Sample records for border-collapse separate font

  1. acionados por fonte: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produced by fnsymbol will always match the text font family.g., say usepackagepplmathcomp to make mathcomp use the Adobe Palatino (ppl) text companion fonts The...

  2. acionados por fontes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produced by fnsymbol will always match the text font family.g., say usepackagepplmathcomp to make mathcomp use the Adobe Palatino (ppl) text companion fonts The...

  3. algumas fontes naturais: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produced by fnsymbol will always match the text font family.g., say usepackagepplmathcomp to make mathcomp use the Adobe Palatino (ppl) text companion fonts The...

  4. Desafios da integrao de fontes renovveis nos

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    necessidade de deslocamentos Aproveitamento de energia solar , eólica e biomassa Setor de transporte Mudanças+ Desafios da integração de fontes renováveis nos sistemas de energia convencionais Gilberto De escala? Sistemas convencionais de energia Carvão, petróleo e gás natural Nuclear Hidroeletricidade

  5. Good Fonts for Dyslexia NLP & Web Research Groups

    E-Print Network [OSTI]

    Good Fonts for Dyslexia Luz Rello NLP & Web Research Groups Universitat Pompeu Fabra Barcelona@acm.org ABSTRACT Around 10% of the people have dyslexia, a neurological dis- ability that impairs a person on a text's accessibility for people with dyslexia. However, to the best of our knowledge

  6. The mathcomp package for using Text Companion fonts in math mode *

    E-Print Network [OSTI]

    Mintmire, John W.

    .g., say \\usepackage[ppl]{mathcomp} to make mathcomp use the Adobe Palatino (ppl) text companion fonts

  7. OS RECENSEAMENTOS DEMOGRAFICOS : UMA FONTE DE INFORMAO SOBRE A FILIAO

    E-Print Network [OSTI]

    Boyer, Edmond

    5 OS RECENSEAMENTOS DEMOGRAFICOS : UMA FONTE DE INFORMA??O SOBRE A FILIA??O RELIGIOSA NO BRASIL NO BRASIL O Brasil é um país de tradição estatística. Os recenseamentos são, em princípio, realizados a cada *** Geógrafa, Pontifícia Universidade Católica, PUC, Rio de Janeiro ­ Brasil. #12;PHILIPPE WANIEZ VIOLETTE

  8. Ultracapacitor separator

    DOE Patents [OSTI]

    Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); LeBlanc, Jr., Oliver Harris (Schenectady, NY)

    2001-03-06T23:59:59.000Z

    An ultracapacitor includes two solid, nonporous current collectors, two porous electrodes separating the collectors, a porous separator between the electrodes and an electrolyte occupying the pores in the electrodes and separator. The electrolyte is a polar aprotic organic solvent and a salt. The porous separator comprises a wet laid cellulosic material.

  9. Propostes temes del treball sobre ER Treball sobre una font d'energia renovable

    E-Print Network [OSTI]

    Batiste, Oriol

    Propostes temes del treball sobre ER Treball sobre una font d'energia renovable Estudi de l'estat de desenvolupament, la implantaci´o i evoluci´o hist`orica d'u- na font d'energia renovable concreta: · Solar fotovoltaica · Solar trmica · Biocombustibiles · Elica Treball sobre una tecnologia espec

  10. Neptunium separations

    SciTech Connect (OSTI)

    Wild, J.F.

    1983-05-09T23:59:59.000Z

    Two procedures for the separation of Np are presented; the first involves separation of /sup 239/Np from irradiated /sup 238/U, and the second involves separation of /sup 237/Np from a solution representing that from a dissolved fuel element.

  11. Separation system

    DOE Patents [OSTI]

    Rubin, Leslie S. (Newton, MA)

    1986-01-01T23:59:59.000Z

    A separation system for dewatering radioactive waste materials includes a disposal container, drive structure for receiving the container, and means for releasably attaching the container to the drive structure. Separation structure disposed in the container adjacent the inner surface of the side wall structure retains solids while allowing passage of liquids. Inlet port structure in the container top wall is normally closed by first valve structure that is centrifugally actuated to open the inlet port and discharge port structure at the container periphery receives liquid that passes through the separation structure and is normally closed by second valve structure that is centrifugally actuated to open the discharge ports. The container also includes coupling structure for releasable engagement with the centrifugal drive structure. Centrifugal force produced when the container is driven in rotation by the drive structure opens the valve structures, and radioactive waste material introduced into the container through the open inlet port is dewatered, and the waste is compacted. The ports are automatically closed by the valves when the container drum is not subjected to centrifugal force such that containment effectiveness is enhanced and exposure of personnel to radioactive materials is minimized.

  12. HIGHRESOLUTION SEISMIC CHARACTERIZATION IN A COMPLEX URBAN , FontCap, J.2

    E-Print Network [OSTI]

    Politcnica de Catalunya, Universitat

    HIGHRESOLUTION SEISMIC CHARACTERIZATION IN A COMPLEX URBAN AREA Mart, D.1 , FontCap, J.2 is very difficult. The street geometry determined the geometry of the seismic data acquisition "weathered" layer of variable thickness (building fundations, sewage system, water supply conductions, etc

  13. Particle separation

    DOE Patents [OSTI]

    Moosmuller, Hans (Reno, NV); Chakrabarty, Rajan K. (Reno, NV); Arnott, W. Patrick (Reno, NV)

    2011-04-26T23:59:59.000Z

    Embodiments of a method for selecting particles, such as based on their morphology, is disclosed. In a particular example, the particles are charged and acquire different amounts of charge, or have different charge distributions, based on their morphology. The particles are then sorted based on their flow properties. In a specific example, the particles are sorted using a differential mobility analyzer, which sorts particles, at least in part, based on their electrical mobility. Given a population of particles with similar electrical mobilities, the disclosed process can be used to sort particles based on the net charge carried by the particle, and thus, given the relationship between charge and morphology, separate the particles based on their morphology.

  14. Separation Processes, Second Edition

    E-Print Network [OSTI]

    King, C. Judson

    1980-01-01T23:59:59.000Z

    by; Uranium isotopes separation) Iteration methods (seemethod for activity coefficients, 43, 481 Uranium isotopes separation,

  15. An analysis of font styles on the screen of a computer terminal

    E-Print Network [OSTI]

    Eason, Joyce Leona

    1988-01-01T23:59:59.000Z

    and put up with me and my alarm clocks over the years: Peggi, Maddie, Lynn, Lizzie, Donna, Helene, Sharon, and Lenia. Love and God bless you all! ACKNOWLEDGMENTS I would like to acknowledge and personally thank my committee members for their timely... individually, but you know who you are---I love you, and may the Lord richly bless you! TABLE OF CONTENTS Page DEDICATION ACKNOWLEDGES . TABLE OF CO~S LIST OF TABLES LIST OF FIGURES INTRODUCTION Font styles Proofreading errors OBJECTIVES METHOD...

  16. Meniscus Membranes For Separation

    DOE Patents [OSTI]

    Dye, Robert C. (Irvine, CA); Jorgensen, Betty (Jemez Springs, NM); Pesiri, David R. (Aliso Viejo, CA)

    2005-09-20T23:59:59.000Z

    Gas separation membranes, especially meniscus-shaped membranes for gas separations are disclosed together with the use of such meniscus-shaped membranes for applications such as thermal gas valves, pre-concentration of a gas stream, and selective pre-screening of a gas stream. In addition, a rapid screening system for simultaneously screening polymer materials for effectiveness in gas separation is provided.

  17. Meniscus membranes for separations

    DOE Patents [OSTI]

    Dye, Robert C. (Irvine, CA); Jorgensen, Betty (Jemez Springs, NM); Pesiri, David R. (Aliso Viejo, CA)

    2004-01-27T23:59:59.000Z

    Gas separation membranes, especially meniscus-shaped membranes for gas separations are disclosed together with the use of such meniscus-shaped membranes for applications such as thermal gas valves, pre-concentration of a gas stream, and selective pre-screening of a gas stream. In addition, a rapid screening system for simultaneously screening polymer materials for effectiveness in gas separation is provided.

  18. New 88Sr(n,<font face="symbol">gfont>)Astrophysical Reaction Rate from Resonance Analysis of New High-Resolution Neutron Capture and Transmission Data

    SciTech Connect (OSTI)

    Koehler, P.E.

    1999-08-30T23:59:59.000Z

    Because of its small cross section, the 88Sr(n,<font face="symbol">gfont>) reaction is an important bottleneck during s-process nucleosynthesis. Hence, an accurate determination of this rate is needed to better constrain the neutron exposure in s-process models and to more fully exploit the recently discovered isotopic anomalies in certain meteorites. We have completed the resonance analysis of our new and improved measurements of the neutron capture and total cross sections for 88Sr made at the Oak Ridge Electron Linear Accelerator (ORELA). We describe our experimental procedures and resonance analysis, compare our results to previous data, and discuss their astrophysical impact.

  19. Membrane Separations Research

    E-Print Network [OSTI]

    Fair, J. R.

    MEMBRANE SEPARATIONS RESEARCH James R. Fair Chemical Engineering Department The University of Texas at Austin Austin, TX 78712 ABSTRACT The use of membranes for separating gaseous and liquid mixtures has grown dramatically in the past 15... years. Applications have been dominated by light gas separations and water purification. During this pioneering period, equipment containing the membrane suIfaces has been developed to a point where failures are minimal and the membranes themselves...

  20. Methods for fluid separations, and devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E [Kennewick, WA; Stenkamp, Victoria S [Richland, WA

    2006-05-30T23:59:59.000Z

    Wick-Containing apparatus capable of separating fluids and methods of separating fluids using wicks are disclosed.

  1. Methods for fluid separations, and devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E. (Kennewick, WA); Stenkamp, Victoria S. (Richland, WA)

    2007-09-25T23:59:59.000Z

    Wick-Containing apparatus capable of separating fluids and methods of separating fluids using wicks are disclosed.

  2. Substituted polyacetylene separation membrane

    DOE Patents [OSTI]

    Pinnau, I.; Morisato, Atsushi

    1998-01-13T23:59:59.000Z

    A separation membrane is described which is useful for gas separation, particularly separation of C{sub 2+} hydrocarbons from natural gas. The invention encompasses the membrane itself, methods of making it and processes for using it. The membrane comprises a polymer having repeating units of a hydrocarbon-based, disubstituted polyacetylene, having the general formula shown in the accompanying diagram, wherein R{sub 1} is chosen from the group consisting of C{sub 1}-C{sub 4} alkyl and phenyl, and wherein R{sub 2} is chosen from the group consisting of hydrogen and phenyl. In the most preferred embodiment, the membrane comprises poly(4-methyl-2-pentyne) [PMP]. The membrane exhibits good chemical resistance and has super-glassy properties with regard to separating certain large, condensable permeant species from smaller, less-condensable permeant species. The membranes may also be useful in other fluid separations. 4 figs.

  3. Substituted polyacetylene separation membrane

    DOE Patents [OSTI]

    Pinnau, Ingo (Palo Alto, CA); Morisato, Atsushi (Tokyo, JP)

    1998-01-13T23:59:59.000Z

    A separation membrane useful for gas separation, particularly separation of C.sub.2+ hydrocarbons from natural gas. The invention encompasses the membrane itself, methods of making it and processes for using it. The membrane comprises a polymer having repeating units of a hydrocarbon-based, disubstituted polyacetylene, having the general formula: ##STR1## wherein R.sub.1 is chosen from the group consisting of C.sub.1 -C.sub.4 alkyl and phenyl, and wherein R.sub.2 is chosen from the group consisting of hydrogen and phenyl. In the most preferred embodiment, the membrane comprises poly(4-methyl-2-pentyne) PMP!. The membrane exhibits good chemical resistance and has super-glassy properties with regard to separating certain large, condensable permeant species from smaller, less-condensable permeant species. The membranes may also be useful in other fluid separations.

  4. Separators for flywheel rotors

    DOE Patents [OSTI]

    Bender, D.A.; Kuklo, T.C.

    1998-07-07T23:59:59.000Z

    A separator forms a connection between the rotors of a concentric rotor assembly. This separator allows for the relatively free expansion of outer rotors away from inner rotors while providing a connection between the rotors that is strong enough to prevent disassembly. The rotor assembly includes at least two rotors referred to as inner and outer flywheel rings or rotors. This combination of inner flywheel ring, separator, and outer flywheel ring may be nested to include an arbitrary number of concentric rings. The separator may be a segmented or continuous ring that abuts the ends of the inner rotor and the inner bore of the outer rotor. It is supported against centrifugal loads by the outer rotor and is affixed to the outer rotor. The separator is allowed to slide with respect to the inner rotor. It is made of a material that has a modulus of elasticity that is lower than that of the rotors. 10 figs.

  5. Separators for flywheel rotors

    DOE Patents [OSTI]

    Bender, Donald A. (Dublin, CA); Kuklo, Thomas C. (Oakdale, CA)

    1998-01-01T23:59:59.000Z

    A separator forms a connection between the rotors of a concentric rotor assembly. This separator allows for the relatively free expansion of outer rotors away from inner rotors while providing a connection between the rotors that is strong enough to prevent disassembly. The rotor assembly includes at least two rotors referred to as inner and outer flywheel rings or rotors. This combination of inner flywheel ring, separator, and outer flywheel ring may be nested to include an arbitrary number of concentric rings. The separator may be a segmented or continuous ring that abuts the ends of the inner rotor and the inner bore of the outer rotor. It is supported against centrifugal loads by the outer rotor and is affixed to the outer rotor. The separator is allowed to slide with respect to the inner rotor. It is made of a material that has a modulus of elasticity that is lower than that of the rotors.

  6. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, Frederick T. (Livermore, CA)

    1981-01-01T23:59:59.000Z

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  7. Gas Separation Using Membranes

    E-Print Network [OSTI]

    Koros, W. J.; Paul, D. R.

    1984-01-01T23:59:59.000Z

    Commercial membrane-based gas separator systems based upon high-flux, asymmetric polysulfone hollow fibers were first introduced in 1977 by Monsanto. These systems were packaged in compact modules containing large amounts of permeation surface area...

  8. USABC Battery Separator Development

    Broader source: Energy.gov (indexed) [DOE]

    Separator Development P.I. - Ron Smith Presenter - Kristoffer Stokes, Ph.D. Celgard, LLC Project ID ES007 May 10, 2011 This presentation does not contain any proprietary,...

  9. Hydrogen separation process

    DOE Patents [OSTI]

    Mundschau, Michael (Longmont, CO); Xie, Xiaobing (Foster City, CA); Evenson, IV, Carl (Lafayette, CO); Grimmer, Paul (Longmont, CO); Wright, Harold (Longmont, CO)

    2011-05-24T23:59:59.000Z

    A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to a hydrogen separation membrane system comprising a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for separating a hydrogen-rich product stream from a feed stream comprising hydrogen and at least one carbon-containing gas, comprising feeding the feed stream, at an inlet pressure greater than atmospheric pressure and a temperature greater than 200.degree. C., to an integrated water gas shift/hydrogen separation membrane system wherein the hydrogen separation membrane system comprises a membrane that is selectively permeable to hydrogen, and producing a hydrogen-rich permeate product stream on the permeate side of the membrane and a carbon dioxide-rich product raffinate stream on the raffinate side of the membrane. A method for pretreating a membrane, comprising: heating the membrane to a desired operating temperature and desired feed pressure in a flow of inert gas for a sufficient time to cause the membrane to mechanically deform; decreasing the feed pressure to approximately ambient pressure; and optionally, flowing an oxidizing agent across the membrane before, during, or after deformation of the membrane. A method of supporting a hydrogen separation membrane system comprising selecting a hydrogen separation membrane system comprising one or more catalyst outer layers deposited on a hydrogen transport membrane layer and sealing the hydrogen separation membrane system to a porous support.

  10. Organic Separation Test Results

    SciTech Connect (OSTI)

    Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

    2014-09-22T23:59:59.000Z

    Separable organics have been defined as those organic compounds of very limited solubility in the bulk waste and that can form a separate liquid phase or layer (Smalley and Nguyen 2013), and result from three main solvent extraction processes: U Plant Uranium Recovery Process, B Plant Waste Fractionation Process, and Plutonium Uranium Extraction (PUREX) Process. The primary organic solvents associated with tank solids are TBP, D2EHPA, and NPH. There is concern that, while this organic material is bound to the sludge particles as it is stored in the tanks, waste feed delivery activities, specifically transfer pump and mixer pump operations, could cause the organics to form a separated layer in the tank farms feed tank. Therefore, Washington River Protection Solutions (WRPS) is experimentally evaluating the potential of organic solvents separating from the tank solids (sludge) during waste feed delivery activities, specifically the waste mixing and transfer processes. Given the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste acceptance criteria per the Waste Feed Acceptance Criteria document (24590-WTP-RPT-MGT-11-014) that there is to be no visible layer of separable organics in the waste feed, this would result in the batch being unacceptable to transfer to WTP. This study is of particular importance to WRPS because of these WTP requirements.

  11. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Chang, Y. Alice (Des Plaines, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

    1986-01-01T23:59:59.000Z

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture through a polymeric membrane. The membrane which is utilized to effect the separation comprises a polymer which is capable of maintaining its integrity in the presence of hydrocarbon compounds and which has been modified by being subjected to the action of a sulfonating agent. Sulfonating agents which may be employed will include fuming sulfuric acid, chlorosulfonic acid, sulfur trioxide, etc., the surface or bulk modified polymer will contain a degree of sulfonation ranging from about 15 to about 50%. The separation process is effected at temperatures ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psig.

  12. Separators for electrochemical cells

    DOE Patents [OSTI]

    Carlson, Steven Allen; Anakor, Ifenna Kingsley

    2014-11-11T23:59:59.000Z

    Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al.sub.2O.sub.3.xH.sub.2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

  13. Molten salt electrolyte separator

    DOE Patents [OSTI]

    Kaun, T.D.

    1996-07-09T23:59:59.000Z

    The patent describes a molten salt electrolyte/separator for battery and related electrochemical systems including a molten electrolyte composition and an electrically insulating solid salt dispersed therein, to provide improved performance at higher current densities and alternate designs through ease of fabrication. 5 figs.

  14. Hydrogen isotope separation

    DOE Patents [OSTI]

    Bartlit, John R. (Los Alamos, NM); Denton, William H. (Abingdon, GB3); Sherman, Robert H. (Los Alamos, NM)

    1982-01-01T23:59:59.000Z

    A system of four cryogenic fractional distillation columns interlinked with two equilibrators for separating a DT and hydrogen feed stream into four product streams, consisting of a stream of high purity D.sub.2, DT, T.sub.2, and a tritium-free stream of HD for waste disposal.

  15. Laser isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Munich, DE); Boyer, Keith (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM)

    1988-01-01T23:59:59.000Z

    A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

  16. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  17. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C.P.; Jensen, R.J.; Cotter, T.P.; Greiner, N.R.; Boyer, K.

    1987-04-28T23:59:59.000Z

    A process is described for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium. 8 figs.

  18. Steam separator latch assembly

    DOE Patents [OSTI]

    Challberg, R.C.; Kobsa, I.R.

    1994-02-01T23:59:59.000Z

    A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof. 12 figures.

  19. Advanced Separation Consortium

    SciTech Connect (OSTI)

    NONE

    2006-01-01T23:59:59.000Z

    The Center for Advanced Separation Technologies (CAST) was formed in 2001 under the sponsorship of the US Department of Energy to conduct fundamental research in advanced separation and to develop technologies that can be used to produce coal and minerals in an efficient and environmentally acceptable manner. The CAST consortium consists of seven universities - Virginia Tech, West Virginia University, University of Kentucky, Montana Tech, University of Utah, University of Nevada-Reno, and New Mexico Tech. The consortium brings together a broad range of expertise to solve problems facing the US coal industry and the mining sector in general. At present, a total of 60 research projects are under way. The article outlines some of these, on topics including innovative dewatering technologies, removal of mercury and other impurities, and modelling of the flotation process. 1 photo.

  20. Steam separator latch assembly

    DOE Patents [OSTI]

    Challberg, Roy C. (Livermore, CA); Kobsa, Irvin R. (San Jose, CA)

    1994-01-01T23:59:59.000Z

    A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof.

  1. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Funk, Edward W. (Highland Park, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Des Plaines, IL)

    1986-01-01T23:59:59.000Z

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture over a polymeric membrane which comprises a polymer capable of maintaining its integrity in the presence of hydrocarbon compounds at temperature ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psi. The membranes which possess pore sizes ranging from about 10 to about 500 Angstroms are cast from a solvent solution and recovered.

  2. Innovative Separations Technologies

    SciTech Connect (OSTI)

    J. Tripp; N. Soelberg; R. Wigeland

    2011-05-01T23:59:59.000Z

    Reprocessing used nuclear fuel (UNF) is a multi-faceted problem involving chemistry, material properties, and engineering. Technology options are available to meet a variety of processing goals. A decision about which reprocessing method is best depends significantly on the process attributes considered to be a priority. New methods of reprocessing that could provide advantages over the aqueous Plutonium Uranium Reduction Extraction (PUREX) and Uranium Extraction + (UREX+) processes, electrochemical, and other approaches are under investigation in the Fuel Cycle Research and Development (FCR&D) Separations Campaign. In an attempt to develop a revolutionary approach to UNF recycle that may have more favorable characteristics than existing technologies, five innovative separations projects have been initiated. These include: (1) Nitrogen Trifluoride for UNF Processing; (2) Reactive Fluoride Gas (SF6) for UNF Processing; (3) Dry Head-end Nitration Processing; (4) Chlorination Processing of UNF; and (5) Enhanced Oxidation/Chlorination Processing of UNF. This report provides a description of the proposed processes, explores how they fit into the Modified Open Cycle (MOC) and Full Recycle (FR) fuel cycles, and identifies performance differences when compared to 'reference' advanced aqueous and fluoride volatility separations cases. To be able to highlight the key changes to the reference case, general background on advanced aqueous solvent extraction, advanced oxidative processes (e.g., volumetric oxidation, or 'voloxidation,' which is high temperature reaction of oxide UNF with oxygen, or modified using other oxidizing and reducing gases), and fluorination and chlorination processes is provided.

  3. Cyclic membrane separation process

    DOE Patents [OSTI]

    Bowser, John

    2004-04-13T23:59:59.000Z

    A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In one of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the other part, the membrane is inoperative while gas pressure rises in the ullage. Ambient air is charged to the membrane separation unit during the latter part of the cycle.

  4. Cyclic membrane separation process

    DOE Patents [OSTI]

    Nemser, Stuart M.

    2005-05-03T23:59:59.000Z

    A cyclic process for controlling environmental emissions of volatile organic compounds (VOC) from vapor recovery in storage and dispensing operations of liquids maintains a vacuum in the storage tank ullage. In the first part of a two-part cyclic process ullage vapor is discharged through a vapor recovery system in which VOC are stripped from vented gas with a selectively gas permeable membrane. In the second part, the membrane is inoperative while gas pressure rises in the ullage. In one aspect of this invention, a vacuum is drawn in the membrane separation unit thus reducing overall VOC emissions.

  5. Enhanced membrane gas separations

    SciTech Connect (OSTI)

    Prasad, R.

    1993-07-13T23:59:59.000Z

    An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

  6. Explosively separable casing

    DOE Patents [OSTI]

    Jacobson, Albin K. (Albuquerque, NM); Rychnovsky, Raymond E. (Livermore, CA); Visbeck, Cornelius N. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    An explosively separable casing including a cylindrical afterbody and a circular cover for one end of the afterbody is disclosed. The afterbody has a cylindrical tongue extending longitudinally from one end which is matingly received in a corresponding groove in the cover. The groove is sized to provide a pocket between the end of the tongue and the remainder of the groove so that an explosive can be located therein. A seal is also provided between the tongue and the groove for sealing the pocket from the atmosphere. A frangible holding device is utilized to hold the cover to the afterbody. When the explosive is ignited, the increase in pressure in the pocket causes the cover to be accelerated away from the afterbody. Preferably, the inner wall of the afterbody is in the same plane as the inner wall of the tongue to provide a maximum space for storage in the afterbody and the side wall of the cover is thicker than the side wall of the afterbody so as to provide a sufficiently strong surrounding portion for the pocket in which the explosion takes place. The detonator for the explosive is also located on the cover and is carried away with the cover during separation. The seal is preferably located at the longitudinal end of the tongue and has a chevron cross section.

  7. Electrified Separation Processes in Industry

    E-Print Network [OSTI]

    Appleby, A. J.

    1983-01-01T23:59:59.000Z

    For any separation procedure in the chemical industry, a certain amount of reversible work in the form of free energy is required, as dictated by the second law of thermodynamics. Classical techniques for effecting liquid-phase separations...

  8. Separation Nanotechnology of Diethylenetriaminepentaacetic Acid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded Magnetic Nanoparticles for Spent Nuclear Fuel. Separation Nanotechnology of Diethylenetriaminepentaacetic Acid Bonded...

  9. Gas separation process

    SciTech Connect (OSTI)

    Nicholas, D.M.; Hopkins, J.A.; Roden, T.M.; Bushinsky, J.P.

    1988-03-22T23:59:59.000Z

    The method for production of high purity hydrogen and high purity carbon monoxide from a mixed gas stream comprising these components together with carbon dioxide and a zero to a minor amount of one or more other gaseous contaminants is described comprising the steps of: (a) passing the mixed gas stream into and through a first bed of solid adsorbent capable of selectively adsorbing carbon dioxide and water while discharging from the bed a dry CO/sub 2/-freed effluent; (b) introducing the dry CO/sub 2/-freed effluent into a cryogenic environment for cooling the same therein under conditions effective for condensation of at least the major part of the carbon monoxide present in the dry CO/sub 2/-freed effluent; (c) withdrawing from the cryogenic environment carbon monoxide of high purity; (d) separately withdrawing from the cryogenic environment an uncondensed first gas stream product comprised of crude hydrogen and subjecting the first gas stream product to selective adsorption of non-hydrogen components therefrom in a second bed of solid absorbent, while recovering from the second bed the non-sorbed fraction as a product stream of essentially pure hydrogen; (e) purging the second solid adsorbent bed to desorb non-hydrogen components sorbed therein in step (d), and withdrawing from the bed a gas stream comprising the desorbed non-hydrogen components.

  10. Organic contaminant separator

    DOE Patents [OSTI]

    Del Mar, P.

    1993-12-28T23:59:59.000Z

    A process is presented of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube. The solvent is capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus is presented for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium. The apparatus includes a composite tube comprised of a blend of a polyolefin and a polyester. The composite tube has an internal diameter of from about 0.1 to about 2.0 millimeters and has sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube. 2 figures.

  11. Separators - Technology review: Ceramic based separators for secondary batteries

    SciTech Connect (OSTI)

    Nestler, Tina; Schmid, Robert; Mnchgesang, Wolfram; Bazhenov, Vasilii; Meyer, Dirk C. [Technische Universitt Bergakademie Freiberg, Institut fr Experimentelle Physik, Leipziger Str. 23, 09596 Freiberg (Germany); Schilm, Jochen [Fraunhofer-Institut fr Keramische Technologien und Systeme IKTS, Winterbergstrae 28, 01277 Dresden (Germany); Leisegang, Tilmann [Fraunhofer-Technologiezentrum Halbleitermaterialien THM, Am St.-Niclas-Schacht 13, 09599 Freiberg (Germany)

    2014-06-16T23:59:59.000Z

    Besides a continuous increase of the worldwide use of electricity, the electric energy storage technology market is a growing sector. At the latest since the German energy transition ('Energiewende') was announced, technological solutions for the storage of renewable energy have been intensively studied. Storage technologies in various forms are commercially available. A widespread technology is the electrochemical cell. Here the cost per kWh, e. g. determined by energy density, production process and cycle life, is of main interest. Commonly, an electrochemical cell consists of an anode and a cathode that are separated by an ion permeable or ion conductive membrane - the separator - as one of the main components. Many applications use polymeric separators whose pores are filled with liquid electrolyte, providing high power densities. However, problems arise from different failure mechanisms during cell operation, which can affect the integrity and functionality of these separators. In the case of excessive heating or mechanical damage, the polymeric separators become an incalculable security risk. Furthermore, the growth of metallic dendrites between the electrodes leads to unwanted short circuits. In order to minimize these risks, temperature stable and non-flammable ceramic particles can be added, forming so-called composite separators. Full ceramic separators, in turn, are currently commercially used only for high-temperature operation systems, due to their comparably low ion conductivity at room temperature. However, as security and lifetime demands increase, these materials turn into focus also for future room temperature applications. Hence, growing research effort is being spent on the improvement of the ion conductivity of these ceramic solid electrolyte materials, acting as separator and electrolyte at the same time. Starting with a short overview of available separator technologies and the separator market, this review focuses on ceramic-based separators. Two prominent examples, the lithium-ion and sodium-sulfur battery, are described to show the current stage of development. New routes are presented as promising technologies for safe and long-life electrochemical storage cells.

  12. Separation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Perry, Steven T. (Galloway, OH); Arora, Ravi (Dublin, OH); Qiu, Dongming (Bothell, WA); Lamont, Michael Jay (Hilliard, OH); Burwell, Deanna (Cleveland Heights, OH); Dritz, Terence Andrew (Worthington, OH); McDaniel, Jeffrey S. (Columbus, OH); Rogers, Jr.; William A. (Marysville, OH); Silva, Laura J. (Dublin, OH); Weidert, Daniel J. (Lewis Center, OH); Simmons, Wayne W. (Dublin, OH); Chadwell, G. Bradley (Reynoldsburg, OH)

    2009-03-24T23:59:59.000Z

    The disclosed invention relates to a process and apparatus for separating a first fluid from a fluid mixture comprising the first fluid. The process comprises: (A) flowing the fluid mixture into a microchannel separator in contact with a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the first fluid is sorbed by the sorption medium, removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing first fluid from the sorption medium and removing desorbed first fluid from the microchannel separator. The process and apparatus are suitable for separating nitrogen or methane from a fluid mixture comprising nitrogen and methane. The process and apparatus may be used for rejecting nitrogen in the upgrading of sub-quality methane.

  13. Gas separation membrane module assembly

    DOE Patents [OSTI]

    Wynn, Nicholas P (Palo Alto, CA); Fulton, Donald A. (Fairfield, CA)

    2009-03-31T23:59:59.000Z

    A gas-separation membrane module assembly and a gas-separation process using the assembly. The assembly includes a set of tubes, each containing gas-separation membranes, arranged within a housing. The housing contains a tube sheet that divides the space within the housing into two gas-tight spaces. A permeate collection system within the housing gathers permeate gas from the tubes for discharge from the housing.

  14. Membrane Separations of Liquid Mixtures

    E-Print Network [OSTI]

    Lloyd, D. R.

    MEMBRANE SEPARATIONS OF LIQUID MIXTURES Douglas R. Lloyd Separations Research Program Department of Chemical Engineering The University of Texas at Austin Austin, Texas In recent years considerable attention has been given to the need... for reduced energy costs in the chemical processing industry. A major portion of the energy consumed in this industry is associated with the separation and recovery of chemicals. Membrane processes offer energy-efficient, cost effective methods...

  15. Separation Membrane Development (Separation Using Encapsulated Metal Hydride)

    E-Print Network [OSTI]

    Separation Membrane Development (Separation Using Encapsulated Metal Hydride) L. Kit Heung Savannah: The first is to produce a sol-gel encapsulated metal hydride packing material that will a) absorbs hydrogen may be that hydrogen must come from multiple sources. These sources will include renewable (solar

  16. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, W.R.; Storz, L.J.

    1991-03-26T23:59:59.000Z

    An electrochemical cell is characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  17. Entrepreneurial separation to transfer technology.

    SciTech Connect (OSTI)

    Fairbanks, Richard R.

    2010-09-01T23:59:59.000Z

    Entrepreneurial separation to transfer technology (ESTT) program is that entrepreneurs terminate their employment with Sandia. The term of the separation is two years with the option to request a third year. Entrepreneurs are guaranteed reinstatement by Sandia if they return before ESTT expiration. Participants may start up or helpe expand technology businesses.

  18. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, Wendy R. (1166 Laurel Loop NE., Albuquerque, NM 87122); Storz, Leonard J. (2215 Ambassador NE., Albuquerque, NM 87112)

    1991-01-01T23:59:59.000Z

    An electrochemical cell characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  19. Three phase downhole separator process

    DOE Patents [OSTI]

    Cognata, Louis John (Baytown, TX)

    2008-06-24T23:59:59.000Z

    Three Phase Downhole Separator Process (TPDSP) is a process which results in the separation of all three phases, (1) oil, (2) gas, and (3) water, at the downhole location in the well bore, water disposal injection downhole, and oil and gas production uphole.

  20. Efficient separations & processing crosscutting program

    SciTech Connect (OSTI)

    NONE

    1996-08-01T23:59:59.000Z

    The Efficient Separations and Processing Crosscutting Program (ESP) was created in 1991 to identify, develop, and perfect chemical and physical separations technologies and chemical processes which treat wastes and address environmental problems throughout the DOE complex. The ESP funds several multiyear tasks that address high-priority waste remediation problems involving high-level, low-level, transuranic, hazardous, and mixed (radioactive and hazardous) wastes. The ESP supports applied research and development (R & D) leading to the demonstration or use of these separations technologies by other organizations within the Department of Energy (DOE), Office of Environmental Management.

  1. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

    1997-09-23T23:59:59.000Z

    A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

  2. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

    1997-01-01T23:59:59.000Z

    A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

  3. Continuous magnetic separator and process

    DOE Patents [OSTI]

    Oder, Robin R. (Export, PA); Jamison, Russell E. (Lower Burrell, PA)

    2008-04-22T23:59:59.000Z

    A continuous magnetic separator and process for separating a slurry comprising magnetic particles into a clarified stream and a thickened stream. The separator has a container with a slurry inlet, an overflow outlet for the discharge of the clarified slurry stream, and an underflow outlet for the discharge of a thickened slurry stream. Magnetic particles in the slurry are attracted to, and slide down, magnetic rods within the container. The slurry is thus separated into magnetic concentrate and clarified slurry. Flow control means can be used to control the ratio of the rate of magnetic concentrate to the rate of clarified slurry. Feed control means can be used to control the rate of slurry feed to the slurry inlet.

  4. Pump and centrifugal separator apparatus

    SciTech Connect (OSTI)

    Erickson, J.W.

    1981-08-11T23:59:59.000Z

    The invention relates to agitating means for preventing the accumulation of particulate matter at the contaminate outlet orifices in a pump and centrifugal separator apparatus. The pump separator apparatus includes a rotatable casing forming a chamber for centrifugally separating the oil, water and contaminant matter in an oil well production fluid. The clean oil is collected by a stationary pitot tube in the chamber, the clean water is drawn off at an outlet port near the outer periphery of the chamber, and the dirty water and contaminants are discharged through outlet orifices formed in the outer wall of the casing. The agitating means includes rotating jet ports for directing streams of pressurized fluid tangentially along the inner surface of the casing to agitate accumulations of separated solid contaminant matter thereby preventing the clogging of the outlet orifices.

  5. Fluorine separation and generation device

    DOE Patents [OSTI]

    Jacobson, Craig P. (Moraga, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA); Stefan, Constantin I. (Hayward, CA)

    2010-03-02T23:59:59.000Z

    A process and apparatus for the electrolytic separation of fluorine from a mixture of gases is disclosed. Also described is the process and apparatus for the generation of fluorine from fluorine/fluoride containing solids, liquids or gases.

  6. Fluorine separation and generation device

    DOE Patents [OSTI]

    The Regents of the University of California (Oakland, CA)

    2008-12-23T23:59:59.000Z

    A process and apparatus for the electrolytic separation of fluorine from a mixture of gases is disclosed. Also described is the process and apparatus for the generation of fluorine from fluorine/fluoride containing solids, liquids or gases.

  7. Phosphazene membranes for gas separations

    DOE Patents [OSTI]

    Stewart, Frederick F.; Harrup, Mason K.; Orme, Christopher J.; Luther, Thomas A.

    2006-07-11T23:59:59.000Z

    A polyphosphazene having a glass transition temperature ("Tg") of approximately -20.degree. C. or less. The polyphosphazene has at least one pendant group attached to a backbone of the polyphosphazene, wherein the pendant group has no halogen atoms. In addition, no aromatic groups are attached to an oxygen atom that is bound to a phosphorus atom of the backbone. The polyphosphazene may have a Tg ranging from approximately -100.degree. C. to approximately -20.degree. C. The polyphosphazene may be selected from the group consisting of poly[bis-3-phenyl-1-propoxy)phosphazene], poly[bis-(2-phenyl-1-ethoxy)phosphazene], poly[bis-(dodecanoxypolyethoxy)-phosphazene], and poly[bis-(2-(2-(2-.omega.-undecylenyloxyethoxy)ethoxy)ethoxy)phosphazene]. The polyphosphazene may be used in a separation membrane to selectively separate individual gases from a gas mixture, such as to separate polar gases from nonpolar gases in the gas mixture.

  8. Actinide Lanthanide Separation Process ALSEP

    SciTech Connect (OSTI)

    Gelis, Artem V.; Lumetta, Gregg J.

    2014-01-29T23:59:59.000Z

    Separation of the minor actinides (Am, Cm) from the lanthanides at an industrial scale remains a significant technical challenge for closing the nuclear fuel cycle. To increase the safety of used nuclear fuel (UNF) reprocessing, as well as reduce associated costs, a novel solvent extraction process has been developed. The process allows for partitioning minor actinides, lanthanides and fission products following uranium/plutonium/neptunium removal; minimizing the number of separation steps, flowsheets, chemical consumption, and waste. This new process, Actinide Lanthanide SEParation (ALSEP), uses an organic solvent consisting of a neutral diglycolamide extractant, either N,N,N',N'-tetra(2 ethylhexyl)diglycolamide (T2EHDGA) or N,N,N',N'-tetraoctyldiglycolamide (TODGA), and an acidic extractant 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]), dissolved in an aliphatic diluent (e.g. n-dodecane). The An/Ln co-extraction is conducted from moderate-to-strong nitric acid, while the selective stripping of the minor actinides from the lanthanides is carried out using a polyaminocarboxylic acid/citrate buffered solution at pH anywhere between 3 and 4.5. The extraction and separation of the actinides from the fission products is very effective in a wide range of HNO3 concentrations and the minimum separation factors for lanthanide/Am exceed 30 for Nd/Am, reaching > 60 for Eu/Am under some conditions. The experimental results presented here demonstrate the great potential for a combined system, consisting of a neutral extractant such as T2EHDGA or TODGA, and an acidic extractant such as HEH[EHP], for separating the minor actinides from the lanthanides.

  9. Energy Conservation Possibilities Using Gas Separating Membranes

    E-Print Network [OSTI]

    Knieriem, H.; Henis, J. M. S.

    1980-01-01T23:59:59.000Z

    The separation of gases using semi permeable membranes is a viable unit operation. A novel composite membrane combined with hollow fiber spinning technology enable Monsanto Co. to offer PRISM (TM); Separators to the industrial market. The separator...

  10. 33rd Actinide Separations Conference

    SciTech Connect (OSTI)

    McDonald, L M; Wilk, P A

    2009-05-04T23:59:59.000Z

    Welcome to the 33rd Actinide Separations Conference hosted this year by the Lawrence Livermore National Laboratory. This annual conference is centered on the idea of networking and communication with scientists from throughout the United States, Britain, France and Japan who have expertise in nuclear material processing. This conference forum provides an excellent opportunity for bringing together experts in the fields of chemistry, nuclear and chemical engineering, and actinide processing to present and discuss experiences, research results, testing and application of actinide separation processes. The exchange of information that will take place between you, and other subject matter experts from around the nation and across the international boundaries, is a critical tool to assist in solving both national and international problems associated with the processing of nuclear materials used for both defense and energy purposes, as well as for the safe disposition of excess nuclear material. Granlibakken is a dedicated conference facility and training campus that is set up to provide the venue that supports communication between scientists and engineers attending the 33rd Actinide Separations Conference. We believe that you will find that Granlibakken and the Lake Tahoe views provide an atmosphere that is stimulating for fruitful discussions between participants from both government and private industry. We thank the Lawrence Livermore National Laboratory and the United States Department of Energy for their support of this conference. We especially thank you, the participants and subject matter experts, for your involvement in the 33rd Actinide Separations Conference.

  11. Gas Separations using Ceramic Membranes

    SciTech Connect (OSTI)

    Paul KT Liu

    2005-01-13T23:59:59.000Z

    This project has been oriented toward the development of a commercially viable ceramic membrane for high temperature gas separations. A technically and commercially viable high temperature gas separation membrane and process has been developed under this project. The lab and field tests have demonstrated the operational stability, both performance and material, of the gas separation thin film, deposited upon the ceramic membrane developed. This performance reliability is built upon the ceramic membrane developed under this project as a substrate for elevated temperature operation. A comprehensive product development approach has been taken to produce an economically viable ceramic substrate, gas selective thin film and the module required to house the innovative membranes for the elevated temperature operation. Field tests have been performed to demonstrate the technical and commercial viability for (i) energy and water recovery from boiler flue gases, and (ii) hydrogen recovery from refinery waste streams using the membrane/module product developed under this project. Active commercializations effort teaming with key industrial OEMs and end users is currently underway for these applications. In addition, the gas separation membrane developed under this project has demonstrated its economical viability for the CO2 removal from subquality natural gas and landfill gas, although performance stability at the elevated temperature remains to be confirmed in the field.

  12. Separations innovative concepts: Project summary

    SciTech Connect (OSTI)

    Lee, V.E. (ed.)

    1988-05-01T23:59:59.000Z

    This project summary includes the results of 10 innovations that were funded under the US Department's Innovative Concept Programs. The concepts address innovations that can substantially reduce the energy used in industrial separations. Each paper describes the proposed concept, and discusses the concept's potential energy savings, market applications, technical feasibility, prior work and state of the art, and future development needs.

  13. Isotope separation by laser means

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1982-06-15T23:59:59.000Z

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  14. Noise suppressing capillary separation system

    DOE Patents [OSTI]

    Yeung, E.S.; Xue, Y.

    1996-07-30T23:59:59.000Z

    A noise-suppressing capillary separation system for detecting the real-time presence or concentration of an analyte in a sample is provided. The system contains a capillary separation means through which the analyte is moved, a coherent light source that generates a beam which is split into a reference beam and a sample beam that irradiate the capillary, and a detector for detecting the reference beam and the sample beam light that transmits through the capillary. The laser beam is of a wavelength effective to be absorbed by a chromophore in the capillary. The system includes a noise suppressing system to improve performance and accuracy without signal averaging or multiple scans. 13 figs.

  15. Convex polytopes and quantum separability

    SciTech Connect (OSTI)

    Holik, F.; Plastino, A. [Departamento de Matematica - Ciclo Basico Comun, Universidad de Buenos Aires - Pabellon III, Ciudad Universitaria, Buenos Aires, Argentina and CONICET (Argentina); National University La Plata and CONICET IFLP-CCT, C.C. 727 - 1900 La Plata (Argentina)

    2011-12-15T23:59:59.000Z

    We advance a perspective of the entanglement issue that appeals to the Schlienz-Mahler measure [Phys. Rev. A 52, 4396 (1995)]. Related to it, we propose a criterium based on the consideration of convex subsets of quantum states. This criterium generalizes a property of product states to convex subsets (of the set of quantum states) that is able to uncover an interesting geometrical property of the separability property.

  16. Supported liquid membrane electrochemical separators

    DOE Patents [OSTI]

    Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

    1986-01-01T23:59:59.000Z

    Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

  17. Guayule resin separation and purification

    E-Print Network [OSTI]

    Bajwa, Mohinder P.S.

    1992-01-01T23:59:59.000Z

    fraction and reducing the presence of these terpenes to practically non-detectable levels in the polar fraction. A single component, as identified by gas chromatograph (GC) was also effectively extracted from the Texas A&M resins. Saponification..., using an FID Solvent fractionation of the Firestone resin between methanol and hexane was also apparently effective in separating the low molecular weight rubber. Figure 16 and Figure 17 show the gas chromatographs of the bottom phase (fraction "a...

  18. Anisotropic membranes for gas separation

    DOE Patents [OSTI]

    Gollan, Arye Z. (Newton, MA)

    1987-01-01T23:59:59.000Z

    A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7.degree.-25.degree. C. and then air dried at ambient temperature, typically 10.degree.-30.degree. C.

  19. Anisotropic membranes for gas separation

    DOE Patents [OSTI]

    Gollan, A.Z.

    1987-07-21T23:59:59.000Z

    A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7--25 C and then air dried at ambient temperature, typically 10--30 C. 2 figs.

  20. Apparatus and method for separating constituents

    DOE Patents [OSTI]

    Maronde, Carl P. (McMurray, PA); Killmeyer, Jr., Richard P. (Pittsburgh, PA)

    1992-01-01T23:59:59.000Z

    A centrifugal separator apparatus and method for improving the efficiency of the separation of constituents in a fluid stream. A cyclone separator includes an assembly for separately discharging both constituents through the same end of the separator housing. A rotary separator includes a rotary housing having a baffle disposed therein for minimizing the differential rotational velocities of the constituents in the housing, thereby decreasing turbulence, and increasing efficiency. The intensity of the centrifugal force and the time which the constituents reside within the housing can be independently controlled to improve efficiency of separation.

  1. Separations and safeguards model integration.

    SciTech Connect (OSTI)

    Cipiti, Benjamin B.; Zinaman, Owen

    2010-09-01T23:59:59.000Z

    Research and development of advanced reprocessing plant designs can greatly benefit from the development of a reprocessing plant model capable of transient solvent extraction chemistry. This type of model can be used to optimize the operations of a plant as well as the designs for safeguards, security, and safety. Previous work has integrated a transient solvent extraction simulation module, based on the Solvent Extraction Process Having Interaction Solutes (SEPHIS) code developed at Oak Ridge National Laboratory, with the Separations and Safeguards Performance Model (SSPM) developed at Sandia National Laboratory, as a first step toward creating a more versatile design and evaluation tool. The goal of this work was to strengthen the integration by linking more variables between the two codes. The results from this integrated model show expected operational performance through plant transients. Additionally, ORIGEN source term files were integrated into the SSPM to provide concentrations, radioactivity, neutron emission rate, and thermal power data for various spent fuels. This data was used to generate measurement blocks that can determine the radioactivity, neutron emission rate, or thermal power of any stream or vessel in the plant model. This work examined how the code could be expanded to integrate other separation steps and benchmark the results to other data. Recommendations for future work will be presented.

  2. Guidelines For Developing Low Energy Separation Processes

    E-Print Network [OSTI]

    Bojnowski, J. H.; Hanks, D. L.

    1981-01-01T23:59:59.000Z

    A large portion of the energy required by the process industry is consumed by separation processes. This paper discusses current engineering techniques that can be used in the development and optimization of low energy separation processes....

  3. Device for hydrogen separation and method

    DOE Patents [OSTI]

    Paglieri, Stephen N. (White Rock, NM); Anderson, Iver E. (Ames, IA); Terpstra, Robert L. (Ames, IA)

    2009-11-03T23:59:59.000Z

    A device for hydrogen separation has a porous support and hydrogen separation material on the support. The support is prepared by heat treatment of metal microparticles, preferably of iron-based or nickel-based alloys that also include aluminum and/or yttrium. The hydrogen separation material is then deposited on the support. Preferred hydrogen separation materials include metals such as palladium, alloys, platinum, refractory metals, and alloys.

  4. Center for Gas Separations Relevant to

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Center for Gas Separations Relevant to Clean Energy Technologies #12;Director Berend Smit Jeffrey, metal-organic framework. © 2013 EFRC Center for Gas Separation Relevant to Clean Energy Technology. All the current separation technology, developed over sixty years ago, requires 25-35% more coal to produce

  5. Cyclone separator having boundary layer turbulence control

    DOE Patents [OSTI]

    Krishna, Coimbatore R. (Mt. Sinai, NY); Milau, Julius S. (Port Jefferson, NY)

    1985-01-01T23:59:59.000Z

    A cyclone separator including boundary layer turbulence control that is operable to prevent undue build-up of particulate material at selected critical areas on the separator walls, by selectively varying the fluid pressure at those areas to maintain the momentum of the vortex, thereby preventing particulate material from inducing turbulence in the boundary layer of the vortical fluid flow through the separator.

  6. GEOMETRIC SOURCE SEPARATION: MERGING CONVOLUTIVE SOURCE

    E-Print Network [OSTI]

    Parra, Lucas C.

    adaptive beamforming algorithms by a cross-power criteria, we gain new geometric source separation with convo- lutive blind source separation. We concentrate on cross-power spectral min- imization which is su to ambiguities in the choice of separating lters. There are in theory multiple lters that invert the room

  7. Centrifugal separator devices, systems and related methods

    DOE Patents [OSTI]

    Meikrantz, David H. (Idaho Falls, ID); Law, Jack D. (Pocatello, ID); Garn, Troy G. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Macaluso, Lawrence L. (Carson City, NV)

    2012-03-20T23:59:59.000Z

    Centrifugal separator devices, systems and related methods are described. More particularly, fluid transfer connections for a centrifugal separator system having support assemblies with a movable member coupled to a connection tube and coupled to a fixed member, such that the movable member is constrained to movement along a fixed path relative to the fixed member are described. Also, centrifugal separator systems including such fluid transfer connections are described. Additionally, methods of installing, removing and/or replacing centrifugal separators from centrifugal separator systems are described.

  8. Process for strontium-82 separation

    DOE Patents [OSTI]

    Heaton, Richard C. (Los Alamos, NM); Jamriska, Sr., David J. (Los Alamos, NM); Taylor, Wayne A. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets comprises dissolving the molybdenum target in a hydrogen peroxide solution to form a first solution containing ions selected from a group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium, rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, and yttrium; passing the solution through a first cationic resin whereby ions selected from a group consisting of zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium a portion of zirconium and a portion of rubidium are selectively absorbed by the first resin; contacting the first resin with an acid solution to strip and remove the absorbed ions from the first cationic exchange resin to form a second solution; evaporating the second solution for a time sufficient to remove substantially all of the acid and water from the solution whereby a residue remains; dissolving the residue in a dilute acid to form a third solution; passing the third solution through a second cationic resin whereby the ions are absorbed by the second resin; contacting the second resin with a dilute sulfuric acid solution whereby the absorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium and zirconium are selectively removed from the second resin; and contacting the second resin with a dilute acid solution whereby the absorbed strontium ions are selectively removed.

  9. Process for strontium-82 separation

    DOE Patents [OSTI]

    Heaton, R.C.; Jamriska, D.J. Sr.; Taylor, W.A.

    1992-12-01T23:59:59.000Z

    A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets comprises dissolving the molybdenum target in a hydrogen peroxide solution to form a first solution containing ions selected from a group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium, rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, and yttrium; passing the solution through a first cationic resin whereby ions selected from a group consisting of zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium a portion of zirconium and a portion of rubidium are selectively absorbed by the first resin; contacting the first resin with an acid solution to strip and remove the absorbed ions from the first cationic exchange resin to form a second solution; evaporating the second solution for a time sufficient to remove substantially all of the acid and water from the solution whereby a residue remains; dissolving the residue in a dilute acid to form a third solution; passing the third solution through a second cationic resin whereby the ions are absorbed by the second resin; contacting the second resin with a dilute sulfuric acid solution whereby the absorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium and zirconium are selectively removed from the second resin; and contacting the second resin with a dilute acid solution whereby the absorbed strontium ions are selectively removed. 1 fig.

  10. Blind Source Separation 2 Understanding Two Simultaneous Speeches by Blind Source Separation

    E-Print Network [OSTI]

    Ikeda, Shiro

    Blind Source Separation 2 Understanding Two Simultaneous Speeches by Blind Source Separation) to segregate speech streams from a mixture of sounds, while the other ex- ploits Blind Source Separation the performance of Blind Source Separation by using the same three benchmarks of 500 mix- ture of two speeches

  11. Liquid phase thermal swing chemical air separation

    DOE Patents [OSTI]

    Erickson, D.C.

    1988-05-24T23:59:59.000Z

    A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite. 2 figs.

  12. Liquid phase thermal swing chemical air separation

    DOE Patents [OSTI]

    Erickson, Donald C. (Annapolis, MD)

    1988-01-01T23:59:59.000Z

    A temperature swing absorption separation of oxygen from air is performed with an oxygen acceptor of alkali metal nitrate and nitrite.

  13. Inertial microfluidics for particle separation and filtration.

    E-Print Network [OSTI]

    Bhagat, Ali Asgar Saleem

    2009-01-01T23:59:59.000Z

    ??Filtration and separation of particles has numerous industrial and research applications in biology and medicine. In this work, inertial microfluidics is used to develop devices (more)

  14. Separation, Characterization and Initial Reaction Studies of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Abstract: Magnetic and density separation methods have been applied to composite sediment sample from the Hanford formation from sediment recovered during drilling of an...

  15. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  16. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  17. Centrifugal separators and related devices and methods

    DOE Patents [OSTI]

    Meikrantz, David H. (Idaho Falls, ID); Law, Jack D. (Pocatello, ID); Garn, Troy G. (Idaho Falls, ID); Macaluso, Lawrence L. (Carson City, NV); Todd, Terry A. (Aberdeen, ID)

    2012-03-06T23:59:59.000Z

    Centrifugal separators and related methods and devices are described. More particularly, centrifugal separators comprising a first fluid supply fitting configured to deliver fluid into a longitudinal fluid passage of a rotor shaft and a second fluid supply fitting sized and configured to sealingly couple with the first fluid supply fitting are described. Also, centrifugal separator systems comprising a manifold having a drain fitting and a cleaning fluid supply fitting are described, wherein the manifold is coupled to a movable member of a support assembly. Additionally, methods of cleaning centrifugal separators are described.

  18. Celgard and Entek - Battery Separator Development

    Broader source: Energy.gov (indexed) [DOE]

    Celgard and Entek Battery Separator Development Harshad Tataria R. Pekala, Ron Smith USABC May 19, 2009 Project ID es08tataria This presentation does not contain any...

  19. Conditions for fluid separations in microchannels, capillary-driven fluid separations, and laminated devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E. (Kennewick, WA); Stenkamp, Victoria S. (Richland, WA)

    2008-03-18T23:59:59.000Z

    Methods of separating fluids using capillary forces and/or improved conditions for are disclosed. The improved methods may include control of the ratio of gas and liquid Reynolds numbers relative to the Suratman number. Also disclosed are wick-containing, laminated devices that are capable of separating fluids.

  20. Conditions for fluid separations in microchannels, capillary-driven fluid separations, and laminated devices capable of separating fluids

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E [Kennewick, WA; Stenkamp, Victoria S [Richland, WA

    2005-04-05T23:59:59.000Z

    Methods of separating fluids using capillary forces and/or improved conditions for are disclosed. The improved methods may include control of the ratio of gas and liquid Reynolds numbers relative to the Suratman number. Also disclosed are wick-containing, laminated devices that are capable of separating fluids.

  1. Passive gas separator and accumulator device

    DOE Patents [OSTI]

    Choe, Hwang (Saratoga, CA); Fallas, Thomas T. (Berkeley, CA)

    1994-01-01T23:59:59.000Z

    A separation device employing a gas separation filter and swirler vanes for separating gas from a gasliquid mixture is provided. The cylindrical filter utilizes the principle that surface tension in the pores of the filter prevents gas bubbles from passing through. As a result, the gas collects in the interior region of the filter and coalesces to form larger bubbles in the center of the device. The device is particularly suited for use in microgravity conditions since the swirlers induce a centrifugal force which causes liquid to move from the inner region of the filter, pass the pores, and flow through the outlet of the device while the entrained gas is trapped by the filter. The device includes a cylindrical gas storage screen which is enclosed by the cylindrical gas separation filter. The screen has pores that are larger than those of the filters. The screen prevents larger bubbles that have been formed from reaching and interfering with the pores of the gas separation filter. The device is initially filled with a gas other than that which is to be separated. This technique results in separation of the gas even before gas bubbles are present in the mixture. Initially filling the device with the dissimilar gas and preventing the gas from escaping before operation can be accomplished by sealing the dissimilar gas in the inner region of the separation device with a ruptured disc which can be ruptured when the device is activated for use.

  2. Passive gas separator and accumulator device

    DOE Patents [OSTI]

    Choe, H.; Fallas, T.T.

    1994-08-02T23:59:59.000Z

    A separation device employing a gas separation filter and swirler vanes for separating gas from a gas-liquid mixture is provided. The cylindrical filter utilizes the principle that surface tension in the pores of the filter prevents gas bubbles from passing through. As a result, the gas collects in the interior region of the filter and coalesces to form larger bubbles in the center of the device. The device is particularly suited for use in microgravity conditions since the swirlers induce a centrifugal force which causes liquid to move from the inner region of the filter, pass the pores, and flow through the outlet of the device while the entrained gas is trapped by the filter. The device includes a cylindrical gas storage screen which is enclosed by the cylindrical gas separation filter. The screen has pores that are larger than those of the filters. The screen prevents larger bubbles that have been formed from reaching and interfering with the pores of the gas separation filter. The device is initially filled with a gas other than that which is to be separated. This technique results in separation of the gas even before gas bubbles are present in the mixture. Initially filling the device with the dissimilar gas and preventing the gas from escaping before operation can be accomplished by sealing the dissimilar gas in the inner region of the separation device with a ruptured disc which can be ruptured when the device is activated for use. 3 figs.

  3. Brownian Ratchets: Molecular Separations in Lipid Bilayers

    E-Print Network [OSTI]

    Boxer, Steven G.

    Brownian Ratchets: Molecular Separations in Lipid Bilayers Supported on Patterned Arrays Alexander van Oudenaarden and Steven G. Boxer* Brownian ratchets use a time-varying asymmetric potential that can be applied to separate diffusing particles or molecules. A new type of Brownian ratchet

  4. Separation of regenerated catalyst from combustion products

    SciTech Connect (OSTI)

    Benslay, R. M.

    1984-10-16T23:59:59.000Z

    A method and apparatus for separating regenerated catalyst from gaseous combustion products within a regenerator. The apparatus comprises a downcomer within the regenerator vessel through which the catalyst and gaseous combustion products flow. Means are provided at the lower end of the downcomer for utilizing the momentum of the catalyst particles to separate them from the gaseous combustion products.

  5. Encapsulated Metal Hydride for Hydrogen Separation

    E-Print Network [OSTI]

    concentration feed stock, not for low concentration ­ Hydrogen economy will need hydrogen recovery from lowEncapsulated Metal Hydride for Hydrogen Separation (Formerly Separation Membrane Development) DOE Hydrogen Program 2003 Merit Review and Peer Evaluation L. Kit Heung, Jim Congdon Savannah River Technology

  6. Fabrication of Separator Demonstration Facility process vessel

    SciTech Connect (OSTI)

    Oberst, E.F.

    1985-01-15T23:59:59.000Z

    The process vessel system is the central element in the Separator Development Facility (SDF). It houses the two major process components, i.e., the laser-beam folding optics and the separators pods. This major subsystem is the critical-path procurement for the SDF project. Details of the vaious parts of the process vessel are given.

  7. Source Separation for Hearing Aid Applications

    E-Print Network [OSTI]

    .imm.dtu.dk IMM-PHD: ISSN 0909-3192 #12;Summary The main focuses in this thesis are on blind separation of acoustic signals and on a speech enhancement by time-frequency masking. As a part of the thesis, an exhaustive review on existing techniques for blind separation of convolutive acoustic mixtures is provided

  8. Apparatus and process for separating hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K; Sessions, Henry T; Xiao, Xin

    2013-06-25T23:59:59.000Z

    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  9. Advanced Aqueous Separation Systems for Actinide Partitioning

    SciTech Connect (OSTI)

    Nash, Kenneth L.; Sue Clark; G. Patrick Meier; Spiro Alexandratos; Robert Paine; Robert Hancock; Dale Ensor

    2012-03-21T23:59:59.000Z

    One of the most challenging aspects of advanced processing of spent nuclear fuel is the need to isolate transuranium elements from fission product lanthanides. This project expanded the scope of earlier investigations of americium (Am) partitioning from the lanthanides with the synthesis of new separations materials and a centralized focus on radiochemical characterization of the separation systems that could be developed based on these new materials. The primary objective of this program was to explore alternative materials for actinide separations and to link the design of new reagents for actinide separations to characterizations based on actinide chemistry. In the predominant trivalent oxidation state, the chemistry of lanthanides overlaps substantially with that of the trivalent actinides and their mutual separation is quite challenging.

  10. Gas separation using ultrasound and light absorption

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM)

    2012-07-31T23:59:59.000Z

    An apparatus and method for separating a chosen gas from a mixture of gases having no moving parts and utilizing no chemical processing is described. The separation of particulates from fluid carriers thereof has been observed using ultrasound. In a similar manner, molecular species may be separated from carrier species. It is also known that light-induced drift may separate light-absorbing species from carrier species. Therefore, the combination of temporally pulsed absorption of light with ultrasonic concentration is expected to significantly increase the efficiency of separation by ultrasonic concentration alone. Additionally, breaking the spatial symmetry of a cylindrical acoustic concentrator decreases the spatial distribution of the concentrated particles, and increases the concentration efficiency.

  11. Font d'energia utilitzada abans de l'era dels combustibles f`ossils. Encara es el combustible majorit`ariament usat per a cuinar i escalfar-se

    E-Print Network [OSTI]

    Batiste, Oriol

    ¨isos poc desenvolupats #12;BIOMASSA: Energia Solar Productivitat prim`aria neta PPN: 75 - 125 TW 3000 EJBIOMASSA Font d'energia utilitzada abans de l'era dels combustibles f`ossils. Encara ´es el eficients. #12;CONSUM D'ENERGIA PRIMARIA AL M´ON (420 EJ) #12;BIOMASSA Algunes questions: · Qu`e ´es el

  12. Methods for separating a fluid, and devices capable of separating a fluid

    DOE Patents [OSTI]

    TeGrotenhuis, Ward E; Humble, Paul H; Caldwell, Dustin D

    2013-05-14T23:59:59.000Z

    Methods and apparatus for separating fluids are disclosed. We have discovered that, surprisingly, providing an open pore structure between a wick and an open flow channel resulted in superior separation performance. A novel and compact integrated device components for conducting separations are also described.

  13. Cesium and Strontium Separation Technologies Literature Review

    SciTech Connect (OSTI)

    T. A. Todd; T. A. Todd; J. D. Law; R. S. Herbst

    2004-03-01T23:59:59.000Z

    Integral to the Advanced Fuel Cycle Initiative (AFCI) Programs proposed closed nuclear fuel cycle, the fission products cesium and strontium in the dissolved spent nuclear fuel stream are to be separated and managed separately. A comprehensive literature survey is presented to identify cesium and strontium separation technologies that have the highest potential and to focus research and development efforts on these technologies. Removal of these high-heat-emitting fission products reduces the radiation fields in subsequent fuel cycle reprocessing streams and provides a significant short-term (100 yr) heat source reduction in the repository. This, along with separation of actinides, may provide a substantial future improvement in the amount of fuel that could be stored in a geologic repository. The survey and review of the candidate cesium and strontium separation technologies are presented herein. Because the AFCI program intends to manage cesium and strontium together, technologies that simultaneously separate both elements are of the greatest interest, relative to technologies that separate only one of the two elements.

  14. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  15. Process for separating anthracite coal from impurities

    SciTech Connect (OSTI)

    Stiller, D.W.; Stiller, A.H.

    1985-05-06T23:59:59.000Z

    A process is described for separating a first mixture including previously mined anthracite coal, klinker-type cinder ash and other refuse consisting of: a. separating the first mixture to produce a refuse portion and a second mixture consisting of anthracite and klinker-type cinder ash, b. reducing the average particle size in the second mixture to a uniform size, c. subjecting the second mixture to a separating magnetic field to produce a klinker-type cinder ash portion and an anthracite coal portion.

  16. Separator plate for a fuel cell

    DOE Patents [OSTI]

    Petri, R.J.; Meek, J.; Bachta, R.P.; Marianowski, L.G.

    1996-04-02T23:59:59.000Z

    A separator plate is described for a fuel cell comprising an anode current collector, a cathode current collector and a main plate, the main plate disposed between the anode current collector and the cathode current collector. The anode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the anode side of the separator plate and the cathode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the cathode side of the separator plate. In this manner, the number of components required to manufacture and assemble a fuel cell stack is reduced. 9 figs.

  17. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  18. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  19. Method of separating thorium from plutonium

    DOE Patents [OSTI]

    Clifton, D.G.; Blum, T.W.

    1984-07-10T23:59:59.000Z

    A method is described for chemically separating plutonium from thorium. Plutonium and thorium to be separated are dissolved in an aqueous feed solution, preferably as the nitrate salts. The feed solution is acidified and sodium nitrite is added to the solution to adjust the valence of the plutonium to the +4 state. A chloride salt, preferably sodium chloride, is then added to the solution to induce formation of an anionic plutonium chloride complex. The anionic plutonium chloride complex and the thorium in solution are then separated by ion exchange on a strong base anion exchange column.

  20. Method of separating thorium from plutonium

    DOE Patents [OSTI]

    Clifton, David G. (Los Alamos, NM); Blum, Thomas W. (Los Alamos, NM)

    1984-01-01T23:59:59.000Z

    A method of chemically separating plutonium from thorium. Plutonium and thorium to be separated are dissolved in an aqueous feed solution, preferably as the nitrate salts. The feed solution is acidified and sodium nitrite is added to the solution to adjust the valence of the plutonium to the +4 state. A chloride salt, preferably sodium chloride, is then added to the solution to induce formation of an anionic plutonium chloride complex. The anionic plutonium chloride complex and the thorium in solution are then separated by ion exchange on a strong base anion exchange column.

  1. Separator plate for a fuel cell

    DOE Patents [OSTI]

    Petri, Randy J. (Crete, IL); Meek, John (Downers Grove, IL); Bachta, Robert P. (Chicago, IL); Marianowski, Leonard G. (Mount Prospect, IL)

    1996-01-01T23:59:59.000Z

    A separator plate for a fuel cell comprising an anode current collector, a cathode current collector and a main plate, the main plate disposed between the anode current collector and the cathode current collector. The anode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the anode side of the separator plate and the cathode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the cathode side of the separator plate. In this manner, the number of components required to manufacture and assemble a fuel cell stack is reduced.

  2. A Vortex Contactor for Carbon Dioxide Separations

    SciTech Connect (OSTI)

    Raterman, Kevin Thomas; Mc Kellar, Michael George; Turner, Terry Donald; Podgorney, Anna Kristine; Stacey, Douglas Edwin; Stokes, B.; Vranicar, J.

    2001-05-01T23:59:59.000Z

    Many analysts identify carbon dioxide (CO2) capture and separation as a major roadblock in efforts to cost effectively mitigate greenhouse gas emissions via sequestration. An assessment 4 conducted by the International Energy Agency (IEA) Greenhouse Gas Research and Development Programme cited separation costs from $35 to $264 per tonne of CO2 avoided for a conventional coal fired power plant utilizing existing capture technologies. Because these costs equate to a greater than 40% increase in current power generation rates, it appears obvious that a significant improvement in CO2 separation technology is required if a negative impact on the world economy is to be avoided.

  3. Membrane separation advances in FE hydrogen program

    SciTech Connect (OSTI)

    NONE

    2007-12-31T23:59:59.000Z

    Since its inception in Fiscal Year 2003 the US Office of Fossil Energy (FE) Hydrogen from Coal Program has sponsored more than 60 projects and made advances in the science of separating out pure hydrogen from syngas produced through coal gasification. The Program is focusing on advanced hydrogen separation technologies, which include membranes, and combining the WGS reaction and hydrogen separation in a single operation known as process intensification. The article explains the technologies and describes some key FE membrane projects. More details are available from http://www.fossil.energy.gov. 1 fig.

  4. Particulate residue separators for harvesting devices

    SciTech Connect (OSTI)

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  5. Air separation with temperature and pressure swing

    DOE Patents [OSTI]

    Cassano, Anthony A. (Allentown, PA)

    1986-01-01T23:59:59.000Z

    A chemical absorbent air separation process is set forth which uses a temperature swing absorption-desorption cycle in combination with a pressure swing wherein the pressure is elevated in the desorption stage of the process.

  6. Separation of carbon nanotubes in density gradients

    DOE Patents [OSTI]

    Hersam, Mark C. (Evanston, IL); Stupp, Samuel I. (Chicago, IL); Arnold, Michael S. (Northbrook, IL)

    2012-02-07T23:59:59.000Z

    The separation of single-walled carbon nanotubes (SWNTs), by chirality and/or diameter, using centrifugation of compositions of SWNTs in and surface active components in density gradient media.

  7. Separation of carbon nanotubes in density gradients

    DOE Patents [OSTI]

    Hersam, Mark C. (Evanston, IL); Stupp, Samuel I. (Chicago, IL); Arnold, Michael S. (Northbrook, IL)

    2010-02-16T23:59:59.000Z

    The separation of single-walled carbon nanotubes (SWNTs), by chirality and/or diameter, using centrifugation of compositions of SWNTs in and surface active components in density gradient media.

  8. Hybrid Membranes for Light Gas Separations

    E-Print Network [OSTI]

    Liu, Ting

    2012-07-16T23:59:59.000Z

    Membrane separations provide a potentially attractive technology over conventional processes due to their advantages, such as low capital cost and energy consumption. The goal of this thesis is to design hybrid membranes that facilitate specific gas...

  9. pH-biased isoelectric trapping separations

    E-Print Network [OSTI]

    Shave, Evan Eric

    2006-10-30T23:59:59.000Z

    The classical isoelectric trapping (IET) technique, using the multicompartment electrolyzer (MCE), has been one of the most successful electrophoretic techniques in preparative-scale protein separations. IET is capable of achieving high resolution...

  10. Electrochemically mediated separation for carbon capture

    E-Print Network [OSTI]

    Simeon, Fritz

    Carbon capture technology has been proposed as an effective approach for the mitigation of anthropogenic CO[subscript 2] emissions. Thermal-swing separation technologies based on wet chemical scrubbing show potential for ...

  11. Continuous flow separation techniques for microchemical synthesis

    E-Print Network [OSTI]

    Kralj, Jason G

    2006-01-01T23:59:59.000Z

    Performing multistep microchemical synthesis requires many techniques from combining micromixers in series to the development of continuous microfluidic separation tools. Safety, high heat and mass transfer rates, and cost ...

  12. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, Charles L. (Lincoln, MA); He, Bo X. (Newton, MA)

    1990-01-01T23:59:59.000Z

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from when it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel.

  13. Method for improved gas-solids separation

    DOE Patents [OSTI]

    Kusik, C.L.; He, B.X.

    1990-11-13T23:59:59.000Z

    Methods are disclosed for the removal of particulate solids from a gas stream at high separation efficiency, including the removal of submicron size particles. The apparatus includes a cyclone separator type of device which contains an axially mounted perforated cylindrical hollow rotor. The rotor is rotated at high velocity in the same direction as the flow of an input particle-laden gas stream to thereby cause enhanced separation of particulate matter from the gas stream in the cylindrical annular space between the rotor and the sidewall of the cyclone vessel. Substantially particle-free gas passes through the perforated surface of the spinning rotor and into the hollow rotor, from where it is discharged out of the top of the apparatus. Separated particulates are removed from the bottom of the vessel. 4 figs.

  14. Separability and dynamical symmetry of Quantum Dots

    SciTech Connect (OSTI)

    Zhang, P.-M., E-mail: zhpm@impcas.ac.cn [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou (China); Zou, L.-P., E-mail: zoulp@impcas.ac.cn [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou (China); Horvathy, P.A., E-mail: horvathy@lmpt.univ-tours.fr [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou (China); Laboratoire de Mathmatiques et de Physique Thorique, Tours University (France); Gibbons, G.W., E-mail: G.W.Gibbons@damtp.cam.ac.uk [Department of Applied Mathematics and Theoretical Physics, Cambridge University, Cambridge (United Kingdom)

    2014-02-15T23:59:59.000Z

    The separability and RungeLenz-type dynamical symmetry of the internal dynamics of certain two-electron Quantum Dots, found by Simonovi? et al. (2003), are traced back to that of the perturbed Kepler problem. A large class of axially symmetric perturbing potentials which allow for separation in parabolic coordinates can easily be found. Apart from the 2:1 anisotropic harmonic trapping potential considered in Simonovi? and Nazmitdinov (2013), they include a constant electric field parallel to the magnetic field (Stark effect), the ring-shaped Hartmann potential, etc. The harmonic case is studied in detail. -- Highlights: The separability of Quantum Dots is derived from that of the perturbed Kepler problem. Harmonic perturbation with 2:1 anisotropy is separable in parabolic coordinates. The system has a conserved RungeLenz type quantity.

  15. Flow separation control with rotating cylinders

    E-Print Network [OSTI]

    Schulmeister, James Crandall

    2012-01-01T23:59:59.000Z

    The hydrodynamic forces on ocean vehicles increase dramatically during sharp maneuvers as compared to forward motion due to large areas of separated flow. These large forces severely limit maneuverability and reduce ...

  16. SEPARATIONS AND WASTE FORMS CAMPAIGN IMPLEMENTATION PLAN

    SciTech Connect (OSTI)

    Vienna, John D.; Todd, Terry A.; Peterson, Mary E.

    2012-11-26T23:59:59.000Z

    This Separations and Waste Forms Campaign Implementation Plan provides summary level detail describing how the Campaign will achieve the objectives set-forth by the Fuel Cycle Reasearch and Development (FCRD) Program. This implementation plan will be maintained as a living document and will be updated as needed in response to changes or progress in separations and waste forms research and the FCRD Program priorities.

  17. Laser Isotope Separation Employing Condensation Repression

    SciTech Connect (OSTI)

    Eerkens, Jeff W.; Miller, William H.

    2004-09-15T23:59:59.000Z

    Molecular laser isotope separation (MLIS) techniques using condensation repression (CR) harvesting are reviewed and compared with atomic vapor laser isotope separation (AVLIS), gaseous diffusion (DIF), ultracentrifuges (UCF), and electromagnetic separations (EMS). Two different CR-MLIS or CRISLA (Condensation Repression Isotope Separation by Laser Activation) approaches have been under investigation at the University of Missouri (MU), one involving supersonic super-cooled free jets and dimer formation, and the other subsonic cold-wall condensation. Both employ mixtures of an isotopomer (e.g. {sup i}QF{sub 6}) and a carrier gas, operated at low temperatures and pressures. Present theories of VT relaxation, dimerization, and condensation are found to be unsatisfactory to explain/predict experimental CRISLA results. They were replaced by fundamentally new models that allow ab-initio calculation of isotope enrichments and predictions of condensation parameters for laser-excited and non-excited vapors which are in good agreement with experiment. Because of supersonic speeds, throughputs for free-jet CRISLA are a thousand times higher than cold-wall CRISLA schemes, and thus preferred for large-quantity Uranium enrichments. For small-quantity separations of (radioactive) medical isotopes, the simpler coldwall CRISLA method may be adequate.

  18. Carbometallic oil conversion with ballistic separation

    SciTech Connect (OSTI)

    Walters, P.W.; Benslay, R.M.; Barger, D.F.

    1991-09-03T23:59:59.000Z

    This patent describes improvement in a method for converting carbo-metallic containing residual oils to form upgraded liquid products by mixing. The improvement comprises: discharging the suspension from the reaction zone at a velocity of 55 to 100 ft/sec. imparting greater momentum to the solid particles than to the hydrocarbon product vapors whereby instantaneous separation of at least about 80 wt % of the vapors from the solid particles occurs; encouraging separation of solids from remaining vapors following discharge from the reaction zone by diverting solids from the remaining vapors by directional impingement on a target baffle and by providing a lower pressure vapor recovery zone in open communication with one or more cyclone separation zones outside the reaction zone open end; recovering solid particles separated by momentum from the suspension and diverted laterally from the vapor recovery zone as a mass of collected solid particles; stripping and regenerating the collected the particles in a sequence of separate zones; and recycling hot regenerated solids to the reaction zone for contact with the residual oil feed.

  19. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1991-01-01T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  20. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1990-01-01T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  1. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1991-08-20T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

  2. Asymptotic and measured large frequency separations

    E-Print Network [OSTI]

    Mosser, B; Belkacem, K; Goupil, M J; Baglin, A; Barban, C; Provost, J; Samadi, R; Auvergne, M; Catala, C

    2012-01-01T23:59:59.000Z

    With the space-borne missions CoRoT and Kepler, a large amount of asteroseismic data is now available. So-called global oscillation parameters are inferred to characterize the large sets of stars, to perform ensemble asteroseismology, and to derive scaling relations. The mean large separation is such a key parameter. It is therefore crucial to measure it with the highest accuracy. As the conditions of measurement of the large separation do not coincide with its theoretical definition, we revisit the asymptotic expressions used for analysing the observed oscillation spectra. Then, we examine the consequence of the difference between the observed and asymptotic values of the mean large separation. The analysis is focused on radial modes. We use series of radial-mode frequencies to compare the asymptotic and observational values of the large separation. We propose a simple formulation to correct the observed value of the large separation and then derive its asymptotic counterpart. We prove that, apart from glitc...

  3. Development of FCC catalyst magnetic separation

    SciTech Connect (OSTI)

    Goolsby, T.L.; Moore, H.F. [Ashland Petroleum Co., KY (United States)

    1997-01-01T23:59:59.000Z

    Magnetic separation has been historically active in several different industries, yet has not been utilized in petroleum refining until recently. Development of economical permanent magnets with high magnetic strength has led to a new process known as MagnaCat{reg_sign}. The MagnaCat{reg_sign}. Process separates less active (high metals) particles catalyst from equilibrium Fluid Catalytic Cracking (FCC) catalyst, producing a higher activity/lower metals catalyst for recycle. Pilot FCC studies showed lower hydrogen, dry gas, and coke make with higher wet gas and octane from catalyst separated by MagnaCat{reg_sign}. With the use of a MagnaCat{reg_sign} Process unit, a refiner would produce an economic advantage of $0.20 to $0.40/Barrel of FCC charge and enhance unit operability.

  4. Separation of particles from gaseous fluid flows

    SciTech Connect (OSTI)

    Paul, E.; Reither, K.

    1980-12-16T23:59:59.000Z

    In a gas washer and similar separator devices which utilize stationary wall means to deflect a gas flow and to subject the same to centrifugal force for continuously separating out foreign particulate matter which is collected on or adjacent the stationary wall means, the invention provides spirally curved laminae constituting the stationary wall means and co-operating to define passage means, at least a part of which has a cross-section which first narrows and then widens in the direction of fluid flow and which is also curved spirally first in one and then in the opposite direction. Nozzle means may be arranged to feed moisture into the fluid flow to assist wet separation, and by electrically insulating conductive laminae from one another, the invention may also be used as an electrostatic precipitator.

  5. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22T23:59:59.000Z

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  6. Separation of strontium from fecal matter

    DOE Patents [OSTI]

    Kester, D.K.

    1995-01-03T23:59:59.000Z

    A method is presented of separating strontium from a sample of biomass potentially contaminated with various radionuclides. After the sample is reduced, dissociated, and carried on a first precipitate of actinides, the first precipitate is removed to leave a supernate. Next, oxalic acid is added to the supernate to cause a second precipitate of strontium and calcium. Then, after separating the second precipitate, nitric acid is added to the second precipitate to cause a third precipitate of strontium. The calcium remains in solution and is discarded to leave essentially the precipitate of strontium.

  7. Separation of strontium from fecal matter

    DOE Patents [OSTI]

    Kester, Dianne K. (Idaho Falls, ID)

    1995-01-01T23:59:59.000Z

    A method of separating strontium from a sample of biomass potentially contaminated with various radionuclides. After the sample is reduced, dissociated, and carried on a first precipitate of actinides, the first precipitate is removed to leave a supernate. Next, oxalic acid is added to the supernate to cause a second precipitate of strontium and calcium. Then, after separating the second precipitate, nitric acid is added to the second precipitate to cause a third precipitate of strontium. The calcium remains in solution and is discarded to leave essentially the precipitate of strontium.

  8. Laser-assisted isotope separation of tritium

    DOE Patents [OSTI]

    Herman, Irving P. (Castro Valley, CA); Marling, Jack B. (Livermore, CA)

    1983-01-01T23:59:59.000Z

    Methods for laser-assisted isotope separation of tritium, using infrared multiple photon dissociation of tritium-bearing products in the gas phase. One such process involves the steps of (1) catalytic exchange of a deuterium-bearing molecule XYD with tritiated water DTO from sources such as a heavy water fission reactor, to produce the tritium-bearing working molecules XYT and (2) photoselective dissociation of XYT to form a tritium-rich product. By an analogous procedure, tritium is separated from tritium-bearing materials that contain predominately hydrogen such as a light water coolant from fission or fusion reactors.

  9. Tax consequences of separating corporate businesses

    E-Print Network [OSTI]

    Zuber, Gordon Dewey

    2012-06-07T23:59:59.000Z

    Lips ARY g ~ggpgF ep &Ex' TAX CONSEQUENCES OP SEPARATING CORPORATE BUSINESSES A Thesis Gordon D. Zuber Submitted to the Graduate School of the Agricultural and lNechanical College of Texas in partial fulfillment of the requirements... for the Degree of MASTER OP BUSINESS ADl/iliVISTRAT ION August 1958 Ma)or Subject: Accounting TAX CONSEQUENCES OP SEPARATING CORPORATE BUSINESSES A Thesis Gordon D. Zuber Approved as to style and content by: Chairman of the Committee ead. o the Divas...

  10. Straight-line separation of two polyhedra

    E-Print Network [OSTI]

    Wang, Su-Hua

    1992-01-01T23:59:59.000Z

    STRAIGHT-LINE SEPARATION OF TWO POLYHEDRA A Thesis by SU-HUA WANG Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1992 Major Subject...: Computer Science STRAIGHT-LINE SEPARATION OF TWO POLYHEDRA A Thesis by SU-HUA WANG Approved as to style and content by: Jan Wolter hair of Committee) Donald K. Friesen (Member) esa O. alav ( ember) Richard A, Volz (Head of Department) December...

  11. Simulating spin-charge separation with light

    E-Print Network [OSTI]

    Dimitris G. Angelakis; Mingxia Huo; Elica Kyoseva; Leong Chuan kwek

    2010-06-08T23:59:59.000Z

    In this work we show that stationary light-matter excitations generated inside a hollow one-dimensional waveguide filled with atoms, can be made to generate a photonic two-component Lieb Liniger model. We explain how to prepare and drive the atomic system to a strongly interacting regime where spin-charge separation could be possible. We then proceed by explaining how to measure the corresponding effective spin and charge densities and velocities through standard optical methods based in measuring dynamically the emitted photon intensities or by analyzing the photon spectrum. The relevant interactions exhibit the necessary tunability both to generate and efficiently observe spin charge separation with current technology.

  12. Novel Metallic Membranes for Hydrogen Separation

    SciTech Connect (OSTI)

    Dogan, Omer

    2011-02-27T23:59:59.000Z

    To reduce dependence on oil and emission of greenhouse gases, hydrogen is favored as an energy carrier for the near future. Hydrogen can be converted to electrical energy utilizing fuel cells and turbines. One way to produce hydrogen is to gasify coal which is abundant in the U.S. The coal gasification produces syngas from which hydrogen is then separated. Designing metallic alloys for hydrogen separation membranes which will work in a syngas environment poses significant challenges. In this presentation, a review of technical targets, metallic membrane development activities at NETL and challenges that are facing the development of new technologies will be given.

  13. Frustrated phase separation and high temperature superconductivity

    SciTech Connect (OSTI)

    Emery, V.J. [Brookhaven National Lab., Upton, NY (United States); Kivelson, S.A. [California Univ., Los Angeles, CA (United States). Dept. of Physics

    1992-09-01T23:59:59.000Z

    A dilute system of neutral holes in an antiferromagnet separates into a hole-rich and a hole-poor phase. The phase separation is frustrated by long-range Coulomb interactions but, provided the dielectric constant is sufficiently large, there remain large-amplitude low-energy fluctuations in the hole density at intermediate length scales. The extensive experimental evidence showing that this behavior giver, a reasonable picture of high temperature superconductors is surveyed. Further, it is shown that the scattering of mobile holes from the local density fluctuations may account for the anomalous normal-state properties of high temperature superconductors and also provide the mechanism of pairing.

  14. Frustrated phase separation and high temperature superconductivity

    SciTech Connect (OSTI)

    Emery, V.J. (Brookhaven National Lab., Upton, NY (United States)); Kivelson, S.A. (California Univ., Los Angeles, CA (United States). Dept. of Physics)

    1992-01-01T23:59:59.000Z

    A dilute system of neutral holes in an antiferromagnet separates into a hole-rich and a hole-poor phase. The phase separation is frustrated by long-range Coulomb interactions but, provided the dielectric constant is sufficiently large, there remain large-amplitude low-energy fluctuations in the hole density at intermediate length scales. The extensive experimental evidence showing that this behavior giver, a reasonable picture of high temperature superconductors is surveyed. Further, it is shown that the scattering of mobile holes from the local density fluctuations may account for the anomalous normal-state properties of high temperature superconductors and also provide the mechanism of pairing.

  15. College of Engineering Electromagnetically Enhanced Hydrocyclone for Magnetite Separation during

    E-Print Network [OSTI]

    Demirel, Melik C.

    designed the cyclone; a safer technology aimed at replacing the drum separators. The prototy er increase Electromagnetically Enhanced Hydrocyclone for Magnetite Separation during cyclone; a safer technology aimedPENNSTATE College of Engineering Electromagnetically Enhanced Hydrocyclone for Magnetite Separation

  16. Process, including PSA and membrane separation, for separating hydrogen from hydrocarbons

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Union City, CA); He, Zhenjie (Fremont, CA); Pinnau, Ingo (Palo Alto, CA)

    2001-01-01T23:59:59.000Z

    An improved process for separating hydrogen from hydrocarbons. The process includes a pressure swing adsorption step, a compression/cooling step and a membrane separation step. The membrane step relies on achieving a methane/hydrogen selectivity of at least about 2.5 under the conditions of the process.

  17. Apparatus for centrifugal separation of coal particles

    DOE Patents [OSTI]

    Dickie, William (New Eagle, PA); Cavallaro, Joseph A. (Mt. Keesport, PA); Killmeyer, Richard P. (Pleasant Hills, PA)

    1991-01-01T23:59:59.000Z

    A gravimetric cell for centrifugal separation of fine coal by density has a cylindrical body and a butterfly valve or other apparatus for selectively sealing the body radially across the approximate center of the cylinder. A removable top is provided which seals the cylinder in the centrifuge and in unvented areas.

  18. Cellular/Molecular Separate Ca2

    E-Print Network [OSTI]

    Blohm, Gunnar

    Cellular/Molecular Separate Ca2 Sources Are Buffered by Distinct Ca2 Handling Systems in Aplysia's University, Kingston, Ontario K7L 3N6, Canada AlthoughthecontributionofCa2 bufferingsystemscanvarybetweenneuronaltypesandcellularcompartments,itisunknownwhether distinct Ca2 sources within a neuron have different buffers. As individual Ca2

  19. Metal volatilization and separation during incineration

    SciTech Connect (OSTI)

    Ho, T.C.; Chu, H.W.; Hopper, J.R. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering)

    1993-01-01T23:59:59.000Z

    The US Environmental Protection Agency (US EPA) has reported that metals can account for almost all of the identified risks from a thermal treatment process. Fundamental research leading to better understanding of their behavior and improved control of their emissions is greatly needed. This paper reports studies on metal volatilization and separation during incineration. Metal volatilization studies were carried out in two separate experiments. In the first experiment, the dynamic volatilization characteristics of various metals during the combustion of metal-containing wood pellets were investigated in a high-temperature electric furnace. In addition to uncontrolled volatilization, the potential of employing chemical additives to bind metals and prevent them from volatilizing during combustion was also investigated. The second experiment involved the investigation of metal volatilization characteristics during the thermal treatment of metal-contaminated clay in a fluidized bed unit. The metal species tested in both experiments were compounds of lead and cadmium. Metal capture/separation studies were also carried out in two separate experiments. The first involved the use of sorbents in the combustion chamber to capture metals during the fluidized bed incineration of metal-containing wood pellets. The second experiments, however, employed sorbents to absorb metal vapors in a fluidized-bed waste-heat boiler. The objective of both the experiments is to characterize the metal absorption efficiency associated with the processes.

  20. Separator-spacer for electrochemical systems

    DOE Patents [OSTI]

    Grimes, Patrick G. (Westfield, NJ); Einstein, Harry (Springfield, NJ); Newby, Kenneth R. (Berkeley Heights, NJ); Bellows, Richard J. (Westfield, NJ)

    1983-08-02T23:59:59.000Z

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  1. Composite hydrogen separation element and module

    DOE Patents [OSTI]

    Edlund, D.J.

    1996-03-12T23:59:59.000Z

    There are disclosed improvements in multicomponent composite metal membranes useful for the separation of hydrogen, the improvements comprising the provision of a flexible porous intermediate layer between a support layer and a nonporous hydrogen-permeable coating metal layer, and the provision of a textured coating metal layer. 15 figs.

  2. Chromatographic Separations of Enantiomers and Underivatized Oligosaccharides

    SciTech Connect (OSTI)

    Ying Liu

    2004-12-19T23:59:59.000Z

    My graduate research has focused on separation science and bioanalytical analysis, which emphasized in method development. It includes three major areas: enantiomeric separations using high performance liquid chromatography (HPLC), Super/subcritical fluid chromatography (SFC), and capillary electrophoresis (CE); drug-protein binding behavior studies using CE; and carbohydrate analysis using liquid chromatograph-electrospray ionization mass spectrometry (LC-ESI-MS). Enantiomeric separations continue to be extremely important in the pharmaceutical industry. An in-depth evaluation of the enantiomeric separation capabilities of macrocyclic glycopeptides CSPs with SFC mobile phases was investigated using a set of over 100 chiral compounds. It was found that the macrocyclic based CSPs were able to separate enantiomers of various compounds with different polarities and functionalities. Seventy percent of all separations were achieved in less than 4 min due to the high flow rate (4.0 ml/min) that can be used in SFC. Drug-protein binding is an important process in determining the activity and fate of a drug once it enters the body. Two drug/protein systems have been studied using frontal analysis CE method. More sensitive fluorescence detection was introduced in this assay, which overcame the problem of low sensitivity that is common when using UV detection for drug-protein studies. In addition, the first usage of an argon ion laser with 257 nm beam coupled with CCD camera as a frontal analysis detection method enabled the simultaneous observation of drug fluorescence as well as the protein fluorescence. LC-ESI-MS was used for the separation and characterization of underivatized oligosaccharide mixtures. With the limits of detection as low as 50 picograms, all individual components of oligosaccharide mixtures (up to 11 glucose-units long) were baseline resolved on a Cyclobond I 2000 column and detected using ESI-MS. This system is characterized by high chromatographic resolution, high column stability, and high sensitivity. In addition, this method showed potential usefulness for the sensitive and quick analysis of hydrolysis products of polysaccharides, and for trace level analysis of individual oligosaccharides or oligosaccharide isomers from biological systems.

  3. Section 3161 Rehiring Preference for Eligible Separated Employees

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Section 3161 rehiring preference, if they are separated as a result of: (1) termination for cause; (2) voluntary separation from employment; (3) the normal completion of a...

  4. Novel Application of Air Separation Membranes Reduces NOx Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Application of Air Separation Membranes Reduces NOx Emissions Technology available for licensing: Selective permeation of gases using an air separation membrane. Can be retrofitted...

  5. Effects of cell positive cans and separators on the performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the batteries by more than 13%. Among the five separators studied in this work, polyethylene (PE) separator shows the best electrochemical stability. The cells using...

  6. Multifunctional, Inorganic-Filled Separators for Large Format...

    Broader source: Energy.gov (indexed) [DOE]

    & Publications Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries...

  7. Multifunctional, Inorganic-Filled Separators for Large Format...

    Broader source: Energy.gov (indexed) [DOE]

    Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries 2012 DOE Hydrogen...

  8. Solid-Liquid Separation of Animal Manure and Wastewater

    E-Print Network [OSTI]

    Mukhtar, Saqib; Sweeten, John M.; Auvermann, Brent W.

    1999-10-19T23:59:59.000Z

    Solid-liquid separation is an alternative treatment for animal manure and process-generated wastewater. This publication explains the techniques, equipment, performance and economics of separators....

  9. Accelerated High-Resolution Differential Ion Mobility Separations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Resolution Differential Ion Mobility Separations Using Hydrogen. Accelerated High-Resolution Differential Ion Mobility Separations Using Hydrogen. Abstract: The resolving...

  10. Graphene as the Ultimate Membrane for Gas Separation Project...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Graphene as the Ultimate Membrane for Gas Separation Graphene as the Ultimate Membrane for Gas Separation GraphenePore.jpg Key Challenges: Investigate the permeability and...

  11. Size separation in vibrated granular matter

    E-Print Network [OSTI]

    A. Kudrolli

    2004-02-06T23:59:59.000Z

    We review recent developments in size separation in vibrated granular materials. Motivated by a need in industry to efficiently handle granular materials and a desire to make fundamental advances in non-equilibrium physics, experimental and theoretical investigations have shown size separation to be a complex phenomena. Large particles in a vibrated granular system invariably rise to the top. However, they may also sink to the bottom, or show other patterns depending on subtle variations in physical conditions. While size ratio is a dominant factor, particle specific properties such as density, inelasticity and friction can play an important role. The nature of the energy input, boundary conditions and interstitial air have been also shown to be significant factors in determining spatial distributions. The presence of convection can enhance mixing or lead to size separation. Experimental techniques including direct visualization and magnetic resonance imaging are being used to investigate these properties. Molecular dynamics and Monte Carlo simulation techniques have been developed to probe size separation. Analytical methods such as kinetic theory are being used to study the interplay between particle size and density in the vibro-fluidized regime, and geometric models have been proposed to describe size separation for deep beds. Besides discussing these studies, we will also review the impact of inelastic collision and friction on the density and velocity distributions to gain a deeper appreciation of the non-equilibrium nature of the system. While a substantial number of studies have been accomplished, considerable work is still required to achieve a firm description of the phenomena.

  12. Separations and Actinide Science -- 2005 Roadmap

    SciTech Connect (OSTI)

    Not Available

    2005-09-01T23:59:59.000Z

    The Separations and Actinide Science Roadmap presents a vision to establish a separations and actinide science research (SASR) base composed of people, facilities, and collaborations and provides new and innovative nuclear fuel cycle solutions to nuclear technology issues that preclude nuclear proliferation. This enabling science base will play a key role in ensuring that Idaho National Laboratory (INL) achieves its long-term vision of revitalizing nuclear energy by providing needed technologies to ensure our nation's energy sustainability and security. To that end, this roadmap suggests a 10-year journey to build a strong SASR technical capability with a clear mission to support nuclear technology development. If nuclear technology is to be used to satisfy the expected growth in U.S. electrical energy demand, the once-through fuel cycle currently in use should be reconsidered. Although the once-through fuel cycle is cost-effective and uranium is inexpensive, a once-through fuel cycle requires long-term disposal to protect the environment and public from long-lived radioactive species. The lack of a current disposal option (i.e., a licensed repository) has resulted in accumulation of more than 50,000 metric tons of spent nuclear fuel. The process required to transition the current once-through fuel cycle to full-recycle will require considerable time and significant technical advancement. INL's extensive expertise in aqueous separations will be used to develop advanced separations processes. Computational chemistry will be expanded to support development of future processing options. In the intermediate stage of this transition, reprocessing options will be deployed, waste forms with higher loading densities and greater stability will be developed, and transmutation of long-lived fission products will be explored. SASR will support these activities using its actinide science and aqueous separations expertise. In the final stage, full recycle will be enabled by advanced reactors and reprocessing methods based on pyrochemical methods and by using different fuel cycles that do not readily produce plutonium. SASR will facilitate the deployment of advanced pyrochemical separation technology and support development of reprocessing of thorium-based reactor fuels.

  13. Air separation by the Moltox process

    SciTech Connect (OSTI)

    Erickson, D. C.

    1981-04-01T23:59:59.000Z

    The report describes results of a development program on a new and energy saving process for air separation. The Moltox process involves reversibly reacting oxygen in air with a recirculating salt solution, such that oxygen is extracted without depressurizing the remaining nitrogen. Energy savings of approximately 50% are indicated for this process compared to conventional cryogenic air separation. The development program consisted of design, construction, and operation of a 6 liter/minute pilot plant; optimization of the process flowsheet through computer modelling; investigation of engineering aspects of the process including corrosion, safety, and NO/sub x/ generation; and an economic comparison to conventional cryogenic practice. All objectives were satisfactorily achieved except for continuous operation of the pilot plant, and the modifications necessary to achieve that have been identified. Economically the Moltox process shows a substantial advantage over large scale cryogenic plants which are powered by fuel vice electricity.

  14. Two stroke engine exhaust emissions separator

    DOE Patents [OSTI]

    Turner, Terry D. (Ammon, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Raterman, Kevin T. (Idaho Falls, ID)

    2003-04-22T23:59:59.000Z

    A separator for substantially resolving at least one component of a process stream, such as from the exhaust of an internal combustion engine. The separator includes a body defining a chamber therein. A nozzle housing is located proximate the chamber. An exhaust inlet is in communication with the nozzle housing and the chamber. A nozzle assembly is positioned in the nozzle housing and includes a nozzle moveable within and relative to the nozzle housing. The nozzle includes at least one passage formed therethrough such that a process stream entering the exhaust inlet connection passes through the passage formed in the nozzle and imparts a substantially rotational flow to the process stream as it enters the chamber. A positioning member is configured to position the nozzle relative to the nozzle housing in response to changes in process stream pressure thereby adjusting flowrate of said process stream entering into the chamber.

  15. Two stroke engine exhaust emissions separator

    DOE Patents [OSTI]

    Turner, Terry D. (Ammon, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Raterman, Kevin T. (Idaho Falls, ID)

    2002-01-01T23:59:59.000Z

    A separator for substantially resolving at least one component of a process stream, such as from the exhaust of an internal combustion engine. The separator includes a body defining a chamber therein. A nozzle housing is located proximate the chamber. An exhaust inlet is in communication with the nozzle housing and the chamber. A nozzle assembly is positioned in the nozzle housing and includes a nozzle moveable within and relative to the nozzle housing. The nozzle includes at least one passage formed therethrough such that a process stream entering the exhaust inlet connection passes through the passage formed in the nozzle, which imparts a substantially rotational flow to the process stream as it enters the chamber. A positioning member is configured to position the nozzle relative to the nozzle housing in response to changes in process stream pressure to adjust flowrate of said process stream entering into the chamber.

  16. Charge separation in organic photovoltaic cells

    E-Print Network [OSTI]

    Giazitzidis, Paraskevas; Bisquert, Juan; Vikhrenko, Vyacheslav S

    2014-01-01T23:59:59.000Z

    We consider a simple model for the geminate electron-hole separation process in organic photovoltaicssss cells, in order to illustrate the influence of dimensionality of conducting channels on the efficiency of the process. The Miller-Abrahams expression for the transition rates between nearest neighbor sites was used for simulating random walks of the electron in the Coulomb field of the hole. The non-equilibrium kinetic Monte Carlo simulation results qualitatively confirm the equilibrium estimations, although quantitatively the efficiency of the higher dimensional systems is less pronounced. The lifetime of the electron prior to recombination is approximately equal to the lifetime prior to dissociation. Their values indicate that electrons perform long stochastic walks before they are captured by the collector or recombined. The non-equilibrium free energy considerably differs from the equilibrium one. The efficiency of the separation process decreases with increasing the distance to the collector, and this...

  17. Apparatus for separating and recovering hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01T23:59:59.000Z

    An apparatus for recovering hydrogen and separating its isotopes. The apparatus includes a housing bearing at least a fluid inlet and a fluid outlet. A baffle is disposed within the housing, attached thereto by a bracket. A hollow conduit is coiled about the baffle, in spaced relation to the baffle and the housing. The coiled conduit is at least partially filled with a hydride. The hydride can be heated to a high temperature and cooled to a low temperature quickly by circulating a heat transfer fluid in the housing. The spacing between the baffle and the housing maximizes the heat exchange rate between the fluid in the housing and the hydride in the conduit. The apparatus can be used to recover hydrogen isotopes (protium, deuterium and tritium) from gaseous mixtures, or to separate hydrogen isotopes from each other.

  18. Rotary adsorbers for continuous bulk separations

    DOE Patents [OSTI]

    Baker, Frederick S. (Oak Ridge, TN)

    2011-11-08T23:59:59.000Z

    A rotary adsorber for continuous bulk separations is disclosed. The rotary adsorber includes an adsorption zone in fluid communication with an influent adsorption fluid stream, and a desorption zone in fluid communication with a desorption fluid stream. The fluid streams may be gas streams or liquid streams. The rotary adsorber includes one or more adsorption blocks including adsorbent structure(s). The adsorbent structure adsorbs the target species that is to be separated from the influent fluid stream. The apparatus includes a rotary wheel for moving each adsorption block through the adsorption zone and the desorption zone. A desorption circuit passes an electrical current through the adsorbent structure in the desorption zone to desorb the species from the adsorbent structure. The adsorbent structure may include porous activated carbon fibers aligned with their longitudinal axis essentially parallel to the flow direction of the desorption fluid stream. The adsorbent structure may be an inherently electrically-conductive honeycomb structure.

  19. Development of an Electrochemical Separator and Compressor

    SciTech Connect (OSTI)

    Trent Molter

    2011-04-28T23:59:59.000Z

    Global conversion to sustainable energy is likely to result in a hydrogen-based economy that supports U.S. energy security objectives while simultaneously avoiding harmful carbon emissions. A key hurdle to successful implementation of a hydrogen economy is the low-cost generation, storage, and distribution of hydrogen. One of the most difficult requirements of this transformation is achieving economical, high density hydrogen storage in passenger vehicles. Transportation applications may require compression and storage of high purity hydrogen up to 12,000 psi. Hydrogen production choices range from centralized low-pressure generation of relatively impure gas in large quantities from steam-methane reformer plants to distributed generation of hydrogen under moderate pressure using water electrolysis. The Electrochemical Hydrogen Separator + Compressor (EHS+C) technology separates hydrogen from impurities and then compresses it to high pressure without any moving parts. The Phase I effort resulted in the construction and demonstration of a laboratory-scale hardware that can separate and compress hydrogen from reformate streams. The completion of Phase I has demonstrated at the laboratory scale the efficient separation and compression of hydrogen in a cost effective manner. This was achieved by optimizing the design of the Electrochemical Hydrogen Compression (EHC) cell hardware and verified by parametric testing in single cell hardware. A broad range of commercial applications exist for reclamation of hydrogen. One use this technology would be in combination with commercial fuel cells resulting in a source of clean power, heat, and compressed hydrogen. Other applications include the reclamation of hydrogen from power plants and other industrial equipment where it is used for cooling, recovery of process hydrogen from heat treating processes, and semiconductor fabrication lines. Hydrogen can also be recovered from reformate streams and cryogenic boil-offs using this technology.

  20. Power generation method including membrane separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01T23:59:59.000Z

    A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

  1. Holographic Mutual Information at small separations

    E-Print Network [OSTI]

    Agon, Cesar A

    2015-01-01T23:59:59.000Z

    The holographic mutual information for the small separation of two circles and two strips in 2+1 dimensional space-time is considered based on the known exact minimal surfaces spanning the boundaries on AdS4. The results suggest a universality for the leading term in the short-distance expansion of holographic mutual information. A conjecture for a similar result for d > 2 is also presented, as well as comments about the analogous expansion in conformal field theory.

  2. Separations Technology for Clean Water and Energy

    SciTech Connect (OSTI)

    Jarvinen, Gordon D [Los Alamos National Laboratory

    2012-06-22T23:59:59.000Z

    Providing clean water and energy for about nine billion people on the earth by midcentury is a daunting challenge. Major investments in efficiency of energy and water use and deployment of all economical energy sources will be needed. Separations technology has an important role to play in producing both clean energy and water. Some examples are carbon dioxide capture and sequestration from fossil energy power plants and advanced nuclear fuel cycle scemes. Membrane separations systems are under development to improve the economics of carbon capture that would be required at a huge scale. For nuclear fuel cycles, only the PUREX liquid-liquid extraction process has been deployed on a large scale to recover uranium and plutonium from used fuel. Most current R and D on separations technology for used nuclear fuel focuses on ehhancements to a PUREX-type plant to recover the minor actinides (neptunium, americiu, and curium) and more efficiently disposition the fission products. Are there more efficient routes to recycle the actinides on the horizon? Some new approaches and barriers to development will be briefly reviewed.

  3. Novel, Ceramic Membrane System For Hydrogen Separation

    SciTech Connect (OSTI)

    Elangovan, S.

    2012-12-31T23:59:59.000Z

    Separation of hydrogen from coal gas represents one of the most promising ways to produce alternative sources of fuel. Ceramatec, teamed with CoorsTek and Sandia National Laboratories has developed materials technology for a pressure driven, high temperature proton-electron mixed conducting membrane system to remove hydrogen from the syngas. This system separates high purity hydrogen and isolates high pressure CO{sub 2} as the retentate, which is amenable to low cost capture and transport to storage sites. The team demonstrated a highly efficient, pressure-driven hydrogen separation membrane to generate high purity hydrogen from syngas using a novel ceramic-ceramic composite membrane. Recognizing the benefits and limitations of present membrane systems, the all-ceramic system has been developed to address the key technical challenges related to materials performance under actual operating conditions, while retaining the advantages of thermal and process compatibility offered by the ceramic membranes. The feasibility of the concept has already been demonstrated at Ceramatec. This project developed advanced materials composition for potential integration with water gas shift rectors to maximize the hydrogenproduction.

  4. Phase separation and coarsening in active matter

    E-Print Network [OSTI]

    Giuseppe Gonnella; Davide Marenduzzo; Antonio Suma; Adriano Tiribocchi

    2015-02-08T23:59:59.000Z

    Active systems, or active matter, are self-driven systems which live, or function, far from equilibrium - a paradigmatic example which we focus on here is provided by a suspension of self-motile particles. Active systems are far from equilibrium because their microscopic constituents constantly consume energy from the environment in order to do work, for instance to propel themselves. The nonequilibrium nature of active matter leads to a variety of non-trivial intriguing phenomena. An important one which has recently been the subject of intense interest among biological and soft matter physicists is that of the so-called "motility-induced phase separation", whereby self-propelled particles accumulate into clusters in the absence of any explicit attractive interactions between them. Here we review the physics of motility-induced phase separation, and discuss this phenomenon within the framework of the classic physics of phase separation and coarsening. We also discuss cases where the coarsening may be arrested, either in theories for bacterial colonies or in experiments. Most of this work will focus on the case of run-and-tumble and active Brownian particles in the absence of solvent-mediated hydrodynamic interactions - we will briefly discuss at the end their role, which is not currently fully understood in this context.

  5. Large-Eddy Simulations of Zero-Net-Mass-Flux Jet Based Separation Control in a Canonical Separated

    E-Print Network [OSTI]

    Mittal, Rajat

    Large-Eddy Simulations of Zero-Net-Mass-Flux Jet Based Separation Control in a Canonical Separated by Mittal et al1 for investigating active separation control using zero-net-mass-flux jets. Large. Zero-net-mass-flux forcing of the separated flow at the superharmonics of this baseline lock

  6. Biomolecular transport and separation in nanotubular networks.

    SciTech Connect (OSTI)

    Stachowiak, Jeanne C.; Stevens, Mark Jackson (Sandia National Laboratories, Albuquerque, NM); Robinson, David B.; Branda, Steven S.; Zendejas, Frank; Meagher, Robert J.; Sasaki, Darryl Yoshio; Bachand, George David (Sandia National Laboratories, Albuquerque, NM); Hayden, Carl C.; Sinha, Anupama; Abate, Elisa; Wang, Julia; Carroll-Portillo, Amanda (Sandia National Laboratories, Albuquerque, NM); Liu, Haiqing (Sandia National Laboratories, Albuquerque, NM)

    2010-09-01T23:59:59.000Z

    Cell membranes are dynamic substrates that achieve a diverse array of functions through multi-scale reconfigurations. We explore the morphological changes that occur upon protein interaction to model membrane systems that induce deformation of their planar structure to yield nanotube assemblies. In the two examples shown in this report we will describe the use of membrane adhesion and particle trajectory to form lipid nanotubes via mechanical stretching, and protein adsorption onto domains and the induction of membrane curvature through steric pressure. Through this work the relationship between membrane bending rigidity, protein affinity, and line tension of phase separated structures were examined and their relationship in biological membranes explored.

  7. Method and apparatus for tritiated water separation

    DOE Patents [OSTI]

    Nelson, D.A.; Duncan, J.B.; Jensen, G.A.

    1995-09-19T23:59:59.000Z

    The present invention is a membrane method and apparatus for separating isotopic water constituents from light water. The method involves providing a supported membrane of an aromatic polyphosphazene and pressurizing the water on one side of the membrane thereby forcing the light water through the supported membrane while isotopic water constituents are retained or vice versa. The apparatus of the present invention includes an aromatic polyphosphazene placed on a porous support and means for pressurizing water through the membrane while certain isotopic water constituents are retained. 1 fig.

  8. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C.P.; Rockwood, S.D.; Jensen, R.J.; Lyman, J.L.; Aldridge, J.P. III.

    1987-04-07T23:59:59.000Z

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO[sub 2] laser light may be used to highly enrich [sup 34]S in natural SF[sub 6] and [sup 11]B in natural BCl[sub 3]. 8 figs.

  9. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Lyman, John L. (Los Alamos, NM); Aldridge, III, Jack P. (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

  10. Fluorescent labels and their use in separations

    DOE Patents [OSTI]

    Mathies, Richard A. (El Cerrito, CA); Glazer, Alexander (Orinda, CA); Ju, Jingyue (Berkeley, CA)

    1997-01-01T23:59:59.000Z

    Compositions are provided comprising sets of fluorescent labels carrying pairs of donor and acceptor dye molecules, designed for efficient excitation of the donors at a single wavelength and emission from the acceptor in each of the pairs at different wavelengths. The different molecules having different donor-acceptor pairs can be modified to have substantially the same mobility under separation conditions, by varying the distance between the donor and acceptor in a given pair. Particularly, the fluorescent compositions find use as labels in sequencing nucleic acids.

  11. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01T23:59:59.000Z

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  12. Separating Cloud Forming Nuclei from Interstitial Aerosol

    SciTech Connect (OSTI)

    Kulkarni, Gourihar R.

    2012-09-12T23:59:59.000Z

    It has become important to characterize the physicochemical properties of aerosol that have initiated the warm and ice clouds. The data is urgently needed to better represent the aerosol-cloud interaction mechanisms in the climate models. The laboratory and in-situ techniques to separate precisely the aerosol particles that act as cloud condensation nuclei (CCN) and ice nuclei (IN), termed as cloud nuclei (CN) henceforth, have become imperative in studying aerosol effects on clouds and the environment. This review summarizes these techniques, design considerations, associated artifacts and challenges, and briefly discusses the need for improved designs to expand the CN measurement database.

  13. Metal oxide membranes for gas separation

    DOE Patents [OSTI]

    Anderson, M.A.; Webster, E.T.; Xu, Q.

    1994-08-30T23:59:59.000Z

    A method for formation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation. 4 figs.

  14. Metal oxide membranes for gas separation

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI); Webster, Elizabeth T. (Madison, WI); Xu, Qunyin (Plainsboro, NJ)

    1994-01-01T23:59:59.000Z

    A method for permformation of a microporous ceramic membrane onto a porous support includes placing a colloidal suspension of metal oxide particles on one side of the porous support and exposing the other side of the porous support to a drying stream of gas or a reactive gas stream so that the particles are deposited on the drying side of the support as a gel. The gel so deposited can be sintered to form a supported ceramic membrane having mean pore sizes less than 30 Angstroms and useful for ultrafiltration, reverse osmosis, or gas separation.

  15. Membranes for separation of carbon dioxide

    DOE Patents [OSTI]

    Ku, Anthony Yu-Chung (Rexford, NY); Ruud, James Anthony (Delmar, NY); Ramaswamy, Vidya (Niskayuna, NY); Willson, Patrick Daniel (Latham, NY); Gao, Yan (Niskayuna, NY)

    2011-03-01T23:59:59.000Z

    Methods for separating carbon dioxide from a fluid stream at a temperature higher than about 200.degree. C. with selectivity higher than Knudsen diffusion selectivity include contacting a porous membrane with the fluid stream to preferentially transport carbon dioxide. The porous membrane includes a porous support and a continuous porous separation layer disposed on a surface of the porous support and extending between the fluid stream and the porous support layer. The porous support comprises alumina, silica, zirconia, stabilized zirconia, stainless steel, titanium, nickel-based alloys, aluminum-based alloys, zirconium-based alloys or a combination thereof. Median pore size of the porous separation layer is less than about 10 nm, and the porous separation layer comprises titania, MgO, CaO, SrO, BaO, La.sub.2O.sub.3, CeO.sub.2, HfO.sub.2, Y.sub.2O.sub.3, VO.sub.z, NbO.sub.z, TaO.sub.z, ATiO.sub.3, AZrO.sub.3, AAl.sub.2O.sub.4, A.sup.1FeO.sub.3, A.sup.1MnO.sub.3, A.sup.1CoO.sub.3, A.sup.1NiO.sub.3, A.sup.2HfO.sub.3, A.sup.3 CeO.sub.3, Li.sub.2ZrO.sub.3, Li.sub.2SiO.sub.3, Li.sub.2TiO.sub.3, Li.sub.2HfO.sub.3, A.sup.4N.sup.1.sub.yO.sub.z, Y.sub.xN.sup.1.sub.yO.sub.z, La.sub.xN.sup.1.sub.yO.sub.z, HfN.sup.2.sub.yO.sub.z, or a combination thereof; wherein A is La, Mg, Ca, Sr or Ba; A.sup.1 is La, Ca, Sr or Ba; A.sup.2 is Ca, Sr or Ba; A.sup.3 is Sr or Ba; A.sup.4 is Mg, Ca, Sr, Ba, Ti or Zr; N.sup.1 is V, Nb, Ta, Cr, Mo, W, Mn, Si or Ge; N.sup.2 is V, Mo, W or Si; x is 1 or 2; y ranges from 1 to 3; and z ranges from 2 to 7.

  16. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

    1988-06-14T23:59:59.000Z

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  17. Lab announces results of Voluntary Separation Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformationPostdocs space control NewsUW MadisonVoluntary Separation

  18. Super Separator | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystalline Gallium OxideSumin Kim Sumin KimSunil K. Sinha,Super Separator

  19. Plutonium Chemistry in the UREX+ Separation Processes

    SciTech Connect (OSTI)

    ALena Paulenova; George F. Vandegrift, III; Kenneth R. Czerwinski

    2009-10-01T23:59:59.000Z

    The project "Plutonium Chemistry in the UREX+ Separation Processes is led by Dr. Alena Paulenova of Oregon State University under collaboration with Dr. George Vandegrift of ANL and Dr. Ken Czerwinski of the University of Nevada at Las Vegas. The objective of the project is to examine the chemical speciation of plutonium in UREX+ (uranium/tributylphosphate) extraction processes for advanced fuel technology. Researchers will analyze the change in speciation using existing thermodynamics and kinetic computer codes to examine the speciation of plutonium in aqueous and organic phases. They will examine the different oxidation states of plutonium to find the relative distribution between the aqueous and organic phases under various conditions such as different concentrations of nitric acid, total nitrates, or actinide ions. They will also utilize techniques such as X-ray absorbance spectroscopy and small-angle neutron scattering for determining plutonium and uranium speciation in all separation stages. The project started in April 2005 and is scheduled for completion in March 2008.

  20. Cu--Pd--M hydrogen separation membranes

    DOE Patents [OSTI]

    Do{hacek over (g)}an, Omer N; Gao, Michael C; Young, Rongxiang Hu; Tafen, De Nyago

    2013-12-17T23:59:59.000Z

    The disclosure provides an H2 separation membrane comprised of an allow having the composition Cu.Sub.(100-x-y)Pd.sub.xM.sub.y, where x is from about 35 to about 50 atomic percent and where y is from greater than 0 to about 20 atomic percent, and where M consists of magnesium, yttrium, aluminum, titanium, lanthanum, or combinations thereof. The M elements act as strong stabilizers for the B2 phase of the allow, and extend the critical temperature of the alloy for a given hydrogen concentration and pressure. Due to the phase stabilization and the greater temperature range over which a B2 phase can be maintained, the allow is well suited for service as a H2 separation membrane, particularly when applicable conditions are established or cycled above about 600.degree. C. over the course of expected operations. In certain embodiments, the B2 phase comprises at least 60 estimated volume percent of the allow at a steady-state temperature of 400.degree. C. The B2 phase stability is experimentally validated through HT-XRD.

  1. Development of an electrochemical hydrogen separator

    SciTech Connect (OSTI)

    Abens, S.; Fruchtman, J.; Kush, A.

    1993-09-01T23:59:59.000Z

    The EHS is an electrochemical hydrogen separator based on the uniquely reversible nature of hydrogen oxidation-reduction reactions in electrochemical systems. The principle and the hardware concept are shown in Figure 1. Hydrogen from the mixed gas stream is oxidized to H{sup +} ions, transported through a cation transport electrolyte membrane (matrix) under an applied electric field and discharged in a pure hydrogen state on the cathode. The cation transfer electrolyte membrane provides a barrier between the feed and product gases. The EHS design is an offshoot of phosphoric acid fuel cell development. Although any proton transfer electrolyte can be used, the phosphoric acid based system offers a unique advantage because its operating temperature of {approximately}200{degree}C makes it tolerant to trace CO and also closely matches the water-shift reactor exit gas temperature ({approximately}250{degree}C). Hydrogen-containing streams in coal gasification systems have large carbon monoxide contents. For efficient hydrogen recovery, most of the CO must be converted to hydrogen by the low temperature water-shift reaction (Figure 2). Advanced coal gasification and gas separation technologies offer an important pathway to the clean utilization of coal resources.

  2. Functionalized inorganic membranes for gas separation

    DOE Patents [OSTI]

    Ku, Anthony Yu-Chung (Rexford, NY); Ruud, James Anthony (Delmar, NY); Molaison, Jennifer Lynn (Marietta, GA); Schick, Louis Andrew ,(Delmar, NY); Ramaswamy, Vidya (Niskayuna, NY)

    2008-07-08T23:59:59.000Z

    A porous membrane for separation of carbon dioxide from a fluid stream at a temperature higher than about 200.degree. C. with selectivity higher than Knudsen diffusion selectivity. The porous membrane comprises a porous support layer comprising alumina, silica, zirconia or stabilized zirconia; a porous separation layer comprising alumina, silica, zirconia or stabilized zirconia, and a functional layer comprising a ceramic oxide contactable with the fluid stream to preferentially transport carbon dioxide. In particular, the functional layer may be MgO, CaO, SrO, BaO, La.sub.2O.sub.3, CeO.sub.2, ATiO.sub.3, AZrO.sub.3, AAl.sub.2O.sub.4, A.sup.1FeO.sub.3, A.sup.1MnO.sub.3, A.sup.1CoO.sub.3, A.sup.1NiO.sub.3, A.sup.2HfO.sub.3, A.sup.3CeO.sub.3, Li.sub.2ZrO.sub.3, Li.sub.2SiO.sub.3, Li.sub.2TiO.sub.3 or a mixture thereof; wherein A is Mg, Ca, Sr or Ba; A.sup.1 is La, Ca, Sr or Ba; A.sup.2 is Ca, Sr or Ba; and A.sup.3 is Sr or Ba.

  3. Separable states improve protocols with restricted randomness

    E-Print Network [OSTI]

    T. K. Chuan; T. Paterek

    2014-10-07T23:59:59.000Z

    It is known from Bell's theorem that quantum predictions for some entangled states cannot be mimicked using local hidden variable (LHV) models. From a computer science perspective, LHV models may be interpreted as classical computers operating on a potentially infinite number of correlated bits originating from a common source. As such, Bell inequality violations achieved through entangled states are able to characterise the quantum advantage of certain tasks, so long as the task itself imposes no restriction on the availability of correlated bits. However, if the number of shared bits is limited, additional constraints are placed on the possible LHV models and separable, i.e. disentangled, states may become a useful resource. Bell violations are therefore no longer necessary to achieve a quantum advantage. Here we show that in particular, separable states may improve the so-called random access codes, which is a class of communication problems where one party tries to read a portion of the data held by another distant party in presence of finite shared randomness and limited classical communication. We also show how the bias of classical bits can be used to avoid wrong answers in order to achieve the optimal classical protocol and how the advantage of quantum protocols is linked to quantum discord.

  4. Electrochemically-mediated amine regeneration for carbon dioxide separations

    E-Print Network [OSTI]

    Stern, Michael C. (Michael Craig)

    2014-01-01T23:59:59.000Z

    This thesis describes a new strategy for carbon dioxide (CO?) separations based on amine sorbents, which are electrochemically-mediated to facilitate the desorption and regeneration steps of the separation cycle. The ...

  5. Alpha phase precipitation from phase-separated beta phase in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alpha phase precipitation from phase-separated beta phase in a model Ti-Mo-Al alloy studied by direct coupling of transmission Alpha phase precipitation from phase-separated beta...

  6. Isotopic Effect on Ion Mobility and Separation of Isotopomers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect on Ion Mobility and Separation of Isotopomers by High-Field Ion Mobility Spectrometry . Isotopic Effect on Ion Mobility and Separation of Isotopomers by High-Field Ion...

  7. Feedback control of flow separation using synthetic jets

    E-Print Network [OSTI]

    Kim, Kihwan

    2006-04-12T23:59:59.000Z

    The primary goal of this research is to assess the effect of synthetic jets on flow separation and provide a feedback control strategy for flow separation using synthetic jets. The feedback control synthesis is conducted based upon CFD simulation...

  8. Multifunctional, Inorganic-Filled Separators for Large Format...

    Broader source: Energy.gov (indexed) [DOE]

    for excellent power capability Separator morphology --- 67% Al 2 O 3 Surface Fracture Fracture SEM --- 67% Al 2 O 3 Separator morphology --- 69% SiO 2 Surface Fracture...

  9. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

  10. michael smith ornlradioactive beams: equipment & techniques recoil separators

    E-Print Network [OSTI]

    michael smith ornlradioactive beams: equipment & techniques recoil separators approach! · directly Smith, Rolfs, Barnes NIMA306 (1991) 233 #12;michael smith ornlradioactive beams: equipment & techniques;michael smith ornlradioactive beams: equipment & techniques recoil separators proof of concept with 12C

  11. Marine clathrate mining and sediment separation

    DOE Patents [OSTI]

    Borns, David J. (Albuquerque, NM); Hinkebein, Thomas E. (Albuquerque, NM); Lynch, Richard W. (Albuquerque, NM); Northrop, David A. (Albuquerque, NM)

    2001-01-01T23:59:59.000Z

    A method and apparatus for mining of hydrocarbons from a hydrocarbon-containing clathrate such as is found on the ocean floor. The hydrocarbon containing clathrate is disaggregated from sediment by first disrupting clathrate-containing strata using continuous mining means such as a rotary tilling drum, a fluid injector, or a drill. The clathrate-rich portion of sediment thus disrupted from the sea floor strata are carried through the apparatus to regions of relative lower pressure and/or relative higher temperature where the clathrate further dissociates into component hydrocarbons and water. The hydrocarbon is recovered with the assistance of a gas that is injected and buoys the hydrocarbon containing clathrate helping it to rise to regions of lower pressure and temperature where hydrocarbon is released. The sediment separated from the hydrocarbon returns to the ocean floor.

  12. The Elliptic Billiard: Subtleties of Separability

    E-Print Network [OSTI]

    R. van Zon; Th. W. Ruijgrok

    1997-02-10T23:59:59.000Z

    Some of the subtleties of the integrability of the elliptic quantum billiard are discussed. A well known classical constant of the motion has in the quantum case an ill-defined commutator with the Hamiltonian. It is shown how this problem can be solved. A geometric picture is given revealing why levels of a separable system cross. It is shown that the repulsions found by Ayant and Arvieu are computational effects and that the method used by Traiber et al. is related to the present picture which explains the crossings they find. An asymptotic formula for the energy-levels is derived and it is found that the statistical quantities of the spectrum P(s) and \\Delta(L) have the form expected for an integrable system.

  13. Separable geodesic action slicing in stationary spacetimes

    E-Print Network [OSTI]

    Donato Bini; Andrea Geralico; Robert T. Jantzen

    2014-08-22T23:59:59.000Z

    A simple observation about the action for geodesics in a stationary spacetime with separable geodesic equations leads to a natural class of slicings of that spacetime whose orthogonal geodesic trajectories represent freely falling observers. The time coordinate function can then be taken to be the observer proper time, leading to a unit lapse function. This explains some of the properties of the original Painlev\\'e-Gullstrand coordinates on the Schwarzschild spacetime and their generalization to the Kerr-Newman family of spacetimes, reproducible also locally for the G\\"odel spacetime. For the static spherically symmetric case the slicing can be chosen to be intrinsically flat with spherically symmetric geodesic observers, leaving all the gravitational field information in the shift vector field.

  14. Permeable polyaniline articles for gas separation

    DOE Patents [OSTI]

    Wang, Hsing-Lin (Los Alamos, NM); Mattes, Benjamin R. (Santa Fe, NM)

    2009-07-21T23:59:59.000Z

    Immersion precipitation of solutions having 15%-30% (w/w) and various molecular weights of the emeraldine base form of polyaniline in polar aprotic solvents are shown to form integrally skinned asymmetric membranes and fibers having skin layers <1 .mu.m thick which exhibit improved rates of gas transport while preserving good selectivity. These membranes can be further transformed by an acid doping process after fabrication to achieve excellent permeation rates and high selectivities for particular gas separations. Prior to the use of concentrated EB solutions, the formation of integrally skinned asymmetric membranes was not possible, since films and fibers made from <5% w/w polyaniline solutions were found to disintegrate during the IP process.

  15. Permeable polyaniline articles for gas separation

    DOE Patents [OSTI]

    Wang, Hsing-Lin; Mattes, Benjamin R.

    2004-09-28T23:59:59.000Z

    Immersion precipitation of solutions having 15%-30% (w/w) and various molecular weights of the emeraldine base form of polyaniline in polar aprotic solvents are shown to form integrally skinned asymmetric membranes and fibers having skin layers <1 .mu.m thick which exhibit improved rates of gas transport while preserving good selectivity. These membranes can be further transformed by an acid doping process after fabrication to achieve excellent permeation rates and high selectivities for particular gas separations. Prior to the use of concentrated EB solutions, the formation of integrally skinned asymmetric membranes was not possible, since films and fibers made from <5% w/w polyaniline solutions were found to disintegrate during the IP process.

  16. Immobilized fluid membranes for gas separation

    DOE Patents [OSTI]

    Liu, Wei; Canfield, Nathan L; Zhang, Jian; Li, Xiaohong Shari; Zhang, Jiguang

    2014-03-18T23:59:59.000Z

    Provided herein are immobilized liquid membranes for gas separation, methods of preparing such membranes and uses thereof. In one example, the immobilized membrane includes a porous metallic host matrix and an immobilized liquid fluid (such as a silicone oil) that is immobilized within one or more pores included within the porous metallic host matrix. The immobilized liquid membrane is capable of selective permeation of one type of molecule (such as oxygen) over another type of molecule (such as water). In some examples, the selective membrane is incorporated into a device to supply oxygen from ambient air to the device for electrochemical reactions, and at the same time, to block water penetration and electrolyte loss from the device.

  17. Advances and problems in plasma-optical mass-separation

    SciTech Connect (OSTI)

    Bardakov, V. M.; Ivanov, S. D.; Strokin, N. A. [Institute for Physics and Technology, Irkutsk State Technical University, Irkutsk, Ulitsa Lermontova, 83, 664074 Irkutsk (Russian Federation)] [Institute for Physics and Technology, Irkutsk State Technical University, Irkutsk, Ulitsa Lermontova, 83, 664074 Irkutsk (Russian Federation)

    2014-03-15T23:59:59.000Z

    This paper presents a short review of plasma-optical mass-separation and defines the fields for its possible application. During theoretical studies, numerical simulations, and experiments, the effect of the azimuthator finite size and of the vacuum conditions on the mass separator characteristics was revealed, as well as the quality of different-mass ion separation. The problems, solving which may lead to a successful end of the mass-separation plasma-optical technique implementation, were specified.

  18. MassMass transfer andtransfer and separation technologyseparation technology

    E-Print Network [OSTI]

    Zevenhoven, Ron

    - kemiteknik - Vrme- och strmningsteknik Biskopsgatan 8, 20500 bo 4 #12;Example: Natural gas separationExample: Natural gas separationeknik Example: Natural gas separationExample: Natural gas separation .htmlSepa A porous polymer, ceramic or metal, or A liquid or gas N l l b 4 erfringo Natural polymers may be wood

  19. Blind Separation of Filtered Sources Using State-Space Approach

    E-Print Network [OSTI]

    Cichocki, Andrzej

    Blind Separation of Filtered Sources Using State-Space Approach Liqing Zhang and Andrzej Cichockiy to multichannel blind separation/generalized deconvolution, assuming that both mixing and demixing models are described by stable linear state-space sys- tems. We decompose the blind separation problem into two pro

  20. Blind Source Separation and the Analysis of Microarray Data

    E-Print Network [OSTI]

    Torrsani, Bruno

    1 Blind Source Separation and the Analysis of Microarray Data P. Chiappetta, M.C. Roubaud, B. Torr expression data, based upon blind source separation techniques. This approach exploits higher order validates the proposed approach. Keywords gene expression data, blind source separation, independent

  1. Separating Signal from Noise in Global Warming Bert W. Rust

    E-Print Network [OSTI]

    Rust, Bert W.

    Separating Signal from Noise in Global Warming Bert W. Rust Reprinted from the CD Rust, B. W. (2003) "Separating Signal from Noise in Global Warming," Computing Science and Statistics, 35, 263-277. ­ or ­ Rust, B. W. (2003) "Separating Signal from Noise in Global Warming," Computing Science and Statistics, 35

  2. Diesel: Applying Privilege Separation to Database Adrienne Porter Felt

    E-Print Network [OSTI]

    Wagner, David

    Diesel: Applying Privilege Separation to Database Access Adrienne Porter Felt Matthew Finifter Joel to lists, requires prior specific permission. #12;Diesel: Applying Privilege Separation to Database Access and code reviewers. We design and construct a system called Diesel, which implements data separation

  3. Four-port gas separation membrane module assembly

    DOE Patents [OSTI]

    Wynn, Nicholas P. (Redwood City, CA); Fulton, Donald A. (Fairfield, CA); Lokhandwala, Kaaeid A. (Fremont, CA); Kaschemekat, Jurgen (Campbell, CA)

    2010-07-20T23:59:59.000Z

    A gas-separation membrane assembly, and a gas-separation process using the assembly. The assembly incorporates multiple gas-separation membranes in an array within a single vessel or housing, and is equipped with two permeate ports, enabling permeate gas to be withdrawn from both ends of the membrane module permeate pipes.

  4. Separation of carbon nanotubes into chirally enriched fractions

    DOE Patents [OSTI]

    Doorn, Stephen K. (Los Alamos, NM); Niyogi, Sandip (Los Alamos, NM)

    2012-04-10T23:59:59.000Z

    A mixture of single-walled carbon nanotubes ("SWNTs") is separated into fractions of enriched chirality by preparing an aqueous suspension of a mixture of SWNTs and a surfactant, injecting a portion of the suspension on a column of separation medium having a density gradient, and centrifuging the column. In some embodiments, salt is added prior to centrifugation. In other embodiments, the centrifugation is performed at a temperature below room temperature. Fractions separate as colored bands in the column. The diameter of the separated SWNTs decreases with increasing density along the gradient of the column. The colored bands can be withdrawn separately from the column.

  5. Secondary battery containing zinc electrode with modified separator and method

    DOE Patents [OSTI]

    Poa, D.S.

    1984-02-16T23:59:59.000Z

    A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

  6. Activated Carbon Composites for Air Separation

    SciTech Connect (OSTI)

    Baker, Frederick S [ORNL; Contescu, Cristian I [ORNL; Tsouris, Costas [ORNL; Burchell, Timothy D [ORNL

    2011-09-01T23:59:59.000Z

    Coal-derived synthesis gas is a potential major source of hydrogen for fuel cells. Oxygen-blown coal gasification is an efficient approach to achieving the goal of producing hydrogen from coal, but a cost-effective means of enriching O2 concentration in air is required. A key objective of this project is to assess the utility of a system that exploits porous carbon materials and electrical swing adsorption to produce an O2-enriched air stream for coal gasification. As a complement to O2 and N2 adsorption measurements, CO2 was used as a more sensitive probe molecule for the characterization of molecular sieving effects. To further enhance the potential of activated carbon composite materials for air separation, work was implemented on incorporating a novel twist into the system; namely the addition of a magnetic field to influence O2 adsorption, which is accompanied by a transition between the paramagnetic and diamagnetic states. The preliminary findings in this respect are discussed.

  7. Blind Source Separation For Ion Mobility Spectra

    SciTech Connect (OSTI)

    Marco, S.; Pomareda, V. [Department of Electronics, University of Barcelona, C/Marti i Franques, no 1, planta 2, 08028, Barcelona (Spain); Artificial Olfaction Lab, Institute of BioEngineering of Catalonia and Institut de Bioenginyeria de Catalunya (IBEC), C/Baldiri Reixac 13, 08028 Barcelona (Spain); Pardo, A. [Department of Electronics, University of Barcelona, C/Marti i Franques, no 1, planta 2, 08028, Barcelona (Spain); Kessler, M.; Goebel, J.; Mueller, G. [Department LG-SI 2, EADS Innovation Works, EADS Deutschland GmbH and EADS Innovation Works, Dept. IW-SI-Sensors, Electronics and Systems Integration, 81663 Muenchen (Germany)

    2009-05-23T23:59:59.000Z

    Miniaturization is a powerful trend for smart chemical instrumentation in a diversity of applications. It is know that miniaturization in IMS leads to a degradation of the system characteristics. For the present work, we are interested in signal processing solutions to mitigate limitations introduced by limited drift tube length that basically involve a loss of chemical selectivity. While blind source separation techniques (BSS) are popular in other domains, their application for smart chemical instrumentation is limited. However, in some conditions, basically linearity, BSS may fully recover the concentration time evolution and the pure spectra with few underlying hypothesis. This is extremely helpful in conditions where non-expected chemical interferents may appear, or unwanted perturbations may pollute the spectra. SIMPLISMA has been advocated by Harrington et al. in several papers. However, more modern methods of BSS for bilinear decomposition with the restriction of positiveness have appeared in the last decade. In order to explore and compare the performances of those methods a series of experiments were performed.

  8. Integration of advanced nuclear materials separation processes

    SciTech Connect (OSTI)

    Jarvinen, G.D.; Worl, L.A.; Padilla, D.D.; Berg, J.M.; Neu, M.P.; Reilly, S.D.; Buelow, S.

    1998-12-31T23:59:59.000Z

    This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project has examined the fundamental chemistry of plutonium that affects the integration of hydrothermal technology into nuclear materials processing operations. Chemical reactions in high temperature water allow new avenues for waste treatment and radionuclide separation.Successful implementation of hydrothermal technology offers the potential to effective treat many types of radioactive waste, reduce the storage hazards and disposal costs, and minimize the generation of secondary waste streams. The focus has been on the chemistry of plutonium(VI) in solution with carbonate since these are expected to be important species in the effluent from hydrothermal oxidation of Pu-containing organic wastes. The authors investigated the structure, solubility, and stability of the key plutonium complexes. Installation and testing of flow and batch hydrothermal reactors in the Plutonium Facility was accomplished. Preliminary testing with Pu-contaminated organic solutions gave effluent solutions that readily met discard requirements. A new effort in FY 1998 will build on these promising initial results.

  9. Charge separation in photoredox reactions. Final report

    SciTech Connect (OSTI)

    Kevan, L.

    1993-07-15T23:59:59.000Z

    The structural aspects controlling charge separation in molecular photoionization reactions in organized molecular assemblies involving micelles, reverse micelles and vesicles are being studied by optical and electron magnetic resonance techniques including the time domain technique of deuterium electron spin echo modulation (ESEM) and matrix proton electron nuclear double resonance (ENDOR) to measure weak electron-nuclear dipolar interactions. ESEM and matrix ENDOR are particularly well adapted to the study of disordered systems as exemplified by micelles and vesicles. The photoionization yields of alkylphenothiazines in micelles and vesicles have been shown to depend on the alkyl chain length and to correlate with relative distances from the surfactant assembly interface measured by deuterium ESEM and matrix proton ENDOR. The photoionization of alkylmethylviologens versus alkyl chain length has also been studied in vesicles, micelles and reverse micelles. Nitroxide spin probes have been used to study the degree of water penetration into mixed ionic/nonionic poly(ethylene oxide) and cationic/anionic micelles by using ESEM methods and selectively deuterated surfactants. The effect of urea interaction at micellar interfaces on the interface hydration has also been evaluated by studying nitroxide probes with ESEM.

  10. Actinide and lanthanide separation process (ALSEP)

    DOE Patents [OSTI]

    Guelis, Artem V.

    2013-01-15T23:59:59.000Z

    The process of the invention is the separation of minor actinides from lanthanides in a fluid mixture comprising, fission products, lanthanides, minor actinides, rare earth elements, nitric acid and water by addition of an organic chelating aid to the fluid; extracting the fluid with a solvent comprising a first extractant, a second extractant and an organic diluent to form an organic extractant stream and an aqueous raffinate. Scrubbing the organic stream with a dicarboxylic acid and a chelating agent to form a scrubber discharge. The scrubber discharge is stripped with a simple buffering agent and a second chelating agent in the pH range of 2.5 to 6.1 to produce actinide and lanthanide streams and spent organic diluents. The first extractant is selected from bis(2-ethylhexyl)hydrogen phosphate (HDEHP) and mono(2-ethylhexyl)2-ethylhexyl phosphonate (HEH(EHP)) and the second extractant is selected from N,N,N,N-tetra-2-ethylhexyl diglycol amide (TEHDGA) and N,N,N',N'-tetraoctyl-3-oxapentanediamide (TODGA).

  11. Conditions for uniqueness of product representations for separable quantum channels and separable quantum states

    E-Print Network [OSTI]

    Scott M. Cohen

    2014-05-29T23:59:59.000Z

    We give a sufficient condition that an operator sum representation of a separable quantum channel in terms of product operators is the unique product representation for that channel, and then provide examples of such channels for any number of parties. This result has implications for efforts to determine whether or not a given separable channel can be exactly implemented by local operations and classical communication. By the Choi-Jamiolkowski isomorphism, it also translates to a condition for the uniqueness of product state ensembles representing a given quantum state. These ideas follow from considerations concerning whether or not a subspace spanned by a given set of product operators contains at least one additional product operator.

  12. Membrane separation systems---A research and development needs assessment

    SciTech Connect (OSTI)

    Baker, R.W. (Membrane Technology and Research, Inc., Menlo Park, CA (USA)); Cussler, E.L. (Minnesota Univ., Minneapolis, MN (USA). Dept. of Chemical Engineering and Materials Science); Eykamp, W. (California Univ., Berkeley, CA (USA)); Koros, W.J. (Texas Univ., Austin, TX (USA)); Riley, R.L. (Separation Systems Technology, San Diego, CA (USA)); Strathmann, H. (Fraunhofer-Institut fuer Grenzflaech

    1990-03-01T23:59:59.000Z

    Membrane based separation technology, a relative newcomer on the separations scene, has demonstrated the potential of saving enormous amounts of energy in the processing industries if substituted for conventional separation systems. Over 1 quad annually, out of 2.6, can possibly be saved in liquid-to-gas separations, alone, if membrane separation systems gain wider acceptance, according to a recent DOE/OIP (DOE/NBM-80027730 (1986)) study. In recent years great strides have been made in the field and offer even greater energy savings in the future when substituted for other conventional separation techniques such as distillation, evaporation, filtration, sedimentation, and absorption. An assessment was conducted by a group of six internationally known membrane separations experts who examined the worldwide status of research in the seven major membrane areas. This encompassed four mature technology areas: reverse osmosis, micorfiltration, ultrafiltration, and electrodialysis; two developing areas: gas separation and and pervaporation; and one emerging technology: facilitated transport. Particular attention was paid to identifying the innovative processes currently emerging, and even further improvements which could gain wider acceptance for the more mature membrane technology. The topics that were pointed out as having the greatest research emphasis are pervaporation for organic-organic separations; gas separation; micorfiltration; an oxidant-resistant reverse osmosis membrane; and a fouling-resistant ultrafiltration membrane. 35 refs., 6 figs., 22 tabs.

  13. Oil/gas collector/separator for underwater oil leaks

    DOE Patents [OSTI]

    Henning, Carl D. (Livermore, CA)

    1993-01-01T23:59:59.000Z

    An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

  14. Process for separating nitrogen from methane using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

    2007-07-31T23:59:59.000Z

    The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

  15. SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION

    SciTech Connect (OSTI)

    Timothy L. Ward

    2000-06-30T23:59:59.000Z

    Mixed-conducting membranes have the ability to conduct oxygen with perfect selectivity at elevated temperatures, which makes them an extremely attractive alternative for oxygen separation and membrane reactor applications. The ability to reliably fabricate these membranes in thin or thick films would enable solid-state divisional limitations to be minimized, thus providing higher oxygen flux. Based on that motivation, the overall objective for this project is to develop and demonstrate a strategy for the fabrication of supported Wick film ceramic mixed conducting membranes, and improve the understanding of the fundamental issues associated with reliable fabrication of these membranes. The project has focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} because of its superior permeability and stability in reducing atmospheres. The fabrication strategy employed involves the deposition of SrCo{sub 0.5}FeO{sub x} thick films onto porous supports of the same composition. In the second year of this project, we completed characterization of the sintering and phase behavior of the porous SrCo{sub 0.5}FeO{sub x} supports, leading to a standard support fabrication methodology. Using a doctor blade method, pastes made from aerosol-derived SrCo{sub 0.5}FeO{sub x} powder dispersed with polyethylene glycol were applied to the supports, and the sintering behavior of the thick film membranes was examined in air and nitrogen atmospheres. It has been demonstrated that the desired crystalline phase content can be produced in the membranes, and that the material in the membrane layer can be highly densified without densifying the underlying support. However, considerable cracking and opening of the film occurred when films densified to a high extent. The addition of MgO into the SrCo{sub 0.5}FeO{sub x} supports was shown to inhibit support sintering so that temperatures up to 1300 C, where significant liquid formation occurs, could be used for film sintering. This successfully reduced cracking, however the films retained open porosity. The investigation of this concept will be continued in the final year of the project. Investigation of a metal organic chemical vapor deposition (MOCVD) method for defect mending in dense membranes was also initiated. An appropriate metal organic precursor (iron tetramethylheptanedionate) was identified whose deposition can be controlled by access to oxygen at temperatures in the 280-300 C range. Initial experiments have deposited iron oxide, but only on the membrane surface; thus refinement of this method will continue.

  16. Supported Molten Metal Membranes for Hydrogen Separation

    SciTech Connect (OSTI)

    Datta, Ravindra; Ma, Yi Hua; Yen, Pei-Shan; Deveau, Nicholas; Fishtik, Ilie; Mardilovich, Ivan

    2013-09-30T23:59:59.000Z

    We describe here our results on the feasibility of a novel dense metal membrane for hydrogen separation: Supported Molten Metal Membrane, or SMMM.1 The goal in this work was to develop these new membranes based on supporting thin films of low-melting, non- precious group metals, e.g., tin (Sn), indium (In), gallium (Ga), or their alloys, to provide a flux and selectivity of hydrogen that rivals the conventional but substantially more expensive palladium (Pd) or Pd alloy membranes, which are susceptible to poisoning by the many species in the coal-derived syngas, and further possess inadequate stability and limited operating temperature range. The novelty of the technology presented numerous challenges during the course of this project, however, mainly in the selection of appropriate supports, and in the fabrication of a stable membrane. While the wetting instability of the SMMM remains an issue, we did develop an adequate understanding of the interaction between molten metal films with porous supports that we were able to find appropriate supports. Thus, our preliminary results indicate that the Ga/SiC SMMM at 550 C has a permeance that is an order of magnitude higher than that of Pd, and exceeds the 2015 DOE target. To make practical SMM membranes, however, further improving the stability of the molten metal membrane is the next goal. For this, it is important to better understand the change in molten metal surface tension and contact angle as a function of temperature and gas-phase composition. A thermodynamic theory was, thus, developed, that is not only able to explain this change in the liquid-gas surface tension, but also the change in the solid-liquid surface tension as well as the contact angle. This fundamental understanding has allowed us to determine design characteristics to maintain stability in the face of changing gas composition. These designs are being developed. For further progress, it is also important to understand the nature of solution and permeation process in these molten metal membranes. For this, a comprehensive microkinetic model was developed for hydrogen permeation in dense metal membranes, and tested against data for Pd membrane over a broad range of temperatures.3 It is planned to obtain theoretical and experimental estimates of the parameters to corroborate the model against mental results for SMMM.

  17. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid (Menlo Park, CA)

    1997-01-01T23:59:59.000Z

    A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

  18. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, K.

    1997-07-15T23:59:59.000Z

    A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

  19. Gas storage and separation by electric field swing adsorption

    DOE Patents [OSTI]

    Currier, Robert P; Obrey, Stephen J; Devlin, David J; Sansinena, Jose Maria

    2013-05-28T23:59:59.000Z

    Gases are stored, separated, and/or concentrated. An electric field is applied across a porous dielectric adsorbent material. A gas component from a gas mixture may be selectively separated inside the energized dielectric. Gas is stored in the energized dielectric for as long as the dielectric is energized. The energized dielectric selectively separates, or concentrates, a gas component of the gas mixture. When the potential is removed, gas from inside the dielectric is released.

  20. Method for preparing membranes with adjustable separation performance

    DOE Patents [OSTI]

    Peterson, E.S.; Orme, C.J.; Stone, M.L.

    1995-01-31T23:59:59.000Z

    Methods for adjustable separation of solutes and solvents involve the combination of the use of a maximally swollen membrane and subsequent vacuum depressurization exerted on the permeate side of that membrane. By adjusting the extent of depressurization it is possible to separate solvent from solutes and solutes from each other. Improved control of separation parameters as well as improved flux rates characterize the present invention. 2 figs.

  1. A simple method for the separation of diastereomers

    E-Print Network [OSTI]

    Cheowtirakul, Srisamorn

    2012-06-07T23:59:59.000Z

    to separate malcic and fumaric acids, crotoni c and isocrotonic acids, and coumsric. and coumarinic acids by adsorption chromatography on Sephadex. However, the method failed to separate mesaconic and citraconic acids, also 27 diastereomers. Andersson... was demonstrated by using it to separate the diastereomers of the following carboxylic acids; cis- and trans-cinnamic (1 and 2), styrylacetic (3 and 4), furanacrylic (5 and 6), and geranic (7 and 8); cis, trans- and trans, trans-2, 3-diphenylcyclopropane...

  2. ESP/rotary gas separator duo found to optimize production

    SciTech Connect (OSTI)

    Jacobs, G.H.

    1986-11-01T23:59:59.000Z

    A field test conducted on a low-volume waterflood well in West Texas equipped with an electric submersible pump (ESP) proved to rotary gas separator (RGS) to be more efficient than conventional reverse flow gas separators, achieving gas separation efficiencies close to 90%. Further, the RGS increased the run time of the ESP, thus lowering the wellbore fluid level and increasing oil production. The one drawback found is that RGSs can be susceptible to fluid erosion.

  3. Fuel cell system with separating structure bonded to electrolyte

    DOE Patents [OSTI]

    Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY); Quek, Shu Ching (Clifton Park, NY); Hasz, Wayne Charles (Pownal, VT); Powers, James Daniel (Santa Monica, CA)

    2010-09-28T23:59:59.000Z

    A fuel cell assembly comprises a separating structure configured for separating a first reactant and a second reactant wherein the separating structure has an opening therein. The fuel cell assembly further comprises a fuel cell comprising a first electrode, a second electrode, and an electrolyte interposed between the first and second electrodes, and a passage configured to introduce the second reactant to the second electrode. The electrolyte is bonded to the separating structure with the first electrode being situated within the opening, and the second electrode being situated within the passage.

  4. Oil/gas separator for installation at burning wells

    SciTech Connect (OSTI)

    Alonso, C.T.; Bender, D.A.; Bowman, B.R. [and others

    1991-12-31T23:59:59.000Z

    An oil/gas separator is disclosed that can be utilized to return the burning wells in Kuwait to production. Advantageously, a crane is used to install the separator at a safe distance from the well. The gas from the well is burned off at the site, and the oil is immediately pumped into Kuwait`s oil gathering system. Diverters inside the separator prevent the oil jet coming out of the well from reaching the top vents where the gas is burned. The oil falls back down, and is pumped from an annular oil catcher at the bottom of the separator, or from the concrete cellar surrounding the well.

  5. The Integration of Separated Minors in Finland : Perceptions of Professionals.

    E-Print Network [OSTI]

    Sagaria, Mary Kathryn

    2006-01-01T23:59:59.000Z

    ??Separated minors account for almost 10 percent of asylum seekers in Finland, a national percentage that is one of the highest in the European Union. (more)

  6. Separation of Peptide Isomers with Variant Modified Sites by...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isomers with Variant Modified Sites by High-Resolution Differential Ion Mobility Spectrometry. Separation of Peptide Isomers with Variant Modified Sites by High-Resolution...

  7. Effective Separation of Disjunctive Cuts for Convex Mixed Integer ...

    E-Print Network [OSTI]

    2010-11-11T23:59:59.000Z

    This limits the total effort we spend generating cuts and helps to maintain numerical stability of (CGLP). If a cut is generated by Algorithm 2 that separates

  8. Oil/gas separator for installation at burning wells

    DOE Patents [OSTI]

    Alonso, C.T.; Bender, D.A.; Bowman, B.R.; Burnham, A.K.; Chesnut, D.A.; Comfort, W.J. III; Guymon, L.G.; Henning, C.D.; Pedersen, K.B.; Sefcik, J.A.; Smith, J.A.; Strauch, M.S.

    1993-03-09T23:59:59.000Z

    An oil/gas separator is disclosed that can be utilized to return the burning wells in Kuwait to production. Advantageously, a crane is used to install the separator at a safe distance from the well. The gas from the well is burned off at the site, and the oil is immediately pumped into Kuwait's oil gathering system. Diverters inside the separator prevent the oil jet coming out of the well from reaching the top vents where the gas is burned. The oil falls back down, and is pumped from an annular oil catcher at the bottom of the separator, or from the concrete cellar surrounding the well.

  9. Process for the recovery and separation of plastics

    DOE Patents [OSTI]

    Jody, Bassam J.; Daniels, Edward J.; Pomykala Jr., Joseph A.

    2003-07-29T23:59:59.000Z

    A method of separating a portion of acrylonitrile-butadiene-styrene (ABS) from a mixture containing ABS and for separating a portion of ABS and polycarbonate (PC) from a mixture of plastics containing ABS and PC is disclosed. The method includes shredding and/or granulating the mixture of plastics containing ABS and PC to provide a selected particle size; sequentially dispersing the shredded mixture of plastics in a series aqueous solutions having different specific gravities and separating the floating fraction until the desired separation is obtained. Surface tension and pH are also variable to be controlled.

  10. actinide separations optimized: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (more) Potter, Michael Wayne 1981-01-01 2 Optimal distance separating halfspace Optimization Online Summary: which uses a proof based on the Kuhn-Tucker conditions). Corollary...

  11. Ion Mobility Separation of Isomeric Phosphopeptides from a Protein...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    based on accurate separation properties. The results are unchanged over a range of infusion solvent pH, hence present approach should work in conjunction with chromatographic...

  12. Building separating concentric balls to solve a multi-instance ...

    E-Print Network [OSTI]

    2008-02-03T23:59:59.000Z

    Feb 3, 2008 ... Building separating concentric balls to solve a multi-instance classification problem. ?. Emilio Carrizosa, Jos Gordillo. . Universidad de...

  13. Oil/gas separator for installation at burning wells

    DOE Patents [OSTI]

    Alonso, Carol T. (Orinda, CA); Bender, Donald A. (Dublin, CA); Bowman, Barry R. (Livermore, CA); Burnham, Alan K. (Livermore, CA); Chesnut, Dwayne A. (Pleasanton, CA); Comfort, III, William J. (Livermore, CA); Guymon, Lloyd G. (Livermore, CA); Henning, Carl D. (Livermore, CA); Pedersen, Knud B. (Livermore, CA); Sefcik, Joseph A. (Tracy, CA); Smith, Joseph A. (Livermore, CA); Strauch, Mark S. (Livermore, CA)

    1993-01-01T23:59:59.000Z

    An oil/gas separator is disclosed that can be utilized to return the burning wells in Kuwait to production. Advantageously, a crane is used to install the separator at a safe distance from the well. The gas from the well is burned off at the site, and the oil is immediately pumped into Kuwait's oil gathering system. Diverters inside the separator prevent the oil jet coming out of the well from reaching the top vents where the gas is burned. The oil falls back down, and is pumped from an annular oil catcher at the bottom of the separator, or from the concrete cellar surrounding the well.

  14. Thermodynamic Investigations of Aqueous Ternary Complexes for Am/Cm Separation

    E-Print Network [OSTI]

    Leggett, Christina Joy

    2012-01-01T23:59:59.000Z

    A New Method of Separating Americium and Curium from thestill be used to separate americium from curium, however.Chair The separation of americium from curium in spent

  15. K-25 Structural Separation and Demolition

    SciTech Connect (OSTI)

    Cater, Frank [Bechtel Jacobs Company, LLC, East Tennessee Technology Park, Post Office Box 4699, Oak Ridge, TN 37831 (United States)

    2008-01-15T23:59:59.000Z

    The K-25 building is a former gaseous diffusion plant, built in 1944-1945 as part of the United States Manhattan Project. The structure was the largest structure under one roof, surpassed only by the Pentagon. Together the three wings represent about 17.8 hectare (44 acres) under roof and are generally about 18.3 meters (60 ft.) high on the outside face and approximately 12.2 meters (40 ft.) high on the inside face. The entire structure was built in the shape of a 'U', with a lateral distance of approximately one mile. It was constructed in individual building units with each unit connected using expansion joint-type connection. A single unit is approximately 24.4 meters (80 ft.) across and 122 meters (400 ft.) deep. The northern structure is connected to the eastern and western structures at the upper level floors. The four-level, U-shaped building is a steel-frame structure with corrugated cement-asbestos siding. The cell level is an elevated concrete structure supported by reinforced concrete columns located in the basement, or vault area. The vault area can be accessed at grade level from the outside perimeter. Inside the courtyard, the grade level has been raised to provide entry to the second or cell floor level. An engineering evaluation of the structure was performed to determine the condition of the structure and possibility of unplanned collapse of any portion of the structure. The evaluation included physical inspections, calculations for wind, pre-demolition loads, and evaluation of failure modes. The results of the evaluation have provided guidance for the demolition plan and the development of criteria for protection of personnel performing pre-demolition activities. Challenges include degradation of the structure that necessitated repair, dealing with changes in the code revisions from both the American Concrete Institute (ACI) and the American Institute of Steel Construction (AISC), access to areas of the structure that were not necessarily designed for access, and acceleration of the building degradation due to the pre-demolition activities. When a full building is evaluated, 50 percent of wind and applied forces are dissipated in 3 units and 80 percent is dissipated in 12 units. The forces are basically linear for the first 6 units once the building is opened at the start of demolition. Some column buckling, based on current codes, was noted in the analysis that would have to be mitigated to ensure a controlled demolition. Loading for the removal of the equipment required structural engineering evaluation of the certainty of the load and the application of the load. Corbels are being evaluated through an inspection program and criteria for repair based on current loading and anticipated additional live loads. Access issues continue to be a challenge and have created the need for a significant fall protection program. Other areas of access require different approaches and engineering solutions, sometime considering ultimate strength design versus standard yield stress design. An evaluation of separating a wing into two sections to allow for worker re-entry to perform pre-demolition activities during the demolition off shift was conducted. The evaluation has shown that because of both design and history of the K-25 and K-27 Buildings, significant care and attention is needed to demolish these structures from a structural perspective. When the project schedule issues are overlaid, that may demand workers in other parts of the structure after demolition has begun, the structural issues become severe, demanding exacting analysis and significant controls to ensure the safety of the workers both in and outside the building performing the demolition work.

  16. Aquagel electrode separator for use in batteries and supercapacitors

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1995-01-01T23:59:59.000Z

    An electrode separator for electrochemical energy storage devices, such as a high energy density capacitor incorporating a variety of carbon foam electrodes. The separator is derived from an aquagel of resorcinol-formaldehyde and related polymers and containing ionically conducting electrolyte in the pores thereof.

  17. Aquagel electrode separator for use in batteries and supercapacitors

    DOE Patents [OSTI]

    Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

    1995-03-28T23:59:59.000Z

    An electrode separator is described for electrochemical energy storage devices, such as a high energy density capacitor incorporating a variety of carbon foam electrodes. The separator is derived from an aquagel of resorcinol-formaldehyde and related polymers and containing ionically conducting electrolyte in the pores thereof. 9 figures.

  18. A Characterization of a Dual Chambered, Two Phase Separator

    E-Print Network [OSTI]

    Klein, Casey

    2012-02-14T23:59:59.000Z

    A new two phase separator for use in space applications has been invented. It is a vortex separator designed to accommodate gas driven two phase flows of gas and liquid. The work presented here is a first of a kind study of this newly invented...

  19. Contextually Supervised Source Separation with Application to Energy Disaggregation

    E-Print Network [OSTI]

    Kolter, J. Zico

    Contextually Supervised Source Separation with Application to Energy Disaggregation Matt Wytock amounts of data but no explicit su- pervision; our motivating application is energy disag- gregation of hourly smart meter data (the separation of whole-home power signals into different energy uses). Here

  20. A threshold Cherenkov detector for K separation using silica aerogel

    E-Print Network [OSTI]

    Magiera, Andrzej

    A threshold Cherenkov detector for Kþ =pþ separation using silica aerogel R. Siudak a,b , A August 2008 Keywords: Threshold Cherenkov detector Silica aerogel Reaction pp ! Kþ ðLp? Kþ =pþ separation in the focal plane of a magnetic spectrograph. Silica aerogel with refractive index of n ¼ 1:05 is applied

  1. Accelerator Generation and Thermal Separation (AGATS) of Technetium-99m

    ScienceCinema (OSTI)

    None

    2013-05-28T23:59:59.000Z

    Accelerator Generation and Thermal Separation (AGATS) of Technetium-99m is a linear electron accelerator-based technology for producing medical imaging radioisotopes from a separation process that heats, vaporizes and condenses the desired radioisotope. You can learn more about INL's education programs at http://www.facebook.com/idahonationallaboratory.

  2. Phase separation of acetonitrile-water mixture in protein purification

    E-Print Network [OSTI]

    Gu, Tingyue

    Phase separation of acetonitrile-water mixture in protein purification Tingyue Gu, Yesong Gu approximately 6045% ACN with 0.1% TFA. A Waters dual-pumpgradient HPLC system(Millipore Corporation, Bedford, MA-drying. This work shows that a phase separation occurs for ACN-water solutions at -]PC.The top phase contains 88

  3. Pollution prevention by process modification: Reactions and separations

    SciTech Connect (OSTI)

    Hopper, J.R.; Yaws, C.L.; Vichailak, M.; Ho, T.C. (Lamar Univ., Beaumont, TX (United States). Chemical Engineering Dept.)

    1994-01-01T23:59:59.000Z

    Pollution prevention by process modification of chemical process reaction and separation parameters is illustrated with case studies of four chemical processes. Each case has demonstrated the opportunities for minimizing waste products by applying the fundamentals of chemical engineering in the analysis of reactor design and separation parameters for each specific process. Two of the examples have resulted in commercial implementations.

  4. Blind Source Separation: the Sparsity Starck J.-L. a

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Blind Source Separation: the Sparsity Revolution Bobin J. a Starck J.-L. a Moudden Y. a Fadili M issues have already been addressed as testified by the wide literature on the so-called blind source signal representations. GMCA is a fast and efficient blind source separation method. In remote sensing

  5. Blind Source Separation and Independent Component Analysis: Seungjin Choi

    E-Print Network [OSTI]

    Cichocki, Andrzej

    REVIEW Blind Source Separation and Independent Component Analysis: A Review Seungjin Choi, sylee}@kaist.ac.kr (Submitted on October 20, 2004) Abstract - Blind source separation (BSS meaningful coding or blind source estimation. The key issue is to find a such transformation or coding

  6. BROADBAND ANALOG OPTO-ELECTRONIC BLIND SOURCE SEPARATION

    E-Print Network [OSTI]

    Popovic, Zoya

    -electronic blind source separation Thesis directed by Professor Zoya Popovic This thesis addresses the problemBROADBAND ANALOG OPTO-ELECTRONIC BLIND SOURCE SEPARATION by PAUL CARSON SMITH B.E., University of Colorado, 2000 M.S., University of Colorado, 2000 A thesis submitted to the Faculty of the Graduate School

  7. Life Cycle Assessment of Biogas from Separated slurry

    E-Print Network [OSTI]

    Life Cycle Assessment of Biogas from Separated slurry Lorie Hamelin, Marianne Wesnæs and Henrik AND ALTERNATIVES 28 2.2.1 Reference Scenario (Scenario A) 28 2.2.2 Biogas from raw pig slurry and fibre fraction from chemical- mechanical separation (Scenario F) 29 2.2.3 Biogas from raw cow slurry and fibre

  8. Means and method of detection in chemical separation procedures

    DOE Patents [OSTI]

    Yeung, Edward S. (Ames, IA); Koutny, Lance B. (Ames, IA); Hogan, Barry L. (Ames, IA); Cheung, Chan K. (Ames, IA); Ma, Yinfa (Ames, IA)

    1993-03-09T23:59:59.000Z

    A means and method for indirect detection of constituent components of a mixture separated in a chemical separation process. Fluorescing ions are distributed across the area in which separation of the mixture will occur to provide a generally uniform background fluorescence intensity. For example, the mixture is comprised of one or more charged analytes which displace fluorescing ions where its constituent components separate to. Fluorescing ions of the same charge as the charged analyte components cause a displacement. The displacement results in the location of the separated components having a reduced fluorescence intensity to the remainder of the background. Detection of the lower fluorescence intensity areas can be visually, by photographic means and methods, or by automated laser scanning.

  9. Means and method of detection in chemical separation procedures

    DOE Patents [OSTI]

    Yeung, E.S.; Koutny, L.B.; Hogan, B.L.; Cheung, C.K.; Yinfa Ma.

    1993-03-09T23:59:59.000Z

    A means and method are described for indirect detection of constituent components of a mixture separated in a chemical separation process. Fluorescing ions are distributed across the area in which separation of the mixture will occur to provide a generally uniform background fluorescence intensity. For example, the mixture is comprised of one or more charged analytes which displace fluorescing ions where its constituent components separate to. Fluorescing ions of the same charge as the charged analyte components cause a displacement. The displacement results in the location of the separated components having a reduced fluorescence intensity to the remainder of the background. Detection of the lower fluorescence intensity areas can be visually, by photographic means and methods, or by automated laser scanning.

  10. T. Larsson, S. Skogestad, C.C. Yu Control of reactor, separator with recycle. Control of reactor, separator with recycle.

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad, C.C. Yu Control of reactor, separator with recycle. Control of reactor, Taiwan AIChE annual meeting / 11.3.1999 1 NTNU #12; T. Larsson, S. Skogestad, C.C. Yu Control of reactor / 11.3.1999 2 NTNU #12; T. Larsson, S. Skogestad, C.C. Yu Control of reactor, separator with recycle

  11. T. Larsson, S. Skogestad, C.C. Yu Control of reactor, separator with recycle. Control of reactor, separator with recycle.

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad, C.C. Yu Control of reactor, separator with recycle. Control of reactor, Taiwan AIChE annual meeting / 11.3.1999 1 NTNU #12;T. Larsson, S. Skogestad, C.C. Yu Control of reactor. Skogestad, C.C. Yu Control of reactor, separator with recycle. Related work A lot has been on the control

  12. Microwave Enhanced Separation of Water-In-Oil Emulsions

    E-Print Network [OSTI]

    Fang, C. S.; Lai, P.

    MICRaVAVE ENHANCED SEPARATION OF WATER-IN-oIL EMULSIONS C.S. FANG DEPAR'lMENT OF rnEMICAL ENGINEERING UNIVERSITY OF SOUTHWESTERN LOUISIANA LAFAYE'ITE, IDUISIANA ABSTRACT The experimental data showed that viscous and stable water...-in-oil emulsions can be separated by nucrowave radiation, providing an opportunity for oll ~ecovery and waste reduction. At optimal condltlons, the separation of water can be accom plished at 80% or better, without using demulsi fying chemicals. The experi...

  13. Portable apparatus for separating sample and detecting target analytes

    DOE Patents [OSTI]

    Renzi, Ronald F. (Tracy, CA); Wally, Karl (Lafayette, CA); Crocker, Robert W. (Fremont, CA); Stamps, James F. (Livermore, CA); Griffiths; Stewart K. , (Livermore, CA); Fruetel, Julia A. (Livermore, CA); Horn, Brent A. (Roy, UT); Shokair, Isaac R. (Livermore, CA); Yee, Daniel D. (Dublin, CA); VanderNoot, Victoria A. (Pleasanton, CA); Wiedenman, Boyd J. (Aiken, SC); West, Jason A. A. (Pleasanton, CA); Ferko, Scott M. (Livermore, CA)

    2008-11-18T23:59:59.000Z

    Portable devices and methods for determining the presence of a target analyte using a portable device are provided. The portable device is preferably hand-held. A sample is injected to the portable device. A microfluidic separation is performed within the portable device and at least one separated component detected by a detection module within the portable device, in embodiments of the invention. A target analyte is identified, based on the separated component, and the presence of the target analyte is indicated on an output interface of the portable device, in accordance with embodiments of the invention.

  14. Separating the Minor Actinides Through Advances in Selective Coordination Chemistry

    SciTech Connect (OSTI)

    Lumetta, Gregg J.; Braley, Jenifer C.; Sinkov, Sergey I.; Carter, Jennifer C.

    2012-08-22T23:59:59.000Z

    This report describes work conducted at the Pacific Northwest National Laboratory (PNNL) in Fiscal Year (FY) 2012 under the auspices of the Sigma Team for Minor Actinide Separation, funded by the U.S. Department of Energy Office of Nuclear Energy. Researchers at PNNL and Argonne National Laboratory (ANL) are investigating a simplified solvent extraction system for providing a single-step process to separate the minor actinide elements from acidic high-level liquid waste (HLW), including separating the minor actinides from the lanthanide fission products.

  15. Codings of separable compact subsets of the first Baire class

    E-Print Network [OSTI]

    Dodos, Pandelis

    2008-01-01T23:59:59.000Z

    Let $X$ be a Polish space and $K$ a separable compact subset of the first Baire class on $X$. For every sequence $\\bs$ dense in $\\kk$, the descriptive set-theoretic properties of the set \\[ \\lbf=\\{L\\in[\

  16. Reticulated Nanoporous Polymers by Controlled Polymerization-Induced Microphase Separation

    SciTech Connect (OSTI)

    Seo, Myungeun; Hillmyer, Marc A. (UMM)

    2013-04-08T23:59:59.000Z

    Materials with percolating mesopores are attractive for applications such as catalysis, nanotemplating, and separations. Polymeric frameworks are particularly appealing because the chemical composition and the surface chemistry are readily tunable. We report on the preparation of robust nanoporous polymers with percolating pores in the 4- to 8-nanometer range from a microphase-separated bicontinuous precursor. We combined polymerization-induced phase separation with in situ block polymer formation from a mixture of multifunctional monomers and a chemically etchable polymer containing a terminal chain transfer agent. This marriage results in microphase separation of the mixture into continuous domains of the etchable polymer and the emergent cross-linked polymer. Precise control over pore size distribution and mechanical integrity renders these materials particularly suited for various advanced applications.

  17. Impact of Separation on Community Social Service Utilization

    E-Print Network [OSTI]

    McDonald, Thomas P.; Piliavin, Irving

    1981-01-01T23:59:59.000Z

    This experiment indicates that AFDC recipients who received public welfare social services under the format of separation of services from financial aid are more likely than recipients in the combined condition to use ...

  18. Haverford Researchers Create Carbon Dioxide-Separating Polymer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PG-ES1, that uses a combination of surface adsorption and narrow pores to separate carbon dioxide from nitrogen, oxygen, and methane gases. Image by Joshua Schrier, Haverford...

  19. Max-min separability: incremental approach and application to ...

    E-Print Network [OSTI]

    2007-06-20T23:59:59.000Z

    [9] Bennet, K.P. and Mangasarian, O.L. (1993), Bilinear separation of two sets in n-space,. Computational Optimization and Applications, 2(3), pp. 207-227.

  20. Increased Photovoltaic Power Output via Diffractive Spectrum Separation

    E-Print Network [OSTI]

    Kim, Ganghun

    In this Letter, we report the preliminary demonstration of a new paradigm for photovoltaic power generation that utilizes a broadband diffractive-optical element (BDOE) to efficiently separate sunlight into laterally spaced ...

  1. Hydrogen separation membranes - annual report for FY 2007.

    SciTech Connect (OSTI)

    Chen, L.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Park, C. Y.; Picciolo, J. J.; Song, S. J.; Energy Systems

    2008-01-31T23:59:59.000Z

    The objective of this work is to develop dense ceramic membranes for separating hydrogen from other gaseous components in a nongalvanic mode, i.e., without using an external power supply or electrical circuitry.

  2. ROBUST SPEECH RECOGNITION BY INTEGRATING SPEECH SEPARATION AND HYPOTHESIS TESTING

    E-Print Network [OSTI]

    Wang, DeLiang "Leon"

    on recognition, noisy speech is typically preprocessed by speech enhancement algorithms, such as spectral- tral subtraction for speech enhancement followed by recognition of enhanced speech [4]. The missingROBUST SPEECH RECOGNITION BY INTEGRATING SPEECH SEPARATION AND HYPOTHESIS TESTING Soundararajan

  3. Separation processes using expulsion from dilute supercritical solutions

    DOE Patents [OSTI]

    Cochran, H.D. Jr.

    1993-04-20T23:59:59.000Z

    A process is described for separating isotopes as well as other mixtures by utilizing the behavior of dilute repulsive or weakly attractive elements of the mixtures as the critical point of the solvent is approached.

  4. Computational modeling of biological molecule separation in nanofluidic devices

    E-Print Network [OSTI]

    Fayad, Ghassan Najib, 1982-

    2010-01-01T23:59:59.000Z

    Separation of biological molecules such as DNA and protein is of great importance for the chemical and pharmaceutical industries. In recent years, several researchers focused on fabricating patterned regular sieving ...

  5. Gas Separation Membrane Use in the Refinery and Petrochemical Industries

    E-Print Network [OSTI]

    Vari, J.

    Membranes have gained commercial acceptance as proven methods to recover valuable gases from waste gas streams. This paper explores ways in which gas separation membranes are used in the refinery and petrochemical industries to recover and purify...

  6. Liquid absorbent solutions for separating nitrogen from natural gas

    DOE Patents [OSTI]

    Friesen, Dwayne T. (Bend, OR); Babcock, Walter C. (Bend, OR); Edlund, David J. (Redmond, OR); Lyon, David K. (Bend, OR); Miller, Warren K. (Bend, OR)

    2000-01-01T23:59:59.000Z

    Nitrogen-absorbing and -desorbing compositions, novel ligands and transition metal complexes, and methods of using the same, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

  7. Separation processes using expulsion from dilute supercritical solutions

    DOE Patents [OSTI]

    Cochran, Jr., Henry D. (Oak Ridge, TN)

    1993-01-01T23:59:59.000Z

    A process for separating isotopes as well as other mixtures by utilizing the behavior of dilute repulsive or weakly attractive elements of the mixtures as the critical point of the solvent is approached.

  8. Membrane separation systems---A research and development needs assessment

    SciTech Connect (OSTI)

    Baker, R.W. (Membrane Technology and Research, Inc., Menlo Park, CA (USA)); Cussler, E.L. (Minnesota Univ., Minneapolis, MN (USA). Dept. of Chemical Engineering and Materials Science); Eykamp, W. (California Univ., Berkeley, CA (USA)); Koros, W.J. (Texas Univ., Austin, TX (USA)); Riley, R.L. (Separation Systems Technology, San Diego, CA (USA)); Strathmann, H. (Fraunhofer-Institut fuer Grenzflaech

    1990-04-01T23:59:59.000Z

    Industrial separation processes consume a significant portion of the energy used in the United States. A 1986 survey by the Office of Industrial Programs estimated that about 4.2 quads of energy are expended annually on distillation, drying and evaporation operations. This survey also concluded that over 0.8 quads of energy could be saved in the chemical, petroleum and food industries alone if these industries adopted membrane separation systems more widely. Membrane separation systems offer significant advantages over existing separation processes. In addition to consuming less energy than conventional processes, membrane systems are compact and modular, enabling easy retrofit to existing industrial processes. The present study was commissioned by the Department of Energy, Office of Program Analysis, to identify and prioritize membrane research needs in light of DOE's mission. Each report will be individually cataloged.

  9. Solid-supported phospholipid bilayers: separation matrix for proteomics applications

    E-Print Network [OSTI]

    Diaz Vazquez, Arnaldo Joel

    2009-05-15T23:59:59.000Z

    matrix. As a first step towards the purification of proteins, this work showed that streptavidin proteins doubly bound to a bilayer by a biotinylated lipid can be separated from streptavidin proteins which are singly bounded....

  10. Electrochemical Isotope Effect and Lithium Isotope Separation Jay R. Black,

    E-Print Network [OSTI]

    Mcdonough, William F.

    results showing a large lithium isotope separation due to electrodeposition. The fractionation is tunable lithium were plated from solutions of 1 M LiClO4 in propylene carbonate (PC) on planar nickel electrodes

  11. 30th Actinide Separations Conference, PNNL-SA-50126

    SciTech Connect (OSTI)

    Delegard, Calvin H.

    2006-05-25T23:59:59.000Z

    Program booklet for the 30th Actinide Separations Conference. Contains agenda and abstracts for 27 poster and 38 oral presentations to be made during the 3-day meeting, May 23-25, 2006.

  12. Underdetermined Blind Source Separation Based on Subspace Representation

    E-Print Network [OSTI]

    Kim, Sanggyun

    This paper considers the problem of blindly separating sub- and super-Gaussian sources from underdetermined mixtures. The underlying sources are assumed to be composed of two orthogonal components: one lying in the rowspace ...

  13. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11T23:59:59.000Z

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  14. A TRUEX-based separation of americium from the lanthanides

    SciTech Connect (OSTI)

    Bruce J. Mincher; Nicholas C. Schmitt; Mary E. Case

    2011-03-01T23:59:59.000Z

    Abstract: The inextractability of the actinide AnO2+ ions in the TRUEX process suggests the possibility of a separation of americium from the lanthanides using oxidation to Am(V). The only current method for the direct oxidation of americium to Am(V) in strongly acidic media is with sodium bismuthate. We prepared Am(V) over a wide range of nitric acid concentrations and investigated its solvent extraction behavior for comparison to europium. While a separation is achievable in principal, the presence of macro amounts of cerium competes for the sparingly soluble oxidant and the oxidant itself competes for CMPO complexation. These factors conspire to reduce the Eu/Am separation factor from ~40 using tracer solutions to ~5 for extractions from first cycle raffinate simulant solution. To separate pentavalent americium directly from the lanthanides using the TRUEX process, an alternative oxidizing agent will be necessary.

  15. Gas separation with oligomer-modified inorganic membranes

    E-Print Network [OSTI]

    Javaid, Asad

    1999-01-01T23:59:59.000Z

    -based separation are presented. Alumina membranes with average pore sizes near 5 nm and 10 run were treated with various n-alkyl trichlorosilanes. Pure gas permeation studies using nitrogen, methane, and propane were performed to investigate the effects...

  16. A graph-separation theorem for quantum causal models

    E-Print Network [OSTI]

    Jacques Pienaar; Caslav Brukner

    2014-10-31T23:59:59.000Z

    A causal model is an abstract representation of a physical system as a directed acyclic graph (DAG), where the statistical dependencies are encoded using a graphical criterion called `d-separation'. Recent work by Wood & Spekkens shows that causal models cannot, in general, provide a faithful representation of quantum systems. Since d-separation encodes a form of Reichenbach's Common Cause Principle (RCCP), whose validity is questionable in quantum mechanics, we propose a generalised graph separation rule that does not assume the RCCP. We prove that the new rule faithfully captures the statistical dependencies between observables in a quantum network, encoded as a DAG, and is consistent with d-separation in a classical limit. We note that the resulting model is still unable to give a faithful representation of correlations stronger than quantum mechanics, such as the Popescu-Rorlich box.

  17. Separated Response Function Ratios in Exclusive, Forward ?[superscript ] Electroproduction

    E-Print Network [OSTI]

    Huber, G.?M.

    The study of exclusive ?[superscript ] electroproduction on the nucleon, including separation of the various structure functions, is of interest for a number of reasons. The ratio R[subscript L] = ?[?? over L]/?[?+ over ...

  18. Advanced Palladium Membrane Scale-up for Hydrogen Separation

    SciTech Connect (OSTI)

    Sean Emerson; Neal Magdefrau; Ying She; Catherine Thibaud-Erkey

    2012-10-31T23:59:59.000Z

    The main objective of this project was to construct, test, and demonstrate a Pd-Cu metallic tubular membrane micro-channel separator capable of producing 2 lb day{sup -1} H{sub 2} at ?95% recovery when operating downstream of an actual coal gasifier. A key milestone for the project was to complete a pilot-scale gasifier test by 1 September 2011 and demonstrate the separation of 2 lb day{sup -1} H{sub 2} to verify progress toward the DOE??s goals prior to down-selection for larger-scale (??100 lb day{sup -1}) hydrogen separator development. Three different pilot-scale (??1.5 ft{sup 2}) separators were evaluated downstream of coal gasifiers during four different tests and the key project milestone was achieved in August 2011, ahead of schedule. During three of those tests, all of the separators demonstrated or exceeded the targeted separation rate of 2 lb day{sup -1} H{sub 2}. The separator design was proved to be leak tight and durable in the presence of gasifier exhaust contaminants at temperatures and pressures up to 500 °C and 500 psia. The contaminants in the coal gasifier syngas for the most part had negligible impact on separator performance, with H{sub 2} partial pressure being the greatest determinant of membrane performance. Carbon monoxide and low levels of H{sub 2}S (<39 ppmv) had no effect on H{sub 2} permeability, in agreement with laboratory experiments. However, higher levels of H{sub 2}S (>100 ppmv) were shown to significantly reduce H{sub 2} separation performance. The presence of trace metals, including mercury and arsenic, appeared to have no effect based on the experimental data. Subscale Pd-Cu coupon tests further quantified the impact of H{sub 2}S on irreversible sulfide formation in the UTRC separators. Conditions that have a thermodynamic driving force to form coke were found to reduce the performance of the separators, presumably by blockage of effective separation area with carbon deposits. However, it was demonstrated that both in situ and ex situ (laboratory) air regeneration at 450 °C could restore separator performance by burning out such deposits. Gasifier testing revealed that high molecular weight hydrocarbons have the potential to retard H2 separation. Unconverted coal tars with carbon numbers greater than 14 have a boiling point such that they can act as a reversible poison to the Pd-Cu membranes even at temperatures above 500 °C. The use of real-time, physics-based, performance models revealed the effect of these coal tars. It is believed that this project provided the first evidence for the impact of coal tars on H{sub 2} separator performance. Final down-selection of candidate alloys for non-membrane materials of construction proceeded by evaluating the alloys in both UTRC laboratory tests and testing downstream of an actual gasifier at the National Carbon Capture Center (NCCC). The overall alloy ratings were calculated by multiplying the projected cost of a 100 lb day{sup -1} H{sub 2} separator outer shell by the projected oxide scale thickness for 5 years of operation. The alloy with the lowest resulting rating parameter was stainless steel 309 (SS-309) followed by stainless steel 310 (SS-310). However, it was noted that approximately half of the alloys showed susceptibility to pitting and localized corrosion. SS-309 was one of the alloys that exhibited heavy localized attack after 2000 hours of laboratory testing. As this localized corrosion can potentially lead to accelerated end of life, it was determined that SS-310 would be the best alloy selection for this application as it does not show signs of localized pitting corrosion.

  19. Separation of solids from coal liquefaction products using sonic waves

    SciTech Connect (OSTI)

    Slomka, B.J.

    1994-10-01T23:59:59.000Z

    Product streams containing solids are generated in both direct and indirect coal liquefaction processes. This project seeks to improve the effectiveness of coal liquefaction by novel application of sonic and ultrasonic energy to separation of solids from coal liquefaction streams.

  20. Molecular dynamics simulation of nanoporous graphene for selective gas separation

    E-Print Network [OSTI]

    Au, Harold (Harold S.)

    2012-01-01T23:59:59.000Z

    Graphene with sub-nanometer sized pores has the potential to act as a filter for gas separation with considerable efficiency gains compared to traditional technologies. Nanoporous graphene membranes are expected to yield ...

  1. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, Christopher A. (3035 Ferdale Ct., Pleasanton, CA 94566); Worden, Earl F. (117 Vereda del Ciervo, Diablo, CA 94528)

    1995-01-01T23:59:59.000Z

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of .sup.167 Er. The hyperfine structure of .sup.167 Er was used to find two three-step photoionization pathways having a common upper energy level.

  2. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  3. A study of the separation of particles from gases

    SciTech Connect (OSTI)

    Stevens, G.L. II; Masudi, H.

    1995-03-01T23:59:59.000Z

    Cyclones are the simplest and most reliable means of particles and gas separation. They also function as a method of air pollution control and as a cost efficient way of doing so. These basic machines have been in use for many years, and based on advances in technology, cyclones have now been designed for specific applications and conditions. These applications are restricted by inherent properties of the construction of the cyclone, and the materials being separated within the cyclone.

  4. Numerical simulation of flow separation control by oscillatory fluid injection

    E-Print Network [OSTI]

    Resendiz Rosas, Celerino

    2005-08-29T23:59:59.000Z

    NUMERICAL SIMULATION OF FLOW SEPARATION CONTROL BY OSCILLATORY FLUID INJECTION A Dissertation by CELERINO RESENDIZ ROSAS Submitted to the O?ce of Graduate Studies of Texas A&M University in partial ful?llment of the requirements for the degree... of DOCTOR OF PHILOSOPHY May 2005 Major Subject: Aerospace Engineering NUMERICAL SIMULATION OF FLOW SEPARATION CONTROL BY OSCILLATORY FLUID INJECTION A Dissertation by CELERINO RESENDIZ ROSAS Submitted to Texas A&M University in partial ful...

  5. In-Plant Testing of High-Efficiency Hydraulic Separators

    SciTech Connect (OSTI)

    G. H. Luttrell; R. Q. Honaker; R. C. Bratton; T. C. Westerfield; J. N. Kohmuench

    2006-06-30T23:59:59.000Z

    Hydraulic separators are commonly used for particle size classification and gravity concentration of minerals and coal. Unfortunately, the efficiency of these processes can be quite low due to poor equipment design and variations in feed consistency. To help alleviate these problems, an industry-driven R&D program has been undertaken to develop a new generation of hydraulic separators that are more efficient and less costly to operate and maintain. These units, which are commercially called the CrossFlow separator and HydroFloat separator, have the potential to improve performance (separation efficiency and throughput) and reduce operating costs (power consumption, water and reagent usage). In Phase I of this project, laboratory and pilot-scale test units were evaluated at various industrial sites in both the coal and mineral industries. Based on promising results obtained from Phase I, full-scale prototypes were purchased and installed by a major U.S. phosphate producer and a large eastern U.S. coal company. The test data obtained from these sites demonstrate that significant performance improvements can be realized through the application of these high-efficiency separators.

  6. IN-PLANT TESTING OF HIGH-EFFICIENCY HYDRAULIC SEPARATORS

    SciTech Connect (OSTI)

    G.H. Luttrell; R.Q. Honaker; R.C. Bratton; T.C. Westerfield; J.N. Kohmuench

    2006-05-22T23:59:59.000Z

    Hydraulic separators are commonly used for particle size classification and gravity concentration of minerals and coal. Unfortunately, the efficiency of these processes can be quite low due to poor equipment design and variations in feed consistency. To help alleviate these problems, an industry-driven R&D program has been undertaken to develop a new generation of hydraulic separators that are more efficient and less costly to operate and maintain. These units, which are commercially called the CrossFlow separator and HydroFloat separator, have the potential to improve performance (separation efficiency and throughput) and reduce operating costs (power consumption, water and reagent usage). In Phase I of this project, laboratory and pilot-scale test units were evaluated at various industrial sites in both the coal and mineral industries. Based on promising results obtained from Phase I, full-scale prototypes were purchased and installed by a major U.S. phosphate producer and a large eastern U.S. coal company. The test data obtained from these sites demonstrate that significant performance improvements can be realized through the application of these high-efficiency separators.

  7. Formatted: Footer, Left Formatted: Font: 10 pt

    E-Print Network [OSTI]

    Formatted: Space Before: 12 pt, Border: Bottom: (Single solid line, Auto, 0.5 pt Line width) Deleted: Angelis ­ Sacramento Municipal Utility District Anne Gillette ­ California Public Utilities Commission Steven Kelly

  8. Rendering PostScript Fonts on FPGAs

    E-Print Network [OSTI]

    Macvicar, D.; Singh, S.; Patterson, J.W.

    Macvicar,D. Singh,S. Patterson,J.W. Proceedings of 9th Intl. Workshop on Field-Programmable Logic and Applications, FPL'99, (Lysaght, P., Irvine, J. and Hartenstein, R. Eds.). Lecture Notes in Computer Science, Volume No 1673 pp 223-232 Springer

  9. Fermilab | Graphic Standards at Fermilab | Fonts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibility ofSmall15.000 Rev.Group Robert R.Color

  10. Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

    2012-08-21T23:59:59.000Z

    A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

  11. Advanced Nanostructured Molecular Sieves for Energy Efficient Industrial Separations

    SciTech Connect (OSTI)

    Kunhao Li, Michael Beaver

    2012-01-18T23:59:59.000Z

    Due to the very small relative volatility difference between propane and propylene, current propane/propylene separation by distillation requires very tall distillation towers (150-250 theoretical plates) and large reflux ratios (up to 15), which is considered to be the most energy consuming large-scale separation process. Adsorptive separation processes are widely considered to be more energy-efficient alternatives to distillation. However, slow diffusion kinetics/mass transport rate through the adsorbent bed often limits the performance of such processes, so further improvements are possible if intra-particle mass transfer rates can be improved. Rive Technology, Inc. is developing and commercializing its proprietary mesoporous zeolite technology for catalysis and separation. With well-controlled intracrystalline mesoporosity, diffusion kinetics through such mesoporous zeolite based catalysts is much improved relative to conventional zeolites, leading to significantly better product selectivity. This 'proof-of-principle' project (DE-EE0003470) is intended to demonstrate that Rive mesoporous zeolite technology can be extended and applied in adsorptive propane/propylene separation and lead to significant energy saving compared to the current distillation process. In this project, the mesoporous zeolite Y synthesis technology was successfully extended to X and A zeolites that are more relevant to adsorbent applications. Mesoporosity was introduced to zeolite X and A for the first time while maintaining adequate adsorption capacity. Zeolite adsorbents were tested for liquid phase separation performance using a pulse flow test unit and the test results show that the separation selectivity of the mesoporous zeolite adsorbent is much closer to optimal for a Simulated Moving Bed (SMB) separation process and the enhanced mesoporosity lead to >100% increase of overall mass transport rate for propane and propylene. These improvements will significantly improve the performance of an adsorptive separation unit for propane/propylene separation compared with traditional zeolite adsorbents. The enhanced transport will allow for more efficient utilization of a given adsorbent inventory by reducing process cycle time, allowing a faster production rate with a fixed amount of adsorbent or smaller adsorbent inventory at a fixed production rate. Smaller adsorbent inventory would also lead to significant savings in the capital cost due to smaller footprint of the equipment. Energy consumption calculation, based on the pulse test results for rived NaX zeolite adsorbent, of a hypothetical moderate-scale SMB propane/propylene separation plant that processes 6000 BPSD refinery grade propylene (70% propylene) will consume about 60-80% less energy (both re-boiler and condenser duties) compared to a C3 splitter that process the same amount of feed. This energy saving also translates to a reduction of 30,000-35,000 tons of CO2 emission per year at this moderate processing rate. The enhancement of mass transport achievable by introduction of controlled mesoporosity to the zeolite also opens the door for the technology to be applied to several other adsorption separation processes such as the separation of xylene isomers by SMB, small- and large scale production of O2/N2 from air by pressure swing adsorption, the separation of CO2 from natural gas at natural gas wellheads, and the purification of ultra-high purity H2 from the off gas produced by steam-methane-reforming.

  12. SULFUR HEXAFLUORIDE TREATMENT OF USED NUCLEAR FUEL TO ENHANCE SEPARATIONS

    SciTech Connect (OSTI)

    Gray, J.; Torres, R.; Korinko, P.; Martinez-Rodriguez, M.; Becnel, J.; Garcia-Diaz, B.; Adams, T.

    2012-09-25T23:59:59.000Z

    Reactive Gas Recycling (RGR) technology development has been initiated at Savannah River National Laboratory (SRNL), with a stretch-goal to develop a fully dry recycling technology for Used Nuclear Fuel (UNF). This approach is attractive due to the potential of targeted gas-phase treatment steps to reduce footprint and secondary waste volumes associated with separations relying primarily on traditional technologies, so long as the fluorinators employed in the reaction are recycled for use in the reactors or are optimized for conversion of fluorinator reactant. The developed fluorination via SF{sub 6}, similar to the case for other fluorinators such as NF{sub 3}, can be used to address multiple fuel forms and downstream cycles including continued processing for LWR via fluorination or incorporation into a aqueous process (e.g. modified FLUOREX) or for subsequent pyro treatment to be used in advanced gas reactor designs such metal- or gas-cooled reactors. This report details the most recent experimental results on the reaction of SF{sub 6} with various fission product surrogate materials in the form of oxides and metals, including uranium oxides using a high-temperature DTA apparatus capable of temperatures in excess of 1000{deg}C . The experimental results indicate that the majority of the fission products form stable solid fluorides and sulfides, while a subset of the fission products form volatile fluorides such as molybdenum fluoride and niobium fluoride, as predicted thermodynamically. Additional kinetic analysis has been performed on additional fission products. A key result is the verification that SF{sub 6} requires high temperatures for direct fluorination and subsequent volatilization of uranium oxides to UF{sub 6}, and thus is well positioned as a head-end treatment for other separations technologies, such as the volatilization of uranium oxide by NF{sub 3} as reported by colleagues at PNNL, advanced pyrochemical separations or traditional full recycle approaches. Based on current results of the research at SRNL on SF{sub 6} fluoride volatility for UNF separations, SF{sub 6} treatment renders all anticipated volatile fluorides studied to be volatile, and all non-volatile fluorides studied to be non-volatile, with the notable exception of uranium oxides. This offers an excellent opportunity to use this as a head-end separations treatment process because: 1. SF{sub 6} can be used to remove volatile fluorides from a UNF matrix while leaving behind uranium oxides. Therefore an agent such as NF{sub 3} should be able to very cleanly separate a pure UF{sub 6} stream, leaving compounds in the bottoms such as PuF{sub 4}, SrF{sub 2} and CsF after the UNF matrix has been pre-treated with SF{sub 6}. 2. Due to the fact that the uranium oxide is not separated in the volatilization step upon direct contact with SF{sub 6} at moderately high temperatures (? 1000{deg}C), this fluoride approach may be wellsuited for head-end processing for Gen IV reactor designs where the LWR is treated as a fuel stock, and it is not desired to separate the uranium from plutonium, but it is desired to separate many of the volatile fission products. 3. It is likely that removal of the volatile fission products from the uranium oxide should simplify both traditional and next generation pyroprocessing techniques. 4. SF{sub 6} treatment to remove volatile fission products, with or without treatment with additional fluorinators, could be used to simplify the separations of traditional aqueous processes in similar fashion to the FLUOREX process. Further research should be conducted to determine the separations efficiency of a combined SF{sub 6}/NF{sub 3} separations approach which could be used as a stand-alone separations technology or a head-end process.

  13. Design and Development of Integrated Compact Multiphase Separation System (CMSS)

    SciTech Connect (OSTI)

    Ram S. Mohan; Ovadia Shoham

    2006-04-30T23:59:59.000Z

    The petroleum industry has relied in the past mainly on conventional vessel-type separators, which are bulky, heavy and expensive, to process wellhead production of oil-water-gas flow. Economic and operational pressures continue to force the petroleum industry to seek less expensive and more efficient separation alternatives in the form of compact separators. The compact dimensions, smaller footprint and lower weight of compact separators have a potential for cost savings to the industry, especially in offshore and subsea applications. Also, compact separators reduce the inventory of hydrocarbons significantly, which is critical for environmental This report presents a brief overview of the activities and tasks accomplished during the Budget Period II (October 09, 2004-April 30, 2006) of the DOE project titled ''Design and Development of Integrated Compact Multiphase Separation System (CMSS{copyright})''. An executive summary is presented initially followed by the tasks of the current budget period. Then, detailed description of the experimental and modeling investigations are presented. Subsequently, the technical and scientific results of the activities of this project period are presented with discussions. The findings of this investigation are summarized in the ''Conclusions'' section In this investigation, the concept of CMSS{copyright} has been developed and is proven through simulation studies and validated by experimental data. As part of the second phase of the project (Budget Period II--10/09/2004-04/30/2006) experimental investigation of the integrated CMSS{copyright} for different configurations has been conducted in order to evaluate the performance of the individual separation components, and determine how they will affect the performance of each other when integrated in the CMSS{copyright}. An intelligent control system is also developed to improve the total system efficiency of Compact Multiphase Separation System (CMSS{copyright}). In mature oil fields, water handling poses a huge problem. Thus water knock out at the earliest stage helps in significant cost savings during handling, separation and transportation of oil. One of the objectives of the CMSS{copyright} configuration is to knock out free water from the upstream fluids. The results from theoretical and experimental studies show that Free Water Knock Out (FWKO) CMSS{copyright} system can be readily deployed in the field using the control system strategies designed, implemented and tested in this study.

  14. Efficient Separations and Processing Crosscutting Program. Technology summary

    SciTech Connect (OSTI)

    NONE

    1995-06-01T23:59:59.000Z

    The Efficient Separations and Processing (ESP) Crosscutting Program was created in 1991 to identify, develop, and perfect separations technologies and processes to treat wastes and address environmental problems throughout the DOE Complex. The ESP funds several multi-year tasks that address high-priority waste remediation problems involving high-level, low-level, transuranic, hazardous, and mixed (radioactive and hazardous) wastes. The ESP supports applied research and development (R and D) leading to demonstration or use of these separations technologies by other organizations within DOE-EM. Treating essentially all DOE defense wastes requires separation methods that concentrate the contaminants and/or purify waste streams for release to the environment or for downgrading to a waste form less difficult and expensive to dispose of. Initially, ESP R and D efforts focused on treatment of high-level waste (HLW) from underground storage tanks (USTs) because of the potential for large reductions in disposal costs and hazards. As further separations needs emerge and as waste management and environmental restoration priorities change, the program has evolved to encompass the breadth of waste management and environmental remediation problems.

  15. Identification of Heavy and Superheavy Nuclides Using Chemical Separator Systems

    SciTech Connect (OSTI)

    Turler, Andreas

    1999-12-31T23:59:59.000Z

    With the recent synthesis of superheavy nuclides produced in the reactions {sup 48}Ca+{sup 238}U and {sup 48}Ca+{sup 242,244}Pu, much longer-lived nuclei than the previously known neutron-deficient isotopes of the heaviest elements have been identified. Half-lives of several hours and up to several years have been predicted for the longest-lived isotopes of these elements. Thus, the sensitivity of radiochemical separation techniques may present a viable alternative to physical separator systems for the discovery of some of the predicted longer-lived heavy and superheavy nuclides. The advantages of chemical separator systems in comparison to kinematic separators lie in the possibility of using thick targets, high beam intensities spread over larger target areas and in providing access to nuclides emitted under large angles and low velocities. Thus, chemical separator systems are ideally suited to study also transfer and (HI, axn) reaction products. In the following, a study of (HI, axn) reactions will be presented and prospects to chemically identify heavy and superheavy elements discussed.

  16. Proceedings of the First Hanford Separation Science Workshop

    SciTech Connect (OSTI)

    Not Available

    1993-05-01T23:59:59.000Z

    The First Hanford Separation Science Workshop, sponsored by PNL had two main objectives: (1) assess the applicability of available separation methods for environmental restoration and for minimization, recovery, and recycle of mixed and radioactive mutes; and (2) identify research needs that must be addressed to create new or improved technologies. The information gathered at this workshop not only applies to Hanford but could be adapted to DOE facilities throughout the nation as well. These proceedings have been divided into three components: Background and Introduction to the Problem gives an overview of the history of the Site and the cleanup mission, including waste management operations, past disposal practices, current operations, and plans for the future. Also included in this section is a discussion of specific problems concerning the chemistry of the Hanford wastes. Separation Methodologies contains the papers given at the workshop by national experts in the field of separation science regarding the state-of-the-art of various methods and their applicability/adaptability to Hanford. Research Needs identifies further research areas developed in working group sessions. Individual papers are indexed separately.

  17. Separation and Classification of Lipids Using Differential Ion Mobility Spectrometry

    SciTech Connect (OSTI)

    Shvartsburg, Alexandre A.; Isaac, Georgis; Leveque, Nathalie; Smith, Richard D.; Metz, Thomas O.

    2011-04-12T23:59:59.000Z

    Correlations between the dimensions of a 2-D separation create trend lines that normally depend on structural or functional characteristics of the compound class and thus facilitate classification of unknowns. This broadly applies to conventional ion mobility spectrometry (IMS)/mass spectrometry (MS), where the major biomolecular classes (e.g., lipids, peptides, nucleotides) occupy different trend line domains. However, strong correlation between the IMS and MS separations for ions of same charge has impeded finer distinctions. Differential IMS (or FAIMS) is generally much less correlated to MS and thus should better separate the trend lines and associated domains. We report the first observation of chemical class separation by trend lines using FAIMS, here for lipids. For all lipids, FAIMS is indeed more independent of MS than conventional IMS, and subclasses (such as phospho-, glycero-, or sphingolipids) form distinct, often non-overlapping domains. Even finer categories with different functional groups or degrees of unsaturation are often separated. As expected, resolution improves in He-rich gases: at ~70% He, glycerolipid isomers with different positions of fatty acid attachment can be resolved. These results open the door for lipidomics application of FAIMS, particularly shotgun lipidomics and targeted analyses of bioactive lipids.

  18. Multi-Spectral Detection of Microfluidic Separation Products.

    SciTech Connect (OSTI)

    Hayden, Carl C.; Meagher, Robert

    2007-12-01T23:59:59.000Z

    The objectives of this project were to develop a new scientific tool for studies of chemical processes at the single molecule level, and to provide enhanced capabilities for multiplexed, ultrasensitive separations and immunoassays. We have combined microfluidic separation techniques with our newly developed technology for spectrally and temporally resolved detection of single molecules. The detection of individual molecules can reveal fluctuations in molecular conformations, which are obscured in ensemble measurements, and allows detailed studies of reaction kinetics such as ligand or antibody binding. Detection near the single molecule level also enables the use of correlation techniques to extract information, such as diffusion rates, from the fluorescence signal. The micro-fluidic technology offers unprecedented control of the chemical environment and flow conditions, and affords the unique opportunity to study biomolecules without immobilization. For analytical separations, the fluorescence lifetime and spectral resolution of the detection makes it possible to use multiple parameters for identification of separation products to improve the certainty of identification. We have successfully developed a system that can measure fluorescence spectra, lifetimes and diffusion constants of the components of mixtures separated in a microfluidic electrophoresis chip.

  19. Separation of flue-gas scrubber sludge into marketable products

    SciTech Connect (OSTI)

    Kawatra, S.K.; Eisele, T.C.

    1997-08-31T23:59:59.000Z

    A tremendous amount of wet flue-gas desulfurization scrubber sludge (estimated 20 million metric tons per year in the US) is currently being landfilled at a huge cost to utility companies. Scrubber sludge is the solid precipitate produced during desulfurization of flue-gas from burning high sulfur coal. The amount of this sludge is expected to increase in the near future due to ever increasing governmental regulation concerning the amount of sulfur emissions. Scrubber sludge is a fine, grey colored powder that contains calcium sulfite hemihydrate (CaSO{sub 3} {center_dot} 1/2H{sub 2}), calcium sulfate dihydrate (CaSO{sub 4} {center_dot} 2H{sub 2}O), limestone (CaCO{sub 3}), silicates, and iron oxides. This material can continue to be landfilled at a steadily increasing cost, or an alternative for utilizing this material can be developed. This study explores the characteristics of a naturally oxidized wet flue-gas desulfurization scrubber sludge and uses these characteristics to develop alternatives for recycling this material. In order for scrubber sludge to be used as a feed material for various markets, it was necessary to process it to meet the specifications of these markets. A physical separation process was therefore needed to separate the components of this sludge into useful products at a low cost. There are several physical separation techniques available to separate fine particulates. These techniques can be divided into four major groups: magnetic separation, electrostatic separation, physico-chemical separation, and density-based separation. The properties of this material indicated that two methods of separation were feasible: water-only cycloning (density-based separation), and froth flotation (physico-chemical separation). These processes could be used either separately, or in combination. The goal of this study was to reduce the limestone impurity in this scrubber sludge from 5.6% by weight to below 2.0% by weight. The resulting clean calcium sulfite/sulfate material can be oxidized into a synthetic gypsum that can be used in several markets which include: wallboard manufacturing, plaster, portland cement, and as a soil conditioner. Single stage water-only cycloning removed nearly 50% of the limestone by weight from the scrubber sludge and maintained a weight recovery of 76%. Froth flotation produced a calcium sulfite/sulfate that contained 4.30% limestone by weight with a 71% weight recovery. These methods were successful in removing some of the limestone impurity, but were not able to meet the specifications needed. However, the combination of water-only cycloning and froth flotation provided a clean, useful calcium sulfite/sulfate material with a limestone grade of 1.70% by weight and a total weight recovery of nearly 66%.

  20. Hydrogen separation membranes annual report for FY 2010.

    SciTech Connect (OSTI)

    Balachandran, U.; Dorris, S. E; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J. (Energy Systems)

    2011-03-14T23:59:59.000Z

    The objective of this work is to develop dense ceramic membranes for separating hydrogen from other gaseous components in a nongalvanic mode, i.e., without using an external power supply or electrical circuitry. The goal of this project is to develop dense hydrogen transport membranes (HTMs) that nongalvanically (i.e., without electrodes or external power supply) separate hydrogen from gas mixtures at commercially significant fluxes under industrially relevant operating conditions. These membranes will be used to separate hydrogen from gas mixtures such as the product streams from coal gasification, methane partial oxidation, and water-gas shift reactions. Potential ancillary uses of HTMs include dehydrogenation and olefin production, as well as hydrogen recovery in petroleum refineries and ammonia synthesis plants, the largest current users of deliberately produced hydrogen. This report describes the results from the development and testing of HTM materials during FY 2010.

  1. Advanced Sorbents as a Versatile Platform for Gas Separation

    SciTech Connect (OSTI)

    Neil Stephenson

    2003-09-30T23:59:59.000Z

    The program objective was to develop materials and processes for industrial gas separations to reduce energy use and enable waste reduction. The approach chosen combined novel oxygen selective adsorbents and pressure swing adsorption (PSA) processes. Preliminary materials development and process simulation results indicated that oxygen selective adsorbents could provide a versatile platform for industrial gas separations. If fully successful, this new technology offered the potential for reducing the cost of producing nitrogen/oxygen co-products, high purity nitrogen, argon, and possibly oxygen. The potential energy savings for the gas separations are appreciable, but the end users are the main beneficiaries. Lowering the cost of industrial gases expands their use in applications that can employ them for reducing energy consumption and emissions.

  2. Hydrogen separation membranes annual report for FY 2008.

    SciTech Connect (OSTI)

    Balachandran, U.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J.; Energy Systems

    2009-03-17T23:59:59.000Z

    The objective of this work is to develop dense ceramic membranes for separating hydrogen from other gaseous components in a nongalvanic mode, i.e., without using an external power supply or electrical circuitry. The goal of this project is to develop dense hydrogen transport membranes (HTMs) that nongalvanically (i.e., without electrodes or external power supply) separate hydrogen from gas mixtures at commercially significant fluxes under industrially relevant operating conditions. HTMs will be used to separate hydrogen from gas mixtures such as the product streams from coal gasification, methane partial oxidation, and water-gas shift reactions. Potential ancillary uses of HTMs include dehydrogenation and olefin production, as well as hydrogen recovery in petroleum refineries and ammonia synthesis plants, the largest current users of deliberately produced hydrogen. This report describes progress that was made during Fy 2008 on the development of HTM materials.

  3. Methods for separating medical isotopes using ionic liquids

    SciTech Connect (OSTI)

    Luo, Huimin; Boll, Rose Ann; Bell, Jason Richard; Dai, Sheng

    2014-10-21T23:59:59.000Z

    A method for extracting a radioisotope from an aqueous solution, the method comprising: a) intimately mixing a non-chelating ionic liquid with the aqueous solution to transfer at least a portion of said radioisotope to said non-chelating ionic liquid; and b) separating the non-chelating ionic liquid from the aqueous solution. In preferred embodiments, the method achieves an extraction efficiency of at least 80%, or a separation factor of at least 1.times.10.sup.4 when more than one radioisotope is included in the aqueous solution. In particular embodiments, the method is applied to the separation of medical isotopes pairs, such as Th from Ac (Th-229/Ac-225, Ac-227/Th-227), or Ra from Ac (Ac-225 and Ra-225, Ac-227 and Ra-223), or Ra from Th (Th-227 and Ra-223, Th-229 and Ra-225).

  4. Fuel cell repeater unit including frame and separator plate

    DOE Patents [OSTI]

    Yamanis, Jean; Hawkes, Justin R; Chiapetta, Jr., Louis; Bird, Connie E; Sun, Ellen Y; Croteau, Paul F

    2013-11-05T23:59:59.000Z

    An example fuel cell repeater includes a separator plate and a frame establishing at least a portion of a flow path that is operative to communicate fuel to or from at least one fuel cell held by the frame relative to the separator plate. The flow path has a perimeter and any fuel within the perimeter flow across the at least one fuel cell in a first direction. The separator plate, the frame, or both establish at least one conduit positioned outside the flow path perimeter. The conduit is outside of the flow path perimeter and is configured to direct flow in a second, different direction. The conduit is fluidly coupled with the flow path.

  5. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Christopher E. Hull

    2005-01-20T23:59:59.000Z

    The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/Biological Extraction; (4) Modeling and Control; and (5) Environmental Control.

  6. Concentration and separation of biological organisms by ultrafiltration and dielectrophoresis

    DOE Patents [OSTI]

    Simmons, Blake A. (San Francisco, CA); Hill, Vincent R. (Decatur, GA); Fintschenko, Yolanda (Livermore, CA); Cummings, Eric B. (Livermore, CA)

    2010-10-12T23:59:59.000Z

    Disclosed is a method for monitoring sources of public water supply for a variety of pathogens by using a combination of ultrafiltration techniques together dielectrophoretic separation techniques. Because water-borne pathogens, whether present due to "natural" contamination or intentional introduction, would likely be present in drinking water at low concentrations when samples are collected for monitoring or outbreak investigations, an approach is needed to quickly and efficiently concentrate and separate particles such as viruses, bacteria, and parasites in large volumes of water (e.g., 100 L or more) while simultaneously reducing the sample volume to levels sufficient for detecting low concentrations of microbes (e.g., <10 mL). The technique is also designed to screen the separated microbes based on specific conductivity and size.

  7. Evaporation-based Ge/.sup.68 Ga Separation

    DOE Patents [OSTI]

    Mirzadeh, Saed (Albuquerque, NM); Whipple, Richard E. (Los Alamos, NM); Grant, Patrick M. (Los Alamos, NM); O'Brien, Jr., Harold A. (Los Alamos, NM)

    1981-01-01T23:59:59.000Z

    Micro concentrations of .sup.68 Ga in secular equilibrium with .sup.68 Ge in strong aqueous HCl solution may readily be separated in ionic form from the .sup.68 Ge for biomedical use by evaporating the solution to dryness and then leaching the .sup.68 Ga from the container walls with dilute aqueous solutions of HCl or NaCl. The chloro-germanide produced during the evaporation may be quantitatively recovered to be used again as a source of .sup.68 Ga. If the solution is distilled to remove any oxidizing agents which may be present as impurities, the separation factor may easily exceed 10.sup.5. The separation is easily completed and the .sup.68 Ga made available in ionic form in 30 minutes or less.

  8. Method and apparatus for separation of heavy and tritiated water

    DOE Patents [OSTI]

    Lee, Myung W. (late of North Augusta, SC)

    2001-01-01T23:59:59.000Z

    The present invention is a bi-thermal membrane process for separating and recovering hydrogen isotopes from a fluid containing hydrogen isotopes, such as water and hydrogen gas. The process in accordance with the present invention provides counter-current cold and hot streams of the fluid separated with a thermally insulating and chemically transparent proton exchange membrane (PEM). The two streams exchange hydrogen isotopes through the membrane: the heavier isotopes migrate into the cold stream, while the lighter isotopes migrate into the hot stream. The heavy and light isotopes are continuously withdrawn from the cold and hot streams respectively.

  9. Article separation apparatus and method for unit operations

    SciTech Connect (OSTI)

    Pardini, Allan F.; Gervais, Kevin L.; Mathews, Royce A.; Hockey, Ronald L.

    2010-06-22T23:59:59.000Z

    An apparatus and method are disclosed for separating articles from a group of articles. The apparatus includes a container for containing one or more articles coupled to a suitable fluidizer for suspending articles within the container and transporting articles to an induction tube. A portal in the induction tube introduces articles singly into the induction tube. A vacuum pulls articles through the induction tube separating the articles from the group of articles in the container. The apparatus and method can be combined with one or more unit operations or modules, e.g., for inspecting articles, assessing quality of articles, or ascertaining material properties and/or parameters of articles, including layers thereof.

  10. Separation of Nuclear Fuel Surrogates from Silicon Carbide Inert Matrix

    SciTech Connect (OSTI)

    Dr. Ronald Baney

    2008-12-15T23:59:59.000Z

    The objective of this project has been to identify a process for separating transuranic species from silicon carbide (SiC). Silicon carbide has become one of the prime candidates for the matrix in inert matrix fuels, (IMF) being designed to reduce plutonium inventories and the long half-lives actinides through transmutation since complete reaction is not practical it become necessary to separate the non-transmuted materials from the silicon carbide matrix for ultimate reprocessing. This work reports a method for that required process.l

  11. Phase Separation and Emergent Structures in an Active Nematic

    E-Print Network [OSTI]

    Elias Putzig; Aparna Baskaran

    2014-09-03T23:59:59.000Z

    We consider a phenomenological continuum model for an active nematic fluid and show a universal, model independent, instability which renders the homogeneous nematic state unstable to order fluctuations. Using numerical and analytic tools we show that, for low energy excitations in the vicinity of a critical point, this instability leads to a phase separation in which the ordered regions form bands with the direction of nematic order being perpendicular to the direction of density gradient. We argue that this mechanism of phase separation, which we term self-regulation, is a universal feature of active fluids.

  12. Method and apparatus for component separation using microwave energy

    DOE Patents [OSTI]

    Morrow, Marvin S. (Kingston, TN); Schechter, Donald E. (Ten Mile, TN); Calhoun, Jr., Clyde L. (Knoxville, TN)

    2001-04-03T23:59:59.000Z

    A method for separating and recovering components includes the steps of providing at least a first component bonded to a second component by a microwave absorbent adhesive bonding material at a bonding area to form an assembly, the bonding material disposed between the components. Microwave energy is directly and selectively applied to the assembly so that substantially only the bonding material absorbs the microwave energy until the bonding material is at a debonding state. A separation force is applied while the bonding material is at the debonding state to permit disengaging and recovering the components. In addition, an apparatus for practicing the method includes holders for the components.

  13. Process to remove actinides from soil using magnetic separation

    DOE Patents [OSTI]

    Avens, Larry R. (Los Alamos, NM); Hill, Dallas D. (Los Alamos, NM); Prenger, F. Coyne (Los Alamos, NM); Stewart, Walter F. (Las Cruces, NM); Tolt, Thomas L. (Los Alamos, NM); Worl, Laura A. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    A process of separating actinide-containing components from an admixture including forming a slurry including actinide-containing components within an admixture, said slurry including a dispersion-promoting surfactant, adjusting the pH of the slurry to within a desired range, and, passing said slurry through a pretreated matrix material, said matrix material adapted to generate high magnetic field gradients upon the application of a strong magnetic field exceeding about 0.1 Tesla whereupon a portion of said actinide-containing components are separated from said slurry and remain adhered upon said matrix material is provided.

  14. Thermophoretic separation of aerosol particles from a sampled gas stream

    SciTech Connect (OSTI)

    Postma, Arlin K. (Halfway, OR)

    1986-01-01T23:59:59.000Z

    A method for separating gaseous samples from a contained atmosphere that includes aerosol particles uses the step of repelling particles from a gas permeable surface or membrane by heating the surface to a temperature greater than that of the surrounding atmosphere. The resulting thermophoretic forces maintain the gas permeable surface clear of aerosol particles. The disclosed apparatus utilizes a downwardly facing heated plate of gas permeable material to combine thermophoretic repulsion and gravity forces to prevent particles of any size from contacting the separating plate surfaces.

  15. Microfluidic ultrasonic particle separators with engineered node locations and geometries

    DOE Patents [OSTI]

    Rose, Klint A; Fisher, Karl A; Wajda, Douglas A; Mariella, Jr., Raymond P; Bailey, Christoppher; Dehlinger, Dietrich; Shusteff, Maxim; Jung, Byoungsok; Ness, Kevin D

    2014-05-20T23:59:59.000Z

    An ultrasonic microfluidic system includes a separation channel for conveying a sample fluid containing small particles and large particles, flowing substantially parallel, adjacent to a recovery fluid, with which it is in contact. An acoustic transducer produces an ultrasound standing wave, that generates a pressure field having at least one node of minimum pressure amplitude. An acoustic extension structure is located proximate to said separation channel for positioning said acoustic node off center in said acoustic area and concentrating the large particles in said recovery fluid stream.

  16. California Associated-Dissolved Natural Gas, Wet After Lease Separation,

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYearReservesm 3SeparationSeparationProved

  17. Thermophoretic separation of aerosol particles from a sampled gas stream

    DOE Patents [OSTI]

    Postma, A.K.

    1984-09-07T23:59:59.000Z

    This disclosure relates to separation of aerosol particles from gas samples withdrawn from within a contained atmosphere, such as containment vessels for nuclear reactors or other process equipment where remote gaseous sampling is required. It is specifically directed to separation of dense aerosols including particles of any size and at high mass loadings and high corrosivity. The United States Government has rights in this invention pursuant to Contract DE-AC06-76FF02170 between the US Department of Energy and Westinghouse Electric Corporation.

  18. Blind source separation of convolutive mixtures of non circular linearly modulated signals with unknown baud

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Blind source separation of convolutive mixtures of non circular linearly modulated signals addresses the problem of blind separation of convolutive mix- tures of BPSK and circular linearly modulated theoretical statements. Keywords: Blind source separation, Convolutive mixture, Constant Modulus Algorithm

  19. Nineteenth annual actinide separations conference: Conference program and abstracts

    SciTech Connect (OSTI)

    Bronson, M. [ed.

    1995-12-31T23:59:59.000Z

    This report contains the abstracts from the conference presentations. Sessions were divided into the following topics: Waste treatment; Spent fuel treatment; Issues and responses to Defense Nuclear Facility Safety Board 94-1; Pyrochemical technologies; Disposition technologies; and Aqueous separation technologies.

  20. Split-flow regeneration in absorptive air separation

    DOE Patents [OSTI]

    Weimer, R.F.

    1987-11-24T23:59:59.000Z

    A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs. 4 figs.

  1. Split-flow regeneration in absorptive air separation

    DOE Patents [OSTI]

    Weimer, Robert F. (Allentown, PA)

    1987-01-01T23:59:59.000Z

    A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs.

  2. Heuristic Continuous Base Flow Separation Jozsef Szilagyi1

    E-Print Network [OSTI]

    Szilagyi, Jozsef

    Heuristic Continuous Base Flow Separation Jozsef Szilagyi1 Abstract: A digital filtering algorithm 1994 and aquifer characterization Brutsaert and Nie- ber 1977; Troch et al. 1993; Szilagyi et al. 1998; Wittenberg and Sivapalan 1999; Szilagyi et al. 2003 , which is crucial in ascertaining safe yields of water

  3. Charge Separation via Strain in Silicon Zhigang Wu,

    E-Print Network [OSTI]

    Wu, Zhigang

    been used in hybrid organic polymer/inorganic nanocrystal solar cells2,3 and in dye-sensitized solar cells by morphology control, where effectively a type-II homojunction is formed and charge separation expensive solar cells, comparable to the costs of fossil-based electricity, from abundant, environmen- tally

  4. Water purification by shock electrodialysis: Deionization, filtration, separation, and disinfection

    E-Print Network [OSTI]

    Bazant, Martin Z.

    purification is performed primarily by reverse osmosis (RO) plants and in some cases by electrodialysis (EDWater purification by shock electrodialysis: Deionization, filtration, separation, and disinfection H L I G H T S · Experiments demonstrate the multi- functionality of shock electrodialysis. · Besides

  5. Control structure selection for Reactor, Separator and Recycle Process

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control structure selection for Reactor, Separator and Recycle Process T. Larsson M.S. Govatsmark S to control", for a simple plant with a liquid phase reactor, a distillation column and recycle of unreacted study that reactor level should be kept at its maximum, which rules out many of control structures

  6. Separations/pretreatment considerations for Hanford privatization phase 2

    SciTech Connect (OSTI)

    Hunt, R.D.; McGinnis, C.P.; Welch, T.D.

    1998-05-01T23:59:59.000Z

    The Tank Focus Area is funded to develop, demonstrate, and deploy technologies that will assist in the treatment and closure of its nuclear waste tanks. Pretreatment technologies developed to support the privatization effort by the Department of Energy are reviewed. Advancements in evaporation, solid-liquid separation, sludge treatment, solids controls, sodium management, and radionuclide removal are considered.

  7. Separator Design for Use in High GVF Multiphase Flow

    E-Print Network [OSTI]

    Cihak, Daniel

    2012-10-19T23:59:59.000Z

    The requirement of bringing an outside coolant source to run through the seals of a multiphase pump has always been a costly endeavor. Using a separator to extract liquid from the exhaust of the pump to use as a coolant is often more expensive than...

  8. Continuous flow system for controlling phases separation near ? transition

    SciTech Connect (OSTI)

    Chorowski, M.; Poli?ski, J. [Wroc?aw University of Technology, Wybrze?e Wyspia?skiego 27,50-560 Wroc?aw (Poland); Kempi?ski, W.; Trybu?a, Z.; ?o?, Sz. [Institute of Molecular Physics, Polish Academy of Sciences, ul. Smoluchowskiego 17,60-179 Pozna? (Poland); Cho?ast, K.; Kociemba, A. [Polish Oil and Gas Company, Odolanow, ul. Krotoszynska 148, 63-430 Odolanow (Poland)

    2014-01-29T23:59:59.000Z

    As demands on 3He are increasing and conventional 3He production through tritium decay is decreasing, alternative 3He production methods are becoming economically viable. One such possibility is to use entropy filters for extraction of the 3He isotope from natural gas. According to the phase diagram of the 3He, its solidification is impossible by only lowering of the temperature. Hence during the cooling process at stable pressure we can reach ?-point and pass to the special phase - He II. The total density of HeII is a sum of the two phases: normal the superfluid ones. It is possible to separate these two phases with an entropy filter - the barrier for the classically-behaving normal phase. This barrier can also be used to separate the two main isotopes of He: 4He and 3He, because at temperatures close to the 4He-?-point the 3He isotope is part of the normal phase. The paper presents continuous flow schemes of different separation methods of 3He from helium commodity coming from natural gas cryogenic processing. An overall thermodynamic efficiency of the 3He/4He separation process is presented. A simplified model of continuous flow HeI -HeII recuperative heat exchanger is given. Ceramic and carbon porous plugs have been tested in entropy filter applications.

  9. Gas Separation With Graphene Membranes By Will Soutter

    E-Print Network [OSTI]

    Bunch, Scott

    applications including fuel cells, batteries, gas sensors and gas purification. The materials, and inorganic membranes made of ceramics, metals or glass. These membranes all have the key properties nanopores in separating gases like methane, carbon dioxide and hydrogen from air using a model based

  10. Liquidliquid separation in solutions of normal and sickle cell hemoglobin

    E-Print Network [OSTI]

    Vekilov, Peter

    Liquid­liquid separation in solutions of normal and sickle cell hemoglobin Oleg Galkin*, Kai Chen, Comprehensive Sickle Cell Center, Bronx, NY 10461 Edited by John M. Prausnitz, University of California the nucleation of HbS polymers, whose formation is the primary pathogenic event for sickle cell anemia. In view

  11. Separation phenomenon in the Windowless Gaseous Tritium Source of KATRIN

    E-Print Network [OSTI]

    Sharipov, Felix

    Separation phenomenon in the Windowless Gaseous Tritium Source of KATRIN experiment. Ternary separa- tion. In the KATRIN experiment, in order to analyze the spectrum of electrons emmited by Tritium decay, it is very important to know the concentration distribution of Tritium along the source

  12. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Christopher E. Hull

    2005-11-04T23:59:59.000Z

    This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

  13. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Christopher E. Hull

    2006-05-15T23:59:59.000Z

    This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

  14. Crosscutting Technology Development at the Center for Advanced Separation Technologies

    SciTech Connect (OSTI)

    Christopher E. Hull

    2006-09-30T23:59:59.000Z

    This Technical Progress Report describes progress made on the twenty nine subprojects awarded in the second year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

  15. Mechanical Properties of Lithium-Ion Battery Separator Materials

    E-Print Network [OSTI]

    Petta, Jason

    Mechanical Properties of Lithium-Ion Battery Separator Materials Patrick Sinko B.S. Materials Science and Engineering 2013, Virginia Tech John Cannarella PhD. Candidate Mechanical and Aerospace and motivation ­ Why study lithium-ion batteries? ­ Lithium-ion battery fundamentals ­ Why study the mechanical

  16. Hanford Site physical separations CERCLA treatability test plan

    SciTech Connect (OSTI)

    Not Available

    1992-03-01T23:59:59.000Z

    This test plan describes specifications, responsibilities, and general procedures to be followed to conduct a physical separations soil treatability test in the North Process Pond of the 300-FF-1 Operable Unit at the Hanford Site, Washington. The objective of this test is to evaluate the use of physical separation systems as a means of concentrating chemical and radioactive contaminants into fine soil fractions and thereby minimizing waste volumes. If successful the technology could be applied to clean up millions of cubic meters of contaminated soils in waste sites at Hanford and other sites. It is not the intent of this test to remove contaminated materials from the fine soils. Physical separation is a simple and comparatively low cost technology to potentially achieve a significant reduction in the volume of contaminated soils. Organic contaminants are expected to be insignificant for the 300-FF-I Operable Unit test, and further removal of metals and radioactive contaminants from the fine fraction of soils will require secondary treatment such as chemical extraction, electromagnetic separation, or other technologies. Additional investigations/testing are recommended to assess the economic and technical feasibility of applying secondary treatment technologies, but are not within the scope of this test. This plan provides guidance and specifications for the treatability test to be conducted as a service contract. More detailed instructions and procedures will be provided as part of the vendors (sellers) proposal. The procedures will be approved by Westinghouse Hanford Company (Westinghouse Hanford) and finalized by the seller prior to initiating the test.

  17. Blind source separation using spatial and temporal priors

    E-Print Network [OSTI]

    Roberts, Stephen

    #12;Blind source separation using spatial and temporal priors W D Addison Balliol University of Oxford A thesis submitted for the degree of Doctor of Philosophy Trinity 2009 2 #12;3 #12 for providing such fine accommodation in Oxford and to my wife for her incredible patience while this thesis

  18. advanced separation technology: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    advanced separation technology First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 February 2000 Advanced...

  19. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S to obtain a light and a heavy fraction simultaneously from the top and the bottom of the column, while an intermediate fraction may also be recovered in the middle vessel. Two modifications of the multivessel

  20. Electrochemically Mediated Separation for Carbon Capture Michael C. Sterna

    E-Print Network [OSTI]

    change [1]. Since the industrial revolution, fossil fuels have become the primary energy source potential for facilitating CO2 capture at industrial-scale carbon emitters; however, the total operational of installing an electrically driven separation system would also allow its application to other industrial

  1. Diesel: Applying Privilege Separation to Database Access Adrienne Porter Felt

    E-Print Network [OSTI]

    Wagner, David

    Diesel: Applying Privilege Separation to Database Access Adrienne Porter Felt UC Berkeley apf reviewers. We construct a system called Diesel, which implements data sep- aration by intercepting database queries and applying mod- ules' restrictions to the queries. We evaluate Diesel on three widely

  2. Robust Efficient Frontier Analysis with a Separable Uncertainty Model

    E-Print Network [OSTI]

    Robust Efficient Frontier Analysis with a Separable Uncertainty Model Seung-Jean Kim Stephen Boyd efficient frontier, i.e., the optimal trade-off curve in terms of worst-case MV preference, as the extension of the efficient frontier to the worst-case MV analysis setting. We establish some basic properties of the robust

  3. Materials and interfaces for catalysis, separation, storage, and environmental applications

    E-Print Network [OSTI]

    Li, Mo

    and interfaces for a host of sustainable chemical processes that provide renewable (or cleaner) fuels the next generation of catalysts, separation processes, gas and liquid storage technologies, and environmental remediation methods. These materials and technologies are at the heart of industrial processes

  4. SHORT COMMUNICATION Gas-Phase Separations of Protease Digests

    E-Print Network [OSTI]

    Clemmer, David E.

    SHORT COMMUNICATION Gas-Phase Separations of Protease Digests Stephen J. Valentine, Anne E University, Bloomington, Indiana, USA A mixture of peptides from a complete tryptic digest of ubiquitin has and identify peptides from a tryptic digest of ubiquitin. The mixture was electrosprayed into the gas phase

  5. SEPARATION OF OVERLAPPED ELECTROCHEMICAL PEAKS USING THE KALMAN FILTER

    SciTech Connect (OSTI)

    Brown, T.F.; Brown, S.D.

    1981-01-01T23:59:59.000Z

    A major limitation in the use of electrochemical techniques for the quantitative analysis of mixtures is the difficulty of resolving overlapped peaks. This problem is further complicated by the low signal-to-noise ratios often encountered in trace analysis and by the use of electrochemical techniques that produce broad, asymmetric waveforms. This paper demonstrates the use of the Kalman Filter for multi-component analysis of linear sweep voltammograms. Even with the broad, asymmetric LSV waveform, synthetic data runs show that a peak separation of as little as 2.5 mV is sufficient for peak deconvolution in the presence of random noise. Besides separating overlapped peaks, the methods also filters the noise from the signal and can be used to separate the capacitive current component from the faradaic current component. The method is validated further using the Cd(II)/In(III) and Cd(II)/In(III)/Pb(II) systems which show peak separations of 40 to 200 mV. The use of the techniques with two other voltammetric waveforms is also demonstrated.

  6. Waste Management in Dsseldorf Combination of separate collection,

    E-Print Network [OSTI]

    Columbia University

    Waste Management in Düsseldorf Combination of separate collection, recycling and waste-to-energy Biowaste Garden waste Light packaging Paper Glass Wood from bulky waste Bulky waste Rest / mixed waste Bio- Garden- Paper Glass Light Metals Wood Bulky Rest waste waste Card- Pack. waste board Saved CO2

  7. Zeolitic imidazolate frameworks for kinetic separation of propane and propene

    DOE Patents [OSTI]

    Li, Jing; Li, Kunhao; Olson, David H.

    2014-08-05T23:59:59.000Z

    Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.

  8. E-Print Network 3.0 - actinide separations unique Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Separations Technologies... . Both aqueous and nonaqueous (elec- trometallurgical) methods have been developed to separate and reduce... as to tailor their design to take...

  9. Blind separation and tracking of sources with spatial, temporal and spectral dynamics

    E-Print Network [OSTI]

    Masnadi-Shirazi, Alireza

    2012-01-01T23:59:59.000Z

    and Spectral Dynamics in Blind Source Sepa- ration andYilmaz and S. Rickard, Blind separation of speech mixturesH. Sawada, Underdetermined blind separation for speech in

  10. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Hugh W. Rimmer

    2004-05-12T23:59:59.000Z

    This Technical Progress Report describes progress made on the seventeen subprojects awarded in the first year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices. Due to the time taken up by the solicitation/selection process, these cover the initial 6-month period of project activity only. The U.S. is the largest producer of mining products in the world. In 1999, U.S. mining operations produced $66.7 billion worth of raw materials that contributed a total of $533 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium--Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech and University of Nevada, Reno--that is supported through U.S. DOE Cooperative Agreement No. DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation (2) Solid-liquid separation (3) Chemical/Biological Extraction (4) Modeling and Control, and (5) Environmental Control.

  11. Air separation by the Moltox process. Interim final report

    SciTech Connect (OSTI)

    Erickson, D.C.

    1981-04-01T23:59:59.000Z

    Results are described of a development program on a new and energy-saving process for air separation. The Moltox process involves reversibly reacting oxygen in air with a recirculating salt solution, such that oxygen is extracted without depressurizing the remaining nitrogen. Energy savings of approximately 50% are indicated for this process compared to conventional cryogenic air separation. The development program consisted of design, construction, and operation of a 6 liter/minute pilot plant; optimization of the process flowsheet through computer modelling; investigation of engineering aspects of the process including corrosion, safety, and NO/sub x/ generation; and an economic comparison to conventional cryogenic practice. All objectives were satisfactorily achieved except for continuous operation of the pilot plant, and the modifications necessary to achieve that have been identified. Economically the Moltox process shows a substantial advantage over large scale cryogenic plants which are powered by fuel vice electricity.

  12. CRADA Final Report: Ionically Conductive Membranes Oxygen Separation

    SciTech Connect (OSTI)

    Visco, Steven J.

    2001-10-29T23:59:59.000Z

    Scientists at the Lawrence Berkeley National Laboratory (LBNL) in a collaborative effort with Praxair Corporation developed a bench-top oxygen separation unit capable of producing ultra-high purity oxygen from air. The device is based on thin-film electrolyte technology developed at LBNL as part of a solid oxide fuel cell program. The two teams first demonstrated the concept using planar ceramic disks followed by the development of tubular ceramic structures for the bench-top unit. The highly successful CRADA met all technical milestones on time and on budget. Due to the success of this program the industrial partner and the team at LBNL submitted a grant proposal for further development of the unit to the Advanced Technology Program administered by the National Institute of Standar~s. This proposal was selected for funding, and now the two teams are developing a precommercial oxygen separation unit under a 3-year, $6 million dollar program.

  13. Axial Current Generation from Electric Field: Chiral Electric Separation Effect

    E-Print Network [OSTI]

    Xu-Guang Huang; Jinfeng Liao

    2013-06-07T23:59:59.000Z

    We study a relativistic plasma containing charged chiral fermions in an external electric field. We show that with the presence of both vector and axial charge densities, the electric field can induce an axial current along its direction and thus cause chirality separation. We call it the Chiral Electric Separation Effect (CESE). On very general basis, we argue that the strength of CESE is proportional to $\\mu_V\\mu_A$ with $\\mu_V$ and $\\mu_A$ the chemical potentials for vector charge and axial charge. We then explicitly calculate this CESE conductivity coefficient in thermal QED at leading-log order. The CESE can manifest a new gapless wave mode propagating along the electric field. Potential observable of CESE in heavy-ion collisions is also discussed.

  14. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01T23:59:59.000Z

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  15. Development of Halide and Oxy-Halides for Isotopic Separations

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Jana Pfeiffer; Martha R. Finck

    2014-10-01T23:59:59.000Z

    The goal of this project was to synthesize a volatile form of Np for introduction into mass spectrometers at INL. Volatile solids of the 5f elements are typically those of the halides (e.g. UF6), however fluorine is highly corrosive to the sensitive internal components of the mass separator, and the other volatile halides exist as several different stable isotopes in nature. However, iodide is both mono-isotopic and volatile, and as such presents an avenue for creation of a form of Np suitable for introduction into the mass separator. To accomplish this goal, the technical work in the project sought to establish a novel synthetic route for the conversion NpO2+ (dissolved in nitric acid) to NpI3 and NpI4.

  16. Process for separation and preconcentration of radium from water

    DOE Patents [OSTI]

    Dietz, M.; Horwitz, E.P.; Chiarizia, R.; Bartsch, R.A.

    1999-01-26T23:59:59.000Z

    A process for preconcentrating and separating radium from a contaminated solution containing at least water and radium includes the steps of adding a quantity of a water-soluble macrocyclic polyether to the contaminated solution to form a combined solution. An acid is added to the combined solution to form an acidic combined solution having an [H{sup +}] concentration of about 0.5M. The acidic combined solution is contacted with a sulfonic acid-based strong acid cation exchange medium or a organophilic sulfonic acid medium having a plurality of binding sites thereon to bind the radium thereto and to form a radium-depleted solution. The radium-depleted solution is separated from the strong acid cation exchange medium or organophilic sulfonic acid medium. The radium remaining bound to the exchange medium or organophilic reagent is then stripped from the exchange medium or organophilic medium and the activity of the radium is measured. 24 figs.

  17. Separating hydrogen from coal gasification gases with alumina membranes

    SciTech Connect (OSTI)

    Egan, B.Z. (Oak Ridge National Lab., TN (USA)); Fain, D.E.; Roettger, G.E.; White, D.E. (Oak Ridge K-25 Site, TN (USA))

    1991-01-01T23:59:59.000Z

    Synthesis gas produced in coal gasification processes contains hydrogen, along with carbon monoxide, carbon dioxide, hydrogen sulfide, water, nitrogen, and other gases, depending on the particular gasification process. Development of membrane technology to separate the hydrogen from the raw gas at the high operating temperatures and pressures near exit gas conditions would improve the efficiency of the process. Tubular porous alumina membranes with mean pore radii ranging from about 9 to 22 {Angstrom} have been fabricated and characterized. Based on hydrostatic tests, the burst strength of the membranes ranged from 800 to 1600 psig, with a mean value of about 1300 psig. These membranes were evaluated for separating hydrogen and other gases. Tests of membrane permeabilities were made with helium, nitrogen, and carbon dioxide. Measurements were made at room temperature in the pressure range of 15 to 589 psi. Selected membranes were tested further with mixed gases simulating a coal gasification product gas. 5 refs., 7 figs.

  18. Phase Separation Dynamics in Isotropic Ion-Intercalation Particles

    E-Print Network [OSTI]

    Zeng, Yi

    2013-01-01T23:59:59.000Z

    Lithium-ion batteries exhibit complex nonlinear dynamics, resulting from diffusion and phase transformations coupled to ion intercalation reactions. Using the recently developed Cahn-Hilliard reaction (CHR) theory, we investigate a simple mathematical model of ion intercalation in a spherical solid nanoparticle, which predicts transitions from solid-solution radial diffusion to two-phase shrinking-core dynamics. This general approach extends previous Li-ion battery models, which either neglect phase separation or postulate a spherical shrinking-core phase boundary, by predicting phase separation only under appropriate circumstances. The effect of the applied current is captured by generalized Butler-Volmer kinetics, formulated in terms of diffusional chemical potentials, and the model consistently links the evolving concentration profile to the battery voltage. We examine sources of charge/discharge asymmetry, such as asymmetric charge transfer and surface "wetting" by ions within the solid, which can lead to...

  19. Star/Galaxy Separation Revisited : Into the Zone of Avoidance

    E-Print Network [OSTI]

    A. Naim

    1997-01-29T23:59:59.000Z

    The problem of automated separation of stars and galaxies on photographic plates is revisited with two goals in mind : First, to separate galaxies from everything else (as opposed to most previous work, in which galaxies were lumped together with all other non-stellar images). And second, to search optically for galaxies at low Galactic latitudes (an area that has been largely avoided in the past). This paper demonstrates how an artificial neural network can be trained to achieve both goals on Schmidt plates of the Digitised Sky Survey. Here I present the method while its application to large numbers of plates is deferred to a later paper. Analysis is also provided of the way in which the network operates and the results are used to counter claims that it is a complicated and incomprehensible tool.

  20. Non-destructive component separation using infrared radiant energy

    DOE Patents [OSTI]

    Simandl, Ronald F. (Knoxville, TN); Russell, Steven W. (Knoxville, TN); Holt, Jerrid S. (Knoxville, TN); Brown, John D. (Harriman, TN)

    2011-03-01T23:59:59.000Z

    A method for separating a first component and a second component from one another at an adhesive bond interface between the first component and second component. Typically the method involves irradiating the first component with infrared radiation from a source that radiates substantially only short wavelengths until the adhesive bond is destabilized, and then separating the first component and the second component from one another. In some embodiments an assembly of components to be debonded is placed inside an enclosure and the assembly is illuminated from an IR source that is external to the enclosure. In some embodiments an assembly of components to be debonded is simultaneously irradiated by a multi-planar array of IR sources. Often the IR radiation is unidirectional. In some embodiments the IR radiation is narrow-band short wavelength infrared radiation.

  1. Pretreatment/Radionuclide Separations of Cs/Tc from Supernates

    SciTech Connect (OSTI)

    Thompson, M.C. [Westinghouse Savannah River Company, AIKEN, SC (United States)

    1998-09-01T23:59:59.000Z

    Significant improvements have been made in ion exchange and solvent extraction materials and processes available for separation of the radionuclides cesium and technetium from both acid and alkaline waste solutions. New ion exchange materials and solvent extraction reagents are more selective for Cs over sodium and potassium than previous materials. The higher selectivity gives higher Cs capacity and improved separation processes. Technetium removal has been improved by new ion exchange resins, which have either improved capacity or easier elution. Several different crown ethers have been shown to extract pertechnetate ion selectively over other anions. Organic complexants in some waste solutions reduce pertechnetate ion and stabilize the reduced species. Selective oxidation allows conversion to pertechnetate without oxidation of the organic complexants.

  2. Isotope separation with the RICH detector of the AMS Experiment

    E-Print Network [OSTI]

    Arruda, Lusa; Borges, Joo; Carmo, Fernando; Gonalves, Patrcia; Pereira, Rui; Pimenta, Mrio

    2007-01-01T23:59:59.000Z

    The Alpha Magnetic Spectrometer (AMS), to be installed on the International Space Station (ISS) in 2008, is a cosmic ray detector with several subsystems, one of which is a proximity focusing Ring Imaging Cherenkov (RICH) detector. This detector will be equipped with a dual radiator (aerogel+NaF), a lateral conical mirror and a detection plane made of 680 photomultipliers and light guides, enabling precise measurements of particle electric charge and velocity. Combining velocity measurements with data on particle rigidity from the AMS Tracker it is possible to obtain a measurement for particle mass, allowing the separation of isotopes. A Monte Carlo simulation of the RICH detector, based on realistic properties measured at ion beam tests, was performed to evaluate isotope separation capabilities. Results for three elements -- H (Z=1), He (Z=2) and Be (Z=4) -- are presented.

  3. Americium separation from nuclear fuel dissolution using higher oxidation states.

    SciTech Connect (OSTI)

    Bruce J. Mincher

    2009-09-01T23:59:59.000Z

    Much of the complexity in current AFCI proposals is driven by the need to separate the minor actinides from the lanthanides. Partitioning and recycling Am, but not Cm, would allow for significant simplification because Am has redox chemistry that may be exploited while Cm does not. Here, we have explored methods based on higher oxidation states of Am (AmV and AmVI) to partition Am from the lanthanides. In a separate but related approach we have also initiated an investigation of the utility of TRUEX Am extraction from thiocyanate solution. The stripping of loaded TRUEX by Am oxidation or SCN- has not yet proved successful; however, the partitioning of inextractable AmV by TRUEX shows promise.

  4. Hybrid membrane--PSA system for separating oxygen from air

    DOE Patents [OSTI]

    Staiger, Chad L. (Albuquerque, NM); Vaughn, Mark R. (Albuquerque, NM); Miller, A. Keith (Albuquerque, NM); Cornelius, Christopher J. (Blackburg, VA)

    2011-01-25T23:59:59.000Z

    A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

  5. Separation and concentration of lower alcohols from dilute aqueous solutions

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Eakin, David E. (Kennewick, WA); Baker, Eddie G. (Richland, WA); Hallen, Richard T. (Richland, WA)

    1991-01-01T23:59:59.000Z

    A process for producing, from a dilute aqueous solution of a lower (C.sub.1 -C.sub.5) alcohol, a concentrated liquid solution of the alcohol in an aromatic organic solvent is disclosed. Most of the water is removed from the dilute aqueous solution of alcohol by chilling sufficiently to form ice crystals. Simultaneously, the remaining liquid is extracted at substantially the same low temperature with a liquid organic solvent that is substantially immiscible in aqueous liquids and has an affinity for the alcohol at that temperature, causing the alcohol to transfer to the organic phase. After separating the organic liquid from the ice crystals, the organic liquid can be distilled to enrich the concentration of alcohol therein. Ethanol so separated from water and concentrated in an organic solvent such as toluene is useful as an anti-knock additive for gasoline.

  6. Hydrodynamic coarsening in phase-separated silicate melts

    E-Print Network [OSTI]

    David Bouttes; Ocane Lambert; Corinne Claireaux; William Woelffel; Davy Dalmas; Emmanuelle Gouillart; Pierre Lhuissier; Luc Salvo; Elodie Boller; Damien Vandembroucq

    2015-02-12T23:59:59.000Z

    Using in-situ synchrotron tomography, we investigate the coarsening dynamics of barium borosilicate melts during phase separation. The 3-D geometry of the two interconnected phases is determined thanks to image processing. We observe a linear growth of the size of domains with time, at odds with the sublinear diffusive growth usually observed in phase-separating glasses or alloys. Such linear coarsening is attributed to viscous flow inside the bicontinuous phases, and quantitative measurements show that the growth rate is well explained by the ratio of surface tension over viscosity. The geometry of the domains is shown to be statistically similar at different times, provided that the microstructure is rescaled by the average domain size. Complementary experiments on melts with a droplet morphology demonstrate that viscous flow prevails over diffusion in the large range of domain sizes measured in our experiments (1 - 80 microns).

  7. Separation of anthracene from crude anthracene using gas antisolvent recrystallization

    SciTech Connect (OSTI)

    Yuchung Liou; Chiehming Chang (Yuan-Ze Inst. of Tech., Neili (Taiwan))

    1992-08-01T23:59:59.000Z

    Pure anthracene is mostly used for conversion to anthraquinone, an intermediate for the synthesis of very powerful vat dyestuffs. A coal tar distillate, crude anthracene, which contains 30% anthracene, 25% phenanthrene, 15% carbazole, and other impurities, was used as the model mixture. In this study, 90% by weight purity anthracene was obtained using gas antisolvent (GAS) recrystallization. The GAS process induces the separation of solids by introducing an antisolvent, carbon dioxide (or the supercritical fluid), into acetone which was used as the liquid solvent. The dissolution of the compressed gas into the solute-laden solution selectively lowers the solubilities of solid solutes and salts them out. The results showed that high purity anthracene was obtained at a high feed concentration and high pressure conditions. The separation factor of anthracene versus phenanthrene is close to 30.07.

  8. Sulfolane-Cross-Polybenzimidazole Membrane For Gas Separation

    DOE Patents [OSTI]

    Young, Jennifer S. (Los Alamos, NM); Long, Gregory S. (Los Alamos, NM); Espinoza, Brent F. (Los Alamos, NM)

    2006-02-14T23:59:59.000Z

    A cross-linked, supported polybenzimidazole membrane for gas separation is prepared by reacting polybenzimidazole (PBI) with the sulfone-containing crosslinking agent 3,4-dichloro-tetrahydro-thiophene-1,1-dioxide. The cross-linked reaction product exhibits enhanced gas permeability to hydrogen, carbon dioxide, nitrogen, and methane as compared to the unmodified analog, without significant loss of selectivity, at temperatures from about 20 degrees Celsius to about 400 degrees Celsius.

  9. MassMass transfer andtransfer and separation technologyseparation technology

    E-Print Network [OSTI]

    Zevenhoven, Ron

    liquid extraction involves three stages: ­ Contacting / extraction al-extraction.j ­ Separation the component of interest solute (A) will distribute over extract (E, phase II or 2) and raffinate (R, phase I with equilibrium constant K: 4 erföringo cA,II/cA,I = K´ , or Massöve xA,E/xA,R = xA,II/xA,I = xA,2/xA,1 = K K´= K

  10. NOVEL CONCEPTS FOR ISOTOPIC SEPARATION OF 3HE/4HE

    SciTech Connect (OSTI)

    Roy, L.; Nigg, H.; Watson, H.

    2012-09-04T23:59:59.000Z

    The research outlined below established theoretical proof-of-concept using ab initio calculations that {sup 3}He can be separated from {sup 4}He by taking advantage of weak van der Waals interactions with other higher molecular weight rare gases such as xenon. To the best of our knowledge, this is the only suggested method that exploits the physical differences of the isotopes using a chemical interaction.

  11. Gas separation device based on electrical swing adsorption

    DOE Patents [OSTI]

    Judkins, Roddie R. (Knoxville, TN); Burchell, Timothy D. (Oak Ridge, TN)

    1999-10-26T23:59:59.000Z

    A method and apparatus for separating one constituent, especially carbon dioxide, from a fluid mixture, such as natural gas. The fluid mixture flows through an adsorbent member having an affinity for molecules of the one constituent, the molecules being adsorbed on the adsorbent member. A voltage is applied to the adsorbent member, the voltage imparting a current flow which causes the molecules of the one constituent to be desorbed from the adsorbent member.

  12. Self-doped microphase separated block copolymer electrolyte

    DOE Patents [OSTI]

    Mayes, Anne M. (Waltham, MA); Sadoway, Donald R. (Waltham, MA); Banerjee, Pallab (Boston, MA); Soo, Philip (Cambridge, MA); Huang, Biying (Cambridge, MA)

    2002-01-01T23:59:59.000Z

    A polymer electrolyte includes a self-doped microphase separated block copolymer including at least one ionically conductive block and at least one second block that is immiscible in the ionically conductive block, an anion immobilized on the polymer electrolyte and a cationic species. The ionically conductive block provides a continuous ionically conductive pathway through the electrolyte. The electrolyte may be used as an electrolyte in an electrochemical cell.

  13. S'eparation des convexes J.Ch. Gilbert, Inria

    E-Print Network [OSTI]

    S'eparation des convexes J.Ch. Gilbert, Inria Th'eor`eme de Hahn­Banach (forme analytique) ffl Soit. ffl Th'eor`eme de Hahn­Banach (forme analytique). Si \\Delta E est un espace vectoriel (non n toujours un f tel que l'on ait 'egalit'e. 1 #12; Th'eor`emes de Hahn­Banach (formes g'eom'etriques) ffl

  14. Organic light emitting device having multiple separate emissive layers

    DOE Patents [OSTI]

    Forrest, Stephen R. (Ann Arbor, MI)

    2012-03-27T23:59:59.000Z

    An organic light emitting device having multiple separate emissive layers is provided. Each emissive layer may define an exciton formation region, allowing exciton formation to occur across the entire emissive region. By aligning the energy levels of each emissive layer with the adjacent emissive layers, exciton formation in each layer may be improved. Devices incorporating multiple emissive layers with multiple exciton formation regions may exhibit improved performance, including internal quantum efficiencies of up to 100%.

  15. Maximum Entry and Mandatory Separation Ages for Certain Security Employees

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-10-11T23:59:59.000Z

    The policy establishes the DOE policy on maximum entry and mandatory separation ages for primary or secondary positions covered under special statutory retirement provisions and for those employees whose primary duties are the protection of officials of the United States against threats to personal safety or the investigation, apprehension, and detention of individuals suspected or convicted of offenses against the criminal laws of the United States. Admin Chg 1, dated 12-1-11, cancels DOE P 310.1.

  16. Establishment of the Center for Advanced Separation Technologies

    SciTech Connect (OSTI)

    Christopher E. Hull

    2006-09-30T23:59:59.000Z

    This Final Technical Report covers the eight sub-projects awarded in the first year and the five projects awarded in the second year of Cooperative Agreement DE-FC26-01NT41091: Establishment of the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices.

  17. Countercurrent Process for Lignin Separation from Biomass Matrix

    SciTech Connect (OSTI)

    Kiran Kadam; Ed Lehrburger

    2006-03-31T23:59:59.000Z

    The overall goal of the project was to test the concept of using a twin-screw extruder to conduct autohydrolysis pretreatment of wheat straw in countercurrent fashion, demonstrate in situ solid/liquid separation, and produce a low-lignin cellulose product using ethanol as an extractant. The resultant solid product is suitable for sugar production through enzymatic hydrolysis and for pulp applications. Pilot-scale equipment was used to successfully demonstrate the process both for sugar and pulp applications.

  18. Crosscutting Technology Development at the Center for Advanced Separation Technologies

    SciTech Connect (OSTI)

    Christopher Hull

    2009-10-31T23:59:59.000Z

    The U.S. is the largest producer of mining products in the world. In 2003, U.S. mining operations produced $57 billion worth of raw materials that contributed a total of $564 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium -- Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech and University of Nevada, Reno - that is supported through U.S. DOE Cooperative Agreement No. DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (1) Solid-solid separation; (2) Solid-liquid separation; (3) Chemical/biological extraction; (4) Modeling and control; and (5) Environmental control. Distribution of funds is handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. The successful projects are listed by category, along with brief abstracts of their aims and objectives.

  19. Mechanism governing separation in microfluidic pinched flow fractionation devices

    E-Print Network [OSTI]

    Sumedh R. Risbud; German Drazer

    2014-04-04T23:59:59.000Z

    We present a computational investigation of the mechanism governing size-based particle separation in microfluidic pinched flow fractionation. We study the behavior of particles moving through a pinching gap (i.e., a constriction in the aperture of a channel) in the Stokes regime as a function of particle size. The constriction aperture is created by a plane wall and spherical obstacle, and emulates the pinching segment in pinched flow fractionation devices. The simulation results show that the distance of closest approach between the particle and obstacle surfaces (along a trajectory) decreases with increasing particle size. We then use the distance of closest approach to investigate the effect of short-range repulsive non-hydrodynamic interactions (e.g., solid-solid contact). We define a critical trajectory as the one in which the minimum particle-obstacle separation is equal to the range of the non-hydrodynamic interactions. The results further show that the initial offset of the critical trajectory (defined as the critical offset) increases with particle size. We interpret the variation of the critical offset with particle size as the basis for size-based microfluidic separation in pinched flow fractionation. We also compare the effect of different driving fields on the particle trajectories; we simulate a constant force driving the particles in a quiescent fluid as well as a freely suspended particles in a pressure-driven flow. We observe that the particles driven by a constant force approach closer to the obstacle than those suspended in a flow (for the same initial offset). On the other hand, the increment in the critical offset (as a function of particle size) is larger in the pressure-driven case than in the force-driven case. Thus, pressure-driven particle separation using pinched flow fractionation would prove more effective than its force-driven counterpart.

  20. Separation Programs Releases and Waivers | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of Energyof the Americas | DepartmentDepartmentDepartmentSendSeparation Programs

  1. Louisiana Associated-Dissolved Natural Gas, Wet After Lease Separation,

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year in Review1,213Separation, Proved Reserves

  2. Louisiana Nonassociated Natural Gas, Wet After Lease Separation, Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year in Review1,213Separation,Year Jan

  3. Louisiana State Offshore Natural Gas, Wet After Lease Separation Proved

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year in Review1,213Separation,Year(Billion

  4. The modern day discount house as a separate retail establishment

    E-Print Network [OSTI]

    Broussard, Carroll James

    2012-06-07T23:59:59.000Z

    Opinions of Authorities In Retailing Analysis of Authorities' Conclusions Author's Conclusions Settling of Retail Margins Trend Toward Larger Stores Elimination of "List Price" and "Fair Trade" Every Large Retailer a Type of Department St, ore... Department Store X, 1955 22 Gross Margin, Old-Line Retailers Versus Masters, Inc. , 1954 Listed Discounts in Different Departments oi' Better Business Buying, Inc. , Berkeley, cali fornia--1955 25 27 THE MODERN DAY DISCOUNT HOUSE AS A SEPARATE RETAIL...

  5. ESTABLISHMENT OF THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Hugh W. Rimmer

    2003-07-01T23:59:59.000Z

    Technical Progress Report describes progress made on the eight sub-projects awarded in the first year of Cooperative Agreement DE-FC26-01NT41091: Establishment of the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices. Due to the time taken up by the solicitation/selection process, these cover the initial 6-month period of activity only.

  6. Correction to "Blind Source Separation Using Renyi's Mutual Information" Abstract: The paper entitled, "Blind Source Separation Using Renyi's Mutual Information," was

    E-Print Network [OSTI]

    Slatton, Clint

    Correction to "Blind Source Separation Using Renyi's Mutual Information" Abstract: The paper entitled, "Blind Source Separation Using Renyi's Mutual Information," was found to contain an incorrect of Florida Gainesville, FL 32611, USA The authors of the paper entitled, "Blind Source Separation Using Renyi

  7. Ammonia-Activated Mesoporous Carbon Membranes for Gas Separations

    SciTech Connect (OSTI)

    Mahurin, Shannon Mark [ORNL; Lee, Jeseung [ORNL; Wang, Xiqing [ORNL; Dai, Sheng [ORNL

    2011-01-01T23:59:59.000Z

    Porous carbon membranes, which generally show improved chemical and thermal stability compared to polymer membranes, have been used in gas separations for many years. In this work, we show that the post-synthesis ammonia treatment of porous carbon at elevated temperature can improve the permeance and selectivity of these membranes for the separation of carbon dioxide and hydrocarbons from permanent gases. Hierarchically structured porous carbon membranes were exposed to ammonia gas at temperatures ranging from 850 C to 950 C for up to 10 min and the N{sub 2}, CO{sub 2}, and C{sub 3}H{sub 6} permeances were measured for these different membranes. Higher treatment temperatures and longer exposure times resulted in higher gas permeance values. In addition, CO{sub 2}/N{sub 2} and C{sub 3}H{sub 6}/N{sub 2} selectivities increased by a factor of 2 as the treatment temperature and time increased up to a temperature and time of 900 C, 10 min. Higher temperatures showed increased permeance but decreased selectivity indicating excess pore activation. Nitrogen adsorption measurements show that the ammonia treatment increased the porosity of the membrane while elemental analysis revealed the presence of nitrogen-containing surface functionalities in the treated carbon membranes. Thus, ammonia treatment at high temperature provides a controlled method to introduce both added microporosity and surface functionality to enhance gas separations performance of porous carbon membranes.

  8. Computational investigation of thermal gas separation for CO2 capture.

    SciTech Connect (OSTI)

    Gallis, Michail A.; Bryan, Charles R.; Brady, Patrick Vane; Torczynski, John Robert; Brooks, Carlton, F.

    2009-09-01T23:59:59.000Z

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 09-1351, 'Computational Investigation of Thermal Gas Separation for CO{sub 2} Capture'. Thermal gas separation for a binary mixture of carbon dioxide and nitrogen is investigated using the Direct Simulation Monte Carlo (DSMC) method of molecular gas dynamics. Molecular models for nitrogen and carbon dioxide are developed, implemented, compared to theoretical results, and compared to several experimental thermophysical properties. The molecular models include three translational modes, two fully excited rotational modes, and vibrational modes, whose degree of excitation depends on the temperature. Nitrogen has one vibrational mode, and carbon dioxide has four vibrational modes (two of which are degenerate). These models are used to perform a parameter study for mixtures of carbon dioxide and nitrogen confined between parallel walls over realistic ranges of gas temperatures and nominal concentrations of carbon dioxide. The degree of thermal separation predicted by DSMC is slightly higher than experimental values and is sensitive to the details of the molecular models.

  9. Supercritical Fluid Extraction and Separation of Uranium from Other Actinides

    SciTech Connect (OSTI)

    Donna L. Quach; Bruce J. Mincher; Chien M. Wai

    2014-06-01T23:59:59.000Z

    This paper investigates the feasibility of separating uranium from other actinides by using supercritical fluid carbon dioxide (sc-CO2) as a solvent modified with tri-n-butylphosphate (TBP) for the development of an extraction and counter current stripping technique, which would be a more efficient and environmentally benign technology for used nuclear fuel reprocessing compared to traditional solvent extraction. Several actinides (U(VI), Np(VI), Pu(IV), and Am(III)) were extracted in sc-CO2 modified with TBP over a range of nitric acid concentrations and then the actinides were exposed to reducing and complexing agents to suppress their extractability. According to this study, the separation of uranium from plutonium in sc-CO2 modified with TBP was successful at nitric acid concentrations of less than 3 M in the presence of acetohydroxamic acid or oxalic acid, and the separation of uranium from neptunium was successful at nitric acid concentrations of less than 1 M in the presence of acetohydroxamic acid, oxalic acid, or sodium nitrite.

  10. Combined heat and mass transfer device for improving separation process

    DOE Patents [OSTI]

    Tran, Thanh Nhon (Flossmoor, IL)

    1999-01-01T23:59:59.000Z

    A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area.

  11. Combined heat and mass transfer device for improving separation process

    DOE Patents [OSTI]

    Tran, T.N.

    1999-08-24T23:59:59.000Z

    A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area. 12 figs.

  12. Plasmons in spatially separated double-layer graphene nanoribbons

    SciTech Connect (OSTI)

    Bagheri, Mehran, E-mail: mh-bagheri@sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, G. C., Evin, Tehran 19835-63113 (Iran, Islamic Republic of); Bahrami, Mousa [ICFO-Institut de Ciencies Fotoniques, Parc Mediterrani de la Tecnologia, 08860 Castelldefels (Barcelona) (Spain)

    2014-05-07T23:59:59.000Z

    Motivated by innovative progresses in designing multi-layer graphene nanostructured materials in the laboratory, we theoretically investigate the Dirac plasmon modes of a spatially separated double-layer graphene nanoribbon system, made up of a vertically offset armchair and metallic graphene nanoribbon pair. We find striking features of the collective excitations in this novel Coulomb correlated system, where both nanoribbons are supposed to be either intrinsic (undoped/ungated) or extrinsic (doped/gated). In the former, it is shown the low-energy acoustical and the high-energy optical plasmon modes are tunable only by the inter-ribbon charge separation. In the later, the aforementioned plasmon branches are modified by the added doping factor. As a result, our model could be useful to examine the existence of a linear Landau-undamped low-energy acoustical plasmon mode tuned via the inter-ribbon charge separation as well as doping. This study might also be utilized for devising novel quantum optical waveguides based on the Coulomb coupled graphene nanoribbons.

  13. Journal of Chromatography B, 800 (2004) 8389 Plastic substrates based separation channels in

    E-Print Network [OSTI]

    Miksik, Ivan

    for manufacturing separation columns (polyester and polyurethane capillaries were used) or separation channels as the test mixture. Using -cyclodextrin additive to the background electrolyte in the case of the chip to a considerable extent poly- meric substrates for manufacturing the separation channels. Separation on silica

  14. Separations and Waste Forms Research and Development: FY 2012 Accomplishments Report

    SciTech Connect (OSTI)

    Not Listed

    2013-02-01T23:59:59.000Z

    This report contains FY 2012 accomplishments for the Separations and Waste Form Research and Development Project.

  15. STATISTICAL PROPERTIES OF STFT RATIOS FOR TWO CHANNEL SYSTEMS AND APPLICATIONS TO BLIND SOURCE SEPARATION

    E-Print Network [OSTI]

    Balan, Radu V.

    SEPARATION Radu Balan and Justinian Rosca frvbalan,roscag@scr.siemens.com Siemens Corporate Research

  16. Use of exhaust gas as sweep flow to enhance air separation membrane performance

    DOE Patents [OSTI]

    Dutart, Charles H. (Washington, IL); Choi, Cathy Y. (Morton, IL)

    2003-01-01T23:59:59.000Z

    An intake air separation system for an internal combustion engine is provided with purge gas or sweep flow on the permeate side of separation membranes in the air separation device. Exhaust gas from the engine is used as a purge gas flow, to increase oxygen flux in the separation device without increasing the nitrogen flux.

  17. CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Hugh W. Rimmer

    2003-11-15T23:59:59.000Z

    The U.S. is the largest producer of mining products in the world. In 1999, U.S. mining operations produced $66.7 billion worth of raw materials that contributed a total of $533 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Much of the research to be conducted with Cooperative Agreement funds will be longer-term, high-risk, basic research and will be carried out in five broad areas: (a) Solid-solid separation (b) Solid-liquid separation (c) Chemical/Biological Extraction (d) Modeling and Control, and (e) Environmental Control. Distribution of funds is being handled via competitive solicitation of research proposals through Site Coordinators at the seven member universities. The first of these solicitations, referred to as the CAST II-Round 1 RFP, was issued on October 28, 2002. Thirty-eight proposals were received by the December 10, 2002 deadline for this RFP-eleven (11) Solid-Solid Separation, seven (7) Solid-Liquid Separation, ten (10) Chemical/Biological Extraction, six (6) Modeling & Control and four (4) Environmental Control. These were first reviewed and ranked by a group of technical reviewers (selected primarily from industry). Based on these reviews, and an assessment of overall program requirements, the CAST Technical Committee made an initial selection/ranking of proposals and forwarded these to the DOE/NETL Project Officer for final review and approval. This process took some 7 months to complete but 17 projects (one joint) were in place at the constituent universities (three at Virginia Tech, two at West Virginia University, three at University of Kentucky, three at University of Utah, three at Montana Tech, three at New Mexico Tech, and one at the University of Nevada, Reno) by May 17, 2003. These projects are listed by category, along with brief abstracts of their aims and objectives.

  18. Separation of Highly Complex Mixtures by Two-Dimension Liquid Chromatography

    SciTech Connect (OSTI)

    Georges Guiochon

    2009-12-11T23:59:59.000Z

    This report summarizes the progress made on the title project during the grant period. We developed a new classification of two-dimensional separations based on the observation that separations can be made in time or in space. Thus, two-dimensional separations can be made in timetime, spacespace, spacetime, or timespace. The two successive separations must use two different modes of chromatography that afford uncorrelated or weakly correlated patterns of retention factors for the components of the samples analyzed. Our attention was mainly focused on the separation of protein digests, particularly, on those of the digests of myoglobin and bovine serum albumin as model systems and extremely efficient temporal separations were developed. We also designed and constructed new instruments to carry out spacespace separations (True Bidimensional Chromatography, HPLC2 or spacial separations) and timespace separations (a new hybrid combination of a temporal and a spacial separation that we designed).

  19. High gliding fluid power generation system with fluid component separation and multiple condensers

    DOE Patents [OSTI]

    Mahmoud, Ahmad M; Lee, Jaeseon; Radcliff, Thomas D

    2014-10-14T23:59:59.000Z

    An example power generation system includes a vapor generator, a turbine, a separator and a pump. In the separator, the multiple components of the working fluid are separated from each other and sent to separate condensers. Each of the separate condensers is configured for condensing a single component of the working fluid. Once each of the components condense back into a liquid form they are recombined and exhausted to a pump that in turn drives the working fluid back to the vapor generator.

  20. Separated Response Function Ratios in Exclusive, Forward pi^{+/-} Electroproduction

    E-Print Network [OSTI]

    G. M. Huber; H. P. Blok; C. Butuceanu; D. Gaskell; T. Horn; D. J. Mack; D. Abbott; K. Aniol; H. Anklin; C. Armstrong; J. Arrington; K. Assamagan; S. Avery; O. K. Baker; B. Barrett; E. J. Beise; C. Bochna; W. Boeglin; E. J. Brash; H. Breuer; C. C. Chang; N. Chant; M. E. Christy; J. Dunne; T. Eden; R. Ent; H. Fenker; E. F. Gibson; R. Gilman; K. Gustafsson; W. Hinton; R. J. Holt; H. Jackson; S. Jin; M. K. Jones; C. E. Keppel; P. H. Kim; W. Kim; P. M. King; A. Klein; D. Koltenuk; V. Kovaltchouk; M. Liang; J. Liu; G. J. Lolos; A. Lung; D. J. Margaziotis; P. Markowitz; A. Matsumura; D. McKee; D. Meekins; J. Mitchell; T. Miyoshi; H. Mkrtchyan; B. Mueller; G. Niculescu; I. Niculescu; Y. Okayasu; L. Pentchev; C. Perdrisat; D. Pitz; D. Potterveld; V. Punjabi; L. M. Qin; P. E. Reimer; J. Reinhold; J. Roche; P. G. Roos; A. Sarty; I. K. Shin; G. R. Smith; S. Stepanyan; L. G. Tang; V. Tadevosyan; V. Tvaskis; R. L. J. van der Meer; K. Vansyoc; D. Van Westrum; S. Vidakovic; J. Volmer; W. Vulcan; G. Warren; S. A. Wood; C. Xu; C. Yan; W. -X. Zhao; X. Zheng; B. Zihlmann

    2014-04-15T23:59:59.000Z

    The study of exclusive $\\pi^{\\pm}$ electroproduction on the nucleon, including separation of the various structure functions, is of interest for a number of reasons. The ratio $R_L=\\sigma_L^{\\pi^-}/\\sigma_L^{\\pi^+}$ is sensitive to isoscalar contamination to the dominant isovector pion exchange amplitude, which is the basis for the determination of the charged pion form factor from electroproduction data. A change in the value of $R_T=\\sigma_T^{\\pi^-}/\\sigma_T^{\\pi^+}$ from unity at small $-t$, to 1/4 at large $-t$, would suggest a transition from coupling to a (virtual) pion to coupling to individual quarks. Furthermore, the mentioned ratios may show an earlier approach to pQCD than the individual cross sections. We have performed the first complete separation of the four unpolarized electromagnetic structure functions above the dominant resonances in forward, exclusive $\\pi^{\\pm}$ electroproduction on the deuteron at central $Q^2$ values of 0.6, 1.0, 1.6 GeV$^2$ at $W$=1.95 GeV, and $Q^2=2.45$ GeV$^2$ at $W$=2.22 GeV. Here, we present the $L$ and $T$ cross sections, with emphasis on $R_L$ and $R_T$, and compare them with theoretical calculations. Results for the separated ratio $R_L$ indicate dominance of the pion-pole diagram at low $-t$, while results for $R_T$ are consistent with a transition between pion knockout and quark knockout mechanisms.

  1. Separation of CO2 from flue gas using electrochemical cells

    SciTech Connect (OSTI)

    Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

    2010-06-01T23:59:59.000Z

    ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

  2. Auto shredder residue recycling: Mechanical separation and pyrolysis

    SciTech Connect (OSTI)

    Santini, Alessandro [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Passarini, Fabrizio, E-mail: fabrizio.passarini@unibo.it [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Vassura, Ivano [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Serrano, David; Dufour, Javier [Department of Chemical and Energy Technology, ESCET, Universidad Rey Juan Carlos, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Instituto IMDEA Energy, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Morselli, Luciano [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy)

    2012-05-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

  3. Gas separation by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

    1989-04-25T23:59:59.000Z

    There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

  4. Gas separation by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

    1989-01-01T23:59:59.000Z

    There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

  5. Soil separator and sampler and method of sampling

    DOE Patents [OSTI]

    O'Brien, Barry H. (Idaho Falls, ID) [Idaho Falls, ID; Ritter, Paul D. (Idaho Falls, ID) [Idaho Falls, ID

    2010-02-16T23:59:59.000Z

    A soil sampler includes a fluidized bed for receiving a soil sample. The fluidized bed may be in communication with a vacuum for drawing air through the fluidized bed and suspending particulate matter of the soil sample in the air. In a method of sampling, the air may be drawn across a filter, separating the particulate matter. Optionally, a baffle or a cyclone may be included within the fluidized bed for disentrainment, or dedusting, so only the finest particulate matter, including asbestos, will be trapped on the filter. The filter may be removable, and may be tested to determine the content of asbestos and other hazardous particulate matter in the soil sample.

  6. Nitrogen Trifluoride-Based Fluoride- Volatility Separations Process: Initial Studies

    SciTech Connect (OSTI)

    McNamara, Bruce K.; Scheele, Randall D.; Casella, Andrew M.; Kozelisky, Anne E.

    2011-09-28T23:59:59.000Z

    This document describes the results of our investigations on the potential use of nitrogen trifluoride as the fluorinating and oxidizing agent in fluoride volatility-based used nuclear fuel reprocessing. The conceptual process uses differences in reaction temperatures between nitrogen trifluoride and fuel constituents that produce volatile fluorides to achieve separations and recover valuable constituents. We provide results from our thermodynamic evaluations, thermo-analytical experiments, kinetic models, and provide a preliminary process flowsheet. The evaluations found that nitrogen trifluoride can effectively produce volatile fluorides at different temperatures dependent on the fuel constituent.

  7. Separation of the unsaponifiable matter from cottonseed oil by adsorption

    E-Print Network [OSTI]

    Zeitoun, Mohamed Ali

    2012-06-07T23:59:59.000Z

    oxide. All the results they obtained were in accordance with the theory that the number of double bonds was responsible for the degree of adsorption. They concluded tnat with aluminium oxide their method of separation was only applicable to sterols..., in a ratio 5 crude oil to I silica gel by weight, resulted in the removal of moxe than 50 pex cent of the unsaponifiable matter. Hot 90/ isopropanol was found to be the best of a number of solvents tested for desorbing the material. The solvent...

  8. Integrated reactor and centrifugal separator and uses thereof

    DOE Patents [OSTI]

    Birdwell, Jr., Joseph F (Knoxville, TN); Jennings, Harold L. (Clinton, TN); McFarlane, Joanna (Oak Ridge, TN); Tsouris, Constantino (Oak Ridge, TN)

    2012-01-17T23:59:59.000Z

    An apparatus for providing reaction of fluids and separation of products with increased residence time. The apparatus includes a stationary shell, a rotating hollow cylindrical component disposed in the stationary shell, a residence-time increasing device external to the stationary shell, a standpipe for introducing fluid into an interior cavity of the hollow cylindrical component from the residence-time increasing device, a first outlet in fluid flow communication with the interior cavity of the hollow cylindrical component for a less dense phase fluid, and a second outlet in fluid flow communication with the interior cavity of the hollow cylindrical component for a more dense phase fluid.

  9. Registered and antiregistered phase separation of mixed amphiphilic bilayers

    E-Print Network [OSTI]

    John J. Williamson; Peter D. Olmsted

    2014-08-12T23:59:59.000Z

    We derive a mean-field free energy for phase separation in coupled bilayer leaflets. Our model accounts for amphiphile-level structure, in particular hydrophobic mismatch, which promotes $\\textit{antiregistration}$ (AR), in competition with the `direct' trans-midplane coupling usually studied, promoting registration (R). For phospholipid parameters equilibrium demixing is typically R, but hydrophobic mismatch favours metastable AR phases, which can cause a bilayer in the `spinodal region' to require nucleation in order to equilibrate. This provides a framework for understanding existing observations, elucidating a subtle, often overlooked competition of couplings, and a key role for phase transition kinetics in determining domain registration/antiregistration.

  10. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, F.K.

    1986-07-29T23:59:59.000Z

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process. 4 figs.

  11. Separating and combining single-mode and multimode optical beams

    DOE Patents [OSTI]

    Ruggiero, Anthony J; Masquelier, Donald A; Cooke, Jeffery B; Kallman, Jeffery S

    2013-11-12T23:59:59.000Z

    Techniques for combining initially separate single mode and multimode optical beams into a single "Dual Mode" fiber optic have been developed. Bi-directional propagation of two beams that are differentiated only by their mode profiles (i.e., wavefront conditions) is provided. The beams can be different wavelengths and or contain different modulation information but still share a common aperture. This method allows the use of conventional micro optics and hybrid photonic packaging techniques to produce small rugged packages suitable for use in industrial or military environments.

  12. A Maxwell Construction for Phase Separation in Vibrated Granular Matter?

    E-Print Network [OSTI]

    James P. D. Clewett; Jack Wade; R. M. Bowley; Stephan Herminghaus; Michael R. Swift; Marco G. Mazza

    2015-02-28T23:59:59.000Z

    Experiments and computer simulations are carried out to investigate ordering principles in a granular gas which phase separates under vibration. The densities of the dilute and the dense phase are found to follow a lever rule. A Maxwell construction is found to predict both the coexisting pressure and binodal densities remarkably well, despite the fact that the pressure-volume characteristic $P(v)$ is not an isotherm. Although the system is far from equilibrium and energy conservation is strongly violated, we derive the construction from the minimization of mechanical work and fluctuating particle currents.

  13. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, R.J.; Kurek, P.R.

    1988-07-19T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  14. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, Frank K. (Upper Macungie, PA)

    1986-01-01T23:59:59.000Z

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

  15. Quantum and classical separability of spin-orbit laser modes

    E-Print Network [OSTI]

    L. J. Pereira; A. Z. Khoury; K. Dechoum

    2014-09-02T23:59:59.000Z

    In this work we investigate the quantum noise properties of polarization vortices in connection with an intensity based Clauser-Horne-Shimony-Holt inequality for their spin-orbit separability. We evaluate the inequality for different input quantum states and the corresponding intensity fluctuations. The roles played by coherence and photon number squeezing provide a suitable framework for characterizing pure state spin-orbit entanglement. Structural inseparability of the spin-orbit mode requires coherence, an issue concerning either classical or quantum descriptions. In both cases, it can be witnessed by violation of this intensity based CHSH inequality. However, in the quantum domain, entanglement requires both coherence and reduced photon number fluctuations.

  16. Norman Ramsey and the Separated Oscillatory Fields Method

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohnSecurity ComplexNorman Ramsey and the Separated

  17. Texas Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear JanSeparation, Proved1 4.70 1967-2010 Imports 4.08

  18. Texas Nonassociated Natural Gas, Wet After Lease Separation, Proved

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear JanSeparation, Proved1 4.70 1967-2010 Imports 4.08Reserves

  19. Texas State Offshore Natural Gas, Wet After Lease Separation Proved

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear JanSeparation, Proved1 4.70 1967-2010Cubic Feet) Dry

  20. Texas State Offshore Nonassociated Natural Gas, Wet After Lease Separation,

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear JanSeparation, Proved1 4.70 1967-2010Cubic Feet) DryProved

  1. Louisiana Natural Gas, Wet After Lease Separation Proved Reserves (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing Reservoirs Year in Review1,213Separation,Year Jan FebWellheadCubic

  2. Nanopatterns by phase separation of patterned mixed polymer monolayers

    DOE Patents [OSTI]

    Huber, Dale L; Frischknecht, Amalie

    2014-02-18T23:59:59.000Z

    Micron-size and sub-micron-size patterns on a substrate can direct the self-assembly of surface-bonded mixed polymer brushes to create nanoscale patterns in the phase-separated mixed polymer brush. The larger scale features, or patterns, can be defined by a variety of lithographic techniques, as well as other physical and chemical processes including but not limited to etching, grinding, and polishing. The polymer brushes preferably comprise vinyl polymers, such as polystyrene and poly(methyl methacrylate).

  3. Separable Representation of Proton-Nucleus Optical Potentials

    E-Print Network [OSTI]

    L. Hlophe; V. Eremenko; Ch. Elster; F. M. Nunes; G. Arbanas; J. E. Escher; I. J. Thompson

    2014-09-14T23:59:59.000Z

    Recently, a new approach for solving the three-body problem for (d,p) reactions in the Coulomb-distorted basis in momentum space was proposed. Important input quantities for such calculations are the scattering matrix elements for proton- and neutron-nucleus scattering. We present a generalization of the Ernst-Shakin-Thaler scheme in which a momentum space separable representation of proton-nucleus scattering matrix elements can be calculated in the Coulomb basis. The viability of this method is demonstrated by comparing S-matrix elements obtained for p$+^{48}$Ca and p$+^{208}$Pb for a phenomenological optical potential with corresponding coordinate space calculations.

  4. Utah Nonassociated Natural Gas Proved Reserves, Wet After Lease Separation

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand28 198Separation 321Working Gas)

  5. Hydrocarbon Separations in Metal-Organic Frameworks | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region service area.Portal SolarAboutSeparationsRelevant to Clean Energy

  6. Entropy-based separation of linear chain molecules by exploiting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region service area. TheEPSCI Home It isGas SeparationsRelevant todifferences

  7. Nonassociated Natural Gas Reserves Sales, Wet After Lease Separation

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet) Year Jan FebFeet)SalesYear Jan FebSeparation 8,998

  8. Industrial Membrane Filtration and Short-bed Fractal Separation Systems for Separating Monomers from Heterogeneous Plant Material

    SciTech Connect (OSTI)

    Kearney, M; Kochergin, V; Hess, R; Foust, T; Herbst, R; Mann, N

    2005-03-31T23:59:59.000Z

    Large-scale displacement of petroleum will come from low-cost cellulosic feedstocks such as straw and corn stover crop residues. This project has taken a step toward making this projection a reality by reducing capital and energy costs, the two largest cost factors associated with converting cellulosic biomass to chemicals and fuels. The technology exists for using acid or enzyme hydrolysis processes to convert biomass feedstock (i.e., waste cellulose such as straw, corn stover, and wood) into their base monomeric sugar building blocks, which can, in turn, be processed into chemicals and fuels using a number of innovative fermentation technologies. However, while these processes are technically possible, practical and economic barriers make these processes only marginally feasible or not feasible at all. These barriers are due in part to the complexity and large fixed and recurring capital costs of unit operations including filtration, chromatographic separation, and ion exchange. This project was designed to help remove these barriers by developing and implementing new purification and separation technologies that will reduce the capital costs of the purification and chromatographic separation units by 50% to 70%. The technologies fundamental to these improvements are: (a) highly efficient clarification and purification systems that use screening and membrane filtration to eliminate suspended solids and colloidal material from feed streams and (b) fractal technology based chromatographic separation and ion exchange systems that can substitute for conventional systems but at much smaller size and cost. A non-hazardous ''raw sugar beet juice'' stream (75 to 100 gal/min) was used for prototype testing of these technologies. This raw beet juice stream from the Amalgamated Sugar LLC plant in Twin Falls, Idaho contained abrasive materials and membrane foulants. Its characteristics were representative of an industrial-scale heterogeneous plant extract/hydrolysis stream, and therefore was an ideal model system for developing new separation equipment. Subsequent testing used both synthetic acid hydrolysate and corn stover derived weak acid hydrolysate (NREL produced). A two-phased approach was used for the research and development described in this project. The first level of study involved testing the new concepts at the bench level. The bench-scale evaluations provided fundamental understanding of the processes, building and testing small prototype systems, and determining the efficiency of the novel processes. The second level of study, macro-level, required building larger systems that directly simulated industrial operations and provided validation of performance to minimize financial risk during commercialization. The project goals and scope included: (1) Development of low-capital alternatives to conventional crop-based purification/separation processes; and (2) Development of each process to the point that transition to commercial operation is low risk. The project reporting period was January 2001 to December 2004. This included a one year extension of the project (without additional funding).

  9. PMBP extraction and TPE separation in alkaline pyrophosphate solutions

    SciTech Connect (OSTI)

    Karalova, Z.K.; Bukina, T.I.; Lavrinovich, E.A.; Trofimov, T.I.; Kulyako, Yu.M.; Myasoedov, B.F.

    1988-11-01T23:59:59.000Z

    Measurements have been made on the solvent extraction of Am(III), Am(V), Cm(III), and Eu(III) in trace and macroscopic amounts from (NH/sub 4/)/sub 4/P/sub 2/O/sub 7/ (pH = 7.6) and Na/sub 4/P/sub 2/O/sub 7/ (pH = 10) solutions as coordination compounds with 1-phenyl-3-methyl-4-benzoylpyrazol-5-one (PMBP). A method has been devised for separating weighable amounts of americium and curium, which is based in trivalent curium being extracted quantitatively from 0.1 M sodium pyrophosphate (pH 10) by 0.1 M PMBP solution in chloroform, where high distribution coefficients apply, while americium is electrochemically oxidized in that medium to Am(VI) and on contact with the extraction agent is reduced to Am(V) and remains in the aqueous phase. The separation factor for the Cm(III)-Am(V) pair is about 10/sup 3/.

  10. RAPID SEPARATION METHOD FOR ACTINIDES IN EMERGENCY SOIL SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.; Culligan, B.; Noyes, G.

    2009-11-09T23:59:59.000Z

    A new rapid method for the determination of actinides in soil and sediment samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used for samples up to 2 grams in emergency response situations. The actinides in soil method utilizes a rapid sodium hydroxide fusion method, a lanthanum fluoride soil matrix removal step, and a streamlined column separation process with stacked TEVA, TRU and DGA Resin cartridges. Lanthanum was separated rapidly and effectively from Am and Cm on DGA Resin. Vacuum box technology and rapid flow rates are used to reduce analytical time. Alpha sources are prepared using cerium fluoride microprecipitation for counting by alpha spectrometry. The method showed high chemical recoveries and effective removal of interferences. This new procedure was applied to emergency soil samples received in the NRIP Emergency Response exercise administered by the National Institute for Standards and Technology (NIST) in April, 2009. The actinides in soil results were reported within 4-5 hours with excellent quality.

  11. RAPID SEPARATION OF ACTINIDES AND RADIOSTRONTIUM IN VEGETATION SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.

    2010-06-01T23:59:59.000Z

    A new rapid method for the determination of actinides and radiostrontium in vegetation samples has been developed at the Savannah River Site Environmental Lab (Aiken, SC, USA) that can be used in emergency response situations or for routine analysis. The actinides in vegetation method utilizes a rapid sodium hydroxide fusion method, a lanthanum fluoride matrix removal step, and a streamlined column separation process with stacked TEVA, TRU and DGA Resin cartridges. Lanthanum was separated rapidly and effectively from Am and Cm on DGA Resin. Alpha emitters are prepared using rare earth microprecipitation for counting by alpha spectrometry. The purified {sup 90}Sr fractions are mounted directly on planchets and counted by gas flow proportional counting. The method showed high chemical recoveries and effective removal of interferences. The actinide and {sup 90}Sr in vegetation sample analysis can be performed in less than 8 h with excellent quality for emergency samples. The rapid fusion technique is a rugged sample digestion method that ensures that any refractory actinide particles or vegetation residue after furnace heating is effectively digested.

  12. Method of separation of yttrium-90 from strontium-90

    DOE Patents [OSTI]

    Bray, L.A.; Wester, D.W.

    1996-04-30T23:59:59.000Z

    A method is described for purifying Y-90 from a Sr-90/Y-90 ``cow`` wherein raw Sr-90/Y-90 source containing impurities is obtained from nuclear material reprocessing. Raw Sr-90/Y-90 source is purified to a fresh Sr-90/Y-90 source ``cow`` by removing impurities by addition of sodium hydroxide and by removing Cs-137 by further addition of sodium carbonate. The ``cow`` is set aside to allow ingrowth. An HDEHP organic extractant is obtained from a commercial supplier and further purified by saturation with Cu(II), precipitation with acetone, and washing with nitric acid. The ``cow`` is then dissolved in nitric acid and the purified HDEHP is washed with nitric acid and scrubbed with either nitric or hydrochloric acid. The dissolved ``cow`` and scrubbed HDEHP are combined in an organic extraction, separating Y-90 from Sr-90, resulting in a Sr-90/Y-90 concentration ratio of not more than 10(E-7), and a metal impurity concentration of not more than 10 ppm per curie of Y-90. The separated Y-90 may then be prepared for delivery. 1 fig.

  13. Method of separation of yttrium-90 from strontium-90

    DOE Patents [OSTI]

    Bray, Lane A. (Richland, WA); Wester, Dennis W. (Richland, WA)

    1996-01-01T23:59:59.000Z

    A method for purifying Y-90 from a Sr-90/Y-90 "cow" wherein raw Sr-90/Y-90 source containing impurities is obtained from nuclear material reprocessing. Raw Sr-90/Y-90 source is purified to a fresh Sr-90/Y-90 source "cow" by removing impurities by addition of sodium hydroxide and by removing Cs-137 by further addition of sodium carbonate. The "cow" is set aside to allow ingrowth. An HDEHP organic extractant is obtained from a commercial supplier and further purified by saturation with Cu(II), precipitation with acetone, and washing with nitric acid. The "cow" is then dissolved in nitric acid and the purified HDEHP is washed with nitric acid and scrubbed with either nitric or hydrochloric acid. The dissolved "cow" and scrubbed HDEHP are combined in an organic extraction, separating Y-90 from Sr-90, resulting in a Sr-90/Y-90 concentration ratio of not more than 10(E-7), and a metal impurity concentration of not more than 10 ppm per curie of Y-90. The separated Y-90 may then be prepared for delivery.

  14. Iodine-129 separation and determination by neutron activation analysis

    SciTech Connect (OSTI)

    Bate, L.C.; Stokely, J.R.

    1981-01-01T23:59:59.000Z

    A method is described for analysis of /sup 129/I in fission product mixtures originating from fuel reprocessing studies and low-level wastes. The method utilizes conventional iodine valence adjustment and solvent extraction techniques to chemically separate /sup 129/I from most fission products. The /sup 129/I is determined by neutron irradiation and measurement of the 12.4 h /sup 130/I produced by the neutron capture reaction. Special techniques were devised for neutron irradiation of /sup 129/I samples in the pneumatic tube irradiation facilities at the High Flux Isotope (HFIR) and Oak Ridge Research (ORR) Reactors. Chemically separated /sup 129/I is adsorbed on an anion exchange resin column made from an irradiation container. The loaded resin is then irradiated in either of the pneumatic facilities to produce /sup 130/I. Sensitivity of the analysis with the HFIR facility (flux: 5 x 10/sup 14/ n/cm/sup 2//sec) and a 100-second irradiation time is approximately 0.03 nanograms. Samples up to 250 ml in volume can be easily processed.

  15. Technetium and Iodine Separations in the UREX Process.

    SciTech Connect (OSTI)

    Schroeder, N. C. (Norman C.); Attrep, Moses; Marrero, T. (Thomas)

    2001-01-01T23:59:59.000Z

    The Accelerator Transmutation of Waste (ATW) program is being developed to determine the feasibility of separatin and transmutating the transactinides (Pu-Cm) and long-lived fission product (99Tc and 'I) from spent light water reactor (LWR) fuel. This approach would help with the disposal of spent commercial fuel. In addition, since the residual waste after ATW treatment will have much lower levels of long-lived species, this process may improve the performance and acceptability of long-term geologic disposal of nuclear waste. A roadmap for the Accelerator Transmutation of Waste (ATW) was submitted to Congress in 1999.' This document gave an overall view of the ATW concept and program. A subsequent document prepared by the Technical Working Group for ATW Separations Technologies and Waste Forms issued a second roadmap that dealt more specifically with the radionuclide separations and waste disposal needs for the ATW program.' This latter document discusses the UREX (Uranium Extraction) process. The latest iteration of the UREX flowsheet is shown in Figure le3T his flowsheet anticipates the co-extraction of technetium with uranium from dissolved LWR fuel by tributylphosphate (TBP) and their subsequent sequential bwk-extraction from the TBP stream.

  16. Safety analysis, 200 Area, Savannah River Plant: Separations area operations

    SciTech Connect (OSTI)

    Perkins, W.C.; Lee, R.; Allen, P.M.; Gouge, A.P.

    1991-07-01T23:59:59.000Z

    The nev HB-Line, located on the fifth and sixth levels of Building 221-H, is designed to replace the aging existing HB-Line production facility. The nev HB-Line consists of three separate facilities: the Scrap Recovery Facility, the Neptunium Oxide Facility, and the Plutonium Oxide Facility. There are three separate safety analyses for the nev HB-Line, one for each of the three facilities. These are issued as supplements to the 200-Area Safety Analysis (DPSTSA-200-10). These supplements are numbered as Sup 2A, Scrap Recovery Facility, Sup 2B, Neptunium Oxide Facility, Sup 2C, Plutonium Oxide Facility. The subject of this safety analysis, the, Plutonium Oxide Facility, will convert nitrate solutions of {sup 238}Pu to plutonium oxide (PuO{sub 2}) powder. All these new facilities incorporate improvements in: (1) engineered barriers to contain contamination, (2) barriers to minimize personnel exposure to airborne contamination, (3) shielding and remote operations to decrease radiation exposure, and (4) equipment and ventilation design to provide flexibility and improved process performance.

  17. Phase Separation in Giant Planets: Inhomogeneous Evolution of Saturn

    E-Print Network [OSTI]

    Jonathan J. Fortney; William B. Hubbard

    2003-05-01T23:59:59.000Z

    We present the first models of Jupiter and Saturn to couple their evolution to both a radiative-atmosphere grid and to high-pressure phase diagrams of hydrogen with helium and other admixtures. We find that prior calculated phase diagrams in which Saturn's interior reaches a region of predicted helium immiscibility do not allow enough energy release to prolong Saturn's cooling to its known age and effective temperature. We explore modifications to published phase diagrams that would lead to greater energy release, and propose a modified H-He phase diagram that is physically reasonable, leads to the correct extension of Saturn's cooling, and predicts an atmospheric helium mass fraction Y_atmos = 0.185, in agreement with recent estimates. We also explore the possibility of internal separation of elements heavier than helium, and find that, alternatively, such separation could prolong Saturn's cooling to its known age and effective temperature under a realistic phase diagram and heavy element abundance (in which case Saturn's Y_atmos would be solar but heavier elements would be depleted). In none of these scenarios does Jupiter's interior evolve to any region of helium or heavy-element immiscibility: Jupiter evolves homogeneously to the present day. We discuss the implications of our calculations for Saturn's primordial core mass.

  18. Hydrogen separation membranes annual report for FY 2006.

    SciTech Connect (OSTI)

    Balachandran, U.; Chen, L.; Ciocco, M.; Doctor, R. D.; Dorris, S.E.; Emerson, J. E.; Fisher, B.; Lee, T. H.; Killmeyer, R. P.; Morreale,B.; Picciolo, J. J.; Siriwardane, R. V.; Song, S. J.

    2007-02-05T23:59:59.000Z

    The objective of this work is to develop dense ceramic membranes for separating hydrogen from other gaseous components in a nongalvanic mode, i.e., without using an external power supply or electrical circuitry. This goal of this project is to develop two types of dense ceramic membrane for producing hydrogen nongalvanically, i.e., without electrodes or external power supply, at commercially significant fluxes under industrially relevant operating conditions. The first type of membrane, hydrogen transport membranes (HTMs), will be used to separate hydrogen from gas mixtures such as the product streams from coal gasification, methane partial oxidation, and water-gas shift reactions. Potential ancillary uses of HTMs include dehydrogenation and olefin production, as well as hydrogen recovery in petroleum refineries and ammonia synthesis plants, the largest current users of deliberately produced hydrogen. The second type of membrane, oxygen transport membranes (OTMs), will produce hydrogen by nongalvanically removing oxygen that is generated when water dissociates at elevated temperatures. This report describes progress that was made during FY 2006 on the development of OTM and HTM materials.

  19. Realization of Optimal Disentanglement by Teleportation via Separable Channel

    E-Print Network [OSTI]

    Sibasish Ghosh; Guruprasad Kar; Anirban Roy; Debasis Sarkar; Ujjwal Sen

    2001-02-02T23:59:59.000Z

    We discuss here the best disentanglement processes of states of two two-level systems which belong to (i) the universal set, (ii) the set in which the states of one party lie on a single great circle of the Bloch sphere, and (iii) the set in which the states of one party commute with each other, by teleporting the states of one party (on which the disentangling machine is acting) through three particular type of separable channels, each of which is a mixture of Bell states. In the general scenario, by teleporting one party's state of an arbitrary entangled state of two two-level parties through some mixture of Bell states, we have shown that this entangled state can be made separable by using a physically realizable map $\\tilde{V}$, acting on one party's states, if $\\tilde{V} (I) = I, \\tilde{V} ({\\sigma}_j) = {\\lambda}_j {\\sigma}_j$, where ${\\lambda}_j \\ge 0$ (for $j = 1, 2, 3$), and ${\\lambda}_1 + {\\lambda}_2 + {\\lambda}_3 \\le 1$.

  20. Radiolysis and hydrolysis of magnetically assisted chemical separation particles

    SciTech Connect (OSTI)

    Buchholz, B.A.; Nunez, L.; Vandegrift, G.F.

    1995-05-01T23:59:59.000Z

    The magnetically assisted chemical separation (MACS) process is designed to separate transuranic (TRU) elements out of high-level waste (HLW) or TRU waste. Magnetic microparticles (1--25 {mu}m) were coated with octyl (phenyl)N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) dissolved in tributyl phosphate (TBP) and tested for removing TRU elements from acidic nitrate solutions. The particles were contacted with nitric acid solutions and Hanford plutonium finishing plant (PFP) simulant, irradiated with a high intensity {sup 60}Co {gamma}-ray source, and evaluated for effectiveness in removing TRU elements from 2m HNO{sub 3} solutions. The resistance of the coatings and magnetic cores to radiolytic damage and hydrolytic degradation was investigated by irradiating samples of particles suspended in a variety of solutions with doses of up to 5 Mrad. Transmission electron microscopy (TEM), magnetic susceptibility measurements, and physical observations of the particles and suspension solutions were used to assess physical changes to the particles. Processes that affect the surface of the particles dramatically alter the binding sites for TRU in solution. Hydrolysis played a larger role than radiolysis in the degradation of the extraction capacity of the particles.

  1. The Separation of Tritiated Water Using Supported Polyphosphazene Membranes

    SciTech Connect (OSTI)

    Duncan, James B. (CHEMMET LTD); Nelson, David A. (BATTELLE (PACIFIC NW LAB))

    1998-12-01T23:59:59.000Z

    Carboxylated poly(diaryloxy)phosphazene was examined as the active constituent of the composite membranes to separate tritiated water (HTO) from light water. These membranes were tested with water containing 10 800 pCi/l and 3 mu-Ci/l of tritiated water, respectively, under cross-flow filtration conditions. Reductions in the permeate of nearly 30% HTO were observed with these tritium concentrations. Low temperature (5 degrees C), low pressure (137.9-551.6 kPa), and high pH (near 10 or above) were required to obtain such reductions (rejection). Salt species (Na2SO4, CaCl2 and CaSO4) at various concentrations and pressures, within a 137.9-551.6 kPa range, did not appear to affect the HTO separation efficiency. Mass balances performed during these experiments indicate an unaccounted small amount of tritium (0.5-2.2%). Sorption experiments with the polyphosphazene suggest that the membrane does not operate by an ion exchange mechanism; that is, tritium accumulation within the membrane.

  2. Conjugates of Actinide Chelator-Magnetic Nanoparticles for Used Fuel Separation Technology

    SciTech Connect (OSTI)

    You Qiang; Andrzej Paszczynski; Linfeng Rao

    2011-10-30T23:59:59.000Z

    The actinide separation method using magnetic nanoparticles (MNPs) functionalized with actinide specific chelators utilizes the separation capability of ligand and the ease of magnetic separation. This separation method eliminated the need of large quantity organic solutions used in the liquid-liquid extraction process. The MNPs could also be recycled for repeated separation, thus this separation method greatly reduces the generation of secondary waste compared to traditional liquid extraction technology. The high diffusivity of MNPs and the large surface area also facilitate high efficiency of actinide sorption by the ligands. This method could help in solving the nuclear waste remediation problem.

  3. Improved high efficiency third stage separator cyclones for separation of fines from fluid catalytic cracking flue gas

    SciTech Connect (OSTI)

    Chitnis, G.K.; Schatz, K.W. [Mobil Technology Co., Paulsboro, NJ (United States); Bussey, B.K. [M.W. Kellogg Co., Houston, TX (United States)

    1996-12-31T23:59:59.000Z

    Stairmand type small diameter (0.254 m) multicyclones were cold flow tested for fluid catalytic cracking third stage separator application. The gas discharge from the cyclone dust outlet into the common collection hopper was found to far exceed the hopper bleed rate (underflow). The excess gas reentrained dust from the hopper back into cyclones, which lowered collection efficiencies. Vortex {open_quotes}stabilization{close_quotes} using apex cones was unsuccessful whereas a Mobil proprietary cyclone modification was successful in minimizing excess gas discharge and dust reentrainment at the cyclone-hopper boundary. In tests at 700 {degrees}C, the modified cyclones captured all particles above 4 {mu}m. Mobil-Kellogg incorporated the modified cyclones in a new third stage separator design which is targeted for achieving lowest opacity and <50 mg/Nm{sup 3} emissions at the stack. The first such unit will be commercialized in Mobil`s newest catalytic cracker (M.W. Kellogg design) under construction in Altona, Australia in late 1996. 5 refs., 4 figs., 2 tabs.

  4. Electrochemical Membrane for Carbon Dioxide Separation and Power Generation

    SciTech Connect (OSTI)

    Jolly, Stephen; Ghezel-Ayagh, Hossein; Hunt, Jennifer; Patel, Dilip; Steen, William A.; Richardson, Carl F.; Marina, Olga A.

    2012-12-28T23:59:59.000Z

    uelCell Energy, Inc. (FCE) has developed a novel system concept for separation of carbon dioxide (CO2) from greenhouse gas (GHG) emission sources using an electrochemical membrane (ECM). The salient feature of the ECM is its capability to produce electric power while capturing CO2 from flue gas, such as from an existing pulverized coal (PC) plant. Laboratory scale testing of the ECM has verified the feasibility of the technology for CO2 separation from simulated flue gases of PC plants as well as combined cycle power plants and other industrial facilities. Recently, FCE was awarded a contract (DE-FE0007634) from the U.S. Department of Energy to evaluate the use of ECM to efficiently and cost effectively separate CO2 from the emissions of existing coal fired power plants. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from flue gas of an existing PC plant with no more than 35% increase in the cost of electricity (COE) produced by the plant. The specific objectives and related activities planned for the project include: 1) conduct bench scale tests of a planar membrane assembly consisting of ten or more cells of about 0.8 m2 area each, 2) develop the detailed design for an ECM-based CO2 capture system applied to an existing PC plant, and 3) evaluate the effects of impurities (pollutants such as SO2, NOx, Hg) present in the coal plant flue gas by conducting laboratory scale performance tests of the membrane. The results of this project are anticipated to demonstrate that the ECM is an advanced technology, fabricated from inexpensive materials, based on proven operational track records, modular, scalable to large sizes, and a viable candidate for >90% carbon capture from existing PC plants. In this paper, the fundamentals of ECM technology including: material of construction, principal mechanisms of operation, carbon capture test results and the benefits of applications to PC plants will be presented.

  5. Separating Oil-Water Nanoemulsions using Flux-Enhanced Hierarchical Membranes

    E-Print Network [OSTI]

    Solomon, Brian Richmond

    Membranes that separate oil-water mixtures based on contrasting wetting properties have recently received significant attention. Separation of nanoemulsions, i.e. oil-water mixtures containing sub-micron droplets, still ...

  6. Sound Source Separation G. Evangelista, S. Marchand, M. D. Plumbley, E. Vincent

    E-Print Network [OSTI]

    Plumbley, Mark

    Chapter 1 Sound Source Separation G. Evangelista, S. Marchand, M. D. Plumbley, E. Vincent 1 preprint of: G. Evangelista, S. Marchand, M. D. Plumbley and E. Vincent. Sound source separation. In U

  7. Poly(vinyl alcohol)-based buffering membranes for isoelectric trapping separations

    E-Print Network [OSTI]

    Craver, Helen C.

    2009-05-15T23:59:59.000Z

    Isoelectric trapping (IET) in multicompartment electrolyzers (MCE) has been widely used for the electrophoretic separation of ampholytic compounds such as proteins. In IET, the separation occurs in the buffering membranes that form a step-wise p...

  8. An experimental study of unsteady separation in a two-dimensional flow

    E-Print Network [OSTI]

    Coral Pinto, Raul Javier

    2005-01-01T23:59:59.000Z

    An experimental study of flow separation in an incompressible two-dimensional unsteady flow was undertaken with the aim of validating recently developed flow separation criteria, which are based on kinematic principles. ...

  9. The tangential velocity profile and momentum transfer within a microgravity, vortex separator

    E-Print Network [OSTI]

    Ellis, Michael Clay

    2009-05-15T23:59:59.000Z

    Liquid and gas do not separate naturally in microgravity, presenting a problem for twophase space systems. Increased integration of multiphase systems requires a separation method adaptable to a variety of systems. Researchers at Texas A...

  10. Research and development separation technology: The DOE Industrial Energy Conservation Program

    SciTech Connect (OSTI)

    Not Available

    1987-07-01T23:59:59.000Z

    This brochure summarizes the Office of Industrial Programs' RandD efforts in the advancement of separation technology. The purpose of this brochure is to provide interested parties with information on federal industrial energy conservation activities in separation technology. The brochure is comprised of the following sections: Separation Technology, summarizes the current state of separation technology and its uses. Potential Energy Savings, discusses the potential for industrial energy conservation through the implementation of advanced separation processes. Office of Industrial Programs' RandD Efforts in Separation Technology Development, describes the separation RandD projects conducted by IP. RandD Data Base, lists contractor, principal investigator, and location of each separation-related RandD effort sponsored by IP.

  11. March 22, 2004 EAS 4/8803 1 Separating PM2.5 at Sample Inlet

    E-Print Network [OSTI]

    Weber, Rodney

    March 22, 2004 EAS 4/8803 1 Separating PM2.5 at Sample Inlet Classical Cyclone Sharp Cut Cyclone medium is extracted separately for direct quantification of: NH3, HONO, HNO3, SO2, Formic, Acetic, Oxalic

  12. E-Print Network 3.0 - actinides separation chemistry Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    separation chemistry Search Powered by Explorit Topic List Advanced Search Sample search results for: actinides separation chemistry Page: << < 1 2 3 4 5 > >> 1 www.emsl.pnl.gov...

  13. Development of an Automatic Method for Americium and Plutonium Separation and

    E-Print Network [OSTI]

    Sánchez, David

    Development of an Automatic Method for Americium and Plutonium Separation and Preconcentration and separation in a short time using large sample volumes. Americium is eluted from the column with 4 mol L-1

  14. Boundary element simulation of oscillating foil with leading-edge separation

    E-Print Network [OSTI]

    Dong, Xiaoxia, S.M. Massachusetts Institute of Technology

    2007-01-01T23:59:59.000Z

    In this thesis, we develop a numerical model to account for the leading-edge separation for the boundary element simulation of the oscillating foil with potential flow assumption. Similar to the trailing-edge separation, ...

  15. Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and David H. Olson,

    E-Print Network [OSTI]

    Li, Jing

    Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Kunhao Li, David H the first examples of MMOFs that are capable of kinetic separation of propane and propene (propylene), which

  16. Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films Studied Using Atom Probe Tomography: Comparison Of Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films...

  17. Analyte separation utilizing temperature programmed desorption of a preconcentrator mesh

    DOE Patents [OSTI]

    Linker, Kevin L. (Albuquerque, NM); Bouchier, Frank A. (Albuquerque, NM); Theisen, Lisa (Albuquerque, NM); Arakaki, Lester H. (Edgewood, NM)

    2007-11-27T23:59:59.000Z

    A method and system for controllably releasing contaminants from a contaminated porous metallic mesh by thermally desorbing and releasing a selected subset of contaminants from a contaminated mesh by rapidly raising the mesh to a pre-determined temperature step or plateau that has been chosen beforehand to preferentially desorb a particular chemical specie of interest, but not others. By providing a sufficiently long delay or dwell period in-between heating pulses, and by selecting the optimum plateau temperatures, then different contaminant species can be controllably released in well-defined batches at different times to a chemical detector in gaseous communication with the mesh. For some detectors, such as an Ion Mobility Spectrometer (IMS), separating different species in time before they enter the IMS allows the detector to have an enhanced selectivity.

  18. Multilevel cascade voltage source inverter with separate DC sources

    DOE Patents [OSTI]

    Peng, F.Z.; Lai, J.S.

    1997-06-24T23:59:59.000Z

    A multilevel cascade voltage source inverter having separate DC sources is described herein. This inverter is applicable to high voltage, high power applications such as flexible AC transmission systems (FACTS) including static VAR generation (SVG), power line conditioning, series compensation, phase shifting and voltage balancing and fuel cell and photovoltaic utility interface systems. The M-level inverter consists of at least one phase wherein each phase has a plurality of full bridge inverters equipped with an independent DC source. This inverter develops a near sinusoidal approximation voltage waveform with only one switching per cycle as the number of levels, M, is increased. The inverter may have either single-phase or multi-phase embodiments connected in either wye or delta configurations. 15 figs.

  19. Development of mixed-conducting ceramic membranes for hydrogen separation.

    SciTech Connect (OSTI)

    Guan, J.

    1998-05-18T23:59:59.000Z

    SrCeO{sub 3}- and BaCeO{sub 3}-based proton conductors have been prepared and their transport properties have been investigated by impedance spectroscopy in conjunction with open circuit voltage and water vapor evolution measurements. BaCe{sub 0.8}Y{sub 0.2}O{sub 3-{delta}} exhibits the highest conductivity in a hydrogen-containing atmosphere; however, its electronic conductivity is not adequate for hydrogen separation in a nongalvanic mode. In an effort to enhance ambipolar conductivity and improve interfacial catalytic properties, BaCe{sub 0.8}Y{sub 0.2}O{sub 3-{delta}} cermets have been fabricated into membranes. The effects of ambipolar conductivity, membrane thickness, and interfacial resistance on permeation rates have been investigated. In particular, the significance of interfacial resistance is emphasized.

  20. Species separation and kinetic effects in collisional plasma shocks

    SciTech Connect (OSTI)

    Bellei, C., E-mail: bellei1@llnl.gov; Wilks, S. C.; Amendt, P. A. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States); Rinderknecht, H.; Zylstra, A.; Rosenberg, M.; Sio, H.; Li, C. K.; Petrasso, R. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2014-05-15T23:59:59.000Z

    The properties of collisional shock waves propagating in uniform plasmas are studied with ion-kinetic calculations, in both slab and spherical geometry and for the case of one and two ion species. Despite the presence of an electric field at the shock frontand in contrast to the case where an interface is initially present [C. Bellei et al., Phys. Plasmas 20, 044702 (2013)]essentially no ion reflection at the shock front is observed due to collisions, with a probability of reflection ?10{sup ?4} for the cases presented. A kinetic two-ion-species spherical convergent shock is studied in detail and compared against an average-species calculation, confirming effects of species separation and differential heating of the ion species at the shock front. The effect of different ion temperatures on the DT and D{sup 3}He fusion reactivity is discussed in the fluid limit and is estimated to be moderately important.

  1. Separation of carbon dioxide from flue emissions using Endex principles

    E-Print Network [OSTI]

    Ball, R

    2009-01-01T23:59:59.000Z

    In an Endex reactor endothermic and exothermic reactions are directly thermally coupled and kinetically matched to achieve intrinsic thermal stability, efficient conversion, autothermal operation, and minimal heat losses. Applied to the problem of in-line carbon dioxide separation from flue gas, Endex principles hold out the promise of effecting a carbon dioxide capture technology of unprecedented economic viability. In this work we describe an Endex Calcium Looping reactor, in which heat released by chemisorption of carbon dioxide onto calcium oxide is used directly to drive the reverse reaction, yielding a pure stream of carbon dioxide for compression and geosequestration. In this initial study we model the proposed reactor as a continuous-flow dynamical system in the well-stirred limit, compute the steady states and analyse their stability properties over the operating parameter space, flag potential design and operational challenges, and suggest an optimum regime for effective operation.

  2. Apparatus for separating particles utilizing engineered acoustic contrast capture particles

    DOE Patents [OSTI]

    Kaduchak, Gregory; Ward, Michael D

    2014-10-21T23:59:59.000Z

    An apparatus for separating particles from a medium includes a capillary defining a flow path therein that is in fluid communication with a medium source. The medium source includes engineered acoustic contrast capture particle having a predetermined acoustic contrast. The apparatus includes a vibration generator that is operable to produce at least one acoustic field within the flow path. The acoustic field produces a force potential minima for positive acoustic contrast particles and a force potential minima for negative acoustic contrast particles in the flow path and drives the engineered acoustic contrast capture particles to either the force potential minima for positive acoustic contrast particles or the force potential minima for negative acoustic contrast particles.

  3. Apparatus for separating particles utilizing engineered acoustic contrast capture particles

    DOE Patents [OSTI]

    Kaduchak, Gregory (Los Alamos, NM); Ward, Michael D. (Los Alamos, NM)

    2011-12-27T23:59:59.000Z

    An apparatus for separating particles from a medium includes a capillary defining a flow path therein that is in fluid communication with a medium source. The medium source includes engineered acoustic contrast capture particle having a predetermined acoustic contrast. The apparatus includes a vibration generator that is operable to produce at least one acoustic field within the flow path. The acoustic field produces a force potential minima for positive acoustic contrast particles and a force potential minima for negative acoustic contrast particles in the flow path and drives the engineered acoustic contrast capture particles to either the force potential minima for positive acoustic contrast particles or the force potential minima for negative acoustic contrast particles.

  4. Theory of Nucleation in Phase-separating Nanoparticles

    E-Print Network [OSTI]

    Cogswell, Daniel A

    2013-01-01T23:59:59.000Z

    The basic physics of nucleation in solid \\hl{single-crystal} nanoparticles is revealed by a phase-field theory that includes surface energy, chemical reactions and coherency strain. In contrast to binary fluids, which form arbitrary contact angles at surfaces, complete "wetting" by one phase is favored at binary solid surfaces. Nucleation occurs when surface wetting becomes unstable, as the chemical energy gain (scaling with area) overcomes the elastic energy penalty (scaling with volume). The nucleation barrier thus decreases with the area-to-volume ratio and vanishes below a critical size, and nanoparticles tend to transform in order of increasing size, leaving the smallest particles homogeneous (in the phase of lowest surface energy). The model is used to simulate phase separation in realistic nanoparticle geometries for \\ce{Li_XFePO4}, a popular cathode material for Li-ion batteries, and collapses disparate experimental data for the nucleation barrier, with no adjustable parameters. Beyond energy storage,...

  5. Ionic liquids for separation of olefin-paraffin mixtures

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

    2013-09-17T23:59:59.000Z

    The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

  6. Photoinduced charge separation in a porphyrin-tetraviologen supramolecular array

    SciTech Connect (OSTI)

    Batteas, J.D.; Harriman, A. (Univ. of Texas, Austin (USA)); Kanda, Yu.; Mataga, Noboru (Osaka Univ. (Japan)); Nowak, A.K. (Royal Institution, London (England))

    1990-01-03T23:59:59.000Z

    A porphyrin-tetraviologen supramolecule P-V{sub 4}, in which a viologen molecule is appended to each of the porphyrin meso positions via a 1,3-propanoxy-4-phenyl chain, has been studied by picosecond and nanosecond laser flash photolysis techniques. In DMSO solution, rapid charge separation (CS) occurs from the first excited singlet state of the porphyrin, giving rise to long-lived redox products. These products recombine via first-order kinetics ({tau} = 6.4 {plus minus} 0.7 {mu}s) to restore the ground-state reactants. Similar, but much slower, CS takes place from the porphyrin triplet excited state, which is formed in competition to CS from the singlet state. Quantum yields for formation of redox products and rates of both CS and charge recombination (CR) are solvent dependent, protic solvents favoring rapid CR.

  7. Ionic liquids for separation of olefin-paraffin mixtures

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

    2014-07-15T23:59:59.000Z

    The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

  8. Effect of temperature on layer separation by plasma-hydrogenation

    SciTech Connect (OSTI)

    Di, Zengfeng [Los Alamos National Laboratory; Michael, Nastasi A [Los Alamos National Laboratory; Wang, Yongqiang [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    We have studied hydrogen diffusion in plasma hydrogenated Si/SiGe/Si heterostructure at different temperatures. At low temperature, intrinsic point defects in the molecular beam epitaxy grown Si capping layer are found to compete with the buried strain SiGe layer for hydrogen trapping. The interaction of hydrogen with point defects affects the hydrogen long-range diffusion, and restricts the amount of hydrogen available for trapping by the SiGe layer. However, hydrogen trapping by the capping layer is attenuated with increasing hydrogenation temperature allowing more hydrogen to be trapped in the strain SiGe layer with subsequent surface blister formation. A potential temperature window for plasma hydrogenation induced layer separation is identified based on the combined considerations of trap-limited diffusion at low temperature and outdiffusion of H{sub 2} molecule together with the dissociation of Si-H bonds inside of H platelet at high temperature.

  9. Dual Phase Membrane for High Temperature CO2 Separation

    SciTech Connect (OSTI)

    Jerry Lin

    2007-06-30T23:59:59.000Z

    This project aimed at synthesis of a new inorganic dual-phase carbonate membrane for high temperature CO{sub 2} separation. Metal-carbonate dual-phase membranes were prepared by the direct infiltration method and the synthesis conditions were optimized. Permeation tests for CO{sub 2} and N{sub 2} from 450-750 C showed very low permeances of those two gases through the dual-phase membrane, which was expected due to the lack of ionization of those two particular gases. Permeance of the CO{sub 2} and O{sub 2} mixture was much higher, indicating that the gases do form an ionic species, CO{sub 3}{sup 2-}, enhancing transport through the membrane. However, at temperatures in excess of 650 C, the permeance of CO{sub 3}{sup 2-} decreased rapidly, while predictions showed that permeance should have continued to increase with temperature. XRD data obtained from used membrane indicated that lithium iron oxides formed on the support surface. This lithium iron oxide layer has a very low conductivity, which drastically reduces the flow of electrons to the CO{sub 2}/O{sub 2} gas mixture; thus limiting the formation of the ionic species required for transport through the membrane. These results indicated that the use of stainless steel supports in a high temperature oxidative environment can lead to decreased performance of the membranes. This revelation created the need for an oxidation resistant support, which could be gained by the use of a ceramic-type membrane. Work was extended to synthesize a new inorganic dual-phase carbonate membrane for high temperature CO{sub 2} separation. Helium permeance of the support before and after infiltration of molten carbonate are on the order of 10{sup -6} and 10{sup -10} moles/m{sup 2} {center_dot} Pa {center_dot} s respectively, indicating that the molten carbonate is able to sufficiently infiltrate the membrane. It was found that La{sub 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF) was a suitable candidate for the support material. This support material proved to separate CO{sub 2} when combined with O{sub 2} at a flux of 0.194 ml/min {center_dot} cm{sup 2} at 850 C. It was also observed that, because LSCF is a mixed conductor (conductor of both electrons and oxygen ions), the support was able to provide its own oxygen to facilitate separation of CO{sub 2}. Without feeding O{sub 2}, the LSCF dual phase membrane produced a maximum CO{sub 2} flux of 0.246 ml/min {center_dot} cm{sup 2} at 900 C.

  10. Silica membranes for hydrogen separation from coal gas. Final report

    SciTech Connect (OSTI)

    Gavalas, G.R.

    1996-01-01T23:59:59.000Z

    This project is a continuation of a previous DOE-UCR project (DE-FG22- 89PC89765) dealing with the preparation of silica membranes highly permselective to hydrogen at elevated temperatures, suitable for hydrogen separation from coal gas. The membranes prepared in the previous project had very high selectivity but relatively low permeance. Therefore, the general objectives of this project were to improve the permeance of these membranes and to obtain fundamental information about membrane structure and properties. The specific objectives were: (1) to explore new silylation reagents and reaction conditions with the purpose of reducing the thickness and increasing the permeance of silica membranes prepared by chemical vapor deposition (CVD), (2) to characterize the membrane structure, (3) to delineate mechanism and kinetics of deposition, (4) to measure the permeability of silica layers at different extents of deposition, and (5) to mathematically model the relationship between structure and deposition kinetics.

  11. Scalar $?^4$ field theory for active-particle phase separation

    E-Print Network [OSTI]

    Raphael Wittkowski; Adriano Tiribocchi; Joakim Stenhammar; Rosalind J. Allen; Davide Marenduzzo; Michael E. Cates

    2014-07-11T23:59:59.000Z

    Recent theories predict phase separation among orientationally disordered active particles whose propulsion speed decreases rapidly enough with density. Coarse-grained models of this process show time-reversal symmetry (detailed balance) to be restored for uniform states, but broken by gradient terms; hence detailed-balance violation is strongly coupled to interfacial phenomena. To explore the subtle generic physics resulting from such coupling we here introduce `Active Model B'. This is a scalar $\\phi^4$ field theory (or phase-field model) that minimally violates detailed balance via a leading-order square-gradient term. We find that this additional term has modest effects on coarsening dynamics, but alters the static phase diagram by creating a jump in (thermodynamic) pressure across flat interfaces. Both results are surprising, since interfacial phenomena are always strongly implicated in coarsening dynamics but are, in detailed-balance systems, irrelevant for phase equilibria.

  12. Thermophoretic separation of aerosol particles from a sampled gas stream

    SciTech Connect (OSTI)

    Poztman, A.K.

    1986-02-25T23:59:59.000Z

    A method is described for separating aerosol particles from a gas sample being withdrawn from a contained atmosphere, comprising the following steps: placing within the contained atmosphere a covering gas impermeable enclosure have an interior chamber partly defined by a bottom metal plate that is permeable to gas; fixing the position of the enclosure with the plate facing downwardly and directly exposed to the contained atmosphere; heating the metal plate to a temperature greater than that of the contained atmosphere, whereby aerosol particles are repelled to the resulting thermophoretic forces applied to them by the temperature gradient produced in the atmosphere immediately under the plate; and sampling gas within the interior chamber of the enclosure.

  13. Separated isotopes: vital tools for science and medicine

    SciTech Connect (OSTI)

    Not Available

    1982-01-01T23:59:59.000Z

    Deliberations and conclusions of a Workshop on Stable Isotopes and Derived Radioisotopes organized by the Subcommittee on Nuclear and Radiochemistry of the National Research Council's Committee on Chemical Sciences at the request of the Department of Energy (DOE) are summarized. The workshop was jointly supported by the National Institutes of Health and DOE's Office of Basic Energy Sciences. An overview with three recommendations resulting from the Workshop is followed by reports of the four Workshop panels. Background papers were prepared by individuals on the Steering Committee and made available to all participants prior to the Workshop. They are reproduced as Appendixes 3 to 8. Short reports on alternate separation techniques were presented at the Workshop and are reproduced in Appendixes 9 to 11.

  14. Simulations of strongly phase-separated liquid-gas systems

    E-Print Network [OSTI]

    A. J. Wagner; C. M. Pooley

    2006-08-22T23:59:59.000Z

    Lattice Boltzmann simulations of liquid-gas systems are believed to be restricted to modest density ratios of less than 10. In this article we show that reducing the speed of sound and, just as importantly, the interfacial contributions to the pressure allows lattice Boltzmann simulations to achieve high density ratios of 1000 or more. We also present explicit expressions for the limits of the parameter region in which the method gives accurate results. There are two separate limiting phenomena. The first is the stability of the bulk liquid phase. This consideration is specific to lattice Boltzmann methods. The second is a general argument for the interface discretization that applies to any diffuse interface method.

  15. Separating Signal From Background Using Ensembles of Rules

    SciTech Connect (OSTI)

    Friedman, J.H.; /SLAC /Stanford U., Phys. Dept.

    2006-12-01T23:59:59.000Z

    Machine learning has emerged as a important tool for separating signal events from associated background in high energy particle physics experiments. This paper describes a new machine learning method based on ensembles of rules. Each rule consists of a conjuction of a small number of simple statements (''cuts'') concerning the values of individual input variables. These rule ensembles produce predictive accuracy comparable to the best methods. However their principal advantage lies in interpretation. Because of its simple form, each rule is easy to understand, as is its influence on the predictive model. Similarly, the degree of relevance of each of the respective input variables can be assessed. Graphical representations are presented that can be used to ascertain the dependence of the model jointly on the variables used for prediction.

  16. Moltox Chemical Air Separation System-A Progress Report

    E-Print Network [OSTI]

    Erickson, D. C.; Brown, W. R.; Dunbobbin, B. R.; Massey, R. G.

    MOLTOX~* CHEMICAL AIR SEPARATION SYSTEM - A PROGRESS REPORT Donald C. Er1ckson Energy Concepts Co. Annapo11s, Maryland W111iam R. Brown and Br1an R. Dunbobb1n A1r Products and Chem1ca1s, Inc. Allentown, Pennsy1van1a Robert G. Massey U....S. Department of Energy Wash1ngton, D.C. ABSTRACT A new low energy route to tonnage oxygen product1on, the HOLTOX~ system, 1s now commenc1ng p110t plant test1ng. The process, 1ts h1story, and potent1a1 app11cat10ns will be descr1bed, 1n add1t1on...

  17. Amorphous Alloy Membranes for High Temperature Hydrogen Separation

    SciTech Connect (OSTI)

    Coulter, K

    2013-09-30T23:59:59.000Z

    At the beginning of this project, thin film amorphous alloy membranes were considered a nascent but promising new technology for industrial-scale hydrogen gas separations from coal- derived syngas. This project used a combination of theoretical modeling, advanced physical vapor deposition fabricating, and laboratory and gasifier testing to develop amorphous alloy membranes that had the potential to meet Department of Energy (DOE) targets in the testing strategies outlined in the NETL Membrane Test Protocol. The project is complete with Southwest Research Institute (SwRI), Georgia Institute of Technology (GT), and Western Research Institute (WRI) having all operated independently and concurrently. GT studied the hydrogen transport properties of several amorphous alloys and found that ZrCu and ZrCuTi were the most promising candidates. GT also evaluated the hydrogen transport properties of V, Nb and Ta membranes coated with different transition-metal carbides (TMCs) (TM = Ti, Hf, Zr) catalytic layers by employing first-principles calculations together with statistical mechanics methods and determined that TiC was the most promising material to provide catalytic hydrogen dissociation. SwRI developed magnetron coating techniques to deposit a range of amorphous alloys onto both porous discs and tubular substrates. Unfortunately none of the amorphous alloys could be deposited without pinhole defects that undermined the selectivity of the membranes. WRI tested the thermal properties of the ZrCu and ZrNi alloys and found that under reducing environments the upper temperature limit of operation without recrystallization is ~250 C. There were four publications generated from this project with two additional manuscripts in progress and six presentations were made at national and international technical conferences. The combination of the pinhole defects and the lack of high temperature stability make the theoretically identified most promising candidate amorphous alloys unsuitable for application as hydrogen separation membranes in coal fire systems.

  18. WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION

    SciTech Connect (OSTI)

    Maria Flytzani-Stephanopoulos; Jerry Meldon; Xiaomei Qi

    2001-12-01T23:59:59.000Z

    Optimization of the water-gas shift (WGS) reaction system for hydrogen production for fuel cells is of particular interest to the energy industry. To this end, it is desirable to couple the WGS reaction to hydrogen separation using a semi-permeable membrane, with both processes carried out at high temperature to improve reaction kinetics. Reduced equilibrium conversion of the WGS reaction at high temperatures is overcome by product H{sub 2} removal via the membrane. This project involves fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H{sub 2}-separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams will be examined in the project. In the first year of the project, we prepared a series of nanostructured Cu- and Fe-containing ceria catalysts by a special gelation/precipitation technique followed by air calcination at 650 C. Each sample was characterized by ICP for elemental composition analysis, BET-N2 desorption for surface area measurement, and by temperature-programmed reduction in H{sub 2} to evaluate catalyst reducibility. Screening WGS tests with catalyst powders were conducted in a flow microreactor at temperatures in the range of 200-550 C. On the basis of both activity and stability of catalysts in simulated coal gas, and in CO{sub 2}-rich gases, a Cu-CeO{sub 2} catalyst formulation was selected for further study in this project. Details from the catalyst development and testing work are given in this report. Also in this report, we present H{sub 2} permeation data collected with unsupported flat membranes of pure Pd and Pd-alloys over a wide temperature window.

  19. Dynamical separation of spherical bodies in supersonic flow

    SciTech Connect (OSTI)

    Laurence, Stuart J [Institute of Aerodynamics and Flow Technology, German Aerospace Center; Parziale, Nick J [California Institute of Technology, Pasadena; Deiterding, Ralf [ORNL

    2012-01-01T23:59:59.000Z

    An experimental and computational investigation of the unsteady separation behaviour of two spheres in a highly supersonic flow is carried out. The spherical bodies, initially touching, are released with negligible relative velocity, an arrangement representing the idealized binary fragmentation of a meteoritic body in the atmosphere. In experiments performed in a Mach-4 Ludwieg tube, nylon spheres are initially suspended in the test section by weak threads and, following detachment of the threads by the arrival of the flow, fly freely according to the aerodynamic forces experienced. The resulting sphere motions and unsteady flow structures are recorded using high-speed shadowgraphy. The qualitative separation behaviour and the final lateral velocity of the smaller sphere are found to vary strongly with both the radius ratio and the initial alignment angle of the two spheres. More disparate radii and initial configurations in which the smaller sphere centre lies downstream of that of the larger sphere both increase the tendency for the smaller sphere to be entrained within the flow region bounded by the bow-shock of the larger body, rather than expelled from this region. At a critical angle for a given radius ratio (or a critical radius ratio for a given angle), transition from entrainment to expulsion occurs; at this critical value, the final lateral velocity is close to maximum due to the surfing effect noted by Laurence & Deiterding (J. Fluid Mech., vol. 676, 2011, pp. 396-431) at hypersonic Mach numbers. A high-precision tracking algorithm is used to provide quantitative comparisons between experiments and high-resolution inviscid numerical simulations, with generally favourable agreement.

  20. Binary electrokinetic separation of target DNA from background DNA primers.

    SciTech Connect (OSTI)

    James, Conrad D.; Derzon, Mark Steven

    2005-10-01T23:59:59.000Z

    This report contains the summary of LDRD project 91312, titled ''Binary Electrokinetic Separation of Target DNA from Background DNA Primers''. This work is the first product of a collaboration with Columbia University and the Northeast BioDefense Center of Excellence. In conjunction with Ian Lipkin's lab, we are developing a technique to reduce false positive events, due to the detection of unhybridized reporter molecules, in a sensitive and multiplexed detection scheme for nucleic acids developed by the Lipkin lab. This is the most significant problem in the operation of their capability. As they are developing the tools for rapidly detecting the entire panel of hemorrhagic fevers this technology will immediately serve an important national need. The goal of this work was to attempt to separate nucleic acid from a preprocessed sample. We demonstrated the preconcentration of kilobase-pair length double-stranded DNA targets, and observed little preconcentration of 60 base-pair length single-stranded DNA probes. These objectives were accomplished in microdevice formats that are compatible with larger detection systems for sample pre-processing. Combined with Columbia's expertise, this technology would enable a unique, fast, and potentially compact method for detecting/identifying genetically-modified organisms and multiplexed rapid nucleic acid identification. Another competing approach is the DARPA funded IRIS Pharmaceutical TIGER platform which requires many hours for operation, and an 800k$ piece of equipment that fills a room. The Columbia/SNL system could provide a result in 30 minutes, at the cost of a few thousand dollars for the platform, and would be the size of a shoebox or smaller.