National Library of Energy BETA

Sample records for brine brine string

  1. Viscous heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1984-07-10

    Hydroxyethyl cellulose and a sequestrant are added to a heavy brine containing one or more salts selected from calcium chloride, calcium bromide, and zinc bromide to increase the viscosity of the brine. Preferably the brine contains zinc bromide, has a density in the range from about 14.2-19.2 pounds per gallon, and the sequestrant is a polyphosphonic acid or water soluble salt thereof.

  2. Thickened heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1983-12-13

    A thickened brine solution useful as a well servicing fluid is prepared, said solution consisting essentially of water, at least 20% by weight zinc bromide, calcium bromide, and a viscosifying amount of hydroxyethyl cellulose.

  3. Brine stability study

    SciTech Connect (OSTI)

    Gary Garland

    2015-04-15

    This is a study of the brine formulations that we were using in our testing were stable over time. The data includes charts, as well as, all of the original data from the ICP-MS runs to complete this study.

  4. Gas evolution from geopressured brines

    SciTech Connect (OSTI)

    Matthews, C.S.

    1980-06-01

    The process of gas evolution from geopressured brine is examined using as a basis the many past studies of gas evolution from liquids in porous media. A discussion of a number of speculations that have been made concerning gas evolution from geopressured brines is provided. According to one, rapid pressure reduction will cause methane gas to evolve as when one opens a champagne bottle. It has been further speculated that evolved methane gas would migrate up to form an easily producible cap. As a result of detailed analyses, it can be concluded that methane gas evolution from geopressured brines is far too small to ever form a connected gas saturation except very near to the producing well. Thus, no significant gas cap could ever form. Because of the very low solubility of methaned in brine, the process of methane gas evolution is not at all analogous to evolution of carbon dioxide from champagne. A number of other speculations and questions on gas evolution are analyzed, and procedures for completing wells and testing geopressured brine reservoirs are discussed, with the conclusion that presently used procedures will provide adequate data to enable a good evaluation of this resource.

  5. Brine Sampling and Evaluation Program, 1991 report

    SciTech Connect (OSTI)

    Deal, D.E.; Abitz, R.J.; Myers, J.; Martin, M.L.; Milligan, D.J.; Sobocinski, R.W.; Lipponer, P.P.J.; Belski, D.S.

    1993-09-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plan (WIPP) during 1991. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. When excavations began at the WIPP in 1982, small brine seepages (weeps) were observed on the walls. Brine studies began as part of the Site Validation Program and were formalized as a program in its own right in 1985. During nine years of observations (1982--1991), evidence has mounted that the amount of brine seeping into the WIPP excavations is limited, local, and only a small fraction of that required to produce hydrogen gas by corroding the metal in the waste drums and waste inventory. The data through 1990 is discussed in detail and summarized by Deal and others (1991). The data presented in this report describes progress made during the calendar year 1991 and focuses on four major areas: (1) quantification of the amount of brine seeping across vertical surfaces in the WIPP excavations (brine ``weeps); (2) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes; (3) further characterization of brine geochemistry; and (4) preliminary quantification of the amount of brine that might be released by squeezing the underconsolidated clays present in the Salado Formation.

  6. Viscous heavy brine completion fluids. [Oil wells

    SciTech Connect (OSTI)

    Darlington, R.K.; Hunter, D.V.

    1982-01-01

    An activated hydroxyethyl cellulose (HEC) has been developed which will viscosify brines of any density up to 19.2 lb/gal containing calcium chloride, calcium bromide and/or zinc bromide. The use of activated hydroxyethyl cellulose allows preparation of viscosified brines at ambient emperature and without undissolved polymer solids. The time required to prepare a viscosified brine is greatly reduced. In addition, the rheology of brines viscosified with activated HEC can be accurately predicted allowing brines with equivalent solution rheology properties to be prepared batch after batch. 29 refs.

  7. Improved Water Flooding through Injection Brine Modification

    SciTech Connect (OSTI)

    Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman

    2003-01-01

    Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

  8. Brine disposal process for Morcinek coal mine

    SciTech Connect (OSTI)

    Tait, J.H.

    1995-04-01

    This paper describes the work to develop a commercial brine disposal process for the Morcinek mine, located 45 km south of the city of Katowice in Poland. Currently, brine is discharged into the Odra river and methane from the mine is released into the atmosphere. The process would use the released methane and convert a large percentage of the brine into potable water for commercial use. Thus, the proposed process has two environmental benefits. The brine salinity is about 31,100 ppm. Major brine components are Na (10,300 ppm), Ca (1,170 ppm), Mg (460 ppm), Cl (18,500 ppm) and SO{sub 4}{sup 2-} (252 ppm). Present in smaller amounts are K, S, Sr, B, Ba and NO{sub 3}. The process integrates a reverse osmosis (RO) unit and a submerged combustion evaporator. Extensive studies made at the Lawrence Livermore National Laboratory established the pretreatment method of the brine before it enters the RO unit. Without adequate pretreatment, mineral phases in the brine would become super-saturated and would precipitate in the RO unit. The pretreatment consists of first adding sodium carbonate to increase both the pH and the carbonate concentration of the brine. This addition causes precipitation of carbonate solids containing Ca, Mg, Sr, and Ba. After filtration of these precipitates, the fluid is acidified with HCl to prevent precipitation in the RO unit as the brine increases in salinity.

  9. Brine Migration Experimental Studies for Salt Repositories

    Broader source: Energy.gov [DOE]

    Experiments were used to examine water content in Permian salt samples including impact of variation in thermal regime on water content of evaporites and other mineral species, behavior of brine inclusions in salt, and evolution of the gas/liquid brine/salt system.

  10. Summary Results for Brine Migration Modeling Performed by LANL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program Summary Results for Brine Migration Modeling Performed by LANL, LBNL and ...

  11. Modeling acid-gas generation from boiling chloride brines (Journal...

    Office of Scientific and Technical Information (OSTI)

    Modeling acid-gas generation from boiling chloride brines Citation Details In-Document Search Title: Modeling acid-gas generation from boiling chloride brines This study ...

  12. Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide, Brine, and Clay ...

  13. TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems...

    Office of Scientific and Technical Information (OSTI)

    Title: TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems Deep saline formations and oil and gas reservoirs often contain concentrated brine solutions of ionic ...

  14. Raft River Geothermal Field Well Head Brine Sample

    SciTech Connect (OSTI)

    Tim Lanyk

    2015-12-18

    Raw data and data workup of assay for real-world brine sample. Brine sample was taken at the well head.

  15. Property:BrineConstituents | Open Energy Information

    Open Energy Info (EERE)

    Chloride type brine, "The content of potassium and calcium are high, while that of lithium, boron and sulfate is very low", See table 1 of Izquierdo et al. (2006). + Chena...

  16. How temperature and pressure affect clear brines

    SciTech Connect (OSTI)

    Hubbard, J.T.

    1984-04-01

    The correct application of the expansivity and compressibility of brine fluids under the influence of temperature and pressure is needed to calculate the actual hydrostatic pressure in a well. Well operations can benefit by reducing unintentional overbalance, lessening fluid losses, and lowering recommended fluid densities, hence reducing fluid costs. Since the early 1970s, the effects of temperature and pressure on the density of clear brine fluids have been questioned. As early as 1973, studies were started to define density loss with increased temperature in zinc bromide brines. This article describes a continuing study, begun in 1978, which has characterized the expansivity and compressibility of single salt brine solutions, such as are used in workover and completion fluids.

  17. Integrated process for coalbed brine disposal

    SciTech Connect (OSTI)

    Brandt, H. |; Bourcier, W.L.; Jackson, K.J.

    1994-03-01

    A brine disposal process is described that converts the brine stream of a coalbed gas producing site into clean water for agricultural use, combustion products and water vapor that can be released into the atmosphere and dry solids that can be recycled for industrial consumption. The process uses a reverse osmosis unit, a submerged combustion evaporator and a pulse combustion dryer. Pretreatment of the brine feedstream is necessary to prevent fouling of the membranes of the reverse osmosis unit and to separate from the brine stream hazardous metal and other constituents that may make the permeate from the reverse osmosis unit unsuitable for agricultural or other use. A chemical modeling code is used to calculate the saturation states of solids that may precipitate and foul the reverse osmosis membranes. Sodium carbonate is added to the brine to precipitate carbonates of Ba, Ca, Mg and Sr prior to filtration, acidification, and passage into the reverse osmosis unit. Optimization of the process in terms of types and amounts of additives is possible with analysis using the modeling code. The minimum amounts of additives to prevent scaling are calculated. In a typical operation, a brine feedstream of 1,000 m{sup 3}/day (6,290 bpd) that may have a total dissolved salt concentration (TDS) of 7,000 ppm will be separated into a permeate stream of 750 m{sup 3}/day (4,718 bpd) with a TDS of 400 ppm and a concentrated brine stream of 250 m{sup 3}/day (1,573 bpd) with a TDS of 26,800 ppm. The submerged combustion evaporator will concentrate this latter stream to a concentration of 268,000 ppm and reduce the volume to 25 m{sup 3}/day (158 bpd). The pulse combustion dryer can dry the concentrated brine mixture to a low moisture salt. Energy costs to operate the reverse osmosis unit are primarily the pumping costs.

  18. Hydrocarbon content of geopressured brines. Final report

    SciTech Connect (OSTI)

    Osif, T.L.

    1985-08-01

    Design Well data (bottomhole pressure minus wellhead pressure, GWR, and hydrocarbon composition) is presented as a function of producing conditions. These are examined in conjunction with the following models to attempt to deduce the reservoir brine saturation level: (1) reservoir contains gas dispersed in the pores and the gas saturation is greater than critical; (2) reservoir brine is gas-saturated; (3) bubble point below hydrostatic pressure; and (4) bubble point between hydrostatic pressure and reservoir pressure. 24 figs., 10 tabs. (ACR)

  19. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  20. Portable brine evaporator unit, process, and system

    DOE Patents [OSTI]

    Hart, Paul John; Miller, Bruce G.; Wincek, Ronald T.; Decker, Glenn E.; Johnson, David K.

    2009-04-07

    The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

  1. Method of removing benzene from petroleum desalter brine

    SciTech Connect (OSTI)

    Hart, P.R.

    1993-08-17

    A method is described for removing benzene from petroleum refinery desalter effluent brine containing dispersed oil, solids, oily solids and benzene comprising contacting the brine with a sufficient amount for the purpose of flocculating oily solids of a combination of a aluminum chlorohydrate and a water soluble cationic polymer selected from the group consisting of polyamines and dialkyldiallylammonium polymers, in a ratio of from 1:10 to 100:1 at a temperature of about 250 F, separating the resulting floc from the brine; and thereafter contacting the brine with a sufficient amount for the purpose of reducing benzene levels in the brine of an oil solvent in combination with a demulsifier.

  2. Expected brine movement at potential nuclear waste repository salt sites

    SciTech Connect (OSTI)

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

  3. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon ...

  4. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide ...

  5. Fate of Magnesium Chloride Brine Applied to Suppress Dust from...

    Office of Scientific and Technical Information (OSTI)

    Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests ...

  6. Origin, distribution, and movement of brine in the Permian Basin (U. S. A. ). A model for displacement of connate brine

    SciTech Connect (OSTI)

    Bein, A.; Dutton, A.R. )

    1993-06-01

    Na-Cl, halite Ca-Cl, and gypsum Ca-Cl brines with salinities from 45 to >300 g/L are identified and mapped in four hydrostratigraphic units in the Permian Basin area beneath western Texas and Oklahoma and eastern New Mexico, providing spatial and lithologic constraints on the interpretation of the origin and movement of brine. Na-Cl brine is derived from meteoric water as young as 5-10 Ma that dissolved anhydrite and halite, whereas Ca-Cl brine is interpreted to be ancient, modified-connate Permian brine that now is mixing with, and being displaced by, the Na-Cl brine. Displacement fronts appear as broad mixing zones with no significant salinity gradients. Evolution of Ca-Cl brine composition from ideal evaporated sea water is attributed to dolomitization and syndepositional recycling of halite and bittern salts by intermittent influx of fresh water and sea water. Halite Ca-Cl brine in the evaporite section in the northern part of the basin differs from gypsum Ca-Cl brine in the south-central part in salinity and Na/Cl ratio and reflects segregation between halite- and gypsum-precipitating lagoons during the Permian. Ca-Cl brine moved downward through the evaporite section into the underlying Lower Permian and Pennsylvanian marine section that is now the deep-basin brine aquifer, mixing there with pre-existing sea water. Buoyancy-driven convection of brine dominated local flow for most of basin history, with regional advection governed by topographically related forces dominant only for the past 5 to 10 Ma. 71 refs., 11 figs.

  7. Reduce completion fluid costs with on-site brine tests

    SciTech Connect (OSTI)

    Thomas, D.C.; Darlington, R.K.; Kinney, W.R.; Lowell, J.L.

    1982-09-01

    A newly developed field kit makes on-site brine completion fluid testing practical. Simple titration procedures are used to analyze brine for calcium, zinc, chloride and bromide with an accuracy and repeatability that compares favorably with expensive laboratory techniques. This article describes the field testing theory and details analytical procedures used.

  8. Radionuclide transport in sandstones with WIPP brine

    SciTech Connect (OSTI)

    Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

    1981-02-01

    Retardation factors (R) have been measured for the transport of /sup 3/H, /sup 95m/Tc, and /sup 85/Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for /sup 85/Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for /sup 85/Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta.

  9. Technique for thermodynamic crystallization temperature of brine fluids

    SciTech Connect (OSTI)

    Clark, D.E.; Hubbard, J.T.

    1983-03-01

    The application of high density solids free brine fluids has proven to be technically and economically successful in hydrocarbon completion and workover operations. The use of inorganic salts such as calcium chloride, calcium bromide, zinc bromide, and sodium bromide has contributed to the development of complex salt systems. As the density and complexity of these systems becomes more detailed, the requirement for proper fluid design becomes increasingly important. When a brine solution is cooled sufficiently, a temperature is reached where the solution will be saturated. A further decrease in temperature will result in the precipitation of salt from the solution. The temperature at which this transpires, provided no super-cooling occurs, is the crystallization point of the solution. A correctly formulated solids free brine should have the optimum crystallization point for the temperature conditions it will encounter. A recently developed semiautomatic procedure constructs a cooling curve plot of each brine tested. This cooling curve plot allows the determination of the super-cooling potential, the Thermodynamic Crystallization Temperature, and the Last Crystal To Dissolve Temperature. The device provides a permanent record of the cooling curve with repeatable accuracy, which assists in the development of error free brine formulation tables, brine density, and/or crystallization point adjustments, and brine analysis.

  10. Formate brines -- New fluids for drilling and completions

    SciTech Connect (OSTI)

    Ramsey, M.S.; Shipp, J.A.

    1996-01-01

    The term ``formate brines`` refers broadly to three primary compounds dissolved in water -- sodium formate (NaCOOH), potassium formate (KCOOH) and cesium formate (CsCOOH). Each is chemically classified as an alkali-metal salt of formic acid. They offer properties that in many respects are superior to their predecessors, halide brines such as zinc bromide and calcium bromide, without the undesirable side effects of those more common halide brine systems. This article introduces the technology and provides an overview of published work to date regarding formates.

  11. Actinide (III) solubility in WIPP Brine: data summary and recommendations

    SciTech Connect (OSTI)

    Borkowski, Marian; Lucchini, Jean-Francois; Richmann, Michael K.; Reed, Donald T.

    2009-09-01

    The solubility of actinides in the +3 oxidation state is an important input into the Waste Isolation Pilot Plant (WIPP) performance assessment (PA) models that calculate potential actinide release from the WIPP repository. In this context, the solubility of neodymium(III) was determined as a function of pH, carbonate concentration, and WIPP brine composition. Additionally, we conducted a literature review on the solubility of +3 actinides under WIPP-related conditions. Neodymium(III) was used as a redox-invariant analog for the +3 oxidation state of americium and plutonium, which is the oxidation state that accounts for over 90% of the potential release from the WIPP through the dissolved brine release (DBR) mechanism, based on current WIPP performance assessment assumptions. These solubility data extend past studies to brine compositions that are more WIPP-relevant and cover a broader range of experimental conditions than past studies.

  12. Brine pH Modification Scale Control Technology. 2. A Review.pdf...

    Open Energy Info (EERE)

    Brine pH Modification Scale Control Technology. 2. A Review.pdf Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Brine pH Modification Scale...

  13. Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential...

    Office of Environmental Management (EM)

    Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential August 21, 2013 - 12:00am Addthis Utilizing a 1...

  14. Uranium (VI) solubility in carbonate-free ERDA-6 brine

    SciTech Connect (OSTI)

    Lucchini, Jean-francois; Khaing, Hnin; Reed, Donald T

    2010-01-01

    When present, uranium is usually an element of importance in a nuclear waste repository. In the Waste Isolation Pilot Plant (WIPP), uranium is the most prevalent actinide component by mass, with about 647 metric tons to be placed in the repository. Therefore, the chemistry of uranium, and especially its solubility in the WIPP conditions, needs to be well determined. Long-term experiments were performed to measure the solubility of uranium (VI) in carbonate-free ERDA-6 brine, a simulated WIPP brine, at pC{sub H+} values between 8 and 12.5. These data, obtained from the over-saturation approach, were the first repository-relevant data for the VI actinide oxidation state. The solubility trends observed pointed towards low uranium solubility in WIPP brines and a lack of amphotericity. At the expected pC{sub H+} in the WIPP ({approx} 9.5), measured uranium solubility approached 10{sup -7} M. The objective of these experiments was to establish a baseline solubility to further investigate the effects of carbonate complexation on uranium solubility in WIPP brines.

  15. Durability of concrete materials in high-magnesium brine

    SciTech Connect (OSTI)

    Wakeley, L.D.; Poole, T.S.; Burkes, J.P.

    1994-03-01

    Cement pastes and mortars representing 11 combinations of candidate concrete materials were cast in the laboratory and monitored for susceptibility to chemical deterioration in high-magnesium brine. Mixtures were selected to include materials included in the current leading candidate concrete for seals at the Waste Isolation Pilot Plant (WIPP). Some materials were included in the experimental matrix to answer questions that had arisen during study of the concrete used for construction of the liner of the WIPP waste-handling shaft. Mixture combinations compared Class C and Class F fly ashes, presence or absence of an expansive component, and presence or absence of salt as a mixture component. Experimental conditions exposed the pastes and mortars to extreme conditions, those being very high levels of Mg ion and an effectively unlimited supply of brine. All pastes and mortars showed deterioration with brine exposure. In general, mortars deteriorated more extensively than the corresponding pastes. Two-inch cube specimens of mortar were not uniformly deteriorated, but showed obvious zoning even after a year in the brine, with a relatively unreacted zone remaining at the center of each cube. Loss of calcium from the calcium hydroxide of paste/aggregate interfaces caused measurable strength loss in the reacted zone comprising the outer portion of every mortar specimen. The current candidate mass concrete for WIPP seals includes salt as an initial component, and has a relatively closed initial microstructure. Both of these features contribute to its suitability for use in large placements within the Salado Formation.

  16. Progress on radiometric dating of Wolfcamp brines using /sup 4/He and /sup 40/Ar

    SciTech Connect (OSTI)

    Zaikowski, A.; Kosanke, B.J.; Hubbard, N.

    1984-01-01

    Ground water samples (brines) from deep wells in the Palo Duro Basin, Texas are being analyzed for noble gases in an attempt to obtain radiometric ages for these brines. The brines contain radiogenic /sup 4/He and /sup 40/Ar produced from the radioactive decay of U, Th, and K. Consideration of hydrochemical data for the brines, various isotopic, chemical, and mineralogical data for the aquifer rocks and noble gas production rates allow estimating the age of the brines to be about 130 million years at two wells. At a third well interaquifer mixing has occurred and the age is presently indeterminate. 9 references, 3 figures, 1 table.

  17. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect (OSTI)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  18. Pre-injection brine production for managing pressure in compartmentalized CO₂ storage reservoirs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO₂ storage that combines CO₂ injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO₂. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO₂ injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO₂ injection directly informs reservoir managers about CO₂ storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be usedmore » directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.« less

  19. Pre-injection brine production for managing pressure in compartmentalized CO₂ storage reservoirs

    SciTech Connect (OSTI)

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO₂ storage that combines CO₂ injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO₂. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO₂ injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO₂ injection directly informs reservoir managers about CO₂ storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be used directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.

  20. Simulation and economic evaluation of a solar evaporation system for concentrating sodium chloride brines

    SciTech Connect (OSTI)

    Smith, M.K.; Newell, T.A. )

    1991-01-01

    An hourly simulation program has been developed for detailed modelin of an evaporation surface (ES) and an evaporation pond (EP) for reconcentration of a solar pond's (SP's) surface brine. The results are relavant to other systems in which it is desirable to concentrate a brine. The simulation results are used in three ways: first, for general comparison of brine reconcentration performance for a variety of locations; second, development of an ES design method based on long term monthly averaged weather data; and third, an economic comparison between ESs and EPs. The results show that regions with moderate to high precipitation favor ESs over EPs. Dry climates will generally favor EPs for brine reconcentration.

  1. Community Geothermal Technology Program: Electrodeposition of minerals in geothermal brine

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    Objective was to study the materials electrodeposited from geothermal brine, from the HGP-A well in Puna, Hawaii. Due to limitations, only one good set of electrodeposited material was obtained; crystallography indicates that vaterite forms first, followed by calcite and then perhaps aragonite as current density is increased. While the cost to weight ratio is reasonable, the deposition rate is very slow. More research is needed, such as reducing the brittleness. The electrodeposited material possibly could be used as building blocks, tables, benches, etc. 49 figs, 4 tabs, 7 refs.

  2. Chemical-equilibrium calculations for aqueous geothermal brines

    SciTech Connect (OSTI)

    Kerrisk, J.F.

    1981-05-01

    Results from four chemical-equilibrium computer programs, REDEQL.EPAK, GEOCHEM, WATEQF, and SENECA2, have been compared with experimental solubility data for some simple systems of interest with geothermal brines. Seven test cases involving solubilities of CaCO/sub 3/, amorphous SiO/sub 2/, CaSO/sub 4/, and BaSO/sub 4/ at various temperatures from 25 to 300/sup 0/C and in NaCl or HCl solutions of 0 to 4 molal have been examined. Significant differences between calculated results and experimental data occurred in some cases. These differences were traced to inaccuracies in free-energy or equilibrium-constant data and in activity coefficients used by the programs. Although currently available chemical-equilibrium programs can give reasonable results for these calculations, considerable care must be taken in the selection of free-energy data and methods of calculating activity coefficients.

  3. Brine-in-crude-oil emulsions at the Strategic Petroleum Reserve.

    SciTech Connect (OSTI)

    Nemer, Martin B.; Lord, David L.; MacDonald, Terry L.

    2013-10-01

    Metastable water-in-crude-oil emulsion formation could occur in a Strategic Petroleum Reserve (SPR) cavern if water were to flow into the crude-oil layer at a sufficient rate. Such a situation could arise during a drawdown from a cavern with a broken-hanging brine string. A high asphaltene content (> 1.5 wt %) of the crude oil provides the strongest predictor of whether a metastable water-in-crude-oil emulsion will form. However there are many crude oils with an asphaltene content > 1.5 wt % that don't form stable emulsions, but few with a low asphaltene content that do form stable emulsions. Most of the oils that form stable emulsions are %E2%80%9Csour%E2%80%9D by SPR standards indicating they contain total sulfur > 0.50 wt %.

  4. Calculation of brine properties. [Above 80/sup 0/F and for salt...

    Office of Scientific and Technical Information (OSTI)

    Brine saturation pressure is calculated as a percentage of the pure water saturation ... temperature and pressure and are obtained from the ASME equation-of-state for pure water. ...

  5. Study of thermal-gradient-induced migration of brine inclusions in salt. Final report

    SciTech Connect (OSTI)

    Olander, D.R.

    1984-08-01

    Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed.

  6. Recovery of energy from geothermal brine and other hot water sources

    DOE Patents [OSTI]

    Wahl, III, Edward F.; Boucher, Frederic B.

    1981-01-01

    Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g. with respect to the design of such plates, number of plates employed, spacing between plates, area thereof, column diameter, and the like, are designed to achieve maximum throughput of brine or hot water and reduction in temperature differential at the respective stages or plates between the brine or hot water and the working fluid, and so minimize lost work and maximize efficiency, and minimize scale deposition from hot water containing fluid including salts, such as brine. Maximum throughput approximates minimum cost of electricity which can be produced by conversion of the recovered thermal energy to electrical energy.

  7. West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume III. Biological oceanography. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J.

    1983-02-01

    The Department of Energy's Strategic Petroleum Reserve Program began discharging brine into the Gulf of Mexico from its West Hackberry site near Cameron, Louisiana in May 1981. The brine originates from underground salt domes being leached with water from the Intracoastal Waterway, making available vast underground storage caverns for crude oil. The effects of brine discharge on aquatic organisms are presented in this volume. The topics covered are: benthos; nekton; phytoplankton; zooplankton; and data management.

  8. Behavior of natural uranium, thorium, and radium isotopes in the Wolfcamp brine aquifers, Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1984-10-01

    Previously reported results for Palo Duro deep brines show that Ra is highly soluble and not retarded. Relative to Ra, U and Th are highly sorbed. Uranium, like thorium, is in the +4 valence state, indicating a reducing environment. Additional data reported here support these results. However, one Wolfcamp brine sample gives somewhat different results. Radium appears to be somewhat sorbed. Uranium is largely in the +6 valence state, indicating a less reducing condition. In all brines, kinetics for sorption (/sup 228/Th) and desorption (/sup 224/Ra) are rapid. This Wolfcamp brine was tested for the effects of colloids for Ra, U, and Th concentrations. No effects were found.

  9. Summary Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    The report summarizes laboratory and field observations and numerical modeling related to coupledprocesses involving brine and vapor migration in geologic salt, focusing on recent developments and...

  10. Silica separation from reinjection brines at Monte Amiata geothermal plants, Italy

    SciTech Connect (OSTI)

    Vitolo, S.; Cialdella, M.L. . Dipartimento di Ingegneria Chimica)

    1994-06-01

    A process for the separation of silica from geothermal reinjection brines is reported, in which the phases of coagulation, sedimentation and filtration of silica are involved. The effectiveness of lime and calcium chloride as coagulating agents has been investigated and the separating operations have been set out. Attention has been focused on Monte Amiata reinjection geothermal brines, whose scaling effect causes serious problems in the operation and maintenance of reinjection facilities. The study has been conducted using different amounts of added coagulants and at different temperatures, to determine optimal operating conditions. Though calcium chloride was revealed to be effective as a coagulant of the polymeric silica fraction, lime has also proved capable of removing monomeric dissolved silica at high dosages. Investigation on the behavior of coagulated brine has revealed the feasibility of separating the coagulated silica by sedimentation and filtration.

  11. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT STABILIZED BASIN 43 GROUNDWATER BRINE

    SciTech Connect (OSTI)

    COOKE GA; DUNCAN JB; LOCKREM LL

    2008-09-30

    This report is an initial report on the laboratory effort executed under RPP-PLAN-33338, Test Plan for the Assessment of Technetium Leachability in Cement-Stabilized Basin 43 Groundwater Brine. This report delineates preliminary data obtained under subcontract 21065, release 30, from the RJ Lee Group, Inc., Center for Laboratory Sciences. The report is predicated on CLS RPT-816, Draft Report: Assessment of Technetium Leachability in Cement Stabilized Basin 43 Groundwater Brine. This document will be revised on receipt of the final RJ Lee Group, Inc., Center for Laboratory Sciences report, which will contain data subjected to quality control and quality assurance criteria.

  12. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  13. Brine flow up a borehole caused by pressure perturbation from CO2 storage: Static and dynamic evaluations

    SciTech Connect (OSTI)

    Birkholzer, J.T.; Nicot, J.-P.; Oldenburg, C.M.; Zhou, Q.; Kraemer, S.; Bandilla, K.W.

    2011-05-01

    Industrial-scale storage of CO{sub 2} in saline sedimentary basins will cause zones of elevated pressure, larger than the CO{sub 2} plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards along these conduits and mix with groundwater resources. This paper discusses the potential for such brine leakage to occur in temperature- and salinity-stratified systems. Using static mass-balance calculations as well as dynamic well flow simulations, we evaluate the minimum reservoir pressure that would generate continuous migration of brine up a leaking wellbore into a freshwater aquifer. Since the brine invading the well is denser than the initial fluid in the wellbore, continuous flow only occurs if the pressure perturbation in the reservoir is large enough to overcome the increased fluid column weight after full invasion of brine into the well. If the threshold pressure is exceeded, brine flow rates are dependent on various hydraulic (and other) properties, in particular the effective permeability of the wellbore and the magnitude of pressure increase. If brine flow occurs outside of the well casing, e.g., in a permeable fracture zone between the well cement and the formation, the fluid/solute transfer between the migrating fluid and the surrounding rock units can strongly retard brine flow. At the same time, the threshold pressure for continuous flow to occur decreases compared to a case with no fluid/solute transfer.

  14. Performance of CRA in concentrated brines at 130 to 180 C -- Effect of H{sub 2}S, elemental sulfur and brine composition

    SciTech Connect (OSTI)

    Schmitt, G.; Pankoke, U.; Klemp, G.; Bruckhoff, W.; Siegmund, G.

    1997-08-01

    Failure analysis of localized corrosion at 28Cr32Ni (Alloy 28) tubing in a sour gas well prompted systematic investigations on the performance of relevant corrosion resistant alloys (CRA) in synthetic high salinity brines at high H{sub 2}S partial pressures in the absence and presence of elemental sulfur at 130 to 180 C. The CRAs included superaustenitic steels, nickel and nickel-cobalt base alloys and titanium alloys. CRAs with pitting resistance equivalents (PRE) of 39 and lower (including 28Cr32Ni) suffered in unbuffered brines from pitting and crevice corrosion already at 130 C. Alloy C276 and Ti Beta-C alloys proved complete resistance in all media tested up to 180 C. The effect of medium composition on CRA performance was studied at 130 C with respect to the presence of elemental sulfur, H{sub 2}S, iron sulfide, and CaCo{sub 3} in NaCl/CaCl{sub 2} brines with a total of 160 g/l chloride.

  15. Shaker Table Experiments with Rare Earth Elements Sorption from Geothermal Brine

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  16. RealGasBrine v1.0 option of TOUGH+ v1.5

    SciTech Connect (OSTI)

    Moridis, George

    2015-02-27

    RealGasBrine v1.0 is a numerical code that for the simulation of the behavior of gas-bearing porous and/fractured geologic media. It is an option of TOUGH+ v1.5 [Moridis, 2014], a successor to the TOUGH2 [Pruess et al., 1999; 2012] family of codes for multi-component, multiphase ?uid and heat ?ow developed at the Lawrence Berkeley National Laboratory. RealGasBrine v1.0 needs the TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRAN 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. RealGasBrine v1.0 describes the non-isothermal two- (for pure water) or three-phase (for brine) flow of an aqueous phase and a real gas mixture in a gas-bearing medium, with a particular focus in ultra-tight (such as tight-sand and shale gas) systems. Up to 12 individual real gases can be tracked, and salt can precipitate as solid halite. The capabilities of the code include coupled flow and thermal effects, real gas behavior, Darcy and non-Darcy flow, several isotherm options of gas sorption onto the grains of the porous media, complex fracture descriptions, gas solubility into water, and geomechanical effects on flow properties. RealGasBrine v1.0 allows the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in any problem involving the flow of gases in geologic media, including the geologic storage of greenhouse gas mixtures, the behavior of geothermal reservoirs with multi-component condensable (H2O and CO2) and non-condensable gas mixtures, the transport of water and released H2 in nuclear waste storage applications, etc.

  17. Disposal/recovery options for brine waters from oil and gas production in New York State. Final report

    SciTech Connect (OSTI)

    Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

    1996-03-01

    Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated.

  18. Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration

    SciTech Connect (OSTI)

    Goddard, William

    2012-11-30

    To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

  19. West Hackberry Brine Disposal Project pre-discharge characterization. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.

    1982-01-01

    The physical, chemical and biological attributes are described for: (1) a coastal marine environment centered about a Department of Energy Strategic Petroleum Reserve (SPR) brine disposal site 11.4 km off the southwest coast of Louisiana; and (2) the lower Calcasieu and Sabine estuarine systems that provide leach waters for the SPR project. A three month sampling effort, February through April 1981, and previous investigations from the study area are integrated to establish baseline information for evaluation of impacts from brine disposal in the nearshore marine waters and from freshwater withdrawal from the coastal marsh of the Chenier Plain. January data are included for some tasks that sampled while testing and mobilizing their instruments prior to the February field effort. The study addresses the areas of physical oceanography, estuarine hydrology and hydrography, water and sediment quality, benthos, nekton, phytoplankton, zooplankton, and data management.

  20. Comparison of selected oil-field brines from fields in the Permian basin, West Texas-southeast New Mexico

    SciTech Connect (OSTI)

    White, H.G. III

    1992-04-01

    Stiff diagrams of oil-field brines from the west Texas Permian basin are identifiable within the geological framework. Plotted from a simple analysis of three cations and three anions, older Paleozoic waters can be categorized as either 'pristine' or modified, usually by a later influx of Permian or early Pennsylvanian water. These different plots can be segregated by geologic province. The Permian brines differ by age and also by environment (shelf, basin, etc.).

  1. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  2. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extractionmore » control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing ‘Area of Review’, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.« less

  3. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

  4. Ground-water hydraulics of the deep-basin brine aquifer, Palo Duro Basin, Texas panhandle

    SciTech Connect (OSTI)

    Smith, D.A.

    1985-01-01

    The Deep-Basin Brine aquifer of the Palo Duro Basin (Texas Panhandle) underlies thick Permian bedded evaporites that are being evaluated as a potential high-level nuclear waste isolation repository. Potentiometric surface maps of 5 units of the Deep-Basin Brine aquifer were drawn using drill-stem test (DST) pressure data, which were analyzed by a geostatistical technique (kriging) to smooth the large variation in the data. The potentiometric surface maps indicate that the Deep-Basin Brine aquifer could be conceptually modeled as 5 aquifer units; a Lower Permian (Wolfcamp) aquifer, upper and lower Pennsylvanian aquifers, a pre-Pennsylvanian aquifer, and a Pennsylvanian to Wolfcampian granite-wash aquifer. The hydraulic head maps indicate that ground-water flow in each of the units is west to east with a minor northerly component near the Amarillo Uplift, the northern structural boundary of the basin. The Wolfcamp potentiometric surface indicates the strongest component of northerly flow. Inferred flow direction in Pennsylvanian aquifers is easterly, and in the pre-Pennsylvanian aquifer near its pinch-out in the basin center, flow is inferred to be to the north. In the granite-wash aquifer the inferred flow direction is east across the northern edge of the basin and southeast along the Amarillo Uplift.

  5. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    SciTech Connect (OSTI)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at a proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ

  6. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore » proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir

  7. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect (OSTI)

    David B. Burnett

    2005-09-29

    This study is developing a comprehensive study of what is involved in the desalination of oil field produced brine and the technical developments and regulatory changes needed to make the concept a commercial reality. It was originally based on ''conventional'' produced water treatment and reviewed (1) the basics of produced water management, (2) the potential for desalination of produced brine in order to make the resource more useful and available in areas of limited fresh water availability, and (3) the potential beneficial uses of produced water for other than oil production operations. Since we have begun however, a new area of interest has appeared that of brine water treatment at the well site. Details are discussed in this technical progress report. One way to reduce the impact of O&G operations is to treat produced brine by desalination. The main body of the report contains information showing where oil field brine is produced, its composition, and the volume available for treatment and desalination. This collection of information all relates to what the oil and gas industry refers to as ''produced water management''. It is a critical issue for the industry as produced water accounts for more than 80% of all the byproducts produced in oil and gas exploration and production. The expense of handling unwanted waste fluids draws scarce capital away for the development of new petroleum resources, decreases the economic lifetimes of existing oil and gas reservoirs, and makes environmental compliance more expensive to achieve. More than 200 million barrels of produced water are generated worldwide each day; this adds up to more than 75 billion barrels per year. For the United States, the American Petroleum Institute estimated about 18 billion barrels per year were generated from onshore wells in 1995, and similar volumes are generated today. Offshore wells in the United States generate several hundred million barrels of produced water per year. Internationally

  8. RealGasBrine v1.0 option of TOUGH+ v1.5

    Energy Science and Technology Software Center (OSTI)

    2015-02-27

    RealGasBrine v1.0 is a numerical code that for the simulation of the behavior of gas-bearing porous and/fractured geologic media. It is an option of TOUGH+ v1.5 [Moridis, 2014], a successor to the TOUGH2 [Pruess et al., 1999; 2012] family of codes for multi-component, multiphase ?uid and heat ?ow developed at the Lawrence Berkeley National Laboratory. RealGasBrine v1.0 needs the TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRANmore » 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. RealGasBrine v1.0 describes the non-isothermal two- (for pure water) or three-phase (for brine) flow of an aqueous phase and a real gas mixture in a gas-bearing medium, with a particular focus in ultra-tight (such as tight-sand and shale gas) systems. Up to 12 individual real gases can be tracked, and salt can precipitate as solid halite. The capabilities of the code include coupled flow and thermal effects, real gas behavior, Darcy and non-Darcy flow, several isotherm options of gas sorption onto the grains of the porous media, complex fracture descriptions, gas solubility into water, and geomechanical effects on flow properties. RealGasBrine v1.0 allows the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in any problem involving the flow of gases in geologic media, including the geologic storage of greenhouse gas mixtures, the behavior of geothermal reservoirs with multi-component condensable (H2O and CO2) and non-condensable gas mixtures, the transport of water and released H2 in nuclear waste storage applications, etc.« less

  9. PILOT TESTING: PRETREATMENT OPTIONS TO ALLOW RE-USE OF FRAC FLOWBACK AND PRODUCED BRINE FOR GAS SHALE RESOURCE DEVELOPMENT

    SciTech Connect (OSTI)

    Burnett, David

    2012-12-31

    The goal of the A&M DOE NETL Project No. DE-FE0000847 was to develop a mobile, multifunctional water treatment capability designed specifically for “pre-treatment” of field waste brine. The project consisted of constructing s mobile “field laboratory” incorporating new technology for treating high salinity produced water and using the lab to conduct a side-by-side comparison between this new technology and that already existing in field operations. A series of four field trials were performed utilizing the mobile unit to demonstrate the effectiveness of different technology suitable for use with high salinity flow back brines and produced water. The design of the mobile unit was based on previous and current work at the Texas A&M Separation Sciences Pilot Plant. The several treatment techniques which have been found to be successful in both pilot plant and field tests had been tested to incorporate into a single multifunctional process train. Eight different components were evaluated during the trials, two types of oil and grease removal, one BTEX removal step, three micro-filters, and two different nanofilters. The performance of each technique was measured by its separation efficiency, power consumption, and ability to withstand fouling. The field trials were a success. Four different field brines were evaluated in the first trial in New York. Over 16,000 gallons of brine were processed. Using a power cost of $.10 per kWh, media pretreatment power use averaged $0.004 per barrel, solids removal $.04 per barrel and brine “softening” $.84 per barrel. Total power cost was approximately $1.00 per barrel of fluid treated. In Pennsylvania, brines collected from frac ponds were tested in two additional trials. Each of the brines was converted to an oil-free, solids-free brine with no biological activity. Brines were stable over time and would be good candidates for use as a make-up fluid in a subsequent fracturing fluid design. Reports on all of the field

  10. Geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro basin, Texas

    SciTech Connect (OSTI)

    Langmuir, D.; Melchior, D.

    1985-11-01

    The geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro Basin of north Texas, was studied to define geochemical controls on radionuclides such as /sup 90/Sr and /sup 226/Ra. Published solubility data for gypsum, anhydrite, celestite, barite and RaSO/sub 4/ were first reevaluated, in most cases using the ion interaction approach of Pitzer, to determine solubility products of the sulfates as a function of temperature and pressure. Ionic strengths of the brines were from 2.9 to 4.8 m, their temperatures and pressures up to 40/sup 0/C and 130 bars. Saturation indices of the sulfates were computed with the ion-interaction approach in one brine from the arkosic granite wash facies and four from the carbonate Wolfcamp Formation. All five brines are saturated with respect to gypsum, anhydrite and celestite, and three of the five with respect to barite. All are undersaturated by from 5 to 6 orders of magnitude with respect to pure RaSO/sub 4/. /sup 226/Ra concentrations in the brines, which ranged from 10/sup -11.3/ to 10/sup -12.7/ m, are not controlled by RaSO/sub 4/ solubility or adsorption, but possibly by the solubility of trace Ra solid solutions in sulfates including celestite and barite.

  11. The sup 36 Cl ages of the brines in the Magadi-Natron basin, east Africa

    SciTech Connect (OSTI)

    Kaufman, A.; Margaritz, M.A.; Hollos, G. ); Paul, M.; Boaretto, E. ); Hillaire-Marcel, C. ); Taieb, M. )

    1990-10-01

    The depression in the East African Rift which includes both Lake Magadi and Lake Natron forms a closed basin within which almost all the dissolved chloride originates in precipitation, since there is no important source of very ancient sedimentary chloride. This provides an ideal setting for the evaluation of the {sup 36}Cl methodology as a geochemical and hydrological tracer. The main source of recent water, as represented by the most dilute samples measured, is characterized by a {sup 36}Cl/Cl ratio of 2.5 {times} 10{sup {minus}14}, in agreement with the calculated value expected in precipitation. Surface evaporation increases the chlorinity of the local freshwater inflow by about a factor of 110 without changing the isotopic ratio, indicating that little chloride enters the system in the form of sediment leachate. A second type of brine found in the basin occurs in a hot deep groundwater reservoir and is characterized by lower {sup 36}Cl/Cl ratios (<1.2 {times} 10{sup {minus}14}). By comparing this value with the 2.5 {times} 10{sup {minus}14} in recent recharge, one obtains an approximate salt accumulation age of 760 Ka which is consistent with thee time of the first appearance of the lake. These older brines also have lower {sup 18}O and {sup 2}H values which indicate that they were recharged during a climatically different era. The {sup 36}Cl/Cl ratios in the inflowing waters and in the accumulated brine, together with the known age of the Lake Magadi basin, may be used to estimate the importance of the hypogene and epigene, as opposed to the meteoric, mode of {sup 36}Cl production. Such a calculation shows that the hypogene and epigene processes together contribute less than 6% of the total {sup 36}Cl present in the lake.

  12. Brine migration test for Asse Mine, Federal Republic of Germany: final test plan

    SciTech Connect (OSTI)

    Not Available

    1983-07-01

    The United States and the Federal Republic of Germany (FRG) will conduct a brine migration test in the Asse Salt Mine in the FRG as part of the US/FRG Cooperative Radioactive Waste Management Agreement. Two sets of two tests each will be conducted to study both liquid inclusion migration and vapor migration in the two salt types chosen for the experiments: (1) pure salt, for its characteristics similar to the salt that might occur in potential US repositories, and (2) transitional salt, for its similarity to the salt that might occur in potential repositories in Germany.

  13. Advanced biochemical processes for geothermal brines FY 1998 annual operating plan

    SciTech Connect (OSTI)

    1997-10-01

    As part of the overall Geothermal Energy Research which is aimed at the development of economical geothermal resources production systems, the aim of the Advanced Biochemical Processes for Geothermal Brines (ABPGB) effort is the development of economic and environmentally acceptable methods for disposal of geothermal wastes and conversion of by-products to useful forms. Methods are being developed for dissolution, separation and immobilization of geothermal wastes suitable for disposal, usable in inert construction materials, suitable for reinjection into the reservoir formation, or used for recovery of valuable metals.

  14. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  15. Fluid sampling and chemical modeling of geopressured brines containing methane. Final report, March 1980-February 1981

    SciTech Connect (OSTI)

    Dudak, B.; Galbraith, R.; Hansen, L.; Sverjensky, D.; Weres, O.

    1982-07-01

    The development of a flowthrough sampler capable of obtaining fluid samples from geopressured wells at temperatures up to 400/sup 0/F and pressures up to 20,000 psi is described. The sampler has been designed, fabricated from MP35N alloy, laboratory tested, and used to obtain fluid samples from a geothermal well at The Geysers, California. However, it has not yet been used in a geopressured well. The design features, test results, and operation of this device are described. Alternative sampler designs are also discussed. Another activity was to review the chemistry and geochemistry of geopressured brines and reservoirs, and to evaluate the utility of available computer codes for modeling the chemistry of geopressured brines. The thermodynamic data bases for such codes are usually the limiting factor in their application to geopressured systems, but it was concluded that existing codes can be updated with reasonable effort and can usefully explain and predict the chemical characteristics of geopressured systems, given suitable input data.

  16. Sensitivity study of CO2 storage capacity in brine aquifers withclosed boundaries: Dependence on hydrogeologic properties

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Rutqvist, J.; Tsang, C-F.

    2007-02-07

    In large-scale geologic storage projects, the injected volumes of CO{sub 2} will displace huge volumes of native brine. If the designated storage formation is a closed system, e.g., a geologic unit that is compartmentalized by (almost) impermeable sealing units and/or sealing faults, the native brine cannot (easily) escape from the target reservoir. Thus the amount of supercritical CO{sub 2} that can be stored in such a system depends ultimately on how much pore space can be made available for the added fluid owing to the compressibility of the pore structure and the fluids. To evaluate storage capacity in such closed systems, we have conducted a modeling study simulating CO{sub 2} injection into idealized deep saline aquifers that have no (or limited) interaction with overlying, underlying, and/or adjacent units. Our focus is to evaluate the storage capacity of closed systems as a function of various reservoir parameters, hydraulic properties, compressibilities, depth, boundaries, etc. Accounting for multi-phase flow effects including dissolution of CO{sub 2} in numerical simulations, the goal is to develop simple analytical expressions that provide estimates for storage capacity and pressure buildup in such closed systems.

  17. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect (OSTI)

    David B. Burnett

    2004-09-29

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  18. Summary Results for Brine Migration Modeling Performed by LANL LBNL and SNL for the UFD Program.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L

    2014-09-01

    This report summarizes laboratory and field observations and numerical modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies conducted at Sandia, Los Alamos, and Berkeley National Laboratories. Interest into the disposal of heat-generating waste in salt has led to interest into water distribution and migration in both run-of-mine crushed and intact geologic salt. Ideally a fully coupled thermal-hydraulic-mechanical-chemical simulation is performed using numerical models with validated constitutive models and parameters. When mechanical coupling is not available, mechanical effects are prescribed in hydraulic models as source, boundary, or initial conditions. This report presents material associated with developing appropriate initial conditions for a non-mechanical hydrologic simulation of brine migration in salt. Due to the strong coupling between the mechanical and hydrologic problems, the initial saturation will be low for the excavation disturbed zone surrounding the excavation. Although most of the material in this report is not new, the author hopes it is presented in a format making it useful to other salt researchers.

  19. Brine migration test report: Asse Salt Mine, Federal Republic of Germany: Technical report

    SciTech Connect (OSTI)

    Coyle, A.J.; Eckert, J.; Kalia, H.

    1987-01-01

    This report presents a summary of Brine Migration Tests which were undertaken at the Asse mine of the Federal Republic of Germany (FRG) under a bilateral US/FRG agreement. This experiment simulates a nuclear waste repository at the 800-m (2624-ft) level of the Asse salt mine in the Federal Republic of Germany. This report describes the Asse salt mine, the test equipment, and the pretest properties of the salt in the mine and in the vicinity of the test area. Also included are selected test data (for the first 28 months of operation) on the following: brine migration rates, thermomechaical behavior of the salt (including room closure, stress reading, and thermal profiles), borehole gas pressures, and borehole gas analyses. In addition to field data, laboratory analyses of pretest salt properties are included in this report. The operational phase of these experiments was completed on October 4, 1985, with the commencement of cooldown and the start of posttest activities. 7 refs., 68 figs., 48 tabs.

  20. Modeling Coupled THMC Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco Martin, Laura; Mukhopadhyay, Sumit; Houseworth, Jim; Birkholzer, Jens

    2014-08-14

    In this report, we present FY2014 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. LBNL’s work on the modeling of coupled THMC processes in salt was initiated in FY2012, focusing on exploring and demonstrating the capabilities of an existing LBNL modeling tool (TOUGH-FLAC) for simulating temperature-driven coupled flow and geomechanical processes in salt. This work includes development related to, and implementation of, essential capabilities, as well as testing the model against relevant information and published experimental data related to the fate and transport of water. we provide more details on the FY2014 work, first presenting updated tools and improvements made to the TOUGH-FLAC simulator, and the use of this updated tool in a new model simulation of long-term THM behavior within a generic repository in a salt formation. This is followed by the description of current benchmarking and validations efforts, including the TSDE experiment. We then present the current status in the development of constitutive relationships and the dual-continuum model for brine migration. We conclude with an outlook for FY2015, which will be much focused on model validation against field experiments and on the use of the model for the design studies related to a proposed heater experiment.

  1. Evaluation of materials for systems using cooled, treated geothermal or high-saline brines

    SciTech Connect (OSTI)

    Suciu, D.F.; Wikoff, P.M.

    1982-09-01

    Lack of adequate quantities of clean surface water for use in wet (evaporative) cooling systems indicates the use of high-salinity waste waters, or cooled geothermal brines, for makeup purposes. High-chloride, aerated water represents an extremely corrosive environment. In order to determine metals suitable for use in such an environment, metal coupons were exposed to aerated, treated geothermal brine salted to a chloride concentration of 10,000 and 50,000 ppM (mg/L) for periods of up to 30 days. The exposed coupons were evaluated to determine the general, pitting, and crevice corrosion characteristics of the metals. The metals exhibiting corrosion resistance at 50,000 ppM chloride were then evaluated at 100,000 and 200,000 ppM chloride. Since these were screening tests to select materials for components to be used in a cooling system, with primary emphasis on condenser tubing, several materials were exposed for 4 to 10 months in pilot cooling tower test units with heat transfer for further corrosion evaluation. The results of the screening tests indicate that ferritic stainless steels (29-4-2 and SEA-CURE) exhibit excellent corrosion resistance at all levels of chloride concentration. Copper-nickel alloys (70/30 and Monel 400) exhibited excellent corrosion resistance in the high-saline water. The 70/30 copper-nickel alloy, which showed excellent resistance to general corrosion, exhibited mild pitting in the 30-day tests. This pitting was not apparent, however, after 6 months of exposure in the pilot cooling tower tests. The nickel-base alloys exhibited excellent corrosion resistance, but their high cost prevents their use unless no other material is found feasible. Other materials tested, although unsuitable for condenser tubing material, would be suitable as tube sheet material.

  2. Reduced order models for prediction of groundwater quality impacts from CO₂ and brine leakage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO₂ storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO₂ and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO₂ leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highlymore » efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO₂ and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO₂ storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO₂ storage projects.« less

  3. Reduced order models for prediction of groundwater quality impacts from CO? and brine leakage

    SciTech Connect (OSTI)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO? storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO? and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO? leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highly efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO? and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO? storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO? storage projects.

  4. REE Sorption Study on sieved -50 +100 mesh fraction of Media #1 in Brine #1 with Different Starting pH's at 70C

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gary Garland

    2015-09-29

    This is a continuation of the REE sorption study for shaker bath tests on 2g media #1 in 150mL brine #1 with different starting pH's at 70C. In a previous submission we reported data for shaker bath tests for brine #1 with starting pH's of 3.5, 4.5 and 5.5. In this submission we these pH's compared to starting brine #1 pH's of 6, and 7.

  5. Radioactive waste isolation in salt: geochemistry of brine in rock salt in temperature gradients and gamma-radiation fields - a selective annotated bibliography

    SciTech Connect (OSTI)

    Hull, A.B.; Williams, L.B.

    1985-07-01

    Evaluation of the extensive research concerning brine geochemistry and transport is critically important to successful exploitation of a salt formation for isolating high-level radioactive waste. This annotated bibliography has been compiled from documents considered to provide classic background material on the interactions between brine and rock salt, as well as the most important results from more recent research. Each summary elucidates the information or data most pertinent to situations encountered in siting, constructing, and operating a mined repository in salt for high-level radioactive waste. The research topics covered include the basic geology, depositional environment, mineralogy, and structure of evaporite and domal salts, as well as fluid inclusions, brine chemistry, thermal and gamma-radiation effects, radionuclide migration, and thermodynamic properties of salts and brines. 4 figs., 6 tabs.

  6. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    SciTech Connect (OSTI)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additional wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in

  7. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additionalmore » wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7

  8. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    SciTech Connect (OSTI)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extraction control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing Area of Review, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.

  9. Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report

    SciTech Connect (OSTI)

    Alicia M. Wilson

    2009-11-30

    Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

  10. Evaluation of brine disposal from the Bryan Mound site of the strategic petroleum reserve program. Final report

    SciTech Connect (OSTI)

    Case, Robert J.; Chittenden, Jr, Mark E.; Harper, Jr, Donald E.; Kelly, Jr, Francis J.; Loeblich, Laurel A.; McKinney, Larry D.; Minello, Thomas J.; Park, E. Taisoo; Randall, Robert E.; Slowey, J. Frank

    1981-01-01

    On March 10, 1980, the Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging the resulting brine into the coastal waters off Freeport, Texas. During the months of March and April, a team of scientists and engineers from Texas A and M University conducted an intensive environmental study of the area surrounding the diffuser site. A pipeline has been laid from the Bryan Mound site to a location 12.5 statute miles (20 km) offshore. The last 3060 ft (933 m) of this pipeline is a 52-port diffuser through which brine can be discharged at a maximum rate of 680,000 barrels per day. Initially, 16 ports were open which permitted a maximum discharge rate of 350,000 barrels per day and a continuous brine discharge was achieved on March 13, 1980. The purpose of this report is to describe the findings of the project team during the intensive postdisposal study period of March and April, 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management.

  11. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    SciTech Connect (OSTI)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution features including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.

  12. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    SciTech Connect (OSTI)

    David B. Burnett; Mustafa Siddiqui

    2006-12-29

    Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes for the

  13. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution featuresmore » including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.« less

  14. Evaluation of brine disposal from the Bryan Mound site of the Strategic Petroleum Reserve Program. Final report

    SciTech Connect (OSTI)

    Hann, R.W. Jr.; Randall, R.E.

    1980-12-01

    The purpose of this report is to describe the environmental conditions found by the principal investigators during the predisposal study conducted from September 1977 through February 1980 prior to the start of brine discharge in March 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management. Volume 1 describes the results of the predisposal study, and it is divided into eight chapters entitled: Physical Oceanography, Analysis of the Discharge Plume, Water and Sediment Quality, Nekton, Benthos, Zooplankton, Phytoplankton, and Data Management. Volume 2 consists of appendices which contain additional supporting data in the form of figures and tables.

  15. The implications of UIC and NPDES regulations on selection of disposal options for spent geothermal brine

    SciTech Connect (OSTI)

    1982-07-01

    This document reviews and evaluates the various options for the disposal of geothermal wastewater with respect to the promulgated regulations for the protection of surface and groundwaters. The Clean Water Act of 1977 and the Safe Drinking Water Act Amendments are especially important when designing disposal systems for geothermal fluids. The former promulgates regulations concerning the discharge of wastewater into surface waters, while the latter is concerned with the protection of ground water aquifers through the establishment of underground injection control (UIC) programs. There is a specific category for geothermal fluid discharge if injection is to be used as a method of disposal. Prior to February 1982, the UIC regulations required geothermal power plant to use Class III wells and direct use plants to use Class V wells. More stringent regulatory requirements, including construction specification and monitoring, are imposed on the Class III wells. On February 3, 1982, the classification of geothermal injection wells was changed from a Class III to Class V on the basis that geothermal wells do not inject for the extraction of minerals or energy, but rather they are used to inject brines, from which heat has been extracted, into formations from which they were originally taken. This reclassification implies that a substantial cost reduction will be realized for geothermal fluid injection primarily because well monitoring is no longer mandatory. The Clean Water Act of 1977 provides the legal basis for regulating the discharge of liquid effluent into the nation's surface waters, through a permitting system called the National Pollution Discharge Elimination System (NPDES) Discharge quantities, rates, concentrations and temperatures are regulated by the NPDES permits. These permits systems are based upon effluent guidelines developed by EPA on an industry by industry basis. For geothermal energy industry, effluent guidelines have not been formulated and are not

  16. Modifications of Carbonate Fracture Hydrodynamic Properties by CO{sub 2}-Acidified Brine Flow

    SciTech Connect (OSTI)

    Deng, Hang; Ellis, Brian R.; Peters, Catherine A.; Fitts, Jeffrey P.; Crandall, Dustin; Bromhal, Grant S.

    2013-08-01

    Acidic reactive flow in fractures is relevant in subsurface activities such as CO{sub 2} geological storage and hydraulic fracturing. Understanding reaction-induced changes in fracture hydrodynamic properties is essential for predicting subsurface flows such as leakage, injectability, and fluid production. In this study, x-ray computed tomography scans of a fractured carbonate caprock were used to create three dimensional reconstructions of the fracture before and after reaction with CO{sub 2}-acidified brine (Ellis et al., 2011, Greenhouse Gases: Sci. Technol., 1:248-260). As expected, mechanical apertures were found to increase substantially, doubling and even tripling in some places. However, the surface geometry evolved in complex ways including ‘comb-tooth’ structures created from preferential dissolution of calcite in transverse sedimentary bands, and the creation of degraded zones, i.e. porous calcite-depleted areas on reacted fracture surfaces. These geometric alterations resulted in increased fracture roughness, as measured by surface Z{sub 2} parameters and fractal dimensions D{sub f}. Computational fluid dynamics (CFD) simulations were conducted to quantify the changes in hydraulic aperture, fracture transmissivity and permeability. The results show that the effective hydraulic apertures are smaller than the mechanical apertures, and the changes in hydraulic apertures are nonlinear. Overestimation of flow rate by a factor of two or more would be introduced if fracture hydrodynamic properties were based on mechanical apertures, or if hydraulic aperture is assumed to change proportionally with mechanical aperture. The differences can be attributed, in part, to the increase in roughness after reaction, and is likely affected by contiguous transverse sedimentary features. Hydraulic apertures estimated by the 1D statistical model and 2D local cubic law (LCL) model are consistently larger than those calculated from the CFD simulations. In addition, a novel

  17. GEOCHEMICAL INVESTIGATIONS OF CO₂-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO₂ injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO₂ and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  18. Evaporite Caprock Integrity. An experimental study of reactive mineralogy and pore-scale heterogeneity during brine-CO2 exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Sholokhova, Yelena; Hao, Yue; Carroll, Susan A.

    2012-07-25

    Characterization and geochemical data are presented from a core-flooding experiment on a sample from the Three Fingers evaporite unit forming the lower extent of caprock at the Weyburn-Midale reservoir, Canada. This low-permeability sample was characterized in detail using X-ray computed microtomography before and after exposure to CO 2-acidified brine, allowing mineral phase and voidspace distributions to be quantified in three dimensions. Solution chemistry indicated that CO 2-acidified brine preferentially dissolved dolomite until saturation was attained, while anhydrite remained unreactive. Dolomite dissolution contributed to increases in bulk permeability through the formation of a localized channel, guided by microfractures as well asmore » porosity and reactive phase distributions aligned with depositional bedding. An indirect effect of carbonate mineral reactivity with CO 2-acidified solution is voidspace generation through physical transport of anhydrite freed from the rock matrix following dissolution of dolomite. The development of high permeability fast pathways in this experiment highlights the role of carbonate content and potential fracture orientations in evaporite caprock formations considered for both geologic carbon sequestration and CO 2-enhanced oil recovery operations.« less

  19. Wetting behavior of selected crude oil/brine/rock systems. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Zhou, X.; Morrow, N.R.; Ma, S.

    1996-12-31

    Previous studies of crude oil/brine/rock (COBR) and related ensembles showed that wettability and its effect on oil recovery depend on numerous complex interactions. In the present work, the wettability of COBR ensembles prepared using Prudhoe Bay crude oil, a synthetic formation brine, and Berea Sandstone was varied by systematic change in initial water saturation and length of aging time at reservoir temperature (88 C). All displacement tests were run at ambient temperature. Various degrees of water wetness were achieved and quantified by a modified Amott wettability index to water, the relative pseudo work of imbibition, and a newly defined apparent advancing dynamic contact angle. Pairs of spontaneous imbibition (oil recovery by spontaneous imbibition of water) and waterflood (oil recovery vs. pore volumes of water injected) curves were measured for each of the induced wetting states. Several trends were observed. Imbibition rate, and hence water wetness, decreased with increase in aging time and with decrease in initial water saturation. Breakthrough recoveries and final oil recovery by waterflooding increased with decrease in water wetness. Correlations between water wetness and oil recovery by waterflooding and spontaneous imbibition are presented.

  20. Environmental assessment of the brine pipeline replacement for the Strategic Petroleum Reserve Bryan Mound Facility in Brazoria County, Texas

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0804, for the proposed replacement of a deteriorated brine disposal pipeline from the Strategic Petroleum Reserve (SPR) Bryan Mound storage facility in Brazoria County, Texas, into the Gulf of Mexico. In addition, the ocean discharge outfall would be moved shoreward by locating the brine diffuser at the end of the pipeline 3.5 miles offshore at a minimum depth of 30 feet. The action would occur in a floodplain and wetlands; therefore, a floodplain/wetlands assessment has been prepared in conjunction with this EA. Based on the analyses in the EA, DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969 (42 USC. 4321, et seg.). Therefore, the preparation of an Environmental Impact Statement (EIS) is not required, and the Department is issuing this Finding of No Significant Impact (FONSI). This FONSI also includes a Floodplain Statement of Findings in accordance with 10 CFR Part 1022.

  1. REE Sorption Study for Media #1 and Media #2 in Brine #1 and #2 at different Liquid to Solid Ratio's at Ambient Temperature

    SciTech Connect (OSTI)

    Gary Garland

    2015-03-27

    This data set shows the different loading capacities of Media #1 and Media #2 in a high and low salt content brine matrix at different liquid to solid ratio's. These data sets are shaker bath tests on media #1 and media #2 in brine's #1 and #2 at 500mL-.5g(1000-1 ratio), 150mL-.75g(200-1 ratio), and 150mL-2.5g(60-1 ratio) at ambient temperature.

  2. REE Sorption Study of Sieved -50 +100 mesh Media #1 in Brine #1 with Different Starting pH's at 70C

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  3. Rare-earth elements in hot brines (165 to 190 degree C) from the Salton Sea geothermal field

    SciTech Connect (OSTI)

    Lepel, E.A.; Laul, J.C.; Smith, M.R.

    1988-01-01

    Rare-earth element (REE) concentrations are important indicators for revealing various chemical fractionation processes (water/rock interactions) and source region geochemistry. Since the REE patterns are characteristic of geologic materials (basalt, granite, shale, sediments, etc.) and minerals (K-feldspar, calcite, illite, epidote, etc.), their study in geothermal fluids may serve as a geothermometer. The REE study may also enable us to address the issue of groundwater mixing. In addition, the behavior of the REE can serve as analogs of the actinides in radioactive waste (e.g., neodymium is an analog of americium and curium). In this paper, the authors port the REE data for a Salton Sea Geothermal Field (SSGF) brine (two aliquots: port 4 at 165{degree}C and port 5 at 190{degree}C) and six associated core samples.

  4. Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot

    SciTech Connect (OSTI)

    Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

    2009-11-01

    To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

  5. Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

    SciTech Connect (OSTI)

    Beauheim, R.L. ); Saulnier, G.J. Jr.; Avis, J.D. )

    1991-08-01

    Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

  6. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  7. REE Sorption Study of Seived -50 +100 Mesh Fraction of Media #1 in Brine #1 at Different Concentrations of REE at 70C

    SciTech Connect (OSTI)

    Gary Garland

    2015-06-29

    This dataset shows the sorption capacities of smaller grain size (-50 +100 mesh) of media #1 in brine #1 at different starting concentrations of REE's at elevated temperature of 70C. The experimental conditions are 2g of -50 +100 mesh media #1 to 150mL of REE solution at concentartions of .2ppm each, 2ppm each, and 20ppm each. The pH of the solution is 5.5, and the temperature was at 70C.

  8. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-14

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  9. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    SciTech Connect (OSTI)

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

    2013-04-01

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

  10. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  11. Accident Investigation of the February 7, 2013, Scissor Lift Accident in the West Hackberry Brine Tank-14 Resulting in Injury, Strategic Petroleum Reserve West Hackberry, LA

    Broader source: Energy.gov [DOE]

    On February 15, 2013, an Accident Investigation Board (the Board) was appointed to investigate an accident that resulted in serious injuries caused when a scissor lift tipped over in Brine Tank-14 (WHT-14) at the Strategic Petroleum Reserve, West Hackberry, Louisiana, site on February 7, 2013. The Board’s responsibilities have been completed with respect to this investigation. The analysis and the identification of the direct cause, root causes, contributing causes, and judgments of need resulting from this investigation were performed in accordance with the Department of Energy (DOE) Order 225.1B, Accident Investigations.

  12. Batteries from Brine

    Broader source: Energy.gov [DOE]

    Low-temp geothermal technologies are meeting a growing demand for strategic materials in clean manufacturing.

  13. Estimates of the solubilities of waste element radionuclides in waste isolation pilot plant brines: A report by the expert panel on the source term

    SciTech Connect (OSTI)

    Hobart, D.E.; Bruton, C.J.; Millero, F.J.; Chou, I.M.; Trauth, K.M.; Anderson, D.R.

    1996-05-01

    Evaluation of the long-term performance of the WIPP includes estimation of the cumulative releases of radionuclide elements to the accessible environment. Nonradioactive lead is added because of the large quantity expected in WIPP wastes. To estimate the solubilities of these elements in WIPP brines, the Panel used the following approach. Existing thermodynamic data were used to identify the most likely aqueous species in solution through the construction of aqueous speciation diagrams. Existing thermodynamic data and expert judgment were used to identify potential solubility-limiting solid phases. Thermodynamic data were used to calculate the activities of the radionuclide aqueous species in equilibrium with each solid. Activity coefficients of the radionuclide-bearing aqueous species were estimated using Pitzer`s equations. These activity coefficients were then used to calculate the concentration of each radionuclide at the 0.1 and 0.9 fractiles. The 0.5 fractile was chosen to represent experimental data with activity coefficient corrections as described above. Expert judgment was used to develop the 0.0, 0.25, 0.75, and 1.0 fractiles by considering the sensitivity of solubility to the potential variability in the composition of brine and gas, and the extent of waste contaminants, and extending the probability distributions accordingly. The results were used in the 1991 and 1992 performance assessment calculations. 68 refs.

  14. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-03-31

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite

  15. Numerical modeling of regional ground-water flow in the deep-basin brine aquifer of the Palo Duro Basin, Texas Panhandle

    SciTech Connect (OSTI)

    Wirojanagud, P.; Kreitler, C.W.; Smith, D.A.

    1986-01-01

    Bedded Permian-age evaporite sequences in the Palo Duro Basin are being considered for a permanent nuclear waste repository by the U.S. Department of Energy. The purpose of this modeling study is to provide an understanding of regional ground-water flow in the formations beneath the Permian evaporite section. From this understanding, more detailed, smaller scale studies can be designed. This study is also intended to provide a better understanding of the boundary conditions and permeabilities of the aquifer and aquitard system as well as provide estimates of ground-water travel times across the basin. Numerical simulations were made of the Wolfcamp aquifer modeled as a single layer and of the entire Deep-Basin Brine aquifer system, including the Wolfcamp aquifer, modeled as a single layer.

  16. An objective rapid screening tool for surfactants used in foam-like dispersions of CO{sub 2} into Permian Basin brines

    SciTech Connect (OSTI)

    Horton, R.L.; Wicks, J.P.; Prieditis, J.; Turbeville, J.B.

    1995-11-01

    Foam-like dispersions of CO{sub 2} into brines can reduce the mobility of drive fluids in CO{sub 2} floods. To evaluate the effectiveness of such foam-like dispersions, time-consuming laboratory coreflood tests are routinely used. Because of the costliness of such coreflood tests, simple qualitative tests have long been employed to screen potential surfactants. Then only a few of the better candidates are subsequently evaluated in coreflood tests. There are a number of disadvantages of such qualitative tests; therefore the authors developed, instead, a quantitative screening process. Their quantitative process is based on two simple, quick laboratory tests and a neural network interpretation of the test data. The neural network predicted CO{sub 2} mobility reduction values which correlated well with the mobility reductions seen in coreflood tests.

  17. Preliminary performance assessment for the Waste Isolation Pilot Plant, December 1992. Volume 5, Uncertainty and sensitivity analyses of gas and brine migration for undisturbed performance

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    Before disposing of transuranic radioactive waste in the Waste Isolation Pilot Plant (WIPP), the United States Department of Energy (DOE) must evaluate compliance with applicable long-term regulations of the United States Environmental Protection Agency (EPA). Sandia National Laboratories is conducting iterative performance assessments (PAs) of the WIPP for the DOE to provide interim guidance while preparing for a final compliance evaluation. This volume of the 1992 PA contains results of uncertainty and sensitivity analyses with respect to migration of gas and brine from the undisturbed repository. Additional information about the 1992 PA is provided in other volumes. Volume 1 contains an overview of WIPP PA and results of a preliminary comparison with 40 CFR 191, Subpart B. Volume 2 describes the technical basis for the performance assessment, including descriptions of the linked computational models used in the Monte Carlo analyses. Volume 3 contains the reference data base and values for input parameters used in consequence and probability modeling. Volume 4 contains uncertainty and sensitivity analyses with respect to the EPA`s Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes (40 CFR 191, Subpart B). Finally, guidance derived from the entire 1992 PA is presented in Volume 6. Results of the 1992 uncertainty and sensitivity analyses indicate that, conditional on the modeling assumptions and the assigned parameter-value distributions, the most important parameters for which uncertainty has the potential to affect gas and brine migration from the undisturbed repository are: initial liquid saturation in the waste, anhydrite permeability, biodegradation-reaction stoichiometry, gas-generation rates for both corrosion and biodegradation under inundated conditions, and the permeability of the long-term shaft seal.

  18. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    SciTech Connect (OSTI)

    Myint, P. C.; Hao, Y.; Firoozabadi, A.

    2015-03-27

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO2) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data [1]. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi [2], and the CO2 activity coefficient model by Duan and Sun [3]. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO2, pure water, and both CO2-rich and aqueous (H2O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Suns model yields accurate results for the partial molar enthalpy of CO2. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H2O-CO2-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  19. West Hackberry Strategic Petroleum Reserve site brine disposal monitoring, Year I report. Volume V. Supporting data for estuarine hydrology, discharge plume analysis, chemical oceanography, biological oceanography, and data management. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J.

    1983-02-01

    This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which located in southwestern Louisiana, and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Volume V contains appendices for the following: supporting data for estuarine hydrology and hydrography; supporting data analysis of discharge plume; supporting data for water and sediment chemistry; CTD/DO and pH profiles during biological monitoring; supporting data for nekton; and supporting data for data management.

  20. The deep hydrogeologic flow system underlying the Oak Ridge Reservation -- Assessing the potential for active groundwater flow and origin of the brine

    SciTech Connect (OSTI)

    Nativ, R.; Halleran, A.; Hunley, A.

    1997-08-01

    The deep hydrogeologic system underlying the Oak Ridge Reservation (ORR) contains contaminants such as radionuclides, heavy metals, nitrates, and organic compounds. The groundwater in the deep system is saline and has been considered to be stagnant in previous studies. This study was designed to address the following questions: is groundwater in the deep system stagnant; is contaminant migration controlled by diffusion only or is advection a viable mechanism; where are the potential outlet points? On the basis of existing and newly collected data, the nature of saline groundwater flow and potential discharge into shallow, freshwater systems was assessed. Data used for this purpose included (1) spatial and temporal pressures and hydraulic heads measured in the deep system, (2) hydraulic parameters of the formations in question, (3) spatial and temporal temperature variations at depth, and (4) spatial and temporal chemical and isotopic composition of the saline groundwater. The observations suggest that the saline water contained at depth is old but not isolated (in terms of recharge and discharge) from the overlying active, freshwater-bearing units. Influx of recent water does occur. Groundwater volumes involved in this flow are likely to be small. The origin of the saline groundwater was assessed by using existing and newly acquired chemical and isotopic data. The proposed model that best fits the data is modification of residual brine from which halite has been precipitated. Other models, such as ultrafiltration and halite dissolution, were also evaluated.

  1. Use of data obtained from core tests in the design and operation of spent brine injection wells in geopressured or geothermal systems

    SciTech Connect (OSTI)

    Jorda, R.M.

    1980-03-01

    The effects of formation characteristics on injection well performance are reviewed. Use of data acquired from cores taken from injection horizons to predict injectivity is described. And methods for utilizing data from bench scale testing of brine and core samples to optimize injection well design are presented. Currently available methods and equipment provide data which enable the optimum design of injection wells through analysis of cores taken from injection zones. These methods also provide a means of identifying and correcting well injection problems. Methods described in this report are: bulk density measurement; porosity measurement; pore size distribution analysis; permeability measurement; formation grain size distribution analysis; core description (lithology) and composition; amount, type and distribution of clays and shales; connate water analysis; consolidatability of friable reservoir rocks; grain and pore characterization by scanning electron microscopy; grain and pore characterization by thin section analysis; permeability damage and enhancement tests; distribution of water-borne particles in porous media; and reservoir matrix acidizing effectiveness. The precise methods of obtaining this information are described, and their use in the engineering of injection wells is illustrated by examples, where applicable. (MHR)

  2. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    SciTech Connect (OSTI)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthite component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.

  3. {gamma}-Radiolysis of NaCl Brine in the Presence of UO{sub 2}(s): Effects of Hydrogen and Bromide

    SciTech Connect (OSTI)

    Metz, Volker; Bohnert, Elke; Kelm, Manfred; Schild, Dieter; Kienzler, Bernhard

    2007-07-01

    A concentrated NaCl solution was {gamma}-irradiated in autoclaves under a pressure of 25 MPa. A set of experiments were conducted in 6 mol (kg H{sub 2}O){sup -1} NaCl solution in the presence of UO{sub 2}(s) pellets; in a second set of experiments, {gamma}-radiolysis of the NaCl brine was studied without UO{sub 2}(s). Hydrogen, oxygen and chlorate were formed as long-lived radiolysis products. Due to the high external pressure, all radiolysis products remained dissolved. H{sub 2} and O{sub 2} reached steady state concentrations in the range of 5.10{sup -3} to 6.10{sup -2} mol (kg H{sub 2}O){sup -1} corresponding to a partial gas pressure of {approx}2 to {approx}20 MPa. Radiolytic formation of hydrogen and oxygen increased with the concentration of bromide added to solution. Both, in the presence of bromide, resulting in a relatively high radiolytic yield, and in the absence of bromide surfaces of the UO{sub 2}(s) samples were oxidized, and concentration of dissolved uranium reached the solubility limit of the schoepite / NaUO{sub 2}O(OH)(cr) transition. At the end of the experiments, the pellets were covered by a surface layer of a secondary solid phase having a composition close to Na{sub 2}U{sub 2}O{sub 7}. The experimental results demonstrate that bromide counteracts an H{sub 2} inhibition effect on radiolysis gas production, even at a concentration ratio of [H{sub 2}] / [Br{sup -}] > 100. The present observations are related to the competitive reactions of OH radicals with H{sub 2}, Br{sup -} and Cl{sup -}. A similar competition of hydrogen and bromide, controlling the yield of {gamma}-radiolysis products, is expected for solutions of lower Cl{sup -} concentration. (authors)

  4. Rock-brine chemical interactions. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-02-01

    The results of experimental interaction of powdered volcanic rock with aqueous solutions are presented at temperatures from 200 to 400/sup 0/C, 500 to 1000 bars fluid pressure, with reaction durations of approximately 30 days under controlled laboratory conditions. The aim of this research is to develop data on the kinetics and equilibria of rock solution interactions that will provide insight into the complex geochemical processes attending geothermal reservoir development, stimulation, and reinjection. The research was done in the Stanford Hydrothermal Lab using gold cell equipment of the Dickson design. This equipment inverts the solution rock mixture several times a minute to ensure thorough mixing. Solution samples were periodically withdrawn without interruption of the experimental conditions. The data from these experiments suggests a path dependent series of reactions by which geothermal fluids might evolve from meteoric or magmatic sources.

  5. Development Operations Hypersaline Geothermal Brine Utilization...

    Open Energy Info (EERE)

    Abstract NA Authors Whitescarver and Olin D. Published U.S. Department of Energy, 1984 Report Number NA DOI Not Provided Check for DOI availability: http:crossref.org...

  6. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Peer-review under responsibility of the Organizing Committee of GHGT-12 doi: 10.1016j.egy... + ajkXjXj + ai>i,kXi2, where i 1,22 and jl,22 and k 1,37 The goodness-of-fit (R2) ...

  7. GEOTHERMAL ENERGY; 59 BASIC BIOLOGICAL SCIENCES; BRINES; DETOXIFICATIO...

    Office of Scientific and Technical Information (OSTI)

    PROCESSING; BACTERIA; BIOCHEMISTRY; BIOREACTORS; BIOTECHNOLOGY; GEOCHEMISTRY; GEOTHERMAL ENERGY; METALS; SLUDGES; TOXIC MATERIALS; CHEMISTRY; ELEMENTS; ENERGY; ENERGY SOURCES;...

  8. Drill string enclosure

    DOE Patents [OSTI]

    Jorgensen, Douglas K.; Kuhns, Douglass J.; Wiersholm, Otto; Miller, Timothy A.

    1993-01-01

    The drill string enclosure consists of six component parts, including; a top bracket, an upper acrylic cylinder, an acrylic drill casing guide, a lower acrylic cylinder, a bottom bracket, and three flexible ducts. The upper acrylic cylinder is optional based upon the drill string length. The drill string enclosure allows for an efficient drill and sight operation at a hazardous waste site.

  9. Drill string enclosure

    DOE Patents [OSTI]

    Jorgensen, D.K.; Kuhns, D.J.; Wiersholm, O.; Miller, T.A.

    1993-03-02

    The drill string enclosure consists of six component parts, including; a top bracket, an upper acrylic cylinder, an acrylic drill casing guide, a lower acrylic cylinder, a bottom bracket, and three flexible ducts. The upper acrylic cylinder is optional based upon the drill string length. The drill string enclosure allows for an efficient drill and sight operation at a hazardous waste site.

  10. Remote multiple string well completion

    SciTech Connect (OSTI)

    Kirkland, K.G.

    1981-04-21

    Method and apparatus for multiple string well completions by remote operations in underwater installations, by which the tubing strings are installed independently rather than simultaneously.

  11. PT-symmetric strings

    SciTech Connect (OSTI)

    Amore, Paolo; Fernndez, Francisco M.; Garcia, Javier; Gutierrez, German

    2014-04-15

    We study both analytically and numerically the spectrum of inhomogeneous strings with PT-symmetric density. We discuss an exactly solvable model of PT-symmetric string which is isospectral to the uniform string; for more general strings, we calculate exactly the sum rules Z(p)??{sub n=1}{sup ?}1/E{sub n}{sup p}, with p=1,2, and find explicit expressions which can be used to obtain bounds on the lowest eigenvalue. A detailed numerical calculation is carried out for two non-solvable models depending on a parameter, obtaining precise estimates of the critical values where pair of real eigenvalues become complex. -- Highlights: PT-symmetric Hamiltonians exhibit real eigenvalues when PT symmetry is unbroken. We study PT-symmetric strings with complex density. They exhibit regions of unbroken PT symmetry. We calculate the critical parameters at the boundaries of those regions. There are exact real sum rules for some particular complex densities.

  12. Final Report: "Strings 2014"

    SciTech Connect (OSTI)

    Witten, Edward

    2015-10-21

    The Strings 2014 meeting was held at Princeton University June 23-27, 2014, co-sponsored by Princeton University and the Institute for Advanced Study. The goal of the meeting was to provide a stimulating and up-to-date overview of research in string theory and its relations to other areas of physics and mathematics, ranging from geometry to quantum field theory, condensed matter physics, and more. This brief report lists committee members and speakers but contains no scientific information. Note that the talks at Strings 2014 were videotaped and are available on the conference website: http://physics.princeton.edustrings2014/Talk_titles.shtml.

  13. Subsurface drill string

    DOE Patents [OSTI]

    Casper, William L.; Clark, Don T.; Grover, Blair K.; Mathewson, Rodney O.; Seymour, Craig A.

    2008-10-07

    A drill string comprises a first drill string member having a male end; and a second drill string member having a female end configured to be joined to the male end of the first drill string member, the male end having a threaded portion including generally square threads, the male end having a non-threaded extension portion coaxial with the threaded portion, and the male end further having a bearing surface, the female end having a female threaded portion having corresponding female threads, the female end having a non-threaded extension portion coaxial with the female threaded portion, and the female end having a bearing surface. Installation methods, including methods of installing instrumented probes are also provided.

  14. Hydroball string sensing system

    DOE Patents [OSTI]

    Hurwitz, Michael J.; Ekeroth, Douglas E.; Squarer, David

    1991-01-01

    A hydroball string sensing system for a nuclear reactor that includes stainless tubes positioned to guide hydroball strings into and out of the nuclear reactor core. A sensor such as an ultrasonic transducer transmitter and receiver is positioned outside of the nuclear reactor core and adjacent to the tube. The presence of an object such a bullet member positioned at an end a hydroball string, or any one of the hydroballs interrupts the transmission of ultrasound from the transmitter to the receiver. Alternatively, if the bullet member and hydroballs include a ferritic material, either a Hall effect sensor or other magnetic field sensors such as a magnetic field rate of change sensor can be used to detect the location and position of a hydroball string. Placing two sensors along the tube with a known distance between the sensors enables the velocity of a hydroball string to be determined. This determined velocity can be used to control the flow rate of a fluid within the tube so as to control the velocity of the hydroball string.

  15. EERE Success Story—Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential

    Broader source: Energy.gov [DOE]

    Utilizing EERE funds, ElectraTherm developed a geothermal technology that will generate electricity for less than $0.06 per kilowatt hour.

  16. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT-STABILIZED BASIN 43 GROUNDWATER BRINE

    SciTech Connect (OSTI)

    DUNCAN JB; COOKE GA; LOCKREM LL

    2009-07-20

    This report documents the effort to sequester technetium by the use of getters, reductants (tin(II) apatite and ferrous sulfate), sorbents (A530E and A532E ion exchange resins), and cementitious waste form. The pertechnetate form of technetium is highly soluble and mobile in aerobic (oxidizing) environments.

  17. The role of wellbore remediation on the evolution of groundwater quality from CO₂ and brine leakage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO₂ in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO₂ mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strongmore » correlation between cumulative injected CO₂ mass and maximum plume pH volumes and a positive correlation between CO₂ flux, cumulative injected CO₂, and plume recovery times, with secondary dependence on permeability.« less

  18. Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential

    Broader source: Energy.gov [DOE]

    Utilizing EERE funds, ElectraTherm developed a geothermal technology that will generate electricity for less than $0.06 per kilowatt hour.

  19. APPLIED PHYTO-REMEDIATION TECHNIQUES USING HALOPHYTES FOR OIL AND BRINE SPILL SCARS

    SciTech Connect (OSTI)

    M.L. Korphage; Bruce G. Langhus; Scott Campbell

    2003-03-01

    Produced salt water from historical oil and gas production was often managed with inadequate care and unfortunate consequences. In Kansas, the production practices in the 1930's and 1940's--before statewide anti-pollution laws--were such that fluids were often produced to surface impoundments where the oil would segregate from the salt water. The oil was pumped off the pits and the salt water was able to infiltrate into the subsurface soil zones and underlying bedrock. Over the years, oil producing practices were changed so that segregation of fluids was accomplished in steel tanks and salt water was isolated from the natural environment. But before that could happen, significant areas of the state were scarred by salt water. These areas are now in need of economical remediation. Remediation of salt scarred land can be facilitated with soil amendments, land management, and selection of appropriate salt tolerant plants. Current research on the salt scars around the old Leon Waterflood, in Butler County, Kansas show the relative efficiency of remediation options. Based upon these research findings, it is possible to recommend cost efficient remediation techniques for slight, medium, and heavy salt water damaged soil. Slight salt damage includes soils with Electrical Conductivity (EC) values of 4.0 mS/cm or less. Operators can treat these soils with sufficient amounts of gypsum, install irrigation systems, and till the soil. Appropriate plants can be introduced via transplants or seeded. Medium salt damage includes soils with EC values between 4.0 and 16 mS/cm. Operators will add amendments of gypsum, till the soil, and arrange for irrigation. Some particularly salt tolerant plants can be added but most planting ought to be reserved until the second season of remediation. Severe salt damage includes soil with EC values in excess of 16 mS/cm. Operators will add at least part of the gypsum required, till the soil, and arrange for irrigation. The following seasons more gypsum will be added and as the soil EC is reduced, plants can be introduced. If rapid remediation is required, a sufficient volume of topsoil, or sand, or manure can be added to dilute the local salinity, the bulk amendments tilled into the surface with added gypsum, and appropriate plants added. In this case, irrigation will be particularly important. The expense of the more rapid remediation will be much higher.

  20. Molecular dynamics study of interfacial confinement effects of aqueous NaCl brines in nanoporous carbon

    SciTech Connect (OSTI)

    Wander, M. C. F.; Shuford, K. L.

    2010-12-09

    In this paper, studies of aqueous electrolyte solutions in contact with a family of porous carbon geometries using classical molecular dynamics simulations are presented. These simulations provide an atomic scale depiction of ion transport dynamics in different environments to elucidate power of aqueous electrolyte supercapacitors. The electrolyte contains alkali metal and halide ions, which allow for the examination of size trends within specific geometries as well as trends in concentration. The electrode pores are modeled as planar graphite sheets and carbon nanotubes with interstices ranging from one to four nanometers. Ordered layers form parallel to the carbon surface, which facilitates focused ion motion under slightly confining conditions. As a result, the ions diffusivities are enhanced in the direction of the slit or pore. Further confining the system leads to decreased ion diffusivities. The ions are fully hydrated in all but the smallest slits and pores with those sizes showing increased ion pairing. There is strong evidence of charge separation perpendicular to the surface at all size scales, concentrations, and ion types, providing a useful baseline for examining differential capacitance behavior and future studies on energy storage. These systems show promise as high-power electrical energy storage devices.

  1. EERE Success Story-Nevada: Geothermal Brine Brings Low-Cost Power...

    Broader source: Energy.gov (indexed) [DOE]

    Utilizing a 1 million EERE investment, heat from geothermal fluids-a byproduct of gold mining-will be generating electricity this year for less than 0.06 per kilowatt hour with ...

  2. Geothermal Brine Brings Low-Cost Power with Big Potential | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thanks to a 1 million Geothermal Technologies Office investment, heat from geothermal fluids--a byproduct of gold mining--is generating electricity this year for less than 6 a ...

  3. Repetitive Regeneration of Media #1 after REE Sorption from Brine #1 at 70C

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-23

    This dataset shows the ability of media #1 to be loaded with REE's, stripped of the REE's sequestered, regenerated, and reused over many cycles.

  4. Galvanic corrosion of a copper alloy in lithium bromide heavy brine environments

    SciTech Connect (OSTI)

    Itzhak, D.; Greenberg, T.

    1999-08-01

    Galvanic corrosion of the copper alloy 84% Cu-15% Zn-1% Ni was studied in 55 wt% lithium bromide (LiBr) environments. The galvanic couples studied were: 84% Cu-15% Zn-1% Ni-Ti2, 84% Cu-15% Zn-1% Ni-Ti7, 84% Cu-15% Zn-1% Ni-30% Cu-70% Ni, 84% Cu-15% Zn-1% Ni-Pb, 84% Cu-15% Zn-1% Ni-Ag, and 84% Cu-15% Zn-1% Ni-Sn. Potentiodynamic polarization measurements, open-circuit potential (OCP), and weight change measurements were carried out to evaluate the galvanic effect. Results indicated that Ti alloys and 30% Cu-70% Ni were the most passive alloys tested, and they behaved as cathodes. Although galvanic corrosion was expected, a negligible effect was measured because of an effective passivation layer on the surface of Ti alloys and 30% Cu-70% Ni. Pb, Ag, and Sn showed anodic behavior as compared to 84% Cu-15% Zn-1% Ni. As a result of the galvanic coupling, significant weight loss of these metals was measured. Sn was the most effective anode as compared to the other tested alloys; it acted as a sacrificial anode. Sn provided effective cathodic protection to 84% Cu-15% Zn-1% Ni in 55 wt% LiBr environments at 140 C.

  5. Draft Test Plan for Brine Migration Experimental Studies in Run-of-Mine Salt Backfill

    SciTech Connect (OSTI)

    Jordan, Amy B.; Stauffer, Philip H.; Reed, Donald T.; Boukhalfa, Hakim; Caporuscio, Florie Andre; Robinson, Bruce Alan

    2015-02-02

    The primary objective of the experimental effort described here is to aid in understanding the complex nature of liquid, vapor, and solid transport occurring around heated nuclear waste in bedded salt. In order to gain confidence in the predictive capability of numerical models, experimental validation must be performed to ensure that (a) hydrological and physiochemical parameters and (b) processes are correctly simulated. The experiments proposed here are designed to study aspects of the system that have not been satisfactorily quantified in prior work. In addition to exploring the complex coupled physical processes in support of numerical model validation, lessons learned from these experiments will facilitate preparations for larger-scale experiments that may utilize similar instrumentation techniques.

  6. Gas content of Gladys McCall reservoir brine (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    ... However, observed small transients in EthaneMethane and PropaneMethane ratios indicate that some free gas was produced from the near wellbore region. These results suggest that ...

  7. Geochemistry of Bolivian salars, Lipez, southern Altiplano: Origin of solutes and brine evolution

    SciTech Connect (OSTI)

    Risacher, F. ); Fritz, B. )

    1991-03-01

    This paper focuses on poorly understood processes related to saline lakes, or salars, of the southern Bolivian Altiplano. A morphologic classification system is described, and the origin of solutes in the inflow waters is discussed. Next, the actual chemical evolution of these inflow waters is compared with their theoretical evolution based on thermodynamic equilibria. The water chemistry of a specific sequence of evaporating waters is then scrutinized to determine which processes are responsible for a significant discrepancy which is apparent between the measured and the calculated evolution.

  8. Gas Content of Gladys McCall Reservoir Brine A Topical Report

    Office of Scientific and Technical Information (OSTI)

    Produced Gas Composition 2.4 The IGT Bubble Test 2.4.1 Physical Phenomena That Cause the Bubble 2.4.2 The Febuary 1 I , 1986 Bubble Test 2.4.3 The April 14, 1987 Bubble Test 2.4.4 ...

  9. Experimental investigation of brine-CO2 flow through a natural...

    Office of Scientific and Technical Information (OSTI)

    ... A paper copy of this document is also available for sale to the public from the National Technical Information Service, Springfield, VA at www.ntis.gov. Authors: Smith, M M ; ...

  10. The role of wellbore remediation on the evolution of groundwater quality from CO? and brine leakage

    SciTech Connect (OSTI)

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO? in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO? mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strong correlation between cumulative injected CO? mass and maximum plume pH volumes and a positive correlation between CO? flux, cumulative injected CO?, and plume recovery times, with secondary dependence on permeability.

  11. Hydrogen chloride in superheated steam and chloride in deep brine at The Geysers geothermal field, California

    SciTech Connect (OSTI)

    Haizlip, J.R.; Truesdell, A.H.

    1988-01-01

    Chloride (Cl) concentrations of 10-120 ppm{sub w} have been measured in superheated steam produced by wells at The Geysers, a vapor-dominated geothermal field in northern California. Corrosion of the well casing and steam-gathering system has been recognized in some parts of The Geysers, and is apparently related to the presence of Cl. Cl in the steam is in a volatile form, generated with the steam at reservoir temperatures, and probably travels to the wellhead as HCl gas. Published experimental data for partial pressures of HCl in steam over aqueous HCl solutions and for dissociation constants of HCl were used to calculate distribution coefficients for HCl. Reservoir liquid Cl concentrations capable of generating steam with the observed Cl concentrations were then calculated as a function of pH and temperatures from 250 to 350 C. Equilibrium mineral/liquid reactions with the K-mica and K-feldspar assemblage found in the wells limit the reservoir liquid pH values at various Cl concentrations to about 5 to 6 (near neutral at 250 to 350 C). Within this pH range, liquid at 250 C could not produce steam containing the high Cl concentrations observed. However, liquid at higher temperatures (300 to 350 C) with chloride concentrations greater than 10,000 ppm{sub w} could generate steam with 10 to over 200 ppm{sub w} Cl. There is a positive correlation between pH and the chloride concentrations required to generate a given Cl concentration in steam. The concentration of Cl in superheated steam constrains not only the reservoir liquid composition, but the temperature at which the steam last equilibrated with liquid.

  12. Repetitive Regeneration of Media #1 in a Dynamic Column Extraction using Brine #1

    SciTech Connect (OSTI)

    Gary Garland

    2015-10-14

    This data is from a regeneration study from a dynamic column extraction experiment where we ran a solution of REE's through a column of media #1 then stripped the REE's off the media using 2M HNO3 solution. We then re-equilibrated the media and repeated the process of running a REE solution through the column and stripping the REE's off the media and comparing the two runs.

  13. Have You Used LED Light Strings?

    Broader source: Energy.gov [DOE]

    This week, you read about LED holiday light strings, which can use 90% less energy than regular incandescent light strings.

  14. Probing the String Landscape

    ScienceCinema (OSTI)

    Keith Dienes

    2010-01-08

    We are currently in the throes of a potentially huge paradigm shift in physics. Motivated by recent developments in string theory and the discovery of the so-called "string landscape", physicists are beginning to question the uniqueness of fundamental theories of physics and the methods by which such theories might be understood and investigated. In this colloquium, I will give a non-technical introduction to the nature of this paradigm shift and how it developed. I will also discuss some of the questions to which it has led, and the nature of the controversies it has spawned.

  15. Remarks on string solitons

    SciTech Connect (OSTI)

    Loginov, E. K.

    2008-05-15

    We consider generalized self-duality equations for U(2r) Yang-Mills theory on R{sup 8} with quaternionic structure. We employ the extended ADHM method in eight dimensions to construct exact soliton solutions of the low-energy effective theory of the heterotic string.

  16. Current balancing for battery strings

    DOE Patents [OSTI]

    Galloway, James H.

    1985-01-01

    A battery plant is described which features magnetic circuit means for balancing the electrical current flow through a pluraliircuitbattery strings which are connected electrically in parallel. The magnetic circuit means is associated with the battery strings such that the conductors carrying the electrical current flow through each of the battery strings pass through the magnetic circuit means in directions which cause the electromagnetic fields of at least one predetermined pair of the conductors to oppose each other. In an alternative embodiment, a low voltage converter is associated with each of the battery strings for balancing the electrical current flow through the battery strings.

  17. Device for balancing parallel strings

    DOE Patents [OSTI]

    Mashikian, Matthew S.

    1985-01-01

    A battery plant is described which features magnetic circuit means in association with each of the battery strings in the battery plant for balancing the electrical current flow through the battery strings by equalizing the voltage across each of the battery strings. Each of the magnetic circuit means generally comprises means for sensing the electrical current flow through one of the battery strings, and a saturable reactor having a main winding connected electrically in series with the battery string, a bias winding connected to a source of alternating current and a control winding connected to a variable source of direct current controlled by the sensing means. Each of the battery strings is formed by a plurality of batteries connected electrically in series, and these battery strings are connected electrically in parallel across common bus conductors.

  18. The String of Pearls

    Energy Science and Technology Software Center (OSTI)

    2006-07-01

    A team of collaborators within the Southwest Regional Partnership (SRP) on Carbon Sequestration developed an interactive software tool to help facilitate discussions involving the science, engineering, economic and policy considerations for a carbon sequestration pilot project. This model illustrates the "String of Pearls" algorithm used to develop a hypothetical carbon dioxide (CO2) transportation network in sequence with existing infrastructure. The "String of Pearls" model can assess geological sink combinations according to their distance from themore » point source (e.g., power plant), relative size (to maintain a useful fill lifetime for a project), relative distance from existing CO2 transportation infrastructure, and other salient project attributes. The results indicate that the cost to capture CO2 at point sources (e.g. power plants) is the largest component of the overall CO2 capture, transportation and storage system's initial cost estimate. The "String of Pearls" Integrated Assessment model can help planners assess these issues using an integrated, systems view when deciding where to develop future carbon sequestration pilot projects. Likely users of this model include partners within the SRP, other regional partnerships and interested individuals, and private industry interested in carbon sequestration systems. The model seeks to improve understanding of the economic viability and emission trade-offs associated with all stages of carbone sequestration systems analysis.« less

  19. Coulomb string tension, asymptotic string tension, and the gluon chain

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Greensite, Jeff; Szczepaniak, Adam P.

    2015-02-01

    We compute, via numerical simulations, the non-perturbative Coulomb potential and position-space ghost propagator in pure SU(3) gauge theory in Coulomb gauge. We find that that the Coulomb potential scales nicely in accordance with asymptotic freedom, that the Coulomb potential is linear in the infrared, and that the Coulomb string tension is about four times larger than the asymptotic string tension. We explain how it is possible that the asymptotic string tension can be lower than the Coulomb string tension by a factor of four.

  20. Summing Planar Bosonic Open Strings

    SciTech Connect (OSTI)

    Bardakci, Korkut

    2006-02-16

    In earlier work, planar graphs of massless {phi}{sup 3} theory were summed with the help of the light cone world sheet picture and the mean field approximation. In the present article, the same methods are applied to the problem of summing planar bosonic open strings. They find that in the ground state of the system, string boundaries form a condensate on the world sheet, and a new string emerges from this summation. Its slope is always greater than the initial slope, and it remains non-zero even when the initial slope is set equal to zero. If they assume the initial string tends to a field a theory in the zero slope limit, this result provides evidence for string formation in field theory.

  1. Geometry, topology, and string theory

    SciTech Connect (OSTI)

    Varadarajan, Uday

    2003-07-10

    A variety of scenarios are considered which shed light upon the uses and limitations of classical geometric and topological notions in string theory. The primary focus is on situations in which D-brane or string probes of a given classical space-time see the geometry quite differently than one might naively expect. In particular, situations in which extra dimensions, non-commutative geometries as well as other non-local structures emerge are explored in detail. Further, a preliminary exploration of such issues in Lorentzian space-times with non-trivial causal structures within string theory is initiated.

  2. Save Money with LED Holiday Light Strings

    Broader source: Energy.gov [DOE]

    LED (or light emitting diode) light strings can use 90% less energy than regular incandescent light strings. They also last about ten times longer, are cooler than incandescents (reducing fire hazards), and are more durable.

  3. Metastable cosmic strings in realistic models

    SciTech Connect (OSTI)

    Holman, R.; Hsu, S.; Vachaspati, T.; Watkins, R. |

    1992-11-01

    The stability of the electroweak Z-string is investigated at high temperatures. The results show that, while finite temperature corrections can improve the stability of the Z-string, their effect is not strong enough to stabilize the Z-string in the standard electroweak model. Consequently, the Z-string will be unstable even under the conditions present during the electroweak phase transition. Phenomenologically viable models based on the gauge group SU(2){sub L} {times} SU(2) {sub R} {times} U(1){sub B-L} are then considered, and it is shown that metastable strings exist and are stable to small perturbations for a large region of the parameter space for these models. It is also shown that these strings are superconducting with bosonic charge carriers. The string superconductivity may be able to stabilize segments and loops against dynamical contraction. Possible implications of these strings for cosmology are discussed.

  4. Metastable cosmic strings in realistic models

    SciTech Connect (OSTI)

    Holman, R. . Dept. of Physics); Hsu, S. . Lyman Lab. of Physics); Vachaspati, T. . Dept. of Physics and Astronomy); Watkins, R. Fermi National Accelerator Lab., Batavia, IL )

    1992-01-01

    The stability of the electroweak Z-string is investigated at high temperatures. The results show that, while finite temperature corrections can improve the stability of the Z-string, their effect is not strong enough to stabilize the Z-string in the standard electroweak model. Consequently, the Z-string will be unstable even under the conditions present during the electroweak phase transition. Phenomenologically viable models based on the gauge group SU(2)[sub L] [times] SU(2) [sub R] [times] U(1)[sub B-L] are then considered, and it is shown that metastable strings exist and are stable to small perturbations for a large region of the parameter space for these models. It is also shown that these strings are superconducting with bosonic charge carriers. The string superconductivity may be able to stabilize segments and loops against dynamical contraction. Possible implications of these strings for cosmology are discussed.

  5. Acoustic data transmission through a drill string

    DOE Patents [OSTI]

    Drumheller, D.S.

    1988-04-21

    Acoustical signals are transmitted through a drill string by canceling upward moving acoustical noise and by preconditioning the data in recognition of the comb filter impedance characteristics of the drill string. 5 figs.

  6. Alteration Behavior of High Burnup Spent Fuel in Salt Brine Under Hydrogen Overpressure and in Presence of Bromide

    SciTech Connect (OSTI)

    Loida, Andreas; Metz, Volker; Kienzler, Bernhard

    2007-07-01

    Recent studies have shown that in the presence of H2 overpressure, which forms due to the corrosion of the Fe based container, the dissolution rate of the spent fuel matrix is slowed down by a factor of about 10, associated with a distinct decrease of concentrations of important radionuclides. However, in a natural salt environment as well as in geological formations with chloride rich groundwater the presence of radiation chemically active impurities such as bromide must be taken in consideration. Bromide is known to react with {beta}/{gamma} radiolysis products, thus counteracting the protective H{sub 2} effect. In the present experiments using high burnup spent fuel, it is observed that during 212 days the matrix dissolution rate was enhanced by a factor of about 10 in the presence of up to 10{sup -3} M bromide and 3.2 bar H{sub 2} overpressure. However, concentrations of matrix bound actinides were found at the same level or below as found under identical conditions, but in the absence of bromide. In the long-term it is expected that the effect of bromide becomes less important, because the decrease of {beta}/{gamma}-activity results in a decrease of oxidative radicals, which react with bromide, while a-activity will dominate the radiation field. (authors)

  7. RealGasBrine v1.0 option of TOUGH+ v1.5 () | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Guide; Sample Problem Input Data; 1 CD-ROM Software CPU: MLTPL Open Source: No Source Code Available: Yes Research Org: Lawrence Berkeley National Laboratory Sponsoring Org: ...

  8. Remote multiple string well completion

    SciTech Connect (OSTI)

    Kirkland, K.G.

    1981-09-15

    In a remotely installed underwater well apparatus, a tubular body, typically a multiple string tubing hanger, is landed in a position oriented rotationally with respect to a reference point on the apparatus and a seal device is then energized by the same tool employed to land and orient the tubular body.

  9. Filter for a drill string

    DOE Patents [OSTI]

    Hall, David R.; Pixton, David S.; Briscoe, Michael; McPherson, James

    2007-12-04

    A filter for a drill string comprises a perforated receptacle having an open end and a perforated end and first and second mounting surfaces are adjacent the open end. A transmission element is disposed within each of the first and second mounting surfaces. A capacitor may modify electrical characteristics of an LC circuit that comprises the transmission elements. The respective transmission elements are in communication with each other and with a transmission network integrated into the drill string. The transmission elements may be inductive couplers, direct electrical contacts, or optical couplers. In some embodiments of the present invention, the filter comprises an electronic component. The electronic component may be selected from the group consisting of a sensor, a router, a power source, a clock source, a repeater, and an amplifier.

  10. Extraordinary vacuum black string solutions

    SciTech Connect (OSTI)

    Kim, Hyeong-Chan; Lee, Jungjai

    2008-01-15

    In addition to the boosted static solution there are two other classes of stationary stringlike solutions of the vacuum Einstein equation in (4+1) dimensions. Each class is characterized by three parameters of mass, tension, and momentum flow along the fifth coordinate. We analyze the metric properties of one of the two classes, which was previously assumed to be naked singular, and show that the solution spectrum contains black string and wormhole in addition to the known naked singularity as the momentum flow to mass ratio increases. Interestingly, there does not exist new zero momentum solution in these cases.

  11. Towards Inflation in String Theory (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Towards Inflation in String Theory Citation Details In-Document Search Title: Towards Inflation in String Theory We investigate the embedding of brane inflation into stable ...

  12. Covariant functional diffusion equation for Polyakov's bosonic string

    SciTech Connect (OSTI)

    Botelho, L. C. L.

    1989-07-15

    I write a covariant functional diffusion equation for Polyakov's bosonic string with the string's world-sheet area playing the role of proper time.

  13. Melt dumping in string stabilized ribbon growth

    DOE Patents [OSTI]

    Sachs, Emanuel M.

    1986-12-09

    A method and apparatus for stabilizing the edge positions of a ribbon drawn from a melt includes the use of wettable strings drawn in parallel up through the melt surface, the ribbon being grown between the strings. A furnace and various features of the crucible used therein permit continuous automatic growth of flat ribbons without close temperature control or the need for visual inspection.

  14. Effects of overlapping strings in pp collisions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bierlich, Christian; Gustafson, Gösta; Lönnblad, Leif; Tarasov, Andrey

    2015-03-26

    In models for hadron collisions based on string hadronization, the strings are usually treated as independent, allowing no interaction between the confined colour fields. In studies of nucleus collisions it has been suggested that strings close in space can fuse to form "colour ropes." Such ropes are expected to give more strange particles and baryons, which also has been suggested as a signal for plasma formation. Overlapping strings can also be expected in pp collisions, where usually no phase transition is expected. In particular at the high LHC energies the expected density of strings is quite high. To investigate possiblemore » effects of rope formation, we present a model in which strings are allowed to combine into higher multiplets, giving rise to increased production of baryons and strangeness, or recombine into singlet structures and vanish. Also a crude model for strings recombining into junction structures is considered, again giving rise to increased baryon production. The models are implemented in the DIPSY MC event generator, using PYTHIA8 for hadronization, and comparison to pp minimum bias data, reveals improvement in the description of identified particle spectra.« less

  15. Effects of overlapping strings in pp collisions

    SciTech Connect (OSTI)

    Bierlich, Christian; Gustafson, Gösta; Lönnblad, Leif; Tarasov, Andrey

    2015-03-26

    In models for hadron collisions based on string hadronization, the strings are usually treated as independent, allowing no interaction between the confined colour fields. In studies of nucleus collisions it has been suggested that strings close in space can fuse to form "colour ropes." Such ropes are expected to give more strange particles and baryons, which also has been suggested as a signal for plasma formation. Overlapping strings can also be expected in pp collisions, where usually no phase transition is expected. In particular at the high LHC energies the expected density of strings is quite high. To investigate possible effects of rope formation, we present a model in which strings are allowed to combine into higher multiplets, giving rise to increased production of baryons and strangeness, or recombine into singlet structures and vanish. Also a crude model for strings recombining into junction structures is considered, again giving rise to increased baryon production. The models are implemented in the DIPSY MC event generator, using PYTHIA8 for hadronization, and comparison to pp minimum bias data, reveals improvement in the description of identified particle spectra.

  16. Apparatus in a drill string

    DOE Patents [OSTI]

    Hall, David R.; Dahlgren, Scott; Hall, Jr., Tracy H.; Fox, Joe; Pixton, David S.

    2007-07-17

    An apparatus in a drill string comprises an internally upset drill pipe. The drill pipe comprises a first end, a second end, and an elongate tube intermediate the first and second ends. The elongate tube and the ends comprising a continuous an inside surface with a plurality of diameters. A conformable spirally welded metal tube is disposed within the drill pipe intermediate the ends thereof and terminating adjacent to the ends of the drill pipe. The conformable metal tube substantially conforms to the continuous inside surface of the metal tube. The metal tube may comprise a non-uniform section which is expanded to conform to the inside surface of the drill pipe. The non-uniform section may comprise protrusions selected from the group consisting of convolutions, corrugations, flutes, and dimples. The non-uniform section extends generally longitudinally along the length of the tube.

  17. Charged rotating dilaton black strings

    SciTech Connect (OSTI)

    Dehghani, M.H.; Farhangkhah, N.

    2005-02-15

    In this paper we, first, present a class of charged rotating solutions in four-dimensional Einstein-Maxwell-dilaton gravity with zero and Liouville-type potentials. We find that these solutions can present a black hole/string with two regular horizons, an extreme black hole or a naked singularity provided the parameters of the solutions are chosen suitable. We also compute the conserved and thermodynamic quantities, and show that they satisfy the first law of thermodynamics. Second, we obtain the (n+1)-dimensional rotating solutions in Einstein-dilaton gravity with Liouville-type potential. We find that these solutions can present black branes, naked singularities or spacetimes with cosmological horizon if one chooses the parameters of the solutions correctly. Again, we find that the thermodynamic quantities of these solutions satisfy the first law of thermodynamics.

  18. The pomeron in closed bosonic string theory

    SciTech Connect (OSTI)

    Fazio, A. R.

    2010-12-22

    We compute the couplings of the pomeron to the first few mass levels of closed bosonic string states in flat space. We recognize the deviation from the linearity of the Regge trajectories in a five dimensional anti De Sitter background.

  19. String model for spinning quark jets

    SciTech Connect (OSTI)

    Artru, X.; Belghobsi, Z.

    2012-06-27

    A string model of quark hadronization, taking the quark spin degree of freedom into account, is proposed. The method for using the model in a Monte-Carlo code for jet generation is given.

  20. Nonuniform black strings in various dimensions

    SciTech Connect (OSTI)

    Sorkin, Evgeny

    2006-11-15

    The nonuniform black-strings branch, which emerges from the critical Gregory-Laflamme string, is numerically constructed in dimensions 6{<=}D{<=}11 and extended into the strongly nonlinear regime. All the solutions are more massive and less entropic than the marginal string. We find the asymptotic values of the mass, the entropy and other physical variables in the limit of large horizon deformations. By explicit metric comparison we verify that the local geometry around the waist of our most nonuniform solutions is conelike with less than 10% deviation. We find evidence that in this regime the characteristic length scale has a power-law dependence on a parameter along the branch of the solutions, and estimate the critical exponent.

  1. Coiled tubing velocity strings keep wells unloaded

    SciTech Connect (OSTI)

    Wesson, H.R.; Shursen, J.L.

    1989-07-01

    Liquid loading is a problem in many older and even some newer gas wells, particularly in pressure depletion type reservoirs. This liquid loading results in decreased production and may even kill the well. The use of coiled tubing as a velocity string (or siphon string) has proved to be an economically viable alternative to allow continued and thus, increased cumulative production for wells experiencing liquid loading problems. Coiled tubing run inside the existing production string reduces the flow area, whether the well is produced up the tubing or up the annulus. This reduction in flow area results in an increase in flow velocity and thus, an increase in the well's ability to unload fluids.

  2. Cosmic strings: A problem or a solution

    SciTech Connect (OSTI)

    Bennett, D.P.; Bouchet, F.R.

    1987-10-01

    The most fundamental issue in the theory of cosmic strings is addressed by means of Numerical Simulations: the existence of a scaling solution. The resolution of this question will determine whether cosmic strings can form the basis of an attractive theory of galaxy formation or prove to be a cosmological disaster like magnetic monopoles or domain walls. After a brief discussion of our numerical technique, results are presented which, though still preliminary, offer the best support to date of this scaling hypothesis. 6 refs., 2 figs.

  3. Diffractive Scattering and Gauge/String Duality

    ScienceCinema (OSTI)

    Tan, Chung-I [Brown University, Providence, Rhode Island, United States

    2009-09-01

    High-energy diffractive scattering will be discussed based on Gauge/String duality. As shown by Brower, Polchinski, Strassler and Tan, the ubiquitous Pomeron emerges naturally in gauge theories with string-theoretical descriptions. Its existence is intimately tied to gluons, and also to the energy-momentum tensor. With a confining dual background metric, the Pomeron can be interpreted as a 'massive graviton'. In a single unified step, both its infrared and ultraviolet properties are dealt with, reflecting confinement and conformal symmetry respectively. An effective field theory for high-energy scattering can be constructed. Applications based on this approach will also be described.

  4. Strings on AdS wormholes

    SciTech Connect (OSTI)

    Ali, Mir; Ruiz, Frenny; Saint-Victor, Carlos; Vazquez-Poritz, Justin F.

    2009-08-15

    We consider the behavior of open strings on anti-de Sitter wormholes in Gauss-Bonnet theory, which are the Gauss-Bonnet gravity duals of a pair of field theories. A string with both endpoints on the same side of the wormhole describes two charges within the same field theory, which exhibit Coulomb interaction for small separation. On the other hand, a string extending through the wormhole describes two charges which live in different field theories, and they exhibit a springlike confining potential. A transition occurs when there is a pair of charges present within each field theory: for small separation each pair of charges exhibits Coulomb interaction, while for large separation the charges in the different field theories pair up and exhibit confinement. Two steadily-moving charges in different field theories can occupy the same location provided that their speed is less than a critical speed, which also plays the role of a subluminal speed limit. However, for some wormhole backgrounds, charges moving at the critical speed cannot occupy the same location and energy is transferred from the leading charge to the lagging one. We also show that strings on anti-de Sitter wormholes in supergravity theories without higher-derivative curvature terms can exhibit these properties as well.

  5. Underwater well installations and handling string joint therefor

    SciTech Connect (OSTI)

    Lawson, J.E.

    1982-07-20

    Underwater well apparatus in which the handling string for manipulating a handling tool to, E.G., orient and land a multiple string tubing hanger includes a power portion in the form of a single metal piece having a plain cylindrical outer surface to be presented to the blowout protectors, so that orientation of the handling string relative to the protectors is not necessary, and also having through passages for communicating with the tubing strings, and coupling means for attaching the handling tool to the handling string.

  6. Puna Geothermal Venture 8MW Expantion | Open Energy Information

    Open Energy Info (EERE)

    potential brine in a state-of-the-art binary plant, development of highly reliable brine pH monitoring and control system, and brine injection management in a high energy resource....

  7. Bounds on cosmic strings from WMAP and SDSS

    SciTech Connect (OSTI)

    Wyman, Mark; Wasserman, Ira; Pogosian, Levon

    2005-07-15

    We find the constraints from Wilkinson microwave anisotropy probe (WMAP) and Sloan digital sky survey (SDSS) data on the fraction of cosmological fluctuations sourced by local cosmic strings using a Markov Chain Monte Carlo (MCMC) analysis. In addition to varying the usual 6 cosmological parameters and the string tension ({mu}), we also varied the amount of small-scale structure on the strings. Our results indicate that cosmic strings can account for up to 7 (14)% of the total power of the microwave anisotropy at 68 (95)% confidence level. The corresponding bound on the string mass per unit length, within our string model, is G{mu}<3.4(5)x10{sup -7} at 68 (95)% C.L. We also calculate the B-type polarization spectra sourced by cosmic strings and discuss the prospects of their detection.

  8. EFFECT OF QUARTZ/MULLITE BLEND CERAMIC ADDITIVE ON IMPROVING RESISTANCE TO ACID OF SODIUM SILICATE-ACTIVATED SLAG CEMENT. CELCIUS BRINE.

    SciTech Connect (OSTI)

    SUGAMA, T.; BROTHERS, L.E.; VAN DE PUTTE, T.R.

    2006-06-01

    We evaluated the usefulness of manufactured quartz/mullite blend (MQMB) ceramic powder in increasing the resistance to acid of sodium silicate-activated slag (SSAS) cementitious material for geothermal wells. A 15-day exposure to 90{sup o} CO{sub 2}-laden H{sub 2}SO{sub 4} revealed that the MQMB had high potential as an acid-resistant additive for SSAS cement. Two factors, the appropriate ratio of slag/MQMB and the autoclave temperature, contributed to better performance of MQMB-modified SSAS cement in abating its acid erosion. The most effective slag/MQMB ratio in minimizing the loss in weight by acid erosion was 70/30 by weight. For autoclave temperature, the loss in weight of 100 C autoclaved cement was a less than 2%, but at 300 C it was even lower. Before exposure to acid, the cement autoclaved at 100 C was essentially amorphous; increasing the temperature to 200 C led to the formation of crystalline analcime in the zeolitic mineral family during reactions between the mullite in MQMB and the Na from sodium silicate. In addition, at 300 C, crystal of calcium silicate hydrate (1) (CSH) was generated in reactions between the quartz in MQMB and the activated slag. These two crystalline phases (CSH and analcime) were responsible for densifying the autoclaved cement, conveying improved compressive strength and minimizing water permeability. The CSH was susceptible to reactions with H{sub 2}SO{sub 4}, forming two corrosion products, bassanite and ionized monosilicic acid. However, the uptake of ionized monosilicic acid by Mg dissociated from the activated slag resulted in the formation of lizardite as magnesium silicate hydrate. On the other hand, the analcime was barely susceptible to acid if at all. Thus, the excellent acid resistance of MQMB-modified SSAS cement was due to the combined phases of lizardite and analcime.

  9. Modeling CO{sub 2}-Brine-Rock Interaction Including Mercury and H{sub 2}S Impurities in the Context of CO{sub 2} Geologic Storage

    SciTech Connect (OSTI)

    Spycher, N.; Oldenburg, C.M.

    2014-01-01

    This study uses modeling and simulation approaches to investigate the impacts on injectivity of trace amounts of mercury (Hg) in a carbon dioxide (CO{sub 2}) stream injected for geologic carbon sequestration in a sandstone reservoir at ~2.5 km depth. At the range of Hg concentrations expected (7-190 ppbV, or ~ 0.06-1.6 mg/std.m{sup 3}CO{sub 2}), the total volumetric plugging that could occur due to complete condensation of Hg, or due to complete precipitation of Hg as cinnabar, results in a very small porosity change. In addition, Hg concentration much higher than the concentrations considered here would be required for Hg condensation to even occur. Concentration of aqueous Hg by water evaporation into CO{sub 2} is also unlikely because the higher volatility of Hg relative to H{sub 2}O at reservoir conditions prevents the Hg concentration from increasing in groundwater as dry CO{sub 2} sweeps through, volatilizing both H{sub 2}O and Hg. Using a model-derived aqueous solution to represent the formation water, batch reactive geochemical modeling show that the reaction of the formation water with the CO{sub 2}-Hg mixture causes the pH to drop to about 4.7 and then become buffered near 5.2 upon reaction with the sediments, with a negligible net volume change from mineral dissolution and precipitation. Cinnabar (HgS(s)) is found to be thermodynamically stable as soon as the Hg-bearing CO{sub 2} reacts with the formation water which contains small amounts of dissolved sulfide. Liquid mercury (Hg(l)) is not found to be thermodynamically stable at any point during the simulation. Two-dimensional radial reactive transport simulations of CO{sub 2} injection at a rate of 14.8 kg/s into a 400 m-thick formation at isothermal conditions of 106°C and average pressure near 215 bar, with varying amounts of Hg and H{sub 2}S trace gases, show generally that porosity changes only by about ±0.05% (absolute, i.e., new porosity = initial porosity ±0.0005) with Hg predicted to readily precipitate from the CO{sub 2} as cinnabar in a zone mostly matching the single-phase CO{sub 2} plume. The precipitation of minerals other than cinnabar, however, dominates the evolution of porosity. Main reactions include the replacement of primarily Fe-chlorite by siderite, of calcite by dolomite, and of K-feldspar by muscovite. Chalcedony is also predicted to precipitate from the dissolution of feldspars and quartz. Although the range of predicted porosity change is quite small, the amount of dissolution and precipitation predicted for these individual minerals is not negligible. These reactive transport simulations assume that Hg gas behaves ideally. To examine effects of non-ideality on these simulations, approximate calculations of the fugacity coefficient of Hg in CO{sub 2} were made. Results suggest that Hg condensation could be significantly overestimated when assuming ideal gas behavior, making our simulation results conservative with respect to impacts on injectivity. The effect of pressure on Henry’s constant for Hg is estimated to yield Hg solubilities about 10% lower than when this effect is not considered, a change that is considered too small to affect the conclusions of this report. Although all results in this study are based on relatively mature data and modeling approaches, in the absence of experimental data and more detailed site-specific information, it is not possible to fully validate the results and conclusions.

  10. EERE Success Story-California: Geothermal Plant to Help Meet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Plant to Help Meet High Lithium Demand EERE Success Story-California: ... Here, lithium is extracted from geothermal brines in California. Batteries from Brine ...

  11. Passive injection: A strategy for mitigating reservoir pressurization...

    Office of Scientific and Technical Information (OSTI)

    induced seismicity and brine migration in geologic CO2 storage Citation Details ... induced seismicity and brine migration in geologic CO2 storage Authors: ...

  12. Coupled Model for Heat and Water Transport in a High Level Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and dissolutionprecipitation of the salt in the brine inclusion are simulated; effects of initial inclusion size and temperature gradient on the brine behavior are investigated. ...

  13. Gun below packer completion tool string

    SciTech Connect (OSTI)

    Brieger, E. F.; Colle Jr., E. A.; George, F. R.

    1985-09-03

    A perforating gun is suspended downhole in a cased borehole, in underlying relationship relative to a packer device, and adjacent to a hydrocarbon-bearing formation to be completed. A connecting tubing interconnects the gun with the packer device, and includes a rupture barrier therebetween which prevents debris from accumulating within a gun firing head. An upper tubing string is removably connected to the packer device and forms a passageway which extends from the surface of the earth, down through the packer, and to the gun firing head. The upper tubing string includes a seal means and an extension tube which sealingly engages the packer device and penetrates the rupture barrier to provide a passageway through which the gun can be fired from the surface of the earth. This combination of elements prevents malfunction of the gun when the tool is left downhole for an appreciable length of time.

  14. Signal connection for a downhole tool string

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David S.; Bradford, Kline; Fox, Joe; Briscoe, Michael

    2006-08-29

    A signal transmission connection for a tool string used in exploration and production of natural resources, namely: oil, gas, and geothermal energy resources. The connection comprises first and second annular elements deployed in cooperative association with each other. The respective elements comprise inductive transducers that are capable of two-way signal transmission between each other, with downhole components of the tool string, and with ground-level equipment. The respective inductive transducers comprise one or more conductive loops housed within ferrite troughs, or within ferrite trough segments. When energized, the conductive loops produce a magnetic field suitable for transmitting the signal. The second element may be rotational in drilling applications. The respective elements may be fitted with electronic equipment to aid and manipulate the transmission of the signal. The first element may also be in communication with the World Wide Web.

  15. Obstacle to populating the string theory landscape

    SciTech Connect (OSTI)

    Johnson, Matthew C; Larfors, Magdalena

    2008-12-15

    We construct domain walls and instantons in a class of models with coupled scalar fields, determining, in agreement with previous studies, that many such solutions contain naked timelike singularities. Vacuum bubble solutions of this type do not contain a region of true vacuum, obstructing the ability of eternal inflation to populate other vacua. We determine a criterion that potentials must satisfy to avoid the existence of such singularities and show that many domain wall solutions in type IIB string theory are singular.

  16. String melting in a photon bath

    SciTech Connect (OSTI)

    Karouby, Johanna

    2013-10-01

    We compute the decay rate of a metastable cosmic string in contact with a thermal bath by finding the instanton solution. The new feature is that this decay rate is found in the context of non thermal scalar fields in contact with a thermal bath of photons. In general, to make topologically unstable strings stable, one can couple them to such a bath. The resulting plasma effect creates metastable configurations which can decay from the false vacuum to the true vacuum. In our specific set-up, the instanton computation is realized for the case of two out-of-equilibrium complex scalar fields: one is charged and coupled to the photon field, and the other is neutral. New effects coming from the thermal bath of photons make the radius of the nucleated bubble and most of the relevant physical quantities temperature-dependent. However, the temperature appears in a different way than in the purely thermal case, where all scalar fields are in thermal equilibrium. As a result of the tunneling, the core of the initial string melts while bubbles of true vacuum expand at the speed of light.

  17. Cosmic strings in hidden sectors: 2. Cosmological and astrophysical signatures

    SciTech Connect (OSTI)

    Long, Andrew J.; Vachaspati, Tanmay E-mail: tvachasp@asu.edu

    2014-12-01

    Cosmic strings can arise in hidden sector models with a spontaneously broken Abelian symmetry group. We have studied the couplings of the Standard Model fields to these so-called dark strings in the companion paper. Here we survey the cosmological and astrophysical observables that could be associated with the presence of dark strings in our universe with an emphasis on low-scale models, perhaps TeV . Specifically, we consider constraints from nucleosynthesis and CMB spectral distortions, and we calculate the predicted fluxes of diffuse gamma ray cascade photons and cosmic rays. For strings as light as TeV, we find that the predicted level of these signatures is well below the sensitivity of the current experiments, and therefore low scale cosmic strings in hidden sectors remain unconstrained. Heavier strings with a mass scale in the range 10{sup 13} GeV to 10{sup 15} GeV are at tension with nucleosynthesis constraints.

  18. Cosmic strings in hidden sectors: 2. Cosmological and astrophysical signatures

    SciTech Connect (OSTI)

    Long, Andrew J.; Vachaspati, Tanmay

    2014-12-18

    Cosmic strings can arise in hidden sector models with a spontaneously broken Abelian symmetry group. We have studied the couplings of the Standard Model fields to these so-called dark strings in the companion paper. Here we survey the cosmological and astrophysical observables that could be associated with the presence of dark strings in our universe with an emphasis on low-scale models, perhaps TeV. Specifically, we consider constraints from nucleosynthesis and CMB spectral distortions, and we calculate the predicted fluxes of diffuse gamma ray cascade photons and cosmic rays. For strings as light as TeV, we find that the predicted level of these signatures is well below the sensitivity of the current experiments, and therefore low scale cosmic strings in hidden sectors remain unconstrained. Heavier strings with a mass scale in the range 10{sup 13} GeV to 10{sup 15} GeV are at tension with nucleosynthesis constraints.

  19. The Hubble Web: The Dark Matter Problem and Cosmic Strings

    SciTech Connect (OSTI)

    Alexander, Stephon

    2009-07-06

    I propose a reinterpretation of cosmic dark matter in which a rigid network of cosmic strings formed at the end of inflation. The cosmic strings fulfill three functions: At recombination they provide an accretion mechanism for virializing baryonic and warm dark matter into disks. These cosmic strings survive as configurations which thread spiral and elliptical galaxies leading to the observed flatness of rotation curves and the Tully-Fisher relation. We find a relationship between the rotational velocity of the galaxy and the string tension and discuss the testability of this model.

  20. Three-Dimensional Crystallization of Vortex Strings in Frustrated...

    Office of Scientific and Technical Information (OSTI)

    Three-Dimensional Crystallization of Vortex Strings in Frustrated Quantum Magnets Citation Details In-Document Search This content will become publicly available on August 31, 2016 ...

  1. Property:Incentive/StartDateString | Open Energy Information

    Open Energy Info (EERE)

    Pages using the property "IncentiveStartDateString" Showing 25 pages using this property. (previous 25) (next 25) 3 30% Business Tax Credit for Solar (Vermont) +...

  2. Supersymmetry of Green-Schwarz superstring and matrix string theory

    SciTech Connect (OSTI)

    Hyun, Seungjoon; Shin, Hyeonjoon

    2001-08-15

    We study the dynamics of a Green-Schwarz superstring on the gravitational wave background corresponding to the matrix string theory and the supersymmetry transformation rules of the superstring. The dynamics is obtained in the light-cone formulation and is shown to agree with that derived from matrix string theory. The supersymmetry structure has corrections due to the effect of the background and is identified with that of the low-energy one-loop effective action of matrix string theory in a two superstring background in the weak string coupling limit.

  3. CMB ISW-lensing bispectrum from cosmic strings

    SciTech Connect (OSTI)

    Yamauchi, Daisuke; Sendouda, Yuuiti; Takahashi, Keitaro E-mail: sendouda@cc.hirosaki-u.ac.jp

    2014-02-01

    We study the effect of weak lensing by cosmic (super-)strings on the higher-order statistics of the cosmic microwave background (CMB). A cosmic string segment is expected to cause weak lensing as well as an integrated Sachs-Wolfe (ISW) effect, the so-called Gott-Kaiser-Stebbins (GKS) effect, to the CMB temperature fluctuation, which are thus naturally cross-correlated. We point out that, in the presence of such a correlation, yet another kind of the post-recombination CMB temperature bispectra, the ISW-lensing bispectra, will arise in the form of products of the auto- and cross-power spectra. We first present an analytic method to calculate the autocorrelation of the temperature fluctuations induced by the strings, and the cross-correlation between the temperature fluctuation and the lensing potential both due to the string network. In our formulation, the evolution of the string network is assumed to be characterized by the simple analytic model, the velocity-dependent one scale model, and the intercommutation probability is properly incorporated in order to characterize the possible superstringy nature. Furthermore, the obtained power spectra are dominated by the Poisson-distributed string segments, whose correlations are assumed to satisfy the simple relations. We then estimate the signal-to-noise ratios of the string-induced ISW-lensing bispectra and discuss the detectability of such CMB signals from the cosmic string network. It is found that in the case of the smaller string tension, Gμ << 10{sup -7}, the ISW-lensing bispectrum induced by a cosmic string network can constrain the string-model parameters even more tightly than the purely GKS-induced bispectrum in the ongoing and future CMB observations on small scales.

  4. Early reionization by cosmic strings reexamined

    SciTech Connect (OSTI)

    Pogosian, Levon; Vilenkin, Alexander

    2004-09-15

    Measurements of the Cosmic Microwave Background (CMB) temperature anisotropy and the temperature-polarization cross correlation by Wilkinson Microwave Anistropy Probe (WMAP) suggest a reionization redshift of z{approx}17{+-}5. On the other hand, observations of high redshift galaxies indicate a presence of a significant fraction of neutral hydrogen at redshift z{approx}6-7. We show that cosmic strings with tensions well within, but not far from, current observation bounds could cause early star formation at a level sufficient to explain the high reionization redshift.

  5. From Decay to Complete Breaking: Pulling the Strings in SU(2) Yang-Mills Theory

    SciTech Connect (OSTI)

    Pepe, M.; Wiese, U.-J.

    2009-05-15

    We study (2Q+1) strings connecting two static charges Q in (2+1)D SU(2) Yang-Mills theory. While the fundamental (2) string between two charges Q=(1/2) is unbreakable, the adjoint (3) string connecting two charges Q=1 can break. When a (4) string is stretched beyond a critical length, it decays into a (2) string by gluon pair creation. When a (5) string is stretched, it first decays into a (3) string, which eventually breaks completely. The energy of the screened charges at the ends of a string is well described by a phenomenological constituent gluon model.

  6. From string theory to algebraic geometry and back

    SciTech Connect (OSTI)

    Brinzanescu, Vasile

    2011-02-10

    We describe some facts in physics which go up to the modern string theory and the related concepts in algebraic geometry. Then we present some recent results on moduli-spaces of vector bundles on non-Kaehler Calabi-Yau 3-folds and their consequences for heterotic string theory.

  7. Resonant acoustic transducer system for a well drilling string

    DOE Patents [OSTI]

    Kent, William H.; Mitchell, Peter G.

    1981-01-01

    For use in transmitting acoustic waves propagated along a well drilling string, a piezoelectric transducer is provided operating in the relatively low loss acoustic propagation range of the well drilling string. The efficiently coupled transmitting transducer incorporates a mass-spring-piezoelectric transmitter combination permitting resonant operation in the desired low frequency range.

  8. Resonant acoustic transducer system for a well drilling string

    DOE Patents [OSTI]

    Nardi, Anthony P.

    1981-01-01

    For use in transmitting acoustic waves propated along a well drilling string, a piezoelectric transducer is provided operating in the relatively low loss acoustic propagation range of the well drilling string. The efficiently coupled transmitting transducer incorporates a mass-spring-piezoelectric transmitter combination permitting a resonant operation in the desired low frequency range.

  9. String stabilized ribbon growth a method for seeding same

    DOE Patents [OSTI]

    Sachs, Emanuel M. (39 Harding Ave., Belmont, MA 02178)

    1987-08-25

    This invention is a method of initiating or seeding the growth of a crystalline or polycrystalline ribbon by the String Stabilized Ribbon Growth Method. The method for seeding the crystal growth comprises contacting a melt surface with a seed and two strings used in edge stabilization. The wetted strings attach to the wetted seed as a result of the freezing of the liquid melt. Upon drawing the seed, which is attached to the strings, away from the melt surface a melt liquid meniscus, a seed junction, and a growth interface forms. Further pulling of the attached seed causes a crystal ribbon to grow at the growth interface. The boundaries of the growing ribbon are: at the top the seed junction, at the bottom the freezing boundary of the melt liquid meniscus, and at the edges frozen-in strings.

  10. Pre-inflationary clues from String Theory?

    SciTech Connect (OSTI)

    Kitazawa, N.; Sagnotti, A. E-mail: sagnotti@sns.it

    2014-04-01

    ''Brane supersymmetry breaking'' occurs in String Theory when the only available combinations of D-branes and orientifolds are not mutually BPS and yet do not introduce tree-level tachyon instabilities. It is characterized by the emergence of a steep exponential potential, and thus by the absence of maximally symmetric vacua. The corresponding low-energy supergravity admits intriguing spatially-flat cosmological solutions where a scalar field is forced to climb up toward the steep potential after an initial singularity, and additional milder terms can inject an inflationary phase during the ensuing descent. We show that, in the resulting power spectra of scalar perturbations, an infrared suppression is typically followed by a pre-inflationary peak that reflects the end of the climbing phase and can lie well apart from the approximately scale invariant profile. A first look at WMAP9 raw data shows that, while the χ{sup 2} fits for the low-ℓ CMB angular power spectrum are clearly compatible with an almost scale invariant behavior, they display nonetheless an eye-catching preference for this type of setting within a perturbative string regime.

  11. Conformable apparatus in a drill string

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David S.; Fox, Joe

    2007-08-28

    An apparatus in a drill string comprises an internally upset drill pipe. The drill pipe comprises a first end, a second end, and an elongate tube intermediate the first and second ends. The elongate tube and the ends comprising a continuous an inside surface with a plurality of diameters. A conformable metal tube is disposed within the drill pipe intermediate the ends thereof and terminating adjacent to the ends of the drill pipe. The conformable metal tube substantially conforms to the continuous inside surface of the metal tube. The metal tube may comprise a non-uniform section which is expanded to conform to the inside surface of the drill pipe. The non-uniform section may comprise protrusions selected from the group consisting of convolutions, corrugations, flutes, and dimples. The non-uniform section extends generally longitudinally along the length of the tube. The metal tube may be adapted to stretch as the drill pipes stretch.

  12. Width of the Confining String in Yang-Mills Theory

    SciTech Connect (OSTI)

    Gliozzi, F.; Pepe, M.; Wiese, U.-J.

    2010-06-11

    We investigate the transverse fluctuations of the confining string connecting two static quarks in (2+1)D SU(2) Yang-Mills theory using Monte Carlo calculations. The exponentially suppressed signal is extracted from the large noise by a very efficient multilevel algorithm. The resulting width of the string increases logarithmically with the distance between the static quark charges. Corrections at intermediate distances due to universal higher-order terms in the effective string action are calculated analytically. They accurately fit the numerical data.

  13. Finding Transition Pathways Using the String Method with Swarms of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trajectories | Argonne Leadership Computing Facility Finding Transition Pathways Using the String Method with Swarms of Trajectories Authors: Pan, A.C., Sezer, D., Roux, B. An approach to find transition pathways in complex systems is presented. The method, which is related to the string method in collective variables of Maragliano et al. (J. Chem. Phys. 2006, 125, 024106), is conceptually simple and straightforward to implement. It consists of refining a putative transition path in the

  14. Shooting string holography of jet quenching at RHIC and LHC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ficnar, Andrej; Gubser, Steven S.; Gyulassy, Miklos

    2014-10-13

    We derive a new formula for jet energy loss using finite endpoint momentum shooting strings initial conditions in SYM plasmas to overcome the difficulties of previous falling string holographic scenarios. We apply the new formula to compute the nuclear modification factor RAA and the elliptic flow parameter v2 of light hadrons at RHIC and LHC. We show furthermore that GaussBonnet quadratic curvature corrections to the AdS5 geometry improve the agreement with the recent data.

  15. Gravitational radiation from rotating monopole-string systems

    SciTech Connect (OSTI)

    Babichev, E.; Dokuchaev, V.; Kachelriess, M.

    2005-02-15

    We study the gravitational radiation from a rotating monopole-antimonopole pair connected by a string. While at not too high frequencies the emitted gravitational spectrum is described asymptotically by P{sub n}{proportional_to}n{sup -1}, the spectrum is exponentially suppressed in the high-frequency limit, P{sub n}{proportional_to}exp(-n/n{sub cr}). Below n{sub cr}, the emitted spectrum of gravitational waves is very similar to the case of an oscillating monopole pair connected by a string, and we argue, therefore, that the spectrum found holds approximately for any moving monopole-string system. As an application, we discuss the stochastic gravitational wave background generated by monopole-antimonopole pairs connected by strings in the early Universe and gravitational wave bursts emitted at present by monopole-string networks. We confirm that advanced gravitational wave detectors have the potential to detect a signal for string tensions as small as G{mu}{approx}10{sup -13}.

  16. Dynamics of cosmic strings with higher-dimensional windings

    SciTech Connect (OSTI)

    Yamauchi, Daisuke; Lake, Matthew J.

    2015-06-11

    We consider F-strings with arbitrary configurations in the Minkowski directions of a higher-dimensional spacetime, which also wrap and spin around S{sup 1} subcycles of constant radius in an arbitrary internal manifold, and determine the relation between the higher-dimensional and the effective four-dimensional quantities that govern the string dynamics. We show that, for any such configuration, the motion of the windings in the compact space may render the string effectively tensionless from a four-dimensional perspective, so that it remains static with respect to the large dimensions. Such a critical configuration occurs when (locally) exactly half the square of the string length lies in the large dimensions and half lies in the compact space. The critical solution is then seen to arise as a special case, in which the wavelength of the windings is equal to their circumference. As examples, long straight strings and circular loops are considered in detail, and the solutions to the equations of motion that satisfy the tensionless condition are presented. These solutions are then generalized to planar loops and arbitrary three-dimensional configurations. Under the process of dimensional reduction, in which higher-dimensional motion is equivalent to an effective worldsheet current (giving rise to a conserved charge), this phenomenon may be seen as the analogue of the tensionless condition which arises for superconducting and chiral-current carrying cosmic strings.

  17. Cosmic super-strings and Kaluza-Klein modes

    SciTech Connect (OSTI)

    Dufaux, Jean-Franois

    2012-09-01

    Cosmic super-strings interact generically with a tower of relatively light and/or strongly coupled Kaluza-Klein (KK) modes associated with the geometry of the internal space. In this paper, we study the production of spin-2 KK particles by cusps on loops of cosmic F- and D-strings. We consider cosmic super-strings localized either at the bottom of a warped throat or in a flat internal space with large volume. The total energy emitted by cusps in KK modes is comparable in both cases, although the number of produced KK modes may differ significantly. We then show that KK emission is constrained by the photo-dissociation of light elements and by observations of the diffuse gamma ray background. We show that this rules out regions of the parameter space of cosmic super-strings that are complementary to the regions that can be probed by current and upcoming gravitational wave experiments. KK modes are also expected to play an important role in the friction-dominated epoch of cosmic super-string evolution.

  18. Theoretical Research in Cosmology, High-Energy Physics and String Theory

    SciTech Connect (OSTI)

    Ng, Y Jack; Dolan, Louise; Mersini-Houghton, Laura; Frampton, Paul

    2013-07-29

    The research was in the area of Theoretical Physics: Cosmology, High-Energy Physics and String Theory

  19. Parabosonic string and space-time non-commutativity

    SciTech Connect (OSTI)

    Seridi, M. A.; Belaloui, N.

    2012-06-27

    We investigate the para-quantum extension of the bosonic strings in a non-commutative space-time. We calculate the trilinear relations between the mass-center variables and the modes and we derive the Virasoro algebra where a new anomaly term due to the non-commutativity is obtained.

  20. Flux-induced Isometry Gauging in Heterotic Strings

    SciTech Connect (OSTI)

    Chuang, Wu-yen; Gao, Peng

    2007-01-05

    We study the effect of flux-induced isometry gauging of the scalar manifold in N = 2 heterotic string compactification with gauge fluxes. We show that a vanishing theorem by Witten provides the protection mechanism. The other ungauged isometries in hyper moduli space could also be protected, depending on the gauge bundle structure. We also discuss the related issue in IIB setting.

  1. Test report for drill string seal pressure test

    SciTech Connect (OSTI)

    McCormick, J.F.

    1996-02-06

    A basic question was asked concerning the drill string which is used in rotary Mode coring operations: ``...what is the volume leak rate loss in a drill rod string under varying condiditons of the joint boxes and pins being either dry or coated with lubricant...``. A Variation of this was to either have an o-ring installed or absent on the drill rod that was grooved on the pin. A series of tests were run with both the o-ring grooved Longyear drill rod and the plain pin end rod manufactured by Diamond Drill. Test results show that drill rod leakage of both types is lowered dramatically when thread lubricant is applied to the threaded joints and the joints made up tight. The Diamond Drill rod with no o-ring groove has virtually no leakage when used with thread lubricant and the joints are properly tightened.

  2. Open parabosonic string theory between two parallel Dp-branes

    SciTech Connect (OSTI)

    Hamam, D.; Belaloui, N.

    2012-06-27

    We investigate an open parabosonic string theory between two parallel Dp-branes. The spectrum is constructed and the partition function is derived. A common chord between the development of this latter and the degeneracy of the states for each mass level is obtained. The theory is consistent and with no tachyon. The Virasoro algebra is derived and compared to the one of the ordinary case.

  3. Modeling coiled tubing velocity strings for gas wells

    SciTech Connect (OSTI)

    Martinez, J.; Martinez, A.

    1995-12-31

    Multiphase flowing pressure and velocity prediction models are necessary to coiled tubing velocity string design. A model used by most of the coiled tubing service companies or manufacturers is reviewed. Guidance is provided for selecting a coiled tubing of the proper size. The steps include: (1) Measured data matching; (2) Fluid property adjustment; (3) Pressure, velocity, and holdup selection; (4) Correlation choice; (5) Coiled tubing selection. A velocity range for the lift of liquid is given.

  4. Effective Supergravity from the Weakly Coupled HeteroticString

    SciTech Connect (OSTI)

    Gaillard, Mary K.

    2005-05-01

    The motivation for Calabi-Yau-like compactifications of the weakly coupled E{sub 8} {circle_times} E{sub 8} heterotic string theory, its particle spectrum and the issue of dilaton stabilization are briefly reviewed. Modular invariant models for hidden sector condensation and supersymmetry breaking are described at the quantum level of the effective field theory. Their phenomenological and cosmological implications, including a possible origin for R-parity, are discussed.

  5. Geometric Transitions, Topological Strings, and Generalized Complex Geometry

    SciTech Connect (OSTI)

    Chuang, Wu-yen; /SLAC /Stanford U., Phys. Dept.

    2007-06-29

    Mirror symmetry is one of the most beautiful symmetries in string theory. It helps us very effectively gain insights into non-perturbative worldsheet instanton effects. It was also shown that the study of mirror symmetry for Calabi-Yau flux compactification leads us to the territory of ''Non-Kaehlerity''. In this thesis we demonstrate how to construct a new class of symplectic non-Kaehler and complex non-Kaehler string theory vacua via generalized geometric transitions. The class admits a mirror pairing by construction. From a variety of sources, including super-gravity analysis and KK reduction on SU(3) structure manifolds, we conclude that string theory connects Calabi-Yau spaces to both complex non-Kaehler and symplectic non-Kaehler manifolds and the resulting manifolds lie in generalized complex geometry. We go on to study the topological twisted models on a class of generalized complex geometry, bi-Hermitian geometry, which is the most general target space for (2, 2) world-sheet theory with non-trivial H flux turned on. We show that the usual Kaehler A and B models are generalized in a natural way. Since the gauged supergravity is the low energy effective theory for the compactifications on generalized geometries, we study the fate of flux-induced isometry gauging in N = 2 IIA and heterotic strings under non-perturbative instanton effects. Interestingly, we find we have protection mechanisms preventing the corrections to the hyper moduli spaces. Besides generalized geometries, we also discuss the possibility of new NS-NS fluxes in a new doubled formalism.

  6. CERN Winter School on Supergravity, Strings, and Gauge Theory 2010

    ScienceCinema (OSTI)

    None

    2011-10-06

    The CERN Winter School on Supergravity, Strings, and Gauge Theory is the analytic continuation of the yearly training school of the former EC-RTN string network "Constituents, Fundamental Forces and Symmetries of the Universe". The 2010 edition of the school is supported and organized by the CERN Theory Divison, and will take place from Monday January 25 to Friday January 29, at CERN. As its predecessors, this school is meant primarily for training of doctoral students and young postdoctoral researchers in recent developments in theoretical high-energy physics and string theory. The programme of the school will consist of five series of pedagogical lectures, complemented by tutorial discussion sessions in the afternoons. Previous schools in this series were organized in 2005 at SISSA in Trieste, and in 2006, 2007, 2008, and 2009 at CERN, Geneva. Other similar schools have been organized in the past by the former related RTN network "The Quantum Structure of Spacetime and the Geometric Nature of Fundamental Interactions". This edition of the school is not funded by the European Union. The school is funded by the CERN Theory Division, and the Arnold Sommerfeld Center at Ludwig-Maximilians University of Munich. Scientific committee: M. Gaberdiel, D. Luest, A. Sevrin, J. Simon, K. Stelle, S. Theisen, A. Uranga, A. Van Proeyen, E. Verlinde Local organizers: A. Uranga, J. Walcher

  7. Interpolating the Coulomb phase of little string theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Ying -Hsuan; Shao, Shu -Heng; Wang, Yifan; Yin, Xi

    2015-12-03

    We study up to 8-derivative terms in the Coulomb branch effective action of (1,1) little string theory, by collecting results of 4-gluon scattering amplitudes from both perturbative 6D super-Yang-Mills theory up to 4-loop order, and tree-level double scaled little string theory (DSLST). In previous work we have matched the 6-derivative term from the 6D gauge theory to DSLST, indicating that this term is protected on the entire Coulomb branch. The 8-derivative term, on the other hand, is unprotected. In this paper we compute the 8-derivative term by interpolating from the two limits, near the origin and near the infinity onmore » the Coulomb branch, numerically from SU(k) SYM and DSLST respectively, for k=2,3,4,5. We discuss the implication of this result on the UV completion of 6D SYM as well as the strong coupling completion of DSLST. As a result, we also comment on analogous interpolating functions in the Coulomb phase of circle-compactified (2,0) little string theory.« less

  8. Experiences with string matching on the Fermi Architecture

    SciTech Connect (OSTI)

    Tumeo, Antonino; Secchi, Simone; Villa, Oreste

    2011-02-25

    String matching is at the core of many real-world applications, such as security, bioinformatic, data mining. All these applications requires the ability to match always growing data sets against large dictionaries effectively, fastly and possibly in real time. Unfortunately, string matching is a computationally intensive procedure which poses significant challenges on current software and hardware implementations. Graphic Processing Units (GPU) have become an interesting target for such high-throughput applications, but the algorithms and the data structures need to be redesigned to be parallelized and adapted to the underlining hardware, coping with the limitations imposed by these architectures. In this paper we present an efficient implementation of the Aho-Corasick string matching algorithm on GPU, showing how we progressively redesigned the algorithm and the data structures to fit on the architecture. We then evaluate the implementation on single and multiple Tesla C2050 (T20 ``Fermi'' based) boards, comparing them to the previous Tesla C1060 (T10 based) solutions and equivalent multicore implementations on x86 CPUs. We discuss the various tradeoffs of the different architectures.

  9. Portable apparatus and method for assisting in the removal and emplacement of pipe strings in boreholes

    DOE Patents [OSTI]

    Mitchell, Brian R.

    2005-03-22

    A portable pipe installation/removal support apparatus for assisting in the installation/removal of a series of connectable pipe strings from a ground-level borehole. The support apparatus has a base, an upright extending from the base, and, in an exemplary embodiment, a pair of catch arms extending from the upright to define a catch platform. The pair of catch arms serves to hold an upper connector end of a pipe string at an operator-convenient standing elevation by releasably catching an underside of a pipe coupler connecting two pipe strings of the series of connectable pipe strings. This enables an operator to stand upright while coupling/uncoupling the series of connectable pipe strings during the installation/removal thereof from the ground-level borehole. Additionally, a process for installing and a process for removing a series of connectable pipe strings is disclosed utilizing such a support apparatus.

  10. Resonant acoustic transducer and driver system for a well drilling string communication system

    DOE Patents [OSTI]

    Chanson, Gary J.; Nicolson, Alexander M.

    1981-01-01

    The acoustic data communication system includes an acoustic transmitter and receiver wherein low frequency acoustic waves, propagating in relatively loss free manner in well drilling string piping, are efficiently coupled to the drill string and propagate at levels competitive with the levels of noise generated by drilling machinery also present in the drill string. The transmitting transducer incorporates a mass-spring piezoelectric transmitter and amplifier combination that permits self-oscillating resonant operation in the desired low frequency range.

  11. Topological fermionic string representation for Chern-Simons non-Abelian gauge theories

    SciTech Connect (OSTI)

    Botelho, L.C.L. )

    1990-05-15

    We show that loop wave equations in non-Abelian Chern-Simons gauge theory are exactly solved by a conformally invariant topological fermionic string theory.

  12. U-092: Sudo Format String Bug Lets Local Users Gain Elevated Privileges

    Broader source: Energy.gov [DOE]

    A local user can supply a specially crafted command line argument to trigger a format string flaw and execute arbitrary commands on the target system with root privileges.

  13. Five-dimensional black strings in Einstein-Gauss-Bonnet gravity

    SciTech Connect (OSTI)

    Kobayashi, Tsutomu; Tanaka, Takahiro

    2005-04-15

    We consider black-string-type solutions in five-dimensional Einstein-Gauss-Bonnet gravity. Numerically constructed solutions under static, axially symmetric and translationally invariant metric ansatz are presented. The solutions are specified by two asymptotic charges: mass of a black string and a scalar charge associated with the radion part of the metric. Regular black string solutions are found if and only if the two charges satisfy a fine-tuned relation, and otherwise the spacetime develops a singular event horizon or a naked singularity. We can also generate bubble solutions from the black strings by using a double Wick rotation.

  14. Efficient Aho-Corasick String Matching on Emerging Multicore Architectures

    SciTech Connect (OSTI)

    Tumeo, Antonino; Villa, Oreste; Secchi, Simone; Chavarría-Miranda, Daniel

    2013-12-12

    String matching algorithms are critical to several scientific fields. Beside text processing and databases, emerging applications such as DNA protein sequence analysis, data mining, information security software, antivirus, ma- chine learning, all exploit string matching algorithms [3]. All these applica- tions usually process large quantity of textual data, require high performance and/or predictable execution times. Among all the string matching algorithms, one of the most studied, especially for text processing and security applica- tions, is the Aho-Corasick algorithm. 1 2 Book title goes here Aho-Corasick is an exact, multi-pattern string matching algorithm which performs the search in a time linearly proportional to the length of the input text independently from pattern set size. However, depending on the imple- mentation, when the number of patterns increase, the memory occupation may raise drastically. In turn, this can lead to significant variability in the performance, due to the memory access times and the caching effects. This is a significant concern for many mission critical applications and modern high performance architectures. For example, security applications such as Network Intrusion Detection Systems (NIDS), must be able to scan network traffic against very large dictionaries in real time. Modern Ethernet links reach up to 10 Gbps, and malicious threats are already well over 1 million, and expo- nentially growing [28]. When performing the search, a NIDS should not slow down the network, or let network packets pass unchecked. Nevertheless, on the current state-of-the-art cache based processors, there may be a large per- formance variability when dealing with big dictionaries and inputs that have different frequencies of matching patterns. In particular, when few patterns are matched and they are all in the cache, the procedure is fast. Instead, when they are not in the cache, often because many patterns are matched and the caches are

  15. Corrosion Resistances of Iron-Based Amorphous Metals with Yttrium and Tungsten Additions in Hot Calcium Chloride Brine & Natural Seawater: Fe48Mo14Cr15Y2C15B6 and W-Containing Variants

    SciTech Connect (OSTI)

    Farmer, J C; Haslam, J; Day, S; Lian, T; Saw, C; Hailey, P; Choi, J; Yang, N; Blue, C; Peter, W; Payer, J; Branagan, D J

    2006-10-20

    Yttrium-containing SAM1651 (Fe{sub 48.0}Cr{sub 15.0}Mo{sub 14.0}B{sub 6.0}C{sub 15.0}Y{sub 2.0}), has a critical cooling rate (CCR) of approximately 80 Kelvin per second, while SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) with no yttrium has a higher critical cooling rate of approximately 600 Kelvin per second. SAM1651's low CCR enables it to be rendered as a completely amorphous material in practical materials processes. Chromium (Cr), molybdenum (Mo) and tungsten (W) provide corrosion resistance; boron (B) enables glass formation; and rare earths such as yttrium (Y) lower critical cooling rate (CCR). The passive film stability of these Fe-based amorphous metal formulations have been found to be superior to that of conventional stainless steels, and comparable to that of Ni-based alloys, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates.

  16. Ripple distribution in magnet strings of Super Collider

    SciTech Connect (OSTI)

    Smedley, K. ); Jayasuriya, A. ); Christiansen, C. ); Shafer, R. )

    1994-08-01

    The voltage ripple in the power supplies of the Collider generate ripple current in the magnet coil that, in turn, generates ripple in the magnetic field of dipoles and quadrupoles. The ripple in the magnetic field will be a function of time and space due to the transmission line effect. The work reported in this paper gives a thorough analysis the frequency spectrum and the spatial propagation pattern of the differential mode ripple in the magnet strings for the injection mode and the collider mode.

  17. System and method for damping vibration in a drill string

    DOE Patents [OSTI]

    Wassell, Mark Ellsworth; Turner, William Evans; Burgess, Daniel E.; Perry, Carl Allison

    2007-05-22

    A system for damping vibration in a drill string can include a valve assembly having a supply of a fluid, a first member, and a second member capable of moving in relation to first member in response to vibration of the drill bit. The first and second members define a first and a second chamber for holding the fluid. Fluid can flow between the first and second chambers in response to the movement of the second member in relation to the first member. The valve assembly can also include a coil or a valve for varying a resistance of the fluid to flow between the first and second chambers.

  18. System and method for damping vibration in a drill string

    DOE Patents [OSTI]

    Wassell, Mark Ellsworth; Turner, William Evans; Burgess, Daniel E.; Perry, Carl Allison

    2012-08-14

    A system for damping vibration in a drill string can include a valve assembly having a supply of a fluid, a first member, and a second member capable of moving in relation to first member in response to vibration of the drill bit. The first and second members define a first and a second chamber for holding the fluid. Fluid can flow between the first and second chambers in response to the movement of the second member in relation to the first member. The valve assembly can also include a coil or a valve for varying a resistance of the fluid to flow between the first and second chambers.

  19. System and method for damping vibration in a drill string

    DOE Patents [OSTI]

    Wassell, Mark Ellsworth; Turner, William Evans; Burgess, Daniel E.; Perry, Carl Allison

    2008-05-27

    A system for damping vibration in a drill string can include a valve assembly having a supply of a fluid, a first member, and a second member capable of moving in relation to first member in response to vibration of the drill bit. The first and second members define a first and a second chamber for holding the fluid. Fluid can flow between the first and second chambers in response to the movement of the second member in relation to the first member. The valve assembly can also include a coil or a valve for varying a resistance of the fluid to flow between the first and second chambers.

  20. System and method for damping vibration in a drill string

    DOE Patents [OSTI]

    Wassell, Mark Ellsworth; Turner, William Evans; Burgess, Daniel E; Perry, Carl Allison

    2015-02-03

    A system for damping vibration in a drill string can include a valve assembly having a supply of a fluid, a first member, and a second member capable of moving in relation to first member in response to vibration of the drill bit. The first and second members define a first and a second chamber for holding the fluid. Fluid can flow between the first and second chambers in response to the movement of the second member in relation to the first member. The valve assembly can also include a coil or a valve for varying a resistance of the fluid to flow between the first and second chambers.

  1. System and method for damping vibration in a drill string

    DOE Patents [OSTI]

    Wassell, Mark Ellsworth; Turner, William Evans; Burgess, Daniel E; Perry, Carl Allison

    2014-03-04

    A system for damping vibration in a drill string can include a valve assembly having a supply of a fluid, a first member, and a second member capable of moving in relation to first member in response to vibration of the drill bit. The first and second members define a first and a second chamber for holding the fluid. Fluid can flow between the first and second chambers in response to the movement of the second member in relation to the first member. The valve assembly can also include a coil or a valve for varying a resistance of the fluid to flow between the first and second chambers.

  2. System and method for damping vibration in a drill string

    DOE Patents [OSTI]

    Wassell, Mark Ellsworth; Turner, William Evans; Burgess, Daniel E.; Perry, Carl Allison

    2011-08-16

    A system for damping vibration in a drill string can include a valve assembly having a supply of a fluid, a first member, and a second member capable of moving in relation to first member in response to vibration of the drill bit. The first and second members define a first and a second chamber for holding the fluid. Fluid can flow between the first and second chambers in response to the movement of the second member in relation to the first member. The valve assembly can also include a coil or a valve for varying a resistance of the fluid to flow between the first and second chambers.

  3. Is it really naked? On cosmic censorship in string theory

    SciTech Connect (OSTI)

    Frolov, Andrei V.

    2004-11-15

    We investigate the possibility of cosmic censorship violation in string theory using a characteristic double-null code, which penetrates horizons and is capable of resolving the spacetime all the way to the singularity. We perform high-resolution numerical simulations of the evolution of negative mass initial scalar field profiles, which were argued to provide a counterexample to cosmic censorship conjecture for AdS-asymptotic spacetimes in five-dimensional supergravity. In no instances formation of naked singularity is seen. Instead, numerical evidence indicates that black holes form in the collapse. Our results are consistent with earlier numerical studies, and explicitly show where the 'no black hole' argument breaks.

  4. Is it Really Naked? On Cosmic Censorship in String Theory

    SciTech Connect (OSTI)

    Frolov, A

    2004-09-30

    We investigate the possibility of cosmic censorship violation in string theory using a characteristic double-null code, which penetrates horizons and is capable of resolving the spacetime all the way to the singularity. We perform high-resolution numerical simulations of the evolution of negative mass initial scalar field profiles, which were argued to provide a counter example to cosmic censorship conjecture for AdS-asymptotic spacetimes in five-dimensional supergravity. In no instances formation of naked singularity is seen. Instead, numerical evidence indicates that black holes form in the collapse. Our results are consistent with earlier numerical studies, and explicitly show where the ''no black hole'' argument breaks.

  5. Operating Experience Summary, 2014-04

    Broader source: Energy.gov (indexed) [DOE]

    that store brine used to displace stored crude oil when the oil is withdrawn from underground caverns. The brine tanks must be repaired and repainted every 3 to 5 years to...

  6. Geochemical engineering reference manual

    SciTech Connect (OSTI)

    Owen, L.B.; Michels, D.E.

    1984-01-01

    The following topics are included in this manual: physical and chemical properties of geothermal brine and steam, scale and solids control, processing spent brine for reinjection, control of noncondensable gas emissions, and goethermal mineral recovery. (MHR)

  7. CX-010404: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Brine Disposal System Header to West Hackberry Brine Tanks, Government Furnished Equipment CX(s) Applied: B1.3 Date: 04/22/2013 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  8. CX-010401: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Brine Disposal System Header to West Hackberry Brine Tanks CX(s) Applied: B1.3 Date: 04/22/2013 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  9. CX-009718: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Brine Disposal System Header to Bryan Mound Brine Tank, GFE CX(s) Applied: B1.3 Date: 12/11/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    fuel cycle and fuel materials (2) radioactive wastes (2) sensitivity (2) simulation (2) water (2) arsenic (1) bentonite (1) boom clay (1) brine leakage (1) brines (1) buffers (1)...

  11. Column Sorption Uptake and Regeneration Study; Rare Earth Element Sorbent Uptake and Sorbent Stripping

    SciTech Connect (OSTI)

    Tim Lanyk

    2015-12-18

    Study of rare earth element (REE) uptake from geothermal brine simulant by column loading, metal recovery through stripping, and regeneration of column for re-loading. Simulated brine testing.

  12. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reaction with CO 2 -brine at 200C (Smith et al, 2013) 2 | US DOE Geothermal Office ... reaction with CO 2 -brine at 200C (Smith et al, 2013) Increased fracture ...

  13. The Viability of Sustainable, Self-Propping Shear Zones in Ehanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reaction with CO 2 -brine at 200C (Smith et al, 2013) 2 | US DOE Geothermal Office ... reaction with CO 2 -brine at 200C (Smith et al, 2013) 7 | US DOE Geothermal Office ...

  14. Cosmic strings as the source of small-scale microwave background anisotropy

    SciTech Connect (OSTI)

    Pogosian, Levon; Tye, S.-H. Henry; Wasserman, Ira; Wyman, Mark E-mail: tye@lepp.cornell.edu E-mail: mwyman@perimeterinstitute.ca

    2009-02-15

    Cosmic string networks generate cosmological perturbations actively throughout the history of the universe. Thus, the string sourced anisotropy of the cosmic microwave background is not affected by Silk damping as much as the anisotropy seeded by inflation. The spectrum of perturbations generated by strings does not match the observed CMB spectrum on large angular scales (l < 1000) and is bounded to contribute no more than 10% of the total power on those scales. However, when this bound is marginally saturated, the anisotropy created by cosmic strings on small angular scales l {approx}> 2000 will dominate over that created by the primary inflationary perturbations. This range of angular scales in the CMB is presently being measured by a number of experiments; their results will test this prediction of cosmic string networks soon.

  15. High redshift signatures in the 21 cm forest due to cosmic string wakes

    SciTech Connect (OSTI)

    Tashiro, Hiroyuki; Sekiguchi, Toyokazu; Silk, Joseph E-mail: toyokazu.sekiguchi@nagoya-u.jp

    2014-01-01

    Cosmic strings induce minihalo formation in the early universe. The resultant minihalos cluster in string wakes and create a ''21 cm forest'' against the cosmic microwave background (CMB) spectrum. Such a 21 cm forest can contribute to angular fluctuations of redshifted 21 cm signals integrated along the line of sight. We calculate the root-mean-square amplitude of the 21 cm fluctuations due to strings and show that these fluctuations can dominate signals from minihalos due to primordial density fluctuations at high redshift (z?>10), even if the string tension is below the current upper bound, G? < 1.5 10{sup ?7}. Our results also predict that the Square Kilometre Array (SKA) can potentially detect the 21 cm fluctuations due to strings with G? ? 7.5 10{sup ?8} for the single frequency band case and 4.0 10{sup ?8} for the multi-frequency band case.

  16. Cosmic strings in hidden sectors: 1. Radiation of standard model particles

    SciTech Connect (OSTI)

    Long, Andrew J.; Hyde, Jeffrey M.; Vachaspati, Tanmay E-mail: jmhyde@asu.edu

    2014-09-01

    In hidden sector models with an extra U(1) gauge group, new fields can interact with the Standard Model only through gauge kinetic mixing and the Higgs portal. After the U(1) is spontaneously broken, these interactions couple the resultant cosmic strings to Standard Model particles. We calculate the spectrum of radiation emitted by these ''dark strings'' in the form of Higgs bosons, Z bosons, and Standard Model fermions assuming that string tension is above the TeV scale. We also calculate the scattering cross sections of Standard Model fermions on dark strings due to the Aharonov-Bohm interaction. These radiation and scattering calculations will be applied in a subsequent paper to study the cosmological evolution and observational signatures of dark strings.

  17. Correlation between dark matter and dark radiation in string compactifications

    SciTech Connect (OSTI)

    Allahverdi, Rouzbeh; Cicoli, Michele; Dutta, Bhaskar; Sinha, Kuver E-mail: mcicoli@ictp.it E-mail: kusinha@syr.edu

    2014-10-01

    Reheating in string compactifications is generically driven by the decay of the lightest modulus which produces Standard Model particles, dark matter and light hidden sector degrees of freedom that behave as dark radiation. This common origin allows us to find an interesting correlation between dark matter and dark radiation. By combining present upper bounds on the effective number of neutrino species N{sub eff} with lower bounds on the reheating temperature as a function of the dark matter mass m{sub DM} from Fermi data, we obtain strong constraints on the (N{sub eff}, m{sub DM})-plane. Most of the allowed region in this plane corresponds to non-thermal scenarios with Higgsino-like dark matter. Thermal dark matter can be allowed only if N{sub eff} tends to its Standard Model value. We show that the above situation is realised in models with perturbative moduli stabilisation where the production of dark radiation is unavoidable since bulk closed string axions remain light and do not get eaten up by anomalous U(1)s.

  18. A new string model (VENUS 2) for hadronic collisions based on color exchange between quarks and antiquarks

    SciTech Connect (OSTI)

    Werner, K.

    1989-05-01

    We describe the latest version of the string model VENUS, taking also into account antiquarks as participants in the color exchange (string flip) process, the basic mechanism to form strings. An important consequence is a rapidity plateau for protons and lambdas in symmetric heavy ion collision contradicting the assumption of transparency. 10 refs., 7 figs.

  19. EA-1482: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Pilot Experiment for Geological Sequestration of Carbon Dioxide in Saline Aquifer Brine Formations, Frio Formation, Liberty County, Texas

  20. Demonstration of a Variable Phase Turbine Power System for Low Temperature Geothermal Resources

    Broader source: Energy.gov [DOE]

    Project objectives: Demonstrate a 1 megawatt Variable Phase Turbine and Variable Phase Cycle with low temperature brine.

  1. Norm removal from frac water

    DOE Patents [OSTI]

    Silva, James Manio; Matis, Hope; Kostedt, IV, William Leonard

    2014-11-18

    A method for treating low barium frac water includes contacting a frac water stream with a radium selective complexing resin to produce a low radium stream, passing the low radium stream through a thermal brine concentrator to produce a concentrated brine; and passing the concentrated brine through a thermal crystallizer to yield road salt.

  2. Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The theoretical analysis is given for calculating the composition of the aqueous vapor and the saline brine (hydrosaline liquid) present at run pressure and temperature in the experiment. The mixture of aqueous vapor and brine is homogenized upon quench. The method for calculating the concentration of HCl and NaCl in the coexisting aqueous vapor and brine is shown.

  3. Implications of fast radio bursts for superconducting cosmic strings

    SciTech Connect (OSTI)

    Yu, Yun-Wei; Cheng, Kwong-Sang; Shiu, Gary; Tye, Henry E-mail: hrspksc@hku.hk E-mail: iastye@ust.hk

    2014-11-01

    Highly beamed, short-duration electromagnetic bursts could be produced by superconducting cosmic string (SCS) loops oscillating in cosmic magnetic fields. We demonstrated that the basic characteristics of SCS bursts such as the electromagnetic frequency and the energy release could be consistently exhibited in the recently discovered fast radio bursts (FRBs). Moreover, it is first showed that the redshift distribution of the FRBs can also be well accounted for by the SCS burst model. Such agreements between the FRBs and SCS bursts suggest that the FRBs could originate from SCS bursts and thus they could provide an effective probe to study SCSs. The obtained values of model parameters indicate that the loops generating the FRBs have a small length scale and they are mostly formed in the radiation-dominated cosmological epoch.

  4. Cosmological and astrophysical constraints on superconducting cosmic strings

    SciTech Connect (OSTI)

    Miyamoto, Koichi; Nakayama, Kazunori E-mail: kazunori@hep-th.phys.s.u-tokyo.ac.jp

    2013-07-01

    We investigate the cosmological and astrophysical constraints on superconducting cosmic strings (SCSs). SCS loops emit strong bursts of electromagnetic waves, which might affect various cosmological and astrophysical observations. We take into account the effect on the CMB anisotropy, CMB blackbody spectrum, BBN, observational implications on radio wave burst and X-ray or ?-ray events, and stochastic gravitational wave background measured by pulsar timing experiments. We then derive constraints on the parameters of SCS from current observations and estimate prospects for detecting SCS signatures in on-going observations. As a result, we find that these constraints exclude broad parameter regions, and also that on-going radio wave observations can probe large parameter space.

  5. Nonreciprocal wave scattering on nonlinear string-coupled oscillators

    SciTech Connect (OSTI)

    Lepri, Stefano; Pikovsky, Arkady

    2014-12-01

    We study scattering of a periodic wave in a string on two lumped oscillators attached to it. The equations can be represented as a driven (by the incident wave) dissipative (due to radiation losses) system of delay differential equations of neutral type. Nonlinearity of oscillators makes the scattering non-reciprocal: The same wave is transmitted differently in two directions. Periodic regimes of scattering are analyzed approximately, using amplitude equation approach. We show that this setup can act as a nonreciprocal modulator via Hopf bifurcations of the steady solutions. Numerical simulations of the full system reveal nontrivial regimes of quasiperiodic and chaotic scattering. Moreover, a regime of a chaotic diode, where transmission is periodic in one direction and chaotic in the opposite one, is reported.

  6. Lectures on the gauge/string duality with emphasis on spectroscopy

    SciTech Connect (OSTI)

    Mateos, David

    2010-11-12

    I review recent progress on the connection between string theory and quantum chromo-dynamics in the context of the gauge/string duality. Emphasis is placed on conciseness and conceptual aspects rather than on technical details. Topics covered include the large-N{sub c} limit of gauge theories, the gravitational description of gauge theory thermodynamics and hydrodynamics, and the physics of quarks and mesons in the quark-gluon plasma.

  7. Methods and systems for determining angular orientation of a drill string

    DOE Patents [OSTI]

    Cobern, Martin E.

    2010-03-23

    Preferred methods and systems generate a control input based on a periodically-varying characteristic associated with the rotation of a drill string. The periodically varying characteristic can be correlated with the magnetic tool face and gravity tool face of a rotating component of the drill string, so that the control input can be used to initiate a response in the rotating component as a function of gravity tool face.

  8. Semiclassical circular strings in AdS{sub 5} and 'long' gauge field strength operators

    SciTech Connect (OSTI)

    Park, I.Y.; Tirziu, A.; Tseytlin, A.A.

    2005-06-15

    We consider circular strings rotating with equal spins S{sub 1}=S{sub 2}=S in two orthogonal planes in AdS{sub 5} and suggest that they may be dual to long gauge-theory operators built out of self-dual components of gauge field strength. As was found in hep-th/0404187, the one-loop anomalous dimensions of the such gauge-theory operators are described by an antiferromagnetic XXX{sub 1} spin chain and scale linearly with length L>>1. We find that in the case of rigid rotating string both the classical energy E{sub 0} and the 1-loop string correction E{sub 1} depend linearly on the spin S (within the stability region of the solution). This supports the identification of the rigid rotating string with the gauge-theory operator corresponding to the maximal-spin (ferromagnetic) state of the XXX{sub 1} spin chain. The energy of more general rotating and pulsating strings also happens to scale linearly with both the spin and the oscillation number. Such solutions should be dual to other lower-spin states of the spin chain, with the antiferromagnetic ground state presumably corresponding to the string pulsating in two planes with no rotation.

  9. Analytical model for CMB temperature angular power spectrum from cosmic (super-)strings

    SciTech Connect (OSTI)

    Yamauchi, Daisuke; Yoo, Chul-Moon; Sasaki, Misao; Takahashi, Keitaro; Sendouda, Yuuiti

    2010-09-15

    We present a new analytical method to calculate the small angle cosmic microwave background (CMB) temperature angular power spectrum due to cosmic (super-)string segments. In particular, using our method, we clarify the dependence on the intercommuting probability P. We find that the power spectrum is dominated by Poisson-distributed string segments. The power spectrum for a general value of P has a plateau on large angular scales and shows a power-law decrease on small angular scales. The resulting spectrum in the case of conventional cosmic strings is in very good agreement with the numerical result obtained by Fraisse et al.. Then we estimate the upper bound on the dimensionless tension of the string for various values of P by assuming that the fraction of the CMB power spectrum due to cosmic (super-)strings is less than ten percent at various angular scales up to l=2000. We find that the amplitude of the spectrum increases as the intercommuting probability. As a consequence, strings with smaller intercommuting probabilities are found to be more tightly constrained.

  10. Coiled tubing velocity string hangoff method and apparatus

    SciTech Connect (OSTI)

    Gipson, T.C.

    1991-07-02

    This patent describes a method for hanging off a coiled tube velocity string in an active gas production well tubing run, the run having at least a master valve and a first line valve. It includes installing a hangoff assembly in the production well tubing run between the master valve and the first line valve the hangoff assembly comprising a hangoff head, a second line valve, an upper valve, and a hydraulic packoff valve, the hangoff head further comprising a threaded body member, a slip bowl and a threaded cap; inserting through the hydraulic packoff valve, the upper valve, and the hangoff head, coiled tubing for fluid communication with well gases and fluids in the production well tubing run, the coiled tubing having a first downhole end being open to immediately receive and conduct the gases and fluids; opening gas and fluid communication between the production well tubing run and the open end of the coiled tubing whereby the well gases and fluid may pass up through the coiled tubing, the hangoff head sealing the gases and fluids from passing to the hydraulic packoff valve, the upper valve and the second line valve; further inserting the coiled tubing to a desired depth in the production well tubing run; and rotating the cap of the hangoff head to expose the slip bowl.

  11. Strings of liquid beads for gas-liquid contact operations

    SciTech Connect (OSTI)

    Hattori, Kenji; Ishikawa, Mitsukuni; Mori, Y.H. . Dept. of Mechanical Engineering)

    1994-12-01

    Energy recovery from hot gases exhausted from power plants, garbage incineration facilities, and many industrial processes has been growing due to demands for saving the primary-energy consumption. A novel device for gas-liquid contact operations is proposed to feed a liquid onto wires (or threads) hanging down in a gas stream is proposed. The liquid disintegrates into beads strung on each wire at regular intervals; if the wire is moderately wettable, a thin film forms to sheathe the wire, thereby interconnecting the beads. Since the beads fall down slowly, which possibly renews the film flowing down even more slowly, a sufficient gas-liquid contact time is available even in a contactor with considerably limited height. An approximate calculation method is developed for predicting the variation in the temperature effectiveness for the liquid (the fractional approach of the liquid exit temperature to the gas inlet temperature) with the falling distance, assuming an applicability of strings-of-beads contactors to thermal energy recovery from hot gas streams.

  12. Evaluation of the corrosivity of dust deposited on waste packages at Yucca Mountain, Nevada.

    SciTech Connect (OSTI)

    Wolery, Thomas J.; Bryan, Charles R.; Barr, Deborah; Jarek, Russell L.; Hardin, Ernest L.; Shields, David R.; Sutton, Mark A.

    2005-08-01

    Potentially corrosive brines can form during post-closure by deliquescence of salt minerals in dust deposited on the surface of waste packages at Yucca Mountain during operations and the pre-closure ventilation period. Although thermodynamic modeling and experimental studies of brine deliquescence indicates that brines are likely to form, they will be nitrate-rich and noncorrosive. Processes that modify the brines following deliquescence are beneficial with respect to inhibition of corrosion. For example, acid degassing (HCl, HNO{sub 3}) could dry out brines, but kinetic limitations are likely to limit the effect to increasing their passivity by raising the pH and increasing the NO{sub 3}/Cl ratio. Predicted dust quantities and maximum brine volumes on the waste package surface are small, and physical isolation of salt minerals in the dust may inhibit formation of eutectic brines and decrease brine volumes. If brines do contact the WP surface, small droplet volumes and layer thicknesses do not support development of diffusive gradients necessary for formation on separate anodic-cathodic zones required for localized corrosion. Finally, should localized corrosion initiate, corrosion product buildup will stifle corrosion, by limiting oxygen access to the metal surface, by capillary retention of brine in corrosion product porosity, or by consumption of brine components (Cl{sup -}).

  13. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, Pascal M.

    1982-01-01

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carry-over through the turbine causes corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  14. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, P.M.

    1979-12-27

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carryover through the turbine causing corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  15. The 21 cm signature of shock heated and diffuse cosmic string wakes

    SciTech Connect (OSTI)

    Hernndez, Oscar F.; Brandenberger, Robert H. E-mail: rhb@physics.mcgill.ca

    2012-07-01

    The analysis of the 21 cm signature of cosmic string wakes is extended in several ways. First we consider the constraints on G? from the absorption signal of shock heated wakes laid down much later than matter radiation equality. Secondly we analyze the signal of diffuse wake, that is those wakes in which there is a baryon overdensity but which have not shock heated. Finally we compare the size of these signals to the expected thermal noise per pixel which dominates over the background cosmic gas brightness temperature and find that the cosmic string signal will exceed the thermal noise of an individual pixel in the Square Kilometre Array for string tensions G? > 2.5 10{sup ?8}.

  16. On the motion of a quantum particle in the spinning cosmic string space–time

    SciTech Connect (OSTI)

    Hassanabadi, H.; Afshardoost, A.; Zarrinkamar, S.

    2015-05-15

    We analyze the energy spectrum and the wave function of a particle subjected to magnetic field in the spinning cosmic string space–time and investigate the influence of the spinning reference frame and topological defect on the system. To do this we solve Schrödinger equation in the spinning cosmic string background. In our work, instead of using an approximation in the calculations, we use the quasi-exact ansatz approach which gives the exact solutions for some primary levels. - Highlights: • Solving the Schrödinger equation in the spinning cosmic string space time. • Proposing a quasi-exact analytical solution to the general form of the corresponding equation. • Generalizing the previous works.

  17. Coiled tubing velocity string set at record 20,500 ft

    SciTech Connect (OSTI)

    Adams, L.S. )

    1992-04-13

    This paper reports that coiled tubing, set at record depth, significantly reduced costs and posed lower mechanical failure risk for recompleting a gas well in the Delaware basin of West Texas. Alternative completions such as replacing the existing tubing string with smaller diameter conventional API production tubing was deemed less economical and effective. The gas well, George M. Shelton No. 2, was recompleted on July 18, 1991, by Chevron U.S.A. Production Co. The gas is produced from the deep, low-pressure Ellenburger formation in the Gomez field. The hang-off depth of 20,500 ft set a world record for the deepest permanently installed coiled tubing. The 1-1/2 in. coiled tubing velocity string, run within the existing 4-1/2 and 4-in. tapered production tubing string, consists of seven segments that vary in wall thickness from 0.087 to 0.156 in.

  18. String loops in the field of braneworld spherically symmetric black holes and naked singularities

    SciTech Connect (OSTI)

    Stuchlk, Z.; Kolo, M. E-mail: martin.kolos@fpf.slu.cz

    2012-10-01

    We study motion of current-carrying string loops in the field of braneworld spherically symmetric black holes and naked singularities. The spacetime is described by the Reissner-Nordstrm geometry with tidal charge b reflecting the non-local tidal effects coming from the external dimension; both positive and negative values of the spacetime parameter b are considered. We restrict attention to the axisymmetric motion of string loops when the motion can be fully governed by an appropriately defined effective potential related to the energy and angular momentum of the string loops. In dependence on these two constants of the motion, the string loops can be captured, trapped, or can escape to infinity. In close vicinity of stable equilibrium points at the centre of trapped states the motion is regular. We describe how it is transformed to chaotic motion with growing energy of the string loop. In the field of naked singularities the trapped states located off the equatorial plane of the system exist and trajectories unable to cross the equatorial plane occur, contrary to the trajectories in the field of black holes where crossing the equatorial plane is always admitted. We concentrate our attention to the so called transmutation effect when the string loops are accelerated in the deep gravitational field near the black hole or naked singularity by transforming the oscillatory energy to the energy of the transitional motion. We demonstrate that the influence of the tidal charge can be substantial especially in the naked singularity spacetimes with b > 1 where the acceleration to ultrarelativistic velocities with Lorentz factor ? ? 100 can be reached, being more than one order higher in comparison with those obtained in the black hole spacetimes.

  19. Cosmological and wormhole solutions in low-energy effective string theory

    SciTech Connect (OSTI)

    Cadoni, M. INFN, Sezione di Cagliari, Via Ada Negri 18, I---09127 Cagliari ); Cavaglia, M. INFN, Sezione di Cagliari, Via Ada Negri 18, I-09127 Cagliari )

    1994-11-15

    We derive and study a class of cosmological and wormhole solutions of low-energy effective string field theory. We consider a general four-dimensional string effective action where moduli of the compactified manifold and the electromagnetic field are present. The cosmological solutions of the two-dimensional effective theory obtained by dimensional reduction of the former are discussed. In particular we demonstrate that the two-dimensional theory possesses a scale-factor duality invariance. Eucidean four-dimensional instantons describing the nucleation of the baby universes are found and the probability amplitude for the nucleation process given.

  20. Full-power test of a string of magnets comprising a half-cell of the Superconducting Super Collider

    SciTech Connect (OSTI)

    Burgett, W.; Christianson, M.; Coombes, R.

    1992-10-01

    In this paper we describe the full-powered operation of a string of industrially-fabricated magnets comprising a half-cell of the Superconducting Super Collider (SSC). The completion of these tests marks the first successful operation of a major SSC subsystem. The five 15-m long dipole magnets in the string had an aperture of 50 mm and the single 5-m long quadrupole aperture was 40 mm. Power and cryogenic connections were made to the string through spool pieces that are prototypes for SSC operations. The string was cooled to cryogenic temperatures in early July, 1992, and power tests were performed at progressively higher currents up to the nominal SSC operating point above 6500 amperes achieved in mid-August. In this paper we report on the electrical and cryogenic performance of the string components and the quench protection system during these initial tests.

  1. Effect of temperature, salinity and oil composition on wetting behavior and oil recovery by waterflooding

    SciTech Connect (OSTI)

    Tang, G.Q.; Morrow, N.R.

    1996-12-31

    The effect of aging and displacement temperatures, and brine and oil composition on wettability and the recovery of crude oil by spontaneous imbibition and waterflooding has been investigated. This study is based on displacement tests in Berea Sandstone using three distinctly different crude oils and three reservoir brines. Brine concentration was varied by changing the concentration of total dissolved solids of the synthetic brine in proportion to give brine of twice, one tenth, and one hundredth of the reservoir brine concentration. Aging and displacement temperatures were varied independently. For all crude oils, water-wetness and oil recovery increased with increase in displacement temperature. Tests on the effect of brine concentration showed that salinity of the connate and invading brines can have a major influence on wettability and oil recovery at reservoir temperature. Oil recovery increased over that for the reservoir brine with dilution of both the initial (connate) and invading brine or dilution of either. Removal of light components from the crude oil resulted in increased water-wetness. Addition of alkanes to the crude oil reduced the water-wetness, and increased oil recovery. Relationships between waterflood recovery and wettability are summarized.

  2. All or nothing: On the small fluctuations of two-dimensional string theoretic black holes

    SciTech Connect (OSTI)

    Gilbert, Gerald; Raiten, Eric

    1992-10-01

    A comprehensive analysis of small fluctuations about two-dimensional string-theoretic and string-inspired black holes is presented. It is shown with specific examples that two-dimensional black holes behave in a radically different way from all known black holes in four dimensions. For both the SL(2,R)/U(1) black hole and the two-dimensional black hole coupled to a massive dilaton with constant field strength, it is shown that there are a {\\it continuous infinity} of solutions to the linearized equations of motion, which are such that it is impossible to ascertain the classical linear response. It is further shown that the two-dimensional black hole coupled to a massive, linear dilaton admits {\\it no small fluctuations at all}. We discuss possible implications of our results for the Callan-Giddings-Harvey-Strominger black hole.

  3. Apparatus and method for recharging a string a avalanche transistors within a pulse generator

    DOE Patents [OSTI]

    Fulkerson, E. Stephen

    2000-01-01

    An apparatus and method for recharging a string of avalanche transistors within a pulse generator is disclosed. A plurality of amplification stages are connected in series. Each stage includes an avalanche transistor and a capacitor. A trigger signal, causes the apparatus to generate a very high voltage pulse of a very brief duration which discharges the capacitors. Charge resistors inject current into the string of avalanche transistors at various points, recharging the capacitors. The method of the present invention includes the steps of supplying current to charge resistors from a power supply; using the charge resistors to charge capacitors connected to a set of serially connected avalanche transistors; triggering the avalanche transistors; generating a high-voltage pulse from the charge stored in the capacitors; and recharging the capacitors through the charge resistors.

  4. Nucleation rate of critical droplets on an elastic string in a {phi}{sup 6} potential

    SciTech Connect (OSTI)

    Kerr, W.C.; Graham, A.J.

    2004-12-01

    We obtain the nucleation rate of critical droplets for an elastic string moving in a {phi}{sup 6} local potential and subject to noise and damping forces. The critical droplet is a bound soliton-antisoliton pair that carries a section of the string out of the metastable central minimum into one of the stable side minima. The frequencies of small oscillations about the critical droplet are obtained from a Heun equation. We solve the Fokker-Planck equation for the phase-space probability density by projecting it onto the eigenfunction basis obtained from the Heun equation. We employ Farkas' 'flux-overpopulation' method to obtain boundary conditions for solving the Fokker-Planck equation; these restrict the validity of our solution to the moderate to heavy damping regime. We present results for the rate as a function of temperature, well depth, and damping.

  5. Circuit for echo and noise suppression of acoustic signals transmitted through a drill string

    DOE Patents [OSTI]

    Drumheller, D.S.; Scott, D.D.

    1993-12-28

    An electronic circuit for digitally processing analog electrical signals produced by at least one acoustic transducer is presented. In a preferred embodiment of the present invention, a novel digital time delay circuit is utilized which employs an array of First-in-First-out (FiFo) microchips. Also, a bandpass filter is used at the input to this circuit for isolating drill string noise and eliminating high frequency output. 20 figures.

  6. Circuit for echo and noise suppression of accoustic signals transmitted through a drill string

    DOE Patents [OSTI]

    Drumheller, Douglas S.; Scott, Douglas D.

    1993-01-01

    An electronic circuit for digitally processing analog electrical signals produced by at least one acoustic transducer is presented. In a preferred embodiment of the present invention, a novel digital time delay circuit is utilized which employs an array of First-in-First-out (FiFo) microchips. Also, a bandpass filter is used at the input to this circuit for isolating drill string noise and eliminating high frequency output.

  7. Sources of CP violation from E{sub 6} inspired heterotic string model

    SciTech Connect (OSTI)

    Boussahel, M.; Mebarki, N.

    2012-06-27

    Sources of the weak CP violation from the SU{sub L}(3)x SU{sub R}(3)x SU{sub c}(3) subgroup of the E{sub 6} inspired heterotic string model are discussed. It is shown that the number of the Cabibo-Kobayachi-Maskawa like matrices depends on the spontaneous breakdown of the E{sub 6} gauge symmetry and/or supersymmetry.

  8. Long-range correlations in proton-nucleus collisions in MC model with string fusion

    SciTech Connect (OSTI)

    Kovalenko, V.

    2014-07-23

    The study of long-range correlations between observables in two rapidity windows was proposed as a signature of the string fusion and percolation phenomenon. In the present work we calculate the correlation functions and coefficients for p–Pb collisions in the framework of the Monte Carlo string-parton model, based on the picture of elementary collisions of color dipoles. It describes pA and AA scattering without referring to the Glauber picture of independent nucleons collisions and includes effects of string fusion. Different types of correlations are considered: n–n, p{sub t}–n, p{sub t}–p{sub t} where n is the event multiplicity of charged particles in a given rapidity window and p{sub t} is their mean transverse momentum. The results, obtained in the present work for p–Pb collisions, are compared with available experimental results for p{sub t}–n correlations in one window and further predictions are made.

  9. Aho-Corasick String Matching on Shared and Distributed Memory Parallel Architectures

    SciTech Connect (OSTI)

    Tumeo, Antonino; Villa, Oreste; Chavarra-Miranda, Daniel

    2012-03-01

    String matching is at the core of many critical applications, including network intrusion detection systems, search engines, virus scanners, spam filters, DNA and protein sequencing, and data mining. For all of these applications string matching requires a combination of (sometimes all) the following characteristics: high and/or predictable performance, support for large data sets and flexibility of integration and customization. Many software based implementations targeting conventional cache-based microprocessors fail to achieve high and predictable performance requirements, while Field-Programmable Gate Array (FPGA) implementations and dedicated hardware solutions fail to support large data sets (dictionary sizes) and are difficult to integrate and customize. The advent of multicore, multithreaded, and GPU-based systems is opening the possibility for software based solutions to reach very high performance at a sustained rate. This paper compares several software-based implementations of the Aho-Corasick string searching algorithm for high performance systems. We discuss the implementation of the algorithm on several types of shared-memory high-performance architectures (Niagara 2, large x86 SMPs and Cray XMT), distributed memory with homogeneous processing elements (InfiniBand cluster of x86 multicores) and heterogeneous processing elements (InfiniBand cluster of x86 multicores with NVIDIA Tesla C10 GPUs). We describe in detail how each solution achieves the objectives of supporting large dictionaries, sustaining high performance, and enabling customization and flexibility using various data sets.

  10. Input-independent, Scalable and Fast String Matching on the Cray XMT

    SciTech Connect (OSTI)

    Villa, Oreste; Chavarra-Miranda, Daniel; Maschhoff, Kristyn J.

    2009-05-25

    String searching is at the core of many security and network applications like search engines, intrusion detection systems, virus scanners and spam ?lters. The growing size of on-line content and the increasing wire speeds push the need for fast, and often real- time, string searching solutions. For these conditions, many software implementations (if not all) targeting conventional cache-based microprocessors do not perform well. They either exhibit overall low performance or exhibit highly variable performance depending on the types of inputs. For this reason, real-time state of the art solutions rely on the use of either custom hardware or Field-Programmable Gate Arrays (FPGAs) at the expense of overall system ?exibility and programmability. This paper presents a software based implementation of the Aho-Corasick string searching algorithm on the Cray XMT multithreaded shared memory machine. Our so- lution relies on the particular features of the XMT architecture and on several algorith- mic strategies: it is fast, scalable and its performance is virtually content-independent. On a 128-processor Cray XMT, it reaches a scanning speed of ? 28 Gbps with a performance variability below 10 %. In the 10 Gbps performance range, variability is below 2.5%. By comparison, an Intel dual-socket, 8-core system running at 2.66 GHz achieves a peak performance which varies from 500 Mbps to 10 Gbps depending on the type of input and dictionary size.

  11. Preliminary evidence for fractionation of stable chlorine isotopes in ore-forming hydrothermal systems

    SciTech Connect (OSTI)

    Eastoe, C.J.; Guilbert, J.M. ); Kaufmann, R.S. )

    1989-03-01

    Chloride from fluid inclusions in hydrothermal minerals is found to have variable and distinctive {delta}{sup 37}Cl values spanning the range -1.1 0/{per thousand} to +0.8 {per thousand}. In Mississippi Valley-type deposits of Tennessee, brines of high (>0{per thousand}) and low (near -1{per thousand}) {delta}{sup 37}Cl are present. High {delta}{sup 37}Cl brines may be saline formation waters, but low {delta}{sup 37}Cl brines remain unexplained. In porphyry copper deposits, both high {delta}{sup 37}Cl (0.8{per thousand}, 0.3{per thousand}) and low {delta}{sup 37}Cl (-1.1{per thousand}, 0.7{per thousand}) hypersaline brines of probable magmatic origin occur. High-salinity magmatic brines with low {delta}{sup 37}Cl values contrast isotopically with high {delta}{sup 37}Cl, less concentrated brines responsible for quartz-sericite-pyrite assemblages.

  12. Request for Information explores mineral recovery from geothermal fluids

    Broader source: Energy.gov [DOE]

    The DOE Geothermal Technologies Office (GTO) is seeking input on ideas that encourage geothermal development by exploring innovations in extracting critical materials found in geothermal brines....

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Julianna Eileen An integrated framework for CO2 accounting and risk analysis ... Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an ...

  14. EIS-0444-SA-01: Draft Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and additional information gathered from an exploratory well and nearby production wells to support planning for the TCEP's deep well injection option for brine disposal has ...

  15. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TX; Trimeric Corporation: Champaign, IL and Buda, TX. FESCCStorage Division Bruce Brown Brine Extraction and Treatment Strategies to Enhance Pressure Management... Project...

  16. Categorical Exclusion Determination Forn1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Modification (not expansion)abandonment of oil storage access brine injectiongasgeothermal wells; no site closure OBS.4 - Repairreplacement of pipeline sections within...

  17. Dixie Valley Bottoming Binary Cycle

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ScientificTechnical Approach Brine Injection Pipeline 6 | US DOE Geothermal Program ... level - Makeup water requirements - Permit Impacts - Space requirements * Phase 1 ...

  18. Beowawe Binary Bottoming Cycle

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ScientificTechnical Approach Brine Injection Pipeline 6 | US DOE Geothermal Program ... level - Makeup water requirements - Permit Impacts - Space requirements * Phase 1 ...

  19. Accident Investigation of the February 7, 2013, Scissor Lift...

    Energy Savers [EERE]

    February 7, 2013, Scissor Lift Accident in the West Hackberry Brine Tank-14 Resulting in Injury, Strategic Petroleum Reserve West Hackberry, LA Accident Investigation of the ...

  20. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Reduced Order Model for the Geochemical Impacts of Carbon Dioxide Brine and Trace Metal Leakage into an Unconfined Oxidizing Carbonate Aquifer Version Bacon Diana H carbon...

  1. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Citation Details...

  2. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1","Bacon, Diana...

  3. Simbol Mining Corp | Open Energy Information

    Open Energy Info (EERE)

    company commercialising zero waste, zero carbon footprint production processes for lithium, EMD, and zinc battery chemicals produced from geothermal brines. Coordinates:...

  4. DOE-EA-1116 | Open Energy Information

    Open Energy Info (EERE)

    storage tanks and transferring geothermal brine at the power plant. imposed Dames & Moore completed a detailed risk assessment to evaluate potential impacts from an accidental...

  5. Probabilistic evaluation of shallow groundwater resources at...

    Office of Scientific and Technical Information (OSTI)

    atmosphere. This study first develops an integrated Monte Carlo method for simulating CO2 and brine leakage from carbon sequestration and subsequent geochemical interactions in...

  6. Demonstration of a Variable Phase Turbine Power System for Low...

    Broader source: Energy.gov (indexed) [DOE]

    Project objectives: Demonstrate a 1 megawatt Variable Phase Turbine and Variable Phase Cycle with low temperature brine. lowhaysvariablephaseturbine.pdf (732.28 KB) More ...

  7. Li and Mn uptake data from initial set of imprinted polymers

    SciTech Connect (OSTI)

    Susanna Ventura

    2015-03-27

    Batch tests of crosslinked lithium and manganese imprinted polymers of variable composition to assess their ability to extract lithium and manganese from synthetic brines at T=45C .

  8. C R O S S C U T T I N G R E S E A R C H

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... High Temperature Applications Peter Liaw, University of Tennessee * Low-Energy Water Recovery from Subsurface Brines Zachary Hendren, Research Triangle Institute * Treatment of ...

  9. 2016 CROSSCUTTING RESEARCH & RARE EARTH ELEMENTS PORTFOLIOS REVIEW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University of Maine System * Low-Cost Efficient and Durable High Temperature Wireless Sensors by Direct ... High Salinity Produced Brine Treatment via Direct Waste Heat ...

  10. Ohio Department of Natural Resources | Open Energy Information

    Open Energy Info (EERE)

    division's responsibilities include regulation of Ohio's oil and gas drilling operations oil and gas production operations brine disposal operations solution mining operations...

  11. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * Geothermal fluids have a complex chemical composition determined by the ... RelevanceImpact of Research x Green and Nix, NRELTP-840-40665 (2006) Brine ...

  12. State Oil and Gas Boards | Open Energy Information

    Open Energy Info (EERE)

    and protect the correlative rights of ownership associated with the production of oil, natural gas and brine, while protecting the environment during the production process,...

  13. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Magnetic Partitioning Nanofluid for Rare Earth Extraction from Geothermal Fluids 2 | US DOE ... them suitable to extract rare earth elements (REE) from geothermal brines. ...

  14. Geothermal Technologies Office March

    Broader source: Energy.gov (indexed) [DOE]

    ... supplying new applications for geothermal power, some geothermal brines are turning up relatively high concentrations of rare earth elements (REEs) and other valu- able materials. ...

  15. Geothermal Energy News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lakes, California. August 21, 2013 Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential Utilizing EERE funds, ElectraTherm developed a geothermal technology that...

  16. CO2-H2O Mixtures in the Geological Sequestration of CO2. II....

    Office of Scientific and Technical Information (OSTI)

    and Duan and Sun (2003), which can be extended to chloride solutions other than NaCl. ... BRINES; CHLORIDES; MIXTURES; REACTION KINETICS; SOLUBILITY; SUN; THERMODYNAMIC ACTIVITY

  17. Section 33: Consideration of Drilling Events in Performance Assessment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... of the WIPP, brinefluid removal, and circulation of brine within the panels. ... and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes; Final Rule." ...

  18. Document

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Disposal of Spent Nuclear Fuel, High-Level and Transuranic (TRU) Radioactive Waste.'' ... to block brine flow between waste panels in WIPP. In the CCA, DOE presented ...

  19. Li and Mn uptake data from initial set of imprinted polymers

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Susanna Ventura

    Batch tests of crosslinked lithium and manganese imprinted polymers of variable composition to assess their ability to extract lithium and manganese from synthetic brines at T=45C .

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center Office of Groundwater and Soil Remediation Office of Nonproliferation and ... (2) water (2) aqueous solutions (1) bacteria (1) bioremediation (1) brines (1) ...

  1. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Filter Results Filter by Subject ammonia (1) battery separators (1) brines (1) cathodes ... Channel flow cathode assembly and electrolyzer Larson, E. H. ; Fitch, R. H. ; Kurtz, B. E. ...

  2. Lithium uptake data of lithium imprinted polymers

    SciTech Connect (OSTI)

    Susanna Ventura

    2015-12-04

    Batch tests of lithium imprinted polymers of variable composition to assess their ability to extract lithium from synthetic brines at T=45C. Initial selectivity data are included

  3. Evaluation Project 4492

    National Nuclear Security Administration (NNSA)

    Fossil, and Renewable Energy Activities B5.1 - Actions ...abandonment of oil storage access brine injection... - Environmental control system improvements in existing ...

  4. Computer Modeling of Chemical and Geochemical Processes in High...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer modeling of chemical and geochemical processes in high ionic strength solutions ... in brine Computer modeling of chemical and geochemical processes in high ionic ...

  5. EIS-0385: Draft Environmental Impact Statement | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at two or three existing sites. Storage capacity would be developed by solution mining of salt domes and disposing of the resulting salt brine by ocean discharge or...

  6. EIS-0385: Final Environmental Impact Statement | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at two or three existing sites. Storage capacity would be developed by solution mining of salt domes and disposing of the resulting salt brine by ocean discharge or...

  7. Microsoft PowerPoint - 4 Chris Camphouse [Compatibility Mode...

    Office of Environmental Management (EM)

    Direct Releases Dominate Total Releases Waste Panel Borehole Cuttings (Solids from Drilling) Cavings (Solids from Drilling) Spallings (Solids from Pressure Release) Direct Brine ...

  8. On the strong coupling dynamics of heterotic string theory onC3/Z3

    SciTech Connect (OSTI)

    Ganor, O.J.; Sonnenschein, J.

    2002-02-28

    The authors study the strong coupling dynamics of the heterotic E{sub 8} x E{sub 8} string theory on the orbifolds T{sup 6}/Z{sub 3} and C{sup 3}/Z{sub 3} using the duality with the Horava-Witten M-theory picture. This leads us to a conjecture about the low energy description of the five dimensional E{sub 0}-theory (the CFT that describes the singularity region of M-theory on C{sup 3}/Z{sub 3}) compactified on S{sup 1}/Z{sub 2}.

  9. The viscosity to entropy ratio: From string theory motivated bounds to warm dense matter

    SciTech Connect (OSTI)

    Faussurier, G.; Libby, S. B.; Silvestrelli, P. L.

    2014-07-04

    Here, we study the ratio of viscosity to entropy density in Yukawa one-component plasmas as a function of coupling parameter at fixed screening, and in realistic warm dense matter models as a function of temperature at fixed density. In these two situations, the ratio is minimized for values of the coupling parameters that depend on screening, and for temperatures that in turn depend on density and material. In this context, we also examine Rosenfeld arguments relating transport coefficients to excess reduced entropy for Yukawa one-component plasmas. For these cases we show that this ratio is always above the lower-bound conjecture derived from string theory ideas.

  10. Global strings in extra dimensions: The full map of solutions, matter trapping, and the hierarchy problem

    SciTech Connect (OSTI)

    Bronnikov, K. A.; Meierovich, B. E.

    2008-02-15

    We consider (d{sub 0} + 2)-dimensional configurations with global strings in two extra dimensions and a flat metric in d{sub 0} dimensions, endowed with a warp factor e{sup 2{gamma}} depending on the distance l from the string center. All possible regular solutions of the field equations are classified by the behavior of the warp factor and the extradimensional circular radius r(l). Solutions with r {yields} {infinity} and r {yields} const > 0 as l {yields} {infinity} are interpreted in terms of thick brane-world models. Solutions with r {yields} 0 as l {yields} l{sub c} > 0, i.e., those with a second center, are interpreted as either multibrane systems (which are appropriate for large enough distances l{sub c} between the centers) or as Kaluza-Klein-type configurations with extra dimensions invisible due to their smallness. In the case of the Mexican-hat symmetry-breaking potential, we build the full map of regular solutions on the ({epsilon}, {Gamma}) parameter plane, where {epsilon} acts as an effective cosmological constant and {Gamma} characterizes the gravitational field strength. The trapping properties of candidate brane worlds for test scalar fields are discussed. Good trapping properties for massive fields are found for models with increasing warp factors. Kaluza-Klein-type models are shown to have nontrivial warp factor behaviors, leading to matter particle mass spectra that seem promising from the standpoint of hierarchy problems.

  11. Global strings in extra dimensions: The full map of solutions, matter trapping, and the hierarchy problem

    SciTech Connect (OSTI)

    Bronnikov, K. A.; Meierovich, B. E.

    2008-02-15

    We consider (d{sub 0} + 2)-dimensional configurations with global strings in two extra dimensions and a flat metric in d{sub 0} dimensions, endowed with a warp factor e{sup 2{gamma}} depending on the distance l from the string center. All possible regular solutions of the field equations are classified by the behavior of the warp factor and the extradimensional circular radius r(l). Solutions with r {sup {yields}} {infinity} and r {sup {yields}} const > 0 as l {sup {yields}} {infinity} are interpreted in terms of thick brane-world models. Solutions with r {sup {yields}} 0 as l {sup {yields}} l{sub c} > 0, i.e., those with a second center, are interpreted as either multibrane systems (which are appropriate for large enough distances l{sub c} between the centers) or as Kaluza-Klein-type configurations with extra dimensions invisible due to their smallness. In the case of the Mexican-hat symmetry-breaking potential, we build the full map of regular solutions on the ({epsilon}, {gamma}) parameter plane, where {epsilon} acts as an effective cosmological constant and {gamma} characterizes the gravitational field strength. The trapping properties of candidate brane worlds for test scalar fields are discussed. Good trapping properties for massive fields are found for models with increasing warp factors. Kaluza-Klein-type models are shown to have nontrivial warp factor behaviors, leading to matter particle mass spectra that seem promising from the standpoint of hierarchy problems.

  12. The viscosity to entropy ratio: From string theory motivated bounds to warm dense matter

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Faussurier, G.; Libby, S. B.; Silvestrelli, P. L.

    2014-07-04

    Here, we study the ratio of viscosity to entropy density in Yukawa one-component plasmas as a function of coupling parameter at fixed screening, and in realistic warm dense matter models as a function of temperature at fixed density. In these two situations, the ratio is minimized for values of the coupling parameters that depend on screening, and for temperatures that in turn depend on density and material. In this context, we also examine Rosenfeld arguments relating transport coefficients to excess reduced entropy for Yukawa one-component plasmas. For these cases we show that this ratio is always above the lower-bound conjecturemore » derived from string theory ideas.« less

  13. STAR CLUSTERS IN A NUCLEAR STAR FORMING RING: THE DISAPPEARING STRING OF PEARLS

    SciTech Connect (OSTI)

    Visnen, Petri; Barway, Sudhanshu; Randriamanakoto, Zara

    2014-12-20

    An analysis of the star cluster population in a low-luminosity early-type galaxy, NGC2328, is presented. The clusters are found in a tight star forming nuclear spiral/ring pattern and we also identify a bar from structural two-dimensional decomposition. These massive clusters are forming very efficiently in the circumnuclear environment and they are young, possibly all less than 30 Myr of age. The clusters indicate an azimuthal age gradient, consistent with a ''pearls-on-a-string'' formation scenario, suggesting bar-driven gas inflow. The cluster mass function has a robust down turn at low masses at all age bins. Assuming clusters are born with a power-law distribution, this indicates extremely rapid disruption at timescales of just several million years. If found to be typical, it means that clusters born in dense circumnuclear rings do not survive to become old globular clusters in non-interacting systems.

  14. Hydrogen generation by metal corrosion in simulated Waste Isolation Pilot Plant environments. Progress report for the period November 1989 through December 1992

    SciTech Connect (OSTI)

    Telander, M.R.; Westerman, R.E.

    1993-09-01

    The corrosion and gas-generation characteristics of three material types: low-carbon steel (the current waste packaging material for the Waste Isolation Pilot Plant), Cu-base materials, and Ti-base materials were determined in both the liquid and vapor phase of Brine A, a brine representative of an intergranular Salado Formation brine. Test environments included anoxic brine and anoxic brine with overpressures of CO{sub 2}, H{sub 2}S, and H{sub 2}. Low-carbon steel reacted at a slow, measurable rate with anoxic brine, liberating H{sub 2} on an equimolar basis with Fe reacted. Presence of CO{sub 2} caused the initial reaction to proceed more rapidly, but CO{sub 2}-induced passivation stopped the reaction if the CO{sub 2} were present in sufficient quantities. Low-carbon steel immersed in brine with H{sub 2}S showed no reaction, apparently because of passivation of the steel by formation of a protective iron sulfide reaction product. Cu- and Ti-base materials showed essentially no corrosion when exposed to brine and overpressures of N{sub 2}, CO{sub 2}, and H{sub 2}S except for the rapid and complete reaction between Cu-base materials and H{sub 2}S. No significant reaction took place on any material in any environment in the vapor-phase exposures.

  15. Heber geothermal coupon analytical report: (Final technical report)

    SciTech Connect (OSTI)

    Not Available

    1986-10-20

    The objectives of this paper are: to determine the cause of accelerated metal loss from the loading edges (as relates to brine flow) of carbon steel coupons in the low temperature portion of the Heber brine loop; and to clarify the reason for the distinctly different morphology of attack on the A53B pipe steel compared to the sheet 1018 steel. 6 figs.

  16. CX-010712: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace West Hackberry Brine Disposal System Header from MOV-51’s to WHT-14/15 Brine Tanks with HDPE Pipe CX(s) Applied: B5.2 Date: 07/03/2013 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  17. Countercurrent direct contact heat exchange process and system

    DOE Patents [OSTI]

    Wahl, III, Edward F.; Boucher, Frederic B.

    1979-01-01

    Recovery of energy from geothermal brines and other hot water sources by direct contact heat exchange with a working fluid, such as a hydrocarbon working fluid, e.g. isobutane. The process and system consists of a plurality of stages, each stage including mixing and settling units. In the first stage, hot brine and arm working fluid are intimately mixed and passed into a settler wherein the brine settles to the bottom of the settler and the hot working fluid rises to the top. The hot working fluid is passed to a heat engine or turbine to produce work and the working fluid is then recycled back into the system. The system is comprised of a series of stages each containing a settler and mixer, and wherein the working fluid and the brine flow in a countercurrent manner through the stages to recover the heat from the brine in increments and raise the temperature of the working fluid in increments.

  18. Natural radionuclides in groundwaters

    SciTech Connect (OSTI)

    Laul, J.C.

    1990-01-01

    The U-234 and Th-230 radionuclides are highly retarded by factors of 10{sup 4} to 10{sup 5} in basalt groundwater (Hanford) and briny groundwaters from Texas and geothermal brine from the Salton Sea Geothermal Field (SSGF). In basalt groundwaters (low ionic strength), Ra is highly sorbed, while in brines (high ionic strength), Ra is soluble. This is probably because the sorption sites are saturated with Na{sup +} and Cl{sup {minus}} ions and RaCl{sub 2} is soluble in brines. Pb-210 is soluble in SSGF brine, probably as a chloride complex. The U-234/Th-230 ratios in basalt groundwaters and brines from Texas and SSGF are nearly unity, indicating that U is in the +4 state, suggesting a reducing environment for these aquifers. 19 refs., 3 figs.

  19. Integrability of the symmetry reduced bosonic dynamics and soliton generating transformations in the low energy heterotic string effective theory

    SciTech Connect (OSTI)

    Alekseev, G. A.

    2009-08-15

    Integrable structure of the symmetry reduced dynamics of massless bosonic sector of the heterotic string effective action is presented. For string background equations that govern in the space-time of D dimensions (D{>=}4), the dynamics of interacting gravitational, dilaton, antisymmetric tensor and any number n{>=}0 of Abelian vector gauge fields, all depending only on two coordinates, we construct an equivalent (2d+n)x(2d+n)-matrix spectral problem (d=D-2). This spectral problem provides the base for the development of various solution constructing procedures (dressing transformations, integral equation methods). For the case of the absence of Abelian gauge fields, we present the soliton generating transformations of any background with interacting gravitational, dilaton, and the second rank antisymmetric tensor fields.

  20. String or branelike solutions in four-dimensional Einstein gravity in the presence of a cosmological constant

    SciTech Connect (OSTI)

    Lee, Youngone; Kang, Gungwon; Kim, Hyeong-Chan; Lee, Jungjai

    2011-10-15

    We investigate string or branelike solutions for four-dimensional vacuum Einstein equations in the presence of a cosmological constant. For the case of negative cosmological constant, the Banados-Teitelboim-Zanelli black string is the only warped stringlike solution. The general solutions for nonwarped branelike configurations are found and they are characterized by the Arnowitt-Deser-Misner mass density and two tensions. Interestingly, the sum of these tensions is equal to the minus of the mass density. Other than the well-known black string and soliton spacetimes, all the static solutions possess naked singularities. The time-dependent solutions can be regarded as the anti-de Sitter extension of the well-known Kasner solutions. The speciality of those static regular solutions and the implication of singular solutions are also discussed in the context of cylindrical matter collapse. For the case of positive cosmological constant, the Kasner-de Sitter spacetime appears as time-dependent solutions and all static solutions are found to be naked singular.

  1. Drill string splined resilient tubular telescopic joint for balanced load drilling of deep holes

    SciTech Connect (OSTI)

    Garrett, W.R.

    1981-08-04

    A drill string splined resilient tubular telescopic joint for balanced load deep well drilling comprises a double acting damper having a very low spring rate upon both extension and contraction from the zero deflection condition. Preferably the spring means itself is a double acting compression spring means wherein the same spring means is compressed whether the joint is extended or contracted. The damper has a like low spring rate over a considerable range of deflection, both upon extension and contraction of the joint, but a gradually then rapidly increased spring rate upon approaching the travel limits in each direction. Stacks of spring rings are employed for the spring means, the rings being either shaped elastomer-metal sandwiches or, preferably, roller belleville springs. The spline and spring means are disposed in an annular chamber formed by mandrel and barrel members constituting the telescopic joint. The spring rings make only such line contact with one of the telescoping members as is required for guidance therefrom, and no contact with the other member. The chamber containing the spring means, and also containing the spline means, is filled with lubricant, the chamber being sealed with a pressure seal at its lower end and an inverted floating seal at its upper end. Magnetic and electrical means are provided to check for the presence and condition of the lubricant. To increase load capacity the spring means is made of a number of components acting in parallel.

  2. Drill string splined resilient tubular telescopic joint for balanced load drilling of deep holes

    SciTech Connect (OSTI)

    Garrett, W.R.

    1984-03-06

    A drill string splined resilient tubular telescopic joint for balanced load deep well drilling comprises a double acting damper having a very low spring rate upon both extension and contraction from the zero deflection condition. Stacks of spring rings are employed for the spring means, the rings being either shaped elastomer-metal sandwiches or, preferably, roller Belleville springs. The spline and spring means are disposed in an annular chamber formed by mandrel and barrel members constituting the telescopic joint. The chamber containing the spring means, and also containing the spline means, is filled with lubricant, the chamber being sealed with a pressure seal at its lower end and an inverted floating seal at its upper end. A prototype includes of this a bellows seal instead of the floating seal at the upper end of the tool, and a bellows in the side of the lubricant chamber provides volume compensation. A second lubricant chamber is provided below the pressure seal, the lower end of the second chamber being closed by a bellows seal and a further bellows in the side of the second chamber providing volume compensation. Modifications provide hydraulic jars.

  3. System and method for damping vibration in a drill string using a magnetorheological damper

    DOE Patents [OSTI]

    Wassell, Mark Ellsworth; Burgess, Daniel E.; Barbely, Jason R.

    2012-01-03

    A system for damping vibration in a drill string can include a magnetorheological fluid valve assembly having a supply of a magnetorheological fluid, a first member, and a second member capable of moving in relation to first member in response to vibration of the drill bit. The first and second members define a first and a second chamber for holding the fluid. Fluid can flow between the first and second chambers in response to the movement of the second member in relation to the first member. The valve assembly can also include a coil for inducing a magnetic field that alters the resistance of the magnetorheological fluid to flow between the first and second chambers, thereby increasing the damping provided by the valve. A remnant magnetic field is induced in one or more components of the magnetorheological fluid valve during operation that can be used to provide the magnetic field for operating the valve so as to eliminate the need to energize the coils during operation except temporarily when changing the amount of damping required, thereby eliminating the need for a turbine alternator power the magnetorheological fluid valve. A demagnetization cycle can be used to reduce the remnant magnetic field when necessary.

  4. Limits on a muon flux from neutralino annihilations in the Sun with the IceCube 22-string detector

    SciTech Connect (OSTI)

    IceCube Collaboration; Klein, Spencer

    2009-04-28

    A search for muon neutrinos from neutralino annihilations in the Sun has been performed with the IceCube 22-string neutrino detector using data collected in 104.3 days of live-time in 2007. No excess over the expected atmospheric background has been observed. Upper limits have been obtained on the annihilation rate of captured neutralinos in the Sun and converted to limits on the WIMP-proton cross-sections for WIMP masses in the range 250-5000 GeV. These results are the most stringent limits to date on neutralino annihilation in the Sun.

  5. Laboratory measurements of large-scale carbon sequestration flows in saline reservoirs

    SciTech Connect (OSTI)

    Backhaus, Scott N

    2010-01-01

    Brine saturated with CO{sub 2} is slightly denser than the original brine causing it to sink to the bottom of a saline reservoir where the CO{sub 2} is safely sequestered. However, the buoyancy of pure CO{sub 2} relative to brine drives it to the top of the reservoir where it collects underneath the cap rock as a separate phase of supercritical fluid. Without additional processes to mix the brine and CO{sub 2}, diffusion in this geometry is slow and would require an unacceptably long time to consume the pure CO{sub 2}. However, gravity and diffusion-driven convective instabilities have been hypothesized that generate enhanced CO{sub 2}-brine mixing promoting dissolution of CO{sub 2} into the brine on time scale of a hundred years. These flows involve a class of hydrodynamic problems that are notoriously difficult to simulate; the simultaneous flow of mUltiple fluids (CO{sub 2} and brine) in porous media (rock or sediment). The hope for direct experimental confirmation of simulations is dim due to the difficulty of obtaining high resolution data from the subsurface and the high pressures ({approx}100 bar), long length scales ({approx}100 meters), and long time scales ({approx}100 years) that are characteristic of these flows. We have performed imaging and mass transfer measurements in similitude-scaled laboratory experiments that provide benchmarks to test reservoir simulation codes and enhance their predictive power.

  6. Overview of fundamental geochemistry basic research at the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Anovitz, L.M.; Benezeth, P.; Blencoe, J.G.

    1996-01-01

    Researchers in ORNL`s Geochemistry and High Temperature Aqueous Chemistry groups are conducting detailed experimental studies of physicochemical properties of the granite-melt-brine system; sorption of water on rocks from steam-dominated reservoirs; partitioning of salts and acid volatiles between brines and steam; effects of salinity on H and O isotope partitioning between brines, minerals, and steam; and aqueous geochemistry of Al. These studies contribute in many ways to cost reductions and improved efficiency in the discovery, characterization, and production of energy from geothermal resources.

  7. EIS-0165: Strategic Petroleum Reserve Alabama, Louisiana, Mississippi, and Texas

    Broader source: Energy.gov [DOE]

    This EIS assesses the impacts of construction and operation for the range of alternatives being considered and focuses on oil and brine spill risk and impacts of brine disposal. The proposed action entails the development of a plan for 250 million barrels of new crude oil storage capacity in two Gulf Coast salt domes to expand the Strategic Petroleum Reserve pursuant to Congressional directive (PL I 01-383 and PL 101-512). Storage capacity would be developed by solution-mining the salt which would require about two billion barrels of surface water and would generate about two billion barrels of salt brine.

  8. Geothermal research at the Puna Facility

    SciTech Connect (OSTI)

    Chen, B.

    1986-05-01

    Chemical analyses were conducted on the flocculated silica samples obtained during previous field experiments at HGP-A on both flashed and unflashed brines to determine the composition of the recovered silica for specific constituents of the brine which seem to often be entrapped in the silica during the flocculation process. Metals added as flocculants to the brine were also analyzed in order to evaluate the ease or difficulty with which these can be removed from the precipitated silica under varying conditions. Conditions employed included simple distilled water and acid washing (HCl of varying concentration).

  9. The effect of voltage waveform and tube diameter on transporting cold plasma strings through a flexible dielectric tube

    SciTech Connect (OSTI)

    Sohbatzadeh, Farshad; Omran, Azadeh Valinataj

    2014-11-15

    In this work, we developed transporting atmospheric pressure cold plasma using single electrode configuration through a sub-millimetre flexible dielectric tube beyond 100 cm. It was shown that the waveform of the applied high voltage is essential for controlling upstream and downstream plasma inside the tube. In this regard, sawtooth waveform enabled the transport of plasma with less applied high voltage compared to sinusoidal and pulsed form voltages. A cold plasma string as long as 130 cm was obtained by only 4 kV peak-to-peak sawtooth high voltage waveform. Optical emission spectroscopy revealed that reactive chemical species, such as atomic oxygen and hydroxyl, are generated at the tube exit. The effect of tube diameter on the transported plasma was also examined: the smaller the diameter, the higher the applied voltage. The device is likely to be used for sterilization, decontamination, and therapeutic endoscopy as already suggested by other groups in recent past years.

  10. Investigations of α-helix↔β-sheet transition pathways in a miniprotein using the finite-temperature string method

    SciTech Connect (OSTI)

    Ovchinnikov, Victor; Karplus, Martin

    2014-05-07

    A parallel implementation of the finite-temperature string method is described, which takes into account the invariance of coordinates with respect to rigid-body motions. The method is applied to the complex α-helix↔β-sheet transition in a β-hairpin miniprotein in implicit solvent, which exhibits much of the complexity of conformational changes in proteins. Two transition paths are considered, one derived from a linear interpolant between the endpoint structures and the other derived from a targeted dynamics simulation. Two methods for computing the conformational free energy (FE) along the string are compared, a restrained method, and a tessellation method introduced by E. Vanden-Eijnden and M. Venturoli [J. Chem. Phys. 130, 194103 (2009)]. It is found that obtaining meaningful free energy profiles using the present atom-based coordinates requires restricting sampling to a vicinity of the converged path, where the hyperplanar approximation to the isocommittor surface is sufficiently accurate. This sampling restriction can be easily achieved using restraints or constraints. The endpoint FE differences computed from the FE profiles are validated by comparison with previous calculations using a path-independent confinement method. The FE profiles are decomposed into the enthalpic and entropic contributions, and it is shown that the entropy difference contribution can be as large as 10 kcal/mol for intermediate regions along the path, compared to 15–20 kcal/mol for the enthalpy contribution. This result demonstrates that enthalpic barriers for transitions are offset by entropic contributions arising from the existence of different paths across a barrier. The possibility of using systematically coarse-grained representations of amino acids, in the spirit of multiple interaction site residue models, is proposed as a means to avoid ad hoc sampling restrictions to narrow transition tubes.

  11. Tuba City, Arizona, Disposal Site Fact Sheet

    Office of Legacy Management (LM)

    This site is managed by the U.S. Department of Energy Office of Legacy Management under ... A lined solar evaporation pond receives the waste liquid (brine) and the softener ...

  12. CX-013488: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace 24" West Hackberry Brine Disposal Pipeline (GFE) (WH-MM-826A) CX(s) Applied: B1.3Date: 03/09/2015 Location(s): LouisianaOffices(s): Strategic Petroleum Reserve Field Office

  13. CX-013485: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Re-coat WHT-15 Brine Tank (WH-MM-819D) CX(s) Applied: B1.3Date: 03/24/2015Location(s): LouisianaOffices(s): Strategic Petroleum Reserve Field Office

  14. DOE-Sponsored Project Tests Novel Method to Increase Oil Recovery

    Office of Energy Efficiency and Renewable Energy (EERE)

    Successful laboratory tests at the Energy Department’s National Energy Technology Laboratory (NETL) have verified that the use of a brine-soluble ionic surfactant could improve the efficiency of carbon dioxide enhanced oil recovery (CO2-EOR).

  15. CX-013851: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Advanced Analytical Methods for Air and Stray Gas Emissions and Produced Brine Characterization CX(s) Applied: B3.1Date: 06/23/2015 Location(s): TexasOffices(s): National Energy Technology Laboratory

  16. Microsoft Word - Appendix C_DisposalCellContents.doc

    Office of Legacy Management (LM)

    ... Total occupied volume is below 50 cy. Use 50 cy. 50.00 Brine tanks from SWTP Mixed with soil. Est. conversion factor is 0.430. 25.80 Contaminated Jersey barriers 27 each at 0.5 cy. ...

  17. CX-011223: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Brine Disposal Pump Replacement (Install) CX(s) Applied: B5.2 Date: 10/28/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  18. CX-010711: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Brine Disposal Pump Replacement CX(s) Applied: B5.2 Date: 07/03/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  19. CX-100008: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Selective Recovery of Metals from Geothermal Brines Award Number: DE-EE0006747 CX(s) Applied: A9, B3.6 Geothermal Technologies Date: 08/28/2014 Location(s): California Office(s): Golden Field Office

  20. Energy Department Selects Five Projects in First Step to Produce...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and the flow of CO2 - also known as a plume steering- brine can be extracted from the formation at specific points, where fresh water can be separated in a process known as...

  1. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Bacon, Diana H. carbon...

  2. CX-013764: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Repair Bayou Choctaw Brine Disposal Road (LANG and Subcontractor) CX(s) Applied: B1.3Date: 05/27/2015 Location(s): LouisianaOffices(s): Strategic Petroleum Reserve Field Office

  3. CX-007505: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion for Big Hill Raw Water Brine header Piping Inspection CX(s) Applied: B1.3 Date: 11/28/2011 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  4. CX-005610: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Soil Amendment Product for Oilfield Brine Contaminated Soil ? Field Testing Part IICX(s) Applied: B3.7Date: 04/12/2011Location(s): Rosalia, KansasOffice(s): Fossil Energy, National Energy Technology Laboratory

  5. CX-004719: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Upgrade Communication/Control Systems to BC Brine Disposal Well (Government Furnished Equipment and Install)CX(s) Applied: B1.7Date: 11/23/2010Location(s): LouisianaOffice(s): Strategic Petroleum Reserve Field Office

  6. CX-004274: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Soil Amendment Product for Oilfield Brine Contaminated Soil ? Field Testing Part IICX(s) Applied: B3.7Date: 10/19/2010Location(s): Blackwell, OklahomaOffice(s): Fossil Energy, National Energy Technology Laboratory

  7. DOE Partner Begins Carbon Storage Test | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of 6-8 months into an existing brine-water injection well at depths of about 1,900 feet. ... Following injection, the oil, gas, and water produced will be measured to evaluate the ...

  8. Most Viewed Documents for Renewable Energy Sources: September...

    Office of Scientific and Technical Information (OSTI)

    (2000) 62 Calculation of brine properties. Above 80sup 0F and for salt content between 5 and 25% Dittman, G.L. (1977) 54 Development of the helical reaction hydraulic turbine. ...

  9. EERE Success Story-Geothermal Technology Breakthrough in Alaska...

    Broader source: Energy.gov (indexed) [DOE]

    A binary process mixes geothermal brine with a working fluid that has a lower boiling point than water. This fluid is compressed into steam to turn a turbine and generate ...

  10. Laboratory testing and modeling to evaluate perfluorocarbon compounds...

    Office of Scientific and Technical Information (OSTI)

    Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second ...

  11. CX-010606: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Development of Subsurface Brine Disposal Framework in the Northern Appalachian Basin CX(s) Applied: B3.1 Date: 07/25/2013 Location(s): Kentucky Offices(s): National Energy Technology Laboratory

  12. THIRD GEOPRESSURED-GEOTHERMAL ENERGY CONFERENCE University of...

    Office of Scientific and Technical Information (OSTI)

    ... increasing depth (Fig. 15) (De Sitter, 1947; Bredehoeft et al, 1963; Dickey, 1966; ... Geology: v . 2, p. 195-197. De Sitter, L. U . , 1947, Diagenesis of oil-field brines: Am. ...

  13. CX-011437: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Advanced Analytical Methods for Air and Stray Gas Emissions and Produced Brine Characterization CX(s) Applied: A9 Date: 11/21/2013 Location(s): New York Offices(s): National Energy Technology Laboratory

  14. Manganese uptake of imprinted polymers

    SciTech Connect (OSTI)

    Susanna Ventura

    2015-09-30

    Batch tests of manganese imprinted polymers of variable composition to assess their ability to extract lithium and manganese from synthetic brines at T=45C . Data on manganese uptake for two consecutive cycles are included.

  15. CX-006250: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Blast and Paint Bayou Choctaw Brine Pump Pad and Associate PipingCX(s) Applied: B1.3Date: 06/20/2011Location(s): Iberville Parish, LouisianaOffice(s): Strategic Petroleum Reserve Field Office

  16. Microsoft Word - NRAP-TRS-III-005-2012_ROMDevelopment_20121018...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carlo simulation with 1000 samples, using (a) HFM and (b) ROM. Suggested Citation: Zhang, Y.; Pau, G. Reduced-Order Model Development for CO 2 Storage in Brine Reservoirs; ...

  17. CX-005370: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Clean and Inspect West Hackberry (WHT-14) Brine TankCX(s) Applied: B1.3Date: 02/22/2011Location(s): West Hackberry, LouisianaOffice(s): Strategic Petroleum Reserve Field Office

  18. CX-013882: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Bayou Choctaw Brine Disposal/Recycle Piping in Pump/Pond Area CX(s) Applied: B1.3Date: 07/17/2015 Location(s): None ProvidedOffices(s): Strategic Petroleum Reserve Field Office

  19. Beowawe Binary Bottoming Cycle

    Broader source: Energy.gov [DOE]

    Project objectives: Demonstrate the technical and economic feasibility of electricity generation from the nonconventional geothermal resources of 205°F by extracting waste heat from the brine to power a binary power plant.

  20. Dixie Valley Bottoming Binary Cycle

    Broader source: Energy.gov [DOE]

    Project objective: Prove the technical and economic feasibility of utilizing the available unused heat to generate additional electric power from a binary power plant from low-temperature brine at the Dixie Valley Geothermal Power Plant.

  1. Research News January 2015, Issue 4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experiments and Models Help Predict CO2 Solubility in Brines page 2 the ENERGY lab NATIONAL ENERGY TECHNOLOGY LABORATORY From NETL's Office of Research & Development Researchnews June 2015, Issue 9 2 Contents June 2015, Issue 9 2 Feature Story: Experiments and Models Help Predict CO2 Solubility in Brines 4 Novel Techniques for Field Measurement of CO2 in Groundwater 5 New Tool Predicts Behavior of Materials Used in CO2 Capture Processes 6 New Capability Takes Sensor Fabrication to a New

  2. Nevada manufacturer installing geothermal power plant | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Nevada manufacturer installing geothermal power plant Nevada manufacturer installing geothermal power plant August 26, 2010 - 4:45pm Addthis Chemetall extracts lithium carbonate, a powder, from brine, a salty solution from within the earth. | Photo courtesy Chemetall Chemetall extracts lithium carbonate, a powder, from brine, a salty solution from within the earth. | Photo courtesy Chemetall Joshua DeLung Chemetall supplies materials for lithium-ion batteries for electric vehicles

  3. Disequilibrium study of natural radionuclides of uranium and thorium series in cores and briny groundwaters from Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.

    1988-05-01

    The concentrations of natural radionuclides of the /sup 238/U and /232/Th series are reported in several cores and in ten deep and five shallow briny groundwaters from various formations in the Palo Duro Basin. The formations include Granite Wash, Pennsylvanian Granite Wash, Wolfcamp Carbonate, Pennsylvanian Carbonate, Seven River, Queen Grayburg, San Andres, Yates and Salado. The natural radionuclide data in cores suggest that the radionuclides have not migrated or been leached for at least a period of about 1 million years. Relative to the U and Th concentrations in cores, the brines are depleted by a factor of 10/sup 4/ to 10/sup 5/, indicating extremely low solubility of U and Th in brines. The natural radionuclide data in brines suggest that radium is not sorbed significantly and thus not retarded in nine deep brines. Radium is somewhat sorbed in one deep brine of Wolfcamp Carbonate and significantly sorbed in shallow brines. Relative to radium, the U, Th, Pb, Bi, and Po radionuclides are highly retarded by sorption. The retardation factors for /sup 228/Th range from 10/sup 2/ to 10/sup 3/, whereas those for /sup 230/Th and /sup 234/U range from 10/sup 3/ to 10/sup 5/, depending on the formation. The /sup 234/U//sup 238/U ratios in these brines are constant at about 1.5. The magnitude of the /sup 234/U//sup 230/Th ratio appears to reflect the degree of redox state of the aquifer's environment. The /sup 234/U//sup 230/Th ratio in nine deep brines is about unity, suggesting that U, like Th/sup +4/, is in the +4 state, which in turn suggests a reduced environment. 49 refs., 23 figs., 18 tabs.

  4. Water purification using organic salts

    DOE Patents [OSTI]

    Currier, Robert P.

    2004-11-23

    Water purification using organic salts. Feed water is mixed with at least one organic salt at a temperature sufficiently low to form organic salt hydrate crystals and brine. The crystals are separated from the brine, rinsed, and melted to form an aqueous solution of organic salt. Some of the water is removed from the aqueous organic salt solution. The purified water is collected, and the remaining more concentrated aqueous organic salt solution is reused.

  5. An integrated experimental and numerical study: Developing a reaction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and temporal flow variations in CO2/brine/rock systems | Department of Energy An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and temporal flow variations in CO2/brine/rock systems An integrated experimental and numerical study: Developing a reaction transport model that

  6. Charged black holes in string-inspired gravity II. Mass inflation and dependence on parameters and potentials

    SciTech Connect (OSTI)

    Hansen, Jakob; Yeom, Dong-han

    2015-09-07

    We investigate the relation between the existence of mass inflation and model parameters of string-inspired gravity models. In order to cover various models, we investigate a Brans-Dicke theory that is coupled to a U(1) gauge field. By tuning a model parameter that decides the coupling between the Brans-Dicke field and the electromagnetic field, we can make both of models such that the Brans-Dicke field is biased toward strong or weak coupling directions after gravitational collapses. We observe that as long as the Brans-Dicke field is biased toward any (strong or weak) directions, there is no Cauchy horizon and no mass inflation. Therefore, we conclude that to induce a Cauchy horizon and mass inflation inside a charged black hole, either there is no bias of the Brans-Dicke field as well as no Brans-Dicke hair outside the horizon or such a biased Brans-Dicke field should be well trapped and controlled by a potential.

  7. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, R.M.; Lu, Peng; Allen, D.E.; Soong, Yee; Hedges, S.W.; Fu, J.K.; Dobbs, C.L.; DeGalbo, A.D.; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20 °C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  8. Fresh Water Generation from Aquifer-Pressured Carbon Storage: Interim Progress Report

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Hao, Y; Bourcier, W L

    2009-07-22

    This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including nanofiltration (NF) and reverse osmosis (RO). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine would be reinjected into the formation at net volume reduction. This process provides additional storage space (capacity) in the aquifer, reduces operational risks by relieving overpressure in the aquifer, and provides a source of low-cost fresh water to offset costs or operational water needs. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations for brines typical of CCS sites. Computer modeling is being used to evaluate processes in the aquifer, including the evolution of the pressure field. This progress report deals mainly with our geochemical modeling of high-salinity brines and covers the first six months of project execution (September, 2008 to March, 2009). Costs and implementation results will be presented in the annual report. The brines typical of sequestration sites can be several times more concentrated than seawater, requiring specialized modeling codes typical of those developed for nuclear waste disposal calculations. The osmotic pressure developed as the brines are concentrated is of particular concern, as are precipitates that can cause fouling of reverse osmosis membranes and other types of membranes (e.g., NF). We have now completed the development associated with tasks (1) and (2) of the work plan. We now have a contract with Perlorica, Inc., to provide support to the cost analysis and nanofiltration evaluation. We have also conducted several preliminary analyses of the pressure effect in the reservoir in order to confirm that reservoir

  9. Results of industry experience survey on coiled tubing uses and failures

    SciTech Connect (OSTI)

    Maldonado, J.G.; Cayard, M.S.; Kane, R.D.

    1999-11-01

    A survey of coiled tubing failures in various field applications was conducted. The survey included the collection of information on failure type, number of strain cycles to failure, service environment, well depth, failure location on the coiled tubing string, and coiled tubing grade employed. The most prevalent causes of failures and the impact of localized corrosion on the performance of coiled tubing were assessed from over thirty case studies herein reported. Pitting and tensile overload were the primary causes for failure in fifty percent of the cases reported from the field. Fatigue and weld area failures were the next most common types of failure. Most failures occurred within the range of 10 to 50 strain cycles. H{sub 2}S and brine/water containing environments were the most prevalent service conditions. Most failures occurred at well depths between 5,001 to 10,000 feet (1,524.3 to 3,048 meters). Also, most failures occurred in the coiled tubing string near the surface (less than 1,000 feet (304.8 meters)). Failures in roughly similar numbers were reported in 70, 80 and 100 coiled tubing grades. The understanding of the principal modes of failure herein reported should help in the development of improved handling and running procedures to minimize coiled tubing failures.

  10. A novel 3D structure composed of strings of hierarchical TiO{sub 2} spheres formed on TiO{sub 2} nanobelts with high photocatalytic properties

    SciTech Connect (OSTI)

    Jiang, Yongjian; Li, Meicheng; Song, Dandan; Li, Xiaodan; Yu, Yue

    2014-03-15

    A novel hierarchical titanium dioxide (TiO{sub 2}) composite nanostructure with strings of anatase TiO{sub 2} hierarchical micro-spheres and rutile nanobelts framework (TiO{sub 2} HSN) is successfully synthesized via a one-step hydrothermal method. Particularly, the strings of hierarchical spheres are assembled by very thin TiO{sub 2} nanosheets, which are composed of highly crystallized anatase nanocrystals. Meanwhile, the HSN has a large surface area of 191 m{sup 2}/g, which is about 3 times larger than Degussa P25. More importantly, the photocatalytic activity of HSN and P25 were evaluated by the photocatalytic oxidation decomposition of methyl orange (MO) under UV light illumination, and the TiO{sub 2} HSN shows enhanced photocatalytic activity compared with Degussa P25, as result of its continuous hierarchical structures, special conductive channel and large specific surface area. With these features, the hierarchical TiO{sub 2} may have more potential applications in the fields of dye-sensitized solar cells and lithium ion batteries. -- Graphical abstract: Novel TiO{sub 2} with anatase micro-spheres and rutile nanobelts is synthesized. Enhanced photocatalysis is attributed to hierarchical structures (3D spheres), conductive channel (1D nanobelts) and large specific surface area (2D nanosheet). Highlights: • The novel TiO{sub 2} nanostructure (HSN) is fabricated for the first time. • HSN is composed of strings of anatase hierarchical spheres and rutile nanobelt. • HSN presents a larger S{sub BET} of 191 m{sup 2}/g, 3 times larger than the Degussa P25 (59 m{sup 2}/g). • HSN owns three kinds of dimensional TiO{sub 2} (1D, 2D and 3D) simultaneously. • HSN exhibits better photocatalytic performance compared with Degussa P25.

  11. Limits on a muon flux from Kaluza-Klein dark matter annihilations in the Sun from the IceCube 22-string detector

    SciTech Connect (OSTI)

    IceCube Collaboration; Abbasi, R.; al., et

    2009-10-23

    A search for muon neutrinos from Kaluza-Klein dark matter annihilations in the Sun has been performed with the 22-string configuration of the IceCube neutrino detector using data collected in 104.3 days of live-time in 2007. No excess over the expected atmospheric background has been observed. Upper limits have been obtained on the annihilation rate of captured lightest Kaluza-Klein particle (LKP) WIMPs in the Sun and converted to limits on the LKP-proton cross-sections for LKP masses in the range 250 - 3000 GeV. These results are the most stringent limits to date on LKP annihilation in the Sun.

  12. The composition of Permian seawater

    SciTech Connect (OSTI)

    Horita, J.; Friedman, T.J.; Lazar, B.; Holland, H.D. )

    1991-02-01

    Forty-nine brine inclusions in marine halite from the Ochoan Salado Formation in the Delaware Basin and fifteen inclusions in halite from the Leonardian Wellington Formation in the Kansas Basin were extracted, and their chemical compositions were determined. The brines are of the Na-K-Mg-Cl-SO{sub 4} type; their compositions resemble those of evaporated modern seawater. The values of (m{sub Cl{sup {minus}}} - m{sub Na{sup +}})/m{sub Br{sup {minus}}} and (m{sub Mg{sup 2+}} + ,{sub Ca{sup 2+}} {minus} m{sub SO{sub 4}{sup 2{minus}}} {minus} {1/2}m{sub HCO{sub 3}{sup {minus}}})/m{sub Br{sup {minus}}} of the inclusion brine from the two formations are equal to or slightly higher than those of modern seawater. The original m{sub Na{sup +}}/m{sub Br{sup {minus}}} and m{sub Cl{sup {minus}}}/m{sub Br{sup {minus}}} ratios of the inclusion brines were probably equal to or slightly larger than those of modern seawater. The values of m{sub Mg{sup 2+}}/m{sub Br{sup {minus}}} of the inclusion brines from the Salado Formation are very close to that of modern seawater; the ratios of inclusion brines from the Wellington Formation are very close to that of modern seawater; the ratios of inclusion brines from the Wellington Formation are slightly lower, probably due to the formation of dolomite/magnesite. The m{sub Mg{sup 2+}}/m{sub Br{sup {minus}}} ratio in the initial seawater was probably close to the parent seawater of the Salado brines. The values of (m{sub SO{sub 4}{sup 2{minus}}} {minus} m{sub Ca{sup 2+}} + {1/2}m{sub HCO{sub 3}{sup {minus}}})/m{sub Br{sup {minus}}} of the inclusion brines appear to be reduced by the formation of dolomite/magnesite, and the value of this ratio in Permian seawater was probably similar to that of modern seawater. The m{sub K{sup +}}/m{sub Br{sup -}} ratios of the inclusion brines are variable, but the original ratios are probably close to or slightly larger than that of modern seawater.

  13. Shoe-String Automation

    SciTech Connect (OSTI)

    Duncan, M.L.

    2001-07-30

    Faced with a downsizing organization, serious budget reductions and retirement of key metrology personnel, maintaining capabilities to provide necessary services to our customers was becoming increasingly difficult. It appeared that the only solution was to automate some of our more personnel-intensive processes; however, it was crucial that the most personnel-intensive candidate process be automated, at the lowest price possible and with the lowest risk of failure. This discussion relates factors in the selection of the Standard Leak Calibration System for automation, the methods of automation used to provide the lowest-cost solution and the benefits realized as a result of the automation.

  14. [Mathematics and string theory

    SciTech Connect (OSTI)

    Jaffe, A.; Yau, Shing-Tung.

    1993-01-01

    Work on this grant was centered on connections between non- commutative geometry and physics. Topics covered included: cyclic cohomology, non-commutative manifolds, index theory, reflection positivity, space quantization, quantum groups, number theory, etc.

  15. String | Open Energy Information

    Open Energy Info (EERE)

    rty:CommunityEnergyToolsCostRange Property:CompanyOwnership Property:CompanyType Property:Component Integration Property:ConditionMonitoringAttribute Property:Contact...

  16. Drill string transmission line

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David S.; Bradford, Kline; Fox, Joe

    2006-03-28

    A transmission line assembly for transmitting information along a downhole tool comprising a pin end, a box end, and a central bore traveling between the pin end and the box end, is disclosed in one embodiment of the invention as including a protective conduit. A transmission line is routed through the protective conduit. The protective conduit is routed through the central bore and the ends of the protective conduit are routed through channels formed in the pin end and box end of the downhole tool. The protective conduit is elastically forced into a spiral or other non-linear path along the interior surface of the central bore by compressing the protective conduit to a length within the downhole tool shorter than the protective conduit.

  17. Stringing and Sagging (1950)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shaheen Nancy Mitman Cathy Ehli Administrators of BPA Mary Jensen Mission Vision Values History Film Vault Film Collection Volume One Film Collection Volume Two 75th Anniversary...

  18. Two-phase convective CO2 dissolution in saline aquifers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlyingmore » two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.« less

  19. Two-phase convective CO2 dissolution in saline aquifers

    SciTech Connect (OSTI)

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlying two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.

  20. Multilayer insulation for the interconnect region in the Accelerator System String Test: A practical engineering approach for a new scheme of design and installation bridges

    SciTech Connect (OSTI)

    Baritchi, D.; Jalloh, A.

    1993-04-01

    In order to minimize the heat leak in the Accelerator System String Test (ASST) inter-connect region, shield bridges and multilayer insulation (MLI) are provided. A sliding joint between shield bridges on adjacent magnets accommodates the contraction that occurs during cooldown. In the original design of the MLI bridges, thermal contraction was provided for by compressing the MLI. During assembly of the interconnect region, it was realized that there was not enough room for the required compression. This resulted in a redesign of the MLI bridges. The new scheme involves splitting and overlapping the MLI. This scheme has worked very well in subsequent assembly of the interconnect region. In this paper, we are going to present the new design scheme. We will also compare this design with the original design and present its advantages.

  1. The geochemistry of formation waters in the Molasse basin of upper Austria

    SciTech Connect (OSTI)

    Andrews, J.N.; Youngman, M.J. ); Goldbrunner, J.E. ); Darling, W.G. )

    1987-01-01

    The geochemistry of formation waters in the Molasse basin of Upper Austria has been investigated to ascertain the extent of meteoric water replacement of the connate interstitial fluids in these sediments. The chemistry, isotopic composition, and dissolved gas contents of the groundwaters and of oil and gas associated brines have been determined. The most superficial sediments of the basin, the Innviertel (Miocene), have been completely flushed by meteoric waters within the last 200 ka. The underlying Hall and Puchkirchen formations (Miocene/Oligocene) form gas reservoirs for biogenic methane, and the associated formation water are chemically and isotopically modified connate brines of the original marine deposition. In the northeastern part of the basin, the connate brines of the deeper sediments (Cretaceous/Jurassic) have been partially or completely replaced by meteoric waters, whereas in the south of the basin these sediments contain high salinity fluids which are substantially of connate origin. These conclusions are supported by the stable isotope composition of the various brines. Oil-associated brines from the Eocene sediments contain large amounts of dissolved radiogenic {sup 40}Ar, which suggests that the oils have migrated from high-temperature environments. The overall geochemical situation confirms the existence of separate hydraulic systems with little interconnection in the several overlying geological horizons.

  2. Effect of water in salt repositories. Final report

    SciTech Connect (OSTI)

    Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

    1983-09-01

    Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

  3. Cerro Prieto cold water injection: effects on nearby production wells

    SciTech Connect (OSTI)

    Truesdell, A.H.; Lippmann, M.J.; De Leon, J.; Rodriguez, M.H.

    1999-07-01

    The liquid-dominated Cerro Prieto geothermal field of northern Baja California, Mexico has been under commercial exploitation since 1973. During the early years of operation, all waste brines were sent to an evaporation pond built west of the production area. In 1989, cooled pond brines began to be successfully injected into the reservoir along the western boundary of the geothermal system. The injection rate varied over the years, and is at present about 20% of the total fluid extracted. As expected under the continental desert conditions prevailing in the area, the temperature and salinity of the pond brines change with the seasons, being higher during the summer and lower during the winter. The chemistry of pond brines is also affected by precipitation of silica, oxidation of H{sub 2}S and reaction with airborne clays. Several production wells in the western part of the field (CP-I area) showed beneficial effects from injection. The chemical (chloride, isotopic) and physical (enthalpy, flow rate) changes observed in producers close to the injectors are reviewed. Some wells showed steam flow increases, in others steam flow decline rates flattened. Because of their higher density, injected brines migrated downward in the reservoir and showed up in deep wells.

  4. Salinity, temperature, oil composition, and oil recovery by waterflooding

    SciTech Connect (OSTI)

    Tang, G.Q.; Morrow, N.R.

    1997-11-01

    The effect of aging and displacement temperatures and brine and oil composition on wettability and the recovery of crude oil by spontaneous imbibition and waterflooding has been investigated. This study is based on displacement tests in Berea sandstone with three crude oils and three reservoir brines (RB`s). Salinity was varied by changing the concentration of total dissolved solids (TDS`s) of the synthetic brine in proportion. Salinity of the connate and invading brines can have a major influence on wettability and oil recovery at reservoir temperature. Oil recovery increased over that for the RB with dilution of both the initial (connate) and invading brine or dilution of either. Aging and displacement temperatures were varied independently. For all crude oils, water wetness and oil recovery increased with increase in displacement temperature. Removal of light components from the crude oil resulted in increased water wetness. Addition of alkanes to the crude oil reduced the water wetness, and increased oil recovery. Relationships between waterflood recovery and rate and extent of oil recovery by spontaneous imbibition are summarized.

  5. Innovative Approaches to Low-Cost Module Manufacturing of String Ribbon Si PV Modules; Final Subcontract Report, March 2002 - January 2005

    SciTech Connect (OSTI)

    Hanoka, J. I.

    2005-10-01

    As a result of this work, Evergreen Solar, Inc., is now poised to take String Ribbon technology to new heights. In the ribbon growth area, Project Gemini-the growth of dual ribbons from a single crucible-has reached or exceeded all the manufacturing goals set for it. This project grew from an R&D concept to a production pilot phase and finally to a full production phase, all within the span of this subcontract. A major aspect of the overall effort was the introduction of controls and instrumentation as in-line diagnostic tools. In the ribbon production area, the result has been a 12% increase in yields, a 10% increase in machine uptime, and the flattest ribbon ever grown at Evergreen. In the cell area, advances in process development and robotic handling of Gemini wafers have contributed, along with the advances in crystal growth, to a yield improvement of 6%. Particularly noteworthy in the cell area was the refinement of the no-etch process whereby the as-grown ribbon surface could be controlled sufficiently to allow this process to succeed as well as it has. This process obviates any need for wet chemistry or etching between ribbon growth and diffusion.

  6. Hydraulic accumulator-compressor for geopressured enhanced oil recovery

    DOE Patents [OSTI]

    Goldsberry, Fred L.

    1988-01-01

    A hydraulic accumulator-compressor vessel using geothermal brine under pressure as a piston to compress waste (CO.sub.2 rich) gas is used in a system having a plurality of gas separators in tandem to recover pipeline quality gas from geothermal brine. A first high pressure separator feeds gas to a membrance separator which separates low pressure waste gas from high pressure quality gas. A second separator produces low pressure waste gas. Waste gas from both separators is combined and fed into the vessel through a port at the top as the vessel is drained for another compression cycle. High pressure brine is then admitted into the vessel through a port at the bottom of the vessel. Check valves control the flow of low pressure waste gas into the vessel and high pressure waste gas out of the vessel.

  7. Overfilling of cavern blamed for LPG blasts

    SciTech Connect (OSTI)

    Not Available

    1992-07-06

    Three explosions and a fire Apr. 7 at an LPG salt dome storage cavern near Brenham, Tex., were triggered when the cavern was overfilled, the Texas Railroad Commission (TRC) has reported. This paper reports that a TRC investigation found that LPG escaped to the surface at the Brenham site through brine injection tubing after excessive fill from an LPG line forced the cavern's water level below the brine tubing's bottom. At the surface, LPG was released into a brine storage pit where it turned into a dense, explosive vapor. At 7:08 a.m., the vapor was ignited by an unknown source. The resulting blast killed three persons and injured 19 and brought operations at the site to a halt.

  8. Research project on CO2 geological storage and groundwaterresources: Large-scale hydrological evaluation and modeling of impact ongroundwater systems

    SciTech Connect (OSTI)

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan,Preston; Zhang,K.; Tsang, Chin-Fu

    2007-10-24

    If carbon dioxide capture and storage (CCS) technologies areimplemented on a large scale, the amounts of CO2 injected and sequesteredunderground could be extremely large. The stored CO2 then replaces largevolumes of native brine, which can cause considerable pressureperturbation and brine migration in the deep saline formations. Ifhydraulically communicating, either directly via updipping formations orthrough interlayer pathways such as faults or imperfect seals, theseperturbations may impact shallow groundwater or even surface waterresources used for domestic or commercial water supply. Possibleenvironmental concerns include changes in pressure and water table,changes in discharge and recharge zones, as well as changes in waterquality. In compartmentalized formations, issues related to large-scalepressure buildup and brine displacement may also cause storage capacityproblems, because significant pressure buildup can be produced. Toaddress these issues, a three-year research project was initiated inOctober 2006, the first part of which is summarized in this annualreport.

  9. Electrodialysis technology for salt recovery from aluminum salt cake

    SciTech Connect (OSTI)

    Hryn, J. N.; Krumdick, G.; Graziano, D.; Sreenivasarao, K.

    2000-02-02

    Electrodialysis technology for recovering salt from aluminum salt cake is being developed at Argonne National Laboratory. Salt cake, a slag-like aluminum-industry waste stream, contains aluminum metal, salt (NaCl and KCl), and nonmetallics (primarily aluminum oxide). Salt cake can be recycled by digesting with water and filtering to recover the metal and oxide values. A major obstacle to widespread salt cake recycling is the cost of recovering salt from the process brine. Electrodialysis technology developed at Argonne appears to be a cost-effective approach to handling the salt brines, compared to evaporation or disposal. In Argonne's technology, the salt brine is concentrated until salt crystals are precipitated in the electrodialysis stack; the crystals are recovered downstream. The technology is being evaluated on the pilot scale using Eurodia's EUR 40-76-5 stack.

  10. Enhanced oil recovery system

    DOE Patents [OSTI]

    Goldsberry, Fred L.

    1989-01-01

    All energy resources available from a geopressured geothermal reservoir are used for the production of pipeline quality gas using a high pressure separator/heat exchanger and a membrane separator, and recovering waste gas from both the membrane separator and a low pressure separator in tandem with the high pressure separator for use in enhanced oil recovery, or in powering a gas engine and turbine set. Liquid hydrocarbons are skimmed off the top of geothermal brine in the low pressure separator. High pressure brine from the geothermal well is used to drive a turbine/generator set before recovering waste gas in the first separator. Another turbine/generator set is provided in a supercritical binary power plant that uses propane as a working fluid in a closed cycle, and uses exhaust heat from the combustion engine and geothermal energy of the brine in the separator/heat exchanger to heat the propane.

  11. Sensitivity of CO2 migration estimation on reservoir temperature and pressure uncertainty

    SciTech Connect (OSTI)

    Jordan, Preston; Doughty, Christine

    2008-11-01

    The density and viscosity of supercritical CO{sub 2} are sensitive to pressure and temperature (PT) while the viscosity of brine is sensitive primarily to temperature. Oil field PT data in the vicinity of WESTCARB's Phase III injection pilot test site in the southern San Joaquin Valley, California, show a range of PT values, indicating either PT uncertainty or variability. Numerical simulation results across the range of likely PT indicate brine viscosity variation causes virtually no difference in plume evolution and final size, but CO{sub 2} density variation causes a large difference. Relative ultimate plume size is almost directly proportional to the relative difference in brine and CO{sub 2} density (buoyancy flow). The majority of the difference in plume size occurs during and shortly after the cessation of injection.

  12. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, Robert; Lu, Peng; Allen, Douglas; Soong, Yee; Hedges, Sheila; Fu, Jaw K.; Dobbs, Charles L.; Degalbo, Angelo; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20 C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  13. A method for quick assessment of CO2 storage capacity in closedand semi-closed saline formations

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Tsang, C.F.; Rutqvist, J.

    2008-02-10

    Saline aquifers of high permeability bounded by overlying/underlying seals may be surrounded laterally by low-permeability zones, possibly caused by natural heterogeneity and/or faulting. Carbon dioxide (CO{sub 2}) injection into and storage in such 'closed' systems with impervious seals, or 'semi-closed' systems with nonideal (low-permeability) seals, is different from that in 'open' systems, from which the displaced brine can easily escape laterally. In closed or semi-closed systems, the pressure buildup caused by continuous industrial-scale CO{sub 2} injection may have a limiting effect on CO{sub 2} storage capacity, because geomechanical damage caused by overpressure needs to be avoided. In this research, a simple analytical method was developed for the quick assessment of the CO{sub 2} storage capacity in such closed and semi-closed systems. This quick-assessment method is based on the fact that native brine (of an equivalent volume) displaced by the cumulative injected CO{sub 2} occupies additional pore volume within the storage formation and the seals, provided by pore and brine compressibility in response to pressure buildup. With nonideal seals, brine may also leak through the seals into overlying/underlying formations. The quick-assessment method calculates these brine displacement contributions in response to an estimated average pressure buildup in the storage reservoir. The CO{sub 2} storage capacity and the transient domain-averaged pressure buildup estimated through the quick-assessment method were compared with the 'true' values obtained using detailed numerical simulations of CO{sub 2} and brine transport in a two-dimensional radial system. The good agreement indicates that the proposed method can produce reasonable approximations for storage-formation-seal systems of various geometric and hydrogeological properties.

  14. Two-Stage, Integrated, Geothermal-CO2 Storage Reservoirs: An Approach for Sustainable Energy Production, CO2-Sequestration Security, and Reduced Environmental Risk

    SciTech Connect (OSTI)

    Buscheck, T A; Chen, M; Sun, Y; Hao, Y; Elliot, T R

    2012-02-02

    We introduce a hybrid two-stage energy-recovery approach to sequester CO{sub 2} and produce geothermal energy at low environmental risk and low cost by integrating geothermal production with CO{sub 2} capture and sequestration (CCS) in saline, sedimentary formations. Our approach combines the benefits of the approach proposed by Buscheck et al. (2011b), which uses brine as the working fluid, with those of the approach first suggested by Brown (2000) and analyzed by Pruess (2006), using CO{sub 2} as the working fluid, and then extended to saline-formation CCS by Randolph and Saar (2011a). During stage one of our hybrid approach, formation brine, which is extracted to provide pressure relief for CO{sub 2} injection, is the working fluid for energy recovery. Produced brine is applied to a consumptive beneficial use: feedstock for fresh water production through desalination, saline cooling water, or make-up water to be injected into a neighboring reservoir operation, such as in Enhanced Geothermal Systems (EGS), where there is often a shortage of a working fluid. For stage one, it is important to find economically feasible disposition options to reduce the volume of brine requiring reinjection in the integrated geothermal-CCS reservoir (Buscheck et al. 2012a). During stage two, which begins as CO{sub 2} reaches the production wells; coproduced brine and CO{sub 2} are the working fluids. We present preliminary reservoir engineering analyses of this approach, using a simple conceptual model of a homogeneous, permeable CO{sub 2} storage formation/geothermal reservoir, bounded by relatively impermeable sealing units. We assess both the CO{sub 2} sequestration capacity and geothermal energy production potential as a function of well spacing between CO{sub 2} injectors and brine/CO{sub 2} producers for various well patterns and for a range of subsurface conditions.

  15. Final report on Weeks Island Monitoring Phase : 1999 through 2004.

    SciTech Connect (OSTI)

    Ehgartner, Brian L.; Munson, Darrell Eugene

    2005-05-01

    This Final Report on the Monitoring Phase of the former Weeks Island Strategic Petroleum Reserve crude oil storage facility details the results of five years of monitoring of various surface accessible quantities at the decommissioned facility. The Weeks Island mine was authorized by the State of Louisiana as a Strategic Petroleum Reserve oil storage facility from 1979 until decommissioning of the facility in 1999. Discovery of a sinkhole over the facility in 1992 with freshwater inflow to the facility threatened the integrity of the oil storage and led to the decision to remove the oil, fill the chambers with brine, and decommission the facility. Thereafter, a monitoring phase, by agreement between the Department of Energy and the State, addressed facility stability and environmental concerns. Monitoring of the surface ground water and the brine of the underground chambers from the East Fill Hole produced no evidence of hydrocarbon contamination, which suggests that any unrecovered oil remaining in the underground chambers has been contained. Ever diminishing progression of the initial major sinkhole, and a subsequent minor sinkhole, with time was verification of the response of sinkholes to filling of the facility with brine. Brine filling of the facility ostensively eliminates any further growth or new formation from freshwater inflow. Continued monitoring of sinkhole response, together with continued surface surveillance for environmental problems, confirmed the intended results of brine pressurization. Surface subsidence measurements over the mine continued throughout the monitoring phase. And finally, the outward flow of brine was monitored as a measure of the creep closure of the mine chambers. Results of each of these monitoring activities are presented, with their correlation toward assuring the stability and environmental security of the decommissioned facility. The results suggest that the decommissioning was successful and no contamination of the

  16. Origin of fluids and the evolution of the Atlantis II deep hydrothermal system, Red Sea: Strontium isotope study

    SciTech Connect (OSTI)

    Anschutz, P.; Blanc, G.; Stille, P.

    1995-12-31

    Atlantis II is the largest and most mineralized of the deeps along the axis of the Red Sea spreading center. Its basaltic substratum is covered by recent layered metalliferous sediments, which precipitated from an overlying brine pool. The {sup 87}Sr/{sup 86}Sr ratio and the strontium concentration of interstitial waters within these sediments range between 0.70708 and 0.70725 and between 43 and 53 ppm, respectively. They are close to what is found for the present-day deep brine pool (0.707105, 45.10 ppm). The strontium concentration and the {sup 87}Sr/{sup 86}Sr ratio of the Atlantis II Deep brines can be derived from those of the interstitial waters of the surrounding Miocene evaporite by hydrothermal interaction with oceanic basaltic rocks at a maximal water/rock ratio 2-3. This water/rock ratio is similar to that calculated for oceanic hydrothermal systems on sediment-free ridges. Interstitial waters show a linear trend on plot of {sup 87}Sr/{sup 86}Sr vs. 1/Sr. The highest strontium concentration and the most radiogenic interstitial waters correspond to sediment samples enriched in iron and manganese oxide minerals. These waters reflect the diagenetic release of strontium by oxide minerals and initially precipitated at the interface between the brine pool and more radiogenic seawater. The solid fraction of the sediment has {sup 87}sr{sup 86}Sr isotopic compositions intermediate to those of the brines and seawater. The solid fraction of the sediment has {sup 87}Sr/{sup 86}Sr isotopic compositions intermediate to those of the brines and seawater. The most radiogenic strontium values were observed in samples strongly enriched in marine microbiota. The gradual isotopic evolution in the lowest part of the western basin sediments testifies to the gradual influence of the hydrothermal activity in the deep in the beginning of the Atlantis II Deep sedimentary history. 62 refs., 6 figs., 2 tabs.

  17. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, Robert; Lu, Peng; Allen, Douglas; Soong, Yee; Hedges, Sheila; Fu, Jaw K.; Dobbs, Charles L.; Degalbo, Angelo; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20º C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  18. Computer simulation of production from geothermal-geopressured aquifers. Final report, October 1, 1978 through January 31, 1983

    SciTech Connect (OSTI)

    Doherty, M.G.; Poonawala, N.A.

    1983-07-01

    The effort utilized a computer to interpret the results of well tests and compile data on gas solubility in brine and the viscosity of brine. A detailed computer reservoir study of a geopressured test well that had been abandoned as a dry hole but became a commercial producer of hydrocarbons is presented. A number of special topical reports pertaining to test activities performed on Department of Energy test wells (MG-T/DOE Amoco Fee No. 1 Well, Leroy Sweezy No. 1 Well, and Pleasant Bayou No. 2 Well) are appended. A referenced article written under this study that appeared in the Journal of Petroleum Technology is also reproduced.

  19. Gravity monitoring of CO2 movement during sequestration: Model studies

    SciTech Connect (OSTI)

    Gasperikova, E.; Hoversten, G.M.

    2008-07-15

    We examine the relative merits of gravity measurements as a monitoring tool for geological CO{sub 2} sequestration in three different modeling scenarios. The first is a combined CO{sub 2} enhanced oil recovery (EOR) and sequestration in a producing oil field, the second is sequestration in a brine formation, and the third is for a coalbed methane formation. EOR/sequestration petroleum reservoirs have relatively thin injection intervals with multiple fluid components (oil, hydrocarbon gas, brine, and CO{sub 2}), whereas brine formations usually have much thicker injection intervals and only two components (brine and CO{sub 2}). Coal formations undergoing methane extraction tend to be thin (3-10 m), but shallow compared to either EOR or brine formations. The injection of CO{sub 2} into the oil reservoir produced a bulk density decrease in the reservoir. The spatial pattern of the change in the vertical component of gravity (G{sub z}) is directly correlated with the net change in reservoir density. Furthermore, time-lapse changes in the borehole G{sub z} clearly identified the vertical section of the reservoir where fluid saturations are changing. The CO{sub 2}-brine front, on the order of 1 km within a 20 m thick brine formation at 1900 m depth, with 30% CO{sub 2} and 70% brine saturations, respectively, produced a -10 Gal surface gravity anomaly. Such anomaly would be detectable in the field. The amount of CO{sub 2} in a coalbed methane test scenario did not produce a large enough surface gravity response; however, we would expect that for an industrial size injection, the surface gravity response would be measurable. Gravity inversions in all three scenarios illustrated that the general position of density changes caused by CO{sub 2} can be recovered, but not the absolute value of the change. Analysis of the spatial resolution and detectability limits shows that gravity measurements could, under certain circumstances, be used as a lower-cost alternative to seismic

  20. Scale Resistant Heat Exchanger for Low Temperature Geothermal Binary Cycle Power Plant

    SciTech Connect (OSTI)

    Hays, Lance G.

    2014-11-18

    Phase 1 of the investigation of improvements to low temperature geothermal power systems was completed. The improvements considered were reduction of scaling in heat exchangers and a hermetic turbine generator (eliminating seals, seal system, gearbox, and lube oil system). A scaling test system with several experiments was designed and operated at Coso geothermal resource with brine having a high scaling potential. Several methods were investigated at the brine temperature of 235 ºF. One method, circulation of abradable balls through the brine passages, was found to substantially reduce scale deposits. The test heat exchanger was operated with brine outlet temperatures as low as 125 ºF, which enables increased heat input available to power conversion systems. For advanced low temperature cycles, such as the Variable Phase Cycle (VPC) or Kalina Cycle, the lower brine temperature will result in a 20-30% increase in power production from low temperature resources. A preliminary design of an abradable ball system (ABS) was done for the heat exchanger of the 1 megawatt VPC system at Coso resource. The ABS will be installed and demonstrated in Phase 2 of this project, increasing the power production above that possible with the present 175 ºF brine outlet limit. A hermetic turbine generator (TGH) was designed and manufacturing drawings produced. This unit will use the working fluid (R134a) to lubricate the bearings and cool the generator. The 200 kW turbine directly drives the generator, eliminating a gearbox and lube oil system. Elimination of external seals eliminates the potential of leakage of the refrigerant or hydrocarbon working fluids, resulting in environmental improvement. A similar design has been demonstrated by Energent in an ORC waste heat recovery system. The existing VPC power plant at Coso was modified to enable the “piggyback” demonstration of the TGH. The existing heat exchanger, pumps, and condenser will be operated to provide the required

  1. Removal of Radionuclides from Waste Water at Fukushima Daiichi Nuclear Power Plant: Desalination and Adsorption Methods - 13126

    SciTech Connect (OSTI)

    Kani, Yuko; Kamosida, Mamoru; Watanabe, Daisuke; Asano, Takashi; Tamata, Shin

    2013-07-01

    Waste water containing high levels of radionuclides due to the Fukushima Daiichi Nuclear Power Plant accident, has been treated by the adsorption removal and reverse-osmosis (RO) desalination to allow water re-use for cooling the reactors. Radionuclides in the waste water are collected in the adsorbent medium and the RO concentrate (RO brine) in the water treatment system currently operated at the Fukushima Daiichi site. In this paper, we have studied the behavior of radionuclides in the presently applied RO desalination system and the removal of radionuclides in possible additional adsorption systems for the Fukushima Daiichi waste water treatment. Regarding the RO desalination system, decontamination factors (DFs) of the elements present in the waste water were obtained by lab-scale testing using an RO unit and simulated waste water with non-radioactive elements. The results of the lab-scale testing using representative elements showed that the DF for each element depended on its hydrated ionic radius: the larger the hydrated ionic radius of the element, the higher its DF is. Thus, the DF of each element in the waste water could be estimated based on its hydrated ionic radius. For the adsorption system to remove radionuclides more effectively, we studied adsorption behavior of typical elements, such as radioactive cesium and strontium, by various kinds of adsorbents using batch and column testing. We used batch testing to measure distribution coefficients (K{sub d}s) for cesium and strontium onto adsorbents under different brine concentrations that simulated waste water conditions at the Fukushima Daiichi site. For cesium adsorbents, K{sub d}s with different dependency on the brine concentration were observed based on the mechanism of cesium adsorption. As for strontium, K{sub d}s decreased as the brine concentration increased for any adsorbents which adsorbed strontium by intercalation and by ion exchange. The adsorbent titanium oxide had higher K{sub d}s and it

  2. Colloid formation study of U, Th, Ra, Pb, Po, Sr, Rb, and Cs in briny (high ionic strength) groundwaters

    SciTech Connect (OSTI)

    Maiti, T.C.; Smith, M.R.; Laul, J.C.

    1989-01-01

    Colloid formation of uranium, thorium, radium, lead, polonium, strontium, rubidium, and cesium in briny (high ionic strength) groundwaters is studied to predict their capability as vectors for transporting radionuclides. This knowledge is essential in developing models to infer the transport of radionuclides from the source region to the surrounding environment. Except polonium, based on the experimental results, colloid formation of uranium, thorium, radium, lead, strontium, rubidium, and cesium is unlikely in brines with compositions similar to the synthetic Palo Duro Basin brine. This observation of no colloid formation is explained by electrokinetic theory and inorganic solution chemistry.

  3. CX-001190: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    An Integrated Experimental and Numerical Study: Developing a Reaction Transport Model that Couples Chemical Reactions of Mineral Dissolution/Precipitation with Spatial and Temporal Flow Variations in Carbon Dioxide/Brine/Rock SystemsCX(s) Applied: A9, B3.6Date: 03/21/2010Location(s): Minneapolis, MinnesotaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  4. CX-000459: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine Carbon Dioxide SequestrationCX(s) Applied: A9, B3.6Date: 12/07/2009Location(s): Pasadena, CaliforniaOffice(s): Fossil Energy, National Energy Technology Laboratory

  5. SImbol Materials Lithium Extraction Operating Data From Elmore and Featherstone Geothermal Plants

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Stephen Harrison

    2015-07-08

    The data provided in this upload is summary data from its Demonstration Plant operation at the geothermal power production plants in the Imperial Valley. The data provided is averaged data for the Elmore Plant and the Featherstone Plant. Included is both temperature and analytical data (ICP_OES). Provide is the feed to the Simbol Process, post brine treatment and post lithium extraction.

  6. Dixie Valley Binary Cycle Production Data 2013 YTD

    SciTech Connect (OSTI)

    Lee, Vitaly

    2013-10-18

    Proving the technical and economic feasibility of utilizing the available unused heat to generate additional electric power from a binary power plant from the low-temperature brine at the Dixie Valley Geothermal Power Plant. Monthly data for Jan 2013-September 2013

  7. Process for separating dissolved solids from a liquid using an anti-solvent and multiple effect evaporators

    DOE Patents [OSTI]

    Daniels, Edward J.; Jody, Bassam J.; Bonsignore, Patrick V.

    1994-01-01

    A process and system for treating aluminum salt cake containing water soluble halide salts by contacting the salt cake with water to dissolve water soluble halide salts forming a saturated brine solution. Transporting a portion of about 25% of the saturated brine solution to a reactor and introducing into the saturated brine solution at least an equal volume of a water-miscible low-boiling organic material such as acetone to precipitate a portion of the dissolved halide salts forming a three-phase mixture of an aqueous-organic-salt solution phase and a precipitated salt phase and an organic rich phase. The precipitated salt phase is separated from the other phases and the organic rich phase is recycled to the reactor. The remainder of the saturated brine solution is sent to a multiple effect evaporator having a plurality of stages with the last stage thereof producing low grade steam which is used to boil off the organic portion of the solution which is recycled.

  8. Process for separating dissolved solids from a liquid using an anti-solvent and multiple effect evaporators

    DOE Patents [OSTI]

    Daniels, E.J.; Jody, B.J.; Bonsignore, P.V.

    1994-07-19

    A process and system are disclosed for treating aluminum salt cake containing water soluble halide salts by contacting the salt cake with water to dissolve water soluble halide salts forming a saturated brine solution. Transporting a portion of about 25% of the saturated brine solution to a reactor and introducing into the saturated brine solution at least an equal volume of a water-miscible low-boiling organic material such as acetone to precipitate a portion of the dissolved halide salts forming a three-phase mixture of an aqueous-organic-salt solution phase and a precipitated salt phase and an organic rich phase. The precipitated salt phase is separated from the other phases and the organic rich phase is recycled to the reactor. The remainder of the saturated brine solution is sent to a multiple effect evaporator having a plurality of stages with the last stage thereof producing low grade steam which is used to boil off the organic portion of the solution which is recycled. 3 figs.

  9. Extent of water-rock interactions in Lower Permian Wolfcamp carbonates, Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Fisher, R.S.; Posey, H.H.

    1985-01-01

    A laterally-extensive permeable zone in upper Wolfcampian carbonate strata constitutes the first important transmissive unit below a thick evaporite sequence that is being considered for nuclear waste isolation. The extent of water-rock interaction was evaluated by comparing the chemical and isotopic composition of formation water and core collected at four DOE test wells. Wolfcamp mineralogy is dominantly calcite and dolomite with minor anhydrite at each of the four sites despite minor variations in depositional environment, diagenetic alteration, and abundance of clastic material. Isotopic compositions of calcite and dolomite and of anhydrite are within the ranges expected for Permian marine sediments altered by early diagenesis. Wolfcamp formation water compositions are more variable than host rock compositions, and are not completely controlled by local water-rock equilibria. Wolfcamp brines from two wells in the western part of the basin have depleted isotopic compositions relative to the two eastern wells and have not equilibrated with Wolfcamp carbonates, whereas the eastern fluids have. Strontium in the western samples is more radiogenic than that of the eastern samples, indicating a greater influence of clays or feldspars on the western fluids. Comparison of water and rock compositions suggests: (1) the western brines have interacted less with the carbonate host than the eastern brines due to shorter residence times or greater water: rock ratios, and (2) the minerals encountered along flow paths prior to entering the Wolfcamp are different for the western and eastern Wolfcamp brines.

  10. Code System to Calculate Waste-Isolation Flow and Transport.

    Energy Science and Technology Software Center (OSTI)

    1999-10-18

    Version 00 SWIFT solves the coupled or individual equations governing fluid flow, heat transport, brine displacement, and radionuclide displacement in geologic media. Fluid flow may be transient or steady state. One, two, or three dimensions are available, and transport of radionuclides chains is possible.

  11. An analysis of weep holes as a product detection device for underground compensated LPG storage systems

    SciTech Connect (OSTI)

    Sarica, C.; Demir, H.M.; Brill, J.P.

    1996-09-01

    Weep holes have been used widely to detect the presence of Liquefied Petroleum Gases (LPG) in brine for underground compensated storage systems. When the brine level drops below the weep hole, LPG product enters the brine production system causing an increase in both tubing head pressure and flow rate. To prevent cavern overfill, a cavern shutdown is initiated upon detection of LPG in the surface brine system by pressure or flow instruments at the tubing head. In this study, we have investigated the multiphase flow characteristics of weep hole LPG detection systems to correctly estimate the operating limits. A simple and easy to use model has been developed to predict the tubing head pressure and flow rate increases. The model can be used to implement safer and more efficient operation procedures for underground compensated LPG storage systems. The model predictions for a typical field case are presented. An analysis of weep holes as product detection devices for LPG storage reservoirs has been carried out. It was found that the increases in pressure and flow rates at the tubing head change as a function of injection flow rate of the product. Therefore, a thorough consideration of cavern operating parameters is necessary to evaluate the use constant pressure and flow rate values to initiate emergency shut down of the cavern.

  12. Thermoelectric Materials Development for Low Temperature Geothermal Power Generation

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Tim Hansen

    2016-01-29

    Data includes characterization results for novel thermoelectric materials developed specifically for power generation from low temperature geothermal brines. Materials characterization data includes material density, thickness, resistance, Seebeck coefficient. This research was carried out by Novus Energy Partners in Cooperation with Southern Research Institute for a Department of Energy Sponsored Project.

  13. Geothermal injection treatment: process chemistry, field experiences, and design options

    SciTech Connect (OSTI)

    Kindle, C.H.; Mercer, B.W.; Elmore, R.P.; Blair, S.C.; Myers, D.A.

    1984-09-01

    The successful development of geothermal reservoirs to generate electric power will require the injection disposal of approximately 700,000 gal/h (2.6 x 10/sup 6/ 1/h) of heat-depleted brine for every 50,000 kW of generating capacity. To maintain injectability, the spent brine must be compatible with the receiving formation. The factors that influence this brine/formation compatibility and tests to quantify them are discussed in this report. Some form of treatment will be necessary prior to injection for most situations; the process chemistry involved to avoid and/or accelerate the formation of precipitate particles is also discussed. The treatment processes, either avoidance or controlled precipitation approaches, are described in terms of their principles and demonstrated applications in the geothermal field and, when such experience is limited, in other industrial use. Monitoring techniques for tracking particulate growth, the effect of process parameters on corrosion and well injectability are presented. Examples of brine injection, preinjection treatment, and recovery from injectivity loss are examined and related to the aspects listed above.

  14. Localized corrosion in materials for geothermal power

    SciTech Connect (OSTI)

    Roy, A.; Peterson, J.A.; Hehemann, R.F.; Troiano, A.R.

    1980-12-01

    Ten different commercially available steels were examined for general and localized corrosion in 14 different environmental conditions. The chloride concentration was varied from 1 to 24 percent. In general, the influence of chloride was minor and seemed slightly more agressive at 1 than at 5 or 24 percent. The brines were examined with and without saturated H/sub 2/S. Saturation with H/sub 2/S increased the general corrosion rate but appeared to reduce crevice attack in the acid solutions. Selected brines were examined in both acid and neutral conditions. As anticipated, a neutral brine with or without H/sub 2/S greatly reduced all forms of attack. Tests at 150/sup 0/C exhibited greater attack than at ambient. A relatively new alloy, Ni-Cu-Cb, consistently demonstrated good resistance to both general and localized attack. Typical economical N80 grade steels clearly demonstrated the strong dependence of localized attack on inclusion variables and offer great promise in the minimized and/or controlled inclusion condition. The Cr-Mo steels surprisingly did not look good at ambient but did exhibit substantial improvement at 150/sup 0/C. The laboratory tests gave higher weight loss values for similar steels recently tested in a well; although in neutral brines without saturated H/sub 2/S, the difference was not significantly larger.

  15. CX-007510: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion for Tear Down, Inspect and Repair Bayou Choctaw Brine Filters at BDW Pad 1 CX(s) Applied: B1.3 Date: 11/29/2011 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  16. Balanced-activity improved inverse emulsion to inhibit brittle lutite hydration in oil fields

    SciTech Connect (OSTI)

    Olmedo, E. P.; de J. Hernandez Alvarez, R.; Barrera, C. D.; Ramos, J. D. G.

    1984-10-02

    An improved inverse emulsion for use as a drilling fluid that inhibits brittle lutite hydration. The emulsion includes a heavy oil; brine; a viscosity agent with thermostabilizing properties; an emulsifying agent; a thickening agent; a gelatinizing additive; and an alkaline earth metal hydroxide. The emulsion avoids hole collapsing and improves well gage stability.

  17. CX-011808: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Advanced Analytical Methods for Air and Stray Gas Emissions and Produced Brine Characterization CX(s) Applied: A9, A11, B3.6 Date: 01/27/2014 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory

  18. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Dihydrogen sulfide 70 5. 5 cycle thermal shock (One cycle: 300 o C-24hr -heat and 25 o C ... geo- brine fluid Heat-quenching thermal shock EPDM (1) 2 3 2 3 4 Type I FKM (1x2.5) 4 5 ...

  19. EIS-0001: Strategic Petroleum Reserve, Bryan Mound Salt Dome, Brazoria County, Texas

    Broader source: Energy.gov [DOE]

    The Strategic Petroleum Reserve prepared this SEIS to address the environmental impacts of construction and operation of two types of brine disposal systems and a new water supply system. This EIS supplements FES 76/77-6, Bryan Mound Storage Site.

  20. CX-014078: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Developing and Validating Pressure Management and Plume Control Strategies in the Williston Basin through a Brine Extraction and Storage Test CX(s) Applied: A9, B3.6, B4.6Date: 07/22/2015 Location(s): North DakotaOffices(s): National Energy Technology Laboratory

  1. Fresh Water Generation from Aquifer-Pressured Carbon Storage

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Bourcier, W L; Wolfe, T; Haussmann, C

    2010-02-19

    Can we use the pressure associated with sequestration to make brine into fresh water? This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including reverse osmosis (RO) and nanofiltration (NF). Possible products are: Drinking water, Cooling water, and Extra aquifer space for CO{sub 2} storage. The conclusions are: (1) Many saline formation waters appear to be amenable to largely conventional RO treatment; (2) Thermodynamic modeling indicates that osmotic pressure is more limiting on water recovery than mineral scaling; (3) The use of thermodynamic modeling with Pitzer's equations (or Extended UNIQUAC) allows accurate estimation of osmotic pressure limits; (4) A general categorization of treatment feasibility is based on TDS has been proposed, in which brines with 10,000-85,000 mg/L are the most attractive targets; (5) Brines in this TDS range appear to be abundant (geographically and with depth) and could be targeted in planning future CCS operations (including site selection and choice of injection formation); and (6) The estimated cost of treating waters in the 10,000-85,000 mg/L TDS range is about half that for conventional seawater desalination, due to the anticipated pressure recovery.

  2. CX-100019: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Determination of Rare Earths in Geothermal Brines and Evaluation of Potential Extraction Techniques CX(s) Applied: A9, B3.1, B3.6 Date: 08/18/2014 Location(s): California Offices(s): Golden Field Office Technology Office: Geothermal Technologies Award Number: DE-EE0006750

  3. Actinide chemistry research supporting the Waste Isolation Pilot Plant (WIPP): FY94 results

    SciTech Connect (OSTI)

    Novak, C.F.

    1995-08-01

    This document contains six reports on actinide chemistry research supporting the Waste Isolation Pilot Plant (WIPP). These reports, completed in FY94, are relevant to the estimation of the potential dissolved actinide concentrations in WIPP brines under repository breach scenarios. Estimates of potential dissolved actinide concentrations are necessary for WIPP performance assessment calculations. The specific topics covered within this document are: the complexation of oxalate with Th(IV) and U(VI); the stability of Pu(VI) in one WIPP-specific brine environment both with and without carbonate present; the solubility of Nd(III) in a WIPP Salado brine surrogate as a function of hydrogen ion concentration; the steady-state dissolved plutonium concentrations in a synthetic WIPP Culebra brine surrogate; the development of a model for Nd(III) solubility and speciation in dilute to concentrated sodium carbonate and sodium bicarbonate solutions; and the development of a model for Np(V) solubility and speciation in dilute to concentrated sodium Perchlorate, sodium carbonate, and sodium chloride media.

  4. Prediction of dissolved actinide concentrations in concentrated electrolyte solutions: a conceptual model and model results for the Waste Isolation Pilot Plant (WIPP)

    SciTech Connect (OSTI)

    Novak, C.F.; Moore, R.C.; Bynum, R.V.

    1996-10-25

    The conceptual model for WIPP dissolved concentrations is a description of the complex natural and artificial chemical conditions expected to influence dissolved actinide concentrations in the repository. By a set of physical and chemical assumptions regarding chemical kinetics, sorption substrates, and waste-brine interactions, the system was simplified to be amenable to mathematical description. The analysis indicated that an equilibrium thermodynamic model for describing actinide solubilities in brines would be tractable and scientifically supportable. This paper summarizes the conceptualization and modeling approach and the computational results as used in the WIPP application for certification of compliance with relevant regulations for nuclear waste repositories. The WIPP site contains complex natural brines ranging from sea water to 10x more concentrated than sea water. Data bases for predicting solubility of Am(III) (as well as Pu(III) and Nd(III)), Th(IV), and Np(V) in these brines under potential repository conditions have been developed, focusing on chemical interactions with Na, K, Mg, Cl, SO{sub 4}, and CO{sub 3} ions, and the organic acid anions acetate, citrate, EDTA, and oxalate. The laboratory and modeling effort augmented the Harvie et al. parameterization of the Pitzer activity coefficient model so that it could be applied to the actinides and oxidation states important to the WIPP system.

  5. Final Technical Report, DE-SC0000581

    SciTech Connect (OSTI)

    Douglas C. Lynn, Executive Director

    2010-12-28

    The focus of the CEHMM award was alternative energy research and education. The objective of the CEHMM algae to biodiesel project was to determine the viability and feasibility of using algae as a feedstock for commercial biodiesel production. The project investigated the propagation, harvesting and extraction of oil from a salt/brine water algae in open raceway ponds.

  6. Test plan for laboratory and modeling studies of repository and radionuclide chemistry for the Waste Isolation Pilot Plant

    SciTech Connect (OSTI)

    Brush, L.H.

    1990-01-29

    This Test Plan describes laboratory and modeling studies of: the chemistry of brines that could enter Waste Isolation Pilot Plant (WIPP) disposal rooms; the effects of anoxic corrosion of metals in steel containers and the waste on the gas and H{sub 2}O budgets of the repository; the effects of microbial activity, especially microbial degradation of cellulosics in the waste, on the gas and H{sub 2}O budgets of the repository, the Eh and pH of any brine present, and the chemical behavior of radionuclides; the effects of radiolysis on the gas and H{sub 2}O budgets of the repository; the efficacy of backfill additives proposed to remove microbially produced CO{sub 2} or prevent the formation of H{sub 2} from anoxic corrosion, and their effects on repository chemistry; the chemical behavior of Pu, Am, Th, and U in WIPP brines; additional development of the EQ3/6 geochemical software package for use in predicting the behavior of silicates and radionuclides in brines. This Test Plan describes studies of the chemical behavior of the repository as currently designed, and the chemical behavior of radionuclides under these conditions. Addenda will discuss additional studies relevant to design modifications, especially reprocessed waste, and chemically hazardous waste constituents. 165 refs., 7 tabs.

  7. Energy Department Selects Projects to Demonstrate Feasibility of Producing Usable Water from CO2 Storage Sites

    Broader source: Energy.gov [DOE]

    Today, the Department of Energy (DOE) announced the selection of two projects that will test emerging enhanced water recovery (EWR) technologies for their potential to produce useable water from carbon dioxide (CO2) storage sites. The two projects were competitively selected from the five Brine Extraction Storage Test (BEST) projects awarded in September 2015.

  8. Low-Salinity Waterflooding to Improve Oil Recovery - Historical Field Evidence

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-11-01

    Waterflooding is by far the most widely applied method of improved oil recovery. Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of wa-terfloods. Laboratory water-flood tests and single-well tracer tests have shown that injection of dilute brine can increase oil recovery, but work designed to test the method on a field scale has not yet been undertaken. Historical waterflood records could unintentionally provide some evidence of improved recovery from waterflooding with lower salinity brine. Nu-merous fields in the Powder River basin of Wyoming have been waterflooded using low salinity brine (about 500 ppm) obtained from the Madison limestone or Fox Hills sandstone. Three Minnelusa formation fields in the basin were identified as potential candidates for waterflood comparisons based on the salinity of the connate and injection water. Historical pro-duction and injection data for these fields were obtained from the public record. Field waterflood data were manipulated to be displayed in the same format as laboratory coreflood re-sults. Recovery from fields using lower salinity injection wa-ter was greater than that using higher salinity injection wa-ter—matching recovery trends for laboratory and single-well tests.

  9. Recent seafloor metallogeneses: examples from the Atlantis II Deep, Red Sea and 21/sup 0/N East Pacific Rise

    SciTech Connect (OSTI)

    Zierenberg, R.A.

    1983-01-01

    Massive sulfide from 21/sup 0/N East Pacific Rise consists of pyrrhotite, cubic cubanite, wurtzite, chalcopyrite, pyrite, sphalerite, marcasite, and traces of galena. The samples show a complex paragenesis with extensive replacement and sulfur isotope disequilibrium. Sulfides in the Atlantis II Deep, Red Sea are very fine grained pyrrhotite, cubic cubanite, chalcopyrite, sphalerite, and pyrite which are interlayered with iron phyllosilicates. Epigenetic veins cutting unlithified metalliferous sediment in the Atlantis II are the conduits for the entry or new hot brine into the Deep. Vein mineralogy is dominated by talc and anhydrite with subordinate sulfides and phyllosilicates. Vertical zoning of vein minerals is related to cooling of hydrothermal fluid. Stable isotope ratios indicate depositional temperatures up to 300/sup 0/C. Stable isotope ratios also suggest that cooling of the hydrothermal fluid is caused by mixing with cooler brine having the approximate composition of the lower brine layer. Geochemical modeling of mixing successfully predicts the observed vertical zonation. The 21/sup 0/N East Pacific Rise deposit and the Atlantis II Deep have similar geochemical systems dominated by interaction with hot tholeiitic basalt. The differences in the deposits are related to their different depositional environments. The 21/sup 0/N East Pacific Rise deposit is forming directly on the seafloor in contact with cold oxygenated seawater, while the Atlantis II Deep deposit is forming beneath a warm, saline, anoxic brine pool.

  10. SImbol Materials Lithium Extraction Operating Data From Elmore and Featherstone Geothermal Plants

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Stephen Harrison

    The data provided in this upload is summary data from its Demonstration Plant operation at the geothermal power production plants in the Imperial Valley. The data provided is averaged data for the Elmore Plant and the Featherstone Plant. Included is both temperature and analytical data (ICP_OES). Provide is the feed to the Simbol Process, post brine treatment and post lithium extraction.

  11. CX-011807: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Advanced Analytical Methods for Air and Stray Gas Emissions and Produced Brine Characterization CX(s) Applied: A9, A11, B3.1, B3.6 Date: 01/27/2014 Location(s): Pennsylvania, Pennsylvania Offices(s): National Energy Technology Laboratory

  12. Thermal waters and the effect of their use on the environment

    SciTech Connect (OSTI)

    Dvorov, I.M.; Dvorov, V.I.

    1982-01-01

    A few of the many types and quantities of salt and gas components in hydrothermal waters are examined. In successive order, the chemical composition of hydrothermal fluids are considered from fresh water to brines. The undesirable effects of the thermoenergetic and chemical use of thermal waters on nature are considered. (MHR)

  13. Multi-stage flash degaser

    DOE Patents [OSTI]

    Rapier, P.M.

    1980-06-26

    A multi-stage flash degaser is incorporated in an energy conversion system having a direct-contact, binary-fluid heat exchanger to remove essentially all of the noncondensable gases from geothermal brine ahead of the direct-contact binary-fluid heat exchanger in order that the heat exchanger and a turbine and condenser of the system can operate at optimal efficiency.

  14. CX-014268: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Nonlinear Acoustic Methods for the Detection and Monitoring of Carbon Dioxide/Brine Leak... CX(s) Applied: A1, A9, B3.6, B3.15Date: 08/31/2015 Location(s): New MexicoOffices(s): National Energy Technology Laboratory

  15. Risk Reduction and Soil Ecosystem Restoration in an Active Oil Producing Area in an Ecologically Sensitive Setting

    SciTech Connect (OSTI)

    Kerry L. Sublette; Greg Thoma; Kathleen Duncan

    2006-01-01

    The empowerment of small independent oil and gas producers to solve their own remediation problems will result in greater environmental compliance and more effective protection of the environment as well as making small producers more self-reliant. In Chapter 1 we report on the effectiveness of a low-cost method of remediation of a combined spill of crude oil and brine in the Tallgrass Prairie Preserve in Osage County, OK. Specifically, we have used hay and fertilizer as amendments for remediation of both the oil and the brine. No gypsum was used. Three spills of crude oil plus produced water brine were treated with combinations of ripping, fertilizers and hay, and a downslope interception trench in an effort to demonstrate an inexpensive, easily implemented, and effective remediation plan. There was no statistically significant effect of treatment on the biodegradation of crude oil. However, TPH reduction clearly proceeded in the presence of brine contamination. The average TPH half-life considering all impacted sites was 267 days. The combination of hay addition, ripping, and a downslope interception trench was superior to hay addition with ripping, or ripping plus an interception trench in terms of rates of sodium and chloride leaching from the impacted sites. Reductions in salt inventories (36 months) were 73% in the site with hay addition, ripping and an interception trench, 40% in the site with hay addition and ripping only, and < 3% in the site with ripping and an interception trench.

  16. CX-000482: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Project Number MS-09-116 - Structural Assessment of Big Hill Raw Water Intake Structure, Big Hill Brine Disposal Pump Pad and Bryan Mound Raw Water Intake StructureCX(s) Applied: B1.3Date: 12/29/2009Location(s): TexasOffice(s): Fossil Energy, Strategic Petroleum Reserve Field Office

  17. Results of site validation experiments. Volume II. Supporting documents 5 through 14

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    Volume II contains the following supporting documents: Summary of Geologic Mapping of Underground Investigations; Logging of Vertical Coreholes - ''Double Box'' Area and Exploratory Drift; WIPP High Precision Gravity Survey; Basic Data Reports for Drillholes, Brine Content of Facility Internal Strata; Mineralogical Content of Facility Interval Strata; Location and Characterization of Interbedded Materials; Characterization of Aquifers at Shaft Locations; and Permeability of Facility Interval Strate.

  18. Microbial oxidation of soluble sulfide in produced water from the Bakkeen Sands

    SciTech Connect (OSTI)

    Gevertz, D.; Zimmerman, S.; Jenneman, G.E.

    1995-12-31

    The presence of soluble sulfide in produced water results in problems for the petroleum industry due to its toxicity, odor, corrosive nature, and potential for wellbore plugging. Sulfide oxidation by indigenous nitrate-reducing bacteria (NRB) present in brine collected from wells at the Coleville Unit (CVU) in Saskatchewan, Canada, was investigated. Sulfide oxidation took place readily when nitrate and phosphate were added to brine enrichment cultures, resulting in a decrease in sulfide levels of 99-165 ppm to nondetectable levels (< 3.3 ppm). Produced water collected from a number of producing wells was screened to determine the time required for complete sulfide oxidation, in order to select candidate wells for treatment. Three wells were chosen, based on sulfide removal in 48 hours or less. These wells were treated down the backside of the annulus with a solution containing 10 mM KNO{sub 3} and 100 {mu}M NaH{sub 2}PO{sub 4}. Following a 24- to 72-hour shut-in, reductions in pretreatment sulfide levels of greater than 90% were observed for two of the wells, as well as sustained sulfide reductions of 50% for at least two days following startup. NRB populations in the produced brine were observed to increase significantly following treatment, but no significant increases in sulfate-reducing bacteria were observed. These results demonstrate the technical feasibility of stimulating indigenous populations of NRB to remediate and control sulfide in produced brine.

  19. Kalispel Resident Fish Project : Tribal Hatchery Operations and Maintenance Annual Report, 2002.

    SciTech Connect (OSTI)

    Nenema, David

    2003-03-01

    The Kalispel Tribal hatchery successfully spawned largemouth bass broodfish in spring 2002. Approximately 150,000 eggs were produced and hatched. These fry were started on brine shrimp for a period of ten days. At this time, the fry needed more abundance food supply. Cannibalism started and the hatchery staff transferred the remaining fry to the river in hopes that some fish would survive.

  20. Process chemistry monitoring at the HGP-A power plant: analytical results, process problems and modifications

    SciTech Connect (OSTI)

    Thomas, D.M.

    1982-10-01

    The HGP-A generator plant began operations on June 12, 1981 and came on-line on a continuous basis on March 1, 1982. During this period process problems were identified and, in most cases, plant modifications have eliminated the difficulties. Silica in the brine was stable at a pH 7.5, however, at a pH above 9.5 deposition of silica was triggered in a brine disposal system and required abandonment of the hydrogen sulfide abatement process originally proposed for the brine system. The steam phase sulfide abatement system for standby conditions was 90% effective, although superheat in the treatment system reduced abatement efficiency. Brine carryover through the separator was very low; however, scale deposition on the turbine blades resulted in substantial damage to the turbine. Non-condensable gases in the condenser were weakly partitioned into the liquid phase, and about 99% were carried into the off-gas treatment system which was found to be approximately 99% effective.

  1. Investigation and evaluation of geopressured-geothermal wells. Final report, Tenneco Fee N No. 1 Well Terrebonne Paris, Louisiana

    SciTech Connect (OSTI)

    Dobson, R.J.; Hartsock, J.H.; McCoy, R.L.; Rodgers, J.A.

    1980-09-01

    The reservoir conditions that led to the choice of this well as the fifth well of opportunity are described as well as the attempts to complete the well for high-volume brine production. Individual opinions concerning underlying and conributing causes for the liner failure which aborted the completion attempt are included. (MHR)

  2. Expected environments in high-level nuclear waste and spent fuel repositories in salt

    SciTech Connect (OSTI)

    Claiborne, H.C.; Rickertsen, L.D., Graham, R.F.

    1980-08-01

    The purpose of this report is to describe the expected environments associated with high-level waste (HLW) and spent fuel (SF) repositories in salt formations. These environments include the thermal, fluid, pressure, brine chemistry, and radiation fields predicted for the repository conceptual designs. In this study, it is assumed that the repository will be a room and pillar mine in a rock-salt formation, with the disposal horizon located approx. 2000 ft (610 m) below the surface of the earth. Canistered waste packages containing HLW in a solid matrix or SF elements are emplaced in vertical holes in the floor of the rooms. The emplacement holes are backfilled with crushed salt or other material and sealed at some later time. Sensitivity studies are presented to show the effect of changing the areal heat load, the canister heat load, the barrier material and thickness, ventilation of the storage room, and adding a second row to the emplacement configuration. The calculated thermal environment is used as input for brine migration calculations. The vapor and gas pressure will gradually attain the lithostatic pressure in a sealed repository. In the unlikely event that an emplacement hole will become sealed in relatively early years, the vapor space pressure was calculated for three scenarios (i.e., no hole closure - no backfill, no hole closure - backfill, and hole closure - no backfill). It was assumed that the gas in the system consisted of air and water vapor in equilibrium with brine. A computer code (REPRESS) was developed assuming that these changes occur slowly (equilibrium conditions). The brine chemical environment is outlined in terms of brine chemistry, corrosion, and compositions. The nuclear radiation environment emphasized in this report is the stored energy that can be released as a result of radiation damage or crystal dislocations within crystal lattices.

  3. Offshore oceanographic and environmental monitoring services for the Strategic Petroleum Reserve. Volume I. Appendices. Annual report for the Bryan Mound Site, September 1982-August 1983

    SciTech Connect (OSTI)

    1984-03-01

    The Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging brine into the coastal waters offshore of Freeport, Texas on March 10, 1980. This report describes the findings of a team of Texas A and M University scientists and engineers who have conducted a study to evaluate the effects of the Bryan Mound brine discharge on the marine environment. The study addresses the areas of physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos and data management. It focuses on the period from September 1982 through August 1983. The ambient physical environment and its temporal and spatial variability were studied by means of continuously recording in situ current/conductivitiy/temperature meters and twelve, one-day synoptic hydrographic cruises. The quarterly water and sediment quality data show a small increase in salinity, sodium and chloride ions occurs in the bottom waters and sediment pore waters near the diffuser relative to those values measured at stations farther away. Data from the brine plume study for this reporting study show the largest areal extent within the +1 o/oo above ambient salinity contour was 40.0 km/sup 2/ which occurred on August 11, 1983. It appears that brine disposal at Bryan Mound has had neglible if any influence on the nekton community surrounding the diffuser. The benthic quarterly data from 26 stations, including 7 collections made after the diffuser outflow rate was increased to 1,000,000 barrels/day, show the total numbers of species at the diffuser station were higher than most other nearfield stations as well as many farfield stations in both the pre- and post-1,000,000 barrels/day brine flow periods. 138 references, 175 figures, 53 tables.

  4. Flow tests of the Gladys McCall well. Appendix A, Gladys McCall Site (Cameron Parish, LA): Final report, October 1985--October 1990

    SciTech Connect (OSTI)

    Randolph, P.L.; Hayden, C.G.; Rogers, L.A.

    1992-04-01

    This report pulls together the data from all of the geopressured-geothermal field research conducted at the Gladys McCall well. The well produced geopressured brine containing dissolved natural gas from the Lower Miocene sands at a depth of 15,150 to 16,650 feet. More than 25 million barrels of brine and 727 million standard cubic feet of natural gas were produced in a series of flow tests between December 1982 and October 1987 at various brine flow rates up to 28,000 barrels per day. Initial short-term flow tests for the Number 9 Sand found the permeability to be 67 to 85 md (millidarcies) for a brine volume of 85 to 170 million barrels. Initial short-term flow tests for the Number 8 Sand found a permeability of 113 to 132 md for a reservoir volume of 430 to 550 million barrels of brine. The long-term flow and buildup test of the Number 8 Sand found that the high-permeability reservoir connected to the wellbore (measured by the short-term flow test) was connected to a much larger, low-permeability reservoir. Numerical simulation of the flow and buildup tests required this large connected reservoir to have a volume of about 8 billion barrels (two cubic miles of reservoir rock) with effective permeabilities in the range of 0.2 to 20 md. Calcium carbonate scale formation in the well tubing and separator equipment was a problem. During the first 2 years of production, scale formation was prevented in the surface equipment by injection of an inhibitor upstream of the choke. Starting in 1985, scale formation in the production tubing was successfully prevented by injecting inhibitor ``pills`` directly into the reservoir. Corrosion and/or erosion of surface piping and equipment, as well as disposal well tubing, was also significant.

  5. Flow tests of the Gladys McCall well

    SciTech Connect (OSTI)

    Randolph, P.L.; Hayden, C.G.; Rogers, L.A. )

    1992-04-01

    This report pulls together the data from all of the geopressured-geothermal field research conducted at the Gladys McCall well. The well produced geopressured brine containing dissolved natural gas from the Lower Miocene sands at a depth of 15,150 to 16,650 feet. More than 25 million barrels of brine and 727 million standard cubic feet of natural gas were produced in a series of flow tests between December 1982 and October 1987 at various brine flow rates up to 28,000 barrels per day. Initial short-term flow tests for the Number 9 Sand found the permeability to be 67 to 85 md (millidarcies) for a brine volume of 85 to 170 million barrels. Initial short-term flow tests for the Number 8 Sand found a permeability of 113 to 132 md for a reservoir volume of 430 to 550 million barrels of brine. The long-term flow and buildup test of the Number 8 Sand found that the high-permeability reservoir connected to the wellbore (measured by the short-term flow test) was connected to a much larger, low-permeability reservoir. Numerical simulation of the flow and buildup tests required this large connected reservoir to have a volume of about 8 billion barrels (two cubic miles of reservoir rock) with effective permeabilities in the range of 0.2 to 20 md. Calcium carbonate scale formation in the well tubing and separator equipment was a problem. During the first 2 years of production, scale formation was prevented in the surface equipment by injection of an inhibitor upstream of the choke. Starting in 1985, scale formation in the production tubing was successfully prevented by injecting inhibitor pills'' directly into the reservoir. Corrosion and/or erosion of surface piping and equipment, as well as disposal well tubing, was also significant.

  6. Geochemical Mud Logging of geothermal drilling

    SciTech Connect (OSTI)

    Tonani, F.B.; Guidi, M.; Johnson, S.D.

    1988-01-01

    The experience and results described in the present paper were developed over nearly two decades, with a major R&D project around 1980. The expression Geochemical Mud Logging (GML) has ill defined meaning in the geothermal industry, and ought to be specified. We refer here to GML as featuring mud and formation fluid tracer(s) and temperature as the bare essentials and with specified accuracies. Air and water logging are expected to be less demanding with regard to analysis accuracy, but are not discussed in this report. During application of GML to several drill holes with low formation permeabilities and under conditions of high temperature and high mud weight, GML as specified, revealed unexpected influx of formation brine. Such influx was a recurring feature that has been referenced to individual fractures and reflects both fracture size and permeability. As a consequence, continuous or subcontinuous sampling of mud systems appears more cost effective than trying to keep up with cumulative changes of bulk mud composition; although, the latter approach is more sensitive to extremely low rate, steady, inflow of formation fluid into the mud system. It appears, that based on this influx of formation fluid, permeability can be estimated well before mud losses are detected and/or drill strings are stuck. The main advantages of GML are: (1) the capability to assess formation temperature and permeability in nearly real time, resulting in (a) assessments of undisturbed formation and (b) having data in hand for holes lost during drilling operations and (2) being effective under conditions of very high temperatures where electrical logs are very costly and less reliable. Estimated cost for GML is $1500 per day (1982) based on assessments of R&D operations. However, extrapolating to larger scale services and to different operating conditions is indeed difficult. GML cost is probably the only significant point of controversy with regard to GML being a viable evaluation tool.

  7. Integrating CO₂ storage with geothermal resources for dispatchable renewable electricity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Buscheck, Thomas A.; Bielicki, Jeffrey M.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Edmunds, Thomas A.; Saar, Martin O.; Randolph, Jimmy B.

    2014-12-31

    We present an approach that uses the huge fluid and thermal storage capacity of the subsurface, together with geologic CO₂ storage, to harvest, store, and dispatch energy from subsurface (geothermal) and surface (solar, nuclear, fossil) thermal resources, as well as energy from electrical grids. Captured CO₂ is injected into saline aquifers to store pressure, generate artesian flow of brine, and provide an additional working fluid for efficient heat extraction and power conversion. Concentric rings of injection and production wells are used to create a hydraulic divide to store pressure, CO₂, and thermal energy. Such storage can take excess power frommore » the grid and excess/waste thermal energy, and dispatch that energy when it is demanded, enabling increased penetration of variable renewables. Stored CO₂ functions as a cushion gas to provide enormous pressure-storage capacity and displaces large quantities of brine, which can be desalinated and/or treated for a variety of beneficial uses.« less

  8. Desalination Plant Optimization

    Energy Science and Technology Software Center (OSTI)

    1992-10-01

    MSF21 and VTE21 perform design and costing calculations for multistage flash evaporator (MSF) and multieffect vertical tube evaporator (VTE) desalination plants. An optimization capability is available, if desired. The MSF plant consists of a recovery section, reject section, brine heater, and associated buildings and equipment. Operating costs and direct and indirect capital costs for plant, buildings, site, and intakes are calculated. Computations are based on the first and last stages of each section and amore » typical middle recovery stage. As a result, the program runs rapidly but does not give stage by stage parameters. The VTE plant consists of vertical tube effects, multistage flash preheater, condenser, and brine heater and associated buildings and equipment. Design computations are done for each vertical tube effect, but preheater computations are based on the first and last stages and a typical middle stage.« less

  9. Computer simulation of production from geothermal-geopressured aquifers. Final report, October 1, 1978-January 31, 1983

    SciTech Connect (OSTI)

    Doherty, M.G.; Poonawala, N.A.

    1983-07-01

    This is the final report on research conducted to improve the technical and scientific understanding of geopressured and geothermal resources. The effort utilized a computer to interpret the results of well tests and compile data on gas solubility in brine and the viscosity of brine. A detailed computer reservoir study of a geopressured test well that had been abandoned as a dry hole but became a commercial producer of hydrocarbons is presented. A number of special topical reports pertaining to test activities performed on Department of Energy test wells (MG-T/DOE Amoco Fee No. 1 Well, Leroy Sweezy No. 1 Well, and Pleasant Bayou No. 2 Well) are appended to the report. A referenced article written under this study that appeared in the Journal of Petroleum Technology is also reproduced.

  10. Integrating CO₂ storage with geothermal resources for dispatchable renewable electricity

    SciTech Connect (OSTI)

    Buscheck, Thomas A.; Bielicki, Jeffrey M.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Edmunds, Thomas A.; Saar, Martin O.; Randolph, Jimmy B.

    2014-12-31

    We present an approach that uses the huge fluid and thermal storage capacity of the subsurface, together with geologic CO₂ storage, to harvest, store, and dispatch energy from subsurface (geothermal) and surface (solar, nuclear, fossil) thermal resources, as well as energy from electrical grids. Captured CO₂ is injected into saline aquifers to store pressure, generate artesian flow of brine, and provide an additional working fluid for efficient heat extraction and power conversion. Concentric rings of injection and production wells are used to create a hydraulic divide to store pressure, CO₂, and thermal energy. Such storage can take excess power from the grid and excess/waste thermal energy, and dispatch that energy when it is demanded, enabling increased penetration of variable renewables. Stored CO₂ functions as a cushion gas to provide enormous pressure-storage capacity and displaces large quantities of brine, which can be desalinated and/or treated for a variety of beneficial uses.

  11. Acoustic and electrical properties of Mexican geothermal rock samples

    SciTech Connect (OSTI)

    Contreras, E.A.; King, M.S.

    1984-12-01

    Acoustic compressional and shear-wave velocities have been measured on a suite of ten sandstone samples obtained from wells in the Cerro Prieto geothermal field and on two rock samples from other Mexican geothermal fields. The samples were tested in both their dry and fully brine-saturated states at uniaxial stresses to 15 MPa. Electrical resistivities and associated phase angles have been measured on the same core samples as a function of frequency in the range 10 Hz to 10/sup 5/ Hz under drained conditions at hydrostatic confining stresses to 10 MPa. The electrical properties were measured on samples tested in their fully saturated state, using brines of two different concentrations.

  12. Evolution of Chemistry and Its Effects on the Corrosion of Engineered Barrier Materials

    SciTech Connect (OSTI)

    Dunn, Darrell; Pan, Yi-Ming; He, Xihua; Yang, Lietai; Pabalan, Roberto

    2007-07-01

    The evolution of environmental conditions within the emplacement drifts of a potential high-level waste repository at Yucca Mountain, Nevada, may be influenced by several factors, including the temperature and relative humidity within the emplacement drifts and the composition of seepage water. The performance of the waste package and the drip shield may be affected by the evolution of the environmental conditions within the emplacement drifts. In this study, tests evaluated the evolution of environmental conditions on the waste package surfaces and in the surrounding host rock. The tests were designed to (i) simulate the conditions expected within the emplacement drifts; (ii) measure the changes in near-field chemistry; and (iii) determine environmental influence on the performance of the engineered barrier materials. Results of tests conducted in this study indicate the composition of salt deposits was consistent with the initial dilute water chemistry. Salts and possibly concentrated calcium chloride brines may be more aggressive than either neutral or alkaline brines. (authors)

  13. Microbial characterization for the Source-Term Waste Test Program (STTP) at Los Alamos

    SciTech Connect (OSTI)

    Leonard, P.A.; Strietelmeier, B.A.; Pansoy-Hjelvik, M.E.; Villarreal, R.

    1999-04-01

    The effects of microbial activity on the performance of the proposed underground nuclear waste repository, the Waste Isolation Pilot Plant (WIPP) at Carlsbad, New Mexico are being studied at Los Alamos National Laboratory (LANL) as part of an ex situ large-scale experiment. Actual actinide-containing waste is being used to predict the effect of potential brine inundation in the repository in the distant future. The study conditions are meant to simulate what might exist should the underground repository be flooded hundreds of years after closure as a result of inadvertent drilling into brine pockets below the repository. The Department of Energy (DOE) selected LANL to conduct the Actinide Source-Term Waste Test Program (STTP) to confirm the predictive capability of computer models being developed at Sandia National Laboratory.

  14. 500-kW DCHX pilot-plant evaluation testing

    SciTech Connect (OSTI)

    Hlinak, A.; Lee, T.; Loback, J.; Nichols, K.; Olander, R.; Oshmyansky, S.; Roberts, G.; Werner, D.

    1981-10-01

    Field tests with the 500 kW Direct Contact Pilot Plant were conducted utilizing brine from well Mesa 6-2. The tests were intended to develop comprehensive performance data, design criteria, and economic factors for the direct contact power plant. The tests were conducted in two phases. The first test phase was to determine specific component performance of the DCHX, turbine, condensers and pumps, and to evaluate chemical mass balances of non-condensible gases in the IC/sub 4/ loop and IC/sub 4/ in the brine stream. The second test phase was to provide a longer term run at nearly fixed operating conditions in order to evaluate plant performance and identify operating cost data for the pilot plant. During these tests the total accumulated run time on major system components exceeded 1180 hours with 777 hours on the turbine prime mover. Direct contact heat exchanger performance exceeded the design prediction.

  15. Solubility and Surface Adsorption Characteristics of Metal Oxides to High Temperature

    SciTech Connect (OSTI)

    D.J. Wesolowski; M.L. Machesky; S.E. Ziemniak; C. Xiao; D.A. Palmer; L.M. Anovitz; P. Benezeth

    2001-05-04

    The interaction of high temperature aqueous solutions with mineral surfaces plays a key role in many aspects of fossil, geothermal and nuclear energy production. This is an area of study in which the subsurface geochemical processes that determine brine composition, porosity and permeability changes, reservoir integrity, and fluid flow rates overlap with the industrial processes associated with corrosion of metal parts and deposition of solids in pipes and on heat exchanger surfaces. The sorption of ions on mineral surfaces is also of great interest in both the subsurface and ''above ground'' regimes of power production, playing a key role in subsurface migration of contaminants (nuclear waste disposal, geothermal brine re-injection, etc.) and in plant operations (corrosion mitigation, migration of radioactive metals from reactor core to heat exchanger, etc.). In this paper, results of the solubility and surface chemistry of metal oxides relevant to both regimes are summarized.

  16. Development history of the Tiwi geothermal field, Philippines

    SciTech Connect (OSTI)

    Gambill, D.T.; Beraquit, D.B.

    1993-10-01

    Commercial production of electricity from the Tiwi geothermal system began in 1979. In 1982, Tiwi became the world`s first water-dominated system to produce more than 160 MWe. Today the field supplies about 11% of Luzon`s electricity. Initially, the reservoir was single-phase liquid with a small, shallow steam zone on the east side. Temperature reversals in the first wells showed the east to be an outflow zone. As production began, reservoir pressure declined, two-phase conditions developed, and groundwater entered the reservoir from the east. As many productions wells cooled, brine production increased and generation decreased from about 280 MWe in 1983 to about 190 MWe in 1986. Improvements to surface facilities and new wells drilled farther west raised generation to about 280 MWe by mid-1993. Separated brine was first injected into the reservoir, but this lowered steam production; injection is now outside the field.

  17. Sampling and analytical methods development at the HGP-a generator facility

    SciTech Connect (OSTI)

    Thomas, D.M.

    1982-10-01

    During shakedown operations for the HGP-A generator plant sampling and analytical problems were encountered during the process chemistry monitoring effort. Acid-preservation of brine for cation analysis required the use of nitrous oxideacetylene flame for accurate A-A analysis of calcium. Analysis of gases for carbonate and sulfide was by specific ion electrode and alkalinity titration, respectively. Sulfide caused substantial interferences with the alkalinity method and corrections for sulfide were required. Sulfide also interfered with chloride analyses in the steam phase requiring removal of the sulfide by boiling. Analysis of dissolved silica in the brine was complicated by the presence of colloidal silica which produced erratic analytical results. An accurate evaluation of the hydrogen sulfide abatement system was possible only when the hydrogen sulfide concentrations in the treated and untreated steam were compared with a second component in the steam phase that was unaffected by caustic injection.

  18. Chemistry, scale, and performance of the Hawaii geothermal project-A plant

    SciTech Connect (OSTI)

    Baughman, E.C.; Uemura, R.T.

    1985-12-01

    The objective of this study was to determine the effects of scale, corrosion, and erosion of the geothermal resource on HGP-A Geothermal Wellhead Power Plant. Analysis of the fluid chemistry was made to interpret the cause of corrosion and scale deposition in the brine and steam systems. It was found that metal sulfide scale formation occurred in the steam system and silica type scale formation in the brine system. The rate of scale deposition was strongly influenced by the chemical conditions in those systems. Although scale and corrosion did occur in the plant piping systems and equipment, they did not appreciably affect the performance of the plant. The results of this study will make the utilities more aware of the effects of geothermal fluid chemistry on scale deposition and corrosion which may increase plant efficiency and reduce maintenance of future plants. 7 refs., 67 figs., 13 tabs.

  19. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios K; Torres, Sharon G; Hakala, J Alexandra; Shao, Hongbo; Cantrell, Kirk J; Carroll, Susan

    2012-02-05

    Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising, however, possible CO₂ or CO₂-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define trace metal source terms from the reaction of supercritical CO₂, storage reservoir brines, reservoir and cap rocks. Storage reservoir source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from sandstones, shales, carbonates, evaporites, basalts and cements from the Frio, In Salah, Illinois Basin – Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution is tracked by measuring solution concentrations over time under conditions (e.g. pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for Maximum Contaminant Levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments due to the presence of CO₂. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rock exceed the MCLs by an order of magnitude while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the reservoir and caprock source term to further evaluate the impact of leakage on groundwater quality.

  20. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6160 UNDEERC Grand Forks, ND Additional Location - Johnsons Corner, McKenzie County, ND Schlumberger Carbon Services - Denver, Colorado FE/TDIC/Coal/Carbon Storage Team Andrea McNemar Developing and Validating Pressure Management and Plume Control Strategies in th The scope of will consist of conducting a pilot test involving the extraction, treatment, and reinjection of brine from the subsurface. This will include the drilling and completing of wells all tasks of Phase II Andrea T. McNemar

  1. CHARACTERIZATION OF MIXED WETTABILITY AT DIFFERENT SCALES AND ITS IMPACT ON OIL RECOVERY EFFICIENCY

    SciTech Connect (OSTI)

    Mukul M. Sharma; George J. Hirasaki

    2003-09-01

    The objectives of the this research project were to: (1) Quantify the pore scale mechanisms that determine the wettability state of a reservoir; (2) Study the effect of crude oil, brine and mineral compositions in the establishment of mixed wet states; (3) Clarify the effect of mixed-wettability on oil displacement efficiency in waterfloods; and (4) Develop a new tracer technique to measure wettability, fluid distributions, residual saturations and relative permeabilities.

  2. Method of determining interwell oil field fluid saturation distribution

    DOE Patents [OSTI]

    Donaldson, Erle C.; Sutterfield, F. Dexter

    1981-01-01

    A method of determining the oil and brine saturation distribution in an oil field by taking electrical current and potential measurements among a plurality of open-hole wells geometrically distributed throughout the oil field. Poisson's equation is utilized to develop fluid saturation distributions from the electrical current and potential measurement. Both signal generating equipment and chemical means are used to develop current flow among the several open-hole wells.

  3. R & D Supercritiacl CO2/ Rock Chemicals Interactions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution / precipitation with spatial and temporal flow variations in CO 2 /brine/rock systems Principal Investigator: Martin Saar Department of Earth Sciences University of Minnesota Track Name: Resource Characterization, Modeling, Supercritical CO 2 / Rock Chemical Interactions Total Project Funding: $1,937,523 ($1,550,018 from DOE-GTP) This presentation does not

  4. EERE Success Story-California: Geothermal Plant to Help Meet High Lithium

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demand | Department of Energy Geothermal Plant to Help Meet High Lithium Demand EERE Success Story-California: Geothermal Plant to Help Meet High Lithium Demand May 21, 2013 - 5:54pm Addthis Through funding provided by the American Recovery and Reinvestment Act of 2009, EERE's Geothermal Technologies Office is working with California's Simbol Materials to develop technologies that extract battery materials like lithium, manganese, and zinc from geothermal brines. Simbol has the potential to

  5. Simulation of CO2 Sequestration at Rock Spring Uplift, Wyoming: Heterogeneity and Uncertainties in Storage Capacity, Injectivity and Leakage

    SciTech Connect (OSTI)

    Deng, Hailin; Dai, Zhenxue; Jiao, Zunsheng; Stauffer, Philip H.; Surdam, Ronald C.

    2011-01-01

    Many geological, geochemical, geomechanical and hydrogeological factors control CO{sub 2} storage in subsurface. Among them heterogeneity in saline aquifer can seriously influence design of injection wells, CO{sub 2} injection rate, CO{sub 2} plume migration, storage capacity, and potential leakage and risk assessment. This study applies indicator geostatistics, transition probability and Markov chain model at the Rock Springs Uplift, Wyoming generating facies-based heterogeneous fields for porosity and permeability in target saline aquifer (Pennsylvanian Weber sandstone) and surrounding rocks (Phosphoria, Madison and cap-rock Chugwater). A multiphase flow simulator FEHM is then used to model injection of CO{sub 2} into the target saline aquifer involving field-scale heterogeneity. The results reveal that (1) CO{sub 2} injection rates in different injection wells significantly change with local permeability distributions; (2) brine production rates in different pumping wells are also significantly impacted by the spatial heterogeneity in permeability; (3) liquid pressure evolution during and after CO{sub 2} injection in saline aquifer varies greatly for different realizations of random permeability fields, and this has potential important effects on hydraulic fracturing of the reservoir rock, reactivation of pre-existing faults and the integrity of the cap-rock; (4) CO{sub 2} storage capacity estimate for Rock Springs Uplift is 6614 {+-} 256 Mt at 95% confidence interval, which is about 36% of previous estimate based on homogeneous and isotropic storage formation; (5) density profiles show that the density of injected CO{sub 2} below 3 km is close to that of the ambient brine with given geothermal gradient and brine concentration, which indicates CO{sub 2} plume can sink to the deep before reaching thermal equilibrium with brine. Finally, we present uncertainty analysis of CO{sub 2} leakage into overlying formations due to heterogeneity in both the target saline

  6. Environmental impact of geopressure - geothermal cogeneration facility on wetland resources and socioeconomic characteristics in Louisiana Gulf Coast region. Final report, October 10, 1983-September 31, 1984

    SciTech Connect (OSTI)

    Smalley, A.M.; Saleh, F.M.S.; Fontenot, M.

    1984-08-01

    Baseline data relevant to air quality are presented. The following are also included: geology and resource assessment, design well prospects in southwestern Louisiana, water quality monitoring, chemical analysis subsidence, microseismicity, geopressure-geothermal subsidence modeling, models of compaction and subsidence, sampling handling and preparation, brine chemistry, wetland resources, socioeconomic characteristics, impacts on wetlands, salinity, toxic metals, non-metal toxicants, temperature, subsidence, and socioeconomic impacts. (MHR)

  7. September 2015 Most Viewed Documents for Renewable Energy Sources | OSTI,

    Office of Scientific and Technical Information (OSTI)

    US Dept of Energy Office of Scientific and Technical Information September 2015 Most Viewed Documents for Renewable Energy Sources Calculation of brine properties. [Above 80/sup 0/F and for salt content between 5 and 25%] Dittman, G.L. (1977) 257 Aerodynamic characteristics of seven symmetrical airfoil sections through 180-degree angle of attack for use in aerodynamic analysis of vertical axis wind turbines Sheldahl, R E; Klimas, P C (1981) 217 Thermal conductivity of aqueous NaCl solutions

  8. Management Overview

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    344 PE. Stress Corrosion Cracking of SNF Interim Storage Canisters: SNL Research Status Charles Bryan and David Enos Sandia National Laboratories UFD Workshop June 7-9, 2016 Las Vegas, NV Used Fuel Disposition Overview  Environment * Brine stability experiments, inland sites (new data on mixed salt assemblages) * Data gaps  Localized Corrosion Modeling * General model (Chen and Kelly 2010 approach) * Data gaps  Experiment Plan for Localized Corrosion * Localized corrosion

  9. Monitoring CO 2 sequestration into deep saline aquifer and associated salt intrusion using coupled multiphase flow modeling and time lapse electrical resistivity tomography

    SciTech Connect (OSTI)

    Chuan Lu; CHI Zhang; Hai Hanag; Timothy C. Johnson

    2014-04-01

    Successful geological storage and sequestration of carbon dioxide (CO2) require efficient monitoring of the migration of CO2 plume during and after large-scale injection in order to verify the containment of the injected CO2 within the target formation and to evaluate potential leakage risk. Field studies have shown that surface and cross-borehole electrical resistivity tomography (ERT) can be a useful tool in imaging and characterizing solute transport in heterogeneous subsurface. In this synthetic study, we have coupled a 3-D multiphase flow model with a parallel 3-D time-lapse ERT inversion code to explore the feasibility of using time-lapse ERT for simultaneously monitoring the migration of CO2 plume in deep saline formation and potential brine intrusion into shallow fresh water aquifer. Direct comparisons of the inverted CO2 plumes resulting from ERT with multiphase flow simulation results indicate the ERT could be used to delineate the migration of CO2 plume. Detailed comparisons on the locations, sizes and shapes of CO2 plume and intruded brine plumes suggest that ERT inversion tends to underestimate the area review of the CO2 plume, but overestimate the thickness and total volume of the CO2 plume. The total volume of intruded brine plumes is overestimated as well. However, all discrepancies remain within reasonable ranges. Our study suggests that time-lapse ERT is a useful monitoring tool in characterizing the movement of injected CO2 into deep saline aquifer and detecting potential brine intrusion under large-scale field injection conditions.

  10. Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations: Data used in Geosphere Journal Article

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Thomas A. Buscheck

    2015-06-01

    This data submission is for Phase 2 of Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations, which focuses on multi-fluid (CO2 and brine) geothermal energy production and diurnal bulk energy storage in geologic settings that are suitable for geologic CO2 storage. This data submission includes all data used in the Geosphere Journal article by Buscheck et al (2016). All assumptions are discussed in that article.

  11. Puna Geothermal Research Facility technology transfer program. Final report, August 23, 1985--August 23, 1989

    SciTech Connect (OSTI)

    Takahashi, P.

    1989-12-31

    The funds were used in a series of small grants to entrepreneurs demonstrating the direct use of geothermal heat supplied by Hawaii`s HGP-A well; this effort was known as the Community Geothermal Technology Program. Summaries are presented of the nine completed projects: fruit dehydration, greenhouse bottom heating, lumber kiln, glass making, cloth dyeing, aquaculture (incomplete), nursery growing media pasteurization, bronze casting, and electrodeposition from geothermal brine.

  12. NREL: Geothermal Technologies - Neil Popovich

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Popovich Chemical Engineer-Multi Discipline On staff since 2010 Phone number: 303-275-3074 E-mail: Neil.Popovich@nrel.gov General Profile Neil Popovich is a member of the Systems Engineering and Program Integration Office (SEPIO). Areas of expertise Low temperature geothermal power production systems Mineral recovery from geothermal brines Data and instrumentation systems Fuel cell systems, manufacturing and engineering Education and background training M.S. in chemical engineering, University

  13. Isothermal evaporation process simulation using the Pitzer model for the Quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Lingzong; Gruszkiewicz, Miroslaw S.; Deng, Tianlong; Guo, Yafei; Li, Dan

    2015-08-05

    In this study, the Pitzer thermodynamic model for solid-liquid equilibria in the quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K was constructed by selecting the proper parameters for the subsystems in the literature. The solubility data of the systems NaCl–SrCl2–H2O, KCl–SrCl2–H2O, LiCl–SrCl2–H2O, and NaCl–KCl–SrCl2–H2O were used to evaluate the model. Good agreement between the experimental and calculated solubilities shows that the model is reliable. The Pitzer model for the quinary system at 298.15 K was then used to calculate the component solubilities and conduct computer simulation of isothermal evaporation of the mother liquor for the oilfield brine from Nanyishan district in themore » Qaidam Basin. The evaporation-crystallization path and sequence of salt precipitation, change in concentration and precipitation of lithium, sodium, potassium, and strontium, and water activities during the evaporation process were demonstrated. The salts precipitated from the brine in the order : KCl, NaCl, SrCl2∙6H2O, SrCl2∙2H2O, and LiCl∙H2O. The entire evaporation process may be divided into six stages. In each stage the variation trends for the relationships between ion concentrations or water activities and the evaporation ratio are different. This result of the simulation of brines can be used as a theoretical reference for comprehensive exploitation and utilization of this type of brine resources.« less

  14. Microsoft Word - NRAP-TRS-III-005-2012_ROMDevelopment_20121018.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduced-Order Model Development for CO 2 Storage in Brine Reservoirs 17 October 2012 Office of Fossil Energy NRAP-TRS-III-005-2012 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus,

  15. Oil Recovery Increases by Low-Salinity Flooding: Minnelusa and Green River Formations

    SciTech Connect (OSTI)

    Eric P. Robertson

    2010-09-01

    Waterflooding is by far the most widely used method in the world to increase oil recovery. Historically, little consideration has been given in reservoir engineering practice to the effect of injection brine composition on waterflood displacement efficiency or to the possibility of increased oil recovery through manipulation of the composition of the injected water. However, recent work has shown that oil recovery can be significantly increased by modifying the injection brine chemistry or by injecting diluted or low salinity brine. This paper reports on laboratory work done to increase the understanding of improved oil recovery by waterflooding with low salinity injection water. Porous media used in the studies included outcrop Berea sandstone (Ohio, U.S.A.) and reservoir cores from the Green River formation of the Uinta basin (Utah, U.S.A.). Crude oils used in the experimental protocols were taken from the Minnelusa formation of the Powder River basin (Wyoming, U.S.A.) and from the Green River formation, Monument Butte field in the Uinta basin. Laboratory corefloods using Berea sandstone, Minnelusa crude oil, and simulated Minnelusa formation water found a significant relationship between the temperature at which the oil- and water-saturated cores were aged and the oil recovery resulting from low salinity waterflooding. Lower aging temperatures resulted in very little to no additional oil recovery, while cores aged at higher temperatures resulted in significantly higher recoveries from dilute-water floods. Waterflood studies using reservoir cores and fluids from the Green River formation of the Monument Butte field also showed significantly higher oil recoveries from low salinity waterfloods with cores flooded with fresher water recovering 12.4% more oil on average than those flooded with undiluted formation brine.

  16. Community Geothermal Technology Program: Bottom heating system using geothermal power for propagation. Final report, Phases 1 and 2

    SciTech Connect (OSTI)

    Downing, J.C.

    1990-01-01

    The objective is to develop and study a bottom-heating system in a greenhouse utilizing geothermal energy to aid germination and speed growth of palms. Source of heat was geothermal brine from HGP-A well. The project was successful; the heat made a dramatic difference with certain varieties, such as Areca catechu (betelnut) with 82% germination with heat, zero without. For other varieties, germination rates were much closer. Quality of seed is important. Tabs, figs.

  17. FE00880_RBDMS | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Risk Based Data Management System (RBDMS) and Cost Effective Regulatory Approaches (CERA) Related to Hydraulic Fracturing and Geologic Sequestration of Carbon Dioxide (CO2) Last Reviewed 6/13/2016 DE-FE0000880 Goal The goal of this project is to enhance the RBDMS by adding new components relevant to environmental topics associated with hydraulic fracturing (HF), and by management of myriad data regarding oil and natural gas well histories, brine disposal, production, enhanced recovery,

  18. Chemistry of transuranium elements in salt-base repository

    SciTech Connect (OSTI)

    Borkowski, Marian; Reed, Donald T; Lucchini, Jean - Francois; Richmann, Michael K; Khaing, H; Swanson, J; Ams, D

    2010-12-02

    The mobility and potential release of actinides into the accessible environment continues to be the key performance assessment concern of nuclear repositories. Actinide, in particular plutonium speciation under the wide range of conditions that can exist in the subsurface is complex and depends strongly on the coupled effects of redox conditions, inorganic/organic complexation, and the extent/nature of aggregation. Understanding the key factors that define the potential for actinide migration is, in this context, an essential and critical part of making and sustaining a licensing case for a nuclear repository. Herein we report on recent progress in a concurrent modeling and experimental study to determine the speciation of plutonium, uranium and americium in high ionic strength Na-CI-Mg brines. This is being done as part of the ongomg recertification effort m the Waste Isolation Pilot Plant (WIPP). The oxidation-state specific solubility of actinides were established in brine as function of pC{sub H+}, brine composition and the presence and absence of organic chelating agents and carbonate. An oxidation-state invariant analog approach using Nd{sup 3+} and Th{sup 4+} was used for An{sup 3+} and An{sup 4+} respectively. These results show that organic ligands and hydrolysis are key factors for An(III) solubility, hydrolysis at pC{sub H+} above 8 is predominate for An(IV) and carbonates are the key factor for U(VI) solubility. The effect of high ionic strength and brine components measured in absence of carbonates leads to measurable increased in overall solubility over analogous low ionic strength groundwater. Less is known about the bioreduction of actinides by halo-tolerant microorganisms, but there is now evidence that bioreduction does occur and is analogous, in many ways, to what occurs with soil bacteria. Results of solubility studies that focus on Pitzer parameter corrections, new species (e.g. borate complexation), and the thermodynamic parameters for

  19. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    develop platform to study subsurface reservoir conditions March 7, 2016 Los Alamos researchers have developed a high pressure and temperature microfluidic experimental system to investigate pore-scale fluid flow and transport within geo- materials encountered in subsurface energy resource applications. The experiments can be conducted with brine, oil, and carbon dioxide (CO 2 ) at temperatures and pressures similar to naturally occurring reservoirs. The information gained from this system could

  20. Chapter 7 - Glossary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7-1 CHAPTER 7 GLOSSARY actinide The 15 chemical elements with atomic numbers 89 to 103, inclusively. The group consists of actinium, thorium, protactinium, uranium, neptunium, plutonium, americium, curium, berkelium, californium, einsteinium, fermium, mendelevium, nobelium, and lawrencium. Actinide Source-Term Waste Test Program (STTP) Program designed to measure time-dependent concentrations of actinide elements from actual, contact-handled transuranic waste immersed in brines that are