National Library of Energy BETA

Sample records for boone cabell clay

  1. BooNE: Picture Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Picture Gallery BooNE Collaboration Members of the BooNE collaboration Civil Construction Pictorial progress of BooNE civil construction work Detector Installation Pictorial...

  2. BooNE: About BooNE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About BooNE General Information BooNE Collaboration BooNE Experiment BooNE vs MiniBooNE Interesting Facts Posters Virtual Tour Picture Gallery News Articles BooNE photo montage Technical Information BooNE Proposal Original BooNE proposal (30M ps) Run Plan MiniBooNE Run Plan(3.0M ps.gz) Detector TDR Technical Design Report for the MiniBooNE detector (6.1M .ps.gz) Horn TDR Technical Design Report for the MiniBooNE horn (7.5M .ps.gz) 8GeV Beam TDR Technical Design Report for the primary beam (0.4M

  3. BooNE Collaboration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Collaboration The BooNE collaboration consists of approximately sixty-five physicists from 13 institutions. While small on the scale of high energy physics experiments, BooNE thrives from the diversity of its membership. This includes scientists from national laboratories, research universities, predominantly undergraduate institutions, as well as a high school physics teacher. List of Collaborators The BooNE Collaboration The BooNE Collaboration

  4. BooNE Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experiment Goals of BooNE BooNE in a Nutshell Making Neutrinos Detecting Neutrinos schematic of BooNE experiment A sample event (3M animated PDF file) A cosmic ray event as displayed by the MiniBooNE detector.

  5. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Booster Neutrino Experiment (BooNE) Goals of BooNE BooNE in a Nutshell Making Neutrinos Detecting Neutrinos

  6. BooNE: Interesting Facts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interesting Facts About the BooNE experiment: BooNE is the only experiment to search the entire range covered by the LSND oscillation signal. First proposed in 1997, BooNE will be ready to collect data in summer, 2002. The BooNE collaboration is small by high energy physics standards, having 65 physicists from 13 instiutions. If BooNE detects a supernova, it will send an automatic signal to telescopes around the world describing its position. BooNE collaboration - click to enlarge About the

  7. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Picture Gallery BooNE Collaboration Members of the BooNE collaboration Civil Construction Pictorial progress of BooNE civil construction work Detector Installation Pictorial progress of MiniBooNE detector installation BooNE Scrapbook A selection from BooNE

  8. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interesting Facts About the Booster Neutrino Experiment (BooNE): BooNE is the only experiment to search the entire range covered by the LSND oscillation signal. First proposed in 1997, BooNE has been collecting data since August 2002. The BooNE collaboration is small by high energy physics standards, comprising 75 physicists from 16 instiutions. If BooNE detects a supernova, it will send an automatic signal to telescopes around the world describing its position. BooNE collaboration - click to

  9. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Goals of BooNE BooNE's primary goal is to investigate the neutrino oscillation signal reported by the Los Alamos Liquid Scintillator Neutrino Detector (LSND) experiment. In 1995,...

  10. Boone Electric Coop | Open Energy Information

    Open Energy Info (EERE)

    Phone Number: (573) 449-4181 Website: www.booneelectric.coop Twitter: @BooneElectric Facebook: http:www.facebook.comBooneElectric Outage Hotline: (800) 225-8143 Outage Map:...

  11. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact BooNE Spokespersons: E898 (ν running); E944 (anti-ν and beam-dump running) Rex Tayloe rtayloe@indiana.edu (812) 855-3057 Richard Van de Water vdwater@lanl.gov (505) 695 8364 BooNE Experiment: contact-boone@fnal.gov Current Shifter: (505) 500 5511 Detector Enclosure: (630) 840 6881 or 6081 BooNE Collaborators and Associates:

  12. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BooNE General Information BooNE Collaboration Booster Neutrino Experiment (BooNE) BooNE vs MiniBooNE Interesting Facts Posters Virtual Tour Picture Gallery News Articles Technical Information BooNE Proposal Original BooNE proposal (30M ps) Run Plan MiniBooNE Run Plan(3.0M ps.gz) Detector TDR Technical Design Report for the MiniBooNE detector (6.1M .ps.gz) Horn TDR Technical Design Report for the MiniBooNE horn (7.5M .ps.gz) 8GeV Beam TDR Technical Design Report for the primary beam (0.4M .ps.gz)

  13. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scrapbook Page 2 The BooNE collaboration in winter. A tour of the construction site. Working with the BooNE Horn. BooNE in the winter A tour of the construction site. A day with the Horn Janet, Bonnie, and Jen in the Tank. Janet and Bill: the early years. Bill, Richard, Jeff, and Shawn in the midst of discussion. Preparing the tubes Janet and Bill: the early days Discussion in progress The oil tanker arrives. The final stages of oil filling. The BooNE Collaboration in the summer. The oil tanker

  14. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vs MiniBooNE MiniBooNE is the first phase of the Booster Neutrino Experiment (BooNE); in this phase, neutrino oscillation measurements will be made with a single detector. If oscillations are observed, then MiniBooNE will be upgraded to stage two (BooNE) with a two-detector configuration. The BooNE experiment proposes to definitively explore the neutrino oscillation signal reported by the Los Alamos LSND experiment. MiniBooNE represents the first phase for the BooNE collaboration and consists of

  15. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The BooNE collaboration consists of approximately sixty-five physicists from 13 institutions. While small on the scale of high energy physics experiments, BooNE thrives from the diversity of its membership. This includes scientists from national laboratories, research universities, predominantly undergraduate institutions, as well as a high school physics teacher. List of Collaborators

  16. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in a Nutshell BooNE will investigate the question of neutrino mass by searching for oscillations of muon neutrinos into electron neutrinos. This will be done by directing a muon neutrino beam into the MiniBooNE detector and looking for electron neutrinos. This experiment is motivated by the oscillation results reported by the LSND experiment at Los Alamos. By changing the muon neutrino beam into a muon anti-neutrino beam, BooNE can explore oscillations from muon anti-neutrinos to electron

  17. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experiment Details This page provides information on the MiniBooNE experiment. Images are linked in their own page with captions. Additional resources are the Talks, Slides and Posters page, Publications page, and Data Release page Beamline Flux Detector Cross sections Light Propagation (Optical Model) Calibration Particle Identification BooNE photo montage

  18. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For Physicists These pages provides information (numbers, plots, details) of the MiniBooNE experiment and analysis pieces. Images are linked in their own page with captions. Additional resources are the Talks, Slides and Posters page and the Publications page Experiment Details Data Releases BooNE photo montage

  19. Boone County, Missouri: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    is classified as ASHRAE 169-2006 Climate Zone Number 4 Climate Zone Subtype A. Registered Energy Companies in Boone County, Missouri AFuels Technologies LLC Renewable Alternatives...

  20. Boone County, Nebraska: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Albion, Nebraska Cedar Rapids, Nebraska Petersburg, Nebraska Primrose, Nebraska St. Edward, Nebraska Retrieved from "http:en.openei.orgwindex.php?titleBooneCounty,Nebrask...

  1. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proceedings This page contains links to conference proceedings submitted by members of the MiniBooNE collaboration New Guidelines for Submitting Proceedings at MiniBooNE: As of June 2007, we have changed the rules on conference proceedings. Proceedings must be read by one other MiniBooNE person (besides the author) of postdoc level or above before being submitted. Proceedings should also be sent to boone-talks@fnal.gov for archiving on this website. back to Talks page Speaker Proceedings Info

  2. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The primary goal of The inside of the MiniBooNE tank is covered with 1280 photomultiplier tubes. (Courtesy: Fermilab Visual Media Services) this experiment is: To test for neutrino mass by searching for neutrino oscillations. Neutrino mass is important because it may lead us to physics beyond the Standard Model. Masses in the range accessible to MiniBooNE will expand our understanding of how the universe has evolved. The BooNE project began in 1997. The first beam induced neutrino events were

  3. BooNE versus MiniBooNE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vs MiniBooNE MiniBooNE refers to the first phase of the BooNE experiment and describes the neutrino oscillation measurements that will be made with a single detector. If neutrino oscillations are observed, then MiniBooNE will be upgraded to a second detector. This 2-detector arrangement (BooNE) will fulfill the second and final stage of the experiment. The BooNE experiment sets out to definitively explore the neutrino oscillation signal reported by the Los Alamos LSND experiment. MiniBooNE

  4. Solar Viewed as Triple Boon for Bishop Paiute Tribe | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Viewed as Triple Boon for Bishop Paiute Tribe Solar Viewed as Triple Boon for Bishop Paiute Tribe July 1, 2014 - 8:00am Addthis What does this project do? Tribal participants in the GRID Alternatives/Bishop Paiute solar project view the project's triple bottom line of financial savings, job training, and clean energy as a boon to their community in the economically depressed, drought-stricken, and polluted Owens Valley. GRID Alternatives estimates that the Bishop Paiute solar electric

  5. Clay Minerals

    SciTech Connect (OSTI)

    Mueller, Karl T.; Sanders, Rebecca L.; Washton, Nancy M.

    2014-03-14

    Clay minerals are important components of the environment and are involved or implicated in processes such as the uptake of pollutants and the release of nutrients and as potential platforms for a number of chemical reactions. Owing to their small particle sizes (typically, on the order of microns or smaller) and mixing with a variety of other minerals and soil components, advanced characterization methods are needed to study their structures, dynamics, and reactivities. In this article, we describe the use of solid-state NMR methods to characterize the structures and chemistries of clay minerals. Early one-pulse magic-angle spinning (MAS) NMR studies of 27Al and 29Si have now been enhanced and extended with new studies utilizing advanced methodologies (such as Multiple Quantum MAS) as well as studies of less-sensitive nuclei. In additional work, the issue of reactivity of clay minerals has been addressed, including studies of reactive surface area in the environment. Utilizations of NMR-sensitive nuclides within the clay minerals themselves, and in molecules that react with speci?c sites on the clay mineral surfaces, have aided in understanding the reactivity of these complex aluminosilicate systems.

  6. Modified clay sorbents

    DOE Patents [OSTI]

    Fogler, H. Scott; Srinivasan, Keeran R.

    1990-01-01

    A novel modified clay sorbent and method of treating industrial effluents to remove trace pollutants, such as dioxins, biphenyls, and polyaromatics such as benzo(a)pyrene and pentachlorophenol. The novel clay sorbent has a composite structure in which the interlayer space of an expandable clay, such as smectite, is filled with polyvalent or multivalent inorganic cations which forces weaker surfactant cations to locate on the surface of the clay in such an orientation that the resulting composite is hydrophilic in nature. A specific example is cetylpyridinium-hydroxy aluminum-montmorillonite. In certain embodiments, a non-expanding clay, such as kaolinite, is used and surfactant cations are necessarily located on an external surface of the clay. A specific example is cetylpyridinium-kaolinite.

  7. Novel Enzyme from Tiny Gribble Could Prove a Boon for Biofuels Research -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Releases | NREL Novel Enzyme from Tiny Gribble Could Prove a Boon for Biofuels Research Wood borer makes its own enzyme, which could thrive in industrial setting June 11, 2013 Researchers from the United Kingdom, the Energy Department's National Renewable Energy Laboratory (NREL), and the University of Kentucky have recently published a paper describing a novel cellulose-degrading enzyme from a marine wood borer Limnoria quadripunctata, commonly known as the gribble. Gribbles are

  8. Webster Co. Kanawha Co. Cabell C

    Gasoline and Diesel Fuel Update (EIA)

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Appalachian Basin Boundary Appalachian Basin, Southern OH (Panel 4 of 7) Oil and Gas Fields By 2001 BOE Reserve Class Total Total Total Number Liquid Gas BOE of Reserves Reserves Reserves Basin Fields (Mbbl) (MMcf) (Mbbl) Appalachian 3354 79,141 9,550,156 1,670,834 2001 Proved Reserves for Entire Applachian Basin OH WV The mapped oil and gas field

  9. Webster Co. Kanawha Co. Cabell C

    Gasoline and Diesel Fuel Update (EIA)

    Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Appalachian Basin Boundary Appalachian Basin, Southern OH (Panel 4 of 7) Oil and Gas Fields By 2001 Gas

  10. Webster Co. Kanawha Co. Cabell C

    Gasoline and Diesel Fuel Update (EIA)

    Liquids Reserve Class No 2001 liquids reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl Appalachian Basin Boundary Appalachian Basin, Southern OH (Panel 4 of 7) Oil and Gas Fields By 2001 Liquids

  11. Clay Electric Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    Clay Electric Coop Inc Jump to: navigation, search Name: Clay Electric Coop Inc Place: Illinois Phone Number: 1-800-582-9012 Website: www.clayelectric.com Facebook: https:...

  12. Contact micromechanics in granular media with clay

    SciTech Connect (OSTI)

    Ita, S.L.

    1994-08-01

    Many granular materials, including sedimentary rocks and soils, contain clay particles in the pores, grain contacts, or matrix. The amount and location of the clays and fluids can influence the mechanical and hydraulic properties of the granular material. This research investigated the mechanical effects of clay at grain-to-grain contacts in the presence of different fluids. Laboratory seismic wave propagation tests were conducted at ultrasonic frequencies using spherical glass beads coated with Montmorillonite clay (SWy-1) onto which different fluids were adsorbed. For all bead samples, seismic velocity increased and attenuation decreased as the contact stiffnesses increased with increasing stress demonstrating that grain contacts control seismic transmission in poorly consolidated and unconsolidated granular material. Coating the beads with clay added stiffness and introduced viscosity to the mechanical contact properties that increased the velocity and attenuation of the propagating seismic wave. Clay-fluid interactions were studied by allowing the clay coating to absorb water, ethyl alcohol, and hexadecane. Increasing water amounts initially increased seismic attenuation due to clay swelling at the contacts. Attenuation decreased for higher water amounts where the clay exceeded the plastic limit and was forced from the contact areas into the surrounding open pore space during sample consolidation. This work investigates how clay located at grain contacts affects the micromechanical, particularly seismic, behavior of granular materials. The need for this work is shown by a review of the effects of clays on seismic wave propagation, laboratory measurements of attenuation in granular media, and proposed mechanisms for attenuation in granular media.

  13. Cabell County, West Virginia: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Barboursville, West Virginia Culloden, West Virginia Huntington, West Virginia Milton, West Virginia Pea Ridge, West Virginia Retrieved from "http:en.openei.orgw...

  14. Clay Electric Cooperative, Inc- Energy Conservation Loans

    Broader source: Energy.gov [DOE]

    Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 North Florida counties, including Gainesville, Keystone Heights, Lake City, Orange Park, Palatka, and Salt Springs. It...

  15. Clay Electric Cooperative, Inc- Solar Thermal Loans

    Broader source: Energy.gov [DOE]

    Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 counties in northern Florida, including Gainesville, Keystone Heights, Lake City, Orange Park, Palatka, and Salt Springs....

  16. Clay County, Missouri: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Registered Energy Companies in Clay County, Missouri Alternative Energy Sources Inc Smith Electric Vehicles US SEV US Registered Financial Organizations in Clay County,...

  17. Clay Electric Cooperative, Inc | Open Energy Information

    Open Energy Info (EERE)

    Inc Place: Florida Phone Number: 1-888-434-9844 Website: www.clayelectric.com Facebook: https:www.facebook.comClayElectric Outage Hotline: 1-888-434-9844 Outage Map:...

  18. Testing of hollow clay tile masonry prisms

    SciTech Connect (OSTI)

    Jones, W.D.; Butala, M.B.

    1993-10-15

    This paper presents test results of 610-mm wide (24-in.) by 1219-mm high (48-in.) by 203-or 330-mm (8- or 13-in.) thick prisms constructed of hollow clay tiles. Three prisms were extracted fro existing hollow clay title walls and 69 were constructed in laboratories at The University of Tennessee and the National Institute of Standards and Technology (NIST) in Gaithersburg, Maryland. Modulus of Elasticity, E, and compressive strength f{prime}{sub m} were calculated from the results.

  19. Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society (June 2007)

    SciTech Connect (OSTI)

    Randall T. Cygan

    2007-06-01

    Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society was held in early June 2007 in beautiful and historic Santa Fe, New Mexico, USA. Santa Fe provided an idyllic location in the southwestern United States for the attendees to enjoy technical and social sessions while soaking up the diverse culture and wonderful climate of New MexicoThe Land of Enchantment. The meeting included a large and varied group of scientists, sharing knowledge and ideas, benefitting from technical interactions, and enjoying the wonderful historic and enchanted environs of Santa Fe. Including significant number of international scientists, the meeting was attended by approximately two hundred participants. The meeting included three days of technical sessions (oral and poster presentations), three days of field trips to clay and geological sites of northern New Mexico, and a full day workshop on the stabilization of carbon by clays. Details can be found at the meeting web site: www.sandia.gov/clay.

  20. Organic or organometallic template mediated clay synthesis

    DOE Patents [OSTI]

    Gregar, K.C.; Winans, R.E.; Botto, R.E.

    1994-05-03

    A method is described for incorporating diverse varieties of intercalates or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and lithium fluoride for two days in the presence of an organic or organometallic intercalate or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue that are based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by U.S. Pat. No. 3,887,454 issued to Hickson, Jun. 13, 1975; however, a variety of intercalates or templates may be introduced. The intercalates or templates should have (i) water-solubility, (ii) positive charge, and (iii) thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays. 22 figures.

  1. Organic or organometallic template mediated clay synthesis

    DOE Patents [OSTI]

    Gregar, Kathleen C.; Winans, Randall E.; Botto, Robert E.

    1994-01-01

    A method for incorporating diverse Varieties of intercalants or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and lithium fluoride for two days in the presence of an organic or organometallic intercalant or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue that are based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by U.S. Pat. No. 3,887,454 issued to Hickson, Jun. 13, 1975; however, a variety of intercalants or templates may be introduced. The intercalants or templates should have (i) water-solubility, (ii) positive charge, and (iii) thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays.

  2. Microsoft Word - Clay Memo PMC Coburn Obama 11_9_06.doc | Department...

    Office of Environmental Management (EM)

    Clay Memo PMC Coburn Obama 11906.doc Microsoft Word - Clay Memo PMC Coburn Obama 11906.doc Microsoft Word - Clay Memo PMC Coburn Obama 11906.doc More Documents & Publications...

  3. Clay-Union Electric Coop | Open Energy Information

    Open Energy Info (EERE)

    Clay-Union Electric Coop Jump to: navigation, search Name: Clay-Union Electric Coop Place: South Dakota Phone Number: 605-624-2673 Website: www.clayunionelectric.coop Facebook:...

  4. Platte-Clay Electric Coop, Inc | Open Energy Information

    Open Energy Info (EERE)

    Platte-Clay Electric Coop, Inc Jump to: navigation, search Name: Platte-Clay Electric Coop, Inc Place: Missouri Phone Number: 816-628-3121 Website: www.pcec.coop Twitter:...

  5. boone1.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  6. boone2.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  7. boone3.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  8. boone4.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  9. BooNE: Posters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Posters What's a Neutrino? How neutrinos fit into our understanding of the universe. Recipe for a Neutrino Beam Start with some protons... concocting the MiniBooNE beam. The...

  10. Coatings and films derived from clay/wax nanocomposites

    DOE Patents [OSTI]

    Chaiko, David J.; Leyva, Argentina A.

    2006-11-14

    The invention provides methods for making clay/wax nanocomposites and coatings and films of same with improved chemical resistance and gas barrier properties. The invention further provides methods for making and using emulsions of such clay/wax nanocomposites. Typically, an organophillic clay is combined with a wax or wax/polymer blend such that the cohesion energy of the clay matches that of the wax or wax/polymer blend. Suitable organophilic clays include mica and phyllosilicates that have been surface-treated with edge or edge and surface modifying agents. The resulting nanocomposites have applications as industrial coatings and in protective packaging.

  11. Clay-based geothermal drilling fluids

    SciTech Connect (OSTI)

    Guven, N.; Carney, L.L.; Lee, L.J.; Bernhard, R.P.

    1982-11-01

    The rheological properties of fluids based on fibrous clays such as sepiolite and attapulgite have been systematically examined under conditions similar to those of geothermal wells, i.e. at elevated temperatures and pressures in environments with concentrated brines. Attapulgite- and sepiolite-based fluids have been autoclaved at temperatures in the range from 70 to 800/sup 0/F with the addition of chlorides and hydroxides of Na, K, Ca, and Mg. The rheological properties (apparent and plastic viscosity, fluid loss, gel strength, yield point, and cake thickness) of the autoclaved fluids have been studied and correlated with the chemical and physical changes that occur in the clay minerals during the autoclaving process.

  12. Preparation of Clay Brick Using Coal Waste

    SciTech Connect (OSTI)

    Yoo, Jung W.; Jung, Jin H.; Kim, Jae M.; Lee, Sung M.; Kim, Hyung T.

    2004-03-31

    A great deal of coal waste produced during the development of a mine was accumulated around the mine, which caused many problems such as traffic, acid mine drainage and damage of forest and scenery. Carbon in the coal waste helps calcination of the brick even at low temperature. Considering the reuse of natural waste and energy saving, clay brick was prepared using coal waste under various conditions, including particle size, amount of coal waste mixed, calcination temperature and pressing pressure. The specimens were characterized by XRD, SEM and TG-DTA and interpreted in terms of water absorption and compressive strength.

  13. Deputy Secretary Clay Sell Touts Georgian Efforts to Advance Regional

    Energy Savers [EERE]

    Energy Cooperation and Non-Proliferation | Department of Energy Clay Sell Touts Georgian Efforts to Advance Regional Energy Cooperation and Non-Proliferation Deputy Secretary Clay Sell Touts Georgian Efforts to Advance Regional Energy Cooperation and Non-Proliferation March 16, 2007 - 10:55am Addthis Visits National Nuclear Waste Repository in Mtskheta, Georgia TBILISI, Georgia - U.S. Deputy Secretary of Energy Clay Sell today visited the National Radioactive Waste Repository in Mtskheta,

  14. Diagenesis and clay mineral formation at Gale Crater, Mars (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Journal Article: Diagenesis and clay mineral formation at Gale Crater, Mars Citation Details In-Document Search Title: Diagenesis and clay mineral formation at Gale Crater, Mars The Mars Science Laboratory rover Curiosity found host rocks of basaltic composition and alteration assemblages containing clay minerals at Yellowknife Bay, Gale Crater. On the basis of the observed host rock and alteration minerals, we present results of equilibrium thermochemical modeling

  15. Clay County, Florida: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Clay County, Florida: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 29.9943564, -81.7787021 Show Map Loading map... "minzoom":false,"mappings...

  16. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Title: Molecular Simulation of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Abstract not provided. Authors: Tenney, Craig M ; Cygan, ...

  17. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in...

    Office of Scientific and Technical Information (OSTI)

    Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in Deep Saline Aquifers. Authors: Tenney, Craig M. Publication Date: 2012-06-01 OSTI Identifier: 1073284 Report ...

  18. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces...

    Office of Scientific and Technical Information (OSTI)

    Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces in Deep Saline Aquifers. Authors: Tenney, Craig M. Publication Date: 2013-01-01 OSTI Identifier: 1063603 ...

  19. Clay Electric Cooperative, Inc- Energy Smart Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Rebates are available only to Clay Electric Cooperative (CEC) residential members who are making efficiency upgrades to primary residence served by CEC. Rebates are available for residential...

  20. Clay Central Everly School Dist Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Everly School District Energy Purchaser Clay CentralEverly School District Location IA Coordinates 43.1392, -95.2644 Show Map Loading map... "minzoom":false,"mappingservi...

  1. The washability of lignites for clay removal

    SciTech Connect (OSTI)

    Oteyaka, B.; Yamik, A.; Ucar, A.; Sahbaz, O.; Demir, U.

    2008-07-01

    In the washability research of the Seyitomer Lignites (Kutahya-Turkey), with lower calorific value (1,863 kcal/kg) and high ash content (51.91%), by heavy medium separation, it was found out that middling clay in the coal had an effect to change the medium density. To prevent this problem, a trommel sieve with 18 and 5 mm aperture diameter was designed, and the clay in the coal was tried to be removed using it before the coal was released to heavy medium. Following that, the obtained coal in -100 + 18 mm and -18 + 5 mm fractions was subjected to sink and float test having 1.4 gcm{sup -3} and 1.7 gcm{sup -3} medium densities (-5 mm fraction will be evaluated in a separate work). Depending on the raw coal, with the floating of -100 + 18 mm and -18 + 5 mm size fraction in 1.4 gcm{sup -3} medium density, clean coal with 60.10% combustible matter recovery, 19.12% ash, and 3,150 kcal/kg was obtained. Also floating of the samples sinking in 1.4 gcm{sup -3} in the medium density (1.7 gcm{sup -3}), middling with 18.70% combustible matter recovery, 41.93% ash, 2,150 kcal/kg, and tailing having 78.31% ash were obtained.

  2. Clay County Electric Coop Corp | Open Energy Information

    Open Energy Info (EERE)

    Corp Jump to: navigation, search Name: Clay County Electric Coop Corp Place: Arkansas Service Territory: Arkansas, Missouri Phone Number: 870.857.3521 or 870.892.5251 or...

  3. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    SciTech Connect (OSTI)

    Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange; Sonnenthal, Eric; Houseworth, Jim; Birkholzer, Jens

    2010-08-31

    As a result of the termination of the Yucca Mountain Project, the United States Department of Energy (DOE) has started to explore various alternative avenues for the disposition of used nuclear fuel and nuclear waste. The overall scope of the investigation includes temporary storage, transportation issues, permanent disposal, various nuclear fuel types, processing alternatives, and resulting waste streams. Although geologic disposal is not the only alternative, it is still the leading candidate for permanent disposal. The realm of geologic disposal also offers a range of geologic environments that may be considered, among those clay shale formations. Figure 1-1 presents the distribution of clay/shale formations within the USA. Clay rock/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at Mol site, Belgium (Barnichon et al., 2005) have all been under intensive scientific investigations (at both field and laboratory scales) for understanding a variety of rock properties and their relations with flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated and plastic clays (Tsang et al., 2005). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. For both clay rocks, coupled thermal, hydrological, mechanical and chemical (THMC) processes are expected to have a significant impact on the long-term safety of a clay repository. For example, the excavation-damaged zone (EDZ) near repository tunnels can modify local permeability (resulting from induced fractures), potentially leading to less confinement capability (Tsang et al., 2005). Because of clay's swelling and shrinkage behavior (depending on whether the clay is in imbibition or drainage processes), fracture properties in the EDZ are quite dynamic and evolve over time as hydromechanical conditions change. To understand and model the coupled processes and their impact on repository performance is critical for the defensible performance assessment of a clay repository. Within the Natural Barrier System (NBS) group of the Used Fuel Disposition (UFD) Campaign at DOE's Office of Nuclear Energy, LBNL's research activities have focused on understanding and modeling such coupled processes. LBNL provided a report in this April on literature survey of studies on coupled processes in clay repositories and identification of technical issues and knowledge gaps (Tsang et al., 2010). This report will document other LBNL research activities within the natural system work package, including the development of constitutive relationships for elastic deformation of clay rock (Section 2), a THM modeling study (Section 3) and a THC modeling study (Section 4). The purpose of the THM and THC modeling studies is to demonstrate the current modeling capabilities in dealing with coupled processes in a potential clay repository. In Section 5, we discuss potential future R&D work based on the identified knowledge gaps. The linkage between these activities and related FEPs is presented in Section 6.

  4. City of Clay Center, Kansas (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    commu Facebook: https:www.facebook.compagesCity-of-Clay-Center172525069449548?refbrrs Outage Hotline: 785-632-2139 or (785) 632-5454 References: EIA Form EIA-861 Final...

  5. Clay Sell Sworn in as Deputy Secretary of Energy

    Broader source: Energy.gov [DOE]

    WASHINGTON, DC – Jeffrey Clay Sell was sworn in today as Deputy Secretary of Energy at a small ceremony held at the Department of Energy headquarters in Washington, DC.  Mr. Sell was sworn in by...

  6. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral Interactions

    Office of Scientific and Technical Information (OSTI)

    and Determination of Contact Angles. (Journal Article) | SciTech Connect Journal Article: Molecular Simulation of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Abstract not provided. Authors: Tenney, Craig M ; Cygan, Randall T. Publication Date: 2013-08-01 OSTI Identifier: 1106710 Report Number(s):

  7. Diagenesis and clay mineral formation at Gale Crater, Mars (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Journal Article: Diagenesis and clay mineral formation at Gale Crater, Mars Citation Details In-Document Search Title: Diagenesis and clay mineral formation at Gale Crater, Mars × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and

  8. Hollow clay tile wall program summary report

    SciTech Connect (OSTI)

    Henderson, R.C.; Jones, W.D.

    1995-07-30

    Many of the Y-12 Plant buildings, constructed during the 1940s and 1950s, consist of steel ed concrete framing infilled with hollow clay tile (HCT). The infill was intended to provide for building enclosure and was not designed to have vertical or lateral load-carrying capacity. During the late 1970s and early 1980s, seismic and wind evaluations were performed on many of these buildings in conjunction with the preparation of a site-wide safety analysis report. This analytical work, based on the best available methodology, considered lateral load-carrying capacity of the HCT infill on the basis of building code allowable shear values. In parallel with the analysis effort, DOE initiated a program to develop natural phenomena capacity and performance criteria for existing buildings, but these criteria did not specify guidelines for determining the lateral force capacity of frames infilled with HCT. The evaluation of infills was, therefore, based on the provisions for the design of unreinforced masonry as outlined in standard masonry codes. When the results of the seismic and wind evaluations were compared with the new criteria, the projected building capacities fell short of the requirements. Apparently, if the buildings were to meet the new criteria, many millions of dollars would be required for building upgrades. Because the upgrade costs were significant, the assumptions and approaches used in the analyses were reevaluated. Four issues were identified: (1) Once the infilled walls cracked, what capacity (nonlinear response), if any, would the walls have to resist earthquake or wind loads applied in the plane of the infill (in-plane)? (2) Would the infilled walls remain within the steel or reinforced concrete framing when subjected to earthquake or high wind loads applied perpendicular to the infill (out-of-plane)? (3) What was the actual shear capacity of the HCT infill? (4) Was modeling the HCT infill as a shear wall the best approach?

  9. Constitutive relationships for elastic deformation of clay rock: Data Analysis

    SciTech Connect (OSTI)

    Liu, H.H.; Rutqvist, J.; Birkholzer, J.T.

    2011-04-15

    Geological repositories have been considered a feasible option worldwide for storing high-level nuclear waste. Clay rock is one of the rock types under consideration for such purposes, because of its favorable features to prevent radionuclide transport from the repository. Coupled hydromechanical processes have an important impact on the performance of a clay repository, and establishing constitutive relationships for modeling such processes are essential. In this study, we propose several constitutive relationships for elastic deformation in indurated clay rocks based on three recently developed concepts. First, when applying Hooke's law in clay rocks, true strain (rock volume change divided by the current rock volume), rather than engineering strain (rock volume change divided by unstressed rock volume), should be used, except when the degree of deformation is very small. In the latter case, the two strains will be practically identical. Second, because of its inherent heterogeneity, clay rock can be divided into two parts, a hard part and a soft part, with the hard part subject to a relatively small degree of deformation compared with the soft part. Third, for swelling rock like clay, effective stress needs to be generalized to include an additional term resulting from the swelling process. To evaluate our theoretical development, we analyze uniaxial test data for core samples of Opalinus clay and laboratory measurements of single fractures within macro-cracked Callovo-Oxfordian argillite samples subject to both confinement and water reduced swelling. The results from this evaluation indicate that our constitutive relationships can adequately represent the data and explain the related observations.

  10. BooNE Neutrino Oscillations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  11. BooNE News Articles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Articles FermiNews Fermilab's biweekly magazine (several stories) Beam Line: Special Neutrino Issue A special issue of SLAC's quarterly magazine. Earth & Sky "Catching Ghost...

  12. Application of hard X-ray microprobe methods to clay-rich materials (Book)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Application of hard X-ray microprobe methods to clay-rich materials Citation Details In-Document Search Title: Application of hard X-ray microprobe methods to clay-rich materials Authors: Lanzirotti, A. [1] + Show Author Affiliations (UC) Publication Date: 2014-12-22 OSTI Identifier: 1168411 Resource Type: Book Resource Relation: Related Information: CMS Workshop Lectures, Advanced Applications of Synchrotron Radiation in Clay Science Publisher: 2014; Tha Clay Minerals

  13. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces in

    Office of Scientific and Technical Information (OSTI)

    Deep Saline Aquifers. (Conference) | SciTech Connect Surfaces in Deep Saline Aquifers. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces in Deep Saline Aquifers. Authors: Tenney, Craig M. Publication Date: 2013-01-01 OSTI Identifier: 1063603 Report Number(s): SAND2013-0408C DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the CFSES Seminar, University of

  14. Photocatalytic properties of titania pillared clays by different drying methods

    SciTech Connect (OSTI)

    Ding, Z.; Zhu, H.Y.; Lu, G.Q.; Greenfield, P.F.

    1999-01-01

    Photocatalysts based on titania pillared clays (TiO{sub 2} PILCs) have been prepared through a sol-gel method. Different drying methods, air drying (AD), air drying after ethanol extraction (EAD), and supercritical drying (SCD) have been employed and found to have significant effects on the photocatalytic efficiency of the resultant catalysts for the oxidation of phenol in water. Titania pillared clay (TiO{sub 2} PILC) obtained by SCD has the highest external and micropore surface area, largest amount and smallest crystallite size of anatase, and exhibited the highest photocatalytic activity. Furthermore, silica titania pillared clay (SiO{sub 2}-TiO{sub 2} PILC) after SCD, titania coated TiO{sub 2} PILC (SCD) and SiO{sub 2}-TiO{sub 2} PILC (SCD) were synthesized to study the key factors controlling the photocatalytic activity. It is concluded that the dispersion of nanometer-sized anatase on the surface of the PILC particles and the suspensibility of the particles are the most important factors for high photocatalytic efficiency.

  15. Evaluation of Used Fuel Disposition in Clay-Bearing Rock

    SciTech Connect (OSTI)

    Jové Colón, Carlos F.; Weck, Philippe F.; Sassani, David H.; Zheng, Liange; Rutqvist, Jonny; Steefel, Carl I.; Kim, Kunhwi; Nakagawa, Seiji; Houseworth, James; Birkholzer, Jens; Caporuscio, Florie A.; Cheshire, Michael; Rearick, Michael S.; McCarney, Mary K.; Zavarin, Mavrik; Benedicto, Ana; Kersting, Annie B.; Sutton, Mark; Jerden, James; Frey, Kurt E.; Copple, Jacqueline M.; Ebert, William

    2014-08-29

    Radioactive waste disposal in shale/argillite rock formations has been widely considered given its desirable isolation properties (low permeability), geochemically reduced conditions, anomalous groundwater pressures, and widespread geologic occurrence. Clay/shale rock formations are characterized by their high content of clay minerals such as smectites and illites where diffusive transport and chemisorption phenomena predominate. These, in addition to low permeability, are key attributes of shale to impede radionuclide mobility. Shale host-media has been comprehensively studied in international nuclear waste repository programs as part of underground research laboratories (URLs) programs in Switzerland, France, Belgium, and Japan. These investigations, in some cases a decade or more long, have produced a large but fundamental body of information spanning from site characterization data (geological, hydrogeological, geochemical, geomechanical) to controlled experiments on the engineered barrier system (EBS) (barrier clay and seals materials). Evaluation of nuclear waste disposal in shale formations in the USA was conducted in the late 70’s and mid 80’s. Most of these studies evaluated the potential for shale to host a nuclear waste repository but not at the programmatic level of URLs in international repository programs. This report covers various R&D work and capabilities relevant to disposal of heat-generating nuclear waste in shale/argillite media. Integration and cross-fertilization of these capabilities will be utilized in the development and implementation of the shale/argillite reference case planned for FY15. Disposal R&D activities under the UFDC in the past few years have produced state-of-the-art modeling capabilities for coupled Thermal-Hydrological-Mechanical-Chemical (THMC), used fuel degradation (source term), and thermodynamic modeling and database development to evaluate generic disposal concepts. The THMC models have been developed for shale repository leveraging in large part on the information garnered in URLs and laboratory data to test and demonstrate model prediction capability and to accurately represent behavior of the EBS and the natural (barrier) system (NS). In addition, experimental work to improve our understanding of clay barrier interactions and TM couplings at high temperatures are key to evaluate thermal effects as a result of relatively high heat loads from waste and the extent of sacrificial zones in the EBS. To assess the latter, experiments and modeling approaches have provided important information on the stability and fate of barrier materials under high heat loads. This information is central to the assessment of thermal limits and the implementation of the reference case when constraining EBS properties and the repository layout (e.g., waste package and drift spacing). This report is comprised of various parts, each one describing various R&D activities applicable to shale/argillite media. For example, progress made on modeling and experimental approaches to analyze physical and chemical interactions affecting clay in the EBS, NS, and used nuclear fuel (source term) in support of R&D objectives. It also describes the development of a reference case for shale/argillite media. The accomplishments of these activities are summarized as follows: Development of a reference case for shale/argillite; Investigation of Reactive Transport and Coupled THM Processes in EBS: FY14; Update on Experimental Activities on Buffer/Backfill Interactions at elevated Pressure and Temperature; and Thermodynamic Database Development: Evaluation Strategy, Modeling Tools, First-Principles Modeling of Clay, and Sorption Database Assessment;ANL Mixed Potential Model For Used Fuel Degradation: Application to Argillite and Crystalline Rock Environments.

  16. Deputy Secretary of Energy Clay Sell to Depart | Department of Energy

    Energy Savers [EERE]

    Clay Sell to Depart Deputy Secretary of Energy Clay Sell to Depart January 14, 2008 - 10:23am Addthis WASHINGTON, DC - U.S. Secretary of Energy Samuel W. Bodman today released the following statement: "It is with regret that I announce the resignation of Deputy Secretary of Energy Clay Sell. Clay has served with distinction as the Deputy Secretary of Energy for nearly three years and has played a key role in the Administration's efforts to enact landmark energy legislation in 2005 and

  17. Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity...

    Office of Scientific and Technical Information (OSTI)

    Conference: Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity Logs: The Propagation of Errors and Uncertainty Citation Details In-Document Search Title:...

  18. Diagenesis and clay mineral formation at Gale Crater, Mars

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bridges, J. C.; Schwenzer, S. P.; Leveille, R.; Westall, F.; Wiens, R. C.; Mangold, N.; Bristow, T.; Edwards, P.; Berger, G.

    2015-01-18

    The Mars Science Laboratory rover Curiosity found host rocks of basaltic composition and alteration assemblages containing clay minerals at Yellowknife Bay, Gale Crater. On the basis of the observed host rock and alteration minerals, we present results of equilibrium thermochemical modeling of the Sheepbed mudstones of Yellowknife Bay in order to constrain the formation conditions of its secondary mineral assemblage. Building on conclusions from sedimentary observations by the Mars Science Laboratory team, we assume diagenetic, in situ alteration. The modeling shows that the mineral assemblage formed by the reaction of a CO₂-poor and oxidizing, dilute aqueous solution (Gale Portage Water)more » in an open system with the Fe-rich basaltic-composition sedimentary rocks at 10–50°C and water/rock ratio (mass of rock reacted with the starting fluid) of 100–1000, pH of ~7.5–12. Model alteration assemblages predominantly contain phyllosilicates (Fe-smectite, chlorite), the bulk composition of a mixture of which is close to that of saponite inferred from Chemistry and Mineralogy data and to that of saponite observed in the nakhlite Martian meteorites and terrestrial analogues. To match the observed clay mineral chemistry, inhomogeneous dissolution dominated by the amorphous phase and olivine is required. We therefore deduce a dissolving composition of approximately 70% amorphous material, with 20% olivine, and 10% whole rock component.« less

  19. Radiolysis of alanine adsorbed in a clay mineral

    SciTech Connect (OSTI)

    Aguilar-Ovando, Ellen Y.; Negron-Mendoza, Alicia

    2013-07-03

    Optical activity in molecules is a chemical characteristic of living beings. In this work, we examine the hypothesis of the influence of different mineral surfaces on the development of a specific chirality in organic molecules when subjected to conditions simulating the primitive Earth during the period of chemical evolution. By using X-ray diffraction techniques and HPLC/ELSD to analyze aqueous suspensions of amino acids adsorbed on minerals irradiated in different doses with a cobalt-60 gamma source, the experiments attempt to prove the hypothesis that some solid surfaces (like clays and meteorite rocks) may have a concentration capacity and protective role against external sources of ionizing radiation (specifically {gamma}-ray) for some organic compounds (like some amino acids) adsorbed on them. Preliminary results show a slight difference in the adsorption and radiolysis of the D-and L-alanine.

  20. Lanthanides-clay nanocomposites: Synthesis, characterization and optical properties

    SciTech Connect (OSTI)

    Celedon, Salvador; Quiroz, Carolina; Gonzalez, Guillermo; Sotomayor Torres, Clivia M.; Benavente, Eglantina

    2009-05-06

    Complexes of Europium(III) and Terbium(III) with 2,2-bipyridine and 1,10-phenanthroline were inserted into Na-bentonite by ion exchange reactions at room temperature. The products display interlaminar distances and stoichiometries in agreement with the ion exchange capacity and the interlayer space available in the clay. The optical properties of the intercalates, being qualitatively similar to those of the free complexes, are additionally improved with respect to exchange processes with the medium, especially in a moist environment. The protection again hydrolysis, together with the intensity of the optical transition {sup 5}D{sub 0}-{sup 5}F{sub 2} observed in the nanocomposite, makes these products promising for the development of novel optical materials.

  1. Formulation of cracking catalyst based on zeolite and natural clays

    SciTech Connect (OSTI)

    Aliev, R.R.; Lupina, M.I.

    1995-11-01

    Domestically manufactured cracking catalysts are based on a synthetic amorphous aluminosilicate matrix and Y zeolite. A multistage {open_quotes}gel{close_quotes} technology is used in manufacturing the catalysts. The process includes mixing solutions of sodium silicate and acidic aluminum sulfate, forming, syneresis, and activation of the beaded gel. In the manufacture of bead catalysts, the next steps in the process are washing, drying, and calcining; in the manufacture of microbead catalysts, the next steps are dispersion and formation of a hydrogel slurry, spray-drying, and calcining. The Y zeolite is either introduced into the alumina-silica sol in the stage of forming the beads, or introduced in the dispersion stage. With the aim of developing an active and selective cracking catalyst based on Y zeolite and natural clays, with improved physicomechanical properties, the authors carried out a series of studies, obtaining results that are set forth in the present article.

  2. Characterization of Interlayer Cs+ in Clay Samples Using Secondary Ion Mass Spectrometry with Laser Sample Modification

    SciTech Connect (OSTI)

    G. S. Groenewold; R. Avci; C. Karahan; K. Lefebre; R. V. Fox; M. M. Cortez; A. K. Gianotto; J. Sunner; W. L. Manner

    2004-04-01

    Ultraviolet laser irradiation was used to greatly enhance the secondary ion mass spectrometry (SIMS) detection of Cs+ adsorbed to soil consisting of clay and quartz. Imaging SIMS showed that the enhancement of the Cs+ signal was spatially heterogeneous: the intensity of the Cs+ peak was increased by factors up to 100 for some particles but not at all for others. Analysis of standard clay samples exposed to Cs+ showed a variable response to laser irradiation depending on the type of clay analyzed. The Cs+ abundance was significantly enhanced when Cs+-exposed montmorillonite was irradiated and then analyzed using SIMS, which contrasted with the behavior of Cs+-exposed kaolinite, which displayed no Cs+ enhancement. Exposed illitic clays displayed modest enhancement of Cs+ upon laser irradiation, intermediate between that of kaolinite and montmorillonite. The results for Cs+ were rationalized in terms of adsorption to interlayer sites within the montmorillonite, which is an expandable phyllosilicate. In these locations, Cs+ was not initially detectable using SIMS. Upon irradiation, Cs+ was thermally redistributed, which enabled detection using SIMS. Since neither the illite nor the kaolinite is an expandable clay, adsorption to inner-layer sites does not occur, and either modest or no laser enhancement of the Cs+ signal is observed. Laser irradiation also produced unexpected enhancement of Ti+ from illite and kaolinite clays that contained small quantities of Ti, which indicates the presence of microscopic titanium oxide phases in the clay materials.

  3. Mineralogical evaluation and industrial applications of the Triassic clay deposits, Southern Tunisia

    SciTech Connect (OSTI)

    Baccour, H. Medhioub, M.; Jamoussi, F.; Mhiri, T.; Daoud, A.

    2008-11-15

    This study deals with the mineralogical and thermal analysis of Triassic clays in the south-Eastern Tunisia (Medenine area) in order to use them in the faience ceramic. That is why the study had recourse to several quantitative and qualitative research instruments: chemical analysis, mineralogical study, thermal analyses and analyses of geotechnical traits. The data collected from these techniques show that illite and kaolinite are the major clay phases. The accessory minerals detected in powdered rock are; quartz, dolomite and hematite. Geotechnical characterization was carried out on the three representative mixtures of Triassic clay samples. Each mixture is fired at three different temperatures 850,900 and 950 deg. C. Firing characteristics (shrinkage, water absorption, and mechanical resistance to the inflection) were measured and the neomineralization processes were investigated principally by X-ray diffraction. At the end of this study, one can affirm that these clays have qualities necessary for the manufacture of faience ceramic and earthenware production.

  4. Clay Electric Cooperative, Inc- Energy Smart Solar Water Heater Rebate Program

    Broader source: Energy.gov [DOE]

    Clay Electric Cooperative (CEC) provides a rebate of $0.01 per BTU output to its residential members when they purchase qualified solar water heaters. This rebate is capped at 60,000 BTUs per...

  5. Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity

    Office of Scientific and Technical Information (OSTI)

    Logs: The Propagation of Errors and Uncertainty (Conference) | SciTech Connect Conference: Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity Logs: The Propagation of Errors and Uncertainty Citation Details In-Document Search Title: Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity Logs: The Propagation of Errors and Uncertainty No abstract prepared. Authors: Wempe, Wendy ; Mavko, Gary Publication Date: 1999-10-25 OSTI Identifier: 836300 Resource

  6. Statement by Deputy Secretary of Energy Clay Sell on NRG's License

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy by Deputy Secretary of Energy Clay Sell on NRG's License Application Statement by Deputy Secretary of Energy Clay Sell on NRG's License Application September 25, 2007 - 2:49pm Addthis "Today marks the most significant and tangible step to date, towards the construction of the first new nuclear power plant in the United States in over 30 years. DOE is confident that with NRG's reactor design selection and cooperation with their partners, General

  7. Evaluation Of Used Fuel Disposition In Clay-Bearing Rock | Department of

    Office of Environmental Management (EM)

    Energy Of Used Fuel Disposition In Clay-Bearing Rock Evaluation Of Used Fuel Disposition In Clay-Bearing Rock Radioactive waste disposal in shale/argillite rock formations has been widely considered given its desirable isolation properties, e.g., low permeability, potential geochemically reduced conditions, anomalous groundwater pressures, and widespread geologic occurrence. This report describes various R&D activities applicable to shale/argillite media (e.g., progress made on modeling

  8. Spherules from the Cretaceous/Tertiary boundary clay at Gubbio, Italy: the problem of outcrop contamination

    SciTech Connect (OSTI)

    Montanari, A.

    1986-12-01

    Surficial outcrop contamination has occurred in some well-known stratigraphic sections of carbonate rocks in the northern Apennines. A critical case involves several contaminated clay partings, including the Cretaceous/Tertiary boundary clay in the classic Bottaccione section near Gubbio, Italy. These clay layers contain shiny spherules which, in several recent studies, have been said to consist of volcanic glass and have been used to support the hypothesis that the terminal Cretaceous mass extinction was caused by widespread volcanism. Laboratory tests, however, indicate that these shiny spherules are made of HF-insoluble and combustible material and are therefore of recent biological origin. These objects were introduced into the Cretaceous/Tertiary boundary clay and other clay layers from the surrounding soil along with abundant detrital contaminants derived from erosion of the middle Miocene flysch exposed at the head of the Bottaccione Gorge. They are completely different from the altered and flattened microtektitelike spheroids that are found only in the iridium-rich Cretaceous/Tertiary boundary clay and that provide strong evidence for a large impact.

  9. Formation of hydrocarbons from acid-Clay suspensions by gamma irradiation

    SciTech Connect (OSTI)

    Cruz-Castaneda, J.; Negron-Mendoza, A.; Ramos-Bernal, S.

    2013-07-03

    The adsorption of certain organic compounds by clays gives rise to the transformation of the adsorbate through the action of the clays. This phenomenon can be enhanced using ionizing radiation. In this context, these kinds of reactions play an important role in many natural and industrial processes. For example, in oil and gas exploration, the source and trap of petroleum hydrocarbons is frequently clay-rich rocks. Clay-water-based muds are also seen as environmentally friendly alternatives to toxic oil-based fluids. The principal processes that occur in sediments are usually held to be of bacterial action and thermal transformation, which may include thermally induced catalytic alteration of the organic debris. On the other hand, radioactive materials are widely distributed throughout Earth. They were more abundant in the past, but are present in petroleum reservoirs. Their presence induced radioactive bombardment, which may have altered these sediments. This important subject has not been extensively studied. The aim of this work is to study the behavior of fatty acids-like behenic acid-and dicarboxylic acids-like fumaric acid-as model compounds, which are adsorbed in a clay mineral (Na-montmorillonite) and exposed to gamma radiation. The results show that the radiation-induced decomposition of the clay-acid system goes along a definitive path (oxidation), rather than following several modes of simultaneous decomposition, as happens in radiolysis without clay or by heating the system. The main radiolytic products for fatty acids are their corresponding hydrocarbons, with one C-atom less than the original acid.

  10. Report on Modeling Coupled Processes in the Near Field of a Clay Repository

    Broader source: Energy.gov [DOE]

    Clay/shale has been considered as potential host rock for geological disposal of high-level radioactive waste throughout the world. Coupled thermal, hydrological, mechanical, and chemical (THMC) processes have a significant impact on the long-term safety of a clay repository. This report documents results from three R&D activities: (1) implementation and validation of constitutive relationships, (2) development of a discrete fracture network (DFN) model for investigating coupled processes in the excavation damaged zone, and (3) development of a THM model for the Full-Scale Emplacement Experiment tests at Mont Terri, Switzerland, for the purpose of model validation. One major goal is to provide a better understanding of the evolution of the excavation damage zone in clay repositories.

  11. Dynamics of confined reactive water in Smectic clay-zeolite composites.

    SciTech Connect (OSTI)

    Pitman, Michael C.; Van Duin, Adri C. T.

    2012-01-01

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  12. Dynamics of confined reactive water in smectite clay-zeolite composites

    SciTech Connect (OSTI)

    Pitman, Michael C.; Van Duin, Adri C. T.

    2012-01-01

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  13. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  14. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FermiNews A biweekly magazine published by the Fermilab Office of Public Affairs about work and life at Fermilab. 2002: September 20, 2002 - New Neutrino Experiment at Fermilab Goes Live June 14, 2002 - Changing of the Guard: Mike Shaevitz returns to Columbia May 24, 2002 - Beam Me Up: MiniBooNE gets ready to go May 10, 2002 - Dastow 2002: 3D neutrino event simulation Mar. 29, 2002 - Exploring the Invisible Universe Jan. 18, 2002 - A Clear View: MiniBooNE's detector oil 2001: Dec. 14, 2001 -

  15. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Making Neutrinos The Booster Neutrino Experiment starts by producing a beam of neutrinos. In a multi-stage process, protons from one of the Fermilab proton accelerators -- the Booster -- are used to generate muon neutrinos, one of the three types of neutrinos presently known. In the first stage of the production, a pre-accelerator speeds hydrogen ions up to an energy of 750,000 electron volts. The ions then enter a linear accelerator; this device gives the particles even more energy before

  16. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detector The MiniBooNE tank is 12 m diameter sphere, filled with approximately 800 tons of mineral oil, CH2, which has a density of 0.845 ± 0.001 g/cm3. 1280 PMTs provide about 10% coverage of the inner tank region, and 240 PMTs cover the outer, optically isolated "veto" region in the last 1.3 m in the tank. Most of the tubes were recovered from LSND, and are 'old' tubes, some additional ones were bought for MiniBooNE, and are 'new'; differences in the new vs the old tube function are

  17. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Light propagation in mineral oil Though the dominant light observed in MiniBooNE is Cherenkov light, scintillation and fluorescence (here, reabsorbed Cherenkov light re-emitted) account for about 25% of the light. We model: scintillation light (yield, decay times, spectrum), fluorescence, scattering (Rayleigh, Raman), absorption, reflection (off tank walls, PMT faces) and PMT effects (single pe charge response). External measurements Scintillation from p beam (IUCF) Scintillation from cosmic mu

  18. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on a beryllium target. The beam is modeled with measured mean position and angle with Gaussian smearing. MiniBooNE simulates the effects of varying the spread in the beam and...

  19. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dominate. For MiniBooNE, the contributions from multi-pion production and deep inelastic scattering (DIS) are small. image: neutrino cross sections vs energy There are...

  20. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Civil Construction Pictures The civil construction required for the MiniBooNE experiment consists of two independent construction projects. The Detector Construction: This project...

  1. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of light in the oil. image of laser light time components Muon Tracker Two hodoscope planes trigger muons that enter the tank. If the muon stops in one of 3 scintillation cubes,...

  2. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on signal leaves as +1, -1 otherwise. This forms the PID variable. References: Hai-Jun Yang, Byron P. Roe, Ji Zhu(U. Michigan), "Studies of Stability and Robustness for Artificial...

  3. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Some neutrino interactions produce the neutrino's namesake lepton (electron, muon, or tau); this allows the type of neutrino to be tagged. Since neutrino oscillation searches...

  4. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Releases This page provides MiniBooNE data (histograms, error matrices, ntuples, etc) released in association with particular publications. Only the subset of MiniBooNE papers with released data are listed here. Refer to the Publications page for a complete list of MiniBooNE publications. Other MiniBooNE Data Releases: Data Released with A.A. Aguilar-Arevalo et al., "First Measurement of the Muon Antineutrino Double-Differential Charged-Current Quasielastic Cross section",

  5. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plots The plots/images found under the "Public" or "Restricted" headings are approved for public use. Plots listed as "Incoming" are not yet approved and may not be shown publicly. Plots marked PRELIMINARY are subject to change, and care should be taken to mention this fact during any public use. Plots marked TECHNICAL require detailed explanation and should only be used in contexts where it is possible to accompany them with a sufficient amount. In general they

  6. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Milestones 2008: January 1 1E21 protons on target recorded by MiniBooNE 2007: April 10 25m absorber repaired 2006: August 23 9e16 protons delivered in a single hour (Booster champagne goal) January 18 first antineutrino beam 2004: April 26 Record week (04/19-04/26) 6.83E18 protons delivered. 2003: March 28 Record day: 9.6E17 protons delivered March 18 Record day: 8.18E17 protons delivered March 06 5.5E17 protons delivered to MiniBooNE in 1 hour. (passed the official BD 5E16 milestone) March 01

  7. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Progress in Delivering Beam to MiniBooNE

  8. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Author Resources The following is a randomly ordered set of useful resources for people writing MiniBooNE publications:- Have a journal in mind when first putting together the paper. Each journal has LaTeX style files that can be downloaded from their web pages. There is a nice little LaTeX macro that will put line numbers by each line of your document. This makes it much easier for people to feedback comments on the paper. To use it just put \RequirePackage{lineno} just before the

  9. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Talks and Proceedings This page contains links to talks and proceedings about the MiniBooNE experiment presented by members of the collaboration. Password protected link to page containing future talks schedule and unassigned talks list. Password protected link to seminar schedule. Conference talks Other talks Proceedings Posters All Experimenters Meeting talks The MiniBooNE Talks Committee is Jon Link (chair), Rex Tayloe, and Morgan Wascko. Conference Talks Speaker Conference Info Material Name

  10. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Neutrinos General Information Neutrinos Matter A colorful booklet presenting a general introduction to neutrinos, neutrino mass, and neutrino oscillations. Describes theory in a comprehensible way using graphs and diagrams. Neutrino Physics at Fermilab An introduction to the search for neutrino mass and the discovery of the tau neutrino produced by the Public Affairs office at Fermilab; also describes the neutrino experiments at Fermilab. Beam Line: Special Neutrino Issue A special issue of

  11. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    collaboration Find here collaboration lists of MiniBooNE at various stages of the experiment Current MiniBooNE-darkmatter collaboration Original MiniBooNE collaboration From script reading a simple data base, last updated ~2008. from inspirehep.net Booster Neutrino Experiment FNAL-E-0898

  12. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at work Most of the links on this page are password protected. Operational Operations Beam Line Detector Calibrations Analysis Teams Beam Dump Nue Nucleon-DarkMatter Electron-DarkMatter All Nu Run Analyses 2011- Oscillation Low E Events Alt Oscillation NuMI CCQE/NCEL pion (old) CC pi+ (old) NC/CC pi0 POT Summary Summaries Author Resources Publications Oscillation Analysis Worklist ToDo Review Analysis Beam X Factor Baseline X-Sections Final Fits Exotics Algorithms Data Quality LMC OM Fitting

  13. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Events Milestones Latest Beam Progress

  14. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Publications Goto: refereed publications , theses , related publications, proposals/TDRs. Refereed publications by the MiniBooNE Collaboration: A.A. Aguilar-Arevalo et al., Measurement of the Antineutrino Neutral-Current Elastic Differential Cross Section, arXiv:1309.7257, Phys. Rev. D91, 012004 (2015), Data Release A.A. Aguilar-Arevalo et al., First Measurement of the Muon Antineutrino Double Differential Charged Current Quasi-Elastic Cross Section, arXiv:1301.7067, Phys. Rev. D88, 032001

  15. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Virtual Tour This series of pages about MiniBooNE will help you understand more about the what, why, and how of our experiment. When you begin the tour, a new window will open and you can use the next and back buttons to navigate. You may exit at any time by clicking on the "X" button in the upper right hand corner of the window. Start the tour here... This tour was created by Jessica Falco in 2000 and updated by Kelly O'Hear in 2002. Jessica and Kelly were high school students who

  16. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    arXiv:hep-ex0702024 E910 @6.4,12.3 GeVc Parameterization: J.R. Sanford and C.L. Wang, BNL Internal Report BNL11479 image of + production cross section data, fit,...

  17. Special purpose revenue bonds: boon or bane

    SciTech Connect (OSTI)

    Taussig, R.A.

    1985-02-21

    Utilities are looking with increasing interest at the advantages offered by industrial development bonds (IDBs), a financing tool made available to investor-owned utilities through provision of federal law. IDBs are not without problems, however, particularly if regulatory agencies account for them improperly in rate cases. Regulatory agencies should allow returns based on the funds-used rather than the total-funds approach or the tariffs will not compensate investors adequately. The author examines both the risks to be avoided and the benefits when using IDBs.

  18. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Articles FermiNews Fermilab's biweekly magazine (several stories) Beam Line: Special Neutrino Issue A special issue of SLAC's quarterly magazine. Earth & Sky "Catching Ghost...

  19. BooNE: Booster Neutrino Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Posters What's a Neutrino? How neutrinos fit into our understanding of the universe. Recipe for a Neutrino Beam Start with some protons... concocting the MiniBooNE beam. The...

  20. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in Deep Saline

    Office of Scientific and Technical Information (OSTI)

    Aquifers. (Conference) | SciTech Connect in Deep Saline Aquifers. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in Deep Saline Aquifers. Authors: Tenney, Craig M. Publication Date: 2012-06-01 OSTI Identifier: 1073284 Report Number(s): SAND2012-5175C DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the 49th Annual Meeting of The Clay Minerals Society held July

  1. Report on THMC Modeling of the Near Field Evolution of a Generic Clay Repository: Model Validation and Demonstration Rev 2

    Broader source: Energy.gov [DOE]

    Shale and clay-rich rock formations have been considered as potential host rocks for geological disposal of high-level radioactive waste throughout the world: modeling thermal, hydrological, mechanical, and chemical (THMC) of the near field of generic clay repository is discussed.

  2. Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay

    SciTech Connect (OSTI)

    Zheng, L.; Samper, J.; Montenegro, L.; Major, J.C.

    2008-10-15

    During the construction and operational phases of a high-level radioactive waste (HLW) repository constructed in a clay formation, ventilation of underground drifts will cause desaturation and oxidation of the rock. The Ventilation Experiment (VE) was performed in a 1.3 m diameter unlined horizontal microtunnel on Opalinus clay at Mont Terri underground research laboratory in Switzerland to evaluate the impact of desaturation on rock properties. A multiphase flow and reactive transport model of VE is presented here. The model accounts for liquid, vapor and air flow, evaporation/condensation and multicomponent reactive solute transport with kinetic dissolution of pyrite and siderite and local-equilibrium dissolution/precipitation of calcite, ferrihydrite, dolomite, gypsum and quartz. Model results reproduce measured vapor flow, liquid pressure and hydrochemical data and capture the trends of measured relative humidities, although such data are slightly overestimated near the rock interface due to uncertainties in the turbulence factor. Rock desaturation allows oxygen to diffuse into the rock and triggers pyrite oxidation, dissolution of calcite and siderite, precipitation of ferrihydrite, dolomite and gypsum and cation exchange. pH in the unsaturated rock varies from 7.8 to 8 and is buffered by calcite. Computed changes in the porosity and the permeability of Opalinus clay in the unsaturated zone caused by oxidation and mineral dissolution/precipitation are smaller than 5%. Therefore, rock properties are not expected to be affected significantly by ventilation of underground drifts during construction and operational phases of a HLW repository in clay.

  3. Stereo soft x-ray microscopy and elemental mapping of hematite and clay suspensions

    SciTech Connect (OSTI)

    Gleber, S.-C.; Thieme, J.; Chao, W.; Fischer, P.

    2008-09-01

    The spatial arrangements of hematite particles within aqueous soil and clay samples are investigated with soft X-ray microscopy, taking advantage of the elemental contrast at the Fe-L edge around E = 707 eV. In combination with stereo microscopy, information about spatial arrangements are revealed and correlated to electrostatic interactions of the different mixtures. Manipulation of a sample mounted to the microscope is possible and particles added while imaging can be detected.

  4. Investigations of Near-Field Thermal-Hydrologic-Mechanical-Chemical Models for Radioactive Waste Disposal in Clay/Shale Rock

    SciTech Connect (OSTI)

    Liu, H.H.; Li, L.; Zheng, L.; Houseworth, J.E.; Rutqvist, J.

    2011-06-20

    Clay/shale has been considered as potential host rock for geological disposal of high-level radioactive waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus Clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at the Mol site, Belgium (Barnichon and Volckaert, 2003) have all been under intensive scientific investigation (at both field and laboratory scales) for understanding a variety of rock properties and their relationships to flow and transport processes associated with geological disposal of radioactive waste. Figure 1-1 presents the distribution of clay/shale formations within the USA.

  5. Molecular simulation of structure and diffusion at smectite-water interfaces: Using expanded clay interlayers as model nanopores

    SciTech Connect (OSTI)

    Greathouse, Jeffery A.; Hart, David; Bowers, Geoffrey M.; Kirkpatrick, R. James; Cygan, Randall Timothy

    2015-07-20

    In geologic settings relevant to a number of extraction and potential sequestration processes, nanopores bounded by clay mineral surfaces play a critical role in the transport of aqueous species. Solution structure and dynamics at claywater interfaces are quite different from their bulk values, and the spatial extent of this disruption remains a topic of current interest. We have used molecular dynamics simulations to investigate the structure and diffusion of aqueous solutions in clay nanopores approximately 6 nm thick, comparing the effect of clay composition with model Na-hectorite and Na-montmorillonite surfaces. In addition to structural properties at the interface, water and ion diffusion coefficients were calculated within each aqueous layer at the interface, as well as in the central bulk-like region of the nanopore. The results show similar solution structure and diffusion properties at each surface, with subtle differences in sodium adsorption complexes and water structure in the first adsorbed layer due to different arrangements of layer hydroxyl groups in the two clay models. Interestingly, the extent of surface disruption on bulk-like solution structure and diffusion extends to only a few water layers. Additionally, a comparison of sodium ion residence times confirms similar behavior of inner-sphere and outer-sphere surface complexes at each clay surface, but ~1% of sodium ions adsorb in ditrigonal cavities on the hectorite surface. Thus, the presence of these anhydrous ions is consistent with highly immobile anhydrous ions seen in previous nuclear magnetic resonance spectroscopic measurements of hectorite pastes.

  6. Molecular Simulation of Structure and Diffusion at Smectite-Water Interfaces: Using Expanded Clay Interlayers as Model Nanopores

    SciTech Connect (OSTI)

    Greathouse, Jeffery A.; Hart, David; Bowers, Geoffrey M.; Kirkpatrick, R. James; Cygan, Randall Timothy

    2015-07-20

    In geologic settings relevant to a number of extraction and potential sequestration processes, nanopores bounded by clay mineral surfaces play a critical role in the transport of aqueous species. Solution structure and dynamics at claywater interfaces are quite different from their bulk values, and the spatial extent of this disruption remains a topic of current interest. We have used molecular dynamics simulations to investigate the structure and diffusion of aqueous solutions in clay nanopores approximately 6 nm thick, comparing the effect of clay composition with model Na-hectorite and Na-montmorillonite surfaces. In addition to structural properties at the interface, water and ion diffusion coefficients were calculated within each aqueous layer at the interface, as well as in the central bulk-like region of the nanopore. The results show similar solution structure and diffusion properties at each surface, with subtle differences in sodium adsorption complexes and water structure in the first adsorbed layer due to different arrangements of layer hydroxyl groups in the two clay models. Interestingly, the extent of surface disruption on bulk-like solution structure and diffusion extends to only a few water layers. Additionally, a comparison of sodium ion residence times confirms similar behavior of inner-sphere and outer-sphere surface complexes at each clay surface, but ~1% of sodium ions adsorb in ditrigonal cavities on the hectorite surface. Thus, the presence of these anhydrous ions is consistent with highly immobile anhydrous ions seen in previous nuclear magnetic resonance spectroscopic measurements of hectorite pastes.

  7. Clay-sewage sludge co-pyrolysis. A TG-MS and Py-GC study on potential advantages afforded by the presence of clay in the pyrolysis of wastewater sewage sludge

    SciTech Connect (OSTI)

    Ischia, Marco; Maschio, Roberto Dal; Grigiante, Maurizio; Baratieri, Marco

    2011-01-15

    Wastewater sewage sludge was co-pyrolyzed with a well characterized clay sample, in order to evaluate possible advantages in the thermal disposal process of solid waste. Characterization of the co-pyrolysis process was carried out both by thermogravimetric-mass spectrometric (TG-MS) analysis, and by reactor tests, using a lab-scale batch reactor equipped with a gas chromatograph for analysis of the evolved gas phase (Py-GC). Due to the presence of clay, two main effects were observed in the instrumental characterization of the process. Firstly, the clay surface catalyzed the pyrolysis reaction of the sludge, and secondly, the release of water from the clay, at temperatures of approx. 450-500 deg. C, enhanced gasification of part of carbon residue of the organic component of sludge following pyrolysis. Moreover, the solid residue remaining after pyrolysis process, composed of the inorganic component of sludge blended with clay, is characterized by good features for possible disposal by vitrification, yielding a vitreous matrix that immobilizes the hazardous heavy metals present in the sludge.

  8. Laboratory measurements of contaminant attenuation of uranium mill tailings leachates by sediments and clay liners

    SciTech Connect (OSTI)

    Serne, R.J.; Peterson, S.R.; Gee, G.W.

    1983-04-01

    We discuss FY82 progress on the development of laboratory tools to aid in the prediction of migration potential of contaminants present in acidic uranium mill tailings leachate. Further, empirical data on trace metal and radionuclide migration through a clay liner are presented. Acidic uranium mill tailings solution from a Wyoming mill was percolated through a composite sediment called Morton Ranch Clay liner. These laboratory columns and subsequent sediment extraction data show: (1) As, Cr, Pb, Ag, Th and V migrate very slowly; (2) U, Cd, Ni, Zn, Fe, Mn and similar transition metals are initially immobilized during acid neutralization but later are remobilized as the tailings solution exhausts the clay liner's acid buffering capacity. Such metals remain immobilized as long as the effluent pH remains above a pH value of 4 to 4.5, but they become mobile once the effluent pH drops below this range; and (3) fractions of the Se and Mo present in the influent tailings solution are very mobile. Possible controlling mechanisms for the pH-dependent immobilization-mobilization of the trace metals are discussed. More study is required to understand the controlling mechanisms for Se and Mo and Ra for which data were not successfully collected. Using several column lengths (from 4.5 to 65 cm) and pore volume residence times (from 0.8 to 40 days) we found no significant differences in contaminant migration rates or types and extent of controlling processes. Thus, we conclude that the laboratory results may be capable of extrapolation to actual disposal site conditions.

  9. Effects of biogenic silica on acoustic and physical properties of clay-rich marine sediments

    SciTech Connect (OSTI)

    Tribble, J.S.; Mackenzie, F.T.; Urmos, J.; O'Brien, D.K.; Manghnani, M.H. )

    1992-06-01

    The physical properties of marine sediments are influenced by compaction and diagenesis during burial. Changes in mineralogy, chemistry, density, porosity, and microfabric all affect a sediment's acoustic and electrical properties. Sediments from the Japan Trench illustrate the dependence of physical properties on biogenic silica content. Increased opal-A content is correlated with increased porosity and decreased grain density and compressional velocity. Variations with depth in opal-A concentration are therefore reflected in highly variable and, at times, inverse velocity-depth gradients. The diagenetic conversion of opal-A to opal-CT and finally to quartz was investigated at a site in the San Miguel Gap, California. Distinct changes in microfabric, particularly in the porosity distribution, accompany the diagenetic reactions and contribute to a sharp velocity discontinuity at the depth of the opal-A to opal-CT conversion. Evaluation of this reaction at several sites indicates a systematic dependence on temperature and age in clay-rich and moderately siliceous sediments. In ocean margin regions, sediments are buried rapidly, and opal-A may be converted to opal-CT in less than 10 m.y. Temperatures of conversion range from 30{degree} to 50{degree}C. Much longer times (>40 m.y.) are required to complete the conversion in open ocean deposits which are exposed to temperatures less than 15{degree}C. In the absence of silica diagenesis, velocity-depth gradients of most clay-rich and moderately siliceous sediments fall in the narrow range of 0.15 to 0.25 km/s/km which brackets the gradient (0.18 km/s/km) determined for a type pelagic clay section. Relationships such as these can be useful in unraveling the history of a sediment sequence, including the evolution with time of reservoir properties and seismic signatures.

  10. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY GLENVILLE N MINNORA JARVISVILLE FAR MINGTON PH ILIPPI BELIN GT ON WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK WESTON-JAN E LEW SWN DL-WID EN VADIS STANL EY DEKALB UNION TALLM AN SVILL E ASPINALL-FIN ST ER ZOLLARSVILLE WILBU R RAMSEY HEATER S BR IDGEPORT-PRUNT YTOWN ALEXAND ER LILLY FORK SH ERMAN HIRAM ST FK-BLST N CK BU RNS CH APEL S BR WN -LUM BER PORT CON INGS PR ATT BOSWELL REVEL ELK C REEK

  11. Molecular simulation of structure and diffusion at smectite-water interfaces: Using expanded clay interlayers as model nanopores

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Greathouse, Jeffery A.; Hart, David; Bowers, Geoffrey M.; Kirkpatrick, R. James; Cygan, Randall Timothy

    2015-07-20

    In geologic settings relevant to a number of extraction and potential sequestration processes, nanopores bounded by clay mineral surfaces play a critical role in the transport of aqueous species. Solution structure and dynamics at clay–water interfaces are quite different from their bulk values, and the spatial extent of this disruption remains a topic of current interest. We have used molecular dynamics simulations to investigate the structure and diffusion of aqueous solutions in clay nanopores approximately 6 nm thick, comparing the effect of clay composition with model Na-hectorite and Na-montmorillonite surfaces. In addition to structural properties at the interface, water andmore » ion diffusion coefficients were calculated within each aqueous layer at the interface, as well as in the central bulk-like region of the nanopore. The results show similar solution structure and diffusion properties at each surface, with subtle differences in sodium adsorption complexes and water structure in the first adsorbed layer due to different arrangements of layer hydroxyl groups in the two clay models. Interestingly, the extent of surface disruption on bulk-like solution structure and diffusion extends to only a few water layers. Additionally, a comparison of sodium ion residence times confirms similar behavior of inner-sphere and outer-sphere surface complexes at each clay surface, but ~1% of sodium ions adsorb in ditrigonal cavities on the hectorite surface. Thus, the presence of these anhydrous ions is consistent with highly immobile anhydrous ions seen in previous nuclear magnetic resonance spectroscopic measurements of hectorite pastes.« less

  12. Replacemernt of thermally produced calcined clay with chemically structured pigments and methods for the same, quarterly report, January 1, 1995-April 1, 1995

    SciTech Connect (OSTI)

    Whalen-Shaw, M.

    1995-04-25

    The business objective is to manufacture an economically viable chemically structured clay to replace thermally structured calcined clay. The technology will provide substantial benefit in paper coating. The structured pigment containing 90% clay and 10% TiO2 vs the loose blend of these materials as a filler for paper was evaluated. A plan to improve the permanence of the structured pigment using dual functional dispersed pigments is in place. The cationic dispersant for TiO2 will also be a binder. Spray drying will be use to fix the structure of the internally bound structured pigment.

  13. Capillary suction-time tests on selected clays and shales. Master's thesis

    SciTech Connect (OSTI)

    Hart, K.M.

    1989-05-01

    Shale stability has been an ongoing problem in the drilling of oil wells. The Capillary Suction Time test is simple and easy to use, allowing operators to conduct the test at the rigsite. However because of difficulty in reproducing results, the test should be used only qualitatively. The CST, along with the Methylene Blue, Specific Surface Area and Ensilin tests, accurately predicts shale swelling and dispersion. The tests have the added advantage of being able to be conducted relatively quickly. These tests could be carried out at the rigsite while the drilling is taking place. The experiments conducted also demonstrated the usefulness of KCL as an inhibitor of shale swelling and dispersion. From the CST data, it can be seen that KCL concentrations as low as 0.5% are effective in controlling the swelling of Phillips Ekofisk, Phillips Andrews County, Texaco Mississippi Canyon and Pierre Texaco. However a greater concentration of KCL is required to inhibit the swelling of Gold Seal Bentonite, Standard Arizona, Standard Wyoming and Standard Texas. It is recommended that more concentrations of KCL be tested of the high swelling clays to determine the minimum concentration required to inhibit swelling and dispersion.

  14. Petrographic report on clay-rich samples from Permian Unit 4 salt, G. Friemel No. 1 well, Palo Duro Basin, Deaf Smith County, Texas: unanalyzed data

    SciTech Connect (OSTI)

    Fukui, L M

    1983-09-01

    This report presents the results of mineralogic and petrographic analyses performed on five samples of clay-rich rock from salt-bearing Permian strata sampled by drill core from G. Friemel No. 1 Well, Deaf Smith County, Texas. Five samples of clay-rich rock from depths of about 2457, 2458, 2521, 2548, and 2568 feet were analyzed to determine the amounts of soluble phase (halite) and the amounts and mineralogy of the insoluble phases. The amounts of halite found were 59, 79, 47, 40, and 4 weight percent, respectively, for the samples. The insoluble minerals are predominately clay (20 to 60 volume percent) and anhydrite (up to 17 volume percent), with minor (about 1.0%) and trace amounts of quartz, dolomite, muscovite, and gypsum. The clays include illite, chlorite, and interstratified chlorite-smectite. The results presented in this petrographic report are descriptive, uninterpreted data. 2 references, 7 tables.

  15. Swelling properties of montmorillonite and beidellite clay minerals from molecular simulation: Comparison of temperature interlayer cation, and charge location effects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Teich-McGoldrick, Stephanie L.; Greathouse, Jeffery A.; Jove-Colon, Carlos F.; Cygan, Randall Timothy

    2015-08-27

    In this study, the swelling properties of smectite clay minerals are relevant to many engineering applications including environmental remediation, repository design for nuclear waste disposal, borehole stability in drilling operations, and additives for numerous industrial processes and commercial products. We used molecular dynamics and grand canonical Monte Carlo simulations to study the effects of layer charge location, interlayer cation, and temperature on intracrystalline swelling of montmorillonite and beidellite clay minerals. For a beidellite model with layer charge exclusively in the tetrahedral sheet, strong ion–surface interactions shift the onset of the two-layer hydrate to higher water contents. In contrast, for amore » montmorillonite model with layer charge exclusively in the octahedral sheet, weaker ion–surface interactions result in the formation of fully hydrated ions (two-layer hydrate) at much lower water contents. Clay hydration enthalpies and interlayer atomic density profiles are consistent with the swelling results. Water adsorption isotherms from grand canonical Monte Carlo simulations are used to relate interlayer hydration states to relative humidity, in good agreement with experimental findings.« less

  16. Swelling properties of montmorillonite and beidellite clay minerals from molecular simulation: Comparison of temperature interlayer cation, and charge location effects

    SciTech Connect (OSTI)

    Teich-McGoldrick, Stephanie L.; Greathouse, Jeffery A.; Jove-Colon, Carlos F.; Cygan, Randall Timothy

    2015-08-27

    In this study, the swelling properties of smectite clay minerals are relevant to many engineering applications including environmental remediation, repository design for nuclear waste disposal, borehole stability in drilling operations, and additives for numerous industrial processes and commercial products. We used molecular dynamics and grand canonical Monte Carlo simulations to study the effects of layer charge location, interlayer cation, and temperature on intracrystalline swelling of montmorillonite and beidellite clay minerals. For a beidellite model with layer charge exclusively in the tetrahedral sheet, strong ion–surface interactions shift the onset of the two-layer hydrate to higher water contents. In contrast, for a montmorillonite model with layer charge exclusively in the octahedral sheet, weaker ion–surface interactions result in the formation of fully hydrated ions (two-layer hydrate) at much lower water contents. Clay hydration enthalpies and interlayer atomic density profiles are consistent with the swelling results. Water adsorption isotherms from grand canonical Monte Carlo simulations are used to relate interlayer hydration states to relative humidity, in good agreement with experimental findings.

  17. Boone County, Arkansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Bellefonte, Arkansas Bergman, Arkansas Diamond City, Arkansas Everton, Arkansas Harrison, Arkansas Lead Hill, Arkansas Omaha, Arkansas South Lead Hill, Arkansas Valley...

  18. Stimulus Spending at Oak Ridge: A Boon or A Bust?

    Broader source: Energy.gov [DOE]

    Regardless of any political or personal beliefs, ARRA funding enabled the Department of Energys Environmental Management program (DOE EM) to achieve major milestones well ahead of schedule in the environmental clean-up at nuclear sites across the United States.

  19. Boone County, West Virginia: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    West Virginia: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 37.9838605, -81.734942 Show Map Loading map... "minzoom":false,"mappingservice":...

  20. Multiaxial deformation of polyethylene and polyethylene/clay nanocomposites: In situ synchrotron small angle and wide angle X-ray scattering study

    SciTech Connect (OSTI)

    Gurun, Bilge; Bucknall, David G.; Thio, Yonathan S.; Teoh, Chin Ching; Harkin-Jones, Eileen

    2013-01-10

    A unique in situ multiaxial deformation device has been designed and built specifically for simultaneous synchrotron small angle X-ray scattering (SAXS) and wide angle X-ray scattering (WAXS) measurements. SAXS and WAXS patterns of high-density polyethylene (HDPE) and HDPE/clay nanocomposites were measured in real time during in situ multiaxial deformation at room temperature and at 55 C. It was observed that the morphological evolution of polyethylene is affected by the existence of clay platelets as well as the deformation temperature and strain rate. Martensitic transformation of orthorhombic into monoclinic crystal phases was observed under strain in HDPE, which is delayed and hindered in the presence of clay nanoplatelets. From the SAXS measurements, it was observed that the thickness of the interlamellar amorphous region increased with increasing strain, which is due to elongation of the amorphous chains. The increase in amorphous layer thickness is slightly higher for the nanocomposites compared to the neat polymer.

  1. Relationship between crystal structure and thermo-mechanical properties of kaolinite clay: Beyond standard density functional theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Weck, Philippe F.; Kim, Eunja; Jove-Colon, Carlos F.

    2015-03-04

    In this study, the structural, mechanical and thermodynamic properties of 1 : 1 layered dioctahedral kaolinite clay, with ideal Al2Si2O5(OH)4 stoichiometry, were investigated using density functional theory corrected for dispersion interactions (DFT-D2). The bulk moduli of 56.2 and 56.0 GPa predicted at 298 K using the Vinet and Birch–Murnaghan equations of state, respectively, are in good agreement with the recent experimental value of 59.7 GPa reported for well-crystallized samples. The isobaric heat capacity computed for uniaxial deformation of kaolinite along the stacking direction reproduces calorimetric data within 0.7–3.0% from room temperature up to its thermal stability limit.

  2. Relationship between crystal structure and thermo-mechanical properties of kaolinite clay: Beyond standard density functional theory

    SciTech Connect (OSTI)

    Weck, Philippe F.; Kim, Eunja; Jove-Colon, Carlos F.

    2015-03-04

    In this study, the structural, mechanical and thermodynamic properties of 1 : 1 layered dioctahedral kaolinite clay, with ideal Al2Si2O5(OH)4 stoichiometry, were investigated using density functional theory corrected for dispersion interactions (DFT-D2). The bulk moduli of 56.2 and 56.0 GPa predicted at 298 K using the Vinet and BirchMurnaghan equations of state, respectively, are in good agreement with the recent experimental value of 59.7 GPa reported for well-crystallized samples. The isobaric heat capacity computed for uniaxial deformation of kaolinite along the stacking direction reproduces calorimetric data within 0.73.0% from room temperature up to its thermal stability limit.

  3. Efficiency of clay-TiO2 nanocomposites on the photocatalytic eliminationof a model hydrophobic air pollutant

    SciTech Connect (OSTI)

    Kibanova, Daria; Cervini-Silva, Javiera; Destaillats, Hugo

    2009-01-01

    Clay-supported TiO2 photocatalysts can potentially improve the performance of air treatment technologies via enhanced adsorption and reactivity of target volatile organic compounds (VOCs). In this study, a bench-top photocatalytic flow reactor was used to evaluate the efficiency of hectorite-TiO2 and kaolinite-TiO2, two novel composite materials synthesized in our laboratory. Toluene, a model hydrophobic VOC and a common indoor air pollutant, was introduced in the air stream at realistic concentrations, and reacted under UVA (gamma max = 365 nm) or UVC (gamma max = 254 nm) irradiation. The UVC lamp generated secondary emission at 185 nm, leading to the formation of ozone and other short-lived reactive species. Performance of clay-TiO2 composites was compared with that of pure TiO2 (Degussa P25), and with UV irradiation in the absence of photocatalyst under identical conditions. Films of clay-TiO2 composites and of P25 were prepared by a dip-coating method on the surface of Raschig rings, which were placed inside the flow reactor. An upstream toluene concentration of ~;;170 ppbv was generated by diluting a constant flow of toluene vapor from a diffusion source with dry air, or with humid air at 10, 33 and 66percent relative humidity (RH). Toluene concentrations were determined by collecting Tenax-TA (R) sorbent tubes downstream of the reactor, with subsequent thermal desorption -- GC/MS analysis. The fraction of toluene removed, percentR, and the reaction rate, Tr, were calculated for each experimental condition from the concentration changes measured with and without UV irradiation. Use of UVC light (UV/TiO2/O3) led to overall higher reactivity, which can be partially attributed to the contribution of gas phase reactions by short-lived radical species. When the reaction rate was normalized to the light irradiance, Tr/I gamma, the UV/TiO2 reaction under UVA irradiation was more efficient for samples with a higher content of TiO2 (P25 and Hecto-TiO2), but not for Kao-TiO2. In all cases, reaction rates peaked at 10percent RH, with Tr values between 10 and 50percent higher than those measured under dry air. However, a net inhibition was observed as RH increased to 33percent and 66percent, indicating that water molecules competed effectively with toluene for reactive surface sites and limited the overall photocatalytic conversion. Compared to P25, inhibition by co-adsorbed water was less significant for Kao-TiO2 samples, but was more dramatic for Hecto-TiO2 due to the high water uptake capacity of hectorite.

  4. Thermal and mechanical properties of palm oil-based polyurethane acrylate/clay nanocomposites prepared by in-situ intercalative method and electron beam radiation

    SciTech Connect (OSTI)

    Salih, A. M.; Ahmad, Mansor Bin; Ibrahim, Nor Azowa; Dahlan, Khairul Zaman Hj Mohd; Tajau, Rida; Mahmood, Mohd Hilmi; Yunus, Wan Md. Zin Wan

    2014-02-12

    Palm oil based-polyurethane acrylate (POBUA)/clay nanocomposites were prepared via in-situ intercalative polymerization using epoxidized palm oil acrylate (EPOLA) and 4,4' methylene diphenyl diisocyante (MDI). Organically modified Montmorillonite (ODA-MMT) was incorporated in EPOLA (1, 3 and 5%wt), and then subjected to polycondensation reaction with MDI. Nanocomposites solid films were obtained successfully by electron beam radiation induced free radical polymerization (curing). FTIR results reveal that the prepolymer was obtained successfully, with nanoclay dispersed in the matrix. The intercalation of the clay in the polymer matrix was investigated by XRD and the interlayer spacing of clay was found to be increased up to 37 , while the structure morphology of the nanocomposites was investigated by TEM and SEM. The nanocomposites were found to be a mixture of exfoliated and intercalated morphologies. The thermal stability of the nanocomposites was significantly increased by incorporation of nanoclay into the polymer matrix. DSC results reveal that the Tg was shifted to higher values, gradually with increasing the amount of filler in the nanocomposites. Tensile strength and Young's modulus of the nanocomposites showed remarkable improvement compared to the neat POBUA.

  5. {sup 31}P NMR study of the complexation of TBP with lanthanides and actinides in solution and in a clay matrix

    SciTech Connect (OSTI)

    Hartzell, C.J.

    1994-07-24

    Goal was to use NMR to study TBP/lanthanide complexes in the interlayer or on edge sites of clays. Work in this laboratory yielded details of the complexation of Eu(NO{sub 3}){sub 3} and Pr(NO{sub 3}){sub 3} with TBP in hexane solution; this information is crucial to interpretation of results of NMR studies of the complexes exchanged into clays. The solution {sup 31}P-chemical shift values were improved by repeating the studies on the lanthanide salts dissolved directly into neat TBP. NMR studies of these neat solutions of the Eu(NO{sub 3}){sub 3}{lg_bullet}3TBP-complex and the Pr(NO{sub 3}){sub 3}{lg_bullet}3TBP-complex show that the {sup 31}P chemical shift remains relatively constant for TBP: lanthanide ratios below 3: 1. At higher ratios, the chemical shift approaches that of free TBP, indicating rapid exchange of TBP between the free and complexed state. Exchange of these complexes into the clay hectorite yielded discrete {sup 31}P-NMR signals for the Eu{lg_bullet}TBP complex at -190 ppm and free TBP at -6 ppm. Adsorption of the Pr{lg_bullet}TBP complex yielded broad signals at 76 ppm for the complex and -6 ppm for free TBP. There was no evidence of exchange between the incorporated complex and the free TBP.

  6. The effect of clay catalyst on the chemical composition of bio-oil obtained by co-pyrolysis of cellulose and polyethylene

    SciTech Connect (OSTI)

    Solak, Agnieszka; Rutkowski, Piotr

    2014-02-15

    Highlights: Non-catalytic and catalytic fast pyrolysis of cellulose/polyethylene blend was carried out in a laboratory scale reactor. Optimization of process temperature was done. Optimization of clay catalyst type and amount for co-pyrolysis of cellulose and polyethylene was done. The product yields and the chemical composition of bio-oil was investigated. - Abstract: Cellulose/polyethylene (CPE) mixture 3:1, w/w with and without three clay catalysts (K10 montmorillonite K10, KSF montmorillonite KSF, B Bentonite) addition were subjected to pyrolysis at temperatures 400, 450 and 500 C with heating rate of 100 C/s to produce bio-oil with high yield. The pyrolytic oil yield was in the range of 41.379.5 wt% depending on the temperature, the type and the amount of catalyst. The non-catalytic fast pyrolysis at 500 C gives the highest yield of bio-oil (79.5 wt%). The higher temperature of catalytic pyrolysis of cellulose/polyethylene mixture the higher yield of bio-oil is. Contrarily, increasing amount of montmorillonite results in significant, almost linear decrease in bio-oil yield followed by a significant increase of gas yield. The addition of clay catalysts to CPE mixture has a various influence on the distribution of bio-oil components. The addition of montmorillonite K10 to cellulose/polyethylene mixture promotes the deepest conversion of polyethylene and cellulose. Additionally, more saturated than unsaturated hydrocarbons are present in resultant bio-oils. The proportion of liquid hydrocarbons is the highest when a montmorillonite K10 is acting as a catalyst.

  7. Obama Administration Announces Additional $14,003,800 for Local...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... WV Wheeling City 137,800 WV Berkeley County 329,600 WV Cabell County 206,900 WV Harrison County 219,100 WV Jefferson County 207,900 WV Kanawha County 583,400 WV Mercer ...

  8. EIS-0169-SA-08: Supplement Analysis

    Broader source: Energy.gov [DOE]

    Yakima/Klickitat Fisheries Project, Boone Pond Acclimation Site, Cle Elum, Kittitas County, Washington

  9. Carbon Emissions: Stone, Clay, and Glass Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Contact: Stephanie Battles Stephanie.Battles@eia.doe.gov (Phone: (202) 586-7237) FAX: 202-586-0018 Contact Us URL: http:www.eia.govemeuefficiencycarbonemissionsstone...

  10. North Carolina Residential Energy Code Field Study

    Broader source: Energy.gov [DOE]

    Lead Performer: Appalachian State University – Boone, NCPartners: North Carolina Energy Efficiency Alliance – Boone, NCDOE Total Funding: $774,723Cost Share: $89,301Project Term: 2014 – 2017Funding...

  11. Use of Reinforced Lightweight Clay Aggregates for Landslide Stabilisation

    SciTech Connect (OSTI)

    Herle, Vitezslav

    2008-07-08

    In spring 2006 a large landslide combined with rock fall closed a highway tunnel near Svitavy in NE part of Czech Republic and cut the main highway connecting Bohemia with Moravia regions. Stabilisation work was complicated by steep mountainous terrain and large inflow of surface and underground water. The solution was based on formation of a stabilisation fill made of reinforced free draining aggregates at the toe of the slope with overlying lightweight fill up to 10 m high reinforced with PET geogrid and steel mesh protecting soft easily degrading sandstone against weathering. Extensive monitoring made possible to compare the FEM analysis with real values. The finished work fits very well in the environment and was awarded a special prize in the 2007 transport structures contest.

  12. Clay County, Kentucky: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Kentucky: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 37.1738044, -83.7199136 Show Map Loading map... "minzoom":false,"mappingservice":"goo...

  13. Clay County, Arkansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Arkansas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 36.3492244, -90.3748354 Show Map Loading map... "minzoom":false,"mappingservice":"goo...

  14. Clay County, Indiana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Indiana: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 39.368622, -87.1422895 Show Map Loading map... "minzoom":false,"mappingservice":"googl...

  15. Clay County, North Carolina: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    North Carolina: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 35.0964003, -83.7199136 Show Map Loading map... "minzoom":false,"mappingservice...

  16. Clay County, Tennessee: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Tennessee: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 36.5701766, -85.56121 Show Map Loading map... "minzoom":false,"mappingservice":"goog...

  17. Clay County, South Dakota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    South Dakota: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 42.8829344, -97.0068393 Show Map Loading map... "minzoom":false,"mappingservice":...

  18. Clay County, Kansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Kansas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 39.34792, -97.179026 Show Map Loading map... "minzoom":false,"mappingservice":"googlema...

  19. Clay County, West Virginia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    West Virginia: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 38.4417717, -81.1196075 Show Map Loading map... "minzoom":false,"mappingservice"...

  20. Clay County, Alabama: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Alabama: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 33.279527, -85.8486236 Show Map Loading map... "minzoom":false,"mappingservice":"googl...

  1. Clay Center, Ohio: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Ohio: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 41.5633831, -83.3618725 Show Map Loading map... "minzoom":false,"mappingservice":"googlem...

  2. Clay County, Iowa: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Iowa: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 43.1368038, -95.1432068 Show Map Loading map... "minzoom":false,"mappingservice":"googlem...

  3. Clay County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Texas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 33.7900416, -98.2212979 Show Map Loading map... "minzoom":false,"mappingservice":"google...

  4. Clay Minerals Related To The Hydrothermal Activity Of The Bouillante...

    Open Energy Info (EERE)

    Minerals Related To The Hydrothermal Activity Of The Bouillante Geothermal Field (Guadeloupe) Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  5. Clay County, Nebraska: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Nebraska: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.5975479, -98.0465185 Show Map Loading map... "minzoom":false,"mappingservice":"goo...

  6. Clay County, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Illinois: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 38.7279431, -88.556531 Show Map Loading map... "minzoom":false,"mappingservice":"goog...

  7. Clay County, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Minnesota: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 46.878186, -96.4257589 Show Map Loading map... "minzoom":false,"mappingservice":"goo...

  8. Clay County, Georgia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Georgia: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 31.6447931, -85.0025539 Show Map Loading map... "minzoom":false,"mappingservice":"goog...

  9. Clay County, Mississippi: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Mississippi: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 33.6567838, -88.8263006 Show Map Loading map... "minzoom":false,"mappingservice":"...

  10. Deputy Secretary Clay Sell Touts Georgian Efforts to Advance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    While in Georgia, Deputy Secretary Sell met with the Speaker of the Georgian Parliament, Nino Burjanadze and Minister of Foreign Affairs, Gela Bezhuashvili, to discuss the ...

  11. Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Energy Frontier Research Centers (EFRC); Center for Frontiers of Subsurface Energy Security (CFSES) Sponsoring Org: USDOE SC Office of Basic Energy Sciences (SC-22) ...

  12. Tensile strengths of problem shales and clays. Master's thesis

    SciTech Connect (OSTI)

    Rechner, F.J.

    1990-01-01

    The greatest single expense faced by oil companies involved in the exploration for crude oil is that of drilling wells. The most abundant rock drilled is shale. Some of these shales cause wellbore stability problems during the drilling process. These can range from slow rate of penetration and high torque up to stuck pipe and hole abandonment. The mechanical integrity of the shale must be known when the shalers are subjected to drilling fluids to develop an effective drilling plan.

  13. PowerFilm Solar Inc | Open Energy Information

    Open Energy Info (EERE)

    Solar Inc Place: Boone, Iowa Zip: 50036 7538 Product: Developer of a method for manufacturing thin-film amorphous silicon modules, from silane gas and plastic substrate, using...

  14. Microsoft PowerPoint - Chairs Round Robin Presentation- Topics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (taxes & payroll) properties; financial drain to financial boon. www.energy.gov... Northern New Mexico Citizens' Advisory Board Topic: * Addressing Transuranic Waste at Los ...

  15. Two former longtime employees pass away | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    employees pass away Former Ames Laboratory metallurgy program chair John (Jack) Smith of Ames passed away Sept. 26 and long-time facilities plumber Pat Stowell of Boone,...

  16. Tritium High Vacuum Pump Test Plan

    Office of Environmental Management (EM)

    High Vacuum Pump Test Plan Tritium Programs Engineering Louis Boone Joel Bennett ... Shimming will have to be internal to the pump. Test System Measure ultimate vacuum with ...

  17. STARTING TODAY: Bloomberg, Daniels, Musk, Pickens, Chu and Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Investment Bank Regulatory Affairs Blythe Masters Tesla Motors CEO Elon Musk Entrepreneur T. Boone Pickens DARPA Director Arati Prabhakar Michael Jones, Chief Technology ...

  18. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    provides loans for single family residencies and owner occupied duplexes in Hamilton, Butler, Warren, and Clermont counties in Ohio and Boone, Kenton, and... Eligibility:...

  19. Greater Cincinnati Energy Alliance- Residential Loan Program

    Broader source: Energy.gov [DOE]

    The Greater Cincinnati Energy Alliance provides loans for single family residencies and owner occupied duplexes in Hamilton, Butler, Warren, and Clermont counties in Ohio and Boone, Kenton, and...

  20. South Dakota begins to reap benefits of underground lab

    SciTech Connect (OSTI)

    Feder, Toni

    2015-04-15

    The boon to the states education and economy will be amplified if the Long-Baseline Neutrino Facility is realized.

  1. Computing Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    here you can find information relating to: Obtaining the right computer accounts. Using NIC terminals. Using BooNE's Computing Resources, including: Choosing your desktop....

  2. Geoffrey Mills Los Alamos National Laboratory SBNP Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SBNP Workshop 12 May, 2011 MiniBooNE and BooNE 1. MiniBooNE Appearance Results 2. Other Anomalies 3. Resolution: The BooNE Proposal 4. Conclusions Synopsis: " A number of anomalies are appearing in neutrino data in the region of m 2 ~ an eV 2 " Predominantly from single detector experiments... " There is some possibility that the effects are due to oscillations between sterile neutrinos and active neutrinos " A definitive experiment is warranted " BooNE would be such an

  3. Morgan Wascko Imperial College London M.O. Wascko FNAL User's Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the BooNEs Morgan Wascko Imperial College London M.O. Wascko FNAL User's Meeting M. Sorel Goals of the BooNEs * MiniBooNE: Confirm or rule out LSND * SciBooNE: * Near detector measurements for MiniBooNE * Precise cross section measurements * Especially useful for T2K 2 M.O. Wascko FNAL User's Meeting Goals of the BooNEs * MiniBooNE: Confirm or rule out LSND * SciBooNE: * Near detector measurements for MiniBooNE * Precise cross section measurements * Especially useful for T2K 2 W + ν µ n p

  4. Microsoft Word - FINAL 2013 Hydropower Meeting Agenda 060713

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SOUTHWESTERN FEDERAL HYDROPOWER MEETING The Earl Cabell Federal Building 1100 Commerce Street Red River Room Floor 7, Room 752A Dallas, Texas June 12 - 13, 2013 Wednesday, June 12 1:00 p.m. Welcome Terry Bachim, SWF 1:15 p.m. Introductory Remarks SWD SWF Steven Miles, HDC Chris Turner, SWPA Ted Coombes, SPRA 1:30 p.m. Proposed Planning Documentation Kamau Sadiki, COE HQ For Major Rehabs, Washington Update, HMI Progress 2:00 p.m. Roundtable Discussion - Miles Waldron, SWD Regionalization of Corps

  5. Microsoft Word - FINAL 2013 HydropowerCouncilAgenda 060513

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Southwestern Federal Hydropower Council The Earl Cabell Federal Building 1100 Commerce Street Red River Room Floor 7, Room 752A Dallas, Texas June 11 - 12, 2013 Monday, June 10 1:30 p.m. Whitney Powerhouse Site Visit Fort Worth District Hillsboro, Texas Tuesday, June 11 1:00 p.m. Welcome Fort Worth District 1:05 p.m. Introductions All 1:15 p.m. FY 13 COE Budget Southwestern / COE Districts 1:30 p.m. Presentation of Proposed FY 14 COE Districts Work Packages 3:15 p.m. BREAK 3:30 p.m. Presentation

  6. Strong-Sludge Gas Retention and Release Mechanisms in Clay Simulants

    SciTech Connect (OSTI)

    Gauglitz, Phillip A.; Buchmiller, William C.; Probert, Samuel G.; Owen, Antionette T.; Brockman, Fred J.

    2012-02-24

    The Hanford Site has 28 double-shell tanks (DSTs) and 149 single-shell tanks (SSTs) containing radioactive wastes that are complex mixes of radioactive and chemical products. The mission of the Department of Energy's River Protection Project is to retrieve and treat the Hanford tank waste for disposal and close the tank farms. A key aspect of the mission is to retrieve and transfer waste from the SSTs, which are at greater risk for leaking, into DSTs for interim storage until the waste is transferred to and treated in the Waste Treatment and Immobilization Plant. There is, however, limited space in the existing DSTs to accept waste transfers from the SSTs, and approaches to overcoming the limited DST space will benefit the overall mission. The purpose of this study is to summarize and analyze the key previous experiment that forms the basis for the relaxed controls and to summarize progress and results on new experiments focused on understanding the conditions that result in low gas retention. The previous large-scale test used about 50 m3 of sediment, which would be unwieldy for doing multiple parametric experiments. Accordingly, experiments began with smaller-scale tests to determine whether the desired mechanisms can be studied without the difficulty of conducting very large experiments. The most significant results from the current experiments are that progressively lower gas retention occurs in tests with progressively deeper sediment layers and that the method of gas generation also affects the maximum retention. Based on the results of this study, it is plausible that relatively low gas retention could occur in sufficiently deep tank waste in DSTs. The current studies and previous work, however, have not explored how gas retention and release will behave when two or more layers with different properties are present.

  7. Kathryn Clay, Ph.D. Vice President of Policy Strategy American...

    Broader source: Energy.gov (indexed) [DOE]

    ... establishing special permitting processes for specific categories of natural gas pipeline projects, such as emergency work, replacements and repeat projects in existing easements, ...

  8. K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles...

    Open Energy Info (EERE)

    (765 m) gives an age of 6.74 Ma. Two dates on illite from sandstones in Permian red beds (1008 and 1187 m) are 4.33 and 4.07 Ma, respectively. Surprisingly, three dates on...

  9. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A. (Idaho Falls, ID); Dugan, Patrick R. (Idaho Falls, ID)

    1995-01-01

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  10. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A.; Dugan, Patrick R.

    1995-04-04

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  11. Application of hard X-ray microprobe methods to clay-rich materials...

    Office of Scientific and Technical Information (OSTI)

    Authors: Lanzirotti, A. 1 + Show Author Affiliations (UC) Publication Date: 2014-12-22 OSTI Identifier: 1168411 Resource Type: Book Resource Relation: Related Information: CMS ...

  12. Z-Bed Recovery Water Disposal

    Office of Environmental Management (EM)

    Z-Bed Recovery Water Disposal Tritium Programs Engineering Louis Boone Josh Segura Savannah River Nuclear Solutions, LLC M-TRT-H-00087 Rev 0 Date: 4102014 Tritium Facilities...

  13. Herbert Glaser | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    was in private practice with the international law firm of Haynes and Boone, LLP. Mr. ... the fields of project finance and energy law. He is an honors graduate of Kalamazoo ...

  14. Sheldahl, Iowa: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    is a stub. You can help OpenEI by expanding it. Sheldahl is a city in Boone County and Polk County and Story County, Iowa. It falls under Iowa's 4th congressional district and...

  15. BioenergizeME Virtual Science Fair: Is Algae the Next Big Thing

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Daniel Boone Area High School in Birdsboro, PA, as part of the U.S. Department of Energy-BioenergizeME Virtual Science Fair.

  16. BioenergizeME Virtual Science Fair: History of Biomass

    Broader source: Energy.gov [DOE]

    This infographic was created by students from Daniel Boone Area High School in Birdsboro, PA, as part of the U.S. Department of Energy-BioenergizeME Virtual Science Fair.

  17. Graphene's 3D Counterpart

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    All of these novel properties can be a boon for future electronic technologies. Future 3DTDS systems can also serve as an ideal platform for applications in spintronics. A ...

  18. Cincinnati Canvassing Spreads Retrofitting Message | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    awarded to the Alliance with support from Cincinnati and Hamilton County in Ohio, and the counties of Boone, Kenton and Campbell and cities of Covington and Florence in Kentucky. ...

  19. CX-007548: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Boone County Sewer District - Waste Water Treatment Plant Upgrades CX(s) Applied: B5.1 Date: 01/10/2012 Location(s): Missouri Offices(s): Golden Field Office

  20. CX-005747: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Biobased Materials Automotive Value Chain Market Development AnalysisCX(s) Applied: A9Date: 05/04/2011Location(s): Boone County, IllinoisOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  1. TFG Apr 2014 Attendance SRS.xlsx

    Office of Environmental Management (EM)

    Attendee Presenter Topic Antoniazzi, Armando Kinectrics, Inc.   Tritium in Molecular Sieves Boniface, Hugh AECL   Aspects of current tritium R&D at AECL Boone, Louis SRNL   Normatex Pump Replacement Progress Boone, Louis SRNL   Tritiated Water Disposal Buley, Rex Leidos/NA-123  Busigin, Anthony Nitek   Comparison of Water-Hydrogen Catalytic Exchange Processes versus Water Distillation for Water Detritiation Clark, Jared SRNL   Diffuser Stage Procurement

  2. Sandia Energy - Study Could Help Improve Nuclear Waste Repositories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    underground clay formations for nuclear waste disposal, because clay offers low permeability and high radionuclide retention. Even when a repository isn't sited in clay,...

  3. 2016MSSBresults

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 13 2 6 3 7 14 4 8 19 9 15 L 7 16 11 17 L 14 18 20 21 CHAMPIONSHIP Champion Ames Middle School Runner-up LeMars Middle School Third Place Madrid Middle School Fourth Place Stilwell Middle School (WDM) Challenger Bracket Undefeated Bracket Science Bowl 2016 Double Elimination Competition (12 Teams) Ames #1 60 10 L 5 12 North Union 56 Lynville-Sully 58 LeMars 72 Northwood-Kensett 78 Boone 40 Madrid 56 North Union 34 Lynnville-Sully 52 Boone - Forfeit Adel-Desoto-Minburn Adel-Desoto-Minburn 36

  4. Computing Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resources This page is the repository for sundry items of information relevant to general computing on BooNE. If you have a question or problem that isn't answered here, or a suggestion for improving this page or the information on it, please mail boone-computing@fnal.gov and we'll do our best to address any issues. Note about this page Some links on this page point to www.everything2.com, and are meant to give an idea about a concept or thing without necessarily wading through a whole website

  5. MiniBooNE Cross Sections

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sections Group e-mail: BOONE-CROSSSECTIONS(AT)fnal.gov convenors: Alessandro Curioni (alessandro.curioni(AT)yale.edu) and Sam Zeller (gzeller(AT)fnal.gov) Cross Sections at MiniBooNE, Meetings, Reference Articles, Conferences, Useful Links Last updated on 07/19/07

  6. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Clay Electric Cooperative, Inc- Energy Conservation Loans Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 North Florida counties, including Gainesville,...

  7. Remote Sensing For Geothermal Exploration Over Buffalo Valley...

    Open Energy Info (EERE)

    and spectral resolution of the data allows for the identification of carbonate, sulfate, silica and clay minerals. Quartz- and clay-rich regions of Buffalo Valley were...

  8. Experimental and Modeling Investigation of Radionuclide Interaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    interactions with clay minerals with results suggesting that iodide may directly interact with clays by forming ion-pairs which may concentrate within the interlayer space as...

  9. Magnetotelluric Techniques | Open Energy Information

    Open Energy Info (EERE)

    cap, and also in determining the boundary between the alteration zone and the geothermal reservoir. The clay cap composition typically consists of a conductive clay from the...

  10. Round Robin Testing of Commercial Hydrogen Sensor Performance - Observations and Results: Preprnt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Round Robin Testing of Commercial Hydrogen Sensor Performance-Observations and Results Preprint W. Buttner, R. Burgess, C. Rivkin, and M. Post National Renewable Energy Laboratory L. Boon-Brett, G. Black, F. Harskamp, and P. Moretto European Commission, DG Joint Research Centre, Institute for Energy Presented at the 2010 National Hydrogen Association Hydrogen Conference and Expo Long Beach, California May 3-6, 2010 Conference Paper NREL/CP-5600-48305 October 2010 NOTICE The submitted manuscript

  11. This is the title of the presentation on three lines if you need it

    Office of Environmental Management (EM)

    Polymers for Tritium Service Laura Tovo Jay Gaillard 1 , Steven Serkiz 1 , Hector Colon-Mercado 1 , Brent Peters 1 , Timothy DeVol 2 , Richard Czerw 3 Tritium Engineer: Louis Boone September 24, 2014 1 Savannah River National Laboratory, Aiken, SC 2 Clemson University, Clemson, SC 2 NanoTechLabs, Inc., Yadkinville, NC Tritium Focus Group (TFG) meeting 23-25 Sept. 2014, Energy Innovation Laboratory Idaho National Laboratory, Idaho Falls, ID Project Team 2 * Jay Gaillard - SRNL/Material Science

  12. Tritium High Vacuum Pump Test Plan

    Office of Environmental Management (EM)

    High Vacuum Pump Test Plan Tritium Programs Engineering Louis Boone Joel Bennett M-TRT-H-00088 Rev 0 Date: 4/10/2014 Tritium Facilities Savannah River Nuclear Solutions, LLC Scope * Comparison of Normetex vs. Eumeca/ Air Squared/ Edwards/ Busch * Ultimate Vacuum * Develop Flow Curve * Provide basis for selecting the Normetex Pump Replacement Performance * Flow Rate - 9 cfm at 3 torr inlet pressure * Ultimate Vacuum Pressure - Acceptable: Less than 0.01 torr at discharge pressure of 30 torr -

  13. PowerPoint Presentation

    Office of Environmental Management (EM)

    Normetex Pump Replacement Tritium Programs Engineering Louis Boone P. J. Foster Tritium Facilities Normetex Pump Alternatives Rev Date: 4-9-13 Savannah River Nuclear Solutions, LLC 2 Objectives * Determine specific pump requirements * Evaluate alternatives to the Normetex pump * Short-term Actions (in-house activities until a new pump is available) * Proposed Path Forward 3 Normetex Background * Normetex is truly a unique pump - the Met-Bel / Normetex pump train provides a hermetically sealed,

  14. Z-Bed Recovery Water Disposal

    Office of Environmental Management (EM)

    Z-Bed Recovery Water Disposal Tritium Programs Engineering Louis Boone Josh Segura Savannah River Nuclear Solutions, LLC M-TRT-H-00087 Rev 0 Date: 4/10/2014 Tritium Facilities Purpose * Provide detailed explanation of the plan to capture and dispose of Z-Bed Recovery (ZR) water. Agenda * New Technology * Background * Z-Bed Recovery Water Disposal * Cost Saving * Alternatives New Technology * Dry Disconnect Fittings * Double Door Transfer Container (DDTC) * Bucket (Stainless Steel ASME pressure

  15. Conversion of Biomass Sugars via Fermentation - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion of Biomass Sugars via Fermentation Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Microorganisms like yeast and Escherichia coli are cultured in labs for many purposes, notably the production of useful chemicals (such as ethanol) via fermentation. The growth media used in these processes are relatively expensive. Cheaper media derived from renewable resources would be a boon to researchers and industries that rely on

  16. 2016 Middle School Science Bowl Participating Teams | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Middle School Science Bowl Participating Teams The following schools will be competing in the 2016 Ames Laboatory/Iowa State University Regional Middle School Science Bowl: Adel-DeSoto-Minburn (Adel) Ames - Team #1 Ames - Team #2 Boone Clarion-Goldfield Eleanor Roosevelt (Dubuque) Glenwood Le Mars Lenox Lynnville-Sully Madrid Melcher-Dallas New Hampton North Union (Swea City) Northwood-Kensett Ogden Pella Shenandoah Southeast Polk (Pleasant Hill) Southeast Valley (Burnside) St. Albert (Council

  17. Radiocarbon (Geochronology)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiocarbon (Geochronology) With regards to geochronology, radiocarbon is both blessed and cursed-the boon is that it is ubiquitous in nature and often we can date the exact carrier of the biogeochemical or paleoclimate proxy that we are studying, including studying the carbon cycle. However, due to the variable production of 14C, and its partitioning between the atmosphere-ocean-land reservoirs, a fundamental tenet of decay-based radioisotope geochronology is invalidated: namely the initial

  18. Supernova Twins: Making Standard Candles More Standard Than Ever

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supernova Twins: Making Standard Candles More Standard Than Ever Supernova Twins: Making Standard Candles More Standard Than Ever New Modeling Method Measures Cosmological Distances With Far Greater Accuracy January 13, 2016 Contact: Paul Preuss, paul_preuss@lbl.gov, +1 415 272 3253 supernovatwins From left, Greg Aldering, Kyle Boone, Hannah Fakhouri and Saul Perlmutter of the Nearby Supernova Factory. Behind them is a poster of a supernova spectrum. Matching spectra among different supernovae

  19. Liquefaction Triggering Evaluations at DOE Sites - An Update | Department

    Office of Environmental Management (EM)

    of Energy Liquefaction Triggering Evaluations at DOE Sites - An Update Liquefaction Triggering Evaluations at DOE Sites - An Update Liquefaction Triggering Evaluations at DOE Sites - An Update 2014 Natural Phenomena Hazards Meeting October 21-22, 2014 Germantown, Maryland Michael R. Lewis, Bechtel Corporation Michael D. Boone, Bechtel Corporation Rucker J. Williams, Savannah River Nuclear Solutions, LLC Brent Gutierrez, U.S. Department of Energy, Savannah River Site PDF icon Liquefaction

  20. EA-1083: Final Environmental Assessment

    Broader source: Energy.gov [DOE]

    New Silt/Clay Source Development and Use at the Idaho National Engineering and Environmental Laboratory

  1. Process for the preparation of organoclays

    DOE Patents [OSTI]

    Chaiko, David J.

    2004-11-23

    A method for preparing organoclays for use as rheological control agents and in the preparation of nanocomposites. Typically, the clay is dispersed in water, and a specific amount of polymeric hydrotrope, ranging from 0.1 to 15 weight percent relative to the weight of the clay, is adsorbed onto the clay surface. Quaternary amine exchange is also performed on the clay to modify the surface hydrophilic/lipophilic balance (HLB) of the clay.

  2. Steering Committee Progress Report on Hydrogen Sensor Performance Testing and Evaluation under the Memorandum of Agreement between NREL, U.S. DOE and JRC-IET, EC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Steering Committee Progress Report on Hydrogen Sensor Performance Testing and Evaluation under the Memorandum of Agreement between NREL, U.S. DOE and JRC-IET, EC W. Buttner, M. Post, R. Burgess, and C. Rivkin National Renewable Energy Laboratory L. Boon-Brett, V. Palmisano, C. Bonato and F. Harskamp Joint Research Centre Institute for Energy and Transport Technical Report NREL/TP-5600-57207 December 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency

  3. Steve Brice FNAL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3/18/03 Steve Brice FNAL Page 1 MiniBooNE Status Steve Brice Fermilab Overview Beam Primary Beam Secondary Beam Detector Calibration Triggering Neutrinos Summary DOE Review 3/18/03 Steve Brice FNAL Page 2 The Collaboration Small experiment ¡ ~60 scientists ¡ 13 institutions The BooNE Collaboration Y.Liu, I.Stancu University of Alabama S.Koutsoliotas Bucknell University E.Church, C.Green, G.J.VanDalen University of California, Riverside E.Hawker, R.A.Johnson, J.L.Raaf University of Cincinnati

  4. 32nd attendees 042313.xlsx

    Office of Environmental Management (EM)

    Lastname Firstname Site Presenting Y/N Presentation Topic Babineau Dave SRNL Y Advances in Design of the Next Generation Hydride Bed Blanton Paul SRNL Y Bulk Tritium Shipping Package Boone Louis SRNL Y Tritium-Compatible Pump Replacement for the Normatex Pump Cabauy Peter City Labs, Inc. N Overview of Tritium Betavoltaic MicroPower for Autonomous Sensors Carter Roger NOAA Caudill Craig FemtoTech Clark Jared SRNL Y Z-Bed Recovery (Glovebox Stripper) Corrosion Cloessner Paul SRNL N Dunlevy Michael

  5. Booster Neutrino Experiment - Introduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    close The MiniBooNE Experiment next The Oscillating Neutrino The first phase of the Booster Neutrino Experiment (BooNE) at the Fermi National Accelerator Laboratory is a smaller version of the final planned experiment, and has been dubbed "MiniBooNE." The physicists working on MiniBooNE are trying to find out more about the fundamental properties of neutrinos. But, what exactly is a neutrino? To answer that question, we need to look at what's called the Standard Model of particles and

  6. Exclusive Neutrino Cross Sections From MiniBooNE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exclusive Neutrino Cross Sections From MiniBooNE Martin Tzanov University of Colorado PANIC 2008, 9-14 November, Eilat, ISRAEL Martin Tzanov, PANIC 2008 Neutrino Cross Sections Today * Precise knowledge needed for precise oscillation measurements. * Cross section well measured above 20 GeV. * Few measurements below 20 GeV. * 20-30 years old bubble chamber experiments (mostly H 2 , D 2 ). * Neutral current cross sections are even less understood. ν CC world data CC world data ν T2K, BooNE K2K,

  7. Embedded image processing engine using ARM cortex-M4 based STM32F407 microcontroller

    SciTech Connect (OSTI)

    Samaiya, Devesh

    2014-10-06

    Due to advancement in low cost, easily available, yet powerful hardware and revolution in open source software, urge to make newer, more interactive machines and electronic systems have increased manifold among engineers. To make system more interactive, designers need easy to use sensor systems. Giving the boon of vision to machines was never easy, though it is not impossible these days; it is still not easy and expensive. This work presents a low cost, moderate performance and programmable Image processing engine. This Image processing engine is able to capture real time images, can store the images in the permanent storage and can perform preprogrammed image processing operations on the captured images.

  8. Jonathan Link, Columbia NuCosmo '02

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7-19, 2002 Jonathan Link, Columbia NuCosmo '02 Jonathan Link Columbia University Workshop on Neutrino News from the Lab and the Cosmos October 17-19, 2002 October 17-19, 2002 Jonathan Link, Columbia NuCosmo '02 Outline 1. The LSND Experiment a. The experimental setup b. Results c. Ramifications 2. MiniBooNE a. The BooNE Collaboration b. The beam line and expected neutrino flux c. The MiniBooNE detector d. Expected backgrounds and systematics e. First neutrino events, and cosmic rays f.

  9. Kaon Monitoring in MiniBooNE: The LMC Detector E. D. Zimmerman

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kaon Monitoring in MiniBooNE: The LMC Detector E. D. Zimmerman University of Colorado NBI 2003 KEK, Tsukuba November 10, 2003 Kaon Monitoring at MiniBooNE 1) K-decay ν e background at BooNE K production estimates 2) Decay kinematics 3) The "Little Muon Counter" (LMC) Concept/Placement Civil construction/infrastructure Collimator Fiber Tracker Temporary detector Status K-decay ν e background MiniBooNE will see ~200-400 ν e from K + and K 0 L decays each year -- comparable to the

  10. LE & ME n Highlights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

     and   Disappearance W.C. Louis, DNP Conference, October 16, 2009 * MiniBooNE Appearance Results (talk by Zarko Pavlovic) * MiniBooNE Disappearance Results * Global 3+1 Fits to World Data * Preliminary MINOS Experiments * Future Experiment: BooNE (talk by Geoff Mills) * Conclusions MiniBooNE observes a low-energy excess for  e appearance MiniBooNE  e appearance data show a low-energy excess A.A. Aguilar-Arevalo et al., PRL 102, 101802 (2009) MiniBooNE  e appearance data are

  11. Michel Sorel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Michel Sorel (Columbia University) for the MiniBooNE Collaboration NFWG Seminar, CERN, August 2002 1 Outline * Introduction: MiniBooNE and the BooNE beam * MiniBooNE horn: physics motivations * Design of the horn, striplines, power supply, horn cooling * Highlights of horn construction and assembly * Horn testing at the test facility * Horn installation at the target hall * Horn changeover (if needed. . .) and radioactive horn handling 2 The MiniBooNE Experiment * MiniBooNE: Fermilab experiment

  12. Growth in Solar Means Growth in Ohio | Department of Energy

    Office of Environmental Management (EM)

    Growth in Solar Means Growth in Ohio Growth in Solar Means Growth in Ohio October 6, 2010 - 2:26pm Addthis Lorelei Laird Writer, Energy Empowers Editor's Note: Yesterday Secretary Chu announced that solar panels and a solar hot water heater will be added to the White House by the end of next spring. This entry is cross-posted from the Energy Empowers blog and deals with how the continued growth of solar power is not only a boon for industry, but for local economies as well. The solar industry

  13. Secretary Moniz: What the Natural Gas Boom Means for the Future of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewables | Department of Energy Moniz: What the Natural Gas Boom Means for the Future of Renewables Secretary Moniz: What the Natural Gas Boom Means for the Future of Renewables May 23, 2013 - 2:34pm Addthis In a town hall meeting with Department employees, Secretary of Energy Ernest Moniz talks about how a boom in natural gas might be a boon for renewable energy. Dan Leistikow Dan Leistikow Former Director, Office of Public Affairs More from Secretary Moniz See a video recap of Secretary

  14. International Collaborations on Engineered Barrier Systems: Experiment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1) HE-E Heater Test - Studies of bentoniterock interaction to evaluate sealing and clay ... heating conditions and interaction with the clay host rock, at Horonobe URL in Japan. ...

  15. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    approval, Wind (Small), Anaerobic Digestion, Fuel Cells using Renewable Fuels, Other Distributed Generation Technologies Clay Electric Cooperative, Inc- Energy Conservation...

  16. On the structural stability and catalytic properties of smectities pillared with RE-Al, Al-Ga polyoxications

    SciTech Connect (OSTI)

    Caballero, L.; Dominguez, J.M.; De los Santos, J.L.

    1995-12-01

    Pillaring of Smectite type clays offers the possibility to develop highly porous catalytic materials with surface acid properties, (1) their me in hydrotreating and FCC hydrocarbon processes has been extensively discussed (2) and still some research on the stabilization of the clays structure is being carried out. Therefore, the aim of the present work was to investigate thermal stability of Montmorillonite type clays, by means of pillaring with distinct polyoxications and by ion-exchanging and treating the clays under several conditions.

  17. Process for the preparation of organoclays

    DOE Patents [OSTI]

    Chaiko, David J. (Naperville, IL)

    2003-01-01

    A method for preparing organoclays from smectites for use as rheological control agents and in the preparation of nanocomposites. Typically, the clay is dispersed in water, and a substantially monomolecular layer of a water soluble polymer is applied to the surfaces of the clay. A surfactant is also applied to the clay to modify the surface hydrophilic/hydrophobic balance of the clay, and the organoclay is separated out for subsequent use.

  18. ARM - Measurement - Soil characteristics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement : Soil characteristics Includes available water capacity, bulk density, permeability, porosity, rock fragment classification, rock fragment volume, percent clay,...

  19. Method of preparation of a CO.sub.2 removal sorbent with high chemical stability during multiple cycles

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.; Rosencwaig, Shira

    2015-07-14

    Method for the production of a clay-alkali-amine CO.sub.2 sorbent prepared by integrating a clay substrate, basic alkali salt, and amine liquid. The basic alkali salt is present relative to the clay substrate in a weight ratio of from about 1 part to about 50 parts per 100 parts of the clay substrate. The amine liquid is present relative to a clay-alkali combination in a weight ratio of from about 1 part to about 10 parts per 10 parts of the clay-alkali combination. The clay substrate and basic alkali salt may be combined in a solid-solid heterogeneous mixture and followed by introduction of the amine liquid. Alternatively, an alkaline solution may be blended with the amine solution prior to contacting the clay substrate. The clay-alkali-amine CO.sub.2 sorbent is particularly advantageous for low temperature CO.sub.2 removal cycles in a gas stream having a CO.sub.2 concentration less than around 2000 ppm and an oxygen concentration around 21%, such as air. Results are presented illustrating the performance of the clay-alkali-amine CO.sub.2 sorbent compared to a clay-amine sorbent lacking the alkali inclusion.

  20. CO.sub.2 removal sorbent composition with high chemical stability during multiple cycles

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.; Rosencwaig, Shira

    2015-09-22

    Disclosed herein is a clay-alkali-amine CO.sub.2 sorbent composition prepared by integrating a clay substrate, basic alkali salt, and amine liquid. The basic alkali salt is present relative to the clay substrate in a weight ratio of from about 1 part to about 50 parts per 100 parts of the clay substrate. The amine liquid is present relative to a clay-alkali combination in a weight ratio of from about 1 part to about 10 parts per 10 parts of the clay-alkali combination. The clay-alkali-amine C02 sorbent is particularly advantageous for low temperature CO.sub.2 removal cycles in a gas stream having a C02 concentration less than around 2000 ppm and an oxygen concentration around 21%, such as air.

  1. Polyolefin nanocomposites

    DOE Patents [OSTI]

    Chaiko, David J.

    2007-01-02

    The present invention relates to methods for the preparation of clay/polymer nanocomposites. The methods include combining an organophilic clay and a polymer to form a nanocomposite, wherein the organophilic clay and the polymer each have a peak recrystallization temperature, and wherein the organophilic clay peak recrystallization temperature sufficiently matches the polymer peak recrystallization temperature such that the nanocomposite formed has less permeability to a gas than the polymer. Such nanocomposites exhibit 2, 5, 10, or even 100 fold or greater reductions in permeability to, e.g., oxygen, carbon dioxide, or both compared to the polymer. The invention also provides a method of preparing a nanocomposite that includes combining an amorphous organophilic clay and an amorphous polymer, each having a glass transition temperature, wherein the organophilic clay glass transition temperature sufficiently matches the polymer glass transition temperature such that the nanocomposite formed has less permeability to a gas than the polymer.

  2. Carbons for lithium batteries prepared using sepiolite as an inorganic template

    DOE Patents [OSTI]

    Sandi, Giselle (Wheaton, IL); Winans, Randall E. (Downers Grove, IL); Gregar, K. Carrado (Naperville, IL)

    2000-01-01

    A method of preparing an anode material using sepiolite clay having channel-like interstices in its lattice structure. Carbonaceous material is deposited in the channel-like interstices of the sepiolite clay and then the sepiolite clay is removed leaving the carbonaceous material. The carbonaceous material is formed into an anode. The anode is combined with suitable cathode and electrolyte materials to form a battery of the lithium-ion type.

  3. Synthesis and structural characterization of ferrous trioctahedral

    Office of Scientific and Technical Information (OSTI)

    smectites: Implications for clay mineral genesis and detectability on Mars (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Synthesis and structural characterization of ferrous trioctahedral smectites: Implications for clay mineral genesis and detectability on Mars Citation Details In-Document Search Title: Synthesis and structural characterization of ferrous trioctahedral smectites: Implications for clay mineral genesis and detectability on Mars Authors:

  4. Using electrical impedance tomography to map subsurface hydraulic conductivity

    DOE Patents [OSTI]

    Berryman, James G.; Daily, William D.; Ramirez, Abelardo L.; Roberts, Jeffery J.

    2000-01-01

    The use of Electrical Impedance Tomography (EIT) to map subsurface hydraulic conductivity. EIT can be used to map hydraulic conductivity in the subsurface where measurements of both amplitude and phase are made. Hydraulic conductivity depends on at least two parameters: porosity and a length scale parameter. Electrical Resistance Tomography (ERT) measures and maps electrical conductivity (which can be related to porosity) in three dimensions. By introducing phase measurements along with amplitude, the desired additional measurement of a pertinent length scale can be achieved. Hydraulic conductivity controls the ability to flush unwanted fluid contaminants from the surface. Thus inexpensive maps of hydraulic conductivity would improve planning strategies for subsequent remediation efforts. Fluid permeability is also of importance for oil field exploitation and thus detailed knowledge of fluid permeability distribution in three-dimension (3-D) would be a great boon to petroleum reservoir analysts.

  5. 8. R. Q8tavaoa, Chlei, Aooouatability Branoh,

    Office of Legacy Management (LM)

    . R. Q8tavaoa, Chlei, Aooouatability Branoh, Ptodu@tlzm D¶tioi oa Ilr 1% w!% 3, ?. o8nrig110, ahior, Mudlo0.x 8anlpllnQ Plan4 T'RM8pBR OP MXDDIBm XHVBNTORY 01 SF yU'R:'W8 * Ilr; you Imaw, Mlddlsaex alaae-out plana oall for the tranrfer out of a11 l f and 0-r rkrlrlr rhiah krvo boon hold in rtora@. TheLlr+r portion of there abarials arm to k Wanaferrod bo lhwnald for l torrgo and ultirta dirporitioa thonfrar. C&w plum for rfaooountxbility~trolo~~ thlr mrfer rretdhavm United had C~panymako a

  6. TR1P~TTOUPQIH?RurJn#ll

    Office of Legacy Management (LM)

    * - - I 1' MP .b-/ j3 4 -/-5 +,' *i Q-/-k 9 July 13, l9S4 w-0 TR1P~TTOUPQIH?RurJn#ll JULY 9, 2956 Tooe~AHY,MID8ow,--~ J. A. Q&by, M.D. P. w. Boone ObJectin of TrAq ~vRlrpouofvi8itin@~c~~toaaln4uct8~~iea nuvey am eqaQm8t preTieuo&y llud 8y a0 per8aaaelua 8 teat tith tuudm neta&, aad to wperriu th8 brcaetrrlnitioa of th3.8 u@p- arcpIt if mewmry. cc*scm m Recwtiaao ml8 8quQMat iuvelmd (aw tmm&ing aachine mId au u8or prerr) rerdth8 lwrrrpdky ueauerc fotadtok 4mlyv8w&ightlr

  7. 3.27 Why Dinosaurs Are Extinct

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Walter Alvarez discovered a layer of red clay between fossil- containing limestone deposits in Italy. His father, Nobel laureate Luis Alvarez, suggested how to analyze it. ...

  8. Bi-Con Services Inc | Open Energy Information

    Open Energy Info (EERE)

    Services Inc Jump to: navigation, search Name: Bi-Con Services Inc Address: 10901 Clay Pike Road Place: Derwent, Ohio Zip: 43733 Sector: Buildings, Efficiency, Services Product:...

  9. U.S. and Mongolia Sign MOU to Increase Cooperation in Preventing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    WASHINGTON, DC - Today the governments of the United States and Mongolia strengthened their efforts in the fight against nuclear terrorism. U.S. Deputy Secretary of Energy Clay ...

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Additional data provided by the FTIR study is that CO2 intercalation into clays, if it ... viscosity quench experiments, and FTIR. Both the viscosity quench experiments and ...

  11. Moeck-Beardsmore Play Types | Open Energy Information

    Open Energy Info (EERE)

    Magmatic-hydrothermal Circulation --- Extensive Low Permeability Clay-rich Layers Java CV-1b: Intrusive Magmatic Arcs, Mid Oceanic Ridges, Hot Spots Active Volcanism, Shallow...

  12. New hydrogen-isotope measurements refine the picture of water on Mars

    SciTech Connect (OSTI)

    Wilson, R. Mark

    2015-05-15

    Atmospheric maps and in situ spectrometry of clay minerals constrain climate models and the prevalence of water in the planets ancient past.

  13. Model Evaluation of the Thermo-Hydrological Response in Argillaceous...

    Office of Scientific and Technical Information (OSTI)

    of Publication: United States Language: English Subject: 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS Dual-purpose canister, dispoal, clay Word Cloud More Like This Full Text...

  14. TRU TeamWorks 7-7-11

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    have a daughter, Jennifer, and a son, Jason. They also have three grandchildren, Clay, Logan and Kyle. David Hoffer- Budget Analyst David Hoffer handles budget formulation and...

  15. Modeling Fluid Flow in Natural Systems, Model Validation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modeling Fluid Flow in Natural Systems, Model Validation and Demonstration Clay and granitic units are potential host media for future repositories for used nuclear fuel. The ...

  16. CO2 interaction with geomaterials. (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    of Publication: United States Language: English Subject: 01 COAL, LIGNITE, AND PEAT; 03 NATURAL GAS; BOILING POINTS; CATIONS; CLATHRATES; CLAYS; COAL; COMPUTERIZED SIMULATION;...

  17. Microsoft Word - FFATA Memo 30 March 2007.doc

    Broader source: Energy.gov (indexed) [DOE]

    MEMORANDUM FOR THE PRESIDENT'S MANAGEMENT COUNCIL From: Clay Johnson Deputy Director for Management Subject: Reporting of Data Elements Required by the Federal Funding...

  18. Agassiz Beach Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Scale Wind Facility Status In Service Owner NAEEnel North America Developer Northern Alternative Energy Energy Purchaser Xcel Energy Location Clay County MN Coordinates...

  19. An Investigation for Disposal of Drill Cuttings into Unconsolidated...

    Office of Scientific and Technical Information (OSTI)

    Subject: 02 PETROLEUM; DRILLING FLUIDS; MINERAL WASTES; ROCK MECHANICS; SANDSTONES; CLAYS; DISPOSAL WELLS; ABANDONED WELLS; GROUND WATER; WATER POLLUTION CONTROL; WASTE MANAGEMENT ...

  20. Synthesis and structural characterization of ferrous trioctahedral...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Synthesis and structural characterization of ferrous trioctahedral smectites: Implications for clay mineral genesis and ...

  1. Update On Geothermal Exploration At Fort Bidwell, Surprise Valley...

    Open Energy Info (EERE)

    awaits clean-out and testing activities. Authors Joe LaFleur, Anna Carter, Karen Moore, Ben Barker, Paul Atkinson, Clay Jones, Joseph Moore and Bernold Pollard Published...

  2. Petrography Analysis At Raft River Geothermal Area (2011) | Open...

    Open Energy Info (EERE)

    flows, tuffaceous siltstone, greywacke, and sandstone. References Clay Jones, Joseph Moore, William Teplow, Seth Craig (2011) Geology and Hydrothermal Alteration of the Raft...

  3. Thermal Gradient Holes At Fort Bidwell Area (Lafleur, Et Al....

    Open Energy Info (EERE)

    continue exploration when funding allows." References Joe LaFleur, Anna Carter, Karen Moore, Ben Barker, Paul Atkinson, Clay Jones, Joseph Moore, Bernold Pollard (2010) Update On...

  4. An Investigation for Disposal of Drill Cuttings into Unconsolidated...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 02 PETROLEUM; DRILLING FLUIDS; MINERAL WASTES; ROCK MECHANICS; SANDSTONES; CLAYS; DISPOSAL WELLS; ABANDONED WELLS; ...

  5. Other Requirements - DOE Directives, Delegations, and Requirements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assurance WT - Office of Industrial Relations Issue Date Start date End date Signatory Clay Sell Daniel B. Poneman Ernest J. Moniz None Owen F. Barwell, Acting Chief Financial...

  6. Agenda

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (High Resolution Global Coupled Ocean SeaIce Modeling) Gary Sposito, LBNLUC Berkeley (Clay Mineral Surface Geochemistry) John Bell, LBNLNERSC (Applied Partial Differential...

  7. Controls on Fault-Hosted Fluid Flow: Preliminary Results from...

    Open Energy Info (EERE)

    Flow: Preliminary Results from the Coso Geothermal Field, CA Abstract cap rock, permeability, fault, fracture, clay, Coso Authors Davatzes, N.C.; Hickman and S.H. Published...

  8. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Cooperative, Inc- Energy Conservation Loans Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 North Florida counties, including Gainesville,...

  9. Property:CapRockLithology | Open Energy Information

    Open Energy Info (EERE)

    + Hydrothermal alteration layer + Bouillante Geothermal Area + Illite-Smectite Clay + Brady Hot Springs Geothermal Area + Hydrothermally altered volcanics + C Cerro Prieto...

  10. Evaluation of Generic EBS Design Concepts and Process Models Implications to EBS Design Optimization

    Broader source: Energy.gov [DOE]

    The assessment of generic EBS concepts and design optimization to harbor various disposal configurations and waste types needs advanced approaches and methods to analyze barrier performance. The report addresses: 1) Overview of the importance of THMC processes to barrier performance, and international collaborations; 2) THMC processes in clay barriers; 3) experimental studies of clay stability and clay-metal interactions at high temperatures and pressures; 4) thermodynamic modeling and database development; 5) Molecular Dynamics (MD) study of clay hydration at ambient and elevated temperatures; and 6) coupled thermal-mechanical (TM) and thermo-hydrological (TH) modeling in salt.

  11. NREL Announces Participants in the National Executive Education...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Professor of Professional Practice in Finance, Energy Policy and Sustainability ... Market Talent Director Workforce Development Agency, State of Michigan Clay Butler, ...

  12. University of Alaska Fairbanks | Department of Energy

    Energy Savers [EERE]

    Team roster: Clay Allen, Mechanical Engineering; Elisha Dalbec, Mechanical Engineering; Jessica Garvin, Mechanical Engineering; Matthew Pacheco, Mechanical Engineering; Adam Becia, Mechanical Engineering; Daniel Poesy, Mechanical Engineering; Taylor Roth, Mechanical Engineering; Alex Mitchell, Mechanical Engineering; Isaac Lammers, Mechanical Engineering; Dalton Newbrough, Mechanical Engineering Team roster: Clay Allen, Mechanical Engineering; Elisha Dalbec, Mechanical Engineering; Jessica

  13. Surface decontamination compositions and methods

    DOE Patents [OSTI]

    Wright; Karen E.; Cooper, David C.; Peterman, Dean R.; Demmer, Ricky L.; Tripp, Julia L.; Hull, Laurence C.

    2011-03-29

    Clay-based compositions capable of absorbing contaminants from surfaces or objects having surface faces may be applied to a surface and later removed, the removed clay-based compositions absorbing at least a portion of the contaminant from the surface or object to which it was applied.

  14. Seismic Velocities Contain Information About Depth, Lithology, Fluid Content, and Microstructure

    SciTech Connect (OSTI)

    Berge, P A; Bonner, B P

    2002-01-03

    Recent advances in field and laboratory methods for measuring elastic wave velocities provide incentive and opportunity for improving interpretation of geophysical data for engineering and environmental applications. Advancing the state-of-the-art of seismic imaging requires developing petrophysical relationships between measured velocities and the hydrogeology parameters and lithology. Our approach uses laboratory data and rock physics methods. Compressional (Vp) and shear (Vs) wave velocities, Vp/Vs ratios, and relative wave amplitudes show systematic changes related to composition, saturation, applied stress (analogous to depth), and distribution of clay for laboratory ultrasonic measurements on soils. The artificial soils were mixtures of Ottawa sand and a second phase, either Wyoming bentonite or peat moss used to represent clay or organic components found in natural soils. Compressional and shear wave velocities were measured for dry, saturated, and partially-saturated conditions, for applied stresses between about 7 and 100 kPa, representing approximately the top 5 m of the subsurface. Analysis of the results using rock physics methods shows the link between microstructure and wave propagation, and implications for future advances in seismic data interpretation. For example, we found that Vp in dry sand-clay mixtures initially increases as clay cements the sand grains and fills porosity, but then Vp decreases when the clay content is high enough that the clay matrix controls the elastic response of the material. Vs decreases monotonically with increasing clay content. This provides a method for using Vp/Vs ratios to estimate clay content in a dry soil.

  15. Natural materials for carbon capture.

    SciTech Connect (OSTI)

    Myshakin, Evgeniy M.; Romanov, Vyacheslav N.; Cygan, Randall Timothy

    2010-11-01

    Naturally occurring clay minerals provide a distinctive material for carbon capture and carbon dioxide sequestration. Swelling clay minerals, such as the smectite variety, possess an aluminosilicate structure that is controlled by low-charge layers that readily expand to accommodate water molecules and, potentially, carbon dioxide. Recent experimental studies have demonstrated the efficacy of intercalating carbon dioxide in the interlayer of layered clays but little is known about the molecular mechanisms of the process and the extent of carbon capture as a function of clay charge and structure. A series of molecular dynamics simulations and vibrational analyses have been completed to assess the molecular interactions associated with incorporation of CO2 in the interlayer of montmorillonite clay and to help validate the models with experimental observation.

  16. Process for preparing organoclays for aqueous and polar-organic systems

    DOE Patents [OSTI]

    Chaiko, David J. (Naperville, IL)

    2001-01-01

    A process for preparing organoclays as thixotropic agents to control the rheology of water-based paints and other aqueous and polar-organic systems. The process relates to treating low-grade clay ores to achieve highly purified organoclays and/or to incorporate surface modifying agents onto the clay by adsorption and/or to produce highly dispersed organoclays without excessive grinding or high shear dispersion. The process involves the treatment of impure, or run-of-mine, clay using an aqueous biphasic extraction system to produce a highly dispersed clay, free of mineral impurities and with modified surface properties brought about by adsorption of the water-soluble polymers used in generating the aqueous biphasic extraction system. This invention purifies the clay to greater than 95%.

  17. Natural-analog studies for partial validation of conceptual models of radionuclide retardation at the Waste Isolation Pilot Plant (WIPP)

    SciTech Connect (OSTI)

    Ward, D.B.; Brookins, D.G. . Dept. of Geology); Siegel, M.D.; Lambert, S.J. )

    1990-01-01

    Transport by groundwater within the Culebra Dolomite, an aquifer above the Waste Isolation Pilot Plant (WIPP), is the most probable mechanism for long-term release of radionuclides to the accessible environment. Radionuclides could be retarded by sorption if the groundwater is exposed to sufficient amounts of fracture-lining clays. In this natural-analog study, distributions of U and trace metals have been examined to constrain the strength of clay/solute interactions within the Culebra. Uranium solid/liquid distribution ratios, calculated from U concentrations of groundwaters and consanguineous fracture-filling clays, range from {approximately}80 to 800 m{ell}/g and imply retardation factors of 60 to 500 using a fracture-flow model. Retardation factors inferred from uranium-series disequilibria and {sup 14}C ages in Culebra groundwaters alone are much lower ({approximately}10), implying that clays may contain a significant unreactive component of U. Such a possibility is corroborated by Rb/Sr ages; these imply long-term stability of the clays,with resetting occurring more than 250 Ma ago. Factor analysis and mass-balance calculations suggest, however, that Mg-rich clays are dissolving in Pleistocene-age groundwaters and/or are converting to Na-rich smectites, and that B and Li are taken up from the water by the clays. Apparently, the solution chemistry reflects gradual equilibration of clays with groundwater, but thus far the bulk of the clays remain structurally intact. Measurements of the distribution of U in the Culebra will be more meaningful if the inert and exchangeable components of the U content of the clays can be quantified. 26 refs., 3 figs., 2 tabs.

  18. Brick manufacture with fly ash from Illinois coals. Quarterly technical report, September 1, 1994--November 30, 1994

    SciTech Connect (OSTI)

    Hughes, R.E.; Dreher, G.; Frost, J.; Moore, D.; Rostam-Abadi, M.; Fiocchi, T.; Swartz, D.

    1995-03-01

    This investigation seeks to utilize fly ash in fired-clay products such as building and patio bricks, ceramic blocks, field and sewer tile, and flower pots. This goal is accomplished by (1) one or more plant-scale, 5000-brick tests with fly ash mixed with brick clays at the 20% or higher level; (2) a laboratory-scale study to measure the firing reactions of a range of compositions of clay and fly ash mixtures; (3) a technical and economic study to evaluate the potential environmental and economic benefits of brick manufacture with fly ash. Bricks and feed materials will be tested for compliance with market specifications and for leachability of pollutants derived from fly ash. The laboratory study will combine ISGS databases, ICCI-supported characterization methods, and published information to improve predictions of the firing characteristics of Illinois fly ash and brick clay mixtures. Because identical methods are used to test clay firing and coal ash fusion, and because melting mechanisms are the same, improved coal ash fusion predictions are an expected result of this research. If successful, this project should convert an environmental problem (fly ash) into valuable products - bricks. During this quarter, the authors set up the manufacturing run at Colonial Brick Co., provided an expanded NEPA questionnaire for DOE, made preliminary arrangements for a larger brick manufacturing run at Marseilles Brick Co., revised laboratory procedures for selective dissolution analysis, and began characterization of brick clays that could be mixed with fly ash for fired-clay products.

  19. Kaolinization in examples of Carboniferous and Cretaceous tonsteins

    SciTech Connect (OSTI)

    McCuistion, J.T.; Ambers, C.P. . Dept. of Geological Science)

    1993-03-01

    Optical and electron petrography were used to test if differences of mineral textures in tonsteins offer any evidence of the alteration history of their volcanic precursors. A suspect tonstein from the Mississippian Sample fm. In Crawford County, IN, and true tonsteins from the Pennsylvanian Breathitt Fm. in Leslie County, KY; Cretaceous Adaville Fm. in Lincoln County, WY; and the Cretaceous Williams Fork Fm. in Moffat and Routt Counties, CO were studied. Optical petrography showed lack of silt or sand in the Indiana clay, minor silt/fine-sand in the Kentucky clay, and lack of mica in both. The Indiana clay is very fine grained and has a strong preferred orientation, whereas the Kentucky clay matrix is also very fine grained but is isotropic. Abundant, angular, quartzofeldspathic, medium sand abounds in the western clays. Very large kaolinite verms up to 0.5 mm in length dominate the western clays. Each large kaolinite contains evenly spaced interlayers of relict biotite extending exactly the width of each verm. Kaolinite in the western clays shows strong compactional strain including undulose extinction, kink bands, and shearing along the basal plane. Compactional fabrics show all of the samples to have altered from their parent material before significant burial.

  20. Studying methane migration mechanisms at Walker Ridge, Gulf of Mexico, via 3D methane hydrate reservoir modeling

    SciTech Connect (OSTI)

    Nole, Michael; Daigle, Hugh; Mohanty, Kishore; Cook, Ann; Hillman, Jess

    2015-12-15

    We have developed a 3D methane hydrate reservoir simulator to model marine methane hydrate systems. Our simulator couples highly nonlinear heat and mass transport equations and includes heterogeneous sedimentation, in-situ microbial methanogenesis, the influence of pore size contrast on solubility gradients, and the impact of salt exclusion from the hydrate phase on dissolved methane equilibrium in pore water. Using environmental parameters from Walker Ridge in the Gulf of Mexico, we first simulate hydrate formation in and around a thin, dipping, planar sand stratum surrounded by clay lithology as it is buried to 295mbsf. We find that with sufficient methane being supplied by organic methanogenesis in the clays, a 200x pore size contrast between clays and sands allows for a strong enough concentration gradient to significantly drop the concentration of methane hydrate in clays immediately surrounding a thin sand layer, a phenomenon that is observed in well log data. Building upon previous work, our simulations account for the increase in sand-clay solubility contrast with depth from about 1.6% near the top of the sediment column to 8.6% at depth, which leads to a progressive strengthening of the diffusive flux of methane with time. By including an exponentially decaying organic methanogenesis input to the clay lithology with depth, we see a decrease in the aqueous methane supplied to the clays surrounding the sand layer with time, which works to further enhance the contrast in hydrate saturation between the sand and surrounding clays. Significant diffusive methane transport is observed in a clay interval of about 11m above the sand layer and about 4m below it, which matches well log observations. The clay-sand pore size contrast alone is not enough to completely eliminate hydrate (as observed in logs), because the diffusive flux of aqueous methane due to a contrast in pore size occurs slower than the rate at which methane is supplied via organic methanogenesis. Therefore, it is likely that additional mechanisms are at play, notably bound water activity reduction in clays. Three-dimensionality allows for inclusion of lithologic heterogeneities, which focus fluid flow and subsequently allow for heterogeneity in the methane migration mechanisms that dominate in marine sediments at a local scale. Incorporating recently acquired 3D seismic data from Walker Ridge to inform the lithologic structure of our modeled reservoir, we show that even with deep adjective sourcing of methane along highly permeable pathways, local hydrate accumulations can be sourced either by diffusive or advective methane flux; advectively-sourced hydrates accumulate evenly in highly permeable strata, while diffusively-sourced hydrates are characterized by thin strata-bound intervals with high clay-sand pore size contrasts.

  1. BPA-2011-01832-FOIA Correspondence

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3, 2011 In reply refer to: DK-7 Clay Hebenton AP Wireless Infrastructure Partners 5703 Oberlin Drive., Suite 308 San Diego, CA 92121 FOIA BPA-2011-01832-F Dear Mr. Hebenton: Thank...

  2. CX-001271: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Energy Efficiency RetrofitsCX(s) Applied: B2.5, B5.1Date: 11/30/2009Location(s): Clay, MissouriOffice(s): Energy Efficiency and Renewable Energy

  3. Core Analysis | Open Energy Information

    Open Energy Info (EERE)

    Area 1992 K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New Mexico And Their Relation To Alteration In A Large Hydrothermal System Core Analysis At...

  4. Structure and function of subsurface microbial communities affecting radionuclide transport and bio-immobilization

    SciTech Connect (OSTI)

    Stucki, Joseph William

    2013-05-13

    The purpose of this study was to provide comparative information regarding the changes in clay structure that occur due to biotic or abiotic reduction, as probed by variable-temperature Mössbauer spectroscopy.

  5. Argillic-Advanced Argillic Alteration | Open Energy Information

    Open Energy Info (EERE)

    clay minerals. Advanced Argillic alteration forms at higher temperatures and lower pH conditions (e.g. the acid-steam condensate zone of a hydrothermal system). It consists...

  6. Quadrennial Technology Review 2015

    Broader source: Energy.gov (indexed) [DOE]

    program supported improvements in this technology, such as the use of nano-clay for next-generation HVDC cables. A research emphasis is also needed on superconducting HVDC cables,...

  7. Integrated hydrogeological model of the general separations area. Volume 2: groundwater flow model

    SciTech Connect (OSTI)

    Flach, G.P.; Harris, M.K.

    1997-08-01

    This report models the Gordon aquifer, the Gordon confining unit, and the `lower` aquifer zone, `tan clay` confining zone, and `upper` aquifer zone of the Water Table aquifer. The report presents structure-contour and isopach maps of each unit.

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    fuel cycle and fuel materials (2) radioactive wastes (2) sensitivity (2) simulation (2) water (2) arsenic (1) bentonite (1) boom clay (1) brine leakage (1) brines (1) buffers (1)...

  9. Strategic Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Clay Dillingham (505) 667-7814 Email Actinide Research Quarterly Susanne King (505) 667-4421 Email Connections Newsletter Ute Haker (505) 665-9871 Email AlumniLink...

  10. Ottawa County, Ohio: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Ohio Clay Center, Ohio Elmore, Ohio Genoa, Ohio Marblehead, Ohio Oak Harbor, Ohio Port Clinton, Ohio Put-in-Bay, Ohio Rocky Ridge, Ohio Retrieved from "http:en.openei.org...

  11. Microsoft Word - LL-WM08 Paper 8351.doc

    Broader source: Energy.gov (indexed) [DOE]

    Tests on Geosynthetic Clay Liners Subjected to Differential Settlement," MS Thesis, Univ. of Texas, Austin, TX (1992). 25. W.J. WAUGH, G.M. SMITH, D.BERGMAN-TABBERT, and...

  12. Microsoft Word - LL-White Paper Prac_Improve_Perform.doc

    Broader source: Energy.gov (indexed) [DOE]

    tests on geosynthetic clay liners subjected to differential settlement. MS Thesis, Univ. of Texas, Austin, TX. Lapham, S.C., J.B. Millard, and J.M. Samet, 1989. "Health...

  13. Department Of Energy Offers $60 Million to Spur Industry Engagement...

    Broader source: Energy.gov (indexed) [DOE]

    WASHINGTON, DC - The U.S. Department of Energy (DOE) Deputy Secretary Clay Sell today announced that DOE will provide up to 60 million, over two years (FY'07-'08), to engage...

  14. Underground waste barrier structure

    DOE Patents [OSTI]

    Saha, Anuj J. (Hamburg, NY); Grant, David C. (Gibsonia, PA)

    1988-01-01

    Disclosed is an underground waste barrier structure that consists of waste material, a first container formed of activated carbonaceous material enclosing the waste material, a second container formed of zeolite enclosing the first container, and clay covering the second container. The underground waste barrier structure is constructed by forming a recessed area within the earth, lining the recessed area with a layer of clay, lining the clay with a layer of zeolite, lining the zeolite with a layer of activated carbonaceous material, placing the waste material within the lined recessed area, forming a ceiling over the waste material of a layer of activated carbonaceous material, a layer of zeolite, and a layer of clay, the layers in the ceiling cojoining with the respective layers forming the walls of the structure, and finally, covering the ceiling with earth.

  15. EI Summary of SIC 24

    U.S. Energy Information Administration (EIA) Indexed Site

    Lumber (24) All (20-39) Food (20) Textiles (22) Apparel (23) Furniture (25) Paper (26) Printing (27) Chemicals (28) Refineries (29) Rubber (30) Stone, Clay & Glass(32) Primary...

  16. Cone Penetrometer N Factor Determination Testing Results

    SciTech Connect (OSTI)

    Follett, Jordan R.

    2014-03-05

    This document contains the results of testing activities to determine the empirical 'N Factor' for the cone penetrometer in kaolin clay simulant. The N Factor is used to releate resistance measurements taken with the cone penetrometer to shear strength.

  17. Natural Gas Weekly Update, Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    In order to avoid an OFO, Northwest will use its limited storage flexibility at Jackson Prairie and Clay Basin to offset possible OFOs at the Kemmerer station by withdrawing...

  18. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    In order to avoid an OFO, Northwest will use its limited storage flexibility at Jackson Prairie and Clay Basin to offset possible OFOs at the Kemmerer station by withdrawing...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Monday, March 29. Questar Pipeline issued a reminder to customers that a reservoir test at its Clay Basin storage facility in Utah began on Wednesday, March 24 and is expected...

  20. Core Analysis At Yellowstone Region (Sturchio, Et Al., 1990)...

    Open Energy Info (EERE)

    were 43 hydrothermal minerals (silica, clay and calcite) from Yellowstone drill cores Y-5, Y-6, Y-7, Y-8, Y-11, Y-12, and Y-13 (Fig. 1). References N. C. Sturchio, T. E. C....

  1. Fluid Flow Model Development for Representative Geologic Media

    Broader source: Energy.gov [DOE]

    Clay and granitic geologic rock units are potential host media for future repositories for used nuclear fuel and high level waste. This report addresses the representation of flow in these two media within numerical process (discrete fracture network) models.

  2. SSRL HEADLINES July 2007

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of ancient pottery. Here, Sciau holds a replica of the clay pots. Call it old-school outsourcing - more than 2,000 years ago, the Roman Empire exploited the labor of artisans in...

  3. TTW 3-17-11

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    crash analyses with clay pots. "It's nice to be able to go out in the community and teach these kids about science and engineering," said Norbert Rempe, W IPP principal...

  4. Shale Reservoir Characterization

    Broader source: Energy.gov [DOE]

    Gas-producing shales are predominantly composed of consolidated clay-sized particles with a high organic content. High subsurface pressures and temperatures convert the organic matter to oil and...

  5. EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate...

    Office of Environmental Management (EM)

    and recommendation. Conclusions: 1. Nitrate salts not yet remediated having no free liquid should be mixed with at least 1.2 volumes of Kitty LitterZeolite clay per...

  6. Extruded ceramic honeycomb and method

    DOE Patents [OSTI]

    Day, J. Paul (Big Flats, NY)

    1995-04-04

    Extruded low-expansion ceramic honeycombs comprising beta-spodumene solid solution as the principal crystal phase and with less than 7 weight percent of included mullite are produced by compounding an extrusion batch comprising a lithium aluminosilicate glass powder and a clay additive, extruding a green honeycomb body from the batch, and drying and firing the green extruded cellular honeycomb to crystallize the glass and clay into a low-expansion spodumene ceramic honeycomb body.

  7. Results of the measurement survey of elevation and environmental media in surface impoundments 3513 (B) and 3524 (A) at Oak Ridge National Laboratory, Oak Ridge, TN

    SciTech Connect (OSTI)

    Murray, M.E.; Rose, D.A.; Brown, K.S.; Coe, R.H.C. III; Lawrence, J.D.; Winton, W.

    1998-07-01

    A measurement survey of the elevation and environmental media in impoundments 3513 (B) and 3524 (A) at the Oak Ridge National Laboratory (ORNL) was conducted during April 1998. The investigation was performed by the Measurement Applications and Development Group of the Life Sciences Division of ORNL at the request of Bechtel Jacobs Company. Measurement activities were conducted at selected locations in order to determine the depth and appearance of the sediment and describe the clay underlying the impoundments prior to remediation. The survey was a follow-up to a previous elevation survey. The survey included the following: collection of sediment/clay cores from selected locations in each impoundment; measurement and documentation of the elevation at the water surface, at the top of sediment, at the top of clay, and at the bottom of each core; visual inspection of each core by a soil scientist to confirm the presence of clay and not material such as fly ash and soda lime compacted over the last 50 years; measurement and documentation of the background beta-gamma radiation level at the time and location of collection of each core, the highest beta-gamma level along the sediment portion of each core, and the highest beta-gamma level along the clay portion of each core; measurement and documentation of the length of the clay and of the sediment portion of each core; photographic documentation of each core; and replacement of each core in the impoundment.

  8. A Multi-Factor Analysis of Sustainable Agricultural Residue Removal Potential

    SciTech Connect (OSTI)

    Jared Abodeely; David Muth; Paul Adler; Eleanor Campbell; Kenneth Mark Bryden

    2012-10-01

    Agricultural residues have significant potential as a near term source of cellulosic biomass for bioenergy production, but sustainable removal of agricultural residues requires consideration of the critical roles that residues play in the agronomic system. Previous work has developed an integrated model to evaluate sustainable agricultural residue removal potential considering soil erosion, soil organic carbon, greenhouse gas emission, and long-term yield impacts of residue removal practices. The integrated model couples the environmental process models WEPS, RUSLE2, SCI, and DAYCENT. This study uses the integrated model to investigate the impact of interval removal practices in Boone County, Iowa, US. Residue removal of 4.5 Mg/ha was performed annually, bi-annually, and tri-annually and were compared to no residue removal. The study is performed at the soil type scale using a national soil survey database assuming a continuous corn rotation with reduced tillage. Results are aggregated across soil types to provide county level estimates of soil organic carbon changes and individual soil type soil organic matter content if interval residue removal were implemented. Results show interval residue removal is possible while improving soil organic matter. Implementation of interval removal practices provide greater increases in soil organic matter while still providing substantial residue for bioenergy production.

  9. The Open Science Grid status and architecture

    SciTech Connect (OSTI)

    Pordes, Ruth; Petravick, Don; Kramer, Bill; Olsen, James D.; Livny, Miron; Roy, Gordon A.; Avery, Paul Ralph; Blackburn, Kent; Wenaus, Torre J.; Wuerthwein, Frank K.; Foster, Ian; /Chicago U. /Indiana U.

    2007-09-01

    The Open Science Grid (OSG) provides a distributed facility where the Consortium members provide guaranteed and opportunistic access to shared computing and storage resources. The OSG project[1] is funded by the National Science Foundation and the Department of Energy Scientific Discovery through Advanced Computing program. The OSG project provides specific activities for the operation and evolution of the common infrastructure. The US ATLAS and US CMS collaborations contribute to and depend on OSG as the US infrastructure contributing to the World Wide LHC Computing Grid on which the LHC experiments distribute and analyze their data. Other stakeholders include the STAR RHIC experiment, the Laser Interferometer Gravitational-Wave Observatory (LIGO), the Dark Energy Survey (DES) and several Fermilab Tevatron experiments- CDF, D0, MiniBoone etc. The OSG implementation architecture brings a pragmatic approach to enabling vertically integrated community specific distributed systems over a common horizontal set of shared resources and services. More information can be found at the OSG web site: www.opensciencegrid.org.

  10. Selection of area and specific site for drilling a horizontal well in Calhoun County, West Virginia

    SciTech Connect (OSTI)

    Reeves, T.K.; Overbey, W.K. Jr.; Salamy, S.P.; Locke, C.D.

    1992-03-01

    This report discusses the data collection and analysis procedures used to establish criteria for geologic and engineering studies conducted by BDM to select a general area for more detailed study and a specific site for the drilling of a cooperative well with an industry partner, the Consolidated Natural Gas Development Company (CNGD). The results of detailed geologic studies are presented for two areas in Calhoun County, West Virginia, and one area along the Logan-Boone County line in West Virginia. The effects of Appalachian Basin tectonics and the Rome Trough Rift system were identified on seismic lines made available by (CNGD). These helped to identify and define the trapping mechanisms which had been effective in each area. Engineering analyses of past production histories provided data to support selection of target areas and then to select a specific site that met the project requirements for production, reservoir pressure, and risk. A final site was selected in Lee District at the southwestern margin of the Sand Ridge gas field based on the combination of a geologic trapping mechanism and reservoir pressures which were projected as 580 psi with a stress ratio of 0.53.

  11. Characterization of montmorillonite surfaces after modification by organosilane.

    SciTech Connect (OSTI)

    Song, K.; Sandi, G.; Chemistry

    2001-04-01

    X-ray powder diffraction (XRD), thermal gravimetric analysis (TGA), surface area measurements, and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy were used to examine the surface properties of organosilane-modified smectite-type aluminosilicate clays. Organic modified clays derived from the reactions of montmorillonite (containing 93-95% montmorillonite from a bentonite, <1% quartz, and 4-6% opal CT) with octadecyltrichlorosilane (C{sub 18}H{sub 37}SiCl{sub 3}) and octadecyltrimethoxysilane [C{sub 18}H{sub 37}Si(OMe){sub 3}] are highly hydrophobic. Surface loadings of the modified clays depend on the organosilane and the solvent, and they range from 10 to 25 wt. %. The organic species are probably adsorbed to the outer surfaces and bound to the edges of the clay via condensation with edge-OH groups. Encapsulation of montmorillonite with C{sub 18}H{sub 37}SiCl{sub 3} and C{sub 18}H{sub 37}Si(OMe){sub 3} resulted in hydrophobic coating that acts like a 'cage' around the clay particles to limit diffusion. Basal spacings of the organic modified clays remain at {approx}15 {angstrom} upon heating to 400{sup o}C in N{sub 2}, whereas those of unmodified clays collapse to {approx}10 {angstrom}. A considerable reduction in surface area (by 75-90%) for organic modified clays is observed, which is consistent with the existence of a surface coating. The solvent used can affect the amount of organic silane coated on the clay particles, whereas the difference between the products prepared using C{sub 18}H{sub 37}SiCl{sub 3} and C{sub 18}H{sub 37}Si(OMe){sub 3} in the same solvent is relatively small. The carbon and oxygen K-edge NEXAFS spectroscopy of the modified montmorillonite surfaces showed that surface coatings on the outside of the clay particles exist. The encapsulating system may allow for economical remediation and storage of hazardous materials.

  12. Process for producing advanced ceramics

    DOE Patents [OSTI]

    Kwong, Kyei-Sing (Tuscaloosa, AL)

    1996-01-01

    A process for the synthesis of homogeneous advanced ceramics such as SiC+AlN, SiAlON, SiC+Al.sub.2 O.sub.3, and Si.sub.3 N.sub.4 +AlN from natural clays such as kaolin, halloysite and montmorillonite by an intercalation and heat treatment method. Included are the steps of refining clays, intercalating organic compounds into the layered structure of clays, drying the intercalated mixture, firing the treated atmospheres and grinding the loosely agglomerated structure. Advanced ceramics produced by this procedure have the advantages of homogeneity, cost effectiveness, simplicity of manufacture, ease of grind and a short process time. Advanced ceramics produced by this process can be used for refractory, wear part and structure ceramics.

  13. Headspace solid-phase microextraction (HS-SPME) for the determination of benzene, toluene, ethylbenzene, and xylenes (BTEX) in foundry molding sand

    SciTech Connect (OSTI)

    Dungan, R.S. [USDA ARS, Beltsville, MD (United States). Environmental Management & Byproducts Utilization Laboratory

    2005-07-01

    The use of headspace solid-phase microextraction (HS-SPME) to determine benzene, toluene, ethylbenzene, and xylenes (BTEX) in foundry molding sand, specifically a 'green sand' (clay-bonded sand) was investigated. The BTEX extraction was conducted using a 75 {mu} M carboxen-polydimethylsiloxane (CAR-PDMS) fiber, which was suspended above 10 g of sample. The SPME fiber was desorbed in a gas chromatograph injector port (280{sup o}C for 1 min) and the analytes were characterized by mass spectrometry. The effects of extraction time and temperature, water content, and clay and bituminous coal percentage on HS-SPME of BTEX were investigated. Because green sands contain bentonite clay and carbonaceous material such as crushed bituminous coal, a matrix effect was observed. The detection limits for BTEX were determined to be {lt}= 0.18 ng g{sup -1} of green sand.

  14. Permeability and porosity of hydrate-bearing sediments in the northern Gulf of Mexico

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Daigle, Hugh; Cook, Ann; Malinverno, Alberto

    2015-10-14

    Hydrate-bearing sands are being actively explored because they contain the highest concentrations of hydrate and are the most economically recoverable hydrate resource. However, relatively little is known about the mechanisms or timescales of hydrate formation, which are related to methane supply, fluid flux, and host sediment properties such as permeability. We used logging-while-drilling data from locations in the northern Gulf of Mexico to develop an effective medium theory-based model for predicting permeability based on clay-sized sediment fraction. The model considers permeability varying between sand and clay endpoint permeabilities that are defined from laboratory data. We verified the model using permeabilitymore » measurements on core samples from three boreholes, and then used the model to predict permeability in two wells drilled in Walker Ridge Block 313 during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II expedition in 2009. We found that the cleanest sands (clay-sized fraction <0.05) had intrinsic (hydrate-free) permeability contrasts of 5-6 orders of magnitude with the surrounding clays, which is sufficient to provide focused hydrate formation due to advection of methane from a deep source or diffusion of microbial methane from nearby clay layers. In sands where the clay-sized fraction exceeds 0.05, the permeability reduces significantly and focused flow is less pronounced. In these cases, diffusion of dissolved microbial methane is most likely the preferred mode of methane supply for hydrate formation. In conclusion, our results provide important constraints on methane supply mechanisms in the Walker Ridge area and have global implications for evaluating rates of methane migration and hydrate formation in hydrate-bearing sands.« less

  15. Permeability and porosity of hydrate-bearing sediments in the northern Gulf of Mexico

    SciTech Connect (OSTI)

    Daigle, Hugh; Cook, Ann; Malinverno, Alberto

    2015-10-14

    Hydrate-bearing sands are being actively explored because they contain the highest concentrations of hydrate and are the most economically recoverable hydrate resource. However, relatively little is known about the mechanisms or timescales of hydrate formation, which are related to methane supply, fluid flux, and host sediment properties such as permeability. We used logging-while-drilling data from locations in the northern Gulf of Mexico to develop an effective medium theory-based model for predicting permeability based on clay-sized sediment fraction. The model considers permeability varying between sand and clay endpoint permeabilities that are defined from laboratory data. We verified the model using permeability measurements on core samples from three boreholes, and then used the model to predict permeability in two wells drilled in Walker Ridge Block 313 during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II expedition in 2009. We found that the cleanest sands (clay-sized fraction <0.05) had intrinsic (hydrate-free) permeability contrasts of 5-6 orders of magnitude with the surrounding clays, which is sufficient to provide focused hydrate formation due to advection of methane from a deep source or diffusion of microbial methane from nearby clay layers. In sands where the clay-sized fraction exceeds 0.05, the permeability reduces significantly and focused flow is less pronounced. In these cases, diffusion of dissolved microbial methane is most likely the preferred mode of methane supply for hydrate formation. In conclusion, our results provide important constraints on methane supply mechanisms in the Walker Ridge area and have global implications for evaluating rates of methane migration and hydrate formation in hydrate-bearing sands.

  16. Regenerable sorbents for CO.sub.2 capture from moderate and high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    2008-01-01

    A process for making a granular sorbent to capture carbon dioxide from gas streams comprising homogeneously mixing an alkali metal oxide, alkali metal hydroxide, alkaline earth metal oxide, alkaline earth metal hydroxide, alkali titanate, alkali zirconate, alkali silicate and combinations thereof with a binder selected from the group consisting of sodium ortho silicate, calcium sulfate dihydrate (CaSO.sub.4.2H.sub.2O), alkali silicates, calcium aluminate, bentonite, inorganic clays and organic clays and combinations thereof and water; drying the mixture and placing the sorbent in a container permeable to a gas stream.

  17. Geothermal Reservoir Well Stimulation Program: technology transfer

    SciTech Connect (OSTI)

    Not Available

    1980-05-01

    A literature search on reservoir and/or well stimulation techniques suitable for application in geothermal fields is presented. The literature on stimulation techniques in oil and gas field applications was also searched and evaluated as to its relevancy to geothermal operations. The equivalent low-temperature work documented in the open literature is cited, and an attempt is made to evaluate the relevance of this information as far as high-temperature stimulation work is concerned. Clays play an important role in any stimulation work. Therefore, special emphasis has been placed on clay behavior anticipated in geothermal operations. (MHR)

  18. Method for the regeneration of spent molten zinc chloride

    DOE Patents [OSTI]

    Zielke, Clyde W.; Rosenhoover, William A.

    1981-01-01

    In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

  19. Effectiveness of interim remedial actions at a radioactive waste facility

    SciTech Connect (OSTI)

    Devgun, J.S.; Beskid, N.J.; Peterson, J.M.; Seay, W.M.; McNamee, E.; USDOE Oak Ridge Operations Office, TN; Bechtel National, Inc., Oak Ridge, TN )

    1989-01-01

    Over the past eight years, several interim remedial actions have been taken at the Niagara Falls Storage Site (NFSS), primarily to reduce radon and gamma radiation exposures and to consolidate radioactive waste into a waste containment facility. Interim remedial actions have included capping of vents, sealing of pipes, relocation of the perimeter fence (to limit radon risk), transfer and consolidation of waste, upgrading of storage buildings, construction of a clay cutoff wall (to limit the potential groundwater transport of contaminants), treatment and release of contaminated water, interim use of a synthetic liner, and emplacement of an interim clay cap. An interim waste containment facility was completed in 1986. 6 refs., 3 figs.

  20. Append_F_Stream Flow.xls

    Office of Legacy Management (LM)

    Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe (groundwater impoundment in old Van Pile area) 4/14/2000 >VANPILE-STEEP/LINED 0.38 Montezuma Creek above old Vanadium Pile, where

  1. Appendix F Stream Flow.xls

    Office of Legacy Management (LM)

    Stream Flow Measurement Results Since 2000 This page intentionally left blank Appendix F Stream Flow Measurement Results Since 2000 Collect Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe

  2. Microsoft Word - S02459_2006Annual GW Rpt.doc

    Office of Legacy Management (LM)

    Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe (groundwater impoundment in old Van Pile area) 4/14/2000 >VANPILE-STEEP/LINED 0.38 Montezuma Creek above old Vanadium Pile, where

  3. Microsoft Word - S03623_2007AnnRep_091007.doc

    Office of Legacy Management (LM)

    Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe (groundwater impoundment in old Van Pile area) 4/14/2000 >VANPILE-STEEP/LINED 0.38 Montezuma Creek above old Vanadium Pile, where

  4. Microsoft Word - S06596_GW.doc

    Office of Legacy Management (LM)

    Date Surface ID Calculated Flow (ft 3 /sec) Comments 1/14/2000 CARB POND TRENCH OUT 0.25 Carb Pond trench outfall 1/14/2000 MNT CR E OF HWY CULV 0.22 MONTEZUMA CREEK 100 FT EAST OF HIGHWAY CULVERT 1/14/2000 MC>CUTOFFTRENCH CLAY 0.19 Montezuma Creek above ground water cutoff trench, clay bottom. 4/14/2000 MIDPOND OUTFALL PIPE 0.26 Middle Pond outfall pipe (groundwater impoundment in old Van Pile area) 4/14/2000 >VANPILE-STEEP/LINED 0.38 Montezuma Creek above old Vanadium Pile, where

  5. Microsoft Word - Cooper_Tritium.final.doc

    Office of Legacy Management (LM)

    PROCEEDINGS, TOUGH Symposium 2006 Lawrence Berkeley National Laboratory, Berkeley, California, May 15-17, 2006 - 1 - TRITIUM TRANSPORT THROUGH A LOW-PERMEABILITY NATURAL GAS RESERVOIR Clay A. Cooper 1 , Ming Ye 2 , and Jenny Chapman 2 Desert Research Institute 1 2215 Raggio Pkwy Reno, Nevada, 89512, USA E-mail: clay@dri.edu 2 755 E. Flamingo Road Las Vegas, NV 89119, USA ABSTRACT The U.S. Department of Energy and its predecessor agencies conducted a program in the 1960s and 1970s to evaluate

  6. SEISMIC AND ROCK PHYSICS DIAGNOSTICS OF MULTISCALE RESERVOIR TEXTURES

    SciTech Connect (OSTI)

    Gary Mavko

    2002-05-01

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have studied (1) How to quantify elastic properties of clay minerals using Atomic Force Acoustic Microscopy. We show how bulk modulus of clay can be measured using atomic force acoustic microscopy (AFAM) (2) We have successfully measured elastic properties of unconsolidated sediments in an effort to quantify attributes for detection of overpressures from seismic (3) We have initiated efforts for velocity upscaling to quantify long-wavelength and short-wavelength velocity behavior and the scale-dependent dispersion caused by sediment variability in different depositional environments.

  7. Measurement of the absolute \

    SciTech Connect (OSTI)

    Aunion, Jose Luis Alcaraz; /Barcelona, IFAE

    2010-07-01

    This thesis presents the measurement of the charged current quasi-elastic (CCQE) neutrino-nucleon cross section at neutrino energies around 1 GeV. This measurement has two main physical motivations. On one hand, the neutrino-nucleon interactions at few GeV is a region where existing old data are sparse and with low statistics. The current measurement populates low energy regions with higher statistics and precision than previous experiments. On the other hand, the CCQE interaction is the most useful interaction in neutrino oscillation experiments. The CCQE channel is used to measure the initial and final neutrino fluxes in order to determine the neutrino fraction that disappeared. The neutrino oscillation experiments work at low neutrino energies, so precise measurement of CCQE interactions are essential for flux measurements. The main goal of this thesis is to measure the CCQE absolute neutrino cross section from the SciBooNE data. The SciBar Booster Neutrino Experiment (SciBooNE) is a neutrino and anti-neutrino scattering off experiment. The neutrino energy spectrum works at energies around 1 GeV. SciBooNE was running from June 8th 2007 to August 18th 2008. In that period, the experiment collected a total of 2.65 x 10{sup 20} protons on target (POT). This thesis has used full data collection in neutrino mode 0.99 x 10{sup 20} POT. A CCQE selection cut has been performed, achieving around 70% pure CCQE sample. A fit method has been exclusively developed to determine the absolute CCQE cross section, presenting results in a neutrino energy range from 0.2 to 2 GeV. The results are compatible with the NEUT predictions. The SciBooNE measurement has been compared with both Carbon (MiniBoonE) and deuterium (ANL and BNL) target experiments, showing a good agreement in both cases.

  8. MODIFIED REVERSE OSMOSIS SYSTEM FOR TREATMENT OF PRODUCED WATERS

    SciTech Connect (OSTI)

    T.M. Whitworth; Liangxiong Li

    2002-09-15

    This report describes work performed during the first year of the project ''Modified Reverse Osmosis System for Treatment of Produced Waters.'' This research project has two objectives. The first objective is to test the use of clay membranes in the treatment of produced waters by reverse osmosis. The second objective is to test the ability of a system patented by the New Mexico Tech Research Foundation to remove salts from reverse osmosis waste streams as a solid. We performed 12 experiments using clay membranes in cross-flow experimental cells. We found that, due to dispersion in the porous frit used adjacent to the membrane, the concentration polarization layer seems to be completely (or nearly completely) destroyed at low flow rates. This observation suggests that clay membranes used with porous frit material many reach optimum rejection rates at lower pumping rates than required for use with synthetic membranes. The solute rejection efficiency decreases with increasing solution concentration. For the membranes and experiments reported here, the rejection efficiency ranged from 71% with 0.01 M NaCl solution down to 12% with 2.3 M NaCl solution. More compacted clay membranes will have higher rejection capabilities. The clay membranes used in our experiments were relatively thick (approximately 0.5 mm). The active layer of most synthetic membranes is only 0.04 {micro}m (0.00004 mm), approximately 1250 times thinner than the clay membranes used in these experiments. Yet clay membranes as thin as 12 {micro}m have been constructed (Fritz and Eady, 1985). Since Darcy's law states that the flow through a material of constant permeability is inversely proportional to it's the material's thickness, then, based on these experimental observations, a very thin clay membrane would be expected to have much higher flow rates than the ones used in these experiments. Future experiments will focus on testing very thin clay membranes. The membranes generally exhibited reasonable stable rejection rates over time for chloride for a range of concentrations between 0.01 and 2.5 M. One membrane ran in excess of three months with no apparent loss of usability. This suggests that clay membranes may have a long useable life. Twenty different hyperfiltration-induced solute precipitation experiments were either attempted or completed and are reported here. The results of these experiments suggest that hyperfiltration-induced solute precipitation is possible, even for very soluble substances such as NaCl. However, the precipitation rates obtained in the laboratory do not appear to be adequate for commercial application at this time. Future experiments will focus on making the clay membranes more compact and thinner in order to obtain higher flux rates. Two alternative methods of removing solutes from solution, for which the New Mexico Tech Research Foundation is preparing patent applications, are also being investigated. These methods will be described in the next annual report after the patent applications are filed. Technology transfer efforts included two meetings (one in Farmington NM, and one in Hobbs, NM) where the results of this research were presented to independent oil producers and other interested parties. In addition, members of the research team gave seven presentations concerning this research and because of this research project T. M. (Mike) Whitworth was asked to sit on the advisory board for development of a new water treatment facility for the City of El Paso, Texas. Several papers are in preparation for submission to peer-reviewed journals based on the data presented in this report.

  9. Catalytic membranes for CO oxidation in fuel cells

    DOE Patents [OSTI]

    Sandi-Tapia, Giselle; Carrado Gregar, Kathleen; Kizilel, Riza

    2010-06-08

    A hydrogen permeable membrane, which includes a polymer stable at temperatures of about 200 C having clay impregnated with Pt or Au or Ru or Pd particles or mixtures thereof with average diameters of less than about 10 nanometers (nms) is disclosed. The membranes are useful in fuel cells or any device which requires hydrogen to be separated from carbon monoxide.

  10. Aqueous biphasic extraction process with pH and particle control

    DOE Patents [OSTI]

    Chaiko, David J. (Woodridge, IL); Mensah-Biney, R. (Downers Grove, IL)

    1995-01-01

    A process for aqueous biphasic extraction of metallic oxides and the like from substances containing silica. Control of media pH enables efficient and effective partition of mixture components. The inventive method may be employed to remove excess silica from kaolin clay.

  11. Aqueous biphasic extraction process with pH and particle control

    DOE Patents [OSTI]

    Chaiko, D.J.; Mensah-Biney, R.

    1995-05-02

    A process for aqueous biphasic extraction of metallic oxides and the like from substances containing silica. Control of media pH enables efficient and effective partition of mixture components. The inventive method may be employed to remove excess silica from kaolin clay. 2 figs.

  12. Polymer nanocomposites for lithium battery applications

    DOE Patents [OSTI]

    Sandi-Tapia, Giselle; Gregar, Kathleen Carrado

    2006-07-18

    A single ion-conducting nanocomposite of a substantially amorphous polyethylene ether and a negatively charged synthetic smectite clay useful as an electrolyte. Excess SiO2 improves conductivity and when combined with synthetic hectorite forms superior membranes for batteries. A method of making membranes is also disclosed.

  13. QER- Comment of American Gas Association 1

    Broader source: Energy.gov [DOE]

    Attached please find AGA's comments on methane emissions issues in the first phase of the DOE Quadrennial Energy Review (QER), consisting of a cover letter and attachments. Dr. Kathryn Clay will be submitting AGA's comments on other aspects of the QER. Please let me know if you have any questions.

  14. Failure mode analysis for lime/limestone FGD system. Volume III. Plant profiles. Part 1 of 3

    SciTech Connect (OSTI)

    Kenney, S.M.; Rosenberg, H.S.; Nilsson, L.I.O.; Oxley, J.H.

    1984-08-01

    This volume contains plant profiles for: Petersburg 3; Hawthorn 3, 4; La Cygne 1; Jeffry 1, 2; Lawrence 4, 5; Green River 1-3; Cane Run 4, 5; Mill Creek 1, 3; Paddy's Run 6; Clay Boswell 4; Milton R. Young 2; Pleasants 1, 2; and Colstrip 1, 2. (DLC)

  15. Cracking catalysts comprising phosphorus and method of preparing and using the same

    SciTech Connect (OSTI)

    Absil, R.P.L.; Herbst, J.A.

    1993-07-27

    A zeolite catalyst is described for cracking hydrocarbons formed by a process comprising the steps of: forming a slurry comprising clay, a source of phosphorus and an acid stable zeolite; and spray drying said slurry in the absence of other non-zeolitic inorganic oxide matrices at a pH which is sufficiently low to provide a calcined attrition index of [<=] 10.

  16. Dry scrubbing of SO/sub 2/

    SciTech Connect (OSTI)

    Shah, N.D.

    1982-06-01

    The advantages of dry scrubbing over wet scrubbing or spray drying are considered. One of the problem areas is that of waste disposal. The most cost-effective solutions are land disposal or landfill in clay cells. The factors influencing the selection of an SO/sub 2/ scrubbing system are discussed. Nahcolite appears to be the most promising agent for dry scrubbing.

  17. QER- Comment of American Gas Association 3

    Broader source: Energy.gov [DOE]

    Dear Ms. Pickett: Attached please find AGA's comments on natural gas vehicle fueling infrastructure as part of our response to the first phase of the DOE Quadrennial Energy Review (QER), consisting of a cover letter and attachments. Respectfully submitted, Kathryn Clay

  18. Infrastructure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure (D2SA) Co-Chairs: Christopher Beggio, Sandia National Laboratories Robin Goldstone, Lawrence Livermore National Laboratories 1 Contributors * Bill Allcock, Argonne Leadership Computing Facility * Chris Beggio, Sandia National Laboratories * Clay England, Oak Ridge Leadership Computing Facility * Doug Fuller, Oak Ridge Leadership Computing Facility * Robin Goldstone, Lawrence Livermore National Laboratory * Jason Hick, National Energy Research Scientific Computing Center * Kyle

  19. Nontoxic chemical process for in situ permeability enhancement and accelerated decontamination of fine-grain subsurface sediments

    DOE Patents [OSTI]

    Kansa, Edward J. (Livermore, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

    1997-01-01

    The remediation of heterogeneous subsurfaces is extremely time consuming and expensive with current and developing technologies. Although such technologies can adequately remove contaminants in the high hydraulic conductivity, coarse-grained sediments, they cannot access the contaminated low hydraulic conductivity fine-grained sediments. The slow bleed of contaminants from the fine-grained sediments is the primary reason why subsurface remediation is so time-consuming and expensive. This invention addresses the problem of remediating contaminated fine-grained sediments. It is intended that, in the future, a heterogeneous site be treated by a hybrid process that first remediates the high hydraulic conductivity, coarse-grained sediments, to be followed by the process, described in this invention, to treat the contaminated low hydraulic conductivity fine-grained sediments. The invention uses cationic flocculents and organic solvents to collapse the swelling negative double layer surrounding water saturated clay particles, causing a flocculated, cracked clay structure. The modification of the clay fabric in fine-grained sediments dramatically increases the hydraulic conductivity of previously very tight clays many orders of magnitude.

  20. Nontoxic chemical process for in situ permeability enhancement and accelerated decontamination of fine-grain subsurface sediments

    DOE Patents [OSTI]

    Kansa, E.J.; Wijesinghe, A.M.; Viani, B.E.

    1997-01-14

    The remediation of heterogeneous subsurfaces is extremely time consuming and expensive with current and developing technologies. Although such technologies can adequately remove contaminants in the high hydraulic conductivity, coarse-grained sediments, they cannot access the contaminated low hydraulic conductivity fine-grained sediments. The slow bleed of contaminants from the fine-grained sediments is the primary reason why subsurface remediation is so time-consuming and expensive. This invention addresses the problem of remediating contaminated fine-grained sediments. It is intended that, in the future, a heterogeneous site be treated by a hybrid process that first remediates the high hydraulic conductivity, coarse-grained sediments, to be followed by the process, described in this invention, to treat the contaminated low hydraulic conductivity fine-grained sediments. The invention uses cationic flocculants and organic solvents to collapse the swelling negative double layer surrounding water saturated clay particles, causing a flocculated, cracked clay structure. The modification of the clay fabric in fine-grained sediments dramatically increases the hydraulic conductivity of previously very tight clays many orders of magnitude. 8 figs.

  1. Modeling Blast Loading on Buried Reinforced Concrete Structures with Zapotec

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bessette, Greg C.

    2008-01-01

    A coupled Euler-Lagrange solution approach is used to model the response of a buried reinforced concrete structure subjected to a close-in detonation of a high explosive charge. The coupling algorithm is discussed along with a set of benchmark calculations involving detonations in clay and sand.

  2. Treatability study of absorbent polymer waste form for mixed waste treatment

    SciTech Connect (OSTI)

    Herrmann, S. D.; Lehto, M. A.; Stewart, N. A.; Croft, A. D.; Kern, P. W.

    2000-02-10

    A treatability study was performed to develop and characterize an absorbent polymer waste form for application to low level (LLW) and mixed low level (MLLW) aqueous wastes at Argonne National Laboratory-West (ANL-W). In this study absorbent polymers proved effective at immobilizing aqueous liquid wastes in order to meet Land Disposal Restrictions for subsurface waste disposal. Treatment of aqueous waste with absorbent polymers provides an alternative to liquid waste solidification via high-shear mixing with clays and cements. Significant advantages of absorbent polymer use over clays and cements include ease of operations and waste volume minimization. Absorbent polymers do not require high-shear mixing as do clays and cements. Granulated absorbent polymer is poured into aqueous solutions and forms a gel which passes the paint filter test as a non-liquid. Pouring versus mixing of a solidification agent not only eliminates the need for a mixing station, but also lessens exposure to personnel and the potential for spread of contamination from treatment of radioactive wastes. Waste minimization is achieved as significantly less mass addition and volume increase is required of and results from absorbent polymer use than that of clays and cements. Operational ease and waste minimization translate into overall cost savings for LLW and MLLW treatment.

  3. MODIFIED REVERSE OSMOSIS SYSTEM FOR TREATMENT OF PRODUCED WATERS

    SciTech Connect (OSTI)

    T.M. Whitworth; Liangxiong Li

    2002-09-15

    This report describes work performed during the second year of the project ''Modified reverse osmosis system for treatment of produced waters.'' We performed two series of reverse osmosis experiments using very thin bentonite clay membranes compacted to differing degrees. The first series of 10 experiments used NaCl solutions with membranes that ranged between 0.041 and 0.064mm in thickness. Our results showed compaction of such ultra-thin clay membranes to be problematic. The thickness of the membranes was exceeded by the dimensional variation in the machined experimental cell and this is believed to have resulted in local bypassing of the membrane with a resultant decrease in solute rejection efficiency. In two of the experiments, permeate flow was varied as a percentage of the total flow to investigate results of changing permeate flow on solute rejection. In one experiment, the permeate flow was varied between 2.4 and 10.3% of the total flow with no change in solute rejection. In another experiment, the permeate flow was varied between 24.6 and 52.5% of the total flow. In this experiment, the solute rejection rate decreased as the permeate occupied greater fractions of the total flow. This suggests a maximum solute rejection efficiency for these clay membranes for a permeate flow of between 10.3 and 24.6% of the total; flow. Solute rejection was found to decrease with increasing salt concentration and ranged between 62.9% and 19.7% for chloride and between 61.5 and 16.8% for sodium. Due to problems with the compaction procedure and potential membrane bypassing, these rejection rates are probably not the upper limit for NaCl rejection by bentonite membranes. The second series of four reverse osmosis experiments was conducted with a 0.057mm-thick bentonite membrane and dilutions of a produced water sample with an original TDS of 196,250 mg/l obtained from a facility near Loco Hill, New Mexico, operated by an independent. These experiments tested the separation efficiency of the bentonite membrane for each of the dilutions. We found that membrane efficiency decreased with increasing solute concentration and with increasing TDS. The rejection of SO{sub 4}{sup 2-} was greater than Cl{sup -}. This may be because the SO{sub 4}{sup 2-} concentration was much lower than the Cl{sup -} concentration in the waters tested. The cation rejection sequence varied with solute concentration and TDS. The solute rejection sequence for multi-component solutions is difficult to predict for synthetic membranes; it may not be simple for clay membranes either. The permeate flows in our experiments were 4.1 to 5.4% of the total flow. This suggests that very thin clay membranes may be useful for some separations. Work on development of a spiral-wound clay membrane module found that it is difficult to maintain compaction of the membrane if the membrane is rolled and then inserted in the outer tube. A different design was tried using a cylindrical clay membrane and this also proved difficult to assemble with adequate membrane compaction. The next step is to form the membrane in place using hydraulic pressure on a thin slurry of clay in either water or a nonpolar organic solvent such as ethanol. Technology transfer efforts included four manuscripts submitted to peer-reviewed journals, two abstracts, and chairing a session on clays as membranes at the Clay Minerals Society annual meeting.

  4. Naturally occurring radionuclides in agricultural products: An overview

    SciTech Connect (OSTI)

    Hanlon, E.A.

    1994-07-01

    Low levels of naturally occurring radionuclides exist in phosphatic clays, a by-product of phosphatic mining and beneficiation processes. Concerns about these radionuclides entering the human food chain were an immediate research priority before the phosphate clays could be reclaimed for intensive agricultural purposes. Efforts included the assembly of a large body of data from both sons and plants, part of which were produced by the Polk County (Florida) Mined Lands Agricultural Research/Demonstration Project MLAR/DP. Additional detailed studies involving dairy and beef cattle (Bos taurus) were conducted by researchers working with the MLAR/DP. A national symposium was conducted in which data concerning the MLAR/DP work and other research projects also dealing with naturally occurring radionuclides in agriculture could be discussed. The symposium included invited review papers dealing with the identification of radionuclide geological origins, the geochemistry and movement of radionuclides within the environment, mechanisms of plant uptake, entry points into the food chain, and evaluation of dose and risk assessment to the consumer of low levels of radionuclides. The risk to human health of an individual obtaining 0.1 of his or her dietary intake from crops produced on phosphatic clays increased by 1 in 5 x 10{sup 6}/yr above a control individual consuming no food grown on phosphatic clays. Leaf tissues were found to be generally higher than fruit, grain, or root tissues. The natural range in radionuclide content among various food types was greater than the difference in radionuclides content between the same food produced on phosphatic clays vs. natural soils. 19 refs.

  5. Morphology of Gas Release in Physical Simulants

    SciTech Connect (OSTI)

    Daniel, Richard C.; Burns, Carolyn A.; Crawford, Amanda D.; Hylden, Laura R.; Bryan, Samuel A.; MacFarlan, Paul J.; Gauglitz, Phillip A.

    2014-07-03

    This report documents testing activities conducted as part of the Deep Sludge Gas Release Event Project (DSGREP). The testing described in this report focused on evaluating the potential retention and release mechanisms of hydrogen bubbles in underground radioactive waste storage tanks at Hanford. The goal of the testing was to evaluate the rate, extent, and morphology of gas release events in simulant materials. Previous, undocumented scoping tests have evidenced dramatically different gas release behavior from simulants with similar physical properties. Specifically, previous gas release tests have evaluated the extent of release of 30 Pa kaolin and 30 Pa bentonite clay slurries. While both materials are clays and both have equivalent material shear strength using a shear vane, it was found that upon stirring, gas was released immediately and completely from bentonite clay slurry while little if any gas was released from the kaolin slurry. The motivation for the current work is to replicate these tests in a controlled quality test environment and to evaluate the release behavior for another simulant used in DSGREP testing. Three simulant materials were evaluated: 1) a 30 Pa kaolin clay slurry, 2) a 30 Pa bentonite clay slurry, and 3) Rayleigh-Taylor (RT) Simulant (a simulant designed to support DSGREP RT instability testing. Entrained gas was generated in these simulant materials using two methods: 1) application of vacuum over about a 1-minute period to nucleate dissolved gas within the simulant and 2) addition of hydrogen peroxide to generate gas by peroxide decomposition in the simulants over about a 16-hour period. Bubble release was effected by vibrating the test material using an external vibrating table. When testing with hydrogen peroxide, gas release was also accomplished by stirring of the simulant.

  6. Physical Properties of Hanford Transuranic Waste Sludge

    SciTech Connect (OSTI)

    Berg, John C.

    2005-06-01

    Equipment that was purchased in the abbreviated year 1 of this project has been used during year 2 to study the fundamental behavior of materials that simulate the behavior of the Hanford transuranic waste sludge. Two significant results have been found, and each has been submitted for publication. Both studies found non-DLVO behavior in simulant systems. These separate but related studies were performed concurrently. It was previously shown in Rassat et al.'s report Physical and Liquid Chemical Simulant Formulations for Transuranic Wastes in Hanford Single-Shell Tanks that colloidal clays behave similarly to transuranic waste sludge (PNNL-14333, National Technical Information Service, U.S. Dept. of Commerce). Rassat et al. also discussed the pH and salt content of actual waste materials. It was shown that these materials exist at high pHs, generally above 10, and at high salt content, approximately 1.5 M from a mixture of different salts. A type of clay commonly studied, due to its uniformity, is a synthetic hectorite, Laponite. Therefore the work performed over the course of the last year was done mainly using suspensions of Laponite at high pH and involving high salt concentrations. One study was titled ''Relating Clay Rheology to Colloidal Parameters''. It has been submitted to the Journal of Colloid and INterface Science and is currently in the review process. The idea was to gain the ability to use measurable quantities to predict the flow behavior of clay systems, which should be similar to transuranic waste sludge. Leong et al. had previously shown that the yield stress of colloidal slurries of titania and alumina could be predicted, given the measurement of the accessible parameter zeta potential (Leong YK et al. J Chem Soc Faraday Trans, 19 (1993) 2473). Colloidal clays have a fundamentally different morphology and surface charge distribution than the spheroidal, uniformly charged colloids previously studied. This study was therefore performed in order to determine the applicability of the previous findings to the systems of interest. The yield stress of clay slurries was measured using the Physica MCR 300 purchased in year 1 of this project. The zeta potential of these systems was then measured using the Brookhaven Zeta PALS, also purchased in year 1. These two parameters were then plotted and compared with the Leong result. It was found that this system behaved in a non-DLVO manner. Leong found that colloidal slurry yield stress decreases with increased zeta potential which is consistent with the DLVO theory's assertion that particle attractions decrease as their electrostatic repulsion increases. Clay systems, however, show an increase in yield stress as zeta potential is increased. This is due to the nature of the charge distribution on the surface of clay particles. Clay particles are in the form of platelets.

  7. Dose equations for shift-variant CT acquisition modes using variable pitch, tube current, and aperture, and the meaning of their associated CTDI{sub vol}

    SciTech Connect (OSTI)

    Dixon, Robert L.; Boone, John M.; Kraft, Robert A.

    2014-11-01

    Purpose: With the increasing clinical use of shift-variant CT protocols involving tube current modulation (TCM), variable pitch or pitch modulation (PM), and variable aperture a(t), the interpretation of the scanner-reported CTDI{sub vol} is called into question. This was addressed for TCM in their previous paper published by Dixon and Boone [Med. Phys. 40, 111920 (14pp.) (2013)] and is extended to PM and concurrent TCM/PM as well as variable aperture in this work. Methods: Rigorous convolution equations are derived to describe the accumulated dose distributions for TCM, PM, and concurrent TCM/PM. A comparison with scanner-reported CTDI{sub vol} formulae clearly identifies the source of their differences with the traditional CTDI{sub vol}. Dose distribution simulations using the convolution are provided for a variety of TCM and PM scenarios including a helical shuttle used for perfusion studies (as well as constant mA)all having the same scanner-reported CTDI{sub vol}. These new convolution simulations for TCM are validated by comparison with their previous discrete summations. Results: These equations show that PM is equivalent to TCM if the pitch variation p(z) is proportional to 1/i(z), where i(z) is the local tube current. The simulations show that the local dose at z depends only weakly on the local tube current i(z) or local pitch p(z) due to scatter from all other locations along z, and that the local CTDI{sub vol}(z) or CTDI{sub vol} per slice do not represent a local dose but rather only a relative i(z) or p(z). The CTDI-paradigm does not apply to shift-variant techniques and the scanner-reported CTDI{sub vol} for the same lacks physical significance and relevance. Conclusions: While the traditional CTDI{sub vol} at constant tube current and pitch conveys useful information (the peak dose at the center of the scan length), CTDI{sub vol} for shift-variant techniques (TCM or PM) conveys no useful information about the associated dose distribution it purportedly represents. On the other hand, the total energy absorbed E (integral dose) as well as its surrogate DLP remain robust (invariant) with respect to shift-variance, depending only on the total mAs = ?i?t{sub 0} accumulated during the total beam-on time t{sub 0} and aperture a, where ?i? is the average current.

  8. Review of Metals in Past Societies: A Global Perspective on Indigenous African Metallurgy by Shadreck Chirikure, Springer, 2015

    SciTech Connect (OSTI)

    Devanathan, Ram

    2015-10-01

    This slim book (166 pages) shines a spotlight on pre-industrial African metallurgy, its global connections, and anthropological implications. It integrates seemingly disparate disciplines, such as history, geology, ethnography, archeology, and metallurgy, to illustrate the diversity and innovation in metallurgy across Africa and the role of metals in the rise of socio-economic inequalities and political power. The book has 7 chapters and the focus on metals as enablers of human needs and wants is evident in each chapter. The first chapter presents the context of the work and data sources. The second chapter focuses on the origin and development of mining and metallurgy in pre-industrial Africa. Chapter 3 is dedicated to the interaction of nature and culture in the process of mining. Chapter 4 deals with the transformation of the ore into metal by smelting and the sociocultural aspects of this process. Chapter 5 explores the social and cultural roles acquired by metals as a result of fabrication into objects. Chapter 6 examines the social role of metals, trade in metals, cultural contact, proto-globalization, and technology transfer. Finally, Chapter 7 draws lessons for global anthropology from the African experience. The sources of information are adequately cited and the long list of references at the end of each chapter will be a boon to researchers in this field. The author highlights the cultural aspects and social context of the adoption of metallurgy in Africa while drawing parallels between practices in pre-industrial Africa and those in other parts of the world. The book is peppered with delightful vignettes that offer insights into the process of transforming nature into culturally significant objects. For instance, African miners, like their counterparts in Nepal and Latin America, called upon deities, spirits and ancestors to mediate between nature and humans. Women had distinct roles in this process, but there were variations in these roles and in the caste status of metal workers across Africa. Taboos, rituals and magic were very much a part of the development of metallurgical technology. The smelting of metal was considered analogous to conception, gestation, and child birth. Power, fertility and metallurgy were intertwined as shown by the decoration of furnaces with female anatomical features. The book concludes with a warning against broad generalizations and stereotypes about African practices. This volume is well written and illustrated with photos, micrographs, colorful maps and illustrations that make it eminently readable.

  9. Thermal acidization and recovery process for recovering viscous petroleum

    DOE Patents [OSTI]

    Poston, Robert S. (Winter Park, FL)

    1984-01-01

    A thermal acidization and recovery process for increasing production of heavy viscous petroleum crude oil and synthetic fuels from subterranean hydrocarbon formations containing clay particles creating adverse permeability effects is described. The method comprises injecting a thermal vapor stream through a well bore penetrating such formations to clean the formation face of hydrocarbonaceous materials which restrict the flow of fluids into the petroleum-bearing formation. Vaporized hydrogen chloride is then injected simultaneously to react with calcium and magnesium salts in the formation surrounding the bore hole to form water soluble chloride salts. Vaporized hydrogen fluoride is then injected simultaneously with its thermal vapor to dissolve water-sensitive clay particles thus increasing permeability. Thereafter, the thermal vapors are injected until the formation is sufficiently heated to permit increased recovery rates of the petroleum.

  10. Development of a glass polymer composite sewer pipe from waste glass. Final report

    SciTech Connect (OSTI)

    Rayfiel, R.; Kukacka, L.E.

    1980-02-01

    A range of polymer-aggregate composites for applications in industry which appear to be economically attractive and contribute to energy conservation were developed at BNL. Waste glass is the aggregate in one such material, which is called glass-polymer-composite (GPC). This report assays the economics and durability of GPC in piping for storm drains and sewers. The properties of the pipe are compared statistically with the requirements of industrial specifications. These establish the raw materials requirements. The capital and operating costs for producing pipe are then estimated. Using published sales values for competing materials, the return on investment is calculated for two cases. The ultimate energy requirement of the raw materials in GPC is compared with the corresponding requirement for vitrified clay pipe. The strengths of GPC, reinforced concrete, vitrified clay and asbestos cement pipe are compared after extended exposure to various media. The status of process and product development is reviewed and recommendations are made for future work.

  11. Decontamination of Radioactive Cesium Released from Fukushima Daiichi Nuclear Power Plant - 13277

    SciTech Connect (OSTI)

    Parajuli, Durga; Minami, Kimitaka; Tanaka, Hisashi; Kawamoto, Tohru

    2013-07-01

    Peculiar binding of Cesium to the soil clay minerals remained the major obstacle for the immediate Cs-decontamination of soil and materials containing clay minerals like sludge. Experiments for the removal of Cesium from soil and ash samples from different materials were performed in the lab scale. For soil and sludge ash formed by the incineration of municipal sewage sludge, acid treatment at high temperature is effective while washing with water removed Cesium from ashes of plants or burnable garbage. Though total removal seems a difficult task, water-washing of wood-ash or garbage-ash at 40 deg. C removes >90% radiocesium, while >60% activity can be removed from soil and sludge-ash by acid washing at 95 deg. C. (authors)

  12. Correlation of Chemical and Mechanical Property Changes During Oxidative Degradation of Neoprene

    SciTech Connect (OSTI)

    Celina, M.; Wise, J.; Ottesen, D.K.; Gillen, K.T.; Clough, R.L.

    1999-07-01

    The thermal degradation of a commercial, stabilized, unfilled neoprene (chloroprene) rubber was investigated at temperatures up to 140 C. The degradation of this material is dominated by oxidation rather than dehydrochlorination. Important heterogeneous oxidation effects were observed at the various temperatures investigated using infrared micro-spectroscopy and modulus profiling. Intensive degradation-related spectral changes in the IR occurred in the conjugated carbonyl and hydroxyl regions. Quantitative analysis revealed some differences in the development of the IR oxidation profiles, particularly towards the sample surface. These chemical degradation profiles were compared with modulus profiles (mechanical properties). It is concluded that the profile development is fundamentally described by a diffusion-limited autoxidation mechanism. Oxygen consumption measurements showed that the oxidation rates display non-Arrhenius behavior (curvature) at low temperatures. The current results, when compared to those of a previously studied, clay-filled commercial neoprene formulation, indicate that the clay filler acts as an antioxidant, but only at low temperatures.

  13. Beneficial uses of paper mill residuals for New York State`s recycled-paper mills. Final report

    SciTech Connect (OSTI)

    1995-09-01

    This report evaluates the New York paper mill industry in terms of the productive management and treatment of solid wastes. It identifies current efforts by recycling mills to beneficially use paper mill residuals (often called sludge) and suggests additional options that should be considered by the industry in general and individual mills in particular. It also examines the regulations and economics affecting the mills and suggests actions that could improve the industry`s ability to convert wastes to value-added products. The report recommends that the mills should continue measures to reduce fiber and filler clay losses, promote the transfer of usable fiber and clay to mills able to use them, upgrade sludge dewatering capabilities, and take a more regional approach to solid waste disposal problems. State agencies are urged to support these efforts, encourage the development and commercialization of new beneficial use technologies, and reduce regulatory barriers whenever possible.

  14. Acidity characterization of a titanium and sulfate modified vermiculite

    SciTech Connect (OSTI)

    Hernandez, W.Y.; Centeno, M.A.; Odriozola, J.A.; Moreno, S.; Molina, R.

    2008-07-01

    A natural vermiculite has been modified with titanium and sulfated by the intercalation and impregnation method in order to optimize the acidity of the clay mineral, and characterization of samples were analyzed by X-ray fluorescence (XRF), X-ray diffraction (XRD), nitrogen adsorption isotherms, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and temperature programmed desorption with ammonia (TPD-NH{sub 3}). All the modified solids have a significantly higher number of acidic sites with respect to the parent material and in all of these, Broensted as well as Lewis acidity are identified. The presence of sulfate appears not to increase the number of acidic centers in the modified clay. For the materials sulfated with the intercalation method, it is observed that the strength of the acidic sites found in the material increases with the nominal sulfate/metal ratio. Nevertheless, when elevated quantities of sulfur are deposited, diffusion problems in the heptane reaction appear.

  15. Used Fuel Disposal in Crystalline Rocks. FY15 Progress Report

    SciTech Connect (OSTI)

    Wang, Yifeng

    2015-08-20

    The objective of the Crystalline Disposal R&D Work Package is to advance our understanding of long-term disposal of used fuel in crystalline rocks and to develop necessary experimental and computational capabilities to evaluate various disposal concepts in such media. Chapter headings are as follows: Fuel matrix degradation model and its integration with performance assessments, Investigation of thermal effects on the chemical behavior of clays, Investigation of uranium diffusion and retardation in bentonite, Long-term diffusion of U(VI) in bentonite: dependence on density, Sorption and desorption of plutonium by bentonite, Dissolution of plutonium intrinsic colloids in the presence of clay and as a function of temperature, Laboratory investigation of colloid-facilitated transport of cesium by bentonite colloids in a crystalline rock system, Development and demonstration of discrete fracture network model, Fracture continuum model and its comparison with discrete fracture network model.

  16. Seismic and Rockphysics Diagnostics of Multiscale Reservoir Textures

    SciTech Connect (OSTI)

    Gary Mavko

    2002-11-01

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have studied (1) Kerogen-rich shales using Scanning Acoustic Microscopy and ultrasonic wave propagation. We find that an increase in elastic modulus with increasing kerogen maturity can be directly related to the microstructural acoustic impedance changes. A positive relation is established between microstructural changes and velocity variations as functions of kerogen maturity. (2) Elastic properties of clay minerals using Atomic Force Acoustic Microscopy and Scanning Acoustic Microscopy. We show the effect of clay minerals in contact zones as load-bearing constituents of rocks (3) Elastic properties of unconsolidated sediments in an effort to quantify attributes for detection of overpressures from seismic and for effects of stress-induced velocity anisotropy in sediments (4) We have initiated efforts for velocity upscaling to quantify long-wavelength and short-wavelength velocity behavior and the scale-dependent dispersion caused by sediment variability in different depositional environments.

  17. Uranium distribution in relation to sedimentary facies, Kern Lake, California

    SciTech Connect (OSTI)

    Merifield, P.M.; Carlisle, D.; Idiz, E.; Anderhalt, R.; Reed, W.E.; Lamar, D.L.

    1980-04-01

    Kern Lake has served as a sink for drainage from the southern Sierra Nevada and, in lesser amounts, from the southern Temblor Range. Both areas contain significant uranium source rocks. The uranium content in Holocene Kern Lake sediments correlates best with the mud (silt and clay) fraction. It correlates less well with organic carbon. Biotite grains could account for much of the uranium in the sand fraction, and perhaps the silt fraction as well. The data suggest that fixation of uranium by adsorption on mineral grains is a dominant process in this lake system. Further work is required to determine the importance of cation-exchange of uranium on clays and micas and of organically complexed uranium adsorbed to mineral surfaces. These findings also raise the question of whether uranium transport down the Kern River occurs largely as uranium adsorbed to mineral surfaces.

  18. Black Bear Prep plant replaces high-frequency screens with fine wire sieves

    SciTech Connect (OSTI)

    Barbee, C.J.; Nottingham, J.

    2007-12-15

    At the Black Bear prep plant (near Wharncliffe, WV, USA) the clean coal from the spirals traditionally reported to high-frequency screens, which removed high-ash clay fines. Screens have inherent inefficiencies that allow clean coal to report to the screen underflow. The goal of this project was to capture the maximum amount of spiral clean coal while still removing the high-ash clay material found in the spiral product. The reduction of the circulating load and plant downtime for unscheduled maintenance were projected as additional benefits. After the plant upgrade, the maintenance related to the high frequency screens was eliminated and an additional 2.27 tons per hour (tph) of fine coal was recovered, which resulted in a payback period of less than one year. The article was adapted from a paper presented at Coal Prep 2007 in April 2007, Lexington, KY, USA. 1 ref., 1 fig., 1 tab.

  19. Inventory of landslides in southern Illinois near the New Madrid Seismic Zone and the possible failure mechanism at three sites

    SciTech Connect (OSTI)

    Su, Wen June . Engineering Geology Section)

    1992-01-01

    A total of 221 landslides was inventoried along a 200-kilometer reach of the Ohio and the Mississippi Rivers from Olmsted to Chester, IL using Side-Looking Airborne Radar imagery, vertical, stereoscopic, black and white aerial photography at various scales, and low altitude, oblique color and color infrared photography. Features observed on aerial photographs were used to classify landslides into three types (rock/debris fall, block slide, and rotational/translational slide) at three levels of confidence: certain, probable, or possible. Some landslides combined two or more types at a single site. Only a few of the landslides showed evidence of repeated activity; most are ancient landforms. Most of the landslides were developed in the loess, alluvium, colluvium, and weak clay layers of the Chesterian Series or in the Porter's Creek Clay and McNairy Formation. Failure of three representative landslides was modeled under static (aseismic) and dynamic (seismic) situations using three different sliding mechanisms. Both the pseudo-static method and a simplified method of the Newmark displacement analysis were used to determine the stability of the slope under earthquake conditions. The three representative landslides selected for detailed slope stability analysis were the Ford Hill, Jones Ridge, and Olmsted landslides. The Ford Hill and Jones Ridge landslides have similar slope geometries. Their modes of failure were recognized as a translational block slide on a weak clay layer. The Olmsted landslide is a complex of several rotational slides of different ages and a mega block slide on weak clay layers. The stability analyses of these three landslides suggest that they would not have occurred under aseismic conditions. However, under earthquake loadings similar to those generated by the 1811-12 earthquakes, most of the slopes could have experienced large displacements leading to landslide initiation.

  20. Welcome to this Issue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Welcome National Security Science Latest Issue:July 2015 past issues All Issues » submit Welcome to this Issue The nation's scientific credibility now plays a key role in national security and nuclear deterrence in an increasingly dangerous and unstable world. July 1, 2015 Welcome to this Issue Craig Leasure Contact Managing Editor Clay Dillingham Email The world remains a dangerous and unstable place, as Russia rattles its sabers, North Korea seems intent on developing intercontinental

  1. RPSEA REPORT PROCEDURES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RPSEA Final Technical Report 08121.2201.02.FINAL Heavy Viscous Oil Pressure, Volume, and Temperature 08121-2201-02 February 4, 2015 Hongying Zhao Project Manager, PhD, PEng Schlumberger, DBR Technology Center 9450, 17 Avenue NW, Edmonton, T6N 1M9, Canada (On behalf of Schlumberger Technology Corporation, 333 Clay Street, Suite 1900, Houston, TX, 77002, USA) 2 LEGAL NOTICE This report was prepared by Schlumberger Technology Corporation as an account of work sponsored by the Research Partnership

  2. Iron-titanium-mischmetal alloys for hydrogen storage

    DOE Patents [OSTI]

    Sandrock, Gary Dale (Ringwood, NJ)

    1978-01-01

    A method for the preparation of an iron-titanium-mischmetal alloy which is used for the storage of hydrogen. The alloy is prepared by air-melting an iron charge in a clay-graphite crucible, adding titanium and deoxidizing with mischmetal. The resultant alloy contains less than about 0.1% oxygen and exhibits a capability for hydrogen sorption in less than half the time required by vacuum-melted, iron-titanium alloys.

  3. All Issues

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    All Issues All Issues Bi-monthly publication connecting our alumni with news, information and former colleagues from the Lab. Archive - 2015 September July May March January Archive - 2014 November September June Publications 1663 Actinide Research Quarterly (ARQ) AlumniLink Publications Archive Connections National Security Science Strategic Plan VISTAS Contact Us Annual Report Matt Nerzig (505) 665-9178 Email 1663 Magazine Craig Tyler (505) 667-1447 Email National Security Science Clay

  4. Photocathode Device Using Diamondoid and Cesium Bromide Films (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Journal Article: Photocathode Device Using Diamondoid and Cesium Bromide Films Citation Details In-Document Search Title: Photocathode Device Using Diamondoid and Cesium Bromide Films Authors: Clay, William A.:a Juan R.Maldonado ; Pianetta, Piero ; Dahl, Jeremy E.P. ; Carlson, Robert M.K. ; Schreiner, Peter R. ; Fokin, Andrey A. ; Tkachenko, Boryslav A. ; Melosh, Nicholas A. ; Shen, Zhi-Xun Publication Date: 2014-09-23 OSTI Identifier: 1158622 Report Number(s):

  5. Isolation and microbial reduction of Fe(III) phyllosilicates from

    Office of Scientific and Technical Information (OSTI)

    subsurface sediments (Journal Article) | SciTech Connect Isolation and microbial reduction of Fe(III) phyllosilicates from subsurface sediments Citation Details In-Document Search Title: Isolation and microbial reduction of Fe(III) phyllosilicates from subsurface sediments Fe(III)-bearing phyllosilicates can be important sources of Fe(III) for dissimilatory microbial iron reduction in clay-rich anoxic soils and sediments. The goal of this research was to isolate Fe(III) phyllosilicate

  6. Introduction to computed microtomography and applications in Earth science

    Office of Scientific and Technical Information (OSTI)

    (Book) | SciTech Connect Introduction to computed microtomography and applications in Earth science Citation Details In-Document Search Title: Introduction to computed microtomography and applications in Earth science Authors: Rivers, M. [1] + Show Author Affiliations (UC) Publication Date: 2014-12-22 OSTI Identifier: 1168409 Resource Type: Book Resource Relation: Related Information: CMS Workshop Lectures, Advanced Applications of Synchrotron Radiation in Clay Science Publisher: 2014; Tha

  7. http://www.lvvwd.com/about/wr_groundwater.html

    National Nuclear Security Administration (NNSA)

    Water Resources » Groundwater About 10 percent of the Las Vegas Valley's water comes from groundwater, which is a water supply under the Earth's surface. In some areas, water fills the spaces throughout porous bedrock, alluvial gravels, sands, silts and clays to form a natural reservoir. Groundwater occurs as part of the hydrologic cycle, which is the movement of water between the earth and the atmosphere through evaporation and precipitation. The underground area where groundwater exists is

  8. U.S. and Mongolia Sign MOU to Increase Cooperation in Preventing Nuclear

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Smuggling | Department of Energy Mongolia Sign MOU to Increase Cooperation in Preventing Nuclear Smuggling U.S. and Mongolia Sign MOU to Increase Cooperation in Preventing Nuclear Smuggling October 23, 2007 - 3:21pm Addthis WASHINGTON, DC - Today the governments of the United States and Mongolia strengthened their efforts in the fight against nuclear terrorism. U.S. Deputy Secretary of Energy Clay Sell and Mongolia's Minister of Finance Nadmid Bayartsaikhan signed a Memorandum of

  9. Rad-Release

    ScienceCinema (OSTI)

    None

    2013-05-28

    The R&D 100 Award winning Rad-Release Chemical Decontamination Technology is a highly effective (up to 99% removal rate), affordable, patented chemical-foam-clay decontamination process tailored to specific radiological and metal contaminants, which is applicable to a wide variety of substrates. For more information about this project, visit http://www.inl.gov/rd100/2011/rad-release/

  10. Apostolos Enotiadis > Postdoc - Giannelis Group > Researchers, Postdocs &

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Graduates > The Energy Materials Center at Cornell Apostolos Enotiadis Postdoc - Giannelis Group ae176@cornell.edu Born in Chalkida, Greece, Apostolos graduated from the Materials Science and Engineering Department at Ioannina University in Greece and completed his Master's degree (Onassis Foundation Scholarship) and PhD (Academy of Athens Scholarship) in 2011 at the same University. His research involved the synthesis and characterization of hybrid layered materials (clays, graphene

  11. Generalized thickness and configuration of the top of the intermediate aquifer, West-Central Florida

    SciTech Connect (OSTI)

    Corral, M.A. Jr.; Wolansky, R.M.

    1984-01-01

    The water-bearing units of the intermediate aquifer consist of discontinuous sand, gravel, shell, and limestone and dolomite beds in the Tamiami Formation of late Miocene age and the Hawthorn Formation of middle Miocene age. Within parts of Polk, Manatee, Hardee, De Soto, Sarasota, and Charlotte Counties, sand and clay beds within the Tampa Limestone that are hydraulically connected to the Hawthorn Formation are also included in the intermediate aquifer. 15 refs.

  12. Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Temperatures - Energy Innovation Portal Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low Temperatures National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication S-126827 (Organoclay Sorbent).pdf (292 KB) Technology Marketing Summary By incorporating amines inside clay containing quaternary ammonium salts (organoclay) minerals, this invention has created a way to prepare sorbents that capture carbon dioxide (CO2)

  13. Geochemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Research/Basic Energy Sciences/Geochemistry - Geochemistryadmin2015-04-15T14:39:13+00:00 From Surfaces to Interlayers to Clusters Objective clay-ion Molecular-scale understanding of processes at mineral-water interfaces including adsorption at mineral surfaces in soils and sediments to characterize and develop predictive models of atomic and molecular structures, wetting, adsorption, redox, and other processes. Tasks Molecular Simulation and Spectroscopy of Dynamical Processes at

  14. Batch compositions for cordierite ceramics

    DOE Patents [OSTI]

    Hickman, David L. (Big Flats, NY)

    1994-07-26

    Ceramic products consisting principally of cordierite and a method for making them are provided, the method employing batches comprising a mineral component and a chemical component, the mineral component comprising clay and talc and the chemical component consisting essentially of a combination of the powdered oxides, hydroxides, or hydrous oxides of magnesium, aluminum and silicon. Ceramics made by extrusion and firing of the batches can exhibit low porosity, high strength and low thermal expansion coefficients.

  15. Microsoft PowerPoint - Hydropower conf SDOX June 2008 final [Compatibility Mode]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supersaturated Dissolved Oxygen (SDOX(tm)) Delivery Technology at Norfork Dam Delivery Technology at Norfork Dam Scott Osborn Chief Technology Officer Scott Osborn, Chief Technology Officer Clay Thompson, Senior Engineer Southwestern Federal Hydropower Conference June 12, 2008 BlueInGreen, LLC 535 W. Research Blvd. Fayetteville, AR 72701 (479) 527 6378 , (479) 527-6378 Background Background  Thanks to Marshall Boyken, Southwestern Power Administration Tulsa for inviting us and setting this up

  16. Zeolite-templated Pt/C electrocatalysts (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Zeolite-templated Pt/C electrocatalysts Citation Details In-Document Search Title: Zeolite-templated Pt/C electrocatalysts In an effort to reduce the amount of platinum required in low temperature fuel cells, we have prepared electrocatalysts of platinum nanoparticles-on-carbon through zeolite-templating methods. Several different zeolite structure-types, as well as clays and mesoporous silicas were investigated as hosts for the preparation of small Pt clusters through thermal decomposition of

  17. Introduction and Purpose

    Office of Legacy Management (LM)

    Addendum: Tritium Transport at the Rulison Site, a Nuclear-stimulated Low-permeability Natural Gas Reservoir prepared by Clay A. Cooper, Ming Ye, and Jenny B. Chapman Desert Research Institute Nevada System of Higher Education And Rex Hodges S.M. Stoller Corporation submitted to S.M.Stoller Corporation Office of Legacy Management U.S. Department of Energy Grand Junction, Colorado January 2009 Executive Summary Project Rulison, located in western Colorado, was the site of a subsurface nuclear

  18. Letter report to Pete Sanders, DOE:

    Office of Legacy Management (LM)

    Letter Report Scoping Analysis of Gas Phase Transport from the Rulison Underground Nuclear Test prepared by Clay Cooper Division of Hydrologic Sciences Desert Research Institute University and Community College System of Nevada submitted to Nevada Site Office National Nuclear Security Administration U.S. Department of Energy Las Vegas, Nevada May 6, 2004 _______________________________ The work upon which this report is based was supported by the U.S. Department of Energy under Contract

  19. Microsoft Word - 0905_rev0.doc

    Office of Legacy Management (LM)

    Environmental Programs, Oakland, California Weiss Associates Environmental Science, Engineering and Management ANNUAL SITE ENVIRONMENTAL REPORT CALENDAR YEAR 2004 for the LABORATORY FOR ENERGY-RELATED HEALTH RESEARCH UNIVERSITY OF CALIFORNIA, DAVIS Submitted to: United States Department of Energy Oakland Environmental Programs 1301 Clay Street Oakland, California 94612-5208 Prepared by: Weiss Associates 5801 Christie Avenue, Suite 600 Emeryville, California 94608-1827 September 22, 2005 Rev. 0

  20. Microsoft Word - RC_fnl.doc

    Office of Legacy Management (LM)

    Operations Office, Oakland, California Weiss Associates Environmental Science, Engineering and Management SITE-WIDE RISK ASSESSMENT, VOLUME I: HUMAN HEALTH RISK ASSESSMENT (PART B-RISK CHARACTERIZATION FOR DOE AREAS) at the: LABORATORY FOR ENERGY-RELATED HEALTH RESEARCH UNIVERSITY OF CALIFORNIA, DAVIS Prepared for: United States Department of Energy Oakland Environmental Programs 1301 Clay Street Oakland, California 94612-5208 Prepared by: Weiss Associates 5801 Christie Avenue, Suite 600

  1. Microsoft Word - rul_rpt.09.20.2010

    Office of Legacy Management (LM)

    Letter Report Update of Tritium Transport Calculations for the Rulison Site: Report of Activities and Results During 2009 - 2010 prepared by Clay A. Cooper, Jenny B. Chapman, Yong Zhang (Desert Research Institute, Nevada System of Higher Education) Rex Hodges (Stoller-Grand Junction) Ming Ye (Florida State University) submitted to S.M. Stoller Corporation Office of Legacy Management U.S. Department of Energy Grand Junction, Colorado September 2010 _______________________________________ The work

  2. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1988-05-26

    A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

  3. Repository Reference Disposal Concepts and Thermal Load Management Analysis

    Energy Savers [EERE]

    | Department of Energy Repository Reference Disposal Concepts and Thermal Load Management Analysis Repository Reference Disposal Concepts and Thermal Load Management Analysis A disposal concept consists of three parts: waste inventory (7 waste types examined), geologic setting (e.g., clay/shale, salt, crystalline, other sedimentary), and the engineering concept of operations (range of generic operational concepts examined). Two major categories for waste package emplacement modes are

  4. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

    1990-01-01

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  5. Status of UFD Campaign International Activities in Disposal Research |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Status of UFD Campaign International Activities in Disposal Research Status of UFD Campaign International Activities in Disposal Research Several international organizations have made significant progress in the characterization and performance evaluation of other disposal design options and host rock characteristics (clay/shale, granite), most of which were very different from those studied in the United States. The DOE recognizes that close international collaboration

  6. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1990-03-13

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  7. Generic Disposal System Modeling, Fiscal Year 2011 Progress Report |

    Office of Environmental Management (EM)

    Department of Energy Disposal System Modeling, Fiscal Year 2011 Progress Report Generic Disposal System Modeling, Fiscal Year 2011 Progress Report The UFD Campaign is developing generic disposal system models (GDSM) of different disposal environments and waste form options. Currently, the GDSM team is investigating four main disposal environment options: mined repositories in three geologic media (salt, clay, and granite) and the deep borehole concept in crystalline rock (DOE 2010d). Further

  8. PROJECT PROFILE: GeoCF LLC (Incubator 10) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GeoCF LLC (Incubator 10) PROJECT PROFILE: GeoCF LLC (Incubator 10) Project Title: Smart Power Maps Funding Opportunity: SunShot Technology to Market (Incubator 10) SunShot Subprogram: Technology to Market Location: Austin, TX Amount Awarded: $773,500 Awardee Cost Share: $773,500 Project Investigator: Clay Butler GeoCF's Smart Power Maps solution is a comprehensive software platform for utility-scale solar project evaluation and development. Smart Power Maps gives solar developers, utilities, and

  9. Hualapai Tribe - Hualapai Renewable Energy Development

    Office of Environmental Management (EM)

    Hualapai Renewable Energy Development DOE-Tribal Energy Program Peer Review Meeting 2012 The Hualapai Reservation Hualapai Project Description l Wind Farm Development - 200MW Grand Canyon West l Solar Power Plant Development - 50MW - Clay Springs - 30-40MW - Nelson l Community Solar - 1MW - GCW Hualapai Status l Completing the Final Feasibility Report - For Tribal Council - For Wind Developers - For Solar Developers l Wrap Up Activities - Critical Issues Analysis - Avian Studies -

  10. Workshop on Condensing Heating and Water Heating Equipment

    Broader source: Energy.gov (indexed) [DOE]

    Workshop on Condensing Heating and Water Heating Equipment Thursday, October 9, 2014 List of Attendees Organization/Attendees DOE - John Cymbalsky - Ashley Armstrong - Johanna Hariharan AGA - Kathryn Clay - Rick Murphy - Lisa Dundon APGA - Dave Schryver - Bud Miller Gas Technology Institute - Neil Leslie Washington Gas Light - Melissa Adams - Kevin Dunn ACEEE - Harvey Sachs ASAP - Andrew deLaski ASE - Rodney Sobin NRDC - Elizabeth Noll AHRI - Frank Stanonik ACCA - Charlie McCrudden - Glenn

  11. Modeling Fluid Flow in Natural Systems, Model Validation and Demonstration

    Office of Environmental Management (EM)

    | Department of Energy Modeling Fluid Flow in Natural Systems, Model Validation and Demonstration Modeling Fluid Flow in Natural Systems, Model Validation and Demonstration Clay and granitic units are potential host media for future repositories for used nuclear fuel. The report addresses the representation and characterization of flow in these two media within numerical process models. In low permeability crystalline rock, flow is primarily in relatively sparse networks of fractures.

  12. Disposal Systems Evaluations and Tool Development - Engineered Barrier

    Office of Environmental Management (EM)

    System (EBS) Evaluation | Department of Energy Disposal Systems Evaluations and Tool Development - Engineered Barrier System (EBS) Evaluation Disposal Systems Evaluations and Tool Development - Engineered Barrier System (EBS) Evaluation The engineered barrier system (EBS) plays a key role in the long-term isolation of nuclear waste in geological repository environments. This report focuses on the progress made in the evaluation of EBS design concepts, assessment of clay phase stability at

  13. Simulations of the quart (101-bar1)/water interface: A comparison of classical force fields, ab initi molecular dynamics, and x-ray reflectivity experiments.

    SciTech Connect (OSTI)

    Skelton, Adam; Fenter, Paul; Kubicki, James D.; Wesolowski, David J; Cummings, Peter T

    2011-01-01

    Classical molecular dynamics (CMD) simulations of the (1011) surface of quartz interacting with bulk liquid water are performed using three different classical force fields, Lopes et al., ClayFF, and CHARMM water contact angle (CWCA), and compared to ab initio molecular dynamics (AIMD) and X-ray reflectivity (XR) results. The axial densities of the water and surface atoms normal to the surface are calculated and compared to previous XR experiments. Favorable agreement is shown for all the force fields with respect to the position of the water atoms. Analyses such as the radial distribution functions between water and hydroxyl atoms and the average cosine of the angle between the water dipole vector and the normal of the surface are also calculated for each force field. Significant differences are found between the different force fields from such analyses, indicating differing descriptions of the structured water in the near vicinity of the surface. AIMD simulations are also performed to obtain the water and hydroxyl structure for comparison among the predictions of the three classical force fields to better understand which force field is most accurate. It is shown that ClayFF exhibits the best agreement with the AIMD simulations for water hydroxyl radial distribution functions, suggesting that ClayFF treats the hydrogen bonding more accurately.

  14. Mineralogic Zonation Within the Tuff Confining Unit, Yucca Flat, Nevada Test Site

    SciTech Connect (OSTI)

    Lance Prothro

    2005-09-01

    Recently acquired mineralogic data from drill hole samples in Yucca Flat show that the tuff confining unit (TCU) can be subdivided into three mineralogic zones based on the relative abundances of primary and secondary mineral assemblages. These zones are (1) an upper zone characterized by the abundance of the zeolite mineral clinoptilolite with lesser amounts of felsic and clay minerals; (2) a middle zone with felsic minerals dominant over clinoptilolite and clay minerals; and (3) a basal argillic zone where clay minerals are dominant over felsic minerals and clinoptilolite. Interpretation of the mineralogic data, along with lithologic, stratigraphic, and geophysical data from approximately 500 drill holes, reveals a three-layer mineralogic model for the TCU that shows all three zones are extensive beneath Yucca Flat. The mineralogic model will be used to subdivide the TCU in the Yucca Flat hydrostratigraphic framework model, resulting in a more accurate and versatile framework model. In addition, the identification of the type, quantity, and distribution of minerals within each TCU layer will permit modelers to better predict the spatial distribution and extent of contaminant transport from underground tests in Yucca Flat, at both the level of the hydrologic source term and the corrective action unit.

  15. Evaluation of ceramic filter material, selection for application

    SciTech Connect (OSTI)

    Alvin, M.A.; Tressler, R.E.; Lippert, T.E.; Diaz, E.S.

    1993-09-01

    Field testing in several of the Westinghouse Advanced Particulate Filtration (APF) systems has indicated that the oxide-based materials are more susceptible to thermal shock which results from system transients (i.e., combustion of char or reducing gases; system startup/turbine transients). The current clay bonded silicon carbide filter materials have a higher thermal shock resistance, but appear to be more susceptible to high temperature creep, as well as to changes that occur within the binder phase(s). Strength has frequently been used to assess what effects advanced coal fired process systems have on the stability and projected life of the various porous ceramic filter materials (Tables 1 and 2). Based on the numerous phase changes that occur, and the influence of pulse cleaning on the thermal fatigue characteristics of both the alumina/mullite and clay bonded silicon carbide filter materials, alternate material properties as thermal conductivity, thermal coefficient of expansion, elastic modulus, fracture toughness, and emissivity as a function of thermal/chemical aging are now being considered as critical factors for projecting filter durability and operating life. Table 3 provides a summary of the as-manufactured material properties for the alumina/mullite and clay bonded silicon carbide filter materials which have been used in the Westinghouse`s APF systems. Effort is currently being directed to determine how these properties change during thermal aging of the filters in various subpilot and pilot plant systems.

  16. Influence of impurities on the creep of salt from the Palo Duro Basin

    SciTech Connect (OSTI)

    Hansen, F.D.; Senseny, P.E.; Pfeifle, T.W.; Vogt, T.J.

    1987-05-01

    Twelve triaxial compression creep tests were performed on salt specimens from the Woods-Holtzclaw well in the Palo Duro Basin to assess the influence of impurities on creep deformation. Four nominal impurity levels were initially selected for investigation: pure salt, salt containing 10% anhydrite, salt containing 10% mud, and salt containing 20% mud. Subsequent petrological measurements show these idealized categories do not exist. Composition of the samples was measured by methods of wet chemistry coupled with ethylene diaminetetraacetic acid (EDTA) digestion and point counting on full-size polished sections. Overall, the 12 specimens comprise 71.6--96.6% halite, 2.4--7.5% anhydrite, and 0.2--24.7% clay. Nine of the 12 specimens are similar to many other tested specimens from the Lower San Andres Unit 5. They range from 90--97% halite and average 94% with a standard deviation of 2%. The remaining 6% impurities are disseminated clay and anhydrite. The other three specimens from the Lower San Andres Unit 4 contain large amounts (average 20%) of uniformly distributed clays and average only 75% halite. 11 refs., 21 figs., 5 tabs.

  17. Eddy-driven sediment transport in the Argentine Basin: Is the height of the Zapiola Rise hydrodynamically controlled?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Weijer, Wilbert; Maltrud, Mathew E.; Homoky, William B.; Polzin, Kurt L.; Maas, Leo R. M.

    2015-03-27

    In this study, we address the question whether eddy-driven transports in the Argentine Basin can be held responsible for enhanced sediment accumulation over the Zapiola Rise, hence accounting for the existence and growth of this sediment drift. To address this question, we perform a 6 year simulation with a strongly eddying ocean model. We release two passive tracers, with settling velocities that are consistent with silt and clay size particles. Our experiments show contrasting behavior between the silt fraction and the lighter clay. Due to its larger settling velocity, the silt fraction reaches a quasisteady state within a few years,more » with abyssal sedimentation rates that match net input. In contrast, clay settles only slowly, and its distribution is heavily stratified, being transported mainly along isopycnals. Yet, both size classes display a significant and persistent concentration minimum over the Zapiola Rise. We show that the Zapiola Anticyclone, a strong eddy-driven vortex that circulates around the Zapiola Rise, is a barrier to sediment transport, and hence prevents significant accumulation of sediments on the Rise. We conclude that sediment transport by the turbulent circulation in the Argentine Basin alone cannot account for the preferred sediment accumulation over the Rise. We speculate that resuspension is a critical process in the formation and maintenance of the Zapiola Rise.« less

  18. Eddy-driven sediment transport in the Argentine Basin: Is the height of the Zapiola Rise hydrodynamically controlled?

    SciTech Connect (OSTI)

    Weijer, Wilbert; Maltrud, Mathew E.; Homoky, William B.; Polzin, Kurt L.; Maas, Leo R. M.

    2015-03-27

    In this study, we address the question whether eddy-driven transports in the Argentine Basin can be held responsible for enhanced sediment accumulation over the Zapiola Rise, hence accounting for the existence and growth of this sediment drift. To address this question, we perform a 6 year simulation with a strongly eddying ocean model. We release two passive tracers, with settling velocities that are consistent with silt and clay size particles. Our experiments show contrasting behavior between the silt fraction and the lighter clay. Due to its larger settling velocity, the silt fraction reaches a quasisteady state within a few years, with abyssal sedimentation rates that match net input. In contrast, clay settles only slowly, and its distribution is heavily stratified, being transported mainly along isopycnals. Yet, both size classes display a significant and persistent concentration minimum over the Zapiola Rise. We show that the Zapiola Anticyclone, a strong eddy-driven vortex that circulates around the Zapiola Rise, is a barrier to sediment transport, and hence prevents significant accumulation of sediments on the Rise. We conclude that sediment transport by the turbulent circulation in the Argentine Basin alone cannot account for the preferred sediment accumulation over the Rise. We speculate that resuspension is a critical process in the formation and maintenance of the Zapiola Rise.

  19. Molecular dynamics simulations of the electrical double layer on smectite surfaces contacting concentrated mixed electrolyte (NaCl-CaCl?) solutions

    SciTech Connect (OSTI)

    Bourg, Ian C.; Sposito, Garrison

    2011-01-01

    We report new molecular dynamics results elucidating the structure of the electrical double layer (EDL) on smectite surfaces contacting mixed NaClCaCl2 electrolyte solutions in the range of concentrations relevant to pore waters in geologic repositories for CO2 or high-level radioactive waste (0.341.83 molc dm-3). Our results confirm the existence of three distinct ion adsorption planes (0-, ?-, and d-planes), often assumed in EDL models, but with two important qualifications: (1) the location of the ?- and d-planes are independent of ionic strength or ion type and (2) indifferent electrolyte ions can occupy all three planes. Charge inversion occurred in the diffuse ion swarm because of the affinity of the clay surface for CaCl+ ion pairs. Therefore, at concentrations {>=0.34 molc dm-3}, properties arising from long-range electrostatics at interfaces (electrophoresis, electro-osmosis, co-ion exclusion, colloidal aggregation) will not be correctly predicted by most EDL models. Co-ion exclusion, typically neglected by surface speciation models, balanced a large part of the clay mineral structural charge in the more concentrated solutions. Water molecules and ions diffused relatively rapidly even in the first statistical water monolayer, contradicting reports of rigid ice-like structures for water on clay mineral surfaces.

  20. Pyramiding tumuli waste disposal site and method of construction thereof

    DOE Patents [OSTI]

    Golden, Martin P. (Hamburg, NY)

    1989-01-01

    An improved waste disposal site for the above-ground disposal of low-level nuclear waste as disclosed herein. The disposal site is formed from at least three individual waste-containing tumuli, wherein each tumuli includes a central raised portion bordered by a sloping side portion. Two of the tumuli are constructed at ground level with adjoining side portions, and a third above-ground tumulus is constructed over the mutually adjoining side portions of the ground-level tumuli. Both the floor and the roof of each tumulus includes a layer of water-shedding material such as compacted clay, and the clay layer in the roofs of the two ground-level tumuli form the compacted clay layer of the floor of the third above-ground tumulus. Each tumulus further includes a shield wall, preferably formed from a solid array of low-level handleable nuclear wate packages. The provision of such a shield wall protects workers from potentially harmful radiation when higher-level, non-handleable packages of nuclear waste are stacked in the center of the tumulus.

  1. Integrated geologic/engineering study of Kurten field waterflood project

    SciTech Connect (OSTI)

    Gay, A.L.

    1989-03-01

    An integrated interpretation of petrographic, geochemical, engineering, and electric-log data is used to evaluate a current waterflood project in Kurten field, Brazos County, Texas. Petrographic studies reveal three sand facies deposited in a dynamic sand ridge environment. Although electric-log porosity is relatively constant throughout the sand body, SEM, thin-section, and engineering profile studies reveal the clean well-sorted sand facies to be impermeable due to quartz overgrowths. A quartz-rich bioturbated sand is identified as the reservoir facies, having fewer quartz overgrowths and more authigenic clays. The third sand facies, a clay-rich bioturbated sand, is impermeable due to an overabundance of authigenic and detrital clays. Engineering and production data support this interpretation. A comparison of hydrocarbon composition of the oils using capillary gas chromatography supports the conclusion that the well-sorted clean sand contains many permeability barriers and is not a continuous reservoir conductive to waterflooding. Interactive computer interpretation of electric logs, using a combination of sonic and density porosities, deep resistivity, and SP, allows the mapping of the sand facies. Water saturation and net oil-in-place maps reveal the best portions of the field on which to focus the revised waterflood project. This revision should concentrate on the quartz-rich bioturbated sand in the central portion of the original unit to result in a more efficient, economical, secondary recovery program.

  2. Integrated geologic/engineering study of the Kurten Field waterflood

    SciTech Connect (OSTI)

    Gay, A.L. )

    1990-05-01

    An integrated interpretation of petrographic, geochemical, engineering, and electric-log data was used to evaluate a current waterflood project in Kurten field, Brazos County, Texas. Petrographic studies reveal three sand facies deposited in a dynamic sand ridge environment. Although electric-log porosity is relatively constant throughout the sand body, scanning electron microscope thin section and engineering profile studies reveal the clean well-sorted sand facies to be impermeable due to quartz overgrowths. A quartz-rich bioturbated sand is identified as the reservoir facies, having fewer quartz overgrowths and more authigenic clays. The third sand facies, a clay-rich bioturbated sand, is impermeable due to an overabundance of authigenic and detrital clays. Engineering and production data support this interpretation. A comparison of hydrocarbon composition of the oils, using capillary gas chromatography, supports the conclusion that the well-sorted clean sand contains many permeability barriers and is not a continuous reservoir conducive to waterflooding. Interactive computer interpretation of electric logs, using a combination of sonic and density porosities, deep resistivity, and spontaneous potential, allows the mapping of the sand facies. Water saturations and net oil in place maps reveal the best parts of the field on which to focus the revised waterflood project. This revision should concentrate on the quartz-rich bioturbated sand in the central part of the original unit to result in a more efficient economical secondary recovery program.

  3. Passive recovery of DNAPL from clayey soil via vertical collection wells

    SciTech Connect (OSTI)

    Tease, B.; Gagnon, D.

    1995-12-01

    A release of dense non-aqueous phase liquids (DNAPL) from two underground storage tanks (USTs), created a contaminant plume that extended approximately 30 feet into lacustrine sediments comprised mainly of varved clay. Subsurfaces investigations indicated that the release was comprised primarily of the chlorinated solvent Trichloroethene which had migrated horizontally approximately 250 feet cross-gradient to groundwater flow. A relatively narrow zone of free phase product extended from the UST area approximately 150-200 feet along the plume of migration at a depth of 20-30 feet below the ground surface. Since clay varves interconnected by vertical fractures is believed to have facilitated the DNAPL migration, 4{close_quotes} diameter stainless steel collection recovery of 10-20 quarts of DNAPL per each collection event, over a 4 month period supported what is believed to be preferential DNAPL migration. DNAPL recovery continued for a total of 6 months before the point of diminimus return (1-2 quarts/month) resulted in adopting a quarterly recovery schedule. To date, 201 quarts of free phase DNAPL have been recovered. DNAPL mobility, delineation, well installation and collection techniques are discussed. Compared to conventional remediation alternatives, this passive recovery system provides an innovative approach to a difficult and costly problem; recovery of DNAPL isolated within clay.

  4. The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California

    SciTech Connect (OSTI)

    Maher, K.; Steefel, C. I.; White, A.F.; Stonestrom, D.A.

    2009-02-25

    In order to explore the reasons for the apparent discrepancy between laboratory and field weathering rates and to determine the extent to which weathering rates are controlled by the approach to thermodynamic equilibrium, secondary mineral precipitation and flow rates, a multicomponent reactive transport model (CrunchFlow) was used to interpret soil profile development and mineral precipitation and dissolution rates at the 226 ka marine terrace chronosequence near Santa Cruz, CA. Aqueous compositions, fluid chemistry, transport, and mineral abundances are well characterized (White et al., 2008, GCA) and were used to constrain the reaction rates for the weathering and precipitating minerals in the reactive transport modeling. When primary mineral weathering rates are calculated with either of two experimentally determined rate constants, the nonlinear, parallel rate law formulation of Hellmann and Tisser and [2006] or the aluminum inhibition model proposed by Oelkers et al. [1994], modeling results are consistent with field-scale observations when independently constrained clay precipitation rates are accounted for. Experimental and field rates, therefore, can be reconciled at the Santa Cruz site. Observed maximum clay abundances in the argillic horizons occur at the depth and time where the reaction fronts of the primary minerals overlap. The modeling indicates that the argillic horizon at Santa Cruz can be explained almost entirely by weathering of primary minerals and in situ clay precipitation accompanied by undersaturation of kaolinite at the top of the profile. The rate constant for kaolinite precipitation was also determined based on model simulations of mineral abundances and dissolved Al, SiO{sub 2}(aq) and pH in pore waters. Changes in the rate of kaolinite precipitation or the flow rate do not affect the gradient of the primary mineral weathering profiles, but instead control the rate of propagation of the primary mineral weathering fronts and thus total mass removed from the weathering profile. Our analysis suggests that secondary clay precipitation is as important as aqueous transport in governing the amount of dissolution that occurs within a profile because clay minerals exert a strong control over the reaction affinity of the dissolving primary minerals. The modeling also indicates that the weathering advance rate and the total mass of mineral dissolved is controlled by the thermodynamic saturation of the primary dissolving phases plagioclase and K-feldspar, as is evident from the difference in propagation rates of the reaction fronts for the two minerals despite their very similar kinetic rate laws.

  5. Generic Argillite/Shale Disposal Reference Case

    SciTech Connect (OSTI)

    Zheng, Liange; Colon, Carlos Jov; Bianchi, Marco; Birkholzer, Jens

    2014-08-08

    Radioactive waste disposal in a deep subsurface repository hosted in clay/shale/argillite is a subject of widespread interest given the desirable isolation properties, geochemically reduced conditions, and widespread geologic occurrence of this rock type (Hansen 2010; Bianchi et al. 2013). Bianchi et al. (2013) provides a description of diffusion in a clay-hosted repository based on single-phase flow and full saturation using parametric data from documented studies in Europe (e.g., ANDRA 2005). The predominance of diffusive transport and sorption phenomena in this clay media are key attributes to impede radionuclide mobility making clay rock formations target sites for disposal of high-level radioactive waste. The reports by Hansen et al. (2010) and those from numerous studies in clay-hosted underground research laboratories (URLs) in Belgium, France and Switzerland outline the extensive scientific knowledge obtained to assess long-term clay/shale/argillite repository isolation performance of nuclear waste. In the past several years under the UFDC, various kinds of models have been developed for argillite repository to demonstrate the model capability, understand the spatial and temporal alteration of the repository, and evaluate different scenarios. These models include the coupled Thermal-Hydrological-Mechanical (THM) and Thermal-Hydrological-Mechanical-Chemical (THMC) models (e.g. Liu et al. 2013; Rutqvist et al. 2014a, Zheng et al. 2014a) that focus on THMC processes in the Engineered Barrier System (EBS) bentonite and argillite host hock, the large scale hydrogeologic model (Bianchi et al. 2014) that investigates the hydraulic connection between an emplacement drift and surrounding hydrogeological units, and Disposal Systems Evaluation Framework (DSEF) models (Greenberg et al. 2013) that evaluate thermal evolution in the host rock approximated as a thermal conduction process to facilitate the analysis of design options. However, the assumptions and the properties (parameters) used in these models are different, which not only make inter-model comparisons difficult, but also compromise the applicability of the lessons learned from one model to another model. The establishment of a reference case would therefore be helpful to set up a baseline for model development. A generic salt repository reference case was developed in Freeze et al. (2013) and the generic argillite repository reference case is presented in this report. The definition of a reference case requires the characterization of the waste inventory, waste form, waste package, repository layout, EBS backfill, host rock, and biosphere. This report mainly documents the processes in EBS bentonite and host rock that are potentially important for performance assessment and properties that are needed to describe these processes, with brief description other components such as waste inventory, waste form, waste package, repository layout, aquifer, and biosphere. A thorough description of the generic argillite repository reference case will be given in Jov Colon et al. (2014).

  6. Mitigation of Hydrogen Gas Generation from the Reaction of Uranium Metal with Water in K Basin Sludge and Sludge Waste Forms

    SciTech Connect (OSTI)

    Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

    2011-06-08

    Prior laboratory testing identified sodium nitrate and nitrite to be the most promising agents to minimize hydrogen generation from uranium metal aqueous corrosion in Hanford Site K Basin sludge. Of the two, nitrate was determined to be better because of higher chemical capacity, lower toxicity, more reliable efficacy, and fewer side reactions than nitrite. The present lab tests were run to determine if nitrate’s beneficial effects to lower H2 generation in simulated and genuine sludge continued for simulated sludge mixed with agents to immobilize water to help meet the Waste Isolation Pilot Plant (WIPP) waste acceptance drainable liquid criterion. Tests were run at ~60°C, 80°C, and 95°C using near spherical high-purity uranium metal beads and simulated sludge to emulate uranium-rich KW containerized sludge currently residing in engineered containers KW-210 and KW-220. Immobilization agents tested were Portland cement (PC), a commercial blend of PC with sepiolite clay (Aquaset II H), granulated sepiolite clay (Aquaset II G), and sepiolite clay powder (Aquaset II). In all cases except tests with Aquaset II G, the simulated sludge was mixed intimately with the immobilization agent before testing commenced. For the granulated Aquaset II G clay was added to the top of the settled sludge/solution mixture according to manufacturer application directions. The gas volumes and compositions, uranium metal corrosion mass losses, and nitrite, ammonia, and hydroxide concentrations in the interstitial solutions were measured. Uranium metal corrosion rates were compared with rates forecast from the known uranium metal anoxic water corrosion rate law. The ratios of the forecast to the observed rates were calculated to find the corrosion rate attenuation factors. Hydrogen quantities also were measured and compared with quantities expected based on non-attenuated H2 generation at the full forecast anoxic corrosion rate to arrive at H2 attenuation factors. The uranium metal corrosion rates in water alone and in simulated sludge were near or slightly below the metal-in-water rate while nitrate-free sludge/Aquaset II decreased rates by about a factor of 3. Addition of 1 M nitrate to simulated sludge decreased the corrosion rate by a factor of ~5 while 1 M nitrate in sludge/Aquaset II mixtures decreased the corrosion rate by ~2.5 compared with the nitrate-free analogues. Mixtures of simulated sludge with Aquaset II treated with 1 M nitrate had uranium corrosion rates about a factor of 8 to 10 lower than the water-only rate law. Nitrate was found to provide substantial hydrogen mitigation for immobilized simulant sludge waste forms containing Aquaset II or Aquaset II G clay. Hydrogen attenuation factors of 1000 or greater were determined at 60°C for sludge-clay mixtures at 1 M nitrate. Hydrogen mitigation for tests with PC and Aquaset II H (which contains PC) were inconclusive because of suspected failure to overcome induction times and fully enter into anoxic corrosion. Lessening of hydrogen attenuation at ~80°C and ~95°C for simulated sludge and Aquaset II was observed with attenuation factors around 100 to 200 at 1 M nitrate. Valuable additional information has been obtained on the ability of nitrate to attenuate hydrogen gas generation from solution, simulant K Basin sludge, and simulant sludge with immobilization agents. Details on characteristics of the associated reactions were also obtained. The present testing confirms prior work which indicates that nitrate is an effective agent to attenuate hydrogen from uranium metal corrosion in water and simulated K Basin sludge to show that it is also effective in potential candidate solidified K Basin waste forms for WIPP disposal. The hydrogen mitigation afforded by nitrate appears to be sufficient to meet the hydrogen generation limits for shipping various sludge waste streams based on uranium metal concentrations and assumed waste form loadings.

  7. Sediment Properties: E-Area Completion Project

    SciTech Connect (OSTI)

    Millings, M.; Bagwell, L.; Amidon, M.; Dixon, K.

    2011-04-29

    To accommodate a future need for additional waste disposal facilities at the Savannah River Site, the Solid Waste Management Division (SWMD) designated nine additional plots for development (Kasraii 2007; SRS 2010); these plots are collectively known as the E Area Completion Project (ECP). Subsurface samples were collected from ECP plots 6, 7, 8 and 9 (Figure 1) for chemical and physical property analyses to support Performance Assessment (PA) and Special Analyses (SA) modeling. This document summarizes the sampling and analysis scheme and the resultant data, and provides interpretations of the data particularly in reference to existing soil property data. Analytical data in this document include: gamma log, cone penetrometer log, grain size (sieve and hydrometer), water retention, saturated hydraulic conductivity (falling head permeameter), porosity, dry bulk density, total organic carbon, x-ray diffraction, and x-ray fluorescence data. SRNL provided technical and safety oversight for the fieldwork, which included completion of eight soil borings, four geophysical logs, and the collection of 522 feet of core and 33 Shelby tubes from ECP plots 6, 7, 8, and 9. Boart Longyear provided sonic drilling and logging services. Two soil borings were completed at each location. The first set of boreholes extended into (but did not fully penetrate) the Warley Hill Formation. These boreholes were continuously cored, then geophysically (gamma ray) logged. The recovered core was split, photographed, and described; one half of the core was archived at SRS's Core Lab facilities, and the remaining half was consumed as necessary for testing at SRS and off-site labs. Core descriptions and geophysical data were used to calculate target elevations for Shelby tube samples, which were obtained from the second set of boreholes. Shelby tubes were shipped to MACTEC Engineering and Consulting Inc. (MACTEC) in Atlanta for physical property testing. SRNL deployed their Site Characterization and Analysis Penetrometer System (SCAPS) cone penetrometer test (CPT) truck at ECP plots 6, 7, 8 and 9 to collect inferred lithology data for the vadose zone. Results from this study are used to make recommendations for future modeling efforts involving the ECP plots. The conceptual model of the ECP hydrogeology differs from the conceptual model of the current ELLWF disposal area in that for the ECP plots, the topography (ground surface) is generally lower in elevation; The Upland and top of Tobacco Road lithostratigraphic units are missing (eroded); The water table occurs lower in elevation (i.e., it occurs in lower stratigraphic units); and the Tan Clay Confining Zone (TCCZ) often occurs within the vadose zone (rather than in the saturated zone). Due to the difference in the hydrogeology between the current ELLWF location and the ECP plots, different vadose zone properties are recommended for the ECP plots versus the properties recommended by Phifer et al. (2006) for the current disposal units. Results from this study do not invalidate or conflict with the current PA's use of the Upper and Lower Vadose Zone properties as described by Phifer et al. (2006) for the current ELLWF disposal units. The following modeling recommendations are made for future modeling of the ECP plots where vadose zone properties are required: (1) If a single vadose zone property is preferred, the properties described by Phifer et al. (2006) for the Upper Vadose Zone encompass the general physical properties of the combined sands and clays in the ECP vadose zone sediments despite the differences in hydrostratigraphic units. (2) If a dual zone system is preferred, a combination of the Lower Zone properties and the Clay properties described by Phifer et al. (2006) are appropriate for modeling the physical properties of the ECP vadose zone. The Clay properties would be assigned to the Tan Clay Confining Zone (TCCZ) and any other significant clay layers, while the Lower Zone properties would be assigned for the remainder of the vadose zone. No immediate updates or changes are recommended for

  8. Geochemical information for sites contaminated with low-level radioactive wastes. III. Weldon Spring Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-02-01

    The Weldon Spring Storage Site (WSSS), which includes both the chemical site and the quarry, became radioactively contaminated as the result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the WSSS. This report describes the results of geochemical investigations carried out at Oak Ridge National Laboratory (ORNL) to support these activities and to help quantify various remedial action options. Soil and groundwater samples were characterized, and uranium and radium sorption ratios were measured in site soil/groundwater systems by batch contact methodology. Soil samples from various locations around the raffinate pits were found to contain major amounts of silica, along with illite as the primary clay constituent. Particle sizes of the five soil samples were variable (50% distribution point ranging from 12 to 81 ..mu..m); the surface areas varied from 13 to 62 m/sup 2//g. Elemental analysis of the samples showed them to be typical of sandy clay and silty clay soils. Groundwater samples included solution from Pit 3 and well water from Well D. Anion analyses showed significant concentrations of sulfate and nitrate (>350 and >7000 mg/L, respectively) in the solution from Pit 3. These anions were also present in the well water, but in lower concentrations. Uranium sorption ratios for four of the soil samples contacted with the solution from Pit 3 were moderate to high (approx. 300 to approx. 1000 mL/g). The fifth sample had a ratio of only 12 mL/g. Radium sorption ratios for the five samples were moderate to high (approx. 600 to approx. 1000 mL/g). These values indicate that soil at the WSSS may show favorable retardation of uranium and radium in the groundwater. 13 references, 13 figures, 10 tables.

  9. Investigating the Quartz (1010)/Water Interface using Classical and

    SciTech Connect (OSTI)

    Skelton, A A; Wesolowski, David J; Cummings, Peter T

    2011-01-01

    Two different terminations of the (1010) surface of quartz (R and ) interacting with water are simulated by classical (CMD) (using two different force fields) and ab initio molecular dynamics (AIMD) and compared with previously published X-ray reflectivity (XR) experiments. Radial distribution functions between hydroxyl and water show good agreement between AIMD and CMDusing the ClayFF force field for both terminations. The Lopes et al. (Lopes, P. E. M.; Murashov, V.; Tazi, M.; Demchuk, E.; MacKerell, A. D. J. Phys. Chem. B 2006, 110, 27822792) force field (LFF), however, underestimates the extent of hydroxylwater hydrogen bonding. The termination is found to contain hydroxylhydroxyl hydrogen bonds; the quartz surface hydroxyl hydrogens and oxygens that hydrogen bond with each other exhibit greatly reduced hydrogen bonding to water. Conversely, the hydroxyl hydrogen and oxygens that are not hydrogen bonded to other surface hydroxyls but are connected to those that are show a considerable amount of hydrogen bonding to water. The electron density distribution of an annealed surface of quartz (1010) obtained by XR is in qualitative agreement with electron densities calculated byCMDand AIMD. In all simulation methods, the interfacial water peak appears farther from the surface than observed by XR. Agreement among AIMD, LFF, and XR is observed for the relaxation of the near-surface atoms; however, ClayFF shows a larger discrepancy. Overall, results show that for both terminations of (1010), LFF treats the near-surface structure more accurately whereas ClayFF treats the interfacial water structure more accurately. It is shown that the number of hydroxyl and water hydrogen bonds to the bridging SiOSi oxygens connecting the surface silica groups to the rest of the crystal is much greater for the R than the termination. It is suggested that this may play a role in the greater resistance to dissolution of the termination than that of the R termination.

  10. FT-IR Study of CO2 Interaction with Na-rich Montmorillonite

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Krukowski, Elizabeth G; Goodman, Angela; Rother, Gernot; Ilton, Eugene; Guthrie, George; Bodnar, Robert

    2015-01-01

    Carbon capture, utilization and storage (CCUS) in saline reservoirs in sedimentary formations has the potential to reduce the impact of fossil fuel combustion on climate change by reducing CO2 emissions to the atmosphere and storing the CO2 in geologic formations in perpetuity. At pressure and temperature (PT) conditions relevant to CCUS, CO2 is less dense than the pre-existing brine in the formation, and the more buoyant CO2 will migrate to the top of the formation where it will be in contact with cap rock. Interactions between clay-rich shale cap rocks and CO2 are poorly understood at PT conditions appropriate formore » CCUS in saline formations. In this study, the interaction of CO2 with clay minerals in the cap rock overlying a saline formation has been examined using Na+ exchanged montmorillonite (Mt) (Na+-STx-1) (Na+ Mt) as an analog for clay-rich shale. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) was used to discern mechanistic information for CO2 interaction with hydrated (both one- and two-water layers) and relatively dehydrated (both dehydrated layers and one-water layers) Na+-STx-1 at 35 C and 50 C and CO2 pressure from 0 5.9 MPa. CO2-induced perturbations associated with the water layer and Na+-STx-1 vibrational modes such as AlAlOH and AlMgOH were examined. Data indicate that CO2 is preferentially incorporated into the interlayer space, with relatively dehydrated Na+-STx-1 capable of incorporating more CO2 compared to hydrated Na+-STx-1. Spectroscopic data provide no evidence of formation of carbonate minerals or the interaction of CO2 with sodium cations in the Na+-STx-1 structure.« less

  11. Computed solid phases limiting the concentration of dissolved constituents in basalt aquifers of the Columbia Plateau in eastern Washington. Geochemical modeling and nuclide/rock/groundwater interaction studies

    SciTech Connect (OSTI)

    Deutsch, W.J.; Jenne, E.A.; Krupka, K.M.

    1982-08-01

    A speciation-solubility geochemical model, WATEQ2, was used to analyze geographically-diverse, ground-water samples from the aquifers of the Columbia Plateau basalts in eastern Washington. The ground-water samples compute to be at equilibrium with calcite, which provides both a solubility control for dissolved calcium and a pH buffer. Amorphic ferric hydroxide, Fe(OH)/sub 3/(A), is at saturation or modestly oversaturated in the few water samples with measured redox potentials. Most of the ground-water samples compute to be at equilibrium with amorphic silica (glass) and wairakite, a zeolite, and are saturated to oversaturated with respect to allophane, an amorphic aluminosilicate. The water samples are saturated to undersaturated with halloysite, a clay, and are variably oversaturated with regard to other secondary clay minerals. Equilibrium between the ground water and amorphic silica presumably results from the dissolution of the glassy matrix of the basalt. The oversaturation of the clay minerals other than halloysite indicates that their rate of formation lags the dissolution rate of the basaltic glass. The modeling results indicate that metastable amorphic solids limit the concentration of dissolved silicon and suggest the same possibility for aluminum and iron, and that the processes of dissolution of basaltic glass and formation of metastable secondary minerals are continuing even though the basalts are of Miocene age. The computed solubility relations are found to agree with the known assemblages of alteration minerals in the basalt fractures and vesicles. Because the chemical reactivity of the bedrock will influence the transport of solutes in ground water, the observed solubility equilibria are important factors with regard to chemical-retention processes associated with the possible migration of nuclear waste stored in the earth's crust.

  12. Lunette dunes and yardangs of the Carson desert, Nevada: Implications for Holocene eolian activity in the northern Great Basin

    SciTech Connect (OSTI)

    Lancaster, N. (Desert Research Inst., Reno, NV (United States). Quaternary Sciences Center)

    1993-04-01

    A large complex of lunette dunes consisting of two and locally three ridges up to 40 m high occurs on the northeast margin of the Carson Sink playa. The outer, or north-easterly, ridge consists of a core of fine and coarse and partially cemented by saline clay and silt (Unit 1) with avalanche face cross-beds dipping to the north-east at 25--30[degree], as well as planar sets of wind ripple laminae with dips to both the northeast and west at 2--5[degree]. Overlying this unit on the crest and lee side of the ridge is 2--5 m of mobile poorly sorted, very fine and coarse sand that forms an active avalanche face up to 25 m high on the east side of the ridge (Unit 3). At a number of localities, the indurated core of the larger dune ridge is carved into yardanges, or streamlined small hills with a lemniscate shape that result from wind erosion of homogeneous sediments. The dunes overlie, with an erosional contact, Late Pleistocene saline lacustrine clays of paleolake Lahontan. They represent at least two episodes of mid- to late-Holocene deflation of sediments from the Carson Sink playa. Erosion of the dunes and yardang formation suggests: (1) termination of sediment supply from the playa as a result of reduced sediment supply and runoff from the Carson River, (2) cementation of the dunes by clay and silt accumulation, and (3) modern eolian erosion through flow acceleration on dune windward slopes.

  13. Preliminary Evaluation of Cesium Distribution for Wet Sieving Process Planned for Soil Decontamination in Japan - 13104

    SciTech Connect (OSTI)

    Enokida, Y.; Tanada, Y.; Hirabayashi, D.; Sawada, K.

    2013-07-01

    For the purpose of decontaminating radioactive cesium from a huge amount of soil, which has been estimated to be 1.2x10{sup 8} m{sup 3} by excavating to a 5-cm depth from the surface of Fukushima Prefecture where a severe nuclear accident occurred at TEPCO's power generating site and has emitted a significant amount of radioactive materials, mainly radioactive cesium, a wet sieving process was selected as one of effective methods available in Japan. Some private companies have demonstrated this process for soil treatment in the Fukushima area by testing at their plants. The results were very promising, and a full-fledged application is expected to follow. In the present study, we spiked several aqueous samples containing soil collected from an industrial wet sieving plant located near our university for the recycling of construction wastes with non-radioactive cesium hydroxide. The present study provides scientific data concerning the effectiveness in volume reduction of the contaminated soil by a wet sieving process as well as the cesium distribution between the liquid phase and clay minerals for each sub-process of the full-scale one, but a simulating plant equipped with a process of coagulating sedimentation and operational safety fundamentals for the plant. Especially for the latter aspect, the study showed that clay minerals of submicron size strongly bind a high content of cesium, which was only slightly removed by coagulation with natural sedimentation (1 G) nor centrifugal sedimentation (3,700 G) and some of the cesium may be transferred to the effluent or recycled water. By applying ultracentrifugation (257,000 G), most of submicron clay minerals containing cesium was removed, and the cesium amount which might be transferred to the effluent or recycled water, could be reduced to less than 2.3 % of the original design by the addition of a cesium barrier consisting of ultracentrifugation or a hollow fiber membrane. (authors)

  14. Lateral Earth Pressure at Rest and Shear Modulus Measurements on Hanford Sludge Simulants

    SciTech Connect (OSTI)

    Wells, Beric E.; Jenks, Jeromy WJ; Boeringa, Gregory K.; Bauman, Nathan N.; Guzman, Anthony D.; Arduino, P.; Keller, P. J.

    2010-09-30

    This report describes the equipment, techniques, and results of lateral earth pressure at rest and shear modulus measurements on kaolin clay as well as two chemical sludge simulants. The testing was performed in support of the problem of hydrogen gas retention and release encountered in the double- shell tanks (DSTs) at the Hanford Site near Richland, Washington. Wastes from single-shell tanks (SSTs) are being transferred to double-shell tanks (DSTs) for safety reasons (some SSTs are leaking or are in danger of leaking), but the available DST space is limited.

  15. Large-Scale Field Study of Landfill Covers at Sandia National Laboratories

    SciTech Connect (OSTI)

    Dwyer, S.F.

    1998-09-01

    A large-scale field demonstration comparing final landfill cover designs has been constructed and is currently being monitored at Sandia National Laboratories in Albuquerque, New Mexico. Two conventional designs (a RCRA Subtitle `D' Soil Cover and a RCRA Subtitle `C' Compacted Clay Cover) were constructed side-by-side with four alternative cover test plots designed for dry environments. The demonstration is intended to evaluate the various cover designs based on their respective water balance performance, ease and reliability of construction, and cost. This paper presents an overview of the ongoing demonstration.

  16. Simulation of Sediment and Cesium Transport in the Ukedo River and the Ogi Dam Reservoir during a Rainfall Event using the TODAM Code

    SciTech Connect (OSTI)

    Onishi, Yasuo; Yokuda, Satoru T.; Kurikami, Hiroshi

    2014-03-28

    The accident at the Fukushima Daiichi Nuclear Power Plant in March 2011 caused widespread environmental contamination. Although decontamination activities have been performed in residential areas of the Fukushima area, decontamination of forests, rivers, and reservoirs is still controversial because of the economical, ecological, and technical difficulties. Thus, an evaluation of contaminant transport in such an environment is important for safety assessment and for implementation of possible countermeasures to reduce radiation exposure to the public. The investigation revealed that heavy rainfall events play a significant role in transporting radioactive cesium deposited on the land surface, via soil erosion and sediment transport in rivers. Therefore, we simulated the sediment and cesium transport in the Ukedo River and its tributaries in Fukushima Prefecture, including the Ogaki Dam Reservoir, and the Ogi Dam Reservoir of the Oginosawa River in Fukushima Prefecture during and after a heavy rainfall event by using the TODAM (Time-dependent, One-dimensional Degradation And Migration) code. The main outcomes are the following: • Suspended sand is mostly deposited on the river bottom. Suspended silt and clay, on the other hand, are hardly deposited in the Ukedo River and its tributaries except in the Ogaki Dam Reservoir in the Ukedo River even in low river discharge conditions. • Cesium migrates mainly during high river discharge periods during heavy rainfall events. Silt and clay play more important roles in cesium transport to the sea than sand does. • The simulation results explain variations in the field data on cesium distributions in the river. Additional field data currently being collected and further modeling with these data may shed more light on the cesium distribution variations. • Effects of 40-hour heavy rainfall events on clay and cesium transport continue for more than a month. This is because these reservoirs slow down the storm-induced high flow moving through these reservoirs. • The reservoirs play a major role as a sink of sediment and cesium in the river systems. Some amounts of sediment pass through them along with cesium in dissolved and clay-sorbed cesium forms. • Effects of countermeasures such as overland decontamination, dam control and sorbent injection were tentatively estimated. The simulation suggested that overland decontamination and sorbent injection would be effective for decreasing the contamination of water in the reservoir and in the river below the dam.

  17. Engineering theory of slide processes in the design of earth dams on a soft ground foundation

    SciTech Connect (OSTI)

    Krasil'nikov, N.A.

    1987-11-01

    This paper discusses the slope stability and landslide propensity of several hydroelectric plant earth dams throughout the Soviet Union from the standpoint of slide theory and compares the research of several Soviet institutions into this problem with existing standards and recommendations on dam stability and reliability. The comparisons are made for earth dams having a soft ground foundation under static loading conditions. Applicable properties are discussed for a wide range of soils and rocks including clays, loams, sands, alluvials, and soft and hard gravels. Seismic effects are not discussed.

  18. Value of Information spreadsheet

    SciTech Connect (OSTI)

    Trainor-Guitton, Whitney

    2014-05-12

    This spreadsheet represents the information posteriors derived from synthetic data of magnetotellurics (MT). These were used to calculate value of information of MT for geothermal exploration. Information posteriors describe how well MT was able to locate the "throat" of clay caps, which are indicative of hidden geothermal resources. This data is full explained in the peer-reviewed publication: Trainor-Guitton, W., Hoversten, G. M., Ramirez, A., Roberts, J., Jlusson, E., Key, K., Mellors, R. (Sept-Oct. 2014) The value of spatial information for determining well placement: a geothermal example, Geophysics.

  19. Mars north polar dunes: possible formation from low-density sediment aggregates

    SciTech Connect (OSTI)

    Saunders, R.S.; Blewett, D.T.

    1987-10-01

    Low-density aggregates, composed of submicron clay aerosols, have been formed experimentally as the sublimation residues of masses of dust-nucleated ice. These ice-dust mixtures are possible analogues of materials of Martian north polar deposits. Low-density (0.002 g/cm/sup 3/) spheroidal pellets formed from these materials in wind tunnel experiments have been examined as possible candidates for forming north polar dunes on Mars. It is shown that these particles move like sand grains under conditions of saltation and, given a sufficient supply, would be capable of forming the dunes observed in the north circumpolar erg.

  20. Method of dispersing particulate aerosol tracer

    DOE Patents [OSTI]

    O'Holleran, Thomas P. (Belleville, MI)

    1988-01-01

    A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

  1. ELECTROKINETIC DENSIFICATION OF COAL FINES IN WASTE PONDS

    SciTech Connect (OSTI)

    E. James Davis

    1999-12-18

    The objective of this research was to demonstrate that electrokinetics can be used to remove colloidal coal and mineral particles from coal-washing ponds and lakes without the addition of chemical additives such as salts and polymeric flocculants. The specific objectives were: Design and develop a scaleable electrophoresis apparatus to clarify suspensions of colloidal coal and clay particles; Demonstrate the separation process using polluted waste water from the coal-washing facilities at the coal-fired power plants in Centralia, WA; Develop a mathematical model of the process to predict the rate of clarification and the suspension electrical properties needed for scale up.

  2. Rheology Of MonoSodium Titanate (MST) And Modified Mst (mMST) Mixtures Relevant To The Salt Waste Processing Facility

    SciTech Connect (OSTI)

    Koopman, D. C.; Martino, C. J.; Shehee, T. C.; Poirier, M. R.

    2013-07-31

    The Savannah River National Laboratory performed measurements of the rheology of suspensions and settled layers of treated material applicable to the Savannah River Site Salt Waste Processing Facility. Suspended solids mixtures included monosodium titanate (MST) or modified MST (mMST) at various solid concentrations and soluble ion concentrations with and without the inclusion of kaolin clay or simulated sludge. Layers of settled solids were MST/sludge or mMST/sludge mixtures, either with or without sorbed strontium, over a range of initial solids concentrations, soluble ion concentrations, and settling times.

  3. Deputy Secretary Leads U.S. Delegation to Turkey | Department of Energy

    Energy Savers [EERE]

    Leads U.S. Delegation to Turkey Deputy Secretary Leads U.S. Delegation to Turkey July 13, 2006 - 3:02pm Addthis Hails International Cooperation on BTC Pipeline Completion WASHINGTON, DC - U.S. Energy Deputy Secretary Clay Sell today led a United States delegation to the official completion ceremony of the Baku-Tibilisi-Ceyhan (BTC) pipeline in Ceyhan,Turkey. The BTC pipeline, now operational, carries one-million barrels of Caspian oil daily to the global markets faster in an environmentally safe

  4. Deputy Secretary Sell Highlights Cooperation in Global Energy Security and

    Energy Savers [EERE]

    Nuclear Non-Proliferation in Moscow | Department of Energy Sell Highlights Cooperation in Global Energy Security and Nuclear Non-Proliferation in Moscow Deputy Secretary Sell Highlights Cooperation in Global Energy Security and Nuclear Non-Proliferation in Moscow March 12, 2007 - 10:28am Addthis Co-Chairs U.S. - Russia Energy Working Group on First Stop on Three Nation Swing MOSCOW, Russia - U.S. Deputy Secretary of Energy Clay Sell today participated in the U.S. - Russia Energy Working

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Switch to Detail View for this search SciTech Connect Search Results Page 1 of 1 Search for: All records Creators/Authors contains: "Dvorkin, Jack" × Sort by Relevance Sort by Date (newest first) Sort by Date (oldest first) Sort by Relevance « Prev Next » Everything5 Electronic Full Text4 Citations1 Multimedia0 Datasets0 Software0 Filter Results Filter by Subject abandoned wells (1) cements (1) clays (1) disposal wells (1) drilling fluids (1) elasticity (1) environmental sciences

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Switch to Detail View for this search SciTech Connect Search Results Page 1 of 1 Search for: All records Creators/Authors contains: "Mavko, Gary" × Sort by Relevance Sort by Date (newest first) Sort by Date (oldest first) Sort by Relevance « Prev Next » Everything4 Electronic Full Text3 Citations1 Multimedia0 Datasets0 Software0 Filter Results Filter by Subject environmental sciences (2) geosciences (2) porosity (2) algorithms (1) attenuation (1) clay (1) gas saturation (1)

  7. Department Of Energy Offers $60 Million to Spur Industry Engagement in

    Energy Savers [EERE]

    Global Nuclear Energy Partnership | Department of Energy Of Energy Offers $60 Million to Spur Industry Engagement in Global Nuclear Energy Partnership Department Of Energy Offers $60 Million to Spur Industry Engagement in Global Nuclear Energy Partnership May 9, 2007 - 12:45pm Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) Deputy Secretary Clay Sell today announced that DOE will provide up to $60 million, over two years (FY'07-'08), to engage industry experts in the conceptual

  8. Pseudophasic extraction method for the separation of ultra-fine minerals

    DOE Patents [OSTI]

    Chaiko, David J. (Naperville, IL)

    2002-01-01

    An improved aqueous-based extraction method for the separation and recovery of ultra-fine mineral particles. The process operates within the pseudophase region of the conventional aqueous biphasic extraction system where a low-molecular-weight, water soluble polymer alone is used in combination with a salt and operates within the pseudo-biphase regime of the conventional aqueous biphasic extraction system. A combination of low molecular weight, mutually immiscible polymers are used with or without a salt. This method is especially suited for the purification of clays that are useful as rheological control agents and for the preparation of nanocomposites.

  9. U.S. Commits $14 million to U.S. - Ukraine Nuclear Fuel Qualification

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project | Department of Energy Commits $14 million to U.S. - Ukraine Nuclear Fuel Qualification Project U.S. Commits $14 million to U.S. - Ukraine Nuclear Fuel Qualification Project March 15, 2007 - 10:55am Addthis KYIV, Ukraine - U.S. Department of Energy Deputy Secretary Clay Sell today announced that the United States will invest $14 million to provide 42 nuclear fuel assemblies to the South Ukraine Nuclear Power Plant under the U.S.-Ukraine Nuclear Fuel Qualification Project (UNFQP). In

  10. U.S. Department Of Energy Commends Industry Consortia for Making Headway to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Build Much-Needed, New Nuclear Reactors in U.S. | Department of Energy Of Energy Commends Industry Consortia for Making Headway to Build Much-Needed, New Nuclear Reactors in U.S. U.S. Department Of Energy Commends Industry Consortia for Making Headway to Build Much-Needed, New Nuclear Reactors in U.S. October 30, 2007 - 4:21pm Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) Deputy Secretary Clay Sell today commended the Tennessee Valley Authority (TVA) and the NuStart Energy

  11. Atomic Photography: Blasts from the Past

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic Photography National Security Science Latest Issue:July 2015 past issues All Issues » submit Atomic Photography: Blasts from the Past A gallery of images reveals the weird beauty of fireballs, mushroom clouds, vapor columns, and the "rope trick" during atomic tests in the Pacific and at the Nevada Test Site. July 1, 2015 Atomic Photography: Blasts from the Past Atomic Photography: Blasts from the Past Contact Managing Editor Clay Dillingham Email Twenty-five U.S. atmospheric

  12. Evaluating the variability of ceramics with x-ray fluorescence

    SciTech Connect (OSTI)

    Crown, P.L.; Schwalbe, L.A.; London, J.R.

    1984-01-01

    Our assessment of prehistoric trade in ceramics depends on our ability to identify and distinguish different sources of manufacture. For the American Southwest, archaeologists have proposed various models of ceramic manufacture and exchange. Until recently, conflicting hypotheses were tested mainly on the basis of petrographic analysis of nonplastic tempering materials. We have extended these analyses to include x-ray fluorescence (XRF). XRF provides a fast and inexpensive means of analyzing large numbers of samples. Since 1982, approximately 500 prehistoric sherds and 40 prepared clay and mineral samples have been examined with XRF. Multivariate statistical techniques have been applied to help identify groupings of samples with possible archaeological significance.

  13. Spray dryer capacity stretched 50%

    SciTech Connect (OSTI)

    Paraskevas, J.

    1983-01-01

    This article describes plant equipment modifications which has resulted in a 50% increase in spray drying capacity. The installation of a new atomizer and screening system in NL Chemicals' Newberry Springs plant which produces natural clays for use as rheological additives in industrial coatings, cosmetics and other products, resulted in a 50% increase in spray drying capacity. Energy consumption per pound of product was reduced by 7%, and product quality improved. This was achieved in less than three months at an investment of less than 10% of what an additional spray dryer would have cost.

  14. National Coal Council Meeting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Coal Council Meeting National Coal Council Meeting June 7, 2007 - 1:40pm Addthis Remarks As Prepared By Deputy Energy Secretary Clay Sell Thank you, Georgia [Nelson, Chair of the NCC]. I am grateful for the opportunity to be here this morning. Before I begin my remarks, I'd like to take a moment to honor the late Senator Craig Thomas. As everyone in this room knows, Senator Thomas was an important voice in the shaping of this nation's energy policy for more than a decade. He was a

  15. Out With the Old, In With the New: New Hampshire Town to Upgrade Lighting |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Stephen Graff Former Writer & editor for Energy Empowers, EERE Newfields, New Hampshire's town hall has a lot of old-time charm worth keeping, with its steeple, rusted-red brick and chimney stacks, but the town lights are ready for a makeover. "Obviously, they don't have gas lamps from the 1800s," jokes Clay Mitchell, Newfields' town planner. "But the lights are old. In the town hall meeting room, they are awful. They are big, fat and hum when you turn

  16. DATE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 SECTION A. Project Title: TRA-609 Compressed Air System Drain Line Modification and Valve Replacement SECTION B. Project Description: Due to periods of insufficient water flow to the sewer ponds, the clay liners in the ponds can dry out and crack. This proposed action is to add an additional drain line, which will allow clean well water that has been used to cool compressors to then be drained into the sewer system ponds during low flow periods in order to maintain a higher, more consistent

  17. Turnaround team revitalizes mining operations

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2005-11-01

    Starting from scratch, the Broe Companies' Century Coal trains the next generation. The article describes how the newly created Century Coal LLC, controlled by Denver-based Broe Companies investment firm, is rebuilding and expanding its highwall mining operations, increasing production from a current 1 million tons to 5 to 6 million tons in 2006 and 2007. The company has a $100,000 outreach program with 95% of these funds going to local communities. Present coal mining operations are spread around Bell, Clay, Harlan Knox and Leslie Counties. A priority is the renovation of the WenLar preparation plant in Bell County. 5 photos.

  18. Determination of the Rate of Formation of Hydroceramic Waste Forms made with INEEL Calcined Wastes

    SciTech Connect (OSTI)

    Barry Scheetz; Johnson Olanrewaju

    2001-10-15

    The formulation, synthesis, characterization and hydration kinetics of hydroceramic waste forms designed as potential hosts for existing INEEL calcine high-level wastes have been established as functions of temperature and processing time. Initial experimentations were conducted with several aluminosilicate pozzolanic materials, ranging from fly ash obtained from various power generating coal and other combustion industries to reactive alumina, natural clays and ground bottled glass powders. The final selection criteria were based on the ease of processing, excellent physical properties and chemical durability (low-leaching) determined from the PCT test produced in hydroceramic. The formulation contains vermiculite, Sr(NO32), CsC1, NaOH, thermally altered (calcined natural clay) and INEEL simulated calcine high-level nuclear wastes and 30 weight percent of fluorinel blend calcine and zirconia calcine. Syntheses were carried out at 75-200 degree C at autogeneous water pressure (100% relative humidity) at various time intervals. The resulting monolithic compact products were hard and resisted breaking when dropped from a 5 ft height. Hydroceramic host mixed with fluorinel blend calcine and processed at 75 degree C crumbled into rice hull-side grains or developed scaly flakes. However, the samples equally possessed the same chemical durability as their unbroken counterparts. Phase identification by XRD revealed that hydroceramic host crystallized type zeolite at 75-150 degree C and NaP1 at 175-200 degree C in addition to the presence of quartz phase originating from the clay reactant. Hydroceramic host mixed with either fluorinel blend calcine or zirconia calcine crystallized type A zeolite at 75-95 degree C, formed a mixture of type A zeolite and hydroxysodalite at 125-150 degree C and hydroxysodalite at 175-200 degree C. Quartz, calcium fluoride and zirconia phases from the clay reactant and the two calcine wastes were also detected. The PCT test solution conductivity, pH and analytical concentration measured as a function of time decrease exponentially. In some cases nitrate, sulfate, chloride and fluoride ion concentrations increased with time and processing temperature with respect to the reference sample. The increasing concentration of these ions was due to the lack of formation of crystalline phases that can incorporate them in their structures, especially cancrinite. Another plausible explanations for their increase was due to the continuous withdrawal of cations with time, for example sodium to form zeolites, thereby increase their concentrations.

  19. Table 2. Ten largest plants by generation capacity, 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    Minnesota" ,"Plant","Primary energy source","Operating company","Net summer capacity (MW)" 1,"Sherburne County","Coal","Northern States Power Co - Minnesota",2242.8 2,"Clay Boswell","Coal","Minnesota Power Inc",1082.4 3,"Prairie Island","Nuclear","Northern States Power Co - Minnesota",1040 4,"Monticello Nuclear

  20. Soil stabilization and pavement recycling with self-cementing coal fly ash

    SciTech Connect (OSTI)

    2008-01-15

    This manual provides design information for self-cementing coal fly ash as the sole stabilizing agent for a wide range of engineering applications. As in any process, the application of sound engineering practices, appropriate testing, and evaluation of fly ash quality and characteristics will lend themselves to successful projects using the guidelines in this manual. Topics discussed include: self-cementing coal fly ash characteristics; laboratory mix design; stabilization of clay soils; stabilisation of granular materials; construction considerations; high sulfate ash; environmental considerations for fly ash stabilization; design considerations; state specification/guidelines/standards; and a sample of a typical stabilization specification.

  1. Improved method and composition for immobilization of waste in cement-based material

    DOE Patents [OSTI]

    Tallent, O.K.; Dodson, K.E.; McDaniel, E.W.

    1987-10-01

    A composition and method for fixation or immobilization of aqueous hazardous waste material in cement-based materials (grout) is disclosed. The amount of drainable water in the cured grout is reduced by the addition of an ionic aluminum compound to either the waste material or the mixture of waste material and dry-solid cement- based material. This reduction in drainable water in the cured grout obviates the need for large, expensive amounts of gelling clays in grout materials and also results in improved consistency and properties of these cement-based waste disposal materials.

  2. Subsea technology progress buoys Gulf of Mexico deepwater action

    SciTech Connect (OSTI)

    Koen, A.D.

    1996-09-02

    This paper reviews the technological advances in subsea oil and gas equipment to drive a new era of exploration and development in the outer continental shelf and other areas considered to complex to economically pursue. As subsea technology expands into deep waters, operators in the Gulf are using subsea production systems based on template and well cluster designs. Subsea cluster systems are gaining favor among operators because they allow more flexibility with shallow water flow which occurs during the first 1,000 feet of clay formations below the seabed. The paper also provides insight into deep water drilling, remote operated vehicles, deep water umbilicals, and other deep water production equipment.

  3. The Draugen platform and subsea structures, installation and foundation aspects

    SciTech Connect (OSTI)

    Alm, T.; Bye, A.; Sandvik, K.; Egeland, S.

    1995-12-01

    Installation data from the Draugen GBS and subsea structures have been processed and analyzed in order to verify the design assumptions with regards to soil reactions. These results have shown that penetration of concrete skirts and piles into the very hard clay layer, typically found at the Haltenbanken area is feasible. The resistances may be predicted with reasonable accuracy using conventional methods and average soil strength values as obtained by traditional soil testing. This paper reveals and comments the installation data both for the gravity platform and the piles for the different subsea structures and provides and updated basis for foundation design of similar structures in the area.

  4. Zirconium-modified materials for selective adsorption and removal of aqueous arsenic

    DOE Patents [OSTI]

    Zhao, Hongting; Moore, Robert C.

    2004-11-30

    A method, composition, and apparatus for removing contaminant species from an aqueous medium comprising: providing a material to which zirconium has been added, the material selected from one or more of zeolites, cation-exchangeable clay minerals, fly ash, mesostructured materials, activated carbons, cellulose acetate, and like porous and/or fibrous materials; and contacting the aqueous medium with the material to which zirconium has been added. The invention operates on all arsenic species in the form of arsenate, arsenite and organometallic arsenic, with no pretreatment necessary (e.g., oxidative conversion of arsenite to arsenate).

  5. The role of nanopores on U(VI) sorption and redox behavior in

    Office of Scientific and Technical Information (OSTI)

    U(VI)-contaminated subsurface sediments (Technical Report) | SciTech Connect The role of nanopores on U(VI) sorption and redox behavior in U(VI)-contaminated subsurface sediments Citation Details In-Document Search Title: The role of nanopores on U(VI) sorption and redox behavior in U(VI)-contaminated subsurface sediments Most reactive surfaces in clay-dominated sediments are present within nanopores (pores of nm dimension). The behavior of geological fluids and minerals in nanopores is

  6. Nuclear, multichannel-sonic, ultrasonic analyses for determination of degree of fracturing and alteration in a fast formation: The deep ocean crust

    SciTech Connect (OSTI)

    Anderson, R.N.; O'Malley, H.; Newmark, R.L.

    1984-01-01

    Multichannel, Full-Waveform Sonic Logs offer quantitative information on the response of the formation to propagating acoustic energy. When coupled with ultrasonic borehole imagery, these logs show clear evidence of fractures intersecting the wellbore. P-wave, S-wave, Stoneley and late arriving normal modal CODA all show energy and frequency changes across fracture zones. One critical ingredient missing from the sonic-ultrasonic cross-correlations to date, has been the ability to estimate the quantity of alteration material infilling fractures. A new nuclear analysis technique has been developed to extract a reliable estimate of the amount of clay infilling in highly fractured basalts from the oceanic crust.

  7. Imaging Reservoir Quality: Seismic Signatures of Geologic Processes

    SciTech Connect (OSTI)

    Department of Geophysics

    2008-06-30

    Lithofacies successions from diverse depositional environments show distinctive patterns in various rock-physics planes (velocity-porosity, velocity-density and porosity-clay). Four clear examples of decameter-scale lithofacies sequences are documented in this study: (1) Micocene fluvial deposits show an inverted-V pattern indicative of dispersed fabric, (2) a fining-upward sequence of mud-rich deep deposits shows a linear trend associated with laminated sand-clay mixtures, (3) sand-rich deposits show a pattern resulting from the scarcity of mixed lithofacies, and (4) a coarsening-upward sequence shows evidence of both dispersed and horizontally laminated mixed lithofacies, with predominating dispersed mixtures generated by bioturbation. It was observed that carbonate-cemented sandstones are extremely heterogeneous in the project deep-water study area. Those from the base of incisions are usually associated with lower shaliness, lower porosity and higher P-impedance, while from the top of flooding surfaces exhibit higher shaliness, higher porosity and lower P-impedance. One rock physics model that captures the observed impedance-porosity trend is the 'stiff-sand model'. For this model, the high-porosity end-member is unconsolidated sand whose initial porosity is a function of sorting and shaliness, while the low-porosity end-member is solid mineral. These two end points are joined with a Hashin-Shtrikman equation. A systematic variation of quartz:clay ratio from proximal to distal locations was observed in the study area even within a single facies. The quartz:clay ratio changes from [0.5:0.5] to [1:0] along the direction of flow, based on the trends of P-impedance vs. porosity as predicted by the rock model for uncemented sands. The results are in agreement with spill-and-fill sequence stratigraphic model in mini-basin setting. In addition, porosity at the distal location ({approx}25 % to 35%) is higher than the porosity at the proximal location ({approx}20 % to 23%). This trend is explained by a sequence stratigraphic model which predicts progressive increase in sorting by turbidity current along the flow, as well as, quantified by a rock model that heuristically accounts for sorting. The results can be applied to improve quantitative predication of sediment parameters from seismic impedance, away from well locations.

  8. SEISMIC AND ROCK PHYSICS DIAGNOSTICS OF MULTISCALE RESERVOIR TEXTURES

    SciTech Connect (OSTI)

    Gary Mavko

    2003-10-01

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have (1) Studied relationships between velocity and permeability. (2) Used independent experimental methods to measure the elastic moduli of clay minerals as functions of pressure and saturation. (3) Applied different statistical methods for characterizing heterogeneity and textures from scanning acoustic microscope (SAM) images of shale microstructures. (4) Analyzed the directional dependence of velocity and attenuation in different reservoir rocks (5) Compared Vp measured under hydrostatic and non-hydrostatic stress conditions in sands. (6) Studied stratification as a source of intrinsic anisotropy in sediments using Vp and statistical methods for characterizing textures in sands.

  9. Cask weeping mitigation

    DOE Patents [OSTI]

    Krumhansl, James L. (Albuquerque, NM); Brady, Patrick V. (Albuquerque, NM); Teter, David M. (Edgewood, NM); McConnell, Paul (Albuquerque, NM)

    2007-09-18

    A method (and concomitant kit) for treating a surface to reduce subsequent .sup.137Cs nuclide desorption comprising contacting the surface with a first cation-containing solution, the cation being one or more of Cs.sup.+, Rb.sup.+, Ag.sup.+, Tl.sup.+, K.sup.+, and NH.sub.4.sup.+, and contacting the surface with a second cation-containing solution, the cation being one or more of Cs.sup.+, Rb.sup.+, Ag.sup.+, Tl.sup.+, K.sup.+, and NH.sub.4.sup.+, thereby reducing amounts of radioactive cesium embedded in clays found on the surface.

  10. War damages and reconstruction of Peruca dam

    SciTech Connect (OSTI)

    Nonveiller, E.; Rupcic, J.; Sever, Z.

    1999-04-01

    The paper describes the heavy damages caused by blasting in the Peruca rockfill dam in Croatia in January 1993. Complete collapse of the dam by overtopping was prevented through quick action of the dam owner by dumping clayey gravel on the lowest sections of the dam crest and opening the bottom outlet of the reservoir, thus efficiently lowering the water level. After the damages were sufficiently established and alternatives for restoration of the dam were evaluated, it was decided to construct a diaphragm wall through the damaged core in the central dam part as the impermeable dam element and to rebuild the central clay core at the dam abutments. Reconstruction works are described.

  11. From: Miller, William [mailto:wmiller@McCarter.com]

    Office of Environmental Management (EM)

    October 28, 2014 4:59 PM To: Cohen, Daniel Cc: Clay, Kathryn; 'Dave Schryver'; Cymbalsky, John; 'Bert Kalisch'; rmurphy@aga.org; Leslie, Neil (Neil.Leslie@gastechnology.org) Subject: RE: Furnaces Data Dan: per our earlier email exchanges, attached are the initial questions of APGA/AGA regarding the LCC spreadsheets distributed by DOE regarding the furnace rule remand. We anticipate that we will have additional questions by the time of the Nov. 7 meeting, as we are continuing our review; we also

  12. NATURAL GAS FROM SHALE: Questions and Answers

    Office of Environmental Management (EM)

    is shale gas? Basically, it is natural gas - primarily methane - found in shale formations, some of which were formed 300-million-to-400-million years ago during the Devonian period of Earth's history. The shales were deposited as fine silt and clay particles at the bottom of relatively enclosed bodies of water. At roughly the same time, primitive plants were forming forests on land and the first amphibians were making an appearance. Some of the methane that formed from the organic matter buried

  13. Bioturbating animals control the mobility of redox-sensitive trace elements in organic-rich mudstone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harazim, Dario; McIlroy, Duncan; Edwards, Nicholas P.; Wogelius, Roy A.; Manning, Phillip L.; Poduska, Kristin M.; Layne, Graham D.; Sokaras, Dimosthenis; Alonso-Mori, Roberto; Bergmann, Uwe

    2015-10-07

    Bioturbating animals modify the original mineralogy, porosity, organic content, and fabric of mud, thus affecting the burial diagenetic pathways of potential hydrocarbon source, seal, and reservoir rocks. High-sensitivity, synchrotron rapid scanning X-ray fluorescence elemental mapping reveals that producers of phycosiphoniform burrows systematically partition redox-sensitive trace elements (i.e., Fe, V, Cr, Mn, Co, Ni, Cu, and As) in fine-grained siliciclastic rocks. Systematic differences in organic carbon content (total organic carbon >1.5 wt%) and quality (Δ13Corg~0.6‰) are measured between the burrow core and host sediment. The relative enrichment of redox-sensitive elements in the burrow core does not correlate with significant neo-formation ofmore » early diagenetic pyrite (via trace metal pyritization), but is best explained by physical concentration of clay- and silt-sized components. A measured loss (~–15%) of the large-ionic-radius elements Sr and Ba from both burrow halo and core is most likely associated with the release of Sr and Ba to pore waters during biological (in vivo) weathering of silt- to clay-sized lithic components and feldspar. In conclusion, this newly documented effect has significant potential to inform the interpretation of geochemical proxy and rock property data, particularly from shales, where elemental analyses are commonly employed to predict reservoir quality and support paleoenvironmental analysis.« less

  14. Mechanical properties and modeling of seal-forming lithologies. Technical progress report No. 3, March 15, 1992--June 14, 1993

    SciTech Connect (OSTI)

    Kronenberg, A.K.; Russell, J.E.; Carter, N.L.; Mazariegos, R.; Ibanez, W.

    1993-06-01

    Specific goals and accomplishments of this research include: (1) The evaluation of models of salt diaper ascent that involve either power law, dislocation creep as determined experimentally by Horseman et al. (1993) or linear, fluid-assisted creep as reported by Spiers et al. (1988, 1990, 1992). We have compared models assuming these two, experimentally evaluated flow laws and examined the predictions they make regarding diaper incubation periods, ascent velocities, deviatoric stresses and strain rates. (2) The evaluation of the effects of differential loading on the initiation an of salt structures. (3) Examination of the role of basement faults on the initiation and morphologic evolution of salt structures. (4) Evaluation of the mechanical properties of shale as a function of pressure and determination of the nature of its brittle-ductile transition. (5) Evaluation of the mechanical anisotropies of shales with varying concentrations, distributions and preferred orientations of clay. (6) The determination of temperature and ratedependencies of strength for a shale constitutive model that can be used in numerical models that depend on viscous formulations. (7) Determination of the mechanisms of deformation for argillaceous rocks over awide range of conditions. (8) Evaluation of the effects of H{sub 2}O within clay interlayers, as adsorbed surface layers.

  15. Mechanical properties and modeling of seal-forming lithologies

    SciTech Connect (OSTI)

    Kronenberg, A.K.; Russell, J.E.; Carter, N.L.; Mazariegos, R.; Ibanez, W.

    1993-01-01

    Specific goals and accomplishments of this research include: (1) The evaluation of models of salt diaper ascent that involve either power law, dislocation creep as determined experimentally by Horseman et al. (1993) or linear, fluid-assisted creep as reported by Spiers et al. (1988, 1990, 1992). We have compared models assuming these two, experimentally evaluated flow laws and examined the predictions they make regarding diaper incubation periods, ascent velocities, deviatoric stresses and strain rates. (2) The evaluation of the effects of differential loading on the initiation an of salt structures. (3) Examination of the role of basement faults on the initiation and morphologic evolution of salt structures. (4) Evaluation of the mechanical properties of shale as a function of pressure and determination of the nature of its brittle-ductile transition. (5) Evaluation of the mechanical anisotropies of shales with varying concentrations, distributions and preferred orientations of clay. (6) The determination of temperature and ratedependencies of strength for a shale constitutive model that can be used in numerical models that depend on viscous formulations. (7) Determination of the mechanisms of deformation for argillaceous rocks over awide range of conditions. (8) Evaluation of the effects of H[sub 2]O within clay interlayers, as adsorbed surface layers.

  16. Backfill barrier as a component in a multiple barrier nuclear waste isolation system

    SciTech Connect (OSTI)

    Nowak, E.J.

    1980-05-01

    Quantitative estimates of the potential effectiveness of backfill barriers based on a linear sorption model are presented. Using getters such as clays (known sorbents), a backfill approximately 1-foot-thick can delay by 10/sup 4/ to 10/sup 5/ years the breakthrough of transuranics. A delay of 10/sup 3/ years is possible for major cationic fission products. These delays can be achieved provided that (1) the distribution coefficient (K/sub d/, a measure of affinity for sorbed species) for the barrier material is equal to or greater than 2000 ml/g for transuranics and 200 ml/g for fission products; (2) the interstitial groundwater velocity through the barrier is limited to 1 ft/year or less; (3) the effective porosity of the barrier is equal to or less than 0.1; and (4) the physical integrity of the barrier is maintained (no channels or cracks). Mixtures containing expanding clays such as smectites and other getters are expected to satisfy these criteria.

  17. Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama. Final report, March 1996--September 1998

    SciTech Connect (OSTI)

    Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Carroll, R.E.; Groshong, R.H.; Jin, G.

    1998-12-01

    This project was designed to analyze the structure of Mesozoic and Tertiary strata in Gilbertown Field and adjacent areas to suggest ways in which oil recovery can be improved. The Eutaw Formation comprises 7 major flow units and is dominated by low-resistivity, low-contrast play that is difficult to characterize quantitatively. Selma chalk produces strictly from fault-related fractures that were mineralized as warm fluid migrated from deep sources. Resistivity, dipmeter, and fracture identification logs corroborate that deformation is concentrated in the hanging-wall drag zones. New area balancing techniques were developed to characterize growth strata and confirm that strain is concentrated in hanging-wall drag zones. Curvature analysis indicates that the faults contain numerous fault bends that influence fracture distribution. Eutaw oil is produced strictly from footwall uplifts, whereas Selma oil is produced from fault-related fractures. Clay smear and mineralization may be significant trapping mechanisms in the Eutaw Formation. The critical seal for Selma reservoirs, by contrast, is where Tertiary clay in the hanging wall is juxtaposed with poorly fractured Selma chalk in the footwall. Gilbertown Field can be revitalized by infill drilling and recompletion of existing wells. Directional drilling may be a viable technique for recovering untapped oil from Selma chalk. Revitalization is now underway, and the first new production wells since 1985 are being drilled in the western part of the field.

  18. Clean, premium-quality chars: Demineralized and carbon enriched. Quarterly report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Smith, G.V.

    1992-08-01

    The interaction of methane, methane/oxygen, helium, and hydrogen with IBC-102 coal samples ({le} 2mg) has been investigated in a thermogravimetric reactor at 20{degrees}C--650{degrees}C. The results show that the reactive gases are converting some of the mineral matter of the coal into catalysts through chemical reactions (reduction or oxidation). Also, these gases (except He) dissolve in the softened coal. Added clays (kaolinite and Ca-montmorillonite) increase the reactivity of the coal. This higher reactivity may be attributed to the fact that clays may serve as catalysts for methane activation, may prevent the coal agglomeration, and/or may increase the number of active sites for the reaction by modification of the geometric structure of the coal surface. Differential Scanning Calorimetry (DSC) experiments show that clean coal (no mineral matter) devolatilizes at a lower temperature than raw coal. Also, the preoxidation at 150{degrees}C for 50 minutes results in a 13{degrees} lowering of the devolatilization temperature. ISDR-FTIR experiments suggest that phenol groups of the coal play an important role in the cross-linkage of the coal structure when thermally treated.

  19. Bioturbating animals control the mobility of redox-sensitive trace elements in organic-rich mudstone

    SciTech Connect (OSTI)

    Harazim, Dario; McIlroy, Duncan; Edwards, Nicholas P.; Wogelius, Roy A.; Manning, Phillip L.; Poduska, Kristin M.; Layne, Graham D.; Sokaras, Dimosthenis; Alonso-Mori, Roberto; Bergmann, Uwe

    2015-10-07

    Bioturbating animals modify the original mineralogy, porosity, organic content, and fabric of mud, thus affecting the burial diagenetic pathways of potential hydrocarbon source, seal, and reservoir rocks. High-sensitivity, synchrotron rapid scanning X-ray fluorescence elemental mapping reveals that producers of phycosiphoniform burrows systematically partition redox-sensitive trace elements (i.e., Fe, V, Cr, Mn, Co, Ni, Cu, and As) in fine-grained siliciclastic rocks. Systematic differences in organic carbon content (total organic carbon >1.5 wt%) and quality (?13Corg~0.6) are measured between the burrow core and host sediment. The relative enrichment of redox-sensitive elements in the burrow core does not correlate with significant neo-formation of early diagenetic pyrite (via trace metal pyritization), but is best explained by physical concentration of clay- and silt-sized components. A measured loss (~15%) of the large-ionic-radius elements Sr and Ba from both burrow halo and core is most likely associated with the release of Sr and Ba to pore waters during biological (in vivo) weathering of silt- to clay-sized lithic components and feldspar. In conclusion, this newly documented effect has significant potential to inform the interpretation of geochemical proxy and rock property data, particularly from shales, where elemental analyses are commonly employed to predict reservoir quality and support paleoenvironmental analysis.

  20. Progress report on colloid-facilitated transport at Yucca Mountain: Yucca Mountain site characterization program milestone 3383

    SciTech Connect (OSTI)

    Triay, I.R.; Degueldre, C.; Wistrom, A.O.; Cotter, C.R.; Lemons, W.W.

    1996-06-01

    To assess colloid-facilitated radionuclide transport in groundwaters at the potential nuclear waste repository at Yucca Mountain, it is very important to understand the generation and stability of colloids, including naturally occurring colloids. To this end, we measured the colloid concentration in waters from Well J-13, which is on the order of 106 particles per milliliter (for particle sizes larger than 100 manometers). At this low particle loading, the sorption of radionuclides to colloids would have to be extremely high before the colloids could carry a significant amount of radionuclides from the repository to the accessible environment. We also performed aggregation experiments to evaluate the stability of silica (particle diameter: 85 nm) and clay colloids (particle diameter: 140 nm) as a function of ionic strength in a carbonate-rich synthetic groundwater. When the concentration of electrolyte is increased to induce aggregation, the aggregation is irreversible and the rate of aggregation increases with increasing electrolyte strength. We used autocorrelation photon spectroscopy to estimate the rate of particle aggregation for both types of colloids. By relating the measured aggregation rate to the Smoluchowski rate expression, we determined the stability ratio, W. Aggregation of silica particles and kaolinite clay particles decreased dramatically for an electrolyte concentration, C{sub NaCl}, below 300 mM and 200 mM, respectively.

  1. Optimization of the Processing of HNBR/Organoclay Nanocomposite

    SciTech Connect (OSTI)

    Cadambi, Rahul M.; Ghassemieh, Elaheh

    2010-06-02

    In the current investigation, rubber/clay nanocomposites were prepared by two different methods using hydrogenated nitrile butadiene rubber (HNBR) and the organoclay namely Cloisite 15A (C15A). A new novel approach involving swelling of C15A by ulltrasonication in HNBR solution has been carried out for improving the exfoliation and compatibilization of organoclays with HNBR matrix. With the addition of 5phr of clay, the elongation at break and tear strength improved by 16% and 24% respectively. The effect of coupling agents namely amino functional silane and tetrasulfido silane on the nanocomposites have been investigated. The elongation at break and tear strength improved by 46% and 77% respectively with the use of silanes. The improvement in the mechanical properties attributes to improved interaction between the organoclays and HNBR matrix. This interaction has been studied by X-ray diffraction and transmission electron microscope. Pre-dispersion technique clearly suggests very good improvement in the dispersion and properties due to better filler-rubber compatibility.

  2. Preliminary characterization of the 100 area at Argonne National Laboratory

    SciTech Connect (OSTI)

    Biang, C.; Biang, R.; Patel, P.

    1994-06-01

    This characterization report is based on the results of sampling and an initial environmental assessment of the 100 Area of Argonne National Laboratory. It addresses the current status, projected data requirements, and recommended actions for five study areas within the 100 Area: the Lime Sludge Pond, the Building 108 Liquid Retention Pond, the Coal Yard, the East Area Burn Pit, and the Eastern Perimeter Area. Two of these areas are solid waste management units under the Resource Conservation and Recovery Act (the Lime Sludge Pond and the Building 108 Liquid Retention Pond); however, the Illinois Environmental Protection Agency has determined that no further action is necessary for the Lime Sludge Pond. Operational records for some of the activities were not available, and one study area (the East Area Burn Pit) could not be precisely located. Recommendations for further investigation include sample collection to obtain the following information: (1) mineralogy of major minerals and clays within the soils and underlying aquifer, (2) pH of the soils, (3) total clay fraction of the soils, (4) cation exchange capacity of the soils and aquifer materials, and (5) exchangeable cations of the soils and aquifer material. Various other actions are recommended for the 100 Area, including an electromagnetic survey, sampling of several study areas to determine the extent of contamination and potential migration pathways, and sampling to determine the presence of any radionuclides. For some of the study areas, additional actions are contingent on the results of the initial recommendations.

  3. Upper Pleistocene-to-Holocene depositional sequences in the north-central Gulf of Mexico

    SciTech Connect (OSTI)

    Bowland, C. ); Wood, L.J. )

    1991-03-01

    Upper Quaternary depositional sequences and their systems tracts can be delineated in the Main Pass area using minisparker seismic data. Core collected by the Gulf of Mexico Outer Shelf/Slope Research Consortium (Amoco, ARCO, BP, Chevron, Elf-Aquitaine, Exxon, Marathon, Mobil, and Texaco) sampled these systems tracts on one site in Main Pass 303. At the shelfbreak, a distinct change in depositional style occurs across the latest Wisconsinan sequence boundary. Widespread progradational systems (late highstand systems tract) below become focused into discrete depocenters with predominantly aggradational deposits (lowstand systems tract) above. Focusing was probably a result of localized high subsidence rates due to salt movement, progradation into rapidly deepening water, and, possibly, stabilization of sediment transport paths on the exposed shelf. No age-equivalent submarine canyons are present in this area. The oldest mappable systems tract is a highstand systems tract deposited during stage 3 interstadial and the early-to-middle stage 2 glacial. The overlying transgressive systems tract was deposited coeval with the stage 2-stage 1 transition. It thins in a land-ward direction, except where an updip depocenter was present. At the corehole site, the transgressive systems tract consists of fining-upward deposits ranging from medium-grained sands to clays. The transgressive systems tract includes small slope-front-fill lenses deposited on the uppermost slope above and adjacent to lowstand deltaic depocenters. These lenses likely comprise silt and clay derived from either reworking of lowstand deltas or sediment bypassing the outer shelf.

  4. Assessment of industrial minerals and rocks in the controlled area

    SciTech Connect (OSTI)

    Castor, S.B.; Lock, D.E.

    1996-08-01

    Yucca Mountain in Nye County, Nevada, is a potential site for a permanent repository for high-level nuclear waste in Miocene ash flow tuff. The Yucca Mountain controlled area occupies approximately 98 km{sup 2} that includes the potential repository site. The Yucca Mountain controlled area is located within the southwestern Nevada volcanic field, a large area of Miocene volcanism that includes at least four major calderas or cauldrons. It is sited on a remnant of a Neogene volcanic plateau that was centered around the Timber Mountain caldera complex. The Yucca Mountain region contains many occurrences of valuable or potentially valuable industrial minerals, including deposits with past or current production of construction aggregate, borate minerals, clay, building stone, fluorspar, silicate, and zeolites. The existence of these deposits in the region and the occurrence of certain mineral materials at Yucca Mountain, indicate that the controlled area may have potential for industrial mineral and rock deposits. Consideration of the industrial mineral potential within the Yucca Mountain controlled area is mainly based on petrographic and lithologic studies of samples from drill holes in Yucca Mountain. Clay minerals, zeolites, fluorite, and barite, as minerals that are produced economically in Nevada, have been identified in samples from drill holes in Yucca Mountain.

  5. Niagara Falls Storage Site environmental report for calendar year 1992, 1397 Pletcher Road, Lewiston, New York. Formerly Utilized Sites Remedial Action Program (FUSRAP)

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    This report describes the environmental surveillance program at the Niagara Falls Storage Site (NFSS) and provides the results for 1992. From 1944 to the present, the primary use of NFSS has been storage of radioactive residues produced as a by-product of uranium production. All onsite areas of residual radioactivity above guidelines have been remediated. Materials generated during remediation are stored onsite in the 4-ha (10-acre) waste containment structure (WCS). The WCS is a clay-lined, clay-capped, and grass-covered storage pile. The environmental surveillance program at NFSS includes sampling networks for radon concentrations in air; external gamma radiation exposure; and total uranium and radium-226 concentrations in surface water, sediments, and groundwater. Several chemical parameters, including seven metals, are also routinely measured in groundwater. This surveillance program assists in fulfilling the DOE policy of measuring and monitoring effluents from DOE activities and calculating hypothetical doses. Monitoring results are compared with applicable Environmental Protection Agency (EPA) and New York State Department of Environmental Conservation (NYSDEC) standards, DOE derived concentration guides (DCGs), dose limits, and other DOE requirements. Results of environmental monitoring during 1992 indicate that levels of the parameters measured were in compliance with all but one requirement: Concentrations of iron and manganese in groundwater were above NYSDEC groundwater quality standards. However, these elements occur naturally in the soils and groundwater associated with this region. In 1992 there were no environmental occurrences or reportable quantity releases.

  6. Molecular dynamics simulation of diffusion and electrical conductivity in montmorillonite interlayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Greathouse, Jeffery A.; Cygan, Randall T.; Fredrich, Joanne T.; Jerauld, Gary R.

    2016-01-20

    In this study, the diffusion of water and ions in the interlayer region of smectite clay minerals represents a direct probe of the type and strength of clay–fluid interactions. Interlayer diffusion also represents an important link between molecular simulation and macroscopic experiments. Here we use molecular dynamics simulation to investigate trends in cation and water diffusion in montmorillonite interlayers, looking specifically at the effects of layer charge, interlayer cation and cation charge (sodium or calcium), water content, and temperature. For Na-montmorillonite, the largest increase in ion and water diffusion coefficients occurs between the one-layer and two-layer hydrates, corresponding to themore » transition from inner-sphere to outer-sphere surface complexes. Calculated activation energies for ion and water diffusion in Na-montmorillonite are similar to each other and to the water hydrogen bond energy, suggesting the breaking of water–water and water–clay hydrogen bonds as a likely mechanism for interlayer diffusion. A comparison of interlayer diffusion with that of bulk electrolyte solutions reveals a clear trend of decreasing diffusion coefficient with increasing electrolyte concentration, and in most cases the interlayer diffusion results are nearly coincident with the corresponding bulk solutions. Trends in electrical conductivities computed from the ion diffusion coefficients are also compared.« less

  7. Effects of pulverized coal fly-ash addition as a wet-end filler in papermaking

    SciTech Connect (OSTI)

    Sinha, A.S.K.

    2008-09-15

    This experimental study is based on the innovative idea of using pulverized coal fly ash as a wet-end filler in papermaking. This is the first evaluation of the possible use of fly ash in the paper industry. Coal-based thermal power plants throughout the world are generating fly ash as a solid waste product. The constituents of fly ash can be used effectively in papermaking. Fly ash has a wide variation in particle size, which ranges from a few micrometers to one hundred micrometers. Fly ash acts as an inert material in acidic, neutral, and alkaline papermaking processes. Its physical properties such as bulk density (800-980 kg/m{sup 3}), porosity (45%-57%), and surface area (0.138-2.3076 m{sup 2}/g) make it suitable for use as a paper filler. Fly ash obtained from thermal power plants using pulverized coal was fractionated by a vibratory-sieve stack. The fine fraction with a particle size below 38 micrometers was used to study its effect on the important mechanical-strength and optical properties of paper. The effects of fly-ash addition on these properties were compared with those of kaolin clay. Paper opacity was found to be much higher with fly ash as a filler, whereas brightness decreased as the filler percentage increased Mechanical strength properties of the paper samples with fly ash as filler were superior to those with kaolin clay.

  8. The effect of sorption on the degradation of aromatic acids and bases

    SciTech Connect (OSTI)

    Ainsworth, C.C.; Fredrickson, J.K.; Smith, S.C.

    1992-10-01

    The availability and degradation of selected ionizable organic compounds sorbed to pure mineral phases are discussed. Substrates sorbed to mineral surfaces may or may not be protected from microbial attack; the degree of protection appears to be dependent on the type and cell density of the microorganism involved. The currently available data, however, demonstrate that there is little, if any, consensus on the types of reactions or interactions that facilitate sorbed substrate utilization. Rates of degradation of organic bases and cations that sorb to clay minerals via an exchange reaction are suggested to be directly related to substrate binding intensity and conformation on the clay surface. Similarly, rates of degradation of organic acids sorbed to the surface of oxides are suggested to be related to their interaction with the surface and the type of oxide sorbent. Although the rate-limiting step in microbial utilization of sorbed acids and bases is apparently a desorption process, the rate of desorption is itself linked to the compound's binding intensities on a given sorbent. Thus, as the binding intensities of compounds increase, chemical kinetic reactions, rather than mass-transfer processes, appear to limit the rate of desorption.

  9. The effect of sorption on the degradation of aromatic acids and bases

    SciTech Connect (OSTI)

    Ainsworth, C.C.; Fredrickson, J.K.; Smith, S.C.

    1992-10-01

    The availability and degradation of selected ionizable organic compounds sorbed to pure mineral phases are discussed. Substrates sorbed to mineral surfaces may or may not be protected from microbial attack; the degree of protection appears to be dependent on the type and cell density of the microorganism involved. The currently available data, however, demonstrate that there is little, if any, consensus on the types of reactions or interactions that facilitate sorbed substrate utilization. Rates of degradation of organic bases and cations that sorb to clay minerals via an exchange reaction are suggested to be directly related to substrate binding intensity and conformation on the clay surface. Similarly, rates of degradation of organic acids sorbed to the surface of oxides are suggested to be related to their interaction with the surface and the type of oxide sorbent. Although the rate-limiting step in microbial utilization of sorbed acids and bases is apparently a desorption process, the rate of desorption is itself linked to the compound`s binding intensities on a given sorbent. Thus, as the binding intensities of compounds increase, chemical kinetic reactions, rather than mass-transfer processes, appear to limit the rate of desorption.

  10. Modeling experimental results of diffusion of alkaline solutions through a compacted bentonite barrier

    SciTech Connect (OSTI)

    Fernandez, Raul; Cuevas, Jaime; Maeder, Urs K.

    2010-08-15

    The interaction between concrete/cement and swelling clay (bentonite) has been modeled in the context of engineered barrier systems for deep geological disposal of high-level radioactive waste. The geochemical transformations observed in laboratory diffusion experiments at 60 and 90 {sup o}C between bentonite and different high-pH solutions (K-Na-OH and Ca(OH){sub 2}-saturated) were reconciled with the reactive transport code CrunchFlow. For K-Na-OH solutions (pH = 13.5 at 25 {sup o}C) partial dissolution of montmorillonite and precipitation of Mg-silicates (talc-like), hydrotalcite and brucite at the interface are predicted at 60 {sup o}C, while at 90 {sup o}C the alteration is wider. Alkaline cations diffused beyond the mineralogical alteration zone by means of exchange with Mg{sup 2+} in the interlayer region of montmorillonite. Very slow reactivity and minor alteration of the clay are predicted in the Ca(OH){sub 2}-bentonite system. The model is a reasonable description of the experiments but also demonstrates the difficulties in modeling processes operating at a small scale under a diffusive regime.

  11. Spatio-temporal self-organization in mudstones.

    SciTech Connect (OSTI)

    Dewers, Thomas A.

    2010-12-01

    Shales and other mudstones are the most abundant rock types in sedimentary basins, yet have received comparatively little attention. Common as hydrocarbon seals, these are increasingly being targeted as unconventional gas reservoirs, caprocks for CO2 sequestration, and storage repositories for waste. The small pore and grain size, large specific surface areas, and clay mineral structures lend themselves to rapid reaction rates, high capillary pressures, and semi-permeable membrane behavior accompanying changes in stress, pressure, temperature and chemical conditions. Under far from equilibrium conditions, mudrocks display a variety of spatio-temporal self-organized phenomena arising from nonlinear thermo-mechano-chemo-hydro coupling. Beginning with a detailed examination of nano-scale pore network structures in mudstones, we discuss the dynamics behind such self-organized phenomena as pressure solitons in unconsolidated muds, chemically-induced flow self focusing and permeability transients, localized compaction, time dependent well-bore failure, and oscillatory osmotic fluxes as they occur in clay-bearing sediments. Examples are draw from experiments, numerical simulation, and the field. These phenomena bear on the ability of these rocks to serve as containment barriers.

  12. Mechanical-chemical coupling and self-organization in mudstones.

    SciTech Connect (OSTI)

    Heath, Jason E.; Dewers, Thomas A.

    2010-06-01

    Shales and other mudstones are the most abundant rock types in sedimentary basins, yet have received comparatively little attention. Common as hydrocarbon seals, these are increasingly being targeted as unconventional gas reservoirs, caprocks for CO{sub 2} sequestration, and storage repositories for waste. The small pore and grain size, large specific surface areas, and clay mineral structures lend themselves to rapid reaction rates accompanying changes in stress, pressure, temperature and chemical conditions. Under far from equilibrium conditions, mudrocks display a variety of spatio-temporal self-organized phenomena arising from the nonlinear coupling of mechanics with chemistry. Beginning with a detailed examination of nano-scale pore network structures in mudstones, we discuss the dynamics behind such self-organized phenomena as pressure solitons, chemically-induced flow self focusing and permeability transients, localized compaction, time dependent well-bore failure, and oscillatory osmotic fluxes as they occur in clay-bearing sediments. Examples are draw from experiments, numerical simulation, and the field. These phenomena bear on the ability of these rocks to serve as containment barriers.

  13. Field study plan for alternate barriers

    SciTech Connect (OSTI)

    Freeman, H.D.; Gee, G.W.; Relyea, J.F.

    1989-05-01

    Pacific Northwest Laboratory (PNL) is providing technical assistance in selecting, designing, evaluating, and demonstrating protective barriers. As part of this technical assistance effort, asphalt, clay, and chemical grout will be evaluated for use as alternate barriers. The purpose of the subsurface layer is to reduce the likelihood that extreme events (i.e., 100-year maximum storms, etc.) will cause significant drainage through the barrier. The tests on alternate barriers will include laboratory and field analysis of the subsurface layer performance. This field test plan outlines the activities required to test and design subsurface moisture barriers. The test plan covers activities completed in FY 1988 and planned through FY 1992 and includes a field-scale test of one or more of the alternate barriers to demonstrate full-scale application techniques and to provide performance data on a larger scale. Tests on asphalt, clay, and chemical grout were initiated in FY 1988 in small (30.5 cm diameter) tube-layer lysimeters. The parameters used for testing the materials were different for each one. The tests had to take into account the differences in material characteristics and response to change in conditions, as well as information provided by previous studies. 33 refs., 8 figs., 1 tab.

  14. Shale disposal of U.S. high-level radioactive waste.

    SciTech Connect (OSTI)

    Sassani, David Carl; Stone, Charles Michael; Hansen, Francis D.; Hardin, Ernest L.; Dewers, Thomas A.; Martinez, Mario J.; Rechard, Robert Paul; Sobolik, Steven Ronald; Freeze, Geoffrey A.; Cygan, Randall Timothy; Gaither, Katherine N.; Holland, John Francis; Brady, Patrick Vane

    2010-05-01

    This report evaluates the feasibility of high-level radioactive waste disposal in shale within the United States. The U.S. has many possible clay/shale/argillite basins with positive attributes for permanent disposal. Similar geologic formations have been extensively studied by international programs with largely positive results, over significant ranges of the most important material characteristics including permeability, rheology, and sorptive potential. This report is enabled by the advanced work of the international community to establish functional and operational requirements for disposal of a range of waste forms in shale media. We develop scoping performance analyses, based on the applicable features, events, and processes identified by international investigators, to support a generic conclusion regarding post-closure safety. Requisite assumptions for these analyses include waste characteristics, disposal concepts, and important properties of the geologic formation. We then apply lessons learned from Sandia experience on the Waste Isolation Pilot Project and the Yucca Mountain Project to develop a disposal strategy should a shale repository be considered as an alternative disposal pathway in the U.S. Disposal of high-level radioactive waste in suitable shale formations is attractive because the material is essentially impermeable and self-sealing, conditions are chemically reducing, and sorption tends to prevent radionuclide transport. Vertically and laterally extensive shale and clay formations exist in multiple locations in the contiguous 48 states. Thermal-hydrologic-mechanical calculations indicate that temperatures near emplaced waste packages can be maintained below boiling and will decay to within a few degrees of the ambient temperature within a few decades (or longer depending on the waste form). Construction effects, ventilation, and the thermal pulse will lead to clay dehydration and deformation, confined to an excavation disturbed zone within a few meters of the repository, that can be reasonably characterized. Within a few centuries after waste emplacement, overburden pressures will seal fractures, resaturate the dehydrated zones, and provide a repository setting that strongly limits radionuclide movement to diffusive transport. Coupled hydrogeochemical transport calculations indicate maximum extents of radionuclide transport on the order of tens to hundreds of meters, or less, in a million years. Under the conditions modeled, a shale repository could achieve total containment, with no releases to the environment in undisturbed scenarios. The performance analyses described here are based on the assumption that long-term standards for disposal in clay/shale would be identical in the key aspects, to those prescribed for existing repository programs such as Yucca Mountain. This generic repository evaluation for shale is the first developed in the United States. Previous repository considerations have emphasized salt formations and volcanic rock formations. Much of the experience gained from U.S. repository development, such as seal system design, coupled process simulation, and application of performance assessment methodology, is applied here to scoping analyses for a shale repository. A contemporary understanding of clay mineralogy and attendant chemical environments has allowed identification of the appropriate features, events, and processes to be incorporated into the analysis. Advanced multi-physics modeling provides key support for understanding the effects from coupled processes. The results of the assessment show that shale formations provide a technically advanced, scientifically sound disposal option for the U.S.

  15. Report on International Collaboration Involving the FE Heater and HG-A Tests at Mont Terri

    SciTech Connect (OSTI)

    Houseworth, Jim; Rutqvist, Jonny; Asahina, Daisuke; Chen, Fei; Vilarrasa, Victor; Liu, Hui-Hai; Birkholzer, Jens

    2013-11-06

    Nuclear waste programs outside of the US have focused on different host rock types for geological disposal of high-level radioactive waste. Several countries, including France, Switzerland, Belgium, and Japan are exploring the possibility of waste disposal in shale and other clay-rich rock that fall within the general classification of argillaceous rock. This rock type is also of interest for the US program because the US has extensive sedimentary basins containing large deposits of argillaceous rock. LBNL, as part of the DOE-NE Used Fuel Disposition Campaign, is collaborating on some of the underground research laboratory (URL) activities at the Mont Terri URL near Saint-Ursanne, Switzerland. The Mont Terri project, which began in 1995, has developed a URL at a depth of about 300 m in a stiff clay formation called the Opalinus Clay. Our current collaboration efforts include two test modeling activities for the FE heater test and the HG-A leak-off test. This report documents results concerning our current modeling of these field tests. The overall objectives of these activities include an improved understanding of and advanced relevant modeling capabilities for EDZ evolution in clay repositories and the associated coupled processes, and to develop a technical basis for the maximum allowable temperature for a clay repository. The R&D activities documented in this report are part of the work package of natural system evaluation and tool development that directly supports the following Used Fuel Disposition Campaign (UFDC) objectives: ? Develop a fundamental understanding of disposal-system performance in a range of environments for potential wastes that could arise from future nuclear-fuel-cycle alternatives through theory, simulation, testing, and experimentation. ? Develop a computational modeling capability for the performance of storage and disposal options for a range of fuel-cycle alternatives, evolving from generic models to more robust models of performance assessment. For the purpose of validating modeling capabilities for thermal-hydro-mechanical (THM) processes, we developed a suite of simulation models for the planned full-scale FE Experiment to be conducted in the Mont Terri URL, including a full three-dimensional model that will be used for direct comparison to experimental data once available. We performed for the first time a THM analysis involving the Barcelona Basic Model (BBM) in a full three-dimensional field setting for modeling the geomechanical behavior of the buffer material and its interaction with the argillaceous host rock. We have simulated a well defined benchmark that will be used for codeto- code verification against modeling results from other international modeling teams. The analysis highlights the complex coupled geomechanical behavior in the buffer and its interaction with the surrounding rock and the importance of a well characterized buffer material in terms of THM properties. A new geomechanical fracture-damage model, TOUGH-RBSN, was applied to investigate damage behavior in the ongoing HG-A test at Mont Terri URL. Two model modifications have been implemented so that the Rigid-Body-Spring-Network (RBSN) model can be used for analysis of fracturing around the HG-A microtunnel. These modifications are (1) a methodology to compute fracture generation under compressive stress conditions and (2) a method to represent anisotropic elastic and strength properties. The method for computing fracture generation under compressive load produces results that roughly follow trends expected for homogeneous and layered systems. Anisotropic properties for the bulk rock were represented in the RBSN model using layered heterogeneity and gave bulk material responses in line with expectations. These model improvements were implemented for an initial model of fracture damage at the HG-A test. While the HG-A test model results show some similarities with the test observations, differences between the model results and observations remain.

  16. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank Farm Blend) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-08-21

    The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP’s LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750°C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at <2g/m2 during ASTM C1285 (Product Consistency) durability testing. Monolithing of the granular FBSR product was investigated to prevent dispersion during transport or burial/storage. Monolithing in an inorganic geopolymer binder, which is amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for total constituents and durability tested as a granular waste form. A subset of the granular material was stabilized in a clay based geopolymer matrix at 42% and 65% FBSR loadings and durability tested as a monolith waste form. The 65 wt% FBSR loaded monolith made with clay (radioactive) was more durable than the 67-68 wt% FBSR loaded monoliths made from fly ash (non-radioactive) based on short term PCT testing. Long term, 90 to 107 day, ASTM C1308 testing (similar to ANSI/ANS 16.1 testing) was only performed on two fly ash geopolymer monoliths at 67-68 wt% FBSR loading and three clay geopolymer monoliths at 42 wt% FBSR loading. More clay geopolymers need to be made and tested at longer times at higher FBSR loadings for comparison to the fly ash monoliths. Monoliths made with metakaolin (heat treated) clay are of a more constant composition and are very reactive as the heat treated clay is amorphous and alkali activated. The monoliths made with fly ash are subject to the inherent compositional variation found in fly ash as it is a waste product from burning coal and it contains unreactive components such as mullite. However, both the fly ash and the clay based monoliths perform well in long term ASTM C1308 testing. Extensive testing and characterization of the granular and monolith material were made including the following American Society of Testing and Materials (ASTM) tests: ASTM C1285 testing (Product Consistency Test) of granular and monolithic waste forms; Comparison of granular BSR radioactive to ESTD and pilot scale granular non-radioactive waste form made from the Rassat simulant  Comparison of granular radioactive to granular non-radioactive waste form made from the Rassat simulant made using the SRNL BSR; Comparison of monolithic BSR radioactive waste forms to monolithic BSR and ESTD non-radioactive waste forms made of fly ash; Comparison of granular BSR radioactive waste forms to monolithic BSR non-radioactive waste forms made of fly ash; Comparison of granular BSR radioactive waste forms to monolithic BSR non-radioactive waste forms made of clay; ASTM C1308 Accelerated Leach Test for Diffusive Releases from Solidified Waste and a Computer Program to Model Diffusive, Fractional Leaching from Cylindrical Waste Forms; Comparison of BSR non-radioactive waste forms to monolithic ESTD non-radioactive waste forms made from fly ash; Testing of BSR non-radioactive monoliths made from clay for comparison to non-radioactive monoliths made from fly ash; ASTM C39 Compressive Strength of Cylindrical Concrete Specimens; Comparison of monolithic BSR radioactive waste forms to monolithic BSR and ESTD non-radioactive waste forms; EPA Manual SW-846 Method 1311, Toxicity Characteristic Leaching Procedure (TCLP); Comparison of granular BSR radioactive to ESTD and pilot scale granular non-radioactive waste form made from the Rassat simulant; Comparison of granular radioactive to granular non-radioactive waste form made from the Rassat simulant made using the SRNL BSR; Comparison of monolithic BSR radioactive waste forms to monolithic BSR non-radioactive waste forms.

  17. Development of Recycling Compatible Pressure-Sensitive Adhesives and Coatings

    SciTech Connect (OSTI)

    Steven J. Severtson

    2010-02-15

    The objective of this project was the design of new water-based pressure-sensitive adhesive (PSA) products and coatings engineered for enhanced removal during the processing of recycled fiber. Research included the formulation, characterization, and performance measurements of new screenable coatings, testing of modified paper and board substrates and the design of test methods to characterize the inhibition of adhesive and coating fragmentation and relative removal efficiencies of developed formulations. This project was operated under the requirements that included commercially viable approaches be the focus, that findings be published in the open literature and that new strategies could not require changes in the methods and equipment used to produce PSA and PS labels or in the recycling process. The industrial partners benefited through the building of expertise in their company that they would not, and likely could not, have pursued if it had not been for the partnership. Results of research on water-based PSAs clearly identifies which PSA and paper facestock properties govern the fragmentation of the adhesive and provide multiple strategies for making (pressure-sensitive) PS labels for which the PSA is removed at very high efficiencies from recycling operations. The application of these results has led to the identification of several commercial products in Franklin Internationals (industrial partner) product line that are recycling compatible. Several new formulations were also designed and are currently being scaled-up. Work on recycling compatible barrier coatings for corrugated containers examined the reinforcement of coatings using a small amount of exfoliated organically modified montmorillonite (OMMT). These OMMT/paraffin wax nanocomposites demonstrated significantly improved mechanical properties. Paraffin waxes containing clay were found to have significantly higher Youngs moduli and yield stress relative to the wax matrix, but the most impressive finding was the impact of the clay on the elongation at break; a nearly 400% increase was observed for a clay concentration of 0.5 wt.%. These coatings also demonstrate a number of other property enhancements, which make them a good candidate for continued research. Another approach explored in this research was the use of structured and self-cleaning surfaces. If the amount of coating utilized can be significantly reduced, the environmental impact is diminished.

  18. Weathering of Roofing Materials-An Overview

    SciTech Connect (OSTI)

    Berdahl, Paul; Akbari, Hashem; Levinson, Ronnen; Miller, William A.

    2006-03-30

    An overview of several aspects of the weathering of roofing materials is presented. Degradation of materials initiated by ultraviolet radiation is discussed for plastics used in roofing, as well as wood and asphalt. Elevated temperatures accelerate many deleterious chemical reactions and hasten diffusion of material components. Effects of moisture include decay of wood, acceleration of corrosion of metals, staining of clay, and freeze-thaw damage. Soiling of roofing materials causes objectionable stains and reduces the solar reflectance of reflective materials. (Soiling of non-reflective materials can also increase solar reflectance.) Soiling can be attributed to biological growth (e.g., cyanobacteria, fungi, algae), deposits of organic and mineral particles, and to the accumulation of flyash, hydrocarbons and soot from combustion.

  19. Remaining Sites Verification Package for the 100-F-44:2, Discovery Pipeline Near 108-F Building, Waste Site Reclassification Form 2007-006

    SciTech Connect (OSTI)

    J. M. Capron

    2008-05-30

    The 100-F-44:2 waste site is a steel pipeline that was discovered in a junction box during confirmatory sampling of the 100-F-26:4 pipeline from December 2004 through January 2005. The 100-F-44:2 pipeline feeds into the 100-F-26:4 subsite vitrified clay pipe (VCP) process sewer pipeline from the 108-F Biology Laboratory at the junction box. In accordance with this evaluation, the confirmatory sampling results support a reclassification of this site to No Action. The current site conditions achieve the remedial action objectives and the corresponding remedial action goals established in the Remaining Sites ROD. The results of confirmatory sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River.

  20. Selection and durability of seal materials for a bedded salt repository: preliminary studies

    SciTech Connect (OSTI)

    Roy, D.M.; Grutzeck, M.W.; Wakeley, L.D.

    1983-11-01

    This report details preliminary results of both experimental and theoretical studies of cementitious seal materials for use in a proposed nuclear waste repository in bedded salt. Effects of changes in bulk composition and environment upon phase stability and physical/mechanical properties have been evaluated for more than 25 formulations. Bonding and interfacial characteristics of the region between host rock and seal material or concrete aggregate and cementitious matrix for selected formulations have been studied. Compatibilities of clays and zeolites in brines typical of the SE New Mexico region have been investigated, and their stabilities reviewed. Results of these studies have led to the conclusion that cementitious materials can be formulated which are compatible with the major rock types in a bedded salt repository environment. Strengths are more than adequate, permeabilities are consistently very low, and elastic moduli generally increase only very slightly with time. Seal formulation guidelines and recommendations for present and future work are presented. 73 references, 25 figures, 61 tables.

  1. Comparing of Normal Stress Distribution in Static and Dynamic Soil-Structure Interaction Analyses

    SciTech Connect (OSTI)

    Kholdebarin, Alireza; Massumi, Ali; Davoodi, Mohammad; Tabatabaiefar, Hamid Reza

    2008-07-08

    It is important to consider the vertical component of earthquake loading and inertia force in soil-structure interaction analyses. In most circumstances, design engineers are primarily concerned about the analysis of behavior of foundations subjected to earthquake-induced forces transmitted from the bedrock. In this research, a single rigid foundation with designated geometrical parameters located on sandy-clay soil has been modeled in FLAC software with Finite Different Method and subjected to three different vertical components of earthquake records. In these cases, it is important to evaluate effect of footing on underlying soil and to consider normal stress in soil with and without footing. The distribution of normal stress under the footing in static and dynamic states has been studied and compared. This Comparison indicated that, increasing in normal stress under the footing caused by vertical component of ground excitations, has decreased dynamic vertical settlement in comparison with static state.

  2. Map showing landslide susceptibility in Prince Georges County, Maryland

    SciTech Connect (OSTI)

    Pomeroy, J.S.

    1989-01-01

    Prince Georges County was identified during a statewide investigation of landslide susceptibility (MF-2048) as the county with the most serious slope-stability problems. This map uses a ranking system ranging from 1 (nil to very low susceptibility) to 4 (moderate to severe susceptibility). Geologic factors and precipitation are major elements in the initiation of landslides in the county. The Potomac Group and the Marlboro Clay are the most slideprone units. This map should enable users to make a rapid, generalized evaluation of the potential for mass movement. Planners, engineers, soil scientists, geologist, university faculty, and elected officials should find it useful in the assessment of slope hazards for county-wide analyses.

  3. Ceramic fiber ceramic matrix filter development

    SciTech Connect (OSTI)

    Judkins, R.R.; Stinton, D.P.; Smith, R.G.; Fischer, E.M.

    1994-09-01

    The objectives of this project were to develop a novel type of candle filter based on a ceramic fiber-ceramic matrix composite material, and to extend the development to full-size, 60-mm OD by 1-meter-long candle filters. The goal is to develop a ceramic filter suitable for use in a variety of fossil energy system environments such as integrated coal gasification combined cycles (IGCC), pressurized fluidized-bed combustion (PFBC), and other advanced coal combustion environments. Further, the ceramic fiber ceramic matrix composite filter, hereinafter referred to as the ceramic composite filter, was to be inherently crack resistant, a property not found in conventional monolithic ceramic candle filters, such as those fabricated from clay-bonded silicon carbide. Finally, the adequacy of the filters in the fossil energy system environments is to be proven through simulated and in-plant tests.

  4. Remaining Sites Verification Package for the 100-F-26:13, 108-F Drain Pipelines, Waste Site Reclassification Form 2005-011

    SciTech Connect (OSTI)

    L. M. Dittmer

    2008-03-03

    The 100-F-26:13 waste site is the network of process sewer pipelines that received effluent from the 108-F Biological Laboratory and discharged it to the 188-F Ash Disposal Area (126-F-1 waste site). The pipelines included one 0.15-m (6-in.)-, two 0.2-m (8-in.)-, and one 0.31-m (12-in.)-diameter vitrified clay pipe segments encased in concrete. In accordance with this evaluation, the verification sampling results support a reclassification of this site to Interim Closed Out. The results of verification sampling demonstrated that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also showed that residual contaminant concentrations are protective of groundwater and the Columbia River.

  5. Final Report DOE Contract No. DE-FG36-04G014294 ICEKAP 2004: A Collaborative Joint Geophysical Imaging Project at Krafla and IDDP P.E. Malin, S.A. Onacha, E. Shalev Division of Earth and Ocean Sciences Nicholas School of the Environment Duke University Durham, NC 27708

    SciTech Connect (OSTI)

    Malin, Peter E.; Shalev, Eylon; Onacha, Stepthen A.

    2006-12-15

    In this final report, we discuss both theoretical and applied research resulting from our DOE project, ICEKAP 2004: A Collaborative Joint Geophysical Imaging Project at Krafla and IDDP. The abstract below begins with a general discussion of the problem we addressed: the location and characterization of blind geothermal resources using microearthquake and magnetotelluric measurements. The abstract then describes the scientific results and their application to the Krafla geothermal area in Iceland. The text following this abstract presents the full discussion of this work, in the form of the PhD thesis of Stephen A. Onacha. The work presented here was awarded the Best Geophysics Paper at the 2005 Geothermal Resources Council meeting, Reno. This study presents the modeling of buried fault zones using microearthquake and electrical resistivity data based on the assumptions that fluid-filled fractures cause electrical and seismic anisotropy and polarization. In this study, joint imaging of electrical and seismic data is used to characterize the fracture porosity of the fracture zones. P-wave velocity models are generated from resistivity data and used in locating microearthquakes. Fracture porosity controls fluid circulation in the hydrothermal systems and the intersections of fracture zones close to the heat source form important upwelling zones for hydrothermal fluids. High fracture porosity sites occur along fault terminations, fault-intersection areas and fault traces. Hydrothermal fault zone imaging using resistivity and microearthquake data combines high-resolution multi-station seismic and electromagnetic data to locate rock fractures and the likely presence fluids in high temperature hydrothermal systems. The depths and locations of structural features and fracture porosity common in both the MT and MEQ data is incorporated into a joint imaging scheme to constrain resistivity, seismic velocities, and locations of fracture systems. The imaging of the fault zones is constrained by geological, drilling, and geothermal production data. The objective is to determine interpretation techniques for evaluating structural controls of fluid circulation in hydrothermal systems. The conclusions are: directions of MT polarization and anisotropy and MEQ S-splitting correlate. Polarization and anisotropy are caused by fluid filled fractures at the base of the clay cap. Microearthquakes occur mainly on the boundary of low resistivity within the fracture zone and high resistivity in the host rock. Resistivity is lowest within the core of the fracture zone and increases towards the margins of the fracture zone. The heat source and the clay cap for the hydrothermal have very low resistivity of less than 5?m. Fracture porosity imaged by resistivity indicates that it varies between 45-5% with most between 10-20%, comparable to values from core samples in volcanic areas in Kenya and Iceland. For resistivity values above 60?m, the porosity reduces drastically and therefore this might be used as the upper limit for modeling fracture porosity from resistivity. When resistivity is lower than 5?m, the modeled fracture porosity increases drastically indicating that this is the low resistivity limit. This is because at very low resistivity in the heat source and the clay cap, the resistivity is dominated by ionic conduction rather than fracture porosity. Microearthquakes occur mainly above the heat source which is defined by low resistivity at a depth of 3-4.5 km at the Krafla hydrothermal system and 4-7 km in the Longonot hydrothermal system. Conversions of S to P waves occur for microearthquakes located above the heat source within the hydrothermal system. Shallow microearthquakes occur mainly in areas that show both MT and S-wave anisotropy. S-wave splitting and MT anisotropy occurs at the base of the clay cap and therefore reflects the variations in fracture porosity on top of the hydrothermal system. In the Krafla hydrothermal system in Iceland, both MT polarization and MEQ splitting directions align with

  6. A new generation of refractory concretes colloid-chemical aspect of their technology

    SciTech Connect (OSTI)

    Pivinskii, Y.E.

    1994-09-01

    Some peculiarities of the technology of new refractory concretes (ceramoconcretes, low-cement refractory concretes, and vibrocompacted thixotropic fluid refractory pastes) are analyzed from the standpoint of modern colloid chemistry. Interactions of disperse particles and the aggregation stability of disperse systems are discussed. Using a highly concentrated binding suspension (HCBS) of quartz glass as an example, a diagram of the regions of stability and coagulation of particles depending on the pH index of the suspension has been constructed. The state and form of the bonds of water in disperse systems are analyzed. It is shown for clays and HCBS of a number of materials that the strength properties of binders depend on the electrokinetic potential of the initial disperse system. A correlation between the acid-basic properties of the solid phase and the characteristics of the binder is demonstrated. The effects of heterocoagulation in systems with a mixed solid phase are also discussed.

  7. Methods for enhancing mapping of thermal fronts in oil recovery

    DOE Patents [OSTI]

    Lee, D.O.; Montoya, P.C.; Wayland, J.R. Jr.

    1984-03-30

    A method for enhancing the resistivity contrasts of a thermal front in an oil recovery production field as measured by the controlled source audio frequency magnetotelluric (CSAMT) technique is disclosed. This method includes the steps of: (1) preparing a CSAMT-determined topological resistivity map of the production field; (2) introducing a solution of a dopant material into the production field at a concentration effective to alter the resistivity associated with the thermal front; said dopant material having a high cation exchange capacity which might be selected from the group consisting of montmorillonite, illite, and chlorite clays; said material being soluble in the conate water of the production field; (3) preparing a CSAMT-determined topological resistivity map of the production field while said dopant material is moving therethrough; and (4) mathematically comparing the maps from step (1) and step (3) to determine the location of the thermal front. This method is effective with the steam flood, fire flood and water flood techniques.

  8. Complete Genome Sequence of Pelosinus sp. Strain UFO1 Assembled Using Single-Molecule Real-Time DNA Sequencing Technology

    SciTech Connect (OSTI)

    Steven D. Brown; Sagar M. Utturkar; Timothy S. Magnuson; Allison E. Ray; Farris L. Poole; W. Andrew Lancaster; Michael P. Thorgersen; Michael W. W. Adams; Dwayne A. Elias

    2014-09-01

    Pelosinus fermentans strain R7 was isolated from Russian kaolin clays as the type strain and it can reduce Fe(III) during fermentative growth (1). Draft genome sequences for P. fermentans R7 and four strains from Hanford, Washington, USA, have been published (24). The P. fermentans 16S rRNA sequence dominated the lactate-based enrichment cultures from three geochemically contrasting soils from the Melton Branch Watershed, Oak Ridge, Tennessee, USA (5) and also at another stimulated, uraniumcontaminated field site near Oak Ridge (6). For the current work, strain UFO1 was isolated from pristine sediments at a background field site in Oak Ridge and characterized as facilitating U(VI) reduction and precipitation with phosphate (7).

  9. Soil stabilization using oil-shale solid waste

    SciTech Connect (OSTI)

    Turner, J.P. (Univ. of Wyoming, Laramie, WY (United States). Dept. of Civil and Archeological Engineering)

    1994-04-01

    Oil-shale solid wastes are evaluated for use as soil stabilizers. A laboratory study consisted of the following tests on compacted samples of soil treated with water and spent oil shale: unconfined compressive strength, moisture-density relationships, wet-dry and freeze-thaw durability, and resilient modulus. Significant increases in strength, durability, and resilient modulus were obtained by treating a silty sand with combusted western oil shale. Moderate increases in durability and resilient modulus were obtained by treating a highly plastic clay with combusted western oil shale. Solid waste from eastern oil shale appears to be feasible for soil stabilization only if limestone is added during combustion. Testing methods, results, and recommendations for mix design of spent shale-stabilized pavement subgrades are presented and the mechanisms of spent-shale cementation are discussed.

  10. Utilization of Estonian oil shale at power plants

    SciTech Connect (OSTI)

    Ots, A. [Tallin Technical Univ. (Estonia). Thermal Engineering Department

    1996-12-31

    Estonian oil shale belongs to the carbonate class and is characterized as a solid fuel with very high mineral matter content (60--70% in dry mass), moderate moisture content (9--12%) and low heating value (LHV 8--10 MJ/kg). Estonian oil shale deposits lie in layers interlacing mineral stratas. The main constituent in mineral stratas is limestone. Organic matter is joined with sandy-clay minerals in shale layers. Estonian oil shale at power plants with total capacity of 3060 MW{sub e} is utilized in pulverized form. Oil shale utilization as fuel, with high calcium oxide and alkali metal content, at power plants is connected with intensive fouling, high temperature corrosion and wear of steam boiler`s heat transfer surfaces. Utilization of Estonian oil shale is also associated with ash residue use in national economy and as absorbent for flue gas desulfurization system.

  11. Soil stabilization using oil shale solid wastes: Laboratory evaluation of engineering properties

    SciTech Connect (OSTI)

    Turner, J.P.

    1991-01-01

    Oil shale solid wastes were evaluated for possible use as soil stabilizers. A laboratory study was conducted and consisted of the following tests on compacted samples of soil treated with water and spent oil shale: unconfined compressive strength, moisture-density relationships, wet-dry and freeze-thaw durability, and resilient modulus. Significant increases in strength, durability, and resilient modulus were obtained by treating a silty sand with combusted western oil shale. Moderate increases in strength, durability, and resilient modulus were obtained by treating a highly plastic clay with combusted western oil shale. Solid waste from eastern shale can be used for soil stabilization if limestone is added during combustion. Without limestone, eastern oil shale waste exhibits little or no cementation. The testing methods, results, and recommendations for mix design of spent shale-stabilized pavement subgrades are presented. 11 refs., 3 figs., 10 tabs.

  12. Oxidizer gels for detoxification of chemical and biological agents

    DOE Patents [OSTI]

    Hoffman, Dennis M.; McGuire, Raymond R.

    2002-01-01

    A gel composition containing oxidizing agents and thickening or gelling agents is used to detoxify chemical and biological agents by application directly to a contaminated area. The gelling agent is a colloidal material, such as silica, alumina, or alumino-silicate clays, which forms a viscous gel that does not flow when applied to tilted or contoured surfaces. Aqueous or organic solutions of oxidizing agents can be readily gelled with less than about 30% colloidal material. Gel preparation is simple and suitable for field implementation, as the gels can be prepared at the site of decontamination and applied quickly and uniformly over an area by a sprayer. After decontamination, the residue can be washed away or vacuumed up for disposal.

  13. SALINITY AND SODICITY INTERACTIONS OF WEATHERED MINESOILS IN NORTHWESTERN NEW MEXICO AND NORTH EASTERN ARIZONA

    SciTech Connect (OSTI)

    Brent Musslewhite; Song Jin

    2006-05-01

    Weathering characteristics of minesoils and rooting patterns of key shrub and grass species were evaluated at sites reclaimed for 6 to 14 years from three surface coal mine operations in northwestern New Mexico and northeastern Arizona. Non-weathered minesoils were grouped into 11 classifications based on electrical conductivity (EC) and sodium adsorption ratio (SAR). Comparisons of saturated paste extracts, from non-weathered and weathered minesoils show significant (p < 0.05) reductions in SAR levels and increased EC. Weathering increased the apparent stability of saline and sodic minesoils thereby reducing concerns of aggregate slaking and clay particle dispersion. Root density of four-wing saltbush (Atriplex canascens), alkali sacaton (Sporobolus airoides), and Russian wildrye (Psathyrostachys junceus) were nominally affected by increasing EC and SAR levels in minesoil. Results suggest that saline and sodic minesoils can be successfully reclaimed when covered with topsoil and seeded with salt tolerant plant species.

  14. Alkaline Waterflooding Demonstration Project, Ranger Zone, Long Beach Unit, Wilmington Field, California. Fourth annual report, June 1979-May 1980. Volume 3. Appendices II-XVII

    SciTech Connect (OSTI)

    Carmichael, J.D.

    1981-03-01

    Volume 3 contains Appendices II through XVII: mixing instructions for sodium orthosilicate; oil displacement studies using THUMS C-331 crude oil and extracted reservoir core material from well B-110; clay mineral analysis of B-827-A cores; sieve analysis of 4 Fo sand samples from B-110-IA and 4 Fo sand samples from B-827-A; core record; delayed secondary caustic consumption tests; long-term alkaline consumption in reservoir sands; demulsification study for THUMS Long Beach Company, Island White; operating plans and instructions for DOE injection demonstration project, alkaline injection; caustic pilot-produced water test graphs; well test irregularities (6/1/79-5/31/80); alkaline flood pump changes (6/1/79-5/31/80); monthly DOE pilot chemical waterflood injection reports (preflush injection, alkaline-salt injection, and alkaline injection without salt); and caustic safety procedures-alkaline chemicals.

  15. Complete genome sequence of Pelosinus sp. strain UFO1 assembled using single-molecule real-time DNA sequencing technology

    SciTech Connect (OSTI)

    Brown, Steven D.; Utturkar, Sagar M.; Magnuson, Timothy S.; Ray, Allison E.; Poole, Farris L.; Lancaster, W. Andrew; Thorgersen, Michael P.; Adams, Michael W. W.; Elias, Dwayne A.

    2014-09-04

    Pelosinus fermentans strain R7 was isolated from Russian kaolin clays as the type strain and it can reduce Fe(III) during fermentative growth (1). Draft genome sequences for P. fermentans R7 and four strains from Hanford, Washington, USA, have been published (24). The P. fermentans 16S rRNA sequence dominated the lactate-based enrichment cultures from three geochemically contrasting soils from the Melton Branch Watershed, Oak Ridge, Tennessee, USA (5) and also at another stimulated, uraniumcontaminated field site near Oak Ridge (6). For the current work, strain UFO1 was isolated from pristine sediments at a background field site in Oak Ridge and characterized as facilitating U(VI) reduction and precipitation with phosphate (7).

  16. Methods for enhancing mapping of thermal fronts in oil recovery

    DOE Patents [OSTI]

    Lee, David O. (Albuquerque, NM); Montoya, Paul C. (Albuquerque, NM); Wayland, Jr., James R. (Albuquerque, NM)

    1987-01-01

    A method for enhancing the resistivity contrasts of a thermal front in an oil recovery production field as measured by the CSAMT technique is disclosed. This method includes the steps of: (a) preparing a CSAMT-determined topological resistivity map of the production field; (b) introducing a solution of a dopant material into the production field at a concentration effective to alter the resistivity associated with the thermal front; said dopant material having a high cation exchange capacity which might be selected from the group consisting of montmorillonite, illite, and chlorite clays; said material being soluble in the connate water of the production field; (c) preparing a CSAMT-determined topological resistivity map of the production field while said dopant material is moving therethrough; and (d) mathematically comparing the maps from step (a) and step (c) to determine the location of the thermal front. This method is effective with the steam flood, fire flood and water flood techniques.

  17. Complete genome sequence of Pelosinus sp. strain UFO1 assembled using single-molecule real-time DNA sequencing technology

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brown, Steven D.; Utturkar, Sagar M.; Magnuson, Timothy S.; Ray, Allison E.; Poole, Farris L.; Lancaster, W. Andrew; Thorgersen, Michael P.; Adams, Michael W. W.; Elias, Dwayne A.

    2014-09-04

    Pelosinus fermentans strain R7 was isolated from Russian kaolin clays as the type strain and it can reduce Fe(III) during fermentative growth (1). Draft genome sequences for P. fermentans R7 and four strains from Hanford, Washington, USA, have been published (2–4). The P. fermentans 16S rRNA sequence dominated the lactate-based enrichment cultures from three geochemically contrasting soils from the Melton Branch Watershed, Oak Ridge, Tennessee, USA (5) and also at another stimulated, uraniumcontaminated field site near Oak Ridge (6). For the current work, strain UFO1 was isolated from pristine sediments at a background field site in Oak Ridge and characterizedmore » as facilitating U(VI) reduction and precipitation with phosphate (7).« less

  18. Rare earth element behavior in the development of energy resources

    SciTech Connect (OSTI)

    Laul, J.C.

    1984-04-02

    The REE patterns in soil-soil extract-plant-coal-flyash are all identical, show a negative Eu anomaly, and follow a smooth function of the REE ionic radii. The patterns are similar to that observed in the secondary mineral apatite. Their enrichment factors in various liquefaction products and ash depositories of a coal fired power plant are nearly unity (Class 1). The REE do not chemically fractionate even in size fractions 25 ..mu..m-0.5 ..mu..m of flyash. Almost all (99%) of the REE are bound in an inorganic form in high temperature clay minerals. The remarkable similarity in REE patterns in a wide variety of matrices with REE content varying over six orders of magnitude demonstrates that the REE do not significantly fractionate during transformation from the geological-biological-geological chain over geological time scales.

  19. Field studies of the potential for wind transport of plutonium- contaminated soils at sites in Areas 6 and 11, Nevada Test Site

    SciTech Connect (OSTI)

    Lancaster, N.; Bamford, R.; Metzger, S.

    1995-07-01

    This report describes and documents a series of field experiments carried out in Areas 6 and 11 of the Nevada Test Site in June and July 1994 to determine parameters of boundary layer winds, surface characteristics, and vegetation cover that can be used to predict dust emissions from the affected sites. Aerodynamic roughness of natural sites is determined largely by the lateral cover of the larger and more permanent roughness elements (shrubs). These provide a complete protection of the surface from wind erosion. Studies using a field-portable wind tunnel demonstrated that natural surfaces in the investigated areas of the Nevada Test Site are stable except at very high wind speeds (probably higher than normally occur, except perhaps in dust devils). However, disturbance of silty-clay surfaces by excavation devices and vehicles reduces the entrainment threshold by approximately 50% and makes these areas potentially very susceptible to wind erosion and transport of sediments.

  20. Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

    2012-10-22

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.