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Sample records for bond log chemical

  1. Cement Bond Log | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to:RAPIDCavallo Energy JumpCeiling Fan JumpCement Bond Log

  2. Chemical logging of geothermal wells

    DOE Patents [OSTI]

    Allen, Charles A. (Idaho Falls, ID); McAtee, Richard E. (Idaho Falls, ID)

    1981-01-01

    The presence of geothermal aquifers can be detected while drilling in geothermal formations by maintaining a chemical log of the ratio of the concentrations of calcium to carbonate and bicarbonate ions in the return drilling fluid. A continuous increase in the ratio of the concentrations of calcium to carbonate and bicarbonate ions is indicative of the existence of a warm or hot geothermal aquifer at some increased depth.

  3. Chemical Logging | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County,Camilla,Thermal GradientChateau Tebeau LLC Jump to:ConsortiumLogging

  4. Chemical Logging At Dixie Valley Geothermal Area (Los Alamos...

    Open Energy Info (EERE)

    Chemical Logging At Dixie Valley Geothermal Area (Los Alamos National Laboratory, NM, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  5. Log-domain circuit models of chemical reactions

    E-Print Network [OSTI]

    Mandal, Soumyajit

    We exploit the detailed similarities between electronics and chemistry to develop efficient, scalable bipolar or subthreshold log-domain circuits that are dynamically equivalent to networks of chemical reactions. Our ...

  6. Nanoscale metals and semiconductors for the storage of solar energy in chemical bonds

    E-Print Network [OSTI]

    Manthiram, Karthish

    2015-01-01

    for the storage of solar energy in chemical bonds Byfor the storage of solar energy in chemical bonds Copyrightfor the storage of solar energy in chemical bonds By

  7. Chemically bonded phospho-silicate ceramics

    DOE Patents [OSTI]

    Wagh, Arun S. (Orland Park, IL); Jeong, Seung Y. (Westmont, IL); Lohan, Dirk (Chicago, IL); Elizabeth, Anne (Chicago, IL)

    2003-01-01

    A chemically bonded phospho-silicate ceramic formed by chemically reacting a monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and a sparsely soluble oxide, with a sparsely soluble silicate in an aqueous solution. The monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and sparsely soluble oxide are both in powder form and combined in a stochiometric molar ratio range of (0.5-1.5):1 to form a binder powder. Similarly, the sparsely soluble silicate is also in powder form and mixed with the binder powder to form a mixture. Water is added to the mixture to form a slurry. The water comprises 50% by weight of the powder mixture in said slurry. The slurry is allowed to harden. The resulting chemically bonded phospho-silicate ceramic exhibits high flexural strength, high compression strength, low porosity and permeability to water, has a definable and bio-compatible chemical composition, and is readily and easily colored to almost any desired shade or hue.

  8. A Corpuscular Picture of Electrons in Chemical Bond

    E-Print Network [OSTI]

    Ando, Koji

    2015-01-01

    We introduce a theory of chemical bond with a corpuscular picture of electrons. It employs a minimal set of localized electron wave packets with 'floating and breathing' degrees of freedom and the spin-coupling of non-orthogonal valence-bond theory. It accurately describes chemical bonds in ground and excited states of spin singlet and triplet, in a distinct manner from conventional theories, indicating potential for establishing a dynamical theory of electrons in chemical bonds.

  9. Material Properties of Chemically Bonded Phosphate Ceramic/Wood Interfaces

    E-Print Network [OSTI]

    Collins, Gary S.

    Material Properties of Chemically Bonded Phosphate Ceramic/Wood Interfaces M.J. Benjamin, K Chemically bonded phosphate ceramics (CBPCs) are man made inorganic solids that lie in between hydraulic cements and ceramics . Normally, ceramics are sintered at temperatures ranging from 700-2000C

  10. Proton Transfer and Hydrogen Bonding in Chemical and Biological

    E-Print Network [OSTI]

    Amrhein, Valentin

    Proton Transfer and Hydrogen Bonding in Chemical and Biological Systems: A Force Field Approach and support. i #12;ii #12;Abstract Proton transfer and hydrogen bonds are fundamental for the function be regarded as incipient proton transfer reactions, so theoretically they can be de- scribed in unitary way

  11. Log-Domain Circuit Models of Chemical Reactions Soumyajit Mandal and Rahul Sarpeshkar

    E-Print Network [OSTI]

    Sarpeshkar, Rahul

    Log-Domain Circuit Models of Chemical Reactions Soumyajit Mandal and Rahul Sarpeshkar Department to networks of chemical reactions. Our circuits can be used for transient and steady-state simulations the energy barrier of a chemical reaction, exponentially changing its speed. In an analogous fashion, gate

  12. Chemical Shielding Tensors for a Silicon-Carbon Double Bond

    E-Print Network [OSTI]

    Apeloig, Yitzhak

    Chemical Shielding Tensors for a Silicon-Carbon Double Bond Jarrod J. Buffy, Robert West,*, Michael of NMR chemical shielding tensors (CST) have been important in aiding the understanding of the nature shielding tensors have been reported and interpreted for compounds containing SidSi,1 PdP,2 SndSn,3 Cd

  13. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes...

    Office of Scientific and Technical Information (OSTI)

    Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion Batteries: A XANES Study Citation Details In-Document Search Title: Chemical Bonding In Amorphous Si...

  14. Chemical bond and entanglement of electrons in the hydrogen molecule

    E-Print Network [OSTI]

    Nikos Iliopoulos; Andreas F. Terzis

    2014-08-01

    We theoretically investigate the quantum correlations (in terms of concurrence of indistinguishable electrons) in a prototype molecular system (hydrogen molecule). With the assistance of the standard approximations of the linear combination of atomic orbitals and the con?guration interaction methods we describe the electronic wavefunction of the ground state of the H2 molecule. Moreover, we managed to ?find a rather simple analytic expression for the concurrence (the most used measure of quantum entanglement) of the two electrons when the molecule is in its lowest energy. We have found that concurrence does not really show any relation to the construction of the chemical bond.

  15. Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical Exchange Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical ExchangeVed: January 12, 2010 Hydrogen-bonded complexes between phenol and phenylacetylene are studied using ultrafast hydrogen bonding acceptor sites (phenyl or acetylene) that compete for hydrogen bond donors in solution

  16. Tuning the Metal-Adsorbate Chemical Bond through the Ligand Effect...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning the Metal-Adsorbate Chemical Bond through the Ligand Effect on Platinum Subsurface Alloys Tuesday, July 31, 2012 The ability to design and control the activities of...

  17. Concept of chemical bond and aromaticity based on quantum information theory

    E-Print Network [OSTI]

    Szilvási, T; Legeza, Ö

    2015-01-01

    Quantum information theory (QIT) emerged in physics as standard technique to extract relevant information from quantum systems. It has already contributed to the development of novel fields like quantum computing, quantum cryptography, and quantum complexity. This arises the question what information is stored according to QIT in molecules which are inherently quantum systems as well. Rigorous analysis of the central quantities of QIT on systematic series of molecules offered the introduction of the concept of chemical bond and aromaticity directly from physical principles and notions. We identify covalent bond, donor-acceptor dative bond, multiple bond, charge-shift bond, and aromaticity indicating unified picture of fundamental chemical models from ab initio.

  18. Method of waste stabilization with dewatered chemically bonded phosphate ceramics

    DOE Patents [OSTI]

    Wagh, Arun; Maloney, Martin D.

    2010-06-29

    A method of stabilizing a waste in a chemically bonded phosphate ceramic (CBPC). The method consists of preparing a slurry including the waste, water, an oxide binder, and a phosphate binder. The slurry is then allowed to cure to a solid, hydrated CBPC matrix. Next, bound water within the solid, hydrated CBPC matrix is removed. Typically, the bound water is removed by applying heat to the cured CBPC matrix. Preferably, the quantity of heat applied to the cured CBPC matrix is sufficient to drive off water bound within the hydrated CBPC matrix, but not to volatalize other non-water components of the matrix, such as metals and radioactive components. Typically, a temperature range of between 100.degree. C.-200.degree. C. will be sufficient. In another embodiment of the invention wherein the waste and water have been mixed prior to the preparation of the slurry, a select amount of water may be evaporated from the waste and water mixture prior to preparation of the slurry. Another aspect of the invention is a direct anyhydrous CBPC fabrication method wherein water is removed from the slurry by heating and mixing the slurry while allowing the slurry to cure. Additional aspects of the invention are ceramic matrix waste forms prepared by the methods disclosed above.

  19. EFFECT OF EXCIMER LASER IRRADIATION OF BIODEGRADABLE POLYMER ON ITS CHEMICAL BONDING

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    EFFECT OF EXCIMER LASER IRRADIATION OF BIODEGRADABLE POLYMER ON ITS CHEMICAL BONDING Paper M1306 profile is favorable for surface treatment. The effects of excimer laser irradiation on the surface irradiation as a hea

  20. Effect of excimer laser irradiation on crystallinity and chemical bonding of biodegradable polymer

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    Effect of excimer laser irradiation on crystallinity and chemical bonding of biodegradable polymer: Biodegradable polymer Poly(L-lactic acid) Laser irradiation Chemical modification Crystallinity Radical mobility is favorable for surface treatment. The effects of excimer laser irradiation on the surface morphology

  1. Chemical Bonding: The Classical Description sharing or transferring electrons between atoms

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    Chemical Bonding: The Classical Description sharing or transferring electrons between atoms LEWIS electron dot diagram -> formula (SF6) VSEPR (valence-shell electron-pair repulsion) theory Molecular Structure (w/o quantum mechanics) Chapter. 3 Two or more atoms approach -> their electrons interact and form

  2. Noncovalent interaction or chemical bonding between alkaline earth cations and benzene? A quantum chemistry study using

    E-Print Network [OSTI]

    Sussman, Joel L.

    Noncovalent interaction or chemical bonding between alkaline earth cations and benzene? A quantum earth metal ion±benzene complexes were performed using the density-functional theory (DFT) B3LYP and ab of the al- kaline earth metal ions to benzene may be attributed to s±p and p±p interactions, which are signi

  3. Multi-layered, chemically bonded lithium-ion and lithium/air batteries

    DOE Patents [OSTI]

    Narula, Chaitanya Kumar; Nanda, Jagjit; Bischoff, Brian L; Bhave, Ramesh R

    2014-05-13

    Disclosed are multilayer, porous, thin-layered lithium-ion batteries that include an inorganic separator as a thin layer that is chemically bonded to surfaces of positive and negative electrode layers. Thus, in such disclosed lithium-ion batteries, the electrodes and separator are made to form non-discrete (i.e., integral) thin layers. Also disclosed are methods of fabricating integrally connected, thin, multilayer lithium batteries including lithium-ion and lithium/air batteries.

  4. Phonon-energy-coupling enhancement: Strengthening the chemical bonds of the SiO2/Si system

    E-Print Network [OSTI]

    Chen, Zhi

    Phonon-energy-coupling enhancement: Strengthening the chemical bonds of the SiO2/Si system Zhi Chena and Jun Guo Department of Electrical and Computer Engineering and Center for Nanoscale Science

  5. Change Log

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Log NERSC-8 Trinity Benchmarks Change Log 09032013 Correction applied to MiniDFT web-page (to remove inconsistency with MiniDFT README). Capability Improvement...

  6. Chemical Bonding in Aqueous Ferrocyanide: Experimental and Theoretical X-ray Spectroscopic Study

    E-Print Network [OSTI]

    Engel, Nicholas; Suljoti, Edlira; Garcia-Diez, Raul; Lange, Kathrin M; Atak, Kaan; Golnak, Ronny; Kothe, Alexander; Dantz, Marcus; Kühn, Oliver; Aziz, Emad F

    2013-01-01

    Resonant inelastic X-ray scattering (RIXS) and X-ray absorption (XA) experiments at the iron L- and nitrogen K-edge are combined with high-level first principles restricted active space self-consistent field (RASSCF) calculations for a systematic investigation of the nature of the chemical bond in potassium ferrocyanide in aqueous solution. The atom- and site-specific RIXS excitations allow for direct observation of ligand-to-metal (Fe L-edge) and metal-to-ligand (N K-edge) charge transfer bands and thereby evidence for strong {\\sigma}-donation and {\\pi}-back-donation. The effects are identified by comparing experimental and simulated spectra related to both the unoccupied and occupied molecular orbitals in solution.

  7. Novel Chemically-Bonded Phosphate Ceramic Borehole Sealants (Ceramicretes) for Arctic Environments

    SciTech Connect (OSTI)

    Shirish Patil; Godwin A. Chukwu; Gang Chen; Santanu Khataniar

    2008-12-31

    Novel chemically bonded phosphate ceramic borehole sealant, i.e. Ceramicrete, has many advantages over conventionally used permafrost cement at Alaska North Slope (ANS). However, in normal field practices when Ceramicrete is mixed with water in blenders, it has a chance of being contaminated with leftover Portland cement. In order to identify the effect of Portland cement contamination, recent tests have been conducted at BJ services in Tomball, TX as well as at the University of Alaska Fairbanks with Ceramicrete formulations proposed by the Argonne National Laboratory. The tests conducted at BJ Services with proposed Ceramicrete formulations and Portland cement contamination have shown significant drawbacks which has caused these formulations to be rejected. However, the newly developed Ceramicrete formulation at the University of Alaska Fairbanks has shown positive results with Portland cement contamination as well as without Portland cement contamination for its effective use in oil well cementing operations at ANS.

  8. Method for producing chemically bonded phosphate ceramics and for stabilizing contaminants encapsulated therein utilizing reducing agents

    DOE Patents [OSTI]

    Singh, Dileep (Naperville, IL); Wagh, Arun S. (Orland Park, IL); Jeong, Seung-Young (Westmont, IL)

    2000-01-01

    Known phosphate ceramic formulations are improved and the ability to produce iron-based phosphate ceramic systems is enabled by the addition of an oxidizing or reducing step during the acid-base reactions that form the phosphate ceramic products. The additives allow control of the rate of the acid-base reactions and concomitant heat generation. In an alternate embodiment, waste containing metal anions are stabilized in phosphate ceramic products by the addition of a reducing agent to the phosphate ceramic mixture. The reduced metal ions are more stable and/or reactive with the phosphate ions, resulting in the formation of insoluble metal species within the phosphate ceramic matrix, such that the resulting chemically bonded phosphate ceramic product has greater leach resistance.

  9. Proton chemical shift anisotropy measurements of hydrogen-bonded functional groups by fast magic-angle spinning solid-state NMR

    E-Print Network [OSTI]

    Proton chemical shift anisotropy measurements of hydrogen-bonded functional groups by fast magic) spectroscopy is one of the most suitable tools for studying hydrogen bonding phenomena. Proton NMR spectroscopy theoretically4 and experimentally5 that the isotropic chemical shifts of hydroxyl or amide protons depend

  10. Chemical Bonding and Structural Information of Black Carbon Reference Materials and Individual Carbonaceous Atmospheric Aerosols

    E-Print Network [OSTI]

    Hopkins, Rebecca J.; Tivanski, Alexei V.; Marten, Bryan D.; Gilles, Mary K.

    2007-01-01

    A. (1998), Determination of chemical- structural changes inOptical, physical, and chemical properties of tar ballsE. (2001), Study on the chemical character of water soluble

  11. Change Log

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &BradburyMay 1,CenterJohnCeremony TheChallenges andChange Log

  12. Change Log

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &BradburyMay 1,CenterJohnCeremony TheChallenges andChange LogChange

  13. Chemical Distribution and Bonding of Lithium in Intercalated Graphite: Identification with Optimized Electron Energy Loss Spectroscopy

    SciTech Connect (OSTI)

    Wang, Feng; Graetz, Jason; Moreno, M. Sergio; Ma, Chao; Wu, Lijun; Volkov, Vyacheslav; Zhu, Yimei

    2011-01-01

    Direct mapping of the lithium spatial distribution and the chemical state provides critical information on structure-correlated lithium transport in electrode materials for lithium batteries. Nevertheless, probing lithium, the lightest solid element in the periodic table, poses an extreme challenge with traditional X-ray or electron scattering techniques due to its weak scattering power and vulnerability to radiation damage. Here, we report nanoscale maps of the lithium spatial distribution in electrochemically lithiated graphite using electron energy loss spectroscopy in the transmission electron microscope under optimized experimental conditions. The electronic structure of the discharged graphite was obtained from the near-edge fine structure of the Li and C K-edges and ab initio calculations. A 2.7 eV chemical shift of the Li K-edge, along with changes in the density of states, reveals the ionic nature of the intercalated lithium with significant charge transfer to the graphene sheets. Direct mapping of lithium in graphite revealed nanoscale inhomogeneities (nonstoichiometric regions), which are correlated with local phase separation and structural disorder (i.e., lattice distortion and dislocations) as observed by high-resolution transmission electron microscopy. The surface solid?electrolyte interphase (SEI) layer was also imaged and determined to have a thickness of 10?50 nm, covering both edge and basal planes with LiF as its primary inorganic component. The Li K-edge spectroscopy and mapping, combined with electron microscopy-based structural analysis provide a comprehensive view of the structure-correlated lithium intercalation in graphite and of the formation of the SEI layer.

  14. Chemical Distribution and Bonding of Lithium in Intercalated Graphite: Identification with Optimized Electron Energy Loss Spectroscopy

    SciTech Connect (OSTI)

    Zhu, Y.; Wang, F.; Graetz, J.; Moreno, M.S.; Ma, C.; Wu, L.; Volkov, V.

    2011-02-01

    Direct mapping of the lithium spatial distribution and the chemical state provides critical information on structure-correlated lithium transport in electrode materials for lithium batteries. Nevertheless, probing lithium, the lightest solid element in the periodic table, poses an extreme challenge with traditional X-ray or electron scattering techniques due to its weak scattering power and vulnerability to radiation damage. Here, we report nanoscale maps of the lithium spatial distribution in electrochemically lithiated graphite using electron energy loss spectroscopy in the transmission electron microscope under optimized experimental conditions. The electronic structure of the discharged graphite was obtained from the near-edge fine structure of the Li and C K-edges and ab initio calculations. A 2.7 eV chemical shift of the Li K-edge, along with changes in the density of states, reveals the ionic nature of the intercalated lithium with significant charge transfer to the graphene sheets. Direct mapping of lithium in graphite revealed nanoscale inhomogeneities (nonstoichiometric regions), which are correlated with local phase separation and structural disorder (i.e., lattice distortion and dislocations) as observed by high-resolution transmission electron microscopy. The surface solid-electrolyte interphase (SEI) layer was also imaged and determined to have a thickness of 10-50 nm, covering both edge and basal planes with LiF as its primary inorganic component. The Li K-edge spectroscopy and mapping, combined with electron microscopy-based structural analysis provide a comprehensive view of the structure-correlated lithium intercalation in graphite and of the formation of the SEI layer.

  15. Volume 136, number 6 CHEMICAL PHYSICS LETTERS 22 May 1987 MECHANISM FOR BOND-SELECTIVE PROCESSES IN LASER DESORPTION

    E-Print Network [OSTI]

    for short pulse excitation. Deviations from such statistical behavior require the existence of "bottlenecks pumped. A bottleneck may occur however in the energy flow from the sur- face-adsorbate van der Waals bond to be pumped via excitation of the physisorption bond. The energy flow out of this bond and into the mol- 0 009

  16. Effects of lithium doping on microstructure, electrical properties, and chemical bonds of sol-gel derived NKN thin films

    SciTech Connect (OSTI)

    Lin, Chun-Cheng; Chen, Chan-Ching; Weng, Chung-Ming; Chu, Sheng-Yuan; Tsai, Cheng-Che

    2015-02-28

    Highly (100/110) oriented lead-free Li{sub x}(Na{sub 0.5}K{sub 0.5}){sub 1?x}NbO{sub 3} (LNKN, x?=?0, 0.02, 0.04, and 0.06) thin films are fabricated on Pt/Ti/SiO{sub 2}/Si substrates via a sol-gel processing method. The lithium (Li) dopants modify the microstructure and chemical bonds of the LNKN films, and therefore improve their electrical properties. The optimal values of the remnant polarization (P{sub r}?=?14.3??C/cm{sup 2}), piezoelectric coefficient (d{sub 33}?=?48.1?pm/V), and leakage current (<10{sup ?5} A/cm{sup 2}) are obtained for a lithium addition of x?=?0.04 (i.e., 4 at.?%). The observation results suggest that the superior electrical properties are the result of an improved crystallization, a larger grain size, and a smoother surface morphology. It is shown that the ion transport mechanism is dominated by an Ohmic behavior under low electric fields and the Poole-Frenkel emission effect under high electric fields.

  17. Marked influence of the nature of chemical bond on CP-violating signature in molecular ions $\\mathrm{HBr}^{+}$ and $\\mathrm{HI}^{+}$

    E-Print Network [OSTI]

    Boris Ravaine; Sergey G. Porsev; Andrei Derevianko

    2004-11-30

    Heavy polar molecules offer a great sensitivity to the electron Electric Dipole Moment(EDM). To guide emerging searches for EDMs with molecular ions, we estimate the EDM-induced energy corrections for hydrogen halide ions $\\mathrm{HBr}^{+}$ and $\\mathrm{HI}^{+}$ in their respective ground $X ^2\\Pi_{3/2}$ states. We find that the energy corrections due to EDM for the two ions differ by an unexpectedly large factor of fifteen. We demonstrate that a major part of this enhancement is due to a dissimilarity in the nature of the chemical bond for the two ions: the bond that is nearly of ionic character in $\\mathrm{HBr}^{+}$ exhibits predominantly covalent nature in $\\mathrm{HI}^{+}$. We conclude that because of this enhancement the HI$^+$ ion may be a potentially competitive candidate for the EDM search.

  18. Characterization of anodic bonding

    E-Print Network [OSTI]

    Tudryn, Carissa Debra, 1978-

    2004-01-01

    Anodic bonding is a common process used in MicroElectroMechanical Systems (MEMS) device fabrication and packaging. Polycrystalline chemical vapor deposited (CVD) silicon carbide (SiC) is emerging as a new MEMS device and ...

  19. Biomass from Logging Residue and Mill Residue

    E-Print Network [OSTI]

    as a renewable energy resource or for chemical extraction. This report represents the most current data harvesting or are cut off the central stem of the tree due to a merchantability standard. Limbs refer for energy production or chemical extraction. Table 1 shows the logging residue available in East Texas

  20. An XPS study on the chemical bond structure at the interface between SiO{sub x}N{sub y} and N doped polyethylene terephthalate

    SciTech Connect (OSTI)

    Ding Wanyu [School of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028 (China); Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Ministry of Education, Dalian University of Technology, Dalian 116024 (China); Li Li; Zhang Lina; Chai Weiping [School of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028 (China); Ju Dongying [Department of Material Science and Engineering, Saitama Institute of Technology, Fukaya 369-0293 (Japan); Peng Shou [China Triumph International Engineering Co., Ltd., 2000 Zhongshanbei Road, 200063 Shanghai (China)

    2013-03-14

    The super-thin silicon oxynitride (SiO{sub x}N{sub y}) films were deposited onto the N doped polyethylene terephthalate (PET) surface. Varying the N doping parameters, the different chemical bond structures were obtained at the interface between the SiO{sub x}N{sub y} film and the PET surface. X-ray photoelectron spectra results showed that at the initial stage of SiO{sub x}N{sub y} film growth, the C=N bonds could be broken and C-N-Si crosslink bonds could be formed at the interface of SiO{sub x}N{sub y}/PET, which C=N bonds could be formed onto the PET surface during the N doping process. At these positions, the SiO{sub x}N{sub y} film could be crosslinked well onto the PET surface. Meanwhile, the doped N could crosslink the [SiO{sub 4}] and [SiN{sub 4}] tetrahedrons, which could easily form the dense layer structure at the initial stage of SiO{sub x}N{sub y} film growth, instead of the ring and/or chain structures of [SiO{sub 4}] tetrahedrons crosslinked by O. Finally, from the point of applying SiO{sub x}N{sub y}/PET complex as the substrate, the present work reveals a simple way to crosslink them, as well as the crosslink model and physicochemical mechanism happened at the interface of complex.

  1. NbF{sub 5} and TaF{sub 5}: Assignment of {sup 19}F NMR resonances and chemical bond analysis from GIPAW calculations

    SciTech Connect (OSTI)

    Biswal, Mamata; Body, Monique; Legein, Christophe; Sadoc, Aymeric; Boucher, Florent

    2013-11-15

    The {sup 19}F isotropic chemical shifts (?{sub iso}) of two isomorphic compounds, NbF{sub 5} and TaF{sub 5}, which involve six nonequivalent fluorine sites, have been experimentally determined from the reconstruction of 1D {sup 19}F MAS NMR spectra. In parallel, the corresponding {sup 19}F chemical shielding tensors have been calculated using the GIPAW method for both experimental and DFT-optimized structures. Furthermore, the [M{sub 4}F{sub 20}] units of NbF{sub 5} and TaF{sub 5} being held together by van der Waals interactions, the relevance of Grimme corrections to the DFT optimization processes has been evaluated. However, the semi-empirical dispersion correction term introduced by such a method does not show any significant improvement. Nonetheless, a complete and convincing assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} is obtained, ensured by the linearity between experimental {sup 19}F ?{sub iso} values and calculated {sup 19}F isotropic chemical shielding ?{sub iso} values. The effects of the geometry optimizations have been carefully analyzed, confirming among other matters, the inaccuracy of the experimental structure of NbF{sub 5}. The relationships between the fluorine chemical shifts, the nature of the fluorine atoms (bridging or terminal), the position of the terminal ones (opposite or perpendicular to the bridging ones), the fluorine charges, the ionicity and the length of the M–F bonds have been established. Additionally, for three of the {sup 19}F NMR lines of NbF{sub 5}, distorted multiplets, arising from {sup 1}J-coupling and residual dipolar coupling between the {sup 19}F and {sup 93}Nb nuclei, were simulated yielding to values of {sup 93}Nb–{sup 19}F {sup 1}J-coupling for the corresponding fluorine sites. - Graphical abstract: The complete assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} allow establishing relationships between the {sup 19}F ?{sub iso} values, the nature of the fluorine atoms (bridging or terminal), the position of the terminal ones (opposite or perpendicular to the bridging ones), the fluorine charges, the ionicity and the length of the M–F bonds. Display Omitted - Highlights: • The {sup 19}F ?{sub iso} values of NbF{sub 5} and TaF{sub 5} have been determined. • The {sup 19}F chemical shielding tensors have been calculated using the GIPAW method. • A confident assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} is obtained. • The relationships between the {sup 19}F?{sub iso} values and the M–F bonds features are established.

  2. M01506020006 log check dam

    E-Print Network [OSTI]

    XY! ¬« 35-0027 M01506020006 log check dam M01506020007 log check dam M01506020001 log check dam M location Berm Channel/swale Check dam Sediment trap/basin Gabion Seed and mulch Cap Established vegetation

  3. October 2006 LOG MANAGEMENT: USING

    E-Print Network [OSTI]

    to Computer Security Log Management NIST's Information Technology Laboratory recently issued SpecialOctober 2006 LOG MANAGEMENT: USING COMPUTER AND NETWORK RECORDS TO IMPROVE INFORMATION SECURITY LOG MANAGEMENT: USING COMPUTER AND NETWORK RECORDS TO IMPROVE INFORMATION SECURITY Shirley Radack, Editor

  4. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Chaplin, Martin

    2007-01-01

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperature...

  5. G8 Illegal Logging Dialogue G8 Illegal Logging Dialogue

    E-Print Network [OSTI]

    G8 Illegal Logging Dialogue G8 Illegal Logging Dialogue A global legislator partnership for legal International http://www.illegal-logging.info/item_single.php?item=presentation&item_id=133&approach_id=8 #12;G8 Illegal Logging Dialogue Presentation purpose · role of GLOBE International · aim and objectives of the G8

  6. NMR logging apparatus

    DOE Patents [OSTI]

    Walsh, David O; Turner, Peter

    2014-05-27

    Technologies including NMR logging apparatus and methods are disclosed. Example NMR logging apparatus may include surface instrumentation and one or more downhole probes configured to fit within an earth borehole. The surface instrumentation may comprise a power amplifier, which may be coupled to the downhole probes via one or more transmission lines, and a controller configured to cause the power amplifier to generate a NMR activating pulse or sequence of pulses. Impedance matching means may be configured to match an output impedance of the power amplifier through a transmission line to a load impedance of a downhole probe. Methods may include deploying the various elements of disclosed NMR logging apparatus and using the apparatus to perform NMR measurements.

  7. Logging in to Franklin

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse BergkampCenter (LMI-EFRC)Lodging Lodging Meeting Hotel -LoggingLogging

  8. ILLEGAL LOGGING IN INDONESIA

    E-Print Network [OSTI]

    to feed the country's enormous timber processing mills. Indonesia's paper and pulp industry has a record products. The U.S. Bureau of Labor Statistics reports that the logging, wood, paper and cabinetry industries have lost 242,000 jobs, or roughly 23 percent of its workforce, since 2006.viii Conservative

  9. Category:Chemical Logging | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,Cammack Village,8199089°,Analytical Modeling JumpCLEAN Partner

  10. Internet Data logging and Display 

    E-Print Network [OSTI]

    Sweeney, J., Jr.; Culp, C.; Haberl, J. S.

    2001-01-01

    The current energy savings technology relies on conventional data logging systems, in which two major barriers exist. Formost is the fact that retrieving the energy data is not convenient, and the cost of the data logging ...

  11. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Martin Chaplin

    2007-06-10

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

  12. Logging in to Edison

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse BergkampCenter (LMI-EFRC)Lodging Lodging Meeting Hotel -Logging

  13. Coiled-tubing logging system

    SciTech Connect (OSTI)

    Howell, E.P.; Smith, L.J.; Blount, C.G.

    1988-03-01

    Techniques have been developed to use coiled tubing containing a seven-conductor wireline to facilitate logging operations. Equipment has been designed to permit the connection of conventional logging tools to the tubing and the recording of logs. Operating techniques have been developed and applied under various wellbore conditions. The system allows traditional log measurements in a well while wellbore conditions are controlled. Advantages of the system include reduced wellbore pressure during peroration to maximize perforation performance; lubrication during pulling or pushing a logging tool through a borehole so that a more uniform velocity can be maintained with a logging sonde; continued circulation and thus borehole stability during logging; temperature reduction for improved reliability of logging sonde electronics in hot holes; and more stable positioning of perforation equipment. The ability of coiled tubing to push tools down highly deviated or horizontal wellbores makes logging or perforating feasible in these wells. Expenses can often be reduced with coiled-tubing logging because a rig is unnecessary during many operations.

  14. Coiled-tubing logging system

    SciTech Connect (OSTI)

    Howell, E.P.; Smith, L.J.; Blount, C.G.

    1986-01-01

    Techniques have been developed which use coiled tubing containing a seven-conductor wireline to facilitate logging operations. Equipment has been designed which permits the connection of conventional logging tools to the tubing and the recording of logs. Also, operating techniques have been developed and applied under various wellbore conditions. The system allows traditional log measurements in a well while controlling wellbore conditions. Advantages of the system include: reduced wellbore pressure during perforation to minimize formation damage: lubrication while pulling or pushing a logging tool through a borehole so that a more uniform velocity can be maintained with a logging sonde; continued circulation and thus borehole stability while logging; temperature reduction for improved reliability of logging sonde electronics in hot holes; and more stable positioning of perforation equipment. The ability of coiled tubing to push tools down highly deviated, or even horizontal wellbores, makes logging or perforating feasible in these wells. Expenses can often be reduced with coiled-tubing logging, since a rig is unnecessary during many operations.

  15. April 27, 2010 Well Logging I

    E-Print Network [OSTI]

    Ito, Garrett

    completing drilling) Logging While Drilling (LWD) Both use similar tools and each has its advantages seismic profile (VSP) · Logging While Drilling (LWD) Standard Logs #12;4/26/2010 3 · Nuclear Logs (VSP) · Logging While Drilling (LWD) · Nuclear Logs · Sonic - Monopole - Dipole · Electrical

  16. Acoustic paramagnetic logging tool

    DOE Patents [OSTI]

    Vail, III, William B. (Bothell, WA)

    1988-01-01

    New methods and apparatus are disclosed which allow measurement of the presence of oil and water in geological formations using a new physical effect called the Acoustic Paramagnetic Logging Effect (APLE). The presence of petroleum in formation causes a slight increase in the earth's magnetic field in the vicinity of the reservoir. This is the phenomena of paramagnetism. Application of an acoustic source to a geological formation at the Larmor frequency of the nucleons present causes the paramagnetism of the formation to disappear. This results in a decrease in the earth3 s magnetic field in the vicinity of the oil bearing formation. Repetitively frequency sweeping the acoustic source through the Larmor frequency of the nucleons present (approx. 2 kHz) causes an amplitude modulation of the earth's magnetic field which is a consequence of the APLE. The amplitude modulation of the earth's magnetic field is measured with an induction coil gradiometer and provides a direct measure of the amount of oil and water in the excitation zone of the formation . The phase of the signal is used to infer the longitudinal relaxation times of the fluids present, which results in the ability in general to separate oil and water and to measure the viscosity of the oil present. Such measurements may be preformed in open boreholes and in cased well bores.

  17. LOG HAZARD REGRESSION Huiying Sun

    E-Print Network [OSTI]

    Heckman, Nancy E.

    LOG HAZARD REGRESSION by Huiying Sun Ph.D, Harbin Institute of Technology, Harbin, CHINA, 1991 .................................................................... .................................................................... .................................................................... .................................................................... THE UNIVERSITY OF BRITISH COLUMBIA September, 1999 c flHuiying Sun, 1999 #12; Abstract We propose using

  18. Health Calculators & Logs - HPMC Occupational Health Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Calculators & Logs Health Education & Wellness Downloads & Patient Materials Health & Productivity Health Calculators & Logs Body Mass Index Health Coaching Health Fairs and...

  19. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

  20. Effect of the valence electron concentration on the bulk modulus and chemical bonding in Ta{sub 2}AC and Zr{sub 2}AC (A=Al, Si, and P)

    SciTech Connect (OSTI)

    Schneider, Jochen M.; Music, Denis; Sun Zhimei

    2005-03-15

    We have studied the effect of the valence electron concentration, on the bulk modulus and the chemical bonding in Ta{sub 2}AC and Zr{sub 2}AC (A=Al, Si, and P) by means of ab initio calculations. Our equilibrium volume and the hexagonal ratio (c/a) agree well (within 2.7% and 1.2%, respectively) with previously published experimental data for Ta{sub 2}AlC. The bulk moduli of both Ta{sub 2}AC and Zr{sub 2}AC increase as Al is substituted with Si and P by 13.1% and 20.1%, respectively. This can be understood since the substitution is associated with an increased valence electron concentration, resulting in band filling and an extensive increase in cohesion.

  1. briefing paper Controlling Illegal Logging

    E-Print Network [OSTI]

    -producing countries, the inclusion of provisions on illegal logging in free trade agreements (in the US­Peru Free Trade Agreement for example), and public procurement policies for timber.4 Within Europe, discussion has to control imports of illegal timber. The EU's Action Plan on Forest Law Enforcement, Governance and Trade

  2. Investing in Bonds 

    E-Print Network [OSTI]

    Johnson, Jason; Polk, Wade

    2002-08-12

    bonds Corporate bonds are generally the riskiest of all fixed-income securities because companies? even large, stable ones?are much more susceptible than govern- ments to economic problems, mis- management and competition. However, corporate bonds can...

  3. Energy Citations Database (ECD) - Alerts Log On

    Office of Scientific and Technical Information (OSTI)

    Log On You must Log On to use the ECD Alerts. Alerts provide users with e-mail notification of updates to the ECD in specific areas of interest. If you wish to receive an Alert and...

  4. Bivariate Log Birnbaum-Saunders Distribution

    E-Print Network [OSTI]

    Kundu, Debasis

    Bivariate Log Birnbaum-Saunders Distribution Debasis Kundu1 Abstract Univariate Birnbaum-Saunders distribution has received a considerable amount of attention in recent years. Rieck and Nedelman (1991, 'A log-linear model for the Birnbaum-Saunders distribution', Technometrics, 51-60) introduced a log Birnbaum- Saunders

  5. Log interpretation of shaly sandstones 

    E-Print Network [OSTI]

    Baker, Joel Foster

    1987-01-01

    and Gas, Arco Oil and Gas, and Sun Oil Companies for their contributions of cores, logs, and other valuable data. Their contributions were an immense help in formulating and supporting the ideas developed in my study. I also wish to express gratitute... from the Reese Oil and Gas Intracoastal Land ?2 well in the Bayou Cholpe field, West Baton Parish, Louisiana, and from the Arco Hankamer 630-1 well in Newton County, Texas. The cores were described and sampled for petrographic analysis. To determine...

  6. Mud Logging | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII Jump to: navigation, searchsource HistoryCharleston,Peak UtilityLogging Jump to:

  7. Method of forming a chemical composition

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); Klingler, Kerry M. (Idaho Falls, ID); Zollinger, William T. (Idaho Falls, ID); Wendt, Kraig M. (Idaho Falls, ID)

    2007-10-09

    A method of forming a chemical composition such as a chemical hydride is described and which includes the steps of selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of hydrogen; and exposing the selected composition to an amount of ionizing radiation to encourage the changing of the chemical bonds of the selected composition, and chemically reacting the selected composition with the source of hydrogen to facilitate the formation of a chemical hydride.

  8. Chemical Zeolites Combinatorial . . .

    E-Print Network [OSTI]

    Servatius, Brigitte

    Chemical Zeolites Combinatorial . . . Realization 2d Zeolites Finite Zeolites The Layer . . . Holes University (Brigitte Servatius -- WPI) #12;Chemical Zeolites Combinatorial . . . Realization 2d Zeolites. Chemical Zeolites · crystalline solid · units: Si + 4O Si O O O O · two covalent bonds per oxygen #12

  9. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of...

  10. Essays on corporate bonds

    E-Print Network [OSTI]

    Bao, Jack (Jack C.)

    2009-01-01

    This thesis consists of three empirical essays on corporate bonds, examining the role of both credit risk and liquidity. In the first chapter, I test the ability of structural models of default to price corporate bonds in ...

  11. Identification of products containing {single_bond}COOH, {single_bond}OH, and {single_bond}C{double_bond}O in atmospheric oxidation of hydrocarbons

    SciTech Connect (OSTI)

    Yu, J.; Flagan, R.C.; Seinfeld, J.H.

    1998-08-15

    Atmospheric oxidation of hydrocarbons by hydroxyl radicals and ozone leads to products containing {single_bond}COOH, {single_bond}OH, and {single_bond}C{double_bond}O functional groups. The high polarity of such compounds precludes direct GC-MS analysis. In addition, many such compounds often exist in a single sample at trace levels. An analytical method has been developed to identify compounds containing one or more functional groups of carbonyl, carboxy, and hydroxy in atmospheric samples. In the method, {single_bond}C{double_bond}O groups are derivatized using O-(2,3,4,5,6-pentafluorobenzyl) hydroxy amine(PFBHA), and {single_bond}COOH and {single_bond}OH groups are derivatized using a silylation reagent N,O-bis(trimethylsilyl)-trifluoroacetamide (BSTFA). The derivatives are easily resolved by a GC column. The chemical ionization mass spectra of these derivatives exhibit several pseudomolecular ions, allowing unambiguous determination of molecular weights. Functional group identification is accomplished by monitoring the ions in the electron ionization mass spectra that are characteristic of each functional group derivative: m/z 181 for carbonyl and m/z 73 and 75 for carboxyl and hydroxy groups. The method is used to identify products in laboratory studies of ozone oxidation of {alpha}-pinene and {Delta}{sup 3}-carene.

  12. Leak checker data logging system

    DOE Patents [OSTI]

    Gannon, J.C.; Payne, J.J.

    1996-09-03

    A portable, high speed, computer-based data logging system for field testing systems or components located some distance apart employs a plurality of spaced mass spectrometers and is particularly adapted for monitoring the vacuum integrity of a long string of a superconducting magnets such as used in high energy particle accelerators. The system provides precise tracking of a gas such as helium through the magnet string when the helium is released into the vacuum by monitoring the spaced mass spectrometers allowing for control, display and storage of various parameters involved with leak detection and localization. A system user can observe the flow of helium through the magnet string on a real-time basis hour the exact moment of opening of the helium input valve. Graph reading can be normalized to compensate for magnet sections that deplete vacuum faster than other sections between testing to permit repetitive testing of vacuum integrity in reduced time. 18 figs.

  13. Leak checker data logging system

    DOE Patents [OSTI]

    Gannon, Jeffrey C. (Arlington, TX); Payne, John J. (Waterman, IL)

    1996-01-01

    A portable, high speed, computer-based data logging system for field testing systems or components located some distance apart employs a plurality of spaced mass spectrometers and is particularly adapted for monitoring the vacuum integrity of a long string of a superconducting magnets such as used in high energy particle accelerators. The system provides precise tracking of a gas such as helium through the magnet string when the helium is released into the vacuum by monitoring the spaced mass spectrometers allowing for control, display and storage of various parameters involved with leak detection and localization. A system user can observe the flow of helium through the magnet string on a real-time basis hour the exact moment of opening of the helium input valve. Graph reading can be normalized to compensate for magnet sections that deplete vacuum faster than other sections between testing to permit repetitive testing of vacuum integrity in reduced time.

  14. Argonne researchers make new study of special type of chemical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    make new study of special type of chemical bond By Jared Sagoff * September 29, 2014 Tweet EmailPrint Covalent bonds, one of the most common classes of chemical interactions, occur...

  15. Bonding thermoplastic polymers

    DOE Patents [OSTI]

    Wallow, Thomas I. (Fremont, CA); Hunter, Marion C. (Livermore, CA); Krafcik, Karen Lee (Livermore, CA); Morales, Alfredo M. (Livermore, CA); Simmons, Blake A. (San Francisco, CA); Domeier, Linda A. (Danville, CA)

    2008-06-24

    We demonstrate a new method for joining patterned thermoplastic parts into layered structures. The method takes advantage of case-II permeant diffusion to generate dimensionally controlled, activated bonding layers at the surfaces being joined. It is capable of producing bonds characterized by cohesive failure while preserving the fidelity of patterned features in the bonding surfaces. This approach is uniquely suited to production of microfluidic multilayer structures, as it allows the bond-forming interface between plastic parts to be precisely manipulated at micrometer length scales. The bond enhancing procedure is easily integrated in standard process flows and requires no specialized equipment.

  16. Log-Sobolev inequalities for subelliptic operators

    E-Print Network [OSTI]

    Fabrice Baudoin

    2012-02-07

    Log-Sobolev inequalities for subelliptic operators. Fabrice Baudoin. Purdue University. Georgia Tech Probability Seminar. Based on a joint work with M.

  17. Storing Renewable Energy in Chemical Bonds

    ScienceCinema (OSTI)

    Helm, Monte; Bullock, Morris

    2014-06-13

    With nearly 7 billion people, the world's population is demanding more electricity every year. Improved technologies are bringing wind and solar power to our electrical grid. However, wind turbines and solar panels only work when the wind blows or the sun shines. PNNL scientists discuss catalysis approaches for storing and releasing energy on demand.

  18. Storing Renewable Energy in Chemical Bonds

    SciTech Connect (OSTI)

    Helm, Monte; Bullock, Morris

    2013-03-27

    With nearly 7 billion people, the world's population is demanding more electricity every year. Improved technologies are bringing wind and solar power to our electrical grid. However, wind turbines and solar panels only work when the wind blows or the sun shines. PNNL scientists discuss catalysis approaches for storing and releasing energy on demand.

  19. Shippers in Indonesia fight decree on illegal logging Shippers in Indonesia fight decree on illegal logging

    E-Print Network [OSTI]

    Shippers in Indonesia fight decree on illegal logging Shippers in Indonesia fight decree on illegal Organization (ITTO), shippers in Indonesia are threatening to stop transporting logs if the government insists harvesting affects 700,000-850,000 hectares of forest per year in Indonesia, but widespread illegal logging

  20. Illegal timber logging in Vietnam: Who profits from forest privatization connected with a logging ban?

    E-Print Network [OSTI]

    1 Illegal timber logging in Vietnam: Who profits from forest privatization connected with a logging the distribution of income from illegal timber logging in northern Vietnam. The Vietnamese government implemented actors' control over markets and power derived from state positions. I. Introduction Vietnam's forest

  1. Biomass from Logging Residue and Mill Residue

    E-Print Network [OSTI]

    Biomass from Logging Residue and Mill Residue in East Texas, 2008 by Curtis L. VanderSchaaf, Forest Resource Analyst October 2009 #12;N Introduction The abundance of woody biomass from East Texas forests. This report represents the most current data on the availability of woody biomass in the form of logging

  2. Chemical Logging At Dixie Valley Geothermal Area (Los Alamos National

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR JumpMaine: EnergyEnergy Information Geothermometers

  3. Chemical Logging At North Brawley Geothermal Area (Department, 1979) | Open

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR JumpMaine: EnergyEnergy Information GeothermometersEnergy

  4. Chemical Logging At Raft River Geothermal Area (1979) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR JumpMaine: EnergyEnergy Information

  5. Chemical logging- a geothermal technique | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County,Camilla,Thermal GradientChateau Tebeau LLC JumpSystem at

  6. Coal-log pipeline system development

    SciTech Connect (OSTI)

    Liu, H.

    1991-12-01

    Project tasks include: (1) Perform the necessary testing and development to demonstrate that the amount of binder in coal logs can be reduced to 8% or lower to produce logs with adequate strength to eliminate breakage during pipeline transportation, under conditions experienced in long distance pipeline systems. Prior to conducting any testing and demonstration, grantee shall perform an information search and make full determination of all previous attempts to extrude or briquette coal, upon which the testing and demonstration shall be based. (2) Perform the necessary development to demonstrate a small model of the most promising injection system for coal-logs, and tests the logs produced. (3) Conduct economic analysis of coal-log pipeline, based upon the work to date. Refine and complete the economic model. (VC)

  7. Bonded semiconductor substrate

    DOE Patents [OSTI]

    Atwater, Jr.; Harry A. (South Pasadena, CA), Zahler; James M. (Pasadena, CA)

    2010-07-13

    Ge/Si and other nonsilicon film heterostructures are formed by hydrogen-induced exfoliation of the Ge film which is wafer bonded to a cheaper substrate, such as Si. A thin, single-crystal layer of Ge is transferred to Si substrate. The bond at the interface of the Ge/Si heterostructures is covalent to ensure good thermal contact, mechanical strength, and to enable the formation of an ohmic contact between the Si substrate and Ge layers. To accomplish this type of bond, hydrophobic wafer bonding is used, because as the invention demonstrates the hydrogen-surface-terminating species that facilitate van der Waals bonding evolves at temperatures above 600.degree. C. into covalent bonding in hydrophobically bound Ge/Si layer transferred systems.

  8. Effect of hydrogen bond on coal extraction by in-situ vacuum FTIR

    SciTech Connect (OSTI)

    Li, J.; Feng, J.; Li, W.Y.; Chang, H.Z.; Xie, K.C. [Taiyuan University of Technol, Taiyuan (China)

    2009-07-01

    Coal chemical formation environment might result in different properties of hydrogen bonds in coal structure. The thermo stability, amount and types of hydrogen bond in six typical Chinese coal macerals were investigated by in situ vacuum Fourier transform infrared spectroscopy (FTIR). It was found that three types of hydrogen bond were involved in coal structure, which were OH-N, OH self associated, and OH tetrapolymer hydrogen bond. There was no correlation between the amount of three types of hydrogen bonds and extraction yield. The thermo stability of hydrogen bond in inertinite was stronger than that of vitrinite, especially the thermo stability of hydrogen bond in Pingshuo inertinite.

  9. Spectroscopic investigations of hydrogen bond dynamics in liquid water

    E-Print Network [OSTI]

    Fecko, Christopher J., 1975-

    2004-01-01

    Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

  10. Synthesis, structure and chemical bonding of CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2) and SrCo{sub 2}Si{sub 2}

    SciTech Connect (OSTI)

    Hlukhyy, Viktor Hoffmann, Andrea V.; Fässler, Thomas F.

    2013-07-15

    The finding of superconductivity in Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2} put the attention on the investigation of compounds that crystallize with ThCr{sub 2}Si{sub 2} structure type such as AT{sub 2}X{sub 2} (A=alkali/alkaline earth/rare earth element; T=transition metal and X=element of the 13–15th group). In this context the silicides CaFe{sub 2}Si{sub 2}, CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}, CaRh{sub 2}Si{sub 2} and SrCo{sub 2}Si{sub 2} have been synthesized by reaction of the elements under an argon atmosphere. Single crystals were obtained by special heat treatment in welded niobium/tantalum ampoules. The compounds were investigated by means of powder and single crystal X-ray diffraction. All compounds crystallize in the ThCr{sub 2}Si{sub 2}-type structure with space group I4/mmm (No. 139): a=3.939(1) Ĺ, c=10.185(1) Ĺ, R{sub 1}=0.045, 85 F{sup 2} values, 8 variable parameters for CaFe{sub 2}Si{sub 2}; a=4.0590(2) Ĺ, c=9.9390(8) Ĺ, R{sub 1}=0.030, 90 F{sup 2} values, 10 variable parameters for CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}; a=4.0695(1) Ĺ, c=9.9841(3) Ĺ, R{sub 1}=0.031, 114 F{sup 2} values, 9 variable parameters for CaRh{sub 2}Si{sub 2}; and a=3.974(1) Ĺ, c=10.395(1) Ĺ, R{sub 1}=0.036, 95 F{sup 2} values, 8 variable parameters for SrCo{sub 2}Si{sub 2}. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} 2D-layers in the ab-plane whereas in CaFe{sub 2?x}Rh{sub x}Si{sub 2} the [T{sub 2}Si{sub 2}] layers (T=Fe and Rh) are interconnected along the c-axis via Si3Si bonds resulting in a three-dimentional (3D) [T{sub 2}Si{sub 2}]{sup 2?} polyanions and therefore belong to the so-called collapsed form of the ThCr{sub 2}Si{sub 2}-type structure. The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 iron–pnictide superconductors AeFe{sub 2}As{sub 2} (Ae=alkaline earth elements), whereas CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of CaFe{sub 2}As{sub 2}. The crystal chemistry and chemical bonding in the title compounds are discussed in terms of LMTO band structure calculations and a topological analysis using the Electron Localization Function (ELF). - Graphical abstract: The SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x==0, 1.32, and 2) crystallize in the ThCr{sub 2}Si{sub 2}-type. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} layers in the ab-plane, whereas the [T{sub 2}Si{sub 2}] layers in CaFe{sub 2?x}Rh{sub x}Si{sub 2} are interconnected along the c-axis via Si3Si bonds resulting in a [T{sub 2}Si{sub 2}]{sup 2?} network. - Highlights: • Synthesis and structure of ternary silicides SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2). • The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 iron–pnictide superconductors AeFe{sub 2}As{sub 2}. • CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of superconductor CaFe{sub 2}As{sub 2}. • The title compounds demonstrate the tunable Si3Si distances.

  11. Formation mechanical properties and the sonic log

    SciTech Connect (OSTI)

    Elphick, R.Y.

    1988-11-01

    A program is presented that calculates the mechanical properties of reservoir rocks from sonic logs. The program was written in Microsoft BASIC and the source code for MS-DOS, Apple Macintosh, and Amiga personal computers is given.

  12. JourneyLog 64 5 Vehicle tracking

    E-Print Network [OSTI]

    Haddadi, Hamed

    JourneyLog 64 5 Vehicle tracking blinkx 8 Five years on Tomas Pfister 11 Graduate story Raspberry Pi 12 Exciting and engaging children to learn about computing Ring news 2 Note from the Editor

  13. Energy Citations Database (ECD) - Alerts Log On

    Office of Scientific and Technical Information (OSTI)

    ECD Alerts Log On Alerts provide users with e-mail notification of updates to the ECD in specific areas of interest. If you wish to receive an Alert and are not registered, please...

  14. Logging-while-coring method and apparatus

    DOE Patents [OSTI]

    Goldberg, David S.; Myers, Gregory J.

    2007-01-30

    A method and apparatus for downhole coring while receiving logging-while-drilling tool data. The apparatus includes core collar and a retrievable core barrel. The retrievable core barrel receives core from a borehole which is sent to the surface for analysis via wireline and latching tool The core collar includes logging-while-drilling tools for the simultaneous measurement of formation properties during the core excavation process. Examples of logging-while-drilling tools include nuclear sensors, resistivity sensors, gamma ray sensors, and bit resistivity sensors. The disclosed method allows for precise core-log depth calibration and core orientation within a single borehole, and without at pipe trip, providing both time saving and unique scientific advantages.

  15. Logging-while-coring method and apparatus

    DOE Patents [OSTI]

    Goldberg, David S. (New York, NY); Myers, Gregory J. (Cornwall, NY)

    2007-11-13

    A method and apparatus for downhole coring while receiving logging-while-drilling tool data. The apparatus includes core collar and a retrievable core barrel. The retrievable core barrel receives core from a borehole which is sent to the surface for analysis via wireline and latching tool The core collar includes logging-while-drilling tools for the simultaneous measurement of formation properties during the core excavation process. Examples of logging-while-drilling tools include nuclear sensors, resistivity sensors, gamma ray sensors, and bit resistivity sensors. The disclosed method allows for precise core-log depth calibration and core orientation within a single borehole, and without at pipe trip, providing both time saving and unique scientific advantages.

  16. Logs Wood Chips Straw Corn Switchgrass

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clean energy can come from the sun. The energy in wind can make electricity. Bioenergy comes from plants we can turn into fuel. Logs Wood Chips Straw Corn Switchgrass We can use...

  17. Energy Efficiency in Log Homes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency in Log Homes Energy Efficiency in Log Homes April 13, 2012 - 11:29am Addthis Consider energy efficiency when designing or purchasing a log home. | Photo courtesy...

  18. A chemical approach to understanding oxide surfaces James A. Enterkin a,b,c

    E-Print Network [OSTI]

    Marks, Laurence D.

    A chemical approach to understanding oxide surfaces James A. Enterkin a,b,c , Andres E. Becerra-Toledo d , Kenneth R. Poeppelmeier a,b,c , Laurence D. Marks c,d, a Chemical Sciences and Engineering Keywords: Bond valence sum Coordination Chemical bond Surface structure Metal oxide Chemical bonding has

  19. Density Log At Valles Caldera - Redondo Geothermal Area (Wilt...

    Open Energy Info (EERE)

    Density Log At Valles Caldera - Redondo Geothermal Area (Wilt & Haar, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Density Log At Valles...

  20. Well Log Data At Valles Caldera - Redondo Geothermal Area (Shevenell...

    Open Energy Info (EERE)

    Well Log Data At Valles Caldera - Redondo Geothermal Area (Shevenell, Et Al., 1988) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Well Log Data...

  1. Green Energy Resources Inc formerly New York International Log...

    Open Energy Info (EERE)

    Green Energy Resources Inc formerly New York International Log Lumber Company Jump to: navigation, search Name: Green Energy Resources Inc (formerly New York International Log &...

  2. Well Log Data At Blue Mountain Geothermal Area (Fairbank & Niggemann...

    Open Energy Info (EERE)

    Well Log Data At Blue Mountain Geothermal Area (Fairbank & Niggemann, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Well Log Data At Blue...

  3. Low Temperature Material Bonding Technique

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2000-10-10

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  4. Low temperature material bonding technique

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2002-02-12

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  5. Qualified Energy Conservation Bonds

    Broader source: Energy.gov [DOE]

    Provides an in-depth description of qualified energy conservation bonds, including process and mechanics, case studies, utilization trends, barriers, and regulatory and legal issues. Author: Energy Programs Consortium

  6. Bonding aerogels with polyurethanes

    SciTech Connect (OSTI)

    Matthews, F.M.; Hoffman, D.M.

    1989-11-01

    Aerogels, porous silica glasses with ultra-fine cell size (30nm), are made by a solution gelation (sol-gel) process. The resulting gel is critical point dried to densities from 0.15--0.60 g/cc. This material is machinable, homogeneous, transparent, coatable and bondable. To bond aerogel an adhesive should have long cure time, no attack on the aerogel structure, and high strength. Several epoxies and urethanes were examined to determine if they satisfied these conditions. Bond strengths above 13 psi were found with double bubble and DP-110 epoxies and XI-208/ODA-1000 and Castall U-2630 urethanes. Hardman Kalex Tough Stuff'' A-85 hardness urethane gave 18 psi bond strength. Hardman A-85, Tuff-Stuff'' was selected for further evaluation because it produced bond strengths comparable to the adherend cohesive strength. 5 refs., 2 figs.

  7. Epoxy bond and stop etch fabrication method

    DOE Patents [OSTI]

    Simmons, Jerry A. (Sandia Park, NM); Weckwerth, Mark V. (Pleasanton, CA); Baca, Wes E. (Albuquerque, NM)

    2000-01-01

    A class of epoxy bond and stop etch (EBASE) microelectronic fabrication techniques is disclosed. The essence of such techniques is to grow circuit components on top of a stop etch layer grown on a first substrate. The first substrate and a host substrate are then bonded together so that the circuit components are attached to the host substrate by the bonding agent. The first substrate is then removed, e.g., by a chemical or physical etching process to which the stop etch layer is resistant. EBASE fabrication methods allow access to regions of a device structure which are usually blocked by the presence of a substrate, and are of particular utility in the fabrication of ultrafast electronic and optoelectronic devices and circuits.

  8. Ultrafast Laser Spectroscopyof Chemical Reactions

    E-Print Network [OSTI]

    Zewail, Ahmed

    Ultrafast Laser Spectroscopyof Chemical Reactions - Joseph L. Kneeand AhmedH. Zewail California of chemical physics is to understand how chemi- cal reactions complete their journey from reactants to prod at the molecular level. The making of new bonds (and the breaking of old ones) in elementary chemical reactions

  9. Combating Illegal LoggingCombating Illegal Logging in Russia:in Russia

    E-Print Network [OSTI]

    the creation of special body for licensing export operations · changes in the Federal Crime Code #12;RUSSIACombating Illegal LoggingCombating Illegal Logging in Russia:in Russia: Case study ofCase study of PrimorskyPrimorsky RegionRegion AlexeyAlexey MorozovMorozov Greenpeace RussiaGreenpeace Russia http://www

  10. Combating Illegal LoggingCombating Illegal Logging in Russia:in Russia

    E-Print Network [OSTI]

    of special body for licensing export operations · changes in the Federal Crime Code #12;RUSSIA ...A barbarianCombating Illegal LoggingCombating Illegal Logging in Russia:in Russia: Case study ofCase study of PrimorskyPrimorsky RegionRegion AlexeyAlexey MorozovMorozov Greenpeace RussiaGreenpeace Russia #12;Primorsky

  11. The Impact of the Russian Log Export Tariff on the Global Market for Logs and Lumber

    E-Print Network [OSTI]

    The Impact of the Russian Log Export Tariff on the Global Market for Logs and Lumber CINTRAFOR News's Notes ....2 CINTRAFOR celebrates 25th aniversary Winter 2009 Russia contains the largest area of natural in Russia, estimated at 808,790,000 hectares, represents 20.5% of total global forest area and almost half

  12. Permeability extraction: A sonic log inversion

    SciTech Connect (OSTI)

    Akbar, N.; Kim, J.J. [Saudi Aramco, Dhahran (Saudi Arabia)

    1994-12-31

    In this paper the authors provide the missing important link between permeability and acoustic velocities by generating a permeability-dependent synthetic sonic log in a carbonate reservoir. The computations are based on Akbar`s theory that relates wave velocity to frequency, rock properties (e.g., lithology, permeability, and porosity), and fluid saturation and properties (viscosity, density, and compressibility). An inverted analytical expression of the theory is used to extract permeability from sonic velocity. The synthetic sonic and the computed permeability are compared with the observed sonic log and with plug permeability, respectively. The results demonstrate, as predicted by theory, that permeability can be related directly to acoustic velocities.

  13. Logging of subterranean wells using coiled tubing

    SciTech Connect (OSTI)

    Pilla, J.

    1991-01-15

    This patent describes an apparatus for production logging of a well utilizing artificial lift in a wellbore. It comprises: coiled tubing extending into the wellbore having wireline electrical cable passing through a central bore thereof and having a remote end within the wellbore which end is connected to gas injector means. The wireline cable passing through the gas injector means to a flexible electrically conductive support spacer having an end portion remote from the gas injector means and logging means connected to the end portion of the support spacer.

  14. Graphene Electronic Device Based Biosensors and Chemical Sensors

    E-Print Network [OSTI]

    Jiang, Shan

    2014-01-01

    116] Perkins, F.K. et al. Chemical Vapor Sensing with Monoof Monolayer MoS 2 via Chemical Doping, Nano Letters 13,of axial ligands on the surface chemical bonds of adsorbed

  15. Qualifying Energy Conservation Bonds 

    E-Print Network [OSTI]

    Briggs, J.

    2013-01-01

    Bonds (QECB’s) CATEE Conference December 18, 2013 ESL-KT-13-12-39 CATEE 2013: Clean Air Through Energy Efficiency Conference, San Antonio, Texas Dec. 16-18 • Originally authorized by the Energy Improvement & Extension Act of 2008 • American Recovery... ) of the interest cost associated with the transaction • Typical effective interest rates anywhere from 0%-2% depending on credit strength • Bond issuance or private placement is acceptable 2 What are QECB’s ESL-KT-13-12-39 CATEE 2013: Clean Air Through Energy...

  16. Photochemical tissue bonding

    DOE Patents [OSTI]

    Redmond, Robert W. (Brookline, MA); Kochevar, Irene E. (Charlestown, MA)

    2012-01-10

    Photochemical tissue bonding methods include the application of a photosensitizer to a tissue and/or tissue graft, followed by irradiation with electromagnetic energy to produce a tissue seal. The methods are useful for tissue adhesion, such as in wound closure, tissue grafting, skin grafting, musculoskeletal tissue repair, ligament or tendon repair and corneal repair.

  17. INSPIRE and SPIRES Log File Analysis

    SciTech Connect (OSTI)

    Adams, Cole; /Wheaton Coll. /SLAC

    2012-08-31

    SPIRES, an aging high-energy physics publication data base, is in the process of being replaced by INSPIRE. In order to ease the transition from SPIRES to INSPIRE it is important to understand user behavior and the drivers for adoption. The goal of this project was to address some questions in regards to the presumed two-thirds of the users still using SPIRES. These questions are answered through analysis of the log files from both websites. A series of scripts were developed to collect and interpret the data contained in the log files. The common search patterns and usage comparisons are made between INSPIRE and SPIRES, and a method for detecting user frustration is presented. The analysis reveals a more even split than originally thought as well as the expected trend of user transition to INSPIRE.

  18. Chiral Gravity, Log Gravity and Extremal CFT

    E-Print Network [OSTI]

    Alexander Maloney; Wei Song; Andrew Strominger

    2009-03-26

    We show that the linearization of all exact solutions of classical chiral gravity around the AdS3 vacuum have positive energy. Non-chiral and negative-energy solutions of the linearized equations are infrared divergent at second order, and so are removed from the spectrum. In other words, chirality is confined and the equations of motion have linearization instabilities. We prove that the only stationary, axially symmetric solutions of chiral gravity are BTZ black holes, which have positive energy. It is further shown that classical log gravity-- the theory with logarithmically relaxed boundary conditions --has finite asymptotic symmetry generators but is not chiral and hence may be dual at the quantum level to a logarithmic CFT. Moreover we show that log gravity contains chiral gravity within it as a decoupled charge superselection sector. We normally evaluate the Euclidean sum over geometries of chiral gravity and show that it gives precisely the holomorphic extremal CFT partition function. The modular invariance and integrality of the expansion coefficients of this partition function are consistent with the existence of an exact quantum theory of chiral gravity. We argue that the problem of quantizing chiral gravity is the holographic dual of the problem of constructing an extremal CFT, while quantizing log gravity is dual to the problem of constructing a logarithmic extremal CFT.

  19. Acoustic Waveform Logging - Advances In Theory And Application

    E-Print Network [OSTI]

    Cheng, C. H.

    Full-waveform acoustic logging has made significant advances in both theory and application in recent years, and these advances have greatly increased the capability of log analysts to measure the physical properties of ...

  20. Pauling bond strength, bond length and electron density distribution

    SciTech Connect (OSTI)

    Gibbs, Gerald V.; Ross, Nancy L.; Cox, David F.; Rosso, Kevin M.; Iversen, Bo B.; Spackman, M. A.

    2014-01-18

    A power law regression equation, = 1.46(/r)-0.19, connecting the average experimental bond lengths, , with the average accumulation of the electron density at the bond critical point, , between bonded metal M and oxygen atoms, determined at ambient conditions for oxide crystals, where r is the row number of the M atom, is similar to the regression equation R(M-O) = 1.39(?(rc)/r)-0.21 determined for three perovskite crystals for pressures as high as 80 GPa. The two equations are also comparable with those, = 1.43(/r)-0.21, determined for a large number of oxide crystals at ambient conditions and = 1.39(/r)-0.22, determined for geometry optimized hydroxyacid molecules, that connect the bond lengths to the average Pauling electrostatic bond strength, , for the M-O bonded interactions. On the basis of the correspondence between the two sets of equations connecting ?(rc) and the Pauling bond strength s with bond length, it appears that Pauling’s simple definition of bond strength closely mimics the accumulation of the electron density between bonded pairs of atoms. The similarity of the expressions for the crystals and molecules is compelling evidence that the M-O bonded interactions for the crystals and molecules 2 containing the same bonded interactions are comparable. Similar expressions, connecting bond lengths and bond strength, have also been found to hold for fluoride, nitride and sulfide molecules and crystals. The Brown-Shannon bond valence, ?, power law expression ? = [R1/(R(M-O)]N that has found wide use in crystal chemistry, is shown to be connected to a more universal expression determined for oxides and the perovskites, = r[(1.41)/]4.76, demonstrating that the bond valence for a bonded interaction is likewise closely connected to the accumulation of the electron density between the bonded atoms. Unlike the Brown-Shannon expression, it is universal in that it holds for the M-O bonded interactions for a relatively wide range of M atoms of the periodic table. The power law equation determined for the oxide crystals at ambient conditions is similar to the power law expression = r[1.46/]5.26 determined for the perovskites at pressures as high as 80 GPa, indicating that the intrinsic connection between R(M-O) and ?(rc) that holds at ambient conditions also holds, to a first approximation, at high pressures.

  1. An Oblivious Transfer Protocol with Log-Squared Communication

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    An Oblivious Transfer Protocol with Log-Squared Communication Helger Lipmaa 1 Cybernetica AS, Lai 6-computation and communication (k · log2 n + · log n), where k is a possibly non-constant security parameter. The new proto- col communication and is private in the standard complexity-theoretic model. Keywords. Computationally

  2. An Oblivious Transfer Protocol with LogSquared Communication

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    An Oblivious Transfer Protocol with Log­Squared Communication Helger Lipmaa 1 Cybernetica AS, Lai 6­computation and communication #(k · log 2 n + # · log n), where k is a possibly non­constant security parameter. The new proto the same asymptotic communication and is private in the standard complexity­theoretic model. Keywords

  3. Incorporating Seasonality into Search Suggestions Derived from Intranet Query Logs

    E-Print Network [OSTI]

    Kruschwitz, Udo

    Incorporating Seasonality into Search Suggestions Derived from Intranet Query Logs Stephen Dignum performed on query logs collected for major Web search engines, query log analysis to enhance search search engine can be enhanced by adapting the search system to real users' search behaviour through

  4. Test results of a corrosion logging technique using electromagnetic thickness and pipe analysis logging tools

    SciTech Connect (OSTI)

    Iliyan, I.S.; Brown, G.A.; Cotton, W.J. Jr.

    1983-04-01

    Recent innovations in subsurface corrosion practices of the Arabian American Oil Co. (ARAMCO) have reduced logging and workover costs substantially and have permitted the detection of corrosion in the outer string of two concentric casing strings. At the request of ARAMCO, Schlumberger conducted test under both simulated and field conditions. Results showed that the data required to evaluate casing corrosion in a 7-in.X9 5/8-in. completion can be obtained during a single logging run using a 21.6-in. coil spacing electromagnetic thickness tool (ETT-A /SUP TM/ ) sonde (as opposed to two runs with 17.6-in. and 21.6-in. sondes previously used). In addition, corrosion of the outer string of 9 5/8-in. or 13 3/8-in. casing can be detected by using the results of the ETT-A logs and pipe-analysis tool (PAT) logs or caliper logs. To date, the application of this technique has been very successful in ARAMCO's operations.

  5. The Borneo Project : Indonesia Fails to Stop Illegal Logging, Report Says Indonesia Fails to Stop Illegal Logging, Report Says

    E-Print Network [OSTI]

    The Borneo Project : Indonesia Fails to Stop Illegal Logging, Report Says Indonesia Fails to Stop Illegal Logging, Report Says by Irwan Firdaus, The Associated Press January 15th, 2003 JAKARTA, Indonesia -- Corruption in Indonesia's police and military has contributed to a surge in illegal logging that has

  6. Spontaneous Potential Well Log | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing CapacityVectren) Jump to:Spill Prevention andWell Log Jump to: navigation,

  7. Logging in to Cori P1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse BergkampCenter (LMI-EFRC)Lodging Lodging Meeting Hotel -Logging in

  8. Low temperature reactive bonding

    DOE Patents [OSTI]

    Makowiecki, D.M.; Bionta, R.M.

    1995-01-17

    The joining technique is disclosed that requires no external heat source and generates very little heat during joining. It involves the reaction of thin multilayered films deposited on faying surfaces to create a stable compound that functions as an intermediate or braze material in order to create a high strength bond. While high temperatures are reached in the reaction of the multilayer film, very little heat is generated because the films are very thin. It is essentially a room temperature joining process. 5 figures.

  9. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.WeekProducts >TransportationEHSSTrending: Metal Oxo Bonds

  10. Dual excitation acoustic paramagnetic logging tool

    DOE Patents [OSTI]

    Vail, W.B. III.

    1989-02-14

    New methods and apparatus are disclosed which allow measurement of the presence of oil and water in geological formations using a new physical effect called the Acoustic Paramagnetic Logging Effect (APLE). The presence of petroleum in formation causes a slight increase in the earth's magnetic field in the vicinity of the reservoir. This is the phenomena of paramagnetism. Application of an acoustic source to a geological formation at the Larmor frequency of the nucleons present causes the paramagnetism of the formation to disappear. This results in a decrease in the earth's magnetic field in the vicinity of the oil bearing formation. Repetitively frequency sweeping the acoustic source through the Larmor frequency of the nucleons present (approx. 2 kHz) causes an amplitude modulation of the earth's magnetic field which is a consequence of the APLE. The amplitude modulation of the earth's magnetic field is measured with an induction coil gradiometer and provides a direct measure of the amount of oil and water in the excitation zone of the formation. The phase of the signal is used to infer the longitudinal relaxation times of the fluids present, which results in the ability in general to separate oil and water and to measure the viscosity of the oil present. Such measurements may be performed in open boreholes and in cased well bores. The Dual Excitation Acoustic Paramagnetic Logging Tool employing two acoustic sources is also described. 6 figs.

  11. Dual excitation acoustic paramagnetic logging tool

    DOE Patents [OSTI]

    Vail, III, William B. (Bothell, WA)

    1989-01-01

    New methods and apparatus are disclosed which allow measurement of the presence of oil and water in gelogical formations using a new physical effect called the Acoustic Paramagnetic Logging Effect (APLE). The presence of petroleum in formation causes a slight increase in the earth's magnetic field in the vicinity of the reservoir. This is the phenomena of paramagnetism. Application of an acoustic source to a geological formation at the Larmor frequency of the nucleous present causes the paramagnetism of the formation to disappear. This results in a decrease in the earth's magnetic field in the vicinity of the oil bearing formation. Repetitively frequency sweeping the acoustic source through the Larmor frequency of the nucleons present (approx. 2 kHz) causes an amplitude modulation of the earth's magnetic field which is a consequence of the APLE. The amplitude modulation of the earth's magnetic field is measured with an induction coil gradiometer and provides a direct measure of the amount of oil and water in the excitation zone of the formation. The phase of the signal is used to infer the longitudinal relaxation times of the fluids present, which results in the ability in general to separate oil and water and to measure the viscosity of the oil present. Such measurements may be preformed in open boreholes and in cased well bores. The Dual Excitation Acoustic Paramagnetic Logging Tool employing two acoustic sources is also described.

  12. Better Bonded Ethernet Load Balancing

    SciTech Connect (OSTI)

    Gabler, Jason

    2006-09-29

    When a High Performance Storage System's mover shuttles large amounts of data to storage over a single Ethernet device that single channel can rapidly become saturated. Using Linux Ethernet channel bonding to address this and similar situations was not, until now, a viable solution. The various modes in which channel bonding could be configured always offered some benefit but only under strict conditions or at a system resource cost that was greater than the benefit gained by using channel bonding. Newer bonding modes designed by various networking hardware companies, helpful in such networking scenarios, were already present in their own switches. However, Linux-based systems were unable to take advantage of those new modes as they had not yet been implemented in the Linux kernel bonding driver. So, except for basic fault tolerance, Linux channel bonding could not positively combine separate Ethernet devices to provide the necessary bandwidth.

  13. Actuated Transitory Metal-Ligand Bond As Tunable Electromechanical Switch

    E-Print Network [OSTI]

    Ortega, Enrique

    a copper atom and coordinating organic molecules adsorbed on a metal surface acts as variable frequency of STM is the on-demand forma- tion and breaking of chemical bonds with atomic precision. Furthermore-vinyl)] benzoic acid (hereafter referred to as PVBA) with copper adatoms on the Cu (111) surface.26

  14. Modeling the metal-semiconductor interaction: Analytical bond-order potential for platinum-carbon

    E-Print Network [OSTI]

    Nordlund, Kai

    Modeling the metal-semiconductor interaction: Analytical bond-order potential for platinum for this potential makes use of the fact that chemical bonding in both covalent systems and d-transition metals can for describing the C-C/Pt-Pt/Pt-C interactions. It resembles, in the case of the pure metal interaction

  15. 2003 ~OE2 CHINESE JOURNAL OF CHEMICAL PHYSICS

    E-Print Network [OSTI]

    Liu, Shilin

    16 ˇˇ 1 2003 ~OE2 ´ »fl§§­¤ CHINESE JOURNAL OF CHEMICAL PHYSICS Vol. 16 ,No. 1 Feb. 2003 100327713 of Bond Selective Chemistry , Chinese Academy of Sciences , Department of Chemical Physics , University

  16. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2001-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  17. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2000-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  18. Bond selective chemistry beyond the adiabatic approximation

    SciTech Connect (OSTI)

    Butler, L.J. [Univ. of Chicago, IL (United States)

    1993-12-01

    One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

  19. Energy Efficiency in Log Homes | Department of Energy

    Office of Environmental Management (EM)

    or purchasing a manufactured log home, you should consider several factors related to energy efficiency. The R-Value of Wood A material's thermal resistance or resistance to...

  20. Log-normal distribution for correlators in lattice QCD?

    E-Print Network [OSTI]

    Thomas DeGrand

    2012-04-20

    Many hadronic correlators used in spectroscopy calculations in lattice QCD simulations appear to show a log-normal distribution at intermediate time separations.

  1. Geophysical logging case history of the Raft River geothermal...

    Open Energy Info (EERE)

    5490655 Citation Applegate, J. K.; Moens, T. A. . 411980. Geophysical logging case history of the Raft River geothermal system, Idaho. () : DOE Information Bridge. Related...

  2. Selecting The Optimal Logging Suite For Geothermal Reservoir...

    Open Energy Info (EERE)

    tensile wall fractures, and were adequate to detect stratigraphic features. Density, photo-electric factor (PEF), neutron, and gamma ray (GR) logs provided sufficient...

  3. COMPARISON OF ACOUSTIC AND ELECTRICAL IMAGE LOGS FROM THE COSO...

    Open Energy Info (EERE)

    COMPARISON OF ACOUSTIC AND ELECTRICAL IMAGE LOGS FROM THE COSO GEOTHERMAL FIELD, CA Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings:...

  4. Method for determining formation quality factor from well log...

    Office of Scientific and Technical Information (OSTI)

    determining formation quality factor from well log data and its application to seismic reservoir characterization Citation Details In-Document Search Title: Method for...

  5. Quantum Confinement in Hydrogen Bond

    E-Print Network [OSTI]

    Carlos da Silva dos Santos; Elso Drigo Filho; Regina Maria Ricotta

    2015-02-09

    In this work, the quantum confinement effect is proposed as the cause of the displacement of the vibrational spectrum of molecular groups that involve hydrogen bonds. In this approach the hydrogen bond imposes a space barrier to hydrogen and constrains its oscillatory motion. We studied the vibrational transitions through the Morse potential, for the NH and OH molecular groups inside macromolecules in situation of confinement (when hydrogen bonding is formed) and non-confinement (when there is no hydrogen bonding). The energies were obtained through the variational method with the trial wave functions obtained from Supersymmetric Quantum Mechanics (SQM) formalism. The results indicate that it is possible to distinguish the emission peaks related to the existence of the hydrogen bonds. These analytical results were satisfactorily compared with experimental results obtained from infrared spectroscopy.

  6. Physical Nature of Hydrogen Bond

    E-Print Network [OSTI]

    Zhyganiuk, I V

    2015-01-01

    The physical nature and the correct definition of hydrogen bond (H-bond) are considered.\\,\\,The influence of H-bonds on the thermodynamic, kinetic, and spectroscopic properties of water is analyzed.\\,\\,The conventional model of H-bonds as sharply directed and saturated bridges between water molecules is incompatible with the behavior of the specific volume, evaporation heat, and self-diffusion and kinematic shear viscosity coefficients of water. On the other hand, it is shown that the variation of the dipole moment of a water molecule and the frequency shift of valence vibrations of a hydroxyl group can be totally explained in the framework of the electrostatic model of H-bond.\\,\\,At the same time, the temperature dependences of the heat capacity of water in the liquid and vapor states clearly testify to the existence of weak H-bonds.\\,\\,The analysis of a water dimer shows that the contribution of weak H-bonds to its ground state energy is approximately 4--5 times lower in comparison with the energy of electr...

  7. Drag reduction in coal log pipelines

    SciTech Connect (OSTI)

    Marrero, T.R.; Liu, H.

    1996-12-31

    It is well-known that solutions of dissolved long-chain macromolecules produce lower friction or drag losses than with the solvent alone. In coal log pipeline (CLP), water is the conveying medium. Synthetic polymers such as poly(ethylene oxide) have been dissolved in water and tested for their extent of drag reduction as a function of concentration and other variables. Lab-scale experimental results for CLP indicate substantial drag reduction at low concentration levels of polymer. But, the macromolecules exhibit degradation under mechanical shear stresses. The large molecules break into smaller units. This degradation effect causes a loss of drag reduction. However, high levels of drag reduction can be maintained as follows: (1) by injecting polymer into the CLP at several locations along the pipeline, (2) by injecting polymer of different particle sizes, (3) by using more robust types of polymers, or (4) by using polymer-fiber mixtures. This report presents the value of drag-reducing agents in terms of pumping power net cost savings. In addition, this report outlines the environmental impact of drag reduction polymers, and end-of-pipeline water treatment processes. For an operating CLP, hundreds of miles in length, the use of poly(ethylene oxide) as a drag reducing agent provides significant pumping power cost savings at a minimal materials cost.

  8. Saving big bucks with your log sheets

    SciTech Connect (OSTI)

    Puskar, J.R. [CEC Consultants, Inc., Cleveland, OH (United States)

    1999-07-01

    This article speaks to a common problem in a lot of industrial and institutional boilerhouses. Most boilerhouses do an excellent job at collecting information. Circular chart recorders churn out pressures, temperatures, and flows for everything from steam to natural gas to city water consumption. At most facilities, this stuff all gets chucked into a drawer or file cabinet daily. Have you ever wondered why you collect and record what you do? What were people thinking when the existing logs were set up? This article attempts to challenge the original thought process and hopes to evoke in the reader a renewed vision of what should be collected, how, and then what can be done with it. The goal of this article is not to define new and expensive data acquisition or control system projects. It is instead to show how to develop systems that only require paper, pencils, and people who are motivated and care. These people are probably already being paid to do most of this work. Experience is that if these people are treated with respect and given some simple tools they will do amazing things beyond what was thought possible. This is a low-tech humanistic approach that has a fabulous rate of return. It`s also something that can be immediately implemented.

  9. M.Sc. Thesis Forensic examination of log files

    E-Print Network [OSTI]

    to aid the investigation, so that the digital evidence can be extracted in a fast and e#cient manner of artificial neural networks to classify router logs, classification of each log entry, and development of Service, Flow Classification, Feature Extraction, Tra#c Aggregation. #12; #12; Contents 1 Introduction 1 1

  10. M.Sc. Thesis Forensic examination of log files

    E-Print Network [OSTI]

    to aid the investigation, so that the digital evidence can be extracted in a fast and efficient manner of artificial neural networks to classify router logs, classification of each log entry, and development of Service, Flow Classification, Feature Extraction, Traffic Aggregation. #12;#12;Contents 1 Introduction 1 1

  11. Efficient Discovery of Understandable Declarative Process Models from Event Logs

    E-Print Network [OSTI]

    van der Aalst, Wil

    Efficient Discovery of Understandable Declarative Process Models from Event Logs Fabrizio M. Maggi models are more suitable for less structured processes, most discovery techniques generate conventional) process discovery (learning a model from example traces in an event log), (b) confor- mance checking

  12. Mining Configurable Process Models from Collections of Event Logs

    E-Print Network [OSTI]

    van der Aalst, Wil

    towards the discovery of a configurable process model based on a collection of event logs. In this paper related work on process discovery, configurable process models and current model merging techniquesMining Configurable Process Models from Collections of Event Logs J.C.A.M. Buijs, B.F. van Dongen

  13. Preprocessing and Mining Web Log Data for Web Personalization

    E-Print Network [OSTI]

    Ruggieri, Salvatore

    Preprocessing and Mining Web Log Data for Web Personalization M. Baglioni1 , U. Ferrara2 , A. Romei/26, 56017 S. Martino Ulmiano (PI) Italy ferrara@ksolutions.it Abstract. We describe the web usage mining behaviour of a web site users. The models are inferred from the access logs of a web server by means of data

  14. Directed Planar Reachability Is in Unambiguous Log-Space

    E-Print Network [OSTI]

    Variyam, Vinodchandran N.

    4 Directed Planar Reachability Is in Unambiguous Log-Space CHRIS BOURKE, RAGHUNATH TEWARI, and N. V reachability, planar graphs, unambiguous log-space ACM Reference Format: Bourke, C., Tewari, R. Bourke, R. Tewari, and N. V. Vinodchandran, Department of Computer Science and Engineering, University

  15. Fusion bonding and alignment fixture

    DOE Patents [OSTI]

    Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

    2000-01-01

    An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all the components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

  16. Method for vacuum fusion bonding

    DOE Patents [OSTI]

    Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

    2001-01-01

    An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

  17. Method of bonding

    DOE Patents [OSTI]

    Saller, deceased, Henry A. (late of Columbus, OH); Hodge, Edwin S. (Columbus, OH); Paprocki, Stanley J. (Columbus, OH); Dayton, Russell W. (Columbus, OH)

    1987-12-01

    1. A method of making a fuel-containing structure for nuclear reactors, comprising providing an assembly comprising a plurality of fuel units; each fuel unit consisting of a core plate containing thermal-neutron-fissionable material, sheets of cladding metal on its bottom and top surfaces, said cladding sheets being of greater width and length than said core plates whereby recesses are formed at the ends and sides of said core plate, and end pieces and first side pieces of cladding metal of the same thickness as the core plate positioned in said recesses, the assembly further comprising a plurality of second side pieces of cladding metal engaging the cladding sheets so as to space the fuel units from one another, and a plurality of filler plates of an acid-dissolvable nonresilient material whose melting point is above 2000.degree. F., each filler plate being arranged between a pair of said second side pieces and the cladding plates of two adjacent fuel units, the filler plates having the same thickness as the second side pieces; the method further comprising enclosing the entire assembly in an envelope; evacuating the interior of the entire assembly through said envelope; applying inert gas under a pressure of about 10,000 psi to the outside of said envelope while at the same time heating the assembly to a temperature above the flow point of the cladding metal but below the melting point of any material of the assembly, whereby the envelope is pressed against the assembly and integral bonds are formed between plates, sheets, first side pieces, and end pieces and between the sheets and the second side pieces; slowly cooling the assembly to room temperature; removing the envelope; and dissolving the filler plates without attacking the cladding metal.

  18. Low Temperature Material Bonding Techniq Ue

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2002-08-06

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  19. Hydrogen Bond Shaping of Membrane Protein Structure

    E-Print Network [OSTI]

    Cao, Zheng

    2013-01-01

    2 1.3. HYDROGEN BOND STRENGTHAND EQUILIBRIUM HYDROGEN / DEUTERIUM FRACTIONATION4 1.4. MEASUING HYDROGEN BOND STRENGTH IN A MEMBRANE PROTEIN

  20. Sandia Energy - Diffusion Bonding Characterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bond surface is poor or only the region near this corner. Diffusion 7-8-9 "Diffusion Welding and Brazing," in Welding Handbook, 7th ed., American Welding Society, 1980, p 311-335...

  1. Quantification of Wellbore Leakage Risk Using Non-destructive Borehole Logging Techniques

    SciTech Connect (OSTI)

    Duguid, Andrew; Butsch, Robert; Cary, J.; Celia, Michael; Chugunov, Nikita; Gasda, Sarah; Hovorka, Susan; Ramakrishnan, T. S.; Stamp, Vicki; Thingelstad, Rebecca; Wang, James

    2014-08-29

    Well integrity is important at all potential CCS locations and may play a crucial role establishing leakage risk in areas where there is a high density of existing wells that could be impacted by the storage operations including depleted petroleum fields where EOR or CCS will occur. To address a need for risk quantification methods that can be directly applied to individual wells using borehole logging tools a study was conducted using data from five wells in Wyoming. The objectives of the study were: Objective 1: Develop methods to establish the baseline flow parameters (porosity and permeability or mobility) from individual measurements of the material properties and defects in a well. Objective 2: Develop a correlation between field flow-property data and cement logs that can be used to establish the flow-properties of well materials and well features using cement mapping tools. Objective 3: Establish a method that uses the flow-property model (Objective 2) to analyze the statistical uncertainties associated with individual well leakage that can provide basis for uncertainty in risk calculations. The project objectives were met through the logging of five wells in Carbon and Natrona County Wyoming to collect data that was used to estimate individual and average well flow properties and model the results using ultrasonic data collected during the logging. Three of the five wells provided data on point and average flow properties for well annuli. Data from the other two wells were used to create models of cement permeability and test whether information collected in one well could be used to characterize another well. The results of the in-situ point measurements were confirmed by the lab measurements sidewall cores collected near the same depths Objective 1 was met using the data collected through logging, testing, and sampling. The methods were developed that can establish baseline flow parameters of wells by both point and average test methods. The methods to estimate the flow properties modeling of point pressure tests, modeling of vertical interference tests, and laboratory measurement of cased-hole sidewall cores The wells were in sufficiently good shape to allow the development of the characterization methods while still having enough defects to study differences in results as they relate to well integrity. Samples and tests analyzed from three of five wells studied in showed the cements were largely intact and had not degraded from exposure native brines. Log results taken in conjunction with the core measurements indicate that interfaces and/or problems with cement placement due to eccentering provide preferential flow paths for fluids, which can increase the effective permeability of the barrier several orders of magnitude above the permeability of intact cement. The results of the maps created using logging tools indicating that the cement condition and bond are generally good identify a need for more research to understand how logs can be used to predicteffective well permeabilities such as those measured by the VITs in this study.

  2. Chemical leukoderma

    E-Print Network [OSTI]

    O'Reilly, Kathryn E; Patel, Utpal; Chu, Julie; Patel, Rishi; Machler, Brian C

    2011-01-01

    the first report, to date, of chemical leukoderma that wasreview on biological, chemical and clinical aspects. Pigment4. Briganti S, et al. Chemical and instrumental approaches

  3. Geothermal well log interpretation state of the art. Final report

    SciTech Connect (OSTI)

    Sanyal, S.K.; Wells, L.E.; Bickham, R.E.

    1980-01-01

    An in-depth study of the state of the art in Geothermal Well Log Interpretation has been made encompassing case histories, technical papers, computerized literature searches, and actual processing of geothermal wells from New Mexico, Idaho, and California. A classification scheme of geothermal reservoir types was defined which distinguishes fluid phase and temperature, lithology, geologic province, pore geometry, salinity, and fluid chemistry. Major deficiencies of Geothermal Well Log Interpretation are defined and discussed with recommendations of possible solutions or research for solutions. The Geothermal Well Log Interpretation study and report has concentrated primarily on Western US reservoirs. Geopressured geothermal reservoirs are not considered.

  4. Transient liquid phase ceramic bonding

    DOE Patents [OSTI]

    Glaeser, Andreas M. (Berkeley, CA)

    1994-01-01

    Ceramics are joined to themselves or to metals using a transient liquid phase method employing three layers, one of which is a refractory metal, ceramic or alloy. The refractory layer is placed between two metal layers, each of which has a lower melting point than the refractory layer. The three layers are pressed between the two articles to be bonded to form an assembly. The assembly is heated to a bonding temperature at which the refractory layer remains solid, but the two metal layers melt to form a liquid. The refractory layer reacts with the surrounding liquid and a single solid bonding layer is eventually formed. The layers may be designed to react completely with each other and form refractory intermetallic bonding layers. Impurities incorporated into the refractory metal may react with the metal layers to form refractory compounds. Another method for joining ceramic articles employs a ceramic interlayer sandwiched between two metal layers. In alternative embodiments, the metal layers may include sublayers. A method is also provided for joining two ceramic articles using a single interlayer. An alternate bonding method provides a refractory-metal oxide interlayer placed adjacent to a strong oxide former. Aluminum or aluminum alloys are joined together using metal interlayers.

  5. Partnership Logging Accidents Cornelis de Hoop, LA Forest Products Lab

    E-Print Network [OSTI]

    , · Sonny Mills, LA Dept. of Labor · Greg Honaker, OSHA #12;OSHA -- LA Logging Council Strategic Partnership startup procedures. · Safe maintenance & repair procedures. · Safe work flow. · Minimize risk to fellers

  6. Multipole seismoelectric logging while drilling (LWD) for acoustic velocity measurements

    E-Print Network [OSTI]

    Zhu, Zhenya

    2012-01-01

    In seismoelectric well logging, an acoustic wave propagates along a borehole and induces electrical signals along the borehole wall. The apparent velocities of these seismoelectric signals are equal to the formation ...

  7. JOBAID-LOGGING IN TO THE OLC LEARNING SYSTEM

    Broader source: Energy.gov [DOE]

    In this job aid you will Log In to the system, Retrieve Forgotten Password and/or User ID, and Use the LMS Help System built into the application.

  8. Efficiently log and perforate 60 + wells with coiled tubing

    SciTech Connect (OSTI)

    Fertl, W.H.; Hotz, R.F.

    1987-07-01

    In today's petroleum industry, more and more emphasis is being placed on logging and completion techniques for highly deviated (extended-reach) and horizontal boreholes. This is the result of cost-effective development of oil and gas via: a minimum number of production platforms on large structures, incremental but marginal reserves in outlying and/or small fault blocks, shallow reservoirs in deep offshore waters, and significant hydrocarbon accumulations in environmentally sensitive and/or restrictive areas, e.g., perma-frost, urban areas, etc. The major challenge in logging such high-angle, extended-reach, and also horizontal boreholes is guiding the logging tool string to the bottom of the wellbore. In the horizontal portion of a borehole, the use of coiled tubing has proven successful in ''pushing'' the logging instrumentation toward the bottom (end) of the borehole.

  9. Symposium on high-temperature well-logging instrumentation

    SciTech Connect (OSTI)

    Dennis, B.R. (comp.)

    1986-06-01

    The symposium contains papers about developments in borehole logging instrumentation that can withstand downhole temperatures in excess of 300/sup 0/C and pressures greater than 103 MPa. Separate abstracts have been prepared for individual papers. (ACR)

  10. Higher Order Modes in Acoustic Logging While Drilling

    E-Print Network [OSTI]

    Chi, Shihong

    2005-01-01

    In multipole acoustic logging while drilling (LWD), the fundamental modes dominate recorded waveforms. Higher order modes may also appear and complicate the processing of LWD data. In dipole LWD measurements, the dipole ...

  11. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    Hirasaki, George J.; Mohanty, Kishore K.

    2003-02-10

    The objective of this project was to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. The advances made in the understanding of NMR fluid properties are summarized in a chapter written for an AAPG book on NMR well logging. This includes live oils, viscous oils, natural gas mixtures, and the relation between relaxation time and diffusivity.

  12. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    Hirasaki, George J.; Mohanty, Kishore K.

    2003-02-10

    The objective of this project was to characterize the fluid properties and fluid-rock interactions which are needed for formation evaluation by NMR well logging. NMR well logging is finding wide use in formation evaluation. The formation parameters commonly estimated were porosity, permeability, and capillary bound water. Special cases include estimation of oil viscosity, residual oil saturation, location of oil/water contact, and interpretation on whether the hydrocarbon is oil or gas.

  13. Initial results from an acoustic logging-while-drilling tool

    SciTech Connect (OSTI)

    Minear, J.W.; Heysse, D.R.; Boonen, P.M.

    1996-12-31

    This paper presents the initial results from field tests of an acoustic logging-while-drilling tool. Over 60,000 ft of well have been logged with 6.75-in.- and 8-in.-diameter versions of the tool. Various types of formations were encountered with compressional slowness values ranging from 55 {mu}sec/ft to 170 {mu}sec/ft. The tool is configured as a borehole-compensated device; transmitters are located on opposite sides of an array of four receivers. An ultrasonic standoff transducer provides a tool-to-borehole wall distance measurement for data quality evaluation and processing. Slowness values are computed downhole using real-time waveform processing. Full-waveform data are stored for retrieval and re-processing at the surface. Interactive processing software allows an engineer to reprocess log intervals of poorer log quality and improve the slowness log computed downhole. Downhole-processed and post-drilling-processed slowness logs are compared, and generally show close agreement. These logs also agree well with wireline slowness logs. Rugose boreholes and attenuating formations can reduce waveform quality. A new rapid-fire technique acquires multiple estimates of slowness as the drillstring rotates through only a fraction of a revolution, and improves slowness quality in rugose boreholes. Shear-wave energy is clearly apparent in most waveform data. Waveforms can be processed to yield both shear and compressional slowness values. These can then be used to estimate porosity, compute elastic moduli of the rock (for example, Poisson`s ratio, Young`s modulus, bulk compressibility, and shear modulus), and to compute synthetic seismograms for correlation with seismic profiles. Some of these applications of compressional and shear slowness data are discussed with examples.

  14. Chemically bonded phosphate ceramic sealant formulations for oil field applications

    DOE Patents [OSTI]

    Wagh, Arun S. (Naperville, IL); Jeong, Seung-Young (Taejon, KR); McDaniel, Richard (Crest Hill, IL)

    2008-10-21

    A sealant for an oil or geothermal well capable of setting within about 3 to about 6 hours at temperatures less than about 250.degree. F. for shallow wells less than about 10,000 feet and deep wells greater than about 10,000 feet having MgO present in the range of from about 9.9 to about 14.5%, KH.sub.2PO.sub.4 present in the range of from about 29.7 to about 27.2%, class C fly ash present in the range of from about 19.8 to about 36.3%, class F fly ash present in the range of from about 19.8 to about 0%, boric acid or borax present in the range of from about 0.39 to about 1.45%, and water present in the range of from about 20.3 to about 21.86% by weight of the sealant.A method of sealing wells is disclosed as are compositions for very high temperature wells is disclosed as is a composition for treating oil field wastes.

  15. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance...

    Office of Scientific and Technical Information (OSTI)

    Energy Technology Laboratory - In-house Research Sponsoring Org: USDOE Office of Electricity Delivery and Energy Reliability (OE); USDOE Office of Fossil Energy (FE) Country of...

  16. Method of waste stabilization via chemically bonded phosphate ceramics

    DOE Patents [OSTI]

    Wagh, A.S.; Singh, D.; Jeong, S.Y.

    1998-11-03

    A method for regulating the reaction temperature of a ceramic formulation process is provided comprising supplying a solution containing a monovalent alkali metal; mixing said solution with an oxide powder to create a binder; contacting said binder with bulk material to form a slurry; and allowing the slurry to cure. A highly crystalline waste form is also provided consisting of a binder containing potassium and waste substrate encapsulated by the binder. 3 figs.

  17. Formation of chemically bonded ceramics with magnesium dihydrogen phosphate binder

    DOE Patents [OSTI]

    Wagh, Arun S.; Jeong, Seung-Young

    2004-08-17

    A new method for combining magnesium oxide, MgO, and magnesium dihydrogen phosphate to form an inexpensive compactible ceramic to stabilize very low solubility metal oxides, ashes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast, and to reinforce and strengthen the ceramics formed by the addition of fibers to the initial ceramic mixture.

  18. Method of waste stabilization via chemically bonded phosphate ceramics

    DOE Patents [OSTI]

    Wagh, Arun S. (Joliet, IL); Singh, Dileep (Naperville, IL); Jeong, Seung-Young (Hinsdale, IL)

    1998-01-01

    A method for regulating the reaction temperature of a ceramic formulation process is provided comprising supplying a solution containing a monovalent alkali metal; mixing said solution with an oxide powder to create a binder; contacting said binder with bulk material to form a slurry; and allowing the slurry to cure. A highly crystalline waste form is also provided consisting of a binder containing potassium and waste substrate encapsulated by the binder.

  19. Intramolecular hydrogen bonding as a synthetic tool to induce chemical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenryInhibitingInteractive JobsEngagementInternships

  20. Micromachined chemical jet dispenser

    DOE Patents [OSTI]

    Swierkowski, S.P.

    1999-03-02

    A dispenser is disclosed for chemical fluid samples that need to be precisely ejected in size, location, and time. The dispenser is a micro-electro-mechanical systems (MEMS) device fabricated in a bonded silicon wafer and a substrate, such as glass or silicon, using integrated circuit-like fabrication technology which is amenable to mass production. The dispensing is actuated by ultrasonic transducers that efficiently produce a pressure wave in capillaries that contain the chemicals. The 10-200 {micro}m diameter capillaries can be arranged to focus in one spot or may be arranged in a larger dense linear array (ca. 200 capillaries). The dispenser is analogous to some ink jet print heads for computer printers but the fluid is not heated, thus not damaging certain samples. Major applications are in biological sample handling and in analytical chemical procedures such as environmental sample analysis, medical lab analysis, or molecular biology chemistry experiments. 4 figs.

  1. Micromachined chemical jet dispenser

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA)

    1999-03-02

    A dispenser for chemical fluid samples that need to be precisely ejected in size, location, and time. The dispenser is a micro-electro-mechanical systems (MEMS) device fabricated in a bonded silicon wafer and a substrate, such as glass or silicon, using integrated circuit-like fabrication technology which is amenable to mass production. The dispensing is actuated by ultrasonic transducers that efficiently produce a pressure wave in capillaries that contain the chemicals. The 10-200 .mu.m diameter capillaries can be arranged to focus in one spot or may be arranged in a larger dense linear array (.about.200 capillaries). The dispenser is analogous to some ink jet print heads for computer printers but the fluid is not heated, thus not damaging certain samples. Major applications are in biological sample handling and in analytical chemical procedures such as environmental sample analysis, medical lab analysis, or molecular biology chemistry experiments.

  2. Bond percolation on multiplex networks

    E-Print Network [OSTI]

    Hackett, A; Gómez, S; Arenas, A; Gleeson, J P

    2015-01-01

    We present an analytical approach for bond percolation on multiplex networks and use it to determine the expected size of the giant connected component and the value of the critical bond occupation probability in these networks. We advocate the relevance of these tools to the modeling of multilayer robustness and contribute to the debate on whether any benefit is to be yielded from studying a full multiplex structure as opposed to its monoplex projection, especially in the seemingly irrelevant case of a bond occupation probability that does not depend on the layer. Although we find that in many cases the predictions of our theory for multiplex networks coincide with previously derived results for monoplex networks, we also uncover the remarkable result that for a certain class of multiplex networks, well described by our theory, new critical phenomena occur as multiple percolation phase transitions are present. We provide an instance of this phenomenon in a multipex network constructed from London rail and Eu...

  3. Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation

    SciTech Connect (OSTI)

    Colby, Denise; Bergman, Robert; Ellman, Jonathan

    2010-05-13

    Once considered the 'holy grail' of organometallic chemistry, synthetically useful reactions employing C-H bond activation have increasingly been developed and applied to natural product and drug synthesis over the past decade. The ubiquity and relative low cost of hydrocarbons makes C-H bond functionalization an attractive alternative to classical C-C bond forming reactions such as cross-coupling, which require organohalides and organometallic reagents. In addition to providing an atom economical alternative to standard cross - coupling strategies, C-H bond functionalization also reduces the production of toxic by-products, thereby contributing to the growing field of reactions with decreased environmental impact. In the area of C-C bond forming reactions that proceed via a C-H activation mechanism, rhodium catalysts stand out for their functional group tolerance and wide range of synthetic utility. Over the course of the last decade, many Rh-catalyzed methods for heteroatom-directed C-H bond functionalization have been reported and will be the focus of this review. Material appearing in the literature prior to 2001 has been reviewed previously and will only be introduced as background when necessary. The synthesis of complex molecules from relatively simple precursors has long been a goal for many organic chemists. The ability to selectively functionalize a molecule with minimal pre-activation can streamline syntheses and expand the opportunities to explore the utility of complex molecules in areas ranging from the pharmaceutical industry to materials science. Indeed, the issue of selectivity is paramount in the development of all C-H bond functionalization methods. Several groups have developed elegant approaches towards achieving selectivity in molecules that possess many sterically and electronically similar C-H bonds. Many of these approaches are discussed in detail in the accompanying articles in this special issue of Chemical Reviews. One approach that has seen widespread success involves the use of a proximal heteroatom that serves as a directing group for the selective functionalization of a specific C-H bond. In a survey of examples of heteroatom-directed Rh catalysis, two mechanistically distinct reaction pathways are revealed. In one case, the heteroatom acts as a chelator to bind the Rh catalyst, facilitating reactivity at a proximal site. In this case, the formation of a five-membered metallacycle provides a favorable driving force in inducing reactivity at the desired location. In the other case, the heteroatom initially coordinates the Rh catalyst and then acts to stabilize the formation of a metal-carbon bond at a proximal site. A true test of the utility of a synthetic method is in its application to the synthesis of natural products or complex molecules. Several groups have demonstrated the applicability of C-H bond functionalization reactions towards complex molecule synthesis. Target-oriented synthesis provides a platform to test the effectiveness of a method in unique chemical and steric environments. In this respect, Rh-catalyzed methods for C-H bond functionalization stand out, with several syntheses being described in the literature that utilize C-H bond functionalization in a key step. These syntheses are highlighted following the discussion of the method they employ.

  4. Bond Underwriter Costs: Texas School Districts and the Hidden Cost of Issuing Bonds 

    E-Print Network [OSTI]

    Stasny, Mary Knetsar

    2011-02-22

    The purpose of this study was to investigate possible relationships between school district characteristics and bond underwriter costs for Texas independent school districts. Bond data for all school districts issuing bonds in the five-year period...

  5. Non-bonded ultrasonic transducer

    DOE Patents [OSTI]

    Eoff, J.M.

    1984-07-06

    A mechanically assembled non-bonded ultrasonic transducer includes a substrate, a piezoelectric film, a wetting agent, a thin metal electrode, and a lens held in intimate contact by a mechanical clamp. No epoxy or glue is used in the assembly of this device.

  6. Enhanced rigid-bond restraints

    SciTech Connect (OSTI)

    Thorn, Andrea; Dittrich, Birger; Sheldrick, George M., E-mail: gsheldr@shelx.uni-ac.gwdg.de [Department of Structural Chemistry, University of Göttingen, Tammannstrasse 4, D-37077 Göttingen (Germany)

    2012-07-01

    An extension is proposed to the rigid-bond description of atomic thermal motion in crystals. The rigid-bond model [Hirshfeld (1976 ?). Acta Cryst. A32, 239–244] states that the mean-square displacements of two atoms are equal in the direction of the bond joining them. This criterion is widely used for verification (as intended by Hirshfeld) and also as a restraint in structure refinement as suggested by Rollett [Crystallographic Computing (1970 ?), edited by F. R. Ahmed et al., pp. 167–181. Copenhagen: Munksgaard]. By reformulating this condition, so that the relative motion of the two atoms is required to be perpendicular to the bond, the number of restraints that can be applied per anisotropic atom is increased from about one to about three. Application of this condition to 1,3-distances in addition to the 1,2-distances means that on average just over six restraints can be applied to the six anisotropic displacement parameters of each atom. This concept is tested against very high resolution data of a small peptide and employed as a restraint for protein refinement at more modest resolution (e.g. 1.7 Ĺ)

  7. Bonded polyimide fuel cell package

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan; Graff, Robert T.; Bettencourt, Kerry

    2010-06-08

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  8. Direct synthesis of sp-bonded carbon chains on graphite surface by femtosecond laser irradiation

    SciTech Connect (OSTI)

    Hu, A.; Rybachuk, M.; Lu, Q.-B.; Duley, W. W.

    2007-09-24

    Microscopic phase transformation from graphite to sp-bonded carbon chains (carbyne) and nanodiamond has been induced by femtosecond laser pulses on graphite surface. UV/surface enhanced Raman scattering spectra and x-ray photoelectron spectra displayed the local synthesis of carbyne in the melt zone while nanocrystalline diamond and trans-polyacetylene chains form in the edge area of gentle ablation. These results evidence possible direct 'writing' of variable chemical bonded carbons by femtosecond laser pulses for carbon-based applications.

  9. Logging with coiled tubing less effective than with drill pipe

    SciTech Connect (OSTI)

    Van Den Bosch, R. )

    1994-01-31

    Coiled tubing offered neither economic nor operational advantages over drill pipe for conveying logging tools in open hole shallow horizontal wells in Germany. In the past 2 years, Mobil Erdgas-Erdoel GMbH (MEEG) participated in completing eight shallow horizontal wells. These were medium-to-short radius wells at measured depths of between 850 and 2,000 m. The average horizontal section was 350 m. The logging tools were conveyed by coiled tubing or drill pipe. MEEG attempted to log five wells with coiled tubing-conveyed tools, four with 1 1/2-in. tubing. Total depth was reached reliably in only one well, the shallowest and with the shortest horizontal section. Simulation programs were unreliable for calculating the downhole forces of the coil/tool combination or predicting possible helical lockups. In wells with drill pipe-conveyed logs, the tool combination could always be pushed to total depth, and the operations were generally faster and cost less than logging with coiled tubing. Also, drill pipe allowed longer and heavier tool strings. For reliable operations, coiled tubing needs to be more rigid, rig-up/rig-down times need to be improved, and the simulation programs must be more reliable for predicting downhole lock-up.

  10. Technical evaluation of software for gamma-ray logging system

    SciTech Connect (OSTI)

    Stromswold, D.C.

    1994-05-01

    This report contains results of a technical review of software, identified as LGCALC, that processes data collected by a high-resolution gamma-ray borehole logging system. The software presently operates within Westinghouse Hanford Company, Department of Geosciences, to process data collected by the Radionuclide Logging System. The software has been reviewed for its suitability for processing data to be collected by new high-resolution gamma-ray logging trucks scheduled to begin operational tests within Westinghouse Tank Waste Remediation Systems during 1994. Examination of the program code and hands-on operational tests have shown that this software is suitable for its intended use of processing high-resolution gamma-ray data obtained from borehole logging. Most of the code requires no changes, but in a few limited cases, suggestions have been made to correct errors or improve operation. Section 4 describes these changes. The technical review has confirmed the appropriateness, correctness, completeness, and coding accuracy of algorithms used to process spectral gamma-ray data, leading to a calculation of subsurface radionuclide contaminants. Running the program with test data from calibration models has confirmed that the program operates correctly. Comparisons with hand calculations have shown the correctness of the output from the program, based on known input data. Section 3 describes these tests. The recommended action is to make the near term programming changes suggested in Section 4.1 and then use the LGCALC analysis program with the new high-resolution logging systems once they have been properly calibrated.

  11. User's manual for geophysical well-logging software programs

    SciTech Connect (OSTI)

    Petrie, G.M.; Gibson, D.; Blair, S.C.

    1983-02-01

    Since 1958 the Ground-Water Surveillance Program for the Hanford Site has made geophysical logging measurements in most of the 800 wells and deep boreholes that have been drilled on the Hanford Site. In 1980 the Pacific Northwest Laboratory (PNL), which conducts the Ground-Water Surveillance Program, began forming a computerized data base for storing and retrieving geophysical well log data and developing software for quantitative analysis of the well log data. This report, designed to serve as a user's guide, documents the data base system that handles the well log data. Two programs, DIGLOG1 and LOGIT, are used to manipulate the data. The program DIGLOG1 translates analog paper strip charts into digital format; the program LOGIT is a general utility program that edits, displays, checks, stores, writes, and deletes sets of well log data. These two programs do not provide sophisticated display and analytical capabilities; rather, they provide programs that give the user easy access to powerful standard analytical software.

  12. Hydrogen Bond Shaping of Membrane Protein Structure

    E-Print Network [OSTI]

    Cao, Zheng

    2013-01-01

    Energy of Amide Hydrogen Bond Formation in Vacuum, in Water, andEnergy of Amide Hydrogen Bond Formation in Vacuum, in Water, andto water is dependent on the zero-point energies, i.e. the

  13. The Market for Borrowing Corporate Bonds

    E-Print Network [OSTI]

    Asquith, Paul

    This paper describes the market for borrowing corporate bonds using a comprehensive data set from a major lender. The cost of borrowing corporate bonds is comparable to the cost of borrowing stock, between 10 and 20 basis ...

  14. Chemical Education Today JChemEd.chem.wisc.edu Vol. 75 No. 5 May 1998 Journal of Chemical Education 537

    E-Print Network [OSTI]

    Rioux, Frank

    Chemical Education Today JChemEd.chem.wisc.edu · Vol. 75 No. 5 May 1998 · Journal of Chemical the following statement (1a): In our opinion we make chemistry seem more abstract, more mysterious, and more in understanding the physical nature of the chemical bond. Unfortunately, in spite of discussion of this profoundly

  15. Annual Logging Symposium, June 3-6, 2007 RAPID SIMULATION OF BOREHOLE NUCLEAR MEASUREMENTS

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    with other well logs. The particular case of logging while drilling (LWD) logs in high-angle wells of Petrophysicists and Well Log Analysts (SPWLA) and the submitting authors. This paper was prepared for presentation techniques as well as for their quantitative integration with other borehole measurements

  16. VerSum: Verifiable Computations over Large Public Logs Jelle van den Hooff

    E-Print Network [OSTI]

    blockchains, or a Certificate Transparency log. VERSUM clients ensure that the output is correct by comparing publicly available logs, whose validity is guaranteed. The logs are large (e.g., the Bitcoin blockchain is added to the Bitcoin blockchain). To run computations over these logs requires a Permission to make

  17. APPLIED PHYSICS REVIEWSFOCUSED REVIEW Adhesive wafer bonding

    E-Print Network [OSTI]

    Lü, James Jian-Qiang

    APPLIED PHYSICS REVIEWS­FOCUSED REVIEW Adhesive wafer bonding F. Niklausa Microsystem Technology 9 February 2006 Wafer bonding with intermediate polymer adhesives is an important fabrication-dimensional integrated circuits, advanced packaging, and microfluidics. In adhesive wafer bonding, the polymer adhesive

  18. Clean Energy and Bond Finance Initiative

    Broader source: Energy.gov [DOE]

    Provides information on Clean Energy and Bond Finance Initiative (CE+BFI). CE+BFI brings together public infrastructure finance agencies, clean energy public fund managers and institutional investors across the country to explore how to raise capital at scale for clean energy development through bond financing. Author: Clean Energy and Bond Finance Initiative

  19. Well-log interpretation of carbonate reservoirs with bimodal porosity 

    E-Print Network [OSTI]

    Tandircioglu, Ahmet

    1990-01-01

    ) in the flushed zone. The difference between the two was an INDUCTION RESISTIVITY SP-R-2 5 MV 9750 GAS EFFECT 4t W Run I SONIC g SW 26 58% 22 65% st Run 2 Figure 4-%ell-log responses from a Frio sandstone with bimodal porosity, Nueces County, Texas... ~ ~ ~ ' ~ ~ 23 Ol LIPF 5 OAMM* RAY SHIRE' IA POROSITY 55 15 OAL O 0 PORE ~ PERF Figure 9-Gamma-ray (GR), caliper(CAL), density porosity (gD), and neutron porosity (9N) logs through the Smackover in the Shirey 1A well, Claiborne Parish, Louisiana...

  20. Correlation of log response to production in the Austin Chalk 

    E-Print Network [OSTI]

    Behseresht, Cyrus Douglas

    1992-01-01

    of this study is to determine to what degree the response of resistivity well-logs reflects the productivity of individual wells in the Austin Chalk. An area in south-central Burleson County was chosen for the study. Logs were available from 38 wells... for the Proco Gise data, Ro at 4% is 3. 59 ohm-m (figure 12). Thus, the Proco Gise ?1 data supports an Ro of approximately 3. 58 at 4% porosity in the Austin Chalk. This test of the empirical relationship between Rt and water saturation in the Chalk does...

  1. Bonding, antibonding and tunable optical forces in asymmetric membranes

    E-Print Network [OSTI]

    Hui, Pui-Chuen

    We demonstrate that tunable attractive (bonding) and repulsive (anti-bonding) forces can arise in highly asymmetric structures coupled to external radiation, a consequence of the bonding/anti-bonding level repulsion of ...

  2. Illegal Logging and Illegal Activites in the Forestry Sector

    E-Print Network [OSTI]

    illegal activities in the forestry sector Definition of illegal logging : · "Timber harvesting harvesting procedure itself may be illegal, including corrupt means to gain access to forests(....)." (Fern, riverbanks and water catchments · Removing under/oversized trees from public forests · Extracting more timber

  3. Subsistence Halibut Community Harvest Log Page 1 of 4

    E-Print Network [OSTI]

    -0512, Expiration date: 08/31/2017 Subsistence Halibut Community Harvest Permit (CHP) Log U.S. Dept of Commerce-1668 Telephone: 1-800-304-4846 FAX: 907-586-7354 BLOCK A ­ CHP COORDINATOR 1. Name of CHP Coordinator 2. Signature of CHP Coordinator BLOCK B -- SUBSISTENCE FISHER IDENTIFICATION 1. Name of Fisher (First, Middle

  4. SPE-163690-MS Synthetic, Geomechanical Logs for Marcellus Shale

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    SPE-163690-MS Synthetic, Geomechanical Logs for Marcellus Shale M. O. Eshkalak, SPE, S. D of hydrocarbons from the reservoirs, notably shale, is attributed to realizing the key fundamentals of reservoir and mineralogy is crucial in order to identify the "right" pay-zone intervals for shale gas production. Also

  5. 17. Integrating Engineered Log JamTechnology into River Rehabilitation

    E-Print Network [OSTI]

    Montgomery, David R.

    17. Integrating Engineered Log JamTechnology into River Rehabilitation Tim Abbe, George Pess, David R. Montgomery, and Kevin L. Fetherston ABSTRACT Reach-scale river rehabilitation projects using and engineering practices. The ELJ demonstration projects were developed as part of river rehabilitation efforts

  6. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    George J. Hirasaki; Kishore K. Mohanty

    2005-09-05

    The objective of this report is to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. The advances made in the understanding of NMR fluid properties are summarized in a chapter written for an AAPG book on NMR well logging. This includes live oils, viscous oils, natural gas mixtures, and the relation between relaxation time and diffusivity. Oil based drilling fluids can have an adverse effect on NMR well logging if it alters the wettability of the formation. The effect of various surfactants on wettability and surface relaxivity are evaluated for silica sand. The relation between the relaxation time and diffusivity distinguishes the response of brine, oil, and gas in a NMR well log. A new NMR pulse sequence in the presence of a field gradient and a new inversion technique enables the T{sub 2} and diffusivity distributions to be displayed as a two-dimensional map. The objectives of pore morphology and rock characterization are to identify vug connectivity by using X-ray CT scan, and to improve NMR permeability correlation. Improved estimation of permeability from NMR response is possible by using estimated tortuosity as a parameter to interpolate between two existing permeability models.

  7. Logging threatens Indonesia's biodiversity By Dianthus Saputra Estey in Jakarta

    E-Print Network [OSTI]

    Logging threatens Indonesia's biodiversity By Dianthus Saputra Estey in Jakarta Monday 13 October 2003, 16:57 Makka Time, 13:57 GMT A tenth of the world's tropical rainforests lie in Indonesia year," Togu Manurung from Forest Watch Indonesia said. This ranks the depletion of Indonesia

  8. Feedback Control Theory and Processing System Log Streams Research Project

    E-Print Network [OSTI]

    Tang, Pingzhong

    Feedback Control Theory and Processing System Log Streams by Wei Xu Research Project Submitted, and on exploring general techniques of applying feedback control theory to distributed computer systems. We have. All problems addressed are solved systematically with feedback-control-theory. We discuss three uses

  9. Lightweight Logging for Lazy Release Consistent Distributed Shared Memory

    E-Print Network [OSTI]

    Neves, Nuno

    Lightweight Logging for Lazy Release Consistent Distributed Shared Memory Manuel Costa, Paulo Guedes, Manuel Sequeira, Nuno Neves, Miguel Castro IST - INESC R. Alves Redol 9, 1000 Lisboa PORTUGAL algorithm for a DSM system based on lazy release Manuel Costa, Nuno Neves and Miguel Castro were supported

  10. Interface Evolution of Au-Au Thermocompression Bonding and Nanotwins

    E-Print Network [OSTI]

    Beekley, Brett

    2015-01-01

    bonds. Journal of Microelectromechanical Systems, 2004. 13(bonds. Journal of Microelectromechanical Systems, 2002. 11(packaging. Journal of Microelectromechanical Systems, 2000.

  11. Annual Logging Symposium, June 26-29, 2005 JOINT STOCHASTIC INVERSION OF PETROPHYSICAL LOGS AND 3D

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    : APPLICATION TO A GULF- OF-MEXICO DEEPWATER HYDROCARBON RESERVOIR A. Contreras and C. Torres seismic data acquired in the deepwater Gulf of Mexico. Reservoir units consist of stacked turbidite sands and fluid saturation. Both petrophysical logs and elastic-petrophysical correlation cross-plots, together

  12. Bond Programs | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois:Energy Authority JumpBond Programs Jump to:

  13. Bonding Tools | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment|Marketing, LLC |Energycurrently provides technicalBonds are one of

  14. Knowledge-based stratigraphic well-log correlation 

    E-Print Network [OSTI]

    Denton, Michael A.

    1990-01-01

    correlated higher ranking strata. Thus, higher ranking correlations provide heuristics for lower ranking correlations. The system represents strata by symbols from a set of standard symbols which include peaks, troughs, and steps. Symbols replace events.... The zone attributes abstracted from the well-log include the following: interval, lithology ? classified as shale or non-shale, zone position, general zone shape, thickness, average amplitude, zone above name, and zone below name. Thus, the expert system...

  15. Gamma-Ray Logging Workshop (February 1981) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,Executive Compensation References: FARWashers |Gamma-Ray Logging Workshop

  16. Hydrogen Adsorption Induces Interlayer Carbon Bond Formation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Adsorption Induces Interlayer Carbon Bond Formation in Supported Few-Layer Graphene Friday, February 28, 2014 Among the allotropes of carbon, diamond has some of the most...

  17. Nuclear reactor multiphysics via bond graph formalism

    E-Print Network [OSTI]

    Sosnovsky, Eugeny

    2014-01-01

    This work proposes a simple and effective approach to modeling nuclear reactor multiphysics problems using bond graphs. Conventional multiphysics simulation paradigms normally use operator splitting, which treats the ...

  18. Thermal Conductivity from Core and Well log Data

    E-Print Network [OSTI]

    Hartmann, Andreas; Clauser, Christoph

    2008-01-01

    The relationships between thermal conductivity and other petrophysical properties have been analysed for a borehole drilled in a Tertiary Flysch sequence. We establish equations that permit us to predict rock thermal conductivity from logging data. A regression analysis of thermal conductivity, bulk density, and sonic velocity yields thermal conductivity with an average accuracy of better than 0.2 W/(m K). As a second step, logging data is used to compute a lithological depth profile, which in turn is used to calculate a thermal conductivity profile. From a comparison of the conductivity-depth profile and the laboratory data it can be concluded that thermal conductivity can be computed with an accuracy of less than 0.3 W/(m K)from conventional wireline data. The comparison of two different models shows that this approach can be practical even if old and incomplete logging data is used. The results can be used to infer thermal conductivity for boreholes without appropriate core data that are drilled in a simil...

  19. Bonding energies and long-range order in the trialuminides

    SciTech Connect (OSTI)

    Sparks, C.J.; Specht, E.D.; Ice, G.E.; Zschack, P.; Schneibel, J.

    1990-01-01

    The degree of long-range order in the trialuminides is determined by X-ray powder diffraction techniques. Long-range order exists to their melting points. For the binary trialuminides Al{sub 3}Ti, Al{sub 73}Ti{sub 27}, and Al{sub 3}Sc, the degree of long-range order is nearly perfect and is a measure of the lack of mixing of the aluminum atoms onto the sublattice occupied by either Ti or Sc. A calculation of the bond energy between neighboring pairs of atoms from the ordering (melting) temperature is made following the Bragg-Williams mean field theory approach. These bond energies compare favorably with more sophisticated calculations. Bond energies are found to be larger than the energy difference between the crystal structure forms DO{sub 22}, Ll{sub 2}, and DO{sub 23}, and therefore, more relevant to understanding the mechanical and chemical behavior of the trialuminides. Ordering or melting temperatures of these intermetallics reflect the strong Al-metal near-neighbor pair potentials and may provide insights to their brittle properties. 11 refs., 2 figs., 2 tabs.

  20. Vacuum fusion bonded glass plates having microstructures thereon

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2001-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  1. Bond Strength Measurements from an Australian Standard Bond Wrench in Comparison to the Unbalanced ASTM C 1072 Bond Wrench to the Balanced and Unbalanced Wrenches 

    E-Print Network [OSTI]

    Suresh, Sri Vishnu Chaitanya Guptha

    2014-08-14

    in 1980s in the Australian laboratories. Former TAMU students had built a lightweight Indian unbalanced and balanced bond wrench. An Australian bond wrench was manufactured in 2011 and subsequently in 2012 an ASTM C 1072 Bond Wrench was developed...

  2. Valence Bond States: Link models

    E-Print Network [OSTI]

    E. Rico; R. Hübener; S. Montangero; N. Moran; B. Pirvu; J. Vala; H. J. Briegel

    2009-08-07

    An isotropic anti-ferromagnetic quantum state on a square lattice is characterized by symmetry arguments only. By construction, this quantum state is the result of an underlying valence bond structure without breaking any symmetry in the lattice or spin spaces. A detailed analysis of the correlations of the quantum state is given (using a mapping to a 2D classical statistical model and methods in field theory like mapping to the non-linear sigma model or bosonization techniques) as well as the results of numerical treatments (regarding exact diagonalization and variational methods). Finally, the physical relevance of the model is motivated. A comparison of the model to known anti-ferromagnetic Mott-Hubbard insulators is given by means of the two-point equal-time correlation function obtained i) numerically from the suggested state and ii) experimentally from neutron scattering on cuprates in the anti-ferromagnetic insulator phase.

  3. Moab Project Logs 2 Million Work Hours Without Lost-Time Injury...

    Energy Savers [EERE]

    Logs 2 Million Work Hours Without Lost-Time Injury or Illness Moab Project Logs 2 Million Work Hours Without Lost-Time Injury or Illness March 31, 2014 - 12:00pm Addthis Empty...

  4. Event Based Low Frequency Impedance Modeling using Well Logs and Seismic Attributes

    E-Print Network [OSTI]

    Mosegaard, Klaus

    prediction of this specific attribute. However, quantitative reservoir characterization in chalk is severelyEvent Based Low Frequency Impedance Modeling using Well Logs and Seismic Attributes Radmila logs. Seismic inversion, a process of converting seismic data into relative impedance, provides

  5. What is a blog? The word "blog," a contraction of "web log," is an informational web

    E-Print Network [OSTI]

    Zhou, Pei

    What is a blog? The word "blog," a contraction of "web log," is an informational web page's log, blogs on the web tend to maintain an ordered chronology, although they often unfold in reverse

  6. Method for producing components with internal architectures, such as micro-channel reactors, via diffusion bonding sheets

    DOE Patents [OSTI]

    Alman, David E. (Corvallis, OR); Wilson, Rick D. (Corvallis, OR); Davis, Daniel L. (Albany, OR)

    2011-03-08

    This invention relates to a method for producing components with internal architectures, and more particularly, this invention relates to a method for producing structures with microchannels via the use of diffusion bonding of stacked laminates. Specifically, the method involves weakly bonding a stack of laminates forming internal voids and channels with a first generally low uniaxial pressure and first temperature such that bonding at least between the asperites of opposing laminates occurs and pores are isolated in interfacial contact areas, followed by a second generally higher isostatic pressure and second temperature for final bonding. The method thereby allows fabrication of micro-channel devices such as heat exchangers, recuperators, heat-pumps, chemical separators, chemical reactors, fuel processing units, and combustors without limitation on the fin aspect ratio.

  7. Comparison of VSP and sonic-log data in nonvertical wells in a heterogeneous structure

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    geophysics, sonic-log measurements and vertical seismic profiling VSP are two techniques which provide and Ludk Klimes1 ABSTRACT To compare the results of sonic-log measurements and of vertical seismic profiling VSP , sonic-log velocities are used to estimate the corresponding traveltime in the geologic

  8. Quantitative interpretation of pulsed neutron capture logs: Part 1 --Fast numerical simulation

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    for shoulder-bed effects on R logs acquired in sand- shale laminated reservoirs. Because of diffusion effects responses of pure-sand and pure- shale end members of the sedimentary sequence. We have developed a new of waterflood residual oil saturation via the log-inject-log procedure (Richardson et al., 1973; Reedy, 1984

  9. Experimental Observation of Bonding Electrons in Proteins*

    E-Print Network [OSTI]

    Experimental Observation of Bonding Electrons in Proteins* (Received for publication, April 15 enables bonding details of electron distributions in proteins to be revealed experimentally for the first time. We move one step closer to imaging directly the fine details of the electronic structure on which

  10. 1 mil gold bond wire study.

    SciTech Connect (OSTI)

    Huff, Johnathon; McLean, Michael B.; Jenkins, Mark W.; Rutherford, Brian Milne

    2013-05-01

    In microcircuit fabrication, the diameter and length of a bond wire have been shown to both affect the current versus fusing time ratio of a bond wire as well as the gap length of the fused wire. This study investigated the impact of current level on the time-to-open and gap length of 1 mil by 60 mil gold bond wires. During the experiments, constant current was provided for a control set of bond wires for 250ms, 410ms and until the wire fused; non-destructively pull-tested wires for 250ms; and notched wires. The key findings were that as the current increases, the gap length increases and 73% of the bond wires will fuse at 1.8A, and 100% of the wires fuse at 1.9A within 60ms. Due to the limited scope of experiments and limited data analyzed, further investigation is encouraged to confirm these observations.

  11. Atomic Structures of Riboflavin (Vitamin B2) and its Reduced Form with Bond Lengths Based on Additivity of Atomic Radii

    E-Print Network [OSTI]

    Raji Heyrovska

    2008-06-21

    It has been shown recently that chemical bond lengths, in general, like those in the components of nucleic acids, caffeine related compounds, all essential amino acids, methane, benzene, graphene and fullerene are sums of the radii of adjacent atoms constituting the bond. Earlier, the crystal ionic distances in all alkali halides and lengths of many partially ionic bonds were also accounted for by the additivity of ionic as well as covalent radii. Here, the atomic structures of riboflavin and its reduced form are presented based on the additivity of the same set of atomic radii as for other biological molecules.

  12. Atomic Structures of Riboflavin (Vitamin B2) and its Reduced Form with Bond Lengths Based on Additivity of Atomic Radii

    E-Print Network [OSTI]

    Heyrovska, Raji

    2008-01-01

    It has been shown recently that chemical bond lengths, in general, like those in the components of nucleic acids, caffeine related compounds, all essential amino acids, methane, benzene, graphene and fullerene are sums of the radii of adjacent atoms constituting the bond. Earlier, the crystal ionic distances in all alkali halides and lengths of many partially ionic bonds were also accounted for by the additivity of ionic as well as covalent radii. Here, the atomic structures of riboflavin and its reduced form are presented based on the additivity of the same set of atomic radii as for other biological molecules.

  13. Property:FirstWellLog | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to: navigation,Property EditMimeType Jump to:FirstWellLog Jump to: navigation,

  14. CHEMICAL ENGINEERING AND MANUFACTURING CHEMICAL ENGINEERING

    E-Print Network [OSTI]

    Provancher, William

    CHEMICAL ENGINEERING AND MANUFACTURING CHEMICAL ENGINEERING Objective Chemical Engineers of chemicals. This lesson introduces students to one component of chemical engineering: food processing, and a chemical engineer 2. How chemical engineers are involved in food production 3. That chemical engineers need

  15. Chemical sensors

    DOE Patents [OSTI]

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1991-07-02

    Sensors responsive to small changes in the concentration of chemical species are disclosed. The sensors comprise a mechanochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment. They are operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical response. 9 figures.

  16. Qualitative properties of optimal portfolios in log-normal markets

    E-Print Network [OSTI]

    Zariphopoulou, Thaleia

    ), t (stock allocation) · Value of allocation Xt = 0 t + t dXt = t( dt + dWt) ; = 4 #12;Value function-normal markets (with S. Kallblad) · Completely monotone functions and marginal utilities (with S. Kallblad securities dSt = St dt + St dWt , S0 > 0 dBt = 0 , B0 = 1 · Self-financing strategies 0 t (bond allocation

  17. Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines

    E-Print Network [OSTI]

    Khodagholian, Sevana

    2010-01-01

    9. S. Yaghmaei, In Search of a Low Barrier Hydrogen Bond inP.A. Frey, and J.A. Gerlt, “The Low Barrier Hydrogen Bond inConsiderations Show That Low-Barrier Hydrogen Bonds do not

  18. A Surprising Path for Proton Transfer Without Hydrogen Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Surprising Path for Proton Transfer Without Hydrogen Bonds Print Hydrogen bonds are found everywhere in chemistry and biology and are critical in DNA and RNA. A hydrogen bond...

  19. A Surprising Path for Proton Transfer Without Hydrogen Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Surprising Path for Proton Transfer Without Hydrogen Bonds A Surprising Path for Proton Transfer Without Hydrogen Bonds Print Wednesday, 25 July 2012 00:00 Hydrogen bonds are...

  20. Log of Changes to IMA Mineral List This log file was begun in June 2010 to keep track of changes to the IMA list of minerals

    E-Print Network [OSTI]

    Downs, Robert T.

    1 Log of Changes to IMA Mineral List This log file was begun in June 2010 to keep track of changes to the IMA list of minerals at http://rruff.info/IMA. 2 August 2013: Eltyubyuite: New mineral descriptions of wadalite: a new mineral from the Northern Caucasus, Kabardino-Balkaria, Russia. European Journal

  1. Process Of Bonding Copper And Tungsten

    DOE Patents [OSTI]

    Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO); Davis, John W. (Ballwin, MO)

    2000-07-18

    Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by sintering a stack of individual copper and tungsten powder blend layers having progressively higher copper content/tungsten content, by volume, ratio values in successive powder blend layers in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

  2. Atomically Bonded Transparent Superhydrophobic Coatings

    SciTech Connect (OSTI)

    Aytug, Tolga

    2015-08-01

    Maintaining clarity and avoiding the accumulation of water and dirt on optically transparent surfaces such as US military vehicle windshields, viewports, periscope optical head windows, and electronic equipment cover glasses are critical to providing a high level of visibility, improved survivability, and much-needed safety for warfighters in the field. Through a combination of physical vapor deposition techniques and the exploitation of metastable phase separation in low-alkali borosilicate, a novel technology was developed for the fabrication of optically transparent, porous nanostructured silica thin film coatings that are strongly bonded to glass platforms. The nanotextured films, initially structurally superhydrophilic, exhibit superior superhydrophobicity, hence antisoiling ability, following a simple but robust modification in surface chemistry. The surfaces yield water droplet contact angles as high as 172°. Moreover, the nanostructured nature of these coatings provides increased light scattering in the UV regime and reduced reflectivity (i.e., enhanced transmission) over a broad range of the visible spectrum. In addition to these functionalities, the coatings exhibit superior mechanical resistance to abrasion and are thermally stable to temperatures approaching 500°C. The overall process technology relies on industry standard equipment and inherently scalable manufacturing processes and demands only nontoxic, naturally abundant, and inexpensive base materials. Such coatings, applied to the optical components of current and future combat equipment and military vehicles will provide a significant strategic advantage for warfighters. The inherent self-cleaning properties of such superhydrophobic coatings will also mitigate biofouling of optical windows exposed to high-humidity conditions and can help decrease repair/replacement costs, reduce maintenance, and increase readiness by limiting equipment downtime.

  3. New Bond Helps Toledo, Ohio, Expand Financing Pool | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Bond Helps Toledo, Ohio, Expand Financing Pool New Bond Helps Toledo, Ohio, Expand Financing Pool The logo for Better Buildings Northwest Ohio, Toleco Lucas County Port...

  4. Surface Modification by Atmospheric Pressure Plasma for Improved Bonding

    E-Print Network [OSTI]

    Williams, Thomas Scott

    2013-01-01

    of hydrogen- bonded hydroxyl groups. Acknowledgements Thisonto the exposed surface hydroxyl groups. The rate offraction of hydrogen-bonded hydroxyl groups increased from

  5. Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    conservation bond and new clean renewable energy bonds, including characteristics, mechanics, allocated volume, and other information. Author: U.S. Department of Energy...

  6. Using Qualified Energy Conservation Bonds for Public Building...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bonds for Public Building Upgrades: Reducing Energy Bills in the City of Philadelphia Using Qualified Energy Conservation Bonds for Public Building Upgrades: Reducing...

  7. Review of Direct Metal Bonding for Microelectronic Interconnections

    E-Print Network [OSTI]

    Zhang, G.G.

    Microelectronic interconnections require advanced joining techniques. Direct metal bonding methods, which include thercomsonic and thermocompression bonding, offer remarkable advantages over soldering and adhesives joining. ...

  8. REITs: Stocks, Bonds, or Real Estate?

    E-Print Network [OSTI]

    Rosen, Kenneth T.

    1995-01-01

    Berkeley FISHER CENTER FOR REAL ESTATE AND URBAN ECONOMICS244 RElTs: Stocks, Bonds or Real Estate? By KENNETH T. ROSENBUSINESS FISHER CENTER FOR REAL ESTATE AND URBAN ECONOMICS

  9. Mechanics aspects of water thermocompression bonding

    E-Print Network [OSTI]

    Stamoulis, Konstantinos, 1970-

    2005-01-01

    Wafer-level, thermocompression bonding is a promising technique for microelectromechanical systems (MEMS) packaging. The process is a form of solid-state joining and requires the simultaneous application of temperature and ...

  10. Ultrafast Infrared Studies of Bond Activation in

    E-Print Network [OSTI]

    Harris, Charles B.

    a few. Predominate in the field are UV-pump visible-probe techniques, a fact which derives largely from industry. Si-H bond activation by certain transition-metal-containing com- pounds was discovered by Jetz

  11. Corporate bond repurchases and earnings management

    E-Print Network [OSTI]

    Lemayian, Zawadi Rehema

    2013-01-01

    This paper investigates whether earnings management incentives are associated with gains/losses recognized when firms repurchase bonds. The research question is motivated by the inclusion of these gains/losses in firms' ...

  12. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, V.A.

    1991-04-23

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof is disclosed. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, Au and alloys thereof. 3 figures.

  13. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, Victor A. (Naperville, IL)

    1991-01-01

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, An and alloys thereof.

  14. Explicit Collision Simulation of Chemical Reactions in a Graph Based Artifical Chemistry

    E-Print Network [OSTI]

    Stadler, Peter F.

    Explicit Collision Simulation of Chemical Reactions in a Graph Based Artifical Chemistry Gil BenkË?uckel Theory method. Here we describe an extension of the model that models chemical reactions as the result, the reactions are simulated in a way that treats the formation and breakage of individual chemical bonds

  15. Explicit Collision Simulation of Chemical Reactions in a Graph Based Artifical Chemistry

    E-Print Network [OSTI]

    Stadler, Peter F.

    Explicit Collision Simulation of Chemical Reactions in a Graph Based Artifical Chemistry Gil Benk¨uckel Theory method. Here we describe an extension of the model that models chemical reactions as the result, the reactions are simulated in a way that treats the formation and breakage of individual chemical bonds

  16. Chemical sensors

    DOE Patents [OSTI]

    Lowell, J.R. Jr.; Edlund, D.J.; Friesen, D.T.; Rayfield, G.W.

    1992-06-09

    Sensors responsive to small changes in the concentration of chemical species are disclosed, comprising a mechanicochemically responsive polymeric film capable of expansion or contraction in response to a change in its chemical environment, either operatively coupled to a transducer capable of directly converting the expansion or contraction to a measurable electrical or optical response, or adhered to a second inert polymeric strip, or doped with a conductive material. 12 figs.

  17. Influence of silicon dangling bonds on germanium thermal diffusion within SiO{sub 2} glass

    SciTech Connect (OSTI)

    Barba, D.; Martin, F.; Ross, G. G. [INRS Centre for Energy, Materials and Telecommunications, 1650 Boul. Lionel-Boulet, Varennes, Québec J3X 1S2 (Canada); Cai, R. S.; Wang, Y. Q. [The Cultivation Base for State Key Laboratory, Qingdao University, Qingdao 266071 (China); Demarche, J.; Terwagne, G. [LARN, Centre de Recherche en Physique de la Matičre et du Rayonnement (PMR), University of Namur (FUNDP), B-5000 Namur (Belgium); Rosei, F. [INRS Centre for Energy, Materials and Telecommunications, 1650 Boul. Lionel-Boulet, Varennes, Québec J3X 1S2 (Canada); Center for Self-Assembled Chemical Structures, McGill University, Montreal, Quebec H3A 2K6 (Canada)

    2014-03-17

    We study the influence of silicon dangling bonds on germanium thermal diffusion within silicon oxide and fused silica substrates heated to high temperatures. By using scanning electron microscopy and Rutherford backscattering spectroscopy, we determine that the lower mobility of Ge found within SiO{sub 2}/Si films can be associated with the presence of unsaturated SiO{sub x} chemical bonds. Comparative measurements obtained by x-ray photoelectron spectroscopy show that 10% of silicon dangling bonds can reduce Ge desorption by 80%. Thus, the decrease of the silicon oxidation state yields a greater thermal stability of Ge inside SiO{sub 2} glass, which could enable to considerably extend the performance of Ge-based devices above 1300?K.

  18. Tubulin bond energies and microtubule biomechanics determined from nanoindentation in silico

    E-Print Network [OSTI]

    Kononova, Olga; Theisen, Kelly E; Marx, Kenneth A; Dima, Ruxandra I; Ataullakhanov, Fazly I; Grishchuk, Ekaterina L; Barsegov, Valeri

    2015-01-01

    Microtubules, the primary components of the chromosome segregation machinery, are stabilized by longitudinal and lateral non-covalent bonds between the tubulin subunits. However, the thermodynamics of these bonds and the microtubule physico-chemical properties are poorly understood. Here, we explore the biomechanics of microtubule polymers using multiscale computational modeling and nanoindentations in silico of a contiguous microtubule fragment. A close match between the simulated and experimental force-deformation spectra enabled us to correlate the microtubule biomechanics with dynamic structural transitions at the nanoscale. Our mechanical testing revealed that the compressed MT behaves as a system of rigid elements interconnected through a network of lateral and longitudinal elastic bonds. The initial regime of continuous elastic deformation of the microtubule is followed by the transition regime, during which the microtubule lattice undergoes discrete structural changes, which include first the reversib...

  19. Galaxy rotation curves with log-normal density distribution

    E-Print Network [OSTI]

    Marr, John H

    2015-01-01

    The log-normal distribution represents the probability of finding randomly distributed particles in a micro canonical ensemble with high entropy. To a first approximation, a modified form of this distribution with a truncated termination may represent an isolated galactic disk, and this disk density distribution model was therefore run to give the best fit to the observational rotation curves for 37 representative galaxies. The resultant curves closely matched the observational data for a wide range of velocity profiles and galaxy types with rising, flat or descending curves in agreement with Verheijen's classification of 'R', 'F' and 'D' type curves, and the corresponding theoretical total disk masses could be fitted to a baryonic Tully Fisher relation (bTFR). Nine of the galaxies were matched to galaxies with previously published masses, suggesting a mean excess dynamic disk mass of dex0.61+/-0.26 over the baryonic masses. Although questionable with regard to other measurements of the shape of disk galaxy g...

  20. arXiv:0909.0288v2[math.AG]16May2010 GEOGRAPHY OF LOG MODELS

    E-Print Network [OSTI]

    Cheltsov, Ivan

    arXiv:0909.0288v2[math.AG]16May2010 GEOGRAPHY OF LOG MODELS: THEORY AND APPLICATIONS. V.V. SHOKUROV AND SUNG RAK CHOI Abstract. An introduction to geography of log models with ap- plications to positive 2. Geography of log models 2 3. Positive cones 13 4. Finiteness results for log models 18 5

  1. Kinetics of bond formation in crosslinked gelatin gels

    E-Print Network [OSTI]

    T. Abete; E. Del Gado; D. Hellio Serughetti; L. de Arcangelis; M. Djabourov; A. Coniglio

    2006-11-07

    In chemical crosslinking of gelatin solutions, two different time scales affect the kinetics of the gel formation in the experiments. We complement the experimental study with Monte Carlo numerical simulations of a lattice model. This approach shows that the two characteristic time scales are related to the formation of single bonds crosslinker-chain and of bridges between chains. In particular their ratio turns out to control the kinetics of the gel formation. We discuss the effect of the concentration of chains. Finally our results suggest that, by varying the probability of forming bridges as an independent parameter, one can finely tune the kinetics of the gelation via the ratio of the two characteristic times.

  2. Double site-bond percolation model for biomaterial implants

    E-Print Network [OSTI]

    Mely, H

    2011-01-01

    We present a double site-bond percolation model to account, on the one hand, for the vascularization and/or resorption of biomaterial implant in bones and, on the other hand, for its mechanical continuity. The transformation of the implant into osseous material, and the dynamical formation/destruction of this osseous material is accounted for by creation and destruction of links and sites in two, entangled, networks. We identify the relevant parameters to describe the implant and its evolution, and separate their biological or chemical origin from their physical one. We classify the various phenomena in the two regimes, percolating or non-percolating, of the networks. We present first numerical results in two dimensions.

  3. Qualified Energy Conservation Bond State-by-State Summary Tables

    Broader source: Energy.gov [DOE]

    Provides a list of qualified energy conservation bond state summary tables. Author: Energy Programs Consortium

  4. Hydrogen Bonding DOI: 10.1002/anie.200501349

    E-Print Network [OSTI]

    Simons, Jack

    Hydrogen Bonding DOI: 10.1002/anie.200501349 Observation of Weak C�H···O Hydrogen Bonding to Unactivated Alkanes** Xue-Bin Wang, Hin-Koon Woo, Boggavarapu Kiran, and Lai-Sheng Wang* The hydrogen bond carbon can also behave as a proton donor to form C�H···O-type hydrogen bonds has been the subject

  5. Improved Characterization of Transmitted Wavefront Error on CADB Epoxy-Free Bonded Solid State Laser Materials

    SciTech Connect (OSTI)

    Bayramian, A

    2010-12-09

    Current state-of-the-art and next generation laser systems - such as those used in the NIF and LIFE experiments at LLNL - depend on ever larger optical elements. The need for wide aperture optics that are tolerant of high power has placed many demands on material growers for such diverse materials as crystalline sapphire, quartz, and laser host materials. For such materials, it is either prohibitively expensive or even physically impossible to fabricate monolithic pieces with the required size. In these cases, it is preferable to optically bond two or more elements together with a technique such as Chemically Activated Direct Bonding (CADB{copyright}). CADB is an epoxy-free bonding method that produces bulk-strength bonded samples with negligible optical loss and excellent environmental robustness. The authors have demonstrated CADB for a variety of different laser glasses and crystals. For this project, they will bond quartz samples together to determine the suitability of the resulting assemblies for large aperture high power laser optics. The assemblies will be evaluated in terms of their transmitted wavefront error, and other optical properties.

  6. Lithology and well log study of Campbell E-2 geothermal test...

    Open Energy Info (EERE)

    Lithology and well log study of Campbell E-2 geothermal test well, Humboldt House geothermal prospect, Pershing County, Nevada Jump to: navigation, search OpenEI Reference...

  7. Managing Value-at-Risk for a bond using bond put options

    E-Print Network [OSTI]

    Vanmaele, Michčle

    Managing Value-at-Risk for a bond using bond put options Griselda Deelstra1 , Ahmed Ezzine1 , Dries. Furthermore, at a suffi- ciently low confidence level the VaR measure explicitly focuses risk managersR-based risk management. The starting point of our analysis is the classical hedging example, where

  8. Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, Tobias Steinel, and M. D. Fayer*

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, TobiasVed: September 1, 2003; In Final Form: December 18, 2003 The nature of hydrogen bonding networks following hydrogen bond breaking is investigated using vibrational echo correlation spectroscopy of the hydroxyl

  9. Chemical Occurrences

    Broader source: Energy.gov [DOE]

    Classification of Chemical Occurrence Reports into the following four classes: Occurrences characterized by serious energy release, injury or exposure requiring medical treatment, or severe environmental damage, Occurrences characterized by minor injury or exposure, or reportable environmental release, Occurrences that were near misses including notable safety violations and Minor occurrences.

  10. Chemical Evolution

    E-Print Network [OSTI]

    Francesca Matteucci

    2007-04-05

    In this series of lectures we first describe the basic ingredients of galactic chemical evolution and discuss both analytical and numerical models. Then we compare model results for the Milky Way, Dwarf Irregulars, Quasars and the Intra-Cluster- Medium with abundances derived from emission lines. These comparisons allow us to put strong constraints on the stellar nucleosynthesis and the mechanisms of galaxy formation.

  11. J. Am. Chem. SOC.1995,117, 3231-3243 3231 Multiple Bonds between Main-Group Elements and Transition

    E-Print Network [OSTI]

    Bluemel, Janet

    J. Am. Chem. SOC.1995,117, 3231-3243 3231 Multiple Bonds between Main-Group Elements and Transition Britain, HOECHST AG, Zentralforschung (G 487), 0-65926 Frankfurt am Main, Germany, and Institutfur are the main techniques used to study the unique structure of this organometallic polymer. Chemical

  12. Bonded ultrasonic transducer and method for making

    DOE Patents [OSTI]

    Dixon, R.D.; Roe, L.H.; Migliori, A.

    1995-11-14

    An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements. 12 figs.

  13. Process Of Bonding Copper And Tungsten

    DOE Patents [OSTI]

    Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO)

    1999-11-23

    Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by thermal plasma spraying mixtures of copper powder and tungsten powder in a varied blending ratio such that the blending ratio of the copper powder and the tungsten powder that is fed to a plasma torch is intermittently adjusted to provide progressively higher copper content/tungsten content, by volume, ratio values in the interlayer in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

  14. Bonded ultrasonic transducer and method for making

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Roe, Lawrence H. (Los Alamos, NM); Migliori, Albert (Santa Fe, NM)

    1995-01-01

    An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements.

  15. Stanford University EH&S: Chemical Waste Manager Quick Start Guide Revision: August, 2009 1/2 Stanford University EH&S Presents

    E-Print Network [OSTI]

    Stanford University EH&S: Chemical Waste Manager Quick Start Guide Revision: August, 2009 1/2 Stanford University EH&S Presents: Chemical Waste Manager ­ Quick Start Guide Welcome to the new Chemical Waste Manager. This quick start guide will help you get started with logging in, creating new waste tags

  16. Microstructural Characteristics of HIP-bonded Monolithic Nuclear Fuels with a Diffusion Barrier

    SciTech Connect (OSTI)

    Jan-Fong Jue; Dennis D. Keiser, Jr.; Cynthia R. Breckenridge; Glenn A. Moore; Mitchell K. Meyer

    2014-05-01

    Due to the limitation of maximum uranium load achievable by dispersion fuel type, the Global Threat Reduction Initiative (GTRI) is developing an advanced monolithic fuel to convert US high performance research reactors to low-enriched uranium. Hot-isostatic-press bonding was the single process down-selected to bond monolithic U-Mo fuel meat to aluminum alloy cladding. A diffusion barrier was applied to the U–Mo fuel meat by roll-bonding process to prevent extensive interaction between fuel meat and aluminum-alloy cladding. Microstructural characterization was performed on fresh fuel plates fabricated at Idaho National Laboratory. Interfaces between fuel meat, cladding, and diffusion barrier, as well as U–10Mo fuel meat and Al–6061 cladding were characterized by scanning electron microscopy. Preliminary results indicate that the interfaces contain many different phases while decomposition, second phases, and chemical banding were also observed in the fuel meat. The important attributes of the HIP-bonded monolithic fuel are • A typical Zr diffusion barrier of thickness 25 µm • Transverse cross section that exhibits relatively equiaxed grains with an average grain diameter of 10 µm • Chemical banding, in some areas more than 100 µm in length, that is very pronounced in longitudinal (i.e., rolling) direction with Mo concentration varying from 7–13 wt% • Decomposed areas containing plate-shaped low-Mo phase • A typical Zr/cladding interaction layer of thickness 1-2 µm • A visible UZr2 bearing layer of thickness 1-2 µm • Mo-rich precipitates (mainly Mo2Zr, forming a layer in some areas) followed by a Mo-depleted sub-layer between the visible UZr2-bearing layer and the U–Mo matrix • No excessive interaction between cladding and the uncoated fuel edge • Cladding-to-cladding bonding that exhibits no cracks or porosity with second phases high in Mg, Si, and O decorating the bond line. • Some of these attributes might be critical to the irradiation performance of monolithic U-10Mo nuclear fuel. There are several issues or concerns that warrant more detailed study, such as precipitation along cladding-to-cladding bond line, chemical banding, uncovered fuel-zone edge, and interaction layer between U–Mo fuel meat and zirconium. Future post-irradiation examination results will focus, among other things, on identifying in-reactor failure mechanisms and, eventually, directing further fresh fuel characterization efforts.

  17. Phosphate-bonded calcium aluminate cements

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY)

    1993-01-01

    A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120.degree. C. to about 300.degree. C. to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate.

  18. Phosphate-bonded calcium aluminate cements

    DOE Patents [OSTI]

    Sugama, T.

    1993-09-21

    A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120 C to about 300 C to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate. 10 figures.

  19. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

    1998-08-25

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

  20. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

    1998-09-08

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

  1. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); McMillan, April D. (Knoxville, TN); Paulauskas, Felix L. (Oak Ridge, TN); Fathi, Zakaryae (Cary, NC); Wei, Jianghua (Raleigh, NC)

    1998-01-01

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy.

  2. Fluid-Rock Characterization and Interactions in NMR Well Logging

    SciTech Connect (OSTI)

    Hirasaki, George J.; Mohanty, Kishore, K.

    2001-07-13

    The objective of this project is to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. This is the first annual progress report submitted to the DOE. It reports on the work completed during the reporting period even if it may have started before this period. This project is a partnership between Professor George J. Hirasaki at Rice University and Professor Kishore Mohanty at University of Houston. In addition to the DOE, this project is supported by a consortium of oil companies and service companies. The fluid properties characterization has emphasized the departure of live oils from correlations based on dead oils. Also, asphaltic components can result in a difference between the T1 and T2 relaxation time distributions as well as reduce the hydrogen index. The fluid rock characterizations that are reported here are the effects of wettability and internal magnetic field gradients. A pore reconstruction method ha s been developed to recreate three-dimensional porous media from two-dimensional images that reproduce some of their key statistical properties. A Monte Carlo simulation technique has been developed to calculate the magnetization decay in fluid saturated porous media given their pore structure.

  3. SIMULATION OF RESISTIVITY LOGGING-WHILE-DRILLING (LWD) MEASUREMENTS USING A SELF-ADAPTIVE

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    SIMULATION OF RESISTIVITY LOGGING-WHILE-DRILLING (LWD) MEASUREMENTS USING A SELF-ADAPTIVE GOAL simulate electromagnetic (EM) measurements acquired with a Logging-While- Drilling (LWD) instrument-oriented hp-adaptivity becomes essential to simulate LWD instruments, since it reduces the computational cost

  4. Annual Logging Symposium, May 14-18, 2011 RAPID MODELING OF LWD NUCLEAR MEASUREMENTS ACQUIRED

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    SPWLA 52nd Annual Logging Symposium, May 14-18, 2011 1 RAPID MODELING OF LWD NUCLEAR MEASUREMENTS Reliable interpretation of nuclear logging-while-drilling (LWD) measurements acquired in thinly-sector LWD responses in high-angle and horizontal (HA/HZ) wells. We introduce a fast method for numerical

  5. IPL-P: In-Page Logging with PCRAM Kangnyeon Kim

    E-Print Network [OSTI]

    Moon, Bongki

    of flash memory. We report a few advantages of this new design that will make IPL more suitable for flashIPL-P: In-Page Logging with PCRAM Kangnyeon Kim School of Info. & Comm. Engr. Sungkyunkwan (IPL) by augment- ing it with Phase Change RAM (PCRAM) in its log area. IPL is a buffer and storage

  6. Accelerating In-Page Logging with Non-Volatile Memory Sang-Won Lee

    E-Print Network [OSTI]

    Moon, Bongki

    memory. We report a few advantages of this new design that will make IPL more suitable for flash memory competitive in both capacity and price. In this paper, we present an improved design of In-Page Logging (IPL) by augmenting it with phase change RAM (PCRAM) in its log area. IPL is a buffer and storage man- agement

  7. MATHEMATICS AND SCIENCE CENTERS STUDENT SERVICES ACTIVITY LOG/EVENT RECORD

    E-Print Network [OSTI]

    MATHEMATICS AND SCIENCE CENTERS STUDENT SERVICES ACTIVITY LOG/EVENT RECORD Use this log for all): (Check one) ______ GENDER: RACE/ETHNICITY: ___ Mathematics ____ Female ___ Am. Indian/Alaska Native student career and college ___ Mathematics awareness in STEM fields? ___ Yes ___ No ___ Science

  8. Computing Reliability Distributions of Windowed Max-log-map (MLM) Detectors : ISI Channels

    E-Print Network [OSTI]

    Kavcic, Aleksandar

    Computing Reliability Distributions of Windowed Max-log-map (MLM) Detectors : ISI Channels Fabian-log-map (MLM) detector has well-known appli- cations to the intersymbol interefence (ISI) channel [1, · · · , is trans- mitted across the ISI channel. Let the following random This work was performed when F. Lim

  9. Discovering Block-Structured Process Models From Event Logs -A Constructive Approach

    E-Print Network [OSTI]

    van der Aalst, Wil

    Discovering Block-Structured Process Models From Event Logs - A Constructive Approach S University of Technology, P.O. Box 513, NL-5600 MB, Eindhoven, The Netherlands Abstract Process discovery is the problem of, given a log of observed behaviour, finding a process model that `best' describes

  10. Down the borehole but outside the box: innovative approaches to wireline log data interpretation

    E-Print Network [OSTI]

    Bodin, Thomas

    Down the borehole but outside the box: innovative approaches to wireline log data interpretation or more different properties, with depth down a borehole. They are routinely correlated with, and, such as oil and gas, wireline log interpretation is highly developed. In other industries, such as geothermal

  11. Adaptive Fluid Electrical Conductivity Logging to Determine the Salinity Profiles in Groundwater

    E-Print Network [OSTI]

    Quinn, Nigel

    quality data ­ existing production wells mostly used for emergency water supply · High cost of groundwater packers #12;Down-hole tool in difference flow logging (DIFF) #12;Flowing electrical conductivity logging water of constant salinity distinctly different from that of formation water). 2. Shut in well and lower

  12. P2P Logging and Timestamping for Reconciliation Mounir Tlili, W. Kokou Dedzoe,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    P2P Logging and Timestamping for Reconciliation Mounir Tlili, W. Kokou Dedzoe, Esther Pacitti-INRIA {FirstName.LastName}@loria.fr ABSTRACT In this paper, we address data reconciliation in peer-to-peer (P2P) collaborative applications. We propose P2P-LTR (Logging and Timestamping for Reconciliation) which provides P2P

  13. PROCESS MINING OF EVENT LOGS IN AUDITING: OPPORTUNITIES AND Hasselt University

    E-Print Network [OSTI]

    1 PROCESS MINING OF EVENT LOGS IN AUDITING: OPPORTUNITIES AND CHALLENGES Mieke Jans Hasselt 15, 20101 1 Comments are welcome and may be addressed to mieke.jans@uhasselt.be. #12;2 PROCESS MINING that process mining of event logs can provide to internal and external auditors. Process mining aims to extract

  14. Discovering Structured Event Logs from Unstructured Audit Trails for Workflow Mining

    E-Print Network [OSTI]

    Discovering Structured Event Logs from Unstructured Audit Trails for Workflow Mining Liqiang Geng1@ucalgary.ca, {larry.korba, hongyu.liu, yunlin.wang}@nrc.gc.ca Abstract. Workflow mining aims to find graph workflow mining techniques mainly deal with well-structured and -symbolized event logs. In most real

  15. THE EXTENT AND CAUSES OF ILLEGAL LOGGING: AN ANALYSIS OF A MAJOR CAUSE OF TROPICAL

    E-Print Network [OSTI]

    THE EXTENT AND CAUSES OF ILLEGAL LOGGING: AN ANALYSIS OF A MAJOR CAUSE OF TROPICAL DEFORESTATION;2 THE EXTENT AND CAUSES OF ILLEGAL LOGGING: AN ANALYSIS OF A MAJOR CAUSE OF TROPICAL DEFORESTATION IN INDONESIA (CIFOR). ISSN 0967-8875 #12;3 Abstract: This paper considers the scale and underlying causes of recent

  16. Measuring the Effect of Selective Logging on Tropical Forest-Atmosphere Exchange

    E-Print Network [OSTI]

    Goulden, Michael L.

    and low impact extraction methods 1. Conventional Selective Logging: ·Large percent of canopy/soil can takes advantage of newly available PAR. · Reduced Impact Logging and/or Light Harvest resulted in little disturbance. · These are dry season data - chambers indicate decomposition is water limited. POSSIBLE

  17. Reservoir parameters estimation from well log and core data: a case study from the North Sea

    E-Print Network [OSTI]

    Edinburgh, University of

    Reservoir parameters estimation from well log and core data: a case study from the North Sea Jun approach to derive reservoir parameters from core and well-log data in clay­sand mixtures. This method volume, clay content, permeability and fluid saturation. This information is then fed into a velocity

  18. Annual Logging Symposium, June 19-23, 2010 JOINT PROCESSING OF FORWARD AND BACKWARD EXTENDED

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    Copyright 2010, held jointly by the Society of Petrophysicists and Well Log Analysts (SPWLA) and the submitting authors. This paper was prepared for presentation at the SPWLA 51st Annual Logging Symposium held the assessment of drilling-induced formation damage because it associates high- and low-frequency slownesses

  19. human_subjects_payment_log_less_fifty.docx LAST UPDATED: March 16, 2012 Financial Operations Office

    E-Print Network [OSTI]

    Yu, Gexin

    human_subjects_payment_log_less_fifty.docx LAST UPDATED: March 16, 2012 Financial Operations and Mary Human Subject Payment Log (HSPL) (Use when payment to human subject(s) is $50 or less) RELATED POLICY: Paying Human Subjects for Research Studies The College of William and Mary (the College

  20. Integration of Geology, Rock-Physics, Logs, and Pre-stack Seismic for Reservoir Porosity Estimation

    E-Print Network [OSTI]

    Al Muhaidib, Abdulaziz

    2011-01-01

    The main objective of this paper is to obtain reservoir properties, such as porosity, both at the well locations and in the inter-well regions from seismic data and well logs. The seismic and well-log datasets are from an ...

  1. Annual Logging Symposium, June 19-23, 2010 QUANTITATIVE INTERPRETATION OF PULSED NEUTRON

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    for shoulder-bed effects on PNC logs acquired in sand- shale laminated reservoirs. Due to diffusion effects the sigma responses of pure-sand and pure-shale end members of the sedimentary sequence. We introduce a new measurements. The extension of time-lapse logging in waterflooded reservoirs is the estimation of waterflood

  2. Android Diabetes Log Book E-mail: kongkamol@kku.ac.th

    E-Print Network [OSTI]

    Runapongsa, Kanda

    Android Diabetes Log Book 1 2 3 1 . . 40002 2, 3 . . 40002 E-mail: kongkamol@kku.ac.th Abstract. Generally, the patients record their health conditions in patients' log book. An android application had. Keywords: android application, diabetes 4.07 5.00 , 1. 285 . . 2573 435 . . 2552 558,156 7,019 [1] 15 7% [2

  3. Detection of electrophilic and nucleophilic chemical agents

    DOE Patents [OSTI]

    McElhanon, James R.; Shepodd, Timothy J.

    2014-08-12

    A "real time" method for detecting chemical agents generally and particularly electrophilic and nucleophilic species by employing tunable, precursor sensor materials that mimic the physiological interaction of these agents to form highly florescent berberine-type alkaloids that can be easily and rapidly detected. These novel precursor sensor materials can be tuned for reaction with both electrophilic (chemical species, toxins) and nucleophilic (proteins and other biological molecules) species. By bonding or otherwise attaching these precursor molecules to a surface or substrate they can be used in numerous applications.

  4. Coal-log pipeline system development. Fifth quarterly report, August 25, 1991--November 25, 1991

    SciTech Connect (OSTI)

    Liu, H.

    1991-12-01

    Project tasks include: (1) Perform the necessary testing and development to demonstrate that the amount of binder in coal logs can be reduced to 8% or lower to produce logs with adequate strength to eliminate breakage during pipeline transportation, under conditions experienced in long distance pipeline systems. Prior to conducting any testing and demonstration, grantee shall perform an information search and make full determination of all previous attempts to extrude or briquette coal, upon which the testing and demonstration shall be based. (2) Perform the necessary development to demonstrate a small model of the most promising injection system for coal-logs, and tests the logs produced. (3) Conduct economic analysis of coal-log pipeline, based upon the work to date. Refine and complete the economic model. (VC)

  5. Quantum Matter-Photonics Framework: Analyses of Chemical Conversion Processes

    E-Print Network [OSTI]

    O. Tapia

    2014-10-29

    A quantum Matter-Photonics framework is adapted to help scrutinize chemical reaction mechanisms and used to explore a process mapped from chemical tree topological model. The chemical concept of bond knitting/breaking is reformulated via partitioned base sets leading to an abstract and general quantum presentation. Pivotal roles are assigned to entanglement, coherence,de-coherence and Feshbach resonance quantum states that permit apprehend gating states in conversion processes. A view from above in the state energy eigenvalue ladder, belonging to full system spectra complement the standard view from ground state. A full quantum physical view supporting chemical change obtains.

  6. Fluorinated diamond bonded in fluorocarbon resin

    DOE Patents [OSTI]

    Taylor, Gene W. (Los Alamos, NM)

    1982-01-01

    By fluorinating diamond grit, the grit may be readily bonded into a fluorocarbon resin matrix. The matrix is formed by simple hot pressing techniques. Diamond grinding wheels may advantageously be manufactured using such a matrix. Teflon fluorocarbon resins are particularly well suited for using in forming the matrix.

  7. Various Carbon to Carbon Bond Lengths Inter-related via the Golden Ratio, and their Linear Dependence on Bond Energies

    E-Print Network [OSTI]

    Raji Heyrovska

    2008-09-11

    This work presents the relations between the carbon to carbon bond lengths in the single, double and triple bonds and in graphite, butadiene and benzene. The Golden ratio, which was shown to divide the Bohr radius into two parts pertaining to the charged particles, the electron and proton, and to divide inter-atomic distances into their cationic and anionic radii, also plays a role in the carbon-carbon bonds and in the ionic/polar character of those in graphite, butadiene and benzene. Further, the bond energies of the various CC bonds are shown to vary linearly with the bond lengths.

  8. Chemical Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of raregovAboutRecoveryplanning CareerNationalCNMSTHEmaterials |Chemical

  9. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time-Resolved Study of Bonding in Liquid Carbon Time-Resolved Study of Bonding in Liquid Carbon Print Wednesday, 28 September 2005 00:00 We are accustomed to observing carbon in...

  10. FUNDAMENTALS OF WETTING AND BONDING BETWEEN CERAMICS AND METALS

    E-Print Network [OSTI]

    Pask, J.A.

    2010-01-01

    WETTING AND BONDING BETWEEN CERAMICS AND METALS Jo s eph A.OF WETTING AND BONDING BETWEEN CERAMICS AND METALS Joseph A.and glass-to-metal or ceramic-to-metal seals. Both physical

  11. FITCH RATES ENERGY NORTHWEST, WA'S ELECTRIC REV RFDG BONDS 'AA...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FITCH RATES ENERGY NORTHWEST, WA'S ELECTRIC REV RFDG BONDS 'AA'; OUTLOOK STABLE Fitch Ratings-Austin-22 September 2015: Fitch Ratings assigns its 'AA' rating to the following bonds...

  12. A deep high-resolution optical log of dust, ash, and stratigraphy in South Pole glacial ice

    E-Print Network [OSTI]

    Woschnagg, Kurt

    A deep high-resolution optical log of dust, ash, and stratigraphy in South Pole glacial ice N. E (2005), A deep high-resolution optical log of dust, ash, and stratigraphy in South Pole glacial ice

  13. 22 September 2000 Z .Chemical Physics Letters 328 2000 197202

    E-Print Network [OSTI]

    Ashworth, Stephen H.

    22 September 2000 Z .Chemical Physics Letters 328 2000 197­202 www.elsevier.nlrlocatercplett Sub BS8 1TS, UK Received 4 July 2000; in final form 2 August 2000 Abstract A preliminary version with a discussion of the bonding in PF as revealed by the hyperfine constants. q 2000 Elsevier Science B.V. All

  14. Computational Study of Bond Dissociation Enthalpies for Substituted $\\beta$-O-4 Lignin Model Compounds

    SciTech Connect (OSTI)

    Younker, Jarod M; Beste, Ariana; Buchanan III, A C

    2011-01-01

    The biopolymer lignin is a potential source of valuable chemicals. Phenethyl phenyl ether (PPE) is representative of the dominant $\\beta$-O-4 ether linkage. Density functional theory (DFT) is used to calculate the Boltzmann-weighted carbon-oxygen and carbon-carbon bond dissociation enthalpies (BDEs) of substituted PPE. These values are important in order to understand lignin decomposition. Exclusion of all conformers that have distributions of less than 5\\% at 298 K impacts the BDE by less than 1 kcal mol$^{-1}$. We find that aliphatic hydroxyl/methylhydroxyl substituents introduce only small changes to the BDEs (0-3 kcal mol$^{-1}$). Substitution on the phenyl ring at the $ortho$ position substantially lowers the C-O BDE, except in combination with the hydroxyl/methylhydroxyl substituents, where the effect of methoxy substitution is reduced by hydrogen bonding. Hydrogen bonding between the aliphatic substituents and the ether oxygen in the PPE derivatives has a significant influence on the BDE. CCSD(T)-calculated BDEs and hydrogen bond strengths of $ortho$-substituted anisoles when compared with M06-2X values confirm that the latter method is sufficient to describe the molecules studied and provide an important benchmark for lignin model compounds.

  15. Identifying Complex Fluvial Sandstone Reservoirs Using Core, Well Log, and 3D Seismic Data: Cretaceous Cedar Mountain and Dakota Formations,

    E-Print Network [OSTI]

    Seamons, Kent E.

    core, well-log, and 3D seismic data. The detailed stratigraphy and sedimentology of the interval were

  16. Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang*

    E-Print Network [OSTI]

    Caflisch, Amedeo

    Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang* Department of Biochemistry, University of Zurich, Zurich, Switzerland Abstract Ligand binding involves breakage of hydrogen bonds with water molecules and formation of new hydrogen bonds between protein and ligand. In this work, the change

  17. Hydrogen Bond Networks in Graphene Oxide Composite Paper: Structure and

    E-Print Network [OSTI]

    Hydrogen Bond Networks in Graphene Oxide Composite Paper: Structure and Mechanical Properties of hydrogen bonds mediated by oxygen-containing functional groups and water molecules. A quantitative analysis of the formation of hydrogen bond networks further shows that they play a central role in *Address correspondence

  18. Hydrogen bonds in liquid water are broken only fleetingly

    E-Print Network [OSTI]

    Geissler, Phillip

    Hydrogen bonds in liquid water are broken only fleetingly J. D. Eaves* , J. J. Loparo* , C. J that the local structure of liquid water has tetrahedral arrangements of molecules ordered by hydrogen bonds, the mechanism by which water molecules switch hydrogen-bonded partners remains unclear. In this mechanism

  19. Hydrogen bonding in benzonitrilewater complexes Eugene S. Kryachkoa)

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    Hydrogen bonding in benzonitrile­water complexes Eugene S. Kryachkoa) and Minh Tho Nguyenb January 2001; accepted 23 March 2001 The hydrogen bonding between benzonitrile and one and two water,p and aug-cc-pVDZ basis sets. The strength of such hydrogen bonding is analyzed in terms of a magnitude

  20. Analysis of C H...O hydrogen bonds

    E-Print Network [OSTI]

    Babu, M. Madan

    1 Analysis of C H...O hydrogen bonds in high resolution protein crystal structures from the PDB 1.4 Identification of C-H...O hydrogen bonds............................................. 1.4.1 The definition of a C-H...O hydrogen bond.................................... 1.4.2 Fixing the hydrogen and measuring the parameters

  1. Oil prices and government bond risk premiums Herv Alexandre*

    E-Print Network [OSTI]

    Boyer, Edmond

    Oil prices and government bond risk premiums By Hervé Alexandre*º Antonin de Benoist * Abstract : This article analyses the impact of oil price on bond risk premiums issued by emerging economies. No empirical study has yet focussed on the effects of the oil price on government bond risk premiums. We develop

  2. Article coated with flash bonded superhydrophobic particles

    DOE Patents [OSTI]

    Simpson, John T (Clinton, TN) [Clinton, TN; Blue, Craig A (Knoxville, TN) [Knoxville, TN; Kiggans, Jr., James O [Oak Ridge, TN

    2010-07-13

    A method of making article having a superhydrophobic surface includes: providing a solid body defining at least one surface; applying to the surface a plurality of diatomaceous earth particles and/or particles characterized by particle sizes ranging from at least 100 nm to about 10 .mu.m, the particles being further characterized by a plurality of nanopores, wherein at least some of the nanopores provide flow through porosity, the particles being further characterized by a plurality of spaced apart nanostructured features that include a contiguous, protrusive material; flash bonding the particles to the surface so that the particles are adherently bonded to the surface; and applying a hydrophobic coating layer to the surface and the particles so that the hydrophobic coating layer conforms to the nanostructured features.

  3. Public Bonding Options | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7, 2011 | DepartmentFunds for Renewables andBonding

  4. Microchannel cooling of face down bonded chips

    DOE Patents [OSTI]

    Bernhardt, A.F.

    1993-06-08

    Microchannel cooling is applied to flip-chip bonded integrated circuits, in a manner which maintains the advantages of flip-chip bonds, while overcoming the difficulties encountered in cooling the chips. The technique is suited to either multi chip integrated circuit boards in a plane, or to stacks of circuit boards in a three dimensional interconnect structure. Integrated circuit chips are mounted on a circuit board using flip-chip or control collapse bonds. A microchannel structure is essentially permanently coupled with the back of the chip. A coolant delivery manifold delivers coolant to the microchannel structure, and a seal consisting of a compressible elastomer is provided between the coolant delivery manifold and the microchannel structure. The integrated circuit chip and microchannel structure are connected together to form a replaceable integrated circuit module which can be easily decoupled from the coolant delivery manifold and the circuit board. The coolant supply manifolds may be disposed between the circuit boards in a stack and coupled to supplies of coolant through a side of the stack.

  5. Femtosecond Chemically Activated Reactions: Concept of Nonstatistical Activation at High Thermal Energies

    E-Print Network [OSTI]

    Kim, Sang Kyu

    Femtosecond Chemically Activated Reactions: Concept of Nonstatistical Activation at High Thermal Femtosecond chemical activation of reactions at very high thermal energies, much above the bond energy activation, collision-free, and temporally and spatially defined. Introduction Since the work in the 1920s

  6. Chemical Accelerators The phrase "chemical accelerators"

    E-Print Network [OSTI]

    Meetings Chemical Accelerators The phrase "chemical accelerators" is scarcely older than for one or two dozen people grew to include nearly a hundred. Chemical accelerators is a name sug- gested by one of us for devices that produce beams of chemically interesting species at relative kinetic

  7. In cooperation with the University of Waterloo, Canada Application of Advanced Geophysical Logging Methods

    E-Print Network [OSTI]

    Singha, Kamini

    .S. Geological Survey #12;2 Figure 1. Location of Rocketdyne Santa Susana Field Laboratory and logged boreholes sandstone and mudstone at the Rocketdyne Santa Susana Field ,, in southern Ventura County, California (fig

  8. A comparison of logging while drilling (LWD) and wireline acoustic measurements

    E-Print Network [OSTI]

    Briggs, Victoria Alice, 1974-

    2006-01-01

    The instruments used to measure borehole acoustic data can be classified as either wireline or logging while drilling (LWD). The wireline tool measures formation speeds after the borehole is drilled, and the LWD tool ...

  9. Elimination of LWD (Logging-While-Drilling) Tool Modes Using Seismoelectric Data

    E-Print Network [OSTI]

    Zhan, Xin

    2006-01-01

    Borehole acoustic logging-while-drilling (LWD) for formation evaluation has become an indispensable part of hydrocarbon reservoir assessment (Tang et al., 2002; Cittá et al., 2004; Esmersoy et al., 2005). However, the ...

  10. A TALE OF TWO (SIMILAR) CITIES: Inferring City Similarity Through Geo-Spatial Query Log Analysis

    E-Print Network [OSTI]

    Cortes, Corinna

    a variety of more in-depth information about households. Advertisers often use the high-level information in the US. In contrast to the Census studies, passive studies of search engine query logs have become common

  11. Integrating User Feedback Log into Relevance Feedback by Coupled SVM for Content-Based Image Retrieval

    E-Print Network [OSTI]

    Lyu, Michael R.

    , the user feedback log is one of the most important resources to bridge the seman- tic gap problem in image to re- peat many rounds of feedback in order to achieve satisfac- tory results. Hence, the learning task

  12. Formation evaluation using wavelet analysis on logs of the Chinji and Nagri Formations, northern Pakistan 

    E-Print Network [OSTI]

    Tanyel, Emre Doruk

    2006-10-30

    The relatively new method of using wavelets in well log analysis is a powerful tool for defining multiple superimposed scales of lithic trends and contacts. Interpreting depositional processes associated with different scales of vertical variation...

  13. Navigation to Important information on Raiderlink/Webraider Portal: Log into Raiderlink/WebRaider Portal

    E-Print Network [OSTI]

    Rock, Chris

    Navigation to Important information on Raiderlink/Webraider Portal: Log into Raiderlink/WebRaider Portal: TTU and TTUSA employees: http://raiderlink.ttu.edu: HSC: http://webraider.ttuhsc.edu: Select TTU

  14. Sonic Logging in Deviated Boreholes in an Anisotropic Formation: Laboratory Study

    E-Print Network [OSTI]

    Zhu, Zhenya

    2006-01-01

    Deepwater field development requires drilling of deviated or horizontal wells. Most formations encountered can be highly anisotropic and P- and S-wave velocities vary with propagation directions. Sonic logs acquired in ...

  15. Temperatures and Natural Gamma-Ray Logs Obtained in 1986 from...

    Open Energy Info (EERE)

    and following drilling and possibly to ground shaking associated with present and past seismic activity in the Long Valley region.Natural gamma-ray logs obtained on four...

  16. High-energy photon transport modeling for oil-well logging

    E-Print Network [OSTI]

    Johnson, Erik D., Ph. D. Massachusetts Institute of Technology

    2009-01-01

    Nuclear oil well logging tools utilizing radioisotope sources of photons are used ubiquitously in oilfields throughout the world. Because of safety and security concerns, there is renewed interest in shifting to ...

  17. FrogLog 21 (3), Number 107 (July 2013) | 1 Survival Alliance

    E-Print Network [OSTI]

    Andreone, Franco

    FrogLog 21 (3), Number 107 (July 2013) | 1 Amphibian Survival Alliance Website Urban Amphibians and The Environment. Plant nursery and water quality Fifteen hundred essential oil plants belonging to the species

  18. Annual Logging Symposium, May 14-18, 2011 QUANTIFYING WETTABILITY ALTERATION DURING OIL-BASE

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    by the Society of Petrophysicists and Well Log Analysts (SPWLA) and the submitting authors. This paper and efficiency of drilling, reduce borehole washouts, achieve better borehole control, and minimize the swelling

  19. Precise inversion of logged slownesses for elastic parameters in a gas shale formation

    E-Print Network [OSTI]

    Miller, Douglas E.

    Dipole sonic log data recorded in a vertical pilot well and the associated production well are analyzed over a 200×1100-ft section of a North American gas shale formation. The combination of these two wells enables angular ...

  20. Technical memorandum on analysis of the EU ETS using the community independent transaction log

    E-Print Network [OSTI]

    McGuinness, Meghan

    2007-01-01

    This memorandum provides an overview of three deficiencies within the current presentation of the Community Independent Transaction Log (CITL) data that have implications for researchers' ability to accurately analyze the ...

  1. Field Test of a Low-Frequency Sparker Source for Acoustic Waveform Logging

    E-Print Network [OSTI]

    Paillet, Frederick L.

    1984-01-01

    Low-frequency acoustic-energy sources for waveform logging have important applications in: 1) Verifying theoretical calculations; 2) generating tube waves in large-diameter boreholes; and 3) providing larger sample volumes ...

  2. Full Waveform Acoustic Logging - Where We Are, Where We Are Going

    E-Print Network [OSTI]

    Toksoz, M. Nafi

    1984-01-01

    We have now completed the second year of the Full Waveform Acoustic Logging Consortium. During these two years, we have developed a good understanding of seismic wave propagation in a borehole through both theoretical ...

  3. Reduced impact logging minimally alters tropical rainforest carbon and energy exchange

    E-Print Network [OSTI]

    2011-01-01

    Brazil | Amazon | land use | micrometeorology D eforestation in the tropics affects the land–atmosphere ex- change of trace gases and energyand energy (W·m ?2 ) ?uxes, calculated as (? = logged ? unlogged), in Tapajos National Forest, Para, Brazil.

  4. deep highresolution optical log dust, ash, and stratigraphy South Pole glacial

    E-Print Network [OSTI]

    Woschnagg, Kurt

    deep high­resolution optical log dust, ash, and stratigraphy South Pole glacial Bramall, Bay, Rohde, Price (2005), high­resolution optical dust, stratigraphy South Pole glacial Geophys. Res. Lett

  5. Transport coefficients in high temperature gauge theories: (I) Leading-log results

    E-Print Network [OSTI]

    Peter Arnold; Guy D. Moore; Laurence G. Yaffe

    2000-10-16

    Leading-log results are derived for the shear viscosity, electrical conductivity, and flavor diffusion constants in both Abelian and non-Abelian high temperature gauge theories with various matter field content.

  6. Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch K. J. Gaffney, I. R. Piletic, and M. D. Fayer* Department measured with ultrafast infrared pump-probe experiments. Non-hydrogen-bond donating OD stretches (2690 cm-1

  7. Results of investigations at the Zunil geothermal field, Guatemala: Well logging and brine geochemistry

    SciTech Connect (OSTI)

    Adams, A.; Dennis, B.; Van Eeckhout, E.; Goff, F.; Lawton, R.; Trujillo, P.E.; Counce, D.; Archuleta, J. (Los Alamos National Lab., NM (USA)); Medina, V. (Instituto Nacional de Electrificacion, Guatemala City (Guatemala). Unidad de Desarollo Geotermico)

    1991-07-01

    The well logging team from Los Alamos and its counterpart from Central America were tasked to investigate the condition of four producing geothermal wells in the Zunil Geothermal Field. The information obtained would be used to help evaluate the Zunil geothermal reservoir in terms of possible additional drilling and future power plant design. The field activities focused on downhole measurements in four production wells (ZCQ-3, ZCQ-4, ZCQ-5, and ZCQ-6). The teams took measurements of the wells in both static (shut-in) and flowing conditions, using the high-temperature well logging tools developed at Los Alamos National Laboratory. Two well logging missions were conducted in the Zunil field. In October 1988 measurements were made in well ZCQ-3, ZCQ-5, and ZCQ-6. In December 1989 the second field operation logged ZCQ-4 and repeated logs in ZCQ-3. Both field operations included not only well logging but the collecting of numerous fluid samples from both thermal and nonthermal waters. 18 refs., 22 figs., 7 tabs.

  8. Method for bonding a transmission line to a downhole tool

    DOE Patents [OSTI]

    Hall, David R. (Provo, UT); Fox, Joe (Spanish Fork, UT)

    2007-11-06

    An apparatus for bonding a transmission line to the central bore of a downhole tool includes a pre-formed interface for bonding a transmission line to the inside diameter of a downhole tool. The pre-formed interface includes a first surface that substantially conforms to the outside contour of a transmission line and a second surface that substantially conforms to the inside diameter of a downhole tool. In another aspect of the invention, a method for bonding a transmission line to the inside diameter of a downhole tool includes positioning a transmission line near the inside wall of a downhole tool and placing a mold near the transmission line and the inside wall. The method further includes injecting a bonding material into the mold and curing the bonding material such that the bonding material bonds the transmission line to the inside wall.

  9. 1/19/2015 Nanoscale NMR Advances | Chemical & Engineering News http://cen.acs.org.ezpprod1.hul.harvard.edu/articles/93/i2/NanoscaleNMRAdvances.html 1/2

    E-Print Network [OSTI]

    Walsworth, Ronald L.

    1/19/2015 Nanoscale NMR Advances | Chemical & Engineering News http://cen.acs.org.ezpprod1.hul nuclear species in a region measuring 50 µm2. Chemical & Engineering News ISSN 00092347 Copyright © 2015.harvard.edu/articles/93/i2/NanoscaleNMRAdvances.html 1/2 CASC&ENACS PublicationsACS Log In Serving The Chemical, Life

  10. Repairable chip bonding/interconnect process

    DOE Patents [OSTI]

    Bernhardt, Anthony F. (Berkeley, CA); Contolini, Robert J. (Livermore, CA); Malba, Vincent (Livermore, CA); Riddle, Robert A. (Tracy, CA)

    1997-01-01

    A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder.

  11. Repairable chip bonding/interconnect process

    DOE Patents [OSTI]

    Bernhardt, A.F.; Contolini, R.J.; Malba, V.; Riddle, R.A.

    1997-08-05

    A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules is disclosed. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder. 10 figs.

  12. Covalent Bonding in Actinide Sandwich Molecules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding in Actinide Sandwich Molecules Print Glenn Seaborg was one

  13. Covalent Bonding in Actinide Sandwich Molecules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding in Actinide Sandwich Molecules Print Glenn Seaborg was

  14. Bonded Compliant Seal (BCS) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download52015 |Bonded

  15. State Bond Program | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS ReportEurope GmbHSoloPage EditStamford,Energy CenterStateState Bond

  16. Bio-butanol: Combustion properties and detailed chemical kinetic model

    SciTech Connect (OSTI)

    Black, G.; Curran, H.J.; Pichon, S.; Simmie, J.M.; Zhukov, V.

    2010-02-15

    Autoignition delay time measurements were performed at equivalence ratios of 0.5, 1 and 2 for butan-1-ol at reflected shock pressures of 1, 2.6 and 8 atm at temperatures from 1100 to 1800 K. High-level ab initio calculations were used to determine enthalpies of formation and consequently bond dissociation energies for each bond in the alcohol. A detailed chemical kinetic model consisting of 1399 reactions involving 234 species was constructed and tested against the delay times and also against recent jet-stirred reactor speciation data with encouraging results. The importance of enol chemistry is highlighted. (author)

  17. CHEMICAL ENGINEERING Curriculum Notes

    E-Print Network [OSTI]

    Mohan, Chilukuri K.

    CHEMICAL ENGINEERING Curriculum Notes 2013-2014 1. Chemical engineering students must complete not included in the required chemical engineering curriculum. All technical electives are subject to approval be in chemical engineering. 2. Chemical engineering students must complete a minimum of 18 credits in the Social

  18. X-ray Photoelectron Spectroscopy study of the compatibility of the explosive PETN with candidate plastic bonding materials

    SciTech Connect (OSTI)

    Vannet, M.D.; Wang, P.S.; Moddeman, W.E.; Bowling, W.C.

    1985-01-01

    The compatibility of the explosive PETN with two plastic bonding materials, ethyl cellulose and a halogenated vinyl polymer (FPC 461), was determined by X-ray Photoelectron Spectroscopy (XPS). Both were found to coat the PETN crystals, and no change in chemical composition was found in the PETN or the plastic due to either the process or their mutual presence. 3 refs., 1 fig., 1 tab.

  19. Response transforms from comparative study of commercial pulsed-neutron-capture logging systems

    SciTech Connect (OSTI)

    Salaita, G.N. (Chevron Oil Field Research Co., La Habra, CA (United States))

    1992-09-01

    This paper reports that three generations of Schlumberger's Thermal Decay Time (TDT{sup SM}) logging devices - viz., TDT-K, TDT-M, and TDT-P - along with an Atlas Wireline PDK-100{sup SM} system were run in a Saudi Aramco well. The wellbore (8 1/2 in. with 7-in. casing) penetrated a sequence of clean sand, shaly sand, and shale streaks as exhibited by the openhole natural gamma ray log. The initial wellbore fluid was diesel. The fluid was then changed to brines of 42,000 and 176,000 ppm NaCl, respectively. Three repeat passes at a logging speed of 900 ft/hr were obtained by each device for each borehole liquid. As a result of this extensive comparative study, a set of departure curves and mathematical transforms was developed primarily for standardizing the various Schlumberger tools to a common reference logging system and/or borehole environment. The transforms were used beneficially to determine residual oil saturation (ROS) from time-lapse logs in a Saudi Aramco reservoir.

  20. Laser induced chemical reactions

    E-Print Network [OSTI]

    Orel, Ann E.

    2010-01-01

    the simplest prototype chemical reaction, and since it is soLASER ENHANCEMENT OF CHEMICAL REACTIONS A. B. C. D. E.Laser Inhibition of Chemical Reaction Effect of Isotopic

  1. Microfluidic chemical reaction circuits

    DOE Patents [OSTI]

    Lee, Chung-cheng (Irvine, CA); Sui, Guodong (Los Angeles, CA); Elizarov, Arkadij (Valley Village, CA); Kolb, Hartmuth C. (Playa del Rey, CA); Huang, Jiang (San Jose, CA); Heath, James R. (South Pasadena, CA); Phelps, Michael E. (Los Angeles, CA); Quake, Stephen R. (Stanford, CA); Tseng, Hsian-rong (Los Angeles, CA); Wyatt, Paul (Tipperary, IE); Daridon, Antoine (Mont-Sur-Rolle, CH)

    2012-06-26

    New microfluidic devices, useful for carrying out chemical reactions, are provided. The devices are adapted for on-chip solvent exchange, chemical processes requiring multiple chemical reactions, and rapid concentration of reagents.

  2. Sandia Energy - Chemical Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Dynamics Home Transportation Energy Predictive Simulation of Engines Combustion Chemistry Chemical Dynamics Chemical DynamicsAshley Otero2015-10-28T02:45:37+00:00...

  3. NMR chemical shifts in amino acids: Effects of environments, electric field, and amine group rotation

    SciTech Connect (OSTI)

    Yoon, Young-Gui; Pfrommer, Bernd G.; Louie, Steven G.; Canning, Andrew

    2002-03-03

    The authors present calculations of NMR chemical shifts in crystalline phases of some representative amino acids such as glycine, alanine, and alanyl-alanine. To get an insight on how different environments affect the chemical shifts, they study the transition from the crystalline phase to completely isolated molecules of glycine. In the crystalline limit, the shifts are dominated by intermolecular hydrogen-bonds. In the molecular limit, however, dipole electric field effects dominate the behavior of the chemical shifts. They show that it is necessary to average the chemical shifts in glycine over geometries. Tensor components are analyzed to get the angle dependent proton chemical shifts, which is a more refined characterization method.

  4. ITP Chemicals: Chemical Industry of the Future: New Biocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemical Industry of the Future: New Biocatalysts: Essential Tools for a Sustainable 21st Century Chemical Industry ITP Chemicals: Chemical Industry of the Future: New...

  5. Institute of Chemical Engineering and High Temperature Chemical...

    Open Energy Info (EERE)

    Institute of Chemical Engineering and High Temperature Chemical Processes ICEHT Jump to: navigation, search Name: Institute of Chemical Engineering and High Temperature Chemical...

  6. Municipal Bond - Power Purchase Agreement Model Continues to...

    Broader source: Energy.gov (indexed) [DOE]

    power purchase agreement model to provide low-cost solar energy. Author: National Renewable Energy Laboratory Municipal Bond - Power Purchase Agreement Model Continues to Provide...

  7. Qualified Energy Conservation Bond (QECB) Update: New Guidance...

    Office of Environmental Management (EM)

    clarification of what constitutes a qualified project for potential issuers of qualified energy conservation bond capacity. Author: Lawrence Berkeley National Laboratory Qualified...

  8. Qualified Energy Conservation Bonds (ŤQECBs?) & New Clean Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conservation Bonds (QECBs) may be issued by state, local and tribal governments to finance qualified energy conservation projects. A minimum of 70% of a state's allocation must...

  9. Douglas County School District (Nevada) Bonds Case Study | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bonds Case Study Douglas County School District faced a challenging combination of aging equipment and buildings (most over 37 years old), rising energy costs, and limited...

  10. Chemical Industry Corrosion Management

    SciTech Connect (OSTI)

    2003-02-01

    Improved Corrosion Management Could Provide Significant Cost and Energy Savings for the Chemical Industry. In the chemical industry, corrosion is often responsible for significant shutdown and maintenance costs.

  11. Enhanced Chemical Cleaning

    Office of Environmental Management (EM)

    Enhanced Chemical Cleaning Renee H. Spires Enhanced Chemical Cleaning Project Manager July 29, 2009 Tank Waste Corporate Board 2 Objective Provide an overview of the ECC process...

  12. Filtrations in Dyson-Schwinger equations: next-to^{j} -leading log expansions systematically

    E-Print Network [OSTI]

    Olaf Krueger; Dirk Kreimer

    2015-02-11

    Dyson-Schwinger equations determine the Green functions $G^r(\\alpha,L)$ in quantum field theory. Their solutions are triangular series in a coupling constant $\\alpha$ and an external scale parameter $L$ for a chosen amplitude $r$, with the order in $L$ bounded by the order in the coupling. Perturbation theory calculates the first few orders in $\\alpha$. On the other hand, Dyson--Schwinger equations determine next-to$^{\\{\\mathrm{j}\\}}$-leading log expansions, $G^r(\\alpha,L) = 1 + \\sum_{j=0}^\\infty \\sum_{\\mathcal{M}} p_j^{\\mathcal{M}}\\alpha^j \\mathcal{M}(u)$. $\\sum_{\\mathcal{M}}$ sums a finite number of functions $\\mathcal{M}$ in $u = \\alpha L/2$. The leading logs come from the trivial representation $\\mathcal{M}(u) = \\begin{bsmallmatrix}\\bullet\\end{bsmallmatrix}(u)$ at $j=0$ with $p_0^{\\begin{bsmallmatrix}\\bullet\\end{bsmallmatrix}} = 1$. All non-leading logs are organized by the suppression in powers $\\alpha^j$. We describe an algebraic method to derive all next-to$^{\\{\\mathrm{j}\\}}$-leading log terms from the knowledge of the first $(j+1)$ terms in perturbation theory and their filtrations. This implies the calculation of the functions $\\mathcal{M}(u)$ and periods $p_j^\\mathcal{M}$. In the first part of our paper, we investigate the structure of Dyson-Schwinger equations and develop a method to filter their solutions. Applying renormalized Feynman rules maps each filtered term to a certain power of $\\alpha$ and $L$ in the log-expansion. Based on this, the second part derives the next-to$^{\\{\\mathrm{j}\\}}$-leading log expansions. Our method is general. Here, we exemplify it using the examples of the propagator in Yukawa theory and the photon self-energy in quantum electrodynamics. The reader may apply our method to any (set of) Dyson-Schwinger equation(s) appearing in renormalizable quantum field theories.

  13. Method of bonding single crystal quartz by field-assisted bonding

    DOE Patents [OSTI]

    Curlee, R.M.; Tuthill, C.D.; Watkins, R.D.

    1991-04-23

    The method of producing a hermetic stable structural bond between quartz crystals includes providing first and second quartz crystals and depositing thin films of borosilicate glass and silicon on portions of the first and second crystals, respectively. The portions of the first and second crystals are then juxtaposed in a surface contact relationship and heated to a temperature for a period sufficient to cause the glass and silicon films to become electrically conductive. An electrical potential is then applied across the first and second crystals for creating an electrostatic field between the adjoining surfaces and causing the juxtaposed portions to be attracted into an intimate contact and form a bond for joining the adjoining surfaces of the crystals. 2 figures.

  14. Chemical Management Contacts

    Broader source: Energy.gov [DOE]

    Contacts for additional information on Chemical Management and brief description on Energy Facility Contractors Group

  15. Polymers for Chemical Sensors Using Hydrosilylation Chemistry

    SciTech Connect (OSTI)

    Grate, Jay W.; Kaganove, Steven N.; Nelson, David A.

    2001-06-28

    Sorbent and functionalized polymers play a key role in a diverse set of fields, including chemical sensors, separation membranes, solid phase extraction techniques, and chromatography. Sorbent polymers are critical to a number of sensor array or "electronic nose" systems. The responses of the sensors in the array give rise to patterns that can be used to distinguish one compound from another, provided that a sufficiently diverse set of sensing materials is present in the array. Figure 1 illustrates the concept of several sensors, each with a different sensor coating, giving rise to variable responses to an analyte that appear as a pattern in bar graph format. Using hydrosilylation as the bond-forming reaction, we have developed a versatile and efficient approach to developing sorbent polymers with diverse interactive properties for sensor applications. Both the chemical and physical properties of these polymers are predictable and tunable by design.

  16. Flip chip electrical interconnection by selective electroplating and bonding

    E-Print Network [OSTI]

    Lin, Liwei

    Flip chip electrical interconnection by selective electroplating and bonding L.-W. Pan, P. Yuen, L resistance of the electroplating bond is 12 W. This process has potential applications in replacing-step approach for high-density electrical in- terconnection by using flip chip selective electroplating

  17. Quantum Finance Hamiltonian for Coupon Bond European and Barrier Options

    E-Print Network [OSTI]

    Chaudhuri, Sanjay

    Quantum Finance Hamiltonian for Coupon Bond European and Barrier Options Belal E. Baaquie RMI are financial derivatives that can be analyzed in the Hamiltonian formulation of quantum finance. Forward-2963 Fax: (65) 6777-6126 Email: phybeb@nus.edu.sg #12;Quantum Finance Hamiltonian for Coupon Bond European

  18. PINS chemical identification software

    DOE Patents [OSTI]

    Caffrey, Augustine J.; Krebs, Kennth M.

    2004-09-14

    An apparatus and method for identifying a chemical compound. A neutron source delivers neutrons into the chemical compound. The nuclei of chemical elements constituting the chemical compound emit gamma rays upon interaction with the neutrons. The gamma rays are characteristic of the chemical elements constituting the chemical compound. A spectrum of the gamma rays is generated having a detection count and an energy scale. The energy scale is calibrated by comparing peaks in the spectrum to energies of pre-selected chemical elements in the spectrum. A least-squares fit completes the calibration. The chemical elements constituting the chemical compound can be readily determined, which then allows for identification of the chemical compound.

  19. In situ measurement of the bonded film thickness of Z-Tetraol lubricant on magnetic recording media

    SciTech Connect (OSTI)

    Zhu Lei; Li Feng

    2010-10-15

    Currently, the bonded film thickness of perfluoropolyether lubricant on top of magnetic recording media is measured by a two-step process. First, the media disk has to be rinsed thoroughly using a fluorocarbon solvent (for instance, Vetrel) to remove the mobile lubricant. Second, the thickness of the remaining lubricant on the media surface which is regarded as the bonded lubricant thickness is then measured either by Fourier transform infrared spectroscopy (FTIR) or electron spectroscopy for chemical analysis. As the total lubricant thickness approaches single molecular dimension ({approx}10 A), current methods face tremendous challenge on the accuracy and sensitivity of the measurement. We studied the spectral characteristics responding to the lubricant bonding with the carbon overcoat by the time-of-flight secondary ion mass spectra and proposed to use the peak area ratio (C{sub 3}H{sub 2}F/C{sub 3}H{sub 5}O and C{sub 4}H{sub 10}O/C{sub 3}H{sub 6}O{sub 2}) to characterize the bonded Z-Tetraol lubricant that produces a direct bonded lubricant thickness measurement without the need to remove the mobile lubricant with a solvent. After taking the background signal of disks prior to bonding by UV irradiation into account, this method becomes independent of the total lubricant thickness as well as shows good correlation linearity (R{sup 2{approx}}87%) with the current FTIR method for the ratio of C{sub 4}H{sub 10}O/C{sub 3}H{sub 6}O{sub 2}.

  20. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, Jr., Thomas M. (P.O. Box 4231, Clearwater, FL 33518); Wells, Barbara J. (865 N. Village Dr., Apt. 101B, St. Petersburg, FL 33702)

    1987-01-01

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40.degree. to 365.degree. C. to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  1. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, T.M. Jr.; Wells, B.J.

    1985-01-01

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40 to 365/sup 0/C to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  2. Fourier sparsity, spectral norm, and the Log-rank conjecture Hing Yin Tsang*

    E-Print Network [OSTI]

    Xie, Ning

    Fourier sparsity, spectral norm, and the Log-rank conjecture Hing Yin Tsang* hytsang@cse.cuhk.edu.hk Abstract--We study Boolean functions with sparse Fourier spectrum or small spectral norm, and show for such functions is exactly the Fourier sparsity of f. Let d = deg2(f) be the F2-degree of f and DCC (f ) stand

  3. Eliciting Motivation Knowledge from Log Files towards Motivation Diagnosis for Adaptive Systems

    E-Print Network [OSTI]

    Cocea, Mihaela

    Eliciting Motivation Knowledge from Log Files towards Motivation Diagnosis for Adaptive Systems, Dublin 1, Ireland {mcocea, sweibelzahl}@ncirl.ie Abstract. Motivation is well-known for its importance a user model of the learner's motivation, especially if integrated with information about knowledge

  4. Annual Logging Symposium, June 21-24, 2009 INVERSION OF SECTOR-BASED LWD DENSITY MEASUREMENTS

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    SPWLA 50th Annual Logging Symposium, June 21-24, 2009 1 INVERSION OF SECTOR-BASED LWD DENSITY-while-drilling (LWD) density measurements acquired in high-angle and horizontal (HA/HZ) wells. Our interpretation to increasing tool standoff in the upper sectors of the measurement. INTRODUCTION Conventional processing of LWD

  5. Annual Logging Symposium, June 4-7, 2006 ASSESSMENT OF SHOULDER-BED, INVASION, AND LAMINATION

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    Annual Logging Symposium held in Veracruz, Mexico, June 4-7, 2006. ABSTRACT We quantify the relative effects of shoulder beds, layer thickness, invasion, and sand-shale laminations on monopole and dipole soft and hard formations bounded by shale layers. The thickness of the formation is changed to consider

  6. Freezing Cells Make sure cells are in log phase of growth, ie. subconfluent

    E-Print Network [OSTI]

    Pike, Linda J.

    Freezing Cells Make sure cells are in log phase of growth, ie. subconfluent Protocol 1: 1. Wash cells and trypsinize as usual. 2. Spin down trypsinized cells at 1000 rpm in the tabletop centrifuge 3. Resuspend cells in 0.45 ml standard medium 4. Add 0.45 ml fetal calf serum 5. Add dropwise, 100 µl

  7. East Asian Governments Failing on Illegal Logging as Greenpeace Launches Global Paradise Forests Campaign

    E-Print Network [OSTI]

    East Asian Governments Failing on Illegal Logging as Greenpeace Launches Global Paradise Forests non-violent, creative confrontation to expose global environmental problems, and to force solutions Law Enforcement and Governance (FLEG) to put words into action and take steps to seriously address

  8. Surveys of the Logging Contractor Population 8 Southern States and Maine Cornelis F. de Hoop

    E-Print Network [OSTI]

    10.0 Surveys of the Logging Contractor Population ­ 8 Southern States and Maine by Cornelis F. de. Egan Associate Professor Department of Forest Management University of Maine Orono, ME 04469-5755 W. Thus, surveys of loggers in Maine and in eight southern states were conducted to gain additional

  9. Weekly Security Incident Log Period of Aug 12 -Aug 18, 2013

    E-Print Network [OSTI]

    2013-001248 THOMPSON ROAD Gas leak Security , Toronto Fire, Toronto Police, and Occupational Health and Safety responded to a report of a natural gas leak in the area of the Life Science BuildingWeekly Security Incident Log Period of Aug 12 - Aug 18, 2013 Incident No. Reported Date Building

  10. Weekly Security Incident Log Period of Feb 6 -Feb 12, 2012

    E-Print Network [OSTI]

    Gas leak Security and Toronto Fire responded to a report of a natural gas odour in B-wing. TorontoWeekly Security Incident Log Period of Feb 6 - Feb 12, 2012 Incident No. Reported Date Building\\Const. Security, York Fire Prevention and Toronto Fire responded to a fire alarm. The cause of the alarm

  11. Weekly Security Incident Log Period of Jul 9 -Jul 15, 2012

    E-Print Network [OSTI]

    and Safety responded to a report of a natural gas odour in the building. The building was checked and no natural gas was found. Toronto Fire determined that all was in order. 7/12/2012 07:31 AM HazardousWeekly Security Incident Log Period of Jul 9 - Jul 15, 2012 Incident No. Reported Date Building

  12. Weekly Security Incident Log Period of Apr 29 -May 5, 2013

    E-Print Network [OSTI]

    2013-000845 YORK LANES RETAIL Gas leak Security, Toronto Fire and Enbridge Gas responded to a report of a natural gas odour in the building. The source of the odour was located in a restaurant kitchen. EnbridgeWeekly Security Incident Log Period of Apr 29 - May 5, 2013 Incident No. Reported Date Building

  13. An Approach for Mining Web Service Composition Patterns from Execution Logs

    E-Print Network [OSTI]

    Zou, Ying

    1 An Approach for Mining Web Service Composition Patterns from Execution Logs Ran Tang and Ying Zou.zou}@queensu.ca Abstract-- A service-oriented application is composed of multiple web services to fulfill complex functionality that cannot be provided by individual web service. The combination of services is not random

  14. How do I enroll? 1. Log into WSU's online portal (Academica).

    E-Print Network [OSTI]

    Finley Jr., Russell L.

    How do I enroll? 1. Log into WSU's online portal (Academica). 2 by noon the following business day. 8. Check your account in the online portal in WSU's online portal (Academica). The first payment may include non-deferred fees. What if I add

  15. Parsing the WSJ using CCG and Log-Linear Models Stephen Clark

    E-Print Network [OSTI]

    Curran, James R.

    of Edinburgh 2 Buccleuch Place, Edinburgh, UK stephen.clark@ed.ac.uk James R. Curran School of Information and Steedman, 2002; Hockenmaier, 2003b). In Clark and Curran (2003) we argued for the use of log-linear parsing (Nocedal and Wright, 1999). And finally, we show that the parsing algo- rithm described in Clark and Curran

  16. SPE 159255-PP Rock Classification from Conventional Well Logs in Hydrocarbon-Bearing

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    SPE 159255-PP Rock Classification from Conventional Well Logs in Hydrocarbon-Bearing Shale Andrew C typing method for application in hydrocarbon-bearing shale (specifically source rock) reservoirs using-hoc correlations where the interpretation becomes a core matching exercise. Scale effects on measurements

  17. ANALYSIS OF PHYSICAL FACTORS AFFECTING ILLEGAL LOGGING OF TROPICAL FOREST OF BERAU, EAST KALIMANTAN, INDONESIA

    E-Print Network [OSTI]

    , INDONESIA USING REMOTE SENSING AND GIS Anita Zaitunah Yousif Ali Hussin Ali Sharifi Department of Natural pollution and storms. The annual deforestation rate in Indonesia was 1.8 million ha between 1985 and 1997 of forests and cutting in unauthorised areas. In Indonesia, there is a smuggling of illegal logs

  18. April 2002 Page 1 of 6 Export credits: Fuelling illegal logging

    E-Print Network [OSTI]

    April 2002 Page 1 of 6 Export credits: Fuelling illegal logging Export Credit Agencies (ECAs are ECAs? Export Credit Agencies and Investment Insurance Agencies, commonly known as ECAs, are public and investment ­ nearly 10 percent of world exports. Longer term loans and guarantees by ECAs increased four

  19. Log-Gamma Polymer Free Energy Fluctuations via a Fredholm Determinant Identity

    E-Print Network [OSTI]

    Borodin, Alexei

    We prove that under n[superscript 1/3] scaling, the limiting distribution as n ? ? of the free energy of Seppalainen’s log-Gamma discrete directed polymer is GUE Tracy-Widom. The main technical innovation we provide is a ...

  20. Oblivious RAM with O((log N)3 ) Worst-Case Cost

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Oblivious RAM with O((log N)3 ) Worst-Case Cost Elaine Shi PARC/UC Berkeley T-H. Hubert Chan HKU applications. This paper proposes novel O-RAM con- structions that achieves poly-logarithmic worst-case cost in outsourced storage applications. Not surprisingly, the client has to pay a certain cost in order to hide its

  1. Annual Logging Symposium, June 3-6, 2007 COMBINED INVERSION OF BOREHOLE RESISTIVITY AND SONIC

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    n wS . In other words, resistivity measurements alone can not render separate estimates of w saturation, wS , and porosity, , play important roles in well-log interpretation and formation evaluation for fluid substitution in the study of seismic properties of rocks. Generally, wS is computed using Archie

  2. A Principled Approach to Mining From Noisy Logs Using Heuristics Miner

    E-Print Network [OSTI]

    Tino, Peter

    A Principled Approach to Mining From Noisy Logs Using Heuristics Miner Philip Weber, Behzad Bordbar Miner algorithm, and demonstrate on a simple example. We show that for a given model it is possible in the the robustness of Heuristics Miner to different types of noise. I. INTRODUCTION Process mining is the learning

  3. DistributionFree Multivariate Process Control Based On LogLinear Modeling School of Statistics

    E-Print Network [OSTI]

    Qiu, Peihua

    Distribution­Free Multivariate Process Control Based On Log­Linear Modeling Peihua Qiu School the process measurement is multivariate. In the literature, most existing multivariate SPC procedures assume that the in­control distribution of the multivariate process measurement is known and it is a Gaussian

  4. CareLog: A Selective Archiving Tool for Behavior Management in Schools

    E-Print Network [OSTI]

    Hayes, Gillian R.

    to five design principles that governed the development of CareLog. We present results from a five- month]. Such behaviors can disrupt the educational activities for the student with the behavior disorder other disabilities, frequently Autism Spectrum Disorder (ASD) but also Down's Syndrome, Fragile X

  5. Annual Logging Symposium, June 1620, 2012 IMPROVED ASSESSMENT OF IN-SITU FLUID SATURATION WITH

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    SATURATION WITH MULTI-DIMENSIONAL NMR MEASUREMENTS AND CONVENTIONAL WELL LOGS Kanay Jerath and Carlos Torres saturating fluids. However, often there is ambiguity as to whether fluids appraised with NMR measurements-filtrate invasion, the NMR response of virgin reservoir fluids can be masked by that of mud filtrate. In order

  6. LogStore: Toward Energy-Proportional Storage Servers Wei Zheng Ana Paula Centeno Frederic Chong

    E-Print Network [OSTI]

    Bianchini, Ricardo

    LogStore: Toward Energy-Proportional Storage Servers Wei Zheng Ana Paula Centeno Frederic Chong,anapaula,ricardob}@cs.rutgers.edu chong@cs.ucsb.edu ABSTRACT Storage servers consume significant amounts of energy and are highly non-energy throughput. Categories and Subject Descriptors D.4 [Operating systems]: Storage management Keywords Energy

  7. On the optimal wealth process in a log-normal market

    E-Print Network [OSTI]

    Knopf, Dan

    On the optimal wealth process in a log-normal market: Applications to risk management Phillip Monin and portfolio processes for different utility functions are related through a deter- ministic transformation with respect to the cumulative excess stock return, time, and market parameters. We conclude with a study

  8. Learn from Web Search Logs to Organize Search Results Xuanhui Wang

    E-Print Network [OSTI]

    Zhai, ChengXiang

    and Subject Descriptors: H.3.3 [Informa- tion Search and Retrieval]: Clustering, Search process General TermsLearn from Web Search Logs to Organize Search Results Xuanhui Wang Department of Computer Science Effective organization of search results is critical for improv- ing the utility of any search engine

  9. Upward pressure on timber prices eased as logging conditions improved and lumber &

    E-Print Network [OSTI]

    Upward pressure on timber prices eased as logging conditions improved and lumber & panel prices plummeted back to where they were before the spring run-ups. Overall, timber prices were higher than the prices a year ago. Lumber imports from Canada increased in June due to the temporary re- moval

  10. Small Log Conference Creating Capacity to Compete Coeur d'Alene, Idaho, USA, 1 April 2005

    E-Print Network [OSTI]

    Assessment · UNECE Timber Committee market forecasts · UNECE/FAO Timber Bulletin "Forest products annual Forest Sector Outlook Study · FAO State of the World's Forests, 2005 #12;Small Log Conference ­ Creating countries · Low value · Modern wood energy ­ Small international trade ­ Growing market ­ Policy push

  11. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries

    SciTech Connect (OSTI)

    Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail; Hu, Shilin; Yi, Ran; Tang, Duihai; Walter, Timothy; Regula, Michael; Choi, Daiwon; Li, Xiaolin; Manivannan, Ayyakkannu; Wang, Donghai

    2014-11-12

    Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost, natural abundance of sodium. Here, we report a novel graphene nanosheets-wrapped phosphorus composite as an anode for high performance sodium-ion batteries though a facile ball-milling of red phosphorus and graphene nanosheets. Not only can the graphene nanosheets significantly improve the electrical conductivity, but they also serve as a buffer layer to accommodate the large volume change of phosphorus in the charge-discharge process. As a result, the graphene wrapped phosphorus composite anode delivers a high reversible capacity of 2077 mAh/g with excellent cycling stability (1700 mAh/g after 60 cycles) and high Coulombic efficiency (>98%). This simple synthesis approach and unique nanostructure can potentially extend to other electrode materials with unstable solid electrolyte interphases in sodium-ion batteries.

  12. Corporate bodies and chemical bonds : an STS analysis of natural gas development in the United States

    E-Print Network [OSTI]

    Wylie, Sara Ann

    2011-01-01

    Natural gas extraction in the United States in the early 21st century has transformed social, physical, legal and biological landscapes. The technique of hydraulic fracturing, which entails the high-pressure injection into ...

  13. Chemical dynamics and bonding at gas/semiconductor and oxide/semiconductor interfaces

    E-Print Network [OSTI]

    Bishop, Sarah R.

    2010-01-01

    and physical properties of semiconductor materials. Onematerials considered, Ge and III-V semiconductors, have favorable intrinsic properties

  14. Chemically bonded phosphate ceramics of trivalent oxides of iron and manganese

    DOE Patents [OSTI]

    Wagh, Arun S. (Orland Park, IL); Jeong, Seung-Young (Westmont, IL)

    2002-01-01

    A new method for combining elemental iron and other metals to form an inexpensive ceramic to stabilize arsenic, alkaline red mud wastes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast.

  15. Nanoscale metals and semiconductors for the storage of solar energy in chemical bonds

    E-Print Network [OSTI]

    Manthiram, Karthish

    2015-01-01

    hydrogen evolution reaction overpotentials and adsorbate binding energies, such as zinc, gallium, palladium,

  16. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing Bacteria (TechnicalTransmission,TextitSciTech

  17. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing Bacteria (TechnicalTransmission,TextitSciTechin Complex Interfacial| SciTech|

  18. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing Bacteria (TechnicalTransmission,TextitSciTechin Complex Interfacial| SciTech|for

  19. Tuning the Metal-Adsorbate Chemical Bond through the Ligand Effect on

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: April 15, 2014 Truck fireContactPlatinum Subsurface

  20. On the possible exceptions for the transcendence of the log-gamma function at rational values and its consequences for the transcendence of $ \\log{\\pi} $ and $ \\pi e $

    E-Print Network [OSTI]

    Lima, F M S

    2009-01-01

    In a recent work published in this journal [JNT \\textbf{129}, 2154 (2009)], it has been argued that the numbers $\\log{\\Gamma(x)} + \\log{\\Gamma(1-x)}$, $x$ being a rational number between 0 and 1, are transcendental with at most \\emph{one} possible exception, but the proof presented there is \\emph{incorrect}. Here in this paper, I point out the mistake committed in that proof and I present a theorem that establishes the transcendence of those numbers, with at most \\emph{two} possible exceptions. This yields a criteria for the algebraicity of $\\log{\\pi}$, a number that presently is not known even to be irrational. I also show that each pair $\\{\\log{[\\pi/\\sin(\\pi x)]}, \\log{[\\pi/\\sin(\\pi y)]}\\}$ contains at least one transcendental number, e.g. $\\{\\log{\\pi}, \\log{(2 \\pi)} \\}$. With respect to this pair, I show that if $ \\log{(k \\pi)}$ is algebraic for some non-zero algebraic $k$ then the product $\\pi e$, another number whose irrationality is not proved, has to be transcendental.

  1. ANALYTICAL METHODS in CHEMICAL ECOLOGY

    E-Print Network [OSTI]

    (SLU), Alnarp separation identification log [nominal amount/ml] log[analyzedamount/ml] 10pg 100pg 1ng 10ng 100ng 1µg 10µg 10pg 100pg 1ng 10ng 100ng 1µg 10µg quantification MOST WELCOME!!!! /Göran

  2. Differentiation of O-H and C-H Bond Scission Mechanisms of Ethylene Glycol on Pt and Ni/Pt Using Theory and Isotopic Labeling Experiments

    SciTech Connect (OSTI)

    Salciccioli, Michael [Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation (CCEI) and Center for Catalytic Science and Technology (CCST); Yu, Weiting [Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation (CCEI) and Center for Catalytic Science and Technology (CCST); Barteau, Mark A. [Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation (CCEI) and Center for Catalytic Science and Technology (CCST); Chen, Jingguang G. [Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation (CCEI) and Center for Catalytic Science and Technology (CCST); Vlachos, Dionisios G. [Univ. of Delaware, Newark, DE (United States). Catalysis Center for Energy Innovation (CCEI) and Center for Catalytic Science and Technology (CCST)

    2011-05-25

    Understanding and controlling bond-breaking sequences of oxygenates on transition metal catalysts can greatly impact the utilization of biomass feedstocks for fuels and chemicals. The decomposition of ethylene glycol, as the simplest representative of biomass-derived polyols, was studied via density functional theory (DFT) calculations to identify the differences in reaction pathways between Pt and the more active Ni/Pt bimetallic catalyst. Comparison of the computed transition states indicated three potentially feasible paths from ethylene glycol to C1 oxygenated adsorbates on Pt. While not important on Pt, the pathway to 1,2-dioxyethylene (OCH?CH?O) is favored energetically on the Ni/Pt catalyst. Temperature-programmed desorption (TPD) experiments were conducted with deuterated ethylene glycols for comparison with DFT results. These experiments confirmed that decomposition of ethylene glycol on Pt proceeds via initial O–H bond cleavage, followed by C–H and the second O–H bond cleavages, whereas on the Ni/Pt surface, both O–H bonds are cleaved initially. The results are consistent with vibrational spectra and indicate that tuning of the catalyst surface can selectively control bond breaking. Finally, the significant mechanistic differences in decomposition of polyols compared to that of monoalcohols and hydrocarbons serve to identify general trends in bond scission sequences.

  3. Theoretical Electron Density Distributions for Fe-and Cu-Sulfide Earth Materials: A Connection between Bond Length, Bond Critical Point Properties, Local Energy Densities,

    E-Print Network [OSTI]

    Downs, Robert T.

    between Bond Length, Bond Critical Point Properties, Local Energy Densities, and Bonded Interactions G. V; In Final Form: December 6, 2006 Bond critical point and local energy density properties together with netTheoretical Electron Density Distributions for Fe- and Cu-Sulfide Earth Materials: A Connection

  4. Using Visualizations to Monitor Changes and Harvest Insights from a Global-Scale Logging Infrastructure at Twitter

    E-Print Network [OSTI]

    Daume III, Hal

    on three platforms: strawberry, coconut, and banana. Log events follow a six-level naming hierarchy (client:page:section:component:element:action). Here, we see that the event strawberry:search:personal:-:-:impression in- creased in frequency compared strawberry:inbox:inbox:conversation:-:impression dropped slightly. Abstract-- Logging user activities

  5. Page-Differential Logging: An Efficient and DBMS-Independent Approach for Storing Data into Flash Memory

    E-Print Network [OSTI]

    Whang, Kyu-Young

    Page-Differential Logging: An Efficient and DBMS- Independent Approach for Storing Data into Flash or from log-based ones that keep track of the history of all the changes in a page. Our method allows.e., it is DBMS-independent. Experimental results show that the proposed method is superior in I/O performance

  6. Outline Directed polymers Log-gamma polymer KPZ equation Fluctuation exponents for certain 1+1 dimensional

    E-Print Network [OSTI]

    Seppäläinen, Timo

    Outline Directed polymers Log-gamma polymer KPZ equation Fluctuation exponents for certain 1+1 dimensional directed polymers Timo Sepp¨al¨ainen Department of Mathematics University of Wisconsin-Madison MSRI December 2010 Fluctuation exponents for polymers 1/36 #12;Outline Directed polymers Log

  7. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

    2011-01-18

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  8. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

    2012-04-10

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  9. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D.; Dumesic, James A.

    2013-04-02

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  10. Vacuum pull down method for an enhanced bonding process

    DOE Patents [OSTI]

    Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    1999-01-01

    A process for effectively bonding arbitrary size or shape substrates. The process incorporates vacuum pull down techniques to ensure uniform surface contact during the bonding process. The essence of the process for bonding substrates, such as glass, plastic, or alloys, etc., which have a moderate melting point with a gradual softening point curve, involves the application of an active vacuum source to evacuate interstices between the substrates while at the same time providing a positive force to hold the parts to be bonded in contact. This enables increasing the temperature of the bonding process to ensure that the softening point has been reached and small void areas are filled and come in contact with the opposing substrate. The process is most effective where at least one of the two plates or substrates contain channels or grooves that can be used to apply vacuum between the plates or substrates during the thermal bonding cycle. Also, it is beneficial to provide a vacuum groove or channel near the perimeter of the plates or substrates to ensure bonding of the perimeter of the plates or substrates and reduce the unbonded regions inside the interior region of the plates or substrates.

  11. Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional Vibrational Stimulated Echoes

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional, USA (Received 24 February 2003; published 3 December 2003) Hydrogen bond dynamics are explicated hydrogen bonded network are measured with ultrashort (

  12. Bond length and electric current oscillation of long linear carbon chains: Density functional theory, MpB model, and quantum spin transport studies

    SciTech Connect (OSTI)

    Oeiras, R. Y.; Silva, E. Z. da [Institute of Physics “Gleb Wataghin”, University of Campinas-Unicamp, 13083-859 Campinas, SP (Brazil)] [Institute of Physics “Gleb Wataghin”, University of Campinas-Unicamp, 13083-859 Campinas, SP (Brazil)

    2014-04-07

    Carbon linear atomic chains attached to graphene have experimentally been produced. Motivated by these results, we study the nature of the carbon bonds in these nanowires and how it affects their electrical properties. In the present study we investigate chains with different numbers of atoms and we observe that nanowires with odd number of atoms present a distinct behavior than the ones with even numbers. Using graphene nanoribbons as leads, we identify differences in the quantum transport of the chains with the consequence that even and odd numbered chains have low and high electrical conduction, respectively. We also noted a dependence of current with the wire size. We study this unexpected behavior using a combination of first principles calculations and simple models based on chemical bond theory. From our studies, the electrons of carbon nanowires present a quasi-free electron behavior and this explains qualitatively the high electrical conduction and the bond lengths with unexpected values for the case of odd nanowires. Our study also allows the understanding of the electric conduction dependence with the number of atoms and their parity in the chain. In the case of odd number chains a proposed ?-bond (MpB) model describes unsaturated carbons that introduce a mobile ?-bond that changes dramatically the structure and transport properties of these wires. Our results indicate that the nature of bonds plays the main role in the oscillation of quantum electrical conduction for chains with even and odd number of atoms and also that nanowires bonded to graphene nanoribbons behave as a quasi-free electron system, suggesting that this behavior is general and it could also remain if the chains are bonded to other materials.

  13. Log Summarization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse BergkampCenter (LMI-EFRC)Lodging Lodging Meeting Hotel - Hyatt

  14. Outage Log

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams forOrhan Kizilkaya, Ph.D.Our Team Our Team OurOurOut

  15. Wire bond vibration of forward pixel tracking detector of CMS

    SciTech Connect (OSTI)

    Atac, M.; /Fermilab; Gobbi, B.; /Northwestern U.; Kwan, S.; Pischalnikov, Y.; /Fermilab; Spencer, E.; /Northwestern U.; Sellberg, G.; Pavlicek, V.; /Fermilab

    2006-10-01

    Wire bonds of the Forward Pixel (FPix) tracking detectors are oriented in the direction that maximizes Lorentz Forces relative to the 4 Tesla field of the Compact Muon Solenoid (CMS) Detector's magnet. The CMS Experiment is under construction at the Large Hadron Collider at CERN, Geneva, Switzerland. We were concerned about Lorentz Force oscillating the wires at their fundamental frequencies and possibly fracturing or breaking them at their heels, as happened with the CDF wire bonds. This paper reports a study to understand what conditions break such bonds.

  16. Chemical Industry Bandwidth Study

    SciTech Connect (OSTI)

    none,

    2006-12-01

    The Chemical Bandwidth Study provides a snapshot of potentially recoverable energy losses during chemical manufacturing. The advantage of this study is the use of "exergy" analysis as a tool for pinpointing inefficiencies.

  17. Chemicals Industry Vision

    SciTech Connect (OSTI)

    none,

    1996-12-01

    Chemical industry leaders articulated a long-term vision for the industry, its markets, and its technology in the groundbreaking 1996 document Technology Vision 2020 - The U.S. Chemical Industry. (PDF 310 KB).

  18. Capacitive chemical sensor

    DOE Patents [OSTI]

    Manginell, Ronald P; Moorman, Matthew W; Wheeler, David R

    2014-05-27

    A microfabricated capacitive chemical sensor can be used as an autonomous chemical sensor or as an analyte-sensitive chemical preconcentrator in a larger microanalytical system. The capacitive chemical sensor detects changes in sensing film dielectric properties, such as the dielectric constant, conductivity, or dimensionality. These changes result from the interaction of a target analyte with the sensing film. This capability provides a low-power, self-heating chemical sensor suitable for remote and unattended sensing applications. The capacitive chemical sensor also enables a smart, analyte-sensitive chemical preconcentrator. After sorption of the sample by the sensing film, the film can be rapidly heated to release the sample for further analysis. Therefore, the capacitive chemical sensor can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  19. Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen Bonds and An Alternative to the Low Barrier Hydrogen-Bond Proposal

    SciTech Connect (OSTI)

    Shokri, Alireza; Wang, Yanping; O'Doherty, George A.; Wang, Xue B.; Kass, Steven R.

    2013-11-27

    We report quantifying the strengths of different types of hydrogen bonds in hydrogen bond networks (HBNs) via measurement of the adiabatic electron detachment energy of the conjugate base of a small covalent polyol model compound (i.e., (HOCH2CH2CH(OH)CH2)2CHOH) in the gas phase and the pKa of the corresponding acid in DMSO. The latter result reveals that the hydrogen bonds to the charged center and those that are one solvation shell further away (i.e., primary and secondary) provide 5.3 and 2.5 pKa units of stabilization per hydrogen bond in DMSO. Computations indicate that these energies increase to 8.4 and 3.9 pKa units in benzene and that the total stabilizations are 16 (DMSO) and 25 (benzene) pKa units. Calculations on a larger linear heptaol (i.e., (HOCH2CH2CH(OH)CH2CH(OH)CH2)2CHOH) reveal that the terminal hydroxyl groups each contribute 0.6 pKa units of stabilization in DMSO and 1.1 pKa units in benzene. All of these results taken together indicate that the presence of a charged center can provide a powerful energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN.

  20. Surface chemistry and bonding configuration of ultrananocrystalline diamond surfaces and their effects on nanotribological properties

    SciTech Connect (OSTI)

    Sumant, A. V.; Grierson, D. S.; Carpick, R. W.; Gerbi, J. E.; Carlisle, J. A.; Auciello, O.

    2007-12-15

    We present a comprehensive study of surface composition and nanotribology for ultrananocrystalline diamond (UNCD) surfaces, including the influence of film nucleation on these properties. We describe a methodology to characterize the underside of the films as revealed by sacrificial etching of the underlying substrate. This enables the study of the morphology and composition resulting from the nucleation and initial growth of the films, as well as the characterization of nanotribological properties which are relevant for applications including micro-/nanoelectromechanical systems. We study the surface chemistry, bonding configuration, and nanotribological properties of both the topside and the underside of the film with synchrotron-based x-ray absorption near-edge structure spectroscopy to identify the bonding state of the carbon atoms, x-ray photoelectron spectroscopy to determine the surface chemical composition, Auger electron spectroscopy to further verify the composition and bonding configuration, and quantitative atomic force microscopy to study the nanoscale topography and nanotribological properties. The films were grown on SiO{sub 2} after mechanically polishing the surface with detonation synthesized nanodiamond powder, followed by ultrasonication in a methanol solution containing additional nanodiamond powder. The sp{sup 2} fraction, morphology, and chemistry of the as-etched underside are distinct from the topside, exhibiting a higher sp{sup 2} fraction, some oxidized carbon, and a smoother morphology. The nanoscale single-asperity work of adhesion between a diamond nanotip and the as-etched UNCD underside is far lower than for a silicon-silicon interface (59.2{+-}2 vs 826{+-}186 mJ/m{sup 2}, respectively). Exposure to atomic hydrogen dramatically reduces nanoscale adhesion to 10.2{+-}0.4 mJ/m{sup 2}, at the level of van der Waals' interactions and consistent with recent ab initio calculations. Friction is substantially reduced as well, demonstrating a direct link between the surface chemistry and nanoscale friction. The proposed mechanism, supported by the detailed surface spectroscopic analysis, is the elimination of reactive (e.g., C*-), polar (e.g., C=O), and {pi}-bonded (C=C) surface groups, which are replaced by fully saturated, hydrogen-terminated surface bonds to produce an inert surface that interacts minimally with the contacting counterface.

  1. Surface chemistry and bonding configuration of ultrananocrystalline diamond surfaces and their effects on nanotribological properties.

    SciTech Connect (OSTI)

    Sumant, A. V.; Grierson, D. S.; Gerbi, J. E.; Carlisle, J. A.; Auciello, O.; Carpick, R. W.; Univ. of Wisconsin at Madison

    2007-12-01

    We present a comprehensive study of surface composition and nanotribology for ultrananocrystalline diamond (UNCD) surfaces, including the influence of film nucleation on these properties. We describe a methodology to characterize the underside of the films as revealed by sacrificial etching of the underlying substrate. This enables the study of the morphology and composition resulting from the nucleation and initial growth of the films, as well as the characterization of nanotribological properties which are relevant for applications including micro-/nanoelectromechanical systems. We study the surface chemistry, bonding configuration, and nanotribological properties of both the topside and the underside of the film with synchrotron-based x-ray absorption near-edge structure spectroscopy to identify the bonding state of the carbon atoms, x-ray photoelectron spectroscopy to determine the surface chemical composition, Auger electron spectroscopy to further verify the composition and bonding configuration, and quantitative atomic force microscopy to study the nanoscale topography and nanotribological properties. The films were grown on SiO{sub 2} after mechanically polishing the surface with detonation synthesized nanodiamond powder, followed by ultrasonication in a methanol solution containing additional nanodiamond powder. The sp{sup 2} fraction, morphology, and chemistry of the as-etched underside are distinct from the topside, exhibiting a higher sp{sup 2} fraction, some oxidized carbon, and a smoother morphology. The nanoscale single-asperity work of adhesion between a diamond nanotip and the as-etched UNCD underside is far lower than for a silicon-silicon interface (59.2 {+-} 2 vs 826 {+-} 186 mJ/m{sup 2}, respectively). Exposure to atomic hydrogen dramatically reduces nanoscale adhesion to 10.2 {+-} 0.4 mJ/m{sup 2}, at the level of van der Waals interactions and consistent with recent ab initio calculations. Friction is substantially reduced as well, demonstrating a direct link between the surface chemistry and nanoscale friction. The proposed mechanism, supported by the detailed surface spectroscopic analysis, is the elimination of reactive (e.g., C*-), polar (e.g., C-O), and {pi}-bonded (C-C) surface groups, which are replaced by fully saturated, hydrogen-terminated surface bonds to produce an inert surface that interacts minimally with the contacting counterface.

  2. Anion Coordination in Metal-Organic Frameworks Functionalized with Urea Hydrogen-Bonding Groups

    SciTech Connect (OSTI)

    Custelcean, Radu; Moyer, Bruce A.; Bryantsev, Vyacheslav; Hay, Benjamin P.

    2005-12-15

    A series of metal-organic frameworks (MOFs) functionalized with urea hydrogen-bonding groups have been designed, synthesized, and structurally analyzed by single crystal X-ray diffraction to evaluate the efficacy of anion binding within the structural constraints of the MOFs. We found that urea-based functionalities may be used for anion binding within metal-organic frameworks when the tendency for urea???urea self-association is decreased by strengthening the intramolelcular CH???O hydrogen bonding of N-phenyl substituents to the carbonyl oxygen atom. Theoretical calculations indicate that N,N?-bis(m-pyridyl)urea (BPU) and N,N?-bis(m-cyanophenyl)urea (BCPU) should have enhanced hydrogen-bonding donor abilities toward anions and decreased tendencies to self-associate into hydrogen-bonded chains compared to other disubstituted ureas. Accordingly, BPU and BCPU were incorporated in MOFs as linkers through coordination of various Zn, Cu, and Ag transition metal salts, including Zn(ClO4)2, ZnSO4, Cu(NO3)2, Cu(CF3SO3)2, AgNO3 and AgSO3CH3. Structural analysis by single-crystal X-ray diffraction showed that these linkers are versatile anion binders, capable of chelate hydrogen bonding to all of the oxoanions explored. Anion binding by the urea functionalities was found to successfully compete with urea self-association in all cases except for that of charge-diffuse perchlorate. This research was sponsored by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences of the U.S. Department of Energy, under contract number DE-AC05-00OR22725 with Oak Ridge National Laboratory (managed by UT-Battelle, LLC), and performed at Oak Ridge National laboratory and Pacific Northwest National Laboratory (managed by Battelle for the U.S. Department of Energy under contract DE-AC05-76RL01830). This research was performed in part using the Molecular Science Computing Facility (MSCF) in the William R. Wiley Environmental Molecular Sciences laboratory, a national scientific user facility sponsored by the U.S. Department of Energy's Office of Biological and Environmental Research located at the Pacific Northwest National Laboratory.

  3. Chemical Sciences Division - CSD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CSD Chemical Sciences Division CSD Organization Contact List Search Other Links Research Areas Research Highlights Organization Contacts Publications Awards Employment...

  4. MECS 2006- Chemicals

    Broader source: Energy.gov [DOE]

    Manufacturing Energy and Carbon Footprint for Chemicals Sector (NAICS 325) with Total Energy Input, October 2012 (MECS 2006)

  5. Department of Chemical Engineering

    E-Print Network [OSTI]

    Zhigilei, Leonid V.

    Developing Leaders of Innovation Department of Chemical Engineering #12;At the University of Virginia, we educate students in traditional and nontraditional areas of chemical engineering, giving them.Va. Department of Chemical Engineering benefit from a modern academic curriculum and state

  6. Equilibrium Chemical Engines

    E-Print Network [OSTI]

    Tatsuo Shibata; Shin-ichi Sasa

    1997-10-30

    An equilibrium reversible cycle with a certain engine to transduce the energy of any chemical reaction into mechanical energy is proposed. The efficiency for chemical energy transduction is also defined so as to be compared with Carnot efficiency. Relevance to the study of protein motors is discussed. KEYWORDS: Chemical thermodynamics, Engine, Efficiency, Molecular machine.

  7. HARVARD UNIVERSITY CHEMICAL BIOLOGY

    E-Print Network [OSTI]

    Church, George M.

    HARVARD UNIVERSITY CHEMICAL BIOLOGY PHD PROGRAM 2013-2014 Student Handbook #12;Program Contacts at the beginning of each semester. Laboratory Rotations Students in the Chemical Biology Program are expected an interest in having Chemical Biology Program Students in their labs. Students may rotate in the labs

  8. A Uniqueness Result for Minimizers of the 1D Log-gas Renormalized Energy

    E-Print Network [OSTI]

    Thomas Leblé

    2014-08-10

    Sandier and Serfaty studied the one-dimensional Log-gas model, in particular they gave a crystallization result by showing that the one-dimensional lattice $\\mathbb{z}$ is a minimizer for the so-called renormalized energy which they obtained as a limit of the $N$-particle Log-gas Hamiltonian for $N \\to \\infty$. However, this minimizer is not unique among infinite point configurations (for example small perturbations of $\\mathbb{z}$ leave the renormalized energy unchanged). In this paper, we establish that uniqueness holds at the level of (stationary) point processes, the only minimizer being given by averaging $\\mathbb{z}$ over a choice of the origin in $[0,1]$. This is proved by showing a quantitative estimate on the two-point correlation function of a process in terms of its renormalized energy.

  9. The high-energy radiation pattern from BFKLex with double-log collinear contributions

    E-Print Network [OSTI]

    Chachamis, G

    2015-01-01

    We study high-energy jet production in the multi-Regge limit making use of the Monte Carlo event generator BFKLex which includes collinear improvements in the form of double-log contributions as presented in [1]. Making use of the anti-kt jet algorithm in the FastJet implementation, we present results for the average transverse momentum and azimuthal angle of the produced jets when two tagged forward/backward jets are present in the final state. We also introduce a new observable which accounts for the average rapidity separation among subsequent emissions. Results are presented, for comparison, at leading order and next-to-leading order, with the resummation of collinear double logs proposed in [2].

  10. Low temperature transient liquid phase bonding of copper

    E-Print Network [OSTI]

    Williams, Joel C. (Joel Carlton)

    2005-01-01

    This thesis describes a Pb-free solder alternative that is capable of fluxless bonding. The main advantage of this process is that it offers the benefits of low fabrication temperature (125?C) while producing a joint capable ...

  11. Multilayer roll bonded aluminium foil: processing, microstructure and flow stress

    SciTech Connect (OSTI)

    Barlow, C.Y.; Nielsen, P.; Hansen, N

    2004-08-02

    Bulk aluminium has been produced by warm-rolling followed by cold-rolling of commercial purity (99% purity) aluminium foil. The bonding appeared perfect from observation with the naked eye, light and transmission electron microscopy. By comparison with bulk aluminium of similar purity (AA1200) rolled to a similar strain (90%RA), the roll-bonded metal showed a much higher density of high-angle grain boundaries, similar strength and improved thermal stability. This study has implications for a number of applications in relation to the processing of aluminium. Roll bonding is of interest as a method for grain size refinement; oxide-containing materials have increased strength, enhanced work-hardening behaviour, and exhibit alterations in recrystallisation behaviour. The behaviour of the hard oxide film is of interest in aluminium processing, and has been investigated by characterising the size and distribution of oxide particles in the roll-bonded samples.

  12. MODE II FRACTURE BEHAVIOR OF BONDED VISCOELASTIC THERMAL COMPRESSED WOOD

    E-Print Network [OSTI]

    Nairn, John A.

    MODE II FRACTURE BEHAVIOR OF BONDED VISCOELASTIC THERMAL COMPRESSED WOOD Andreja Kutnar* Graduate Student Department of Wood Science and Technology Biotechnical Faculty University of Ljubljana 1000 Ljubljana, Slovenia Frederick A. Kamke Professor John A. Nairn Professor Department of Wood Science

  13. Mpemba paradox: Hydrogen bond memory and water-skin supersolidity

    E-Print Network [OSTI]

    Chang Q Sun

    2015-01-05

    Numerical reproduction of measurements, experimental evidence for skin super-solidity and hydrogen-bond memory clarified that Mpemba paradox integrates the heat emission-conduction-dissipation dynamics in the source-path-drain cycle system.

  14. Application of Social Impact Bonds in Built Infrastructure Sustainability Projects 

    E-Print Network [OSTI]

    White, Robert Joseph

    2014-05-01

    This study examines a first look at the implementation of Social Impact Bonds (SIB) for sustainability projects by comparing two cases. The cases are described using System Dynamic (SD) modeling to portray the feedback structures and characteristics...

  15. Bond graph models of electromechanical systems. The AC generator case

    E-Print Network [OSTI]

    Batlle, Carles

    Bond graph models of electromechanical systems. The AC generator case Carles Batlle Department. After reviewing electromechanical energy conversion and torque gener- ation, the core element present in any electromechanical system is introduced, and the corresponding electrical and mechanical ports

  16. Reply to comment on "Quantum Confinement in Hydrogen Bond"

    E-Print Network [OSTI]

    Santos, Carlos da Silva dos; Ricotta, Regina Maria

    2015-01-01

    We reply to the comments on our paper "Quantum Confinement in Hydrogen Bond" (Int. J. Quantum Chem. 115 (2015) 765 DOI: 10.1002/qua.24894) made by Matthias Heger and Martin A. Suhm.

  17. Influence of receptor flexibility on intramolecular H-bonding interactions

    E-Print Network [OSTI]

    Sun, Hongmei; Guo, Kai; Gan, Haifeng; Li, Xin; Hunter, Christopher A.

    2015-01-01

    Atropisomers of a series of zinc tetraphenyl porphyrins were synthesized and used as supramolecular receptors. Rotation around the porphyrin-meso phenyl bonds is restricted by installing ortho-chlorine substituents on the phenyl groups. The chlorine...

  18. IRS Announces New Tribal Economic Development Bond Allocation Guidance

    Broader source: Energy.gov [DOE]

    Treasury and the IRS published new guidance today allocating Tribal Economic Development Bonds (TEDBs) for Tribes that have projects that are in the final stages of going to the market to receive financing.

  19. Low-Cost Financing with Clean Renewable Energy Bonds

    Broader source: Energy.gov [DOE]

    Contains information from the TAP Webcast on June 24, 2009 on clean renewable energy bonds from Claire Kreycik on feed-in tariffs, an economic resource for developing renewable energy.

  20. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time-Resolved Study of Bonding in Liquid Carbon Print We are accustomed to observing carbon in its elemental form as a solid, ranging from the soft "lead" in pencils to the...

  1. The Geography of European Convertible Bonds: Why Firms Issue Convertibles?

    E-Print Network [OSTI]

    Saskatchewan, University of

    1 The Geography of European Convertible Bonds: Why Firms Issue Convertibles? Franck Bancel Usha R at the geography of CB issuance. The size and development of the CB market varies widely across countries and over

  2. Understanding mechanisms for C-H bond activation 

    E-Print Network [OSTI]

    Vastine, Benjamin Alan

    2009-05-15

    The results from density functional theory (DFT) studies into C–H bond activation, hydrogen transfer, and alkyne–to–vinylidene isomerization are presented in this work. The reaction mechanism for the reductive elimination ...

  3. Airborne LiDAR Detects Selectively Logged Tropical Forest Even in an Advanced Stage of Recovery

    E-Print Network [OSTI]

    Kent, Rafi; Lindsell, Jeremy A.; Laurin, Gaia Vaglio; Valentini, Riccardo; Coomes, David A.

    2015-01-01

    logged tropical forests: the attained and the attainable. Conserv. Lett. 2012, 5, 296–303. 10. Silver, W. L.; Ostertag, R.; Lugo, a. E. The Potential for Carbon Sequestration Through Reforestation of Abandoned Tropical Agricultural and Pasture Lands... be of high conservation value [2,7–9] and act as globally-important carbon sinks [9–12]. However, there is much uncertainty regarding the changing extent of regenerating forests, their rate and stage of recovery, and the influence of recovery on further...

  4. An O(M(n) log n) algorithm for the Jacobi symbol

    E-Print Network [OSTI]

    Zimmermann, Paul

    An O(M(n) log n) algorithm for the Jacobi symbol Richard P. Brent1 and Paul Zimmermann2 1 January 2010 Abstract. The best known algorithm to compute the Jacobi symbol of two n-bit integers runs Introduction We want to compute the Jacobi symbol3 (b|a) for n-bit integers a and b, where a is odd positive

  5. Evaluation of Non-Nuclear Techniques for Well Logging: Final Report

    SciTech Connect (OSTI)

    Bond, Leonard J.; Griffin, Jeffrey W.; Harris, R. V.; Denslow, Kayte M.; Moran, Traci L.

    2011-08-01

    The focus of this study is the understanding of the technical obstacles that hinder the replacement of and the disadvantages from the loss of extensive interpretation experience based on data accumulated with AmBe. Enhanced acoustic and electromagnetic sensing methods in combination with non-isotope-based well logging techniques have the potential to complement and/or replace existing isotope-based techniques, providing the opportunity to reduce oil industry dependence on isotopic sources such as AmBe.

  6. DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act.

    E-Print Network [OSTI]

    1 DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act. DATE. of Bolivar St. A-005-10 Slip and Fall 1-18-10 Signal 21 425 S. Roman St. A-006-10 Keep Off Property 1 1100 Florida Ave. A-010-10 Vehicle Damage 1-25-10 Signal 21 425 S. Roman St. A-011-10 Power Outage 1

  7. DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act.

    E-Print Network [OSTI]

    DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act. DATEB 425 S. Roman St. A-016-13 Theft of bicycle 1/23/13 Signal 21 1900 Perdido St. A-017-13 Medical With The Student Right To Know Act. DATE OFFENSE LOCATION ITEM NUMBER COMMENTS 2/1/13 Signal 21 1100 Florida Ave. B

  8. DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act.

    E-Print Network [OSTI]

    1 DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act. DATE. Roman St. A-008-09 Parked car rolls back into another parked car 1-23-09 Signal 21L 1100 Florida Ave. A With The Student Right To Know Act. DATE OFFENSE LOCATION ITEM NUMBER COMMENTS 2-27-09 Signal 21 1100 Florida Ave

  9. DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act.

    E-Print Network [OSTI]

    DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act. DATE-12 Stolen Bike 1/17/12 Signal 21 425 S. Roman St. A-009-12 Damage to Vehicle 1/18/12 Signal 21 1100 Florida/25/12 Signal 24 1900 Gravier St. A-016-12 Medical Emergency 1/30/12 Signal 20 425 S. Roman St. A-017-12 Vehicle

  10. DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act.

    E-Print Network [OSTI]

    1 DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act. DATE Gravier St. A-008-11 Subject allegedly stalking employee 1-19-11 Signal 20 Tulane and Roman Sts. A-009 (Perdido Lot) A-012-11 Auto accident 1/25/11 Signal 21L 136 S. Roman St. A-013-11 Lost or stolen internet

  11. DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act.

    E-Print Network [OSTI]

    1 DAILY CRIME LOG This Information Is Posted In Compliance With The Student Right To Know Act. DATE-08 Student hit parked vehicles 3-6-08 Signal 21 425 S. Roman St. C-001-08 Damage to parked vehicle 3-7-08 Signal 21 1900 Perdido St. C-002-08 Damage to vehicle 3-7-08 Signal 21 425 S. Roman St. C-003-08 Damage

  12. Method of making sintered ductile intermetallic-bonded ceramic composites

    DOE Patents [OSTI]

    Plucknett, K.; Tiegs, T.N.; Becher, P.F.

    1999-05-18

    A method of making an intermetallic-bonded ceramic composite involves combining a particulate brittle intermetallic precursor with a particulate reactant metal and a particulate ceramic to form a mixture and heating the mixture in a non-oxidizing atmosphere at a sufficient temperature and for a sufficient time to react the brittle intermetallic precursor and the reactant metal to form a ductile intermetallic and sinter the mixture to form a ductile intermetallic-bonded ceramic composite. 2 figs.

  13. Proton magnetic resonance studies of the chemical shifts occurring in propionic acid-dioxane solutions 

    E-Print Network [OSTI]

    Oldham, William J. Bryan

    1958-01-01

    ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 0 ~ ~ ~ 35 LIET OF TABES TAEIR6 l, Chemical shiftsoccurring in aqueous solutions of propionic PAGE ac id ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 21 2, Chemical shifts occurring in propionic ac1d-dioxane solut1ons 22 3. C... is added. , the dimers break up to form monomers. There i, s formed alternately a hydrogen bond between the monomer ac1d and the water, forming a complex. If the correlation times of the diner state aud oomplex water state ere sufficiently smallv...

  14. Chemical Hygiene and Safety Plan

    E-Print Network [OSTI]

    Ricks Editor, R.

    2009-01-01

    V. , Ed. , Safety in the Chemical Laboratory. J. Chem.Łd. Amer/can Chemical Society. Easlon. PA. 18042. Vol. Lof Laboratory Safety. the Chemical Rubber Company Cleveland.

  15. Siphons in Chemical Reaction Networks

    E-Print Network [OSTI]

    Shiu, Anne; Sturmfels, Bernd

    2010-01-01

    strongly-connected chemical reaction, and the compu- tationcredited. Siphons in Chemical Reaction Networks Referencesto persistence analysis in chemical reaction networks. In:

  16. Modeling of capillary pressure behavior using standard open hole wireline log data: Demonstrated on carbonates from the Middle East

    SciTech Connect (OSTI)

    Ross, C.M. [Rice Univ., Houston, TX (United States); Callender, C.A.; Turbeville, J.B. [and others

    1995-12-31

    A new technique was developed to model capillary pressure behavior from wireline log data and applied to carbonate reservoir rock from a Saudi Aramco field. The method utilizes image analysis of petrographic thin sections, capillary pressure measurements, and neural network analysis of standard open hole wireline log data. Twenty capillary pressure curves and their associated pore type proportions (identified in thin section) are the basis for the capillary pressure predictive model for the reservoir interval under study. Neural network analysis of the wireline log data was used to continuously predict pore type proportions downhole. The neural network-derived pore proportions were than applied in constructing wireline log-based capillary pressure curves using the capillary pressure predictive model. This method provides an accurate means of determining capillary pressure behavior from wireline log data and extends the applicability of the limited number of available capillary pressure curves. Once trained, the neural network may be applied to other wells in the field as long as the training set (both rock samples and wireline log types) is representative within the study area. The capillary pressure curves predicted from wireline log data can be used for the same purposes as capillary pressure curves measured on core samples, such as determining water saturation in intervals above and within the transition zone.

  17. Bonded Bracket Assmebly for Frameless Solar Panels

    SciTech Connect (OSTI)

    Murray, Todd

    2013-01-30

    In February 2011 the US Department of Energy announced their new Sunshot Initiative. The Sunshot goal is to reduce the total cost of solar energy systems by about 75 percent before the end of the decade. The DOE estimated that a total installed cost of $1 per watt for photovoltaic systems would be equivalent to 6���¢/kilowatt hour (kWh) for energy available from the grid. The DOE also estimated that to meet the $1 per watt goal, PV module costs would need to be reduced to $.50 per watt, balance of systems costs would need to be reduced to $.40 per watt, and power electronic costs would need to reach $.10 per watt. To address the BOS balance of systems cost component of the $1 per watt goal, the DOE announced a funding opportunity called (BOS-X) Extreme Balance of System Hardware Cost Reductions. The DOE identified eight areas within the total BOS costs: 1) installation labor, 2) installation materials, 3) installation overhead and profit, 4) tracker, 5) permitting and commissioning, 6) site preparation, 7) land acquisition, 8) sales tax. The BOS-X funding announcement requested applications in four specific topics: Topic 1: Transformational Building Integrated Photovoltaic (BIPV) Modules Topic 2: Roof and Ground Mount Innovations Topic 3: Transformational Photovoltaic System Designs Topic 4: Development of New Wind Load Codes for PV Systems The application submitted by ARaymond Tinnerman reflected the requirements listed in Topic #2, Roof and Ground Mount Innovations. The goal of topic #2 was to develop technologies that would result in the extreme reduction of material and labor costs associated with applications that require physical connections and attachments to roof and ground mount structures. The topics researched in this project included component cost reduction, labor reduction, weight reduction, wiring innovations, and alternative material utilization. The project objectives included: 1) The development of an innovative quick snap bracket assembly that would be bonded to frameless PV modules for commercial rooftop installations. 2) The development of a composite pultruded rail to replace traditional racking materials. 3) In partnership with a roofing company, pilot the certification of a commercial roof to be solar panel compliant, eliminating the need for structural analysis and government oversight resulting in significantly decreased permitting costs. 4) Reduce the sum of all cost impacts in topic #2 from a baseline total of $2.05/watt to $.34/watt.

  18. Wyss Institute Chemical Hygiene Plan CHEMICAL HYGIENE PLAN

    E-Print Network [OSTI]

    Napp, Nils

    Wyss Institute Chemical Hygiene Plan CHEMICAL HYGIENE PLAN The Wyss Institute for Biologically Inspired Engineering June 2015 #12;Wyss Institute Chemical Hygiene Plan TABLE OF CONTENTS 1.0 POLICY..........................................................................................2 2.1 CHEMICAL HYGIENE OFFICER

  19. The Breathing Orbital Valence Bond Method in Diffusion Monte Carlo: C-H Bond Dissociation of Acetylene

    E-Print Network [OSTI]

    Braida, Benoit

    2009-01-01

    Quantum Chem. 2005, (19) Barnett, R. N. ; Sun, Z. ; Lester,In a systematic DMC study, Barnett et al. 19 explored thefor the C-H bond distance. Barnett et al. reported 1-CSF DMC

  20. Volume 145,number I CHEMICAL PHYSICS LETTERS 18March 1988 HYDROPHOBIC INTERACTION BETWEEN A METHANE MOLECULE

    E-Print Network [OSTI]

    Berne, Bruce J.

    . This is equivalent to study- ing the hydrophobic driving force of a small hydro- carbon towards a large hydrophobic perturbs the water structure in such a way as to minimize the loss of hydrogen bonds. For small non CHEMICAL PHYSICS LETTERS 18March 1988 considers a small sphere near a large sphere it is dif- ficult

  1. Bond-valence methods for pKa prediction. II. Bond-valence, electrostatic, molecular geometry, and solvation effects

    SciTech Connect (OSTI)

    Bickmore, Barry R.; Rosso, Kevin M.; Tadanier, Christopher J.; Bylaska, Eric J.; Doud, Darrin

    2006-08-15

    In a previous contribution, we outlined a method for predicting (hydr)oxy-acid and oxide surface acidity constants based on three main factors: bond valence, Me?O bond ionicity, and molecular shape. Here electrostatics calculations and ab initio molecular dynamics simulations are used to qualitatively show that Me?O bond ionicity controls the extent to which the electrostatic work of proton removal departs from ideality, bond valence controls the extent of solvation of individual functional groups, and bond valence and molecular shape controls local dielectric response. These results are consistent with our model of acidity, but completely at odds with other methods of predicting acidity constants for use in multisite complexation models. In particular, our ab initio molecular dynamics simulations of solvated monomers clearly indicate that hydrogen bonding between (hydr)oxo-groups and water molecules adjusts to obey the valence sum rule, rather than maintaining a fixed valence based on the coordination of the oxygen atom as predicted by the standard MUSIC model.

  2. Bonding exterior grade structural panels with copolymer resins of biomass residue components, phenol, and formaldehyde

    SciTech Connect (OSTI)

    Chen, C.M. [Univ. of Georgia, Athens, GA (United States)

    1993-12-31

    Components of various forest and agricultural residue biomass-including the polyphenolic compounds-were converted into aqueous solution and/or suspension by extraction and digestion. Some biomass components reacted vigorously under alkaline catalysis with formaldehyde and initially showed a high degree of exothermic reaction; however, other components did not react as vigorously under these conditions, indicating that different biomass materials require different methods to obtain optimum reactivity for the copolymerization with phenol. Our primary goal is to develop adhesives capable of producing acceptable bond quality, as determined by the wood products industries` standards, under a reasonable range of gluing conditions. Copolymer resins of phenol, formaldehyde, and biomass components were synthesized and evaluated for gluability of bonding exterior grade structural replaced with chemicals derived from peanut hulls, pecan shell flour, pecan pith, southern pine bark, and pine needle required shorter press times. These resins also tolerated a broader range of gluing conditions. In summary, it appears that the technology of the fast curing copolymer resins of biomass components as adhesives for wood products has been developed and is ready to be transferred to industrial practice.

  3. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 102, NO. B8, PAGES 18,391-18,403, AUGUST 10, 1997 Spectral analyses of the KTB sonic and density logs

    E-Print Network [OSTI]

    Jones, Alan G.

    , coherences and transfer functions ofthe Gennan Continental Deep Drilling Program (KTB) sonic and density logs is that fluctuations in the physical logs in the intermediate wavelength range (-10-150 m) are dominated by cracks ofborehole logs. Traditionally, deep boreholes (1000 m or deeper) in crystal- line rocks were drilled

  4. Inversion-based method for interpretation of logging-while-drilling density measurements acquired in high-angle and horizontal wells

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    Inversion-based method for interpretation of logging-while-drilling density measurements acquired-based inversion method to improve the petrophysical interpretation of logging-while-drilling density measurements measurements. INTRODUCTION Conventional processing of logging-while-drilling (LWD) den- sity measurements

  5. Mild Catalytic methods for Alkyl-Alkyl Bond Formation

    SciTech Connect (OSTI)

    Vicic, David A

    2009-08-10

    Overview of Research Goals and Accomplishments for the Period 07/01/06 – 06/30/07: Our overall research goal is to transform the rapidly emerging synthetic chemistry involving alkyl-alkyl cross-couplings into more of a mechanism-based field so that that new, rationally-designed catalysts can be performed under energy efficient conditions. Our specific objectives for the previous year were 1) to obtain a proper electronic description of an active catalyst for alkyl-alkyl cross-coupling reactions and 2) to determine the effect of ligand structure on the rate, scope, selectivity, and functional group compatibility of C(sp3)-C(sp3) cross-coupling catalysis. We have completed both of these initial objectives and established a firm base for further studies. The specific significant achievements of the current grant period include: 1) we have performed magnetic and computational studies on (terpyridine)NiMe, an active catalyst for alkyl-alkyl cross couplings, and have discovered that the unpaired electron resides heavily on the terpyridine ligand and that the proper electronic description of this nickel complex is a Ni(II)-methyl cation bound to a reduced terpyridine ligand; 2) we have for the first time shown that alkyl halide reduction by terpyridyl nickel catalysts is substantially ligand based; 3) we have shown by isotopic labeling studies that the active catalyst (terpyridine)NiMe is not produced via a mechanism that involves the formation of methyl radicals when (TMEDA)NiMe2 is used as the catalyst precursor; 4) we have performed an extensive ligand survey for the alkyl-alkyl cross-coupling reactions and have found that electronic factors only moderately influence reactivity in the terpyridine-based catalysis and that the most dramatic effects arise from steric and solubility factors; 5) we have found that the use of bis(dialkylphosphino)methanes as ligands for nickel does not produce active catalysts for cross-coupling but rather leads to bridging hydride complexes of varying geometries; 6) we have determined that the geometry of aforementioned bridging hydride complexes is largely determined by external forces such as hydrogen bonding interactions and crystal packing forces; 7) we have found that the rate of reductive elimination of alkane from a (pyridyl-2-pyrrolide)AuMe2 complex is severely inhibited due to the rigid geometry of the pyridyl-2-pyrrolide ligand; 8) we have prepared, structurally characterized, and explored the reactivity of 1-adamantylzinc reagents as model nucleophiles for sterically challenging alkyl-alkyl cross-coupling reactions. The continued success of this work will lead to alkyl-alkyl cross-coupling catalysts with broad scope and selectivities. The work has potential to significantly impact science and technologies of interest to the DOE as the chemistry is focused on developing useful reactions using reagents that can be directly prepared from petroleum and natural gas feedstocks. Moreover, the developing synthetic chemistry can profoundly affect the way materials, fine chemicals, and drugs are made. Since the methodology we are developing can shorten existing synthetic protocols, proceed at room temperature, and operate under environmentally benign conditions, it can greatly reduce energy expenditures, especially considering the contribution of the chemical manufacturing field to the gross domestic product.

  6. Raman microscopy as a defect microprobe for hydrogen bonding characterization in materials used in fusion applications

    E-Print Network [OSTI]

    Pardanaud, Cédric; Martin, Céline; Roubin, Pascale; Pegourié, Bernard; Oberkofler, Martin; Köppen, Martin; Dittmar, Timo; Linsmeier, Christian

    2014-01-01

    We present the Raman microscopy ability to detect and characterize the way hydrogen is bonded with elements that will be used for ITER's plasma facing components. For this purpose we first use hydrogenated amorphous carbon samples, formed subsequently to plasma-wall interactions (hydrogen implantation, erosion, deposition...) occurring inside tokamaks, to demonstrate how this technique can be used to retrieve useful information. We pay attention in identifying which spectroscopic parameters are sensitive to the local structure (sp 3 /sp 2) and which gives information on the hydrogen content using isothermal and linear temperature ramp studies on reference samples produced by plasma enhanced chemical vapor deposition. We then focus on the possibility to use this fast, non-destructive and non-contact technique to characterize the influence of hydrogen isotope implantation in few nanometers of graphite and beryllium as C is still used in the JT-60 tokamak and Be is used in JET and will be used as plasma-facing c...

  7. The C OH O hydrogen bond: A determinant of stability and specificity

    E-Print Network [OSTI]

    Senes, Alessandro

    recovered by hydro- gen bond formation, so hydrogen bonds provide a small or even unfavorable net energy hydro- gen bond has been unclear and its interaction energy has been believed to be small. Recently that apparent carbon hydro- gen bonds cluster frequently at glycine-, serine-, and threonine-rich packing

  8. Hydrogen bonding between neon and hydrogen fluoride M. Losonczy and J. W. Moskowitz*

    E-Print Network [OSTI]

    Stillinger, Frank

    Hydrogen bonding between neon and hydrogen fluoride M. Losonczy and J. W. Moskowitz* Chemistry of hydrogen fluoride. The results exhibit formation of a linear hydrogen bond. Although this bond is weak (0.234 kcal!mole), its strength exceeds that found earlier for the neon-water hydrogen bond. I. INTRODUCTION

  9. A new hydrogen-bonding potential for the design of proteinRNA interactions predicts specific

    E-Print Network [OSTI]

    Baker, David

    A new hydrogen-bonding potential for the design of protein­RNA interactions predicts specific-dependent hydrogen-bonding potential based on the statistical analysis of hydrogen-bonding geometries of hydrogen-bonding atom pairs at protein­ nucleic acid interfaces. A scoring function based on the hydrogen

  10. Thermal Performance and Reliability of Bonded Interfaces for Power Electronics Packaging Applications (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2013-07-01

    This presentation discusses the thermal performance and reliability of bonded interfaces for power electronics packaging applications.

  11. Comparison of bond character in hydrocarbons and fullerenes D. W. Snoke

    E-Print Network [OSTI]

    Snoke, David

    Comparison of bond character in hydrocarbons and fullerenes D. W. Snoke Department of Physics a comparison of the bond polarizabilities for carbon-carbon bonds in hydrocarbons and fullerenes, using two and ethylene. We find that the polarizabilities for single bonds in fullerenes and hydrocarbons compare well

  12. Chemical Stabilization of Hanford Tank Residual Waste

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Um, Wooyong; Williams, Benjamin D.; Bowden, Mark E.; Gartman, Brandy N.; Lukens, Wayne W.; Buck, Edgar C.; Mausolf, Edward J.

    2014-03-01

    Three different chemical treatment methods were tested for their ability to stabilize residual waste from Hanford tank C-202 for reducing contaminant release (Tc, Cr, and U in particular). The three treatment methods tested were lime addition [Ca(OH)2], an in-situ Ceramicrete waste form based on chemically bonded phosphate ceramics, and a ferrous iron/goethite treatment. These approaches rely on formation of insoluble forms of the contaminants of concern (lime addition and ceramicrete) and chemical reduction followed by co-precipitation (ferrous iron/goethite incorporation treatment). The results have demonstrated that release of the three most significant mobile contaminants of concern from tank residual wastes can be dramatically reduced after treatment compared to contact with simulated grout porewater without treatment. For uranium, all three treatments methods reduced the leachable uranium concentrations by well over three orders of magnitude. In the case of uranium and technetium, released concentrations were well below their respective MCLs for the wastes tested. For tank C-202 residual waste, chromium release concentrations were above the MCL but were considerably reduced relative to untreated tank waste. This innovative approach has the potential to revolutionize Hanford’s tank retrieval process, by allowing larger volumes of residual waste to be left in tanks while providing an acceptably low level of risk with respect to contaminant release that is protective of the environment and human health. Such an approach could enable DOE to realize significant cost savings through streamlined retrieval and closure operations.

  13. Chemical Reaction due to Stronger Ramachandran Interaction

    E-Print Network [OSTI]

    Andrew Das Arulsamy

    2013-12-26

    The origin of a chemical reaction between two reactant atoms is associated to the activation energy, with the assumption that, high-energy collisions between these atoms, are the ones that overcome the activation energy. Here, we (i) show that a stronger attractive van der Waals (vdW) and electron-ion Coulomb interactions between two polarized atoms are responsible to initiate a chemical reaction, either before or after the collision. We derive this stronger vdW attraction formula exactly using the quasi one-dimensional Drude model within the ionization energy theory and the energy-level spacing renormalization group method. Along the way, we (ii) expose the precise physical mechanism responsible for the existence of a stronger vdW interaction for both long and short distances, and also show how to technically avoid the electron-electron Coulomb repulsion between polarized electrons from these two reactant atoms. Finally, we properly and correctly associate the existence of this stronger attraction to Ramachandran's 'normal limits' (distance shorter than what is allowed by the standard vdW bond) between chemically nonbonded atoms.

  14. Interfacial structure, bonding and composition of InAs and GaSb thin films determined using coherent Bragg rod analysis.

    SciTech Connect (OSTI)

    Cionca, C.; Walko, D. A.; Yacoby, Y.; Dorin, C.; Millunchick, J. M.; Clarke, R.; X-Ray Science Division; Univ. of Michigan; Hebrew Univ.

    2007-01-01

    We have used Bragg rod x-ray diffraction combined with a direct method of phase retrieval to extract atomic resolution electron-density maps of a complementary series of heteroepitaxial III-V semiconductor samples. From the three-dimensional electron-density maps we derive the monolayer spacings, the chemical compositions, and the characteristics of the bonding for all atomic planes in the film and across the film-substrate interface. InAs films grown on GaSb(001) under two different As conditions (using dimer or tetramer forms) both showed conformal roughness and mixed GaAs/InSb interfacial bonding character. The As tetramer conditions favored InSb bonding at the interface while, in the case of the dimer, the percentages corresponding to GaAs and InSb bonding were equal within the experimental error. The GaSb film grown on InAs(001) displayed significant In and As interdiffusion and had a relatively large fraction of GaAs-like bonds at the interface.

  15. Mechanism and Site Requirements for Activation and Chemical Conversion of Methane on Supported Pt Clusters and Turnover Rate Comparisons among Noble Metals

    E-Print Network [OSTI]

    Iglesia, Enrique

    Mechanism and Site Requirements for Activation and Chemical Conversion of Methane on Supported Pt smaller than the rate of methane chemical conversion in CO2 and H2O reforming reactions; thus, C-H bond and Pt2,3,8-32 lead to H2/CO mixtures useful as precursors to fuels and petrochemicals. Pt appears

  16. Investigation of the high-frequency wavefield of an off-center monopole acoustic logging-while-drilling tool

    E-Print Network [OSTI]

    Wang, Hua

    During logging-while-drilling (LWD) operations, complex drill string movements and the weight of the drill pipe often lead to a measurement tool that is not centralized. Therefore, studies of the response of an off-center ...

  17. Supplementary Materials Table 1: Simulated log-normal survival data marginal posterior probability of inclusion of relevant

    E-Print Network [OSTI]

    Vannucci, Marina

    .1835 Table 1: Simulated log-normal survival data: Marginal posterior probabilities of inclusion of rele- vant: Marginal posterior probabilities of inclusion of rele- vant variables under different maximum correlation

  18. Method of assaying uranium with prompt fission and thermal neutron borehole logging adjusted by borehole physical characteristics. [Patient application

    DOE Patents [OSTI]

    Barnard, R.W.; Jensen, D.H.

    1980-11-05

    Uranium formations are assayed by prompt fission neutron logging techniques. The uranium in the formation is proportional to the ratio of epithermal counts to thermal or epithermal dieaway. Various calibration factors enhance the accuracy of the measurement.

  19. Numerical simulation of borehole acoustic logging in the frequency and time domains with hp-adaptive finite elements

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    for Computational Engineering and Sciences (ICES), The University of Texas at Austin, 201 East 24th Street, ACES and for the improvement of acoustic logging techniques used by oil- and oil-service companies to detect and quantify

  20. Field emission chemical sensor

    DOE Patents [OSTI]

    Panitz, J.A.

    1983-11-22

    A field emission chemical sensor for specific detection of a chemical entity in a sample includes a closed chamber enclosing two field emission electrode sets, each field emission electrode set comprising (a) an electron emitter electrode from which field emission electrons can be emitted when an effective voltage is connected to the electrode set; and (b) a collector electrode which will capture said electrons emitted from said emitter electrode. One of the electrode sets is passive to the chemical entity and the other is active thereto and has an active emitter electrode which will bind the chemical entity when contacted therewith.