National Library of Energy BETA

Sample records for br uff br

  1. br Owner br Facility br Type br Capacity br MW br Commercial...

    Open Energy Info (EERE)

    Owner br Facility br Type br Capacity br MW br Commercial br Online br Date br Geothermal br Area br Geothermal br Region Coordinates Ahuachapan Geothermal Power Plant LaGeo SA de...

  2. BR UFF BIG PINEY WILD ROSE BLU E GAP BR UFF UNIT WAMSUT TER

    U.S. Energy Information Administration (EIA) Indexed Site

    The boundaries are not informed by subsurface structural information. The data and methods ... BIG PINEY TIP TOP BIR D CANYON SWAN FONTEN ELL E LABARGE HOGSBACK CHIMNEY BUT TE BIG PINEY ...

  3. BR UFF BIG PINEY WILD ROSE BLU E GAP BR UFF UNIT WAMSUT TER

    U.S. Energy Information Administration (EIA) Indexed Site

    BIG PINEY TIP TOP BIR D CANYON SWAN FONTEN ELL E LABARGE HOGSBACK CHIMNEY BUT TE BIG PINEY AREA TIP TOP UNI T LINCOLN ROAD BLU E FOREST DEER HILL FOGART Y CREEK GREEN RIVER BEND ...

  4. BR UFF BIG PINEY WILD ROSE BLU E GAP BR UFF UNIT WAMSUT TER

    Gasoline and Diesel Fuel Update (EIA)

    (1) and Robert King (2) (1) Z, Inc., (2) Energy Information Administration BIG PINEY TIP ... BLU E FOREST SWAN DEER HILL FOGART Y CREEK GREEN RIVER BEND DRY PINEY SWAN S HOGSBACK AREA ...

  5. BR UFF BIG PINEY WILD ROSE BLU E GAP BR UFF UNIT WAMSUT TER

    U.S. Energy Information Administration (EIA) Indexed Site

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Basin Outline ID The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by subsurface structural

  6. BR UFF BIG PINEY WILD ROSE BLU E GAP BR UFF UNIT WAMSUT TER

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Basin Outline ID The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by subsurface

  7. BR UFF BIG PINEY WILD ROSE BLU E GAP BR UFF UNIT WAMSUT TER

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquids Reserve Class No 2001 liquids reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl 10,000.1 - 100,000 Mbbl Basin Outline ID The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by subsurface structural

  8. Jatropha BR | Open Energy Information

    Open Energy Info (EERE)

    BR Jump to: navigation, search Name: Jatropha BR Place: Brazil Product: Brazilian-based consortium of five leading Brazilian companies engaged in the integrated jatropha curcas...

  9. Photoinduced Br Desorption from CsBr Thin Films Grown on Cu(100)

    SciTech Connect (OSTI)

    Halliday, Matthew T.; Joly, Alan G.; Hess, Wayne P.; Shluger, AL

    2015-10-22

    Thin films of CsBr deposited onto metals such as copper are potential photocathode materials for light sources and other applications. We investigate desorption dynamics of Br atoms from CsBr films grown on insulator (KBr, LiF) and metal (Cu) substrates induced by sub-bandgap 6.4 eV laser pulses. The experimental results demonstrate that the peak kinetic energy of Br atoms desorbed from CsBr/Cu films is much lower than that for the hyperthermal desorption from CsBr/LiF films. Kelvin probe measurements indicate negative charge at the surface following Br desorption from CsBr/Cu films. Our ab initio calculations of excitons at CsBr surfaces demonstrate that this behavior can be explained by an exciton model of desorption including electron trapping at the CsBr surface. Trapped negative charges reduce the energy of surface excitons available for Br desorption. We examine the electron-trapping characteristics of low-coordinated sites at the surface, in particular, divacancies and kink sites. We also provide a model of cation desorption caused by Franck-Hertz excitation of F centers at the surface in the course of irradiation of CsBr/Cu films. These results provide new insights into the mechanisms of photoinduced structural evolution of alkali halide films on metal substrates and activation of metal photocathodes coated with CsBr.

  10. X-ray absorption studies of mixed salt polymer electrolytes: ZnBr{sub 2}/CaBr{sub 2}-PEO, ZnBr{sub 2}/LiBr-PEO, and ZnBr{sub 2}/RbBr-PEO complexes

    SciTech Connect (OSTI)

    McBreen, J.; Yang, X.Q.; Lee, H.S.; Okamoto, Y.

    1995-02-01

    Polyethylene oxide (PEO)-salt systems are an important new class of electrolytes that are being considered for many uses. X-ray absorption (XAS) studies of ZnBr{sub 2}-PEO complexes, at the Zn K edge, at temperatures between 25 and 120 C, indicate that additions of bromide salts of Li, Rb, or Ca result in the formation of ZnBr{sub 4}{sup {minus} 2} complexes with a Zn-Br bond length of 2.42 {angstrom}. XAS, at the Rb K edge, in mixed RbBr/ZnBr{sub 2}-PEO complexes with an excess of ZnBr{sub 2}, shows that the ZnBr{sub 2} causes the RbBr to dissolve in the polymer. The Rb{sup +} ions are weakly complexed with the PEO with an Rb-O bond distance of 2.93 {angstrom}.

  11. High energy XeBr electric discharge laser

    DOE Patents [OSTI]

    Sze, Robert C.; Scott, Peter B.

    1981-01-01

    A high energy XeBr laser for producing coherent radiation at 282 nm. The XeBr laser utilizes an electric discharge as the excitation source to minimize formation of molecular ions thereby minimizing absorption of laser radiation by the active medium. Additionally, HBr is used as the halogen donor which undergoes harpooning reactions with Xe.sub.M * to form XeBr*.

  12. High energy XeBr electric discharge laser

    DOE Patents [OSTI]

    Sze, R.C.; Scott, P.B.

    A high energy XeBr laser for producing coherent radiation at 282 nm is disclosed. The XeBr laser utilizes an electric discharge as the excitation source to minimize formation of molecular ions thereby minimizing absorption of laser radiation by the active medium. Additionally, HBr, is used as the halogen donor which undergoes harpooning reactions with Xe/sub M/ to form XeBr.

  13. Improved production of Br atoms near zero speed by photodissociating laser aligned Br{sub 2} molecules

    SciTech Connect (OSTI)

    Deng, L. Z., E-mail: lzdeng@phy.ecnu.edu.cn; Yin, J. P., E-mail: jpyin@phy.ecnu.edu.cn [State Key Laboratory of Precision Spectroscopy, Department of Physics, East China Normal University, Shanghai 200062 (China)

    2014-10-28

    We theoretically investigated the improvement on the production rate of the decelerated bromine (Br) atoms near zero speed by photodissociating laser aligned Br{sub 2} precursors. Adiabatic alignment of Br{sub 2} precursors exposed to long laser pulses with duration on the order of nanoseconds was investigated by solving the time-dependent Schrdinger equation. The dynamical fragmentation of adiabatically aligned Br{sub 2} precursors was simulated and velocity distribution of the Br atoms produced was analyzed. Our study shows that the larger the degree of the precursor alignment, ?cos{sup 2}???, the higher the production rate of the decelerated Br atoms near zero speed. For Br{sub 2} molecules with an initial rotational temperature of ?1 K, a ?cos{sup 2}??? value of ?0.88 can result in an improvement factor of over ?20 on the production rate of the decelerated Br atoms near zero speed, requiring a laser intensity of only ?1 10{sup 12} W/cm{sup 2} for alignment.

  14. Preliminary upper limit on BR(D{sup {+-}}{r_arrow}{pi}{sup {...

    Office of Scientific and Technical Information (OSTI)

    Preliminary upper limit on BR(Dsup +-rarrowpisup +-musup +musup -) Citation Details In-Document Search Title: Preliminary upper limit on BR(Dsup ...

  15. Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Doty, F. Patrick; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Josh; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  16. Photoelectron Emission Studies in CsBr at 257 nm

    SciTech Connect (OSTI)

    Maldonado, Juan R.; Liu, Zhi; Sun, Yun; Pianetta, Piero A.; Pease, Fabian W.; /Stanford U., Elect. Eng. Dept. /SLAC, SSRL

    2006-09-28

    CsBr/Cr photocathodes were found [1,2] to meet the requirements of a multi-electron beam lithography system operating with a light energy of 4.8 eV (257nm). The fact that photoemission was observed with a light energy below the reported 7.3 eV band gap for CsBr was not understood. This paper presents experimental results on the presence of intra-band gap absorption sites (IBAS) in CsBr thin film photo electron emitters, and presents a model based on IBAS to explain the observed photoelectron emission behavior at energies below band gap. A fluorescence band centered at 330 nm with a FWHM of about 0.34 eV was observed in CsBr/Cr samples under 257 nm laser illumination which can be attributed to IBAS and agrees well with previously obtained synchrotron photoelectron spectra[1] from the valence band of CsBr films.

  17. Decommissioning of the BR3 reactor: status and perspectives

    SciTech Connect (OSTI)

    Noynaert, L.; Verstraeten, I.

    2007-07-01

    The BR3 plant at Mol in Belgium built at the end of the fifties was the first PWR plant built outside the USA. The reactor had a small net power output (10 MWe) but comprised all the loops and features of a commercial PWR plant. The BR3 plant was operated with the main objective of testing advanced PWR fuels under irradiation conditions similar to those encountered in large commercial PWR plants. The reactor was started in 1962 and shut down in 1987 after 25 years of continuous operation. Since 1989, SCK.CEN is decommissioning the BR3 PWR research reactor. The dismantling of the metallic components including reactor pressure vessel and internals is completed and extensively reported in the literature. The dismantling of auxiliary components and the decontamination of parts of the infrastructure are now going on. The decommissioning progress is continuously monitored and costs and strategy are regularly reassessed. The first part of the paper describes the main results and lessons learned from the reassessment exercises performed in 1994, 1999, 2004 and 2007. Impacts of changes in legal framework on the decommissioning costs will be addressed. These changes concern e.g. licensing aspects, clearance levels, waste management... The middle part of the paper discusses the management of activated and/or contaminated concrete. The costing exercise performed in 1995 highlighted that the management of activated and contaminated concrete is the second main cost item after the dismantling of the reactor pressure vessel and internals. Different possible solutions were studied. These are evacuation as radioactive waste with or without supercompaction, recycling this 'radioactive' grout or concrete for conditioning of radioactive waste e.g. conditioning of metallic waste. The paper will give the results of the cost-benefit analysis made to select the solution retained. The last part of the paper will discuss the end goal of the decommissioning of the BR3. In the final decommissioning plan approved by ONDRAF/NIRAS, it was mentioned that the final goal of the BR3 decommissioning will be the 'green field' unless opportunities for reuse of the BR3 site will occur during decommissioning. A strategy of partial reuse of the BR3 facility is proposed and being discussed with the main stakeholders. The paper will give the present state of the discussion. (authors)

  18. A preliminary report on the photoionization efficiency spectrum, ionization energy and heat of formation of Br{sub 2}O; and the appearance energy of BrO{sup +} (Br{sub 2}O)

    SciTech Connect (OSTI)

    Thorn, R.P. Jr.; Monks, P.S.; Stief, L.J.; Kuo, S.C.; Zhang, Z.; Klemm, R.B.

    1995-08-01

    We report experimental results for the photoionization efficiency (PIE) spectrum of Br{sub 2}O along with the ionization energy (derived form the ionization threshold) and the appearance energy (AE) of BrO{sup +} (Br{sub 2}O). A value for the heat of formation of Br{sub 2}O is derived form the AE result. Experiments were performed by employing a discharge flow-photoionization mass spectrometer (DF-PIMS) apparatus coupled to beamline U-11 at the National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory.

  19. High gradient rf gun studies of CsBr photocathodes

    SciTech Connect (OSTI)

    Vecchione, Theodore; Maldonado, Juan R.; Gierman, Stephen; Corbett, Jeff; Hartmann, Nick; Pianetta, Piero A.; Hesselink, Lambertus; Schmerge, John F.

    2015-04-03

    CsBr photocathodes have 10 times higher quantum efficiency with only 3 times larger intrinsic transverse emittance than copper. They are robust and can withstand 80 MV/m fields without breaking down or emitting dark current. They can operate in 210?? torr vacuum and survive exposure to air. They are well suited for generating high pulse charge in rf guns without a photocathode transfer system.

  20. High gradient rf gun studies of CsBr photocathodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vecchione, Theodore; Maldonado, Juan R.; Gierman, Stephen; Corbett, Jeff; Hartmann, Nick; Pianetta, Piero A.; Hesselink, Lambertus; Schmerge, John F.

    2015-04-03

    CsBr photocathodes have 10 times higher quantum efficiency with only 3 times larger intrinsic transverse emittance than copper. They are robust and can withstand 80 MV/m fields without breaking down or emitting dark current. They can operate in 2×10⁻⁹ torr vacuum and survive exposure to air. They are well suited for generating high pulse charge in rf guns without a photocathode transfer system.

  1. AmeriFlux BR-Sa3 Santarem-Km83-Logged Forest

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Goulden, Mike [University of California - Irvine

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site BR-Sa3 Santarem-Km83-Logged Forest. Site Description - Cleared forest. Logged site is near km 83 along BR-183.

  2. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP...

  3. Improved Growth Methods for LaBr3 Scintillation Radiation Detectors

    SciTech Connect (OSTI)

    McGregor, Douglas S

    2011-05-01

    The objective is to develop advanced materials for deployment as high-resolution gamma ray detectors. Both LaBr3 and CeBr3 are advanced scintillation materials, and will be studied in this research. Prototype devices, in collaboration Sandia National Laboratories, will be demonstrated along with recommendations for mass production and deployment. It is anticipated that improved methods of crystal growth will yield larger single crystals of LaBr3 for deployable room-temperature operated gamma radiation spectrometers. The growth methods will be characterized. The LaBr3 and CeBr3 scintillation crystals will be characterized for light yield, spectral resolution, and for hardness.

  4. Natural Organobromine in Marine Sediments: New Evidence of Biogeochemical Br Cycling

    SciTech Connect (OSTI)

    A Leri; J Hakala; M Marcus; A Lanzirotti; C Reddy; S Myneni

    2011-12-31

    Organobromine (Br{sub org}) compounds, commonly recognized as persistent, toxic anthropogenic pollutants, are also produced naturally in terrestrial and marine systems. Several enzymatic and abiotic bromination mechanisms have been identified, as well as an array of natural Br{sub org} molecules associated with various marine organisms. The fate of the carbon-bromine functionality in the marine environment, however, remains largely unexplored. Oceanographic studies have noted an association between bromine (Br) and organic carbon (C{sub org}) in marine sediments. Even so, there has been no direct chemical evidence that Br in the sediments exists in a stable form apart from inorganic bromide (Br{sub inorg}), which is widely presumed conservative in marine systems. To investigate the scope of natural Br{sub org} production and its fate in the environment, we probed Br distribution and speciation in estuarine and marine sediments using in situ X-ray spectroscopy and spectromicroscopy. We show that Br{sub org} is ubiquitous throughout diverse sedimentary environments, occurring in correlation with C{sub org} and metals such as Fe, Ca, and Zn. Analysis of sinking particulate carbon from the seawater column links the Br{sub org} observed in sediments to biologically produced Br{sub org} compounds that persist through humification of natural organic matter (NOM). Br speciation varies with sediment depth, revealing biogeochemical cycling of Br between organic and inorganic forms as part of the burial and degradation of NOM. These findings illuminate the chemistry behind the association of Br with Corg in marine sediments and cast doubt on the paradigmatic classification of Br as a conservative element in seawater systems.

  5. Novel visible-light AgBr/Ag?PO? hybrids photocatalysts with surface plasma resonance effects

    SciTech Connect (OSTI)

    Wang, Yunfang Li, Xiuli; Wang, Yawen; Fan, Caimei

    2013-06-01

    Three kinds of AgBr/Ag?PO? hybrids were synthesised via an anion-exchange precipitation method and characterised by XRD, XPS, SEM, EDS, and UVvis. The results showed that AgBr/Ag?PO? hybrids displayed much higher photocatalytic activities than single Ag?PO? or AgBr under visible light (?>420 nm), and OH and h? were the major active species during the degradation process. Considering interstitial ions Ag?? on lattice gap of AgBr are easy to become sliver particle, we deduced the possible photocatalytic mechanism could be ascribed to the synergistic effects of the appropriate valence band position of Ag?PO? and AgBr, surface plasmon resonance effect of Ag?, reactive radical species Br?, and the Ag vacancy on the surface of catalysts. - Graphical abstract: The optical absorption and structural morphology of the as-prepared AgBr@Ag?PO? photocatalyst using an anion-exchange precipitation method are conductive to the photocatalytic degradation of organics in water. Highlights: Novel AgBr/Ag?PO? hybrids are synthesised by a facile method. AgBr/Ag?PO? hybrids show excellent photocatalytic activities under visible light. Interstitial ions are in favour of the formation of Ag particle. Surface plasmon resonance effect plays a key factor for light absorption. The photocatalytic mechanism for AgBr/Ag?PO? hybrids is studied.

  6. Apparatus for improving the working time of the XeBr laser

    DOE Patents [OSTI]

    Sander, R.K.; Balog, G.; Seegmiller, E.T.

    1980-03-04

    In XeBr lasers which make use of HBr as the source of bromine, it has been found that the working life of the laser is limited because of dissociation of the HBr in the lasing region to form H/sub 2/ and Br/sub 2/. Accordingly, apparatus is disclosed for substantially improving the working time of the XeBr laser wherein means are provided for recombining H/sub 2/ and Br/sub 2/ into HBr and for continuously circulating the gaseous working medium from the lasing region through the recombination region.

  7. Apparatus for improving the working time of the XeBr laser

    DOE Patents [OSTI]

    Sander, Robert K.; Balog, George; Seegmiller, Emma T.

    1982-01-01

    In XeBr lasers which make use of HBr as the source of bromine, it has been found that the working life of the laser is limited because of dissociation of the HBr in the lasing region to form H.sub.2 and Br.sub.2. Accordingly, apparatus is disclosed for substantially improving the working time of the XeBr laser wherein means are provided for recombining H.sub.2 and Br.sub.2 into HBr and for continuously circulating the gaseous working medium from the lasing region through the recombination region. BACKGROUND OF THE INVENTION

  8. X-ray photoemission analysis of chemically modified TlBr surfaces for improved radiation detectors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nelson, A. J.; Voss, L. F.; Beck, P. R.; Graff, R. T.; Conway, A. M.; Nikolic, R. J.; Payne, S. A.; Lee, J. -S.; Kim, H.; Cirignano, L.; et al

    2013-01-12

    We subjected device-grade TlBr to various chemical treatments used in room temperature radiation detector fabrication to determine the resulting surface composition and electronic structure. As-polished TlBr was treated separately with HCl, SOCl2, Br:MeOH and HF solutions. High-resolution photoemission measurements on the valence band electronic structure and Tl 4f, Br 3d, Cl 2p and S 2p core lines were used to evaluate surface chemistry and shallow heterojunction formation. Surface chemistry and valence band electronic structure were correlated with the goal of optimizing the long-term stability and radiation response.

  9. Performance of LiAlloy/Ag(2)CrO(4) Couples in Molten CsBr-LiBr-KBr Eutectic

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    1999-10-18

    The performance of Li-alloy/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} systems was studied over a temperature range of 250 C to 300 C, for possible use as a power source for geothermal borehole applications. Single cells were discharged at current densities of 15.8 and 32.6 mA/cm{sup 2} using Li-Si and Li-Al anodes. When tested in 5-cell batteries, the Li-Si/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} system exhibited thermal runaway. Thermal analytical tests showed that the Ag{sub 2}CrO{sub 4} cathode reacted exothermically with the electrolyte on activation. Consequently, this system would not be practical for the envisioned geothermal borehole applications.

  10. Results for aliovalent doping of CeBr{sub 3} with Ca{sup 2+}

    SciTech Connect (OSTI)

    Guss, Paul; Foster, Michael E.; Wong, Bryan M.; Patrick Doty, F.; Shah, Kanai; Squillante, Michael R.; Shirwadkar, Urmila; Hawrami, Rastgo; Tower, Joshua; Yuan, Ding

    2014-01-21

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr{sub 3}) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca{sup 2+}) was used as a dopant to strengthen CeBr{sub 3} without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca{sup 2+} dopant were grown, i.e., 1.9% of the CeBr{sub 3} molecules were replaced by CaBr{sub 2} molecules, to match our target replacement of 1 out of 54 cerium atoms be replaced by a calcium atom. Precisely the mixture was composed of 2.26 g of CaBr{sub 2} added to 222.14 g of CeBr{sub 3}. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca{sup 2+}-doped CeBr{sub 3} exhibited little or no change in the peak fluorescence emission for 371?nm optical excitation for CeBr{sub 3}. The structural, electronic, and optical properties of CeBr{sub 3} crystals were studied using the density functional theory within the generalized gradient approximation. Calculated lattice parameters are in agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr{sub 3}, including the dielectric function, were calculated.

  11. Characterization of the LiSi/CsBr-LiBr-KBr/FeS(2) System for Potential Use as a Geothermal Borehole Power Source

    SciTech Connect (OSTI)

    GUIDOTTI, RONALD A.; REINHARDT, FREDERICK W.

    1999-10-18

    We are continuing to study the suitability of modified thermal-battery technology as a potential power source for geothermal borehole applications. Previous work focused on the LiSi/FeS{sub 2} couple over a temperature range of 350 C to 400 C with the LiBr-KBr-LiF eutectic, which melts at 324.5 C. In this work, the discharge processes that take place in LiSi/CsBr-LiBr-KBr eutectic/FeS{sub 2} thermal cells were studied at temperatures between 250 C and 400 C using pelletized cells with immobilized electrolyte. The CsBr-LiBr-KBr eutectic was selected because of its lower melting point (228.5 C). Incorporation of a quasi-reference electrode allowed the determination of the relative contribution of each electrode to the overall cell polarization. The results of single-cell tests and limited battery tests are presented, along with preliminary data for battery stacks tested in a simulated geothermal borehole environment.

  12. Studies on Ca2+-Doped CeBr3 Scintillating Materials

    SciTech Connect (OSTI)

    Guss, P. [NSTec; Foster, M. E. [SNL; Wong, B. M. [SNL; Doty, F. P. [SNL; Shah, K. [RMD; Squillante, M. [RMD; Glodo, J. [RMD; Yuan, D. [NSTec

    2013-07-03

    Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide (LaBr3:Ce), their commercial availability and application is limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. The objective of this investigation was to employ aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was investigated as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were investigated using the density functional theory within generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.

  13. Structure and properties of electronic and hole centers in CsBr from theoretical calculations

    SciTech Connect (OSTI)

    Halliday, Matthew T.; Hess, Wayne P.; Shluger, Alexander L.

    2015-06-24

    The electronic structure, geometry, diffusion barriers and optical properties of fundamental defects of CsBr are calculated using hybrid functional DFT and TD- DFT methods. The B3LYP functional with a modified exchange contribution has been used in an embedded cluster scheme to model the structure and spectroscopic properties of self-trapped triplet exciton, interstitial Br atoms and ions, self-trapped holes and Br vacancies. The calculated migration barriers and positions of maxima of optical absorption bands are in good agreement with experiment, justifying the obtained defect geometries. The o*-center triplet exciton luminescence energy is also accurately calculated.

  14. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications, April 2005 | Department of Energy Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 The objective of this paper is to summarize the development status of air-cooled lithium bromide (LiBr)-water absorption chillers to guide future efforts to develop chillers for combined heat and power (CHP) applications in light-commercial buildings. The key

  15. Measurement of the Ratio of Branching Fractions Br(Bs -> Ds- pi+)/Br(B -> D- pi+) at CDF-II

    SciTech Connect (OSTI)

    Furic, Ivan Kresimir; /MIT

    2004-03-01

    The measurement of B{sub s}{sup 0} mixing is one of the flagship analyses for the Run II B physics program. The sensitivity of the measurement to the frequency of B{sub s}{sup 0} oscillations strongly depends on the number of reconstructed B{sub s}{sup 0} mesons. They present the measurement of the ratio of branching fractions Br(B{sub s}{sup 0} {yields} D{sub s}{sup -}{pi}{sup +})/Br(B{sup 0} {yields} D{sup -}{pi}{sup +}), which directly influences the number of B{sub s}{sup 0} events available for the measurement of B{sub s}{sup 0} mixing at CDF-II. They analyze 115 pb{sup -1} of data collected with the CDF-II detector in p{bar p} collisions at {radical}s = 1.96 TeV using a novel displaced track trigger. They reconstruct 78 {+-} 11 B{sub s}{sup 0} {yields} D{sub s}{sup -}{pi}{sup +} decays at 1153 {+-} 45 B{sup 0} {yields} D{sup -}{pi}{sup +} decays with good signal to background ratio. This is the world's largest sample of fully reconstructed B{sub s}{sup 0} {yields} D{sub s}{sup -}{pi}{sup +} decays. They find the ratio of production fractions multiplied by the ratio of branching fractions to be: f{sub s}/f{sub d} {center_dot} Br(B{sub s}{sup 0} {yields} D{sub s}{sup -}{pi}{sup +})/Br(B{sup 0} {yields} D{sup -}{pi}{sup +}) = 0.325 {+-} 0.046(stat) {+-} 0.034(syst) {+-} 0.084 (BR). Using the world average value of f{sub s}/f{sub d} = 0.26 {+-} 0.03, we infer that the ratio of branching fractions is: Br(B{sub s}{sup 0} {yields} D{sub s}{sup -}{pi}{sup +})/Br(B{sup 0} {yields} D{sup -}{pi}{sup +}) = 1.25 {+-} 0.18(stat) {+-} 0.13(syst) {+-} 0.32(BR) {+-} 0.14(PR) where the last uncertainty is due to the uncertainty on the world average measurement of the ratio of B{sub s}{sup 0} to B{sup 0} production rates, f{sub s}/f{sub d}.

  16. LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON

    U.S. Energy Information Administration (EIA) Indexed Site

    81 81 LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON CALEDONIA HURON C REEK LEIC EST ER COL DEN ASH FORD INDIAN FALLS LAWTONS SAR DINIA RPD-037 -2 ...

  17. Measurement of BR(Bu to phi K)/BR(Bu to J/psi K) at the collider detector at Fermilab

    SciTech Connect (OSTI)

    Napora, Robert A

    2004-10-01

    This thesis presents evidence for the decay mode B{sup {+-}} {yields} {phi}K{sup {+-}} in p{bar p} collisions at {radical}s = 1.96 TeV using (120 {+-} 7)pb{sup -1} of data collected by the Collider Detector at Fermilab (CDF). This signal is then used to measure the branching ratio relative to the decay mode B{sup {+-}} {yields} J/{psi}K{sup {+-}}. The measurement starts from reconstructing the two decay modes: B{sup {+-}} {yields} {phi}K{sup {+-}}, where {phi} {yields} K{sup +}K{sup -} and B{sup {+-}} {yields} J/{psi}K{sup {+-}}, where J/{psi} {yields} {mu}{sup +}{mu}{sup -}. The measurement yielded 23 {+-} 7 B{sup {+-}} {yields} {phi}K{sup {+-}} events, and 406 {+-} 26 B{sup {+-}} {yields} J/{psi}K{sup {+-}} events. The fraction of B{sup {+-}} {yields} J/{psi}K{sup {+-}} events where the J/{psi} subsequently decayed to two muons (as opposed to two electrons) was found to be f{sub {mu}{mu}} = 0.839 {+-} 0.066. The relative branching ratio of the two decays is then calculated based on the equation: BR(B{sup {+-}} {yields} {phi}K{sup {+-}})/BR(B{sup {+-}} {yields} J/{psi}K{sup {+-}}) = N{sub {phi}K}/N{sub {psi}K} {center_dot}f{sub {mu}{mu}} BR(J/{psi} {yields} {mu}{sup +}{mu}{sup -})/BR({phi} {yields} K{sup +}K{sup -}) {epsilon}{sub {mu}{mu}}K/{epsilon}KKK R({epsilon}{sub iso}). The measurement finds BR(B{sup {+-}} {yields} {phi}K{sup {+-}})/BR(B{sup {+-}} {yields} J/{psi}K{sup {+-}}) = 0.0068 {+-} 0.0021(stat.) {+-} 0.0007(syst.). The B{sup {+-}} {yields} {phi}K{sup {+-}} branching ratio is then found to be BR(B{sup {+-}} {yields} {phi}K{sup {+-}}) = [6.9 {+-} 2.1(stat.) {+-} 0.8(syst.)] x 10{sup -6}. This value is consistent with similar measurements reported by the e{sup +}e{sup -} collider experiments BaBar[1], Belle[2], and CLEO[3].

  18. Lattice dynamics in perovskite halides CsSn X 3 with X = I , Br , Cl

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Lattice dynamics in perovskite halides CsSn X 3 with X = I , Br , Cl « Prev Next » Title: Lattice dynamics in perovskite halides CsSn X 3 with X = I , Br , Cl Authors: Huang, Ling-yi ; Lambrecht, Walter R. L. Publication Date: 2014-11-05 OSTI Identifier: 1180124 Grant/Contract Number: ER 46874-SC0008933 Type: Publisher's Accepted Manuscript Journal Name: Physical Review B Additional Journal Information: Journal Volume: 90; Journal Issue: 19; Journal ID: ISSN

  19. Very fast doped LaBr.sub.3 scintillators and time-of-flight PET

    DOE Patents [OSTI]

    Shah, Kanai S.

    2006-10-31

    The present invention concerns very fast scintillator materials capable of resolving the position of an annihilation event within a portion of a human body cross-section. In one embodiment, the scintillator material comprises LaBr.sub.3 doped with cerium. Particular attention is drawn to LaBr.sub.3 doped with a quantity of Ce that is chosen for improving the timing properties, in particular the rise time and resultant timing resolution of the scintillator, and locational capabilities of the scintillator.

  20. LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON

    U.S. Energy Information Administration (EIA) Indexed Site

    81 § ¨ ¦ 81 LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON CALEDONIA HURON C REEK LEIC EST ER COL DEN ASH FORD INDIAN FALLS LAWTONS SAR DINIA RPD-037 -2 GLENWOOD PU LASKI PAVILION CON CORD COL LINS N ELM A ORC HARD PARK-H AMBU RG DANLEY CORNERS ST ILLWAT ER CHAFF EE-ARCAD E FAYETT E-WATERLOO LAKEVIEW JAVA SEN EC A W ELLER Y AU RORA E ZOAR BU FFALO TIOGA SILVER LAKE AKR ON ROM E RAT HBON E ALM A BET HANY WYOMING ULYSSES BR ANCH W SAN DY CREEK COL LINS BLOOMFIELD E LEBANON

  1. Oxidation/Reduction Reactions at the Metal Contact-TlBr Interface: An X-ray

    Office of Scientific and Technical Information (OSTI)

    Photoelectron Spectroscopy Study (Conference) | SciTech Connect Conference: Oxidation/Reduction Reactions at the Metal Contact-TlBr Interface: An X-ray Photoelectron Spectroscopy Study Citation Details In-Document Search Title: Oxidation/Reduction Reactions at the Metal Contact-TlBr Interface: An X-ray Photoelectron Spectroscopy Study Authors: Nelson, A J ; Swanberg, E L ; Voss, L F ; Graff, R T ; Conway, A M ; Nikolic, R J ; Payne, S A ; Kim, H ; Cirignano, L ; Shah, K Publication Date:

  2. CALiPER Application Summary Report 16. LED BR30 and R30 Lamps

    SciTech Connect (OSTI)

    none,

    2012-07-01

    This report analyzes the independently tested performance of 13 LED products labeled as BR30 or R30 lamps. The test results indicate substantial improvement versus earlier CALiPER testing of similar products, and performance comparable to recent data from LED Lighting Facts and ENERGY STAR.

  3. Hydrogen for X-group exchange in CH3X, X = Cl, Br, I, OMe and...

    Office of Scientific and Technical Information (OSTI)

    Hydrogen for X-group exchange in CH3X, X Cl, Br, I, OMe and NMe2 byMonomeric 1,2,4-(Me3C)3C5H22CeH: Experimental and Computational Support for a Carbenoid Mechanism Citation ...

  4. Geothermal br Resource br Area Geothermal br Resource br Area...

    Open Energy Info (EERE)

    Aluto Langano Geothermal Area Aluto Langano Geothermal Area East African Rift System Ethiopian Rift Valley Major Normal Fault Basalt MW K Amatitlan Geothermal Area Amatitlan...

  5. Investigation into Nanostructured Lanthanum Halides and CeBr{sub 3} for Nuclear Radiation Detection

    SciTech Connect (OSTI)

    Guss, P., Guise, R., Mukhopadhyay, S., Yuan, D.

    2011-06-22

    This slide-show presents work on radiation detection with nanostructured lanthanum halides and CeBr{sub 3}. The goal is to extend the gamma energy response on both low and high-energy regimes by demonstrating the ability to detect low-energy x-rays and relatively high-energy activation prompt gamma rays simultaneously using the nano-structured lanthanum bromide, lanthanum fluoride, cerium bromide, or other nanocrystal material. Homogeneous and nano structure cases are compared.

  6. Optimization of electrode characteristics for the Br-2/H-2 redox flow cell

    SciTech Connect (OSTI)

    Tucker, MC; Cho, KT; Weber, AZ; Lin, GY; Nguyen, TV

    2014-10-17

    The Br-2/H-2 redox flow cell shows promise as a high-power, low-cost energy storage device. The effect of various aspects of material selection, processing, and assembly of electrodes on the operation, performance, and efficiency of the system is determined. In particular, (+) electrode thickness, cell compression, hydrogen pressure, and (-) electrode architecture are investigated. Increasing hydrogen pressure and depositing the (-) catalyst layer on the membrane instead of on the carbon paper backing layers have a large positive impact on performance, enabling a limiting current density above 2 A cm(-2) and a peak power density of 1.4 W cm(-2). Maximum energy efficiency of 79 % is achieved. In addition, the root cause of limiting-current behavior in this system is elucidated, where it is found that Br- reversibly adsorbs at the Pt (-) electrode for potentials exceeding a critical value, and the extent of Br- coverage is potential-dependent. This phenomenon limits maximum cell current density and must be addressed in system modeling and design. These findings are expected to lower system cost and enable higher efficiency.

  7. Optimization of electrode characteristics for the Br?/H? redox flow cell

    SciTech Connect (OSTI)

    Tucker, Michael C.; Cho, Kyu Taek; Weber, Adam Z.; Lin, Guangyu; Van Nguyen, Trung

    2015-01-01

    The Br?/H? redox flow cell shows promise as a high-power, low-cost energy storage device. The effect of various aspects of material selection, processing, and assembly of electrodes on the operation, performance, and efficiency of the system is determined. In particular, (+) electrode thickness, cell compression, hydrogen pressure, and () electrode architecture are investigated. Increasing hydrogen pressure and depositing the () catalyst layer on the membrane instead of on the carbon-paper backing layers have a large positive impact on performance, enabling a limiting current density above 2 A cm-2 and a peak power density of 1.4 W cm-2. Maximum energy efficiency of 79% is achieved. In addition, the root cause of limiting-current behavior in this system is elucidated, where it is found that Br- reversibly adsorbs at the Pt () electrode for potentials exceeding a critical value, and the extent of Br- coverage is potential-dependent. This phenomenon limits maximum cell current density and must be addressed in system modeling and design. These findings are expected to lower system cost and enable higher efficiency.

  8. A modified Stillinger-Weber potential for TlBr and its polymorphic extension

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Xiaowang; Foster, Michael E.; Jones, Reese E.; Doty, F. Patrick; Yang, Pin; Fan, Hongyou

    2015-04-30

    TlBr is promising for g- and x- radiation detection, but suffers from rapid performance degradation under the operating external electric fields. To enable molecular dynamics (MD) studies of this degradation, we have developed a Stillinger-Weber type of TlBr interatomic potential. During this process, we have also addressed two problems of wider interests. First, the conventional Stillinger-Weber potential format is only applicable for tetrahedral structures (e.g., diamond-cubic, zinc-blende, or wurtzite). Here we have modified the analytical functions of the Stillinger-Weber potential so that it can now be used for other crystal structures. Second, past modifications of interatomic potentials cannot always bemore » applied by a broad community because any new analytical functions of the potential would require corresponding changes in the molecular dynamics codes. Here we have developed a polymorphic potential model that simultaneously incorporates Stillinger-Weber, Tersoff, embedded-atom method, and any variations (i.e., modified functions) of these potentials. As a result, we have implemented this polymorphic model in MD code LAMMPS, and demonstrated that our TlBr potential enables stable MD simulations under external electric fields.« less

  9. Response of LaBr{sub 3}(Ce) scintillators to 2.5 MeV fusion neutrons

    SciTech Connect (OSTI)

    Cazzaniga, C.; Nocente, M.; Gorini, G.; Istituto di Fisica del Plasma, Associazione EURATOM-ENEA-CNR, Via Roberto Cozzi 53, Milano 20125 ; Tardocchi, M.; Croci, G.; Giacomelli, L.; Angelone, M.; Pillon, M.; Villari, S.; Weller, A.; Petrizzi, L.; Collaboration: ASDEX Upgrade Team; JET-EFDA Contributors

    2013-12-15

    Measurements of the response of LaBr{sub 3}(Ce) to 2.5 MeV neutrons have been carried out at the Frascati Neutron Generator and at tokamak facilities with deuterium plasmas. The observed spectrum has been interpreted by means of a Monte Carlo model. It is found that the main contributor to the measured response is neutron inelastic scattering on {sup 79}Br, {sup 81}Br, and {sup 139}La. An extrapolation of the count rate response to 14 MeV neutrons from deuterium-tritium plasmas is also presented. The results are of relevance for the design of ?-ray diagnostics of fusion burning plasmas.

  10. Characterization of low-melting electrolytes for potential geothermal borehole power supplies: The LiBr-KBr-LiF eutectic

    SciTech Connect (OSTI)

    Guidotti, R.A.; Reinhardt, F.W.

    1998-05-01

    The suitability of modified thermal-battery technology for use as a potential power source for geothermal borehole applications is under investigation. As a first step, the discharge processes that take place in LiSi/LiBr-KBr-LiF/FeS{sub 2} thermal cells were studied at temperatures of 350 C and 400 C using pelletized cells with immobilized electrolyte. Incorporation of a reference electrode allowed the relative contribution of each electrode to the overall cell polarization to be determined. The results of single-cell tests are presented, along with preliminary data for cells based on a lower-melting CsBr-LiBr-KBr eutectic salt.

  11. Measurement of ratio R = (BR(D{sup 0}{yields}K{pi}{pi}{pi})/BR(D{sup 0}{yields}K{pi})) in {pi}{sup -}-Nucleus interactions at 500 GeV/c

    SciTech Connect (OSTI)

    Solano Salinas, C. J.; Paucarchuco, C.; Fernandez, A.; Sheaff, M.

    2007-10-26

    We report a very preliminary result on the measurement of the ratio of branching ratios, for two decays D{sup 0} meson, R = (BR(D{sup 0}{yields}K{pi}{pi}{pi})/BR(D{sup 0}{yields}K{pi})), using data from the E791 experiment. We find R = 1.96{+-}0.0286 (stat){+-}0.06 (sys). This is in agreement with and of similar precision to the current PDG average value 1.97{+-}0.09.

  12. Br-rich Tips of Calcified Crab Claws are Less Hard but More Fracture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resistant: A Comparison of Mineralized and Heavy-element Biological Materials Br-rich Tips of Calcified Crab Claws are Less Hard but More Fracture Resistant: A Comparison of Mineralized and Heavy-element Biological Materials figure 1 Figure 1. The heavy element biomaterial is the darker material at the tip of the shore crab claws. Figure "b" shows the same claw as "a" but after bead blasting. The claw tips are less eroded by the bead blasting than surrounding calcified

  13. High temperature crystal structures and superionic properties of SrCl{sub 2}, SrBr{sub 2}, BaCl{sub 2} and BaBr{sub 2}

    SciTech Connect (OSTI)

    Hull, Stephen; Norberg, Stefan T.; Ahmed, Istaq; Eriksson, Sten G.; Mohn, Chris E.

    2011-11-15

    The structural properties of the binary alkaline-earth halides SrCl{sub 2}, SrBr{sub 2}, BaCl{sub 2} and BaBr{sub 2} have been investigated from ambient temperature up to close to their melting points, using the neutron powder diffraction technique. Fluorite-structured SrCl{sub 2} undergoes a gradual transition to a superionic phase at 900-1100 K, characterised by an increasing concentration of anion Frenkel defects. At a temperature of 920(3) K, the tetragonal phase of SrBr{sub 2} undergoes a first-order transition to a cubic fluorite phase. This high temperature phase shows the presence of extensive disorder within the anion sublattice, which differs from that found in superionic SrCl{sub 2}. BaCl{sub 2} and BaBr{sub 2} both adopt the cotunnite crystal structure under ambient conditions. BaCl{sub 2} undergoes a first-order structural transition at 917(5) K to a disordered fluorite-structured phase. The relationship between the (disordered) crystal structures and the ionic conductivity behaviour is discussed and the influence of the size of the mobile anion on the superionic behaviour is explored. - Graphical abstract: Anomalous behaviour of the lattice expansion of SrCl{sub 2} at temperatures of {approx}1000 K is associated with the gradual transition to a superionic phase, whilst SrBr{sub 2} undergoes a first-order structural transition ({beta}{yields}{alpha}) to a fluorite-structured superionic phase at 920(3) K. Highlights: > Anomalous behaviour of the lattice expansion of SrCl{sub 2} occurs at temperatures {approx}1000 K. > Crystal structure of {beta}-SrBr{sub 2} is described in detail. > On heating, SrBr{sub 2} and BaCl{sub 2} transform to a fluorite-structured superionic phase. > Temperature dependence of the BaCl{sub 2} and BaBr{sub 2} structures is presented. > Nature of the superionic phases within the alkaline-earth halides is discussed.

  14. LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery

    DOE Patents [OSTI]

    Ko, Suk M.

    1980-01-01

    This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

  15. X-ray-absorption study of CuBr at high pressure

    SciTech Connect (OSTI)

    Tranquada, J.M.; Ingalls, R.

    1986-09-15

    The x-ray-absorption spectrum of cuprous bromide has been measured as a function of pressure. The x-ray-absorption near-edge structure proved to be an excellent indicator of high-pressure phase transitions in this material. The normalized ''white-line'' peak heights at both the Cu and Br K-italic edges decreased on entering the tetragonal phase and increased in going to the NaCl structure. The zinc-blende to tetragonal phase transition took place over a very narrow pressure range centered at 46 +- 5 kbar. The transformation from the tetragonal to the NaCl structure, on the other hand, showed a broad mixed-phase region, suggesting a nucleation-and-growth mechanism for the transition. The mixed-phase region was centered at 75 +- 6 kbar. No evidence of a phase between the zinc-blende and tetragonal phases was observed, presumably because it does not exist. Analysis of the extended x-ray-absorption fine-structure (EXAFS) clearly showed that there is no change in coordination in going from the zinc-blende to the tetragonal phase although the nearest-neighbor distance increases slightly. A much larger increase in R-italic/sub 1/ occurs at the transition to the NaCl structure, where the coordination increases from 4 to 6. The mean-square deviation in the nearest-neighbor bond length, sigma/sub 1//sup 2/, appears to be a fairly smooth function of nearest-neighbor distance, decreasing (or increasing) as R-italic/sub 1/ decreases (or increases) more or less independent of structure. Evidence from the literature was presented to suggest that the zinc-blende to tetragonal transition in CuBr (and also CuCl) should occur by shear deformation.

  16. Molecular Characterization of Brown Carbon (BrC) Chromophores in Secondary Organic Aerosol Generated From Photo-Oxidation of Toluene

    SciTech Connect (OSTI)

    Lin, Peng; Liu, Jiumeng; Shilling, John E.; Kathmann, Shawn M.; Laskin, Julia; Laskin, Alexander

    2015-09-28

    Atmospheric Brown carbon (BrC) is a significant contributor to light absorption and climate forcing. However, little is known about a fundamental relationship between the chemical composition of BrC and its optical properties. In this work, light-absorbing secondary organic aerosol (SOA) was generated in the PNNL chamber from toluene photo-oxidation in the presence of NOx (Tol-SOA). Molecular structures of BrC components were examined using nanospray desorption electrospray ionization (nano-DESI) and liquid chromatography (LC) combined with UV/Vis spectroscopy and electrospray ionization (ESI) high-resolution mass spectrometry (HRMS). The chemical composition of BrC chromophores and the light absorption properties of toluene SOA (Tol-SOA) depend strongly on the initial NOx concentration. Specifically, Tol-SOA generated under high-NOx conditions (defined here as initial NOx/toluene of 5/1) appears yellow and mass absorption coefficient of the bulk sample (MACbulk@365nm = 0.78 m2 g-1) is nearly 80 fold higher than that measured for the Tol-SOA sample generated under low-NOx conditions (NOx/toluene < 1/300). Fifteen compounds, most of which are nitrophenols, are identified as major BrC chromophores responsible for the enhanced light absorption of Tol-SOA material produced in the presence of NOx. The integrated absorbance of these fifteen chromophores accounts for 40-60% of the total light absorbance by Tol-SOA at wavelengths between 300 nm and 500 nm. The combination of tandem LC-UV/Vis-ESI/HRMS measurements provides an analytical platform for predictive understanding of light absorption properties by BrC and their relationship to the structure of individual chromophores. General trends in the UV/vis absorption by plausible isomers of the BrC chromophores were evaluated using theoretical chemistry calculations. The molecular-level understanding of BrC chemistry is helpful for better understanding the evolution and behavior of light absorbing aerosols in the atmosphere.

  17. Synthesis, crystal structure, spectroscopic and thermal properties of [Et{sub 4}N][Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]Br{sub 4}.4H{sub 2}O (Et=ethyl)-A new compound with the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} cluster core

    SciTech Connect (OSTI)

    Peric, Berislav; Jozic, Drazan; Planinic, Pavica; Brnicevic, Nevenka; Giester, Gerald

    2009-09-15

    A new hexanuclear cluster compound, [Et{sub 4}N][Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]Br{sub 4}.4H{sub 2}O (Et=ethyl) (1), with the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} cluster entity, was synthesized and characterized by elemental and TG/DTA analyses, IR and UV/Vis spectroscopy and by a single-crystal X-ray diffraction study. The presence of the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} unit was confirmed also by the room-temperature magnetic and EPR measurements. The compound crystallizes in the tetragonal I4{sub 1}/a space group, with a=14.299(5), c=21.241(5) A, Z=4, R{sub 1}(F)/wR{sub 2}(F{sup 2})=0.0296/0.0811. The structure contains discrete [Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]{sup 3+} cations with an octahedron of metal atoms edge-bridged by bromine atoms and with water molecules occupying all six terminal positions. The cluster units are positioned in the vertices of the three-dimensional (pseudo)diamond lattice. The structure shows similarities with literature reported structures of cluster compounds crystallizing in the diamond (Fd3-barm) space group. - Graphical abstract: Two interpenetrating (pseudo)diamond nets formed by packing of the paramagnetic [Ta{sub 6}Br{sub 12}(H{sub 2}O)]{sup 3+} (octahedral) and diamagnetic [Et{sub 4}N]{sup +} (spheres) cations.

  18. Ultrafast dynamics of strong-field dissociative ionization ofCH2Br2 probed by femtosecond soft x-ray transient absorptionspectroscopy

    SciTech Connect (OSTI)

    Loh, Zhi-Heng; Leone, Stephen R.

    2008-01-15

    Femtosecond time-resolved soft x-ray transient absorption spectroscopy based on a high-order harmonic generation source is used to investigate the dissociative ionization of CH{sub 2}Br{sub 2} induced by 800 nm strong-field irradiation. At moderate peak intensities (2.0 x 10{sup 14} W/cm{sup 2}), strong-field ionization is accompanied by ultrafast C-Br bond dissociation, producing both neutral Br ({sup 2}P{sub 3/2}) and Br* ({sup 2}P{sub 1/2}) atoms together with the CH{sub 2}Br{sup +} fragment ion. The measured rise times for Br and Br* are 130 {+-} 22 fs and 74 {+-} 10 fs, respectively. The atomic bromine quantum state distribution shows that the Br/Br* population ratio is 8.1 {+-} 3.8 and that the Br {sup 2}P{sub 3/2} state is not aligned. The observed product distribution and the timescales of the photofragment appearances suggest that multiple field-dressed potential energy surfaces are involved in the dissociative ionization process. In addition, the transient absorption spectrum of CH{sub 2}Br{sub 2}{sup +} suggests that the alignment of the molecule relative to the polarization axis of the strong-field ionizing pulse determines the electronic symmetry of the resulting ion; alignment of the Br-Br, H-H, and C{sub 2} axis of the molecule along the polarization axis results in the production of the ion {tilde X}({sup 2}B{sub 2}), {tilde B}({sup 2}B{sub 1}) and {tilde C}({sup 2}A{sub 1}) states, respectively. At higher peak intensities (6.2 x 10{sup 14} W/cm{sup 2}), CH{sub 2}Br{sub 2}{sup +} undergoes sequential ionization to form the metastable CH{sub 2}Br{sub 2}{sup 2+} dication. These results demonstrate the potential of core-level probing with high-order harmonic transient absorption spectroscopy for studying ultrafast molecular dynamics.

  19. A XANES and EXAFS Study of Hydration and Ion Pairing in Ambient Aqueous MnBr[subscript 2] Solutions

    SciTech Connect (OSTI)

    Chen, Yongsheng; Fulton, John L.; Partenheimer, Walter

    2008-09-25

    Extended X-ray absorption fine structure (EXAFS) and X-ray absorption near edge structure (XANES) spectroscopies were used to probe the first-shell coordination structure of Mn(II) in aqueous MnBr{sub 2} solutions at ambient conditions from very dilute to the near saturation limit. The Mn K-edge EXAFS spectra for 0.05 and 0.2 m solutions showed that there was no Br(-I) in the first shell, and that the Mn(II) was fully hydrated with six water molecules in an octahedral arrangement. In contrast, for 6 m solution, the coordination number of water was reduced to about 5, and an average of about one bromine atom was present in the first shell as a contact ion pair. The 1s {yields} 4p transition at 6545.5 eV confirmed the observation of Mn-Br contact ion pairs at high concentrations and the 1s {yields} 3d transition at 6539.5 eV showed that the first shell coordination symmetry remained octahedral even in the presence of Mn-Br ion pairs.

  20. Electrodeposition of zinc on glassy carbon from ZnCl/sub 2/ and ZnBr/sub 2/ electrolytes

    SciTech Connect (OSTI)

    McBreen, J.; Gannon, E.

    1983-08-01

    The initial stages of the electrocrystallization of zinc from 3M ZnCl/sub 2/ and 3M ZnBr/sub 2/ on glassy carbon has been investigated using cyclic voltametry, the potential step method, and scanning electron microscopy. Particular care was taken to ensure electrolyte purity and to eliminate resistance effects in the measurements. The nucleation overvoltage in 3M ZnCl/sub 2/ was about 17 and about 12 mV in 3M ZnBr/sub 2/. In 3M ZnCl/sub 2/, the current transients from the potential step measurements could be fitted to a simple model that assumes instantaneous nucleation followed by growth of three dimensional centers under kinetic control. A similar mechanism is operative for 3M ZnBr/sub 2/ at low overvoltages. At higher overvoltages, the current transient is governed by mixed kinetic and diffusion control and cannot be fitted to a simple model. The lower nucleation overvoltage and the faster kinetics in 3M ZnBr/sub 2/ is correlated with the lower stability constants for the zinc bromide complexes. Erroneous results are obtained when resistance effects are not accounted for.

  1. Ag/AgBr/g-C{sub 3}N{sub 4}: A highly efficient and stable composite photocatalyst for degradation of organic contaminants under visible light

    SciTech Connect (OSTI)

    Cao, Jing; Zhao, Yijie; Lin, Haili; Xu, Benyan; Chen, Shifu

    2013-10-15

    Graphical abstract: Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts displayed excellent photocatalytic activities on the degradation of methyl orange (MO) under visible light. The improved photocatalytic performance and stability of Ag/AgBr/g-C{sub 3}N{sub 4} originated from the synergetic effects of AgBr/g-C{sub 3}N{sub 4} interface and metallic Ag nanoparticles. O{sub 2}?, one of the reactive species, was responsible for the photodegradation of MO compared to H+ and OH. - Highlights: Novel Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalyst was reported. Ag/AgBr/g-C{sub 3}N{sub 4} had novel energy band combination between AgBr and g-C{sub 3}N{sub 4}. Synergetic effects of AgBr/g-C{sub 3}N{sub 4} interface and metallic Ag nanoparticles. Electron trapping role of metallic Ag dominated the stability of Ag/AgBr/g-C{sub 3}N{sub 4}. - Abstract: Novel Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts were constructed via depositionprecipitation method and extensively characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM) and UVvis diffuse reflectance spectroscopy (DRS). Under visible light (? > 420 nm), Ag/AgBr/g-C{sub 3}N{sub 4} composite photocatalysts displayed much higher photocatalytic activities than those of Ag/AgBr and g-C{sub 3}N{sub 4} for degradation of methyl orange (MO). 50% Ag/AgBr/g-C{sub 3}N{sub 4} presented the best photocatalytic performance, which was mainly attributed to the synergistic effects of AgBr/g-C{sub 3}N{sub 4} interface and the in situ metallic Ag nanoparticles for efficiently separating electronhole pairs. Furthermore, Ag/AgBr/g-C{sub 3}N{sub 4} remained good photocatalytic activity through 5 times of cycle experiments. Additionally, the radical scavengers experiment indicated that O{sub 2}{sup ?} was the main reactive species for the MO degradation under visible light.

  2. Direct molecular diffusion and micro-mixing for rapid dewatering of LiBr solution

    SciTech Connect (OSTI)

    Bigham, S; Isfahani, RN; Moghaddam, S

    2014-03-01

    A slow molecular diffusion rate often limits the desorption process of an absorbate molecule from a liquid absorbent. To enhance the desorption rate, the absorbent is often boiled to increase the liquid vapor interfacial area. However, the growth of bubbles generated during the nucleate boiling process still remains mass-diffusion limited. Here, it is shown that a desorption rate higher than that of boiling can be achieved, if the vapor absorbent interface is continuously replenished with the absorbate-rich solution to limit the concentration boundary layer growth. The study is conducted in a LiBr-water-solution, in which the water molecules' diffusion rate is quite slow. The manipulation of the vapor solution interface concentration distribution is enabled by the mechanical confinement of the solution flow within microchannels, using a hydrophobic vapor-venting membrane and the implementation of microstructures on the flow channel's bottom wall. The microstructures stretch and fold the laminar streamlines within the solution film and produce vortices. The vortices continuously replace the concentrated solution at the vapor solution interface with the water-rich solution brought from the bottom and middle of the flow channel. The physics of the process is described using a combination of experimental and numerical studies. Published by Elsevier Ltd.

  3. The corrosion phenomena in the coin cell BR2325 of the ``superstoichiometric fluorocarbon-lithium'' system

    SciTech Connect (OSTI)

    Mitkin, V.N.; Galkin, P.S.; Denisova, T.N.

    1998-07-01

    It was noted at the earlier study and at the longer observations of the novel various types of superstoichiometric fluorocarbon materials CF{sub 1+x}, where x = 0.1--0.33 (FCM) and their behavior, that despite of their known hygroscopity during a storage of samples in laboratory and technological utensils nevertheless occurs an appreciable sorption of atmospheric moisture. The color of samples does not change but sometimes there appears a smell of hydrogen fluoride and even corrosion of glasswares at a long storage. On the basis of these facts was assumed that at a long storage the slow reactions of HF producing with a sorption moisture can proceed. This phenomena is necessary to take into account for successful manufacturing of long life lithium cells based on superstoichiometric fluorocarbon composite cathodes (FCC). The chemistry of such slow hydrolytic process and especially of processes which can proceed at manufacturing of FCC earlier was not investigated also of any data in the literature in this occasion is not present. Just for this reason the authors undertook a study of the corrosion phenomena which can proceed in industrial sources of a current at a long storage under influence of slow hydrolysis of C-F bonds by moisture. The goal of the study was to search long term damages in the slightly wet FCM and based on these materials cathodic composites for fluorocarbon-lithium cells. As a model for corrosion process investigation they have chosen a standard coin lithium battery of a type BR2325.

  4. Photoluminescence characteristics of polariton condensation in a CuBr microcavity

    SciTech Connect (OSTI)

    Nakayama, Masaaki Murakami, Katsuya; Furukawa, Yoshiaki; Kim, DaeGwi

    2014-07-14

    We have investigated the photoluminescence (PL) properties of a CuBr microcavity at 10?K, including the temporal profiles, from the viewpoint of cavity-polariton condensation. The excitation energy density dependence of the PL intensity (band width) of the lower polariton branch at an in-plane wave vector of k{sub //}?=?0 exhibits a threshold-like increase (decrease). A large blueshift in the PL energy of ?10?meV caused by the cavity-polariton renormalization is correlated with the excitation energy density dependence of the PL intensity. The estimated density of photogenerated electron-hole pairs at the threshold is two orders lower than the Mott transition density. These results consistently demonstrate the occurrence of cavity-polariton condensation. In addition, we found that the PL rise and decay times are shortened dramatically by the cavity-polariton condensation, which reflects the bosonic final state stimulation in the relaxation process and the intrinsic cavity-polariton lifetime in the decay process.

  5. Synthesis and photocatalytic performance of an efficient Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} composite photocatalyst under visible light

    SciTech Connect (OSTI)

    Liang, Yinghua; Lin, Shuanglong; Liu, Li; Hu, Jinshan; Cui, Wenquan

    2014-08-15

    Highlights: The plasmatic Ag@AgBr sensitized K{sub 2}Ti{sub 4}O{sub 9} composite photocatalysts. Ag@AgBr greatly increased visible light absorption for K{sub 2}Ti{sub 4}O{sub 9}. The plamonic photocatalysts exhibited enhanced activity for the degradation of RhB. - Abstract: Ag@AgBr nanoparticle-sensitized K{sub 2}Ti{sub 4}O{sub 9} composite photocatalysts (Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9}) were prepared by a facile precipitationphotoreduction method. The photocatalytic activities of the Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} nanocomposites were evaluated for photocatalytic degradation of (RhB) under visible light irradiation. The composites exhibited excellent visible light absorption, which was attributable to the surface plasmon effect of Ag nanoparticles. The Ag@AgBr was uniformly scattered on the surface of K{sub 2}Ti{sub 4}O{sub 9} and possessed sizes in the range of 2050 nm. The loading amount of Ag@AgBr was also studied, and was found to influence the absorption spectra of the resulting composites. Approximately 95.9% of RhB was degraded by Ag@AgBr (20 wt.%)/K{sub 2}Ti{sub 4}O{sub 9} after irradiation for 1 h. The stability of the material was also investigated by performing consecutive runs. Additionally, studies performed using radical scavengers indicated that O{sub 2}{sup ?} and Br{sup 0} acted as the main reactive species. Based on the experimental results, a photocatalytic mechanism for organics degradation over Ag@AgBr/K{sub 2}Ti{sub 4}O{sub 9} photocatalysts was proposed.

  6. Viscosity and density of aqueous solutions of LiBr, LiCl, ZnBr[sub 2], CaCl[sub 2], and LiNO[sub 3]; 1: Single salt solutions

    SciTech Connect (OSTI)

    Wimby, J.M.; Berntsson, T.S. . Dept. of Heat and Power Technology)

    1994-01-01

    New experimental data for the viscosity and density of the binary systems lithium chloride + water, lithium bromide + water, calcium chloride + water, lithium nitrate + water, and zinc bromide + water are presented. Densities are presented in tabular form and as 10-parameter correlations, while kinematic and dynamic viscosities are presented in tabular form. Data are presented in the concentration range from intermediate dilution to close to room temperature crystallization concentration. The temperature ranges are 20--70 C for density and 25--90 C for viscosity. When available, literature data are compared with the new data, and some disagreement is found. New thermogravimetric curves are presented for the dehydration of CaCl[sub 2], ZnBr[sub 2], and LiBr in order to enable evaluation of drying as a composition determination technique.

  7. Hydrogen for X-group exchange in CH3X, X = Cl, Br, I, OMe and NMe2

    Office of Scientific and Technical Information (OSTI)

    byMonomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism (Journal Article) | SciTech Connect Hydrogen for X-group exchange in CH3X, X = Cl, Br, I, OMe and NMe2 byMonomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism Citation Details In-Document Search Title: Hydrogen for X-group exchange in CH3X, X = Cl, Br, I, OMe and NMe2 byMonomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for

  8. Steady-State Thermal-Hydraulics Analyses for the Conversion of the BR2 Reactor to LEU

    SciTech Connect (OSTI)

    Licht, J. R.; Bergeron, A.; Dionne, B.; Van den Branden, G.; Kalcheva, S.; Sikik, E.; Koonen, E.

    2015-12-01

    BR2 is a research reactor used for radioisotope production and materials testing. It’s a tank-in-pool type reactor cooled by light water and moderated by beryllium and light water (Figure 1). The reactor core consists of a beryllium moderator forming a matrix of 79 hexagonal prisms in a hyperboloid configuration; each having a central bore that can contain a variety of different components such as a fuel assembly, a control or regulating rod, an experimental device, or a beryllium or aluminum plug. Based on a series of tests, the BR2 operation is currently limited to a maximum allowable heat flux of 470 W/cm2 to ensure fuel plate integrity during steady-state operation and after a loss-of-flow/loss-of-pressure accident.

  9. Comparison of CsBr and KBr coated Cu photocathodes: Effects of laser irradiation and work function changes

    SciTech Connect (OSTI)

    He, Weidong; VilayurGanapathy, Subramanian; Joly, Alan G.; Droubay, Timothy C.; Chambers, Scott A.; Maldonado, Juan R.; Hess, Wayne P.

    2013-02-20

    Thin films (7 nm layers) of CsBr and KBr were deposited on Cu(100) to investigate photoemission properties of these potential photocathode materials. After thin film deposition and prolonged laser ultraviolet (UV) irradiation (266 nm picosecond laser) photoemission quantum efficiency increases by factors of 26 and 77 for KBr/Cu(100) and CsBr/Cu(100) photocathodes, respectively. Immediately following thin film deposition, a decrease in work function is observed, compared to bare Cu, in both cases. Quantum efficiency enhancements are attributed to the decrease in photocathode work function, due to the deposition of alkali halide thin films, and photo-induced processes, that introduce defect states into the alkali halide bandgap, induced by UV laser irradiation. It is possible that alkali metal formation occurs during UV irradiation and that this further contributes to photoemission enhancement. Our results suggest that KBr, a relatively stable alkali-halide, has potential for photocathode applications.

  10. Periodicity, Electronic Structures, and Bonding of Gold Tetrahalides [AuX4](-) (X = F, CI, Br, I, At, Uus)

    SciTech Connect (OSTI)

    Li, Wan-Lu; Li, Yong; Xu, Congqiao; Wang, Xue B.; Vorpagel, Erich R.; Li, Jun

    2015-12-07

    Systematic theoretical and experimental investigations have been performed to understand the periodicity and electronic structures of trivalent-gold halides using gold tetrahalides [AuX4]⁻ anions (X = F, Cl, Br, I, At, Uus). The [AuX4]⁻ (X = Cl, Br, I) anions were produced in gas phase and their negative-ion photoelectron spectra were obtained, which exhibited rich and well-resolved spectral peaks. We calculated the adiabatic as well as vertical electron detachment energies using density functional methods with scalar and spin-orbit coupling relativistic effects. The simulated photoelectron spectra based on these calculations are in good agreement with the experimental spectra. Our results show that the trivalent Au(III) oxidation state becomes progressively less stable while Au(I) is preferred when the halides become heavier along the Period Table. This trend reveals that the oxidation state of metals in complexes can be manipulated through ligand design

  11. Cs{sub 3}Zr{sub 6}Br{sub 15}Z (Z = C, B): A stuffed rhombohedral perovskite structure of linked clusters

    SciTech Connect (OSTI)

    Qi, Ru-Yi; Corbett, J.D.

    1995-03-29

    The isostructural title compounds are synthesized in good yields form reactions of Zr, ZrBr{sub 4}, CsBr, and Z in sealed Ta tubing for {approximately}3 weeks at 850 {degrees}C. Their single-crystal data refinements established the products as Cs{sub 3.02(7)-}Zr{sub 6}Br{sub 14}C and Cs{sub 3.39(5)}Zr{sub 6}br{sub 15}B (R3c, Z = 6, a = 13.1031 (6), 13.116(1) {angstrom}, c = 35.800(3), 35.980(6) {angstrom}, R(F)/R{sub w} = 5.4/5.9, 5.4/4.4%, respectively). The structure is derived form a three-dimensional [Zr{sub 6}(Z)Br{sub 12}]Br{sub 6/2} network of four-rings (as in ReO{sub 6/2}) twisted into a rhombohedral perovskite analogous to VF{sub 3}. The three necessary Cs{sup +} cations are fractionally distributed over five sites that are far from optimal or common, with either eight asymmetric or only three close bromide neighbors. Refinement of a third Cs{sub 3.18(5)}Zr{sub 6}Br{sub 15}C structure at {minus}50 {degrees}C gave the same result with somewhat smaller positional distributions of the atoms.

  12. Palladium-catalyzed Br/D exchange of arenes: Selective deuterium incorporation with versatile functional group tolerance and high efficiency

    SciTech Connect (OSTI)

    Zhang, Honghai -Hai; Bonnesen, Peter V.; Hong, Kunlun

    2015-07-13

    There is a facile method for introducing one or more deuterium atoms onto an aromatic nucleus via Br/D exchange with high functional group tolerance and high incorporation efficiency is disclosed. Deuterium-labeled aryl chlorides and aryl borates which could be used as substrates in cross-coupling reactions to construct more complicated deuterium-labeled compounds can also be synthesized by this method.

  13. Palladium-catalyzed Br/D exchange of arenes: Selective deuterium incorporation with versatile functional group tolerance and high efficiency

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Honghai -Hai; Bonnesen, Peter V.; Hong, Kunlun

    2015-01-01

    There is a facile method for introducing one or more deuterium atoms onto an aromatic nucleus via Br/D exchange with high functional group tolerance and high incorporation efficiency is disclosed. Deuterium-labeled aryl chlorides and aryl borates which could be used as substrates in cross-coupling reactions to construct more complicated deuterium-labeled compounds can also be synthesized by this method.

  14. Magnetic excitations in the spin-1/2 triangular-lattice antiferromagnet Cs2CuBr4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zvyagin, S. A.; Ozerov, M.; Kamenskyi, D.; Wosnitza, J.; Krzystek, J.; Yoshizawa, D.; Hagiwara, M.; Hu, Rongwei; Ryu, Hyejin; Petrovic, C.; et al

    2015-11-27

    We present on high- field electron spin resonance (ESR) studies of magnetic excitations in the spin- 1/2 triangular-lattice antiferromagnet Cs2CuBr4. Frequency- field diagrams of ESR excitations are measured for different orientations of magnetic fields up to 25 T. We show that the substantial zero- field energy gap, Δ ≈ 9.5 K, observed in the low-temperature excitation spectrum of Cs2CuBr4 [Zvyagin et al:, Phys. Rev. Lett. 112, 077206 (2014)], is present well above TN. Noticeably, the transition into the long-range magnetically ordered phase does not significantly affect the size of the gap, suggesting that even below TN the high-energy spin dynamicsmore » in Cs2CuBr4 is determined by short-range-order spin correlations. The experimental data are compared with results of model spin-wave-theory calculations for spin-1/2 triangle-lattice antiferromagnet.« less

  15. Preparation, characterization and photocatalytic activity of visible-light-driven plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites

    SciTech Connect (OSTI)

    Li, Xiaojuan Tang, Duanlian; Tang, Fan; Zhu, Yunyan; He, Changfa; Liu, Minghua Lin, Chunxiang; Liu, Yifan

    2014-08-15

    Highlights: A plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} photocatalyst has been successfully synthesized. Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites exhibit high visible light photocatalytic activity. Ag/AgBr/ZnFe{sub 2}O{sub 4} photocatalyst is stable and magnetically separable. - Abstract: A visible-light-driven plasmonic Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposite has been successfully synthesized via a depositionprecipitation and photoreduction through a novel one-pot process. X-ray diffraction spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and UVvis diffuse reflectance spectroscopy were employed to investigate the crystal structure, chemical composition, morphology, and optical properties of the as-prepared nanocomposites. The photocatalytic activities of the nanocomposites were evaluated by photodegradation of Rhodamine B (RhB) and phenol under visible light. The results demonstrated that the obtained Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposites exhibited higher photocatalytic activity as compared to pure ZnFe{sub 2}O{sub 4}. In addition, the sample photoreduced for 20 min and calcined at 500 C achieved the highest photocatalytic activity. Furthermore, the Ag/AgBr/ZnFe{sub 2}O{sub 4} nanocomposite has high stability under visible light irradiation and could be conveniently separated by using an external magnetic field.

  16. Nanostructured Lanthanum Halides and CeBr3 for Nuclear Radiation and Detection

    SciTech Connect (OSTI)

    Paul Guss, Sanjoy Mukhopadhyay, Ron Guise, Ding Yuan

    2010-06-09

    Scintillator materials are used to detect, and in some cases identify, gamma rays. Higher performance scintillators are expensive, hard to manufacture, fragile, and sometimes require liquid nitrogen or cooling engines. But whereas lower-quality scintillators are cheap, easy to manufacture, and more rugged, their performance is lower. At issue: can the desirable qualities of high-and low-performance scintillators be combined to achieve better performance at lower cost? Preliminary experiments show that a LaF{sub 3}:Ce oleic acid-based nanocomposite exhibits a photopeak when exposed to {sup 137}Cs source gamma-radiation. The chemical synthesis of the cerium-doped lanthanum halide nanoparticles are scalable and large quantities of material can be produced at a time, unlike typical crystal growth processes such as the Bridgeman process. Using a polymer composite (Figure 1), produced by LANL, initial measurements of the unloaded and 8% LaF{sub 3}:Ce-loaded sample have been made using {sup 137}Cs sources. Figure 2 shows an energy spectrum acquired for CeF{sub 3}. The lighter plot is the measured polymer-only spectrum and the black plot is the spectrum from the nanocomposite scintillator. As the development of this material continues, the energy resolution is expected to improve and the photopeak-to-Compton ratio will become greater at higher loadings. These measurements show the expected Compton edge in the polymer-only sample, and the Compton edge and photo-peak expected in the nanophosphor composites that LANL has produced. Using a porous VYCORR with CdSe/ZnS core shell quantum dots, Letant has demonstrated that he has obtained signatures of the 241Am photopeak with energy resolution as good at NaI (Figure 3). We begin with the fact that CeBr{sub 3} crystals do not have a self-activity component as strong as the lanthanum halides. The radioactive 0.090% {sup 138}La component of lanthanum leads to significant self-activity, which will be a problem for very large detector volumes. Yet a significant strength of the nanostructure detector concept is the ability to create extremely large detector volumes by mixing nanoparticles into a transparent matrix. This would argue for use of nanoparticles other than lanthanum halides. Nanocomposites are easy to prepare; it is much less costly to use nanocomposites than to grow large whole crystals of these materials. The material can be fabricated at an industrial scale, further reducing cost. This material potentially offers the performance of $300/cc material (e.g., lanthanum bromide) at a cost of $1/cc. Because the material acts as a plastic, it is rugged and flexible, and can be made in large sheets, increasing the sensitivity of a detector using it. It would operate at ambient temperatures. Very large volumes of detector may be produced at greatly reduced cost, enhancing the non-proliferation posture of the nation for the same dollar value.

  17. Preliminary design report: Babcock and Wilcox BR-100 100-ton rail/barge spent fuel shipping cask

    SciTech Connect (OSTI)

    None

    1990-02-01

    The purpose of this document is to provide information on burnup credit as applied to the preliminary design of the BR-100 shipping cask. There is a brief description of the preliminary basket design and the features used to maintain a critically safe system. Following the basket description is a discussion of various criticality analyses used to evaluate burnup credit. The results from these analyses are then reviewed in the perspective of fuel burnups expected to be shipped to either the final repository or a Monitored Retrievable Storage (MRS) facility. The hurdles to employing burnup credit in the certification of any cask are then outlines and reviewed. the last section gives conclusions reached as to burnup credit for the BR-100 cask, based on our analyses and experience. All information in this study refers to the cask configured to transport PWR fuel. Boiling Water Reactor (BWR) fuel satisfies the criticality requirements so that burnup credit is not needed. All calculations generated in the preparation of this report were based upon the preliminary design which will be optimized during the final design. 8 refs., 19 figs., 16 tabs.

  18. Impact of membrane characteristics on the performance and cycling of the Br-2-H-2 redox flow cell

    SciTech Connect (OSTI)

    Tucker, MC; Cho, KT; Spingler, FB; Weber, AZ; Lin, GY

    2015-06-15

    The Br-2/H-2 redox flow cell shows promise as a high-power, low-cost energy storage device. In this paper, the effect of various aspects of material selection and processing of proton exchange membranes on the operation of the Br-2/H-2 redox flow cell is determined. Membrane properties have a significant impact on the performance and efficiency of the system. In particular, there is a tradeoff between conductivity and crossover, where conductivity limits system efficiency at high current density and crossover limits efficiency at low current density. The impact of thickness, pretreatment procedure, swelling state during cell assembly, equivalent weight, membrane reinforcement, and addition of a microporous separator layer on this tradeoff is assessed. NR212 (50 mu m) pretreated by soaking in 70 degrees C water is found to be optimal for the studied operating conditions. For this case, an energy efficiency of greater than 75% is achieved for current density up to 400 mA cm(-2), with a maximum obtainable energy efficiency of 88%. A cell with this membrane was cycled continuously for 3164 h. Membrane transport properties, including conductivity and bromine and water crossover, were found to decrease moderately upon cycling but remained higher than those for the as-received membrane. (C) 2015 Elsevier B.V. All rights reserved.

  19. Dissociative adsorption of CH{sub 3}X (X = Br and Cl) on a silicon(100) surface revisited by density functional theory

    SciTech Connect (OSTI)

    Wang, Chen-Guang; Huang, Kai E-mail: wji@ruc.edu.cn; Ji, Wei E-mail: wji@ruc.edu.cn

    2014-11-07

    During the dissociative adsorption on a solid surface, the substrate usually participates in a passive manner to accommodate fragments produced upon the cleavage of the internal bond(s) of a (transient) molecular adsorbate. This simple picture, however, neglects the flexibility of surface atoms. Here, we report a Density Functional Theory study to revisit our early studies of the dissociative adsorption of CH{sub 3}X (X = Br and Cl) on Si(100). We have identified a new reaction pathway, which involves a flip of a silicon dimer; this new pathway agrees better with experiments. For our main exemplar of CH{sub 3}Br, insights have been gained using a simple model that involves a three-atom reactive center, Br-C-Si. When the silicon dimer flips, the interaction between C and Si in the Br-C-Si center is enhanced, evident in the increased energy-split of the frontier orbitals. We also examine how the dissociation dynamics of CH{sub 3}Br is altered on a heterodimer (Si-Al, Si-P, and Si-Ge) in a Si(100) surface. In each case, we conclude, on the basis of computed reaction pathways, that no heterodimer flipping is involved before the system transverses the transition state to dissociative adsorption.

  20. Environmental effects on noble-gas hydrides: HXeBr, HXeCCH, and HXeH in noble-gas and molecular matrices

    SciTech Connect (OSTI)

    Tsuge, Masashi E-mail: leonid.khriachtchev@helsinki.fi; Lignell, Antti; Rsnen, Markku; Khriachtchev, Leonid E-mail: leonid.khriachtchev@helsinki.fi

    2013-11-28

    Noble-gas hydrides HNgY (Ng is a noble-gas atom and Y is an electronegative group) are sensitive probes of local environment due to their relatively weak bonding and large dipole moments. We experimentally studied HXeBr in Ar, Kr, and N{sub 2} matrices, HXeCCH in Ne and N{sub 2} matrices, and HXeH in an N{sub 2} matrix. These are the first observations of noble-gas hydrides in an N{sub 2} matrix. An N{sub 2} matrix strongly increases the HXe stretching frequency of HXeBr and HXeCCH with respect to a Ne matrix, which is presumably due to a strong interaction between the HNgY dipole moment and quadrupole moments of the surrounding lattice N{sub 2} molecules. The spectral shift of HXeBr in an N{sub 2} matrix is similar to that in a CO{sub 2} matrix, which is a rather unexpected result because the quadrupole moment of CO{sub 2} is about three times as large as that of N{sub 2}. The HXe stretching frequencies of HXeBr and HXeCCH in noble-gas matrices show a trend of ?(Ne) < ?(Xe) < ?(Kr) < ?(Ar), which is a non-monotonous function of the dielectric constants of the noble-gas solids. The MP2(full) calculations of HXeBr and HXeCCH with the polarizable continuum model as well as the CCSD(T) calculations of the HXeBrNg and HXeCCHNg (Ng = Ne, Ar, Kr, and Xe) complexes cannot fully explain the experimental observations. It is concluded that more sophisticated computational models should be used to describe these experimental findings.

  1. Stabilized wide bandgap MAPbBrxI3-x perovskite by enhanced grain size and improved crystallinity

    SciTech Connect (OSTI)

    Hu, Miao; Bi, Cheng; Yuan, Yongbo; Bai, Yang; Huang, Jinsong

    2015-12-07

    In this study, the light instability of CH3NH3PbIxBr3x has been raised one of the biggest challenges for its application in tandem solar cells. Here we show that an improved crystallinity and grain size of CH3NH3PbIxBr3x films could stabilize these materials under one sun illumination, improving both the efficiency and stability of the wide-bandgap perovskite solar cells.

  2. CROSSED MOLECULAR BEAM STUDIES OF CHEMILUMINESCENT REACTIONS: F{sub 2} + I{sub 2}, Br{sub 2} and ICl

    SciTech Connect (OSTI)

    Kahler, C.C.; Lee, Y.T.

    1980-05-01

    The chemiluminescent bimolecular halogen-halogen reactions, F{sub 2} + I{sub 2}, Br{sub 2} and ICl, have been studied by the crossed molecular beam technique. Undispersed chemiluminescence was measured as a function of collision energy and, for I{sub 2} + F{sub 2}, as a function of the two beam pressures. Although no spectra were obtained to positively identify the emitters as IF*, ClF* and BrF*, arguments are given to support this identification. The observed reaction thresholds of 4.2 and 5.9 kcal/mole for I{sub 2} + F{sub 2} and ICl + F{sub 2} , respectively, are the same as the threshold energies for production of the stable trihalogens I{sub 2}F and ClF. This coincidence of threshold energies, as well as similar high collision energy behavior, implies that the chemiluminescent reaction proceeds via a stable trihalogen intermediate. This mechanism can explain our results and the results of other workers without resorting to a symmetry forbidden four center reaction mechanism. A threshold of 11.3 kcal/mole was found for Br{sub 2} + F{sub 2} , no threshold for Br{sub 2}F has been previously reported. Laser enhancement of the I{sub 2} + F{sub 2} reaction was attempted, but no enhancement was seen.

  3. Magnetic excitations in the spin-1/2 triangular-lattice antiferromagnet Cs2CuBr4

    SciTech Connect (OSTI)

    Zvyagin, S. A.; Ozerov, M.; Kamenskyi, D.; Wosnitza, J.; Krzystek, J.; Yoshizawa, D.; Hagiwara, M.; Hu, Rongwei; Ryu, Hyejin; Petrovic, C.; Zhitomirsky, M. E.

    2015-11-27

    We present on high- field electron spin resonance (ESR) studies of magnetic excitations in the spin- 1/2 triangular-lattice antiferromagnet Cs2CuBr4. Frequency- field diagrams of ESR excitations are measured for different orientations of magnetic fields up to 25 T. We show that the substantial zero- field energy gap, Δ ≈ 9.5 K, observed in the low-temperature excitation spectrum of Cs2CuBr4 [Zvyagin et al:, Phys. Rev. Lett. 112, 077206 (2014)], is present well above TN. Noticeably, the transition into the long-range magnetically ordered phase does not significantly affect the size of the gap, suggesting that even below TN the high-energy spin dynamics in Cs2CuBr4 is determined by short-range-order spin correlations. The experimental data are compared with results of model spin-wave-theory calculations for spin-1/2 triangle-lattice antiferromagnet.

  4. Communication: Transfer ionization in a thermal reaction of a cation and anion: Ar{sup +} with Br{sup −} and I{sup −}

    SciTech Connect (OSTI)

    Shuman, Nicholas S.; Miller, Thomas M.; Viggiano, Albert A.; Johnsen, Rainer

    2013-11-07

    We present experimental evidence that reactions of argon cations Ar{sup +} with the halogen anions Br{sup −} and I{sup −} do not occur exclusively by mutual neutralization, but also produce the cations Br{sup +} or I{sup +} ions by transfer ionization (TI). The experiments were carried out in flowing-afterglow plasmas at gas temperatures between and 300 and 500 K, and employed a variant of the Variable Electron and Neutral Density Attachment Mass Spectrometry method. The measured TI rate coefficients are 1.9 ± 0.6 × 10{sup −9} cm{sup 3} s{sup −1} and 1.1 ± {sub 0.3}{sup 0.8}× 10{sup −9} cm{sup 3} s{sup −1} for the Br{sup −} and I{sup −} reactions, respectively. We find that the TI rate coefficients decline with temperature as T{sup −0.5} to T{sup −1}. No indication of TI was found in the reaction with Cl{sup −}, where it is endoergic.

  5. Neutron inelastic scattering investigation of the magnetic excitations in Cu{sub 2}Te{sub 2}O{sub 5}X{sub 2} (X=Br,Cl)

    SciTech Connect (OSTI)

    Crowe, S.J.; Majumdar, S.; Lees, M.R.; Paul, D. McK.; Bewley, R.I.; Levett, S.J.; Ritter, C.

    2005-06-01

    Neutron inelastic scattering investigations have been performed on the spin tetrahedral system Cu{sub 2}Te{sub 2}O{sub 5}X{sub 2} (X=Cl,Br). We report the observation of magnetic excitations with a dispersive component in both compounds, associated with the three-dimensional incommensurate magnetic order that develops below T{sub N}{sup Cl}=18.2 K and T{sub N}{sup Br}=11.4 K. The excitation in Cu{sub 2}Te{sub 2}O{sub 5}Cl{sub 2} softens as the temperature approaches T{sub N}{sup Cl}, leaving diffuse quasi-elastic scattering above the transition temperature. In the bromide, the excitations are present well above T{sub N}{sup Br}, which might be attributed to the presence of a degree of low dimensional correlations above T{sub N}{sup Br} in this compound.

  6. Parity violation in nuclear magnetic resonance frequencies of chiral tetrahedral tungsten complexes NWXYZ (X, Y, Z = H, F, Cl, Br or I)

    SciTech Connect (OSTI)

    Nahrwold, Sophie Berger, Robert; Clemens-Schöpf-Institute, Technical University Darmstadt, Petersenstr. 22, D-64287 Darmstadt ; Schwerdtfeger, Peter; Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Str., D-35032 Marburg

    2014-01-14

    Density functional theory within the two-component quasi-relativistic zeroth-order regular approximation (ZORA) is used to predict parity violation shifts in {sup 183}W nuclear magnetic resonance shielding tensors of chiral, tetrahedrally bonded tungsten complexes of the form NWXYZ (X, Y, Z = H, F, Cl, Br or I), as well as for the heavier systems NWHAtF and NWH(117)F for comparison. The calculations reveal that sub-mHz accuracy is required to detect such tiny effects in this class of compounds, and that parity violation effects are very sensitive to the choice of ligands.

  7. A chopper system for shortening the duration of pulsed supersonic beams seeded with NO or Br{sub 2} down to 13 μs

    SciTech Connect (OSTI)

    Lam, Jessica; Rennick, Christopher J.; Softley, Timothy P.

    2015-05-15

    A chopper wheel construct is used to shorten the duration of a molecular beam to 13 μs. Molecular beams seeded with NO or with Br{sub 2} and an initial pulse width of ≥200 μs were passed through a spinning chopper wheel, which was driven by a brushless DC in vacuo motor at a range of speeds, from 3000 rpm to 80 000 rpm. The resulting duration of the molecular-beam pulses measured at the laser detection volume ranged from 80 μs to 13 μs and was the same for both NO and Br{sub 2}. The duration is consistent with a simple analytical model, and the minimum pulse width measured is limited by the spreading of the beam between the chopper and the detection point as a consequence of the longitudinal velocity distribution of the beam. The setup adopted here effectively eliminates buildup of background gas without the use of a differential pumping stage, and a clean narrow pulse is obtained with low rotational temperature.

  8. Design and experimental testing of the performance of an outdoor LiBr/H{sub 2}O solar thermal absorption cooling system with a cold store

    SciTech Connect (OSTI)

    Agyenim, Francis; Knight, Ian; Rhodes, Michael

    2010-05-15

    A domestic-scale prototype experimental solar cooling system has been developed based on a LiBr/H{sub 2}O absorption system and tested during the 2007 summer and autumn months in Cardiff University, UK. The system consisted of a 12 m{sup 2} vacuum tube solar collector, a 4.5 kW LiBr/H{sub 2}O absorption chiller, a 1000 l cold storage tank and a 6 kW fan coil. The system performance, as well as the performances of the individual components in the system, were evaluated based on the physical measurements of the daily solar radiation, ambient temperature, inlet and outlet fluid temperatures, mass flow rates and electrical consumption by component. The average coefficient of thermal performance (COP) of the system was 0.58, based on the thermal cooling power output per unit of available thermal solar energy from the 12 m{sup 2} Thermomax DF100 vacuum tube collector on a hot sunny day with average peak insolation of 800 W/m{sup 2} (between 11 and 13.30 h) and ambient temperature of 24 C. The system produced an electrical COP of 3.6. Experimental results prove the feasibility of the new concept of cold store at this scale, with chilled water temperatures as low as 7.4 C, demonstrating its potential use in cooling domestic scale buildings. (author)

  9. Estimation of steady-state and transcient power distributions for the RELAP analyses of the 1963 loss-of-flow and loss-of-pressure tests at BR2.

    SciTech Connect (OSTI)

    Dionne, B.; Tzanos, C. P.

    2011-05-23

    To support the safety analyses required for the conversion of the Belgian Reactor 2 (BR2) from highly-enriched uranium (HEU) to low-enriched uranium (LEU) fuel, the simulation of a number of loss-of-flow tests, with or without loss of pressure, has been undertaken. These tests were performed at BR2 in 1963 and used instrumented fuel assemblies (FAs) with thermocouples (TC) imbedded in the cladding as well as probes to measure the FAs power on the basis of their coolant temperature rise. The availability of experimental data for these tests offers an opportunity to better establish the credibility of the RELAP5-3D model and methodology used in the conversion analysis. In order to support the HEU to LEU conversion safety analyses of the BR2 reactor, RELAP simulations of a number of loss-of-flow/loss-of-pressure tests have been undertaken. Preliminary analyses showed that the conservative power distributions used historically in the BR2 RELAP model resulted in a significant overestimation of the peak cladding temperature during the transient. Therefore, it was concluded that better estimates of the steady-state and decay power distributions were needed to accurately predict the cladding temperatures measured during the tests and establish the credibility of the RELAP model and methodology. The new approach ('best estimate' methodology) uses the MCNP5, ORIGEN-2 and BERYL codes to obtain steady-state and decay power distributions for the BR2 core during the tests A/400/1, C/600/3 and F/400/1. This methodology can be easily extended to simulate any BR2 core configuration. Comparisons with measured peak cladding temperatures showed a much better agreement when power distributions obtained with the new methodology are used.

  10. Feasibility of a super high-energy-density battery of the Li/Br/F sub 3 electrochemical system. Final report, 15 August 1989-14 May 1990

    SciTech Connect (OSTI)

    Frysz, C.A.; Pyszczek, M.F.; Ebel, S.J.

    1990-08-16

    Feasibility studies on the practical aspects of developing a lithium/bromine trifluoride battery have been studied. Efforts directed toward identifying materials for porous electrode separators, glasses for insulated electrical feed-throughs, and metals for lid, case and current collector fabrication via electrochemical testing techniques have resulted in a list of materials suitable for these applications. Prototype cells utilizing a spirally wound electrode configuration have been constructed and discharged. The use of lithium salts as an electrolyte additive has been explored, and has shown a positive effect on discharge performance. Through the use of currently available technology, however, the lithium/bromine trifluoride couple has not delivered energy density comparable to other high energy density lithium systems. This investigation has revealed that practical Li/BrF3 cell development will require further extensive fundamental electrochemical research.

  11. Incommensurate magnetic ordering in Cu{sub 2}Te{sub 2}O{sub 5}X{sub 2} (X=Cl,Br) studied by single crystal neutron diffraction

    SciTech Connect (OSTI)

    Zaharko, O.; Roennow, H.; Mesot, J.; Crowe, S. J.; Paul, D. McK.; Brown, P. J.; Daoud-Aladine, A.; Meents, A.; Wagner, A.; Prester, M.; Berger, H.

    2006-02-01

    Polarized and unpolarized neutron-diffraction studies have been carried out on single crystals of the coupled spin tetrahedra systems Cu{sub 2}Te{sub 2}O{sub 5}X{sub 2} (X=Cl,Br). A model of the magnetic structure associated with the propagation vectors k{sup '}{sub Cl}{approx_equal}(-0.150,0.422,(1/2)) and k{sup '}{sub Br}{approx_equal}(-0.172,0.356,(1/2)) and stable below T{sub N}=18 K for X=Cl and T{sub N}=11 K for X=Br is proposed. A feature of the model, common to both the bromide and chloride, is a canted coplanar motif for the four Cu{sup 2+} spins on each tetrahedron which rotates on a helix from cell to cell following the propagation vector. The Cu{sup 2+} magnetic moment determined for X=Br,0.395(5){mu}{sub B}, is significantly less than for X=Cl,0.88(1){mu}{sub B} at 2 K. The magnetic structure of the chloride associated with the wave vector k{sup '} differs from that determined previously for the wave vector k{approx_equal}(0.150,0.422,(1/2)) [O. Zaharko et al., Phys. Rev. Lett. 93, 217206(E) (2004)].

  12. Laser Raman spectroscopy study of the zinc and bromide ion complex equilibrium in zinc/bromine battery electrolytes. [2M ZnBr/sub 2/ and 1M KBr solution

    SciTech Connect (OSTI)

    Grimes, P.G.; Larrabee, J.A.

    1985-01-01

    Laser Raman spectroscopy was used to study the zinc and bromide ion complex equilibrium in zinc bromine battery model electrolytes. Solutions of zinc bromide with added KBr, HBr and N-methyl, N-ethyl morpholinium (MEM) bromide were examined and compared. Solutions studied ranged from 1 to 3 molar in zinc and from 2.5 to 8 molar in bromide. A typical Raman spectrum of a zinc bromide solution is shown in Figure 1. Each of the zinc species is identified, Zn/sup + +/ (aq), ZnBr/sup +/, ZnBr/sub 2/ (aq), ZnBr/sub 3//sup -/ and ZnBr/sub 4//sup 2 -/. By the use of peak heights or deconvolution/integration along with published Raman cross sections, the amount of each zinc species could be quantitatively determined. The addition of bromide ions to the zinc bromide solutions will shift the equilibrium toward higher bromide complexes. The added cations will influence the shifts. It has been noted that the conductivity of the electrolyte decreases when the quaternary ammonium ions are present compared to cations such as potassium or hydrogen. Significantly more free zinc is present in zinc bromide solutions with added KBr than with either MEMBr or HBr. Shifts are also noted with the other zinc ion containing species. It appears that the quaternary ammonium ions and possibly the pH could have a stabilizing effect on zinc bromide complex ion formation. 2 figs.

  13. Hanford Speakers Bureau<br>>Frequently Asked Questions - Hanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the topics covered by the Hanford Speakers Bureau? The presentation covers various strategies for cleaning up the 586 square miles Hanford Site. Speakers can provide an...

  14. High field magnetotransport and point contact Andreev reflection measurements on CuCr{sub 2}Se{sub 4} and CuCr{sub 2}Se{sub 3}BrDegenerate magnetic semiconductor single crystals

    SciTech Connect (OSTI)

    Borisov, K. Coey, J. M. D.; Stamenov, P.; Alaria, J.

    2014-05-07

    Single crystals of the metallically degenerate fully magnetic semiconductors CuCr{sub 2}Se{sub 4} and CuCr{sub 2}Se{sub 3}Br have been prepared by the Chemical Vapour Transport method, using either Se or Br as transport agents. The high-quality, millimetre-sized, octahedrally faceted, needle- and platelet-shaped crystals are characterised by means of high field magnetotransport (?{sub 0}H? 14?T) and Point Contact Andreev Reflection. The relatively high spin polarisation observed |P|>0.56, together with the relatively low minority carrier effective mass of 0.25 m{sub e}, and long scattering time 10{sup ?13}?s, could poise these materials for integration in low- and close-to-room temperature minority injection bipolar heterojunction transistor demonstrations.

  15. Improvement of {gamma}-ray energy resolution of LaBr{sub 3}:Ce{sup 3+} scintillation detectors by Sr{sup 2+} and Ca{sup 2+} co-doping

    SciTech Connect (OSTI)

    Alekhin, M. S.; Haas, J. T. M. de; Khodyuk, I. V.; Dorenbos, P.; Kraemer, K. W.; Menge, P. R.; Ouspenski, V.

    2013-04-22

    Commercially available LaBr{sub 3}:5% Ce{sup 3+} scintillators show with photomultiplier tube readout about 2.7% energy resolution for the detection of 662 keV {gamma}-rays. Here we will show that by co-doping LaBr{sub 3}:Ce{sup 3+} with Sr{sup 2+} or Ca{sup 2+} the resolution is improved to 2.0%. Such an improvement is attributed to a strong reduction of the scintillation light losses that are due to radiationless recombination of free electrons and holes during the earliest stages (1-10 ps) inside the high free charge carrier density parts of the ionization track.

  16. Optical absorption and luminescence spectroscopy of U{sup 3+} in K{sub 2}La{ital X}{sub 5} ({ital X}=Cl,Br,I)

    SciTech Connect (OSTI)

    Andres, H.P.; Kraemer, K.; Guedel, H.

    1996-08-01

    The title compounds were synthesized and high-resolution absorption and luminescence spectra measured in the near-infrared, VIS, and near UV regions. The visible absorption spectra are dominated by very intense 5{ital f}{r_arrow}6{ital d} bands overlapping with {ital f}-{ital f} transitions. The onset of the first {ital f}-{ital d} absorption is shifted from 46000 cm{sup {minus}1} in K{sub 2}LaCl{sub 5}:Nd{sup 3+} to 15000 cm{sup {minus}1} in K{sub 2}LaCl{sub 5}:U{sup 3+}. Crystal-field splittings in corresponding {sup 2{ital S}+1}{ital L}{sub {ital J}} multiplets are greater by typically a factor of 2 in the U{sup 3+} doped crystal, thus reflecting the larger extension and stronger interaction of the 5{ital f} electrons with the ligands. {ital f}-{ital f} transitions are typically two orders of magnitude more intense in K{sub 2}LaCl{sub 5}:U{sup 3+} than in K{sub 2}LaCl{sub 5}:Nd{sup 3+}. Along the halide series K{sub 2}La{ital X}{sub 5}:U{sup 3+} ({ital X}=Cl,Br,I) the differences in the position of corresponding {ital f}-{ital d} and {ital f}-{ital f} transitions, crystal-field splittings, vibronic intensities, and excited-state lifetimes can be explained with the increasing covalency, the decreasing phonon energies, the increasing electron-phonon coupling, and the increasing U-{ital X} distances. The {ital f}-{ital d} excited states provide a nonradiative bypass of some {ital f}-{ital f} excited states in the case of all these halide lattices. The excited-state dynamics are determined by a delicate interplay of radiative and nonradiative relaxation processes, they are strongly dependent on the nature of {ital X}. Multiphonon relaxation processes are least competitive in the iodide due to the very low value of 106 cm{sup {minus}1} for the highest-energy phonons. A cross-relaxation mechanism determines the dynamics of the iodide at room temperature. {copyright} {ital 1996 The American Physical Society.}

  17. Location of gap nodes in the organic superconductors {kappa}-(ET){sub 2}Cu(NCS){sub 2} and {kappa}-(ET){sub 2}Cu[N(CN){sub 2}Br determined by magnetocalorimetry.

    SciTech Connect (OSTI)

    Malone, L.; Taylor, O. J.; Schlueter, J. A.; Carrington, A.; Materials Science Division; Univ. Bristol

    2010-07-16

    We report specific-heat measurements of the organic superconductors {kappa}-(ET){sub 2}Cu(NCS){sub 2} and {kappa}-(ET){sub 2}Cu[N(CN){sub 2}]Br. When the magnetic field is rotated in the highly conducting planes at low temperature (T = 0.4 K), we observe clear oscillations of specific heat which have a strong fourfold component. The observed strong field and temperature dependence of this fourfold component identifies it as originating from nodes in the superconducting energy gap which point along the in-plane crystal axes (d{sub xy} symmetry).

  18. Effect of externally applied pressure on the magnetic behavior of Cu{sub 2}Te{sub 2}O{sub 5}(Br{sub x}Cl{sub 1-x}){sub 2}

    SciTech Connect (OSTI)

    Crowe, S. J.; Lees, M. R.; Paul, D. M. K.; Bewely, R. I.; Taylor, J.; McIntyre, G.; Zaharko, O.; Berger, H.

    2006-04-01

    The effect of externally applied pressure on the magnetic behavior of Cu{sub 2}Te{sub 2}O{sub 5}(Br{sub x}Cl{sub 1-x}){sub 2} with x=0, 0.73, and 1, is investigated by a combination of magnetic susceptibility, neutron diffraction, and neutron inelastic scattering measurements. The magnetic transition temperatures of the x=0 and 0.73 compositions are observed to increase linearly with increasing pressure at a rate of 0.23(2) and 0.04(1) K/kbar, respectively. However, the bromide shows contrasting behavior with a large suppression of the transition temperature under pressure, at a rate of -0.95(9) K/kbar. In neutron inelastic scattering measurements of Cu{sub 2}Te{sub 2}O{sub 5}Br{sub 2} under pressure only a small change to the ambient pressure magnetic excitations were observed. A peak in the density of states was seen to shift from {approx}5 meV in ambient pressure to {approx}6 meV under an applied pressure of 11.3 kbar, which was associated with an increase in the overall magnetic coupling strength.

  19. Spectral indices measurements using miniature fission chambers at the MINERVE zero-power reactor at CEA using calibration data obtained at the BR1 reactor at SCK.CEN

    SciTech Connect (OSTI)

    De lanaute, N. Blanc; Mellier, F.; Lyoussi, A.; Domergue, C.; Di Salvo, J. [CEA, DEN, DER, SPEX, F-13108 St Paul Les Durance, (France); Borms, L.; Wagemans, J. [CEN SCK, Belgian Nucl Res Ctr, B-2400 Mol, (Belgium)

    2012-08-15

    Spectral indices measurements performed in 2004 at the CEA MINERVE facility loaded with the R-UO{sub 2} lattice, using calibration data acquired at the SCK center dot CEN BR1 facility in 2001, resulted in ambivalent conclusions. On one hand, spectral indices involving only fissile isotopes gave consistent discrepancies between calculation and experiment. On the other hand, spectral indices involving both fissile and fertile isotopes, in particular the {sup 238}U(n, f)/{sup 235}U(n, f) spectral index, showed inconsistent results depending on the type of calibration data used. For different reasons, no definitive explanation was given at that time. In 2009, the preparation of the AMMON program at the EOLE facility motivated the manufacturing of a new set of detectors. At the same time, the re-installation of the R1-UO{sub 2} lattice in MINERVE provided the opportunity to carry out again a spectral indices measurement campaign. Nevertheless, although the isotopic compositions of active deposits were better known than previously, the comparison between experimental results and calculations still lead to inconsistent discrepancies. In April 2010, a new calibration series conducted again at the BR1 facility allowed the CEA to reanalyze the spectral indices measurements performed in 2009. With these very latest calibration data, experimental values of spectral indices finally matched calculations within the uncertainty margins. This paper also sums up the work that has been achieved to explain the incoherencies observed in 2004. (authors)

  20. Solid-state synthesis, structure and properties of a novel open-framework cadmium selenite bromide: [Cd{sub 10}(SeO{sub 3}){sub 8}Br{sub 4}]·HBr·H{sub 2}O

    SciTech Connect (OSTI)

    Chen, Wen-Tong; Wang, Ming-Sheng; Wang, Guan-E; Chen, Hui-Fen; Guo, Guo-Cong

    2013-08-15

    A novel open-framework cadmium selenite bromide, [Cd{sub 10}(SeO{sub 3}){sub 8}Br{sub 4}]·HBr·H{sub 2}O (1), has been obtained by a solid-state reaction at 450 °C, and the structure has been determined by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in Pbcm of the orthorhombic system: a=10.882(3), b=16.275(5), c=18.728(6) Å, V=3317(2) Å{sup 3}, R1/wR2=0.0411/0.0659. Compound 1 is characteristic of a novel 3-D open-framework structure, composing {sub ∞}{sup 2}[CdSeO{sub 3}] layers and the pillars of edge-shared CdO{sub 3}Br{sub 2} square pyramids. The lattice water molecules and the HBr molecules locate in the voids of the framework. Optical absorption spectrum of 1 reveals the presence of an optical gap of 1.65 eV. Solid-state photoluminescent study indicates that compound 1 exhibits strong violet emission. TG–DSC measurement shows that compound 1 is thermally stable up to 200 °C. - Graphical abstract: A metal selenite halide has been synthesized and features a 3-D open-framework structure, composing edge-shared CdO{sub 8} decahedra and pillars of edge-sharing pentahedra. UV–vis, TG–DSC and luminescent measurements are also reported. Highlights: • This paper reports a novel cadmium selenite bromide obtained by an intermediate-temperature solid-state reaction. • The title compound is characteristic of a novel 3-D open-framework structure, composing {sub ∞}{sup 2}[CdSeO{sub 3}] layers and the pillars of edge-shared CdO{sub 3}Br{sub 2} square pyramids. • The title compound is thermally stable up to 200 °C. • The title compound has an optical gap of 1.65 eV and exhibits strong violet emission.

  1. Mutual neutralization of atomic rare-gas cations (Ne{sup +}, Ar{sup +}, Kr{sup +}, Xe{sup +}) with atomic halide anions (Cl{sup −}, Br{sup −}, I{sup −})

    SciTech Connect (OSTI)

    Shuman, Nicholas S.; Miller, Thomas M.; Viggiano, Albert A.; Johnsen, Rainer

    2014-01-28

    We report thermal rate coefficients for 12 reactions of rare gas cations (Ne{sup +}, Ar{sup +}, Kr{sup +}, Xe{sup +}) with halide anions (Cl{sup −}, Br{sup −}, I{sup −}), comprising both mutual neutralization (MN) and transfer ionization. No rate coefficients have been previously reported for these reactions; however, the development of the Variable Electron and Neutral Density Attachment Mass Spectrometry technique makes it possible to measure the difference of the rate coefficients for pairs of parallel reactions in a Flowing Afterglow-Langmuir Probe apparatus. Measurements of 18 such combinations of competing reaction pairs yield an over-determined data set from which a consistent set of rate coefficients of the 12 MN reactions can be deduced. Unlike rate coefficients of MN reactions involving at least one polyatomic ion, which vary by at most a factor of ∼3, those of the atom-atom reactions vary by at least a factor 60 depending on the species. It is found that the rate coefficients involving light rare-gas ions are larger than those for the heavier rare-gas ions, but the opposite trend is observed in the progression from Cl{sup −} to I{sup −}. The largest rate coefficient is 6.5 × 10{sup −8} cm{sup 3} s{sup −1} for Ne{sup +} with I{sup −}. Rate coefficients for Ar{sup +}, Kr{sup +}, and Xe{sup +} reacting with Br{sub 2}{sup −} are also reported.

  2. Experimental and ab initio studies of the reactive processes in gas phase i-C{sub 3}H{sub 7}Br and i-C{sub 3}H{sub 7}OH collisions with potassium ions

    SciTech Connect (OSTI)

    Lpez, E.; Lucas, J. M.; Andrs, J. de; Albert, M.; Aguilar, A., E-mail: a.aguilar@ub.edu [Departament de Qumica Fsica, Institut de Qumica Terica i Computacional (IQTCUB), Universitat de Barcelona, Mart i Franqus, 1, 08028 Barcelona (Spain); Bofill, J. M. [Departament de Qumica Orgnica, Institut de Qumica Terica i Computacional (IQTCUB), Universitat de Barcelona, Mart i Franqus, 1, 08028 Barcelona (Spain); Bassi, D. [Dipartimento di Fisica, Universit degli Studi di Trento, 38123 Povo-Trento (Italy)

    2014-10-28

    Collisions between potassium ions and neutral i-C{sub 3}H{sub 7}Br and i-C{sub 3}H{sub 7}OH, all in their electronic ground state, have been studied in the 0.1010.00 eV center of mass (CM) collision energy range, using the radiofrequency-guided ion beam technique. In K{sup +} + i-C{sub 3}H{sub 7}Br collisions KHBr{sup +} formation was observed and quantified, while the analogous KH{sub 2}O{sup +} formation in K{sup +} + i-C{sub 3}H{sub 7}OH was hardly detected. Moreover, formation of the ion-molecule adducts and their decomposition leading to C{sub 3}H{sub 7}{sup +} and either KBr or KOH, respectively, have been observed. For all these processes, absolute cross-sections were measured as a function of the CM collision energy. Ab initio structure calculations at the MP2 level have given information about the potential energy surfaces (PESs) involved. In these, different stationary points have been characterized using the reaction coordinate method, their connectivity being ensured by using the intrinsic-reaction-coordinate method. From the measured excitation function for KHBr{sup +} formation the corresponding thermal rate constant at 303 K has been calculated. The topology of the calculated PESs allows an interpretation of the main features of the reaction dynamics of both systems, and in particular evidence the important role played by the potential energy wells in controlling the reactivity for the different reaction channels.

  3. Use of InSpector{sup TM} 1 1000 Instrument with LaBr{sub 3} for Nuclear Criticality Safety (NCS) Applications at the Westinghouse Hematite Decommissioning Project (HDP) - 13132

    SciTech Connect (OSTI)

    Pritchard, Megan; Guido, Joe

    2013-07-01

    The Westinghouse Hematite Decommissioning Project (HDP) is a former nuclear fuel cycle facility that is currently undergoing decommissioning. One aspect of the decommissioning scope is remediation of buried nuclear waste in unlined burial pits. The current Nuclear Criticality Safety program relies on application of criticality controls based on radiological setpoints from a 2 x 2 Sodium Iodide (NaI) detector. Because of the nature of the material buried (Low Enriched Uranium (LEU), depleted uranium, thorium, and radium) and the stringent threshold for application of criticality controls based on waste management (0.1 g {sup 235}U/L), a better method for {sup 235}U identification and quantification has been developed. This paper outlines the early stages of a quick, in-field nuclear material assay and {sup 235}U mass estimation process currently being deployed at HDP. Nuclear material initially classified such that NCS controls are necessary can be demonstrated not to require such controls and dispositioned as desired by project operations. Using Monte Carlo techniques and a high resolution Lanthanum Bromide (LaBr) detector with portable Multi-Channel Analyzer (MCA), a bounding {sup 235}U mass is assigned to basic geometries of nuclear material as it is excavated. The deployment of these methods and techniques has saved large amounts of time and money in the nuclear material remediation process. (authors)

  4. Magnetic field, frequency and temperature dependence of complex conductance of ultrathin La1.65Sr0.45CuO4/La2CuO4 films and the organic superconductors κ-(BEDT-TTF)2Cu[N(CN)2]Br

    SciTech Connect (OSTI)

    V. A. Gasparov; Bozovic, I.; He, Xi; Dubuis, G.; Pavuna, D.; Kushch, N. D.; Yagubskii, E. B.; Schlueter, J. A.

    2015-09-01

    In this study, we used atomic-layer molecular beam epitaxy (ALL-MBE) to synthesize bilayer films of a cuprate metal (La1.65Sr0.45CuO4) and a cuprate insulator (La2CuO4), in which interface superconductivity occurs in a layer that is just one-half unit cell thick. We have studied the magnetic field and temperature dependence of the complex sheet conductance, σ(ω), of these films, and compared them to κκ-(BEDT-TTF)2Cu[N(CN)2]Br single crystals. The magnetic field H was applied both parallel and perpendicular to the 2D conducting layers. Experiments have been carried out at frequencies between 23 kHz and 50 MHz using either two-coil mutual inductance technique, or the LC resonators with spiral or rectangular coils. The real and the imaginary parts of the mutual-inductance M(T,ω) between the coil and the sample were measured and converted to complex conductivity. For H perpendicular to the conducting layers, we observed almost identical behavior in both films and κ-Br single crystals: (i) the transition onset in the inductive response, Lk–1(T) occurs at a temperature lower by 2 K than in Re σ(T), (ii) this shift is almost constant with magnetic field up to 8 T; (iii) the vortex diffusion constant D(T) is exponential due to pinning of vortex cores. These results can be described by the extended dynamic theory of the Berezinski–Kosterlitz–Thouless (BKT) transition and dynamics of bound vortex–antivortex pairs with short separation lengths.

  5. Magnetic field, frequency and temperature dependence of complex conductance of ultrathin La1.65Sr0.45CuO4/La2CuO4 films and the organic superconductors κ-(BEDT-TTF)2Cu[N(CN)2]Br

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    V. A. Gasparov; Bozovic, I.; He, Xi; Dubuis, G.; Pavuna, D.; Kushch, N. D.; Yagubskii, E. B.; Schlueter, J. A.

    2015-09-01

    In this study, we used atomic-layer molecular beam epitaxy (ALL-MBE) to synthesize bilayer films of a cuprate metal (La1.65Sr0.45CuO4) and a cuprate insulator (La2CuO4), in which interface superconductivity occurs in a layer that is just one-half unit cell thick. We have studied the magnetic field and temperature dependence of the complex sheet conductance, σ(ω), of these films, and compared them to κκ-(BEDT-TTF)2Cu[N(CN)2]Br single crystals. The magnetic field H was applied both parallel and perpendicular to the 2D conducting layers. Experiments have been carried out at frequencies between 23 kHz and 50 MHz using either two-coil mutual inductance technique, or themore » LC resonators with spiral or rectangular coils. The real and the imaginary parts of the mutual-inductance M(T,ω) between the coil and the sample were measured and converted to complex conductivity. For H perpendicular to the conducting layers, we observed almost identical behavior in both films and κ-Br single crystals: (i) the transition onset in the inductive response, Lk–1(T) occurs at a temperature lower by 2 K than in Re σ(T), (ii) this shift is almost constant with magnetic field up to 8 T; (iii) the vortex diffusion constant D(T) is exponential due to pinning of vortex cores. These results can be described by the extended dynamic theory of the Berezinski–Kosterlitz–Thouless (BKT) transition and dynamics of bound vortex–antivortex pairs with short separation lengths.« less

  6. Enhancement of Br ( B d → μ + μ - ) / Br ( B s → μ + μ - ) in supersymmetric unified models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dutta, Bhaskar; Mimura, Yukihiro

    2015-05-14

    We explain the 2.3σ deviation in the recent measurements of the neutral B meson decays into muon pairs from the standard model prediction in the framework of supersymmetric grand unified models using antisymmetric coupling as a new source of flavor violation. We show a correlation between the Bd→μ⁺μ⁻ decay and the CP phase in the Bd→J/ψK decay and that their deviations from the standard model predictions can be explained after satisfying constraints arising from various hadronic and leptonic rare decay processes, B-B¯, K-K¯ oscillation data, and electric dipole moments of electron and neutron. The allowed parameter space is typically representedmore » by pseudoscalar Higgs mass mA≤1 TeV and tanβH(≡vu/vd)≲20 for squark and gluino masses around 2 TeV.« less

  7. Abraham Hot Springs Geothermal Area Northern Basin and Range...

    Open Energy Info (EERE)

    br Brophy br Model br Moeck br Beardsmore br Type br Volume br Geothermal br Region Mean br Reservoir br Temp br Mean br Capacity Abraham Hot Springs Geothermal Area Northern Basin...

  8. Materials Data on CuTe2Br (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  9. Materials Data on Tl2TeBr6 (SG:128) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  10. Materials Data on BiTeBr (SG:156) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  11. Materials Data on BrO2F (SG:9) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  12. Materials Data on Li6Br3N (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. Materials Data on B5H6Br (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Materials Data on H4BrN (SG:215) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  15. Oxidation/Reduction Reactions at the Metal Contact-TlBr Interface...

    Office of Scientific and Technical Information (OSTI)

    DOE Contract Number: DE-AC52-07NA27344 Resource Type: Conference Resource Relation: Conference: Presented at: SPIE Optics & Photonics, San Diego, CA, United States, Aug 17 - Aug ...

  16. RELAP5 Model Description and Validation for the BR2 Loss-of-Flow Experiments

    SciTech Connect (OSTI)

    Licht, J. R.; Dionne, B.; Van den Branden, G.; Sikik, E.; Koonen, E.

    2015-07-01

    This paper presents a description of the RELAP5 model, the calibration method used to obtain the minor loss coefficients from the available hydraulic data and the LOFA simulation results compared to the 1963 experimental tests for HEU fuel.

  17. Materials Data on Cd(W3Br7)2 (SG:201) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. Materials Data on CdBr2 (SG:186) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  19. Materials Data on Ta(TeBr3)2 (SG:2) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  20. Materials Data on Ta3(Se4Br3)2 (SG:2) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-03-19

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. Materials Data on Pd(SeBr3)2 (SG:2) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  2. Materials Data on Bi(TeBr2)2 (SG:2) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  3. Materials Data on CrBrO (SG:59) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Materials Data on Cs2SbBr6 (SG:0) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Look at the Impact of Building, Cooling, Heating, and Power (BCHP) and Innovation, June ... 2004 Photo credit: Oak Ridge National Lab Residential Absorption Heat Pump Water Heater

  6. Materials Data on Th6CoBr15 (SG:229) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Materials Data on ThBrN (SG:129) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  8. Spectroscopic Evidence for a High-Spin Br-Fe(IV)-Oxo Intermediate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fungicides and antibiotics. Four classes of enzymes are now known to catalyze halogenation reactions: 1) vanadium haloperoxidases, 2) heme haloperoxidases, 3)...

  9. LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON

    U.S. Energy Information Administration (EIA) Indexed Site

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1000 MBOE 1000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Appalachian Basin Boundary C a n a d a N Y P A N Y U S A Appalachian Basin, NY Area (Panel 1 of 7) Oil and Gas Fields By 2001 BOE

  10. LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquids Reserve Class No 2001 Liiquids Reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1000 Mbbl 1000.1 - 10,000 Mbbl Appalachian Basin Boundary C a n a d a N Y P A N Y U S A Appalachian Basin, NY Area (Panel 1 of 7) Oil and Gas Fields By 2001 Liquids

  11. Materials Data on PH9C3Br3N (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  12. Materials Data on PH4Br (SG:129) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. Materials Data on PaBr4 (SG:141) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Materials Data on PaBr5 (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  15. Materials Data on S4(BrN)3 (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquids Reserve Class No 2001 Liiquids Reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1000 Mbbl 1000.1 - 10,000 Mbbl Appalachian Basin Boundary C a n a d a N Y P A N Y U S A ...

  17. LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON

    U.S. Energy Information Administration (EIA) Indexed Site

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1000 MBOE 1000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Appalachian Basin Boundary C a n a d ...

  18. Modeling carbon nanotube growth on the catalyst-substrate surface subjected to reactive plasma [<br>

    SciTech Connect (OSTI)

    Tewari, Aarti; Sharma, Suresh C.

    2014-06-15

    The paper presents a theoretical model to study the growth of the carbon nanotube (CNT) on the catalyst substrate surface subjected to reactive plasma. The charging rate of the CNT, kinetics of electron, ions and neutral atoms, the growth rate of the CNT because of diffusion and accretion of ions on the catalyst nanoparticle inclusion of the issue of the plasma sheath is undertaken in the present model. Numerical calculations on the effect of ion density and temperature and the substrate bias on the growth of the CNT have been carried out for typical glow discharge plasma parameters. It is found that the height of CNT increases with the ion density of carbon ions and radius of CNT decreases with hydrogen ion density. The substrate bias also affects the growth rate of the CNT. The field emission characteristics from the CNTs can be analyzed from the results obtained.

  19. Materials Data on Y4OsBr4 (SG:15) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  20. Materials Data on Rb3Os2Br9 (SG:194) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. Materials Data on OsBr4 (SG:61) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  2. Materials Data on K2OsBr6 (SG:225) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  3. Materials Data on LiBr (SG:225) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Materials Data on Pd(PbBr3)2 (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. Materials Data on Tl3PdBr5 (SG:61) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  6. Materials Data on KAl2Br7 (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Materials Data on KPb2Br5 (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  8. Materials Data on K2(NbBr3)3 (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  9. Method of increments for the halogen molecular crystals: Cl, Br, and I

    SciTech Connect (OSTI)

    Steenbergen, Krista G.; Gaston, Nicola; Müller, Carsten; Paulus, Beate

    2014-09-28

    Method of increments (MI) calculations reveal the n-body correlation contributions to binding in solid chlorine, bromine, and iodine. Secondary binding contributions as well as d-correlation energies are estimated and compared between each solid halogen. We illustrate that binding is entirely determined by two-body correlation effects, which account for >80% of the total correlation energy. One-body, three-body, and exchange contributions are repulsive. Using density-fitting (DF) local coupled-cluster singles, doubles, and perturbative triples for incremental calculations, we obtain excellent agreement with the experimental cohesive energies. MI results from DF local second-order Møller-Plesset perturbation (LMP2) yield considerably over-bound cohesive energies. Comparative calculations with density functional theory and periodic LMP2 method are also shown to be less accurate for the solid halogens.

  10. Materials Data on CuSe3Br (SG:53) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  11. Materials Data on La5(AlBr)4 (SG:140) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-02-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  12. Materials Data on Ga2PdBr8 (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. Materials Data on Tb6Br7 (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Materials Data on Hg3(SeBr)2 (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  15. Materials Data on Tb5Br8 (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. Materials Data on IrBr3 (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  17. Oxidation/Reduction Reactions at the Metal Contact-TlBr Interface...

    Office of Scientific and Technical Information (OSTI)

    A paper copy of this document is also available for sale to the public from the National Technical Information Service, Springfield, VA at www.ntis.gov. Authors: Nelson, A J ; ...

  18. Materials Data on RbBr (SG:221) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  19. Materials Data on CsBr (SG:221) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  20. Materials Data on CuW3Br7 (SG:201) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. Materials Data on W3Br8 (SG:64) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-03-24

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  2. Tank Farm Closure & Waste Management Environmental Impact Statement <br>

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (DOE/EIS-0391) - Hanford Site Statements Tank Closure & WM EIS Info Documents CERCLA Five-Year Review NEPA - Categorical Exclusions NEPA - Environmental Assessments NEPA - Environmental Impact Statements Environmental Management Performance Reports Tank Farm Closure & Waste Management Environmental Impact Statement (DOE/EIS-0391) Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size The U.S. Department of Energy (USDOE) has prepared a Final Environmental

  3. Materials Data on HgBrO3 (SG:15) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Materials Data on CsHgBr3 (SG:221) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. Materials Data on Tl4HgBr6 (SG:128) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  6. Materials Data on Hg3(TeBr)2 (SG:199) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Materials Data on C(Se2Br)2 (SG:33) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  8. Materials Data on Na3Al3Si3AgBrO12 (SG:9) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  9. Materials Data on SiP3H29C10BrN (SG:14) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  10. Feasibility of a superhigh energy-density battery of the Li/BrF sub 3 electrochemical system. Technical report

    SciTech Connect (OSTI)

    Pyszczek, M.F.; Ebel, S.J.; Frysz, C.A.

    1989-01-01

    To date, design and construction of a material-handling and measurement system along with the apparatus required for waste material disposal has been completed. Preliminary corrosion screening of potential case materials is currently underway. A review of the literature, has led us to the use of Monel (trademark) 400 as the material of construction for the handling and measurement system. The inherent stability of this material with bromine trifluoride in its liquid state is crucial to ensure that contamination does not occur during storage and handling. For applications which require a flexible or transparent material, items fabricated from perfluoroalkyoxy polymers (Teflon) (trademark PFA) were utilized. One such application encountered was in the design of the graduated tank which allows visual inspection of the material prior to dispensing. Containers used for compatibility/corrosion testing were also constructed of PFA.

  11. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Credit: James Pryatel<br>>br>>

  12. Timeline and Updates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.5.2<br>cray-tpsl1.5.2<br>cray-trilinos11.12.1.5<br>craype2.5.0<br>craypkg-gen1.3.2<br>fftw3.3.4.6<br>iobuf2.0.6<br>papi5.4.1.3<br>parallel-netcdf...

  13. Feasibility of a superhigh energy-density battery of the Li/BrF sub 3 electrochemical system. Progress report, 15 October-15 December 1989

    SciTech Connect (OSTI)

    Pyszczek, M.F.; Ebel, S.J.; Frysz, C.A.

    1989-12-15

    The feasibility of developing a lithium/bromine trifluoride battery is being studied. Critical to this product development is materials selection. Consequently, efforts have been directed toward identifying candidate porous electrode separators, glasses for insulated electrical feed-throughs and metals for lid, case, and current-collector fabrication. Samples were evaluated via electrochemical testing techniques and one month storage in Teflon vials. Vial test results for metal samples did not vary significantly from those reported in technical report 0001AA. Of the separator samples tested, Raychem proves to be most promising. Further study is required regarding glass selection. Electrochemical testing is still in progress.

  14. Evidence for penguin-diagram decays: First observation of [ital B][r arrow][ital K][sup *](892)[gamma

    SciTech Connect (OSTI)

    Ammar, R.; Ball, S.; Baringer, P.; Coppage, D.; Copty, N.; Davis, R.; Hancock, N.; Kelly, M.; Kwak, N.; Lam, H.; Kubota, Y.; Lattery, M.; Nelson, J.K.; Patton, S.; Perticone, D.; Poling, R.; Savinov, V.; Schrenk, S.; Wang, R.; Alam, M.S.; Kim, I.J.; Nemati, B.; O'Neill, J.J.; Severini, H.; Sun, C.R.; Zoeller, M.M.; Crawford, G.; Daubenmeir, M.; Fulton, R.; Fujino, D.; Gan, K.K.; Honscheid, K.; Kagan, H.; Kass, R.; Lee, J.; Malchow, R.; Morrow, F.; Skovpen, Y.; Sung, M.; White, C.; Whitmore, J.; Wilson, P.; Butler, F.; Fu, X.; Kalbfleisch, G.; Lambrecht, M.; Ross, W.R.; Skubic, P.; Snow, J.; Wang, P.L.; Wood, M.; Bortoletto, D.; Brown, D.N.; Fast, J.; McIlwain, R.L.; Miao, T.; Miller, D.H.; Modesitt, M.; Schaffner, S.F.; Shibata, E.I.; Shipsey, I.P.J.; Wang, P.N.; Battle, M.; Ernst, J.; Kroha, H.; Roberts, S.; Sparks, K.; Thorndike, E.H.; Wang, C.H.; Dominick, J.; Sanghera, S.; Skwarnicki, T.; Stroynowski, R.; Artuso, M.; He, D.; Goldberg, M.; Horwitz, N.; Kennett, R.; Moneti, G.C.; Muh

    1993-08-02

    We have observed the decays [ital B][sup 0][r arrow][ital K][sup *](892)[sup 0][gamma] and [ital B][sup [minus

  15. Development of a promising filtration method for liquid clarification in nuclear facilities. [For TMI-2 water, reprocessing dissolver solutions, ZnBr/sub 2/ shielding solutions

    SciTech Connect (OSTI)

    Collins, E.D.; Knauer, J.B.; Byrd, L.A.; Ross, R.G.; Savage, H.C.

    1982-01-01

    Conclusions reached are that deep beds of diatomaceous earths are especially attractive for clarification of radioactive solutions, or slurries containing insoluble radioactive material, because the diatomaceous material provides a noncompressible medium that is retentive for a wide variety of particle sizes. Also, the diatomaceous material, because of its inorganic composition, is resistant to degradation by radiation from the retained particulate matter. Its silicious character is especially appropriate for conversion to vitrified or cement-type waste forms. This paper studied the use of diatomaceous earth to filter synthetic TMI-2 water, reprocessing dissolver solutions, and zinc bromide solutions (hot-cell shielding).

  16. emergency preparedness

    National Nuclear Security Administration (NNSA)

    to provide assurances of an effective response:<br ><br >Structured TrainingDrills Program<br >A comprehensive, coordinated, and documented program of training...

  17. --No Title--

    U.S. Energy Information Administration (EIA) Indexed Site

    (M) release date: January 29, 2016 for November 2015 data<br>Next monthly release: End of February 2016 (December 2015 data)<br>><---Re...

  18. --No Title--

    U.S. Energy Information Administration (EIA) Indexed Site

    Release Date: January 28, 2016 for November 2015 data<br>Next Monthly Release: End of February 2016 for December 2015 data<br>><---b>Month...

  19. --No Title--

    U.S. Energy Information Administration (EIA) Indexed Site

    04, 2016<br>Next Release Date: February 18, 2016 <---<br>PJM West data for 2005-2012Re-released---><br>>

  20. Property:Incentive/Amt | Open Energy Information

    Open Energy Info (EERE)

    19-211unit<br > LED or Induction HE Garage: 43-483unit<br > LED Traffic (Red, Yellow, Green): 19unit<br > LED Traffic (Pedestrian): 7unit<br > Occupancy...

  1. Measurement of sigma p anti-p --> Z . Br (Z --> 2tau) in p anti-p collisions at s**(1/2) = 1.96 TeV

    SciTech Connect (OSTI)

    Abulencia, A.

    2007-02-01

    We present a measurement of the inclusive production cross-section for Z bosons decaying to tau leptons in p{bar p} collisions at {radical}s = 1.96 TeV. We use a channel with one hadronically-decaying and one electronically-decaying tau. This measurement is based on 350 pb{sup -1} of CDF Run II data. Using a sample of 504 opposite sign e{tau} events with a total expected background of 190 events, we obtain {sigma}(p{bar p} {yields} Z) {center_dot} {Beta}(Z {yields} {tau}{tau}) = 263 {+-} 23(stat) {+-} 14(syst) {+-} 15(lumi) pb, in agreement with the next-to-next-to-leading order QCD prediction. This is the first CDF cross section measurement using hadronically-decaying taus in Run II.

  2. acquisition management

    National Nuclear Security Administration (NNSA)

    the science, technology, and engineering base; and,

  3. Continue NNSA management reforms.
  1. Aluminum electroplating on steel from a fused bromide electrolyte

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Laura A. Wurth; Eric J. Dufek; Toni Y. Gutknecht; Natalie J. Gese; Paula Hahn; Steven M. Frank; Guy L. Frederickson; J. Stephen Herring

    2014-08-01

    A quaternary bromide bath (LiBrKBrCsBrAlBr3) was used to electro-coat aluminum on steel substrates. The electrolytewas prepared by the addition of AlBr3 into the eutectic LiBrKBrCsBr melt. A smooth, thick, adherent and shiny aluminum coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminum coverage. Both salt immersion and open circuit potential measurement suggested that the coatings did display a good corrosionresistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminum coating in preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminumcoating on both ferrous and non-ferrous metals, including complex surfaces/geometries.

  2. Aluminium Electroplating on Steel from a Fused Bromide Electrolyte

    SciTech Connect (OSTI)

    Prabhat Tripathy; Laura Wurth; Eric Dufek; Toni Y. Gutknecht; Natalie Gese; Paula Hahn; Steven Frank; Guy Fredrickson; J Stephen Herring

    2014-08-01

    A quaternary bromide bath (LiBr-KBr-CsBr-AlBr3) was used to electro-coat aluminium on steel substrates. The electrolyte was prepared by the addition of AlBr3 into the eutectic LiBr-KBr-CsBr melt. A smooth, thick, adherent and shiny aluminium coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminium coverage. Both salt immersion and open circuit potential measurement suggest that the coatings did display good corrosion-resistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminium coating in preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminium coating on both ferrous and non-ferrous metals, including complex surfaces/geometries.

  3. Apparatus and method for downhole injection of radioactive tracer

    DOE Patents [OSTI]

    Potter, R.M.; Archuleta, J.; Fink, C.F.

    The disclosure relates to downhole injection of radioactive /sup 82/Br and monitoring its progress through fractured structure to determine the nature thereof. An ampule containing granular /sup 82/Br is remotely crushed and water is repeatedly flushed through it to cleanse the instrument as well as inject the /sup 82/Br into surrounding fractured strata. A sensor in a remote horehole reads progress of the radioactive material through fractured structure.

  4. Apparatus and method for downhole injection of radioactive tracer

    DOE Patents [OSTI]

    Potter, Robert M.; Archuleta, Jacobo R.; Fink, Conrad F.

    1983-01-01

    The disclosure relates to downhole injection of radioactive .sup.82 Br and monitoring its progress through fractured structure to determine the nature thereof. An ampule containing granular .sup.82 Br is remotely crushed and water is repeatedly flushed through it to cleanse the instrument as well as inject the .sup.82 Br into surrounding fractured strata. A sensor in a remote borehole reads progress of the radioactive material through fractured structure.

  5. Microsoft Word - NMMSS News DEC 23 08 Update.doc

    National Nuclear Security Administration (NNSA)

    IS SPONSORED BY DOE AND NRC NMMSS news PUBLISHED PERIODICALLY BY & FOR NMMSS USERS December 23, 2008 SPECIAL EDITION NUREG/BR-0007, Rev.6 Published The NRC wishes to inform industry that it has published its update of NUREG/BR-0007. This NUREG was updated to reflect changes to NMMSS reports that become effective January 1, 2009. Link to the updated NUREG: http://www.nrc.gov/reading-rm/doc-collections/nuregs/brochures/br0007/r6/index.html

  6. U

    National Nuclear Security Administration (NNSA)

    NRC Has Published Draft Updates of NUREG/BR-0006 & 0007 For Public Comment In the March 21, 2007 Federal Register (electronic link) the NRC publicized proposed revisions to NUREG/BR- 0006 and NUREG/BR-0007 for public comment. Following is a repeat of some of the information contained in this Federal Register. "The U.S. Nuclear Regulatory Commission (NRC) is proposing revisions to NUREG/BR-0006, Instructions for the Preparation and Distribution of Material Transaction Reports, and

  7. Next Generation Household Refrigerator | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Next Generation Household Refrigerator Next Generation Household Refrigerator Embraco's high efficiency, oil-free linear compressor.<br > Credit: Whirlpool Embraco's high ...

  8. hrp

    National Nuclear Security Administration (NNSA)

    Program<br >NNSA possesses approximately half of the Department of Energy (DOE) active personnel security clearances, including 65% of the "Q" (which is for...

  9. Membranes Optimized for High Conductivity and Low Crossover of Redox Flow Cells 2015-033

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2015-05-19

    Researchers at Berkeley Lab have determined that membrane properties have a significant impact on the performance and efficiency of the bromine-hydrogen (Br...

  10. New Configuration and Materials for Scalable Bioelectrochemical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marketing Summary2.pdf (160 KB) Proposed spiral wound BES system for more efficient waste treatment and energy production.<br > Proposed spiral wound BES system for...

  11. Doc...~En.

    Office of Legacy Management (LM)

    ... ..,,..,.... - .. I&i3:scD .::-:, TO-340 .":: ..' . - ' - -. ' . .." ,.. .;.. Very traly yours;, -' .X :, Doc...En. ' Br.:Re&ng ';;a' : , Div. Reading File ., ,, ., ,.-...

  12. Microfluidic Polymer Valves - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact SNL About This Technology Check valve incorporating a mobile polymer <br >monolith into a multiple-level silica microchannel. Check valve incorporating a mobile polymer ...

  13. Property:References | Open Energy Information

    Open Energy Info (EERE)

    F Fault Mapping + Curewitz and Karsen, 1997, http:www.sciencedirect.comsciencearticlepiiS0377027397000279 <br>Caskey and Wesnousky, 2000, http:...

  14. Micro-Earthquake At Coso Geothermal Area (2007) | Open Energy...

    Open Energy Info (EERE)

    area Julian, B.R.; Foulger, G.R. (1 January 2010) IMPROVED METHODS FOR MAPPING PERMEABILITY AND HEAT SOURCES IN GEOTHERMAL AREAS USING MICROEARTHQUAKE DATA Additional...

  15. High Performance Buildings Database | Open Energy Information

    Open Energy Info (EERE)

    >Owner: Miller Brothers Construction Inc.<br >

  16. Advanced Hybrid Water Heater using Electrochemical Compressor...

    Broader source: Energy.gov (indexed) [DOE]

    Chemical Compression (ECC) technology to operate a heat pump cycle using water as the working fluid<br > Image: Xergy Xergy is using its Electro Chemical Compression (ECC) ...

  17. 10-04-2010 CA-B-10-0154

    National Nuclear Security Administration (NNSA)

    develop a novel fieldable laser-induced incandescence sensor to measure black carbon (BC) and brown carbon (BrC) organic aerosols and their optical and chemical characteristics. ...

  18. Vykson Formerly Turbine Developments NI Ltd | Open Energy Information

    Open Energy Info (EERE)

    Vykson Formerly Turbine Developments NI Ltd Jump to: navigation, search Name: Vykson (Formerly Turbine Developments (NI) Ltd) Place: Canterbury, England, United Kingdom Zip: BR6...

  19. Hanford Site C Tank Farm Meeting Summary

    Office of Environmental Management (EM)

    4800 EDTECN: DRF UC: Cost Center: Charge Code: B&R Code: Total Pages: 13 Key Words: Waste Management Area C, Performance Assessment, tank closure, waste inventory...

  20. Hanford Site C Tank Farm Meeting Summary

    Office of Environmental Management (EM)

    EDTECN: DRF UC: Cost Center: Charge Code: B&R Code: Total Pages: 16 Key Words: Waste Management Area C, Perfonnance Assessment, tank closure, waste inventory...

  1. RECII'IENT:Solazyme, Inc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solazyme proposes to construct the SzlBR on Parcel 2 of the existing PMP Fermentation ... facilities are currently zoned for industrial, manufacturing, or laboratory uses and ...

  2. Rotartica | Open Energy Information

    Open Energy Info (EERE)

    (Bizkaia), Spain Zip: 48970 Product: Spain-based, manufacturer of compact LiBr absorption chillers (suitable for detached houses). References: Rotartica1 This article is a...

  3. pnnl

    National Nuclear Security Administration (NNSA)

    caption" ><br >PNNL physicist Bob Runkle (middle) explains the nuances of neutron detection to physics students MatthewMichalak,Univ. of Wisconsin...

  4. nuclear security

    National Nuclear Security Administration (NNSA)

    caption" ><br >PNNL physicist Bob Runkle (middle) explains the nuances of neutron detection to physics students MatthewMichalak,Univ. of Wisconsin...

  5. Contract No. DE-AC27-OIRVI4136

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DIRECTION B&R No. Budget Description Appropriation Symbol (Control Point) Authority PD 1250 1110462 1,180,000.00 Subtotal - Budgetary Control Points including Program...

  6. Doc.~:Ru.

    Office of Legacy Management (LM)

    .' , .' c,j .c; Distriblition: ;. <; ..,:L.D.i&%.ay,FiN-OR00 Doc.:Ru. ,.,. 75. ' Br..Reading 'ire' ,lliv. Read&q File ,: '. ,, .-' . ...: - SURNAME.....

  7. Property:Incentive/EquipReqs | Open Energy Information

    Open Energy Info (EERE)

    (Electric) - Residential Energy Efficiency Rebate Program (Ohio) + Appliances must be Energy Star<br > ENERGY STAR Heat Pump Replacement: Existing HP must be SEER 13 and HSPF...

  8. DE-AC05-06OR23100

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    referenced Work Authorization(s): Work Authorization Number Work Authorization Title FD04103636 Revision 0 (Attachment 1) B&R No. FD0412000 Completing National Priority List...

  9. DE-AC05-06OR23100

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    referenced Work Authorization(s): Work Authorization Number Work Authorization Title FD04019OR36 ARRA-1 Rev 04 (Attachment 1) B&R No. FD412000 Characterization,...

  10. DE-AC05-06OR23100

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    referenced Work Authorization(s): Work Authorization Number Work Authorization Title FD04019OR36 ARRA-1 Rev 04 (Attachment 1) B&R No. FD0412000 Characterization,...

  11. DE-AC05-06OR23100

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    referenced Work Authorization(s): Work Authorization Number Work Authorization Title FD04019OR36 ARRA-1 Rev 03 (Attachment 1) B&R No. FD412000 Characterization,...

  12. Property:Incentive/EligSysSize | Open Energy Information

    Open Energy Info (EERE)

    minimum<br > Recycled Energy: 15 Megawatt maximum Alameda Municipal Power - Solar Photovoltaics Rebate Program (California) + Maximum size is 1 MW or 110% of customer's...

  13. Enncloc&et

    Office of Legacy Management (LM)

    .T I. 0 ,; ..i ,I.. ' (,' . . .._ . . . . . . . . . Enncloc&et tm w&r Farm (ln quild.) Res. Ser. Br. 'Feed Idtrls. Fin&" Beenrkm

  14. defense

    National Nuclear Security Administration (NNSA)

    >Madelyn Creedon, Assistant Secretary for Global Strategic Affairs<br >Andrew Weber, Assistant Secretary of Defense for Nuclear, Chemical & Biological Defense...

  15. sherwood-randall

    National Nuclear Security Administration (NNSA)

    made stops at several tour locations to get a first-hand look at the advanced manufacturing operations.<br >

  16. Development of a Bio-Based, Inexpensive, Noncorrosive, Nonflammable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of a Bio-Based, Inexpensive, Noncorrosive, Nonflammable Phenolic Foam for ... Inside the lab of Fraunhofer Center for Sustainable Energy Systems (CSE) in Boston, MA<br ...

  17. C:\\Forms\\DOE F 1350.4.cdr

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Equipment (check) 12. Other Equipment (check) 13. If Audio Recording Requested, DOE Br. ... No Projection Services Required Projectors (vu-graph) Projectors: 35mm Audio Tape Player ...

  18. Use Low-Grade Waste Steam to Power Absorption Chillers | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (LiBr) Absorption for CHP Applications, April 2005 Improving Steam System Performance: A Sourcebook for Industry, Second Edition Flash High-Pressure Condensate to Regenerate Low

  19. Building Envelope Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MA<br > Photo Courtesy of Fraunhofer CSE, Photo Credit: Trent Bell Development of a Bio-Based, Inexpensive, Noncorrosive, Nonflammable Phenolic Foam for Building Insulation ...

  20. Windows Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lead Performer: Heliotrope Technologies - Oakland, CA Partner: Lawrence Berkeley National Laboratory - Berkeley, CA Image of porous silica material in alcohol.<br > Photo credit: ...

  1. FOIA Frequently Requested Documents: Definitized Subcontract...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ZDO-2-30628-09. Subcontract between Midwest Research Institute National Renewable Energy Laboratory and ... More Documents & Publications CO2 Heat Pump Water Heater Prototype<br > ...

  2. Magnetocaloric Refrigerator/Freezer | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Magnetocaloric Refrigerator/Freezer Magnetocaloric Refrigerator/Freezer Researchers demonstrate General Electric's magnetocaloric system. <br /> Photo courtesy of General Electric Researchers demonstrate General Electric's magnetocaloric system. Photo courtesy of General Electric Researchers demonstrate General Electric's magnetocaloric system. <br /> Photo courtesy of General Electric Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partner: General Electric -

  3. Capacity Value: Evaluation of WECC Rule of Thumb; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Milligan, Michael; Ibanez, Eduardo

    2015-06-09

    This presentation compares loss of load expectation and wind and solar capacity values to the rules of thumb used in the Western Interconnection planning and provides alternative recommendations to the modeling efforts of the Western Electricity Coordinating Council's Transmission Expansion Planning Policy Committee. <br/>/>

  4. Magnetohydrodynamic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Magnetocaloric Refrigerator/Freezer Magnetocaloric Refrigerator/Freezer Researchers demonstrate General Electric's magnetocaloric system. <br /> Photo courtesy of General Electric Researchers demonstrate General Electric's magnetocaloric system. Photo courtesy of General Electric Researchers demonstrate General Electric's magnetocaloric system. <br /> Photo courtesy of General Electric Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partner: General Electric -

  5. Recent content in Green Button Applications | OpenEI Community

    Open Energy Info (EERE)

    Jun 2012 - 15:45 Blog entry OpenEI green button SDK Vgarud 5 Feb 2013 - 11:17 Question Hi Vivek-<br>>I reached... NickL 8 Feb 2013 - 14:03 Answer Probably the best reference...

  6. Local environment in poly(ethylene oxide)-zinc bromide complexes

    SciTech Connect (OSTI)

    Chintipalli, S.; Frech, R.; Grady, B.

    1996-12-31

    This study examines atomic-level local environments in Poly(ethylene oxide)-zinc bromide+lithium bromide (PEO){sub 20}[(ZnBr{sub 2}){sub 1-x} (LiBr){sub x}] complexes using Raman spectroscopy and x-ray absorption spectroscopy (XAS). Specific features in the Raman spectra were used to show that the zinc bromide species changes from ZnBr{sub 2} to ZnBr{sub 3}{sup -} to ZnBr{sub 4}{sup 2-} when x is varied from 0 to 0.8. XAS showed a similar change in oxygen coordination number from 4 to 0 when x is varied from 0 to 0.8. This study shows that lithium atoms displace zinc atoms from ether oxygen speciation indicating that lithium coordination to ether oxygens is thermodynamically favored. The effect of adding polar plasticizers is also discussed.

  7. Chamber wall interactions with HBr/Cl{sub 2}/O{sub 2} plasmas

    SciTech Connect (OSTI)

    Srivastava, Ashutosh K.; Ohashi, Tomohiro; Donnelly, Vincent M.

    2015-07-15

    The authors have studied the interaction of HBr/Cl{sub 2}/O{sub 2} inductively coupled plasmas with reactor chamber wall deposits, with and without Si etching, using the spinning wall technique. The spinning wall is part of the reactor chamber walls, allowing near-real-time analysis of the composition of surface layers via Auger electron spectrometry and determination of species desorbing off the walls by mass spectrometry. In HBr plasmas with no bias voltage on the Si substrate, and hence no Si etching, HBr is ?30% dissociated, and H{sub 2} and Br{sub 2} form in the plasma. Layers deposited on the reactor chamber contained little if any Br under these conditions. Adding O{sub 2} to an HBr plasma leads to formation of H{sub 2}O and increased Br{sub 2} (compared to a pure HBr plasma) products that desorb from the spinning wall. H{sub 2}O has a very long residence time on the surface. With bias voltage applied to the Si substrate in an HBr plasma, mass spectrometer signals are prominent for SiBr and SiBr{sub 3}, and weaker for SiBr{sub 2}, SiBr{sub 4}, Si{sub 2}Br{sub 4}, Si{sub 2}Br{sub 5}, and Si{sub 2}OBr{sub 5}. Under these conditions, a SiO{sub x}Br{sub y} layer deposits on the spinning wall. Adding 20% O{sub 2} to HBr stops etching and eliminates Br from the surface layer, indicating that Br on the reactor walls is a result of SiBr{sub x} impingement and not from bromination by impinging Br. With HBr/Cl{sub 2} plasmas and no bias on the stage, a SiO{sub x}Cl{sub y} layer deposits, and no Br is detected. HCl, BrCl, and Br{sub 2} were detected in the line-of-sight leak, around the spinning wall, of a HBr/Cl{sub 2} (1:1) gas mixture in the absence of a plasma. Residence time analysis of species in the chamber and a change in the product distribution with a change in the composition of the layer deposited on the chamber wall suggest that reactions forming these products in the absence of a plasma occur on the reactor walls. With a plasma and bias on the Si substrate, both Br and Cl incorporate in the layer, and a rich spectrum with numerous SiCl{sub x}Br{sub y} peaks was observed up to at least 500 amu. The spectrum does not change with the addition of 6% O{sub 2}. Adding 20% O{sub 2} suppresses Br adsorption, but Cl still adsorbs. In 40% O{sub 2}/HBr/Cl{sub 2} plasmas with stage bias, Cl adsorption also ceases and no etching products are observed in the mass spectrum.

  8. Raman spectral studies of aqueous zinc bromide solutions to 300/sup 0/C at pressures of 9 MPa

    SciTech Connect (OSTI)

    Yang, M.M.; Crerar, D.A.; Irish, D.E.

    1988-08-01

    A Raman spectral study of 14 solutions of varying bromide to zinc ratios was conducted up to 300/sup 0/C and 9 MPa. The tetra-, tri-, di- as well as the mono-bromozinc complexes were identified. The signal from the ZnBr/sup +/ complex increased in intensity as temperature increased, for solutions of low bromide- to-zinc ratios. The ZnBr/sub 4//sup 2 -/ species was favored at higher Br/Zn ratios, and higher temperatures favored the formation of the species ZnBr/sub 2/ and ZnBr/sup +/ at the expense of ZnBr/sub 4//sup 2 -/ and ZnBr/sub 3//sup -/. Although solvated water is probably present in these zinc-bromo complexes, they found no evidence of O-Zn vibrations other than for Zn(H/sub 2/O)/sub 6//sup 2 +/. However, spectra of successive dilutions of solutions with high bromide to zinc ratios show a relative change in species populations thereby suggesting that water activity plays a decisive role in complex formation. For the first time trifluoromethanesulfonic acid (HTFMS) has been used as an internal standard in Raman spectroscopy. This permitted quantitative measurement of stepwise stability constants.

  9. Comparison of the Distributions of Bromine, Lead and Zinc in Tooth and Bone from an Ancient Peruvian Burial site by X-ray Fluorescence

    SciTech Connect (OSTI)

    Martin,R.; Naftel, S.; Nelson, A.; Sapp, W.

    2007-01-01

    Synchrotron micro X-ray fluorescence was used to study the distribution of selected trace elements (Zn, Pb, and Br) in tooth and bone samples obtained from an individual from a pre-Columbian archaeological site (Cabur) located on the north coast of Peru. The results show that Zn, Pb, and Br are present in both the teeth and bone samples and that the Zn and Pb seem to be confined to similar regions (cementum and periostium), while Br shows a novel distribution with enrichment close to the Haversian canals and (or) in regions that appear to be Ca deficient.

  10. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Historic Lasers <h3>Argus Laser Bay</h3>The two-beam Argus laser came online In 1976. Use of Argus increased knowledge about laser propagation limits and helped LLNL Laser Program researchers develop technologies needed for the next generation of laser fusion systems.<br/><br/><a href="content/assets/images/media/photo-gallery/large/nif-1109-17874.jpg" target="_blank">Download hi-res image</a><br/><a

  11. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Construction <h3>Victor Reis</h3>Victor Reis, the Assistant Secretary for the Department of Energy's Defense Programs, played a key leadership role in the 1990s in defining the emerging Stockpile Stewardship Program and the need for the National Ignition Facility.<br/><br/><a href="content/assets/images/media/photo-gallery/large/nif-1209-18052.jpg" target="_blank">Download hi-res image</a><br/><a

  12. Brazil-World Bank Climate Projects | Open Energy Information

    Open Energy Info (EERE)

    1.1 Sao Paulo Metro Line 5 Project 1.2 BR-GEF Sustainable Transport and Air Quality Project (STAQ) 1.3 First Programmatic Development Policy Loan for Sustainable...

  13. small buisness

    National Nuclear Security Administration (NNSA)

    DOE prime contractors.<BR >

  14. I!' L;I)

    Office of Legacy Management (LM)

    If possi?Ae, a slight deisy should be xade br'txeel: the withdrawing of the slugs from the chuck and tiye .:pening ;si the loading zoct to ally the oil m is.;: and fumes to be ...

  15. PrintRes_PeriodicChartPostCard2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    56 Ba Barium 73 Ta Tantalum 19 K Potassium 20 Ca Calcium 21 Sc Scandium 22 Ti Titanium 30 Zn Zinc 31 Ga Gallium 32 Ge Germanium 33 As Arsenic 34 Se Selenium 35 Br Bromine ...

  16. A=5He (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Absolute differential cross sections are reported (BR58B). For Ed > 3.71 MeV, deuteron breakup (reaction (c)) is energetically possible. The cross section for this process has been...

  17. Distribution:

    Office of Legacy Management (LM)

    bav@ @esiaw*cp Suppl. file 'Br & Div rf's shealth (lic.only) UNITED STATES ATOMIC ENERGY COMMISSION SPECIAL NUCLEAB MATERIAL LICENSE pursuant to the Atomic Energy Act of 1954 ...

  18. Microsoft PowerPoint - Oxford_MiniBooNE_and_SterileNus.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -3 < BR < 4.0 x 10 -3 (90% CL) + e + e unlikely to explain LSND signal (also will be investigated by TWIST exp. at TRIUMF) 10 Adding Sterile Neutrinos to...

  19. CENSUS","FIPST","OWNER","PMOVER","FUELTYP","COCODE","PLTCODE...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... GAS & ELECTRIC CO","HAMILTON BR",5400,,52224,0,0,1285,,,86,2601400,0,...14,1,05336,"FO2","IC" 31,39,5,2,2,605,1,"HAMILTON (CITY OF)","HAM MUN EL",128000,"LIGHT ...

  20. 63,01,1,1,,10,1,"ALABAMA POWER CO","BANKHEAD DM",0,,50022,0,0...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... GAS & ELECTRIC CO","HAMILTON BR",0,,52224,0,0,1287,,,88,953200,0,0,11...14,1,05336,"FO2","IC" 31,39,5,2,2,605,1,"HAMILTON (CITY OF)","HAM MUN EL",0,"LIGHT ...

  1. CENSUS","FIPST","OWNER","PMOVER","FUELTYP","COCODE","PLTCODE...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... GAS & ELECTRIC CO","HAMILTON BR",5390,,14328,0,0,1283,,,84,3696700,0,...14,1,50806,"FO2","IC" 31,39,5,2,2,605,1,"HAMILTON (CITY OF)","HAM MUN EL",127991,"LIGHT ...

  2. 63,01,1,1,,10,1,"ALABAMA POWER CO","BANKHEAD DM",0,,19500,1293...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... GAS & ELECTRIC CO","HAMILTON BR",0,,1432800,1293,,,94,1962,0,0,1168,0...14,1,50806,"FO2","IC" 31,39,5,2,6,605,1,"HAMILTON (CITY OF)","HAM MUN EL",0,"BIT ...

  3. CENSUS","FIPST","OWNER","PMOVER","FUELTYP","COCODE","PLTCODE...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... GAS & ELECTRIC CO","HAMILTON BR",0,,52224,0,0,1286,,,87,1321000,0,0,1...14,1,05336,"FO2","IC" 31,39,5,2,2,605,1,"HAMILTON (CITY OF)","HAM MUN EL",0,"LIGHT ...

  4. 63,01,1,1,,10,1,"ALABAMA POWER CO","BANKHEAD DM",0,,50022,0,0...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... GAS & ELECTRIC CO","HAMILTON BR",0,,52224,0,0,1288,,,89,633000,0,0,58...14,1,05336,"FO2","IC" 31,39,5,2,2,605,1,"HAMILTON (CITY OF)","HAM MUN EL",0,"LIGHT ...

  5. 63,01,1,1,,10,1,"ALABAMA POWER CO","BANKHEAD DM",0,,50022,0,0...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... GAS & ELECTRIC CO","HAMILTON BR",0,,52224,0,0,1289,,,90,1884,0,0,791,...14,1,05336,"FO2","IC" 31,39,5,2,2,605,1,"HAMILTON (CITY OF)","HAM MUN EL",0,"LIGHT ...

  6. CENSUS","FIPST","OWNER","PMOVER","FUELTYP","COCODE","PLTCODE...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... GAS & ELECTRIC CO","HAMILTON BR",5390,,52224,0,0,1284,,,85,1431000,0,...14,1,05336,"FO2","IC" 31,39,5,2,2,605,1,"HAMILTON (CITY OF)","HAM MUN EL",127991,"LIGHT ...

  7. Property:Incentive/MaxInc | Open Energy Information

    Open Energy Info (EERE)

    + 20% of the annual C&I Standard Offer Program budget AEP SWEPCO - SMART Source Solar PV Program (Texas) + Residential: 15,000<br > Non-residential: 30,000 AEP Texas Central...

  8. sandia

    National Nuclear Security Administration (NNSA)

    to learn more.<br >

    Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hy...

  9. snl

    National Nuclear Security Administration (NNSA)

    to learn more.<br >

    Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hy...

  10. Transport Energy Impact Analysis; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Gonder, J.

    2015-05-13

    Presented at the Sustainable Transportation Energy Pathways Spring 2015 Symposium on May 13, 2015, this presentation by Jeff Gonder of the National Renewable Energy Laboratory (NREL) provides information about NREL's transportation energy impact analysis of connected and automated vehicles. <br/>

  11. Exclusive and inclusive decays of B mesons into D sub s mesons

    SciTech Connect (OSTI)

    Bortoletto, D.; Goldberg, M.; Horwitz, N.; Jain, V.; Mestayer, M.D.; Moneti, G.C.; Sharma, V.; Shipsey, I.P.J.; Skwarnicki, T.; Thulasidas, M.; Csorna, S.E.; Letson, T.; Alexander, J.; Artuso, M.; Bebek, C.; Berkelman, K.; Cassel, D.G.; Cheu, E.; Coffman, D.M.; Crawford, G.; DeWire, J.W.; Drell, P.S.; Ehrlich, R.; Galik, R.S.; Gittelman, B.; Gray, S.W.; Halling, A.M.; Hartill, D.L.; Heltsley, B.K.; Kandaswamy, J.; Katayama, N.; Kreinick, D.L.; Lewis, J.D.; Mistry, N.B.; Mueller, J.; Namjoshi, R.; Nandi, S.; Nordberg, E.; O'Grady, C.; Peterson, D.; Pisharody, M.; Riley, D.; Sapper, M.; Silverman, A.; Stone, S.; Worden, H.; Worris, M.; Sadoff, A.J.; Avery, P.; Besson, D.; Garren, L.; Yelton, J.; Bowcock, T.; Kinoshita, K.; Pipkin, F.M.; Procario, M.; Wilson, R.; Wolinski, J.; Xiao, D.; Ammar, R.; Baringer, P.; Coppage, D.; Haas, P.; Lam, H.; Jawahery, A.; Park, C.H.; Kubota, Y.; Nelson, J.K.; Perticone, D.; Poling, R.; Fulton, R.; Hempstead, M.; Jensen, T.; Johnson, D.R.; Kagan, H.; Kass

    1990-04-30

    We have studied the production of {ital D}{sub {ital s}} mesons in the decays of {ital B} mesons at the {Upsilon}(4{ital S}) resonance. We report on the first observation of exclusive {ital B}-meson decays {ital B}{r arrow}{ital D}{sub {ital s}}{sup {minus}}{ital D*}{sup +}, {ital B}{r arrow}{ital D}{sub {ital s}}{sup {minus}}{ital D}{sup +}, and {ital B}{r arrow}{ital D}{sub {ital s}}{sup {minus}}{ital D}{sup 0}. We also present a new measurement of the branching ratio and the momentum spectrum for the inclusive decay {ital B}{r arrow}{ital D}{sub {ital s}X}.

  12. Microsoft PowerPoint - lndustry Issues and Perspectives _ Eris...

    National Nuclear Security Administration (NNSA)

    Question regarding the shipment of irradiated reactor fuel: 2 BR-0006 2.1 In the case of spent fuel shipments, in accordance with 10 CFR 73.37, "Requirements for ...

  13. Critical Materials Institute - invention disclosures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a>

  14. High Command Fidelity Electromagnetically Driven Calorimeter (High-CoFi EleDriCal) <br >Patent...

  15. CO2 Heat Pump Water Heater | Department of Energy

    Energy Savers [EERE]

    CO2 Heat Pump Water Heater CO2 Heat Pump Water Heater CO2 Heat Pump Water Heater Prototype<br > Credit: Oak Ridge National Lab CO2 Heat Pump Water Heater Prototype Credit: Oak ...

  16. Working Fluids Low Global Warming Potential Refrigerants - 2013...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    rack and system diagram for the CO2 refrigeration system.<br > Credit: Oak Ridge National Lab High-Efficiency, Low-Emission Refrigeration System Workshop 2: Advanced HVAC&R ...

  17. Advanced Plasma Power APP | Open Energy Information

    Open Energy Info (EERE)

    London, Greater London, United Kingdom Zip: EC2A 1BR Product: London-based geoplasma process technology developer for waste-to-energy systems. Coordinates: 51.506325,...

  18. ARM - PI Product - NOAA PMEL Station Chemistry Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PMEL Station Chemistry Data Submicron and supermicron samples are analyzed by ion chromatography for Cl-, NO3-, SO4-2, Na+, NH4+, K+, Mg2+, and Ca+2. The analysis of MSA-, Br-,...

  19. A=17F (1986AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6AJ04) (See Energy Level Diagrams for 17F) GENERAL: See (1982AJ01) and Table 17.17 [Table of Energy Levels] (in PDF or PS). Nuclear models: (1982ZH01, 1983BR29, 1984ZI04, 1985ME06). Special states: (1981WI1K, 1983AU1B, 1983BR29, 1983WI15, 1984ANZV, 1985ME06, 1985SH24). Electromagnetic transitions: (1982BR24, 1983BR29, 1983TO08, 1984SAZW, 1985AL21). Astrophysical questions: (1981WA1Q, 1981WE1F, 1982WI1B). Complex reactions involving 17F: (1984GR08, 1984HI1A, 1984HO23). Pion reactions: (1980CR03).

  20. Lead and strontium isotopic evidence for crustal interaction...

    Open Energy Info (EERE)

    Kistler, R.W.; Doe and B.R. Published Contributions to Mineralogy and Petrology, 111984 DOI 10.1007BF01150293 Citation Bacon, C.R.; Kurasawa, H.; Delevaux, M.H.; Kistler,...

  21. Revised Manuscript

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Masses, Winnipeg, Canada, 1967 (Winnipeg Univ. Manitoba Press, 1967) 508 1967BR1F F.P. Brady, J.A. Jungerman and J.C. Young, Nucl. Phys. A98 (1967) 241 1967CA17 P. Camiz, Nuovo...

  1. DE-AC05-06OR23100

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Work Authorization(s): Work Authorization Number Work Authorization Title WA No. FD04019OR36 (Revision No. 01) (Attachment 1) B&R No. fd0-41200 Characterization,...

  2. DE-AC05-06OR23100

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    referenced Work Authorization(s): Work Authorization Number Work Authorization Title FD04020OR36 Rev. 1 (Attachment 1a) B&R No. FD0412000 Characterization of Isotope Row...

  3. DE-AC05-06OR23100

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    referenced Work Authorization(s): Work Authorization Number Work Authorization Title FD04020OR36 (Attachment 1a) B&R No. FD0412000 Characterization of Isotope Row Facilities...

  4. Minoan Group | Open Energy Information

    Open Energy Info (EERE)

    Minoan Group Jump to: navigation, search Name: Minoan Group Place: Kent, England, United Kingdom Zip: BR5 1XB Sector: Solar Product: UK-based developer of resorts in Greece that...

  5. A=19Ne (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7AJ02) (See Energy Level Diagrams for 19Ne) GENERAL: See (1983AJ01) and Table 19.21 Table of Energy Levels (in PDF or PS). Nuclear models:(1983BR29, 1983PO02). Special states:...

  6. A=18Ne (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7AJ02) (See Energy Level Diagrams for 18Ne) GENERAL: See (1983AJ01) and Table 18.22 Table of Energy Levels (in PDF or PS). Model calculations:(1982ZH01, 1983BR29, 1984SA37,...

  7. A=20F (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7AJ02) (See Energy Level Diagrams for 20F) GENERAL: See (1983AJ01) and Table 20.2 Table of Energy Levels (in PDF or PS). Model calculations:(1978WI1B, 1982HA43, 1983BR29,...

  8. ITP Industrial Distributed Energy: A Guide to Developing Air...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... The history of air-cooled LiBr chillercooler development suggests that developing such a ... Engine Coolant Waste Heat"; 1999. 4. Arizona Board of Regents, U.S. patent 6155057, ...

  9. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    imagesmediaphoto-gallerylarge40-60-0999-188411.jpg" target"blank">Download hi-res image<br>Direct Link...

  10. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    imagesmediaphoto-gallerylargenifexterior2013-050402.jpg" target"blank">Download hi-res image<br>Direct Link

    NIF...

  11. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    assetsimagesmediaphoto-gallerywebP1186612-lg.jpg" target"blank">Download hi-res image<br>Direct Link

    Master...

  12. Microsoft Word - S05212_2008 Post-Closure InspRpt.doc

    Office of Legacy Management (LM)

    ... B.R. Anderson Pond Lower Little Cr. 1 Lower Little Cr. 2 James Lowe Pond Nobles Pond Howard Smith Pond Figure 7. Tritium Decay Trend and Off-Site Surface Water Sample ...

  13. Consortium for Advanced Simulation of Light Water Reactors (CASL...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Smith, T.M., M.A. Christon, E. Baglietto and H. Luo, "Assessment of Models for Near Wall ... Romano, P., N. Horelik, B.R. Herman, A.G. Nelson, B. Forget and K. Smith, "OpenMC: A ...

  14. Braxenergy | Open Energy Information

    Open Energy Info (EERE)

    Zip: 04002020 Sector: Renewable Energy Year Founded: 2007 Phone Number: 55 11 3889-2233 Website: www.braxenergy.com.br Coordinates: -23.572237, -46.6499856 Show Map...

  15. Exploiting Intrinsic Triangular Geometry in Relativistic He 3...

    Office of Scientific and Technical Information (OSTI)

    GrantContract Number: FG02-03ER412244; BR2012-038; AC02-05CH11231; 20120775PRD4; de-sc0008027 Type: Publisher's Accepted Manuscript Journal Name: Physical Review Letters ...

  16. LED Directional Lamps

    SciTech Connect (OSTI)

    2012-11-01

    Solid-state lighting program technology fact sheet that provides an overview of the current performance of LED PAR-, BR-, R-, and AR-shaped lamps, which were all investigated by CALiPER in 2012.

  17. JNITED STATES ATOMIC ENERGY COMMlSSiON

    Office of Legacy Management (LM)

    ... Radgn could emanatethrough the surficial slag and enter the atmodphe're to be blown downwind. A common wind direction is from the northw&t br west. Radon thus blown may accumulate ...

  18. snl

    National Nuclear Security Administration (NNSA)

    to learn more.<br >

    Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrog...

  19. sandia

    National Nuclear Security Administration (NNSA)

    to learn more.<br >

    Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrog...

  20. Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Image of porous silica material in alcohol.<br > Photo credit: Oak Ridge National Lab Image of porous silica material in alcohol. Photo credit: Oak Ridge National Lab Lead ...

  1. A=11B (1980AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Energy Levels (in PDF or PS). Shell model: (1977BO07, 1977JA14, 1977TE01, 1978BO31). Cluster, collective and rotational models: (1976BR26, 1977BO07, 1977NI1A, 1977OK1C,...

  2. CEM_Metrics_and_Technical_Note_7_14_10.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    clothes dryer<br > Credit: Oak Ridge National Lab Heat Pump Clothes Dryer CEMMetricsandTechnicalNote71410.pdf Wind Vision: A New Era for Wind Power in the United States

  3. Criticality Safety Basics for INL Emergency Responders

    SciTech Connect (OSTI)

    Valerie L. Putman

    2012-08-01

    This document is a modular self-study guide about criticality safety principles for Idaho National Laboratory emergency responders. This guide provides basic criticality safety information for people who, in response to an emergency, might enter an area that contains much fissionable (or fissile) material. The information should help responders understand unique factors that might be important in responding to a criticality accident or in preventing a criticality accident while responding to a different emergency. <br>> This study guide specifically supplements web-based training for firefighters (0INL1226) and includes information for other Idaho National Laboratory first responders. However, the guide audience also includes other first responders such as radiological control personnel.<br>> For interested readers, this guide includes clearly marked additional information that will not be included on tests. The additional information includes historical examples (Been there. Done that.), as well as facts and more in-depth information (Did you know …). <br>> INL criticality safety personnel revise this guide as needed to reflect program changes, user requests, and better information. Revision 0, issued May 2007, established the basic text. Revision 1 incorporates operation, program, and training changes implemented since 2007. Revision 1 increases focus on first responders because later responders are more likely to have more assistance and guidance from facility personnel and subject matter experts. Revision 1 also completely reorganized the training to better emphasize physical concepts behind the criticality controls that help keep emergency responders safe. The changes are based on and consistent with changes made to course 0INL1226.<br>>

  4. Stabilized thallium bromide radiation detectors and methods of making the same

    DOE Patents [OSTI]

    Leao, Cedric Rocha; Lordi, Vincenzo

    2015-11-24

    According to one embodiment, a crystal includes thallium bromide (TlBr), one or more positively charged dopants, and one or more negatively charged dopants. According to another embodiment, a system includes a monolithic crystal including thallium bromide (TlBr), one or more positively charged dopants, and one or more negatively charged dopants; and a detector configured to detect a signal response of the crystal.

  5. Effects of PV Module Soiling on Glass Surface Resistance and Potential-Induced Degradation

    SciTech Connect (OSTI)

    Hacke, Peter; Button, Patrick; Hendrickson, Alex; Spataru, Sergiu; Glick, Stephen

    2015-06-14

    The goals of the project were: Determine applicability of transmission line method (TLM) to evaluate sheet resistance of soils on module glass;<br/>Evaluate various soils on glass for changes in surface resistance and their ability to promote potential-induced degradation with humidity (PID);<br/>Evaluate PID characteristics, rate, and leakage current increases on full-size mc-Si modules associated with a conductive soil on the surface.

  6. Appliance Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HVAC, Water Heating, & Appliances » Appliance Projects Appliance Projects This project seeks to demonstrate a ventless residential dryer with an energy factor greater than 4.04.<br /> Photo credit: GE Global Research Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator Lead Performer: GE Global Research, Niskayuna, NY Schematics of a heat pump clothes dryer<br /> Credit: Oak Ridge National Lab Heat Pump Clothes Dryer Lead Performer: Oak Ridge National

  7. Gulf Coast's Texas City Sees Easy Energy Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Applications, April 2005 | Department of Energy objective of this paper is to summarize the development status of air-cooled lithium bromide (LiBr)-water absorption chillers to guide future efforts to develop chillers for combined heat and power (CHP) applications in light-commercial buildings. The key technical barrier to air-cooled operation is the increased tendency for LiBr solutions to crystallize in the absorber when heat-rejection temperatures rise. PDF icon

  8. Residential Absorption Heat Pump Water Heater | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Residential Absorption Heat Pump Water Heater Residential Absorption Heat Pump Water Heater Photo credit: Oak Ridge National Lab Photo credit: Oak Ridge National Lab Diagram of absorption heat pump water heater. <br /> Photo credit: Oak Ridge National Lab Diagram of absorption heat pump water heater. Photo credit: Oak Ridge National Lab Photo credit: Oak Ridge National Lab Diagram of absorption heat pump water heater. <br /> Photo credit: Oak Ridge National Lab Lead Performer: Oak

  9. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control Room <h3>NIF Control Room</h3>The NIF control room is inspired by the National Aeronautics and Space Administration's Mission Control room in Houston, Texas. Control room operators access data through a hierarchy of on-screen graphics menus. Operators can also view videos of the laser beams and target from camera sensors incorporated into the beampath and Target Chamber.<br/><br/><a

  10. Stabilized wide bandgap MAPbBrxI3-x perovskite by enhanced grain size and improved crystallinity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Miao; Bi, Cheng; Yuan, Yongbo; Bai, Yang; Huang, Jinsong

    2015-12-07

    In this study, the light instability of CH3NH3PbIxBr3–x has been raised one of the biggest challenges for its application in tandem solar cells. Here we show that an improved crystallinity and grain size of CH3NH3PbIxBr3–x films could stabilize these materials under one sun illumination, improving both the efficiency and stability of the wide-bandgap perovskite solar cells.

  11. News Item

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lasing in Robust Cesium Lead Halide Perovskite Nanowires Power-dependent emission spectra from a CsPbBr3 nanowire. Narrow emission peaks at approximately 530 nm are indicative of lasing. Inset: A CsPbBr3 nanowire excited past the lasing threshold by a femtosecond pulsed laser. Scientific Achievement Molecular Foundry users achieve stable, high performance lasing in perovskite-based cesium lead halide nanowires (NWs). Significance and Impact These NW lasers demonstrate improved stability compared

  12. Ozone in sea water. Part 1: Chemistry; Part 2: Corrosion of metals

    SciTech Connect (OSTI)

    Wyllie, W.E. II; Brown, B.E.; Duquette, D.J.

    1995-12-01

    Ozonation of sea water for biofouling control is being utilized in desalination processes, heat exchange systems, as well as in salt water aquariums. The chemistry of ozone in sea water is much more complex than in fresh water due to the high concentration of easily oxidizable, ozone-demanding species and the formation of secondary oxidants. The major secondary oxidant is bromine in the form of hypobromite and hypobromous acid (BrO{sup {minus}}/HOBr) which are formed by oxidation of the bromide ion (Br{sup {minus}}), naturally found in sea water in concentrations of 65 mg/L. HOBr can react again with ozone to return Br{sup {minus}}, resulting in accelerated decomposition of ozone, or to form bromate (BrO{sub 3}{sup {minus}}) The BrO ion is known to interfere with the measurement of residual ozone in sea water, so it is important that the feed gas conditions, solution pH, and the hypobromous and bromate concentrations be reported to quantify the amount of ozone introduced into a system. In 0.5 N NaCl and sea water solutions, ozone appears to stabilize the passivity of passivating metals, but susceptibility to crevice corrosion appears to increase in the same environments. The effect of BrO{sup {minus}}/HOBr on the corrosion of metals in sea water is believed to be similar to chlorine and ozone, in that it acts as a strong oxidizer. However, it is not certain whether BrO{sup {minus}}/HOBr and BrO{sub 3}{sup {minus}} have any damaging effects on protective metal films.

  13. Advanced HD Engine Systems and Emissions Control Modeling and Analysis |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential<br /> Credit: Oak Ridge National Lab Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential Credit: Oak Ridge National Lab Cumulative GSHP conditioned building floor space in the United States and China<br /> Credit: Oak Ridge National Lab Cumulative GSHP conditioned building floor space in the United

  14. NMMSS Reports | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    NMMSS Reports U.S. Department of Energy / U.S. Nuclear Regulatory Commission Nuclear Materials Management & Safeguards System NMMSS Reports DOE D-23 DOE Contractors Rev Jan 2012 DOE Manual 474.2 NMMSS User Guide - Coming Soon! NRC D-24 DOE NRC Licensees Rev Jan 2012 NUREG/BR-0007, Rev. 6 NUREG/BR-0006, Rev. 7 The electronic version of the D-2, D-3, and D-15 RIS directories are available upon request.

  15. NMMSS News Jan 2012.cdr

    National Nuclear Security Administration (NNSA)

    - Updated with Registration and Reservation Information NMMSS Germantown Operations NMMSS Team Members NMMSS Due Dates 2012 NMMSS Calendar NMMSS Mailing Addresses (updated January 2012) January 2012 NMMSS Training Course for NRC NMMSS training for NRC Licensees is scheduled for February 7-9, 2012, at DOE Headquarters, in Germantown, MD. This course is designed for individuals with limited experience in NRC reporting requirements and is based on NUREG/BR-0006, Rev. 7 and NUREG/BR-0007, Rev. 6.

  16. NMMSS News Nov 2011.cdr

    National Nuclear Security Administration (NNSA)

    NMMSS Germantown Operations NMMSS Team Members NMMSS Due Dates 2012 NMMSS Calendar NMMSS Mailing Addresses (updated March 2011) November 2011 NMMSS Training Course for NRC NMMSS training for NRC Licensees is scheduled for February 7-9, 2012, at DOE Headquarters, in Germantown, MD. This course is designed for individuals with limited experience in NRC reporting requirements and is based on NUREG/BR-0006, Rev. 7 and NUREG/BR-0007, Rev. 6. The following topics, among others, will be included: Ø

  17. NMMSS Newsletter, August 2009 Special Edition

    National Nuclear Security Administration (NNSA)

    NMMSS Training Course for NRC Licensees NMMSS training for NRC Licensees is being planned for September 15, 16, and 17, 2009, at the DOE Headquarters, in Germantown, MD. The course is designed for individuals with limited experience in NRC reporting requirements and is based on NUREG/BR-006, Rev. 7 and NUREG/BR-007, Rev. 6. The following topics, among others, will be included: Completion of data forms: transactions, inventory and material balance. Inventory reconciliation Foreign Obligations

  18. Automated Image Analysis of Fibers - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Startup America Startup America Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Automated Image Analysis of Fibers Automatic Nanofiber Characterization and Recognition Software Argonne National Laboratory Contact ANL About This Technology Image with recognized fiber edges<br /> <br /> Diameter - Measure between each yellow and red tail. Image with recognized fiber edges Diameter - Measure between each yellow

  19. Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Phenolic Foam for Building Insulation | Department of Energy Inside the lab of Fraunhofer Center for Sustainable Energy Systems (CSE) in Boston, MA<br /> Photo Courtesy of Fraunhofer CSE, Photo Credit: Trent Bell Inside the lab of Fraunhofer Center for Sustainable Energy Systems (CSE) in Boston, MA Photo Courtesy of Fraunhofer CSE, Photo Credit: Trent Bell Inside the lab of Fraunhofer Center for Sustainable Energy Systems (CSE) in Boston, MA<br /> Photo Courtesy of Fraunhofer

  20. Evaluation of Alkali Bromide Salts for Potential Pyrochemical Applications

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Steven D. Herrmann; Guy L. Fredrickson; Tedd E. Lister; Toni Y. Gutknecht

    2013-10-01

    Transient techniques were employed to study the electrochemical behavior, reduction mechanism and transport properties of REBr3 (RE - La, Nd and Gd) in pure LiBr, LiBr-KBr (eutectic) and LiBr-KBr-CsBr (eutectic) melts. Gd(III) showed a reversible single step soluble-insoluble exchange phenomenon in LiBr melt at 973K. Although La (III), Nd(III) and Gd(III) ions showed reversible behavior in eutectic LiBr-KBr melts, these ions showed a combination of temperature dependent reversible and pseudo-reversible behavior. While both La(III) and Gd(III) showed one step reduction, the reduction of Nd(III) was observed to be a two step process. La metal could be electrodeposited from the ternary electrolyte at a temperature of 673K. Various electrochemical measurements suggest that both binary and ternary bromide melts can potentially be used to electrodeposit high purity RE metals at comparatively lower operating temperatures.

  1. Humectant use in the cathodic protection of reinforced concrete

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Russell, James H.; Bullard, Sophie J.; Cramer, Stephen D.; Collins, W.K.; Bennett, J.E.; Laylor, H.M.

    2000-11-01

    Use of humectants to improve the thermal-sprayed zinc anode performance during the cathodic protection (CP) of reinforced concrete was examined. A humectant is a hygroscopic material. It is applied onto the surface of the zinc anode to keep the concrete-anode interface moist and a good conductor. The thermodynamics of humectants are discussed. Laboratory results are presented on the effects of using lithium bromide (LiBr) and lithium nitrate (LiNO{sub 3}) as humectants in galvanic cathodic protection (GCP) and impressed current cathodic protection (ICCP) systems, in high and low relative humidities, and on new and previously electrochemically aged CP systems. LiNO{sub 3} and LiBr promoted more effective CP performance. Both improved the performance of aged slabs, suggesting that application of humectants onto existing CP systems would be of benefit. Microscopy showed that humectant-treated slabs develop the same cement-reaction zone, zinc anode structures as untreated slabs. Microscopy of LiBr-treated slabs revealed that the highest concentration of bromide was in the reaction zone. In GCP tests, LiBr was more effective than LiNO{sub 3}. In accelerated ICCP tests, LiNO{sub 3} was more effective than LiBr. It was surmised that bromide could be oxidized in the high-voltage accelerated ICCP tests. At the lower impressed currents of most installed ICCP systems, LiBr may perform as well as or better than LiNO{sub 3}.

  2. Humectant use in the cathodic protection of reinforced concrete

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, B.S. Jr.; Russell, J.H.; Bullard, S.J.; Cramer, S.D.; Collins, W.K.; Bennett, J.E.; H.M. Laylor

    2000-03-01

    The use of humectants to improve the thermal-sprayed zinc anode performance during the cathodic protection (CP) of reinforced concrete is examined. A humectant is a hygroscopic material. It is applied onto the surface of the zinc anode to keep the concrete-anode interface moist and a good conductor. The thermodynamics of humectants are discussed. Laboratory results are presented on the effects of using LiBr and LiNO{sub 3} as humectants in galvanic (GCP) and impressed current (ICCP) systems, in high and low relative humidities, and on new and previously electrochemically aged CP systems. LiNO{sub 3} and LiBr promoted more effective CP performance. Both improved the performance of aged slabs, suggesting that application of humectants onto existing CP systems would be of benefit. Microscopy showed that humectant-treated slabs develop the same cement-reaction zone-zinc anode structures as untreated slabs. Microscopy of LiBr-treated slabs revealed that the highest concentration of bromide was in the reaction zone. In GCP tests, LiBr was more effective than LiNO{sub 3}. In accelerated ICCP tests, LiNO{sub 3} was more effective than LiBr. It was surmised that bromide could be oxidized in the high-voltage accelerated ICCP tests. At the lower impressed currents of most installed ICCP systems, LiBr may perform as well as or better than LiNO{sub 3}.

  3. Inducible bilirubin oxidase: A novel function for the mouse cytochrome P450 2A5

    SciTech Connect (OSTI)

    Abu-Bakar, A'edah; Arthur, Dionne Maioha; Cooperative Research Centre for Contamination Assessment and Remediation of the Environment, Adelaide ; Aganovic, Simona; Ng, Jack C.; Cooperative Research Centre for Contamination Assessment and Remediation of the Environment, Adelaide ; Lang, Matti A.; Department of Pharmaceutical Biosciences, Uppsala University, Biomedical Centre, Box 578, S-751 23 Uppsala

    2011-11-15

    We have previously shown that bilirubin (BR), a breakdown product of haem, is a strong inhibitor and a high affinity substrate of the mouse cytochrome P450 2A5 (CYP2A5). The antioxidant BR, which is cytotoxic at high concentrations, is potentially useful in cellular protection against oxygen radicals if its intracellular levels can be strictly controlled. The mechanisms that regulate cellular BR levels are still obscure. In this paper we provide preliminary evidence for a novel function of CYP2A5 as hepatic 'BR oxidase'. A high-performance liquid chromatography/electrospray ionisation mass spectrometry screening showed that recombinant yeast microsomes expressing the CYP2A5 oxidise BR to biliverdin, as the main metabolite, and to three other smaller products with m/z values of 301, 315 and 333. The metabolic profile is significantly different from that of chemical oxidation of BR. In chemical oxidation the smaller products were the main metabolites. This suggests that the enzymatic reaction is selective, towards biliverdin production. Bilirubin treatment of primary hepatocytes increased the CYP2A5 protein and activity levels with no effect on the corresponding mRNA. Co-treatment with cycloheximide (CHX), a protein synthesis inhibitor, resulted in increased half-life of the CYP2A5 compared to cells treated only with CHX. Collectively, the observations suggest that the CYP2A5 is potentially an inducible 'BR oxidase' where BR may accelerate its own metabolism through stabilization of the CYP2A5 protein. It is possible that this metabolic pathway is potentially part of the machinery controlling intracellular BR levels in transient oxidative stress situations, in which high amounts of BR are produced. -- Highlights: Black-Right-Pointing-Pointer CYP2A5 metabolizes bilirubin to biliverdin and dipyrroles. Black-Right-Pointing-Pointer Bilirubin increased the hepatic CYP2A5 protein and activity levels. Black-Right-Pointing-Pointer Bilirubin does not change the hepatic CYP2A5 mRNA levels. Black-Right-Pointing-Pointer Co-treatment with a protein synthesis inhibitor prolongs CYP2A5 half-life. Black-Right-Pointing-Pointer CYP2A5 is potentially an inducible bilirubin oxidase.

  4. A search for charmless dihadron decays of neutral b-hadrons

    SciTech Connect (OSTI)

    Misawa, Shigeki

    1997-03-01

    A search for charmless dihadron decays of neutral b-hadrons was performed using data obtained from 800 GeV/c proton-gold interactions. The following upper limits on the b-hadron branching ratios (including charge conjugates) were obtained at the 90% confidence limit: Br(B{sub s} {yields} K{sup +}K{sup {minus}}) + r{sub s} x Br(B{sub d} {yields} {pi}{sup +}{pi}{sup {minus}}) < 2.0 x 10{sup {minus}3}; Br(B{sub d} {yields} K{sup +}K{sup {minus}}) < 9.5 x 10{sup {minus}4}; Br(B{sub s} {yields}{pi}{sup +}{pi}{sup {minus}}) < 2.0 x 10{sup {minus}3}; Br(B{sub d} {yields} K{sup +}{pi}{sup {minus}}) < 1.9 x 10{sup {minus}3}; Br(B{sub s} {yields} K{sup {minus}}{pi}{sup +}) < 2.2 x 10{sup {minus}3}; Br(B{sub d} {yields} p{bar p}) < 1.6 x 10{sup {minus}3}; Br(B{sub s} {yields} p{bar p}) < 9.0 x 10{sup {minus}3}; Br({Lambda}{sub d} {yields} K{sup +}p{sup {minus}}) < 6.1 x 10{sup {minus}3}; Br({Lambda}{sub b} {yields} {pi}{sup +}p{sup {minus}}) < 9.7 x 10{sup {minus}3}; where r{sub s} was determined to be 2.9 {+-} 0.8. These limits assume that B{sub d}/B{sub s}/{Lambda}{sub b} hadrons are produced in proton on nucleon interactions in the ratio (38 {+-} 5.7) : (13 {+-} 3.2) : (9.6 {+-} 1.7) and that the branching ratio for the cascade decay b-hadron {yields} J/{psi} + X {yields} {mu}{sup +}{mu}{sup {minus}} + X is (6.97 {+-} .64) x 10{sup {minus}4}.

  5. Variable accretion processes in the young binary-star system UY Aur

    SciTech Connect (OSTI)

    Stone, Jordan M.; Eisner, J. A.; Kulesa, Craig; McCarthy, Don; Salyk, Colette E-mail: jeisner@as.arizona.edu E-mail: dmccarthy@as.arizona.edu

    2014-09-01

    We present new K-band spectroscopy of the UY Aur binary star system. Our data are the first to show H{sub 2} emission in the spectrum of UY Aur A and the first to spectrally resolve the Br? line in the spectrum of UY Aur B. We see an increase in the strength of the Br? line in UY Aur A and a decrease in Br? and H{sub 2} line luminosity for UY Aur B compared to previous studies. Converting Br? line luminosity to accretion rate, we infer that the accretion rate onto UY Aur A has increased by 2 10{sup 9} M {sub ?} yr{sup 1} per year since a rate of zero was observed in 1994. The Br? line strength for UY Aur B has decreased by a factor of 0.54 since 1994, but the K-band flux has increased by 0.9 mag since 1998. The veiling of UY Aur B has also increased significantly. These data evince a much more luminous disk around UY Aur B. If the lower Br? luminosity observed in the spectrum of UY Aur B indicates an intrinsically smaller accretion rate onto the star, then UY Aur A now accretes at a higher rate than UY Aur B. However, extinction at small radii or mass pile-up in the circumstellar disk could explain decreased Br? emission around UY Aur B even when the disk luminosity implies an increased accretion rate. In addition to our scientific results for the UY Aur system, we discuss a dedicated pipeline we have developed for the reduction of echelle-mode data from the ARIES spectrograph.

  6. Water adsorption, solvation and deliquescence of alkali halide thin films on SiO2 studied by ambient pressure X-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Arima, Kenta; Jiang, Peng; Deng, Xingyi; Bluhm, Henrik; Salmeron, Miquel

    2010-03-31

    The adsorption of water on KBr thin films evaporated onto SiO2 was investigated as a function of relative humidity (RH) by ambient pressure X-ray photoelectron spectroscopy. At 30percent RH adsorbed water reaches a coverage of approximately one monolayer. As the humidity continues to increase, the coverage of water remains constant or increases very slowly until 60percent RH, followed by a rapid increase up to 100percent RH. At low RH a significant number of the Br atoms are lost due to irradiation damage. With increasing humidity solvation increases ion mobility and gives rise to a partial recovery of the Br/K ratio. Above 60percent RH the increase of the Br/K ratio accelerates. Above the deliquescence point (85percent RH), the thickness of the water layer continues to increase and reaches more than three layers near saturation. The enhancement of the Br/K ratio at this stage is roughly a factor 2.3 on a 0.5 nm KBr film, indicating a strong preferential segregation of Br ions to the surface of the thin saline solution on SiO2.

  7. A=17O (71AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    71AJ02) (See Energy Level Diagrams for 17O) GENERAL: See also (59AJ76) and Table 17.5 [Table of Energy Levels] (in PDF or PS). Shell model: (WI57H, BR59M, FE59E, KH59, SA59C, AK60, TA60L, BA61N, NE61C, BH62, TA62, TA62F, CO63B, HA63A, KU63I, PA63C, BR64Z, RI64B, GI65D, LE65G, MA65J, ZA65B, AR66H, BO66J, BR66C, BR66S, BR66CC, DE66M, LA66L, MA66BB, QU66, RI66G, SO66A, ZA66A, BO67B, EL67C, EN67, FE67A, GO67B, LY67, NI67, PA67K, PF67, BI68A, DE68K, EL68, EL68E, HE68J, HO68, KA68, MA68DD, NI68,

  8. The Correlation of Coupled Heat and Mass Transfer Experimental Data for Vertical Falling Film Absorption

    SciTech Connect (OSTI)

    Keyhani, M.; Miller, W.A.

    1999-11-14

    Absorption chillers are gaining global acceptance as quality comfort cooling systems. These machines are the central chilling plants and the supply for cotnfort cooling for many large commercial buildings. Virtually all absorption chillers use lithium bromide (LiBr) and water as the absorption fluids. Water is the refrigerant. Research has shown LiBr to he one of the best absorption working fluids because it has a high affinity for water, releases water vapor at relatively low temperatures, and has a boiling point much higher than that of water. The heart of the chiller is the absorber, where a process of simultaneous heat and mass transfer occurs as the refrigerant water vapor is absorbed into a falling film of aqueous LiBr. The more water vapor absorbed into the falling film, the larger the chiller?s capacity for supporting comfort cooling. Improving the performance of the absorber leads directly to efficiency gains for the chiller. The design of an absorber is very empirical and requires experimental data. Yet design data and correlations are sparse in the open literature. The experimental data available to date have been derived at LiBr concentrations ranging from 0.30 to 0.60 mass fraction. No literature data are readily available for the design operating conditions of 0.62 and 0.64 mass fraction of LiBr and absorber pressures of 0.7 and 1.0 kPa.

  9. SAPHIRE 8 Software Independent Verification and Validation Plan

    SciTech Connect (OSTI)

    Rae J. Nims; Kent M. Norris

    2010-02-01

    SAPHIRE 8 is being developed with a phased or cyclic iterative rapid application development methodology. Due to this approach, a similar approach is being taken for the IV&V activities on each vital software object. The IV&V plan is structured around NUREG/BR-0167, “Software Quality Assurance Program and Guidelines,” February 1993. The Nuclear Regulatory Research Office Instruction No.: PRM-12, “Software Quality Assurance for RES Sponsored Codes,” March 26, 2007 specifies that RES-sponsored software is to be evaluated against NUREG/BR-0167. Per the guidance in NUREG/BR-0167, SAPHIRE is classified as “Level 1.” Level 1 software corresponds to technical application software used in a safety decision.

  10. Poly(phenylene)-based anion exchange membrane

    DOE Patents [OSTI]

    Hibbs, Michael; Cornelius, Christopher J.; Fujimoto, Cy H.

    2011-02-15

    A poly(phenylene) compound of copolymers that can be prepared with either random or multiblock structures where a first polymer has a repeat unit with a structure of four sequentially connected phenyl rings with a total of 2 pendant phenyl groups and 4 pendant tolyl groups and the second polymer has a repeat unit with a structure of four sequentially connected phenyl rings with a total of 6 pendant phenyl groups. The second polymer has chemical groups attached to some of the pendant phenyl groups selected from CH.sub.3, CH.sub.2Br, and CH.sub.2N(CH.sub.3).sub.3Br groups. When at least one group is CH.sub.2N(CH.sub.3).sub.3Br, the material functions as an anion exchange membrane.

  11. Enhanced T-lymphocyte blastogenic response to tuberculin (PPD) in children of northeast (NE) Thailand supplemented with vitamin A (VA) and zinc (Zn)

    SciTech Connect (OSTI)

    Kramer, T.R.; Udomkesmalee, E.; Dhanamitta, S.; Sirisinha, S.; Charoenkiatkul, S.; Tantipopipat, S.; Banjong, O.; Rojroongwasinkul, N.; Smith, J.C. Jr. Mahidol Univ., Nakhon Pathom )

    1991-03-15

    Beneficial effects of Va and/or Zn supplementation of children in NE Thailand are described in a companion abstract. In the same study, blastogenic response (BR) of T-lymphocytes to concanavalin-A (ConA) and PPD were assayed in cultures containing mononuclear cells (MNC) or whole blood (WB). Methods were previously described. Children were previously vaccinated with BCG. BR to ConA of MNC or WB from children supplemented with VA, Zn, VA + Zn or placebo were similar. BR to PPD of MNC was higher in children receiving VA + Zn than placebo, but not in children supplemented with VA or Zn alone. Data indicate that children with suboptimal VA and Zn nutriture supplemented with < 2 times RDA of these nutrients showed enhanced cellular immunity to PPD. This observation is relevant to BCG immunization program and thus may benefit public health.

  12. Method for production of hydrocarbons from hydrates

    DOE Patents [OSTI]

    McGuire, Patrick L.

    1984-01-01

    A method of recovering natural gas entrapped in frozen subsurface gas hydrate formations in arctic regions. A hot supersaturated solution of CaCl.sub.2 or CaBr.sub.2, or a mixture thereof, is pumped under pressure down a wellbore and into a subsurface hydrate formation so as to hydrostatically fracture the formation. The CaCl.sub.2 /CaBr.sub.2 solution dissolves the solid hydrates and thereby releases the gas entrapped therein. Additionally, the solution contains a polymeric viscosifier, which operates to maintain in suspension finely divided crystalline CaCl.sub.2 /CaBr.sub.2 that precipitates from the supersaturated solution as it is cooled during injection into the formation.

  13. Fetal weight at term influenced by H-2-associated loci

    SciTech Connect (OSTI)

    Tyan, M.L.

    1994-01-01

    Pregnant mice which in theory differ only in the region of the major histocompatibility complex (MHC) on chromosome 17 (C57BL/10, the inbred partner [host strain], and B10.D2, B10.BR, BI0.A, B10.A[2R], Bl0.A[5R], B10.A[15R] and B10.A[18R]) were sacrificed on the 11th and 18th days of gestation, and the fetuses were sexed and weighed. Fetuses from reciprocal crosses between B10.A and B10BR, B10.D2 and C57BL/10 were weighed and sexed on the 18th day of gestation. It was found that (i) fetal weights were not significantly different among the strains examined on day 11 (Bl0.BR, B10.A[15R] and B10.A[18R]), (ii) B10.BR fetuses of both sexes weighed significantly less than fetuses from the other strains on day 18, (iii) B10.D2 18-day-old male but not female fetuses were heavier than the males from the other strains (this difference was not present when corrections for litter size were made), (iv) the fetuses from the B10.A x B10.BR cross were the smallest, those from the B10.D2 x 810.A cross the largest, and those from the B10.A x C57BL/10 crosses intermediate, and (v) maternal effects were noted In the B10.A x B10.BR and B10.A x B10.D2 but not the B10.A x C57BL/10 crosses. The results suggest that there are two or more MHC associated loci that influence growth rate in late gestation. Among the candidate genes are Ped and Igfr II. 17 refs., 4 tabs.

  14. Triazolium based ionic liquid crystals: Effect of asymmetric substitution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stappert, K.; Mudring, A. -V.

    2015-01-27

    A new series of ten different asymmetrical 1-dodecyl-3-alkyl-triazolium bromides, [C12CnTr][Br], has been synthesized and their mesomorphic behavior studied by DSC (differential scanning calorimetry), POM (polarizing optical microscopy) and SAXS (small angle X-ray scattering). The influence of the chain length of the triazolium salts is investigated to explore the effect of asymmetric substitution on the phase behaviour of these compounds. For that reason, the length of one alkyl chain was varied from 14 to 1 carbon atoms (n = 14, 12, 10, 8–4, 2, 1) while the other alkyl chain was kept at 12 carbon. Single crystal X-ray structure analysis ofmore » compounds [C12C12Tr][Br] and [C12C5Tr][Br] reveal that the cations adopt a U-shaped conformation with head-to-head arranged triazolium cores. In contrast, for [C12C1Tr][Br], a rod like shape of the cation with interdigitated alkyl chains is found. All investigated compounds are thermotropic liquid crystals. Higher ordered smectic phases, smectic C as well as smectic A phases were found depending on the chain length of the cation. Moreover, the clearing point temperature decreases with decreasing chain length with exception for the n-dodecyl-3-alkyltrizoliumbromides with the two shortest alkyl chains, [C12C2Tr][Br] and [C12C1Tr][Br], which present higher clearing temperatures (86 and 156 °C) and are structurally distinctly different.« less

  15. U

    National Nuclear Security Administration (NNSA)

    8 SPONSORED BY DOE AND NRC PREPARED BY NAC INTERNATIONAL SPECIAL EDITION NUREG/BR-0006, REVISION 7 "INSTRUCTIONS FOR COMPLETING NUCLEAR MATERIAL TRANSACTION REPORTS" On July 15, 2008 the NRC posted NUREG/BR-0006, Revision 7 on its public web site. The effective date of this document is January 1, 2009. The link for this document is http://www.nrc.gov/reading-rm/doc-collections/nuregs/brochures A draft of this document was published in mid-2007 for comments and discussed during the 2007

  16. B physics: first evidence for b_s0 --> phi phi decay and measurements of branching ratio and a_cp for b+ --> phi k+

    SciTech Connect (OSTI)

    Acosta, D.; The CDF Collaboration

    2005-05-31

    We present the first evidence of charmless decays of the B{sub s}{sup 0} meson, the decay B{sub s}{sup 0} {yields} {phi}{phi}, and a measurement of the Branching Ratio BR(B{sub s}{sup 0} {yields} {phi}{phi}) using 180 pb{sup -1} of data collected by the CDF II experiment at the Fermilab Tevatron collider. In addition, the BR and direct CP asymmetry for the B{sup +} {yields} {phi}K{sup +} decay are measured.

  17. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    U.S. Energy Information Administration (EIA) Indexed Site

    GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY GLENVILLE N MINNORA JARVISVILLE FAR MINGTON PH ILIPPI BELIN GT ON WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK WESTON-JAN E LEW SWN DL-WID EN VADIS STANL EY DEKALB UNION TALLM AN SVILL E ASPINALL-FIN ST ER ZOLLARSVILLE WILBU R RAMSEY HEATER S BR IDGEPORT-PRUNT YTOWN ALEXAND ER LILLY FORK SH ERMAN HIRAM ST FK-BLST N CK BU RNS CH APEL S BR WN -LUM BER PORT CON INGS PR ATT BOSWELL REVEL ELK C REEK

  18. High-resolution H-band spectroscopy of Be stars with SDSS-III/apogee. I. New Be stars, line identifications, and line profiles

    SciTech Connect (OSTI)

    Chojnowski, S. Drew; Majewski, Steven R.; Hall, Matthew; Beaton, Rachael; Burton, Adam; Damke, Guillermo; Wilson, John; Whelan, David G.; Wisniewski, John P.; Shetrone, Matthew; Eikenberry, Steve; Hasselquist, Sten; Holtzman, Jon A.; Brewington, Howard; Brinkmann, J.; Mszros, Szabolcs; Nidever, David; Schneider, Donald P.; Zasowski, Gail; Bizyaev, Dmitry; and others

    2015-01-01

    The Apache Point Observatory Galactic Evolution Experiment (APOGEE) has amassed the largest ever collection of multi-epoch, high-resolution (R?22,500), H-band spectra for B-type emission line (Be) stars. These stars were targeted by APOGEE as telluric standard stars and subsequently identified via visual inspection as Be stars based on H i Brackett series emission or shell absorption in addition to otherwise smooth continua and occasionally non-hydrogen emission features. The 128/238 APOGEE Be stars for which emission had never previously been reported serve to increase the total number of known Be stars by ?6%. Because the H band is relatively unexplored compared to other wavelength regimes, we focus here on identification of the H-band lines and analysis of the emission peak velocity separations (?v{sub p}) and emission peak intensity ratios (V/R) of the usually double-peaked H i and non-hydrogen emission lines. H i Br11 emission is found to preferentially form in the circumstellar disks at an average distance of ?2.2 stellar radii. Increasing ?v{sub p} toward the weaker Br12Br20 lines suggests these lines are formed interior to Br11. By contrast, the observed IR Fe ii emission lines present evidence of having significantly larger formation radii; distinctive phase lags between IR Fe ii and H i Brackett emission lines further supports that these species arise from different radii in Be disks. Several emission lines have been identified for the first time including C i 16895, a prominent feature in the spectra for almost a fifth of the sample and, as inferred from relatively large ?v{sub p} compared to the Br11Br20, a tracer of the inner regions of Be disks. Emission lines at 15760 ? and 16781 ? remain unidentified, but usually appear along with and always have similar line profile morphology to Fe ii 16878. Unlike the typical metallic lines observed for Be stars in the optical, the H-band metallic lines, such as Fe ii 16878, never exhibit any evidence of shell absorption, even when the H i lines are clearly shell-dominated. The first known example of a quasi-triple-peaked Br11 line profile is reported for HD 253659, one of several stars exhibiting intra- and/or extra-species V/R and radial velocity variation within individual spectra. Br11 profiles are presented for all discussed stars, as are full APOGEE spectra for a portion of the sample.

  19. High-Efficiency, Low-Emission Refrigeration System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency, Low-Emission Refrigeration System High-Efficiency, Low-Emission Refrigeration System Image of the compressor rack and system diagram for the CO2 refrigeration system.<br /> Credit: Oak Ridge National Lab Image of the compressor rack and system diagram for the CO2 refrigeration system. Credit: Oak Ridge National Lab Diagram of the compressor rack and system diagram for the CO2 refrigeration system.<br /> Credit: Oak Ridge National Lab Diagram of the compressor rack and

  20. 5Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li Ground-State Decay Evaluated Data Measured Ground-State Γcm for 5Li Adopted value: 1.23 MeV (2002TI10) Measured Mass Excess for 5Li Adopted value: 11680 ± 50 keV (2003AU02) Measurements 1960BA45: 5Li; measured not abstracted; deduced nuclear properties. 1960BR10: 5Li; measured not abstracted; deduced nuclear properties. 1960BR19: 5Li; measured not abstracted; deduced nuclear properties. 1960HA14: 5Li; measured not abstracted; deduced nuclear properties. 1960PE14: 5Li; measured not

  1. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exterior <h3>NIF in Springtime</h3>NIF & Photon Science photographer Jason Laurea captured the colors of spring with this shot of the main entrance to the NIF facility. Ground was broken for the facility on May 29, 1997, and NIF was dedicated 12 years to the day later. NIF is 10 stories high and as wide as three football fields arranged side-by-side. It operates 24 hours a day, seven days a week.<br/><br/><a

  2. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Switchyard <h3>Switchyard Support Structures</h3>The switchyards convert the parallel laser beam layout to the spherical configuration of the target chamber, as the beams need to enter the chamber along radial lines to converge on the target. The switchyard support structures are built to resist vibration. They are firmly anchored to the building's reinforced concrete walls, which are 0.6 meters (two feet) thick.<br/><br/><a

  3. Photo Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Targets <h3>Assuring Target Quality</h3>Cryogenic Systems Operator Eric Mertens takes a pre-installation quality-assurance photo of the keyhole target for a cryogenic equation-of-state (CryoEOS) experiment for the NIF Discovery Science program. The CryoEOS shot measured the optical properties of deuterium along a reverberation compression path to three megabars (three million Earth atmospheres). Credit: James Pryatel<br/><br/><a

  4. IN SITU SURFACE X-RAY SCATTERING STUDIES OF ELECTROSORPTION

    SciTech Connect (OSTI)

    WANG,J.X.; ADZIC,R.R.; OCKO,B.M.

    1998-07-01

    A short review of the application of surface x-ray scattering techniques to the electrode/electrolyte interfaces is presented. Recent results on metal, halide, and metal-halide adlayers with three specific systems: Bi on Au(100) and Au(110); Br on Au(100) and Ag(100); and the coadsorption of Tl with Br or I on Au(111), are given as an illustration. Factors affecting ordering of pure metal and halide adlayers and the metal-halide surface compounds are discussed in some detail.

  5. Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization

    SciTech Connect (OSTI)

    Karpenko, A. Iablonskyi, D.; Kettunen, J. A.; Cao, W.; Huttula, M.; Aksela, H.; Urpelainen, S.

    2014-05-28

    The inner-valence region of alkali bromide XBr (X=Li, Na, K, Rb) vapours has been studied experimentally by means of synchrotron radiation excited photoelectron spectroscopy. Experimental spectra were analyzed by comparing them with available theoretical results and previous experiments. Ionic character of alkali bromides is seen to change in the inner-valence region with increasing atomic number of the alkali atom. A mechanism involving mixing between Br 4s and Rb 4p orbitals has been suggested to account for the fine structure observed in inner-valence ionization region of RbBr.

  6. Chemically modified thermal-spray zinc anodes for galvanic cathodic protection

    SciTech Connect (OSTI)

    Covino, B.S. Jr.; Bullard, S.J.; Holcomb, G.R.; Russell, J.H.; Cramer, S.D.; Bennett, J.E.; Laylor, H.M.

    1999-12-01

    Humectants, substances that promote the retention of moisture, were applied to new and previously aged thermal-sprayed Zn anodes to improve the performance of galvanic cathodic protection systems. Anodes on steel-reinforced concrete were treated with aqueous solutions of the humectants lithium nitrate (LiNO{sub 3}) and lithium bromide (LiBr). LiBr was the most beneficial humectant, increasing the average galvanic current density of new thermal-sprayed Zn anodes by as much as a factor of six.

  7. GLOBAL CLIMATE CHANGE: SOME IMPLICATIONS, OPPORTUNITIES. AND CHALLENGES FOR U.S. FORESTRY

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY GLENVILLE N MINNORA JARVISVILLE FAR MINGTON PH ILIPPI BELIN GT ON WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK WESTON-JAN E LEW SWN DL-WID EN VADIS STANL EY DEKALB UNION TALLM AN SVILL E ASPINALL-FIN ST ER ZOLLARSVILLE WILBU R RAMSEY HEATER S BR IDGEPORT-PRUNT YTOWN ALEXAND ER LILLY FORK SH ERMAN HIRAM ST FK-BLST N CK BU RNS CH APEL S BR WN -LUM BER PORT CON INGS PR ATT BOSWELL REVEL ELK C REEK

  8. NMMSS News, March 2006

    National Nuclear Security Administration (NNSA)

    6 SPONSORED BY DOE AND NRC PREPARED BY NAC INTERNATIONAL Modification of NRC's Two NMMSS Reporting NUREGs In the August/September 2005 NMMSS News, the NRC placed an article noting that it had directed NMMSS to start accepting transaction reports from Licensees reporting Rounding Adjustments. Since that time, the NRC has modified NUREG/BR-0006 and NUREG/BR-0007 through the issuance of an "errata" sheet for each NUREG to document the approval for reporting rounding adjustments. The

  9. Experimental Results in the Comparison of Search Algorithms Used with Room Temperature Detectors

    SciTech Connect (OSTI)

    Guss, P., Yuan, D., Cutler, M., Beller, D.

    2010-11-01

    Analysis of time sequence data was run for several higher resolution scintillation detectors using a variety of search algorithms, and results were obtained in predicting the relative performance for these detectors, which included a slightly superior performance by CeBr{sub 3}. Analysis of several search algorithms shows that inclusion of the RSPRT methodology can improve sensitivity.

  10. A=5Li (1988AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    above threshold i.e., Ex 18.9 0.2 MeV: see (1979AJ01). Recent studies of the breakup have been reported at Ed 23.08 MeV (1986BR1J; reaction (c)) and 60 MeV (1985OK03;...

  11. A=5Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    n)4He is very close. See also (KU55B, BO57G, BR57E). Above Ed 3.71 MeV, deuteron breakup (reaction (b)) is observed (HE55D). 4. 3He(d, d)3He Eb 16.555 Differential cross...

  12. Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations

    DOE Patents [OSTI]

    Marks, Tobin J.; Chen, You-Xian

    2002-01-01

    Organo-Lewis acids of the formula BR'R".sub.2 wherein B is boron, R' is fluorinated biphenyl, and R" is a fluorinated phenyl, fluorinated biphenyl, or fluorinated polycyclic fused ring group, and cationic metallocene complexes formed therewith. Such complexes are useful as polymerization catalysts.

  13. Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations

    DOE Patents [OSTI]

    Marks, Tobin J.; Chen, You-Xian

    2001-01-01

    Organo-Lewis acids of the formula BR'R".sub.2 wherein B is boron, R' is fluorinated biphenyl, and R" is a fluorinated phenyl, fluorinated biphenyl, or fluorinated polycyclic fused ring group, and cationic metallocene complexes formed therewith. Such complexes are useful as polymerization catalysts.

  14. Lawrence Co. Scioto Co. Greenup Co. Jack

    U.S. Energy Information Administration (EIA) Indexed Site

    NE BREEDEN MAR E CREEK SCHOOL FAR LEY C HUR CH W LON G R UN LICKBURG RPD-GALLIA-1 MIMA LEF ... HINDMAN E STAF FORD SPEIGHT E ST EPHENS JUM PIN G BR AN CH GRASSY CREEK RICH POND WH ITMER ...

  15. Alkyl-bis(imidazolium) salts: a new amphiphile platform that forms thermotropic and non-aqueous lyotropic bicontinuous cubic phases

    SciTech Connect (OSTI)

    Robertson, LA; Schenkel, MR; Wiesenauer, BR; Gin, DL

    2013-01-01

    New ionic amphiphiles with a hexyl-bridged bis(imidazolium) headgroup; Br-, BF4-, or Tf2N- anions; and a long n-alkyl tail can form thermotropic bicontinuous cubic liquid crystal phases in neat form and/or lyotropic bicontinuous cubic phases with several non-aqueous solvents or water.

  16. A = 16O (1986AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for 16O) GENERAL: See also (1982AJ01) and Table 16.10. Table of Energy Levels (in PDF or PS) here. Shell model: (1978WI1B, 1981AN18, 1981BR16, 1981CO1X, 1981DE2G, 1981FO12,...

  17. A=16O (1982AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for 16O) GENERAL: See also (1977AJ02) and Table 16.11 Table of Energy Levels (in PDF or PS). Shell model: (1976AP01, 1976BE1W, 1976NA1L, 1977AP01, 1977BR26, 1977CA02,...

  18. A=14N (70AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (See Energy Level Diagrams for 14N) GENERAL: See Table 14.7 Table of Energy Levels (in PDF or PS). Model calculations:(HU57D, BA59F, BR59M, OT59, SK59, PA60, TA60L, WA60, BA61D,...

  19. A=16O (71AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diagrams for 16O) GENERAL: See also (59AJ76) and Table 16.9 Table of Energy Levels (in PDF or PS). Shell model: (WI57H, BR59M, FE59C, PA59A, TA60H, TA60L, BA61N, TR61, BA62F,...

  20. CX-100577 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Reduction of System Cost Characteristics Through Innovative Solutions to Installation, Operations, and Maintenance Award Number: DE-EE0007347 CX(s) Applied: A9 Water Power Program br> Date: 03/18/2016 Location(s): WA Office(s): Golden Field Office

  1. CX-100580 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Next Generation MHK River Power System Optimized for Performance, Durability and Survivability Award Number: DE-EE0007348 CX(s) Applied: A9 Water Power Program br> Date: 03/14/2016 Location(s): AK Office(s): Golden Field Office

  2. NOAA PMEL Station Chemistry Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Quinn, Patricia

    2008-04-04

    Submicron and supermicron samples are analyzed by ion chromatography for Cl-, NO3-, SO4-2, Na+, NH4+, K+, Mg2+, and Ca+2. The analysis of MSA-, Br-, and oxalate has been added to some stations. Samples also are analyzed for total mass by gravimetric analysis at 55 +/- 5% RH.

  3. Hydrogen Financial Analysis Scenario Tool (H2FAST); NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Melaina, Marc

    2015-04-21

    This presentation describes the Hydrogen Financial Analysis Scenario Tool, H2FAST, and provides an overview of each of the three H2FAST formats: the H2FAST web tool, the H2FAST Excel spreadsheet, and the H2FAST Business Case Scenario (BCS) tool. Examples are presented to illustrate the types of questions that H2FAST can help answer. <br/>

  4. Overview of the Hydrogen Financial Analysis Scenario Tool (H2FAST); NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Melaina, Marc; Bush, Brian; Penev, Michael

    2015-05-12

    This presentation provides an introduction to the Hydrogen Financial Analysis Scenario Tool (H2FAST) and includes an overview of each of the three versions of H2FAST: the Web tool, the Excel spreadsheet version, and the beta version of the H2FAST Business Case Scenario tool.<br/>

  5. Retention of Halogens in Waste Glass

    SciTech Connect (OSTI)

    Hrma, Pavel R.

    2010-05-01

    In spite of their potential roles as melting rate accelerators and foam breakers, halogens are generally viewed as troublesome components for glass processing. Of five halogens, F, Cl, Br, I, and At, all but At may occur in nuclear waste. A nuclear waste feed may contain up to 10 g of F, 4 g of Cl, and ?100 mg of Br and I per kg of glass. The main concern is halogen volatility, producing hazardous fumes and particulates, and the radioactive iodine 129 isotope of 1.7x10^7-year half life. Because F and Cl are soluble in oxide glasses and tend to precipitate on cooling, they can be retained in the waste glass in the form of dissolved constituents or as dispersed crystalline inclusions. This report compiles known halogen-retention data in both high-level waste (HLW) and low-activity waste (LAW) glasses. Because of its radioactivity, the main focus is on I. Available data on F and Cl were compiled for comparison. Though Br is present in nuclear wastes, it is usually ignored; no data on Br retention were found.

  6. Soil Analysis using the semi-parametric NAA technique

    SciTech Connect (OSTI)

    Zamboni, C. B.; Silveira, M. A. G.; Medina, N. H.

    2007-10-26

    The semi-parametric Neutron Activation Analysis technique, using Au as a flux monitor, was applied to measure element concentrations of Br, Ca, Cl, K, Mn and Na for soil characterization. The results were compared with those using the Instrumental Neutron Activation Analysis technique and they found to be compatible. The viability, advantages, and limitations of using these two analytic methodologies are discussed.

  7. A=19O (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7AJ02) (See Energy Level Diagrams for 19O) GENERAL: See (1983AJ01) and Table 19.1 Table of Energy Levels (in PDF or PS). Nuclear models: (1978WI1B, 1983BR29, 1983PO02, 1983SH44,...

  8. A=6Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    66LA04) (See Energy Level Diagrams for 6Li) GENERAL: See Table 6.4 Table of Energy Levels (in PDF or PS). See also (AU55, LA55, ME56, FR57, HU57D, LE57F, PI58, BA59K, BR59M,...

  9. Inner Area.FH11

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    241-TX- 155, 241-TX-302B, 241-TX-302BR, 241-TX-302C, 241-U-151, 241-U-152, 241-UX-154, 241-UX-302A, 241-WR VAULT, 241-Z, 276-S-141, 276-S-142, 2904-S-160, 2904-S-171,...

  10. Search for Lambda+(c) ---> p K+ pi- and D+(s) ---> K+ K+ pi- using genetic programming event selection

    SciTech Connect (OSTI)

    Link, J.M.; Yager, P.M.; Anjos, J.C.; Bediaga, I.; Castromonte, C.; Machado, A.A.; Magnin, J.; Massafferri, A.; de Miranda, J.M.; Pepe, I.M.; Polycarpo, E.; dos Reis,A.C.; Carrillo, S.; Casimiro, E.; Cuautle, E.; Sanchez-Hernandez, A.; Uribe, C.; Vazquez, F.; Agostino, L.; Cinquini, L.; Cumalat, J.P.; ,

    2005-07-01

    The authors apply a genetic programming technique to search for the doubly Cabibbo suppressed decays {Lambda}{sub c}{sup +} {yields} pK{sup +} {pi}{sup -} and D{sub s}{sup +} {yields} K{sup +}K{sup +}{pi}{sup -}. They normalize these decays to their Cabibbo favored partners and find BR({Lambda}{sub c}{sup +} {yields} pK{sup +}{pi}{sup -})/BR({Lambda}{sub c}{sup +} {yields} pK{sup -}{pi}{sup +}) = (0.05 {+-} 0.26 {+-} 0.02)% and BR(D{sub s}{sup +} {yields} K{sup +}K{sup +}{pi}{sup -})/BR(D{sub s}{sup +} {yields} K{sup -}K{sup +}{pi}{sup +}) = (0.52 {+-} 0.17 {+-} 0.11)% where the first errors are statistical and the second are systematic. Expressed as 90% confidence levels (CL), they find < 0.46% and < 0.78% respectively. This is the first successful use of genetic programming in a high energy physics data analysis.

  11. Facile fabrication of rutile monolayer films consisting of well crystalline nanorods by following an IL-assisted hydrothermal route

    SciTech Connect (OSTI)

    Peng Peng; Liu Xiaodi; Sun, Chuansheng; Ma Jianmin; Zheng Wenjun

    2009-05-15

    In this study, rutile films consisting of rectangular nanorods were facilely deposited on glass substrates from strongly acid solution of TiCl{sub 4}. The highly ordered array of nanorods was realized in presence of ionic liquid (IL) of [Bmim]Br by following a hydrothermal process. In this process, Degussa P25 nanoparticles served as seeds that were pre-deposited on the substrates to facilitate the array of rutile nanorods. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectrum were used to characterize the obtained nanorod films. The measurements showed that the nanorods were rectangular with width of 100-200 nm and length of more than 1 {mu}m, and grew up typically along c-axis to form the arrays against the substrate. The presence of IL was found vital for the formation of rutile nanorods, and the suitable molar ratio of [Bmim]Br to TiCl{sub 4} ranged from 500:1 to 1500:1. The excessive [Bmim]Br may hinder the precipitation of rutile particles. - Graphical abstract: The rutile film consisting of rectangular nanorods is successfully deposited on glass substrate in presence of ionic liquid (IL) of [Bmim]Br. The nanorods were rectangular with width of 100-200 nm and length of more than 1 {mu}m, which grew up typically along c-axis to form the arrays against the substrate.

  12. Lithium disulfide battery

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1988-01-01

    A negative electrode limited secondary electrochemical cell having dense FeS.sub.2 positive electrode operating exclusively on the upper plateau, a Li alloy negative electrode and a suitable lithium-containing electrolyte. The electrolyte preferably is 25 mole percent LiCl, 38 mole percent LiBr and 37 mole percent KBr. The cell may be operated isothermally.

  13. Resonance Raman and far-infrared studies of isotopically disordered and mixed-halide halogen-bridged platinum chain solids

    SciTech Connect (OSTI)

    Love, S.P.; Worl, L.A.; Donohoe, R.J.; Huckett, S.C.; Saxena, A.; Huang, X.Z.; Bishop, A.R.; Swanson, B.I.

    1992-12-31

    The MX chain solids [Pt(en){sub 2}][Pt(en){sub 2}X{sub 2}](CIO{sub 4}){sub 4}, (en = C{sub 2}H{sub 8}N{sub 2} and X=Cl, Br), referred to as ``PtX,`` are used to explore some of the surprising spectral consequences of disorder in 1-D systems, first for pure PtCl, where the disorder arises from randomly distributed Cl isotopes, then for the more drastic case of the mixed-halide materials PtCl{sub 1minusx}Br{sub x}. Lattice dynamics and Peierls-Hubbard modelling are used to analyze the observed spectral behavior. In both cases, the complex structure seen in the Raman and IR spectra is found to arise from strongly localized vibrational modes residing on chain segments, defined by sequences of Cl isotopes for PtCl, and by sequences of Cl and Br for PtCl{sub 1minusx}Br{sub x}. 4 figs, 8 refs.

  14. Pyrrolo isoquinolines

    DOE Patents [OSTI]

    Goodman, Mark M.; Shi, Bing Z.

    2000-01-01

    Compounds of the formula: ##STR1## wherein X, Y, and R, independently of one another, is each a H; halogen, wherein said halogen is selected from the group consisting of .sup.123 I, .sup.124 I, .sup.125 I, .sup.131 I, .sup.75 Br, .sup.76 Br, .sup.77 Br, .sup.82 Br, .sup.18 F, or .sup.210 At; small alkyl, small alkenyl, or small alkynyl, any of which contains from one to about six carbon atoms and optionally having a carbon atom replaced by an O or S; or halogen substituted-small alkyl, halogen substituted-small alkenyl, or halogen substituted-small alkynyl wherein said compound contains at least one radioacitve halogen. The compounds bind to the serotonin transporter. Depending upon the choice of halogen substituent, the compounds are useful for PET or SPECT imaging, diagnosis and treatment of psychiatric disorders such as depression, anxiety, obsessive-compulsive disorder, and other conditions associated with defects of serotonin transporter function.

  15. Mixed ionic-electronic conductor-based radiation detectors and methods of fabrication

    DOE Patents [OSTI]

    Conway, Adam; Beck, Patrick R; Graff, Robert T; Nelson, Art; Nikolic, Rebecca J; Payne, Stephen A; Voss, Lars; Kim, Hadong

    2015-04-07

    A method of fabricating a mixed ionic-electronic conductor (e.g. TlBr)-based radiation detector having halide-treated surfaces and associated methods of fabrication, which controls polarization of the mixed ionic-electronic MIEC material to improve stability and operational lifetime.

  16. Combustion-related studies using weakly-bonded complexes

    SciTech Connect (OSTI)

    Beaudet, R.A.

    1993-12-01

    Binary van der Waals complexes involving species of interest to combustion research are prepared in supersonic free-jet expansions, and their photochemical and photophysical properties are probed by using IR tunable diode laser (TDL) spectroscopy. In the first phase, geometries and other molecular properties are being determined from vibration-rotational spectra. In the second phase, these complexes will be used as precursors to study photoinitiated reactions in precursor geometry limited environments. Two complementary classes of binary complexes are being investigated. The first involves molecular oxygen and hydrogen containing constituents (e.g. O{sub 2}-HCN, O{sub 2}-HF, O{sub 2}-HCl, O{sub 2}-HBr, O{sub 2}-HI and O{sub 2}-hydrocarbons). These species are interesting candidates for study since upon photodissociating the hydride portion, the reaction H and O{sub 2} via the vibrationally excited HO{sub 2} intermediate can conceivably be studied, (e.g. BrH-O{sub 2} + hv(193 nm) {yields} Br-H-O{sub 2} {yields} Br + HO{sub 2} {yields} Br + OH + O). High resolution IR spectroscopy of such complexes have not been obtained previously and the structural information deriving from IR spectra is certainly very useful for better designing and understanding photoinitiated reactions that occur in these complexes.

  17. Center for Inverse Design: Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    prepared CsNiX3 (XCl, Br, I) A.D. Raw, J.A. Ibers, and K.R. Poeppelmeier, Journal of Solid State Chemistry 192, 34-37 (2012). DOI: 10.1016j.jssc.2012.03.037 Foundational:...

  18. A=18F (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    model: (1978WI1B, 1982ZH01, 1983BR29, 1983KI13, 1984MI1H, 1984MI17, 1985LE1K, 1986YU1B). Cluster, collective and deformed models: (1983ME12, 1984QU1A, 1985BA1A, 1987ER05). Special...

  19. A=8Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the geometric value, supports the hypothesis that 7Li may be described as an ( + t) cluster (RO62C). See also (AL63N, BA63O, BR63M, VA64G). 9. 7Li(d, p)8Li Qm -0.192...

  20. A=17O (1982AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1977HA1Z, 1977PO16, 1978CH26, 1978KR02, 1979KA06, 1980BR13, 1980VA05). Collective and cluster models: (1978CH26, 1978TA1A, 1978TH1A, 1980FU1G). Special states: (1977HE18,...

  1. A=19F (1983AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1978DA1N, 1978MA2H, 1979DA15, 1980KU05, 1980MC1L, 1981ER03, 1981GR06, 1982KI02). Cluster, collective and rotational models: (1977BU22, 1977FO1E, 1978BR21, 1978CH26,...

  2. Fluid-evaporation records preserved in salt assemblages in Meridiani rocks

    SciTech Connect (OSTI)

    Rao, M.N.; Nyquist, L.E.; Sutton, S.R.; Dreibus, G.; Garrison, D.H.; Herrin, J.

    2009-09-25

    We studied the inter-relationships between the major anions (SO{sub 3}, Cl, and Br) and cations (FeO, CaO and MgO) using elemental abundances determined by APXS in salt assemblages of RATted (abraded) rocks at Meridiani to characterize the behavior of fluids that infiltrated into this region on Mars. A plot of SO{sub 3} versus Cl for the abraded rocks yielded an unusual pattern, whereas the SO{sub 3}/Cl ratios versus Cl for the same rocks showed a monotonically decreasing trend represented by a hyperbola. The systematic behavior of the SO{sub 3} and Cl data in the documented rocks at Meridiani suggests that these anions behaved conservatively during fluid-rock interactions. These results further indicate that two kinds of fluids, referred to as SOL-I and SOL-II, infiltrated into Endurance/Eagle/Fram craters, where they underwent progressive evaporative concentration. SOL-I is a low pH fluid consisting of high SO{sub 3} and low Cl and high Br, (this fluid infiltrated all the way to the crater-top region), whereas SOL-II fluid of high pH with low SO{sub 3} and high Cl and low Br reached only an intermediary level known as the Whatanga contact at Endurance. Based on the FeO/MgO as well as CaO/MgO versus SO{sub 3}/Cl diagram for rocks above the Whatanga contact, the cation and anion relationships in this system suggest that the Fe{sup 2+}/SO{sub 4} and Ca{sup 2+}/SO{sub 4} ratios in SOL-I fluids at Meridiani were > 1 before the onset of evaporation based on the 'chemical divide' considerations. Below the Whatanga contact, relatively dilute SOL-II fluids seem to have infiltrated and dissolved/flushed away the easily soluble Mg-sulfate/chloride phases (along with Br) without significantly altering the SO{sub 3}/Cl ratios in the residual salt assemblages. Further, Cl/Br versus Br in rocks above the Whatanga contact show a hyperbolic trend suggesting that Cl and Br behaved conservatively similar to SO{sub 3} and Cl in the SOL-1 fluids at Meridiani. Our results are consistent with a scenario involving two episodes (SOL-I and SOL-II) of groundwater recharge at Meridiani Planum.

  3. A STELLAR WIND ORIGIN FOR THE G2 CLOUD: THREE-DIMENSIONAL NUMERICAL SIMULATIONS

    SciTech Connect (OSTI)

    De Colle, Fabio; Raga, A. C.; Contreras-Torres, Flavio F.; Toledo-Roy, Juan C.

    2014-07-10

    We present three-dimensional, adaptive mesh refinement simulations of G2, a cloud of gas moving in a highly eccentric orbit toward the galactic center. We assume that G2 originates from a stellar wind interacting with the environment of the Sgr A* black hole. The stellar wind forms a cometary bubble which becomes increasingly elongated as the star approaches periastron. A few months after periastron passage, streams of material begin to accrete on the central black hole with accretion rates M-dot ?10{sup ?8} M {sub ?}yr{sup 1}. Predicted Br? emission maps and position-velocity diagrams show an elongated emission resembling recent observations of G2. A large increase in luminosity is predicted by the emission coming from the shocked wind region during periastron passage. The observations, showing a constant Br? luminosity, remain puzzling, and are explained here assuming that the emission is dominated by the free-wind region. The observed Br? luminosity (?8 10{sup 30}ergs{sup 1}) is reproduced by a model with a v{sub w} = 50kms{sup 1} wind velocity and a 10{sup 7} M {sub ?}yr{sup 1} mass-loss rate if the emission comes from the shocked wind. A faster and less dense wind reproduces the Br? luminosity if the emission comes from the inner, free-wind region. The extended cometary wind bubble, largely destroyed by the tidal interaction with the black hole, reforms a few years after periastron passage. As a result, the Br? emission is more compact after periastronpassage.

  4. Mechanism of charge recombination in meso-structured organic-inorganic hybrid perovskite solar cells: A macroscopic perspective

    SciTech Connect (OSTI)

    Yang, Wenchao; Yao, Yao Wu, Chang-Qin

    2015-04-21

    In the currently popular organic-inorganic hybrid perovskite solar cells, the slowness of the charge recombination processes is found to be a key factor for contributing to their high efficiencies and high open circuit voltages, but the underlying recombination mechanism remains unclear. In this work, we investigate the bimolecular recombination (BR) and the trap-assisted monomolecular recombination (MR) in meso-structured perovskite solar cells under steady state working condition, and try to reveal their roles on determining the device performance. Some interfacial effects such as the injection barriers at the selective contacts are examined as well. Based on the macroscopic device modeling, the recombination resistance-voltage (R{sub rec}−V) and the current density-voltage (J–V) curves are calculated to characterize the recombination mechanism and describe the device performance, respectively. Through comparison with the impedance spectroscopy extracted R{sub rec} data, it is found that under the typical BR reduction factor and deep trap densities observed in experiments, the MR dominates the charge recombination in the low voltage regime, while the BR dominates in the high voltage regime. The short circuit current and the fill factor could be reduced by the significant MR but the open circuit voltage is generally determined by the BR. The different electron injection barriers at the contact can change the BR rate and induce different patterns for the R{sub rec}–V characteristics. For the perovskites of increased band gaps, the R{sub rec}'s are significantly enhanced, corresponding to the high open circuit voltages. Finally, it is revealed that the reduced effective charge mobility due to the transport in electron and hole transporting material makes the R{sub rec} decrease slowly with the increasing voltage, which leads to increased open circuit voltage.

  5. Breast Imaging Reporting and Data System (BI-RADS) breast composition descriptors: Automated measurement development for full field digital mammography

    SciTech Connect (OSTI)

    Fowler, E. E.; Sellers, T. A.; Lu, B.; Heine, J. J.

    2013-11-15

    Purpose: The Breast Imaging Reporting and Data System (BI-RADS) breast composition descriptors are used for standardized mammographic reporting and are assessed visually. This reporting is clinically relevant because breast composition can impact mammographic sensitivity and is a breast cancer risk factor. New techniques are presented and evaluated for generating automated BI-RADS breast composition descriptors using both raw and calibrated full field digital mammography (FFDM) image data.Methods: A matched case-control dataset with FFDM images was used to develop three automated measures for the BI-RADS breast composition descriptors. Histograms of each calibrated mammogram in the percent glandular (pg) representation were processed to create the new BR{sub pg} measure. Two previously validated measures of breast density derived from calibrated and raw mammograms were converted to the new BR{sub vc} and BR{sub vr} measures, respectively. These three measures were compared with the radiologist-reported BI-RADS compositions assessments from the patient records. The authors used two optimization strategies with differential evolution to create these measures: method-1 used breast cancer status; and method-2 matched the reported BI-RADS descriptors. Weighted kappa (?) analysis was used to assess the agreement between the new measures and the reported measures. Each measure's association with breast cancer was evaluated with odds ratios (ORs) adjusted for body mass index, breast area, and menopausal status. ORs were estimated as per unit increase with 95% confidence intervals.Results: The three BI-RADS measures generated by method-1 had ? between 0.250.34. These measures were significantly associated with breast cancer status in the adjusted models: (a) OR = 1.87 (1.34, 2.59) for BR{sub pg}; (b) OR = 1.93 (1.36, 2.74) for BR{sub vc}; and (c) OR = 1.37 (1.05, 1.80) for BR{sub vr}. The measures generated by method-2 had ? between 0.420.45. Two of these measures were significantly associated with breast cancer status in the adjusted models: (a) OR = 1.95 (1.24, 3.09) for BR{sub pg}; (b) OR = 1.42 (0.87, 2.32) for BR{sub vc}; and (c) OR = 2.13 (1.22, 3.72) for BR{sub vr}. The radiologist-reported measures from the patient records showed a similar association, OR = 1.49 (0.99, 2.24), although only borderline statistically significant.Conclusions: A general framework was developed and validated for converting calibrated mammograms and continuous measures of breast density to fully automated approximations for the BI-RADS breast composition descriptors. The techniques are general and suitable for a broad range of clinical and research applications.

  6. 14N Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p, X) (Incomplete) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 2003MU12 14N(p, γ): deduced astrophysical S-factors < 600 keV X4 05/06/2013 1990WA10 14N(p, n): σ < 30 X4 04/26/2012 2005CO16, 2006BE50 14N(p, γ): σ, deduced astrophysical S-factors, resonance strength 70 - 228 keV X4 05/08/2013 2006LE13 14N(p, γ): σ, deduced astrophysical S-factors 70 - 228 keV X4 05/30/2013 2005BR04, 2005BR15 14N(p, γ): astrophysical S-factors ~ 0.1 - 2.5 1 08/15/2013 2004FO02,

  7. PYOMELANIN IS PRODUCED BY SHEWANELLA ALGAE BRY AND EFFECTED BY EXOGENOUS IRON

    SciTech Connect (OSTI)

    Turick, C; Frank Caccavo, F; Jr., J; Louis S. Tisa, L

    2006-11-29

    Melanin production by S. algae BrY occurred during late/post-exponential growth in lactate-basal-salts liquid medium supplemented with tyrosine or phenylalanine. The antioxidant ascorbate inhibited melanin production, but not production of the melanin precursor, homogentisic acid. In the absence of ascorbate, melanin production was inhibited by the 4-hydroxyplenylpyruvate dioxygenase inhibitor, sulcotrione and Fe(II) (>0.2mM). These data support the hypothesis that pigment production by S. algae BrY was a result the conversion of tyrosine or phenylalanine to homogentisic acid which was excreted, auto-oxidized and self-polymerized to form pyomelanin. The inverse relationship between Fe(II) concentration and pyomelanin production has implications that pyomelanin may play a role in iron assimilation under Fe(II) limiting conditions.

  8. A=14O (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    59AJ76) (Not illustrated) GENERAL: See also Table 14.13 [Table of Energy Levels] (in PDF or PS). Mass of 14O: The mass excess of 14O is 12.149 ± 0.007 MeV, based on the threshold energy of the 12C(3He, n)14O reaction (BR57) and on the Wapstra masses (WA55C) for 12C, 3He and n. The binding energies of a proton, alpha particle, 3He-particle and deuteron in 14O are, respectively, 4.621, 10.25, 17.563 and 22.58 MeV. In terms of the Mattauch masses (MA56M), the mass excess obtained by (BR57) is

  9. A=20O (1972AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    72AJ02) (See Energy Level Diagrams for 20O) GENERAL: See Table 20.1 [Table of Energy Levels] (in PDF or PS). Model calulations: (1959BR1E, 1960TA1C, 1962TA1B, 1963PA03, 1964CO24, 1964MO1E, 1964PA1D, 1964TR1A, 1965DE1H, 1965FE02, 1966AR10, 1966BR04, 1966TR02, 1967FE01, 1967FL13, 1967LA1H, 1967PI1B, 1968AR02, 1968BE1U, 1968CO1N, 1968FL1C, 1968GU1E, 1968HA17, 1968HA1P, 1968MO1G, 1968PA1Q, 1969FE1A, 1969KU1G, 1969SO08, 1971AR25). Other theoretical calculations: (1961JA1E, 1966KE16, 1967ST1N,

  10. Use of differential pulse polarography to study corrosion of galvanized steel in aqueous lithium bromide solution

    SciTech Connect (OSTI)

    Garcia-Anton, J.; Perez-Herranz, V.; Guinon, J.L. . Dept. de Ingenieria Quimica y Nuclear); Lacoste, G. )

    1994-02-01

    Static and dynamic corrosion of galvanized steel in 4.6 M lithium bromide (LiBr) solution at 20 C and at 70 C was studied using a new polarographic method for the determination of zinc (Zn) in LiBr solution. Static and dynamic corrosion of galvanize steel at 20 C and 70 C followed a linear tendency with exposure time. However, a change in the slope of dynamic corrosion was observed at 20 C. The corrosion product was studied using energy dispersive x-ray analysis (EDXA) and x-ray diffractometry and was considered to be a mixture of zinc hydroxide Zn(OH)[sub 2] and oxides. The corrosion product morphology was amorphous and gelatinous at 20 C and crystalline at 70 C.

  11. Dudley Herschbach: Chemical Reactions and Molecular Beams

    Office of Scientific and Technical Information (OSTI)

    Dudley Herschbach: Chemical Reactions and Molecular Beams Resources with Additional Information Dudley Herschbach Courtesy of Texas A&M University As a co-recipient of the 1986 Nobel Prize in Chemistry, 'Dudley Herschbach was cited for "providing a much more detailed understanding of how chemical reactions take place". Using molecular beams, he studied elementary reactions such as K + CH3I and K + Br2, where it became possible to correlate reaction dynamics with the electronic

  12. Establishment and Characterization of a Bioenergy-Focused Microalgal Strain

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Collection - Energy Innovation Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Establishment and Characterization of a Bioenergy-Focused Microalgal Strain Collection National Renewable Energy Laboratory Colorado School of Mines Contact NREL About This Technology High lipid strain from NREL culture collection. Photo by Lee Elliott, Colorado School of Mines<br /> High lipid strain from NREL culture collection. Photo by Lee Elliott, Colorado School of

  13. Ordovician carbonate formation waters in the Illinois Basin: Chemical and isotopic evolution beneath a regional aquitard

    SciTech Connect (OSTI)

    Stueber, A.M. ); Walter, L.M. . Dept. of Geological Sciences)

    1992-01-01

    Formation waters from carbonate reservoirs in the upper Ordovician Galena Group of the Illinois Basin have been analyzed geochemically to study origin of salinity, chemical and isotopic evolution, and relation to paleohydrologic flow systems. These carbonate reservoirs underlie the Maquoketa Shale Group of Cincinnatian age, which forms a regional aquitard. Cl-Br relations and Na/Br-Cl/Br systematics indicate that initial brine salinity resulted from subaerial evaporation of seawater to a point not significantly beyond halite saturation. Subsequent dilution in the subsurface by meteoric waters is supported by delta D-delta O-18 covariance. Systematic relations between Sr-87/Sr-86 and 1/Sr suggest two distinct mixing events: introduction of a Sr-87 enriched fluid from a siliciclastic source, and a later event which only affected reservoir waters from the western shelf of the basin. The second mixing event is supported by covariance between Sr-87/Sr-86 and concentrations of cations and anions; covariance between Sr and O-D isotopes suggests that the event is related to meteoric water influx. Systematic geochemical relations in ordovician Galena Group formation waters have been preserved by the overlying Maquoketa shale aquitard. Comparison with results from previous studies indicates that waters from Silurian-Devonian carbonate strata evolved in a manner similar to yet distinct from that of the Ordovician carbonate waters, whereas waters from Mississippian-Pennsylvanian strata that overlie the New Albany Shale Group regional aquitard are marked by fundamentally different Cl-Br-Na and Sr isotope systematics. Evolution of these geochemical formation-water regimes apparently has been influenced significantly by paleohydrologic flow systems.

  14. INSTRUCTIONS FOR PREPARATION OF PAPERS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    COLLABORATIVE DEVELOPMENT OF AUTOMATED ADVANCED INTEROPERABILITY CERTIFICATION TEST PROTOCOLS FOR PV SMART GRID INTEGRATION Jay Johnson*, Roland Bründlinger**, Cesar Urrego***, and Ricardo Alonso**** * Corresponding Author Sandia National Laboratories P.O. Box 5800 MS0352 Albuquerque, NM 87185-0352 USA Phone: +1 505-284-9586 Fax: +1 505-844-3952 jjohns2@sandia.gov ** Austrian Institute of Technology Donau-City-Strasse 1 1220 Wien, Austria Phone: +43 50550 6351 Fax: +43 50550 6390

  15. Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous Silica

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Material | Department of Energy Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous Silica Material Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous Silica Material Image of porous silica material in alcohol.<br /> Photo credit: Oak Ridge National Lab Image of porous silica material in alcohol. Photo credit: Oak Ridge National Lab Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partner: VELUX Design and Development Company USA Inc.,

  16. Thermal Scout Software - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Analysis Energy Analysis Find More Like This Return to Search Thermal Scout Software National Renewable Energy Laboratory Contact NREL About This Technology Publications: PDF Document Publication "Field Survey of Parabolic Trough Receiver Thermal Performance" H. Price, R. Forristall, T. Wendelin, and A. Lewandowski, NREL/CP-550-39459, April 2006 (914 KB) Heat Collection Element Survey System software<br /> Heat Collection Element Survey System software Parabolic troughs

  17. Photovoltaic (PV) Module Level Remote Safety Disconnect - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Find More Like This Return to Search Photovoltaic (PV) Module Level Remote Safety Disconnect National Renewable Energy Laboratory Contact NREL About This Technology Figure 1: System configuration of emergency module-level disconnect using module-level &lsquo;Isolation Detection Units&rsquo; (IDU).<br /> Figure 1: System configuration of emergency module-level disconnect using module-level 'Isolation Detection Units' (IDU). Technology Marketing Summary The ability to

  18. Low-temperature fabrication of efficient wide-bandgap organolead trihalide perovskite solar cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bi, Cheng; Yuan, Yongbo; Fang, Yanjun; Huang, Jinsong

    2014-11-25

    A mixed halide perovskite solar cell with a 1.72 eV bandgap is developed by incorporating Br into perovskite through a low-temperature solution process. A high efficiency of 13.1% is achieved by carefully tuning the thickness, morphology, and surface passivation of the perovskite layers. Furthermore, the fabrication techniques and conditions are compatible with future perovskite/Si tandem cell studies.

  19. Optimal design of one-dimensional photonic crystal back reflectors for thin-film silicon solar cells

    SciTech Connect (OSTI)

    Chen, Peizhuan; Hou, Guofu Zhang, Jianjun Zhang, Xiaodan; Zhao, Ying

    2014-08-14

    For thin-film silicon solar cells (TFSC), a one-dimensional photonic crystal (1D PC) is a good back reflector (BR) because it increases the total internal reflection at the back surface. We used the plane-wave expansion method and the finite difference time domain (FDTD) algorithm to simulate and analyze the photonic bandgap (PBG), the reflection and the absorption properties of a 1D PC and to further explore the optimal 1D PC design for use in hydrogenated amorphous silicon (a-Si:H) solar cells. With identified refractive index contrast and period thickness, we found that the PBG and the reflection of a 1D PC are strongly influenced by the contrast in bilayer thickness. Additionally, light coupled to the top three periods of the 1D PC and was absorbed if one of the bilayers was absorptive. By decreasing the thickness contrast of the absorptive layer relative to the non-absorptive layer, an average reflectivity of 96.7% was achieved for a 1D PC alternatively stacked with a-Si:H and SiO{sub 2} in five periods. This reflectivity was superior to a distributed Bragg reflector (DBR) structure with 93.5% and an Ag film with 93.4%. n-i-p a-Si:H solar cells with an optimal 1D PC-based BR offer a higher short-circuit current density than those with a DBR-based BR or an AZO/Ag-based BR. These results provide new design rules for photonic structures in TFSC.

  20. Low-GWP Refrigerants for Refrigeration Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-GWP Refrigerants for Refrigeration Systems Low-GWP Refrigerants for Refrigeration Systems Brian Fricke conducts research in ORNL's Building Technologies Research & Integration Center. Brian Fricke conducts research in ORNL's Building Technologies Research & Integration Center. Life Cycle Climate Performance of supermarket refrigeration.<br /> Credit: Oak Ridge National Lab Life Cycle Climate Performance of supermarket refrigeration. Credit: Oak Ridge National Lab Brian Fricke

  1. Study on third-order nonlinear optical properties of 4-methylsulfanyl chalcone derivatives using picosecond pulses

    SciTech Connect (OSTI)

    D'silva, E.D.; Podagatlapalli, G. Krishna; Venugopal Rao, S.; Dharmaprakash, S.M.

    2012-11-15

    Graphical abstract: Photograph and schematic representation of Z-scan experimental setup used to investigate third order nonlinear properties of the chalcone materials. Highlights: ? Br and NO{sub 2} substituted chalcone derivatives were exposed to picosecond laser pulses. ? Third-order nonlinear optical (NLO) properties were investigated. ? Compounds show promising third-order and optical limiting properties. ? These materials found suitable for electrical and optical applications. -- Abstract: In this paper we present results from the experimental study of third-order nonlinear optical (NLO) properties of three molecules of Br and NO{sub 2} substituted chalcone derivatives namely (2E)-1-(4-bromophenyl)-3-[4(methylsulfanyl)phenyl]prop-2-en-1-one (4Br4MSP), (2E)-1-(3-bromophenyl)-3-[4-(methylsulfanyl) phenyl]prop-2-en-1-one (3Br4MSP) and (2E)-3[4(methylsulfanyl) phenyl]-1-(4-nitrophenyl)prop-2-en-1-one (4N4MSP). The NLO properties have been investigated by Z-scan technique using 2 ps laser pulses at 800 nm. The nonlinear refractive indices, nonlinear absorption coefficient, and the magnitude of third-order susceptibility have been determined. The values obtained are of the order of 10{sup ?7} cm{sup 2}/GW, 10{sup ?3} cm/GW and 10{sup ?14} esu respectively. The molecular second hyperpolarizability for the chalcone derivatives is of the order of 10{sup ?32} esu. The coupling factor, excited state cross section, ground state cross section etc. were determined. The optical limiting (OL) property was studied. The results suggest that the nonlinear properties investigated for present chalcones are comparable with some of the reported chalcone derivatives and can be desirable for NLO applications.

  2. Advanced LWR Nuclear Fuel Development

    Energy Savers [EERE]

    Department of Energy Ground Source Heat Pump Technology for Very-Low-Energy Buildings Advanced Ground Source Heat Pump Technology for Very-Low-Energy Buildings Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential<br /> Credit: Oak Ridge National Lab Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential Credit: Oak Ridge National Lab Cumulative GSHP conditioned building floor

  3. Appliance Rebates: Frequently Asked Questions | Department of Energy

    Energy Savers [EERE]

    HVAC, Water Heating, Appliances R&D » Appliance Projects Appliance Projects Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator Lead Performer: GE Global Research, Niskayuna, NY Schematics of a heat pump clothes dryer<br /> Credit: Oak Ridge National Lab Heat Pump Clothes Dryer Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partner: GE Appliances - Louisville, KY Image of the compressor rack and system diagram for the CO2 refrigeration

  4. Nuclear Data Sheets for A = 68

    SciTech Connect (OSTI)

    McCutchan, E. A.

    2012-07-01

    The experimental results from the various reaction and radioactive decay studies leading to nuclides in the A = 68 mass chain have been reviewed. Nuclides ranging from Cr (Z = 24) to Br (Z = 35) are included. For these nuclei, level and decay schemes, as well as tables of nuclear properties, are given. This work supersedes the previous evaluation of the data on these nuclides (2002Bu29).

  5. Ground-Water Table and Chemical Changes in an Alluvial Aquifer During

    Energy Savers [EERE]

    Ground Source Heat Pump System Data Analysis Ground Source Heat Pump System Data Analysis Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech16_liu_040313.pdf More Documents & Publications Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential<br /> Credit: Oak Ridge National Lab Advanced Ground Source Heat Pump Technology for Very-Low-Energy Buildings Oak Ridge City Center

  6. Helpful Resources for Open Season 2015 | Department of Energy

    Energy Savers [EERE]

    Heating, Ventilation, and Air Conditioning Projects Heating, Ventilation, and Air Conditioning Projects Credit: Oak Ridge National Lab 13-Energy Efficiency Ratio Window Air Conditioner Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partners: General Electric - Fairfield, CT Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential<br /> Credit: Oak Ridge National Lab Advanced Ground Source Heat Pump Technology for

  7. TO: F FROH: SUBJEC

    Office of Legacy Management (LM)

    F FROH: SUBJEC :T: SITE NAME: CITY:- UWNERI -----_ Past 0Wl-N TYPE C - - - - - - 0 Rez CONTRkCTING PERIOD: /+=I s-3 -----T-- -------- -- -------------------------------------- OWNERSHIP: - - .-- !E ; e; Ip; Pj Br Tt Si IF .-- imr ,CE !ct MEMORANDUM :ILE DATE "1) 241g7 --- ---- _______~ -----_----_ G3d:w i/( ?=v;rt i D.'lr.-s:rM ALTERNATE ~----~----_---____--_________________ NAME: -0-------------_____ B&J ii m0T.e ---- -~--___~~~--~----~~ STATE: fi a ---------_-__ I3 Facility Type

  8. Method of selective reduction of polyhalosilanes with alkyltin hydrides

    DOE Patents [OSTI]

    Sharp, Kenneth G.; D'Errico, John J.

    1989-01-01

    The invention relates to the selective and stepwise reduction of polyhalosilanes by reacting at room temperature or below with alkyltin hydrides without the use of free radical intermediates. Alkyltin hydrides selectively and stepwise reduce the Si--Br, Si--Cl, or Si--I bonds while leaving intact any Si--F bonds. When two or more different halogens are present on the polyhalosilane, the halogen with the highest atomic weight is preferentially reduced.

  9. Method of selective reduction of halodisilanes with alkyltin hydrides

    DOE Patents [OSTI]

    D'Errico, John J.; Sharp, Kenneth G.

    1989-01-01

    The invention relates to the selective and sequential reduction of halodisilanes by reacting these compounds at room temperature or below with trialkyltin hydrides or dialkyltin dihydrides without the use of free radical intermediates. The alkyltin hydrides selectively and sequentially reduce the Si-Cl, Si-Br or Si-I bonds while leaving intact the Si-Si and Si-F bonds present.

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reality Check: Estimates for Human-Caused Methane Emissions in the U.S. Appear Off by 50% Download a printable PDF Submitter: Biraud, S. C., Lawrence Berkeley National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Miller SM, SC Wofsy, AM Michalak, EA Kort, AE Andrews, SC Biraud, EJ Dlugokencky, J Elszkeiwicz, ML Fischer, G Janssens-Maenhout, BR Miller, JB Miller, SA Montzka, T Nehrkorn, and C Sweeney. 2013. "Anthropogenic emissions

  11. Advanced Hybrid Water Heater using Electrochemical Compressor | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Hybrid Water Heater using Electrochemical Compressor Advanced Hybrid Water Heater using Electrochemical Compressor Xergy is using its Electro Chemical Compression (ECC) technology to operate a heat pump cycle using water as the working fluid<br /> Image: Xergy Xergy is using its Electro Chemical Compression (ECC) technology to operate a heat pump cycle using water as the working fluid Image: Xergy Xergy's technology has the potential to move away from vapor compression

  12. NOVEL LUBRICANT ADDITIVES - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search NOVEL LUBRICANT ADDITIVES Argonne National Laboratory Contact ANL About This Technology <em>Upper, the functionalized nanostructures mixed with poly-alpha-olefin (PAO)-4 reduce friction as test temperature is raised. Lower, Friction coefficient remains unchanged at all test temperatures with PAO4 alone.&nbsp; </em><br /> Upper, the functionalized nanostructures mixed with poly-alpha-olefin (PAO)-4 reduce friction as test temperature is

  13. Multifunctional Platelet Composites for Tin Whisker Mitigation - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Multifunctional Platelet Composites for Tin Whisker Mitigation Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (555 KB) <br type="_moz" /> SEM image showing in-plane orientation of platelets in Sandia&#39;s multifunctional platelet composite SEM image showing in-plane orientation of platelets in Sandia's multifunctional platelet composite Technology Marketing Summary In order to comply

  14. Dissecting ion-specific dielectric spectra of sodium-halide solutions into

    Office of Scientific and Technical Information (OSTI)

    solvation water and ionic contributions (Journal Article) | SciTech Connect Dissecting ion-specific dielectric spectra of sodium-halide solutions into solvation water and ionic contributions Citation Details In-Document Search Title: Dissecting ion-specific dielectric spectra of sodium-halide solutions into solvation water and ionic contributions Using extensive equilibrium molecular dynamics simulations we determine the dielectric spectra of aqueous solutions of NaF, NaCl, NaBr, and NaI.

  15. Group 3: Humidity, Temperature, and Voltage | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech16_liu_040313.pdf More Documents & Publications Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential<br /> Credit: Oak Ridge National Lab Advanced Ground Source Heat Pump Technology for Very-Low-Energy Buildings Oak Ridge City Center Technology Demonstration Project 4th U.S.-China Energy Efficiency Forum Documents

  16. Pixel and Microstrip detectors for current and future synchrotron light

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sources | Stanford Synchrotron Radiation Lightsource Pixel and Microstrip detectors for current and future synchrotron light sources Friday, July 1, 2011 - 1:00pm SLAC, Kavli Auditorium Dr. Christian Brönnimann, CEO, DECTRIS Ltd., CH-5400 Baden, Switzerland The PILATUS pixel detectors, large area modular two-dimensional hybrid pixel array detectors, have revolutionized protein crystallography and biological small- and wide-angle scattering by combining noise-free counter properties with

  17. Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report

    SciTech Connect (OSTI)

    Alicia M. Wilson

    2009-11-30

    Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

  18. Renewable chemical feedstock - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Renewable chemical feedstock Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Coexpressing Escherichia coli Cyclopropane Synthase with Sterculia foetida Lysophosphatidic Acid Acyltransferase Enhances Cyclopropane Fatty Acid Accumulation (424 KB) <br type="_moz" /> Synthesis of cyclopropane fatty acids (CPFA) and illustrations of natural sources of CPFAs. Synthesis of cyclopropane fatty

  19. Direct Thermal Receivers Using Near Blackbody Configurations - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Thermal Solar Thermal Energy Storage Energy Storage Find More Like This Return to Search Direct Thermal Receivers Using Near Blackbody Configurations National Renewable Energy Laboratory Contact NREL About This Technology Figure 1. Schematic of the cylinder acting as a near-blackbody receiver when solar radiation enters the cylinder&#39;s left end<br /> Figure 1. Schematic of the cylinder acting as a near-blackbody receiver when solar radiation enters the

  20. Electron attachment to C{sub 2} fluorocarbon radicals at high temperature

    SciTech Connect (OSTI)

    Shuman, Nicholas S.; Miller, Thomas M.; Viggiano, Albert A.

    2013-11-14

    Thermal electron attachment to the radical species C{sub 2}F{sub 3} and C{sub 2}F{sub 5} has been studied over the temperature range 300–890 K using the Variable Electron and Neutral Density Attachment Mass Spectrometry technique. Both radicals exclusively undergo dissociative attachment to yield F{sup −}. The rate constant for C{sub 2}F{sub 5} shows little dependence over the temperature range, remaining ∼4 × 10{sup −9} cm{sup 3} s{sup −1}. The rate constant for C{sub 2}F{sub 3} attachment rises steeply with temperature from 3 × 10{sup −11} cm{sup 3} s{sup −1} at 300 K to 1 × 10{sup −9} cm{sup 3} s{sup −1} at 890 K. The behaviors of both species at high temperature are in agreement with extrapolations previously made from data below 600 K using a recently developed kinetic modeling approach. Measurements were also made on C{sub 2}F{sub 3}Br and C{sub 2}F{sub 5}Br (used in this work as precursors to the radicals) over the same temperature range, and, for C{sub 2}F{sub 5}Br as a function of electron temperature. The attachment rate constants to both species rise with temperature following Arrhenius behavior. The attachment rate constant to C{sub 2}F{sub 5}Br falls with increasing electron temperature, in agreement with the kinetic modeling. The current data fall in line with past predictions of the kinetic modeling approach, again showing the utility of this simplified approach.

  1. Inorganic rechargeable non-aqueous cell

    DOE Patents [OSTI]

    Bowden, William L. (Nashua, NH); Dey, Arabinda N. (Needham, MA)

    1985-05-07

    A totally inorganic non-aqueous rechargeable cell having an alkali or alkaline earth metal anode such as of lithium, a sulfur dioxide containing electrolyte and a discharging metal halide cathode, such as of CuCl.sub.2, CuBr.sub.2 and the like with said metal halide being substantially totally insoluble in SO.sub.2 and admixed with a conductive carbon material.

  2. Polytechnic Institute of New York University Researchers Represented in the E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EDUconnections Spotlight Polytechnic Institute of New York University Researchers Represented in the E-print Network Researcher/Research Institution Web page Aronov, Boris - Department of Computer Science and Engineering, Polytechnic Institute of New York University http://cis.poly.edu/~aronov/research. html Brönnimann, Hervé - Department of Computer Science and Engineering, Polytechnic Institute of New York University http://photon.poly.edu/~hbr/publis. html Chiang, Yi-Jen - Department of

  3. Posters Radiation Singularities, Multiple Scattering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Posters Radiation Singularities, Multiple Scattering and Diffusion in Multifractal Clouds P. Silas, G. Brösamlen, and S. Lovejoy Department of Physics McGill University Montreal, Quebec, Canada C. Naud and D. Schertzer Université Pierre and Marie Curie Paris, France B. Watson Department of Physics St. Lawrence University Canton, New York Diffusion on One-Dimensional Multifractals (P. Silas, S. Lovejoy, D. Schertzer) Many geophysical and atmospheric fields exhibit multifractal characteristics

  4. Energy Efficient Clothes Dryer with IR Heating and Electrostatic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Precipitator | Department of Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator Energy Efficient Clothes Dryer with IR Heating and Electrostatic Precipitator This project seeks to demonstrate a ventless residential dryer with an energy factor greater than 4.04.<br /> Photo credit: GE Global Research This project seeks to demonstrate a ventless residential dryer with an energy factor greater than 4.04. Photo credit: GE Global Research Project team members left

  5. Doping Cu{sub 2}O in Electrolyte Solution: Dopant Incorporation, Atomic Structures and Electrical Properties

    SciTech Connect (OSTI)

    Tao, Meng; Zhang, Qiming

    2013-11-24

    We have pursued a number of research activities between April 2010 and April 2011:  A detailed study on n-type doping in Cu2O by Br;  An analysis of natural resource limitations to terawatt-scale solar cells;  Attempt to achieve a 1.4-eV direct band gap in Ni sulfides (NiSx);  First-principles studies of doping in Cu2O and electronic structures of NiSx.

  6. Distribution Category UC-38 UCRL-52863-Rev.l

    Office of Scientific and Technical Information (OSTI)

    ... R >y> Pd J n (VT3) W . I I I - * I I - " * -br 2 V ex P ( " K n 1 P d Z , X f ... F 2 7 0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 Profile number K,T3( 2 kb 0 FIG. ...

  7. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experiments and hybrid multiscale models for the production of p-xylene from DMF and ethylene indicate two regimes vs. acid site concentration and reveal the mechanism for tandem Lewis/Brønsted catalyzed reactions. Kinetic Regimes in the Production of Renewable p-Xylene Work was performed at the Universities of Minnesota, Massachusetts and Delaware by the group of Dauenhauer, Fan, Caratzoulas and Vlachos Research Details - Kinetic experiments indicate two regimes despite cycloaddition having a

  8. A Combined Water Heater, Dehumidifier, and Cooler (WHDC) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy A Combined Water Heater, Dehumidifier, and Cooler (WHDC) A Combined Water Heater, Dehumidifier, and Cooler (WHDC) Figure 1: The system model for the combined Water heater, dehumidifier and cooler (WHDC). Figure 1: The system model for the combined Water heater, dehumidifier and cooler (WHDC). Figure 2: Initial test results from a water heater and dehumidifier utilizing LiBr as a working fluid being tested at UF: System COP and capacity for different heat inputs. Figure 2: Initial test

  9. ARM - Facility News Article

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9, 2008 [Facility News] Final Preparations Underway for Arctic Aerosol Field Campaign Bookmark and Share In this flight pattern, the Convair-580 takes off from Barrow (BR) after refueling, flies several legs within clouds between 1-2 km high, then returns to base at Fairbanks. With just one month before the start of the Indirect and Semi-direct Aerosol Campaign (ISDAC), the ARM Aerial Vehicles Program (AVP) is finalizing the necessary contract arrangements, instrumentation integration

  10. All-Star Nanocrystals | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    All-Star Nanocrystals Researchers discovered semiconducting nanocrystals that not only function as stellar light-to-energy converters but also as stable light emitters. Scientists synthesized a series of perovskite nanocrystals with different morphologies i.e., dots, rods, wires, plates, and sheets. Perovskite materials such as CH3NH3PbX3 (X = I, Br) are known to display many intriguing electronic light and chemical properties. Studies found that the rods and wires showed higher

  11. Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate

    Broader source: Energy.gov (indexed) [DOE]

    See past projects. Acoustic Building Infiltration Measurement System (ABIMS) Lead Performer: Argonne National Laboratory - Lemont, IL Partner: Illinois Institute of Technology - Chicago, IL Building-Integrated Heat & Moisture Exchange (SBIR Phase 2B) Lead Performer: Architectural Applications - Portland, Oregon Partner: Oregon State University - Corvallis, Oregon Inside the lab of Fraunhofer Center for Sustainable Energy Systems (CSE) in Boston, MA<br /> Photo Courtesy of Fraunhofer

  12. Search for new phenomena in events with at least three photons collected in pp collisions at √s = 8 TeV with the ATLAS detector

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aad, G.; Abbott, B.; Abdallah, J.; Abdinov, O.; Aben, R.; Abolins, M.; AbouZeid, O. S.; Abramowicz, H.; Abreu, H.; Abreu, R.; et al

    2016-04-01

    Results of a search for new phenomena in events with at least three photons are reported. Data from proton–proton collisions at a centre-of-mass energy of 8 TeV, corresponding to an integrated luminosity of 20.3 fb-1, were collected with the ATLAS detector at the LHC. The observed data are well described by the Standard Model. Limits at the 95 % confidence level on new phenomena are presented based on the rate of events in an inclusive signal region and a restricted signal region targeting the rare decay Z→3γ, as well as di-photon and tri-photon resonance searches. For a Standard Model Higgsmore » boson decaying to four photons via a pair of intermediate pseudoscalar particles (a), limits are found to be σ× BR (h→aa)× BR (a→γγ)2<10-3σSM for 10 GeV a< 62 GeV. Finally, limits are also presented for Higgs boson-like scalars (H) for mH> 125 GeV, and for a Z' decaying to three photons via Z'→a+γ→3γ. Additionally, the observed limit on the branching ratio of the Z boson decay to three photons is found to be BR(Z→3γ)<2.2×10-6, a result five times stronger than the previous result from LEP.« less

  13. Enhanced γ -Ray Emission from Neutron Unbound States Populated in β Decay

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tain, J. L.; Valencia, E.; Algora, A.; Agramunt, J.; Rubio, B.; Rice, S.; Gelletly, W.; Regan, P.; Zakari-Issoufou, A. -A.; Fallot, M.; et al

    2015-08-01

    Total absorption spectroscopy was used to investigate the β -decay intensity to states above the neutron separation energy followed by γ -ray emission in 87,88Br and 94Rb. Accurate results were obtained thanks to the careful control of systematic errors. An unexpectedly large γ intensity was observed in all three cases extending well beyond the excitation energy region where neutron penetration is hindered by low neutron energy. The γ branching as a function of excitation energy was compared to Hauser-Feshbach model calculations. For 87Br and 88Br the branching reaches 57% and 20% respectively, and could be explained as a nuclear structuremore » effect. Some of the states populated in the daughter can only decay through the emission of a large orbital angular momentum neutron with a strongly reduced barrier penetrability. In the case of neutron-rich 94Rb the observed 4.5% branching is much larger than the calculations performed with standard nuclear statistical model parameters, even after proper correction for fluctuation effects on individual transition widths. The difference can be reconciled introducing an enhancement of one order-of-magnitude in the photon strength to neutron strength ratio. An increase in the photon strength function of such magnitude for very neutron-rich nuclei, if it proved to be correct, leads to a similar increase in the (n, γ) cross section that would have an impact on r process abundance calculations.« less

  14. Direct Photolysis of Chlorophenols In Aqueous Solution By Ultraviolet Excilamps

    SciTech Connect (OSTI)

    Matafonova, Galina; Philippova, Natalya; Batoev, Valeriy

    2011-08-25

    The direct photolysis of 2-chlorophenol (2-CP), 4-chlorophenol (4-CP) and 2,4-dichlorophenol (2,4-DCP) in model aqueous solution was studied using UV XeBr (282 nm) and KrCl (222 nm) excilamps. The highest pseudo-first order rate constants and quantum yields were found for molecular form of 4-CP (at pH 2 and 5.7) and anionic forms of 2-CP and 2,4-DCP (at pH 11) when irradiated by XeBr excilamp. The maximum removal efficiency of molecular form of 2-CP and 2,4-DCP with the lowest UV dose of absorbed energy was observed using KrCl excilamp. On the contrary, the XeBr excilamp required the lowest dose ({approx}2 J{center_dot}cm{sup -2}) for complete degradation of molecular 4-CP and anionic 2-CP. The highest removal efficiency of anionic form of 4-CP (65%) was achieved when using KrCl excilamp.

  15. A=12C (68AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    68AJ02) (See Energy Level Diagrams for 12C) GENERAL: See also Table 12.7 [Table of Energy Levels] (in PDF or PS). Shell model: (KU56, PE56A, KU57A, ME60D, TA60L, WE60B, BA61N, TR61, NA63A, VI63A, AM64, CL64, GI64C, GI64D, NE64C, BA65E, CO65I, FA65C, NE65, GI66A, HA66F, VA66A, YO66A, CO67M, EV67A, KU67B, HI68A). Collective model: (BA59F, BR59M, CL61D, CL62G, GO62I, WA62, GO63G, BR64Z, VO64C, ST65C, UB65, UB65A, VO65A, BO66H, DA66G, DR66B, KR66A, BA67D, BO67D, BO67J, BR67, KR67, LA67F, LA67M,

  16. Development of neutron measurement in high gamma field using new nuclear emulsion

    SciTech Connect (OSTI)

    Kawarabayashi, J.; Ishihara, K.; Takagi, K.; Tomita, H.; Iguchi, T.; Naka, T.; Morishima, K.; Maeda, S.

    2011-07-01

    To precisely measure the neutron emissions from a spent fuel assembly of a fast breeder reactor, we formed nuclear emulsions based on a non-sensitized Oscillation Project with Emulsion tracking Apparatus (OPERA) film with AgBr grain sizes of 60, 90, and 160 nm. The efficiency for {sup 252}Cf neutron detection of the new emulsion was calculated to be 0.7 x 10{sup -4}, which corresponded to an energy range from 0.3 to 2 MeV and was consistent with a preliminary estimate based on experimental results. The sensitivity of the new emulsion was also experimentally estimated by irradiating with 565 keV and 14 MeV neutrons. The emulsion with an AgBr grain size of 60 nm had the lowest sensitivity among the above three emulsions but was still sensitive enough to detect protons. Furthermore, the experimental data suggested that there was a threshold linear energy transfer of 15 keV/{mu}m for the new emulsion, below which no silver clusters developed. Further development of nuclear emulsion with an AgBr grain size of a few tens of nanometers will be the next stage of the present study. (authors)

  17. Evaluation of potential performance additives for the advanced lithium bromide chiller

    SciTech Connect (OSTI)

    Reiner, R.H.; Del Cul, W.; Perez-Blanco, H.; Ally, M.R.; Zaltash, A.

    1991-04-01

    The effectiveness and stability of potential heat-and-mass transfer (performance) additives for an advanced lithium bromide (LiBr) chiller were evaluated in a series of experimental studies. These studies of additive effectiveness and stability were necessary because many currently used performance additives decompose at the high generator temperatures (220{degrees}C to 260{degrees}C) desired for this particular advanced LiBr chiller. For example, one common performance additive, 2-ethyl-l-hexanol (2EH), reacts with the corrosion inhibitor, lithium chromate (Li{sub 2}CrO{sub 4}), even at moderate generator temperatures ({ge}180{degrees}C). These stability problems can be mitigated by using less reactive corrosion inhibitors such as lithium molybdate (Li{sub 2}MoO{sub 4}) and by using more stable performance additives such as 1-heptanol (HEP) or 1H,1H,7H-dodecafluoro-1-heptanol (DFH). There seems to be a trade-off between additive stability and effectiveness: the most effective performance additives are not the most stable additives. These studies indicate that HEP or DFH may be effective additives in the advanced LiBr chiller if Li{sub 2}MoO{sub 4} is used as a corrosion inhibitor.

  18. Lithium bromide chiller technology in gas processing

    SciTech Connect (OSTI)

    Huey, M.A.; Leppin, D.

    1995-12-31

    Lithium Bromide (LiBr) Absorption Chillers have been in use for more than half a century, mainly in the commercial air conditioning industry. The Gas Research Institute and EnMark Natural Gas Company co-funded a field test to determine the viability of this commercial air conditioning technology in the gas industry. In 1991, a 10 MMCFC natural gas conditioning plant was constructed in Sherman, Texas. The plant was designed to use a standard, off-the-shelf chiller from Trane with a modified control scheme to maintain tight operating temperature parameters. The main objective was to obtain a 40 F dewpoint natural gas stream to meet pipeline sales specifications. Various testing performed over the past three years has proven that the chiller can be operated economically and on a continuous basis in an oilfield environment with minimal operation and maintenance costs. This paper will discuss how a LiBr absorption chiller operates, how the conditioning plant performed during testing, and what potential applications are available for LiBr chiller technology.

  19. Papers from U.S. Department of Energy Science Undergraduate Laboratory Internship Program (SULI) 2010

    SciTech Connect (OSTI)

    Not Available

    2011-06-22

    The solvation sphere of halides in water has been investigated using a combination of extended x-ray absorption fine structure (EXAFS) and x-ray absorption near-edge structure (XANES) analysis techniques. The results have indicated that I{sup -} and Br{sup -} both have an asymmetric, 8 water molecule primary solvation spheres. These spheres are identical, with the Br{sup -} sphere about .3 {angstrom} smaller than the I{sup -} sphere. This study utilized near-edge analysis to supplement EXAFS analysis which suffers from signal dampening/broadening due to thermal noise. This paper has reported on the solvation first sphere of I{sup -} and Br{sup -} in water. Using EXAFS and XANES analysis, strong models which describe the geometric configuration of water molecules coordinated to a central anion have been developed. The combination of these techniques has provided us with a more substantiated argument than relying solely on one or the other. An important finding of this study is that the size of the anion plays a smaller role than previously assumed in determining the number of coordinating water molecules. Further experimental and theoretical investigation is required to understand why the size of the anion plays a minor role in determining the number of water molecules bound.

  20. Effects of magnetization on fusion product trapping and secondary neutron spectra

    SciTech Connect (OSTI)

    Knapp, Patrick F.; Schmit, Paul F.; Hansen, Stephanie B.; Gomez, Matthew R.; Hahn, Kelly D.; Sinars, Daniel Brian; Peterson, Kyle J.; Slutz, Stephen A.; Sefkow, Adam B.; Awe, Thomas James; Harding, Eric; Jennings, Christopher A.; Desjarlais, M. P.; Chandler, Gordon A.; Cooper, Gary Wayne; Cuneo, Michael Edward; Geissel, Matthias; Harvey-Thompson, Adam James; Porter, John L.; Rochau, Gregory A.; Rovang, Dean C.; Ruiz, Carlos L.; Savage, Mark E.; Smith, Ian C.; Stygar, William A.; Herrmann, Mark

    2015-05-14

    In magnetizing the fusion fuel in inertial confinement fusion (ICF) systems, we found that the required stagnation pressure and density can be relaxed dramatically. This happens because the magnetic field insulates the hot fuel from the cold pusher and traps the charged fusion burn products. This trapping allows the burn products to deposit their energy in the fuel, facilitating plasma self-heating. Here, we report on a comprehensive theory of this trapping in a cylindrical DD plasma magnetized with a purely axial magnetic field. Using this theory, we are able to show that the secondary fusion reactions can be used to infer the magnetic field-radius product, BR, during fusion burn. This parameter, not ρR, is the primary confinement parameter in magnetized ICF. Using this method, we analyze data from recent Magnetized Liner InertialFusion experiments conducted on the Z machine at Sandia National Laboratories. Furthermore, we show that in these experiments BR ≈ 0.34(+0.14/-0.06) MG · cm, a ~ 14× increase in BR from the initial value, and confirming that the DD-fusion tritons are magnetized at stagnation. Lastly, this is the first experimental verification of charged burn product magnetization facilitated by compression of an initial seed magnetic flux.

  1. Effects of magnetization on fusion product trapping and secondary neutron spectra

    SciTech Connect (OSTI)

    Knapp, P. F.; Schmit, P. F.; Hansen, S. B.; Gomez, M. R.; Hahn, K. D.; Sinars, D. B.; Peterson, K. J.; Slutz, S. A.; Sefkow, A. B.; Awe, T. J.; Harding, E.; Jennings, C. A.; Desjarlais, M. P.; Chandler, G. A.; Cooper, G. W.; Cuneo, M. E.; Geissel, M.; Harvey-Thompson, A. J.; Porter, J. L.; Rochau, G. A.; and others

    2015-05-15

    By magnetizing the fusion fuel in inertial confinement fusion (ICF) systems, the required stagnation pressure and density can be relaxed dramatically. This happens because the magnetic field insulates the hot fuel from the cold pusher and traps the charged fusion burn products. This trapping allows the burn products to deposit their energy in the fuel, facilitating plasma self-heating. Here, we report on a comprehensive theory of this trapping in a cylindrical DD plasma magnetized with a purely axial magnetic field. Using this theory, we are able to show that the secondary fusion reactions can be used to infer the magnetic field-radius product, BR, during fusion burn. This parameter, not ρR, is the primary confinement parameter in magnetized ICF. Using this method, we analyze data from recent Magnetized Liner Inertial Fusion experiments conducted on the Z machine at Sandia National Laboratories. We show that in these experiments BR ≈ 0.34(+0.14/−0.06) MG · cm, a ∼ 14× increase in BR from the initial value, and confirming that the DD-fusion tritons are magnetized at stagnation. This is the first experimental verification of charged burn product magnetization facilitated by compression of an initial seed magnetic flux.

  2. Reaction product imaging

    SciTech Connect (OSTI)

    Chandler, D.W.

    1993-12-01

    Over the past few years the author has investigated the photochemistry of small molecules using the photofragment imaging technique. Bond energies, spectroscopy of radicals, dissociation dynamics and branching ratios are examples of information obtained by this technique. Along with extending the technique to the study of bimolecular reactions, efforts to make the technique as quantitative as possible have been the focus of the research effort. To this end, the author has measured the bond energy of the C-H bond in acetylene, branching ratios in the dissociation of HI, the energetics of CH{sub 3}Br, CD{sub 3}Br, C{sub 2}H{sub 5}Br and C{sub 2}H{sub 5}OBr dissociation, and the alignment of the CD{sub 3} fragment from CD{sub 3}I photolysis. In an effort to extend the technique to bimolecular reactions the author has studied the reaction of H with HI and the isotopic exchange reaction between H and D{sub 2}.

  3. Assessing Lanthanum-Bromide Detectors for Safeguards Applications

    SciTech Connect (OSTI)

    Gariazzo, Claudio Andres; Saavedra, Steven F; Smith, Steven E; Solodov, Alexander A

    2008-01-01

    Major detector technologies currently being used for gamma-ray spectroscopy in safeguards applications include systems based on sodium iodide (NaI), cadmium-zinc-telluride (CZT), cadmium-telluride (CdTe), and high-purity germanium (HPGe) crystals. Recently, a new scintillation detector based on a lanthanum bromide (LaBr3) crystal has become commercially available. The declared benefits of this new detector technology include higher resolution and improved efficiency compared with similarly configured NaI-based systems. Both detector systems offer the advantage of room-temperature operation. This paper describes the results of a study assessing the safeguards applicability and advantages for isotopic and quantitative analyses of uranium using the LaBr3-based detector, as well as an investigation into the general operating characteristics of the LaBr3-based detector. The results are compared with those from a widely used NaI-based detector system (Canberra's Inspector-1000 multichannel analyzer) operated under similar environmental conditions and hardware configuration, using commercially available software packages (NaIGEM and Genie-2000).

  4. Enhanced γ -Ray Emission from Neutron Unbound States Populated in β Decay

    SciTech Connect (OSTI)

    Tain, J. L.; Valencia, E.; Algora, A.; Agramunt, J.; Rubio, B.; Rice, S.; Gelletly, W.; Regan, P.; Zakari-Issoufou, A. -A.; Fallot, M.; Porta, A.; Rissanen, J.; Eronen, T.; Äystö, J.; Batist, L.; Bowry, M.; Bui, V. M.; Caballero-Folch, R.; Cano-Ott, D.; Elomaa, V. -V.; Estevez, E.; Farrelly, G. F.; Garcia, A. R.; Gomez-Hornillos, B.; Gorlychev, V.; Hakala, J.; Jordan, M. D.; Jokinen, A.; Kolhinen, V. S.; Kondev, F. G.; Martínez, T.; Mendoza, E.; Moore, I.; Penttilä, H.; Podolyák, Zs.; Reponen, M.; Sonnenschein, V.; Sonzogni, A. A.

    2015-08-01

    Total absorption spectroscopy was used to investigate the β -decay intensity to states above the neutron separation energy followed by γ -ray emission in 87,88Br and 94Rb. Accurate results were obtained thanks to the careful control of systematic errors. An unexpectedly large γ intensity was observed in all three cases extending well beyond the excitation energy region where neutron penetration is hindered by low neutron energy. The γ branching as a function of excitation energy was compared to Hauser-Feshbach model calculations. For 87Br and 88Br the branching reaches 57% and 20% respectively, and could be explained as a nuclear structure effect. Some of the states populated in the daughter can only decay through the emission of a large orbital angular momentum neutron with a strongly reduced barrier penetrability. In the case of neutron-rich 94Rb the observed 4.5% branching is much larger than the calculations performed with standard nuclear statistical model parameters, even after proper correction for fluctuation effects on individual transition widths. The difference can be reconciled introducing an enhancement of one order-of-magnitude in the photon strength to neutron strength ratio. An increase in the photon strength function of such magnitude for very neutron-rich nuclei, if it proved to be correct, leads to a similar increase in the (n, γ) cross section that would have an impact on r process abundance calculations.

  5. Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids

    SciTech Connect (OSTI)

    Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

    2012-03-14

    Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X? = Cl?, Br?) generates ethyl halides via halogen atom abstraction from FeXn3?n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ?0.05 M X?. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 0.5) 106 M?1 s?1) and with FeBr2+ (k = (3.0 0.5) 107 M?1 s?1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

  6. A water-processable organic electron-selective layer for solution-processed inverted organic solar cells

    SciTech Connect (OSTI)

    Chen, Dongcheng; Zhou, Hu; Cai, Ping; Sun, Shi; Ye, Hua; Su, Shi-Jian Cao, Yong

    2014-02-03

    A triazine- and pyridinium-containing water-soluble material of 1,1?,1?-(4,4?,4?-(1,3,5-triazine-2,4,6-triyl)tris(benzene-4,1-diyl)) tris(methylene)tripyridinium bromide (TzPyBr) was developed as an organic electron-selective layer in solution-processed inverted organic solar cells due to its strong anti-erosion capacity against non-polar organic solvents commonly used for the active layer. Ohmic-like contact with the adjacent active materials like fullerene derivatives is speculated to be formed, as confirmed by the work-function measurements with scanning Kelvin probe and ultraviolet photoelectron spectroscopy techniques. Besides, considering the deep highest occupied molecular orbital energy level of TzPyBr, excellent hole-blocking property of the electron-selective layer is also anticipated. The inverted organic photovoltaic devices based on the TzPyBr/ITO (indium tin oxide) bilayer cathode exhibit dramatically enhanced performance compared to the control devices with bare ITO as the cathode and even higher efficiency than the conventional type devices with ITO and Al as the electrodes.

  7. Association of brominated proteins and changes in protein expression in the rat kidney with subcarcinogenic to carcinogenic doses of bromate

    SciTech Connect (OSTI)

    Kolisetty, Narendrababu; Bull, Richard J.; Muralidhara, Srinivasa; Costyn, Leah J.; Delker, Don A.; Guo, Zhongxian; Cotruvo, Joseph A.; Fisher, Jeffrey W.; Cummings, Brian S.

    2013-10-15

    The water disinfection byproduct bromate (BrO{sub 3}{sup −}) produces cytotoxic and carcinogenic effects in rat kidneys. Our previous studies demonstrated that BrO{sub 3}{sup −} caused sex-dependent differences in renal gene and protein expression in rats and the elimination of brominated organic carbon in their urine. The present study examined changes in renal cell apoptosis and protein expression in male and female F344 rats treated with BrO{sub 3}{sup −} and associated these changes with accumulation of 3-bromotyrosine (3-BT)-modified proteins. Rats were treated with 0, 11.5, 46 and 308 mg/L BrO{sub 3}{sup −} in drinking water for 28 days and renal sections were prepared and examined for apoptosis (TUNEL-staining), 8-oxo-deoxyguanosine (8-oxoG), 3-BT, osteopontin, Kim-1, clusterin, and p-21 expression. TUNEL-staining in renal proximal tubules increased in a dose-related manner beginning at 11.5 mg BrO{sub 3}{sup −}/L in female rats and 46 mg/L in males. Increased 8-oxoG staining was observed at doses as low as 46 mg/L. Osteopontin expression also increased in a dose-related manner after treatment with 46 mg/L, in males only. In contrast, Kim-1 expression increased in a dose-related manner in both sexes, although to a greater extent in females at the highest dose. Clusterin and p21 expression also increased in a dose-related manner in both sexes. The expression of 3-BT-modified proteins only increased in male rats, following a pattern previously reported for accumulation of α-2{sub u}-globulin. Increases in apoptosis in renal proximal tubules of male and female rats at the lowest doses suggest a common mode of action for renal carcinogenesis for the two sexes that is independent of α-2{sub u}-globulin nephropathy. - Highlights: • Bromate induced nephrotoxicity in both male and female rats by similar mechanisms. • Apoptosis was seen in both male and female rats at the lowest doses tested. • Bromate-induced apoptosis correlated to 8-oxo-deoxyguanosine formation. • Bromate increased the level of 3-bromotyrosine-modified proteins in male rats only. • These data identify possible novel mechanisms for bromate-induced nephrotoxicity.

  8. Silver-halide/organic-composite structures: Toward materials with multiple photographic functionalities

    SciTech Connect (OSTI)

    Bringley, Joseph F. . E-mail: joseph.bringley@kodak.com; Rajeswaran, Manju; Olson, Leif P.; Liebert, Nancy M.

    2005-10-15

    We report the synthesis and structure of the novel silver-halide-based organic-inorganic hybrids Ag{sub 2}Br{sub 6}(PPD){sub 2}, Ag{sub 2}Br{sub 6}(CD-2){sub 2}.H{sub 2}O, Ag{sub 2}Br{sub 4}(TMBD), and Ag{sub 2}I{sub 6}(CD-2){sub 2}.H{sub 2}O. 1,4-phenylenediammonium hexabromodiargentate(I) [Ag{sub 2}Br{sub 6}(PPD){sub 2}] crystals are monoclinic (P2{sub 1}/n), with unit-cell dimensions, a=10.1915(3)A, b=7.7562(2)A, c=12.4340(5)A and {beta}=93.109(1){sup o}. N,N-diethyl-2-methyl-1,4-benzenediammonium hexabromodiargentate(I) monohydrate [Ag{sub 2}Br{sub 6}(CD-2){sub 2}.H{sub 2}O] crystals are monoclinic (space group P2{sub 1}/c) with a=10.8434(2)A, b=11.4293(2)A, c=14.3729(1)A, and {beta}=96.153(1){sup o}. N,N,N',N'-tetramethyl-1,4-benzenediammonium tetrabromodiargentate(I) [Ag{sub 2}Br{sub 4}(TMBD)] crystals are orthorhombic (space group Pbcn) with a=17.0030(6)A, b=6.6163(2)A, and c=15.9762(6)A. N,N-diethyl-2-methyl-1,4-benzenediammonium hexaiododiargentate(I) monohydrate, [Ag{sub 2}I{sub 6}(CD-2){sub 2}.H{sub 2}O], are monoclinic (C2/c), with unit-cell dimensions, a=21.4691(4)A, b=12.1411(2)A, c=14.3102(2)A, and {beta}=98.657(1){sup o}. The novel structures are members of a class of silver-halide-based organic-inorganic hybrids based upon the assembly of [Ag{sub a}X{sub b}]{sup n-} clusters and protonated organoamines in aqueous mineral acids. The clusters display short intracluster Ag-Ag distances, and computational methods are used to evaluate intracluster Ag-Ag bonding. The diverse stoichiometries and cluster connectivities observed suggest a rich compositional and structural chemistry based upon the general assembly method. We have extended the methodology to include a silver-halide-organoamonium chemistry in which the organic moiety is chosen to serve a specific photographic function and demonstrate the first examples of such materials. The methodology allows for the direct assembly of [Ag{sub a}X{sub b}]{sup n-} clusters with commercial photographic color developer molecules, and we show that development is repressed but can later be 'switched on' in a unique photographic scheme. The photographic properties of Ag{sub 2}Br{sub 6}(PPD){sub 2} are examined and show an extremely facile development rate owing to the fact that the developer molecules are within molecular proximity to the clusters. As a result of their molecular nature, we anticipate that such materials could enable conventional or completely new imaging technologies with very fast image access rates and very high resolution.

  9. Nuclear Data Sheets for A=77

    SciTech Connect (OSTI)

    Singh B.; Nica N.; Singh,B.; Nica,N.

    2012-05-01

    The experimental nuclear spectroscopic data for known nuclides of mass number 77 (Ni, Cu, Zn, Ga, Ge, As, Se, Br, Kr, Rb, Sr, Y) have been evaluated and presented together with adopted properties for levels and {gamma} rays. New high-spin data are available for {sup 77}Ga, {sup 77}Br and {sup 77}Kr. New precise single-particle transfer cross section data are available for {sup 77}Ge, {sup 77}As, {sup 77}Se and {sup 77}Br from eight different reactions (2009Ka06,2008Sc03); these data give information for occupancy of valence neutron orbitals in the ground states of target nuclides: {sup 76}Ge, {sup 76}Se and {sup 78}Se. No significant new data since the 1997 NDS for A = 77 (1997Fa12) have been reported for {sup 77}Rb and {sup 77}Sr. No data are yet available for excited states in {sup 77}Ni, {sup 77}Cu and {sup 77}Y. Level schemes from the radioactive decays of {sup 77}Ni to {sup 77}Cu and {sup 77}Y to {sup 77}Sr are unknown, while those for the decays of {sup 77}Cu to {sup 77}Zn and {sup 77}Ga to {sup 77}Ge are incomplete. Detailed gamma-ray data for {sup 77}Ge from thermal-neutron capture in {sup 76}Ge, together with extensive gamma-ray data from {sup 77}Ge decay to {sup 77}As have become available from 2012Me04. This work benefited from earlier evaluations (1997Fa12,1989Fa07,1980Si05,1973Ur02) of A = 77 nuclides, however, the data presented here supersede those in above evaluations.

  10. Geophysical features of major structural and lithostratigraphic elements in the southeastern United States: An overview

    SciTech Connect (OSTI)

    Costain, J.K.; Coruh, C. (Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States). Dept. of Geological Sciences)

    1993-03-01

    In the Alleghany Plateau and Valley and Ridge provinces, the quality of shallow and deep vibroseis reflection seismic data acquired where carbonate rocks do not crop out at the surface is generally excellent for depths up to 10 km. One interpretation of heat flow data from granitoids that are exposed east of the central Piedmont is that heat-producing crust is tectonically truncated at a depth of ca. 8 km. Seismic data over the Blue Ridge (BR) and Inner Piedmont (IP) from northwestern SC to central VA image the upward ramping (to the northwest) of the BR master decollement over a distance of at least 600 km. Strikingly similar seismic signatures near this ramp are interpreted to be from thrust nappes composed of an Early Paleozoic( ) volcanic( ) protolith. Similar signatures but from an apparently less deformed protolith have been obtained from the IP in SC. New reprocessing and interpretation of a regional seismic line in VA indicate that the easternmost extent of Paleozoic shelf strata is not far east of the surface exposure of the BR-IP boundary. Large antiforms have been imaged in central VA, COCORP Lines 5 (Kiokee antiform), and Line 8 (beneath the Coastal Plain). Eastward-dipping reflections have been recorded beneath the Atlantic Coastal Plain from VA to GA. Reflections from Coastal Plain sediments are generally excellent. Faulted sediments of Cretaceous and younger age have been clearly imaged on reflection data in VA and SC. In some cases, these faults are upward continuations of fault-bounded Mesozoic rift basins. In the James River seismic zone, there is a good correlation between hypocenters and the roof of the antiform and structures above that are imaged in seismic reflection sections. In other areas of the southeastern US, the seismicity is more diffuse; however, it suggests that the Hydroseismicity hypothesis might be a viable trigger mechanism for intraplate earthquakes.

  11. The liquid surface of chiral ionic liquids as seen from molecular dynamics simulations combined with intrinsic analysis

    SciTech Connect (OSTI)

    Lísal, Martin

    2013-12-07

    We present molecular-level insight into the liquid/gas interface of two chiral room-temperature ionic liquids (RTILs) derived from 1-n-butyl-3-methylimidazolium bromide ([bmim][Br]); namely, (R)-1-butyl-3-(3-hydroxy-2-methylpropyl)imidazolium bromide (hydroxypropyl) and 1-butyl-3-[(1R)-nopyl]imidazolium bromide (nopyl). We use our currently developed force field which was validated against the experimental bulk density, heat of vaporization, and surface tension of [bmim][Br]. The force field for the RTILs adopts the Chemistry at Harvard Molecular Mechanics (CHARMM) parameters for the intramolecular and repulsion-dispersion interactions along with the reduced partial atomic charges based on ab initio calculations. The net charges of the ions are around ±0.8e, which mimic the anion to cation charge transfer and many-body effects. Molecular dynamics simulations in the slab geometry combined with the intrinsic interface analysis are employed to provide a detailed description of the RTIL/gas interface in terms of the structural and dynamic properties of the interfacial, sub-interfacial, and central layers at a temperature of 300 K. The focus is on the comparison of the liquid/gas interface for the chiral RTILs with the interface for parent [bmim][Br]. The structure of the interface is elucidated by evaluating the surface roughness, intrinsic atomic density profiles, and orientation ordering of the cations. The dynamics of the ions at the interfacial region is characterized by computing the survival probability, and normal and lateral self-diffusion coefficients in the layers.

  12. Photo-assisted etching of silicon in chlorine- and bromine-containing plasmas

    SciTech Connect (OSTI)

    Zhu, Weiye; Sridhar, Shyam; Liu, Lei; Hernandez, Eduardo; Donnelly, Vincent M. Economou, Demetre J.

    2014-05-28

    Cl{sub 2}, Br{sub 2}, HBr, Br{sub 2}/Cl{sub 2}, and HBr/Cl{sub 2} feed gases diluted in Ar (50%50% by volume) were used to study etching of p-type Si(100) in a rf inductively coupled, Faraday-shielded plasma, with a focus on the photo-assisted etching component. Etching rates were measured as a function of ion energy. Etching at ion energies below the threshold for ion-assisted etching was observed in all cases, with Br{sub 2}/Ar and HBr/Cl{sub 2}/Ar plasmas having the lowest and highest sub-threshold etching rates, respectively. Sub-threshold etching rates scaled with the product of surface halogen coverage (measured by X-ray photoelectron spectroscopy) and Ar emission intensity (7504?). Etching rates measured under MgF{sub 2}, quartz, and opaque windows showed that sub-threshold etching is due to photon-stimulated processes on the surface, with vacuum ultraviolet photons being much more effective than longer wavelengths. Scanning electron and atomic force microscopy revealed that photo-etched surfaces were very rough, quite likely due to the inability of the photo-assisted process to remove contaminants from the surface. Photo-assisted etching in Cl{sub 2}/Ar plasmas resulted in the formation of 4-sided pyramidal features with bases that formed an angle of 45 with respect to ?110? cleavage planes, suggesting that photo-assisted etching can be sensitive to crystal orientation.

  13. Bridgman Growth of Large SrI2:Eu2+ Single Crystals: A High-performance Scintillator for Radiation Detection Applications

    SciTech Connect (OSTI)

    Boatner, Lynn A; Ramey, Joanne Oxendine; Kolopus, James A; Hawrami, Rastgo; Higgins, William; Van Loef, Edgar; Glodo, J.; Shah, Kanai; Bhattacharya, P.; Tupitsyn, E; Groza, Michael; Burger, Arnold

    2013-01-01

    Single-crystal strontium iodide (SrI2) doped with relatively high levels (e.g., 3 - 6 %) of Eu2+ exhibits characteristics that make this material superior, in a number of respects, to other scintillators that are currently used for radiation detection. Specifically, SrI2:Eu2+ has a light yield that is significantly higher than LaBr3:Ce3+ -a currently employed commercial high-performance scintillator. Additionally, SrI2:Eu2+ is characterized by an energy resolution as high as 2.6% at the 137Cs gamma-ray energy of 662 keV, and there is no radioactive component in SrI2:Eu2+ - unlike LaBr3:Ce3+ that contains 138La. The Ce3+-doped LaBr3 decay time is, however, faster (30 nsec) than the 1.2 sec decay time of SrI2:Eu2+. Due to the relatively low melting point of strontium iodide (~515 oC), crystal growth can be carried out in quartz crucibles by the vertical Bridgman technique. Materials-processing and crystal-growth techniques that are specific to the Bridgman growth of europium-doped strontium iodide scintillators are described here. These techniques include the use of a porous quartz frit to physically filter the molten salt from a quartz antechamber into the Bridgman growth crucible and the use of a bent or bulb grain selector design to suppress multiple grain growth. Single crystals of SrI2:Eu2+ scintillators with good optical quality and scintillation characteristics have been grown in sizes up to 5.0 cm in diameter by applying these techniques. Other aspects of the SrI2:Eu2+ crystal-growth methods and of the still unresolved crystal-growth issues are described here.

  14. "Name","Title","Contact","Alternate Emails","Location","Manager Group Name"

    Office of Scientific and Technical Information (OSTI)

    Name","Title","Contact","Alternate Emails","Location","Manager Group Name" "","","","","","" "","","","","","" "Abbott, Kim","National Environmental Policy Act Document Manager","(510) 486-7909","kim.abbott@bso.science.doe.gov","Berkeley Site Office<br />

  15. Hole Blocking, Electron Transporting and Window Layer for Optimized

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Culn(1-x)GaxSe2 Solar Cells - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Advanced Materials Advanced Materials Find More Like This Return to Search Hole Blocking, Electron Transporting and Window Layer for Optimized Culn(1-x)GaxSe2 Solar Cells Brookhaven National Laboratory Contact BNL About This Technology <br type="_moz" /> A schematic illustration of an exemplary embodiment of the disclosed CIGS based solar cell, with a quasi-2-dimensional electron

  16. INTERNATIONAL DEVELOPMENT OF ENERGY STORAGE INTEROPERABILITY TEST

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DEVELOPMENT OF ENERGY STORAGE INTEROPERABILITY TEST PROTOCOLS FOR PHOTOVOLTAIC INTEGRATION David Rosewater 1 , Jay Johnson 1 *, Maurizio Verga 2 , Riccardo Lazzari 2 , Christian Messner 3 , Roland Bründlinger 3 , Kathan Johannes 3 , Jun Hashimoto 4 , Kenji Otani 4 * Corresponding Author 1 Sandia National Laboratories P.O. Box 5800 MS1033 Albuquerque, NM 87185-1033 USA Phone: +1 505-284-9586 Fax: +1 505-844-3952 jjohns2@sandia.gov 2 Ricerca sul Sistema Energetico-RSE S.P.A. Via R. Rubattino 54

  17. Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage/Separation | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage/Separation Previous Next List Weigang Lu, Daqiang Yuan, Dan Zhao, Christine Inge Schilling, Oliver Plietzsch, Thierry Muller, Stefan Bräse, Johannes Guenther, Janet Blümel, Rajamani Krishna, Zhen Li, and Hong-Cai Zhou, Chem. Mater., 2010, 22 (21), pp 5964-5972 DOI: 10.1021/cm1021068 Abstract Image Abstract:

  18. Microsoft Word - Ce-CH3X ms-revised.doc

    Office of Scientific and Technical Information (OSTI)

    
 1
 Hydrogen for X-group exchange in CH 3 X, X = Cl, Br, I, OMe and NMe 2 by Monomeric [1,2,4-(Me 3 C) 3 C 5 H 2 ] 2 CeH: Experimental and Computational Support for a Carbenoid Mechanism Evan L. Werkema a , Richard A. Andersen* a , Ahmed Yahia b , Laurent Maron* b and Odile Eisenstein* c a) Department of Chemistry, University of California, Berkeley, California 94720- 1460, b) Université de Toulouse, INSA, UPS, LPCNO, 135 avenue de Rangueil, 31077 Toulouse, France, and CNRS, 31077

  19. Theoretical Studies in Chemical Kinetics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studies in Chemical Kinetics ^ ^ iCi| under AEC Contract A T (30-1)-3780 " ■ ' Annual Report (1970) Principal In-vestigator: Martin Karpins Institution: Harvard University The research performed under this contract can best be sunmarized under several headings. (a) Alkali-Halideg Alkali-Halide (MX^ M*X*) Exchange Reactions. This project is being continued. A careful study of certain parameters obtained from alkali-halide crystals and used in the first surface for the KCl, NaBr were not

  20. Tools_Equipment under 10K RO 23_120213.xlsx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Other Government Furnished Property (GFP) / Equipment 1 RO BARCODE DESCRIPTION MANUF. MODEL SN COST BLDG ROOM INVT_DATE 23 0000032497 THERMAL LABELING SYS BRADY WORLDWIDE TLS2200 BPTLS901644924 $0.00 28 119 24-Sep-13 23 F13412 PWR SUPPLY & READ BR BROOKS 5878 881OHC025872 $0.00 94 01 24-Sep-13 23 0000032498 THERMAL LABELING SYS BRADY WORLDWIDE TLS2200 BPTLS902745018 $0.00 17 106 24-Sep-13 23 0000106857 RECIRCULATOR POLYSCI POLY SCIENCE N0691883 G52197 $0.00 83 242 4-Oct-13 23 0000021812

  1. Web-based DOE/ORNL Heat Pump Design Model Released | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Web-based DOE/ORNL Heat Pump Design Model Released Web-based DOE/ORNL Heat Pump Design Model Released May 2, 2016 - 12:28pm Addthis The new Heat Pump Design Model web interface, developed by Oak Ridge National Laboratory, expands the tool’s online accessibility. <br /> Credit: Oak Ridge National Laboratory The new Heat Pump Design Model web interface, developed by Oak Ridge National Laboratory, expands the tool's online accessibility. Credit: Oak Ridge National Laboratory This article

  2. EnergyPlus Is Going Residential | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Is Going Residential EnergyPlus Is Going Residential March 23, 2016 - 2:16pm Addthis RESNET’s decision to use EnergyPlus for the central implementation of HERS Index is part of a broad initiative aimed at enhancing consistency of HERS Index scores. <br />Credit: RESNET, DOE. RESNET's decision to use EnergyPlus for the central implementation of HERS Index is part of a broad initiative aimed at enhancing consistency of HERS Index scores. Credit: RESNET, DOE. Amir Roth, Ph.D. Amir Roth,

  3. EnergyPlus | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EnergyPlus EnergyPlus Architecture firm Skidmore, Owings & Merrill (SOM) used EnergyPlus to design a new 380,000 square foot federal office building in West Virginia. The building has an advanced ventilated double facade and uses low-energy underfloor air distribution and is designed to achieve energy savings of 30% below code.<br /> Image credit: Jason Kirkpatrick, SOM. Architecture firm Skidmore, Owings & Merrill (SOM) used EnergyPlus to design a new 380,000 square foot federal

  4. What You Missed: Tuesday Talk on The National Medals Laureates of Science,

    Energy Savers [EERE]

    What Will Be This Year's vA3C? What Will Be This Year's vA3C? September 22, 2015 - 1:11pm Addthis Watch a pre-recorded movie of the OpenStudio view_data measure, which uses vA3C to display time series data, here hourly outside surface temperature. Movie credit: Dan Macumber, NREL Thornton Tomasetti’s CORE Studio used vA3C and Pollination (another hackathon product), to develop the multi-dimensional design space exploration tool DesignExplorer. <br />Image credit: Mostapha Roudsari and

  5. Nitride Stabilized Core-Shell Nanoparticles - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitride Stabilized Core-Shell Nanoparticles Brookhaven National Laboratory Contact BNL About This Technology <br type="_moz" /> (A) Comparison of surface strain versus predicted binding energy of oxygen (BE-O) on the Pt<sub>2</sub>MLNi<sub>4</sub>N and Pt nanoparticle models with ~1.7 nm. (B) Pt specific activity against BE-O on PtNiN/C and Pt/C. (C) Schematic of the inner Pt diffusion process to the defective sites at the vertex during cycling in the

  6. OBSERVATION O F T H E FORBIDDEN MAGNETIC DIPOLE TRANSITION 62P%+72P%IN ATOMIC THALLIUM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GROVE C OAL D EGAS CEDAR COVE COAL D EGAS BLU E CREEK COAL DEGAS BR OOKWOOD C OAL D EGAS ST AR ROBIN SONS BEND COAL D EGAS BLU FF COR INNE MOU NDVILLE COAL D EGAS BLU EGU T CR EEK WH ITE OAK CREEK COAL DEGAS BEAVERT ON BLU FF FAYETTE W SN EAD S CREEK SPLU NGE PAR HAM N MUSGR OVE CR EEK MCCRAC KEN MOU NTAIN DAVIS C HAPEL BAC ON BLOOMING GROVE MT Z ION FAIRVIEW JASPER BLOWHORN CREEK MAPLE BRAN CH KEN NEDY COAL F IRE CR EEK MCGEE LAKE SILOAM MILLPOR T FERNBANK DAVIS C HAPEL NE DETROIT E BEANS F

  7. Nuclear Data Sheets for A = 91

    SciTech Connect (OSTI)

    Baglin, Coral M.

    2013-10-15

    Experimental nuclear structure and decay data for all known A=91 nuclides (As, Se, Br, Kr, Rb, Sr, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd) have been evaluated. This evaluation, covering data received by 1 September 2013, supersedes the 1998 evaluation by C. M. Baglin published in Nuclear Data Sheets86, 1 (1999) (15 December 1998 literature cutoff), and subsequent evaluations by C. M. Baglin added to the ENSDF database for Kr, Sr and Zr (29 December 2000 literature cutoff) and by B. Singh for {sup 91}Tc (6 November 2000 literature cutoff)

  8. Nuclear Data Sheets for A=85

    SciTech Connect (OSTI)

    Singh, Balraj; Chen, Jun

    2014-02-01

    Evaluated experimental data are presented for 13 known nuclides of mass 85 (Zn, Ga, Ge, As, Se, Br, Kr, Rb, Sr, Y, Zr, Nb, Mo). Since the previous 1990 evaluation of A=85, {sup 85}Zn, {sup 85}Ga, {sup 85}Ge and {sup 85}nuclides are newly added here. Excited state data for {sup 85}Se, {sup 85}Zr have become available from radioactive decay and inbeam ?ray studies. New and improved highspin data are available for {sup 85}Br, {sup 85}Kr, {sup 85}Rb, {sup 85}Y, {sup 85}Nb and {sup 85}Mo. New direct and precise measurement of atomic masses of {sup 85}Ge, {sup 85}As, {sup 85}Se, {sup 85}Br, {sup 85}Rb, {sup 85}Zr, {sup 85}Nb and {sup 85}Mo have greatly improved the landscape of ? decayQ values and separation energies in this mass region. In spite of extensive experimental work on the isobaric nuclei of this mass chain several deficiencies remain. No excited states are known in {sup 85}Zn, {sup 85}Ga, {sup 85}As. Only a few excited state are assigned in {sup 85}Ge from {sup 85}Ga ? decay. From radioactivity studies, the decay schemes of {sup 85}Zn and {sup 85}Mo are not known, and those for {sup 85}Ga, {sup 85}Ge, {sup 85}As and 10.9s isomer of {sup 85}Zr are incomplete. Level lifetimes are not known for excited states in {sup 85}Se, {sup 85}Br, {sup 85}Nb and {sup 85}Mo. The {sup 85}Tc nuclide has not been detected in fragmentation experiments at GANIL, alluding to its unbound nature for proton emission. The {sup 85}Kr, {sup 85}Rb, {sup 85}Sr, and {sup 85}Y nuclides remain the most extensively studied from many different reactions and decays. The evaluation of A=85 nuclides has been done after a span of 23 years, thus includes an extensive amount of new data for almost each nuclide. This work supersedes the data for A=85 nuclides presented in earlier full NDS publication by J. Tepel in 1980Te04 and a later one published in an update mode by H. Sievers in 1991Si01.

  9. Nuclear Data Sheets for A = 92

    SciTech Connect (OSTI)

    Baglin, Coral M.

    2012-10-15

    Nuclear structure and decay data pertaining to all nuclides with mass number A = 92 (As, Se, Br, Kr, Rb, Sr, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd) have been compiled and evaluated, and incorporated into the ENSDF data file. All literature available by 15 September 2012 has been considered. This evaluation supersedes the previous publication for this mass chain (Coral M. Baglin, Nuclear Data Sheets 91, 423 (2000) (November 2000 cutoff date)), and subsequent unpublished reevaluations by C.M. Baglin for {sup 92}Kr (January 2004 literature cut-off) and {sup 92}Sr (August 2003 literature cut-off).

  10. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    al1.pdf filesize 544.75 kB Version 1 date 6-10 July 1998 Downloaded 55 times Category Energy Security, Manual, Photovoltaic, Renewable Energy, Solar Energy, Technology Validation author D.L. King, W.E. Boyson, B.R. Hansen, and W.I. Bower, Sandia event 2nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion location Vienna, Austria Accurate measurements of broadband (full spectrum) solar irradiance are fundamental to the successful implementation of solar power systems, both

  11. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    al.pdf filesize 544.75 kB Version 1 date 6-10 July 1998 Downloaded 89 times Category Energy Security, Manual, Photovoltaic, Renewable Energy, Solar Energy, Technology Validation event 2nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion location Vienna, Austria year 1998 author D.L. King, W.E. Boyson, B.R. Hansen, W.I. Bower Thousands of photovoltaic systems, large and small, are now being installed worldwide. As a result, there is a growing demand for inexpensive devices

  12. Heating and Cooling with Mini Splits in the Northeast

    Energy Savers [EERE]

    Energy Heat Pump Water Heater using Solid-State Energy Converters Heat Pump Water Heater using Solid-State Energy Converters Sheetak will work on developing a full scale prototype of its low cost heat pump water heater. These solid state heat pumping elements can be implemented in low cost manner which have the potential to dramatically change the way in which he heat water.<BR />Image: Sheetak Sheetak will work on developing a full scale prototype of its low cost heat pump water

  13. Videos | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Videos Videos <h3>Better Buildings for a Better Future</h3> Learn how Better Buildings Neighborhood Program partners started bringing the benefits of energy upgrades to their neighborhoods.<br /> <a target="_blank" href="https://www.youtube.com/watch?v=A8auVGOfn9E">Watch the video</a> | <a href="http://energy.gov/eere/better-buildings-neighborhood-program/better-buildings-neighborhood-program-better-future-text"

  14. 2015 Paris Climate Conference - COP21 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2015 Paris Climate Conference - COP21 2015 Paris Climate Conference - COP21 <strong><span style="color:#666;">Mission Innovation: 20 countries pledged to double clean energy R&D</span></strong><br> At the 2015 Paris Climate Conference, world leaders announced <a href="http://mission-innovation.net/">Mission Innovation</a>—an effort to dramatically accelerate clean energy investment in the next five years. Mission Innovation:

  15. TO

    Office of Legacy Management (LM)

    J. fhith, Chief, TO : Hew Pork Operations Branoh, D*TE: July 10, 1951 ! I FROM : 'Russell H. BdcL, Chief, Research Service Branch, Berkeley &~'?A - wp+=q - 'I s , This Br'ea desires 500 pounds of U03 for research work on the TTA /: axtraotion process where the subjeot materisl will be spiked with Pu to make a synthetio solution for pilot plant runs. , It is desired that the material be obtained from the Msllinckrodt Chemical Works.similar to that prooured for this Area in 1950 on SR-1649

  16. Vehicle Testing and Integration Facility; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    2015-03-02

    Engineers at the National Renewable Energy Laboratory’s (NREL’s) Vehicle Testing and Integration Facility (VTIF) are developing strategies to address two separate but equally crucial areas of research: meeting the demands of electric vehicle (EV) grid integration and minimizing fuel consumption related to vehicle climate control. Dedicated to renewable and energy-efficient solutions, the VTIF showcases technologies and systems designed to increase the viability of sustainably powered vehicles. NREL researchers instrument every class of on-road vehicle, conduct hardware and software validation for EV components and accessories, and develop analysis tools and technology for the Department of Energy, other government agencies, and industry partners.<br/>

  17. Sol-gel process of fluoride and fluorobromide materials

    SciTech Connect (OSTI)

    Poncelet, O.; Guilment, J.; Paz-Pujalt, G.

    1996-12-31

    The alkoxides M(OR{sub x}){sub n} wherein M is an alkaline-earth or rare-earth and OR{sub X} is a fluoroalkoxo or bromoalkoxo group exhibit the properties to form pure fluoride materials by hydrolysis at room temperature. Using this property, the authors synthesized pure barium and europium fluoride and pure alkaline-earth bromide. The hydrolysis of a heteroleptic species, Ba(OCH{sub 2}CH{sub 2}Br)[OCH(CF{sub 3}){sub 2}] allowed pure and crystalline BaFBr materials to be obtained at room temperature.

  18. Redox shuttles for lithium ion batteries

    DOE Patents [OSTI]

    Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

    2016-03-22

    An electrolyte may include compounds of general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y, and at least one of R.sup.8, R.sup.9, R.sup.10, and R.sup.11 is other than H.

  19. Redox shuttles for lithium ion batteries

    DOE Patents [OSTI]

    Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

    2014-11-04

    Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.

  20. Rotary-Cooled Solid-State Lighting - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Energy Efficiency Building Energy Efficiency Find More Like This Return to Search Rotary-Cooled Solid-State Lighting Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (1,819 KB) <em>A 100 W RCSSL luminaire used for high-bay lighting. The rotating heat-sink-impeller provides low thermal resistance in a small overall luminaire size.</em><br type="_moz" /> A 100 W RCSSL luminaire used for high-bay

  1. PV Derived Data for Predicting Performance; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Marion, Bill

    2015-09-14

    A method is described for providing solar irradiance data for modeling PV performance by using measured PV performance data and back-solving for the unknown direct normal irradiance (DNI) and diffuse horizontal irradiance (DHI), which can then be used to model the performance of PV systems of any size, PV array tilt, or PV array azimuth orientation. Ideally situated for using the performance data from PV modules with micro-inverters, the PV module operating current is used to determine the global tilted irradiance (GTI), and a separation model is then used to determine the DNI and DHI from the GTI.<br/>

  2. Reaction Mechanism of Oxygen Atoms with Unsaturated Hydrocarbons by the Crossed-Molecular-Beams Method

    DOE R&D Accomplishments [OSTI]

    Buss, R. J.; Baseman, R. J.; Guozhong, H.; Lee, Y. T.

    1982-04-01

    From a series of studies of the reaction of oxygen atoms with unsaturated hydrocarbons using the crossed molecular beam method, the dominant reaction mechanisms were found to be the simple substitution reactions with oxygen atoms replacing H, Cl, Br atom or alkyl groups. Complication due to secondary reaction was avoided by carrying out experiments under single collisions and observing primary products directly. Primary products were identified by measuring the angular and velocity distributions of products at all the mass numbers which could be detected by the mass spectrometer, and from comparison of these distributions, applying the requirement of energy and momentum conservation.

  3. Near-IR spectroscopic monitoring of CLASS I protostars: Variability of accretion and wind indicators

    SciTech Connect (OSTI)

    Connelley, Michael S.; Greene, Thomas P.

    2014-06-01

    We present the results of a program that monitored the near-IR spectroscopic variability of a sample of 19 embedded protostars. Spectra were taken on time intervals from 2 days to 3 yr, over a wavelength range from 0.85 ?m to 2.45 ?m, for 4-9 epochs of observations per target. We found that the spectra of all targets are variable and that every emission feature observed is also variable (although not for all targets). With one exception, there were no drastic changes in the continua of the spectra, nor did any line completely disappear, nor did any line appear that was not previously apparent. This analysis focuses on understanding the connection between accretion (traced by H Br ? and CO) and the wind (traced by He I, [Fe II], and sometimes H{sub 2}). For both accretion and wind tracers, the median variability was constant versus the time interval between observations; however, the maximum variability that we observed increased with the time interval between observations. Extinction is observed to vary within the minimum sampling time of 2 days, suggesting extinguishing material within a few stellar radii at high disk latitudes. The variability of [Fe II] and H{sub 2} were correlated for most (but not all) of the 7 young stellar objects showing both features, and the amplitude of the variability depends on the veiling. Although the occurrence of CO and Br ? emission are connected, their variability is uncorrelated, suggesting that these emissions originate in separate regions near the protostar (e.g., disk and wind). The variability of Br ? and wind tracers were found to be positively correlated, negatively correlated, or uncorrelated, depending on the target. The variability of Br ?, [Fe II], and H{sub 2} always lies on a plane, although the orientation of the plane in three dimensions depends on the target. While we do not understand all interactions behind the variability that we observed, we have shown that spectroscopic variability is a powerful tool toward understanding the star formation process.

  4. Aerogel Insulation: The Materials Science of Empty Space | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Aerogel Insulation: The Materials Science of Empty Space Aerogel Insulation: The Materials Science of Empty Space October 11, 2013 - 10:11am Addthis Aspen Aerogel's innovative insulation material works well under very cold and very hot temperatures. Here, the insulation is held over a flame.<br/> <em>Photo Courtesy of Aspen Aerogels</em> Aspen Aerogel's innovative insulation material works well under very cold and very hot temperatures. Here, the insulation is held

  5. Defect propagation in one-, two-, and three-dimensional compounds doped by

    Office of Scientific and Technical Information (OSTI)

    magnetic atoms (Journal Article) | SciTech Connect Defect propagation in one-, two-, and three-dimensional compounds doped by magnetic atoms Citation Details In-Document Search Title: Defect propagation in one-, two-, and three-dimensional compounds doped by magnetic atoms Inelastic neutron scattering experiments were performed to study manganese(II) dimer excitations in the diluted one-, two-, and three-dimensional compounds CsMnxMg1-xBr3, K2MnxZn1-xF4, and KMnxZn1-xF3 (x≤0.10),

  6. Europium-doped barium bromide iodide

    SciTech Connect (OSTI)

    Gundiah, Gautam; Hanrahan, Stephen M.; Hollander, Fredrick J.; Bourret-Courchesne, Edith D.

    2009-10-21

    Single crystals of Ba0.96Eu0.04BrI (barium europium bromide iodide) were grown by the Bridgman technique. The title compound adopts the ordered PbCl2 structure [Braekken (1932). Z. Kristallogr. 83, 222-282]. All atoms occupy the fourfold special positions (4c, site symmetry m) of the space group Pnma with a statistical distribution of Ba and Eu. They lie on the mirror planes, perpendicular to the b axis at y = +-0.25. Each cation is coordinated by nine anions in a tricapped trigonal prismatic arrangement.

  7. Residential CO2 Heat Pump Water Heater | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Heat Pump Water Heater Residential CO2 Heat Pump Water Heater CO2 Heat Pump Water Heater Prototype<br /> Credit: Oak Ridge National Lab CO2 Heat Pump Water Heater Prototype Credit: Oak Ridge National Lab Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partner: General Electric Appliances - Louisville, KY DOE Funding: $2,147,000 Cost Share: Provided by CRADA partner Project Term: October 1, 2009 - September 30, 2015 Project Objective This project is developing a carbon

  8. untitled

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ac cc co om mp plliis sh hm me en nt ts s A Ac cc co om mp plliis sh hm me en nt ts s 2 20 00 06 6 2 20 00 06 6 F Fe eb br ru ua ar ry y * * 2 20 00 06 6 THE LITTLE ROBOT THAT COULD . . . Meet the Sandia robot that helped secure a radiation source at White Sands Missile Range. Details on page 5. L La ab bs s L La ab bs s Sandia National Laboratories W elcome to this year's edition of the annual Lab News Labs Accomplishments. Throughout this 16-page document, you'll find a resounding affirmation

  9. Heat Pump Water Heater using Solid-State Energy Converters | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Water Heater using Solid-State Energy Converters Heat Pump Water Heater using Solid-State Energy Converters Sheetak will work on developing a full scale prototype of its low cost heat pump water heater. These solid state heat pumping elements can be implemented in low cost manner which have the potential to dramatically change the way in which he heat water.<BR />Image: Sheetak Sheetak will work on developing a full scale prototype of its low cost heat pump water heater. These

  10. CAPTAIN

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MCKEESPORT COR AOPOLIS-MOON REDHAW ST. CLAIR SC ROGGSFIELD FRANKLIN -OAK FOREST RIMERSBURG RENNERD AL E GREENVILL E PAT MOS CRABTR EE BLAC K ASH ROYALT ON N BAKERSTOWN QUEEN ROU GH RUN LUCAS BLAC K H ILL CRESTON WAT TSVILLE WADSWORTH -NORT H OAKLAN D HOM EWORT H UNIT Y ESSELBRUN ALAMED A PAR K-CROOKED RU CHERRY GROVE FRENC HTOWN ST EWART RUN MILL C REEK GLENF IELD-MOU NT NEBO HICKORY E HARRISVILLE E LEST ER GRIGGS CORNERS EN GLAN D WEST VIL LE LAKE BAILEY LAKE OAKFORD BR UNSWICK N HOR ACE

  11. UNITED STATES ENERGY RESEARCH AND OEVELOPMENTADhllNlSTRATiON

    Office of Legacy Management (LM)

    OEVELOPMENTADhllNlSTRATiON ALBUQUERQUE OPERATIONS OFFICE P.O. eox 14cc ALBUQUERQUE, NEW MEXICO 87115 P. C. Leahy, Chief, Real Estate & Maintenance Management Br., BRA0 .-- x*' L-l--- IUDIOACTIVE COlTlIA2~~TION CLEARAXE REPORT FOR THE BBRLIXGTOIU ERRA F.ACILTTY The follok,g information is furnished in response to your verbal request. 1. 2. 3. 4. Measureme2+s for ionizing rad5atLon and radioactive contamina- . . tron ha-~ _ 3een made In all Burlington E,R?M FacLlity buildings where

  12. ft. n. Both, Ohtef, RarourQb DWrion,Oak Ridgo

    Office of Legacy Management (LM)

    _ ,' .' ft. n. Both, Ohtef, RarourQb DWrion,Oak Ridgo hwt 2% w9 s. P. Morgan, Aar' t, Pimotor; Produotlon Dirirloa, i BY00 sniwm! OP Zr T~BIDm 1 . It ir axpeat tbt 4alivery of @air wteri8.l will be maa on orbaforo leptcmwrl, lg4g. Idantifioatioii my&ml "2416" haa been wr@md to thlr ahip nent and all related dauuuentr, aat ma&or Watlr Br n&R 1 ::_,, : ; .,. . . . ,~,-,.", :;> .

  13. l[nterial &oratory the New York h'

    Office of Legacy Management (LM)

    l[nterial &oratory the New York h' ar&l Shipyard at Br&lyn, N. Y., to measure the neutron absorption chaxteristics ?f Tarious oyerlayys of fibergla& and resinous materials. R~TC&S Powder Co., Wilmington, Del., applied for a licerw to re- ceive and possess 25 gram3 of umnium (20 percent enrichment in uwnium 235) in the form of uranyl nitrate, for radiation chemistry osperiments. MalZnckrodt Chanical1Vork.q St. Low& ;Ilo., applied for 3 license to receive nnd possessup to

  14. Magnetic Transitions in Iron Porphyrin Halides by Inelastic Neutron Scattering and Ab-initio Studies of Zero-Field Splittings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stavretis, Shelby E.; Atanasov, Mihail; Podlesnyak, Andrey A.; Hunter, Seth C.; Neese, Frank; Xue, Zi-Ling

    2015-10-02

    Zero-field splitting (ZFS) parameters of nondeuterated metalloporphyrins [Fe(TPP)X] (X = F, Br, I; H2TPP = tetraphenylporphyrin) are determined by inelastic neutron scattering (INS). The ZFS values are D = 4.49(9) cm–1 for tetragonal polycrystalline [Fe(TPP)F], and D = 8.8(2) cm–1, E = 0.1(2) cm–1 and D = 13.4(6) cm–1, E = 0.3(6) cm–1 for monoclinic polycrystalline [Fe(TPP)Br] and [Fe(TPP)I], respectively. Along with our recent report of the ZFS value of D = 6.33(8) cm–1 for tetragonal polycrystalline [Fe(TPP)Cl], these data provide a rare, complete determination of ZFS parameters in a metalloporphyrin halide series. The electronic structure of [Fe(TPP)X] (X =more » F, Cl, Br, I) has been studied by multireference ab initio methods: the complete active space self-consistent field (CASSCF) and the N-electron valence perturbation theory (NEVPT2) with the aim of exploring the origin of the large and positive zero-field splitting D of the 6A1 ground state. D was calculated from wave functions of the electronic multiplets spanned by the d5 configuration of Fe(III) along with spin–orbit coupling accounted for by quasi degenerate perturbation theory. Results reproduce trends of D from inelastic neutron scattering data increasing in the order from F, Cl, Br, to I. A mapping of energy eigenvalues and eigenfunctions of the S = 3/2 excited states on ligand field theory was used to characterize the σ- and π-antibonding effects decreasing from F to I. This is in agreement with similar results deduced from ab initio calculations on CrX63- complexes and also with the spectrochemical series showing a decrease of the ligand field in the same directions. A correlation is found between the increase of D and decrease of the π- and σ-antibonding energies eλX (λ = σ, π) in the series from X = F to I. Analysis of this correlation using second-order perturbation theory expressions in terms of angular overlap parameters rationalizes the experimentally deduced trend. Furthermore, D parameters from CASSCF and NEVPT2 results have been calibrated against those from the INS data, yielding a predictive power of these approaches. Methods to improve the quantitative agreement between ab initio calculated and experimental D and spectroscopic transitions for high-spin Fe(III) complexes are proposed.« less

  15. Scientific system for high-resolution measurement of the circumsolar radiation

    SciTech Connect (OSTI)

    Schrott, Simeon Schmidt, Thomas Hornung, Thorsten Nitz, Peter

    2014-09-26

    We developed a camera based system for measurements of the circumsolar radiation with a high angular resolution of 0.1 mrad. Subsequent measurements may be taken at intervals as short as 15 s. In this publication we describe the optical system in detail and discuss some aspects of the measurement method. First results from two days of measurement at Freiburg i. Br., Germany, are presented and compared to data from literature. The good results encourage us to perform longer measurement campaigns in future to better understand the influence of circumsolar radiation on the power yield of concentrating photovoltaic systems.

  16. Split-System Cold Climate Heat Pump | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Split-System Cold Climate Heat Pump Split-System Cold Climate Heat Pump Photo of the prototype cold climate heat pump outdoor unit, installed at the Ohio field test site in January 2015. <br />Credit: Oak Ridge National Laboratory Photo of the prototype cold climate heat pump outdoor unit, installed at the Ohio field test site in January 2015. Credit: Oak Ridge National Laboratory Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partners: -- Unico Inc. - St. Louis, MO --

  17. Spinorbit interaction mediated molecular dissociation

    SciTech Connect (OSTI)

    Kokkonen, E. Jnkl, K.; Kettunen, J. A.; Heinsmki, S.; Karpenko, A.; Huttula, M.; Lytynoja, T.; Division of Theoretical Chemistry and Biology, School of Biotechnology, Royal Institute of Technology, S-106 91 Stockholm

    2014-05-14

    The effect of the spinorbit interaction to photofragmentation is investigated in the mercury(II) bromide (HgBr{sub 2}) molecule. Changes in the fragmentation between the two spinorbit components of Hg 5d photoionization, as well as within the molecular-field-splitted levels of these components are observed. Dissociation subsequent to photoionization is studied with synchrotron radiation and photoelectron-photoion coincidence spectroscopy. The experimental results are accompanied by relativistic ab initio analysis of the photoelectron spectrum.

  18. Search for High-Mass Resonances Decaying into Leptons of Different Flavor (e mu, e tau, mu tau) in p anti-p Collisions at sqrt(s) = 1.96 TeV

    SciTech Connect (OSTI)

    Tu, Yanjun; /Pennsylvania U.

    2008-10-01

    We present a search for high-mass resonances decaying into two leptons of different flavor: e{mu}, e{tau}, and {mu}{tau}. These resonances are predicted by several models beyond the standard model, such as the R-parity-violating MSSM. The search is based on 1 fb{sup -1} of data collected at the Collider Detector at Fermilab (CDF II) in proton anti-proton collisions. Our observations are consistent with the standard model expectations. The results are interpreted to set 95% C.L. upper limits on {sigma} x BR of {tilde {nu}}{sub {tau}} {yields} e{mu}, e{tau}, {mu}{tau}.

  19. Calculation tool for transported geothermal energy using two-step absorption process

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kyle Gluesenkamp

    2016-02-01

    This spreadsheet allows the user to calculate parameters relevant to techno-economic performance of a two-step absorption process to transport low temperature geothermal heat some distance (1-20 miles) for use in building air conditioning. The parameters included are (1) energy density of aqueous LiBr and LiCl solutions, (2) transportation cost of trucking solution, and (3) equipment cost for the required chillers and cooling towers in the two-step absorption approach. More information is available in the included public report: "A Technical and Economic Analysis of an Innovative Two-Step Absorption System for Utilizing Low-Temperature Geothermal Resources to Condition Commercial Buildings"

  20. A Pyrrolyl-based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions

    SciTech Connect (OSTI)

    Sessler, Jonathan L.; Cia, Jiajia; Gong, Han-Yuan; Yang, Xiauping; Arambula, Jonathan F.; Hay, Benjamin

    2010-01-01

    A pyrrolyl-based triazolophane, incorporating CH and NH donor groups, acts as a receptor for the pyrophosphate anion in chloroform solution. It shows selectivity for this trianion, followed by HSO{sub 4}{sup -} > H{sub 2}PO{sub 4}{sup -} > Cl{sup -} > Br{sup -} (all as the corresponding tetrabutylammonium salts), with NH-anion interactions being more important than CH-anion interactions. In the solid state, the receptor binds the pyrophosphate anion in a clip-like slot via NH and CH hydrogen bonds.