Sample records for boone cabell clay

  1. William L. Cabell: Citizen, soldier, politician

    E-Print Network [OSTI]

    Harvey, Paul Howe

    1970-01-01T23:59:59.000Z

    back in Virginia history to 1724. William Cabell was reared in a Southern area, by a Southern family and, therefore, learned and accepted the ideas of the South. In 1846 William entered the United States Military Academy at. West Point and graduated..., the West, and the South, were already having an impact on the shaping of American history. Many Southerners believed that their section was being treated unfairly because of 26 Ibid. , 248-53, 511. Ibid. , 512. 2B William Lewis Cabell, Memoirs...

  2. Cabell County, West Virginia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

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  3. BooNE: About BooNE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccess Stories Site MapSolar energy(cousin -in-lawHomeAbout BooNE

  4. Boone County Rural EMC | Open Energy Information

    Open Energy Info (EERE)

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  5. Boone, Iowa: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

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  6. Clay Minerals

    SciTech Connect (OSTI)

    Mueller, Karl T.; Sanders, Rebecca L.; Washton, Nancy M.

    2014-03-14T23:59:59.000Z

    Clay minerals are important components of the environment and are involved or implicated in processes such as the uptake of pollutants and the release of nutrients and as potential platforms for a number of chemical reactions. Owing to their small particle sizes (typically, on the order of microns or smaller) and mixing with a variety of other minerals and soil components, advanced characterization methods are needed to study their structures, dynamics, and reactivities. In this article, we describe the use of solid-state NMR methods to characterize the structures and chemistries of clay minerals. Early one-pulse magic-angle spinning (MAS) NMR studies of 27Al and 29Si have now been enhanced and extended with new studies utilizing advanced methodologies (such as Multiple Quantum MAS) as well as studies of less-sensitive nuclei. In additional work, the issue of reactivity of clay minerals has been addressed, including studies of reactive surface area in the environment. Utilizations of NMR-sensitive nuclides within the clay minerals themselves, and in molecules that react with speci?c sites on the clay mineral surfaces, have aided in understanding the reactivity of these complex aluminosilicate systems.

  7. CLAY AND SHALE--2002 18.1 CLAY AND SHALE

    E-Print Network [OSTI]

    CLAY AND SHALE--2002 18.1 CLAY AND SHALE By Robert L. Virta Domestic survey data and tables were Roberts, international data coordinator. Companies in the United States mined six types of clays: ball clay, bentonite, common clay and shale, fire clay, fuller's earth, and kaolin. Ball clays consist

  8. Modeling Radionuclide Transport in Clays

    E-Print Network [OSTI]

    Zheng, L.

    2014-01-01T23:59:59.000Z

    Radionuclide Transport in Clays May 2012 Zheng, L. , J.a single sample of Opalinus Clay. Geochimica et Cosmochimicaadsorption onto kaolinite based clay minerals using FITEQL

  9. Clay and SHale--2004 18.1 Clay and Shale

    E-Print Network [OSTI]

    Clay and SHale--2004 18.1 Clay and Shale By Robert l. Virta Domestic survey data and tables were, and the world production tables were prepared by Linder Roberts, international data coordinator. Ball Clay.--In 2004, 4 companies mined ball clay from 47 pits in 4 States. Production of domestic ball clay

  10. CLAY AND SHALE--1999 18.1 CLAY AND SHALE

    E-Print Network [OSTI]

    CLAY AND SHALE--1999 18.1 CLAY AND SHALE By Robert L. Virta Domestic survey data and tables were Roberts, international data coordinator. The amount of clay sold or used by domestic producers in 1999. Production of ball clay, bentonite, common clay and shale, and fuller's earth increased, and production

  11. Query Optimization as a Datalog Program Mengmeng Liu, Zachary G. Ives, and Boon Thau Loo

    E-Print Network [OSTI]

    Loo, Boon Thau

    Query Optimization as a Datalog Program Mengmeng Liu, Zachary G. Ives, and Boon Thau Loo University is that of specifying the transformation rules and search process of a query optimizer [1]. In certain emerging domains universally understood than the languages used in transformational optimizers like those generated by Volcano

  12. CLAY AND SHALE--1998 R1 CLAY AND SHALE

    E-Print Network [OSTI]

    CLAY AND SHALE--1998 R1 CLAY AND SHALE By Robert L. Virta Domestic survey data and tables were of clay sold or used by domestic producers in 1998 was 41.6 million metric tons (Mt) valued at $1.66 billion, essentially unchanged from that of 1997. Production of ball clay and kaolin increased

  13. Geosynthetic clay liner applications

    SciTech Connect (OSTI)

    McGrath, L.T.; Creamer, P.D. [RMT, Inc., Madison, WI (United States)

    1995-05-01T23:59:59.000Z

    Geosynthetic clay liners (GCLs) are becoming a popular alternative to compacted clay barrier layers at sanitary landfills. They possess many of the same qualities of compacted clay barrier layers while occupying only a small fraction of the airspace. This is a very attractive feature to waste disposal facility owners and operators. Designing for, and constructing with, a GCL can be a challenging task--stability issues must be evaluated, selecting the appropriate product should be considered, comprehensive specifications are needed to ensure proper product selection and installation, and steps must be taken during installation to prevent damage to the GCL. Perhaps most importantly, state regulatory agencies must be convinced that GCLs will provide long-term protection that is equivalent to a clay barrier layer.

  14. Soil damping constants related to common soil properties in sands and clays 

    E-Print Network [OSTI]

    Gibson, Gary Clive

    1968-01-01T23:59:59.000Z

    SOIL D'c~. 'I'IIIG COESTAlxI. S PI', IslTED TO CO!~i'iOI& SOII. PRO& ERTIES J3I SAE1)S AND CL?"S A Thesis by Gary Olive G'boon Sr b':I' te'I to tho Gra=lu. . te Col lope of Texas Afxl Univcrsi ty in pert'al fulfillsent of the requirenent... for the Je;, ree of YiASTER Ol" SCIEI!CE August ISSS II. ';or Subject: Civil I:nSin er. nb SOIL DAMPING CONSTANTS REIATED TO COMMON SOIL PROPERTIES IN SANDS AND CLAYS A Thesis by Gary Clive Gibson Approved as to style and content by: (Head...

  15. Wellbore instability mechanisms in clays

    E-Print Network [OSTI]

    Akl, Sherif Adel

    2011-01-01T23:59:59.000Z

    This dissertation investigates the stability of wellbores drilled in Ko-consolidated clays using non-linear finite element method (FEM) and effective stress soil models to characterize the behavior of clay and unconsolidated ...

  16. Introduction Clays and health: An introduction

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Introduction Clays and health: An introduction "Clays are the materials for ceramics production" is the general idea of people about clays. However, clay minerals are not only the "most abundant components. Hundreds of uses reveal the utility of clays in very different fields (Odom, 1984; Jepson, 1984; Murray

  17. CLAY AND SHALE--2003 18.1 CLAY AND SHALE

    E-Print Network [OSTI]

    %), drilling mud (22%), and iron ore pelletizing (15%); for common clay and shale, brick (55%), cement (19 Protection Agency (EPA) finalized its maximum achievable control technology (MACT) regulation/Mg of uncalcined clay or a reduction of 30% in emissions. For new batch kilns, hydrogen fluoride and hydrogen

  18. CLAY AND SHALE--2001 18.1 CLAY AND SHALE

    E-Print Network [OSTI]

    %), drilling mud (17%), foundry sand bond (20%), and iron ore pelletizing (14%) for bentonite; brick (55 achievable control technology (MACT) requirements for the clay processing and manufacturing industries or used. Clay production was reported in all States except Alaska, Delaware, Hawaii, Idaho, New Hampshire

  19. Multiscale modeling of clay-water systems

    E-Print Network [OSTI]

    Ebrahimi, Davoud

    2014-01-01T23:59:59.000Z

    The engineering properties of soils are highly affected by clay content and clay-water interactions. However, existing macro-scale continuum models have no length scale to describe the evolution of the clay microstructure ...

  20. Clay Mathematics Proceedings Volume 12, 2009

    E-Print Network [OSTI]

    Sart, Remi

    Clay Mathematics Proceedings Volume 12, 2009 Renormalization in connected graded Hopf cO2008 Clay Mathemat* *ics Institute 1 #12

  1. Jamaican red clay tobacco pipes

    E-Print Network [OSTI]

    Heidtke, Kenan Paul

    1992-01-01T23:59:59.000Z

    JAMAICAN RED CLAY TOBACCO PIPES A Thesis by KENAN PAUL HEIDTKE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF ARTS December 1992 Major Subject...: Anthropology JAMAICAN RED CLAY TOBACCO PIPES A Thesis by KENAN PAUL HEIDTKE Approved as to style and content by: Dorm L. Hamilton (Chair of Committee) Frederick H. van Doorninck, J (Member) enry C. Schmidt (Member) Vaughn M. Bryant (Head...

  2. William L. Cabell: Citizen, soldier, politician 

    E-Print Network [OSTI]

    Harvey, Paul Howe

    1970-01-01T23:59:59.000Z

    surgical operations, and he supervised his servants in the fabrication of artificial legs. In addition, he prepared many of the drugs for his pharmacy 14 from rhubarb and various native plants. The aging physician was extremely proud of his library. He... 17 along the river. With the center of the state thus made more secure, Van Dorn could now focus his attention on the expected enemy main effort. By March 6, 1862, Curtis had his troops drawn up in a powerful defensive position near Pea Ri. dge...

  3. Webster Co. Kanawha Co. Cabell C

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14TotalTheE. Great Basin Oil andBOE Reserve Class No 2001

  4. Webster Co. Kanawha Co. Cabell C

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14TotalTheE. Great Basin Oil andBOE Reserve Class No

  5. Webster Co. Kanawha Co. Cabell C

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14TotalTheE. Great Basin Oil andBOE Reserve Class

  6. MATH 132: TOPOLOGY II: SMOOTH MANIFOLDS ANDREW COTTON-CLAY

    E-Print Network [OSTI]

    Cotton-Clay, Andrew

    MATH 132: TOPOLOGY II: SMOOTH MANIFOLDS ANDREW COTTON-CLAY 1. Introduction My Name: Andrew Cotton-Clay

  7. The Swelling of Clays Within Portland Brownstone

    E-Print Network [OSTI]

    Petta, Jason

    The Swelling of Clays Within Portland Brownstone Kelly Rich, Tim Wangler, George Scherer Civil within clay-bearing stone, causing damage to buildings QuickTimeTM and a TIFF (LZW) decompressor are needed to see this picture. Stressful! #12;Brownstone under SEM large quartz grains small clay flakes #12

  8. Stressed swelling clay Arpita Pal Bathija1

    E-Print Network [OSTI]

    Liang, Haiyi

    Stressed swelling clay Arpita Pal Bathija1 , Haiyi Liang2 , Ning Lu3 , Manika Prasad4 , and Michael Lee Batzle1 ABSTRACT Clay minerals are present in most sedimentary rocks. They find applicability- spite their abundance and use, swelling of clays under stress has not received enough scientific

  9. Lipid Peroxidation Induced by Expandable Clay Minerals

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Lipid Peroxidation Induced by Expandable Clay Minerals D A R I A K I B A N O V A , A N T O N I O N and toxicity. Herein, potential hazards of clay particle uptake areaddressed.Thispaperreportsthatthecontentanddistribution of structural Fe influence the ability of expandable clay minerals to induce lipid peroxidation (LP), a major

  10. Clay Minerals and Italy the Nannobacterial

    E-Print Network [OSTI]

    Yang, Zong-Liang

    Clay Minerals and Italy ­ the Nannobacterial Connection R. L. FOLK THE UNIVERSITY OF TEXAS AT AUSTIN This work is dedicated to F. Leo Lynch, a brilliant clay mineralogist who died in 2009. During Leo of nannobacterial precipitation of clay minerals were identified. (Lynch, 1994; Folk, Lynch & Rasbury, 1994). Leo

  11. PROGRAM AND ABSTRACTS FOR CLAY MINERALS SOCIETY

    E-Print Network [OSTI]

    Rathbun, Julie A.

    r PROGRAM AND ABSTRACTS FOR CLAY MINERALS SOCIETY 28th ANNUAL MEETING NI\\SI\\National Aeronautit &II LPI #12;PROGRAM AND ABSTRACTS FOR CLAY MINERALS SOCIETY 28th ANNUAL MEETING Houston, Texas October contains abstracts that have been accepted for presentation at the Clay Minerals Society 28th Annual

  12. CLAYS--2000 19.1 By Robert L. Virta

    E-Print Network [OSTI]

    CLAYS--2000 19.1 CLAYS By Robert L. Virta Domestic survey data and tables were prepared by Maria, international data coordinator. The amount of clay sold or used by domestic producers in 2000 was 40.8 million. Production of fire clay and fuller's earth increased, but production of ball clay, bentonite, common clay

  13. Contact micromechanics in granular media with clay

    SciTech Connect (OSTI)

    Ita, S.L.

    1994-08-01T23:59:59.000Z

    Many granular materials, including sedimentary rocks and soils, contain clay particles in the pores, grain contacts, or matrix. The amount and location of the clays and fluids can influence the mechanical and hydraulic properties of the granular material. This research investigated the mechanical effects of clay at grain-to-grain contacts in the presence of different fluids. Laboratory seismic wave propagation tests were conducted at ultrasonic frequencies using spherical glass beads coated with Montmorillonite clay (SWy-1) onto which different fluids were adsorbed. For all bead samples, seismic velocity increased and attenuation decreased as the contact stiffnesses increased with increasing stress demonstrating that grain contacts control seismic transmission in poorly consolidated and unconsolidated granular material. Coating the beads with clay added stiffness and introduced viscosity to the mechanical contact properties that increased the velocity and attenuation of the propagating seismic wave. Clay-fluid interactions were studied by allowing the clay coating to absorb water, ethyl alcohol, and hexadecane. Increasing water amounts initially increased seismic attenuation due to clay swelling at the contacts. Attenuation decreased for higher water amounts where the clay exceeded the plastic limit and was forced from the contact areas into the surrounding open pore space during sample consolidation. This work investigates how clay located at grain contacts affects the micromechanical, particularly seismic, behavior of granular materials. The need for this work is shown by a review of the effects of clays on seismic wave propagation, laboratory measurements of attenuation in granular media, and proposed mechanisms for attenuation in granular media.

  14. Broadband emission in InAs/InGaAlAs quantum-dash-in-well laser Boon S. Ooi1, a

    E-Print Network [OSTI]

    -broadband sources are generated using nonlinear-optical transformations of ultra-short laser pulses and photonicBroadband emission in InAs/InGaAlAs quantum-dash-in-well laser Boon S. Ooi1, a , Hery S. Djie1: Quantum dash, Quantum dot, Broadband emission, Semiconductor Laser. Abstract. We report on the development

  15. Clays and Clay Minerals. Vol. 40. No.3, 355-358, 1992. THE EFFECT OF CLAY DISPERSION ON THE SORPTION OF

    E-Print Network [OSTI]

    Sparks, Donald L.

    Clays and Clay Minerals. Vol. 40. No.3, 355-358, 1992. NOTES THE EFFECT OF CLAY DISPERSION ON THE SORPTION OF ACETONITRILE Key Words-Clay dispersion, Organic sorption, Partition, Sorption mechanism of solutes on clay minerals and soil materials for systems in which no specific bonding was involved

  16. Coupled hydro-mechanical processes in crytalline rock and in induratedand plastic clays: A comparative discussion

    E-Print Network [OSTI]

    Tsang, Chin-Fu; Blumling, Peter; Bernier, Frederic

    2008-01-01T23:59:59.000Z

    healing and self-sealing processes in clays. Applied ClayScience, Clays in Natural and Engineered Barriers forsurface model for cohesive clays. Soils and Foundations,

  17. Application of a Novel Clay Stabilizer to Mitigate Formation Damage due to Clay Swelling

    E-Print Network [OSTI]

    Clarke, Timothy

    2014-12-09T23:59:59.000Z

    Clay swelling and fines migration can cause formation damage of hydrocarbon bearing zones and prevent economic realization of oil/gas wells. Identification and management of clay particles in the formation is a necessary component of production...

  18. Clay Electric Cooperative, Inc- Energy Conservation Loans

    Broader source: Energy.gov [DOE]

    Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 North Florida counties, including Gainesville, Keystone Heights, Lake City, Orange Park, Palatka, and Salt Springs. It...

  19. Clay Electric Cooperative, Inc- Solar Thermal Loans

    Broader source: Energy.gov [DOE]

    Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 counties in northern Florida, including Gainesville, Keystone Heights, Lake City, Orange Park, Palatka, and Salt Springs....

  20. Clay Sell Sworn in as Deputy Secretary of Energy | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Clay Sell Sworn in as Deputy Secretary of Energy Clay Sell Sworn in as Deputy Secretary of Energy March 21, 2005 - 10:53am Addthis WASHINGTON, DC - Jeffrey Clay Sell was sworn in...

  1. Intercalation of Trichloroethene by Sediment-Associated Clay...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intercalation of Trichloroethene by Sediment-Associated Clay Minerals. Intercalation of Trichloroethene by Sediment-Associated Clay Minerals. Abstract: The objective of this...

  2. Problems in interpretation of clay fabrics

    SciTech Connect (OSTI)

    Reynolds, S.

    1987-05-01T23:59:59.000Z

    Several models have been developed to explain the origins of different clay fabrics as seen with the scanning electron microscope, but some of these models may be oversimplified. One microfabric model suggests that bioturbation leads to a randomization of fabric; nonbioturbated fabrics should exhibit a preferred orientation (PO) of clay particles in the horizontal direction. However, in samples from the Los Angeles basin, California, it was discovered that bioturbated, hemipelagic mudstones had essentially the same clay fabric as nonbioturbated, turbiditic mudstones; both were highly random. The effect of bioturbation was also studied in anoxic-laminated, nonbioturbated muds which exhibited isolated burrows (Pico Formation, Rosario Group, California; Niobrara Formation, Colorado). The clay fabric inside and outside the burrows was similar; diagenesis appeared to be the controlling factor of these microfabrics. Another common conception is that PO of clays is developed during consolidation. The only PO seen in the samples from the Los Angeles basin is of silt-sized detrital micas and diagenetic chlorite. Much of the PO which has been measured in recent sediments may be due to the PO of silt-sized micas, not clays; and PO in shales may be due to diagenetic growth of phyllosilicates under uniaxial pressure. Another model states that pelagic settling of clays will lead to the development of PO. The nonbioturbated mudstones of the Pico Formation display random clay fabrics in both pelagic and turbiditic sediments. These results are not meant to disprove previous clay fabric studies but instead are intended as a warning against oversimplification of the origin and significance of clay fabrics.

  3. Oxidation of pyrite in marine clays and zinc adsorption by clays

    SciTech Connect (OSTI)

    Ohtsubo, Masami [Kyushu Univ., Fukuoka (Japan). Dept. of Agricultural Engineering

    1995-12-31T23:59:59.000Z

    The oxidation of pyrite in marine clays exposed to a subaerial environment was confirmed and was determined to be well correlated with decreased adsorption of zinc by the clays. The production of sulfuric acid and iron oxide by this oxidation and the accompanying decrease in pH was demonstrated based on an investigation of the chemistry of the marine clay profile and laboratory incubation tests for remolded clay samples. Both pH decrease and the production of iron oxides reduced the zinc adsorption capability of the clays. This suggests that the zinc adsorbed by the marine clays would be released into the pore water due to exposure of the sediment surface to the atmosphere.

  4. Clay : Pottery, Sculpture, and .... Joan Watson, Program Director

    E-Print Network [OSTI]

    Hayden, Nancy J.

    1 Clay : Pottery, Sculpture, and .... Joan Watson, Program Director OVERVIEW The Clay: Pottery, Sculpture and... Program aims to cultivate a working knowledge of clay techniques based on a study of historic and contemporary ceramics. The program will enroll students who have prior clay experience

  5. An Interpretation of Secondary Consolidation for the Batiscan Clay

    E-Print Network [OSTI]

    An Interpretation of Secondary Consolidation for the Batiscan Clay Gilberto F. Alexandre, D of the phenomena of secondary consolidation for the sensitive Batiscan clay, a Champlain sea deposit from eastern a model for natural clays which was success- fully applied to Champlain Sea clays. The model can

  6. The Swelling of Clays Within Stone Angela Wylykanowitz

    E-Print Network [OSTI]

    Petta, Jason

    The Swelling of Clays Within Stone Angela Wylykanowitz REU Program Advisor: George Scherer://www.nps.gov/azru/adhi/fig112.jpg http://www.angkorwat.org #12;Why do Clays Swell? - Clays contain negative charges balanced - Organic chain keeps the water out - Organic chain should have charged ends to bond to sheets of clay

  7. Preparation and Properties of Recycled HDPE/Clay Hybrids

    E-Print Network [OSTI]

    Preparation and Properties of Recycled HDPE/Clay Hybrids Yong Lei,1 Qinglin Wu,1 Craig M. Clemons2 on recycled high density poly- ethylene (RHDPE) and organic clay were made by melt com- pounding. The influence of blending method, compatibil- izers, and clay content on clay intercalation and exfoliation

  8. TIME DOMAIN REFLECTOMETRY MEASUREMENT AND HIGHLY PLASTIC CLAYS

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    1 TIME DOMAIN REFLECTOMETRY MEASUREMENT AND HIGHLY PLASTIC CLAYS By: J. A. Kuhn1 and J. G. Zornberg for use in highly plastic clay. The clay used for experimentation was taken locally from the Eagle Ford Ford Clay is determined. INTRODUCTION The progression of wetting and drying fronts in highly plastic

  9. 2006 Minerals Yearbook ClaY and Shale

    E-Print Network [OSTI]

    2006 Minerals Yearbook ClaY and Shale U.S. Department of the Interior U.S. Geological Survey January 2008 #12;Clay and Shale--2006 18.1 The amount of clay sold or used by domestic producers in 2006 in 2005 (table 1). Common clay and shale accounted for 59% of the tonnage, and kaolin accounted for 55

  10. 2005 Minerals Yearbook CLAY AND SHALE

    E-Print Network [OSTI]

    production was in Ohio, where the clays are mainly underclays associated with coal. Domestic production data and less slurried product were sold or used in 2005 than in 2004. Operations in Tennessee supplied 61

  11. Natural Radioactivity of Boron Added Clay Samples

    SciTech Connect (OSTI)

    Akkurt, I.; Guenoglu, K. [Sueleyman Demirel University, Faculty of Arts and Sciences, Dept. of Physics, Isparta (Turkey); Canakcii, H. [Gaziantep University, Engineering Faculty, Civil Engineering Dept., Gaziantep (Turkey); Mavi, B. [Amasya University, Faculty of Arts and Sciences, Dept. of Physics, Amasya (Turkey)

    2011-12-26T23:59:59.000Z

    Clay, consisting fine-grained minerals, is an interesting materials and can be used in a variety of different fields especially in dermatology application. Using clay such a field it is important to measure its natural radioactivity. Thus the purpose of this study is to measure {sup 226}Ra, {sup 232}Th and {sup 40}K concentration in clay samples enriched with boron. Three different types of clay samples were prepared where boron is used in different rate. The measurements have been determined using a gamma-ray spectrometry consists of a 3''x3'' NaI(Tl) detector. From the measured activity the radium equivalent activities (Ra{sub eq}), external hazard index (H{sub ex}), absorbed dose rate in air (D) and annual effective dose (AED) have also been obtained.

  12. Origin of the high sensitivity of Chinese red clay soils to drought: significance of the clay characteristics

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Origin of the high sensitivity of Chinese red clay soils to drought: significance of the clay d'Ulm 75230, Paris, France *Corresponding author: Ary.Bruand@univ-orleans.fr Abstract The red clay but the origin of this high sensitivity to drought remains unclear. Several red clay soils were selected

  13. Clay minerals in the Meuse -Haute Marne underground laboratory (France): Possible influence of organic matter on clay mineral evolution

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Clay minerals in the Meuse - Haute Marne underground laboratory (France): Possible influence of organic matter on clay mineral evolution Francis Claret1,2,* , Boris A. Sakharov3 , Victor A. Drits3 words: Callovo-Oxfordian, Clay minerals, Clay diagenesis, Illite-smectite, Mixed- layering

  14. CLAY MINERALOGY ACROSS THE P-T BOUNDARY OF THE XIAKOU SECTION, CHINA: EVIDENCE OF CLAY PROVENANCE AND ENVIRONMENT

    E-Print Network [OSTI]

    Li, Zhaohui

    CLAY MINERALOGY ACROSS THE P-T BOUNDARY OF THE XIAKOU SECTION, CHINA: EVIDENCE OF CLAY PROVENANCE, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan Abstract--The provenance of clays with an oriented arrangement of detrital clay particles, consisting mainly of illite and minor chlorite

  15. On The Thermal Consolidation Of Boom Clay

    E-Print Network [OSTI]

    Delage, Pierre; Cui, Yu-Jun

    2012-01-01T23:59:59.000Z

    When a mass of saturated clay is heated, as in the case of host soils surrounding nuclear waste disposals at great depth, the thermal expansion of the constituents generates excess pore pressures. The mass of clay is submitted to gradients of pore pressure and temperature, to hydraulic and thermal flows, and to changes in its mechanical properties. In this work, some of these aspects were experimentally studied in the case of Boom clay, so as to help predicting the response of the soil, in relation with investigations made in the Belgian underground laboratory at Mol. Results of slow heating tests with careful volume change measurements showed that a reasonable prediction of the thermal expansion of the clay-water system was obtained by using the thermal properties of free water. In spite of the density of Boom clay, no significant effect of water adsorption was observed. The thermal consolidation of Boom clay was studied through fast heating tests. A simple analysis shows that the hydraulic and thermal trans...

  16. Clay and non-clay minerals in the pharmaceutical industry Part I. Excipients and medical applications

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Clay and non-clay minerals in the pharmaceutical industry Part I. Excipients and medical form 17 July 2009 Accepted 22 July 2009 Available online 29 July 2009 Keywords: Minerals Pharmaceutical industry Excipients Medical applications Physical and physico-chemical properties Minerals are widely used

  17. Review Article Clay and non-clay minerals in the pharmaceutical and cosmetic industries

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Review Article Clay and non-clay minerals in the pharmaceutical and cosmetic industries Part II in revised form 15 October 2009 Accepted 22 October 2009 Available online 31 October 2009 Keywords: Minerals range and variety of minerals are used in the pharmaceutical industry as active ingredients

  18. Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society (June 2007)

    SciTech Connect (OSTI)

    Randall T. Cygan

    2007-06-01T23:59:59.000Z

    “Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society” was held in early June 2007 in beautiful and historic Santa Fe, New Mexico, USA. Santa Fe provided an idyllic location in the southwestern United States for the attendees to enjoy technical and social sessions while soaking up the diverse culture and wonderful climate of New Mexico—The Land of Enchantment. The meeting included a large and varied group of scientists, sharing knowledge and ideas, benefitting from technical interactions, and enjoying the wonderful historic and enchanted environs of Santa Fe. Including significant number of international scientists, the meeting was attended by approximately two hundred participants. The meeting included three days of technical sessions (oral and poster presentations), three days of field trips to clay and geological sites of northern New Mexico, and a full day workshop on the stabilization of carbon by clays. Details can be found at the meeting web site: www.sandia.gov/clay.

  19. Natural rubber-clay nanocomposites: mechanical and structural properties

    E-Print Network [OSTI]

    Camila A. Rezende; Fabio C. Bragança; Telma R. Doi; Lay-Theng Lee; Fernando Galembeck; François Boué

    2010-06-27T23:59:59.000Z

    The mechanical properties of non-vulcanized natural rubber and dialyzed natural rubber-clay nanocomposites have been studied by uniaxial deformations to evaluate the reinforcement efficiency of the clay. We show that while non-rubber molecules contribute to auto-reinforcement, removal of these molecules improves significantly the performance of clay as reinforcement agent. These mechanical properties are discussed in relation to morphological aspects of the clay characterized by TEM and SANS. The nanocomposites prepared by "latex-mixing" with aqueous dispersions of clay are found to contain completely exfoliated clay lamellae in coexistence with tactoids. Improved mechanical properties of the nanocomposites can be modeled by the high aspect ratio of exfoliated clay platelets coupled with immobilized rubber matrix. Interestingly, presence of tactoids does not appear to compromise the excellent reinforcement properties of the exfoliated platelets. At high deformations, strain-induced alignment of the clay exhibits anisotropic scattering, with anisotropy increasing with clay concentration and stretching.

  20. Estimating Undrained Strength of Clays from Direct Shear Testing at Fast Displacement Rates

    E-Print Network [OSTI]

    Bro, Andrew D; Stewart, Jonathan P; Pradel, Daniel E

    2013-01-01T23:59:59.000Z

    for stability of soft clays,” J. Geotech. Engrg. , ASCE,behavior of saturated clay,” J. Geotech. Engrg. , ASCE,Undrained Strength of Clays from Direct Shear Testing at

  1. Damage to HDPE geomembrane from interface shear over gravelly compacted clay liner

    E-Print Network [OSTI]

    Thielmann, Stuart

    2012-01-01T23:59:59.000Z

    hydraulic conductivity of compacted clay liners,” Journal offrom stones in an underlying clay layer,” Geotextiles andof three geosynthetic clay liners,” Journal of Geotechnical

  2. Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay

    E-Print Network [OSTI]

    Zheng, L.

    2010-01-01T23:59:59.000Z

    experiment in Opalinus Clay for the management ofconductivity of the Opalinus clay at a regional scale:1953. Adsorption studies on clay minerals. II. A formulation

  3. Damage to HDPE geomembrane from interface shear over gravelly compacted clay liner

    E-Print Network [OSTI]

    Thielmann, Stuart

    2012-01-01T23:59:59.000Z

    strength of three geosynthetic clay liners,” Journal ofperformance of geosynthetic clay liners under gravel coverShear Machine for Geosynthetic Clay Liners,” Geotechnical

  4. Organic or organometallic template mediated clay synthesis

    DOE Patents [OSTI]

    Gregar, K.C.; Winans, R.E.; Botto, R.E.

    1994-05-03T23:59:59.000Z

    A method is described for incorporating diverse varieties of intercalates or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and lithium fluoride for two days in the presence of an organic or organometallic intercalate or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue that are based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by U.S. Pat. No. 3,887,454 issued to Hickson, Jun. 13, 1975; however, a variety of intercalates or templates may be introduced. The intercalates or templates should have (i) water-solubility, (ii) positive charge, and (iii) thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays. 22 figures.

  5. Organic or organometallic template mediated clay synthesis

    DOE Patents [OSTI]

    Gregar, Kathleen C. (Bolingbrook, IL); Winans, Randall E. (Downers Grove, IL); Botto, Robert E. (Downers Grove, IL)

    1994-01-01T23:59:59.000Z

    A method for incorporating diverse Varieties of intercalants or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and lithium fluoride for two days in the presence of an organic or organometallic intercalant or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue that are based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by U.S. Pat. No. 3,887,454 issued to Hickson, Jun. 13, 1975; however, a variety of intercalants or templates may be introduced. The intercalants or templates should have (i) water-solubility, (ii) positive charge, and (iii) thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays.

  6. Clay Electric Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovationin UrbanCity ofCity ofInformationClaridgeClassicClay CountyClay

  7. Clay Mathematics Proceedings FRACTAL AND MULTIFRACTAL PROPERTIES OF SLE

    E-Print Network [OSTI]

    Lawler, Gregory F.

    Clay Mathematics Proceedings FRACTAL AND MULTIFRACTAL PROPERTIES OF SLE Gregory F. Lawler Introduction This is a slightly expanded version of my lectures at the 2010 Clay Mathematics Institute summer

  8. Characterization of Gulf of Mexico Clay Using Automated Triaxial Testing

    E-Print Network [OSTI]

    Murali, Madhuri

    2012-02-14T23:59:59.000Z

    . This thesis presents the results of SHANSEP triaxial testing performed on undisturbed samples of Gulf of Mexico clay. Background information is given about the clay, the sampling program and the laboratory testing program. The GEOTAC Truepath automated stress...

  9. References on Ball Clay U.S. Geological Survey

    E-Print Network [OSTI]

    : The American Ceramic Society Bulletin, v. 75, no. 6, June, p. 74-76. ------, 1992, Ball and plastic clay, Metallurgy, and Explorations, Inc., Littleton, P. 255-277. Stentiford, M.J., 1996, Ball clay-demand strong

  10. MATH 118A: INTRODUCTION TO REAL ANALYSIS ANDREW COTTON-CLAY

    E-Print Network [OSTI]

    Akhmedov, Azer

    MATH 118A: INTRODUCTION TO REAL ANALYSIS ANDREW COTTON-CLAY 1. Introduction My Name: Andrew Cotton-Clay

  11. PROPERTIES AND APPLICATIONS OF PALYGORSKITE-SEPIOLITE CLAYS

    E-Print Network [OSTI]

    Ahmad, Sajjad

    PROPERTIES AND APPLICATIONS OF PALYGORSKITE-SEPIOLITE CLAYS E. GALAN Departamento de Cristalografi, Spain (Received 20 February 1996; revised 9 May 1996) ABSTRACT: The palygorskite-sepiolite group of clay composition of the clay and its basic physical and physico-chemical parameters must be determined. Then some

  12. An Interpretation of Secondary Consolidation for the Batiscan Clay

    E-Print Network [OSTI]

    Boyer, Edmond

    An Interpretation of Secondary Consolidation for the Batiscan Clay Gilberto F. Alexandre, D of the phenomena of secondary consolidation for the sensitive Batiscan clay, a Champlain sea deposit from eastern) Leroueil et al. (1985) proposed a model for natural clays which was success- fully applied to Champlain Sea

  13. EXTENDING THE PREDICTION OF THE THERMODYNAMIC PROPERTIES OF CLAY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    EXTENDING THE PREDICTION OF THE THERMODYNAMIC PROPERTIES OF CLAY MINERALS TO THE TRAPPING OF TRACE The thermodynamic properties of clay minerals, which control the stability of these minerals in solution, are still are parameterised using a given set of minerals. For clay minerals, the latter are mainly composed by Si, Al, Fe

  14. Role of impact excavation in distributing clays over Noachian surfaces

    E-Print Network [OSTI]

    Nimmo, Francis

    Role of impact excavation in distributing clays over Noachian surfaces C. J. Barnhart1 and F. Nimmo in the ejecta as a function of distance from the crater's rim. Generally, the volume percentage of clays fraction of claypoor material because they excavate to greater depths at which clays are likely absent

  15. Virtual Clay: Haptics-based Deformable Solids of Arbitrary Topology

    E-Print Network [OSTI]

    McDonnell, Kevin

    Virtual Clay: Haptics-based Deformable Solids of Arbitrary Topology Kevin T. McDonnell and Hong Qin|qin}@cs.sunysb.edu Abstract. This paper presents Virtual Clay as a novel, interactive, dy- namic, haptics-based deformable solid of arbitrary topology. Our Virtual Clay methodology is a unique, powerful visual modeling paradigm

  16. Effect of Intermediate Principal Stress on Overconsolidated Kaolin Clay

    E-Print Network [OSTI]

    Prashant, Amit

    Effect of Intermediate Principal Stress on Overconsolidated Kaolin Clay Amit Prashant1 and Dayakar of overconsolidated kaolin clay is investigated using three-dimensional true triaxial testing on cubical specimens specimens under stress and strain-control modes. Undrained tests on kaolin clay show that the following vary

  17. Synthetic clay-magnetite aggregates designed for controlled deposition experiments

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Synthetic clay-magnetite aggregates designed for controlled deposition experiments Feinberg, J M of synthetic clay-magnetite aggregates whose physical attributes can be tailored for controlled depositional orientation or oriented aggregation. Grain size distributions of magnetite in three different clay

  18. CEMENT/CLAY INTERACTIONS A REVIEW: EXPERIMENTS, NATURALANALOGUES, AND MODELING.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 CEMENT/CLAY INTERACTIONS ­ A REVIEW: EXPERIMENTS, NATURALANALOGUES, AND MODELING. Eric C. Gaucher that will be in contact with the clay material of the engineered barriers as well as with the geological formation. France, Switzerland and Belgium are studying the option of clayey geological formations. The clay and cement media

  19. The Link between Clay Mineral Weathering and the Stabilization of

    E-Print Network [OSTI]

    Sparks, Donald L.

    The Link between Clay Mineral Weathering and the Stabilization of Ni Surface Precipitates R O B E R 19717 The formation of transition-metal surface precipitates may occur during sorption to clay minerals formation are poorly understood. We monitored changes in the reversibility of Ni sorbed to a clay mineral

  20. Clay Mathematics Proceedings Noncommutative Geometry and Number Theory

    E-Print Network [OSTI]

    Tretkoff, Paula

    Clay Mathematics Proceedings Noncommutative Geometry and Number Theory Paula B. Cohen Introduction of the Riemann Hypothesis, from which we quote several times, is given by Enrico Bombieri on the Clay Mathematics Mathematics Subject Classification 11J06, 58B34. The author acknowledges support from the Clay Foundation. c

  1. UNL Researchers Studying SDI Technology Near Clay Center

    E-Print Network [OSTI]

    Nebraska-Lincoln, University of

    UNL Researchers Studying SDI Technology Near Clay Center By Steve Ress University of Nebraska researchers have been burying plastic drip irrigation tubing in fields near Clay Center to get a better idea a previously dryland, 33-acre cornfield at UNL's South Central Agricultural Laboratory near Clay Center . Drip

  2. Clay Mathematics Proceedings Kahler-Ricci flow on complete manifolds

    E-Print Network [OSTI]

    Ni, Lei

    Clay Mathematics Proceedings K¨ahler-Ricci flow on complete manifolds Lei Ni Abstract. This is a paper based on author's lectures delivered at the 2005 Clay Mathematics Institute summer school at MSRI The 2005 Clay Mathematics Institute summer school at MSRI focused on Perel- man's work on Ricci flow

  3. A New Environmentally Friendly AL/ZR-Based Clay Stabilizer

    E-Print Network [OSTI]

    El-Monier, Ilham Abdallah

    2013-01-18T23:59:59.000Z

    Clay stabilizers are means to prevent fines migration and clay swelling, which are caused by the contact of formation with low salinity or high pH brines at high temperature. Previous clay stabilizers including: Al and Zr compounds and cationic...

  4. 1 INTRODUCTION Geosynthetic Clay Liners (GCLs) are sealing ele-

    E-Print Network [OSTI]

    Boyer, Edmond

    1 INTRODUCTION Geosynthetic Clay Liners (GCLs) are sealing ele- ments which contain bentonite: A significant number of studies have been published on the field performance of Geosynthetic Clay Liners (GCLs encapsulated between geotextile components. They have been mostly em- ployed to replace clay liners in landfill

  5. 2D and 3D high-resolution imaging to reconstruct the microstructure of clay media

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2D and 3D high-resolution imaging to reconstruct the microstructure of clay media J.C. Robinet1 & S compacted clay (illite) system, considered to be an analogy for the clay matrix constituting clay-rocks, and three different clayrocks (Callovo-Oxfordian argilites (FR), Opalinus Clay (CH), Boom Clay (BE)). Part

  6. Running heading: Water retention properties of the clay in clayey soils Water retention properties of the clay in soils developed

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Running heading: Water retention properties of the clay in clayey soils Water retention properties of the clay in soils developed on clayey sediments: Significance of parent material and soil of clayey subsoils horizons according to the variation of clay characteristics. The horizons studied

  7. Coatings and films derived from clay/wax nanocomposites

    DOE Patents [OSTI]

    Chaiko, David J.; Leyva, Argentina A.

    2006-11-14T23:59:59.000Z

    The invention provides methods for making clay/wax nanocomposites and coatings and films of same with improved chemical resistance and gas barrier properties. The invention further provides methods for making and using emulsions of such clay/wax nanocomposites. Typically, an organophillic clay is combined with a wax or wax/polymer blend such that the cohesion energy of the clay matches that of the wax or wax/polymer blend. Suitable organophilic clays include mica and phyllosilicates that have been surface-treated with edge or edge and surface modifying agents. The resulting nanocomposites have applications as industrial coatings and in protective packaging.

  8. Influence of formation clays on the flow of aqueous fluids

    SciTech Connect (OSTI)

    Hower, W.F.

    1981-01-01T23:59:59.000Z

    Most sandstone formations contain clays that can have a significant effect on the flow of aqueous fluids. The clays most frequently detected are smectite, mixed layer, illite, kaolinite, and chlorite. All of these clays are capable of migrating and causing permeability damage when they are contacted by waters foreign to the formation. Normally, these waters alter ionic environments around the clays, which causes the clays to be dislodged from their original positions. Thus, any time clay is present in the rock, it can be assumed that permeability damage can occur. The degree of damage depends upon the concentration and types of clays present, their relative position in the rock, the severity of the ionic environmental change; and fluid velocity. Permeability damage has been minimized in oil and gas wells through the use of potassium and ammonium ions. 15 references.

  9. Clay mineral reactions in clastic diagenesis

    SciTech Connect (OSTI)

    Hower, J.

    1983-03-01T23:59:59.000Z

    Studies of clastic sediments have documented the formation and transformation of clay mineral assemblages during burial diagensis. The transformation of smectite to illite in shale by its reaction with the decomposition products of detrital K-feldspar and mica results in the production of new pore water at depth. The overall reaction mobilizes all the major chemical components in the shale, most of which are consumed in the formation of the diagenetic assemblage illite/smectite + chlorite + quartz. However, part of all the components is undoubtedly transported from the shale to sandstone units and is involved in cementation, replacement, and diagenetic clay mineral formation in these reservoir rocks. In contrast to burial diagenetic reactions in shale, where the sequence is monotonic and reasonably predictable, diagenetic reactions in sandstone are frequently variable. This variability is probably attributable to the fact that sandstones are open systems in which the reactions that proceed are controlled in part by the influx of new pore water, the chemistry of which is determined by an outside source. The useful understanding role of clay minerals in hydrocarbon exploration will follow from a determination of the system shale/sandstone/organic material. We need to tie in the nature and timing of shale mineral reactions and their control on the fluid and mass transfer from shale to sandstone.

  10. Geosynthetic clay liners in alkaline environments

    SciTech Connect (OSTI)

    McKelvey, J.A. III [Roy F. Weston, Inc., West Chester, PA (United States)

    1997-11-01T23:59:59.000Z

    The use of geosynthetic clay liners (GCLs) as secondary barrier layers in environmental applications such as landfills and other impoundment facilities is becoming increasingly more popular among the engineering community, particularly at project sites where earthen materials suitable for barrier layers may not be locally available. Design engineers for these environmental applications are becoming well versed at performing equivalency calculations comparing the performance of geosynthetic materials to their earthen counterparts. For barrier layers, these equivalency calculations would normally compare the mechanical and hydraulic properties of the GCL to a compacted clay liner. Of these properties, the ability of the hydraulic properties to withstand degradation due to permeation of contained leachates is of prominent concern. Such is the case in alkaline environments. The leachate may adversely affect the GCL by minimizing swelling, decreasing adsorption capacity and increasing the permeability of the material. If the effect on the material is significant, the usefulness of this product is diminished, possibly voiding any equivalency comparison to compacted clay liner performance. The design engineer must fully understand what effect, if any, specific leachates will have on the GCL being considered. Accordingly, appropriate performance testing with the leachate in question must be performed during the design phase and confirmed during construction through quality assurance testing. This paper will present the design considerations, required laboratory testing and conformance tests for a recent project that contained an alkaline leachate. Through appropriate testing, a contaminant resistant GCL was shown to possess desired hydraulic properties in the presence of the alkaline leachate.

  11. The need to design and construct roadways on highly plastic clays is common in central and eastern Texas, where expansive clays are prevalent. Roadways constructed on highly plastic clay subgrades may be damaged

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    The need to design and construct roadways on highly plastic clays is common in central and eastern Texas, where expansive clays are prevalent. Roadways constructed on highly plastic clay subgrades may the infiltration of water into highly plastic clays under an increased gravity field in a centrifuge. Project

  12. Geohydromechanical Processes in the Excavation Damaged Zone in Crystalline Rock, Rock Salt, and Indurated and Plastic Clays

    E-Print Network [OSTI]

    Tsang, Chin-Fu; Bernier, Frederic; Davies, Christophe

    2004-01-01T23:59:59.000Z

    and pore pressure in clays. Proceedings of the Internationalcoupling effects in the Boom clay, Mol Underground ResearchElorza 2004, 2003, CILPEX: Clay Instrumentation Programme

  13. Investigations of Near-Field Thermal-Hydrologic-Mechanical-Chemical Models for Radioactive Waste Disposal in Clay/Shale Rock

    E-Print Network [OSTI]

    Liu, H.H.

    2012-01-01T23:59:59.000Z

    disturbed zone in the Opalinus Clay of the Mont Terri Rockweak mudstone (Opalinus Clay) at low stresses, InternationalHydraulic conductivity of clays in confined tests under low

  14. Investigations of Near-Field Thermal-Hydrologic-Mechanical-Chemical Models for Radioactive Waste Disposal in Clay/Shale Rock

    E-Print Network [OSTI]

    Liu, H.H.

    2012-01-01T23:59:59.000Z

    of a jurassic opalinum shale, switzerland. Clays and Clay96   1 INTRODUCTION Clay/shale has been considered asand Rupture of Heterogeneous Shale Samples by Using a Non-

  15. Clay Electric Cooperative, Inc- Energy Smart Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Rebates are available only to Clay Electric Cooperative (CEC) residential members who are making efficiency upgrades to primary residence served by CEC. Rebates are available for residential...

  16. assess clay mineralogy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Restoration Websites Summary: liner interfaces, such as at the Kettleman Hills landfill (Byrne et al. 1992; Gilbert et al. 1998143 1 INTRODUCTION Geosynthetic clay...

  17. applied clay mineralogy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Restoration Websites Summary: liner interfaces, such as at the Kettleman Hills landfill (Byrne et al. 1992; Gilbert et al. 1998143 1 INTRODUCTION Geosynthetic clay...

  18. Clay Electric Cooperative, Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, clickInformation SmyrnaNewClay Electric Cooperative, Inc Jump to:

  19. CLAY MINERALS OF THE FRONT RANGE: A FIELD GUIDE TO THE GEOLOGY, HISTORY, AND CLAY MINERALOGY OF THE CHIEFTAIN MINE,

    E-Print Network [OSTI]

    .................................................... 71 Appendix I: Clay Minerals Society field trip mileage log ............... 76 #12;FIGURES 1. Line ......................................... 21 7. Robinson Brick Company history ................................... 22 8. Diffractogram showing

  20. Role of clay minerals on the carbonate chemistry in a marine clay formation Lerouge C., Grangeon S., Mazurek M., Wille G.

    E-Print Network [OSTI]

    Boyer, Edmond

    Role of clay minerals on the carbonate chemistry in a marine clay formation Lerouge C., Grangeon S., Mazurek M., Wille G. Samples from different levels of the Opalinus clay formation at Benken were studied. At the scale of the formation, the trace element content in calcite is anticorrelated with clay content

  1. The Don-Kay-Clay Cash Foundation The Don-Kay-Clay Cash Foundation was established in 1997 to provide general and operating

    E-Print Network [OSTI]

    Rock, Chris

    The Don-Kay-Clay Cash Foundation The Don-Kay-Clay Cash Foundation was established in 1997 services. It was set up by Don and Kay Cash and their son, Clay, all graduates of Texas Tech University and is now a retired English teacher. Kay is the Secretary-Treasurer of the family foundation. Clay earned

  2. The washability of lignites for clay removal

    SciTech Connect (OSTI)

    Oteyaka, B.; Yamik, A.; Ucar, A.; Sahbaz, O.; Demir, U. [Dumlupinar University, Kutahya (Turkey). Dept. of Mining Engineering

    2008-07-01T23:59:59.000Z

    In the washability research of the Seyitomer Lignites (Kutahya-Turkey), with lower calorific value (1,863 kcal/kg) and high ash content (51.91%), by heavy medium separation, it was found out that middling clay in the coal had an effect to change the medium density. To prevent this problem, a trommel sieve with 18 and 5 mm aperture diameter was designed, and the clay in the coal was tried to be removed using it before the coal was released to heavy medium. Following that, the obtained coal in -100 + 18 mm and -18 + 5 mm fractions was subjected to sink and float test having 1.4 gcm{sup -3} and 1.7 gcm{sup -3} medium densities (-5 mm fraction will be evaluated in a separate work). Depending on the raw coal, with the floating of -100 + 18 mm and -18 + 5 mm size fraction in 1.4 gcm{sup -3} medium density, clean coal with 60.10% combustible matter recovery, 19.12% ash, and 3,150 kcal/kg was obtained. Also floating of the samples sinking in 1.4 gcm{sup -3} in the medium density (1.7 gcm{sup -3}), middling with 18.70% combustible matter recovery, 41.93% ash, 2,150 kcal/kg, and tailing having 78.31% ash were obtained.

  3. Gasohol - Boon or Boondoggle?

    E-Print Network [OSTI]

    Hyland, M. J.

    1981-01-01T23:59:59.000Z

    Producing alcohol from agricultural products is a very controversial topic in the U.S. today. This paper presents information on the overall energy balance and clears up the recent controversy on the actual efficiency to be expected in these plants...

  4. BooNE Collaboration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewind Generator|December 5, 2011

  5. BooNE Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewind Generator|December 5, 2011Experiment

  6. BooNE: Posters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewindParticle Identification (PID)

  7. Specificity and randomness in the visual cortex Kenichi Ohki and R Clay Reid

    E-Print Network [OSTI]

    Born, Richard

    Specificity and randomness in the visual cortex Kenichi Ohki and R Clay Reid Research 02115, USA Corresponding author: Reid, R Clay (clay_reid@hms.harvard.edu) Current Opinion

  8. Uncertainty in the reactive transport model response to an alkaline perturbation in a clay formation

    E-Print Network [OSTI]

    Burnol, A.; Blanc, P.; Xu, T.; Spycher, N.; Gaucher, E.C.

    2006-01-01T23:59:59.000Z

    degradation of a concrete/clay interface, in Migration'05 -an alkaline plume in a clay barrier, Applied Geochemistry,AN ALKALINE PERTURBATION IN A CLAY FORMATION A. Burnol*, P.

  9. Clay County Extension Center 2463 State Road 16 West~ Green Cove Springs

    E-Print Network [OSTI]

    Florida, University of

    Clay County Extension Center 2463 State Road 16 West~ Green Cove Springs next to the Clay CountyPurchases support your community...your community... The Master Gardeners of UF/IFAS Extension Clay County work

  10. Clay mineralogy and its effect on physical properties in the Gulf of Mexico northwestern continental slope

    E-Print Network [OSTI]

    Berti, Debora

    2005-02-17T23:59:59.000Z

    The clay mineral composition of sediments deposited in the last six oxygen isotope stages in the Gulf of Mexico continental slope was characterized. Smectite and illite were found to be the two major clay minerals of the clay fraction while...

  11. ... FIELD TRIP GUIDEBOOK ON ENVIRONMENTAL IMPACT OF CLAYS

    E-Print Network [OSTI]

    Rathbun, Julie A.

    ... FIELD TRIP GUIDEBOOK ON ENVIRONMENTAL IMPACT OF CLAYS ALONG THE UPPER TEXAS COAST NI Lyndon B. Johnson Space Center Houston, Texas &II LPI #12;FIELD TRIP GUIDEBOOK ON ENVIRONMENTAL IMPACT.....................................................................................................................................vi Introduction: Environmental Impact of Clays Along the Upper Texas Coast

  12. Modeling of strain rate effects on clay in simple shear

    E-Print Network [OSTI]

    Jung, Byoung Chan

    2006-08-16T23:59:59.000Z

    of strain rate on clays in simple shear conditions. The response of clay soils is highly dependent on the rate of strain for both effective stress path and stress-strain behavior. The undrained shear strength is strongly influenced by strain rate both...

  13. Testing of Expansive Clays in a Centrifuge Permeameter

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    Testing of Expansive Clays in a Centrifuge Permeameter M. D. Plaisted & J. G. Zornberg with the objective of characterizing the swelling of highly plastic clays using a centrifuge permeameter. The new. This study, conducted using a comparatively simple, non- instrumented centrifuge device complements ongo- ing

  14. Water in clay-water systems (1) Philip F. LOW

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Water in clay-water systems (1) Philip F. LOW Department of Agronomy, Purdue University. Agric. Exp. Stn., West Lafayette, IN 47907, U.S.A. SUMMARY The swelling of clay-water systems and the thermodynamic, hydrodynamic and spectroscopic properties of water in these systems are discussed. The swelling

  15. Fire Clay coal and sandstone washouts

    SciTech Connect (OSTI)

    Andrews, W.M. Jr.; Hower, J.C. (Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research)

    1992-01-01T23:59:59.000Z

    The Fire Clay coal bed has been studied in a portion of southeastern Kentucky. This seam is easily recognizable by a distinctive flint clay parting. Mine maps, field descriptions, and laboratory investigations were used to investigate this coal bed. Several elongate sandstone bodies cut the seam in the study area. These sandstone bodies are subparallel roughly east-west, and are typically 10[sup 1] to 10[sup 2] m wide, and 10[sup 2] m to tens of kilometers long. These sandstone washouts occur in areas overlain by a larger channel sandstone, which usually is found associated with the thickest areas of the coal seam. In south-central Perry County, a cross section of one washout area was well exposed. North of the washout, a 4 to 7 cm thick cannel coal was present at the base of the sequence. The coal on the north side of the cutout gradually thins from 2 m to 1.5 m away from the washout. On the south side of the washout, the coal thins abruptly from over 1.5 m to 1.25 m within 30 m of the channel. An island of slumped and slickensided coal is present within the washout region. Postdepositional differential compaction of the peat is inferred to be the control on placement of the channel system. The areas of thickest peat compacted the most, creating topographic lows through which the stream moved. The regions of thick coal were probably the result of several controlling factors. Predepositional differential compaction and erosion may have produced relief which influenced peat development. Lithologic and geochemical continuity across the channel is good, supporting postdepositional emplacement of the sandstone bodies.

  16. Semi-permeable vesicles composed of natural clay

    E-Print Network [OSTI]

    Anand B. Subramaniam; Jiandi Wan; Arvind Gopinath; Howard A. Stone

    2010-11-22T23:59:59.000Z

    We report a simple route to form robust, inorganic, semi-permeable compartments composed of montmorillonite, a natural plate-like clay mineral that occurs widely in the environment. Mechanical forces due to shear in a narrow gap assemble clay nanoplates from an aqueous suspension onto air bubbles. Translucent vesicles suspended in a single-phase liquid are produced when the clay-covered air bubbles are exposed to a variety of water-miscible organic liquids. These vesicles of clay are mechanically robust and are stable in water and other liquids. The formation of clay vesicles can be described by a physical mechanism that recognizes changes in the wetting characteristics of clay-covered air bubbles in organic liquids. The clay vesicles are covered with small pores and so intrinsically exhibit size-selective permeability, which allows spontaneous compartmentalization of self-assembling molecules in aqueous environments. The results we report here expand our understanding of potential paths to micro-compartmentalization in natural settings and are of relevance to theories of colloidal aggregation, mineral cycles, and the origins of life.

  17. Potassium Fixation and Supply by Soils with Mixed Clay Minerals.

    E-Print Network [OSTI]

    Hipp, Billy W.

    1969-01-01T23:59:59.000Z

    B-1090 December 1969 1 potassium Fixation and Supply By Soils With Misd Clay Minerals I KUS A&M UNIVERSITY Tcrv Agricultural Experiment Station r i 0. Kunkel, Acting Director, College Station, Texas Summary to the plants while Cameron clay... of the soils n-j Laredo si 1 supplied 3.29 me K/me of exchangeable K increased by the addition of K fertilizer after nme ;- Yotassium Pixation and 3upgly By Soils Witb Mixed Clay Ad111t1;: Bill] " ' " HE POTASSIUM STATUS OF SOILS of the Midwest, North...

  18. Geophysical investigation of a large landslide in glaciolacustrine clays in the Trives area (French Alps)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Geophysical investigation of a large landslide in glaciolacustrine clays in the Trièves area Lyon, LRPC Autun, BP 141, 71404 Autun cedex, France Abstract Slope movements in clay deposits are world differentiating the body to be mapped. For landslides affecting thick clay materials (from soft clay to shale

  19. A variational Cam-clay theory of plasticity M. Ortiz a,*, A. Pandolfi b

    E-Print Network [OSTI]

    Ortiz, Michael

    A variational Cam-clay theory of plasticity M. Ortiz a,*, A. Pandolfi b a Graduate Aeronautical of the so-called Cam-clay theories. As typical of Cam-clay models, soil is assumed to be frictional of the visco-plastic constitutive updates. Ó 2004 Elsevier B.V. All rights reserved. Keywords: Variational Cam-clay

  20. Jurassic and Cretaceous clays of the northern and central North Sea

    E-Print Network [OSTI]

    Haszeldine, Stuart

    Jurassic and Cretaceous clays of the northern and central North Sea hydrocarbon reservoirs reviewedQF, UK AB ST R ACT : The principal clays of the northern and central North Sea are illite (sometimes interpreted as both infiltrated clastic clay, and as an early diagenetic phase. Early clays may have been

  1. INTERACTION BETWEEN PRESSURE SOLUTION AND CLAYS IN STYLOLITE DEVELOPMENT: INSIGHTS FROM MODELING

    E-Print Network [OSTI]

    Einat, Aharonov

    INTERACTION BETWEEN PRESSURE SOLUTION AND CLAYS IN STYLOLITE DEVELOPMENT: INSIGHTS FROM MODELING are strongly correlated both with the surrounding stress and with the distribution of clays within the host-solution with and without the presence of clays, where clays play a role of enhancing pressure solution. We use our model

  2. The Effect of Physico-Chemical Factors on the Stability and Transport of Clay Particles 

    E-Print Network [OSTI]

    Musharova, Darya

    2012-07-16T23:59:59.000Z

    Fixation in Clays ....................................................................... 42 5.3.1 Kaolin-NH4Cl System ................................................................. 43 5.3.2 Zirconium Lactate Clay Stabilizer... ......................................................................................... 84 6.7.3.1 Core effluent analysis ...................................................... 88 6.8 Effect of Zirconium Lactate Clay Stabilizer on Clay Dispersion ........ 90 6.7.4 Summary...

  3. Relationship between the physical and mineralogical properties of two clays and their bloating characteristics

    E-Print Network [OSTI]

    Abbott, Ute Agnes

    1973-01-01T23:59:59.000Z

    . Water Absorbtion of Clay at 22aC and 100 Percent Relative Humidity 3. Chemical Analysis Using Emission Spectrograph 4. Magnetic Properties of Clays and Aggregates 5. Carbon Analysis 6. Compositions of the Mixed Red Clay Samples 11 13 23 28... capacity of some clays. Successful attempts have 3 been made with lignin sulfite liquor and diesel fuel. ((hen the clay structure is destroyed, 11 large amounts of (OH) are released to react with the exchange ions in the clay. Therefore, the clay...

  4. Limits of isotropic plastic deformation of Bangkok clay

    E-Print Network [OSTI]

    P. Evesque

    2005-07-08T23:59:59.000Z

    A model assuming incremental plastic isotropic response has been recently proposed to model the deformation of isotropic packing of grains, in the small-strain range. It is used here on over-consolidated remould clay, to interpret the small-strain range behaviour obtained in [1,2] on Bangkok clay. The data published in [1,2] at constant volume are also used here to measure the size of the domain of validity in the (q/(M'p), p/po) plane, where po is the over-consolidation isotropic pressure, p is the mean stress and q the deviatoric stress, q . So, it is shown that the model works also for clay. This enlarges the application domain of model [3,4] to soft clay with OCR larger than 1.2 to 1.5. Pacs # : 45.70.-n ; 62.20.Fe ; 83.80.Fg, 83.80.Hj

  5. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    SciTech Connect (OSTI)

    Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange; Sonnenthal, Eric; Houseworth, Jim; Birkholzer, Jens

    2010-08-31T23:59:59.000Z

    As a result of the termination of the Yucca Mountain Project, the United States Department of Energy (DOE) has started to explore various alternative avenues for the disposition of used nuclear fuel and nuclear waste. The overall scope of the investigation includes temporary storage, transportation issues, permanent disposal, various nuclear fuel types, processing alternatives, and resulting waste streams. Although geologic disposal is not the only alternative, it is still the leading candidate for permanent disposal. The realm of geologic disposal also offers a range of geologic environments that may be considered, among those clay shale formations. Figure 1-1 presents the distribution of clay/shale formations within the USA. Clay rock/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at Mol site, Belgium (Barnichon et al., 2005) have all been under intensive scientific investigations (at both field and laboratory scales) for understanding a variety of rock properties and their relations with flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated and plastic clays (Tsang et al., 2005). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. For both clay rocks, coupled thermal, hydrological, mechanical and chemical (THMC) processes are expected to have a significant impact on the long-term safety of a clay repository. For example, the excavation-damaged zone (EDZ) near repository tunnels can modify local permeability (resulting from induced fractures), potentially leading to less confinement capability (Tsang et al., 2005). Because of clay's swelling and shrinkage behavior (depending on whether the clay is in imbibition or drainage processes), fracture properties in the EDZ are quite dynamic and evolve over time as hydromechanical conditions change. To understand and model the coupled processes and their impact on repository performance is critical for the defensible performance assessment of a clay repository. Within the Natural Barrier System (NBS) group of the Used Fuel Disposition (UFD) Campaign at DOE's Office of Nuclear Energy, LBNL's research activities have focused on understanding and modeling such coupled processes. LBNL provided a report in this April on literature survey of studies on coupled processes in clay repositories and identification of technical issues and knowledge gaps (Tsang et al., 2010). This report will document other LBNL research activities within the natural system work package, including the development of constitutive relationships for elastic deformation of clay rock (Section 2), a THM modeling study (Section 3) and a THC modeling study (Section 4). The purpose of the THM and THC modeling studies is to demonstrate the current modeling capabilities in dealing with coupled processes in a potential clay repository. In Section 5, we discuss potential future R&D work based on the identified knowledge gaps. The linkage between these activities and related FEPs is presented in Section 6.

  6. Platte-Clay Electric Cooperative- Residential Energy Efficiency Rebates

    Broader source: Energy.gov [DOE]

    Platte-Clay Electric Cooperative offers a variety of rebates to residential and commercial customers who wish to upgrade to energy efficient equipment. Newly installed ground source heat pumps are...

  7. Immersion freezing of clay minerals and bacterial ice nuclei

    E-Print Network [OSTI]

    Hiranuma, Naruki

    2013-01-01T23:59:59.000Z

    The immersion mode ice nucleation efficiency of clay minerals and biological aerosols has been investigated using the AIDA (Aerosol Interaction and Dynamics in the Atmosphere) cloud chamber. Both monodisperse and polydisperse ...

  8. The mechanical behavior of heavily overconsolidated resedimented Boston Blue Clay

    E-Print Network [OSTI]

    Vargas Bustamante, Albalyra Geraldine

    2013-01-01T23:59:59.000Z

    Geotechnical engineers encounter some of the most challenging problems in heavily overconsolidated soils. Clays under this condition originated in nature or man-made construction. This thesis investigates the mechanical ...

  9. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    E-Print Network [OSTI]

    Liu, Hui-Hai

    2010-01-01T23:59:59.000Z

    2010). 4. Impact of rock-property heterogeneity as well asa variety of rock properties and their relations with flowwill use clay host rock properties derived from the Opalinus

  10. Analysis of consolidation around driven piles in overconsolidated clay

    E-Print Network [OSTI]

    Niarchos, Dimitrios G

    2012-01-01T23:59:59.000Z

    The principal objective of this thesis is to assess the capabilities of an already established analytical framework for understanding and predicting the behavior of piles driven in highly overconsolidated clays (OCR24). ...

  11. Influence of loading rate on axially loaded piles in clay

    E-Print Network [OSTI]

    Garland Ponce, Enrique Eduardo

    1984-01-01T23:59:59.000Z

    International Conference on Soil Mechanics and Founda- tion Engineerinq, London, V. l, pp. 207-210 Bjerrum, L. Simons, N. Torblaa, I. (1958) Crawford, C. B. (1959) The Effect of Time on the Shear Strength of a Soft Marine Clay The Influence of Rate... of Strain on Effective Stresses in Sensitive Clay Norweqian Geotechnical Institute, Publication No. 33, pp. 135-142. American Society of Testing Materials (Special Technical Publication No. 361), pp. 36-61. Richardson, A. M. Whitman, R. V. (1963...

  12. Synergistic effects of sulfosuccinate/polymer system for clay stabilization

    SciTech Connect (OSTI)

    Alonso-DeBolt, M.; Jarrett, M. [Baker Hughes INTEQ, Houston, TX (United States)

    1995-12-31T23:59:59.000Z

    A unique polymer system has been developed for on-land drilling applications. This system reduces clay swelling and dispersion by using water-soluble polymers in conjunction with sulfosuccinate derivative-based surfactants. Synergistic benefits with these polymers and surfactants are demonstrated. Reducing or eliminating the hydrophilic nature of clay surfaces by charge neutralization enhances borehole stability and drilling fluid performance. This polymer system is non-toxic and biodegradable.

  13. Shear strength of reinforced geosynthetic clay liner

    SciTech Connect (OSTI)

    Gilbert, R.B. [Univ. of Texas, Austin, TX (United States)] [Univ. of Texas, Austin, TX (United States); Fernandez, F. [Golder Associates, Inc., Naperville, IL (United States)] [Golder Associates, Inc., Naperville, IL (United States); Horsfield, D.W. [Golder Associates, Ltd., Calgary, Alberta (Canada)] [Golder Associates, Ltd., Calgary, Alberta (Canada)

    1996-04-01T23:59:59.000Z

    Direct shear tests are conducted to evaluate the internal strength of a reinforced geosynthetic clay liner (GCL) at normal stresses between 3.45 and 69.0 kPa. The polypropylene reinforcement increases the peak internal strength compared to that reported in the literature for unreinforced GCLs; however, the reinforced GCL exhibits a postpeak reduction in strength with displacement due to failure of the reinforcement. Direct shear tests are also conducted to evaluate the interface strength between the reinforced GCL and other geosynthetic materials. Extrusion of bentonite from the GCL into the interfaces is noticed and may reduce the interface strengths. Peak interface strengths between the GCL and a smooth geomembrane or a drainage geocomposite are less than the internal strength at all normal stresses tested. However, the peak interface strength between the GCL and a textured geomembrane is limited by the peak internal strength for normal stresses exceeding 13.8 kPa. Postpeak reductions in strength with displacement occur for this interface at these higher normal stresses due to reinforcement failure.

  14. Carboxylic acid sorption on synthetic clays in marine water: in vitro experiments and implications for organo-clay behaviour under marine conditions

    E-Print Network [OSTI]

    1 Carboxylic acid sorption on synthetic clays in marine water: in vitro experiments and implications for organo-clay behaviour under marine conditions Sylvain Drouin a , Mohammed Boussafir a* , Jean to investigate the role of clay minerals in organic matter preservation, the fixation of pure organic compounds

  15. Hollow clay tile wall program summary report

    SciTech Connect (OSTI)

    Henderson, R.C.; Jones, W.D. [Gilbert/Commonwealth, Inc., Oak Ridge, TN (United States); Beavers, J.E. [MS Technology, Inc. (United States)

    1995-07-30T23:59:59.000Z

    Many of the Y-12 Plant buildings, constructed during the 1940s and 1950s, consist of steel ed concrete framing infilled with hollow clay tile (HCT). The infill was intended to provide for building enclosure and was not designed to have vertical or lateral load-carrying capacity. During the late 1970s and early 1980s, seismic and wind evaluations were performed on many of these buildings in conjunction with the preparation of a site-wide safety analysis report. This analytical work, based on the best available methodology, considered lateral load-carrying capacity of the HCT infill on the basis of building code allowable shear values. In parallel with the analysis effort, DOE initiated a program to develop natural phenomena capacity and performance criteria for existing buildings, but these criteria did not specify guidelines for determining the lateral force capacity of frames infilled with HCT. The evaluation of infills was, therefore, based on the provisions for the design of unreinforced masonry as outlined in standard masonry codes. When the results of the seismic and wind evaluations were compared with the new criteria, the projected building capacities fell short of the requirements. Apparently, if the buildings were to meet the new criteria, many millions of dollars would be required for building upgrades. Because the upgrade costs were significant, the assumptions and approaches used in the analyses were reevaluated. Four issues were identified: (1) Once the infilled walls cracked, what capacity (nonlinear response), if any, would the walls have to resist earthquake or wind loads applied in the plane of the infill (in-plane)? (2) Would the infilled walls remain within the steel or reinforced concrete framing when subjected to earthquake or high wind loads applied perpendicular to the infill (out-of-plane)? (3) What was the actual shear capacity of the HCT infill? (4) Was modeling the HCT infill as a shear wall the best approach?

  16. Cyclic threshold strains in clays versus sands and the change of secant shear modulus and pore water pressure at small cyclic strains

    E-Print Network [OSTI]

    Mortezaie, Ahmad Reza -

    2012-01-01T23:59:59.000Z

    Tests on Drammen Clay,” Journal of the Geotechnical Eng.on Settlement of Saturated Clay Layer Induced by CyclicProperties and Response of Soft Clay Deposits," Proceedings

  17. Geosynthetic Clay Liner applications in waste disposal facilities

    SciTech Connect (OSTI)

    McGrath, L.T.; Creamer, P.D. [RMT, Inc., Madison, WI (United States)

    1995-12-31T23:59:59.000Z

    Geosynthetic Clay Liners (GCLs) are becoming a popular alternative to compacted clay barrier layers, and represent the state of the art in waste disposal facility design. They possess many of the same qualities of compacted clay barrier layers while occupying only a small fraction of the airspace. This is a very attractive feature to waste disposal facility owners and operators. There are many manufacturers of GCLs in the marketplace, providing numerous products that can be used in a wide variety of applications. Designing for the constructing with a GCL an be a challenging task; stability issues must be evaluated, selecting the appropriate product should be considered, comprehensive specifications are needed to ensure proper product selection and installation, and steps must be taken during installation to prevent damage to the GCL. Perhaps most importantly, state regulatory agencies must be convinced that GCLs will provide long-term protection equivalent to a clay barrier layer. This paper will discuss design considerations, specification guidelines, installation criteria, construction quality assurance guidelines and regulatory issues pertaining to GCL. The paper will also present three brief case histories of relevant GCL applications in waste disposal facility design and construction. The purpose of the paper is to demonstrate that GCLs are a viable alternative to compacted clay barrier layers and to provide useful information in designing, specifying and installing them in waste disposal facilities.

  18. By Robert L. Virta The amount of clay sold or used by domestic facilities for producing bentonite liners in

    E-Print Network [OSTI]

    are mainly underclays associated with coal and suitable for refractory uses. Ball Clay.--The ball clay. Production increased in all States except Kentucky. Water-slurried ball clay was produced in Kentucky

  19. Normalized sensitivities and parameter identifiability of in situ diffusion experiments on Callovo-Oxfordian clay at Bure site

    E-Print Network [OSTI]

    Samper, J.

    2010-01-01T23:59:59.000Z

    and Laboratory Data. Appl. Clay Sci. 26, 123-135. Yllera,in situ diffusion experiment in the Opalinus clay formation.Appl. Clay Sci. 26, 181-196. Figure 1. Sketch of borehole

  20. Investigation of two-phase flow phenomena associated with corrosion in an SF/HLW repository in Opalinus Clay, Switzerland

    E-Print Network [OSTI]

    Senger, R.

    2010-01-01T23:59:59.000Z

    on storage barriers. Applied Clay Science 26, 511–520.properties of the Opalinus Clay, a potential host rock1.EÀ4 c Bentonite Opalinus Clay a Container represented by a

  1. Efficiency of clay-TiO2 nanocomposites on the photocatalytic elimination of a model hydrophobic air pollutant

    E-Print Network [OSTI]

    Kibanova, Daria

    2010-01-01T23:59:59.000Z

    Paris - Chemistry 2000, 3, 405-411. Clay-TiO 2 nanocompositenanocomposites Appl. Clay Sci. 2006, (28) Ooka, C. ;of TiO 2 -pillared clay on adsorption and photocatalysis of

  2. Stable isotope geochemistry of sulfur bearing minerals and clay mineralogy of some soils and sediments in Loot Desert, central Iran

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Stable isotope geochemistry of sulfur bearing minerals and clay mineralogy of some soils Keywords: Sulfur geochemistry Gypsum crystallization water Clay mineralogy Palygorskite Iranian soils Loot technique and clay mineralogy were studied in different landforms in Loot Desert, central Iran. Four

  3. Demonstration of artificial visual percepts generated through thalamic microstimulation John S. Pezaris, and R. Clay Reid

    E-Print Network [OSTI]

    Reid, R. Clay

    . Pezaris, and R. Clay Reid doi:10.1073/pnas.0608563104 published online Apr 23, 2007;PNAS This information microstimulation John S. Pezaris* and R. Clay Reid Department of Neurobiology, Harvard Medical School, 220 Longwood

  4. Evaluation of Alpha-Phased Zirconium Phosphate Nanoparticles as a Clay Stabilizer and an EOR Agent 

    E-Print Network [OSTI]

    Zhou, Yi

    2014-12-15T23:59:59.000Z

    fines migration in sandstone formations and recovery more oil in carbonate. To test the ability of ?-ZrP nanofluids as a clay stabilizer, coreflood tests were conducted using alpha phased zirconium phosphate based nanofluids as a clay stabilizer...

  5. Hydraulic Interaction between Geosynthetic Drainage Layers and Unsaturated Low Plasticity Clay

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    1 Hydraulic Interaction between Geosynthetic Drainage Layers and Unsaturated Low Plasticity Clay of soil density on the hydraulic interaction between unsaturated, low plasticity clay and geosynthetic drainage layers. The hydraulic interaction was evaluated using the system hydraulic conductivity, moisture

  6. H2O and Cation Structure and Dynamics in Expandable Clays: 2H...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H2O and Cation Structure and Dynamics in Expandable Clays: 2H and 39K NMR Investigations of Hectorite. H2O and Cation Structure and Dynamics in Expandable Clays: 2H and 39K NMR...

  7. RIETVELD REFINEMENT OF REAL STRUCTURE PARAMETERS OF DISORDERED CLAY MINERALS IN

    E-Print Network [OSTI]

    Magee, Joseph W.

    -conventional hydrocarbons in Germany) Germany's potential for shale oil and shale gas NIKO seal gas-rich shale shale: sedimentary rock which contains quartz, carbonates and clay minerals #12;clay minerals in shales quartz

  8. Investigations of Near-Field Thermal-Hydrologic-Mechanical-Chemical Models for Radioactive Waste Disposal in Clay/Shale Rock

    E-Print Network [OSTI]

    Liu, H.H.

    2012-01-01T23:59:59.000Z

    illitization in burial diagenesis environments. Geochimicausually part of the diagenesis process of clay formation (is usually part of the diagenesis process of clay formation.

  9. EXPERIMENTAL ANALYSIS OF YIELDING AND STRAIN LOCALIZATION OF MODERATELY OVERCONSOLIDATED KAOLIN CLAY

    E-Print Network [OSTI]

    Prashant, Amit

    CLAY Amit Prashant1 (Member, ASCE) and Dayakar Penumadu2 (Member, ASCE) ABSTRACT Elasto-plasticity theory has been commonly used to model the mechanical behavior of clays. Yielding and normalized failure materials. For isotropically overconsolidated clays, the stress state will be inside the elastic zone

  10. Clay mineral variations in Holocene terrestrial sediments from the Indus Basin Anwar Alizai a,

    E-Print Network [OSTI]

    Clift, Peter

    Clay mineral variations in Holocene terrestrial sediments from the Indus Basin Anwar Alizai a 23 February 2012 Keywords: XRD Clay mineralogy Monsoon Himalaya Indus Delta Floodplain Fluvial processes Large rivers We employed X-ray diffraction methods to quantify clay mineral assemblages

  11. A Simple Method To Improve the Clarity and Rheological Properties of Polymer/Clay

    E-Print Network [OSTI]

    Raghavan, Srinivasa

    A Simple Method To Improve the Clarity and Rheological Properties of Polymer/Clay Nanocomposites by Using Fractionated Clay Particles Bani H. Cipriano,, Takashi Kashiwagi,§ Xin Zhang,| and Srinivasa R prepared using organophilic derivatives of commercial montmorillonite (MMT) clays that contain a wide range

  12. Distribution of Clay Minerals in Lower Cook Inlet and Kodiak Shelf Sediment, Alaska

    E-Print Network [OSTI]

    Distribution of Clay Minerals in Lower Cook Inlet and Kodiak Shelf Sediment, Alaska James R. llein-five surface samples from lower Cook Inlet and forty-three from Kodiak shelf, Alaska, were analyzed for clay percentages of clay minerals. This is because modern ocean currents vigorously rework surficial sediment

  13. Modelling the thermo-mechanical volume change behaviour of compacted expansive clays

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Modelling the thermo-mechanical volume change behaviour of compacted expansive clays Anh-Minh Tang expansive clays are often considered as a possible buffer material in high-level deep radioactive waste disposals. After the installation of waste canisters, the engineered clay barriers are subjected to thermo

  14. Application of a simple viscous model to the cyclic behavior of clays at small strains

    E-Print Network [OSTI]

    Application of a simple viscous model to the cyclic behavior of clays at small strains Gilberto F development of the cyclic behavior of clays at small strains using the model proposed by Martins (1992 tests carried out by Mortezaie (2012) in a fabricated clay. It is shown that satisfactory predictions

  15. Clay minerals and their beneficial effects upon human health. M. Isabel Carretero*

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Clay minerals and their beneficial effects upon human health. A review M. Isabel Carretero* Dpto examines the beneficial effects for human health of clay minerals, describing their use in pharmaceutical process and in its possible degradation effect. Among their uses in spas, clay minerals therapeutic

  16. Polystyrene/Clay Nanocomposites by Atom Transfer Radical Nitroxide Coupling Chemistryy

    E-Print Network [OSTI]

    Turro, Nicholas J.

    Polystyrene/Clay Nanocomposites by Atom Transfer Radical Nitroxide Coupling Chemistryy Muhammed of well- dispersed clay layers such as montmorillonite (MMT) into a polymer matrix has been proved However, the dispersion of clay as indi- vidual platelets throughout the polymer is difficult to achieve

  17. PROBLEMS IN DYNAMICAL SYSTEMS AND RELATED TOPICS RAISED IN CONNECTION WITH THE CLAY

    E-Print Network [OSTI]

    Katok, Svetlana

    PROBLEMS IN DYNAMICAL SYSTEMS AND RELATED TOPICS RAISED IN CONNECTION WITH THE CLAY MATHEMATICS References 45 1. INTRODUCTION At the Clay Mathematics Institute/Mathematical Sciences Research In- stitute these contributions. Thanks are due, therefore, to the Clay Mathematics Insti- tute and the the Mathematical Sciences

  18. Size dependence of microprobe dynamics during gelation of a discotic colloidal clay

    E-Print Network [OSTI]

    Size dependence of microprobe dynamics during gelation of a discotic colloidal clay Jason P. Rich. This phenomenon has recently been demonstrated for a gel-forming aqueous dispersion of Laponite® clay Oppong et al spherical and uncharged, anisotropic charged particles like discotic colloidal clays are common in nature

  19. Andrew Cotton-Clay Massachusetts Institute of Technology E-mail: acotton@math.berkeley.edu

    E-Print Network [OSTI]

    Cotton-Clay, Andrew

    Andrew Cotton-Clay Massachusetts Institute of Technology E-mail: acotton: Gromov's Nonsqueezing Theorem · Advisor: Peter Kronheimer Publications · A. Cotton-Clay. A sharp bound on fixed points of area-preserving surface diffeo- morphisms. In preparation. · A. Cotton-Clay. Symplectic

  20. THE LINK BETWEEN CLAY MINERAL WEATHERING AND THE FORMATION OF NI SURFACE PRECIPITATES

    E-Print Network [OSTI]

    Sparks, Donald L.

    THE LINK BETWEEN CLAY MINERAL WEATHERING AND THE FORMATION OF NI SURFACE PRECIPITATES Andreas C, Schlieren, Switzerland Spectroscopic and microscopic studies have shown that Ni and Co sorption by clay:1 or 2:1 phyllosilicates requires the release ofA1 and Si from clay minerals. Due to similar metal

  1. Compression Behaviour of Natural and Reconstituted Clays Zhen-Shun Hong1

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Compression Behaviour of Natural and Reconstituted Clays Zhen-Shun Hong1 , Ling-Ling Zeng2 , Yu the effect of the starting point on the compressibility of natural and reconstituted clays. It is found of reconstituted clays is controlled solely by the water content at the remoulded yield stress and the liquid limit

  2. Experimental Analysis of Yielding and Strain Localization of Moderately Overconsolidated Kaolin Clay

    E-Print Network [OSTI]

    Prashant, Amit

    Clay Amit Prashant and Dayakar Penumadu 17th ASCE Engineering Mechanics Conference, June 2004. Abstract Elasto-plasticity theory has been commonly used to model the mechanical behavior of clays. Yielding for frictional materials. For isotropically overconsolidated clays, the stress state will be inside the elastic

  3. Detection and cultivation of indigenous microorganisms in Mesozoic claystone core samples from the Opalinus Clay Formation

    E-Print Network [OSTI]

    Gilli, Adrian

    the Opalinus Clay Formation (Mont Terri Rock Laboratory) L. Mauclaire a,*, J.A. McKenzie a , B. Schwyn b , P various deep-subsurface environments, the persistence of microbial activity in clay- stones buried life in the Opalinus Clay Formation (Mesozoic claystone, 170 million years old) at the Mont Terri Rock

  4. Fe-CYCLE BACTERIA FROM INDUSTRIAL CLAYS MINED IN GEORGIA, USA EVGENYA S. SHELOBOLINA

    E-Print Network [OSTI]

    Lovley, Derek

    Fe-CYCLE BACTERIA FROM INDUSTRIAL CLAYS MINED IN GEORGIA, USA EVGENYA S. SHELOBOLINA 1, *,{, SAM M are major discoloring impurities in mined commercial white kaolin clay. In order to evaluate the potential influence of Fe-cycle bacteria on Fe cycling during post- depositional clay-weathering alteration, Fe

  5. Differences in potassium forms between cutans and adjacent soil matrix in a Grey Clay Soil

    E-Print Network [OSTI]

    Boyer, Edmond

    Differences in potassium forms between cutans and adjacent soil matrix in a Grey Clay Soil Fan Liu1 of cutans on potassium forms and their transformations were investigated for a Western Australian grey clay soil. Cutans and matrix soil had similar clay mineral associations with kaolinite, smectite and illite

  6. Intercalation of a Nonionic Surfactant (C10E3) bilayer into a Na-Montmorillonite Clay

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Intercalation of a Nonionic Surfactant (C10E3) bilayer into a Na-Montmorillonite Clay Régis of a Na-montmorillonite clay at several concentrations. The synthesized organoclays were characterized surfactants in clays where the expansion of the interlayer space was limited to two monolayers parallel

  7. Clay: A Type-Safe Systems Programming Language Bucknell Computer Science Technical Report #08-1

    E-Print Network [OSTI]

    Wittie, Lea

    Clay: A Type-Safe Systems Programming Language Bucknell Computer Science Technical Report #08-1 Lea Wittie March 12, 2008 1 Introduction The Clay programming language is a type-safe variant of C, arithmetic constraints in function pre and post conditions, polymorphism, and type inference. Clay is able

  8. Metal-Exchanged Clay and Zeolite Additives as Smoke Suppressants and Fire Retardants for

    E-Print Network [OSTI]

    Pike, Robert D.

    Metal-Exchanged Clay and Zeolite Additives as Smoke Suppressants and Fire Retardants for Poly studies showed that various metal- exchanged clays and zeolites containing only 3­4% of Cu(II), Cu(I), Zn blends of the clays, and the effectiveness of the additives was usually improved considerably by heat

  9. 182 28th ANNUAL eMS Sorption and Desorption of Quaternary Amine Cations on Clays

    E-Print Network [OSTI]

    Sparks, Donald L.

    182 28th ANNUAL eMS Sorption and Desorption of Quaternary Amine Cations on Clays Z. Z. Zhang and D of organic cations on clays was first studied by Hendricks1. It has been shown that organic cations to measure the cation exchange capacity of the clay2 as well as to determine the specific surface area3

  10. Putty und clay Funktionen in Produktion und Finanzen Eine Einfhrung in die Makro-konophysik

    E-Print Network [OSTI]

    Mimkes, Jürgen

    Putty und clay Funktionen in Produktion und Finanzen Eine Einführung in die Makro Funktionen als putty oder clay. Putty bedeutet Kitt, der erst weich ist und dann fest wird. Eine putty Jahresende (ex post) ist es fixiert. Clay bedeutet Ton. Eine (gebrannte) Tonschale ist anfangs fest und auch

  11. Clay minerals in late glacial and Holocene sediments of the northern and southern Aegean Sea

    E-Print Network [OSTI]

    Siebel, Wolfgang

    Clay minerals in late glacial and Holocene sediments of the northern and southern Aegean Sea Werner Different source areas, oceanography and climate regimes influenced the clay mineral assemblages and grain and the Holocene. In the North Aegean Sea, clay mineral composition is mainly controlled by sea level evolution

  12. Hyperspectral laboratory and remote sensing applied to clay minerals identification and mapping

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Hyperspectral laboratory and remote sensing applied to clay minerals identification and mapping contain clay minerals that change volume with water content and cause extensive and expensive damage susceptibility. At local scale, characterization of soil properties and identification of clay minerals using

  13. Epoxy Nanocomposites with Highly Exfoliated Clay: Mechanical Properties and Fracture Mechanisms

    E-Print Network [OSTI]

    George, Steven C.

    Epoxy Nanocomposites with Highly Exfoliated Clay: Mechanical Properties and Fracture Mechanisms Ke; Revised Manuscript Received November 9, 2004 ABSTRACT: Epoxy/clay nanocomposites with a better exfoliated and transmission electron microscopy (TEM). It was found that clay was highly exfoliated and uniformly dispersed

  14. EFFECT OF BENTONITE MIGRATION IN GEOSYNTHETIC CLAY LINERS ON CONTAMINANT TRANSPORT

    E-Print Network [OSTI]

    1 EFFECT OF BENTONITE MIGRATION IN GEOSYNTHETIC CLAY LINERS ON CONTAMINANT TRANSPORT T. D. Stark1.ca.gov ABSTRACT: Since the introduction of geosynthetic clay liners (GCLs) to waste containment facilities, one contaminant transport through a GCL. 1 INTRODUCTION In recent years, geosynthetic clay liners (GCLs

  15. Occurrence and alteration of clay minerals in the Caribbean Sea

    E-Print Network [OSTI]

    Johnson, Charles Michael

    1973-01-01T23:59:59.000Z

    in these sedi- ments. The high angle x-ray diffraction peaks used for the deter- minations (Velde and Hower, 1963; Velde, 1965; Maxwell and Hower, 1967) have little or no intensity in complex clay mixtures. Halloysite 0 Broadening on the low angle side...

  16. Fine particle clay catalysts for coal liquefaction. Final technical report

    SciTech Connect (OSTI)

    Olson, E.S.

    1995-08-01T23:59:59.000Z

    In an effort to develop new disposable catalysts for direct coal liquefaction, several types of clay-supported pyrrhotite catalysts were prepared and tested. These included iron-pillared montmorillonite, mixed iron/alumina-pillared montmorillonite, iron-impregnated montmorillonite, and iron oxometallate-impregnated montmorillonite.

  17. Kinetics of Swelling in Clay-Bearing Stones

    E-Print Network [OSTI]

    Petta, Jason

    neutrality #12;Invasion of Water Water invades between the sheets The water molecules surround the ions (like salt dissolving) Thus the sheets are pushed apart by the water #12;Brownstone Larger Quartz Grains Clay-wc #12;Reasons... The stone has a lack of homogeneity Each sample varies based upon what part

  18. Reinforcement and environmental degradation of nylon-6/clay nanocomposites

    E-Print Network [OSTI]

    Mather, Patrick T.

    2000; accepted 6 December 2000 Abstract Hybrid organic/inorganic nanocomposites are being developedReinforcement and environmental degradation of nylon-6/clay nanocomposites J.S. Shelleya , P their processing characteristics. One such nanocomposite developed by Toyota and commercialized by Ube Industries

  19. A review of WIPP (Waste Isolation Pilot Plant) repository clays and their relationship to clays of adjacent strata

    SciTech Connect (OSTI)

    Krumhansl, J.L.; Kimball, K.M.; Stein, C.L.

    1990-12-01T23:59:59.000Z

    The Salado Formation is a thick evaporite sequence located in the Permian Delaware Basin of southeastern New Mexico. This study focuses on the intense diagenetic alteration that has affected the small amounts of clay, feldspar, and quartz washed into the basin during salt deposition. These changes are of more than academic interest since this formation also houses the WIPP (Waste Isolation Pilot Plant). Site characterization concerns warrant compiling a detailed data base describing the clays in and around the facility horizon. An extensive sampling effort was undertaken to address these programmatic issues as well as to provide additional insight regarding diagenetic mechanisms in the Salado. Seventy-five samples were collected from argillaceous partings in halite at the stratigraphic level of the Waste Isolation Pilot Plant (WIPP). These were compared with twenty-eight samples from cores of the Vaca Triste member of the Salado, a thin clastic unit at the top of the McNutt potash zone, and with a clay-rich sample from the lower contact of the Culebra Dolomite (in the overlying Rustler Formation). These settings were compared to assess the influence of differences in brine chemistry (i.e., halite and potash facies, normal to hypersaline marine conditions) and sediment composition (clays, sandy silt, dolomitized limestone) on diagenetic processes. 44 refs., 11 figs., 5 tabs.

  20. Investigation of the suitability of a geosynthetic clay liner system for the El Paso Solar Pond

    SciTech Connect (OSTI)

    Robbins, M.C.; Lu, H.; Swift, A.H.P. Jr. [Univ. of Texas, El Paso, TX (United States). Mechanical and Industrial Engineering Dept.

    1995-10-01T23:59:59.000Z

    The El Paso Solar Pond Project experienced a complete failure of its XR-5 8130 (SP) membrane liner. This paper will summarize the XR-5 8130 (SP) liner failure analysis, and provide design and installation procedures of its replacement: a geosynthetic clay liner (GCL). This application represents the first use of a GCL in a solar pond. Geosynthetic clay liners offer major advantages over membrane liners. Unlike membrane liners, clay liners are puncture-proof, have predictable permeability, and are self-healing. Furthermore, the cost of clay liners is less than that of membrane liners. However, disagreement exists as to the efficacy of clay liners in solar ponds. The high temperatures and salinity of the pond are factors which cause the most concern. Most information available for clay liners is in conjunction with municipal waste disposal facilities, although compacted clay liners have been used in Israel and Mexico for solar ponds.

  1. WRIGHT, MELANIE CLAY. The Effects of Automation on Team Performance and Team Coordination. (Under the direction of David B. Kaber).

    E-Print Network [OSTI]

    Kaber, David B.

    ABSTRACT WRIGHT, MELANIE CLAY. The Effects of Automation on Team Performance and Team Coordination OF AUTOMATION ON TEAM PERFORMANCE AND TEAM COORDINATION By MELANIE CLAY WRIGHT A dissertation submitted #12;BIOGRAPHY Melanie Clay Wright was born Melanie Carol Clay in Bethesda, Maryland in April, 1966

  2. The occurrence of clays and their bearing on evaporite mineralogy in the Salado Formation, Delaware Basin, New Mexico

    E-Print Network [OSTI]

    Harville, Donald Gene

    1985-01-01T23:59:59.000Z

    , potassium, and magnesium K-alpha linescans from sample in SEM photograph (thin 'line). The dark area corresponding to the high silicon area is clay. The mineral to the left of the clay is langbefnite, and to the right of the clay is halite. . . . Thin.... Thin sections were made from samples in intervals include potash minerals in clay-rich areas, potash minerals in clay-free areas, clay occurrences in halite/poIyhalite areas, and clay-free occurrences of halite and polyhalite. These thin sections...

  3. Deep ocean clay crusts: behaviour and biological origin

    E-Print Network [OSTI]

    Kuo, Matthew Yih-Han

    2011-03-15T23:59:59.000Z

    Deep ocean clay crusts: behaviour and biological origin Matthew Yih-Han Kuo King’s College University of Cambridge A dissertation submitted for the degree of Doctor of Philosophy February 2011 To Kirsty, Mum, Dad and Ivana “. . . observe the small... , the deep Pacific and the Peru Margin. . . . . . . . . . . . . . . . . . . . . . . . . . 18 3.1 Water content and liquid limit measurements taken from box and STACOR core samples confirming measurements by Fugro (also shown). . . . . . . . . . . 23 3...

  4. Diagenesis of clay minerals from early Eocene shales of Texas

    E-Print Network [OSTI]

    Whynot, John David

    1983-01-01T23:59:59.000Z

    de Segonzac, 1979; Foscolos and Kodama, 1. 974; Hower et. al. , 1976; Perry and Hower, 1970; Weaver and Beck, 1971) noted an increase in illite layers with a concommitant decrease in smectite layers and randomness of interstratification in mixed... is reached. This phase seems to be thermo- dynamically stable to temperatures of at least 163'C (Foscolos and Kodama, 1974; Perry and Hower, 1970). Mixed-layer clays may also be converted to chlorite with increas- ing depth of burial (Dunoyer de Segonzac...

  5. Photocatalytic properties of titania pillared clays by different drying methods

    SciTech Connect (OSTI)

    Ding, Z.; Zhu, H.Y.; Lu, G.Q.; Greenfield, P.F. [Univ. of Queensland, Brisbane, Queensland (Australia). Dept. of Chemical Engineering] [Univ. of Queensland, Brisbane, Queensland (Australia). Dept. of Chemical Engineering

    1999-01-01T23:59:59.000Z

    Photocatalysts based on titania pillared clays (TiO{sub 2} PILCs) have been prepared through a sol-gel method. Different drying methods, air drying (AD), air drying after ethanol extraction (EAD), and supercritical drying (SCD) have been employed and found to have significant effects on the photocatalytic efficiency of the resultant catalysts for the oxidation of phenol in water. Titania pillared clay (TiO{sub 2} PILC) obtained by SCD has the highest external and micropore surface area, largest amount and smallest crystallite size of anatase, and exhibited the highest photocatalytic activity. Furthermore, silica titania pillared clay (SiO{sub 2}-TiO{sub 2} PILC) after SCD, titania coated TiO{sub 2} PILC (SCD) and SiO{sub 2}-TiO{sub 2} PILC (SCD) were synthesized to study the key factors controlling the photocatalytic activity. It is concluded that the dispersion of nanometer-sized anatase on the surface of the PILC particles and the suspensibility of the particles are the most important factors for high photocatalytic efficiency.

  6. DE-FG02-06ER15364: Final Technical Report Nanoscale Reactivity of Clays, Clay Analogues (Micas), and Clay Minerals

    SciTech Connect (OSTI)

    Nagy, Kathryn L.

    2008-07-03T23:59:59.000Z

    The project objectives were to determine the nanoscale to molecular scale structure of the interface between muscovite mica and aqueous solutions containing various sorbates and to explore systematics that control the incorporation of inorganic and organic chemical components during aging of nanoparticles of iron-oxides and aluminosilicate clays. The basal surface of phyllosilicates is a primary sorbent of environmental contaminants, natural organic matter, and nutrients. Micas are also superb atomically-flat substrates used in materials science and surface physics applications. We applied X-ray scattering techniques using high brilliance synchrotron radiation to investigate molecular-scale details of mica’s interface structure in solutions containing common and toxic cations, anions, and natural organic molecules. Nanoparticles are ubiquitous in the environment and have a high capacity for sorbing contaminants through the combined effects of their high surface areas and pH-dependent surface charge. Aging of nanoparticles from metastable to stable phases can be inhibited by sorption of nonstructural components, but exact mechanisms are unknown. We synthesized Fe-oxides and aluminosilicate clay minerals from aqueous solutions in the presence of selected anions, and organic molecules, and quantified the uptake of these additives during aging and some implications for nanoparticle formation.

  7. BooNE Neutrino Oscillations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Batteries Batteries An errorABisfuel RetreatsforBoard of

  8. BooNE News Articles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewind Generator|December 5, 2011ExperimentNews

  9. BooNE: Interesting Facts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewindParticle Identification (PID) We

  10. BooNE: Picture Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewindParticle Identification (PID) WePicture

  11. Kinetics of Mixed Ni-Al Precipitate Formation on a Soil Clay Fraction

    E-Print Network [OSTI]

    Sparks, Donald L.

    Kinetics of Mixed Ni-Al Precipitate Formation on a Soil Clay Fraction D A R R Y L R . R O B E R-Al layered double hydroxide (LDH) precipitate formation on a soil clay fraction was monitored using X in 0.1 M NaNO3. Initial Ni sorption kinetics on the soil clay were rapid at all pH values but differed

  12. An Ion Diffusion Model in Semi-Permeable Clay Materials. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Here we proposed a model by coupling electrodynamics and nonequilibrium thermodynamics to describe ion diffusion in the clay materials. The developed model was validated...

  13. and-1b drillcore clay: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Restoration Websites Summary: liner interfaces, such as at the Kettleman Hills landfill (Byrne et al. 1992; Gilbert et al. 1998143 1 INTRODUCTION Geosynthetic clay...

  14. Evaluation of Used Fuel Disposition in Clay-Bearing Rock

    SciTech Connect (OSTI)

    Jové Colón, Carlos F.; Weck, Philippe F.; Sassani, David H.; Zheng, Liange; Rutqvist, Jonny; Steefel, Carl I.; Kim, Kunhwi; Nakagawa, Seiji; Houseworth, James; Birkholzer, Jens; Caporuscio, Florie A.; Cheshire, Michael; Rearick, Michael S.; McCarney, Mary K.; Zavarin, Mavrik; Benedicto, Ana; Kersting, Annie B.; Sutton, Mark; Jerden, James; Frey, Kurt E.; Copple, Jacqueline M.; Ebert, William

    2014-08-29T23:59:59.000Z

    Radioactive waste disposal in shale/argillite rock formations has been widely considered given its desirable isolation properties (low permeability), geochemically reduced conditions, anomalous groundwater pressures, and widespread geologic occurrence. Clay/shale rock formations are characterized by their high content of clay minerals such as smectites and illites where diffusive transport and chemisorption phenomena predominate. These, in addition to low permeability, are key attributes of shale to impede radionuclide mobility. Shale host-media has been comprehensively studied in international nuclear waste repository programs as part of underground research laboratories (URLs) programs in Switzerland, France, Belgium, and Japan. These investigations, in some cases a decade or more long, have produced a large but fundamental body of information spanning from site characterization data (geological, hydrogeological, geochemical, geomechanical) to controlled experiments on the engineered barrier system (EBS) (barrier clay and seals materials). Evaluation of nuclear waste disposal in shale formations in the USA was conducted in the late 70’s and mid 80’s. Most of these studies evaluated the potential for shale to host a nuclear waste repository but not at the programmatic level of URLs in international repository programs. This report covers various R&D work and capabilities relevant to disposal of heat-generating nuclear waste in shale/argillite media. Integration and cross-fertilization of these capabilities will be utilized in the development and implementation of the shale/argillite reference case planned for FY15. Disposal R&D activities under the UFDC in the past few years have produced state-of-the-art modeling capabilities for coupled Thermal-Hydrological-Mechanical-Chemical (THMC), used fuel degradation (source term), and thermodynamic modeling and database development to evaluate generic disposal concepts. The THMC models have been developed for shale repository leveraging in large part on the information garnered in URLs and laboratory data to test and demonstrate model prediction capability and to accurately represent behavior of the EBS and the natural (barrier) system (NS). In addition, experimental work to improve our understanding of clay barrier interactions and TM couplings at high temperatures are key to evaluate thermal effects as a result of relatively high heat loads from waste and the extent of sacrificial zones in the EBS. To assess the latter, experiments and modeling approaches have provided important information on the stability and fate of barrier materials under high heat loads. This information is central to the assessment of thermal limits and the implementation of the reference case when constraining EBS properties and the repository layout (e.g., waste package and drift spacing). This report is comprised of various parts, each one describing various R&D activities applicable to shale/argillite media. For example, progress made on modeling and experimental approaches to analyze physical and chemical interactions affecting clay in the EBS, NS, and used nuclear fuel (source term) in support of R&D objectives. It also describes the development of a reference case for shale/argillite media. The accomplishments of these activities are summarized as follows: ? Development of a reference case for shale/argillite; ? Investigation of Reactive Transport and Coupled THM Processes in EBS: FY14; ? Update on Experimental Activities on Buffer/Backfill Interactions at elevated Pressure and Temperature; ? Thermodynamic Database Development: Evaluation Strategy, Modeling Tools, First-Principles Modeling of Clay, and Sorption Database Assessment; ? ANL Mixed Potential Model For Used Fuel Degradation: Application to Argillite and Crystalline Rock Environments.

  15. Competing interactions in arrested states of colloidal clays

    E-Print Network [OSTI]

    B. Ruzicka; L. Zulian; E. Zaccarelli; R. Angelini; M. Sztucki; A. Moussaid; G. Ruocco

    2010-01-22T23:59:59.000Z

    Using experiments, theory and simulations, we show that the arrested state observed in a colloidal clay at intermediate concentrations is stabilized by the screened Coulomb repulsion (Wigner glass). Dilution experiments allow us to distinguish this high-concentration disconnected state, which melts upon addition of water, from a low-concentration gel state, which does not melt. Theoretical modelling and simulations reproduce the measured Small Angle X-Ray Scattering static structure factors and confirm the long-range electrostatic nature of the arrested structure. These findings are attributed to the different timescales controlling the competing attractive and repulsive interactions.

  16. Non-linear Poisson-Boltzmann Theory for Swollen Clays

    E-Print Network [OSTI]

    R. J. F. Leote de Carvalho; E. Trizac; J. P Hansen

    1998-04-20T23:59:59.000Z

    The non-linear Poisson-Boltzmann equation for a circular, uniformly charged platelet, confined together with co- and counter-ions to a cylindrical cell, is solved semi-analytically by transforming it into an integral equation and solving the latter iteratively. This method proves efficient, robust, and can be readily generalized to other problems based on cell models, treated within non-linear Poisson-like theory. The solution to the PB equation is computed over a wide range of physical conditions, and the resulting osmotic equation of state is shown to be in fair agreement with recent experimental data for Laponite clay suspensions, in the concentrated gel phase.

  17. Chemical, mineralogical and physical properties of the San Saba Clay

    E-Print Network [OSTI]

    Nelson, Larry Alan

    1958-01-01T23:59:59.000Z

    ? San Saba an4 Victoria Clay s 1 ST SOS UCT I OS Ssseawh 4oslgsed to stagy ihe basks pwperikes of ihe sells of ihe Oread Prakrle ef oeniral Tense ls generally Laehkng Consegaontly, there ls lktile soil data aeaklablo fer reselvkng ~ageaesi as4 fer..., Slash are deeply appreelaisd, Maap ihashs also are das io Xa ~ Earrep Qehos~ Senior Corrolaior~ Sell Cessor@a ilos Serrfoo~ sho located ihe ssapllsS elise asd also edNed iho profile de earl pilose. TABLE (~ QOSTXSTS ISTBDDUGTIES Li TXS4TUDZ BKV IX...

  18. The adsorption of selected chemical compounds on soil clays

    E-Print Network [OSTI]

    Hoover, William Leroy

    1964-01-01T23:59:59.000Z

    by such chemical compounds and atomic wastes might be a potent weapon in time of war. Also, such contaminants are adding to the numerous local problems in this country during time of peace, and there is every indication that the problems will increase in magni...- tude in the future, Analogous problems exist with detergent wastes, atomic wastes, factory and industrial wastes, and the widespread uses of insecticides and fungicides. The various high adsorbing soil-clays may provide an answer, or at least a...

  19. Clay County Electric Coop Corp | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovationin UrbanCity ofCity ofInformationClaridgeClassicClay County

  20. Clay-Union Electric Coop | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCity ofClark Energy Coop IncClay-Union

  1. Clay County, Florida: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, clickInformation SmyrnaNew York:Information Systems: AAlabama:Clay

  2. Clay County, Indiana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, clickInformation SmyrnaNew York:Information Systems:Illinois: EnergyClay

  3. Clay Minerals Related To The Hydrothermal Activity Of The Bouillante

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, clickInformation SmyrnaNewClay Electric Cooperative, Inc Jump to:Geothermal

  4. Numerical methods for analysis of clay tile infills

    SciTech Connect (OSTI)

    Flanagan, R.D.; Tenbus, M.A. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States); Bennett, R.M. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Civil Engineering

    1993-10-20T23:59:59.000Z

    Recent Department of Energy requirements have led to a comprehensive evaluation of the industrial facilities at the Oak Ridge Y-12 Plant. The structures consist of simply connected steel frames infilled with structural clay tile walls. The objective of the evaluation was to determine the stability of the unreinforced infills, and whether they provide the lateral capacity necessary to resist the moderate seismic hazard at the site. Due to lack of information on the behavior of structural clay tile infills, various large-scale tests were performed to investigate the in-plane, out-of-plane and combined in-plane and out-of-plane behavior. The results of these tests are briefly summarized, and the development of analytical guidelines based on these tests is given. Little interaction between in-plane and out-of-plane loads was observed, both in terms of stiffness and strength. Out-of-plane stability can be examined panel by panel based on arching action. Inter-story drift does not appear to present a stability problem for the type of infill construction investigated. In-plane behavior may be adequately modeled with a nonlinear compression strut. A typical building is chosen for an illustrative application. The methodology and results of the seismic analysis are presented for this structure.

  5. Layer-by-Layer Assembly of Clay-filled Polymer Nanocomposite Thin Films 

    E-Print Network [OSTI]

    Jang, Woo-Sik

    2010-01-14T23:59:59.000Z

    -filled polymer composite, is believed to be due to a ?brick wall? nanostructure comprised of completely exfoliated clay bricks in polymeric ?mortar?. The growth of polymer and clay assemblies is then shown to be controlled by altering the pH of polyethylenimine...

  6. Reduced adsorption of caesium on clay minerals caused by various humic substances

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Reduced adsorption of caesium on clay minerals caused by various humic substances C. Dumat, S!ect of the addition of various humic substances on the adsorption of caesium on two mineral clays has been studied the amount of humic substance adsorbed and the decrease in Cs adsorption when all complexes were considered

  7. Fibrous-clay mineral formation and soil evolution in Aridisols of northeastern Patagonia, Argentina

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Fibrous-clay mineral formation and soil evolution in Aridisols of northeastern Patagonia, Argentina Patagónico, CONICET, Avd. Brown s/n, 9120, Puerto Madryn, Chubut, Argentina b Departamento de Edafología, EPS horizons; Chubut province of Argentina 1. Introduction Palygorskite and sepiolite are clay minerals

  8. Change in the hydraulic properties of a Brazilian clay Ferralsol on clearing for pasture

    E-Print Network [OSTI]

    Boyer, Edmond

    Change in the hydraulic properties of a Brazilian clay Ferralsol on clearing for pasture L. C 80 to 300 m in size. The aim of this study was to analyze how the hydraulic properties of a clay retention properties were determined by using pressure cell equipment. We determined the saturated hydraulic

  9. 1 INTRODUCTION Geosynthetic clay liners (GCLs) with geomembranes (GMs) placed on slopes as part of composite

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    143 1 INTRODUCTION Geosynthetic clay liners (GCLs) with geomembranes (GMs) placed on slopes as part and interface shear strength of geosynthetic clay liners J.G. ZORNBERG The University of Texas at Austin, Austin of composite liner systems may be subject to a complex, time-dependent state of stresses. Stability is a major

  10. Evacuated Panels Utilizing Clay-Polymer Aerogel Composites for Improved Housing Insulation

    E-Print Network [OSTI]

    Rollins, Andrew M.

    Evacuated Panels Utilizing Clay-Polymer Aerogel Composites for Improved Housing Insulation March 17 encompasses a newly developed clay-polymer aerogel composite material (developed and patented by Dr. David Aerogel ~22 > 2,500 Silica Aerogel Blanket 10 1,800 (Aspen Aerogel) Silica Aerogel / PP Evacuated Panel 50

  11. Solid-State NMR Study of Intercalated Species in Poly( -caprolactone)/Clay Nanocomposites

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Solid-State NMR Study of Intercalated Species in Poly( - caprolactone)/Clay Nanocomposites J of surfactant and polymer chains in intercalated poly( - caprolactone)/clay nanocomposites are characterized by 31 P magic-angle spinning (MAS) and 13 C cross-polarization MAS NMR techniques. To obtain hybrid

  12. Simulation of the degradation of a concrete/clay interface: influence of temperature, unsaturated conditions and porosity variations

    E-Print Network [OSTI]

    Burnol, A.; Dupros, F.; Spycher, N.; Xu, T.; Gaucher, E.C.

    2008-01-01T23:59:59.000Z

    SIMULATION OF THE DEGRADATION OF A CONCRETE/CLAY INTERFACE:transport models applied to degradation of a concrete/clayused by the simulation of degradation of the concrete/clay

  13. Continuous Hyperplastic Models for Overconsolidated ClaysContinuous Hyperplastic Models for Overconsolidated Clays Visit us at: "www.technion.ac.il" and "www-civil.eng.ox.ac.uk"

    E-Print Network [OSTI]

    Houlsby, Guy T.

    Continuous Hyperplastic Models for Overconsolidated ClaysContinuous Hyperplastic Models for Overconsolidated Clays Visit us at: "www.technion.ac.il" and "www-civil.eng.ox.ac.uk" I. Einav and A.M. Puzrin for the formulation of realistic models for the triaxial behaviour of overconsolidated clays at both small and large

  14. J. CHEM. SOC. FARADAY TRANS., 1991, 87(15), 2501-2506 2501 Ca-K-H Exchange on Silt-, Clay-and Silt +Clay-size Soil Separates

    E-Print Network [OSTI]

    Sparks, Donald L.

    J. CHEM. SOC. FARADAY TRANS., 1991, 87(15), 2501-2506 2501 Ca-K-H Exchange on Silt-, Clay- and Silt +Clay-size Soil Separates Steven A. Grant*t and Donald L. Sparks Department of Plant and Soil Sciences and kaolinite clays. To predict accurately chemical equilibria of a natural ion- exchanger, one is forced

  15. 8/24/2005 Prashant and Penumadu. IACMAG-2005 1 On Shear Strength Behavior of Clay with Sudden FailureOn Shear Strength Behavior of Clay with Sudden Failure

    E-Print Network [OSTI]

    Prashant, Amit

    8/24/2005 Prashant and Penumadu. IACMAG-2005 1 On Shear Strength Behavior of Clay with Sudden FailureOn Shear Strength Behavior of Clay with Sudden Failure ResponseResponse Amit Prashant and Dayakar on the cubical specimens of normally to heavily over- consolidated Kaolin clay. The pre-failure elasto

  16. Laboratory Hydro-mechanical Characterisation of Boom Clay at Essen and Mol Y. F. Deng1, 2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Laboratory Hydro-mechanical Characterisation of Boom Clay at Essen and Mol Y. F. Deng1, 2 , A. M. In the present work, the hydro-mechanical behaviour of Boom clay samples from the borehole Essen-1 at a depth and hydro-mechanical behaviour of Boom clay from Essen at 227-m, 240-m and 248-m depths are similar

  17. Thermodynamic assessment of the variation of the surface areas of two synthetic swelling clays during adsorption of water

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Thermodynamic assessment of the variation of the surface areas of two synthetic swelling clays; Synthetic smectite; Water; Adsorption; Surface area; Swelling clay; Interlayer space #12;1. Introduction Synthetic clays are very interesting materials, both for scientific research and for industrial applications

  18. CLAY MINERALOGY ALONG THE LATERITE PROFILE IN HUBEI, SOUTH CHINA: MINERAL EVOLUTION AND EVIDENCE FOR EOLIAN ORIGIN

    E-Print Network [OSTI]

    Li, Zhaohui

    CLAY MINERALOGY ALONG THE LATERITE PROFILE IN HUBEI, SOUTH CHINA: MINERAL EVOLUTION AND EVIDENCE in more detail the associated mineralogical evolution, i.e. clay mineral composition, structural characteristics of clays in various beds with different degrees of weathering along the laterite profile

  19. Origin and significance of clay-coated fractures in mudrock fragments of the SAFOD borehole (Parkfield, California)

    E-Print Network [OSTI]

    Origin and significance of clay-coated fractures in mudrock fragments of the SAFOD borehole Received 4 April 2006; revised 26 June 2006; accepted 12 July 2006; published 24 August 2006. [1] The clay. Warr (2006), Origin and significance of clay-coated fractures in mudrock fragments of the SAFOD

  20. Clay mineralogy of surface sediments as a tool for deciphering river contributions to the Cariaco Basin (Venezuela)

    E-Print Network [OSTI]

    Meyers, Steven D.

    Clay mineralogy of surface sediments as a tool for deciphering river contributions to the Cariaco the Cariaco Basin continental shelf and Orinoco delta was investigated in order to constrain the clay was studied using a geo-statistical approach that allows drawing representative clay-mineral distribution maps

  1. Effective Shear Strength of Fiber-Reinforced Clays Freilich, B. J., Li, C., and Zornberg, J. G.

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    Effective Shear Strength of Fiber-Reinforced Clays Freilich, B. J., Li, C., and Zornberg, J. G unconfined compression testing of clay soils have provided evidence that the short term total shearing-reinforced clay soils is determined utilizing both isotropic consolidated-undrained (ICU) triaxial testing

  2. Oxygen isotope fractionation effects in soil water via interaction with cations (Mg, Ca, K, Na) adsorbed to phyllosilicate clay minerals

    E-Print Network [OSTI]

    Goldsmith, Greg

    ) adsorbed to phyllosilicate clay minerals Erik Oerter a, , Kari Finstad a , Justin Schaefer b , Gregory R with knowledge that clay particles possessing an electronegative surface charge and resulting cation exchange capacity (CEC) interact with a wide range of solutes which, in the absence of clays, have been shown

  3. Clay quantification and AreAr dating of synthetic and natural gouge: Application to the Miocene Sierra Mazatan

    E-Print Network [OSTI]

    Clay quantification and AreAr dating of synthetic and natural gouge: Application to the Miocene on the assumption that illite in fault gouge is a mixture of two populations of clays: one detrital, derived from remained largely untested. We demonstrate the validity of our clay quantification technique using

  4. Environ. Sci. Technol. 1993, 27, 1625-1631 Sorptlon and Desorption of Quaternary Amine Cations on Clays

    E-Print Network [OSTI]

    Sparks, Donald L.

    on Clays 2. Zhong Zhang,'it Donald L. Sparks,? and Noel C. Scrivner* Department of Plant and Soil Sciences. Therefore, it appears that there is good promise in using quaternary amine-modified clays as effective The sorption of organic cations on soils and clays was perhaps first observed by Lloyd in 1916 when he found

  5. EUROPIUM RETENTION ONTO CLAY MINERALS FROM 25 TO 150C: EXPERIMENTAL MEASUREMENTS, SPECTROSCOPIC FEATURES AND SORPTION MODELLING.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 EUROPIUM RETENTION ONTO CLAY MINERALS FROM 25 TO 150°C: EXPERIMENTAL MEASUREMENTS, SPECTROSCOPIC.Tertre@univ-lille1.fr Keywords: europium, sorption, clays, experimental, temperature, Time-Resolved Laser was investigated up to 150°C. The clays were purified samples, saturated with Na in the case of montmorillonite

  6. Clay fabric intensity in natural and artificial fault gouges: Implications for brittle fault zone processes and sedimentary

    E-Print Network [OSTI]

    Clay fabric intensity in natural and artificial fault gouges: Implications for brittle fault zone processes and sedimentary basin clay fabric evolution Samuel H. Haines,1 Ben A. van der Pluijm,1 Matt J intensity measurements using X-ray texture goniometry on 22 natural clay-rich fault gouges from low

  7. Effect of Specimen Conditioning on Geosynthetic Clay Liner Shear J.S. McCartney & J.G. Zornberg

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    635 Effect of Specimen Conditioning on Geosynthetic Clay Liner Shear Strength J.S. McCartney & J of geosynthetic clay liners (GCLs) must replicate field conditions while still accounting for time and cost to conditioning. 1 INTRODUCTION Geosynthetic clay liners (GCLs) are prefabricated geocomposite materials used

  8. Slope stability of geosynthetic clay liner test plots

    SciTech Connect (OSTI)

    Daniel, D.E. [Univ. of Illinois, Urbana, IL (United States); Koerner, R.M. [Drexel Univ., Philadelphia, PA (United States). Geosynthetic Research Inst.; Bonaparte, R. [GeoSyntec Consultants, Atlanta, GA (United States); Landreth, R.E. [Landreth, (Robert E.), West Chester, OH (United States); Carson, D.A. [Environmental Protection Agency, Cincinnati, OH (United States); Scranton, H.B. [Haley and Aldrich, Boston, MA (United States)

    1998-07-01T23:59:59.000Z

    Fourteen full-scale field test plots containing five types of geosynthetic clay liners (GCLs) were constructed on 2H:1V and 3H:1V slopes for the purpose of assessing slope stability. The test plots were designed to simulate typical final cover systems for landfills. Slides occurred in two of the 2H:1V test plots along interfaces between textured geomembranes and the woven geotextile components of internally reinforced GCLs. One additional slide occurred within the unreinforced GCL component of a 2H:1V test plot, when the GCL unexpectedly became hydrated. All 3H:1V slopes have remained stable. Results of laboratory direct shear tests compared favorably with field observations, providing support for the current design procedures that engineers are using for assessing the stability of slopes containing GCLs.

  9. Installation of geosynthetic clay liners at California MSW landfills

    SciTech Connect (OSTI)

    Snow, M.; Jesionek, K.S.; Dunn, R.J.; Kavazanjian, E. Jr.

    1997-11-01T23:59:59.000Z

    The California regulations for liner systems at municipal solid waste (MSW) landfills require that alternatives to the prescriptive federal Subtitle D liner system have a containment capability greater than that of the prescriptive system. Regulators may also require a demonstration that use of the prescriptive system is burdensome prior to approval of an alternative liner design. This paper presents seven case histories of the design and installation of geosynthetic clay liners (GCL) as an alternative to the low-permeability soil component of the prescriptive Subtitle D composite liner system at MSW landfills in California. These case histories cover GCLs from different manufacturers and landfill sites with a wide range of conditions including canyon landfills with slopes as steep as 1H:1V.

  10. Effect of aging of the pillaring reagent on the microstructure and cracking activity of pillared clay

    SciTech Connect (OSTI)

    Harris, J.R. (Phillips Petroleum Company, Bartlesville, OK (USA))

    1987-08-01T23:59:59.000Z

    Pillared interlayer clay (PILC) is formed by exchanging large hydroxyaluminum polycations into the interlayer of a smectite clay such as montmorillonite, which is made up of sheet-like silica/alumina layers. Calcination of the exchanged clay gives a well dispersed array of metal oxide clumps (i.e., pillars) bonded top and bottom to the silica/alumina layers of the clay. The permanent separation of the clay layers gives an 8 to 10-fold increase in surface area, from 30 to 250-300 m{sup 2}/g, and a microporous structure similar to but less constrained than that of zeolites. Recently, there has been an increased interest in the use of these clays as cracking catalysts. For example, pillared clays have been shown to be an active cracking catalyst for both single component and gas oil feeds. PILC's also lead to both higher light cycle oil (LCO) and coke yields than conventional cracking catalysts. Commercially available, metal-hydrolyzed hydroxyaluminum solutions containing chlorhydrol, A1{sub 2}(OH){sub 5}C1.2H{sub 2}O, have been used as one source of the polycation solution. The approach of these hydrolyzed polycation solutions to equilibrium is known as aging. During the aging process certain polycationic species disappear from the solution and new species are formed. For this reason, the aging process can have a significant influence on the properties of the pillared clays. The objective of this work was to determine how the physical and catalytic properties of the pillared clay depend on the aging of dilute cholorhydrol solutions.

  11. (Data in thousand metric tons, unless noted) Domestic Production and Use: In 1995, clays were produced in most States except Alaska, Delaware, Hawaii,

    E-Print Network [OSTI]

    44 CLAYS (Data in thousand metric tons, unless noted) Domestic Production and Use: In 1995, clays, these firms operated about 983 mines. Estimated value of all marketable clay produced was about $1.8 billion. Major domestic uses for specific clays were estimated as follows: kaolin--55% paper, 8% kiln furniture

  12. (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 1998, clays were produced in most States except Alaska, Delaware, Hawaii, Idaho,

    E-Print Network [OSTI]

    50 CLAYS (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 1998, clays were produced in most States except Alaska, Delaware, Hawaii, Idaho, New Hampshire, Rhode clay produced was about $2.14 billion. Major domestic uses for specific clays were estimated as follows

  13. Values of Mineral Modulus of Clay Manika Prasad, Ronny Hofmann, Mike Batzle, Colorado School of Mines; M. Kopycinska-Mller, U. Rabe, and

    E-Print Network [OSTI]

    Values of Mineral Modulus of Clay Manika Prasad, Ronny Hofmann, Mike Batzle, Colorado School formations is altered by the presence of clay minerals. Knowledge about the elastic properties of clay is therefore essential for the interpretation and modeling of the seismic response of clay- bearing formations

  14. K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles...

    Open Energy Info (EERE)

    Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles Caldera, New Mexico And Their Relation To Alteration In A Large Hydrothermal System Jump to: navigation, search OpenEI...

  15. Use of ultrasound attenuation spectroscopy to determine the size distribution of clay tactoids in aqueous suspensions

    E-Print Network [OSTI]

    Samim Ali; Ranjini Bandyopadhyay

    2014-06-27T23:59:59.000Z

    The dispersion processes of aqueous samples of clay are studied using ultrasound attenuation spectroscopy. The attenuation spectra that are acquired in the frequency range $10-100$ MHz are used to determine the particle size distributions (PSDs) for different concentrations and ages of the clay suspensions. Our analysis, using equivalent spherical diameter (ESD) for circular discs under Stokes drag in samples of concentrations greater than 1.5\\% w/v, shows that a substantial fraction of the aggregates in suspension are actually tactoids that are composed of more than one platelet. This is in contrast to the general belief that clay disperses into individual platelets in the concentration range where their suspensions exhibit glassy behavior. We conclude that the incomplete fragmentation of the clay tactoids arises from the rapid enhancement of the inter-tactoid Coulombic repulsion.

  16. A comparison of the behavior of intact and Resedimented Boston Blue Clay (BBC)

    E-Print Network [OSTI]

    House, Robert Donald

    2012-01-01T23:59:59.000Z

    Resedimented Boston Blue Clay (RBBC) has been used as an analog test material for research at MIT for decades, due to local variability and the high cost of sampling. However, a comprehensive study of the differences in ...

  17. Detection and Quantification of Expansive Clay Minerals in Geologically-Diverse Texas Aggregate Fines

    E-Print Network [OSTI]

    Russell, George 1983-

    2012-11-28T23:59:59.000Z

    Expansive clay mineral contamination of road aggregate materials in Texas is a persistent problem. Hydrous layer silicate minerals - particularly smectites - in concretes are associated with decreased strength and durability in Portland cement...

  18. Dechlorination of Pentachlorophenol by ammonium amended clays: development of field applicable techniques

    E-Print Network [OSTI]

    Lu, Junying

    1997-01-01T23:59:59.000Z

    superfund sites in both soil and groundwater. The objective of this thesis is to study mechanisms to dechlorinate PCP into less harmful derivatives. The method that we are interested in utilizes ammonium-amended clays to dechlorinate PCP. Based...

  19. Natural rubber-clay nanocomposites: mechanical and structural properties Camila A. Rezende1,2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , University of Campinas, P.O. Box 6154, CEP 13083-970, Campinas- SP, Brazil *Corresponding Author E-mail: Lay in the number of papers and patents on polymer-clay nanocomposites that report outstanding mechanical

  20. Engineering properties of Resedimented Ugnu Clay from the Alaskan North Slope

    E-Print Network [OSTI]

    Jones, Cullen A. (Cullen Albert)

    2010-01-01T23:59:59.000Z

    This research determined the engineering properties of laboratory Resedimented Ugnu Clay (RUC) specimens created using recovered material from 3800 ft below the surface of the Alaskan Northern Slope to aid with future ...

  1. Layer-by-Layer Assembly of Clay-filled Polymer Nanocomposite Thin Films

    E-Print Network [OSTI]

    Jang, Woo-Sik

    2010-01-14T23:59:59.000Z

    robotic dipping system, for the preparation of these thin films, was built. The robot alternately dips a substrate into aqueous mixtures with rinsing and drying in between. Thin films of sodium montmorillonite clay and cationic polymer were grown...

  2. Coupled hydro-mechanical processes in crytalline rock and in induratedand plastic clays: A comparative discussion

    E-Print Network [OSTI]

    Tsang, Chin-Fu; Blumling, Peter; Bernier, Frederic

    2008-01-01T23:59:59.000Z

    of heterogeneity in rock property (clay content and henceNon-linear) elastic properties of the rock. Biot coefficientNon-linear) elastic properties of the rock including their

  3. Application of the Modified Methylene Blue Test to Detect Clay Minerals in Coarse Aggregate Fines

    E-Print Network [OSTI]

    Pitre, Brandon

    2012-12-04T23:59:59.000Z

    mix asphalt (HMA) and Portland cement concrete (PCC) mixes was also conducted. In one phase of the study, known amounts of standard clay minerals were introduced to the mixes, and performance testing was carried out. This was done in hopes...

  4. Investigating the Use of Chelating Agents for Clay Dissolution and Sandstone Acidizing Purposes 

    E-Print Network [OSTI]

    Andotra, Gautam

    2014-08-06T23:59:59.000Z

    -Glutamic acid N,N-Di Acetic Acid (Na-GLDA). Experiments were conducted to find out the aluminosilicates dissolution and chelation capabilities of these chelating agents. The first set of experiments were clay dissolution experiments, conducted using different...

  5. Clay Electric Cooperative, Inc- Energy Smart Solar Water Heater Rebate Program

    Broader source: Energy.gov [DOE]

    Clay Electric Cooperative (CEC) provides a rebate of $0.01 per BTU output to its residential members when they purchase qualified solar water heaters. This rebate is capped at 60,000 BTUs per...

  6. Clay minerals of recent marine sediments to the west of the Mississippi Delta

    E-Print Network [OSTI]

    McAllister, Raymond Francis

    1958-01-01T23:59:59.000Z

    CLAY MINERALS OF RECENT MARINE SEDIMENTS 10 THE WEST OP THE MISSISSIPPI DKLTA A Dissertation By RAYMOND ERANCIS McALLI9TER> Jr. Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY IN OCEANOGRAPHY May* 1958 Major Subject: Geological Oceanography CLAY MINERALS OF RECENT MARINE SEDIMENTS TO THE WEST OF THE MISSISSIPPI DELTA A Dissertation RAYMOND FRANCIS McALLISTER, Jr. Approved...

  7. Morphological, mineralogical and physicochemical characteristics of some dark clay soils of Puerto Rico

    E-Print Network [OSTI]

    Acevedo, Gilberto

    1958-01-01T23:59:59.000Z

    . '. beany of tho soil propox ties, such as plasticity, stickiness, s~elling and shrinking upon wottixxg and dryinp ~ and exchange capacity, are dependent upon the clay mineral fraction of' the soil. It is expected that thc observed rolationships... l. X-ray d5. ffraction pa'tterns for the clay minerals kaolinite~ illite and montmorlllonite . . . , . . . . . . . . , , ~, . Hap of Puerto 8ioo showing several annual rainfall belts and the approximate locations fox thc profiles studied. ~ o...

  8. Smectite clay adsorbents of aflatoxin B1 to amend animal feed

    E-Print Network [OSTI]

    Kannewischer, Ines

    2009-05-15T23:59:59.000Z

    SMECTITE CLAY ADSORBENTS OF AFLATOXIN B 1 TO AMEND ANIMAL FEED A Thesis by INES KANNEWISCHER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... Science SMECTITE CLAY ADSORBENTS OF AFLATOXIN B 1 TO AMEND ANIMAL FEED A Thesis by INES KANNEWISCHER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree...

  9. High gradient magnetic separation of iron oxide minerals from soil clays

    E-Print Network [OSTI]

    Schulze, Darrell Gene

    1977-01-01T23:59:59.000Z

    HIGH GRADIENT MAGNETIC SEPARATION OF IRON OXIDE MINERALS FROM SOIL CLAYS A Thesis by DARRELL GENE SCHULZE Submitted to the Graduate College of Texas AIM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1977 Major Subject: Soil Science HIGH GRADIENT MAGNETIC SEPARATION OF IRON OXIDE MINERALS FROM SOIL CLAYS A Thesis DARRELL GENE SCHULZE Approved as to style and content by: (Chairman of C ittee) epartm t) j (Member) (Membe December 1977...

  10. Field versus laboratory characterization of clay deposits for use as in situ municipal landfill liners

    E-Print Network [OSTI]

    Wechsler, Sharon Elizabeth

    1990-01-01T23:59:59.000Z

    FIELD VERSUS LABORATORY CHARACTERIZATION OF CLAY DEPOSITS FOR USE AS IN SITU MUNICIPAL LANDFILL LINERS A Thesis by SHARON ELIZABETH WECHSLER Submitted to the Office of Graduate Studies Texas Aa? University in partial fulfillment... of the requirement for the degree of . KASTER OF SCIENCE Nay 1990 Major Subject: Geology FIELD VERSUS LABORATORY CHARACTERIZATION OF CLAY DEPOSITS FOR USE AS IN SITU MUNICIPAL LANDFILL LINERS A Thesis by SHARON ELIZABETH WECHSLER Approved as to style...

  11. Hydroconversion reactions catalyzed by highly stable pillared clays

    SciTech Connect (OSTI)

    Gomez, S.A.; Mosqueira, L.; Espinosa, J.; Fuentes, G.A. [Universidad A. Metropolitana-Iztapalapa (Mexico)

    1993-12-31T23:59:59.000Z

    Al-pillared clays (Al-PILC) and Al-X-PILC (X = Ga, Ni), structurally stable at high temperature - in the case of Ga above 800{degrees}C-have been synthesized by controlling intercalation steps and stabilization procedures. New bidimensional materials with an interlaminar distance about 10-12{angstrom} and with different chemical reactivities in the pillars have thus been produced. The analytical techniques employed to characterize the materials and the processes involved during stabilization include N{sub 2} adsorption, AA, XRD, NH{sub 3}-TPD, TGA-DTA, HR- and MAS-NMR (Al, Si, and Ga) and in-situ IR and DRIFTS. Chemical characterization using high pressure reactions with probe molecules such as diphenylmethane and tert-butylbenzene shows selectivity patterns than can be clearly associated with the microstructure of the PILC used, as well as an effect due to the composition of the pillars. Similar studies with zeolites give patterns that differ from those of PILC, probably because of the change in dimensionality of the internal structure. Poisoning studies with metal porphyrins prove that PLIC have improved resistance compared to standard catalysts. Hydrotreatment of Maya crude results a significant reduction in total sulfur under conditions suitable for commercial operation.

  12. Hygrothermal performance of an engineered clay barrier during sustained heating

    SciTech Connect (OSTI)

    Selvadurai, A.P.S. [Carleton Univ., Ottawa, Ontario (Canada). Dept. of Civil and Environmental Engineering; Onofrei, C. [AECL Research, Pinawa, Manitoba (Canada). Whiteshell Labs.

    1993-12-31T23:59:59.000Z

    Bentonitic clay buffers, with a potential for swelling, form an integral part of the natural (geological formation)/engineered multi-barrier concepts being proposed for the disposal of heat-generating radioactive nuclear fuel wastes. The integrity of such barriers during thermal loadings is of primary interest to the assessment of their reliability. This paper discusses the results of a series of experiments performed to assess the performance of buffer material under sustained heating. These experiments were conducted in a large-scale granite block facility. The laboratory modeling approximately simulates the local environment that can be encountered in a disposal vault in a granitic rock mass. Experiments in which the power supply to an embedded heater was held constant are described. The temperature distributions within the buffer and the granite block together with the residual moisture content distributions are documented. Also discussed is the application of a computational model of coupled heat and moisture flows. Moisture and heat transfer in the buffer under coupled gradients is described by the Philip-de Vries-type model in which the hygrothermal parameters are determined separately.

  13. Intercalation of a Nonionic Surfactant (C10E3) bilayer into a Na-Montmorillonite Clay

    E-Print Network [OSTI]

    Regis Guegan

    2010-11-27T23:59:59.000Z

    A nonionic surfactant, the tri-ethylene glycol mono n-decyl ether (C10E3), characterized by its lamellar phase state, was introduced in the interlayer of a Na-montmorillonite clay at several concentrations. The synthesized organoclays were characterized by Small Angle X-Ray Scattering in conjunction with Fourier Transform Infrared spectroscopy, and adsorption isotherms. Experiments showed that a bilayer of C10E3 was intercalated into the interlayer space of the naturally exchanged Na-montmorillonite, resulting in the aggregation of the lyotropic liquid crystal state in the lamellar phase. This behavior strongly differs from previous observations of confinement of nonionic surfactants in clays where the expansion of the interlayer space was limited to two monolayers parallel to the silicate surface and cationic surfactants in clays where the intercalation of organic compounds is introduced into the clay galleries through ion exchange. The confinement of a bilayer of C10E3 nonionic surfactant in clays offers new perspectives for the realization of hybrid nanomaterials since the synthesized organoclays preserve the electrostatic characteristics of the clays, thus allowing further ion exchange, while presenting at the same time a hydrophobic surface and a maximum opening of the interlayer space for the adsorption of neutral organic molecules of important size with functional properties.

  14. Dissolution Behaviour of UO{sub 2} in Anoxic Conditions: Comparison of Ca-Bentonite and Boom Clay

    SciTech Connect (OSTI)

    Mennecart, Thierry; Cachoir, Christelle; Lemmens, Karel [SCK-CEN, Boeretang 200, MOL, 2400 (Belgium)

    2007-07-01T23:59:59.000Z

    In order to determine in how far the clay properties influence the dissolution of spent fuel, experiments were carried out with depleted UO{sub 2} in the presence of either compacted dry Ca-bentonite with Boom Clay groundwater (KB-BCW) or compacted dry Boom Clay with Boom Clay groundwater (BC-BCW). The leach tests were performed at 25 deg. C in anoxic atmosphere for 2 years. The U concentrations in the clay water were followed during these 2 years, and the amount of U in the clay was determined after 2 years in order to determine the UO{sub 2} dissolution rate. The uranium concentration after 0.45 {mu}m filtration was 50 times higher in the Boom Clay with Boom Clay water (2.0 x 10{sup -7} mol.L{sup -1}) than in Ca-bentonite with Boom Clay water (6.5 x 10{sup -9} mol.L{sup -1}), probably due to colloid formation in the Boom Clay system. Most released uranium was found in the clay. The fraction of uranium, dissolved from the UO{sub 2} pellet and found on the clay represents about 42 % of total uranium release in the system BC-BCW and more than 76 % in the system KB-BCW. The higher uranium retention of Boom Clay goes together with a higher dissolution rate. Global dissolution rates were estimated at about 2.0 x 10{sup -2} {mu}g.cm{sup -2}.d{sup -1} for the BCBCW system and 3.4 x 10{sup -3} {mu}g.cm{sup -2}.d{sup -1} for the KB-BCW system. This is not much lower than for similar tests with spent fuel, reported in literature. (authors)

  15. Proportions of coarse and fine clay across the Cretaceous-Tertiary boundary in Milam, Falls, and Travis Counties, Texas

    E-Print Network [OSTI]

    Smith, John Charles

    1966-01-01T23:59:59.000Z

    for the investigation Explanation of Proposed Method Location of Clay Units Investigated Previous Investigations Methods of Investigation Eield Investigations Laboratory Investigations Hesults of the lnvcstigation 15 26 Locality I Locality II Locality III... and fine clay expressed as percentages of the total clay i'rection from Locality I . 30 Lattice spacings, mineral composition, indices, and intensities of typical samples from Locality I 33 Proportions for duplicate fractionations of coarse and fine...

  16. Efficiency of clay-TiO2 nanocomposites on the photocatalytic elimination of a model hydrophobic air pollutant

    E-Print Network [OSTI]

    Kibanova, Daria

    2010-01-01T23:59:59.000Z

    of semiconductor photocatalysis Chem. Rev. 1995, 95, 69-effluents by TiO 2 photocatalysis Catalysis Today 2000, 63,clay on adsorption and photocatalysis of gaseous molecules

  17. Reduction And Immobilization Of Hexavalent Chromium By Microbially Reduced Fe-bearing Clay Minerals

    SciTech Connect (OSTI)

    Bishop, Michael E.; Glasser, Paul; Dong, Hailiang; Arey, Bruce W.; Kovarik, Libor

    2014-05-15T23:59:59.000Z

    Hexavalent chromium (Cr6+) is a major contaminant in the environment. As a redox-sensitive element, the fate and toxicity of chromium is controlled by reduction-oxidation (redox) reactions. Previous research has shown the ability of structural Fe(II) in naturally present and chemically reduced clay minerals to reduce Cr6+ to Cr(III) as a way of immobilization and detoxification. However, it is still poorly known whether or not structural Fe(II) in biologically reduced clay minerals exhibits a similar reactivity and if so, what the kinetics and mechanisms of Cr6+ reduction are. The objective of this study was to determine the kinetics and possible mechanisms of Cr6+ reduction by structural Fe(II) in microbially reduced clay minerals and the nature of reduced Cr(III). Structural Fe(III) in nontronite (NAu-2), montmorillonite (SWy-2), chlorite (CCa-2), and clay-rich sediments from the Ringold Formation of the Hanford site of Washington State, USA was first bioreduced to Fe(II) by an iron-reducing bacterium Geobacter sulfurreducens with acetate as the sole electron donor and anthraquinone-2,6-disulfate (AQDS) as electron shuttle in synthetic groundwater (pH 7). Biogenic Fe(II) was then used to reduce aqueous Cr6+ at three different temperatures, 10°, 20°, and 30°C, in order to determine the temperature dependence of the redox reaction between Cr6+ and clay-Fe(II). The results showed that nontronite and montmorillonite were most effective in reducing aqueous Cr6+ at all three temperatures. In contrast, most Fe(II) in chlorite was not reactive towards Cr6+ reduction at 10°C, though at 30°C there was some reduction. For all the clay minerals, the ratio of total Fe(II) oxidized to Cr6+ reduced was close to the expected stoichiometric value of 3. Characterization of the Cr-clay reaction product with scanning electron microscopy with focused ion beam and transmission electron microscopy with electron energy loss spectroscopy revealed that reduced chromium was possibly in the form of sub-nanometer Cr2O3 in association with residual clay minerals as micro-aggregates. This textural association was expected to minimize the chance of Cr(III) reoxidation upon exposure to oxidants. These results are important for our understanding of how various clay minerals may be used to reductively immobilize the heavy metal contaminant Cr in the environment.

  18. Diagenetic clays as pore-lining minerals in coalbed methane reservoirs

    SciTech Connect (OSTI)

    Fowler, K.S.; Nick, K.E. (STIM-LAB, Inc., Duncan, OK (United States))

    1996-01-01T23:59:59.000Z

    Cleat surfaces from Mary Lee and Black Creek coal seams in the Black Warrior Basin and Fruitland coal from the San Juan Basin show significant amounts of diagenetic quartz, illite, kaolinite, carbonate minerals, barite, gypsum and iron sulfides and sulfates. SEM, XRD, thin section and reflected light microscopy analyses were used to identify and describe diagenetic minerals and surface textures observed along permeable cleat surfaces. SEM-EDS analysis reveals a variety of pore-lining diagenetic minerals with complex crystal morphologies in permeable cleats of preserved core and mine samples. Surface textures were varied from smooth and vitreous, dull and pitted, to rough and irregular with imbedded diagenetic minerals, often clays or sulfides. Illite is the most abundant clay and occurs as surface coatings, aggregates, authigenic crystals embedded in the coal surface, or oriented subparallel to the fracture face. Kaolinite is also abundant and occurs as abraded platelets and loosely attached aggregates packed against steps, as meniscus shapes on smooth fracture faces, and as a thick crust of anhedral crystals. Chlorite, the least abundant clay, appears as sheets of small crystals. Locally abundant sulfate, sulfide and carbonate minerals are present in masses of euhedral crystals or concentrated as thick crusts. Surface irregularities sometimes control the distribution of diagenetic minerals. Coal fines of unambiguous internal origin and masses of clays are often concentrated at surface irregularities such as steps, laminations of interbedded clays, or sulfides and coal and rough areas of fractures. Their distribution suggests mobility within fractures.

  19. Diagenetic clays as pore-lining minerals in coalbed methane reservoirs

    SciTech Connect (OSTI)

    Fowler, K.S.; Nick, K.E. [STIM-LAB, Inc., Duncan, OK (United States)

    1996-12-31T23:59:59.000Z

    Cleat surfaces from Mary Lee and Black Creek coal seams in the Black Warrior Basin and Fruitland coal from the San Juan Basin show significant amounts of diagenetic quartz, illite, kaolinite, carbonate minerals, barite, gypsum and iron sulfides and sulfates. SEM, XRD, thin section and reflected light microscopy analyses were used to identify and describe diagenetic minerals and surface textures observed along permeable cleat surfaces. SEM-EDS analysis reveals a variety of pore-lining diagenetic minerals with complex crystal morphologies in permeable cleats of preserved core and mine samples. Surface textures were varied from smooth and vitreous, dull and pitted, to rough and irregular with imbedded diagenetic minerals, often clays or sulfides. Illite is the most abundant clay and occurs as surface coatings, aggregates, authigenic crystals embedded in the coal surface, or oriented subparallel to the fracture face. Kaolinite is also abundant and occurs as abraded platelets and loosely attached aggregates packed against steps, as meniscus shapes on smooth fracture faces, and as a thick crust of anhedral crystals. Chlorite, the least abundant clay, appears as sheets of small crystals. Locally abundant sulfate, sulfide and carbonate minerals are present in masses of euhedral crystals or concentrated as thick crusts. Surface irregularities sometimes control the distribution of diagenetic minerals. Coal fines of unambiguous internal origin and masses of clays are often concentrated at surface irregularities such as steps, laminations of interbedded clays, or sulfides and coal and rough areas of fractures. Their distribution suggests mobility within fractures.

  20. Hydration of Clays at the Molecular Scale: The Promising Perspective of Classical Density Functional Theory

    E-Print Network [OSTI]

    Jeanmairet, Guillaume; Levesque, Maximilien; Rotenberg, Benjamin; Borgis, Daniel

    2014-01-01T23:59:59.000Z

    We report here how the hydration of complex surfaces can be efficiently studied thanks to recent advances in classical molecular density functional theory. This is illustrated on the example of the pyrophylite clay. After presenting the most recent advances, we show that the strength of this implicit method is that (i) it is in quantitative or semi-quantitative agreement with reference all-atoms simulations (molecular dynamics here) for both the solvation structure and energetics, and that (ii) the computational cost is two to three orders of magnitude less than in explicit methods. The method remains imperfect, in that it locally overestimates the polarization of water close to hydrophylic sites of the clay. The high numerical efficiency of the method is illustrated and exploited to carry a systematic study of the electrostatic and van der Waals components of the surface-solvant interactions within the most popular force field for clays, CLAYFF. Hydration structure and energetics are found to weakly depend u...

  1. Solvent and water/surfactant process for removal of bitumen from tar sands contaminated with clay

    SciTech Connect (OSTI)

    Guymon, E.P.

    1990-11-06T23:59:59.000Z

    This patent describes a process for removing bitumen from a tar sand contaminated with clay. It comprises: obtaining a tar sand consisting of bitumen and clay mixed with sand; introducing the tar sand into a stripper vessel; dissolving the bitumen with a solvent, the solvent also removing the clay from the sand into a liquid medium formed with the solvent and bitumen; removing the liquid medium from the sand; and washing the sand with water to which a nonionic surface active agent has been added to remove residual bitumen from the sand, the surfactive agent comprising a linear alcohol having carbon atoms within the range on the order of about eight to fifteen carbon atoms and ethoxylate units on the carbon atoms within the range on the order of about two to eight ethoxylate units, the surfactant being present in the water in an effective amount less than about 0.5 percent by volume.

  2. Dynamics of confined reactive water in Smectic clay-zeolite composites.

    SciTech Connect (OSTI)

    Pitman, Michael C. [IBM Watson Research Center, Yorktown Heights, NY; Van Duin, Adri C. T. [Pennsylvania State University, University Park, PA

    2012-01-01T23:59:59.000Z

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  3. Dynamics of confined reactive water in smectite clay-zeolite composites

    SciTech Connect (OSTI)

    Pitman, Michael C. [IBM Watson Research Center, Yorktown Heights, NY; Van Duin, Adri C. T. [Pennsylvania State University, University Park, PA

    2012-01-01T23:59:59.000Z

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  4. 173. NICKEL SORPTION KINETICS ON THE CLAY FRACTION OF A SOIL. D.R. Roberts and D.L. Sparks, Department of Plant and Soil Sciences, University of Delaware, Newark,

    E-Print Network [OSTI]

    Sparks, Donald L.

    173. NICKEL SORPTION KINETICS ON THE CLAY FRACTION OF A SOIL. D.R. Roberts and D.L. Sparks on the release of Ni(II) from the clay fraction. Ascertaining the kinetics of nickel sorption on clay minerals

  5. Structural, textural and catalytic properties of Al-, Ti-pillared clays

    SciTech Connect (OSTI)

    Ramos-Galvan, C.E.; Dominguez, J.M.; Sandoval-Robles, G.; Castillo-Mares, A.; Nava E, N.

    1996-12-31T23:59:59.000Z

    Al-, Ti- and Zr-pillared clays were characterized and NiMo/Pilc`s were tested in HDS reactions. The combination of activity measurements with Moessbauer Spectroscopy and x-ray microanalysis at microscopical scale give insight in the metal phases migration during pillaring, reaction and regeneration steps. {Alpha}-Fe phase in free Fe{sub 2}O{sub 3} islands predominate together with structural Fe{sup 3+} phase, but during the catalytic reaction Fe{sup 2+} forms. Delamination of the Ti- and Zr-Clay supports, together with high Lewis acidity might enhance their catalytic properties.

  6. 069 MCNITORINGTHE GROWTH OF SEODNDARYPRECIPITATES UPON METALSORPTICN CM CLAY MINERALS AND ALUMINUM OXIDES USING X-RAY ABSORPTICN FINE STRUCIURE (XAFS)

    E-Print Network [OSTI]

    Sparks, Donald L.

    069 MCNITORINGTHE GROWTH OF SEODNDARYPRECIPITATES UPON METALSORPTICN CM CLAY MINERALS AND ALUMINUM and oxide minerals is typically fast initially, then the rates gradually diminish. In the literature on surfaces of clay minerals and aluminum oxides. #12;

  7. Formation of Replicating Saponite from a Gel in the Presence of Oxalate: Implications for the Formation of Clay Minerals in Carbonaceous Chondrites and the Origin of Life

    E-Print Network [OSTI]

    Schumann, Dirk

    The potential role of clay minerals in the abiotic origin of life has been the subject of ongoing debate for the past several decades. At issue are the clay minerals found in a class of meteorites known as carbonaceous ...

  8. Comparing local vs. global visible and near-infrared (VisNIR) diffuse reflectance spectroscopy (DRS) calibrations for the prediction of soil clay, organic C

    E-Print Network [OSTI]

    Lawrence, Rick L.

    ) calibrations for the prediction of soil clay, organic C and inorganic C Joel B. Sankey a, , David J. Brown b,1 samples for VisNIR-DRS predictions of soil clay content (clay), organic carbon content (SOC of Prediction (SEP)= 3.8, 6.7, and 26.2 g kg- 1 ]. This was similarly true for clay (SEP=95.3 and 102.5 g kg- 1

  9. Biogeochemical Processes in a Clay Formation In-situ Experiment: Part B Results from overcoring and evidence of strong buffering by the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2 Biogeochemical Processes in a Clay Formation In-situ Experiment: Part B ­ Results from overcoring in the Opalinus Clay formation was carried out at the Mont Terri underground rock laboratory (Jura Mountains/precipitation reactions. After five years, the 4.5 m long vertical test interval was overcored and Opalinus clay samples

  10. Devineau et al 1 Applied Clay Science, 2006, 31, 76-84 In situ neutron diffraction analysis of the influence of geometric confinement on

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Devineau et al 1 Applied Clay Science, 2006, 31, 76-84 In situ neutron diffraction analysis 2 Applied Clay Science, 2006, 31, 76-84 Abstract The swelling properties of a bentonite MX-80 in constrained pellets deviates from that observed for free pellets. Reorientation phenomena of clay layers were

  11. (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 1996, clays were produced in most States except Alaska, Delaware, Hawaii, Rhode

    E-Print Network [OSTI]

    46 CLAYS (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 1996, clays were produced in most States except Alaska, Delaware, Hawaii, Rhode Island, Vermont. Together, these firms operated about 820 mines. Estimated value of all marketable clay produced was about

  12. Role of Clays in Protecting Adsorbed DNA against X-ray Angela Ciaravella 1 , Flavio Scappini 2 ,Marco Franchi 3 , Cesare Cecchi-Pestellini 4 ,

    E-Print Network [OSTI]

    Micela, Giusi

    Role of Clays in Protecting Adsorbed DNA against X-ray Radiation Angela Ciaravella 1 , Flavio Abstract We studied the e#11;ects of soft X-rays radiation on free and clay (montmorillonite, kaolinite of the DNA molecules. Free and clay adsorbed DNA are di#11;erently a#11;ected by X-rays. The former

  13. (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 1999, clays were produced in most States except Alaska, Delaware, Hawaii,

    E-Print Network [OSTI]

    50 CLAYS (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 1999, clays were produced in most States except Alaska, Delaware, Hawaii, Rhode Island, Vermont, and Wisconsin. A total of 238 companies operated approximately 700 clay pits or quarries. The leading 20 firms

  14. (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 1997, clays were produced in most States except Alaska, Delaware, Hawaii, Rhode

    E-Print Network [OSTI]

    46 CLAYS (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 1997, clays were produced in most States except Alaska, Delaware, Hawaii, Rhode Island, Vermont, these firms operated approximately 739 mines. The estimated value of all marketable clay produced was about $1

  15. Kenneth R. Fleischmann, Clay Templeton, and Jordan Boyd-Graber. Modeling Diverse Standpoints in Text Classification: Learning to Be Human by Modeling Human Values. iConference, 2011.

    E-Print Network [OSTI]

    Boyd-Graber, Jordan

    Kenneth R. Fleischmann, Clay Templeton, and Jordan Boyd-Graber. Modeling Diverse Standpoints{Fleischmann:Templeton:Boyd-Graber-2011, Author = {Kenneth R. Fleischmann and Clay Templeton and Jordan Boyd-Graber}, Booktitle = {i Hornbake Building, South Wing College Park, MD 20742-4345 kfleisch@umd.edu Thomas Clay Templeton University

  16. Kinetics of Ion Exchange on Clay Minerals and Soil: II. Elucidation of Rate-limiting Steps1 R. A. OGWADA ANDD. L. SPARKS2

    E-Print Network [OSTI]

    Sparks, Donald L.

    Kinetics of Ion Exchange on Clay Minerals and Soil: II. Elucidation of Rate-limiting Steps1 R. A of this study was to elucidate the rate- limiting steps for K+ adsorption on the clay minerals and soil. We.L. Sparks. 1986. Kinetics of ion exchange on clay minerals and soil: II. Elucidation of rate-limiting steps

  17. Direct dating of Eocene reverse faulting in northeastern Tibet using Ar-dating of fault clays and low-temperature thermochronometry

    E-Print Network [OSTI]

    Direct dating of Eocene reverse faulting in northeastern Tibet using Ar-dating of fault clays fault of northeastern Tibet by dating several size fractions of fault gouge clay that represent variable Ma and continued until at least Middle Miocene time and that authigenic clay growth occurred

  18. Experimental investigation of the interaction of clays with high pH solutions: A case study from the Callovo-Oxfordian formation, Meuse -Haute Marne

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Experimental investigation of the interaction of clays with high pH solutions: A case study from.2) on the clay mineralogy of the Callovo- Oxfordian formation hosting the French underground laboratory- Oxfordian formation consist of a mixture of three main clay phases: discrete illite, discrete smectite

  19. Coolidge and Overmann The Emergence of Symbolic Thinking 217 2010b). I suggested that the invention of the clay-token system

    E-Print Network [OSTI]

    Nieder, Andreas

    of the clay-token system offered a "material scaffold" able to objectify and simplify the problem of number with numerosity. In other words, the tangible material reality of the clay token--as an "epistemic" artefact device. On this construal, the clay token may well facilitate or provide the stimulus for the ex

  20. Clay Templeton, Kenneth R. Fleischmann, and Jordan Boyd-Graber. Simulating Audiences: Automating Analysis of Values, Attitudes, and Sentiment. IEEE International Conference on Social Computing, 2011.

    E-Print Network [OSTI]

    Boyd-Graber, Jordan

    Clay Templeton, Kenneth R. Fleischmann, and Jordan Boyd-Graber. Simulating Audiences: Automating. @inproceedings{Templeton:Fleischmann:Boyd-Graber-2011, Author = {Clay Templeton and Kenneth R. Fleischmann, and Sentiment}, } 1 #12;Simulating Audiences Automating Analysis of Values, Attitudes, and Sentiment Thomas Clay

  1. (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 2000, clays were produced in all States except Alaska, Delaware, Hawaii, Idaho,

    E-Print Network [OSTI]

    46 CLAYS (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 2000, clays were produced in all States except Alaska, Delaware, Hawaii, Idaho, New Hampshire, Rhode Island, Vermont, and Wisconsin. A total of 233 companies operated approximately 650 clay pits or quarries

  2. The MS-Q Force Field for Clay Minerals: Application to Oil Production Sungu Hwang, Mario Blanco, Ersan Demiralp, Tahir Cagin, and William A. Goddard, III*

    E-Print Network [OSTI]

    Çagin, Tahir

    The MS-Q Force Field for Clay Minerals: Application to Oil Production Sungu Hwang, Mario Blanco inhibitor oil production chemical. 1. Introduction Molecular modeling studies of clay and related zeolite of water, hydrocarbons, and polar organic compounds such as oil field production chemicals on clay mineral

  3. (Data in thousand metric tons unless otherwise noted) Domestic Production and Use: In 2009, clay and shale production was reported in 41 States. About 190 companies

    E-Print Network [OSTI]

    44 CLAYS (Data in thousand metric tons unless otherwise noted) Domestic Production and Use: In 2009, clay and shale production was reported in 41 States. About 190 companies operated approximately 830% drilling mud, 17% foundry sand bond, 14% iron ore pelletizing, and 20% other uses; common clay--57% brick

  4. (Data in thousand metric tons unless otherwise noted) Domestic Production and Use: In 2008, clay and shale production was reported in 41 States. About 190 companies

    E-Print Network [OSTI]

    46 CLAYS (Data in thousand metric tons unless otherwise noted) Domestic Production and Use: In 2008, clay and shale production was reported in 41 States. About 190 companies operated approximately 830% drilling mud, 17% foundry sand bond, 14% iron ore pelletizing, and 20% other uses; common clay--57% brick

  5. Packing and voids in electro-rheological structures of polarized clay particles

    E-Print Network [OSTI]

    K. P. S. Parmar; Y. Meheust; J. O. Fossum; K. D. Knudsen; D. M. Fonseca

    2006-09-19T23:59:59.000Z

    Oil suspensions of fluorohectorite clay particles exhibit a dramatic meso-structural ordering when submitted to a strong electric field. This is due to dipolar interaction between polarized fluorohectorite particles, which orientate and aggregate to form chains and/or bundle-like structures along the direction of the applied electric field. We have used synchrotron small angle X-ray scattering to get insight into the nature of the porous medium in the bundles. Three types of fluorohectorite clay samples corresponding to three different intercalated cations Na+, Ni2+ and Fe3+ were studied. The two-dimensional SAXS images from bundles of fluorohectorites exhibit a marked anisotropy which is analyzed by fitting ellipses to iso-intensity lines of SAXS patterns. This also provides principal directions along which one-dimensional spectra are computed. They display a power law behavior typical of porous media, separated by crossovers. The crossovers are interpreted in terms of typical length scales for the clay particle bundles, providing for the first time a quantitative image of the 3D geometry inside such bundles of polarized clay particles. The exponents of the power laws indicate either predominant surface- (for 2 types of samples) or bulk- (for the last type) scattering, at all length scales investigated.

  6. Preliminary inventory of pre-Cenozoic clay shales and argillites of the conterminous United States

    SciTech Connect (OSTI)

    Connolly, J.R.; Woodward, L.A.

    1980-03-01T23:59:59.000Z

    Cretaceous shales of the Western Interior of the United States occur in vast quantities and in thickness greater than 150 m (500 ft). Some older Mesozoic, Paleozoic, and Precambrian shale and argillites also appear to approach these thicknesses in deposits of considerable lateral extent. These older rocks commonly have a lower proportion of expandable clays and lower water contents.

  7. Engineering Geology 54 (1999) 159165 Mechanical interaction between swelling compacted clay and

    E-Print Network [OSTI]

    Peletier, Mark

    1999-01-01T23:59:59.000Z

    a a EnvirosQuantiSci Ltd., 45 Station Road, Henley-On-Thames RG9 1AT, UK b University of Bath, Bath, UK. We show that such mass loss is limited as a mechanism for leaching away the emplaced barrier, yet may Elsevier Science B.V. All rights reserved. Keywords: Clay barrier; Colloids; Fractured rock; Leaching

  8. Evaluating the Effects of Environmentally Acceptable Clay Stabilizer on Bandera Sandstone

    E-Print Network [OSTI]

    Emecheta, Akunna C

    2013-08-26T23:59:59.000Z

    Fines migration and clay swelling are major problems encountered in sandstone formations in the petroleum industry which leads to a decline in the level of productivity in the reservoirs. Inorganic salts such as KCl, NH_(4)Cl, and NaCl are used...

  9. Influence of an adsorbing polymer in the aging dynamics of Laponite clay suspensions

    E-Print Network [OSTI]

    L. Zulian; B. Ruzicka; G. Ruocco

    2008-11-18T23:59:59.000Z

    Clay-polymer dispersions in aqueous solutions have attracted a great interest in recent years due to their industrial applications and intriguing physical properties. Aqueous solutions of bare Laponite particles are known to age spontaneously from an ergodic state to a non ergodic state in a time varying from hours to months depending on Laponite concentration. When a polymer species like Polyethylene Oxide (PEO) is added to the solution, it weakly adsorbs on clay particle surfaces modifying the effective interaction potential between Laponite particles. A dynamic light scattering study, varying polymer concentration at fixed polymer molecular weight (Mw=200.000 g/mol), has been performed in order to understand the effect of polymer on the aging dynamics of the system. The results obtained show that arresting phenomena between clay particles are hindered if PEO is added and consequently the aging dynamics slows down with increasing PEO concentration. This process is possibly due to the progressive coverage of the clay surface by polymers that grow with increasing PEO concentration and may lead to steric stabilization.

  10. Identification of Pore Structure and Clay Content from Seismic Data within an Argillaceous Sandstone Reservoir

    E-Print Network [OSTI]

    Schelstrate, Robert

    2014-08-11T23:59:59.000Z

    -Mindlin and Sun (HMS) rock physics model to wells logs within the Norne field, offshore Norway. The HMS model provided the ability to correlate clay content with acoustic impedance. A new variable was established that links acoustic impedance to the product...

  11. On the dynamics of subaqueous clay rich gravity mass flows--the giant Storegga slide, Norway

    E-Print Network [OSTI]

    On the dynamics of subaqueous clay rich gravity mass flows--the giant Storegga slide, Norway F, Universitetet i Oslo, Postboks 1047 Blindern, 0316 Oslo, Norway b Norges Geotekniske Institutt, Postboks 3930 Ulleva°l Stadion, 0806 Oslo, Norway c Norsk Hydro ASA, 0246 Oslo, Norway Received 10 November 2003

  12. Permeability of illite-bearing shale: 1. Anisotropy and effects of clay content and loading

    E-Print Network [OSTI]

    Herbert, Bruce

    Permeability of illite-bearing shale: 1. Anisotropy and effects of clay content and loading-rich shale recovered from the Wilcox formation and saturated with 1 M NaCl solution varies from 3 Ã? 10Ã?22 transport; KEYWORDS: permeability, shale, connected pore space Citation: Kwon, O., A. K. Kronenberg, A. F

  13. Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay

    SciTech Connect (OSTI)

    Zheng, L.; Samper, J.; Montenegro, L.; Major, J.C.

    2008-10-15T23:59:59.000Z

    During the construction and operational phases of a high-level radioactive waste (HLW) repository constructed in a clay formation, ventilation of underground drifts will cause desaturation and oxidation of the rock. The Ventilation Experiment (VE) was performed in a 1.3 m diameter unlined horizontal microtunnel on Opalinus clay at Mont Terri underground research laboratory in Switzerland to evaluate the impact of desaturation on rock properties. A multiphase flow and reactive transport model of VE is presented here. The model accounts for liquid, vapor and air flow, evaporation/condensation and multicomponent reactive solute transport with kinetic dissolution of pyrite and siderite and local-equilibrium dissolution/precipitation of calcite, ferrihydrite, dolomite, gypsum and quartz. Model results reproduce measured vapor flow, liquid pressure and hydrochemical data and capture the trends of measured relative humidities, although such data are slightly overestimated near the rock interface due to uncertainties in the turbulence factor. Rock desaturation allows oxygen to diffuse into the rock and triggers pyrite oxidation, dissolution of calcite and siderite, precipitation of ferrihydrite, dolomite and gypsum and cation exchange. pH in the unsaturated rock varies from 7.8 to 8 and is buffered by calcite. Computed changes in the porosity and the permeability of Opalinus clay in the unsaturated zone caused by oxidation and mineral dissolution/precipitation are smaller than 5%. Therefore, rock properties are not expected to be affected significantly by ventilation of underground drifts during construction and operational phases of a HLW repository in clay.

  14. INFLUENCE OF TEMPERATURE ON NICKEL SORPTION ON CLAY MINERAL AND OXIDE SURFACES. K. G. Scheckel1

    E-Print Network [OSTI]

    Sparks, Donald L.

    INFLUENCE OF TEMPERATURE ON NICKEL SORPTION ON CLAY MINERAL AND OXIDE SURFACES. K. G. Scheckel1- ues are within the range of mineral formation which sup- ports previous findings of nickel precipitation on these mineral and oxide surfaces. Conclusions: Sorption of nickel on the mineral phases results

  15. Study on the hydraulic conductivity of Boom clay1 Yong-Feng Deng1, 2

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Study on the hydraulic conductivity of Boom clay1 2 Yong-Feng Deng1, 2 , Anh-Minh Tang2 , Yu Geotechnical Journal 48 (2011) 1461-1470" DOI : 10.1139/T11-048 #12;2 Abstract1 The hydraulic conductivity. Experimental results show that the hydraulic conductivity3 is mainly governed by the soil porosity

  16. Original article Mechanical behaviour of silty clay loam/peat mixtures

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Mechanical behaviour of silty clay loam/peat mixtures: cyclic compression or amended with 20 or 40 % by volume of spagh- num peat, were studied at different values of water contentPa is increased to about 55 and 115 % for 20 and 40 % peat contents, respectively. A comparison of the cyclic test

  17. Radiation Sensitivity of Natural Organic Matter: Clay Mineral Association Effects in the Callovo-Oxfordian Argillite

    SciTech Connect (OSTI)

    Schäfer, T.; Michel, P; Claret, F; Beetz, T; Wirick, S; Jacobsen, C

    2009-01-01T23:59:59.000Z

    Clay-rich low-organic carbon formations (e.g., Callovo-Oxfordian argillite in France and Opalinus Clay in Switzerland) are considered as host rocks for radioactive waste disposal. The clay-organic carbon has a strong impact on the chemical stability of the clays. For this reason, the nature of the clay-organic carbon, the release of hydrophilic organic compounds, namely, humic (HA) and fulvic acids (FA) and the radiation sensitivity of the undisturbed host rock organics was investigated. The clay sample originates from Oxfordian argillite (447 m depth, borehole EST 104). HA and FA were extracted following the standard International Humic Substance Society (IHSS) isolation procedure. Synchrotron based (C-, K-, Ca-, O- and Fe-edge XANES) scanning transmission X-ray microscopy (STXM) and FT-IR microspectroscopy was used to identify under high spatial resolution the distribution of clay-organic matter with different functionality using principal component and cluster analysis. The results show that in this old (Jurassic) geological formation, small parts of the organic inventory (1-5%) keeps the structure/functionality and can be mobilized as hydrophilic humic substance type material (HA and FA). Target spectra analysis shows best correlation for isolated humic acids with organics found in smectite-rich regions, whereas the extractable FA has better spectral similarities with the illite mixed layer minerals (MLM) regions. After radiation of 1.7 GGy under helium atmosphere the same rock sample area was investigated for radiation damage. Radiation damage in the smectite and illite-MLM associated organic matter is comparably low with 20-30% total oxygen mass loss and 13-18% total carbon mass loss. A critical dose dc of 2.5 GGy and a optical density after infinite radiation (OD?) of 54% was calculated under room temperature conditions. C(1s) XANES show a clear increase in Cdouble bond; length as m-dashC bonds especially in the illite-MLM associated organics. This results suggests a combination of the formation of Cdouble bond; length as m-dashC bond due to crosslinking via polymerization and mass loss due to bond breaking (scissioning) in the main chain or in side groups of the organic macromolecules upon irradiation.

  18. Bioreduction of Fe-bearing clay minerals and their reactivity toward pertechnetate (Tc-99)

    SciTech Connect (OSTI)

    Bishop, Michael E.; Dong, Hailiang; Kukkadapu, Ravi K.; Liu, Chongxuan; Edelmann, Richard E.

    2011-07-01T23:59:59.000Z

    99Technetium (99Tc) is a fission product of uranium-235 and plutonium-239 and poses a high environmental hazard due to its long half-life (t1/2 = 2.13 x 105 y), abundance in nuclear wastes, and environmental mobility under oxidizing conditions [i.e., Tc(VII)]. Under reducing conditions, Tc(VII) can be reduced to insoluble Tc(IV). Ferrous iron [Fe(II)], either in aqueous form or in mineral form, has been used to reduce Tc(VII) to Tc(IV). However, the reactivity of Fe(II) from clay minerals, other than nontronite, toward immobilization of Tc(VII) and its role in retention of reduced Tc(IV) have not been investigated. In this study the reactivity of a suite of clay minerals toward Tc(VII) reduction and immobilization was evaluated. The clay minerals chosen for this study included five members in the smectite-illite (S-I) series, (montmorillonite, nontronite, rectorite, mixed layered I-S, and illite), chlorite, and palygorskite. Fe-oxides were removed from these minerals with a modified dithionite-citrate-bicarbonate (DCB) procedure. The total Fe content of these clay minerals, after Fe-oxide removal, ranged from 0.7 to 30.4% by weight, and the Fe(III)/Fe(total) ratio ranged from 44.9 to 98.5%. X-ray diffraction (XRD) and Mössbauer spectroscopy results showed that after Fe oxide removal the clay minerals were free of Fe-oxides. Scanning electron microscopy (SEM) revealed that little dissolution occurred during the DCB treatment. Bioreduction experiments were performed in bicarbonate buffer (pH-7) with Fe(III) in the clay minerals as the sole electron acceptor, lactate as the sole electron donor, and Shewanella Putrifaciens CN32 cells as mediators. In select tubes, anthraquinone-2,6-disulfate (AQDS) was added as electron shuttle to facilitate electron transfer. The extent of Fe(III) bioreduction was the highest for chlorite (~43 wt%) and the lowest for palygorskite (~4.17 wt%). In the S-I series, NAu-2 was the most reducible (~31 %) and illite the least (~0.4 %). The extent and initial rate of bioreduction were positively correlated with the percent smectite in the S-I series (i.e., layer expandability). Fe(II) in the bioreduced clay minerals subsequently was used to reduce Tc(VII) to Tc(IV) in PIPES buffer. Similar to the trend of bioreduction, in the S-I series, reduced smectite showed the highest reactivity toward Tc(VII), and reduced illite exhibited the least. The initial rate of Tc(VII) reduction, after normalization to clay and Fe(II) concentrations, was positively correlated with the percent smectite in the S-I series. Fe(II) in chlorite and palygorskite was also reactive toward Tc(VII) reduction. These data demonstrate that crystal chemical parameters (layer expandability, Fe and Fe(II) contents, and surface area etc.) play important roles in controlling the extent and rate of bioreduction and the reactivity toward Tc(VII) reduction. Reduced Tc(IV) resides within clay mineral matrix, and this association could minimize any potential of reoxidation over long term.

  19. A new class of non-zeolitic sorbents for air separations: Lithium ion exchanged pillared clays

    SciTech Connect (OSTI)

    Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States). Dept. of Chemical Engineering

    1995-06-01T23:59:59.000Z

    Zeolites are the only known sorbents that adsorb N{sub 2} selectively over O{sub 2}, and are used for industrial air separation. Pillared clays (PILCs) have a high Broensted acidity (k.e., high proton density). It is found in this study that when the protons are exchanged by alkali metal ions, in particular Li{sup +}, the ion exchanged pillared clays can exhibit a high N{sub 2}/O{sub 2} adsorption selectivity that rivals that of the zeolites. The first result shows a pure-component adsorption ratio of N{sub 2}/O{sub 2} = 3.2 (at 25 C and 1 atm) for Li{sup +}-exchanged PILC. The N{sub 2} capacity, however, is only 20% that of the zeolite, and remains to be improved. A systematic investigation is conducted on the effects of three factors on the N{sub 2}/O{sub 2} selectivity: (1) starting clays (tetrahedral vs octahedral isomorphous substitution and clays with different charge densities), (2) different metal oxides as pillars, and (3) different ion exchange alkali metal cations (Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, and Cs{sup +}). The highest N{sub 2}/O{sub 2} selectivities are achieved by using clays with the highest charge densities, metal oxides forming pillars with the narrowest gallery spaces, and ion exchange cations with the smallest ionic radii. Effects by all three factors are qualitatively understood. The high N{sub 2}/O{sub 2} selectivity on the Li{sup +} exchanged PILC is the result of the small ionic radius (and hence high polarizing power) of Li{sup +} and the strong quadrupole moment of the N{sub 2} molecule. Moreover, a technique is developed with which the amount of the exchanged cations can exceed that allowed by the original cation exchange capacity of the clay by using a high pH value in the ion exchange solution.

  20. Cancer Therapies: A Bane and a Boon

    E-Print Network [OSTI]

    Neogi, Sushrita

    2012-01-01T23:59:59.000Z

    Alternative Medicine in Cancer Treatment. (2012). Retrievedcancertopics/pdq/cam/cam-cancer-treatment/patient/page2 8.and alternative (CAM) cancer treatments in use, including

  1. Cancer Therapies: A Bane and a Boon

    E-Print Network [OSTI]

    Neogi, Sushrita

    2012-01-01T23:59:59.000Z

    on the surgical decision-making process for breast cancer.Cancer, 112(3), 489-494. 2. Grealy, Lucy (1994).Mifflin. 3. He, Lin (2011). Cancer Therapy. [PowerPoint

  2. Boone Electric Coop | Open Energy Information

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  15. BooNE: Booster Neutrino Experiment

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  1. BooNE: Booster Neutrino Experiment

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  2. Boone Valley Electric Coop | Open Energy Information

    Open Energy Info (EERE)

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  4. Detailed mineralogical characterization of the Bullfrog and Tram members USW-G1, with emphasis on clay mineralogy

    SciTech Connect (OSTI)

    Bish, D.L.

    1981-10-01T23:59:59.000Z

    The detailed mineralogy of the Bullfrog and Tram Members of the Crater Flat Tuff from drill hole USW-G1 has been examined, primarily to characterize fully the amounts and types of clay minerals in the tuffs and the possible effects clay minerals have on rock properties. Results of bulk sample x-ray diffraction analyses agree closely with previous determinations, although slightly higher clay mineral contents were found in this study. X-ray diffraction analysis of fine fractions revealed that the clay minerals in the tuffs are sodium-saturated montmorillonite-beidellites with typical layer charges and no high-charge layers. These smectites are found in virtually all samples of the Bullfrog and Tram, and there is no correlation between the amounts of smectites and the amounts of zeolite, quartz, and feldspar. Smectites are present in both welded and nonwelded horizons and are scarce in some zones with slight-to-absent welding.

  5. Investigations of Near-Field Thermal-Hydrologic-Mechanical-Chemical Models for Radioactive Waste Disposal in Clay/Shale Rock

    SciTech Connect (OSTI)

    Liu, H.H.; Li, L.; Zheng, L.; Houseworth, J.E.; Rutqvist, J.

    2011-06-20T23:59:59.000Z

    Clay/shale has been considered as potential host rock for geological disposal of high-level radioactive waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus Clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at the Mol site, Belgium (Barnichon and Volckaert, 2003) have all been under intensive scientific investigation (at both field and laboratory scales) for understanding a variety of rock properties and their relationships to flow and transport processes associated with geological disposal of radioactive waste. Figure 1-1 presents the distribution of clay/shale formations within the USA.

  6. Micromorphology and Stable Isotope Geochemistry of Historical Pedogenic Siderite Formed in PAH-Contaminated Alluvial Clay Soils, Tennessee, USA

    E-Print Network [OSTI]

    Driese, S.G.; Ludvigson, Greg A.; Roberts, Jennifer A.; Fowle, David A.; Gonzalez, Luis A.; Smith, Jon Jay; Vulava, V.M.; McKay, L.D.

    2010-11-01T23:59:59.000Z

    Alluvial clay soil samples from six boreholes advanced to depths of 400–450 cm (top of limestone bedrock) from the Chattanooga Coke Plant (CCP) site were examined micromorphologically and geochemically in order to determine if pedogenic siderite (Fe...

  7. Molecular dynamics simulation of complex molecules at interfaces: dendritic surfactants in clay and amyloid peptides near lipid bilayers

    E-Print Network [OSTI]

    Han, Kunwoo

    2009-06-02T23:59:59.000Z

    We apply a molecular dynamics (MD) simulation technique to complex molecules at interfaces. Partitioning of dendritic surfactants into clay gallery and Ab protein behavior near hydrated lipids are chosen for the purpose. Using a full atomistic model...

  8. Long-term modeling of glass waste in portland cement- and clay-based matrices

    SciTech Connect (OSTI)

    Stockman, H.W.; Nagy, K.L. [Sandia National Labs., Albuquerque, NM (United States); Morris, C.E. [Wollongong Univ., NSW (Australia). Dept. of Civil and Mining Engineering

    1995-12-01T23:59:59.000Z

    A set of ``templates`` was developed for modeling waste glass interactions with cement-based and clay-based matrices. The templates consist of a modified thermodynamic database, and input files for the EQ3/6 reaction path code, containing embedded rate models and compositions for waste glass, cement, and several pozzolanic materials. Significant modifications were made in the thermodynamic data for Th, Pb, Ra, Ba, cement phases, and aqueous silica species. It was found that the cement-containing matrices could increase glass corrosion rates by several orders of magnitude (over matrixless or clay matrix systems), but they also offered the lowest overall solubility for Pb, Ra, Th and U. Addition of pozzolans to cement decreased calculated glass corrosion rates by up to a factor of 30. It is shown that with current modeling capabilities, the ``affinity effect`` cannot be trusted to passivate glass if nuclei are available for precipitation of secondary phases that reduce silica activity.

  9. Comparative studies of mycotoxin adsorption activities by clays and zeolitic minerals

    E-Print Network [OSTI]

    Green, Justin Lane

    1984-01-01T23:59:59.000Z

    II 3 CH&- C-S-CoA CH3 Malonyl-CoA CH3 I 0 0 0 0 ~ ~COOH II II II II CH3 ? C-CH2-C-CH2-C-CH3-C-S-CoA ~ Hp OH Orsellinic Acid CH3 I ~ ~QH p S-adenosyl Methionine Hp + OCH3 H3C OCH3 I Np OCH3 I 0~ H3C ) Q OCH3 I Hp wp H C 3... processing. A variety of clays and zeolitic minerals were tested for their capacity to bind patulin, penicillic acid, ochratoxin A, deoxy- nivalenol and [1- C] deoxynivalenol. Toxin/clay solutions were analyzed in vitro via HPLC using a reverse phase...

  10. Preliminary design of drilled shafts in clay for supporting precast panel retaining walls

    E-Print Network [OSTI]

    Holloway, George Leon

    1978-01-01T23:59:59.000Z

    subjected to large lateral loads. The measurement system used to measure soil pressure consisted of a series of pressure cells placed vertically along the shaft. A load cell instrumented with strain gages was used to measure the lateral load applied... Leon Holloway, B. S. , Texas A&M University Chairman of Advisory Committee: Dr. Harry M. Coyle The behavior of a laterally loaded drilled shaft in clay has been investigated by conducting a second lateral load test on an instrumented shaft. For each...

  11. Compositional characteristics of the Fire Clay coal bed in a portion of eastern Kentucky

    SciTech Connect (OSTI)

    Hower, J.C.; Andrews, W.M. Jr.; Rimmer, S.M. (Univ. of Kentucky, Lexington (United States)); Eble, C.F. (Kentucky Geological Survey, Lexington (United States))

    1991-08-01T23:59:59.000Z

    The Fire Clay (Hazard No. 4) coal bed (Middle Pennsylvanian Breathitt Formation) is one of the most extensively mined coal in eastern Kentucky. The coal is used for metallurgical and steam end uses and, with its low sulfur content, should continue to be a prime steam coal. This study focuses on the petrology, mineralogy, ash geochemistry, and palynology of the coal in an eight 7.5-min quadrangle area of Leslie, Perry, Knott, and Letcher counties.

  12. Geology and kinematics of a clay-rich landslide with an undulatory slip surface

    E-Print Network [OSTI]

    Lantz, James Robert

    1984-01-01T23:59:59.000Z

    in thickness from 1 to 3 meters, and exhibits an i. rregular channel geometry, largely controlled by bedrock inhomogeneity in a structurally complex Franciscan terrain (highly deformed clay- shale). In map view, the landslide has an "hourglass" configuration... internal deformation. Maximum slide mass thicken- ing of 30-40y is associated with the basal step. Lithologic variations within the slide mass (i. e. erratic distribution of a sandy gravel unit) do not affect the steady-state profile, which is largely...

  13. On grouting using a suspension of ultrafine clay on artificially cracked rock samples

    SciTech Connect (OSTI)

    Ito, Y.; Sakaguchi, T.; Nishiyama, K. [Kumagai Gumi Co., Ltd., Tokyo (Japan). Nuclear and Energy Dept.; Fujiwara, A. [Radioactive Waste Management Center, Tokyo (Japan). Second Research Div.

    1993-12-31T23:59:59.000Z

    Recently there has been increasing social interest in the effective disposal of low-level radioactive wastes. The use of underground rock caverns is considered as a possible repository space. This paper presents a new grouting method which uses a suspension of liquefied ultrafine clay in fractured rock masses. In order to demonstrate the effect to block open cracks, two experiments were carried out on large-sized granite samples with open cracks. The experiments proved the method to be highly effective.

  14. Authigenic clay minerals in sandstones of the Delaware Mountain Group: Bell Canyon and Cherry Canyon Formations, Waha Field, West Texas

    E-Print Network [OSTI]

    Walling, Suzette Denise

    1992-01-01T23:59:59.000Z

    AUTHIGENIC CLAY MINERALS IN SANDSTONES OF THE DELAWARE MOUNTAIN GROUP: BELL CANYON AND CHERRY CANYON FORMATIONS, WAHA FIELD, WEST TEXAS A Thesis by SUZETTE DENISE WALLING Submitted to the Office of Graduate Studies of Texas A&M University... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1992 Major Subject: Geology AUTHIGENIC CLAY MINERALS IN SANDSTONES OF THE DELAWARE MOUNTAIN GROUP: BELL CANYON AND CHERRY CANYON FORMATIONS, WAHA FIELD, WEST TEXAS...

  15. Variations in clay mineralogy and sediment texture of salt marsh soils on the Eastern Shore of Virginia

    SciTech Connect (OSTI)

    Robinson, S.E.; Furman, T. (Univ. of Virginia, Charlottesville, VA (United States). Dept. of Environmental Sciences)

    1993-03-01T23:59:59.000Z

    On the Eastern Shore of VA, relative sea level rise has resulted in encroachment of marsh onto upland areas. The amount and type of sediment determines the morphologic environment of the system: lagoon, mudflat, low marsh, high marsh or upland. This research is part of a study to examine the relationship between marsh soil characteristics and the production of Spartina alterniflora. The productivity of marsh vegetation depends on the import and entrapment of sediments that maintain marsh elevation and control water and nutrient availability. This work focused on distribution patterns of sediment texture and mineralogy. One meter deep cores were taken at marsh sites with 10 cm intervals homogenized for analysis. In order to distinguish potential sediment sources, samples were also taken from upland soil pits on the mainland and dredged one-half mile seaward of the barrier islands. Samples have undergone size analysis with a hydrometer and the clay fraction has been analyzed by XRD. Results from the marsh surface indicate large variations in sediment texture, but only slight differences in clay mineralogy between marshes. Barrier island marshes contain a higher average sand content than mainland marshes because of their closer proximity to barrier island beaches and inputs from overwash deposits. The clay minerals found in all marsh surface deposits are illite and chlorite, indicative of oceanic clays. The clay mineralogy of upland soils (kaolinite, chlorite, illite, vermiculite mixed-layer clay) differs from marsh surface clays, indicating that recent sediment deposited on the marsh surface is no upland soil but rather material brought in through tidal inlets. The sediment texture and clay mineralogy at different depths varies as a function of the past geomorphic and depositional history of the site. These data will be used to determine the timing of marsh development on flooded upland sites and to determine the pre-Holocene source of inorganic sediment inputs.

  16. A study of the effects of repeated loadings and free water on the stability of a lime stabilized clay 

    E-Print Network [OSTI]

    Jantos, Carl Thomas

    1959-01-01T23:59:59.000Z

    . Sere Percent Lime (Raw Soil) Triaxial Results . 9, Twe Percent Lime Triaxial Results . 10. Four Percent Lime Triaxial Results 37 37 40 LIST OF FIGURES 1. Triaxial Compression Device and Universal Testing Nachine . 2. Harvard Nlniature Compactor... Equipment 3. Typical Test Speoimens 4. Ltterberg Limits - Brasos River Clay 5. Modified JULS80 Compaction - Brasos River Clay 6. Nohr's Circles and Rupture Envelopes 7, 0 Percent Lime (Raw Soil) Triaxial Test, 15 psi 45 47 48 Lateral Pressure 49 S...

  17. Sub-THz complex dielectric constants of montmorillionite clay thin samples with Na$^{+}$/Ca$^{++}$-ions

    E-Print Network [OSTI]

    Rezwanur Rahman; Douglas K. McCarty; Manika Prasad; John A. Scales

    2015-02-13T23:59:59.000Z

    We implement a technique to characterize electromagnetic properties at frequencies 100 to 165 GHz (3 cm$^{-1}$ to 4.95 cm$^{-1}$) of oriented montmorillionite samples using an open cavity resonator connected to a sub-millimeter wave VNA (Vector Network Analyzer). We measured dielectric constants perpendicular to the bedding plane on oriented Na$^{+}$ and Ca$^{++}$-ion stabilized montmorillionite samples deposited on a glass slide at ambient laboratory conditions (room temperature and room light). The clay layer is much thinner ($\\sim$ 30 $\\mu$m) than the glass substrate ($\\sim$ 2.18 mm). The real part of dielectric constant,$\\epsilon_{re}$, is essentially constant over this frequency range but is larger in Na$^{+}$- than in Ca$^{++}$-ioned clay. The total electrical conductivity (associated with the imaginary part of dielectric constant, $\\epsilon_{im}$) of both samples increases monotonically at lower frequencies ($$ 110 GHz. The dispersion of the samples display a dependence on the ionic strength in the clay interlayers, i.e., $\\zeta$-potential in the Stern layers.

  18. The relation of diagenetic clays and sulfates to the treatment of coalbed methane reservoirs

    SciTech Connect (OSTI)

    Nick, K.E.; Conway, M.W.; Fowler, K.S.

    1995-12-31T23:59:59.000Z

    Field procedures and laboratory experiments to stimulate production from coalbed methane reservoirs have largely been designed from experience with fractured reservoirs and coal geochemistry. This paper describes experiments to investigate the occurrence of cements in the permeability pathways in coal samples from mines and cores and how these diagenetic materials interact with completion and stimulation fluids based on core flow tests. Core flow testing of coals generally suggests damage by polymers and stimulation by several acids. Examination of cleat surfaces from the Mary Lee and Black Creek coal seams in the Black Warrior Basin and Fruitland coal from the San Juan Basin by light microscopy, SEM and XRD analyses show the presence of carbonate, quartz and iron sulfide cements in impermeable cleats and quartz, illite, kaolinite, barite, gypsum, and iron sulfates in permeable fractures. Fracture morphology is also complex with W branching shapes and surface textures. Illite is typically the most abundant clay and is also interlaminated with or interspersed in the coal. Kaolinite is most likely to migrate and its occurrence in meniscus forms and packed against steps in the cleats document mobility. Coal fines are also present in the cleats, concentrated with clays at steps and bends in the cleats. Injection of fluorescin tagged guar through coal plugs demonstrated the polymer`s affinity for clay and identified permeability pathways in coal.

  19. Clay formation and metal fixation during weathering of coal fly ash

    SciTech Connect (OSTI)

    Zevenbergen, C.; Bradley, J.P.; Reeuwijk, L.P. Van; Shyam, A.K.; Hjelmar, O.; Comans, R.N.J.

    1999-10-01T23:59:59.000Z

    The enormous and worldwide production of coal fly ash cannot be durably isolated from the weathering cycle, and the weathering characteristics of fly ash must be known to understand the long-term environmental impact. The authors studied the weathering of two coal fly ashes and compared them with published data from weathered volcanic ash, it's closest natural analogue. Both types of ash contain abundant aluminosilicate glass, which alters to noncrystalline clay. However, this study reveals that the kinetics of coal fly ash weathering are more rapid than those of volcanic ash because the higher pH of fresh coal fly ash promotes rapid dissolution of the glass. After about 10 years of weathering, the noncrystalline clay content of coal fly ash is higher than that of 250-year-old volcanic ash. The observed rapid clay formation together with heavy metal fixation imply that the long-term environmental impact of coal fly ash disposal may be less severe and the benefits more pronounced than predicted from previous studies on unweathered ash. Their findings suggest that isolating coal fly ash from the weathering cycle may be counterproductive because, in the long-term under conditions of free drainage, fly ash is converted into fertile soil capable of supporting agriculture.

  20. Preparation of anionic clay-birnessite manganese oxide composites by interlayer oxidation of oxalate ions by permanganate

    SciTech Connect (OSTI)

    Arulraj, James [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)] [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India); Rajamathi, Michael, E-mail: mikerajamathi@rediffmail.com [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)] [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)

    2013-02-15T23:59:59.000Z

    Oxalate intercalated anionic clay-like nickel zinc hydroxysalt was obtained starting from nickel zinc hydroxyacetate, Ni{sub 3}Zn{sub 2}(OH){sub 8}(OAc){sub 2}{center_dot}2H{sub 2}O, by anion exchange. The intercalated oxalate species was reacted with potassium permanganate in such a way that the layered manganese oxide formed was within the interlayer region of the anionic clay resulting in a layered composite in which the negative charges on the birnessite type manganese oxide layers compensate the positive charges on the anionic clay layers. Birnessite to anionic clay ratio could be varied by varying the reaction time or the amount of potassium permanganate used. - Graphical abstract: Nickel zinc hydroxyoxalate was reacted with potassium permanganate to get nickel zinc hydroxide birnessite composites in which the positive charges on the hydroxide layers are neutralized by the negative charges on birnessite layers. Highlights: Black-Right-Pointing-Pointer Anionic and cationic layered solid composites prepared. Black-Right-Pointing-Pointer Ni-Zn hydroxyoxalate reacted with KMnO{sub 4} to deposit MnO{sub 2} in the interlayer. Black-Right-Pointing-Pointer Birnessite layers coexist with anionic clay layers in the composites. Black-Right-Pointing-Pointer Birnessite/anionic clay ratio controlled by amount of KMnO{sub 4} used and reaction time.

  1. Remediation of a fractured clay soil contaminated with gasoline containing MTBE

    SciTech Connect (OSTI)

    Johnson, R.L.; Grady, D.E. [Oregon Graduate Institute, Portland, OR (United States); Walden, T. [BP Oil Europe, Brussels (Belgium)

    1997-12-31T23:59:59.000Z

    Gasoline and other light non-aqueous phase liquids (LNAPLs) released into fractured clay soils initially move by advection of the LNAPL through the fractures. Once advective movement of the LNAPL ceases, dissolution of the gasoline components into the pore water and diffusion into the intact blocks of clay becomes an important transport process. The aqueous-phase flux of each compound in the mixture depends in large part upon its aqueous solubility. For example, a low-solubility compound like isooctane remains primarily in the fracture in the LNAPL. A high-solubility compound, like methyl-tert-butyl ether (MTBE), dissolves readily and may move almost entirely into the clay matrix. The distribution of compounds between the matrix and the fractures will have an important impact on the rate at which the gasoline contaminated soil can be remediated. In this context, the presence of soluble additives like MTBE can significantly impact the risk and remediation time for the, soil. Beginning in 1993 a field study to examine the applicability of air flushing for remediation of low-permeability soils was sponsored by API. The study focused on a variety of soil vapor extraction (SVE) and in situ air sparging (IAS) approaches for mass removal and risk reduction. The source of gasoline contamination in this study was a release of 50 liters of a mixture containing 14 gasoline hydrocarbons ranging from pentane to naphthalene, and including MTBE. The mixture was released into the shallow subsurface and allowed to redistribute for 10 months prior to air flushing startup. Numerical modeling indicated that essentially all of the MTBE should have dissolved into the matrix. In contrast, essentially all of the isooctane should have remained in the LNAPL in the fractures.

  2. Laboratory measurements of contaminant attenuation of uranium mill tailings leachates by sediments and clay liners

    SciTech Connect (OSTI)

    Serne, R.J.; Peterson, S.R.; Gee, G.W.

    1983-04-01T23:59:59.000Z

    We discuss FY82 progress on the development of laboratory tools to aid in the prediction of migration potential of contaminants present in acidic uranium mill tailings leachate. Further, empirical data on trace metal and radionuclide migration through a clay liner are presented. Acidic uranium mill tailings solution from a Wyoming mill was percolated through a composite sediment called Morton Ranch Clay liner. These laboratory columns and subsequent sediment extraction data show: (1) As, Cr, Pb, Ag, Th and V migrate very slowly; (2) U, Cd, Ni, Zn, Fe, Mn and similar transition metals are initially immobilized during acid neutralization but later are remobilized as the tailings solution exhausts the clay liner's acid buffering capacity. Such metals remain immobilized as long as the effluent pH remains above a pH value of 4 to 4.5, but they become mobile once the effluent pH drops below this range; and (3) fractions of the Se and Mo present in the influent tailings solution are very mobile. Possible controlling mechanisms for the pH-dependent immobilization-mobilization of the trace metals are discussed. More study is required to understand the controlling mechanisms for Se and Mo and Ra for which data were not successfully collected. Using several column lengths (from 4.5 to 65 cm) and pore volume residence times (from 0.8 to 40 days) we found no significant differences in contaminant migration rates or types and extent of controlling processes. Thus, we conclude that the laboratory results may be capable of extrapolation to actual disposal site conditions.

  3. Pillared clays as superior catalysts for selective catalytic reduction of nitric oxide. Second semiannual report, 1996

    SciTech Connect (OSTI)

    Yang, R.T.; Li, W.B.; Sirilumpen, M.; Tharapiwattananon, N.

    1997-08-01T23:59:59.000Z

    During the first six months of the program, the work has progressed as planned. We have constructed a reactor system and assembled all laboratory essentials for conducting the three-year project. First, the catalytic activities of the Cu(2+) ion exchanged alumina-pillared clay for the selective catalytic reduction of NO by ethylene were measured. The temperature range was 250-500{degrees}C. The activities of this catalyst were substantially higher than the catalyst that has been extensively studied in the literature, Cu-ZSM-5. Fourier Transform Infrared Spectroscopy (FTIR) was used to study the acidity of the catalyst. The second part of the work was an in-depth FTIR study of the NO decomposition mechanism on the catalyst. This was planned as the first and the key step to obtain an understanding of the reaction mechanism. Key surface intermediates were identified from the FTIR spectra, and a redox type Eley-Rideal mechanism was proposed for the NO decomposition on this catalyst. This report will be divided into two parts. In Part One, we report results on the catalytic activities of the Cu-alumina-pillared clay and a direct comparison with other known catalysts. In Part two, we focus on the FTIR study and from the results, we propose a NO decomposition mechanism on this new catalyst. Plans for the next six months include tests of different pillared clays as well as the catalytic mechanism. The micro reactor will continue to be the key equipment for measuring the catalytic activities. FTIR will continue to be the major technique for identifying surface species and hence understanding the reaction mechanism.

  4. CO2 Sorption to Subsingle Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction Measurements

    SciTech Connect (OSTI)

    Rother, Gernot; Ilton, Eugene S.; Wallacher, Dirk; Hauss, Thomas; Schaef, Herbert T.; Qafoku, Odeta; Rosso, Kevin M.; Felmy, Andrew R.; Krukowski, Elizabeth; Stack, Andrew G.; Grimm, Nico; Bodnar, Robert J.

    2013-01-15T23:59:59.000Z

    Geologic storage of CO2 requires that the caprock sealing the storage rock is highly impermeable by CO2. Swelling clays, which are important components of caprocks, may interact with CO2 under volume change, potentially impacting the seal quality. The interactions of scCO2 with Na saturated montmorillonite clay containing a sub-single layer of water in the interlayer region have been studied by sorption and neutron diffraction techniques. The excess sorption isotherms show maxima at bulk CO2 densities of ??0.15 g/cm3, followed by an approximately linear decrease of excess sorption to zero and negative values with increasing CO2 bulk density. Neutron diffraction experiments on the same clay sample measured interlayer spacing and composition. The results show that limited amounts of CO2 are sorbed into the interlayer region, leading to depression of the interlayer peak intensity and an increase of the d(001) spacing by ca. 0.5 Å. The density of CO2 in the clay pores is relatively stable over a wide range of CO2 pressures at a given temperature, indicating the formation of a clay-CO2 phase. At the excess sorption maximum, increasing CO2 sorption with decreasing temperature is observed while the high-pressure sorption properties exhibit weak temperature dependence.

  5. CO2 Adsorption to Sub-Single Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction

    SciTech Connect (OSTI)

    Rother, Gernot [ORNL; Ilton, Eugene [Pacific Northwest National Laboratory (PNNL); Wallacher, Dirk [Helmholtz-Zentrum Berlin; Hauss, Thomas [Helmholtz-Zentrum Berlin; Schaef, Herbert [Pacific Northwest National Laboratory (PNNL); Qafoku, Odeta [Pacific Northwest National Laboratory (PNNL); Rosso, Kevin M. [Pacific Northwest National Laboratory (PNNL); Felmy, Andrew [Pacific Northwest National Laboratory (PNNL); Krukowski, Elizabeth G [ORNL; Stack, Andrew G [ORNL; Bodnar, Robert J [ORNL

    2013-01-01T23:59:59.000Z

    Geologic storage of CO2 requires that the caprock sealing the storage rock is highly impermeable by CO2. Swelling clays, which are important components of caprocks, may react with CO2 under volume change, potentially impacting the seal quality. The interactions of scCO2 with Na saturated montmorillonite clay containing a sub-single layer of water in the interlayer region have been studied by sorption and neutron diffraction techniques. The excess sorption isotherms show maxima at bulk CO2 densities of 0.15 g/cm3, followed by an approximately linear decrease of excess sorption to zero and negative values with increasing CO2 bulk density. Neutron diffraction experiments on the same clay sample measured interlayer spacing and composition. The results show that limited amounts of CO2 are sorbed into the interlayer region, leading to depression of the interlayer peak intensity and an increase of the d(001) spacing by ca. 0.5 . The density of CO2 in the clay pores is relatively stable over a wide range of CO2 pressures at a given temperature, indicating the formation of a clay-CO2 phase. At low pressure increasing CO2 adsorption with decreasing temperature is observed while the high-pressure sorption properties exhibit weak or no temperature dependence. Supercritical fluids, sorption phenomena, carbon dioxide, carbon sequestration, caprock integrity

  6. Experimental Test of the validity of "Isotropic" Approximation for the Mechanical Behaviour of Clay

    E-Print Network [OSTI]

    P. Evesque; M. Hattab

    2005-07-07T23:59:59.000Z

    Experimental data from axially symmetric compression test at constant mean pressure p on kaolinite clay are used to study the validity of an "isotropic" modelling as a function of the overconsolidation ratio (OCR).The isotropic assumption is found to be quite good for 24. For very large OCR (OCR >10), anisotropic response is observed at few percents of axial deformation. Relation with anisotropic distribution of local forces is made. Pacs # : 5.40 ; 45.70 ; 62.20 ; 83.70.Fn

  7. Hydrothermal formation of Clay-Carbonate alteration assemblages in the Nili Fossae region of Mars

    E-Print Network [OSTI]

    Brown, Adrian J; Baldridge, Alice M; Crowley, James K; Bridges, Nathan T; Thomson, Bradley J; Marion, Giles M; Filho, Carlos R de Souza; Bishop, Janice L

    2014-01-01T23:59:59.000Z

    The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) has returned observations of the Nili Fossae region indicating the presence of Mg- carbonate in small (characterize these carbonate-bearing units. We applied absorption band mapping techniques to investigate a range of possible phyllosilicate and carbonate minerals that could be present in the Nili Fossae region. We also describe a clay-carbonate hydrothermal alteration mineral assemblage in the Archean Warrawoona Group of Western Australia that is a potential Earth analog to the Nili Fossae carbonate-bearing rock units. We discuss the geological and biological implications for hydrothermal processes on Noachian Mars.

  8. Field tests and new design procedure for laterally loaded drilled shafts in clay 

    E-Print Network [OSTI]

    Bierschwale, Mark W.

    1980-01-01T23:59:59.000Z

    , and develop a new design procedure for drilled shafts supporting precast panel retaining walls. FIELD LOAD TESTS The prediction of the behavior of laterally loaded shafts involves the determination of the shaft-soil interaction. One approach... 4ft to l3 ft 5 -very stiff red clay(CH) below 5ft I-O zL 128 l30 P IC WA R L I QUI 0 LIMIT CONTENT /o LI Ml T ? + 7 IO 20 30 COHESIVE SHEAR STRENGTH, Cu, 0. 6 0, 8 I 0 I. 2 I, 4 I, 6 I. 8 ~ Unconfined Compression Test + Miniature Vane...

  9. Characterization of Geosynthetic Clay Liner Bentonite using Micro-analytical Methods

    SciTech Connect (OSTI)

    Lange, K.; Rowe, R; Jamieson, H; Flemming, R; Lanzirotti, A

    2010-01-01T23:59:59.000Z

    In barrier design, familiarity of the structure and composition of the soil material at the micron scale is necessary for delineating the retention mechanisms of introduced metals, such as the formation of new mineral phases. In this study, the mineralogical and chemical makeup of the bentonite from a geosynthetic clay liner (GCL) was extensively characterized using a combination of conventional benchtop X-ray diffraction (XRD) and micro X-ray diffraction ({mu}XRD) with synchrotron-generated micro X-ray fluorescence ({mu}XRF) elemental mapping and {mu}XRD (S-{mu}XRD). These methods allow for the non-destructive, in situ investigation of a sample, with {micro}m spatial resolution. Synchrotron-based hard X-ray microprobes are specifically advantageous to the study of trace metals due to higher spatial resolution (<10 {micro}m) and higher analytical sensitivity (femtogram detection) than is possible using normal laboratory-based instruments. Minerals comprising less than 5% of the total bentonite sample such as gypsum, goethite and pyrite were identified that were not accessible by other conventional methods for the same GCL bentonite. Two dimensional General Area Diffraction Detector System (GADDS) images proved to be particularly advantageous in differentiating between the microcrystalline clay, which appeared as homogeneous Debye rings, and the 'spotty' or 'grainy' appearance of primary, more-coarsely-crystalline, accessory minerals. For S-{mu}XRD, the tunability of the synchrotron X-rays allowed for efficient distinction of both clay minerals at low scattering angles and in identifying varying Fe oxide minerals at higher angles. GCL samples permeated with metal-bearing mining solutions were also examined in order to consider how mechanisms of metal attenuation may be identified using the same techniques. In addition to the cation exchange capacity from the montmorillonite clay, tests showed how minerals comprising only 1-2% of the bentonite such as goethite could potentially play a significant role in sequestering a range of metals, specifically Ni, Zn and Cu.

  10. The sensitivity of rock mechanical properties to the method by which the clay volume is determined

    E-Print Network [OSTI]

    Ivey, Henry Alexander

    1986-01-01T23:59:59.000Z

    were studied. At At ~ Rv s o form with Rv by the Voigt average technique'' form n Rv ( V xRv xW form i 1 i i i ~ . (7) or with Rv by the Reuse average technique'' form n 1/Rvf $ V xWi Rvi form . . (8) Shear Wave Travel Time Model Determination...'or the degree of MASTER OF SCIENCE AUGUST 1986 Major Subject: petroleum Engineering THE SENSITIVITY OF ROCK MECHANICAL PROPERTIES TO THE METHOD BY WHICH THE CLAY VOLUME IS DETERMINED A Thesis by HENRY ALEXANDER IVEY Approved as to style and content by...

  11. Clay Sell Sworn in as Deputy Secretary of Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platformBuilding RemovalCSSDepartmentDepartment ofCity and 25Clay Sell Sworn in

  12. Clay mineralogy and depositional history of the Frio Formation in two geopressured wells, Brazoria County, Texas

    SciTech Connect (OSTI)

    Freed, R.L.

    1982-01-01T23:59:59.000Z

    Twenty-three shale samples ranging in depth from 5194 ft to 13,246 ft from Gulf Oil Corporation No. 2 Texas State Lease 53034 well and 33 shale samples ranging in depth from 2185 ft to 15,592 ft from General Crude Oil Company/Department of Energy No. 1 Pleasant Bayou well were examined by x-ray techniques to determine the mineralogy of the geopressured zone in the Brazoria Fairway. Both wells have similar weight-percent trends with depth for a portion of the mineralogy. Calcite decreases, and plagioclase, quartz and total clay increase slightly. Within the clays, illite in mixed-layer illite/smectite (I/S) increases and smectite in mixed-layer I/S decreases. Four minerals have distinctly different trends with depth for each well. In the No. 2 Texas State Lease 53034 well, potassium feldspar and mixed-layer I/S decrease, kaolinite increases, and discrete illite is constant. In the No. 1 Pleasant Bayou well, potassium feldspar and kaolinite are constant, mixed-layer I/S increases, and discrete illite decreases.

  13. Steep-Slope Assembly Testing of Clay and Concrete Tile With and Without Cool Pigmented Colors

    SciTech Connect (OSTI)

    Miller, William A [ORNL

    2005-11-01T23:59:59.000Z

    Cool color pigments and sub-tile venting of clay and concrete tile roofs significantly impact the heat flow crossing the roof deck of a steep-slope roof. Field measures for the tile roofs revealed a 70% drop in the peak heat flow crossing the deck as compared to a direct-nailed asphalt shingle roof. The Tile Roofing Institute (TRI) and its affiliate members are keenly interested in documenting the magnitude of the drop for obtaining solar reflectance credits with state and federal "cool roof" building efficiency standards. Tile roofs are direct-nailed or are attached to a deck with batten or batten and counter-batten construction. S-Misson clay and concrete tile roofs, a medium-profile concrete tile roof, and a flat slate tile roof were installed on fully nstrumented attic test assemblies. Temperature measures of the roof, deck, attic, and ceiling, heat flows, solar reflectance, thermal emittance, and the ambient weather were recorded for each of the tile roofs and also on an adjacent attic cavity covered with a conventional pigmented and directnailed asphalt shingle roof. ORNL measured the tile's underside temperature and the bulk air temperature and heat flows just underneath the tile for batten and counter-batten tile systems and compared the results to the conventional asphalt shingle.

  14. Laboratory simulation of geosynthetic clay liner application in contaminated liquids evacuation

    SciTech Connect (OSTI)

    Mlynarek, J.; Vermeersch, O.G. [Geosynthetics Analysis Service, Saint-Hyacinthe, Quebec (Canada); Lemelin, D. [Hydro-Quebec, Montreal, Quebec (Canada)

    1997-11-01T23:59:59.000Z

    To prevent a contamination of soil and underground water by leaking mineral oil, recovery basins are designed and constructed in Quebec, Canada. The functions of such basins are to collect and to evacuate oil to a drainage and then to a recycled and treatment station. The material presently used for such an application is a concrete. However, due to difficult access to some of the transformers, and to the difficult low temperature conditions, engineers are looking for a new, alternate design idea. In order to evaluate the geosynthetic clay liner (GCL) hydraulic behavior in such applications, a laboratory demonstration test has been conducted. A full-scale model was designed and constructed for the purpose of measuring the rate of water flow through different layers of the proposed system. Mineral oil leaks as well as precipitation were simulated during the research program. The testing consisted of the measurements of mineral oil and water (precipitation) volumes at four levels of the demonstration model, during a period of two months. The results showed that only one percent of precipitated water and leaked mineral oil was collected underneath the geosynthetic clay liner. Further research is recommended on: techniques of seaming of GCLs joints and connections; the minimum acceptance rate of hydration of GCLs for different liquids; an influence of water content of soils on GCLs hydration; and a long term hydraulic compatibility of GCLs with different liquids and leachates.

  15. Reconstruction and operation of the El Paso Solar Pond with a geosynthetic clay liner system

    SciTech Connect (OSTI)

    Lu, H.; Swift, A.H.P. [Univ. of Texas, El Paso, TX (United States)

    1996-12-31T23:59:59.000Z

    After the original XR-5 membrane liner failed in 1992, the El Paso Solar Pond was reconstructed and operated with a geosynthetic clay liner (GCL) system. The solar pond is approximately 3,000 m{sup 2} in surface area, and 3.2 meters deep with a 15{degree} side-wall slope. A new heat extraction system includes 15-cm (6-inch) rubber hoses and two redesigned polypropylene diffusers. A new automated instrumentation system was developed for monitoring pond status. It uses a newly developed scanner combined with a computer for both position control and data logging. The salinity gradient was established using a new scanning method, as opposed to the previously used fixed point method. Fresh water was injected into brine through a newly designed PVC bar shaped diffuser, which scans automatically within preset regions. After two months, the pond bottom reached 80 C and heat extraction began. The performance of the GCL system, characterized by its hydraulic conductivity, has been monitored, and generates the first full scale, elevated temperature data for a GCL system. Preliminary hydraulic conductivity data indicate values comparable with other clay liner systems.

  16. GEOC Martial Taillefert Tuesday, April 09, 2013 130 Realtime sorption and precipitation of nickel on clay minerals: An in situ QuickEXAFS investigation

    E-Print Network [OSTI]

    Sparks, Donald L.

    of nickel on clay minerals: An in situ QuickEXAFS investigation Matthew Siebecker1, mgs@udel.edu, Wei Li1 of nickel sorption on Alrich clay minerals utilizing QuickEXAFS spectroscopy and a custom built flow cell Chemical Interactions at the MineralWater Interface (01:00 PM 05:30 PM) Location: Morial Convention Center

  17. RADIOCARBON, Vol 42, Nr 3, 2000, p 323333 2000 by the Arizona Board of Regents on behalf of the University of Arizona AMS RADIOCARBON MEASUREMENTS FROM THE SWEDISH VARVED CLAYS

    E-Print Network [OSTI]

    Wohlfarth, Barbara

    of the University of Arizona 323 AMS RADIOCARBON MEASUREMENTS FROM THE SWEDISH VARVED CLAYS Barbara Wohlfarth correlation of more than 1000 varve-thickness diagrams. The Late Glacial-Early Holocene varved clays were. Formation of varved clays con- tinued throughout the Holocene and is still going on in the estuary of River

  18. Running heading: Bulk density of a clayey subsoil Increase in the bulk density of a Grey Clay subsoil by

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Running heading: Bulk density of a clayey subsoil Increase in the bulk density of a Grey Clay of the prisms were coated by material similar in composition to the topsoil and separated from as the profile dries over summer leading to widening of cracks between prismatic peds, (2) infilling of cracks

  19. Reflectance of dispersed vitrinite in shales hosting PbZnCu ore deposits in western Cuba: comparison with clay crystallinity

    E-Print Network [OSTI]

    Maynard, J. Barry

    : comparison with clay crystallinity J. Barry Maynard a,*, Erika R. Elswick b , James C. Hower c a Department: maynarjb@uc.edu (J.B. Maynard), eelswick@indiana.edu (E.R. Elswick), hower@caer.uky.edu (J.C. Hower). www

  20. Analyses of Adsorption Kinetics Using a Stirred-Flow Chamber: II. Potassium-Calcium Exchange on Clay Minerals

    E-Print Network [OSTI]

    Sparks, Donald L.

    Analyses of Adsorption Kinetics Using a Stirred-Flow Chamber: II. Potassium-Calcium Exchange to be measuredwith the stirred-flowtech- nique, while exchange rates on vermiculite could be ascertained. Adsorption and comparing different ki- netic methods have not been solved. Kinetics of K adsorption on clay minerals have

  1. Shrinkage of microaggregates in Brazilian Latosols during drying: significance of the clay content, mineralogy and hydric stress history

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    content, mineralogy and hydric stress history A. REATTOa,b , A. BRUANDb , E. M. SILVAa , R. GUÉGANb , I in their particle size distribution and mineralogical composition according to insu-00414419,version1-9Sep2009 to the clay content. Consequently, the mineralogy of the

  2. A single hardening elasto-plastic model for Kaolin clay with loading-history-dependent plastic potential function

    E-Print Network [OSTI]

    Prashant, Amit

    A single hardening elasto-plastic model for Kaolin clay with loading-history- dependent plastic and failure criteria are found to be strongly dependent on the principal stress rotation angle () and plastic work. A unique plastic potential function determined solely by the current stress state

  3. Electrical Properties of SandClay Mixtures Containing Trichloroethylene and Ethanol Jeffery J. Roberts and Dorthe Wildenschild*

    E-Print Network [OSTI]

    Wildenschild, Dorthe

    Electrical Properties of Sand­Clay Mixtures Containing Trichloroethylene and Ethanol Jeffery J, and as an ethanol­water mixture (80:20) was flowed through the sample. Resistivity increased by about a factor of 4 as the ethanol mixture replaced the water solution. Nondestructive x-ray imaging of the sample at various stages

  4. High resolution quantitative seismic imaging of a strike-slip fault with small vertical offset in clay-rocks from

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    modify the rock confining properties. In the Tournemire Experimental Platform (TEP, France), fault zones, 2005). However, long term confining properties of the clay-rock layers might be affected of argillaceous rocks and the draining properties of tectonic structures are key parameters for the safety

  5. Effects of aluminosilicate minerals in clay soil fractions on pore water hydroxide ion concentrations in soil/cement matrices 

    E-Print Network [OSTI]

    Cook, Evan Russell

    1998-01-01T23:59:59.000Z

    Ucement/waste matrices. Research described herein was undertaken 1) to ascertain the pH decrement in soil/cement matrices as a function of clay:cement ratio and 2) to develop a methodology to predict hydroxide ion concentrations in soil/cement matrices. To assess...

  6. Non-Linear Poisson-Boltzmann Theory of a Wigner-Seitz Model for Swollen Clays

    E-Print Network [OSTI]

    R. J. F. Leote de Carvalho; E. Trizac; J. -P. Hansen

    1999-12-06T23:59:59.000Z

    Swollen stacks of finite-size disc-like Laponite clay platelets are investigated within a Wigner-Seitz cell model. Each cell is a cylinder containing a coaxial platelet at its centre, together with an overall charge-neutral distribution of microscopic co and counterions, within a primitive model description. The non-linear Poisson-Boltzmann (PB) equation for the electrostatic potential profile is solved numerically within a highly efficient Green's function formulation. Previous predictions of linearised Poisson-Boltzmann (LPB) theory are confirmed at a qualitative level, but large quantitative differences between PB and LPB theories are found at physically relevant values of the charge carried by the platelets. A hybrid theory treating edge effect at the linearised level yields good potential profiles. The force between two coaxial platelets, calculated within PB theory, is an order of magnitude smaller than predicted by LPB theory

  7. Field performance of a geosynthetic clay liner landfill capping system under simulated waste subsidence

    SciTech Connect (OSTI)

    Weiss, W. [Hochschule fur Architektur und Bauwesen (Germany); Siegmund, M. [Materialforschungs - und, Prufanstalt (Germany); Alexiew, D.

    1995-10-01T23:59:59.000Z

    A flexible landfill capping system consisting of a 3-D-geocore composite for gas vent, a Geosynthetic Clay Liner (GCL) for sealing and a 3-D-geocore composite for drainage of the vegetation soil was built on a test field at Michelshoehe landfill near Weimar, Germany. At four locations airbags were installed underneath the thin capping system to simulate subsidences. On top of three of these airbags overlaps of the GCL were positioned, for comparison there was no overlap at the fourth location. After hydratation of the GCL the airbags were de-aerated and subsidences occurred with app. 5 % tensile strain in the GCL. For three weeks the test field was intensively sprinkled in intervals. Then horizontal and vertical deformations were measured, but not displacements were registered in the overlaps. The evaluation of the GCL`s permeability showed no significant difference between the locations with and without overlaps.

  8. Effects of cyclic loading on internal shear strength of unreinforced geosynthetic clay liner

    SciTech Connect (OSTI)

    Lai, J. [Ghaoyang Univ. of Technology, Taichung (Taiwan, Province of China); Daniel, D.E. [Univ. of Illinois, Urbana, IL (United States). Dept. of Civil Engineering; Wright, S.G. [Univ. of Texas, Austin, TX (United States). Dept. of Civil Engineering

    1998-01-01T23:59:59.000Z

    Stress-controlled static and cyclic shear tests were performed by using a direct simple shear device on samples of a geomembrane-supported geosynthetic clay liner (GCL). The dry material showed no degradation in shear strength during cyclic loading as long as the peak shear stress was less than the static shear strength of the GCL with no cyclic loading. Furthermore, cyclic loading slightly densified the dry bentonite and thus increased its shear resistance under subsequent static loading. On the other hand, the shear strength of the hydrated GCL was found to be reduced by cyclic loading. The number of cycles to cause failure decreased with increasing cyclic stress ratio (cyclic shear stress divided by undrained static shear strength); at a cyclic stress ratio of 0.67, failure occurred at 32 cycles of loading, but at a cyclic stress ratio of 0.53, failure did not occur until up to 200 cycles of loading.

  9. Hydraulic conductivity testing of geosynthetic clay liners (GCLs) using the constant volume method

    SciTech Connect (OSTI)

    Wang, X.; Benson, C.H.

    1999-12-01T23:59:59.000Z

    Hydraulic conductivity tests were conducted using open and constant-volume permeation systems on specimens from a geosynthetic clay liner (GCL). Two constant volume (CV) systems were employed: the falling-head constant-volume (FHCV) system and the constant-head constant-volume (CHCV) system. A conventional burette system using pressurized air was employed for the open system (OS) tests. The test results show that hydraulic conductivity tests can be conducted 30 or more times faster with the FHCV and CHCV systems than with an open system. Typically the permeation portion of the FHCV and CHCV tests can be conducted in one-half day. Slightly lower hydraulic conductivities are measured with the CV systems due to the slightly higher effective stress applied during testing with these systems. The CHCV system has several advantages over the FHCV system, including minimizing initial transient behavior, constant applied effective stress during testing, and simpler calculations.

  10. PILLARED CLAYS AS SUPERIOR CATALYSTS FOR SELECTIVE CATALYTIC REDUCTION OF NITRIC OXIDE

    SciTech Connect (OSTI)

    R.Q. Long; N. Tharappiwattananon; W.B. Li; R.T. Yang

    2000-09-01T23:59:59.000Z

    Removal of NO{sub x} (NO + NO{sub 2}) from exhaust gases is a challenging subject. V{sub 2}O{sub 5}-based catalysts are commercial catalysts for selective catalytic reduction (SCR) with NH{sub 3} for stationary sources. However, for diesel and lean-burn gasoline engines in vehicles, hydrocarbons would be the preferred reducing agents over NH{sub 3} because of the practical problems associated with the use of NH{sub 3} (i.e., handling and slippage through the reactor). The noble-metal three-way catalysts are not effective under these conditions. The first catalyst found to be active for selective catalytic reduction of NO by hydrocarbons in the presence of excess oxygen was copper exchanged ZSM-5 and other zeolites, reported in 1990 by Iwamoto in Japan and Held et al. in Germany. Although Cu-ZSM-5 is very active and the most intensively studied catalyst, it suffers from severe deactivation in engine tests, mainly due to H{sub 2}O and SO{sub 2}. In this project, we found that ion-exchanged pillared clays and MCM-41 catalysts showed superior SCR activities of NO with hydrocarbon. All Cu{sup 2+}-exchanged pillared clays showed higher SCR activities than Cu-ZSM-5 reported in the literature. In particular, H{sub 2}O and SO{sub 2} only slightly deactivated the SCR activity of Cu-TiO{sub 2}-PILC, whereas severe deactivation was observed for Cu-ZSM-5. Moreover, Pt/MCM-41 provided the highest specific NO reduction rates as compared with other Pt doped catalysts, i.e., Pt/Al{sub 2}O{sub 3}, Pt/SiO{sub 2} and Pt/ZSM-5. The Pt/MCM-41 catalyst also showed a good stability in the presence of H{sub 2}O and SO{sub 2}.

  11. The electrorheology of suspensions consisting of Na-Fluorohectorite synthetic clay particles in silicon oil

    E-Print Network [OSTI]

    Y. Méheust; K. P. S. Parmar; B. Schjelderupsen; J. O. Fossum

    2010-02-01T23:59:59.000Z

    Under application of an electric field greater than a triggering electric field $E_c \\sim 0.4$ kV/mm, suspensions obtained by dispersing particles of the synthetic clay fluoro-hectorite in a silicon oil, aggregate into chain- and/or column-like structures parallel to the applied electric field. This micro-structuring results in a transition in the suspensions' rheological behavior, from a Newtonian-like behavior to a shear-thinning rheology with a significant yield stress. This behavior is studied as a function of particle volume fraction and strength of the applied electric field, $E$. The steady shear flow curves are observed to scale onto a master curve with respect to $E$, in a manner similar to what was recently found for suspensions of laponite clay [42]. In the case of Na-fluorohectorite, the corresponding dynamic yield stress is demonstrated to scale with respect to $E$ as a power law with an exponent $\\alpha \\sim 1.93$, while the static yield stress inferred from constant shear stress tests exhibits a similar behavior with $\\alpha \\sim 1.58$. The suspensions are also studied in the framework of thixotropic fluids: the bifurcation in the rheology behavior when letting the system flow and evolve under a constant applied shear stress is characterized, and a bifurcation yield stress, estimated as the applied shear stress at which viscosity bifurcation occurs, is measured to scale as $E^\\alpha$ with $\\alpha \\sim 0.5$ to 0.6. All measured yield stresses increase with the particle fraction $\\Phi$ of the suspension. For the static yield stress, a scaling law $\\Phi^\\beta$, with $\\beta = 0.54$, is found. The results are found to be reasonably consistent with each other. Their similarities with-, and discrepancies to- results obtained on laponite-oil suspensions are discussed.

  12. Effect of Residence Time on Ni-Sorption Mechanisms on Clay and Oxide Minerals: An X-ray Absorption Fine Structure (XAFS) Study

    E-Print Network [OSTI]

    Sparks, Donald L.

    Effect of Residence Time on Ni-Sorption Mechanisms on Clay and Oxide Minerals: An X-ray Absorption minerals is typically fast initially, then the rates gradually diminish. In the literature the decline

  13. Petrographic report on clay-rich samples from Permian Unit 4 salt, G. Friemel No. 1 well, Palo Duro Basin, Deaf Smith County, Texas: unanalyzed data

    SciTech Connect (OSTI)

    Fukui, L M

    1983-09-01T23:59:59.000Z

    This report presents the results of mineralogic and petrographic analyses performed on five samples of clay-rich rock from salt-bearing Permian strata sampled by drill core from G. Friemel No. 1 Well, Deaf Smith County, Texas. Five samples of clay-rich rock from depths of about 2457, 2458, 2521, 2548, and 2568 feet were analyzed to determine the amounts of soluble phase (halite) and the amounts and mineralogy of the insoluble phases. The amounts of halite found were 59, 79, 47, 40, and 4 weight percent, respectively, for the samples. The insoluble minerals are predominately clay (20 to 60 volume percent) and anhydrite (up to 17 volume percent), with minor (about 1.0%) and trace amounts of quartz, dolomite, muscovite, and gypsum. The clays include illite, chlorite, and interstratified chlorite-smectite. The results presented in this petrographic report are descriptive, uninterpreted data. 2 references, 7 tables.

  14. Carbonation of Clay Minerals Exposed to scCO2/Water at 200 degrees and 250 degrees C

    SciTech Connect (OSTI)

    Sugama, T.; Ecker, L.; Gill, S.; Butcher, T. (BNL); Bour, D. (AltaRock Energy, Inc.)

    2010-11-01T23:59:59.000Z

    To clarify the mechanisms of carbonation of clay minerals, such as bentonite, kaolinite, and soft clay, we exposed them to supercritical carbon dioxide (scCO2)/water at temperatures of 200 and 250 C and pressures of 1500 and 2000 psi for 72- and 107-hours. Bentonite, comprising three crystalline phases, montmorillonite (MMT), anorthoclase-type albite, and quartz was susceptible to reactions with ionic carbonic acid yielded by the interactions between scCO2 and water, particularly MMT and anorthoclase-type albite phases. For MMT, the cation-exchangeable ions, such as Na+ and Ca2+, present in its basal interplanar space, were replaced by proton, H+, from ionic carbonic acid; thereafter, the cations leaching from MMT directly reacted with CO32- as a counter ion of H+ to form carbonate compounds. Such in-situ carbonation process in basal space caused the shrinkage and breakage of the spacing structure within MMT. In contrast, the wet carbonation of anorthoclase-type albite, categorized as rock minerals, entailed the formation of three amorphous by-products, such as carbonates, kaolinite-like compounds, and silicon dioxide. Together, these two different carbonations caused the disintegration and corruption of bentonite. Kaolinite clay containing the amorphous carbonates and silicon dioxide was inert to wet carbonation. We noted only a gain in weight due to its water uptake, suggesting that kaolinite-like by-products generated by the wet carbonation of rock minerals might remain unchanged even during extended exposure. Soft clay consisting of two crystalline phases, dolomite and silicon dioxide, also was unaltered by wet carbonation, despite the uptake of water.

  15. Response of rice to ammonium and nitrate nitrogen applied at various stages of plant growth on limed and unlimed Beaumont and Lake Charles clays

    E-Print Network [OSTI]

    Gay, William Blalock, III

    1962-01-01T23:59:59.000Z

    RESPONSE OF RICE TO AMMONIUM AND NITRATE NITROGEN APPLIED AT VARIOUS STAGES OF PLANT GROWTH ON LIMED AND UNLINED BEAUNONT AND LAKE CHARLES CLAYS A Thesis By William B. Gay, III Submitted to the Graduate Sohool of the Agricultural... BEAUMONT AND LAKE CHARLES CLAYS A Thesis By Nilliam B. Gay, III Chairman of Committee Head of the Department of Soil Sc Crop Sciences ACKNOWLEDGEMENTS I would like to express my appreciation to Dr. A. G. Caldwell for his 1nterest and guidance...

  16. (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 2002, clay and shale production was reported in all States except Alaska,

    E-Print Network [OSTI]

    to be as follows: ball clay--35% floor and wall tile, 22% sanitaryware, and 43% other uses; bentonite--28% pet for consumption: Artificially activated clay and earth 19 17 18 21 20 Kaolin 53 57 63 114 155 Other 14 16 16 13 49, not elsewhere classified 432 329 357 344 464 Total3 5,230 4,800 5,260 4,970 4,990 Consumption, apparent 36

  17. (Data in thousand metric tons, unless otherwise noted) Domestic Production and Use: In 2003, clay and shale production was reported in all States except Alaska,

    E-Print Network [OSTI]

    ; bentonite-- 25% pet waste absorbent, 21% drilling mud, 21% foundry sand bond, 15% iron ore pelletizing,300 Imports for consumption: Artificially activated clay and earth 17 18 21 27 20 Kaolin 57 63 114 158 275,980 Consumption, apparent 37,500 35,600 34,800 34,600 34,600 Price, average, dollars per ton: Ball clay 40 42 42

  18. Fate of corrosion products released from stainless steel in marine sediments and seawater. Part 1. Northeast Pacific pelagic red clay

    SciTech Connect (OSTI)

    Schmidt, R.L.

    1982-03-01T23:59:59.000Z

    To provide information useful for determining the biogeochemical cycling of corrosion products in the benthic boundary layer of the deep ocean, neutron-activated stainless steel was exposed to seawater and to Northeast Pacific red clay under aerobic and non-oxygenated conditions. This report describes the trace metal geochemistry of the sediment and the chemical speciation of the corrosion products. The sediments generally consisted of reddish-brown clay at the surface grading to a dark-brown transition zone below which mottled olive-gray clay prevailed. Neutron-irradiated 347 stainless steel specimens were exposed to seawater and sediment slurry under aerobic and non-oxygenated conditions for 108 days. The presence of aerated sediment more than doubled the amount of corrosion products released compared to aerated seawater and non-oxygenated sediment treatments. The distribution of /sup 60/Co released from the stainless steel exposed to aerated seawater show that almost 70% of /sup 60/Co activity became associated with suspended particulate matter. No detectable /sup 60/Co activity was present in the soluble, readily dissolved, or inorganic or weakly complexed fractions of aerated sediment which had been used to treat neutron-activated stainless steel. Almost 50% of the /sup 60/Co activity was extracted in the combined soluble, easily dissolved, adsorbed, and organically complexed fractions from the non-oxygenated sediment treatment indicating that this much of the corrosion products may be initially released in ionic form.

  19. Topology of desiccation crack patterns in clay and invariance of crack interface area with thickness

    E-Print Network [OSTI]

    Tajkera Khatun; Tapati Dutta; Sujata Tarafdar

    2014-12-09T23:59:59.000Z

    We study the crack patterns developed on desiccating films of an aqueous colloidal suspension of bentonite on a glass substrate. Varying the thickness of the layer $h$ gives the following new and interesting results: (i)We identify a critical thickness $h_{c}$, above which isolated cracks join each other to form a fully connected network. A topological analysis of the crack network shows that the Euler number falls to a minimum at $h_{c}$. (ii) We find further, that the total vertical surface area of the clay $A_v$, which has opened up due to cracking, is a constant independent of the layer thickness for $h \\geq h_c$. (iii) The total area of the glass substrate $A_s$, exposed by the hierarchical sequence of cracks is also a constant for $h \\geq h_c$. These results are shown to be consistent with a simple energy conservation argument, neglecting dissipative losses. (iv) Finally we show that if the crack pattern is viewed at successively finer resolution, the total cumulative area of cracks visible at a certain resolution, scales with the layer thickness. A suspension of Laponite in methanol is found to exhibit similar salient features (i)-(iv), though in this case the crack initiation process for very thin layers is quite different.

  20. Preliminary evaluation of coal and coalbed gas resource potential of western Clay County, Mississippi

    SciTech Connect (OSTI)

    Henderson, K.S.; Gazzier, C.A.

    1989-01-01T23:59:59.000Z

    After reviewing all previously published data it appeared that if the Mississippi portion of the Black Warrior Basin contained potentially economic seams of coal the thicker downdip section was a more likely place to look. The generosity of several exploration companies in providing an extensive suite of logs that could be correlated with samples contained in the Bureau of Geology Sample Library allowed the authors to correlate and identify these upper Pottsville coal groups previously unknown in Mississippi. The purpose of this study was to identify the potential for coal resources in western Clay County, Mississippi, and to correlate laterally any coal seams identified in order to develop a gross volumetric estimate of in-place resources. It became apparent that many of the shallow coal seams (1,800 feet-3,700 feet) had appreciable quantities of gas, for they exhibited excellent gas shows when drilled. Efforts to determine rank for these coals were made by vitrinite reflectance and thus a preliminary estimate was also made for the potential coalbed methane reserves. 73 refs., 8 figs., 3 tabs.

  1. POLYPHENYLENESULFIED/MONTOMORILLONITE CLAY NANOCOMPOSITE COATINGS: THEIR EFFICACY IN PROTECTING STEEL AGAINST CORROSION.

    SciTech Connect (OSTI)

    SUGAMA, T.; GAWLIK, K.

    2006-06-01T23:59:59.000Z

    Nanoscale montomorillonite (MMT) clay fillers became dispersed in a polyphenylenesulfied (PPS) matrix through the processes of octadecylamine (ODA) intercalation {yields} molten PPS co-intercalation {yields} exfoliation. Cooling this molten exfoliated material led to the formation of a PPS/MMT nanocomposite. The MMT nanofiller conferred three advanced properties on the semi-crystalline PPS: First, it raised its melting point by nearly 40 C to 290 C; second, it increased its crystallization energy, implying that an excellent adherence of the nanofillers surfaces to PPS in terms of a good interfacial bond; and, third, it abated the degree of its hydrothermal oxidation due to sulfide {yields} sulfite linkage transformations. When this advanced PPS nanocomposite was used as a corrosion-preventing coating for carbon steel in a simulated geothermal environment at 300 C, a coating of {approx}150 {micro}m thickness adequately protected the steel against hot brine-caused corrosion. In contrast, an MMT-free PPS coating of similar thickness was not nearly as effective in mitigating corrosion as was the nanocompsite; in fact, the uptake of corrosive ionic electrolyte by the unmodified coating increased with an extending exposure time.

  2. Case studies of the potential effects of carbon taxation on the stone, clay, and glass industry

    SciTech Connect (OSTI)

    Bock, M.J.; Boyd, G.A. (Argonne National Lab., IL (United States). Environmental Assessment and Information Sciences Div.); Rosenbaum, D.I. (Nebraska Univ., Lincoln, NE (United States). Dept. of Economics); Ross, M.H. (Michigan Univ., Ann Arbor, MI (United States). Dept. of Physics)

    1992-12-01T23:59:59.000Z

    This case study focuses on the potential for a carbon tax ($25 and $100 per metric ton of carbon) to reduce energy use and associated carbon dioxide (CO[sub 2]) emissions in three subsectors of the stone, clay, and glass industry: hydraulic cement, glass and glass products, and other products. A conservation supply curve analysis found that (1) opportunities for reducing fossil fuel use in the subsectors are limited (15% reduction under $100 tax) and (2) the relationship between the tax and reduced CO[sub 2] emissions is nonlinear and diminishing. Because cement manufacturing produces a significant amount of CO[sub 2], this subsector was analyzed. A plant-level analysis found more opportunities to mitigate CO[sub 2] emissions; under a $100 tax, fossil fuel use would decrease 52%. (A conservative estimate lies between 15% and 52%). It also confirmed the nonlinear relationship, suggesting significant benefits could result from small taxes (32% reduction under $25 tax). A fuel share analysis found the cement industry could reduce carbon loading 11% under a $100 tax if gas were substituted for coal. Under a $100 tax, cement demand would decrease 17% and its price would increase 32%, a substantial increase for a material commodity. Overall, CO[sub 2] emissions from cement manufacturing would decrease 24--33% under a $100 tax and 10--18% under a $25 tax. Much of the decrease would result from the reduced demand for cement.

  3. Case studies of the potential effects of carbon taxation on the stone, clay, and glass industry

    SciTech Connect (OSTI)

    Bock, M.J.; Boyd, G.A. [Argonne National Lab., IL (United States). Environmental Assessment and Information Sciences Div.; Rosenbaum, D.I. [Nebraska Univ., Lincoln, NE (United States). Dept. of Economics; Ross, M.H. [Michigan Univ., Ann Arbor, MI (United States). Dept. of Physics

    1992-12-01T23:59:59.000Z

    This case study focuses on the potential for a carbon tax ($25 and $100 per metric ton of carbon) to reduce energy use and associated carbon dioxide (CO{sub 2}) emissions in three subsectors of the stone, clay, and glass industry: hydraulic cement, glass and glass products, and other products. A conservation supply curve analysis found that (1) opportunities for reducing fossil fuel use in the subsectors are limited (15% reduction under $100 tax) and (2) the relationship between the tax and reduced CO{sub 2} emissions is nonlinear and diminishing. Because cement manufacturing produces a significant amount of CO{sub 2}, this subsector was analyzed. A plant-level analysis found more opportunities to mitigate CO{sub 2} emissions; under a $100 tax, fossil fuel use would decrease 52%. (A conservative estimate lies between 15% and 52%). It also confirmed the nonlinear relationship, suggesting significant benefits could result from small taxes (32% reduction under $25 tax). A fuel share analysis found the cement industry could reduce carbon loading 11% under a $100 tax if gas were substituted for coal. Under a $100 tax, cement demand would decrease 17% and its price would increase 32%, a substantial increase for a material commodity. Overall, CO{sub 2} emissions from cement manufacturing would decrease 24--33% under a $100 tax and 10--18% under a $25 tax. Much of the decrease would result from the reduced demand for cement.

  4. Short-term and creep shear characteristics of a needlepunched thermally locked geosynthetic clay liner

    SciTech Connect (OSTI)

    Siebken, J.R. [National Seal Co., Galesburg, IL (United States). Technical Services; Swan, R.H. Jr.; Yuan, Z. [GeoSyntec Consultants, Atlanta, GA (United States). Soil-Geosynthetic Interaction Testing Lab.

    1997-11-01T23:59:59.000Z

    A series of constant-rate direct shear tests were conducted on a needlepunched thermally locked geosynthetic clay liner (GCL) in accordance with ASTM Test Method for Determining the Coefficient of Soil and Geosynthetic or Geosynthetic and Geosynthetic Friction by the Direct Shear Method (D 5321). The test results demonstrate that the needlepunched thermally locked reinforcing fibers provide substantial short-term shear strength to a GCL. However, there is a growing concern that the long-term shear strength to a GCL. However, there is a growing concern that the long-term shear strength of this type of GCL can be affected due to the potential of creep within the reinforcing fibers under sustained constant loads which occur in the field. An attempt was made to address this concern through an incrementally-loaded creep shear test conducted in a newly developed constant-load (creep) shear testing device. The results of the creep shear test to date show that the GCL has undergone relatively small shear displacements with incremental shear rates decreasing with time within each loading phase.

  5. A comparison of sample preparation methodology in the evaluation of geosynthetic clay liner (GCL) hydraulic conductivity

    SciTech Connect (OSTI)

    Siebken, J.R. [National Seal Co., Galesburg, IL (United States); Lucas, S. [Albarrie Naue Ltd., Barrie, Ontario (Canada)

    1997-11-01T23:59:59.000Z

    The method of preparing a single needle-punched GCL product for evaluation of hydraulic conductivity in a flexible wall permeameter was examined. The test protocol utilized for this evaluation was GRI Test Method GCL-2 Permeability of GCLs. The GCL product consisted of bentonite clay material supported by a woven and a non-woven geotextile on either side. The method preparation focused on the procedure for separating the test specimen from the larger sample and whether these methods produced difficulty in generating reliable test data. The methods examined included cutting with a razor knife, scissors, and a circular die with the perimeter of the test area under wet and dry conditions. In order to generate as much data as possible, tests were kept brief. Flow was monitored only long enough to determine whether or not preferential flow paths appeared to be present. The results appear to indicate that any of the methods involved will work. Difficulties arose not from the development of preferential flow paths around the edges of the specimens, but from the loss of bentonite from the edges during handling.

  6. Long-term shear strength behavior of a needlepunched geosynthetic clay liner

    SciTech Connect (OSTI)

    Trauger, R.J. [Colloid Environmental Technologies Co., Arlington Heights, IL (United States); Swan, R.H. Jr.; Yuan, Z. [GeoSyntec Consultants, Atlanta, GA (United States). Soil-Geosynthetic Interaction Testing Lab.

    1997-11-01T23:59:59.000Z

    This paper describes two large-scale constant-load (creep) shear testing devices that were developed to evaluate the long-term shearing behavior of geosynthetic clay liners (GCLs) and interfaces between GCLs and other geosynthetics or soils. One device was designed to simulate loading conditions that typically occur on a GCL deployed in a landfill cover system. The other device was designed to simulate loading conditions that typically occur on a GCL deployed in a landfill lining system. A needlepunched GCL was selected for evaluation of its long-term shearing behavior under these two types of loading conditions and the test results are presented in terms of time-displacement curves and shear rate-displacement curves. The results to date show that the GCL has undergone relatively small shear displacements and that the shear displacement rates within the GCL and/or at the test interface have been continuously decreasing with time. For the conditions used in this testing program, it is believed that the GCL`s behavior can be considered stable. Further testing is planned to more accurately define the time-dependent internal and interface shear behavior of the GCL.

  7. Sorption of cadmium and lead by clays from municipal incinerator ash-water suspensions

    SciTech Connect (OSTI)

    Roy, W.R.; Krapac, I.G.; Steele, J.D. [Illinois State Geological Survey, Champaign, IL (United States)

    1993-07-01T23:59:59.000Z

    The effect of Cl complexation in extracts of a flue gas-scrubber incinerator fly ash sample on the sorption of Cd and Ph by kaolinite and illite was investigated using batch-sorption methods. In the pH range of 5 to 9, Cl complexation may reduce sorption and thus increase the mobility of these metals. When an ash-water suspension was acidified to pH 6.85, the dissolution of Cl and Ca essentially eliminated Cd sorption because of complexation and cationic competition. Cadmium would be considered as either mobile or very mobile under these conditions. Lead was not soluble in the pH-6.85 suspension. At pH 12, the approximate pH of water in contact with flue gas-scrubber fly ash, Cd was essentially insoluble and Ph occurred as anionic Ph hydroxide. Anionic Ph was sorbed by the two clays, and the extent of sorption was not influenced by Cl or carbonate complexation. Sorption constants, derived from isotherms, suggested that Ph would be relatively immobile in saturated soil-water systems. The recent concern that highly alkaline, flue gas-scrubber fly ash may release environmentally significant concentrations of mobile Ph when placed in an ash-disposal site with a soil liner should be reevaluated in light of this study. 37 refs., 6 figs., 3 tabs.

  8. Iron oxide and chromia supported on titania-pillared clay for selective catalytic reduction of nitric oxide with ammonia

    SciTech Connect (OSTI)

    Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States)] [State Univ. of New York, Buffalo, NY (United States); Ning Chen [Univ. of Michigan, Ann Arbor, MI (United States)] [Univ. of Michigan, Ann Arbor, MI (United States)

    1996-11-01T23:59:59.000Z

    TiO{sub 2}-pillard clay (PILC) with high surface area, large pore volume, and large interlayer spacing was used as the support for mixed Fe{sub 2}O{sub 3} and Cr{sub 2}O{sub 3} as the catalyst for selective catalytic reduction (SCR) of NO with NH{sub 3}. The Fe/Cr ratio was varied at a fixed total amount of oxide dopant of 10% (wt). The Fe-Cr/TiO{sub 2}-PILC with Fe/Cr=3 showed the highest activity. Compared with commercial V{sub 2}O{sub 5}/TiO{sub 2} catalysts, the activity (on a per gram basis) of the doped pillared clay was approximately twice as high under H{sub 2}O- and SO{sub 2}-free conditions and was approximately 40% higher under conditions with H{sub 2}O and SO{sub 2}. In addition, its activity for SO{sub 2} oxidation was only 20%-25% of that of the V{sub 2}O{sub 5}-based catalysts. TPD of NH{sub 3} on the Fe-Cr/TiO{sub 2}-PILC catalyst showed that both M=O and M-OH (M=Fe or Cr) were necessary for the SCR reaction. In situ IR spectra of NH{sub 3} showed that there was a higher Bronsted acidity than the Lewis acidity on the surface under reaction conditions and that there existed a direct correlation between the SCR activity and the Bronsted acidity among pillared clays with different Fe/Cr ratios. These results, along with the transient response to O{sub 2}, indicated that a similar mechanism to that on the V{sub 2}O{sub 5} catalyst was operative. The TiO{sub 2}-pillared clay used as the support also contributed to the high activity of the Fe-Cr catalyst. The TiO{sub 2} pillars combined with the tetrahedral SiO{sub 2} surfaces of the clay apparently gave rise to a high dispersion of Fe{sub 2}O{sub 3}. 52 refs., 10 figs., 5 tabs.

  9. Structural evaluation of WIPP disposal room raised to Clay Seam G.

    SciTech Connect (OSTI)

    Park, Byoung Yoon (Sandia National Laboratories, Carlsbad, NM); Holland, John F. (Sandia National Laboratories, Albuquerque, NM)

    2007-09-01T23:59:59.000Z

    An error was discovered in the ALGEBBRA script used to calculate the disturbed rock zone around the disposal room and the shear failure zone in the anhydrite layers in the original version. To correct the error, a memorandum of correction was submitted according to the Waste Isolation Pilot Plant (WIPP) Quality Assurance program. The recommended course of action was to correct the error, to repeat the post-process, and to rewrite Section 7.4, 7.5, 8, and Appendix B in the original report. The sections and appendix revised by the post-process using the corrected ALGEBRA scripts are provided in this revision. The original report summarizes a series of structural calculations that examine effects of raising the WIPP repository horizon from the original design level upward 2.43 meters. Calculations were then repeated for grid changes appropriate for the new horizon raised to Clay Seam G. Results are presented in three main areas: (1) Disposal room porosity, (2) Disturbed rock zone characteristics, and (3) Anhydrite marker bed failure. No change to the porosity surface for the compliance re-certification application is necessary to account for raising the repository horizon, because the new porosity surface is essentially identical. The disturbed rock zone evolution and devolution are charted in terms of a stress invariant criterion over the regulatory period. This model shows that the propagation of the DRZ into the surrounding rock salt does not penetrate through MB 139 in the case of both the original horizon and the raised room. Damaged salt would be expected to heal in nominally 150 years. The shear failure does not occur in either the upper or lower anhydrite layers at the moment of excavation, but appears above and below the middle of the pillar one day after the excavation. The damaged anhydrite is not expected to heal as the salt in the DRZ is expected to.

  10. Availability of soil organic phosphorus and fertilizer phosphorus applied to coastal bermudagrass (cynodon dactylon l.) on Houston black clay

    E-Print Network [OSTI]

    Krautmann, Jolly Yang

    1978-01-01T23:59:59.000Z

    ) for different tillage-P treatments during 1976. Mean available P (using 1. 4N NH40Ac extract solution) for different tillage-P treatments during 1976. 46 52 54 61 64 69 70 INTRODUCTION A gradual decline in the annual forage production of recently... con- stitutes the. greatest proportion of the total P in many soils. Supak (1969) found that 46/ of the total P in the check p'lot in a Houston Black clay was organic P. Organic Phosphorus Organic P generally constitutes about 25-75K of the total...

  11. A review of "Bernini: Sculpting in Clay" by C.D. Dickerson III, Anthony Sigel, and Ian Wardropper

    E-Print Network [OSTI]

    Silver, Larry

    2013-01-01T23:59:59.000Z

    engrossing and useful in further research. C. D. Dickerson III, Anthony Sigel, and Ian Wardropper, Bernini: Sculpting in Clay. New Haven: Yale University Press, 2012, 416pp. + 437 color, 35 b/w ills. $65.00. Review by #30;#28;#25;#25;#26; #21... the objects of scienti#15;c techni- cal examination by the third collaborator, Anthony Sigel, published in the Harvard University Art Museum Bulletin (1999). European lend- ers then o#12;ered generous examples?not only from major museums across Italy...

  12. Selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based and pillared interlayer clay-based catalysts 

    E-Print Network [OSTI]

    Oh, Hyuk Jin

    2004-09-30T23:59:59.000Z

    The selective catalytic reduction (SCR) of nitric oxide (NO) with ammonia over vanadia-based (V2O5-WO3/TiO2) and pillared interlayer clay-based (V2O5/Ti-PILC) monolithic honeycomb catalysts using a laboratory laminar-flow ...

  13. Chapter 9. Utilizing mineralogical and chemical information in PTFs (A. Bruand) Soil structure is known to reflect mineralogical composition of clay fraction and soil

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Chapter 9. Utilizing mineralogical and chemical information in PTFs (A. Bruand) Soil structure is known to reflect mineralogical composition of clay fraction and soil chemical composition. Because soil hydraulic properties are likely to depend on soil structure, chemical and mineralogical composition have

  14. Can Next-Generation Reactors Power a Safe Nuclear Futur By Clay Dillow Posted 03.17.2011 at 12:18 pm

    E-Print Network [OSTI]

    Danon, Yaron

    Can Next-Generation Reactors Power a Safe Nuclear Futur By Clay Dillow Posted 03.17.2011 at 12 of nuclear reactors are designed to prevent exactly what we old Fukushima Daiichi plant. Which is good the world rush to reconsider their nuclear plans, nuclear experts look toward a future of smaller, safer

  15. MTBE will be a boon to U. S. gas processors

    SciTech Connect (OSTI)

    Otto, K.W. (Purvin and Gertz, Inc. Dallas, TX (United States))

    1993-01-11T23:59:59.000Z

    This paper reports that the advent of methyl tertiary butyl ether (MTBE) as the primary oxygenate blending component for oxygenated and reformulated motor fuels promises significant benefits for the U.S. gas-processing industry. Increased demand for isobutane as MTBE-plant feedstock will buoy both normal butane and isobutane pricing in U.S. gulf Coast during the 1990s. Elimination of the need to crack normal butane in U.S. olefin plants will also strengthen competitive feedstocks somewhat, including ethane and propane. And increased use of normal butane as isomerization feedstock will result in wider recognition of the premium quality of gas plant normal butane production compared to most refinery C[sub 4] production.

  16. High-pressure imaging breakthrough a boon for nanotechnology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For inquiries on commercializing Argonne technologies, please contact partners@anl.gov. Next article: Argonne researchers uncover structure of new protein implicated in diabetes...

  17. RANDALL B. BOONE March 30, 2011 PROFESSIONAL ADDRESS

    E-Print Network [OSTI]

    Boone, Randall B.

    .S. Environmental Protection Agency's High Performance Computing and Communications research program and their STAR

  18. Boone County, Indiana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: EnergyAvignon,BelcherBlundell 1 GeothermalBonnevilleIndiana: Energy

  19. BooNE versus MiniBooNE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewind Generator|December 5,

  20. Boone County, Arkansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022

  1. Boone County, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022Illinois: Energy Resources Jump to: navigation,

  2. Boone County, Iowa: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022Illinois: Energy Resources Jump to: navigation,Iowa:

  3. Boone County, Kentucky: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022Illinois: Energy Resources Jump to:

  4. Boone County, Missouri: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022Illinois: Energy Resources Jump to:8547°,

  5. Boone County, Nebraska: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass ConversionsSouthby 2022Illinois: Energy Resources Jump to:8547°,Nebraska:

  6. Boone County, West Virginia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

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  7. Manika Prasad is currently Associate Professor of Petroleum Engineering at the Colorado School of Mines. She directs the O-CLASSH (Organic, Clay, Sand, Shale) research group and the

    E-Print Network [OSTI]

    of Mines. She directs the O-CLASSH (Organic, Clay, Sand, Shale) research group and the co interested to understand how the ant-sized phenomena control elephant-sized features. She has published

  8. Clay Cane is a New York City-based, award-winning writer and media consultant. His work covers various topics such as pop culture, sexuality, race, religion, social net-

    E-Print Network [OSTI]

    Miami, University of

    covers various topics such as pop culture, sexuality, race, religion, social net- working and personal social commen- tary website, www.ClayCane. net, a 2007 and 2008 Black Weblog Awards nominee. The College

  9. Evaluation of past and future alterations in tuff at Yucca Mountain, Nevada, based on the clay mineralogy of drill cores USW G-1, G-2, and G-3

    SciTech Connect (OSTI)

    Bish, D.L.

    1989-03-01T23:59:59.000Z

    The tuffs at Yucca Mountain in south-central Nevada are being studied by the Yucca Mountain Project (YMP) to determine their suitability for a high-level radioactive waste repository. For predictive purposes, it is important to understand the alteration history of Yucca Mountain and to know how the minerals in Yucca Mountain tuffs respond to changing conditions such as elevated temperatures. The clay mineralogy of these tuffs has been examined using x-ray powder diffraction, and approximation temperatures of alteration have been determined using available clay mineral data and fluid inclusion analyses. Also, several illites from drill holes USW G-1 and G-2 have been dated using K/Ar techniques, yielding ages of about 11 Myr. The clay mineral in Yucca Mountain tuffs are predominantly interstratified illite/smectites, with minor amounts of chloride, kaolinite, and interstratified chlorite/smectite at depth in USW G-1 and G-2. The reactions observed for these illite/smectites are similar to those observed in pelitic rocks. With depths, the illite/smectites transform from random interstratifications (R = 0) through ordered intermediates (R = 1) to illite in USW G-2 and to Kalkberg (R {ge} 3) interstratifications in USW G-1. The illite/smectites in USW G-3 have not significantly transformed. It appears that the illites in deeper rock results from hydrothermal and diagenetic reactions of earlier-formed smectites. These data demonstrate that the rocks at depth in the northern end of Yucca Mountain were significantly altered about 11 Myr ago. Both clay mineralogy and fluid inclusions suggest that the rocks at depth in USW G-2 have been subjected to postdepositional temperatures of at least 275{degree}C, those in USW G-1 have reached 200{degree}C, and USW G-3 rocks probably have not exceeded 100{degree}C. 64 refs., 9 figs., 3 tabs.

  10. {sup 31}P NMR study of the complexation of TBP with lanthanides and actinides in solution and in a clay matrix

    SciTech Connect (OSTI)

    Hartzell, C.J. [Northern Arizona Univ., Flagstaff, AZ (United States)

    1994-07-24T23:59:59.000Z

    Goal was to use NMR to study TBP/lanthanide complexes in the interlayer or on edge sites of clays. Work in this laboratory yielded details of the complexation of Eu(NO{sub 3}){sub 3} and Pr(NO{sub 3}){sub 3} with TBP in hexane solution; this information is crucial to interpretation of results of NMR studies of the complexes exchanged into clays. The solution {sup 31}P-chemical shift values were improved by repeating the studies on the lanthanide salts dissolved directly into neat TBP. NMR studies of these neat solutions of the Eu(NO{sub 3}){sub 3}{lg_bullet}3TBP-complex and the Pr(NO{sub 3}){sub 3}{lg_bullet}3TBP-complex show that the {sup 31}P chemical shift remains relatively constant for TBP: lanthanide ratios below 3: 1. At higher ratios, the chemical shift approaches that of free TBP, indicating rapid exchange of TBP between the free and complexed state. Exchange of these complexes into the clay hectorite yielded discrete {sup 31}P-NMR signals for the Eu{lg_bullet}TBP complex at -190 ppm and free TBP at -6 ppm. Adsorption of the Pr{lg_bullet}TBP complex yielded broad signals at 76 ppm for the complex and -6 ppm for free TBP. There was no evidence of exchange between the incorporated complex and the free TBP.

  11. Ion-exchanged pillared clays: A new class of catalysts for selective catalytic reduction of NO by hydrocarbons and by ammonia

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    Selective catalytic reduction (SCR) of NO by NH{sub 3} is presently performed with vanadia-based catalysts for flue gas applications. Hydrocarbons would be the preferred reducing agents over NH{sub 3} because of the practical problems associated with the use of NH{sub 3} (i.e., handling and slippage through the reactor). SCR of NO by hydrocarbons can also find important applications for lean-burn (i.e., O{sub 2}-rich) gasoline and diesel engines where the noble-metal three-way catalysts are not effective in the presence of excess oxygen. Pillared interlayered clays (PILCs) have been studied extensively for a number of catalyzed reactions. We have found high activities of PILCs for SCR of NO by NH{sub 3} (26.28). Pillared clays have considerable Bronsted acidity (27, 28), and the protons can be exchanged with metal cations. The Bronsted acidity of TiO{sub 2}-PILC, in particular, remains high after heat treatment at temperatures as high as 400{degrees}C (27-29). In this note, we report first results on the activities of cation-exchanged pillared clays for SCR of NO by both hydrocarbon and NH{sub 3}. 37 refs., 3 figs.

  12. Using synchrotron X-ray scattering to study the diffusion of water in a weakly-hydrated clay sample

    E-Print Network [OSTI]

    Y. Meheust; B. Sandnes; G. Lovoll; K. J. Maloy; J. O. Fossum; G. J. da Silva; M. S. P. Mundim; R. Droppa; D. d. Miranda Fonseca

    2005-09-10T23:59:59.000Z

    We study the diffusion of water in weakly-hydrated samples of the smectite clay Na-fluorohectorite. The quasi one-dimensional samples are dry compounds of nano-layered particles consisting of ~ 80 silicate platelets. Water diffuses into a sample through the mesoporosity in between the particles, and can subsequently intercalate into the adjacent particles. The samples are placed under controlled temperature. They are initially under low humidity conditions, with all particles in a 1WL intercalation state. We then impose a high humidity at one sample end, triggering water penetration along the sample length. We monitor the progression of the humidity front by monitoring the intercalation state of the particles in space and time. This is done by determining the characteristic spacing of the nano-layered particles in situ, from synchrotron wide-angle X-ray scattering measurements. The spatial width of the intercalation front is observed to be smaller than 2mm, while its velocity decreases with time, as expected from a diffusion process.

  13. Analysis of infiltration through a clay radon barrier at an UMTRA disposal cell. Uranium Mill Tailings Remedial Action Project

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    An infiltration study was initiated in January 1988 to assess the percent saturation in, and infiltration through, clay radon barriers of typical Uranium Mill Tailings Remedial Action (UMTRA) Project disposal cells. Predicting infiltration through the radon barrier is necessary to evaluate whether the disposal cell will comply with the proposed US Environmental Protection Agency (EPA) groundwater protection standards (40 CFR 192). The groundwater standards require demonstrating that tailings seepage will not cause background concentrations or maximum concentration limits (MCLs) to be exceeded at the downgradient edge of the disposal facility (the point of compliance, or POC). This demonstration generally consists of incorporating the predicted seepage flux and the concentration of the specific hazardous constituents into a contaminant transport model, and predicting the resultant concentrations at the POC. The infiltration study consisted of a field investigation to evaluate moisture conditions in the radon barrier of the completed Shiprock, New Mexico, UMTRA Project disposal cell and previously completed UMTRA Project disposal cells at Clive, Utah, and Burrell, Pennsylvania. Coring was conducted to measure percent saturation profiles in the radon barriers at these disposal cells. In addition, a detailed investigation of the Shiprock radon barrier was conducted to establish the effects of meteorological stresses on moisture conditions in the filter layer and radon barrier. The Shiprock infiltration study was also intended to characterize hydraulic gradients and operational unsaturated hydraulic conductivities in the radon barrier.

  14. In-situ studies on the performance of landfill caps (compacted soil liners, geomembranes, geosynthetic clay liners, capillary barriers)

    SciTech Connect (OSTI)

    Melchior, S. [IGB - Ingenieurbuero fuer Grundbau, Hamburg (Germany)

    1997-12-31T23:59:59.000Z

    Since 1986 different types of landfill covers have been studied in-situ on the Georgswerder landfill in Hamburg, Germany. Water balance data are available for eight years. The performance of different carriers has been measured by collecting the leakage on areas ranging from 100 m{sup 2} to 500 m{sup 2}. Composite liners with geomembranes performed best, showing no leakage. An extended capillary barrier also performed well. The performance of compacted soil liners, however, decreased severely within five years due to desiccation, shrinkage and plant root penetration (liner leakage now ranging from 150 mm/a to 200 mm/a). About 50 % of the water that reaches the surface of the liner is leaking through it. The maximum leakage rates have increased from 2 x 10{sup -10} m{sup 3} m{sup -2} s{sup -1} to 4 x 10{sup -8} m{sup 3} m{sup -2} s{sup -1}. Two types of geosynthetic clay liners (GCL) have been tested for two years now with disappointing results. The GCL desiccated during the first dry summer of the study. High percolation rates through the GCL were measured during the following winter (45 mm resp. 63 mm in four months). Wetting of the GCL did not significantly reduce the percolation rates.

  15. The effect of clay catalyst on the chemical composition of bio-oil obtained by co-pyrolysis of cellulose and polyethylene

    SciTech Connect (OSTI)

    Solak, Agnieszka; Rutkowski, Piotr, E-mail: piotr.rutkowski@pwr.wroc.pl

    2014-02-15T23:59:59.000Z

    Highlights: • Non-catalytic and catalytic fast pyrolysis of cellulose/polyethylene blend was carried out in a laboratory scale reactor. • Optimization of process temperature was done. • Optimization of clay catalyst type and amount for co-pyrolysis of cellulose and polyethylene was done. • The product yields and the chemical composition of bio-oil was investigated. - Abstract: Cellulose/polyethylene (CPE) mixture 3:1, w/w with and without three clay catalysts (K10 – montmorillonite K10, KSF – montmorillonite KSF, B – Bentonite) addition were subjected to pyrolysis at temperatures 400, 450 and 500 °C with heating rate of 100 °C/s to produce bio-oil with high yield. The pyrolytic oil yield was in the range of 41.3–79.5 wt% depending on the temperature, the type and the amount of catalyst. The non-catalytic fast pyrolysis at 500 °C gives the highest yield of bio-oil (79.5 wt%). The higher temperature of catalytic pyrolysis of cellulose/polyethylene mixture the higher yield of bio-oil is. Contrarily, increasing amount of montmorillonite results in significant, almost linear decrease in bio-oil yield followed by a significant increase of gas yield. The addition of clay catalysts to CPE mixture has a various influence on the distribution of bio-oil components. The addition of montmorillonite K10 to cellulose/polyethylene mixture promotes the deepest conversion of polyethylene and cellulose. Additionally, more saturated than unsaturated hydrocarbons are present in resultant bio-oils. The proportion of liquid hydrocarbons is the highest when a montmorillonite K10 is acting as a catalyst.

  16. Response of rice to ammonium and nitrate nitrogen applied at various stages of plant growth on limed and unlimed Beaumont and Lake Charles clays 

    E-Print Network [OSTI]

    Gay, William Blalock, III

    1962-01-01T23:59:59.000Z

    and Patna1k (1 ) partially support th1s explanation. They found that lime at ths rate of one percent of the weight of the so11 increased mineralisat1on of nitrogen, but most of the n1trogen in their tests accumulated as ammonia rather than nitrate under...RESPONSE OF RICE TO AMMONIUM AND NITRATE NITROGEN APPLIED AT VARIOUS STAGES OF PLANT GROWTH ON LIMED AND UNLINED BEAUNONT AND LAKE CHARLES CLAYS A Thesis By William B. Gay, III Submitted to the Graduate Sohool of the Agricultural...

  17. Evaluation of Devonian shale potential in West Virginia

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    In West Virginia, all significant areas of current Devonian shale gas production are situated where the radioactive shale units are thicker than 200 feet. Most areas of current gas production exhibit a close correlation with the trend of the Rome trough structure, and nearly all lie within the optimum stress-ratio zone. In addition, most of the current gas-producing areas are located within the zone of optimum shale thermal maturity, and optimum shale thermal maturity nearly coincides with the optimum shale stress-ratio value (0.43) in western and southwestern West Virginia. Areas adjacent to existing gas fields, within northeastern Cabell County, northern Lincoln County, and central Wayne County, are excellent prospects for future production. Additional deeper drilling in existing gas fields within the main trend may tap potential new reservoirs in the Rhinestreet and Marcellus Shales. The area east of the Warfield anticline in central Boone, Logan, and eastern Mingo Counties also may be favorable for gas exploitation of the radioactive Huron Shale. Fractures associated with the flank of the anticline and possible reactivation of basement faults in this area should be sufficient to provide the means for production. Further drilling should also be conducted along extensions of the border fault zone of the Rome trough in the western portion of the state. However, the subsurface trend of the trough must be carefully delineated to successfully develop gas production from potential fractured reservoir systems.

  18. JOURNAL DE PHYSIQUE Colloque C6, supplkment au no 12, Tome 35, De'cembre 1974,page C6-569 MOSSBAUER STUDY OF CHANGES IN CLAYS DURING FIRING

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    JOURNAL DE PHYSIQUE Colloque C6, supplkment au no 12, Tome 35, De'cembre 1974,page C6-569 MOSSBAUER STUDY OF CHANGES IN CLAYS DURING FIRING N. A. EISSA and H. A. SALLAM Mossbauer Laboratory, Physics, was collected and fired at temperatures from 200 to 1000 OC. Mossbauer spectra were taken after 1-24hours firing

  19. Kinetics of the smectite to illite transformation in the Denver Basin: Clay mineral, K-Ar data, and mathematical model results

    SciTech Connect (OSTI)

    Elliot, W.C.; Aronson, J.L.; Matisoff, G. (Case Western Reserve Univ., Cleveland, OH (United States)); Gautier, D.L. (Geological Survey, Denver, CO (United States))

    1991-03-01T23:59:59.000Z

    Clay mineral data, potassium-argon (K-Ar) ages, and mathematical model simulations indicate the important kinetic factors controlling the smectite to illite transformation (illitization) in Upper Cretaceous Mowry and Niobrara core and outcrop bentonites from the Denver basin. The data also provide additional information on the thermal history of the basin. Data show that both the percentages of illite layers and the K-Ar ages of mixed layer illite-smectite (I/S) increase with increasing depths of burial, and this trend was simulated mathematically employing a very simplified burial model with a fifth-order overall kinetic expression for the information of illite. For most of the basin, the data is compatible with I/S having been formed in response to increased temperature from progressive burial, because the oldest K-Ar ages of I/S are from the deepest buried I/S along the basin axis. In addition, these data qualitatively suggest that I/S even as small as <0.1 {mu}m retains radiogenic argon under Denver basin burial temperatures. I/S separated from drill core bentonites from the Watenberg gas field, astride the basin axis and known to have been subjected to an anomalously high temperature history, are the most illitic and among the oldest measured from core in this study. The ages of illitization (about 60 Ma) are coincident with the Laramide time of structural development of the basin and uplift of the Front Range. The reconstructions of the burial history, and the modeling of the timing and extent of illitization, suggest that the area of the Wattenberg as field was an upper Cretaceous depocenter, an area of relatively deeper burial along the basin axis.

  20. Selective catalytic reduction of nitrogen oxides by ammonia over Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalysts

    SciTech Connect (OSTI)

    Long, R.Q.; Yang, R.T. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

    1999-09-10T23:59:59.000Z

    Fe-exchanged TiO{sub 2}-pillared clay (PILC) catalysts were prepared and used for selective catalytic reduction (SCR) of NO{sub x} by ammonia. They were also characterized for surface area, pore size distribution, and by XRD, H{sub 2}-TPR, and FT-IR methods. The Fe-TiO{sub 2}-PILC catalysts showed high activities in the reduction of NO{sub x} by NH{sub 3} in the presence of excess oxygen. SO{sub 2} further increased the catalytic activities at above 350 C, whereas H{sub 2}O decreased the activity slightly. The catalysts were about twice as active as commercial-type V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalyst in the presence of H{sub 2}O and SO{sub 2}. Moreover, compared to the commercial catalyst, the Fe-TiO{sub 2}-PILC catalysts had higher N{sub 2}/N{sub 2}O product selectivities (e.g., 0--1% vs 9% N{sub 2}O at 400 C) and substantially lower activities (by 74--88%) for SO{sub 2} oxidation to SO{sub 3} under the same reaction conditions. The activity was further increased to over three times that of the vanadia-based catalyst when Ce was added. The high activity and low N{sub 2}O selectivity for the Fe-TiO{sub 2}-PILC catalysts were attributed to their low activity in the oxidation of ammonia, as compared with vanadia catalysts. XRD patterns of Fe-TiO{sub 2}-PILC were similar to those of TiO{sub 2}-PILC, showing no peaks due to iron oxide, even when the iron content reached 20.1%. The TPR results indicated that iron in the Fe-TiO{sub 2}-PILC catalysts with lower iron contents existed in the form of isolated Fe{sup 3+} ions. The activities of Fe-TiO{sub 2}-PILC catalysts were consistent with their surface acidities, which were identified by FT-IR of the NH{sub 3}-adsorbed samples. The enhancement of activities by H{sub 2}O + SO{sub 2} was attributed to the increase of surface acidity resulting from the formation of surface sulfate species of iron.

  1. Effective forces in saturated clays 

    E-Print Network [OSTI]

    Teetes, George Ray

    1993-01-01T23:59:59.000Z

    This paper is the culmination of a five-phase research effort investigating overpressured soil and rock formations. These formations, found all over the world, at varying depths, contain pore water confined at pressures ...

  2. Effective forces in saturated clays

    E-Print Network [OSTI]

    Teetes, George Ray

    1993-01-01T23:59:59.000Z

    This paper is the culmination of a five-phase research effort investigating overpressured soil and rock formations. These formations, found all over the world, at varying depths, contain pore water confined at pressures greater than the hydrostatic...

  3. Pavement roughness on expansive clays

    E-Print Network [OSTI]

    Velasco, Manuel O

    1980-01-01T23:59:59.000Z

    0 I/I Ql 0 Z 0 V- IU 0 Soil samples were taken adjacent to the roadway segments using a manual auger, in general at depths of 1, 2, and 3 feet. A total of 60 samples were brought to the laboratory, where the following tests have been...

  4. Stimulus Spending at Oak Ridge: A Boon or A Bust? | Department...

    Office of Environmental Management (EM)

    were investigated and mercury contamination in the sewers mitigated. The spread of residual mercury waste was halted as best as possible by containment and treatment of...

  5. NREL: News Feature - NREL Software Tool a Boon for Wind Industry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    temperatures, and other variables alter the air flow and energy production at wind farms. Photo by Dennis Schroeder, NREL Wind energy is blowing away skeptics-it's so close to...

  6. The cholesterol and lecithin requirement of the marine shrimp, Penaeus vannamei Boone

    E-Print Network [OSTI]

    Emery, Ann Elaine

    1987-01-01T23:59:59.000Z

    Karen Hall and Najma Alam for their assistance in laboratory analyses, and Don Clark for his friendly altruism at the Shrimp Nariculture Project. I am grateful to Linda Smith and Leslie Sturmer for providing postlarvae, and to my graduate committee...

  7. Use of Prescribed Fire to Reduce Wildfire Robert E. Martin, J. Boone Kauffman, and Joan

    E-Print Network [OSTI]

    Standiford, Richard B.

    reduces fire hazard and potential fire behavior primarily by reducing fuel quantity and continuity of excessive biomass; it has set the stage for high-intensity, high-fuel- consumption, stand-removal fires. These include maintenance of stand composition, increase in water quantity and quality, reduction

  8. A Software Engineering Approach to Constraint Programming Systems Ka Boon Kevin Ng

    E-Print Network [OSTI]

    Henz, Martin

    Application Technologies Honeywell Automation and Control Solutions kevin.ng@honeywell.com Chiu Wo Choi Dept

  9. . Ion Trap Cavity Quantum Electrodynamics Boon Leng Chuah, Nick Lewty, Arpan Roy and Murray Barrett

    E-Print Network [OSTI]

    Hensinger, Winfried

    F''=3 F''=2 F''=1 F''=0 F =2 F =1 6P1/2 6S1/2 5D3/2 |0> |1> State Detection Method: "Shelving" 137 it a promising qubit candidate. The qubits states are chosen to be |F=1,mF=1>and |F=2,mF=2>. During "shelving

  10. Solar Viewed as Triple Boon for Bishop Paiute Tribe | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently AskedEnergyIssues DOE's Nuclear EnergySmart Metersof EnergyRightsSolar

  11. FTIR and kinetic studies of the mechanism of Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay catalyst for selective catalytic reduction of NO with ammonia

    SciTech Connect (OSTI)

    Long, R.Q.; Yang, R.T.

    2000-02-15T23:59:59.000Z

    A series of FTIR spectroscopic and kinetic studies of the selective catalytic reduction (SCR) of nitric oxide by ammonia were conducted on Fe{sup 3+}-exchanged TiO{sub 2}-pillared clay (Fe-TiO{sub 2}-PILC) catalyst. It was found that No molecules were absorbed on the fresh Fe-TiO{sub 2}-PILC catalyst and then oxidized by O{sub 2} to adsorbed NO{sub 2} and nitrate species. These NO{sub x} adspecies could be reduced by NH{sub 3} at high temperatures. NH{sub 3} molecules could also be adsorbed on the Broensted acid and Lewis acid sites on the Fe-TiO{sub 2}-PILC catalyst to generate, respectively, NH{sup +}{sub 4} ions and coordinated NH{sub 3} species. These NH{sub 3} adspecies were active in reacting with NO, NO + O{sub 2} and NO{sub 2}, but the reaction rates of NH{sub 3} + NO + O{sub 2} and NH{sub 3} + NO{sub 2} were much higher than that of NNO + NH{sub 3}. However, under reaction conditions, the surface of Fe-TiO{sub 2}-PILC was mainly covered by NH{sup +}{sub 4} ions and coordinated NH{sub 3}, and no NO{sub x} adspecies were detected. This is in agreement with the zero-order for the SCR reaction with respect to NH{sub 3}. A possible reaction scheme for the SCR reaction on Fe-TiO{sub 2}-PILC was proposed. NO reduction initially involved the reaction between NO{sub 2} and pairs of NH{sub 3} adspecies to form an active intermediate, which finally reacted with gaseous or weakly adsorbed NO to produce N{sub 2} and H{sub 2}O.

  12. ELASTIC PROPERTIES OF CLAYS Arpita Pal Bathija

    E-Print Network [OSTI]

    are essential for the interpretation and modeling of their seismic response. iv #12;TABLE OF CONTENTS ABSTRACT and shale. R has significant implications for time-lapse(4D) seismic studies where it can be used to infer reservoir or overburden thickness changes from seismic data, but is not well understood. We found that R

  13. Herbicide Update Ian Willoughby and David Clay

    E-Print Network [OSTI]

    and recommendations 15 Label approvals 15 Off-label approvals 15 Off-label arrangements for Christmas trees 16 List recommendations and off-label approvals 20 Forest use 20 Atrazine and cyanazine 20 Cycloxydim 28 Dichlobenil 30

  14. Carbon Emissions: Stone, Clay, and Glass Industry

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,128 2,469 2,321Spain (Million Cubic Feet)Iron andCarbon

  15. Material characterization of the clay bonded silicon carbide candle filters and ash formations in the W-APF system after 500 hours of hot gas filtration at AEP. Appendix to Advanced Particle Filter: Technical progress report No. 11, January--March 1993

    SciTech Connect (OSTI)

    Alvin, M.A.

    1993-04-05T23:59:59.000Z

    (1) After 500 hours of operation in the pressurized fluidized-bed combustion gas environment, the fibrous outer membrane along the clay bonded silicon carbide Schumacher Dia Schumalith candles remained intact. The fibrous outer membrane did not permit penetration of fines through the filter wall. (2) An approximate 10-15% loss of material strength occurred within the intact candle clay bonded silicon carbide matrix after 500 hours of exposure to the PFBC gas environment. A relatively uniform strength change resulted within the intact candles throughout the vessel (i.e., top to bottom plenums), as well as within the various cluster ring positions (i.e., outer versus inner ring candle filters). A somewhat higher loss of material strength, i.e., 25% was detected in fractured candle segments removed from the W-APF ash hopper. (3) Sulfur which is present in the pressurized fluidized-bed combustion gas system induced phase changes along the surface of the binder which coats the silicon carbide grains in the Schumacher Dia Schumalith candle filter matrix.

  16. Competitive sorption of pyrene and pyridine to natural clay minerals and reference clay standards

    E-Print Network [OSTI]

    Lee, Lai Man

    2001-01-01T23:59:59.000Z

    -organic interactions were thought to be negligible or nonexistent. Recent studies have shown that the mineral contribution in sorption of Polycyclic Aromatic Hydrocarbons (PAH) has been underestimated. Sorption mechanisms between minerals and PAH are poorly...

  17. Fracture characterization of clays and clay-like materials using flattened Brazilian Test

    E-Print Network [OSTI]

    Agaiby, Shehab Sherif Wissa

    2013-01-01T23:59:59.000Z

    Fracture mechanics has been used for many years to study the mechanical behavior of brittle and quasi-brittle materials like concrete, rock, wood, and ceramics. To date, the application of fracture mechanics to soils has ...

  18. Engineering in Liberal Education Liberal Education in Engineering

    E-Print Network [OSTI]

    Era The Materials Revolution Technology: Boon or Bane? Energy Technology and Public Policy, and Security in the Current Era The Materials Revolution Technology: Boon or Bane? Energy Technology and Public

  19. A review of "War, Domination, and the Monarchy of France: Claude de Seyssel and the Language of Politics in the Renaissance" by Rebecca Ard Boone

    E-Print Network [OSTI]

    Cohen, Paul

    2009-01-01T23:59:59.000Z

    , the author could be reproached for limiting original research to Seys- sel?s own writings, and relying on secondary sources (notably Alberto Caviglia?s 1928 biography) for sketching out his life. A reconstruc- tion of Seyssel?s career based on archival...

  20. A review of "War, Domination, and the Monarchy of France: Claude de Seyssel and the Language of Politics in the Renaissance" by Rebecca Ard Boone 

    E-Print Network [OSTI]

    Cohen, Paul

    2009-01-01T23:59:59.000Z

    and outlook were also firmly anchored in Savoy, Switzerland, and above all Italy. Seyssel was as committed to serving Savoy as France; he was profoundly shaped by Italian intellectual life, his experience as diplomat and French agent in Italy, by his deep...

  1. ASU SUPERVISOR'S ACCIDENT/ILLNESS INVESTIGATION FORM Return to: ASU HRS Workers' Comp Office, PO Box 32010, Founders Hall, Boone, NC 28608

    E-Print Network [OSTI]

    Thaxton, Christopher S.

    ASU SUPERVISOR'S ACCIDENT/ILLNESS INVESTIGATION FORM Return to: ASU HRS Workers' Comp Office, PO Services Workers' Comp Office within 24 hours or as soon as possible after the accident/illness. IMMEDIATELY report all accidents involving serious bodily injury or death to the Workers' Comp Office (X 6488

  2. Kinetics of the clay roofing tile convection drying

    SciTech Connect (OSTI)

    Thomas, S. (Univ. of Osijek (Croatia). Faculty of Food Technology); Skansi, D. (Univ. of Zagreb (Croatia). Faculty of Chemical Engineering and Technology); Sokele, M. (Croatian Post and Telecommunications, Zagreb (Croatia). Telecommunications Center)

    1993-01-01T23:59:59.000Z

    Kinetics of the convection drying process of flat tile has been investigated experimentally in an industrial tunnel dryer. Several velocities of wet tile movement through the dryer were tested to obtain maximum allowable drying rate curve. As there are various models to describe the kinetics of convection drying, finding a model that would fairly well approximate the kinetics of the whole drying process was part of the research. Especially the polynomial and exponential models were tested. It was found that exponential model of the type: B(t) = (a[minus]B[sub e])[center dot]EXP([minus]bt[sup 2])+B[sub e], ([minus]dB(t)/dt) = 2bt(B(t)[minus]B[sub e]) significantly correlates the kinetics of the whole tile drying process. Applying the maximum allowable drying rate curve obtained for flat tile in the first period of drying, a grapho-analytic model for the optimal conducting of the process has been developed.

  3. Bioreduction of Fe-bearing clay minerals and their reactivity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    donor, and Shewanella Putrifaciens CN32 cells as mediators. In select tubes, anthraquinone-2,6-disulfate (AQDS) was added as electron shuttle to facilitate electron...

  4. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    E-Print Network [OSTI]

    Liu, Hui-Hai

    2010-01-01T23:59:59.000Z

    International Workshop on Geomechanics, hydromechanical andflow, heat transport and geomechanics, by linking the twotransport modeling and geomechanics using the reactive

  5. Deputy Secretary Clay Sell Touts Georgian Efforts to Advance...

    Energy Savers [EERE]

    Energy Cooperation and Non-Proliferation March 16, 2007 - 10:55am Addthis Visits National Nuclear Waste Repository in Mtskheta, Georgia TBILISI, Georgia - U.S. Deputy Secretary of...

  6. Lateral load test of a drilled shaft in clay

    E-Print Network [OSTI]

    Kasch, Vernon R

    1977-01-01T23:59:59.000Z

    will be used to develop rational criteria for the design of drilled shafts that support precast panel retaining walls. The procedure used in conducting the study was: 1. Design and construct a reaction and loading system capable of applying large magnitude... lateral loads to large diameter drilled shafts. 2. Construct a large diameter instrumented drilled shaft. 3. Test the shaft by applying lateral loads. 4. Obtain undisturbed soil samples from the drilled shaft con- struction site and perform laboratory...

  7. applied clay science: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Procedure Contents Introduction i Preface 1 Haller, Gary L. 11 Master of Science Applied Physics Engineering Websites Summary: Master of Science Applied Physics Programme Guide...

  8. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    E-Print Network [OSTI]

    Liu, Hui-Hai

    2010-01-01T23:59:59.000Z

    Pressurized Water Reactor (PWR) used nuclear fuel. The firstrepository tunnels, the PWR type of used fuel is typicallyby the length of individual PWR fuel elements and the number

  9. Nutritional factors limiting forage yields in Houston black clay

    E-Print Network [OSTI]

    Gentzsch, Enrique Pedro

    1968-01-01T23:59:59.000Z

    4 100 25 0 5 100 25 100 6 100 100 0 7 100 100 100 8 100 100 100 y Zn 1. 73 0. 06 1. 70 0. 73 0. 14 1. 75 0. 10 1. 43 0. 64 0. 13 1. 83 0. 09 1. 73 0. 73 0. 14 2. 37 0. 10 1. 49 0. 74 0. 14 2. 42 0 ' 12 1 ~ 47 0 ' 76 0 ' 15 2. 42 0. 13 1... in N s m s P K Ca Mg Zn Fe Mn 1 50 0 2 50 25 14. 3 3 50 25 100 4 100 25 0 5 100 25 100 11. 3 14. 9 11, 2 6 100 100 16. 6 7 100 100 100 8 100 100 100 + Zn 9 100 100 100 * Fe 14. 4 19. 7 23. 3 10 100 100 100 + Fe + Zn 32. 6 164 6. 3...

  10. Model of crack propagation in a clay soil

    E-Print Network [OSTI]

    Carriere, Patrick Edwidge

    1985-01-01T23:59:59.000Z

    in elevation of the soil surface were recorded over time of drying for each of the treatments. A logarithmic model to predict the crack depth, the crack width, and the drop in elevation of the soil surface expressed by the equation y = A + C*logt, was found... 2 MEANS procedure results for crack depth. 3 ANOVA results for crack depth. 19 29 30 4 Values of A and C obtained from linear regression analysis for crack depth. 35 5 Selection of combinations of independent variables for maximum R...

  11. Upper bound analysis for drag anchors in soft clay

    E-Print Network [OSTI]

    Kim, Byoung Min

    2007-04-25T23:59:59.000Z

    and centrifuge model tests. iv ACKNOWLEDGMENTS I would like to acknowledge the support of Department of the Interior Minerals Management Service (Cooperative Agreement No. 1435-01-99-CA-31003), the Offshore Technology Research Center and his... anchor (Vryhof 1999 )...................................................7 1.7 Profile of penetration into seabed.................................................................................9 1.8 Undrained shear strength profile in Gulf of Mexico...

  12. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    E-Print Network [OSTI]

    Liu, Hui-Hai

    2010-01-01T23:59:59.000Z

    I. Reservoir Engineering in Coal Seams: Part 1—The PhysicalStorage and Movement in Coal Seams. SPE Reserv. Eng. , 2 (swelling stress for coal seams that can involve swelling or

  13. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of carbon dioxide (CO2). The minerals may affect the reservoir storage capacity as well as the integrity of its natural seals such as caprock formations. CO2 interaction...

  14. abyssal plane clay: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Global Heat and Sea Level Rise Budgets* Geosciences Websites Summary: Warming of Global Abyssal and Deep Southern Ocean Waters between the 1990s and 2000s: Contributions...

  15. Long-term behaviour of twin tunnels in London clay

    E-Print Network [OSTI]

    Laver, Richard George

    2011-03-15T23:59:59.000Z

    Offset of maximum horizontal displacement from tunnel cen- treline ARS Coefficient in relative settlement equation, see equation (8.19) AT Cross-sectional area of tunnel Atw Multiple of i defining extent of full trough width B Pore pressure coefficient...

  16. Compaction characteristics of clay soil using the gyratory testing machine

    E-Print Network [OSTI]

    Al-Khafaji, Abbas Nasir

    1964-01-01T23:59:59.000Z

    le 1NRRSXN %'NCL ~ ~ e ~ ~ e ~ ' a e ~ gsslltstlw 1asl)sts: ~ 4 ~ ~ ~ QSSSSLCShtSS 1SSL)l?4I ~ ~ s ' ~ i ~ ~ ~ ~ NL ~ ' e'' ~ ~ ' NN ~ ~ ~ ~ ~ 20 I, iyee of Optima . :;-:;. . . ::, '-", ":-'- . '". ". -', ; ", . ::. ", ", ''":;j...

  17. By HENRY CLAY WEBSTER Posted: December 6, 2010

    E-Print Network [OSTI]

    Rhode Island, University of

    , universities, inpatient facilities, and private practices, as well as other settings. Flexible hours can, a doctorate, or complete a postgraduate clinical training program. Two years of supervised clinical work who is too extroverted might not be good at that." Suggested job searches: Counselor jobs | Clinical

  18. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    E-Print Network [OSTI]

    Liu, Hui-Hai

    2010-01-01T23:59:59.000Z

    and the future path of diagenesis have important effects onthe basic basin model for diagenesis. Therefore, some method

  19. Clay Minerals Related To The Hydrothermal Activity Of The Bouillante...

    Open Energy Info (EERE)

    Lesser Antilles arc. Three directional wells were drilled in 2001 to optimize the productivity of the geothermal field up to 15 MWe and to investigate the vertical distribution...

  20. Sandstone Acidizing Using Chelating Agents and their Interaction with Clays

    E-Print Network [OSTI]

    George, Noble Thekkemelathethil 1987-

    2013-01-09T23:59:59.000Z

    OF FIGURES Page Figure 1 Chemical Structures of Important Chelating Agents in Oil and Gas Industry (Frenier et al... of Precipitate Formed when Mixing 20% Na-GLDA with 3% HF acid by Weight Showing the Prominence of Sodium and Fluorine ................................................................................. 53 Figure 28 Elemental Analysis of Precipitate...

  1. A study of selected chemical admixtures for clay soil stabilization

    E-Print Network [OSTI]

    Gover Belendez, Charles Baker

    1966-01-01T23:59:59.000Z

    to amount to 100/ active, If the chemical was . 20'/ active then 5 times as much was used. The samples were mixed well and placed in sealed containers and stored for a period of two days, 14 after which they were ready for use in the particular test... by the Atterberg Limits, are presented in Table 3. One can observe that all values fall in the margin of experimental error. Thus, the effect of these chemical additives upon the plasticity of both soils is non-existent under the conditions tested...

  2. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    E-Print Network [OSTI]

    Liu, Hui-Hai

    2010-01-01T23:59:59.000Z

    sorption including waste heat, hyperalkaline solutions frome.g. , heat production from the decay of the waste, re-waste packages along the tunnels, to achieve a distributed heat

  3. Modeling of strain rate effects on clay in simple shear 

    E-Print Network [OSTI]

    Jung, Byoung Chan

    2006-08-16T23:59:59.000Z

    in monotonic and cyclic simple shear tests. Nevertheless, the few available experimental results cover a very limited range of loading conditions and rates. The existing literature established that the soil response display a unique relationship between shear...

  4. An engineering geology analysis of home foundations on expansive clays

    E-Print Network [OSTI]

    Castleberry, Joe Patterson

    1974-01-01T23:59:59.000Z

    Center Lift Model 70 14 Regression Analysis With Interactions End Lift Model 71 APPENDIX C C-1 Studies in Which Swelling Potential and Pressure Were Compared Against Several Soil Index Properties . . . . . . . . . 126 iX Table APPENDIX D Page.... environmental parameters. Studies directed toward light foundations on expansive soil have been limited to case histories of damaged structures, and, for most purposes, do little more than restate the problem. The Carter's &rove Addition, located...

  5. aluminosilicate clay minerals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    used mineral-based crankcase oil may build up in shellfish or other organisms. q Some metals in used mineral-based crankcase oil dissolve in water and move through the s Used...

  6. Conductive two-dimensional titanium carbide clay with high...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into thin sheets, for a host of applications. When the rolled films were used as supercapacitor electrodes in a H 2 SO 4 electrolyte, the performances were extraordinary, with...

  7. Effect of sample disturbance in opalinus clay shales

    E-Print Network [OSTI]

    Pei, Jianyong, 1975-

    2004-01-01T23:59:59.000Z

    The sample disturbance problem for different geomaterials is reviewed in this thesis. A general discussion on the disturbance sources and complexities of the disturbance problem is followed by detailed reviews on disturbance ...

  8. Platte-Clay Electric Coop, Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroupPerfectenergy InternationalInformationPlacer CountyPlateauRiver

  9. Deputy Secretary Clay Sell Touts Georgian Efforts to Advance Regional

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov. Are you0andEnergyGlobal Nuclearof aDepartment- the Military

  10. City of Clay Center, Kansas (Utility Company) | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof EnergyInnovationin Urban Transport |City ofBlueChappell, NebraskaCityCity

  11. Clay Central Everly School Dist Wind Farm | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCity ofClark Energy Coop Inc JumpCentral

  12. Clay County, Texas: Energy Resources | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png El CER esDatasetCity ofClark Energy Coop Inc

  13. Clay Center, Ohio: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, clickInformation SmyrnaNew York:Information Systems: A

  14. Clay County, Alabama: Energy Resources | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, clickInformation SmyrnaNew York:Information Systems: AAlabama: Energy

  15. Clay County, Arkansas: Energy Resources | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, clickInformation SmyrnaNew York:Information Systems: AAlabama:

  16. Clay County, Georgia: Energy Resources | Open Energy Information

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  17. Clay County, Illinois: Energy Resources | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model, clickInformation SmyrnaNew York:Information Systems:Illinois: Energy

  18. Clay County, Iowa: Energy Resources | Open Energy Information

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