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We encourage you to perform a real-time search of NLEBeta
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1

Energetics of Hydrogen Bond Network Rearrangements in Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

2

Ultrafast structural fluctuations and rearrangements of water's hydrogen bonded network  

E-Print Network [OSTI]

Aqueous chemistry is strongly influenced by water's ability to form an extended network of hydrogen bonds. It is the fluctuations and rearrangements of this network that stabilize reaction products and drive the transport ...

Loparo, Joseph J. (Joseph John)

2007-01-01T23:59:59.000Z

3

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and WestLydiaEnabling time

4

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and WestLydiaEnabling timeEnergetics of

5

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for37 East and WestLydiaEnabling timeEnergetics

6

Long time fluctuation of liquid water: l/f spectrum of energy fluctuation in hydrogen bond network rearrangement dynamics  

E-Print Network [OSTI]

Long time fluctuation of liquid water: l/f spectrum of energy fluctuation in hydrogen bond network of the potential energy fluctuation of liquid water is examined and found to yield so-called l/f frequency of hydrogen bond network relaxations in liquid water. A simple model of cellular dynamics is proposed

Ramaswamy, Ram

7

Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR  

E-Print Network [OSTI]

We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

Nicodemus, Rebecca A.

8

Ideally Glassy Hydrogen Bonded Networks  

E-Print Network [OSTI]

The axiomatic theory of ideally glassy networks, which has proved effective in describing phase diagrams and properties of chalcogenide and oxide glasses and their foreign interfaces, is broadened here to include intermolecular interactions in hydrogen-bonded polyalcohols such as glycerol, monosaccharides (glucose), and the optimal bioprotective hydrogen-bonded disaccharide networks formed from trehalose. The methods of Lagrangian mechanics and Maxwellian scaffolds are useful at the molecular level when bonding hierarchies are characterized by constraint counting similar to the chemical methods used by Huckel and Pauling. Whereas Newtonian molecular dynamical methods are useful for simulating large-scale interactions for times of order 10 ps, constraint counting describes network properties on glassy (almost equilibrated) time scales, which may be of cosmological order for oxide glasses, or years for trehalose. The ideally glassy network of trehalose may consist of extensible tandem sandwich arrays.

J. C. Phillips

2005-08-05T23:59:59.000Z

9

Hydrogen bond rearrangements and the motion of charge defects in water viewed using multidimensional ultrafast infrared spectroscopy  

E-Print Network [OSTI]

Compared with other molecular liquids, water is highly structured due to its ability to form up to four hydrogen bonds to its nearest neighbors, resulting in a tetrahedral network of molecules. However, this network is ...

Roberts, Sean T. (Sean Thomas)

2010-01-01T23:59:59.000Z

10

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage ofDefects on Graphene

11

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage ofDefects on GrapheneEnergetics of

12

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage ofDefects on GrapheneEnergetics

13

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage ofDefects on Graphene throughEnergetics of

14

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage ofDefects on Graphene throughEnergetics

15

A Preorganized Hydrogen Bond Network and Its Effect on Anion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Preorganized Hydrogen Bond Network and Its Effect on Anion Stability. A Preorganized Hydrogen Bond Network and Its Effect on Anion Stability. Abstract: Rigid tricyclic locked in...

16

Rearrangement of a phosphosilicate glass network induced by the 193-nm radiation  

SciTech Connect (OSTI)

The IR absorption and Raman spectra of phosphosilicate glass (PSG) are measured during its exposure to radiation at a wavelength of 193 nm. The obtained data demonstrate the complicated rearrangement dynamics of the glass network around phosphor atoms and of the glass network as a whole. The experimental dependences are explained by the model of the PSG network based on the concepts of the theory of rigidity percolation. (interaction of laser radiation with matter)

Larionov, Yu V [A. M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Sokolov, V O; Plotnichenko, V G [Fiber Optics Research Center, Russian Academy of Sciences, Moscow (Russian Federation)

2008-10-31T23:59:59.000Z

17

Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, Tobias Steinel, and M. D. Fayer*  

E-Print Network [OSTI]

Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, TobiasVed: September 1, 2003; In Final Form: December 18, 2003 The nature of hydrogen bonding networks following hydrogen bond breaking is investigated using vibrational echo correlation spectroscopy of the hydroxyl

Fayer, Michael D.

18

Algorithm for anisotropic diffusion in hydrogen-bonded networks  

E-Print Network [OSTI]

In this paper I describe a specialized algorithm for anisotropic diffusion determined by a field of transition rates. The algorithm can be used to describe some interesting forms of diffusion that occur in the study of proton motion in a network of hydrogen bonds. The algorithm produces data that require a nonstandard method of spectral analysis which is also developed here. Finally, I apply the algorithm to a simple specific example.

Edoardo Milotti

2007-04-04T23:59:59.000Z

19

Hydrogen Bond Switching among Flavin and Amino Acids Determines the Nature of Proton-Coupled Electron Transfer in BLUF  

E-Print Network [OSTI]

Hydrogen Bond Switching among Flavin and Amino Acids Determines the Nature of Proton results from a hydrogen bond switch between the flavin and its surrounding amino acids that preconfigures a rearrangement of the hydrogen bond network around the flavin takes place leading to a 10-15 nm red shift

van Stokkum, Ivo

20

Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen Bonds and An Alternative to the Low Barrier Hydrogen-Bond Proposal  

SciTech Connect (OSTI)

We report quantifying the strengths of different types of hydrogen bonds in hydrogen bond networks (HBNs) via measurement of the adiabatic electron detachment energy of the conjugate base of a small covalent polyol model compound (i.e., (HOCH2CH2CH(OH)CH2)2CHOH) in the gas phase and the pKa of the corresponding acid in DMSO. The latter result reveals that the hydrogen bonds to the charged center and those that are one solvation shell further away (i.e., primary and secondary) provide 5.3 and 2.5 pKa units of stabilization per hydrogen bond in DMSO. Computations indicate that these energies increase to 8.4 and 3.9 pKa units in benzene and that the total stabilizations are 16 (DMSO) and 25 (benzene) pKa units. Calculations on a larger linear heptaol (i.e., (HOCH2CH2CH(OH)CH2CH(OH)CH2)2CHOH) reveal that the terminal hydroxyl groups each contribute 0.6 pKa units of stabilization in DMSO and 1.1 pKa units in benzene. All of these results taken together indicate that the presence of a charged center can provide a powerful energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN.

Shokri, Alireza; Wang, Yanping; O'Doherty, George A.; Wang, Xue B.; Kass, Steven R.

2013-11-27T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN. Citation: Shokri A, Y Wang, GA...

22

adhesively bonded shell: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various conditions, including the type of surface preparation, pH of the environmental media, (more) Xu, Dingying 2004-01-01 2 Bond Characteristics and Qualifications of...

23

Plasticity of hydrogen bond networks regulates mechanochemistry of cell adhesion complexes  

E-Print Network [OSTI]

Mechanical forces acting on cell adhesion receptor proteins regulate a range of cellular functions by formation and rupture of non-covalent interactions with ligands. Typically, force decreases the lifetimes of intact complexes (slip-bonds), making the discovery that these lifetimes can also be prolonged ("catch-bonds"), a surprise. We created a microscopic analytic theory by incorporating the structures of selectin and integrin receptors into a conceptual framework based on the theory of stochastic equations, which quantitatively explains a wide range of experimental data (including catch-bonds at low forces and slip-bonds at high forces). Catch-bonds arise due to force-induced remodeling of hydrogen bond networks, a finding that also accounts for unbinding in structurally unrelated integrin-fibronectin and actomyosin complexes. For the selectin family, remodeling of hydrogen bond networks drives an allosteric transition resulting in the formation of maximum number of hydrogen bonds determined only by the structure of the receptor and is independent of the ligand. A similar transition allows us to predict the increase in number of hydrogen bonds in a particular allosteric state of $\\alpha_5 \\beta_1$ integrin-fibronectin complex, a conformation which is yet to be crystallized. We also make a testable prediction that a single point mutation (Tyr51Phe) in the ligand associated with selectin should dramatically alter the nature of the catch-bond compared to the wild type. Our work suggests that nature utilizes a ductile network of hydrogen bonds to engineer function over a broad range of forces.

Shaon Chakrabarti; Michael Hinczewski; D. Thirumalai

2014-06-12T23:59:59.000Z

24

aliphatic ch bonds: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2015-01-01 39 H-atom high-n Rydberg time-of-flight spectroscopy of CH bond fission in acrolein dissociated at 193 nm Chemistry Websites Summary: H-atom high-n Rydberg...

25

Tyrosine B10 triggers a heme propionate hydrogen bonding network loop with glutamine E7 moiety  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer H-bonding network loop by PheB10Tyr mutation is proposed. Black-Right-Pointing-Pointer The propionate group H-bonding network restricted the flexibility of the heme. Black-Right-Pointing-Pointer The hydrogen bonding interaction modulates the electron density of the iron. Black-Right-Pointing-Pointer Propionate H-bonding network loop explains the heme-ligand stabilization. -- Abstract: Propionates, as peripheral groups of the heme active center in hemeproteins have been described to contribute in the modulation of heme reactivity and ligand selection. These electronic characteristics prompted the question of whether the presence of hydrogen bonding networks between propionates and distal amino acids present in the heme ligand moiety can modulate physiological relevant events, like ligand binding association and dissociation activities. Here, the role of these networks was evaluated by NMR spectroscopy using the hemoglobin I PheB10Tyr mutant from Lucina pectinata as model for TyrB10 and GlnE7 hemeproteins. {sup 1}H-NMR results for the rHbICN PheB10Tyr derivative showed chemical shifts of TyrB10 OH{eta} at 31.00 ppm, GlnE7 N{sub {epsilon}1}H/N{sub {epsilon}2}H at 10.66 ppm/-3.27 ppm, and PheE11 C{sub {delta}}H at 11.75 ppm, indicating the presence of a crowded, collapsed, and constrained distal pocket. Strong dipolar contacts and inter-residues crosspeaks between GlnE7/6-propionate group, GlnE7/TyrB10 and TyrB10/CN suggest that this hydrogen bonding network loop between GlnE7, TyrB10, 6-propionate group, and the heme ligand contribute significantly to the modulation of the heme iron electron density as well as the ligand stabilization mechanism. Therefore, the network loop presented here support the fact that the electron withdrawing character of the hydrogen bonding is controlled by the interaction of the propionates and the nearby electronic environments contributing to the modulation of the heme electron density state. Thus, we hypothesize that in hemeproteins with similar electrostatic environment the flexibility of the heme-6-propionate promotes a hydrogen bonding network loop between the 6-propionate, the heme ligand and nearby amino acids, tailoring in this way the electron density in the heme-ligand moiety.

Ramos-Santana, Brenda J., E-mail: brenda.ramos@upr.edu [Department of Chemistry, University of Puerto Rico, Mayagueez Campus, P.O. Box 9019, Mayagueez 00681-9019 (Puerto Rico); Lopez-Garriga, Juan, E-mail: juan.lopez16@upr.edu [Department of Chemistry, University of Puerto Rico, Mayagueez Campus, P.O. Box 9019, Mayagueez 00681-9019 (Puerto Rico)] [Department of Chemistry, University of Puerto Rico, Mayagueez Campus, P.O. Box 9019, Mayagueez 00681-9019 (Puerto Rico)

2012-08-10T23:59:59.000Z

26

Computational Design of a New Hydrogen Bond Network and at Least a 300-fold Specificity  

E-Print Network [OSTI]

Computational Design of a New Hydrogen Bond Network and at Least a 300-fold Specificity Switch, conformational strain, and packing defects yielded new binding partners that exhibited specificities of at least of similar structure and sequence. Simple rules to identify protein recognition sites and predict energetic

Baker, David

27

E-Print Network 3.0 - adhesively bonded lap Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The lap-shear strengths of adhesively bonded polystyrene (PS), high-density polyethylene (HDPE... bonded in a lap-shear geometry. The bonded area of adhesion was nominally...

28

E-Print Network 3.0 - affects durably bonding Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

adhesive layers are less affected, creep behavior of adhesively bonded joints... ABSTRACT SMITH, GLEN. Bond Characteristics and Qualifications of Adhesives for ... Source:...

29

E-Print Network 3.0 - adhesive bond strength Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The lap-shear strengths of adhesively bonded polystyrene (PS), high-density polyethylene (HDPE... 12;strength of the substrate, or the adhesive strength of the bond 9....

30

E-Print Network 3.0 - amide bonds stabilize Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Amide-Amide and Amide-Water Hydrogen Bonds Summary: Bonds: Implicationsfor Protein Folding and Stability Eric S.Eberhardt and Ronald T. Rained Department... folds, many of...

31

E-Print Network 3.0 - amide bond formation Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Irvine Collection: Chemistry 3 J. Am. Chem. SOC.1994,116,2149-2150 Amide-Amide and Amide-Water Hydrogen Bonds Summary: of hydrogen bonds observed here therefore suggests that...

32

E-Print Network 3.0 - aryl-metal bond chemistry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

metal bond chemistry Search Powered by Explorit Topic List Advanced Search Sample search results for: aryl-metal bond chemistry Page: << < 1 2 3 4 5 > >> 1 Subscriber access...

33

Critical percolation phase and thermal Berezinskii-Kosterlitz-Thouless transition in a scale-free network with short-range and long-range random bonds  

E-Print Network [OSTI]

Percolation in a scale-free hierarchical network is solved exactly by renormalization-group theory in terms of the different probabilities of short-range and long-range bonds. A phase of critical percolation, with algebraic ...

Berker, A. Nihat

34

E-Print Network 3.0 - adhesively bonded aluminum Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Centre de mathmatiques Collection: Mathematics 22 ELASTIC-PLASTIC MODE-II FRACTURE OF ADHESIVE JOINTS Summary: unit width) needed to deform an adhesively-bonded...

35

E-Print Network 3.0 - anodically bonded glass-based Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science 32 APPLICATION OF MEMS TECHNOLOGY TO MICRO DIRECT METHANOL FUEL CELL Xiaowei Liu* Summary: , and anodic bonding. The starting material were two pieces of 3 in....

36

alkane c-h bond: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

37

arene c-h bonds: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

38

E-Print Network 3.0 - actinidecarbon triple bonds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Adhesives that bond metals, plastics, FRP and other ... Source: Collection: Engineering 84 The accuracy of ab initio molecular geometries for systems containing second-row...

39

adhesive bonding high-alumina: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various conditions, including the type of surface preparation, pH of the environmental media, (more) Xu, Dingying 2004-01-01 2 Bond Characteristics and Qualifications of...

40

Combined CL/EBIC/DLTS investigation of a regular dislocation network formed by Si wafer direct bonding  

SciTech Connect (OSTI)

Electrical levels of the dislocation network in Si and recombination processes via these levels were studied by means of the combination of grain-boundary deep level transient spectroscopy, grain-boundary electron beam induced current (GB-EBIC) and cathodoluminescence (CL). It was found two deep level traps and one shallow trap existed at the interface of the bonded interface; these supply the recombination centers for carriers. The total recombination probability based on GB-EBIC data increased with the excitation level monotonically; however, the radiative recombination based on D1-D2 CL data exhibited a maximum at a certain excitation level. By applying an external bias across the bonded interface, the CL signal of D-lines was enhanced dramatically. These results are consistent with our models about two channels of recombination via the trap levels.

Yu, X. [IHP (Germany); Vyvenko, O. [IHP/BTU Joint Lab (Germany); Kittler, M.; Seifert, W. [IHP (Germany); Mtchedlidze, T. [IHP/BTU Joint Lab (Germany); Arguirov, T. [IHP (Germany); Reiche, M. [MPI fuer Mikrostrukturphysik (Germany)

2007-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

The Tri--Methane Rearrangement  

E-Print Network [OSTI]

The Tri--Methane Rearrangement #12;Cirkva, Vladimir; Zuraw, Michael J.; Zimmerman, Howard E.* Department of Chemistry, University of Wisconsin, Madison, WI 53706 #12;INTRODUCTION The tri--methane of a cyclopentene 5a, but only in crystalline medium. However, in the solution photochemistry of tri--methane system

Cirkva, Vladimir

42

The Tri--Methane Rearrangement  

E-Print Network [OSTI]

The Tri--Methane Rearrangement #12;Církva, Vladimír; Zuraw, Michael J.; Zimmerman, Howard E.* Department of Chemistry, University of Wisconsin, Madison, WI 53706 #12;INTRODUCTION The tri--methane of a cyclopentene 5a, but only in crystalline medium. However, in the solution photochemistry of tri--methane system

Cirkva, Vladimir

43

E-Print Network 3.0 - ag au bonded Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ag, Au, and Pb were deposited onto the 7 7 surface at low temperature 95 K .5... of a silicide within 12 ML with bonding characteristics of p-d hybridization.29-33 The Si-Au...

44

E-Print Network 3.0 - azo covalent bond Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Materials Science ; Chemistry 76 1,4-Dimethyl-l,4,5,6-hexahydro-l,2,3,4-tetrazine. A Cyclic cis-2-Tetrazene Summary: the N2-C bond in position for a large interaction...

45

altered intramolecular hydrogen-bonding: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

altered intramolecular hydrogen-bonding First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Dynamic Role of...

46

anionic hydrogen-bonded complexes: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

anionic hydrogen-bonded complexes First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 The Effects of...

47

amine-nitro hydrogen-bond geometry: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

amine-nitro hydrogen-bond geometry First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 A new...

48

Tight Bounds for Influence in Diffusion Networks and Application to Bond Percolation and Epidemiology  

E-Print Network [OSTI]

In this paper, we derive theoretical bounds for the long-term influence of a node in an Independent Cascade Model (ICM). We relate these bounds to the spectral radius of a particular matrix and show that the behavior is sub-critical when this spectral radius is lower than $1$. More specifically, we point out that, in general networks, the sub-critical regime behaves in $O(\\sqrt{n})$ where $n$ is the size of the network, and that this upper bound is met for star-shaped networks. We apply our results to epidemiology and percolation on arbitrary networks, and derive a bound for the critical value beyond which a giant connected component arises. Finally, we show empirically the tightness of our bounds for a large family of networks.

Lemonnier, Remi; Vayatis, Nicolas

2014-01-01T23:59:59.000Z

49

Structural Rearrangements in Water Viewed Through Two- Dimensional Infrared Spectroscopy  

E-Print Network [OSTI]

Compared with other molecular liquids, water is highly structured because of its ability to form up to four hydrogen bonds, resulting in a tetrahedral network of molecules. However, this underlying intermolecular structure ...

Roberts, Sean Thomas

50

New anticancer antibiotic acts through diradical rearrangement  

SciTech Connect (OSTI)

This paper reports that chemists have found and characterized an anticancer antibiotic, dynemicin A, that may be the fouth of a series of antibiotics that act by metabolic rearrangement to a diradical. If true, diradical precursors may represent an antibiotic strategy that evolved widely in nature. And, there may be many more anticancer antibiotics awaiting discovery. Also, the unique internal trigger that seems to set off the dynemicin rearrangement gives chemists a new understanding of how these compounds work. If, indeed, the anthraquinone nucleus in dynemicin A binds by intercalation between strands of DNA as is now thought, chemists will learn more about how to deliver drugs to specific sites.

Stinson, S. (C and EN, Washington, DC (US))

1990-05-28T23:59:59.000Z

51

Does fluoride disrupt hydrogen bond network in cationic lipid bilayer? Time-dependent fluorescence shift of Laurdan and molecular dynamics simulations  

SciTech Connect (OSTI)

Time-dependent fluorescence shift (TDFS) of Laurdan embedded in phospholipid bilayers reports on hydration and mobility of the phospholipid acylgroups. Exchange of H{sub 2}O with D{sub 2}O prolongs the lifetime of lipid-water and lipid-water-lipid interactions, which is reflected in a significantly slower TDFS kinetics. Combining TDFS measurements in H{sub 2}O and D{sub 2}O hydrated bilayers with atomistic molecular dynamics (MD) simulations provides a unique tool for characterization of the hydrogen bonding at the acylgroup level of lipid bilayers. In this work, we use this approach to study the influence of fluoride anions on the properties of cationic bilayers composed of trimethylammonium-propane (DOTAP). The results obtained for DOTAP are confronted with those for neutral phosphatidylcholine (DOPC) bilayers. Both in DOTAP and DOPC H{sub 2}O/D{sub 2}O exchange prolongs hydrogen-bonding lifetime and does not disturb bilayer structure. These results are confirmed by MD simulations. TDFS experiments show, however, that for DOTAP this effect is cancelled in the presence of fluoride ions. We interpret these results as evidence that strongly hydrated fluoride is able to steal water molecules that bridge lipid carbonyls. Consequently, when attracted to DOTAP bilayer, fluoride disrupts the local hydrogen-bonding network, and the differences in TDFS kinetics between H{sub 2}O and D{sub 2}O hydrated bilayers are no longer observed. A distinct behavior of fluoride is also evidenced by MD simulations, which show different lipid-ion binding for Cl{sup ?} and F{sup ?}.

Pokorna, Sarka; Jurkiewicz, Piotr; Hof, Martin, E-mail: martin.hof@jh-inst.cas.cz [J. Heyrovsk Institute of Physical Chemistry of the Academy of Sciences of the Czech Republic v.v.i., Dolejskova 3, 18223 Prague 8 (Czech Republic); Vazdar, Mario [Division of Organic Chemistry and Biochemistry, Rudjer Bokovi? Institute, P.O.B. 180, HR-10002 Zagreb (Croatia); Cwiklik, Lukasz [J. Heyrovsk Institute of Physical Chemistry of the Academy of Sciences of the Czech Republic v.v.i., Dolejskova 3, 18223 Prague 8 (Czech Republic); Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nm. 2, 16610 Prague 6 (Czech Republic); Jungwirth, Pavel [Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nm. 2, 16610 Prague 6 (Czech Republic); Department of Physics, Tampere University of Technology, P.O. Box 692, FI-33101 Tampere (Finland)

2014-12-14T23:59:59.000Z

52

Probing the hydrogen-bond network of water via time-resolved soft x-ray spectroscopy  

SciTech Connect (OSTI)

We report time-resolved studies of hydrogen bonding in liquid H2O, in response to direct excitation of the O-H stretch mode at 3 mu m, probed via soft x-ray absorption spectroscopy at the oxygen K-edge. This approach employs a newly developed nanofluidic cell for transient soft x-ray spectroscopy in liquid phase. Distinct changes in the near-edge spectral region (XANES) are observed, and are indicative of a transient temperature rise of 10K following transient laser excitation and rapid thermalization of vibrational energy. The rapid heating occurs at constant volume and the associated increase in internal pressure, estimated to be 8MPa, is manifest by distinct spectral changes that differ from those induced by temperature alone. We conclude that the near-edge spectral shape of the oxygen K-edge is a sensitive probe of internal pressure, opening new possibilities for testing the validity of water models and providing new insight into the nature of hydrogen bonding in water.

Huse, Nils; Wen, Haidan; Nordlund, Dennis; Szilagyi, Erzsi; Daranciang, Dan; Miller, Timothy A.; Nilsson, Anders; Schoenlein, Robert W.; Lindenberg, Aaron M.

2009-04-24T23:59:59.000Z

53

Rearrangement, Convection and Competition Yann BRENIER  

E-Print Network [OSTI]

steps) 500 grid points in x, heat profile y(t, x) versus x drawn every 2 time steps 0 0.2 0.4 0.6 0.8 1.2)2) - exp(-20(x - 0.4)2) t, x [0, 1] h = 0.005 (= 200 time steps) 500 grid points in x, heat profile y(t, x #12;A function and its rearrangement N = 200 grid points in x 0.6 0.8 1 1.2 1.4 1.6 1.8 2 0 0.1 0.2 0

Brenier, Yann

54

The Tri--methane Rearrangement: Mechanistic and Exploratory Organic  

E-Print Network [OSTI]

The Tri--methane Rearrangement: Mechanistic and Exploratory Organic Photochemistry1 Howard E zimmerman@bert.chem.wisc.edu Received May 31, 2000 ABSTRACT The di--methane rearrangement is firmly established as a mode of synthesizing three-membered-ring compounds. We now report the tri-- methane

Cirkva, Vladimir

55

Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional Vibrational Stimulated Echoes  

E-Print Network [OSTI]

Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional, USA (Received 24 February 2003; published 3 December 2003) Hydrogen bond dynamics are explicated hydrogen bonded network are measured with ultrashort (

Fayer, Michael D.

56

Investing in Bonds  

E-Print Network [OSTI]

Bonds, which are issued by governments and corporations, can be an important part of one's investment portfolio. U.S. government bonds, municipal bonds, zero-coupon bonds and other types are described. Also learn strategies for coping with inflation...

Johnson, Jason; Polk, Wade

2002-08-12T23:59:59.000Z

57

Rearrangement and annihilation in antihydrogen-atom scattering  

SciTech Connect (OSTI)

I review some results for annihilation and rearrangement processes in low-energy antihydrogen-hydrogen and antihydrogen-helium scattering. For the strong nuclear force results using a {delta}-function potential are compared to a scattering length approach. It is found that the {delta}-function potential does not give correct annihilation cross sections in the case of antihydrogen-helium scattering. Problem associated with the use of the Born-Oppenheimer approximation for rearrangement calculations are reviewed.

Jonsell, Svante [Department of Physics, Swansea University, Singleton Park, Swansea SA2 8PP (United Kingdom)

2008-08-08T23:59:59.000Z

58

Ultrafast infrared studies of complex ligand rearrangements in solution  

SciTech Connect (OSTI)

The complete description of a chemical reaction in solution depends upon an understanding of the reactive molecule as well as its interactions with the surrounding solvent molecules. Using ultrafast infrared spectroscopy it is possible to observe both the solute-solvent interactions and the rearrangement steps which determine the overall course of a chemical reaction. The topics addressed in these studies focus on reaction mechanisms which require the rearrangement of complex ligands and the spectroscopic techniques necessary for the determination of these mechanisms. Ligand rearrangement is studied by considering two different reaction mechanisms for which the rearrangement of a complex ligand constitutes the most important step of the reaction. The first system concerns the rearrangement of a cyclopentadienyl ring as the response of an organometallic complex to a loss of electron density. This mechanism, commonly referred to as ''ring slip'', is frequently cited to explain reaction mechanisms. However, the ring slipped intermediate is too short-lived to be observed using conventional methods. Using a combination of ultrafast infrared spectroscopy and electronic structure calculations it has been shown that the intermediate exists, but does not form an eighteen-electron intermediate as suggested by traditional molecular orbital models. The second example examines the initial steps of alkyne polymerization. Group 6 (Cr, Mo, W) pentacarbonyl species are generated photolytically and used to catalyze the polymerization of unsaturated hydrocarbons through a series of coordination and rearrangement steps. Observing this reaction on the femto- to millisecond timescale indicates that the initial coordination of an alkyne solvent molecule to the metal center results in a stable intermediate that does not rearrange to form the polymer precursor. This suggests that polymerization requires the dissociation of additional carbonyl ligands before rearrangement can occur. Overall, this research demonstrates the importance of examining reaction dynamics on the ultrafast timescale. In the case of both ring slip and alkyne polymerization, early time dynamics have been invaluable in understanding the exact reaction mechanisms which show important differences from previously accepted models.

Payne, Christine K.

2003-05-31T23:59:59.000Z

59

Network analysis of proton transfer in liquid water  

SciTech Connect (OSTI)

Proton transfer in macromolecular systems is a fascinating yet elusive process. In the last ten years, molecular simulations have shown to be a useful tool to unveil the atomistic mechanism. Notwithstanding, the large number of degrees of freedom involved make the accurate description of the process very hard even for the case of proton diffusion in bulk water. Here, multi-state empirical valence bond molecular dynamics simulations in conjunction with complex network analysis are applied to study proton transfer in liquid water. Making use of a transition network formalism, this approach takes into account the time evolution of several coordinates simultaneously. Our results provide evidence for a strong dependence of proton transfer on the length of the hydrogen bond solvating the Zundel complex, with proton transfer enhancement as shorter bonds are formed at the acceptor site. We identify six major states (nodes) on the network leading from the special pair to a more symmetric Zundel complex required for transferring the proton. Moreover, the second solvation shell specifically rearranges to promote the transfer, reiterating the idea that solvation beyond the first shell of the Zundel complex plays a crucial role in the process.

Shevchuk, Roman; Rao, Francesco, E-mail: francesco.rao@frias.uni-freiburg.de [Freiburg Institute for Advanced Studies, School of Soft Matter Research, Freiburg im Breisgau (Germany); Agmon, Noam [Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem (Israel)

2014-06-28T23:59:59.000Z

60

Ion Hydration and Associated Defects in Hydrogen Bond Network of Water: Observation of Reorientationally Slow Water Molecules Beyond First Hydration Shell in Aqueous Solutions of MgCl$_2$  

E-Print Network [OSTI]

Effects of presence of ions, at moderate to high concentrations, on dynamical properties of water molecules are investigated through classical molecular dynamics simulations using two well known non-polarizable water models. Simulations reveal that the presence of magnesium chloride (MgCl$_2$) induces perturbations in the hydrogen bond network of water leading to the formation of bulk-like domains with \\textquoteleft defect sites\\textquoteright~on boundaries of such domains: water molecules at such defect sites have less number of hydrogen bonds than those in bulk water. Reorientational autocorrelation functions for dipole vectors of such defect water molecules are computed at different concentrations of ions and compared with system of pure water. Earlier experimental and simulation studies indicate significant differences in reorientational dynamics for water molecules in the first hydration shell of many dissolved ions. Results of this study suggest that defect water molecules, which are beyond the first hydration shells of ions, also experience significant slowing down of reorientation times as a function of concentration in the case of MgCl$_2$. However, addition of cesium chloride(CsCl) to water does not perturb the hydrogen bond network of water significantly even at higher concentrations. This difference in behavior between MgCl$_2$ and CsCl is consistent with the well-known Hofmeister series.

Upayan Baul; Satyavani Vemparala

2014-12-18T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

additional chromosomal rearrangements: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

bats) correlate with predictable chromosomal structural changes (KFTkaryotypic fission theory). Chromosome studies (more) Kolnicki, Robin Lee 2012-01-01 448 Effect of chronic...

62

The Ties That Bond: Re-Examining the Relationship between Facebook Use and Bonding Social Capital  

E-Print Network [OSTI]

The Ties That Bond: Re-Examining the Relationship between Facebook Use and Bonding Social Capital established a positive relationship between measures of Facebook use and perceptions of social capital. Like other social network sites, Facebook is especially well-positioned to enhance users' bridging social

Michigan, University of

63

Surety Bond Program (Maryland)  

Broader source: Energy.gov [DOE]

The Surety Bond Program, a program of the Maryland Small Business Development Financing Authority, assists eligible small businesses in obtaining bid, performance or payment bonds necessary to...

64

Lithium Diisopropylamide-Mediated Ortholithiation and Anionic Fries Rearrangement of Aryl Carbamates: Role of  

E-Print Network [OSTI]

Lithium Diisopropylamide-Mediated Ortholithiation and Anionic Fries Rearrangement of Aryl of the lithium diisopropylamide (LDA)-mediated anionic Fries rearrangements of aryl carbamates are described, an LDA-lithium phenolate mixed dimer, and homoaggregated lithium phenolates. The highly insoluble

Collum, David B.

65

Reactive Rearrangement of Parts under Sensor Inaccuracy: Particle Filter Approach  

E-Print Network [OSTI]

Reactive Rearrangement of Parts under Sensor Inaccuracy: Particle Filter Approach Hal^uk Bayram, Electrical and Electronic Engineering Bogazici University, Bebek 34342 Istanbul Turkey Abstract-- The paper will be left undisturbed, the robot is required to employ a reactive strategy. A feedback-based event

66

Bond Financing (New Jersey)  

Broader source: Energy.gov [DOE]

Bond financing is available to eligible businesses through the New Jersey Economic Development Authority, in the amount of $500,000 to $10 million. The bonds can be used to finance capital...

67

Local Government Revenue Bonds (Montana)  

Broader source: Energy.gov [DOE]

Limited obligation local government bonds ("special revenue bonds") may be issued for qualified electric energy generation facilities, including those powered by renewables. These bonds generally...

68

Bonding thermoplastic polymers  

DOE Patents [OSTI]

We demonstrate a new method for joining patterned thermoplastic parts into layered structures. The method takes advantage of case-II permeant diffusion to generate dimensionally controlled, activated bonding layers at the surfaces being joined. It is capable of producing bonds characterized by cohesive failure while preserving the fidelity of patterned features in the bonding surfaces. This approach is uniquely suited to production of microfluidic multilayer structures, as it allows the bond-forming interface between plastic parts to be precisely manipulated at micrometer length scales. The bond enhancing procedure is easily integrated in standard process flows and requires no specialized equipment.

Wallow, Thomas I. (Fremont, CA); Hunter, Marion C. (Livermore, CA); Krafcik, Karen Lee (Livermore, CA); Morales, Alfredo M. (Livermore, CA); Simmons, Blake A. (San Francisco, CA); Domeier, Linda A. (Danville, CA)

2008-06-24T23:59:59.000Z

69

Chromosome-specific staining to detect genetic rearrangements  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ nucleic acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyzes. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML) and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray, Joe W.; Pinkel, Daniel; Tkachuk, Douglas; Westbrook, Carol

2013-04-09T23:59:59.000Z

70

Private Activity Revenue Bonds (Maryland)  

Broader source: Energy.gov [DOE]

Private Activity Revenue Bonds are available in the form of both taxable bonds and tax-exempt bonds. Both types of bonds provide access to long-term capital markets for fixed asset financing....

71

Rearranging the Exponential Wall for Large N-Body Systems  

SciTech Connect (OSTI)

The work required to solve for the fully interacting N boson wave function, which is widely believed to scale exponentially with N, is rearranged so the problem scales order by order in a perturbation series as N{sup 0}. The exponential complexity reappears in an exponential scaling with the order of our perturbation series allowing exact analytical calculations for very large N systems through low order.

Watson, Deborah K.; Dunn, Martin [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, Norman, Oklahoma 73019 (United States)

2010-07-09T23:59:59.000Z

72

Foreign trade zones and bonded warehouses for luxury goods  

E-Print Network [OSTI]

We explore and compare the benefits of establishing and operating Foreign Trade Zones (FTZs) and Bonded Warehouses (BWs) for luxury goods in North America, using the case of the distribution network of Ralph Lauren Corporation ...

Petrova, Nadya (Nadya Naydenova)

2013-01-01T23:59:59.000Z

73

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing...

74

Structures and Reactivity of Transition-Metal Compounds Featuring Metal-Ligand Multiple Bonds  

E-Print Network [OSTI]

isomers of product 2a-f. .................................................................. 89 Figure 34. The rearrangement between 2_iso6 and 2_iso3. ............................................. 92 Figure 35. The solvated ?G (kcal/mol) diagram... iso3 and iso6 for 2a-f (kcal/mol). ................ 91 Table 17. Results of energies differencesa between 2c_iso6 and 2c_iso3. ...................... 92 xv Table 18. Selected structural parameters of 2a from computations and experiments. (Bond...

Xu, Zhenggang

2014-07-25T23:59:59.000Z

75

Magnetic field re-arrangement after prominence eruption  

SciTech Connect (OSTI)

It has long been known that magnetic reconnection plays a fundamental role in a variety of solar events. Although mainly invoked in flare problems, large-scale loops interconnecting active regions, evolving coronal hole boundaries, the solar magnetic cycle itself, provide different evidence of phenomena which involve magnetic reconnection. A further example might be given by the magnetic field rearrangement which occurs after the eruption of a prominence. Since most often a prominence reforms after its disappearance and may be observed at about the same position it occupied before erupting, the magnetic field has to undergo a temporary disruption to relax back, via reconnection, to a configuration similar to the previous one. The above sequence of events is best observable in the case of two-ribbon (2-R) flares but most probably is associated with all filament eruptions. Even if the explanation of the magnetic field rearrangement after 2-R flares in terms of reconnection is generally accepted, the lack of a three-dimensional model capable of describing the field reconfiguration, has prevented, up to now, a thorough analysis of its topology as traced by H..cap alpha../x-ray loops. The purpose of the present work is to present a numerical technique which enables one to predict and visualize the reconnected configuration, at any time t, and therefore allows one to make a significant comparison of observations and model predictions throughout the whole process. 5 refs., 3 figs.

Kopp, R.A.; Poletto, G.

1986-01-01T23:59:59.000Z

76

Compositions and methods for detecting gene rearrangements and translocations  

DOE Patents [OSTI]

Disclosed is a series of nucleic acid probes for use in diagnosing and monitoring certain types of leukemia using, e.g., Southern and Northern blot analyses and fluorescence in situ hybridization (FISH). These probes detect rearrangements, such as translocations involving chromosome band 11q23 with other chromosomes bands, including 4q21, 6q27, 9p22, 19p13.3, in both dividing leukemic cells and interphase nuclei. The breakpoints in all such translocations are clustered within an 8.3 kb BamHI genomic region of the MLL gene. A novel 0.7 kb BamH1 cDNA fragment derived from this gene detects rearrangements on Southern blot analysis with a single BamHI restriction digest in all patients with the common 11q23 translocations and in patients with other 11q23 anomalies. Northern blot analyses are presented demonstrating that the MLL gene has multiple transcripts and that transcript size differentiates leukemic cells from normal cells. Also disclosed are MLL fusion proteins, MLL protein domains and anti-MLL antibodies.

Rowley, Janet D. (Chicago, IL); Diaz, Manuel O. (Chicago, IL)

2000-01-01T23:59:59.000Z

77

2370 J. Am. Chem. SOC.1985, 107, 2370-2373 Alternative Fe-02 Bond Lengths in O2Adducts of Iron  

E-Print Network [OSTI]

, and four pyrrole N). For the 2-MeIm complex at -150 "C, the Fe-O distance was 1.90 A, in agreement with X by rearrangement to a short Fe-0 bonded structure. The synthesis and study of synthetic analogues to 0, binding

Suslick, Kenneth S.

78

Qualified Energy Conservation Bonds (QECBs) - State Issues &...  

Broader source: Energy.gov (indexed) [DOE]

Qualified Energy Conservation Bonds (QECBs) - State Issues & Approaches Qualified Energy Conservation Bonds (QECBs) - State Issues & Approaches Qualified Energy Conservation Bonds...

79

Wafer-Level Thermocompression Bonds  

E-Print Network [OSTI]

Thermocompression bonding of gold is a promising technique for achieving low temperature, wafer-level bonding without the application of an electric field or complicated pre-bond cleaning procedure. The presence of a ductile ...

Tsau, Christine H.

80

Bond Financing Program (New Hampshire)  

Broader source: Energy.gov [DOE]

BFAs Bond Financing Program offers tax-exempt and taxable bonds for fixed-asset expansion projects. Industrial development revenue bonds can be used by manufacturers for the acquisition,...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Low Temperature Material Bonding Technique  

DOE Patents [OSTI]

A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

2000-10-10T23:59:59.000Z

82

Low temperature material bonding technique  

DOE Patents [OSTI]

A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

2002-02-12T23:59:59.000Z

83

Green Infrastructure Bonds (Hawaii)  

Broader source: Energy.gov [DOE]

In July 2013, Hawaii enacted legislation allowing the Department of Business, Economic Development, and Tourism to issue Green Infrastructure Bonds to secture low-cost financing for clean energy...

84

Bonding aerogels with polyurethanes  

SciTech Connect (OSTI)

Aerogels, porous silica glasses with ultra-fine cell size (30nm), are made by a solution gelation (sol-gel) process. The resulting gel is critical point dried to densities from 0.15--0.60 g/cc. This material is machinable, homogeneous, transparent, coatable and bondable. To bond aerogel an adhesive should have long cure time, no attack on the aerogel structure, and high strength. Several epoxies and urethanes were examined to determine if they satisfied these conditions. Bond strengths above 13 psi were found with double bubble and DP-110 epoxies and XI-208/ODA-1000 and Castall U-2630 urethanes. Hardman Kalex Tough Stuff'' A-85 hardness urethane gave 18 psi bond strength. Hardman A-85, Tuff-Stuff'' was selected for further evaluation because it produced bond strengths comparable to the adherend cohesive strength. 5 refs., 2 figs.

Matthews, F.M.; Hoffman, D.M.

1989-11-01T23:59:59.000Z

85

Water's Hydrogen Bond Strength  

E-Print Network [OSTI]

Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

Martin Chaplin

2007-06-10T23:59:59.000Z

86

Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Tobias Steinel, John B. Asbury, Junrong Zheng, and M. D. Fayer*  

E-Print Network [OSTI]

Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Tobias Steinel, John B. Asbury of picoseconds, observe hydrogen bond breaking and monitor the equilibration of the hydrogen bond network in water. In addition, the vibrational lifetime, the time constant for hydrogen bond breaking, and the rate

Fayer, Michael D.

87

Thread bonds in molecules  

E-Print Network [OSTI]

Unusual chemical bonds are proposed. Each bond is almost covalent but is characterized by the thread of a small radius $\\sim 0.6\\times 10^{-11}$cm, between two nuclei in a molecule. The main electron density is concentrated outside the thread as in a covalent bond. The thread is formed by the electron wave function which has a tendency to be singular on it. The singularity along the thread is cut off by electron "vibrations" due to the interaction with zero point electromagnetic oscillations. The electron energy has its typical value of (1-10)eV. Due to the small tread radius the uncertainty of the electron momentum inside the thread is large resulting in a large electron kinetic energy $\\sim 1 MeV$. This energy is compensated by formation of a potential well due to the reduction of the energy of electromagnetic zero point oscillations. This is similar to formation of a negative van der Waals potential. Thread bonds are stable and cannot be created or destructed in chemical or optical processes.

Ivlev, B

2015-01-01T23:59:59.000Z

88

Atomic origin of hysteresis during cyclic loading of Si due to bond rearrangements at the crack surfaces  

E-Print Network [OSTI]

that invokes mechanically induced subcritical cracking to explain the delayed onset of failure. © 2005 American associated with a larger initial flaw, which is assumed to be caused by subcritical crack growth, 5- time during high cycle fatigue if water is present, and 6 a fatigue lifetime that depends only

Carter, Emily A.

89

Effects of structural rearrangements on sorption capacity of coals  

SciTech Connect (OSTI)

Recently, the problems in practical application of experimental data and modeling to the sequestration of carbon dioxide in coal seams and the concurrent enhanced coalbed methane (ECBM) recovery have underscored the need for new approaches that take into account the ability of coal for structural rearrangements. Areas of interest include plasticization of coal due to CO2 dissolution, the effect of coal swelling on estimation of the capacity of a coal-seam to adsorb CO2 (adsorption isotherm), and the stability of the CO2 saturated phase once formed, especially with respect to how it might be affected by changes in the post-sequestration environment (environmental effects). Coals are organic macromolecular systems well known to imbibe organic liquids and carbon dioxide. CO2 dissolves in coals and swells them. The problems become more prominent in the region of supercritical CO2. We investigated the effects of moisture content and pressure cycling history on temporal changes in the coal sorptive capacity for a set of Argonne premium coals. The samples were tested as received, dried at 80oC for 36 hours, and moisture equilibrated at 96-97% RH and 30oC for 48 hours. The powders were compared to core samples. Additionally, plasticization of coal powders was studied by high pressure dilatometer.

Romanov, Vyacheslav; Soong, Yee; Warzinski, R.P.; Lynn, R.J.

2006-09-01T23:59:59.000Z

90

Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed by Ultrafast Infrared Spectroscopy  

E-Print Network [OSTI]

Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed hydrogen-bond network with nearby amino acid side chains, including a highly conserved tyrosine and glutamine. The participation of particular amino acid side chains in the ultrafast hydrogen-bond switching

van Stokkum, Ivo

91

Claisen Rearrangement of Graphite Oxide: A Route to Covalently Functionalized Graphenes  

E-Print Network [OSTI]

On the GO: The basal plane allylic alcohol functionality of graphite oxide (GO) can be converted into N,N-dimethylamide groups through an EschenmoserClaisen sigmatropic rearrangement by using N,N-dimethylacetamide dimethyl ...

Collins, William R.

92

Economic Development Bond Program (Iowa)  

Broader source: Energy.gov [DOE]

Through its Economic Development Bond Program, the Iowa Finance Authority (IFA) issues tax-exempt bonds on behalf of private entities or organizations for eligible purposes. The responsibility for...

93

Private Activity Bond Allocation (Missouri)  

Broader source: Energy.gov [DOE]

The Private Activity Bond Allocation Program provides low-interest financing through tax-exempt bonds for certain types of projects, including electric and gas utility projects. Eligible applicants...

94

Albert Bond | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bond - Project Officer, Golden Field Office Albert Bond is a Project Officer at the Golden Field Office. Most Recent New Choctaw Nation Recycling Center Posts Quick Results March 8...

95

Bond and Loan Program (Arkansas)  

Broader source: Energy.gov [DOE]

The Bond and Loan programs of Arkansas are four programs designed to attract small business development within the state.

96

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatusButlerTransportation From modelingTrending: Metal Oxo Bonds

97

Collective Hydrogen Bond Reorganization in Water Studied with Temperature-Dependent Ultrafast Infrared Spectroscopy  

E-Print Network [OSTI]

We use temperature-dependent ultrafast infrared spectroscopy of dilute HOD in H2O to study the picosecond reorganization of the hydrogen bond network of liquid water. Temperature-dependent two-dimensional infrared (2D IR), ...

Nicodemus, Rebecca A.

98

Mourning 2.0: Continuing Bonds between the Living and the Dead on Facebook  

E-Print Network [OSTI]

This study examines the burgeoning phenomenon of Facebook memorial pages and how this research about dynamic, online social networking environments can contribute to the existing literature related to Klass et al's (1996) continuing bonds thesis...

Irwin, Melissa D.

2012-05-31T23:59:59.000Z

99

Hydrogen bond reorganization and vibrational relaxation in water studied with ultrafast infrared spectroscopy  

E-Print Network [OSTI]

Water consists of an extended hydrogen bond network that is constantly evolving. More than just a description of the time averaged structure is necessary to understand any process that occurs in water. In this thesis we ...

Nicodemus, Rebecca Anne

2011-01-01T23:59:59.000Z

100

Solder extrusion pressure bonding process and bonded products produced thereby  

DOE Patents [OSTI]

Disclosed is a process for production of soldered joints which are highly reliable and capable of surviving 10,000 thermal cycles between about [minus]40 C and 110 C. Process involves interposing a thin layer of a metal solder composition between the metal surfaces of members to be bonded and applying heat and up to about 1000 psi compression pressure to the superposed members, in the presence of a reducing atmosphere, to extrude the major amount of the solder composition, contaminants including fluxing gases and air, from between the members being bonded, to form a very thin, strong intermetallic bonding layer having a thermal expansion tolerant with that of the bonded members.

Beavis, L.C.; Karnowsky, M.M.; Yost, F.G.

1992-06-16T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Solder extrusion pressure bonding process and bonded products produced thereby  

DOE Patents [OSTI]

Production of soldered joints which are highly reliable and capable of surviving 10,000 thermal cycles between about -40.degree. C. and 110.degree. C. Process involves interposing a thin layer of a metal solder composition between the metal surfaces of members to be bonded and applying heat and up to about 1000 psi compression pressure to the superposed members, in the presence of a reducing atmosphere, to extrude the major amount of the solder composition, contaminants including fluxing gases and air, from between the members being bonded, to form a very thin, strong intermetallic bonding layer having a thermal expansion tolerant with that of the bonded members.

Beavis, Leonard C. (Albuquerque, NM); Karnowsky, Maurice M. (Albuquerque, NM); Yost, Frederick G. (Ceder Crest, NM)

1992-01-01T23:59:59.000Z

102

Vacuum fusion bonding of glass plates  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

103

Vacuum fusion bonding of glass plates  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2000-01-01T23:59:59.000Z

104

Qualified Energy Conservation Bonds (Ohio)  

Broader source: Energy.gov [DOE]

The Ohio Air Quality Development Authority (OAQDA) administers the Qualified Energy Conservation Bonds (QECB) program in Ohio. QECBs have been used by local governments and public universities to...

105

Investigation of bonding strength and sealing behavior of aluminum/stainless steel bonded at room temperature  

E-Print Network [OSTI]

], spark welding [3], explosive bonding [4], and diffusion bonding [5,6]. However, the processing such as diffusion bonding [5,6], friction welding [7e11], vacuum roll bonding [12] and hot roll bonding [13Investigation of bonding strength and sealing behavior of aluminum/stainless steel bonded at room

Howlader, Matiar R

106

Chromosomal Rainbows detect Oncogenic Rearrangements of Signaling Molecules in Thyroid Tumors  

SciTech Connect (OSTI)

Altered signal transduction can be considered a hallmark of many solid tumors. In thyroid cancers the receptor tyrosine kinase (rtk) genes NTRK1 (Online Mendelian Inheritance in Man = OMIM *191315, also known as 'TRKA'), RET ('Rearranged during Transfection protooncogene', OMIM *164761) and MET (OMIM *164860) have been reported as activated, rearranged or overexpressed. In many cases, a combination of cytogenetic and molecular techniques allows elucidation of cellular changes that initiate tumor development and progression. While the mechanisms leading to overexpression of the rtk MET gene remain largely unknown, a variety of chromosomal rearrangements of the RET or NTKR1 gene could be demonstrated in thyroid cancer. Abnormal expressions in these tumors seem to follow a similar pattern: the rearrangement translocates the 3'-end of the rtk gene including the entire catalytic domain to an expressed gene leading to a chimeric RNA and protein with kinase activity. Our research was prompted by an increasing number of reports describing translocations involving ret and previously unknown translocation partners. We developed a high resolution technique based on fluorescence in situ hybridization (FISH) to allow rapid screening for cytogenetic rearrangements which complements conventional chromosome banding analysis. Our technique applies simultaneous hybridization of numerous probes labeled with different reporter molecules which are distributed along the target chromosome allowing the detection of cytogenetic changes at near megabase-pair (Mbp) resolution. Here, we report our results using a probe set specific for human chromosome 10, which is altered in a significant portion of human thyroid cancers (TC's). While rendering accurate information about the cytogenetic location of rearranged elements, our multi-locus, multi-color analysis was developed primarily to overcome limitations of whole chromosome painting (WCP) and chromosome banding techniques for fine mapping of breakpoints in papillary thyroid cancer (PTC).

O'Brien, Benjamin; Jossart, Gregg H.; Ito, Yuko; Greulich-Bode, Karin M.; Weier, Jingly F.; Munne, Santiago; Clark, Orlo H.; Weier, Heinz-Ulrich G.

2010-08-19T23:59:59.000Z

107

Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat Cornell Batteries &NSTCurrent Issues &Network » Network

108

Application of exterior complex scaling to positron-hydrogencollisions including rearrangement  

SciTech Connect (OSTI)

The first application of an exterior complex scaling method to an atomic scattering problem with distinct rearrangement channels is reported. Calculations are performed for positron-hydrogen collisions in an s-wave model employing an electron-positron potential of V{sub 12} = -(8+(r{sub 1}-r{sub 2}){sup 2}){sup 1/2}, using the time-independent propagating exterior complex scaling (PECS) method. This potential has the correct long-range Coulomb tail of the full problem and the results demonstrate that ECS-based methods can accurately calculate scattering, ionization and positronium formation cross sections in this three-body rearrangement collision.

Bartlett, Philip L.; Stelbovics, Andris T.; Rescigno, Thomas N.; McCurdy, C. William

2007-12-06T23:59:59.000Z

109

Tuning by pruning: exploiting disorder for global response and the principle of bond-level independence  

E-Print Network [OSTI]

We exploit the intrinsic difference between disordered and crystalline solids to create systems with unusual and exquisitely tuned mechanical properties. To demonstrate the power of this approach, we design materials that are either virtually incompressible or completely auxetic. Disordered networks can be efficiently driven to these extreme limits by removing a very small fraction of bonds via a selected-bond removal procedure that is both simple and experimentally relevant. The procedure relies on the nearly complete absence of any correlation between the contributions of an individual bond to different elastic moduli. A new principle unique to disordered solids underlies this lack of correlation: independence of bond-level response.

Carl P. Goodrich; Andrea J. Liu; Sidney R. Nagel

2015-02-13T23:59:59.000Z

110

Quantum Confinement in Hydrogen Bond  

E-Print Network [OSTI]

In this work, the quantum confinement effect is proposed as the cause of the displacement of the vibrational spectrum of molecular groups that involve hydrogen bonds. In this approach the hydrogen bond imposes a space barrier to hydrogen and constrains its oscillatory motion. We studied the vibrational transitions through the Morse potential, for the NH and OH molecular groups inside macromolecules in situation of confinement (when hydrogen bonding is formed) and non-confinement (when there is no hydrogen bonding). The energies were obtained through the variational method with the trial wave functions obtained from Supersymmetric Quantum Mechanics (SQM) formalism. The results indicate that it is possible to distinguish the emission peaks related to the existence of the hydrogen bonds. These analytical results were satisfactorily compared with experimental results obtained from infrared spectroscopy.

Santos, Carlos da Silva dos; Ricotta, Regina Maria

2015-01-01T23:59:59.000Z

111

Method for vacuum fusion bonding  

DOE Patents [OSTI]

An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

2001-01-01T23:59:59.000Z

112

Fusion bonding and alignment fixture  

DOE Patents [OSTI]

An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all the components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

2000-01-01T23:59:59.000Z

113

Method of bonding  

DOE Patents [OSTI]

1. A method of making a fuel-containing structure for nuclear reactors, comprising providing an assembly comprising a plurality of fuel units; each fuel unit consisting of a core plate containing thermal-neutron-fissionable material, sheets of cladding metal on its bottom and top surfaces, said cladding sheets being of greater width and length than said core plates whereby recesses are formed at the ends and sides of said core plate, and end pieces and first side pieces of cladding metal of the same thickness as the core plate positioned in said recesses, the assembly further comprising a plurality of second side pieces of cladding metal engaging the cladding sheets so as to space the fuel units from one another, and a plurality of filler plates of an acid-dissolvable nonresilient material whose melting point is above 2000.degree. F., each filler plate being arranged between a pair of said second side pieces and the cladding plates of two adjacent fuel units, the filler plates having the same thickness as the second side pieces; the method further comprising enclosing the entire assembly in an envelope; evacuating the interior of the entire assembly through said envelope; applying inert gas under a pressure of about 10,000 psi to the outside of said envelope while at the same time heating the assembly to a temperature above the flow point of the cladding metal but below the melting point of any material of the assembly, whereby the envelope is pressed against the assembly and integral bonds are formed between plates, sheets, first side pieces, and end pieces and between the sheets and the second side pieces; slowly cooling the assembly to room temperature; removing the envelope; and dissolving the filler plates without attacking the cladding metal.

Saller, deceased, Henry A. (late of Columbus, OH); Hodge, Edwin S. (Columbus, OH); Paprocki, Stanley J. (Columbus, OH); Dayton, Russell W. (Columbus, OH)

1987-12-01T23:59:59.000Z

114

New Clean Renewable Energy Bonds | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New Clean Renewable Energy Bonds New Clean Renewable Energy Bonds New clean renewable energy bonds (CREBs) are tax credit bonds, the proceeds of which are used for capital...

115

Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable...  

Energy Savers [EERE]

Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable Energy Bonds (New CREBs) Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable Energy Bonds (New...

116

Low Temperature Material Bonding Techniq Ue  

DOE Patents [OSTI]

A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

2002-08-06T23:59:59.000Z

117

Pooled Bond Program (South Dakota)  

Broader source: Energy.gov [DOE]

The Pooled Bond Program offered by the Economic Development Finance Authority is designed for capital intensive projects, providing small businesses access to larger capital markets for tax-exempt...

118

E-Print Network 3.0 - aza cope rearrangement Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Related Analogues as Phosphatidylinositol Specic Phospholipase C (PI-PLC) Inhibitors Summary: 3-Hydroxy-6-aza-cholestane and Related Analogues as...

119

CONVERTIBLE BONDS IN A DEFAULTABLE DIFFUSION MODEL  

E-Print Network [OSTI]

CONVERTIBLE BONDS IN A DEFAULTABLE DIFFUSION MODEL Tomasz R. Bielecki Department of Applied Research Grant PS12918. #12;2 Convertible Bonds in a Defaultable Diffusion Model 1 Introduction In [4), such as Convertible Bonds (CB), and we provided a rigorous decomposition of a CB into a bond component and a (game

Jeanblanc, Monique

120

Aza Cope Rearrangement of Propargyl Enammonium Cations Catalyzed By a Self-Assembled `Nanozyme  

SciTech Connect (OSTI)

The tetrahedral [Ga{sub 4}L{sub 6}]{sup 12-} assembly (L = N,N-bis(2,3-dihydroxybenzoyl)-1,5-diaminonaphthalene) encapsulates a variety of cations, including propargyl enammonium cations capable of undergoing the aza Cope rearrangement. For propargyl enammonium substrates that are encapsulated in the [Ga{sub 4}L{sub 6}]{sup 12-} assembly, rate accelerations of up to 184 are observed when compared to the background reaction. After rearrangement, the product iminium ion is released into solution and hydrolyzed allowing for catalytic turnover. The activation parameters for the catalyzed and uncatalyzed reaction were determined, revealing that a lowered entropy of activation is responsible for the observed rate enhancements. The catalyzed reaction exhibits saturation kinetics; the rate data obey the Michaelis-Menten model of enzyme kinetics, and competitive inhibition using a non-reactive guest has been demonstrated.

Hastings, Courntey J.; Fiedler, Dorothea; Bergman, Robert G.; Raymond, Kenneth N.

2008-02-27T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Three methods to measure RH bond energies  

SciTech Connect (OSTI)

In this paper the authors compare and contrast three powerful methods for experimentally measuring bond energies in polyatomic molecules. The methods are: radical kinetics; gas phase acidity cycles; and photoionization mass spectroscopy. The knowledge of the values of bond energies are a basic piece of information to a chemist. Chemical reactions involve the making and breaking of chemical bonds. It has been shown that comparable bonds in polyatomic molecules, compared to the same bonds in radicals, can be significantly different. These bond energies can be measured in terms of bond dissociation energies.

Berkowitz, J. [Argonne National Lab., IL (United States); Ellison, G.B. [Univ. of Colorado, Boulder, CO (United States). Dept. of Chemistry and Biochemistry; Gutman, D. [Catholic Univ. of America, Washington, DC (United States). Dept. of Chemistry

1993-03-21T23:59:59.000Z

122

Bonded polyimide fuel cell package  

DOE Patents [OSTI]

Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

Morse, Jeffrey D.; Jankowski, Alan; Graff, Robert T.; Bettencourt, Kerry

2010-06-08T23:59:59.000Z

123

Non-bonded ultrasonic transducer  

DOE Patents [OSTI]

A mechanically assembled non-bonded ultrasonic transducer includes a substrate, a piezoelectric film, a wetting agent, a thin metal electrode, and a lens held in intimate contact by a mechanical clamp. No epoxy or glue is used in the assembly of this device.

Eoff, J.M.

1984-07-06T23:59:59.000Z

124

The Market for Borrowing Corporate Bonds  

E-Print Network [OSTI]

This paper describes the market for borrowing corporate bonds using a comprehensive data set from a major lender. The cost of borrowing corporate bonds is comparable to the cost of borrowing stock, between 10 and 20 basis ...

Asquith, Paul

125

Industrial Revenue Bond Issuance Cost Assistance (Wisconsin)  

Broader source: Energy.gov [DOE]

Industrial Revenue Bonds (IRB) are tax-exempt bonds that can be used to stimulate capital investment and job creation by providing private borrowers with access to financing at interest rates that...

126

Major Business Expansion Bond Program (Maine)  

Broader source: Energy.gov [DOE]

The Major Business Expansion Bond Program provides long-term, credit-enhanced financing up to $25,000,000 at taxable bond rates for businesses creating or retaining at least 50 jobs; up to $10,000...

127

Secondary Market Taxable Bond Program (Maine)  

Broader source: Energy.gov [DOE]

The Secondary Market Taxable Bond Program provides tax-exempt interest rate bond financing for real estate and machinery and equipment acquisitions. Up to 90% of the project debt may be financed,...

128

Information Sharing Networks and Ethnic Homophily in Hawaii's  

E-Print Network [OSTI]

." (Putnam 2001) Social Networks source:infovark.com #12;Social Capital Bonding Close reciprocal ties trust stakeholders Linking Ties across disparate groups Diffusion of innovation & scientific information (Grafton Coalitional/ Bridging Bridging Complete/ Bonding Complete/ Bonding Framework: Crowe (2007) (Barnes-Mauthe et

Hawai'i at Manoa, University of

129

Bonded, walk-off compensated optical elements  

DOE Patents [OSTI]

A bonded, walk-off compensated crystal, for use with optical equipment, and methods of making optical components including same.

Ebbers, Christopher A. (Livermore, CA)

2003-04-08T23:59:59.000Z

130

Study of bump bonding technology  

SciTech Connect (OSTI)

Pixel detectors proposed for the new generation of hadron collider experiments will use bump-bonding technology based on either indium or Pb/Sn solder to connect the front-end readout chips to the silicon pixel sensors. We have previously reported large-scale tests of the yield using both indium and Pb/Sn solder bump [1]. The conclusion is that both seem to be viable for pixel detectors. We have also carried out studies of various effects (e.g. storage over long period, effect of heating and cooling, and radiation) on both types of bump bonds using daisy-chained parts on a small scale [2], [3]. Overall, these tests showed little changes in the integrity of the bump connections. Nevertheless, questions still remain on the long-term reliability of the bumps due to thermal cycle effects, attachment to a substrate with a different coefficient of thermal expansion (CTE), and radiation.

Selcuk Cihangir et al.

2003-10-17T23:59:59.000Z

131

Clean Energy and Bond Finance Initiative  

Broader source: Energy.gov [DOE]

Provides information on Clean Energy and Bond Finance Initiative (CE+BFI). CE+BFI brings together public infrastructure finance agencies, clean energy public fund managers and institutional investors across the country to explore how to raise capital at scale for clean energy development through bond financing. Author: Clean Energy and Bond Finance Initiative

132

Kinase Expression and Chromosomal Rearrangements in Papillary Thyroid Cancer Tissues: Investigations at the Molecular and Microscopic Levels  

SciTech Connect (OSTI)

Structural chromosome aberrations are known hallmarks of many solid tumors. In the papillary form of thyroid cancer (PTC), for example, activation of the receptor tyrosine kinase (RTK) genes, ret or the neurotrophic tyrosine kinase receptor type I (NTRK1) by intra- or interchromosomal rearrangements have been suggested as a cause of the disease. The 1986 accident at the nuclear power plant in Chernobyl, USSR, led to the uncontrolled release of high levels of radioisotopes. Ten years later, the incidence of childhood papillary thyroid cancer (chPTC) near Chernobyl had risen by two orders of magnitude. Tumors removed from some of these patients showed aberrant expression of the ret RTK gene due to a ret/PTC1 or ret/PTC3 rearrangement involving chromosome 10. However, many cultured chPTC cells show a normal G-banded karyotype and no ret rearrangement. We hypothesize that the 'ret-negative' tumors inappropriately express a different oncogene or have lost function of a tumor suppressor as a result of chromosomal rearrangements, and decided to apply molecular and cytogenetic methods to search for potentially oncogenic chromosomal rearrangements in Chernobyl chPTC cases. Knowledge of the kind of genetic alterations may facilitate the early detection and staging of chPTC as well as provide guidance for therapeutic intervention.

Weier, Heinz-Ulrich; Kwan, Johnson; Lu, Chun-Mei; Ito, Yuko; Wang, Mei; Baumgartner, Adolf; Hayward, Simon W.; Weier, Jingly F.; Zitzelsberger, Horst F.

2009-07-07T23:59:59.000Z

133

Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmasSandy-Nor'easterStatisticalwithRhodiumFew-LayerBonded

134

The metal carbonyl promoted rearrangement of aryl-cyclopropenes. II. Approaches towards a model system of dynemicin A  

SciTech Connect (OSTI)

The ability of 3-vinyl- or 3-phenylcyclopropenes to undergo metal carbonyl promoted rearrangement with CO insertion to yield phenol or naphthol derivatives led to investigations using 3-naphthylcyclopropenes with the goal of producing material containing an anthracene carbon framework. Rearrangement of 1-methyl-3-(1,4-dimethoxynaphth-2-yl)cyclopropene, however, only gave material containing the phenanthrene framework. It is the goal of Part I of this thesis to modify a naphthylcyclopropene so that the metal carbonyl induced rearrangement will yield material containing an anthracene framework. A working hypothesis was put forth that focused on the electronic stabilization of certain aromatic intermediates to explain phenanthrene vs. anthracene formation. Semi-empirical calculations performed on model systems to estimate thermodynamic properties supported the hypothesis. Two naphthoquinone derivatives were prepared based on the hypothesis. In the first case, the cyclopropene substituent is arranged in the 2-position of a naphthoquinone-1,4-bisketal; in the second case, the cyclpropene is at C-2 in a 1,4-naphthoquinone. In both cases, the alkene unit (C-2/C-4) is less aromatic' than an alkene unit in a naphthalene ring, and the expected rearrangement can give only the anthraquinone skeleton. Investigations with the bisketal were unsucessful; attempted rearrangement at low temperatures gave only recovered starting material and experiments at higher temperatures polymerized the sensitive cyclopropene. Investigations with the 1,4-naphthoquinone proved modestly successful. Metal carbonyl catalyzed rearrangement with CO insertion to yield anthraquinone was observed. Additionally, low temperature conditions were developed that may prove useful in future work.

Cohen, D.H.

1992-01-01T23:59:59.000Z

135

Bond Programs | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: Energy ResourcesJersey:formBlueBombay Beach, California:Bonds allow governments

136

Vacuum fusion bonded glass plates having microstructures thereon  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

137

Nuclear reactor multiphysics via bond graph formalism  

E-Print Network [OSTI]

This work proposes a simple and effective approach to modeling nuclear reactor multiphysics problems using bond graphs. Conventional multiphysics simulation paradigms normally use operator splitting, which treats the ...

Sosnovsky, Eugeny

2014-01-01T23:59:59.000Z

138

Public Bonding Options | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

While the revenue stream need not be directly related to the financed project, capital lease revenue bonds entail a third party guaranteeing an energy savings revenue stream,...

139

Qualified Energy Conservation Bonds (QECBs) ? State Issues ...  

Broader source: Energy.gov (indexed) [DOE]

Qualified Energy Conservation Bonds (QECBs) - State Issues & Approaches February 12 th , 2013 DOE's Technical Assistance Program 2 Agenda * TAP Introduction & QECB Resources * QECB...

140

Tax-Exempt Industrial Revenue Bonds (Kansas)  

Broader source: Energy.gov [DOE]

Tax-Exempt Industrial Revenue Bonds are issued by cities and counties for the purchase, construction, improvement or remodeling of a facility for agricultural, commercial, hospital, industrial,...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Tax-Exempt Bond Financing (Delaware)  

Broader source: Energy.gov [DOE]

The Delaware Economic Development Authority provides tax-exempt bond financing for financial assistance to new or expanding businesses, governmental units and certain organizations that are exempt...

142

Hydrogen Adsorption Induces Interlayer Carbon Bond Formation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Adsorption Induces Interlayer Carbon Bond Formation in Supported Few-Layer Graphene Friday, February 28, 2014 Among the allotropes of carbon, diamond has some of the most...

143

IMPACT OF CAPILLARY AND BOND NUMBERS ON RELATIVE PERMEABILITY  

SciTech Connect (OSTI)

Recovery and recovery rate of oil, gas and condensates depend crucially on their relative permeability. Relative permeability in turn depends on the pore structure, wettability and flooding conditions, which can be represented by a set of dimensionless groups including capillary and bond numbers. The effect of flooding conditions on drainage relative permeabilities is not well understood and is the overall goal of this project. This project has three specific objectives: to improve the centrifuge relative permeability method, to measure capillary and bond number effects experimentally, and to develop a pore network model for multiphase flows. A centrifuge has been built that can accommodate high pressure core holders and x-ray saturation monitoring. The centrifuge core holders can operate at a pore pressure of 6.9 MPa (1000 psi) and an overburden pressure of 17 MPa (2500 psi). The effect of capillary number on residual saturation and relative permeability in drainage flow has been measured. A pore network model has been developed to study the effect of capillary numbers and viscosity ratio on drainage relative permeability. Capillary and Reynolds number dependence of gas-condensate flow has been studied during well testing. A method has been developed to estimate relative permeability parameters from gas-condensate well test data.

Kishore K. Mohanty

2002-09-30T23:59:59.000Z

144

CuAl{sub 2} revisited: Composition, crystal structure, chemical bonding, compressibility and Raman spectroscopy  

SciTech Connect (OSTI)

The structure of CuAl{sub 2} is usually described as a framework of base condensed tetragonal antiprisms [CuAl{sub 8/4}]. The appropriate symmetry governed periodic nodal surface (PNS) divides the space of the structure into two labyrinths. All atoms are located in one labyrinth, whereas the second labyrinth seems to be 'empty'. The bonding of the CuAl{sub 2} structure was analyzed by the electron localization function (ELF), crystal orbital Hamiltonian population (COHP) analysis and Raman spectroscopy. From the ELF representation it is seen, that the 'empty' labyrinth is in fact the place of important covalent interactions. ELF, COHP in combination with high-pressure X-ray diffraction and Raman spectroscopy show that the CuAl{sub 2} structure is described best as a network built of interpenetrating graphite-like nets of three-bonded aluminum atoms with the copper atoms inside the tetragonal-antiprismatic cavities. - Graphical abstract: Atomic interactions in the crystal structure of the intermetallic compound CuAl{sub 2}: Three-bonded aluminum atoms form interpenetrating graphite-like nets. The copper atoms are located in the channels of aluminum network by means of three-center bonds. The bonding model is in agreement with the result of polarized Raman spectroscopy and high-pressure X-ray powder diffraction.

Grin, Yuri [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany)]. E-mail: grin@cpfs.mpg.de; Wagner, Frank R. [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Armbruester, Marc [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Kohout, Miroslav [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Leithe-Jasper, Andreas [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Schwarz, Ulrich [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Wedig, Ulrich [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, 70569 Stuttgart (Germany); Georg von Schnering, Hans [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, 70569 Stuttgart (Germany)

2006-06-15T23:59:59.000Z

145

How Hydrogen Bond Redundancy Affects Protein Flexibility  

E-Print Network [OSTI]

Modeling a Protein as a BodyBarHinge and Associated Graph Main Question: Stability in proteins is the resistance to denaturation, or unfolding. A protein that is highly stable has a high tolerance to bonds breaking before unfolding; an unstable protein has less tolerance. In this study, we focus on the question, how many hydrogen bonds

Naomi Fox; Filip Jagodzinski; Jeanne Hardy; Ileana Streinu

146

Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen Bonds and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching. | EMSL Bubbles andof theCoal toAn Alternative to

147

Network Management Network Management  

E-Print Network [OSTI]

that pertain to the operation, administration, maintenance, and provisioning of networked systems Operation deals with keeping the network up (and the service provided by the network) Administration involvesNetwork Management Pag. 1 Network Management Andrea Bianco Telecommunication Network Group Network

148

Geometry of hydrogen bonds formed by lipid bilayer nitroxide probes : A high frequency pulsed ENDOR/EPR study.  

SciTech Connect (OSTI)

Solvent effects on magnetic parameters of nitroxide spin labels in combination with side-directed spin-labeling EPR methods provide very useful means for elucidating polarity profiles in lipid bilayers and mapping local electrostatic effects in complex biomolecular systems. One major contributor to these solvent effects is the hydrogen bonds that could be formed between the nitroxide moiety and water and/or the available hydroxyl groups. Here, formation of hydrogen bonds between a lipid bilayer spin probe 5-doxyl stearic acid, 5DSA and hydrogen-bond donors has been studied using high-frequency (HF) pulsed ENDOR and EPR. A hydrogen-bonded deuteron was directly detected in HF ENDOR (130 GHz) spectra of 5DSA dissolved in several deuterated alcohols, while the characteristic signal was absent in nonpolar toluene-d{sub 8}. The length of the hydrogen bond, 1.74 {+-} 0.06 {angstrom}, and its geometry were found to be essentially the same for all four alcohols studied, indicating that nearly identical hydrogen bonds have been formed regardless of the solvent dielectric constant. This strengthens a hypothesis that HF EPR spectra are exclusively sensitive to formation of hydrogen bonds and could be used for probing the hydrogen-bond network in complex biomolecular assemblies and lipid bilayers with site-directed spin-labeling methods.

Smirnova, T. I.; Smirnov, A. I.; Pachtchenko, S.; Poluektov, O. G.; Chemistry; North Carolina State Univ.

2007-01-01T23:59:59.000Z

149

Process Of Bonding Copper And Tungsten  

DOE Patents [OSTI]

Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by sintering a stack of individual copper and tungsten powder blend layers having progressively higher copper content/tungsten content, by volume, ratio values in successive powder blend layers in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO); Davis, John W. (Ballwin, MO)

2000-07-18T23:59:59.000Z

150

Chromosome-specific staining to detect genetic rearrangements associated with chromosome 3 and/or chromosome 17  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ .[.nudeic.]. .Iadd.nucleic .Iaddend.acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyses. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML), retinoblastoma, ovarian and uterine cancers, and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray, Joe W. (San Francisco, CA); Pinkel, Daniel (Lafayette, CA); Kallioniemi, Olli-Pekka (Turku, FI); Kallioniemi, Anne (Tampere, FI); Sakamoto, Masaru (Tokyo, JP)

2009-10-06T23:59:59.000Z

151

Chromosome-Specific Staining To Detect Genetic Rearrangements Associated With Chromosome 3 And/Or Chromosone 17  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ nucleic acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyses. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML), retinoblastoma, ovarian and uterine cancers, and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray; Joe W. (Livermore, CA); Pinkel; Daniel (Walnut Creek, CA); Kallioniemi; Olli-Pekka (Tampere, FI); Kallioniemi; Anne (Tampere, FI); Sakamoto; Masaru (Tokyo, JP)

2002-02-05T23:59:59.000Z

152

Chromosome-specific staining to detect genetic rearrangements associated with chromosome 3 and/or chromosome 17  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ nucleic acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyses. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML), retinoblastoma, ovarian and uterine cancers, and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray, Joe W. (San Francisco, CA); Pinkel, Daniel (Lafayette, CA); Kallioniemi, Olli-Pekka (Turku, FI); Kallioniemi, Anne (Tampere, FI); Sakamoto, Masaru (Tokyo, JP)

2008-09-09T23:59:59.000Z

153

Chromosome-specific staining to detect genetic rearrangements associated with chromosome 3 and/or chromosome 17  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ nudeic acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyses. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML), retinoblastoma, ovarian and uterine cancers, and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray, Joe W. (Livermore, CA); Pinkel, Daniel (Walnut Creek, CA); Kallioniemi, Olli-Pekka (Tampere, FI); Kallioniemi, Anne (Tampere, FI); Sakamoto, Masaru (Tokyo, JP)

2002-01-01T23:59:59.000Z

154

Tubulin bond energies and microtubule biomechanics determined from nanoindentation in silico  

E-Print Network [OSTI]

Microtubules, the primary components of the chromosome segregation machinery, are stabilized by longitudinal and lateral non-covalent bonds between the tubulin subunits. However, the thermodynamics of these bonds and the microtubule physico-chemical properties are poorly understood. Here, we explore the biomechanics of microtubule polymers using multiscale computational modeling and nanoindentations in silico of a contiguous microtubule fragment. A close match between the simulated and experimental force-deformation spectra enabled us to correlate the microtubule biomechanics with dynamic structural transitions at the nanoscale. Our mechanical testing revealed that the compressed MT behaves as a system of rigid elements interconnected through a network of lateral and longitudinal elastic bonds. The initial regime of continuous elastic deformation of the microtubule is followed by the transition regime, during which the microtubule lattice undergoes discrete structural changes, which include first the reversib...

Kononova, Olga; Theisen, Kelly E; Marx, Kenneth A; Dima, Ruxandra I; Ataullakhanov, Fazly I; Grishchuk, Ekaterina L; Barsegov, Valeri

2015-01-01T23:59:59.000Z

155

Local Option- Industrial Facilities and Development Bonds (Utah)  

Broader source: Energy.gov [DOE]

Under the Utah Industrial Facilities and Development Act, counties, municipalities, and state universities in Utah may issue Industrial Revenue Bonds (IRBs) or Industrial Development Bonds (IDBs)...

156

Atoms in Valence Bond. Method, implementation and application.  

E-Print Network [OSTI]

??The Atoms in Valence Bond (AiVB) approach is presented. The main goal was to develop a new and innovative approach, within the existing Valence Bond (more)

Zielinski, M.L.

2012-01-01T23:59:59.000Z

157

Mechanistic Examination of C?C? Bond Cleavages...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mechanistic Examination of C?C? Bond Cleavages of Tryptophan Residues during Dissociations of Molecular Mechanistic Examination of C?C? Bond...

158

Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with covalently-bound hexafluoroisopropanol groups. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

159

Atomistic modeling of amorphous silicon carbide using a bond...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

modeling of amorphous silicon carbide using a bond-order potential. Atomistic modeling of amorphous silicon carbide using a bond-order potential. Abstract: Molecular dynamics...

160

Using Qualified Energy Conservation Bonds for Public Building...  

Broader source: Energy.gov (indexed) [DOE]

Using Qualified Energy Conservation Bonds for Public Building Upgrades: Reducing Energy Bills in the City of Philadelphia Using Qualified Energy Conservation Bonds for Public...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Taking Advantage of Qualified Energy Conservation Bonds (QECBs...  

Broader source: Energy.gov (indexed) [DOE]

Advantage of Qualified Energy Conservation Bonds (QECBs) Taking Advantage of Qualified Energy Conservation Bonds (QECBs) Blue version of the EERE PowerPoint template, for use with...

162

IRS Announces New Tribal Economic Development Bond Allocation...  

Broader source: Energy.gov (indexed) [DOE]

IRS Announces New Tribal Economic Development Bond Allocation Guidance IRS Announces New Tribal Economic Development Bond Allocation Guidance July 18, 2012 - 3:46pm Addthis To...

163

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

164

Municipal Bond - Power Purchase Agreement Model Continues to...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Municipal Bond - Power Purchase Agreement Model Continues to Provide Low-Cost Solar Energy Municipal Bond - Power Purchase Agreement Model Continues to Provide Low-Cost Solar...

165

Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues. Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues....

166

adhesively bonded composite: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

evaluation MIT - DSpace Summary: During the last half century, the use of composite materials and structures has been increasing within many industries: aerospace, automotive,...

167

additional double bonds: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

such as weak-magnetism and pseudoscalar couplings to the amplitude of neutrinoless double beta decay in the mechanisms of light and heavy Majorana neutrino as well as in that...

168

amide bond cleavage: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the reactions of vanadyl ion and found that incubation of DNA with vanadyl ion and hydrogen peroxide (H202) led to intense DNA cleavage. ESR spin trapping demonstrated that...

169

Investigation of electrostatics in a hydogen bond network  

E-Print Network [OSTI]

('ormed with the DNA. There is large-scale growth of the cells, and finally the cells are harvested for the protein of intcrcst. In the second general step, the protein is purified, first on an ion exchange column (separation based on anion exchange) and then by gel... plasmid. Once the miniprep is completed, an agarose gel is run on the sample collected to verify that indeed a piece of DNA has been isolated. If the agarose gel verifies that DNA was isolated, then a sample of thc DNA is sent to the Gene...

Uddin, Fatema Sultana

2013-02-22T23:59:59.000Z

170

amide bond rotation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on flat space-time suffers from a global pathology which can be cured by introducing a cylindrical mirror if and only if it has a radius smaller than that of the speed-of-light...

171

The Ohio Enterprise Bond Fund (Ohio)  

Broader source: Energy.gov [DOE]

The Ohio Enterprise Bond Fund (OEBF) was created in 1988 to promote economic development, create and retain quality jobs and assist governmental operations. The program enables non-profit and for...

172

Sandia National Laboratories: Diffusion Bonding Characterization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

bond surface is poor or only the region near this corner Diffusion 7-8-9 Diffusion Welding and Brazing, Welding Handbook, 7th ed., American Welding Society, 1980, p 311-335...

173

Industrial Revenue Bond Program (District of Columbia)  

Broader source: Energy.gov [DOE]

The District provides below market bond financing to lower the costs of borrowing for qualified capital construction and renovation projects. The program is available to non-profits, institutions,...

174

Method of bonding metals to ceramics  

DOE Patents [OSTI]

A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof is disclosed. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, Au and alloys thereof. 3 figures.

Maroni, V.A.

1991-04-23T23:59:59.000Z

175

Discrete Element Modeling Results of Proppant Rearrangement in the Cooke Conductivity Cell  

SciTech Connect (OSTI)

The study of propped fracture conductivity began in earnest with the development of the Cooke cell which later became part of the initial API standard. Subsequent developments included a patented multicell design to conduct 4 tests in a press at the same time. Other modifications have been used by various investigators. Recent studies by the Stim-Lab proppant consortium have indicated that the flow field across a Cooke proppant conductivity testing cell may not be uniform as initially believed which resulted is significantly different conductivity results. Post test analysis of low temperature metal alloy injections at the termination of proppant testing prior to the release of the applied stress suggest that higher flow is to be expected along the sides and top of the proppant pack than compared to the middle of the pack. To evaluate these experimental findings, a physics-based two-dimensional (2-D) discrete element model (DEM) was developed and applied to simulate proppant rearrangement during stress loading in the Cooke conductivity cell and the resulting porosity field. Analysis of these simulations are critical to understanding the impact of modification to the testing cell as well as understanding key proppant conductivity issues such as how these effects are manifested in proppant concentration testing results. The 2-D DEM model was constructed to represent a realistic cross section of the Cooke cell with a distribution of four material properties, three that represented the Cooke cell (steel, sandstone,square rings), and one representing the proppant. In principle, Cooke cell materials can be approximated as assemblies of independent discrete elements (particles) of various sizes and material properties that interact via cohesive interactions, repulsive forces, and frictional forces. The macroscopic behavior can then be modeled as the collective behavior of many interacting discrete elements. This DEM model is particularly suitable for modeling proppant mechanical interactions subjected to an applied stress, where the experimental cell is represented as a cohesive body composed of a large number of discrete elements, and proppants can be modeled as the individual discrete particles with various sizes (following the proppant size distribution-density function used in the test) that exhibit no cohesive strength between the particles. Initial 2-D DEM modeling results suggest that proppant rearrangement and non-uniform stress distribution across the proppant pack results in significant non-uniform porosity distribution across the Cooke cell. Larger porosities develop along the edge of the proppant pack beneath the square ring seal and would result in a disproportionate higher flow field along these edges as compared to the middle of the proppant pack. These results suggest that reported conductivity values determined by the Cooke cell may be biased to overestimate the actual conductivity of the proppant at high stresses and that modifications to the standard Cooke cell will affect the magnitude of this bias.

Earl Mattson; Hai Huang; Michael Conway; Lisa O'Connell

2014-02-01T23:59:59.000Z

176

Characterization of an explosively bonded aluminum proton beam window for the Spallation Neutron Source  

SciTech Connect (OSTI)

An effort is underway at the Spallation Neutron Source (SNS) to change the design of the 1st Generation high-nickel alloy proton beam window (PBW) to one that utilizes aluminum for the window material. One of the key challenges to implementation of an aluminum PBW at the SNS was selection of an appropriate joining method to bond an aluminum window to the stainless steel bulk shielding of the PBW assembly. An explosively formed bond was selected as the most promising joining method for the aluminum PBW design. A testing campaign was conducted to evaluate the strength and efficacy of explosively formed bonds that were produced using two different interlayer materials: niobium and titanium. The characterization methods reported here include tensile testing, thermal-shock leak testing, optical microscopy, and advanced scanning electron microscopy. All tensile specimens examined failed in the aluminum interlayer and measured tensile strengths were all slightly greater than the native properties of the aluminum interlayer, while elongation values were all slightly lower. A leak developed in the test vessel with a niobium interlayer joint after repeated thermal-shock cycles, and was attributed to an extensive crack network that formed in a layer of niobium-rich intermetallics located on the bond interfaces of the niobium interlayer; the test vessel with a titanium interlayer did not develop a leak under the conditions tested. Due to the experience gained from these characterizations, the explosively formed bond with a titanium interlayer was selected for the aluminum PBW design at the SNS.

McClintock, David A [ORNL] [ORNL; Janney, Jim G [ORNL] [ORNL; Parish, Chad M [ORNL] [ORNL

2014-01-01T23:59:59.000Z

177

July 18, 2012 Using Qualified Energy Conservation Bonds for Public  

E-Print Network [OSTI]

July 18, 2012 Using Qualified Energy Conservation Bonds for Public Building Upgrades: Reducing Energy Bills in the City of Philadelphia Qualified Energy Conservation Bonds (QECBs) are federally Energy Conservation Bond (QECB) is a bond that enables qualified state, tribal and local government

178

Shirzadi et al. Surface and Interface Analysis 2001; 31:609-618 Interface evolution and bond strength when diffusion bonding  

E-Print Network [OSTI]

strength when diffusion bonding materials with stable oxide films A.A. Shirzadi* , H. Assadi and E morphologies and strengths of aluminium diffusion bonds are reviewed. Previous approaches, proposed to overcome for both solid-state diffusion bonding and conventional transient liquid phase (TLP) diffusion bonding. Non

Cambridge, University of

179

Process Of Bonding Copper And Tungsten  

DOE Patents [OSTI]

Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by thermal plasma spraying mixtures of copper powder and tungsten powder in a varied blending ratio such that the blending ratio of the copper powder and the tungsten powder that is fed to a plasma torch is intermittently adjusted to provide progressively higher copper content/tungsten content, by volume, ratio values in the interlayer in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO)

1999-11-23T23:59:59.000Z

180

Epoxy bond and stop etch fabrication method  

DOE Patents [OSTI]

A class of epoxy bond and stop etch (EBASE) microelectronic fabrication techniques is disclosed. The essence of such techniques is to grow circuit components on top of a stop etch layer grown on a first substrate. The first substrate and a host substrate are then bonded together so that the circuit components are attached to the host substrate by the bonding agent. The first substrate is then removed, e.g., by a chemical or physical etching process to which the stop etch layer is resistant. EBASE fabrication methods allow access to regions of a device structure which are usually blocked by the presence of a substrate, and are of particular utility in the fabrication of ultrafast electronic and optoelectronic devices and circuits.

Simmons, Jerry A. (Sandia Park, NM); Weckwerth, Mark V. (Pleasanton, CA); Baca, Wes E. (Albuquerque, NM)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Bonded ultrasonic transducer and method for making  

DOE Patents [OSTI]

An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements. 12 figs.

Dixon, R.D.; Roe, L.H.; Migliori, A.

1995-11-14T23:59:59.000Z

182

Bonded ultrasonic transducer and method for making  

DOE Patents [OSTI]

An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements.

Dixon, Raymond D. (Los Alamos, NM); Roe, Lawrence H. (Los Alamos, NM); Migliori, Albert (Santa Fe, NM)

1995-01-01T23:59:59.000Z

183

Bond Strength Measurements from an Australian Standard Bond Wrench in Comparison to the Unbalanced ASTM C 1072 Bond Wrench to the Balanced and Unbalanced Wrenches  

E-Print Network [OSTI]

Bond wrenches. The Australian wrench values were significantly higher than the American bond wrenches for similar types of samples. Hence it was recommended that the tests be carried out by replacing the cement with Portland cement. This experimental...

Suresh, Sri Vishnu Chaitanya Guptha

2014-08-14T23:59:59.000Z

184

Adhesive bonding using variable frequency microwave energy  

DOE Patents [OSTI]

Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy.

Lauf, Robert J. (Oak Ridge, TN); McMillan, April D. (Knoxville, TN); Paulauskas, Felix L. (Oak Ridge, TN); Fathi, Zakaryae (Cary, NC); Wei, Jianghua (Raleigh, NC)

1998-01-01T23:59:59.000Z

185

Adhesive bonding using variable frequency microwave energy  

DOE Patents [OSTI]

Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

1998-09-08T23:59:59.000Z

186

Adhesive bonding using variable frequency microwave energy  

DOE Patents [OSTI]

Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

1998-08-25T23:59:59.000Z

187

Phosphate-bonded calcium aluminate cements  

DOE Patents [OSTI]

A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120 C to about 300 C to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate. 10 figures.

Sugama, T.

1993-09-21T23:59:59.000Z

188

Nitride-bonded silicon carbide composite filter  

SciTech Connect (OSTI)

The objective of this program is to develop and demonstrate an advanced hot gas filter, using ceramic component technology, with enhanced durability to provide increased resistance to thermal fatigue and crack propagation. The material is silicon carbide fiber reinforced nitride bonded silicon carbide.

Thomson, B.N.; DiPietro, S.G.

1995-12-01T23:59:59.000Z

189

Fluorinated diamond bonded in fluorocarbon resin  

DOE Patents [OSTI]

By fluorinating diamond grit, the grit may be readily bonded into a fluorocarbon resin matrix. The matrix is formed by simple hot pressing techniques. Diamond grinding wheels may advantageously be manufactured using such a matrix. Teflon fluorocarbon resins are particularly well suited for using in forming the matrix.

Taylor, Gene W. (Los Alamos, NM)

1982-01-01T23:59:59.000Z

190

Dynamic force spectroscopy on multiple bonds: experiments and model  

E-Print Network [OSTI]

We probe the dynamic strength of multiple biotin-streptavidin adhesion bonds under linear loading using the biomembrane force probe setup for dynamic force spectroscopy. Measured rupture force histograms are compared to results from a master equation model for the stochastic dynamics of bond rupture under load. This allows us to extract the distribution of the number of initially closed bonds. We also extract the molecular parameters of the adhesion bonds, in good agreement with earlier results from single bond experiments. Our analysis shows that the peaks in the measured histograms are not simple multiples of the single bond values, but follow from a superposition procedure which generates different peak positions.

T. Erdmann; S. Pierrat; P. Nassoy; U. S. Schwarz

2007-12-18T23:59:59.000Z

191

Chromosome-specific staining to detect genetic rearrangements associated with chromosome 3 and/or chromosome 17  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ nudeic nucleic acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyses. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML), retinoblastoma, ovarian and uterine cancers, and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray, Joe W.; Pinkel, Daniel; Kallioniemi, Olli-Pekka; Kallioniemi, Anne; Sakamoto, Masaru

2009-10-06T23:59:59.000Z

192

Lattice-Mismatched GaAs/InGaAs Two-Junction Solar Cells by Direct Wafer Bonding  

SciTech Connect (OSTI)

Direct bonded interconnect between subcells of a lattice-mismatched III-V compound multijunction cell would enable dislocation-free active regions by confining the defect network needed for lattice mismatch accommodation to tunnel junction interfaces, while metamorphic growth inevitably results in less design flexibility and lower material quality than is desirable. The first direct-bond interconnected multijunction solar cell, a two-terminal monolithic GaAs/InGaAs two-junction solar cell, is reported and demonstrates viability of direct wafer bonding for solar cell applications. The tandem cell open-circuit voltage was approximately the sum of the subcell open-circuit voltages. This achievement shows direct bonding enables us to construct lattice-mismatched III-V multijunction solar cells and is extensible to an ultrahigh efficiency InGaP/GaAs/InGaAsP/InGaAs four-junction cell by bonding a GaAs-based lattice-matched InGaP/GaAs subcell and an InP-based lattice-matched InGaAsP/InGaAs subcell. The interfacial resistance experimentally obtained for bonded GaAs/InP smaller than 0.10 Ohm-cm{sup 2} would result in a negligible decrease in overall cell efficiency of {approx}0.02%, under 1-sun illumination.

Tanabe, K.; Aiken, D. J.; Wanlass, M. W.; Morral, A. F.; Atwater, H. A.

2006-01-01T23:59:59.000Z

193

Network Chimera Network Chimera  

E-Print Network [OSTI]

Network Chimera Network Chimera Objective Chimera aims to understand how the network properties enough with limited resources. The Chimera team is cross-disciplinary, and includes computer scientists Impact The original hypothesis of Chimera was that a physical network could be reduced to a graph

194

Bayesian field theoretic reconstruction of bond potential and bond mobility in single molecule force spectroscopy  

E-Print Network [OSTI]

Quantifying the forces between and within macromolecules is a necessary first step in understanding the mechanics of molecular structure, protein folding, and enzyme function and performance. In such macromolecular settings, dynamic single-molecule force spectroscopy (DFS) has been used to distort bonds. The resulting responses, in the form of rupture forces, work applied, and trajectories of displacements, have been used to reconstruct bond potentials. Such approaches often rely on simple parameterizations of one-dimensional bond potentials, assumptions on equilibrium starting states, and/or large amounts of trajectory data. Parametric approaches typically fail at inferring complex-shaped bond potentials with multiple minima, while piecewise estimation may not guarantee smooth results with the appropriate behavior at large distances. Existing techniques, particularly those based on work theorems, also do not address spatial variations in the diffusivity that may arise from spatially inhomogeneous coupling to...

Chang, Joshua C; Chou, Tom

2015-01-01T23:59:59.000Z

195

Various Carbon to Carbon Bond Lengths Inter-related via the Golden Ratio, and their Linear Dependence on Bond Energies  

E-Print Network [OSTI]

This work presents the relations between the carbon to carbon bond lengths in the single, double and triple bonds and in graphite, butadiene and benzene. The Golden ratio, which was shown to divide the Bohr radius into two parts pertaining to the charged particles, the electron and proton, and to divide inter-atomic distances into their cationic and anionic radii, also plays a role in the carbon-carbon bonds and in the ionic/polar character of those in graphite, butadiene and benzene. Further, the bond energies of the various CC bonds are shown to vary linearly with the bond lengths.

Raji Heyrovska

2008-09-11T23:59:59.000Z

196

Experimental bond critical point and local energy density properties...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mn-O, Fe-O and Co-O bonded interactions for Abstract: Bond critical point, bcp, and local energy density properties for the electron density, ED, distributions, calculated with...

197

Pre-plated reactive diffusion-bonded battery electrode plaques  

DOE Patents [OSTI]

A high strength, metallic fiber battery plaque is made using reactive diffusion bonding techniques, where a substantial amount of the fibers are bonded together by an iron-nickel alloy.

Maskalick, Nicholas J. (Pittsburgh, PA)

1984-01-01T23:59:59.000Z

198

Single-Issue Industrial Revenue Bond Program (Missouri)  

Broader source: Energy.gov [DOE]

The Missouri Development Finance Board administers a Single-Issue Tax-Exempt Industrial Revenue Bond Program as well as a Taxable Industrial Revenue Bond Program. The Tax-Exempt Program finances (i...

199

Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

200

Hydrogen Bonding DOI: 10.1002/anie.200501349  

E-Print Network [OSTI]

systems[5­13] and crystal engineering.[14­18] Most C?H···O hydrogen bonds have been observed for the soHydrogen Bonding DOI: 10.1002/anie.200501349 Observation of Weak C?H···O Hydrogen Bonding to Unactivated Alkanes** Xue-Bin Wang, Hin-Koon Woo, Boggavarapu Kiran, and Lai-Sheng Wang* The hydrogen bond

Simons, Jack

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Article coated with flash bonded superhydrophobic particles  

DOE Patents [OSTI]

A method of making article having a superhydrophobic surface includes: providing a solid body defining at least one surface; applying to the surface a plurality of diatomaceous earth particles and/or particles characterized by particle sizes ranging from at least 100 nm to about 10 .mu.m, the particles being further characterized by a plurality of nanopores, wherein at least some of the nanopores provide flow through porosity, the particles being further characterized by a plurality of spaced apart nanostructured features that include a contiguous, protrusive material; flash bonding the particles to the surface so that the particles are adherently bonded to the surface; and applying a hydrophobic coating layer to the surface and the particles so that the hydrophobic coating layer conforms to the nanostructured features.

Simpson, John T (Clinton, TN) [Clinton, TN; Blue, Craig A (Knoxville, TN) [Knoxville, TN; Kiggans, Jr., James O [Oak Ridge, TN

2010-07-13T23:59:59.000Z

202

Partial-Transient-Liquid-Phase Bonding of Advanced Ceramics Using Surface-Modified Interlayers  

E-Print Network [OSTI]

Theoretical-Model for Diffusion Bonding." Metal Science 16,Derby, B. & Wallach, E. "Diffusion Bonding - Development ofInterfacial Contact during Diffusion Bonding." Metallurgical

Reynolds, Thomas Bither

2012-01-01T23:59:59.000Z

203

Oil prices and government bond risk premiums Herv Alexandre*  

E-Print Network [OSTI]

Oil prices and government bond risk premiums By Herv Alexandre* Antonin de Benoist * Abstract : This article analyses the impact of oil price on bond risk premiums issued by emerging economies. No empirical study has yet focussed on the effects of the oil price on government bond risk premiums. We develop

Boyer, Edmond

204

Diffusion Bonding Aluminium Alloys and Composites: New Approaches and Modelling  

E-Print Network [OSTI]

Diffusion Bonding Aluminium Alloys and Composites: New Approaches and Modelling Amir A. Shirzadi of the research, two new methods for TLP diffusion bonding of aluminium-based composites (aluminium alloys diffusion bonding and hot isostatic pressing without encapsulation. It allows the fabrication of intricate

Cambridge, University of

205

Energetics of hydrogen bonds in peptides Sheh-Yi Sheu*  

E-Print Network [OSTI]

for water. We find that the activation energy for the rupture of the hydrogen bond in a -sheet under calculation can be useful for the prediction of hydrogen bond strengths in various environments of interest extensively to calculate free energy changes caused by hydrogen bond rupture. Here the water environment

Sheu, Sheh-Yi

206

Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang*  

E-Print Network [OSTI]

Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang* Department of Biochemistry, University of Zurich, Zurich, Switzerland Abstract Ligand binding involves breakage of hydrogen bonds with water molecules and formation of new hydrogen bonds between protein and ligand. In this work, the change

Caflisch, Amedeo

207

Analysis of C H...O hydrogen bonds  

E-Print Network [OSTI]

1 Analysis of C H...O hydrogen bonds in high resolution protein crystal structures from the PDB 1.4 Identification of C-H...O hydrogen bonds............................................. 1.4.1 The definition of a C-H...O hydrogen bond.................................... 1.4.2 Fixing the hydrogen and measuring the parameters

Babu, M. Madan

208

Anesthesia cutoff phenomenon: Interfacial hydrogen bonding  

SciTech Connect (OSTI)

Anesthesia cutoff refers to the phenomenon of loss of anesthetic potency in a homologous series of alkanes and their derivatives when their sizes become too large. In this study, hydrogen bonding of 1-alkanol series (ethanol to eicosanol) to dipalmitoyl-L-alpha-phosphatidylcholine (DPPC) was studied by Fourier transform infrared spectroscopy (FTIR) in DPPC-D2O-in-CCl4 reversed micelles. The alkanols formed hydrogen bonds with the phosphate moiety of DPPC and released the DPPC-bound deuterated water, evidenced by increases in the bound O-H stretching signal of the alkanol-DPPC complex and also in the free O-D stretching band of unbound D2O. These effects increased according to the elongation of the carbon chain of 1-alkanols from ethanol (C2) to 1-decanol (C10), but suddenly almost disappeared at 1-tetradecanol (C14). Anesthetic potencies of these alkanols, estimated by the activity of brine shrimps, were linearly related to hydrogen bond-breaking activities below C10 and agreed with the FTIR data in the cutoff at C10.

Chiou, J.S.; Ma, S.M.; Kamaya, H.; Ueda, I. (Univ. of Utah School of Medicine, Salt Lake City (USA))

1990-05-04T23:59:59.000Z

209

Microchannel cooling of face down bonded chips  

DOE Patents [OSTI]

Microchannel cooling is applied to flip-chip bonded integrated circuits, in a manner which maintains the advantages of flip-chip bonds, while overcoming the difficulties encountered in cooling the chips. The technique is suited to either multichip integrated circuit boards in a plane, or to stacks of circuit boards in a three dimensional interconnect structure. Integrated circuit chips are mounted on a circuit board using flip-chip or control collapse bonds. A microchannel structure is essentially permanently coupled with the back of the chip. A coolant delivery manifold delivers coolant to the microchannel structure, and a seal consisting of a compressible elastomer is provided between the coolant delivery manifold and the microchannel structure. The integrated circuit chip and microchannel structure are connected together to form a replaceable integrated circuit module which can be easily decoupled from the coolant delivery manifold and the circuit board. The coolant supply manifolds may be disposed between the circuit boards in a stack and coupled to supplies of coolant through a side of the stack.

Bernhardt, Anthony F. (Berkeley, CA)

1993-01-01T23:59:59.000Z

210

Microchannel cooling of face down bonded chips  

DOE Patents [OSTI]

Microchannel cooling is applied to flip-chip bonded integrated circuits, in a manner which maintains the advantages of flip-chip bonds, while overcoming the difficulties encountered in cooling the chips. The technique is suited to either multi chip integrated circuit boards in a plane, or to stacks of circuit boards in a three dimensional interconnect structure. Integrated circuit chips are mounted on a circuit board using flip-chip or control collapse bonds. A microchannel structure is essentially permanently coupled with the back of the chip. A coolant delivery manifold delivers coolant to the microchannel structure, and a seal consisting of a compressible elastomer is provided between the coolant delivery manifold and the microchannel structure. The integrated circuit chip and microchannel structure are connected together to form a replaceable integrated circuit module which can be easily decoupled from the coolant delivery manifold and the circuit board. The coolant supply manifolds may be disposed between the circuit boards in a stack and coupled to supplies of coolant through a side of the stack.

Bernhardt, A.F.

1993-06-08T23:59:59.000Z

211

Chemical Rearrangement under Hydrothermal Conditions: Formation of Polymeric Chains (CuX)2(dpiz) and (CuX)3(dpiz) (X ) Cl, Br; dpiz ) Dipyrido[1,2-a:2,3-d]imidazole) and Crystal Structures of  

E-Print Network [OSTI]

rearrangement during the hydrothermal self- assembly process in forming copper dipyrido[1,2-a:2,3-d]imi- dazoleChemical Rearrangement under Hydrothermal Conditions: Formation of Polymeric Chains (CuX)2(dpiz the hydrothermal method7 has been widely applied in the synthesis and crystal growth of many inorganic compounds

Li, Jing

212

Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch  

E-Print Network [OSTI]

Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch K. J. Gaffney, I. R. Piletic, and M. D. Fayer* Department measured with ultrafast infrared pump-probe experiments. Non-hydrogen-bond donating OD stretches (2690 cm-1

Fayer, Michael D.

213

DNA rearrangement in human follicular lymphoma can involve the 5' or the 3' region of the bcl-2 gene  

SciTech Connect (OSTI)

In most human lymphomas, the chromosome translocation t(14;18) occurs within two breakpoint clustering regions on chromosome 18, the major one at the 3' untranslated region of the bcl-2 gene and the minor one at 3' of the gene. Analysis of a panel of follicular lymphoma DNAs using probes for the first exon of the bcl-2 gene indicates that DNA rearrangements may also occur 5' to the involved bcl-2 gene. In this case the IgH locus and the bcl-2 gene are found in an order suggesting that an inversion also occurred during the translocation process. The coding region of the bcl-2 gene, however, are left intact in all cases of follicular lymphoma studied to date.

Tsujimoto, Y.; Bashir, M.M.; Givol, I.; Cossman, J.; Jaffe, E.; Croce, C.M.

1987-03-01T23:59:59.000Z

214

BAC-FISH assays delineate complex chromosomal rearrangements in a case of post-Chernobyl childhood thyroid cancer  

SciTech Connect (OSTI)

Structural chromosome aberrations are known hallmarks of many solid tumors. In the papillary form of thyroid cancer (PTC), for example, activation of the receptor tyrosine kinase (RTK) genes, RET and neurotrophic tyrosine kinase receptor type I (NTRK1) by intra- and interchromosomal rearrangements has been suggested as a cause of the disease. However, many phenotypically similar tumors do not carry an activated RET or NTRK-1 gene or express abnormal ret or NTRK-1 transcripts. Thus, we hypothesize that other cellular RTK-type genes are aberrantly expressed in these tumors. Using fluorescence in situ hybridization-based methods, we are studying karyotype changes in a relatively rare subgroup of PTCs, i.e., tumors that arose in children following the 1986 nuclear accident in Chernobyl, Ukraine. Here, we report our technical developments and progress in deciphering complex chromosome aberrations in case S48TK, an aggressively growing PTC cell line, which shows an unusual high number of unbalanced translocations.

Kwan, Johnson; Baumgartner, Adolf; Lu, Chun-Mei; Wang, Mei; Weier, Jingly F.; Zitzelsberger, Horst F.; Weier, Heinz-Ulrich G.

2009-03-09T23:59:59.000Z

215

Complexes of Alkylene-Linked Tacrine Dimers with Torpedo californica Acetylcholinesterase: Binding of Bis(5)-tacrine Produces a Dramatic Rearrangement in the Active-Site Gorge  

E-Print Network [OSTI]

were separated by 5- and 7-carbon spacers. The derivative with the 7-carbon spacer spans the length and Trp279). The derivative with the 5-carbon spacer interacts in a similar manner at the bottom a major rearrangement in the Trp279- Ser291 loop. The ability of this inhibitor to induce large

Sussman, Joel L.

216

Ultrasonic evaluation of beryllium-copper diffusion bonds  

SciTech Connect (OSTI)

A study was performed to compare the effectiveness of several advanced ultrasonic techniques when used to determine the strength of diffusion bonded beryllium-copper, which heretofore have each been applied to only a few material systems. The use of integrated backscatter calculations, frequency domain reflection coefficients, and time-of-flight variance was compared in their ability to characterize the bond strength in a series of beryllium-copper diffusion bond samples having a wide variation in bond quality. Correlation of integrated backscatter calculations and time-of-flight variance with bond strength was good. Some correlation of the slope of the frequency based reflection coefficient was shown for medium and high strength bonds, while its Y-intercept showed moderate correlation for all bond strengths.

Jamieson, E.E.

2000-06-08T23:59:59.000Z

217

Bond selective chemistry beyond the adiabatic approximation  

SciTech Connect (OSTI)

One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

Butler, L.J. [Univ. of Chicago, IL (United States)

1993-12-01T23:59:59.000Z

218

Robin Hutchinson, Gamil Tadros, Jadwiga Kroman, Sami Rizkalla, "Use of Externally Bonded FRP Systems for Rehabilitation of Bridges in Western Canada," Page 1  

E-Print Network [OSTI]

Systems for Rehabilitation of Bridges in Western Canada," Page 1 Use of Externally Bonded FRP Systems for Rehabilitation of Bridges in Western Canada Robin Hutchinson, Gamil Tadros, Jadwiga Kroman, Sami Rizkalla Synopsis: Since its inception in 1995, the ISIS Canada research network has developed design procedures

219

Partial-Transient-Liquid-Phase Bonding of Advanced Ceramics Using Surface-Modified Interlayers  

E-Print Network [OSTI]

Alumina Diffusion Bonding and Titanium Active Brazing."O 3 -Titanium Adhesion in the View of the Diffusion Bonding

Reynolds, Thomas Bither

2012-01-01T23:59:59.000Z

220

Repairable chip bonding/interconnect process  

DOE Patents [OSTI]

A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder.

Bernhardt, Anthony F. (Berkeley, CA); Contolini, Robert J. (Livermore, CA); Malba, Vincent (Livermore, CA); Riddle, Robert A. (Tracy, CA)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Repairable chip bonding/interconnect process  

DOE Patents [OSTI]

A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules is disclosed. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder. 10 figs.

Bernhardt, A.F.; Contolini, R.J.; Malba, V.; Riddle, R.A.

1997-08-05T23:59:59.000Z

222

Covalent Bonding in Actinide Sandwich Molecules  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to User GroupInformationE-GovNatural GasCourse ClustersCovalent Bonding in

223

Qualified Energy Conservation Bonds | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Careerlumens_placard-green.epsEnergy1.pdfMarket37963 Vol.Department of EnergyMarchU.S.Bonds

224

The Molecular Bond: October 2014 | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe Molecular Bond: October 2014 The Molecular

225

Qualified Energy Conservation Bond (QECB) Update: New  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartment of EnergyQualified Energy Conservation Bond (QECB)

226

Qualified Energy Conservation Bonds | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartment of EnergyQualified EnergyBonds Qualified Energy

227

Covalent Bonding in Actinide Sandwich Molecules  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases on &gamma;-Al2O3. |ID#:Synchrotron RadiationCovalent Bonding

228

Cement Bond Log | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV EconomicsOregon: Energy ResourcesCeilingCement Bond

229

Chemically bonded phospho-silicate ceramics  

DOE Patents [OSTI]

A chemically bonded phospho-silicate ceramic formed by chemically reacting a monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and a sparsely soluble oxide, with a sparsely soluble silicate in an aqueous solution. The monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and sparsely soluble oxide are both in powder form and combined in a stochiometric molar ratio range of (0.5-1.5):1 to form a binder powder. Similarly, the sparsely soluble silicate is also in powder form and mixed with the binder powder to form a mixture. Water is added to the mixture to form a slurry. The water comprises 50% by weight of the powder mixture in said slurry. The slurry is allowed to harden. The resulting chemically bonded phospho-silicate ceramic exhibits high flexural strength, high compression strength, low porosity and permeability to water, has a definable and bio-compatible chemical composition, and is readily and easily colored to almost any desired shade or hue.

Wagh, Arun S. (Orland Park, IL); Jeong, Seung Y. (Westmont, IL); Lohan, Dirk (Chicago, IL); Elizabeth, Anne (Chicago, IL)

2003-01-01T23:59:59.000Z

230

Infinitely robust order and local order-parameter tulips in Apollonian networks with quenched disorder  

E-Print Network [OSTI]

For a variety of quenched random spin systems on an Apollonian network, including ferromagnetic and antiferromagnetic bond percolation and the Ising spin glass, we find the persistence of ordered phases up to infinite ...

Kaplan, C. Nadir

231

Protein folding on rugged energy landscapes: Conformational diffusion on fractal networks  

E-Print Network [OSTI]

We employ simulations of model proteins to study folding on rugged energy landscapes. We construct ``first-passage'' networks as the system transitions from unfolded to native states. The nodes and bonds in these networks correspond to basins and transitions between them in the energy landscape. We find power-laws between the folding time and number of nodes and bonds. We show that these scalings are determined by the fractal properties of first-passage networks. Reliable folding is possible in systems with rugged energy landscapes because first passage networks have small fractal dimension.

Gregg Lois; J. Blawzdziewicz; Corey S. O'Hern

2009-06-24T23:59:59.000Z

232

Torsion Testing of Diffusion Bonded LIGA Formed Nickel  

SciTech Connect (OSTI)

A test technique has been devised which is suitable for the testing of the bond strength of batch diffusion bonded LIGA or DXRL defined structures. The method uses a torsion tester constructed with the aid of LIGA fabrication and distributed torsion specimens which also make use of the high aspect ratio nature of DXRL based processing. Measurements reveal achieved bond strengths of 130MPa between electroplated nickel with a bond temperature of 450 C at 7 ksi pressure which is a sufficiently low temperature to avoid mechanical strength degradation.

Buchheit, T.E.; Christenson, T.R.; Schmale, D.T.

1999-01-27T23:59:59.000Z

233

Effects of atmospheres on bonding characteristics of silver and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

temperature. To investigate the effects of atmospheres on the bonding characteristics of ceramic joints brazed with Ag-CuO braze filler metals, alumina joints prepared using a...

234

FITCH RATES ENERGY NORTHWEST (WA) ELECTRIC REV REF BONDS 'AA...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FITCH RATES ENERGY NORTHWEST (WA) ELECTRIC REV REF BONDS 'AA'; OUTLOOK STABLE Fitch Ratings-Austin-08 April 2015: Fitch Ratings assigns 'AA' ratings to the following Energy...

235

Qualified Energy Conservation Bonds (QECBs) APPENDIX A: QECB...  

Broader source: Energy.gov (indexed) [DOE]

Qualified energy conservation bonds appendices. Author: U. S. Department of Energy Appendix A: QECB Counsel, Underwriters, Banks and Trustees More Documents & Publications...

236

ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Direct Bonded Aluminum (DBA) Substrates (Agreement ID:23278) 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

237

ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement...  

Broader source: Energy.gov (indexed) [DOE]

Low-Cost Direct Bonded Aluminum (DBA) Substrates H. -T. Lin, A. A. Wereszczak, and S. Waters Oak Ridge National Laboratory This presentation does not contain any proprietary,...

238

Wafer bonded epitaxial templates for silicon heterostructures  

DOE Patents [OSTI]

A heterostructure device layer is epitaxially grown on a virtual substrate, such as an InP/InGaAs/InP double heterostructure. A device substrate and a handle substrate form the virtual substrate. The device substrate is bonded to the handle substrate and is composed of a material suitable for fabrication of optoelectronic devices. The handle substrate is composed of a material suitable for providing mechanical support. The mechanical strength of the device and handle substrates is improved and the device substrate is thinned to leave a single-crystal film on the virtual substrate such as by exfoliation of a device film from the device substrate. An upper portion of the device film exfoliated from the device substrate is removed to provide a smoother and less defect prone surface for an optoelectronic device. A heterostructure is epitaxially grown on the smoothed surface in which an optoelectronic device may be fabricated.

Atwater, Jr., Harry A. (So. Pasadena, CA); Zahler, James M. (Pasadena, CA); Morral, Anna Fontcubera I (Paris, FR)

2008-03-11T23:59:59.000Z

239

Method of bonding single crystal quartz by field-assisted bonding  

DOE Patents [OSTI]

The method of producing a hermetic stable structural bond between quartz crystals includes providing first and second quartz crystals and depositing thin films of borosilicate glass and silicon on portions of the first and second crystals, respectively. The portions of the first and second crystals are then juxtaposed in a surface contact relationship and heated to a temperature for a period sufficient to cause the glass and silicon films to become electrically conductive. An electrical potential is then applied across the first and second crystals for creating an electrostatic field between the adjoining surfaces and causing the juxtaposed portions to be attracted into an intimate contact and form a bond for joining the adjoining surfaces of the crystals.

Curlee, Richard M. (Tijeras, NM); Tuthill, Clinton D. (Edgewood, NM); Watkins, Randall D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

240

Quantum Finance Hamiltonian for Coupon Bond European and Barrier Options  

E-Print Network [OSTI]

Quantum Finance Hamiltonian for Coupon Bond European and Barrier Options Belal E. Baaquie RMI are financial derivatives that can be analyzed in the Hamiltonian formulation of quantum finance. Forward-2963 Fax: (65) 6777-6126 Email: phybeb@nus.edu.sg #12;Quantum Finance Hamiltonian for Coupon Bond European

Chaudhuri, Sanjay

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

July 18, 2012 Qualified Energy Conservation Bond (QECB) Update: New  

E-Print Network [OSTI]

July 18, 2012 Qualified Energy Conservation Bond (QECB) Update: New Guidance from the U.S. Department of Treasury and the Internal Revenue Service Qualified Energy Conservation Bonds (QECBs a range of energy conservation projects at very attractive borrowing rates over long contract terms

242

BOND PROPERTIES OF CFCC PRESTRESSING STRANDS IN PRETENSIONED CONCRETE BEAMS  

E-Print Network [OSTI]

BOND PROPERTIES OF CFCC PRESTRESSING STRANDS IN PRETENSIONED CONCRETE BEAMS by Nolan G. Domenico plastic prestressing strands (CFCC) in pretensioned concrete beams. The bond characteristics are examined for 15.2 mm diameter and 12.5 mm diameter seven-wire CFCC strands. Ten prestressed concrete beams

243

Time- and temperature-dependent failures of a bonded joint  

SciTech Connect (OSTI)

Time and temperature dependent properties of a tubular lap bonded joint are reported. The joint bonds a cast iron rod and a composite pipe together with an epoxy type of an adhesive material containing chopped glass fiber. A new fabrication method is proposed.

Sihn, Sangwook; Miyano, Yasushi; Tsai, S.W. [Stanford Univ., Palo Alto, CA (United States)

1997-07-01T23:59:59.000Z

244

Electrically conductive resinous bond and method of manufacture  

DOE Patents [OSTI]

A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40 to 365/sup 0/C to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

Snowden, T.M. Jr.; Wells, B.J.

1985-01-01T23:59:59.000Z

245

Network Programming 1 Computer Networks  

E-Print Network [OSTI]

Network Programming 1 Computer Networks client/server architecture, protocols, and sockets 2;Network Programming 1 Computer Networks client/server architecture, protocols, and sockets 2 Network;client/server architecture Client/server architecture defines the communication between two computers

Verschelde, Jan

246

Clean renewable energy bonds (CREBs) present a low-cost opportunity for public entities to issue bonds to finance  

E-Print Network [OSTI]

Clean renewable energy bonds (CREBs) present a low-cost opportunity for public entities to issue bonds to finance renewable energy projects. The federal government lowers the cost of debt by providing created under the Energy Tax Incentives Act of 2005 (and detailed in Internal Revenue Code Section 54

247

Theoretical Electron Density Distributions for Fe-and Cu-Sulfide Earth Materials: A Connection between Bond Length, Bond Critical Point Properties, Local Energy Densities,  

E-Print Network [OSTI]

, Biomolecular and Chemical Sciences, UniVersity of Western Australia, Australia ReceiVed: August 7, 2006 between Bond Length, Bond Critical Point Properties, Local Energy Densities, and Bonded Interactions G. V; In Final Form: December 6, 2006 Bond critical point and local energy density properties together with net

Downs, Robert T.

248

Engineering the bonding scheme in C-S-H: The iono-covalent framework  

SciTech Connect (OSTI)

On the basis of recent molecular simulation and experimental studies, we discuss two possible strategies for tuning the mechanical properties of cementitious materials by modifying the bonding scheme in the hydrates at molecular level. We focus the discussion on the calcium silicate hydrates (C-S-H). A first strategy would be based on the strengthening of the network of cohesion forces acting between the individual C-S-H lamellae or between their crystallites. Atomic scale simulations by ab initio, molecular dynamics and energy minimization techniques show that the iono-covalent forces between individual C-S-H layers or C-S-H layer stacks, separated by strongly localized calcium ions and water molecules, are orders of magnitude larger than the ionic correlation forces acting between C-S-H surfaces separated by nm- or multi-nm-thick layers of mobile water molecules and ions. The elastic properties derived from this iono-covalent bonding scheme are in good agreement with experimental values obtained by ultrasonic or statistical ('grid') nanoindentation techniques. The concept picture for C-S-H which follows is that of a crystalline semi-continuum, with dense domains ('crystallites' or 'particles') iono-covalently bonded to each other, possibly entangled also, and embedded as long as the mesoscale porosity is water-saturated in a relatively weak attractive stress field due to fluctuating electrostatic forces. Depending on the size, the aspect ratio, and the turbostratic order of the crystallites, and also the composition of the interstitial solution, the relative importance of each contribution could be modified. This provides the basis for a better control of properties such as early age or long term strength development for instance. In this respect, the microstructure-properties relationships in clay minerals provide interesting leads, pointing to the importance of bonding continuity rather than bond strength. A second strategy to tune the mechanical properties of cement systems, akin to a biomimetic approach, is to hybridize the hydrates by grafting organic moieties on the mineral lamellae. This can be achieved by controlled hydrolysis of organo-silane precursor mixtures or by performing the hydration of the anhydrous silicates in silanized polymer solutions. The outcome may be materials with improved fracture energy and larger strain at failure.

Pellenq, R.J.-M. [Centre de Recherche en Matiere Condensee et Nanosciences, CNRS, Campus de Luminy, 13288 Marseille cedex 09 (France); Lequeux, N. [Ecole Superieure de Physique et de Chimie Industrielles, Physico-Chimie des Polymeres et des Milieux Disperses, UMR 7615 CNRS-ESPCI-UPMC, 10 rue Vauquelin, 75231 Paris cedex 05 (France); Damme, H. van [Ecole Superieure de Physique et de Chimie Industrielles, Physico-Chimie des Polymeres et des Milieux Disperses, UMR 7615 CNRS-ESPCI-UPMC, 10 rue Vauquelin, 75231 Paris cedex 05 (France)], E-mail: henri.vandamme@espci.fr

2008-02-15T23:59:59.000Z

249

Transient-Liquid-Phase (TLP) Bonding of Al2O3 Using Nb-based Multilayer Interlayers  

E-Print Network [OSTI]

Alumina Diffusion Bonding and Titanium Active Brazing.Requirements for Diffusion Bonding Titanium. In: Jaffee RI,O 3 -Titanium Adhesion in the View of the Diffusion Bonding

Hong, Sung Moo

2009-01-01T23:59:59.000Z

250

Transient-Liquid-Phase (TLP) Bonding of Al2O3 Using Nb-based Multilayer Interlayers  

E-Print Network [OSTI]

p. 539-44. Derby B. Diffusion Bonding. In: Nicholas M (ed).Requirements for Diffusion Bonding Titanium. In: Jaffee RI,Contact During Diffusion Bonding. Metallurgical Transactions

Hong, Sung Moo

2009-01-01T23:59:59.000Z

251

Preliminary Characterisation of Low-Temperature Bonded Copper Interconnects for 3-D Integrated Circuits  

E-Print Network [OSTI]

Three dimensional (3-D) integrated circuits can be fabricated by bonding previously processed device layers using metal-metal bonds that also serve as layer-to-layer interconnects. Bonded copper interconnects test structures ...

Leong, Hoi Liong

252

Bonding Low-density Nanoporous Metal Foams Using Sputtered Solder  

SciTech Connect (OSTI)

A method has been developed for bonding low-density nanoporous metal foam components to a substrate using solder that is sputtered onto the surfaces. Metal foams have unusual properties that make them excellent choices for many applications, and as technologies for processing these materials are evolving, their use in industry is increasing dramatically. Metal foams are lightweight and have advantageous dynamic properties, which make them excellent choices for many structural applications. They also provide good acoustic damping, low thermal conductivity, and excellent energy absorption characteristics. Therefore, these materials are commonly used in the automotive, aerospace, construction, and biomedical industries. The synthesis of nanoporous metal foams with a cell size of less then 1 {micro}m is an emerging technology that is expected to lead to widespread application of metal foams in microdevices, such as sensors and actuators. One of the challenges to manufacturing components from metal foams is that they can be difficult to attach to other structures without degrading their properties. For example, traditional liquid adhesives cannot be used because they are absorbed into foams. The problem of bonding or joining can be particularly difficult for small-scale devices made from nanoporous foam, due to the requirement for a thin bond layer. The current study addresses this problem and develops a method of soldering a nanoporous metal foam to a substrate with a bond thickness of less than 2 {micro}m. There are many applications that require micro-scale metal foams precisely bonded to substrates. This study was motivated by a physics experiment that used a laser to drive a shock wave through an aluminum foil and into a copper foam, in order to determine the speed of the shock in the copper foam. To avoid disturbing the shock, the interface between the copper foam and the aluminum substrate had to be as thin as possible. There are many other applications that could benefit from the bonding technology developed in this study, such as small-scale lightweight structural members, high-strength thermal insulating layers for electronics, and micro-scale mechanical dampers, to name but a few. Each of these applications requires one or more small metal foam components precisely bonded to a substrate. Several methods for bonding metal foam components have been developed by previous researchers. Macroscopic metal foam parts have been successfully bonded by laser welding to create T-sections and butt joints. Ultrasonic welding has been used to join aluminum sheet metal to aluminum foam for structural applications. These methods work well for bonding large foam components, but reducing these methods to a smaller length scale would be challenging. One method that has shown great potential for bonding layers of metal foams to substrates is a brazing process that uses a sputter-deposited interface material. Shirzadi et al.[9] have demonstrated bonds between stainless steel foam and a stainless steel substrate using a layer of copper-titanium filler metal that is sputtered onto the interface surfaces. The foam pieces that they bonded were approximately 10 mm in diameter and 10 mm thick with a cell size of approximately 200 {micro}m. After depositing the filler material, pressing the materials together, and heating them with an induction heater, bonds were achieved without causing significant damage to the foam. The current study also uses a sputter-deposited interface material to bond foam to a substrate. However, in contrast to previous work, the current study examines bonding microscale pieces of fragile nanoporous metal foam. In this study, a method is developed to bond a thin sheet of fragile, low-density nanoporous copper foam to an aluminum foil substrate of thickness 40 {micro}m. By sputter depositing an indium-silver alloy onto the foam and the substrate, a solder joint with a thickness of less than 2 {micro}m was achieved.

Bono, M; Cervantes, O; Akaba, C; Hamza, A; Foreman, R; Teslich, N

2007-08-21T23:59:59.000Z

253

Semi-flexible hydrogen-bonded and non-hydrogen bonded lattice polymers  

E-Print Network [OSTI]

We investigate the addition of stiffness to the lattice model of hydrogen-bonded polymers in two and three dimensions. We find that, in contrast to polymers that interact via a homogeneous short-range interaction, the collapse transition is unchanged by any amount of stiffness: this supports the physical argument that hydrogen bonding already introduces an effective stiffness. Contrary to possible physical arguments, favouring bends in the polymer does not return the model's behaviour to that comparable to the semi-flexible homogeneous interaction model, where the canonical $\\theta$-point occurs for a range of parameter values. In fact, for sufficiently large bending energies the crystal phase disappears altogether, and no phase transition of any type occurs. We also compare the order-disorder transition from the globule phase to crystalline phase in the semi-flexible homogeneous interaction model to that for the fully-flexible hybrid model with both hydrogen and non-hydrogen like interactions. We show that these phase transitions are of the same type and are a novel polymer critical phenomena in two dimensions. That is, it is confirmed that in two dimensions this transition is second-order, unlike in three dimensions where it is known to be first order. We also estimate the crossover exponent and show that there is a divergent specific heat, finding $\\phi=0.7(1)$ or equivalently $\\alpha=0.6(2)$. This is therefore different from the $\\theta$ transition, for which $\\alpha=-1/3$.

J Krawczyk; AL Owczarek; T Prellberg

2008-07-06T23:59:59.000Z

254

Surface Modification by Atmospheric Pressure Plasma for Improved Bonding  

E-Print Network [OSTI]

prepared using (a) the IPA wipe (control), (b) sanding, (c)of aluminum alloy 2024: a) IPA wiped, b) sanded with 180bond primer with a) the IPA wipe (control), b) sanding, c)

Williams, Thomas Scott

2013-01-01T23:59:59.000Z

255

Spectroscopic investigations of hydrogen bond dynamics in liquid water  

E-Print Network [OSTI]

Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

Fecko, Christopher J., 1975-

2004-01-01T23:59:59.000Z

256

Bond resonance energy and verification of the isolated pentagon rule  

SciTech Connect (OSTI)

The isolated pentagon rule (IPR) states that fullerenes with isolated pentagons are kinetically much more stable than their fused pentagon counterparts. This rule can be verified in terms of a graph-theoretically defined bond resonance energy. In general, a {pi} bond shared by two pentagons has a large negative bond resonance energy, thus contributing significantly to the increase in kinetic instability or chemical reactivity of the molecule. The existence of such highly antiaromatic local structures sharply distinguishes IPR-violating fullerenes from isolated-pentagon isomers. {pi}bonds shared by two pentagons are shared by many antiaromatic conjugated circuits but not by relatively small aromatic conjugated circuits. 39 refs., 3 figs., 5 tabs.

Aihara, Jun Ichi [Shizuoka Univ. (Japan)

1995-04-12T23:59:59.000Z

257

Qualified Energy Conservation Bond (QECB) Update: New Guidance...  

Broader source: Energy.gov (indexed) [DOE]

the U.S. Department of Treasury and the Internal Revenue Service Qualified Energy Conservation Bond (QECB) Update: New Guidance from the U.S. Department of Treasury and the...

258

Creep effects in diffusion bonding of oxygen-free copper  

E-Print Network [OSTI]

Diffusion is the transport of atoms or particles through the surrounding material. Various microstructural changes in metals are based on the diffusion phenomena. In solid metals the diffusion is closely related to crystallographic defects. In single-component metals the dominant mechanism of diffusion is the vacancy mechanism. Diffusion bonding is a direct technological application of diffusion. It is an advanced solidstate joining process in which the surfaces of two components are brought to contact with each other and heated under a pressing load in a controlled environment. During the process, the contact surfaces are bonded by atomic diffusion across the interface and as a result, one solid piece is formed. The condition of high temperature and low applied stress combined with relatively long process duration enables the creep effects to take place in bonded metals. Furthermore, creep causes unwanted permanent deformations in the bonded components. Some authors suggest that there could be a threshold fo...

Moilanen, Antti

259

Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids  

SciTech Connect (OSTI)

We develop a resummed thermodynamic perturbation theory for bond cooperativity in associating fluids by extension of Wertheim's multi-density formalism. We specifically consider the case of an associating hard sphere with two association sites and both pairwise and triplet contributions to the energy, such that the first bond in an associated cluster receives an energy ??{sup (1)} and each subsequent bond in the cluster receives an energy ??{sup (2)}. To test the theory we perform new Monte Carlo simulations for potentials of this type. Theory and simulation are found to be in excellent agreement. We show that decreasing the energetic benefit of hydrogen bonding can actually result in a decrease in internal energy in the fluid. We also predict that when ?{sup (1)} = 0 and ?{sup (2)} is nonzero there is a transition temperature where the system transitions from a fluid of monomers to a mixture of monomers and very long chains.

Marshall, Bennett D., E-mail: bennettd1980@gmail.com; Chapman, Walter G. [Department of Chemical and Biomolecular Engineering, Rice University, 6100 S. Main, Houston, Texas 77005 (United States)] [Department of Chemical and Biomolecular Engineering, Rice University, 6100 S. Main, Houston, Texas 77005 (United States)

2013-12-07T23:59:59.000Z

260

FITCH RATES PORT OF MORROW (OR) TRANSMISSION FACILITIES REV BONDS...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FITCH RATES PORT OF MORROW (OR) TRANSMISSION FACILITIES REV BONDS 'AA'; OUTLOOK STABLE Fitch Ratings-Austin-24 November 2014: Fitch Ratings assigns 'AA' ratings to the Port of...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Low-Cost Financing with Clean Renewable Energy Bonds  

Broader source: Energy.gov [DOE]

Contains information from the TAP Webcast on June 24, 2009 on clean renewable energy bonds from Claire Kreycik on feed-in tariffs, an economic resource for developing renewable energy.

262

Application of Social Impact Bonds in Built Infrastructure Sustainability Projects  

E-Print Network [OSTI]

This study examines a first look at the implementation of Social Impact Bonds (SIB) for sustainability projects by comparing two cases. The cases are described using System Dynamic (SD) modeling to portray the feedback structures and characteristics...

White, Robert Joseph

2014-05-01T23:59:59.000Z

263

Low-Cost Direct Bonded Aluminum (DBA) Substrates  

Broader source: Energy.gov (indexed) [DOE]

Low-Cost Direct Bonded Aluminum (DBA) Substrates H. -T. Lin, A. A. Wereszczak, M. L. Santella, and G. Muralidharan Oak Ridge National Laboratory (ORNL) This presentation does not...

264

Mpemba paradox: Hydrogen bond memory and water-skin supersolidity  

E-Print Network [OSTI]

Numerical reproduction of measurements, experimental evidence for skin super-solidity and hydrogen-bond memory clarified that Mpemba paradox integrates the heat emission-conduction-dissipation dynamics in the source-path-drain cycle system.

Chang Q Sun

2015-01-05T23:59:59.000Z

265

Fractionation, rearrangement, consolidation, reconstruction  

E-Print Network [OSTI]

is an innovation. WGD and fractionation are particularly prevalent in flowering plants [6], where the slow (tens itself does not add any new adjacencies or remove any; the pre-existing adjacencies simply continue or by pseudogenization. Even if xy and yz still exist in the homeologous region of the genome, the adjacency xz

El-Mabrouk, Nadia

266

Bond Distortions in Armchair Type Single Wall Carbon Nanotubes  

E-Print Network [OSTI]

The energy band gap structure and stability of (3,3) and (10,10) nanotubes have been comparatively investigated in the frameworks of the traditional form of the Su-Schrieffer-Heeger (SSH) model and a toy model including the contributions of bonds of different types to the SSH Hamiltonian differently. Both models give the same energy band gap structure but bond length distortions in different characters for the nanotubes.

N. Sunel; E. Rizaoglu; K. Harigaya; O. Ozsoy

2005-03-03T23:59:59.000Z

267

Microbial cleavage of organic C-S bonds  

DOE Patents [OSTI]

A microbial process is described for selective cleavage of organic C-S bonds which may be used for reducing the sulfur content of sulfur-containing organic carbonaceous materials. Microorganisms of Rhodococcus rhodochrous and Bacillus sphaericus have been found which have the ability of selective cleavage of organic C-S bonds. Particularly preferred microorganisms are Rhodococcus rhodochrous strain ATCC 53968 and Bacillus sphaericus strain ATCC 53969 and their derivatives.

Kilbane, J.J. II.

1994-10-25T23:59:59.000Z

268

BN Bonded BN fiber article and method of manufacture  

DOE Patents [OSTI]

A boron nitride bonded boron nitride fiber article and the method for its manufacture which comprises forming a shaped article with a composition comprising a bonding compound selected from boron oxide and boric acid and a structural fiber selected from the group consisting of boron oxide, boron nitride and partially nitrided boron oxide fibers, heating the composition in an anhydrous gas to a temperature above the melting point of the compound and nitriding the resulting article in ammonia gas.

Hamilton, Robert S. (Youngstown, NY)

1981-08-18T23:59:59.000Z

269

Mercury stabilization in chemically bonded phosphate ceramics  

SciTech Connect (OSTI)

Mercury stabilization and solidification is a significant challenge for conventional stabilization technologies. This is because of the stringent regulatory limits on leaching of its stabilized products. In a conventional cement stabilization process, Hg is converted at high pH to its hydroxide, which is not a very insoluble compound; hence the preferred route for Hg sulfidation to convert it into insoluble cinnabar (HgS). Unfortunately, efficient formation of this compound is pH-dependent. At a high pH, one obtains a more soluble Hg sulfate, in a very low pH range, insufficient immobilization occurs because of the escape of hydrogen sulfide, while efficient formation of HgS occurs only in a moderately acidic region. Thus, the pH range of 4 to 8 is where stabilization with Chemically Bonded Phosphate Ceramics (CBPC) is carried out. This paper discusses the authors experience on bench-scale stabilization of various US Department of Energy (DOE) waste streams containing Hg in the CBPC process. This process was developed to treat DOE's mixed waste streams. It is a room-temperature-setting process based on an acid-base reaction between magnesium oxide and monopotassium phosphate solution that forms a dense ceramic within hours. For Hg stabilization, addition of a small amount (< 1 wt.%) of Na{sub 2}S or K{sub 2}S is sufficient in the binder composition. Here the Toxicity Characteristic Leaching Procedure (TCLP) results on CBPC waste forms of surrogate waste streams representing secondary Hg containing wastes such as combustion residues and Delphi DETOX{trademark} residues are presented. The results show that although the current limit on leaching of Hg is 0.2 mg/L, the results from the CBPC waste forms are at least one order lower than this stringent limit. Encouraged by these results on surrogate wastes, they treated actual low-level Hg-containing mixed waste from their facility at Idaho. TCLP results on this waste are presented here. The efficient stabilization in all these cases is attributed to chemical immobilization as both a sulfide (cinnabar) and a phosphate, followed by its physical encapsulation in a dense matrix of the ceramic.

Wagh, A. S.; Singh, D.; Jeong, S. Y.

2000-04-04T23:59:59.000Z

270

Bonded Bracket Assmebly for Frameless Solar Panels  

SciTech Connect (OSTI)

In February 2011 the US Department of Energy announced their new Sunshot Initiative. The Sunshot goal is to reduce the total cost of solar energy systems by about 75 percent before the end of the decade. The DOE estimated that a total installed cost of $1 per watt for photovoltaic systems would be equivalent to 6???¢/kilowatt hour (kWh) for energy available from the grid. The DOE also estimated that to meet the $1 per watt goal, PV module costs would need to be reduced to $.50 per watt, balance of systems costs would need to be reduced to $.40 per watt, and power electronic costs would need to reach $.10 per watt. To address the BOS balance of systems cost component of the $1 per watt goal, the DOE announced a funding opportunity called (BOS-X) Extreme Balance of System Hardware Cost Reductions. The DOE identified eight areas within the total BOS costs: 1) installation labor, 2) installation materials, 3) installation overhead and profit, 4) tracker, 5) permitting and commissioning, 6) site preparation, 7) land acquisition, 8) sales tax. The BOS-X funding announcement requested applications in four specific topics: Topic 1: Transformational Building Integrated Photovoltaic (BIPV) Modules Topic 2: Roof and Ground Mount Innovations Topic 3: Transformational Photovoltaic System Designs Topic 4: Development of New Wind Load Codes for PV Systems The application submitted by ARaymond Tinnerman reflected the requirements listed in Topic #2, Roof and Ground Mount Innovations. The goal of topic #2 was to develop technologies that would result in the extreme reduction of material and labor costs associated with applications that require physical connections and attachments to roof and ground mount structures. The topics researched in this project included component cost reduction, labor reduction, weight reduction, wiring innovations, and alternative material utilization. The project objectives included: 1) The development of an innovative quick snap bracket assembly that would be bonded to frameless PV modules for commercial rooftop installations. 2) The development of a composite pultruded rail to replace traditional racking materials. 3) In partnership with a roofing company, pilot the certification of a commercial roof to be solar panel compliant, eliminating the need for structural analysis and government oversight resulting in significantly decreased permitting costs. 4) Reduce the sum of all cost impacts in topic #2 from a baseline total of $2.05/watt to $.34/watt.

Murray, Todd

2013-01-30T23:59:59.000Z

271

Two-step build-up of a thermoreversible polymer network: From early local to late collective dynamics  

E-Print Network [OSTI]

We probe the mechanisms at work in the build-up of thermoreversible gel networks, with the help of hybrid gelatin gels containing a controlled density of irreversible, covalent crosslinks (CL), which we quench below the physical gelation temperature. The detailed analysis of the dependence on covalent crosslink density of both the shear modulus and optical activity evolutions with time after quench enables us to identify two stages of the physical gelation process, separated by a temperature dependent crossover modulus: (i) an early nucleation regime during which rearrangements of the triple-helix CL play a negligible role, (ii) a late, logarithmic aging one, which is preserved, though slowed down, in the presence of irreversible CL. We show that aging is fully controlled by rearrangements and discuss the implication of our results in terms of the switch from an early, local dynamics to a late, cooperative long-range one.

H. Souguir; O. Ronsin; C. Caroli; T. Baumberger

2015-03-05T23:59:59.000Z

272

Dynamics on modular networks with heterogeneous correlations  

SciTech Connect (OSTI)

We develop a new ensemble of modular random graphs in which degree-degree correlations can be different in each module, and the inter-module connections are defined by the joint degree-degree distribution of nodes for each pair of modules. We present an analytical approach that allows one to analyze several types of binary dynamics operating on such networks, and we illustrate our approach using bond percolation, site percolation, and the Watts threshold model. The new network ensemble generalizes existing models (e.g., the well-known configuration model and Lancichinetti-Fortunato-Radicchi networks) by allowing a heterogeneous distribution of degree-degree correlations across modules, which is important for the consideration of nonidentical interacting networks.

Melnik, Sergey [MACSI, Department of Mathematics and Statistics, University of Limerick (Ireland) [MACSI, Department of Mathematics and Statistics, University of Limerick (Ireland); Oxford Centre for Industrial and Applied Mathematics, Mathematical Institute, University of Oxford, Oxford OX2 6GG (United Kingdom); CABDyN Complexity Centre, University of Oxford, Oxford OX1 1HP (United Kingdom); Porter, Mason A. [Oxford Centre for Industrial and Applied Mathematics, Mathematical Institute, University of Oxford, Oxford OX2 6GG (United Kingdom) [Oxford Centre for Industrial and Applied Mathematics, Mathematical Institute, University of Oxford, Oxford OX2 6GG (United Kingdom); CABDyN Complexity Centre, University of Oxford, Oxford OX1 1HP (United Kingdom); Mucha, Peter J. [Department of Mathematics, Carolina Center for Interdisciplinary Applied Mathematics, University of North Carolina, Chapel Hill, North Carolina 27599-3250 (United States) [Department of Mathematics, Carolina Center for Interdisciplinary Applied Mathematics, University of North Carolina, Chapel Hill, North Carolina 27599-3250 (United States); Institute for Advanced Materials, Nanoscience and Technology, University of North Carolina, Chapel Hill, North Carolina 27599-3216 (United States); Gleeson, James P. [MACSI, Department of Mathematics and Statistics, University of Limerick (Ireland)] [MACSI, Department of Mathematics and Statistics, University of Limerick (Ireland)

2014-06-15T23:59:59.000Z

273

PROPOSED MODIFICATION TO THE ACI 318-02 CODE EQUATION ON BOND STRENGTH FOR MMFX STEEL  

E-Print Network [OSTI]

ST-263-1 PROPOSED MODIFICATION TO THE ACI 318-02 CODE EQUATION ON BOND STRENGTH FOR MMFX STEEL R the bond characteristics of Micro-composite Multi-structural Formable reinforcing steel rebars of the current equation of the ACI 318-02 Code on bond to predict the bond capacity of the MMFX steel rebars

274

Mechanical Study of Copper Bonded at Low Temperature using Spark Plasma Sintering Process  

E-Print Network [OSTI]

is approximatively 6.47 MPa [7]. J. W. Elmer & al [8] have presented a diffusion bonding of high purity copper using a conventional furnace. A series of diffusion bonds was done to determine the relationship between bond strengthMechanical Study of Copper Bonded at Low Temperature using Spark Plasma Sintering Process Bassem

Paris-Sud XI, Universit de

275

Highly Efficient Vertical Outgassing Channels for Robust, Void-Free, Low-Temperature Direct Wafer Bonding  

E-Print Network [OSTI]

molecules diffusion at bonding interface to VOCs. Conventional anneal time of 12-18 hours required to bond Bonding Di Liang1 , Erik A. Lucero2 , John E. Bowers1 1 Department of Electrical and Computer Engineering wafer bonding is favored for dissimilar materials integration, particularly in III-V compound

Bowers, John

276

The C OH O hydrogen bond: A determinant of stability and specificity  

E-Print Network [OSTI]

recovered by hydro- gen bond formation, so hydrogen bonds provide a small or even unfavorable net energy hydro- gen bond has been unclear and its interaction energy has been believed to be small. Recently that apparent carbon hydro- gen bonds cluster frequently at glycine-, serine-, and threonine-rich packing

Senes, Alessandro

277

Thermal Performance and Reliability of Bonded Interfaces for Power Electronics Packaging Applications (Presentation)  

SciTech Connect (OSTI)

This presentation discusses the thermal performance and reliability of bonded interfaces for power electronics packaging applications.

Devoto, D.

2013-07-01T23:59:59.000Z

278

A new hydrogen-bonding potential for the design of proteinRNA interactions predicts specific  

E-Print Network [OSTI]

A new hydrogen-bonding potential for the design of protein­RNA interactions predicts specific-dependent hydrogen-bonding potential based on the statistical analysis of hydrogen-bonding geometries of hydrogen-bonding atom pairs at protein­ nucleic acid interfaces. A scoring function based on the hydrogen

Baker, David

279

Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical Exchange Spectroscopy  

E-Print Network [OSTI]

Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical ExchangeVed: January 12, 2010 Hydrogen-bonded complexes between phenol and phenylacetylene are studied using ultrafast hydrogen bonding acceptor sites (phenyl or acetylene) that compete for hydrogen bond donors in solution

Fayer, Michael D.

280

Effect of quantum nuclear motion on hydrogen bonding  

SciTech Connect (OSTI)

This work considers how the properties of hydrogen bonded complexes, XH?Y, are modified by the quantum motion of the shared proton. Using a simple two-diabatic state model Hamiltonian, the analysis of the symmetric case, where the donor (X) and acceptor (Y) have the same proton affinity, is carried out. For quantitative comparisons, a parametrization specific to the OH?O complexes is used. The vibrational energy levels of the one-dimensional ground state adiabatic potential of the model are used to make quantitative comparisons with a vast body of condensed phase data, spanning a donor-acceptor separation (R) range of about 2.4 ? 3.0, i.e., from strong to weak hydrogen bonds. The position of the proton (which determines the XH bond length) and its longitudinal vibrational frequency, along with the isotope effects in both are described quantitatively. An analysis of the secondary geometric isotope effect, using a simple extension of the two-state model, yields an improved agreement of the predicted variation with R of frequency isotope effects. The role of bending modes is also considered: their quantum effects compete with those of the stretching mode for weak to moderate H-bond strengths. In spite of the economy in the parametrization of the model used, it offers key insights into the defining features of H-bonds, and semi-quantitatively captures several trends.

McKenzie, Ross H., E-mail: r.mckenzie@uq.edu.au; Bekker, Christiaan [School of Mathematics and Physics, University of Queensland, Brisbane 4072 (Australia)] [School of Mathematics and Physics, University of Queensland, Brisbane 4072 (Australia); Athokpam, Bijyalaxmi; Ramesh, Sai G. [Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012 (India)] [Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012 (India)

2014-05-07T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Discrete element modeling of rock deformation, fracture network development and permeability evolution under hydraulic stimulation  

SciTech Connect (OSTI)

Key challenges associated with the EGS reservoir development include the ability to reliably predict hydraulic fracturing and the deformation of natural fractures as well as estimating permeability evolution of the fracture network with time. We have developed a physics-based rock deformation and fracture propagation simulator by coupling a discrete element model (DEM) for fracturing with a network flow model. In DEM model, solid rock is represented by a network of discrete elements (often referred as particles) connected by various types of mechanical bonds such as springs, elastic beams or bonds that have more complex properties (such as stress-dependent elastic constants). Fracturing is represented explicitly as broken bonds (microcracks), which form and coalesce into macroscopic fractures when external and internal load is applied. The natural fractures are represented by a series of connected line segments. Mechanical bonds that intersect with such line segments are removed from the DEM model. A network flow model using conjugate lattice to the DEM network is developed and coupled with the DEM. The fluid pressure gradient exerts forces on individual elements of the DEM network, which therefore deforms the mechanical bonds and breaks them if the deformation reaches a prescribed threshold value. Such deformation/fracturing in turn changes the permeability of the flow network, which again changes the evolution of fluid pressure, intimately coupling the two processes. The intimate coupling between fracturing/deformation of fracture networks and fluid flow makes the meso-scale DEM- network flow simulations necessary in order to accurately evaluate the permeability evolution, as these methods have substantial advantages over conventional continuum mechanical models of elastic rock deformation. The challenges that must be overcome to simulate EGS reservoir stimulation, preliminary results, progress to date and near future research directions and opportunities will be discussed. Methodology for coupling the DEM model with continuum flow and heat transport models will also be discussed.

Shouchun Deng; Robert Podgorney; Hai Huang

2011-02-01T23:59:59.000Z

282

Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation  

SciTech Connect (OSTI)

Once considered the 'holy grail' of organometallic chemistry, synthetically useful reactions employing C-H bond activation have increasingly been developed and applied to natural product and drug synthesis over the past decade. The ubiquity and relative low cost of hydrocarbons makes C-H bond functionalization an attractive alternative to classical C-C bond forming reactions such as cross-coupling, which require organohalides and organometallic reagents. In addition to providing an atom economical alternative to standard cross - coupling strategies, C-H bond functionalization also reduces the production of toxic by-products, thereby contributing to the growing field of reactions with decreased environmental impact. In the area of C-C bond forming reactions that proceed via a C-H activation mechanism, rhodium catalysts stand out for their functional group tolerance and wide range of synthetic utility. Over the course of the last decade, many Rh-catalyzed methods for heteroatom-directed C-H bond functionalization have been reported and will be the focus of this review. Material appearing in the literature prior to 2001 has been reviewed previously and will only be introduced as background when necessary. The synthesis of complex molecules from relatively simple precursors has long been a goal for many organic chemists. The ability to selectively functionalize a molecule with minimal pre-activation can streamline syntheses and expand the opportunities to explore the utility of complex molecules in areas ranging from the pharmaceutical industry to materials science. Indeed, the issue of selectivity is paramount in the development of all C-H bond functionalization methods. Several groups have developed elegant approaches towards achieving selectivity in molecules that possess many sterically and electronically similar C-H bonds. Many of these approaches are discussed in detail in the accompanying articles in this special issue of Chemical Reviews. One approach that has seen widespread success involves the use of a proximal heteroatom that serves as a directing group for the selective functionalization of a specific C-H bond. In a survey of examples of heteroatom-directed Rh catalysis, two mechanistically distinct reaction pathways are revealed. In one case, the heteroatom acts as a chelator to bind the Rh catalyst, facilitating reactivity at a proximal site. In this case, the formation of a five-membered metallacycle provides a favorable driving force in inducing reactivity at the desired location. In the other case, the heteroatom initially coordinates the Rh catalyst and then acts to stabilize the formation of a metal-carbon bond at a proximal site. A true test of the utility of a synthetic method is in its application to the synthesis of natural products or complex molecules. Several groups have demonstrated the applicability of C-H bond functionalization reactions towards complex molecule synthesis. Target-oriented synthesis provides a platform to test the effectiveness of a method in unique chemical and steric environments. In this respect, Rh-catalyzed methods for C-H bond functionalization stand out, with several syntheses being described in the literature that utilize C-H bond functionalization in a key step. These syntheses are highlighted following the discussion of the method they employ.

Colby, Denise; Bergman, Robert; Ellman, Jonathan

2010-05-13T23:59:59.000Z

283

Metal-bonded, carbon fiber-reinforced composites  

DOE Patents [OSTI]

Metal bonded carbon fiber-reinforced composites are disclosed in which the metal and the composite are strongly bound by (1) providing a matrix-depleted zone in the composite of sufficient depth to provide a binding site for the metal to be bonded and then (2) infiltrating the metal into the matrix-free zone to fill a substantial portion of the zone and also provide a surface layer of metal, thereby forming a strong bond between the composite and the metal. The invention also includes the metal-bound composite itself, as well as the provision of a coating over the metal for high-temperature performance or for joining to other such composites or to other substrates. 2 figs.

Sastri, S.A.; Pemsler, J.P.; Cooke, R.A.; Litchfield, J.K.; Smith, M.B.

1996-03-05T23:59:59.000Z

284

Metal-bonded, carbon fiber-reinforced composites  

DOE Patents [OSTI]

Metal bonded carbon fiber-reinforced composites are disclosed in which the metal and the composite are strongly bound by (1) providing a matrix-depleted zone in the composite of sufficient depth to provide a binding site for the metal to be bonded and then (2) infiltrating the metal into the matrix-free zone to fill a substantial portion of the zone and also provide a surface layer of metal, thereby forming a strong bond between the composite and the metal. The invention also includes the metal-bound composite itself, as well as the provision of a coating over the metal for high-temperature performance or for joining to other such composites or to other substrates.

Sastri, Suri A. (Lexington, MA); Pemsler, J. Paul (Lexington, MA); Cooke, Richard A. (Framingham, MA); Litchfield, John K. (Bedford, MA); Smith, Mark B. (Ipswich, MA)

1996-01-01T23:59:59.000Z

285

Chemical strategies for die/wafer submicron alignment and bonding.  

SciTech Connect (OSTI)

This late-start LDRD explores chemical strategies that will enable sub-micron alignment accuracy of dies and wafers by exploiting the interfacial energies of chemical ligands. We have micropatterned commensurate features, such as 2-d arrays of micron-sized gold lines on the die to be bonded. Each gold line is functionalized with alkanethiol ligands before the die are brought into contact. The ligand interfacial energy is minimized when the lines on the die are brought into registration, due to favorable interactions between the complementary ligand tails. After registration is achieved, standard bonding techniques are used to create precision permanent bonds. We have computed the alignment forces and torque between two surfaces patterned with arrays of lines or square pads to illustrate how best to maximize the tendency to align. We also discuss complex, aperiodic patterns such as rectilinear pad assemblies, concentric circles, and spirals that point the way towards extremely precise alignment.

Martin, James Ellis; Baca, Alicia I.; Chu, Dahwey; Rohwer, Lauren Elizabeth Shea

2010-09-01T23:59:59.000Z

286

Students' Interdisciplinary Reasoning about "High-Energy Bonds" and ATP  

E-Print Network [OSTI]

Students' sometimes contradictory ideas about ATP (adenosine triphosphate) and the nature of chemical bonds have been studied in the biology and chemistry education literatures, but these topics are rarely part of the introductory physics curriculum. We present qualitative data from an introductory physics course for undergraduate biology majors that seeks to build greater interdisciplinary coherence and therefore includes these topics. In these data, students grapple with the apparent contradiction between the energy released when the phosphate bond in ATP is broken and the idea that an energy input is required to break a bond. We see that students' perceptions of how each scientific discipline bounds the system of interest can influence how they justify their reasoning about a topic that crosses disciplines. This has consequences for a vision of interdisciplinary education that respects disciplinary perspectives while bringing them into interaction in ways that demonstrate consistency amongst the perspectiv...

Dreyfus, Benjamin W; Sawtelle, Vashti; Svoboda, Julia; Turpen, Chandra; Redish, Edward F

2012-01-01T23:59:59.000Z

287

Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate  

E-Print Network [OSTI]

Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

Goddard III, William A.

288

The diffusion bonding of silicon carbide and boron carbide using refractory metals  

SciTech Connect (OSTI)

Joining is an enabling technology for the application of structural ceramics at high temperatures. Metal foil diffusion bonding is a simple process for joining silicon carbide or boron carbide by solid-state, diffusive conversion of the metal foil into carbide and silicide compounds that produce bonding. Metal diffusion bonding trials were performed using thin foils (5 {micro}m to 100 {micro}m) of refractory metals (niobium, titanium, tungsten, and molybdenum) with plates of silicon carbide (both {alpha}-SiC and {beta}-SiC) or boron carbide that were lapped flat prior to bonding. The influence of bonding temperature, bonding pressure, and foil thickness on bond quality was determined from metallographic inspection of the bonds. The microstructure and phases in the joint region of the diffusion bonds were evaluated using SEM, microprobe, and AES analysis. The use of molybdenum foil appeared to result in the highest quality bond of the metal foils evaluated for the diffusion bonding of silicon carbide and boron carbide. Bonding pressure appeared to have little influence on bond quality. The use of a thinner metal foil improved the bond quality. The microstructure of the bond region produced with either the {alpha}-SiC and {beta}-SiC polytypes were similar.

Cockeram, B.V.

1999-10-01T23:59:59.000Z

289

High- and low-temperature bonding techniques for microstructures  

SciTech Connect (OSTI)

The ability to bond together two or more silicon wafers greatly expands the variety and complexity of silicon microstructures that can be designed and fabricated. At LLNL, microstructures have been used for many years as hardware in scientific experiments. The activity has recently been expanded into other areas to include microinstruments for biomedical applications and for chemical analysis. Both high temperature (1100{degrees}C) bonding techniques have been used, depending on the application. This paper discusses these applications with emphasis on the most extensive which is the fabrication of microchannel coolers for diode arrays.

Ciarlo, D.R.

1993-06-22T23:59:59.000Z

290

Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids with small bond angles: Effects of steric hindrance and ring formation  

E-Print Network [OSTI]

In this paper we develop a thermodynamic perturbation theory for two site associating fluids which exhibit bond cooperativity. We include both steric hindrance and ring formation such that the equation of state is bond angle dependent. Here the bond angle is the angle separating the centers of the two association sites. As a test, new Monte Carlo simulations are performed, and the theory is found to accurately predict the internal energy as well as the distribution of associated clusters as a function of bond angle and bond cooperativity.

B. D. Marshall; Amin Haghmoradi; W. G. Chapman

2014-04-03T23:59:59.000Z

291

Cognitive Radio Networks as Sensor Networks  

E-Print Network [OSTI]

is used, assuming the cognitive radios know their ownfor Embedded Networked Sensing Cognitive Radio Networks AsJ. Pottie Introduction: Cognitive Radio (CR) Networks The

Bandari, Dorna; Yang, Seung R.; Zhao, Yue; Pottie, Gregory

2007-01-01T23:59:59.000Z

292

Method of preparation of bonded polyimide fuel cell package  

DOE Patents [OSTI]

Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan (Livermore, CA); Graff, Robert T. (Modesto, CA); Bettencourt, Kerry (Dublin, CA)

2011-04-26T23:59:59.000Z

293

Vibrational Signature of Water Molecules in Asymmetric Hydrogen Bonding Environments  

E-Print Network [OSTI]

Vibrational Signature of Water Molecules in Asymmetric Hydrogen Bonding Environments Chao Zhang contributions of each of the two hydrogen atoms to the vibrational modes 1 and 3 of water molecules the early works on the molecular structure of water, it has been accepted that a water molecule

Guidoni, Leonardo

294

Structural and bonding trends in platinum-carbon clusters  

E-Print Network [OSTI]

. Trends in stability, Pt+-Cx binding energy, doublet-quartet excitation energy, and Pt-C bond lengths were investigated. Explanations for these patterns are provided in terms of orbital interactions and changes imposed on the carbon-chain by the metal...

Miller, Thomas F

2013-02-22T23:59:59.000Z

295

Bond Strength of ASTM A 1035 Grade 100 Reinforcing Steel  

E-Print Network [OSTI]

The bond strength of ASTM A 1035 Grade 100 reinforcing steel is evaluated relative to the values predicted using the development expressions in ACI 318-05 and ACI 408R-03. Sixty-nine beam-splice specimens were tested at the University of Kansas...

Briggs, Michael

2008-04-24T23:59:59.000Z

296

A Single Disulfide Bond Differentiates Aggregation Pathways of 2-Microglobulin  

E-Print Network [OSTI]

simulation; aggregation; domain swapping*Corresponding author Introduction Amyloid fibrils are insolubleA Single Disulfide Bond Differentiates Aggregation Pathways of 2-Microglobulin Yiwen Chen1 at Chapel Hill Chapel Hill, NC 27599, USA Deposition of wild-type 2-microglobulin (2m) into amyloid

Dokholyan, Nikolay V.

297

WHAT'S GRAPHENE? Mono or few layers of sp2 bonded  

E-Print Network [OSTI]

WHAT'S GRAPHENE? · Mono or few layers of sp2 bonded carbon atoms in a honeycomb lattice 105cm2/Vs at RT. 1 Due to its unique transport properties, graphene is suitable for implementation sampling (EOS) timeresolved spectroscopy to optically pump and THz probe exfoliated graphene ribbons (GR

Mellor-Crummey, John

298

Diffusion limited cluster aggregation with irreversible flexible bonds  

E-Print Network [OSTI]

Irreversible diffusion limited cluster aggregation (DLCA) of hard spheres was simulated using Brownian cluster dynamics. Bound spheres were allowed to move freely within a specified range, but no bond breaking was allowed. The structure and size distribution of the clusters was investigated before gelation. The pair correlation function and the static structure factor of the gels were determined as a function of the volume fraction and time. Bond flexibility led to local densification of the clusters and the gels, with a certain degree of order. At low volume fractions densification of the clusters occurred during their growth, but at higher volume fractions it occurred mainly after gelation. At very low volume fractions, the large scale structure (fractal dimension), size distribution and growth kinetics of the clusters was found to be close to that known for DLCA with rigid bonds. Restructuring of the gels continued for long times, indicating that aging processes in systems with strong attraction do not necessarily involve bond breaking. The mean square displacement of particles in the gels was determined. It is shown to be highly heterogeneous and to increase with decreasing volume fraction.

Sujin Babu; Jean-Christophe Gimel; Taco Nicolai

2008-01-29T23:59:59.000Z

299

Advance Refundings of Municipal Bonds Columbia Business School  

E-Print Network [OSTI]

Advance Refundings of Municipal Bonds Andrew Ang Columbia Business School and NBER Richard C. Green of Vineer Bhansali, Trevor Harris, Tal Heppenstall, Andrew Kalotay, Kemp Lewis, Paul Luhmann, Matt of colleagues, especially Jennifer Carpenter, Dan Li, Norman Sch¨urhoff, and Chester Spatt, along with seminar

Sadeh, Norman M.

300

Bonded labour The Dalits of Nepal are a marginalised  

E-Print Network [OSTI]

Bonded labour The Dalits of Nepal are a marginalised group of people who have suffered systematic that, while illegal, is still widespread in remote rural areas of Nepal. To meet their basic needs in their neighbour- hood. Referred to in Nepal as Haliya/ Haruwa and Charuwa, they have to plough the landlords' land

Richner, Heinz

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Water inertial reorientation: Hydrogen bond strength and the angular potential  

E-Print Network [OSTI]

Water inertial reorientation: Hydrogen bond strength and the angular potential David E. Moilanen) The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy with recent molecular dynamics simulations employing the simple point charge-extended water model at room

Fayer, Michael D.

302

Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids  

E-Print Network [OSTI]

We develop a resummed thermodynamic perturbation theory for bond cooperativity in associating fluids by extension of Wertheim's multi - density formalism. We specifically consider the case of an associating hard sphere with two association sites and both pairwise and triplet contributions to the energy. To test the theory we perform new monte carlo simulations. Theory and simulation are found to be in excellent agreement.

B. D. Marshall; W. G. Chapman

2013-09-18T23:59:59.000Z

303

alteredintramolecular hydrogen-bonding pattern: Topics by E-print...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alteredintramolecular hydrogen-bonding pattern First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1...

304

Hydrogen Bonding Increases Packing Density in the Protein Interior  

E-Print Network [OSTI]

Hydrogen Bonding Increases Packing Density in the Protein Interior David Schell,1,2 Jerry Tsai,1 J System Health Science Center, College Station, Texas 77843-1114 ABSTRACT The contribution of hydrogen to the stability, but experimental studies show that bury- ing polar groups, especially those that are hydrogen

305

Concept generation of dynamic systems using bond graphs  

E-Print Network [OSTI]

REPRESENTATIONS OF IMMITTANCES . . . Immittance synthesis in design Conventional immit tance synthesis techniques by Foster and Cauer Immittance synthesis with bond graphs . . . . . . . . . . . . . Example - Synthesis of two frequency absorber... . . . . . . . . . 35 . 35 . 38 . . . . . . 40 . . . . . . 49 TABLE OF CONTENTS (Continued) CHAPTER Page V PHYSICAL REPRESENTATIONS OF TRANSFER FUNCTIONS Transfer function synthesis in design . . . . . . . . . . . General procedure Conditions for passive...

Krishnan, S

1990-01-01T23:59:59.000Z

306

Comparing systemic risk in European government bonds and national indices  

E-Print Network [OSTI]

It has been shown, that the systemic risk contained in financial markets can be indicated by the change of cross-correlation between different indices and stocks. This change is tracked by using principle component analysis (PCA). We use this technique to investigate the systemic risk contained in European economy by comparing government long term bonds and indices.

Jurczyk, Jan; Morgenstern, Ingo

2015-01-01T23:59:59.000Z

307

Network Perspectives on Communities  

E-Print Network [OSTI]

W W. Networks Fields and Organizations: Micro-Dynamics Scaleentitled Networks, Fields and Organizations: Micro-

Wolfe, Alvin W

2006-01-01T23:59:59.000Z

308

Routing in hybrid networks  

E-Print Network [OSTI]

Hybrid networks are networks that have wired as well as wireless components. Several routing protocols exist for traditional wired networks and mobile ad-hoc networks. However, there are very few routing protocols designed for hybrid networks...

Gupta, Avinash

2001-01-01T23:59:59.000Z

309

Facile Thermal W-W Bond Homolysis in the N-Heterocyclic Carbene...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thermal W-W Bond Homolysis in the N-Heterocyclic Carbene-Containing Tungsten Dimer CpW(CO)2(IMe)2. Facile Thermal W-W Bond Homolysis in the N-Heterocyclic Carbene-Containing...

310

Molecular Dynamics of Neutral Polymer Bonding Agent (NPBA) as Revealed by Solid-State NMR Spectroscopy  

E-Print Network [OSTI]

Neutral polymer bonding agent (NPBA) is one of the most promising polymeric materials, widely used in nitrate ester plasticized polyether (NEPE) propellant as bonding agent. The structure and dynamics of NPBA under different ...

Hu, Wei

311

Role of interatomic bonding in the mechanical anisotropy and interlayer cohesion of CSH crystals  

SciTech Connect (OSTI)

Atomic scale properties of calcium silicate hydrate (CSH), the main binding phase of hardened Portland cement, are not well understood. Over a century of intense research has identified almost 50 different crystalline CSH minerals which are mainly categorized by their Ca/Si ratio. The electronic structure and interatomic bonding in four major CSH crystalline phases with structures close to those found in hardened cement are investigated via ab initio methods. Our result reveals the critical role of hydrogen bonding and importance of specifying precise locations for water molecules. Quantitative analysis of contributions from different bond types to the overall cohesion shows that while the Si-O covalent bonds dominate, the hydrogen bonding and Ca-O bonding are also very significant. Calculated results reveal the correlation between bond topology and interlayer cohesion. The overall bond order density (BOD) is found to be a more critical measure than the Ca/Si ratio in classifying different CSH crystals.

Dharmawardhana, C.C. [Department of Physics and Astronomy, University of MissouriKansas City, Kansas City, MO 64110 (United States)] [Department of Physics and Astronomy, University of MissouriKansas City, Kansas City, MO 64110 (United States); Misra, A. [Department of Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045 (United States)] [Department of Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045 (United States); Aryal, S.; Rulis, P. [Department of Physics and Astronomy, University of MissouriKansas City, Kansas City, MO 64110 (United States)] [Department of Physics and Astronomy, University of MissouriKansas City, Kansas City, MO 64110 (United States); Ching, W.Y., E-mail: ccdxz8@mail.umkc.edu [Department of Physics and Astronomy, University of MissouriKansas City, Kansas City, MO 64110 (United States)

2013-10-15T23:59:59.000Z

312

Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion Batteries: A XANES Study. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion...

313

Bond Strength Degradation for CFRP and Steel reinforcing Bars in Concrete at Elevated Temperature  

E-Print Network [OSTI]

tendon as compared with steel prestressing wire. The results of transient elevated temperature bond pullout and tensile strength tests on CFRP tendons and steel prestressing wire are presented and discussed, and show that bond failure at elevated...

Maluk, Cristian; Bisby, Luke; Terrasi, Giovanni; Green, Mark

2011-03-01T23:59:59.000Z

314

2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking....

315

Cu-Cu direct bonding achieved by surface method at room temperature  

SciTech Connect (OSTI)

The metal bonding is a key technology in the processes for the microelectromechanical systems (MEMS) devices and the semiconductor devices to improve functionality and higher density integration. Strong adhesion between surfaces at the atomic level is crucial; however, it is difficult to achieve close bonding in such a system. Cu films were deposited on Si substrates by vacuum deposition, and then, two Cu films were bonded directly by means of surface activated bonding (SAB) at room temperature. The two Cu films, with the surface roughness Ra about 1.3nm, were bonded by using SAB at room temperature, however, the bonding strength was very weak in this method. In order to improve the bonding strength between the Cu films, samples were annealed at low temperatures, between 323 and 473 K, in air. As the result, the Cu-Cu bonding strength was 10 times higher than that of the original samples without annealing.

Utsumi, Jun [Advanced Technology Research Center, Mitsubishi Heavy Industries, Ltd., 1-8-1 Sachiura, Kanazawa-ku, Yokohama 236-8515 (Japan); Ichiyanagi, Yuko, E-mail: yuko@ynu.ac.jp [Department of Physics, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya, Yokohama 240-8501 (Japan)

2014-02-20T23:59:59.000Z

316

Hydrogen Bonding, H-D Exchange, and Molecular Mobility in Thin...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bonding, H-D Exchange, and Molecular Mobility in Thin Water Films on TiO2(110). Hydrogen Bonding, H-D Exchange, and Molecular Mobility in Thin Water Films on TiO2(110). Abstract:...

317

Performance and Reliability of Bonded Interfaces for High-Temperature Packaging (Presentation)  

SciTech Connect (OSTI)

This presentation reviews the status of the performance and reliability of bonded interfaces for high-temperature packaging.

Devoto, D.

2014-06-01T23:59:59.000Z

318

Characterization of Fuel-Cladding Bond Strength Using Laser Shock  

SciTech Connect (OSTI)

This paper describes new laser-based capabilities for characterization of fuel-cladding bond strength in nuclear fuels, and presents preliminary results obtained from studies on as-fabricated monolithic fuel consisting of uranium-10 wt.% molybdenum alloys clad in 6061 aluminum by hot isostatic pressing. Two complementary experimental methods are employed, laser-shock testing and laser-ultrasonic imaging. Measurements are spatially localized, non-contacting and require minimum specimen preparation, and are therefore ideally suited for applications involving radioactive materials, including irradiated materials. The theoretical principles and experimental approaches employed in characterization of nuclear fuel plates are described. The ability to measure layer thicknesses, elastic properties of the constituents, and the location and nature of laser-shock induced debonds is demonstrated, and preliminary bond strength measurement results are discussed.

James A. Smith; David L. Cottle; Barry H. Rabin

2014-04-01T23:59:59.000Z

319

Wafer bonded virtual substrate and method for forming the same  

DOE Patents [OSTI]

A method of forming a virtual substrate comprised of an optoelectronic device substrate and handle substrate comprises the steps of initiating bonding of the device substrate to the handle substrate, improving or increasing the mechanical strength of the device and handle substrates, and thinning the device substrate to leave a single-crystal film on the virtual substrate such as by exfoliation of a device film from the device substrate. The handle substrate is typically Si or other inexpensive common substrate material, while the optoelectronic device substrate is formed of more expensive and specialized electro-optic material. Using the methodology of the invention a wide variety of thin film electro-optic materials of high quality can be bonded to inexpensive substrates which serve as the mechanical support for an optoelectronic device layer fabricated in the thin film electro-optic material.

Atwater, Jr., Harry A. (So. Pasadena, CA); Zahler, James M. (Pasadena, CA); Morral, Anna Fontcuberta i (Paris, FR)

2007-07-03T23:59:59.000Z

320

Bonding topologies in diamondlike amorphous-carbon films  

SciTech Connect (OSTI)

The carbon ion energy used during filtered cathodic vacuum arc deposition determines the bonding topologies of amorphous-carbon (a-C) films. Regions of relatively low density occur near the substrate/film and film/surface interfaces and their thicknesses increase with increasing deposition energy. The ion subplantation growth results in mass density gradients in the bulk portion of a-C in the growth direction; density decreases with distance from the substrate for films grown using ion energies < 60 eV and increases for films grown using ion energies > 160 eV. Films grown between these energies are the most diamondlike with relatively uniform bulk density and the highest optical transparencies. Bonding topologies evolve with increasing growth energy consistent with the propagation of subplanted carbon ions inducing a partial transformation of 4-fold to 3-fold coordinated carbon atoms.

SIEGAL,MICHAEL P.; PROVENCIO,PAULA P.; TALLANT,DAVID R.; SIMPSON,REGINA L.; KLEINSORGE,B.; MILNE,W.I.

2000-01-27T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Cold bond agglomeration of waste oxides for recycling  

SciTech Connect (OSTI)

Recycling of waste oxides has been an on-going challenge for integrated steel plants. The majority of these waste oxides are collected from the cleaning systems of ironmaking and steelmaking processes, and are usually in the form of fine particulates and slurries. In most cases, these waste materials are contaminated by oils and heavy metals and often require treatment at a considerable expense prior to landfill disposal. This contamination also limits the re-use or recycling potential of these oxides as secondary resources of reliable quality. However, recycling of some selected wastes in blast furnaces or steelmaking vessels is possible, but first requires agglomeration of the fine particulate by such methods as cold bond briquetting. Cold bond briquetting technology provides both mechanical compacting and bonding (with appropriate binders) of the particulates. This method of recycling has the potential to be economically viable and environmentally sustainable. The nature of the present study is cold bond briquetting of iron ore pellet fines with a molasses-cement-H{sub 2}O binder for recycling in a blast furnace. The inclusion of molasses is for its contribution to the green strength of briquettes. During the curing stage, significant gains in strength may be credited to molasses in the presence of cement. The interactions of cement (and its substitutes), water and molasses and their effects on the properties of the agglomerates during and after various curing conditions were investigated. Tensile strengths of briquettes made in the laboratory and subjected to experimental conditions which simulated the top part of a blast furnace shaft were also examined.

D`Alessio, G.; Lu, W.K. [McMaster Univ., Hamilton, Ontario (Canada). Dept. of Materials Science and Engineering

1996-12-31T23:59:59.000Z

322

Oxford Area Community School District (Michigan) Bonds Case Study  

Broader source: Energy.gov [DOE]

Michigans Oxford Area Community School District entered into an energy savings performance contract and issued limited tax general obligation bonds to fund the up-front costs of almost $3 million of energy-related improvements. Case study is excerpted from Financing Energy Upgrades for K-12 School Districts: A Guide to Tapping into Funding for Energy Efficiency and Renewable Energy Improvements. Author: Merrian Borgeson and Mark Zimring

323

Flip chip electrical interconnection by selective electroplating and bonding  

E-Print Network [OSTI]

on a glass substrate made of 500/2000 A° of Cr/Au with 3150 lm in length and 10 lm in width. Two silicon. The interconnection chip has 102 Cr/Au interconnection lines with 3150 lm in length and 10 lm in width. The bonding pads on the ends of the interconnection lines are 40 lm by 40 lm. A 0.8 lm thick layer of aluminum

Lin, Liwei

324

Quantum Confinement in Hydrogen Bond of DNA and RNA  

E-Print Network [OSTI]

The hydrogen bond is a fundamental ingredient to stabilize the DNA and RNA macromolecules. The main contribution of this work is to describe quantitatively this interaction as a consequence of the quantum confinement of the hydrogen. The results for the free and confined system are compared with experimental data. The formalism to compute the energy gap of the vibration motion used to identify the spectrum lines is the Variational Method allied to Supersymmetric Quantum Mechanics.

da Silva dos Santos; Elso Drigo Filho; Regina Maria Ricotta

2015-02-09T23:59:59.000Z

325

Understanding mechanisms for C-H bond activation  

E-Print Network [OSTI]

is unclear as electrophilic and oxidative addition / reductive elimination (OA/RE) pathways have been proposed, and the research into this problem and other related aspects of this chemistry have been extensively considered in several books 18 and reviews... been proposed that lie between the two classic mechanisms that were discussed above; Lin has recently reviewed the current work in this field. 41 Webster and coworkers proposed metal-assisted ?-bond metathesis (MA?BM), 42 Lin and coworkers...

Vastine, Benjamin Alan

2009-05-15T23:59:59.000Z

326

Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix  

DOE Patents [OSTI]

A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al/sub 2/O/sub 3/ yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

Taylor, G.W.; Roybal, H.E.

1983-11-14T23:59:59.000Z

327

Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix  

DOE Patents [OSTI]

A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al.sub.2 O.sub.3 yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

Taylor, Gene W. (Los Alamos, NM); Roybal, Herman E. (Santa Fe, NM)

1985-01-01T23:59:59.000Z

328

Quantum Confinement in Hydrogen Bond of DNA and RNA  

E-Print Network [OSTI]

The hydrogen bond is a fundamental ingredient to stabilize the DNA and RNA macromolecules. The main contribution of this work is to describe quantitatively this interaction as a consequence of the quantum confinement of the hydrogen. The results for the free and confined system are compared with experimental data. The formalism to compute the energy gap of the vibration motion used to identify the spectrum lines is the Variational Method allied to Supersymmetric Quantum Mechanics.

Santos, da Silva dos; Ricotta, Regina Maria

2015-01-01T23:59:59.000Z

329

Opening Pandora's Box - Sovereign Bonds in International Arbitration  

E-Print Network [OSTI]

OPENING PANDORAS BOX: SOVEREIGN BONDS IN INTERNATIONAL ARBITRATION By Michael Waibel* In recent years, sovereign debt crises have received much attention from the perspective of international public policy, but an effective legal solution... . In 1995, Mexico was unable to meet its external debt obligations. Three years later, a severe financial crisis hit East Asia. Russia defaulted in 1998. Argentinas 2001 default on more than U.S.$100 billion in private debt was the largest in history.7...

Waibel, Michael

330

Low Temperature Transient Liquid Phase Bonding of Ti6AI4V  

E-Print Network [OSTI]

bonds by intermetallic formation and subsequent diffusion annealing, but are limited to temperatures above 87sc. Solid state activated diffusion bonding using sputtered copper intcrlayers will form joints temperature [1,2]. 1LP bonding of titanium has been used to produce aerospace components as descnoed by Norris

Eagar, Thomas W.

331

Ionwater hydrogen-bond switching observed with 2D IR vibrational echo chemical  

E-Print Network [OSTI]

Ion­water hydrogen-bond switching observed with 2D IR vibrational echo chemical exchange for review November 8, 2008) The exchange of water hydroxyl hydrogen bonds between anions and water oxygens of anion­ water hydroxyl hydrogen bond switching under thermal equilib- rium conditions as Taw 7 1 ps. Pump

Fayer, Michael D.

332

Extent of Hydrogen-Bond Protection in Folded Proteins: A Constraint on Packing Architectures  

E-Print Network [OSTI]

Extent of Hydrogen-Bond Protection in Folded Proteins: A Constraint on Packing Architectures Ariel structuring and ultimately exclusion of water by hydrophobes surrounding backbone hydrogen bonds turn hydrophobes yields an optimal hydrogen-bond stabilization. This motif is shown to be nearly ubiquitous

Berry, R. Stephen

333

Bonding in Sodium Chloride Nanotubes: A New Analysis via Madelung Constants and Cohesive Energies  

E-Print Network [OSTI]

1 Bonding in Sodium Chloride Nanotubes: A New Analysis via Madelung Constants and Cohesive Energies is introduced which employs a linear relationship between nanotube cohesive energies determined via Density between ionic and cohesive bonding energies indicate that, as the nanotubes become longer, ionic bonding

Hanusa, Christopher

334

AN INVESTIGATION OF THE BONDING AT THE CONCRETE POLYMER COMPOSITE INTERFACE  

E-Print Network [OSTI]

AN INVESTIGATION OF THE BONDING AT THE CONCRETE POLYMER COMPOSITE INTERFACE Wai How Soong, S, USA. ABSTRACT Bonding between the concrete and polymer composite (reinforcement) tendon was studied) and surface roughness of composite reinforcement tendons on the two types of bond strengths were investigated

335

TRANSIENT UQUID PHASE BONDING PROCESSES W. D. MacDonald and T.W. Eagar  

E-Print Network [OSTI]

. In this article, the term TLP \\viii apply to those bonding processes which rely on solid state diffusion to drive) ) ) .. ' TRANSIENT UQUID PHASE BONDING PROCESSES W. D. MacDonald and T.W. Eagar Department Transient liquid phase (TLP) bonding is an ancient process that has received increased attention in recent

Eagar, Thomas W.

336

Silver diffusion bonding and layer transfer of lithium niobate to silicon Kenneth Diest,a  

E-Print Network [OSTI]

Silver diffusion bonding and layer transfer of lithium niobate to silicon Kenneth Diest,a Melissa J July 2008; accepted 8 August 2008; published online 5 September 2008 A diffusion bonding method has, and upon heating, a diffusion bond was formed. Transmission electron microscopy confirms the interface

Atwater, Harry

337

Influence of silicon dangling bonds on germanium thermal diffusion within R. S. Cai,2  

E-Print Network [OSTI]

Influence of silicon dangling bonds on germanium thermal diffusion within SiO2 glass D. Barba,1 R online 17 March 2014) We study the influence of silicon dangling bonds on germanium thermal diffusion of several orders of magnitudes.12,1618 This may suggest that Si dangling bonds can affect the diffusion

338

Particle/substrate interaction in the cold-spray bonding process  

E-Print Network [OSTI]

, atomic inter-diffusion is not expected to play a significant role in particle/substrate bonding. This canC2 148 9 Particle/substrate interaction in the cold-spray bonding process M. GRUJICIC, Clemson in this chapter to the problem of particle/substrate interactions and bonding during cold spray. The actual

Grujicic, Mica

339

Electric charge trapping, residual stresses and properties of ceramics after metal/ceramics bonding  

E-Print Network [OSTI]

and diffusion of metallic species in the ceramics, during the bonding process. Keywords: Joining; ToughnessElectric charge trapping, residual stresses and properties of ceramics after metal/ceramics bonding applications is rapidly increasing. Most of these applications require the use of ceramics bonded with metal

Paris-Sud XI, Universit de

340

Low Temperature Transient Liquid Phase (LTTLP) Bonding for Au/Cu  

E-Print Network [OSTI]

of Technology, Cambridge, MA 02139 TheLow Temperature TransientLiquidPhase Diffusion Bonding (LTTLP) process has) ) M. M. Hou Low Temperature Transient Liquid Phase (LTTLP) Bonding for Au/Cu and Cu been bonded to copper heatsink.s at temperatures less than 160"C, using /n-Sn eutectic solders. After

Eagar, Thomas W.

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Simultaneous Bayesian reconstruction of diffusivity and bond potentials using path integrals  

E-Print Network [OSTI]

Simultaneous Bayesian reconstruction of diffusivity and bond potentials using path integrals Joshua requires fewer data and allows simultaneous inference of both complex bond potentials and diffusivity spectroscopy (DFS) has been used to distort bonds. The resulting responses, in the form of rupture forces, work

Levine, Alex J.

342

The time reversed elastic nonlinearity diagnostic applied to evaluation of diffusion bonds  

E-Print Network [OSTI]

The time reversed elastic nonlinearity diagnostic applied to evaluation of diffusion bonds T. J based nondestructive evaluation techniques has begun. Here, diffusion bonded metal disks containing and impulse responses to perform TR experiments in thin h 5 mm, d 5 cm diffusion bonded disks, in order

343

Molecular surface electrostatic potentials in the analysis of non-hydrogen-bonding noncovalent interactions  

SciTech Connect (OSTI)

Electrostatic potentials computed on molecular surfaces are used to analyze some noncovalent interactions that are not in the category of hydrogen bonding, e.g. halogen bonding. The systems examined include halogenated methanes, substituted benzenes, s-tetrazine and 1,3-bisphenylurea. The data were obtained by ab initio SCF calculations. Electrostatic potentials, Non-hydrogen-bonding noncovalent interactions, Molecular surfaces.

Murray, J.S.; Paulsen, K.; Politzer, P.

1993-12-27T23:59:59.000Z

344

Ligand Binding to the Pregnane X Receptor by Geometric Matching of Hydrogen Bonds  

E-Print Network [OSTI]

space. Hydrogen bonds have been used in FlexX [3] as part of a more complete energy function. Our conformations to PXR based on hydrogen bond geometry and use them as a starting point for ranking ligands aspect of the energy function, the hydrogen bonds, in order to identify the discriminating factor

North Carolina at Chapel Hill, University of

345

Hydrogen bond dynamics in the active site of photoactive yellow protein  

E-Print Network [OSTI]

Hydrogen bond dynamics in the active site of photoactive yellow protein Paul A. Sigala, Mark A for review February 5, 2009) Hydrogen bonds play major roles in biological structure and function. Nonetheless, hydrogen-bonded protons are not typically observed by X-ray crystallography, and most structural

Herschlag, Dan

346

The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis  

E-Print Network [OSTI]

The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis of the Molecular of hydrogen-bondformation between guanine (G) and cytusine (C) in o-dichloro- benzene and in chloroformat 25°C forming hydrogen bonds. Consequently, hydrogen-bond formation in our system is primarily between the bases

Williams, Loren

347

Hydrogen bond dynamics in membrane protein function Ana-Nicoleta Bondar a,  

E-Print Network [OSTI]

Review Hydrogen bond dynamics in membrane protein function Ana-Nicoleta Bondar a, , Stephen H 30 November 2011 Available online 8 December 2011 Keywords: Membrane protein structure Hydrogen bond Membrane protein dynamics Lipid­protein interactions Changes in inter-helical hydrogen bonding

White, Stephen

348

Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation  

E-Print Network [OSTI]

Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

Fayer, Michael D.

349

Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation spectroscopy  

E-Print Network [OSTI]

Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation September 2003 Hydrogen bond population dynamics are extricated with exceptional detail using ultrafast ( 50 of methanol­OD oligomers in CCl4 . Hydrogen bond breaking makes it possible to acquire data for times much

Fayer, Michael D.

350

Native Hydrogen Bonds in a Molten Globule: The Apoflavodoxin Thermal Intermediate  

E-Print Network [OSTI]

Native Hydrogen Bonds in a Molten Globule: The Apoflavodoxin Thermal Intermediate Marõ?a P. Iru?n1 in surface- exposed hydrogen bonds connecting secondary-structure elements in the native protein. All hydrogen bonds analysed are formed in the molten globule intermediate, either with native strength

Sancho, Javier

351

Effect of hydrogen bond cooperativity on the behavior of water  

E-Print Network [OSTI]

Four scenarios have been proposed for the low--temperature phase behavior of liquid water, each predicting different thermodynamics. The physical mechanism which leads to each is debated. Moreover, it is still unclear which of the scenarios best describes water, as there is no definitive experimental test. Here we address both open issues within the framework of a microscopic cell model by performing a study combining mean field calculations and Monte Carlo simulations. We show that a common physical mechanism underlies each of the four scenarios, and that two key physical quantities determine which of the four scenarios describes water: (i) the strength of the directional component of the hydrogen bond and (ii) the strength of the cooperative component of the hydrogen bond. The four scenarios may be mapped in the space of these two quantities. We argue that our conclusions are model-independent. Using estimates from experimental data for H bond properties the model predicts that the low-temperature phase diagram of water exhibits a liquid--liquid critical point at positive pressure.

Kevin Stokely; Marco G. Mazza; H. Eugene Stanley; Giancarlo Franzese

2009-08-27T23:59:59.000Z

352

Structural behavior of silicone bonded glass block panels  

SciTech Connect (OSTI)

Silicone sealant was submitted for mortar in bonding glass blocks. The sealant`s tensile and shear strengths and stiffnesses were determined. Joints bonding two glass blocks were tested for stiffness and strength in tension, bending, out-of-plane shear, and in-plane shear. Bending tests were done on specimens one block wide and four blocks long to evaluate one-way bending behavior. A six block by six block panel, supported on all four sides, was built and tested under simulated wind load. An analytical model with material nonlinearity in the joints was developed for the one-way bending case. It gave good comparisons with the experimental data to load levels approaching failure. A more complex analytical model was developed for the two-way panel. It was only valid for lower load levels, in the range of potential allowable design loads, but compared well with test results. Silicone bonded glass block panels have potential for meeting the wind load requirements necessary for exterior use.

Chang, K.F. [Structural Engineering Associates, Inc., San Antonio, TX (United States); Sandberg, L.B. [Michigan Technological Univ. Houghton, MI (United States)

1996-12-31T23:59:59.000Z

353

Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids with small bond angles: Effects of steric hindrance and ring formation  

SciTech Connect (OSTI)

In this paper we develop a thermodynamic perturbation theory for two site associating fluids which exhibit bond cooperativity (system energy is non-pairwise additive). We include both steric hindrance and ring formation such that the equation of state is bond angle dependent. Here, the bond angle is the angle separating the centers of the two association sites. As a test, new Monte Carlo simulations are performed, and the theory is found to accurately predict the internal energy as well as the distribution of associated clusters as a function of bond angle.

Marshall, Bennett D., E-mail: bennettd1980@gmail.com; Haghmoradi, Amin; Chapman, Walter G. [Department of Chemical and Biomolecular Engineering, Rice University, 6100 S. Main, Houston, Texas 77005 (United States)] [Department of Chemical and Biomolecular Engineering, Rice University, 6100 S. Main, Houston, Texas 77005 (United States)

2014-04-28T23:59:59.000Z

354

The Breathing Orbital Valence Bond Method in Diffusion Monte Carlo: C-H Bond Dissociation ofAcetylene  

SciTech Connect (OSTI)

This study explores the use of breathing orbital valence bond (BOVB) trial wave functions for diffusion Monte Carlo (DMC). The approach is applied to the computation of the carbon-hydrogen (C-H) bond dissociation energy (BDE) of acetylene. DMC with BOVB trial wave functions yields a C-H BDE of 132.4 {+-} 0.9 kcal/mol, which is in excellent accord with the recommended experimental value of 132.8 {+-} 0.7 kcal/mol. These values are to be compared with DMC results obtained with single determinant trial wave functions, using Hartree-Fock orbitals (137.5 {+-} 0.5 kcal/mol) and local spin density (LDA) Kohn-Sham orbitals (135.6 {+-} 0.5 kcal/mol).

Domin, D.; Braida, Benoit; Lester Jr., William A.

2008-05-30T23:59:59.000Z

355

E-Print Network 3.0 - adhesively bonded joints Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics 53 MIXED-MODE FRACTURE ANALYSES OF PLASTICALLY-DEFORMING ADHESIVE JOINTS Summary: mechanics approach to...

356

E-Print Network 3.0 - adhesive bonded joints Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics 53 MIXED-MODE FRACTURE ANALYSES OF PLASTICALLY-DEFORMING ADHESIVE JOINTS Summary: mechanics approach to...

357

Supramolecular self-assembled network formation containing NBr halogen bonds in physisorbed overlayers  

E-Print Network [OSTI]

was Papyex, an exfoliated recompressed graphite foil from Le Carbon. Papyex is a compressed powder of graphite crystallites, which have had a preferred orientation imparted to them from the manufacturing process. This preferred orientation was used... at Diamond Light Source, UK36. The X-ray wavelength used was 1.033787 with a detector zero angle offset of 0.00803 for the co-layer, and 1.054700 with a detector offset of 0.05899 for the pure DBTFB layer as determined by Rietveld refinement of a...

Brewer, Adam Y.; Sacchi, Marco; Parker, Julia E.; Truscott, Chris L.; Jenkins, Steve; Clarke, Stuart M.

2014-08-05T23:59:59.000Z

358

E-Print Network 3.0 - au bonded structures Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of non-helical Au... induce structural transitions between Au(n, n) and Au(2n, n) nanotubes. The corresponding energy barriers... Au(n, n) and Au(2n, n) decreases ......

359

E-Print Network 3.0 - anisotropic bond model Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tech Collection: Physics ; Materials Science 47 electronic reprint Acta Crystallographica Section D Summary: performed ten cycles of conjugated-gradient renements (CGLS) in...

360

E-Print Network 3.0 - accumulative roll-bonding arb Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

InAs quantum dots: band bending vs Pauli blocking Summary: .3000 0.3500 A B C energy eV intensity arb.units. a) 1.18 1.16 1.14 1.12 1.1 1.08 1.06 1.04 1.02 1 -2......

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

K{sub 6} carbon: A metallic carbon allotrope in sp{sup 3} bonding networks  

SciTech Connect (OSTI)

We identify by first-principles calculations a new cubic carbon phase in I4{sub 1}32 (O{sup 8}) symmetry, named K{sub 6} carbon, which has a six atom primitive cell comprising sp{sup 3} hybridized C{sub 3} triangle rings. The structural stability is verified by phonon mode analysis. The calculated elastic constants show that the K{sub 6} carbon is a high ductile material with a density even lower than graphite. Electronic band and density of states calculations reveal that it is a metallic carbon allotrope with a high electronic density of states of ?0.10 states/eV per atom at the Fermi level. These results broaden our understanding of the structural and electronic properties of carbon allotropes.

Niu, Chun-Yao; Wang, Xin-Quan; Wang, Jian-Tao, E-mail: wjt@aphy.iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

2014-02-07T23:59:59.000Z

362

aluminide-bonded carbide ceramics: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

j and the magnetic field H in Bi2Sr2CaCu2O8 x ceramics. We provided in high-Tc superconduct- ing granular ceramics remain an intriguing subject of inten- sive investigations...

363

E-Print Network 3.0 - aliphatic c-h bond Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

during its thermal evolution Summary: ) aliphatic hydrogen concentration (integrated area in the 3000-2700 cm-1 , aliphatic C---H stretching modes... hydrogen concentration...

364

A Preorganized Hydrogen Bond Network and Its Effect on Anion Stability. |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011A First LookMicroscopy for|EMSL Preorganized

365

A Unique Coplanar Multi-center Bonding Network in DoublyAcetylide-bridged  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011A FirstEMSL ShellACalmodulin inU T H OBinuclear

366

Synthesis, structure, and bonding in K12Au21Sn4. A polar intermetallic compound with dense Au20 and open AuSn4 layers  

SciTech Connect (OSTI)

The new phase K{sub 12}Au{sub 21}Sn{sub 4} has been synthesized by direct reaction of the elements at elevated temperatures. Single crystal X-ray diffraction established its orthorhombic structure, space group Pmmn (No. 59), a = 12.162(2); b = 18.058(4); c = 8.657(2) {angstrom}, V = 1901.3(7) {angstrom}{sup 3}, and Z = 2. The structure consists of infinite puckered sheets of vertex-sharing gold tetrahedra (Au{sub 20}) that are tied together by thin layers of alternating four-bonded-Sn and -Au atoms (AuSn{sub 4}). Remarkably, the dense but electron-poorer blocks of Au tetrahedra coexist with more open and saturated Au-Sn layers, which are fragments of a zinc blende type structure that maximize tetrahedral heteroatomic bonding outside of the network of gold tetrahedra. LMTO band structure calculations reveal metallic properties and a pseudogap at 256 valence electrons per formula unit, only three electrons fewer than in the title compound and at a point at which strong Au-Sn bonding is optimized. Additionally, the tight coordination of the Au framework atoms by K plays an important bonding role: each Au tetrahedra has 10 K neighbors and each K atom has 8-12 Au contacts. The appreciably different role of the p element Sn in this structure from that in the triel members in K{sub 3}Au{sub 5}In and Rb{sub 2}Au{sub 3}Tl appears to arise from its higher electron count which leads to better p-bonding (valence electron concentrations = 1.32 versus 1.22).

Li, Bin; Kim, Sung-Jin; Miller, Gordon J.; and Corbett, John D.

2009-10-29T23:59:59.000Z

367

Bond strength of cementitious borehole plugs in welded tuff  

SciTech Connect (OSTI)

Axial loads on plugs or seals in an underground repository due to gas, water pressures and temperature changes induced subsequent to waste and plug emplacement lead to shear stresses at the plug/rock contact. Therefore, the bond between the plug and rock is a critical element for the design and effectiveness of plugs in boreholes, shafts or tunnels. This study includes a systematic investigation of the bond strength of cementitious borehole plugs in welded tuff. Analytical and numerical analysis of borehole plug-rock stress transfer mechanics is performed. The interface strength and deformation are studied as a function of Young`s modulus ratio of plug and rock, plug length and rock cylinder outside-to-inside radius ratio. The tensile stresses in and near an axially loaded plug are analyzed. The frictional interface strength of an axially loaded borehole plug, the effect of axial stress and lateral external stress, and thermal effects are also analyzed. Implications for plug design are discussed. The main conclusion is a strong recommendation to design friction plugs in shafts, drifts, tunnels or boreholes with a minimum length to diameter ratio of four. Such a geometrical design will reduce tensile stresses in the plug and in the host rock to a level which should minimize the risk of long-term deterioration caused by excessive tensile stresses. Push-out tests have been used to determine the bond strength by applying an axial load to cement plugs emplaced in boreholes in welded tuff cylinders. A total of 130 push-out tests have been performed as a function of borehole size, plug length, temperature, and degree of saturation of the host tuff. The use of four different borehole radii enables evaluation of size effects. 119 refs., 42 figs., 20 tabs.

Akgun, H.; Daemen, J.J.K. [Arizona Univ., Tucson, AZ (USA). Dept. of Mining and Geological Engineering

1991-02-01T23:59:59.000Z

368

Fuel cell system with separating structure bonded to electrolyte  

DOE Patents [OSTI]

A fuel cell assembly comprises a separating structure configured for separating a first reactant and a second reactant wherein the separating structure has an opening therein. The fuel cell assembly further comprises a fuel cell comprising a first electrode, a second electrode, and an electrolyte interposed between the first and second electrodes, and a passage configured to introduce the second reactant to the second electrode. The electrolyte is bonded to the separating structure with the first electrode being situated within the opening, and the second electrode being situated within the passage.

Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY); Quek, Shu Ching (Clifton Park, NY); Hasz, Wayne Charles (Pownal, VT); Powers, James Daniel (Santa Monica, CA)

2010-09-28T23:59:59.000Z

369

Overlap population density as an index of bond strength  

E-Print Network [OSTI]

be eliminated. This is done by carrying out an orthogonal transformdtion on b, witn a known matrix U, viz. D = UAU' (10) Next~ M is constructed vis, the equation: M=V'D 'U (11) M transforms b to the unit matrix X: (12) Since: I ~1 MdM = U 'D PhU 'D U... on molecules of the same chemical i'amily as those under study, viz, R2-NN02, D. Thermal Decomposition of Nitramides Although estimates of the energies of bonds other than N-N, B?G. Gowcnlock, P. Jones and J. R. Majer~ Trans. Faraday Soc. ~7 23 (1981) RE...

Gallagher, Michael James

2012-06-07T23:59:59.000Z

370

Time-Resolved Study of Bonding in Liquid Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAboutManusScienceThe43068G.Time-Resolved Study of Bonding in

371

Time-Resolved Study of Bonding in Liquid Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAboutManusScienceThe43068G.Time-Resolved Study of Bonding

372

Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Careerlumens_placard-green.epsEnergy1.pdfMarket37963 Vol.Department of EnergyMarchU.S.Bonds (New

373

Qualified Energy Conservation Bond State-by-State Summary Tables |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartment of EnergyQualified Energy Conservation Bond

374

Qualified Energy Conservation Bond Webinars | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L dDepartment of EnergyQualified Energy Conservation BondWebinars

375

Chemical bond and entanglement of electrons in the hydrogen molecule  

E-Print Network [OSTI]

We theoretically investigate the quantum correlations (in terms of concurrence of indistinguishable electrons) in a prototype molecular system (hydrogen molecule). With the assistance of the standard approximations of the linear combination of atomic orbitals and the con?guration interaction methods we describe the electronic wavefunction of the ground state of the H2 molecule. Moreover, we managed to ?find a rather simple analytic expression for the concurrence (the most used measure of quantum entanglement) of the two electrons when the molecule is in its lowest energy. We have found that concurrence does not really show any relation to the construction of the chemical bond.

Nikos Iliopoulos; Andreas F. Terzis

2014-08-01T23:59:59.000Z

376

Analytically solvable geometric network growth model with arbitrary degree distribution  

E-Print Network [OSTI]

We construct a class of network growth models capable of producing arbitrary degree distributions. The conditions necessary for generating the desired degree distribution can be derived analytically. In this model, a network is generated as a result of local interactions among agents residing on a metric space. Specifically, we study the case of random-walking agents who form bonds when they meet at designated locations we refer to as "rendezvous points." The spatial distribution of the rendezvous points determines key characteristics of the network such as the degree distribution. For any arbitrary (monotonic) degree distribution, we are able to analytically solve for the required rendezvous point distribution. Certain features of the model including high clustering coefficients suggest that it may be a suitable candidate for modeling biological and urban networks.

Dianati, Navid

2015-01-01T23:59:59.000Z

377

Macroscale Properties of Porous Media from a Network Model of Bio lm Processes  

E-Print Network [OSTI]

Macroscale Properties of Porous Media from a Network Model of Bio#12;lm Processes Brian J. Suchomel porosity and permeability changes in a porous medium as a result of bio#12;lm buildup in the pore spaces. A bio#12;lm consists of bacteria and extracellular polymeric substances (EPS) bonded together

378

Nitrogen-tuned bonding mechanism of Li and Ti adatom embedded graphene  

SciTech Connect (OSTI)

The effects of nitrogen defects on the bonding mechanism and resultant binding energy between the metal and graphene layer were investigated using density functional theory (DFT) calculations. For the graphitic N-doped graphene, Li adatom exhibited ionic bonding character, while Ti adatom showed features of covalent bonding similar to that of pristine graphene. However, in the cases of pyridinic and pyrrolic structures, partially covalent bonding characteristic occurred around N atoms in the process of binding with metals, and this particular bond formation enhanced the bond strength of metal on the graphene layer as much as it exceeded the cohesive energy of the metal bulk. Thus, Li and Ti metals are expected to be dispersed with atomic accuracy on the pyridinic and pyrrolic N-doped graphene layers. These results demonstrate that the bonding mechanism of metalgraphene complex can change according to the type of N defect, and this also affects the binding results. - Graphical abstract: Display Omitted - Highlights: Nitrogen defects changed the bonding mechanism between metal and graphene. Bonding character and binding results were investigated using DFT calculations. Covalent bonding character occurred around pyridinic and pyrrolic N-doped graphene. Pyridinic and pyrrolic N atoms are effective for metal dispersion on the graphene.

Lee, Sangho; Chung, Yong-Chae, E-mail: yongchae@hanyang.ac.kr

2013-09-15T23:59:59.000Z

379

A theory for calculating the surface-adsorbate bond dissociation energy from collision-induced desorption threshold measurements  

E-Print Network [OSTI]

to determine surface-adsorbate bond energies.3 Here we present a new model for determin- ing the bondA theory for calculating the surface-adsorbate bond dissociation energy from collision is presented for determining the bond dissociation energy, Do, of a surface-adsorbate complex from collision

Levis, Robert J.

380

JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 21, NO. 2, APRIL 2012 497 Rapid Silicon-to-Steel Bonding by Induction  

E-Print Network [OSTI]

, thermocompressive diffusion bonding has been demonstrated for the bonding of sil- icon nitride to steel [1], [2-to-Steel Bonding by Induction Heating for MEMS Strain Sensors Brian D. Sosnowchik, Robert G. Azevedo, Member, IEEE and manufacturable technique to bond sil- icon to steel for microelectromechanical system (MEMS) sensor applications

Lin, Liwei

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Analysis and testing of adhesively bonded lap joints  

SciTech Connect (OSTI)

Detailed studies of adhesively bonded tubular lap joints subjected to axial loads can be efficiently performed with two-dimensional (2D) finite element analyses. However, three-dimensional (3D) analyses are required to model the bending of tubes and the axial loading of many other shapes such as airfoils. Unfortunately, these 3D analyses require significantly more time and computer resources than 2D analyses. Thus, it is of interest to determine whether some aspects of 3D behavior can be captured with 2D analyses. A series of finite element analyses will show that the shear stress in the adhesive of a tubular or an elliptic lap joint -- due to a bending load -- can be reasonably estimated with a 2D analysis even though the behavior is 3D. After the agreement between 2D and 3D analyses is detailed, preliminary efforts to assess the importance of adhesive geometry at the end of the bond will be discussed. Experimental measurements of the mechanical properties of a structural adhesive used in joint tests will also be presented. Tension, compression, and stress relaxation data for a filled, amine-cured epoxy adhesive will be discussed.

Metzinger, K.E.; Guess, T.R.

1995-10-01T23:59:59.000Z

382

Secure and efficient wireless networks  

E-Print Network [OSTI]

CA Systems and Network Administrator California Integrationgives the campus network administrators complete admissionin engineered networks, enterprise administrators try to

Bellardo, John Michael

2006-01-01T23:59:59.000Z

383

Dynamics of Weak, Bifurcated and Strong Hydrogen Bonds in Lithium Nitrate Trihydrate  

SciTech Connect (OSTI)

The properties of three distinct types of hydrogen bonds, namely a weak, a bifurcated and a strong one, all present in/the LiNO3 (HDO)(D2O)2 hydrate lattice unit cell are studied using steady-state and time-resolved spectroscopy. The lifetimes of the OH stretching vibrations for the three individual bonds are 2.2 ps (weak), 1.7 ps (bifurcated), and 1.2 ps (strong), respectively. For the first time the properties of bifurcated H bonds can thus be unambiguously directly compared to those of weak and strong H bonds in the same system. The values of their OH stretching vibration lifetime, anharmonicity, red shift and bond strength lie between those for the strong and weak H bonds. The experimentally observed inhomogeneous broadening of their spectral signature is attributed to the coupling with a low frequency intermolecular wagging vibration/

Werhahn, Jasper C.; Pandelov, S.; Xantheas, Sotiris S.; Iglev, H.

2011-07-07T23:59:59.000Z

384

A Bond Graphs approach to Physical Modelling of Musical Instruments  

E-Print Network [OSTI]

is the equivalent of the current i flowing in the electric circuit. These equivalencies follow from the fact for representing physical systems, such as an electrical circuit or a mechanical engine. They provide a precise of vibrating media using a network of interconnected mechanical units, called mass and spring. On a computer

McGregor, Andrew

385

Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues  

SciTech Connect (OSTI)

Enzymes and their mimics use hydrogen bonds to catalyze chemical transformations. Small molecule transition state analogs of oxyanion holes are characterized by gas phase IR and photoelectron spectroscopy and their binding constants in acetonitrile. As a result, a new class of hydrogen bond catalysts is proposed (OH donors that can contribute three hydrogen bonds to a single functional group) and demonstrated in a Friedel-Crafts reaction.

Beletskiy, Evgeny V.; Schmidt, Jacob C.; Wang, Xue B.; Kass, Steven R.

2012-11-14T23:59:59.000Z

386

A CH O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices  

E-Print Network [OSTI]

A C­H· · ·O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices of Science Bangalore 560012, India The serendipitous observation of a C­H· · ·O hydrogen bond mediated­N hydrogen bond involving the side- chain of residue T 2 4 and the N­H group of residue T þ 3. In as many

Babu, M. Madan

387

Liquid Metal Bond for Improved Heat Transfer in LWR Fuel Rods  

SciTech Connect (OSTI)

A liquid metal (LM) consisting of 1/3 weight fraction each of Pb, Sn, and Bi has been proposed as the bonding substance in the pellet-cladding gap in place of He. The LM bond eliminates the large AT over the pre-closure gap which is characteristic of helium-bonded fuel elements. Because the LM does not wet either UO2 or Zircaloy, simply loading fuel pellets into a cladding tube containing LM at atmospheric pressure leaves unfilled regions (voids) in the bond. The HEATING 7.3 heat transfer code indicates that these void spaces lead to local fuel hot spots.

Donald Olander

2005-08-24T23:59:59.000Z

388

Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers  

DOE Patents [OSTI]

The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

2001-01-01T23:59:59.000Z

389

A Batch Wafer Scale LIGA Assembly and Packaging Technique vai Diffusion Bonding  

SciTech Connect (OSTI)

A technique using diffusion bonding (or solid-state welding) has been used to achieve batch fabrication of two- level nickel LIGA structures. Interlayer alignment accuracy of less than 1 micron is achieved using press-fit gauge pins. A mini-scale torsion tester was built to measure the diffusion bond strength of LIGA formed specimens that has shown successful bonding at temperatures of 450"C at 7 ksi pressure with bond strength greater than 100 Mpa. Extensions to this basic process to allow for additional layers and thereby more complex assemblies as well as commensurate packaging are discussed.

Christenson, T.R.; Schmale, D.T.

1999-01-27T23:59:59.000Z

390

Bond strength of steel hollow sections using carbon fibre reinforced polymer composites.  

E-Print Network [OSTI]

??This research was a step forward in developing bond strength of CFRP strengthened steel hollow sections under tension loads. The studies have revealed the ultimate (more)

Shahanara, Kaniz

2013-01-01T23:59:59.000Z

391

A study of the bond characteristics of concrete reinforcing bars coated with epoxy compounds  

E-Print Network [OSTI]

Selected Refe~ ces. Appendix - A . 12 . 20 . 22 . 24 . 25 LIST OF TABLES Table Page Bond Stress at Slip of 0. 01 in. at Loaded End of the Bar . . . . 13 Bond Stress at Slip of 0. 001 in. at Free End of the Bar. . 14 A-1 Bond Stress and Steel.... SUMMARY A number of processes by which the steel-concrete bond can be improved are described. The procedures involve coating steel with a versamid epoxy compound and either casting the concrete around the treated reinforcement before the epoxy hardens...

Desai, Indravadan S

1964-01-01T23:59:59.000Z

392

Making it Easier to Complete Clean Energy Projects with Qualified Energy Conservation Bonds (QECBs)  

Broader source: Energy.gov [DOE]

This presentation, given through the DOE's Technical Assitance Program (TAP), provides information on How to to Complete Clean Energy Projects with Qualified Energy Conservation Bonds (QECBs)

393

Innovative use of adhesive interface characteristics to nondestructively quantify the strength of bonded joints.  

SciTech Connect (OSTI)

Advances in structural adhesives have permitted engineers to contemplate the use of bonded joints in areas that have long been dominated by mechanical fasteners and welds. Although strength, modulus, and toughness have been improved in modern adhesives, the typical concerns with using these polymers still exist. These include concerns over long-term durability and an inability to quantify bond strength (i.e., identify weak bonds) in adhesive joints. Bond deterioration in aging structures and bond strength in original construction are now critical issues that require more than simple flaw detection. Whether the structure involves metallic or composite materials, it is necessary to extend inspections beyond the detection of disbond flaws to include an assessment of the strength of the bond. Use of advanced nondestructive inspection (NDI) methods to measure the mechanical properties of a bonded joint and associated correlations with post-inspection failure tests have provided some clues regarding the key parameters involved in assessing bond strength. Recent advances in ultrasonic- and thermographic-based inspection methods have shown promise for measuring such properties. Specialized noise reduction and signal enhancement schemes have allowed thermographic interrogations to image the subtle differences between bond lines of various strengths. Similarly, specialized ultrasonic (UT) inspection techniques, including laser UT, guided waves, UT spectroscopy, and resonance methods, can be coupled with unique signal analysis algorithms to accurately characterize the properties of weak interfacial bonds. The generation of sufficient energy input levels to derive bond strength variations, the production of sufficient technique sensitivity to measure such minor response variations, and the difficulty in manufacturing repeatable weak bond specimens are all issues that exacerbate these investigations. The key to evaluating the bond strength lies in the ability to exploit the critical characteristics of weak bonds such as nonlinear responses, poor transmission of shear waves, and changes in response to stiffness-based interrogations. This paper will present several ongoing efforts that have identified promising methods for quantifying bond strength and discuss some completed studies that provide a foundation for further evolution in weak bond assessments.

Roach, Dennis Patrick; Duvall, Randy L.; Rackow, Kirk A.

2010-05-01T23:59:59.000Z

394

Network Connections  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat Cornell Batteries &NSTCurrent Issues &Network » Network

395

Method of making bonded or sintered permanent magnets  

DOE Patents [OSTI]

An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density.

McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

1993-08-31T23:59:59.000Z

396

Tourism networks and computer networks  

E-Print Network [OSTI]

The body of knowledge accumulated in recent years on the structure and the dynamics of complex networks has offered useful insights on the behaviour of many natural and artificial complex systems. The analysis of some of these, namely those formed by companies and institutions, however, has proved problematical mainly for the difficulties in collecting a reasonable amount of data. This contribution argues that the World Wide Web can provide an efficient and effective way to gather significant samples of networked socio-economic systems to be used for network analyses and simulations. The case discussed refers to a tourism destination, the fundamental subsystem of an industry which can be considered one of the most important in today's World economy.

Baggio, Rodolfo

2008-01-01T23:59:59.000Z

397

Intramolecular rearrangement of trimethylsilyl pyrazoles  

E-Print Network [OSTI]

will be concentration dependent and the coalescence temperature of each compound will change with changing concentrations of the sample in inert solvents. On the other hand, if this thermal re- arrangement is concentration independent, it will be intramolecular... with hexamethyldi- si lazane under anhydrous conditions. Four compounds wi th different ring substi tuents were thus synthesi zed. Nu- clear magnetic resonance (nmr) spectra of these compounds indicated the non-equivalence of the 3, 5-substi tuents at room...

Hrung, Chang-Po

1970-01-01T23:59:59.000Z

398

DOI: 10.1002/adma.200602099 Competitive Hydrogen Bonding in p-Stacked Oligomers**  

E-Print Network [OSTI]

DOI: 10.1002/adma.200602099 Competitive Hydrogen Bonding in p-Stacked Oligomers** By Alain, such as light-emitting diodes, field- effect transistors, and photovoltaic cells.[1] Although such mate- rials by multiple amide functional groups with the ability to form hydrogen bonds.[5] Thus, one can sig- nificantly

Rochefort, Alain

399

Formation and Dissociation of Intra-Intermolecular Hydrogen-Bonded Solute-Solvent Complexes: Chemical  

E-Print Network [OSTI]

architectures in supramolecular chemistry, molecular recognition, and self-assembly. The strength of hydrogen, such as the properties of water4 and biological recognition.3 Hydrogen bonding has been studied extensively in many contexts since the birth of the concept in the early 1900s.2,3,5 Hydrogen bonds can be separated into two

Fayer, Michael D.

400

Testing Geometrical Discrimination within an Enzyme Active Site: Constrained Hydrogen Bonding in the Ketosteroid  

E-Print Network [OSTI]

Testing Geometrical Discrimination within an Enzyme Active Site: Constrained Hydrogen Bonding, Stanford UniVersity, Stanford, California 94305, and Departments of Biochemistry and Chemistry-chain reorientation and prevent hydrogen bond shortening by 0.1 ? or less. Further, this constraint has substantial

Herschlag, Dan

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

The Valuation of Convertible Bonds With Credit Risk P. A. Forsyth K. R. Vetzal  

E-Print Network [OSTI]

The Valuation of Convertible Bonds With Credit Risk E. Ayache P. A. Forsyth K. R. Vetzal April 22 upon the history of its stock price. This paper explores the valuation of convertible bonds subject implicit method to decou- ple the system of linear complementarity problems at each timestep. Numerical

Forsyth, Peter A.

402

Bonded carbon or ceramic fiber composite filter vent for radioactive waste  

DOE Patents [OSTI]

Carbon bonded carbon fiber composites as well as ceramic or carbon bonded ceramic fiber composites are very useful as filters which can separate particulate matter from gas streams entraining the same. These filters have particular application to the filtering of radioactive particles, e.g., they can act as vents for containers of radioactive waste material.

Brassell, Gilbert W. (13237 W. 8th Ave., Golden, CO 80401); Brugger, Ronald P. (Lafayette, CO)

1985-02-19T23:59:59.000Z

403

Electronic states of metallic and semiconducting carbon nanotubes with bond and site disorder  

E-Print Network [OSTI]

energy in both of metallic and semiconducting carbon nanotubes. The bond disorder gives rise to a huge nanotube. We have also found that suppression of electronic conductance around the Fermi energy due and semiconducting carbon nanotubes. A huge density of states appears at the Fermi energy in the bond disorder case

Harigaya, Kikuo

404

Instability of two-dimensional graphene: Breaking sp2 bonds with soft x rays  

E-Print Network [OSTI]

Instability of two-dimensional graphene: Breaking sp2 bonds with soft x rays S. Y. Zhou,1,2 . the stability of various kinds of graphene samples under soft x-ray irradiation. Our results show that in single-layer exfoliated graphene a closer analog to two-dimensional material , the in-plane carbon- carbon bonds

Zettl, Alex

405

Mathematical Modeling and Experimental Investigations of Isothermal Solidification during Transient Liquid Phase Bonding of Nickel  

E-Print Network [OSTI]

Liquid Phase Bonding of Nickel Superalloys M. A. Arafin1, a , M. Medraj1, b , D. P. Turner2, c and P Liquid Phase Bonding, Nickel Superalloys. Abstract. Mathematical model, based on Fick's second law of diffusion, was used to predict the time required to complete isothermal solidification and to determine

Medraj, Mamoun

406

FINITE VOLUME APPROXIMATION OF THE EFFECTIVE DIFFUSION MATRIX: THE CASE OF INDEPENDENT BOND  

E-Print Network [OSTI]

FINITE VOLUME APPROXIMATION OF THE EFFECTIVE DIFFUSION MATRIX: THE CASE OF INDEPENDENT BOND with independent jump rates across nearest neighbour bonds of the lattice. We show that the infinite volume effective diffusion matrix can be almost surely recovered as the limit of finite volume periodized effective

407

MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897 905 Dynamics and hydrogen bonding in liquid ethanol  

E-Print Network [OSTI]

MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897± 905 Dynamics and hydrogen bonding in liquid ethanol L of liquid ethanol at three temperatures have been carried out. The hydrogen bonding states of ethanol measurements of the frequency-dependent dielectric permittivity of liquid ethanol. 1. Introduction A detailed

Saiz, Leonor

408

Bonding of thermoplastic polymer microfluidics Chia-Wen Tsao Don L. DeVoe  

E-Print Network [OSTI]

REVIEW Bonding of thermoplastic polymer microfluidics Chia-Wen Tsao ? Don L. DeVoe Received: 20 Abstract Thermoplastics are highly attractive substrate materials for microfluidic systems, with important microchannels and other microfluidic elements, and thus bonding remains a critical step in any thermo- plastic

Rubloff, Gary W.

409

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus  

E-Print Network [OSTI]

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus and Frauke Gra, China ABSTRACT Mechanical force applied along a disulfide bond alters its rate of reduction. We here within proteins by point mutations. INTRODUCTION Similar to thermal or light energy, mechanical force can

Gräter, Frauke

410

Structure and function of circadian clock proteins and deuterium isotope effects in nucleic acid hydrogen bonds  

E-Print Network [OSTI]

-terminal domain. Hydrogen bonds are of paramount importance in nucleic acid structure and function. Here we show that changes in the width and anharmonicity of vibrational potential energy wells of hydrogen bonded groups can be measured in nucleic acids and can...

Vakonakis, Ioannis

2005-08-29T23:59:59.000Z

411

Adhesion, stability, and bonding at metal/metal-carbide interfaces: Al/WC Donald J. Siegel  

E-Print Network [OSTI]

of adhesion between metals and transition metal carbides/nitrides based on Density Functional Theory(DFT)[14Adhesion, stability, and bonding at metal/metal-carbide interfaces: Al/WC Donald J. Siegel the nature of metal/carbide bonding. Based on the surface and interfacial free energies, we find that both

Adams, James B

412

The Brownian Bridge Asymptotics in the Subcritical Phase of Bernoulli Bond Percolation Model.  

E-Print Network [OSTI]

The Brownian Bridge Asymptotics in the Subcritical Phase of Bernoulli Bond Percolation Model-dimensional subcritical Bernoulli bond percolation model conditioned on connecting points (0, ..., 0) and na if scaled percolation cluster in subcritical phase, conditioned on reaching a faraway point on square lattice. We

Kovchegov, Yevgeniy

413

Investigation of the suitability of silicate bonding for facet termination in active  

E-Print Network [OSTI]

Investigation of the suitability of silicate bonding for facet termination in active fiber devices Memorial Drive, Rochester, NY 14623, USA supriyo@stanford.edu Abstract: We demonstrate that silicate / OPTICS EXPRESS 13003 #12;11. K. Mackenzie, I. Brown, P. Ranchod, and R. Meinhold, "Silicate bonding

Byer, Robert L.

414

Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N-AlOOH  

E-Print Network [OSTI]

Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N significant amounts of hydrogen in stishovite under lower-mantle conditions. The enthalpy of solution pressure and temperature. We predict asymmetric hydrogen bonding in the stishovite^N-AlOOH solid solution

Stixrude, Lars

415

Network Embedded Systems Sensor Networks  

E-Print Network [OSTI]

Battery Energy Reserve Manager = Bank Each task requests an account with conditions W fraction Tracking 9 #12;Virtual Battery: An Energy Reserve Abstraction for Embedded Sensor Networks Qing Cao of real battery allocated N number of energy installments L expected lifetime of the task C

Amir, Yair

416

On the mechanism of photoinduced refractive index changes in phosphosilicate glass  

SciTech Connect (OSTI)

The photoinduced growth of the refractive index of phosphosilicate glass during Bragg grating inscription and the thermal decay of the grating have a number of unusual features. The observed index variations are interpreted in terms of a new model for photoinduced glass network rearrangement. The model assumes the formation of photoinduced voids (nanopores) in the glass network near point defects. The nanopores may migrate through the network via bond switching when the network is in a 'soft' state. The photoinduced variations in network density lead to index variations. (fibres)

Larionov, Yu V [A M Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Sokolov, V O; Plotnichenko, V G [Fiber Optics Research Center, Russian Academy of Sciences, Moscow (Russian Federation)

2010-05-26T23:59:59.000Z

417

Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy  

SciTech Connect (OSTI)

We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

2010-05-01T23:59:59.000Z

418

Diffusion bonding of a superplastic Inconel 718SPF superalloy by electroless nickel plating  

SciTech Connect (OSTI)

Although intimate contact can be obtained for diffusion bonding of a superplastic Inconel 718SPF superalloy under a low pressure of 7 MPa, the precipitates formed at the interface retarded achievement of a sound joint. The shear strength was only 41.5 MPa for an overlap length of 12 T (T = 1.3 mm, sheet thickness). The diffusion bondability of t his Inconel 718SPF superalloy was enhanced by electroless nickel plating. In this situation, the bonding shear strength increased to 70.4 MPa for the same overlap length of 12 T under the same bonding condition, regardless of the roughness of the surface to be bonded. Upon decreasing the overlap length from 12 to 6T, the bonding strength remained constant.

Yeh, M.S.; Chang, C.B.; Chuang, T.H.

2000-02-01T23:59:59.000Z

419

Lateral diffusion of receptor-ligand bonds in membrane adhesion zones: Effect of thermal membrane roughness  

E-Print Network [OSTI]

The adhesion of cells is mediated by membrane receptors that bind to complementary ligands in apposing cell membranes. It is generally assumed that the lateral diffusion of mobile receptor-ligand bonds in membrane-membrane adhesion zones is slower than the diffusion of unbound receptors and ligands. We find that this slowing down is not only caused by the larger size of the bound receptor-ligand complexes, but also by thermal fluctuations of the membrane shape. We model two adhering membranes as elastic sheets pinned together by receptor-ligand bonds and study the diffusion of the bonds using Monte Carlo simulations. In our model, the fluctuations reduce the bond diffusion constant in planar membranes by a factor close to 2 in the biologically relevant regime of small bond concentrations.

H. Krobath; G. J. Schuetz; R. Lipowsky; T. R. Weikl

2007-03-19T23:59:59.000Z

420

Method for bonding thin film thermocouples to ceramics  

DOE Patents [OSTI]

A method is provided for adhering a thin film metal thermocouple to a ceramic substrate used in an environment up to 700 degrees Centigrade, such as at a cylinder of an internal combustion engine. The method includes the steps of: depositing a thin layer of a reactive metal on a clean ceramic substrate; and depositing thin layers of platinum and a platinum-10% rhodium alloy forming the respective legs of the thermocouple on the reactive metal layer. The reactive metal layer serves as a bond coat between the thin noble metal thermocouple layers and the ceramic substrate. The thin layers of noble metal are in the range of 1-4 micrometers thick. Preferably, the ceramic substrate is selected from the group consisting of alumina and partially stabilized zirconia. Preferably, the thin layer of reactive metal is in the range of 0.015-0.030 micrometers (15-30 nanometers) thick. The preferred reactive metal is chromium. Other reactive metals may be titanium or zirconium. The thin layer of reactive metal may be deposited by sputtering in ultra high purity argon in a vacuum of approximately 2 milliTorr (0.3 Pascals).

Kreider, Kenneth G. (Potomac, MD)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

MATERIALS INTEGRATION FOR HIGH- PERFORMANCE PHOTOVOLTAICS BY WAFER BONDING  

E-Print Network [OSTI]

No thesis is an individual endeavor, and this thesis would not have been possible without the assistance of my collaborators and advisor and would have been unendurable without the support of my coworkers, friends, and family. I apologize in advance to anyone whom I might omit in this brief acknowledgement, but it is late and I am running out of time! In the summer of 2000, Harry Atwater agreed to allow me to transfer to his group from the chemical engineering department. I was discouraged and doubtful about my future at Caltech and in graduate school in general. Since giving me that chance he has been a great advisor with no shortage of encouragement or ideas. I am never sure if this is by design, but Harry has managed to inspire me to work hard and has given me countless ideas to pursue while always allowing me to feel that I have nearly complete freedom to pursue experiments that are interesting to me. While in Harrys group I had the good fortune to work closely with two post-doctoral scholars, Chang-Geun Ahn and Anna Fontcuberta i Morral. Chang-Geun was extremely helpful in getting the Ge/Si bonding project going and in optical and electrical characterization experiments. Anna was tough to work with because her energy level is so darned high, but she has also been very supportive and her high energy approach to research has pushed me to work

James Michael Zahler; James Michael Zahler

2005-01-01T23:59:59.000Z

422

Method of waste stabilization with dewatered chemically bonded phosphate ceramics  

DOE Patents [OSTI]

A method of stabilizing a waste in a chemically bonded phosphate ceramic (CBPC). The method consists of preparing a slurry including the waste, water, an oxide binder, and a phosphate binder. The slurry is then allowed to cure to a solid, hydrated CBPC matrix. Next, bound water within the solid, hydrated CBPC matrix is removed. Typically, the bound water is removed by applying heat to the cured CBPC matrix. Preferably, the quantity of heat applied to the cured CBPC matrix is sufficient to drive off water bound within the hydrated CBPC matrix, but not to volatalize other non-water components of the matrix, such as metals and radioactive components. Typically, a temperature range of between 100.degree. C.-200.degree. C. will be sufficient. In another embodiment of the invention wherein the waste and water have been mixed prior to the preparation of the slurry, a select amount of water may be evaporated from the waste and water mixture prior to preparation of the slurry. Another aspect of the invention is a direct anyhydrous CBPC fabrication method wherein water is removed from the slurry by heating and mixing the slurry while allowing the slurry to cure. Additional aspects of the invention are ceramic matrix waste forms prepared by the methods disclosed above.

Wagh, Arun; Maloney, Martin D.

2010-06-29T23:59:59.000Z

423

Dinuclear Metalloradicals Featuring Unsupported Metal-Metal Bonds  

SciTech Connect (OSTI)

Unlike the very labile, unobservable radical cations [{l_brace}CpM(CO){sub 3}{r_brace}{sub 2}]{sup {sm_bullet}+} (M = W, Mo), derivatives [{l_brace}CpM(CO){sub 2}(PMe{sub 3}){r_brace}{sub 2}]{sup {sm_bullet}+} are stable enough to be isolated and characterized. Experimental and theoretical studies show that the shortened M-M bonds are of order 1 1/2, and that they are not supported by bridging ligands. The unpaired electron is fully delocalized, with a spin density of ca. 45% on each metal atom. We thank the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences for support of this work. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. The EPR and computational studies were performed using EMSL, a national scientific user facility sponsored by the DOE's Office of Biological and Environmental Research and located at PNNL. We thank Dr. Charles Windisch for access to his UV-Vis-NIR spectrometer.

van der Eide, Edwin F.; Yang, Ping; Walter, Eric D.; Liu, Tianbiao L.; Bullock, R. Morris

2012-08-13T23:59:59.000Z

424

Polyorganosilazane preceramic binder development for reaction bonded silicon nitride composites  

SciTech Connect (OSTI)

This study has examined the use of two commercially available polyorganosilazanes for application as preceramic binders in a composite composed of silicon carbide fibers in a reaction bonded silicon nitride (RBSN) matrix. Ceramic monolithic and composite samples were produced. Density of monolithic and whisker reinforced RBSN samples containing the polysilazane binder was increased. Mercury intrusion porosimetry revealed a significant decrease in the pore sizes of samples containing a polyorganosilazane binder. Electron micrographs of samples containing the preceramic binder looked similar to control samples containing no precursor. Overall, incorporation of the polysilazane into monolithic and whisker reinforced samples resulted in significantly increased density and decreased porosity. Nitriding of the RBSN was slightly retarded by addition of the polysilazane binder. Samples with the preceramic binders contained increased contents of {alpha} versus {beta}-silicon nitride which may be due to interaction of hydrogen evolved from polysilazane pyrolysis with the nitriding process. Initial efforts to produce continuous fiber reinforced composites via this method have not realized the same improvements in density and porosity which have been observed for monolithic and whisker reinforced samples. Further, the addition of perceramic binder resulted in a more brittle fracture morphology as compared to similar composites made without the binder.

Mohr, D.L.; Starr, T.L. [Georgia Tech Research Inst., Atlanta, GA (United States)

1992-11-01T23:59:59.000Z

425

Polyorganosilazane preceramic binder development for reaction bonded silicon nitride composites  

SciTech Connect (OSTI)

This study has examined the use of two commercially available polyorganosilazanes for application as preceramic binders in a composite composed of silicon carbide fibers in a reaction bonded silicon nitride (RBSN) matrix. Ceramic monolithic and composite samples were produced. Density of monolithic and whisker reinforced RBSN samples containing the polysilazane binder was increased. Mercury intrusion porosimetry revealed a significant decrease in the pore sizes of samples containing a polyorganosilazane binder. Electron micrographs of samples containing the preceramic binder looked similar to control samples containing no precursor. Overall, incorporation of the polysilazane into monolithic and whisker reinforced samples resulted in significantly increased density and decreased porosity. Nitriding of the RBSN was slightly retarded by addition of the polysilazane binder. Samples with the preceramic binders contained increased contents of [alpha] versus [beta]-silicon nitride which may be due to interaction of hydrogen evolved from polysilazane pyrolysis with the nitriding process. Initial efforts to produce continuous fiber reinforced composites via this method have not realized the same improvements in density and porosity which have been observed for monolithic and whisker reinforced samples. Further, the addition of perceramic binder resulted in a more brittle fracture morphology as compared to similar composites made without the binder.

Mohr, D.L.; Starr, T.L. (Georgia Tech Research Inst., Atlanta, GA (United States))

1992-11-01T23:59:59.000Z

426

Neural Networks:Neural Networks: Modeling ApplicationsModeling Applications  

E-Print Network [OSTI]

and/or integral equations representing mathematical model of a given physical process. The coefficients of these equations must be exactly known as they are used to program/adjust the coefficient inherent in analog differentiation the [differential] equation is rearranged so that it can be solved

Petriu, Emil M.

427

An On-Target Performic Acid Oxidation Method Suitable for Disulfide Bond Elucidation Using Capillary Electrophoresis - Mass Spectrometry  

E-Print Network [OSTI]

methods before or after MS detection have been developed to aid in disulfide bond assignment, such as tandem MS followed by database searching or modification of the disulfide bond via chemical reduction or oxidation. Despite these technological...

Williams, Brad J.

2011-08-08T23:59:59.000Z

428

Correlation among electronegativity, cation polarizability, optical basicity and single bond strength of simple oxides  

SciTech Connect (OSTI)

A suitable relationship between free-cation polarizability and electronegativity of elements in different valence states and with the most common coordination numbers has been searched on the basis of the similarity in physical nature of both quantities. In general, the cation polarizability increases with decreasing element electronegativity. A systematic periodic change in the polarizability against the electronegativity has been observed in the isoelectronic series. It has been found that generally the optical basicity increases and the single bond strength of simple oxides decreases with decreasing the electronegativity. The observed trends have been discussed on the basis of electron donation ability of the oxide ions and type of chemical bonding in simple oxides. - Graphical abstract: This figure shows the single bond strength of simple oxides as a function of element electronegativity. A remarkable correlation exists between these independently obtained quantities. High values of electronegativity correspond to high values of single bond strength and vice versa. It is obvious that the observed trend in this figure is closely related to the type of chemical bonding in corresponding oxide. Highlights: Black-Right-Pointing-Pointer A suitable relationship between free-cation polarizability and electronegativity of elements was searched. Black-Right-Pointing-Pointer The cation polarizability increases with decreasing element electronegativity. Black-Right-Pointing-Pointer The single bond strength of simple oxides decreases with decreasing the electronegativity. Black-Right-Pointing-Pointer The observed trends were discussed on the basis of type of chemical bonding in simple oxides.

Dimitrov, Vesselin, E-mail: vesselin@uctm.edu [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria)] [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki, E-mail: komatsu@mst.nagaokaut.ac.jp [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)] [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

2012-12-15T23:59:59.000Z

429

C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices  

E-Print Network [OSTI]

C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices Anirban Ghosh and Manju-pair as well as cross-strand C-H..O hydrogen bonds in the minor groove. The C2-H2..O2 hydrogen bonds within leads to a narrow minor groove in these regions. # 1999 Academic Press Keywords: C-H..O hydrogen bonds

Bansal, Manju

430

Dynamic NetworksDynamic Networks ApplicationsApplications  

E-Print Network [OSTI]

Satellite Constellation Network #12;Satellite and Undersea Cable Networks #12;Energy NetworksEnergy Networks Electric Power Network #12;Duke Energy Gas Pipeline Network #12;Components of Some Common Physical Networks Roads, Airline Routes, Railroad Track Automobiles, Trains, and Planes, Manufacturing and logistics

Nagurney, Anna

431

Bond Graph Modeling of Current Diffusion in Magnetic Cores Herv Morel, Bruno Allard, Sabrine M'Rad, Cyril Buttay  

E-Print Network [OSTI]

Bond Graph Modeling of Current Diffusion in Magnetic Cores Herv Morel, Bruno Allard, Sabrine M, F-69621 Villeurbanne Cedex, France KEYBOARD: Bond Graphs, Variational approximation, Diffusive with the diffusion representation. Both approaches yield a same bond graph representation. 2. MODELING CURRENT

Paris-Sud XI, Universit de

432

Plasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon wafers  

E-Print Network [OSTI]

microscopy, profilometer and wafer bow measurements. Plasma-activated direct bonding of DOI wafers to thermalPlasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon (CMP) on the diamond surface makes a poor bonding to silicon wafers with thermal oxide. Our results

Akin, Tayfun

433

Hydrogen Bonds Involved in Binding the Qi-site Semiquinone in the bc1 Complex, Identified through Deuterium Exchange  

E-Print Network [OSTI]

Hydrogen Bonds Involved in Binding the Qi-site Semiquinone in the bc1 Complex, Identified through them. The strength of interactions indicates that the protons are involved in hydrogen bonds with SQ. The hyperfine cou- plings differ from values typical for in-plane hydrogen bonds previously observed in model

Crofts, Antony R.

434

Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran and cyclohexane rings in organic crystals  

E-Print Network [OSTI]

Paper Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran of the hydrogen bonding counts in crystalline pyranose monosaccharides, we noticed that equatorial hydroxyls formed more hydrogen bonds, on average, than axial groups. A survey of the Cambridge Structural Database

de Gispert, Adrià

435

Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen  

E-Print Network [OSTI]

Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen Bond, Stabilize the Transition State in Serine Protease Catalysis Cynthia N. Fuhrmann, Matthew D that destabilizes the His57-Ser195 hydrogen bond, preventing the back-reaction. In both structures the His57-Asp102

Agard, David

436

Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational Echo Spectroscopy  

E-Print Network [OSTI]

Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational@stanford.edu Abstract: Weak hydrogen-bonded solute/solvent complexes are studied with ultrafast two the dissociation and formation rates of the hydrogen-bonded complexes. The dissociation rates of the weak hydrogen

Fayer, Michael D.

437

Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Alexei Khalizov, and Renyi Zhang*  

E-Print Network [OSTI]

Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Precursors, water, and ammonia. A central feature of the complexes is the presence of two hydrogen bonds. Organic acid-sulfuric acid complexes show one strong and one medium-strength hydrogen bond whereas

438

Hydrogen-bond equilibria and life times in a supercooled monohydroxy alcohol  

E-Print Network [OSTI]

Dielectric loss spectra covering 13 decades in frequency were collected for 2-ethyl-1-hexanol, a monohydroxy alcohol that exhibits a prominent Debye-like relaxation, typical for several classes of hydrogen-bonded liquids. The thermal variation of the dielectric absorption amplitude agrees well with that of the hydrogen-bond equilibrium population, experimentally mapped out using near infrared (NIR) and nuclear magnetic resonance (NMR) measurements. Despite this agreement, temperature-jump NIR spectroscopy reveals that the hydrogen-bond switching rate does not define the frequency position of the prominent absorption peak. This contrasts with widespread notions and models based thereon, but is consistent with a recent approach.

C. Gainaru; S. Kastner; F. Mayr; P. Lunkenheimer; S. Schildmann; H. J. Weber; W. Hiller; A. Loidl; R. Bhmer

2011-06-29T23:59:59.000Z

439

Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces  

SciTech Connect (OSTI)

12. Other advances in QNDE and related topics: Preferred Session Laser-ultrasonics Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces 41st Annual Review of Progress in Quantitative Nondestructive Evaluation Conference QNDE Conference July 20-25, 2014 Boise Centre 850 West Front Street Boise, Idaho 83702 James A. Smith, Jeffrey M. Lacy, Barry H. Rabin, Idaho National Laboratory, Idaho Falls, ID ABSTRACT: The US National Nuclear Security Agency has a Global Threat Reduction Initiative (GTRI) which is assigned with reducing the worldwide use of high-enriched uranium (HEU). A salient component of that initiative is the conversion of research reactors from HEU to low enriched uranium (LEU) fuels. An innovative fuel is being developed to replace HEU. The new LEU fuel is based on a monolithic fuel made from a U-Mo alloy foil encapsulated in Al-6061 cladding. In order to complete the fuel qualification process, the laser shock technique is being developed to characterize the clad-clad and fuel-clad interface strengths in fresh and irradiated fuel plates. The Laser Shockwave Technique (LST) is being investigated to characterize interface strength in fuel plates. LST is a non-contact method that uses lasers for the generation and detection of large amplitude acoustic waves to characterize interfaces in nuclear fuel plates. However the deposition of laser energy into the containment layer on specimens surface is intractably complex. The shock wave energy is inferred from the velocity on the backside and the depth of the impression left on the surface from the high pressure plasma pulse created by the shock laser. To help quantify the stresses and strengths at the interface, a finite element model is being developed and validated by comparing numerical and experimental results for back face velocities and front face depressions with experimental results. This paper will report on initial efforts to develop a finite element model for laser shock.

James A. Smith; Jeffrey M. Lacy; Barry H. Rabin

2014-07-01T23:59:59.000Z

440

E-Print Network 3.0 - area network performance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

networks - network performance modeling - wireless networks - wireless sensor networks - ad hoc ... Source: Iowa State University, Office of Biorenewables Programs Collection:...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Network Maps  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohn Cyber SecurityAlamos NationalNeil Network Traffic

442

Network Policies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohn Cyber SecurityAlamos NationalNeil NetworkAcceptable

443

The Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest RegionatSearchScheduled System BurstLong Term ScheduleProject HomeTheNetwork

444

attractor neural network: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Convolutional Neural Networks 5 Mixture of density networks Englebienne, Gwenn 138 Fuzzy neural network pattern recognition algorithm for classification of the events in...

445

analog neural network: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Convolutional Neural Networks 5 Mixture of density networks Englebienne, Gwenn 118 Fuzzy neural network pattern recognition algorithm for classification of the events in...

446

attractor neural networks: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Convolutional Neural Networks 5 Mixture of density networks Englebienne, Gwenn 138 Fuzzy neural network pattern recognition algorithm for classification of the events in...

447

algebraic network coding: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and robust networking. For networks which are restricted to using linear network codes, we find necessary and sufficient conditions for the feasibility of any given set of...

448

FES Science Network Requirements  

E-Print Network [OSTI]

FES Science Network Requirements Report of the Fusion Energy Sciences Network Requirements Workshop Conducted March 13 and 14, 2008 #12;FES Science Network Requirements Workshop Fusion Energy Sciences Program Office, DOE Office of Science Energy Sciences Network Gaithersburg, MD ­ March 13 and 14, 2008 ESnet

Geddes, Cameron Guy Robinson

449

Professional Networking Michelle Burdick  

E-Print Network [OSTI]

Development Green Sustainability Professionals #12;How To Use LinkedIn Groups Group Discussions: ­ Members can Environmental Careers Network GIS Professional & Networking Green Jobs & Career Network Sustainable EnergyLinkedIn Professional Networking Workshop Michelle Burdick 24 January 2014 #12;· Building a Strong

Awtar, Shorya

450

Networks, Information & Social Capital  

E-Print Network [OSTI]

This paper investigates how information flows enable social networks to constitute social capital. By analyzing

Aral, Sinan

2008-01-26T23:59:59.000Z

451

Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Energy Efficiency Loan Program: Case Study on Saint Louis County, MO  

E-Print Network [OSTI]

2011 Using Qualified Energy Conservation Bonds (QECBs) toCounty, MO Qualified Energy Conservation Bonds (QECBs) arerange of qualified energy conservation projects. QECBs offer

Zimring, Mark

2012-01-01T23:59:59.000Z

452

Survivability Considerations in Wireless Networks  

E-Print Network [OSTI]

pre-configured by the network administrator, otherwise thedetermined by the network administrator according to if thebut also allow a network administrator to determine the

Ning, Jianxia

2012-01-01T23:59:59.000Z

453

Long-term performance of epoxy-bonded rebar-couplers  

E-Print Network [OSTI]

Water transport in epoxy resins." Prog. Polymer Science.Hygrothermal effects of epoxy resin. Part I: the nature ofStandard Specification for Epoxy-Resin-Base Bonding Systems

Brungraber, Griffin Rupp

2009-01-01T23:59:59.000Z

454

Stress and Fracture Analysis of a Class of Bonded Joints in Wind Turbine Blades  

E-Print Network [OSTI]

A simplified model is proposed to investigate the stress fields and the strain energy release rate (SERR) associated with cracks in bonded joints in wind turbine blades. The proposed two-dimensional model consists of nonparallel upper and lower...

Chen, Chang

2013-05-08T23:59:59.000Z

455

Hybrid Two-Dimensional Electronic Systems and Other Applications of sp-2 Bonded Light Elements  

E-Print Network [OSTI]

A.4 A.5 vii List of Tables DOE Hydrogen Storage Targets forsp-2 Bonded Materials 5 Hydrogen Storage 5.1 Motivation andJeffrey R. Long. Hydrogen storage in a microporous metal-

Kessler, Brian Maxwell

2010-01-01T23:59:59.000Z

456

EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel  

Broader source: Energy.gov [DOE]

This EIS evaluates thepotential environmental impacts of the proposed electrometallurgical treatment of DOE-owned sodium bonded spent nuclear fuel in the Fuel Conditioning Facility at Argonne...

457

Commercialization of low temperature copper thermocompression bonding for 3D integrated circuits  

E-Print Network [OSTI]

Wafer bonding is a key process and enabling technology for realization of three-dimensional integrated circuits (3DIC) with reduced interconnect delay and correspondingly increased circuit speed and decreased power ...

Nagarajan, Raghavan

2008-01-01T23:59:59.000Z

458

Understanding visual preferences for landscapes: an examination of the relationship between aesthetics and emotional bonding  

E-Print Network [OSTI]

The relationship between humans and the quality of the environment have been examined primarily through two conceptual constructs: landscape aesthetics and place attachment or emotional place bonding. The former focuses on the physical environment...

Cheng, Chia-Kuen

2009-05-15T23:59:59.000Z

459

Distal hydrogen-bonding effects and cofacial bimetallic salen architectures for oxygen activation chemistry  

E-Print Network [OSTI]

Two distinct structural scaffolds elaborated from Schiff-base macrocycles were designed to study the proton-coupled electron transfer chemistry of 0-0 bond forming and activation chemistry. The "Hangman" architecture is ...

Yang, Jenny Yue-fon

2007-01-01T23:59:59.000Z

460

Non-Destructive Inspection of Adhesive Bonds in Metal-Metal Joints...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. lm15moore.pdf More Documents & Publications NonDestructive Inspection of Adhesive Bonds...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Company Name: Tighe & Bond, Inc. Web Site: www.tighebond.com  

E-Print Network [OSTI]

Company Name: Tighe & Bond, Inc. Web Site: www.tighebond.com Industry: Engineering Brief Company Business. Majors they typically recruit: Civil Engineering, Earth Sciences Do they offer internships: Yes in civil, geotechnical and environmental engineering, environmental science, hydrogeology and geographic

New Hampshire, University of

462

Steel bonded dense silicon nitride compositions and method for their fabrication  

DOE Patents [OSTI]

A two-stage bonding technique for bonding high density silicon nitride and other ceramic materials to stainless steel and other hard metals, and multilayered ceramic-metal composites prepared by the technique are disclosed. The technique involves initially slurry coating a surface of the ceramic material at about 1500/sup 0/C in a vacuum with a refractory material and the stainless steel is then pressure bonded to the metallic coated surface by brazing it with nickel-copper-silver or nickel-copper-manganese alloys at a temperature in the range of about 850/sup 0/ to 950/sup 0/C in a vacuum. The two-stage bonding technique minimizes the temperature-expansion mismatch between the dissimilar materials.

Landingham, R.L.; Shell, T.E.

1985-05-20T23:59:59.000Z

463

Partial-Transient-Liquid-Phase Bonding of Advanced Ceramics Using Surface-Modified Interlayers  

E-Print Network [OSTI]

of Thermal Residual Stresses in Joining Ceramics with ThinIn ceramic/metal/ceramic bonds that undergo thermal cycling,cooling or thermal cycling of the component. Ceramics are

Reynolds, Thomas Bither

2012-01-01T23:59:59.000Z

464

Molecular-bond hardening and dynamics of molecular stabilization and trapping in intense laser pulses  

E-Print Network [OSTI]

stabilization and population trapping of high-lying vibrational states and chemical bond hardening are predicted for both continuous-wave (cw) lasers and short laser pulses. While the intensity dependences of the laser-induced stabilization are essentially...

Yao, Guanhua; Chu, Shih-I

1993-07-01T23:59:59.000Z

465

Catalytic C-N and C-F bond formation by organometallic group 11 complexes  

E-Print Network [OSTI]

This thesis presents a study of the reaction between an (NHC)gold(I) fluoride complex (NHC = N-heterocyclic carbene) and alkynes (Chapter 1). Gold(I) and fluoride add trans across the triple bond of 3-hexyne and ...

Akana, Jennifer Anne

2007-01-01T23:59:59.000Z

466

Mechanistic studies on metal-catalyzed carbon-nitrogen bond forming reactions  

E-Print Network [OSTI]

Mechanistic studies on copper and palladium-catalyzed C-N bond forming reactions are described. To understand the mechanistic details of these processes, several principles of physical organic chemistry have been employed. ...

Strieter, Eric R

2005-01-01T23:59:59.000Z

467

Eutectic bonding of a Ti sputter coated, carbon aerogel wafer to a Ni foil  

SciTech Connect (OSTI)

The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer. A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.

Jankowski, A.F.; Hayes, J.P.; Kanna, R.L.

1994-06-01T23:59:59.000Z

468

Geosynthetics International, 2003, 10, No. 2 Air channel testing of thermally bonded PVC  

E-Print Network [OSTI]

Geosynthetics International, 2003, 10, No. 2 Air channel testing of thermally bonded PVC (PVC) possesses excellent thermal welding characteristics, such as a wide thermal seaming range and recommend that destructive testing of PVC geomembranes be reduced and possibly discontinued

469

Strained Silicon on Silicon by Wafer Bonding and Layer Transfer from Relaxed SiGe Buffer  

E-Print Network [OSTI]

We report the creation of strained silicon on silicon (SSOS) substrate technology. The method uses a relaxed SiGe buffer as a template for inducing tensile strain in a Si layer, which is then bonded to another Si handle ...

Isaacson, David M.

470

Universality aspects of the d = 3 random-bond Blume-Capel model  

E-Print Network [OSTI]

The effects of bond randomness on the universality aspects of the simple cubic lattice ferromagnetic Blume-Capel model are discussed. The system is studied numerically in both its first- and second-order phase transition ...

Malakis, A.

471

Storage device sizing for a hybrid railway traction system by means of bicausal bond graphs  

E-Print Network [OSTI]

(a supercapacitor) included in this system is then discussed. Keywords: bond graph, bicausality In the paper, the example of a supercapacitor process consists of choosing the system structure dimensioning

Paris-Sud XI, Université de

472

Environmental durability of FRP bond to concrete subjected to freeze-thaw action  

E-Print Network [OSTI]

An experimental study was performed to determine the environmental durability of the adhesive bond between fiber-reinforced plastic (FRP) and concrete. The study specifically focused on freeze-thaw cycling exposure of such ...

Dohnlek, Pavel

2006-01-01T23:59:59.000Z

473

Useful for cleavage of organic C-S bonds Bacillus sphaericus microorganism  

DOE Patents [OSTI]

A mutant Bacillus sphaericus strain ATCC No. 53969 which has the property of sulfur removal and sulfur metabolism by selective cleavage of C-S bonds in organic carbonaceous materials.

Kilbane, J.J. II.

1993-03-30T23:59:59.000Z

474

Experimental and Theoretical Examination of C-CN Bond Activation of Benzonitrile Using Zerovalent Nickel  

E-Print Network [OSTI]

are important in industrial petroleum refining.1 The transition metal catalyzed activation of C-C bonds has been used in organic synthesis, for which the beneficial features of atom economy and chemoselectivity have

Jones, William D.

475

A C-H...O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif  

E-Print Network [OSTI]

A C-H...O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C-terminus of Helices between the C atom of residue Ala 4 (T-4) and the backbone oxygen atom of DLeu 9. The C-H...O hydrogen Nitrogenase MoFe protein (PDB: 1qh8). The N-H...O hydrogen bond parameters are: O...N = 3.19?; O...H = 2.48 ?

Babu, M. Madan

476

XAS Characterization of a Nitridoiron(IV) Complex With a Very Short Fe-N Bond  

SciTech Connect (OSTI)

X-ray absorption spectroscopy has been used to characterize the novel nitridoiron(IV) units in two [PhBP{sup R}{sub 3}]Fe(N) complexes (R = iPr and CyCH{sub 2}) and obtain direct spectroscopic evidence for a very short Fe-N distance. The distance of 1.51--1.55 {angstrom} reflects the presence of an Fe{triple_bond}N triple bond in accord with the observed Fe{triple_bond}N vibration observed for one of these species (v{sub FeN}=1034 cm{sup -1}). This highly covalent bonding interaction results in the appearance of an unusually intense pre-edge peak, whose estimated area of 100(20) units is much larger than those of the related tetrahedral complexes with Fe{sup I}-N{sub 2}-Fe{sup I}, Fe{sup II}-NPh{sub 2}, and Fe{sup III}{triple_bond}NAd motifs, and those of recently described six-coordinate Fe{sup V}{triple_bond}N and Fe{sup VI}{triple_bond}N complexes. The observation that the Fe{sup IV}-N distances of two [PhBP{sup R}{sub 3}]Fe(N) complexes are shorter than the Fe{sup IV}-O bond lengths of oxoiron(IV) complexes may be rationalized on the basis of the greater ? basicity of the nitrido ligand than the oxo ligand and a lower metal coordination number for the Fe(N) complex.

Rohde, J.-U.; Betley, T.A.; Jackson, T.A.; Saouma, C.T.; Peters, J.C.; Que, L.; Jr.

2009-06-04T23:59:59.000Z

477

Theoretical Studies of the sp2 C-H Bond Activation  

E-Print Network [OSTI]

-picoline C-H activation chemistry is proceeded by -bond metathesis for both the thorium and uranium (C5Me5Theoretical Studies of the sp2 versus sp3 C-H Bond Activation Chemistry of 2-Picoline by (C5Me5)2An activation chemistry of (C5Me5)2Th(CH3)2 and (C5Me5)2U(CH3)2 with 2-picoline (2- methylpyridine) is examined

Burke, Kieron

478

Electronic structure of dimetal bonded systems: ditungsten, dimolybdenum and diruthenium systems  

E-Print Network [OSTI]

with a 0.05 contour surface. The z axis is taken to be perpendicular to the plane defined by the tungsten atoms and ? -CO ligands.......24 5 Orbital correlation diagram for 1 illustrating the changes in energy of the four highest occupied (dashed... Page 1 Crystallographic Data for Tungsten Formamidinate Compounds................. 9 2 Bond Parameters (? or deg) for 1................................................................. 11 3 Bond Parameters (? or deg) for 2...

Villagran Martinez, Dino

2007-04-25T23:59:59.000Z

479

Wafer Bonding and Layer Transfer Processes for High Efficiency Solar Cells  

SciTech Connect (OSTI)

A wafer-bonded four-junction cell design consisting of InGaAs, InGaAsP, GaAs, and Ga0.5In0.5P subcells that could reach one-sun AM0 efficiencies of 35.4% is described. The design relies on wafer-bonding and layer transfer for integration of non-lattice-matched subcells. Wafer bonding and layer transfer processes have shown promise in the fabrication of InP/Si epitaxial templates for growth of the bottom InGaAs and InGaAsP subcells on a Si support substrate. Subsequent wafer bonding and layer transfer of a thin Ge layer onto the lower subcell stack can serve as an epitaxial template for GaAs and Ga0.5In0.5P subcells. Additionally, wafer bonded Ge/Si substrates offer the possibility to improve the mechanical performance of existing triple-junction solar cell designs, while simultaneously reducing their cost. Present results indicate that optically active III/V compound semiconductors can be grown on both Ge/Si and InP/Si heterostructures. Current-voltage electrical characterization of the interfaces of these structures indicates that both InP/Si and Ge/Si interfaces have specific resistances lower than 0.1 W?cm2 for heavily doped wafer bonded interfaces, enabling back surface power extraction from the finished cell structure.

Zahler, J. M.; Fontcuberta i Morral, A.; Ahn, C. G.; Atwater, H. A.; Wanlass, M. W.; Chu, C.; Iles, P. A.

2003-05-01T23:59:59.000Z

480

Method of bonding functional surface materials to substrates and applications in microtechnology and antifouling  

DOE Patents [OSTI]

A simple and effective method to bond a thin coating of poly(N-isopropylacylamide) (NIPAAm) on a glass surface by UV photopolymerization, and the use of such a coated surface in nano and micro technology applications. A silane coupling agent with a dithiocarbamate group is provided as a photosensitizer, preferably, (N,N'-diethylamine)dithiocarbamoylpropyl-(trimethoxy)silane (DATMS). The thiocarbamate group of the sensitizer is then bonded to the glass surface by coupling the silane agent with the hydroxyl groups on the glass surface. The modified surface is then exposed to a solution of NIPAAm and a crosslinking agent which may be any organic molecule having an acrylamide group and at least two double bonds in its structure, such as N,N'-methylenebisacrylamide, and a polar solvent which may be any polar liquid which will dissolve the monomer and the crosslinking agent such as acetone, water, ethanol, or combinations thereof. By exposing the glass surface to a UV light, free radicals are generated in the thiocarbamate group which then bonds to the crosslinking agent and the NIPAAm. Upon bonding, the crosslinking agent and the NIPAAm polymerize to form a thin coating of PNIPAAm bonded to the glass. Depending upon the particular configuration of the glass, the properties of the PNIPAAm allow applications in micro and nano technology.

Feng, Xiangdong (West Richland, WA); Liu, Jun (West Richland, WA); Liang, Liang (Richland, WA)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Method of bonding functional surface materials to substrates and applications in microtechnology and anti-fouling  

DOE Patents [OSTI]

A simple and effective method to bond a thin coating of poly(N-isopropylacylamide) (NIPAAm) on a glass surface by UV photopolymerization, and the use of such a coated surface in nano and micro technology applications. A silane coupling agent with a dithiocarbamate group is provided as a photosensitizer preferably, (N,N'-diethylamine) dithiocarbamoylpropyl-(trimethoxy) silane (DATMS). The thiocarbamate group of the sensitizer is then bonded to the glass surface by coupling the silane agent with the hydroxyl groups on the glass surface. The modified surface is then exposed to a solution of NIPAAm and a crosslinking agent which may be any organic molecule having an acrylamide group and at least two double bonds in its structure, such as N, N'-methylenebisacrylamide, and a polar solvent which may be any polar liquid which will dissolve the monomer and the crosslinking agent such as acetone, water, ethanol, or combinations thereof. By exposing the glass surface to a UV light, free radicals are generated in the thiocarbamate group which then bonds to the crosslinking agent and the NIPAAm. Upon bonding, the crosslinking agent and the NIPAAm polymerize to form a thin coating of PNIPAAm bonded to the glass. Depending upon the particular configuration of the glass, the properties of the PNIPAAm allow applications in micro and nano technology.

Feng, Xiangdong (West Richland, WA); Liu, Jun (West Richland, WA); Liang, Liang (Richland, WA)

2001-01-01T23:59:59.000Z

482

Solving stochasic PERT networks exactly using hybrid Bayesian networks  

E-Print Network [OSTI]

In this paper, we describe how a stochastic PERT network can be formulated as a Bayesian network. We approximate such PERT Bayesian network by mixtures of Gaussians hybrid Bayesian networks. Since there exists algorithms for solving mixtures...

Cinicioglu, Esma N.; Shenoy, Prakash P.

2006-09-16T23:59:59.000Z

483

Networking Call for Residential Network Members Peer Exchange...  

Office of Environmental Management (EM)

Networking Call for Residential Network Members Peer Exchange Call Networking Call for Residential Network Members Peer Exchange Call March 12, 2015 12:30PM to 2:00PM EDT...

484

Building a Network Simulation Model of the Teragrid Network  

E-Print Network [OSTI]

Building a Network Simulation Model of the Teragrid Network Thomas Hacker Preston Smith* Computer in designing and using an accurate network simulation model of the Teragrid network, and the performance

Jiang, Wen

485

analysis network sevan: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Francesco Keywords: Knowledge Base, Social Network Analysis, Variety, Coherence, Industry lifecycles; exploration network analysis (SNA) within an evolutionary framework, to...

486

Interconnection networks  

DOE Patents [OSTI]

A network of interconnected processors is formed from a vertex symmetric graph selected from graphs GAMMA/sub d/(k) with degree d, diameter k, and (d + 1)exclamation/ (d /minus/ k + 1)exclamation processors for each d greater than or equal to k and GAMMA/sub d/(k, /minus/1) with degree d /minus/ 1, diameter k + 1, and (d + 1)exclamation/(d /minus/ k + 1)exclamation processors for each d greater than or equal to k greater than or equal to 4. Each processor has an address formed by one of the permutations from a predetermined sequence of letters chosen a selected number of letters at a time, and an extended address formed by appending to the address the remaining ones of the predetermined sequence of letters. A plurality of transmission channels is provided from each of the processors, where each processor has one less channel than the selected number of letters forming the sequence. Where a network GAMMA/sub d/(k, /minus/1) is provided, no processor has a channel connected to form an edge in a direction delta/sub 1/. Each of the channels has an identification number selected from the sequence of letters and connected from a first processor having a first extended address to a second processor having a second address formed from a second extended address defined by moving to the front of the first extended address the letter found in the position within the first extended address defined by the channel identification number. The second address is then formed by selecting the first elements of the second extended address corresponding to the selected number used to form the address permutations. 9 figs.

Faber, V.; Moore, J.W.

1988-06-20T23:59:59.000Z

487

Reliability Gain of Network Coding in Lossy Wireless Networks  

E-Print Network [OSTI]

Reliability Gain of Network Coding in Lossy Wireless Networks Majid Ghaderi Department of Computer that network coding improves network reliability by reducing the number of packet retransmissions in lossy networks. However, the extent of the reliability benefit of network coding is not known. This paper

Massachusetts at Amherst, University of

488

Rhodium mediated bond activation: from synthesis to catalysis  

SciTech Connect (OSTI)

Recently, our lab has developed monoanionic tridentate ligand, To{sup R}, showing the corresponding coordination chemistry and catalyst reactivity of magnesium, zirconium, zinc and iridium complexes. This thesis details synthetic chemistry, structural study and catalytic reactivity of the To{sup R}-supported rhodium compounds. Tl[To{sup R}] has been proved to be a superior ligand transfer agent for synthesizing rhodium complexes. The salt metathesis route of Tl[To{sup M}] with [Rh({mu}-Cl)(CO)]{sub 2} and [Rh({mu}- Cl)(COE)]{sub 2} gives To{sup M}Rh(CO){sub 2} (2.2) and To{sup M}RhH({eta}{sup 3}-C{sub 8}H{sub 13}) (3.1) respectively while Tl[To{sup P}] with [Rh({mu}-Cl)(CO)]{sub 2} affords To{sup P}Rh(CO){sub 2} (2.3). 2.2 reacts with both strong and weak electrophiles, resulting in the oxazoline N-attacked and the metal center-attacked compounds correspondingly. Using one of the metal center-attacked electrophiles, 2.3 was demonstrated to give high diastereoselectivity. Parallel to COE allylic C-H activation complex 3.1, the propene and allylbenzene allylic C-H activation products have also been synthesized. The subsequent functionalization attempts have been examined by treating with Brnsted acids, Lewis acids, electrophiles, nucleophiles, 1,3-dipolar reagents and reagents containing multiple bonds able to be inserted. Various related complexes have been obtained under these conditions, in which one of the azide insertion compounds reductively eliminates to give an allylic functionalization product stoichiometrically. 3.1 reacts with various primary alcohols to give the decarbonylation dihydride complex To{sup M}Rh(H){sub 2}CO (4.1). 4.1 shows catalytic reactivity for primary alcohol decarbonylation under a photolytic condition. Meanwhile, 2.2 has been found to be more reactive than 4.1 for catalytic alcohol decarbonylation under the same condition. Various complexes and primary alcohols have been investigated as well. The proposed mechanism is based on the stochiometric reactions of the possible metal and organic intermediates. Primary amines, hypothesized to undergo a similar reaction pathway, have been verified to give dehydrogenative coupling product, imines. In the end, the well-developed neutral tridentate Tpm coordinates to the rhodium bis(ethylene) dimer in the presence of TlPF{sub 6} to give the cationic complex, [TpmRh(C{sub 2}H{sub 4}){sub 2}][PF{sub 6}] (5.1). 5.1 serves as the first example of explicit determination of the solid state hapticity, evidenced by X-ray structure, among all the cationic Tpm{sup R}M(C{sub 2}H{sub 4}){sub 2}{sup +} (Tpm{sup R} = Tpm, Tpm*, M = Rh, Ir) derivatives. The substitution chemistry of this compound has been studied by treating with soft and hard donors. The trimethylphosphine-sbustituted complex activates molecular hydrogen to give the dihydride compound.

Ho, Hung-An

2012-03-06T23:59:59.000Z

489

XAS Characterization of a Nitridoiron(IV) Complex with a Very Short Fe-N Bond  

SciTech Connect (OSTI)

X-ray absorption spectroscopy has been used to characterize the novel nitridoiron(IV) units in two [PhBP{sup R}{sub 3}]Fe(N) complexes (R = iPr and CyCH{sub 2}) and obtain direct spectroscopic evidence for a very short Fe-N distance. The distance of 1.51-1.55 {angstrom} reflects the presence of an Fe{triple_bond}N triple bond in accord with the observed Fe{triple_bond}N vibration observed for one of these species ({nu}{sub FeN} = 1034 cm{sup -1}). This highly covalent bonding interaction results in the appearance of an unusually intense pre-edge peak, whose estimated area of 100(20) units is much larger than those of the related tetrahedral complexes with Fe{sup I}-N{sub 2}-Fe{sup I}, Fe{sup II}-NPh{sub 2}, and Fe{sup III}NAd motifs, and those of recently described six-coordinate Fe{sup V}{triple_bond}N and Fe{sup VI}{triple_bond}N complexes. The observation that the Fe{sup IV}-N distances of two [PhBP{sup R}{sub 3}]Fe(N) complexes are shorter than the Fe{sup IV}-O bond lengths of oxoiron(IV) complexes may be rationalized on the basis of the greater {pi} basicity of the nitrido ligand than the oxo ligand and a lower metal coordination number for the Fe(N) complex.

Rohde,J.; Betley, T.; Jackson, T.; Saouma, C.; Peters, J.; Que, Jr., L.

2007-01-01T23:59:59.000Z

490

Microstructural Examination to Aid in Understanding Friction Bonding Fabrication Technique for Monolithic Nuclear Fuel  

SciTech Connect (OSTI)

Monolithic nuclear fuel is currently being developed for use in research reactors, and friction bonding (FB) is a technique being developed to help in this fuels fabrication. Since both FB and monolithic fuel are new concepts, research is needed to understand the impact of varying FB fabrication parameters on fuel plate characteristics. This thesis research provides insight into the FB process and its application to the monolithic fuel design by recognizing and understanding the microstructural effects of varying fabrication parameters (a) FB tool load, and (b) FB tool face alloy. These two fabrication parameters help drive material temperature during fabrication, and thus the material properties, bond strength, and possible formation of interface reaction layers. This study analyzed temperatures and tool loads measured during those FB processes and examined microstructural characteristics of materials and bonds in samples taken from the resulting fuel plates. This study shows that higher tool load increases aluminum plasticization and forging during FB, and that the tool face alloy helps determine the tools heat extraction efficacy. The study concludes that successful aluminum bonds can be attained in fuel plates using a wide range of FB tool loads. The range of tool loads yielding successful uranium-aluminum bonding was not established, but it was demonstrated that such bonding can be attained with FB tool load of 48,900 N (11,000 lbf) when using a FB tool faced with a tungsten alloy. This tool successfully performed FB, and with better results than tools faced with other materials. Results of this study correlate well with results reported for similar aluminum bonding techniques. This studys results also provide support and validation for other nuclear fuel development studies and conclusions. Recommendations are offered for further research.

Karen L. Shropshire

2008-04-01T23:59:59.000Z

491

Explosion bonding of dissimilar materials for fabricating APS front end components: Analysis of metallurgical and mechanical properties and UHV applications  

SciTech Connect (OSTI)

The front end beamline section contains photon shutters and fixed masks. These components are made of OFHC copper and GlidCOP AL-15. Stainless steels (304 or 316) are also used for connecting photon shutters and fixed masks to other components that operate in the ultrahigh vacuum system. All these dissimilar materials need to be joined together. However, bonding these dissimilar materials is very difficult because of their different mechanical and thermal properties and incompatible metallurgical properties. Explosion bonding is a bonding method in which the controlled energy of a detonating explosive is used to create a metallurgical bond between two or more similar or dissimilar materials. No intermediate filler metal, for example, a brazing compound or soldering alloy, is needed to promote bonding, and no external heat need be applied. A study of the metallurgical and mechanical properties and YGV applications of GlidCop AL-15, OFHC copper, and 304 stainless steel explosion-bonded joints has been done. This report contains five parts: an ultrasonic examination of explosion-bonded joints and a standard setup; mechanical-property and thermal-cycle tests of GlidCop AL-15/304 stainless steel explosion-bonded joints; leak tests of a GlidCop AL-15/304 stainless steel explosion-bonded interfaces for UHV application; metallurgical examination of explosion-bonded interfaces and failure analysis, and discussion and conclusion.

Li, Yuheng; Shu, Deming; Kuzay, T.M.

1994-06-15T23:59:59.000Z

492

Evaluation of Cu as an interlayer in Be/F82H diffusion bonds for ITER TBM R.M. Hunt a,  

E-Print Network [OSTI]

expansion in the region. Prior diffusion bonding research has shown that titanium is a good bonding aidEvaluation of Cu as an interlayer in Be/F82H diffusion bonds for ITER TBM R.M. Hunt a, , S.H. Goods has been investigated as a potential interlayer material for diffusion bonds between beryllium

Abdou, Mohamed

493

Non-Gaussian energy landscape of a simple model for strong network-forming liquids: accurate evaluation of the configurational entropy  

E-Print Network [OSTI]

We present a numerical study of the statistical properties of the potential energy landscape of a simple model for strong network-forming liquids. The model is a system of spherical particles interacting through a square well potential, with an additional constraint that limits the maximum number of bonds, $N_{\\rm max}$, per particle. Extensive simulations have been carried out as a function of temperature, packing fraction, and $N_{\\rm max}$. The dynamics of this model are characterized by Arrhenius temperature dependence of the transport coefficients and by nearly exponential relaxation of dynamic correlators, i.e. features defining strong glass-forming liquids. This model has two important features: (i) landscape basins can be associated with bonding patterns; (ii) the configurational volume of the basin can be evaluated in a formally exact way, and numerically with arbitrary precision. These features allow us to evaluate the number of different topologies the bonding pattern can adopt. We find that the number of fully bonded configurations, i.e. configurations in which all particles are bonded to $N_{\\rm max}$ neighbors, is extensive, suggesting that the configurational entropy of the low temperature fluid is finite. We also evaluate the energy dependence of the configurational entropy close to the fully bonded state, and show that it follows a logarithmic functional form, differently from the quadratic dependence characterizing fragile liquids. We suggest that the presence of a discrete energy scale, provided by the particle bonds, and the intrinsic degeneracy of fully bonded disordered networks differentiates strong from fragile behavior.

A. J. Moreno; I. Saika-Voivod; E. Zaccarelli; E. La Nave; S. V. Buldyrev; P. Tartaglia; F. Sciortino

2006-05-29T23:59:59.000Z

494

Network coded wireless architecture  

E-Print Network [OSTI]

Wireless mesh networks promise cheap Internet access, easy deployment, and extended range. In their current form, however, these networks suffer from both limited throughput and low reliability; hence they cannot meet the ...

Katti, Sachin Rajsekhar

2008-01-01T23:59:59.000Z

495

Using Neural Networks  

E-Print Network [OSTI]

unmeasurable parameters in a first-principles mathematical model of the engine. The network is trained using data derived from measured data taken on an auxiliary power unit (APU) engine (from an aircraft application). A discussion of the neural network...

Gabel, S.

496

Financial Networks Anna Nagurney  

E-Print Network [OSTI]

themselves, such as the Internet with electric power networks, financial networks, and transportation Automobiles, Trains, and Planes, Manufacturing and logistics Workstations, Distribution Points Processing Cables Radio Links Voice, Data, Video Energy Pumping Stations, Plants Pipelines, Transmission Lines Water

Nagurney, Anna

497

Membership Criteria: Better Buildings Residential Network | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Membership Criteria: Better Buildings Residential Network Membership Criteria: Better Buildings Residential Network Membership Criteria: Better Buildings Residential Network...

498

Metabolic Engineering to Develop a Pathway for the Selective Cleavage of Carbon-Nitrogen Bonds  

SciTech Connect (OSTI)

The objective of the project is to develop a biochemical pathway for the selective cleavage of C-N bonds in molecules found in petroleum. Specifically a novel biochemical pathway will be developed for the selective cleavage of C-N bonds in carbazole. The cleavage of the first C-N bond in carbazole is accomplished by the enzyme carbazole dioxygenase, that catalyzes the conversion of carbazole to 2-aminobiphenyl-2,3-diol. The genes encoding carbazole dioxygenase were cloned from Sphingomonas sp. GTIN11 and from Pseudomonas resinovorans CA10. The selective cleavage of the second C-N bond has been challenging, and efforts to overcome that challenge have been the focus of recent research in this project. Enrichment culture experiments succeeded in isolating bacterial cultures that can metabolize 2-aminobiphenyl, but no enzyme capable of selectively cleaving the C-N bond in 2-aminobiphenyl has been identified. Aniline is very similar to the structure of 2-aminobiphenyl and aniline dioxygenase catalyzes the conversion of aniline to catechol and ammonia. For the remainder of the project the emphasis of research will be to simultaneously express the genes for carbazole dioxygenase and for aniline dioxygenase in the same bacterial host and then to select for derivative cultures capable of using carbazole as the sole source of nitrogen.

John J. Kilbane II

2005-10-01T23:59:59.000Z

499

Microstructural evolution during transient liquid phase bonding of Inconel 738LC using AMS 4777 filler alloy  

SciTech Connect (OSTI)

IN-738LC nickel-based superalloy was joined by transient liquid phase diffusion bonding using AMS 4777 filler alloy. The bonding process was carried out at 1050 Degree-Sign C under vacuum atmosphere for various hold times. Microstructures of the joints were studied by optical and scanning electron microscopy. Continuous centerline eutectic phases, characterized as nickel-rich boride, chromium-rich boride and nickel-rich silicide were observed at the bonds with incomplete isothermal solidification. In addition to the centerline eutectic products, precipitation of boron-rich particles was observed in the diffusion affected zone. The results showed that, as the bonding time was increased to 75 min, the width of the eutectic zone was completely removed and the joint was isothermally solidified. Homogenization of isothermally solidified joints at 1120 Degree-Sign C for 300 min resulted in the elimination of intermetallic phases formed at the diffusion affected zone and the formation of significant {gamma} Prime precipitates in the joint region. - Highlights: Black-Right-Pointing-Pointer TLP bonding of IN-738LC superalloy was performed using AMS 4777 filler alloy. Black-Right-Pointing-Pointer Insufficient diffusion time resulted in the formation of eutectic product. Black-Right-Pointing-Pointer Precipitation of B-rich particles was observed within the DAZ. Black-Right-Pointing-Pointer The extent of isothermal solidification increased with increasing holding time. Black-Right-Pointing-Pointer Homogenizing of joints resulted in the dissolution of DAZ intermetallics.

Jalilvand, V., E-mail: jalilvand@aut.ac.ir [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of); Omidvar, H. [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of)] [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of); Shakeri, H.R. [Department of Materials Science and Engineering, University of Toronto, Toronto, Ontario M5S 3E4 (Canada)] [Department of Materials Science and Engineering, University of Toronto, Toronto, Ontario M5S 3E4 (Canada); Rahimipour, M.R. [Department of Ceramic, Materials and Energy Research Center, Karaj 31787-316 (Iran, Islamic Republic of)] [Department of Ceramic, Materials and Energy Research Center, Karaj 31787-316 (Iran, Islamic Republic of)

2013-01-15T23:59:59.000Z

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Simultaneous photon absorption as a probe of molecular interaction and hydrogen-bond correlation in liquids  

E-Print Network [OSTI]

We have investigated the simultaneous absorption of near-infrared photons by pairs of neighboring molecules in liquid methanol. Simultaneous absorption by two OH-stretching modes is found to occur at an energy higher than the sum of the two absorbing modes. This frequency shift arises from interaction between the modes, and its value has been used to determine the average coupling between neighboring methanol molecules. We find a rms coupling strength of 46+/-1 cm-1, much larger than can be explained from transition-dipole coupling, suggesting that hydrogen-bond mediated interactions between neighboring molecules play an important role in liquid methanol. The most important aspect of simultaneous vibrational absorption is that it allows for a quantitative investigation of hydrogen-bond cooperativity. We derive the extent to which the hydrogen-bond strengths of neighboring molecules are correlated by comparing the line shape of the absorption band caused by simultaneous absorption with that of the fundamental transition. Surprisingly, neighboring hydrogen bonds in methanol are found to be strongly correlated, and from the data we obtain a hydrogen-bond correlation coefficient of 0.69+/-0.12.

Sander Woutersen

2007-03-06T23:59:59.000Z