of the Spraberry reservoir rock, oil and brine used Spraberry oil, synthetic reservoir brine and Spraberry core at reservoir temperature (138o F

  16. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, Wen Y. (Houston, TX)

    1984-01-01

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them (46, 53, 61, 69) with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide (63) to precipitate silicon constituents, the pH of the resultant solution is increased (81), preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated (84) to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process (86, 18, 17) where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  17. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO?-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore »proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO?. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO? will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO? driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir conditions. Our research has shown that the REE signature imparted to the formation fluid by the introduction of CO? to the formation, can be measured and tracked as part of an MMV program. Additionally, this REE fingerprint may serve as an ideal tracer for fluid migration, both within the CCS target formation, and should formation fluids migrate into overlying aquifers. However application of REE and other trace elements to CCS system is complicated by the high salt content of the brines contained within the target formations. In the United States by regulation, in order for a geologic reservoir to be considered suitable for carbon storage, it must contain formation brine with total dissolved solids (TDS) > 10,000 ppm, and in most cases formation brines have TDS well in excess of that threshold. The high salinity of these brines creates analytical problems for elemental analysis, including element interference with trace metals in Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) (i.e. element mass overlap due to oxide or plasma phenomenon). Additionally, instruments like the ICP-MS that are sensitive enough to measure trace elements down to the parts per trillion level are quickly oversaturated when water TDS exceeds much more than 1,000 ppm. Normally this problem is dealt with through dilution of the sample, bringing the water chemistry into the instruments working range. However, dilution is not an option when analyzing these formation brines for trace metals, because trace elements, specifically the REE, which occur in aqueous solutions at the parts per trillion levels. Any dilution of the sample would make REE detection impossible. Therefore, the ability to use trace metals as in situ natural tracers in high TDS brines environments requires the development of methods for pre-concentrating trace elements, while reducing the salinity and associated elemental interference such that the brines can be routinely analyzed by standard ICP-MS methods. As part of the Big Sky Carbon Sequestration Project the INL-CAES has developed a rapid, easy to use proces

  18. The sup 36 Cl ages of the brines in the Magadi-Natron basin, east Africa

    SciTech Connect (OSTI)

    Kaufman, A.; Margaritz, M.A.; Hollos, G. ); Paul, M.; Boaretto, E. ); Hillaire-Marcel, C. ); Taieb, M. )

    1990-10-01

    The depression in the East African Rift which includes both Lake Magadi and Lake Natron forms a closed basin within which almost all the dissolved chloride originates in precipitation, since there is no important source of very ancient sedimentary chloride. This provides an ideal setting for the evaluation of the {sup 36}Cl methodology as a geochemical and hydrological tracer. The main source of recent water, as represented by the most dilute samples measured, is characterized by a {sup 36}Cl/Cl ratio of 2.5 {times} 10{sup {minus}14}, in agreement with the calculated value expected in precipitation. Surface evaporation increases the chlorinity of the local freshwater inflow by about a factor of 110 without changing the isotopic ratio, indicating that little chloride enters the system in the form of sediment leachate. A second type of brine found in the basin occurs in a hot deep groundwater reservoir and is characterized by lower {sup 36}Cl/Cl ratios (<1.2 {times} 10{sup {minus}14}). By comparing this value with the 2.5 {times} 10{sup {minus}14} in recent recharge, one obtains an approximate salt accumulation age of 760 Ka which is consistent with thee time of the first appearance of the lake. These older brines also have lower {sup 18}O and {sup 2}H values which indicate that they were recharged during a climatically different era. The {sup 36}Cl/Cl ratios in the inflowing waters and in the accumulated brine, together with the known age of the Lake Magadi basin, may be used to estimate the importance of the hypogene and epigene, as opposed to the meteoric, mode of {sup 36}Cl production. Such a calculation shows that the hypogene and epigene processes together contribute less than 6% of the total {sup 36}Cl present in the lake.

  19. Determination of dissolved organic carbon in concentrated brine solutions

    SciTech Connect (OSTI)

    Hannaker, P.; Buchanan, A.S.

    1983-10-01

    An absolute method is reported for the determination of soluble organic carbon in concentrated brine solutions. Wet oxidation with K/sub 2/S/sub 2/O/sub 8/ is used in a sealed ampule at 130/sup 0/C, followed by hot CuO treatment of the gas stream, to fully oxidize organic species to CO/sub 2/. The CO/sub 2/ is measured gravimetrically after gas purification. Results are presented for a wide range of soluble organic species, both with and without NaCl present. This procedure now allows for the accurate determination of organic carbon in brines over a range from about 5 ppm to values in excess of 1000 ppm. The technique overcomes the difficulties of calibration curvature, catalytic clogging, and instrumental fogging, often encountered in modern instrumental methods, when applied to concentrated brine solutions. 1 figure, 3 tables.

  20. Actinide (III) solubility in WIPP Brine: data summary and recommendations

    SciTech Connect (OSTI)

    Borkowski, Marian; Lucchini, Jean-Francois; Richmann, Michael K.; Reed, Donald T.

    2009-09-01

    The solubility of actinides in the +3 oxidation state is an important input into the Waste Isolation Pilot Plant (WIPP) performance assessment (PA) models that calculate potential actinide release from the WIPP repository. In this context, the solubility of neodymium(III) was determined as a function of pH, carbonate concentration, and WIPP brine composition. Additionally, we conducted a literature review on the solubility of +3 actinides under WIPP-related conditions. Neodymium(III) was used as a redox-invariant analog for the +3 oxidation state of americium and plutonium, which is the oxidation state that accounts for over 90% of the potential release from the WIPP through the dissolved brine release (DBR) mechanism, based on current WIPP performance assessment assumptions. These solubility data extend past studies to brine compositions that are more WIPP-relevant and cover a broader range of experimental conditions than past studies.

  1. Wetting behavior of selected crude oil/brine/rock systems. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Zhou, X.; Morrow, N.R.; Ma, S.

    1996-12-31

    Previous studies of crude oil/brine/rock (COBR) and related ensembles showed that wettability and its effect on oil recovery depend on numerous complex interactions. In the present work, the wettability of COBR ensembles prepared using Prudhoe Bay crude oil, a synthetic formation brine, and Berea Sandstone was varied by systematic change in initial water saturation and length of aging time at reservoir temperature (88 C). All displacement tests were run at ambient temperature. Various degrees of water wetness were achieved and quantified by a modified Amott wettability index to water, the relative pseudo work of imbibition, and a newly defined apparent advancing dynamic contact angle. Pairs of spontaneous imbibition (oil recovery by spontaneous imbibition of water) and waterflood (oil recovery vs. pore volumes of water injected) curves were measured for each of the induced wetting states. Several trends were observed. Imbibition rate, and hence water wetness, decreased with increase in aging time and with decrease in initial water saturation. Breakthrough recoveries and final oil recovery by waterflooding increased with decrease in water wetness. Correlations between water wetness and oil recovery by waterflooding and spontaneous imbibition are presented.

  2. Brine-in-crude-oil emulsions at the Strategic Petroleum Reserve.

    SciTech Connect (OSTI)

    Nemer, Martin B.; Lord, David L.; MacDonald, Terry L.

    2013-10-01

    Metastable water-in-crude-oil emulsion formation could occur in a Strategic Petroleum Reserve (SPR) cavern if water were to flow into the crude-oil layer at a sufficient rate. Such a situation could arise during a drawdown from a cavern with a broken-hanging brine string. A high asphaltene content (> 1.5 wt %) of the crude oil provides the strongest predictor of whether a metastable water-in-crude-oil emulsion will form. However there are many crude oils with an asphaltene content > 1.5 wt % that don't form stable emulsions, but few with a low asphaltene content that do form stable emulsions. Most of the oils that form stable emulsions are %E2%80%9Csour%E2%80%9D by SPR standards indicating they contain total sulfur > 0.50 wt %.

  3. High Recovery Desalination of Brackish Water by Chemically-Enhanced Seeded Precipitation

    E-Print Network [OSTI]

    McCool, Brian Carey

    2012-01-01

    water management: (1) direct disposal (no desalination), (2)recovery (62% for RO). Direct disposal of AD brackish watervarious methods for direct brine disposal such as thermal

  4. Evaluation of brine disposal from the Bryan Mound site of the strategic petroleum reserve program. Final report

    SciTech Connect (OSTI)

    Case, Robert J.; Chittenden, Jr, Mark E.; Harper, Jr, Donald E.; Kelly, Jr, Francis J.; Loeblich, Laurel A.; McKinney, Larry D.; Minello, Thomas J.; Park, E. Taisoo; Randall, Robert E.; Slowey, J. Frank

    1981-01-01

    On March 10, 1980, the Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging the resulting brine into the coastal waters off Freeport, Texas. During the months of March and April, a team of scientists and engineers from Texas A and M University conducted an intensive environmental study of the area surrounding the diffuser site. A pipeline has been laid from the Bryan Mound site to a location 12.5 statute miles (20 km) offshore. The last 3060 ft (933 m) of this pipeline is a 52-port diffuser through which brine can be discharged at a maximum rate of 680,000 barrels per day. Initially, 16 ports were open which permitted a maximum discharge rate of 350,000 barrels per day and a continuous brine discharge was achieved on March 13, 1980. The purpose of this report is to describe the findings of the project team during the intensive postdisposal study period of March and April, 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management.

  5. Uranium (VI) solubility in carbonate-free ERDA-6 brine

    SciTech Connect (OSTI)

    Lucchini, Jean-francois; Khaing, Hnin; Reed, Donald T

    2010-01-01

    When present, uranium is usually an element of importance in a nuclear waste repository. In the Waste Isolation Pilot Plant (WIPP), uranium is the most prevalent actinide component by mass, with about 647 metric tons to be placed in the repository. Therefore, the chemistry of uranium, and especially its solubility in the WIPP conditions, needs to be well determined. Long-term experiments were performed to measure the solubility of uranium (VI) in carbonate-free ERDA-6 brine, a simulated WIPP brine, at pC{sub H+} values between 8 and 12.5. These data, obtained from the over-saturation approach, were the first repository-relevant data for the VI actinide oxidation state. The solubility trends observed pointed towards low uranium solubility in WIPP brines and a lack of amphotericity. At the expected pC{sub H+} in the WIPP ({approx} 9.5), measured uranium solubility approached 10{sup -7} M. The objective of these experiments was to establish a baseline solubility to further investigate the effects of carbonate complexation on uranium solubility in WIPP brines.

  6. Assessment of Injection Well Construction and Operation for Water Injection Wells and Salt Water Disposal Wells

    E-Print Network [OSTI]

    such as drilling mud and work- over fluids. These are all shallow wells using injected fresh water to dissolve salt Disposal Wells in the Nine Township Area ­ 2009 September 2009 Prepared by Delaware Basin Drilling into a brine solution. In order to develop a solution mine, either a new well is drilled for brine extraction

  7. Modeling Coupled THMC Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco Martin, Laura; Mukhopadhyay, Sumit; Houseworth, Jim; Birkholzer, Jens

    2014-08-14

    In this report, we present FY2014 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. LBNL’s work on the modeling of coupled THMC processes in salt was initiated in FY2012, focusing on exploring and demonstrating the capabilities of an existing LBNL modeling tool (TOUGH-FLAC) for simulating temperature-driven coupled flow and geomechanical processes in salt. This work includes development related to, and implementation of, essential capabilities, as well as testing the model against relevant information and published experimental data related to the fate and transport of water. we provide more details on the FY2014 work, first presenting updated tools and improvements made to the TOUGH-FLAC simulator, and the use of this updated tool in a new model simulation of long-term THM behavior within a generic repository in a salt formation. This is followed by the description of current benchmarking and validations efforts, including the TSDE experiment. We then present the current status in the development of constitutive relationships and the dual-continuum model for brine migration. We conclude with an outlook for FY2015, which will be much focused on model validation against field experiments and on the use of the model for the design studies related to a proposed heater experiment.

  8. Summary Results for Brine Migration Modeling Performed by LANL LBNL and SNL for the UFD Program.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L

    2014-09-01

    This report summarizes laboratory and field observations and numerical modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies conducted at Sandia, Los Alamos, and Berkeley National Laboratories. Interest into the disposal of heat-generating waste in salt has led to interest into water distribution and migration in both run-of-mine crushed and intact geologic salt. Ideally a fully coupled thermal-hydraulic-mechanical-chemical simulation is performed using numerical models with validated constitutive models and parameters. When mechanical coupling is not available, mechanical effects are prescribed in hydraulic models as source, boundary, or initial conditions. This report presents material associated with developing appropriate initial conditions for a non-mechanical hydrologic simulation of brine migration in salt. Due to the strong coupling between the mechanical and hydrologic problems, the initial saturation will be low for the excavation disturbed zone surrounding the excavation. Although most of the material in this report is not new, the author hopes it is presented in a format making it useful to other salt researchers.

  9. Development of a flow injection analysis method for the determination of acrylamide copolymers in oilfield brines

    SciTech Connect (OSTI)

    Taylor, K.C.; Burke, R.A.; Schramm, L.L. [Petroleum Recovery Inst., Calgary, Alberta (Canada); Nasr-El-Din, H.A. [Saudi Aramco, Dhahran (Saudi Arabia)

    1995-11-01

    An automated method for the determination of acrylamide polymers by flow injection analysis (FIA) has been developed and optimized for routine use. The method has been extensively tested for interferences common in oilfield brines. Potential interferences were examined from Na{sup +}, Ca{sup 2+}, Cr{sup 3+}, Al{sup 3+}, Zr{sup 3+}, NH{sub 4}{sup +}, Cl{sup {minus}}, OH{sup {minus}}, CO{sub 3}{sup 2{minus}}, sample coloration, and commonly used surfactants. The analysis is specific for amides, and the sensitivity to concentration of amide groups in the polymer was shown to be constant as the degree of polymer hydrolysis was varied. The range of the method is 0.1 to 100 mg/L. Sample throughput is 30 samples/h with triplicate analysis. Relative standard deviations of 0.2% are readily obtained from standard solutions and 0.5% from complex samples (at 50 mg/L). The method is applicable to the determination of aqueous, acrylamide-based polymers in process streams, surface waters and oilfield brines.

  10. Evaluation of brine disposal from the Bryan Mound site of the Strategic Petroleum Reserve Program. Final report

    SciTech Connect (OSTI)

    Hann, R.W. Jr.; Randall, R.E.

    1980-12-01

    The purpose of this report is to describe the environmental conditions found by the principal investigators during the predisposal study conducted from September 1977 through February 1980 prior to the start of brine discharge in March 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management. Volume 1 describes the results of the predisposal study, and it is divided into eight chapters entitled: Physical Oceanography, Analysis of the Discharge Plume, Water and Sediment Quality, Nekton, Benthos, Zooplankton, Phytoplankton, and Data Management. Volume 2 consists of appendices which contain additional supporting data in the form of figures and tables.

  11. Evaluation of brine disposal from the Bryan Mound site of the Strategic Petroleum Reserve Program. Final report

    SciTech Connect (OSTI)

    Hann, R.W. Jr.; Randall, R.E. (eds.)

    1980-12-01

    The purpose of this report is to describe the environmental conditions found by the principal investigators during the predisposal study conducted from September 1977 through February 1980 prior to the start of brine discharge in March 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management. Volume 1 describes the results of the predisposal study, and it is divided into eight chapters entitled: Physical Oceanography, Analsyis of the Discharge Plume, Water and Sediment Quality, Nekton, Benthos, Zooplankton, Phytoplankton, and Data Management. Volume 2 consists of appendices which contain additional supporting data in the form of figures and tables.

  12. Apparatus and method for separating constituents

    DOE Patents [OSTI]

    Maronde, Carl P. (McMurray, PA); Killmeyer, Jr., Richard P. (Pittsburgh, PA)

    1992-01-01

    A centrifugal separator apparatus and method for improving the efficiency of the separation of constituents in a fluid stream. A cyclone separator includes an assembly for separately discharging both constituents through the same end of the separator housing. A rotary separator includes a rotary housing having a baffle disposed therein for minimizing the differential rotational velocities of the constituents in the housing, thereby decreasing turbulence, and increasing efficiency. The intensity of the centrifugal force and the time which the constituents reside within the housing can be independently controlled to improve efficiency of separation.

  13. Pre-injection brine production for managing pressure in compartmentalized CO? storage reservoirs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO? storage that combines CO? injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO?. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO? injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO? injection directly informs reservoir managers about CO? storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be usedmore »directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.« less

  14. Waterflood and Enhanced Oil Recovery Studies using Saline Water and Dilute Surfactants in Carbonate Reservoirs 

    E-Print Network [OSTI]

    Alotaibi, Mohammed

    2012-02-14

    . In addition to seawater and dilute seawater (50, 20, 10, and 1 vol%), formation brine, shallow aquifer water, deionized water and different crude oil samples were used throughout this study. The crude oil/water/carbonates interactions were also investigated...

  15. Water 2013, 5, 480-504; doi:10.3390/w5020480 ISSN 2073-4441

    E-Print Network [OSTI]

    to characterize geochemical processes in a complex coastal groundwater system and to provide constraints of native groundwater, intruded seawater, non-native injected water, and oil-field brine water. In some with oil-field brines. Groundwater 3 H above 1 tritium unit (TU) was observed only in a few select wells

  16. Community Geothermal Technology Program: Electrodeposition of minerals in geothermal brine

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    Objective was to study the materials electrodeposited from geothermal brine, from the HGP-A well in Puna, Hawaii. Due to limitations, only one good set of electrodeposited material was obtained; crystallography indicates that vaterite forms first, followed by calcite and then perhaps aragonite as current density is increased. While the cost to weight ratio is reasonable, the deposition rate is very slow. More research is needed, such as reducing the brittleness. The electrodeposited material possibly could be used as building blocks, tables, benches, etc. 49 figs, 4 tabs, 7 refs.

  17. Reduced order models for prediction of groundwater quality impacts from CO? and brine leakage

    SciTech Connect (OSTI)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO? storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO? and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO? leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highly efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO? and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO? storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO? storage projects.

  18. Reduced order models for prediction of groundwater quality impacts from CO? and brine leakage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO? storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO? and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO? leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highlymore »efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO? and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO? storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO? storage projects.« less

  19. SOLVENT EXTRACTION OF PHENOLS FROM WATER

    E-Print Network [OSTI]

    Greminger, Douglas C.

    2012-01-01

    coking (Wurm, 1968) • Phenols are also the principal organic constituents in con- densate waters formed during coal

  20. Nonlinear Thermal Transport and Brine Convection in First Year Sea Ice

    E-Print Network [OSTI]

    temperature gradients and at greater depths in the ice. Preliminary modelling of the impact of brine migration of thermistors frozen into first­year Antarctic sea ice provides temperature against depth data, which is fitted on heat transport through first­year sea ice is presented. Diffusion­driven brine pocket migration

  1. Brine Rejection from Freezing Salt Solutions: A Molecular Dynamics Study Lubos Vrbka and Pavel Jungwirth*

    E-Print Network [OSTI]

    Zhigilei, Leonid V.

    Brine Rejection from Freezing Salt Solutions: A Molecular Dynamics Study Lubos Vrbka and Pavel process of brine rejection from freezing salt solutions is investigated with atomic resolution using. The presence of salt slows down the freezing process, which leads to the formation of an almost neat ice next

  2. Hazardous constituent source term. Revision 2

    SciTech Connect (OSTI)

    Not Available

    1994-11-17

    The Department of Energy (DOE) has several facilities that either generate and/or store transuranic (TRU)-waste from weapons program research and production. Much of this waste also contains hazardous waste constituents as regulated under Subtitle C of the Resource Conservation and Recovery Act (RCRA). Toxicity characteristic metals in the waste principally include lead, occurring in leaded rubber gloves and shielding. Other RCRA metals may occur as contaminants in pyrochemical salt, soil, debris, and sludge and solidified liquids, as well as in equipment resulting from decontamination and decommissioning activities. Volatile organic compounds (VOCS) contaminate many waste forms as a residue adsorbed on surfaces or occur in sludge and solidified liquids. Due to the presence of these hazardous constituents, applicable disposal regulations include land disposal restrictions established by Hazardous and Solid Waste Amendments (HSWA). The DOE plans to dispose of TRU-mixed waste from the weapons program in the Waste Isolation Pilot Plant (WIPP) by demonstrating no-migration of hazardous constituents. This paper documents the current technical basis for methodologies proposed to develop a post-closure RCRA hazardous constituent source term. For the purposes of demonstrating no-migration, the hazardous constituent source term is defined as the quantities of hazardous constituents that are available for transport after repository closure. Development of the source term is only one of several activities that will be involved in the no-migration demonstration. The demonstration will also include uncertainty and sensitivity analyses of contaminant transport.

  3. STUDIES ON THE USE OF CARBON DIOXIDE DISSOLVED IN REFRIGERATED BRINE FOR THE PRESERVATION OF WHOLE FISH

    E-Print Network [OSTI]

    STUDIES ON THE USE OF CARBON DIOXIDE DISSOLVED IN REFRIGERATED BRINE FOR THE PRESERVATION OF WHOLE in rockfish and chum salmon of dissolving carbon dioxide in brine. Storing the fish in the refrigerated brine treated with carbon dioxide inhibited the growth of the bacteria, retarded the rate at which the fish

  4. Chemical-equilibrium calculations for aqueous geothermal brines

    SciTech Connect (OSTI)

    Kerrisk, J.F.

    1981-05-01

    Results from four chemical-equilibrium computer programs, REDEQL.EPAK, GEOCHEM, WATEQF, and SENECA2, have been compared with experimental solubility data for some simple systems of interest with geothermal brines. Seven test cases involving solubilities of CaCO/sub 3/, amorphous SiO/sub 2/, CaSO/sub 4/, and BaSO/sub 4/ at various temperatures from 25 to 300/sup 0/C and in NaCl or HCl solutions of 0 to 4 molal have been examined. Significant differences between calculated results and experimental data occurred in some cases. These differences were traced to inaccuracies in free-energy or equilibrium-constant data and in activity coefficients used by the programs. Although currently available chemical-equilibrium programs can give reasonable results for these calculations, considerable care must be taken in the selection of free-energy data and methods of calculating activity coefficients.

  5. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    and  pumping  water  is  capital  and  energy  intensive,  such  as  geothermal  energy,  water  for  aquaculture,  substantial  capital,   energy,  and  water  demands  of  

  6. Sulfate Removal from Reject Brined in Inland Desalination with Zero Liquid Discharge 

    E-Print Network [OSTI]

    Almasri, Dema A

    2013-07-03

    Sulfate is one of the most problematic ions present in reject brine in desalination systems due to its high potential of scale formation and membrane fouling; making it an obstacle in the application of zero liquid discharge. ...

  7. Seizing a species : the story of the Great Salt Lake brine shrimp harvest

    E-Print Network [OSTI]

    Wotipka, Samuel Alex

    2014-01-01

    In the early 1950s, C.C. "Sparkplug" Sanders began harvesting brine shrimp from Utah's Great Salt Lake. Sanders built up a small business selling their eggs, called "cysts, to aquarium stores across the country. During the ...

  8. Up-Scaling Geochemical Reaction Rates Accompanying Acidic CO2-Saturated Brine Flow in Sandstone Aquifers

    E-Print Network [OSTI]

    New York at Stoney Brook, State University of

    1 Up-Scaling Geochemical Reaction Rates Accompanying Acidic CO2-Saturated Brine Flow in Sandstone in the pore networks corresponding to three different sandstones. The simulations were used to study up

  9. Brine Sampling and Evaluation Program 1992--1993 report and summary of BSEP data since 1982

    SciTech Connect (OSTI)

    Deal, D.E.; Abitz, R.J. [I. T. Corp., Carlsbad, NM (United States); Belski, D.S. [USDOE Albuquerque Operations Office, Carlsbad, NM (United States). Waste Isolation Pilot Plant Project Office

    1995-04-01

    This report is the last one that is currently scheduled in the sequence of reports of new data, and therefore, also includes summary comments referencing important data obtained by BSEP since 1983. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the (WIPP) Waste Isolation Pilot Plant. A project concern is that enough brine might be present after sealing and closure to generate large quantities of hydrogen gas by corroding the metal in the waste drums and waste inventory. This report describes progress made during the calendar years 1992 and 1993 and focuses on four major areas: (1) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes from the underground drifts; (2) observations of weeps in the Air Intake Shaft (AIS); (3) further characterization of brine geochemistry; and (4) additional characterization of the hydrologic conditions in the fractured zone beneath the excavations.

  10. Membrane Desalination of Agricultural Drainage Water: Water Recovery Enhancement and Brine Minimization

    E-Print Network [OSTI]

    Cohen, Yoram

    2008-01-01

    membranes for surface seawater desalination, Desalination,of R&D program in seawater desalination at KISR part I.pressure limit, while seawater desalination RO module are

  11. Membrane Desalination of Agricultural Drainage Water: Water Recovery Enhancement and Brine Minimization

    E-Print Network [OSTI]

    Cohen, Yoram

    2008-01-01

    Program, 2002. Desalination Demonstration Report for Buenaprior to RO membranes for surface seawater desalination,Desalination, 144 (2002) 353. P. Cote, J. Cadera, J. Coburn,

  12. Membrane Desalination of Agricultural Drainage Water: Water Recovery Enhancement and Brine Minimization

    E-Print Network [OSTI]

    Cohen, Yoram

    2008-01-01

    Intermediate Chemical Demineralization, Journal of MembraneIntegration of Chemical Demineralization with RO Membranei.e. , chemical demineralization) or desupersaturated to

  13. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    CO 2 ]  of  geothermal  heat,  desalination  water,  algae  geothermal  energy   extraction,  desalination,  salt  and  Geothermal  Energy  Systems CHP  Binary  Cycle Section  5.3  Non-­?potable  Water   NPV Reverse  Osmosis  Treatment Water  Sold  at  Desalination  

  14. Baryon Spectroscopy and the Constituent Quark Model

    SciTech Connect (OSTI)

    A.W. Thomas; R.D. Young

    2005-07-26

    We explore further the idea that the lattice QCD data for hadron properties in the region m[^2][_pi] > 0.2GeV^2 can be described by the constituent quark model. This leads to a natural explanation of the fact that nucleon excited states are generally stable for pion masses greater than their physical excitation energies. Finally, we apply these same ideas to the problem of how pentaquarks might behave in lattice QCD, with interesting conclusions.

  15. Hybrid States from Constituent Glue Model

    E-Print Network [OSTI]

    F. Iddir; L. Semlala

    2007-12-11

    The hybrid meson is one of the most interesting new hadron specie beyond the naive quark model. It acquire a great attention both from the theoretical and experimental efforts. Many good candidates have been claimed to be observed, but there is no absolute confirmation about existence of hybrid mesons. In the present work we propose new calculations of the masses and decay widths of the hybrid mesons in the context of constituent gluon model.

  16. Regional evaluation of brine management for geologic carbon sequestration

    E-Print Network [OSTI]

    Breunig, H.M.

    2014-01-01

    are: (1) geothermal energy, (2) desalination, (3) salt,desalination; saline water for cooling towers; makeup water for enhanced oil recovery (EOR) systems; and geothermal

  17. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    water  management  options,  including:  geothermal  energy   extraction,  desalination,  salt  and  mineral   harvesting,  

  18. Ambient methods and apparatus for rapid laser trace constituent analysis

    DOE Patents [OSTI]

    Snyder, Stuart C. (Idaho Falls, ID); Partin, Judy K. (Idaho Falls, ID); Grandy, Jon D. (Idaho Falls, ID); Jeffery, Charles L. (Blackfoot, ID)

    2002-01-01

    A method and apparatus are disclosed for measuring trace amounts of constituents in samples by using laser induced breakdown spectroscopy and laser induced fluorescence under ambient conditions. The laser induced fluorescence is performed at a selected wavelength corresponding to an absorption state of a selected trace constituent. The intensity value of the emission decay signal which is generated by the trace constituent is compared to calibrated emission intensity decay values to determine the amount of trace constituent present.

  19. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    SciTech Connect (OSTI)

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

    2013-04-01

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

  20. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    Area Southeast  Regional  Carbon  Sequestration  PartnershipCoast  Regional  Carbon  Sequestration  Partnership Water  West  Coast  Regional  Carbon  Sequestration  Partnership  (

  1. Regional evaluation of brine management for geologic carbon sequestration

    E-Print Network [OSTI]

    Breunig, H.M.

    2014-01-01

    produced water from the Barnett Shale in Texas to freshwatervolume treated in the Barnett Shale project is smaller than

  2. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    for  Geologic  Carbon  Sequestration. ”   International  of  Energy.  “Carbon  Sequestration  Atlas  of  the  Water  Extracted  from  Carbon  Sequestration  Projects."  

  3. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  4. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT STABILIZED BASIN 43 GROUNDWATER BRINE

    SciTech Connect (OSTI)

    COOKE GA; DUNCAN JB; LOCKREM LL

    2008-09-30

    This report is an initial report on the laboratory effort executed under RPP-PLAN-33338, Test Plan for the Assessment of Technetium Leachability in Cement-Stabilized Basin 43 Groundwater Brine. This report delineates preliminary data obtained under subcontract 21065, release 30, from the RJ Lee Group, Inc., Center for Laboratory Sciences. The report is predicated on CLS RPT-816, Draft Report: Assessment of Technetium Leachability in Cement Stabilized Basin 43 Groundwater Brine. This document will be revised on receipt of the final RJ Lee Group, Inc., Center for Laboratory Sciences report, which will contain data subjected to quality control and quality assurance criteria.

  5. New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry

    E-Print Network [OSTI]

    Girguis, Peter R.

    brine pool via in situ mass spectrometry Scott D. Wankel a , Samantha B. Joye b , Vladimir A. Samarkin b

  6. Brian G. Rahm, Ph.D. NYS Water Resources Institute

    E-Print Network [OSTI]

    Walter, M.Todd

    include fluids used during the drilling process to cool and lubricate the drill bit and motor: Brine & frac fluid ­ Also known as flowback and produced water, includes water used for hydraulic fracturing, as well as water naturally present within the shale. In the Marcellus Shale, frac fluids consist

  7. West Hackberry Strategic Petroleum Reserve site brine disposal monitoring, Year I report. Volume V. Supporting data for estuarine hydrology, discharge plume analysis, chemical oceanography, biological oceanography, and data management. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J.

    1983-02-01

    This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which located in southwestern Louisiana, and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Volume V contains appendices for the following: supporting data for estuarine hydrology and hydrography; supporting data analysis of discharge plume; supporting data for water and sediment chemistry; CTD/DO and pH profiles during biological monitoring; supporting data for nekton; and supporting data for data management.

  8. Pressure Buildup and Brine Migration During CO2 Storage in Multilayered Aquifers

    E-Print Network [OSTI]

    Zhou, Quanlin

    of resident brine caused by CCS operations require modeling/analysis tools of considerable complexity (Celia and may allow for effective pressure bleed-off in the storage reservoirs. This study presents, for uncertainty quantification, for parameter estimation, or for the optimization of pressure-management schemes

  9. NUMERICAL INVESTIGATION OF TEMPERATURE EFFECTS DURING THE INJECTION OF CARBON DIOXIDE INTO BRINE

    E-Print Network [OSTI]

    Cirpka, Olaf Arie

    NUMERICAL INVESTIGATION OF TEMPERATURE EFFECTS DURING THE INJECTION OF CARBON DIOXIDE INTO BRINE for the simulation of carbon dioxide injection into geological formations is currently an intensive field of research reservoir scenario. 1. INTRODUCTION Recent investigations of underground carbon dioxide storage

  10. Constraints on origin and evolution of Red Sea brines from helium and argon isotopes

    E-Print Network [OSTI]

    Aeschbach-Hertig, Werner

    mantle production ratio. In the Kebrit Deep, located in the northern Red Sea, we found a helium excessConstraints on origin and evolution of Red Sea brines from helium and argon isotopes Gisela, the Discovery and the Kebrit Deep, were sampled and analyzed for helium and argon isotopes. We identified two

  11. Don Juan Pond, Antarctica: Near-surface CaCl2-brine feeding Earth's most saline

    E-Print Network [OSTI]

    Marchant, David R.

    Don Juan Pond, Antarctica: Near-surface CaCl2-brine feeding Earth's most saline lake on Earth. We report on new studies of Don Juan Pond (DJP), which exists at the upper limit of ephemeral on Juan Pond (DJP), found at the lowest point in the South Fork of Upper Wright Valley, Antarctica (Figure

  12. Geochemical evidence for possible natural migration of Marcellus Formation brine to

    E-Print Network [OSTI]

    Jackson, Robert B.

    of stray gas, metal-rich formation brines, and hydrau- lic fracturing and/or flowback fluids to drinking- ical evidence from northeastern Pennsylvania showing that path- ways, unrelated to recent drilling rapid shale-gas development in the re- gion; however, the presence of these fluids suggests conductive

  13. Electromagnetic form factors and the hypercentral constituent quark model

    SciTech Connect (OSTI)

    Sanctis, M. De; Giannini, M. M.; Santopinto, E.; Vassallo, A.

    2007-12-15

    We present new results concerning the electromagnetic form factors of the nucleon using a relativistic version of the hypercentral constituent quark model and a relativistic current.

  14. GEOCHEMICAL INVESTIGATIONS OF CO?-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    Increased output of greenhouse gases, particularly carbon dioxide (CO?), into the atmosphere from anthropogenic sources is of great concern. A potential technology to reduce CO? emissions is geologic carbon sequestration. This technology is currently being evaluated in the United States and throughout the world. The geology of the Illinois Basin exhibits outstanding potential as a carbon sequestration target, as demonstrated by the ongoing Illinois Basin – Decatur Project that is using the Mt. Simon Sandstone reservoir and Eau Claire Shale seal system to store and contain 1 million tonnes of CO?. The Knox Group-Maquoketa Shale reservoir and seal system, located stratigraphically above the Mt. Simon Sandstone-Eau Claire Shale reservoir and seal system, has little economic value as a resource for fossil fuels or as a potable water source, making it ideal as a potential carbon sequestration target. In order for a reservoir-seal system to be effective, it must be able to contain the injected CO? without the potential for the release of harmful contaminants liberated by the reaction between CO?-formation fluids and reservoir and seal rocks. This study examines portions of the Knox Group (Potosi Dolomite, Gunter Sandstone, New Richmond Sandstone) and St. Peter Sandstone, and Maquoketa Shale from various locations around the Illinois Basin. A total of 14 rock and fluid samples were exposed to simulated sequestration conditions (9101–9860 kPa [1320–1430 psi] and 32°–42°C [90°– 108°F]) for varying amounts of time (6 hours to 4 months). Knox Group reservoir rocks exhibited dissolution of dolomite in the presence of CO? as indicated by petrographic examination, X-ray diffraction analysis, and fluid chemistry analysis. These reactions equilibrated rapidly, and geochemical modeling confirmed that these reactions reached equilibrium within the time frames of the experiments. Pre-reaction sample mineralogy and postreaction fluid geochemistry from this study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO? injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO? and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  15. Food Saving in Texas: Drying, Brining, Canning, Curing. 

    E-Print Network [OSTI]

    Simpson, Cornelia

    1917-01-01

    , Home-made Hot Water Canner. A V E R A G E COMPOSITION OF FRESH A N D DRIED FRUITS. (From U. S. D. A . Bulletin 293 . ) FRESH FRUITS. K I N D Water Protein Ether Extract Zarbohydrates A s h Calories Per L b . Apples 84.-6 0.4 0.5 14.2 0.3 290 Figs.... BERRIES—can, bottled juice, jelly, preserves and jam. QUINCES—preserve and marmalade, jelly. CHERRIES—can, preserve. APRICOTS—dry, can, preserve and marmalade. MELON RINDS—preserve. W I N T E R G A R D E N S A N D HOT BEDS. Collards Green Onions...

  16. Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration

    SciTech Connect (OSTI)

    Goddard, William

    2012-11-30

    To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

  17. Energy optimization in ice hockey halls I. The system COP as a multivariable function, brine and design choices

    E-Print Network [OSTI]

    Andrea Ferrantelli; Paul Melóis; Miska Räikkönen; Martti Viljanen

    2013-05-03

    This work is the first in a series of articles addressing the energy optimization in ice hockey halls. Here we adopt an analytical method, called functional optimization, to find which design and operating conditions maximize the Coefficient Of Performance of the entire cooling system (brine pumps and cooling tower), which we call ${\\rm COP}_{sys}$. This is addressed as a function of several variables, like electric consumption and brine physical properties. By maximizing such function, the best configuration and brine choices for the system can thus be determined accurately and rigorously. We investigate the importance of pipe diameter, depth and brine type (ethylene glycol and ammonia) for average-sized ice rinks. An optimal brine density is found, and we compute the weight of the electric consumption of the brine pumps on ${\\rm COP}_{sys}$. Our formulas are validated with heat flow measurement data obtained at an ice hockey hall in Finland. They are also confronted with technical and cost-related constraints, and implemented by simulations with the program COMSOL Multiphysics. The multivariable approach here discussed is general, and can be applied to the rigorous preliminary study of diverse situations in building physics and in many other areas of interest.

  18. Field Validation of Toxicity Tests to Evaluate the Potential for Beneficial Use of Produced Water

    SciTech Connect (OSTI)

    Joseph Bidwell; Jonathan Fisher; Naomi Cooper

    2008-03-31

    This study investigated potential biological effects of produced water contamination derived from occasional surface overflow and possible subsurface intrusion at an oil production site along the shore of Skiatook Lake, Oklahoma. We monitored basic chemistry and acute toxicity to a suite of standard aquatic test species (fathead minnow-Pimephales promelas, Daphnia pulex, Daphnia magna, and Ceriodaphnia dubia) in produced water and in samples taken from shallow groundwater wells on the site. Toxicity identification evaluations and ion toxicity modeling were used to identify toxic constituents in the samples. Lake sediment at the oil production site and at a reference site were also analyzed for brine intrusion chemically and by testing sediment toxicity using the benthic invertebrates, Chironomus dilutus, and Hyallela azteca. Sediment quality was also assessed with in situ survival and growth studies with H. azteca and the Asian clam, Corbicula fluminea, and by benthic macroinvertebrate community sampling. The produced water was acutely toxic to the aquatic test organisms at concentrations ranging from 1% to 10% of the whole produced water sample. Toxicity identification evaluation and ion toxicity modeling indicated major ion salts and hydrocarbons were the primary mixture toxicants. The standardized test species used in the laboratory bioassays exhibited differences in sensitivity to these two general classes of contaminants, which underscores the importance of using multiple species when evaluating produced water toxicity. Toxicity of groundwater was greater in samples from wells near a produced water injection well and an evaporation pond. Principle component analyses (PCA) of chemical data derived from the groundwater wells indicated dilution by lake water and possible biogeochemical reactions as factors that ameliorated groundwater toxicity. Elevated concentrations of major ions were found in pore water from lake sediments, but toxicity from these ions was limited to sediment depths of 10 cm or greater, which is outside of the primary zone of biological activity. Further, exposure to site sediments did not have any effects on test organisms, and macroinvertebrate communities did not indicate impairment at the oil production site as compared to a reference site. In situ experiments with H. azteca and C. fluminea, indicated a sublethal site effect (on growth of both species), but these could not be definitively linked with produced water infiltration. Severe weather conditions (drought followed by flooding) negatively influenced the intensity of lake sampling aimed at delineating produced water infiltration. Due to the lack of clear evidence of produced water infiltration into the sub-littoral zone of the lake, it was not possible to assess whether the laboratory bioassays of produced water effectively indicate risk in the receiving system. However, the acutely toxic nature of the produced water and general lack of biological effects in the lake at the oil production site suggest minimal to no produced water infiltration into surficial lake sediments and the near-shore water column. This study was able to demonstrate the utility of ion toxicity modeling to support data from toxicity identification evaluations aimed at identifying key toxic constituents in produced water. This information could be used to prioritize options for treating produced water in order to reduce toxic constituents and enhance options for reuse. The study also demonstrated how geographic information systems, toxicity modeling, and toxicity assessment could be used to facilitate future site assessments.

  19. Fresh Water Generation from Aquifer-Pressured Carbon Storage

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Bourcier, W L; Wolfe, T; Haussmann, C

    2010-02-19

    Can we use the pressure associated with sequestration to make brine into fresh water? This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). Possible products are: Drinking water, Cooling water, and Extra aquifer space for CO{sub 2} storage. The conclusions are: (1) Many saline formation waters appear to be amenable to largely conventional RO treatment; (2) Thermodynamic modeling indicates that osmotic pressure is more limiting on water recovery than mineral scaling; (3) The use of thermodynamic modeling with Pitzer's equations (or Extended UNIQUAC) allows accurate estimation of osmotic pressure limits; (4) A general categorization of treatment feasibility is based on TDS has been proposed, in which brines with 10,000-85,000 mg/L are the most attractive targets; (5) Brines in this TDS range appear to be abundant (geographically and with depth) and could be targeted in planning future CCS operations (including site selection and choice of injection formation); and (6) The estimated cost of treating waters in the 10,000-85,000 mg/L TDS range is about half that for conventional seawater desalination, due to the anticipated pressure recovery.

  20. Relating polymer matrix composite delamination behavior to constituent properties

    E-Print Network [OSTI]

    Gregory, Jeremy R. (Jeremy Ryan), 1976-

    2004-01-01

    Developing predictive capabilities of composite material behavior from constituent properties is an important component of accelerating materials insertion. Many models exist that accomplish this objective for a range of ...

  1. Innovative MIOR Process Utilizing Indigenous Reservoir Constituents

    SciTech Connect (OSTI)

    D. O. Hitzman; A. K. Stepp; D. M. Dennis; L. R. Graumann

    2003-03-31

    This research program is directed at improving the knowledge of reservoir ecology and developing practical microbial solutions for improving oil production. The goal is to identify indigenous microbial populations which can produce beneficial metabolic products and develop a methodology to stimulate those select microbes with nutrient amendments to increase oil recovery. This microbial technology has the capability of producing multiple oil-releasing agents. Experimental laboratory work is underway. Microbial cultures have been isolated from produced water samples. Comparative laboratory studies demonstrating in situ production of microbial products as oil recovery agents were conducted in sand packs with natural field waters with cultures and conditions representative of oil reservoirs. Field pilot studies are underway.

  2. Thermal denitration and mineralization of waste constituents

    SciTech Connect (OSTI)

    Nenni, J.A.; Boardman, R.D.

    1997-08-01

    In order to produce a quality grout from LLW using hydraulic cements, proper conditioning of the waste is essential for complete cement curing. Several technologies were investigated as options for conditions. Since the LLW is dilute, removal of all, or most, of the water will significantly reduce the final waste volume. Neutralization of the LLW is also desirable since acidic liquids to not allow cement to cure properly. The nitrate compounds are very soluble and easily leached from solid waste forms; therefore, denitration is desirable. Thermal and chemical denitration technologies have the advantages of water removal, neutralization, and denitration. The inclusion of additives during thermal treatment were investigated as a method of forming insoluable waste conditions.

  3. INNOVATIVE MIOR PROCESS UTILIZING INDIGENOUS RESERVOIR CONSTITUENTS

    SciTech Connect (OSTI)

    D.O. Hitzman; A.K. Stepp; D.M. Dennis; L.R. Graumann

    2003-09-01

    This research program was directed at improving the knowledge of reservoir ecology and developing practical microbial solutions and technologies for improving oil production. The goal was to identify and utilize indigenous microbial populations which can produce beneficial metabolic products and develop a methodology to stimulate those select microbes with nutrient amendments to increase oil recovery. This microbial technology has the capability of producing multiple oil-releasing agents. Experimental laboratory work in model sandpack cores was conducted using microbial cultures isolated from produced water samples. Comparative laboratory studies demonstrating in situ production of microbial products as oil recovery agents were conducted in sand packs with natural field waters using cultures and conditions representative of oil reservoirs. Increased oil recovery in multiple model sandpack systems was achieved and the technology and results were verified by successful field studies. Direct application of the research results has lead to the development of a feasible, practical, successful, and cost-effective technology which increases oil recovery. This technology is now being commercialized and applied in numerous field projects to increase oil recovery. Two field applications of the developed technology reported production increases of 21% and 24% in oil recovery.

  4. Fresh Water Generation from Aquifer-Pressured Carbon Storage: Interim Progress Report

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Hao, Y; Bourcier, W L

    2009-07-22

    This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including nanofiltration (NF) and reverse osmosis (RO). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine would be reinjected into the formation at net volume reduction. This process provides additional storage space (capacity) in the aquifer, reduces operational risks by relieving overpressure in the aquifer, and provides a source of low-cost fresh water to offset costs or operational water needs. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations for brines typical of CCS sites. Computer modeling is being used to evaluate processes in the aquifer, including the evolution of the pressure field. This progress report deals mainly with our geochemical modeling of high-salinity brines and covers the first six months of project execution (September, 2008 to March, 2009). Costs and implementation results will be presented in the annual report. The brines typical of sequestration sites can be several times more concentrated than seawater, requiring specialized modeling codes typical of those developed for nuclear waste disposal calculations. The osmotic pressure developed as the brines are concentrated is of particular concern, as are precipitates that can cause fouling of reverse osmosis membranes and other types of membranes (e.g., NF). We have now completed the development associated with tasks (1) and (2) of the work plan. We now have a contract with Perlorica, Inc., to provide support to the cost analysis and nanofiltration evaluation. We have also conducted several preliminary analyses of the pressure effect in the reservoir in order to confirm that reservoir pressure can indeed be used to drive the reverse osmosis process. Our initial conclusions from the work to date are encouraging: (1) The concept of aquifer-pressured RO to provide fresh water associated with carbon dioxide storage appears feasible. (2) Concentrated brines such as those found in Wyoming are amenable to RO treatment. We have looked at sodium chloride brines from the Nugget Formation in Sublette County. 20-25% removal with conventional methods is realistic; higher removal appears achievable with NF. The less concentrated sulfate-rich brines from the Tensleep Formation in Sublette County would support >80% removal with conventional RO. (3) Brines from other proposed sequestration sites can now be analyzed readily. An osmotic pressure curve appropriate to these brines can be used to evaluate cost and equipment specifications. (4) We have examined a range of subsurface brine compositions that is potentially pertinent to carbon sequestration and noted the principal compositional trends pertinent to evaluating the feasibility of freshwater extraction. We have proposed a general categorization for the feasibility of the process based on total dissolved solids (TDS). (5) Withdrawing pressurized brine can have a very beneficial effect on reservoir pressure and total available storage capacity. Brine must be extracted from a deeper location in the aquifer than the point of CO{sub 2} injection to prevent CO{sub 2} from migrating to the brine extraction well.

  5. Brine migration test for Asse Mine, Federal Republic of Germany: final test plan

    SciTech Connect (OSTI)

    Not Available

    1983-07-01

    The United States and the Federal Republic of Germany (FRG) will conduct a brine migration test in the Asse Salt Mine in the FRG as part of the US/FRG Cooperative Radioactive Waste Management Agreement. Two sets of two tests each will be conducted to study both liquid inclusion migration and vapor migration in the two salt types chosen for the experiments: (1) pure salt, for its characteristics similar to the salt that might occur in potential US repositories, and (2) transitional salt, for its similarity to the salt that might occur in potential repositories in Germany.

  6. Advanced biochemical processes for geothermal brines FY 1998 annual operating plan

    SciTech Connect (OSTI)

    1997-10-01

    As part of the overall Geothermal Energy Research which is aimed at the development of economical geothermal resources production systems, the aim of the Advanced Biochemical Processes for Geothermal Brines (ABPGB) effort is the development of economic and environmentally acceptable methods for disposal of geothermal wastes and conversion of by-products to useful forms. Methods are being developed for dissolution, separation and immobilization of geothermal wastes suitable for disposal, usable in inert construction materials, suitable for reinjection into the reservoir formation, or used for recovery of valuable metals.

  7. Methods of using adsorption media for separating or removing constituents

    DOE Patents [OSTI]

    Tranter, Troy J. (Idaho Falls, ID); Herbst, R. Scott (Idaho Falls, ID); Mann, Nicholas R. (Blackfoot, ID); Todd, Terry A. (Aberdeen, ID)

    2011-10-25

    Methods of using an adsorption medium to remove at least one constituent from a feed stream. The method comprises contacting an adsorption medium with a feed stream comprising at least one constituent and removing the at least one constituent from the feed stream. The adsorption medium comprises a polyacrylonitrile (PAN) matrix and at least one metal hydroxide homogenously dispersed therein. The adsorption medium may comprise from approximately 15 wt % to approximately 90 wt % of the PAN and from approximately 10 wt % to approximately 85 wt % of the at least one metal hydroxide. The at least one metal hydroxide may be selected from the group consisting of ferric hydroxide, zirconium hydroxide, lanthanum hydroxide, cerium hydroxide, titanium hydroxide, copper hydroxide, antimony hydroxide, and molybdenum hydroxide.

  8. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    SciTech Connect (OSTI)

    Bacon, Diana H. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Dai, Zhenxue [Los Alamos National Laboratory, Los Alamos, NM (United States); Zheng, Liange [Lawrence Berkeley National Laboratory, Berkeley, CA (United States)

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2 leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.

  9. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more »leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  10. Brine migration test report: Asse Salt Mine, Federal Republic of Germany: Technical report

    SciTech Connect (OSTI)

    Coyle, A.J.; Eckert, J.; Kalia, H.

    1987-01-01

    This report presents a summary of Brine Migration Tests which were undertaken at the Asse mine of the Federal Republic of Germany (FRG) under a bilateral US/FRG agreement. This experiment simulates a nuclear waste repository at the 800-m (2624-ft) level of the Asse salt mine in the Federal Republic of Germany. This report describes the Asse salt mine, the test equipment, and the pretest properties of the salt in the mine and in the vicinity of the test area. Also included are selected test data (for the first 28 months of operation) on the following: brine migration rates, thermomechaical behavior of the salt (including room closure, stress reading, and thermal profiles), borehole gas pressures, and borehole gas analyses. In addition to field data, laboratory analyses of pretest salt properties are included in this report. The operational phase of these experiments was completed on October 4, 1985, with the commencement of cooldown and the start of posttest activities. 7 refs., 68 figs., 48 tabs.

  11. Sensitivity study of CO2 storage capacity in brine aquifers withclosed boundaries: Dependence on hydrogeologic properties

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Rutqvist, J.; Tsang, C-F.

    2007-02-07

    In large-scale geologic storage projects, the injected volumes of CO{sub 2} will displace huge volumes of native brine. If the designated storage formation is a closed system, e.g., a geologic unit that is compartmentalized by (almost) impermeable sealing units and/or sealing faults, the native brine cannot (easily) escape from the target reservoir. Thus the amount of supercritical CO{sub 2} that can be stored in such a system depends ultimately on how much pore space can be made available for the added fluid owing to the compressibility of the pore structure and the fluids. To evaluate storage capacity in such closed systems, we have conducted a modeling study simulating CO{sub 2} injection into idealized deep saline aquifers that have no (or limited) interaction with overlying, underlying, and/or adjacent units. Our focus is to evaluate the storage capacity of closed systems as a function of various reservoir parameters, hydraulic properties, compressibilities, depth, boundaries, etc. Accounting for multi-phase flow effects including dissolution of CO{sub 2} in numerical simulations, the goal is to develop simple analytical expressions that provide estimates for storage capacity and pressure buildup in such closed systems.

  12. Method for verification of constituents of a process stream

    DOE Patents [OSTI]

    Baylor, L.C.; Buchanan, B.R.; O`Rourke, P.E.

    1993-01-01

    This invention is comprised of a method for validating a process stream for the presence or absence of a substance of interest such as a chemical warfare agent; that is, for verifying that a chemical warfare agent is present in an input line for feeding the agent into a reaction vessel for destruction, or, in a facility for producing commercial chemical products, that a constituent of the chemical warfare agent has not been substituted for the proper chemical compound. The method includes the steps of transmitting light through a sensor positioned in the feed line just before the chemical constituent in the input line enters the reaction vessel, measuring an optical spectrum of the chemical constituent from the light beam transmitted through it, and comparing the measured spectrum to a reference spectrum of the chemical agent and preferable also reference spectra of surrogates. A signal is given if the chemical agent is not entering a reaction vessel for destruction, or if a constituent of a chemical agent is added to a feed line in substitution of the proper chemical compound.

  13. 2. INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 STUDY OF WATERFLOODING PROCESS IN NATURALLY FRACTURED

    E-Print Network [OSTI]

    Schechter, David S.

    - 31 - 2. INVESTIGATION OF CRUDE OIL/BRINE/ROCK INTERACTION 2.1 STUDY OF WATERFLOODING PROCESS plays an important role in oil recovery from the naturally fractured Spraberry Trend Area. Therefore are important. We examined these issues by performing static and dynamic imbibition experiments. Oil recoveries

  14. Macro-and Microscale Waterflooding Performances of Crudes which form w/o Emulsions upon Mixing with Brines

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    the reservoir brine. These crudes are obtained from a large oil field with stock tank oil viscositiesMacro- and Microscale Waterflooding Performances of Crudes which form w/o Emulsions upon Mixing ABSTRACT: We study the micro- and macroscale waterflooding performances of unusual crudes which naturally

  15. Unnatural landscapes in ecology: Generating the spatial distribution of brine spills

    SciTech Connect (OSTI)

    Jager, Yetta [ORNL; Efroymson, Rebecca Ann [ORNL; Sublette, K. [University of Tulsa; Ashwood, Tom L [ORNL

    2005-01-01

    Quantitative tools are needed to evaluate the ecological effects of increasing petroleum production. In this article, we describe two stochastic models for simulating the spatial distribution of brine spills on a landscape. One model uses general assumptions about the spatial arrangement of spills and their sizes; the second model distributes spills by siting rectangular well complexes and conditioning spill probabilities on the configuration of pipes. We present maps of landscapes with spills produced by the two methods and compare the ability of the models to reproduce a specified spill area. A strength of the models presented here is their ability to extrapolate from the existing landscape to simulate landscapes with a higher (or lower) density of oil wells.

  16. The deep hydrogeologic flow system underlying the Oak Ridge Reservation -- Assessing the potential for active groundwater flow and origin of the brine

    SciTech Connect (OSTI)

    Nativ, R.; Halleran, A.; Hunley, A.

    1997-08-01

    The deep hydrogeologic system underlying the Oak Ridge Reservation (ORR) contains contaminants such as radionuclides, heavy metals, nitrates, and organic compounds. The groundwater in the deep system is saline and has been considered to be stagnant in previous studies. This study was designed to address the following questions: is groundwater in the deep system stagnant; is contaminant migration controlled by diffusion only or is advection a viable mechanism; where are the potential outlet points? On the basis of existing and newly collected data, the nature of saline groundwater flow and potential discharge into shallow, freshwater systems was assessed. Data used for this purpose included (1) spatial and temporal pressures and hydraulic heads measured in the deep system, (2) hydraulic parameters of the formations in question, (3) spatial and temporal temperature variations at depth, and (4) spatial and temporal chemical and isotopic composition of the saline groundwater. The observations suggest that the saline water contained at depth is old but not isolated (in terms of recharge and discharge) from the overlying active, freshwater-bearing units. Influx of recent water does occur. Groundwater volumes involved in this flow are likely to be small. The origin of the saline groundwater was assessed by using existing and newly acquired chemical and isotopic data. The proposed model that best fits the data is modification of residual brine from which halite has been precipitated. Other models, such as ultrafiltration and halite dissolution, were also evaluated.

  17. Transformations of inorganic coal constituents in combustion systems

    SciTech Connect (OSTI)

    Helble, J.J.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. (PSI Technology Co., Andover, MA (United States)); Kang, Shin-Gyoo; Sarofim, A.F.; Beer, J.M. (Massachusetts Inst. of Tech., Cambridge, MA (United States)); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. (Arizona Univ., Tucson, AZ (United States)); Shah, N.; Huggins, F.E.; Huffman, G.P. (Kentucky Univ., Lexington, KY (United States))

    1991-09-01

    The technical objectives of this project are: (1) To define the partitioning of inorganic constituents associated with raw coal particles among products (including vapors, aerosols, and residual char/ash particles) formed under conditions representative of pulverized coal flames as a function of the specific (intrinsic and extrinsic) characteristics of the raw coal and the environment in which the transformations occur; and to characterize the resultant spectrum of products in detail. (2) To elucidate and quantify the fundamental processes (involving basic principles of physics, chemistry, thermodynamics) by which transformations of the inorganic constituents occur; and (3) to develop, based on the information required in (1) and (2), a tractable process'' model capable of predicting the significant features of the transformation process, most importantly, the nature and distribution of products. 26 refs., 151 figs., 51 tabs.

  18. REE Sorption Study on sieved -50 +100 mesh fraction of Media #1 in Brine #1 with Different Starting pH's at 70C

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gary Garland

    2015-09-29

    This is a continuation of the REE sorption study for shaker bath tests on 2g media #1 in 150mL brine #1 with different starting pH's at 70C. In a previous submission we reported data for shaker bath tests for brine #1 with starting pH's of 3.5, 4.5 and 5.5. In this submission we these pH's compared to starting brine #1 pH's of 6, and 7.

  19. Identifying Potential Land Use-derived Solute Sources to Stream Baseflow Using Ground Water Models and GIS

    E-Print Network [OSTI]

    to assess the impact of different baseflow solute contributions to surface water chemistry. Numerous field systems, locations of oil brine fields and high- density human populations) likely exist. Impacts of otherBoutt 1 Identifying Potential Land Use-derived Solute Sources to Stream Baseflow Using Ground Water

  20. Removal of Radionuclides from Waste Water at Fukushima Daiichi Nuclear Power Plant: Desalination and Adsorption Methods - 13126

    SciTech Connect (OSTI)

    Kani, Yuko; Kamosida, Mamoru; Watanabe, Daisuke [Hitachi Research Laboratory, Hitachi, Ltd., 7-2-1 Omika-cho, Hitachi, Ibaraki, 319-1221 (Japan)] [Hitachi Research Laboratory, Hitachi, Ltd., 7-2-1 Omika-cho, Hitachi, Ibaraki, 319-1221 (Japan); Asano, Takashi; Tamata, Shin [Hitachi Works, Hitachi-GE Nuclear Energy, Ltd. (Japan)] [Hitachi Works, Hitachi-GE Nuclear Energy, Ltd. (Japan)

    2013-07-01

    Waste water containing high levels of radionuclides due to the Fukushima Daiichi Nuclear Power Plant accident, has been treated by the adsorption removal and reverse-osmosis (RO) desalination to allow water re-use for cooling the reactors. Radionuclides in the waste water are collected in the adsorbent medium and the RO concentrate (RO brine) in the water treatment system currently operated at the Fukushima Daiichi site. In this paper, we have studied the behavior of radionuclides in the presently applied RO desalination system and the removal of radionuclides in possible additional adsorption systems for the Fukushima Daiichi waste water treatment. Regarding the RO desalination system, decontamination factors (DFs) of the elements present in the waste water were obtained by lab-scale testing using an RO unit and simulated waste water with non-radioactive elements. The results of the lab-scale testing using representative elements showed that the DF for each element depended on its hydrated ionic radius: the larger the hydrated ionic radius of the element, the higher its DF is. Thus, the DF of each element in the waste water could be estimated based on its hydrated ionic radius. For the adsorption system to remove radionuclides more effectively, we studied adsorption behavior of typical elements, such as radioactive cesium and strontium, by various kinds of adsorbents using batch and column testing. We used batch testing to measure distribution coefficients (K{sub d}s) for cesium and strontium onto adsorbents under different brine concentrations that simulated waste water conditions at the Fukushima Daiichi site. For cesium adsorbents, K{sub d}s with different dependency on the brine concentration were observed based on the mechanism of cesium adsorption. As for strontium, K{sub d}s decreased as the brine concentration increased for any adsorbents which adsorbed strontium by intercalation and by ion exchange. The adsorbent titanium oxide had higher K{sub d}s and it was used for the column testing to obtain breakthrough curves under various conditions of pH and brine concentration. The breakthrough point had a dependency on pH and the brine concentration. We found that when the pH was higher or the brine concentration was lower, the longer it took to reach the breakthrough point. The inhibition of strontium adsorption by alkali earth metals would be diminished for conditions of higher pH and lower brine concentration. (authors)

  1. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additionalmore »wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in injection rate over the no-extraction base case. However, the practical impacts on capital costs suggest that this strategy is fiscally ineffective when evaluated solely on this metric, with extraction reducing injection well needs by only one per 56 (1x case) or one per 13 (4x case).« less

  2. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    SciTech Connect (OSTI)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additional wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in injection rate over the no-extraction base case. However, the practical impacts on capital costs suggest that this strategy is fiscally ineffective when evaluated solely on this metric, with extraction reducing injection well needs by only one per 56 (1x case) or one per 13 (4x case).

  3. Benefits and costs of brine extraction for increasing injection efficiency in geologic CO2 sequestration

    SciTech Connect (OSTI)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-01-01

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additional wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in injection rate over the no-extraction base case. However, the practical impacts on capital costs suggest that this strategy is fiscally ineffective when evaluated solely on this metric, with extraction reducing injection well needs by only one per 56 (1x case) or one per 13 (4x case).

  4. Analytical methods for removing radiological constituents prior to organic analysis

    SciTech Connect (OSTI)

    Hakonson, K.; Monagle, M.; Cournoyer, M.

    1997-12-31

    Within the Department of Energy (DOE), there is a need to analyze mixed waste materials (i.e. materials that are contaminated with both radiological and hazardous components). As part of the technical support the Organic Analysis Group provides for programs within Los Alamos National Laboratory, methods are under development for radiologically contaminated oil samples being tested for polychlorinated biphenyls and other semivolatile constituents. Radionuclides are removed from oil samples by filtering the samples through a commercials available solid phase extraction cartridge. An aliquot of the eluent is then analyzed to quantitate the residual radioactivity.

  5. Hanford ferrocyanide reactivity: Effects of other tank constituents

    SciTech Connect (OSTI)

    Scheele, R.D.; Burger, L.L.; Tingey, J.M.; Johnston, J.W.; Sell, R.L.

    1993-04-01

    This paper presents results of studies using synthetic chemicals to determine the effect of other potential waste constituents on the reactivity and explosivity of Hanford ferrocyanide wastes. These studies have shown that either individually or in combination some of the tested additives (sodium ethylenediaminetetraacetate and the hydroxide precipitates of iron (III), chromium (III), and nickel] can at a concentration of 0.03 mole/mole ferrocyanide reduce the time to explosion of a near-stoichiometric mixture of sodium nickel ferrocyanide and equimolar sodium nitrate and nitrite. These studies also found no reduction in observed minimum explosion temperature of 293{degrees}C.

  6. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO?-acidified brines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO?-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO? exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution featuresmore »including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO?-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO? exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.« less

  7. Selenium Biotransformations in an Engineered Aquatic Ecosystem for Bioremediation of Agricultural Wastewater via Brine Shrimp

    E-Print Network [OSTI]

    Selenium Biotransformations in an Engineered Aquatic Ecosystem for Bioremediation of Agricultural. Freeman*,,#, Department of Land, Air and Water Resources, University of California, Davis, California, Water Management Research Division, Parlier, California 93648, United States Biological Sciences

  8. Water Management in A PEMFC: Water Transport Mechanism and Material

    E-Print Network [OSTI]

    Kandlikar, Satish

    , 2010; accepted October 09, 2011 1 Introduction Polymer electrolyte membrane fuel cells (PEMFCs) and the resulting drying and/or flooding in the constituent components. In current PEMFC technologies, water content flood, and block the pores of the CLs, GDLs, and gas chan- nels. Both a dry membrane and flooded

  9. Modifications of Carbonate Fracture Hydrodynamic Properties by CO{sub 2}-Acidified Brine Flow

    SciTech Connect (OSTI)

    Deng, Hang; Ellis, Brian R.; Peters, Catherine A.; Fitts, Jeffrey P.; Crandall, Dustin; Bromhal, Grant S.

    2013-08-01

    Acidic reactive flow in fractures is relevant in subsurface activities such as CO{sub 2} geological storage and hydraulic fracturing. Understanding reaction-induced changes in fracture hydrodynamic properties is essential for predicting subsurface flows such as leakage, injectability, and fluid production. In this study, x-ray computed tomography scans of a fractured carbonate caprock were used to create three dimensional reconstructions of the fracture before and after reaction with CO{sub 2}-acidified brine (Ellis et al., 2011, Greenhouse Gases: Sci. Technol., 1:248-260). As expected, mechanical apertures were found to increase substantially, doubling and even tripling in some places. However, the surface geometry evolved in complex ways including ‘comb-tooth’ structures created from preferential dissolution of calcite in transverse sedimentary bands, and the creation of degraded zones, i.e. porous calcite-depleted areas on reacted fracture surfaces. These geometric alterations resulted in increased fracture roughness, as measured by surface Z{sub 2} parameters and fractal dimensions D{sub f}. Computational fluid dynamics (CFD) simulations were conducted to quantify the changes in hydraulic aperture, fracture transmissivity and permeability. The results show that the effective hydraulic apertures are smaller than the mechanical apertures, and the changes in hydraulic apertures are nonlinear. Overestimation of flow rate by a factor of two or more would be introduced if fracture hydrodynamic properties were based on mechanical apertures, or if hydraulic aperture is assumed to change proportionally with mechanical aperture. The differences can be attributed, in part, to the increase in roughness after reaction, and is likely affected by contiguous transverse sedimentary features. Hydraulic apertures estimated by the 1D statistical model and 2D local cubic law (LCL) model are consistently larger than those calculated from the CFD simulations. In addition, a novel ternary segmentation method was devised to handle the degraded zones, allowing for a bounding analysis of the effects on hydraulic properties. We found that the degraded zones account for less than 15% of the fracture volume, but cover 70% to 80% of the fracture surface. When the degraded zones are treated as part of the fracture, the fracture transmissivities are two to four times larger because the fracture surfaces after reaction are not as rough as they would be if one considers the degraded zone as part of the rock. Therefore, while degraded zones created during geochemical reactions may not significantly increase mechanical aperture, this type of feature cannot be ignored and should be treated with prudence when predicting fracture hydrodynamic properties.

  10. Double parton correlations in Light-Front constituent quark model

    E-Print Network [OSTI]

    Matteo Rinaldi; Sergio Scopetta; Marco Traini; Vicente Vento

    2014-12-09

    Double parton distribution functions (dPDF) represent a tool to explore the 3D proton structure. They can be measured in high energy proton-proton and proton nucleus collisions and encode information on how partons inside a proton are correlated among each other. dPFDs are studied here in the valence quark region, by means of a constituent quark model, where two particle correlations are present without any additional prescription. This framework allows to understand the dynamical origin of the correlations and to clarify which, among the features of the results, are model independent. Use will be made of a relativistic light-front scheme, able to overcome some drawbacks of the previous calculation. Transverse momentum correlations, due to the exact treatment of the boosts, are predicted and analyzed. The role of spin correlations is also shown. Due to the covariance of the approach, some symmetries of the dPDFs are seen unambigously. For the valence sector, the study of the QCD evolution of the model results, which can be performed safely thanks to the property of good support, has been also completed.

  11. Mechanical properties of nacre constituents and their impact on mechanical performance

    E-Print Network [OSTI]

    Barthelat, Francois

    Mechanical properties of nacre constituents and their impact on mechanical performance François Barthelat, Chun-Ming Li, Claudia Comi,a) and Horacio D. Espinosab) Department of Mechanical Engineering) The mechanical properties of nacre constituents from red abalone were investigated. Electron microscopy studies

  12. REE Sorption Study for Media #1 and Media #2 in Brine #1 and #2 at different Liquid to Solid Ratio's at Ambient Temperature

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gary Garland

    2015-03-27

    This data set shows the different loading capacities of Media #1 and Media #2 in a high and low salt content brine matrix at different liquid to solid ratio's. These data sets are shaker bath tests on media #1 and media #2 in brine's #1 and #2 at 500mL-.5g(1000-1 ratio), 150mL-.75g(200-1 ratio), and 150mL-2.5g(60-1 ratio) at ambient temperature.

  13. Uncertainty and sensitivity analyses for gas and brine migration at the Waste Isolation Pilot Plant, May 1992

    SciTech Connect (OSTI)

    Helton, J.C. [Arizona State Univ., Tempe, AZ (United States); Bean, J.E. [New Mexico Engineering Research Inst., Albuquerque, NM (United States); Butcher, B.M. [Sandia National Labs., Albuquerque, NM (United States); Garner, J.W.; Vaughn, P. [Applied Physics, Inc., Albuquerque, NM (United States); Schreiber, J.D. [Science Applications International Corp., Albuquerque, NM (United States); Swift, P.N. [Tech Reps, Inc., Albuquerque, NM (United States)

    1993-08-01

    Uncertainty and sensitivity analysis techniques based on Latin hypercube sampling, partial correlation analysis, stepwise regression analysis and examination of scatterplots are used in conjunction with the BRAGFLO model to examine two phase flow (i.e., gas and brine) at the Waste Isolation Pilot Plant (WIPP), which is being developed by the US Department of Energy as a disposal facility for transuranic waste. The analyses consider either a single waste panel or the entire repository in conjunction with the following cases: (1) fully consolidated shaft, (2) system of shaft seals with panel seals, and (3) single shaft seal without panel seals. The purpose of this analysis is to develop insights on factors that are potentially important in showing compliance with applicable regulations of the US Environmental Protection Agency (i.e., 40 CFR 191, Subpart B; 40 CFR 268). The primary topics investigated are (1) gas production due to corrosion of steel, (2) gas production due to microbial degradation of cellulosics, (3) gas migration into anhydrite marker beds in the Salado Formation, (4) gas migration through a system of shaft seals to overlying strata, and (5) gas migration through a single shaft seal to overlying strata. Important variables identified in the analyses include initial brine saturation of the waste, stoichiometric terms for corrosion of steel and microbial degradation of cellulosics, gas barrier pressure in the anhydrite marker beds, shaft seal permeability, and panel seal permeability.

  14. Environmental assessment of the brine pipeline replacement for the Strategic Petroleum Reserve Bryan Mound Facility in Brazoria County, Texas

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0804, for the proposed replacement of a deteriorated brine disposal pipeline from the Strategic Petroleum Reserve (SPR) Bryan Mound storage facility in Brazoria County, Texas, into the Gulf of Mexico. In addition, the ocean discharge outfall would be moved shoreward by locating the brine diffuser at the end of the pipeline 3.5 miles offshore at a minimum depth of 30 feet. The action would occur in a floodplain and wetlands; therefore, a floodplain/wetlands assessment has been prepared in conjunction with this EA. Based on the analyses in the EA, DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969 (42 USC. 4321, et seg.). Therefore, the preparation of an Environmental Impact Statement (EIS) is not required, and the Department is issuing this Finding of No Significant Impact (FONSI). This FONSI also includes a Floodplain Statement of Findings in accordance with 10 CFR Part 1022.

  15. The effect of some dissolved constituents on the redox potential of water 

    E-Print Network [OSTI]

    Wales, Robert David

    1952-01-01

    yeaobLoel ~ease aassbe a eateassgo aleaiwNSa Le eel Laebsse af iba bphNaa Oleeie4e ~ ?ateeacee aleAnde La ibs oe4eeaM ~ balf~ seeL Li La eyebea io gLee ihe Eb NLaee ibe ylabLeea alaaiwde ie Lssaeis LL Le aei aNeAsC Q ~%coos bai ibe ~ ball4sell Le aft... ~ darLag ahLeh ih& Impasse aae 4&g&ee&4s faQeeN by a yes%&4 ~ abXoh ~ ?&co t&bsa &ad oa&lysa&L, The 4IIgaeeL&g oyos?tie& see gee tbe yasp?eo &f et&rhbIg ib& naa aLth & lsas dLeaale&4 osSyg&a edae The ibse~eba4 f lech &s&L lb& re+ ~ ssoe? fLU?4 sslth...

  16. Provenance of Corexit-related chemical constituents found in nearshore and inland Gulf Coast waters

    E-Print Network [OSTI]

    Clement, Prabhakar

    , crude oil from the Deepwater Hori- zon accident began washing onto northern Gulf of Mexico(GOM) sandy beaches, continuing until about mid-July, 2010.This oil ar- rived considerably altered from its original, stocks of this dispersant were quickly exhausted and Corexit 9500 was used during the remaining response

  17. CONSTITUENCY AND UNIT PROGRAMS 6 -Org Chart_Constituency ProgramsN:\\Groups\\handbook\\1 -University_Advancement\\6 -Org Chart_Constituency Programs.docx 6/11/2015

    E-Print Network [OSTI]

    _Advancement\\6 - Org Chart_Constituency Programs.docx 6/11/2015 Agriculture and Natural Resources, University & Info Technology Services Seth Martin, Director Katherine Diamond, Development Assistant Lyman Briggs Assistant Natural Science/Cyclotron Corey Longley, Senior Director Karen Wenk, Associate Director Becky Jo

  18. Conservative behavior of uranium vs. salinity in Arctic sea ice and brine Christelle Not a,

    E-Print Network [OSTI]

    ). In natural waters U is found mostly as dis- solved uranyl carbonates (UO2(CO3)3 4 - ) under oxidizing to (1) destabilization of uranyl carbonate complexes; (2) biological uptake; and/or (3) U adsorption

  19. Light hydrocarbon geochemistry of brines and sediments of the red sea 

    E-Print Network [OSTI]

    Burke, Roger Allen

    1979-01-01

    -induced hydzccarbon po!. lution in the oceans [Bi"oaks and Sockett, 1973]; "sniffing" of light hydrocarbons to evaluate the oil producing potential of an area !Sackett, 1977]; and determination of light hydrocarbons in anoxic. waters [Bunt, 1974; Vtesenbpnp, 1975...

  20. Compositional differences in biomarker constituents of the hydrocarbon, resin, asphaltene and kerogen fractions

    E-Print Network [OSTI]

    Mills, Allen P.

    Compositional differences in biomarker constituents of the hydrocarbon, resin, asphaltene fraction, so biomarker parameters measured for different fractions are not directly comparable. The samples- tion are of equal magnitude to the quantities that are present in the extractable aliphatic hydrocarbon

  1. Method and apparatus for the removal or bioconversion of constituents of organic liquids

    DOE Patents [OSTI]

    Scott, T.; Scott, C.D.

    1994-10-25

    A method and apparatus are disclosed for the removal or conversion of constituents from bulk organic liquids. A countercurrent biphasic bioreactor system is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the constituent. Two transient, high-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the constituent to produce a product which is then removed from the bioreactor in the aqueous phase or retained in the organic phase. The organic liquid, now free of the original constituents, is ready for immediate use or further processing. 1 fig.

  2. Effective moduli of granular and layered composites with piezoelectric constituents Tamara Olsony and Marco Avellanedaz

    E-Print Network [OSTI]

    Olson, Tamara

    made from piezoelectric materials are examined, with particular emphasis on applications to unpoledEffective moduli of granular and layered composites with piezoelectric constituents Tamara Olsony piezoelectric ceramics and layered materials. Explicit formulae for the effective moduli and coupling

  3. Digestibility by Sheep of the Constituents of the Nitrogen-Free Extract of Feeds. 

    E-Print Network [OSTI]

    Fraps, , George Stronach

    1930-01-01

    . MACKEY, M. S., Antmal Husbandry *Dean School of Veterinary Medicine. ?As of November 1, 1930. **In cooperation with U. S. Department of Agriculture. The sugars, starch, and other constituents of feeding stuffs were studied by means of chemical...

  4. Texas County Extension Agents Perceptions of the Effectiveness of Using Facebook to Communicate with Constituents 

    E-Print Network [OSTI]

    Lewis, Lacey

    2014-01-08

    , and perceptions using social media, Facebook in particular, to communicate with constituents. The participants in the study were a randomly selected group of Texas extension agents. A web-based questionnaire was used to measure the perceived level of confidence...

  5. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany)

    1995-12-01

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  6. Impact-driven pressure management via targeted brine extraction Conceptual studies of CO2 storage in saline formations

    E-Print Network [OSTI]

    Birkholzer, J.T.

    2013-01-01

    of active pumping, water extraction wells can also bescenarios in which water extraction wells operate as passivemanagement via extraction of native saline water has been

  7. Terrestrial fate of coal-liquid constituents: behavior of alkyl anilines in soil

    SciTech Connect (OSTI)

    Felice, L.J.; Zachara, J.M.; Rogers, J.E.

    1982-07-01

    The low molecular weight aromatic amines (anilines) are important water soluble constituents of coal liquids. The impact of anilines released to the terrestrial environment will largely depend on their mobility and persistence. Studies were conducted to investigate those processes governing the mobility and persistence of the alkylanilines, namely, soil sorption and chemical/microbial degradation. Soil sorption measurements were conducted on aniline and several methyl substituted anilines on A and B horizons of a soil profile collected from Davies County, Kentucky. The magnitude of sorption was large in all horizons. Sorption in the B horizons was larger than in the A horizon for many of the anilines studied, indicating the importance of both the mineral matrix and organic carbon content of the soil in determining the magnitude of sorption. Results of these measurements indicate that movement of the anilines through the soil would be significantly attenuated by sorption reactions. Aniline sorption measurement in the A horizon after removal of the organic matter and in the B/sub 22/ horizon after removal of amorphous iron oxides and crystalline iron oxides indicate that organic matter largely controls aniline sorption in the A horizon, while crystalline iron oxides and phyllosilicates are important in the B horizons. The effects of pH on aniline sorption was also examined and shown to have significant effects on the magnitude of sorption in both A and B horizons. Soil degradation studies using /sup 14/C-3-methylaniline as a model for alkyl aniline degradation show that 3-methylaniline is readily metabolized by soil microorganisms during the 32-day period examined.

  8. Stability of SiC-Matrix Microencapsulated Fuel Constituents at Relevant LWR Conditions

    SciTech Connect (OSTI)

    Terrani, Kurt A; Katoh, Yutai; Leonard, Keith J; Perez-Bergquist, Alex G; Silva, Chinthaka M; Snead, Lance Lewis

    2014-01-01

    This paper addresses certain key feasibility issues facing the application of SiC-matrix microencapsulated fuels for light water reactor application. Issues addressed are the irradiation stability of the SiC-based nano-powder ceramic matrix under LWR-relevant irradiation conditions, the presence or extent of reaction of the SiC matrix with zirconium-based cladding, the stability of the inner and outer pyrolytic graphite layers of the microencapsulated (TRISO) particle at this uncharacteristically low irradiation temperature, and the state of the particle-matrix interface following irradiation which could possibly effect thermal transport. In the process of determining these feasibility issues microstructural evolution and change in dimension and thermal conductivity was studied. As a general finding the SiC matrix was found to be quite stable with behavior similar to that of CVD SiC. In magnitude the irradiation-induced swelling of the matrix material was slightly higher and irradiation-degraded thermal conductivity was slightly lower as compared to CVD SiC. No significant reaction of this SiC-based nano-powder ceramic matrix material with Zircaloy was observed. Irradiation of the TRISO in the 320-360 C range to a maximum dose of 7.7 1025 n/m2 (E > 0.1 MeV) did not have significant negative impact on the constituent layers of the TRISO fuel. At the highest dose studied layer structure and interface integrity remained essentially unchanged with good apparent thermal transport through the microsphere to the surrounding matrix.

  9. Geophysical (time domain electromagnetic model) delineation of a shallow brine beneath a freshwater lake,

    E-Print Network [OSTI]

    Gvirtzman, Haim

    groundwaters. It is hypothesized that salt transport is dominated by molecular diffusion in the central part streams entering the lake. This order of magnitude difference is a result of salt fluxes from two major cores and nineteen 0.5-m cores drilled to sediments within the lake basin (Figure 1). At the water

  10. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 ?g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  11. APPLIED PHYTO-REMEDIATION TECHNIQUES USING HALOPHYTES FOR OIL AND BRINE SPILL SCARS

    SciTech Connect (OSTI)

    M.L. Korphage; Bruce G. Langhus; Scott Campbell

    2003-03-01

    Produced salt water from historical oil and gas production was often managed with inadequate care and unfortunate consequences. In Kansas, the production practices in the 1930's and 1940's--before statewide anti-pollution laws--were such that fluids were often produced to surface impoundments where the oil would segregate from the salt water. The oil was pumped off the pits and the salt water was able to infiltrate into the subsurface soil zones and underlying bedrock. Over the years, oil producing practices were changed so that segregation of fluids was accomplished in steel tanks and salt water was isolated from the natural environment. But before that could happen, significant areas of the state were scarred by salt water. These areas are now in need of economical remediation. Remediation of salt scarred land can be facilitated with soil amendments, land management, and selection of appropriate salt tolerant plants. Current research on the salt scars around the old Leon Waterflood, in Butler County, Kansas show the relative efficiency of remediation options. Based upon these research findings, it is possible to recommend cost efficient remediation techniques for slight, medium, and heavy salt water damaged soil. Slight salt damage includes soils with Electrical Conductivity (EC) values of 4.0 mS/cm or less. Operators can treat these soils with sufficient amounts of gypsum, install irrigation systems, and till the soil. Appropriate plants can be introduced via transplants or seeded. Medium salt damage includes soils with EC values between 4.0 and 16 mS/cm. Operators will add amendments of gypsum, till the soil, and arrange for irrigation. Some particularly salt tolerant plants can be added but most planting ought to be reserved until the second season of remediation. Severe salt damage includes soil with EC values in excess of 16 mS/cm. Operators will add at least part of the gypsum required, till the soil, and arrange for irrigation. The following seasons more gypsum will be added and as the soil EC is reduced, plants can be introduced. If rapid remediation is required, a sufficient volume of topsoil, or sand, or manure can be added to dilute the local salinity, the bulk amendments tilled into the surface with added gypsum, and appropriate plants added. In this case, irrigation will be particularly important. The expense of the more rapid remediation will be much higher.

  12. Fresh Water Generation from Aquifer-Pressured Carbon Storage: Annual Report FY09

    SciTech Connect (OSTI)

    Wolery, T; Aines, R; Hao, Y; Bourcier, W; Wolfe, T; Haussman, C

    2009-11-25

    This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine is reinjected into the formation at net volume reduction, such that the volume of fresh water extracted balances the volume of CO{sub 2} injected into the formation. This process provides additional CO{sub 2} storage capacity in the aquifer, reduces operational risks (cap-rock fracturing, contamination of neighboring fresh water aquifers, and seismicity) by relieving overpressure in the formation, and provides a source of low-cost fresh water to offset costs or operational water needs. This multi-faceted project combines elements of geochemistry, reservoir engineering, and water treatment engineering. The range of saline formation waters is being identified and analyzed. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations. Computer modeling is being used to evaluate processes in the storage aquifer, including the evolution of the pressure field. Water treatment costs are being evaluated by comparing the necessary process facilities to those in common use for seawater RO. There are presently limited brine composition data available for actual CCS sites by the site operators including in the U.S. the seven regional Carbon Sequestration Partnerships (CSPs). To work around this, we are building a 'catalog' of compositions representative of 'produced' waters (waters produced in the course of seeking or producing oil and gas), to which we are adding data from actual CCS sites as they become available. Produced waters comprise the most common examples of saline formation waters. Therefore, they are expected to be representative of saline formation waters at actual and potential future CCS sites. We are using a produced waters database (Breit, 2002) covering most of the United States compiled by the U.S. Geological Survey (USGS). In one instance to date, we have used this database to find a composition corresponding to the brine expected at an actual CCS site (Big Sky CSP, Nugget Formation, Sublette County, Wyoming). We have located other produced waters databases, which are usually of regional scope (e.g., NETL, 2005, Rocky Mountains basins).

  13. Calcite dissolution kinetics and solubility in Na-Ca-Mg-Cl brines of geologically relevant composition at 0.1 to 1 bar pCO2 and 25 to 80°C 

    E-Print Network [OSTI]

    Gledhill, Dwight Kuehl

    2006-08-16

    Sedimentary basins can contain close to 20% by volume pore fluids that are commonly classified as brines. These fluids can become undersaturated with respect to calcite as a result of processes such as migration, dispersive ...

  14. Effects of Constituent Properties on Performance Improvement of a Quenching and Partitioning Steel

    SciTech Connect (OSTI)

    Choi, Kyoo Sil; Hu, Xiaohua; Sun, Xin; Taylor, Mark D.; De Moor, Emmanuel; Speer, John; Matlock, David K.

    2014-04-01

    In this paper, a two-dimensional microstructure-based finite element modeling method is adopted to investigate the effects of material parameters of the constituent phases on the macroscopic tensile behavior of Q&P steel and then to do a computational materials design approach for its performance improvement. For this purpose, a model Q&P steel is first produced and various experiments are then performed to characterize the steel. Actual microstructure-based model is generated based on the information from EBSD, SEM and nano-indentation test, and the material properties for the constituent phases are determined based on the initial constituents’ properties from HEXRD test and the subsequent calibration of model prediction to tensile test results. Influence of various material parameters of the constituents on the macroscopic behaviors is then investigated by separately adjusting them by small amount. Based on the observation on the respective influence of constituents’ material parameters, a new set of material parameters are devised, which results in better performance in ductility. The results indicate that various material parameters may need to be concurrently adjusted in a cohesive way in order to improve the performance of Q&P steel. In summary, higher austenite stability, less strength difference between the phases, higher hardening exponents of the phases are generally beneficial for the performance improvement. The information from this study can be used to devise new Q&P heat-treating parameters to produce the Q&P steels with better performance.

  15. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-01

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  16. Apparatus for the field determination of concentration of radioactive constituents in a medium

    DOE Patents [OSTI]

    Perkins, R.W.; Schilk, A.J.; Warner, R.A.; Wogman, N.A.

    1995-08-15

    The instant invention is an apparatus for determining the concentration of radioactive constituents in a test sample; such as surface soils, via rapid real-time analyses, and direct readout on location utilizing a probe made up of multiple layers of detection material used in combination with an analyzer and real-time readout unit. This is accomplished by comparing the signal received from the probe, which can discriminate between types of radiation and energies with stored patterns that are based upon experimental results. This comparison can be used in the calibration of a readout display that reads out in real-time the concentrations of constituents per given volume. For example, the concentration of constituents such as Cs-137, Sr-90, U-238 in the soil, and noble gas radionuclides such as Kr-85 in the atmosphere, can be measured in real-time, on location, without the need for laboratory analysis of samples. 14 figs.

  17. Apparatus for the field determination of concentration of radioactive constituents in a medium

    DOE Patents [OSTI]

    Perkins, Richard W. (Richland, WA); Schilk, Alan J. (Richland, WA); Warner, Ray A. (Benton City, WA); Wogman, Ned A. (Richland, WA)

    1995-01-01

    The instant invention is an apparatus for determining the concentration of radioactive constituents in a test sample; such as surface soils, via rapid real-time analyses, and direct readout on location utilizing a probe made up of multiple layers of detection material used in combination with an analyzer and real-time readout unit. This is accomplished by comparing the signal received from the probe, which can discriminate between types of radiation and energies with stored patterns that are based upon experimental results. This comparison can be used in the calibration of a readout display that reads out in real-time the concentrations of constituents per given volume. For example, the concentration of constituents such as Cs-137, Sr-90, U-238 in the soil, and noble gas radionuclides such as Kr-85 in the atmosphere, can be measured in real-time, on location, without the need for laboratory analysis of samples.

  18. Methods of removing a constituent from a feed stream using adsorption media

    DOE Patents [OSTI]

    Tranter, Troy J. (Idaho Falls, ID); Mann, Nicholas R. (Rigby, ID); Todd, Terry A. (Aberdeen, ID); Herbst, Ronald S. (Idaho Falls, ID)

    2011-05-24

    A method of producing an adsorption medium to remove at least one constituent from a feed stream. The method comprises dissolving and/or suspending at least one metal compound in a solvent to form a metal solution, dissolving polyacrylonitrile into the metal solution to form a PAN-metal solution, and depositing the PAN-metal solution into a quenching bath to produce the adsorption medium. The at least one constituent, such as arsenic, selenium, or antimony, is removed from the feed stream by passing the feed stream through the adsorption medium. An adsorption medium having an increased metal loading and increased capacity for arresting the at least one constituent to be removed is also disclosed. The adsorption medium includes a polyacrylonitrile matrix and at least one metal hydroxide incorporated into the polyacrylonitrile matrix.

  19. Constraining the reservoir model of an injected CO2 plume with crosswell CASSM at the Frio-II brine plot

    SciTech Connect (OSTI)

    Daley, T.M.; Ajo-Franklin, J.; Doughty, C.A.

    2011-02-15

    Crosswell CASSM (continuous active-source seismic monitoring) data was acquired as part of the Frio-II brine pilot CO{sub 2} injection experiment. To gain insight into the CO{sub 2} plume evolution, we have integrated the 3D multiphase flow modeling code TOUGH2 with seismic simulation codes via a petrophysical model that predicts seismic velocity for a given CO{sub 2} saturation. Results of forward seismic modeling based on the CO{sub 2} saturation distribution produced by an initial TOUGH2 model compare poorly with the CASSM data, indicating that the initial flow model did not capture the actual CO{sub 2} plume dynamics. Updates to the TOUGH2 model required to better match the CASSM field data indicate vertical flow near the injection well, with increased horizontal plume growth occurring at the top of the reservoir sand. The CASSM continuous delay time data are ideal for constraining the modeled spatiotemporal evolution of the CO{sub 2} plume and allow improvement in reservoir model and estimation of CO{sub 2} plume properties.

  20. Turbid water Clear water

    E-Print Network [OSTI]

    Jaffe, Jules

    Turbid water Clear water pixel position cameraresponsecameraresponse pixel position ABSTRACT: A new underwater laser scanning system, providing microbathymetric information in coastal waters is described the backscatter component resulting in enhanced performance in turbid waters. The system is expected to provide

  1. Modeling of constituent redistribution in U-Pu-Zr metallic fuel.

    SciTech Connect (OSTI)

    Kim, Y. S.; Hofman, G. L.; Hayes, S. L.; Yacout, A. M.; Nuclear Engineering Division; INL

    2006-12-01

    A computer model was developed to analyze constituent redistribution in U-Pu-Zr metallic nuclear fuels. Diffusion and thermochemical properties were parametrically determined to fit the postirradiation data from a fuel test performed in the Experimental Breeder Reactor II (EBR-II). The computer model was used to estimate redistribution profiles of fuels proposed for the conceptual designs of small modular fast reactors. The model results showed that the level of redistribution of the fuel constituents of the designs was similar to the measured data from EBR-II.

  2. Non-destructive method for determining neutron exposure and constituent concentrations of a body

    DOE Patents [OSTI]

    Gold, R.; McElroy, W.N.

    1984-02-22

    A non-destructive method for determination of neutron exposure and constituent concentrations in an object, such as a reactor pressure vessel, is based on the observation of characteristic gamma-rays emitted by activation products in the object by using a unique continuous gamma-ray spectrometer. The spectrometer views the object through appropriate collimators to determine the absolute emission rate of these characteristic gamma-rays, thereby ascertaining the absolute activity of given activation products in the object. These data can then be used to deduce the spatial and angular dependence of neutron exposure or the spatial constituent concentrations at regions of interest within the object.

  3. Purge water management system

    DOE Patents [OSTI]

    Cardoso-Neto, J.E.; Williams, D.W.

    1995-01-01

    A purge water management system is described for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

  4. Purge water management system

    DOE Patents [OSTI]

    Cardoso-Neto, Joao E. (North Augusta, SC); Williams, Daniel W. (Aiken, SC)

    1996-01-01

    A purge water management system for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

  5. The role of wellbore remediation on the evolution of groundwater quality from CO? and brine leakage

    SciTech Connect (OSTI)

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO? in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO? mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strong correlation between cumulative injected CO? mass and maximum plume pH volumes and a positive correlation between CO? flux, cumulative injected CO?, and plume recovery times, with secondary dependence on permeability.

  6. The role of wellbore remediation on the evolution of groundwater quality from CO? and brine leakage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO? in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO? mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strongmore »correlation between cumulative injected CO? mass and maximum plume pH volumes and a positive correlation between CO? flux, cumulative injected CO?, and plume recovery times, with secondary dependence on permeability.« less

  7. Organic Constituents on the Surfaces of Aerosol Particles from Southern Finland, Amazonia, and California Studied by Vibrational

    E-Print Network [OSTI]

    Goldstein, Allen

    Organic Constituents on the Surfaces of Aerosol Particles from Southern Finland, Amazonia of Physics, FI-00014 University of Helsinki, Finland Department of Civil and Environmental Engineering

  8. Results of investigations at the Zunil geothermal field, Guatemala: Well logging and brine geochemistry

    SciTech Connect (OSTI)

    Adams, A.; Dennis, B.; Van Eeckhout, E.; Goff, F.; Lawton, R.; Trujillo, P.E.; Counce, D.; Archuleta, J. (Los Alamos National Lab., NM (USA)); Medina, V. (Instituto Nacional de Electrificacion, Guatemala City (Guatemala). Unidad de Desarollo Geotermico)

    1991-07-01

    The well logging team from Los Alamos and its counterpart from Central America were tasked to investigate the condition of four producing geothermal wells in the Zunil Geothermal Field. The information obtained would be used to help evaluate the Zunil geothermal reservoir in terms of possible additional drilling and future power plant design. The field activities focused on downhole measurements in four production wells (ZCQ-3, ZCQ-4, ZCQ-5, and ZCQ-6). The teams took measurements of the wells in both static (shut-in) and flowing conditions, using the high-temperature well logging tools developed at Los Alamos National Laboratory. Two well logging missions were conducted in the Zunil field. In October 1988 measurements were made in well ZCQ-3, ZCQ-5, and ZCQ-6. In December 1989 the second field operation logged ZCQ-4 and repeated logs in ZCQ-3. Both field operations included not only well logging but the collecting of numerous fluid samples from both thermal and nonthermal waters. 18 refs., 22 figs., 7 tabs.

  9. Strategic Planning Process Constituencies contacted/engaged as of May, 2015

    E-Print Network [OSTI]

    Strategic Planning Process Constituencies contacted/engaged as of May, 2015 Student Engagement Open Meeting with Raleigh alumni Community Engagement Planned for fall 2015: to be determined from meeting with the Vice President for Public Affairs and Government Relations Staff engagement Planned for fall 2015

  10. Constituents of political cognition: Race, party politics, and the alliance detection system

    E-Print Network [OSTI]

    Cosmides, Leda

    Constituents of political cognition: Race, party politics, and the alliance detection system David contains a set of adaptations for detecting alliances: an alliance detection system, which monitors for, encodes, and stores alliance information and then modifies the activation of stored alliance categories

  11. Air Pollution: History Air Pollution: Any atmospheric constituent present as a result of

    E-Print Network [OSTI]

    Weber, Rodney

    Air Pollution: History Air Pollution: Any atmospheric constituent present as a result, or materials. Before 1200 AD · Air pollution results from wood burning, tanning, decaying trash, smelting with carbon PbO + C -> Pb + CO Pollutants Produced: CO, SO2 ·Hong, et al., Greenland ice evidence

  12. Responses in Milk Constituents to Intravascular Administration of Two Mixtures of Amino Acids to Dairy Cows

    E-Print Network [OSTI]

    Bequette, Brian J.

    to inves- tigate the effects of intravascular infusions of AA mixtures on milk constituents. Cows were infusion, followed by a 5-djugular infusion of a mixture of AA. Two mixtures of AA were used in a crossover (total AA); this mixture was infused at 400 g of M d . The other mixture represented the essential AA

  13. Geothermal research at the Puna Facility

    SciTech Connect (OSTI)

    Chen, B.

    1986-05-01

    Chemical analyses were conducted on the flocculated silica samples obtained during previous field experiments at HGP-A on both flashed and unflashed brines to determine the composition of the recovered silica for specific constituents of the brine which seem to often be entrapped in the silica during the flocculation process. Metals added as flocculants to the brine were also analyzed in order to evaluate the ease or difficulty with which these can be removed from the precipitated silica under varying conditions. Conditions employed included simple distilled water and acid washing (HCl of varying concentration).

  14. Water Resources Water Quality and Water Treatment

    E-Print Network [OSTI]

    Sohoni, Milind

    Water Resources TD 603 Lecture 1: Water Quality and Water Treatment CTARA Indian Institute of Technology, Bombay 2nd November, 2011 #12;OVERVIEW Water Quality WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TRE OVERVIEW OF THE LECTURE 1. Water Distribution Schemes Hand Pump

  15. Evaluation of Membrane Treatment Technology to Optimize and Reduce Hypersalinity Content of Produced Brine for Reuse in Unconventional Gas Wells 

    E-Print Network [OSTI]

    Eboagwu, Uche

    2012-10-19

    Over 18 billion barrels of waste fluids are generated annually from oil and gas production in the United States. As a large amount of water is used for oilfield operations, treating and reusing produced water can cut the consumption of fresh water...

  16. Water Clean Water Clean

    E-Print Network [OSTI]

    Ishida, Yuko

    Keep Our Water Clean Keep Our Water Clean Home and garden pesticides and fertilizers are polluting residues wash into gutters, storm drains, and streams by rain,garden watering,or cleaning up drinking water. Follow these tips to keep our rivers, creeks, and oceans clean. What can you do to protect

  17. Water, water everywhere,

    E-Print Network [OSTI]

    Eberhard, Marc O.

    1 Water, water everywhere, but is it safe to drink? An Inquiry-based unit investigating the journey of your drinking water from source to tap of drinking water will contain different contaminants, based on surrounding land uses (guided inquiry activity

  18. Water Resources Forests & Water

    E-Print Network [OSTI]

    Water Resources Forests & Water More than half of the nation's freshwater supply originates on forestland. Healthy and sustainable forests can help ensure a continuous supply of clean and abundant water. Not only does forestland provide the cleanest water of any land use, it also helps absorb rainfall

  19. Effects of fine particulate matter and its constituents on low birth weight among full-term infants in California

    SciTech Connect (OSTI)

    Basu, Rupa; Harris, Maria; Sie, Lillian; Malig, Brian; Broadwin, Rachel; Green, Rochelle

    2014-01-15

    Relationships between prenatal exposure to fine particles (PM{sub 2.5}) and birth weight have been observed previously. Few studies have investigated specific constituents of PM{sub 2.5}, which may identify sources and major contributors of risk. We examined the effects of trimester and full gestational prenatal exposures to PM{sub 2.5} mass and 23 PM{sub 2.5} constituents on birth weight among 646,296 term births in California between 2000 and 2006. We used linear and logistic regression models to assess associations between exposures and birth weight and risk of low birth weight (LBW; <2500 g), respectively. Models were adjusted for individual demographic characteristics, apparent temperature, month and year of birth, region, and socioeconomic indicators. Higher full gestational exposures to PM{sub 2.5} mass and several PM{sub 2.5} constituents were significantly associated with reductions in term birth weight. The largest reductions in birth weight were associated with exposure to vanadium, sulfur, sulfate, iron, elemental carbon, titanium, manganese, bromine, ammonium, zinc, and copper. Several of these PM{sub 2.5} constituents were associated with increased risk of term LBW. Reductions in birth weight were generally larger among younger mothers and varied by race/ethnicity. Exposure to specific constituents of PM{sub 2.5}, especially traffic-related particles, sulfur constituents, and metals, were associated with decreased birth weight in California. -- Highlights: • Examine full gestational and trimester fine particle and its constituents on term birth weight. • Fine particles and several of its constituents associated with birth weight reductions. • Largest reductions for traffic-related particles, sulfur constituents, and metals. • Greater birth weight reductions for younger mothers, and varied by race/ethnicity.

  20. Evaluation of Experimentally Measured and Model-Calculated pH for Rock-Brine-CO2 Systems under Geologic CO2 Sequestration Conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-14

    Reliable pH estimation is essential for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies of formation reactivities conducted under geologic CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH; however, the accuracy of these model predictions is typically uncertain. In this study, we expanded the measurement range of a spectrophotometric method for pH determination, and we applied the method to measure the pH in batch-reactor experiments utilizing rock samples from five ongoing GCS demonstration projects. A combination of color-changing pH indicators, bromophenol blue and bromocresol green, was shown to enable measurements over the pH range of 2.5-5.2. In-situ pH measurements were compared with pH values calculated using geochemical models. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. For rocks comprised of carbonate, siltstone, and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain proton consuming and producing reactions that occur between the basalt minerals and CO2-saturated brine solutions.

  1. Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue

    DOE Patents [OSTI]

    Sharp, David W. (Seabrook, TX)

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  2. Sorption of selected volatile organic constituents of jet fuels and solvents on natural sorbents from gas and solutions phases. Final report, April 1985-September 1987

    SciTech Connect (OSTI)

    Rao, P.S.; Rhue, R.D.; Johnson, C.T.; Oguada, R.A.

    1988-08-01

    Sorption of selected volatile organic constituents (VOC) of jet fuels and solvents on several natural sorbents from the gas and aqueous phases was investigated. The sorbates studied were: trans-1,2-dichloroethylene; 1,2-dichloroethane; trichloroethylene; 1,1,2,2-tetrachloroethane; toluene; ethylbenzene; p-xylene; o-xylene; and cyclohexane. The sorbents used included clays (kaolin, montmorillonite, SAz-1), soils (Webster and Oldsmar), and aquifer materials (Borden and Lula). Sorption from the vapor phase was studied using three techniques; the headspace analysis method, dynamic-flow method, and a gas chromatographic method. Sorption of VOC on anhydrous sorbents and sorbents in equilibrium with water at different relative humidities was examined. The energetics of sorption were characterized by measuring VOC sorption at several temperatures.

  3. An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and temporal flow variations in CO2/brine/rock systems

    Broader source: Energy.gov [DOE]

    Project objectives: Generate and characterize mineral dissolution/precipitation reactions in supercritical CO2/brine/rock systems under pressure-temperature-chemistry conditions resembling CO2injection into EGS. Characterize three-dimensional spatial and temporal distributions of rock structures subject to mineral dissolution/precipitation processes by X-ray tomography, SEM imaging, and Microprobe analysis.

  4. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-03-31

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite sorption sites proving to be of secondary importance. The Groundwater Geochemistry ROM was developed using nonlinear regression to fit the response surface with a quadratic polynomial. The goodness of fit was excellent for the CO2 flux to the atmosphere, and very good for predicting the volumes of groundwater exceeding the pH, TDS, As, Cd and Pb threshold values.

  5. Water Resources Research Institute of the University of North Carolina

    E-Print Network [OSTI]

    Water Resources Research Institute of the University of North Carolina Annual Technical Report FY) of The University of North Carolina added to its research and technology transfer efforts new programs funded Resources and constituent institutions of The University of North Carolina that collectively close knowledge

  6. Breath is a mixture of nitrogen, oxygen, carbon dioxide, water

    E-Print Network [OSTI]

    12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide, as the products of normal metabolism and those that have altered owing to disease, and are transported via

  7. A Comparison of the Corrosion Resistance of Iron-Based Amorphous Metals and Austenitic Alloys in Synthetic Brines at Elevated Temperature

    SciTech Connect (OSTI)

    Farmer, J C

    2008-11-25

    Several hard, corrosion-resistant and neutron-absorbing iron-based amorphous alloys have now been developed that can be applied as thermal spray coatings. These new alloys include relatively high concentrations of Cr, Mo, and W for enhanced corrosion resistance, and substantial B to enable both glass formation and neutron absorption. The corrosion resistances of these novel alloys have been compared to that of several austenitic alloys in a broad range of synthetic brines, with and without nitrate inhibitor, at elevated temperature. Linear polarization and electrochemical impedance spectroscopy have been used for in situ measurement of corrosion rates for prolonged periods of time, while scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDAX) have been used for ex situ characterization of samples at the end of tests. The application of these new coatings for the protection of spent nuclear fuel storage systems, equipment in nuclear service, steel-reinforced concrete will be discussed.

  8. Preliminary performance assessment for the Waste Isolation Pilot Plant, December 1992. Volume 5, Uncertainty and sensitivity analyses of gas and brine migration for undisturbed performance

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    Before disposing of transuranic radioactive waste in the Waste Isolation Pilot Plant (WIPP), the United States Department of Energy (DOE) must evaluate compliance with applicable long-term regulations of the United States Environmental Protection Agency (EPA). Sandia National Laboratories is conducting iterative performance assessments (PAs) of the WIPP for the DOE to provide interim guidance while preparing for a final compliance evaluation. This volume of the 1992 PA contains results of uncertainty and sensitivity analyses with respect to migration of gas and brine from the undisturbed repository. Additional information about the 1992 PA is provided in other volumes. Volume 1 contains an overview of WIPP PA and results of a preliminary comparison with 40 CFR 191, Subpart B. Volume 2 describes the technical basis for the performance assessment, including descriptions of the linked computational models used in the Monte Carlo analyses. Volume 3 contains the reference data base and values for input parameters used in consequence and probability modeling. Volume 4 contains uncertainty and sensitivity analyses with respect to the EPA`s Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes (40 CFR 191, Subpart B). Finally, guidance derived from the entire 1992 PA is presented in Volume 6. Results of the 1992 uncertainty and sensitivity analyses indicate that, conditional on the modeling assumptions and the assigned parameter-value distributions, the most important parameters for which uncertainty has the potential to affect gas and brine migration from the undisturbed repository are: initial liquid saturation in the waste, anhydrite permeability, biodegradation-reaction stoichiometry, gas-generation rates for both corrosion and biodegradation under inundated conditions, and the permeability of the long-term shaft seal.

  9. Treating Coalbed Natural Gas Produced Water for Beneficial Use By MFI Zeolite Membranes

    SciTech Connect (OSTI)

    Robert Lee; Liangxiong Li

    2008-03-31

    Desalination of brines produced from oil and gas fields is an attractive option for providing potable water in arid regions. Recent field-testing of subsurface sequestration of carbon dioxide for climate management purposes provides new motivation for optimizing efficacy of oilfield brine desalination: as subsurface reservoirs become used for storing CO{sub 2}, the displaced brines must be managed somehow. However, oilfield brine desalination is not economical at this time because of high costs of synthesizing membranes and the need for sophisticated pretreatments to reduce initial high TDS and to prevent serious fouling of membranes. In addition to these barriers, oil/gas field brines typically contain high concentrations of multivalent counter cations (eg. Ca{sup 2+} and SO{sub 4}{sup 2-}) that can reduce efficacy of reverse osmosis (RO). Development of inorganic membranes with typical characteristics of high strength and stability provide a valuable option to clean produced water for beneficial uses. Zeolite membranes have a well-defined subnanometer pore structure and extreme chemical and mechanical stability, thus showing promising applicability in produced water purification. For example, the MFI-type zeolite membranes with uniform pore size of {approx}0.56 nm can separate ions from aqueous solution through a mechanism of size exclusion and electrostatic repulsion (Donnan exclusion). Such a combination allows zeolite membranes to be unique in separation of both organics and electrolytes from aqueous solutions by a reverse osmosis process, which is of great interest for difficult separations, such as oil-containing produced water purification. The objectives of the project 'Treating Coalbed Natural Gas Produced Water for Beneficial Use by MFI Zeolite Membranes' are: (1) to conduct extensive fundamental investigations and understand the mechanism of the RO process on zeolite membranes and factors determining the membrane performance, (2) to improve the membranes and optimize operating conditions to enhance water flux and ion rejection, and (3) to perform long-term RO operation on tubular membranes to study membrane stability and to collect experimental data necessary for reliable evaluations of technical and economic feasibilities. Our completed research has resulted in deep understanding of the ion and organic separation mechanism by zeolite membranes. A two-step hydrothermal crystallization process resulted in a highly efficient membrane with good reproducibility. The zeolite membranes synthesized therein has an overall surface area of {approx}0.3 m{sup 2}. Multichannel vessels were designed and machined for holding the tubular zeolite membrane for water purification. A zeolite membrane RO demonstration with zeolite membranes fabricated on commercial alpha-alumina support was established in the laboratory. Good test results were obtained for both actual produced water samples and simulated samples. An overall 96.9% ion rejection and 2.23 kg/m{sup 2}.h water flux was achieved in the demonstration. In addition, a post-synthesis modification method using Al{sup 3+}-oligomers was developed for repairing the undesirable nano-scale intercrystalline pores. Considerable enhancement in ion rejection was achieved. This new method of zeolite membrane modification is particularly useful for enhancing the efficiency of ion separation from aqueous solutions because the modification does not need high temperature operation and may be carried out online during the RO operation. A long-term separation test for actual CBM produced water has indicated that the zeolite membranes show excellent ion separation and extraordinary stability at high pressure and produced water environment.

  10. Distribution and geochemistry of contaminated subsurface waters in fissured volcanogenic bed rocks of the Lake Karachai Area, Chelyabinsk, Southern Urals

    SciTech Connect (OSTI)

    Solodov, I.N.; Belichkin, V.I.; Zotov, A.V.; Kochkin, B.T.; Drozhko, E.G.; Glagolev, A.V.; Skokov, A.N.

    1994-06-01

    The present investigation is devoted to the study of the distribution and geochemistry of contaminated subsurface waters, beneath the site of temporary storage of liquid radioactive waste known as Lake Karachai. For this purpose a method of hydrogeochemical logging (HGCL) together with standard hydrogeochemical and geophysical methods of uncased hole logging were used. The distribution of sodium nitrate brine plumes in the subsurface was determined by the physical and physico-chemical properties of these brines and by the petrochemical composition of enclosing rocks and the structural setting of the flow paths. The latter is represented by fractures and large faults in the bedrock of volcanogenic and volcanogenic-sedimentary rocks of intermediate-to-basic composition. The volcanogenic rocks are overlain in some places by a thin cover of unconsolidated sediments, i.e., by loams and relatively impermeable silts. Contaminated waters flow-in accordance with the eluvium bottom relief towards local areas of natural (Mishelyak and Techa rivers) and artificial (Novogomenskii water intake) discharge of subsurface waters. The large Mishelyak fault, southwest of Lake Karachai and under fluvial sediments of the Mishelyak, is assumed to significantly influence the flow pattern of contaminated waters, diverting them from an intake of drinking water.

  11. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface...

  12. Ground-water surveillance at the Hanford Site for CY 1983

    SciTech Connect (OSTI)

    Prater, L.S.; Rieger, J.T.; Cline, C.S.; Jensen, E.J.; Liikala, T.L.; Oster, K.R.

    1984-07-01

    Operations at the Hanford Site have resulted in the discharge of large volumes of process cooling water and other waste waters to the ground. These effluents contain low level of radioactive and chemical substances. During 1983, 328 monitoring wells were sampled at various times for radioactive and chemical constituents. Three of these constituents, specifically tritium, nitrate, and gross beta activity, were selected for detailed discussion in this report because they are more readily transported in the ground water than some of the other constituents. Transport of these constituents in the ground water has resulted in the formation of plumes that can be mapped by contouring the analytical data obtained from the monitoring wells. This report describes recent changes in the configuration of the tritium, nitrate and gross beta plumes. Changes or trends in contaminant levels in wells located within both the main plumes (originating from the 200 Areas) and the smaller plumes are discussed in this report. Two potential pathways for radionuclide transport from the ground water to the environmental are discussed in this report, and the radiological impacts are examined. In addition to describing the present status of the ground water beneath the Hanford Site, this report contains the results of studies conducted in support of the ground-water surveillance effort during CY 1983. 21 references, 26 figures, 5 tables.

  13. Constituent-quark model description of triply heavy-baryon nonperturbative lattice QCD data

    E-Print Network [OSTI]

    Vijande, J; Garcilazo, H

    2015-01-01

    This paper provides results for the spectra of triply charmed and bottom baryons based on a constituent quark model approach. We take advantage of the assumption that potential models are expected to describe triply heavy baryons to a similar degree of accuracy as the successful results obtained in the charmonium and bottomonium sectors. The high precision calculation of the ground state and positive and negative parity excited states recently reported by nonperturbative lattice QCD provides us with a unique opportunity to confront model predictions with data. This comparison may also help to build a bridge between two difficult to reconcile lattice QCD results, namely, the lattice SU(3) QCD static three-quark potential and the recent results of nonperturbative lattice QCD for the triply heavy-baryon spectra.

  14. Effect of potential Hanford ferrocyanide waste constituents on the reaction between ferrocyanide and nitrates/nitrites

    SciTech Connect (OSTI)

    Scheele, R.D.; Burger, L.L.; Sell, R.L.

    1993-02-01

    During the 1950s, ferrocyanide- and nitrate-bearing wastes were produced at Hanford. A concern about continued safe storage and future treatment of these wastes has arisen because ferrocyanide and nitrate mixtures can explode when heated. Because of this concern, the Pacific Northwest Laboratory has performed experimental studies to determine the conditions needed to continue storing the wastes safely. In this paper, we present the results of our studies on the effects of other potential ferrocyanide waste constituents on the explosivity of mixtures of sodium nickel ferrocyanide and sodium nitrate and nitrite. In particular, this paper presents the results of investigations on the diluent effects of equimolar sodium nitrate and nitrite, sodium nickel ferrocyanide, and sodium aluminate, and the catalyst or initiator effects of nickel sulfide.

  15. Constituent-quark model description of triply heavy-baryon nonperturbative lattice QCD data

    E-Print Network [OSTI]

    J. Vijande; A. Valcarce; H. Garcilazo

    2015-07-14

    This paper provides results for the spectra of triply charmed and bottom baryons based on a constituent quark model approach. We take advantage of the assumption that potential models are expected to describe triply heavy baryons to a similar degree of accuracy as the successful results obtained in the charmonium and bottomonium sectors. The high precision calculation of the ground state and positive and negative parity excited states recently reported by nonperturbative lattice QCD provides us with a unique opportunity to confront model predictions with data. This comparison may also help to build a bridge between two difficult to reconcile lattice QCD results, namely, the lattice SU(3) QCD static three-quark potential and the recent results of nonperturbative lattice QCD for the triply heavy-baryon spectra.

  16. Optical methods and systems for detecting a constituent in a gas containing oxygen in harsh environments

    DOE Patents [OSTI]

    Carpenter, Michael A. (Scotia, NY); Sirinakis, George (Bronx, NY)

    2011-01-04

    A method for detecting a gas phase constituent such as carbon monoxide, nitrogen dioxide, hydrogen, or hydrocarbons in a gas comprising oxygen such as air, includes providing a sensing material or film having a metal embedded in a catalytically active matrix such as gold embedded in a yttria stabilized zirconia (YSZ) matrix. The method may include annealing the sensing material at about 900.degree. C., exposing the sensing material and gas to a temperature above 400.degree. C., projecting light onto the sensing material, and detecting a change in the absorption spectrum of the sensing material due to the exposure of the sensing material to the gas in air at the temperature which causes a chemical reaction in the sensing material compared to the absorption spectrum of the sensing material in the absence of the gas. Systems employing such a method are also disclosed.

  17. Investigating Water 

    E-Print Network [OSTI]

    Howard Jr., Ronald A.

    2002-01-02

    This 3-ring binder contains teaching plans for 12 lessons on topics such as "Water in Our Daily Lives," "The Water Cycle," "Amazing Aquifers," "Water and Soil," "Aquatic Ecosystems," and "Water Wise Use." Accompanying each lesson plan are activity...

  18. Method and apparatus for maintaining condensable constituents of a gas in a vapor phase during sample transport

    DOE Patents [OSTI]

    Felix, Larry Gordon; Farthing, William Earl; Irvin, James Hodges; Snyder, Todd Robert

    2010-05-18

    A system for fluid transport at elevated temperatures having a conduit having a fluid inlet end and a fluid outlet end and at least one heating element disposed within the conduit providing direct heating of a fluid flowing through the conduit. The system is particularly suited for preventing condensable constituents of a high temperature fluid from condensing out of the fluid prior to analysis of the fluid. In addition, operation of the system so as to prevent the condensable constituents from condensing out of the fluid surprisingly does not alter the composition of the fluid.

  19. Please cite this article in press as: Birkholzer, J.T., et al., Brine flow up a well caused by pressure perturbation from geologic carbon sequestration: Static and dynamic evaluations. Int. J. Greenhouse Gas Control (2011), doi:10.1016/j.ijggc.2011.01.003

    E-Print Network [OSTI]

    Zhou, Quanlin

    2011-01-01

    . If the threshold pressure is exceeded, brine flow rates are dependent on various hydraulic (and other) prop- erties occurs outside of the well casing, e.g., in a permeable fracture zone between the well cement

  20. The University of North Carolina Wilmington is one of 17 constituent universities in the UNC system. We are

    E-Print Network [OSTI]

    Olszewski Jr., Edward A.

    about UNCW The University of North Carolina Wilmington is one of 17 constituent universities in the UNC system. We are located in southeastern North Carolina in the city of Wilmington, situated Environmental StudiesUniversity of North Carolina Wilmington "Dare to learn" - William Madison Randall 601 South

  1. Water Heaters and Hot Water Distribution Systems

    E-Print Network [OSTI]

    Lutz, Jim

    2012-01-01

    LBNL collected water and waste water tariffs in Californiastate. Current water and waste water tariffs for these areaswas based on water and waste water tariffs in California

  2. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    E-Print Network [OSTI]

    Zheng, L.

    2011-01-01

    brines co-produced with crude oil (Zarrella et al. , 1967)brines co-produced with crude oil (Zarrella et al. , 1967)of Production Condensate Crude oil Crude oil Crude oil Crude

  3. From constituent quarks to hadrons in course of nuclear matter expansion

    E-Print Network [OSTI]

    O. D. Chernavskaya; I. I. Royzen

    2002-01-13

    The up-dated three-phase concept of nuclear matter evolution in course of cooling down - from the phase of quark-qluon plasma (QGP) through the intermediate phase allowing for massive constituent quarks (valons), pions and kaons (QPK) to the phase of hadronic matter (H) - is exploited for the treatment of relative hadronic yields in the central region of heavy ion collisions. The most attention is paid to the description of the QPK-phase which is argued to be a gaseous one and lasts until the valonic spacing approaches the confinement radius (at the temperature about 110 MeV), when the valons start fusing to be locked, in the end, within the hadrons. The hadronic yields emerged from thermal treatment of QPK-phase and simple combinatorial approach to the hadronization process are shown to fit the available experimental data from AGS, SPS and RHIC quite well. This provides an alternative insight into the real origin of the observed relative hadronic yields which is (to a considerable extent) free of the well known puzzle inherent in some conventional models where the early chemical freeze-out is assumed: namely, why the gaseous thermal approach to actually tightly packed (even overlapping) hadrons seems workable? Many predictions for the other hadronic yields which could be observed at these machines as well as at LHC are given.

  4. Higher twists in polarized DIS and the size of the constituent quark

    SciTech Connect (OSTI)

    Alexander Sidorov; Christian Weiss

    2006-02-15

    The spontaneous breaking of chiral symmetry implies the presence of a short-distance scale in the QCD vacuum, which phenomenologically may be associated with the ''size'' of the constituent quark, rho {approx} 0.3 fm. We discuss the role of this scale in the matrix elements of the twist-4 and 3 quark-gluon operators determining the leading power (1/Q{sup 2}-) corrections to the moments of the nucleon spin structure functions. We argue that the flavor-nonsinglet twist-4 matrix element, f{sub 2}{sup u-d}, has a sizable negative value of the order rho{sup -2}, due to the presence of sea quarks with virtualities {approx} rho{sup -2} in the proton wave function. The twist-3 matrix element, d{sub 2}, is not related to the scale rho{sup -2}. Our arguments support the results of previous calculations of the matrix elements in the instanton vacuum model. We show that this qualitative picture is in agreement with the phenomenological higher-twist correction extracted from an NLO QCD fit to the world data on g{sub 1}{sup p} and g{sub 1}{sup n}, which include recent data from the Jefferson Lab Hall A and COMPASS experiments. We comment on the implications of the short-distance scale rho for quark-hadron duality and the x-dependence of higher-twist contributions.

  5. Methods of chemical analysis for organic waste constituents in radioactive materials: A literature review

    SciTech Connect (OSTI)

    Clauss, S.A.; Bean, R.M.

    1993-02-01

    Most of the waste generated during the production of defense materials at Hanford is presently stored in 177 underground tanks. Because of the many waste treatment processes used at Hanford, the operations conducted to move and consolidate the waste, and the long-term storage conditions at elevated temperatures and radiolytic conditions, little is known about most of the organic constituents in the tanks. Organics are a factor in the production of hydrogen from storage tank 101-SY and represent an unresolved safety question in the case of tanks containing high organic carbon content. In preparation for activities that will lead to the characterization of organic components in Hanford waste storage tanks, a thorough search of the literature has been conducted to identify those procedures that have been found useful for identifying and quantifying organic components in radioactive matrices. The information is to be used in the planning of method development activities needed to characterize the organics in tank wastes and will prevent duplication of effort in the development of needed methods.

  6. Water Intoxication

    E-Print Network [OSTI]

    Lingampalli, Nithya

    2013-01-01

    2008, May 14). Too much water raises seizure risk in babies.id=4844 9. Schoenly, Lorry. “Water Intoxication and Inmates:article/246650- overview>. 13. Water intoxication alert. (

  7. Water Efficiency

    Energy Savers [EERE]

    Water Efficiency Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral, Florida WATER EFFICIENCY Federal Utility Partnership Working Group...

  8. 1. Constituents of rainwater 2. pH and pKa

    E-Print Network [OSTI]

    Schofield, Jeremy

    of soluble gases (reminder) { SO 2 1. Coal burning coal + O 2 (g) #1; ! SO 2 (g) + electricty 2. Volcanos to important physical properties: 1. Density of ice lower than liquid water in range T = 0 4 C. Important

  9. Groundwater transport modeling of constituents originating from the Burial Grounds Complex

    SciTech Connect (OSTI)

    Andersen, P.F.; Shupe, M.G.; Spalding, C.P. [GeoTrans, Inc., Sterling, VA (US)

    1992-10-30

    The Savannah River Site (SRS), operates a number of sites for the land disposal of various leachable radionuclide, organic, and inorganic wastes. Located within the General Separations Area (GSA) of SRS are the Low Level Radioactive Waste Disposal Facility (LLRWDF) and the Old Burial Ground (OBG). A portion of the LLRWDF has been designated as the Mixed Waste Management Facility (MWMF). The OBG began receiving waste in 1952 and was closed in 1974. Various wastes, including transuranic, intermediate and low level beta-gamma, and solvents, were received during this period of operation. In 1969, prior to the closing of the OBG, a portion of the MWMF/LLRWDF (the MWMF) began receiving waste. GeoTrans, Inc. was contracted by WSRC to conduct a numerical modeling study to assess groundwater flow and contaminant transport in the vicinity of the MWMF in support of an Alternate Concentration Limits demonstration for the Part B permit. The project was divided into two phases: development of a groundwater flow model of the hydrogeologic system underlying the MWMF which includes the entire GSA, and development of a solute transport model to assess migration of 19 designated constituents of concern (COCs) over a period 30 years into the future. The first phase was completed in May of 1992 and the results documented in GeoTrans (1992). That report serves as the companion volume to the present contaminant transport modeling report. The transport study is intended to develop predictions of concentration and mass flux of the 19 COCs at downgradient exposure points over the 30 year period of interest. These results are to be used in human health and ecological risk assessments which are also being performed in support of the Part B permit.

  10. NORM Mitigation and Clean Water Recovery from Marcellus Produced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MD process. Every effect is an opportunity to recycle latent heat; higher pressure vapor condenses and cooler brine evaporates to generate lower pressure vapor. The...

  11. The influence of constituent properties on the compression behavior of graphite fiber reinforced composites containing geometric discontinuities 

    E-Print Network [OSTI]

    Crane, David Lee

    1990-01-01

    in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE DECEMBER 1990 Major Subject: Mechanical Engineering THE INFLUENCE OF CONSTITUENT PROPERTIES ON THE COMPRESSION BEHAVIOR OF GRAPHITE FIBER REINFORCED COMPOSITES CONTAINING... Committee: Walter L. Bradley This study addresses the compressive behavior of graphite fiber reinforced composites containing toughened matrices. The effect of thermoplastic and rubber particulate toughening mechanisms is evaluated utilizing four...

  12. An Innovative System for the Efficient and Effective Treatment of Non-Traditional Waters for Reuse in Thermoelectric Power Generation

    SciTech Connect (OSTI)

    John Rodgers; James Castle

    2008-08-31

    This study assessed opportunities for improving water quality associated with coal-fired power generation including the use of non-traditional waters for cooling, innovative technology for recovering and reusing water within power plants, novel approaches for the removal of trace inorganic compounds from ash pond effluents, and novel approaches for removing biocides from cooling tower blowdown. This research evaluated specifically designed pilot-scale constructed wetland systems for treatment of targeted constituents in non-traditional waters for reuse in thermoelectric power generation and other purposes. The overall objective of this project was to decrease targeted constituents in non-traditional waters to achieve reuse criteria or discharge limitations established by the National Pollutant Discharge Elimination System (NPDES) and Clean Water Act (CWA). The six original project objectives were completed, and results are presented in this final technical report. These objectives included identification of targeted constituents for treatment in four non-traditional water sources, determination of reuse or discharge criteria for treatment, design of constructed wetland treatment systems for these non-traditional waters, and measurement of treatment of targeted constituents in non-traditional waters, as well as determination of the suitability of the treated non-traditional waters for reuse or discharge to receiving aquatic systems. The four non-traditional waters used to accomplish these objectives were ash basin water, cooling water, flue gas desulfurization (FGD) water, and produced water. The contaminants of concern identified in ash basin waters were arsenic, chromium, copper, mercury, selenium, and zinc. Contaminants of concern in cooling waters included free oxidants (chlorine, bromine, and peroxides), copper, lead, zinc, pH, and total dissolved solids. FGD waters contained contaminants of concern including arsenic, boron, chlorides, selenium, mercury, chemical oxygen demand (COD), and zinc. Similar to FGD waters, produced waters contained contaminants of concern that are predominantly inorganic (arsenic, cadmium, chlorides, chromium, copper, lead, mercury, nickel, sulfide, zinc, total dissolved solids), but also contained some organics (benzene, PAHs, toluene, total organic carbon, total suspended solids, and oil and grease). Constituents of concern that may cause chemical scaling, biofouling and corrosion, such as pH, hardness and ionic strength, and nutrients (P, K, and N) may also be found in all four non-traditional waters. NPDES permits were obtained for these non-traditional waters and these permit limits are summarized in tabular format within this report. These limits were used to establish treatment goals for this research along with toxicity values for Ceriodaphnia dubia, water quality criteria established by the US EPA, irrigation standards established by the United States Department of Agriculture (USDA), and reuse standards focused on minimization of damage to the power plant by treated waters. Constructed wetland treatment systems were designed for each non-traditional water source based on published literature reviews regarding remediation of the constituents of concern, biogeochemistry of the specific contaminants, and previous research. During this study, 4 non-traditional waters, which included ash basin water, cooling water, FGD water and produced water (PW) were obtained or simulated to measure constructed wetland treatment system performance. Based on data collected from FGD experiments, pilot-scale constructed wetland treatment systems can decrease aqueous concentrations of elements of concern (As, B, Hg, N, and Se). Percent removal was specific for each element, including ranges of 40.1% to 77.7% for As, 77.6% to 97.8% for Hg, 43.9% to 88.8% for N, and no measureable removal to 84.6% for Se. Other constituents of interest in final outflow samples should have aqueous characteristics sufficient for discharge, with the exception of chlorides (<2000 mg/L). Based on total dissolved solids, co-

  13. Salivary influences upon levels of certain chemical constituents in forage residues collected from esophageally cannulated sheep 

    E-Print Network [OSTI]

    Radde, Kenneth Albert

    1967-01-01

    - hydrate content of the offered fo. ames PercentaSe incre, e in ash exnressed on a dry matter basis 24 +- CVG x 100 ? Level of water soluble carbohydrates in foraGe residues relative to calculated level of inc:ested w. . ter soluble carbohydrates...

  14. DUSEL Facility Cooling Water Scaling Issues

    SciTech Connect (OSTI)

    Daily, W D

    2011-04-05

    Precipitation (crystal growth) in supersaturated solutions is governed by both kenetic and thermodynamic processes. This is an important and evolving field of research, especially for the petroleum industry. There are several types of precipitates including sulfate compounds (ie. barium sulfate) and calcium compounds (ie. calcium carbonate). The chemical makeup of the mine water has relatively large concentrations of sulfate as compared to calcium, so we may expect that sulfate type reactions. The kinetics of calcium sulfate dihydrate (CaSO4 {center_dot} 2H20, gypsum) scale formation on heat exchanger surfaces from aqueous solutions has been studied by a highly reproducible technique. It has been found that gypsum scale formation takes place directly on the surface of the heat exchanger without any bulk or spontaneous precipitation in the reaction cell. The kinetic data also indicate that the rate of scale formation is a function of surface area and the metallurgy of the heat exchanger. As we don't have detailed information about the heat exchanger, we can only infer that this will be an issue for us. Supersaturations of various compounds are affected differently by temperature, pressure and pH. Pressure has only a slight affect on the solubility, whereas temperature is a much more sensitive parameter (Figure 1). The affect of temperature is reversed for calcium carbonate and barium sulfate solubilities. As temperature increases, barium sulfate solubility concentrations increase and scaling decreases. For calcium carbonate, the scaling tendencies increase with increasing temperature. This is all relative, as the temperatures and pressures of the referenced experiments range from 122 to 356 F. Their pressures range from 200 to 4000 psi. Because the cooling water system isn't likely to see pressures above 200 psi, it's unclear if this pressure/scaling relationship will be significant or even apparent. The most common scale minerals found in the oilfield include calcium carbonates (CaCO3, mainly calcite) and alkaline-earth metal sulfates (barite BaSO4, celestite SrSO4, anhydrite CaSO4, hemihydrate CaSO4 1/2H2O, and gypsum CaSO4 2H2O or calcium sulfate). The cause of scaling can be difficult to identify in real oil and gas wells. However, pressure and temperature changes during the flow of fluids are primary reasons for the formation of carbonate scales, because the escape of CO2 and/or H2S gases out of the brine solution, as pressure is lowered, tends to elevate the pH of the brine and result in super-saturation with respect to carbonates. Concerning sulfate scales, the common cause is commingling of different sources of brines either due to breakthrough of injected incompatible waters or mixing of two different brines from different zones of the reservoir formation. A decrease in temperature tends to cause barite to precipitate, opposite of calcite. In addition, pressure drops tend to cause all scale minerals to precipitate due to the pressure dependence of the solubility product. And we can expect that there will be a pressure drop across the heat exchanger. Weather or not this will be offset by the rise in pressure remains to be seen. It's typically left to field testing to prove out. Progress has been made toward the control and treatment of the scale deposits, although most of the reaction mechanisms are still not well understood. Often the most efficient and economic treatment for scale formation is to apply threshold chemical inhibitors. Threshold scale inhibitors are like catalysts and have inhibition efficiency at very low concentrations (commonly less than a few mg/L), far below the stoichiometric concentrations of the crystal lattice ions in solution. There are many chemical classes of inhibitors and even more brands on the market. Based on the water chemistry it is anticipated that there is a high likelihood for sulfate compound precipitation and scaling. This may be dependent on the temperature and pressure, which vary throughout the system. Therefore, various types and amounts of scaling may occur at different

  15. EXTENSION WATER SUMMIT PRIORITY: WATER CONSERVATION

    E-Print Network [OSTI]

    Slatton, Clint

    EXTENSION WATER SUMMIT PRIORITY: WATER CONSERVATION Leadership Team Subcommittee: Joan Bradshaw Michael Dukes Pierce Jones Kati Migliaccio #12;Water Conservation - Situation · Florida water supplies are used for agriculture, natural resources, salt water intrusion protection, drinking water, industry

  16. Total reflection infrared spectroscopy of water-ice and frozen aqueous NaCl solutions

    SciTech Connect (OSTI)

    Walker, Rachel L.; Searles, Keith; Willard, Jesse A.; Michelsen, Rebecca R. H., E-mail: RMichelsen@rmc.edu [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)] [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)

    2013-12-28

    Liquid-like and liquid water at and near the surface of water-ice and frozen aqueous sodium chloride films were observed using attenuated total reflection infrared spectroscopy (ATR-IR). The concentration of NaCl ranged from 0.0001 to 0.01 M and the temperature varied from the melting point of water down to 256 K. The amount of liquid brine at the interface of the frozen films with the germanium ATR crystal increased with salt concentration and temperature. Experimental spectra are compared to reflection spectra calculated for a simplified morphology of a uniform liquid layer between the germanium crystal and the frozen film. This morphology allows for the amount of liquid observed in an experimental spectrum to be converted to the thickness of a homogenous layer with an equivalent amount of liquid. These equivalent thickness ranges from a nanometer for water-ice at 260 K to 170 nm for 0.01 M NaCl close to the melting point. The amounts of brine observed are over an order of magnitude less than the total liquid predicted by equilibrium thermodynamic models, implying that the vast majority of the liquid fraction of frozen solutions may be found in internal inclusions, grain boundaries, and the like. Thus, the amount of liquid and the solutes dissolved in them that are available to react with atmospheric gases on the surfaces of snow and ice are not well described by thermodynamic equilibrium models which assume the liquid phase is located entirely at the surface.

  17. Dynamics of a relativistic Rankine vortex for a two-constituent superfluid in a weak perturbation of cylindrical symmetry

    E-Print Network [OSTI]

    B. Boisseau

    1999-01-18

    From a recent study of a stationary cylindrical solution for a relativistic two-constituent superfluid at low temperature limit, we propose to specify this solution under the form of a relativistic generalisation of a Rankine vortex (Potential vortex whose the core has a solid body rotation).Then we establish the dynamics of the central line of this vortex by supposing that the deviation from the cylindrical configuration is weak in the neighbourhood of the core of the vortex. In "stiff" material the Nambu-Goto equations are obtained.

  18. Modeling Constituent Redistribution in U-Pu-Zr Metallic Fuel Using the Advanced Fuel Performance Code BISON

    SciTech Connect (OSTI)

    Douglas Porter; Steve Hayes; Various

    2014-06-01

    The Advanced Fuels Campaign (AFC) metallic fuels currently being tested have higher zirconium and plutonium concentrations than those tested in the past in EBR reactors. Current metal fuel performance codes have limitations and deficiencies in predicting AFC fuel performance, particularly in the modeling of constituent distribution. No fully validated code exists due to sparse data and unknown modeling parameters. Our primary objective is to develop an initial analysis tool by incorporating state-of-the-art knowledge, constitutive models and properties of AFC metal fuels into the MOOSE/BISON (1) framework in order to analyze AFC metallic fuel tests.

  19. High Q{sup 2} behavior of the electromagnetic form factors in the relativistic hypercentral constituent quark model

    SciTech Connect (OSTI)

    Santopinto, E.; Vassallo, A.; Giannini, M. M.; De Sanctis, M.

    2010-12-15

    The ratio R{sub p} between the electric and magnetic proton form factors has been recently measured at Jefferson Lab up to Q{sup 2}=8.5 GeV{sup 2}. We have extended the calculation of the nucleon form factors with the hypercentral constituent quark model and compared them with the data on R{sub p} and on the Q{sup 2} behavior of the ratio Q{sup 2}F{sub 2}/F{sub 1}. In both cases, the theoretical curves agree with the experimental points.

  20. TREATMENT OF PRODUCED OIL AND GAS WATERS WITH SURFACTANT-MODIFIED ZEOLITE

    SciTech Connect (OSTI)

    Lynn E. Katz; R.S. Bowman; E.J. Sullivan

    2003-11-01

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. It is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some must be treated to remove organic constituents before the water is discharged. Current treatment options are successful in reducing the organic content; however, they cannot always meet the levels of current or proposed regulations for discharged water. Therefore, an efficient, cost-effective treatment technology is needed. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. This report summarizes the work and results of this four-year project. We tested the effectiveness of surfactant-modified zeolite (SMZ) for removal of BTEX with batch and column experiments using waters with BTEX concentrations that are comparable to those of produced waters. The data from our experimental investigations showed that BTEX sorption to SMZ can be described by a linear isotherm model, and competitive effects between compounds were not significant. The SMZ can be readily regenerated using air stripping. We field-tested a prototype SMZ-based water treatment system at produced water treatment facilities and found that the SMZ successfully removes BTEX from produced waters as predicted by laboratory studies. When compared to other existing treatment technologies, the cost of the SMZ system is very competitive. Furthermore, the SMZ system is relatively compact, does not require the storage of potentially hazardous chemicals, and could be readily adapted to an automated system.

  1. Ground Water Ground Sky Sky Water Vegetation Ground Vegetation Water

    E-Print Network [OSTI]

    Chen, Tsuhan

    Bear Snow Vegetation RhinoWater Vegetation Ground Water Ground Sky Sky Rhino Water Vegetation Ground Vegetation Water Rhino Water Vegetation Ground Rhino Water Rhino Water Ground Ground Vegetation Water Rhino Vegetation Rhino Vegetation Ground Rhino Vegetation Ground Sky Rhino Vegetation Ground Sky

  2. CHARACTERIZATION OF PEEK (POLYARYLETHERETHERKETONE) POLYMERS BY

    E-Print Network [OSTI]

    Bluemel, Janet

    of high pressures and temperatures, while being exposed to steam, water based drilling fluids or brines

  3. Computerized Waters 

    E-Print Network [OSTI]

    Wythe, Kathy

    2006-01-01

    supply diversions, several hydroelectric plants and numerous environ- mental instream flow requirements. Each of these active permits is included in the datasets. Besides the commission using the WAM/WRAP modeling system in water rights permiting... actions be consistent with relevant regional plans. River authorities, water districts and other water management organizations are beginning to use the WRAP model in operational planning studies to optimize operations of their facilities...

  4. A Phase-Partitioning Model for CO2–Brine Mixtures at Elevated Temperatures and Pressures: Application to CO2-Enhanced Geothermal Systems

    E-Print Network [OSTI]

    Spycher, Nicolas; Pruess, Karsten

    2010-01-01

    of water as the heat transmission ?uid in EGS has beena sys- tem with CO 2 as heat transmission ?uid requires an

  5. Tidal constituent database. West Coast of the United States and Eastern North pacific ocean. Technical note

    SciTech Connect (OSTI)

    NONE

    1995-01-01

    This technical note describes a database of tidal elevation boundary condition information generated in support of the `Long-Term Fate of Dredged Material Disposed in Open Water` research of the Dredging Research Program (DRP), being conducted at the U.S. Army Engineer Waterways Experiment Station. The database, described in detail by Hench and others (1994), allows the user to manually generate time series of tidal elevations or to use a program to access the full database to generate time series of both tidal elevations and currents for any location along the West Coast of the United States and Eastern North Pacific Ocean, extending from Seal Cape on Unimak Island, Alaska, in the North to Punta Parada, Peru, in the South. The land boundary includes the Pacific shorelines of Alaska, Canada, mainland United States, Mexico, Guatemala, El Salvador, Nicaragua, Costa Rica, Panama, Columbia, and Northern Peru. Although the capability to generate these time series was developed to provide input to the Long-Term Fate and Stability Model (LTFATE), the generated time series can be used for any application requiring tidal forcing data.

  6. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Elizabeth C. Chapman,† Rosemary C. Capo,† Brian W. Stewart,*,† Carl S. Kirby,‡ Richard W. Hammack,§

    2012-02-24

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ?375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (?Sr SW = +13.8 to +41.6, where ?Sr SW is the deviation of the 87Sr/86Sr ratio from that of seawater in parts per 104); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  7. Laboratory Report on Performance Evaluation of Key Constituents during Pre-Treatment of High Level Waste Direct Feed

    SciTech Connect (OSTI)

    Huber, Heinz J.

    2013-06-24

    The analytical capabilities of the 222-S Laboratory are tested against the requirements for an optional start up scenario of the Waste Treatment and Immobilization Plant on the Hanford Site. In this case, washed and in-tank leached sludge would be sent directly to the High Level Melter, bypassing Pretreatment. The sludge samples would need to be analyzed for certain key constituents in terms identifying melter-related issues and adjustment needs. The analyses on original tank waste as well as on washed and leached material were performed using five sludge samples from tanks 241-AY-102, 241-AZ-102, 241-AN-106, 241-AW-105, and 241-SY-102. Additionally, solid phase characterization was applied to determine the changes in mineralogy throughout the pre-treatment steps.

  8. TREATMENT OF PRODUCED WATERS USING A SURFACTANT MODIFIED ZEOLITE/VAPOR PHASE BIOREATOR SYSTEM

    SciTech Connect (OSTI)

    LYNN E. KATZ; KERRY A. KINNEY; R.S. BOWMAN; E.J. SULLIVAN

    2003-10-01

    Co-produced water from the oil and gas industry is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some of them must be treated to remove organic constituents before the water is discharged. An efficient, cost-effective treatment technology is needed to remove these constituents. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. Our previous DOE research work (DE-AC26-99BC15221) demonstrated that SMZ could successfully remove BTEX compounds from the produced water. In addition, SMZ could be regenerated through a simple air sparging process. The primary goal of this project is to develop a robust SMZ/VPB treatment system to efficiently remove the organic constituents from produced water in a cost-effective manner. This report summarizes work of this project from March 2003 through September 2003. We have continued our investigation of SMZ regeneration from our previous DOE project. Ten saturation/stripping cycles have been completed for SMZ columns saturated with BTEX compounds. The results suggest that BTEX sorption capacity is not lost after ten saturation/regeneration cycles. The composition of produced water from a site operated by Crystal Solutions Ltd. in Wyoming has been characterized and was used to identify key semi-volatile components. Isotherms with selected semi-volatile components have been initiated and preliminary results have been obtained. The experimental vapor phase bioreactors for this project have been designed and assembled to treat the off-gas from the SMZ regeneration process. These columns will be used both in the laboratory and in the proposed field testing to be conducted next year. Innocula for the columns that degrade all of the BTEX columns have been developed.

  9. Water Privatisation 

    E-Print Network [OSTI]

    Zölls, Elisa

    2011-08-17

    This dissertation deals with the policy issues of large-scale, urban water privatisation projects in the face of uncertainty and variability. The main objective is to evaluate whether a single policy approach, namely privatisation associated...

  10. Grabbing Water

    E-Print Network [OSTI]

    Reis, Pedro Miguel

    We introduce a novel technique for grabbing water with a flexible solid. This new passive pipetting mechanism was inspired by floating flowers and relies purely on the coupling of the elasticity of thin plates and the ...

  11. Effect of potential waste constituents on the reactivity of Hanford ferrocyanide wastes: Diluent, catalyst, and initiator studies

    SciTech Connect (OSTI)

    Scheele, R.D.; Johnston, J.W.; Tingey, J.M.; Burger, L.L.; Sell, R.L.

    1993-04-01

    During the 1980s, scientists at the Hanford Site began considering disposal options for wastes in underground storage tanks. As a result of safety concerns, it was determined that special consideration should be given to ferrocyanide-bearing wastes to ensure their continued safe storage. In addition, Westinghouse Hanford Company (WHC) chartered Pacific Northwest Laboratory (PNL) to determine the conditions necessary for vigorous reactions to occur in the Hanford Site ferrocyanide wastes. As part of those studies, PNL has evaluated the effects of selected potential waste constituents to determine how they might affect the reactivity of the wastes. The authors` investigations of the diluent, catalytic, or initiating effects of potential waste constituents included studies (1) to determine the effect of the oxidant-to-ferrocyanide ratio, (2) to establish the effect of sodium aluminate concentration, (3) to identify materials that could affect the explosivity of a mixture of sodium nickel ferricyanide (a potential aging product of ferrocyanide) and sodium nitrate and nitrite, (4) and to determine the effect of nickel sulfide concentration. They also conducted a thermal sensitivity study and analyzed the results to determine the relative behaviors of sodium nickel ferrocyanide and ferricyanide. A statistical evaluation of the time-to-explosion (TTX) test results from the catalyst and initiator screening study found that the ferricyanide reacted at a faster rate than did the ferrocyanide analog. The thermal analyses indicated that the ferricyanide form is more thermally sensitive, exhibiting exothermic behavior at a lower temperature than the ferrocyanide form. The increased thermal sensitivity of the ferricyanide, which is a potential oxidation product of ferrocyanide, relative to the ferrocyanide analog, does not support the hypothesis that aging independent of the reaction pathway will necessarily reduce the reaction hazard of ferrocyanide wastes.

  12. Several organic parameters on underlying hazardous constituents list can not be measured at the universal treatment standards

    SciTech Connect (OSTI)

    Johnson, H.C.

    1998-07-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) has several permitted treatment, storage and disposal facilities. The INEEL Sample Management Office (SMO) conducts all analysis subcontracting activities for Department of Energy Environmental Management programs at the INEEL. In this role, the INEEL SMO has had the opportunity to subcontract the analyses of various wastes (including ash from an interim status incinerator) requesting a target analyte list equivalent to the constituents listed in 40 Code of Federal Regulations. These analyses are required to ensure that treated wastes do not contain underlying hazardous constituents (UHC) at concentrations greater than the universal treatment standards (UTS) prior to land disposal. The INEEL SMO has conducted a good-faith effort by negotiating with several commercial laboratories to identify the lowest possible quantitation and detection limits that can be achieved for the organic UHC analytes. The results of this negotiating effort has been the discovery that no single laboratory (currently under subcontract with the INEEL SMO) can achieve a detection level that is within an order of magnitude of the UTS for all organic parameters on a clean sample matrix (e.g., sand). This does not mean that there is no laboratory that can achieve the order of magnitude requirements for all organic UHCs on a clean sample matrix. The negotiations held to date indicate that it is likely that no laboratory can achieve the order of magnitude requirements for a difficult sample matrix (e.g., an incinerator ash). The authors suggest that the regulation needs to be revised to address the disparity between what is achievable in the laboratory and the regulatory levels required by the UTS.

  13. Diagnosis of "fizz-gas" and gas reservoirs in deep-water environment De-hua Han, X RPL, Houston Unversity

    E-Print Network [OSTI]

    .78) 0 500 1000 1500 2000 2500 3000 3500 0 20 40 60 80 10 Brine Volume (%) Modulas(Mpa 0 6.9Mpa, 20C 34.5Mpa, 40C 69Mpa, 70C 103.5Mpa, 90C Oil Mixture of brine (50000ppm) & gas (0.78) 0 500 1000 1500 2000Mixture of brine (50000ppm) & gas (0.78) 0 500 1000 1500 2000 2500 3000 3500 0 20 40 60 80 10 Brine Volume

  14. Water Resources Policy & Economics

    E-Print Network [OSTI]

    Buehrer, R. Michael

    Water Resources Policy & Economics FOR 4984 Selected Course Topics · Appropriative and riparian water institutions · Incentives for conservation · Water rights for in-stream environmental use · Surface water-groundwater management · Water quality regulations · Water markets · Economic and policy

  15. Water Heaters and Hot Water Distribution Systems

    E-Print Network [OSTI]

    Lutz, Jim

    2012-01-01

    24 Figure 7. Comparison of Daily Water Heater28 Figure 8. Monitored Field Efficiency of Tankless Water28 Figure 9. Monitored Lab Efficiency of Tankless Water

  16. Characterization of Climax granite ground water

    SciTech Connect (OSTI)

    Isherwood, D.; Harrar, J.; Raber, E.

    1982-08-01

    The Climax ground water fails to match the commonly held views regarding the nature of deep granitic ground waters. It is neither dilute nor in equilibrium with the granite. Ground-water samples were taken for chemical analysis from five sites in the fractured Climax granite at the Nevada Test Site. The waters are high in total dissolved solids (1200 to 2160 mg/L) and rich in sodium (56 to 250 mg/L), calcium (114 to 283 mg/L) and sulfate (325 to 1060 mg/L). Two of the samples contained relatively high amounts of uranium (1.8 and 18.5 mg/L), whereas the other three contained uranium below the level of detection (< 0.1 mg/L). The pH is in the neutral range (7.3 to 8.2). The differences in composition between samples (as seen in the wide range of values for the major constituents and total dissolved solids) suggest the samples came from different, independent fracture systems. However, the apparent trend of increasing sodium with depth at the expense of calcium and magnesium suggests a common evolutionary chemical process, if not an interconnected system. The waters appear to be less oxidizing with depth (+ 410 mV at 420 m below the surface vs + 86 mV at 565 m). However, with Eh measurements on only two samples, this correlation is questionable. Isotopic analyses show that the waters are of meteoric origin and that the source of the sulfate is probably the pyrite in the fracture-fill material. Analysis of the measured water characteristics using the chemical equilibrium computer program EQ3 indicates that the waters are not in equilibrium with the local mineral assemblage. The solutions appear to be supersaturated with respect to the mineral calcite, quartz, kaolinite, muscovite, k-feldspar, and many others.

  17. Arnold Schwarzenegger WATER HEATERS AND HOT WATER

    E-Print Network [OSTI]

    Arnold Schwarzenegger Governor WATER HEATERS AND HOT WATER DISTRIBUTION SYSTEMS;#12;Appendices Appendix A. Multifamily Water Heating Construction Practices, Pricing and Availability Survey Report Appendix B. Multifamily Water Heating Controls Performance Field Report Appendix C. Pipe

  18. Water Heaters and Hot Water Distribution Systems

    E-Print Network [OSTI]

    Lutz, Jim

    2012-01-01

    in order to reduce the water and energy wasted in hot waterhot water) and 17% if hot water energy is included. The datafrom the delivered hot water energy of 66% to provide the

  19. Environmental impacts and sustainability of degraded water reuse

    SciTech Connect (OSTI)

    Corwin, D.L.; Bradford, S.A. [USDA ARS, Riverside, CA (United States). US Salin Laboratory

    2008-09-15

    Greater urban demand for finite water resources to meet domestic, agricultural, industrial, and recreational needs; increased frequency of drought resulting from erratic weather; and continued degradation of available water resources from point and nonpoint sources of pollution have focused attention on the reuse of degraded waters as a potential water source. However, short- and long-term detrimental environmental impacts and sustainability of degraded water reuse are not well known or understood. These concerns led to the organization of the 2007 ASA-CSSA-SSSA Symposium entitled Environmental Impacts and Sustainability of Degraded Water Reuse. Out of this symposium came a special collection of 4 review papers and 12 technical research papers focusing on various issues associated with the reuse of agricultural drainage water, well water generated in the production of natural gas from coalbeds, municipal wastewater and biosolids, wastewater from confined animal operations, urban runoff, and food-processing wastewater. Overviews of the papers, gaps in knowledge, and future research directions are presented. The future prognosis of degraded water reuse is promising, provided close attention is paid to managing constituents that pose short- and long-term threats to the environment and the health of humankind.

  20. A practical application for the chemical treatment of Southern California`s reclaimed, Title 22 water for use as makeup water for recirculating cooling water systems

    SciTech Connect (OSTI)

    Zakrzewski, J.; Cosulich, J.; Bartling, E.

    1998-12-31

    Pilot cooling water studies conducted at a Southern California landfill/cogeneration station demonstrated a successful chemical treatment program for recirculating cooling water that used unnitrified, reclaimed, Title 22 water as the primary makeup water source. The constituents in the reclaimed water are supplied by variety of residential and waste water sources resulting in a water quality that may vary to a greater degree than domestic water supplies. This water contains high concentrations of orthophosphate, ammonia, chlorides and suspended solids. The impact of which, under cycled conditions is calcium orthophosphate scaling, high corrosion of yellow metal and mild steel, stress cracking of copper alloys and stainless steel and rapidly growing biological activity. A mobile cooling water testing laboratory with two pilot recirculating water systems modeled the cogeneration station`s cooling tower operating conditions and parameters. The tube and shell, tube side cooling heat exchangers were fitted with 443 admiralty, 90/10 copper nickel, 316 stainless steel and 1202 mild steel heat exchanger tubes. Coupons and Corrater electrodes were also installed. A chemical treatment program consisting of 60/40 AA/AMPS copolymer for scale, deposits and dispersion, sodium tolyltriazole for yellow metal corrosion, and a bromination program to control the biological activity was utilized in the pilot systems. Recirculating water orthophosphate concentrations reached levels of 70 mg/L as PO, and ammonia concentrations reached levels of 35 mg/L, as total NH3. The study successfully demonstrated a chemical treatment program to control scale and deposition, minimize admiralty, 90/10 copper nickel and carbon steel corrosion rates, prevent non-heat transfer yellow metal and stainless steel stress cracking, and control the biological activity in this high nutrient water.

  1. Marketing water 

    E-Print Network [OSTI]

    Wythe, Kathy

    2008-01-01

    stream_source_info Marketing water savings.pdf.txt stream_content_type text/plain stream_size 9143 Content-Encoding ISO-8859-1 stream_name Marketing water savings.pdf.txt Content-Type text/plain; charset=ISO-8859-1 tx H2... are partnering with federal and state agencies and universities to develop new programs or market existing ones. In North Central Texas, the city of McKin- ney and Texas AgriLife Research and Exten- sion Urban Solutions Center at Dallas recently began...

  2. Ground-water monitoring at the Hanford Site, January-December 1984

    SciTech Connect (OSTI)

    Cline, C.S.; Rieger, J.T.; Raymond, J.R.

    1985-09-01

    This program is designed to evaluate existing and potential pathways of exposure to radioactivity and hazardous chemicals from site operations. This document contains an evaluation of data collected during CY 1984. During 1984, 339 monitoring wells were sampled at various times for radioactive and nonradioactive constituents. Two of these constituents, specifically, tritium and nitrate, have been selected for detailed discussion in this report. Tritium and nitrate in the primary plumes originating from the 200 Areas continue to move generally eastward toward the Columbia River in the direction of ground-water flow. The movement within these plumes is indicated by changes in trends within the analytical data from the monitoring wells. No discernible impact on ground water has yet been observed from the start-up of the PUREX plant in December 1983. The shape of the present tritium plume is similar to those described in previous ground-water monitoring reports, although slight changes on the outer edges have been noted. Radiological impacts from two potential pathways for radionuclide transport in ground water to the environment are discussed in this report. The pathways are: (1) human consumption of ground water from onsite wells, and (2) seepage of ground water into the Columbia River. Concentrations of tritium in spring samples that were collected and analyzed in 1983, and in wells sampled adjacent to the Columbia River in 1984 confirmed that constituents in the ground water are entering the river via springs and subsurface flow. The primary areas where radionuclides enter the Columbia River via ground-water flow are the 100-N and 300 Areas and the shoreline adjacent to the Hanford Townsite. 44 refs., 25 figs., 11 tabs.

  3. Part XI. University of North Carolina Policy Manual and the UNC Code As a constituent institution of the University of North Carolina, East Carolina University is subject to

    E-Print Network [OSTI]

    Gopalakrishnan, K.

    Part XI. University of North Carolina Policy Manual and the UNC Code As a constituent institution of the University of North Carolina, East Carolina University is subject to the policies in the University of North Carolina Policy Manual, which contains the Code of the Board of Governors of the University of North

  4. DEMONSTRATION OF LEACHXS/ORCHESTRA CAPABILITIES BY SIMULATING CONSTITUENT RELEASE FROM A CEMENTITIOUS WASTE FORM IN A REINFORCED CONCRETE VAULT

    SciTech Connect (OSTI)

    Langton, C.; Meeussen, J.; Sloot, H.

    2010-03-31

    The objective of the work described in this report is to demonstrate the capabilities of the current version of LeachXS{trademark}/ORCHESTRA for simulating chemical behavior and constituent release processes in a range of applications that are relevant to the CBP. This report illustrates the use of LeachXS{trademark}/ORCHESTRA for the following applications: (1) Comparing model and experimental results for leaching tests for a range of cementitious materials including cement mortars, grout, stabilized waste, and concrete. The leaching test data includes liquid-solid partitioning as a function of pH and release rates based on laboratory column, monolith, and field testing. (2) Modeling chemical speciation of constituents in cementitious materials, including liquid-solid partitioning and release rates. (3) Evaluating uncertainty in model predictions based on uncertainty in underlying composition, thermodynamic, and transport characteristics. (4) Generating predominance diagrams to evaluate predicted chemical changes as a result of material aging using the example of exposure to atmospheric conditions. (5) Modeling coupled geochemical speciation and diffusion in a three layer system consisting of a layer of Saltstone, a concrete barrier, and a layer of soil in contact with air. The simulations show developing concentration fronts over a time period of 1000 years. (6) Modeling sulfate attack and cracking due to ettringite formation. A detailed example for this case is provided in a separate article by the authors (Sarkar et al. 2010). Finally, based on the computed results, the sensitive input parameters for this type of modeling are identified and discussed. The chemical speciation behavior of substances is calculated for a batch system and also in combination with transport and within a three layer system. This includes release from a barrier to the surrounding soil as a function of time. As input for the simulations, the physical and chemical properties of the materials are used. The test cases used in this demonstration are taken from Reference Cases for Use in the Cementitious Barriers Partnership (Langton et al. 2009). Before it is possible to model the release of substances from stabilized waste or radioactive grout through a cement barrier into the engineered soil barrier or natural soil, the relevant characteristics of such materials must be known. Additional chemical characteristics are needed for mechanistic modeling to be undertaken, not just the physical properties relevant for modeling of transport. The minimum required properties for modeling are given in Section 5.0, 'Modeling the chemical speciation of a material'.

  5. Grabbing water

    E-Print Network [OSTI]

    P. M. Reis; J. Hure; S. Jung; J. W. M. Bush; C. Clanet

    2012-07-16

    We introduce a novel technique for grabbing water with a flexible solid. This new passive pipetting mechanism was inspired by floating flowers and relies purely on the coupling of the elasticity of thin plates and the hydrodynamic forces at the liquid interface. Developing a theoretical model has enabled us to design petal-shaped objects with maximum grabbing capacity.

  6. It's The Fluids SEG Honorary Lecture

    E-Print Network [OSTI]

    information please visit: #12;·WATER and BRINE (BRINE = H2O + Salt) ·HYDROCARBONS Oil Gas TYPES of PORE FLUIDS Gas Mixtures ·DRILLING MUD ·PRODUCTION FLUIDS Miscible Injectants (CO2, Enriched Gas) #12;From Ivar = Porosity = Density sat = 0 (1- ) + f Density: #12;·WATER and BRINE (BRINE = H2O + Salt) ·HYDROCARBONS Oil

  7. Water in the West

    E-Print Network [OSTI]

    Fahlund, Andrew; Choy, Min L. Janny; Szeptycki, Leon

    2014-01-01

    faced with the imperative that water is vital to all life onChoy* and Leon Szeptycki Water in the West Keywords: climategreen infrastructure; water; water-energy; water governance;

  8. Enabling better water management

    E-Print Network [OSTI]

    Greenslade, Diana

    CASE STUDY Enabling better water management Seasonal Streamflow Forecast Service influencing water decisions Water management decisions made with confidence Using the Bureau's streamflow forecasting, ACTEW Water confidently removed temporary water restrictions after the millennium drought. Millennium drought

  9. Free energy of the edge of an open lipid bilayer based on the interactions of its constituent molecules

    E-Print Network [OSTI]

    Meisam Asgari; Aisa Biria

    2015-04-05

    Lipid-bilayers are the fundamental constituents of the walls of most living cells and lipid vesicles, giving them shape and compartment. The formation and growing of pores in a lipid bilayer have attracted considerable attention from an energetic point of view in recent years. Such pores permit targeted delivery of drugs and genes to the cell, and regulate the concentration of various molecules within the cell. The formation of such pores is caused by various reasons such as changes in cell environment, mechanical stress or thermal fluctuations. Understanding the energy and elastic behaviour of a lipid-bilayer edge is crucial for controlling the formation and growth of such pores. In the present work, the interactions in the molecular level are used to obtain the free energy of the edge of an open lipid bilayer. The resulted free-energy density includes terms associated with flexural and torsional energies of the edge, in addition to a line-tension contribution. The line tension, elastic moduli, and spontaneous normal and geodesic curvatures of the edge are obtained as functions of molecular distribution, molecular dimensions, cutoff distance, and the interaction strength. These parameters are further analyzed by implementing a soft-core interaction potential in the microphysical model. The dependence of the elastic free-energy of the edge to the size of the pore is reinvestigated through an illustrative example, and the results are found to be in agreement with the previous observations.

  10. Acoustic-wave sensor apparatus for analyzing a petroleum-based composition and sensing solidification of constituents therein

    DOE Patents [OSTI]

    Spates, J.J.; Martin, S.J.; Mansure, A.J.

    1997-08-26

    An acoustic-wave sensor apparatus and method are disclosed. The apparatus for analyzing a normally liquid petroleum-based composition includes at least one acoustic-wave device in contact with the petroleum-based composition for sensing or detecting the presence of constituents (e.g. paraffins or petroleum waxes) therein which solidify upon cooling of the petroleum-based composition below a cloud-point temperature. The acoustic-wave device can be a thickness-shear-mode device (also termed a quartz crystal microbalance), a surface-acoustic-wave device, an acoustic-plate-mode device or a flexural plate-wave device. Embodiments of the present invention can be used for measuring a cloud point, a pour point and/or a freeze point of the petroleum-based composition, and for determining a temperature characteristic of each point. Furthermore, measurements with the acoustic-wave sensor apparatus can be made off-line by using a sample having a particular petroleum-based composition; or in-situ with the petroleum-based composition contained within a pipeline or storage tank. The acoustic-wave sensor apparatus has uses in many different petroleum technology areas, including the recovery, transport, storage, refining and use of petroleum and petroleum-based products. 7 figs.

  11. Acoustic-wave sensor apparatus for analyzing a petroleum-based composition and sensing solidification of constituents therein

    DOE Patents [OSTI]

    Spates, James J. (Albuquerque, NM); Martin, Stephen J. (Albuquerque, NM); Mansure, Arthur J. (Albuquerque, NM)

    1997-01-01

    An acoustic-wave sensor apparatus and method. The apparatus for analyzing a normally liquid petroleum-based composition includes at least one acoustic-wave device in contact with the petroleum-based composition for sensing or detecting the presence of constituents (e.g. paraffins or petroleum waxes) therein which solidify upon cooling of the petroleum-based composition below a cloud-point temperature. The acoustic-wave device can be a thickness-shear-mode device (also termed a quartz crystal mircrobalance), a surface-acoustic-wave device, an acoustic-plate-mode device or a flexural plate-wave device. Embodiments of the present invention can be used for measuring a cloud point, a pour point and/or a freeze point of the petroleum-based composition, and for determining a temperature characteristic of each point. Furthermore, measurements with the acoustic-wave sensor apparatus can be made off-line by using a sample having a particular petroleum-based composition; or in-situ with the petroleum-based composition contained within a pipeline or storage tank. The acoustic-wave sensor apparatus has uses in many different petroleum technology areas, including the recover transport, storage, refining and use of petroleum and petroleum-based products.

  12. Ordovician carbonate formation waters in the Illinois Basin: Chemical and isotopic evolution beneath a regional aquitard

    SciTech Connect (OSTI)

    Stueber, A.M. ); Walter, L.M. . Dept. of Geological Sciences)

    1992-01-01

    Formation waters from carbonate reservoirs in the upper Ordovician Galena Group of the Illinois Basin have been analyzed geochemically to study origin of salinity, chemical and isotopic evolution, and relation to paleohydrologic flow systems. These carbonate reservoirs underlie the Maquoketa Shale Group of Cincinnatian age, which forms a regional aquitard. Cl-Br relations and Na/Br-Cl/Br systematics indicate that initial brine salinity resulted from subaerial evaporation of seawater to a point not significantly beyond halite saturation. Subsequent dilution in the subsurface by meteoric waters is supported by delta D-delta O-18 covariance. Systematic relations between Sr-87/Sr-86 and 1/Sr suggest two distinct mixing events: introduction of a Sr-87 enriched fluid from a siliciclastic source, and a later event which only affected reservoir waters from the western shelf of the basin. The second mixing event is supported by covariance between Sr-87/Sr-86 and concentrations of cations and anions; covariance between Sr and O-D isotopes suggests that the event is related to meteoric water influx. Systematic geochemical relations in ordovician Galena Group formation waters have been preserved by the overlying Maquoketa shale aquitard. Comparison with results from previous studies indicates that waters from Silurian-Devonian carbonate strata evolved in a manner similar to yet distinct from that of the Ordovician carbonate waters, whereas waters from Mississippian-Pennsylvanian strata that overlie the New Albany Shale Group regional aquitard are marked by fundamentally different Cl-Br-Na and Sr isotope systematics. Evolution of these geochemical formation-water regimes apparently has been influenced significantly by paleohydrologic flow systems.

  13. Clean Water Act Section 401 Water Quality Certification: A Water...

    Open Energy Info (EERE)

    Clean Water Act Section 401 Water Quality Certification: A Water Quality Protection Tool for States and Tribes Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  14. Clean Water Act Section 401 Water Quality Certification A Water...

    Open Energy Info (EERE)

    Clean Water Act Section 401 Water Quality Certification A Water Quality Protection Tool for States and Tribes Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  15. UMTRA project water sampling and analysis plan, Naturita, Colorado

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    Surface remedial action is scheduled to begin at the Naturita UMTRA Project processing site in the spring of 1994. No water sampling was performed during 1993 at either the Naturita processing site (NAT-01) or the Dry Flats disposal site (NAT-12). Results of previous water sampling at the Naturita processing site indicate that ground water in the alluvium is contaminated as a result of uranium processing activities. Baseline ground water conditions have been established in the uppermost aquifer at the Dry Flats disposal site. Water sampling activities scheduled for April 1994 include preconstruction sampling of selected monitor wells at the processing site, surface water sampling of the San Miguel River, sampling of several springs/seeps in the vicinity of the disposal site, and sampling of two monitor wells in Coke Oven Valley. The monitor well locations provide sampling points to characterize ground water quality and flow conditions in the vicinity of the sites. The list of analytes has been updated to reflect constituents related to uranium processing activities and the parameters needed for geochemical evaluation. Water sampling will be conducted annually at minimum during the period of construction activities.

  16. Hanford Site ground-water monitoring for 1992

    SciTech Connect (OSTI)

    Dresel, P.E.; Newcomer, D.R.; Evans, J.C.; Webber, W.D.; Spane, F.A. Jr.; Raymond, R.G.; Opitz, B.E.

    1993-06-01

    Monitoring activities were conducted to determine the distribution of radionuclides and hazardous chemicals present in ground water as a result of Hanford Site operations and, whenever possible, relate the distribution of these constituents to Site operations. A total of 720 wells were sampled during 1992 by all Hanford ground-water monitoring activities. The Ground-Water Surveillance Project prepared water-table maps of DOE`s Hanford Site for June 1992 from water-level elevations measured in 287 wells across the Hanford Site and outlying areas. These maps are used to infer ground-water flow directions and gradients for the interpretation of contaminant transport. Water levels beneath the 200 Areas decreased as much as 0.75 m (2.5 ft) between December 1991 and December 1992. Water levels in the Cold Creek Valley decreased approximately 0.5 m in that same period. The water table adjacent to the Columbia River along the Hanford Reach continues to respond significantly to fluctuations in river stage. These responses were observed in the 100 and 300 areas. The elevation of the ground-water mound beneath B Pond did not change significantly between December 1991 and December 1992. However, water levels from one well located at the center of the mound indicate a water-level rise of approximately 0.3 m (1 ft) during the last quarter of 1992. Water levels measured from unconfined aquifer wells north and east of the Columbia River in 1992 indicate that the primary source of recharge is from irrigation practices.

  17. Innovative Water Management Technology to Reduce Environmental Impacts of Produced Water

    SciTech Connect (OSTI)

    Castle, James; Rodgers, John; Alley, Bethany; Beebe, Alex; Coffey, Ruthanne; Jurinko, Kristen; Pardue, Michael; Ritter, Tina; Spacil, Michael

    2013-05-15

    Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobic biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post-reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or ?footprint? of a full-size CWTS for a given inflow rate of produced water.

  18. Innovative Water Management Technology to Reduce Environment Impacts of Produced Water

    SciTech Connect (OSTI)

    Castle, James; Rodgers, John; Alley, Bethany; Coffey, Ruthanne; Jurinko, Kristen; Pardue, Michael; Ritter, Tina; Spacil, Michael

    2013-05-15

    Clemson University with Chevron as an industry partner developed and applied treatment technology using constructed wetland systems to decrease targeted constituents in simulated and actual produced waters to achieve reuse criteria and discharge limits. Pilot-scale and demonstration constructed wetland treatment system (CWTS) experiments led to design strategies for treating a variety of constituents of concern (COCs) in produced waters including divalent metals, metalloids, oil and grease, and ammonia. Targeted biogeochemical pathways for treatment of COCs in pilot-scale CWTS experiments included divalent metal sulfide precipitation through dissimilatory sulfate reduction, metal precipitation through oxidation, reduction of selenite to insoluble elemental selenium, aerobic biodegradation of oil, nitrification of ammonia to nitrate, denitrification of nitrate to nitrogen gas, separation of oil using an oilwater separator, and sorption of ammonia to zeolite. Treatment performance results indicated that CWTSs can be designed and built to promote specific environmental and geochemical conditions in order for targeted biogeochemical pathways to operate. The demonstration system successfully achieved consistent removal extents even while inflow concentrations of COCs in the produced water differed by orders of magnitude. Design strategies used in the pilot-scale and demonstration CWTSs to promote specific conditions that can be applied to designing full-scale CWTSs include plant and soil selection, water-depth selection, addition of amendments, and hydraulic retention time (HRT). These strategies allow conditions within a CWTS to be modified to achieve ranges necessary for the preferred biogeochemical treatment pathways. In the case of renovating a produced water containing COCs that require different biogeochemical pathways for treatment, a CWTS can be designed with sequential cells that promote different conditions. For example, the pilot-scale CWTS for post-reverse osmosis produced water was designed to promote oxidizing conditions within the first wetland cell for nitrification of ammonia, and the subsequent three cells were designed to promote reducing conditions for denitrification of nitrate. By incorporating multiple wetland cells in a CWTS, the conditions within each cell can be modified for removal of specific COCs. In addition, a CWTS designed with multiple cells allows for convenient sample collection points so that biogeochemical conditions of individual cells can be monitored and performance evaluated. Removal rate coefficients determined from the pilot-scale CWTS experiments and confirmed by the demonstration system can be used to calculate HRTs required to treat COCs in full-scale CWTSs. The calculated HRTs can then be used to determine the surface area or ?footprint? of a full-size CWTS for a given inflow rate of produced water.

  19. Management of water extracted from carbon sequestration projects

    SciTech Connect (OSTI)

    Harto, C. B.; Veil, J. A.

    2011-03-11

    Throughout the past decade, frequent discussions and debates have centered on the geological sequestration of carbon dioxide (CO{sub 2}). For sequestration to have a reasonably positive impact on atmospheric carbon levels, the anticipated volume of CO{sub 2} that would need to be injected is very large (many millions of tons per year). Many stakeholders have expressed concern about elevated formation pressure following the extended injection of CO{sub 2}. The injected CO{sub 2} plume could potentially extend for many kilometers from the injection well. If not properly managed and monitored, the increased formation pressure could stimulate new fractures or enlarge existing natural cracks or faults, so the CO{sub 2} or the brine pushed ahead of the plume could migrate vertically. One possible tool for management of formation pressure would be to extract water already residing in the formation where CO{sub 2} is being stored. The concept is that by removing water from the receiving formations (referred to as 'extracted water' to distinguish it from 'oil and gas produced water'), the pressure gradients caused by injection could be reduced, and additional pore space could be freed up to sequester CO{sub 2}. Such water extraction would occur away from the CO{sub 2} plume to avoid extracting a portion of the sequestered CO{sub 2} along with the formation water. While water extraction would not be a mandatory component of large-scale carbon storage programs, it could provide many benefits, such as reduction of pressure, increased space for CO{sub 2} storage, and potentially, 'plume steering.' Argonne National Laboratory is developing information for the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) to evaluate management of extracted water. If water is extracted from geological formations designated to receive injected CO{sub 2} for sequestration, the project operator will need to identify methods for managing very large volumes of water most of which will contain large quantities of salt and other dissolved minerals. Produced water from oil and gas production also typically contains large quantities of dissolved solids. Therefore, many of the same practices that are established and used for managing produced water also may be applicable for extracted water. This report describes the probable composition of the extracted water that is removed from the formations, options for managing the extracted water, the pros and cons of those options, and some opportunities for beneficial use of the water. Following the introductory material in Chapter 1, the report is divided into chapters covering the following topics: (Chapter 2) examines the formations that are likely candidates for CO{sub 2} sequestration and provides a general evaluation of the geochemical characteristics of the formations; (Chapter 3) makes some preliminary estimates of the volume of water that could be extracted; (Chapter 4) provides a qualitative review of many potential technologies and practices for managing extracted water and for each technology or management practice, pros and cons are provided; (Chapter 5) explores the potential costs of water management; and (Chapter 6) presents the conclusions.

  20. Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead

    SciTech Connect (OSTI)

    BC Technologies

    2009-12-30

    Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL confirmed the feasibility of the process. However, researchers at BCT were unable to develop equipment suitable for continuous operation and demonstration of the process in the field was not attempted. The significant achievements of the research area: Bench-scale batch results using carbon dioxide indicate >40% of the feed water to the hydrate formation reactor was converted to hydrate in a single pass; The batch results also indicate >23% of the feed water to the hydrate formation reactor (>50% of the hydrate formed) was converted to purified water of a quality suitable for discharge; Continuous discharge and collection of hydrates was achieved at atmospheric pressure. Continuous hydrate formation and collection at atmospheric conditions was the most significant achievement and preliminary economics indicate that if the unit could be made operable, it is potentially economic. However, the inability to continuously separate the hydrate melt fraction left the concept not ready for field demonstration and the project was terminated after Phase Two research.

  1. Cleaner, Safer Water through Water Safety Plans

    E-Print Network [OSTI]

    CS232615A Cleaner, Safer Water through Water Safety Plans National Center for Environmental Health (NCEH) Global Water, Sanitation, and Hygiene Team's Water Safety Plan Assistance 1.5 million deaths occur globally every year due to a lack of clean water, inadequate sanitation, and improper hygiene (1

  2. Ground water provides drinking water, irrigation for

    E-Print Network [OSTI]

    Saldin, Dilano

    they join tributaries to the Mississippi River. · The deep ground water divide is the underground boundary Deep ground water divide Racine Kenosha Walworth Waukesha Washington Ozaukee Milwaukee LAKE MICHIGANGround water provides drinking water, irrigation for crops and water for indus- tries. It is also

  3. Baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    This baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota, evaluates the potential impacts to public health or the environment from contaminated ground water at this site. This contamination is a result of the uraniferous lignite ashing process, when coal containing uranium was burned to produce uranium. Potential risk is quantified only for constituents introduced by the processing activities and not for the constituents naturally occurring in background ground water in the site vicinity. Background ground water, separate from any site-related contamination, imposes a percentage of the overall risk from ground water ingestion in the Bowman site vicinity. The US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is developing plans to address soil and ground water contamination at the site. The UMTRA Surface Project involves the determination of the extent of soil contamination and design of an engineered disposal cell for long-term storage of contaminated materials. The UMTRA Ground Water Project evaluates ground water contamination. Based on results from future site monitoring activities as defined in the site observational work plan and results from this risk assessment, the DOE will propose an approach for managing contaminated ground water at the Bowman site.

  4. Water Heaters and Hot Water Distribution Systems

    E-Print Network [OSTI]

    Lutz, Jim

    2012-01-01

    8 Assess California’s Small Gas Storage Water HeaterAssess California’s Small Gas Storage Water Heater Marketassess California’s small gas storage water heater market.

  5. Review and problem definition of water/rock reactions associated with injection of spent geothermal fluids from a geothermal plant into aquifers

    SciTech Connect (OSTI)

    Elders, W.A.

    1986-07-01

    Among the technical problems faced by the burgeoning geothermal industry is the disposal of spent fluids from power plants. Except in unusual circumstances the normal practice, especially in the USA, is to pump these spent fluids into injection wells to prevent contamination of surface waters, and possibly in some cases, to reduce pressure drawdown in the producing aquifers. This report is a survey of experience in geothermal injection, emphasizing geochemical problems, and a discussion of approaches to their possible mitigation. The extraction of enthalpy from geothermal fluid in power plants may cause solutions to be strongly supersaturated in various dissolved components such as silica, carbonates, sulfates, and sulfides. Injection of such supersaturated solutions into disposal wells has the potential to cause scaling in the well bores and plugging of the aquifers, leading to loss of injectivity. Various aspects of the geochemistry of geothermal brines and their potential for mineral formation are discussed, drawing upon a literature survey. Experience of brine treatment and handling, and the economics of mineral extraction are also addressed in this report. Finally suggestions are made on future needs for possible experimental, field and theoretical studies to avoid or control mineral scaling.

  6. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout /Two0Photos and Videos/01/2012 Page 1Water Power

  7. Efficient Water Use & Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Use Goal 4: Efficient Water Use & Management Aware of the arid climate of northern New Mexico, water reduction and conservation remains a primary concern at LANL. Energy...

  8. Saving Water Saves Energy

    E-Print Network [OSTI]

    McMahon, James E.; Whitehead, Camilla Dunham; Biermayer, Peter

    2006-01-01

    P. Potential Water and Energy Savings from Showerheads,Saving Water Saves Energy James E. McMahon, Camilla Dunhamavailable products. The energy savings associated with water

  9. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    paper describing produced water from production of crudeEmerging Issues Paper: Mine Water Pollution. Dep. Environ.40. Vine G. 2010. Cooling water issues and opportunities at

  10. Terrestrial Water Storage

    E-Print Network [OSTI]

    Rodell, M; Chambers, D P; Famiglietti, Jay

    2013-01-01

    with Subantarctic Mode Water. J. Geophys. Res. , 116,Global Climate] Stratospheric water vapor [in “State of the18 2. Total column water

  11. Storm Water Analytical Period

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Individual Permit Storm Water Analytical Period Storm Water Analytical Period The Individual Permit authorizes the discharge of storm water associated with historical industrial...

  12. Water in the West

    E-Print Network [OSTI]

    Fahlund, Andrew; Choy, Min L. Janny; Szeptycki, Leon

    2014-01-01

    connections between water and energy, advances in knowledgeimportant nexus between water and energy. The demand fortwo reports on the water and energy nexus highlighting the

  13. Saving Water Saves Energy

    E-Print Network [OSTI]

    McMahon, James E.; Whitehead, Camilla Dunham; Biermayer, Peter

    2006-01-01

    P. Potential Water and Energy Savings from Showerheads,shorter showers). Water- and energy- conserving activitiesstress imposed on limited water (and energy) supplies from

  14. Drinking Water Standards 

    E-Print Network [OSTI]

    Dozier, Monty; McFarland, Mark L.

    2006-04-26

    This publication explains the federal safety standards for drinking water provided by public water supply systems. It discusses the legal requirements for public water supplies, the maximum level allowed for contaminants in the water...

  15. Drinking Water Problems: Nitrates 

    E-Print Network [OSTI]

    Dozier, Monty; Melton, Rebecca; Hare, Michael; Hopkins, Janie; Lesikar, Bruce J.

    2008-03-28

    at http://ag.arizona.edu/pubs/water/ az9420.pdf. ?Drinking Water Treatment: Distillation.? Nebraska Cooperative Extension. Available at http://ianrpubs. unl.edu/water/g1493.htm. ?Electrodyalisis.? GE Infrastructure Water & Process Technologies. General...

  16. Integrated regional water management: Collaboration or water politics as usual?

    E-Print Network [OSTI]

    Lubell, Mark N.; Lippert, Lucas

    2010-01-01

    the water quality and waste water elements. At the sameAll water supply, waste water, and flood control agenciesprovide services like waste water treatment and drinking

  17. Atomizing, continuous, water monitoring module

    DOE Patents [OSTI]

    Thompson, C.V.; Wise, M.B.

    1997-07-08

    A system for continuously analyzing volatile constituents of a liquid is described. The system contains a pump for continuously pumping the liquid to be tested at a predetermined flow rate into an extracting container through a liquid directing tube having an orifice at one end and positioned to direct the liquid into the extracting container at a flow rate sufficient to atomize the liquid within the extracting container. A continuous supply of helium carrier gas at a predetermined flow rate is directed through a tube into the extracting container and co-mingled with the atomized liquid to extract the volatile constituents contained within the atomized liquid. The helium containing the extracted volatile constituents flows out of the extracting container into a mass spectrometer for an analysis of the volatile constituents of the liquid. 3 figs.

  18. Atomizing, continuous, water monitoring module

    DOE Patents [OSTI]

    Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

    1997-01-01

    A system for continuously analyzing volatile constituents of a liquid is described. The system contains a pump for continuously pumping the liquid to be tested at a predetermined flow rate into an extracting container through a liquid directing tube having an orifice at one end and positioned to direct the liquid into the extracting container at a flow rate sufficient to atomize the liquid within the extracting container. A continuous supply of helium carrier gas at a predetermined flow rate is directed through a tube into the extracting container and co-mingled with the atomized liquid to extract the volatile constituents contained within the atomized liquid. The helium containing the extracted volatile constituents flows out of the extracting container into a mass spectrometer for an analysis of the volatile constituents of the liquid.

  19. Water watch

    SciTech Connect (OSTI)

    Not Available

    1991-02-01

    The Hydropower Generation Report provides generation figures for the largest hydropower producers in each of six regions in the US. The report compares, for each month, the amount of hydroelectricity generated (in thousands of megawatt-hours) by each producers in the last two years to the ten-year average for that month. This database is used to figure long-term generation averages and percent of averages. The producers regularly provide current generation data to update the database. This issue of [open quotes]Water Watch[close quotes] focuses on winter snow conditions across the US as of mid-January. In addition, the department provides an outlook of spring flood potential. The information presented is based on data from the US Geological Survey, the National Weather Service, and the Soil Conservation Service.

  20. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    Geothermal . 20 Energy Used for Water Services . 20 Transporting Water 21 Pumping Groundwater. 22 Treating Wastewater 23 Desalination ..

  1. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    2004-02-19

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  2. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  3. Modeling CO{sub 2}-Brine-Rock Interaction Including Mercury and H{sub 2}S Impurities in the Context of CO{sub 2} Geologic Storage

    SciTech Connect (OSTI)

    Spycher, N.; Oldenburg, C.M.

    2014-01-01

    This study uses modeling and simulation approaches to investigate the impacts on injectivity of trace amounts of mercury (Hg) in a carbon dioxide (CO{sub 2}) stream injected for geologic carbon sequestration in a sandstone reservoir at ~2.5 km depth. At the range of Hg concentrations expected (7-190 ppbV, or ~ 0.06-1.6 mg/std.m{sup 3}CO{sub 2}), the total volumetric plugging that could occur due to complete condensation of Hg, or due to complete precipitation of Hg as cinnabar, results in a very small porosity change. In addition, Hg concentration much higher than the concentrations considered here would be required for Hg condensation to even occur. Concentration of aqueous Hg by water evaporation into CO{sub 2} is also unlikely because the higher volatility of Hg relative to H{sub 2}O at reservoir conditions prevents the Hg concentration from increasing in groundwater as dry CO{sub 2} sweeps through, volatilizing both H{sub 2}O and Hg. Using a model-derived aqueous solution to represent the formation water, batch reactive geochemical modeling show that the reaction of the formation water with the CO{sub 2}-Hg mixture causes the pH to drop to about 4.7 and then become buffered near 5.2 upon reaction with the sediments, with a negligible net volume change from mineral dissolution and precipitation. Cinnabar (HgS(s)) is found to be thermodynamically stable as soon as the Hg-bearing CO{sub 2} reacts with the formation water which contains small amounts of dissolved sulfide. Liquid mercury (Hg(l)) is not found to be thermodynamically stable at any point during the simulation. Two-dimensional radial reactive transport simulations of CO{sub 2} injection at a rate of 14.8 kg/s into a 400 m-thick formation at isothermal conditions of 106°C and average pressure near 215 bar, with varying amounts of Hg and H{sub 2}S trace gases, show generally that porosity changes only by about ±0.05% (absolute, i.e., new porosity = initial porosity ±0.0005) with Hg predicted to readily precipitate from the CO{sub 2} as cinnabar in a zone mostly matching the single-phase CO{sub 2} plume. The precipitation of minerals other than cinnabar, however, dominates the evolution of porosity. Main reactions include the replacement of primarily Fe-chlorite by siderite, of calcite by dolomite, and of K-feldspar by muscovite. Chalcedony is also predicted to precipitate from the dissolution of feldspars and quartz. Although the range of predicted porosity change is quite small, the amount of dissolution and precipitation predicted for these individual minerals is not negligible. These reactive transport simulations assume that Hg gas behaves ideally. To examine effects of non-ideality on these simulations, approximate calculations of the fugacity coefficient of Hg in CO{sub 2} were made. Results suggest that Hg condensation could be significantly overestimated when assuming ideal gas behavior, making our simulation results conservative with respect to impacts on injectivity. The effect of pressure on Henry’s constant for Hg is estimated to yield Hg solubilities about 10% lower than when this effect is not considered, a change that is considered too small to affect the conclusions of this report. Although all results in this study are based on relatively mature data and modeling approaches, in the absence of experimental data and more detailed site-specific information, it is not possible to fully validate the results and conclusions.

  4. EXTENSION WATER SUMMIT PRIORITY: WATER QUALITY

    E-Print Network [OSTI]

    Slatton, Clint

    EXTENSION WATER SUMMIT PRIORITY: WATER QUALITY Leadership Team Subcommittee: Mark Clark Karl Havens BJ Jarvis Kelly Morgan Ramesh Reddy #12;Water Quality ­ Situation (resources) Florida has extensive and diverse water resources 54,836 miles of rivers and streams 1.8 million acres of lakes, reservoirs

  5. Effects of coal fly-ash disposal on water quality in and around the Indiana Dunes National Lakeshore, Indiana. Water-resources investigations (final)

    SciTech Connect (OSTI)

    Hardy, M.A.

    1981-04-01

    Dissolved constituents in seepage from fly-ash settling ponds bordering part of the Indiana Dunes National Lakeshore (the Lakeshore) have increased trace elements, and gross alpha and gross beta radioactivity in ground water and surface water downgradient from the settling ponds. Data suggest that concentrations of some dissolved trace elements may be greater beneath interdunal pond 2 than in the pond. The soil system downgradient from the settling ponds seems to have affected the concentrations of dissolved ions in the settling-pond seepage. Calcium concentrations were greater in ground water downgradient from the settling ponds than in the ponds. Where organic material was present downgradient from the settling ponds, concentrations of arsenic, fluoride, molybdenum, potassium, sulfate, and strontium were greater in the ground water than in the ponds. In contrast, the concentrations of cadmium, copper, nickel, aluminum, cobalt, lead, and zinc were less.

  6. Water Heating | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Public Services Homes Water Heating Water Heating Infographic: Water Heaters 101 Infographic: Water Heaters 101 Everything you need to know about saving money on water...

  7. Water Basins Civil Engineering

    E-Print Network [OSTI]

    Provancher, William

    Water Basins Civil Engineering Objective · Connect the study of water, water cycle, and ecosystems with engineering · Discuss how human impacts can effect our water basins, and how engineers lessen these impacts: · The basic concepts of water basins are why they are important · To use a topographic map · To delineate

  8. Grains, Water Introduction

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Grains, Water & Wet Sand Onno Bokhove Introduction Dry Granular Chute Flows: Cantilever Water Waves: Bores Near the Shore Surf Induced Sand Dynamics Discussion Dry Granular Flows, Water Waves & Surf, Water & Wet Sand Onno Bokhove Introduction Dry Granular Chute Flows: Cantilever Water Waves: Bores Near

  9. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 9: Water in Agriculture () January 13, 2010 1 / 14 #12;Water in Agriculture Historically: Biggest consumer of water, in developed kilos of sugar. Though the source of water in all the three cases is usually different. Agriculture

  10. Stratospheric Temperatures and Water Loss from Moist Greenhouse Atmospheres of Earth-like Planets

    E-Print Network [OSTI]

    Kasting, James F; Kopparapu, Ravi Kumar

    2015-01-01

    A radiative-convective climate model is used to calculate stratospheric temperatures and water vapor concentrations for ozone-free atmospheres warmer than that of modern Earth. Cold, dry stratospheres are predicted at low surface temperatures, in agreement with recent 3-D calculations. However, at surface temperatures above 350 K, the stratosphere warms and water vapor becomes a major upper atmospheric constituent, allowing water to be lost by photodissociation and hydrogen escape. Hence, a 'moist greenhouse' explanation for loss of water from Venus, or some exoplanet receiving a comparable amount of stellar radiation, remains a viable hypothesis. Temperatures in the upper parts of such atmospheres are well below those estimated for a gray atmosphere, and this factor should be taken into account when performing 'inverse' climate calculations to determine habitable zone boundaries using 1-D models.

  11. Water ice deuteration: a tracer of the chemical history of protostars

    E-Print Network [OSTI]

    Taquet, Vianney; Kahane, Claudine; Ceccarelli, Cecilia; Lòpez-Sepulcre, Ana; Toubin, Céline; Duflot, Denis; Wiesenfeld, Laurent

    2012-01-01

    Context. Millimetric observations have measured large degrees of molecular deuteration in several species seen around low-mass protostars. The Herschel Space Telescope, launched in 2009, is now providing new measures of the deuterium fractionation of water, the main constituent of interstellar ices. Aims. We aim at theoretically studying the formation and the deuteration of water which is believed to be formed on interstellar grain surfaces in molecular clouds. Methods. We used our gas-grain astrochemical model GRAINOBLE which considers the multilayer formation of interstellar ices. We varied several input parameters to study their impact on water deuteration. We included the treatment of ortho and para states of key species, including H2, that affects the deuterium fractionation of all molecules. The model also includes relevant laboratory and theoretical works on water formation and deuteration on grain surfaces. In particular, we computed the transmission probabilities of surface reactions using the Eckart...

  12. Mesoscopic modeling of liquid water transport in polymer electrolyte fuel cells

    SciTech Connect (OSTI)

    Mukherjee, Partha P [Los Alamos National Laboratory; Wang, Chao Yang [PENNSTATE UNIV.

    2008-01-01

    A key performance limitation in polymer electrolyte fuel cells (PEFC), manifested in terms of mass transport loss, originates from liquid water transport and resulting flooding phenomena in the constituent components. Liquid water leads to the coverage of the electrochemically active sites in the catalyst layer (CL) rendering reduced catalytic activity and blockage of the available pore space in the porous CL and fibrous gas diffusion layer (GDL) resulting in hindered oxygen transport to the active reaction sites. The cathode CL and the GDL therefore playa major role in the mass transport loss and hence in the water management of a PEFC. In this article, we present the development of a mesoscopic modeling formalism coupled with realistic microstructural delineation to study the profound influence of the pore structure and surface wettability on liquid water transport and interfacial dynamics in the PEFC catalyst layer and gas diffusion layer.

  13. Household Water Quality Home Water Quality Problems

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    Household Water Quality Home Water Quality Problems­ Causes and Treatments Blake Ross, Extension impurities can be corrected if they are a nuisance. Before beginning any treatment plan, have water tested select the most effective and economical treatment method. www.ext.vt.edu Produced by Communications

  14. Chemistry of spring and well waters on Kilauea Volcano, Hawaii, and vicinity

    SciTech Connect (OSTI)

    Janik, C.J.; Nathenson, M.; Scholl, M.A.

    1994-12-31

    Published and new data for chemical and isotopic samples from wells and springs on Kilauea Volcano and vicinity are presented. These data are used to understand processes that determine the chemistry of dilute meteoric water, mixtures with sea water, and thermal water. Data for well and spring samples of non-thermal water indicate that mixing with sea water and dissolution of rock from weathering are the major processes that determine the composition of dissolved constituents in water. Data from coastal springs demonstrate that there is a large thermal system south of the lower east rift of Kilauea. Samples of thermal water from shallow wells in the lower east rift and vicinity have rather variable chemistry indicating that a number of processes operate in the near surface. Water sampled from the available deep wells is different in composition from the shallow thermal water, indicating that generally there is not a significant component of deep water in the shallow wells. Data for samples from available deep wells show significant gradients in chemistry and steam content of the reservoir fluid. These gradients are interpreted to indicate that the reservoir tapped by the existing wells is an evolving vapor-dominated system.

  15. Review: Globalization of Water

    E-Print Network [OSTI]

    Tennant, Matthew Aaron

    2009-01-01

    Review: Globalization of Water: Sharing the Planet’sAshok K. Globalization of Water: Sharing the Planet’s140) liters of virtual water (p. 15). This is one of the

  16. RETORT WATER PARTICULATES

    E-Print Network [OSTI]

    2011-01-01

    layer of retort water from the filter surface, (3) crystaldeep layer of retort water from the filter surface, from C02distilled water before placing the filter RETORT OPERATING

  17. Lawn Water Management 

    E-Print Network [OSTI]

    McAfee, James

    2006-06-26

    Water is a limited resource in Texas. This booklet explains how homeowners can establish a water management program for a home lawn that both maintains a healthy sod and also conserves water. The publication discusses soil types, grass varieties...

  18. Saving Water Saves Energy

    E-Print Network [OSTI]

    McMahon, James E.; Whitehead, Camilla Dunham; Biermayer, Peter

    2006-01-01

    H. , Groves D. California Water 2030: An Efficient Future,Preemption of California’s Water Conservation Standards for2Epdf Biermayer P. Potential Water and Energy Savings from

  19. Landscape Plants: Fertilizing & Watering

    E-Print Network [OSTI]

    Ishida, Yuko

    Landscape Plants: Fertilizing & Watering Landscape Plants: Fertilizing & Watering Prevent runoff and shrubs, either through directly killing plants or making them more prone to disease. Fertilizer runoff into storm drains pollutes waterways. Maintain plant health and protect water quality by fertilizing

  20. Water Conservation Tips

    E-Print Network [OSTI]

    Brown, Martha

    2008-01-01

    Gardener Water Conservation Tips fo r t h e UCSC Farm &aware of the need to use water responsibly, whether or notcut landscape and garden water needs. Here we share some of

  1. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    2009. Thirsty Energy: Water and Energy in the 21st Century.Summary Points 1. Water and energy are strongly dependent onof bioenergy increases water and energy interdependence. 3.

  2. Effect of water in salt repositories. Final report

    SciTech Connect (OSTI)

    Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

    1983-09-01

    Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

  3. Carbon and Water Resource Management for Water Distribution Systems

    E-Print Network [OSTI]

    Hendrickson, Thomas Peter

    2013-01-01

    4 April, 2013. (4) 2010 Water Use Survey Summary Estimates –State Totals; Texas Water Development Board: Austin, TX,indicators for urban water systems. Urban Water. 2004, 4,

  4. Interfacial water on crystalline silica: A comparative molecular dynamics simulation study

    SciTech Connect (OSTI)

    Ho, Tuan A. [University of Oklahoma, Norman; Argyris, D. [University of Oklahoma, Norman; Cole, David [Ohio State University; Striolo, Alberto [Oklahoma University

    2011-01-01

    All-atom molecular dynamics simulations were conducted to study the dynamics of aqueous electrolyte solutions confined in slit-shaped silica nanopores of various degrees of protonation. Five degrees of protonation were prepared by randomly removing surface hydrogen atoms from fully protonated crystalline silica surfaces. Aqueous electrolyte solutions containing NaCl or CsCl salt were simulated at ambient conditions. In all cases, the ionic concentration was 1 M. The results were quantified in terms of atomic density distributions within the pores, and the self-diffusion coefficient along the direction parallel to the pore surface. We found evidence for ion-specific properties that depend on ion surface, water ion, and only in some cases ion ion correlations. The degree of protonation strongly affects the structure, distribution, and the dynamic behavior of confined water and electrolytes. Cl ions adsorb on the surface at large degrees of protonation, and their behavior does not depend significantly on the cation type (either Na+ or Cs+ ions are present in the systems considered). The cations show significant ion-specific behavior. Na+ ions occupy different positions within the pore as the degree of protonation changes, while Cs+ ions mainly remain near the pore center at all conditions considered. For a given degree of protonation, the planar self-diffusion coefficient of Cs+ is always greater than that of Na+ ions. The results are useful for better understanding transport under confinement, including brine behavior in the subsurface, with important applications such as environmental remediation.

  5. Microbial communities in flowback water impoundments from hydraulic fracturing for recovery of shale gas

    SciTech Connect (OSTI)

    Mohan, Arvind Murali; Hartsock, Angela; Hammack, Richard W.; Vidic, Radisav D; Gregory, Kelvin B.

    2013-12-01

    Hydraulic fracturing for natural gas extraction from shale produces waste brine known as flowback that is impounded at the surface prior to reuse and/or disposal. During impoundment, microbial activity can alter the fate of metals including radionuclides, give rise to odorous compounds, and result in biocorrosion that complicates water and waste management and increases production costs. Here, we describe the microbial ecology at multiple depths of three flowback impoundments from the Marcellus shale that were managed differently. 16S rRNA gene clone libraries revealed that bacterial communities in the untreated and biocide-amended impoundments were depth dependent, diverse, and most similar to species within the taxa [gamma]-proteobacteria, [alpha]-proteobacteria, ?-proteobacteria, Clostridia, Synergistetes, Thermotogae, Spirochetes, and Bacteroidetes. The bacterial community in the pretreated and aerated impoundment was uniform with depth, less diverse, and most similar to known iodide-oxidizing bacteria in the [alpha]-proteobacteria. Archaea were identified only in the untreated and biocide-amended impoundments and were affiliated to the Methanomicrobia class. This is the first study of microbial communities in flowback water impoundments from hydraulic fracturing. The findings expand our knowledge of microbial diversity of an emergent and unexplored environment and may guide the management of flowback impoundments.

  6. Water Efficiency Goal Guidance

    Broader source: Energy.gov [DOE]

    The Council on Environmental Quality (CEQ) issued water efficiency goal guidance in Federal Agency Implementation of Water Efficiency and Management Provisions of Executive Order 13514. This...

  7. Drinking Water Problems: Copper 

    E-Print Network [OSTI]

    Dozier, Monty; McFarland, Mark L.; Lesikar, Bruce J.

    2006-01-25

    High levels of copper in drinking water can cause health problems. This publication explains the effects of copper in water and methods of removing it. 4 pp....

  8. Irrigation Water Quality Salinity Management

    E-Print Network [OSTI]

    and industrial waste water can impact water quality. In most irrigation situations, the primary water qual- ity

  9. Carbon and Water Program Protocols for Neutrally Buoyant Sediment Traps Twilight Zone Explorer at BATS, June 2007-December 2009

    E-Print Network [OSTI]

    Buesseler, Ken

    pump o Tubing (CTD to Flojet to filter holder to carboy) o Small carboys of brine o Volumetric flasks of sediment trap tubes #12;o Measure out 500 mL of brine with volumetric flask o Insert tubing into tube

  10. Water-heating dehumidifier

    DOE Patents [OSTI]

    Tomlinson, John J. (Knoxville, TN)

    2006-04-18

    A water-heating dehumidifier includes a refrigerant loop including a compressor, at least one condenser, an expansion device and an evaporator including an evaporator fan. The condenser includes a water inlet and a water outlet for flowing water therethrough or proximate thereto, or is affixed to the tank or immersed into the tank to effect water heating without flowing water. The immersed condenser design includes a self-insulated capillary tube expansion device for simplicity and high efficiency. In a water heating mode air is drawn by the evaporator fan across the evaporator to produce cooled and dehumidified air and heat taken from the air is absorbed by the refrigerant at the evaporator and is pumped to the condenser, where water is heated. When the tank of water heater is full of hot water or a humidistat set point is reached, the water-heating dehumidifier can switch to run as a dehumidifier.

  11. Enhancing Drinking Water Supply by Better Understanding Surface Water Ground Water Interaction

    E-Print Network [OSTI]

    Rhode Island, University of

    Enhancing Drinking Water Supply by Better Understanding Surface Water ­ Ground Water Interaction Primary Investigators Thomas Boving Anne Veeger Patricia Logan #12;Enhancing Drinking Water Supply by Better Understanding Surface Water ­ Ground Water Interaction Thomas Boving, Anne Veeger & Patricia Logan

  12. WaterSense Program: Methodology for National Water Savings Analysis Model Indoor Residential Water Use

    E-Print Network [OSTI]

    McNeil, Michael

    2008-01-01

    Fixtures Market Overview: Water Savings Potential forNew Jersey. American Water Works Association ResearchResidential End Uses of Water (REUWS). 1999. American Water

  13. Irrigation Water Quality 

    E-Print Network [OSTI]

    McFarland, Mark L.; Lemon, Robert G.; Stichler, Charles

    2002-04-11

    Irrigation water quality is determined by the total amounts of salts and the types of salts the water contains. In this publication you'll learn why well water can be salty, what problems salty water can cause, what tests should be done...

  14. Landscape Design & Water Quality

    E-Print Network [OSTI]

    Ishida, Yuko

    drainage lines to allow water to filter into surrounding soils. Install gravel sumps or other percolationLandscape Design & Water Quality Landscape Design & Water Quality Create a landscape design that reduces pesticide and fertilizer runoff and conserves water. Good plant choices, proper site preparation

  15. Drinking Water Problems: Corrosion

    E-Print Network [OSTI]

    valves and other water control surfaces, creating leaks inside and outside of valves and faucetsDrinking Water Problems: Corrosion Mark L. McFarland, Tony L. Provin, and Diane E. Boellstorff* Professor and Extension Water Quality Coordinator, Professor and Extension Water Testing Laboratory Director

  16. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 8: Wells () August 28, 2012 project, utilizing enhanced ground-water. Water lifted from storage, to accumulate overnight from aquifer. Water from shallow aquifer, of about 7-8m thickness. accounts for about 30% of irrigation Unique

  17. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 2: Water cycle, stocks and flows () July 28, 2013 1 / 30 #12;The basic movement of water source: USGS. () July 28, 2013 2 / 30 #12, humidity and air flow. Formation of liquid-water in the Atmosphere-Cloud-Formation Coming Down Rain

  18. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 7: Regional Groundwater than the unit situations that we saw. Surface water/Groundwater interactions. lakes and streams springs (seepage) Ambient water-table movements Seasonal changes Inteference with other water end-users. Inherent

  19. Water Waves Roger Grimshaw

    E-Print Network [OSTI]

    Water Waves Roger Grimshaw May 7, 2003 Abstract A short review of the theory of weakly nonlinear water waves, prepared for the forthcoming Encyclopedia of Nonlinear Science 1 Introduction Water waves nonlinear waves. Throughout the theory is based on the traditional assumptions that water is inviscid

  20. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 5: Aquifer () August 16 above and below the ground, which affect the water balance. surface features affect infiltration parameters related to water: Porosity, specific yield n, Sy : the maximum volume fraction of water

  1. Vadose zone water fluxmeter

    DOE Patents [OSTI]

    Faybishenko, Boris A.

    2005-10-25

    A Vadose Zone Water Fluxmeter (WFM) or Direct Measurement WFM provides direct measurement of unsaturated water flow in the vadose zone. The fluxmeter is a cylindrical device that fits in a borehole or can be installed near the surface, or in pits, or in pile structures. The fluxmeter is primarily a combination of tensiometers and a porous element or plate in a water cell that is used for water injection or extraction under field conditions. The same water pressure measured outside and inside of the soil sheltered by the lower cylinder of the fluxmeter indicates that the water flux through the lower cylinder is similar to the water flux in the surrounding soil. The fluxmeter provides direct measurement of the water flow rate in the unsaturated soils and then determines the water flux, i.e. the water flow rate per unit area.

  2. SUSTAINABLE URBAN WATER MANAGEMENT

    E-Print Network [OSTI]

    Das, Suman

    consumption Vehicle production 0.77 0.59 0.79 0.32 4.35 0.44 12.25 2.45 3.85 0.97 (Source: Harto, C; et al% Mining; 1% Decentralized Water Production (LID) Decentralized Energy Production Urban Farming #12;Water Footprint of Agricultural Products #12;`Water for Energy' and `Energy for Water' in US Water for Energy

  3. Water Management Best Practices 

    E-Print Network [OSTI]

    Hoffman, W.

    2011-01-01

    Municipal Manufacturing Mining Steam Electric Agriculture New Codes & Standards Green Certification& Labeling Programs ? Green Restaurants, Hotels, etc. ? Green Guide for Health Care ? LEED ? GBI ? EPA Water Sense ? EPA Energy Star US Green... of Assistance ? Texas Water Development Board ? www.twdb.state.tx.us ? California Urban Water Conservation Council ? www.cuwcc.org ? Alliance for Water Efficiency www.allianceforwaterefficiency.org ? EPA Water Sense and Energy Star Programs ? www...

  4. Ground water and energy

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    This national workshop on ground water and energy was conceived by the US Department of Energy's Office of Environmental Assessments. Generally, OEA needed to know what data are available on ground water, what information is still needed, and how DOE can best utilize what has already been learned. The workshop focussed on three areas: (1) ground water supply; (2) conflicts and barriers to ground water use; and (3) alternatives or solutions to the various issues relating to ground water. (ACR)

  5. Innovative Water Reuse 

    E-Print Network [OSTI]

    Jaber, F. H.

    2011-01-01

    . Introduction 2. Water conservation indoors 1. Retrofit practices 2. Cooling towers 3. Education 3. Water conservation outdoors 1. Landscape practices 2. Irrigation 3. Rainwater harvesting 4.Greywater 4. Stormwater management 1.Rain... ? Plant selection ? Irrigation practices What Can We Do? (cont?d) ? Water Conservation ? New buildings ? Greywater reuse ? Efficient water towers ? A/C Condensate reuse Bathroom ? Faucet Aerators ? Aerators mix air and water together...

  6. Reactor water cleanup system

    DOE Patents [OSTI]

    Gluntz, D.M.; Taft, W.E.

    1994-12-20

    A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling. 1 figure.

  7. Reactor water cleanup system

    DOE Patents [OSTI]

    Gluntz, Douglas M. (San Jose, CA); Taft, William E. (Los Gatos, CA)

    1994-01-01

    A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling.

  8. Endothelial cell permeability to water and antipyrine

    SciTech Connect (OSTI)

    Garrick, R.A.

    1986-03-05

    The endothelium provides a structural barrier between plasma constituents and the tissues. The permeability characteristics of the the endothelial cells regulate the transcellular movement of materials across this barrier while other movement is paracellular. In this study the permeability of the endothelial cells to tritiated water (/sup 3/HHO) and /sup 14/C-labeled antipyrine (AP) was investigated. The cells were isolated non-enzymatically from calf pulmonary artery and were maintained in culture and used between the seventh and fifteenth passage. The cells were removed from the T-flasks with a rubber policeman, titurated with a 22g needle and centrifuged. The cells were mixed with an extracellular marker, drawn into polyethylene tubing and packed by centrifugation for use in the linear diffusion technique. All measurements were made at 37 C. The diffusion coefficients for /sup 3/HHO through the packed cells (D), the intracellular material (D/sub 2/), and the extracellular material (D/sub 1/) were 0.682, 0.932 and 2.45 x 10/sup -5/ cm/sup 2/ s/sup -1/ and for AP were 0.273, 0.355 and 1.13 x 10/sup -5/ cm/sup 2/ s/sup -1/ respectively. The permeability coefficient calculated by the series-parallel pathway model for /sup 3/HHO was higher than that for AP and for both /sup 3/HHO and AP were lower than those calculated for isolated lung cells and erythrocytes.

  9. Hanford Site ground-water monitoring for April through June 1987

    SciTech Connect (OSTI)

    Evans, J.C.; Mitchell, P.J.; Dennison, D.I.

    1988-01-01

    Pacific Northwest Laboratory (PNL) is conducting ground-water monitoring at the Hanford Site. Results for monitoring by PNL and Westinghouse Hanford Company (WHC) during April-June 1987 show that certain regulated hazardous materials and radionuclides exist in Hanford Site ground waters. The presence of regulated constituents in the ground water derives both from site operations and from natural sources. The major contamination problems defined by recent monitoring activities are carbon tetrachloride in the 200 West Area; cyanide in and north of the 200 East Area; hexavalent chromium contamination in the 100B, 100D, 100K, and 100H areas; chlorinated hydrocarbons in the vicinity of the Central Landfill; uranium at the 216-U-1 and 216-U-2 cribs in the 200 West Area; tritium across the site; and nitrate across the site. The distribution of hazardous materials related to site operations is more limited than the distribution of tritium and nitrate. 8 refs., 22 figs., 5 tabs.

  10. Freeing up Water 

    E-Print Network [OSTI]

    Wythe, Kathy

    2006-01-01

    Freeing up Water Story by Kathy Wythe Freeing up Water Brush control efforts yield water tx H2O | pg. 15 For 10 years during the 1990s drought, H. R.Wardlaw, a West Texas rancher, watchedand waited. He watched as the Middle Concho River and Rocky... and Water Conservation Board and designed to increase water yield by removing or controlling water-con- suming plants such as mesquite, cedar and saltcedar. In 2004, just as he finished excavating cedar, aerially spraying mesquite and hand spraying...

  11. Evaluation of the freeze-thaw/evaporation process for the treatment of produced waters. Final report, August 1992--August 1996

    SciTech Connect (OSTI)

    Boysen, J.E.; Walker, K.L.; Mefford, J.L.; Kirsch, J.R. [Resource Technology Corp., Laramie, WY (United States); Harju, J.A. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

    1996-06-01

    The use of freeze-crystallization is becoming increasingly acknowledged as a low-cost, energy-efficient method for purifying contaminated water. The natural freezing process can be coupled with natural evaporative processes to treat oil and gas produced waters year round in regions where subfreezing temperatures seasonally occur. The climates typical of Colorado`s San Juan Basin and eastern slope, as well as the oil and gas producing regions of Wyoming, are well suited for application of these processes in combination. Specifically, the objectives of this research are related to the development of a commercially-economic FTE (freeze-thaw/evaporation) process for the treatment and purification of water produced in conjunction with oil and natural gas. The research required for development of this process consists of three tasks: (1) a literature survey and process modeling and economic analysis; (2) laboratory-scale process evaluation; and (3) field demonstration of the process. Results of research conducted for the completion of these three tasks indicate that produced water treatment and disposal costs for commercial application of the process, would be in the range of $0.20 to $0.30/bbl in the Rocky Mountain region. FTE field demonstration results from northwestern New Mexico during the winter of 1995--96 indicate significant and simultaneous removal of salts, metals, and organics from produced water. Despite the unusually warm winter, process yields demonstrate disposal volume reductions on the order of 80% and confirm the potential for economic production of water suitable for various beneficial uses. The total dissolved solids concentrations of the FTE demonstration streams were 11,600 mg/L (feed), 56,900 mg/L (brine), and 940 mg/L (ice melt).

  12. CHEMISTRY OF SILICA IN CERRO PRIETO BRINES

    E-Print Network [OSTI]

    Weres, O.

    2012-01-01

    tank, add 20 to 30 ppm lime (CaO), stir for 5 ! Qinutes, andience. In practice, lime (calcium oxide or hydroxide) wouldadding a large amount of lime to them {up to 700 ppm CaO).

  13. Chemistry of Silica in Cerro Prieto Brines

    E-Print Network [OSTI]

    Weres, Oleh

    2012-01-01

    1975). When operated without sludge r e c i r c u l a t i ot o c o l l o i d a l silica. sludge accumulation there. thel a t i o n of part of the sludge coming out of The l a r g

  14. CHEMISTRY OF SILICA IN CERRO PRIETO BRINES

    E-Print Network [OSTI]

    Weres, O.

    2012-01-01

    lfuen operated w:l.thout sludge recirculation, this pilotcould lead to problems with sludge accumulation there. Ifby recirculation of part of the sludge coming out of the

  15. Chemistry of Silica in Cerro Prieto Brines

    E-Print Network [OSTI]

    Weres, O.

    2010-01-01

    1975). When operated without sludge r e c i r c u l a t i ot o c o l l o i d a l silica. sludge accumulation there. thel a t i o n of part of the sludge coming out of The l a r g

  16. Development Operations Hypersaline Geothermal Brine Utilization Imperial

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower VenturesInformation9)ask queries TypeDeveloper headerCounty,

  17. Batteries from Brine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12Power, Inc |Bartlesville Energy Research Centerof

  18. Water produced at the University of Iowa Water treatment plant

    E-Print Network [OSTI]

    Neiman, Maurine

    Water produced at the University of Iowa Water treatment plant meets or surpasses all federal and state drinking-water standards at this time. For information about the University of Iowa water supply, call us at 319-335-5168 Water Source The University of Iowa Water Plants' primary source of water

  19. Water Scarcity and Energy: Water and Power Efficiency of

    E-Print Network [OSTI]

    Scott, Christopher

    ) #12;Water Scarcity = Power Scarcity Lower water availability Lower hydro power availabilityWater Scarcity and Energy: Water and Power Efficiency of Recycled Water Arizona Hydrological and Population Growth · Types of Reuse · Water Efficiency of Reuse · Power Efficiency of Reuse #12;Water Scarcity

  20. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    SciTech Connect (OSTI)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung

    2003-09-24

    The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) Databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information. (2) A web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries. (3) A fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water. (4) A corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project was focused on creating the water quality databases for produced water and surface water, along with collecting of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 7000 entries for New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the accuracy and speed of water quality data entry. (4) Acquisition of ground water data from the New Mexico State Engineer's office, including chloride content and TDS (Total Dissolved Solids) for over 30,000 data points in southeast New Mexico. (5) Creation of a web-based scale prediction tool, again with a web-based interface, that uses two common scaling indices to predict the likelihood of scaling. This prediction tool can either run from user input data, or the user can select samples from the water analysis database. (6) Creation of depth-to-groundwater maps for the study area. (7) Analysis of water quality data by formation. (8) Continuation of efforts to collect produced water quality information from operators in the southeast New Mexico area. (9) Qualitative assessment of produced water from various formations regarding corrosivity. (10) Efforts at corrosion education in the region through operator visits. Future work on this project will include: (1) Development of an integrated web and GIS interface for all the information collected in this effort. (2) Continued development of a fuzzy logic spill risk assessment tool that was initially developed prior to this project. Improvements will include addition of parameters found to be significant in determining the impact of a brine spill at a specific site. (3) Compilation of both hard copy and online corrosion toolkit material.

  1. Walking on water

    E-Print Network [OSTI]

    Bush, John W. M.

    The ingenious methods employed by insects and spiders to move across a water surface rely on microphysics that is of little use to larger water walkers but of considerable interest to the microfluidics community.

  2. Federal Water Use Indices

    Broader source: Energy.gov [DOE]

    FEMP provides water use indices as a guide for Federal agencies. Note that each is a rough estimate of water usage at different types of sites. Your site may vary considerably.

  3. Water Tower - 14 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    Previous studies using tertiary amines to extract water from reagent-grade carboxylate salts (calcium acetate, propionate, and butyrate) have shown selectivity for water and not for the carboxylate salts. These results ...

  4. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Building Numerical Models () August of surface flow of water and infiltration which may include time to flow, movement of solids etc. () August

  5. A gathering of water

    E-Print Network [OSTI]

    Horowitz, Naomi Leah, 1970-

    2005-01-01

    The act of immersion is a powerful catalyst for the affirmation or transformation of identity. How we place ourselves in water expresses cultural valuations of our bodies, water, and social relations, as well as categories ...

  6. Water Conservation Tips

    E-Print Network [OSTI]

    Brown, Martha

    2008-01-01

    Water Needs breath. Adding compost to sandy soils helps thesoil retain water longer—the compost acts like a sponge,from applications of compost and other organic matter. For

  7. Water & Energy Conservation Plan

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    Poornima Group of Colleges, Jaipur, Rajasthan, India #12;Executive Summary This document for Poornima Group's conservation efforts over the next eight years. PGC currently maintains an unsustainable method of water use Environmental Crisis Poornima Group of Colleges Water

  8. What's In My Water

    E-Print Network [OSTI]

    Provin, Tony; Pitt, John L.

    2003-04-21

    You can learn about the quality of your water by sending a sample to a laboratory for analysis. This publication will help you understand the lab report by explaining the properties, components and contaminants often found in water. It describes...

  9. Drinking Water Problems: Benzene 

    E-Print Network [OSTI]

    Dozier, Monty; Lesikar, Bruce J.

    2009-04-16

    , chlorine, radon and some metals. A typical water softener will not remove benzene from water. Home granular activated carbon systems are usu- ally simple. The activated charcoal is packaged in filter cartridges that are inserted into a purification...

  10. Drinking Water Problems: MTBE 

    E-Print Network [OSTI]

    Dozier, Monty; Lesikar, Bruce J.

    2008-08-28

    organic compounds, pesticides and benzene, and can also re- move some metals, chlorine and radon. A typical water softener will not remove MTBE from water. Home granular activated carbon filtering systems are usually simple. The activated charcoal...

  11. Drinking Water Problems: Arsenic 

    E-Print Network [OSTI]

    Lesikar, Bruce J.; Melton, Rebecca; Hare, Michael; Hopkins, Janie; Dozier, Monty

    2005-12-02

    High levels of arsenic in drinking water can poison and even kill people. This publication explains the symptoms of arsenic poisoning and common treatment methods for removing arsenic from your water supply....

  12. Indian Water 2015

    Office of Energy Efficiency and Renewable Energy (EERE)

    Indian Water is a call to help plan a national water summit. This strategic session consist of a facilitated dialog with tribal leaders on important opportunities, challenges and tactics, which...

  13. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    Hydroelectricity for agriculture and hydroelectricity. Large volumes of waterElectricity Production Hydroelectricity The most common type

  14. Water in the West

    E-Print Network [OSTI]

    Fahlund, Andrew; Choy, Min L. Janny; Szeptycki, Leon

    2014-01-01

    hydraulic fracturing (or fracking) fluids, and limited waterEngelder, “Natural gas: Should fracking stop? ” Nature 477 (

  15. Technology in water conservation 

    E-Print Network [OSTI]

    Finch, Dr. Calvin

    2013-01-01

    ?? percent to ?? percent. Water reuse systems treat wastewater by various technologies including ?ltering, bioremediation and ozone exposure. ?ese technologies can involve billions of gallons of wastewater ? such as in a municipal recycling e... Column by Dr. Calvin Finch, Water Conservation and Technology Center director WAT E R CONSERVATION & TECHNOLOGY CENTER Securing Our Water Future It is not unusual for individuals to describe water conservation as a behavioral exercise and urge...

  16. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    into a water source—thermal pollution—has also led to theimpacts from this thermal pollution, including the

  17. Plugging Abandoned Water Wells 

    E-Print Network [OSTI]

    Lesikar, Bruce J.

    2002-02-28

    is abandoned without proper plugging, upward flow of salty water from the deeper aquifer may cause contamination of the shallow, fresh water aquifer. Also, any pollu- tants that occur in one zone can migrate to another zone through a well. Unplugged abandoned... wells may deplete pres- sure within an aquifer. Pressure in artesian aquifers decreases as water discharges at land surface or to less pressurized aquifers. Eventually a drop in pres- sure causes flowing wells to stop flowing and the water level...

  18. Water Transport Within the STack: Water Transport Exploratory...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Within the STack: Water Transport Exploratory Studies Water Transport Within the STack: Water Transport Exploratory Studies Part of a 100 million fuel cell award announced by DOE...

  19. Integrated regional water management: Collaboration or water politics as usual?

    E-Print Network [OSTI]

    Lubell, Mark N.; Lippert, Lucas

    2010-01-01

    patterns, and implications." Water Policy 2 (3):175-99.A. K. 2004. "Integrated water resources management: areassessment." Water International 29 (2):248-56. Blomquist,

  20. Review: Water, Peace, and War: Confronting the Global Water Crisis

    E-Print Network [OSTI]

    Tans, Eric

    2014-01-01

    Review: Water, War, and Peace:Confronting the Global Water Crisis By Brahma ChellaneyUSA Chellaney, Brahma. Water, Peace, and War: Confronting

  1. STORM WATER Residential

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    STORM WATER QUALITY HOTLINE UCSC Residential Car Washing http THAT MAY CAUSE ENVIRONMENTAL HARM TO THE STORM WATER QUALITY HOTLINE: (831) 459-2553. LIKE US ON FACEBOOK AT UCSC STORM WATER MANAGEMENT PROGRAM! DID YOU KNOW? PRACTICAL SOLUTIONS > USE A COMMERCIAL CAR WASH

  2. Water treatment method

    DOE Patents [OSTI]

    Martin, F.S.; Silver, G.L.

    1991-04-30

    A method is described for reducing the concentration of any undesirable metals dissolved in contaminated water, such as waste water. The method involves uniformly reacting the contaminated water with an excess amount of solid particulate calcium sulfite to insolubilize the undesirable metal ions, followed by removal thereof and of the unreacted calcium sulfite.

  3. California's Water Energy Relationship

    E-Print Network [OSTI]

    1 CALIFORNIA ENERGY COMMISSION California's Water ­ Energy Relationship Prepared in Support The California's Water-Energy Relationship report is the product of contributions by many California Energy, Lorraine White and Zhiqin Zhang. Staff would also like to thank the members of the Water-Energy Working

  4. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 6: Mathematics, z). velocity vx (x, y, z, t) : in the x-direction. vx = Kx h/x saturated/water- table. Continuity Equation What is vx x + vy y + vz z ? It is the rate of accumulation of water at the point (x, y

  5. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 1: A Perspective () July 20, 2012 1 / 17 #12;Outline Two parts: The technical side to water. -M. Sohoni The basic hydrological cycle. The societal side to water. -N. C. Narayanan () July 20, 2012 2 / 17 #12;Texts Applied Hydrogeology, by C. W

  6. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 4: Groundwater () December in dried sample. Saturation: When these voids are fully filled with water. Specific Yield Sy : the ration of the colume of water that drains from a rock owing to gravity, to the total rock volumne. 00000000

  7. WATER ADVISORY PARTNERSHIP

    E-Print Network [OSTI]

    US Army Corps of Engineers

    COCONINO PLATEAU WATER ADVISORY COUNCIL& WATERSHED PARTNERSHIP 3624 E. Mesquite St. Gilbe~t, Arizona 85296" 1832 Participants: Arizona Department of Environmental Quality Arizona Department of Water City ofFlagstaff City of Page City of Sedona City of Williams Coconino County Doney Park Water Company

  8. Water Resources Research Center

    E-Print Network [OSTI]

    District of Columbia, University of the

    Water Resources Research Center WASHINGTON, DISTRICT Of COLUMBIA #12;ASSESSMENT OF THE STATE OF THE ART AND DEVELOPMENT OF PROPOSED IMPROVEMENTS IN RECREATION BENEFIT, VALUATION FOR WATER RESOURCES PLANNING conducted by Robert C. Waters Vassilios Moustakis Department of Engineering Administration School

  9. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 10: Minor Structures for Ground and Surface Water () March 23, 2010 1 / 31 #12;Classification by Purpose We may classify the velocity of water-flow (ii) increasing the infiltration coefficient (iii) explicit groundwater recharge

  10. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Analysis Framework for the 2009 / 16 #12;Vol II and Vol III Vol. II 1 Annexure I, Chap. 1: Bulk-water and tariffs-Principles. 2 Annexure I, Chap. 2: International Case Studies. 3 Annexure II: Report on water conservation technologies

  11. Saving Water Saves Energy

    SciTech Connect (OSTI)

    McMahon, James E.; Whitehead, Camilla Dunham; Biermayer, Peter

    2006-06-15

    Hot water use in households, for showers and baths as wellas for washing clothes and dishes, is a major driver of household energyconsumption. Other household uses of water (such as irrigatinglandscaping) require additional energy in other sectors to transport andtreat the water before use, and to treat wastewater. In California, 19percent of total electricity for all sectors combined and 32 percent ofnatural gas consumption is related to water. There is a criticalinterdependence between energy and water systems: thermal power plantsrequire cooling water, and water pumping and treatment require energy.Energy efficiency can be increased by a number of means, includingmore-efficient appliances (e.g., clothes washers or dishwashers that useless total water and less heated water), water-conserving plumbingfixtures and fittings (e.g., showerheads, faucets, toilets) and changesin consumer behavior (e.g., lower temperature set points for storagewater heaters, shorter showers). Water- and energy-conserving activitiescan help offset the stress imposed on limited water (and energy) suppliesfrom increasing population in some areas, particularly in drought years,or increased consumption (e.g., some new shower systems) as a result ofincreased wealth. This paper explores the connections between householdwater use and energy, and suggests options for increased efficiencies inboth individual technologies and systems. Studies indicate that urbanwater use can be reduced cost-effectively by up to 30 percent withcommercially available products. The energy savings associated with watersavings may represent a large additional and largely untappedcost-effective opportunity.

  12. Addressing Water Contamination

    E-Print Network [OSTI]

    Loewith, Robbie

    Addressing Water Contamination without Using Chemicals For more information contact WIPO at: World challenge Farmers and gardeners apply pesticides to their crops. Contaminated waters are released when-off contaminates local water supplies and pollutes the environment. As a consequence a range of pesticides may

  13. Water treatment method

    DOE Patents [OSTI]

    Martin, Frank S. (Farmersville, OH); Silver, Gary L. (Centerville, OH)

    1991-04-30

    A method for reducing the concentration of any undesirable metals dissolved in contaminated water, such as waste water. The method involves uniformly reacting the contaminated water with an excess amount of solid particulate calcium sulfite to insolubilize the undesirable metal ions, followed by removal thereof and of the unreacted calcium sulfite.

  14. Regional water planning Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    LOCATE: - Villages - Peri-urban area - Farmland - Roads - Stream - Small dam (KT bandhara) - Waste water for irrigation Percolation Fresh water supply Domestic and industrial use Waste water treatment Waste water Discharge waste water recycle Treat and discharge untreated Run-off #12;Urban water cycle DRINKING WATER

  15. What's your water footprint? 

    E-Print Network [OSTI]

    Jordan, Leslie

    2009-01-01

    stream_source_info What's your water footprint.pdf.txt stream_content_type text/plain stream_size 6622 Content-Encoding ISO-8859-1 stream_name What's your water footprint.pdf.txt Content-Type text/plain; charset=ISO-8859...-1 tx H2O | pg. 21 What?s your water footprint? When it comes to your water use, do you tread lightly or are you an H2O Sasquatch? How much water do you think you consume every day? You might initially consider the length of your daily shower...

  16. Summary Report on CO{sub 2} Geologic Sequestration & Water Resources Workshop

    SciTech Connect (OSTI)

    Varadharajan, C.; Birkholzer, J.; Kraemer, S.; Porse, S.; Carroll, S.; Wilkin, R.; Maxwell, R.; Bachu, S.; Havorka, S.; Daley, T.; Digiulio, D.; Carey, W.; Strasizar, B.; Huerta, N.; Gasda, S.; Crow, W.

    2012-02-15

    The United States Environmental Protection Agency (EPA) and Lawrence Berkeley National Laboratory (LBNL) jointly hosted a workshop on “CO{sub 2} Geologic Sequestration and Water Resources” in Berkeley, June 1–2, 2011. The focus of the workshop was to evaluate R&D needs related to geological storage of CO{sub 2} and potential impacts on water resources. The objectives were to assess the current status of R&D, to identify key knowledge gaps, and to define specific research areas with relevance to EPA’s mission. About 70 experts from EPA, the DOE National Laboratories, industry, and academia came to Berkeley for two days of intensive discussions. Participants were split into four breakout session groups organized around the following themes: Water Quality and Impact Assessment/Risk Prediction; Modeling and Mapping of Area of Potential Impact; Monitoring and Mitigation; Wells as Leakage Pathways. In each breakout group, participants identified and addressed several key science issues. All groups developed lists of specific research needs; some groups prioritized them, others developed short-term vs. long-term recommendations for research directions. Several crosscutting issues came up. Most participants agreed that the risk of CO{sub 2} leakage from sequestration sites that are properly selected and monitored is expected to be low. However, it also became clear that more work needs to be done to be able to predict and detect potential environmental impacts of CO{sub 2} storage in cases where the storage formation may not provide for perfect containment and leakage of CO{sub 2}–brine might occur.

  17. Gas Water Heater Energy Losses

    E-Print Network [OSTI]

    Biermayer, Peter

    2012-01-01

    including delivered hot water and energy losses. Waterand 17% if hot water energy is included. INTRODUCTION Thedrawn, determines the hot water energy output. The current

  18. Planning Water Use in California

    E-Print Network [OSTI]

    Eisenstein, William; Kondolf, G. Mathias

    2008-01-01

    the University of Maryland Water Policy Collaborative, 2006.FURTH ER READ ING California Department of Water Resources.California Water Plan Update 2005: A Framework for Action.

  19. Super recycled water: quenching computers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Super recycled water: quenching computers Super recycled water: quenching computers New facility and methods support conserving water and creating recycled products. Using reverse...

  20. Groundwater and Terrestrial Water Storage, 

    E-Print Network [OSTI]

    Rodell, M; Chambers, D P; Famiglietti, J S

    2011-01-01

    2003: Tracking fresh water from space. Science, 301, 1485–2007: Mea- suring surface water from space. Rev. Geophys. ,2011:, Stratospheric water vapor trends over Boulder, Colo-

  1. Mitigation, Adaptation, Uncertainty -- Growing Water

    E-Print Network [OSTI]

    Felsen, Martin; Dunn, Sarah

    2008-01-01

    Growing Water Martin Felsen andSarah Dunn The Growing Water project addresses a report fromin the world will face water shortages by 2025, a situation

  2. Toxoplasma gondii Oocysts in Water

    E-Print Network [OSTI]

    Wainwright, Katlyn E.

    2008-01-01

    M. Pavlo. 2005. Do iodine water purification tablets provideof Toxoplasma gondii in water from wells located on farms.Toxoplasma gondii oocysts in water. App. Environ. Micro. 73,

  3. Water chemistry-based classification of streams and implications for restoring mined Appalachian watersheds

    SciTech Connect (OSTI)

    Merovich, G.T.; Stiles, J.M.; Petty, J.T.; Ziemkiewicz, P.F.; Fulton, J.B. [West Virginia University, Morgantown, WV (United States)

    2007-07-15

    We analyzed seasonal water samples from the Cheat and Tygart Valley river basins, West Virginia, USA, in an attempt to classify streams based on water chemistry in this coal-mining region. We also examined temporal variability among water samples. Principal component analysis identified two important dimensions of variation in water chemistry. This variation was determined largely by mining-related factors (elevated metals, sulfates, and conductivity) and an alkalinity-hardness gradient. Cluster analysis grouped water samples into six types that we described as reference, soft, hard, transitional, moderate acid mine drainage, and severe acid mine drainage. These types were statistically distinguishable in multidimensional space. Classification tree analysis confirmed that chemical constituents related to acid mine drainage and acid rain distinguished these six groups. Hard, soft, and severe acid mine drainage type streams were temporally constant compared to streams identified as reference, transitional, and moderate acid mine drainage type, which had a greater tendency to shift to a different water type between seasons. Our research is the first to establish a statistically supported stream classification system in mined watersheds. The results suggest that human-related stressors superimposed on geology are responsible for producing distinct water quality types in this region as opposed to more continuous variation in chemistry that would be expected in an unimpacted setting. These findings provide a basis for simplifying stream monitoring efforts, developing generalized remediation strategies, and identifying specific remediation priorities in mined Appalachian watersheds.

  4. Experimental study of crossover from capillary to viscous fingering for supercritical CO2 - water displacement in a homogeneous pore network

    SciTech Connect (OSTI)

    Wang, Ying; Zhang, Changyong; Wei, Ning; Oostrom, Martinus; Wietsma, Thomas W.; Li, Xiaochun; Bonneville, Alain

    2013-01-01

    Carbon sequestration in saline aquifers involves displacing resident brine from the pore space by supercritical CO2 (scCO2). The displacement process is considered unstable due to the unfavorable viscosity ratio (logM < 0). The unstable mechanisms that affect scCO2 - water displacement under reservoir conditions (i.e., 41 °C, 9 MPa) were investigated in a homogeneous micromodel. A wide range of injection rates (logCa = -7.61~-4.73) was studied in two sets of experiments: discontinuous-rate injection, where the micromodel was first cleaned and saturated with water before each injection rate was imposed, and continuous-rate injection, where the rate was increased after quasi-steady conditions were reached for a certain rate. For the discontinuous-rate experiments, capillary fingering and viscous fingering are the dominant mechanisms for low (logCa <= -6.61) and high injection rates (logCa >= -5.21), respectively. Crossover from capillary to viscous fingering was observed for logCa = -5.91~-5.21, resulting in a large decrease in scCO2 saturation. The discontinuous-rate experimental results confirmed the decrease in nonwetting fluid saturation during crossover from capillary to viscous fingering predicted by numerical simulations by Lenormand et al. (1988).1 Capillary fingering was the only mechanism that dominates all injection rates in the continuous-rate experiment, and resulted in monotonic increase in scCO2 saturation.

  5. Geothermal Water Use: Life Cycle Water Consumption, Water Resource Assessment, and Water Policy Framework

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Schroeder, Jenna N.

    2014-06-10

    This report examines life cycle water consumption for various geothermal technologies to better understand factors that affect water consumption across the life cycle (e.g., power plant cooling, belowground fluid losses) and to assess the potential water challenges that future geothermal power generation projects may face. Previous reports in this series quantified the life cycle freshwater requirements of geothermal power-generating systems, explored operational and environmental concerns related to the geochemical composition of geothermal fluids, and assessed future water demand by geothermal power plants according to growth projections for the industry. This report seeks to extend those analyses by including EGS flash, both as part of the life cycle analysis and water resource assessment. A regional water resource assessment based upon the life cycle results is also presented. Finally, the legal framework of water with respect to geothermal resources in the states with active geothermal development is also analyzed.

  6. Geothermal Water Use: Life Cycle Water Consumption, Water Resource Assessment, and Water Policy Framework

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Schroeder, Jenna N.

    This report examines life cycle water consumption for various geothermal technologies to better understand factors that affect water consumption across the life cycle (e.g., power plant cooling, belowground fluid losses) and to assess the potential water challenges that future geothermal power generation projects may face. Previous reports in this series quantified the life cycle freshwater requirements of geothermal power-generating systems, explored operational and environmental concerns related to the geochemical composition of geothermal fluids, and assessed future water demand by geothermal power plants according to growth projections for the industry. This report seeks to extend those analyses by including EGS flash, both as part of the life cycle analysis and water resource assessment. A regional water resource assessment based upon the life cycle results is also presented. Finally, the legal framework of water with respect to geothermal resources in the states with active geothermal development is also analyzed.

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    fuel cycle and fuel materials (2) radioactive wastes (2) sensitivity (2) simulation (2) water (2) arsenic (1) bentonite (1) boom clay (1) brine leakage (1) brines (1) buffers (1)...

  8. Continuous Commissioning of a Central Chilled Water & Hot Water System 

    E-Print Network [OSTI]

    Deng, S.; Turner, W. D.; Batten, T.; Liu, M.

    2000-01-01

    A central chilled water / hot water system provides cooling / heating energy from central utility plants to multiple customers (buildings) through campus distribution loops. To effectively transport the chilled water and hot water to the buildings...

  9. Herbarium (NCSC), Department of Plant and Microbial Biology, North Carolina State University, http://herbarium.ncsu.edu North Carolina State University is a land-grant university and a constituent institution of the University of North Carolina

    E-Print Network [OSTI]

    Krings, Alexander

    Herbarium (NCSC), Department of Plant and Microbial Biology, North Carolina State University, http://herbarium.ncsu.edu North Carolina State University is a land-grant university and a constituent institution of the University of North Carolina PLANT IDENTIFICATION REQUEST FROM: Agent

  10. Herbarium (NCSC), Department of Plant and Microbial Biology, North Carolina State University, http://herbarium.ncsu.edu North Carolina State University is a land-grant university and a constituent institution of the University of North Carolina

    E-Print Network [OSTI]

    Krings, Alexander

    Herbarium (NCSC), Department of Plant and Microbial Biology, North Carolina State University, http://herbarium.ncsu.edu North Carolina State University is a land-grant university and a constituent institution of the University of North Carolina PLANT IDENTIFICATION REQUEST FROM: Name

  11. (Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite,

    E-Print Network [OSTI]

    /31/98 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth

  12. (Data in metric tons of yttrium oxide (Y2O3) content, unless noted) Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the

    E-Print Network [OSTI]

    ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth

  13. (Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the

    E-Print Network [OSTI]

    /31/96 Thorium ores and concentrates (monazite) 2612.20.0000 Free Free. Rare-earth metals, scandium and yttrium Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth

  14. (Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite,

    E-Print Network [OSTI]

    and concentrates (monazite) 2612.20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed Production and Use: The rare-earth element yttrium was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined

  15. (Data in metric tons of yttrium oxide (Y O ) content, unless otherwise noted)2 3 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the

    E-Print Network [OSTI]

    .20.0000 Free Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805 Domestic Production and Use: The rare-earth element, yttrium, was mined by one company as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth

  16. (Data in metric tons of yttrium oxide (Y2O3) content, unless otherwise noted) Domestic Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral

    E-Print Network [OSTI]

    .20.0000 Free. Rare-earth metals, scandium and yttrium, whether or not intermixed or interalloyed 2805.30.0000 5 Production and Use: The rare-earth element, yttrium, was mined as a constituent of the mineral bastnasite, but was not recovered as a separate element during processing. Bastnasite, a rare-earth fluocarbonate mineral, was mined

  17. Long Term Field Development of a Surfactant Modified Zeolite/Vapor Phase Bioreactor System for Treatment of Produced Waters for Power Generation

    SciTech Connect (OSTI)

    Lynn Katz; Kerry Kinney; Robert Bowman; Enid Sullivan; Soondong Kwon; Elaine Darby; Li-Jung Chen; Craig Altare

    2007-12-31

    The main goal of this research was to investigate the feasibility of using a combined physicochemical/biological treatment system to remove the organic constituents present in saline produced water. In order to meet this objective, a physical/chemical adsorption process was developed and two separate biological treatment techniques were investigated. Two previous research projects focused on the development of the surfactant modified zeolite adsorption process (DE-AC26-99BC15221) and development of a vapor phase biofilter (VPB) to treat the regeneration off-gas from the surfactant modified zeolite (SMZ) adsorption system (DE-FC26-02NT15461). In this research, the SMZ/VPB was modified to more effectively attenuate peak loads and to maintain stable biodegradation of the BTEX constituents from the produced water. Specifically, a load equalization system was incorporated into the regeneration flow stream. In addition, a membrane bioreactor (MBR) system was tested for its ability to simultaneously remove the aromatic hydrocarbon and carboxylate components from produced water. The specific objectives related to these efforts included the following: (1) Optimize the performance VPBs treating the transient loading expected during SMZ regeneration: (a) Evaluate the impact of biofilter operating parameters on process performance under stable operating conditions. (b) Investigate how transient loads affect biofilter performance, and identify an appropriate technology to improve biological treatment performance during the transient regeneration period of an SMZ adsorption system. (c) Examine the merits of a load equalization technology to attenuate peak VOC loads prior to a VPB system. (d) Evaluate the capability of an SMZ/VPB to remove BTEX from produced water in a field trial. (2) Investigate the feasibility of MBR treatment of produced water: (a) Evaluate the biodegradation of carboxylates and BTEX constituents from synthetic produced water in a laboratory-scale MBR. (b) Evaluate the capability of an SMZ/MBR system to remove carboxylates and BTEX from produced water in a field trial. Laboratory experiments were conducted to provide a better understanding of each component of the SMZ/VPB and SMZ/MBR process. Laboratory VPB studies were designed to address the issue of influent variability and periodic operation (see DE-FC26-02NT15461). These experiments examined multiple influent loading cycles and variable concentration loadings that simulate air sparging as the regeneration option for the SMZ system. Two pilot studies were conducted at a produced water processing facility near Farmington, New Mexico. The first field test evaluated SMZ adsorption, SMZ regeneration, VPB buffering, and VPB performance, and the second test focused on MBR and SMZ/MBR operation. The design of the field studies were based on the results from the previous field tests and laboratory studies. Both of the biological treatment systems were capable of removing the BTEX constituents in the laboratory and in the field over a range of operating conditions. For the VPB, separation of the BTEX constituents from the saline aqueous phase yielded high removal efficiencies. However, carboxylates remained in the aqueous phase and were not removed in the combined VPB/SMZ system. In contrast, the MBR was capable of directly treating the saline produced water and simultaneously removing the BTEX and carboxylate constituents. The major limitation of the MBR system is the potential for membrane fouling, particularly when the system is treating produced water under field conditions. The combined process was able to effectively pretreat water for reverse osmosis treatment and subsequent downstream reuse options including utilization in power generation facilities. The specific conclusions that can be drawn from this study are summarized.

  18. Water Data Report: An Annotated Bibliography

    E-Print Network [OSTI]

    Dunham Whitehead, Camilla; Melody, Moya

    2007-01-01

    Table 5: Public supply water withdrawals, 2000. water withdrawals, 2000. water withdrawals, 2000.

  19. West Basin Municipal Water District, California; Water/Sewer

    E-Print Network [OSTI]

    US Army Corps of Engineers

    Exhibit D #12;Summary: West Basin Municipal Water District, California; Water/Sewer Primary Credi90023!! #12;Sttmma1·y: West Basin Municipal Water District, California; Water/Sewer Credit Profile US$16.STANDARDANDPOORS.COM/RATJNGSDJRECT MAY31 2013 2 I126639 I 301008236 #12;Summary: West Basin Municipal Water District, California; Water/Sewer

  20. SA Water Centre for Water Management and Reuse

    E-Print Network [OSTI]

    Li, Jiuyong "John"

    SA Water Centre for Water Management and Reuse #12;2 The SA Water Centre for Water Management and Reuse was established in 2004 as a joint venture between the South Australian Water Corporation and the University of South Australia (UniSA), adding significant expertise to the water research capability in South

  1. SA Water Centre for Water Management and Reuse

    E-Print Network [OSTI]

    Li, Jiuyong "John"

    SA Water Centre for Water Management and Reuse #12;' Our Mission The SA Water Centre for Water Management and Reuse aims to advance the science and technology of sustainable water management through fundamental and applied research. Our Vision To be Australia's leading research centre for water reuse

  2. WATER RESOURCES PLANNING ACT Q:\\COMP\\WATER1\\WRPA

    E-Print Network [OSTI]

    US Army Corps of Engineers

    103 WATER RESOURCES PLANNING ACT Q:\\COMP\\WATER1\\WRPA December 29, 2000 #12;Q:\\COMP\\WATER1\\WRPA December 29, 2000 #12;105 WATER RESOURCES PLANNING ACT [As Amended Through P.L. 106­580, Dec. 29, 2000 planning of water and related land resources, through the establishment of a water resources council

  3. Water Management at UBC Okanagan Part 2: Water Features

    E-Print Network [OSTI]

    Water Management at UBC Okanagan Part 2: Water Features UBC Okanagan 2007 Angele Clarke A SEEDS and Objectives 2 Methods 3 The Symbolic and Cultural Values of Water 3 Landscape Aesthetics Relationship to Water 5 UBC-Okanagan Campus Landscape and Water Features 8 Water Features and the Built Environment Campus

  4. IWA Balkan Young Water Professionals

    E-Print Network [OSTI]

    Psarrakos, Panayiotis

    Networks Industrial Waste Treatment and Disposal River Basins Management Legislation in the Water those associated with cross-border water management issues, which require experience exchange among 2015 - Thessaloniki, Greece Topics Water Management (Water Loss ­ Mitigation Methods and Technologies

  5. UC Sustainable Water Systems Policy

    E-Print Network [OSTI]

    Gleeson, Joseph G.

    , or lubricating equipment. Purified Water: Water that is free of impurities such as microorganisms, particulate consumption because it contains objectionable pollution, contamination minerals or infective agents, including water quality standards for human consumption. Reclaimed or Recycled Water: Wastewater treated

  6. Water Heating | Department of Energy

    Energy Savers [EERE]

    Water Heating Water Heating September 2, 2015 - 11:07am Addthis Low-flow fixtures will help you reduce your hot water use and save money on your water heating bills. | Photo...

  7. Cholesterol enhances surface water diffusion of phospholipid bilayers

    SciTech Connect (OSTI)

    Cheng, Chi-Yuan; Kausik, Ravinath; Han, Songi, E-mail: songi@chem.ucsb.edu [Department of Chemistry and Biochemistry and Materials Research Laboratory, University of California, Santa Barbara, California 93106 (United States); Olijve, Luuk L. C. [Laboratory of Macromolecular and Organic Chemistry and Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven (Netherlands)

    2014-12-14

    Elucidating the physical effect of cholesterol (Chol) on biological membranes is necessary towards rationalizing their structural and functional role in cell membranes. One of the debated questions is the role of hydration water in Chol-embedding lipid membranes, for which only little direct experimental data are available. Here, we study the hydration dynamics in a series of Chol-rich and depleted bilayer systems using an approach termed {sup 1}H Overhauser dynamic nuclear polarization (ODNP) NMR relaxometry that enables the sensitive and selective determination of water diffusion within 5–10 Å of a nitroxide-based spin label, positioned off the surface of the polar headgroups or within the nonpolar core of lipid membranes. The Chol-rich membrane systems were prepared from mixtures of Chol, dipalmitoyl phosphatidylcholine and/or dioctadecyl phosphatidylcholine lipid that are known to form liquid-ordered, raft-like, domains. Our data reveal that the translational diffusion of local water on the surface and within the hydrocarbon volume of the bilayer is significantly altered, but in opposite directions: accelerated on the membrane surface and dramatically slowed in the bilayer interior with increasing Chol content. Electron paramagnetic resonance (EPR) lineshape analysis shows looser packing of lipid headgroups and concurrently tighter packing in the bilayer core with increasing Chol content, with the effects peaking at lipid compositions reported to form lipid rafts. The complementary capability of ODNP and EPR to site-specifically probe the hydration dynamics and lipid ordering in lipid membrane systems extends the current understanding of how Chol may regulate biological processes. One possible role of Chol is the facilitation of interactions between biological constituents and the lipid membrane through the weakening or disruption of strong hydrogen-bond networks of the surface hydration layers that otherwise exert stronger repulsive forces, as reflected in faster surface water diffusivity. Another is the concurrent tightening of lipid packing that reduces passive, possibly unwanted, diffusion of ions and water across the bilayer.

  8. Mitigation, Adaptation, Uncertainty -- Growing Water

    E-Print Network [OSTI]

    Felsen, Martin; Dunn, Sarah

    2008-01-01

    system for harvesting and returning clean water to Lakeharvesting for landscape and species health, and surface water and

  9. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Chaplin, Martin

    2007-01-01

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperature...

  10. Arsenic removal from water

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM); Anderson, D. Richard (Albuquerque, NM)

    2007-07-24

    Methods for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical methods for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A method for continuous removal of arsenic from water is provided. Also provided is a method for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

  11. WATER QUALITY MODELING OF THE

    E-Print Network [OSTI]

    Keller, Arturo A.

    WATER QUALITY MODELING OF THE STATE OF OHIO COMPONENT OF THE OHIO RIVER BASIN WATER QUALITY TRADING PROGRAM #12;Water Quality Modeling of the State of Ohio Component of the Ohio River Basin Water Quality Trading Program #12;2 Water Quality Modeling of the State of Ohio Component of the Ohio River Basin Water

  12. Selecting a new water heater

    SciTech Connect (OSTI)

    1995-03-01

    This fact sheet describes the types of water heaters available (storage water heaters, demand water heaters, heat pump water heaters, tankless coil and indirect water heaters, and solar water heaters). The criteria for selection are discussed. These are capacity, efficiency rating, and cost. A resource list is provided for further information.

  13. Preliminary conceptual design for the destruction of organic/ferrocyanide constituents in the Hanford tank waste with low-temperature hydrothermal processing

    SciTech Connect (OSTI)

    Schmidt, A.J.; Jones, E.O.; Orth, R.J.; Cox, J.L.; Elmore, M.E.; Neuenschwander, G.G.; Hart, T.R. [Pacific Northwest Lab., Richland, WA (United States); Meng, C.D. [Westinghouse Hanford Co., Richland, WA (United States)

    1993-05-01

    Hydrothermal processing (HTP) is a thermal-chemical processing method that can be employed to destroy organic and ferrocyanide constituents in Hanford tank waste by using the abundant existing oxidants in the tank waste such as nitrite and nitrate. Use-temperature HTP effectively destroys organics at temperatures from 250{degree}C to 400{degree}C to eliminate safety hazards and improve further processing. This proposal describes a conceptual design of a low-temperature HTP system (including a preliminary flow diagram and plot plan, equipment descriptions and sizes, utility requirements, and costs); the experimental work supporting this effort at Pacific Northwest Laboratory (PNL); the reaction chemistry and kinetics; the technical maturity of the process; and a preliminary assessment of maintenance, operation, and safety of a system. Nitrate destruction using organic reductants is also described. The low-temperature hydrothermal program at PNL was initiated in January 1993. It is part of an overall program to develop organic destruction technologies, which was originally funded by Hanford`s Tank Waste Remediation System program and then was transferred to the Initial Pretreatment (IPM) project. As described in the document, low-temperature HTP (1) meets or exceeds system requirements in organic, ferrocyanide, and nitrate destruction, and processing rate; (2) is technically mature with little additional technology development required; (3) is a simple process with good operational reliability; (4) is flexible and can be easily integrated in the system; (5) has reasonable costs and utility requirements; and (6) is safe and environmentally-benign.

  14. Water Resources Milind Sohoni

    E-Print Network [OSTI]

    Sohoni, Milind

    TD 603 Water Resources Milind Sohoni www.cse.iitb.ac.in/sohoni/ Lecture 3: Watershed and Maps () July 23, 2013 1 / 18 #12;Domain Decomposition p1 p2 p3 p5 p4 surface water A1 A2 A3 A4 A5 salinity ingress water table q W(q) W(p2) The watershed W (x) of a point x is W (x) = {all points y from where

  15. The Mystery of Water

    SciTech Connect (OSTI)

    Nilsson, Anders

    2005-11-21

    Water is essential for our existence on this planet - critical to countless physical, biological, geological and chemical processes - it has defied scientific understanding. Exhibiting peculiar properties such as increased density upon melting and high surface tension, water is one of the most intriguing problems in condensed matter and chemical physics. Current research at SSRL, however, is illuminating the nature of H-bonding, presenting exciting new avenues of research and challenging existing models of water's structure.

  16. Surface Water Quality Standards 

    E-Print Network [OSTI]

    Wythe, Kathy

    2007-01-01

    Standards Team. This advisory group, with representation from water asso- ciations, the agricultural industry, engineering firms, environmental organizations, consumer groups and government entities, is working with TCEQ staff to review and possibly...SURFACE WATER QUALITY STANDARDS AAs part of the ongoing program to manage Texaswater quality, the Texas Commission onEnvironmental Quality (TCEQ) is currently review- ing the Texas Surface Water Quality Standards, including the standards...

  17. Effects of buoyancy source composition on multiphase plume behavior in stratification

    E-Print Network [OSTI]

    Chow, Aaron C. (Aaron Chunghin), 1978-

    2004-01-01

    Experiments are performed where a dense multiphase plume is released vertically in a salinity stratified ambient. The constituent phase composition of the initial buoyancy flux can be dense brine, particles, or a mixture ...

  18. Cooling water distribution system

    DOE Patents [OSTI]

    Orr, Richard (Pittsburgh, PA)

    1994-01-01

    A passive containment cooling system for a nuclear reactor containment vessel. Disclosed is a cooling water distribution system for introducing cooling water by gravity uniformly over the outer surface of a steel containment vessel using an interconnected series of radial guide elements, a plurality of circumferential collector elements and collector boxes to collect and feed the cooling water into distribution channels extending along the curved surface of the steel containment vessel. The cooling water is uniformly distributed over the curved surface by a plurality of weirs in the distribution channels.

  19. Sandia Energy - Water Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, a backward--bent duct buoy (BBDB) oscillating water column wave energy converter design. The team from HMRC included Tom Walsh, Brian Holmes, Florent Thiebaut, Neil...

  20. Sandia Energy - Water Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News & Events, Partnership, Renewable Energy, Systems Analysis, Systems Engineering, Water Power WEC-Sim Code Development Meeting at the National Renewable Energy Laboratory...

  1. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    Nuclear plants use steam turbines, and cooling water asmajority is used for steam-driven turbines, which generatedelectricity using steam engines, gas turbines, or Stirling

  2. Alkali Soils, Irrigation Waters

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1910-01-01

    ............................................................................ Chloride of soda.. 101 This is an escellcnt water. WATER OF COLORADO RIVER, NEAB SEARON, TEXAS. TPater soluble solids, 1.245 parts per million. MISCELLANEOUS WATERS. The follomirlg ai~alyses give the amount of alkaline salts pre IRIETGITTON WATERS.- S....4LTS IN PARTS PER MILLION . Alkaline Alkaline Alkaline Carbonate Sulphate Chloride I I i 1. 895 ' 1. 558 180 21 112 302 ' 1. 964 703 775 6. 237 F . 934 . 2. 909 635 2. 124 1. 785 951 523 150 1. 788 1. 947 4. 031 1. 698 201...

  3. Cooperating for Cleaner Water 

    E-Print Network [OSTI]

    Wythe, Kathy

    2006-01-01

    . This TMDL plan will budget how much bacteria pollution from point sources (like wastewater treatment facilities) and nonpoint sources (runoff from land) can occur in a single day and still maintain water quality standards. Kerry Niemann, TCEQ project... of water on its 303(d) list (a list of water segments that do not meet water quality standards) and to develop a TMDL for each pollutant that impairs any segment, according to TCEQ docu- ments. TCEQ has adopted 63 TMDLs with EPA approving 60 of those...

  4. Residential Absorption Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Residential Absorption Water Heater 2014 Building Technologies Office Peer Review Kyle Gluesenkamp, gluesenkampk@ornl.gov Oak Ridge National Laboratory Project Summary Timeline:...

  5. Forecasting Water Quality & Biodiversity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Forecasting Water Quality & Biodiversity March 25, 2015 Cross-cutting Sustainability Platform Review Principle Investigator: Dr. Henriette I. Jager Organization: Oak Ridge National...

  6. Analysis of water and soil from the wetlands of Upper Three Runs Creek. Volume 2A, Analytical data packages September--October 1991 sampling

    SciTech Connect (OSTI)

    Haselow, L.A.; Rogers, V.A. [Westinghouse Savannah River Co., Aiken, SC (United States); Riordan, C.J. [Metcalf and Eddy, Inc. (United States); Eidson, G.W.; Herring, M.K. [Normandeau Associates, Inc. (United States)

    1992-08-01

    Shallow water and soils along Upper Three Runs Creek (UTRC) and associated wetlands between SRS Road F and Cato Road were sampled for nonradioactive and radioactive constituents. The sampling program is associated with risk evaluations being performed for various regulatory documents in these areas of the Savannah River Site (SRS). WSRC selected fifty sampling sites bordering the Mixed Waste Management Facility (MWMF), F- and H-Area Seepage Basins (FHSB), and the Sanitary Landfill (SL). The analytical results from this study provided information on the water and soil quality in UTRC and its associated wetlands. The analytical results from this investigation indicated that the primary constituents and radiological indicators detected in the shallow water and soils were tritium, gross alpha, radium 226, total radium and strontium 90. This investigation involved the collection of shallow water samples during the Fall of 1991 and the Spring of 1992 at fifty (50) sampling locations. Sampling was performed during these periods to incorporate high and low water table periods. Samples were collected from three sections along UTRC denoted as Phase I (MWMF), Phase II (FHSB) and Phase III (SL). One vibracored soil sample was also collected in each phase during the Fall of 1991. This document is compiled solely of experimental data obtained from the sampling procedures.

  7. Tidal-Fluvial and Estuarine Processes in the Lower Columbia River: I. Along-channel Water Level Variations, Pacific Ocean to Bonneville Dam

    SciTech Connect (OSTI)

    Jay, D. A.; Leffler, K.; Diefenderfer, Heida L.; Borde, Amy B.

    2014-06-07

    This two-part paper provides comprehensive time and frequency domain analyses and models of along-channel water level variations in the 234km-long Lower Columbia River and Estuary (LCRE) and documents the response of floodplain wetlands thereto. In Part I, power spectra, continuous wavelet transforms, and harmonic analyses are used to understand the influences of tides, river flow, upwelling and downwelling, and hydropower operations ("power-peaking") on the water level regime. Estuarine water levels are influenced primarily by astronomical tides and coastal processes, and secondarily by river flow. The importance of coastal and tidal influences decreases in the landward direction, and water levels are increasingly controlled by river flow variations at periods from ?1day to years. Water level records are only slightly non-stationary near the ocean, but become increasingly irregular upriver. Although astronomically forced tidal constituents decrease above the estuary, tidal fortnightly and overtide variations increase for 80-200km landward, both relative to major tidal constituents and in absolute terms.

  8. Organic Constituents of the Soil. 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1922-01-01

    materials. As might be expected, those in the excrement are the most resistant to the action of the soil bacteria. Other experiments were made, but the results were similar to this one. SUGARS BY HYDROLYSIS OF SOILS The reducing sugars formed by heating... sheep excrement. The amount of reducing substance, calculated as sugars, produced by heating the soil with la per cent. sulphuric acid varied from .OO2 to .215 per cent. with the average of .058 for 7'7 soils. The nitrogen insoluble in permanganate...

  9. Water Waves and Integrability

    E-Print Network [OSTI]

    Rossen I. Ivanov

    2007-07-12

    The Euler's equations describe the motion of inviscid fluid. In the case of shallow water, when a perturbative asymtotic expansion of the Euler's equations is taken (to a certain order of smallness of the scale parameters), relations to certain integrable equations emerge. Some recent results concerning the use of integrable equation in modeling the motion of shallow water waves are reviewed in this contribution.

  10. WATER TEMPERATURE RECORDS FROM

    E-Print Network [OSTI]

    ? WATER TEMPERATURE RECORDS FROM CALIFORNIA'S CENTRAL VALLEY 1939-1948 Marine Biological i STATES DEPARTMENT OF THE INTERIOR FISH AND WILDLIFE SERVICE #12;#12;a WATER TEMPERATURE RECORDS FROM arid to avoid delay in publication. Washington D. CWATER TEMPERATURE RECORDS FROM

  11. Arkansas Water Resources Center

    E-Print Network [OSTI]

    Soerens, Thomas

    Arkan- sas in order to determine the effect of local manganese, phosphate, pyrite, lead-zinc and uranium mineralization on the groundwater chemistry. Most of this study (75 springs) was concentrated in the Batesville .,.:;, Water Quality. 18 Comparison of Water Chemistry. 27 Geochemical Exploration. 30 Four Minera 1i zed Areas

  12. Achievements and Outlook 2012 SA Water Centre for Water

    E-Print Network [OSTI]

    Mayer, Wolfgang

    Achievements and Outlook 2012 SA Water Centre for Water Management and Reuse #12;Contents Our Breaking News 35 SA Water Centre for Water Management and Reuse University of South Australia Mawson Lakes Campus Mawson Lakes SA 5095 Telephone: +61 (08) 8302 3338 Fax: +61 (08) 8302 3386 Web: unisa.edu.au/water

  13. Headquarters Water Mission Area Water Science Field Team

    E-Print Network [OSTI]

    Headquarters Water Mission Area Water Science Field Team John Ho mann(Tucson, AZ) Chief William Guertal Deputy Associate Director for Water Katie Orsi Executive Assistant Harry House Senior Data Science Support Manager Water Business Operations Gene Summerhill O ce of Water Quality Donna Myers Chief Dave

  14. 1. Introduction Chilled water, a unique resource comprising water and

    E-Print Network [OSTI]

    Ahrendt, Wolfgang

    1. Introduction Chilled water, a unique resource comprising water and energy elements, is commonly the targeted buildings. In typical chilled water systems, chilled water is distributed throughout the building to provide air conditioning and equipment cooling. The chilled water system has been one of the most

  15. The floating water bridge The floating water bridge

    E-Print Network [OSTI]

    Podgornik, Rudolf

    The floating water bridge The floating water bridge Elmar C. Fuchs1 , Jakob Woisetschläger2 , Karl, a stable water connection forms spontaneously, giving the impression of a floating water bridge. A detailed this bridge. 1. Introduction Water undoubtedly is the most important chemical substance in the world. Many

  16. Sources of Water Surface water and groundwater are present throughout

    E-Print Network [OSTI]

    MacAdam, Keith

    Sources of Water Surface water and groundwater are present throughout Kentucky's 39,486 square miles. Surface water occurs as rivers, streams, ponds, lakes, and wetlands. Ground- water occurs underlain by soluble carbonate rocks (for example, limestone). Water Supply · Approximately 49 inches

  17. Biotreatment of produced waters for volume reduction and contaminant removal

    SciTech Connect (OSTI)

    Negri, M.C.; Hinchman, R.R. [Argonne National Lab., IL (United States); Mollock, J. [Devon Energy Corp., Oklahoma City, OK (United States)

    1997-10-01

    Produced water is wastewater that is brought to the surface from natural gas wells during natural gas production. Its constituents, mostly salt, with traces of hydrocarbons and heavy metals, are a significant disposal problem. Argonne National Laboratory (ANL), in partnership with the Gas Research Institute (GRI), has developed a low-cost, low-tech method, in which green plants are used to reduce the volume of produced water. The authors have designed an engineered bioreactor system, which is modeled after natural saline wetland ecosystems. The plant bioreactor system maximizes plant evapotranspiration to reduce wastewater volume and, concurrently, may function as a biological filter to enhance contaminant degradation and immobilization in the root/rhizosphere zone. Halophyte plant species having high salt tolerance and high transpiration rates were selected after they tested them in greenhouse experiments. Models obtained by using their greenhouse findings reduced the volume of the wastewater (up to 6% salt) by 75% in about 8 days. A field demonstration of the bioreactor, designed on the basis of the results from the greenhouse study, is successfully under way at a natural gas well site in Oklahoma. The process could offer the petroleum industry a low-cost biological alternative to existing expensive options.

  18. Selecting activated carbon for water and wastewater treatability studies

    SciTech Connect (OSTI)

    Zhang, W.; Chang, Q.G.; Liu, W.D.; Li, B.J.; Jiang, W.X.; Fu, L.J.; Ying, W.C. [East China University of Chemical Technology, Shanghai (China)

    2007-10-15

    A series of follow-up investigations were performed to produce data for improving the four-indicator carbon selection method that we developed to identify high-potential activated carbons effective for removing specific organic water pollutants. The carbon's pore structure and surface chemistry are dependent on the raw material and the activation process. Coconut carbons have relatively more small pores than large pores; coal and apricot nutshell/walnut shell fruit carbons have the desirable pore structures for removing adsorbates of all sizes. Chemical activation, excessive activation, and/or thermal reactivation enlarge small pores, resulting in reduced phenol number and higher tannic acid number. Activated carbon's phenol, iodine, methylene blue, and tannic acid numbers are convenient indicators of its surface area and pore volume of pore diameters < 10, 10-15, 15-28, and > 28 angstrom, respectively. The phenol number of a carbon is also a good indicator of its surface acidity of oxygen-containing organic functional groups that affect the adsorptive capacity for aromatic and other small polar organics. The tannic acid number is an indicator of carbon's capacity for large, high-molecular-weight natural organic precursors of disinfection by-products in water treatment. The experimental results for removing nitrobenzene, methyl-tert-butyl ether, 4,4-bisphenol, humic acid, and the organic constituents of a biologically treated coking-plant effluent have demonstrated the effectiveness of this capacity-indicator-based method of carbon selection.

  19. The solubility and speciation of molybdenum in water vapour at elevated temperatures and pressures: Implications for ore genesis

    E-Print Network [OSTI]

    Long, Bernard

    transport sufficient Mo in about 115,000 years (within the life of geothermal systems) to form a deposit their concentrations in the coexisting brine are 0.30 wt.% and 70 ppm, respectively. Significantly, metal

  20. THERMAL CONDUCTIVITY OF AQUEOUS NaCl SOLUTIONS

    Office of Scientific and Technical Information (OSTI)

    and uti1 ization of geothermal energy, petroleum recovery, desalination of sea water, and other energy systems involving water containing dissolved salts. brines contain a...

  1. Effects of uncertainty in rock-physics models on reservoir parameter estimation using marine seismic AVA and CSEM data

    E-Print Network [OSTI]

    Chen, Jinsong; Dickens, Thomas

    2008-01-01

    random functions of reservoir water saturation and porosity,models We relate reservoir water saturation S w and porosityexponent Saturation exponent Reservoir brine resistivity (W-

  2. WATER-TRAPPED WORLDS

    SciTech Connect (OSTI)

    Menou, Kristen [Department of Astronomy, Columbia University, 550 West 120th Street, New York, NY 10027 (United States)

    2013-09-01

    Although tidally locked habitable planets orbiting nearby M-dwarf stars are among the best astronomical targets to search for extrasolar life, they may also be deficient in volatiles and water. Climate models for this class of planets show atmospheric transport of water from the dayside to the nightside, where it is precipitated as snow and trapped as ice. Since ice only slowly flows back to the dayside upon accumulation, the resulting hydrological cycle can trap a large amount of water in the form of nightside ice. Using ice sheet dynamical and thermodynamical constraints, I illustrate how planets with less than about a quarter the Earth's oceans could trap most of their surface water on the nightside. This would leave their dayside, where habitable conditions are met, potentially dry. The amount and distribution of residual liquid water on the dayside depend on a variety of geophysical factors, including the efficiency of rock weathering at regulating atmospheric CO{sub 2} as dayside ocean basins dry up. Water-trapped worlds with dry daysides may offer similar advantages as land planets for habitability, by contrast with worlds where more abundant water freely flows around the globe.

  3. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Martin Chaplin

    2007-06-10

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

  4. IRRIGATION WATER QUALITY FOR AGRICULTURE

    E-Print Network [OSTI]

    Radcliffe, David

    IRRIGATION WATER QUALITY FOR AGRICULTURE Irrigation Water Background In the past, there were minor of irrigation water in Georgia. This is because only a small amount of acreage under irrigated agriculture utilized potable (suitable for drinking) quality water. Thus, quality of irrigation water was not closely

  5. Green Systems Solar Hot Water

    E-Print Network [OSTI]

    Schladow, S. Geoffrey

    Green Systems Solar Hot Water Heating the Building Co-generation: Heat Recovery System: Solar Thermal Panels (Trex enclosure) Hot Water Storage Tank (TS-5; basement) Hot Water Heaters (HW-1,2; basement) Pre-heats water so water heaters don't need to use as much energy Gas-powered, high efficiency

  6. WATER SUPPLY A Handbook on

    E-Print Network [OSTI]

    US Army Corps of Engineers

    WATER SUPPLY HANDBOOK A Handbook on Water Supply Planning and Resource Management Institute for Water Resources Water Resources Support Center U.S. Army Corps of Engineers 7701 Telegraph Road Studies Division December 1998 Revised IWR Report 96-PS-4 #12;U.S. Army Institute for Water Resources

  7. Water Rx - The Problem of Pharmaceuticals in Our Nation's Waters

    E-Print Network [OSTI]

    Leitman, Melanie

    2011-01-01

    collaboratively lead in our ef- forts to eliminate Water R.PHARMACEUTICALS IN OUR NATION'S WATERS wastes. 20 5 ThisPharmaceuticals in Surface Waters: Use of NEPA, NAT. Ri:s. &

  8. Water in Asbestos

    E-Print Network [OSTI]

    Fomin, Yu D; Tsiok, E N

    2015-01-01

    We present the molecular simulation study of the behavior of water and sodium chloride solution confined in lizardite asbestos nanotube which is a typical example of hydrophilic confinement. The local structure, orientational and dynamic properties are studied. It is shown that the diffusion coefficient drops about two orders of magnitude comparing to the bulk case, and water in lizardite asbestos tubes experiences vitrification rather then crystallization upon cooling in accordance with the results for some other hydrophilic confinements. The behavior of sodium chloride solutions also considered and the formation of double layer is observed. It is shower that both sodium and chlorine have larger diffusion coefficients then water.

  9. Wind/Water Nexus

    SciTech Connect (OSTI)

    Not Available

    2006-04-01

    Nobel laureate Richard Smalley cited energy and water as among humanity's top problems for the next 50 years as the world's population increases from 6.3 billion to 9 billion. The U.S. Department of Energy's Wind and Hydropower Program has initiated an effort to explore wind energy's role as a technical solution to this critically important issue in the United States and the world. This four-page fact sheet outlines five areas in which wind energy can contribute: thermoelectric power plant/water processes, irrigation, municipal water supply, desalination, and wind/hydropower integration.

  10. Drinking Water Problems: Radionuclides 

    E-Print Network [OSTI]

    Lesikar, Bruce J.; Melton, Rebecca; Hare, Michael; Hopkins, Janie; Dozier, Monty

    2006-08-04

    that are radioactive. The most common radionu- clides in drinking water are radium, radon and uranium. Most of the radionuclides in drinking water occur nat- urally at very low levels and are not considered a pub- lic health concern. However, radionuclides can also...-rays, can pass through the human body and are best shielded by dense materials such as lead or thick concrete. levels no higher than 4,000 pCi/L. Because about 1/10,000th of radon in water transfers to air, this would contribute about 0.4 pCi/L of radon...

  11. Water | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout /Two0Photos and Videos/01/2012 Page 1WaterWater forWater The

  12. Water | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematics And Statistics » USAJobsMotionHeatEnergy Solar Training for8 Things YouAboutWater Water Water

  13. California State Water Resources Control Board 401 Water Quality...

    Open Energy Info (EERE)

    California State Water Resources Control Board 401 Water Quality Certification Website Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: California State...

  14. Results of ground-water monitoring for radionuclides in the Separations Area, 1987

    SciTech Connect (OSTI)

    Serkowski, J.A.; Law, A.G.; Ammerman, J.J.; Schatz, A.L.

    1988-04-01

    The purpose of this report is to present a summary of the results for calendar year 1987 of the Westinghouse Hanford Company (Westinghouse Hanford) ground-water monitoring program for radiological constituents in the Separations Area of the Hanford Site. This monitoring program is implemented to partially fulfill the US Department of Energy (DOE) requirement that radioactivity in the environment be monitored. The program is also used to monitor operating disposal facilities for compliance with DOE requirements. The Separations Area radionuclide ground-water monitoring program is coordinated with other ground-water monitoring activities on the Hanford Site conducted by Westinghouse Hanford and Pacific Northwest Laboratory (PNL). The PNL program includes sampling for both radioactive and nonradioactive chemicals throughout the Site (including 100 and 300 Areas) and is responsible for estimating and evaluating the impact on ground water to the general public from all operations at the Hanford Site. Ground water characterization and monitoring for compliance with Resource Conservation and Recovery Act (RCRA) is also being conducted at facilities on the Hanford Site.

  15. Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters

    SciTech Connect (OSTI)

    Ahmed, Musahid; Ahmed, Musahid; Wilson, Kevin R.; Belau, Leonid; Kostko, Oleg

    2008-05-12

    In this work we report on thevacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuumultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH + (n=1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH)n(H2O)H + (n=2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH +, (CH 3OH)2 +, (CH3OH)nH + (n=1-9), and (CH 3OH)n(H2O)H + (n=2-9 ) as a function of photon energy. With an increase in the water content in the molecular beam, there is an enhancement of photoionization intensity for methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

  16. Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters

    SciTech Connect (OSTI)

    Kostko, Oleg; Belau, Leonid; Wilson, Kevin R.; Ahmed, Musahid

    2008-04-24

    In this work, we report on the vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuum-ultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH+(n = 1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH n(H2O)H+ (n = 2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH+, (CH3OH)2+, (CH3OH)nH+ (n = 1-9), and (CH3OH)n(H2O)H+ (n = 2-9) as a function of photon energy. With an increasein the water content in the molecular beam, there is an enhancement of photoionization intensity for the methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

  17. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    Oil Production .quality water (2, 32). Oil Production In 2009, oil supplied90% of U.S. onshore oil production uses between 2.1 and 5.4

  18. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    produced water from production of crude oil, natural gas,the production and processing of each gallon of crude oil (production and processing of 1 gallon (3.8 liters) of crude oil

  19. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01

    water from production of crude oil, natural gas, and coaleach gallon (3.79 liters) of crude oil. When combined withto refine each gallon of crude oil, between 3.6 and 7.0

  20. UV water disinfector

    DOE Patents [OSTI]

    Gadgil, Ashok (El Cerrito, CA); Garud, Vikas (Bombay, IN)

    1998-07-14

    A UV disinfector with a gravity driven feed water delivery system, and an air-suspended bare UV lamp. The disinfector is hydrodynamically optimized with a laminerizing, perforated baffle wall, beveled treatment chamber, and outlet weir.

  1. Contaminating Fresh Waters (Florida)

    Broader source: Energy.gov [DOE]

    It is illegal to discharge any dyestuff, coal tar, oil, sawdust, poison, or deleterious substances into any fresh running waters in Florida in quantities sufficient to injure, stupefy, or kill fish...

  2. Water Sample Concentrator

    ScienceCinema (OSTI)

    Idaho National Laboratory

    2010-01-08

    Automated portable device that concentrates and packages a sample of suspected contaminated water for safe, efficient transport to a qualified analytical laboratory. This technology will help safeguard against pathogen contamination or chemical and biolog

  3. Cooling Water System Optimization 

    E-Print Network [OSTI]

    Aegerter, R.

    2005-01-01

    During summer months, many manufacturing plants have to cut back in rates because the cooling water system is not providing sufficient cooling to support higher production rates. There are many low/no-cost techniques available to improve tower...

  4. Energy and Water Act

    Broader source: Energy.gov (indexed) [DOE]

    Letter 2004-02 - FY 2004 Le2islation Provisions (dated March 1.2004) Energy and Water Act AL-2004-02 provides guidance regarding the implementation of Section 30 I. 304....

  5. Optimization of Cooling Water 

    E-Print Network [OSTI]

    Matson, J.

    1985-01-01

    A cooling water system can be optimized by operation at the highest possible cycles of concentration without risking sealing and fouling on heat exchanger surfaces. The way to optimize will be shown, with a number of examples of new systems....

  6. Electrolysis of Water

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolysis of Water Grades: 5-8 Topic: Hydrogen and Fuel Cells, Solar Owner: Florida Solar Energy Center This educational material is brought to you by the U.S. Department of...

  7. UV water disinfector

    DOE Patents [OSTI]

    Gadgil, A.; Garud, V.

    1998-07-14

    A UV disinfector with a gravity driven feed water delivery system and an air-suspended bare UV lamp are disclosed. The disinfector is hydrodynamically optimized with a laminerizing, perforated baffle wall, beveled treatment chamber, and outlet weir. 7 figs.

  8. Thermoelectrically cooled water trap

    DOE Patents [OSTI]

    Micheels, Ronald H. (Concord, MA)

    2006-02-21

    A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

  9. Laboratory development and field application of a novel water-based drill-in fluid for geopressured horizontal wells

    SciTech Connect (OSTI)

    Dobson, J.W.; Harrison, J.C.; Hale, A.H.

    1996-12-31

    Research has identified a novel water-based drill-in fluid for drilling and completing geopressured horizontal wells. This fluid has a unique combination of properties which make it especially suitable for geopressured applications. They include the use of calcium and/or zinc bromide as a base brine, minimal concentration of calcium carbonate as bridging material, low plastic viscosity, tight fluid loss control, good filter cake properties, and excellent return permeability. This drill-in fluid has been used successfully to drill a 1,200 foot production interval, 4.75 inch diameter wellbore in the Gulf of Mexico with a system weight of 13.2 lbm/gal, bottom hole temperature of 185{degrees} F., and a 1400 to 1700 psi overbalance. The system functioned very well in both the drilling and completion operations. Fluid rheology was easily maintainable and the hole conditions were excellent without torque or drag problems. Initial production data suggests that the well is producing at expected rates with low drawdown pressure.

  10. Purifying contaminated water

    DOE Patents [OSTI]

    Daughton, Christian G. (San Pablo, CA)

    1983-01-01

    Process for removing biorefractory compounds from contaminated water (e.g., oil shale retort waste-water) by contacting same with fragmented raw oil shale. Biorefractory removal is enhanced by preactivating the oil shale with at least one member of the group of carboxylic, acids, alcohols, aldehydes, ketones, ethers, amines, amides, sulfoxides, mixed ether-esters and nitriles. Further purification is obtained by stripping, followed by biodegradation and removal of the cells.

  11. Water Quality Criteria Introduction ....................................................................................................................................798

    E-Print Network [OSTI]

    Pitt, Robert E.

    APPENDIX G Water Quality Criteria CONTENTS Introduction ....................................................................................................................................798 EPA's Water Quality Criteria and Standards Plan -- Priorities for the Future............................798 Compilation of Recommended Water Quality Criteria and EPA's Process for Deriving New

  12. Designing Water Smart Landscapes Activity

    E-Print Network [OSTI]

    Designing Water Smart Landscapes Activity Objective: Create a water smart home landscape. Materials://aggie-horticulture.tamu.edu/plantanswers/publications/publications.html Draw the plants, using tracing paper. Citizenship Activity Develop a water smart plan for a non

  13. Gas Water Heater Energy Losses

    E-Print Network [OSTI]

    Biermayer, Peter

    2012-01-01

    B: Input Screens SCREEN D1: WATER HEATER SPECIFICATIONS 1.no baffle present SCREEN G: WATER SUPPLY AND DRAW PIPEfor EIDs (sec) 0.0 9. Supply Water Temperature (F) 58.00 10.

  14. Emergency Food and Water Supplies 

    E-Print Network [OSTI]

    Van Laanen, Peggy

    1999-05-14

    Creating an emergency supply of food and water, and knowing how to safely handle food and water after a disaster, can reduce stress, worry and inconvenience. This publication provides information on water supply storage and purification...

  15. Gas Water Heater Energy Losses

    E-Print Network [OSTI]

    Biermayer, Peter

    2012-01-01

    forty gallon residential gas-fired storage water heater wasthat could replace a gas-fired storage water heater with adefined a baseline gas-fired storage water heater that meets

  16. Spatial Water Balance in Texas 

    E-Print Network [OSTI]

    Reed, Seann; Maidment, David; Patoux, Jerome

    1994-01-01

    different components of the hydrologic cycle - an atmospheric water balance, a soil-water balance, and a surface water balance. These models were constructed using a geographic information system (GIS). A GIS provides a framework for storing and manipulating...

  17. Year Project Title USGS contact(s) Published paper, data source,

    E-Print Network [OSTI]

    _poster_Final.pdf Vulnerability assessment methods Energy Development, Williston Basin, Brine information Keywords 1 2003-present Delineation of brine contamination in and near the East Poplar oil field_poplar/index.html Project assesses brine contamination to the shallow aquifers and surface water. Energy Development

  18. The Chilled Water and Hot Water Building Differential Pressure Setpoint Calculation - Chilled Water and Hot Water Pump Speed Control 

    E-Print Network [OSTI]

    Turner, W. D.; Bruner, H., Jr.; Claridge, D.; Liu, C.; Deng, S.

    2002-01-01

    Water and Hot Water Building Deferential Pressure Setpoint Calculation ? Chilled Water and Hot Water Pump Speed Control Chenggang Liu Research Associate Energy Systems Laboratory Texas A&M University College Station, TX Homer L. Bruner... of chilled water and hot water consumption with the leaking control valves on the cooling and heating coils. Variable speed pumps save cooling and heating energies. However, most of these advantages are lost when proper speed control is not maintained...

  19. Molded polymer solar water heater

    DOE Patents [OSTI]

    Bourne, Richard C.; Lee, Brian E.

    2004-11-09

    A solar water heater has a rotationally-molded water box and a glazing subassembly disposed over the water box that enhances solar gain and provides an insulating air space between the outside environment and the water box. When used with a pressurized water system, an internal heat exchanger is integrally molded within the water box. Mounting and connection hardware is included to provide a rapid and secure method of installation.

  20. Virgin Islands Water Resources Research Institute Annual Technical Report

    E-Print Network [OSTI]

    , Recreation, Waste Water Descriptors: Water Quality Standards,Water Quality Monitoring, Water Quality, Viruses