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Sample records for bon di ox

  1. Bons Ventos Geradora de Energia S A | Open Energy Information

    Open Energy Info (EERE)

    Bons Ventos Geradora de Energia S A Jump to: navigation, search Name: Bons Ventos Geradora de Energia S.A. Place: Fortaleza, Ceara, Brazil Sector: Wind energy Product:...

  2. Bon Homme Yankton El Assn, Inc | Open Energy Information

    Open Energy Info (EERE)

    Bon Homme Yankton El Assn, Inc Jump to: navigation, search Name: Bon Homme Yankton El Assn, Inc Place: South Dakota Phone Number: (605) 463-2507 Website: byelectric.com Facebook:...

  3. Bon Homme County, South Dakota: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Homme County, South Dakota Broin Enterprises Places in Bon Homme County, South Dakota Avon, South Dakota Scotland, South Dakota Springfield, South Dakota Tabor, South Dakota...

  4. Di?partment o

    Office of Legacy Management (LM)

    ,Di?partment o f E n e r g y ' ' ' : . ' ~' Washington, DC 20585 ., .* -,, : ', ," FEE 17.,1995' , :' ' , ,,- ',/ 'he Honorable Larry.Guidt ' ' : X 1455 W., 126th Street lawthorne; California 90250 1 _. _ tear.Mayor Guidi: ; ..,, _ ietretary of Energy Hazel O'Leary,has announced a new approach to openness.in :he Department .of Energy (DOE) and its communications wifh,the public: In ; - upport of thts initiative, we are ,p;T.eased to forward the enclosed,,information .,~ -elated to the

  5. Politecnico di Milano | Open Energy Information

    Open Energy Info (EERE)

    Politecnico di Milano Jump to: navigation, search Name: Politecnico di Milano Place: Milan, Italy Zip: 20133 Sector: Solar Product: Milan-based technical university. The institute...

  6. Emcore DI Semicon JV | Open Energy Information

    Open Energy Info (EERE)

    Place: Korea (Republic) Product: Emcore and DI Semicon combine forces in a South Korean joint venture to manufacture PV systems. References: Emcore & DI Semicon JV1 This...

  7. Overall Photocatalytic Water Splitting with NiOx-SrTiO3 A Revised Mechanism

    SciTech Connect (OSTI)

    Townsend, Troy K.; Browning, Nigel D.; Osterloh, Frank

    2012-11-01

    NiOx (0 < x < 1) modified SrTiO3 (STO) is one of the best studied photocatalyst for overall water splitting under UV light. The established mechanism for this and many other NiOx containing catalysts assumes water oxidation to occur at the early transition metal oxide and water reduction at NiOx. Here we show that NiOx-STO is more likely a three component Ni-STO-NiO catalyst, in which STO absorbs the light, Ni reduces protons, and NiO oxidizes water. This interpretation is based on systematic H2/O2 evolution tests of appropriately varied catalyst compositions using oxidized, chemically and photochemically added nickel and NiO nanoparticle cocatalysts. Surface photovoltage (SPV) measurements reveal that Ni(0) serves as an electron trap (site for water reduction) and that NiO serves as a hole trap (site for water oxidation). Electrochemical measurements show that the overpotential for water oxidation correlates with NiO content, whereas the water reduction overpotential depends on Ni content. Photodeposition experiments with NiCl2 and H2PtCl6 on NiO-STO show that electrons are available on the STO surface, not on the NiO particles. Based on photoelectrochemistry, both NiO and Ni particles suppress the Fermi level in STO, but the effect of this shift on catalytic activity is not clear. Overall, the results suggest a revised role for NiO in NiOx-STO and in many other nickel-containing water splitting systems, including NiOx-La:KTaO3, and many layered perovskites.

  8. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Hyun You; Liu, Ping

    2015-09-21

    Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film supported on Cu(111), CuTiOx/Cu(111), during CO oxidation was explored using density functional theory (DFT). The unique structural frame of CuTiOx is able to stabilize and isolate a single Cu+ site on the terrace, which is previously proposed active for CO oxidation. Furthermore, it is not the case, where the reaction via both the Langmuir–Hinshelwood (LH) and the Mars-van Krevelen (M-vK) mechanisms are hindered on such single Cu+ site. Upon the formation ofmore » step-edges, the synergy among Cuδ+ sites, TiOx matrix, and Cu(111) is able to catalyze the reaction well. Depending on temperatures and partial pressure of CO and O2, the surface structure varies, which determines the dominant mechanism. In accordance with our results, the Cuδ+ ion alone does not work well for CO oxidation in the form of single sites, while the synergy among multiple active sites is necessary to facilitate the reaction.« less

  9. Imaging of electrical response of NiOx under controlled environment with sub-25-nm resolution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jacobs, Christopher B.; Ievlev, Anton V.; Collins, Liam F.; Muckley, Eric S.; Joshi, Pooran C.; Ivanov, Ilia N.

    2016-07-19

    The spatially resolved electrical response of rf-sputtered polycrystalline NiOx films composed of 40 nm crystallites was investigated under different relative humidity levels (RH). The topological and electrical properties (surface potential and resistance) were characterized using Kelvin probe force microscopy (KPFM) and conductive scanning probe microscopy at 0%, 50%, and 80% relative humidity with sub 25nm resolution. The surface potential of NiOx decreased by about 180 mV and resistance decreased in a nonlinear fashion by about 2 G when relative humidity was increased from 0% to 80%. The dimensionality of surface features obtained through autocorrelation analysis of topological, surface potential andmore » resistance maps increased linearly with increased relative humidity as water was adsorbed onto the film surface. Spatially resolved surface potential and resistance of the NiOx films were found to be heterogeneous, with distinct features that grew in size from about 60 nm to 175 nm between 0% and 80% RH levels, respectively. Here, we find that the changes in the heterogeneous character of the NiO films are consistent through the topological, surface potential, and resistance measurements, suggesting that the nanoscale surface potential and resistance properties converge with the mesoscale properties as water is adsorbed onto the NiOx film.« less

  10. Kinetic simulation of the O-X conversion process in dense magnetized plasmas

    SciTech Connect (OSTI)

    Ali Asgarian, M. [Physics Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of) [Physics Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of); Department of Electrical and Computer Engineering, Michigan State University, Michigan 48824-1226 (United States); Verboncoeur, J. P. [Department of Electrical and Computer Engineering, Michigan State University, Michigan 48824-1226 (United States)] [Department of Electrical and Computer Engineering, Michigan State University, Michigan 48824-1226 (United States); Parvazian, A. [Physics Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of)] [Physics Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of); Trines, R. [STFC Rutherford Appleton Laboratory, Didcot (United Kingdom)] [STFC Rutherford Appleton Laboratory, Didcot (United Kingdom)

    2013-10-15

    One scheme for heating a dense magnetized plasma core, such as in a tokamak, involves launching an ordinary (O) electromagnetic wave at the low density edge. It is converted to a reflected extraordinary (X) electromagnetic wave under certain conditions, and then transformed into an electron Bernstein wave able to reach high density regions inaccessible to most other waves. The O-X mode conversion is important in heating and diagnostic processes in different devices such as tokamaks, stellarators, and some types of pinches. The goal of this study has been to demonstrate that the kinetic particle-in-cell (PIC) scheme is suitable for modeling the O-X conversion process as the first step toward a more complete simulation of O-X-B heating. The O-X process is considered and simulated with a kinetic particle model for parameters of the TJ-II stellarator using the PIC code, XOOPIC. This code is able to model the non-monotonic density and the magnetic profile of the TJ-II stellarator. It can also statistically represent the self-consistent distribution function of the plasma, which has not been possible in previous fluid models. By considering the electric and magnetic components of launched and reflected waves, the O-mode and X-mode waves can be detected, and the O-X conversion can be demonstrated. In this work, the optimum angle for conversion efficiency, as predicted by the previous theory and experimentally confirmed, is used. Via considering the power of the launched O-mode wave and the converted X-mode wave, the efficiency of 63% for O-X conversion for the optimum theoretical launch angle of 47{sup ?} is obtained, which is in good agreement with efficiencies computed via full-wave simulations.

  11. MicroRNAs expression in ox-LDL treated HUVECs: MiR-365 modulates apoptosis and Bcl-2 expression

    SciTech Connect (OSTI)

    Qin, Bing; Xiao, Bo; Liang, Desheng; Xia, Jian; Li, Ye; Yang, Huan

    2011-06-24

    Highlights: {yields} We evaluated the role of miRNAs in ox-LDL induced apoptosis in ECs. {yields} We found 4 up-regulated and 11 down-regulated miRNAs in apoptotic ECs. {yields} Target genes of the dysregulated miRNAs regulate ECs apoptosis and atherosclerosis. {yields} MiR-365 promotes ECs apoptosis via suppressing Bcl-2 expression. {yields} MiR-365 inhibitor alleviates ECs apoptosis induced by ox-LDL. -- Abstract: Endothelial cells (ECs) apoptosis induced by oxidized low-density lipoprotein (ox-LDL) is thought to play a critical role in atherosclerosis. MicroRNAs (miRNAs) are a class of noncoding RNAs that posttranscriptionally regulate the expression of genes involved in diverse cell functions, including differentiation, growth, proliferation, and apoptosis. However, whether miRNAs are associated with ox-LDL induced apoptosis and their effect on ECs is still unknown. Therefore, this study evaluated potential miRNAs and their involvement in ECs apoptosis in response to ox-LDL stimulation. Microarray and qRT-PCR analysis performed on human umbilical vein endothelial cells (HUVECs) exposed to ox-LDL identified 15 differentially expressed (4 up- and 11 down-regulated) miRNAs. Web-based query tools were utilized to predict the target genes of the differentially expressed miRNAs, and the potential target genes were classified into different function categories with the gene ontology (GO) term and KEGG pathway annotation. In particular, bioinformatics analysis suggested that anti-apoptotic protein B-cell CLL/lymphoma 2 (Bcl-2) is a target gene of miR-365, an apoptomir up-regulated by ox-LDL stimulation in HUVECs. We further showed that transfection of miR-365 inhibitor partly restored Bcl-2 expression at both mRNA and protein levels, leading to a reduction of ox-LDL-mediated apoptosis in HUVECs. Taken together, our findings indicate that miRNAs participate in ox-LDL-mediated apoptosis in HUVECs. MiR-365 potentiates ox-LDL-induced ECs apoptosis by regulating the

  12. Nitrogen effects on crystallization kinetics of amorphous TiOxNy thin films

    SciTech Connect (OSTI)

    Hukari, Kyle; Dannenberg, Rand; Stach, E.A.

    2001-03-30

    The crystallization behavior of amorphous TiOxNy (x>>y) thin films was investigated by in-situ transmission electron microscopy. The Johnson-Mehl-Avrami-Kozolog (JMAK) theory is used to determine the Avrami exponent, activation energy, and the phase velocity pre-exponent. Addition of nitrogen inhibits diffusion, increasing the nucleation temperature, while decreasing the growth activation energy. Kinetic variables extracted from individual crystallites are compared to JMAK analysis of the fraction transformed and a change of 6 percent in the activation energy gives agreement between the methods. From diffraction patterns and index of refraction the crystallized phase was found to be predominantly anatase.

  13. Effect of filler metal composition on the strength of yttria stabilized zirconia joints brazed with Pd-Ag-CuOx

    SciTech Connect (OSTI)

    Darsell, Jens T.; Weil, K. Scott

    2008-09-08

    The Ag-CuOx system is of interest to be used to be used as an air braze filler metal for joining high temperature electrochemical devices. Previous work has shown that the melting temperatures can be increased by adding palladium to Ag-CuOx and it is expected that this may aid high temperature stability. This work compares the room temperature bend strength of joints made between yttria-stabilized zirconia (YSZ) air brazed using Ag-CuOx without palladium and with 5 and 15mol% palladium additions. It has been found that in general palladium decreases joint strength, especially in low copper oxide compositions filler metals. At high copper oxide contents, brittle fracture through both copper oxide rich phases and the YSZ limits joint strength.

  14. High critical currents in heavily doped (Gd,Y)Ba2Cu3Ox superconductor tapes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Selvamanickam, V.; Gharahcheshmeh, M. Heydari; Xu, A.; Galstyan, E.; Delgado, L.; Cantoni, C.

    2015-01-20

    REBa2Cu3Ox superconductor tapes with moderate levels of dopants have been optimized for high critical current density in low magnetic fields at 77 K, but they do not exhibit exemplary performance in conditions of interest for practical applications, i.e., temperatures less than 50 K and fields of 2–30 T. Heavy doping of REBCO tapes has been avoided by researchers thus far due to deterioration in properties. Here, we report achievement of critical current densities (Jc) above 20 MA/cm2 at 30 K, 3 T in heavily doped (25 mol. % Zr-added) (Gd,Y)Ba2Cu3Ox superconductor tapes, which is more than three times higher thanmore » the Jc typically obtained in moderately doped tapes. Pinning force levels above 1000 GN/m3 have also been attained at 20 K. A composition map of lift factor in Jc (ratio of Jc at 30 K, 3 T to the Jc at 77 K, 0 T) has been developed which reveals the optimum film composition to obtain lift factors above six, which is thrice the typical value. A highly c-axis aligned BaZrO3 (BZO) nanocolumn defect density of nearly 7 × 1011 cm–2 as well as 2–3nm sized particles rich in Cu and Zr have been found in the high Jc films.« less

  15. Mesoporous MnCeOx solid solutions for low temperature and selective oxidation of hydrocarbons

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Pengfei; Lu, Hanfeng; Zhou, Ying; Zhang, Li; Wu, Zili; Yang, Shize; Shi, Hongliang; Zhu, Qiulian; Chen, Yinfei; Dai, Sheng

    2015-10-15

    The development of noble-metal-free heterogeneous catalysts that can realize the aerobic oxidation of C–H bonds at low temperature is a profound challenge in the catalysis community. Here we report the synthesis of a mesoporous Mn0.5Ce0.5Ox solid solution that is highly active for the selective oxidation of hydrocarbons under mild conditions (100–120 °C). Notably, the catalytic performance achieved in the oxidation of cyclohexane to cyclohexanone/cyclohexanol (100 °C, conversion: 17.7%) is superior to those by the state-of-art commercial catalysts (140–160 °C, conversion: 3-5%). Finally, the high activity can be attributed to the formation of a Mn0.5Ce0.5Ox solid solution with an ultrahigh manganesemore » doping concentration in the CeO2 cubic fluorite lattice, leading to maximum active surface oxygens for the activation of C–H bonds and highly reducible Mn4+ ions for the rapid migration of oxygen vacancies from the bulk to the surface.« less

  16. Interporto di Padova | Open Energy Information

    Open Energy Info (EERE)

    Italy Zip: 35127 Product: Based in Italy, Interporto is a center for the integrated logistics and intermodality. References: Interporto di Padova1 This article is a stub. You...

  17. Some Lessons Learned from 20 Years in RedOx Flow Battery R&d | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Some Lessons Learned from 20 Years in RedOx Flow Battery R&d Some Lessons Learned from 20 Years in RedOx Flow Battery R&d Presentation by Steve Clarke, Applied Intellectual Capital, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC. flowcells2012_clarke.pdf (1.38 MB) More Documents & Publications Flow Cells for Energy Storage Workshop Summary Report Flow Cells for Energy Storage Workshop Overview Energy Storage Systems 2014 Peer

  18. DI-MGMT-81861 DOE Changes Version | Department of Energy

    Energy Savers [EERE]

    DI-MGMT-81861 DOE Changes Version DI-MGMT-81861 DOE Changes Version PDF icon DI-MGMT-81861 IPMR DOE Version 20140211 Chgs.pdf More Documents & Publications Integrated Program...

  19. Facon Electronica di Facconi Massimo C | Open Energy Information

    Open Energy Info (EERE)

    Facon Electronica di Facconi Massimo C Jump to: navigation, search Name: Facon Electronica di Facconi Massimo & C Place: Leno, Italy Zip: 25024 Product: Leno-based electrical...

  20. Constructing hierarchical interfaces: TiO2-supported PtFe-FeOx nanowires for room temperature CO oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Huiyuan; Wu, Zili; Dong, Su; Veith, Gabriel M.; Lu, Hanfeng; Zhang, Pengfei; Chai, Song -Hai; Dai, Sheng

    2015-08-05

    This is a report of a facile approach to constructing catalytic active hierarchical interfaces in one-dimensional (1D) nanostructure, exemplified by the synthesis of TiO2-supported PtFe–FeOx nanowires (NWs). The hierarchical interface, constituting atomic level interactions between PtFe and FeOx within each NW and the interactions between NWs and support (TiO2), enables CO oxidation with 100% conversion at room temperature. We identify the role of the two interfaces by probing the CO oxidation reaction with isotopic labeling experiments. Both the oxygen atoms (Os) in FeOx and TiO2 participate in the initial CO oxidation, facilitating the reaction through a redox pathway. Moreover, themore » intact 1D structure leads to the high stability of the catalyst. After 30 h in the reaction stream, the PtFe–FeOx/TiO2 catalyst exhibits no activity decay. These results provide a general approach and new insights into the construction of hierarchical interfaces for advanced catalysis.« less

  1. NREL: Energy Analysis - Nicholas DiOrio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Selected publications Pratt,J., P. Axelrad, K. Larson, B. Lesage, R. Gerren, and N. DiOrio. "Satellite Clock Bias Estimation for iGPS." GPS Solutions 17 (2013): 381-89. Bershenyi, ...

  2. Highly dispersed SiOx/Al2O3 catalysts illuminate the reactivity of isolated silanol sites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mouat, Aidan R.; George, Cassandra; Kobayashi, Takeshi; Pruski, Marek; van Duyne, Richard P.; Marks, Tobin J.; Stair, Peter C.

    2015-09-23

    The reaction of γ-alumina with tetraethylorthosilicate (TEOS) vapor at low temperatures selectively yields monomeric SiOx species on the alumina surface. These isolated (-AlO)3Si(OH) sites are characterized by PXRD, XPS, DRIFTS of adsorbed NH3, CO, and pyridine, and 29Si and 27Al DNP-enhanced solid-state NMR spectroscopy. The formation of isolated sites suggests that TEOS reacts preferentially at strong Lewis acid sites on the γ-Al2O3 surface, functionalizing the surface with “mild” Brønsted acid sites. As a result, for liquid-phase catalytic cyclohexanol dehydration, these SiOx sites exhibit up to 3.5-fold higher specific activity than the parent alumina with identical selectivity.

  3. Structural evolution of epitaxial SrCoOx films near topotactic phase transition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeen, Hyoung Jeen; Lee, Ho Nyung

    2015-12-18

    Control of oxygen stoichiometry in complex oxides via topotactic phase transition is an interesting avenue to not only modifying the physical properties, but utilizing in many energy technologies, such as energy storage and catalysts. However, detailed structural evolution in the close proximity of the topotactic phase transition in multivalent oxides has not been much studied. In this work, we used strontium cobaltites (SrCoOx) epitaxially grown by pulsed laser epitaxy (PLE) as a model system to study the oxidation-driven evolution of the structure, electronic, and magnetic properties. We grew coherently strained SrCoO2.5thin films and performed post-annealing at various temperatures for topotacticmore » conversion into the perovskite phase (SrCoO3-δ). We clearly observed significant changes in electronic transport, magnetism, and microstructure near the critical temperature for the topotactic transformation from the brownmillerite to the perovskite phase. Furthermore, the overall crystallinity was well maintained without much structural degradation, indicating that topotactic phase control can be a useful tool to control the physical properties repeatedly via redox reactions.« less

  4. Catalytic activity in lithium-treated core–shell MoOx/MoS2 nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cummins, Dustin R.; Martinez, Ulises; Kappera, Rajesh; Voiry, Damien; Martinez-Garcia, Alejandro; Jasinski, Jacek; Kelly, Dan; Chhowalla, Manish; Mohite, Aditya D.; Sunkara, Mahendra K.; et al

    2015-09-22

    Significant interest has grown in the development of earth-abundant and efficient catalytic materials for hydrogen generation. Layered transition metal dichalcogenides present opportunities for efficient electrocatalytic systems. Here, we report the modification of 1D MoOx/MoS2 core–shell nanostructures by lithium intercalation and the corresponding changes in morphology, structure, and mechanism of H2 evolution. The 1D nanowires exhibit significant improvement in H2 evolution properties after lithiation, reducing the hydrogen evolution reaction (HER) onset potential by ~50 mV and increasing the generated current density by ~600%. The high electrochemical activity in the nanowires results from disruption of MoS2 layers in the outer shell, leadingmore » to increased activity and concentration of defect sites. This is in contrast to the typical mechanism of improved catalysis following lithium exfoliation, i.e., crystal phase transformation. As a result, these structural changes are verified by a combination of Raman and X-ray photoelectron spectroscopy (XPS).« less

  5. Exclusive e+e-, di-photon and di-jet production at the Tevatron

    SciTech Connect (OSTI)

    Terashi, Koji; /Rockefeller U.

    2007-05-01

    Results from studies on exclusive production of electron-position pair, di-photon, and dijet production at CDF in proton-antiproton collisions at the Fermilab Tevatron are presented. THe first observation and cross section measurements of exclusive e{sup +}e{sup -} and di-jet production in hadron-hadron collisions are emphasized.

  6. Ponte di Archimede International S P A | Open Energy Information

    Open Energy Info (EERE)

    Ponte di Archimede International S P A Jump to: navigation, search Name: Ponte di Archimede International S P A Address: Viale Libert IS 515 Place: Messina Zip: 98121 Region: Italy...

  7. Batteries & Fuel Cells - Research Thrust Leader > Frank DiSalvo...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frank DiSalvo fjd3@cornell.edu Research The DiSalvo Group's research focuses on the synthesis, characterization and potential applications of new solid state materials. Current...

  8. Distributed Solar Power Ltd Di S P | Open Energy Information

    Open Energy Info (EERE)

    Solar Power Ltd Di S P Jump to: navigation, search Name: Distributed Solar Power Ltd (Di.S.P) Place: Yokneam, Israel Zip: 20692 Sector: Solar Product: Distributed Solar Power...

  9. Promotional effect of surface hydroxyls on electrochemical reduction of CO2 over SnOx/Sn electrode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cui, Chaonan; Han, Jinyu; Zhu, Xinli; Liu, Xiao; Wang, Hua; Mei, Donghai; Ge, Qingfeng

    2016-01-16

    In this study, tin oxide (SnOx) formation on tin-based electrode surfaces during CO2 electrochemical reduction can have a significant impact on the activity and selectivity of the reaction. In the present study, density functional theory (DFT) calculations have been performed to understand the role of SnOx in CO2 reduction using a SnO monolayer on the Sn(112) surface as a model for SnOx. Water molecules have been treated explicitly and considered actively participating in the reaction. The results showed that H2O dissociates on the perfect SnO monolayer into two hydroxyl groups symmetrically on the surface. CO2 energetically prefers to react withmore » the hydroxyl, forming a bicarbonate (HCO3(t)*) intermediate, which can then be reduced to either formate (HCOO*) by hydrogenating the carbon atom or carboxyl (COOH*) by protonating the oxygen atom. Both steps involve a simultaneous Csingle bondO bond breaking. Further reduction of HCOO* species leads to the formation of formic acid in the acidic solution at pH < 4, while the COOH* will decompose to CO and H2O via protonation. Whereas the oxygen vacancy (VO) in the oxide monolayer maybe formed by the reduction, it can be recovered by H2O dissociation, resulting in two embedded hydroxyl groups. The results show that the hydroxylated surface with two symmetric hydroxyls is energetically more favorable for CO2 reduction than the hydroxylated VO surface with two embedded hydroxyls. The reduction potential for the former has a limiting-potential of –0.20 V (RHE), lower than that for the latter (–0.74 V (RHE)). Compared to the pure Sn electrode, the formation of SnOx monolayer on the electrode under the operating conditions promotes CO2 reduction more effectively by forming surface hydroxyls, thereby providing a new channel via COOH* to the CO formation, although formic acid is still the major reduction product.« less

  10. Di-hadron production at Jefferson Lab

    SciTech Connect (OSTI)

    Anefalos Pereira, Sergio; et. al.,

    2014-10-01

    Semi-inclusive deep inelastic scattering (SIDIS) has been used extensively in recent years as an important testing ground for QCD. Studies so far have concentrated on better determination of parton distribution functions, distinguishing between the quark and antiquark contributions, and understanding the fragmentation of quarks into hadrons. Hadron pair (di-hadron) SIDIS provides information on the nucleon structure and hadronization dynamics that complement single hadron SIDIS. Di-hadrons allow the study of low- and high-twist distribution functions and Dihadron Fragmentation Functions (DiFF). Together with the twist-2 PDFs ( f1, g1, h1), the Higher Twist (HT) e and hL functions are very interesting because they offer insights into the physics of the largely unexplored quark-gluon correlations, which provide access into the dynamics inside hadrons. The CLAS spectrometer, installed in Hall-B at Jefferson Lab, has collected data using the CEBAF 6 GeV longitudinally polarized electron beam on longitudinally polarized solid NH3 targets. Preliminary results on di-hadron beam-, target- and double-spin asymmetries will be presented.

  11. Di-interstitial defect in silicon revisited

    SciTech Connect (OSTI)

    Londos, C. A.; Antonaras, G.; Chroneos, A.; Department of Materials, Imperial College London, London SW7 2BP

    2013-11-21

    Infrared spectroscopy was used to study the defect spectrum of Cz-Si samples following fast neutron irradiation. We mainly focus on the band at 533 cm{sup ?1}, which disappears from the spectra at ?170 C, exhibiting similar thermal stability with the Si-P6 electron paramagnetic resonance (EPR) spectrum previously correlated with the di-interstitial defect. The suggested structural model of this defect comprises of two self-interstitial atoms located symmetrically around a lattice site Si atom. The band anneals out following a first-order kinetics with an activation energy of 0.88 0.3 eV. This value does not deviate considerably from previously quoted experimental and theoretical values for the di-interstitial defect. The present results indicate that the 533 cm{sup ?1} IR band originates from the same structure as that of the Si-P6 EPR spectrum.

  12. Basic ReseaRch DiRections

    National Nuclear Security Administration (NNSA)

    Basic ReseaRch DiRections for User Science at the National Ignition Facility Report on the National Nuclear Security Administration - Office of Science Workshop on Basic Research Directions on User Science at the National Ignition Facility BASIC RESEARCH DIRECTIONS FOR USER SCIENCE AT THE NATIONAL IGNITION FACILITY Report on the National Nuclear Security Administration (NNSA) - Office of Science (SC) Workshop on Basic Research Directions on User Science at the National Ignition Facility Chairs:

  13. Low pressure CO₂ hydrogenation to methanol over gold nanoparticles activated on a CeOx/TiO₂ interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Xiaofang; Boscoboinik, J. Anibal; Kattel, Shyam; Senanayake, Sanjaya D.; Nie, Xiaowa; Graciani, Jesus; Rodriguez, Jose A.; Liu, Ping; Stacchiola, Dario J.; Chen, Jingguang G.

    2015-07-28

    Capture and recycling of CO₂ into valuable chemicals such as alcohols could help mitigate its emissions into the atmosphere. Due to its inert nature, the activation of CO₂ is a critical step in improving the overall reaction kinetics during its chemical conversion. Although pure gold is an inert noble metal and cannot catalyze hydrogenation reactions, it can be activated when deposited as nanoparticles on the appropriate oxide support. In this combined experimental and theoretical study, it is shown that an electronic polarization at the metal–oxide interface of Au nanoparticles anchored and stabilized on a CeOx/TiO₂ substrate generates active centers formore » CO₂ adsorption and its low pressure hydrogenation, leading to a higher selectivity toward methanol. In conclusion, this study illustrates the importance of localized electronic properties and structure in catalysis for achieving higher alcohol selectivity from CO₂ hydrogenation.« less

  14. ORISE: Recent Graduate Research Experiences - Nicholas DiLucia

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nicholas DiLucia Computer engineer utilizes skills from NETL to update lab website Nicholas DiLucia Nicholas DiLucia returned to the National Energy and Technology Laboratory for the fourth year in a row to engage in website development. His previous internship experiences at the lab helped him succeed in courses at the Univ. of Pittsburgh, where he graduated in April 2012. When Nicholas DiLucia graduated from the Univ. of Pittsburgh in April 2012, he was excited to have a place to go to develop

  15. Kathy DiBennardi | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kathy DiBennardi Executive Secretary Argonne National Laboratory 9700 South Cass Avenue Building 240 - Wkstn. 4D11 Argonne IL, 60439 630-252-8600 dibennar

  16. TianDi Growth Capital | Open Energy Information

    Open Energy Info (EERE)

    Venture capital investor interested in projects in Wind energy, Electric vehicles, Energy-efficient lighting, Biodiesel and Clean water. References: TianDi Growth Capital1...

  17. The susceptibility of TaOx-based memristors to high dose rate ionizing radiation and total ionizing dose

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLain, Michael Lee; Sheridan, Timothy J.; Hjalmarson, Harold Paul; Mickel, Patrick R.; Hanson, Donald J.; McDonald, Joseph K.; Hughart, David Russell; Marinella, Matthew J.

    2014-11-11

    This paper investigates the effects of high dose rate ionizing radiation and total ionizing dose (TID) on tantalum oxide (TaOx) memristors. Transient data were obtained during the pulsed exposures for dose rates ranging from approximately 5.0 ×107 rad(Si)/s to 4.7 ×108 rad(Si)/s and for pulse widths ranging from 50 ns to 50 μs. The cumulative dose in these tests did not appear to impact the observed dose rate response. Static dose rate upset tests were also performed at a dose rate of ~3.0 ×108 rad(Si)/s. This is the first dose rate study on any type of memristive memory technology. Inmore » addition to assessing the tolerance of TaOx memristors to high dose rate ionizing radiation, we also evaluated their susceptibility to TID. The data indicate that it is possible for the devices to switch from a high resistance off-state to a low resistance on-state in both dose rate and TID environments. The observed radiation-induced switching is dependent on the irradiation conditions and bias configuration. Furthermore, the dose rate or ionizing dose level at which a device switches resistance states varies from device to device; the enhanced susceptibility observed in some devices is still under investigation. As a result, numerical simulations are used to qualitatively capture the observed transient radiation response and provide insight into the physics of the induced current/voltages.« less

  18. DiTour 3.1

    Energy Science and Technology Software Center (OSTI)

    2015-06-30

    There is a need for software that allows a tour guide to present different tracks of slides and then return to the default slide show automatically upon completion. A mobile solution is needed for trade shows. DiTour is an iPad/iPhone app that pulls presentation content from a website, stores it on the device and presents it on a connected display. A tour guide can select a track to present and it will automatically return tomore » the default track after a timeout. It offers a mobile solution which is ideal for trade shows.« less

  19. Anion-controlled assembly of silver-di(aminophenyl)sulfone coordinatio...

    Office of Scientific and Technical Information (OSTI)

    Anion-controlled assembly of silver-di(aminophenyl)sulfone coordination polymers: ... Title: Anion-controlled assembly of silver-di(aminophenyl)sulfone coordination polymers: ...

  20. Development of an SI DI Ethanol Optimized Flex Fuel Engine Using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain Development of an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain Presentation given at the ...

  1. Advantages of MgAlOx over gamma-Al2O3 as a support material for potassium-based high temperature lean NOx traps

    SciTech Connect (OSTI)

    Luo, Jinyong; Gao, Feng; Karim, Ayman M.; Xu, Pinghong; Browning, Nigel D.; Peden, Charles HF

    2015-08-07

    MgAlOx mixed oxides were employed as supports for potassium-based lean NOx traps (LNTs) targeted for high temperature applications. Effects of support compositions, K/Pt loadings, thermal aging and catalyst regeneration on NOx storage capacity were systematically investigated. The catalysts were characterized by XRD, NOx-TPD, TEM, STEM-HAADF and in-situ XAFS. The results indicate that MgAlOx mixed oxides have significant advantages over conventional gamma-Al2O3-supports for LNT catalysts, in terms of high temperature NOx trapping capacity and thermal stability. First, as a basic support, MgAlOx stabilizes stored nitrates (in the form of KNO3) to much higher temperatures than mildly acidic gamma-Al2O3. Second, MgAlOx minimizes Pt sintering during thermal aging, which is not possible for gamma-Al2O3 supports. Notably, combined XRD, in-situ XAFS and STEM-HAADF results indicate that Pt species in the thermally aged Pt/MgAlOx samples are finely dispersed in the oxide matrix as isolated atoms. This strong metal-support interaction stabilizes Pt and minimizes the extent of sintering. However, such strong interactions result in Pt oxidation via coordination with the support so that NO oxidation activity can be adversely affected after aging which, in turn, decreases NOx trapping ability for these catalysts. Interestingly, a high-temperature reduction treatment regenerates essentially full NOx trapping performance. In fact, regenerated Pt/K/MgAlOx catalyst exhibits much better NOx trapping performance than fresh Pt/K/Al2O3 LNTs over the entire temperature range investigated here. In addition to thermal aging, Pt/K loading effects were systemically studied over the fresh samples. The results indicate that NOx trapping is kinetically limited at low temperatures, while thermodynamically limited at high temperatures. A simple conceptual model was developed to explain the Pt and K loading effects on NOx storage. An optimized K loading, which allows balancing between the

  2. Hierarchical heterogeneity at the CeOx-TiO? interface: Electronic and geometric structural influence on the photocatalytic activity of oxide on oxide nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    None

    2015-01-13

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravelmorethe local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the

  3. GeOx/Reduced Graphene Oxide Composite as an Anode for Li-ion Batteries: Enhanced Capacity via Reversible Utilization of Li2O along with Improved Rate Performance

    SciTech Connect (OSTI)

    Lv, Dongping; Gordin, Mikhail; Yi, Ran; Xu, Terrence (Tianren); Song, Jiangxuan; Jiang, Yingbing; Choi, Daiwon; Wang, Donghai

    2014-09-01

    A self-assembled GeOx/reduced graphene oxide (GeOx/RGO) composite, where GeOx nanoparticles were grown directly on reduced graphene oxide sheets, was synthesized via a facile one-step reduction approach and studied by X-ray diffraction, transmission electron microscopy, energy dispersive X-ray spectroscopy, electron energy loss spectroscopy elemental mapping, and other techniques. Electrochemical evaluation indicates that incorporation of reduced graphene oxide enhances both the rate capability and reversible capacity of GeOx, with the latter being due to the RGO enabling reversible utilization of Li2O. The composite delivers a high reversible capacity of 1600 mAhg-1 at a current density of 100 mAg-1, and still maintains a capacity of 410 mAhg-1 at a high current density of 20 Ag-1. Owing to the flexible reduced graphene oxide sheets enwrapping the GeOx particles, the cycling stability of the composite was also improved significantly. To further demonstrate its feasibility in practical applications, the synthesized GeOx/RGO composite anode was successfully paired with a high voltage LiNi0.5Mn1.5O4 cathode to form a full cell, which showed good cycling and rate performance.

  4. ORISE: Recent Graduate Research Experiences - Nicholas DiLucia

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... grade due to the prior exposure to C, a very similar programming language to JAVA. This time around, DiLucia will not be headed back to a classroom, since he already graduated. ...

  5. Reducing the Particulate Emission Numbers in DI Gasoline Engines |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy the Particulate Emission Numbers in DI Gasoline Engines Reducing the Particulate Emission Numbers in DI Gasoline Engines Formation of droplets was minimized through optimization of fuel vaporization and distribution avoiding air/fuel zones richer than stoichiometric and temperatures that promote particle formation deer10_klindt.pdf (866.03 KB) More Documents & Publications Bosch Powertrain Technologies Vehicle Emissions Review - 2012 Ethanol Effects on Lean-Burn and

  6. Quench degradation limit of multifilamentary AgBi2Sr2CaCu2Ox round wires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Liyang; Li, Pei; Shen, Tengming; Schwartz, Justin

    2016-02-02

    Understanding safe operating limits of composite superconducting wires is important for the design of superconducting magnets. Here we report measurements of quench-induced critical current density Jc degradation in commercial Ag/Bi2Sr2CaCu2Ox (Bi-2212) round wires using heater-induced quenches at 4.2 K in self magnetic field that reveal a general degradation behavior. Jc degradation strongly depends on the local hot spot temperature Tmax, and is nearly independent of operating current, the temperature gradient along the conductor dTmax/dx, and the temperature rising rate dTmax/dt. Both Jc and n value (where n is an index of the sharpness of the superconductor-to-normal transition) exhibit small butmore » irreversible degradation when Tmax exceeds 400-450 K, and large degradation occurs when Tmax exceeds 550 K. This behavior was consistently found for a series of Bi-2212 wires with widely variable wire architectures and porosity levels in the Bi-2212 filaments, including a wire processed using a standard partial melt processing and in which Bi-2212 filaments are porous, an overpressure processed wire in which Bi-2212 filaments are nearly porosity-free and that has a Jc(4.2 K, self field) exceeding 8000 A/mm2, and a wire that has nearly no filament to filament bridges after reaction. Microstructural observations of degraded wires reveal cracks in the Bi-2212 filaments perpendicular to the wire axis, indicating that the quench-induced Ic degradation is primarily driven by strain. These results further suggest that the quench degradation temperature limit depends on the strain state of Bi-2212 filaments and this dependence shall be carefully considered when engineering a high-field Bi-2212 magnet.« less

  7. Xiang Ge Li La Xian Mai Di He Hydro Power Development Co Ltd...

    Open Energy Info (EERE)

    Xiang Ge Li La Xian Mai Di He Hydro Power Development Co Ltd Jump to: navigation, search Name: Xiang Ge Li La Xian Mai Di He Hydro Power Development Co., Ltd. Place: Yunnan...

  8. ParaDiS-FEM dislocation dynamics simulation code primer (Technical...

    Office of Scientific and Technical Information (OSTI)

    ParaDiS-FEM dislocation dynamics simulation code primer Citation Details In-Document Search Title: ParaDiS-FEM dislocation dynamics simulation code primer You are accessing a ...

  9. Microsoft Word - SWPF-15-DI-001_R1_Construction Turnover to C...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Construction Turnover to Testing and Commissioning Oversight SWPF-15-DI-001, Rev. 1 September, 2015 SWPF-15-DI-001 Revision 1 Page 3 of 29 REV A Internal Review by DOE Construction ...

  10. Mechanisms of Selective Cleavage of C-O Bonds in Di-aryl Ethers...

    Office of Scientific and Technical Information (OSTI)

    Selective Cleavage of C-O Bonds in Di-aryl Ethers in Aqueous Phase Citation Details In-Document Search Title: Mechanisms of Selective Cleavage of C-O Bonds in Di-aryl Ethers in ...

  11. Average and local crystal structures of (Ga1–xZnx)(N1–xOx) solid solution nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feygenson, Mikhail; Neuefeind, Joerg C.; Tyson, Trevor A.; Schieber, Natalie; Han, Wei -Qiang

    2015-11-06

    We report the comprehensive study of the crystal structure of (Ga1–xZnx)(N1–xOx) solid solution nanoparticles by means of neutron and synchrotron x-ray scattering. In our study we used four different types of (Ga1–xZnx)(N1–xOx) nanoparticles, with diameters of 10–27 nm and x = 0.075–0.51, which show the narrow energy-band gaps from 2.21 to 2.61 eV. The Rietveld analysis of the neutron diffraction data revealed that the average crystal structure is the hexagonal wurtzite (space group P63mc), in agreement with previous reports on similar bulk materials. The pair-distribution function (PDF) analysis of the same data found that the local structure is more disorderedmore » than the average one. It is best described by the model with a lower symmetry space group P1, where atoms are quasirandomly distorted from their nominal positions in the hexagonal wurtzite lattice.« less

  12. Total ionizing dose effect of γ-ray radiation on the switching characteristics and filament stability of HfOx resistive random access memory

    SciTech Connect (OSTI)

    Fang, Runchen; Yu, Shimeng; Gonzalez Velo, Yago; Chen, Wenhao; Holbert, Keith E.; Kozicki, Michael N.; Barnaby, Hugh

    2014-05-05

    The total ionizing dose (TID) effect of gamma-ray (γ-ray) irradiation on HfOx based resistive random access memory was investigated by electrical and material characterizations. The memory states can sustain TID level ∼5.2 Mrad (HfO{sub 2}) without significant change in the functionality or the switching characteristics under pulse cycling. However, the stability of the filament is weakened after irradiation as memory states are more vulnerable to flipping under the electrical stress. X-ray photoelectron spectroscopy was performed to ascertain the physical mechanism of the stability degradation, which is attributed to the Hf-O bond breaking by the high-energy γ-ray exposure.

  13. 15N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOx/CeO2

    SciTech Connect (OSTI)

    Kwak, Ja Hun; Szanyi, Janos

    2014-12-23

    Pulsing 15N18O onto an annealed 1% Mn16Ox/Ce16O2 catalyst resulted in very fast oxygen isotope exchange and 15N2 formation at 295 K. In the 1st 15N18O pulse, due to the presence of large number of surface oxygen defects, extensive 15N218O and 15N2 formations were observed. In subsequent pulses oxygen isotope exchange dominated as a result of highly labile oxygen in the oxide. We gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy/Vehicle Technologies Program for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOEs Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle.

  14. Ryo Wakabayashi > Graduate Student - DiSalvo Group > Researchers, Postdocs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Graduates > The Energy Materials Center at Cornell Ryo Wakabayashi Graduate Student - DiSalvo Group rhw224@cornell.edu

  15. Photocatalytic splitting of water under visible-light irradiation over the NiOx-loaded Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration

    SciTech Connect (OSTI)

    Tang Xinde; Ye Hongqi; Liu Hui; Ma Chenxia; Zhao Zhi

    2010-01-15

    A new visible-light-response photocatalyst Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration crystallized in a cubic system with the space group Fd3m was synthesized by a solid-state reaction method. NiOx-loaded Sm{sub 2}InTaO{sub 7} showed high photocatalytic activities for H{sub 2} evolution from pure water under visible light irradiation (lambda>400 nm). Changes in the photocatalytic activity with the calcination temperature of Sm{sub 2}InTaO{sub 7} and the amount of NiOx loaded indicated that the combination of highly crystallized Sm{sub 2}InTaO{sub 7} and a high dispersion of NiOx particles led to high photocatalytic activity. The high photocatalytic performance of NiOx-loaded Sm{sub 2}InTaO{sub 7} supported the existing view that the photocatalytic activity correlated with the lattice distortion. Density functional theory calculation indicated that strong dispersion from the hybridized In 5s 5p orbitals at the bottom of the conduction band was responsible for the high activity of photocatalyst Sm{sub 2}InTaO{sub 7}. - Graphical abstract: A new visible-light-response photocatalyst Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration was developed. DFT calculation indicated that strong dispersion from the hybridized In 5s 5p orbitals was responsible for the high photocatalytic activity.

  16. dI UNIVERSITY OF NEV\DA SYSTEM

    Office of Legacy Management (LM)

    g3t4 6 dI UNIVERSITY OF NEV\DA SYSTEM tw ?r@ D O E / D P / O 1 2 6 3 - 2 0 L , n z l t P ' " WATER RESOURCES CENTER itf.l This report was prepared as an aecount of work sponsore$ by the United States Government. Neither the United States nor the United States Department of Energy, nor any of their employees, mal assumes any legal liability or responsib usefulness of any informationr apparatus' I that its use would not infringe privately speeifie eommereial produetr proeesst ufacturen, or

  17. Synthesis and study of conjugated polymers containing Di- or Triphenylamine

    SciTech Connect (OSTI)

    Sukwattanasinitt, M.

    1996-06-21

    This thesis consists of two separate parts. The first part addresses the synthesis and study of conjugated polymers containing di- or triphenylamine. Two types of polymers: linear polymers and dendrimers, were synthesized. The polymers were characterized by NMR, IR, UV, GPC, TGA and DSC. Electronic and optical properties of the polymers were studied through the conductivity measurements and excitation- emission spectra. the second part of this thesis deals with a reaction of electron-rich acetylenes with TCNE. The discovery of the reaction from charge transfer complex studies and the investigation of this reaction on various electron-rich acetylenes are presented.

  18. High Catalytic Activity of Au/CeOx/TiO2(110) Controlled by the Nature of the Mixed Metal Oxide at the Nanometer Level

    SciTech Connect (OSTI)

    Park, J.; Graciani, J; Evans, J; Stacchiola, D; Ma, S; Liu, P; Nambu, A; Sanz, J; Hrbek, J; et. al.

    2009-01-01

    Mixed-metal oxides play a very important role in many areas of chemistry, physics, materials science, and geochemistry. Recently, there has been a strong interest in understanding phenomena associated with the deposition of oxide nanoparticles on the surface of a second (host) oxide. Here, scanning tunneling microscopy, photoemission, and density-functional calculations are used to study the behavior of ceria nanoparticles deposited on a TiO2(110) surface. The titania substrate imposes nontypical coordination modes on the ceria nanoparticles. In the CeOx/TiO2(110) systems, the Ce cations adopt an structural geometry and an oxidation state (+3) that are quite different from those seen in bulk ceria or for ceria nanoparticles deposited on metal substrates. The increase in the stability of the Ce3+ oxidation state leads to an enhancement in the chemical and catalytic activity of the ceria nanoparticles. The codeposition of ceria and gold nanoparticles on a TiO2(110) substrate generates catalysts with an extremely high activity for the production of hydrogen through the water-gas shift reaction (H2O + CO ? H2 + CO2) or for the oxidation of carbon monoxide (2CO + O2 ? 2CO2). The enhanced stability of the Ce3+ state is an example of structural promotion in catalysis described here on the atomic level. The exploration of mixed-metal oxides at the nanometer level may open avenues for optimizing catalysts through stabilization of unconventional surface structures with special chemical activity.

  19. Critical cleaning agents for Di-2-ethylhexyl sebacate.

    SciTech Connect (OSTI)

    Hartley, Mya; Archuleta, Kim M.

    2013-08-01

    It is required that Di-2-ethylhexyl Sebacate oil, also commonly known as Dioctyl Sebacate oil, be thoroughly removed from certain metals, in this case stainless steel parts with narrow, enclosed spaces. Dioctyl Sebacate oil is a synthetic oil with a low compressibility. As such, it is ideally used for high pressure calibrations. The current method to remove the Dioctyl Sebacate from stainless steel parts with narrow, enclosed spaces is a labor-intensive, multi-step process, including a detergent clean, a deionized (DI) water rinse, and several solvent rinses, to achieve a nonvolatile residue of0.04 mg per 50 mL rinse effluent. This study was undertaken to determine a superior detergent/solvent cleaning method for the oil to reduce cleaning time and/or the amount of detergent/solvent used. It was determined that while some detergent clean the oil off the metal better than the current procedure, using only solvents obtained the best result. In addition, it can be inferred, based on elevated temperature test results, that raising the temperature of the oil-contaminated stainless steel parts to approximately 50%C2%B0C will provide for improved cleaning efficacy.

  20. Cobalt-iron red-ox behavior in nanostructured La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} cathodes

    SciTech Connect (OSTI)

    Soldati, Analia L.; Baque, Laura; Napolitano, Federico; Serquis, Adriana

    2013-02-15

    Nano-sized La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF) perovskite samples (prepared by a conventional acetate route and a novel acetate synthesis with HMTA additives), were tested simulating a red-ox cycle. The crystallography was studied by X-ray Powder Diffraction (XPD) and the changes in the oxidation state of the perovskite B-site were evaluated by synchrotron X-ray Absorption Near Edge Spectroscopy (XANES). After a reducing treatment, LSFC particles show the appearance of a new phase that coexists with the original one. The structural change is accompanied by a Co and Fe formal oxidation states decrease, although Fe remains always closer to 4+ and Co closer to 3+. The treatment produces a B-site valence average reduction from 3.52+ to 3.26+ and the formation of oxygen vacancies. A re-oxidation treatment under O{sub 2} rich atmosphere at 800 Degree-Sign C for 10 h shows that the change is reversible and independent of the two chemical methods used to synthesize the LSCF nano-particles. - Graphical abstract: XANES and XPD measurements in nanostructured LSCF before (black) and after (red/green) a red/ox cycle. Highlights: Black-Right-Pointing-Pointer Red-ox treatments in LSCF nano-particles cause a reversible reaction. Black-Right-Pointing-Pointer XPD analyses show that a new 'reduced' phase coexist with the oxidize one. Black-Right-Pointing-Pointer The B-site formal oxidation state decreases and the {delta} increases upon reduction. Black-Right-Pointing-Pointer Fe remains in a higher valence (closer to 4+) than Co (close to 3+). Black-Right-Pointing-Pointer The behavior seems to be independent of the synthesis method used.

  1. Hydrogenation of CO2 to methanol on CeOx/Cu(111) and ZnO/Cu(111) catalysts: Role of the metal-oxide interface and importance of Ce3+ sites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sanjaya D. Senanayake; Ramirez, Pedro J.; Waluyo, Iradwikanari; Kundu, Shankhamala; Mudiyanselage, Kumudu; Liu, Zongyuan; Liu, Zhi; Axnanda, Stephanus; Stacchiola, Dario J.; Evans, Jaime; et al

    2016-01-06

    The role of the interface between a metal and oxide (CeOx–Cu and ZnO–Cu) is critical to the production of methanol through the hydrogenation of CO2 (CO2 + 3H2 → CH3OH + H2O). The deposition of nanoparticles of CeOx or ZnO on Cu(111), θoxi < 0.3 monolayer, produces highly active catalysts for methanol synthesis. The catalytic activity of these systems increases in the sequence: Cu(111) < ZnO/Cu(111) < CeOx/Cu(111). The apparent activation energy for the CO2 → CH3OH conversion decreases from 25 kcal/mol on Cu(111) to 16 kcal/mol on ZnO/Cu(111) and 13 kcal/mol on CeOx/Cu(111). The surface chemistry of the highlymore » active CeOx–Cu(111) interface was investigated using ambient pressure X-ray photoemission spectroscopy (AP-XPS) and infrared reflection absorption spectroscopy (AP-IRRAS). Both techniques point to the formation of formates (HCOO–) and carboxylates (CO2δ–) during the reaction. Our results show an active state of the catalyst rich in Ce3+ sites which stabilize a CO2δ– species that is an essential intermediate for the production of methanol. Furthermore, the inverse oxide/metal configuration favors strong metal–oxide interactions and makes possible reaction channels not seen in conventional metal/oxide catalysts.« less

  2. ParaDiS-FEM dislocation dynamics simulation code primer (Technical...

    Office of Scientific and Technical Information (OSTI)

    When we try to perform discrete dislocation dynamics simulations for finite systems such as thin films or cylinders, the ParaDiS code must be extended. First, dislocations need to ...

  3. Frank DiSalvo > Research Thrust Leader - Fuel Cells and Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frank DiSalvo Research Thrust Leader - Fuel Cells and Batteries John A. Newman Professor of Physical Science Chemistry and Chemical Biology Research Group Webpage fjd3@cornell.edu...

  4. Direct Visualization of Spray and Combustion Inside a DI-SI Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel, injection timing, and valve deactivation in a DI optical accessible engine with side-mounted, multi-hole injector are investigated using CFD and high-speed imaging of sprays ...

  5. HD Applications of Significantly Downsized SI Engines Using Alcohol DI for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Knock Avoidance | Department of Energy Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance HD Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance Direct injection of a second fuel (ethanol or methanol) is explored as a means of avoiding knock in turbocharged, high-compression ratio spark-ignited engines that could replace diesels in certain vocational applications. deer08_blumberg.pdf (163.75 KB) More Documents &

  6. Non-Sooting, Low Flame Temperature Mixing-Controlled DI Diesel Combustion |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Sooting, Low Flame Temperature Mixing-Controlled DI Diesel Combustion Non-Sooting, Low Flame Temperature Mixing-Controlled DI Diesel Combustion 2003 DEER Conference Presentation: Sandia National Laboratories 2003_deer_pickett.pdf (538.33 KB) More Documents & Publications Effects of Ambient Density and Temperature on Soot Formation under High-EGR Conditions Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines Optical-Engine and Surrogate-Fuels

  7. New Processing and Characterization Approaches for Achieving Full Performance of High Temperature Superconducting Tapes of (Bi,Pb)2Sr2Ca2Cu3Ox

    SciTech Connect (OSTI)

    E.E. Hellstrom; D.C. Larbalestier

    2006-03-22

    The thrust of this research was to identify and understand current limiting mechanisms (CLMs) that limit the current carrying capacity of (Bi,Pb)2Sr2Ca2Cu3Ox (2223) in Ag-sheathed wire. Our program concentrated on developing new methods to identify CLMs at the micrometer scale and new processing techniques to eliminate CLMs. All of the DOE Superconductivity Partnership Initiative (SPI) programs are using 2223 wire, so increasing the critical current density (Jc) in the wire can improve the technical performance of the demonstration projects, and at the same time it can decrease the cost of the wire. The important cost metric for superconducting wire is $/kAm, so increasing Jc, which is in the denominator, decreases the wire cost. The obvious CLMs were micrometer size obstacles in the 2223 ceramic that block current flow, including: misaligned grains, cracks, pores, and nonsuperconducting phases. Pores and cracks - regions where there is no superconductor or the grains are not physically connected to one another ? cannot carry supercurrent, so they were the first CLMs we tried to eliminate with improved processing. Prior to the contract, we had started investigating overpressure (OP) processing with Williams at ORNL to heal cracks and remove pores. OP processing, which is a variant of hot isostatic pressing (HIP), uses an Ar/O2 gas mixture to apply a high pressure (up to 200 atm) to compress the sample and to set the oxygen partial pressure (pO2) to form 2223. Williams had a static pressure system we used to demonstrate that OP processing healed cracks and densified the wire, but the static system limited the processing parameters we could investigate. We proposed building a new gas-flow OP system to expand the experimental capabilities and to investigate new processing routes using the gas-flow OP system. Using the gas-flow OP system, we established new world records in 2003 for Jc and Ic. These records were finally matched by Sumitomo Electric Company in early

  8. Boosted di-boson from a mixed heavy stop

    SciTech Connect (OSTI)

    Ghosh, Diptimoy

    2013-12-01

    The lighter mass eigenstate ($\\widetilde{t}_1$) of the two top squarks, the scalar superpartners of the top quark, is extremely difficult to discover if it is almost degenerate with the lightest neutralino ($\\widetilde{\\chi}_1^0$), the lightest and stable supersymmetric particle in the R-parity conserving supersymmetry. The current experimental bound on $\\widetilde{t}_1$ mass in this scenario stands only around 200 GeV. For such a light $\\widetilde{t}_1$, the heavier top squark ($\\widetilde{t}_2$) can also be around the TeV scale. Moreover, the high value of the higgs ($h$) mass prefers the left and right handed top squarks to be highly mixed allowing the possibility of a considerable branching ratio for $\\widetilde{t}_2 \\to \\widetilde{t}_1 h$ and $\\widetilde{t}_2 \\to \\widetilde{t}_1 Z$. In this paper, we explore the above possibility together with the pair production of $\\widetilde{t}_2$ $\\widetilde{t}_2^*$ giving rise to the spectacular di-boson + missing transverse energy final state. For an approximately 1 TeV $\\widetilde{t}_2$ and a few hundred GeV $\\widetilde{t}_1$ the final state particles can be moderately boosted which encourages us to propose a novel search strategy employing the jet substructure technique to tag the boosted $h$ and $Z$. The reconstruction of the $h$ and $Z$ momenta also allows us to construct the stransverse mass $M_{T2}$ providing an additional efficient handle to fight the backgrounds. We show that a 4--5$\\sigma$ signal can be observed at the 14 TeV LHC for $\\sim$ 1 TeV $\\widetilde{t}_2$ with 100 fb$^{-1}$ integrated luminosity.

  9. Potentiality of small DI diesel engines under consideration of emissions and noise control

    SciTech Connect (OSTI)

    Sugihara, K.; Matusi, Y.; Saegusa, S.

    1985-01-01

    The potentiality of direct injection (DI) diesel engines for passenger cars has been examined by comparing the characteristics of fuel consumption, exhaust emissions and noise levels between a turbocharged DI diesel engine and a turbocharged IDI diesel engine with the same displacement, 4 cylinders and 2 liters. It was observed that improved fuel consumption was obtained as the engine load increased, namely, 10 - 15% in the higher load range and 5 - 10% in the partial load range. In comparison to the IDI engine, the exhaust emissions of the DI engine tended to contain two or three times higher NOx and HC, and also about 30% higher particulates. Further, the noise levels of the DI engine were approximately 2 - 4 db (a) higher than those of the IDI engine. It was suggested from these results that in those countries which have stringent emission and noise regulations several years would be required to introduce small, high speed DI diesel engines for passenger cars to meet with these regulations.

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Rutherford Appleton Laboratory, Chilton, Didcot, OXON OX11 0QX ; Dipartimento di Fisica E. Amaldi, Universita degli Studi Roma Tre, Via della Vasca Navale 84, 00146 Rome ...

  11. Method of dissolving metal oxides with di- or polyphosphonic acid and a redundant

    DOE Patents [OSTI]

    Horwitz, Earl P.; Chiarizia, Renato

    1996-01-01

    A method of dissolving metal oxides using a mixture of a di- or polyphosphonic acid and a reductant wherein each is present in a sufficient amount to provide a synergistic effect with respect to the dissolution of metal oxides and optionally containing corrosion inhibitors and pH adjusting agents.

  12. Dimeric c-di-GMP is required for post-translational regulation of alginate production in Pseudomonas aeruginosa

    SciTech Connect (OSTI)

    Whitney, John C.; Robinson, Howard; Whitfield, Gregory B.; Marmont, Lindsey S.; Yip, Patrick; Neculai, A. Mirela; Lobsanov, Yuri D.; Ohman, Dennis E.; Howell, P. Lynne

    2015-05-15

    Pseudomonas aeruginosa is an opportunistic human pathogen that secretes the exopolysaccharide alginate during infection of the respiratory tract of individuals afflicted with cystic fibrosis and chronic obstructive pulmonary disease. Among the proteins required for alginate production, Alg44 has been identified as an inner membrane protein whose bis-(3',5')-cyclic dimeric guanosine monophosphate (c-di-GMP) binding activity post-translationally regulates alginate secretion. In this study, we report the 1.8 Å crystal structure of the cytoplasmic region of Alg44 in complex with dimeric self-intercalated c-di-GMP and characterize its dinucleotide-binding site using mutational analysis. The structure shows that the c-di-GMP binding region of Alg44 adopts a PilZ domain fold with a dimerization mode not previously observed for this family of proteins. Moreover, calorimetric binding analysis of residues in the c-di-GMP binding site demonstrate that mutation of Arg-17 and Arg-95 alters the binding stoichiometry between c-di-GMP and Alg44 from 2:1 to 1:1. Introduction of these mutant alleles on the P. aeruginosa chromosome show that the residues required for binding of dimeric c-di-GMP in vitro are also required for efficient alginate production in vivo. Our results suggest that the dimeric form of c-di-GMP represents the biologically active signaling molecule needed for the secretion of an important virulence factor produced by P. aeruginosa.

  13. Dimeric c-di-GMP is required for post-translational regulation of alginate production in Pseudomonas aeruginosa

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Whitney, John C.; Robinson, Howard; Whitfield, Gregory B.; Marmont, Lindsey S.; Yip, Patrick; Neculai, A. Mirela; Lobsanov, Yuri D.; Ohman, Dennis E.; Howell, P. Lynne

    2015-05-15

    Pseudomonas aeruginosa is an opportunistic human pathogen that secretes the exopolysaccharide alginate during infection of the respiratory tract of individuals afflicted with cystic fibrosis and chronic obstructive pulmonary disease. Among the proteins required for alginate production, Alg44 has been identified as an inner membrane protein whose bis-(3',5')-cyclic dimeric guanosine monophosphate (c-di-GMP) binding activity post-translationally regulates alginate secretion. In this study, we report the 1.8 Å crystal structure of the cytoplasmic region of Alg44 in complex with dimeric self-intercalated c-di-GMP and characterize its dinucleotide-binding site using mutational analysis. The structure shows that the c-di-GMP binding region of Alg44 adopts a PilZmore » domain fold with a dimerization mode not previously observed for this family of proteins. Moreover, calorimetric binding analysis of residues in the c-di-GMP binding site demonstrate that mutation of Arg-17 and Arg-95 alters the binding stoichiometry between c-di-GMP and Alg44 from 2:1 to 1:1. Introduction of these mutant alleles on the P. aeruginosa chromosome show that the residues required for binding of dimeric c-di-GMP in vitro are also required for efficient alginate production in vivo. Our results suggest that the dimeric form of c-di-GMP represents the biologically active signaling molecule needed for the secretion of an important virulence factor produced by P. aeruginosa.« less

  14. Joint Statement by President Obama and Prime Minister Elio Di Rupo of

    National Nuclear Security Administration (NNSA)

    Belgium on the 2014 Nuclear Security Summit | National Nuclear Security Administration | (NNSA) Joint Statement by President Obama and Prime Minister Elio Di Rupo of Belgium on the 2014 Nuclear Security Summit March 24, 2014 See a fact sheet here. The White House Office of the Press Secretary Belgium and the United States of America are pleased to announce that they have jointly completed the removal of a significant amount of excess highly enriched uranium (HEU) and separated plutonium from

  15. Efficient Emissions Control for Multi-Mode Lean DI Engines | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy 11 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace031_parks_2011_o.pdf (848.8 KB) More Documents & Publications Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion High Efficiency Clean Combustion in Multi-Cylinder Light-Duty Engines Efficient Emissions Control for Multi-Mode Lean DI Engines

  16. ULEV potential of a DI/TCI diesel passenger car engine operated on dimethyl ether

    SciTech Connect (OSTI)

    Kapus, P.E.; Cartellieri, W.P.

    1995-12-31

    This paper describes a feasibility test program on a 2 liter, 4 cylinder DI/TCI passenger car engine operated on the new alternative fuel Dimethyl Ether (DME) with the aim of demonstrating its potential of meeting ULEV (ultra low emission vehicle) emissions (0.2 g/mi NOx in the FTP 75 test cycle) when installed in a full size passenger car. Special attention is drawn to the fuel injection equipment (FIE) as well as combustion system requirements towards the reduction of NOx and combustion noise while keeping energetic fuel consumption at the level of he baseline DI/TCI diesel engine. FIE and combustion system parameters were optimized on the steady state dynamometer by variation of a number of parameters, such as rate of injection, number of nozzle holes, compression ratio, piston bowl shape and exhaust gas recirculation. The paper presents engine test results achieved with DME under various operating conditions and compares these results to those achieved with the diesel version of the same engine.The FTP 75 cycle results were projected from steady state engine maps using a vehicle simulation program taking into account vehicle data and road resistance data of a given vehicle.The cycle results are also compared to actual chassis dynamometer results achieved with the diesel version of the same engine installed in the same vehicle.the passenger car DI/TCI engine adapted for and operated on DME shows very promising results with respect to meeting ULEV NOx emissions without any soot emissions and without the need for a DENOX catalyst. DME fuel consumption on energy basis can be kept very close to the DI diesel value. An oxidation catalyst will be necessary to meet the stringent CO and HC ULEV emission limits.

  17. Azimuthal angle dependence of di-jet production in unpolarized hadron scattering

    SciTech Connect (OSTI)

    Lu Zhun; Schmidt, Ivan [Departamento de Fisica, Universidad Tecnica Federico Santa Maria, Valparaiso (Chile) and Center of Subatomic Physics, Valparaiso (Chile)

    2009-08-04

    We study the azimuthal asymmetry of back-to-back di-jet production in unpolarized hadron scattering, arising from the product of two Boer-Mulders functions, which describe the transverse spin distribution of quarks inside an unpolarized hadron. We find that there is a cos {delta}{phi} angular dependence of the di-jet, with {delta}{phi} the difference of the azimuthal angle of tow jets respectively. In the case of J{sub q}+J{sub q} production, we find that there is a color factor enhancement in the gluonic cross-section due to the multiple initial-/final-state interactions, compared with the result from the standard generalized parton model. We estimate the cos {delta}{phi} asymmetry of the total di-jet production at RHIC, showing that the color factor enhancement in the azimuthal asymmetric cross section of J{sub q}+J{sub q} production will reverse the sign of the asymmetry.

  18. Di-J/psi Studies, Level 3 Tracking and the D0 Run IIb Upgrade

    SciTech Connect (OSTI)

    Vint, Philip John; /Imperial Coll., London

    2009-10-01

    The D0 detector underwent an upgrade to its silicon vertex detector and triggering systems during the transition from Run IIa to Run IIb to maximize its ability to fully exploit Run II at the Fermilab Tevatron. This thesis describes improvements made to the tracking and vertexing algorithms used by the high level trigger in both Run IIa and Run IIb, as well as a search for resonant di-J/{psi} states using both Run IIa and Run IIb data. Improvements made to the tracking and vertexing algorithms during Run IIa included the optimization of the existing tracking software to reduce overall processing time and the certification and testing of a new software release. Upgrades made to the high level trigger for Run IIb included the development of a new tracking algorithm and the inclusion of the new Layer 0 silicon detector into the existing software. The integration of Layer 0 into the high level trigger has led to an improvement in the overall impact parameter resolution for tracks of {approx}50%. The development of a new parameterization method for finding the error associated to the impact parameter of tracks returned by the high level tracking algorithm, in association with the inclusion of Layer 0, has led to improvements in vertex resolution of {approx}4.5 {micro}m. A previous search in the di-J/{psi} channel revealed a unpredicted resonance at {approx}13.7 GeV/c{sup 2}. A confirmation analysis is presented using 2.8 fb{sup -1} of data and two different approaches to cuts. No significant excess is seen in the di-J/{psi} mass spectrum.

  19. Improved di-p-xylylene polymer and apparatus and method for making the same

    DOE Patents [OSTI]

    Jahn, R.K.; Liepins, R.

    Solid di-para-xylyene dimer is sublimed in a sublimation furnace at approximately 100 to 200/sup 0/C and subsequently conducted to a pyrolysis furnace where it is pyrolyzed to the diradical p-xylylene monomer while in the vapor state at approximately 600 degrees C. The diradical monomer is then introduced into a deposition chamber for deposition onto a suitable substrate. The deposition chamber includes electrodes for producing a low pressure plasma through which the diradical monomer passes prior to deposition. The interaction of the diradical monomer with the low pressure plasma results in the formation of poly-p-xylyene film which is exceptionally hard and thermally stable.

  20. Di-22:6-bis(monoacylglycerol)phosphate: A clinical biomarker of drug-induced phospholipidosis for drug development and safety assessment

    SciTech Connect (OSTI)

    Liu, Nanjun; Tengstrand, Elizabeth A.; Chourb, Lisa; Hsieh, Frank Y.

    2014-09-15

    The inability to routinely monitor drug-induced phospholipidosis (DIPL) presents a challenge in pharmaceutical drug development and in the clinic. Several nonclinical studies have shown di-docosahexaenoyl (22:6) bis(monoacylglycerol) phosphate (di-22:6-BMP) to be a reliable biomarker of tissue DIPL that can be monitored in the plasma/serum and urine. The aim of this study was to show the relevance of di-22:6-BMP as a DIPL biomarker for drug development and safety assessment in humans. DIPL shares many similarities with the inherited lysosomal storage disorder Niemann–Pick type C (NPC) disease. DIPL and NPC result in similar changes in lysosomal function and cholesterol status that lead to the accumulation of multi-lamellar bodies (myeloid bodies) in cells and tissues. To validate di-22:6-BMP as a biomarker of DIPL for clinical studies, NPC patients and healthy donors were classified by receiver operator curve analysis based on urinary di-22:6-BMP concentrations. By showing 96.7-specificity and 100-sensitivity to identify NPC disease, di-22:6-BMP can be used to assess DIPL in human studies. The mean concentration of di-22:6-BMP in the urine of NPC patients was 51.4-fold (p ≤ 0.05) above the healthy baseline range. Additionally, baseline levels of di-22:6-BMP were assessed in healthy non-medicated laboratory animals (rats, mice, dogs, and monkeys) and human subjects to define normal reference ranges for nonclinical/clinical studies. The baseline ranges of di-22:6-BMP in the plasma, serum, and urine of humans and laboratory animals were species dependent. The results of this study support the role of di-22:6-BMP as a biomarker of DIPL for pharmaceutical drug development and health care settings. - Highlights: • A reliable biomarker of drug-induced phospholipidosis (DIPL) is needed for humans. • Di-22:6-BMP is specific/sensitive for DIPL in animals as published in literatures. • The di-22:6-BMP biomarker can be validated for humans via NPC patients. • DIPL

  1. Di-p-xylylene polymer and method for making the same

    DOE Patents [OSTI]

    Jahn, Randy K.; Liepins, Raimond

    1985-01-01

    A method and apparatus for forming an improved poly-p-xylylene film. Solid di-para-xylylene dimer is sublimed in a sublimation furnace at approximately 100.degree. to 200.degree. C. and subsequently conducted to a pyrolysis furnace where it is pyrolyzed to the diradical p-xylylene monomer while in the vapor state at approximately 600 degrees C. The diradical monomer is then introduced into a deposition chamber for deposition onto a suitable substrate. The deposition chamber includes electrodes for producing a low pressure plasma through which the diradical monomer passes prior to deposition. The interaction of the diradical monomer with the low pressure plasma results in the formation of poly-p-xylylene film which is exceptionally hard and thermally stable.

  2. Cerreto di Spoleto (Umbria-Italy): Seismic amplification at the ENEA local array stations

    SciTech Connect (OSTI)

    Rinaldis, Dario

    2008-07-08

    The Nerina valley, where Borgo Cerreto is located, is surrounded by the Apennine mount chain at the top of which lies the historical centre of Cerreto di Spoleto. The study is part of a research project aiming at analysing natural disasters and their impact on the Italian cultural heritage. Within the framework of this research project, local seismic records were analysed for both the carbonate ridge and the bordering alluvial valley. The choice of Cerreto di Spoleto as a test site derives from the analysis of Italian seismic hazard maps, obtained in terms of peak ground velocity and taking into account regional geology. The maps highlight the considerable seismic hazard which characterises the Apennine belt and its possible increase due to the effect of alluvial deposits. To this aim, ENEA installed in the 80's an accelerometric array (CODISMA up to 2000 and, in the following years, ETNA; for more detailed description see [1]. The 14 October event, was recorded both at the roof of CSM and at BCT stations. This is important to check the features observed comparing the FAS of acceleration at CSM and BCT during the 26 September events. Unfortunately the station at CSM basement did not record the above mentioned events but several aftershocks were recorded at each array station. Velocimetric records of both ambient noise and small-magnitude earthquakes were analysed in order to identify amplification conditions. The analysis was carried out in the time domain, through directional energy evaluation, and in the frequency domain, through H/V spectral ratios and spectral ratios with respect to a reference station.

  3. Direct Visualization of Spray and Combustion Inside a DI-SI Engine and Its Implications to Flex-Fuel VVT Operations

    Broader source: Energy.gov [DOE]

    Fuel, injection timing, and valve deactivation in a DI optical accessible engine with side-mounted, multi-hole injector are investigated using CFD and high-speed imaging of sprays and combustion.

  4. Di-photon and photon + b/c production cross sections at Ecm = 1.96- TeV

    SciTech Connect (OSTI)

    Gajjar, Anant; /Liverpool U.

    2005-05-01

    Measurements of the di-photon cross section have been made in the central region and are found to be in good agreement with NLO QCD predictions. The cross section of events containing a photon and additional heavy flavor jet have also been measured, as well as the ratio of photon + b to photon + c. The statistically limited sample shows good agreement with Leading Order predictions.

  5. Kinetic and Thermodynamic Investigation of Hydrogen Release from Ethane 1,2-di-amineborane

    SciTech Connect (OSTI)

    Neiner, Doinita; Karkamkar, Abhijeet J.; Bowden, Mark; Choi, Young Joon; Luedtke, Avery T.; Holladay, Jamelyn D.; Fisher, Allison M.; Szymczak, Nathaniel; Autrey, Thomas

    2011-07-18

    The thermodynamics and kinetics of hydrogen (H2) release from ethane 1,2-di-amineborane (EDAB, BH3NH2CH2CH2NH2BH3) were measured using Calvet and differential scanning calorimetry (DSC), pressure-composition isotherms, and volumetric gas-burette experiments. The results presented here indicate that EDAB releases ~ 9 wt.% H2 at temperatures ranging from 100 C to 200 C in two moderately exothermic steps, approximately -101 kJ/mol H2 and -3.81 kJ/mol H2. Isothermal kinetic analysis shows that EDAB is more stable than ammonia borane (AB) at temperatures lower than 100C; however, the rates of hydrogen release are faster for EDAB than for AB at temperatures higher than 120C. In addition, no volatile impurities in the H2 released by EDAB were detected by mass spectrometry upon heating with 1C/min to 200C in a calorimeter.

  6. Comparative Study of Low-temperature PECVD of Amorphous Silicon using Mono-, Di-, Trisilane and Cyclohexasilane

    SciTech Connect (OSTI)

    Konstantin Pokhodnya; Joseph Sandstrom; Xuliang Dai; Philip Boudjouk; Douglas L. Schulz

    2009-06-08

    The hydrogenated amorphous silicon a-Si:H films were grown by plasma-enhanced chemical vapor deposition (PECVD) using liquid cyclohexasilane Si{sub 6}H{sub 12} (CHS). The growth rate of a-Si:H was studied as a function of substrate temperatures in the range of 30 C < T < 450 C using deposition conditions that were optimized for monosilane SiH{sub 4}. The same parameters were used for a-Si:H films grown using disilane (Si{sub 2}H{sub 6}) and trisilane (Si{sub 3}H{sub 8}) precursors. It was found that the a-Si:H film growth rate for CHS is lower with respect to those for mono-, di- and trisilane in an Ar plasma. Addition of {approx}10% of H{sub 2} dramatically increases the deposition rate for CHS-based films to {_}nm/min - a 700% increase. The as-deposited films were characterized by FTIR and Raman spectroscopy to probe the hydrogen content and local bonding environment. It was found that the films grown using Ar/H{sub 2} mixtures as carrier gas have a reduced hydrogen content relative to polysilane fragments indicating higher quality amorphous silicon.

  7. Di-boson production and SM SUSY Higgs searches at the Tevatron

    SciTech Connect (OSTI)

    Elvira, V.Daniel; /Fermilab

    2005-07-01

    The discovery of the Higgs boson would be a major success for the Standard Model (SM) and would provide further insights into the electroweak symmetry breaking mechanism. This report contains the latest results from the D0 and CDF Tevatron experiments on searches for the SM Higgs produced from gluon fusion with H {yields} WW, and in association with a W boson. It also includes searches for a supersymmetric Higgs in the b{bar b} and {tau}{sup +}{tau}{sup -} decay channels. The study of di-boson production at the Tevatron is important to understand backgrounds in high mass Higgs searches. It also provides a test of the SM through the measurement of the production cross section and the gauge boson self couplings. This paper includes measurements of the WW, W{gamma}, and WZ production cross sections, as well as limits on the anomalous couplings associated with the WW{gamma} and WWZ interactions. The results are based on sets of up to 320 pb{sup -1} of data collected by the D0 and CDF experiments at the {bar p}p Tevatron collider, running at a center-of-mass energy of 1.96 TeV.

  8. Seismic model of a progradational carbonate platform, Picco di Vallandro, the Dolomites, northern Italy

    SciTech Connect (OSTI)

    Biddle, K.T.; Bush, T.L. ); Schlager, W. ); Rudolph, K.W. )

    1992-01-01

    The authors present a seismic model of a well-exposed carbonate platform-to-basin transition from the Triassic succession at Picco di Vallandro, the Dolomites, northern Italy. The core of this model is a detailed lithologic cross section that represents 1,500 m of stratigraphic section over a distance of 3.5 km. The cross section is based on detailed measured sections, photo interpretation, and careful projection of surface mapping into the plane of section. Samples from the measured sections provide control on velocity and density distribution, and these data were used to generate an impedance model from the cross section. The impedance model was convolved with a zero-phase, 25-Hz peak-frequency wavelet to produce the seismic model. The results illustrate how the platform-to-basin transition might be imaged by conventional seismic reflection data, how the reflections relate to the distribution of lithology and through-going geological surfaces, and how constructive and destructive interference and seismic resolution combine to produce individual reflections.

  9. Functionalization/passivation of porous graphitic carbon with di-tert-amylperoxide

    SciTech Connect (OSTI)

    Jensen, David S.; Gupta, Vipul; Olsen, Rebecca E.; Miller, Alex T.; Davis, Robert C.; Ess, Daniel; Zhu, Zihua; Vail, Michael A.; Dadson, Andrew; Linford, Matthew R.

    2011-11-18

    Porous graphitic carbon (PGC) particles were functionalized/passivated in situ in packed beds at elevated temperature with neat di-tert-amylperoxide (DTAP) in a column oven. The performance of these particles for high performance liquid chromatography (HPLC) was assayed before and after this chemistry with the following analytes: benzene, toluene, ethyl benzene, n-propyl benzene, n-butyl benzene, p-xylene, phenol, 4-methylphenol, phenetole, 3,5-xylenol, and anisole. After the first functionalization/passivation, the retention factors, k, of these compounds decreased by about 5% and the number of theoretical plates (N) increased by ca. 15%. These values of k then remained roughly constant after a second functionalization/ passivation but a further increase in N was noticed. In addition, after each of the reactions, the peak asymmetries decreased by ca. 15%, for a total of ca. 30%. The columns were then subjected twice to methanol at 100 C for 5 h at 1 mL/min. After these stability tests, the values of k remained roughly constant, the number of plates increased, which is favorable, and the asymmetries rose and then declined, where they remained below the initial values for the unfunctionalized columns. Functionalized and unfunctionalized particles were characterized by scanning electron microscopy and BET measurements, which showed no difference between the functionalized and unfunctionalized materials, and X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry (ToF-SIMS), where ToF-SIMS suggested some chemical differences between the functionalized and unfunctionalized materials. In particular ToF-SIMS suggested that the expected five-carbon fragments from DTAP exist at higher concentrations on DTAP-functionalized PGC. First principle calculations on model graphitic surfaces suggest that the first addition of a DTAP radical to the surface proceeds in an approximately isothermal or slightly favorable fashion, but that subsequent DTAP

  10. Study of di-pion Bottomonium Transitions and Search for the h_b(1P) State

    SciTech Connect (OSTI)

    Lees, J.P.; Poireau, V.; Tisserand, V.; Garra Tico, J.; Grauges, E.; Martinelli, M.; Milanes, D.A.; Palano, A.; Pappagallo, M.; Eigen, G.; Stugu, B.; Sun, L.; Brown, D.N.; Kerth, L.T.; Kolomensky, Yu.G.; Lynch, G.; Koch, H.; Schroeder, T.; Asgeirsson, D.J.; Hearty, C.; Mattison, T.S.; /British Columbia U. /Brunel U. /Novosibirsk, IYF /UC, Irvine /UC, Riverside /UC, Santa Barbara /UC, Santa Cruz /Caltech /Cincinnati U. /Colorado U. /Colorado State U. /Dortmund U. /Dresden, Tech. U. /Ecole Polytechnique /Edinburgh U. /INFN, Ferrara /INFN, Ferrara /Ferrara U. /INFN, Ferrara /Frascati /INFN, Genoa /Genoa U. /INFN, Genoa /INFN, Genoa /Genoa U. /INFN, Genoa /Indian Inst. Tech., Guwahati /Harvard U. /Harvey Mudd Coll. /Heidelberg U. /Humboldt U., Berlin /Imperial Coll., London /Iowa State U. /Iowa State U. /Johns Hopkins U. /Paris U., VI-VII /LLNL, Livermore /Liverpool U. /Queen Mary, U. of London /Royal Holloway, U. of London /Royal Holloway, U. of London /Louisville U. /Mainz U., Inst. Kernphys. /Manchester U. /Maryland U. /Massachusetts U., Amherst /MIT /McGill U. /INFN, Milan /Milan U. /INFN, Milan /INFN, Milan /Milan U. /Mississippi U. /Montreal U. /INFN, Naples /Naples U. /NIKHEF, Amsterdam /NIKHEF, Amsterdam /Notre Dame U. /Ohio State U. /Oregon U. /INFN, Padua /Padua U. /INFN, Padua /INFN, Padua /Padua U. /Paris U., VI-VII /INFN, Perugia /Perugia U. /INFN, Pisa /Pisa U. /INFN, Pisa /Pisa, Scuola Normale Superiore /INFN, Pisa /Pisa U. /INFN, Pisa /INFN, Pisa /Pisa U. /INFN, Pisa /Princeton U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /INFN, Rome /Rome U. /INFN, Rome /Rostock U. /Rutherford /DAPNIA, Saclay /SLAC /South Carolina U. /Southern Methodist U. /Stanford U., Phys. Dept. /SUNY, Albany /Tel Aviv U. /Tennessee U. /Texas Nuclear Corp., Austin /Texas U., Dallas /INFN, Turin /Turin U. /INFN, Trieste /Trieste U. /Valencia U. /Victoria U. /Warwick U. /Wisconsin U., Madison

    2011-12-09

    We study inclusive di-pion decays using a sample of 108 x 10{sup 6} {Upsilon}(3S) events recorded with the BABAR detector. We search for the decay mode {Upsilon}(3S) {yields} {pi}{sup +}{pi}{sup -}h{sub b} (1P) and find no evidence for the bottomonium spin-singlet state h{sub b}(1P) in the invariant mass distribution recoiling against the {pi}{sup +}{pi}{sup -} system. Assuming the h{sub b}(1P) mass to be 9.900 GeV/c{sup 2}, we measure the upper limit on the branching fraction {Beta}[{Upsilon}(3S) {yields} {pi}{sup +}{pi}{sup -}h{sub b}(1P)] < 1.2 x 10{sup -4}, at 90% confidence level. We also investigate the {chi}{sub bJ}(2P) {yields} {pi}{sup +}{pi}{sup -} {chi}{sub bJ}(1P), {Upsilon}(3S) {yields} {pi}{sup +}{pi}{sup -}{Upsilon}(2S), and {Upsilon}(2S) {yields} {pi}{sup +}{pi}{sup -}{Upsilon}(1S) di-pion transitions and present an improved measurement of the branching fraction of the {Upsilon}(3S) {yields} {pi}{sup +}{pi}{sup -}{Upsilon}(2S) decay and of the {Upsilon}(3S) - {Upsilon}(2S) mass difference.

  11. Thermal chemistry of copper(I)-N,N '-di-sec-butylacetamidinate on Cu(110) single-crystal surfaces

    SciTech Connect (OSTI)

    Ma Qiang; Zaera, Francisco; Gordon, Roy G.

    2012-01-15

    The surface chemistry of copper(I)-N,N'-di-sec-butylacetamidinate on Cu(110) single-crystal surfaces has been characterized under ultrahigh vacuum by temperature programmed desorption (TPD) and X-ray photoelectron spectroscopy. A series of thermal stepwise conversions were identified, starting with the partial dissociative adsorption of the copper acetamidinate dimers into a mixture of monomers and dimers on the surface. An early dissociation of a C-N bond leads to the production of N-sec-butylacetamidine, which is detected in TPD experiments in three temperature regimes, the last one centered around 480 K. Butene, and a small amount of butane, is also detected above approximately 500 K, and hydrogen production, an indication of dehydrogenation of surface fragments, is observed at 460, 550 and 670 K. In total, only about 10% of the initial copper(I)-N,N'-di-sec-butylacetamidinate adsorbed monolayer decomposes, and only about {approx}3% of carbon is left behind on the surface after heating to high temperatures. The implications of this surface chemistry to the design of chemical film growth processes using copper acetamidinates as precursors are discussed.

  12. A Search for Supersymmetric Higgs Bosons in the Di-tau Decay Mode in Proton - Anti-proton Collisions at 1.8 TeV

    SciTech Connect (OSTI)

    Connolly, Amy Lynn

    2003-09-01

    A search for directly produced Supersymmetric Higgs Bosons has been performed in the di-tau decay channel in 86.3 {+-} 3.5 pb{sup -1} of data collected by CDF during Run1b at the Tevatron. They search for events where one tau decays to an electron and the other tau decays hadronically. They perform a counting experiment and set limits on the cross section for Higgs production in the high tan {beta} region of the m{sub A}-tan {beta} plane. For a benchmark parameter space point where m{sub A} = 100 and tan {beta} = 50, they set a 95% confidence level upper limit at 891 pb compared to the theoretically predicted cross section of 122 pb. For events where the tau candidates are not back-to-back, they utilize a di-tau mass reconstruction technique for the first time on hadron collider data. Limits based on a likelihood binned in di-tau mass from non-back-to-back events alone are weaker than the limits obtained from the counting experiment using the full di-tau sample.

  13. DE-EM-0001971 WIPP M&O D-i PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D-i PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING Table of Content D-1 PACKAGING ....................................................................................................... 1 D-2 MARKING ........................................................................................................... 1 DE-EM-0001971 WIPP M&O D-1 PART I - THE SCHEDULE SECTION D PACKAGING AND MARKING D-1 PACKAGING Preservation, packaging, and packing for shipment or mailing of all work delivered

  14. Mechanisms of Selective Cleavage of C-O Bonds in Di-aryl Ethers in Aqueous Phase

    SciTech Connect (OSTI)

    He, Jiayue; Zhao, Chen; Mei, Donghai; Lercher, Johannes A.

    2014-01-02

    A novel route for cleaving the C-O aryl ether bonds of p-substituted H-, CH3-, and OH- diphenyl ethers has been explored over Ni/SiO2 catalysts at very mild conditions. The C-O bond of diphenyl ether is cleaved by parallel hydrogenolysis and hydrolysis (hydrogenolysis combined with HO* addition) on Ni. The rates as a function of H2 pressure from 0 to 10 MPa indicate that the rate-determining step is the C-O bond cleavage on Ni. H* atoms compete with the organic reactant for adsorption leading to a maximum in the rate with increasing H2 pressure. In contrast to diphenyl ether, hydrogenolysis is the exclusive route for cleaving an ether C-O bond of di-p-tolyl ether to form p-cresol and toluene. 4,4'-dihydroxydiphenyl ether undergoes sequential surface hydrogenolysis, first to phenol and HOC6H4O* (adsorbed), which is then cleaved to phenol (C6H5O* with added H*) and H2O (O* with two added H*) in a second step. Density function theory supports the operation of this pathway. Notably, addition of H* to HOC6H4O* is less favorable than a further hydrogenolytic C-O bond cleavage. The TOFs of three aryl ethers with Ni/SiO2 in water followed the order 4,4'-dihydroxydiphenyl ether (69 h-1) > diphenyl ether (26 h-1) > di-p-tolyl ether (1.3 h-1), in line with the increasing apparent activation energies, ranging from 93 kJ∙mol-1 (4,4'-dihydroxydiphenyl ether) < diphenyl ether (98 kJ∙mol-1) to di-p-tolyl ether (105 kJ∙mol-1). D.M. thanks the support from the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. Computing time was granted by the grand challenge of computational catalysis of the William R

  15. Synthesis, characterization and crystal structure of diaquadi(2,2`-bipyridine)di(dichloroacetato)lanthanide (III) monodichloroacetato

    SciTech Connect (OSTI)

    Lu Weimin, Cheng Yiqiang, Dong Nan

    1995-05-01

    The title complexes, Diaquadi(2,2`-bipyridine)Di(Dichloroacetato)Lanthanide (III) Monodichloroacetato [Ln(CHCI{sub 2}COO){sub 2}(2,2`-bipy){sub 2}(H{sub 2}O){sub 2}]{sup +}(CHCI{sub 2}COO){sup -}(Ln=Dy, Ho, Tm, Er, Yb) were obtained and characterized. [Er(CHCI{sub 2}COOO){sub 2}(2,2`-bipy){sub 2} (H{sub 2}O){sub 2}]+(CHCI{sub 2}COO){sup -} crystallizes in the monoclinic space group P2{sub 1}/n with Z=4. Cell dimensions are a=15.886 (9), b=13.758(2), c=16.343(4) {angstrom}, {Beta}=113.31(3){degrees}, and the structure was refined to an R of 0.049 for 3415 observed reflections. The Er(III) ion exhibits a distorted, square antiprismatic configuration. Four N atoms of 2,2`-bipy and four O atoms from two dichloroacetato and two water ligands are coordinated. One dichloroacetato group lies outside the polyhedron and is connected with water ligands by hydrogen bonds.

  16. DiMES Studies of Temperature Dependence of Carbon Erosion and Re-Deposition in the DIII-D Divertor

    SciTech Connect (OSTI)

    Rudakov, D L; Jacob, W; Krieger, K; Litnovsky, A; Philipps, V; West, W P; Wong, C C; Allen, S L; Bastasz, R J; Boedo, J A; Brooks, N H; Boivin, R L; De Temmerman, G; Fenstermacher, M E; Groth, M; Hollmann, E M; Lasnier, C J; McLean, A G; Moyer, R A; Stangeby, P C; Wampler, W R; Watkins, J G; Wienhold, P; Whaley, J

    2007-03-15

    A strong effect of a moderately elevated surface temperature on net carbon deposition and deuterium co-deposition in the DIII-D divertor was observed under detached conditions. A DiMES sample with a gap 2 mm wide and 18 mm deep was exposed to lower-single-null (LSN) L-mode plasmas first at room temperature, and then at 200 C. At the elevated temperature, deuterium co-deposition in the gap was reduced by an order of magnitude. At the plasma-facing surface of the heated sample net carbon erosion was measured at a rate of 3 nm/s, whereas without heating net deposition is normally observed under detachment. In a related experiment three sets of molybdenum mirrors recessed 2 cm below the divertor floor were exposed to identical LSN ELMy H-mode discharges. The first set of mirrors exposed at ambient temperature exhibited net carbon deposition at a rate of up to 3.7 nm/s and suffered a significant drop in reflectivity. In contrast, two other mirror sets exposed at elevated temperatures between 90 C and 175 C exhibited practically no carbon deposition.

  17. Seismic models of a carbonate foreslope-to-basin transition, Picco di Vallandro, Dolomite Alps, northern Italy

    SciTech Connect (OSTI)

    Rudolph, K.W. ); Schlager, W. ); Biddle, K.T. )

    1989-05-01

    Detailed geologic cross sections, augmented by laboratory calibration of lithology and acoustic impedance, have been used to produce synthetic reflection seismic sections of a carbonate foreslope-to-basin transition. Two areas from the Picco di Vallandro region of the Dolomite Alps were modeled: a progradational section and a retrogradational (backstepping) section. The resulting models show how these complex areas of strata interfingering might be displayed on conventional reflection seismic lines. In the area of progradation, rapid stratigraphic thinning below seismic detectibility, coupled with abrupt impedance changes, produces a reflection discontinuity between steeply dipping reflections of the foreslope and gently dipping paralle reflections of the basin section. This apparent downlap surface marks the toe-of-slope for successive clinoforms but dose not correspond to a discrete stratigraphic surface. In the backstepping example, similar stratigraphic thinning and impedance changes create an apparent onlap surface. Wavelet interference causes complications in both examples. These models indicate how stratigraphic complexity can be simplified by the seismic reflection process and suggest that caution should be exercised when using seismic data to construct general models in areas of complex depositional geometries and rapidly changing facies.

  18. Anomalous dynamics of aqueous solutions of di-propylene glycol methylether confined in MCM-41 by quasielastic neutron scattering

    SciTech Connect (OSTI)

    Swenson, Jan Elamin, Khalid; Chen, Guo; Lohstroh, Wiebke; Sakai, Victoria Garcia

    2014-12-07

    The molecular dynamics of solutions of di-propylene glycol methylether (2PGME) and H{sub 2}O (or D{sub 2}O) confined in 28 Å pores of MCM-41 have been studied by quasielastic neutron scattering and differential scanning calorimetry over the concentration range 0–90 wt.% water. This system is of particular interest due to its pronounced non-monotonic concentration dependent dynamics of 2PGME in the corresponding bulk system, showing the important role of hydrogen bonding for the dynamics. In this study we have elucidated how this non-monotonic concentration dependence is affected by the confined geometry. The results show that this behaviour is maintained in the confinement, but the slowest diffusive dynamics of 2PGME is now observed at a considerably higher water concentration; at 75 wt.% water in MCM-41 compared to 30 wt.% water in the corresponding bulk system. This difference can be explained by an improper mixing of the two confined liquids. The results suggest that water up to a concentration of about 20 wt.% is used to hydrate the hydrophilic hydroxyl surface groups of the silica pores, and that it is only at higher water contents the water becomes partly mixed with 2PGME. Hence, due to this partial micro-phase separation of the two liquids larger, and thereby slower relaxing, structural entities of hydrogen bonded water and 2PGME molecules can only be formed at higher water contents than in the bulk system. However, the Q-dependence is unchanged with confinement, showing that the nature of the molecular motions is preserved. Thus, there is no indication of localization of the dynamics at length scales of less than 20 Å. The dynamics of both water and 2PGME is strongly dominated by translational diffusion at a temperature of 280 K.

  19. Di(2-ethylhexyl) phthalate inhibits antral follicle growth, induces atresia, and inhibits steroid hormone production in cultured mouse antral follicles

    SciTech Connect (OSTI)

    Hannon, Patrick R. Brannick, Katherine E. Wang, Wei Gupta, Rupesh K. Flaws, Jodi A.

    2015-04-01

    Di(2-ethylhexyl) phthalate (DEHP) is a ubiquitous environmental toxicant found in consumer products that causes ovarian toxicity. Antral follicles are the functional ovarian units and must undergo growth, survival from atresia, and proper regulation of steroidogenesis to ovulate and produce hormones. Previous studies have determined that DEHP inhibits antral follicle growth and decreases estradiol levels in vitro; however, the mechanism by which DEHP elicits these effects is unknown. The present study tested the hypothesis that DEHP directly alters regulators of the cell cycle, apoptosis, and steroidogenesis to inhibit antral follicle functionality. Antral follicles from adult CD-1 mice were cultured with vehicle control or DEHP (1–100 μg/ml) for 24–96 h to establish the temporal effects of DEHP on the follicle. Following 24–96 h of culture, antral follicles were subjected to gene expression analysis, and media were subjected to measurements of hormone levels. DEHP increased the mRNA levels of cyclin D2, cyclin dependent kinase 4, cyclin E1, cyclin A2, and cyclin B1 and decreased the levels of cyclin-dependent kinase inhibitor 1A prior to growth inhibition. Additionally, DEHP increased the mRNA levels of BCL2-associated agonist of cell death, BCL2-associated X protein, BCL2-related ovarian killer protein, B-cell leukemia/lymphoma 2, and Bcl2-like 10, leading to an increase in atresia. Further, DEHP decreased the levels of progesterone, androstenedione, and testosterone prior to the decrease in estradiol levels, with decreased mRNA levels of side-chain cleavage, 17α-hydroxylase-17,20-desmolase, 17β-hydroxysteroid dehydrogenase, and aromatase. Collectively, DEHP directly alters antral follicle functionality by inhibiting growth, inducing atresia, and inhibiting steroidogenesis. - Highlights: • DEHP inhibits antral follicle growth by dysregulating cell cycle regulators. • DEHP induces antral follicle atresia by dysregulating apoptosis regulators. • DEHP

  20. THE USE OF DI WATER TO MITIGATE DUSTING FOR ADDITION OF DWPF FRIT TO THE SLURRY MIX EVAPORATOR

    SciTech Connect (OSTI)

    Hansen, E.

    2010-07-21

    objective of this task is to perform bench scale testing on various frits that have been used at DWPF or in test programs at SRNL to determine the quantity of de-ionized (DI) water required to mitigate dusting per mass basis of frit. The quantity of DI water required was determined visually by observing the effluent port of the mixer, and DI water addition was made to the point where no visible dust was observed leaving the effluent port. A total of eight different frits were selected for testing. Secondary objectives in this task include the following: (1) Video taping of the de-dusting procedure, (2) Particle size distribution analyses of the dry and wetted frits at the weight fraction of water required for de-dusting, (3) Plate flow tests to determine angle of flow and quantity of material remaining on plate at 90 degrees, (4) Microscopy of dry and wetted frit, and (5) Effect of excess water for selected frits on plate flow. The above analyses were performed within one hour of water addition, to minimize the effect of evaporative water losses. To better understand the size of dust particles, perform settling tests on selected frits and capture the fines. Analyze the fines for particle size distribution. Finally, it is expected that the surface area of frit is an important parameter in the quantity of water required for dust mitigation. An analysis of particle size distribution (PSD) data of as-received frit analyzed by SRNL over the past two to three years will be performed to determine the variation in the distribution of as-received frit. The following objectives were stated in the Technical Task Request4 as objectives that given adequate time would provide insight in helping DWPF in assessing equipment or processes for de-dusting and processing of dry frit. Due to time constraints, commercial methods for dedusting are provided. These results are detailed in section 3.7. Obtain design information from Hanford with respective to equipment used for dedusting. Suggestions

  1. Low Cost SiOx-Graphite and Olivine Materials

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  2. Transient PrOx carbon monoxide measurement, control, and optimization

    SciTech Connect (OSTI)

    Inbody, M. A.; Borup, R. L.; Tafoya, J.

    2002-01-01

    Fuel processing systems for low temperature polymer electrolyte membrane (PEM) fuel cell systems require control of the carbon monoxide concentration to less than 100 ppm to 10 ppm in the anode feed. Conventional hydrocarbon fuel processors use a water-gas shift (WGS) reactor to react CO with water to form H2 and reduce the CO concentration. The CO conversion is limited by equilibrium at the outlet temperature of the WGS reactor. The WGS outlet CO concentration can range from over 1% to 2000 ppm depending on the system and its operating parameters. At these concentrations, CO poisons low temperature PEM fuel cells and the concentrations needs to be reduced further.

  3. Low Cost SiOx-Graphite and Olivine Materials

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  4. DiTour

    Energy Science and Technology Software Center (OSTI)

    2014-06-05

    it is common for facilities to have a lobby with a display loop while also requiring an option for guided tours. Existing solutions have required expensive hardware and awkward software. Our solution is relative low cost as it runs on an iPad connected to an external monitor, and our software provides an intuitive touch interface. The media files are downloaded from a web server onto the device allowing a mobile option (e.g. displays at conferences).more » Media may include arbitrary sequences of images, movies or PDF documents. Tour guides can select different tracks of slides to display and the presentation will return to the default loop after a timeout.« less

  5. DiTour

    SciTech Connect (OSTI)

    Pelaia, II, Thomas A.

    2014-06-05

    it is common for facilities to have a lobby with a display loop while also requiring an option for guided tours. Existing solutions have required expensive hardware and awkward software. Our solution is relative low cost as it runs on an iPad connected to an external monitor, and our software provides an intuitive touch interface. The media files are downloaded from a web server onto the device allowing a mobile option (e.g. displays at conferences). Media may include arbitrary sequences of images, movies or PDF documents. Tour guides can select different tracks of slides to display and the presentation will return to the default loop after a timeout.

  6. Extraction of uranium(VI) by N,N-di-(2-ethylhexyl)isobutyramide (DEHIBA): from the batch experimental data to the countercurrent process

    SciTech Connect (OSTI)

    Miguirditchian, M.; Sorel, C.; Cames, B.; Bisel, I.; Baron, P.

    2008-07-01

    The selective separation of uranium(VI) in the first cycle of the GANEX process is operated by a hydrometallurgical process using a monoamide extractant DEHiBA (N,N-di-(2-ethylhexyl)isobutyramide). Distribution ratios of uranium(VI) and nitric acid in 1 M DEHiBA/HTP were determined with macro-concentrations of uranium, and the experimental data were modelled by taking into account the activity coefficients of the constituents in aqueous phases. A flowsheet was designed and tested in a countercurrent process in laboratory-scale mixer-settlers on a surrogate U(VI)/HNO 3 feed. More than 99.999% of the uranium was recovered. (authors)

  7. Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes

    DOE Patents [OSTI]

    Kerr, John B.; Tian, Minmin

    2000-01-01

    A electrochemical cell is described comprising an anode, a cathode, a solid polymer electrolyte, and a redox shuttle additive to protect the cell against overcharging and a redox shuttle additive to protect the cell against overcharging selected from the group consisting of: (a) a substituted anisole having the general formula (in an uncharged state): ##STR1## where R.sub.1 is selected from the group consisting of H, OCH.sub.3, OCH.sub.2 CH.sub.3, and OCH.sub.2 phenyl, and R.sub.2 is selected from the group consisting of OCH.sub.3, OCH.sub.2 CH.sub.3, OCH.sub.2 phenyl, and O.sup.- Li.sup.+ ; and (b) a di-anisole compound having the general formula (in an uncharged state): ##STR2## where R is selected from the group consisting of -OCH.sub.3 and -CH.sub.3, m is either 1 or 0, n is either 1 or 0, and X is selected from the group consisting of -OCH.sub.3 (methoxy) or its lithium salt --O.sup.- Li.sup.+. The lithium salt of the di-anisole is the preferred form of the redox shuttle additive because the shuttle anion will then initially have a single negative charge, it loses two electrons when it is oxidized at the cathode, and then moves toward the anode as a single positively charged species where it is then reduced to a single negatively charged species by gaining back two electrons.

  8. An in-cylinder study of the particulate/NO{sub x} trade-off in a DI Diesel Engine. Draft of final report

    SciTech Connect (OSTI)

    Litzinger, T.A.; Santavicca, D.A.; Santoro, R.J.

    1994-07-01

    The goal of the work performed during the contract period was to establish the ability to study soot and NO within the combustion chamber of a DI Diesel engine and to couple these measurements with actual exhaust emissions. This work was motivated by the need to obtain a more complete understanding of the particulate/NO{sub X} trade-off, observed in Diesel engines, to aid engine designers in meeting emissions limits. In order to achieve the desired goal, an optically accessible DI Diesel engine was designed and constructed. Also, planar imaging methods for imaging soot and NO were developed in laboratory flames and were then applied to the engine. For the study of soot, planar Mie scattering was used and a polarization ratio method was investigated to distinguish soot from fuel droplets. The Mie scattering technique proved to be well suited for the engine, and extensive results were obtained. In order to observe NO, planar laser induced fluorescence was used and it was successfully applied in the engine. In addition to these techniques, high speed combustion photography and shadowgraph photography were applied to obtain general characteristics of the combustion process. As a final diagnostic, actual engine emissions were measured. This report begins with a brief discussion of the problem under investigation and a summary of other studies of the NO{sub x}/particulate trade-off. Following these sections is a summary of the accomplishments and results from the present study. Finally, detailed results are presented through the six technical papers which were written during the contract period; these papers are appended to the report.

  9. Gold(I) chloride adducts of 1,3-bis(di-2-pyridylphosphino)propane: synthesis, structural studies and antitumour activity

    SciTech Connect (OSTI)

    Humphreys, Anthony S.; Filipovska, Aleksandra; Berners-Price, Susan J.; Koutsantonis, George A.; Skelton, Brian W.; White, Allan H.

    2008-06-30

    The novel water soluble bidentate phosphine ligand 1,3-bis(di-2-pyridylphosphino)propane (d2pypp) has been synthesized by a convenient route involving treatment of 2-pyridyllithium with Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} and isolation in crystalline form as the hydrochloride salt. The synthesis of the precursor Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} has been optimized by the use of triphosgene as the chlorinating agent. The 2:1 and 1:2 AuCl:d2pypp adducts have been synthesized and characterized by NMR spectroscopy and single crystal X-ray studies, and shown to be of the form (AuCl){sub 2}({mu}-d2pypp-P,P{prime}) and Au(d2pypp-P,P{prime}){sub 2}Cl(-3.75H{sub 2}O), respectively. The latter is more lipophilic than analogous 1:2 adducts of gold(I) chloride with the diphosphine ligands 1,2-bis(di-n-pyridylphosphino)ethane (dnpype) for n = 2, 3 and 4, based on measurement of the n-octanol-water partition coefficient (log P = -0.46). A single crystal structure determination of the 1:2 Au(I) complex of the 3-pyridyl ethane ligand shows it to be of the form [Au(d3pype-P,P{prime}){sub 2}]Cl {center_dot} 5H{sub 2}O. The in vitro cytotoxic activity of [Au(d2pypp){sub 2}]Cl was assessed in human normal and cancer breast cells and selective toxicity to the cancer cells found. The significance of these results to the antitumour properties of chelated 1:2 Au(I) diphosphine complexes is discussed.

  10. Synthesis and characterization of d{sup 10} metal complexes with mixed 1,3-di(1H-imidazol-4-yl)benzene and multicarboxylate ligands

    SciTech Connect (OSTI)

    Chen, Zhi-Hao; Zhao, Yue; Chen, Shui-Sheng; Wang, Peng; Sun, Wei-Yin

    2013-06-15

    Seven new coordination polymers [Zn(H{sub 2}L)(mbdc)] (1), [Zn(H{sub 3}L)(btc)] (2), [Zn(H{sub 2}L)(Hbtc)] (3), [Zn(H{sub 2}L)(Hbtc)]H{sub 2}O (4), [Zn{sub 2}(H{sub 2}L)(btc)(?{sub 2}-OH)] (5), [Cd(H{sub 2}L)(mbdc)] (6) and [Cd{sub 3}(H{sub 2}L){sub 2}(btc){sub 2}(H{sub 2}O)]5H{sub 2}O (7) were synthesized by reactions of the corresponding metal salt with rigid ligand 1,3-di(1H-imidazol-4-yl)benzene (H{sub 2}L) and different carboxylic acids of 1,3-benzenedicarboxylic acid (H{sub 2}mbdc) and benzene-1,3,5-tricarboxylic acid (H{sub 3}btc), respectively. The results of X-ray crystallographic analysis indicate that complex 1 is 1D chain while 2 is a (3,3)-connected 2D network with Point (Schlfli) symbol of (4,8{sup 2}). Complexes 3 and 6 are 2D networks, 4 is a 3-fold interpenetrating 3D framework with Point (Schlfli) symbol of (6{sup 5},8) and 5 is a (3,8)-connected 2D network with Point (Schlfli) symbol of (3,4{sup 2}){sub 2}(3{sup 4},4{sup 6},5{sup 6},6{sup 8},7{sup 3},8), while 7 is a (3,10)-connected 3D net with Schlfli symbol of (3,4,5){sub 2}(3{sup 4},4{sup 8},5{sup 18},6{sup 12},7{sup 2},8). The thermal stability and photoluminescence of the complexes were investigated. Furthermore, DFT calculations were performed for 24 to discuss the temperature controlled self-assembly of the complexes. - Graphical abstract: Seven new coordination polymers with multicarboxylate and rigid ditopic 4-imidazole containing ligands have been obtained and found to show different structures and topologies. - Highlights: Metal complexes with diverse structures of 1D chain, 2D network and 3D framework. Mixed ligands of 1,3-di(1H-imidazol-4-yl)benzene and multicarboxylate. Photoluminescence property.

  11. Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia

    SciTech Connect (OSTI)

    Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

    2014-03-15

    Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

  12. Study of very high pressure fuel-injection for high-BMEP DI-diesel engine. Final report, 30 September 1997--28 February 1999

    SciTech Connect (OSTI)

    Rhee, K.T.

    1999-03-16

    In order to help design a high-power-density (HPD) low-heat-rejection (LHR) high-injection-fuel (HIP) direct-injection compression-ignition engine (DI-CI), two main methods were employed: (1) engine performance analysis; and (2) in-cylinder imaging. In the performance analysis, a Cummins 903 engine was used. The range of air/fuel ratio studied was from 18-1 to over 35-1, the injection pressure investigated was as high as 30,625 psi (210 Mpa) under varied intake air temperature over 150 deg C. In the in-cylinder imaging, a separate optical single-cylinder Cummins 903 engine was used. A high-speed four-color IR digital imaging system was greatly improved during this contract period. New spectrometric methods were developed to simultaneously determine the distributions of temperature, water vapor and soot concentrations. In addition, a new data analysis and presentation method has been developed. The performance analysis results are reported in two parts: a preliminary report as included in Appendix-I and an additional set of results (Appendix-III). Some of the in-cylinder imaging results, which are now being captured by the improved 515 after incorporating with new electronic packages (designed and fabricated in the laboratory), are included with discussions.

  13. Understanding the Electronic Structure of 4d Metal Complexes: From Molecular Spinors to L-Edge Spectra of a di-Ru Catalyst

    SciTech Connect (OSTI)

    Alperovich, Igor; Smolentsev, Grigory; Moonshiram, Dooshaye; Jurss, Jonah W.; Concepcion, Javier J.; Meyer, Thomas J.; Soldatov, Alexander; Pushkar, Yulia

    2015-09-17

    L{sub 2,3}-edge X-ray absorption spectroscopy (XAS) has demonstrated unique capabilities for the analysis of the electronic structure of di-Ru complexes such as the blue dimer cis,cis-[Ru{sub 2}{sup III}O(H{sub 2}O){sub 2}(bpy){sub 4}]{sup 4+} water oxidation catalyst. Spectra of the blue dimer and the monomeric [Ru(NH{sub 3}){sub 6}]{sup 3+} model complex show considerably different splitting of the Ru L{sub 2,3} absorption edge, which reflects changes in the relative energies of the Ru 4d orbitals caused by hybridization with a bridging ligand and spin-orbit coupling effects. To aid the interpretation of spectroscopic data, we developed a new approach, which computes L{sub 2,3}-edges XAS spectra as dipole transitions between molecular spinors of 4d transition metal complexes. This allows for careful inclusion of the spin-orbit coupling effects and the hybridization of the Ru 4d and ligand orbitals. The obtained theoretical Ru L{sub 2,3}-edge spectra are in close agreement with experiment. Critically, existing single-electron methods (FEFF, FDMNES) broadly used to simulate XAS could not reproduce the experimental Ru L-edge spectra for the [Ru(NH{sub 3}){sub 6}]{sup 3+} model complex nor for the blue dimer, while charge transfer multiplet (CTM) calculations were not applicable due to the complexity and low symmetry of the blue dimer water oxidation catalyst. We demonstrated that L-edge spectroscopy is informative for analysis of bridging metal complexes. The developed computational approach enhances L-edge spectroscopy as a tool for analysis of the electronic structures of complexes, materials, catalysts, and reactive intermediates with 4d transition metals.

  14. Visible Light-Induced Electron Transfer from Di-mu-oxo Bridged Dinuclear Mn Complexes to Cr Centers in Silica Nanopores

    SciTech Connect (OSTI)

    Frei, Heinz; Weare, Walter W.; Pushkar, Yulia; Yachandra, Vittal K.; Frei, Heinz

    2008-06-03

    The compound (bpy)2MnIII(mu-O)2MnIV(bpy)2, a structural model relevant for the photosynthetic water oxidation complex, was coupled to single CrVI charge-transfer chromophores in the channels of the nanoporous oxide AlMCM-41. Mn K-edge EXAFS spectroscopy confirmed that the di-mu-oxo dinuclear Mn core of the complex is unaffected when loaded into the nanoscale pores. Observation of the 16-line EPR signal characteristic of MnIII(mu-O)2MnIV demonstrates that the majority of the loaded complexes retained their nascent oxidation state in the presence or absence of CrVI centers. The FT-Raman spectrum upon visible light excitation of the CrVI-OII --> CrV-OI ligand-to-metal charge-transfer reveals electron transfer from MnIII(mu-O)2MnIV (Mn-O stretch at 700 cm-1) to CrVI, resulting in the formation of CrV and MnIV(mu-O)2MnIV (Mn-O stretch at 645 cm-1). All initial and final states are directly observed by FT-Raman or EPR spectroscopy, and the assignments corroborated by X-ray absorption spectroscopy measurements. The endoergic charge separation products (DELTA Eo = -0.6 V) remain after several minutes, which points to spatial separation of CrV and MnIV(mu-O)2MnIV as a consequence of hole (OI) hopping as a major contributing mechanism. This is the first observation of visible light-induced oxidation of a potential water oxidation complex by a metal charge-transfer pump in a nanoporous environment. These findings will allow for the assembly and photochemical characterization of well defined transition metal molecular units, with the ultimate goal of performing endothermic, multi-electron transformations that are coupled to visible light electron pumps in nanostructured scaffolds.

  15. Evaluating the use of PAO (4 cSt polyalphaoelfin) oil instead of DOP (di-octyl phthalate) oil for measuring the aerosol capture of nuclear canister filters

    SciTech Connect (OSTI)

    Moore, Murray E.

    2014-07-18

    This document details the distinction between using PAO (4 cSt polyalphaoelfin) oil instead of DOP (di-octyl phthalate) oil for measuring the aerosol capture of filters. This document is developed to justify the use of PAO rather than DOP for evaluating the performance of filters in the SAVY 4000 and Hagan containers. The design criteria (Anderson et al, 2012) for purchasing SAVY 4000 containers and the Safety Analysis Report for the SAVY 4000 Container Series specified that the filter must “capture greater than 99.97% of 0.45 μm mean diameter dioctyl phthalate (DOP) aerosol at the rated flow with a DOP concentration of 65±15 micrograms per liter.”This corresponds to a leakage percent of 0.03% (3.0x10-2). The density of DOP oil is 985 kg/m3 and the density of PAO oil is 819 kg/m3. ATI Test Inc measured the mass mean diameter of aerosol distributions produced by a single Laskin type III-A nozzle operating at a 20 psig air pressure as 0.563 μm for DOP oil and 0.549 μm for PAO oil. (See Appendix A.) For both types of oil in this document, the single fiber method calculated the leakage percent to be 4.4x10-5 for DOP oil and 4.7x10-5 for PAO oil. Although the percent error between these two quantities is 7.7%, these calculated leakage percent values are more than two orders of magnitude less than the criterion specified in the SAVY canister SAR. As a point of reference, the photometer used to measure the SAVY canister filter performance cannot resolve values for the leakage percent below 1.0x10-5. Additionally, over a range of particle sizes from 0.01 μm to 3.0 μm, there was less than 4.0x10-5 error between the calculated filter efficiency for the two types of oil at any particular particle size diameter. In conclusion, the difference between using DOP and PAO for testing SAVY canister filters is of inconsequential concern.

  16. INFN - LABORATORI NAZIONALI DI FRASCATI

    Office of Scientific and Technical Information (OSTI)

    1 - FERMILAB-CONF-13-037-APC IHEP-AC-2013-001 SLAC-PUB-15370 CERN-ATS-2013-032 arXiv:1302.3318 physics.acc-ph Report of the ICFA Beam Dynamics Workshop "Accelerators for a Higgs...

  17. Separation of actinides(III) from lanthanides(III) by extraction chromatography using new n,n'-dialkyl-n,n'-diphenyl-pyridine-2,6-di-carboxy-amides

    SciTech Connect (OSTI)

    Arisaka, Makoto; Watanabe, Masayuki; Kimura, Takaumi

    2007-07-01

    Four N,N'-dialkyl-N,N'-diphenyl-pyridine-2,6- di-carboxy-amides (R-PDA; R butyl, octyl, decyl, dodecyl) were newly synthesized and were applied to extraction chromatography as extractant to attain the separation of actinides(III) from high level radioactive waste containing lanthanides(III). R-PDA was successfully impregnated into XAD-4 resin. It was found that (i) the leakage of R-PDA from XAD-4 resin was suppressed with an increase of the length of the alkyl groups in R-PDA, while the leakage for each adsorbent resin was promoted with an increase of HNO{sub 3} concentration in the aqueous phase and (ii) Oc-PDA or De-PDA/XAD-4 resin exhibits moderate separation ability of actinides(III) from lanthanides(III) at relatively high HNO{sub 3} concentration. (authors)

  18. Large voltage-induced modification of spin-orbit torques in Pt/Co/GdOx

    SciTech Connect (OSTI)

    Emori, Satoru Bauer, Uwe; Woo, Seonghoon; Beach, Geoffrey S. D.

    2014-12-01

    We report on large modifications of current-induced spin-orbit torques in a gated Pt/Co/Gd-oxide microstrip due to voltage-driven O{sup 2−} migration. The Slonczewski-like and field-like torques are quantified using a low-frequency harmonic technique based on the polar magneto-optical Kerr effect. Voltage-induced oxidation of Co enhances the Slonczewski-like torque by as much as an order of magnitude and simultaneously reduces the anisotropy energy barrier by a factor of ∼5. Such magneto-ionic tuning of interfacial spin-orbit effects may significantly enhance the efficiency of magnetization switching and provide additional degrees of freedom in spintronic devices.

  19. Some Lessons Learned from 20 Years in RedOx Flow Battery R&d

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    metals recovery Advanced materials and nano-structures Novel catalysts High ... (low p) Materials Novel nano-structured non- carbon electrodes ...

  20. Adsorption and Reaction of C1-C3 Alcohols over CeOx(111) Thin Films

    SciTech Connect (OSTI)

    D Mullins; S Senanayake; T Chen

    2011-12-31

    This study reports the interaction of methanol, ethanol, 1-propanol, and 2-propanol with well-ordered CeO{sub 2}(111) thin film surfaces. All of the alcohols adsorb at low temperature by forming alkoxy and hydroxyl species on the surface. On fully oxidized CeO{sub 2}(111), recombination occurs between some of the alkoxys and hydroxyls, resulting in alcohol desorption near 220 K. At the same temperature, some of the surface hydroxyls disproportionate to produce water and the loss of lattice O. The remaining alkoxys react above 550 K. The primary alcohols favor dehydrogenation products (aldehydes). There is a net loss of O from the system, resulting in a reduction of the ceria. The secondary alcohol, 2-propanol, undergoes primarily dehydration, producing propene with no net change in the cerium oxidation state. Reduced CeO{sub x}(111) competes with the gaseous products for available O. Little or no water is produced. The reaction selectivity for the C{sub 2} and C{sub 3} alcohols shifts toward favoring dehydration products. The loss of O from the alcohols leads to oxidation of the reduced ceria. Compared with the oxidized surface, the alkene desorption shifts to lower temperature, whereas the aldehyde desorption shifts to higher temperature. This indicates that, on the reduced surface, it is easier to break the C-O bond but more difficult to break the O-substrate bond.

  1. Catalytic activity in lithium-treated core-shell MoOx/MoS2 nanowires...

    Office of Scientific and Technical Information (OSTI)

    The high electrochemical activity in the nanowires results ... 119; Journal Issue: 40; Journal ID: ISSN 1932-7447 Publisher: American Chemical Society Research Org: Los Alamos ...

  2. Structural evolution of epitaxial SrCoOx films near topotactic...

    Office of Scientific and Technical Information (OSTI)

    films near topotactic phase transition Control of oxygen stoichiometry in complex oxides ... indicating that topotactic phase control can be a useful tool to control the ...

  3. Low Cost SiOx-Graphite and High Voltage Spinel Cathode

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  4. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22) Country of Publication: United States Language: English Subject: 30 DIRECT ENERGY CONVERSION CO ...

  5. Reversible redox reactions in an epitaxially stabilized SrCoOx...

    Office of Scientific and Technical Information (OSTI)

    DOE Contract Number: DE-AC05-00OR22725 Resource Type: Journal Article Resource Relation: Journal Name: Nature Materials; Journal Volume: 12; Journal Issue: 11 Research Org: Oak ...

  6. Transient control of carbon monoxide with staged PrOx reactors

    SciTech Connect (OSTI)

    Inbody, M. A.; Borup, R. L.; Tafoya, J.

    2002-01-01

    Fuel Processor systems generate hydrogen for fuel cell systems from hydrocarbon fuels such as gasoline for automotive fuel cell systems and natural gas for stationary fuel cell systems. These fuel processor systems must remove any contaminants to levels that won't poison the fuel cell before the outlet hydrogen-rich gas stream can be used by the fuel cell to generate electricity. Carbon monoxide is a contaminant that must be removed to levels of < 100 ppm or < 10 ppm depending on the CO tolerance of the fuel cell. Typically, the last unit operation in a fuel processor is a preferential oxidation reactor or a selective oxidation reactor, which removes CO by oxidizing it to form C02. These are catalytic reactors where the catalyst and operating conditions are selected so that the oxidation rate of the carbon monoxide is higher than the oxidation rate of hydrogen, even though the hydrogen is present at much higher concentrations (> 30%) than carbon monoxide which is present at trace concentrations (< 1%).

  7. Reversal of the Lattice Structure in SrCoOx Epitaxial Thin Films...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Journal Name: Physical Review Letters; Journal Volume: 111; Journal ... Export Metadata Endnote Excel CSV XML Save to My Library Send to Email Send to Email ...

  8. Interfacial engineering of solution-processed Ni nanochain-SiOx...

    Office of Scientific and Technical Information (OSTI)

    Title: Interfacial engineering of solution-processed Ni ... 03755, USA Department of Chemical and Materials ... Type: Publisher's Accepted Manuscript Journal Name: Journal ...

  9. Improving the efficiency of copper indium gallium (Di-)selenide (CIGS) solar cells through integration of a moth-eye textured resist with a refractive index similar to aluminum doped zinc oxide

    SciTech Connect (OSTI)

    Burghoorn, M.; Kniknie, B.; Deelen, J. van; Ee, R. van; Xu, M.; Vroon, Z.; Belt, R. van de; Buskens, P. E-mail: buskens@dwi.rwth-aachen.de

    2014-12-15

    Textured transparent conductors are widely used in thin-film silicon solar cells. They lower the reflectivity at interfaces between different layers in the cell and/or cause an increase in the path length of photons in the Si absorber layer, which both result in an increase in the number of absorbed photons and, consequently, an increase in short-circuit current density (J{sub sc}) and cell efficiency. Through optical simulations, we recently obtained strong indications that texturing of the transparent conductor in copper indium gallium (di-)selenide (CIGS) solar cells is also optically advantageous. Here, we experimentally demonstrate that the J{sub sc} and efficiency of CIGS solar cells with an absorber layer thickness (d{sub CIGS}) of 0.85 μm, 1.00 μm and 2.00 μm increase through application of a moth-eye textured resist with a refractive index that is sufficiently similar to AZO (n{sub resist} = 1.792 vs. n{sub AZO} = 1.913 at 633 nm) to avoid large optical losses at the resist-AZO interface. On average, J{sub sc} increases by 7.2%, which matches the average reduction in reflection of 7.0%. The average relative increase in efficiency is slightly lower (6.0%). No trend towards a larger relative increase in J{sub sc} with decreasing d{sub CIGS} was observed. Ergo, the increase in J{sub sc} can be fully explained by the reduction in reflection, and we did not observe any increase in J{sub sc} based on an increased photon path length.

  10. Distinguishing tautomerism in the crystal structure of (Z)-N-(5-ethyl-2,3-di-hydro-1,3,4-thiadiazol-2-ylidene) -4-methylbenzenesulfonamide using DFT-D calculations and {sup 13}C solid-state NMR

    SciTech Connect (OSTI)

    Li, Xiaozhou; Bond, Andrew D.; Johansson, Kristoffer E.; Van de Streek, Jacco

    2014-08-01

    The crystal structure of (Z)-N-(5-ethyl-2,3-di-hydro-1,3,4-thiadiazol-2-ylidene) -4-methylbenzenesulfonamide contains an imine tautomer, rather than the previously reported amine tautomer. The tautomers can be distinguished using dispersion-corrected density functional theory calculations and by comparison of calculated and measured {sup 13}C solid-state NMR spectra. The crystal structure of the title compound, C{sub 11}H{sub 13}N{sub 3}O{sub 2}S{sub 2}, has been determined previously on the basis of refinement against laboratory powder X-ray diffraction (PXRD) data, supported by comparison of measured and calculated {sup 13}C solid-state NMR spectra [Hangan et al. (2010 ▶). Acta Cryst. B66, 615–621]. The mol@@ecule is tautomeric, and was reported as an amine tautomer [systematic name: N-(5-ethyl-1,3,4-thia@@diazol-2-yl)-p-toluene@@sulfonamide], rather than the correct imine tautomer. The protonation site on the mol@@ecule’s 1,3,4-thia@@diazole ring is indicated by the inter@@molecular contacts in the crystal structure: N—H⋯O hydrogen bonds are established at the correct site, while the alternative protonation site does not establish any notable inter molecular inter@@actions. The two tautomers provide essentially identical Rietveld fits to laboratory PXRD data, and therefore they cannot be directly distinguished in this way. However, the correct tautomer can be distinguished from the incorrect one by previously reported qu@@anti@@tative criteria based on the extent of structural distortion on optimization of the crystal structure using dispersion-corrected density functional theory (DFT-D) calculations. Calculation of the {sup 13}C SS-NMR spectrum based on the correct imine tautomer also provides considerably better agreement with the measured {sup 13}C SS-NMR spectrum.

  11. Kinetics of di(2-ethylhexyl) phthalate (DEHP) and mono(2-ethylhexyl) phthalate in blood and of DEHP metabolites in urine of male volunteers after single ingestion of ring-deuterated DEHP

    SciTech Connect (OSTI)

    Kessler, Winfried; Numtip, Wanwiwa; Vlkel, Wolfgang; Seckin, Elcim; Csandy, Gyrgy A.; Institut fr Toxikologie und Umwelthygiene, Technische Universitt Mnchen, Mnchen ; Ptz, Christian; and others

    2012-10-15

    The plasticizer di(2-ethylhexyl) phthalate (DEHP) is suspected to induce antiandrogenic effects in men via its metabolite mono(2-ethylhexyl) phthalate (MEHP). However, there is only little information on the kinetic behavior of DEHP and its metabolites in humans. The toxikokinetics of DEHP was investigated in four male volunteers (2861 y) who ingested a single dose (645 20 ?g/kg body weight) of ring-deuterated DEHP (DEHP-D{sub 4}). Concentrations of DEHP-D{sub 4}, of free ring-deuterated MEHP (MEHP-D{sub 4}), and the sum of free and glucuronidated MEHP-D{sub 4} were measured in blood for up to 24 h; amounts of the monoesters MEHP-D{sub 4}, ring-deuterated mono(2-ethyl-5-hydroxyhexyl) phthalate and ring-deuterated mono(2-ethyl-5-oxohexyl) phthalate were determined in urine for up to 46 h after ingestion. The bioavailability of DEHP-D{sub 4} was surprisingly high with an area under the concentration-time curve until 24 h (AUC) amounting to 50% of that of free MEHP-D{sub 4}. The AUC of free MEHP-D{sub 4} normalized to DEHP-D{sub 4} dose and body weight (AUC/D) was 2.1 and 8.1 times, that of DEHP-D{sub 4} even 50 and 100 times higher than the corresponding AUC/D values obtained earlier in rat and marmoset, respectively. Time courses of the compounds in blood and urine of the volunteers oscillated widely. Terminal elimination half-lives were short (4.36.6 h). Total amounts of metabolites in 22-h urine are correlated linearly with the AUC of free MEHP-D{sub 4} in blood, the parameter regarded as relevant for risk assessment. -- Highlights: ? After DEHP intake, DEHP and MEHP in blood show oscillating time courses. ? Dose-related blood levels of DEHP are 50 times higher in humans than in rats. ? Dose-related blood levels of free MEHP are 2 times higher in humans than in rats. ? Elimination of DEHP and its metabolites is short with half-lives of 4.3-6.6 h.

  12. Thermodynamic properties and ideal-gas enthalpies of formation for butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol

    SciTech Connect (OSTI)

    Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Smith, N.K.

    1996-11-01

    Ideal-gas enthalpies of formation of butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo-[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol are reported. Enthalpies of fusion were determined for bicyclo[2.2.1]hept-2-ene and trans-azobenzene. Two-phase (solid + vapor) or (liquid + vapor) heat capacities were determined from 300 K to the critical region or earlier decomposition temperature for each compound studied. Liquid-phase densities along the saturation line were measured for bicyclo[2.2.1]hept-2-ene. For butyl vinyl ether and 1,2-dimethoxyethane, critical temperatures and critical densities were determined from the dsc results and corresponding critical pressures derived from the fitting procedures. Fitting procedures were used to derive critical temperatures, critical pressures, and critical densities for bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, and di-tert-butyl ether. Group-additivity parameters or ring-correction terms useful in the application of the Benson group-contribution correlations were derived.

  13. DI Semicon Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Seoul, Korea (Republic) Sector: Solar Product: Korean company that offers testing and packaging of Display Drive ID; as of December 2007, entered into a secondary business in solar...

  14. DI-MMAP V.1.0

    Energy Science and Technology Software Center (OSTI)

    002804WKSTN00 Data-Intensive Memory-Map simulator and runtime https://computation.llnl.gov/casc/dcca-pub/dcca/downloads.ht

  15. Basic ReseaRch DiRections

    National Nuclear Security Administration (NNSA)

    ... of nuclear energy to the use of nuclear isotopes for medical diagnostics and treatment. ... probes such as heavy ion accelerators, neutron sources, and rare isotope facilities. ...

  16. Di-Jia Liu | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & high-performance computing Systems architecture & design Physics ... electrode for proton exchange membrane (PEM) fuel cell application; low-cost electrode ...

  17. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ... Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ...

  18. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  19. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  20. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  1. AquaLite Wuhan Di Yuan Optoelectronic | Open Energy Information

    Open Energy Info (EERE)

    Place: Wuhan, Hubei Province, China Zip: 430074 Product: High-power and high-brightness LED manufacturer. Coordinates: 30.572399, 114.279121 Show Map Loading map......

  2. Efficient Emissions Control for Multi-Mode Lean DI Engines

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  3. Process for selective production of di- and tri-alkylamines

    DOE Patents [OSTI]

    Klier, Kamil; Herman, Richard G.; Vedage, Gamini A.

    1984-01-01

    A primary alkyl amine and an alcohol of up to 12 carbon atoms are reacted at low temperature (50.degree.-250.degree. C.) over specific catalysts (alkali-treated catalysts generally or binary Cu/ZnO and Pd/SiO.sub.2 systems, with or without alkali treatment) to produce, with good selectivity, secondary and tertiary alkylamines of the general formula, R.sub.1 N(R.sub.2).sub.2, wherein R.sub.1 is a lower alkyl or an aryl group, and R.sub.2 is hydrogen or another lower alkyl or aryl group, with at least one of R.sub.2 's being an alkyl or aryl group.

  4. Instituto Torcuato Di Tella (ITDT) | Open Energy Information

    Open Energy Info (EERE)

    In the beginning, ITDT categorized activities through research centers specializing in different subjects, mainly economics, social sciences, urban planning, and the arts....

  5. Women @ Energy: Pascale Di Nicola | Department of Energy

    Office of Environmental Management (EM)

    I have always loved science in general; mathematics, physics, and chemistry were my ... I wanted to study organic chemistry to become a fragrance designer, so I followed the ...

  6. Di- and tri-benzotriazole substituted tri-hydroxybenzenes

    DOE Patents [OSTI]

    Vogl, O.; Li, S.

    1983-10-06

    Ultraviolet light stabilizing compounds of the formula (phenyl) R/sub 1/, R/sub 2/(OH)/sub 3/R/sub 3/, are described, wherein R/sub 1/, R/sub 2/, and R/sub 3/ are hydrogen or 2H-benzotriazole-2-yl groups and wherein no more than one of R/sub 1/, R/sub 2/, and R/sub 3/ is hydrogen, and organic compositions susceptible to ultraviolet light degradation containing these compounds, and method for selectively producing the compounds.

  7. Crystal structure of cerium (IV)-di-potassium trisulfate monohydrate

    SciTech Connect (OSTI)

    Kuznetsov, V.Ya.; Dikareva, L.M.; Rogachev, D.L.; Porai-Koshits, M.A.

    1986-07-01

    The compound K2Ce(SO4)3 x H2O (I) was obtained in a study of the system Ce(SO4)2-K2SO4-H2O4-HO2 at 50-150C (1). The refined unit-cell parameters are: a = 20.600(3), b = 7.0744 (6), c = 18.583(3) A, US = 126.083(8), V = 2189(1) AT, Z = 8, rho/sub calc/ = 3.202(2) g/cmT, space group C2. The previously given unit-cell parameters are related to those given here by the matrices 100/010/0.5 0 1 and 100/010/-1 0-1. The intensities of 3416 independent reflections (3363 with I greater than or equal to 2sigma) and the unit cell parameters were measured on a Syntex P21 four-circle automatic diffractometer (lambdaMoK , theta/2 theta scanning at variable rate from 4 to 29.3 deg/min to theta = 60). The structural calculations were done on a Nova 1200 minicomputer by means of the Syntex XTL programs and on an ES 1022 computer by means of the Struktura programs. They used the heavy atom method; the final refinement over 3240 reflections (R = 0.071) was made allowing for the anisotropy of the thermal vibrations of the atoms.

  8. DI-MGMT-81861 DOE Changes Version -- Integrated Program Management...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrated Program Management Report (IPMR) Data Item Description (DID) Earned Value Management System Interpretation Handbook (EVMSIH) Enhancing Earned Value (EV) Analysis Using ...

  9. Institute for Advanced Study Christine Di Bella Institute for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    driven research in the sciences and humanities. Diverse schol- ars including Albert Einstein, Erwin Panofsky, John von Neu- mann, J. Robert Oppenheimer, Freeman Dyson,...

  10. Surface Di-directional Reflectance Properties Over the ARM SGP...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Z. Li Earth System Science Interdisciplinary Center University of Maryland College Park, Maryland Introduction Surface albedo is an important parameter in atmospheric...

  11. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  12. Advanced Lean-Burn DI Spark Ignition Fuels Research

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  13. DI-MGMT-81861 DOE Changes Version | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Earned Value Management System Interpretation Handbook (EVMSIH) Enhancing Earned Value (EV) Analysis Using Project Assessment & Reporting System (PARS II) - Road Show Presentation...

  14. Overview of Sonex Combustion Systems (SCS) for DI Engines

    Broader source: Energy.gov [DOE]

    The SCS system has undergone computational and experimental verification and allows for controlled auto-ignition of low-cetane fuels.

  15. Chesterfield County, Virginia: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Facility Places in Chesterfield County, Virginia Bellwood, Virginia Bensley, Virginia Bon Air, Virginia Chester, Virginia Chesterfield Court House, Virginia Ettrick, Virginia...

  16. Talladega County, Alabama: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Climate Zone Number 3 Climate Zone Subtype A. Places in Talladega County, Alabama Bon Air, Alabama Childersburg, Alabama Lincoln, Alabama Mignon, Alabama Munford, Alabama...

  17. BPA-2015-01168-FOIA Response

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    federal facility in the NW. Example projects that have been completed or are underway: BON hatchery efficiency upgrades, DET lighting upgrades, DWK hatchery VFDs on circulation...

  18. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    SciTech Connect (OSTI)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic - oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria

  19. Mechanistic insights of ethanol steam reforming over Ni-CeOx(111): The importance of hydroxyl groups for suppressing coke formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Senanayake, Sanjaya D.; Duchon, Tomas; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolin, Vladimir; Stacchiola, Dario J.; et al

    2015-07-10

    We have studied the reaction of ethanol and water over NiCeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on NiCeO2-x(111) at varying Ce? concentrations (CeO1.82.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themoreactive phase leading to both the CC and CH cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metalsupport interaction between nickel and ceria that facilitates oxygen transfer.less

  20. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more » oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  1. Tunable Transmittance of Near-infrared and Visible Light in Reconstruc...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... To identify the structural changes in the NbOx amorphous network, the authors performed Raman spectroscopy on pure amorphous NbOx and ITO-in-NbOx with different nanocrystal-glass ...

  2. Apparatus to study crystal channeling and volume reflection phenomena...

    Office of Scientific and Technical Information (OSTI)

    De Salvador, Davide 3 ; Dipartimento di Fisica, Universita di Padova, Via Marzolo 8, ... INFN Sezione di Ferrara, Dipartimento di Fisica, Universita di Ferrara, Via Saragat 1, ...

  3. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... De Francesco, A. (1) Devetta, M. CIMAINA and Dipartimento di Fisica, Universit di ... Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ...

  4. Volume Reflection Dependence of 400 GeV/c Protons on the Bent...

    Office of Scientific and Technical Information (OSTI)

    INFN Sezione di Ferrara, Dipartimento di Fisica, Universita di Ferrara Via Saragat 1, ... 06123 Perugia (Italy) Dipartimento di Fisica, Universita degli Studi di Perugia via ...

  5. High-Efficiency Deflection of High-Energy Protons through Axial...

    Office of Scientific and Technical Information (OSTI)

    INFN Sezione di Ferrara, Dipartimento di Fisica, Universita di Ferrara, Via Saragat 1, ... degli Studi di Perugia, Dipartimento di Fisica, Via Pascoli, 06123 Perugia (Italy) INFN ...

  6. Engineering helimagnetism in MnSi thin films (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    A. A. 1 ; Magnetic Spectroscopy Group, Diamond Light Source, Didcot, OX11 0DE 3 ; ... Kingdom) Magnetic Spectroscopy Group, Diamond Light Source, Didcot, OX11 0DE (United ...

  7. United States Government

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    .---.-.-.--.- -.--..- Department of Enery y memorandum si!%.rE:.c;. Letter Re,porr on "Sandi;;, Natianai .I:,al-ji~;.utory-?L'::'~~i bIe.xieo Stetdent hitern Saf2i-y Training" INS.-L.-OX-46 ('hspeztion 'i'4o. SOS:IS007:) Mzfiager:, Sandla Size 0fr"ice '7'his I.,etter Xtepor? provid.es the results of an CBffice ofInspec1-or Gel~eriii inspection of the student intern safety P P . O ~ T . ~ I X J af the Dcpaxtn~cnt of Energy's (Di:>Ilys] Srnnr1i.a National X,;ll,r>ratr>ry

  8. Donald Frederick, LLNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Donald Frederick, LLNL - Presented at Supercomputing 11 Lawrence Livermore National Laboratory, P. O. Box 808, Livermore, CA 94551! Case Study: Beyond Homogeneous Decomposition with Qbox Scaling Long-Range Forces on Massively Parallel Systems LLNL---PRES---508651 Case S tudy: O utline * Problem D escripBon * ComputaBonal A pproach * Changes f or S caling LLNL---PRES---508651 Computer s imulaBons o f m aterials Computer s imulaBons a re w idely used t o p redict t he p roperBes o f new m aterials

  9. Synthesis, characterization, and structure of a uranyl complex with a disulfide ligand, Bis(di-n-propylammonium) Disulfidobis(di-n-propylthiocarbamato)dioxouranate(VI)

    SciTech Connect (OSTI)

    Perry, D.L.; Zalkin, A.; Ruben, H.; Templeton, D.H.

    1982-01-01

    Olive green crystals of the title compound, ((n-C/sub 3/H/sub 7/)/sub 2/NH/sub 2//sup +/)/sub 2/(UO/sub 2/((n-C/sub 3/H/sub 7/)/sub 2/NCOS)/sub 2/(S/sub 2/))/sup 2 -/, are orthorhombic, space group Pcan, with a = 15.326 (6) A, b = 17.474 (6) A, c = 14.728 (6) A, and Z = 4 (d/sub x/ = 1.45 g/cm/sup 3/). For 1833 data, I > sigma/sub I/, R = 0.052, and R/sub w/ = 0.069. The structure was revealed by single-crystal x-ray diffraction studies to consist of ((n-C/sub 3/H/sub 7/)/sub 2/NH/sub 2/)/sup +/ cations and (UO/sub 2/((n-C/sub 3/H/sub 7/)/sub 2/NCOS)/sub 2/(S/sub 2/))/sup 2 -/ anions with the uranium atom at the center of an irregular hexagonal bipyramid. The uranyl oxygen atoms occupy the axial positions. The equatorial coordiantion plane contains the disulfide (S/sub 2//sup 2 -/) group bonded in a side-on fashion and two oxygen and two sulfur donor atoms from the monothiocarbamate ligands. Interatomic distances are S-S = 2.05 (1) A and U-S = 2.711 (3) A (disulfide), U-S = 2.873 (3) A and U-O = 2.48 (1) A (thiocarbamate), and U-0 = 1.82 (1) A (uranyl). The nitrogen atom in the dipropylammonium cation is hydrogen bonded to the uranyl oxygen atoms.

  10. SYNTHESIS, CHARACTERIZATION, AND STRUCTURE OF A URANYL COMPLEX WITH A DISULFIDE LIGAND, BIS(DI-n-PROPYLAMMONIUM) DISULFIDOBIS (DI-n-PROPYLMONOTHIOCARBAMATO) DIOXOURANATE(VI)

    SciTech Connect (OSTI)

    Perry, Dale L.; Zalkin, Allan; Ruben, Helena; Templeton, David H.

    1981-05-01

    Olive-green crystals of the title compound, [({underline n}-C{sub 3}H{sub 7}){sub 2}NH{sub 2}{sup +}]{sub 2} [UO(({underline n}-C{sub 3}H{sub 7}){sub 2}NCOS){sub 2}(S{sub 2}){sup -2}, are orthorhombic, space group Pcan, with {underline a}= 15.326(6) {Angstrom}, {underline b} = 17.474(6) {Angstrom}, {underline C} = 14.728(6) {Angstrom}, and Z = 4, (d{sub X} = 1.45 g/cm{sup 3}). For 1833 data, I >{sigma}, R = 0.052, and R{sub w} = 0.069. The structure was revealed by single-crystal x-ray diffraction studies to consist of [(n-C{sub 3}H{sub 7}){sub 2}NH{sub 2}]+ cations and [UO{sub 2}(({underline n|-C{sub 3}H{sub 7}){sub 2}NCOS){sub 2}(S{sub 2}){sup -2} anions with the uranium atom at the center of an irregular hexagonal bipyramid. The uranyl oxygen atoms occupy the axial positions. The equatorial coordination plane contains the disulfide (S{sub 2}{sup -2}) group bonded in a "side-on" fashion, and two oxygen and two sulfur donor atoms from the monothiocarbamate ligands. Interatomic distances are S-S = 2.05(1) {Angstrom}, U-S= 2.714(3) {Angstrom} (disulfide); U-S= 2.871(3) {Angstrom} and U-O = 2.46(1) {Angstrom} (thiocarbamate); U-O = 1.81(1) {Angstrom} (uranyl), The nitrogen atom in the dipropylammonium cation is hydrogen bonded to the uranyl oxgyen atoms,

  11. VII-7 RESEARCH PERSONNEL AND ENGINEERING STAFF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A. Bon asera, INF N, Catan ia, Italy 1 V. Kolomietz, INR, Kiev, Ukraine 2 B.H. Sa, CIAE, Beijing, China 3 Y.-M. Zheng, CIAE, Beijing, China 4 RESEARCH STAFF Robert B urch, Jr., Re ...

  12. A Comparative Study of the Mississippian Barnett Shale, Fort...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... The kerogen is classifed as Type II (with minor admixture of Type III) and oil-prone when immature (1.41 hydrogencarbon ratio and 0.10 oxygencar- bon ratio). Pollastro and others ...

  13. REPORT OF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    when the website was released for use during the first week of April 2012, to enable Bon neville to correctly address actions in each month, starting in April 2012. Bonneville...

  14. Managements Discussion and Analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    supply depends on the amount and timing of precipitation in the Columbia Rive es y he Bon T kets wholesale electrical power from 31 federal hydroelectric projects owned and...

  15. BPA-2014-00382-FOIA Response

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bon neville Power Admin istration P.O. Box 362 1 Portla nd, Oregon 97208-3621 August 13, 2014 In reply refer to: FOIA BPA-2014-00382-F Jerry Healy Columbia Basin Electric...

  16. Inder\tMonga CTO,\tEnergy\tSciences\tNetwork Deputy,\tScienEfic\tNetworking...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to New Zealand 2816 2 Image from NZ, Maori Design Pa:ern 2816 3 Talk 2816 4 ESnet and NRENs IntroducBon Established Design Pa:erns Emerging Design Pa:erns DOE's Energy ...

  17. Evidence for near-Surface NiOOH Species in Solution-Processed NiOx Selective Interlayer Materials: Impact on Energetics and the Performance of Polymer Bulk Heterojunction Photovoltaics

    SciTech Connect (OSTI)

    Ratcliff, Erin L.; Meyer, Jens; Steirer, K. Xerxes; Garcia, Andres; Berry, Joseph J.; Ginley, David S.; Olson, Dana C.; Kahn, Antoine; Armstrong, Neal R.

    2011-11-22

    The characterization and implementation of solution-processed, wide bandgap nickel oxide (NiO{sub x}) hole-selective interlayer materials used in bulk-heterojunction (BHJ) organic photovoltaics (OPVs) are discussed. The surface electrical properties and charge selectivity of these thin films are strongly dependent upon the surface chemistry, band edge energies, and midgap state concentrations, as dictated by the ambient conditions and film pretreatments. Surface states were correlated with standards for nickel oxide, hydroxide, and oxyhydroxide components, as determined using monochromatic X-ray photoelectron spectroscopy. Ultraviolet and inverse photoemission spectroscopy measurements show changes in the surface chemistries directly impact the valence band energies. O?-plasma treatment of the as-deposited NiO{sub x} films was found to introduce the dipolar surface species nickel oxyhydroxide (NiOOH), rather than the p-dopant Ni?O?, resulting in an increase of the electrical band gap energy for the near-surface region from 3.1 to 3.6 eV via a vacuum level shift. Electron blocking properties of the as-deposited and O?-plasma treated NiO{sub x} films are compared using both electron-only and BHJ devices. O?-plasma-treated NiO{sub x} interlayers produce electron-only devices with lower leakage current and increased turn on voltages. The differences in behavior of the different pretreated interlayers appears to arise from differences in local density of states that comprise the valence band of the NiO{sub x} interlayers and changes to the band gap energy, which influence their hole-selectivity. The presence of NiOOH states in these NiO{sub x} films and the resultant chemical reactions at the oxide/organic interfaces in OPVs is predicted to play a significant role in controlling OPV device efficiency and lifetime.

  18. Vehicle Technologies Office Merit Review 2014: Advanced Lean-Burn DI Spark Ignition Fuels Research

    Broader source: Energy.gov [DOE]

    Presentation given by Sandia National Laboratories at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced lean...

  19. Doubly Heavy Baryons, Heavy Quark-DiQuark Symmetry and NRQCD...

    Office of Scientific and Technical Information (OSTI)

    Date: 2005-09-27 OSTI Identifier: 850526 Report Number(s): JLAB-THY-05-415; DOEER40150-3612; hep-ph0509313 DOE Contract Number: AC05-84ER40150 Resource Type: Journal...

  20. Microsoft Word - SWPF-15-DI-001_R1_Construction Turnover to C&T Oversight

    Office of Environmental Management (EM)

    April 6, 2015 1 SAFETY SYSTEM OVERSIGHT ANNUAL AWARD PROGRAM OBJECTIVE The Safety System Oversight (SSO) Annual Award is a special award designed to recognize superior or exemplary service by an employee who has performed SSO functions. This special award program has been established in accordance with the requirements of Department of Energy (DOE) Order 331.1C, Employee Performance Management and Recognition Program. SAFETY SYSTEM OVERSIGHT ANNUAL AWARD The SSO Annual Award recipient is

  1. Development of an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain

    Broader source: Energy.gov [DOE]

    Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

  2. Chromatographic extraction with di(2-ethylhexyl)orthophosphoric acid for production and purification of promethium-147

    DOE Patents [OSTI]

    Boll, Rose A [Knoxville, TN

    2008-10-14

    A method of producing and purifying promethium-147 including the steps of: irradiating a target material including neodymium-146 with neutrons to produce promethium-147 within the irradiated target material; dissolving the irradiated target material to form an acidic solution; loading the acidic solution onto a chromatographic separation apparatus containing HDEHP; and eluting the apparatus to chromatographically separate the promethium-147 from the neodymium-146.

  3. DEPARTMENT OF FNERGY EERE PROJECT MANAGEMENT CENTER NFPA DI!TERJ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEPARTMENT OF FNERGY EERE PROJECT MANAGEMENT CENTER NFPA DITERJ.fiNATION ... publication. and distribution; and classroom training and informational programs), ...

  4. Non-Sooting, Low Flame Temperature Mixing-Controlled DI Diesel...

    Broader source: Energy.gov (indexed) [DOE]

    Effects of Ambient Density and Temperature on Soot Formation under High-EGR Conditions Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines Optical-Engine ...

  5. A Mixed Mode HCCI/DI Engine Based on a Novel Heavy Fuel Atomizer...

    Broader source: Energy.gov (indexed) [DOE]

    Mixture Formation: Preliminary Results Diesel HCCI with External Mixture Preparation A Micro-Variable Circular Orifice (MVCO) Fuel Injector for Zoned Low Temperature Combustion

  6. A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application

    SciTech Connect (OSTI)

    Fang, Howard L.; Huang, Shyan C.; Yu, Robert C.; Wan, C. Z.; Howden, Ken

    2002-10-01

    Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed. Development of the NOx adsorber technology is discussed. Spectroscopic techniques are applied to understand the underlying chemical reactions over the catalyst surface during NOx trapping and regeneration periods. In-situ surface probes are useful in providing not only thermodynamic and kinetics information required for model development but also a fundamental understanding of storage capacity and degradation mechanisms. The distribution of various nitration/sulfation species is related to surface basicity. Surface displacement reactions of carbonates also play roles in affecting the trapping capability of NOx adsorbers. When ultralow-S fuel is used as a reductant during the regeneration, sulfur induced performance degradation is still observed in an aged catalyst. Other possible sources related to catalyst deactivation include incomplete reduction of surface nitration, coke formation derived from incomplete hydrocarbon burning, and lubricant formulations. Sulfur management and the direction of future work for the successful implementation of such integrated engine and aftertreatment technology are discussed. SAE Paper SAE-2002-01-2889 {copyright} 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.

  7. Helicity amplitudes of di-photons production at the LHC with scalar unparticles intermediate states

    SciTech Connect (OSTI)

    Aliane, I.; Mebarki, N.; Haouchine, M.

    2012-06-27

    The helecity amplitudes of the subprocess gg{yields}{gamma}{gamma} via scalar unparticles intermediate states are calculated. The differential cross section is compared to that of the standard model. Phenomenological implications are also discussed.

  8. Cylinder-averaged histories of nitrogen oxide in a D.I. diesel with simulated turbocharging

    SciTech Connect (OSTI)

    Donahue, R.J.; Borman, G.L.; Bower, G.R.

    1994-10-20

    An experimental study was conducted using the dumping technique (total cylinder sampling) to produce cylinder mass-averaged nitric oxide histories. Data were taken using a four stroke diesel research engine employing a quiescent chamber, high pressure direct ijection fuel system, and simulated turbocharging. Two fuels were used to determine fuel cetane number effects. Two loads were run, one at an equivalence ratio of 0.5 and the other at a ratio of 0.3. The engine speed was held constant at 1500 rpm. Under the turbocharged and retarded timing conditions of this study, nitric oxide was produced up to the point of about 85% mass burned. Two different models were used to simulate the engine mn conditions: the phenomenological Hiroyasu spray-combustion model, and the three dimensional, U.W.-ERO modified KIVA-lI computational fluid dynamic code. Both of the models predicted the correct nitric oxide trend. Although the modified KIVA-lI combustion model using Zeldovich kinetics correctly predicted the shapes of the nitric oxide histories, it did not predict the exhaust concentrations without arbitrary adjustment based on experimental values.

  9. Exhaust particle characterization for lean and stoichiometric DI vehicles operating on ethanol-gasoline blends

    SciTech Connect (OSTI)

    Storey, John Morse; Barone, Teresa L; Thomas, John F; Huff, Shean P

    2012-01-01

    Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.

  10. Effect of pilot injection on combustion in a turbocharged D.I. diesel engine

    SciTech Connect (OSTI)

    Ishida, Masahiro; Chen, Z.L.; Luo, G.F.; Ueki, Hironobu

    1994-09-01

    For reducing the exhaust emissions and improving the ignition characteristics, the effect of pilot injection was investigated experimentally in a turbocharged direct injection diesel engine. The pilot injection quantity was varied by changing the seat diameter of the Doge plunger installed in the newly developed pilot injector while the separation period between the beginning of pilot injection and that of main injection was fixed at a short interval in the present experiment. The pilot injection effect on combustion was compared with the case of normal injection in two fuel oils with the cetane indexes of 53 and 40-respectively. The pilot injection showed some significant effects on improving the ignition characteristics and fuel consumption as follows: (1) The pilot ignition delay and the main ignition delay were about half of the ignition delay of the normal injection respectively. (2) The lower fuel consumption and NOx could be attained by the pilot injection at the retarded injection timing, especially under the lower load condition. (3) The trade-off relationship between the specific fuel consumption and NOx was significantly improved by the pilot injection. (4) In the present short pilot-main interval, a small amount of pilot quantity was recommended to reduce NOx and fuel consumption without deteriorating smoke density. 12 refs., 16 figs., 1 tab.

  11. Table A26. Components of Total Electricity Demand by Census Region, Census Di

    U.S. Energy Information Administration (EIA) Indexed Site

    Components of Total Electricity Demand by Census Region, Census Division, and" " Economic Characteristics of the Establishment, 1994" " (Estimates in Million Kilowatthours)" " "," "," "," ","Sales/"," ","RSE" " "," ","Transfers","Onsite","Transfers"," ","Row" "Economic

  12. MHK Projects/Colorado River Indian Tribes IRR DI | Open Energy...

    Open Energy Info (EERE)

    Organization Marine Power Water Inc Project Licensing FERC License Docket Number P-13350 Environmental Monitoring and Mitigation Efforts See Tethys << Return to the MHK database...

  13. A Conceptual Model of DI Diesel Combustion Based on Laser-Sheet...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Table 2 summarizes the specifications of the fuel injector. The injector is instru- mented with a Hall-effect needle lift sensor, and injection pressure is determined from strain ...

  14. Doubly Heavy Baryons, Heavy Quark-DiQuark Symmetry and NRQCD...

    Office of Scientific and Technical Information (OSTI)

    This method is used to rederive Lagrangians for the Qbar Q and QQ sectors of pNRQCD and give a correct derivation of the O(1mQ) prediction for the hyperfine splitting of doubly ...

  15. Idling Emissions Reduction Technology with Low Temperature Combustion of DI Biodiesel and PFI n-Butanol

    Broader source: Energy.gov [DOE]

    Results from an idling strategy using PCCI coupled with LTC indicate that, when used with n-butanol, it can be very promising for extended idling including the LTC regimes.

  16. The Role of The fedeRal PRojecT diRecToR

    Office of Environmental Management (EM)

    Subcommittee on Energy and Power Committee on Energy and Commerce U.S. House of Representatives February 11, 2015 Chairman Upton, Ranking Member Pallone, Chairman Whitfield, Ranking Member Rush, and Members of the Subcommittee, thank you for the opportunity to appear before you today to discuss the Department of Energy's (DOE) Budget Request for fiscal year (FY) 2016. I appreciate the opportunity to discuss how the Budget Request advances the Department of Energy's missions. Advancing Nuclear

  17. Vehicle Technologies Office Merit Review 2015: Advanced Lean-Burn DI Spark Ignition Fuels Research

    Broader source: Energy.gov [DOE]

    Presentation given by Sandia National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and vehicle technologies office annual merit review and peer evaluation meeting about advanced lean-burn...

  18. Resonance-continuum interference in the di-photon Higgs signal at the LHC

    SciTech Connect (OSTI)

    Dixon, Lance

    2003-02-25

    A low mass Standard Model Higgs boson should be visible at the Large Hadron Collider through its production via gluon-gluon fusion and its decay to two photons. We compute the interference of this resonant process, gg {yields} H {yields} {gamma}{gamma}, with the continuum QCD background, gg {yields} {gamma}{gamma} induced by quark loops. Helicity selection rules suppress the effect, which is dominantly due to the imaginary part of the two-loop gg {yields} {gamma}{gamma} scattering amplitude. The interference is destructive, but only of order 5% in the Standard Model, which is still below the 10-20% present accuracy of the total cross section prediction. We comment on the potential size of such effects in other Higgs models.

  19. DI-MGMT-81861 DOE Changes Version-- Integrated Program Management Report

    Office of Energy Efficiency and Renewable Energy (EERE)

    Integrated Program Management Report (IPMR) combines the Contractor Performance Report (CPR) and Integrated Master Schedule (IMS) reporting requirements on contracts requiring Earned Value Management (EVM) reporting of project/contract performance.

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    AlOx Fe, oxidation at the Fe4N AlOx interface creates Fe3O4, leading to negativemore ... heterostructures with well-controlled crystallography and interface structures. ...

  1. Design and Analysis of Salmonid Tagging Studies in the Columbia Basin, Volume XVI; Alternative Designs for Future Adult PIT-Tag Detection Studies, 2000 Technical Report.

    SciTech Connect (OSTI)

    Perez-Comas, Jose A.; Skalski, John R.

    2000-09-25

    In the advent of the installation of a PIT-tag interrogation system in the Cascades Island fish ladder at Bonneville Dam (BON), and other CRB dams, this overview describes in general terms what can and cannot be estimated under seven different scenarios of adult PIT-tag detection capabilities in the CRB. Moreover, this overview attempted to identify minimal adult PIT-tag detection configurations required by the ten threatened Columbia River Basin (CRB) chinook and steelhead ESUs. A minimal adult PIT-tag detection configuration will require the installation of adult PIT-tag detection facilities at Bonneville Dam and another dam above BON. Thus, the Snake River spring/summer and fall chinook salmon, and the Snake River steelhead will require a minimum of three dams with adult PIT-tag detection capabilities to guarantee estimates of ''ocean survival'' and at least of one independent, in-river returning adult survival (e.g., adult PIT-tag detection facilities at BON and LGR dams and at any other intermediary dam such as IHR). The Upper Columbia River spring chinook salmon and steelhead will also require a minimum of three dams with adult PIT-tag detection capabilities: BON and two other dams on the BON-WEL reach. The current CRB dam system configuration and BPA's and COE's commitment to install adult PIT-tag detectors only in major CRB projects will not allow the estimation of an ''ocean survival'' and of any in-river adult survival for the Lower Columbia River chinook salmon and steelhead. The Middle Columbia River steelhead ESU will require a minimum of two dams with adult PIT-tag detection capabilities: BON and another upstream dam on the BON-McN reach. Finally, in spite of their importance in terms of releases, PIT-tag survival studies for the Upper Willamette chinook and Upper Willamette steelhead ESUs cannot be perform with the current CRB dam system configuration and PIT-tag detection capabilities.

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... di Chimica, Biologia e Biotecnologie, Universit degli Studi di Perugia, 06123 Perugia (Italy) (1) Roncaratti, Luiz F. Dipartimento di Chimica, Biologia e Biotecnologie, ...

  3. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Francesco, E-mail: francesco.tarantelli@unipg.it ; Dipartimento di Chimica, Biologia e Biotecnologie, Universit degli Studi di Perugia, via Elce di Sotto 8, I-06123 ...

  4. Catching the role of anisotropic electronic distribution and...

    Office of Scientific and Technical Information (OSTI)

    ... del CNR, Perugia 06123 5 + Show Author Affiliations Dipartimento di Chimica, Biologia e Biotecnologie, Universit di Perugia, Perugia 06123 (Italy) Istituto di Scienze e ...

  5. Microsoft Word - Mazzocco_abs_11

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marco Mazzocco Dipartimento di Fisica and INFN - Sezione di Padova, Padova, Italy The ... (RIB's) is now fully operational at the Laboratori Nazionali di Legnaro (LNL, Italy). ...

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ; INFN Sezione di Ferrara, via Saragat 1, 44100 Ferrara, Italy, ; and Dipartimento di Fisica, Universita di Ferrara, via Saragat 1, 44100 Ferrara A new mechanism of adjustment of...

  7. Stress effects on the elastic properties of amorphous polymeric...

    Office of Scientific and Technical Information (OSTI)

    Istituto Officina dei Materiali del CNR (CNR-IOM) - Unit di Perugia, co Dipartimento di Fisica e Geologia, Perugia I-06100 (Italy) Dipartimento di Fisica e Geologia, Universit ...

  8. Evidence of Luttinger-liquid behavior in one-dimensional dipolar...

    Office of Scientific and Technical Information (OSTI)

    Dipartimento di Fisica E. R. Caianiello and CNISM, Universita degli Studi di Salerno, ... DEMOCRITOS INFM-CNR and Dipartimento di Fisica Teorica, Universita Trieste, Trieste ...

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Paciaroni, A., E-mail: alessandro.paciaroni@fisica.unipg.it (1) Petrillo, C. (1) ... Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ...

  10. Hydration-dependent dynamics of human telomeric oligonucleotides...

    Office of Scientific and Technical Information (OSTI)

    Unit di Perugia, co Dipartimento di Fisica e Geologia, Universit di Perugia, 06123 ... A., E-mail: alessandro.paciaroni@fisica.unipg.it 1 ; De Francesco, A. 3 ; ...

  11. Browse by Discipline -- E-print Network Subject Pathways: Biotechnolog...

    Office of Scientific and Technical Information (OSTI)

    ... Romu (Romu Romero) - Departament de Fsica, Universitat de les Illes Balears Romps, ... Universit di - Dipartimento di Fisica, Laboratorio di Fisica Terrestre Royal ...

  12. Angle-resolved spin wave band diagrams of square antidot lattices...

    Office of Scientific and Technical Information (OSTI)

    (IOM-CNR), Sede di Perugia, co Dipartimento di Fisica e Geologia, Via A. Pascoli, I-06123 Perugia (Italy) Dipartimento di Fisica e Scienze della Terra, Universit di Ferrara, ...

  13. Lanthanide(III) di- and tetra-nuclear complexes supported by a chelating tripodal tris(amidate) ligand

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brown, Jessie L.; Jones, Matthew B.; Gaunt, Andrew J.; Scott, Brian L.; MacBeth, Cora E.; Gordon, John C.

    2015-04-06

    Syntheses, structural, and spectroscopic characterization of multinuclear tris(amidate) lanthanide complexes is described. Addition of K3[N(o-PhNC(O)tBu)3] to LnX3 (LnX3 = LaBr3, CeI3, and NdCl3) in N,N-dimethylformamide (DMF) results in the generation of dinuclear complexes, [Ln(N(o-PhNC(O)tBu)3)(DMF)]2(μ-DMF) (Ln = La (1), Ce (2), Nd(3)), in good yields. Syntheses of tetranuclear complexes, [Ln(N(o-PhNC(O)tBu)3)]4 (Ln = Ce (4), Nd(5)), resulted from protonolysis of Ln[N(SiMe3)2]3 (Ln = Ce, Nd) with N(o-PhNCH(O)tBu)3. As a result, in the solid-state, complexes 1–5 exhibit coordination modes of the tripodal tris(amidate) ligand that are unique to the 4f elements and have not been previously observed in transition metal systems.

  14. Microsoft Word - 2014_01_10 D&I At a Glance_v4_dda.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 4 Strategic Projects Table 4: Strategic Projects Strategic Project Description (25 words or less) Objectives FY funded 1. Workforce Pipeline Engage and develop current employees and ...

  15. STUDY OF THE RECURRING DIMMING REGION DETECTED AT AR 11305 USING THE CORONAL DIMMING TRACKER (CoDiT)

    SciTech Connect (OSTI)

    Krista, Larisza D.; Reinard, Alysha

    2013-01-10

    We present a new approach to coronal dimming detection using the COronal DImming Tracker tool (CODIT), which was found to be successful in locating and tracking multiple dimming regions. This tool, an extension of a previously developed coronal hole tracking software, allows us to study the properties and the spatial evolution of dimming regions at high temporal and spatial cadence from the time of their appearance to their disappearance. We use Solar Dynamics Observatory/Atmospheric Imaging Assembly 193 A wavelength observations and Helioseismic and Magnetic Imager magnetograms to study dimmings. As a demonstration of the detection technique we analyzed six recurrences of a dimming observed near AR 11305 between 2011 September 29 and October 2. The dimming repeatedly appeared and formed in a similar way, first expanding then shrinking and occasionally stabilizing in the same location until the next eruption. The dimming areas were studied in conjunction with the corresponding flare magnitudes and coronal mass ejection (CME) masses. These properties were found to follow a similar trend during the observation period, which is consistent with the idea that the magnitude of the eruption and the CME mass affect the relative sizes of the consecutive dimmings. We also present a hypothesis to explain the evolution of the recurrent single dimming through interchange reconnection. This process would accommodate the relocation of quasi-open magnetic field lines and hence allow the CME flux rope footpoint (the dimming) to expand into quiet-Sun regions. By relating the properties of dimmings, flares, and CMEs we improve our understanding of the magnetic field reconfiguration caused by reconnection.

  16. A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine

    Broader source: Energy.gov [DOE]

    A single-cylinder engine was used to study how selected oxygenated fuels affect combustion and emissions in a modern diesel engine during conventional combustion and low-temperature combustion (LTC).

  17. DE-EM-0001971 WIPP M&O D-i PART I - THE SCHEDULE SECTION D

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Identifies the contract number under which the item is being delivered; and * Identifies the contract requirement or other instruction which requires the delivered item(s)....

  18. Fluorescence-based optimization of human bitter taste receptor...

    Office of Scientific and Technical Information (OSTI)

    Membrane Protein Crystallography Group, Imperial College London, London SW7 2AZ 5 ; Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Chilton, Oxfordshire OX11 ...

  19. Agrivert | Open Energy Information

    Open Energy Info (EERE)

    Agrivert Jump to: navigation, search Name: Agrivert Place: Chipping Norton, England, United Kingdom Zip: OX7 4EB Product: String representation "Agrivert is a m ... aste...

  20. Future Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: Future Energy Solutions Place: Didcot, United Kingdom Zip: OX11 0QR Product: Future Energy Solutions is a sustainable energy...

  1. 2degrees | Open Energy Information

    Open Energy Info (EERE)

    Kingdom Zip: OX2 7HT Product: Oxford-based collaborative network provider for sustainability professionals. Coordinates: 43.781517, -89.571699 Show Map Loading map......

  2. A two-parameter model for the infrared/submillimeter/radio spectral...

    Office of Scientific and Technical Information (OSTI)

    Pasadena, CA 91125 (United States) Department of Physics, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom) Spitzer Science Center, California Institute of ...

  3. Project No 974 | Open Energy Information

    Open Energy Info (EERE)

    Project No 974 Place: Oxford, United Kingdom Zip: OX2 7SG Product: Biological fuel cell technology employing enzymatic catalysts. Project is at present without company name....

  4. ANL2014-JMA.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Department of Physics and Astronomy, Rutgers University, New Brunswick, NJ 08903 8 Oxford Physics, University of Oxford, Oxford OX1 3PU, United Kingdom *Research sponsored by...

  5. Radiocarbon (Geochronology)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Belfast: Marine Reservoir Database Calib Calibomb CLAMBACON IntCal Database Oxford University Radiocarbon Unit: OxCal PaleoclimateEnvironmental Databases: Neotoma NOAA...

  6. Cornwall Light Power CLP | Open Energy Information

    Open Energy Info (EERE)

    Cornwall Light Power CLP Jump to: navigation, search Name: Cornwall Light & Power (CLP) Place: Didcot, England, United Kingdom Zip: OX11 9DD Sector: Wind energy Product:...

  7. Sorption Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    Oxford, England, United Kingdom Zip: OX1 2AY Product: Oxford-based firm developing adsorption air-conditioning and heating systems for domestic-scale products. Coordinates:...

  8. Oxford Catalysts Group plc | Open Energy Information

    Open Energy Info (EERE)

    Oxford Catalysts Group plc Place: Oxford, United Kingdom Zip: OX2 6UD Sector: Hydro, Hydrogen Product: Developer of catalysts for room-temperature hydrogen production, hot steam...

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... been a promising carbon capture technology in terms of fuel combustion for power generation. ... the attrition-resistance, the thermal stability in red-ox cycles and the ...

  10. Yields at Forward Rapidity A. Poulsen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p rocedure i s f ound t o r eject t he background c ontribuBons. M ost o f t he d i---jets t hat r emain c an b e m atched t o i niBal h ard s caIered p artons w ith m omentum f...

  11. I

    Office of Legacy Management (LM)

    of thQ rmt9x.i of holdlk3q Lb de and RfJna Thoroforca, it fs bul:med thsx'bit ii :wy 5s ussfux to aontsr3,ao Bon* Of thO8@ OXf3-iXlt8 at *&' lVOCit?F)r A aa ple of ths...

  12. Route-Specific Passage and Survival of Steelhead Kelts at The Dalles and Bonneville Dams, 2012 - Final Report

    SciTech Connect (OSTI)

    Rayamajhi, Bishes; Ploskey, Gene R.; Woodley, Christa M.; Weiland, Mark A.; Faber, Derek M.; Kim, Jin A.; Colotelo, Alison HA; Deng, Zhiqun; Fu, Tao

    2013-07-31

    This study was mainly focused on evaluating the route-specific passage and migration success of steelhead kelts passing downstream through The Dalles Dam (TDA) and Bonneville Dam (BON) at Columbia River (CR) river kilometers 309 and 234 respectively. Oregon Department of Fish and Wildlife (ODFW) personnel collected, tagged and released out-migrating steelhead kelts in the tributaries of the Deschutes River, 15 Mile Creek and Hood River between April 14 and June 4, 2012. A PIT tag was injected into each kelt’s dorsal sinus whereas a Juvenile Salmon Acoustic Telemetry System (JSATS) acoustic micro-transmitter was attached to an external FLoy T-bar tag and inserted into the dorsal back musculature using a Floy tagging gun. JSATS cabled arrays were deployed at TDA and BON and autonomous node arrays were deployed near Celilo, Oregon (CR325); the BON forebay (CR236); the BON tailrace (CR233); near Knapp, Washington (CR156); and near Kalama, Washington (CR113) to monitor the kelts movement while passing through the dams and above mentioned river cross-sections.

  13. Taurine protects HK-2 cells from oxidized LDL-induced cytotoxicity via the ROS-mediated mitochondrial and p53-related apoptotic pathways

    SciTech Connect (OSTI)

    Chang, Chun-Yu; Shen, Chao-Yu; Kang, Chao-Kai; Sher, Yuh-Pyng; Sheu, Wayne H.-H.; Chang, Chia-Che; Lee, Tsung-Han

    2014-09-15

    Oxidized LDL (oxLDL) induces a pro-oxidative environment and promotes apoptosis, causing the progression of renal diseases in humans. Taurine is a semi-essential amino acid in mammals and has been shown to be a potent endogenous antioxidant. The kidney plays a pivotal role in maintaining the balance of taurine. However, the mechanisms underlying the protective effects of taurine against oxLDL-induced injury in renal epithelial cells have not been clarified. In the present study, we investigated the anti-apoptotic effects of taurine on human proximal tubular epithelial (HK-2) cells exposed to oxLDL and explored the related mechanisms. We observed that oxLDL increased the contents of ROS and of malondialdehyde (MDA), which is a lipid peroxidation by-product that acts as an indicator of the cellular oxidation status. In addition, oxLDL induced cell death and apoptosis in HK-2 cells. Pretreatment with taurine at 100 μM significantly attenuated the oxLDL-induced cytotoxicity. We determined that oxLDL triggered the phosphorylation of ERK and, in turn, the activation of p53 and other apoptosis-related events, including calcium accumulation, destabilization of the mitochondrial permeability and disruption of the balance between pro-apoptotic Bax and anti-apoptotic Bcl-2 proteins. The malfunctions induced by oxLDL were effectively blocked by taurine. Thus, our results suggested that taurine exhibits potential therapeutic activity by preventing oxLDL-induced nephrotoxicity. The inhibition of oxLDL-induced epithelial apoptosis by taurine was at least partially due to its anti-oxidant activity and its ability to modulate the ERK and p53 apoptotic pathways. - Highlights: • Oxidized LDL induced cytotoxicity and apoptosis in HK-2 cells. • Pretreatment with taurine attenuated oxLDL-induced nephrotoxicity. • Taurine protected against renal damages through inhibition of ROS generation. • Taurine prevented apoptosis through modulation of the p53 phosphorylation.

  14. Effects of support on bifunctional methanol oxidation pathways catalyzed by polyoxometallate keggin clusters

    SciTech Connect (OSTI)

    Liu, Haichao; Iglesia, Enrique

    2003-12-26

    H5PV2Mo10O40 polyoxometallate Keggin clusters supported on ZrO2, TiO2, SiO2, and Al2O3 are effective catalysts for CH3OH oxidation reactions to form HCHO, methyl formate (MF), and dimethoxymethane (DMM). Rates and selectivities and the structure of supported clusters depend on the surface properties of the oxide supports. Raman spectroscopy showed that Keggin structures remained essentially intact on ZrO2, TiO2, and SiO2 after treatment in air at 553 K, but decomposed to MoOx and VOx oligomers on Al2O3. Accessible protons per Keggin unit (KU) were measured during CH3OH oxidation by titration with 2,6-di-tert-butyl pyridine. For similar KU surface densities (0.28 0.37 KU/nm2), the number of accessible protons was larger on SiO2 than on ZrO2 and TiO2 and much smaller on Al2O3 supports, even though residual dimethyl ether (DME) synthesis rates after titrant saturation indicated that the fractional dispersion of KU was similar on the first three supports. These effects of support on structure and on H+ accessibility reflect varying extents of interaction between polyoxometallate clusters and supports. Rates of CH3OH oxidative dehydrogenation per KU were higher on ZrO2 and TiO2 than on SiO2 at similar KU surface densities (0.28 0.37 KU/nm2) and dispersion, indicating that redox properties of Keggin clusters depend on the identity of the support used to disperse them. ZrO2 and TiO2 supports appear to enhance the reducibility of anchored polyoxometallate clusters. Rates were much lower on Al2O3, because structural degradation led to less reactive MoOx and VOx domains. CH3OH reactions involve primary oxidation to form HCHO and subsequent secondary reactions to form DMM and MF. These reactions involve HCHO CH3OH acetalization steps leading to methoxymethanol (CH3OCH2OH) or hemiacetal intermediates, which condense with CH3OH on acid sites to form DMM or dehydrogenate to form MF. COx formation rates are much lower than those of other reactions, and DME forms in parallel

  15. How to stabilize highly active Cu+ cations in a mixed-oxide catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mudiyanselage, Kumudu; Luo, Si; Kim, Hyun You; Yang, Xiaofang; Baber, Ashleigh E.; Hoffmann, Friedrich M.; Senanayake, Sananayake; Rodriguez, Jose A.; Chen, Jingguang G.; Liu, Ping; et al

    2015-09-12

    Mixed-metal oxides exhibit novel properties that are not present in their isolated constituent metal oxides and play a significant role in heterogeneous catalysis. In this study, a titanium-copper mixed-oxide (TiCuOx) film has been synthesized on Cu(111) and characterized by complementary experimental and theoretical methods. At sub-monolayer coverages of titanium, a Cu2O-like phase coexists with TiCuOx and TiOx domains. When the mixed-oxide surface is exposed at elevated temperatures (600–650 K) to oxygen, the formation of a well-ordered TiCuOx film occurs. Stepwise oxidation of TiCuOx shows that the formation of the mixed-oxide is faster than that of pure Cu2O. As the Timore » coverage increases, Ti-rich islands (TiOx) form. The adsorption of CO has been used to probe the exposed surface sites on the TiOx–CuOx system, indicating the existence of a new Cu+ adsorption site that is not present on Cu2O/Cu(111). Adsorption of CO on Cu+ sites of TiCuOx is thermally more stable than on Cu(111), Cu2O/Cu(111) or TiO2(110). The Cu+ sites in TiCuOx domains are stable under both reducing and oxidizing conditions whereas the Cu2O domains present on sub-monolayer loads of Ti can be reduced or oxidized under mild conditions. Furthermore, the results presented here demonstrate novel properties of TiCuOx films, which are not present on Cu(111), Cu2O/Cu(111), or TiO2(110), and highlight the importance of the preparation and characterization of well-defined mixed-metal oxides in order to understand fundamental processes that could guide the design of new materials.« less

  16. HCCI and Stratified-Charge CI Engine Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... CNL, DI-60 CNL, PFS CNL, PM RI, DI-60 RI, PFS RI, PM CA50 Sweeps at Constant Fueling P in 2.4 bar, PM, std. PFS, & Early -DI Adapted Matlab code for combustion noise level ...

  17. Yb-Zn-Al ternary system: CaCu{sub 5}-type derived compounds in...

    Office of Scientific and Technical Information (OSTI)

    Chimica Fisica, Universita di Genova, Via Dodecaneso 31, 16146 Genova (Italy). E-mail: cfmet@chimica.unige.it Dipartimento di Chimica e Chim. Ind., Sezione di Chimica Fisica, ...

  18. Compact

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Compact soft x-ray multichord camera: Design and initial operation P. Franz Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Italy and Istituto Nazionale di Fisica della Materia, Unita ` di Ricerca di Padova, Italy G. Gadani Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Italy R. Pasqualotto Consorzio RFX-Associazione EURATOM ENEA sulla fusione, Italy and Istituto Nazionale di Fisica della Materia, Unita ` di Ricerca di Padova, Italy L. Marrelli Consorzio RFX-Associazione EURATOM

  19. The Hubble space telescope UV legacy survey of galactic globular...

    Office of Scientific and Technical Information (OSTI)

    a.cunial@studenti.unipd.it 1 ; and others + Show Author Affiliations Dipartimento di Fisica e Astronomia "Galileo Galilei," Universit di Padova, Vicolo dell'Osservatorio 3,...

  20. Chirality of weakly bound complexes: The potential energy surfaces...

    Office of Scientific and Technical Information (OSTI)

    Instituto de Fsica, Universidade de Braslia, 70910 Braslia (Brazil) Dipartimento di Chimica, Biologia e Biotecnologie, Universit di Perugia, 06123 Perugia (Italy) (Brazil) ...

  1. Role of the antiferromagnetic pinning layer on spin wave properties...

    Office of Scientific and Technical Information (OSTI)

    Authors: Gubbiotti, G., E-mail: gubbiotti@fisica.unipg.it ; Tacchi, S. 1 ; Del Bianco, ... 4 ; Tamisari, M. 4 ; Dipartimento di Fisica e Geologia, Universit di Perugia, ...

  2. Ion implantation for manufacturing bent and periodically bent...

    Office of Scientific and Technical Information (OSTI)

    Galilei, University of Padova, Via Marzolo 8, 35131 Padova (Italy) Dipertimento di Economia e Tecnologia, Universit degli Studi della Repubblica di San Marino, Salita alla ...

  3. High-resolution Soft-RIXS: Scientific Goals and Technical Challenges...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SSRL Conference Room 137-322 Giacomo Ghiringhelli, CNRSPIN and Dipartimento di Fisica, Politecnico di Milano, Italy Visiting scholar at SIMES-Department of physics, Stanford ...

  4. Center for Nanophase Materials Sciences (CNMS) - CNMS User Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    di Fisica "A. Volta", Universita degli Studi di Pavia, via Bassi 6, 27100 Pavia, Italy Department of Physics and Institute for Optical Sciences, University of Toronto, 60 St. ...

  5. Center for Nanophase Materials Sciences (CNMS) - CNMS Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    di Fisica "A. Volta", Universita degli Studi di Pavia, via Bassi 6, 27100 Pavia, Italy Department of Physics and Institute for Optical Sciences, University of Toronto, 60 St. ...

  6. Micro-focused Brillouin light scattering study of the magnetization...

    Office of Scientific and Technical Information (OSTI)

    Authors: Madami, M., E-mail: marco.madami@fisica.unipg.it ; Carlotti, G. 1 ; Gubbiotti, ... Show Author Affiliations Dipartimento di Fisica e Geologia, Universit di Perugia, ...

  7. Disorder effects in the {ital t}-{ital J} model (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Authors: Caprara, S. 1 ; Dipartimento di Fisica, Universita Tor Vergata, Via della ... Dipartimento di Fisica, Universita La Sapienza, Piazzale Aldo Moro, 00185 Roma (Italy) ...

  8. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Zabaras, Nicholas J. (Nicholas J. Zabaras) - School of Engineering, University of Warwick Zaccarelli, Emanuela (Emanuela Zaccarelli) - Dipartimento di Fisica, Universit di Roma ...

  9. Browse by Discipline -- E-print Network Subject Pathways: Energy...

    Office of Scientific and Technical Information (OSTI)

    ... Andrea (Andrea Marini) - Dipartimento di Fisica, Universit di Roma Tor Vergata ... Marko) - Departments of Biochemistry, Molecular Biology, and Cell Biology & Physics and ...

  10. Development of a process for the extraction of {sup 137}Cs from acidic HLLW based on crown-calix extractant use of di-alkylamide modifier

    SciTech Connect (OSTI)

    Alexova, J.; Sirova, M.; Rais, J.; Suzuki, S.; Hirata, M.; Kimura, T.; Tachimori, S.

    2008-07-01

    Within the framework of the ARTIST project of total fuel retreatment with ecological mixtures of solvents and extractants containing only C, H, O, and N atoms, a process segment of extraction of {sup 137}Cs from acidic stream was developed. The process with 25,27-Bis(1-octyloxy)calix[4]arene-crown- 6, DOC[4]C6, dissolved at its 0.01 M concentration in a mixture of 90 vol % 1-octanol and 10% dihexyl octanamide, DHOA was proposed as a viable variant due to its good multicycle performance, even with irradiated solvent, and due to the good chemical stability of the chosen combination of solvent mixture. (authors)