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Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Energetics of Hydrogen Bond Network Rearrangements in Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Wednesday, 25 May 2005 00:00 The unique...

2

Ultrafast structural fluctuations and rearrangements of water's hydrogen bonded network  

E-Print Network [OSTI]

Aqueous chemistry is strongly influenced by water's ability to form an extended network of hydrogen bonds. It is the fluctuations and rearrangements of this network that stabilize reaction products and drive the transport ...

Loparo, Joseph J. (Joseph John)

2007-01-01T23:59:59.000Z

3

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

4

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

5

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

6

Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR  

E-Print Network [OSTI]

We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

Nicodemus, Rebecca A.

7

Hydrogen bond rearrangements and the motion of charge defects in water viewed using multidimensional ultrafast infrared spectroscopy  

E-Print Network [OSTI]

Compared with other molecular liquids, water is highly structured due to its ability to form up to four hydrogen bonds to its nearest neighbors, resulting in a tetrahedral network of molecules. However, this network is ...

Roberts, Sean T. (Sean Thomas)

2010-01-01T23:59:59.000Z

8

Rearrangement of a phosphosilicate glass network induced by the 193-nm radiation  

SciTech Connect (OSTI)

The IR absorption and Raman spectra of phosphosilicate glass (PSG) are measured during its exposure to radiation at a wavelength of 193 nm. The obtained data demonstrate the complicated rearrangement dynamics of the glass network around phosphor atoms and of the glass network as a whole. The experimental dependences are explained by the model of the PSG network based on the concepts of the theory of rigidity percolation. (interaction of laser radiation with matter)

Larionov, Yu V [A. M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Sokolov, V O; Plotnichenko, V G [Fiber Optics Research Center, Russian Academy of Sciences, Moscow (Russian Federation)

2008-10-31T23:59:59.000Z

9

Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, Tobias Steinel, and M. D. Fayer*  

E-Print Network [OSTI]

Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, TobiasVed: September 1, 2003; In Final Form: December 18, 2003 The nature of hydrogen bonding networks following hydrogen bond breaking is investigated using vibrational echo correlation spectroscopy of the hydroxyl

Fayer, Michael D.

10

Neutron structure of human carbonic anhydrase II: A hydrogen bonded water network switch is observed between pH 7.8 and 10.0.  

SciTech Connect (OSTI)

The neutron structure of wild type human carbonic anhydrase II at pH 7.8 has been determined to 2.0 resolution. Detailed analysis and comparison to the previous determined structure at pH 10.0 shows important differences in protonation of key catalytic residues in the active site as well as a rearrangement of the hydrogen bonded water network. For the first time, a completed hydrogen bonded network stretching from the Zn-bound solvent to the proton shuttling residue His64 has been directed observed.

Fisher, Zoe [Los Alamos National Laboratory (LANL); Langan, Paul [ORNL; Mustyakimov, Marat [Los Alamos National Laboratory (LANL); Kovalevsky, Andrey [Los Alamos National Laboratory (LANL)

2011-01-01T23:59:59.000Z

11

Hydrogen Bond Networks in Graphene Oxide Composite Paper: Structure and  

E-Print Network [OSTI]

a precur- sor for graphene, GO itself can be useful in flexible electronics,7 in battery electrodes,8Hydrogen Bond Networks in Graphene Oxide Composite Paper: Structure and Mechanical Properties Engineering, University of Texas, Austin, Texas 78712 I n recent years, grapheneOa single layer of carbon

12

Hydrogen Bond Switching among Flavin and Amino Acids Determines the Nature of Proton-Coupled Electron Transfer in BLUF  

E-Print Network [OSTI]

Hydrogen Bond Switching among Flavin and Amino Acids Determines the Nature of Proton results from a hydrogen bond switch between the flavin and its surrounding amino acids that preconfigures a rearrangement of the hydrogen bond network around the flavin takes place leading to a 10-15 nm red shift

van Stokkum, Ivo

13

Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN. Citation: Shokri A, Y Wang, GA...

14

Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen Bonds and An Alternative to the Low Barrier Hydrogen-Bond Proposal  

SciTech Connect (OSTI)

We report quantifying the strengths of different types of hydrogen bonds in hydrogen bond networks (HBNs) via measurement of the adiabatic electron detachment energy of the conjugate base of a small covalent polyol model compound (i.e., (HOCH2CH2CH(OH)CH2)2CHOH) in the gas phase and the pKa of the corresponding acid in DMSO. The latter result reveals that the hydrogen bonds to the charged center and those that are one solvation shell further away (i.e., primary and secondary) provide 5.3 and 2.5 pKa units of stabilization per hydrogen bond in DMSO. Computations indicate that these energies increase to 8.4 and 3.9 pKa units in benzene and that the total stabilizations are 16 (DMSO) and 25 (benzene) pKa units. Calculations on a larger linear heptaol (i.e., (HOCH2CH2CH(OH)CH2CH(OH)CH2)2CHOH) reveal that the terminal hydroxyl groups each contribute 0.6 pKa units of stabilization in DMSO and 1.1 pKa units in benzene. All of these results taken together indicate that the presence of a charged center can provide a powerful energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN.

Shokri, Alireza; Wang, Yanping; O'Doherty, George A.; Wang, Xue B.; Kass, Steven R.

2013-11-27T23:59:59.000Z

15

Nuclear rearrangement energy  

Science Journals Connector (OSTI)

The concept of rearrangement energy in nuclear particle removal is carefully defined by specifying several energies associated with the process and its analysis. Connection is made between the present definition and closely related concepts apt to be confused with "rearrangement energy" so defined. Remarks are made concerning the implications of rearrangement to analysis and interpretation of experimental data.NUCLEAR STRUCTURE Nuclear rearrangement energy theoretically defined and differentiated from related energies. Reaction theories examined regarding rearrangement.

William A. Friedman

1975-07-01T23:59:59.000Z

16

Ettringite Strengthening at High Pressures Induced by the Densification of the Hydrogen Bond Network  

Science Journals Connector (OSTI)

Ettringite Strengthening at High Pressures Induced by the Densification of the Hydrogen Bond Network ... Ettringite is a rare mineral with high-water content, more than half of its weight, and a relevant secondary product in Portland cement. ... Using density functional theory, we simulate the crystal structure and properties of ettringite under pressure. ...

H. Manzano; A. Ayuela; A. Telesca; P. J. M. Monteiro; J. S. Dolado

2012-07-06T23:59:59.000Z

17

E-Print Network 3.0 - adhesively bonded lap Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The lap-shear strengths of adhesively bonded polystyrene (PS), high-density polyethylene (HDPE... bonded in a lap-shear geometry. The bonded area of adhesion was nominally...

18

E-Print Network 3.0 - adhesive bond strength Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The lap-shear strengths of adhesively bonded polystyrene (PS), high-density polyethylene (HDPE... 12;strength of the substrate, or the adhesive strength of the bond 9....

19

E-Print Network 3.0 - affects durably bonding Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

adhesive layers are less affected, creep behavior of adhesively bonded joints... ABSTRACT SMITH, GLEN. Bond Characteristics and Qualifications of Adhesives for ... Source:...

20

E-Print Network 3.0 - alteredintramolecular hydrogen-bonding...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alteredintramolecular hydrogen-bonding pattern Search Powered by Explorit Topic List Advanced Search Sample search results for: alteredintramolecular hydrogen-bonding pattern Page:...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

E-Print Network 3.0 - amide bonds stabilize Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Amide-Amide and Amide-Water Hydrogen Bonds Summary: Bonds: Implicationsfor Protein Folding and Stability Eric S.Eberhardt and Ronald T. Rained Department... folds, many of...

22

E-Print Network 3.0 - aryl-metal bond chemistry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

metal bond chemistry Search Powered by Explorit Topic List Advanced Search Sample search results for: aryl-metal bond chemistry Page: << < 1 2 3 4 5 > >> 1 Subscriber access...

23

Proton transfer reactions and hydrogen-bond networks in protein environments  

Science Journals Connector (OSTI)

...recognized that a salt bridge is a strong H-bond and plays a...pronounced in salt bridges owing to the large pK a difference for the H-bond donor and acceptor...for single-well H-bond formation is...required for salt-bridge formation, which...

2014-01-01T23:59:59.000Z

24

Critical percolation phase and thermal Berezinskii-Kosterlitz-Thouless transition in a scale-free network with short-range and long-range random bonds  

E-Print Network [OSTI]

Percolation in a scale-free hierarchical network is solved exactly by renormalization-group theory in terms of the different probabilities of short-range and long-range bonds. A phase of critical percolation, with algebraic ...

Berker, A. Nihat

25

E-Print Network 3.0 - anisotropic bond model Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Summary: of the combined bonds. In terms FIG. 7: Phase boundary surface for the Ising model on the d 3 fully anisotropic... anisotropic systems are introduced. These...

26

E-Print Network 3.0 - aluminide-bonded carbide ceramics Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

R. Begleyw Summary: include TBCs on superalloys, EBCs on sili- con-based ceramics, or TiCNbN coatings on cemented carbide... with Diffusion Aluminide Bond Coatings,'' Mater....

27

E-Print Network 3.0 - azo covalent bond Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Materials Science ; Chemistry 76 1,4-Dimethyl-l,4,5,6-hexahydro-l,2,3,4-tetrazine. A Cyclic cis-2-Tetrazene Summary: the N2-C bond in position for a large interaction...

28

Photo-Arbuzov rearrangements of benzyl phosphites  

Science Journals Connector (OSTI)

Photo-Arbuzov rearrangements of benzyl phosphites ... Effect of Amino Substituents on the Stereochemical Outcome of the Photo-Arbuzov Rearrangements of 1-Arylethyl Phosphorodiamidites ... Effect of Amino Substituents on the Stereochemical Outcome of the Photo-Arbuzov Rearrangements of 1-Arylethyl Phosphorodiamidites ...

Jan. Omelanzcuk; Alan E. Sopchik; Sueg Geun. Lee; Kunihiko. Akutagawa; S. Matthew. Cairns; Wesley G. Bentrude

1988-09-01T23:59:59.000Z

29

Alkanethiol-Induced Structural Rearrangements in Silica-Gold Core-Shell-type Nanoparticle Clusters: An  

E-Print Network [OSTI]

Alkanethiol-Induced Structural Rearrangements in Silica-Gold Core-Shell-type Nanoparticle Clusters 21, 2003. In Final Form: April 19, 2004 Electrostatically bonded SiO2,Au nanoparticle clusters form by reaction of 3-aminopropylsilane-modified SiO2 spheres (470 nm) with citrate-coated gold nanoparticles (9

Guo, Ting

30

Structural Rearrangements in Water Viewed Through Two- Dimensional Infrared Spectroscopy  

E-Print Network [OSTI]

Compared with other molecular liquids, water is highly structured because of its ability to form up to four hydrogen bonds, resulting in a tetrahedral network of molecules. However, this underlying intermolecular structure ...

Roberts, Sean Thomas

31

Measurement of correlations between low-frequency vibrational modes and particle rearrangements in quasi-two-dimensional colloidal glasses  

E-Print Network [OSTI]

We investigate correlations between low-frequency vibrational modes and rearrangements in two-dimensional colloidal glasses composed of thermosensitive microgel particles which readily permit variation of sample packing fraction. At each packing fraction, the particle displacement covariance matrix is measured and used to extract the vibrational spectrum of the "shadow" colloidal glass (i.e., the particle network with the same geometry and interactions as the sample colloid but absent damping). Rearrangements are induced by successive, small reductions in packing fraction. The experimental results suggest that low-frequency quasi-localized phonon modes in colloidal glasses, i.e., modes that present low energy barriers for system rearrangements, are spatially correlated with rearrangements in this thermal system.

K. Chen; M. L. Manning; P. J. Yunker; W. G. Ellenbroek; Z. Zhang; Andrea J. Liu; A. G. Yodh

2011-03-11T23:59:59.000Z

32

Assignment of Orthologous Genes via Genome Rearrangement  

E-Print Network [OSTI]

Assignment of Orthologous Genes via Genome Rearrangement Xin Chen, Jie Zheng, Zheng Fu, Peng Nan of genomes is a fundamental and challenging problem in comparative genomics. Existing methods that assign sequence similarity and evolutionary events at a genome level, where orthologous genes are assumed

Lonardi, Stefano

33

Bonding Tools  

Broader source: Energy.gov [DOE]

Bonds are one of the most common forms of financing used by state and local governments, because they are a low-cost source of capital available to most entities. State and local officials may consider using bonds for a variety of clean energy purposes, including...

34

Probing the hydrogen-bond network of water via time-resolved soft x-ray spectroscopy  

SciTech Connect (OSTI)

We report time-resolved studies of hydrogen bonding in liquid H2O, in response to direct excitation of the O-H stretch mode at 3 mu m, probed via soft x-ray absorption spectroscopy at the oxygen K-edge. This approach employs a newly developed nanofluidic cell for transient soft x-ray spectroscopy in liquid phase. Distinct changes in the near-edge spectral region (XANES) are observed, and are indicative of a transient temperature rise of 10K following transient laser excitation and rapid thermalization of vibrational energy. The rapid heating occurs at constant volume and the associated increase in internal pressure, estimated to be 8MPa, is manifest by distinct spectral changes that differ from those induced by temperature alone. We conclude that the near-edge spectral shape of the oxygen K-edge is a sensitive probe of internal pressure, opening new possibilities for testing the validity of water models and providing new insight into the nature of hydrogen bonding in water.

Huse, Nils; Wen, Haidan; Nordlund, Dennis; Szilagyi, Erzsi; Daranciang, Dan; Miller, Timothy A.; Nilsson, Anders; Schoenlein, Robert W.; Lindenberg, Aaron M.

2009-04-24T23:59:59.000Z

35

Rearrangement, Convection and Competition Yann BRENIER  

E-Print Network [OSTI]

steps) 500 grid points in x, heat profile y(t, x) versus x drawn every 2 time steps 0 0.2 0.4 0.6 0.8 1.2)2) - exp(-20(x - 0.4)2) t, x [0, 1] h = 0.005 (= 200 time steps) 500 grid points in x, heat profile y(t, x #12;A function and its rearrangement N = 200 grid points in x 0.6 0.8 1 1.2 1.4 1.6 1.8 2 0 0.1 0.2 0

Brenier, Yann

36

Rack-mounted chemistry IV: the thermal rearrangement of 7-oxabenzonorbornadienes into benzo[b]oxepines on and off the polycyclic rack  

Science Journals Connector (OSTI)

Abstract The thermal rearrangement of [3]polynorbornane bis-imide rack-mounted 7-oxabenzonorbornadienes has been conducted using flash vacuum pyrolysis (FVP) at 520 °C and is compared with the FVP of similar 7-oxabenzonorbornadienes off the rack. The isomerisation is considered to involve (a) C–O bond cleavage to a vinylogous 1,5-dipole, (b) formation of a benzene epoxide by nucleophilic ring-closure and (c) valence-isomerisation of the benzene epoxide to the oxepine. Competing fragmentation to the isobenzofuran by ejection of acetylene and other rearrangements become prominent pathways off the rack, whereas isomerisation to the oxepine is highly favored on the rack.

Muhong Shang; Douglas N. Butler; Ronald N. Warrener; Davor Margeti?

2013-01-01T23:59:59.000Z

37

Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Network Network Facts & Stats Engineering Services The Network Network Maps Network Facts & Stats Connected Sites Peering Connections ESnet Site Availabiliy OSCARS Fasterdata...

38

Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional Vibrational Stimulated Echoes  

E-Print Network [OSTI]

Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional, USA (Received 24 February 2003; published 3 December 2003) Hydrogen bond dynamics are explicated hydrogen bonded network are measured with ultrashort (

Fayer, Michael D.

39

Rearrangements in genomes with centromeres part I: translocations  

E-Print Network [OSTI]

Rearrangements in genomes with centromeres part I: translocations Michal Ozery-Flato and Ron Shamir. Every new chromosome created by a genome rearrange- ment event must have a centromere in order to survive. This constraint has been ignored in the computational modeling and analysis of genome

Shamir, Ron

40

Genome Rearrangement and Planning Institute of Information Systems  

E-Print Network [OSTI]

Genome Rearrangement and Planning Esra Erdem Institute of Information Systems Vienna University Avenue, Toronto, Canada e.tillier@utoronto.ca Abstract The genome rearrangement problem is to find the most eco­ nomical explanation for observed differences between the gene orders of two genomes

Erdem, Esra

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bonded Arrays: The Power of Multiple Hydrogen Bonds. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds. Abstract: Hydrogen bond interactions in small covalent model...

42

Ion Hydration and Associated Defects in Hydrogen Bond Network of Water: Observation of Reorientationally Slow Water Molecules Beyond First Hydration Shell in Aqueous Solutions of MgCl$_2$  

E-Print Network [OSTI]

Effects of presence of ions, at moderate to high concentrations, on dynamical properties of water molecules are investigated through classical molecular dynamics simulations using two well known non-polarizable water models. Simulations reveal that the presence of magnesium chloride (MgCl$_2$) induces perturbations in the hydrogen bond network of water leading to the formation of bulk-like domains with \\textquoteleft defect sites\\textquoteright~on boundaries of such domains: water molecules at such defect sites have less number of hydrogen bonds than those in bulk water. Reorientational autocorrelation functions for dipole vectors of such defect water molecules are computed at different concentrations of ions and compared with system of pure water. Earlier experimental and simulation studies indicate significant differences in reorientational dynamics for water molecules in the first hydration shell of many dissolved ions. Results of this study suggest that defect water molecules, which are beyond the first hydration shells of ions, also experience significant slowing down of reorientation times as a function of concentration in the case of MgCl$_2$. However, addition of cesium chloride(CsCl) to water does not perturb the hydrogen bond network of water significantly even at higher concentrations. This difference in behavior between MgCl$_2$ and CsCl is consistent with the well-known Hofmeister series.

Upayan Baul; Satyavani Vemparala

2014-12-18T23:59:59.000Z

43

TWO NOTES ON GENOME REARRANGEMENT MICHAL OZERY-FLATO AND RON SHAMIR  

E-Print Network [OSTI]

TWO NOTES ON GENOME REARRANGEMENT MICHAL OZERY-FLATO AND RON SHAMIR Abstract. A central problem in genome rearrangement is #12;nding a most parsimonious rearrangement scenario using certain rearrangement operations. An important problem of this type is sorting a signed genome by reversals and translocations

Shamir, Ron

44

TWO NOTES ON GENOME REARRANGEMENT MICHAL OZERY-FLATO AND RON SHAMIR  

E-Print Network [OSTI]

TWO NOTES ON GENOME REARRANGEMENT MICHAL OZERY-FLATO AND RON SHAMIR Abstract. A central problem in genome rearrangement is finding a most parsimonious rearrangement scenario using certain rearrangement operations. An important problem of this type is sorting a signed genome by reversals and translocations

Shamir, Ron

45

Rearrangement and annihilation in antihydrogen-atom scattering  

SciTech Connect (OSTI)

I review some results for annihilation and rearrangement processes in low-energy antihydrogen-hydrogen and antihydrogen-helium scattering. For the strong nuclear force results using a {delta}-function potential are compared to a scattering length approach. It is found that the {delta}-function potential does not give correct annihilation cross sections in the case of antihydrogen-helium scattering. Problem associated with the use of the Born-Oppenheimer approximation for rearrangement calculations are reviewed.

Jonsell, Svante [Department of Physics, Swansea University, Singleton Park, Swansea SA2 8PP (United Kingdom)

2008-08-08T23:59:59.000Z

46

Brueckner Rearrangement Effects in $^5_?$He and $^6_{??}$He  

E-Print Network [OSTI]

Rearrangement effects in light hypernuclei are investigated in the framework of the Brueckner theory. We can estimate without detailed numerical calculations that the energy of the $\\alpha$-core is reduced by more than 2.5 MeV when the $\\Lambda$ adheres to $^4$He to form $^5_\\Lambda$He. Similar assessment of rearrangement contributions is essential to deduce the strength of $\\Lambda\\Lambda$ interaction from experimentally observed $\\Delta B_{\\Lambda\\Lambda}$. The recently observed experimental value of $\\sim$ 1 MeV for the $\\Delta B_{\\Lambda\\Lambda}$ of \\hll suggests that the matrix element of $$ in \\hll is around -2 MeV.

M. Kohno; Y. Fujiwara; Y. Akaishi

2003-07-28T23:59:59.000Z

47

Genome Rearrangement: A Planning Approach Tansel Uras and Esra Erdem  

E-Print Network [OSTI]

Genome Rearrangement: A Planning Approach Tansel Uras and Esra Erdem Faculty of Engineering be reconstructed by pair- wise comparison of their entire genomes. Such a comparison can be quantified by determining the number of events that change the order of genes in a genome. Earlier Erdem and Tillier

Erdem, Esra

48

Genome Rearrangement and Planning: Revisited Tansel Uras and Esra Erdem  

E-Print Network [OSTI]

Genome Rearrangement and Planning: Revisited Tansel Uras and Esra Erdem Faculty of Engineering be reconstructed by pair- wise comparison of their entire genomes. Such a comparison can be quantified by determining the number of events that change the order of genes in a genome. Earlier Erdem and Tillier

Erdem, Esra

49

AdhesiveBonding.qrk  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Adhesive Bonding Adhesive Bonding Manufacturing Technologies Understanding and controlling the factors that affect adhesion is vital for ensuring consistent successful bonding operations. The Manufacturing Science and Technology Center's research into adhesion is focused on achieving a good initial bond and then understanding the mechanisms leading to eventual bond failure. The department is working to understand crack propagation at the interface and has developed a variety of mechanical testing techniques to evalu- ate this failure mode. The factors affecting wetting and formation of the bond (e.g., contamination, surface roughness) are being explored to further our knowledge. In addition to research into adhesion, we bond and join components for our cus- tomers. Researchers have formulated new

50

Private Activity Revenue Bonds (Maryland)  

Broader source: Energy.gov [DOE]

Private Activity Revenue Bonds are available in the form of both taxable bonds and tax-exempt bonds. Both types of bonds provide access to long-term capital markets for fixed asset financing....

51

Rearranging the Exponential Wall for Large N-Body Systems  

SciTech Connect (OSTI)

The work required to solve for the fully interacting N boson wave function, which is widely believed to scale exponentially with N, is rearranged so the problem scales order by order in a perturbation series as N{sup 0}. The exponential complexity reappears in an exponential scaling with the order of our perturbation series allowing exact analytical calculations for very large N systems through low order.

Watson, Deborah K.; Dunn, Martin [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, Norman, Oklahoma 73019 (United States)

2010-07-09T23:59:59.000Z

52

Water molecules insert into N-HCl-M hydrogen bonds while M-ClX-C halogen bonds remain intact in dihydrates of halopyridinium hexachloroplatinates  

Science Journals Connector (OSTI)

Crystals of the dihydrates of three halopyridinium hexachloroplatinate salts form networks that are propagated via N-HO and O-HCl-Pt hydrogen bonds and Pt-ClX-C halogen bonds. The water molecules can be considered to have been inserted into N-HCl-Pt hydrogen bonds anticipated in the anyhdrous form of such salts.

Zordan, F.

2004-09-15T23:59:59.000Z

53

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

54

Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Site Feedback: info@es.net About ESnet A Nationwide Platform for Science Discovery The Energy Sciences Network (ESnet) is a high-performance, unclassified national network built to...

55

Structures and Reactivity of Transition-Metal Compounds Featuring Metal-Ligand Multiple Bonds  

E-Print Network [OSTI]

isomers of product 2a-f. .................................................................. 89 Figure 34. The rearrangement between 2_iso6 and 2_iso3. ............................................. 92 Figure 35. The solvated ?G (kcal/mol) diagram... iso3 and iso6 for 2a-f (kcal/mol). ................ 91 Table 17. Results of energies differencesa between 2c_iso6 and 2c_iso3. ...................... 92 xv Table 18. Selected structural parameters of 2a from computations and experiments. (Bond...

Xu, Zhenggang

2014-07-25T23:59:59.000Z

56

Qualified Energy Conservation Bonds  

Broader source: Energy.gov [DOE]

A Qualified Energy Conservation Bond (QECB) is a bond that enables qualified state, tribal, and local government issuers to borrow money at attractive rates to fund energy conservation projects (it is important to note that QECBs are not grants). A QECB is among the lowest-cost public financing tools because the U.S. Department of the Treasury subsidizes the issuer's borrowing costs.

57

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

58

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

59

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

60

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trending: Metal Oxo Bonds Print Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide variety of important emergent technologies, including industrial catalysis, biomimetic transformations, and artificial photosynthesis. To address this problem, a research team from four national laboratories, three Department of Energy synchrotron user facilities, and the University of Washington has applied spectroscopic and computational analyses to a number of metal oxides, quantifying trends in metal oxo bonding for groups of metals across the periodic table.

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Argonne Coal Structure Rearrangement Caused by Sorption of CO2  

Science Journals Connector (OSTI)

Argonne Coal Structure Rearrangement Caused by Sorption of CO2 ... The sorption of CO2 on seven Argonne premium coals was measured by using attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy as a function of time at constant CO2 pressure (0.62 MPa) and temperature (55 °C). ... The following seven Argonne premium coals were investigated:? Upper Freeport (medium volatile bituminous), Pittsburgh No. 8 (high volatile bituminous), Lewiston?Stockton (high volatile bituminous), Blind Canyon (high volatile bituminous), Illinois No. 6 (high volatile bituminous), Wyodak (sub-bituminous), and Beulah Zap (lignite). ...

A. L. Goodman; R. N. Favors; John W. Larsen

2006-10-05T23:59:59.000Z

62

Characterization of the sp2 bonds network in a-C:H layers with nuclear magnetic resonance, electron energy loss spectroscopy and electron spin resonance  

Science Journals Connector (OSTI)

a-C:H layers prepared at different ion energies have been investigated by several methods including 13C nuclear magnetic resonance (NMR), electron energy loss spectroscopy (EELS) and electron spin resonance (ESR). The sp2 fraction of the samples rose from 27% to about 60 at.% with increasing ion energies from 30 eV to 170 eV. In the EELS spectra of these layers the intensity of the ? ? ?? transition between 4 and 7 eV showed no significant variation. But a shift of the peak is observed from 7 eV to lower energy losses with increasing ion energies indicating an enhanced formation of larger sp2 cluster sizes. This shift is accompanied by a broadening of the energy loss peak, suggesting a broadening of the cluster size distribution. The ESR spectra showed an increase of the spin density by more than one order of magnitude with increasing ion energies. Simultaneously the linewidth of the ESR signal gets narrower. This can also be interpreted as an increasing cluster size from single benzene rings to three and four fused six-fold rings. Hence, the EELS and ESR spectra lead to the same conclusions with respect to the microstructure of the a-C:H network.

R. Kleber; K. Jung; H. Ehrhardt; I. Mühling; K. Breuer; H. Metz; F. Engelke

1991-01-01T23:59:59.000Z

63

Wafer-Level Thermocompression Bonds  

E-Print Network [OSTI]

Thermocompression bonding of gold is a promising technique for achieving low temperature, wafer-level bonding without the application of an electric field or complicated pre-bond cleaning procedure. The presence of a ductile ...

Tsau, Christine H.

64

Compositions and methods for detecting gene rearrangements and translocations  

DOE Patents [OSTI]

Disclosed is a series of nucleic acid probes for use in diagnosing and monitoring certain types of leukemia using, e.g., Southern and Northern blot analyses and fluorescence in situ hybridization (FISH). These probes detect rearrangements, such as translocations involving chromosome band 11q23 with other chromosomes bands, including 4q21, 6q27, 9p22, 19p13.3, in both dividing leukemic cells and interphase nuclei. The breakpoints in all such translocations are clustered within an 8.3 kb BamHI genomic region of the MLL gene. A novel 0.7 kb BamH1 cDNA fragment derived from this gene detects rearrangements on Southern blot analysis with a single BamHI restriction digest in all patients with the common 11q23 translocations and in patients with other 11q23 anomalies. Northern blot analyses are presented demonstrating that the MLL gene has multiple transcripts and that transcript size differentiates leukemic cells from normal cells. Also disclosed are MLL fusion proteins, MLL protein domains and anti-MLL antibodies.

Rowley, Janet D. (Chicago, IL); Diaz, Manuel O. (Chicago, IL)

2000-01-01T23:59:59.000Z

65

Characterization of anodic bonding  

E-Print Network [OSTI]

Anodic bonding is a common process used in MicroElectroMechanical Systems (MEMS) device fabrication and packaging. Polycrystalline chemical vapor deposited (CVD) silicon carbide (SiC) is emerging as a new MEMS device and ...

Tudryn, Carissa Debra, 1978-

2004-01-01T23:59:59.000Z

66

The New Chemical Bond  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

off when the first convincing experimental evidence of the phi bond showed up for the thorium sandwich complex, as revealed by its elaborate, never-before-seen symmetry. The...

67

Qualified Energy Conservation Bonds  

Broader source: Energy.gov [DOE]

Provides an in-depth description of qualified energy conservation bonds, including process and mechanics, case studies, utilization trends, barriers, and regulatory and legal issues. Author: Energy Programs Consortium

68

Water's Hydrogen Bond Strength  

E-Print Network [OSTI]

Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

Martin Chaplin

2007-06-10T23:59:59.000Z

69

A 2-Approximation Algorithms for Genome Rearrangements by Reversals and Transpositions 1  

E-Print Network [OSTI]

A 2-Approximation Algorithms for Genome Rearrangements by Reversals and Transpositions 1 Qian of Texas at Dallas, Richardson, TX 75083 U.S.A. Keywords: Sorting of permutations, genome rearrangements: Recently, a new approach to analyze genomes evolving was proposed which is based on comparison of gene

Gu, Qianping

70

MODELING PHOTO COMPOSITION AND ITS APPLICATION TO PHOTO RE-ARRANGEMENT  

E-Print Network [OSTI]

MODELING PHOTO COMPOSITION AND ITS APPLICATION TO PHOTO RE-ARRANGEMENT Jaesik Park, Joon-Young Lee a learning based photo composition model and its application on photo re-arrangement. In contrast to previ- ous approaches which evaluate quality of photo composition using the rule of thirds or the golden

Kim, Dae-Shik

71

Stocks, bonds and the  

Science Journals Connector (OSTI)

In this paper, we investigate the relative performance of stocks and bonds for various investment horizons on the French market. We use a new matched block bootstrap approach to take account of estimation risk. Furthermore, in the light of non-normality of returns, we use two different risk approaches as inputs in portfolio optimization: the traditional variance, and a downside risk measure, the semi-variance. Our results suggest that an investor should avoid bonds in the long run due to the time diversification effect.

Gilles Sanfilippo

2003-01-01T23:59:59.000Z

72

Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Tobias Steinel, John B. Asbury, Junrong Zheng, and M. D. Fayer*  

E-Print Network [OSTI]

Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Tobias Steinel, John B. Asbury of picoseconds, observe hydrogen bond breaking and monitor the equilibration of the hydrogen bond network in water. In addition, the vibrational lifetime, the time constant for hydrogen bond breaking, and the rate

Fayer, Michael D.

73

Photochemical tissue bonding  

DOE Patents [OSTI]

Photochemical tissue bonding methods include the application of a photosensitizer to a tissue and/or tissue graft, followed by irradiation with electromagnetic energy to produce a tissue seal. The methods are useful for tissue adhesion, such as in wound closure, tissue grafting, skin grafting, musculoskeletal tissue repair, ligament or tendon repair and corneal repair.

Redmond, Robert W. (Brookline, MA); Kochevar, Irene E. (Charlestown, MA)

2012-01-10T23:59:59.000Z

74

Thread bonds in molecules  

E-Print Network [OSTI]

Unusual chemical bonds are proposed. Each bond is almost covalent but is characterized by the thread of a small radius $\\sim 0.6\\times 10^{-11}$cm, between two nuclei in a molecule. The main electron density is concentrated outside the thread as in a covalent bond. The thread is formed by the electron wave function which has a tendency to be singular on it. The singularity along the thread is cut off by electron "vibrations" due to the interaction with zero point electromagnetic oscillations. The electron energy has its typical value of (1-10)eV. Due to the small tread radius the uncertainty of the electron momentum inside the thread is large resulting in a large electron kinetic energy $\\sim 1 MeV$. This energy is compensated by formation of a potential well due to the reduction of the energy of electromagnetic zero point oscillations. This is similar to formation of a negative van der Waals potential. Thread bonds are stable and cannot be created or destructed in chemical or optical processes.

Ivlev, B

2015-01-01T23:59:59.000Z

75

A Facile Access to Densely Functionalized Substituted Cyclopentanes and Spiro Cyclopentanes. Carbocation Stabilization Directed Bond Migration in Rearrangement of Cyclobutanes  

Science Journals Connector (OSTI)

A magnetically stirred solution of the diene 5a (1.3 g, 7.8 mmol) in diethyl ether (250 mL) containing CuOTf (0.2 g) under an Ar atmosphere was irradiated with a 450 W medium pressure mercury vapor lamp (Hanovia) through a double-walled water-cooled quartz immersion well for 6?7 h. ...

Azizul Haque; Anjan Ghatak; Subrata Ghosh; Nanda Ghoshal

1997-07-25T23:59:59.000Z

76

Atomic origin of hysteresis during cyclic loading of Si due to bond rearrangements at the crack surfaces  

E-Print Network [OSTI]

that invokes mechanically induced subcritical cracking to explain the delayed onset of failure. © 2005 American associated with a larger initial flaw, which is assumed to be caused by subcritical crack growth, 5- time during high cycle fatigue if water is present, and 6 a fatigue lifetime that depends only

Carter, Emily A.

77

Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed by Ultrafast Infrared Spectroscopy  

E-Print Network [OSTI]

Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed hydrogen-bond network with nearby amino acid side chains, including a highly conserved tyrosine and glutamine. The participation of particular amino acid side chains in the ultrafast hydrogen-bond switching

van Stokkum, Ivo

78

Albert Bond | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bond - Project Officer, Golden Field Office Albert Bond is a Project Officer at the Golden Field Office. Most Recent New Choctaw Nation Recycling Center Posts Quick Results March 8...

79

Effects of structural rearrangements on sorption capacity of coals  

SciTech Connect (OSTI)

Recently, the problems in practical application of experimental data and modeling to the sequestration of carbon dioxide in coal seams and the concurrent enhanced coalbed methane (ECBM) recovery have underscored the need for new approaches that take into account the ability of coal for structural rearrangements. Areas of interest include plasticization of coal due to CO2 dissolution, the effect of coal swelling on estimation of the capacity of a coal-seam to adsorb CO2 (adsorption isotherm), and the stability of the CO2 saturated phase once formed, especially with respect to how it might be affected by changes in the post-sequestration environment (environmental effects). Coals are organic macromolecular systems well known to imbibe organic liquids and carbon dioxide. CO2 dissolves in coals and swells them. The problems become more prominent in the region of supercritical CO2. We investigated the effects of moisture content and pressure cycling history on temporal changes in the coal sorptive capacity for a set of Argonne premium coals. The samples were tested as received, dried at 80oC for 36 hours, and moisture equilibrated at 96-97% RH and 30oC for 48 hours. The powders were compared to core samples. Additionally, plasticization of coal powders was studied by high pressure dilatometer.

Romanov, Vyacheslav; Soong, Yee; Warzinski, R.P.; Lynn, R.J.

2006-09-01T23:59:59.000Z

80

Opportunities in Bond Financing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Opportunities in Bond Financing Opportunities in Bond Financing James Dack Vice President Alternative Energy Finance Group Stern Brothers & Co. Seattle, WA 98101 Biogas and Fuel Cells Workshop National Renewable Energy Laboratory Golden, Colorado June 11-13, 2012 2 INTRODUCTION * Stern Brothers, founded in 1917 and headquartered in St. Louis, is an investment banking firm that is focused on project financing (taxable and tax-exempt) for renewable energy, real estate, higher education and healthcare. * Stern's Alternative Energy Finance Group structures and places tax- exempt and taxable debt, and provides financial advisory services for renewable energy projects in the U.S. * Waste-to-energy, second generation biofuels, biochemicals, biomass, solar, wind, landfill gas-to-energy, cogen, CHP, hydro,

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

A Combined Allylic Azide Rearrangement and Intramolecular Schmidt Reaction - Discovery, Development, and Application  

E-Print Network [OSTI]

and intramolecular Schmidt reaction afforded the target with desired stereochemistry, and the synthesis of the cyclobutanone was achieved by an asymmetric [2+2] cycloaddition. Prior to its combination with the intramolecular Schmidt reaction, the rearrangement...

Liu, Ruzhang

2012-12-31T23:59:59.000Z

82

Delineating Rearrangements in Single Yeast Artificial Chromosomes by Quantitative DNA Fiber Mapping  

SciTech Connect (OSTI)

Cloning of large chunks of human genomic DNA in recombinant systems such as yeast or bacterial artificial chromosomes has greatly facilitated the construction of physical maps, the positional cloning of disease genes or the preparation of patient-specific DNA probes for diagnostic purposes. For this process to work efficiently, the DNA cloning process and subsequent clone propagation need to maintain stable inserts that are neither deleted nor otherwise rearranged. Some regions of the human genome; however, appear to have a higher propensity than others to rearrange in any host system. Thus, techniques to detect and accurately characterize such rearrangements need to be developed. We developed a technique termed 'Quantitative DNA Fiber Mapping (QDFM)' that allows accurate tagging of sequence elements of interest with near kilobase accuracy and optimized it for delineation of rearrangements in recombinant DNA clones. This paper demonstrates the power of this microscopic approach by investigating YAC rearrangements. In our examples, high-resolution physical maps for regions within the immunoglobulin lambda variant gene cluster were constructed for three different YAC clones carrying deletions of 95 kb and more. Rearrangements within YACs could be demonstrated unambiguously by pairwise mapping of cosmids along YAC DNA molecules. When coverage by YAC clones was not available, distances between cosmid clones were estimated by hybridization of cosmids onto DNA fibers prepared from human genomic DNA. In addition, the QDFM technology provides essential information about clone stability facilitating closure of the maps of the human genome as well as those of model organisms.

Weier, Heinz-Ulrich G.; Greulich-Bode, Karin M.; Wu, Jenny; Duell, Thomas

2009-09-18T23:59:59.000Z

83

Collective Hydrogen Bond Reorganization in Water Studied with Temperature-Dependent Ultrafast Infrared Spectroscopy  

E-Print Network [OSTI]

We use temperature-dependent ultrafast infrared spectroscopy of dilute HOD in H2O to study the picosecond reorganization of the hydrogen bond network of liquid water. Temperature-dependent two-dimensional infrared (2D IR), ...

Nicodemus, Rebecca A.

84

Vacuum fusion bonding of glass plates  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

85

Vacuum fusion bonding of glass plates  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2000-01-01T23:59:59.000Z

86

Tax credits, exempt bonds hit  

Science Journals Connector (OSTI)

Tax credits, exempt bonds hit ... A tax credit permits a taxpayer to deduct a certain amount from his final tax bill. ...

1967-03-06T23:59:59.000Z

87

Chromosomal Rainbows detect Oncogenic Rearrangements of Signaling Molecules in Thyroid Tumors  

SciTech Connect (OSTI)

Altered signal transduction can be considered a hallmark of many solid tumors. In thyroid cancers the receptor tyrosine kinase (rtk) genes NTRK1 (Online Mendelian Inheritance in Man = OMIM *191315, also known as 'TRKA'), RET ('Rearranged during Transfection protooncogene', OMIM *164761) and MET (OMIM *164860) have been reported as activated, rearranged or overexpressed. In many cases, a combination of cytogenetic and molecular techniques allows elucidation of cellular changes that initiate tumor development and progression. While the mechanisms leading to overexpression of the rtk MET gene remain largely unknown, a variety of chromosomal rearrangements of the RET or NTKR1 gene could be demonstrated in thyroid cancer. Abnormal expressions in these tumors seem to follow a similar pattern: the rearrangement translocates the 3'-end of the rtk gene including the entire catalytic domain to an expressed gene leading to a chimeric RNA and protein with kinase activity. Our research was prompted by an increasing number of reports describing translocations involving ret and previously unknown translocation partners. We developed a high resolution technique based on fluorescence in situ hybridization (FISH) to allow rapid screening for cytogenetic rearrangements which complements conventional chromosome banding analysis. Our technique applies simultaneous hybridization of numerous probes labeled with different reporter molecules which are distributed along the target chromosome allowing the detection of cytogenetic changes at near megabase-pair (Mbp) resolution. Here, we report our results using a probe set specific for human chromosome 10, which is altered in a significant portion of human thyroid cancers (TC's). While rendering accurate information about the cytogenetic location of rearranged elements, our multi-locus, multi-color analysis was developed primarily to overcome limitations of whole chromosome painting (WCP) and chromosome banding techniques for fine mapping of breakpoints in papillary thyroid cancer (PTC).

O'Brien, Benjamin; Jossart, Gregg H.; Ito, Yuko; Greulich-Bode, Karin M.; Weier, Jingly F.; Munne, Santiago; Clark, Orlo H.; Weier, Heinz-Ulrich G.

2010-08-19T23:59:59.000Z

88

Bond Programs | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » Bond Programs Jump to: navigation, search Bonds allow governments (and corporations) to raise money by borrowing. A few states and local governments have established bond programs to support energy efficiency and renewable energy for government-owned facilities. After a government has raised an authorized sum of money through the sale of bonds, the money collected is used to improve energy efficiency or to install renewable energy systems on government facilities. The bonding authority is usually reimbursed using the energy savings resulting from these projects. [1]

89

Quantum Confinement in Hydrogen Bond  

E-Print Network [OSTI]

In this work, the quantum confinement effect is proposed as the cause of the displacement of the vibrational spectrum of molecular groups that involve hydrogen bonds. In this approach the hydrogen bond imposes a space barrier to hydrogen and constrains its oscillatory motion. We studied the vibrational transitions through the Morse potential, for the NH and OH molecular groups inside macromolecules in situation of confinement (when hydrogen bonding is formed) and non-confinement (when there is no hydrogen bonding). The energies were obtained through the variational method with the trial wave functions obtained from Supersymmetric Quantum Mechanics (SQM) formalism. The results indicate that it is possible to distinguish the emission peaks related to the existence of the hydrogen bonds. These analytical results were satisfactorily compared with experimental results obtained from infrared spectroscopy.

Santos, Carlos da Silva dos; Ricotta, Regina Maria

2015-01-01T23:59:59.000Z

90

Novel Mutations in a Patient with ALK-Rearranged Lung Cancer  

Science Journals Connector (OSTI)

To the Editor: A 49-year-old nonsmoking woman presented with pleuritic pain on the right side of her chest. Computed tomography (CT) of the chest revealed a spiculated, noncalcified pulmonary nodule in the right middle lobe 1.2 cm in diameter and multiple noncalcified nodules (2.0 to 3.0 mm in... A variety of mechanisms of crizotinib resistance have been defined in patients with ALK-rearranged lung cancer who no longer have a response to the drug. A case is presented in which the tumor lost the rearrangement and mutations developed in several other genes.

2014-10-23T23:59:59.000Z

91

Crizotinib in ROS1-Rearranged Non–Small-Cell Lung Cancer  

Science Journals Connector (OSTI)

...Assessments. Patients underwent baseline tumor imaging, with computed tomography or magnetic resonance imaging of the chest, abdomen, and pelvis. Brain and bone scans were obtained at baseline if disease at these sites was suspected. Tumor assessments were performed by the investigators every 8 weeks... About 1% of non–small-cell lung cancers have ROS1 rearrangements. This oncogene is inhibited by crizotinib. In a cohort of 50 patients with ROS1-rearranged lung cancer, crizotinib induced responses in 72%; the median duration of response was nearly a year and a half.

Shaw A.T.; Ou S.-H.I.; Bang Y.-J.

2014-11-20T23:59:59.000Z

92

Method for vacuum fusion bonding  

DOE Patents [OSTI]

An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

2001-01-01T23:59:59.000Z

93

Fusion bonding and alignment fixture  

DOE Patents [OSTI]

An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all the components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

2000-01-01T23:59:59.000Z

94

Fast Phylogenetic Methods for the Analysis of Genome Rearrangement Data: An Empirical Study  

E-Print Network [OSTI]

Fast Phylogenetic Methods for the Analysis of Genome Rearrangement Data: An Empirical Study Li Austin, TX 78712 Evolution operates on whole genomes through mutations that change the order and strandedness of genes within the genomes. Thus analyses of gene-order data present new opportunities

Moret, Bernard

95

Fast Phylogenetic Methods for the Analysis of Genome Rearrangement Data: An Empirical Study  

E-Print Network [OSTI]

Fast Phylogenetic Methods for the Analysis of Genome Rearrangement Data: An Empirical Study Li Austin, TX 78712 Evolution operates on whole genomes through mutations that change the order and strandedness of genes within the genomes. Thus analyses of gene­order data present new opportunities

Moret, Bernard

96

RNA splicing mutation in an aberrantly rearranged immunoglobulin lambda I gene  

Science Journals Connector (OSTI)

...nitrocellulose blotting by using as probe the nick-trans- Abbreviations: V, J, and C...obtain the 300-bp fragment (13). After nick trans- lation, the'300-bp fiagment...the abnormally rearranged Al gene that merit comment. The first is that there is thymidine...

N Hozumi; G E Wu; H Murialdo; L Roberts; D Vetter; W L Fife; M Whiteley; P Sadowski

1981-01-01T23:59:59.000Z

97

New Clean Renewable Energy Bonds | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New Clean Renewable Energy Bonds New Clean Renewable Energy Bonds New clean renewable energy bonds (CREBs) are tax credit bonds, the proceeds of which are used for capital...

98

Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable...  

Energy Savers [EERE]

Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable Energy Bonds (New CREBs) Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable Energy Bonds (New...

99

E-Print Network 3.0 - aza cope rearrangement Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Related Analogues as Phosphatidylinositol Specic Phospholipase C (PI-PLC) Inhibitors Summary: 3-Hydroxy-6-aza-cholestane and Related Analogues as...

100

E-Print Network 3.0 - additional chromosomal rearrangements Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Department of Medical Genetics, University of Wisconsin at Madison Collection: Renewable Energy ; Biology and Medicine 2 TRENDS in Ecology & Evolution Vol.16 No.7 July 2001 http:...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Covalent Bonding in Actinide Sandwich Molecules  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalent Bonding in Actinide Sandwich Molecules Print Glenn Seaborg was one of the first scientists to recognize that differences in the degree of covalent bonding in lanthanide...

102

Magnetic Testing of Bonded Magnets  

Science Journals Connector (OSTI)

Many techniques exist to characterize the magnetic properties of bonded magnets. We will review the common and not so common techniques in use, with emphasis on the advantages and disadvantages of each one, an...

S. R. Trout

2003-01-01T23:59:59.000Z

103

Digital Bond Fact Sheet.cdr  

Broader source: Energy.gov (indexed) [DOE]

cost-shared effort between industry and cost-shared effort between industry and Cyber Security Audit and Attack Detection Toolkit Cyber Security Audit and Attack Detection Toolkit Bandolier Audit Files for optimizing security configurations and the Portaledge event detection capability for energy control systems Bandolier Audit Files for optimizing security configurations and the Portaledge event detection capability for energy control systems Cyber Security for Energy Delivery Systems Electricity Delivery & Energy Reliability Project Lead: Digital Bond Partners: OSIsoft Tenable Network Security PacifiCorp Tennessee Valley Authority Other Participating Vendors: ABB AREVA Emerson Matrikon SNC Telvent Bandolier and Portaledge The Concept Bandolier-The Approach By building configuration audit and attack detection capabilities into tools already

104

Effect of hydrogen bridge geometry on the vibrational spectra of water: Three-parameter potential of H bond  

Science Journals Connector (OSTI)

The ability of water molecules to form a three-dimensional network of hydrogen bonds basically determines both the intrinsic structure and unique properties of this liquid and also a character of interactions wit...

Yu. Ya. Efimov

2010-06-01T23:59:59.000Z

105

Neutron diffraction of. cap alpha. ,. beta. and. gamma. cyclodextrins: hydrogen bonding patterns  

SciTech Connect (OSTI)

Cyclodextrins (CD's) are torus-shaped molecules composed of six (..cap alpha..), seven (..beta..) or eight (..gamma..) (1 ..-->.. 4) linked glucoses. ..cap alpha..-CD has been shown to have two different structures with well-defined hydrogen bonds, one tense and the other relaxed. An induced-fit-like mechanism for ..cap alpha..-CD complex formation has been proposed. Circular hydrogen bond networks have also been found for ..cap alpha..-CD due to the energetically favored cooperative effect. ..beta..-CD with a disordered water structure possesses an unusual flip-flop hydrogen bonding system of the type O-H H-O representing an equilibrium between two states; O-H O reversible H-O. ..gamma..-CD with a disordered water structure similar to ..beta..-CD also possesses the flip-flop hydrogen bond. This study demonstrates that hydrogen bonds are operative in disordered systems and display dynamics even in the solid state.

Hingerty, B.E.; Klar, B.; Hardgrove, G.; Betzel, C.; Saenger, W.

1983-01-01T23:59:59.000Z

106

Non-bonded ultrasonic transducer  

DOE Patents [OSTI]

A mechanically assembled non-bonded ultrasonic transducer includes a substrate, a piezoelectric film, a wetting agent, a thin metal electrode, and a lens held in intimate contact by a mechanical clamp. No epoxy or glue is used in the assembly of this device.

Eoff, J.M.

1984-07-06T23:59:59.000Z

107

The Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Network Engineering Services The Network Network Maps Network Facts & Stats Connected Sites Peering Connections ESnet Site Availabiliy OSCARS Fasterdata IPv6 Network Network...

108

Long Range Bond-Bond Correlations in Dense Polymer Solutions  

Science Journals Connector (OSTI)

The scaling of the bond-bond correlation function P1(s) along linear polymer chains is investigated with respect to the curvilinear distance s along the flexible chain and the monomer density ? via Monte Carlo and molecular dynamics simulations. Surprisingly, the correlations in dense three-dimensional solutions are found to decay with a power law P1(s)?s-? with ?=3/2 and the exponential behavior commonly assumed is clearly ruled out for long chains. In semidilute solutions, the density dependent scaling of P1(s)?g-?0(s/g)-? with ?0=2-2?=0.824 (?=0.588 being Flory's exponent) is set by the number of monomers g(?) in an excluded volume blob. Our computational findings compare well with simple scaling arguments and perturbation calculation. The power-law behavior is due to self-interactions of chains caused by the chain connectivity and the incompressibility of the melt.

J. P. Wittmer; H. Meyer; J. Baschnagel; A. Johner; S. Obukhov; L. Mattioni; M. Müller; A. N. Semenov

2004-09-29T23:59:59.000Z

109

State Bond Program | Open Energy Information  

Open Energy Info (EERE)

Bonds allow governments (and corporations) to raise money by borrowing. A Bonds allow governments (and corporations) to raise money by borrowing. A few states and local governments have established bond programs to support energy efficiency and renewable energy for government-owned facilities. After a government has raised an authorized sum of money through the sale of bonds, the money collected is used to improve energy efficiency or to install renewable energy systems on government facilities. The bonding authority is usually reimbursed using the energy savings resulting from these projects. [1] State Bond Program Incentives CSV (rows 1 - 7) Incentive Incentive Type Place Applicable Sector Eligible Technologies Active Energy Efficiency & Renewable Energy Bond Program (New Mexico) State Bond Program New Mexico Schools

110

The Market for Borrowing Corporate Bonds  

E-Print Network [OSTI]

This paper describes the market for borrowing corporate bonds using a comprehensive data set from a major lender. The cost of borrowing corporate bonds is comparable to the cost of borrowing stock, between 10 and 20 basis ...

Asquith, Paul

111

Study of bump bonding technology  

SciTech Connect (OSTI)

Pixel detectors proposed for the new generation of hadron collider experiments will use bump-bonding technology based on either indium or Pb/Sn solder to connect the front-end readout chips to the silicon pixel sensors. We have previously reported large-scale tests of the yield using both indium and Pb/Sn solder bump [1]. The conclusion is that both seem to be viable for pixel detectors. We have also carried out studies of various effects (e.g. storage over long period, effect of heating and cooling, and radiation) on both types of bump bonds using daisy-chained parts on a small scale [2], [3]. Overall, these tests showed little changes in the integrity of the bump connections. Nevertheless, questions still remain on the long-term reliability of the bumps due to thermal cycle effects, attachment to a substrate with a different coefficient of thermal expansion (CTE), and radiation.

Selcuk Cihangir et al.

2003-10-17T23:59:59.000Z

112

Bonded, walk-off compensated optical elements  

DOE Patents [OSTI]

A bonded, walk-off compensated crystal, for use with optical equipment, and methods of making optical components including same.

Ebbers, Christopher A. (Livermore, CA)

2003-04-08T23:59:59.000Z

113

Metallic bonding in magnesium microclusters  

Science Journals Connector (OSTI)

We investigate the size evolution of bonding in magnesium clusters Mgn, with n?20. Computations are performed in the density-functional scheme with two prescriptions for the exchange-correlation energy: the local-density approximation (LDA), and an improved scheme including gradient corrections (GC). The LDA results show that Mg10 clusters already have acquired several of the characteristic features of metallic aggregates. GC significantly decrease the cohesive energies, and predict a slower convergence with n to the bulk, without changing, however, the qualitative picture given by LDA.

P. Delaly; P. Ballone; J. Buttet

1992-02-15T23:59:59.000Z

114

Vacuum fusion bonded glass plates having microstructures thereon  

DOE Patents [OSTI]

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

115

Linker Dependent Bond Rupture Force Measurements in Single-Molecule Junctions  

SciTech Connect (OSTI)

We use a modified conducting atomic force microscope to simultaneously probe the conductance of a single-molecule junction and the force required to rupture the junction formed by alkanes terminated with four different chemical link groups which vary in binding strength and mechanism to the gold electrodes. Molecular junctions with amine, methylsulfide, and diphenylphosphine terminated molecules show clear conductance signatures and rupture at a force that is significantly smaller than the measured 1.4 nN force required to rupture the single-atomic gold contact. In contrast, measurements with a thiol terminated alkane which can bind covalently to the gold electrode show conductance and force features unlike those of the other molecules studied. Specifically, the strong Au-S bond can cause structural rearrangements in the electrodes, which are accompanied by substantial conductance changes. Despite the strong Au-S bond and the evidence for disruption of the Au structure, the experiments show that on average these junctions also rupture at a smaller force than that measured for pristine single-atom gold contacts.

Frei M.; Hybertsen M.; Aradhya S.V.; Venkataraman L.

2012-02-16T23:59:59.000Z

116

Public Bonding Options | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

While the revenue stream need not be directly related to the financed project, capital lease revenue bonds entail a third party guaranteeing an energy savings revenue stream,...

117

Hydrogen Adsorption Induces Interlayer Carbon Bond Formation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Adsorption Induces Interlayer Carbon Bond Formation in Supported Few-Layer Graphene Friday, February 28, 2014 Among the allotropes of carbon, diamond has some of the most...

118

Nuclear reactor multiphysics via bond graph formalism  

E-Print Network [OSTI]

This work proposes a simple and effective approach to modeling nuclear reactor multiphysics problems using bond graphs. Conventional multiphysics simulation paradigms normally use operator splitting, which treats the ...

Sosnovsky, Eugeny

2014-01-01T23:59:59.000Z

119

E-Print Network Topics: B  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ceramic staircase bonded composite doubler bonded composite doublers bonded composite patch bonded composite repair bonded composite repairs bonded composite semicircular bonded...

120

Energy landscapes, structural topologies and rearrangement mechanisms in clusters of dipolar particles  

E-Print Network [OSTI]

Clusters of spherical particles with isotropic attraction favour compact structures that maximise the number of energetically optimal nearest-neighbour interactions. In contrast, dipolar interactions lead to the formation of chains with a low coordination number. When both isotropic and dipolar interactions are present, the competition between them can lead to intricate knot, link and coil structures. Here, we investigate how these structures may self-organise and interconvert in clusters bound by the Stockmayer potential (Lennard-Jones plus point dipole). We map out the low-lying region of the energy landscape using disconnectivity graphs to follow how it evolves as the strength of the dipolar interactions increases. From comprehensive surveys of isomerisation pathways, we identify a number of rearrangement mechanisms that allow the topology of chain-like structures to interconvert.

James D. Farrell; Christabel Lines; James J. Shepherd; Dwaipayan Chakrabarti; Mark A. Miller; David J. Wales

2013-04-29T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

CuAl{sub 2} revisited: Composition, crystal structure, chemical bonding, compressibility and Raman spectroscopy  

SciTech Connect (OSTI)

The structure of CuAl{sub 2} is usually described as a framework of base condensed tetragonal antiprisms [CuAl{sub 8/4}]. The appropriate symmetry governed periodic nodal surface (PNS) divides the space of the structure into two labyrinths. All atoms are located in one labyrinth, whereas the second labyrinth seems to be 'empty'. The bonding of the CuAl{sub 2} structure was analyzed by the electron localization function (ELF), crystal orbital Hamiltonian population (COHP) analysis and Raman spectroscopy. From the ELF representation it is seen, that the 'empty' labyrinth is in fact the place of important covalent interactions. ELF, COHP in combination with high-pressure X-ray diffraction and Raman spectroscopy show that the CuAl{sub 2} structure is described best as a network built of interpenetrating graphite-like nets of three-bonded aluminum atoms with the copper atoms inside the tetragonal-antiprismatic cavities. - Graphical abstract: Atomic interactions in the crystal structure of the intermetallic compound CuAl{sub 2}: Three-bonded aluminum atoms form interpenetrating graphite-like nets. The copper atoms are located in the channels of aluminum network by means of three-center bonds. The bonding model is in agreement with the result of polarized Raman spectroscopy and high-pressure X-ray powder diffraction.

Grin, Yuri [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany)]. E-mail: grin@cpfs.mpg.de; Wagner, Frank R. [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Armbruester, Marc [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Kohout, Miroslav [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Leithe-Jasper, Andreas [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Schwarz, Ulrich [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany); Wedig, Ulrich [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, 70569 Stuttgart (Germany); Georg von Schnering, Hans [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, 70569 Stuttgart (Germany)

2006-06-15T23:59:59.000Z

122

Construction of chiral trifluoromethylated materials by combination of stereochemically predictable SN2? reaction and Ireland-Claisen rearrangement  

Science Journals Connector (OSTI)

We have succeeded in establishment of a novel route for the construction of optically active CF3-containing carboxylic acids in a stereochemically predictable manner starting from easily available mandelic acid by convenient combination of the copper-mediated anti-SN2? type substitution and Ireland-Claisen rearrangement.

Tomoaki Ichikawa; Tomoko Kawasaki-Takasuka; Shigeyuki Yamada; Takashi Yamazaki; Toshio Kubota

2013-01-01T23:59:59.000Z

123

Bond Strength of Grade 100 Reinforcing Steel  

E-Print Network [OSTI]

The bond strength of Grade 100 ASTM A 1035 reinforcing steel manufactured by MMFX Technologies Corp. is evaluated with respect to bond strength equations found in ACI 318-05 and ACI 408R-03. Test specimens are fullscale beam-splice specimens tested...

Miller, Shelby

2007-12-14T23:59:59.000Z

124

Channel Bonding in Cognitive Radio Wireless Sensor Networks  

E-Print Network [OSTI]

including, environmental monitoring, home automation, tracking, health care, just to name a few. Another. Moreover, WMSN have a lot of new po- tential applications, such as, environmental monitoring, home automation, tracking, surveillance, and hospital environment applications [2]. However, there are several

Paris-Sud XI, Université de

125

Investigation of electrostatics in a hydogen bond network  

E-Print Network [OSTI]

('ormed with the DNA. There is large-scale growth of the cells, and finally the cells are harvested for the protein of intcrcst. In the second general step, the protein is purified, first on an ion exchange column (separation based on anion exchange) and then by gel... plasmid. Once the miniprep is completed, an agarose gel is run on the sample collected to verify that indeed a piece of DNA has been isolated. If the agarose gel verifies that DNA was isolated, then a sample of thc DNA is sent to the Gene...

Uddin, Fatema Sultana

2013-02-22T23:59:59.000Z

126

Network Maps  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fasterdata IPv6 Network Network Performance Tools The ESnet Engineering Team Network R&D Overview Experimental Network Testbeds Performance (perfSONAR) Software & Tools...

127

Effect of nanoscale surface roughness on the bonding energy of direct-bonded silicon wafers  

Science Journals Connector (OSTI)

Direct wafer bonding of silicon wafers is a promising technology for manufacturing three-dimensional complex microelectromechanical systems as well as silicon-on-insulator substrates. Previous work has reported that the bond quality declines with increasing surface roughness however this relationship has not been quantified. This article explicitly correlates the bond quality which is quantified by the apparent bonding energy and the surface morphology via the bearing ratio which describes the area of surface lying above a given depth. The apparent bonding energy is considered to be proportional to the real area of contact. The effective area of contact is defined as the area sufficiently close to contribute to the attractive force between the two bonding wafers. Experiments were conducted with silicon wafers whose surfaces were roughened by a buffered oxide etch solution (BOE HF:NH 4 F =1:7) and/or a potassium hydroxide solution. The surface roughness was measured by atomic force microscopy. The wafers were direct bonded to polished “monitor” wafers following a standard RCA cleaning and the resulting bonding energy was measured by the crack-opening method. The experimental results revealed a clear correlation between the bonding energy and the bearing ratio. A bearing depth of ?1.4 nm was found to be appropriate for the characterization of direct-bonded silicon at room temperature which is consistent with the thickness of the water layer at the interface responsible for the hydrogen bonds that link the mating wafers.

N. Miki; S. M. Spearing

2003-01-01T23:59:59.000Z

128

Solving the Mystery of the Billion-Dollar Bond, Double Bond | Department of  

Broader source: Energy.gov (indexed) [DOE]

Solving the Mystery of the Billion-Dollar Bond, Double Bond Solving the Mystery of the Billion-Dollar Bond, Double Bond Solving the Mystery of the Billion-Dollar Bond, Double Bond October 26, 2011 - 4:56pm Addthis John Shanklin, biochemist at Brookhaven National Laboratory, and Ed Whittle, research assistant in Shanklin's lab, with a fatty acid molecule model and plant seeds and casings in the foreground. | Courtesy of Brookhaven National Laboratory John Shanklin, biochemist at Brookhaven National Laboratory, and Ed Whittle, research assistant in Shanklin's lab, with a fatty acid molecule model and plant seeds and casings in the foreground. | Courtesy of Brookhaven National Laboratory Charles Rousseaux Charles Rousseaux Senior Writer, Office of Science What are the key facts? Understanding how proteins exert precise control over double bond

129

Geometry of hydrogen bonds formed by lipid bilayer nitroxide probes : A high frequency pulsed ENDOR/EPR study.  

SciTech Connect (OSTI)

Solvent effects on magnetic parameters of nitroxide spin labels in combination with side-directed spin-labeling EPR methods provide very useful means for elucidating polarity profiles in lipid bilayers and mapping local electrostatic effects in complex biomolecular systems. One major contributor to these solvent effects is the hydrogen bonds that could be formed between the nitroxide moiety and water and/or the available hydroxyl groups. Here, formation of hydrogen bonds between a lipid bilayer spin probe 5-doxyl stearic acid, 5DSA and hydrogen-bond donors has been studied using high-frequency (HF) pulsed ENDOR and EPR. A hydrogen-bonded deuteron was directly detected in HF ENDOR (130 GHz) spectra of 5DSA dissolved in several deuterated alcohols, while the characteristic signal was absent in nonpolar toluene-d{sub 8}. The length of the hydrogen bond, 1.74 {+-} 0.06 {angstrom}, and its geometry were found to be essentially the same for all four alcohols studied, indicating that nearly identical hydrogen bonds have been formed regardless of the solvent dielectric constant. This strengthens a hypothesis that HF EPR spectra are exclusively sensitive to formation of hydrogen bonds and could be used for probing the hydrogen-bond network in complex biomolecular assemblies and lipid bilayers with site-directed spin-labeling methods.

Smirnova, T. I.; Smirnov, A. I.; Pachtchenko, S.; Poluektov, O. G.; Chemistry; North Carolina State Univ.

2007-01-01T23:59:59.000Z

130

Determinants of bond market development in Asia  

Science Journals Connector (OSTI)

One of the major reasons behind the Asian financial crisis in 1997 was the excessive dependence of the Asian economies on commercial banks for domestic financing. The region failed to diversify its sources of corporate financing as it relied mainly on banks since its other types of financing, namely bond markets, were still underdeveloped and their sizes were quite small. On the other hand, the 2008 global financial crisis and the ongoing European debt crisis have led to constraints in acquiring local currency and foreign currency liquidity in the corporate sector in Asia as foreign banks withdrew investments from Asia. Furthermore, Asia needs large long term capital (US$ 750 billion per year for 2010–2020) for developing infrastructure connectivity within and across its economies. Local and regional capital can be channeled for long-term infrastructure projects and other productive investment through bond markets. Having a well-developed local currency bond markets can enhance the resilience of domestic financial sector to external shocks and it can facilitate better intermediation of savings into productive investments in Asia. To enhance corporate bond financing, it is important to examine factors that affect the effective development of bond markets in Asia. The study attempts to identify the determinants of bond market development in Asian economies through examining the relationship of bond issuance with selected key financial and economic factors. It also intends to provide policy recommendations for the further development of the Asian bond market. Major determinants for bond market development in Asia include the size of an economy, the stage of economic development, the openness of an economy, the exchange rate variability, the size of the banking system, and interest rate variability.

Biswa Nath Bhattacharyay

2013-01-01T23:59:59.000Z

131

Process Of Bonding Copper And Tungsten  

DOE Patents [OSTI]

Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by sintering a stack of individual copper and tungsten powder blend layers having progressively higher copper content/tungsten content, by volume, ratio values in successive powder blend layers in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO); Davis, John W. (Ballwin, MO)

2000-07-18T23:59:59.000Z

132

Tubulin bond energies and microtubule biomechanics determined from nanoindentation in silico  

E-Print Network [OSTI]

Microtubules, the primary components of the chromosome segregation machinery, are stabilized by longitudinal and lateral non-covalent bonds between the tubulin subunits. However, the thermodynamics of these bonds and the microtubule physico-chemical properties are poorly understood. Here, we explore the biomechanics of microtubule polymers using multiscale computational modeling and nanoindentations in silico of a contiguous microtubule fragment. A close match between the simulated and experimental force-deformation spectra enabled us to correlate the microtubule biomechanics with dynamic structural transitions at the nanoscale. Our mechanical testing revealed that the compressed MT behaves as a system of rigid elements interconnected through a network of lateral and longitudinal elastic bonds. The initial regime of continuous elastic deformation of the microtubule is followed by the transition regime, during which the microtubule lattice undergoes discrete structural changes, which include first the reversib...

Kononova, Olga; Theisen, Kelly E; Marx, Kenneth A; Dima, Ruxandra I; Ataullakhanov, Fazly I; Grishchuk, Ekaterina L; Barsegov, Valeri

2015-01-01T23:59:59.000Z

133

Municipal Bond - Power Purchase Agreement Model Continues to...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Municipal Bond - Power Purchase Agreement Model Continues to Provide Low-Cost Solar Energy Municipal Bond - Power Purchase Agreement Model Continues to Provide Low-Cost Solar...

134

Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with covalently-bound hexafluoroisopropanol groups. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

135

Atomistic modeling of amorphous silicon carbide using a bond...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

modeling of amorphous silicon carbide using a bond-order potential. Atomistic modeling of amorphous silicon carbide using a bond-order potential. Abstract: Molecular dynamics...

136

Bond Energies in Models of the Schrock Metathesis Catalyst. ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energies in Models of the Schrock Metathesis Catalyst. Bond Energies in Models of the Schrock Metathesis Catalyst. Abstract: Heats of formation, adiabatic and diabatic bond...

137

Atoms in Valence Bond. Method, implementation and application.  

E-Print Network [OSTI]

??The Atoms in Valence Bond (AiVB) approach is presented. The main goal was to develop a new and innovative approach, within the existing Valence Bond… (more)

Zielinski, M.L.

2012-01-01T23:59:59.000Z

138

Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues. Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues....

139

IRS Announces New Tribal Economic Development Bond Allocation...  

Broader source: Energy.gov (indexed) [DOE]

IRS Announces New Tribal Economic Development Bond Allocation Guidance IRS Announces New Tribal Economic Development Bond Allocation Guidance July 18, 2012 - 3:46pm Addthis To...

140

Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

142

International political risk and government bond pricing  

Science Journals Connector (OSTI)

Abstract This paper investigates the impact of international political risk on government bond yields in 34 debtor countries using a comprehensive database of 109 international political crises from 1988 through 2007. After employing the total number of international political crises as a proxy for political risk and controlling for country-specific economic conditions, we establish a positive and significant link between international political risk and government bond yields. This is consistent with global bond investors demanding higher returns at times of high political uncertainty. In addition, we show that international political risk has a reduced adverse effect on bond prices when the debtor country has a stable political system and strong investor protection.

Tao Huang; Fei Wu; Jing Yu; Bohui Zhang

2014-01-01T23:59:59.000Z

143

Industrial Revenue Bond Program (District of Columbia)  

Broader source: Energy.gov [DOE]

The District provides below market bond financing to lower the costs of borrowing for qualified capital construction and renovation projects. The program is available to non-profits, institutions,...

144

Chromosome-Specific Staining To Detect Genetic Rearrangements Associated With Chromosome 3 And/Or Chromosone 17  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ nucleic acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyses. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML), retinoblastoma, ovarian and uterine cancers, and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray; Joe W. (Livermore, CA); Pinkel; Daniel (Walnut Creek, CA); Kallioniemi; Olli-Pekka (Tampere, FI); Kallioniemi; Anne (Tampere, FI); Sakamoto; Masaru (Tokyo, JP)

2002-02-05T23:59:59.000Z

145

Chromosome-specific staining to detect genetic rearrangements associated with chromosome 3 and/or chromosome 17  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ nucleic acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyses. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML), retinoblastoma, ovarian and uterine cancers, and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray, Joe W. (San Francisco, CA); Pinkel, Daniel (Lafayette, CA); Kallioniemi, Olli-Pekka (Turku, FI); Kallioniemi, Anne (Tampere, FI); Sakamoto, Masaru (Tokyo, JP)

2008-09-09T23:59:59.000Z

146

Chromosome-specific staining to detect genetic rearrangements associated with chromosome 3 and/or chromosome 17  

DOE Patents [OSTI]

Methods and compositions for staining based upon nucleic acid sequence that employ nudeic acid probes are provided. Said methods produce staining patterns that can be tailored for specific cytogenetic analyses. Said probes are appropriate for in situ hybridization and stain both interphase and metaphase chromosomal material with reliable signals. The nucleic acid probes are typically of a complexity greater than 50 kb, the complexity depending upon the cytogenetic application. Methods and reagents are provided for the detection of genetic rearrangements. Probes and test kits are provided for use in detecting genetic rearrangements, particularly for use in tumor cytogenetics, in the detection of disease related loci, specifically cancer, such as chronic myelogenous leukemia (CML), retinoblastoma, ovarian and uterine cancers, and for biological dosimetry. Methods and reagents are described for cytogenetic research, for the differentiation of cytogenetically similar but genetically different diseases, and for many prognostic and diagnostic applications.

Gray, Joe W. (Livermore, CA); Pinkel, Daniel (Walnut Creek, CA); Kallioniemi, Olli-Pekka (Tampere, FI); Kallioniemi, Anne (Tampere, FI); Sakamoto, Masaru (Tokyo, JP)

2002-01-01T23:59:59.000Z

147

Characterization of an explosively bonded aluminum proton beam window for the Spallation Neutron Source  

SciTech Connect (OSTI)

An effort is underway at the Spallation Neutron Source (SNS) to change the design of the 1st Generation high-nickel alloy proton beam window (PBW) to one that utilizes aluminum for the window material. One of the key challenges to implementation of an aluminum PBW at the SNS was selection of an appropriate joining method to bond an aluminum window to the stainless steel bulk shielding of the PBW assembly. An explosively formed bond was selected as the most promising joining method for the aluminum PBW design. A testing campaign was conducted to evaluate the strength and efficacy of explosively formed bonds that were produced using two different interlayer materials: niobium and titanium. The characterization methods reported here include tensile testing, thermal-shock leak testing, optical microscopy, and advanced scanning electron microscopy. All tensile specimens examined failed in the aluminum interlayer and measured tensile strengths were all slightly greater than the native properties of the aluminum interlayer, while elongation values were all slightly lower. A leak developed in the test vessel with a niobium interlayer joint after repeated thermal-shock cycles, and was attributed to an extensive crack network that formed in a layer of niobium-rich intermetallics located on the bond interfaces of the niobium interlayer; the test vessel with a titanium interlayer did not develop a leak under the conditions tested. Due to the experience gained from these characterizations, the explosively formed bond with a titanium interlayer was selected for the aluminum PBW design at the SNS.

McClintock, David A [ORNL] [ORNL; Janney, Jim G [ORNL] [ORNL; Parish, Chad M [ORNL] [ORNL

2014-01-01T23:59:59.000Z

148

Metal-and hydrogen-bonding competition during water absorption on Pd(111) and Ru(0001)  

SciTech Connect (OSTI)

The initial stages of water adsorption on the Pd(111) and Ru(0001) surfaces have been investigated experimentally by Scanning Tunneling Microscopy in the temperature range between 40 K and 130 K, and theoretically with Density Functional Theory (DFT) total energy calculations and STM image simulations. Below 125 K water dissociation does not occur at any appreciable rate and only molecular films are formed. Film growth starts by the formation of flat hexamer clusters where the molecules bind to the metal substrate through the O-lone pair while making H-bonds with neighboring molecules. As coverage increases, larger networks of linked hexagons are formed with a honeycomb structure, which requires a fraction of the water molecules to have their molecular plane perpendicular to the metal surface with reduced water-metal interaction. Energy minimization favors the growth of networks with limited width. As additional water molecules adsorb on the surface they attach to the periphery of existing islands, where they interact only weakly with the metal substrate. These molecules hop along the periphery of the clusters at intermediate temperatures. At higher temperatures they bind to the metal to continue the honeycomb growth. The water-Ru interaction is significantly stronger than the water-Pd interaction, which is consistent with the greater degree of hydrogen-bonded network formation and reduced water-metal bonding observed on Pd relative to Ru.

Tatarkhanov, Mouslim; Ogletree, D. Frank; Rose, Franck; Mitsui, Toshiyuki; Fomin, Evgeny; Rose, Mark; Cerda, Jorge I.; Salmeron, Miquel

2009-09-03T23:59:59.000Z

149

Qualified Energy Conservation Bond State-by-State Summary Tables  

Broader source: Energy.gov [DOE]

Provides a list of qualified energy conservation bond state summary tables. Author: Energy Programs Consortium

150

Discrete Element Modeling Results of Proppant Rearrangement in the Cooke Conductivity Cell  

SciTech Connect (OSTI)

The study of propped fracture conductivity began in earnest with the development of the Cooke cell which later became part of the initial API standard. Subsequent developments included a patented multicell design to conduct 4 tests in a press at the same time. Other modifications have been used by various investigators. Recent studies by the Stim-Lab proppant consortium have indicated that the flow field across a Cooke proppant conductivity testing cell may not be uniform as initially believed which resulted is significantly different conductivity results. Post test analysis of low temperature metal alloy injections at the termination of proppant testing prior to the release of the applied stress suggest that higher flow is to be expected along the sides and top of the proppant pack than compared to the middle of the pack. To evaluate these experimental findings, a physics-based two-dimensional (2-D) discrete element model (DEM) was developed and applied to simulate proppant rearrangement during stress loading in the Cooke conductivity cell and the resulting porosity field. Analysis of these simulations are critical to understanding the impact of modification to the testing cell as well as understanding key proppant conductivity issues such as how these effects are manifested in proppant concentration testing results. The 2-D DEM model was constructed to represent a realistic cross section of the Cooke cell with a distribution of four material properties, three that represented the Cooke cell (steel, sandstone,square rings), and one representing the proppant. In principle, Cooke cell materials can be approximated as assemblies of independent discrete elements (particles) of various sizes and material properties that interact via cohesive interactions, repulsive forces, and frictional forces. The macroscopic behavior can then be modeled as the collective behavior of many interacting discrete elements. This DEM model is particularly suitable for modeling proppant mechanical interactions subjected to an applied stress, where the experimental cell is represented as a cohesive body composed of a large number of discrete elements, and proppants can be modeled as the individual discrete particles with various sizes (following the proppant size distribution-density function used in the test) that exhibit no cohesive strength between the particles. Initial 2-D DEM modeling results suggest that proppant rearrangement and non-uniform stress distribution across the proppant pack results in significant non-uniform porosity distribution across the Cooke cell. Larger porosities develop along the edge of the proppant pack beneath the square ring seal and would result in a disproportionate higher flow field along these edges as compared to the middle of the proppant pack. These results suggest that reported conductivity values determined by the Cooke cell may be biased to overestimate the actual conductivity of the proppant at high stresses and that modifications to the standard Cooke cell will affect the magnitude of this bias.

Earl Mattson; Hai Huang; Michael Conway; Lisa O'Connell

2014-02-01T23:59:59.000Z

151

Qualified Energy Conservation Bond (QECB) Update: New  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

8, 2012 8, 2012 Qualified Energy Conservation Bond (QECB) Update: New Guidance from the U.S. Department of Treasury and the Internal Revenue Service Qualified Energy Conservation Bonds (QECBs) are federally-subsidized bonds that enable state, tribal, and local government issuers to borrow money to fund a range of energy conservation projects at very attractive borrowing rates over long contract terms. In June 2012, the U.S. Department of the Treasury (Treasury) and the Internal Revenue Service (IRS) published a notice to clarify what constitutes a qualified project for potential issuers of the approximately $2.5 billion of remaining QECB issuance capacity. The guidance addresses two qualified uses of QECB proceeds-how issuers should measure energy use reductions in publicly-owned buildings and what constitutes a green community program.

152

Bonded ultrasonic transducer and method for making  

DOE Patents [OSTI]

An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements. 12 figs.

Dixon, R.D.; Roe, L.H.; Migliori, A.

1995-11-14T23:59:59.000Z

153

Epoxy bond and stop etch fabrication method  

DOE Patents [OSTI]

A class of epoxy bond and stop etch (EBASE) microelectronic fabrication techniques is disclosed. The essence of such techniques is to grow circuit components on top of a stop etch layer grown on a first substrate. The first substrate and a host substrate are then bonded together so that the circuit components are attached to the host substrate by the bonding agent. The first substrate is then removed, e.g., by a chemical or physical etching process to which the stop etch layer is resistant. EBASE fabrication methods allow access to regions of a device structure which are usually blocked by the presence of a substrate, and are of particular utility in the fabrication of ultrafast electronic and optoelectronic devices and circuits.

Simmons, Jerry A. (Sandia Park, NM); Weckwerth, Mark V. (Pleasanton, CA); Baca, Wes E. (Albuquerque, NM)

2000-01-01T23:59:59.000Z

154

Bonded ultrasonic transducer and method for making  

DOE Patents [OSTI]

An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements.

Dixon, Raymond D. (Los Alamos, NM); Roe, Lawrence H. (Los Alamos, NM); Migliori, Albert (Santa Fe, NM)

1995-01-01T23:59:59.000Z

155

Process Of Bonding Copper And Tungsten  

DOE Patents [OSTI]

Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by thermal plasma spraying mixtures of copper powder and tungsten powder in a varied blending ratio such that the blending ratio of the copper powder and the tungsten powder that is fed to a plasma torch is intermittently adjusted to provide progressively higher copper content/tungsten content, by volume, ratio values in the interlayer in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO)

1999-11-23T23:59:59.000Z

156

Adhesive bonding using variable frequency microwave energy  

DOE Patents [OSTI]

Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy.

Lauf, Robert J. (Oak Ridge, TN); McMillan, April D. (Knoxville, TN); Paulauskas, Felix L. (Oak Ridge, TN); Fathi, Zakaryae (Cary, NC); Wei, Jianghua (Raleigh, NC)

1998-01-01T23:59:59.000Z

157

Adhesive bonding using variable frequency microwave energy  

DOE Patents [OSTI]

Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

1998-09-08T23:59:59.000Z

158

Adhesive bonding using variable frequency microwave energy  

DOE Patents [OSTI]

Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

1998-08-25T23:59:59.000Z

159

Rings in central-force network dynamics  

Science Journals Connector (OSTI)

The central-force network dynamics model for glasses is extended to treat networks involving small regular rings of bonds. In particular, band-limit formulas are obtained for an A2X3 glass consisting of regular puckered six-membered A3X3 rings. The special case of planar rings is compared with observations on vitreous B2O3. This continuous random network of "boroxol" rings shows improved agreement with experiment over a model not containing rings. The remaining discrepancies illustrate the need to include noncentral forces in the network dynamics of v-B2O3.

F. L. Galeener and M. F. Thorpe

1983-11-15T23:59:59.000Z

160

Charge rearrangement by sprites over a north Texas mesoscale convective system  

E-Print Network [OSTI]

is called a "K-change" when it is observed in a lightning flash. Citation: Hager, W. W., R. G. Sonnenfeld, W of the sprites. Data from the National Lightning Detection Network (NLDN) show that each sprite was preceded] that sprites were often preceded by large, positive cloud-to-ground lightning strokes (+CGs). Previously

Cummer, Steven A.

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Bond Underwriter Costs: Texas School Districts and the Hidden Cost of Issuing Bonds  

E-Print Network [OSTI]

dramatically across Texas school districts, both in total and as a percentage of the total amount borrowed. As an example, in 2008 Alto ISD issued $6.3 million in bonds and Glen Rose ISD borrowed $6.2 million. The underwriter for Glen Rose earned $38...,936 in fees; the underwriter on the Alto deal earned $193,712, nearly five times that amount. On a per bond basis, Glen Rose paid .628%, while Alto paid more than 3%. An examination of bond issues across the state demonstrates similar variations...

Stasny, Mary Knetsar

2011-02-22T23:59:59.000Z

162

Tax-Exempt Industrial Revenue Bonds (Kansas) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Industrial Revenue Bonds (Kansas) Industrial Revenue Bonds (Kansas) Tax-Exempt Industrial Revenue Bonds (Kansas) < Back Eligibility Agricultural Commercial Construction Industrial Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Kansas Program Type Bond Program Provider Revenue Tax-Exempt Industrial Revenue Bonds are issued by cities and counties for the purchase, construction, improvement or remodeling of a facility for agricultural, commercial, hospital, industrial, natural resources, recreational development or manufacturing purposes. The board of county commissioners of any county or the governing body of any city may approve an exemption of property funded by industrial revenue bonds (IRB's). Some

163

Dynamic force spectroscopy on multiple bonds: experiments and model  

E-Print Network [OSTI]

We probe the dynamic strength of multiple biotin-streptavidin adhesion bonds under linear loading using the biomembrane force probe setup for dynamic force spectroscopy. Measured rupture force histograms are compared to results from a master equation model for the stochastic dynamics of bond rupture under load. This allows us to extract the distribution of the number of initially closed bonds. We also extract the molecular parameters of the adhesion bonds, in good agreement with earlier results from single bond experiments. Our analysis shows that the peaks in the measured histograms are not simple multiples of the single bond values, but follow from a superposition procedure which generates different peak positions.

T. Erdmann; S. Pierrat; P. Nassoy; U. S. Schwarz

2007-12-18T23:59:59.000Z

164

Private Activity Bond Allocation (Missouri) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bond Allocation (Missouri) Bond Allocation (Missouri) Private Activity Bond Allocation (Missouri) < Back Eligibility Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative Systems Integrator Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Maximum Rebate Total Program Cap 2012: $571,015,360 Program Info State Missouri Program Type Bond Program Provider Missouri Department of Economic Development The Private Activity Bond Allocation Program provides low-interest financing through tax-exempt bonds for certain types of projects, including electric and gas utility projects. Eligible applicants include certain state agencies, cities, counties and industrial development authorities

165

Lattice-Mismatched GaAs/InGaAs Two-Junction Solar Cells by Direct Wafer Bonding  

SciTech Connect (OSTI)

Direct bonded interconnect between subcells of a lattice-mismatched III-V compound multijunction cell would enable dislocation-free active regions by confining the defect network needed for lattice mismatch accommodation to tunnel junction interfaces, while metamorphic growth inevitably results in less design flexibility and lower material quality than is desirable. The first direct-bond interconnected multijunction solar cell, a two-terminal monolithic GaAs/InGaAs two-junction solar cell, is reported and demonstrates viability of direct wafer bonding for solar cell applications. The tandem cell open-circuit voltage was approximately the sum of the subcell open-circuit voltages. This achievement shows direct bonding enables us to construct lattice-mismatched III-V multijunction solar cells and is extensible to an ultrahigh efficiency InGaP/GaAs/InGaAsP/InGaAs four-junction cell by bonding a GaAs-based lattice-matched InGaP/GaAs subcell and an InP-based lattice-matched InGaAsP/InGaAs subcell. The interfacial resistance experimentally obtained for bonded GaAs/InP smaller than 0.10 Ohm-cm{sup 2} would result in a negligible decrease in overall cell efficiency of {approx}0.02%, under 1-sun illumination.

Tanabe, K.; Aiken, D. J.; Wanlass, M. W.; Morral, A. F.; Atwater, H. A.

2006-01-01T23:59:59.000Z

166

Elongation of Axolotl Tailbud Embryos Requires GPI-Linked Proteins and Organizer-Induced, Active, Ventral Trunk Endoderm Cell Rearrangements  

Science Journals Connector (OSTI)

Application of phosphatidylinositol-specific phospholipase C to early tailbud stage axolotl embryos reveals that a specific subset of morphogenetic movements requires glycosylphosphatidylinositol (GPI)-linked cell-surface proteins. These include pronephric duct extension, “gill bulge” formation, and embryonic elongation along the anteroposterior axis. The work of Kitchin (1949, J. Exp. Zool. 112, 393–416) led to the conclusion that extension of the notochord provided the motive force driving anteroposterior stretching in axolotl embryos, elongation of other tissues being a passive response. We therefore conjectured that axial mesoderm cells might display the GPI-linked proteins required for elongation of the embryo. However, we show here that removal of most of the neural plate and axial and paraxial mesoderm prior to neural tube closure does not prevent elongation of ventrolateral tissues. Tissue-extirpation and tissue-marking experiments indicate that elongation of the ventral trunk occurs via active, directed tissue rearrangements within the endoderm, directed by signals emanating from the blastopore region. Extension of both dorsal and ventral tissues requires GPI-linked proteins. We conclude that elongation of axolotl embryos requires active cell rearrangements within ventral as well as axial tissues. The fact that both types of elongation are prevented by removal of GPI-linked proteins implies that they share a common molecular mechanism.

Julie Drawbridge; Malcolm S. Steinberg

2000-01-01T23:59:59.000Z

167

Local Government Revenue Bonds (Montana) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Government Revenue Bonds (Montana) Government Revenue Bonds (Montana) Local Government Revenue Bonds (Montana) < Back Eligibility Utility Commercial Investor-Owned Utility Municipal/Public Utility Local Government Rural Electric Cooperative Tribal Government Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Montana Program Type Bond Program Provider Any interested county or municipality. Limited obligation local government bonds ("special revenue bonds") may be issued for qualified electric energy generation facilities, including those powered by renewables. These bonds generally are secured by the project itself. The taxing power or general credit of the government may not be used to secure the bonds. Local governments may not operate any project

168

Major Business Expansion Bond Program (Maine) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Expansion Bond Program (Maine) Expansion Bond Program (Maine) Major Business Expansion Bond Program (Maine) < Back Eligibility Commercial Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Maine Program Type Bond Program Provider Finance Authority of Maine The Major Business Expansion Bond Program provides long-term, credit-enhanced financing up to $25,000,000 at taxable bond rates for businesses creating or retaining at least 50 jobs; up to $10,000,000 is available for businesses which expand their manufacturing services. The bond proceeds may be used to acquire real estate, machinery, equipment, or rehabilitate or expand an existing facility. The interest rate is determined by market forces at the time of the bond sale

169

Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

170

Ge-Au eutectic bonding of Ge {100} single crystals  

Science Journals Connector (OSTI)

We present preliminary results on the eutectic bonding between two {100} Ge single crystal surfaces using thin films of ... Au sample show epitaxial growth of Ge. In sections of the bond, lattice continuity...

W. B. Knowlton; K. M. Itoh; J. W. Beeman; J. H. Emes…

1993-11-01T23:59:59.000Z

171

Pooled Bond Program (South Dakota) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Pooled Bond Program (South Dakota) Pooled Bond Program (South Dakota) Pooled Bond Program (South Dakota) < Back Eligibility Commercial Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State South Dakota Program Type Bond Program Provider South Dakota Governor's Office of Economic Development The Pooled Bond Program offered by the Economic Development Finance Authority is designed for capital intensive projects, providing small businesses access to larger capital markets for tax-exempt or taxable bond issuances. Bond proceeds can be used to finance 80 percent of new construction, and 75 percent of new equipment costs, with no greater than 25 percent of the bond proceeds being used for ancillary activities such as

172

Industrial Revenue Bond Issuance Cost Assistance (Wisconsin) | Department  

Broader source: Energy.gov (indexed) [DOE]

Revenue Bond Issuance Cost Assistance (Wisconsin) Revenue Bond Issuance Cost Assistance (Wisconsin) Industrial Revenue Bond Issuance Cost Assistance (Wisconsin) < Back Eligibility Local Government Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Wind Solar Program Info State Wisconsin Program Type Bond Program Provider Wisconsin Economic Development Corporation Industrial Revenue Bonds (IRB) are tax-exempt bonds that can be used to stimulate capital investment and job creation by providing private borrowers with access to financing at interest rates that are lower than conventional bank loans. The IRB process involves five separate entities - the borrower, lender, bond attorney, issuer, and WEDC. WEDC allocates the bonding authority or the volume cap for the program under Wis. Stat. §

173

Article coated with flash bonded superhydrophobic particles  

DOE Patents [OSTI]

A method of making article having a superhydrophobic surface includes: providing a solid body defining at least one surface; applying to the surface a plurality of diatomaceous earth particles and/or particles characterized by particle sizes ranging from at least 100 nm to about 10 .mu.m, the particles being further characterized by a plurality of nanopores, wherein at least some of the nanopores provide flow through porosity, the particles being further characterized by a plurality of spaced apart nanostructured features that include a contiguous, protrusive material; flash bonding the particles to the surface so that the particles are adherently bonded to the surface; and applying a hydrophobic coating layer to the surface and the particles so that the hydrophobic coating layer conforms to the nanostructured features.

Simpson, John T (Clinton, TN) [Clinton, TN; Blue, Craig A (Knoxville, TN) [Knoxville, TN; Kiggans, Jr., James O [Oak Ridge, TN

2010-07-13T23:59:59.000Z

174

Definition: Cement Bond Log | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Cement Bond Log Jump to: navigation, search Dictionary.png Cement Bond Log A representation of the integrity of the cement job, especially whether the cement is adhering solidly to the outside of the casing. The log is typically obtained from one of a variety of sonic-type tools. The newer versions, called cement evaluation logs, along with their processing software, can give detailed, 360-degree representations of the integrity of the cement job, whereas older versions may display a single line representing the integrated integrity around the casing.[1] Related Terms Acoustic Logs References ↑ Schlumberger Oilfield Glossary Ret LikeLike UnlikeLike You like this.Sign Up to see what your friends like.

175

A New Hydrogen Bond in Coal  

Science Journals Connector (OSTI)

During our study on hydrogen bond in coal by diffuse reflectance IR, we found that a weak peak at 2514 cm-1 always occurred for some coals. ... Infrared absorption spectra of coals and coal extracts ... The FTIR spectra during the heat-up of eight coals (seven Argonne premium coals and an Australian brown coal), an ion-exchange resin, and a lignin were measured every 20 °C from room temp. ...

Dongtao Li; Wen Li; Baoqing Li

2003-04-30T23:59:59.000Z

176

Effects of Bond Stretching on Polymer Statistics  

Science Journals Connector (OSTI)

Effects of Bond Stretching on Polymer Statistics ... When a system becomes strained, longer chain end-to-end separations become more probable and the assumptions that go into the Gaussian chain model are no longer valid. ... The associated probability distribution attaches too much weight to the probabilities at larger end-to-end separations, and a statistical analysis based on this distribution would unrealistically overemphasize the contributions of these longer chains. ...

Gary G. Hoffman

1999-08-10T23:59:59.000Z

177

Bonding on the corrugator; The energy aspects  

SciTech Connect (OSTI)

This paper discusses what new features are needed on the corrugator of the future. The author analyzes trends in the industry of the last 15-20 years. The trends point to more automation and more process and quality control, but new designs will react to new market needs such as just-in-time production and product flexibility. In this paper, the author focuses on the bonding process.

Bradatsch, E. (BHS-Werk Weiherhammer, D-8481 Weiherhammer (DE))

1990-01-01T23:59:59.000Z

178

Cement Bond Log | Open Energy Information  

Open Energy Info (EERE)

Cement Bond Log Cement Bond Log Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Cement Bond Log Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Downhole Techniques Exploration Sub Group: Well Log Techniques Parent Exploration Technique: Acoustic Logs Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Cost Information Low-End Estimate (USD): 0.8585 centUSD 8.5e-4 kUSD 8.5e-7 MUSD 8.5e-10 TUSD / foot Median Estimate (USD): 1.25125 centUSD 0.00125 kUSD 1.25e-6 MUSD 1.25e-9 TUSD / foot High-End Estimate (USD): 3.00300 centUSD 0.003 kUSD 3.0e-6 MUSD 3.0e-9 TUSD / foot Time Required Low-End Estimate: 0.35 days9.582478e-4 years 8.4 hours 0.05 weeks 0.0115 months / job

179

Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang*  

E-Print Network [OSTI]

Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang* Department of Biochemistry, University of Zurich, Zurich, Switzerland Abstract Ligand binding involves breakage of hydrogen bonds with water molecules and formation of new hydrogen bonds between protein and ligand. In this work, the change

Caflisch, Amedeo

180

Analysis of C H...O hydrogen bonds  

E-Print Network [OSTI]

1 Analysis of C H...O hydrogen bonds in high resolution protein crystal structures from the PDB 1.4 Identification of C-H...O hydrogen bonds............................................. 1.4.1 The definition of a C-H...O hydrogen bond.................................... 1.4.2 Fixing the hydrogen and measuring the parameters

Babu, M. Madan

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Oil prices and government bond risk premiums Herv Alexandre*  

E-Print Network [OSTI]

Oil prices and government bond risk premiums By Hervé Alexandre*º Antonin de Benoist * Abstract : This article analyses the impact of oil price on bond risk premiums issued by emerging economies. No empirical study has yet focussed on the effects of the oil price on government bond risk premiums. We develop

Boyer, Edmond

182

Artificial Neural Networks Single Layer Networks Multi Layer Networks Generalization Artificial Neural Networks  

E-Print Network [OSTI]

Artificial Neural Networks Single Layer Networks Multi Layer Networks Generalization Artificial Neural Networks #12;Artificial Neural Networks Single Layer Networks Multi Layer Networks Generalization 1 Artificial Neural Networks Properties Applications Classical Examples Biological Background 2

Kjellström, Hedvig

183

Artificial Neural Networks Single Layer Networks Multi Layer Networks Generalization Artificial Neural Networks  

E-Print Network [OSTI]

Artificial Neural Networks Single Layer Networks Multi Layer Networks Generalization Artificial Neural Networks Artificial Neural Networks Single Layer Networks Multi Layer Networks Generalization 1 Artificial Neural Networks Properties Applications Classical Examples Biological Background 2 Single Layer

Kjellström, Hedvig

184

Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch  

E-Print Network [OSTI]

Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch K. J. Gaffney, I. R. Piletic, and M. D. Fayer* Department measured with ultrafast infrared pump-probe experiments. Non-hydrogen-bond donating OD stretches (2690 cm-1

Fayer, Michael D.

185

Infinitely robust order and local order-parameter tulips in Apollonian networks with quenched disorder  

E-Print Network [OSTI]

For a variety of quenched random spin systems on an Apollonian network, including ferromagnetic and antiferromagnetic bond percolation and the Ising spin glass, we find the persistence of ordered phases up to infinite ...

Kaplan, C. Nadir

186

Tax-Exempt Bond Financing (Delaware) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bond Financing (Delaware) Bond Financing (Delaware) Tax-Exempt Bond Financing (Delaware) < Back Eligibility Utility Commercial Agricultural Investor-Owned Utility State/Provincial Govt Industrial Construction Municipal/Public Utility Local Government Installer/Contractor Rural Electric Cooperative Tribal Government Retail Supplier Systems Integrator Fuel Distributor Transportation Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Delaware Program Type Bond Program Provider Delaware Economic Development Office The Delaware Economic Development Authority provides tax-exempt bond financing for financial assistance to new or expanding businesses, governmental units and certain organizations that are exempt from federal

187

Bond and Loan Program (Arkansas) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bond and Loan Program (Arkansas) Bond and Loan Program (Arkansas) Bond and Loan Program (Arkansas) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Program Info State Arkansas Program Type Bond Program Loan Program Provider Department of Finance and Administration The Bond and Loan programs of Arkansas are four programs designed to

188

Network Programming 1 Computer Networks  

E-Print Network [OSTI]

Network Programming 1 Computer Networks client/server architecture, protocols, and sockets 2;Network Programming 1 Computer Networks client/server architecture, protocols, and sockets 2 Network;client/server architecture Client/server architecture defines the communication between two computers

Verschelde, Jan

189

Economic Development Bond Program (Iowa) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bond Program (Iowa) Bond Program (Iowa) Economic Development Bond Program (Iowa) < Back Eligibility Agricultural Commercial Industrial Institutional Investor-Owned Utility Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Rural Electric Cooperative Schools Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info Funding Source Iowa Finance Authority State Iowa Program Type Bond Program Provider Iowa Finance Authority Through its Economic Development Bond Program, the Iowa Finance Authority (IFA) issues tax-exempt bonds on behalf of private entities or organizations for eligible purposes. The responsibility for repayment of the bonds rests with the applicant. Neither IFA nor the State of Iowa has

190

Single-Issue Industrial Revenue Bond Program (Missouri) | Department of  

Broader source: Energy.gov (indexed) [DOE]

Single-Issue Industrial Revenue Bond Program (Missouri) Single-Issue Industrial Revenue Bond Program (Missouri) Single-Issue Industrial Revenue Bond Program (Missouri) < Back Eligibility Commercial Construction Industrial Retail Supplier Systems Integrator Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Program Info State Missouri Program Type Bond Program Provider Missouri Development Finance Board The Missouri Development Finance Board administers a Single-Issue Tax-Exempt Industrial Revenue Bond Program as well as a Taxable Industrial Revenue Bond Program. The Tax-Exempt Program finances (i) the acquisition, construction and equipping of qualified manufacturing production facilities and/or equipment, and (ii) refinances outstanding tax-exempt bonds. It

191

Qualified Energy Conservation Bonds (Ohio) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Qualified Energy Conservation Bonds (Ohio) Qualified Energy Conservation Bonds (Ohio) Qualified Energy Conservation Bonds (Ohio) < Back Eligibility Agricultural Institutional Local Government Municipal/Public Utility Rural Electric Cooperative Schools Savings Category Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Ohio Program Type Bond Program Provider Ohio Air Quality Development Authority The Ohio Air Quality Development Authority (OAQDA) administers the Qualified Energy Conservation Bonds (QECB) program in Ohio. QECBs have been used by local governments and public universities to finance the installation of energy conserving equipment in publicly owned buildings. Under a QECB financing package, OAQDA authorizes Air Quality Development Bonds for issuance as a Series A federally tax-exempt bond and a Series B

192

Dual-bonded catalyst layer structure cathode for PEMFC  

Science Journals Connector (OSTI)

Novel electrode structure based on dual-bonded catalyst layer structure is reported to elevate proton exchange membrane fuel cell (PEMFC) cathode performance. Differing from conventional cathode with simplex PTFE or ionomer as binder material in catalyst layer (CL), dual-bonded CL combines those two types of binders, respectively, in a composite structure. In order to develop a cathode possessing the superior merits of both mass transport and proton transfer, a PTFE-rich CL and an ionomer-rich CL were fabricated on gas diffusion layer in proper order. Polarization characteristic of cathodes with dual-bonded CL, conventional PTFE-bonded CL and ionomer-bonded CL were evaluated at ambient pressure in oxygen/air. Better performance of cathode was achieved with dual-bonded, compared with conventional structures. Electric yield rate of dual-bonded cathode was about 50%, whilst that of conventional cathodes was about 40%.

Xuewei Zhang; Pengfei Shi

2006-01-01T23:59:59.000Z

193

Method for bonding a transmission line to a downhole tool  

DOE Patents [OSTI]

An apparatus for bonding a transmission line to the central bore of a downhole tool includes a pre-formed interface for bonding a transmission line to the inside diameter of a downhole tool. The pre-formed interface includes a first surface that substantially conforms to the outside contour of a transmission line and a second surface that substantially conforms to the inside diameter of a downhole tool. In another aspect of the invention, a method for bonding a transmission line to the inside diameter of a downhole tool includes positioning a transmission line near the inside wall of a downhole tool and placing a mold near the transmission line and the inside wall. The method further includes injecting a bonding material into the mold and curing the bonding material such that the bonding material bonds the transmission line to the inside wall.

Hall, David R. (Provo, UT); Fox, Joe (Spanish Fork, UT)

2007-11-06T23:59:59.000Z

194

Ultrasonic evaluation of beryllium-copper diffusion bonds  

SciTech Connect (OSTI)

A study was performed to compare the effectiveness of several advanced ultrasonic techniques when used to determine the strength of diffusion bonded beryllium-copper, which heretofore have each been applied to only a few material systems. The use of integrated backscatter calculations, frequency domain reflection coefficients, and time-of-flight variance was compared in their ability to characterize the bond strength in a series of beryllium-copper diffusion bond samples having a wide variation in bond quality. Correlation of integrated backscatter calculations and time-of-flight variance with bond strength was good. Some correlation of the slope of the frequency based reflection coefficient was shown for medium and high strength bonds, while its Y-intercept showed moderate correlation for all bond strengths.

Jamieson, E.E.

2000-06-08T23:59:59.000Z

195

Protein folding on rugged energy landscapes: Conformational diffusion on fractal networks  

Science Journals Connector (OSTI)

We perform simulations of model proteins to study folding on rugged energy landscapes. We construct “first-passage” networks as the system transitions from unfolded to native states. The nodes and bonds in these networks correspond to basins and transitions between them in the energy landscape. We find power-law relations between the folding time and the number of nodes and bonds. We show that these scalings are determined by the fractal properties of first-passage networks. Thus, we have identified a possible mechanism—the small fractal dimension of first passage networks—which can give rise to reliable folding in proteins with rugged energy landscapes.

Gregg Lois; Jerzy Blawzdziewicz; Corey S. O’Hern

2010-05-06T23:59:59.000Z

196

Protein folding on rugged energy landscapes: Conformational diffusion on fractal networks  

E-Print Network [OSTI]

We employ simulations of model proteins to study folding on rugged energy landscapes. We construct ``first-passage'' networks as the system transitions from unfolded to native states. The nodes and bonds in these networks correspond to basins and transitions between them in the energy landscape. We find power-laws between the folding time and number of nodes and bonds. We show that these scalings are determined by the fractal properties of first-passage networks. Reliable folding is possible in systems with rugged energy landscapes because first passage networks have small fractal dimension.

Gregg Lois; J. Blawzdziewicz; Corey S. O'Hern

2009-06-24T23:59:59.000Z

197

Bond energy effects on strength, cooperativity and robustness of molecular structures  

Science Journals Connector (OSTI)

...robustness at smaller bond energy lower strength at smaller bond energy bond spacing L 0 higher...biology of the cell. New York, NY: Taylor Francis...Cracks and fracture. New York, NY: Academic Press. Bond energy effects on strength...

2011-01-01T23:59:59.000Z

198

Bond selective chemistry beyond the adiabatic approximation  

SciTech Connect (OSTI)

One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

Butler, L.J. [Univ. of Chicago, IL (United States)

1993-12-01T23:59:59.000Z

199

Mechanical modeling of the plastic bonded explosive LX17  

E-Print Network [OSTI]

, . ""Av, dV+ f T, ""dv, dS (44) Which, when rearranged, yields: f iSa?dp?dV = f pf, ""Av, dV+ f T, ""Av, . dS ? f a" Ap?dV 2 Substituting the constitutive equation (42) into (45) yields: 22 f [V ?, . 4, 4 ]G. V dV f=2rG"4 dV f T ddd , ? f ", Gd. d...V (46) 2 Rearranging gives: f C?'?, '~za~pdV=f pfd"AvdV+f T, ""AvdS ? f o", ., ApddV ? f Aa?". Ap?dV (47) G 2 which can be expressed in matrix notation as follows: f ([D][hv] )[C'][D][du]dV= f [Av] pr f""]dV+ f [trav] [T""]dS ? f ([D][Av]')[o "]d...

Clayton, Kyle Martin

2012-06-07T23:59:59.000Z

200

Repairable chip bonding/interconnect process  

DOE Patents [OSTI]

A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder.

Bernhardt, Anthony F. (Berkeley, CA); Contolini, Robert J. (Livermore, CA); Malba, Vincent (Livermore, CA); Riddle, Robert A. (Tracy, CA)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Statistics of modifier distributions in mixed network glasses  

Science Journals Connector (OSTI)

The constituents of any network glass can be broadly classified as either network formers or network modifiers. Network formers such as SiO2 Al2O3 B2O3 P2O5 etc. provide the backbone of the glass network and are the primary source of its rigid constraints. Network modifiers play a supporting role such as charge stabilization of the network formers or alteration of the network topology through rupture of bridging bonds and introduction of floppy modes. The specific role of the modifiers depends on which network formers are present in the glass and the relative free energies of modifier interactions with each type of network former site. This variation of free energy with modifier speciation is responsible for the so-called mixed network former effect i.e. the nonlinear scaling of property values in glasses having fixed modifier concentration but a varying ratio of network formers. In this paper a general theoretical framework is presented describing the statistical mechanics of modifier speciation in mixed network glasses. The model provides a natural explanation for the mixed network former effect and also accounts for the impact of thermal history and relaxation on glass network topology.

John C. Mauro

2013-01-01T23:59:59.000Z

202

Calorimetry of dehydrogenation and dangling-bond recombination in several hydrogenated amorphous silicon materials  

Science Journals Connector (OSTI)

Differential scanning calorimetry (DSC) was used to study the dehydrogenation processes that take place in three hydrogenated amorphous silicon materials: nanoparticles, polymorphous silicon, and conventional device-quality amorphous silicon. Comparison of DSC thermograms with evolved gas analysis (EGA) has led to the identification of four dehydrogenation processes arising from polymeric chains (A), SiH groups at the surfaces of internal voids (A?), SiH groups at interfaces (B), and in the bulk (C). All of them are slightly exothermic with enthalpies below 50meV?(H atoms), indicating that, after dissociation of any SiH group, most dangling bonds recombine. The kinetics of the three low-temperature processes [with DSC peak temperatures at around 320 (A), 360 (A?), and 430°C (B)] exhibit a kinetic-compensation effect characterized by a linear relationship between the activation entropy and enthalpy, which constitutes their signature. Their Si?H bond-dissociation energies have been determined to be E(Si?H)0=3.14 (A), 3.19 (A?), and 3.28eV (B). In these cases it was possible to extract the formation energy E(DB) of the dangling bonds that recombine after Si?H bond breaking [0.97 (A), 1.05 (A?), and 1.12 (B)]. It is concluded that E(DB) increases with the degree of confinement and that E(DB)>1.10eV for the isolated dangling bond in the bulk. After Si?H dissociation and for the low-temperature processes, hydrogen is transported in molecular form and a low relaxation of the silicon network is promoted. This is in contrast to the high-temperature process for which the diffusion of H in atomic form induces a substantial lattice relaxation that, for the conventional amorphous sample, releases energy of around 600meV per H atom. It is argued that the density of sites in the Si network for H trapping diminishes during atomic diffusion.

P. Roura, J. Farjas, Chandana Rath, J. Serra-Miralles, E. Bertran, and P. Roca i Cabarrocas

2006-02-13T23:59:59.000Z

203

The Ohio Enterprise Bond Fund (Ohio) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Bond Fund (Ohio) Bond Fund (Ohio) The Ohio Enterprise Bond Fund (Ohio) < Back Eligibility Commercial State/Provincial Govt Industrial Local Government Nonprofit Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Maximum Rebate $10 million Program Info Funding Source Ohio Treasurer of State Start Date 1988 State Ohio Program Type Bond Program The Ohio Enterprise Bond Fund (OEBF) was created in 1988 to promote economic development, create and retain quality jobs and assist governmental operations. The program enables non-profit and for-profit borrowers to access the national capital markets through bonds issued through OEBF. The program is administered by the Ohio Department of Development and financing is provided by the Ohio Treasurer of State.

204

A Surprising Path for Proton Transfer Without Hydrogen Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Surprising Path for Proton Transfer Without Hydrogen Bonds Print A Surprising Path for Proton Transfer Without Hydrogen Bonds Print Hydrogen bonds are found everywhere in chemistry and biology and are critical in DNA and RNA. A hydrogen bond results from the attractive dipolar interaction of a chemical group containing a hydrogen atom with a group containing an electronegative atom, such as nitrogen, oxygen, or fluorine, in the same or a different molecule. Conventional wisdom has it that proton transfer from one molecule to another can only happen via hydrogen bonds. Recently, a team of Berkeley Lab and University of Southern California researchers, using the ALS, discovered to their surprise that in some cases, protons can find ways to transfer even when hydrogen bonds are blocked. Sometimes You Have to

205

Ultrasonic NDT of titanium diffusion bonding with guided waves  

SciTech Connect (OSTI)

An ultrasonic guided wave technique is developed for the NDT of diffusion bonded titanium-to-titanium structures. A three-layer model based on the normal beam experimental results has been proposed. Dispersion curves and wave structure are analyzed to direct the experimental study. Two features related to Lamb waves propagating in diffusion bonded titanium plates, the spectral peak to peak ratios and the wave mode frequency shift, are extracted from the guided wave experimental results for both 2 mm (0.08 in.) and 4 mm (0.16 in.) diffusion bond panels. It is found for some specific modes and frequencies that these two features are sensitive to the diffusion bonding states and, therefore, could be used to distinguish good bond panels from poor bond ones.

Rose, J.L.; Zhu, W. [Pennsylvania State Univ., University Park, PA (United States). Dept. of Engineering Science and Mechanics; Zaidi, M. [Boeing Co., Long Beach, CA (United States)

1998-04-01T23:59:59.000Z

206

A Surprising Path for Proton Transfer Without Hydrogen Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Surprising Path for Proton Transfer Without Hydrogen Bonds Print A Surprising Path for Proton Transfer Without Hydrogen Bonds Print Hydrogen bonds are found everywhere in chemistry and biology and are critical in DNA and RNA. A hydrogen bond results from the attractive dipolar interaction of a chemical group containing a hydrogen atom with a group containing an electronegative atom, such as nitrogen, oxygen, or fluorine, in the same or a different molecule. Conventional wisdom has it that proton transfer from one molecule to another can only happen via hydrogen bonds. Recently, a team of Berkeley Lab and University of Southern California researchers, using the ALS, discovered to their surprise that in some cases, protons can find ways to transfer even when hydrogen bonds are blocked. Sometimes You Have to

207

Bond formation at the Ni/ZrO2 interface  

Science Journals Connector (OSTI)

We report on the formation of strong chemical bonds at the Ni(100)/cubic-ZrO2(100) polar interfaces. Ab initio density functional theory calculations demonstrate that both Zr/Ni and O/Ni junctions are energetically stable, and predict that two different interactions determine the interface adhesion. Our results reveal that O-Ni ionic bonds are formed by Ni electron donation, while the Zr-Ni bonds show a mixed character with ionic and electron hybridization contributions.

J. I. Beltrán; S. Gallego; J. Cerdá; J. S. Moya; M. C. Muńoz

2003-08-07T23:59:59.000Z

208

Torsion Testing of Diffusion Bonded LIGA Formed Nickel  

SciTech Connect (OSTI)

A test technique has been devised which is suitable for the testing of the bond strength of batch diffusion bonded LIGA or DXRL defined structures. The method uses a torsion tester constructed with the aid of LIGA fabrication and distributed torsion specimens which also make use of the high aspect ratio nature of DXRL based processing. Measurements reveal achieved bond strengths of 130MPa between electroplated nickel with a bond temperature of 450 C at 7 ksi pressure which is a sufficiently low temperature to avoid mechanical strength degradation.

Buchheit, T.E.; Christenson, T.R.; Schmale, D.T.

1999-01-27T23:59:59.000Z

209

Shear strength of composite bonded to laser-pretreated dentin  

SciTech Connect (OSTI)

As research progresses, laser energy moves closer to acceptable usefulness. Laser application to prepare dentin creates a more retentive surface for composite bonding.

Cooper, L.F.; Myers, M.L.; Nelson, D.G.; Mowery, A.S.

1988-07-01T23:59:59.000Z

210

Intramolecular hydrogen bonding as a synthetic tool to induce...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intramolecular hydrogen bonding as a synthetic tool to induce chemical selectivity in acid catalyzed porphyrin synthesis Authors: Megiatto, J. D., Patterson, D., Sherman, B. D.,...

211

Low-Cost Direct Bonded Aluminum (DBA) Substrates | Department...  

Energy Savers [EERE]

(DBA) Substrates Low-Cost Direct Bonded Aluminum (DBA) Substrates 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

212

Low-Cost Direct Bonded Aluminum (DBA) Substrates | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Aluminum (DBA) Substrates Low-Cost Direct Bonded Aluminum (DBA) Substrates 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and...

213

ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Direct Bonded Aluminum (DBA) Substrates (Agreement ID:23278) 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

214

ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement...  

Broader source: Energy.gov (indexed) [DOE]

Low-Cost Direct Bonded Aluminum (DBA) Substrates H. -T. Lin, A. A. Wereszczak, and S. Waters Oak Ridge National Laboratory This presentation does not contain any proprietary,...

215

Wafer bonded epitaxial templates for silicon heterostructures  

DOE Patents [OSTI]

A heterostructure device layer is epitaxially grown on a virtual substrate, such as an InP/InGaAs/InP double heterostructure. A device substrate and a handle substrate form the virtual substrate. The device substrate is bonded to the handle substrate and is composed of a material suitable for fabrication of optoelectronic devices. The handle substrate is composed of a material suitable for providing mechanical support. The mechanical strength of the device and handle substrates is improved and the device substrate is thinned to leave a single-crystal film on the virtual substrate such as by exfoliation of a device film from the device substrate. An upper portion of the device film exfoliated from the device substrate is removed to provide a smoother and less defect prone surface for an optoelectronic device. A heterostructure is epitaxially grown on the smoothed surface in which an optoelectronic device may be fabricated.

Atwater, Jr., Harry A. (So. Pasadena, CA); Zahler, James M. (Pasadena, CA); Morral, Anna Fontcubera I (Paris, FR)

2008-03-11T23:59:59.000Z

216

A mesoscopic network model for permanent set in crosslinked elastomers  

SciTech Connect (OSTI)

A mesoscopic computational model for polymer networks and composites is developed as a coarse-grained representation of the composite microstructure. Unlike more complex molecular dynamics simulations, the model only considers the effects of crosslinks on mechanical behavior. The elastic modulus, which depends only on the crosslink density and parameters in the bond potential, is consistent with rubber elasticity theory, and the network response satisfies the independent network hypothesis of Tobolsky. The model, when applied to a commercial filled silicone elastomer, quantitatively reproduces the experimental permanent set and stress-strain response due to changes in the crosslinked network from irradiation.

Weisgraber, T H; Gee, R H; Maiti, A; Clague, D S; Chinn, S; Maxwell, R S

2009-01-29T23:59:59.000Z

217

Method of bonding single crystal quartz by field-assisted bonding  

DOE Patents [OSTI]

The method of producing a hermetic stable structural bond between quartz crystals includes providing first and second quartz crystals and depositing thin films of borosilicate glass and silicon on portions of the first and second crystals, respectively. The portions of the first and second crystals are then juxtaposed in a surface contact relationship and heated to a temperature for a period sufficient to cause the glass and silicon films to become electrically conductive. An electrical potential is then applied across the first and second crystals for creating an electrostatic field between the adjoining surfaces and causing the juxtaposed portions to be attracted into an intimate contact and form a bond for joining the adjoining surfaces of the crystals.

Curlee, Richard M. (Tijeras, NM); Tuthill, Clinton D. (Edgewood, NM); Watkins, Randall D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

218

Metal-on-Metal Bonding and Rebonding Revisited  

Science Journals Connector (OSTI)

Density-functional calculations for a wide variety of metals show that, contrary to rebonding theory, ad-dimers do not have notably longer surface bonds than adatoms, do not reside farther above the surface, and do not meet the rebonding arguments for augmented mobility. Rebonding contributes to destabilize ad-dimers, but does not explain inherently weak ad-dimer bonds.

Alexander Bogicevic

1999-06-28T23:59:59.000Z

219

Clean Renewable Energy Bonds (CREBs) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Clean Renewable Energy Bonds (CREBs) Clean Renewable Energy Bonds (CREBs) Clean Renewable Energy Bonds (CREBs) < Back Eligibility Local Government Municipal Utility Rural Electric Cooperative Schools State Government Tribal Government Savings Category Bioenergy Buying & Making Electricity Water Solar Wind Program Info Start Date 09/01/2010 (New CREBs Electric Cooperatives Solicitation) Expiration Date 11/01/2010 Program Type Federal Loan Program Rebate Amount Varies Provider U.S. Internal Revenue Service '''''Note: The IRS is not currently accepting applications for New CREB bond volume. The deadline for New CREB applications from electric cooperatives under IRS Announcement 2010-54 expired November 1, 2010. Bond volume for other eligible sectors (government entities and public power providers) was fully allocated in October 2009.

220

Renewable Energy Project Bond Program | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Project Bond Program Project Bond Program Renewable Energy Project Bond Program < Back Eligibility Commercial Savings Category Bioenergy Commercial Heating & Cooling Manufacturing Buying & Making Electricity Alternative Fuel Vehicles Hydrogen & Fuel Cells Water Solar Wind Program Info State Idaho Program Type State Bond Program Provider Idaho Energy Resources Authority Legislation enacted in Idaho in April 2005 ([http://legislature.idaho.gov/legislation/2005/S1192.html Senate Bill 1192]) allows independent (non-utility) developers of renewable energy projects in the state to request financing from the Idaho Energy Resources Authority, a state bonding authority created in March 2005 by the Environment, Energy and Technology Energy Resources Authority Act (House Bill 106). The authority was created to finance the construction of

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Pressure-Induced Phase Transition in Guanidinium Perchlorate: A Supramolecular Structure Directed by Hydrogen Bonding and Electrostatic Interactions  

SciTech Connect (OSTI)

In situ Raman spectroscopy and synchrotron X-ray diffraction (XRD) experiments have been performed to investigate the response of guanidinium perchlorate (C(NH{sub 2}){sub 3}{sup +} {center_dot} ClO{sub 4}{sup -}, GP) to high pressures of {approx}11 GPa. GP exhibits a typical supramolecular structure of two-dimensional (2D) hydrogen-bonded ionic networks at ambient conditions. A subtle phase transition, accompanied by the symmetry transformation from R3m to C2, has been confirmed by obvious changes in both Raman and XRD patterns at 4.5 GPa. The phase transition is attributed to the competition between hydrogen bonds and close packing of the supramolecular structure at high pressure. Hydrogen bonds have been demonstrated to evolve into a distorted state through the phase transition, accompanied by the reduction in separation of oppositely charged ions in adjacent sheet motifs. A detailed mechanism of the phase transition, as well as the cooperativity between hydrogen bonding and electrostatic interactions, is discussed by virtue of the local nature of the structure.

Li, Shourui; Li, Qian; Wang, Kai; Tan, Xiao; Zhou, Mi; Li, Bing; Liu, Bingbing; Zou, Guangtian; Zou, Bo (Jilin)

2012-01-20T23:59:59.000Z

222

Measuring Electrostatic Fields in Both Hydrogen-Bonding and Non-Hydrogen-Bonding Environments Using Carbonyl Vibrational Probes  

E-Print Network [OSTI]

of the probe's difference dipole, which is determined by measuring the vibrational Stark effect and definesMeasuring Electrostatic Fields in Both Hydrogen-Bonding and Non- Hydrogen-Bonding Environments Using Carbonyl Vibrational Probes Stephen D. Fried, Sayan Bagchi, and Steven G. Boxer* Department

Boxer, Steven G.

223

Flexibility and Symmetry of Prokaryotic Genome Rearrangement Reveal Lineage-Associated Core-Gene-Defined Genome Organizational Frameworks  

Science Journals Connector (OSTI)

...significantly enriched in categories C (energy production and conversion...functional categories: ribosomal, energy production/conversion, and...significantly enriched, and green asterisks indicate those of...interaction network. Red, green, and blue solid circles denote...

Yu Kang; Chaohao Gu; Lina Yuan; Yue Wang; Yanmin Zhu; Xinna Li; Qibin Luo; Jingfa Xiao; Daquan Jiang; Minping Qian; Aftab Ahmed Khan; Fei Chen; Zhang Zhang; Jun Yu

2014-12-01T23:59:59.000Z

224

Dynamics on modular networks with heterogeneous correlations  

SciTech Connect (OSTI)

We develop a new ensemble of modular random graphs in which degree-degree correlations can be different in each module, and the inter-module connections are defined by the joint degree-degree distribution of nodes for each pair of modules. We present an analytical approach that allows one to analyze several types of binary dynamics operating on such networks, and we illustrate our approach using bond percolation, site percolation, and the Watts threshold model. The new network ensemble generalizes existing models (e.g., the well-known configuration model and Lancichinetti-Fortunato-Radicchi networks) by allowing a heterogeneous distribution of degree-degree correlations across modules, which is important for the consideration of nonidentical interacting networks.

Melnik, Sergey [MACSI, Department of Mathematics and Statistics, University of Limerick (Ireland) [MACSI, Department of Mathematics and Statistics, University of Limerick (Ireland); Oxford Centre for Industrial and Applied Mathematics, Mathematical Institute, University of Oxford, Oxford OX2 6GG (United Kingdom); CABDyN Complexity Centre, University of Oxford, Oxford OX1 1HP (United Kingdom); Porter, Mason A. [Oxford Centre for Industrial and Applied Mathematics, Mathematical Institute, University of Oxford, Oxford OX2 6GG (United Kingdom) [Oxford Centre for Industrial and Applied Mathematics, Mathematical Institute, University of Oxford, Oxford OX2 6GG (United Kingdom); CABDyN Complexity Centre, University of Oxford, Oxford OX1 1HP (United Kingdom); Mucha, Peter J. [Department of Mathematics, Carolina Center for Interdisciplinary Applied Mathematics, University of North Carolina, Chapel Hill, North Carolina 27599-3250 (United States) [Department of Mathematics, Carolina Center for Interdisciplinary Applied Mathematics, University of North Carolina, Chapel Hill, North Carolina 27599-3250 (United States); Institute for Advanced Materials, Nanoscience and Technology, University of North Carolina, Chapel Hill, North Carolina 27599-3216 (United States); Gleeson, James P. [MACSI, Department of Mathematics and Statistics, University of Limerick (Ireland)] [MACSI, Department of Mathematics and Statistics, University of Limerick (Ireland)

2014-06-15T23:59:59.000Z

225

Semi-flexible hydrogen-bonded and non-hydrogen bonded lattice polymers  

E-Print Network [OSTI]

We investigate the addition of stiffness to the lattice model of hydrogen-bonded polymers in two and three dimensions. We find that, in contrast to polymers that interact via a homogeneous short-range interaction, the collapse transition is unchanged by any amount of stiffness: this supports the physical argument that hydrogen bonding already introduces an effective stiffness. Contrary to possible physical arguments, favouring bends in the polymer does not return the model's behaviour to that comparable to the semi-flexible homogeneous interaction model, where the canonical $\\theta$-point occurs for a range of parameter values. In fact, for sufficiently large bending energies the crystal phase disappears altogether, and no phase transition of any type occurs. We also compare the order-disorder transition from the globule phase to crystalline phase in the semi-flexible homogeneous interaction model to that for the fully-flexible hybrid model with both hydrogen and non-hydrogen like interactions. We show that these phase transitions are of the same type and are a novel polymer critical phenomena in two dimensions. That is, it is confirmed that in two dimensions this transition is second-order, unlike in three dimensions where it is known to be first order. We also estimate the crossover exponent and show that there is a divergent specific heat, finding $\\phi=0.7(1)$ or equivalently $\\alpha=0.6(2)$. This is therefore different from the $\\theta$ transition, for which $\\alpha=-1/3$.

J Krawczyk; AL Owczarek; T Prellberg

2008-07-06T23:59:59.000Z

226

Cognitive Radio Networks as Sensor Networks  

E-Print Network [OSTI]

is used, assuming the cognitive radios know their ownfor Embedded Networked Sensing Cognitive Radio Networks AsJ. Pottie Introduction: Cognitive Radio (CR) Networks The

Bandari, Dorna; Yang, Seung R.; Zhao, Yue; Pottie, Gregory

2007-01-01T23:59:59.000Z

227

Do Main Chain Hydrogen Bonds Create Dominant Electron Transfer Pathways?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Main Chain Hydrogen Bonds Create Dominant Electron Transfer Pathways? An Main Chain Hydrogen Bonds Create Dominant Electron Transfer Pathways? An Investigation in Designed Proteins Yongjian Zheng, Martin A. Case, James F. Wishart, and George L. McLendon J. Phys. Chem. B, 107, 7288-7292 (2003). [Find paper at ACS Publications] Abstract: We have investigated the contribution of main chain hydrogen bond (H-bond) pathways to the tunneling matrix elements which control electron transfer (ET) rates across an alpha-helical protein matrix. The paradigm system for these investigations is a metal ion-assembled parallel three-helix bundle protein that contains a ruthenium(II) tris(bipyridyl) electron donor and a ruthenium(III) pentammine electron acceptor separated by a direct metal to metal distance of ca. 19 Ă…, requiring tunneling through 15 Ă… of

228

Laser surface roughening of PTFE for increased bonding strength  

Science Journals Connector (OSTI)

Treatment of pure Teflon (PTFE) with UV laser pulses (193 nm) produces area-selective rough surfaces. These irradiated areas are bondable with ordinary adhesives. The stability of the bonds is about one order ...

M. Rauh; J. Ihlemann; A. Koch

2007-08-01T23:59:59.000Z

229

Economic Significance, Survey of Applications, and Six Bonding Functions  

Science Journals Connector (OSTI)

The following remarks will review the uses of phenolic resins and their distribution throughout the various areas of application, making reference to the six “bonding functions” that phenolic resins mainly ass...

Dr. Arno Gardziella; Dr. Louis A. Pilato; Dr. Andre Knop

2000-01-01T23:59:59.000Z

230

Bond resonance energy and verification of the isolated pentagon rule  

SciTech Connect (OSTI)

The isolated pentagon rule (IPR) states that fullerenes with isolated pentagons are kinetically much more stable than their fused pentagon counterparts. This rule can be verified in terms of a graph-theoretically defined bond resonance energy. In general, a {pi} bond shared by two pentagons has a large negative bond resonance energy, thus contributing significantly to the increase in kinetic instability or chemical reactivity of the molecule. The existence of such highly antiaromatic local structures sharply distinguishes IPR-violating fullerenes from isolated-pentagon isomers. {pi}bonds shared by two pentagons are shared by many antiaromatic conjugated circuits but not by relatively small aromatic conjugated circuits. 39 refs., 3 figs., 5 tabs.

Aihara, Jun Ichi [Shizuoka Univ. (Japan)

1995-04-12T23:59:59.000Z

231

Surface Modification by Atmospheric Pressure Plasma for Improved Bonding  

E-Print Network [OSTI]

prepared using (a) the IPA wipe (control), (b) sanding, (c)of aluminum alloy 2024: a) IPA wiped, b) sanded with 180bond primer with a) the IPA wipe (control), b) sanding, c)

Williams, Thomas Scott

2013-01-01T23:59:59.000Z

232

Low-Cost Financing with Clean Renewable Energy Bonds  

Broader source: Energy.gov [DOE]

Contains information from the TAP Webcast on June 24, 2009 on clean renewable energy bonds from Claire Kreycik on feed-in tariffs, an economic resource for developing renewable energy.

233

Nature of Bridging Bonds in Lithium and Potassium Acetate Dimers  

Science Journals Connector (OSTI)

The structures of lithium and potassium acetates were studied by the RHF/6-31G*...3COOLi)2 and (CH3COOK)2 are electrostatic in nature. The bridging lithium bond is intermediate between hydrogen and ionic, ... of ...

I. A. Panteleev; S. G. Semenov; D. N. Glebovskii

234

Mpemba paradox: Hydrogen bond memory and water-skin supersolidity  

E-Print Network [OSTI]

Numerical reproduction of measurements, experimental evidence for skin super-solidity and hydrogen-bond memory clarified that Mpemba paradox integrates the heat emission-conduction-dissipation dynamics in the source-path-drain cycle system.

Chang Q Sun

2015-01-05T23:59:59.000Z

235

Conservation of bond lengths in strained Ge-Si layers  

Science Journals Connector (OSTI)

The combined techniques of x-ray-absorption fine structure and x-ray diffraction have been used to study the strain and bond distortions in epitaxial Ge-Si on Si(001). In a 31% Ge, 340-Ĺ pseudomorphic Ge-Si film, the Ge-Ge and Ge-Si first-neighbor bond lengths have been found to be 2.44±0.02 and 2.38±0.02 Ĺ, respectively. The lattice parameter perpendicular to the Ge-Si/Si(001) interface has been found to be a?=5.552±0.002 Ĺ, in agreement with the predictions of macroscopic elastic theory. These results show that the bond-length strain in the epitaxial layer appears in the second and higher coordination shells, rather than in the nearest-neighbor bond lengths, which remain the same as in unstrained Ge-Si. A microscopic model is presented that accounts for these findings.

J. C. Woicik; C. E. Bouldin; M. I. Bell; J. O. Cross; D. J. Tweet; B. D. Swanson; T. M. Zhang; L. B. Sorensen; C. A. King; J. L. Hoyt; P. Pianetta; J. F. Gibbons

1991-01-15T23:59:59.000Z

236

Low-Cost Direct Bonded Aluminum (DBA) Substrates  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Managed by UT-Battelle for the Department of Energy Low-Cost Direct Bonded Aluminum (DBA) Substrates H. -T. Lin, A. A. Wereszczak, and S. Waters Oak Ridge National Laboratory This...

237

Low-Cost Direct Bonded Aluminum (DBA) Substrates  

Broader source: Energy.gov (indexed) [DOE]

Low-Cost Direct Bonded Aluminum (DBA) Substrates H. -T. Lin, A. A. Wereszczak, M. L. Santella, and G. Muralidharan Oak Ridge National Laboratory (ORNL) This presentation does not...

238

Application of Social Impact Bonds in Built Infrastructure Sustainability Projects  

E-Print Network [OSTI]

This study examines a first look at the implementation of Social Impact Bonds (SIB) for sustainability projects by comparing two cases. The cases are described using System Dynamic (SD) modeling to portray the feedback structures and characteristics...

White, Robert Joseph

2014-05-01T23:59:59.000Z

239

IRS Announces New Tribal Economic Development Bond Allocation Guidance |  

Broader source: Energy.gov (indexed) [DOE]

IRS Announces New Tribal Economic Development Bond Allocation IRS Announces New Tribal Economic Development Bond Allocation Guidance IRS Announces New Tribal Economic Development Bond Allocation Guidance July 18, 2012 - 3:46pm Addthis To promote economic growth in tribal communities, Treasury and the Internal Revenue Service (IRS) published new guidance on July 18, 2012, allocating Tribal Economic Development Bonds (TEDBs). The TEDB program was established under the American Reinvestment and Recovery Act, and provides Tribes with the authority to issue tax-exempt debt for a wider range of activities to spur job creation and promote economic growth in Indian country. Providing Tribes with the ability to issue tax-exempt debt for a broader scope of activities similar to that available to states and local governments lowers

240

MODE II FRACTURE BEHAVIOR OF BONDED VISCOELASTIC THERMAL COMPRESSED WOOD  

E-Print Network [OSTI]

MODE II FRACTURE BEHAVIOR OF BONDED VISCOELASTIC THERMAL COMPRESSED WOOD Andreja Kutnar* Graduate Student Department of Wood Science and Technology Biotechnical Faculty University of Ljubljana 1000 Ljubljana, Slovenia Frederick A. Kamke Professor John A. Nairn Professor Department of Wood Science

Nairn, John A.

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

A revised structure and hydrogen bonding system in cellulose II from a neutron fiber diffraction analysis  

SciTech Connect (OSTI)

The crystal and molecular structure and hydrogen bonding system in cellulose II have been revised using new neutron diffraction data extending to 1.2 {angstrom} resolution collected from two highly crystalline fiber samples of mercerized flax. Mercerization was achieved in NaOH/H{sub 2}O for one sample and in NaOD/D{sub 2}O for the other, corresponding to the labile hydroxymethyl moieties being hydrogenated and deuterated, respectively. Fourier difference maps were calculated in which neutron difference amplitudes were combined with phases calculated from two revised X-ray models of cellulose II. The revised phasing models were determined by refinement against the X-ray data set of Kolpak and Blackwell, using the LALS methodology. Both models have two antiparallel chains organized in a P2{sub 1} space group and unit cell parameters: a = 8.01 {angstrom}, b = 9.04 {angstrom}, c = 10.36 {angstrom}, and {gamma} = 117.1{degree}. One has equivalent backbone conformations for both chains but different conformations for the hydroxymethyl moieties: gt for the origin chain and tg for the center chain. The second model based on the recent crystal structures of cellotetraose, has different conformations for the two chains but nearly equivalent conformations for the hydroxymethyl moieties. On the basis of the X-ray data alone, the models could not be differentiated. From the neutron Fourier difference maps, possible labile hydrogen atom positions were identified for each model and refined using LALS. The second model is significantly different from previous proposals based on the crystal structures of cellotetraose, MD simulations of cellulose II, and any potential hydrogen-bonding network in the structure of cellulose II determined in earlier X-ray fiber diffraction studies. The exact localization of the labile hydrogen atoms involved in this bonding, together with their donor and acceptor characteristics, is presented and discussed. This study provides, for the first time, the coordinates of all of the atoms in cellulose II.

Langan, P.; Nishiyama, Y.; Chanzy, H.

1999-11-03T23:59:59.000Z

242

Bonded Bracket Assmebly for Frameless Solar Panels  

SciTech Connect (OSTI)

In February 2011 the US Department of Energy announced their new Sunshot Initiative. The Sunshot goal is to reduce the total cost of solar energy systems by about 75 percent before the end of the decade. The DOE estimated that a total installed cost of $1 per watt for photovoltaic systems would be equivalent to 6���¢/kilowatt hour (kWh) for energy available from the grid. The DOE also estimated that to meet the $1 per watt goal, PV module costs would need to be reduced to $.50 per watt, balance of systems costs would need to be reduced to $.40 per watt, and power electronic costs would need to reach $.10 per watt. To address the BOS balance of systems cost component of the $1 per watt goal, the DOE announced a funding opportunity called (BOS-X) Extreme Balance of System Hardware Cost Reductions. The DOE identified eight areas within the total BOS costs: 1) installation labor, 2) installation materials, 3) installation overhead and profit, 4) tracker, 5) permitting and commissioning, 6) site preparation, 7) land acquisition, 8) sales tax. The BOS-X funding announcement requested applications in four specific topics: Topic 1: Transformational Building Integrated Photovoltaic (BIPV) Modules Topic 2: Roof and Ground Mount Innovations Topic 3: Transformational Photovoltaic System Designs Topic 4: Development of New Wind Load Codes for PV Systems The application submitted by ARaymond Tinnerman reflected the requirements listed in Topic #2, Roof and Ground Mount Innovations. The goal of topic #2 was to develop technologies that would result in the extreme reduction of material and labor costs associated with applications that require physical connections and attachments to roof and ground mount structures. The topics researched in this project included component cost reduction, labor reduction, weight reduction, wiring innovations, and alternative material utilization. The project objectives included: 1) The development of an innovative quick snap bracket assembly that would be bonded to frameless PV modules for commercial rooftop installations. 2) The development of a composite pultruded rail to replace traditional racking materials. 3) In partnership with a roofing company, pilot the certification of a commercial roof to be solar panel compliant, eliminating the need for structural analysis and government oversight resulting in significantly decreased permitting costs. 4) Reduce the sum of all cost impacts in topic #2 from a baseline total of $2.05/watt to $.34/watt.

Murray, Todd

2013-01-30T23:59:59.000Z

243

New Bond Helps Toledo, Ohio, Expand Financing Pool  

Broader source: Energy.gov [DOE]

The BetterBuildings Northwest Ohio (BBNWO) Program, in conjunction with the Toledo Ohio Advanced Energy Improvement Corporation—a pioneering Energy Special Improvement District in Ohio that allows energy efficiency improvements to be funded and paid for through property special assessments—has received a second bond from the Toledo-Lucas County Port Authority. This bond is in the amount of $6,435,000.

244

Bond Distortions in Armchair Type Single Wall Carbon Nanotubes  

E-Print Network [OSTI]

The energy band gap structure and stability of (3,3) and (10,10) nanotubes have been comparatively investigated in the frameworks of the traditional form of the Su-Schrieffer-Heeger (SSH) model and a toy model including the contributions of bonds of different types to the SSH Hamiltonian differently. Both models give the same energy band gap structure but bond length distortions in different characters for the nanotubes.

N. Sunel; E. Rizaoglu; K. Harigaya; O. Ozsoy

2005-03-03T23:59:59.000Z

245

Method of making sintered ductile intermetallic-bonded ceramic composites  

DOE Patents [OSTI]

A method of making an intermetallic-bonded ceramic composite involves combining a particulate brittle intermetallic precursor with a particulate reactant metal and a particulate ceramic to form a mixture and heating the mixture in a non-oxidizing atmosphere at a sufficient temperature and for a sufficient time to react the brittle intermetallic precursor and the reactant metal to form a ductile intermetallic and sinter the mixture to form a ductile intermetallic-bonded ceramic composite. 2 figs.

Plucknett, K.; Tiegs, T.N.; Becher, P.F.

1999-05-18T23:59:59.000Z

246

BN Bonded BN fiber article and method of manufacture  

DOE Patents [OSTI]

A boron nitride bonded boron nitride fiber article and the method for its manufacture which comprises forming a shaped article with a composition comprising a bonding compound selected from boron oxide and boric acid and a structural fiber selected from the group consisting of boron oxide, boron nitride and partially nitrided boron oxide fibers, heating the composition in an anhydrous gas to a temperature above the melting point of the compound and nitriding the resulting article in ammonia gas.

Hamilton, Robert S. (Youngstown, NY)

1981-08-18T23:59:59.000Z

247

Time-Resolved Study of Bonding in Liquid Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Time-Resolved Study of Bonding Time-Resolved Study of Bonding in Liquid Carbon Time-Resolved Study of Bonding in Liquid Carbon Print Wednesday, 28 September 2005 00:00 We are accustomed to observing carbon in its elemental form as a solid, ranging from the soft "lead" in pencils to the precious gemstone in diamond rings. While considerable attention has been focused on solid forms of carbon, the properties of liquid carbon are much more difficult to measure accurately. The very strong bonding between carbon atoms that gives diamonds their hardness also makes carbon very difficult to melt, requiring temperatures above 5000 K at pressures above 100 bar. Maintaining such conditions in a laboratory is a challenge that has hampered efforts to fully understand the chemical bonding properties of this biologically, industrially, and environmentally important element. At the ALS, researchers have found a way to rapidly heat a carbon sample and contain the resulting liquid long enough to perform picosecond time-resolved x-ray absorption spectroscopy. The technique provides a way to measure the bonding properties of liquid carbon at near-solid densities that can then be compared with results from molecular dynamics simulations.

248

Transient liquid phase bonding of structural intermetallic compounds  

Science Journals Connector (OSTI)

The intermetallic compound NiAl is a candidate material for high-temperature structural applications, for example in the hot-zone of aero gas turbine engines. However, if this material is to find significant structural applications, methodologies for primary fabrication of complex components and post-service repair will be required. In particular, joining technologies suitable for bonding NiAl to nickel-base alloys are required. This paper examines transient liquid phase (TLP) bonding as a method of joining NiAl to nickel-base alloys. The focus of the paper is microstructural development at the bond-line and in the adjacent (nickel-base and NiAl) substrates. Two different interlayer materials are considered in this paper, namely: Ni – 4.5 wt.% Si – 3.2 wt.%B (designated by the American Welding Society as 'BNi-3') and commercially pure copper. Bonds between binary, nominally-stoichiometric NiAl and both commercially pure nickel and Martin Marietta 247 are examined using edge-on transmission electron microscopy. The paper considers the character of the isothermal solidification process, the formation of second-phases at the bond-line and in the adjacent substrates and the extent to which NiAl-Ni-base alloy TLP bonds obey the assumptions implicit in standard models of the TLP process.

W.F. Gale; Y. Guan; S.V. Orel

1998-01-01T23:59:59.000Z

249

Theory of bonding of transition metals to nontransition metals  

Science Journals Connector (OSTI)

We present a theory of the chemical bond in compounds consisting of both transition metals and nontransition metals. Chemical trends in the bonding properties are established by directly comparing the total energies of a large number of such compounds with the total energies of their constituents. These chemical trends are analyzed in terms of the s-, p-, and d-like state densities of the compounds and the constituents. Rather different types of bonding are shown to result when the atomic s and p levels of the nontransition metal lie above, below, and near the energy of the transition-metal d level. The heat of compound formation is shown to result from a competition between two simple physical effects: (1) the weakening of the transition-metal bonds by the lattice dilatation required for the accommodation of the nontransition metal, and (2) the increased bonding which results from the occupation of the bonding members of the hybrid states formed from the interaction between the transition-metal d states and the s-p states on the nontransition metal. Our theoretical values for the heats of formation of these compounds are generally similar to those given by Miedema's empirical formula. Distinctive aspects of the variation of the heat of formation with the number of valence electrons reveal, however, that the microscopic picture on which the empirical formula is based is quite different from that given by our self-consistent energy-band theory.

C. D. Gelatt; Jr.; A. R. Williams; V. L. Moruzzi

1983-02-15T23:59:59.000Z

250

Discrete element modeling of rock deformation, fracture network development and permeability evolution under hydraulic stimulation  

SciTech Connect (OSTI)

Key challenges associated with the EGS reservoir development include the ability to reliably predict hydraulic fracturing and the deformation of natural fractures as well as estimating permeability evolution of the fracture network with time. We have developed a physics-based rock deformation and fracture propagation simulator by coupling a discrete element model (DEM) for fracturing with a network flow model. In DEM model, solid rock is represented by a network of discrete elements (often referred as particles) connected by various types of mechanical bonds such as springs, elastic beams or bonds that have more complex properties (such as stress-dependent elastic constants). Fracturing is represented explicitly as broken bonds (microcracks), which form and coalesce into macroscopic fractures when external and internal load is applied. The natural fractures are represented by a series of connected line segments. Mechanical bonds that intersect with such line segments are removed from the DEM model. A network flow model using conjugate lattice to the DEM network is developed and coupled with the DEM. The fluid pressure gradient exerts forces on individual elements of the DEM network, which therefore deforms the mechanical bonds and breaks them if the deformation reaches a prescribed threshold value. Such deformation/fracturing in turn changes the permeability of the flow network, which again changes the evolution of fluid pressure, intimately coupling the two processes. The intimate coupling between fracturing/deformation of fracture networks and fluid flow makes the meso-scale DEM- network flow simulations necessary in order to accurately evaluate the permeability evolution, as these methods have substantial advantages over conventional continuum mechanical models of elastic rock deformation. The challenges that must be overcome to simulate EGS reservoir stimulation, preliminary results, progress to date and near future research directions and opportunities will be discussed. Methodology for coupling the DEM model with continuum flow and heat transport models will also be discussed.

Shouchun Deng; Robert Podgorney; Hai Huang

2011-02-01T23:59:59.000Z

251

Network Perspectives on Communities  

E-Print Network [OSTI]

W W. Networks Fields and Organizations: Micro-Dynamics Scaleentitled “Networks, Fields and Organizations: Micro-

Wolfe, Alvin W

2006-01-01T23:59:59.000Z

252

Better networking  

Science Journals Connector (OSTI)

... world' network means that it can be crossed in a few hops. But, reports John Whitfield, it's not necessarily easy to find the best route. It's all ...

John Whitfield

2000-08-24T23:59:59.000Z

253

Network Policies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acceptable Use Policy About ESnet Our Mission The Network ESnet History Governance & Policies ESnet Policy Board ESCC Acceptable Use Policy Facility Data Policy Career...

254

Network Embedded Systems Sensor Networks  

E-Print Network [OSTI]

Link Network Transport Application SPIN BroadcastStorm TinyOS0.6 WooMAC GAF S-MAC AlohaPS PSFQ GDI CODA

Amir, Yair

255

PROPOSED MODIFICATION TO THE ACI 318-02 CODE EQUATION ON BOND STRENGTH FOR MMFX STEEL  

E-Print Network [OSTI]

ST-263-1 PROPOSED MODIFICATION TO THE ACI 318-02 CODE EQUATION ON BOND STRENGTH FOR MMFX STEEL R the bond characteristics of Micro-composite Multi-structural Formable reinforcing steel rebars of the current equation of the ACI 318-02 Code on bond to predict the bond capacity of the MMFX steel rebars

256

A new hydrogen-bonding potential for the design of proteinRNA interactions predicts specific  

E-Print Network [OSTI]

A new hydrogen-bonding potential for the design of protein­RNA interactions predicts specific-dependent hydrogen-bonding potential based on the statistical analysis of hydrogen-bonding geometries of hydrogen-bonding atom pairs at protein­ nucleic acid interfaces. A scoring function based on the hydrogen

Baker, David

257

Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical Exchange Spectroscopy  

E-Print Network [OSTI]

Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical ExchangeVed: January 12, 2010 Hydrogen-bonded complexes between phenol and phenylacetylene are studied using ultrafast hydrogen bonding acceptor sites (phenyl or acetylene) that compete for hydrogen bond donors in solution

Fayer, Michael D.

258

The C OH O hydrogen bond: A determinant of stability and specificity  

E-Print Network [OSTI]

recovered by hydro- gen bond formation, so hydrogen bonds provide a small or even unfavorable net energy hydro- gen bond has been unclear and its interaction energy has been believed to be small. Recently that apparent carbon hydro- gen bonds cluster frequently at glycine-, serine-, and threonine-rich packing

Senes, Alessandro

259

Time-Resolved Study of Bonding in Liquid Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Time-Resolved Study of Bonding in Liquid Carbon Print Time-Resolved Study of Bonding in Liquid Carbon Print We are accustomed to observing carbon in its elemental form as a solid, ranging from the soft "lead" in pencils to the precious gemstone in diamond rings. While considerable attention has been focused on solid forms of carbon, the properties of liquid carbon are much more difficult to measure accurately. The very strong bonding between carbon atoms that gives diamonds their hardness also makes carbon very difficult to melt, requiring temperatures above 5000 K at pressures above 100 bar. Maintaining such conditions in a laboratory is a challenge that has hampered efforts to fully understand the chemical bonding properties of this biologically, industrially, and environmentally important element. At the ALS, researchers have found a way to rapidly heat a carbon sample and contain the resulting liquid long enough to perform picosecond time-resolved x-ray absorption spectroscopy. The technique provides a way to measure the bonding properties of liquid carbon at near-solid densities that can then be compared with results from molecular dynamics simulations.

260

Time-Resolved Study of Bonding in Liquid Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Time-Resolved Study of Bonding in Liquid Carbon Print Time-Resolved Study of Bonding in Liquid Carbon Print We are accustomed to observing carbon in its elemental form as a solid, ranging from the soft "lead" in pencils to the precious gemstone in diamond rings. While considerable attention has been focused on solid forms of carbon, the properties of liquid carbon are much more difficult to measure accurately. The very strong bonding between carbon atoms that gives diamonds their hardness also makes carbon very difficult to melt, requiring temperatures above 5000 K at pressures above 100 bar. Maintaining such conditions in a laboratory is a challenge that has hampered efforts to fully understand the chemical bonding properties of this biologically, industrially, and environmentally important element. At the ALS, researchers have found a way to rapidly heat a carbon sample and contain the resulting liquid long enough to perform picosecond time-resolved x-ray absorption spectroscopy. The technique provides a way to measure the bonding properties of liquid carbon at near-solid densities that can then be compared with results from molecular dynamics simulations.

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Time-Resolved Study of Bonding in Liquid Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Time-Resolved Study of Bonding in Liquid Carbon Print Time-Resolved Study of Bonding in Liquid Carbon Print We are accustomed to observing carbon in its elemental form as a solid, ranging from the soft "lead" in pencils to the precious gemstone in diamond rings. While considerable attention has been focused on solid forms of carbon, the properties of liquid carbon are much more difficult to measure accurately. The very strong bonding between carbon atoms that gives diamonds their hardness also makes carbon very difficult to melt, requiring temperatures above 5000 K at pressures above 100 bar. Maintaining such conditions in a laboratory is a challenge that has hampered efforts to fully understand the chemical bonding properties of this biologically, industrially, and environmentally important element. At the ALS, researchers have found a way to rapidly heat a carbon sample and contain the resulting liquid long enough to perform picosecond time-resolved x-ray absorption spectroscopy. The technique provides a way to measure the bonding properties of liquid carbon at near-solid densities that can then be compared with results from molecular dynamics simulations.

262

From an insulating to a superfluid pair-bond liquid  

Science Journals Connector (OSTI)

We study an exchange coupled system of itinerant electrons and localized fermion pairs resulting in a resonant pairing formation. This system inherently contains resonating fermion pairs on bonds that lead to a superconducting phase, provided that long-range phase coherence between their constituents can be established. The prerequisite is that the resonating fermion pairs can become itinerant. This is rendered possible through the emergence of two kinds of bond fermions: individual and composite fermions made of one individual electron attached to a bound pair on a bond. If the strength of the exchange coupling exceeds a certain value, then the superconducting ground state undergoes a quantum phase transition into an insulating pair-bond liquid state. The gap of the superfluid phase thereby goes over continuously into a charge gap of the insulator. The changeover from the superconducting to the insulating phase is accompanied by a corresponding qualitative modification of the dispersion of the two kinds of fermionic excitations. Using a bond operator formalism, we derive the phase diagram of such a scenario together with the elementary excitations characterizing the various phases as a function of the exchange coupling and the temperature.

M. Cuoco and J. Ranninger

2006-09-20T23:59:59.000Z

263

New Insights into Hydrogen Bonding and Stacking Interactions in Cellulose  

SciTech Connect (OSTI)

In this quantum chemical study, we explore hydrogen bonding (H-bonding) and stacking interactions in different crystalline cellulose allomorphs, namely cellulose I and cellulose IIII. We consider a model system representing a cellulose crystalline core, made from six cellobiose units arranged in three layers with two chains per layer. We calculate the contributions of intrasheet and intersheet interactions to the structure and stability in both cellulose I and cellulose IIII crystalline cores. Reference structures for this study were generated from molecular dynamics simulations of water-solvated cellulose I and IIII fibrils. A systematic analysis of various conformations describing different mutual orientations of cellobiose units is performed using the hybrid density functional theory (DFT) with the M06-2X with 6-31+G (d, p) basis sets. We dissect the nature of the forces that stabilize the cellulose I and cellulose IIII crystalline cores and quantify the relative strength of H-bonding and stacking interactions. Our calculations demonstrate that individual H-bonding interactions are stronger in cellulose I than in cellulose IIII. We also observe a significant contribution from cooperative stacking interactions to the stabilization of cellulose I . In addition, the theory of atoms-in-molecules (AIM) has been employed to characterize and quantify these intermolecular interactions. AIM analyses highlight the role of nonconventional CH O H-bonding in the cellulose assemblies. Finally, we calculate molecular electrostatic potential maps for the cellulose allomorphs that capture the differences in chemical reactivity of the systems considered in our study.

Langan, Paul [ORNL

2011-01-01T23:59:59.000Z

264

Analytic bond-order potential for the gallium arsenide system  

Science Journals Connector (OSTI)

An analytic, bond-order potential (BOP) is proposed and parametrized for the gallium arsenide system. The potential addresses primary (?) and secondary (?) bonding and the valence-dependent character of heteroatomic bonding, and it can be combined with an electron counting potential to address the distribution of electrons on the GaAs surface. The potential was derived from a tight-binding description of covalent bonding by retaining the first two levels of an expanded Green’s function for the ? and ? bond-order terms. Predictions using the potential were compared with independent estimates for the structures and binding energy of small clusters (dimers, trimers, and tetramers) and for various bulk lattices with coordinations varying from 4 to 12. The structure and energies of simple point defects and melting transitions were also investigated. The relative stabilities of the (001) surface reconstructions of GaAs were well predicted, especially under high-arsenic-overpressure conditions. The structural and binding energy trends of this GaAs BOP generally match experimental observations and ab initio calculations.

D. A. Murdick; X. W. Zhou; H. N. G. Wadley; D. Nguyen-Manh; R. Drautz; D. G. Pettifor

2006-01-20T23:59:59.000Z

265

Compound “J” in Late Cretaceous/Tertiary terrigenous oils revisited: Structure elucidation of a rearranged oleanane coeluting on GC with 18?(H)-oleanane  

Science Journals Connector (OSTI)

Abstract A C30 pentacyclic triterpane eluting slightly after 18?(H)-oleanane in the m/z 191 mass chromatograms of Late Cretaceous/Tertiary terrigenous oils (peak “J” in the early literature) has been isolated from a Niger Delta oil and identified using NMR spectroscopy as 3?-methyl-24-nor-18?(H)-oleanane. The previous assignment as 18?(H)-oleanane is therefore partly erroneous. 3?-Methyl-24-nor-18?(H)-oleanane affords a larger m/z 412 ? 356 response than the oleananes and the relative contribution of 3?-methyl-24-nor-18?(H)-oleanane to the 412 ? 191 “oleanane peak” can be roughly estimated from comparison of the 412 ? 356/412 ? 191 ratio from the oleanane peak with that of the pure compounds. 3?-Methyl-24-nor-18?(H)-oleanane can be as abundant as 18?(H)-oleanane in oils having a high concentration of early eluting rearranged oleananes. 3?-Methyl-24-nor-19?(H)-taraxastane was also tentatively assigned in the oils on the basis of its mass spectrum as well as its gas chromatography and high performance liquid chromatography retention times. 3?-Methyl-24-nor-gammacerane was tentatively assigned in a similar way in an oil containing gammacerane. All 3?-methyl-24-nor-triterpanes could be formed via dehydration, rearrangement and hydrogenation of triterpenoids having an OH group at C-3.

Hans Peter Nytoft; Geir Kildahl-Andersen; Tatjana Šolevi? Knudsen; Ksenija Stojanovi?; Frode Rise

2014-01-01T23:59:59.000Z

266

Business Incentive Loans and Bonds (Georgia) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

You are here You are here Home » Business Incentive Loans and Bonds (Georgia) Business Incentive Loans and Bonds (Georgia) < Back Eligibility Agricultural Commercial Construction Developer Fuel Distributor General Public/Consumer Industrial Installer/Contractor Investor-Owned Utility Local Government Municipal/Public Utility Retail Supplier Rural Electric Cooperative Systems Integrator Transportation Utility Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Maximum Rebate Unlimited but generally should not exceed 20% of the asset needs of the company's Gerogia location. Program Info State Georgia Program Type Bond Program Loan Program Provider Georgia Department of Community Affairs The Strategic Industries Loan Fund (SILF) is a program offered by the

267

Fitzgerald Wtr Lgt & Bond Comm | Open Energy Information  

Open Energy Info (EERE)

Fitzgerald Wtr Lgt & Bond Comm Fitzgerald Wtr Lgt & Bond Comm Jump to: navigation, search Name Fitzgerald Wtr Lgt & Bond Comm Place Georgia Utility Id 6380 Utility Location Yes Ownership M NERC Location SERC NERC RFC Yes Activity Distribution Yes Activity Bundled Services Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Utility Rate Schedules Grid-background.png Commercial Commercial Industrial Industrial Residential City Residential Residential Rural Residential Average Rates Residential: $0.1000/kWh Commercial: $0.1140/kWh Industrial: $0.0817/kWh References ↑ "EIA Form EIA-861 Final Data File for 2010 - File1_a"

268

Students' Interdisciplinary Reasoning about "High-Energy Bonds" and ATP  

E-Print Network [OSTI]

Students' sometimes contradictory ideas about ATP (adenosine triphosphate) and the nature of chemical bonds have been studied in the biology and chemistry education literatures, but these topics are rarely part of the introductory physics curriculum. We present qualitative data from an introductory physics course for undergraduate biology majors that seeks to build greater interdisciplinary coherence and therefore includes these topics. In these data, students grapple with the apparent contradiction between the energy released when the phosphate bond in ATP is broken and the idea that an energy input is required to break a bond. We see that students' perceptions of how each scientific discipline bounds the system of interest can influence how they justify their reasoning about a topic that crosses disciplines. This has consequences for a vision of interdisciplinary education that respects disciplinary perspectives while bringing them into interaction in ways that demonstrate consistency amongst the perspectiv...

Dreyfus, Benjamin W; Sawtelle, Vashti; Svoboda, Julia; Turpen, Chandra; Redish, Edward F

2012-01-01T23:59:59.000Z

269

Metal-bonded, carbon fiber-reinforced composites  

DOE Patents [OSTI]

Metal bonded carbon fiber-reinforced composites are disclosed in which the metal and the composite are strongly bound by (1) providing a matrix-depleted zone in the composite of sufficient depth to provide a binding site for the metal to be bonded and then (2) infiltrating the metal into the matrix-free zone to fill a substantial portion of the zone and also provide a surface layer of metal, thereby forming a strong bond between the composite and the metal. The invention also includes the metal-bound composite itself, as well as the provision of a coating over the metal for high-temperature performance or for joining to other such composites or to other substrates.

Sastri, Suri A. (Lexington, MA); Pemsler, J. Paul (Lexington, MA); Cooke, Richard A. (Framingham, MA); Litchfield, John K. (Bedford, MA); Smith, Mark B. (Ipswich, MA)

1996-01-01T23:59:59.000Z

270

Metal-bonded, carbon fiber-reinforced composites  

DOE Patents [OSTI]

Metal bonded carbon fiber-reinforced composites are disclosed in which the metal and the composite are strongly bound by (1) providing a matrix-depleted zone in the composite of sufficient depth to provide a binding site for the metal to be bonded and then (2) infiltrating the metal into the matrix-free zone to fill a substantial portion of the zone and also provide a surface layer of metal, thereby forming a strong bond between the composite and the metal. The invention also includes the metal-bound composite itself, as well as the provision of a coating over the metal for high-temperature performance or for joining to other such composites or to other substrates. 2 figs.

Sastri, S.A.; Pemsler, J.P.; Cooke, R.A.; Litchfield, J.K.; Smith, M.B.

1996-03-05T23:59:59.000Z

271

Reduction of Thermal Conductivity in Wafer-Bonded Silicon  

SciTech Connect (OSTI)

Blocks of silicon up to 3-mm thick have been formed by directly bonding stacks of thin wafer chips. These stacks showed significant reductions in the thermal conductivity in the bonding direction. In each sample, the wafer chips were obtained by polishing a commercial wafer to as thin as 36 {micro}m, followed by dicing. Stacks whose starting wafers were patterned with shallow dots showed greater reductions in thermal conductivity. Diluted-HF treatment of wafer chips prior to bonding led to the largest reduction of the effective thermal conductivity, by approximately a factor of 50. Theoretical modeling based on restricted conduction through the contacting dots and some conduction across the planar nanometer air gaps yielded fair agreement for samples fabricated without the HF treatment.

ZL Liau; LR Danielson; PM Fourspring; L Hu; G Chen; GW Turner

2006-11-27T23:59:59.000Z

272

Bond Amendment, Security Clearances - January 1, 2008 | Department of  

Broader source: Energy.gov (indexed) [DOE]

Bond Amendment, Security Clearances - January 1, 2008 Bond Amendment, Security Clearances - January 1, 2008 Bond Amendment, Security Clearances - January 1, 2008 January 1, 2008 In General.-Title III of the Intelligence Reform and Terrorism Prevention Act of 2004 (50 U.S.C. 435b) is amended by adding at the end the following new section: "SEC. 3002. SECURITY CLEARANCES; LIMITATIONS SEC. 1072. SECURITY CLEARANCES; LIMITATIONS. (a) In General.-Title III of the Intelligence Reform and Terrorism Prevention Act of 2004 (50 U.S.C. 435b) is amended by adding at the end the following new section: "SEC. 3002. SECURITY CLEARANCES; LIMITATIONS. "(a) Definitions.-In this section: "(1) Controlled substance.-The term `controlled substance' has the meaning given that term in section 102 of the Controlled Substances Act (21 U.S.C.

273

Hydrogen Bonds in Crystals. X. The Isotope Effect and Thermal Expansion of Non-Co-Operative Hydrogen Bonds in Furoic Acid  

Science Journals Connector (OSTI)

24 April 1956 research-article Hydrogen Bonds in Crystals. X. The Isotope Effect...Thermal Expansion of Non-Co-Operative Hydrogen Bonds in Furoic Acid J. McC. Pollock...Ubbelohde Ida Woodward Thermal effects in the hydrogen bonds in crystalline furoic acid have...

1956-01-01T23:59:59.000Z

274

Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate  

E-Print Network [OSTI]

Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

Goddard III, William A.

275

High- and low-temperature bonding techniques for microstructures  

SciTech Connect (OSTI)

The ability to bond together two or more silicon wafers greatly expands the variety and complexity of silicon microstructures that can be designed and fabricated. At LLNL, microstructures have been used for many years as hardware in scientific experiments. The activity has recently been expanded into other areas to include microinstruments for biomedical applications and for chemical analysis. Both high temperature (1100{degrees}C) bonding techniques have been used, depending on the application. This paper discusses these applications with emphasis on the most extensive which is the fabrication of microchannel coolers for diode arrays.

Ciarlo, D.R.

1993-06-22T23:59:59.000Z

276

Historical Network Maps  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Publications and Presentations Galleries ESnet Awards and Honors ESnet Live Blog Home Engineering Services The Network Network Maps Historical Network Maps Engineering...

277

Effects of interface bonding and defects on boron diffusion at Si/SiO{sub 2} interface  

SciTech Connect (OSTI)

We perform first-principles density functional calculations to find the migration pathway and barrier for B diffusion at the Si/SiO{sub 2} interface. For various interface models, in which crystalline ?-quartz or amorphous silica (a-SiO{sub 2}) is placed on Si, we examine stable and metastable configurations of B-related defects which play a role in B diffusion. While a substitutional B alone is immobile in Si, it tends to diffuse to the interface via an interstitialcy mechanism in the presence of a self-interstitial and then changes into an interstitial B in oxide via a kick-out mechanism, leaving the self-interstitial at the interface. At the defect-free interface, where bridging O atoms are inserted to remove interface dangling bonds, an interstitial B prefers to intervene between the interface Si and bridging O atoms and subsequently diffuses through the hollow space or along the network of the Si-O-Si bonds in oxide. The overall migration barriers are calculated to be 2.02–2.12?eV at the Si/?-quartz interface, while they lie in the range of 2.04?±?0.44?eV at the Si/a-SiO{sub 2} interface, similar to that in ?-quartz. The migration pathway and barrier are not significantly affected by interface defects such as suboxide bond and O protrusion, while dangling bonds in the suboxide region can increase the migration barrier by about 1.5?eV. The result that the interface generally does not hinder the B diffusion from Si to SiO{sub 2} assists in understanding the underlying mechanism for B segregation which commonly occurs at the Si/SiO{sub 2} interface.

Kim, Geun-Myeong; Oh, Young Jun; Chang, K. J., E-mail: kchang@kaist.ac.kr [Department of Physics, Korea Advanced Institute of Science and Technology, Daejeon 305-701 (Korea, Republic of)

2013-12-14T23:59:59.000Z

278

Network Interventions  

Science Journals Connector (OSTI)

...Identifying influential young people to undertake effective...a network tailored substance abuse prevention program among...Rice, J. E. Katz, The Internet and Health Communication: Experience...National Institute on Alcohol Abuse and Alcoholism). I thank...

Thomas W. Valente

2012-07-06T23:59:59.000Z

279

Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids with small bond angles: Effects of steric hindrance and ring formation  

E-Print Network [OSTI]

In this paper we develop a thermodynamic perturbation theory for two site associating fluids which exhibit bond cooperativity. We include both steric hindrance and ring formation such that the equation of state is bond angle dependent. Here the bond angle is the angle separating the centers of the two association sites. As a test, new Monte Carlo simulations are performed, and the theory is found to accurately predict the internal energy as well as the distribution of associated clusters as a function of bond angle and bond cooperativity.

B. D. Marshall; Amin Haghmoradi; W. G. Chapman

2014-04-03T23:59:59.000Z

280

Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Energy Efficiency Loan Program: Case Study on Saint Louis County, MO Title Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Energy Efficiency Loan Program: Case Study on Saint Louis County, MO Publication Type Policy Brief Authors Zimring, Mark Secondary Title Clean Energy Program Policy Brief Publisher LBNL Place Published Berkeley Year of Publication 2011 Pagination 7 Date Published 06/2011 Abstract Qualified Energy Conservation Bonds (QECBs) are federally-subsidized debt instruments that enable state, tribal, and local government issuers to borrow money to fund a range of qualified energy conservation projects. QECBs offer issuers very attractive borrowing rates and long terms, and can fund low-interest energy efficiency loans for home and commercial property owners. Saint Louis County, MO recently issued over $10 million of QECBs to finance the Saint Louis County SAVES residential energy efficiency loan program. The county's experience negotiating QECB regulations and restrictions can inform future issuers.

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Describing bond graph models of hydraulic components in Modelica  

Science Journals Connector (OSTI)

In this paper we discuss an object oriented description of bond graph models of hydraulic components by means of the unified modeling language Modelica. A library which is still under development is briefly described and models of some standard hydraulic components are given for illustration. In particular we address the modeling of hydraulic orifices.

W. Borutzky; B. Barnard; J.U. Thoma

2000-01-01T23:59:59.000Z

282

Type II halogen???halogen contacts are halogen bonds  

Science Journals Connector (OSTI)

Cl/Br/I alternative substitutions in a series of dihalophenols indicate that type I and type II halogen???halogen contacts have different chemical nature. Only the latter ones qualify as true halogen bonds, according to the recent IUPAC definition.

Metrangolo, P.

2013-12-31T23:59:59.000Z

283

Vibrational Signature of Water Molecules in Asymmetric Hydrogen Bonding Environments  

E-Print Network [OSTI]

Vibrational Signature of Water Molecules in Asymmetric Hydrogen Bonding Environments Chao Zhang contributions of each of the two hydrogen atoms to the vibrational modes 1 and 3 of water molecules the early works on the molecular structure of water, it has been accepted that a water molecule

Guidoni, Leonardo

284

Simulation of an Electrical Substation Using the Bond Graph Technique  

Science Journals Connector (OSTI)

Simulation and especially computer simulation, is a basic tool since it enables engineers to understand how systems work without actually needing to see them. They can learn how they work in different circumstances and optimize their design with considerably ... Keywords: simulation, electrical substations, elements, electricity, bond graph

Gregorio Romero; Jesus Felez; Joaquin Maroto; Jose Manuel Mera

2008-04-01T23:59:59.000Z

285

Structural and bonding trends in platinum-carbon clusters  

E-Print Network [OSTI]

. Trends in stability, Pt+-Cx binding energy, doublet-quartet excitation energy, and Pt-C bond lengths were investigated. Explanations for these patterns are provided in terms of orbital interactions and changes imposed on the carbon-chain by the metal...

Miller, Thomas F

2013-02-22T23:59:59.000Z

286

Bonding and Electronic Properties of Ice at High Pressure  

E-Print Network [OSTI]

between the nearest oxygen atoms. All ice structures that we discussed so far are insulators. Militzer 1 Bonding and Electronic Properties of Ice at High Pressure B. Militzer Department of Earth of water ice at megabar pressure are characterized with ab initio computer simulations. The focus lies

Militzer, Burkhard

287

WHAT'S GRAPHENE? Mono or few layers of sp2 bonded  

E-Print Network [OSTI]

WHAT'S GRAPHENE? · Mono or few layers of sp2 bonded carbon atoms in a honeycomb lattice 105cm2/Vs at RT. 1 Due to its unique transport properties, graphene is suitable for implementation sampling (EOS) timeresolved spectroscopy to optically pump and THz probe exfoliated graphene ribbons (GR

Mellor-Crummey, John

288

Hydrogen Bonding Increases Packing Density in the Protein Interior  

E-Print Network [OSTI]

Hydrogen Bonding Increases Packing Density in the Protein Interior David Schell,1,2 Jerry Tsai,1 J System Health Science Center, College Station, Texas 77843-1114 ABSTRACT The contribution of hydrogen to the stability, but experimental studies show that bury- ing polar groups, especially those that are hydrogen

289

Method of preparation of bonded polyimide fuel cell package  

DOE Patents [OSTI]

Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan (Livermore, CA); Graff, Robert T. (Modesto, CA); Bettencourt, Kerry (Dublin, CA)

2011-04-26T23:59:59.000Z

290

Bonded labour The Dalits of Nepal are a marginalised  

E-Print Network [OSTI]

Bonded labour The Dalits of Nepal are a marginalised group of people who have suffered systematic that, while illegal, is still widespread in remote rural areas of Nepal. To meet their basic needs in their neighbour- hood. Referred to in Nepal as Haliya/ Haruwa and Charuwa, they have to plough the landlords' land

Richner, Heinz

291

Water inertial reorientation: Hydrogen bond strength and the angular potential  

E-Print Network [OSTI]

Water inertial reorientation: Hydrogen bond strength and the angular potential David E. Moilanen) The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy with recent molecular dynamics simulations employing the simple point charge-extended water model at room

Fayer, Michael D.

292

Quantum nuclear effects on surfaces and dispersion bonded systems  

E-Print Network [OSTI]

Quantum nuclear effects on surfaces and dispersion bonded systems Erlend Davidson A dissertation all system types. In particular long range van der Waals dispersion forces and quantum nuclear effects of the art methods to include van der Waals dispersion and quantum nuclear effects on a range of well defined

Guillas, Serge

293

Resummed thermodynamic perturbation theory for bond cooperativity in associating fluids  

E-Print Network [OSTI]

We develop a resummed thermodynamic perturbation theory for bond cooperativity in associating fluids by extension of Wertheim's multi - density formalism. We specifically consider the case of an associating hard sphere with two association sites and both pairwise and triplet contributions to the energy. To test the theory we perform new monte carlo simulations. Theory and simulation are found to be in excellent agreement.

B. D. Marshall; W. G. Chapman

2013-09-18T23:59:59.000Z

294

Concept generation of dynamic systems using bond graphs  

E-Print Network [OSTI]

REPRESENTATIONS OF IMMITTANCES . . . Immittance synthesis in design Conventional immit tance synthesis techniques by Foster and Cauer Immittance synthesis with bond graphs . . . . . . . . . . . . . Example - Synthesis of two frequency absorber... . . . . . . . . . 35 . 35 . 38 . . . . . . 40 . . . . . . 49 TABLE OF CONTENTS (Continued) CHAPTER Page V PHYSICAL REPRESENTATIONS OF TRANSFER FUNCTIONS Transfer function synthesis in design . . . . . . . . . . . General procedure Conditions for passive...

Krishnan, S

1990-01-01T23:59:59.000Z

295

Measuring Interfacial Stiffness of Adhesively-Bonded Wood  

E-Print Network [OSTI]

1 Measuring Interfacial Stiffness of Adhesively-Bonded Wood Edward A. Le FPInnovations - Engineered Wood Products Manufacturing 2665 East Mall Vancouver, BC V6T 1W5 Canada Email: Edward.Le@FPInnovations.ca John A. Nairn Wood Science & Engineering Oregon State University Corvallis, OR 97330, USA Email: John

Nairn, John A.

296

Neural Networks  

SciTech Connect (OSTI)

Physicists use large detectors to measure particles created in high-energy collisions at particle accelerators. These detectors typically produce signals indicating either where ionization occurs along the path of the particle, or where energy is deposited by the particle. The data produced by these signals is fed into pattern recognition programs to try to identify what particles were produced, and to measure the energy and direction of these particles. Ideally, there are many techniques used in this pattern recognition software. One technique, neural networks, is particularly suitable for identifying what type of particle caused by a set of energy deposits. Neural networks can derive meaning from complicated or imprecise data, extract patterns, and detect trends that are too complex to be noticed by either humans or other computer related processes. To assist in the advancement of this technology, Physicists use a tool kit to experiment with several neural network techniques. The goal of this research is interface a neural network tool kit into Java Analysis Studio (JAS3), an application that allows data to be analyzed from any experiment. As the final result, a physicist will have the ability to train, test, and implement a neural network with the desired output while using JAS3 to analyze the results or output. Before an implementation of a neural network can take place, a firm understanding of what a neural network is and how it works is beneficial. A neural network is an artificial representation of the human brain that tries to simulate the learning process [5]. It is also important to think of the word artificial in that definition as computer programs that use calculations during the learning process. In short, a neural network learns by representative examples. Perhaps the easiest way to describe the way neural networks learn is to explain how the human brain functions. The human brain contains billions of neural cells that are responsible for processing information [2]. Each one of these cells acts as a simple processor. When individual cells interact with one another, the complex abilities of the brain are made possible. In neural networks, the input or data are processed by a propagation function that adds up the values of all the incoming data. The ending value is then compared with a threshold or specific value. The resulting value must exceed the activation function value in order to become output. The activation function is a mathematical function that a neuron uses to produce an output referring to its input value. [8] Figure 1 depicts this process. Neural networks usually have three components an input, a hidden, and an output. These layers create the end result of the neural network. A real world example is a child associating the word dog with a picture. The child says dog and simultaneously looks a picture of a dog. The input is the spoken word ''dog'', the hidden is the brain processing, and the output will be the category of the word dog based on the picture. This illustration describes how a neural network functions.

Smith, Patrick I.

2003-09-23T23:59:59.000Z

297

Networking from a network coding perspective  

E-Print Network [OSTI]

Network coding generalizes network operation beyond traditional routing, or store-and-forward, approaches, allowing for mathematical operations across data streams within a network. This thesis considers a number of ...

Ho, Tracey, 1976-

2004-01-01T23:59:59.000Z

298

E-Print Network 3.0 - altered intramolecular hydrogen-bonding...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by strong intramolecular hydrogen ... Source: Balaram , P. - Molecular Biophysics Unit, Indian Institute of Science, Bangalore Collection: Biology and Medicine 47 Layered,...

299

E-Print Network 3.0 - au bonded structures Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of non-helical Au... induce structural transitions between Au(n, n) and Au(2n, n) nanotubes. The corresponding energy barriers... Au(n, n) and Au(2n, n) decreases ......

300

Hydrogen-Bonding Density of Supramolecular Self-Assembled Fibrillar Networks Probed Using Synchrotron Infrared Spectromicroscopy  

Science Journals Connector (OSTI)

Two weight percent samples of 12HSA in each solvent were prepared by heating the mixture to 85 °C for 30 min. ... Light is focused on the sample using a 36× magnification Schwarzschild condenser, collected by a 36× magnification Schwarzschild objective and detected by a liquid nitrogen cooled narrowband MCT detector with a 100 ?m sensing element. ... Interferograms were collected using 256 scans and were recorded by scanning the moving mirror at 40 kHz, to an upper frequency limit of 7899 cm?1 and with a spectral resolution of 4 cm?1. ...

Michael A. Rogers; Tor Pedersen; Luca Quaroni

2009-06-17T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

E-Print Network 3.0 - adhesively bonded joints Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics 53 MIXED-MODE FRACTURE ANALYSES OF PLASTICALLY-DEFORMING ADHESIVE JOINTS Summary: mechanics approach to...

302

E-Print Network 3.0 - adhesive bonded joints Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics 53 MIXED-MODE FRACTURE ANALYSES OF PLASTICALLY-DEFORMING ADHESIVE JOINTS Summary: mechanics approach to...

303

E-Print Network 3.0 - anodically bonded glass-based Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for micro-batteries. Lithium (Li) can be inserted reversibly within most Source: Yang, Eui-Hyeok - Department of Mechanical Engineering, Stevens Institute of Technology...

304

E-Print Network 3.0 - accumulative roll-bonding arb Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

InAs quantum dots: band bending vs Pauli blocking Summary: .3000 0.3500 A B C energy eV intensity arb.units. a) 1.18 1.16 1.14 1.12 1.1 1.08 1.06 1.04 1.02 1 -2......

305

K{sub 6} carbon: A metallic carbon allotrope in sp{sup 3} bonding networks  

SciTech Connect (OSTI)

We identify by first-principles calculations a new cubic carbon phase in I4{sub 1}32 (O{sup 8}) symmetry, named K{sub 6} carbon, which has a six atom primitive cell comprising sp{sup 3} hybridized C{sub 3} triangle rings. The structural stability is verified by phonon mode analysis. The calculated elastic constants show that the K{sub 6} carbon is a high ductile material with a density even lower than graphite. Electronic band and density of states calculations reveal that it is a metallic carbon allotrope with a high electronic density of states of ?0.10 states/eV per atom at the Fermi level. These results broaden our understanding of the structural and electronic properties of carbon allotropes.

Niu, Chun-Yao; Wang, Xin-Quan; Wang, Jian-Tao, E-mail: wjt@aphy.iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

2014-02-07T23:59:59.000Z

306

E-Print Network 3.0 - alkyl-alkyl bond formation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Molecular Physics, Vol. 105, Nos. 23, 20 January10 February 2007, 261272 Summary: -SAFT-VR approach In the SAFT-VR approach molecules are modelled as chains of tangentially...

307

Network Connections  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Connecting to NERSC Using X Windows Connecting to NERSC with NX Transferring Data Network Performance Queues and Scheduling Job Logs & Analytics Training & Tutorials Software Accounts & Allocations Policies Data Analytics & Visualization Data Management Policies Science Gateways User Surveys NERSC Users Group User Announcements Help Operations for: Passwords & Off-Hours Status 1-800-66-NERSC, option 1 or 510-486-6821 Account Support https://nim.nersc.gov accounts@nersc.gov 1-800-66-NERSC, option 2 or 510-486-8612 Consulting http://help.nersc.gov consult@nersc.gov 1-800-66-NERSC, option 3 or 510-486-8611 Home » For Users » Network Connections Network Connections NERSC's resources can be accessed using SSH and related tools, grid tools, and via the web. This section explains how to connect to NERSC

308

Role of interatomic bonding in the mechanical anisotropy and interlayer cohesion of CSH crystals  

SciTech Connect (OSTI)

Atomic scale properties of calcium silicate hydrate (CSH), the main binding phase of hardened Portland cement, are not well understood. Over a century of intense research has identified almost 50 different crystalline CSH minerals which are mainly categorized by their Ca/Si ratio. The electronic structure and interatomic bonding in four major CSH crystalline phases with structures close to those found in hardened cement are investigated via ab initio methods. Our result reveals the critical role of hydrogen bonding and importance of specifying precise locations for water molecules. Quantitative analysis of contributions from different bond types to the overall cohesion shows that while the Si-O covalent bonds dominate, the hydrogen bonding and Ca-O bonding are also very significant. Calculated results reveal the correlation between bond topology and interlayer cohesion. The overall bond order density (BOD) is found to be a more critical measure than the Ca/Si ratio in classifying different CSH crystals.

Dharmawardhana, C.C. [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)] [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States); Misra, A. [Department of Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045 (United States)] [Department of Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045 (United States); Aryal, S.; Rulis, P. [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)] [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States); Ching, W.Y., E-mail: ccdxz8@mail.umkc.edu [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)

2013-10-15T23:59:59.000Z

309

Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion Batteries: A XANES Study. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion...

310

Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). Abstract: We investigated methanol adsorption and dissociation on...

311

Experimental method to find weak bond distribution functions in a high-temperature superconductor  

Science Journals Connector (OSTI)

A simple phenomenological model of a weakly bonded superconductor is suggested. The model considers the transition from a single weak dangling bond to a disruptive two-dimensional structure in taking the I–V char...

M. A. Vasyutin

2013-11-01T23:59:59.000Z

312

Hydrogen Bonding Interactions Between Ions: A Powerful Tool in Molecular Crystal Engineering  

Science Journals Connector (OSTI)

Hydrogen bonding interactions are the strongest of the non-covalent interactions and are highly directional (hence transportable and reproducible). With respect to hydrogen bonds between neutral molecules the hyd...

Dario Braga; Lucia Maini; Marco Polito…

2004-01-01T23:59:59.000Z

313

Hydrogen Bonding, H-D Exchange, and Molecular Mobility in Thin...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bonding, H-D Exchange, and Molecular Mobility in Thin Water Films on TiO2(110). Hydrogen Bonding, H-D Exchange, and Molecular Mobility in Thin Water Films on TiO2(110). Abstract:...

314

Bond County, Illinois: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Bond County, Illinois: Energy Resources Bond County, Illinois: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 38.902985°, -89.4742177° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":38.902985,"lon":-89.4742177,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

315

Wafer bonded virtual substrate and method for forming the same  

DOE Patents [OSTI]

A method of forming a virtual substrate comprised of an optoelectronic device substrate and handle substrate comprises the steps of initiating bonding of the device substrate to the handle substrate, improving or increasing the mechanical strength of the device and handle substrates, and thinning the device substrate to leave a single-crystal film on the virtual substrate such as by exfoliation of a device film from the device substrate. The handle substrate is typically Si or other inexpensive common substrate material, while the optoelectronic device substrate is formed of more expensive and specialized electro-optic material. Using the methodology of the invention a wide variety of thin film electro-optic materials of high quality can be bonded to inexpensive substrates which serve as the mechanical support for an optoelectronic device layer fabricated in the thin film electro-optic material.

Atwater, Jr., Harry A. (So. Pasadena, CA); Zahler, James M. (Pasadena, CA); Morral, Anna Fontcuberta i (Paris, FR)

2007-07-03T23:59:59.000Z

316

Characterization of Fuel-Cladding Bond Strength Using Laser Shock  

SciTech Connect (OSTI)

This paper describes new laser-based capabilities for characterization of fuel-cladding bond strength in nuclear fuels, and presents preliminary results obtained from studies on as-fabricated monolithic fuel consisting of uranium-10 wt.% molybdenum alloys clad in 6061 aluminum by hot isostatic pressing. Two complementary experimental methods are employed, laser-shock testing and laser-ultrasonic imaging. Measurements are spatially localized, non-contacting and require minimum specimen preparation, and are therefore ideally suited for applications involving radioactive materials, including irradiated materials. The theoretical principles and experimental approaches employed in characterization of nuclear fuel plates are described. The ability to measure layer thicknesses, elastic properties of the constituents, and the location and nature of laser-shock induced debonds is demonstrated, and preliminary bond strength measurement results are discussed.

James A. Smith; David L. Cottle; Barry H. Rabin

2014-04-01T23:59:59.000Z

317

Bond strength and stress measurements in thermal barrier coatings  

SciTech Connect (OSTI)

Thermal barrier coatings have been used extensively in aircraft gas turbines for more than 15 years to insulate combustors and turbine vanes from the hot gas stream. Plasma sprayed thermal barrier coatings (TBCs) provide metal temperature reductions as much as 300{degrees}F, with improvements in durability of two times or more being achieved. The introduction of TBCs deposited by electron beam physical vapor deposition (EB-PVD) processes in the last five years has provided a major improvement in durability and also enabled TBCs to be applied to turbine blades for improved engine performance. This program evaluates the bond strength of yttria stabilized zirconia coatings with MCrAlY and Pt-Al bond coats utilizing diffraction and fluorescence methods.

Gell, M.; Jordan, E.

1995-12-31T23:59:59.000Z

318

Effect of nuclear ownership on utility bond ratings and yields  

SciTech Connect (OSTI)

The major objective of this study was to test the hypothesis that investors have required an additional interest rate premium before purchasing bonds of utilities with large investments in nuclear facilities. The study required several tasks. First, the literature relating to firm bankruptcy and default was reviewed. Second, the failing financial health of the electric utility industry was assessed in terms of construction problems, the impact of federal and state regulations, and the impact of Three Mile Island. Finally, data were collected on 63 electric utilities. This allowed statistical estimation of the magnitude of the risk premium associated with utility involvement in nuclear power. The effect of this involvement on a utility's bond ratings was also examined. Multiple regression was the statistical tool used for the statistical testing and estimation.

Nesse, R.J.

1982-02-01T23:59:59.000Z

319

Performance and Reliability of Bonded Interfaces for High-Temperature Packaging (Presentation)  

SciTech Connect (OSTI)

This presentation reviews the status of the performance and reliability of bonded interfaces for high-temperature packaging.

Devoto, D.

2014-06-01T23:59:59.000Z

320

Human-animal interactions, relationships and bonds: a review and analysis of the literature  

E-Print Network [OSTI]

human-animal bond: health implications across the lifespan.H. (2012). Mental health implications of human attachment to

Hosey, Geoff; Melfi, Vicky

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Analytically solvable geometric network growth model with arbitrary degree distribution  

E-Print Network [OSTI]

We construct a class of network growth models capable of producing arbitrary degree distributions. The conditions necessary for generating the desired degree distribution can be derived analytically. In this model, a network is generated as a result of local interactions among agents residing on a metric space. Specifically, we study the case of random-walking agents who form bonds when they meet at designated locations we refer to as "rendezvous points." The spatial distribution of the rendezvous points determines key characteristics of the network such as the degree distribution. For any arbitrary (monotonic) degree distribution, we are able to analytically solve for the required rendezvous point distribution. Certain features of the model including high clustering coefficients suggest that it may be a suitable candidate for modeling biological and urban networks.

Dianati, Navid

2015-01-01T23:59:59.000Z

322

Tourism networks and computer networks  

E-Print Network [OSTI]

The body of knowledge accumulated in recent years on the structure and the dynamics of complex networks has offered useful insights on the behaviour of many natural and artificial complex systems. The analysis of some of these, namely those formed by companies and institutions, however, has proved problematical mainly for the difficulties in collecting a reasonable amount of data. This contribution argues that the World Wide Web can provide an efficient and effective way to gather significant samples of networked socio-economic systems to be used for network analyses and simulations. The case discussed refers to a tourism destination, the fundamental subsystem of an industry which can be considered one of the most important in today's World economy.

Baggio, Rodolfo

2008-01-01T23:59:59.000Z

323

Flip chip electrical interconnection by selective electroplating and bonding  

E-Print Network [OSTI]

on a glass substrate made of 500/2000 A° of Cr/Au with 3150 lm in length and 10 lm in width. Two silicon. The interconnection chip has 102 Cr/Au interconnection lines with 3150 lm in length and 10 lm in width. The bonding pads on the ends of the interconnection lines are 40 lm by 40 lm. A 0.8 lm thick layer of aluminum

Lin, Liwei

324

Compacting Plastic-Bonded Explosive Molding Powders to Dense Solids  

SciTech Connect (OSTI)

Dense solid high explosives are made by compacting plastic-bonded explosive molding powders with high pressures and temperatures for extended periods of time. The density is influenced by manufacturing processes of the powders, compaction temperature, the magnitude of compaction pressure, pressure duration, and number of repeated applications of pressure. The internal density variation of compacted explosives depends on method of compaction and the material being compacted.

B. Olinger

2005-04-15T23:59:59.000Z

325

Quantum Confinement in Hydrogen Bond of DNA and RNA  

E-Print Network [OSTI]

The hydrogen bond is a fundamental ingredient to stabilize the DNA and RNA macromolecules. The main contribution of this work is to describe quantitatively this interaction as a consequence of the quantum confinement of the hydrogen. The results for the free and confined system are compared with experimental data. The formalism to compute the energy gap of the vibration motion used to identify the spectrum lines is the Variational Method allied to Supersymmetric Quantum Mechanics.

Santos, da Silva dos; Ricotta, Regina Maria

2015-01-01T23:59:59.000Z

326

A Very Short Ruthenium(II) - Nitrogen Heterocycle Bond  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Very Short Ruthenium(II) - Nitrogen Heterocycle Bond: The Crystal Very Short Ruthenium(II) - Nitrogen Heterocycle Bond: The Crystal Structures of Pentaammine(N-methylpyrazinium)ruthenium(II) Iodide and Pentaammine(N-methylpyrazinium)ruthenium(III) p-Toluenesulfonate Pentahydrate James F. Wishart, Avi Bino and Henry Taube Inorg. Chem. 25, 3318-3321 (1986) Abstract: The crystal structures of [(NH3)5Ru(NC4H4NCH3)] I3 and [(NH3)5Ru(NC4H4NCH3)] (CH3C6H4SO3)4°5H2O have been solved to weighted R factors of 0.053 and 0.083, respectively. For the former structure, the space group is Pmma with a = 10.655(2)Å, b = 7.704(1)Å, c = 21.488(3)Å, and Z = 4. The Ru(II)-N(Mepyz) distance of 1.95(1)Å in this complex is the shortest yet reported for a ruthenium(II) to heteroctclic nitrogen bond. A difference of 0.04(1)Å between the cis (2.122(7)Å and 2.136(8)Å) and

327

Scanning white light interferometry in quality control of single-point tape automated bonding  

Science Journals Connector (OSTI)

We report on applying a scanning white light interferometry (SWLI) for quality control of aluminum lead single-point tape automated bonding (spTAB). A spTAB process was used to connect Al leads on a thin polyimide flex to Al bond pads on a flexible Al-polyimide ... Keywords: Bonding, Interferometry

Ivan Vl. Kassamakov; Henri O. Seppänen; Markku J. Oinonen; Edward O. Híggström; J. Mathias Österberg; Juha P. Aaltonen; Heimo Saarikko; Zoran P. Radivojevic

2007-01-01T23:59:59.000Z

328

AN INVESTIGATION OF THE BONDING AT THE CONCRETE POLYMER COMPOSITE INTERFACE  

E-Print Network [OSTI]

AN INVESTIGATION OF THE BONDING AT THE CONCRETE POLYMER COMPOSITE INTERFACE Wai How Soong, S, USA. ABSTRACT Bonding between the concrete and polymer composite (reinforcement) tendon was studied) and surface roughness of composite reinforcement tendons on the two types of bond strengths were investigated

329

Bonding in Sodium Chloride Nanotubes: A New Analysis via Madelung Constants and Cohesive Energies  

E-Print Network [OSTI]

1 Bonding in Sodium Chloride Nanotubes: A New Analysis via Madelung Constants and Cohesive Energies is introduced which employs a linear relationship between nanotube cohesive energies determined via Density between ionic and cohesive bonding energies indicate that, as the nanotubes become longer, ionic bonding

Hanusa, Christopher

330

Improved Enantioselective Synthesis of (?)-Linderol A: Hindered Rotation about Aryl?Csp3 Bond  

Science Journals Connector (OSTI)

Improved Enantioselective Synthesis of (?)-Linderol A: Hindered Rotation about Aryl?Csp3 Bond ... (11) In general, Ar?Csp3 bonds have very low rotation barriers. ... Atropisomerism about Aryl–Csp3 Bonds: The Electronic and Steric Influence of ortho-Substituents on Conformational Exchange in Cannabidiol and Linderatin Derivatives ...

Pierre-Olivier Delaye; Pedro Lameiras; Nelly Kervarec; Catherine Mirand; Hatice Berber

2010-03-24T23:59:59.000Z

331

5750 J. Am. Chem. SOC.1990, 112, 5750-5759 Bond Strengths of Ethylene and Acetylene  

E-Print Network [OSTI]

5750 J. Am. Chem. SOC.1990, 112, 5750-5759 Bond Strengths of Ethylene and Acetylene Kent M. Ervin-phase proton transfer kinetics were employed to determine the CH bond dissociationenergiesof acetylene,ethylene-H) = 81.0f 3.5 kcal mol-'. The strengths of each of the other CH and CC bonds in acetylene and ethylene

Ellison, Barney

332

Molecular surface electrostatic potentials in the analysis of non-hydrogen-bonding noncovalent interactions  

SciTech Connect (OSTI)

Electrostatic potentials computed on molecular surfaces are used to analyze some noncovalent interactions that are not in the category of hydrogen bonding, e.g. halogen bonding. The systems examined include halogenated methanes, substituted benzenes, s-tetrazine and 1,3-bisphenylurea. The data were obtained by ab initio SCF calculations. Electrostatic potentials, Non-hydrogen-bonding noncovalent interactions, Molecular surfaces.

Murray, J.S.; Paulsen, K.; Politzer, P.

1993-12-27T23:59:59.000Z

333

The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis  

E-Print Network [OSTI]

The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis of the Molecular of hydrogen-bondformation between guanine (G) and cytusine (C) in o-dichloro- benzene and in chloroformat 25°C forming hydrogen bonds. Consequently, hydrogen-bond formation in our system is primarily between the bases

Williams, Loren

334

Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation spectroscopy  

E-Print Network [OSTI]

Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation September 2003 Hydrogen bond population dynamics are extricated with exceptional detail using ultrafast ( 50 of methanol­OD oligomers in CCl4 . Hydrogen bond breaking makes it possible to acquire data for times much

Fayer, Michael D.

335

Hydrogen bond dynamics in membrane protein function Ana-Nicoleta Bondar a,  

E-Print Network [OSTI]

Review Hydrogen bond dynamics in membrane protein function Ana-Nicoleta Bondar a, , Stephen H 30 November 2011 Available online 8 December 2011 Keywords: Membrane protein structure Hydrogen bond Membrane protein dynamics Lipid­protein interactions Changes in inter-helical hydrogen bonding

White, Stephen

336

Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation  

E-Print Network [OSTI]

Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

Fayer, Michael D.

337

Hydrogen bond dynamics in the active site of photoactive yellow protein  

E-Print Network [OSTI]

Hydrogen bond dynamics in the active site of photoactive yellow protein Paul A. Sigala, Mark A for review February 5, 2009) Hydrogen bonds play major roles in biological structure and function. Nonetheless, hydrogen-bonded protons are not typically observed by X-ray crystallography, and most structural

Herschlag, Dan

338

Native Hydrogen Bonds in a Molten Globule: The Apoflavodoxin Thermal Intermediate  

E-Print Network [OSTI]

Native Hydrogen Bonds in a Molten Globule: The Apoflavodoxin Thermal Intermediate Marõ�a P. Iru�n1 in surface- exposed hydrogen bonds connecting secondary-structure elements in the native protein. All hydrogen bonds analysed are formed in the molten globule intermediate, either with native strength

Sancho, Javier

339

Energy-based analysis of biochemical cycles using bond graphs  

Science Journals Connector (OSTI)

...7 a shows the response of the amount...increases or the frequency of the input...require free-energy transduction...networks to derive frequency responses with respect...electrochemical energy storage: electrical...

2014-01-01T23:59:59.000Z

340

Effects of surface treatment on the bonding quality of wafer-level Cu-to-Cu thermo-compression bonding for 3D integration  

Science Journals Connector (OSTI)

Various surface treatments are applied for surface oxide removal prior to wafer-level Cu-to-Cu thermo-compression bonding and the bonding quality is systematically analyzed in this work. Three methods are investigated: self-assembled monolayer (SAM) passivation, forming gas annealing and acetic acid wet cleaning. The surface conditions are carefully examined including roughness, contact angle and x-ray photoelectron spectroscopy (XPS) scan. The wafer pairs are bonded at 250??C under a bonding force of 5500?N for a duration of 1?h in a vacuum environment. The bonding medium consists of a Cu (300?nm) bonding layer and a Ti (50?nm) barrier layer. The bonding quality investigation consists of two parts: hermeticity based on helium leak test and mechanical strength using four-point bending method. Although all samples under test with different surface treatment methods present an excellent hermetic seal and a robust mechanical support, the measurement results show that samples bonded after SAM passivation exhibit the best hermeticity and bonding strength for 3D integration application.

J Fan; D F Lim; C S Tan

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Macroscale Properties of Porous Media from a Network Model of Bio lm Processes  

E-Print Network [OSTI]

Macroscale Properties of Porous Media from a Network Model of Bio#12;lm Processes Brian J. Suchomel porosity and permeability changes in a porous medium as a result of bio#12;lm buildup in the pore spaces. A bio#12;lm consists of bacteria and extracellular polymeric substances (EPS) bonded together

342

EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel |  

Broader source: Energy.gov (indexed) [DOE]

306: Treatment and Management of Sodium-Bonded Spent Nuclear 306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel Summary This EIS evaluates the potential environmental impacts of the proposed electrometallurgical treatment of DOE-owned sodium bonded spent nuclear fuel in the Fuel Conditioning Facility at Argonne National Laboratory-West (ANL-W). Public Comment Opportunities None available at this time. Documents Available for Download September 19, 2000 EIS-0306: Record of Decision Treatment and Management of Sodium-Bonded Spent Nuclear Fuel July 1, 2000 EIS-0306: Final Environmental Impact Statement Treatment and Management of Sodium-Bonded Spent Nuclear Fuel July 1, 1999 EIS-0306: Draft Environmental Impact Statement Treatment of Sodium-Bonded Spent Nuclear Fuel

343

Hybrid artificial neural network  

Science Journals Connector (OSTI)

Artificial neural networks (ANNs) or simply neural networks (NNs) are now a consolidated technique ... , and simulate the behavior of the biological neural network in a human brain. For that purpose ... use a sta...

Nadia Nedjah; Ajith Abraham; Luiza M. Mourelle

2007-05-01T23:59:59.000Z

344

Artificial Neural Network  

Science Journals Connector (OSTI)

An artificial neural network (with acronym ANN), usually addressed as neural network (with acronym NN), is a model ... the structure and/or functional aspects of biological neural networks or human brain. A neural

Dr. Gómez González Daniel

2013-01-01T23:59:59.000Z

345

Science-Driven Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science-Driven Network Requirements for ESnet Update to the 2002 Office of Science Networking Requirements Workshop Report February 21, 2006 1-1 Science-Driven Network Requirements...

346

Book Review of Introduction to Bonding and Hybridization Theory  

Science Journals Connector (OSTI)

Book Review of Introduction to Bonding and Hybridization Theory ... I had never really thought about this before (the standard textbook figure showing electronegativities omits the noble gases), but is it true noble gases do not have electronegativity values, or simply that textbooks have redrawn the figure from Pauling’s work, which predates the discovery of compounds with xenon? ... I plan to use these DVDs (particularly Hybridization Theory) in future classes, especially where the repeated shifting between two- and three-dimensional representations and the 360° rotations of molecules will help students immensely. ...

Scott Smidt

2010-11-03T23:59:59.000Z

347

Overlap population density as an index of bond strength  

E-Print Network [OSTI]

be eliminated. This is done by carrying out an orthogonal transformdtion on b, witn a known matrix U, viz. D = UAU' (10) Next~ M is constructed vis, the equation: M=V'D 'U (11) M transforms b to the unit matrix X: (12) Since: I ~1 MdM = U 'D PhU 'D U... on molecules of the same chemical i'amily as those under study, viz, R2-NN02, D. Thermal Decomposition of Nitramides Although estimates of the energies of bonds other than N-N, B?G. Gowcnlock, P. Jones and J. R. Majer~ Trans. Faraday Soc. ~7 23 (1981) RE...

Gallagher, Michael James

2012-06-07T23:59:59.000Z

348

Chemical bond and entanglement of electrons in the hydrogen molecule  

E-Print Network [OSTI]

We theoretically investigate the quantum correlations (in terms of concurrence of indistinguishable electrons) in a prototype molecular system (hydrogen molecule). With the assistance of the standard approximations of the linear combination of atomic orbitals and the con?guration interaction methods we describe the electronic wavefunction of the ground state of the H2 molecule. Moreover, we managed to ?find a rather simple analytic expression for the concurrence (the most used measure of quantum entanglement) of the two electrons when the molecule is in its lowest energy. We have found that concurrence does not really show any relation to the construction of the chemical bond.

Nikos Iliopoulos; Andreas F. Terzis

2014-08-01T23:59:59.000Z

349

ASCR Science Network Requirements  

E-Print Network [OSTI]

ASCR Science Network Requirements Office of AdvancedScientific Computing Research, DOE Office of ScienceEnergy Sciences Network Gaithersburg, MD — April 15 and 16,

Dart, Eli

2010-01-01T23:59:59.000Z

350

BES Science Network Requirements  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Basic Energy Sciences Network Requirements Workshop Conducted June 4-5, 2007 BES Science Network Requirements Workshop Basic Energy Sciences Program Office, DOE Office of...

351

Energy Efficient Networks  

Science Journals Connector (OSTI)

Optical networks are at the center of efforts to achieve sustainable Internet growth. Techniques for modeling energy use in networks are reviewed along with results of recent research...

Kilper, Dan

352

Nitrogen-tuned bonding mechanism of Li and Ti adatom embedded graphene  

SciTech Connect (OSTI)

The effects of nitrogen defects on the bonding mechanism and resultant binding energy between the metal and graphene layer were investigated using density functional theory (DFT) calculations. For the graphitic N-doped graphene, Li adatom exhibited ionic bonding character, while Ti adatom showed features of covalent bonding similar to that of pristine graphene. However, in the cases of pyridinic and pyrrolic structures, partially covalent bonding characteristic occurred around N atoms in the process of binding with metals, and this particular bond formation enhanced the bond strength of metal on the graphene layer as much as it exceeded the cohesive energy of the metal bulk. Thus, Li and Ti metals are expected to be dispersed with atomic accuracy on the pyridinic and pyrrolic N-doped graphene layers. These results demonstrate that the bonding mechanism of metal–graphene complex can change according to the type of N defect, and this also affects the binding results. - Graphical abstract: Display Omitted - Highlights: • Nitrogen defects changed the bonding mechanism between metal and graphene. • Bonding character and binding results were investigated using DFT calculations. • Covalent bonding character occurred around pyridinic and pyrrolic N-doped graphene. • Pyridinic and pyrrolic N atoms are effective for metal dispersion on the graphene.

Lee, Sangho; Chung, Yong-Chae, E-mail: yongchae@hanyang.ac.kr

2013-09-15T23:59:59.000Z

353

Network coding for robust wireless networks  

E-Print Network [OSTI]

Wireless networks and communications promise to allow improved access to services and information, ubiquitous connectivity, and mobility. However, current wireless networks are not well-equipped to meet the high bandwidth ...

Kim, MinJi, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

354

Neural Networks:Neural Networks: Modeling ApplicationsModeling Applications  

E-Print Network [OSTI]

and/or integral equations representing mathematical model of a given physical process. The coefficients of these equations must be exactly known as they are used to program/adjust the coefficient inherent in analog differentiation the [differential] equation is rearranged so that it can be solved

Petriu, Emil M.

355

RDP Neural Network RDP Neural Network Construction Principle  

E-Print Network [OSTI]

for building RDP Neural Networks Geometrical Approaches for Artificial Neural Networks David Elizondo Centre Elizondo Geometrical Approaches for Artificial Neural Networks #12;RDP Neural Network RDP Neural Network David Elizondo Geometrical Approaches for Artificial Neural Networks #12;RDP Neural Network RDP Neural

Gorban, Alexander N.

356

Dynamic NetworksDynamic Networks ApplicationsApplications  

E-Print Network [OSTI]

Satellite Constellation Network #12;Satellite and Undersea Cable Networks #12;Energy NetworksEnergy Networks Electric Power Network #12;Duke Energy Gas Pipeline Network #12;Components of Some Common Physical Networks Roads, Airline Routes, Railroad Track Automobiles, Trains, and Planes, Manufacturing and logistics

Nagurney, Anna

357

NREL-Low-Cost Financing with Clean Renewable Energy Bonds Webinar | Open  

Open Energy Info (EERE)

NREL-Low-Cost Financing with Clean Renewable Energy Bonds Webinar NREL-Low-Cost Financing with Clean Renewable Energy Bonds Webinar Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Low-Cost Financing with Clean Renewable Energy Bonds Agency/Company /Organization: National Renewable Energy Laboratory Partner: United States Department of Energy Sector: Energy Topics: Finance Resource Type: Webinar, Training materials, Lessons learned/best practices Website: www.nrel.gov/applying_technologies/state_local_activities/webinar_2009 Low-Cost Financing with Clean Renewable Energy Bonds Screenshot References: Low-Cost Financing with Clean Renewable Energy Bonds[1] Logo: Low-Cost Financing with Clean Renewable Energy Bonds Sponsored by the U.S. Department of Energy Technical Assistance Project for state and local officials, this Webinar described the elements of clean

358

Dynamics of Weak, Bifurcated and Strong Hydrogen Bonds in Lithium Nitrate Trihydrate  

SciTech Connect (OSTI)

The properties of three distinct types of hydrogen bonds, namely a weak, a bifurcated and a strong one, all present in/the LiNO3 (HDO)(D2O)2 hydrate lattice unit cell are studied using steady-state and time-resolved spectroscopy. The lifetimes of the OH stretching vibrations for the three individual bonds are 2.2 ps (weak), 1.7 ps (bifurcated), and 1.2 ps (strong), respectively. For the first time the properties of bifurcated H bonds can thus be unambiguously directly compared to those of weak and strong H bonds in the same system. The values of their OH stretching vibration lifetime, anharmonicity, red shift and bond strength lie between those for the strong and weak H bonds. The experimentally observed inhomogeneous broadening of their spectral signature is attributed to the coupling with a low frequency intermolecular wagging vibration/

Werhahn, Jasper C.; Pandelov, S.; Xantheas, Sotiris S.; Iglev, H.

2011-07-07T23:59:59.000Z

359

Knowledge-based model of hydrogen-bonding propensity in organic crystals  

Science Journals Connector (OSTI)

A new method is presented to predict which donors and acceptors form hydrogen bonds in a crystal structure, based on the statistical analysis of hydrogen bonds in the Cambridge Structural Database. The approach has potential application in identifying both likely and unusual hydrogen bonding, which can help to rationalize stable and metastable crystalline forms, of relevance to the drug development process in the pharmaceutical industry.

Galek, P.T.A.

2007-09-14T23:59:59.000Z

360

Three Hydrogen Bond Donor Catalysts: Oxyanion Hole Mimics and Transition State Analogues  

SciTech Connect (OSTI)

Enzymes and their mimics use hydrogen bonds to catalyze chemical transformations. Small molecule transition state analogs of oxyanion holes are characterized by gas phase IR and photoelectron spectroscopy and their binding constants in acetonitrile. As a result, a new class of hydrogen bond catalysts is proposed (OH donors that can contribute three hydrogen bonds to a single functional group) and demonstrated in a Friedel-Crafts reaction.

Beletskiy, Evgeny V.; Schmidt, Jacob C.; Wang, Xue B.; Kass, Steven R.

2012-11-14T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

A CH O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices  

E-Print Network [OSTI]

A C­H· · ·O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices of Science Bangalore 560012, India The serendipitous observation of a C­H· · ·O hydrogen bond mediated­N hydrogen bond involving the side- chain of residue T 2 4 and the N­H group of residue T þ 3. In as many

Babu, M. Madan

362

Network Algorithms (Lecture Notes)  

E-Print Network [OSTI]

Network Algorithms (Lecture Notes) Dr. Stefan Schmid Thanks to Prof. Dr. Roger Wattenhofer and Prof to the Network Algorithms course! Computer systems are becoming more distributed and networked. This has two main, in order to fully exploit the distributed resource network, efficient algorithms need to be designed

Schmid, Stefan

363

Professional Networking Michelle Burdick  

E-Print Network [OSTI]

Development Green Sustainability Professionals #12;How To Use LinkedIn Groups Group Discussions: ­ Members can Environmental Careers Network GIS Professional & Networking Green Jobs & Career Network Sustainable EnergyLinkedIn Professional Networking Workshop Michelle Burdick 24 January 2014 #12;· Building a Strong

Awtar, Shorya

364

Networks, Information & Social Capital  

E-Print Network [OSTI]

This paper investigates how information flows enable social networks to constitute social capital. By analyzing

Aral, Sinan

2008-01-26T23:59:59.000Z

365

Making it Easier to Complete Clean Energy Projects with Qualified Energy Conservation Bonds (QECBs)  

Broader source: Energy.gov [DOE]

This presentation, given through the DOE's Technical Assitance Program (TAP), provides information on How to to Complete Clean Energy Projects with Qualified Energy Conservation Bonds (QECBs)

366

Bond strength of steel hollow sections using carbon fibre reinforced polymer composites.  

E-Print Network [OSTI]

??This research was a step forward in developing bond strength of CFRP strengthened steel hollow sections under tension loads. The studies have revealed the ultimate… (more)

Shahanara, Kaniz

2013-01-01T23:59:59.000Z

367

Liquid Metal Bond for Improved Heat Transfer in LWR Fuel Rods  

SciTech Connect (OSTI)

A liquid metal (LM) consisting of 1/3 weight fraction each of Pb, Sn, and Bi has been proposed as the bonding substance in the pellet-cladding gap in place of He. The LM bond eliminates the large AT over the pre-closure gap which is characteristic of helium-bonded fuel elements. Because the LM does not wet either UO2 or Zircaloy, simply loading fuel pellets into a cladding tube containing LM at atmospheric pressure leaves unfilled regions (voids) in the bond. The HEATING 7.3 heat transfer code indicates that these void spaces lead to local fuel hot spots.

Donald Olander

2005-08-24T23:59:59.000Z

368

Investigation of Bonding Mechanism of Coking on Semi-coke from Lignite with Pitch and Tar  

Science Journals Connector (OSTI)

Investigation of Bonding Mechanism of Coking on Semi-coke from Lignite with Pitch and Tar ... Study on the coking mechanism of coal and coal tar pitches. ...

Vedat Arslan

2006-08-16T23:59:59.000Z

369

A study of the bond characteristics of concrete reinforcing bars coated with epoxy compounds  

E-Print Network [OSTI]

Selected Refe~ ces. Appendix - A . 12 . 20 . 22 . 24 . 25 LIST OF TABLES Table Page Bond Stress at Slip of 0. 01 in. at Loaded End of the Bar . . . . 13 Bond Stress at Slip of 0. 001 in. at Free End of the Bar. . 14 A-1 Bond Stress and Steel.... SUMMARY A number of processes by which the steel-concrete bond can be improved are described. The procedures involve coating steel with a versamid epoxy compound and either casting the concrete around the treated reinforcement before the epoxy hardens...

Desai, Indravadan S

1964-01-01T23:59:59.000Z

370

Weird Oxygen Bonding under Pressure | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Breakthrough in Improving Osteoporosis Drug Design A Breakthrough in Improving Osteoporosis Drug Design Allaying Structural-Alloy Corrosion Putting the Pressure on MOFs Newly Described "Dragon" Protein Could Be Key to Bird Flu Cure Hearing the Highest Pitches Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Weird Oxygen Bonding under Pressure AUGUST 8, 2008 Bookmark and Share Schematic shows the topology of π* orbital interactions in the (O2)4 cluster. (Image copyright National Academy of Sciences, PNAS.) Oxygen, the third most abundant element in the cosmos and essential to life on Earth, changes its forms dramatically under pressure, transforming to a solid with spectacular colors. Eventually it becomes metallic and a

371

Method of making bonded or sintered permanent magnets  

DOE Patents [OSTI]

An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density. 14 figs.

McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

1995-11-28T23:59:59.000Z

372

Bond fluctuation method for a polymer undergoing gel electrophoresis  

Science Journals Connector (OSTI)

We present a computational methodology for the investigation of gel electrophoresis of polyelectrolytes. We have developed the method initially to incorporate sliding motion of tight parts of a polymer pulled by an electric field into the bond fluctuation method (BFM). Such motion due to tensile force over distances much larger than the persistent length is realized by nonlocal movement of a slack monomer at either end of the tight part. The latter movement is introduced stochastically. This new BFM overcomes the well-known difficulty in the conventional BFM that polymers are trapped by gel fibers in relatively large fields. At the same time it also reproduces properly equilibrium properties of a polymer in a vanishing field limit. The new BFM thus turns out to be an efficient computational method to study gel electrophoresis in a wide range of the electric field strength.

Ryuzo Azuma and Hajime Takayama

1999-01-01T23:59:59.000Z

373

Method of making bonded or sintered permanent magnets  

DOE Patents [OSTI]

An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density.

McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

1993-08-31T23:59:59.000Z

374

Complexes of niobium and tantalum containing metal-metal bonds  

SciTech Connect (OSTI)

A new entry into the area of low valent niobium and tantalum complexes containing metal-metal bonds is described. M/sub 2/X/sub 6/ (..mu..-THT)(THF)/sub 2/ complexes, where M = Nb or Ta, X = Cl or Br and THT - tetrahydrothiophene, are conveniently synthesized via the reaction of M/sub 2/M/sub 6/(THT)/sub 3/ with THF (THF = tetrahydrofuran). Unlike M/sub 2/X/sub 6/(THT)/sub 3/, M/sub 2/X/sub 6/(..mu..-THT)(THF)/sub 2/ can be easily reduced by sodium amalgam. In THF and in the presence of THT, complexes of the type M/sub 2/X/sub 6/(..mu..-THT)/sub 3//sup 2 -/ form. Salts of these compounds can also be synthesized directly from the metal pentahalides in a two step, one pot reaction in which M/sub 2/X/sub 6/(THT)/sub 3/ is an intermediate. The M/sub 2/X/sub 6/(..mu..-THT)/sub 3//sup 2 -/ complexes have a face-sharing bioctahedral structure with metal-metal triple bonds, the first reported for niobium or tantalum. These compounds are relatively inert, but (Nb/sub 2/Cl/sub 6/(..mu..-THT)/sub 3//sup 2 -/ does reach with pyridine and with a solution of acetic acid/acetic anhydride. These reactions and those of some of the sodium salts are described. In general, trinuclear complexes of niobium and tantalum are rare, and this type of discrete trinuclear complex, which contains one capping, three bridging and nine terminal ligands, has been seen only once before for the group 5 metals, although many examples of similar group 6 metal complexes are known. Full details of the synthesis and characterization of these complexes are described and an interpretation of their electronic structures is given.

Diebold, M.P.

1987-01-01T23:59:59.000Z

375

A supra­molecular ladder-like network from trimesic acid and pyrazine N,N'-dioxide  

Science Journals Connector (OSTI)

Cocrystallized trimesic acid (TMA) and pyrazine N,N'-dioxide (PNO) mol­ecules form strong O-HO hydrogen bonds, but also important weak C-HO and dipole-dipole inter­molecular inter­actions, to generate a densely packed three-dimensional network.

Yadav, V.N.

2013-12-07T23:59:59.000Z

376

E-Print Network 3.0 - area network performance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

networks - network performance modeling - wireless networks - wireless sensor networks - ad hoc ... Source: Iowa State University, Office of Biorenewables Programs Collection:...

377

Effects of the H-bond bridge geometry on the vibrational spectra of water: The simplest models of the H-bond potential  

Science Journals Connector (OSTI)

The approach suggested in this work within the fluctuation theory of the hydrogen bond allows one to correlate the vibrational band shape with the statistical distribution of the geometrical parameters of the O-H

Yu. Ya. Efimov

2008-03-01T23:59:59.000Z

378

Reductive Elimination from Cyclometalated Platinum(IV) Complexes To Form Csp2–Csp3 Bonds and Subsequent Competition between Csp2–H and Csp3–H Bond Activation  

Science Journals Connector (OSTI)

Reductive elimination reactions of the cyclometalated platinum(IV) compounds [PtMe2Br{C6H4CH?NCH2(4-ClC6H4)}L] (L = SMe2, PPh3) to form Csp3–Csp2 bonds, followed by either exclusive Csp2–H bond activation (L = SMe2) or competition between Csp2–H and Csp3–...

Margarita Crespo; Craig M. Anderson; Nicole Kfoury; Mercč Font-Bardia; Teresa Calvet

2012-06-14T23:59:59.000Z

379

Building a Network Simulation Model of the Teragrid Network  

E-Print Network [OSTI]

Building a Network Simulation Model of the Teragrid Network Thomas Hacker Preston Smith* Computer in designing and using an accurate network simulation model of the Teragrid network, and the performance

Jiang, Wen

380

On the mechanism of photoinduced refractive index changes in phosphosilicate glass  

SciTech Connect (OSTI)

The photoinduced growth of the refractive index of phosphosilicate glass during Bragg grating inscription and the thermal decay of the grating have a number of unusual features. The observed index variations are interpreted in terms of a new model for photoinduced glass network rearrangement. The model assumes the formation of photoinduced voids (nanopores) in the glass network near point defects. The nanopores may migrate through the network via bond switching when the network is in a 'soft' state. The photoinduced variations in network density lead to index variations. (fibres)

Larionov, Yu V [A M Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Sokolov, V O; Plotnichenko, V G [Fiber Optics Research Center, Russian Academy of Sciences, Moscow (Russian Federation)

2010-05-26T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Morphological neural networks  

SciTech Connect (OSTI)

The theory of artificial neural networks has been successfully applied to a wide variety of pattern recognition problems. In this theory, the first step in computing the next state of a neuron or in performing the next layer neural network computation involves the linear operation of multiplying neural values by their synaptic strengths and adding the results. Thresholding usually follows the linear operation in order to provide for nonlinearity of the network. In this paper we introduce a novel class of neural networks, called morphological neural networks, in which the operations of multiplication and addition are replaced by addition and maximum (or minimum), respectively. By taking the maximum (or minimum) of sums instead of the sum of products, morphological network computation is nonlinear before thresholding. As a consequence, the properties of morphological neural networks are drastically different than those of traditional neural network models. In this paper we consider some of these differences and provide some particular examples of morphological neural network.

Ritter, G.X.; Sussner, P. [Univ. of Florida, Gainesville, FL (United States)

1996-12-31T23:59:59.000Z

382

The Brownian Bridge Asymptotics in the Subcritical Phase of Bernoulli Bond Percolation Model.  

E-Print Network [OSTI]

The Brownian Bridge Asymptotics in the Subcritical Phase of Bernoulli Bond Percolation Model-dimensional subcritical Bernoulli bond percolation model conditioned on connecting points (0, ..., 0) and na if scaled percolation cluster in subcritical phase, conditioned on reaching a faraway point on square lattice. We

Kovchegov, Yevgeniy

383

MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897 905 Dynamics and hydrogen bonding in liquid ethanol  

E-Print Network [OSTI]

MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897± 905 Dynamics and hydrogen bonding in liquid ethanol L of liquid ethanol at three temperatures have been carried out. The hydrogen bonding states of ethanol measurements of the frequency-dependent dielectric permittivity of liquid ethanol. 1. Introduction A detailed

Saiz, Leonor

384

DOI: 10.1002/cphc.201400055 Effects of Adsorbate Coverage and Bond-Length Disorder  

E-Print Network [OSTI]

DOI: 10.1002/cphc.201400055 Effects of Adsorbate Coverage and Bond-Length Disorder on the d the effects of bond-length disorder and adsorbate coverage (CO and H2) on the d-band center of 1.25 nm size Pt catalysts supported on carbon. We found that the decrease in adsorbate coverage at elevated temperatures

Frenkel, Anatoly

385

Energetics of Homogeneous Intermolecular Vinyl and Allyl Carbon-Hydrogen Bond Activation by the  

E-Print Network [OSTI]

of alkanes for both industrial and synthetic applications. While the goal of catalytic activation-H bonds,4 few have allowed for quantification of activated products crucial to the assessment of a C-H bond to a coordinatively unsaturated late-metal center (d8 Rh and Ir), generating a relatively

Jones, William D.

386

Electronic states of metallic and semiconducting carbon nanotubes with bond and site disorder  

E-Print Network [OSTI]

energy in both of metallic and semiconducting carbon nanotubes. The bond disorder gives rise to a huge nanotube. We have also found that suppression of electronic conductance around the Fermi energy due and semiconducting carbon nanotubes. A huge density of states appears at the Fermi energy in the bond disorder case

Harigaya, Kikuo

387

Formation and Dissociation of Intra-Intermolecular Hydrogen-Bonded Solute-Solvent Complexes: Chemical  

E-Print Network [OSTI]

architectures in supramolecular chemistry, molecular recognition, and self-assembly. The strength of hydrogen, such as the properties of water4 and biological recognition.3 Hydrogen bonding has been studied extensively in many contexts since the birth of the concept in the early 1900s.2,3,5 Hydrogen bonds can be separated into two

Fayer, Michael D.

388

Testing Geometrical Discrimination within an Enzyme Active Site: Constrained Hydrogen Bonding in the Ketosteroid  

E-Print Network [OSTI]

Testing Geometrical Discrimination within an Enzyme Active Site: Constrained Hydrogen Bonding, Stanford UniVersity, Stanford, California 94305, and Departments of Biochemistry and Chemistry-chain reorientation and prevent hydrogen bond shortening by 0.1 Ă? or less. Further, this constraint has substantial

Herschlag, Dan

389

Bond energy effects on strength, cooperativity and robustness of molecular structures  

Science Journals Connector (OSTI)

...systematic study of the effect of the energy of chemical bonds on the mechanical...insight into the interplay of bond energy, robustness and other geometric...in adverse environments where energy, material quality and quantity as well as time scales...

2011-01-01T23:59:59.000Z

390

Bonded carbon or ceramic fiber composite filter vent for radioactive waste  

DOE Patents [OSTI]

Carbon bonded carbon fiber composites as well as ceramic or carbon bonded ceramic fiber composites are very useful as filters which can separate particulate matter from gas streams entraining the same. These filters have particular application to the filtering of radioactive particles, e.g., they can act as vents for containers of radioactive waste material.

Brassell, Gilbert W. (13237 W. 8th Ave., Golden, CO 80401); Brugger, Ronald P. (Lafayette, CO)

1985-02-19T23:59:59.000Z

391

Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N-AlOOH  

E-Print Network [OSTI]

Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N significant amounts of hydrogen in stishovite under lower-mantle conditions. The enthalpy of solution pressure and temperature. We predict asymmetric hydrogen bonding in the stishovite^N-AlOOH solid solution

Stixrude, Lars

392

Bonding of thermoplastic polymer microfluidics Chia-Wen Tsao Don L. DeVoe  

E-Print Network [OSTI]

REVIEW Bonding of thermoplastic polymer microfluidics Chia-Wen Tsao Ă? Don L. DeVoe Received: 20 Abstract Thermoplastics are highly attractive substrate materials for microfluidic systems, with important microchannels and other microfluidic elements, and thus bonding remains a critical step in any thermo- plastic

Rubloff, Gary W.

393

Single-Molecule Force Spectroscopy Measurements of Bond Elongation during a Bimolecular Reaction  

E-Print Network [OSTI]

to probe the TS of disulfide bond reduction, a bimolecular nucleophilic substitution (SN2) reaction. We use calculations of the role of solvent molecules in the reduction TS of an SN2 reaction. These results demonstrateSingle-Molecule Force Spectroscopy Measurements of Bond Elongation during a Bimolecular Reaction

Koti, Ainavarapu Sri Rama

394

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus  

E-Print Network [OSTI]

Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds Ilona B. Baldus and Frauke Gra, China ABSTRACT Mechanical force applied along a disulfide bond alters its rate of reduction. We here within proteins by point mutations. INTRODUCTION Similar to thermal or light energy, mechanical force can

Gräter, Frauke

395

Competitive oxygen-18 kinetic isotope effects expose OO bond formation in water oxidation  

E-Print Network [OSTI]

Competitive oxygen-18 kinetic isotope effects expose O­O bond formation in water oxidation. Roth*a Competitive oxygen kinetic isotope effects (18 O KIEs) on water oxidation initiated by ruthenium during oxygenic photo- synthesis.1 Formation of the O­O bond in molecular oxygen has been proposed

Roth, Justine P.

396

Adhesion, stability, and bonding at metal/metal-carbide interfaces: Al/WC Donald J. Siegel  

E-Print Network [OSTI]

of adhesion between metals and transition metal carbides/nitrides based on Density Functional Theory(DFT)[14Adhesion, stability, and bonding at metal/metal-carbide interfaces: Al/WC Donald J. Siegel the nature of metal/carbide bonding. Based on the surface and interfacial free energies, we find that both

Adams, James B

397

Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy  

SciTech Connect (OSTI)

We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

2010-05-01T23:59:59.000Z

398

NA Standards | Valence Geometries | Bond Lengths & Angles - Adenine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Adenine Adenine ---------------------------------------------------- Bond or Angle Mean (esd, N) Value ---------------------------------------------------- N1-C2 1.339 (0.009, 48) C2-N3 1.331 (0.009, 48) N3-C4 1.344 (0.006, 48) C4-C5 1.383 (0.007, 48) C5-C6 1.406 (0.009, 48) C6-N1 1.351 (0.007, 48) C5-N7 1.388 (0.006, 48) N7-C8 1.311 (0.007, 48) C8-N9 1.373 (0.008, 48) N9-C4 1.374 (0.006, 48) C6-N6 1.335 (0.008, 48) N9-C1' 1.462 (0.010, 48) C6-N1-C2 118.6 (0.6, 48) N1-C2-N3 129.3 (0.5, 48) C2-N3-C4 110.6 (0.5, 48) N3-C4-C5 126.8 (0.7, 48) C4-C5-C6 117.0 (0.5, 48) C5-C6-N1 117.7 (0.5, 48) C4-C5-N7 110.7 (0.5, 48) C5-N7-C8 103.9 (0.5, 48)

399

NA Standards | Valence Geometries | Bond Lengths & Angles - Protonated  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Protonated Adenine Protonated Adenine ---------------------------------------------------- Bond or Angle Mean (esd, N) Value ---------------------------------------------------- N1-C2 1.357 (0.009, 15) C2-N3 1.305 (0.008, 15) N3-C4 1.356 (0.006, 15) C4-C5 1.378 (0.008, 15) C5-C6 1.403 (0.007, 15) C6-N1 1.359 (0.007, 15) C5-N7 1.379 (0.005, 15) N7-C8 1.312 (0.008, 15) C8-N9 1.373 (0.009, 15) N9-C4 1.365 (0.007, 15) C6-N6 1.320 (0.008, 15) N9-C1' 1.466 (0.009, 15) C6-N1-C2 123.3 (0.6, 15) N1-C2-N3 125.7 (0.6, 15) C2-N3-C4 111.6 (0.4, 15) N3-C4-C5 127.4 (0.6, 15) C4-C5-C6 117.9 (0.5, 15) C5-C6-N1 114.0 (0.4, 15) C4-C5-N7 111.0 (0.3, 15) C5-N7-C8 103.7 (0.4, 15)

400

NA Standards | Valence Geometries | Bond Lengths & Angles - Guanine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Guanine Guanine ---------------------------------------------------- Bond or Angle Mean (esd, N) Value ---------------------------------------------------- N1-C2 1.373 (0.008, 21) C2-N3 1.323 (0.008, 21) N3-C4 1.350 (0.007, 21) C4-C5 1.379 (0.007, 21) C5-C6 1.419 (0.010, 21) C6-N1 1.391 (0.007, 21) C5-N7 1.388 (0.006, 21) N7-C8 1.305 (0.006, 21) C8-N9 1.374 (0.007, 21) N9-C4 1.375 (0.008, 21) C2-N2 1.341 (0.010, 21) C6-O6 1.237 (0.009, 21) N9-C1' 1.459 (0.009, 21) C6-N1-C2 125.1 (0.6, 21) N1-C2-N3 123.9 (0.6, 21) C2-N3-C4 111.9 (0.5, 21) N3-C4-C5 128.6 (0.5, 21) C4-C5-C6 118.8 (0.6, 21) C5-C6-N1 111.5 (0.5, 21)

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Bonding Strength by Methane Hydrate Formed among Sand Particles  

Science Journals Connector (OSTI)

The mechanical properties of methane hydrate?bearing sand were investigated by low temperature and high confining pressure triaxial testing apparatus in the present study. The specimens were prepared by infiltrating the methane gas into partially saturated sand specimen under the given temperature and stress condition which is compatible with the phase equilibrium condition for the stability of methane hydrate. The tests were firstly performed to investigate the effect of temperature on the shear behaviour of the specimen. Then the effect of backpressure was investigated. The strength of methane hydrate bearing sand increased as the temperature decreased and the back pressure increased. The bonding strength due to methane hydrate was dependent on methane hydrate saturation temperature and back pressure but independent of effective stress. Dissociation tests of methane hydrate were also performed by applying the temperature to the specimen at the various initial stress conditions. The marked development of shear and volumetric strains were observed due to dissociation of the methane hydrate in the specimen corresponding to the initial stress conditions.

M. Hyodo; Y. Nakata; N. Yoshimoto; R. Orense; J. Yoneda

2009-01-01T23:59:59.000Z

402

MATERIALS INTEGRATION FOR HIGH- PERFORMANCE PHOTOVOLTAICS BY WAFER BONDING  

E-Print Network [OSTI]

No thesis is an individual endeavor, and this thesis would not have been possible without the assistance of my collaborators and advisor and would have been unendurable without the support of my coworkers, friends, and family. I apologize in advance to anyone whom I might omit in this brief acknowledgement, but it is late and I am running out of time! In the summer of 2000, Harry Atwater agreed to allow me to transfer to his group from the chemical engineering department. I was discouraged and doubtful about my future at Caltech and in graduate school in general. Since giving me that chance he has been a great advisor with no shortage of encouragement or ideas. I am never sure if this is by design, but Harry has managed to inspire me to work hard and has given me countless ideas to pursue while always allowing me to feel that I have nearly complete freedom to pursue experiments that are interesting to me. While in Harry’s group I had the good fortune to work closely with two post-doctoral scholars, Chang-Geun Ahn and Anna Fontcuberta i Morral. Chang-Geun was extremely helpful in getting the Ge/Si bonding project going and in optical and electrical characterization experiments. Anna was tough to work with because her energy level is so darned high, but she has also been very supportive and her high energy approach to research has pushed me to work

James Michael Zahler; James Michael Zahler

2005-01-01T23:59:59.000Z

403

Dinuclear Metalloradicals Featuring Unsupported Metal-Metal Bonds  

SciTech Connect (OSTI)

Unlike the very labile, unobservable radical cations [{l_brace}CpM(CO){sub 3}{r_brace}{sub 2}]{sup {sm_bullet}+} (M = W, Mo), derivatives [{l_brace}CpM(CO){sub 2}(PMe{sub 3}){r_brace}{sub 2}]{sup {sm_bullet}+} are stable enough to be isolated and characterized. Experimental and theoretical studies show that the shortened M-M bonds are of order 1 1/2, and that they are not supported by bridging ligands. The unpaired electron is fully delocalized, with a spin density of ca. 45% on each metal atom. We thank the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences for support of this work. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. The EPR and computational studies were performed using EMSL, a national scientific user facility sponsored by the DOE's Office of Biological and Environmental Research and located at PNNL. We thank Dr. Charles Windisch for access to his UV-Vis-NIR spectrometer.

van der Eide, Edwin F.; Yang, Ping; Walter, Eric D.; Liu, Tianbiao L.; Bullock, R. Morris

2012-08-13T23:59:59.000Z

404

Intramolecular rearrangement of trimethylsilyl pyrazoles  

E-Print Network [OSTI]

with hexamethyldi- si lazane under anhydrous conditions. Four compounds wi th different ring substi tuents were thus synthesi zed. Nu- clear magnetic resonance (nmr) spectra of these compounds indicated the non-equivalence of the 3, 5-substi tuents at room... temperature. All the compounds showed temperature- dependent nmr spectra. The peak separation between the 3, 5-substi tuents of each compound was found to be a func- tion of temperature. As the temperature was increased the peak separation decreased...

Hrung, Chang-Po

2012-06-07T23:59:59.000Z

405

Network coded wireless architecture  

E-Print Network [OSTI]

Wireless mesh networks promise cheap Internet access, easy deployment, and extended range. In their current form, however, these networks suffer from both limited throughput and low reliability; hence they cannot meet the ...

Katti, Sachin Rajsekhar

2008-01-01T23:59:59.000Z

406

Financial Networks Anna Nagurney  

E-Print Network [OSTI]

themselves, such as the Internet with electric power networks, financial networks, and transportation Automobiles, Trains, and Planes, Manufacturing and logistics Workstations, Distribution Points Processing Cables Radio Links Voice, Data, Video Energy Pumping Stations, Plants Pipelines, Transmission Lines Water

Nagurney, Anna

407

Energy Efficient Digital Networks  

E-Print Network [OSTI]

Energy Use of Network Equipment, by Device Type (TWh) Power (W) Market Segment (Measurement Units)Energy Use of Network Equipment, by Device Type (TWh) Power (W) Market Segment (Measurement Unit)

Lanzisera, Steven

2014-01-01T23:59:59.000Z

408

Probabilistic Biological Network Alignment  

Science Journals Connector (OSTI)

Interactions between molecules are probabilistic events. An interaction may or may not happen with some probability, depending on a variety of factors such as the size, abundance, or proximity of the interacting molecules. In this paper, we consider ... Keywords: Probabilistic logic,Proteins,Network topology,Polynomials,Random variables,Topology,random graphs,Probabilistic biological networks,network alignment,neighborhood topology

Andrei Todor; Alin Dobra; Tamer Kahveci

2013-01-01T23:59:59.000Z

409

Microstructure and fracture toughness aspects of diffusion bonded interface between Ti and Al  

SciTech Connect (OSTI)

This study was undertaken to identify the microstructural characteristics of the intermetallic phases formed at the interface during the bonding process and determine the mechanical properties of Ti-Al dissimilar diffusion bonded joints, namely strength and fracture toughness. Furthermore, the effect of the intermetallic phases on the strength and fracture toughness of the joint was also determined. The effect of strength mis-match between Ti and Al on the fracture process will also be discussed. This investigation is the first phase of a larger project on the characterization of the intermetallics formed and their influence on strength and fracture toughness of the joints between TiAl-TiAl. A series of diffusion bonds of 25mm {times} 25 mm thick Ti bars were produced using aluminum foils of different thicknesses as interlayer. The bonded joints were tested to determine the fracture toughness properties of the interface formed and the effect of intermetallic phase formation on the fracture toughness was evaluated. Four-point bend specimens containing a crack introduced into the interface during the bonding process were tested to determine the diffusion-bonded interface fracture toughness. Tensile tests of the joints were also conducted to determine their strengths. The bonding conditions required to obtain a sound joint between Ti and Al were also evaluated.

Cam, G.; Dobi, D.; Kocak, M. [GKSS Research Center, Geesthacht (Germany); Heikinheimo, L.; Siren, M. [VTT Manufacturing Technology, Espoo (Finland)

1996-12-31T23:59:59.000Z

410

Correlation among electronegativity, cation polarizability, optical basicity and single bond strength of simple oxides  

SciTech Connect (OSTI)

A suitable relationship between free-cation polarizability and electronegativity of elements in different valence states and with the most common coordination numbers has been searched on the basis of the similarity in physical nature of both quantities. In general, the cation polarizability increases with decreasing element electronegativity. A systematic periodic change in the polarizability against the electronegativity has been observed in the isoelectronic series. It has been found that generally the optical basicity increases and the single bond strength of simple oxides decreases with decreasing the electronegativity. The observed trends have been discussed on the basis of electron donation ability of the oxide ions and type of chemical bonding in simple oxides. - Graphical abstract: This figure shows the single bond strength of simple oxides as a function of element electronegativity. A remarkable correlation exists between these independently obtained quantities. High values of electronegativity correspond to high values of single bond strength and vice versa. It is obvious that the observed trend in this figure is closely related to the type of chemical bonding in corresponding oxide. Highlights: Black-Right-Pointing-Pointer A suitable relationship between free-cation polarizability and electronegativity of elements was searched. Black-Right-Pointing-Pointer The cation polarizability increases with decreasing element electronegativity. Black-Right-Pointing-Pointer The single bond strength of simple oxides decreases with decreasing the electronegativity. Black-Right-Pointing-Pointer The observed trends were discussed on the basis of type of chemical bonding in simple oxides.

Dimitrov, Vesselin, E-mail: vesselin@uctm.edu [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria)] [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki, E-mail: komatsu@mst.nagaokaut.ac.jp [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)] [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

2012-12-15T23:59:59.000Z

411

Partial transient liquid phase diffusion bonding of Zircaloy-4 to stabilized austenitic stainless steel 321  

SciTech Connect (OSTI)

An innovative method was applied for bonding Zircaloy-4 to stabilized austenitic stainless steel 321 using an active titanium interlayer. Specimens were joined by a partial transient liquid phase diffusion bonding method in a vacuum furnace at different temperatures under 1 MPa dynamic pressure of contact. The influence of different bonding temperatures on the microstructure, microindentation hardness, joint strength and interlayer thickness has been studied. The diffusion of Fe, Cr, Ni and Zr has been investigated by scanning electron microscopy and energy dispersive spectroscopy elemental analyses. Results showed that control of the heating and cooling rate and 20 min soaking at 1223 K produces a perfect joint. However, solid-state diffusion of the melting point depressant elements into the joint metal causes the solid/liquid interface to advance until the joint is solidified. The tensile strength of all the bonded specimens was found around 480-670 MPa. Energy dispersive spectroscopy studies indicated that the melting occurred along the interface of the bonded specimens as a result of the transfer of atoms between the interlayer and the matrix during bonding. This technique provides a reliable method of bonding zirconium alloy to stainless steel.

Atabaki, M. Mazar, E-mail: m.mazaratabaki@gmail.com [Department of Materials Engineering, Faculty of Mechanical Engineering, University Technology Malaysia, 81310 (Malaysia); Hanzaei, A. Talebi [Department of Metallurgy and Materials Engineering, Faculty of Engineering, University of Tehran (Iran, Islamic Republic of)

2010-10-15T23:59:59.000Z

412

C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices  

E-Print Network [OSTI]

C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices Anirban Ghosh and Manju-pair as well as cross-strand C-H..O hydrogen bonds in the minor groove. The C2-H2..O2 hydrogen bonds within leads to a narrow minor groove in these regions. # 1999 Academic Press Keywords: C-H..O hydrogen bonds

Bansal, Manju

413

NA Standards | Valence Geometries | Bond Lengths & Angles - Thymine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thymine Thymine ---------------------------------------------------- Bond or Angle Mean (esd, N) Value ---------------------------------------------------- N1-C2 1.376 (0.008, 50) C2-N3 1.373 (0.008, 50) N3-C4 1.382 (0.008, 50) C4-C5 1.445 (0.009, 50) C5-C6 1.339 (0.007, 50) C6-N1 1.378 (0.007, 50) C2-O2 1.220 (0.008, 50) C4-O4 1.228 (0.009, 50) C5-M5 1.496 (0.006, 50) N1-C1' 1.473 (0.014, 50) C6-N1-C2 121.3 (0.5, 50) N1-C2-N3 114.6 (0.6, 50) C2-N3-C4 127.2 (0.6, 50) N3-C4-C5 115.2 (0.6, 50) C4-C5-C6 118.0 (0.6, 50) C5-C6-N1 123.7 (0.6, 50) N1-C2-O2 123.1 (0.8, 50) N3-C2-O2 122.3 (0.6, 50) N3-C4-O4 119.9 (0.6, 50) C5-C4-O4 124.9 (0.7, 50) C4-C5-M5 119.0 (0.6, 50)

414

NA Standards | Valence Geometries | Bond Lengths & Angles - Protonated  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Protonated Cytosine Protonated Cytosine ---------------------------------------------------- Bond or Angle Mean (esd, N) Value ---------------------------------------------------- N1-C2 1.381 (0.007, 17) C2-N3 1.384 (0.007, 17) N3-C4 1.353 (0.006, 17) C4-C5 1.413 (0.005, 17) C5-C6 1.346 (0.006, 17) C6-N1 1.365 (0.007, 17) C2-O2 1.212 (0.006, 17) C4-N4 1.315 (0.007, 17) N1-C1' 1.483 (0.015, 17) C6-N1-C2 121.7 (0.5, 17) N1-C2-N3 114.7 (0.7, 17) C2-N3-C4 125.3 (0.7, 17) N3-C4-C5 117.6 (0.5, 17) C4-C5-C6 118.4 (0.5, 17) C5-C6-N1 122.2 (0.5, 17) N1-C2-O2 123.4 (0.7, 17) N3-C2-O2 121.9 (0.5, 17) N3-C4-N4 119.5 (0.7, 17) C5-C4-N4 123.0 (0.8, 17) C6-N1-C1' 121.2 (0.9, 17) C2-N1-C1' 116.9 (1.0, 17

415

Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces  

SciTech Connect (OSTI)

12. Other advances in QNDE and related topics: Preferred Session Laser-ultrasonics Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces 41st Annual Review of Progress in Quantitative Nondestructive Evaluation Conference QNDE Conference July 20-25, 2014 Boise Centre 850 West Front Street Boise, Idaho 83702 James A. Smith, Jeffrey M. Lacy, Barry H. Rabin, Idaho National Laboratory, Idaho Falls, ID ABSTRACT: The US National Nuclear Security Agency has a Global Threat Reduction Initiative (GTRI) which is assigned with reducing the worldwide use of high-enriched uranium (HEU). A salient component of that initiative is the conversion of research reactors from HEU to low enriched uranium (LEU) fuels. An innovative fuel is being developed to replace HEU. The new LEU fuel is based on a monolithic fuel made from a U-Mo alloy foil encapsulated in Al-6061 cladding. In order to complete the fuel qualification process, the laser shock technique is being developed to characterize the clad-clad and fuel-clad interface strengths in fresh and irradiated fuel plates. The Laser Shockwave Technique (LST) is being investigated to characterize interface strength in fuel plates. LST is a non-contact method that uses lasers for the generation and detection of large amplitude acoustic waves to characterize interfaces in nuclear fuel plates. However the deposition of laser energy into the containment layer on specimen’s surface is intractably complex. The shock wave energy is inferred from the velocity on the backside and the depth of the impression left on the surface from the high pressure plasma pulse created by the shock laser. To help quantify the stresses and strengths at the interface, a finite element model is being developed and validated by comparing numerical and experimental results for back face velocities and front face depressions with experimental results. This paper will report on initial efforts to develop a finite element model for laser shock.

James A. Smith; Jeffrey M. Lacy; Barry H. Rabin

2014-07-01T23:59:59.000Z

416

NA Standards | Valence Geometries | Bond Lengths & Angles - Uracil  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Uracil Uracil ---------------------------------------------------- Bond or Angle Mean (esd, N) Value ---------------------------------------------------- N1-C2 1.381 (0.009, 46) C2-N3 1.373 (0.007, 46) N3-C4 1.380 (0.009, 46) C4-C5 1.431 (0.009, 46) C5-C6 1.337 (0.009, 46) C6-N1 1.375 (0.009, 46) C2-O2 1.219 (0.009, 46) C4-O4 1.232 (0.008, 46) N1-C1' 1.469 (0.014, 46) C6-N1-C2 121.0 (0.6, 46) N1-C2-N3 114.9 (0.6, 46) C2-N3-C4 127.0 (0.6, 46) N3-C4-C5 114.6 (0.6, 46) C4-C5-C6 119.7 (0.6, 46) C5-C6-N1 122.7 (0.5, 46) N1-C2-O2 122.8 (0.7, 46) N3-C2-O2 122.2 (0.7, 46) N3-C4-O4 119.4 (0.7, 46) C5-C4-O4 125.9 (0.6, 46) C6-N1-C1' 121.2 (1.4, 46) C2-N1-C1' 117.7 (1.2, 46

417

Hydrogen-bond equilibria and life times in a supercooled monohydroxy alcohol  

E-Print Network [OSTI]

Dielectric loss spectra covering 13 decades in frequency were collected for 2-ethyl-1-hexanol, a monohydroxy alcohol that exhibits a prominent Debye-like relaxation, typical for several classes of hydrogen-bonded liquids. The thermal variation of the dielectric absorption amplitude agrees well with that of the hydrogen-bond equilibrium population, experimentally mapped out using near infrared (NIR) and nuclear magnetic resonance (NMR) measurements. Despite this agreement, temperature-jump NIR spectroscopy reveals that the hydrogen-bond switching rate does not define the frequency position of the prominent absorption peak. This contrasts with widespread notions and models based thereon, but is consistent with a recent approach.

C. Gainaru; S. Kastner; F. Mayr; P. Lunkenheimer; S. Schildmann; H. J. Weber; W. Hiller; A. Loidl; R. Böhmer

2011-06-29T23:59:59.000Z

418

JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 9, NO. 1, MARCH 2000 3 Localized Silicon Fusion and Eutectic Bonding for  

E-Print Network [OSTI]

are required to provide the bonding energy. For example, the conventional silicon-to-silicon fusion bondingJOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 9, NO. 1, MARCH 2000 3 Localized Silicon Fusion, Fellow, IEEE Abstract--Silicon fusion and eutectic bonding processes based on the technique of localized

Lin, Liwei

419

Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen  

E-Print Network [OSTI]

Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen Bond, Stabilize the Transition State in Serine Protease Catalysis Cynthia N. Fuhrmann, Matthew D that destabilizes the His57-Ser195 hydrogen bond, preventing the back-reaction. In both structures the His57-Asp102

Agard, David

420

Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational Echo Spectroscopy  

E-Print Network [OSTI]

Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational@stanford.edu Abstract: Weak hydrogen-bonded solute/solvent complexes are studied with ultrafast two the dissociation and formation rates of the hydrogen-bonded complexes. The dissociation rates of the weak hydrogen

Fayer, Michael D.

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421

Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Alexei Khalizov, and Renyi Zhang*  

E-Print Network [OSTI]

Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Precursors, water, and ammonia. A central feature of the complexes is the presence of two hydrogen bonds. Organic acid-sulfuric acid complexes show one strong and one medium-strength hydrogen bond whereas

422

Hydrogen Bonds Involved in Binding the Qi-site Semiquinone in the bc1 Complex, Identified through Deuterium Exchange  

E-Print Network [OSTI]

Hydrogen Bonds Involved in Binding the Qi-site Semiquinone in the bc1 Complex, Identified through them. The strength of interactions indicates that the protons are involved in hydrogen bonds with SQ. The hyperfine cou- plings differ from values typical for in-plane hydrogen bonds previously observed in model

Crofts, Antony R.

423

Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran and cyclohexane rings in organic crystals  

E-Print Network [OSTI]

Paper Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran of the hydrogen bonding counts in crystalline pyranose monosaccharides, we noticed that equatorial hydroxyls formed more hydrogen bonds, on average, than axial groups. A survey of the Cambridge Structural Database

de Gispert, AdriĂ 

424

The Origin of Power-Law Emergent Scaling in Large Binary Networks  

E-Print Network [OSTI]

In this paper we study the macroscopic conduction properties of large but finite binary networks with conducting bonds. By taking a combination of a spectral and an averaging based approach we derive asymptotic formulae for the conduction in terms of the component proportions p and the total number of components N. These formulae correctly identify both the percolation limits and also the emergent power law behaviour between the percolation limits and show the interplay between the size of the network and the deviation of the proportion from the critical value of p = 1/2. The results compare excellently with a large number of numerical simulations.

D. P. Almond; C. J. Budd; M. A. Freitag; G. W. Hunt; N. J. McCullen; N. D. Smith

2012-04-25T23:59:59.000Z

425

Network Topology and the Fragility of Tetrahedral Glass-Forming Liquids  

Science Journals Connector (OSTI)

Network-forming liquids comprising tetrahedral motifs are investigated by large-scale molecular dynamics computer simulations within the framework of an ionic interaction model. The network topology is controlled by varying the anion polarizability, which governs the intertetrahedral bond angle, for different system densities. A coupling is found between the growth in magnitude and range of extended range oscillations and the appearance of ordering on an intermediate length scale. The interrelation between the system fragility and the structural arrangements on these two different length scales shows the trends that are observed for glass-forming systems. In particular, the fragility increases with number of edge-sharing motifs.

Mark Wilson and Philip S. Salmon

2009-10-07T23:59:59.000Z

426

Energy Sciences Network (ESnet)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages

ESnet ESnet ESnet ESnet ESnet ESnet » MyESnet search... Go Home Network Overview Tools Peering Information Interactive Network Map Network Maps Connected Sites Services Overview ECS Audio/Video Conferencing Fasterdata IPv6 Network Network Performance Tools (perfSONAR) ESnet OID Registry PGP Key Service Virtual Circuits (OSCARS) DOE Grids Service Transition R&D Overview 100G Testbed Virtual Circuits (OSCARS) Performance (perfSONAR) Tools Development Green Networking Authentication & Trust Federation (ATF) Partnerships News & Publications ESnet in the News ESnet News Publications and Presentations Galleries ESnet Awards and Honors About ESnet Overview ESnet Staff Governance Our Network Case Studies ESnet Strategic Plan ESnet Organizational Chart ESnet History Science Requirements Careers Contact Us

427

Bond Renewal Final Notice, Extension of DOE N 470.5 - September 28, 2011 |  

Broader source: Energy.gov (indexed) [DOE]

Bond Renewal Final Notice, Extension of DOE N 470.5 - September 28, Bond Renewal Final Notice, Extension of DOE N 470.5 - September 28, 2011 Bond Renewal Final Notice, Extension of DOE N 470.5 - September 28, 2011 September 28, 2011 Effective immediately, DOE N 470.5, Implementation of Section 1072 of the National Defense Authorization Act for Fiscal Year 2008, dated 8-12-09 is extended until 9-28-11 Effective immediately, DOE N 470.5, Implementation of Section 1072 of the National Defense Authorization Act for Fiscal Year 2008, dated 8-12-09 is extended until 9-28-11. Requirements in the Notice will be integrated into a new DOE Order, Personnel Security, which is currently under development. Direct inquiries concerning the extension to Stephanie Brewer, (202) 586-3249. BY ORDER OF THE SECRETARY OF ENERGY Bond Renewal Final Notice, Extension of DOE N 470.5 - September 28, 2011

428

Ab initio valence-bond cluster model for ionic solids: Alkaline-earth oxides  

Science Journals Connector (OSTI)

A linear M-O-M (M=metal, O=oxygen) cluster embedded in a Madelung field, and also including the quantum effects of the neighboring ions, is used to represent the alkaline-earth oxides. For this model an ab initio wave function is constructed as a linear combination of Slater determinants written in an atomic orbital basis set, i.e., a valence-bond wave function. Each valence-bond determinant (or group of determinants) corresponds to a resonating valence-bond structure. We have obtained ab initio valence-bond cluster-model wave functions for the electronic ground state and the excited states involved in the optical-gap transitions. Numerical results are reasonably close to the experimental values. Moreover, the model contains the ionic model as a limiting case and can be readily extended and improved.

A. Lorda; F. Illas; J. Rubio; J. B. Torrance

1993-03-15T23:59:59.000Z

429

Non-Destructive Inspection of Adhesive Bonds in Metal-Metal Joints...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. lm15moore.pdf More Documents & Publications NonDestructive Inspection of Adhesive Bonds...

430

Modeling of Covalent Bonding in Solids by Inversion of Cohesive Energy Curves  

Science Journals Connector (OSTI)

We provide a systematic test of empirical theories of covalent bonding in solids using an exact procedure to invert ab initio cohesive energy curves. By considering multiple structures of the same material, it is possible for the first time to test competing angular functions, expose inconsistencies in the basic assumption of a cluster expansion, and extract general features of covalent bonding. We test our methods on silicon, and provide direct evidence that the Tersoff-type bond-order formalism correctly describes coordination dependence. For bond-bending forces, we obtain skewed angular functions that favor small angles, unlike existing models. As a proof-of-principle demonstration, we derive a Si interatomic potential which exhibits comparable accuracy to existing models.

Martin Z. Bazant and Efthimios Kaxiras

1996-11-18T23:59:59.000Z

431

Partial-Transient-Liquid-Phase Bonding of Advanced Ceramics Using Surface-Modified Interlayers  

E-Print Network [OSTI]

of Thermal Residual Stresses in Joining Ceramics with ThinIn ceramic/metal/ceramic bonds that undergo thermal cycling,cooling or thermal cycling of the component. Ceramics are

Reynolds, Thomas Bither

2012-01-01T23:59:59.000Z

432

Periodic Hartree-Fock study of a weakly bonded layer structure: Brucite Mg(OH)2  

Science Journals Connector (OSTI)

The layered mineral brucite Mg(OH)2 is investigated theoretically using an ab initio all-electron linear combination of atomic orbitals Hartree-Fock (HF) approximation. At the HF level, the interlayer interaction is weak and the interlayer distance is larger than the experimental one. Bonding is discussed on the basis of density of states and charge-density maps. No hydrogen bond is characterized. A posteriori correction of the energy for the correlation error is performed by use of the functional approach. The three semilocal functional formulas used yield similar results. This brings in extra interlayer bonding interaction, and yields a calculated geometry in agreement with experiments. The analysis of the interlayer bondings shows that it is mainly of dispersion type, and that the used functionals account for dispersion, in particular at short interatomic distances.

Philippe D’Arco; Mauro Causŕ; Carla Roetti; Bernard Silvi

1993-02-15T23:59:59.000Z

433

Environmental durability of FRP bond to concrete subjected to freeze-thaw action  

E-Print Network [OSTI]

An experimental study was performed to determine the environmental durability of the adhesive bond between fiber-reinforced plastic (FRP) and concrete. The study specifically focused on freeze-thaw cycling exposure of such ...

Dohnálek, Pavel

2006-01-01T23:59:59.000Z

434

Financing and risk management of renewable energy projects with a hybrid bond  

Science Journals Connector (OSTI)

Abstract Although many incentive schemes and renewable energy policies, such as feed-in tariffs and tax credits, have been imposed to boost renewable energy investment, renewable energy investment still necessitates huge initial capital costs and involves numerous uncertainties. Unless the problems are well addressed, renewable energy developments are hindered. In this paper, we present a new financing instrument, called hybrid bond, to build renewable energy projects. The hybrid bond consists of a portfolio of renewable energy projects. It does not only financially support the initial capital costs, but also manages the risks associated with renewable energy investment. Key risks including market risks, credit risks, liquidity risks, operational risks and political risks are identified and managed. In the proposed framework, it reveals that the sale of a hybrid bond can finance a substantial share of upfront capital costs of renewable energy projects and the use of hybrid bond is able to manage major uncertainties.

Cheuk Wing Lee; Jin Zhong

2015-01-01T23:59:59.000Z

435

Computationally Useful Bridge Diagram Series. II. Diagrams in H-Bonds  

SciTech Connect (OSTI)

Equations for calculating accurate 4-point and 5-point bridge diagrams in terms of h-bonds have been presented and solved for various phase points of the Lennard-Jones fluid. A method of finding a self-consistent solution for the bridge function and the radial distribution function is demonstrated. The significance of this result over bridge diagrams expressed as f-bonds, in terms of its applicability to charged and dipolar models is discussed. Two very simple phenomenological bridge diagram forms for the bridge function for this model are examined and found to give results almost as accurate and in some cases more accurate than previous forms in the literature. This work represents the first use of directly calculated 5-point bridge diagrams in terms of h-bonds, and the many extra orders of f-bond diagrams which they include, in an integral equation result.

Perkyns, John S.; Dyer, Kippi M.; Pettitt, Bernard M.

2002-06-01T23:59:59.000Z

436

Relation between the bond lengths in an O-H…O bridge  

Science Journals Connector (OSTI)

The data in the literature on the bond lengths of O-H…O bridges formed in organic and inorganic crystals have...r 1 ? r 0/b) + exp(?(r 2 ? r 0/b) = ...

G. V. Yukhnevich

2009-03-01T23:59:59.000Z

437

Muon bonding versus muonium formation: Muon-Spin-Relaxation in ?-Al2O3  

Science Journals Connector (OSTI)

Results of Muon-Spin-Relaxation (?SR) experiments on well...2O3...) are reported. Major issue in this study is the controversy of muon bonding or muonium formation in insulators. Transverse ... applied field. The...

C. Boekema; K. C. Chan; R. L. Lichti; A. B. Denison; D. W. Cooke…

1986-12-01T23:59:59.000Z

438

Distal hydrogen-bonding effects and cofacial bimetallic salen architectures for oxygen activation chemistry  

E-Print Network [OSTI]

Two distinct structural scaffolds elaborated from Schiff-base macrocycles were designed to study the proton-coupled electron transfer chemistry of 0-0 bond forming and activation chemistry. The "Hangman" architecture is ...

Yang, Jenny Yue-fon

2007-01-01T23:59:59.000Z

439

Stress and Fracture Analysis of a Class of Bonded Joints in Wind Turbine Blades  

E-Print Network [OSTI]

A simplified model is proposed to investigate the stress fields and the strain energy release rate (SERR) associated with cracks in bonded joints in wind turbine blades. The proposed two-dimensional model consists of nonparallel upper and lower...

Chen, Chang

2013-05-08T23:59:59.000Z

440

Molecular-bond hardening and dynamics of molecular stabilization and trapping in intense laser pulses  

E-Print Network [OSTI]

stabilization and population trapping of high-lying vibrational states and chemical bond hardening are predicted for both continuous-wave (cw) lasers and short laser pulses. While the intensity dependences of the laser-induced stabilization are essentially...

Yao, Guanhua; Chu, Shih-I

1993-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Commercialization of low temperature copper thermocompression bonding for 3D integrated circuits .  

E-Print Network [OSTI]

??Wafer bonding is a key process and enabling technology for realization of three-dimensional integrated circuits (3DIC) with reduced interconnect delay and correspondingly increased circuit speed… (more)

Nagarajan, Raghavan

2008-01-01T23:59:59.000Z

442

Commercialization of low temperature copper thermocompression bonding for 3D integrated circuits  

E-Print Network [OSTI]

Wafer bonding is a key process and enabling technology for realization of three-dimensional integrated circuits (3DIC) with reduced interconnect delay and correspondingly increased circuit speed and decreased power ...

Nagarajan, Raghavan

2008-01-01T23:59:59.000Z

443

Hydrogen bonds of DsrD protein revealed by neutron crystallography  

Science Journals Connector (OSTI)

Hydrogen bonds of DNA-binding protein DsrD have been determined by neutron diffraction. In terms of proton donors and acceptors, DsrD protein shows striking differences from other proteins.

Chatake, T.

2008-04-18T23:59:59.000Z

444

Tests of concrete beams with externally-bonded glass-fiber fabric web reinforcement  

E-Print Network [OSTI]

of strengthening techniques used for rehabilitation of concrete structures is the method of using thin glass and carbon fiber fabrics, which are bonded externally to the surface of concrete. The study is focused on investigating the feasibility of using fabrics...

Dabholkar, Niranjan Shamsunder

2012-06-07T23:59:59.000Z

445

Recognizing molecular patterns by machine learning: an agnostic structural definition of the hydrogen bond  

E-Print Network [OSTI]

The concept of chemical bonding can ultimately be seen as a rationalization of the recurring structural patterns observed in molecules and solids. Chemical intuition is nothing but the ability to recognize and predict such patterns, and how they transform into one another. Here we discuss how to use a computer to identify atomic patterns automatically, so as to provide an algorithmic definition of a bond based solely on structural information. We concentrate in particular on hydrogen bonding -- a central concept to our understanding of the physical chemistry of water, biological systems and many technologically important materials. Since the hydrogen bond is a somewhat fuzzy entity that covers a broad range of energies and distances, many different criteria have been proposed and used over the years, based either on sophisticate electronic structure calculations followed by an energy decomposition analysis, or on somewhat arbitrary choices of a range of structural parameters that is deemed to correspond to a ...

Gasparotto, Piero

2014-01-01T23:59:59.000Z

446

Universality aspects of the d = 3 random-bond Blume-Capel model  

E-Print Network [OSTI]

The effects of bond randomness on the universality aspects of the simple cubic lattice ferromagnetic Blume-Capel model are discussed. The system is studied numerically in both its first- and second-order phase transition ...

Malakis, A.

447

Explicit renormalization-group analysis of the D=2 random-bond Ising model  

Science Journals Connector (OSTI)

It is shown by an explicit momentum-space renormalization-group analysis that the true renormalization-group equations for the D=2 random-bond Ising model agree with the equations obtained using the replica trick.

Ganpathy Murthy

1987-07-01T23:59:59.000Z

448

Hydrogen-bonded complexes of serotonin with methanol and ethanol: a DFT study  

Science Journals Connector (OSTI)

Density functional theoretical studies on hydrogen-bonded complexes of serotonin with methanol/ethanol have been carried out in a systematic ... -hydroxyl group. Serotonin-molecules strongly bind with ethanol tha...

A. Mano Priya; L. Senthilkumar; P. Kolandaivel

2014-02-01T23:59:59.000Z

449

Experimental and Theoretical Examination of C-CN Bond Activation of Benzonitrile Using Zerovalent Nickel  

E-Print Network [OSTI]

are important in industrial petroleum refining.1 The transition metal catalyzed activation of C-C bonds has been used in organic synthesis, for which the beneficial features of atom economy and chemoselectivity have

Jones, William D.

450

Cellular telephone-based wide-area radiation detection network  

DOE Patents [OSTI]

A network of radiation detection instruments, each having a small solid state radiation sensor module integrated into a cellular phone for providing radiation detection data and analysis directly to a user. The sensor module includes a solid-state crystal bonded to an ASIC readout providing a low cost, low power, light weight compact instrument to detect and measure radiation energies in the local ambient radiation field. In particular, the photon energy, time of event, and location of the detection instrument at the time of detection is recorded for real time transmission to a central data collection/analysis system. The collected data from the entire network of radiation detection instruments are combined by intelligent correlation/analysis algorithms which map the background radiation and detect, identify and track radiation anomalies in the region.

Craig, William W. (Pittsburg, CA); Labov, Simon E. (Berkeley, CA)

2009-06-09T23:59:59.000Z

451

Chain Retraction Potential in a Fixed Entanglement Network  

Science Journals Connector (OSTI)

When a chain, tethered at one end, is immersed in a fixed entanglement network, the mobile tip of the chain encounters an entropic potential barrier that penalizes deep fluctuations needed to bring the tip close to the tethering point. Using the tube model, Doi and Kuzuu [J. Polym. Sci., Polym. Lett. Ed. 18, 775 (1980)] estimated that this potential, which is crucial to describe the rheology of branched polymers in fixed networks and melts, has a quadratic form with a prefactor ?=1.5. Later calculations based on regular lattices indicated that the potential is nonquadratic, and its steepness depends on the lattice coordination number. In this Letter, we analyze the primitive paths obtained using the bond-fluctuation model for chains with up to 12.5 entanglements. Our simulations confirm a quadratic form for the potential with a prefactor close to the Doi-Kuzuu value, ??1.5.

Sachin Shanbhag and Ronald G. Larson

2005-02-23T23:59:59.000Z

452

XAS Characterization of a Nitridoiron(IV) Complex With a Very Short Fe-N Bond  

SciTech Connect (OSTI)

X-ray absorption spectroscopy has been used to characterize the novel nitridoiron(IV) units in two [PhBP{sup R}{sub 3}]Fe(N) complexes (R = iPr and CyCH{sub 2}) and obtain direct spectroscopic evidence for a very short Fe-N distance. The distance of 1.51--1.55 {angstrom} reflects the presence of an Fe{triple_bond}N triple bond in accord with the observed Fe{triple_bond}N vibration observed for one of these species (v{sub FeN}=1034 cm{sup -1}). This highly covalent bonding interaction results in the appearance of an unusually intense pre-edge peak, whose estimated area of 100(20) units is much larger than those of the related tetrahedral complexes with Fe{sup I}-N{sub 2}-Fe{sup I}, Fe{sup II}-NPh{sub 2}, and Fe{sup III}{triple_bond}NAd motifs, and those of recently described six-coordinate Fe{sup V}{triple_bond}N and Fe{sup VI}{triple_bond}N complexes. The observation that the Fe{sup IV}-N distances of two [PhBP{sup R}{sub 3}]Fe(N) complexes are shorter than the Fe{sup IV}-O bond lengths of oxoiron(IV) complexes may be rationalized on the basis of the greater ? basicity of the nitrido ligand than the oxo ligand and a lower metal coordination number for the Fe(N) complex.

Rohde, J.-U.; Betley, T.A.; Jackson, T.A.; Saouma, C.T.; Peters, J.C.; Que, L.; Jr.

2009-06-04T23:59:59.000Z

453

Electronic structure of dimetal bonded systems: ditungsten, dimolybdenum and diruthenium systems  

E-Print Network [OSTI]

with a 0.05 contour surface. The z axis is taken to be perpendicular to the plane defined by the tungsten atoms and ? -CO ligands.......24 5 Orbital correlation diagram for 1 illustrating the changes in energy of the four highest occupied (dashed... Page 1 Crystallographic Data for Tungsten Formamidinate Compounds................. 9 2 Bond Parameters (? or deg) for 1................................................................. 11 3 Bond Parameters (? or deg) for 2...

Villagran Martinez, Dino

2007-04-25T23:59:59.000Z

454

Fatigue life evaluation of wire bonds in LED packages using numerical analysis  

Science Journals Connector (OSTI)

Abstract Reliability of LED packages is evaluated using several tests. When a thermal shock test, which is one of the reliability tests, is conducted, the most common failure mode is wire neck breakage. In order to evaluate the wire bonding reliability of LED packages, performing the thermal shock test is time-consuming. In this paper the wire bonding reliability for LED packages is evaluated by using numerical analysis. A wire bonding lifetime model for the thermal shock test was developed, which is based on Coffin-Manson fatigue law. The model was calibrated from fatigue data of thermal shock tests and volume averaging accumulated plastic strains. The accumulated plastic strains were calculated by using finite element analysis corresponding to the test conditions. The test conditions were changed by silicones, package sizes, wire bonding diameters, heights, and lengths. The calibrated model was used to estimate the number cycle to failure so that the wire bonding reliability for the thermal shock test was evaluated by performing the numerical analysis. Furthermore, we used a response surface methodology to study the relationship between the wire loop and the accumulated plastic strain to determine the optimal wire loop. The plastic strain was a function of diameter, height and length. At the optimal point, the number of cycle to failure for the thermal shock test was suggested using the wire bonding lifetime model.

Sung-Uk Zhang; Bang Weon Lee

2014-01-01T23:59:59.000Z

455

Modeling and numerical analysis of the bond behavior of masonry elements strengthened with SRP/SRG  

Science Journals Connector (OSTI)

Abstract Steel Reinforced Polymers (SRPs) and Steel Reinforced Grout (SRG) strengthening systems have been recently introduced as an alternative solution to the traditional systems based on the use of fiber reinforced polymers materials (FRPs). Few studies on SRP/SRG are available in the current literature and all have shown the potentialities of SRP/SRG in improving structural performances of masonry and concrete elements and, at the same time, their difference with respect to \\{FRPs\\} particularly in terms of bond behavior. Aim of the present paper is to propose a simple approach devoted to study the bond behavior of masonry structures strengthened with SRP/SRG systems. The approach, based on experimental evidences and theoretical considerations mainly consists of deriving approximate bond stress-slip laws for the strengthening/support interface layer, able to reproduce the local bond stresses transferring mechanism. Finite Element (FE) analyses are then developed with reference to the experimental tests available in the current literature by adopting the bond stress-slip laws obtained through the proposed approach. The deduced results show the reliability of the proposed approach in simulating the bond behavior of masonry elements strengthened with SRP/SRG and the possibility to investigate further peculiarities characterizing this kind of strengthening systems.

Ernesto Grande; Maura Imbimbo; Elio Sacco

2013-01-01T23:59:59.000Z

456

Wafer Bonding and Layer Transfer Processes for High Efficiency Solar Cells  

SciTech Connect (OSTI)

A wafer-bonded four-junction cell design consisting of InGaAs, InGaAsP, GaAs, and Ga0.5In0.5P subcells that could reach one-sun AM0 efficiencies of 35.4% is described. The design relies on wafer-bonding and layer transfer for integration of non-lattice-matched subcells. Wafer bonding and layer transfer processes have shown promise in the fabrication of InP/Si epitaxial templates for growth of the bottom InGaAs and InGaAsP subcells on a Si support substrate. Subsequent wafer bonding and layer transfer of a thin Ge layer onto the lower subcell stack can serve as an epitaxial template for GaAs and Ga0.5In0.5P subcells. Additionally, wafer bonded Ge/Si substrates offer the possibility to improve the mechanical performance of existing triple-junction solar cell designs, while simultaneously reducing their cost. Present results indicate that optically active III/V compound semiconductors can be grown on both Ge/Si and InP/Si heterostructures. Current-voltage electrical characterization of the interfaces of these structures indicates that both InP/Si and Ge/Si interfaces have specific resistances lower than 0.1 W?cm2 for heavily doped wafer bonded interfaces, enabling back surface power extraction from the finished cell structure.

Zahler, J. M.; Fontcuberta i Morral, A.; Ahn, C. G.; Atwater, H. A.; Wanlass, M. W.; Chu, C.; Iles, P. A.

2003-05-01T23:59:59.000Z

457

Method of bonding functional surface materials to substrates and applications in microtechnology and antifouling  

DOE Patents [OSTI]

A simple and effective method to bond a thin coating of poly(N-isopropylacylamide) (NIPAAm) on a glass surface by UV photopolymerization, and the use of such a coated surface in nano and micro technology applications. A silane coupling agent with a dithiocarbamate group is provided as a photosensitizer, preferably, (N,N'-diethylamine)dithiocarbamoylpropyl-(trimethoxy)silane (DATMS). The thiocarbamate group of the sensitizer is then bonded to the glass surface by coupling the silane agent with the hydroxyl groups on the glass surface. The modified surface is then exposed to a solution of NIPAAm and a crosslinking agent which may be any organic molecule having an acrylamide group and at least two double bonds in its structure, such as N,N'-methylenebisacrylamide, and a polar solvent which may be any polar liquid which will dissolve the monomer and the crosslinking agent such as acetone, water, ethanol, or combinations thereof. By exposing the glass surface to a UV light, free radicals are generated in the thiocarbamate group which then bonds to the crosslinking agent and the NIPAAm. Upon bonding, the crosslinking agent and the NIPAAm polymerize to form a thin coating of PNIPAAm bonded to the glass. Depending upon the particular configuration of the glass, the properties of the PNIPAAm allow applications in micro and nano technology.

Feng, Xiangdong (West Richland, WA); Liu, Jun (West Richland, WA); Liang, Liang (Richland, WA)

1999-01-01T23:59:59.000Z

458

Method of bonding functional surface materials to substrates and applications in microtechnology and anti-fouling  

DOE Patents [OSTI]

A simple and effective method to bond a thin coating of poly(N-isopropylacylamide) (NIPAAm) on a glass surface by UV photopolymerization, and the use of such a coated surface in nano and micro technology applications. A silane coupling agent with a dithiocarbamate group is provided as a photosensitizer preferably, (N,N'-diethylamine) dithiocarbamoylpropyl-(trimethoxy) silane (DATMS). The thiocarbamate group of the sensitizer is then bonded to the glass surface by coupling the silane agent with the hydroxyl groups on the glass surface. The modified surface is then exposed to a solution of NIPAAm and a crosslinking agent which may be any organic molecule having an acrylamide group and at least two double bonds in its structure, such as N, N'-methylenebisacrylamide, and a polar solvent which may be any polar liquid which will dissolve the monomer and the crosslinking agent such as acetone, water, ethanol, or combinations thereof. By exposing the glass surface to a UV light, free radicals are generated in the thiocarbamate group which then bonds to the crosslinking agent and the NIPAAm. Upon bonding, the crosslinking agent and the NIPAAm polymerize to form a thin coating of PNIPAAm bonded to the glass. Depending upon the particular configuration of the glass, the properties of the PNIPAAm allow applications in micro and nano technology.

Feng, Xiangdong (West Richland, WA); Liu, Jun (West Richland, WA); Liang, Liang (Richland, WA)

2001-01-01T23:59:59.000Z

459

Networks within networks - interaction in bioenergy business  

Science Journals Connector (OSTI)

Collaboration is seen as one of the most important means for small and medium-sized enterprises (SMEs) to compete and innovate in dynamic business environments. This paper approaches this phenomenon by studying a group of Finnish biomass heating firms and their interaction in the bioenergy business. In this paper, two frameworks are combined into a practical two-level tool for relationship and network analysis. This paper offers detailed information on the formation of partnerships and networks around the bioenergy business. Moreover, it speculates about the motives and mechanisms behind an actor's business relations. This study confirms that it is often profitable for SMEs to act simultaneously in different types of networks. In these networks, the firms form relationships that are different in breadth and depth.

Kirsi Kokkonen; Tuomo Kässi; Ville Ojanen

2014-01-01T23:59:59.000Z

460

Random Walks and Electrical Networks Electrical Network ...  

E-Print Network [OSTI]

Feb 4, 2008 ... Much of this talk is based on the book Random Walks and Electric. Networks by Peter .... Rx,y resistance of the edge from x to y. Cx,y = 1. Rx,y.

Jonathon Peterson

2008-01-30T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Faster information dissemination in dynamic networks via network coding  

E-Print Network [OSTI]

We use network coding to improve the speed of distributed computation in the dynamic network model of Kuhn, Lynch and Oshman [STOC '10]. In this model an adversary adaptively chooses a new network topology in every round, ...

Haeupler, Bernhard

462

Handbook of Network Analysis [KONECT -- the Koblenz Network Collection  

E-Print Network [OSTI]

This is the Handbook of Network Analysis, the companion article to the KONECT (Koblenz Network Collection) project. This project is intended to collect network datasets, analyse them systematically, and provide both datasets and the underlying network analysis code to researchers. This article outlines the project, gives all definitions used within the project, reviews all network statistics used, reviews all network plots used, and gives a brief overview of the API used by KONECT.

Kunegis, Jérôme

2014-01-01T23:59:59.000Z

463

From Photo Networks to Social Networks, Creation and Use of a Social Network Derived with Photos  

E-Print Network [OSTI]

From Photo Networks to Social Networks, Creation and Use of a Social Network Derived with Photos and photos have received plenty of attention in the digital age. In this paper, we show how social photos that reveals social attributes. From this photo network, a social network is extracted that can help to build

Boyer, Edmond

464

Rooftop Unit Network Project  

Broader source: Energy.gov (indexed) [DOE]

Network Project Network Project RTU Network Project Michael Brambley, Ph.D. Pacific Northwest National Laboratory Michael.Brambley@pnnl.gov (509) 375-6875 April 4, 2013 2 | Building Technologies Office eere.energy.gov * Packaged air conditioners and heat pumps (RTUs) are used in about 58% of all cooled commercial buildings, serving about 69% of the cooled commercial building floor space (EIA 2003) - Navigant estimates packaged A/C uses 0.9 quads of electricity for cooling annually and

465

Mild Catalytic methods for Alkyl-Alkyl Bond Formation  

SciTech Connect (OSTI)

Overview of Research Goals and Accomplishments for the Period 07/01/06 – 06/30/07: Our overall research goal is to transform the rapidly emerging synthetic chemistry involving alkyl-alkyl cross-couplings into more of a mechanism-based field so that that new, rationally-designed catalysts can be performed under energy efficient conditions. Our specific objectives for the previous year were 1) to obtain a proper electronic description of an active catalyst for alkyl-alkyl cross-coupling reactions and 2) to determine the effect of ligand structure on the rate, scope, selectivity, and functional group compatibility of C(sp3)-C(sp3) cross-coupling catalysis. We have completed both of these initial objectives and established a firm base for further studies. The specific significant achievements of the current grant period include: 1) we have performed magnetic and computational studies on (terpyridine)NiMe, an active catalyst for alkyl-alkyl cross couplings, and have discovered that the unpaired electron resides heavily on the terpyridine ligand and that the proper electronic description of this nickel complex is a Ni(II)-methyl cation bound to a reduced terpyridine ligand; 2) we have for the first time shown that alkyl halide reduction by terpyridyl nickel catalysts is substantially ligand based; 3) we have shown by isotopic labeling studies that the active catalyst (terpyridine)NiMe is not produced via a mechanism that involves the formation of methyl radicals when (TMEDA)NiMe2 is used as the catalyst precursor; 4) we have performed an extensive ligand survey for the alkyl-alkyl cross-coupling reactions and have found that electronic factors only moderately influence reactivity in the terpyridine-based catalysis and that the most dramatic effects arise from steric and solubility factors; 5) we have found that the use of bis(dialkylphosphino)methanes as ligands for nickel does not produce active catalysts for cross-coupling but rather leads to bridging hydride complexes of varying geometries; 6) we have determined that the geometry of aforementioned bridging hydride complexes is largely determined by external forces such as hydrogen bonding interactions and crystal packing forces; 7) we have found that the rate of reductive elimination of alkane from a (pyridyl-2-pyrrolide)AuMe2 complex is severely inhibited due to the rigid geometry of the pyridyl-2-pyrrolide ligand; 8) we have prepared, structurally characterized, and explored the reactivity of 1-adamantylzinc reagents as model nucleophiles for sterically challenging alkyl-alkyl cross-coupling reactions. The continued success of this work will lead to alkyl-alkyl cross-coupling catalysts with broad scope and selectivities. The work has potential to significantly impact science and technologies of interest to the DOE as the chemistry is focused on developing useful reactions using reagents that can be directly prepared from petroleum and natural gas feedstocks. Moreover, the developing synthetic chemistry can profoundly affect the way materials, fine chemicals, and drugs are made. Since the methodology we are developing can shorten existing synthetic protocols, proceed at room temperature, and operate under environmentally benign conditions, it can greatly reduce energy expenditures, especially considering the contribution of the chemical manufacturing field to the gross domestic product.

David A Vicic

2009-08-10T23:59:59.000Z

466

Multiperiod Competitive Supply Chain Networks with Inventorying and A Transportation Network Equilibrium Reformulation Multiperiod Competitive Supply Chain Networks  

E-Print Network [OSTI]

Multiperiod Competitive Supply Chain Networks with Inventorying and A Transportation Network Equilibrium Reformulation Multiperiod Competitive Supply Chain Networks with Inventorying and A Transportation Competitive Supply Chain Networks with Inventorying and A Transportation Network Equilibrium Reformulation

Nagurney, Anna

467

Building A Science DMZ Eli Dart, Network Engineer ESnet Network...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Science DMZ Eli Dart, Network Engineer ESnet Network Engineering Group Joint Techs, Winter 2013 Honolulu, HI January 13, 2013 Lawrence Berkeley National Laboratory U.S....

468

Handoff Notification in Wireless Hybrid Networks  

Science Journals Connector (OSTI)

Hybrid networks composed of a wireless infrastructure network providing Internet access to an underlying...

Guillaume Chelius; Claude Chaudet

2005-01-01T23:59:59.000Z

469

Classifying Artificial Neural Network Architecture  

Science Journals Connector (OSTI)

Most Artificial Neural Network architecture appears to be heuristic in conception; ... be preferable to develop a formal taxonomy for Neural Networks in order that network size and designs may be matched more ......

Dr J. P. Evans

1990-01-01T23:59:59.000Z

470

Home Area Networks  

Science Journals Connector (OSTI)

Indoor networks must transport a wide variety of services, and support both wirebound and wireless broadband connectivity. Architectures and techniques for cost- and energy-efficient...

Koonen, A

471

Nanotechnology for Optical Networks  

Science Journals Connector (OSTI)

Transparent optical networks will rely on electronics for control and monitoring. Integrating infrared optoelectronic devices such as lasers, modulators, and detectors onto silicon...

Sargent, Edward

472

Thermodynamics of Fractal Networks  

Science Journals Connector (OSTI)

Optimal channel networks are fractal structures that bear a striking resemblance to real rivers. They are obtained by minimizing an energy functional associated with spanning trees. We show that large network development effectively occurs at zero temperature since the entropy scales subdominantly with system size compared to the energy. Thus these networks develop under generic conditions and freeze into a static scale-free structure. We suggest a link of optimal channel networks with self-organized critical systems and critical phenomena which exhibit spatial and temporal fractality, the former under generic conditions and the latter on fine tuning.

Andrea Rinaldo; Amos Maritan; Francesca Colaiori; Alessandro Flammini; Riccardo Rigon; Ignacio Rodriguez-Iturbe; Jayanth R. Banavar

1996-04-29T23:59:59.000Z

473

BER Science Network Requirements  

E-Print Network [OSTI]

Networking) David Benton, GLBRC/University of Wisconsin (and analysis tools. GLBRC currently comprises some 44 inter-year funding period of the GLBRC, while several terabytes of

Dart, Eli

2011-01-01T23:59:59.000Z

474

XAS Characterization of a Nitridoiron(IV) Complex with a Very Short Fe-N Bond  

SciTech Connect (OSTI)

X-ray absorption spectroscopy has been used to characterize the novel nitridoiron(IV) units in two [PhBP{sup R}{sub 3}]Fe(N) complexes (R = iPr and CyCH{sub 2}) and obtain direct spectroscopic evidence for a very short Fe-N distance. The distance of 1.51-1.55 {angstrom} reflects the presence of an Fe{triple_bond}N triple bond in accord with the observed Fe{triple_bond}N vibration observed for one of these species ({nu}{sub FeN} = 1034 cm{sup -1}). This highly covalent bonding interaction results in the appearance of an unusually intense pre-edge peak, whose estimated area of 100(20) units is much larger than those of the related tetrahedral complexes with Fe{sup I}-N{sub 2}-Fe{sup I}, Fe{sup II}-NPh{sub 2}, and Fe{sup III}NAd motifs, and those of recently described six-coordinate Fe{sup V}{triple_bond}N and Fe{sup VI}{triple_bond}N complexes. The observation that the Fe{sup IV}-N distances of two [PhBP{sup R}{sub 3}]Fe(N) complexes are shorter than the Fe{sup IV}-O bond lengths of oxoiron(IV) complexes may be rationalized on the basis of the greater {pi} basicity of the nitrido ligand than the oxo ligand and a lower metal coordination number for the Fe(N) complex.

Rohde,J.; Betley, T.; Jackson, T.; Saouma, C.; Peters, J.; Que, Jr., L.

2007-01-01T23:59:59.000Z

475

Microstructural Examination to Aid in Understanding Friction Bonding Fabrication Technique for Monolithic Nuclear Fuel  

SciTech Connect (OSTI)

Monolithic nuclear fuel is currently being developed for use in research reactors, and friction bonding (FB) is a technique being developed to help in this fuel’s fabrication. Since both FB and monolithic fuel are new concepts, research is needed to understand the impact of varying FB fabrication parameters on fuel plate characteristics. This thesis research provides insight into the FB process and its application to the monolithic fuel design by recognizing and understanding the microstructural effects of varying fabrication parameters (a) FB tool load, and (b) FB tool face alloy. These two fabrication parameters help drive material temperature during fabrication, and thus the material properties, bond strength, and possible formation of interface reaction layers. This study analyzed temperatures and tool loads measured during those FB processes and examined microstructural characteristics of materials and bonds in samples taken from the resulting fuel plates. This study shows that higher tool load increases aluminum plasticization and forging during FB, and that the tool face alloy helps determine the tool’s heat extraction efficacy. The study concludes that successful aluminum bonds can be attained in fuel plates using a wide range of FB tool loads. The range of tool loads yielding successful uranium-aluminum bonding was not established, but it was demonstrated that such bonding can be attained with FB tool load of 48,900 N (11,000 lbf) when using a FB tool faced with a tungsten alloy. This tool successfully performed FB, and with better results than tools faced with other materials. Results of this study correlate well with results reported for similar aluminum bonding techniques. This study’s results also provide support and validation for other nuclear fuel development studies and conclusions. Recommendations are offered for further research.

Karen L. Shropshire

2008-04-01T23:59:59.000Z

476

Probing the hydrogen-bond network of water via time-resolved soft x-ray spectroscopy  

E-Print Network [OSTI]

S. Pshenichnikov and D. A. Wiersma, J. Phys. Chem. B, 2004,Dan Cringus, Douwe A. Wiersma and Maxim Mostovoy, Chem.

Huse, Nils

2009-01-01T23:59:59.000Z

477

Water Dynamics in Nafion Fuel Cell Membranes: The Effects of Confinement and Structural Changes on the Hydrogen Bond Network  

E-Print Network [OSTI]

emissions energy source is hydrogen. Hydrogen powered vehicles using polymer electrolyte membrane fuel cells and hydrophilic aggregates.1-4 Hydrogen fuel cells operate through the oxidation of hydrogen gas at the anodeWater Dynamics in Nafion Fuel Cell Membranes: The Effects of Confinement and Structural Changes

Fayer, Michael D.

478

Explosion bonding of dissimilar materials for fabricating APS front end components: Analysis of metallurgical and mechanical properties and UHV applications  

SciTech Connect (OSTI)

The front end beamline section contains photon shutters and fixed masks. These components are made of OFHC copper and GlidCOP AL-15. Stainless steels (304 or 316) are also used for connecting photon shutters and fixed masks to other components that operate in the ultrahigh vacuum system. All these dissimilar materials need to be joined together. However, bonding these dissimilar materials is very difficult because of their different mechanical and thermal properties and incompatible metallurgical properties. Explosion bonding is a bonding method in which the controlled energy of a detonating explosive is used to create a metallurgical bond between two or more similar or dissimilar materials. No intermediate filler metal, for example, a brazing compound or soldering alloy, is needed to promote bonding, and no external heat need be applied. A study of the metallurgical and mechanical properties and YGV applications of GlidCop AL-15, OFHC copper, and 304 stainless steel explosion-bonded joints has been done. This report contains five parts: an ultrasonic examination of explosion-bonded joints and a standard setup; mechanical-property and thermal-cycle tests of GlidCop AL-15/304 stainless steel explosion-bonded joints; leak tests of a GlidCop AL-15/304 stainless steel explosion-bonded interfaces for UHV application; metallurgical examination of explosion-bonded interfaces and failure analysis, and discussion and conclusion.

Li, Yuheng; Shu, Deming; Kuzay, T.M.

1994-06-15T23:59:59.000Z

479

The simplicity of planar networks  

E-Print Network [OSTI]

source and observe the micro-tube network at six phases ofin a planar network-like structure of micro-tubes 33 . In

Viana, Matheus P; Strano, Emanuele; Bordin, Patricia; Barthelemy, Marc

2013-01-01T23:59:59.000Z

480

Fusion Energy Sciences Network Requirements  

E-Print Network [OSTI]

Network Research) C.S. Chang, PPPL (Fusion Simulations) EliGreenwald, MIT PSFC (Alcator C-Mod) Paul Henderson, PPPL (PPPL Networking) Steve Jardin, PPPL (Fusion Simulations)

Dart, Eli

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "bond network rearrangements" from the National Library of EnergyBeta (NLEBeta).
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481

Water Network Design by MINLP  

E-Print Network [OSTI]

Feb 13, 2008 ... We propose a solution method for a water-network optimization problem ... The optimal design of a WDN (Water Distribution Network) consists, ...

2008-02-12T23:59:59.000Z

482

Ligand Additions to Cp*(CO)2ReRe(CO)2Cp* and Fragmentation and Rearrangement Reactions of Cp*(CO)2Re(?-CO)Re(CO)(L)Cp*  

Science Journals Connector (OSTI)

Ligand Additions to Cp*(CO)2ReRe(CO)2Cp* and Fragmentation and Rearrangement Reactions of Cp*(CO)2Re(?-CO)Re(CO)(L)Cp* ... Cp*(CO)2ReRe(CO)2Cp* (1) reacted with 2-butyne at ?78 °C to form the 1:1 adduct Cp*(CO)2Re(?-CO)Re(CO)(2-butyne)Cp* (8). ... At ?40 °C, 8 was converted to a mixture of the dimetallacyclopentenone Cp*(CO)2Re[?-?1,?3-(CH3)CC(CH3)CO]Re(CO)Cp* (9) and two fragmentation products:? Cp*Re(CO)3 and Cp*Re(CO)(CH3C?CCH3) (14). ...

Charles P. Casey; Ronald S. Carińo; Hiroyuki Sakaba; Randy K. Hayashi

1996-05-28T23:59:59.000Z

483

Metabolic Engineering to Develop a Pathway for the Selective Cleavage of Carbon-Nitrogen Bonds  

SciTech Connect (OSTI)

The objective of the project is to develop a biochemical pathway for the selective cleavage of C-N bonds in molecules found in petroleum. Specifically a novel biochemical pathway will be developed for the selective cleavage of C-N bonds in carbazole. The cleavage of the first C-N bond in carbazole is accomplished by the enzyme carbazole dioxygenase, that catalyzes the conversion of carbazole to 2-aminobiphenyl-2,3-diol. The genes encoding carbazole dioxygenase were cloned from Sphingomonas sp. GTIN11 and from Pseudomonas resinovorans CA10. The selective cleavage of the second C-N bond has been challenging, and efforts to overcome that challenge have been the focus of recent research in this project. Enrichment culture experiments succeeded in isolating bacterial cultures that can metabolize 2-aminobiphenyl, but no enzyme capable of selectively cleaving the C-N bond in 2-aminobiphenyl has been identified. Aniline is very similar to the structure of 2-aminobiphenyl and aniline dioxygenase catalyzes the conversion of aniline to catechol and ammonia. For the remainder of the project the emphasis of research will be to simultaneously express the genes for carbazole dioxygenase and for aniline dioxygenase in the same bacterial host and then to select for derivative cultures capable of using carbazole as the sole source of nitrogen.

John J. Kilbane II

2005-10-01T23:59:59.000Z

484

Single Molecule Junctions: A Laboratory for Chemistry, Mechanics and Bond Rupture  

SciTech Connect (OSTI)

Simultaneous measurement [1] of junction conductance and sustained force in single molecule junctions bridging metal electrodes provides a powerful tool in the quantitative study of the character of molecule-metal bonds. In this talk I will discuss three topics. First, I will describe chemical trends in link bond strength based on experiments and Density Functional Theory based calculations. Second, I will focus on the specific case of pyridine-linked junctions. Bond rupture from the high conductance junction structure shows a requires a force that exceeds the rupture force of gold point contacts and clearly indicates the role of additional forces, beyond the specific N-Au donor acceptor bond. DFT-D2 calculations with empirical addition of dispersion interactions illustrates the interplay between the donor-acceptor bonding and the non-specific van der Waals interactions between the pyridine rings and Au asperities. Third, I will describe recent efforts to characterize the diversity of junction structures realized in break-junction experiments with suitable models for the potential surfaces that are observed. [1] Venkataraman Group, Columbia University.

Hybertsen M. S.

2013-07-08T23:59:59.000Z

485

Microstructural evolution during transient liquid phase bonding of Inconel 738LC using AMS 4777 filler alloy  

SciTech Connect (OSTI)

IN-738LC nickel-based superalloy was joined by transient liquid phase diffusion bonding using AMS 4777 filler alloy. The bonding process was carried out at 1050 Degree-Sign C under vacuum atmosphere for various hold times. Microstructures of the joints were studied by optical and scanning electron microscopy. Continuous centerline eutectic phases, characterized as nickel-rich boride, chromium-rich boride and nickel-rich silicide were observed at the bonds with incomplete isothermal solidification. In addition to the centerline eutectic products, precipitation of boron-rich particles was observed in the diffusion affected zone. The results showed that, as the bonding time was increased to 75 min, the width of the eutectic zone was completely removed and the joint was isothermally solidified. Homogenization of isothermally solidified joints at 1120 Degree-Sign C for 300 min resulted in the elimination of intermetallic phases formed at the diffusion affected zone and the formation of significant {gamma} Prime precipitates in the joint region. - Highlights: Black-Right-Pointing-Pointer TLP bonding of IN-738LC superalloy was performed using AMS 4777 filler alloy. Black-Right-Pointing-Pointer Insufficient diffusion time resulted in the formation of eutectic product. Black-Right-Pointing-Pointer Precipitation of B-rich particles was observed within the DAZ. Black-Right-Pointing-Pointer The extent of isothermal solidification increased with increasing holding time. Black-Right-Pointing-Pointer Homogenizing of joints resulted in the dissolution of DAZ intermetallics.

Jalilvand, V., E-mail: jalilvand@aut.ac.ir [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of); Omidvar, H. [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of)] [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15875-4413 (Iran, Islamic Republic of); Shakeri, H.R. [Department of Materials Science and Engineering, University of Toronto, Toronto, Ontario M5S 3E4 (Canada)] [Department of Materials Science and Engineering, University of Toronto, Toronto, Ontario M5S 3E4 (Canada); Rahimipour, M.R. [Department of Ceramic, Materials and Energy Research Center, Karaj 31787-316 (Iran, Islamic Republic of)] [Department of Ceramic, Materials and Energy Research Center, Karaj 31787-316 (Iran, Islamic Republic of)

2013-01-15T23:59:59.000Z

486

Improved Characterization of Transmitted Wavefront Error on CADB Epoxy-Free Bonded Solid State Laser Materials  

SciTech Connect (OSTI)

Current state-of-the-art and next generation laser systems - such as those used in the NIF and LIFE experiments at LLNL - depend on ever larger optical elements. The need for wide aperture optics that are tolerant of high power has placed many demands on material growers for such diverse materials as crystalline sapphire, quartz, and laser host materials. For such materials, it is either prohibitively expensive or even physically impossible to fabricate monolithic pieces with the required size. In these cases, it is preferable to optically bond two or more elements together with a technique such as Chemically Activated Direct Bonding (CADB{copyright}). CADB is an epoxy-free bonding method that produces bulk-strength bonded samples with negligible optical loss and excellent environmental robustness. The authors have demonstrated CADB for a variety of different laser glasses and crystals. For this project, they will bond quartz samples together to determine the suitability of the resulting assemblies for large aperture high power laser optics. The assemblies will be evaluated in terms of their transmitted wavefront error, and other optical properties.

Bayramian, A

2010-12-09T23:59:59.000Z

487

Essays on Network Formation  

E-Print Network [OSTI]

that may depend on the network of connections among the individuals that make up each group. I assume the existence of a single divisible good, such as a monetary prize, which will be divided amongst the members of the winning network. The probability...

Mueller, William Graham

2012-10-19T23:59:59.000Z

488

Green Networking Basem Shihada  

E-Print Network [OSTI]

business areas for green networking. #12;Resource & Energy Allocation Applications Application Domains #12Green Networking Systems Basem Shihada CEMSE, KAUST Graduate Seminar Sunday Sept. 22nd 2013 #12 connectivity and load will fluctuate rapidly, both in space and time. #12;ICT Energy Consumption Trends

Shihada, Basem

489

BER Science Network Requirements  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Network Network Requirements Report of the Biological and Environmental Research Network Requirements Workshop Conducted July 26 and 27, 2007 BER Science Network Requirements Workshop Biological and Environmental Research Program Office, DOE Office of Science Energy Sciences Network Bethesda, MD - July 26 and 27, 2007 ESnet is funded by the US Dept. of Energy, Office of Science, Advanced Scientific Computing Research (ASCR) program. Dan Hitchcock is the ESnet Program Manager. ESnet is operated by Lawrence Berkeley National Laboratory, which is operated by the University of California for the US Department of Energy under contract DE-AC02-05CH11231. This work was supported by the Directors of the Office of Science, Office of Advanced Scientific Computing Research, Facilities Division, and the Office of Biological &

490

Collective network routing  

DOE Patents [OSTI]

Disclosed are a unified method and apparatus to classify, route, and process injected data packets into a network so as to belong to a plurality of logical networks, each implementing a specific flow of data on top of a common physical network. The method allows to locally identify collectives of packets for local processing, such as the computation of the sum, difference, maximum, minimum, or other logical operations among the identified packet collective. Packets are injected together with a class-attribute and an opcode attribute. Network routers, employing the described method, use the packet attributes to look-up the class-specific route information from a local route table, which contains the local incoming and outgoing directions as part of the specifically implemented global data flow of the particular virtual network.

Hoenicke, Dirk

2014-12-02T23:59:59.000Z

491

Neural Networks and Radial Basis Functions 1. Neural network theory  

E-Print Network [OSTI]

Neural Networks and Radial Basis Functions 1. Neural network theory 1. Since artificial computational solutions to problems in intelligence 2. Neural network theory has held that promise. Existence, psychology, engineering, mathematics 3. A basic component of many neural nets: feed-forward neural networks

Kon, Mark

492

Adoption of Vehicular Ad Hoc Networking Protocols by Networked Robots  

Science Journals Connector (OSTI)

This paper focuses on the utilization of wireless networking in the robotics domain. Many researchers have already equipped their robots with wireless communication capabilities, stimulated by the observation that multi-robot systems tend to have several ... Keywords: Networked robot, Robotic ad hoc network, V2I, V2V, Vehicular ad hoc network, Wireless robot

Wim Vandenberghe; Ingrid Moerman; Piet Demeester

2012-06-01T23:59:59.000Z

493

Seminar: Ad Hoc Networks Konrad Meier Seminar Ad Hoc Networks  

E-Print Network [OSTI]

1 Seminar: Ad Hoc Networks Konrad Meier Seminar Ad Hoc Networks Feasibility of an Aeronautical Mobile Ad Hoc Network Over the North Atlantic Corridor Daniel Medina, Felix Hoffmann, Serkan Ayaz;2 What is the idea? Ad Hoc Network in the North Atlantic Corridor ­ multihop air to air communication

Schindelhauer, Christian

494

Software-Defined Networking Based Capacity Sharing in Hybrid Networks  

E-Print Network [OSTI]

Software-Defined Networking Based Capacity Sharing in Hybrid Networks Mateus A. S. Santos and Bruno proposes a novel approach to capacity sharing in hybrid networked environments, i.e., environments that consist of infrastructure-based as well as infrastructure- less networks. The proposed framework is based

Turletti, Thierry

495

New Paradigm for Seismic Networks: Crowd-Sourced Seismic Networks,  

E-Print Network [OSTI]

#12;New Paradigm for Seismic Networks: Crowd-Sourced Seismic Networks, including Buildings Tom Egill Hauksson #12;SCSN: what does it encompass? · ~360 Seismic Stations · ~60 stations from partners SCSN/SCEDC total of ~26 FTE's #12;Crowd Sourced Networks · Current broadband seismic network

Greer, Julia R.

496

E-Print Network 3.0 - acute hypersensitivity reactions Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to locate... rearrangements and chromosomal translocations observed in human T-cell acute lymphoblastic leukemia (T-ALL) often Source: Ecole Polytechnique, Centre de...

497

E-Print Network 3.0 - aps magnet support Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Effect in MSMAs Bjorn Kiefera and Dimitris C. Lagoudasa a Department of Aerospace... ABSTRACT This work is concerned with the magnetic field-induced rearrangement of...

498

Hydrogen-bridge bonding on semiconductor surfaces:?Density-functional calculations  

Science Journals Connector (OSTI)

The relative stabilities of hydrogen bridge bonds on diamond C(001), Si(001), Ge(001), and GaAs(001) surfaces have been studied within the framework of density functional theory. Hydrogen-bridge bonds are found to be stable on cation terminated GaAs(001) and almost stable on p-type doped Si(001) surfaces with an excess energy of 0.08eV per bridge. Bridge bonds are unstable on n-type doped Si(001) and anion terminated GaAs(001). H-bridges are metastable on intrinsic group IV surfaces, and the excess energy cost diminishes monotonically across the C-Si-Ge series. In stark contrast with group IV semiconductors, the (2×1) monohydride dimer structure is not stable on GaAs(001).

J. M. Ripalda; J. D. Gale; T. S. Jones

2004-12-16T23:59:59.000Z

499

Kids at Camp Discovery Bond Over Building Electric Vehicle | Department of  

Broader source: Energy.gov (indexed) [DOE]

Kids at Camp Discovery Bond Over Building Electric Vehicle Kids at Camp Discovery Bond Over Building Electric Vehicle Kids at Camp Discovery Bond Over Building Electric Vehicle August 13, 2010 - 11:30am Addthis Campers at Camp Discovery put the finishing touches on a newly assembled electric vehicle they built to learn more about EV technology while sharing their experiences with battling cancer. | Photo courtesy of Craig Egan Campers at Camp Discovery put the finishing touches on a newly assembled electric vehicle they built to learn more about EV technology while sharing their experiences with battling cancer. | Photo courtesy of Craig Egan Joshua DeLung Each year, about 150 kids gather during the summer at Camp Discovery in Kerrville, Texas, to learn new things and have fun. But this isn't an ordinary summer camp - the attendees, ages seven to 16, all have been

500

Kids at Camp Discovery Bond Over Building Electric Vehicle | Department of  

Broader source: Energy.gov (indexed) [DOE]

Kids at Camp Discovery Bond Over Building Electric Vehicle Kids at Camp Discovery Bond Over Building Electric Vehicle Kids at Camp Discovery Bond Over Building Electric Vehicle August 13, 2010 - 11:30am Addthis Campers at Camp Discovery put the finishing touches on a newly assembled electric vehicle they built to learn more about EV technology while sharing their experiences with battling cancer. | Photo courtesy of Craig Egan Campers at Camp Discovery put the finishing touches on a newly assembled electric vehicle they built to learn more about EV technology while sharing their experiences with battling cancer. | Photo courtesy of Craig Egan Joshua DeLung Each year, about 150 kids gather during the summer at Camp Discovery in Kerrville, Texas, to learn new things and have fun. But this isn't an ordinary summer camp - the attendees, ages seven to 16, all have been