Sample records for bran ch ken

  1. Ken J. Auberry | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Title: Senior Research Scientist Phone: (509) 371-6442 Contact Email: Kenneth.Auberry@pnnl.gov Overview: Ken Auberry's primary research interests are automated high-throughput...

  2. Photo courtesy Ken Suslick

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    Photo courtesy Ken Suslick The handheld reader analyzes the color changes in the sensor array. | Photo courtesy Ken Suslick Sniffing out shoe bombs: A new and simple sensor for explosive chemicals 10 to quickly monitor the environment for explosive chemicals. « Click photo to enlarge The detector uses

  3. Data Semantics Ken Baclawski

    E-Print Network [OSTI]

    Baclawski, Kenneth B.

    Data Semantics Ken Baclawski College of Computer and Information Science Northeastern University #12;What is data semantics? #12;What is data semantics? To answer this we will look at software semantics in general. #12;What is data semantics? Software #12;What is data semantics? ProgramProgram Data

  4. Ken Bernander | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bernander Ken Bernander Oral History Videos Speakers INTRODUCTION Ed Bailey Jim Bailey Kay Bailey Ken Bernander Willard Brock Wilma Brooks Elmer Brummitt Naomi Brummitt Blake Case...

  5. Ken Sommerfeld | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sommerfeld Ken Sommerfeld Oral History Videos Speakers INTRODUCTION Ed Bailey Jim Bailey Kay Bailey Ken Bernander Willard Brock Wilma Brooks Elmer Brummitt Naomi Brummitt Blake...

  6. Interview of Ken Edwards

    E-Print Network [OSTI]

    Edwards, Ken

    2009-06-19T23:59:59.000Z

    home, so didn't see as much of the world as I had hoped to in those two years; when I arrived at university at twenty I felt more confident about being able to mix with people because of that experience 14:33:34 Reading was a very small university... Ken Edwards interviewed by Alan Macfarlane 5th February 2009 0:09:07 Born in Shropshire in 1934; parents ran a small tenant farm; went to the local grammar school in Market Drayton; became interested in science and wanted to be a scientist; because...

  7. Ken Salazar | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetter Report: I11IG002RTC3WASTE-TO-ENERGY:Ken Salazar About Us

  8. Lovelock-Brans-Dicke gravity

    E-Print Network [OSTI]

    Tian, David Wenjie

    2015-01-01T23:59:59.000Z

    According to Lovelock's theorem, the Hilbert-Einstein and the Lovelock actions are indistinguishable from their field equations. However, they have different scalar-tensor counterparts, which correspond to the Brans-Dicke and the \\emph{Lovelock-Brans-Dicke} (LBD) gravities, respectively. In this paper the LBD model of alternative gravity with the Lagrangian density $\\mathscr{L}_{\\text{LBD}}=\\frac{1}{16\\pi}\\left[\\phi\\left(R+\\frac{a}{\\sqrt{-g}}{}^*RR + b\\mathcal{G}\\right)-\\frac{\\omega_{\\text L}}{\\phi}\

  9. Lovelock-Brans-Dicke gravity

    E-Print Network [OSTI]

    David Wenjie Tian; Ivan Booth

    2015-03-02T23:59:59.000Z

    According to Lovelock's theorem, the Hilbert-Einstein and the Lovelock actions are indistinguishable from their field equations. However, they have different scalar-tensor counterparts, which correspond to the Brans-Dicke and the \\emph{Lovelock-Brans-Dicke} (LBD) gravities, respectively. In this paper the LBD model of alternative gravity with the Lagrangian density $\\mathscr{L}_{\\text{LBD}}=\\frac{1}{16\\pi}[\\phi(R+\\frac{a}{\\sqrt{-g}}{}^*RR + b\\mathcal{G})-\\frac{\\omega_{\\text L}}{\\phi}\

  10. Biomass Rapid Analysis Network (BRAN)

    SciTech Connect (OSTI)

    Not Available

    2003-10-01T23:59:59.000Z

    Helping the emerging biotechnology industry develop new tools and methods for real-time analysis of biomass feedstocks, process intermediates and The Biomass Rapid Analysis Network is designed to fast track the development of modern tools and methods for biomass analysis to accelerate the development of the emerging industry. The network will be led by industry and organized and coordinated through the National Renewable Energy Lab. The network will provide training and other activities of interest to BRAN members. BRAN members will share the cost and work of rapid analysis method development, validate the new methods, and work together to develop the training for the future biomass conversion workforce.

  11. Valuation of Forward Starting CDOs Ken Jackson

    E-Print Network [OSTI]

    Toronto, University of

    Valuation of Forward Starting CDOs Ken Jackson Wanhe Zhang February 10, 2007 Abstract A forward and hedging forward starting CDOs has become an active research topic. We present a method for pricing CDO can then be computed by the well developed methods for pricing the equivalent synthetic one. We

  12. Cosmic acceleration and Brans-Dicke theory

    SciTech Connect (OSTI)

    Sharif, M., E-mail: msharif.math@pu.edu.pk; Waheed, S. [University of the Punjab, Department of Mathematics (Pakistan)

    2012-10-15T23:59:59.000Z

    We study the accelerated expansion of the universe by exploring the Brans-Dicke parameter in different eras. For this, we take the FRW universe model with a viscous fluid (without potential) and the Bianchi type-I universe model with a barotropic fluid (with and without a potential). We evaluate the deceleration parameter and the Brans-Dicke parameter to explore cosmic acceleration. It is concluded that accelerated expansion of the universe can also be achieved for higher values of the Brans-Dicke parameter in some cases.

  13. Ken T. Venuto | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial602 1,39732on ArmedManufacturingJune 17, 2015 - SEABSmallKen T. Venuto

  14. Ken Hogstrom, PI, & Medical Physics Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home as ReadyAppointed toCAMD Targets Cancer Ken Hogstrom,

  15. VEE-0083- In the Matter of Ken Bettridge Distributing, Inc.

    Broader source: Energy.gov [DOE]

    On February 28, 2002, Ken Bettridge Distributing, Inc. (Bettridge) of Cedar City, Utah, filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy ...

  16. A Knowledge Acquisition Tool for Course of Action Analysis* Ken Barker1

    E-Print Network [OSTI]

    Forbus, Kenneth D.

    A Knowledge Acquisition Tool for Course of Action Analysis* Ken Barker1 , Jim Blythe2 , Gary Gil2 , Boris Katz3 , Jihie Kim2 , Gary King6 , Sunil Mishra4 , Clayton Morrison6 , Ken Murray4

  17. Brane cosmic string compactification in Brans-Dicke theory

    SciTech Connect (OSTI)

    Abdalla, M. C. B.; Hoff da Silva, J. M. [Instituto de Fisica Teorica, Universidade Estadual Paulista, Rua Pamplona 145 01405-900 Sao Paulo, SP (Brazil); Guimaraes, M. E. X. [Departamento de Matematica, Universidade de Brasilia, Asa Norte 70910-900, Brasilia-DF (Brazil)

    2007-04-15T23:59:59.000Z

    We investigate an alternative compactification of extra dimensions using local cosmic string in the Brans-Dicke gravity framework. In the context of dynamical systems it is possible to show that there exist a stable field configuration for the Einstein-Brans-Dicke equations. We explore the analogies between this particular model and the Randall-Sundrum scenario.

  18. Fast Valuation of Forward-Starting Basket Default Ken Jackson

    E-Print Network [OSTI]

    Toronto, University of

    Fast Valuation of Forward-Starting Basket Default Swaps Ken Jackson Alex Kreinin Wanhe Zhang swap (FBDS) is a BDS starting at a specified future time. Existing analytic or semi-analytic methods starts. This paper develops a fast approximation method for FBDS based on the conditional independence

  19. Light trapping in photonic crystals Ken Xingze Wang,ab

    E-Print Network [OSTI]

    Cui, Yi

    Light trapping in photonic crystals Ken Xingze Wang,ab Zongfu Yu,bc Victor Liu,bd Aaswath Raman,b Yi Cuief and Shanhui Fan*b We consider light trapping in photonic crystals in the weak material-integrated absorption enhancement by light trapping is proportional to the photonic density of states. The tight bound

  20. PLUTONIUM ISOTOPES I N THE NORTH ATLANTIC KEN 0. BUESSELER

    E-Print Network [OSTI]

    Buesseler, Ken

    PLUTONIUM ISOTOPES I N THE NORTH ATLANTIC by KEN 0. BUESSELER B.A., University of California The a r t i f i c i a l radionuclide Plutonium (Pu) has been introduced i n t o the environment p r i m

  1. Holographic energy density in the Brans-Dicke teory

    E-Print Network [OSTI]

    Hungsoo Kim; H. W. Lee; Y. S. Myung

    2005-01-15T23:59:59.000Z

    We study cosmological applications of the holographic energy density. Considering the holographic energy density as a dynamical cosmological constant, we need the Brans-Dicke theory as a dynamical framework instead of general relativity. In this case we use the Bianchi identity as a consistency relation to obtain physical solutions. It is shown that the future event horizon as the IR cutoff provides the dark energy in the Brans-Dicke theory. Furthermore the role of the Brans-Dicke scalar is clarified in the dark energy-dominated universe by calculating its equation of state.

  2. Exact Vacuum Solutions of Jordan, Brans-Dicke Field Equations

    E-Print Network [OSTI]

    Sergey Kozyrev

    2005-12-04T23:59:59.000Z

    We present the static spherically symmetric vacuum solutions of the Jordan, Brans-Dicke field equations. The new solutions are obtained by considering a polar Gaussian, isothermal and radial hyperbolic metrics.

  3. Einstein metrics and Brans-Dicke superfields

    SciTech Connect (OSTI)

    Marques, S.

    1988-01-01T23:59:59.000Z

    It is obtained here a space conformal to the Einstein space-time, making the transition from an internal bosonic space, constructed with the Majorana constant spinors in the Majorana representation, to a bosonic ''superspace,'' through the use of Einstein vierbeins. These spaces are related to a Grassmann space constructed with the Majorana spinors referred to above, where the ''metric'' is a function of internal bosonic coordinates. The conformal function is a scale factor in the zone of gravitational radiation. A conformal function dependent on space-time coordinates can be constructed in that region when we introduce Majorana spinors which are functions of those coordinates. With this we obtain a scalar field of Brans-Dicke type. 11 refs.

  4. Spectra of Relic Gravitons and Brans-Dicke Theory

    E-Print Network [OSTI]

    B. K. Sahoo

    2004-06-11T23:59:59.000Z

    The spectra of relic gravitational waves produced as a result of cosmological expansion of the inflationary models are derived in Brans-Dicke theory of gravity.The time dependence of the very early Hubble parameter and matter energy density are derived from frequency dependent spectrum of relic gravitational waves.Also it is found that Brans-Dicke scalar field contributes to the energy density of relic gravitons.

  5. Rice Bran as a Feed for Dairy Cows.

    E-Print Network [OSTI]

    Lush, Jay L. (Jay Laurence); Hale, Fred

    1927-01-01T23:59:59.000Z

    . TEXAS AGRICULTURAL EXPERIMENT STATION B. YOUNGBLOOD, DIRECTOR COLLEGE STATION, BRAZOS COUNTY, TEXAS -- BULLETIN NO. 352 ' MARCH, 1927 RICE BRAN AS A FEED FOR DAIRY COWS AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS T. 0. WALTON, President...~culture. 1t f ion: 1 I I SYNOPSIS This Bulletin contains a general description of rice bran and a short review of the published experiments about its use as a feed for farm animals. A report is given of the findings obtained in three experiments mith...

  6. Ken Caryl, Colorado: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetecGtelInteriasIowa: EnergyKanabec County,KaolinKelleysKemp Mill,Ken Caryl,

  7. Dynamics of false vacuum bubbles in Brans-Dicke theory

    E-Print Network [OSTI]

    Bum-Hoon Lee; Wonwoo Lee; Dong-han Yeom

    2011-01-11T23:59:59.000Z

    We study the dynamics of false vacuum bubbles in the Brans-Dicke theory of gravity by using the thin shell or thin wall approximation. We consider a false vacuum bubble that has a different value for the Brans-Dicke field between the inside false vacuum region and the outside true vacuum region. Within a certain limit of field values, the difference of field values makes the effective tension of the shell negative. This allows new expanding false vacuum bubbles to be seen by the outside observer, which are disallowed in Einstein gravity.

  8. Dynamics of false vacuum bubbles in Brans-Dicke theory

    SciTech Connect (OSTI)

    Lee, Bum-Hoon; Lee, Wonwoo [Department of Physics and BK21 Division and Center for Quantum Spacetime, Sogang University, Seoul 121-742 (Korea, Republic of); Yeom, Dong-han, E-mail: bhl@sogang.ac.kr, E-mail: warrior@sogang.ac.kr, E-mail: innocent@muon.kaist.ac.kr [Department of Physics, KAIST, Daejeon 305-701 (Korea, Republic of)

    2011-01-01T23:59:59.000Z

    We study the dynamics of false vacuum bubbles in the Brans-Dicke theory of gravity by using the thin shell or thin wall approximation. We consider a false vacuum bubble that has a different value for the Brans-Dicke field between the inside false vacuum region and the outside true vacuum region. Within a certain limit of field values, the difference of field values makes the effective tension of the shell negative. This allows new expanding false vacuum bubbles to be seen by the outside observer, which are disallowed in Einstein gravity.

  9. Vacuum less global monopole in Brans-Dicke theory

    E-Print Network [OSTI]

    F. Rahaman; M. Kalam; R. Mukherjee; S. Das; T. Roy

    2007-02-28T23:59:59.000Z

    In the present work, the gravitational field of a vacuum less global monopole has been investigated in Brans-Dicke theory under weak field assumption of the field equations. It has been shown that the vacuum less global monopole exerts attractive gravitational effects on a test particle. It is dissimilar to the case studied in general relativity.

  10. Unified dark fluid in Brans-Dicke theory

    E-Print Network [OSTI]

    Sunil K. Tripathy; Dipanjali Behera; Bivudutta Mishra

    2015-03-30T23:59:59.000Z

    Anisotropic dark energy cosmological models are constructed in the frame work of generalised Brans-Dicke theory with a self interacting potential. Wet dark fluid characterized by a linear equation of state is considered as the source of dark energy. Shear scalar is considered to be proportional to the expansion scalar simulating an anisotropic relationship among the directional expansion rates. The dynamics of the universe in presence of wet dark fluid in anisotropic background have been discussed. The presence of evolving scalar field makes it possible to get accelerating phase of expansion even for a linear relationship among the directional Hubble rates. It is found that, the anisotropy in expansion rates does not affect the scalar field, self interacting potential but it controls the non-evolving part of the Brans- Dicke parameter.

  11. The effects of barley bran flour on colonic physiology

    E-Print Network [OSTI]

    Morin, Janet Louise

    1990-01-01T23:59:59.000Z

    of barley bran flour. To measure gastrointestinal transit time, subjects ingested 20 barium sulfate impregnated polyethylene pellets (Portex LTD) in two gelatin capsules, and fecal samples were collected for five days during baseline and during... have never met a professor who is so devoted to her students as Dr. Lupton is. I could never thank her enough for all the time, energy and knowledge that she shared with me on this research proiect. I would also like to extend a very special thank...

  12. Nonstatic global string in Brans-Dicke theory

    E-Print Network [OSTI]

    A. A. Sen; N. Banerjee

    2000-07-19T23:59:59.000Z

    Gravitational field of a nonstatic global string has been studied in the context of Brans-Dicke theory of gravity. Both the metric components and the BD scalar field are assumed to be nonseparable functions of time and space.The spacetime may or may not have any singularity at a finite distance from the string core but the singularity at a particular time always remains. It has been shown that the spacetime exhibits both outgoing and incoming gravitational radiation.

  13. Ricci Dark Energy in Brans-Dicke theory

    E-Print Network [OSTI]

    Chao-Jun Feng

    2008-06-04T23:59:59.000Z

    A holographic dark energy from Ricci scalar curvature called Ricci dark energy was proposed recently. In this model the future event horizon area is replaced by the inverse of the Ricci scalar curvature. We study the evolution of equation of state of the Ricci dark energy and the transition from decelerated to accelerated expansion of the universe in the Brans-Dicke theory, which is a natural extension of general relativity. We find that the current acceleration of our universe is well explained.

  14. www.vacet.org E. WES BETHEL (LBNL), CHRIS JOHNSON (UTAH), KEN JOY (UC DAVIS), SEAN AHERN (ORNL), VALERIO PASCUCCI (LLNL),

    E-Print Network [OSTI]

    Utah, University of

    www.vacet.org E. WES BETHEL (LBNL), CHRIS JOHNSON (UTAH), KEN JOY (UC DAVIS), SEAN AHERN (ORNL (LLNL) E. WES BETHEL (LBNL), CHRIS JOHNSON (UTAH), KEN JOY (UC DAVIS), SEAN AHERN (ORNL), VALERIO

  15. Corrosion Protection byCorrosion Protection by ShewanellaShewanella oneidensisoneidensis MRMR--11 EsraEsra KuKu11, Ken Nealson, Ken Nealson22 andand FlorianFlorian MansfeldMansfeld11

    E-Print Network [OSTI]

    Southern California, University of

    Corrosion Protection byCorrosion Protection by ShewanellaShewanella oneidensisoneidensis MRMR--11 EsraEsra KuKu11, Ken Nealson, Ken Nealson22 andand FlorianFlorian MansfeldMansfeld11 1.1. Corrosion and Environmental Effects Laboratory (CEEL)Corrosion and Environmental Effects Laboratory (CEEL) TheThe Mork

  16. CH Packaging Operations Manual

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-05-15T23:59:59.000Z

    Introduction - This procedure provides instructions forassembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

  17. CH Packaging Operations Manual

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-12-18T23:59:59.000Z

    Introduction - This procedure provides instructions forassembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

  18. CH Packaging Operations Manual

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-08-22T23:59:59.000Z

    This procedure provides instructions forassembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

  19. CH Packaging Operations Manual

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-11-29T23:59:59.000Z

    This procedure provides instructions forassembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

  20. The Phosphorus Compounds of Cotton Seed Meal and Wheat Bran.

    E-Print Network [OSTI]

    Rather, J. B. (James Burness)

    1913-01-01T23:59:59.000Z

    of the organic silver salt beyond the limit of analytical error. Analysis of the products from the extractions of cottonseed meal gave the following results: .6675 gram of the product from the acid extraction gave .0020 gram combined iron, aluminum, lime... that the products from the acid and ammonia extracts of cottonseed meal and the acid extract of wheat bran are all salts of the same acid, but containing different quantities of silver. The latter is to he expected as no attempt was made to precipitate the salts...

  1. Wormholes and Naked Singularities in Brans-Dicke cosmology

    E-Print Network [OSTI]

    Tretyakova, D A; Alexeyev, S O

    2015-01-01T23:59:59.000Z

    We perform analytical and numerical study of static spherically symmetric solutions in the context of Brans-Dicke-like cosmological model by Elizalde et al.. In this model the phantom regime arises without the appearance of any ghost degree of freedom due to the specific form of coupling. For the certain parameter ranges the model contains a regular solution which we interpret as a wormhole. The space-time structure is similar to Schwarzschild-AdS one, representing a wormhole in AdS Universe. We put several bounds on the parameter values: $\\omegalaw correction to the gravitational potential for the ...

  2. CARBON SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams

    E-Print Network [OSTI]

    CARBON SEQUESTRATION VIA DIRECT INJECTION Howard J. Herzog, Ken Caldeira, and Eric Adams and sequestration. Carbon sequestration is often associated with the planting of trees. As they mature, the trees INTRODUCTION The build-up of carbon dioxide (CO2) and other greenhouse gases in the Earth's atmosphere has

  3. Shape Memory and Pseudoelasticity in Metal Nanowires Harold S. Park,1,* Ken Gall,2

    E-Print Network [OSTI]

    Lin, Xi

    Shape Memory and Pseudoelasticity in Metal Nanowires Harold S. Park,1,* Ken Gall,2 and Jonathan A nanowires can exhibit both shape memory and pseudoelastic behavior. We also show that the formation to show a reversible transition between two crystal orientations during loading and thus shape memory

  4. Secret Sequence Comparison on Public Grid Computing Resources Ken-ichi Kurata and Hiroshi Nakamura

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Secret Sequence Comparison on Public Grid Computing Resources Ken-ichi Kurata and Hiroshi Nakamura Landais, 63177 Aubiere, France Email: breton@clermont.in2p3.fr Abstract Once a new gene has been sequenced, it must be ver- ified whether or not it is similar to previously sequenced genes. In many cases

  5. Frequent Pattern Mining for Kernel Trace Data Christopher LaRosa, Li Xiong, Ken Mandelberg

    E-Print Network [OSTI]

    Xiong, Li

    , application programmers, operating systems engineers, and security analysts. In the systems area, data miningFrequent Pattern Mining for Kernel Trace Data Christopher LaRosa, Li Xiong, Ken Mandelberg patterns and other recurring runtime execution patterns in operating system trace logs, we employ data

  6. Nucleation of vacuum bubbles in Brans-Dicke type theory

    E-Print Network [OSTI]

    Hongsu Kim; Bum-Hoon Lee; Wonwoo Lee; Young Jae Lee; Dong-han Yeom

    2011-07-19T23:59:59.000Z

    In this paper, we explore the nucleation of vacuum bubbles in the Brans-Dicke type theory of gravity. In the Euclidean signature, we evaluate the fields at the vacuum bubbles as solutions of the Euler-Lagrange equations of motion as well as the bubble nucleation probabilities by integrating the Euclidean action. We illustrate three possible ways to obtain vacuum bubbles: true vacuum bubbles for \\omega>-3/2, false vacuum bubbles for \\omegafalse vacuum bubbles for \\omega>-3/2 when the vacuum energy of the false vacuum in the potential of the Einstein frame is less than that of the true vacuum. After the bubble is nucleated at the t=0 surface, we can smoothly interpolate the field combinations to some solutions in the Lorentzian signature and consistently continue their subsequent evolutions. Therefore, we conclude that, in general scalar-tensor theories like this Brans-Dicke type theories, which may include and represent certain features of string theory, vacuum bubbles come in false vacuum bubbles as well as in true vacuum bubbles, as long as a special condition is assumed on the potential.

  7. Modified Brans-Dicke theory of gravity from five-dimensional vacuum

    E-Print Network [OSTI]

    Jose Edgar Madriz Aguilar; Carlos Romero; Adriano Barros

    2007-05-03T23:59:59.000Z

    We investigate, in the context of five-dimensional (5D) Brans-Dicke theory of gravity, the idea that macroscopic matter configurations can be generated from pure vacuum in five dimensions, an approach first proposed in the framework of general relativity. We show that the 5D Brans-Dicke vacuum equations when reduced to four dimensions lead to a modified version of Brans-Dicke theory in four dimensions (4D). As an application of the formalism, we obtain two five-dimensional extensions of four-dimensional O'Hanlon and Tupper vacuum solution and show that they lead two different cosmological scenarios in 4D.

  8. Generalized Sparling-Thirring form in the Brans-Dicke theory

    E-Print Network [OSTI]

    Ahmet Baykal; Özgür Delice

    2014-10-15T23:59:59.000Z

    The definition of the Sparling-Thirring form is extended to the Brans-Dicke theory. By writing the Brans-Dicke field equations in a formally Maxwell-like form, a superpotential and a corresponding pseudo energy-momentum form are defined. The general energy expression provided by the superpotential in the Jordan frame is discussed in relation to the corresponding expression in the Einstein frame. In order to substantiate its formal definition, the generalized Sparling-Thirring form is used to calculate the energy for the spherically symmetric vacuum solution in the Brans-Dicke theory.

  9. The U.S. JGOFS Data Management David M. Glover, Cynthia L. Chandler, Scott C. Doney, Ken O. Buesseler,

    E-Print Network [OSTI]

    Glover, David M.

    The U.S. JGOFS Data Management Experience David M. Glover, Cynthia L. Chandler, Scott C. Doney, Ken (Appendix A), first created by Glenn Flierl, Jim Bishop, David Glover, and Satish Paranjpe under support

  10. The bulking effect of dietary fiber in the rat large intestine: an in vivo study of cellulose, guar, pectin, wheat bran and oat bran

    E-Print Network [OSTI]

    Gazzaniga, Jeanne Marie

    1985-01-01T23:59:59.000Z

    THE BULKING EFFECT OF DIETARY FIBER IN THE RAT LARGE INTESTINE: AN IN VIVO STUDY OF CELLULOSE, GUAR, PECTIN, WHEAT BRAN AND OAT BRAN A Thesis by JEANNE MARIE GAZZANIGA Submitted to the Graduate College of Texas A&M University in partial... JEANNE MARIE GAZZANIGA Approved as to style and content by: o~P L sc J nne R. Lupton (Chair of Committee) Karen S. Kubena (Member) ayne Suter (Member) G. C. Smith (Head of Department) December 1985 ABSTRACT The Bulking Effect of Dietary Fiber...

  11. Chemical, color, and sensory attributes of sorghum bran-enhanced beef patties in a high oxygen environment

    E-Print Network [OSTI]

    Jenschke, Blaine Edward

    2006-04-12T23:59:59.000Z

    Bottom rounds were shipped to the Rosenthal Meat Science and Technology Center, ground and enhanced with one of the following predetermined treatments: control; 0.4% sodium phosphates and 0.3% salt; 0.25% sorghum bran; 2.0% sorghum bran; 0...

  12. A review of "Spiritual Architecture and Paradise Regained : Milton’s Literary Ecclesiology" By Ken Simpson

    E-Print Network [OSTI]

    Clark, Ira

    2008-01-01T23:59:59.000Z

    r e v i e w s 141 Ken Simpson. Spiritual Architecture and Paradise Regained : Milton?s Literary Ecclesiology. Pittsburgh: Duquesne University Press, 2007. 256 pp. $58.00. Review by ir a Cl a r k , Un i v e r s i t y o f fl o r i d a... . Spiritual Architecture and Paradise Regained : Milton?s Literary Eccle- siology supplies the revelation and promulgation of church identity as an integral complement to reading Milton?s final poem as the spiritual discovery and proclamation of the Son...

  13. {gamma} parameter and Solar System constraint in chameleon-Brans-Dicke theory

    SciTech Connect (OSTI)

    Saaidi, Kh.; Mohammadi, A.; Sheikhahmadi, H. [Department of Physics, Faculty of Science, University of Kurdistan, Sanandaj (Iran, Islamic Republic of)

    2011-05-15T23:59:59.000Z

    The post Newtonian parameter is considered in the chameleon-Brans-Dicke model. In the first step, the general form of this parameter and also effective gravitational constant is obtained. An arbitrary function for f({Phi}), which indicates the coupling between matter and scalar field, is introduced to investigate validity of solar system constraint. It is shown that the chameleon-Brans-Dicke model can satisfy the solar system constraint and gives us an {omega} parameter of order 10{sup 4}, which is in comparable to the constraint which has been indicated in [19].

  14. Physical interpretation of constants in the solutions to the Brans-Dicke equations

    E-Print Network [OSTI]

    Aroonkumar Beesham

    1998-02-18T23:59:59.000Z

    Using an energy-momentum complex we give a physical interpretation to the constants in the well-known static spherically symmetric asymptotically flat vacuum solution to the Brans-Dicke equations. The positivity of the tensor mass puts a bound on parameters in the solution.

  15. Exact metric for the exterior of a global string in the Brans-Dicke theory

    E-Print Network [OSTI]

    B. Boisseau; B. Linet

    1998-02-03T23:59:59.000Z

    We determine in closed form the general static solution with cylindrical symmetry to the Brans-Dicke equations for an energy-momentum tensor corresponding to the one of the straight U(1) global string outside the core radius assuming that the Goldstone boson field takes its asymptotic value

  16. Electrostatic Potential of a Point Charge in a Brans-Dicke Reissner-Nordstrom Field

    E-Print Network [OSTI]

    Maya Watanabe; A. W. C Lun

    2013-08-12T23:59:59.000Z

    We consider the Brans-Dicke Reissner-Nordstrom spacetime in isotropic coordinates and the electrostatic field of an electric point charge placed outside its surface of inversion. We treat the static electric point charge as a linear perturbation on the Brans-Dicke Reissner-Nordstrom background. We develop a method based upon the Copson method to convert the governing Maxwell equation on the electrostatic potential generated by the static electric point charge into a solvable linear second order ordinary differential equation. We obtain a closed form fundamental solution of the curved space Laplace equation arising from the background metric, which is shown to be regular everywhere except at the point charge and its image point inside the surface of inversion. We also develop a method that demonstrates that the solution does not contain any other charge that may creep into the region that lies beyond the surface of inversion and which is not covered by the isotropic coordinates. The Brans-Dicke Reissner-Nordstrom spacetime therefore is linearly stable under electrostatic perturbations. This stability result includes the three degenerate cases of the fundamental solution that correspond to the Brans Type 1, the Reissner-Nordstrom and the Schwarzschild background spacetimes.

  17. An Analysis of Facebook Photo Caching Qi Huang, Ken Birman, Robbert van Renesse, Wyatt Lloyd, Sanjeev Kumar, Harry C. Li

    E-Print Network [OSTI]

    Keinan, Alon

    An Analysis of Facebook Photo Caching Qi Huang, Ken Birman, Robbert van Renesse, Wyatt Lloyd, Sanjeev Kumar, Harry C. Li Cornell University, Princeton University, Facebook Inc. Abstract This paper examines the workload of Facebook's photo- serving stack and the effectiveness of the many layers

  18. Local Solutions of Optimal Power Flow Waqquas A. Bukhsh, Andreas Grothey, Ken McKinnon, and Paul Trodden

    E-Print Network [OSTI]

    Grothey, Andreas

    is primarily due to Kirchhoff's voltage law (KVL), which describes the flow of power in transmission lines that minimizes the cost of electric power generation while satisfying operating constraints and meeting demandLocal Solutions of Optimal Power Flow Waqquas A. Bukhsh, Andreas Grothey, Ken McKinnon, and Paul

  19. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-08-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  20. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2004-10-01T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  1. CH-TRU Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-10-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  2. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-05-01T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  3. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-11-20T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  4. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-06-20T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  5. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-01-18T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  6. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-09-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  7. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-01-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codesand corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  8. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-03-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  9. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-08-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  10. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-06-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  11. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-08-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  12. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-12-20T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  13. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-02-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  14. CH-TRU Waste Content Codes (CH TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2004-12-01T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  15. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-09-20T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  16. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-06-20T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  17. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-12-15T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  18. CH-TRU Waste Content Codes (CH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-01-30T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  19. Ken Fikes

    E-Print Network [OSTI]

    Owner

    2007-11-06T23:59:59.000Z

    From the end of the accident year (at 12 months) to the end of the following .... To project season total from current statistics, multiply the current statistics by 4.

  20. CH E 2421 Chemical Engineering Thermodynamics I CH E 3322 Chemical Engineering Thermodynamics II

    E-Print Network [OSTI]

    Zhang, Yuanlin

    CH E 2421 Chemical Engineering Thermodynamics I CH E 3322 Chemical Engineering Thermodynamics II CH E 3330 Engineering Materials Science CH E 4342 Polymer Physics Engineering Thermodynamics I M E 3311 Materials Science M E 3322 Engineering Thermodynamics II M

  1. CH-TRUCON Rev. 21, January 2008

    Office of Environmental Management (EM)

    DOEWIPP 01-3194 Rev. 21 CH-TRU WASTE CONTENT CODES (CH-TRUCON) Revision 21 January 2008 This document supercedes DOEWIPP 01-3194, Revision 20 CH-TRUCON, Rev. 21, January 2008...

  2. Interacting new agegraphic dark energy in non-flat Brans-Dicke cosmology

    E-Print Network [OSTI]

    Ahmad Sheykhi

    2009-12-19T23:59:59.000Z

    We construct a cosmological model of late acceleration based on the new agegraphic dark energy model in the framework of Brans-Dicke cosmology where the new agegraphic energy density $\\rho_{D}= 3n^2 m^2_p /\\eta^{2}$ is replaced with $\\rho_{D}= {3n^2\\phi^2}/({4\\omega \\eta^2}$). We show that the combination of Brans-Dicke field and agegraphic dark energy can accommodate $w_D = -1 $ crossing for the equation of state of \\textit{noninteracting} dark energy. When an interaction between dark energy and dark matter is taken into account, the transition of $w_D $ to phantom regime can be more easily accounted for than when resort to the Einstein field equations is made. In the limiting case $\\alpha = 0$ $(\\omega\\to \\infty)$, all previous results of the new agegraphic dark energy in Einstein gravity are restored.

  3. NostalgisCH Anton Nijholt

    E-Print Network [OSTI]

    Nijholt, Anton

    CH stuk te schrijven over een periode van voor 2006 enerzijds interessant, anderzijds ook een beetje een stuk van wiens leven dan ook automatisch te reconstrueren, wellicht vanuit een bepaald

  4. Lecture Ch. 8 Cloud Classification

    E-Print Network [OSTI]

    Russell, Lynn

    clouds Middle clouds Grayish, block the sun, sometimes patchy Sharp outlines, rising, bright white1 Lecture Ch. 8 · Cloud Classification ­ Descriptive approach to clouds · Drop Growth and Precipitation Processes ­ Microphysical characterization of clouds · Complex (i.e. Real) Clouds ­ Examples

  5. The Roles of Cu Impurity States in CdTe Thin Film Solar Cells Ken K. Chin1

    E-Print Network [OSTI]

    , to a better p-type, to insulating, and then to n-type -- is all due to different levels of Cu involvement treatment temperature. #12;2 I. Introduction CdTe based solar panels have emerged in recent years1 The Roles of Cu Impurity States in CdTe Thin Film Solar Cells Ken K. Chin1 , T.A. Gessert2

  6. Propagation of quantum particles in Brans-Dicke spacetime. The case of Gamma Ray Bursts

    E-Print Network [OSTI]

    S. Capozziello; G. Lambiase

    2015-01-22T23:59:59.000Z

    The propagation of boson particles in a gravitational field described by the Brans-Dicke theory of gravity is analyzed. We derive the wave function of the scalar particles, and the effective potential experienced by the quantum particles considering the role of the varying gravitational coupling. Besides, we calculate the probability to find the scalar particles near the region where a naked singularity is present. The extremely high energy radiated in such a situation could account for the huge emitted power observed in Gamma Ray Bursts.

  7. Propagation of quantum particles in Brans-Dicke spacetime. The case of Gamma Ray Bursts

    E-Print Network [OSTI]

    Capozziello, S

    2015-01-01T23:59:59.000Z

    The propagation of boson particles in a gravitational field described by the Brans-Dicke theory of gravity is analyzed. We derive the wave function of the scalar particles, and the effective potential experienced by the quantum particles considering the role of the varying gravitational coupling. Besides, we calculate the probability to find the scalar particles near the region where a naked singularity is present. The extremely high energy radiated in such a situation could account for the huge emitted power observed in Gamma Ray Bursts.

  8. Instability Analysis of Cylindrical Stellar Object in Brans-Dicke Gravity

    E-Print Network [OSTI]

    Sharif, M

    2015-01-01T23:59:59.000Z

    This paper investigates instability ranges of a cylindrically symmetric collapsing stellar object in Brans-Dicke theory of gravity. For this purpose, we use perturbation approach in the modified field equations as well as dynamical equations and construct a collapse equation. The collapse equation with adiabatic index ($\\Gamma$) is used to explore the instability ranges of both isotropic as well as anisotropic fluid in Newtonian and post-Newtonian approximations. It turns out that the instability ranges depend on the dynamical variables of collapsing fluid. We conclude that the system always remains unstable for $01$ provides instability only for the special case.

  9. 4, 31953227, 2007 Modelling CH4

    E-Print Network [OSTI]

    Boyer, Edmond

    Interactive Discussion EGU 1 Introduction Together with water vapour and carbon dioxide (CO2), CH4, hydrology, soil physical properties, vegetation type and NPP.15 For Kytalyk the simulated CH4 fluxes show

  10. EDUCATIONALIMPACTSTATEMENT C.H. Nash Museum

    E-Print Network [OSTI]

    Dasgupta, Dipankar

    EDUCATIONALIMPACTSTATEMENT CHUCALISSA C.H. Nash Museum The UniversiTy of MeMphis 1987 Indian of the C.H. Nash Museum at Chucalissa, a division of The University of Memphis, is to protect and interpret and present Native American and traditional cultures. CHUCALISSA FACTS · Since 1962, both the C.H. Nash Museum

  11. Dilatonic Brans-Dicke Anisotropic Collapsing Fluid Sphere And de Broglie Quantum Wave Motion

    E-Print Network [OSTI]

    Hossein Ghaffarnejad

    2014-12-18T23:59:59.000Z

    Two dimensional analogue of vacuum sector of the Brans Dicke gravity [1] is studied to obtain dynamics of anisotropic spherical symmetric perfect fluid. Solutions of dynamical field equations are obtained in terms of time and radial coordinates. In static regime the obtained solutions leads to a dark matter fluid with state equation $\\gamma=\\frac{p(\\rho)}{\\varrho}=-0.25.$ For non-static regime the fluid can be treat as a regular matter with positive barotropic index $\\gamma>0.$ Evaluation of total mass of the fluid leads to choose particular values on the Brans Dick parameter as $\\omega>\\frac{2}{3};\\omega0$ the apparent horizon is covered by event horizon and hence the cosmic censorship hypothesis is still maintained as valid. \\\\ In second part of the paper we obtain de Broglie pilot wave of our fluid model. It can be describe particles ensemble which are distinguished from each other by $\\omega.$ Incident current density of particles ensemble is evaluated on the event and apparent horizon describing the `Hawking radiation` in statistical mechanics perspective. The quantum potential is calculated on the event horizon which is independent from $\\omega$ but the evaluated quantum potential on the apparent horizon is depended to particular value of $\\omega$.

  12. Derivation of conditions for a Brans-Dicke coupling constant of order unity be consistent with solar system bounds

    E-Print Network [OSTI]

    Jean Paul Mbelek

    2013-04-30T23:59:59.000Z

    We provide proofs of some assumptions recently made by F. O. Minotti to conclude on the possibility that an additional scalar field minimally coupled to gravity may help to reconcile a Brans-Dicke coupling constant $\\omega$ of the order unity with solar system bounds.

  13. CH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccess Stories Siteandscience, and8 FY0LinkA Look

  14. Gravitational Collapse In Husain Space-time For Brans-Dicke Gravity Theory with Power-law Potential

    E-Print Network [OSTI]

    Prabir Rudra; Ritabrata Biswas; Ujjal Debnath

    2014-08-18T23:59:59.000Z

    The motive of this work is to study gravitational collapse in Husain space-time in Brans-Dicke gravity theory. Among many scalar-tensor theories of gravity, Brans-Dicke is the simplest and the impact of it can be regulated by two parameters associated with it, namely, the Brans-Dicke parameter, $\\omega$, and the potential-scalar field dependency parameter $n$ respectively. V. Husain's work on exact solution for null fluid collapse in 1996 has influenced many authors to follow his way to find the end-state of the homogeneous/in-homogeneous dust cloud. Vaidya's metric is used all over to follow the nature of future outgoing radial null geodesics. Detecting whether the central singularity is naked or wrapped by an event horizon, by the existence of future directed radial null geodesic emitted in past from the singularity is the basic objective. To point out the existence of positive trajectory tangent solution, both particular parametric cases(through tabular forms) and wide range contouring process have been applied. Precisely, perfect fluid's EoS satisfies a wide range of phenomena : from dust to exotic fluid like dark energy. We have used the EoS parameter $k$ to determine the end state of collapse in different cosmological era. Our main target is to check low $\\omega$ (more deviations from Einstein gravity-more Brans Dicke effect) and negative $k$ zones. This particularly throws light on the nature of the end-state of collapse in accelerated expansion in Brans Dicke gravity. It is seen that for positive values of EoS parameter $k$, the collapse results in a black hole, whereas for negative values of $k$, naked singularity is the only outcome. It is also to be noted that "low $\\omega$" leads to the possibility of getting more naked singularities even for a non-accelerating universe.

  15. ARM - Datastreams - nfov2ch

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492airDatastreamsncepgfsnausfc Documentation XDC documentation Data QualityDatastreamsnfov2ch Documentation

  16. Higher Dimensional Szekeres' Space-time in Brans-Dicke Scalar Tensor Theory

    E-Print Network [OSTI]

    Asit Banerjee; Ujjal Debnath; Subenoy Chakraborty

    2004-04-21T23:59:59.000Z

    The generalized Szekeres family of solution for quasi-spherical space-time of higher dimensions are obtained in the scalar tensor theory of gravitation. Brans-Dicke field equations expressed in Dicke's revised units are exhaustively solved for all the subfamilies of the said family. A particular group of solutions may also be interpreted as due to the presence of the so-called C-field of Hoyle and Narlikar and for a chosen sign of the coupling parameter. The models show either expansion from a big bang type of singularity or a collapse with the turning point at a lower bound. There is one particular case which starts from the big bang, reaches a maximum and collapses with the in course of time to a crunch.

  17. Mass and Weak Field Limit of Boson Stars in Brans Dicke Gravity

    E-Print Network [OSTI]

    A. W. Whinnett

    1999-06-14T23:59:59.000Z

    We study boson stars in Brans Dicke gravity and use them to illustrate some of the properties of three different mass definitions: the Schwarzschild mass, the Keplerian mass and the Tensor mass. We analyse the weak field limit of the solutions and show that only the Tensor mass leads to a physically reasonable definition of the binding energy. We examine numerically strong field $\\omega=-1$ solutions and show how, in this extreme case, the three mass values and the conserved particle number behave as a function of the central boson field amplitude. The numerical studies imply that for $\\omega=-1$, solutions with extremal Tensor mass also have extremal particle number. This is a property that a physically reasonable definition of the mass of a boson star must have, and we prove analytically that this is true for all values of $\\omega$. The analysis supports the conjecture that the Tensor mass uniquely describes the total energy of an asymptotically flat solution in BD gravity.

  18. MArCh 2008 46 Introduction

    E-Print Network [OSTI]

    Feng, Xizhou

    Systems #12;MArCh 2008 47 4 US-Canada Power System Outage Task Force. Final Report on the August 14, 2003MArCh 2008 46 Introduction This article describes our ongoing efforts to develop a global modeling-resolution scalable models of complex socio-technical systems;i. Service-oriented architecture and delivery mechanism

  19. Phase plane analysis and statefinder diagnostic of agegraphic dark energy in 5D Brans-Dicke cosmology

    E-Print Network [OSTI]

    Salehi, Amin; Sadeghi, Jafar; Pourali, M

    2015-01-01T23:59:59.000Z

    We present an autonomous phase-plane describing the evolution of field equations containing an agegraphic dark energy in 5D Brans- Dicke cosmology. To observationally verify the numerical results, we simultaneously solve the equations by constraining the model parameters with SNe Ia data. We find conditions for the existence and stability of the critical points (states of the universe) and numerically examine the cosmological parameters. We also investigate the model by means of statefinder diagnostic.

  20. CH-TRU Waste Content Codes

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2008-01-16T23:59:59.000Z

    The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

  1. ARM - Datastreams - fullavhrr15ch4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We wouldDatastreamsdisdrometerch2 Documentation XDC documentation Data Qualitych2ch4ch2ch4

  2. Prof. Roger Wattenhofer http://www.dcg.ethz.ch

    E-Print Network [OSTI]

    @tik.ee.ethz.ch, ETZ G61.3, · Philipp Sommer: sommer@tik.ee.ethz.ch, ETZ G64.1 · Roger Wattenhofer: wattenhofer

  3. Reversible and irreversible spacetime thermodynamics for general Brans-Dicke theories

    SciTech Connect (OSTI)

    Chirco, Goffredo; Eling, Christopher; Liberati, Stefano [SISSA, Via Bonomea 265, 34136 Trieste (Italy); INFN Sezione di Trieste, Via Valerio 2, 34127 Trieste (Italy)

    2011-01-15T23:59:59.000Z

    We derive the equations of motion for Palatini F(R) gravity by applying an entropy balance law TdS={delta}Q+{delta}N to the local Rindler wedge that can be constructed at each point of spacetime. Unlike previous results for metric F(R), there is no bulk viscosity term in the irreversible flux {delta}N. Both theories are equivalent to particular cases of Brans-Dicke scalar-tensor gravity. We show that the thermodynamical approach can be used ab initio also for this class of gravitational theories and it is able to provide both the metric and scalar equations of motion. In this case, the presence of an additional scalar degree of freedom and the requirement for it to be dynamical naturally imply a separate contribution from the scalar field to the heat flux {delta}Q. Therefore, the gravitational flux previously associated to a bulk viscosity term in metric F(R) turns out to be actually part of the reversible thermodynamics. Hence we conjecture that only the shear viscosity associated with Hartle-Hawking dissipation should be associated with irreversible thermodynamics.

  4. QCD Phase Transition in Brans-Dicke DGP model of Brane Gravity

    E-Print Network [OSTI]

    T. Golanbari; A. Mohammadi; Kh. Saaidi

    2014-08-24T23:59:59.000Z

    A DGP brane-world model with a perfect fluid brane matter including a Brans-Dicke (BD) scalar field on brane has been utilized to investigate the problem of quark-hadron phase (QHP) transition in early times of the Universe evoltion. The presence of BD scalar field came up with some modification terms in the Friedmann equation, however we have a usual form of conservation equation for brane matter since scalar field only has a non-mnimally interaction with geometry. Behavior of phase transition strongly depends on the basic evolution equations. Then, even a small change in these relation might come to interesting results about the time of transition. Two different formalisms as smooth crossover formalism in which lattice QCD data is used for obtaining the matter equation of state and first-order phase transition formalism, have been used to investigate of the evolution of physical quatities relevant to quantitative of early times such as energy density $\\rho$, scale factor $a$, and temperature $T$. The obtained results show that the general behavior of temperature is similar in both of two formalisms and the QHP transition occurred at about micro-second after the Big Bang.

  5. Risk management for CAT events Georg Ch. Pflug

    E-Print Network [OSTI]

    Pflug, Georg

    Outline Risk management for CAT events Georg Ch. Pflug 20.5.2005 Georg Ch. Pflug Risk management billion in reconstruction lending. Georg Ch. Pflug Risk management for CAT events #12;Outline Fundamentals, budget reallocation, additional taxation) Georg Ch. Pflug Risk management for CAT events #12;Outline

  6. ARM - Datastreams - avhrr10ch4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would loveDatastreamsassistch2 Documentation Data Quality Plots Citation DOI:ch2ch4

  7. ARM - Datastreams - avhrr12ch4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would loveDatastreamsassistch2 Documentation Data Quality Plots Citationch41rad2ch2ch4

  8. ARM - Datastreams - avhrr15ch4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would loveDatastreamsassistch2 Documentation Data Quality4rad Documentation XDC5ch2ch4

  9. ARM - Datastreams - fullavhrr15ch2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We wouldDatastreamsdisdrometerch2 Documentation XDC documentation Data Qualitych2ch4ch2

  10. People's Physics Book Ch 7-1 The Big Idea

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    People's Physics Book Ch 7-1 The Big Idea The universe has many remarkable qualities, among them;People's Physics Book Ch 7-2 as just the two cars. In this case, internal forces include

  11. sp2 Carbon-Hydrogen Bond (C-H) Functionalization

    E-Print Network [OSTI]

    Yotphan, Sirilata

    2010-01-01T23:59:59.000Z

    C-C) bonds from carbon-hydrogen (C-H) bonds in organicof them is unusually short. Hydrogen atoms were included insp 2 Carbon-Hydrogen Bond (C-H) Functionalization By

  12. J.-J. CH. MEYER* R. J. WIER,INGA**

    E-Print Network [OSTI]

    Wieringa, Roel

    F. DIGNUM J.-J. CH. MEYER* R. J. WIER,INGA** Free Choice and Contextually Permitted Actions the hospitality of Link5ping University during revision of this paper. **This research of J.-J.Ch.Meyer and R Academic Publishers. Printed in the Netherlands. #12;194 F.Dignurn, J.-J.Ch.Meyer, R.J. Wieringa Kamp [14

  13. Competitive CH and OD bond fission channels in the UV photodissociation of the deuterated hydroxymethyl radical CH2OD

    E-Print Network [OSTI]

    Reisler, Hanna

    Competitive C­H and O­D bond fission channels in the UV photodissociation of the deuterated hydroxymethyl radical CH2OD Lin Feng, Andrey V. Demyanenko, and Hanna Reisler Department of Chemistry January 2004 Photodissociation studies of the CH2OD radical in the region 28 000­41 000 cm 1 357­244 nm

  14. Inteview of Ken Moody

    E-Print Network [OSTI]

    Moody, Ken

    2009-02-18T23:59:59.000Z

    thought of doing the Diploma, Alan Turing was not talked about in King's; probably among the Fellowship, people like A.E. Ingham, a senior King's mathematician, would have remembered him; I think it was a hard subject to discuss because of his ending... ; there was also Maurice Wilkes in Cambridge at that time, and the Cambridge initiative to build computers was very much in competition with Manchester where Turing had been; Turing was also at the National Physical Laboratory, and these were the three locations...

  15. Ringleader: Ken Goldberg

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection TechnicalResonantNovember 15 to March 15A Megawatt isJohn1-4179 C

  16. Sorghum Bran, Chestnut Wood Powder, and Chardonnay Grape Seed Flour Addition Effect on Lipid Oxidation and Color in Ground Beef Patties

    E-Print Network [OSTI]

    Roybal, Tabitha Lynn

    2012-02-14T23:59:59.000Z

    &M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 2010 Major Subject: Food Science and Technology SORGHUM BRAN, CHESTNUT WOOD POWDER, AND CHARDONNAY GRAPE SEED FLOUR ADDITION EFFECT... by: Chair of Committee, Rhonda K. Miller Committee Members, Lloyd Rooney Joseph M. Awika Peter S. Murano Intercollegiate Faculty Chair, Jimmy Keeton December 2010 Major Subject: Food Science and Technology iii ABSTRACT...

  17. ARM - Datastreams - aeri01ch2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would love torwpprecipmom Documentation Data Quality Plotsrwpwindmom Documentationch1ch2

  18. ARM - Datastreams - avhrr10ch2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would loveDatastreamsassistch2 Documentation Data Quality Plots Citation DOI:ch2

  19. ARM - Datastreams - avhrr12ch2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would loveDatastreamsassistch2 Documentation Data Quality Plots Citationch41rad2ch2

  20. ARM - Datastreams - avhrr14ch2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would loveDatastreamsassistch2 Documentation Data Quality Plotslacnau Documentation4ch2

  1. ARM - Datastreams - avhrr15ch2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We would loveDatastreamsassistch2 Documentation Data Quality4rad Documentation XDC5ch2

  2. ARM - Datastreams - fullavhrr12ch2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We wouldDatastreamsdisdrometerch2 Documentation XDC documentation Data Quality Plotsch4ch2

  3. ARM - Datastreams - fullavhrr14ch4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492air Comments? We wouldDatastreamsdisdrometerch2 Documentation XDC documentation Data Qualitych2ch4

  4. Central Characterization Program (CCP) Contact-Handled (CH) TRU...

    Office of Environmental Management (EM)

    and Waste Information SystemWaste Data System (WWISWDS) Data Entry Central Characterization Program (CCP) Contact-Handled (CH) TRU Waste Certification and Waste Information...

  5. Best values of parameters for interacting HDE with GO IR-cutoff in Brans-Dicke cosmology

    E-Print Network [OSTI]

    A. Khodam-Mohammadi; E. Karimkhani; A. Sheykhi

    2014-09-09T23:59:59.000Z

    We investigate the interacting holographic dark energy (HDE) with Granda-Oliveros (GO) IR-cutoff in the framework of Brans-Dicke (BD) cosmology. We obtain the equation of state (EoS) parameter of HDE, $w_D$, the effective EoS parameter $w_{\\mathrm{eff}}$, the deceleration parameter $q $ and the squared of sound speed $v_s^2$ in a flat FRW universe. We show that at late time the cosmic coincidence problem can be alleviated. Also we show that for non-interacting case, HDE can give a unified dark matter-dark energy profile in BD cosmology, except that it cannot solve the coincidence problem in the future. By studying the equation of state parameter, we see that the phantom divide may be crossed. Using the latest observational data, we calculate the best values of the parameters for interacting HDE in BD framework. Computing the deceleration parameter implies that the transition from deceleration to the acceleration phase occurred for redshift $z\\geq 0.5$. Finally, we investigate the sound stability of the model, and find that HDE with GO cutoff in the framework of BD cosmology can lead to a stable DE-dominated universe favored by observations, provided we take $\\beta=0.44$ and $b^2<0.35$. This is in contrast to HDE model in Einstein gravity which does not lead to a stable DE dominated universe.

  6. People's Physics Book Ch 21-1 The Big Idea

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    People's Physics Book Ch 21-1 The Big Idea The nuclei of atoms are affected by three forces, the breaking apart of nuclei and it is responsible for atom bombs and nuclear power. A form of fission, where/tH #12;People's Physics Book Ch 21-2 Key Concepts · Some of the matter on Earth is unstable

  7. People's Physics book Ch 2-1 The Big Idea

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    People's Physics book Ch 2-1 The Big Idea Energy is a measure of the amount of, or potential for, often by heat or sound waves. #12;People's Physics book Ch 2-2 Key Applications · In "roller coaster of the bonding energy into energy that is used to power the body. This energy goes on to turn into kinetic energy

  8. People's Physics Book Ch 8-1 The Big Idea

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    People's Physics Book Ch 8-1 The Big Idea When any two bodies in the universe interact, they can an initial configuration and the final configuration · P = E/t Power delivered to or from a system components are conserved. #12;People's Physics Book Ch 8-2 Key Concepts · Impulse is how momentum

  9. Approved Module Information for CH2107, 2014/5 Module Title/Name: Physical Chemistry II Module Code: CH2107

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    : CH2107 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module. ----- [Part 2: Physical Chemistry Laboratory]; Building on material from a number of modules in the 1st and 2Approved Module Information for CH2107, 2014/5 Module Title/Name: Physical Chemistry II Module Code

  10. Approved Module Information for CH3010, 2014/5 Module Title/Name: Catalysis Module Code: CH3010

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CH3010, 2014/5 Module Title/Name: Catalysis Module Code: CH3010 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 in which available: BSc/MChem Applied Chemistry. BSc/MChem Chemistry. BEng/MEng Chemical Engineering. MEng

  11. Excitation functions for the reactions of Ar^+ with CH4, CD4, and CH2D2

    E-Print Network [OSTI]

    Wyatt, J. R.; Strattan, L. W.; Chivalak, S.; Hierl, Peter M.

    1975-01-01T23:59:59.000Z

    Integral reaction cross sections as a function of initial translational energy (0.4–30 eV c.m.) are reported for isotopic variants of the exoergic ion?molecule reaction Ar++CH4 ? ArH++CH3. The excitation functions, which maximize at about 5 e...

  12. Evidence for Methane -Complexes in Reductive Elimination Reactions from TpRh(L)(CH3)H

    E-Print Network [OSTI]

    Jones, William D.

    , the methyl deuteride complex TpRh(L)(CH3)D is observed to rearrange to TpRh(L)(CH2D)H prior to loss of CH3D

  13. JASPERSE CHEM 350 TEST 2 VERSION 3 Ch. 4 The Study of Chemical Reactions

    E-Print Network [OSTI]

    Jasperse, Craig P.

    carbons in the following structures as (R) or (S). CH3 H CH3 H HHO 15. Draw (R)-2-bromopentane 16. Draw

  14. JASPERSE CHEM 341 TEST 2 VERSION 3 Ch. 5 The Study of Chemical Reactions

    E-Print Network [OSTI]

    Jasperse, Craig P.

    of the chiral carbons in the following structures as (R) or (S). CH3 H CH3 H HHO 15. Draw (R)-2-bromopentane 16

  15. aliphatic ch bonds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2015-01-01 39 H-atom high-n Rydberg time-of-flight spectroscopy of CH bond fission in acrolein dissociated at 193 nm Chemistry Websites Summary: H-atom high-n Rydberg...

  16. Imperial College London ChBE London Summer Program 2015

    E-Print Network [OSTI]

    Sherrill, David

    Imperial College London ChBE London Summer Program 2015 (June 28­July 31, 2015) 6 credit hours has taught the London Program twice and GTL twice. Deadline for first payment ($500) with application

  17. Lecture Ch. 5a Surface tension (Kelvin effect)

    E-Print Network [OSTI]

    Russell, Lynn

    1 Lecture Ch. 5a · Surface tension (Kelvin effect) ­ Hygroscopic growth (subsaturated humidity: · Expansion against pressure difference Surface Tension · By definition · By 1st Law (modified for surface) ­ Saturation · Chemical potential (Raoult effect) · Nucleation ­ Competition between surface and chemical

  18. Analysis of the mouse embryonic stem cell regulatory networks obtained by ChIP-chip and ChIP-PET

    E-Print Network [OSTI]

    Mathur, Divya

    Background: Genome-wide approaches have begun to reveal the transcriptional networks responsible for pluripotency in embryonic stem (ES) cells. Chromatin Immunoprecipitation (ChIP) followed either by hybridization to a ...

  19. NOx-Mediated Homogeneous Pathways for the Synthesis of Formaldehyde from CH4-O2 Mixtures

    E-Print Network [OSTI]

    Iglesia, Enrique

    CH4 conversion, because weaker C-H bonds in HCHO and CH3OH relative to CH4 lead to their fast that the O2 distribution along a reactor will not improve HCHO yields but may prove useful to inhibit NOx losses to less reactive N-compounds. 1. Introduction The practical conversion of remote natural gas

  20. Quantum Rate Coefficients and Kinetic Isotope Effect for the Reaction Cl + CH[subscript 4] ? HCl + CH[subscript 3] from Ring Polymer Molecular Dynamics

    E-Print Network [OSTI]

    Li, Yongle

    Thermal rate coefficients and kinetic isotope effect have been calculated for prototypical heavy–light–heavy polyatomic bimolecular reactions Cl + CH[subscript 4]/CD[subscript 4] ? HCl/DCl + CH[subscript 3]/CD[subscript ...

  1. Radio broadcasting and the politics of mass culture in transwar Japan

    E-Print Network [OSTI]

    Jung, Ji Hee

    2010-01-01T23:59:59.000Z

    natta senjika no h?s? ken’etsu. ” H?s? kenky? to ch?sa 52,ni natta senjika no h?s? ken’etsu,” H?s? kenky? to ch?sa 52,see Kogo, “Tai-Nichi ken’etsu seisaku no keisei katei to

  2. Subthreshold Photoionization Spectra of CH3I Perturbed by SF6 C. M. Evansa,b

    E-Print Network [OSTI]

    Findley, Gary L.

    1 (1) Subthreshold Photoionization Spectra of CH3I Perturbed by SF6 C. M. Evansa,b , R. Reiningera spectra of pure CH3I (up to 200 mbar) and CH3I doped into SF6 (up to 1 bar). At the high pressures studied number density (pure CH3I) and SF6 number density (CH3I doped into SF6) shows a quadratic dependence

  3. Ch.2 Solar Energy to Earth and the Seasons

    E-Print Network [OSTI]

    Pan, Feifei

    -Output Energy=Storage Change #12;Learning Objective Four: The Seasons #12;The Seasons SeasonalityCh.2 Solar Energy to Earth and the Seasons #12;Learning Objective One: The Solar System #12;Milky Aphelion ­ farthest, on July 4 152,083,000 km #12;Learning Objective Two: The Solar Energy #12;What

  4. People's Physics Book Ch13-1 The Big Ideas

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    People's Physics Book Ch13-1 The Big Ideas: The name electric current is given to the phenomenon of the power source, you need the total resistance of the circuit and the total current: Vtotal = ItotalRtotal. · Power is the rate that energy is released. The units for power are Watts (W), which equal Joules per

  5. People's Physics Book Ch 16-1 The Big Idea

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    People's Physics Book Ch 16-1 The Big Idea Modern circuitry depends on much more than just elements. An active circuit element needs an external source of power to operate. This differentiates them. base emitter collector Diodes have an arrow showing the direction of the flow. #12;People's Physics

  6. AT 351 Lab 3: Seasons and Surface Temperature (Ch. 3)

    E-Print Network [OSTI]

    Rutledge, Steven

    an important role in an area's local vertical temperature distribution. Below, Figure 1 shows the verticalAT 351 Lab 3: Seasons and Surface Temperature (Ch. 3) Question #1: Seasons (20 pts) A. In your own words, describe the cause of the seasons. B. In the Northern Hemisphere we are closer to the sun during

  7. Molecular Dynamics of Methanol Monocation (CH3OH+ ) in Strong

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Molecular Dynamics of Methanol Monocation (CH3OH+ ) in Strong Laser Fields Bishnu Thapa and H surfaces of methanol neutral, monocation, and singlet and triplet dication were explored using the CBS in the presence of a 2.9 × 1014 W/cm2 800 nm laser field for methanol monocation on the ground state potential

  8. ChE 210A M. F. Doherty Thermodynamics

    E-Print Network [OSTI]

    Bigelow, Stephen

    ChE 210A M. F. Doherty Thermodynamics Instructor: Michael F. Doherty (mfd@engineering.ucsb.edu, 893 is an introduction to the fundamentals of classical and statistical thermodynamics. We focus on equilibrium are formulated using either classical or statistical thermodynamics, and these methods have found wide

  9. Lecture Ch. 2a Energy and heat capacity

    E-Print Network [OSTI]

    Russell, Lynn

    machine! Conservation of energy! Definition of energy! Uniqueness of work values! Q = 0,W = 0 ! "E = 0 ! E1 Lecture Ch. 2a · Energy and heat capacity ­ State functions or exact differentials ­ Internal energy vs. enthalpy · 1st Law of thermodynamics ­ Relate heat, work, energy · Heat/work cycles (and path

  10. Lecture Ch. 2a Energy and heat capacity

    E-Print Network [OSTI]

    Russell, Lynn

    of energy Definition of energy Uniqueness of work values Q = 0,W = 0 E = 0 E2 = E1 Q = 0 E = W Wrev1 Lecture Ch. 2a · Energy and heat capacity ­ State functions or exact differentials ­ Internal energy vs. enthalpy · 1st Law of thermodynamics ­ Relate heat, work, energy · Heat/work cycles (and path

  11. Enantioselective nickel catalysis : exploiting activated C-H bonds

    E-Print Network [OSTI]

    Bencivenga, Nicholas Ernest

    2012-01-01T23:59:59.000Z

    A method for the nickel-catalyzed cross-coupling between benzoxazole and secondary halides was explored. This method was to make use of the activated C-H bond found in benzoxazole at the 2-position to generate the nucleophilic ...

  12. FIBER ORIENTATION MEASUREMENTS IN COMPOSITE MATERIALS , Ch. GERMAIN1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 FIBER ORIENTATION MEASUREMENTS IN COMPOSITE MATERIALS R. BLANC1 , Ch. GERMAIN1 , J.P. DA COSTA1 for the physical properties of composite materials. The theoretical parameters of a given reinforcement are usually. Our method has been successfully applied to the characterization of carbon reinforcement of composite

  13. Seismic Tomography: Definitions Lapo Boschi (lapo@erdw.ethz.ch)

    E-Print Network [OSTI]

    Boschi, Lapo

    Tomography Seismic tomography is the science of interpreting seismic measurements (seismograms) to derive; that is to say, solve the seismological inverse problem. Seismic data and their interpretation Seismic stationsSeismic Tomography: Definitions Lapo Boschi (lapo@erdw.ethz.ch) September 14, 2009 Seismic

  14. Open Source Ch Control System Toolkit and Web-Based

    E-Print Network [OSTI]

    Cheng, Harry H.

    Open Source Ch Control System Toolkit and Web-Based Control System Design for Teaching Automatic, and WCCDM for teaching automatic control of linear time-invariant systems is presented. With the CCST.20454 Keywords: control systems; Web-based education INTRODUCTION Automatic control has become a major

  15. Ch 20. Magnetism Liu UCD Phy1B 2012 1

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Ch 20. Magnetism Liu UCD Phy1B 2012 1 #12;I. MagnetI. Magnet Poles of a magnet: magnetic effect is strongest When the magnet is freely suspended North pole: pointing to north South pole: pointing to south Poles always come in pairs Liu UCD Phy1B 2012 2 #12;Magnetic MaterialsMagnetic Materials Magnetite Fe3O4

  16. 1997 by M. Kostic Ch.4: Probability and Statistics

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    1 ©1997 by M. Kostic Ch.4: Probability and Statistics Variations due to: · Measurement System. ©1997 by M. Kostic Statistical Measurement Theory · Sample - a set of measured data · Measurand - measured variable · (True) mean value: (x') xmean #12;2 ©1997 by M. Kostic Mean Value and Uncertainty x

  17. Lecture Ch. 5a Surface tension (Kelvin effect)

    E-Print Network [OSTI]

    Russell, Lynn

    1 Lecture Ch. 5a · Surface tension (Kelvin effect) ­ Hygroscopic growth (subsaturated humidity Surface Tension · By definition · By 1st Law (modified for surface area change) Kelvin Effect · Force: What happens to condensed H2O? ­ Precipitation processes Surface Thermodynamics · Surfaces require

  18. Approved Module Information for CH1102, 2014/5 Module Title/Name: Organic Chemistry I Module Code: CH1102

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    : CH1102 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module of Delivery Learning Hours Lecture: 12 hours Tutorial: 2 hours Lab Session: 16 hours Independent Study: 70 reading, tutorial support, supervised laboratory sessions Module Assessment Methods of Assessment

  19. Approved Module Information for CH3115, 2014/5 Module Title/Name: Inorganic Chemistry III Module Code: CH3115

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Code: CH3115 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module is provided. The fields of Homogeneous Catalysis and Heterogeneous Catalysis are introduced and basic aspects homogeneous and heterogenous catalytic process), hydroformylation (homogeneous catalysis), ammonia synthesis

  20. Identification of Transcription Factor Binding Sites Derived from Transposable Element Sequences Using ChIP-seq

    E-Print Network [OSTI]

    Jordan, King

    unnoticed using conservation screens. Here, we describe a simple pipeline method for using data generated through ChIP-seq to identify TE-derived TFBS. Key words: Transposable elements, ChIP-seq, gene regulation

  1. Salinity-induced hydrate dissociation: A mechanism for recent CH4 release on Mars

    SciTech Connect (OSTI)

    Madden, Megan Elwood [ORNL; Ulrich, Shannon M [ORNL; Onstott, Tullis [Princeton University; Phelps, Tommy Joe [ORNL

    2007-01-01T23:59:59.000Z

    Recent observations of CH4 in the Martian atmosphere suggest that CH4 has been added relatively recently. Several mechanisms for recent CH4 release have been proposed including subsurface biological methanogenesis, abiogenic hydrothermal and/or volcanic activity, dissociation of CH4 hydrates, atmospheric photolysis, or addition of organics via bolide impact. This study examines the effects of increasing salinity on gas hydrate stability and compares estimates of the Martian geothermal gradient to CH4 and CO2 hydrate stability fields in the presence of high salinity brines. The results demonstrate that salinity increases alone result in a significant decrease in the predicted hydrate stability zone within the Martian subsurface and may be a driving force in CH4 hydrate destabilization. Active thermal and/or pressure fluctuations are not required in order for CH4 hydrates to be the source of atmospheric CH4.

  2. Isomerization of Acetonitrile N-Methylide [CH3CNCH2]+ and N-Methylketenimine [CH3NCCH2]+ Radical Cations in the Gas Phase: Theoretical Study of the [C3,H5,N]+

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    Isomerization of Acetonitrile N-Methylide [CH3CNCH2]·+ and N-Methylketenimine [CH3NCCH2]·+ Radical(d,p) basis set show that acetonitrile N-methylide [CH3CNCH2]·+, a·+, and N-methylketenimine [CH3NCCH2]·+, b with acetonitrile and methyl isocyanide to generate acetonitrile N-methylide [CH3-CtN-CH2]·+, a·+, and N

  3. Chem 350 Jasperse Ch. 3 Handouts 1 ALKANE NAMES (Memorize) (Sections 3.2)

    E-Print Network [OSTI]

    Jasperse, Craig P.

    C) Structure 1 Methane CH4 -162 H-(CH2)-H 2 Ethane C2H6 -89 H-(CH2)2-H 3 Propane C3H8 -42 H-(CH2)3-H 4 Butane C "Petroleum Gas" C2-C4 Propane C3 -42º Propane tanks, camping, etc. Gasoline C4-C9 30-180º

  4. Theoretical Studies of the sp2 C-H Bond Activation

    E-Print Network [OSTI]

    Burke, Kieron

    ring sp2 C-H bond and the methyl sp3 C-H bond are explored. The energies to form the 2 -(N products for both thorium and uranium systems with similar reaction energies of -15.8 kcal(IV) and uranium(IV) alkyl complexes (C5Me5)2AnR2 (where An ) Th, U; R ) CH3, CH2Ph, Ph) have proven

  5. Independent Activity Report, CH2M Hill Plateau Remediation Company- January 2011

    Broader source: Energy.gov [DOE]

    Review of the CH2M Hill Plateau Remediation Company Unreviewed Safety Question Procedure [ARPT-RL-2011-003

  6. Near-infrared electronic spectrum of CH2 Jennifer L. Gottfried and Takeshi Okaa)

    E-Print Network [OSTI]

    Oka, Takeshi

    Near-infrared electronic spectrum of CH2 ¿ Jennifer L. Gottfried and Takeshi Okaa) Department B1( u)X~ 2 A1 electronic transition of CH2 have been observed in the near infrared from 11 000 of CH2 was reported by our group in 1992 as the infrared vibration­ rotation spectrum of the 3 band

  7. 2001 by M. Kosticwww.kostic.niu.edu Ch.3: Measurement System Behavior

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    1 ©2001 by M. Kosticwww.kostic.niu.edu Ch.3: Measurement System Behavior · Ch.3: Measurement System) · Magnitude ratio (2nd O.S.) · Phase shift (2nd O.S.) · 2nd Order System (MathCAD) · The End ©2001 by M. Kosticwww.kostic.niu.edu Ch.3:MeasurementSystem Behavior #12;2 ©2001 by M. Kosticwww

  8. NETWORKS OF LAW ENCODING DIAGRAMS FOR UNDERSTANDING Peter C-H. Cheng

    E-Print Network [OSTI]

    Cheng, Peter

    NETWORKS OF LAW ENCODING DIAGRAMS FOR UNDERSTANDING SCIENCE. Peter C-H. Cheng ESRC Centre learning environments based on LEDs are considered. Cheng, P. C.-H. (1999). Networks of Law Encoding Diagrams for understanding science. European Journal of Psychology of Education, 14(2), 167-184. #12;P. C-H

  9. MODELING THE EMISSIONS OF NITROUS OXIDE (N20) AND METHANE (CH 4) FROM THE

    E-Print Network [OSTI]

    MODELING THE EMISSIONS OF NITROUS OXIDE (N20) AND METHANE (CH 4) FROM THE TERRESTRIAL BIOSPHERE;2 #12;MODELING THE EMISSIONS OF NITROUS OXIDE (N 20) AND METHANE (CH 4) FROM THE TERRESTRIAL BIOSPHERE cli- mate has on natural emissions of N2 0 and CH4 from the terrestrial biosphere to the atmosphere

  10. Interactions between wetlands CH4 emissions and climate at global scale

    E-Print Network [OSTI]

    Canet, Léonie

    emissions? Observations Introduction Tool Wetlands emissions [CH4 ]atmo Feedback Conclusion #12;[CO2 ]atmo e.g.: Climate (T) CO2 anthropogenic emissions wetlands CH4 emissions Under future climate change, Shindell et al. (2004) => +78% under climate change generated by 2xCO2 Introduction Tool Wetlands emissions [CH4

  11. Chemical Hydrides Ken Stroh, facilitator

    E-Print Network [OSTI]

    Development Approach To Deliver Economic H2 via NaBH4 NaBH4 Natural Gas Solar Energy Hydro Power H2 Catalyst and distributed generation applications could be early markets that help establish the infrastructure #12;Refining

  12. de Lange Lab Chromatin Immunoprecipitation (ChIP)

    E-Print Network [OSTI]

    de Lange, Titia

    with cold PBS x 2. 7. Scrape cells in ~ 10 ml PBS into 50 ml conical tube . Spin down cells. 8. Combine cell. The remainder can be kept at 4ºC and reused, but add sodium azide before storage. ChIP Protocol Timeline Day 1IP) protocol 3 Preparing the lysate 1. Grow cells to subconfluence. Set up experiment for 10 IPs. For primary

  13. Ch 15. Thermodynamics Liu UCD Phy1B 2012 1

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Ch 15. Thermodynamics Liu UCD Phy1B 2012 1 #12;I The First Law of ThermodynamicsI. The First Law of Thermodynamics Closed system: U=Q-Wy Q U Internal energy: all the energy of the moleculesgy gy for an ideal gas1B 2012 2 #12;Thermodynamic ProcessesThermodynamic Processes Isothermal: T=0, U=0, Q=W Adiabatic: Q

  14. Efficiency of formation of CH{sub 3}O in the reaction of CH{sub 3}O{sub 2} with ClO

    SciTech Connect (OSTI)

    Biggs, P.; Canosa-Mas, C.E.; Frachebound, J.M. [Physical Chemistry Laboratory, Oxford (United Kingdom)] [Physical Chemistry Laboratory, Oxford (United Kingdom)

    1995-05-15T23:59:59.000Z

    Employing a discharge-flow apparatus the authors measure the branching ratio for the reaction of ClO with CH{sub 3}O{sub 2} to the formation of CH{sub 3}O. The CH{sub 3}O{sub 2} is formed in the stratosphere from the reaction of Cl with CH{sub 4}. This branching ratio is of interest to determine if a chain of reactions through it could be a contributor to the stratospheric decomposition of ozone.

  15. Role of impact parameter in branching reactions: Chemical accelerator studies of the reaction Xe++CH4?XeCH3 ++H

    E-Print Network [OSTI]

    Miller, G. D.; Strattan, L. W.; Hierl, Peter M.

    1981-01-01T23:59:59.000Z

    Integral reaction cross sections and product velocity distributions have been measured for the ion–molecule reaction Xe+(CH4,H)XeCH3 + over the relative reactant translational energy range of 0.7–5.5 eV by chemical accelerator techniques...

  16. Approved Module Information for CH3102, 2014/5 Module Title/Name: Advances in Biomaterials Science Module Code: CH3102

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CH3102, 2014/5 Module Title/Name: Advances in Biomaterials Science Module Code: CH3102 School: Engineering and Applied Science Module Type: Standard Module New Module of lectures, directed reading and tutorial support Module Assessment Methods of Assessment & associated

  17. A Single Transition State Serves Two Mechanisms. The Branching Ratio for CH2O-+ CH3Cl on Improved Potential Energy Surfaces

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    for this reaction has been studied by ab initio molecular dynamics (AIMD). The energies of transition states change of the potential energy surface around the transition state may vary the branching ratioA Single Transition State Serves Two Mechanisms. The Branching Ratio for CH2O·- + CH3Cl on Improved

  18. Formation and Characterization of Acetonitrile N-Methylide [CH3CNCH2]+ and N-Methylketenimine [CH3NCCH2]+ Radical Cations in the Gas Phase

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    Formation and Characterization of Acetonitrile N-Methylide [CH3CNCH2]·+ and N-Methylketenimine [CH3 Palaiseau Cedex, France ReceiVed: July 24, 1997; In Final Form: NoVember 4, 1997 Acetonitrile N by ion-molecule reactions between ionized cyclobutanone or ionized ketene and acetonitrile or methyl

  19. chApter 1. Introduction to Synthesis of Current Science 1 Regarding Cumulative Watershed Effects of Fuel

    E-Print Network [OSTI]

    Watershed Effects of Fuel Reduction Treatments Douglas F. Ryan chApter 2. Fire Regimes and Ecoregions 7 Robert G. Bailey chApter 3. Fuel Management in Forests of the Inland West 19 Russell T. Graham, Theresa B. Jain, Susan Matthews chApter 4. Tools for Fuel Management 69 Bob Rummer chApter 5. Fuel Management

  20. Contrasting wetland CH4 emission responses to simulated glacial atmospheric CO2 in temperate bogs and fens

    E-Print Network [OSTI]

    Gauci, Vincent

    Contrasting wetland CH4 emission responses to simulated glacial atmospheric CO2 in temperate bogs, glacial, Last Glacial Maximum (LGM), methane (CH4), peatland, wetland. Summary · Wetlands were the largest (n = 8 per treatment) and measured gaseous CH4 flux, pore water dissolved CH4 and volatile fatty acid

  1. ChEAS Data: The Chequamegon Ecosystem Atmosphere Study

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Davis, Kenneth J. [Penn State

    The Chequamegon Ecosystem-Atmosphere Study (ChEAS) is a multi-organizational research effort studying biosphere/atmosphere interactions within a northern mixed forest in Northern Wisconsin. A primary goal is to understand the processes controlling forest-atmosphere exchange of carbon dioxide and the response of these processes to climate change. Another primary goal is to bridge the gap between canopy-scale flux measurements and the global CO2 flask sampling network. The ChEAS flux towers participate in AmeriFlux, and the region is an EOS-validation site. The WLEF tower is a NOAA-CMDL CO2 sampling site. ChEAS sites are primarily located within or near the Chequamegon-Nicolet National Forest in northern Wisconsin, with one site in the Ottawa National Forest in the upper peninsula of Michigan. Current studies observe forest/atmosphere exchange of carbon dioxide at canopy and regional scales, forest floor respiration, photosynthesis and transpiration at the leaf level and use models to scale to canopy and regional levels. EOS-validation studies quantitatively assess the land cover of the area using remote sensing and conduct extensive ground truthing of new remote sensing data (i.e. ASTER and MODIS). Atmospheric remote sensing work is aimed at understanding atmospheric boundary layer dynamics, the role of entrainment in regulating the carbon dioxide mixing ratio profiles through the lower troposphere, and feedback between boundary layer dynamics and vegetation (especially via the hydrologic cycle). Airborne studies have included include balloon, kite and aircraft observations of the CO2 profile in the troposphere.

  2. Manganese Porphyrins Catalyze Selective C-H Bond Halogenations

    SciTech Connect (OSTI)

    Liu, Wei; Groves, John T

    2010-01-01T23:59:59.000Z

    We report a manganese porphyrin mediated aliphatic C?H bond chlorination using sodium hypochlorite as the chlorine source. In the presence of catalytic amounts of phase transfer catalyst and manganese porphyrin Mn(TPP)Cl 1, reaction of sodium hypochlorite with different unactivated alkanes afforded alkyl chlorides as the major products with only trace amounts of oxygenation products. Substrates with strong C?H bonds, such as neopentane (BDE =?100 kcal/mol) can be also chlorinated with moderate yield. Chlorination of a diagnostic substrate, norcarane, afforded rearranged products indicating a long-lived carbon radical intermediate. Moreover, regioselective chlorination was achieved by using a hindered catalyst, Mn(TMP)Cl, 2. Chlorination of trans-decalin with 2 provided 95% selectivity for methylene-chlorinated products as well as a preference for the C2 position. This novel chlorination system was also applied to complex substrates. With 5?-cholestane as the substrate, we observed chlorination only at the C2 and C3 positions in a net 55% yield, corresponding to the least sterically hindered methylene positions in the A-ring. Similarly, chlorination of sclareolide afforded the equatorial C2 chloride in a 42% isolated yield. Regarding the mechanism, reaction of sodium hypochlorite with the Mn{sup III} porphyrin is expected to afford a reactive Mn{sup V}?O complex that abstracts a hydrogen atom from the substrate, resulting in a free alkyl radical and a Mn{sup IV}—OH complex. We suggest that this carbon radical then reacts with a Mn{sup IV}—OCl species, providing the alkyl chloride and regenerating the reactive Mn{sup V}?O complex. The regioselectivity and the preference for CH{sub 2} groups can be attributed to nonbonded interactions between the alkyl groups on the substrates and the aryl groups of the manganese porphyrin. The results are indicative of a bent [Mn{sup v}?O---H---C] geometry due to the C—H approach to the Mn{sup v}?O (d??p?)* frontier orbital.

  3. L: Shape-based peak identification for ChIPSeq

    E-Print Network [OSTI]

    Valerie Hower; Steven N. Evans; Lior Pachter

    Abstract. We present a new algorithm for the identification of bound regions from ChIP-seq experiments. Our method for identifying statistically significant peaks from read coverage is inspired by the notion of persistence in topological data analysis and provides a non-parametric approach that is robust to noise in experiments. Specifically, our method reduces the peak calling problem to the study of tree-based statistics derived from the data. We demonstrate the accuracy of our method on existing datasets, and we show that it can discover previously missed regions and can more clearly discriminate between multiple binding events.

  4. Methanogenic Conversion of CO2 Into CH4

    SciTech Connect (OSTI)

    Stevens, S.H., Ferry, J.G., Schoell, M.

    2012-05-06T23:59:59.000Z

    This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

  5. Pyrolysis and Combustion of Acetonitrile (CH{sub 3}CN)

    SciTech Connect (OSTI)

    Britt, P.F.

    2002-05-22T23:59:59.000Z

    Acetonitrile (CH{sub 3}CN) is formed from the thermal decomposition of a variety of cyclic, noncyclic, and polymeric nitrogen-containing compounds such as pyrrole and polyacrylonitrile. The pyrolysis and combustion of acetonitrile have been studied over the past 30 years to gain a more detailed understanding of the complex mechanisms involved in the release of nitrogen-containing compounds such as hydrogen cyanide (HCN) in fires and nitrogen oxides (NOx) in coal combustion. This report reviews the literature on the formation of HCN and NOx from the pyrolysis and combustion of acetonitrile and discusses the possible products found in an acetonitrile fire.

  6. CH2M HILL Plateau Remediation Company have

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C l a r k C o'IUHopper3 Environmental CH2M

  7. Laser photolysis, infrared fluorescence determination of CH3(nu3) vibrational deactivation by He, Ar, N2, CO, SF6, and (CH3)2CO

    SciTech Connect (OSTI)

    Donaldson, D.J.; Leone, S.R.

    1987-06-04T23:59:59.000Z

    Room temperature vibrational deactivation rate constants are reported for methyl radicals with antisymmetric stretch excitation, CH3(nu3) + M CH3 + M, where M = He, Ar, N2, CO, SF6, (CH3)2CO. Excimer laser photolysis of acetone at 193 nm is used to populate CH3(nu3), and time-resolved infrared emission from the CH stretch is used to follow the deactivation kinetics. The rate constants obtained are (+/-2sigma) (2.6 +/- 0.5) x 10 T (He, (6.8 +/- 0.7) x 10 T (Ar), (6.1 +/- 0.6) x 10 T (N2), (3.6 +/- 0.7) x 10 T (CO), (6.9 +/- 0.7) x 10 T (SF6), and (8.1 +/- 0.9) x 10 S (CH3COCH3) in units of cmT molecule s . The deactivation probability is not controlled by long-range forces due to the lone electron on the radical, but rather by the probabilities for intramode vibrational energy flow in CH3.

  8. DISSOCIATIVE RECOMBINATION OF VIBRATIONALLY COLD CH{sup +}{sub 3} AND INTERSTELLAR IMPLICATIONS

    SciTech Connect (OSTI)

    Thomas, R. D.; Kashperka, I.; Vigren, E.; Geppert, W. D.; Hamberg, M.; Larsson, M.; Af Ugglas, M.; Zhaunerchyk, V. [Department of Physics, Stockholm University, Albanova University Centre, SE-106 91 Stockholm (Sweden); Indriolo, N. [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218 (United States); Yagi, K.; Hirata, S. [Department of Chemistry, University of Illinois, Urbana, IL 61801 (United States); McCall, B. J., E-mail: rdt@fysik.su.se [Departments of Chemistry, Astronomy, and Physics, University of Illinois, Urbana, IL 61801 (United States)

    2012-10-10T23:59:59.000Z

    CH{sup +}{sub 3} is an important molecular ion in the astrochemistry of diffuse clouds, dense clouds, cometary comae, and planetary ionospheres. However, the rate of one of the major destruction mechanisms of CH{sup +}{sub 3}, dissociative recombination (DR), has long been uncertain, hindering the use of CH{sup +}{sub 3} as an astrochemical probe. Here, we present the first absolute measurement of the DR of vibrationally cold CH{sup +}{sub 3}, which has been made using the heavy storage ring CRYRING in Stockholm, Sweden. From our collision-energy-dependent cross sections, we infer a thermal rate constant of k(T) = 6.97({+-} 0.03) Multiplication-Sign 10{sup -7}(T/300){sup -0.61({+-}0.01)} cm{sup 3} s{sup -1} over the region 10 K {<=} T {<=} 1000 K. At low collision energies, we have measured the branching fractions of the DR products to be CH{sub 3} (0.00{sup +0.01}{sub -0.00}), CH{sub 2} + H (0.35{sup +0.01}{sub -0.01}), CH + 2H (0.20{sup +0.02}{sub -0.02}), CH + H{sub 2} (0.10{sup +0.01}{sub -0.01}), and C + H{sub 2} + H (0.35{sup +0.01}{sub -0.02}), indicating that two or more C-H bonds are broken in 65% of all collisions. We also present vibrational calculations which indicate that the CH{sup +}{sub 3} ions in the storage ring were relaxed to the vibrational ground state by spontaneous emission during the storage time. Finally, we discuss the implications of these new measurements for the observation of CH{sup +}{sub 3} in regions of the diffuse interstellar medium where CH{sup +} is abundant.

  9. Stoichiometry of CH4 and CO2 flux in a California Rice Paddy

    E-Print Network [OSTI]

    McMillan, Andrew M. S.; Goulden, Michael L.; Tyler, Stanley C.

    2007-01-01T23:59:59.000Z

    Measurements of carbon sequestration by long-term eddyemission versus carbon sequestration, Tellus, Ser. B,which to estimate carbon sequestration from F CH4 data since

  10. Isotopic constraints on off-site migration of landfill CH{sub 4}

    SciTech Connect (OSTI)

    Desrocher, S.; Lollar, B.S. [Univ. of Toronto, Ontario (Canada). Dept. of Geology

    1998-09-01T23:59:59.000Z

    Occurrences of CH{sub 4} in residential areas in the vicinity of the Beare Road landfill, Toronto, Canada, have raised public concern about potential off-site migration of CH{sub 4} from the landfill site. Carbon isotopic analysis of dissolved and gas phase CH{sub 4} at the Beare Road site, however, indicates that CH{sub 4} in the ground water systems in the vicinity of the landfill is related to naturally occurring microbial methanogenesis within these geologic units, rather than to contamination by landfill CH{sub 4}. CH{sub 4} gas in the landfill and landfill cover has {delta}{sup 13}C values typical of microbially produced gas. Concentrations of CH{sub 4} found in deep ground water in the Scarborough, Don, and Whitby Formations underlying the landfill are isotopically distinct from the landfill gases. They are isotopically and compositionally similar, however, to naturally occurring microbial CH{sub 4} identified in organic-rich glacial deposits throughout Ontario. The lack of any significant CH{sub 4} concentrations or concentration gradients in the upper tin zone between the landfill and the deep ground water aquifer is further evidence that no transport between the landfill and deep ground water is occurring.

  11. Bimetallic cleavage of aromatic C-H bonds by rare-earth-metal complexes

    E-Print Network [OSTI]

    Huang, W; Huang, W; Dulong, F; Khan, SI; Cantat, T; Diaconescu, PL

    2014-01-01T23:59:59.000Z

    of Aromatic C-H Bonds by Rare Earth Metal Complexes Wenliangone week prior to use. Rare earth metal oxides (scandium,

  12. alkane c-h bond: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

  13. aliphatic c-h bond: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

  14. arene c-h bonds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

  15. Voluntary Protection Program Onsite Review, CH2M WG LLC, Idaho Cleanup Project – March 2014

    Broader source: Energy.gov [DOE]

    Evaluation to determine whether CH2M WG LLC, Idaho Cleanup Project is performing at a level deserving DOE-VPP Star recognition.

  16. Bimolecular reaction of CH{sub 3} + CO in solid p-H{sub 2}: Infrared absorption of acetyl radical (CH{sub 3}CO) and CH{sub 3}-CO complex

    SciTech Connect (OSTI)

    Das, Prasanta [Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Lee, Yuan-Pern, E-mail: yplee@mail.nctu.edu.tw [Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China)

    2014-06-28T23:59:59.000Z

    We have recorded infrared spectra of acetyl radical (CH{sub 3}CO) and CH{sub 3}-CO complex in solid para-hydrogen (p-H{sub 2}). Upon irradiation at 248 nm of CH{sub 3}C(O)Cl/p-H{sub 2} matrices, CH{sub 3}CO was identified as the major product; characteristic intense IR absorption features at 2990.3 (?{sub 9}), 2989.1 (?{sub 1}), 2915.6 (?{sub 2}), 1880.5 (?{sub 3}), 1419.9 (?{sub 10}), 1323.2 (?{sub 5}), 836.6 (?{sub 7}), and 468.1 (?{sub 8}) cm{sup ?1} were observed. When CD{sub 3}C(O)Cl was used, lines of CD{sub 3}CO at 2246.2 (?{sub 9}), 2244.0 (?{sub 1}), 1866.1 (?{sub 3}), 1046.7 (?{sub 5}), 1029.7 (?{sub 4}), 1027.5 (?{sub 10}), 889.1 (?{sub 6}), and 723.8 (?{sub 7}) cm{sup ?1} appeared. Previous studies characterized only three vibrational modes of CH{sub 3}CO and one mode of CD{sub 3}CO in solid Ar. In contrast, upon photolysis of a CH{sub 3}I/CO/p-H{sub 2} matrix with light at 248 nm and subsequent annealing at 5.1 K before re-cooling to 3.2 K, the CH{sub 3}-CO complex was observed with characteristic IR features at 3165.7, 3164.5, 2150.1, 1397.6, 1396.4, and 613.0 cm{sup ?1}. The assignments are based on photolytic behavior, observed deuterium isotopic shifts, and a comparison of observed vibrational wavenumbers and relative IR intensities with those predicted with quantum-chemical calculations. This work clearly indicates that CH{sub 3}CO can be readily produced from photolysis of CH{sub 3}C(O)Cl because of the diminished cage effect in solid p-H{sub 2} but not from the reaction of CH{sub 3} + CO because of the reaction barrier. Even though CH{sub 3} has nascent kinetic energy greater than 87 kJ mol{sup ?1} and internal energy ?42 kJ mol{sup ?1} upon photodissociation of CH{sub 3}I at 248 nm, its energy was rapidly quenched so that it was unable to overcome the barrier height of ?27 kJ mol{sup ?1} for the formation of CH{sub 3}CO from the CH{sub 3} + CO reaction; a barrierless channel for formation of a CH{sub 3}-CO complex was observed instead. This rapid quenching poses a limitation in production of free radicals via bimolecular reactions in p-H{sub 2}.

  17. Thermal desorption of CH4 retained in CO2 ice

    E-Print Network [OSTI]

    R. Luna; C. Millan; M. Domingo; M. A. Satorre

    2008-01-21T23:59:59.000Z

    CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO2 traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH4 in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO2 ice.

  18. Thermal desorption of CH4 retained in CO2 ice

    E-Print Network [OSTI]

    Luna, R; Domingo, M; Satorre, M A

    2008-01-01T23:59:59.000Z

    CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO2 traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH4 in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO2 ice.

  19. TransCom model simulations of CH? and related species: linking transport, surface flux and chemical loss with CH? variability in the troposphere and lower stratosphere

    E-Print Network [OSTI]

    Patra, P. K.

    A chemistry-transport model (CTM) intercomparison experiment (TransCom-CH?) has been designed to investigate the roles of surface emissions, transport and chemical loss in simulating the global methane distribution. Model ...

  20. OD bond dissociation from the 3s state of deuterated hydroxymethyl radical ,,CH2OD...

    E-Print Network [OSTI]

    Reisler, Hanna

    O­D bond dissociation from the 3s state of deuterated hydroxymethyl radical ,,CH2OD... Lin Feng of the deuterated hydroxymethyl radical CH2OD is investigated on the lowest excited state, the 3s Rydberg state at these wavelengths. Comparison with the conical intersection calculations of Hoffman and Yarkony suggests that O­D

  1. Method of preparing (CH.sub.3).sub.3 SiNSO and byproducts thereof

    DOE Patents [OSTI]

    Spicer, Leonard D. (Salt Lake City, UT); Bennett, Dennis W. (Clemson, SC); Davis, Jon F. (Salt Lake City, UT)

    1984-01-01T23:59:59.000Z

    (CH.sub.3).sub.3 SiNSO is produced by the reaction of ((CH.sub.3).sub.3 Si).sub.2 NH with SO.sub.2. Also produced in the reaction are ((CH.sub.3).sub.3 Si).sub.2 O and a new solid compound [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ]. Both (CH.sub.3).sub.3 SiNSO and [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO.sub.2 pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH.sub.3).sub.3 Si).sub.2 NH, whereby any SO.sub.2 present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO.sub.2 in the original gas sample. The solid product [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] may be used as a standard in solid state NMR spectroscopy.

  2. People's Physics book 3e Ch 19-1 The Big Ideas

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    People's Physics book 3e Ch 19-1 The Big Ideas Heat is a form of energy transfer. It can change). Thermodynamics is the study of heat engines. Any engine or power plant obeys the laws of thermodynamics by the expanding gas. Work can be done on the gas in order to compress it. #12;People's Physics book 3e Ch 19

  3. People's Physics Book 3e Ch 14-1 The Big Idea

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    People's Physics Book 3e Ch 14-1 The Big Idea For static electric charges, the electromagnetic a loop of wire generate currents in that wire; this is how electric power generators work. Likewise field is pointing. Be sure to use your right hand! #12;People's Physics Book 3e Ch 14-2 o Right Hand

  4. RESEARCH ARTICLE Greenhouse gas emissions (CO2, CH4, and N2O) from several

    E-Print Network [OSTI]

    Wehrli, Bernhard

    RESEARCH ARTICLE Greenhouse gas emissions (CO2, CH4, and N2O) from several perialpine and alpine hydropower reservoirs by diffusion and loss in turbines T. Diem · S. Koch · S. Schwarzenbach · B. Wehrli · C investigated greenhouse gas emissions (CO2, CH4, and N2O) from reservoirs located across an altitude gradient

  5. Photodissociation spectroscopy and dynamics of the vinoxy (CH{sub 2}CHO) radical

    SciTech Connect (OSTI)

    Osborn, D.L.; Choi, H.; Neumark, D.M. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley Lab., CA (United States). Chemical Sciences Div.

    1995-11-01T23:59:59.000Z

    The photodissociation spectroscopy and dynamics of the vinoxy (CH{sub 2}CHO) radical have been studied using fast beam photofragment translational spectroscopy. The photodissociation cross section over the B{sup 2}A{double_prime} {l_arrow} X{sup 2}A{double_prime} band is measured, and photofragment translational energy and angular distributions are obtained at several excitation energies. For CH{sub 2}CHO, predissociation is observed over the entire band, including several transitions near the band origin which were seen previously in laser-induced fluorescence experiments. Two dissociation channels are seen: CH{sub 3} + CO and H + CH{sub 2}CO. The CH{sub 3} + CO channel was investigated in considerable detail and appears to proceed via internal conversion to the CH{sub 2}CHO ground state followed by isomerization to CH{sub 3}CO and subsequent dissociation. The translational energy distributions for this channel suggest an isomerization barrier in the range of 2 eV with respect to CH{sub 3} + CO products.

  6. DISCOVERY OF THE FIRST METHANOL (CH [subscript 3] OH) MASER IN THE ANDROMEDA GALAXY (M31)

    E-Print Network [OSTI]

    Sjouwerman, Loránt O.

    We present the first detection of a 6.7 GHz Class II methanol (CH[subscript 3]OH) maser in the Andromeda galaxy (M31). The CH[subscript 3]OH maser was found in a VLA survey during the fall of 2009. We have confirmed the ...

  7. SimpleMonitorUSBXPress User Guide Tobi Delbruck, tobi@ini.phys.ethz.ch

    E-Print Network [OSTI]

    Delbruck, Tobi

    SimpleMonitorUSBXPress User Guide Tobi Delbruck, tobi@ini.phys.ethz.ch Allows monitoring AER over at the University of Sevilla and the second by Tobi Delbruck at INI in Zurich. The firmware and host code is written. Last modified 8/20/2005 Under subversion https://svn.ini.unizh.ch/repos/avlsi/CAVIAR/wp5/USBAER

  8. Ligand Lone-Pair Influence on Hydrocarbon C-H Activation: A Computational Perspective

    SciTech Connect (OSTI)

    Ess, Daniel H; Gunnoe, T. Brent; Cundari, Thomas R; Goddard, William A; Periana, Roy A

    2010-01-01T23:59:59.000Z

    Mid to late transition metal complexes that break hydrocarbon C?H bonds by transferring the hydrogen to a heteroatom ligand while forming a metal?alkyl bond offer a promising strategy for C?H activation. Here we report a density functional (B3LYP, M06, and X3LYP) analysis of cis-(acac){sub 2}MX and TpM(L)X (M = Ir, Ru, Os, and Rh; acac = acetylacetonate, Tp = tris(pyrazolyl)borate; X = CH{sub 3}, OH, OMe, NH{sub 2}, and NMe{sub 2}) systems for methane C?H bond activation reaction kinetics and thermodynamics. We address the importance of whether a ligand lone pair provides an intrinsic kinetic advantage through possible electronic d{sub ?}?p{sub ?} repulsions for M?OR and M?NR{sub 2} systems versus M?CH{sub 3} systems. This involves understanding the energetic impact of the X ligand group on ligand loss, C?H bond coordination, and C?H bond cleavage steps as well as understanding how the nucleophilicity of the ligand X group, the electrophilicity of the transition metal center, and cis-ligand stabilization effect influence each of these steps. We also explore how spectator ligands and second- versus third-row transition metal centers impact the energetics of each of these C?H activation steps.

  9. A CH O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices

    E-Print Network [OSTI]

    Babu, M. Madan

    A C­H· · ·O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices of Science Bangalore 560012, India The serendipitous observation of a C­H· · ·O hydrogen bond mediated­N hydrogen bond involving the side- chain of residue T 2 4 and the N­H group of residue T þ 3. In as many

  10. Time-resolved dynamics in acetonitrile cluster anions CH3CN Ryan M. Young a

    E-Print Network [OSTI]

    Neumark, Daniel M.

    Time-resolved dynamics in acetonitrile cluster anions ðCH3CN�� n Ryan M. Young a , Graham B December 2009 a b s t r a c t Excited state dynamics of acetonitrile cluster anions, ðCH3CN�� n , were, antiparallel solvent molecules [19,20]. Evidence for two electron solvation motifs in acetonitrile also comes

  11. Safety Evaluation Report of the Waste Isolation Pilot Plant Contact Handled (CH) Waste Documented Safety Analysis

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-09-01T23:59:59.000Z

    This Safety Evaluation Report (SER) documents the Department of Energy’s (DOE's) review of Revision 9 of the Waste Isolation Pilot Plant Contact Handled (CH) Waste Documented Safety Analysis, DOE/WIPP-95-2065 (WIPP CH DSA), and provides the DOE Approval Authority with the basis for approving the document. It concludes that the safety basis documented in the WIPP CH DSA is comprehensive, correct, and commensurate with hazards associated with CH waste disposal operations. The WIPP CH DSA and associated technical safety requirements (TSRs) were developed in accordance with 10 CFR 830, Nuclear Safety Management, and DOE-STD-3009-94, Preparation Guide for U. S. Department of Energy Nonreactor Nuclear Safety Analysis Reports.

  12. Reaction Dynamics of Phenyl Radicals (C6H5) with Propylene (CH3CHCH2) and Its Deuterated Isotopologues

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    ARTICLES Reaction Dynamics of Phenyl Radicals (C6H5) with Propylene (CH3CHCH2) and Its Deuterated The reactions between phenyl radicals (C6H5) and propylene (CH3CHCH2) together with its D6- and two D3 atom) of the propylene molecule at the dCH2 unit to form a radical intermediate (CH3CHCH2C6H5

  13. ChBE 4505/4525 Chemical Process Design/Biochemical Process Design Basic Curriculum and Learning Outcomes.

    E-Print Network [OSTI]

    Sherrill, David

    Outcomes. Credit: 3-0-3 Instructor: Matthew J. Realff Textbook: Product & Process Design Principles, Third Edition, Wiley 2009. W.D. Seider, J.D. Seader, D.R. Lewin, S. Widagdo, Catalog Description: Principles Phen. II (ChBE 3210), Kinetics & Reactor Design (ChBE 4300), and separation processes (ChBE 3225

  14. au melange co2-ch4: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of natural gas production. Facing Paris-Sud XI, Universit de 11 Open top chambers and infrared lamps: A comparison of heating efficacy and CO2CH4 dynamics in a lake superior...

  15. 28 BIts&ChIps 17 november 2005 Energetiq Technology heeft een licht-

    E-Print Network [OSTI]

    Cambridge, University of

    28 · BIts&ChIps · 17 november 2005 Energetiq Technology heeft een licht- bron gelanceerd voor extreem ultravi- olet (EUV) metrologie. Deze Electrode- less Z-Pinch EUV-source, of EQ-10M, genereert EUV

  16. Hydrogen Storage in Carbon Nanotubes Through Formation of C-H...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil...

  17. Preliminary Notice of Violation, CH2M-Washington Group Idaho...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LLC - EA-2007-03 June 14, 2007 Issued to CH2M-Washington Group Idaho, LLC, related to Radiation Protection Program Deficiencies at the Radioactive Waste Management Complex -...

  18. ChIMES: "Limited only by our imaginations" | Y-12 National Security...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sensors consist of an MRPs and a ferromagnetic wire. There are no moving parts, and the sensor communicates wirelessly with the detection system. Photo: ChIMES uses chemical...

  19. Intern experience at CH?M Hill, Inc.: an internship report

    E-Print Network [OSTI]

    Winter, William John, 1949-

    2013-03-13T23:59:59.000Z

    A review of the author's internship experience with CH?M HILL, Inc. during the period September 1975 through May 1976 is presented. During this nine month internship the author worked as an Engineer II in the Industrial Processes...

  20. STATEMENT OF CONSIDERATIONS REQUEST BY MlCH..t\\EL BROCKWELL ...

    Broader source: Energy.gov (indexed) [DOE]

    MlCH..tEL BROCKWELL (INVENTOR) FOR THE W .AJVER OF DOM ESTIC N'l'D FOREIGN RJG HTS TO AN IDENTIFIED INVENTION ENTITLED ''EXOTEN SIONED STRU CTURE AND METHOD FOR CONSTRUCTION,"...

  1. Flooding of the continental shelves as a contributor to deglacial CH4 rise

    E-Print Network [OSTI]

    Jones, Peter JS

    Flooding of the continental shelves as a contributor to deglacial CH4 rise ANDY RIDGWELL,1 MARK of the continental shelves that were exposed and vegetated during the glacial sea-level low stand and that can help

  2. PHOTOIONIZATION SPECTRA OF CH3I PERTURBED BY SF6: ELECTRON SCATTERING IN SF6 GAS

    E-Print Network [OSTI]

    Findley, Gary L.

    1 PHOTOIONIZATION SPECTRA OF CH3I PERTURBED BY SF6: ELECTRON SCATTERING IN SF6 GAS C. M. Evansa of SF6 perturbers (up to the perturber density 9.75 x 1019 cm-3 ) disclosed a red shift of autoionizing of the CH3I nd! Rydbergs (n=9,10,11,12), the electron scattering length of SF6 was found to be A = -0.484 nm

  3. 1997-2001 by M. Kostic Ch.5: Uncertainty/Error Analysis

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    1 ©1997-2001 by M. Kostic Ch.5: Uncertainty/Error Analysis · Introduction · Bias and Precision Summation/Propagation (Expanded Combined Uncertainty) · Problem 5-30 ©1997-2001 by M. Kostic Ch.5) at corresponding Probability (%P) Remember: u = d%P = t,%PS (@ %P); z=t=d/S #12;2 ©1997-2001 by M. Kostic Bias

  4. Site Battelle, btiment D 7 route de Drize CH1227 Carouge Tl. 022 379 06 46 Fax 022 379 06 39 www.unige.ch/energie

    E-Print Network [OSTI]

    Laemmli, Ulrich

    Energy Agency SDC: Swiss Agency for Development and Cooperation #12;Site Battelle, bâtiment D 7 route University of New York, Albany. o National Renewable Energy Laboratory à Golden. France : o Ecole des www.unige.ch/energie Groupe Energie ­ Institut Forel / Institut des sciences de l

  5. Fourier Transform Spectroscopy of CH3OH: Rotation-Torsion-Vibration Structure for the CH3-Rocking and OH-Bending Modes

    SciTech Connect (OSTI)

    Lees, R M.; Xu, Li-Hong; Johns, Judy C.; Lu, Zhe; Winnewisser, Brenda P.; Sams, Robert L.

    2004-12-01T23:59:59.000Z

    High-resolution Fourier Transform Spectra of CH3OH have been investigated in the infrared region from 930 -1450 cm-1 in order to map the torsion-rotation energy manifolds associated with the v7 in-plane CH3 rock, the v11 out-of-plane CH3 rock, and the v6 OH bend. Upper-state term values have been determined from the assigned spectral subbands, and have been fitted to power-series expansions to obtain substate origins and effective B-values for the three modes. The substate origins have been grouped into related families according to systemic trends observed in the torsion-vibration energy map, but there are substantial differences from the traditional torsional patterns. There appears to be significant torsion-mediated spectral fractionation, and a variety of subbands of mixed torsion-vibration parentage have been observed. For example, coupling of the v6=1 OH bend to nearby torsionally excited (v1, vt) = (1,1) CH3-rock and (v8, vt) = (1,1) CO-stretch states introduces (v6, vt) = (1,0) ? (0,1) ''forbidden'' subbands into the spectrum and makes the v7+v12-v12 torsional hot band stronger than the v7 fundamental. The results suggest a picture of strong coupling the OH-bending, CH3-rocking and CO-stretching modes that modifies the traditional energy structure and raises interesting and provocative questions about the torsion-vibration identity of a number of the observed states.

  6. Insights into the structure of mixed CO2/CH4 in gas hydrates

    SciTech Connect (OSTI)

    Everett, Susan M [ORNL; Rawn, Claudia J [ORNL; Chakoumakos, Bryan C [ORNL; Keffer, David J. [University of Tennessee, Knoxville (UTK); Huq, Ashfia [ORNL; Phelps, Tommy Joe [ORNL

    2015-01-01T23:59:59.000Z

    The exchange of CO2 for CH4 in natural gas hydrates is an attractive approach to methane for energy production while simultaneously sequestering CO2. In addition to the energy and environmental implications, the solid solution of clathrate hydrate (CH4)1-x(CO2)x 5.75H2O provides a model system to study how the distinct bonding and shapes of CH4 and CO2 influence the structure and properties of the compound. High-resolution neutron diffraction was used to examine mixed CO2/CH4 gas hydrates. CO2-rich hydrates had smaller lattice parameters, which were attributed to the higher affinity of the CO2 molecule interacting with H2O molecules that form the surrounding cages, and resulted in a reduction in the unit cell volume. Experimental nuclear scattering densities illustrate how the cage occupants and energy landscape change with composition. These results provide important insights on the impact and mechanisms for exchanging CH4 and CO2.

  7. J. Chem. Thermodynamics 1996, 28, 521538 Volumetric properties for {(1-x)CO2+xCH4},

    E-Print Network [OSTI]

    Bodnar, Robert J.

    J. Chem. Thermodynamics 1996, 28, 521­538 Volumetric properties for {(1-x)CO2+xCH4}, {(1-x)CO2+xN2, U.S.A. Densities r of pure CO2, CH4, and {(1-x)CO2+xCH4}, {(1-x)CO2+xN2}, and {(1-x)CH4+xN2} were from mole fraction x=0 to x=1. The results were obtained with a custom-designed, high-pressure, high-temperature

  8. Core-to-valence spectroscopic detection of the CH{sub 2}Br radical and element-specific femtosecond photodissociation dynamics of CH{sub 2}IBr

    SciTech Connect (OSTI)

    Attar, Andrew R.; Piticco, Lorena [Department of Chemistry, University of California, Berkeley, California 94720 (United States); Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Leone, Stephen R. [Department of Chemistry, University of California, Berkeley, California 94720 (United States); Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Physics, University of California, Berkeley, California 94720 (United States)

    2014-10-28T23:59:59.000Z

    Element-specific single photon photodissociation dynamics of CH{sub 2}IBr and core-to-valence absorption spectroscopy of CH{sub 2}Br radicals are investigated using femtosecond high-harmonic extreme ultraviolet (XUV) transient absorption spectroscopy. Photodissociation of CH{sub 2}IBr along both the C–I or C–Br reaction coordinates is observed in real-time following excitation at 266 nm. At this wavelength, C–I dissociation is the dominant reaction channel and C–Br dissociation is observed as a minor pathway. Both photodissociation pathways are probed simultaneously through individual 4d(I) N{sub 4/5} and 3d(Br) M{sub 4/5} core-to-valence transitions. The 3d(Br) M{sub 4/5} pre-edge absorption spectrum of the CH{sub 2}Br radical photoproduct corresponding to the C–I dissociation channel is characterized for the first time. Although the radical's singly occupied molecular orbital (SOMO) is mostly localized on the central carbon atom, the 3d(Br) ? ?{sup *}(SOMO) resonances at 68.5 eV and 69.5 eV are detected 2 eV below the parent molecule 3d(Br) ? ?{sup *}(LUMO) transitions. Core-to-valence XUV absorption spectroscopy provides a unique probe of the local electronic structure of the radical species in reference to the Br reporter atom. The measured times for C–I dissociation leading to I and I{sup *} atomic products are 48 ± 12 fs and 44 ± 4 fs, respectively, while the measured C–Br dissociation time leading to atomic Br is 114 ± 17 fs. The investigation performed here demonstrates the capability of femtosecond time-resolved core-level spectroscopy utilizing multiple reporter atoms simultaneously.

  9. Observation of CH4 and other Non-CO2 Green House Gas Emissions from California

    SciTech Connect (OSTI)

    Fischer, Marc L.; Zhao, Chuanfeng; Riley, William J.; Andrews, Arlyn C.

    2009-01-09T23:59:59.000Z

    In 2006, California passed the landmark assembly bill AB-32 to reduce California's emissions of greenhouse gases (GHGs) that contribute to global climate change. AB-32 commits California to reduce total GHG emissions to 1990 levels by 2020, a reduction of 25 percent from current levels. To verify that GHG emission reductions are actually taking place, it will be necessary to measure emissions. We describe atmospheric inverse model estimates of GHG emissions obtained from the California Greenhouse Gas Emissions Measurement (CALGEM) project. In collaboration with NOAA, we are measuring the dominant long-lived GHGs at two tall-towers in central California. Here, we present estimates of CH{sub 4} emissions obtained by statistical comparison of measured and predicted atmospheric mixing ratios. The predicted mixing ratios are calculated using spatially resolved a priori CH{sub 4} emissions and surface footprints, that provide a proportional relationship between the surface emissions and the mixing ratio signal at tower locations. The footprints are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Integral to the inverse estimates, we perform a quantitative analysis of errors in atmospheric transport and other factors to provide quantitative uncertainties in estimated emissions. Regressions of modeled and measured mixing ratios suggest that total CH{sub 4} emissions are within 25% of the inventory estimates. A Bayesian source sector analysis obtains posterior scaling factors for CH{sub 4} emissions, indicating that emissions from several of the sources (e.g., landfills, natural gas use, petroleum production, crops, and wetlands) are roughly consistent with inventory estimates, but livestock emissions are significantly higher than the inventory. A Bayesian 'region' analysis is used to identify spatial variations in CH{sub 4} emissions from 13 sub-regions within California. Although, only regions near the tower are significantly constrained by the tower measurements, CH{sub 4} emissions from the south Central Valley appear to be underestimated in a manner consistent with the under-prediction of livestock emissions. Finally, we describe a pseudo-experiment using predicted CH{sub 4} signals to explore the uncertainty reductions that might be obtained if additional measurements were made by a future network of tall-tower stations spread over California. These results show that it should be possible to provide high-accuracy estimates of surface CH{sub 4} emissions for multiple regions as a means to verify future emissions reductions.

  10. 3 C E 301 Civil Engineering Systems * (fall or spring) 3 CH 302 Principles of Chemistry II * 3 CH 301 Principles of Chemistry I * 4 M 408D Seq, Series & Multivariable Calculus *

    E-Print Network [OSTI]

    Lightsey, Glenn

    S Probability & Statistics for Civil Engineers * 3 E M 306 Statics * 3 E M 319 Mechanics of Solids requirements. Approved Math/Science/ Engineering Science Elective ______________ Approved Science Elective3 C E 301 Civil Engineering Systems * (fall or spring) 3 CH 302 Principles of Chemistry II * 3 CH

  11. Multiphase Turbulent Flow Ken Kiger -UMCP

    E-Print Network [OSTI]

    Gruner, Daniel S.

    emulsions Multi-phase Steam bubble in H20 Ice slurry Coal particles in air Sand particle in H20 #12://www.physics.utoronto.ca/~nonlin/turbidity/turbidity.html #12;Material processing ­ generation of particles & composite materials Energy production ­ coal

  12. Professor Ken Peach Denys Wilkinson Building

    E-Print Network [OSTI]

    Crowther, Paul

    Comprehensive Spending Review. Upon receipt of a written request for information the Freedom of Information Act by a government department if it relates to the formulation or development of government policy. Section 35. We have also taken into account that details of the overall strategic priorities for the research

  13. Ken Nealson is the Wrigley Professor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    account for the major portion of organic carbon oxidation in many sediments. On more modest spatial scales, iron and manganese reduction can be linked to the oxidation of a wide...

  14. Information Gathering Session Gillian Charles & Ken Dragoon

    E-Print Network [OSTI]

    and associated technologies. ­ Hydropower upgrades, new hydropower projects 3 Purpose Develop a hydro supply curve to determine the hydropower development potential in the NW region ­ Council's Seventh Power Plan-effectiveness Quantity-MWh Price - $/MWh 4 #12;3/27/2012 3 Hydro Assessment: 1980's National Hydropower Survey Hydro Site

  15. Updated: May 19, 2014 Ken Christensen

    E-Print Network [OSTI]

    Christensen, Ken

    of direct and induced energy use of network links, equipment, and hosts. Performance evaluation of computer Society for Engineering Education (ASEE) Member of Tau Beta Pi (engineering honor society), Eta Kappa Nu State-of-the-Art Methods to Power Manage Desktop Computers, USF Student Green Energy Fund Council, 2012

  16. Ken Dragoon Northwest Power and Conservation Council

    E-Print Network [OSTI]

    water heaters. Provide market depth around zero market price. 11 #12;1. Efficient Generation.g.: Pulp mills, municipal water pumping systems, irrigation pumps, server farms, water treatment plants Technologies Increasing Transmission Intertie Capability Passing Water Through Unloaded Turbines Passing

  17. Elliot Mainzer, BPA Ken Dragoon, NWPCCg

    E-Print Network [OSTI]

    capital investmentp · Environmental Benefits: ­ CO2 emissions reduced nearly 30 million tons2 y · 2011 reduction equivalent to removing 1 million cars. ­ Nitrogen oxide emissions reduced 450 tons 6 National Protection Agency (EPA). eGRID2010 Version 1.0 Year 2007 GHG Annual Output Emission Rates. http

  18. Dr. Ken Friedman | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,Office of Policy,Policy ActDetroit7471 FederalDonna FriendDecember StatementDr.

  19. Ultrafast UV Pump/IR Probe Studies of C-H Activation in Linear, Cyclic, and Aryl Hydrocarbons

    E-Print Network [OSTI]

    Harris, Charles B.

    Ultrafast UV Pump/IR Probe Studies of C-H Activation in Linear, Cyclic, and Aryl Hydrocarbons, cyclic, and aromatic hydrocarbon solvents on a femtosecond to microsecond time scale. These results have revealed that the structure of the hydrocarbon substrate affects the final C-H bond activation step, which

  20. Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [TpRh(CNneopentyl)] Complex

    E-Print Network [OSTI]

    Jones, William D.

    Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp activation of fluorinated aromatic hydrocarbons by [TpRh(CNneopentyl)] resulted in the formation of products of homogeneous transition-metal catalysts to activate and functionalize C-H bonds of hydrocarbons for industrial

  1. * Corresponding author. Fax: 0041-1-823-5210. E-mail address: peeters@eawag.ch (F. Peeters)

    E-Print Network [OSTI]

    Aeschbach-Hertig, Werner

    .M. Imboden , K. Rozanski , K. FroK hlich Swiss Federal Institute of Technology (ETH), CH-8600 Du( bendorf, Switzerland Swiss Federal Institute of Environmental Science and Technology (EAWAG), CH-8600 Du( bendorf International Atomic Energy Agency, Department of Research and Isotopes, Vienna, Austria Received 24 June 1998

  2. Synthesis, Structure, and Reactivity of O-Donor Ir(III) Complexes: C-H Activation Studies with Benzene

    E-Print Network [OSTI]

    Goddard III, William A.

    with Benzene Gaurav Bhalla, Xiang Yang Liu, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana. All the R-Ir-Py complexes undergo quantitative, intermolecular CH activation reactions with benzene to benzene to generate a discrete benzene complex, cis-R-Ir-PhH; and (D) rapid C-H cleavage. Kinetic isotope

  3. 2590 J. Am. Chem. SOC.1995,117, 2590-2599 The C-H Bond Energy of Benzene

    E-Print Network [OSTI]

    Ellison, Barney

    2590 J. Am. Chem. SOC.1995,117, 2590-2599 The C-H Bond Energy of Benzene Gustavo E. Davico ion with benzene and phenide ion with ammonia: c&6 +NH2- C6H5- +NH3. The ratio of these rate constants for derived. The enthalpy of deprotonationof benzene, the C-H bond dissociationenergy, and the electron

  4. Contract No. DE-AC02-07CH11358 Contract Modification No. 0145

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H-11 H.8 PRIVACY ACT RECORDS H-12 H.9 ADDITIONAL DEFINITIONS H-12 H.10 SERVICE CONTRACT ACT OF 1965 (41 U.S.C. 35) H-14 Contract No. DE-AC02-07CH11358 Section H TOC...

  5. CH 5 MANAGEMENT PLAN.DOC 5-1 5 Management Plan

    E-Print Network [OSTI]

    CH 5 MANAGEMENT PLAN.DOC 5-1 5 Management Plan 5.1 Vision The Willamette Subbasin Plan Oversight drafted the following vision: Willamette Basin citizens from all walks of life prize and enjoy a quilt-work of natural areas, working landscapes, and distinctive communities, from the crest of the Coast Range

  6. LeTemps.ch I Des robots pour mieux comprendre l,volution 08011217:49

    E-Print Network [OSTI]

    Alvarez, Nadir

    LeTemps.ch I Des robots pour mieux comprendre l,volution LE TEMPs 08011217:49 biologie Vendredi6 janvier 2012 Des robots pour mieux comprendre l'6volution Par L'aldatoire entrerait en jeu Le d6'y parvenir en employant comme cobayes... des robots. Etude qu,ils publient cette semaine dans une

  7. Fractal characterisation of high-pressure and hydrogen-enriched CH4air turbulent premixed flames

    E-Print Network [OSTI]

    Gülder, �mer L.

    Fractal characterisation of high-pressure and hydrogen-enriched CH4­air turbulent premixed flames measurements were performed to obtain the flame front images, which were further analyzed for fractal of the flame front curvature as a function of the pressure. Fractal dimension showed a strong dependence

  8. *Email: findley@chem.ulm.edu Photoionization Spectra of CH3I Perturbed by SF6

    E-Print Network [OSTI]

    Findley, Gary L.

    1 *Email: findley@chem.ulm.edu (1) (2) (3) Photoionization Spectra of CH3I Perturbed by SF6: Electron Scattering in SF6 Gas C. M. Evansa,b , R. Reiningera and G. L. Findleya a Department of Chemistry in the presence of SF6 perturbers (up to the perturber density 9.75 x 1019 cm-3 ) disclosed a red shift

  9. Use of phytostabilisation to remediate mtal polluted dredged V Bert', Ch Lors2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Use of phytostabilisation to remediate métal polluted dredged sédiment V Bert', Ch Lors2 scale on dredged sédiments polluted with metals. A sédiment deposit contaminated with metals of waterways générâtes numerous dredged sédiment deposits. Due to the local intensive industrial history

  10. A liquid-crystal model for friction C.H. A. Cheng

    E-Print Network [OSTI]

    Shkoller, Steve

    for sliding friction. Dry friction between two sliding surfaces gen- erates granulation, resultingA liquid-crystal model for friction C.H. A. Cheng , L. H. Kellogg , S. Shkoller , and D. L, University of California, Davis, CA 95616 Contributed by D. L. Turcotte, November 19, 2007 Rate-and-state-friction

  11. Thursday, March 11, 2010 Pages to read: CH5, 407-422

    E-Print Network [OSTI]

    Toohey, Darin W.

    Acid Rain Thursday, March 11, 2010 Pages to read: CH5, 407-422 #12;Cap and Trade Working Already rain, to 7.6 million tons in 2008. #12;Overview of Acid Rain Phenomenon Most common term Agency announced that power plants across the country decreased emissions of SO2, a precursor to acid

  12. Modification No.0136 Contract No. DE-AC02-09CH11466

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    of the Princeton Plasma Physics Laboratory A Department of Energy National Laboratory Contract No. DE-AC02-09CH.2 Provide Effective and Efficient Science and Technology Project / Program / Facilities Management J-B-28 3 Financial Management System(s) J-B-42 6.2 Provide and Efficient, Effective, and Responsive Acquisition

  13. Ch. 13 Transform Coding My Coverage is Different from the Book

    E-Print Network [OSTI]

    Fowler, Mark

    1 Ch. 13 Transform Coding My Coverage is Different from the Book #12;2 Overview Transform. Block Diagram of Transform Coding "Fig. A" Often (but not always!) done on a block-by-block basis: · Non-Overlapped Blocks (most common) · Overlapped Blocks #12;3 Transform as Linear Operator We'll view transforms

  14. CH 4 INVENTORY.DOC 4-1 4 Inventory and Assessment of Conservation Efforts

    E-Print Network [OSTI]

    CH 4 INVENTORY.DOC 4-1 4 Inventory and Assessment of Conservation Efforts 4.1 Background According and imminent protections, and 3) current strategies implemented through specific projects. The inventory residents makes an inventory and assessment of this nature very difficult. It may therefore be helpful

  15. REMARQUES SUR LE MMOIRE DE MM. NAGAOKA ET HONDA; Par CH.-ED. GUILLAUME.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    621 REMARQUES SUR LE MÉMOIRE DE MM. NAGAOKA ET HONDA; Par CH.-ED. GUILLAUME. 11 est facile de voir que le plissement des courbes d'aimantation et d'allongement constaté par MM. Nagaoka et Honda et Honda indique un point singulier des alliages, ou s'il s'agit d'un fait fortuit. J'ajou- terai que

  16. REMARQUES SUR LE TRAVAIL DE MM. NAGAOKA ET HONDA ; Par M. CH.-D. GUILLAUME

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    633 REMARQUES SUR LE TRAVAIL DE MM. NAGAOKA ET HONDA ; Par M. CH.-ÉD. GUILLAUME Les recherches de MM. Nagaolia et Honda sur la inagnéto- striction donnent lieu à deux genres de remarques : les unes que pour une proportion insignifiante dans les résultats énoncés par MM. Nagaoka et Honda, et que les

  17. Temperature and peat type control CO2 and CH4 production in Alaskan permafrost peats

    E-Print Network [OSTI]

    Temperature and peat type control CO2 and CH4 production in Alaskan permafrost peats C . C . T R E Hampshire, Durham, NH, USA, 3 Department of Natural Resources and the Environment, University of New carbon (SOC) losses following perma- frost thaw in peat soils across Alaska. We compared the carbon

  18. Soil chemistry versus environmental controls on production of CH4 and CO2 in northern peatlands

    E-Print Network [OSTI]

    Williams, Christopher J.

    . B. YAVITT a , C. J. WILLIAMS b & R. K. WIEDER c a Department of Natural Resources, Cornell Rates of organic carbon mineralization (to CO2 and CH4) vary widely in peat soil. We transplanted four peat soils with different chemical composition into six sites with different environmental conditions

  19. Temperature Dependence of Scott Thermomagnetic Torque in N2, Ch4, and Hd

    E-Print Network [OSTI]

    Adair, Thomas W.

    1972-01-01T23:59:59.000Z

    curve'which has a maxi- mum value at a field-to-pressure .ratio (P/P) ~. The temperature dependence of (JI/P) ~ for N2 and CH4 has been measured, and from these data the value for the optimum ratio of preces- sion frequency to collision frequency...

  20. PREPARED FORTHE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DEAC0276CH03073

    E-Print Network [OSTI]

    , radial electric fields generated rf­induced fast loss utilized drive poloidal rotation thereby inducePREPARED FORTHE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE­AC02­76CH03073 PRINCETON PLASMA Electric Fields on ICRF Waves C.K. Phillips, J.C. Hosea, Ono, Wilson June 2001 #12; PPPL Reports Disclaimer

  1. The Drivetrain of Sustainability Powering innovation in Clean teCh

    E-Print Network [OSTI]

    California at Davis, University of

    The Drivetrain of Sustainability Powering innovation in Clean teCh iNSiDe: BUSiNeSS OF HeALTH CARe energy use, generation and storage, as well as other necessities of life, environmentally responsible of Management, I hope to participate in what many expect to be the next big chapter of the California Dream

  2. ChBE 4300 Kinetics and Reactor Design (required course) Credit: 3-0-3

    E-Print Network [OSTI]

    Sherrill, David

    , and (ii) reactor design for the homogeneous reaction systems. The design principles for ideal homogeneousChBE 4300 Kinetics and Reactor Design (required course) Credit: 3-0-3 Prerequisite in terms of reaction mechanisms, kinetics, and reactor design. Both homogeneous and heterogeneous reactions

  3. ChBE 4310 Bioprocess Engineering (required course) Credit: 3-0-3

    E-Print Network [OSTI]

    Sherrill, David

    Description: Integrating several ChBE core concepts, bioprocess engineering applies the engineering principles) or Biochemistry II (Chem 4511) minimum grade "D", and Kinetics and Reactor Design, minimum grade "C" Objectives: Specifically, after completing the course, students should be able to: 1.) Apply engineering principles

  4. EnvironMEntAl chEMiStry College of Natural Science and Mathematics

    E-Print Network [OSTI]

    Hartman, Chris

    EnvironMEntAl chEMiStry College of Natural Science and Mathematics Department of Chemistry education and research opportunities focused on the molecular scale as- pects of environmental science prepares students for careers in the environmental science and technology sector as specialists

  5. Learning Qualitative Relations in Physics with Law Encoding Diagrams Peter C-H. Cheng

    E-Print Network [OSTI]

    Cheng, Peter

    Learning Qualitative Relations in Physics with Law Encoding Diagrams Peter C-H. Cheng ESRC Centre that evaluates the effectiveness of Law Encoding Diagrams (LEDs) for learning qualitative relations in the domain of elastic colli- sions in physics. A LED is a representation that captures the laws or important relations

  6. SCIENTIFIC DISCOVERY WITH LAW ENCODING DIAGRAMS Peter C-H. Cheng

    E-Print Network [OSTI]

    Cheng, Peter

    - 1 - SCIENTIFIC DISCOVERY WITH LAW ENCODING DIAGRAMS Peter C-H. Cheng ESRC Centre for Research the concept of Law Encoding Diagrams, LEDs, and argues that they have had a role in scientific discovery the underlying relations of a law, or a system of simultaneous laws, in the structure of a diagram by the means

  7. 16. Wave-particle interaction Reading: Shu, Vol.II, Ch.29

    E-Print Network [OSTI]

    Pohl, Martin Karl Wilhelm

    16. Wave-particle interaction Reading: Shu, Vol.II, Ch.29 16.1 Landau damping We started our discussion of hydromagnetic waves with simple one-dimensional electrostatic fluctuations, the Langmuir waves, whose dispersion relation is = p = e2 ne 0 me Can the waves change plasma properties or, vice versa

  8. Large-Scale Quality Analysis of Published ChIP-seq Data

    E-Print Network [OSTI]

    Kundaje, Anshul

    ChIP-seq has become the primary method for identifying in vivo protein–DNA interactions on a genome-wide scale, with nearly 800 publications involving the technique appearing in PubMed as of December 2012. Individually and ...

  9. Effect of plastic deformation on the formation of acicular ferrite C.H. Lee a,1

    E-Print Network [OSTI]

    Cambridge, University of

    Effect of plastic deformation on the formation of acicular ferrite C.H. Lee a,1 , H deformation on the transformation of austenite to acicular ferrite in a FeÁ/MnÁ/SiÁ/C alloy steel containing non-metallic inclusions was investigated. The transformation to acicular ferrite is retarded

  10. High resolution spectroscopy of BaCH3,,X~ 2 A1...: Fine and hyperfine

    E-Print Network [OSTI]

    Ziurys, Lucy M.

    interactions were also resolved, arising from the spin of the barium nucleus. The complete data set has been these improvements, some of the simplest organometallic compounds such as methyl lithium (LiCH3) have not been in their crystalline state.7,8 In such environments, establishing the fundamental properties of a given molecule

  11. FL47CH15-Goldstein ARI 25 November 2014 9:45 Green Algae as Model

    E-Print Network [OSTI]

    Goldstein, Raymond E.

    FL47CH15-Goldstein ARI 25 November 2014 9:45 Green Algae as Model Organisms for Biological Fluid green algae, spanning from the unicellular Chlamydomonas to multicellular Volvox, have emerged as model of flagellar synchronization. Green algae are well suited to the study of such problems because of their range

  12. Fax +41 61 306 12 34 E-Mail karger@karger.ch

    E-Print Network [OSTI]

    Denver, Robert J.

    Fax +41 61 306 12 34 E-Mail karger@karger.ch www.karger.com At the Cutting Edge Neuroendocrinology in a blood-borne factor, while the db/db strain was deficient in the receptor for this factor [1­3]. Over

  13. BE12CH08-Zare ARI 22 April 2010 20:22 Microfluidic Platforms

    E-Print Network [OSTI]

    Zare, Richard N.

    BE12CH08-Zare ARI 22 April 2010 20:22 R E V I E W S IN A D V A N CE Microfluidic Platforms, genetic analysis Abstract Microfluidics, the study and control of the fluidic behavior in microstruc to analyze various types of intracellular components quantitatively. The microfluidic approach offers a rapid

  14. Charge-Separation in Uranium Diazomethane Complexes Leading to C-H Activation and Chemical Transformation

    E-Print Network [OSTI]

    Meyer, Karsten

    coordination and organometallic chemistry.1-3 The covalency in uranium ligand bonds is weaker thanCharge-Separation in Uranium Diazomethane Complexes Leading to C-H Activation and ChemicalVersity of California, San Diego, Department of Chemistry, 9500 Gilman DriVe, La Jolla, California 92093, and Uni

  15. Bennett's Ch. 17: `Even If...' Maile Holck, 11/16/04

    E-Print Network [OSTI]

    Fitelson, Branden

    1 Bennett's Ch. 17: `Even If...' Maile Holck, 11/16/04 Bennett begins this chapter by dismissing, but the material is fun and (possibly) more relevant to conditionals than Bennett wants to believe. §102. `Even': Preliminaries Bennett starts with Pollock's 1976 account of "even if" wherein: `even if' is an idiom

  16. Bennett's Ch 7: Indicative Conditionals Lack Truth Values Jennifer Zale, 10/12/04

    E-Print Network [OSTI]

    Fitelson, Branden

    Bennett's Ch 7: Indicative Conditionals Lack Truth Values Jennifer Zale, 10/12/04 §38. No Truth Ernest Adams (founder) Jackson Bennett Lycan Gibbard Edgington McDermott III. Requirements for joining. (cf. Jackson, who believes AC has Ramseyan `assertability' conditions PLUS truth conditions). Bennett

  17. Effect of Blast Design on Crack Response C.H. Dowding

    E-Print Network [OSTI]

    Effect of Blast Design on Crack Response C.H. Dowding Professor of Civil & Environmental to assess the effect of changes in blast design on the house response. Velocity response was measured some 11 velocity transducers and 3 crack sensors measured excitation and response for each blast

  18. Computer simulation study of liquid CH2F2 with a new effective pair potential model

    E-Print Network [OSTI]

    Mezei, Mihaly

    to reproduce the thermodynamic internal energy, density, heat capacity, vapor-liquid equilibrium and structuralComputer simulation study of liquid CH2F2 with a new effective pair potential model Pa potential model is proposed for computer simulations of liquid methylene fluoride and used in Monte Carlo

  19. Catalytic C-H Activation and Functionalization: Some Applications in Organic Synthesis

    E-Print Network [OSTI]

    Stoltz, Brian M.

    Non-hydro renewables Hydro power Natural Gas Transportation is Costly - CH4 major constituent,000 3,000 4,000 5,000 6,000 1970 1980 1990 2000 2010 2020 2030 Mtoe Oil Natural gas Coal Nuclear power of natural gas with 5-10% ethane - The energy efficiency of natural gas liquefaction and regasification add

  20. Joint CO2 and CH4 accountability for global warming Kirk R. Smitha,1,2

    E-Print Network [OSTI]

    Silver, Whendee

    the causes of global warming, because the amount of global warming occurring at any time is ac- tually dueJoint CO2 and CH4 accountability for global warming Kirk R. Smitha,1,2 , Manish A. Desaia,1 for global warming is its current annual emissions of greenhouse gases (GHGs)*. The second most common

  1. The time evolution of a vortex-flame interaction observed via planar imaging of CH and OH

    SciTech Connect (OSTI)

    Nguyen, Quang-Viet; Paul, P.H.

    1996-05-01T23:59:59.000Z

    Planar laser-induced fluorescence imaging diagnostics of OH and CH are used to examine a premixed laminar flame subjected to a strong line-vortex pair. Results are reported for a fuel-rcih lamiar CH{sub 4}-air-N{sub 2} rod-stabilized flame. The flow studied was highly reproducible, which enabled the use of phase-sampled imaging to provide time-resolved image sequences. Image sequences are shown for a condition sufficient to produce localized extinction of the primary flame. Results indicate that a breakage in the CH front is not preceded by any distinct change in the OH front. The structure of the CH and OH profiles during the transient leading up to, and through the breakage of the CH front do not appear to be consistent with the concept of a strained laminar flame.

  2. Rare-earth transition-metal gallium chalcogenides RE{sub 3}MGaCh{sub 7} (M=Fe, Co, Ni; Ch=S, Se)

    SciTech Connect (OSTI)

    Rudyk, Brent W.; Stoyko, Stanislav S.; Oliynyk, Anton O.; Mar, Arthur, E-mail: arthur.mar@ualberta.ca

    2014-02-15T23:59:59.000Z

    Six series of quaternary rare-earth transition-metal chalcogenides RE{sub 3}MGaCh{sub 7} (M=Fe, Co, Ni; Ch=S, Se), comprising 33 compounds in total, have been prepared by reactions of the elements at 1050 °C (for the sulphides) or 900 °C (for the selenides). They adopt noncentrosymmetric hexagonal structures (ordered Ce{sub 3}Al{sub 1.67}S{sub 7}-type, space group P6{sub 3}, Z=2) with cell parameters in the ranges of a=9.5–10.2 Å and c=6.0–6.1 Å for the sulphides and a=10.0–10.5 Å and c=6.3–6.4 Å for the selenides as refined from powder X-ray diffraction data. Single-crystal structures were determined for five members of the sulphide series RE{sub 3}FeGaS{sub 7} (RE=La, Pr, Tb) and RE{sub 3}CoGaS{sub 7} (RE=La, Tb). The highly anisotropic crystal structures consist of one-dimensional chains of M-centred face-sharing octahedra and stacks of Ga-centred tetrahedra all pointing in the same direction. Magnetic measurements on the sulphides reveal paramagnetic behaviour in some cases and long-range antiferromagnetic behaviour with low Néel temperatures (15 K or lower) in others. Ga L-edge XANES spectra support the presence of highly cationic Ga tetrahedral centres with a tendency towards more covalent Ga–Ch character on proceeding from the sulphides to the selenides. Band structure calculations on La{sub 3}FeGaS{sub 7} indicate that the electronic structure is dominated by Fe 3d-based states near the Fermi level. - Graphical abstract: The series of chalcogenides RE{sub 3}MGaS{sub 7}, which form for a wide range of rare-earth and transition metals (M=Fe, Co, Ni), adopt highly anisotropic structures containing chains of M-centred octahedra and stacks of Ga-centred tetrahedra. Display Omitted - Highlights: • Six series (comprising 33 compounds) of chalcogenides RE{sub 3}MGaCh{sub 7} were prepared. • They adopt noncentrosymmetric hexagonal structures with high anisotropy. • Most compounds are paramagnetic; some show antiferromagnetic ordering. • Ga L-edge XANES confirms presence of cationic Ga species.

  3. THE CH(G) INDEX AS A NEW CRITERION FOR SELECTING RED GIANT STARS

    SciTech Connect (OSTI)

    Chen, Y. Q.; Zhao, G.; Carrell, K.; Zhao, J. K.; Tan, K. F., E-mail: cyq@bao.ac.cn [Key Laboratory of Optical Astronomy, National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China)

    2013-03-10T23:59:59.000Z

    We have measured the CH G band (CH(G)) index for evolved stars in the globular cluster M3 based on the Sloan Digital Sky Survey (SDSS) spectroscopic survey. It is found that there is a useful way to select red giant branch (RGB) stars from the contamination of other evolved stars such as asymptotic giant branch (AGB) and red horizontal branch (RHB) stars by using the CH(G) index versus (g - r){sub 0} diagram if the metallicity is known from the spectra. When this diagram is applied to field giant stars with similar metallicity, we establish a calibration of CH(G) = 1.625(g - r){sub 0} - 1.174(g - r){sup 2}{sub 0} - 0.934. This method is confirmed by stars with [Fe/H] {approx} -2.3 where spectra of member stars in globular clusters M15 and M92 are available in the SDSS database. We thus extend this kind of calibration to every individual metallicity bin ranging from [Fe/H] {approx} -3.0 to [Fe/H] {approx} 0.0 by using field red giant stars with 0.4 {<=} (g - r){sub 0} {<=} 1.0. The metallicity-dependent calibrations give CH(G) = 1.625(g - r){sub 0} - 1.174(g - r){sup 2}{sub 0} + 0.060[Fe/H] - 0.830 for -3.0 < [Fe/H] {<=} -1.2 and CH(G) = 0.953(g - r){sub 0} - 0.655(g - r){sup 2}{sub 0} + 0.060[Fe/H] - 0.650 for -1.2 < [Fe/H] < 0.0. The calibrations are valid for the SDSS spectroscopic data set, and they cannot be applied blindly to other data sets. With the two calibrations, a significant number of the contaminating stars (AGB and RHB stars) were excluded and thus a clear sample of red giant stars is obtained by selecting stars within {+-}0.05 mag of the calibration. The sample is published online and it is expected that this large and clean sample of RGB stars will provide new information on the formation and evolution of the Galaxy.

  4. Intermolecular C-H Bond Activation Promoted by a Titanium Alkylidyne Brad C. Bailey, Hongjun Fan, Erich W. Baum, John C. Huffman, Mu-Hyun Baik,* and

    E-Print Network [OSTI]

    Baik, Mu-Hyun

    Intermolecular C-H Bond Activation Promoted by a Titanium Alkylidyne Brad C. Bailey, Hongjun Fan to perform intermolecular activation of inert C-H bonds.3-7 We now report that transient titanium alkylidynes an energy profile for the C-H bond activation reaction. Recently, our group reported the synthesis

  5. 2902 J. Phys. Chem. 1984,88, 2902-2905 combination of the resultant CH3 + LiH fragments to form

    E-Print Network [OSTI]

    Huppert, Herbert

    of these two parts but with less C-H bonding. Registry No. Li, 7439-93-2;CH4,74-82-8;CH,LiH, 89922 and Dynamic Stability Criteria during Free Diffusion in a Ternary System Herbert E. Huppert* and Mark A systemsfor which the main diffusion terms greatly exceed the cross-diffusionterms. The results

  6. CO2 CH4 flux Air temperature Soil temperature and Soil moisture, Barrow, Alaska 2013 ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Margaret Torn

    This dataset consists of field measurements of CO2 and CH4 flux, as well as soil properties made during 2013 in Areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) measurements of CO2 and CH4 flux made from June to September (ii) Calculation of corresponding Gross Primary Productivity (GPP) and CH4 exchange (transparent minus opaque) between atmosphere and the ecosystem (ii) Measurements of Los Gatos Research (LGR) chamber air temperature made from June to September (ii) measurements of surface layer depth, type of surface layer, soil temperature and soil moisture from June to September.

  7. CH-{\\pi} interaction-induced deep orbital deformation in a benzene-methane weak binding system

    E-Print Network [OSTI]

    Li, Jianfu

    2015-01-01T23:59:59.000Z

    The nonbonding interaction between benzene and methane, called CH-{\\pi} interaction, plays an important role in physical, chemical, and biological fields. CH-{\\pi} interaction can decrease the system total energy and promote the formation of special geometric configurations. This work investigates systemically the orbital distribution and composition of the benzene-methane complex for the first time using ab initio calculation based on different methods and basis sets. Surprisingly, we find strong deformation in HOMO-4 and LUMO+2 induced by CH-{\\pi} interaction, extending the general view that nonbonding interaction does not cause orbital change of molecules.

  8. REMARQUES SUR LE MMOIRE DE MM. NAGAOKA ET HONDA; Par CH.-ED. GUILLAUME.

    E-Print Network [OSTI]

    Boyer, Edmond

    621 REMARQUES SUR LE M�MOIRE DE MM. NAGAOKA ET HONDA; Par CH.-ED. GUILLAUME. 11 est facile de voir que le plissement des courbes d'aimantation et d'allongement constaté par MM. Nagaoka et Honda et Honda indique un point singulier des alliages, ou s'il s'agit d'un fait fortuit. J'ajou- terai que

  9. Synthesis and spectroscopic characterization of the d{sup 0}transition metal-alkyl-alkene complex Cp{sup *}{sub 2}YCH{sub 2}CH{sub 2}C(CH{sub 3}){sub 2} CH=CH{sub 2}

    SciTech Connect (OSTI)

    Casey, C.P.; Hallenbeck, S.L.; Pollock, D.W.; Landis, C.R. [Univ. of Wisconsin, Madison, WI (United States)

    1995-09-27T23:59:59.000Z

    We have investigated the reaction of yttrium hydride dimer (Cp{sup *} {sub 2}YH){sub 2} (2) with 3,3-dimethyl-1,4-pentadiene in an effort to generate a stable d{sup 0} transition metal-alkyl-alkene complex. Intramolecular alkene insertion is thermodynamically disfavored by the 26 kcal mol{sup -1} strain in the resulting methylcyclobutyl complex. Nonlocal DFT calculations of H{sub 2}SiCp{sub 2}Zr(CH{sub 3} )(CH{sub 2}=CH{sub 2}){sup +} indicate that ethylene is strongly polarized and asymmetrically bonded to the d{sup 0} metal center. Jordan`s X-ray structure of zirconium(IV) pentallyloxo complex 1 showed asymmetric bonding of the alkene ligand to Zr with a bond length difference of 0.21 A (2.68 and 2.89 A). The similarity of the {sup 1}H and {sup 13}C NMR chemical shifts of the complexed alkenes of 3 and 5 with those reported by Jordan for 1 suggests that the complexed alkenes of the chelate complexes 3 and 5 also are bound asymmetrically to the d{sup 0} yttrium center and that the internal alkene carbon is positively polarized. 18 refs., 1 fig.

  10. Shape-based peak identification for ChIP-Seq Valerie Hower, Steven N. Evans, and Lior Pachter

    E-Print Network [OSTI]

    Evans, Steven N.

    Shape-based peak identification for ChIP-Seq Valerie Hower, Steven N. Evans, and Lior PachterSeq [27] and MACS [29] using two published data sets. #12;2 Valerie Hower, Steven N. Evans, and Lior

  11. A crossed molecular beam study of the O(/sup 1/D/sub 2/)+CH/sub 4/ reaction

    SciTech Connect (OSTI)

    Casavecchia, P.; Buss, R.J.; Sibener, S.J.; Lee, Y.T.

    1980-12-15T23:59:59.000Z

    A cross molecular beam experiment was performed to study the O(/sup 1/D/sub 2/)+CH/sub 4/ reaction. The results show that hydrogen atom elimination reaction greatly exceeds molecular hydrogen elimination. (AIP)

  12. ch_1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon3 TheDiscovery

  13. ch_10

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon3 TheDiscovery0

  14. ch_11

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon3 TheDiscovery00

  15. ch_12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon3 TheDiscovery00.0

  16. ch_13

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon3

  17. ch_2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B B ackgr

  18. ch_2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B B ackgr4

  19. ch_2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B B ackgr410

  20. ch_3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B B

  1. ch_3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B B13

  2. ch_3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B B135

  3. ch_3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B B1353-34

  4. ch_3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B B1353-3447

  5. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B

  6. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B8, INEEL

  7. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B8, INEEL18

  8. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  9. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B8,40

  10. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B8,4047

  11. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B8,404758

  12. ch_4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B8,40475871

  13. ch_5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0 B8,404758710

  14. ch_5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.0

  15. ch_5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044

  16. ch_5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW &

  17. ch_5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW &25

  18. ch_5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW

  19. ch_5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW160

  20. ch_6

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW160 6.0

  1. ch_7

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW160 6.00

  2. ch_8

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW160

  3. ch_9

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW160.0

  4. ch_9

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30 2.044HLW160.0

  5. ch_9

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon30

  6. Electron Transfer to SF6 and Oriented CH3Br Sean A. Harris, Susan D. Wiediger, and Philip R. Brooks*

    E-Print Network [OSTI]

    Brooks, Philip R.

    ARTICLES Electron Transfer to SF6 and Oriented CH3Br Sean A. Harris, Susan D. Wiediger, and Philip in collisions of unoriented SF6 and oriented CH3Br. For lab energies 5-30 eV, Br- is the only ion observed from the same energetic threshold for forming Br- . SF5 - , SF6 - , and F- ions are observed from SF6 and O2

  7. Leslie Roche & Ken Tate 10/20/2014 LeslieRoche&KenTate

    E-Print Network [OSTI]

    Tate, Kenneth

    2to5 Months 6to11 Dormant season YearLong Continuous 19 1to5 2to5 Year 11to20 None Rocheetal.InReview. AdaptiveRangelandDecisionMaking Rocheetal.InReview. 1n=494 2n=492 Numberof responsespercounty #12;Leslie) AdaptiveRangelandDecisionMaking Rocheetal.InReview. RanchingInformationResources Rocheetal.InReview. #12

  8. Vibrational relaxation of matrix-isolated CH/sub 3/F and HCl

    SciTech Connect (OSTI)

    Young, L.

    1981-08-01T23:59:59.000Z

    Kinetic and spectroscopic studies have been performed on CH/sub 3/F and HCl as a function of host matrix and temperature. Temporally and spectrally resolved infrared fluorescence was used to monitor the populations of both the initially excited state and the lower lying levels which participate in the relaxation process. For CH/sub 3/F, relaxation from any of the levels near 3.5 ..mu.., i.e. the CH stretching fundamentals or bend overtones, occurs via rapid (< 5 ns) V ..-->.. V transfer to 2..nu../sub 3/ with subsequent relaxation of the ..nu../sub 3/ (CF stretch) manifold. Lifetimes of 2..nu../sub 3/ and ..nu../sub 3/ were determined through overtone, ..delta..V = 2, and fundamental fluorescence. These lifetimes show a dramatic dependence on host lattice, an increase of two orders of magnitude in going from Xe and Ar matrices. Lifetimes depend only weakly on temperature. The relaxation of 2..nu../sub 3/ and ..nu../sub 3/ is consistent with a model in which production of a highly rotationally excited guest via collisions with the repulsive wall of the host is the rate limiting step. For HCl, lifetimes of v = 1,2,3 have been determined. In all hosts, the relaxation is non-radiative. For a given vibrational state, v, the relaxation rate increases in the series k(Ar) < k(Kr) < k(Xe). The dependence of the relaxation rate; on v is superlinear in all matrices, the deviation from linearity increasng in the order Ar < Kr < Xe. The relaxation rates become more strongly temperature dependent with increasing vibrational excitation. The results are consistent with a mechanism in which complex formation introduces the anisotropy necessary to induce a near resonant V ..-->.. R transition in the rate limiting step.

  9. Estimation of mass transport parameters of gases for quantifying CH{sub 4} oxidation in landfill soil covers

    SciTech Connect (OSTI)

    Im, J.; Moon, S.; Nam, K.; Kim, Y.-J. [Department of Civil and Environmental Engineering, College of Engineering, Seoul National University, Seoul (Korea, Republic of); Kim, J.Y. [Department of Civil and Environmental Engineering, College of Engineering, Seoul National University, Seoul (Korea, Republic of)], E-mail: jaeykim@snu.ac.kr

    2009-02-15T23:59:59.000Z

    Methane (CH{sub 4}), which is one of the most abundant anthropogenic greenhouse gases, is produced from landfills. CH{sub 4} is biologically oxidized to carbon dioxide, which has a lower global warming potential than methane, when it passes through a cover soil. In order to quantify the amount of CH{sub 4} oxidized in a landfill cover soil, a soil column test, a diffusion cell test, and a mathematical model analysis were carried out. In the column test, maximum oxidation rates of CH{sub 4} (V{sub max}) showed higher values in the upper part of the column than those in the lower part caused by the penetration of O{sub 2} from the top. The organic matter content in the upper area was also higher due to the active microbial growth. The dispersion analysis results for O{sub 2} and CH{sub 4} in the column are counter-intuitive. As the upward flow rate of the landfill gas increased, the dispersion coefficient of CH{sub 4} slightly increased, possibly due to the effect of mechanical dispersion. On the other hand, as the upward flow rate of the landfill gas increased, the dispersion coefficient of O{sub 2} decreased. It is possible that the diffusion of gases in porous media is influenced by the counter-directional flow rate. Further analysis of other gases in the column, N{sub 2} and CO{sub 2}, may be required to support this hypothesis, but in this paper we propose the possibility that the simulations using the diffusion coefficient of O{sub 2} under the natural condition may overestimate the penetration of O{sub 2} into the soil cover layer and consequently overestimate the oxidation of CH{sub 4}.

  10. CH spectroscopy for carbon chemical erosion analysis in high density low temperature hydrogen plasma

    SciTech Connect (OSTI)

    Westerhout, J.; Rooij, G. J. van [FOM Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster, P. O. Box 1207, 3430 BE Nieuwegein (Netherlands); Lopes Cardozo, N. J. [FOM Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster, P. O. Box 1207, 3430 BE Nieuwegein (Netherlands); Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven (Netherlands); Rapp, J. [FOM Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster, P. O. Box 1207, 3430 BE Nieuwegein (Netherlands); Institut fuer Energieforschung--Plasmaphysik, Forschungszentrum Juelich, Association EURATOM-FZJ, Trilateral Euregio Cluster, D-52425 Juelich (Germany)

    2009-10-12T23:59:59.000Z

    The CH A-X molecular band is measured upon seeding the hydrogen plasma in the linear plasma generator Pilot-PSI [electron temperature T{sub e}=0.1-2.5 eV and electron density n{sub e}=(0.5-5)x10{sup 20} m{sup -3}] with methane. Calculated inverse photon efficiencies for these conditions range from 3 up to >10{sup 6} due to a steeply decreasing electron excitation cross section. The experiments contradict the calculations and show a constant effective inverse photon efficiency of {approx}100 for T{sub e}<1 eV. The discrepancy is explained as the CH A level is populated through dissociative recombination of the molecular ions formed by charge exchange. Collisional de-excitation is observed for n{sub e}>5x10{sup 20} m{sup -3} and 0.1 eV

  11. CHIRON: a package for ChPT numerical results at two loops

    E-Print Network [OSTI]

    Johan Bijnens

    2014-12-02T23:59:59.000Z

    This document describes the package CHIRON which includes two libraries, chiron itself and jbnumlib. CHIRON is a set of routines useful for two-loop numerical results in Chiral Perturbation Theory (ChPT). It includes programs for the needed one- and two-loop integrals as well as routines to deal with the ChPT parameters. The present version includes everything needed for the masses, decay constants and quark-antiquark vacuum-expectation-values. An added routine calculates consistent values for the masses and decay constants when the pion and kaon masses are varied. In addition a number of finite volume results are included: one-loop tadpole integrals, two-loop sunset integrals and the results for masses and decay constants. The numerical routine library jbnumlib contains the numerical routines used in chiron. Many are to a large extent simple C++ versions of routines in the CERNLIB numerical library. Notable exceptions are the dilogarithm and the Jacobi theta function implementations. This paper describes what is included in CHIRON v0.50.

  12. CO2 and CH4 Fluxes across Polygon Geomorphic Types, Barrow, Alaska, 2006-2010

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Tweedie,Craig; Lara, Mark

    Carbon flux data are reported as Net Ecosystem Exchange (NEE), Gross Ecosystem Exchange (GEE), Ecosystem Respiration (ER), and Methane (CH4) flux. Measurements were made at 82 plots across various polygon geomorphic classes at research sites on the Barrow Environmental Observatory (BEO), the Biocomplexity Experiment site on the BEO, and the International Biological Program (IBP) site a little west of the BEO. This product is a compilation of data from 27 plots as presented in Lara et al. (2012), data from six plots presented in Olivas et al. (2010); and from 49 plots described in (Lara et al. 2014). Measurements were made during the peak of the growing seasons during 2006 to 2010. At each of the measurement plots (except Olivas et al., 2010) four different thicknesses of shade cloth were used to generate CO2 light response curves. Light response curves were used to normalize photosynthetically active radiation that is diurnally variable to a peak growing season average ~400 umolm-2sec-1. At the Olivas et al. (2010) plots, diurnal patterns were characterized by repeated sampling. CO2 measurements were made using a closed-chamber photosynthesis system and CH4 measurements were made using a photo-acoustic multi-gas analyzer. In addition, plot-level measurements for thaw depth (TD), water table depth (WTD), leaf area index (LAI), and normalized difference vegetation index (NDVI) are summarized by geomorphic polygon type.

  13. Cooperative, Multicentered CH/ Interaction-Controlled Supramolecular Self-Assembly Processes

    SciTech Connect (OSTI)

    Li, Qing [ORNL; Han, Chengbo [North Carolina State University; Horton, Scott R [ORNL; Fuentes-Cabrera, Miguel A [ORNL; Sumpter, Bobby G [ORNL; Lu, Wenchang [North Carolina State University; Bernholc, J. [North Carolina State University; Maksymovych, Petro [ORNL; Pan, Minghu [ORNL

    2012-01-01T23:59:59.000Z

    Supramolecular self-assembly on well-defined surfaces provides access to a multitude of nanoscale architectures, including clusters of distinct symmetry and size. The driving forces underlying supramolecular structures generally involve both graphoepitaxy and weak directional nonconvalent interactions. Here we show that functionalizing a benzene molecule with an ethyne group introduces attractive interactions in a 2D geometry, which would otherwise be dominated by intermolecular repulsion. Furthermore, the attractive interactions enable supramolecular self-assembly, wherein a subtle balance between very weak CH/{pi} bonding and molecule-surface interactions produces a well-defined 'magic' dimension and chirality of supramolecular clusters. The nature of the process is corroborated by extensive scanning tunneling microscopy/spectroscopy (STM/S) measurements and ab initio calculations, which emphasize the cooperative, multicenter characters of the CH/{pi} interaction. This work points out new possibilities for chemical functionalization of {pi}-conjugated hydrocarbon molecules that may allow for the rational design of supramolecular clusters with a desired shape and size.

  14. CH3-ReO3 on gamma-Al2O3: understanding its structure, initiation,and reactivity in olefin metathesis

    SciTech Connect (OSTI)

    Salameh, Alain; Joubert, Jerome; Baudouin, Anne; Lukens, Wayne; Delbecq, Francoise; Sautet, Philippe; Basset, Jean Marie; Coperet,Christophe

    2007-01-20T23:59:59.000Z

    Me-ReO3 on gamma-alumina: understanding the structure, theinitiation and thereactivity of a highly active olefin metathesiscatalyst Heterolytic splitting of the C-H bond of the methyl group ofCH3ReO3 on AlsO reactive sites of alumina as a way to generate the activesite of CH3ReO3 supported on gamma-Al203.

  15. Infrared diode laser studies of the products from the reaction CH{sub 2}({tilde X}{sup 3}B{sub 1}) + O{sub 2} and from the near-UV photolysis of CH{sub 3}NCS

    SciTech Connect (OSTI)

    Alvarez, R.A.

    1993-12-01T23:59:59.000Z

    Absolute yields of CO, CO{sub 2}, and H{sub 2}CO formed in reaction of triplet methylene ({tilde X} {sup 3}B{sub 1} {triple_bond} CH{sub 2}) with O{sub 2} were determined using a flash kinetic spectrometer. CH{sub 2} radicals were generated by excimer laser photolysis of ketene and product formation was monitored by time-resolved infrared diode laser absorption. Reaction was carried out in a static gas cell at room temperature at 1--25 torr. Measured product yields were CO, 0.34 {plus_minus} 0.06; CO{sub 2}, 0.40 {plus_minus} 0.08 H{sub 2}CO, 0.16 {plus_minus} 0.04. Rate constants for production of CO and CO{sub 2} were equivalent to the published rate constant for removal of CH{sub 2}. Indirect evidence indicated that yield of OH is 0.30 {plus_minus} 0.05. Ultraviolet spectrum of methyl isothiocyanate (CH{sub 3}NCS {triple_bond} MITC) and quantum yield for dissociation into methyl isocyanide (CH{sub 3}NC) and atomic sulfur at 308 nm, {Phi} 0.98 {plus_minus} 0.24, were measured. MITC is widely used as a fumigant and readily enters the atmosphere during and after application. Results indicate that photodissociation by sunlight is an effective pathway for removal of MITC from atmosphere. A mechanism is proposed to account for the observed formation of methyl isocyanate (CH{sub 3}NCO) as a secondary product in controlled laboratory studies.

  16. Analysis of the Christensen et al. Clauser-Horne (CH)-Inequality-Based Test of Local Realism

    E-Print Network [OSTI]

    Donald A. Graft

    2015-01-03T23:59:59.000Z

    The Clauser-Horne (CH) inequality can validly test aspects of locality when properly applied. This paper analyzes a recent CH-based EPRB experiment, the Christensen et al. experiment. Full details of the data analysis applied to the experiment are given. It is shown that the experiment confirms locality and disconfirms the quantum joint prediction. Additionally, the paper contributes to promulgation of robust and correct data analysis by describing the important degrees of freedom that affect the analysis, and that must be addressed in the analysis of any experiment.

  17. Liu Shao-Ch'i and "People's War": A Report on the Creation of Base Areas in 1938

    E-Print Network [OSTI]

    Schwarz, Henry G.

    1969-01-01T23:59:59.000Z

    and the methods they used in dealing with those problems. The document is a report by Liu Shao-ch'i on the creation of Chin-Ch'a-Chi, formally the Shansi-Chahar-Hopei Border region, and other resistance cen ters behind Japanese lines. It was said to have been... provinces of Hopei, Chahar, Suiyiian, Shan tung, and Shansi. Only the East Hopei Autonomous Council 5 under General Yin Ju-keng materialized from the Japanese ef forts. Along the northern periphery of North China, bordering on the Gobi desert...

  18. Detection of Class I Methanol (CH3OH) Maser Candidates in Supernova Remnants

    E-Print Network [OSTI]

    Pihlström, Y M; Frail, D A; Claussen, M J; Mesler, R A; McEwen, B C

    2013-01-01T23:59:59.000Z

    We have used the Karl G. Jansky Very Large Array (VLA) to search for 36 GHz and 44 GHz methanol (CH3OH) lines in a sample of 21 Galactic supernova remnants (SNRs). Mainly the regions of the SNRs with 1720 MHz OH masers were observed. Despite the limited spatial extent covered in our search, methanol masers were detected in both G1.4-0.1 and W28. Additional masers were found in SgrAEast. More than 40 masers were found in G1.4-0.1 which we deduce are due to interactions between the SNR and at least two separate molecular clouds. The six masers in W28 are associated with the molecular cloud that is also associated with the OH maser excitation. We discuss the possibility that the methanol maser may be more numerous in SNRs than the OH maser, but harder to detect due to observational constraints.

  19. Final Report for DOE Project DE-FC07-99CH11010

    SciTech Connect (OSTI)

    Jed Randall; Robert Kean

    2003-10-22T23:59:59.000Z

    Department of Energy award number DE-FC07-99CH11010, Enhanced Utilization of Corn Based Biomaterials, supported a technology development program sponsored by Cargill Dow LLC from September 30, 1999 through June 30, 2003. The work involved fundamental scientific studies on poly lactic acid (PLA), a new environmentally benign plastic material from renewable resources. DOE funds supported academic research at the Colorado School of Mines and the National Renewable Energy Laboratory (NREL), and industry cost share was directed towards applied research into new product development utilizing the fundamental information generated by the academic partners. Under the arrangement of the grant, the fundamental information is published so that other companies can utilize it in evaluating the applicability of PLA in their own products. The overall project objective is to increase the utilization of PLA, a renewable resource based plastic, currently produced from fermented corn sugar.

  20. Theoretical study on collision dynamics of H{sup +} + CH{sub 4} at low energies

    SciTech Connect (OSTI)

    Gao, Cong-Zhang [The Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China) [The Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Laboratoire de Physique Théorique-IRSAMC, Université Paul Sabatier, F-31062 Toulouse Cedex, France and CNRS, UMR5152, F-31062 Toulouse Cedex (France); Wang, Jing [The Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China) [The Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China); Wang, Feng [Laser Micro/Nano Fabrication Laboratory, School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081 (China)] [Laser Micro/Nano Fabrication Laboratory, School of Mechanical Engineering, Beijing Institute of Technology, Beijing 100081 (China); Zhang, Feng-Shou, E-mail: fszhang@bnu.edu.cn [The Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China) [The Key Laboratory of Beam Technology and Material Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Beijing Radiation Center, Beijing 100875 (China); Center of Theoretical Nuclear Physics, National Laboratory of Heavy Ion Accelerator of Lanzhou, Lanzhou 730000 (China)

    2014-02-07T23:59:59.000Z

    In this work we make an investigation on collision dynamics of H{sup +} + CH{sub 4} at 30 eV by using time-dependent density functional theory coupled with molecular dynamics approach. All possible reactions are presented based on 9 incident orientations. The calculated fragment intensity is in nice agreement with experimental results. The mechanism of reaction transition for dissociation and proton exchange processes is explained by the intra-molecule energy transfer. However, the energy loss of the proton is in poor agreement with experimental results. The discrepancy is attributed to the mean-field treatment of potential surface. We also studied the dependence on initial velocity of both proton and methane. In addition, we find that for dynamical evolution a different self-interaction correction (SIC) may lead to different results, but with respect to the position of rainbow angle, average-density SIC seems to have reasonable correction.

  1. Detection of class I methanol (CH{sub 3}OH) maser candidates in supernova remnants

    SciTech Connect (OSTI)

    Pihlström, Y. M.; Mesler, R. A.; McEwen, B. C. [Department of Physics and Astronomy, University of New Mexico, MSC07 4220, Albuquerque, NM 87131 (United States); Sjouwerman, L. O.; Frail, D. A.; Claussen, M. J., E-mail: ylva@unm.edu [National Radio Astronomy Observatory, P.O. Box 0, Lopezville Road 1001, Socorro, NM 87801 (United States)

    2014-04-01T23:59:59.000Z

    We have used the Karl G. Jansky Very Large Array to search for 36 GHz and 44 GHz methanol (CH{sub 3}OH) lines in a sample of 21 Galactic supernova remnants (SNRs). Mainly the regions of the SNRs with 1720 MHz OH masers were observed. Despite the limited spatial extent covered in our search, methanol masers were detected in both G1.4–0.1 and W28. Additional masers were found in Sgr A East. More than 40 masers were found in G1.4–0.1, which we deduce are due to interactions between the SNR and at least two separate molecular clouds. The six masers in W28 are associated with the molecular cloud that is also associated with the OH maser excitation. We discuss the possibility that the methanol maser may be more numerous in SNRs than the OH maser, but harder to detect due to observational constraints.

  2. Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation

    SciTech Connect (OSTI)

    Colby, Denise; Bergman, Robert; Ellman, Jonathan

    2010-05-13T23:59:59.000Z

    Once considered the 'holy grail' of organometallic chemistry, synthetically useful reactions employing C-H bond activation have increasingly been developed and applied to natural product and drug synthesis over the past decade. The ubiquity and relative low cost of hydrocarbons makes C-H bond functionalization an attractive alternative to classical C-C bond forming reactions such as cross-coupling, which require organohalides and organometallic reagents. In addition to providing an atom economical alternative to standard cross - coupling strategies, C-H bond functionalization also reduces the production of toxic by-products, thereby contributing to the growing field of reactions with decreased environmental impact. In the area of C-C bond forming reactions that proceed via a C-H activation mechanism, rhodium catalysts stand out for their functional group tolerance and wide range of synthetic utility. Over the course of the last decade, many Rh-catalyzed methods for heteroatom-directed C-H bond functionalization have been reported and will be the focus of this review. Material appearing in the literature prior to 2001 has been reviewed previously and will only be introduced as background when necessary. The synthesis of complex molecules from relatively simple precursors has long been a goal for many organic chemists. The ability to selectively functionalize a molecule with minimal pre-activation can streamline syntheses and expand the opportunities to explore the utility of complex molecules in areas ranging from the pharmaceutical industry to materials science. Indeed, the issue of selectivity is paramount in the development of all C-H bond functionalization methods. Several groups have developed elegant approaches towards achieving selectivity in molecules that possess many sterically and electronically similar C-H bonds. Many of these approaches are discussed in detail in the accompanying articles in this special issue of Chemical Reviews. One approach that has seen widespread success involves the use of a proximal heteroatom that serves as a directing group for the selective functionalization of a specific C-H bond. In a survey of examples of heteroatom-directed Rh catalysis, two mechanistically distinct reaction pathways are revealed. In one case, the heteroatom acts as a chelator to bind the Rh catalyst, facilitating reactivity at a proximal site. In this case, the formation of a five-membered metallacycle provides a favorable driving force in inducing reactivity at the desired location. In the other case, the heteroatom initially coordinates the Rh catalyst and then acts to stabilize the formation of a metal-carbon bond at a proximal site. A true test of the utility of a synthetic method is in its application to the synthesis of natural products or complex molecules. Several groups have demonstrated the applicability of C-H bond functionalization reactions towards complex molecule synthesis. Target-oriented synthesis provides a platform to test the effectiveness of a method in unique chemical and steric environments. In this respect, Rh-catalyzed methods for C-H bond functionalization stand out, with several syntheses being described in the literature that utilize C-H bond functionalization in a key step. These syntheses are highlighted following the discussion of the method they employ.

  3. Prerequisite Chain for CH E courses The chemical engineering department has revised the current list of prerequisites according to the map

    E-Print Network [OSTI]

    Maranas, Costas

    Prerequisite Chain for CH E courses The chemical engineering department has revised the currentth semester 7th semester 8th semester PROPOSED PREREQUISITES prerequisite prerequisite or concurrent except CH E 300. 3. Math 230 and 251 cover material that is used in several chemical engineering courses

  4. UCOWRJournal of Contemporary Water researCh & eduCation Universities CoUnCil on Water resoUrCes

    E-Print Network [OSTI]

    Pasternack, Gregory B.

    of flooding and cost of protection. van Dantzig's 1956 paper described this risk-based calculation. HeUrnal of Contemporary Water researCh & edUCation issUe 141, pages 1-16, marCh 2009 Dutch Flood Policy Innovations of California - Davis F lood risk management is an important part of life in the Netherlands. The Netherlands

  5. Effects of Collision and Vibrational Energy on the Reaction of CH3CHO+() with C2D4 Ho-Tae Kim, Jianbo Liu, and Scott L. Anderson*

    E-Print Network [OSTI]

    Anderson, Scott L.

    , we calculated the structures and energetics of 13 different complexes that potentially could serve vibrational state. REMPI through different vibrational levels of the B~ electronic state is used to produce CH dynamics with increasing energy. For the CH3CHO+- C2H4 system, there is an important direct mechanism even

  6. CH O Hydrogen Bonds at Protein-Protein Interfaces*S Received for publication, May 8, 2002, and in revised form, July 8, 2002

    E-Print Network [OSTI]

    Luhua, Lai

    CH O Hydrogen Bonds at Protein-Protein Interfaces*S Received for publication, May 8, 2002, a statistical potential has been de- veloped to quantitatively describe the CH O hydrogen bonding interaction-protein interaction studies. The conventional hydrogen bonds of the type X­H Y (where X and Y N or O) have been widely

  7. CB26CH23-Ideker ARI 26 June 2010 20:15 A Decade of Systems Biology

    E-Print Network [OSTI]

    advances in soft- ware tools that allow biologists to explore system-wide models and to formulate newCB26CH23-Ideker ARI 26 June 2010 20:15 R E V I E W S IN A D V A N CE A Decade of Systems Biology) Abstract Systems biology provides a framework for assembling models of biolog- ical pathways from

  8. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    with a project management system that closely linked the field crews to the engineering staff which developedPREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMA. Availability This report is posted on the U.S. Department of Energy's Princeton Plasma Physics Laboratory

  9. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    to the general public from: National Technical Information Service U.S. Department of Commerce 5285 Port Royal of the computer control system for the LPI. I. INTRODUCTION The National Spherical Torus Experiment (NSTXPREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMA

  10. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    copies of this report from: U.S. Department of Energy Office of Scientific and Technical Information DOE how these are provided by the candidate PBX-M NBI system. I. INTRODUCTION The National CompactPREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMA

  11. Resonance enhanced multiphoton ionization probing of H atoms and CH3 radicals in a hot lament chemical vapour deposition reactor

    E-Print Network [OSTI]

    Bristol, University of

    - lished route for forming polycrystalline diamond ®lms, which are ®nding ever increasing roles reactor used for diamond chemical vapour deposition (CVD). Parameters varied include the hydrocarbon (CH4 to reinforce the consensus view that H atom production during diamond CVD in a hot ®lament reactor arises

  12. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    electric fields generated by rf-induced fast ion loss will be utilized to drive poloidal rotationPREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMA Electric Fields on ICRF Waves C.K. Phillips, J.C. Hosea, M. Ono, and J.R. Wilson June 2001 #12;PPPL Reports

  13. TpPt(IV)Me(H)2 Forms a -CH4 Complex That Is Kinetically Resistant to Methane Liberation

    E-Print Network [OSTI]

    Keinan, Ehud

    Jolla, California 92037, and Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Technion City, Haifa 32000, Israel Received February 21, 2001 heating at 55-70 °C in CH3OH for several hours. However, when 1 was heated at the same temperatures

  14. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMAAccess: Interactive Statistics and Graphics for Plasma Physics Databases by W. Davis and D. Mastrovito October 2003 on the U.S. Department of Energy's Princeton Plasma Physics Laboratory Publications and Reports web site

  15. Communication: Spectroscopic characterization of an alkyl substituted Criegee intermediate syn-CH{sub 3}CHOO through pure rotational transitions

    SciTech Connect (OSTI)

    Nakajima, Masakazu; Endo, Yasuki, E-mail: endo@bunshi.c.u-tokyo.ac.jp [Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902 (Japan)] [Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902 (Japan)

    2014-01-07T23:59:59.000Z

    An alkyl-substituted Criegee intermediate syn-CH{sub 3}CHOO was detected in the gas phase through Fourier-transform microwave spectroscopy. Observed pure rotational transitions show a small splitting corresponding to the A/E components due to the threefold methyl internal rotation. The rotational constants and the barrier height of the hindered methyl rotation were determined to be A = 17?586.5295(15) MHz, B = 7133.4799(41) MHz, C = 5229.1704(40) MHz, and V{sub 3} = 837.1(17) cm{sup ?1}. High-level ab initio calculations which reproduce the experimentally determined values well indicate that the in-plane C–H bond in the methyl moiety is trans to the C–O bond, and other two protons are directed to the terminal oxygen atom for the most stable structure of syn-CH{sub 3}CHOO. The torsional barrier of the methyl top is fairly large in syn-CH{sub 3}CHOO, implying a significant interaction between the terminal oxygen and the protons of the methyl moiety, which may be responsible for the high production yields of the OH radical from energized alkyl-substituted Criegee intermediates.

  16. Gibbs and Helmholtz energies of formation of sI clathrate hydrates from CO$_2$, CH$_4$ and water

    E-Print Network [OSTI]

    K. S. Glavatskiy; T. J. H. Vlugt; S. Kjelstrup

    2013-07-26T23:59:59.000Z

    We determine thermodynamic stability conditions in terms of Helmholtz and Gibbs energies for sI clathrate hydrates with CH$_4$ and CO$_2$ at 278 K. Helmholtz energies are relevant for processing from porous rocks (constant volume), while Gibbs energies are relevant for processing from layers on the ocean floor (constant pressure). We define three steps leading to hydrate formation, and find Helmholtz energy differences from molecular simulations for two of them using grand-canonical Monte Carlo simulations at constant temperature and volume; while the third step was calculated from literature data. The Gibbs energy change for the same steps are also determined. From the variations in the total Helmholtz and Gibbs energies we suggest thermodynamic paths for exchange of CH$_4$ by CO$_2$ in the isothermal hydrate, for constant volume or pressure, respectively. We show how these paths for the mixed hydrate can be understood from single-component occupancy isotherms, where CO$_2$, but not CH$_4$, can distinguish between large and small cages. The strong preference for CH$_4$ for a range of compositions can be explained by these.

  17. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    energy sources. As fossil fuels become less and less available as an energy option, the transmission o fPREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMA. Availability This report is posted on the U.S. Department of Energy's Princeton Plasma Physics Laboratory

  18. Information Retrieval and Situation Theory Th.W.Ch. Huibers M. Lalmas and C.J. van Rijsbergen

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Information Retrieval and Situation Theory Th.W.Ch. Huibers M. Lalmas and C.J. van Rijsbergen of information has made it a matter of survival for companies to have at their disposal good information on a theory of information, Situation Theory, which provides a powerful arsenal of concepts, which is useful

  19. Information Retrieval and Situation Theory Th.W.Ch. Huibers M. Lalmas and C.J. van Rijsbergen

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Information Retrieval and Situation Theory Th.W.Ch. Huibers M. Lalmas and C.J. van Rijsbergen of information has made it a matter of survival for companies to have at their disposal good information should be based on a theory of information, Situation Theory, which provides a powerful arsenal

  20. Assessment of kinetic modeling for lean H2/CH4/O2/diluent flames at high pressures

    E-Print Network [OSTI]

    Ju, Yiguang

    : Hydrogen; Methane; Syngas; Flame speed; Chemical mechanism 1. Introduction The H2/O2 reaction system CO, CO2, H2O, CH4 and other small hydrocarbons (synthetic gas or "syngas") from coal or biomass gasification [2]. Typical syngas mixtures can contain significant amounts of small molecular weight

  1. 40 CFR Ch. I (7105 Edition)Pt. 194 1,2,4-Trichlorobenzene (Benzene, 1,2,4-

    E-Print Network [OSTI]

    36 40 CFR Ch. I (7­1­05 Edition)Pt. 194 Toxaphene 1,2,4-Trichlorobenzene (Benzene, 1,2,4- trichloro (Benzene, 1,3,5-trinitro-) Tris(1-aziridinyl)phosphine sulfide (Aziridine, 1,1,1phosphinothioylidyne

  2. Experimental and Theoretical Examination of C-CN and C-H Bond Activations of Acetonitrile Using Zerovalent Nickel

    E-Print Network [OSTI]

    Jones, William D.

    Experimental and Theoretical Examination of C-CN and C-H Bond Activations of Acetonitrile Using and density functional theory show that the reaction of acetonitrile with a zerovalent nickel bis -nitrile complex and the activation products. The lowest energy transition state is an 3 -acetonitrile

  3. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    /FW for on-axis current drive and a Lower Hybrid system for off-axis. Transport projections are presentedPREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMA agency thereof. Availability This report is posted on the U.S. Department of Energy's Princeton Plasma

  4. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    ://www.ntis.gov/ordering.htm #12;A Lower Hybrid Current Drive System for Alcator C-Mod. S. Bernabei, J.C. Hosea, D. Loesser, J, P. Woskov, PSFC, MIT. Abstract. A Lower Hybrid Current Drive system is being constructed jointlyPREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMA

  5. Induction of ovulation in deeply anestrous mares by different doses of a gonadotropin-releasing hormone analogue (CH 690030)

    E-Print Network [OSTI]

    Chen, Fang-Jane Jennifer

    1993-01-01T23:59:59.000Z

    A total of 54 mares in seasonal anestrous were assigned to 5 groups to receive implants containing one of the 5 doses (0, 0.9, 1.8, 3.6, and 5.4 mg/head in group order) of a GnRH analogue (CH 690030 or Goserelin) on January 28. Five mares...

  6. Mixing, Lyapunov instability, and the approach to equilibrium in a hard-sphere gas Ch. Dellago and H. A. Posch

    E-Print Network [OSTI]

    Dellago, Christoph

    Mixing, Lyapunov instability, and the approach to equilibrium in a hard-sphere gas Ch. Dellago, Austria Received 31 July 1996 We present maximum Lyapunov exponents 1 and related Kolmogorov time of a one-particle distribution. At low densities the Lyapunov time 1/ 1 is much smaller than

  7. PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073

    E-Print Network [OSTI]

    and granite mining operations in South Africa and Europe, has existed for more than 25 years. When miningPREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073 PRINCETON PLASMA on the U.S. Department of Energy's Princeton Plasma Physics Laboratory Publications and Reports web site

  8. Gas Hydrate Equilibria for CO2-N2 and CO2-CH4 gas mixtures Experimental studies and Thermodynamic Modelling

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Gas Hydrate Equilibria for CO2-N2 and CO2-CH4 gas mixtures ­ Experimental studies and Thermodynamic of experimental data on the phase equilibrium of gas hydrates in the presence of binary gas mixtures comprising CO of the gas phase as well as the hydrate phase without the need to sample the hydrate. The experimental

  9. Electrophilic, Ambiphilic, and Nucleophilic C-H bond Activation: Understanding the electronic continuum of C-H bond activation through transition-state and reaction pathway interaction energy decompositions

    SciTech Connect (OSTI)

    Ess, Daniel H; Goddard, William A; Periana, Roy A

    2010-01-01T23:59:59.000Z

    The potential energy and interaction energy profiles for metal- and metal?ligand-mediated alkane C?H bond activation were explored using B3LYP density functional theory (DFT) and the absolutely localized molecular orbital energy decomposition analysis (ALMO-EDA). The set of complexes explored range from late transition metal group 10 (Pt and Pd) and group 11 (Au) metal centers to group 7?9 (Ir, Rh, Ru, and W) metal centers as well as a group 3 Sc complex. The coordination geometries, electron metal count (d{sup 8}, d{sup 6}, d{sup 4}, and d{sup 0}), and ligands (N-heterocycles, O-donor, phosphine, and Cp*) are also diverse. Quantitative analysis using ALMO-EDA of both directions of charge-transfer stabilization (occupied to unoccupied orbital stabilization) energies between the metal?ligand fragment and the coordinated C?H bond in the transition state for cleavage of the C?H bond allows classification of C?H activation reactions as electrophilic, ambiphilic, or nucleophilic on the basis of the net direction of charge-transfer energy stabilization. This bonding pattern transcends any specific mechanistic or bonding paradigm, such as oxidative addition, ?-bond metathesis, or substitution. Late transition metals such as Au(III), Pt(II), Pd(II), and Rh(III) metal centers with N-heterocycle, halide, or O-donor ligands show electrophilically dominated reaction profiles with forward charge-transfer from the C?H bond to the metal, leading to more stabilization than reverse charge transfer from the metal to the C?H bond. Transition states and reaction profiles for d{sup 6} Ru(II) and Ir(III) metals with Tp and acac ligands were found to have nearly equal forward and reverse charge-transfer energy stabilization. This ambiphilic region also includes the classically labeled electrophilic cationic species Cp*(PMe{sub 3})Ir(Me). Nucleophilic character, where the metal to C?H bond charge-transfer interaction is most stabilizing, was found in metathesis reactions with W(II) and Sc(III) metal center complexes in reactions as well as late transition metal Ir(I) and Rh(I) pincer complexes that undergo C?H bond insertion. Comparison of pincer ligands shows that the PCP ligand imparts more nucleophilic character to an Ir metal center than a deprotonated PNP ligand. The PCP and POCOP ligands do not show a substantial difference in the electronics of C?H activation. It was also found that Rh(I) is substantially more nucleophilic than Ir(I). Lastly, as a qualitative approximation, investigation of transition-state fragment orbital energies showed that relative frontier orbital energy gaps correctly reflect electrophilic, ambiphilic, or nucleophilic charge-transfer stabilization patterns.

  10. Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C-H Bond Activation

    SciTech Connect (OSTI)

    Lewis, Jared; Bergman, Robert; Ellman, Jonathan

    2008-02-04T23:59:59.000Z

    Nitrogen heterocycles are present in many compounds of enormous practical importance, ranging from pharmaceutical agents and biological probes to electroactive materials. Direct funtionalization of nitrogen heterocycles through C-H bond activation constitutes a powerful means of regioselectively introducing a variety of substituents with diverse functional groups onto the heterocycle scaffold. Working together, our two groups have developed a family of Rh-catalyzed heterocycle alkylation and arylation reactions that are notable for their high level of functional-group compatibility. This Account describes their work in this area, emphasizing the relevant mechanistic insights that enabled synthetic advances and distinguished the resulting transformations from other methods. They initially discovered an intramolecular Rh-catalyzed C-2-alkylation of azoles by alkenyl groups. That reaction provided access to a number of di-, tri-, and tetracyclic azole derivatives. They then developed conditions that exploited microwave heating to expedite these reactions. While investigating the mechanism of this transformation, they discovered that a novel substrate-derived Rh-N-heterocyclic carbene (NHC) complex was involved as an intermediate. They then synthesized analogous Rh-NHC complexes directly by treating precursors to the intermediate [RhCl(PCy{sub 3}){sub 2}] with N-methylbenzimidazole, 3-methyl-3,4-dihydroquinazolein, and 1-methyl-1,4-benzodiazepine-2-one. Extensive kinetic analysis and DFT calculations supported a mechanism for carbene formation in which the catalytically active RhCl(PCy{sub 3}){sub 2} fragment coordinates to the heterocycle before intramolecular activation of the C-H bond occurs. The resulting Rh-H intermediate ultimately tautomerizes to the observed carbene complex. With this mechanistic information and the discovery that acid co-catalysts accelerate the alkylation, they developed conditions that efficiently and intermolecularly alkylate a variety of heterocycles, including azoles, azolines, dihydroquinazolines, pyridines, and quinolines, with a wide range of functionalized olefins. They demonstrated the utility of this methodology in the synthesis of natural products, drug candidates, and other biologically active molecules. In addition, they developed conditions to directly arylate these heterocycles with aryl halides. The initial conditions that used PCy{sub 3} as a ligand were successful only for aryl iodides. However, efforts designed to avoid catalyst decomposition led to the development of ligands based on 9-phosphabicyclo[4.2.1]nonane (Phoban) that also facilitated the coupling of aryl bromides. They then replicated the unique coordination environment, stability, and catalytic activity of this complex using the much simpler tetrahydrophosphepine ligands and developed conditions that coupled aryl bromides bearing diverse functional groups without the use of a glovebox or purified reagents. With further mechanistic inquiry, they anticipate that researchers will better understand the details of the aforementioned Rh-catalyzed C-H bond functionalization reactions, resulting in the design of more efficient and robust catalysts, expanded substrate scope, and new transformations.

  11. Thermochemical Insight into the Reduction of CO to CH3OH with [Re(CO)]+ and [Mn(CO)]+ Complexes

    SciTech Connect (OSTI)

    Wiedner, Eric S.; Appel, Aaron M.

    2014-05-22T23:59:59.000Z

    To gain insight into thermodynamic barriers for reduction of CO into CH3OH, free energies for reduction of [CpRe(PPh3)(NO)(CO)]+ into CpRe(PPh3)(NO)(CH2OH) have been determined from experimental measurements. Using model complexes, the free energies for the transfer of H+, H–, and e– have been determined. A pKa of 10.6 was estimated for [CpRe(PPh3)(NO)(CHOH)]+ by measuring the pKa for the analogous [CpRe(PPh3)(NO)(CMeOH)]+. The hydride donor ability (?G°H–) of CpRe(PPh3)(NO)(CH2OH) was estimated to be 58.0 kcal mol–1, based on calorimetry measurements of the hydride transfer reaction between CpRe(PPh3)(NO)(CHO) and [CpRe(PPh3)(NO)(CHOMe)]+ to generate the methylated analog, CpRe(PPh3)(NO)(CH2OMe). Cyclic voltammograms recorded on CpRe(PPh3)(NO)(CMeO), CpRe(PPh3)(NO)(CH2OMe), and [CpRe(PPh3)(NO)(CHOMe)]+ displayed either a quasireversible oxidation (neutral species) or reduction (cationic species). These potentials were used as estimates for the oxidation of CpRe(PPh3)(NO)(CHO) or CpRe(PPh3)(NO)(CH2OH), or the reduction of [CpRe(PPh3)(NO)(CHOH)]+. Combination of the thermodynamic data permits construction of three-dimensional free energy landscapes under varying conditions of pH and PH2. The free energy for H2 addition (?G°H2) to [CpRe(PPh3)(NO)(CO)]+ (+15 kcal mol–1) was identified as the most significant thermodynamic impediment for the reduction of CO. DFT computations indicate that ?G°H2 varies by only 4.3 kcal mol–1 across a series of [CpXRe(L)(NO)(CO)]+, while the experimental ?G°H– values for the analogous series of CpRe(PPh3)(NO)(CHO) varies by 12.9 kcal mol–1. The small range of ?G°H2 values is attributed to a minimal change in the C–O bond polarization upon modification of the ancillary ligands, as determined from the computed atomic charges. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

  12. Discovery of Interstellar Propylene (CH_2CHCH_3): Missing Links in Interstellar Gas-Phase Chemistry

    E-Print Network [OSTI]

    Marcelino, N; Agundez, M; Roueff, E; Gerin, M; Martín-Pintado, J; Mauersberger, R; Thum, C

    2007-01-01T23:59:59.000Z

    We report the discovery of propylene (also called propene, CH_2CHCH_3) with the IRAM 30-m radio telescope toward the dark cloud TMC-1. Propylene is the most saturated hydrocarbon ever detected in space through radio astronomical techniques. In spite of its weak dipole moment, 6 doublets (A and E species) plus another line from the A species have been observed with main beam temperatures above 20 mK. The derived total column density of propylene is 4 10^13 cm^-2, which corresponds to an abundance relative to H_2 of 4 10^-9, i.e., comparable to that of other well known and abundant hydrocarbons in this cloud, such as c-C_3H_2. Although this isomer of C_3H_6 could play an important role in interstellar chemistry, it has been ignored by previous chemical models of dark clouds as there seems to be no obvious formation pathway in gas phase. The discovery of this species in a dark cloud indicates that a thorough analysis of the completeness of gas phase chemistry has to be done.

  13. Discovery of Interstellar Propylene (CH_2CHCH_3): Missing Links in Interstellar Gas-Phase Chemistry

    E-Print Network [OSTI]

    N. Marcelino; J. Cernicharo; M. Agundez; E. Roueff; M. Gerin; J. Martin-Pintado; R. Mauersberger; C. Thum

    2007-07-09T23:59:59.000Z

    We report the discovery of propylene (also called propene, CH_2CHCH_3) with the IRAM 30-m radio telescope toward the dark cloud TMC-1. Propylene is the most saturated hydrocarbon ever detected in space through radio astronomical techniques. In spite of its weak dipole moment, 6 doublets (A and E species) plus another line from the A species have been observed with main beam temperatures above 20 mK. The derived total column density of propylene is 4 10^13 cm^-2, which corresponds to an abundance relative to H_2 of 4 10^-9, i.e., comparable to that of other well known and abundant hydrocarbons in this cloud, such as c-C_3H_2. Although this isomer of C_3H_6 could play an important role in interstellar chemistry, it has been ignored by previous chemical models of dark clouds as there seems to be no obvious formation pathway in gas phase. The discovery of this species in a dark cloud indicates that a thorough analysis of the completeness of gas phase chemistry has to be done.

  14. CH{sub 4}-CO{sub 2} reforming over Ni-substituted barium hexaaluminate catalysts

    SciTech Connect (OSTI)

    Gardner, Todd H. [U.S. DOE; Spivey, James J. [ORISE; Kugler, Edwin L.; Pakhare, Devendra

    2013-03-30T23:59:59.000Z

    A series of Ni-substituted barium hexaaluminate catalysts, Ba{sub 0.75}Ni{sub y}Al{sub 12?y}O{sub 19??} (y = 0.4, 0.6 and 1.0), were tested for CO{sub 2} reforming of CH{sub 4} at temperatures between 200 and 900 °C. Temperature programmed surface reaction results show that the reaction lights-off in a temperature range between 448 and 503 °C with a consistent decrease in light-off temperature with increasing Ni substitution. Isothermal runs performed at 900 °C show near equilibrium conversion and stable product concentrations for 18 h on all catalysts. Temperature programmed oxidation of the used catalysts show that the amount of carbon deposited on the catalyst increases with Ni substitution. High resolution XRD of the used Ba{sub 0.75}Ni{sub 0.4}Al{sub 11.6}O{sub 19??} catalyst shows a statistically significant contraction of the unit cell which is the result of NiO reduction from the lattice. XRD of the used catalyst also confirms the presence of graphitic carbon. XPS and ICP measurements of the as prepared catalysts show that lower levels of Ni substitution result in an increasing proportion of Ba at the surface.

  15. CH4-CO2 reforming over Ni-substituted barium hexaaluminate catalysts

    SciTech Connect (OSTI)

    Gardner, Todd H. [U.S. DOE; Spivey, James J. [Louisiana State University; Kugler, Edwin L. [WVU; Pakhare, Devendra [Louisiana State University

    2013-01-01T23:59:59.000Z

    A series of Ni-substituted barium hexaaluminate catalysts, Ba0.75NiyAl12?yO19?? (y = 0.4, 0.6 and 1.0), were tested for CO2 reforming of CH4 at temperatures between 200 and 900 ?C. Temperature programmed surface reaction results show that the reaction lights-off in a temperature range between 448 and 503 ?C with a consistent decrease in light-off temperature with increasing Ni substitution. Isothermal runs performed at 900 ?C show near equilibrium conversion and stable product concentrations for 18 h on all catalysts. Temperature programmed oxidation of the used catalysts show that the amount of carbon deposited on the catalyst increases with Ni substitution. High resolution XRD of the used Ba0.75Ni0.4Al11.6O19?? catalyst shows a statistically significant contraction of the unit cell which is the result of NiO reduction from the lattice. XRD of the used catalyst also confirms the presence of graphitic carbon. XPS and ICP measurements of the as prepared catalysts show that lower levels of Ni substitution result in an increasing proportion of Ba at the surface.

  16. OH and CH luminescence in opposed flow methane oxy-flames

    SciTech Connect (OSTI)

    De Leo, Maurizio; Saveliev, Alexei; Kennedy, Lawrence A. [Department of Mechanical and Industrial Engineering, University of Illinois at Chicago, Chicago, IL 60607 (United States); Zelepouga, Serguei A. [Gas Technology Institute, Des Plaines, IL 60018 (United States)

    2007-06-15T23:59:59.000Z

    Emission spectroscopy is a 2-D nonintrusive diagnostic technique that offers spatially resolved data for combustion optimization and control. The UV and visible chemiluminescence of the excited radicals CH(A{sup 2}{delta},B{sup 2}{sigma}{sup -}) and OH(A{sup 2}{sigma}{sup +}) is studied experimentally and numerically in opposed-flow diffusion flames of methane and oxygen-enriched air. The oxidized oxygen content is varied from 21 to 100% while the range of the studied strain rates spans from 20 to 40 s{sup -1}. The spectrally resolved imaging is obtained by two different methods: scattering through a grating monochromator and interposition of interference filters along the optical path. Absolute measured chemiluminescence intensities, coupled with a numerical model based on the opposed flow flame code, are used to evaluate the chemical kinetics of the excited species. The predictions of the selected model are in good agreement with the experimental data over the range of the studied flame conditions. (author)

  17. Solvent dependent branching between C-I and C-Br bond cleavage following 266 nm excitation of CH{sub 2}BrI

    SciTech Connect (OSTI)

    Anderson, Christopher P.; Spears, Kenneth G.; Wilson, Kaitlynn R.; Sension, Roseanne J. [Department of Chemistry and Department of Physics, University of Michigan, Ann Arbor, Michigan 48109 (United States)] [Department of Chemistry and Department of Physics, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2013-11-21T23:59:59.000Z

    It is well known that ultraviolet photoexcitation of halomethanes results in halogen-carbon bond cleavage. Each halogen-carbon bond has a dominant ultraviolet (UV) absorption that promotes an electron from a nonbonding halogen orbital (n{sub X}) to a carbon-halogen antibonding orbital (?*{sub C-X}). UV absorption into specific transitions in the gas phase results primarily in selective cleavage of the corresponding carbon-halogen bond. In the present work, broadband ultrafast UV-visible transient absorption studies of CH{sub 2}BrI reveal a more complex photochemistry in solution. Transient absorption spectra are reported spanning the range from 275 nm to 750 nm and 300 fs to 3 ns following excitation of CH{sub 2}BrI at 266 nm in acetonitrile, 2-butanol, and cyclohexane. Channels involving formation of CH{sub 2}Br + I radical pairs, iso-CH{sub 2}Br-I, and iso-CH{sub 2}I-Br are identified. The solvent environment has a significant influence on the branching ratios, and on the formation and stability of iso-CH{sub 2}Br-I. Both iso-CH{sub 2}Br-I and iso-CH{sub 2}I-Br are observed in cyclohexane with a ratio of ?2.8:1. In acetonitrile this ratio is 7:1 or larger. The observation of formation of iso-CH{sub 2}I-Br photoproduct as well as iso-CH{sub 2}Br-I following 266 nm excitation is a novel result that suggests complexity in the dissociation mechanism. We also report a solvent and concentration dependent lifetime of iso-CH{sub 2}Br-I. At low concentrations the lifetime is >4 ns in acetonitrile, 1.9 ns in 2-butanol and ?1.4 ns in cyclohexane. These lifetimes decrease with higher initial concentrations of CH{sub 2}BrI. The concentration dependence highlights the role that intermolecular interactions can play in the quenching of unstable isomers of dihalomethanes.

  18. DISCOVERY OF THE FIRST METHANOL (CH{sub 3}OH) MASER IN THE ANDROMEDA GALAXY (M31)

    SciTech Connect (OSTI)

    Sjouwerman, Lorant O.; Murray, Claire E. [National Radio Astronomy Observatory, P.O. Box 0, Lopezville Rd. 1001, Socorro, NM 87801 (United States); Pihlstroem, Ylva M. [Department of Physics and Astronomy, University of New Mexico, MSC07 4220, Albuquerque, NM 87131 (United States); Fish, Vincent L. [Massachusetts Institute of Technology, Haystack Observatory, Route 40, Westford, MA 01886 (United States); Araya, Esteban D., E-mail: lsjouwer@nrao.ed [Physics Department, Western Illinois University, 1 University Circle, Macomb, IL 61455 (United States)

    2010-12-01T23:59:59.000Z

    We present the first detection of a 6.7 GHz Class II methanol (CH{sub 3}OH) maser in the Andromeda galaxy (M31). The CH{sub 3}OH maser was found in a VLA survey during the fall of 2009. We have confirmed the methanol maser with the new EVLA, in operation since 2010 March, but were unsuccessful in detecting a water maser at this location. A direct application for this methanol maser is the determination of the proper motion of M31, such as was previously obtained with water masers in M33 and IC10. Unraveling the three-dimensional velocity of M31 would solve for the biggest unknown in the modeling of the dynamics and evolution of the Local Group of galaxies.

  19. The Breathing Orbital Valence Bond Method in Diffusion Monte Carlo: C-H Bond Dissociation ofAcetylene

    SciTech Connect (OSTI)

    Domin, D.; Braida, Benoit; Lester Jr., William A.

    2008-05-30T23:59:59.000Z

    This study explores the use of breathing orbital valence bond (BOVB) trial wave functions for diffusion Monte Carlo (DMC). The approach is applied to the computation of the carbon-hydrogen (C-H) bond dissociation energy (BDE) of acetylene. DMC with BOVB trial wave functions yields a C-H BDE of 132.4 {+-} 0.9 kcal/mol, which is in excellent accord with the recommended experimental value of 132.8 {+-} 0.7 kcal/mol. These values are to be compared with DMC results obtained with single determinant trial wave functions, using Hartree-Fock orbitals (137.5 {+-} 0.5 kcal/mol) and local spin density (LDA) Kohn-Sham orbitals (135.6 {+-} 0.5 kcal/mol).

  20. Characteristics of molecular hydrogen and CH* radicals in a methane plasma in a magnetically enhanced capacitive RF discharge

    SciTech Connect (OSTI)

    Avtaeva, S. V.; Lapochkina, T. M. [Kyrgyz-Russian Slavic University (Kyrgyzstan)

    2007-09-15T23:59:59.000Z

    The parameters of a methane-containing plasma in an asymmetric RF capacitive discharge in an external magnetic field were studied using optical emission spectroscopy. The power deposited in the discharge was 90 W and the gas pressure and magnetic field were varied in the ranges 1-5 Pa and 50-200 G, respectively. The vibrational and rotational temperatures of hydrogen molecules and CH* radicals were measured as functions of the magnetic field and methane pressure. The ratio between the densities of atomic and molecular hydrogen was estimated. The processes responsible for the excitation of molecular hydrogen and CH* radicals in a methane-containing plasma in an RF capacitive discharge are analyzed.

  1. Electron Transport Coefficients and Scattering Cross Sections in CH4, HBr and in Mixtures of He and Xe

    SciTech Connect (OSTI)

    Sasic, Olivera M. [Institute of Physics, POB 68, 11080 Belgrade (Serbia and Montenegro); Faculty of Transport and Traffic Engineering, Belgrade (Serbia and Montenegro)

    2006-12-01T23:59:59.000Z

    We have applied a standard swarm procedure in order to obtain electron scattering cross sections and transport coefficients that provide a data base for plasma modeling. In case of CH4 the dissociative excitation cross sections from binary collision experiments were renormalized by fitting the measured excitation coefficients with our calculations. In case of HBr we have produced a complete set of cross sections based on available data from the literature, with some extrapolations. We have also tested the cross sections in He-Xe mixtures and the application of Blanc's law and common mean energy procedure in calculating drift velocities in by comparison with recent measurements. Finally, a well tested Monte Carlo code was used in wide range of both DC and RF electric and magnetic fields in order to calculate a number of transport coefficients in case of CH4 and HBr.

  2. Supplementary Figure 1: ChR2-EYFP expression after fear conditioning recapitulates endogenous c-fos expression.

    E-Print Network [OSTI]

    Schnitzer, Mark

    -fos expression. The c-fos-tTA mice were injected with AAV9-TRE-ChR2-EYFP targeting the DG and kept on Dox for a month prior to training. Then, they were taken off Dox for two days to open a window of activity­positive cells do not overlap. (a) DG from experimental mice kept off Dox for two days and then subjected to fear

  3. Marc A. Meyers Y.Z.Tang, C.-H. Lu,T. Remington, S. Zhao, E. Hahn UCSD

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    Marc A. Meyers Y.Z.Tang, C.-H. Lu,T. Remington, S. Zhao, E. Hahn UCSD E. M. Bringa, C. Ruestes, U (transmission) Meyers,Wark, Remington, Ravichandran et al., Acta Mat, 2001 #12;0 100 200 300 400 500 600 1.0E+03 Diffraction during Shock Compression Meyers,Wark, Remington, Ravichandran et al., Acta Mat, 2001 (12)f = (1

  4. Resolving the Dusty Circumstellar Structure of the Enigmatic Symbiotic Star CH Cygni with the MMT Adaptive Optics System

    E-Print Network [OSTI]

    Beth A. Biller; Laird M. Close; Aigen Li; Massimo Marengo; John H. Bieging; Phil M. Hinz; William F. Hoffmann; Guido Brusa; Doug Miller

    2006-04-14T23:59:59.000Z

    We imaged the symbiotic star CH Cyg and two PSF calibration stars using the unique 6.5m MMT deformable secondary adaptive optics system. Our high-resolution (FWHM=0.3"), very high Strehl (98%+-2%) mid-infrared (9.8 and 11.7 um) images of CH Cyg allow us to probe finer length scales than ever before for this object. CH Cyg is significantly extended compared to our unresolved PSF calibration stars (Mu UMa and Alpha Her) at 9.8 and 11.7 um. We estimated the size of the extension by convolving a number of simple Gaussian models with the Mu UMa PSF and determining which model provided the best fit to the data. Adopting the Hipparcos distance for this object of 270 pc, we found a nearly Gaussian extension with a FWHM at 9.8 um of ~40.5+-2.7 AU (0.15+-0.01") and a FWHM at 11.7 um of 45.9+-2.7 AU (0.17+-0.01"). After subtracting out the Gaussian component of the emission (convolved with our PSF), we found a faint \\~0.7" asymmetric extension which peaks in flux ~0.5" north of the stars. This extension is roughly coincident with the northern knotlike feature seen in HST WFPC2 images obtained in 1999.

  5. New way of healing : experienced counsellors’ perceptions of the influence of ch’i-related exercises on counselling practice in Taiwan 

    E-Print Network [OSTI]

    Liou, Chin-Ping

    2014-07-01T23:59:59.000Z

    This study examines how Taiwanese senior counsellors with substantial experience of ch’i-related exercise (CRE) perceived the influence of their regular CRE on their counselling practice. I am interested in the perceived influence of CRE on both...

  6. A Highly Reactive Mononuclear Non-Heme Manganese(IV)?Oxo Complex That Can Activate the Strong C?H Bonds of Alkanes

    SciTech Connect (OSTI)

    Wu, Xiujuan; Seo, Mi Sook; Davis, Katherine M.; Lee, Yong-Min; Chen, Junying; Cho, Kyung-Bin; Pushkar, Yulia N.; Nam, Wonwoo (Ewha); (Purdue)

    2012-03-15T23:59:59.000Z

    A mononuclear non-heme manganese(IV)-oxo complex has been synthesized and characterized using various spectroscopic methods. The Mn(IV)-oxo complex shows high reactivity in oxidation reactions, such as C-H bond activation, oxidations of olefins, alcohols, sulfides, and aromatic compounds, and N-dealkylation. In C-H bond activation, the Mn(IV)-oxo complex can activate C-H bonds as strong as those in cyclohexane. It is proposed that C-H bond activation by the non-heme Mn(IV)-oxo complex does not occur via an oxygen-rebound mechanism. The electrophilic character of the non-heme Mn(IV)-oxo complex is demonstrated by a large negative {rho} value of {approx}4.4 in the oxidation of para-substituted thioanisoles.

  7. Spatial and temporal patterns of CO[subscript 2] and CH[subscript 4] fluxes in China's croplands in response to multifactor environmental changes

    E-Print Network [OSTI]

    REN, WEI

    The spatial and temporal patterns of CO[subscript 2] and CH[subscript 4] fluxes in China's croplands were investigated and attributed to multifactor environmental changes using the agricultural module of the Dynamic Land ...

  8. Room Temperature Copper(II)-Catalyzed Oxidative Cyclization of Enamides to 2,5-Disubstituted Oxazoles via Vinylic C–H Functionalization

    E-Print Network [OSTI]

    Cheung, Chi Wai

    A copper(II)-catalyzed oxidative cyclization of enamides to oxazoles via vinylic C–H bond functionalization at room temperature is described. Various 2,5-disubstituted oxazoles bearing aryl, vinyl, alkyl, and heteroaryl ...

  9. The Reaction of bis(1,2,4-tri-t-butylcyclopentadienyl)ceriumbenzyl, Cp'2CeCH2Ph with Methylhalides: a Metathesis Reaction that does not proceed by a Metathesis Transition State

    SciTech Connect (OSTI)

    Werkema, Evan; Andersen, Richard; Maron, Laurent; Eisenstein, Odile

    2009-09-02T23:59:59.000Z

    The experimental reaction between [1,2,4-(Me3C)3C5H2]2CeCH2Ph and CH3X, X = F, Cl, Br, and I, yields the metathetical exchange products, [1,2,4-(Me3C)3C5H2]2CeX and CH3CH2Ph. The reaction is complicated by the equilibrium between the benzyl derivative and the metallacycle [[1,2,4-(Me3C)3C5H2] [(Me3C)2C5H2C(CH3)2CH2]Ce, plus toluene since the metallacycle reacts with CH3X. Labelling studies show that the methyl group of the methylhalide is transferred intact to the benzyl group. The mechanism, as revealed by DFT calculations on (C5H5)2CeCH2Ph and CH3F, does not proceed by way of a four-center mechanism, (sigma-bond metathesis) but a lower barrier process involves a haptotropic shift of the Cp2Ce fragment so that at the transition state the para-carbon of the benzene ring is attached to the Cp2Ce fragment while the CH2 fragment of the benzyl group attacks CH3F that is activated by coordination to the metal ion. As a result the mechanism is classified as an associative interchange process.

  10. Anisotropic contribution to the van der Waals and the Casimir-Polder energies for CO$_2$ and CH$_4$ molecules near surfaces and thin films

    E-Print Network [OSTI]

    Thiyam, Priyadarshini; Shajesh, K V; Persson, Clas; Schaden, Martin; Brevik, Iver; Parsons, Drew F; Milton, Kimball A; Malyi, Oleksandr I; Boström, Mathias

    2015-01-01T23:59:59.000Z

    In order to understand why carbon dioxide (CO$_2$) and methane (CH$_4$) molecules interact differently with surfaces, we investigate the Casimir-Polder energy of a linearly polarizable CO$_2$ molecule and an isotropically polarizable CH$_4$ molecule in front of an atomically thin gold film and an amorphous silica slab. We quantitatively analyze how the anisotropy in the polarizability of the molecule influences the van der Waals contribution to the binding energy of the molecule.

  11. Intermolecular CH bond activation of benzene and pyridines by a vanadium(III) alkylidene including a stepwise conversion of benzene to

    E-Print Network [OSTI]

    McQuade, D. Tyler

    Intermolecular C­H bond activation of benzene and pyridines by a vanadium(III) alkylidene including a stepwise conversion of benzene to a vanadium-benzyne complex Jose G. Andino,a Uriah J. Kilgore,a Maren Pink of benzene and pyridine is observed with (PNP)V(CH2tBu)2 (1), and in the case of benzene, the formation

  12. Free Choice and Contextually Permitted Actions F.Dignum \\Lambda J.J.Ch.Meyer y R.J.Wieringa z

    E-Print Network [OSTI]

    Dignum, Frank

    Free Choice and Contextually Permitted Actions F.Dignum \\Lambda J.­J.Ch.Meyer y R.J.Wieringa z, The Netherlands, e­mail:roelw@cs.vu.nl This research of J.­J.Ch.Meyer and R.J.Wieringa is partially supported between actions and states, McCarty [McC83], Khosla and Maibaum [KM87] and Meyer [Mey88] inde­ pendently

  13. Infrared absorption of gaseous CH{sub 2}BrOO detected with a step-scan Fourier-transform absorption spectrometer

    SciTech Connect (OSTI)

    Huang, Yu-Hsuan [Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Lee, Yuan-Pern, E-mail: yplee@mail.nctu.edu.tw [Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China)

    2014-10-28T23:59:59.000Z

    CH{sub 2}BrOO radicals were produced upon irradiation, with an excimer laser at 248 nm, of a flowing mixture of CH{sub 2}Br{sub 2} and O{sub 2}. A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to record temporally resolved infrared (IR) absorption spectra of reaction intermediates. Transient absorption with origins at 1276.1, 1088.3, 961.0, and 884.9 cm{sup ?1} are assigned to ?{sub 4} (CH{sub 2}-wagging), ?{sub 6} (O–O stretching), ?{sub 7} (CH{sub 2}-rocking mixed with C–O stretching), and ?{sub 8} (C–O stretching mixed with CH{sub 2}-rocking) modes of syn-CH{sub 2}BrOO, respectively. The assignments were made according to the expected photochemistry and a comparison of observed vibrational wavenumbers, relative IR intensities, and rotational contours with those predicted with the B3LYP/aug-cc-pVTZ method. The rotational contours of ?{sub 7} and ?{sub 8} indicate that hot bands involving the torsional (?{sub 12}) mode are also present, with transitions 7{sub 0}{sup 1}12{sub v}{sup v} and 8{sub 0}{sup 1}12{sub v}{sup v}, v = 1–10. The most intense band (?{sub 4}) of anti-CH{sub 2}BrOO near 1277 cm{sup ?1} might have a small contribution to the observed spectra. Our work provides information for directly probing gaseous CH{sub 2}BrOO with IR spectroscopy, in either the atmosphere or laboratory experiments.

  14. C-H surface diamond field effect transistors for high temperature (400?°C) and high voltage (500?V) operation

    SciTech Connect (OSTI)

    Kawarada, H., E-mail: kawarada@waseda.jp [Faculty of Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Institute of Nano-Science and Nano-Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Kagami Memorial Laboratory for Material Science and Technology, Waseda University, Shinjuku, Tokyo 169-0051 (Japan); Tsuboi, H.; Naruo, T.; Yamada, T.; Xu, D.; Daicho, A.; Saito, T. [Faculty of Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Hiraiwa, A. [Institute of Nano-Science and Nano-Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan)

    2014-07-07T23:59:59.000Z

    By forming a highly stable Al{sub 2}O{sub 3} gate oxide on a C-H bonded channel of diamond, high-temperature, and high-voltage metal-oxide-semiconductor field-effect transistor (MOSFET) has been realized. From room temperature to 400?°C (673?K), the variation of maximum drain-current is within 30% at a given gate bias. The maximum breakdown voltage (V{sub B}) of the MOSFET without a field plate is 600?V at a gate-drain distance (L{sub GD}) of 7 ?m. We fabricated some MOSFETs for which V{sub B}/L{sub GD}?>?100?V/?m. These values are comparable to those of lateral SiC or GaN FETs. The Al{sub 2}O{sub 3} was deposited on the C-H surface by atomic layer deposition (ALD) at 450?°C using H{sub 2}O as an oxidant. The ALD at relatively high temperature results in stable p-type conduction and FET operation at 400?°C in vacuum. The drain current density and transconductance normalized by the gate width are almost constant from room temperature to 400?°C in vacuum and are about 10 times higher than those of boron-doped diamond FETs.

  15. Adsorption Kinetics of CO2, CH4, and their Equimolar Mixture on Coal from the Black Warrior Basin, West-Central Alabama

    SciTech Connect (OSTI)

    Gruszkiewicz, Miroslaw {Mirek} S [ORNL; Naney, Michael {Mike} T [ORNL; Blencoe, James {Jim} G [ORNL; Cole, David R [ORNL; Pashin, Jack C. [Geological Survey of Alabama; Carroll, Richard E. [Geological Survey of Alabama

    2009-01-01T23:59:59.000Z

    Laboratory experiments were conducted to investigate the adsorption kinetic behavior of pure and mixed gases (CO2, CH4, approximately equimolar CO2 + CH4 mixtures, and He) on a coal sample obtained from the Black Warrior Basin at the Littleton Mine (Twin Pine Coal Company), Jefferson County, west-central Alabama. The sample was from the Mary Lee coal zone of the Pottsville Formation (Lower Pennsylvanian). Experiments with three size fractions (45-150 m, 1-2 mm, and 5-10 mm) of crushed coal were performed at 40 C and 35 C over a pressure range of 1.4 6.9 MPa to simulate coalbed methane reservoir conditions in the Black Warrior Basin and provide data relevant for enhanced coalbed methane recovery operations. The following key observations were made: (1) CO2 adsorption on both dry and water-saturated coal is much more rapid than CH4 adsorption; (2) water saturation decreases the rates of CO2 and CH4 adsorption on coal surfaces, but it appears to have minimal effects on the final magnitude of CO2 or CH4 adsorption if the coal is not previously exposed to CO2; (3) retention of adsorbed CO2 on coal surfaces is significant even with extreme pressure cycling; and (4) adsorption is significantly faster for the 45-150 m size fraction compared to the two coarser fractions.

  16. S-OO bond dissociation energies and enthalpies of formation of the thiomethyl peroxyl radicals CH{sub 3}S(O){sub n}OO (n=0,1,2)

    SciTech Connect (OSTI)

    Salta, Zoi; Kosmas, Agnie Mylona [Department of Chemistry, University of Ioannina, Ioannina 45110 (Greece); Lesar, Antonija [Department of Physical and Organic Chemistry, Jožef Stefan Institute, Jamova 39, SI-1000, Ljubljana (Slovenia)

    2014-10-06T23:59:59.000Z

    Optimized geometries, S-OO bond dissociation energies and enthalpies of formation for a series of thiomethyl peroxyl radicals are investigated using high level ab initio and density functional theory methods. The results show that the S-OO bond dissociation energy is largest in the methylsulfonyl peroxyl radical, CH{sub 3}S(O){sub 2}OO, which contains two sulfonic type oxygen atoms followed by the methylthiyl peroxyl radical, CH{sub 3}SOO. The methylsulfinyl peroxyl radical, CH{sub 3}S(O)OO, which contains only one sulfonic type oxygen shows the least stability with regard to dissociation to CH{sub 3}S(O)+O{sub 2}. This stabilization trend is nicely reflected in the variations of the S-OO bond distance which is found to be shortest in CH{sub 3}S(O){sub 2}OO and longest in CH{sub 3}S(O)OO.

  17. KEN SALAZAR, Secretary U.S. Geological Survey

    E-Print Network [OSTI]

    R. Burns; Daniel T. Snyder; Jonathan V. Haynes; Michael S. Waibel; Marcia K. Mcnutt

    the trend lines of spring median water levels for select groups of wells with similar hydraulic response in the Umatilla Basin, Oregon (East-West groups). (See figures 10 and 11B, respectively, in the report.) Center foreground: Map showing distribution of groundwater-level trends in the Columbia Plateau Regional Aquifer System for the period 1968–2009. Red circles indicate groundwater-level declines, yellow circles indicate little or no change in groundwater levels, and blue circles indicate groundwater-level rises. Circle size is representative of magnitude of change. (See figure 8 in the report.) Lower right: Map showing select groups of wells with similar hydraulic response within portions of the Palouse Slope and the Columbia Basin Ground Water Management Area, Washington. Hydrographs showing the trend lines of spring median water levels for groups of wells with similar hydraulic response in the vicinity of the Palouse Slope and the Columbia Basin Ground Water Management Area, Washington (Eastern Flowpath groups).

  18. Book review Functional Metabolism: Regulation and Adaptation, Ken-

    E-Print Network [OSTI]

    Storey, Kenneth B.

    of this idea was promulgated by August Krogh, it was Hochachka and his contemporaries who put meat to this idea of animals that developed the ability to survive anoxia, cold and freezing, estivation principles. Most striking of these is the metabolic commonalities observed, for example, between freeze

  19. GB Seniority Jan 14 Ken Macdonald QC Warden

    E-Print Network [OSTI]

    Wallace, Mark

    and Tutor in Human Sciences Dr Jane Griffiths Placito Fellow and Tutor in English Dr Eveline Ramaekers

  20. West Ken-Lark, Florida: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown ofNationwideWTED JumpHills, New York: Energy Resources JumpNorth

  1. Unusual defect physics in CH{sub 3}NH{sub 3}PbI{sub 3} perovskite solar cell absorber

    SciTech Connect (OSTI)

    Yin, Wan-Jian, E-mail: wanjian.yin@utoledo.edu; Shi, Tingting; Yan, Yanfa, E-mail: yanfa.yan@utoledo.edu [Department of Physics and Astronomy and Center for Photovoltaics Innovation and Commercialization, The University of Toledo, Toledo, Ohio 43606 (United States)

    2014-02-10T23:59:59.000Z

    Thin-film solar cells based on Methylammonium triiodideplumbate (CH{sub 3}NH{sub 3}PbI{sub 3}) halide perovskites have recently shown remarkable performance. First-principle calculations show that CH{sub 3}NH{sub 3}PbI{sub 3} has unusual defect physics: (i) Different from common p-type thin-film solar cell absorbers, it exhibits flexible conductivity from good p-type, intrinsic to good n-type depending on the growth conditions; (ii) Dominant intrinsic defects create only shallow levels, which partially explain the long electron-hole diffusion length and high open-circuit voltage in solar cell. The unusual defect properties can be attributed to the strong Pb lone-pair s orbital and I p orbital antibonding coupling and the high ionicity of CH{sub 3}NH{sub 3}PbI{sub 3}.

  2. Complete Phase I Tests As Described in the Multi-lab Test Plan for the Evaluation of CH3I Adsorption on AgZ

    SciTech Connect (OSTI)

    Bruffey, S. H. [ORNL; Jubin, R. T. [ORNL

    2014-09-30T23:59:59.000Z

    Silver-exchanged mordenite (AgZ) has been identified as a potential sorbent for iodine present in the off-gas streams of a used nuclear fuel reprocessing facility. In such a facility, both elemental and organic forms of iodine are released from the dissolver in gaseous form. These species of iodine must be captured with high efficiency for a facility to avoid radioactive iodine release above regulatory limits in the gaseous effluent of the plant. Studies completed at Idaho National Laboratory (INL) examined the adsorption of organic iodine in the form of CH3I by AgZ. Upon breakthrough of the feed gas through the sorbent bed, elemental iodine was observed in the effluent stream, despite the fact that the only source of iodine in the system was the CH3I in the feed gas.1 This behavior does not appear to have been reported previously nor has it been independently confirmed. Thus, as a result of these prior studies, multiple knowledge gaps relating to the adsorption of CH3I by AgZ were identified, and a multi-lab test plan, including Oak Ridge National Laboratory (ORNL), INL, Pacific Northwest National Laboratory (PNNL), and Sandia National Laboratories, was formulated to address each in a systematic way.2 For this report, the scope of work for ORNL was further narrowed to three thin-bed experiments that would characterize CH3I adsorption onto AgZ in the presence of water, NO, and NO2. Completion of these three-thin bed experiments demonstrated that organic iodine in the form of CH3I was adsorbed by reduced silver mordenite (Ag0Z) to a 50% higher loading than that of I2 when adsorbed from a dry air stream. Adsorption curves suggest different adsorption mechanisms for I2 and CH3I. In the presence of NO and NO2 gas, the loading of CH3I onto Ag0Z is suppressed and may be reversible. Further, the presence of NO and NO2 gas appears to oxidize CH3I to I2; this is indicated by an adsorption curve similar to that of I2 on Ag0Z. Finally, the loss of organic iodine loading capacity by Ag0Z in the presence of NOx is unaffected by the addition of water vapor to the gas stream; no marked additional loss in capacity or retention was observed.

  3. The CH3CHOO `Criegee Intermediate' and its anion: Isomers, Infrared spectra, and W3-F12 energetics

    E-Print Network [OSTI]

    Kettner, Marcus; McKinley, Allan; Wild, Duncan

    2015-01-01T23:59:59.000Z

    For the CH3CHOO Criegee intermediates (ethanal-oxide) and analogous anions, we obtain heats of formations and electron affinities at CCSDT(Q)/CBS level of theory by means of the high-level W3-F12 thermochemical protocol. The electron affinities amount to 0.20 eV and 0.35 eV for the cis and trans isomer, respectively. Neutral cis and trans isomers are separated by 14.1 kJ/mol, the anions are almost isoenergetic (0.4 kJ/mol separation). Harmonic vibrational frequencies are presented at CCSD(T)/aug'-cc-pVTZ level of theory. Since the synthesis of these species in gas-phase experiments might be possible in the near future, we include a predicted photoelectron spectrum.

  4. In situ quantification of CH4 bubbling events from a peat soil using a new infrared laser spectrometer Sbastien Gogo Christophe Guimbaud Fatima Laggoun-Dfarge Valry Catoire Claude Robert

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 In situ quantification of CH4 bubbling events from a peat soil using a new infrared laser in May 2009, in Sphagnum and Betula plots, and in a wet artificially bared peat area with Eriophorum of increased CH4 production and accumulation in peat. In May, bubbling was higher at nighttime (65.5%) than

  5. Oxidation Kinetics of Pure and Blended Methyl Octanoate/n-Nonane/Methylcyclohexane: Measurements and Modeling of OH*/CH* Chemiluminescence, Ignition Delay Times and Laminar Flame Speeds

    E-Print Network [OSTI]

    Rotavera, Brandon Michael

    2012-07-16T23:59:59.000Z

    and for the three constituents were obtained by monitoring excited-state OH or CH transitions, A2Epsilon+ -> X2Pi or A2Delta -> X2Pi, respectively, behind reflected shock waves using a heated shock tube facility. Dilute conditions of 99% Ar (vol.) were maintained...

  6. Research by BNL investigators was performed under the auspices of the U.S. Department of Energy under Contract No. DE-AC02-98CH10886.

    E-Print Network [OSTI]

    of Energy under Contract No. DE-AC02-98CH10886. BNL-60909 Use of five zone tracer model to diagnose. Goodrich , and D. Leonard American Industrial Hygiene Conference & Exposition, Kansas City, May 20-26, 1995 was measured at 12.9 ± 1.6 ACH. The affected clinical Laboratory area was noted to be most negative relative

  7. Kinetic Study in a Microwave-Induced Plasma Afterglow of the Cu(2S) Atom Reaction with CH3Cl in the Temperature Range 389-853 K

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    carried out in a fast-flow reactor. The gas phase copper atoms were generated using the microwave chloride was carried out in a fast-flow reactor. The microwave-induced plasma (MIP) afterglow technique will be repeated here. The Cu + CH3Cl reaction has been investigated in a quartz fast-flow reactor with an internal

  8. Research by BNL investigators was performed under the auspices of the U.S. Department of Energy under Contract No. DE-AC02-98CH10886.

    E-Print Network [OSTI]

    of Energy under Contract No. DE-AC02-98CH10886. BNL-63565 THE PHOTOCHEMICAL FORMATION OF OZONE: RESULTS FROM UV measurements from an Eppley radiometer. For j(NO2) levels greater than 0.005 s-1 the gross O3 production rate observed in the air masses passing the site averaged 38 ppbvh-1 , but were highly variable

  9. Measurement and modeling of Ar/H2/CH4 arc jet discharge chemical vapor deposition reactors II: Modeling of the spatial dependence of expanded

    E-Print Network [OSTI]

    Bristol, University of

    and used to deposit thin films of polycrystalline diamond. This reactor has been the subject of many prior of micro- and nanocrystalline diamond and diamondlike carbon films. The model incorporates gas activation-containing radical species incident on the growing diamond surface C atoms and CH radicals within this reactor

  10. Deproto-metallation using mixed lithium-zinc and lithium-copper bases and computed CH acidity of 2-substituted quinolines

    E-Print Network [OSTI]

    Boyer, Edmond

    Deproto-metallation using mixed lithium-zinc and lithium-copper bases and computed CH acidity of 2 corresponding iodo derivatives or 2-chlorophenyl ketones using the lithium-zinc or the lithium using the lithium-zinc base. With 3-pyridyl, 2-furyl and 2-thienyl substituents, the reaction took place

  11. AgriculturAl lAnd ApplicAtion of Biosolids in VirginiA: production And chArActeristics of Biosolids

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    AgriculturAl lAnd ApplicAtion of Biosolids in VirginiA: production And chArActeristics of Biosolids to permit these materials to be safely land-applied. The term was introduced by the wastewater treatment treatment of domestic wastewater. Biosolids comprise the solids that are removed from the wastewater

  12. Sulfur addition to microwave activated CH4/CO2 gas mixtures used for diamond CVD: growth studies and gas phase investigations

    E-Print Network [OSTI]

    Bristol, University of

    with H2S additions of 0­5000 ppm to a 51% CH4/49% CO2 plasma, with growth carried out for two different to deteriorate with increased H2S addition, as investigated by scanning electron microscopy (SEM) and laser Raman spectroscopy (LRS). H2S addition also appears to alter the resistivity of films, as measured by the four

  13. Universities CoUnCil on Water resoUrCes JoUrnal of Contemporary Water researCh & edUCation

    E-Print Network [OSTI]

    Wolf, Aaron

    than one billion people already lack access to safe drinking water (Gleick 1999; Loftus 2009) and more than 2.4 billion lack access to sanitation worldwide (World Health Organization 2000). Globally, waterUniversities CoUnCil on Water resoUrCes JoUrnal of Contemporary Water researCh & edUCation iss

  14. Temporal and spatial evolution of laser ablated plasma from YBa,Ch.& S. S. Harilal, P. Radhakrishnan, V. P. N. Nampoori, and C. P. G. Vallabhan

    E-Print Network [OSTI]

    Harilal, S. S.

    to local heating and drilling, the sample was rotated about an axis parallel to the laser beam. LaserTemporal and spatial evolution of laser ablated plasma from YBa,Ch.& S. S. Harilal, P. Radhakrishnan, V. P. N. Nampoori, and C. P. G. Vallabhan Laser Division, Department of Physics, Cochin

  15. J. Phys. Chem. 1995, 99, 1633-1636 1633 Negative Ion Zero Electron Kinetic Energy Spectroscopy of I-*CH3I

    E-Print Network [OSTI]

    Neumark, Daniel M.

    J. Phys. Chem. 1995, 99, 1633-1636 1633 Negative Ion Zero Electron Kinetic Energy Spectroscopy of I: October IO,1994@ The negative ion zero electron kinetic energy (ZEKE) spectrum of I-H3I is presented ion zero electron kinetic energy (ZEKE) spectrum of I-CH3I in which we observe that the neutralcomplex

  16. Transferring oxygen isotopes to 1,2,4-benzotriazine 1-oxides forming the corresponding 1,4-dioxides by using the HOF$CH3CN complex

    E-Print Network [OSTI]

    Gates, Kent. S.

    Transferring oxygen isotopes to 1,2,4-benzotriazine 1-oxides forming the corresponding 1,4-dioxides Available online 14 August 2012 Keywords: Oxygen transfer 18 O isotope Tirapazamine HOF$CH3CN F2/N2 N is their ability to capitalize on the low oxygen (hypoxic) environment found in many solid tumors. The lead

  17. Prepared for the U.S. Department of Energy under Contract DE-AC02-76CH03073. Princeton Plasma Physics Laboratory

    E-Print Network [OSTI]

    , California 92186 3 Columbia University, New York, New York 10027 Abstract Plasma shape control using realPrepared for the U.S. Department of Energy under Contract DE-AC02-76CH03073. Princeton Plasma is posted on the U.S. Department of Energy's Princeton Plasma Physics Laboratory Publications and Reports

  18. Time-Resolved Quantitative Measurement of OH HO2 and CH2O in Fuel Oxidation Reactions by High Resolution IR Absorption Spectroscopy.

    SciTech Connect (OSTI)

    Huang, Haifeng; Rotavera, Brandon; Taatjes, Craig A.

    2014-08-01T23:59:59.000Z

    Combined with a Herriott-type multi-pass slow flow reactor, high-resolution differential direct absorption spectroscopy has been used to probe, in situ and quantitatively, hydroxyl (OH), hydroperoxy (HO 2 ) and formaldehyde (CH 2 O) molecules in fuel oxidation reactions in the reactor, with a time resolution of about 1 micro-second. While OH and CH 2 O are probed in the mid-infrared (MIR) region near 2870nm and 3574nm respectively, HO 2 can be probed in both regions: near-infrared (NIR) at 1509nm and MIR at 2870nm. Typical sensitivities are on the order of 10 10 - 10 11 molecule cm -3 for OH at 2870nm, 10 11 molecule cm -3 for HO 2 at 1509nm, and 10 11 molecule cm -3 for CH 2 O at 3574nm. Measurements of multiple important intermediates (OH and HO 2 ) and product (CH 2 O) facilitate to understand and further validate chemical mechanisms of fuel oxidation chemistry.

  19. BENDIX SYSTEMS DIVISION ANN A R8 oR, M1CH NO. REV.NO. Solar Wind Programming for

    E-Print Network [OSTI]

    Rathbun, Julie A.

    experiment program decommutates its own data, organizes it, processes it, and prepares it for output. Specifically, for Solar Wind, there is provision (using sense switches) for allowing or inhibiting the outputBENDIX SYSTEMS DIVISION ANN A R8 oR, M1CH NO. REV.NO. Solar Wind Programming for I I DPS 2000

  20. Research by BNL investigators was performed under the auspices of the U.S. Department of Energy under Contract No. DE-AC02-98CH10886.

    E-Print Network [OSTI]

    of Energy under Contract No. DE-AC02-98CH10886. BNL-61220 The Whitehouse Effect: Shortwave radiative forcing and Visual Air Quality, Snowbird, UT, Sept. 26-30, pp. 403-409, Air and Waste Management Association-atmosphere system both directly, by scattering light and, indirectly, by increasing the reflectivity of clouds

  1. Research by BNL investigators was performed under the auspices of the U.S. Department of Energy under Contract No. DE-AC02-98CH10886.

    E-Print Network [OSTI]

    suspended in air) scatter solar radiation and also serve as nuclei of cloud droplets. Industrial activities of Energy under Contract No. DE-AC02-98CH10886. BNL-64585 (Abstract) THE WHITEHOUSE EFFECT: CLIMATIC EFFECTS of planetary albedo under cloud-free conditions and also to greater concentration of cloud droplets, resulting

  2. CH2M Hill Hanford Group, Inc. Standards and Requirements Identification Document (SRID) Requirements Management System and Requirements Specification

    SciTech Connect (OSTI)

    JOHNSON, A.L.

    2000-11-30T23:59:59.000Z

    The current Tank Farm Contractor (TFC) for the U. S. Department of Energy, Office of River Protection (ORP), River Protection Project (RPP), CH2M Hill Hanford Group, Inc. (CHG), will use a computer based requirements management system. The system will serve as a tool to assist in identifying, capturing, and maintaining the Standards/Requirements Identification Document (S/RID) requirements and links to implementing procedures and other documents. By managing requirements as one integrated set, CHG will be able to carry out its mission more efficiently and effectively. CHG has chosen the Dynamic Object Oriented Requirements System (DOORS{trademark}) as the preferred computer based requirements management system. Accordingly, the S/RID program will use DOORS{trademark}. DOORS{trademark} will replace the Environmental Requirements Management Interface (ERMI) system as the tool for S/RID data management. The DOORS{trademark} S/RID test project currently resides on the DOORSTM test server. The S/RID project will be migrated to the DOORS{trademark} production server. After the migration the S/RID project will be considered a production project and will no longer reside on the test server.

  3. Thermogravimetric Analysis of Modified Hematite by Methane (CH{sub 4}) for Chemical-Looping Combustion: A Global Kinetics Mechanism

    SciTech Connect (OSTI)

    Monazam, Esmail R.; Breault, Ronald W.; Siriwardane, Ranjani; Miller, Duane D.

    2013-10-01T23:59:59.000Z

    Iron oxide (Fe{sub 2}O{sub 3}) or in its natural form (hematite) is a potential material to capture CO{sub 2} through the chemical-looping combustion (CLC) process. It is known that magnesium (Mg) is an effective methyl cleaving catalyst and as such it has been combined with hematite to assess any possible enhancement to the kinetic rate for the reduction of Fe{sub 2}O{sub 3} with methane. Therefore, in order to evaluate its effectiveness as a hematite additive, the behaviors of Mg-modified hematite samples (hematite –5% Mg(OH){sub 2}) have been analyzed with regard to assessing any enhancement to the kinetic rate process. The Mg-modified hematite was prepared by hydrothermal synthesis. The reactivity experiments were conducted in a thermogravimetric analyzer (TGA) using continuous stream of CH{sub 4} (5, 10, and 20%) at temperatures ranging from 700 to 825 {degrees}C over ten reduction cycles. The mass spectroscopy analysis of product gas indicated the presence of CO{sub 2}, H{sub 2}O, H{sub 2} and CO in the gaseous product. The kinetic data at reduction step obtained by isothermal experiments could be well fitted by two parallel rate equations. The modified hematite samples showed higher reactivity as compared to unmodified hematite samples during reduction at all investigated temperatures.

  4. THE DETECTION OF INTERSTELLAR ETHANIMINE (CH{sub 3}CHNH) FROM OBSERVATIONS TAKEN DURING THE GBT PRIMOS SURVEY

    SciTech Connect (OSTI)

    Loomis, Ryan A.; Zaleski, Daniel P.; Steber, Amanda L.; Neill, Justin L.; Muckle, Matthew T.; Harris, Brent J.; Pate, Brooks H. [Department of Chemistry, University of Virginia, McCormick Road, Charlottesville, VA 22904 (United States); Hollis, Jan M. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Jewell, Philip R.; Remijan, Anthony J. [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22904-2475 (United States); Lattanzi, Valerio; Martinez, Oscar Jr.; McCarthy, Michael C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Lovas, Frank J. [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Corby, Joanna F. [Department of Astronomy, University of Virginia, McCormick Road, Charlottesville, VA 22904 (United States)

    2013-03-01T23:59:59.000Z

    We have performed reaction product screening measurements using broadband rotational spectroscopy to identify rotational transition matches between laboratory spectra and the Green Bank Telescope PRIMOS radio astronomy survey spectra in Sagittarius B2 North (Sgr B2(N)). The broadband rotational spectrum of molecules created in an electrical discharge of CH{sub 3}CN and H{sub 2}S contained several frequency matches to unidentified features in the PRIMOS survey that did not have molecular assignments based on standard radio astronomy spectral catalogs. Several of these transitions are assigned to the E- and Z-isomers of ethanimine. Global fits of the rotational spectra of these isomers in the range of 8-130 GHz have been performed for both isomers using previously published mm-wave spectroscopy measurements and the microwave measurements of the current study. Possible interstellar chemistry formation routes for E-ethanimine and Z-ethanimine are discussed. The detection of ethanimine is significant because of its possible role in the formation of alanine-one of the twenty amino acids in the genetic code.

  5. Direct Observation of Long Electron-Hole Diffusion Distance beyond 1 Micrometer in CH3NH3PbI3 Perovskite Thin Film

    E-Print Network [OSTI]

    Li, Yu; Li, Yunlong; Wang, Wei; Bian, Zuqiang; Xiao, Lixin; Wang, Shufeng; Gong, Qihuang

    2015-01-01T23:59:59.000Z

    In high performance perovskite based on CH3NH3PbI3, the formerly reported short charge diffusion distance is a confliction to thick working layer in solar cell devices. We carried out a study on charge diffusion in spin-coated CH3NH3PbI3 perovskite thin film by transient fluorescent spectroscopy. A thickness-dependent fluorescent lifetime was found. This effect correlates to the defects at crystal grain boundaries. By coating the film with electron or hole transfer layer, PCBM or Spiro-OMeTAD respectively, we observed the charge transfer directly through the fluorescent decay. One-dimensional diffusion model was applied to obtain long charge diffusion distances, which is ~1.3 micron for electrons and ~5.2 micron for holes. This study gives direct support to the high performance of perovskite solar cells.

  6. * Corresponding author. Tel.: #41-1-4451474, Fax: #41-1-4451499. E-mail address: tiwari@iqe.phys.ethz.ch (A.N. Tiwari).

    E-Print Network [OSTI]

    Romeo, Alessandro

    @iqe.phys.ethz.ch (A.N. Tiwari). Solar Energy Materials & Solar Cells 67 (2001) 311}321 In#uence of CdS growth process than of those grown on HVE-CdS. The structural and electrical properties of CdTe/CdS solar cells at 803C using a solution of Cd salt, ammonia and thiourea. The thickness of the HVE-CdS was varied

  7. El laberinto de la indigenidad: Cómo se determina quién es indígena maya ch’orti’ en Guatemala, Honduras y El Salvador

    E-Print Network [OSTI]

    Metz, Brent

    2012-01-01T23:59:59.000Z

    idioma primero y privilegiado de Dios. Dios prefiere oraciones en ch’orti’. Las fuerzas de la naturaleza personificadas en santos, como las cuatro direcciones, el sol, la tierra, el agua y el viento, son fundamentales en la visión tradicional del..., una dieta con altos porcentajes de maíz y frijoles cocinados con recetas antiguas, trabajo agrícola sin maquinaria, baja educación e incluso menosprecio hacia ella, el uso de yerbas medicinales y la producción de artesanías utilitarias. La raíz de...

  8. Bio390 Study Questions for S-N Ch. 2 --Blood 1. Know S-N's list of 10 general functions/properties of blood.

    E-Print Network [OSTI]

    Prestwich, Ken

    effects of temperature, pH, CO2, PO4 2-, and ionic strength on the ability of hemoglobin to bind oxygenBio390 Study Questions for S-N Ch. 2 -- Blood Spring '01 1. Know S-N's list of 10 general functions/properties tends to decrease as body size increases. How does a relatively high P50 serve as an adaptation in small

  9. Intermolecular C?H bond activation of benzene and pyridines by a vanadium(III) alkylidene including a stepwise conversion of benzene to a vanadium-benzyne complex

    SciTech Connect (OSTI)

    Andino, José G.; Kilgore, Uriah J.; Pink, Maren; Ozarowski, Andrew; Krzystek, J.; Telser, Joshua; Baik, Mu-Hyun; Mindiola, Daniel J. (Roosevelt); (FSU); (Indiana)

    2012-01-20T23:59:59.000Z

    Breaking of the carbon-hydrogen bond of benzene and pyridine is observed with (PNP)V(CH{sub 2}tBu){sub 2} (1), and in the case of benzene, the formation of an intermediate benzyne complex (C) is proposed, and indirect proof of its intermediacy is provided by identification of (PNP)VO({eta}{sup 2}-C{sub 6}H{sub 4}) in combination with DFT calculations.

  10. A QUANTUM BAND MODEL OF THE {nu}{sub 3} FUNDAMENTAL OF METHANOL (CH{sub 3}OH) AND ITS APPLICATION TO FLUORESCENCE SPECTRA OF COMETS

    SciTech Connect (OSTI)

    Villanueva, G. L.; DiSanti, M. A.; Mumma, M. J. [Solar System Exploration Division, Mailstop 690.3, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Xu, L.-H., E-mail: Geronimo.Villanueva@nasa.gov [Department of Physics and Centre for Laser, Atomic, and Molecular Sciences, University of New Brunswick, Saint John, New Brunswick E2L 4L5 (Canada)

    2012-03-01T23:59:59.000Z

    Methanol (CH{sub 3}OH) radiates efficiently at infrared wavelengths, dominating the C-H stretching region in comets, yet inadequate quantum-mechanical models have imposed limits on the practical use of its emission spectra. Accordingly, we constructed a new line-by-line model for the {nu}{sub 3} fundamental band of methanol at 2844 cm{sup -1} (3.52 {mu}m) and applied it to interpret cometary fluorescence spectra. The new model permits accurate synthesis of line-by-line spectra for a wide range of rotational temperatures, ranging from 10 K to more than 400 K. We validated the model by comparing simulations of CH{sub 3}OH fluorescent emission with measured spectra of three comets (C/2001 A2 LINEAR, C/2004 Q2 Machholz and 8P/Tuttle) acquired with high-resolution infrared spectrometers at high-altitude sites. The new model accurately describes the complex emission spectrum of the {nu}{sub 3} band, providing distinct rotational temperatures and production rates at greatly improved confidence levels compared with results derived from earlier fluorescence models. The new model reconciles production rates measured at infrared and radio wavelengths in C/2001 A2 (LINEAR). Methanol can now be quantified with unprecedented precision and accuracy in astrophysical sources through high-dispersion spectroscopy at infrared wavelengths.

  11. Alternative current conduction mechanisms of organic-inorganic compound [N(CH{sub 3}){sub 3}H]{sub 2}ZnCl{sub 4}

    SciTech Connect (OSTI)

    Ben Bechir, M., E-mail: mohamedbenbechir@hotmail.fr; Karoui, K.; Guidara, K.; Ben Rhaiem, A. [Laboratory of Condensed Matter, Faculty of Sciences, University of Sfax, BP1171, 3018 Sfax (Tunisia); Tabellout, M. [LUNAM Université, Université du Maine, CNRS UMR 6283, Institut des Molécules et Matériaux du Mans (IMMM), Avenue Olivier Messiaen, F-72085, Le Mans Cedex 09 (France)

    2014-04-21T23:59:59.000Z

    [N(CH{sub 3}){sub 3}H]{sub 2}ZnCl{sub 4} has been studied by X-ray powder diffraction patterns, differential scanning calorimetry (DSC), and impedance spectroscopy. The [N(CH{sub 3}){sub 3}H]{sub 2}ZnCl{sub 4} hybrid compound is crystallized at room temperature (T ? 300?K) in the orthorhombic system with Pnma space group. Five phase transitions (T{sub 1}?=?255?K, T{sub 2}?=?282?K, T{sub 3}?=?302?K, T{sub 4}?=?320?K, and T{sub 5}?=?346?K) have been proved by DSC measurements. The electrical technique was measured in the 10{sup ?1}-10{sup 7}?Hz frequency range and 233–363?K temperature interval. The frequency dependence of alternative current (AC) conductivity is interpreted in terms of Jonscher's law. The AC electrical conduction in [N(CH{sub 3}){sub 3}H]{sub 2}ZnCl{sub 4} is analyzed by different processes, which can be attributed to several models: the correlated barrier hopping model in phase I, the overlapping large polaron tunneling model in phase II, the quantum mechanical tunneling model in phase IV, and the non-overlapping small polaron tunneling model in phases III, V, and VI. The conduction mechanism is studied with the help of Elliot's theory, and the Elliot's parameters are determined.

  12. Alternative current conduction mechanisms of organic-inorganic compound [N(CH{sub 3}){sub 3}H]{sub 2}CuCl{sub 4}

    SciTech Connect (OSTI)

    Ben Bechir, M., E-mail: mohamedbenbechir@hotmail.fr; Karoui, K.; Guidara, K.; Ben Rhaiem, A. [Laboratory of Condensed Matter, Faculty of Sciences, University of Sfax, BP1171, 3018 Sfax (Tunisia); Tabellout, M. [LUNAM Université, Université du Maine, CNRS UMR 6283, Institut des Molécules et Matériaux du Mans (IMMM), Avenue Olivier Messiaen, F-72085 Le Mans Cedex 09 (France)

    2014-05-28T23:59:59.000Z

    The [N(CH{sub 3}){sub 3}H]{sub 2}CuCl{sub 4} single crystal has been analyzed by X-ray powder diffraction patterns, differential scanning calorimetry (DSC), and electrical impedance spectroscopy. [N(CH{sub 3}){sub 3}H]{sub 2}CuCl{sub 4} crystallizes at room temperature in the monoclinic system with P2{sub 1}/{sub C} space group. Three phase transitions at T{sub 1}?=?226?K, T{sub 2}?=?264?K, and T{sub 3}?=?297?K have been evidenced by DSC measurements. The electrical technique was measured in the 10{sup ?1}–10{sup 7}?Hz frequency range and 203–313?K temperature intervals. The frequency dependence of alternative current (AC) conductivity is interpreted in terms of Jonscher's law (developed). The AC electrical conduction in [N(CH{sub 3}){sub 3}H]{sub 2}CuCl{sub 4} compound is studied by two processes which can be attributed to a hopping transport mechanism: the correlated barrier hopping model in phases I, II, and III, the non-overlapping small polaron tunneling model in phase IV. The conduction mechanism is interpreted with the help of Elliot's theory, and the Elliot's parameters are found.

  13. The structure and electrochemical behavior of nitrogen-containing nanocrystalline diamond films deposited from CH4/N2/Ar mixtures.

    SciTech Connect (OSTI)

    Chen, Q.; Gruen, D. M.; Krauss, A. R.; Corrigan, T. D.; Swain, G. M.; Utah State Univ.; Northwestern Univ.

    2001-01-01T23:59:59.000Z

    Electrically conductive nanocrystalline diamond films (approximately 750 to 1000 nm thick) were deposited on conducting Si and W substrates from CH{sub 4}/N{sub 2}/Ar gas mixtures using plasma-enhanced chemical vapor deposition. Such films are continuous over the surface and nanometer smooth. The grain size is 3 to 10 nm, and the grain boundaries are 0.2 to 0.5 nm wide (two carbon atoms). Nitrogen appears to substitutionally insert into the grain boundaries and the film concentration ({approx}10{sup 20} atom/cm{sup 3}) scales with the N{sub 2} added to the source gas mixture up to about the 5% level. The nitrogen-incorporated films are void of pinholes and cracks, and electrically conducting due in part to the high concentration of nitrogen impurities and or the nitrogen-related defects (sp{sup 2} bonding). The films possess semimetallic electronic properties over a potential range from at least -1.5 to 1.0 V vs. SCE. The electrodes, like boron-doped microcrystalline diamond, exhibit a wide working potential window, a low background current, and high degree of electrochemical activity for redox systems such as Fe(CN)6{sup -3/-4}, Ru(NH{sub 3}6{sup +3/+2}), IrCl6{sup -2/-3}, and methyl viologen (MV{sup +2/+}). More sluggish electrode kinetics are observed for 4-methylcatechol, presumably due to weak adsorption on the surface. Apparent heterogeneous electron transfer rate constants of 10{sup -2} to 10{sup -1} cm/s are observed for Fe(CN)6{sup -3/-4}, Ru(NH{sub 3})6{sup +3/+2}, IrCl6{sup -2/-3}, and MV {sup +2/+} at films without any pretreatment.

  14. Numerical studies of gas production from several CH4-hydrate zones at the Mallik Site, Mackenzie Delta, Canada

    SciTech Connect (OSTI)

    Moridis, George J.; Collett, Timothy S.; Dallimore, Scott R.; Satoh, Tohru; Hancock, Steven; Weatherill, Brian

    2002-05-08T23:59:59.000Z

    The Mallik site represents an onshore permafrost-associated gas hydrate accumulation in the Mackenzie Delta, Northwest Territories, Canada. A gas hydrate research well was drilled at the site in 1998. The objective of this study is the analysis of various gas production scenarios from several gas-hydrate-bearing zones at the Mallik site. The TOUGH2 general-purpose simulator with the EOSHYDR2 module were used for the analysis. EOSHYDR2 is designed to model the non-isothermal CH{sub 4} release, phase behavior and flow under conditions typical of methane-hydrate deposits by solving the coupled equations of mass and heat balance, and can describe any combination of gas hydrate dissociation mechanisms. Numerical simulations indicated that significant gas hydrate production at the Mallik site was possible by drawing down the pressure on a thin free-gas zone at the base of the hydrate stability field. Gas hydrate zones with underlying aquifers yielded significant gas production entirely from dissociated gas hydrate, but large amounts of produced water. Lithologically isolated gas-hydrate-bearing reservoirs with no underlying free gas or water zones, and gas-hydrate saturations of at least 50% were also studied. In these cases, it was assumed that thermal stimulation by circulating hot water in the well was the method used to induce dissociation. Sensitivity studies indicated that the methane release from the hydrate accumulations increases with gas-hydrate saturation, the initial formation temperature, the temperature of the circulating water in the well, and the formation thermal conductivity. Methane production appears to be less sensitive to the rock and hydrate specific heat and permeability of the formation.

  15. Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10 volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3 and SO2

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    methyl tertiary- butyl ether (MTBE) and its effect on plasmaand three VOCs (propyne, furan, MTBE) remained below their 3Ethanol Acetone MEK MAC MVK MTBE Furan CH 3 OH C 2 H 5 OH C

  16. Metal alkoxides. Models for metal oxides. 15. Carbon-carbon and carbon-hydrogen bond activation in the reactions between ethylene and ditungsten hexaalkoxides: W sub 2 (OCH sub 2 -t-Bu) sub 6 (. eta. sup 2 -C sub 2 H sub 4 ) sub 2 , W sub 2 (OR) sub 6 (CH sub 2 ) sub 4 (. eta. sup 2 -C sub 2 H sub 4 ), and W sub 2 (OR) sub 6 (. mu. -CCH sub 2 CH sub 2 CH sub 2 ) (where r = CH sub 2 -t-Bu, i-Pr, c-C sub 5 h sub 9 , and c-C sub 6 H sub 11 ). Preparations, properties, structures, and reaction mechanisms

    SciTech Connect (OSTI)

    Chisholm, M.H.; Huffman, J.C.; Hampden-Smith, M.J. (Indiana Univ., Bloomington (USA))

    1989-07-05T23:59:59.000Z

    W{sub 2}(OR){sub 6} (M {triple bond}M) compounds and ethylene (1 atm, 22{degree}C) react in alkane and aromatic hydrocarbon solvents to give W{sub 2}(OR){sub 6}({mu}-CCH{sub 2}CH{sub 2}CH{sub 2}) compounds and ethane, where R = i-Pr, c-C{sub 5}H{sub 9}, c-C{sub 6}H{sub 11}, and CH{sub 2}-t-Bu. Under comparable conditions, W{sub 2}(O-t-Bu){sub 6} and ethylene fail to react. In the formation of W{sub 2}(OR){sub 6}({mu}-CCH{sub 2}CH{sub 2}CH{sub 2}) compounds, the intermediates W{sub 2}(OCH{sub 2}-t-Bu){sub 6}({eta}{sup 2}-C{sub 2}H{sub 4}){sub 2} and W{sub 2}(OR){sub 6}(CH{sub 2}){sub 4}({eta}{sup 2}-C{sub 2}H{sub 4}), where R = C-C{sub 5}H{sub 9}, i-Pr, and CH{sub 2}-t-Bu, have been characterized. For R = i-Pr and CH{sub 2}-t-Bu, the intermediates are shown to be formed reversibly from W{sub 2}(OR){sub 6} and ethylene. The compound W{sub 2}(O-i-Pr){sub 6}(CH{sub 2}){sub 4}({eta}{sup 2}-C{sub 2}H{sub 4}) has been fully characterized by an X-ray study and found to contain a metallacyclopentane ring and a W-{eta}{sup 2}-C{sub 2}H{sub 4} moiety, one at each metal center. The pyridine adduct W{sub 2}(O-i-Pr){sub 6}({mu}-CCH{sub 2}CH{sub 2}ch{sub 2})(py) has been fully characterized and shown to contain a novel 1,6-dimetallabicyclo(3.1.0)hex-1(5)-ene organometallic core. All compounds have been characterized by {sup 13}C and {sup 1}H NMR studies. Various aspects of the reaction pathway have been probed by the use of isotopically labeled ethylenes, and a proposed general scheme is compared to previous studies of ethylene activation at mononuclear metal centers and carbonyl dinuclear and cluster compounds.

  17. CH7 Windows Introduction

    E-Print Network [OSTI]

    Collette. Sébastien

    4 Server · Account lockout security ­ Protection contre les attaques sur les mots de passe Windows NT 4 Server · Account lockout security ­ Protection contre les attaques sur les mots de passe

  18. CH Packaging Maintenance Manual

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2002-01-02T23:59:59.000Z

    This procedure provides instructions for performing inner containment vessel (ICV) and outer containment vessel (OCV) maintenance and periodic leakage rate testing on the following packaging seals and corresponding seal surfaces using a nondestructive helium (He) leak test. In addition, this procedure provides instructions for performing ICV and OCV structural pressure tests.

  19. CH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2002-03-04T23:59:59.000Z

    The purpose of this document is to provide the technical requirements for preparation for use, operation, inspection, and maintenance of a Transuranic Package Transporter Model II (TRUPACT-II), a HalfPACT Shipping Package, and directly related components. This document complies with the minimum requirements as specified in TRUPACT-II Safety Analysis Report for Packaging (SARP), HalfPACT SARP, and Nuclear Regulatory Commission (NRC) Certificates of Compliance (C of C) 9218 and 9279, respectively. In the event there is a conflict between this document and the SARP or C of C, the SARP and/or C of C shall govern. C of Cs state: ''each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application.'' They further state: ''each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application.'' Chapter 9.0 of the SAR P charges the WIPP Management and Operation (M&O) contractor with assuring packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 CFR 71.11. Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. This document details the instructions to be followed to operate, maintain, and test the TRUPACT-II and HalfPACT packaging. The intent of these instructions is to standardize these operations. All users will follow these instructions or equivalent instructions that assure operations are safe and meet the requirements of the SARPs.

  20. CH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2005-02-28T23:59:59.000Z

    The purpose of this document is to provide the technical requirements for preparation for use, operation, inspection, and maintenance of a Transuranic Package Transporter Model II (TRUPACT-II), a HalfPACT shipping package, and directly related components. This document complies with the minimum requirements as specified in the TRUPACT-II Safety Analysis Report for Packaging (SARP), HalfPACT SARP, and U.S. Nuclear Regulatory Commission (NRC) Certificates of Compliance (C of C) 9218 and 9279, respectively. In the event of a conflict between this document and the SARP or C of C, the C of C shall govern. The C of Cs state: "each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." They further state: "each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP charges the Waste Isolation Pilot Plant (WIPP) management and operating (M&O) contractor with assuring packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with Title 10 Code of Federal Regulations (CFR) §71.8. Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the Carlsbad Field Office (CBFO) shall be notified immediately. The CBFO will evaluate the issue and notify the NRC if required.

  1. Pub-3000: CH45

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah47,193.70COMMUNITY AEROSOL INLET J.-L.Pseudogaps,Pu Qian Pu Qian45

  2. Functionality of alkaline cooked corn bran on tortilla texture

    E-Print Network [OSTI]

    Guajardo Flores, Sara

    1998-01-01T23:59:59.000Z

    0. 34 0. 79 0. 46 0. 95 ' Values are means of 3 replicates, 3 duplicates per replicate. P = percent pericarp remaining. ' MCM = moisture content of fresh masa. MCT = moisture content of tortillas. ' Least significant difference (P = 0. 05). 22...

  3. Experimental densities, entropies and energies for pure H?S and equimolar mixtures of H?S/CH? and H?S/CO? between 300 and 500 K

    E-Print Network [OSTI]

    Liu, Chung Hsiu

    1985-01-01T23:59:59.000Z

    and temperature data for H 5, H 5/CH and H S/CO were 2 2 4 2 2 measured between 300 and 500 K and 0 to 60 MPa using the Burnett- coupled isochoric technique. Second and third virial coefficients, densities, entropies and energies were derived from the pressure..., M , which has temperature and pressure R as independent variables, is defined in a similar fashion M (T, P) = M(T, P) ? M (T, P) (20) The density and pressure residual functions are related as follows 0 M (T, P) ? M (T, p) = ( -ln 2 if M=V or H...

  4. Preparation of Single Phase Films of CH3NH3Pb(I1-xBrx)3 with Sharp Optical Band Edges

    E-Print Network [OSTI]

    Sadhanala, Aditya; Deschler, Felix; Thomas, Tudor H; Dutton, Siân E.; Goedel, Karl C.; Hanusch, Fabian C.; Lai, May L.; Steiner, Ullrich; Bein, Thomas; Docampo, Pablo; Cahen, David; Friend, Richard H.

    2014-07-09T23:59:59.000Z

    ?inorganic perovskite (CH3NH3PbI3?xClx) solar cells now show photovoltaic (PV) performance1?4 approaching 18%,5,6 and high charge-carrier mobilities.7 Perovskite films have also shown promising photoluminescence quantum efficiencies (PLQEs) of more than 70% and lasing... .; Grat?zel, M.; Mhaisalkar, S.; Sum, T. C. Low-Temperature Solution- Processed Wavelength-Tunable Perovskites for Lasing. Nat. Mater. 2014, 13, 476?480. (9) Deschler, F.; Price, M.; Pathak, S.; Klintberg, L. E.; Jarausch, D.- D.; Higler, R.; Hu?ttner, S...

  5. Assessment of Standard Force Field Models against High-Quality ab initio Potential Curves for Prototypes of pi-pi, CH/pi, and SH/pi Interactions

    SciTech Connect (OSTI)

    Sumpter, Bobby G [ORNL; Sherrill, David [Georgia Institute of Technology; Sinnokrot, Mutasem O [University of Jordan; Marshall, Michael S. [Georgia Institute of Technology; Hohenstein, Edward G. [Georgia Institute of Technology; Walker, Ross [San Diego Supercomputer Center; Gould, Ian R [ORNL

    2009-01-01T23:59:59.000Z

    Several popular force fields, namely, CHARMM, AMBER, OPLS-AA, and MM3, have been tested for their ability to reproduce highly accurate quantum mechani- cal potential energy curves for noncovalent interactions in the benzene dimer, the benzene-CH4 complex, and the benzene-H2S complex. All of the force fields are semi-quantitatively correct, but none of them is consistently reliable quantitatively. Re-optimization of Lennard-Jones parameters and symmetry-adapted perturbation theory analysis for the benzene dimer suggests that better agreement cannot be expected unless more flexible functional forms (particularly for the electrostatic contributions)are employed for the empirical force fields.

  6. Spectroscopic analysis of H{sub 2}/CH{sub 4} microwave plasma and fast growth rate of diamond single crystal

    SciTech Connect (OSTI)

    Derkaoui, N.; Rond, C., E-mail: rond@lspm.cnrs.fr; Hassouni, K.; Gicquel, A. [Laboratoire des Sciences des Procédés et des Matériaux (LSPM), UPR3407 CNRS, Université Paris 13, 99 Avenue Jean Baptiste Clément, 93430 Villetaneuse (France)

    2014-06-21T23:59:59.000Z

    One of the best ways to increase the diamond growth rate is to couple high microwave power to the plasma. Indeed, increasing the power density leads to increase gas temperature the atomic hydrogen density in the plasma bulk, and to produce more hydrogen and methyl at the diamond surface. Experimental and numerical approaches were used to study the microwave plasma under high power densities conditions. Gas temperature was measured by optical emission spectroscopy and H-atom density using actinometry. CH{sub 3}-radical density was obtained using a 1D model that describes temperatures and plasma composition from the substrate to the top of the reactor. The results show that gas temperature in the plasma bulk, atomic hydrogen, and methyl densities at the diamond surface highly increase with the power density. As a consequence, measurements have shown that diamond growth rate also increases. At very high power density, we measured a growth rate of 40??m/h with an H-atom density of 5 × 10{sup 17} cm{sup ?3} which corresponds to a H{sub 2} dissociation rate higher than 50%. Finally, we have shown that the growth rate can be framed between a lower and an upper limit as a function depending only on the maximum of H-atom density measured or calculated in the plasma bulk. The results also demonstrated that increasing fresh CH{sub 4} by an appropriate injection into the boundary layer is a potential way to increase the diamond growth rates.

  7. Differentiation of O-H and C-H Bond Scission Mechanisms of Ethylene Glycol on Pt and Ni/Pt Using Theory and Isotopic Labeling Experiments

    SciTech Connect (OSTI)

    Salciccioli, Michael; Yu, Weiting; Barteau, Mark A; Chen, Jingguang; Vlachos, Dion G.

    2011-05-25T23:59:59.000Z

    Understanding and controlling bond-breaking sequences of oxygenates on transition metal catalysts can greatly impact the utilization of biomass feedstocks for fuels and chemicals. The decomposition of ethylene glycol, as the simplest representative of biomass-derived polyols, was studied via density functional theory (DFT) calculations to identify the differences in reaction pathways between Pt and the more active Ni/Pt bimetallic catalyst. Comparison of the computed transition states indicated three potentially feasible paths from ethylene glycol to C1 oxygenated adsorbates on Pt. While not important on Pt, the pathway to 1,2-dioxyethylene (OCH?CH?O) is favored energetically on the Ni/Pt catalyst. Temperature-programmed desorption (TPD) experiments were conducted with deuterated ethylene glycols for comparison with DFT results. These experiments confirmed that decomposition of ethylene glycol on Pt proceeds via initial O–H bond cleavage, followed by C–H and the second O–H bond cleavages, whereas on the Ni/Pt surface, both O–H bonds are cleaved initially. The results are consistent with vibrational spectra and indicate that tuning of the catalyst surface can selectively control bond breaking. Finally, the significant mechanistic differences in decomposition of polyols compared to that of monoalcohols and hydrocarbons serve to identify general trends in bond scission sequences.

  8. Origin of graphitic filaments on improving the electron field emission properties of negative bias-enhanced grown ultrananocrystalline diamond films in CH{sub 4}/Ar plasma

    SciTech Connect (OSTI)

    Sankaran, K. J.; Tai, N. H., E-mail: inanlin@mail.tku.edu.tw, E-mail: nhtai@mse.nthu.edu.tw [Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan (China); Huang, B. R.; Saravanan, A. [Graduate Institute of Electro-Optical Engineering and Department of Electronic Engineering, National Taiwan University of Science and Technology, Taipei 106, Taiwan (China); Lin, I. N., E-mail: inanlin@mail.tku.edu.tw, E-mail: nhtai@mse.nthu.edu.tw [Department of Physics, Tamkang University, Tamsui 251, Taiwan (China)

    2014-10-28T23:59:59.000Z

    Microstructural evolution of bias-enhanced grown (BEG) ultrananocrystalline diamond (UNCD) films has been investigated using microwave plasma enhanced chemical vapor deposition in gas mixtures of CH{sub 4} and Ar under different negative bias voltages ranging from ?50 to ?200?V. Scanning electron microscopy and Raman spectroscopy were used to characterize the morphology, growth rate, and chemical bonding of the synthesized films. Transmission electron microscopic investigation reveals that the application of bias voltage induced the formation of the nanographitic filaments in the grain boundaries of the films, in addition to the reduction of the size of diamond grains to ultra-nanosized granular structured grains. For BEG-UNCD films under ?200?V, the electron field emission (EFE) process can be turned on at a field as small as 4.08?V/?m, attaining a EFE current density as large as 3.19?mA/cm{sup 2} at an applied field of 8.64?V/?m. But the films grown without bias (0?V) have mostly amorphous carbon phases in the grain boundaries, possessing poorer EFE than those of the films grown using bias. Consequently, the induction of nanographitic filaments in grain boundaries of UNCD films grown in CH{sub 4}/Ar plasma due to large applied bias voltage of ?200?V is the prime factor, which possibly forms interconnected paths for facilitating the transport of electrons that markedly enhance the EFE properties.

  9. Thermodynamic Studies of [H2Rh(diphosphine)2]+ and [HRh(diphosphine)2(CH3CN)]2+ Complexes in Acetonitrile

    SciTech Connect (OSTI)

    Aaron D. Wilson; Alexander J. M. Miller; Daniel L. DuBois; Jay A. Labinger; John E. Bercaw

    2011-04-01T23:59:59.000Z

    Thermodynamic studies of a series of [H2Rh(PP)2]+ and [HRh(PP)2(CH3CN)]2+ complexes have been carried out in acetonitrile. Seven different diphosphine (PP) ligands were selected to allow variation of the electronic properties of the ligand substituents, the cone angles, and the natural bite angles (NBAs). Oxidative addition of H2 to [Rh(PP)2]+ complexes is favored by diphosphine ligands with large NBAs, small cone angles, and electron donating substituents, with the NBA being the dominant factor. Large pKa values for [HRh(PP)2(CH3CN)]2+ complexes are favored by small ligand cone angles, small NBAs, and electron donating substituents with the cone angles playing a major role. The hydride donor abilities of [H2Rh(PP)2]+ complexes increase as the NBAs decrease, the cone angles decrease, and the electron donor abilities of the substituents increase. These results indicate that if solvent coordination is involved in hydride transfer or proton transfer reactions, the observed trends can be understood in terms of a combination of two different steric effects, NBAs and cone angles, and electron-donor effects of the ligand substituents.

  10. Thermodynamic Studies of [H2Rh(diphosphine)2]+ and [HRh(diphosphine)2(CH3CN)]2+ Complexes in Acetonitrile

    SciTech Connect (OSTI)

    Wilson, Aaron D.; Miller, Alexander J.; DuBois, Daniel L.; Labinger, Jay A.; Bercaw, John E.

    2010-04-19T23:59:59.000Z

    Thermodynamic studies of a series of [H2Rh(PP)2]+ and [HRh(PP)2(CH3CN)]2+ complexes have been carried out in acetonitrile. Seven different diphosphine (PP) ligands were selected to allow variation of the electronic properties of the ligand substituents, the cone angles, and the natural bite angles (NBAs). Oxidative addition of H2 to [Rh(PP)2]+ complexes is favored by diphosphine ligands with large NBAs, small cone angles, and electron donating substituents, with the NBA being the dominant factor. Large pKa values for [HRh(PP)2(CH3CN)]2+ complexes are favored by small ligand cone angles, small NBAs, and electron donating substituents with the cone angles playing a major role. The hydride donor abilities of [H2Rh(PP)2]+ complexes increase as the NBAs decrease, the cone angles decrease, and the electron donor abilities of the substituents increase. These results indicate that if solvent coordination is involved in hydride transfer or proton transfer reactions, the observed trends can be understood in terms of a combination of two different steric effects, NBAs and cone angles, and electron-donor effects of the ligand substituents. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  11. Electric polarizabilities of Ge(CH{sub 3}){sub 4} from collision-induced light-scattering experiments and ab initio calculations

    SciTech Connect (OSTI)

    Maroulis, G.; Hohm, Uwe [Department of Chemistry, University of Patras, GR-26500 Patras (Greece); Institut fuer Physikalische und Theoretische Chemie der Technischen, Universitaet Braunschweig, Hans-Sommer-Strasse 10, D-38106 Braunschweig (Germany)

    2007-09-15T23:59:59.000Z

    The dipole-quadrupole and dipole-octopole polarizabilities A and E of Ge(CH{sub 3}){sub 4} have been determined from collision-induced light-scattering experiments and ab initio calculations. Our experimental results are |A|/e{sup 2}a{sub 0}{sup 3}E{sub h}{sup -1}<143 and |E|/e{sup 2}a{sub 0}{sup 4}E{sub h}{sup -1}<545. Our best theoretical values are A=45.48 and E=-389.9, respectively. The calculated value for the dipole polarizability is {alpha}/e{sup 2}a{sub 0}{sup 2}E{sub h}{sup -1}=83.26, in fine accord with our static experimental estimate of 83.2. We present a detailed discussion of the level of agreement between experiment and theory.

  12. Analysis of the microwave, terahertz, and far infrared spectra of monodeuterated methanol CH{sub 2}DOH up to J = 26, K = 11, and o{sub 1}

    SciTech Connect (OSTI)

    Coudert, L. H., E-mail: laurent.coudert@lisa.u-pec.fr [Laboratoire Inter-universitaire des Systèmes Atmosphériques, UMR 7583 du CNRS, Universités Paris Est Créteil et Paris Diderot, 61 Avenue du Général de Gaulle, 94010 Créteil Cedex (France); Zemouli, M. [Laboratoire d'Études Physico-Chimiques, Université Dr. T. Moulay de Saïda, Saïda 20000 (Algeria)] [Laboratoire d'Études Physico-Chimiques, Université Dr. T. Moulay de Saïda, Saïda 20000 (Algeria); Motiyenko, R. A.; Margulès, L. [Laboratoire de Physique des Lasers, Atomes et Molécules, UMR 8523 CNRS - Université Lille I, Bât. P5, 59655 Villeneuve d'Ascq Cedex (France)] [Laboratoire de Physique des Lasers, Atomes et Molécules, UMR 8523 CNRS - Université Lille I, Bât. P5, 59655 Villeneuve d'Ascq Cedex (France); Klee, S. [Physikalisch-Chemisches Institut, Justus-Liebig-Universität Gießen, 35392 Gießen (Germany)] [Physikalisch-Chemisches Institut, Justus-Liebig-Universität Gießen, 35392 Gießen (Germany)

    2014-02-14T23:59:59.000Z

    The first theoretical approach aimed at accounting for the energy levels of a non-rigid molecule displaying asymmetric-top asymmetric-frame internal rotation is developed. It is applied to a line position analysis of the high-resolution spectrum of the non-rigid CH{sub 2}DOH molecule and allows us to carry out a global analysis of a data set consisting of already available data and of microwave and far infrared transitions measured in this work. The analysis is restricted to the three lowest lying torsional levels (e{sub 0}, e{sub 1}, and o{sub 1}), to K ? 11, and to J ? 26. For the 8211 fitted lines, the unitless standard deviation is 2.4 and 103 parameters are determined including kinetic energy, hindering potential, and distortion effects parameters.

  13. Calculation of exact vibrational spectra for P{sub 2}O and CH{sub 2}NH using a phase space wavelet basis

    SciTech Connect (OSTI)

    Halverson, Thomas, E-mail: tom.halverson@ttu.edu; Poirier, Bill [Department of Chemistry and Biochemistry and Department of Physics, Texas Tech University, P.O. Box 41061, Lubbock, Texas 79409-1061 (United States)

    2014-05-28T23:59:59.000Z

    ‘‘Exact” quantum dynamics calculations of vibrational spectra are performed for two molecular systems of widely varying dimensionality (P{sub 2}O and CH{sub 2}NH), using a momentum-symmetrized Gaussian basis. This basis has been previously shown to defeat exponential scaling of computational cost with system dimensionality. The calculations were performed using the new “SWITCHBLADE” black-box code, which utilizes both dimensionally independent algorithms and massive parallelization to compute very large numbers of eigenstates for any fourth-order force field potential, in a single calculation. For both molecules considered here, many thousands of vibrationally excited states were computed, to at least an “intermediate” level of accuracy (tens of wavenumbers). Future modifications to increase the accuracy to “spectroscopic” levels, along with other potential future improvements of the new code, are also discussed.

  14. Off-resonance photoemission dynamics studied by recoil frame F1s and C1s photoelectron angular distributions of CH{sub 3}F

    SciTech Connect (OSTI)

    Stener, M., E-mail: stener@univ.trieste.it; Decleva, P. [Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste, Via L. Giorgieri 1, I-34127 Trieste (Italy) [Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste, Via L. Giorgieri 1, I-34127 Trieste (Italy); Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali Unita'di Trieste, 34127 Trieste (Italy); CNR-IOM DEMOCRITOS, 34149 Trieste (Italy)] [Italy; Mizuno, T.; Yagishita, A. [Photon Factory, Institute of Materials Structure Science, KEK, Oho 1-1, Tsukuba 305-0801 (Japan)] [Photon Factory, Institute of Materials Structure Science, KEK, Oho 1-1, Tsukuba 305-0801 (Japan); Yoshida, H. [Department of Chemistry, Hiroshima University, Higashi-Hiroshima, Hirosima 739-8526 (Japan)] [Department of Chemistry, Hiroshima University, Higashi-Hiroshima, Hirosima 739-8526 (Japan)

    2014-01-28T23:59:59.000Z

    F1s and C1s photoelectron angular distributions are considered for CH{sub 3}F, a molecule which does not support any shape resonance. In spite of the absence of features in the photoionization cross section profile, the recoil frame photoelectron angular distributions (RFPADs) exhibits dramatic changes depending on both the photoelectron energy and polarization geometry. Time-dependent density functional theory calculations are also given to rationalize the photoionization dynamics. The RFPADs have been compared with the theoretical calculations, in order to assess the accuracy of the theoretical method and rationalize the experimental findings. The effect of finite acceptance angles for both ionic fragments and photoelectrons has been included in the calculations, as well as the effect of rotational averaging around the fragmentation axis. Excellent agreement between theory and experiment is obtained, confirming the good quality of the calculated dynamical quantities (dipole moments and phase shifts)

  15. Dependency of temperature on polarization in CH{sub 4}/N{sub 2} dielectric barrier discharge plasma: A crude assumption

    SciTech Connect (OSTI)

    Majumdar, Abhijit; Hippler, Rainer [Institut of Physics, University of Greifswald, Felix Hausdorff Strasse 6, 17489 Greifswald (Germany); Ghosh, Basudev [Jadavpur University, Kolkata 700032, West Bengal (India)

    2010-11-15T23:59:59.000Z

    We have investigated the variations of polarization (P) and the temperature ({Delta}T) at the electrode surfaces during the deposition of C-N layer in CH{sub 4}/N{sub 2} (1:2) dielectric barrier discharge plasma. The reactive deposition process influences the surface temperature, polarization, and the value of the in situ dielectric constant. We have developed a crude model that correlates the surface temperature and surface polarization with thin film properties. We assume that during the thin film deposition process, the atomic mean kinetic energy is equal to the electrostatic energy stored in the electrode surface area. Theoretically estimated temperature is found to agree well with the experimental results. However, the linear model thus developed cannot be used to explain the phenomena in the interfacial polarization stage that requires a nonlinear theory.

  16. Crystal structure and electric properties of the organic–inorganic hybrid: [(CH{sub 2}){sub 6}(NH{sub 3}){sub 2}]ZnCl{sub 4}

    SciTech Connect (OSTI)

    Mostafa, M.F., E-mail: Mohga40@Yahoo.com; El-khiyami, S.S.

    2014-01-15T23:59:59.000Z

    The new organic-inorganic hybrid [(CH{sub 2}){sub 6}(NH{sub 3}){sub 2}]ZnCl{sub 4}, M{sub r}=325.406 crystallized in a triclinic, P1¯, a=7.2816 (5) Å, b=10.0996 (7) Å, c=10.0972 (7) Å, ?=74.368 (4)°, ?=88.046 (4)°, ?=85.974 (3)°, V=713.24 (9) Å{sup 3} and Z=2, D{sub x}=1.486 Mg m{sup ?3}. Differential thermal scanning and x-ray powder diffraction, permittivity and ac conductivity indicated three phase transitions. Conduction takes place via correlated barrier hopping. - Graphical abstract: Display Omitted.

  17. Possible hydride and methide transfer reactions: Reactions of Fe(CO){sub 4}R{sup -} (R=H, CH{sub 3}) and W(CO){sub 5}R{sup -} (R = H, CH{sub 3}, CL, Br, I) with metal carbonyl cations

    SciTech Connect (OSTI)

    Wang, P.; Striejewske, W.S.; Atwood, J.D. [State Univ. of New York, Buffalo, NY (United States)

    1996-02-01T23:59:59.000Z

    Reactions of metal carbonyl cations (M(CO){sub 6}{sup +}, M = Mn, Re) with hydride-, methide- or halide-containing metal carbonyl anions Fe(CO){sub 4}R{sup -}, R = H, Me; W(CO){sub 5} (CH{sub 3}CN) and W(CO){sub 5}X{sup -}. In contrast, the tungsten hydride and methide complexes react, predominantly, by transfer of the hydride or methide to a carbonyl of the cation at a much faster rate. The iron hydride and methide complexes react by iron-based nucleophilicity involving a two-electron process.

  18. Fig. S1. Current efficiency of electromethanogenesis. Electron equivalents needed for the2 formation of the measured concentrations of CH4 or H2 (from CO2 or water, respectively) and3

    E-Print Network [OSTI]

    culture and grown at 37C in an shaking water bath. Cells were harvested in early stationary35 phase formation of the measured concentrations of CH4 or H2 (from CO2 or water, respectively) and3 electrons. thermolithotrophicus cells were cultured in a modified DSMZ mineral medium 141, omitting18 Na-acetate, yeast extract

  19. Volume 2, Chapter 6: Rubbing the Powder on Smooth 1 When the two halves of the ch'in, the top and bottom, and also the area within the belly

    E-Print Network [OSTI]

    Binkley, Jim

    the lacquer­powder mixture has been put on, wait for it to dry through. [ Let it dry for three to five days is ground fine and mixed with lacquer making a very hard cement­like material when dry. The surface of the ch'in is coated with several layers which provide protection for the wood from the constant rubbing

  20. INTERNATIONAL OSTEOPOROSIS FOUNDATION RUE JUSTE-OLIVIER, 9 CH-1260 NYON SWITZERLAND T +41 22 994 01 00 F +41 22 994 01 01 INFO@IOFBONEHEALTH.ORG WWW.IOFBONEHEALTH.ORG

    E-Print Network [OSTI]

    Shihadeh, Alan

    INTERNATIONAL OSTEOPOROSIS FOUNDATION RUE JUSTE-OLIVIER, 9 · CH-1260 NYON · SWITZERLAND T +41 22 994 01 00 · F +41 22 994 01 01 · INFO@IOFBONEHEALTH.ORG · WWW.IOFBONEHEALTH.ORG OSTEOPOROSIS woman' released for World Osteoporosis Day shows urgent action must be taken to safeguard the quality

  1. 820 mV open-circuit voltages from Cu2O/CH3CN junctions Chengxiang Xiang, Gregory M. Kimball, Ronald L. Grimm, Bruce S. Brunschwig, Harry A. Atwater*

    E-Print Network [OSTI]

    Kimball, Gregory

    couple, cuprous oxide yielded open- circuit voltage, Voc, values of 820 mV and short-circuit current-conversion efficiency of 1.5% was limited by solution absorption and optical reflection losses that reduced the short-circuit820 mV open-circuit voltages from Cu2O/CH3CN junctions Chengxiang Xiang, Gregory M. Kimball, Ronald

  2. The attractive quartet potential energy surface for the CH(a{sup 4}{sigma}{sup {minus}}) + CO reaction: A role for the a {sup 4}A`` state of the ketenyl radical in combustion?

    SciTech Connect (OSTI)

    Schaefer, H.F. III [Univ. of Georgia, Athens (United States)

    1993-12-01T23:59:59.000Z

    Ab initio quantum mechanical techniques, including the self-consistent field (SCF), single and double excitation configuration interaction (CISD), single and double excitation double cluster (CCSD), and the single, double and perturbative triple excitation coupled cluster [CCSD(T)] methods have been applied to study the HCCO(a {sup 4}A{open_quotes}) energy hypersurface. Rate constant measurements suggest an attractive potential for the reaction of CH(a {sup 4}{sigma}{sup -}) with CO, and a vanishingly small energy barrier is predicted here in the CH(a {sup 4}{sigma}{sup -}) + CO reaction channel. The {sup 4}A{open_quotes} state of HCCO is predicted to be bound by about 30 kcal/mol with respect to separated CH(a {sup 4}{sigma}{sup -}) + CO. The authors propose that a spin-forbidden electronic deactivation of CH(a {sup 4}{sigma}{sup -}) might occur through through an intersystem crossing involving the {sup 4}A{open_quotes} state of HCCO. The energetics and the geometries of the reactants and products on both quartet and doublet energy surfaces are presented. The relationship between this research and experimental combustion chemistry has been explored.

  3. Photometry of symbiotic stars XI. EG And, Z And, BF Cyg, CH Cyg, CI Cyg, V1329 Cyg, TX CVn, AG Dra, RW Hya, QW Sge, IV Vir and the LMXB V934 Her

    E-Print Network [OSTI]

    A. Skopal; T. Pribulla; M. Vanko; Z. Velic; E. Semkov; M. Wolf; A. Jones

    2004-02-06T23:59:59.000Z

    We present new photometric observations of EG And, Z And, BF Cyg, CH Cyg, CI Cyg, V1329 Cyg, TX CVn, AG Dra, RW Hya, AR Pav, AG Peg, AX Per, QW Sge, IV Vir and the peculiar M giant V934 Her. The current issue gathers observations of these objects to December 2003.

  4. Quantum cascade laser investigations of CH{sub 4} and C{sub 2}H{sub 2} interconversion in hydrocarbon/H{sub 2} gas mixtures during microwave plasma enhanced chemical vapor deposition of diamond

    SciTech Connect (OSTI)

    Ma Jie; Cheesman, Andrew; Ashfold, Michael N. R. [School of Chemistry, University of Bristol, Bristol BS8 1TS (United Kingdom); Hay, Kenneth G.; Wright, Stephen; Langford, Nigel; Duxbury, Geoffrey [Department of Physics, University of Strathclyde, John Anderson Building, 107 Rottenrow, Glasgow G4 0NG (United Kingdom); Mankelevich, Yuri A. [Skobel'tsyn Institute of Nuclear Physics, Moscow State University, Leninskie Gory, Moscow 119991 (Russian Federation)

    2009-08-01T23:59:59.000Z

    CH{sub 4} and C{sub 2}H{sub 2} molecules (and their interconversion) in hydrocarbon/rare gas/H{sub 2} gas mixtures in a microwave reactor used for plasma enhanced diamond chemical vapor deposition (CVD) have been investigated by line-of-sight infrared absorption spectroscopy in the wavenumber range of 1276.5-1273.1 cm{sup -1} using a quantum cascade laser spectrometer. Parameters explored include process conditions [pressure, input power, source hydrocarbon, rare gas (Ar or Ne), input gas mixing ratio], height (z) above the substrate, and time (t) after addition of hydrocarbon to a pre-existing Ar/H{sub 2} plasma. The line integrated absorptions so obtained have been converted to species number densities by reference to the companion two-dimensional (r,z) modeling of the CVD reactor described in Mankelevich et al. [J. Appl. Phys. 104, 113304 (2008)]. The gas temperature distribution within the reactor ensures that the measured absorptions are dominated by CH{sub 4} and C{sub 2}H{sub 2} molecules in the cool periphery of the reactor. Nonetheless, the measurements prove to be of enormous value in testing, tensioning, and confirming the model predictions. Under standard process conditions, the study confirms that all hydrocarbon source gases investigated (methane, acetylene, ethane, propyne, propane, and butane) are converted into a mixture dominated by CH{sub 4} and C{sub 2}H{sub 2}. The interconversion between these two species is highly dependent on the local gas temperature and the H atom number density, and thus on position within the reactor. CH{sub 4}->C{sub 2}H{sub 2} conversion occurs most efficiently in an annular shell around the central plasma (characterized by 1400CH{sub 4} is favored in the more distant regions where T{sub gas}<1400 K. Analysis of the multistep interconversion mechanism reveals substantial net consumption of H atoms accompanying the CH{sub 4}->C{sub 2}H{sub 2} conversion, whereas the reverse C{sub 2}H{sub 2}->CH{sub 4} process only requires H atoms to drive the reactions; H atoms are not consumed by the overall conversion.

  5. Studies of a Series of [Ni(PR2NPh2)2(CH3CN)]2+ Complexes as Electrocatalysts for H2 Production: Substituent Variation at the Phosphorus Atom of the P2N2 Ligand

    SciTech Connect (OSTI)

    Kilgore, Uriah J.; Stewart, Michael P.; Helm, Monte L.; Dougherty, William G.; Kassel, W. S.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

    2011-11-07T23:59:59.000Z

    A series of [Ni(PR2NPh2)2(CH3CN)](BF4)2 complexes containing the cyclic diphosphine ligands (PR2NPh2 = 1,5-diaza-3,7-diphosphacyclooctane; R = benzyl (Bn), n-butyl (n-Bu), 2-phenylethyl (PE), 2,4,4-trimethylpentyl (TP), and cyclohexyl (Cy)) have been synthesized and characterized. X-ray diffraction studies reveal that the cations of [Ni(PBn2NPh2)2(CH3CN)](BF4)2 and [Ni(Pn-Bu2NPh2)2(CH3CN)](BF4)2 have distorted trigonal bipyramidal geometries. The Ni(0) complex [Ni(PBn2NPh2)2 (CH3CN)] was also synthesized and characterized by X-ray diffraction studies and shown to have a distorted tetrahedral structure. These complexes, with the exception of [Ni(PCy2NPh2)2(CH3CN)](BF4)2, all exhibit reversible electron transfer processes for both the Ni(II/I) and Ni(I/0) couples and are electrocatalysts for the production of H2 in acidic acetonitrile solutions. The heterolytic cleavage of H2 by [Ni(PR2NPh2)2(CH3CN)](BF4)2 complexes in the presence of p-anisidine or p-bromoaniline was used to determine the hydride donor abilities of the corresponding [HNi(PR2NPh2)2](BF4) complexes. However, the failure to observe a strong correlation between the turnover frequencies for H2 production and the hydride donor abilities, along with structural features of [Ni(PBn2NPh2)2(CH3CN)], suggest that steric interactions between the alkyl substituents on phosphorus and the nitrogen atom of the pendant amines play an important role in determining the overall catalytic rate. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

  6. CO2 Hydrate: Synthesis, Composition, Structure, Dissociation Behavior, and a Comparison to Structure I CH4 Hydrate

    SciTech Connect (OSTI)

    Circone, S. [U.S. Geological Survey, Menlo Park, CA; Stern, Laura A. [U.S. Geological Survey, Menlo Park, CA; Kirby, Stephen H. [U.S. Geological Survey, Menlo Park, CA; Durham, william B. [U.S. Geological Survey, Menlo Park, CA; Chakoumakos, Bryan C [ORNL; Rawn, Claudia J [ORNL; Rondinone, Adam Justin [ORNL; Ishii, Yoshinobu [Japan Atomic Energy Agency (JAEA)

    2003-01-01T23:59:59.000Z

    Structure I (sI) carbon dioxide (CO{sub 2}) hydrate exhibits markedly different dissociation behavior from sI methane (CH{sub 4}) hydrate in experiments in which equilibrated samples at 0.1 MPa are heated isobarically at 13 K/h from 210 K through the H{sub 2}O melting point (273.15 K). The CO{sub 2} hydrate samples release only about 3% of their gas content up to temperatures of 240 K, which is 22 K above the hydrate phase boundary. Up to 20% is released by 270 K, and the remaining CO{sub 2} is released at 271.0 {+-} 0.5 K, where the sample temperature is buffered until hydrate dissociation ceases. This reproducible buffering temperature for the dissociation reaction CO{sub 2}{center_dot}nH{sub 2}O = CO{sub 2}(g) + nH{sub 2}O(l to s) is measurably distinct from the pure H{sub 2}O melting point at 273.15 K, which is reached as gas evolution ceases. In contrast, when sI CH{sub 4} hydrate is heated at the same rate at 0.1 MPa, >95% of the gas is released within 25 K of the equilibrium temperature (193 K at 0.1 MPa). In conjunction with the dissociation study, a method for efficient and reproducible synthesis of pure polycrystalline CO{sub 2} hydrate with suitable characteristics for material properties testing was developed, and the material was characterized. CO{sub 2} hydrate was synthesized from CO{sub 2} liquid and H{sub 2}O solid and liquid reactants at pressures between 5 and 25 MPa and temperatures between 250 and 281 K. Scanning electron microscopy (SEM) examination indicates that the samples consist of dense crystalline hydrate and 50--300 {mu}m diameter pores that are lined with euhedral cubic hydrate crystals. Deuterated hydrate samples made by this same procedure were analyzed by neutron diffraction at temperatures between 4 and 215 K; results confirm that complete conversion of water to hydrate has occurred and that the measured unit cell parameter and thermal expansion are consistent with previously reported values. On the basis of measured weight gain after synthesis and gas yields from the dissociation experiments, approximately all cages in the hydrate structure are filled such that n {approx} 5.75.

  7. High-Pressure Synchtron Radiation X-Ray Diffraction Studies of Pentaerythritol Tetranitrate C(CH[subscript 2]ONO[subscript 2 ])[subscript 4

    SciTech Connect (OSTI)

    Lipinska-Kalita, K.E.; Pravica, M.; Nicol, M. (UNLV)

    2006-02-02T23:59:59.000Z

    A high-pressure x-ray diffraction study of nanocrystalline pentaerythritol tetranitrate, C(CH{sub 2}ONO{sub 2}){sub 4}, (PETN), has been performed in a diamond-anvil cell at ambient temperature using synchrotron radiation. Pressure-induced alterations in the profiles of the diffraction lines, including their positions, widths and intensities were followed up to 30 GPa in a compressino cycle. The spectral changes in the diffraction patterns at low pressures indicated continuous densification of the tetragonal structure (space group P{bar 4}2{sub 1}c). The diffraction patterns confirmed that PETN compressed from ambient pressure to 7.4 GPa by 17%. At 8.2 GPa and above, several new diffraction lines appeared in the patterns. These lines suggest that the lattice undergoes an incomplete stress-induced structural transformation from the tetragonal to an orthorhombic structure (most probably space group P2{sub 1}22{sub 1}). The mixture of both structures appeared to persist to 30 GPa. The progressive broadening of the diffraction lines as the pressure increased beyond 10 GPa is attributed to the combined diffraction lines of a mixture of two coexisting PETN phases and inhomogeneous pressure distribution within the sample.

  8. Els UK Job: CDI Ch01-I047172 30-10-2007 9:17a.m. Page:25 Trim:165240MM Float:Top/Bot TS: Integra, India Fonts: Palatino & Helvetica 9/11 Margins:Top:4PC Gutter:5PC T. W:30PC open recto 1 Color 49 Lines

    E-Print Network [OSTI]

    Oren, Shmuel S.

    Els UK Job: CDI Ch01-I047172 30-10-2007 9:17a.m. Page:25 Trim:165×240MM Float:Top/Bot TS: Integra Part I Market Reform Evolution #12;Els UK Job: CDI Ch01-I047172 30-10-2007 9:17a.m. Page:26 Trim:165:30PC open recto 1 Color 49 Lines #12;Els UK Job: CDI Ch01-I047172 30-10-2007 9:17a.m. Page:27 Trim

  9. Els UK Job: CDI ch09-i047172 16-11-2007 4:15p.m. Page:325 Trim:165240MM Float:Top/Bot TS: Integra, India Fonts: Palatino & Helvetica 9/11 Margins:Top:4PC Gutter:5PC T. W:30PC open recto 1 Color 49 Lines

    E-Print Network [OSTI]

    Oren, Shmuel S.

    Els UK Job: CDI ch09-i047172 16-11-2007 4:15p.m. Page:325 Trim:165×240MM Float:Top/Bot TS: Integra Part III Capacity, Resource Adequacy, and Investment #12;Els UK Job: CDI ch09-i047172 16-11-2007 4:15pPC Gutter:5PC T. W:30PC open recto 1 Color 49 Lines #12;Els UK Job: CDI ch09-i047172 16-11-2007 4:15p

  10. Laser-induced fluorescence measurements of NCN in low-pressure CH{sub 4}/O{sub 2}/N{sub 2} flames and its role in prompt NO formation

    SciTech Connect (OSTI)

    Sutton, Jeffrey A.; Williams, Bradley A.; Fleming, James W. [Navy Technology Center for Safety and Survivability, Chemistry Division, Combustion Dynamics Section, Code 6185, Naval Research Laboratory, Washington, DC 20375-5342 (United States)

    2008-05-15T23:59:59.000Z

    NCN profiles were measured for five rich and lean premixed, low-pressure methane flames using laser-induced fluorescence (LIF). A semiquantitative determination of the NCN mole fractions as a function of spatial height above the burner is made by calibrating the NCN LIF signals using highly accurate OH LIF measurements in an adjacent spectral region. The resulting calibration yields an uncertainty estimate of a factor of 3 for the absolute values, but only {+-}25% for the relative NCN profiles. For all flame conditions, the NCN profiles occur immediately downstream of previously measured CH profiles. In addition, high correlations are found between the peak CH and peak NCN concentrations and the peak NCN and postflame NO concentrations over all equivalence ratios. These observations are consistent with NCN being the primary product channel from the CH + N{sub 2} reaction and the initial intermediate in the prompt NO formation. This is the first mechanistic study in hydrocarbon flames that provides such experimental evidence. The experimental profiles are compared to numerical calculations using modified versions of two well-established hydrocarbon kinetic mechanisms. Reasonable agreement between the calculations and experiment is found for NCN profile shape, location of peak NCN concentrations, and absolute mole fractions. However, the dependence on stoichiometry of the peak NCN concentration is overestimated. Further work is required on NCN kinetics for modeling prompt NO in laminar premixed flames. (author)

  11. High ion density plasma etching of InGaP, AlInP, and AlGaP in CH{sub 4}/H{sub 2}/Ar

    SciTech Connect (OSTI)

    Lee, J.W.; Pearton, S.J.; Santana, C.J.; Mileham, J.R.; Lambers, E.S.; Abernathy, C.R. [Univ. of Florida, Gainesville, FL (United States); Ren, F.; Hobson, W.S. [AT and T Bell Labs., Murray Hill, NJ (United States)

    1996-03-01T23:59:59.000Z

    High microwave power (1,000 W) electron cyclotron resonance CH{sub 4}/H{sub 2}/Ar discharges produce etch rates for In{sub 0.5}Ga{sub 0.5}P, Al{sub 0.5}In{sub 0.5}P{sub 0.5}, and Al{sub 0.5}Ga{sub 0.5}P of {approximately} 2,000 {angstrom}/min at moderate RF power levels (150 W) and low pressure (1.5 mTorr). This is approximately a factor of five faster than for conventional reactive ion etching conditions where much higher ion energies are necessary. The etched surfaces are smooth over a wide range of CH{sub 4}-to-H{sub 2} ratios and microwave powers. AlInP is more resistant to preferential loss of P from the near-surface during etching than is InGaP. While the etching is ion-driven, pure Ar discharges produce rough surfaces and the CH{sub 4}/H{sub 2} is necessary in the achievement of acceptable morphologies. The InGaAlP/GaAs heterostructure is being increasingly utilized in diode lasers, light emitting diodes, field-effect transistors, and heterojunction bipolar transistors.

  12. Synthesis and characterization by sup 1 H, sup 13 C, and sup 19 F NMR spectroscopy of (CH sub 3 CN) sub n (CO) sub 4 minus n (NO)W(. mu. -F)BF sub 3 and ((CH sub 3 CN) sub n+1 (CO) sub 4 minus n (NO)W)(BF sub 4 )(n = 0 minus 2), tungsten mononitrosyl carbonyl cations with labile acetonitrile and ((. mu. -F)BF sub 3 ) sup minus ligands

    SciTech Connect (OSTI)

    Hersh, W.H. (Univ. of California, Los Angeles (USA))

    1990-02-21T23:59:59.000Z

    Addition of (NO)(BF{sub 4}) to CH{sub 3}CNW(CO){sub 5} in CH{sub 2}Cl{sub 2} gives a mixture of five mononitrosyl compounds, mer-(cis-CH{sub 3}CN)(trans-NO)(CO){sub 3}W({mu}-F)BF{sub 3} (1), (mer,cis-(CH{sub 3}CN){sub 2}W(CO){sub 3}(NO))(BF{sub 4}) (2a), cis,cis,trans-(CH{sub 3}CN){sub 2}(CO){sub 2}(NO)W({mu}-F)BF{sub 3} (3), (fac-(CH{sub 3}CN){sub 3} W(CO){sub 2}(NO))(BF){sub 4} (4a), and trans-(NO)(CO){sub 4}W({mu}-F)BF{sub 3} (5); in a typical experiment the yield is 90%, and the ratio 1:2a:3:4a:5 is 47:14:11:1:27. Support for the identities of 1-5 is obtained by reaction of the mixture with Me{sub 3}P, giving (mer-(cis-CH{sub 3}CN)(trans-Me{sub 3}P)W(CO){sub 3}(NO))(BF{sub 4}) (7a), (cis,cis,trans-(CH{sub 3}CN){sub 2}(CO){sub 2}(NO)W(PMe{sub 3}))(BF{sub 4}) (8a), (trans-Me{sub 3}P(CO){sub 4}WNO)(BF{sub 4}) (9), and the previously reported compound (mer,cis-(Me{sub 3}P){sub 2}W(CO){sub 3}(NO))(BF{sub 4}) (10a). The reaction mixtures are analyzed by IR and {sup 1}H, {sup 13}C, and {sup 19}F NMR spectroscopy. In particular, the {sup 13}C NMR spectrum exhibits quintets for the carbonyl ligands of 1,3, 5 due to a dynamic spinning process of the (({mu}-F)BF{sub 3}){sup {minus}} ligand, and the {sup 19}F NMR spectrum exhibits doublets for the terminal fluorine atoms (which are further separated into {sup 10}B and {sup 11}B isotopomers) near {minus}153 ppM and quartets for the bridging fluorine atoms from {minus}203 to {minus}238 ppM. Independent synthesis and isolation in good yield of 2b-c, 4a-d, 7b-c, and 8b (where the anions for a-d are (BF{sub 4}){sup {minus}}, (SbF{sub 6}){sup {minus}}, ((C{sub 6}H{sub 5}){sub 4}B){sup {minus}}, and (PF{sub 6}){sup {minus}}{sup {minus}}, respectively) are described, as are the independent synthesis and spectroscopic characterization of 3, 5, and 6. 4 figs., 1 tab.

  13. CH 101 Syllabus. Page 1 of 5 CH 101 SYLLABUS

    E-Print Network [OSTI]

    Stuart, Steven J.

    : Chemical Energy 5.0 3.0 Chap. 9 Gases: Their Properties and Behavior 3.0 2.0 Chap. 10 Liquids, Solids on the General Chemistry website. You can access our home page through the Chemistry Department site at http

  14. Microsoft Word - Ch 1-Ch9-umai-thesis.doc

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found TheHot electron dynamics in807 DE899Synthesis and

  15. Kinetics of the reduction of hematite (Fe{sub 2}O{sub 3}) by methane (CH{sub 4}) during chemical looping combustion: A global mechanism

    SciTech Connect (OSTI)

    Monazam, Esmail R.; Breault, Ronald W.; Siriwardane, Ranjani; Richards, George; Carpenter, Stephen

    2013-10-01T23:59:59.000Z

    Chemical-looping combustion (CLC) has emerged as a promising technology for fossil fuel combustion which produces a sequestration ready concentrated CO{sub 2} stream in power production. A CLC system is composed with two reactors, an air and a fuel reactor. An oxygen carrier such as hematite (94%Fe{sub 2}O{sub 3}) circulates between the reactors, which transfers the oxygen necessary for the fuel combustion from the air to the fuel. An important issue for the CLC process is the selection of metal oxide as oxygen carrier, since it must retain its reactivity through many cycles. The primary objective of this work is to develop a global mechanism with respective kinetics rate parameters such that CFD simulations can be performed for large systems. In this study, thermogravimetric analysis (TGA) of the reduction of hematite (Fe{sub 2}O{sub 3}) in a continuous stream of CH{sub 4} (15, 20, and 35%) was conducted at temperatures ranging from 700 to 825{degrees}C over ten reduction cycles. The mass spectroscopy analysis of product gas indicated the presence of CO{sub 2} and H{sub 2}O at the early stage of reaction and H{sub 2} and CO at the final stage of reactions. A kinetic model based on two parallel reactions, 1) first-order irreversible rate kinetics and 2) Avrami equation describing nucleation and growth processes, was applied to the reduction data. It was found, that the reaction rates for both reactions increase with, both, temperature and the methane concentration in inlet gas.

  16. [Ni(PPh2NBn2)2(CH3CN)]2+ as an Electrocatalyst for H2 Production: Dependence on Acid Strength and Isomer Distribution

    SciTech Connect (OSTI)

    Appel, Aaron M.; Pool, Douglas H.; O'Hagan, Molly J.; Shaw, Wendy J.; Yang, Jenny Y.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

    2011-07-01T23:59:59.000Z

    [Ni(PPh2NBz2)2(CH3CN)](BF4)2, Ni(PPh2NBz2)22+ (where PPh2NBz2 is 1,5-dibenzyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) has been studied as an electrocatalyst for the production of hydrogen in acetonitrile. Using strong acids, such as p cyanoanilinium, Ni(PPh2NBz2)22+ has been shown to be protonated under catalytic conditions prior to reduction, with an effective pKa of 6.7±0.4. Through multinuclear NMR spectroscopy studies, the nickel(II) complex was found to be doubly protonated without any observed singly protonated species. In the doubly protonated complex, both protons are positioned exo with respect to the metal center and are stabilized by an N-H-N hydrogen bond. The formation of exo protonated isomers is proposed to limit the rate of hydrogen production because the protons are unable to gain suitable proximity to the reduced metal center to generate dihydrogen. Pre-protonation of Ni(PPh2NBz2)22+ has been found to shift the catalytic operating potential to more positive potentials by up to 440 mV, depending upon the conditions. The catalytic rate was found to increase by an order of magnitude by increasing the solution pH or through the addition of water. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

  17. Hydrogen for X-group exchange in CH3X, X = Cl, Br, I, OMe and NMe2 by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism

    E-Print Network [OSTI]

    Werkema, Evan

    2010-01-01T23:59:59.000Z

    Hydrogen for X-group exchange in CH 3 X, X = Cl, Br, I, OMespectrum in which a single hydrogen atom is statisticallyprobability ellipsoids. The non-hydrogen atoms are refined

  18. Ch.3 User Authentication Textbook?

    E-Print Network [OSTI]

    Dong, Yingfei

    : wall clock time · exploiting multiple password use: same passwd · electronic monitoring: keyloging

  19. ch1_General_Info

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    technology for the reuse of Carbon dioxide (CO 2 ) emissions from industrial sources for green energy products. This project would use CO 2 to grow algae for the production of...

  20. LCLS_CDR-ch06

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 - -/e),,s - 1 2 3 4 5 6 7 8 9 10 11 12 136

  1. LCLS_CDR-ch10

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 - -/e),,s - 1 2 3 4 5 6 7 8 9 10 11 12 1360 0

  2. CH-TRAMPAC Rev. 4

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T, Inc.'sEnergy Bush HydrogenEmissions and the Effects of ClimateCFCNCA

  3. ch07wrkg.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon3 TheDiscovery of5

  4. ch1_General_Info

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ . :, ,.2 MesabaCarbon3 TheDiscovery of5R

  5. INPUT/OUTPUT DEVICES AND INTERACTION TECHNIQUES Ken Hinckley, Microsoft Research

    E-Print Network [OSTI]

    Jacob, Robert J.K.

    light emitting diodes), speakers, or tactile and force feedback devices (sometimes referred to as haptic

  6. Collaborative Teleoperation via the Internet Ken Goldberg, Billy Chen, Rory Solomon, Steve Bui,

    E-Print Network [OSTI]

    Goldberg, Ken

    robot arm via the Internet. A java applet at each client streams mouse motion vectors from up to 30 receive visual feedback from a digital camera mounted above the robot arm. To our knowledge to control a single industrial robot arm. We proposed the term "collaborative teleoperation" to describe

  7. Genetic Evolution of Symbolic Signal Models Ken C. Sharman & Anna E. EsparciaAlcazar 1

    E-Print Network [OSTI]

    Fernandez, Thomas

    these three processes can be combined to yield a powerful general purpose modelling system. 1. Introduction@music.gla.ac.uk Abstract This paper reports on a novel method of signal modelling that employs a variable model structure as opposed to the fixed model structure used in conventional modelling methods. The functional form

  8. Flexible Loads in Future Energy Networks Jay Taneja, Ken Lutz, and David Culler

    E-Print Network [OSTI]

    Culler, David E.

    electrical loads in the form of a domestic refrigerator augmented with a thermal storage system and a supply re- sults show that with 10% penetration of thermal storage across refrigeration and freezer load. These types of loads, primarily refrigeration and freezer systems but also electric vehicles or rooftop ice

  9. Trap Design for Vibratory Bowl Feeders # RobertPaul Berretty +# Ken Goldberg Mark H. Overmars +

    E-Print Network [OSTI]

    Utrecht, Universiteit

    devices such as wiper blades, grooves and traps. Most of these devices are filters # Research is supported

  10. Squirrel Works Creative Inquiry, Fall 2010 Drs D. E. Stevenson and Ken Weaver, SoC

    E-Print Network [OSTI]

    Hallstrom, Jason

    developed stealth technology (U-2, SR-71, and F-117) but also had an enviable record of cost containment. Evaluating of team members; 8. Participating in project management; 9. Developing marketing materials

  11. Hydrogen and Fuel Cell Vehicle Evaluation Richard Parish, Leslie Eudy, and Ken Proc

    E-Print Network [OSTI]

    the Upper Atmospheric Research Collaboratory (UARC) [5][6], Diesel Combustion Collaboratory (DCC) [7

  12. Towards Ubiquitous Database in Mobile Commerce Kimio Kuramitsu and Ken Sakamura

    E-Print Network [OSTI]

    Madiraju, Praveen

    processor and memory for data storage. Very small DBMS implemented on them can interact through queries a set of the small-embedded database ubiquitous database. In the ubiquitous database, a very small DBMS will be attached to each real-world entity, such as goods, materials and persons. A data object on a DBMS can move

  13. Internal stress storage in shape memory polymer nanocomposites Ken Gall,a)

    E-Print Network [OSTI]

    Balzar, Davor

    shape memory polymer matrix. Although the shape memory effect is not inherent to the ceramic strain, by the inclusion of hard ceramic reinforcements.3 In the present study, we examine the storage and release of internal stress in nanometer-scale SiC ceramic reinforce- ments embedded in an amorphous active

  14. Eurographics/ IEEE-VGTC Symposium on Visualization (2007) Ken Museth, Torsten Mller, and Anders Ynnerman (Editors)

    E-Print Network [OSTI]

    the systems are also delivering data with out- put, i.e. calibrated amplitude, they can deliver fairly accuHz [ABGL06]. The sonar has un- dergone sea trials from research vessel "G. O. Sars" from December 2005

  15. Real Time Tracking of Borescope Tip Pose Ken Martin, Charles V. Stewart*

    E-Print Network [OSTI]

    . Electromagnetic fields are cor- rupted by the surrounding presence of metal. Acoustic techniques are susceptible-dimensional image coordi- nate system. It then matches each to the current borescope video image (without explicitly, or a small video camera located at the tip of the borescope and a video monitor at the other end. Borescopes

  16. A review of "Renaissance Ecology: Imagining Eden in Milton’s England" edited by Ken Hiltner 

    E-Print Network [OSTI]

    Fenton, Mary C.

    2008-01-01T23:59:59.000Z

    : The Flight Into Egypt in Renaissance Art,? Joan Blythe presents a strikingly original reading of the Nativity Ode, Paradise Lost, and Paradise Regained, by showing the how the concepts and images recurring in artistic depictions of ?The Flight into Egypt...? figure significantly in Milton?s poetry. These include Jesus? role as new Moses, the ?world view? presentation of landscape, and the pivotal importance of Mary. Primary among Blythe?s 18 illustrations are ?Flight? paintings by Joachim Patinir...

  17. Artificial Sand Pictures -A Complex Systems Simulation Brad Pearce and Ken Hawick

    E-Print Network [OSTI]

    Hawick, Ken

    recent applications still find it useful[10]. The conventional IP model is essentially parameterless model for considering migration within multi phase fluid systems. Hydrocarbons in a reservoir can hydrocarbons ­ in the form of liquid or gas ­ will migrate across the rocks and strata etc within a reservoir

  18. Mr. Ken Blower, Manager Corporate Environmental Affairs Standard Oil Company of Ohio

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7 August 2008 Office7-TACi+J-UN 2DCT i S 198?

  19. SIMULTANEOUS OBSERVATIONS OF COMET C/2002 T7 (LINEAR) WITH THE BERKELEY-ILLINOIS-MARYLAND ASSOCIATION AND OWENS VALLEY RADIO OBSERVATORY INTERFEROMETERS: HCN AND CH{sub 3}OH

    SciTech Connect (OSTI)

    Hogerheijde, Michiel R. [Leiden Observatory, Leiden University, P.O. Box 9513, 2300 RA, Leiden (Netherlands); Qi Chunhua [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); De Pater, Imke; Wright, M. C. H. [Department of Astronomy, 601 Campbell Hall, University of California at Berkeley, Berkeley, CA 94720 (United States); Blake, Geoffrey A. [Division of Geophysics and Planetary Science, MS 150-21, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125 (United States); Friedel, D. N.; Snyder, L. E. [Department of Astronomy, University of Illinois, 1002 West Green Street, Urbana, IL 61801 (United States); Forster, J. R. [Hat Creek Radio Observatory, 42231 Bidwell Road, Hat Creek, CA 96040 (United States); Palmer, Patrick [Department of Astronomy and Astrophysics, University of Chicago, 5640 South Ellis Avenue, Chicago, IL 60637 (United States); Remijan, Anthony J. [National Radio Astronomy Observatory, 520 Edgemont Rd, Charlottesville, VA 22901 (United States)], E-mail: michiel@strw.leidenuniv.nl

    2009-06-15T23:59:59.000Z

    We present observations of HCN J = 1-0 and CH{sub 3}OH J(K{sub a} , K{sub c} ) = 3(1, 3)-4(0, 4) A{sup +} emission from comet C/2002 T7 (LINEAR) obtained simultaneously with the Owens Valley Radio Observatory (OVRO) and Berkeley-Illinois-Maryland Association (BIMA) millimeter interferometers. We combined the data from both arrays to increase the (u, v) sampling and signal to noise of the detected line emission. We also report the detection of CH{sub 3}OH J(K{sub a} , K{sub c} ) = 8(0, 8)-7(1, 7) A{sup +} with OVRO data alone. Using a molecular excitation code that includes the effects of collisions with water and electrons, as well as pumping by the Solar infrared photons (for HCN alone), we find a production rate of HCN of 2.9 x 10{sup 26} s{sup -1} and for CH{sub 3}OH of 2.2 x 10{sup 27} s{sup -1}. Compared to the adopted water production rate of 3 x 10{sup 29} s{sup -1}, this corresponds to an HCN/H{sub 2}O ratio of 0.1% and a CH{sub 3}OH/H{sub 2}O ratio of 0.7%. We critically assess the uncertainty of these values due to the noise ({approx}10%), the uncertainties in the adopted comet model ({approx}50%), and the uncertainties in the adopted collisional excitation rates (up to a factor of 2). Pumping by Solar infrared photons is found to be a minor effect for HCN, because our 15'' synthesized beam is dominated by the region in the coma where collisions dominate. Since the uncertainties in the derived production rates are at least as large as one-third of the differences found between comets, we conclude that reliable collision rates and an accurate comet model are essential. Because the collisionally dominated region critically depends on the water production rate, using the same approximate method for different comets may introduce biases in the derived production rates. Multiline observations that directly constrain the molecular excitation provide much more reliable production rates.

  20. Comparison of [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+ as Electrocatalysts for H2 Production

    SciTech Connect (OSTI)

    Wiedner, Eric S.; Helm, Monte L.

    2014-09-22T23:59:59.000Z

    The complexes [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+, where PPh2NPh2 is 1,5-diphenyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane, are compared as electrocatalysts for H2 production under identical experimental conditions. With [(DMF)H]+ as the acid in acetonitrile solution, [Pd(PPh2NPh2)2]2+ afforded a turnover frequency (TOF) of 230 s-1 for formation of H2 under dry conditions and a TOF of 640 s-1 when H2O was added. These rates are similar to the TOF’s of 590 s-1 (dry) and 720 s-1 (wet) that were previously measured for [Ni(PPh2NPh2)2(CH3CN)]2+ using [(DMF)H]+. The [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+ complexes both exhibited large current enhancements when treated with trifluoroacetic acid (TFA). At a TFA concentration of 1.8 M, TOF values of 5670 s-1 and 2060 s-1 were measured for [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+, respectively. The fast rates observed using TFA are, in part, attributed to homoconjugation of TFA in acetonitrile solutions, which decreases the effective pKa of the acid. In support of this hypothesis, dramatically lower rates of H2 production were observed using p anisidinium, which has a pKa comparable to TFA but does not homoconjugate significantly in acetonitrile solutions. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is oper-ated by Battelle for the U.S. Department of Energy.