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Sample records for blue ruthenium dimer

  1. Blue Ruthenium Dimer Catalysis for Hydrogen Generation | Advanced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to APS Science Highlights rss feed Blue Ruthenium Dimer Catalysis for Hydrogen Generation APRIL 15, 2013 Bookmark and Share Key intermediates in the water oxidation catalytic...

  2. Sensitivity of the Properties of RutheniumBlue Dimer” to Method, Basis Set, and Continuum Model

    SciTech Connect (OSTI)

    Ozkanlar, Abdullah; Clark, Aurora E.

    2012-05-23

    The rutheniumblue dimer” [(bpy)2RuIIIOH2]2O4+ is best known as the first well-defined molecular catalyst for water oxidation. It has been subject to numerous computational studies primarily employing density functional theory. However, those studies have been limited in the functionals, basis sets, and continuum models employed. The controversy in the calculated electronic structure and the reaction energetics of this catalyst highlights the necessity of benchmark calculations that explore the role of density functionals, basis sets, and continuum models upon the essential features of blue-dimer reactivity. In this paper, we report Kohn-Sham complete basis set (KS-CBS) limit extrapolations of the electronic structure of “blue dimer” using GGA (BPW91 and BP86), hybrid-GGA (B3LYP), and meta-GGA (M06-L) density functionals. The dependence of solvation free energy corrections on the different cavity types (UFF, UA0, UAHF, UAKS, Bondi, and Pauling) within polarizable and conductor-like polarizable continuum model has also been investigated. The most common basis sets of double-zeta quality are shown to yield results close to the KS-CBS limit; however, large variations are observed in the reaction energetics as a function of density functional and continuum cavity model employed.

  3. Structure and Electronic Configurations of the Intermediates of Water Oxidation in Blue Ruthenium Dimer Catalysis

    SciTech Connect (OSTI)

    Moonshiram, Dooshaye; Jurss, Jonah W.; Concepcion, Javier J.; Zakharova, Taisiya; Alperovich, Igor; Meyer, Thomas J.; Pushkar, Yulia

    2013-04-08

    Catalytic O{sub 2} evolution with cis,cis-[(bpy){sub 2}(H{sub 2}O)Ru{sup III}ORu{sup III}(OH{sub 2})(bpy){sub 2}]{sup 4+} (bpy is 2,2-bipyridine), the so-called blue dimer, the first designed water oxidation catalyst, was monitored by UV-vis, EPR, and X-ray absorption spectroscopy (XAS) with ms time resolution. Two processes were identified, one of which occurs on a time scale of 100 ms to a few seconds and results in oxidation of the catalyst with the formation of an intermediate, here termed [3,4]'. A slower process occurring on the time scale of minutes results in the decay of this intermediate and O{sub 2} evolution. Spectroscopic data suggest that within the fast process there is a short-lived transient intermediate, which is a precursor of [3,4]'. When excess oxidant was used, a highly oxidized form of the blue dimer [4,5] was spectroscopically resolved within the time frame of the fast process. Its structure and electronic state were confirmed by EPR and XAS. As reported earlier, the [3,4]' intermediate likely results from reaction of [4,5] with water. While it is generated under strongly oxidizing conditions, it does not display oxidation of the Ru centers past [3,4] according to EPR and XAS. EXAFS analysis demonstrates a considerably modified ligand environment in [3,4]'. Raman measurements confirmed the presence of the O-O fragment by detecting a new vibration band in [3,4]' that undergoes a 46 cm{sup -1} shift to lower energy upon {sup 16}O/{sup 18}O exchange. Under the conditions of the experiment at pH 1, the [3,4]' intermediate is the catalytic steady state form of the blue dimer catalyst, suggesting that its oxidation is the rate-limiting step.

  4. Selective deposition of nanostructured ruthenium oxide using...

    Office of Scientific and Technical Information (OSTI)

    Selective deposition of nanostructured ruthenium oxide using Tobacco mosaic virus for micro-supercapacitors in solid Nafion electrolyte Citation Details In-Document Search Title:...

  5. Blue Note

    ScienceCinema (OSTI)

    Murray Gibson

    2010-01-08

    Argonne's Murray Gibson is a physicist whose life's work includes finding patterns among atoms. The love of distinguishing patterns also drives Gibson as a musician and Blues enthusiast."Blue" notes are very harmonic notes that are missing from the equal temperament scale.The techniques of piano blues and jazz represent the melding of African and Western music into something totally new and exciting.

  6. Blue Note

    SciTech Connect (OSTI)

    Murray Gibson

    2007-04-27

    Argonne's Murray Gibson is a physicist whose life's work includes finding patterns among atoms. The love of distinguishing patterns also drives Gibson as a musician and Blues enthusiast."Blue" notes are very harmonic notes that are missing from the equal temperament scale.The techniques of piano blues and jazz represent the melding of African and Western music into something totally new and exciting.

  7. Blue Bonnet 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    Anchialine blue holes found in the interior of the Bahama Islands have distinct fresh and salt water layers, with vertical mixing, and dysoxic to anoxic conditions below the halocline. Scientific cave diving exploration and microbiological...

  8. Blue Cross Blue Shield Major Medical Program

    E-Print Network [OSTI]

    Blue Cross Blue Shield Major Medical Program Carnegie-Mellon University Group 50387-02 Effective January 1, 2010 Printed August, 2010 Highmark Blue Cross Blue Shield is an Independent Licensee of the Blue Cross and Blue Shield Association. #12;#12;Language Assistance Services Available for Multiple

  9. Platinum-ruthenium-palladium fuel cell electrocatalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2006-02-07

    A catalyst suitable for use in a fuel cell, especially as an anode catalyst, that contains platinum at a concentration that is between about 20 and about 60 atomic percent, ruthenium at a concentration that is between about 20 and about 60 atomic percent, palladium at a concentration that is between about 5 and about 45 atomic percent, and having an atomic ratio of platinum to ruthenium that is between about 0.7 and about 1.2. Alternatively, the catalyst may contain platinum at a concentration that is between about 25 and about 50 atomic percent, ruthenium at a concentration that is between about 25 and about 55 atomic percent, palladium at a concentration that is between about 5 and about 45 atomic percent, and having a difference between the concentrations of ruthenium and platinum that is no greater than about 20 atomic percent.

  10. Blue Pork

    E-Print Network [OSTI]

    Hacker, Randi; Boyd, David

    2011-05-29

    Broadcast Transcript: The Chinese have a centuries-old love affair with pork. It constitutes 70% of the meat in their diet. Mao Zedong even called pork a "national treasure." However, that pork was the "the other white meat," not phosphorescent blue...

  11. The Blue Wall

    E-Print Network [OSTI]

    Milano, Michael

    2015-01-01

    The  Blue  Wall   A  Documentary  Film  by     Michael  talking   about,  The  Blue  Wall.   Your  Honor,  as  the  

  12. Bluefield Blue Jays Internships

    E-Print Network [OSTI]

    Minnesota, University of

    Bluefield Blue Jays Internships General Internship Start Date: Mid May 2014 JOB DESCRIPTION: The Bluefield Blue Jays, Appalachian League Affiliate of the Toronto Blue Jays is looking for an individual: #12;The Bluefield Blue Jays, Appalachian League Affiliate of the Toronto Blue Jays is looking

  13. Wide Blue Sky

    E-Print Network [OSTI]

    Collins, Caroline Imani

    2011-01-01

    dressed neatly in a dark blue dress, its high neck trimmedIt was covered in a light blue fabric embellished with softOF CALIFORNIA RIVERSIDE Wide Blue Sky A Thesis submitted in

  14. A method for activation analysis of ruthenium in sea water 

    E-Print Network [OSTI]

    Dixon, Bryan William

    1965-01-01

    of Ruthenium in the Gulf of Mexico . 8 Solubility of Ruthenium in Sea Water C H A P T E R I INTRODUCTION Ruthenium, the rarest of the platinum metals, was discovered in 1845 by Klaus. Sidgewick (1950) and Goldschmidt (1954) state an abundance of about 0... of allow ing for the detection of the contributing physical and chemical forms to the total present. It is thought that the method is applicable to marine biota and sediments as well as water samples. The concentrations of soluble ruthenium found...

  15. Anthem Blue Cross and Blue Shield 6740 North High St.

    E-Print Network [OSTI]

    Pittendrigh, Barry

    Anthem Blue Cross and Blue Shield 6740 North High St. Worthington, OH 43085 An independent licensee of the Blue Cross and Blue Shield Association...... Anthem Blue Cross and Blue Shield is the trade name of Community Insurance Company. ® Registered marks Blue Cross and Blue Shield Association. Date REPLY MUST

  16. Cationic Ruthenium Catalysts for Olefin Hydrovinylation 

    E-Print Network [OSTI]

    Sanchez, Richard P., Jr

    2010-01-14

    of the Hydrovinylation Reaction ................................. 1 1.2 Mechanism of the Hydrovinylation Reaction........................... 4 1.3 Nickel and Palladium Catalyzed Reactions.............................. 6 1.4 Ruthenium Catalyzed Reactions... to form followed by isomerization to give the observed product. Ph Ph Me Ph Me Me RhCl3?3H2O 1000 atm ethylene MeOH, 50 ?C (6) Few catalysts had been used in early studies, but typically nickel and palladium catalysts were used due to their higher...

  17. Fischer-Tropsch synthesis process employing a moderated ruthenium catalyst

    DOE Patents [OSTI]

    Abrevaya, H.

    1990-07-31

    A Fischer-Tropsch type process produces hydrocarbons from carbon monoxide and hydrogen using a novel catalyst comprising moderated ruthenium on an inorganic oxide support. The preferred moderator is silicon. Preferably the moderator is effectively positioned in relationship to ruthenium particles through simultaneous placement on the support using reverse micelle impregnation. 1 fig.

  18. The CRAC channel consists of a tetramer formed by Stim-induced dimerization of Orai dimers

    E-Print Network [OSTI]

    Parker, Ian

    LETTERS The CRAC channel consists of a tetramer formed by Stim-induced dimerization of Orai dimers terminus of Stim thus induces Orai dimers to dimerize, forming tetramers that constitute the Ca21-treated cells14 , whereas functional measurements of expressed tandem Orai multimers indicate a tetramer

  19. Height fluctuations in interacting dimers

    E-Print Network [OSTI]

    Alessandro Giuliani; Vieri Mastropietro; Fabio Lucio Toninelli

    2015-05-05

    We consider a non-integrable model for interacting dimers on the two-dimensional square lattice. Configurations are perfect matchings of $\\mathbb Z^2$, i.e. subsets of edges such that each vertex is covered exactly once ("close-packing" condition). Dimer configurations are in bijection with discrete height functions, defined on faces $\\boldsymbol{\\xi}$ of $\\mathbb Z^2$. The non-interacting model is "integrable" and solvable via Kasteleyn theory; it is known that all the moments of the height difference $h_{\\boldsymbol{\\xi}}-h_{\\boldsymbol{\\eta}}$ converge to those of the massless Gaussian Free Field (GFF), asymptotically as $|{\\boldsymbol{\\xi}}-{\\boldsymbol{\\eta}}|\\to \\infty$. We prove that the same holds for small non-zero interactions, as was conjectured in the theoretical physics literature. Remarkably, dimer-dimer correlation functions are instead not universal and decay with a critical exponent that depends on the interaction strength. Our proof is based on an exact representation of the model in terms of lattice interacting fermions, which are studied by constructive field theory methods. In the fermionic language, the height difference $h_{\\boldsymbol{\\xi}}-h_{\\boldsymbol{\\eta}}$ takes the form of a non-local operator, consisting of a sum of monomials along an {\\it arbitrary} path connecting $\\boldsymbol{\\xi}$ and $\\boldsymbol{\\eta}$. As in the non-interacting case, this path-independence plays a crucial role in the proof.

  20. Ruthenium / aerogel nanocomposits via Atomic Layer Deposition

    SciTech Connect (OSTI)

    Biener, J; Baumann, T F; Wang, Y; Nelson, E J; Kucheyev, S O; Hamza, A V; Kemell, M; Ritala, M; Leskela, M

    2006-08-28

    We present a general approach to prepare metal/aerogel nanocomposites via template directed atomic layer deposition (ALD). In particular, we used a Ru ALD process consisting of alternating exposures to bis(cyclopentadienyl)ruthenium (RuCp{sub 2}) and air at 350 C to deposit metallic Ru nanoparticles on the internal surfaces of carbon and silica aerogels. The process does not affect the morphology of the aerogel template and offers excellent control over metal loading by simply adjusting the number of ALD cycles. We also discuss the limitations of our ALD approach, and suggest ways to overcome these.

  1. The Pennsylvania State University Marching Blue Band Blue Band Office

    E-Print Network [OSTI]

    Maroncelli, Mark

    The Pennsylvania State University Marching Blue Band Press Kit Blue Band Office 101 Blue Band Director vcc2@psu.edu orb1@psu.edu gad157@psu.edu (814) 865 - 3982 #12;History of the Blue Band The Marching Blue Band numbers 310 members which includes: 260 instrumentalists, 34 silks, 14 Touch of Blue

  2. Fiber optic D dimer biosensor

    DOE Patents [OSTI]

    Glass, R.S.; Grant, S.A.

    1999-08-17

    A fiber optic sensor for D dimer (a fibrinolytic product) can be used in vivo (e.g., in catheter-based procedures) for the diagnosis and treatment of stroke-related conditions in humans. Stroke is the third leading cause of death in the United States. It has been estimated that strokes and stroke-related disorders cost Americans between $15-30 billion annually. Relatively recently, new medical procedures have been developed for the treatment of stroke. These endovascular procedures rely upon the use of microcatheters. These procedures could be facilitated with this sensor for D dimer integrated with a microcatheter for the diagnosis of clot type, and as an indicator of the effectiveness, or end-point of thrombolytic therapy. 4 figs.

  3. Blue Cross and Blue Shield of Florida is now Florida Blue State Employees' PPO Plan health insurance provider Blue Cross and Blue Shield of

    E-Print Network [OSTI]

    Ronquist, Fredrik

    Blue Cross and Blue Shield of Florida is now Florida Blue State Employees' PPO Plan health insurance provider Blue Cross and Blue Shield of Florida has recently changed its name to Florida Blue Resources Benefits Office at (850) 6444015, or insben@admin.fsu.edu. RELATED LINKS ­ Florida Blue

  4. Electronic transitions of palladium dimer

    SciTech Connect (OSTI)

    Qian, Yue; Ng, Y. W.; Chen, Zhihua; Cheung, A. S.-C., E-mail: hrsccsc@hku.hk [Department of Chemistry, The University of Hong Kong, Pokfulam Road (Hong Kong)

    2013-11-21

    The laser induced fluorescence spectrum of palladium dimer (Pd{sub 2}) in the visible region between 480 and 700 nm has been observed and analyzed. The gas-phase Pd{sub 2} molecule was produced by laser ablation of palladium metal rod. Eleven vibrational bands were observed and assigned to the [17.1] {sup 3}II{sub g} - X{sup 3}?{sub u}{sup +} transition system. The bond length (r{sub o}) and vibrational frequency (?G{sub 1/2}) of the ground X{sup 3}?{sub u}{sup +} state were determined to be 2.47(4) Å and 211.4(5) cm{sup ?1}, respectively. A molecular orbital energy level diagram was used to understand the observed ground and excited electronic states. This is the first gas-phase experimental investigation of the electronic transitions of Pd{sub 2}.

  5. The geometry of dimer models

    E-Print Network [OSTI]

    David Cimasoni

    2014-09-16

    This is an expanded version of a three-hour minicourse given at the winterschool Winterbraids IV held in Dijon in February 2014. The aim of these lectures was to present some aspects of the dimer model to a geometrically minded audience. We spoke neither of braids nor of knots, but tried to show how several geometrical tools that we know and love (e.g. (co)homology, spin structures, real algebraic curves) can be applied to very natural problems in combinatorics and statistical physics. These lecture notes do not contain any new results, but give a (relatively original) account of the works of Kasteleyn, Cimasoni-Reshetikhin and Kenyon-Okounkov-Sheffield.

  6. Thermodynamically Stable Blue Phases

    E-Print Network [OSTI]

    F. Castles; S. M. Morris; E. M. Terentjev; H. J. Coles

    2011-01-28

    We show theoretically that flexoelectricity stabilizes blue phases in chiral liquid crystals. Induced internal polarization reduces the elastic energy cost of splay and bend deformations surrounding singular lines in the director field. The energy of regions of double twist is unchanged. This in turn reduces the free energy of the blue phase with respect to that of the chiral nematic phase, leading to stability over a wider temperature range. The theory explains the discovery of large temperature range blue phases in highly flexoelectric "bimesogenic" and "bent-core" materials, and predicts how this range may be increased further.

  7. DENTAL INSURANCE ANTHEM BLUE CROSS AND BLUE SHIELD

    E-Print Network [OSTI]

    - 28 - DENTAL INSURANCE ANTHEM BLUE CROSS AND BLUE SHIELD Your two choices are: After enrollment and a variety of ways to manage your personal dental care and the dental care of your family. Anthem Blue Dental PPO Plus Anthem Blue Dental PPO NOTE: Children are eligible for coverage before, on or within 31 days

  8. Blue Coat Systems, Inc. Blue Coat Systems, Software Cryptographic Module

    E-Print Network [OSTI]

    Blue Coat Systems, Inc. Blue Coat Systems, Software Cryptographic Module SW Version: 1.0 FIPS 140: Blue Coat Systems, Inc. Corsec Security, Inc. 420 N. Mary Avenue Sunnyvale, CA 94085 United States://www.corsec.com #12;Security Policy, Version 1.9 April 24, 2014 Blue Coat Systems, Software Cryptographic Module Page

  9. Blue Cross Blue Shield of Massachusetts is an Independent Licensee of the Blue Cross and Blue Shield Association Expanded Coverage for Preventive Care Under

    E-Print Network [OSTI]

    Aalberts, Daniel P.

    Blue Cross Blue Shield of Massachusetts is an Independent Licensee of the Blue Cross and Blue. Effect the New Rules Will Have on Members and Accounts Blue Cross Blue Shield of Massachusetts. Blue Cross Blue Shield of Massachusetts will offer the following services with no member cost share

  10. Benzene Dimer DOI: 10.1002/anie.201300653

    E-Print Network [OSTI]

    Benzene Dimer DOI: 10.1002/anie.201300653 Structure of the Benzene Dimer--Governed by Dynamics van der Avoird* The benzene dimer is a prototypical system for studying noncovalent interactions in the structure and dynamic behavior of proteins and DNA. The first (1975) experimental study of the benzene dimer

  11. Choosing between Blue Cross plans...

    E-Print Network [OSTI]

    Burke, Peter

    Choosing between Blue Cross plans... ...when you have Medicare PresentedPresented By Glenn. Medicare and UC II. Medicare and Anthem Blue Cross III. Plan Comparisons · Pros/Cons · Medical coverage will automatically be enrolled in Part D by Blue Cross No additional Part D premium · Blue Cross members have

  12. Reversible Dimerization of (+)-Myrmicarin 215B

    E-Print Network [OSTI]

    Movassaghi, Mohammad

    Brønsted acid promoted reversible dimerization of myrmicarin 215B leads to formation of a new heptacyclic product, isomyrmicarin 430B, that possesses a C1,C2-trans,C2,C3-trans-substituted cyclopentane ring. Mechanistic ...

  13. Discovery of Yttrium, Zirconium, Niobium, Technetium, and Ruthenium Isotopes

    E-Print Network [OSTI]

    A. Nystrom; M. Thoennessen

    2011-02-11

    Currently, thirty-four yttrium, thirty-five zirconium, thirty-four niobium, thirty-five technetium, and thirty-eight ruthenium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  14. Discovery of Yttrium, Zirconium, Niobium, Technetium, and Ruthenium Isotopes

    E-Print Network [OSTI]

    Nystrom, A

    2011-01-01

    Currently, thirty-four yttrium, thirty-five zirconium, thirty-four niobium, thirty-five technetium, and thirty-eight ruthenium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  15. Sclerosing cellular blue nevus simulating melanoma

    E-Print Network [OSTI]

    Aydingoz, Ikbal Esen; Dikicioglu-Cetin, Emel

    2012-01-01

    F, Cainelli T. Agminate blue nevus combined with lentigo. Ais a very rare type of blue nevus and owing to the diversitymelanocytic neoplasms: sclerotic blue nevi. Arch Dermatol .

  16. Sclerosing cellular blue nevus simulating melanoma

    E-Print Network [OSTI]

    Aydingoz, Ikbal Esen; Dikicioglu-Cetin, Emel

    2012-01-01

    Sclerosing cellular blue nevus simulating melanoma Ikbal48-year-old female with sclerosing cellular blue nevus withwas unusual for a sclerosing cellular blue nevus. Besides

  17. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander (Sunnyvale, CA)

    2003-01-01

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  18. Platinum-ruthenium-nickel alloy for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander

    2004-04-20

    An improved noble metal alloy composition for a fuel cell catalyst, the alloy containing platinum, ruthenium, and nickel. The alloy shows methanol oxidation activity.

  19. The Blue Whale, Balaenoptera musculus

    E-Print Network [OSTI]

    The Blue Whale, Balaenoptera musculus SALLY A. MIZROCH, DALE W. RICE, and JEFFREY M. BREIWICK Introduction The blue whale, Balaenoptera mus- culus (Linnaeus, 1758), is not only the largest of the whales metric tons (t) (Mackintosh, 1942). Blue whales are entirely bluish-gray in color, except for the white

  20. Complex of transferrin with ruthenium for medical applications

    DOE Patents [OSTI]

    Richards, Powell (Bayport, NY); Srivastava, Suresh C. (Setauket, NY); Meinken, George E. (Middle Island, NY)

    1984-05-15

    A novel Ruthenium-transferrin complex, prepared by reacting iron-free human transferrin dissolved in a sodium acetate solution at pH 7 with ruthenium by heating at about 40.degree. C. for about 2 hours, and purifying said complex by means of gel chromotography with pH 7 sodium acetate as eluent. The mono- or di-metal complex produced can be used in nuclear medicine in the diagnosis and/or treatment of tumors and abscesses. Comparative results with Ga-67-citrate, which is the most widely used tumor-localizing agent in nuclear medicine, indicate increased sensitivity of detection and greater tumor uptake with the Ru-transferrin complex.

  1. Why Blue-Collar Blacks Help Less

    E-Print Network [OSTI]

    Smith, Sandra Susan; Young, Kara Alexis

    2013-01-01

    Exclude Black Men from Blue-Collar Jobs. Berkeley, CA:How Black and Latino Blue Collar Workers Make Decisionsof Sample Respondents Blue-Collar Latinos Blue-Collar Black

  2. Universal bosonic tetramers of dimer-atom-atom structure

    E-Print Network [OSTI]

    A. Deltuva

    2012-03-28

    Unstable four-boson states having an approximate dimer-atom-atom structure are studied using momentum-space integral equations for the four-particle transition operators. For a given Efimov trimer the universal properties of the lowest associated tetramer are determined. The impact of this tetramer on the atom-trimer and dimer-dimer collisions is analyzed. The reliability of the three-body dimer-atom-atom model is studied.

  3. Universal bosonic tetramers of dimer-atom-atom structure

    E-Print Network [OSTI]

    Deltuva, A

    2012-01-01

    Unstable four-boson states having an approximate dimer-atom-atom structure are studied using momentum-space integral equations for the four-particle transition operators. For a given Efimov trimer the universal properties of the lowest associated tetramer are determined. The impact of this tetramer on the atom-trimer and dimer-dimer collisions is analyzed. The reliability of the three-body dimer-atom-atom model is studied.

  4. Stabilising the Blue Phases

    E-Print Network [OSTI]

    G. P. Alexander; J. M. Yeomans

    2006-09-22

    We present an investigation of the phase diagram of cholesteric liquid crystals within the framework of Landau - de Gennes theory. The free energy is modified to incorporate all three Frank elastic constants and to allow for a temperature dependent pitch in the cholesteric phase. It is found that the region of stability of the cubic blue phases depends significantly on the value of the elastic constants, being reduced when the bend elastic constant is larger than splay and when twist is smaller than the other two. Most dramatically we find a large increase in the region of stability of blue phase I, and a qualitative change in the phase diagram, in a system where the cholesteric phase displays helix inversion.

  5. BlueFire Ethanol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Researchof Energy|Make6,Energy Blue Ribbon

  6. Best Linear Unbiased Estimate Motivation for BLUE

    E-Print Network [OSTI]

    Fowler, Mark

    1 Chapter 6 Best Linear Unbiased Estimate (BLUE) #12;2 Motivation for BLUE Except for Linear Model to a sub-optimal estimate BLUE is one such sub-optimal estimate Idea for BLUE: 1. Restrict estimate) Advantage of BLUE:Needs only 1st and 2nd moments of PDF Mean & Covariance Disadvantages of BLUE: 1. Sub

  7. On the asymptotics of dimers on tori

    E-Print Network [OSTI]

    Richard W. Kenyon; Nike Sun; David B. Wilson

    2015-11-09

    We study asymptotics of the dimer model on large toric graphs. Let $\\mathbb L$ be a weighted $\\mathbb{Z}^2$-periodic planar graph, and let $\\mathbb{Z}^2 E$ be a large-index sublattice of $\\mathbb{Z}^2$. For $\\mathbb L$ bipartite we show that the dimer partition function on the quotient $\\mathbb{L}/(\\mathbb{Z}^2 E)$ has the asymptotic expansion $\\exp[A f_0 + \\text{fsc} + o(1)]$, where $A$ is the area of $\\mathbb{L}/(\\mathbb{Z}^2 E)$, $f_0$ is the free energy density in the bulk, and $\\text{fsc}$ is a finite-size correction term depending only on the conformal shape of the domain together with some parity-type information. Assuming a conjectural condition on the zero locus of the dimer characteristic polynomial, we show that an analogous expansion holds for $\\mathbb{L}$ non-bipartite. The functional form of the finite-size correction differs between the two classes, but is universal within each class. Our calculations yield new information concerning the distribution of the number of loops winding around the torus in the associated double-dimer models.

  8. Flexoelectric blue phases

    E-Print Network [OSTI]

    G P Alexander; J M Yeomans

    2007-07-01

    We describe the occurence and properties of liquid crystal phases showing two dimensional splay and bend distortions which are stabilised by flexoelectric interactions. These phases are characterised by regions of locally double splayed order separated by topological defects and are thus highly analogous to the blue phases of cholesteric liquid crystals. We present a mean field analysis based upon the Landau--de Gennes Q-tensor theory and construct a phase diagram for flexoelectric structures using analytic and numerical results. We stress the similarities and discrepancies between the cholesteric and flexoelectric cases.

  9. Blue-Dam

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download

  10. Blue-Dam

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N N E V

  11. Blue-Dam

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N N E

  12. Blue-Dam

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N N E3

  13. Blue-Dam

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N N E33

  14. Blue-Dam

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N N

  15. Blue-LessInk

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N N6 th

  16. BlueChoice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N N6EPO

  17. BlueChoice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N

  18. BlueChoice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N5

  19. BlueChoice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N55

  20. Mechanism of water oxidation by [Ru(bda)(L)?]: The return of the "blue dimer"

    SciTech Connect (OSTI)

    Concepcion, Javier J. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhong, Diane K. [Brookhaven National Lab. (BNL), Upton, NY (United States); Szalda, David J. [Baruch College, New York, NY (United States); Muckerman, James T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fujita, Etsuko [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01

    We describe here a combined solution-surface-DFT calculations study for complexes of the type [Ru(bda)(L)?] including X-ray structure of intermediates, their reactivity, as well as pH-dependent electrochemistry and spectroelectrochemistry. These studies shed light on the mechanism of water oxidation by [Ru(bda)(L)?], revealing key features unavailable from solution studies with sacrificial oxidants.

  1. Mechanism of water oxidation by [Ru(bda)(L)?]: The return of the "blue dimer"

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Concepcion, Javier J.; Zhong, Diane K.; Szalda, David J.; Muckerman, James T.; Fujita, Etsuko

    2015-02-05

    We describe here a combined solution-surface-DFT calculations study for complexes of the type [Ru(bda)(L)?] including X-ray structure of intermediates, their reactivity, as well as pH-dependent electrochemistry and spectroelectrochemistry. These studies shed light on the mechanism of water oxidation by [Ru(bda)(L)?], revealing key features unavailable from solution studies with sacrificial oxidants.

  2. Fibrillar dimer formation of islet amyloid polypeptides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chiu, Chi -cheng; de Pablo, Juan J.

    2015-05-08

    Amyloid deposits of human islet amyloid polypeptide (hIAPP), a 37-residue hormone co-produced with insulin, have been implicated in the development of type 2 diabetes. Residues 20 – 29 of hIAPP have been proposed to constitute the amyloidogenic core for the aggregation process, yet the segment is mostly unstructured in the mature fibril, according to solid-state NMR data. Here we use molecular simulations combined with bias-exchange metadynamics to characterize the conformational free energies of hIAPP fibrillar dimer and its derivative, pramlintide. We show that residues 20 – 29 are involved in an intermediate that exhibits transient ?-sheets, consistent with recent experimentalmore »and simulation results. By comparing the aggregation of hIAPP and pramlintide, we illustrate the effects of proline residues on inhibition of the dimerization of IAPP. The mechanistic insights presented here could be useful for development of therapeutic inhibitors of hIAPP amyloid formation.« less

  3. Dimerization specificities of leucine zipper mutants 

    E-Print Network [OSTI]

    Rieker, Jennifer Dawn

    2013-02-22

    -1 DIMEItIZA TION SPECIFICITIES OF LEUCINE ZIPPER MUTAIV TS A Senior Thesis By Jennifer Dawn Rieker 1997-98 University Undergraduate Research Fellow Texas ARM University Group: Biochemistry/Chemistry DIMERIZATION SPECIFICITIES OF LEUCINE ZIPPER... MUTANTS by Jennifer Dawn Rieker Submitted to the Office of Honors Programs and Academic Scholarships, Texas AkM University in partial fulfillment of the requirements for 1997-98 UNVERSITY UNDERGRADUATE RESEARCH FELLOWS PROGRAM April 16, 1998...

  4. Hydrodesulfurization of dibenzothiophene catalyzed by alumina-supported ruthenium carbonyl complexes in a pressurized flow system

    SciTech Connect (OSTI)

    NONE

    1994-11-01

    Ruthenium sulfide has been found to be most active for hydrodesulfurization (HDS) of thiophenes as well as hydrogenation and hydrodenitrogenation among transition metal sulfides. When ruthenium sulfide is supported on alumina, silica, or zeolite with high surface area, highly dispersed ruthenium sulfide formed on the supports would increase the catalytic activity per a ruthenium atom. Several researchers have already reported HDS using supported ruthenium sulfides. In these works [Ru(NH{sub 3}){sub 6}]{sup +}, Ru{sub 3}(CO){sub 12}, RuCl{sub 3}, and Ru(III) acetate supported on alumina, zeoliate, carbon, etc., were used as catalyst precursors in HDS of thiophene, benzothiophene, or dibenzothiophene. Although these HDS reactions were performed under an atmospheric pressure, the activity of the catalysts derived from supported ruthenium in a pressurized flow system have not yet been understood. In the present study, HDS of DBT catalyzed by ruthenium catalysts is investigated in a pressurized flow reactor. 17 refs., 2 figs., 2 tabs.

  5. Ruthenium Behavior at Phase Separation of Borosilicate Glass-12259

    SciTech Connect (OSTI)

    Enokida, Youichi [Graduate School of Engineering, Nagoya University, Nagoya, 463-8603 (Japan); Sawada, Kayo [EcoTopia Science Institute, Nagoya University, Nagoya, 463-8603 (Japan)

    2012-07-01

    The Rokkasho reprocessing plant (RRP) located in Aomori, Japan, vitrifies high level waste (HLW) into a borosilicate glass. The HLW is generated from the reprocessing of spent fuel and contains ruthenium (Ru) and other platinum group metals (PGMs). Based on the recent consequences after a huge earthquake that occurred in Japan, a hypothetical blackout was postulated for the RRP to address additional safety analysis requirements. During a prolonged blackout, the borosilicate glass could phase separate due to cooling of the glass in the melter. The Ru present in the glass matrix could migrate into separate phases and impact the durability of the borosilicate glass. The durability of the glass is important for quality assurance and performance assessment of the vitrified HLW. A fundamental study was performed at an independent university to understand the impact of a prolonged blackout. Simulated HLW glasses were prepared for the RRP, and the Ru behavior in phase separated glasses was studied. The simulated HLW glasses contained nonradioactive elements and PGMs. The glass compositions were then altered to enhance the formation of the phase-separated glasses when subjected to thermal treatment at 700 deg. C for 24 hours. The synthesized simulated glasses contained 1.1 % Ru by weight as ruthenium dioxide (RuO{sub 2}). A portion of the RuO{sub 2} formed needle-shaped crystals in the glass specimens. After the thermal treatment, the glass specimen had separated into two phases. One of the two phases was a B{sub 2}O{sub 3} rich phase, and the other phase was a SiO{sub 2} rich phase. The majority of the chemical species in the B{sub 2}O{sub 3} rich phase was leached away with the Material Characterization Center-3 (MCC-3) protocol standardized by the Pacific Northwest National Laboratory using an aqueous low-concentrated nitric acid solution, but the leaching of the Ru fraction was very limited; less than 1% of the original Ru content. The Ru leaching was much less than those of the other elements, and the needle-shaped crystals of RuO{sub 2} were observed in the B{sub 2}O{sub 3} rich phase in the specimen after the leaching test. Another experiment was performed using another glass specimen which had been prepared with the same frits, but used reagent RuO{sub 2} of granular shape at lower content (0.0073% by weight as RuO{sub 2}). The leached fractions of elements for the latter specimen increased to almost the same fraction (more than 10% of the original Ru content) as observed for boron and sodium, when the phase separated glass was leached using the MMC-3 protocol with non-acidic de-ionized water. Based on the results of this study, it was concluded that needle-shaped RuO{sub 2} crystals are contained in the B{sub 2}O{sub 3}-rich phase after phase separation of the borosilicate glass after a hypothetical blackout. The leaching fraction for the needle-shaped RuO{sub 2} present in the phase separated glass is much lower than those for boron or sodium. Ruthenium behavior has been studied for a hypothetical loss of cooling in the liquid fed ceramic melter for high level waste by taking into account the phase separation of borosilicate glass. The needle-shaped crystal of ruthenium dioxide after bi-nodal-type phase separation of the borosilicate glass at 700 deg. C migrated into the B{sub 2}O{sub 3} rich phase, but remained without dissolution by an acidic aqueous solution. Additionally, granular ruthenium dioxide can be a morphological form of ruthenium after bimodal-type phase separation of the vitrified high level waste with borosilicate glass media. After the phase separation of the borosilicate glass, the crystal shape of the ruthenium dioxide is either needle-shaped or granular, and the leachable fraction of ruthenium is relatively much lower than those of major components (boron and sodium) in the vitrified borosilicate glass. The fraction of leached ruthenium increased to almost the same fraction as observed for boron and sodium when the phase-separated glass was leached with ultrapure water. (authors)

  6. Blue Care Elect Enhanced Value (PPO)

    E-Print Network [OSTI]

    Aalberts, Daniel P.

    Blue Care Elect SM Enhanced Value (PPO) Summary of Benefits Williams College An Association of Independent Blue Cross and Blue Shield Plans This health plan meets Minimum Creditable Coverage Standards of your directory, call Member Service at the number on your ID card. ·Visit the Blue Cross Blue Shield

  7. Company Name: Blue Cross Blue Shield of MA Web Site: www.bluecrossma.com

    E-Print Network [OSTI]

    New Hampshire, University of

    Company Name: Blue Cross Blue Shield of MA Web Site: www.bluecrossma.com Industry: Healthcare Brief Company Overview: Headquartered in Boston, Blue Cross Blue Shield of Massachusetts provides comprehensive-level position: Please visit www.bluecrossma.com/careers. With almost 3 million members, Blue Cross Blue Shield

  8. BRANCHED ALKANES FROM BLUE-GREEN ALGAE

    E-Print Network [OSTI]

    Han, Jerry; Calvin, Melvin.

    2008-01-01

    ALKANES FROM BLUE-GREEN ALGAE RECEIV r -· LAWREW RADIATIONAlkanes From Blue-Green Algae by Jerry Han and Oep~rtment l~alkanes from blue-green algae were separated on a The

  9. The Huge, Blue, Jesus Glass Statue

    E-Print Network [OSTI]

    Robbins, Joanna

    2013-01-01

    Later, I found a huge, blue, glass statue of Jesus stuffedOF CALIFORNIA RIVERSIDE The Huge, Blue, Jesus Glass Statue Aeyes as RED And wrote down BLUE for your hair. I had to fix

  10. Quantum Phase Transition in Dimerized Spin-1/2 Chains

    E-Print Network [OSTI]

    Aparajita Das; Sreeparna Bhadra; Sonali Saha

    2015-03-30

    Quantum phase transition in dimerized antiferromagnetic Heisenberg spin chain has been studied. A staircase structure in the variation of concurrence within strongly coupled pairs with that of external magnetic field has been observed indicating multiple critical points. Emergence of entanglement due to external magnetic field or magnetic entanglement is observed for weakly coupled spin pairs in the same dimer chain. Though closed dimerized isotropic XXX Heisenberg chains with different dimer strengths were mainly explored, analogous studies on open chains as well as closed anisotropic (XX interaction) chains with tilted external magnetic field have also been studied.

  11. 21073CAMENABC 5/11 Anthem Blue Cross is the trade name of Blue Cross of California. Anthem Blue Cross and Anthem Blue Cross Life and Health Insurance Company are independent licensees of the Blue Cross Association.

    E-Print Network [OSTI]

    Mease, Kenneth D.

    21073CAMENABC 5/11 Anthem Blue Cross is the trade name of Blue Cross of California. Anthem Blue Cross and Anthem Blue Cross Life and Health Insurance Company are independent licensees of the Blue Cross Association. ® ANTHEM is a registered trademark of Anthem Insurance Companies, Inc. The Blue Cross

  12. Characterization of Palladium and Ruthenium after Reaction with Tetraphenylborate and Mercury

    SciTech Connect (OSTI)

    Duff, M.C.

    2001-09-11

    This report documents a second series of X-ray fine structure and chemical analyses to examine the form that Pd - and, to a lesser extent, ruthenium (Ru) - takes in simulated high-level slurries containing TPB salts.

  13. Platinum-ruthenium-palladium alloys for use as a fuel cell catalyst

    DOE Patents [OSTI]

    Gorer, Alexander (Sunnyvale, CA)

    2002-01-01

    A noble metal alloy composition for a fuel cell catalyst, a ternary alloy composition containing platinum, ruthenium and palladium. The alloy shows increased activity as compared to well-known catalysts.

  14. Novel Ruthenium complexes and their application in dye sensitised solar cells 

    E-Print Network [OSTI]

    McCall, Keri Laura

    2009-01-01

    This work focuses on the design, synthesis and characterisation of novel ruthenium bipyridyl complexes and their use in dye sensitised solar cells (DSSCs). Four series of dyes have been synthesised with the general formula ...

  15. Ruthenium or osmium complexes and their uses as catalysts for water oxidation

    SciTech Connect (OSTI)

    Concepcion Corbea, Javier Jesus; Chen, Zuofeng; Jurss, Jonah Wesley; Templeton, Joseph L; Hoertz, Paul; Meyer, Thomas J

    2014-10-28

    The present invention provides ruthenium or osmium complexes and their uses as a catalyst for catalytic water oxidation. Another aspect of the invention provides an electrode and photo-electrochemical cells for electrolysis of water molecules.

  16. Ruthenium or osmium complexes and their uses as catalysts for water oxidation

    DOE Patents [OSTI]

    Corbea, Javier Jesus Concepcion; Chen, Zuofeng; Jurss, Jonah Wesley; Templeton, Joseph L.; Hoertz, Paul; Meyer, Thomas J.

    2013-09-03

    The present invention provides ruthenium or osmium complexes and their uses as a catalyst for catalytic water oxidation. Another aspect of the invention provides an electrode and photo-electrochemical cells for electrolysis of water molecules.

  17. Volume$3, number 3 CHEMICAL. PHYSICS LETTERS 1 Februrf 1978 INTERACTION OF METHANOL WITH RUTHENIUM

    E-Print Network [OSTI]

    Goodman, Wayne

    Volume$3, number 3 CHEMICAL. PHYSICS LETTERS 1 Februrf 1978 INTERACTION OF METHANOL WITH RUTHENIUM of methanol with a clean methods. Methanol dissociates upon adsorption at 300 K and yields Ha(g) and chemisorbed CO as the domiwt

  18. Dendrimer-Encapsulated Ruthenium Nanoparticles as Catalysts for Lithium-O2 Batteries

    SciTech Connect (OSTI)

    Bhattacharya, Priyanka; Nasybulin, Eduard N.; Engelhard, Mark H.; Kovarik, Libor; Bowden, Mark E.; Li, Shari; Gaspar, Daniel J.; Xu, Wu; Zhang, Jiguang

    2014-12-01

    Dendrimer-encapsulated ruthenium nanoparticles (DEN-Ru) have been used as catalysts in lithium-O2 batteries for the first time. Results obtained from UV-vis spectroscopy, electron microscopy and X-ray photoelectron spectroscopy show that the nanoparticles synthesized by the dendrimer template method are ruthenium oxide instead of metallic ruthenium reported earlier by other groups. The DEN-Ru significantly improve the cycling stability of lithium (Li)-O2 batteries with carbon black electrodes and decrease the charging potential even at low catalyst loading. The monodispersity, porosity and large number of surface functionalities of the dendrimer template prevent the aggregation of the ruthenium nanoparticles making their entire surface area available for catalysis. The potential of using DEN-Ru as stand-alone cathode materials for Li-O2 batteries is also explored.

  19. Equivalence between XY and dimerized models

    SciTech Connect (OSTI)

    Campos Venuti, Lorenzo; Roncaglia, Marco

    2010-06-15

    The spin-1/2 chain with XY anisotropic coupling in the plane and the XX isotropic dimerized chain are shown to be equivalent in the bulk. For finite systems, we prove that the equivalence is exact in given parity sectors, after taking care of the precise boundary conditions. The proof is given constructively by finding unitary transformations that map the models onto each other. Moreover, we considerably generalized our mapping and showed that even in the case of fully site-dependent couplings the XY chain can be mapped onto an XX model. This result has potential application in the study of disordered systems.

  20. Ruthenium on rutile catalyst, catalytic system, and method for aqueous phase hydrogenations

    DOE Patents [OSTI]

    Elliot, Douglas C. (Richland, WA); Werpy, Todd A. (West Richland, WA); Wang, Yong (Richland, WA); Frye, Jr., John G. (Richland, WA)

    2001-01-01

    An essentially nickel- and rhenium-free catalyst is described comprising ruthenium on a titania support where the titania is greater than 75% rutile. A catalytic system containing a nickel-free catalyst comprising ruthenium on a titania support where the titania is greater than 75% rutile, and a method using this catalyst in the hydrogenation of an organic compound in the aqueous phase is also described.

  1. Blue Ribbon Panel Recommendations Report

    Broader source: Energy.gov [DOE]

    The Department of Energy's Geothermal Technologies Office (formerly Geothermal Technologies Program) assembled a geothermal Blue Ribbon Panel on March 22-23, 2011 in Albuquerque, New Mexico for a...

  2. Columbia Blue Furnald MathematicsLewisohn

    E-Print Network [OSTI]

    Bergman, Keren

    Columbia Blue #12;Furnald MathematicsLewisohn Dodge Miller Theatre Kent International Affairs Columbia Blue Blue View: Part I 4 Exponential Education 10 Columbia Days 26 Common Core, 44 Uncommon 72 Columbia Engineering 78 Community, Columbia Style 84 Columbia Moments: 100 Tried and True Blue

  3. The Blue Language1 Michael Klling

    E-Print Network [OSTI]

    Kent, University of

    1 The Blue Language1 Michael Kölling School of Computer Science and Software Engineering Monash. The system we are about to discuss is named Blue. Blue is an integrated programming environment and an object. In this issue, we discuss the language aspects of Blue. Next month we will continue the discussion by describing

  4. STOCK ASSESSMENT OF THE BLUE CRAB

    E-Print Network [OSTI]

    STOCK ASSESSMENT OF THE BLUE CRAB IN CHESAPEAKE BAY 2011 #12;2011 Stock assessment for blue crab in Chesapeake Bay iii Executive Summary The blue crab (Callinectes sapidus) is an icon for the Chesapeake Bay region. The commercial fisheries for blue crab in the Bay remain one of the most valuable fishery sectors

  5. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

    2010-04-04

    Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

  6. Platinum adlayered ruthenium nanoparticles, method for preparing, and uses thereof

    DOE Patents [OSTI]

    Tong, YuYe; Du, Bingchen

    2015-08-11

    A superior, industrially scalable one-pot ethylene glycol-based wet chemistry method to prepare platinum-adlayered ruthenium nanoparticles has been developed that offers an exquisite control of the platinum packing density of the adlayers and effectively prevents sintering of the nanoparticles during the deposition process. The wet chemistry based method for the controlled deposition of submonolayer platinum is advantageous in terms of processing and maximizing the use of platinum and can, in principle, be scaled up straightforwardly to an industrial level. The reactivity of the Pt(31)-Ru sample was about 150% higher than that of the industrial benchmark PtRu (1:1) alloy sample but with 3.5 times less platinum loading. Using the Pt(31)-Ru nanoparticles would lower the electrode material cost compared to using the industrial benchmark alloy nanoparticles for direct methanol fuel cell applications.

  7. 1) Anthem Blue Dental PPO Plus 2) Anthem Blue Dental PPO

    E-Print Network [OSTI]

    - 35 - 1) Anthem Blue Dental PPO Plus 2) Anthem Blue Dental PPO DENTAL INSURANCE ANTHEM BLUE CROSS AND BLUE SHIELD You may select from two separate dental care plans to meet your individual needs. Premium Resources/Benefits Office for additional information. ANTHEM BLUE DENTAL PPO PLUS This dental plan offers

  8. Development of a stable cobalt-ruthenium Fisher-Tropsch catalyst. Final report

    SciTech Connect (OSTI)

    Frame, R.R.; Gala, H.B.

    1995-02-01

    The reverse micelle catalyst preparation method has been used to prepare catalysts on four supports: magnesium oxide, carbon, alumina- titania and steamed Y zeolite. These catalysts were not as active as a reference catalyst prepared during previous contracts to Union Carbide Corp. This catalyst was supported on steamed Y zerolite support and was impregnated by a pore-filling method using a nonaqueous solvent. Additional catalysts were prepared via pore- filling impregnation of steamed Y zeolites. These catalysts had levels of cobalt two to three and a half times as high as the original Union Carbide catalyst. On a catalyst volume basis they were much more active than the previous catalyst; on an atom by atom basis the cobalt was about of the same activity, i.e., the high cobalt catalysts` cobalt atoms were not extensively covered over and deactivated by other cobalt atoms. The new, high activity, Y zerolite catalysts were not as stable as the earlier Union Carbide catalyst. However, stability enhancement of these catalysts should be possible, for instance, through adjustment of the quantity and/or type of trace metals present. A primary objective of this work was determination whether small amounts of ruthenium could enhance the activity of the cobalt F-T catalyst. The reverse micelle catalysts were not activated by ruthenium, indeed scanning transmission electronic microscopy (STEM) analysis provided some evidence that ruthenium was not present in the cobalt crystallites. Ruthenium did not seem to activate the high cobalt Y zeolite catalyst either, but additional experiments with Y zeolite-supported catalysts are required. Should ruthenium prove not to be an effective promoter under the simple catalyst activation procedure used in this work, more complex activation procedures have been reported which are claimed to enhance the cobalt/ruthenium interaction and result in activity promotion by ruthenium.

  9. Adsorption of silver dimer on graphene - A DFT study

    SciTech Connect (OSTI)

    Kaur, Gagandeep, E-mail: gaganj1981@yahoo.com [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014, India and Chandigarh Engineering College, Landran, Mohali-140307, Punjab (India); Gupta, Shuchi [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014, India and University Institute of Engineering and Technology, Panjab University, Chandigarh -160014 (India); Rani, Pooja; Dharamvir, Keya [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014 (India)

    2014-04-24

    We performed a systematic density functional theory (DFT) study of the adsorption of silver dimer (Ag{sub 2}) on graphene using SIESTA (Spanish Initiative for Electronic Simulations with Thousands of Atoms) package, in the generalized gradient approximation (GGA). The adsorption energy, geometry, and charge transfer of Ag2-graphene system are calculated. The minimum energy configuration for a silver dimer is parallel to the graphene sheet with its two atoms directly above the centre of carbon-carbon bond. The negligible charge transfer between the dimer and the surface is also indicative of a weak bond. The methodology demonstrated in this paper may be applied to larger silver clusters on graphene sheet.

  10. A quantum dimer model for the pseudogap metal

    E-Print Network [OSTI]

    Matthias Punk; Andrea Allais; Subir Sachdev

    2015-07-05

    We propose a quantum dimer model for the metallic state of the hole-doped cuprates at low hole density, $p$. The Hilbert space is spanned by spinless, neutral, bosonic dimers and spin $S=1/2$, charge $+e$ fermionic dimers. The model realizes a `fractionalized Fermi liquid' with no symmetry-breaking and small hole pocket Fermi surfaces enclosing a total area determined by $p$. Exact diagonalization, on lattices of sizes up to $8 \\times 8$, shows anisotropic quasiparticle residue around the pocket Fermi surfaces. We discuss the relationship to experiments.

  11. Blue-green upconversion laser

    DOE Patents [OSTI]

    Nguyen, Dinh C. (Los Alamos, NM); Faulkner, George E. (Los Alamos, NM)

    1990-01-01

    A blue-green laser (450-550 nm) uses a host crystal doped with Tm.sup.3+. The Tm.sup.+ is excited through upconversion by a red pumping laser and an IR pumping laser to a state which transitions to a relatively lower energy level through emissions in the blue-green band, e.g., 450.20 nm at 75 K. The exciting laser may be tunable dye lasers or may be solid-state semiconductor laser, e.g., GaAlAs and InGaAlP.

  12. Blue light emitting thiogallate phosphor

    DOE Patents [OSTI]

    Dye, Robert C. (Los Alamos, NM); Smith, David C. (Los Alamos, NM); King, Christopher N. (Portland, OR); Tuenge, Richard T. (Hillsboro, OR)

    1998-01-01

    A crystalline blue emitting thiogallate phosphor of the formula RGa.sub.2 S.sub.4 :Ce.sub.x where R is selected from the group consisting of calcium, strontium, barium and zinc, and x is from about 1 to 10 atomic percent, the phosphor characterized as having a crystalline microstructure on the size order of from about 100 .ANG. to about 10,000 .ANG. is provided together with a process of preparing a crystalline blue emitting thiogallate phosphor by depositing on a substrate by CVD and resultant thin film electroluminescent devices including a layer of such deposited phosphor on an ordinary glass substrate.

  13. Blue-green upconversion laser

    DOE Patents [OSTI]

    Nguyen, D.C.; Faulkner, G.E.

    1990-08-14

    A blue-green laser (450--550 nm) uses a host crystal doped with Tm[sup 3+]. The Tm[sup 3+] is excited through upconversion by a red pumping laser and an IR pumping laser to a state which transitions to a relatively lower energy level through emissions in the blue-green band, e.g., 450.20 nm at 75 K. The exciting laser may be tunable dye lasers or may be solid-state semiconductor laser, e.g., GaAlAs and InGaAlP. 3 figs.

  14. Development of carbon-metal oxide supercapacitors from sol-gel derived carbon-ruthenium xerogels

    SciTech Connect (OSTI)

    Lin, C.; Ritter, J.A.; Popov, B.N.

    1999-09-01

    There has been increasing interest in electrochemical capacitors as energy storage systems because of their high power density and long cycle life, compared to battery devices. According to the mechanism of energy storage, there are two types of electrochemical capacitors. One type is based on double layer (dl) formation due to charge separation, and the other type is based on a faradaic process due to redox reactions. Sol-gel derived high surface area carbon-ruthenium xerogels were prepared from carbonized resorcinol-formaldehyde resins containing an electrochemically active form of ruthenium oxide. The electrochemical capacitance of these materials increased with an increase in the ruthenium content indicating the presence of pseudocapacitance associated with the ruthenium oxide undergoing reversible faradaic redox reactions. A specific capacitance of 256 F/g (single electrode) was obtained from a carbon xerogel containing 14 wt% Ru, which corresponded to more than 50% utilization of the ruthenium. The double layer accounted for 40% of this capacitance. This material was also electrochemically stable, showing no change in a cyclic voltammogram for over 2,000 cycles.

  15. Deep Blue No.1-A Slimhole Geothermal Discovery At Blue Mountain...

    Open Energy Info (EERE)

    Area (Fairbank & Niggemann, 2004) Slim Holes At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Thermal Gradient Holes At Blue Mountain Geothermal Area (Fairbank &...

  16. A structural investigation of the chemokine dimer interface 

    E-Print Network [OSTI]

    Hayes, Garret Lance

    2013-02-22

    Macrophage Inflammatory Protein (MIP)-1b is a dimeric protein of the CC chemokine subfamily. Interest in both the structure and function of MIP-1b has increased rapidly over the past several years, resulting primarily from ...

  17. Glassy Dislocation Dynamics in 2-D Colloidal Dimer Crystals

    E-Print Network [OSTI]

    Sharon J. Gerbode; Umang Agarwal; Desmond C. Ong; Chekesha M. Liddell; Fernando Escobedo; Itai Cohen

    2010-08-11

    Although glassy relaxation is typically associated with disorder, here we report on a new type of glassy dynamics relating to dislocations within 2-D crystals of colloidal dimers. Previous studies have demonstrated that dislocation motion in dimer crystals is restricted by certain particle orientations. Here, we drag an optically trapped particle through such dimer crystals, creating dislocations. We find a two-stage relaxation response where initially dislocations glide until encountering particles that cage their motion. Subsequent relaxation occurs logarithmically slowly through a second process where dislocations hop between caged configurations. Finally, in simulations of sheared dimer crystals, the dislocation mean squared displacement displays a caging plateau typical of glassy dynamics. Together, these results reveal a novel glassy system within a colloidal crystal.

  18. Blue whale response to underwater noise from commercial ships

    E-Print Network [OSTI]

    McKenna, Megan Frances

    2011-01-01

    hydrodynamics and energetics of blue whale lunge feeding:2010. Association between Blue Whale (Balaenoptera musculus)and calling behavior of blue whales from a suction-cup-

  19. Mathematical and experimental approaches to the dimer catastrophe theory

    E-Print Network [OSTI]

    Field, Christopher Martyn

    2011-02-08

    to the Dimer Catastrophe Theory Christopher Martyn Field Gonville & Caius College Department of Genetics University of Cambridge A dissertation submitted for the degree of Doctor of Philosophy November 12, 2010 Title Mathematical and Experimental Approaches... to the Dimer Catastrophe Theory Abstract Multicopy plasmids rely on random distribution for stable inheritance by daughter cells at division. Threats to plasmid copy number increase the probability of plasmid loss, which can be detrimental to both plasmid...

  20. Painting Your Home Blue David Cypher

    E-Print Network [OSTI]

    Painting Your Home Blue David Cypher Advanced Network Technologies Division (ANTD) / ITL / NIST;Painting Your Home Blue David Cypher Information Technology Laboratory #12;BluetoothTM Wireless Networking

  1. Simulating Ru L3-Edge X-ray Absorption Spectroscopy with Time-Dependent Density Functional Theory: Model Complexes and Electron Localization in Mixed-Valence Metal Dimers

    SciTech Connect (OSTI)

    Kuiken, Benjamin E. Van; Valiev, Marat; Daifuku, Stephanie L.; Bannan, Caitlin; Strader, Matthew L.; Cho, Hana; Huse, Nils; Schoenlein, Robert W.; Govind, Niranjan; Khalil, Munira

    2013-04-26

    Ruthenium L3-edge X-ray absorption (XA) spectroscopy probes unoccupied 4d orbitals of the metal atom and is increasingly being used to investigate the local electronic structure in ground and excited electronic states of Ru complexes. The simultaneous development of computational tools for simulating Ru L3-edge spectra is crucial for interpreting the spectral features at a molecular level. This study demonstrates that time-dependent density functional theory (TDDFT) is a viable and predictive tool for simulating ruthenium L3-edge XA spectroscopy. We systematically investigate the effects of exchange correlation functional and implicit and explicit solvent interactions on a series of RuII and RuIII complexes in their ground and electronic excited states. The TDDFT simulations reproduce all of the experimentally observed features in Ru L3-edge XA spectra within the experimental resolution (0.4 eV). Our simulations identify ligand-specific charge transfer features in complicated Ru L3-edge spectra of [Ru(CN)6]4- and RuII polypyridyl complexes illustrating the advantage of using TDDFT in complex systems. We conclude that the B3LYP functional most accurately predicts the transition energies of charge transfer features in these systems. We use our TDDFT approach to simulate experimental Ru L3-edge XA spectra of transition metal mixed-valence dimers of the form [(NC)5MII-CN-RuIII(NH3)5] (where M = Fe or Ru) dissolved in water. Our study determines the spectral signatures of electron delocalization in Ru L3-edge XA spectra. We find that the inclusion of explicit solvent molecules is necessary for reproducing the spectral features and the experimentally determined valencies in these mixed-valence complexes. This study validates the use of TDDFT for simulating Ru 2p excitations using popular quantum chemistry codes and providing a powerful interpretive tool for equilibrium and ultrafast Ru L3-edge XA spectroscopy.

  2. Blue Version Math 1432 -Exam III Name:____________________

    E-Print Network [OSTI]

    Glowinski, Roland

    Blue Version Math 1432 - Exam III Name:____________________ Morgan, Spring 2003 Social Sec converge absolutely, converge conditionally, or diverge? #12;Blue Version 11. 3)1('',1)1(',2)1( -==-= fff of )2( +x . Write the solutions to Problems 13-17 in your blue book. Show all of your work. 13. (5

  3. BLUE RIVER BASIN (Dodson Industrial District)

    E-Print Network [OSTI]

    US Army Corps of Engineers

    BLUE RIVER BASIN (Dodson Industrial District) Kansas City, Missouri MODIFICATION REQUEST capability to support this request. PROJECT PURPOSE Dodson Industrial District is located along the Blue of a 6,800 foot long levee- floodwall along the north bank of the Blue River from the Bannister Road

  4. Blue Waters: An Extraordinary Research Capability for

    E-Print Network [OSTI]

    Blue Waters: An Extraordinary Research Capability for Ad ancing Science & Engineering Frontiers will talk about the new supercomputer Blue Waters and its proposed use by the science and engineering of the University of Illinois at Urbana-Champaign. This system, called Blue Waters, is based on the latest computing

  5. Original article Blue-stain fungi associated

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Blue-stain fungi associated with Tomicus piniperda in Sweden and preliminary to determine the development of blue-staining of sapwood. Fungi were isolated from samples of inner bark and blue-stained sapwood in connection with galleries of T piniperda. Samples were also taken from beetle

  6. Accessibility Application Blue Badge Car Park UK

    E-Print Network [OSTI]

    Painter, Kevin

    i Accessibility Application Blue Badge Car Park UK Konstantinos Grassos H00113751 August 2012. In this project, Blue Badge Car Park (BBCP) is presented which is actually a mobile-based park finder application. It specifically focuses on finding parking spaces for wheelchair users, which are indicated by the blue badge

  7. Why is the ocean blue? One of these misconceptions is that the ocean is blue

    E-Print Network [OSTI]

    Cruz-Pol, Sandra L.

    can absorb light, as in tea or coffee. Green algae in rivers and streams often lend a blue-green color into the water. Red, yellow, green, and blue all go into the sea. Then, the sea absorbs the red, yellow, and green light, leaving the blue light. Some of the blue light scatters off water molecules

  8. The riddle of the blue-straggler stars Die Blauen Nachz uglersterne (blue-straggler

    E-Print Network [OSTI]

    The riddle of the blue-straggler stars Die Blauen Nachz uglersterne (blue-straggler stars) sind sequence beyond the turn o#11;. These so- called blue-straggler stars (BS) are quite common, they occur systems. Fig. 1 provides an example of an intermediate old open cluster with a rich blue

  9. PART A: TYPE OF COVERAGE HMO Colorado/Anthem Blue Cross and Blue Shield

    E-Print Network [OSTI]

    PART A: TYPE OF COVERAGE HMO Colorado/Anthem Blue Cross and Blue Shield Colorado Higher Education Insurance Benefits Alliance Trust Effective January 1, 2015 Blue Advantage HMO/Point-of-Service(POS) Plan and copayment options reflect the amount the covered person will pay. BlueAdvantage HMO

  10. Rheology of cholesteric blue phases

    E-Print Network [OSTI]

    A. Dupuis; D. Marenduzzo; E. Orlandini; J. M. Yeomans

    2006-05-11

    Blue phases of cholesteric liquid crystals offer a spectacular example of naturally occurring disclination line networks. Here we numerically solve the hydrodynamic equations of motion to investigate the response of three types of blue phases to an imposed Poiseuille flow. We show that shear forces bend and twist and can unzip the disclination lines. Under gentle forcing the network opposes the flow and the apparent viscosity is significantly higher than that of an isotropic liquid. With increased forcing we find strong shear thinning corresponding to the disruption of the defect network. As the viscosity starts to drop, the imposed flow sets the network into motion. Disclinations break-up and re-form with their neighbours in the flow direction. This gives rise to oscillations in the time-dependent measurement of the average stress.

  11. 2H2O O2 + 4H+ + 4e b H2O OH + H+

    E-Print Network [OSTI]

    Hendry, Andrew

    2 R2 R2 Ruthenium 'blue dimer' + Figure 1 | Catalytic water oxidation. Photosynthesis is fuelled by the conversion of water into oxygen and hydrogen. a, In the first part of this process, known as water oxidation, water is converted into oxygen, four protons (H+ ) and four electrons (e­ ). b, Oxidation by the removal

  12. Confined Cubic Blue Phases under Shear

    E-Print Network [OSTI]

    O. Henrich; K. Stratford; D. Marenduzzo; P. V. Coveney; M. E. Cates

    2012-03-14

    We study the behaviour of confined cubic blue phases under shear flow via lattice Boltzmann simulations. We focus on the two experimentally observed phases, blue phase I and blue phase II. The disinclination network of blue phase II continuously breaks and reforms under shear, leading to an oscillatory stress response in time. The oscillations are only regular for very thin samples. For thicker samples, the shear leads to a "stick-slip" motion of part of the network along the vorticity direction. Blue phase I responds very differently: its defect network undergoes seemingly chaotic rearrangements under shear, irrespective of system size.

  13. Inflation and Alternatives with Blue Tensor Spectra

    E-Print Network [OSTI]

    Yi Wang; Wei Xue

    2014-10-20

    We study the tilt of the primordial gravitational waves spectrum. A hint of blue tilt is shown from analyzing the BICEP2 and POLARBEAR data. Motivated by this, we explore the possibilities of blue tensor spectra from the very early universe cosmology models, including null energy condition violating inflation, inflation with general initial conditions, and string gas cosmology, etc. For the simplest G-inflation, blue tensor spectrum also implies blue scalar spectrum. In general, the inflation models with blue tensor spectra indicate large non-Gaussianities. On the other hand, string gas cosmology predicts blue tensor spectrum with highly Gaussian fluctuations. If further experiments do confirm the blue tensor spectrum, non-Gaussianity becomes a distinguishing test between inflation and alternatives.

  14. Inflation and alternatives with blue tensor spectra

    SciTech Connect (OSTI)

    Wang, Yi; Xue, Wei E-mail: wei.xue@sissa.it

    2014-10-01

    We study the tilt of the primordial gravitational waves spectrum. A hint of blue tilt is shown from analyzing the BICEP2 and POLARBEAR data. Motivated by this, we explore the possibilities of blue tensor spectra from the very early universe cosmology models, including null energy condition violating inflation, inflation with general initial conditions, and string gas cosmology, etc. For the simplest G-inflation, blue tensor spectrum also implies blue scalar spectrum. In general, the inflation models with blue tensor spectra indicate large non-Gaussianities. On the other hand, string gas cosmology predicts blue tensor spectrum with highly Gaussian fluctuations. If further experiments do confirm the blue tensor spectrum, non-Gaussianity becomes a distinguishing test between inflation and alternatives.

  15. 1370 Rev. (3/03) An independent licensee of the Blue Cross and Blue Shield Association. Anthem Blue Cross and Blue Shield is the trade name of Anthem Health Plans of New Hampshire, Inc.

    E-Print Network [OSTI]

    Myers, Lawrence C.

    1370 Rev. (3/03) An independent licensee of the Blue Cross and Blue Shield Association. Anthem Blue Cross and Blue Shield is the trade name of Anthem Health Plans of New Hampshire, Inc. ® Registered marks of the Blue Cross and Blue Shield Association. Request for Certification for a Mentally or Physically

  16. Highly stable tetrathiafulvalene radical dimers in [3]catenanes

    SciTech Connect (OSTI)

    Spruell, Jason M.; Coskun, Ali; Friedman, Douglas C.; Forgan, Ross S.; Sarjeant, Amy A.; Trabolsi, Ali; Fahrenbach, Albert C.; Barin, Gokhan; Paxton, Walter F.; Dey, Sanjeev K.; Olson, Mark A.; Benítez, Diego; Tkatchouk, Ekaterina; Colvin, Michael T.; Carmielli, Raanan; Caldwell, Stuart T.; Rosair, Georgina M.; Hewage, Shanika Gunatilaka; Duclairoir, Florence; Seymour, Jennifer L.; Slawin, Alexandra M.Z.; Goddard, III, William A.; Wasielewski, Michael R.; Cooke, Graeme; Stoddart, J. Fraser

    2010-12-03

    Two [3]catenane 'molecular flasks' have been designed to create stabilized, redox-controlled tetrathiafulvalene (TTF) dimers, enabling their spectrophotometric and structural properties to be probed in detail. The mechanically interlocked framework of the [3]catenanes creates the ideal arrangement and ultrahigh local concentration for the encircled TTF units to form stable dimers associated with their discrete oxidation states. These dimerization events represent an affinity umpolung, wherein the inversion in electronic affinity replaces the traditional TTF-bipyridinium interaction, which is over-ridden by stabilizing mixed-valence (TTF){sub 2}{sup {sm_bullet}+} and radical-cation (TTF{sup {sm_bullet}+}){sub 2} states inside the 'molecular flasks.' The experimental data, collected in the solid state as well as in solution under ambient conditions, together with supporting quantum mechanical calculations, are consistent with the formation of stabilized paramagnetic mixed-valence dimers, and then diamagnetic radical-cation dimers following subsequent one-electron oxidations of the [3]catenanes.

  17. Synthesis, Characterization and Reactivity of Electrophilic Organometallic Compounds of Ruthenium, Tantalum and Silicon 

    E-Print Network [OSTI]

    Ramirez, Rodrigo

    2014-12-11

    symmetry and charge distribution. The synthesis of a family of d^6 ML5 and d^6 ML6 ruthenium triflate complexes of the pincer (P2C=)Ru(X) (X = Cl, H, OAc, acac) architecture by ligand exchange using Me3SiOTf will be presented. It was speculated...

  18. The Reactivity Limit for Methanol Oxidation on Platinum/Ruthenium Catalysts

    E-Print Network [OSTI]

    The Reactivity Limit for Methanol Oxidation on Platinum/Ruthenium Catalysts A. Wieckowski 0.5 1.0 1.5 2.0 2.5 3.0 Pt/Ru Decorated (UIUC) PtRu Alloy (JM) E = 0.4 V Oxidation in 0.5 M Methanol

  19. Investigation of ruthenium dioxide formation mechanisms in containment glass synthesized by liquid feed

    SciTech Connect (OSTI)

    Sawada, K.; Shimada, T.; Sako, N.; Enokida, Y. [Graduate School of Engineering, Nagoya University (Japan); Schuller, S.; Angeli, F. [CEA-DEN-DTCD-LCV-SECM, 30207 Bagnols-sur-Ceze (France); Charpentier, T. [CEA-Saclay, DSM-IRAMIS-SIS2M, 91191 Gif-sur-Yvette (France)

    2013-07-01

    The presenting paper focuses on the structural configuration of ruthenium in vitreous matrices with the objective of obtaining more insight into ruthenium incorporation and solubilization mechanisms in borosilicate glasses. To determine the structural effect of an increasing RuO{sub 2} in a borosilicate glass, a series of glass samples were selected from a benchmark composition. {sup 11}B NMR shows that the borate network is influenced by the presence of RuO{sub 2} in the glass: the addition of 2% RuO{sub 2} in a borosilicate glass led to a significant rise of BO{sub 4}. RuO{sub 2} precipitated in the glass does not seem to be the cause of this modification because when RuO{sub 2} increase there is no further change of BO{sub 4} fraction. This effect can be therefore attributed to RuO{sub 2} dissolved in the glass. RuO{sub 2} is known to have a very low solubility in borosilicate glasses (50 to 2000 ppm depending on the temperature, sodium concentration and conditions of synthesis). The link between the ruthenium and the borated network is not yet clearly identified, however, assumptions can be made such as the formation of Ru-O-B when a sufficient quantity of Ru is add (> 400 ppm). Ruthenium could play the role of silicon in increasing the possibility of bridging bond formation with boron coordination number IV.

  20. Method for producing electricity using a platinum-ruthenium-palladium catalyst in a fuel cell

    DOE Patents [OSTI]

    Gorer, Alexander

    2004-01-27

    A method for producing electricity using a fuel cell that utilizes a ternary alloy composition as a fuel cell catalyst, the ternary alloy composition containing platinum, ruthenium and palladium. The alloy shows increased activity as compared to well-known catalysts.

  1. Protonation effect on the electronic properties of 2-pyridone monomer, dimer and its water clusters: A theoretical study

    SciTech Connect (OSTI)

    Saed, Behnaz; Omidyan, Reza E-mail: reza.omidyan@u-psud.fr; Centre Laser de l’Université Paris Sud , Bât. 106, Univ. Paris-Sud 11, 91405 Orsay Cedex

    2014-01-14

    The CC2 (second order approximate coupled cluster method) has been applied to investigate protonation effect on electronic transition energies of 2-pyridone (2PY), 2-pyridone dimer, and micro-solvated 2-pyridone (0-2 water molecules). The PE profiles of protonated 2-pyridone (2PYH{sup +}) as well as monohydrated 2PYH{sup +} at the different electronic states have been investigated. The {sup 1}??* state in protonated species (2PYH{sup +}) is a barrier free and dissociative state along the O-H stretching coordinate. In this reaction coordinate, the lowest lying {sup 1}??* predissociates the bound S{sub 1}({sup 1}??*) state, connecting the latter to a conical intersection with the S{sub 0} state. These conical intersections lead the {sup 1}??* state to proceed as predissociative state and finally direct the excited system to the ground state. Furthermore, in presence of water molecule, the {sup 1}??* state still remains dissociative but the conical intersection between {sup 1}??* and ground state disappears. In addition, according to the CC2 calculation results, it has been predicted that protonation significantly blue shifts the S{sub 1}-S{sub 0} electronic transition of monomer, dimer, and microhydrated 2-pyridone.

  2. Palladium- and Ruthenium-Catalyzed Decarboxylative Allylations and Michael Addition-Allylation Reactions. Applications in Nitrogen Heterocycle Synthesis

    E-Print Network [OSTI]

    Wang, Chao

    2008-08-21

    Our group has a long-standing interest in Pd or Ru-catalyzed decarboxylative coupling reactions. It has been shown that allyl ?-ketoesters, upon treatment with palladium or ruthenium, generate freely diffusing enolates and ?-allyl electrophiles...

  3. PHYSICAL REVIEW B 84, 214110 (2011) Ordered phases in ruthenium binary alloys from high-throughput first-principles calculations

    E-Print Network [OSTI]

    Hart, Gus

    2011-01-01

    properties, as a pure element and as an alloy component. Ruthenium's practical importance as a catalytic-oxidation, CO electro-oxidation, and methane steam reforming).7 Experimental examples of this potential

  4. Blue Summit | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:BlueBioStar

  5. BLUE MOUNTAIN | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12Power, Inc | DepartmentPeer20InsulatedofBESTCorn CanBLUE MOUNTAIN

  6. BLUE MOUNTAIN | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12Power, Inc | DepartmentPeer20InsulatedofBESTCorn CanBLUE

  7. Selective catalytic reduction system and process for treating NOx emissions using a palladium and rhodium or ruthenium catalyst

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly (Orlando, FL); Rossin, Joseph A. (Columbus, OH); Knapke, Michael J. (Columbus, OH)

    2011-07-12

    A process for the catalytic reduction of nitrogen oxides (NOx) in a gas stream (29) in the presence of H.sub.2 is provided. The process comprises contacting the gas stream with a catalyst system (38) comprising zirconia-silica washcoat particles (41), a pre-sulfated zirconia binder (44), and a catalyst combination (40) comprising palladium and at least one of rhodium, ruthenium, or a mixture of ruthenium and rhodium.

  8. Structure of a Loose Dimer: an Intermediate in Nitric Oxide Synthase Assembly

    SciTech Connect (OSTI)

    Pant,K.; Crane, B.

    2005-01-01

    Cooperativity among ligand binding, subunit association, and protein folding has implications for enzyme regulation as well as protein aggregation events associated with disease. The binding of substrate l-arginine or cofactor tetrahydrobiopterin converts nitric oxide synthases (NOSs) from a 'loose dimer', with an exposed active center and higher sensitivity to proteolysis, to a 'tight dimer' competent for catalysis. The crystallographic structure of the Bacillus subtilis NOS loose dimer shows an altered association state with severely destabilized subdomains. Ligand binding or heme reduction converts loose dimers to tight dimers in solution and crystals. Mutations at key positions in the dimer interface that distinguish prokaryotic from eukaryotic NOSs affect the propensity to form loose dimers. The loose dimer structure indicates that non-native interactions can mediate subunit association in NOS.

  9. Thermodynamics of Blue Phases In Electric Fields

    E-Print Network [OSTI]

    O. Henrich; D. Marenduzzo; K. Stratford; M. E. Cates

    2010-03-04

    We present extensive numerical studies to determine the phase diagrams of cubic and hexagonal blue phases in an electric field. We confirm the earlier prediction that hexagonal phases, both 2 and 3 dimensional, are stabilized by a field, but we significantly refine the phase boundaries, which were previously estimated by means of a semi-analytical approximation. In particular, our simulations show that the blue phase I -- blue phase II transition at fixed chirality is largely unaffected by electric field, as observed experimentally.

  10. Geothermal Technologies Program Blue Ribbon Panel Recommendations

    SciTech Connect (OSTI)

    none,

    2011-06-17

    The Geothermal Technologies Program assembled a geothermal Blue Ribbon Panel on March 22-23, 2011 in Albuquerque, New Mexico for a guided discussion on the future of geothermal energy in the United States and the role of the DOE Program. The Geothermal Blue Ribbon Panel Report captures the discussions and recommendations of the experts. An addendum is available here: http://www.eere.energy.gov/geothermal/pdfs/gtp_blue_ribbon_panel_report_addendum10-2011.pdf

  11. Deep Blue No. 1-A Slimhole Geothermal Discovery at Blue Mountain...

    Open Energy Info (EERE)

    Deep Blue No. 1-A Slimhole Geothermal Discovery at Blue Mountain, Humboldt County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Deep...

  12. Transition Metal Dimer Internuclear Distances from Measured Force Constants Joseph L. Jules and John R. Lombardi*

    E-Print Network [OSTI]

    Lombardi, John R.

    Transition Metal Dimer Internuclear Distances from Measured Force Constants Joseph L. Jules distances, have been extended to the transition metal dimers to test which one gives the most accurate fit's and Guggenheimer's for the transition metal dimers. Although Pauling's rule gives the best results, the remarkable

  13. Grain Fish Money Financing Africa's Green and Blue Revolutions Financing Africa's Green and Blue Revolutions

    E-Print Network [OSTI]

    Grain Fish Money Financing Africa's Green and Blue Revolutions 1 Financing Africa's Green and Blue Revolutions GRAIN FISH MONEY AFRICA PROGRESS REPORT 2014 #12;AFRICA PROGRESS REPORT 2014 2 #12;Grain Fish Money Financing Africa's Green and Blue Revolutions 3 #12;#12;Grain Fish Money Financing Africa's Green

  14. Flexoelectric switching in cholesteric blue phases

    E-Print Network [OSTI]

    A. Tiribocchi; M. E. Cates; G. Gonnella; D. Marenduzzo; E. Orlandini

    2013-03-25

    We present computer simulations of the response of a flexoelectric blue phase network, either in bulk or under confinement, to an applied field. We find a transition in the bulk between the blue phase I disclination network and a parallel array of disclinations along the direction of the applied field. Upon switching off the field, the system is unable to reconstruct the original blue phase but gets stuck in a metastable phase. Blue phase II is comparatively much less affected by the field. In confined samples, the anchoring at the walls and the geometry of the device lead to the stabilisation of further structures, including field-aligned disclination loops, splayed nematic patterns, and yet more metastable states. Our results are relevant to the understanding of the switching dynamics for a class of new, "superstable", blue phases which are composed of bimesogenic liquid crystals, as these materials combine anomalously large flexoelectric coefficients, and low or near-zero dielectric anisotropy.

  15. Blue Stragglers After the Main Sequence

    E-Print Network [OSTI]

    Alison Sills; Amanda Karakas; John Lattanzio

    2008-11-18

    We study the post-main sequence evolution of products of collisions between main sequence stars (blue stragglers), with particular interest paid to the horizontal branch and asymptotic giant branch phases. We found that the blue straggler progeny populate the colour-magnitude diagram slightly blueward of the red giant branch and between 0.2 and 1 magnitudes brighter than the horizontal branch. We also found that the lifetimes of collision products on the horizontal branch is consistent with the numbers of so-called "evolved blue straggler stars" (E-BSS) identified by various authors in a number of globular clusters, and is almost independent of mass or initial composition profile. The observed ratio of the number of E-BSS to blue stragglers points to a main sequence lifetime for blue stragglers of approximately 1-2 Gyr on average.

  16. Complex of transferrin with ruthenium for medical applications. [Ru 97, Ru 103

    DOE Patents [OSTI]

    Richards, P.; Srivastava, S.C.; Meinken, G.E.

    1980-11-03

    A novel Ruthenium-transferrin complex, prepared by reacting iron-free human transferrin dissolved in a sodium acetate solution at pH 7 with ruthenium by heating at about 40/sup 0/C for about 2 hours, and purifying said complex by means of gel chromatography with pH 7 sodium acetate as eluent. The mono- or di-metal complex produced can be used in nuclear medicine in the diagnosis and/or treatment of tumors and abscesses. Comparitive results with Ga-67-citrate, which is the most widely used tumor-localizing agent in nuclear medicine, indicate increased sensitivity of detection and greater tumor uptake with the Ru-transferrin complex.

  17. Blue oak seedling age influences growth and mortality

    E-Print Network [OSTI]

    Phillips, Ralph L.; McDougald, Neil K.; McCreary, Doug D.; Atwill, Edward R.

    2007-01-01

    1997b. Stand- level status of blue oak sapling recruitment1991. Soil water effects on blue oak seedling establishment.NK, Standiford RB, Frost WE. 1996. Blue oak seedlings may be

  18. Blue rubber bleb nevus syndrome: a rare multisystem affliction

    E-Print Network [OSTI]

    Sangwan, Ankita; Kaur, Sarbjit; Jain, V.K.; Dayal, Surabhi

    2015-01-01

    4. Moodley M, Ramdial P. Blue rubber bleb nevus syndrome:A . Grammatopoulos .Blue Rubber Bleb Nevus Syndrome:A casePMID 7783168] 8. Munkad M. Blue rubber bleb nevus syndrome.

  19. Blue and fin whale acoustics and ecology off Antarctic Peninsula

    E-Print Network [OSTI]

    Širovi?, Ana

    2006-01-01

    for increases in Antarctic blue whales based on BayesianG. , 1962b. The movements of blue and fin whales within theF. G. Wheeler, 1929. Southern blue and fin whales. Discovery

  20. The truth about 'The truth about true blue'

    E-Print Network [OSTI]

    Cohen, Jonathan; Hardin, C. L.; McLaughlin, Brian P.

    2007-01-01

    2168. Tye, M. (2006a). True blue. Analysis, 66. Tye, M. (2006b). The truth about true blue. Analysis, 66(4).D. R. (2006). Truest blue. Analysis, 66. Cohen, J. , Hardin,

  1. BLUE: Active Queue Management CS756 Project Report

    E-Print Network [OSTI]

    BLUE: Active Queue Management CS756 Project Report Sunitha Burri May 5, 2004 #12;1 INDEX Abstract ........................................................... 2 1. Introduction ...................................................... 2 2. BLUE Active Queue Management Algorithm .............. 4 3. Performance Evaluation of BLUE by simulation ........... 5 3

  2. Blue Waters An Extraordinary Computer to Enable Extraordinary Research

    E-Print Network [OSTI]

    Blue Waters An Extraordinary Computer to Enable Extraordinary Research Thom Dunning National Center for Supercomputing Applications Blue Waters Extraordinaire · 25 February 2011 · Pacific Northwest National Laboratory (NCSA Building, NPCF) · Three major computing systems (Abe, Lincoln, Ember) Blue Waters Extraordinaire

  3. Flow Test At Blue Mountain Geothermal Area (Fairbank Engineering...

    Open Energy Info (EERE)

    Flow Test At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At Blue...

  4. Slim Holes At Blue Mountain Geothermal Area (Fairbank Engineering...

    Open Energy Info (EERE)

    Slim Holes At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Slim Holes At Blue...

  5. Task Force for Strategic Developments to Blue Ribbon Commission...

    Office of Environmental Management (EM)

    Task Force for Strategic Developments to Blue Ribbon Commission Recommendations Task Force for Strategic Developments to Blue Ribbon Commission Recommendations Formed at the...

  6. Blue Mountain Hot Spring Guest Ranch Pool & Spa Low Temperature...

    Open Energy Info (EERE)

    Blue Mountain Hot Spring Guest Ranch Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Blue Mountain Hot Spring Guest Ranch Pool & Spa Low Temperature...

  7. Well Log Data At Blue Mountain Geothermal Area (Fairbank & Niggemann...

    Open Energy Info (EERE)

    Well Log Data At Blue Mountain Geothermal Area (Fairbank & Niggemann, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Well Log Data At Blue...

  8. Leading the Charge: Jana Ganion Advances Blue Lake Rancheria...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Leading the Charge: Jana Ganion Advances Blue Lake Rancheria's Climate Action Agenda Leading the Charge: Jana Ganion Advances Blue Lake Rancheria's Climate Action Agenda February...

  9. EA-1746: Blue Mountain Geothermal Development Project, Humboldt...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    46: Blue Mountain Geothermal Development Project, Humboldt & Pershing County, NV EA-1746: Blue Mountain Geothermal Development Project, Humboldt & Pershing County, NV December 3,...

  10. UV resonance Raman analysis of trishomocubane and diamondoid dimers

    SciTech Connect (OSTI)

    Meinke, Reinhard Thomsen, Christian; Maultzsch, Janina; Richter, Robert; Merli, Andrea; Fokin, Andrey A.; Department of Organic Chemistry, Kiev Polytechnic Institute, pr. Pobedy 37, 03056 Kiev ; Koso, Tetyana V.; Schreiner, Peter R.; Rodionov, Vladimir N.

    2014-01-21

    We present resonance Raman measurements of crystalline trishomocubane and diamantane dimers containing a C=C double bond. Raman spectra were recorded with excitation energies between 2.33 eV and 5.42 eV. The strongest enhancement is observed for the C=C stretch vibration and a bending mode involving the two carbon atoms of the C=C bond, corresponding to the B{sub 2g} wagging mode of ethylene. This is associated with the localization of the ?-HOMO and LUMO and the elongation of the C=C bond length and a pyramidalization of the two sp{sup 2}-hybridized carbon atoms at the optical excitation. The observed Raman resonance energies of the trishomocubane and diamantane dimers are significantly lower than the HOMO-LUMO gaps of the corresponding unmodified diamondoids.

  11. Binding Energies in Benzene Dimers: Nonlocal Density Functional Calculations

    E-Print Network [OSTI]

    Aaron Puzder; Maxime Dion; David C. Langreth

    2005-09-15

    The interaction energy and minimum energy structure for different geometries of the benzene dimer has been calculated using the recently developed nonlocal correlation energy functional for calculating dispersion interactions. The comparison of this straightforward and relatively quick density functional based method with recent calculations can elucidate how the former, quicker method might be exploited in larger more complicated biological, organic, aromatic, and even infinite systems such as molecules physisorbed on surfaces, and van der Waals crystals.

  12. On the structure of the Nx phase of symmetric dimers

    E-Print Network [OSTI]

    Anke Hoffmann; Alexandros G. Vanakaras; Alexandra Kohlmeier; Georg H. Mehl; Demetri J. Photinos

    2014-07-07

    NMR measurements on a selectively deuteriated liquid crystal dimer CB-C9-CB exhibiting two nematic phases show that the molecules in the lower temperature nematic phase, Nx, experience a chiral environment and are ordered about a unique direction. The results are contrasted with previous reports that proposed a twist-bend spatial variation of the director. A structural model is proposed wherein the molecules show organization into highly correlated assemblies of opposite chirality.

  13. Mercury dimer spectroscopy and an Einstein-Podolsky-Rosen experiment 

    E-Print Network [OSTI]

    Qu, Xinmei

    2009-05-15

    SPECTROSCOPY AND AN EINSTEIN-PODOLSKY-ROSEN EXPERIMENT A Dissertation by XINMEI QU Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY... August 2008 Major Subject: Physics MERCURY DIMER SPECTROSCOPY AND AN EINSTEIN-PODOLSKY-ROSEN EXPERIMENT A Dissertation by XINMEI QU Submitted to the Office of Graduate Studies of Texas A&M University in partial...

  14. Dimer Models, Integrable Systems and Quantum Teichmuller Space

    E-Print Network [OSTI]

    Sebastian Franco

    2011-07-05

    We introduce a correspondence between dimer models (and hence superconformal quivers) and the quantum Teichmuller space of the Riemann surfaces associated to them by mirror symmetry. Via the untwisting map, every brane tiling gives rise to a tiling of the Riemann surface with faces surrounding punctures. We explain how to obtain an ideal triangulation by dualizing this tiling. In order to do so, tiling nodes of valence greater than 3 (equivalently superpotential terms of order greater than 3 in the corresponding quiver gauge theories) must be decomposed by the introduction of 2-valent nodes. From a quiver gauge theory perspective, this operation corresponds to integrating-in massive fields. Fock coordinates in Teichmuller space are in one-to-one correspondence with chiral fields in the quiver. We present multiple explicit examples, including infinite families of theories, illustrating how the right number of Fock coordinates is generated by this procedure. Finally, we explain how Chekhov and Fock commutation relations between coordinates give rise to the commutators associated to dimer models by Goncharov and Kenyon in the context of quantum integrable systems. For generic dimer models (i.e. those containing nodes that are not 3-valent), this matching requires the introduction of a natural generalization of Chekhov and Fock rules. We also explain how urban renewal in the original brane tiling (Seiberg duality for the quivers) is mapped to flips of the ideal triangulation.

  15. Benchmark calculations for elastic fermion-dimer scattering

    E-Print Network [OSTI]

    Shahin Bour; H. -W. Hammer; Dean Lee; Ulf-G. Meißner

    2012-06-08

    We present continuum and lattice calculations for elastic scattering between a fermion and a bound dimer in the shallow binding limit. For the continuum calculation we use the Skorniakov-Ter-Martirosian (STM) integral equation to determine the scattering length and effective range parameter to high precision. For the lattice calculation we use the finite-volume method of L\\"uscher. We take into account topological finite-volume corrections to the dimer binding energy which depend on the momentum of the dimer. After subtracting these effects, we find from the lattice calculation kappa a_fd = 1.174(9) and kappa r_fd = -0.029(13). These results agree well with the continuum values kappa a_fd = 1.17907(1) and kappa r_fd = -0.0383(3) obtained from the STM equation. We discuss applications to cold atomic Fermi gases, deuteron-neutron scattering in the spin-quartet channel, and lattice calculations of scattering for nuclei and hadronic molecules at finite volume.

  16. Polar Chemoreceptor Clustering by Coupled Trimers of Dimers

    E-Print Network [OSTI]

    Robert G. Endres

    2009-06-11

    Receptors of bacterial chemotaxis form clusters at the cell poles, where clusters act as "antennas" to amplify small changes in ligand concentration. Interestingly, chemoreceptors cluster at multiple length scales. At the smallest scale, receptors form dimers, which assemble into stable timers of dimers. At a large scale, trimers form large polar clusters composed of thousands of receptors. Although much is known about the signaling properties emerging from receptor clusters, it is unknown how receptors localize at the cell poles and what the cluster-size determining factors are. Here, we present a model of polar receptor clustering based on coupled trimers of dimers, where cluster size is determined as a minimum of the cluster-membrane free energy. This energy has contributions from the cluster-membrane elastic energy, penalizing large clusters due to their high intrinsic curvature, and receptor-receptor coupling favoring large clusters. We find that the reduced cluster-membrane curvature mismatch at the curved cell poles leads to large and robust polar clusters in line with experimental observation, while lateral clusters are efficiently suppressed.

  17. Heparin sensing: Blue-chip binding

    E-Print Network [OSTI]

    Shriver, Zachary H.

    Heparin is an anionic polysaccharide that has tremendous clinical importance as an anticoagulant. Several dyes have been developed that can detect heparin, and the latest example — named Mallard Blue — has now been shown ...

  18. Elementary Theorems Regarding Blue Isocurvature Perturbations

    E-Print Network [OSTI]

    Daniel J. H. Chung; Hojin Yoo

    2015-01-23

    Blue CDM-photon isocurvature perturbations are attractive in terms of observability and may be typical from the perspective of generic mass relations in supergravity. We present and apply three theorems useful for blue isocurvature perturbations arising from linear spectator scalar fields. In the process, we give a more precise formula for the blue spectrum associated with the axion model of 0904.3800, which can in a parametric corner give a factor of O(10) correction. We explain how a conserved current associated with Peccei-Quinn symmetry plays a crucial role and explicitly plot several example spectra including the breaks in the spectra. We also resolve a little puzzle arising from a naive multiplication of isocurvature expression that sheds light on the gravitational imprint of the adiabatic perturbations on the fields responsible for blue isocurvature fluctuations.

  19. Blue Ribbon Commission Tour of Hanford Site

    ScienceCinema (OSTI)

    Paul Saueressig

    2010-09-01

    The Blue Ribbon Commission on America's Nuclear Future toured the Department of Energy's Hanford Site on July 14, 2010. Commission members, invited guests, and members of the public visited facilities that store high-level, radioactive waste.

  20. Geothermal Technologies Program Blue Ribbon Panel Recommendations

    Broader source: Energy.gov [DOE]

    This report describes the recommendations of the Geothermal Blue Ribbon Panel, a panel of geothermal experts assembled in March 2011 for a discussion on the future of geothermal energy in the U.S.

  1. The California Economy: Singing the Housing Blues

    E-Print Network [OSTI]

    Thornberg, Christopher

    2007-01-01

    THE CALIFORNIA ECONOMY: SINGING THE HOUSING  BLUES Many  parts  of  the  economy  are  doing  better  than towards 2007 the entire economy is being threatened by the 

  2. A Clock Reaction Based on Molybdenum Blue

    E-Print Network [OSTI]

    Neuenschwander, Ulrich

    Clock reactions are rare kinetic phenomena, so far limited mostly to systems with ionic oxoacids and oxoanions in water. We report a new clock reaction in cyclohexanol that forms molybdenum blue from a noncharged, yellow ...

  3. Blue Ribbon Commission Tour of Hanford Site

    SciTech Connect (OSTI)

    Paul Saueressig

    2010-07-14

    The Blue Ribbon Commission on America's Nuclear Future toured the Department of Energy's Hanford Site on July 14, 2010. Commission members, invited guests, and members of the public visited facilities that store high-level, radioactive waste.

  4. BLUE VIEW VISION INSIGHT! Good news--your vision plan

    E-Print Network [OSTI]

    Mease, Kenneth D.

    WELCOME TO BLUE VIEW VISION INSIGHT! Good news--your vision plan is flexible and easy to use, your discounts, and much more! Blue View VisionSM Insight University of California Student Health Insurance Plan (UC SHIP) 2014/15 Your Blue View Vision Insight network Blue View Vision Insight offers you

  5. Petascale Debugging via Allinea DDT for IBM Blue Gene /P

    E-Print Network [OSTI]

    Kemner, Ken

    Petascale Debugging via Allinea DDT for IBM Blue Gene /P and IBM Blue Gene /Q Ian Lumb petascaling Allinea DDT Petascaling Allinea DDT for IBM Blue Gene /x Getting Started with Allinea DDT #12 for each core ­ No tree to help here: not fast within one I/O node! ­ The bottleneck of IBM Blue Gene /P

  6. BLUE VIEW VISION INSIGHT! Good news--your vision plan

    E-Print Network [OSTI]

    Barrett, Jeffrey A.

    WELCOME TO BLUE VIEW VISION INSIGHT! Good news--your vision plan is flexible and easy to use, your discounts, and much more! Blue View Vision InsightSM University of California Student Health Insurance Plan (UC SHIP) 2012/13 Your Blue View Vision Insight Network Blue View Vision Insight offers you

  7. Blue Choice New EnglandSM Summary of Benefits

    E-Print Network [OSTI]

    Aalberts, Daniel P.

    Blue Choice New EnglandSM Summary of Benefits Williams College An Association of Independent Blue Cross and Blue Shield Plans This health plan meets Minimum Creditable Coverage Standards Reform Law. #12;Your Care Your Primary Care Provider. When you enroll in Blue Choice New England, you

  8. BLUE VIEW VISION INSIGHT! Good news--your vision plan

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    WELCOME TO BLUE VIEW VISION INSIGHT! Good news--your vision plan is flexible and easy to use, your discounts, and much more! Blue View Vision InsightSM University of California Student Health Insurance Plan (UC SHIP) 2013/14 Your Blue View Vision Insight Network Blue View Vision Insight offers you

  9. Calculation of the Dimer Equilibrium Constant of Heavy Water Saturated Vapor

    E-Print Network [OSTI]

    L. A. Bulavin; S. V. Khrapatiy; V. N. Makhlaichuk

    2015-03-13

    Water is the most common substance on Earth.The discovery of heavy water and its further study have shown that the change of hydrogen for deuterium leads to the significant differences in their properties.The triple point temperature of heavy water is higher,at the same time the critical temperature is lower.Experimental values of the second virial coefficient of the EOS for the vapor of normal and heavy water differ at all temperatures.This fact can influence the values of the dimerization constant for the heavy water vapor.The equilibrium properties of the dimerization process are described with the methods of chemical thermodynamics.The chemical potentials for monomers (m) and dimers (d)are the functions of their concentrations.The interactions of monomer-dimer and dimer-dimer types are taken into account within the solution of equation for chemical potentials.The obtained expression for the dimerization constant contains the contributions of these types.The averaged potentials are modeled by the Sutherland potential.Theoretical values of the dimerization constant for the heavy water vapor at different temperatures are compared to those for normal water.We see the exceeding of the values for the heavy water at all temperatures.This fact is in good agreement with all experimental data that is available.The excess is related to the differences in the character of the heat excitations of the dimers of normal and heavy water,their rotational constants and energy of their vibrational excitations.Significant role is also played by the monomer-dimer and dimer-dimer interactions.

  10. Blue crabs are a valuable economic species in Biscayne Bay. The blue crabs Latin name translates as

    E-Print Network [OSTI]

    Blue crabs are a valuable economic species in Biscayne Bay. The blue crabs Latin name translates as beautiful swimmer that is savory. They are from the Phylum Arthropoda (animals with jointed legs). Blue. Blue crabs can walk very quickly across the ocean floor. The females have been known to swim 500 miles

  11. The Arabidopsis blue light receptor cryptochrome 2 is a nuclear protein regulated by a blue light-dependent post-

    E-Print Network [OSTI]

    Lin, Chentao

    The Arabidopsis blue light receptor cryptochrome 2 is a nuclear protein regulated by a blue light Charles E. Young Dr. South, Los Angeles, CA 90095-1606, USA Summary Cryptochrome 2 is a ¯avin-type blue light receptor mediating ¯oral induction in response to photoperiod and a blue light-induced hypocotyl

  12. An Association of Independent Blue Cross and Blue Shield Plans This health plan meets Minimum Creditable Coverage Standards for

    E-Print Network [OSTI]

    Aalberts, Daniel P.

    An Association of Independent Blue Cross and Blue Shield Plans This health plan meets Minimum, as part of the Massachusetts Health Care Reform Law. HMO Blue New EnglandSM Summary of Benefits Williams College #12;Your Care Your Primary Care Provider. When you enroll in HMO Blue New England, you must choose

  13. Radiation-induced tetramer-to-dimer transition of Escherichia coli lactose repressor

    SciTech Connect (OSTI)

    Goffinont, S. [Centre de Biophysique Moleculaire, CNRS, rue C. Sadron, 45071 Orleans (France)] [Centre de Biophysique Moleculaire, CNRS, rue C. Sadron, 45071 Orleans (France); Davidkova, M. [Department of Radiation Dosimetry, Nuclear Physics Institute AS CR, Na Truhlarce 39/64, 18086, Prague 8 (Czech Republic)] [Department of Radiation Dosimetry, Nuclear Physics Institute AS CR, Na Truhlarce 39/64, 18086, Prague 8 (Czech Republic); Spotheim-Maurizot, M., E-mail: spotheim@cnrs-orleans.fr [Centre de Biophysique Moleculaire, CNRS, rue C. Sadron, 45071 Orleans (France)

    2009-08-21

    The wild type lactose repressor of Escherichia coli is a tetrameric protein formed by two identical dimers. They are associated via a C-terminal 4-helix bundle (called tetramerization domain) whose stability is ensured by the interaction of leucine zipper motifs. Upon in vitro {gamma}-irradiation the repressor losses its ability to bind the operator DNA sequence due to damage of its DNA-binding domains. Using an engineered dimeric repressor for comparison, we show here that irradiation induces also the change of repressor oligomerisation state from tetramer to dimer. The splitting of the tetramer into dimers can result from the oxidation of the leucine residues of the tetramerization domain.

  14. GREEN BLUE CITY Visions of Green-Blue Infrastructure in the Salt Lake Valley

    E-Print Network [OSTI]

    Capecchi, Mario R.

    GREEN BLUE CITY Visions of Green-Blue Infrastructure in the Salt Lake Valley Memorial House, Memory will focus on the natural systems of land and water that support and enhance the economy, ecology and quality:55 SARAH HINNERS Ecological Planning Center 2:20 Break 2:35 JEFF NIERMEYER Salt Lake City Public Utilities

  15. Colorado Supplement to the Summary of Benefits and Coverage Form Anthem Blue Cross and Blue Shield

    E-Print Network [OSTI]

    Supplement to the Summary of Benefits and Coverage Form Anthem Blue Cross and Blue Shield CHEIBA HMO/POS Plan-of-network care 3. Areas of Colorado where plan is available Plan is available throughout Colorado SUPPLEMENTAL information meant to supplement the Summary of Benefits of Coverage you have received for this plan. This plan

  16. Colorado Supplement to the Summary of Benefits and Coverage Form Anthem Blue Cross and Blue Shield

    E-Print Network [OSTI]

    Supplement to the Summary of Benefits and Coverage Form Anthem Blue Cross and Blue Shield CHEIBA Custom Plus where plan is available Plan is available throughout Colorado SUPPLEMENTAL INFORMATION REGARDING to supplement the Summary of Benefits of Coverage you have received for this plan. This plan may exclude

  17. Colorado Supplement to the Summary of Benefits and Coverage Form Anthem Blue Cross and Blue Shield

    E-Print Network [OSTI]

    Supplement to the Summary of Benefits and Coverage Form Anthem Blue Cross and Blue Shield CHEIBA Prime PPO of Colorado where plan is available Plan is available throughout Colorado SUPPLEMENTAL INFORMATION REGARDING to supplement the Summary of Benefits of Coverage you have received for this plan. This plan may exclude

  18. Enhanced Dimer Relaxation in an Atomic/Molecular BEC

    E-Print Network [OSTI]

    Eric Braaten; H. -W. Hammer

    2004-08-02

    We derive a universal formula for the rate constant \\beta for relaxation of a shallow dimer into deeply-bound diatomic molecules in the case of atoms with a large scattering length a. We show that \\beta is determined by a and by two 3-body parameters that also determine the binding energies and widths of Efimov states. The rate constant \\beta scales like \\hbar a/m near the resonance, but the coefficient is a periodic function of ln(a) that may have resonant enhancement at values of a that differ by multiples of 22.7.

  19. Jamming probabilities for a vacancy in the dimer model

    E-Print Network [OSTI]

    V. S. Poghosyan; V. B. Priezzhev; P. Ruelle

    2008-01-28

    Following the recent proposal made by Bouttier et al [Phys. Rev. E 76, 041140 (2007)], we study analytically the mobility properties of a single vacancy in the close-packed dimer model on the square lattice. Using the spanning web representation, we find determinantal expressions for various observable quantities. In the limiting case of large lattices, they can be reduced to the calculation of Toeplitz determinants and minors thereof. The probability for the vacancy to be strictly jammed and other diffusion characteristics are computed exactly.

  20. Multiple-charge transfer and trapping in DNA dimers

    E-Print Network [OSTI]

    Tornow, Sabine; Anders, Frithjof B; Zwicknagl, Gertrud

    2010-01-01

    We investigate the charge transfer characteristics of one and two excess charges in a DNA base-pair dimer using a model Hamiltonian approach. The electron part comprises diagonal and off-diagonal Coulomb matrix elements such a correlated hopping and the bond-bond interaction, which were recently calculated by Starikov [E. B. Starikov, Phil. Mag. Lett. {\\bf 83}, 699 (2003)] for different DNA dimers. The electronic degrees of freedom are coupled to an ohmic or a super-ohmic bath serving as dissipative environment. We employ the numerical renormalization group method in the nuclear tunneling regime and compare the results to Marcus theory for the thermal activation regime. For realistic parameters, the rate that at least one charge is transferred from the donor to the acceptor in the subspace of two excess electrons significantly exceeds the rate in the single charge sector. Moreover, the dynamics is strongly influenced by the Coulomb matrix elements. We find sequential and pair transfer as well as a regime wher...

  1. Ionization satellites of the ArHe dimer

    SciTech Connect (OSTI)

    Miteva, Tsveta; Klaiman, Shachar; Gokhberg, Kirill [Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg (Germany); Gromov, Evgeniy V., E-mail: Evgeniy.Gromov@pci.uni-heidelberg.de [Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg (Germany); Laboratory of Quantum Chemistry, Computer Center, Irkutsk State University, K. Marks 1, 664003 Irkutsk (Russian Federation)

    2014-05-28

    Ionization satellites are key ingredients in the control of post ionization processes such as molecular dissociation and interatomic Coulombic decay. Here, using the high-level ab initio method of multi-reference configuration interaction up to triple excitations, we study the potential energy curves (PECs) of the ionization satellites of the ArHe dimer. With this model system, we demonstrate that the simple model used in alkaline earth metal and rare gas complexes to describe the satellites as a Rydberg electron moving on top of a dicationic core does not fully hold for the rare gas clusters. The more complex valence structure in the rare gas atom leads to the mixing of different electronic configurations of the dimer. This prevents one from assigning a single dicationic parent state to some of the ionization satellites. We further analyze the structure of the different PECs, demonstrating how the density of the Rydberg electron is reflected in the structure of the PEC wherever the simple model is applicable.

  2. Structures and Properties of Zirconia-Supported Ruthenium Oxide Catalysts for the Selective Oxidation of Methanol to Methyl Formate

    E-Print Network [OSTI]

    Iglesia, Enrique

    Structures and Properties of Zirconia-Supported Ruthenium Oxide Catalysts for the Selective Species, College of Chemistry and Molecular Engineering, Green Chemistry Center, Peking UniVersity, Beijing 100871, China, and Department of Chemical Engineering, UniVersity of California at Berkeley

  3. Bistable defect structures in blue phase devices

    E-Print Network [OSTI]

    A. Tiribocchi; G. Gonnella; D. Marenduzzo; E. Orlandini; F. Salvadore

    2011-10-28

    Blue phases (BPs) are liquid crystals made up by networks of defects, or disclination lines. While existing phase diagrams show a striking variety of competing metastable topologies for these networks, very little is known as to how to kinetically reach a target structure, or how to switch from one to the other, which is of paramount importance for devices. We theoretically identify two confined blue phase I systems in which by applying an appropriate series of electric field it is possible to select one of two bistable defect patterns. Our results may be used to realise new generation and fast switching energy-saving bistable devices in ultrathin surface treated BPI wafers.

  4. Blue Ribbon Commission on America's Nuclear Future

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download originalBlue

  5. Blue Mountain Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois: EnergyHills, Connecticut: EnergyMotionBlueBlue

  6. If you have a Blue Cross Blue Shield of Massachusetts health plan, we've got a healthy incentive for you.

    E-Print Network [OSTI]

    Stoiciu, Mihai

    If you have a Blue Cross Blue Shield of Massachusetts health plan, we've got a healthy incentive for you. As a subscriber to Blue Cross Blue Shield of Massachusetts, your Weight Loss Benefit can save you the qualified program in which you enroll. Receipts must show the Blue Cross Blue Shield of Massachusetts member

  7. If you have a Blue Cross Blue Shield of Massachusetts health plan, we've got a healthy incentive for you.

    E-Print Network [OSTI]

    Stoiciu, Mihai

    If you have a Blue Cross Blue Shield of Massachusetts health plan, we've got a healthy incentive for you. As a Blue Cross Blue Shield of Massachusetts subscriber your Fitness Benefit can save you or your Benefit after you've belonged to your health club and been a Blue Cross Blue Shield of Massachusetts

  8. Proton transfer in adsorbed water dimers Xiao Liang Hu, Jir i Klimes and Angelos Michaelides*

    E-Print Network [OSTI]

    Alavi, Ali

    Proton transfer in adsorbed water dimers Xiao Liang Hu, Jir i´ Klimes and Angelos Michaelides) reveal rapid proton transfer within clusters of just two water molecules. Facile dissociation and recombination of the molecules within the dimers along with a concerted surface-mediated exchange of protons

  9. Protonated Water Dimer on Benzene: Standing Eigen or Crouching Huan Wang and Noam Agmon*

    E-Print Network [OSTI]

    Agmon, Noam

    Protonated Water Dimer on Benzene: Standing Eigen or Crouching Zundel? Huan Wang and Noam Agmon to a neutral benzene molecule are a reductionist model for protons at hydrophobic surfaces, which water dimer ("Zundel ion") on benzene, whose gas-phase messenger IR spectrum has been previously

  10. Giant Helium Dimers Produced by Photoassociation of Ultracold Metastable Atoms J. Leonard,* M. Walhout,

    E-Print Network [OSTI]

    Cohen-Tannoudj, Claude

    Giant Helium Dimers Produced by Photoassociation of Ultracold Metastable Atoms J. Le´onard,* M long-range helium dimers by photoassociation of metastable helium atoms in a magnetically trapped ion production rates, which are usually high for He , we measure the tempera- ture increase

  11. Intramolecular Energy Transfer within Butadiyne-Linked Chlorophyll and Porphyrin Dimer-Faced, Self-Assembled

    E-Print Network [OSTI]

    photosynthesis and solar cell applications. Introduction Photofunctional materials for use in organic-Northwestern Solar Energy Research (ANSER) Center, Northwestern UniVersity, EVanston, Illinois 60208-3113, Chemistry axes of the dimers. These transitions greatly increase the ability of these dimers to absorb the solar

  12. Curved EFC/F-BAR-Domain Dimers Are Joined End to End into a Filament for

    E-Print Network [OSTI]

    Zhijie, Liu

    Curved EFC/F-BAR-Domain Dimers Are Joined End to End into a Filament for Membrane Invagination a gently curved helical-bundle dimer of $220 A° in length, which forms filaments through end that impaired filament formation also impaired membrane tubulation and cell membrane invagination. Furthermore

  13. Getting in Sync with Dimeric Eg5 INITIATION AND REGULATION OF THE PROCESSIVE RUN*S

    E-Print Network [OSTI]

    Grabe, Michael

    Getting in Sync with Dimeric Eg5 INITIATION AND REGULATION OF THE PROCESSIVE RUN*S Received the Department of Biological Sciences, University of Pittsburgh, Pittsburgh, Pennsylvania 15260 Eg5/KSP assembly and dynamics. Recent work using a dimeric form of Eg5 has found it to be a processive motor

  14. Chemical equilibrium in supercritical fluids: Solvent effects on the dimerization equilibrium constant

    E-Print Network [OSTI]

    Rabani, Eran

    supercritical sol- vents CO2 , CHF3 , CClF3 , Ar, and Xe across the whole solvent density range, from gasChemical equilibrium in supercritical fluids: Solvent effects on the dimerization equilibrium; accepted 27 February 2002 We study dimerization equilibrium between two dilute solutes in a supercritical

  15. Higher Energy States in the CO Dimer: Millimeter-Wave Spectra and Rovibrational Calculations

    E-Print Network [OSTI]

    Higher Energy States in the CO Dimer: Millimeter-Wave Spectra and Rovibrational Calculations Leonid millimeter-wave data yielded the precise location of 33 new energy levels of A+ symmetry and 20 levels of A extensive millimeter-wave measurements of the 12C16O dimer have been made, and more than 300 new spectral

  16. Coherent low-frequency motions of hydrogen bonded acetic acid dimers in the liquid phase

    E-Print Network [OSTI]

    Mukamel, Shaul

    of 1­2 ps. Calculations of the vibrational potential energy surface based on density functional theoryCoherent low-frequency motions of hydrogen bonded acetic acid dimers in the liquid phase Karsten; accepted 22 April 2004 Ultrafast vibrational dynamics of cyclic hydrogen bonded dimers and the underlying

  17. Effects of Ar plasma treatment for deposition of ruthenium film by remote plasma atomic layer deposition

    SciTech Connect (OSTI)

    Park, Taeyong; Lee, Jaesang; Park, Jingyu; Jeon, Heeyoung; Jeon, Hyeongtag; Lee, Ki-Hoon; Cho, Byung-Chul; Kim, Moo-Sung; Ahn, Heui-Bok

    2012-01-15

    Ruthenium thin films were deposited on argon plasma-treated SiO{sub 2} and untreated SiO{sub 2} substrates by remote plasma atomic layer deposition using bis(ethylcyclopentadienyl)ruthenium [Ru(EtCp){sub 2}] as a Ru precursor and ammonia plasma as a reactant. The results of in situ Auger electron spectroscopy (AES) analysis indicate that the initial transient region of Ru deposition was decreased by Ar plasma treatment at 400 deg. C, but did not change significantly at 300 deg. C The deposition rate exhibited linearity after continuous film formation and the deposition rates were about 1.7 A/cycle and 0.4 A/cycle at 400 deg. C and 300 deg. C, respectively. Changes of surface energy and polar and dispersive components were measured by the sessile drop test. The quantity of surface amine groups was measured from the surface nitrogen concentration with AES. Furthermore, the Ar plasma-treated SiO{sub 2} contained more amine groups and less hydroxyl groups on the surface than on untreated SiO{sub 2}. Auger spectra exhibited chemical shifts by Ru-O bonding, and larger shifts were observed on untreated substrates due to the strong adhesion of Ru films.

  18. Behavioral context of call production by eastern North Pacific blue whales

    E-Print Network [OSTI]

    Oleson, Erin M; Calambokidis, J; Burgess, W C; McDonald, M A; LeDuc, C A; Hildebrand, J A

    2007-01-01

    by eastern North Pacific blue whales Erin M. Oleson 1, *,context of calls produced by blue whales Balaenoptera mus-North Pacific population of blue whales (Thompson 1965,

  19. Homogeneous blue pattern: A rare presentation in an acral congenital melanocytic nevus

    E-Print Network [OSTI]

    2010-01-01

    Malvehy J. Homogeneous blue pattern in an acral congenitalof a plantar combined blue nevus: a simulator of melanoma.Homogeneous blue pattern: A rare presentation in an acral

  20. Red-white and blue baby: a case of phacomatosis pigmentovascularis type V

    E-Print Network [OSTI]

    Byrom, Lisa; Surjana, Devita; Yoong, Corinne; Zappala, Tania

    2015-01-01

    vignette Red-white and blue baby: a case of phacomatosisextensive greyish-blue patches (dermal melanocytosis)addition, marble-like reddish- blue patches consistent with

  1. Numerical Results for the Blue Phases

    E-Print Network [OSTI]

    G. P. Alexander; J. M. Yeomans

    2009-06-04

    We review recent numerical work investigating the equilibrium phase diagram, and the dynamics, of the cholesteric blue phases. In equilibrium numerical results confirm the predictions of the classic analytical theories, and extend them to incorporate different values of the elastic constants, or the effects of an applied electric field. There is a striking increase in the stability of blue phase I in systems where the cholesteric undergoes helical sense inversion, and the anomalous electrostriction observed in this phase is reproduced. Solving the equations of motion allows us to present results for the phase transition kinetics of blue phase I under dielectric or flexoelectric coupling to an applied electric field. We also present simulations of the blue phases in a flow field, showing how the disclination network acts to oppose the flow. The results are based on the Landau-de Gennes exapnsion of the liquid crystal free energy: that such a simple and elegant theory can predict such complex and subtle physical behaviour is remarkable.

  2. Switching dynamics in cholesteric blue phases

    E-Print Network [OSTI]

    A. Tiribocchi; G. Gonnella; D. Marenduzzo; E. Orlandini

    2011-03-30

    Blue phases are networks of disclination lines, which occur in cholesteric liquid crystals near the transition to the isotropic phase. They have recently been used for the new generation of fast switching liquid crystal displays. Here we study numerically the steady states and switching hydrodynamics of blue phase I (BPI) and blue phase II (BPII) cells subjected to an electric field. When the field is on, there are three regimes: for very weak fields (and strong anchoring at the boundaries) the blue phases are almost unaffected, for intermediate fields the disclinations twist (for BPI) and unzip (for BPII), whereas for very large voltages the network dissolves in the bulk of the cell. Interestingly, we find that a BPII cell can recover its original structure when the field is switched off, whereas a BPI cell is found to be trapped more easily into metastable configurations. The kinetic pathways followed during switching on and off entails dramatic reorganisation of the disclination networks. We also discuss the effect of changing the director field anchoring at the boundary planes and of varying the direction of the applied field.

  3. Exploring ruthenium dye synthesis and TiO2-dye-I-/I3- electron transfer reactions in a dye-sensitised solar cell. 

    E-Print Network [OSTI]

    Chadwick, Nina

    2013-11-28

    Octahedral, six co-ordinate ruthenium complexes containing acid substituted polypyridyl ligands have proved particularly successful as dyes for Dye-Sensitised Solar Cells (DSSCs); thus there have been hundreds, if not ...

  4. Charge localization and JahnTeller distortions in the benzene dimer cation Piotr A. Pieniazek, Stephen E. Bradforth,a

    E-Print Network [OSTI]

    Krylov, Anna I.

    Charge localization and Jahn­Teller distortions in the benzene dimer cation Piotr A. Pieniazek August 2008 Jahn­Teller JT distortions and charge localization in the benzene dimer cation are analyzed.1063/1.2969107 I. INTRODUCTION The benzene dimer cation is an important model system for radiation

  5. WHEN THE BLUE-GREEN WATERS TURN RED

    E-Print Network [OSTI]

    WHEN THE BLUE-GREEN WATERS TURN RED Historical Flooding in Havasu Creek, Arizona U.S. GEOLOGICAL OF RECLAMATION #12;WHEN THE BLUE-GREEN WATERS TURN RED Historical Flooding in Havasu Creek, Arizona By THEODORE S

  6. A Preliminary Structural Model for the Blue Mountain Geothermal...

    Open Energy Info (EERE)

    thewest flanks of Blue Mountain and the Eugene Mountains, and amore local WNW-striking, SW-dipping normal-dextral fault onthe southwest side of Blue Mountain. The WNW-striking...

  7. Nonlocal fluctuations and control of dimer entanglement dynamics

    SciTech Connect (OSTI)

    Susa, Cristian E.; Reina, John H.

    2010-10-15

    We report on the dissipative dynamics of an entangled, bipartite interacting system. We show how to induce and control the so-called early-stage disentanglement (and 'delayed' entanglement generation) dynamics by means of a driving laser field. We demonstrate that some of the features currently associated with pure non-Markovian effects in such entanglement behavior can actually take place in Markovian environments if background-noise quantum electrodynamics fluctuations are considered. We illustrate this for the case of a dimer interacting molecular system for which emission rates, interaction strength, and radiative corrections have been previously measured. We also show that even in the absence of collective decay mechanisms and qubit-qubit interactions, the entanglement still exhibits collapse-revival behavior. Our results indicate that zero-point energy fluctuations should be taken into account when formulating precise entanglement dynamics statements.

  8. Restricted Dislocation Motion in Crystals of Colloidal Dimer Particles

    E-Print Network [OSTI]

    Sharon J. Gerbode; Stephanie H. Lee; Chekesha M. Liddell; Itai Cohen

    2008-11-07

    At high area fractions, monolayers of colloidal dimer particles form a degenerate crystal (DC) structure in which the particle lobes occupy triangular lattice sites while the particles are oriented randomly along any of the three lattice directions. We report that dislocation glide in DCs is blocked by certain particle orientations. The mean number of lattice constants between such obstacles is 4.6 +/- 0.2 in experimentally observed DC grains and 6.18 +/- 0.01 in simulated monocrystalline DCs. Dislocation propagation beyond these obstacles is observed to proceed through dislocation reactions. We estimate that the energetic cost of dislocation pair separation via such reactions in an otherwise defect free DC grows linearly with final separation, hinting that the material properties of DCs may be dramatically different from those of 2-D crystals of spheres.

  9. Aeromagnetic Survey At Blue Mountain Geothermal Area (Fairbank...

    Open Energy Info (EERE)

    Aeromagnetic Survey At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  10. Exploratory Boreholes At Blue Mountain Geothermal Area (Parr...

    Open Energy Info (EERE)

    Exploratory Boreholes At Blue Mountain Geothermal Area (Parr & Percival, 1991) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Exploratory...

  11. Blue oak seedlings may be older than they look

    E-Print Network [OSTI]

    Blue oak seedlings may be older than they look Ralph L. Phillips u Neil K. McDougald o Richard B. Standiford William E.Frost A 4-year study indicates that na- tive blue oak seedlings are prob- ably much the year of above- average rainfall. Blue oak (Quercusdouglasii)trees are a valuable economic and aesthetic

  12. Fast Adaptive Blue Noise on Polygonal Surfaces Esdras Medeirosa,

    E-Print Network [OSTI]

    Díaz, Lorenzo J.

    Fast Adaptive Blue Noise on Polygonal Surfaces Esdras Medeirosa, , Lis Ingridb , Sin´esio Pescob with blue noise characteristics, temporal-coherence and real-time computation. Classical algorithms produce preserving the good blue noise properties. We present applications on Non Photo Realistic rendering (NPR

  13. Stochastic Fair Blue: A Queue Management Algorithm for Enforcing Fairness

    E-Print Network [OSTI]

    Stochastic Fair Blue: A Queue Management Algorithm for Enforcing Fairness Wu-chang Feng Dilip D of a marking probability derived from the BLUE queue management algorithm and a Bloom filter. Using analysis of responsive flows. This paper describes and evaluates Stochastic Fair BLUE (SFB), a novel technique

  14. Blue Solid-State Photoluminescence and Electroluminescence from Novel

    E-Print Network [OSTI]

    Myrick, Michael Lenn

    Blue Solid-State Photoluminescence and Electroluminescence from Novel Poly copolymers give rise to efficient ( ) 0.16-0.76) blue solid-state emission (max ) 422-443 nm) which can-PPE (max 500-520 nm). The effective and blue-shifted solid-state emission is a result of disrupting

  15. Blue whale (Balaenoptera musculus) sounds from the North Atlantic

    E-Print Network [OSTI]

    Blue whale (Balaenoptera musculus) sounds from the North Atlantic David K. Mellingera) Bioacoustics 2003 Sounds of blue whales were recorded from U.S. Navy hydrophone arrays in the North Atlantic-duration, very-low-frequency sound units repeated every 1­2 min are typical of blue whale sounds recorded

  16. Blue Moon sampling, vectorial reaction coordinates, and unbiased constrained dynamics

    E-Print Network [OSTI]

    Van Den Eijnden, Eric

    Blue Moon sampling, vectorial reaction coordinates, and unbiased constrained dynamics Giovanni force in terms of a conditional expectation which can be computed by Blue Moon sampling Introduction Fifteen years ago the Blue Moon ensemble method was introduced to sample rare events that occur

  17. BLUE: An Interactive Visualization System for Categorical Data Technical Note

    E-Print Network [OSTI]

    Kerbs, R. W.

    BLUE: An Interactive Visualization System for Categorical Data Technical Note Robert W. Kerbs. This paper introduces a prototype data visualization system, BLUE, to help induce meaningful decision trees from databases that contain primarily categorical attributes. BLUE is an interactive model creation

  18. ANCHIALINE ECOSYSTEMS Microbial hotspots in anchialine blue holes

    E-Print Network [OSTI]

    Macalady, Jenn

    ANCHIALINE ECOSYSTEMS Microbial hotspots in anchialine blue holes: initial discoveries from+Business Media B.V. 2011 Abstract Inland blue holes of the Bahamas are anchialine ecosystems with distinct fresh and geomicrobiology exploration of blue holes are providing a first glimpse of the geochemistry and microbial life

  19. Blue Crab, Callinectes sapidus, Trap Selectivity Studies: Mesh Size

    E-Print Network [OSTI]

    Blue Crab, Callinectes sapidus, Trap Selectivity Studies: Mesh Size VINCENT GUILLORY and PAUL had replaced drop nets and trot lines as the dominant gear in the commercial blue crab, Callinectes, LA 70343. ABSTRACT-Catch rates and sizes of blue crabs, Callinectes sapidus, were com pared in traps

  20. Blue Noise through Optimal Transport Fernando de Goes

    E-Print Network [OSTI]

    Desbrun, Mathieu

    Blue Noise through Optimal Transport Fernando de Goes Caltech Katherine Breeden Stanford Victor high-quality blue noise point distributions of arbitrary density functions. At its core is a novel diagrams. Our mathematical, algorithmic, and practical contributions lead to high-quality blue noise point

  1. THE BLUE SKY CATASTROPHE ON THE KLEIN BOTTLE

    E-Print Network [OSTI]

    Zhang, Meirong

    THE BLUE SKY CATASTROPHE ON THE KLEIN BOTTLE Weigu Li and Meirong Zhang Department of Mathematics orbit, the so-called blue sky catastrophe. Let's begin with the definition. Definition 1 One-parameter family of vector fields on a compact manifold has a blue sky catastrophe if for all parameter values from

  2. Alcian Blue Alizarin Red Skeletal Staining October 2003

    E-Print Network [OSTI]

    De Robertis, Eddy M.

    Alcian Blue ­ Alizarin Red Skeletal Staining October 2003 Eddy M. De Robertis 1. Dissect mice damage. 3. Replace 95% ethanol with Alcian blue staining solution for 1-3 days slowly rocking at room days. 4. Replace Alcian blue solution with 95% ethanol for 6 hours slowly rocking at room temperature

  3. Blue Lacuna: Lessons Learned Writing the World's Longest Interactive Fiction

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    1 Blue Lacuna: Lessons Learned Writing the World's Longest Interactive Fiction Aaron A. Reed Abstract--Blue Lacuna is a new long form interactive fic- tion comprising nearly 400,000 words of prose play time of fifteen to twenty hours. In development between 2006 and 2009, Blue Lacuna fea- tures

  4. Blue marlin (Makaira nigricans) are widely distributed throughout the

    E-Print Network [OSTI]

    waters of the Pacific and Indian oceans (Nakamura, 1985). In the Pacific, blue marlin are harvested data (Kleiber et al., 2003) indicate that there is a single stock of blue marlin in the Pacific Ocean- ies for the stock of blue marlin in the Pacific Ocean, there have been few published studies

  5. Calculation of the Dimer Equilibrium Constant of Heavy Water Saturated Vapor

    E-Print Network [OSTI]

    Bulavin, L A; Makhlaichuk, V N

    2015-01-01

    Water is the most common substance on Earth.The discovery of heavy water and its further study have shown that the change of hydrogen for deuterium leads to the significant differences in their properties.The triple point temperature of heavy water is higher,at the same time the critical temperature is lower.Experimental values of the second virial coefficient of the EOS for the vapor of normal and heavy water differ at all temperatures.This fact can influence the values of the dimerization constant for the heavy water vapor.The equilibrium properties of the dimerization process are described with the methods of chemical thermodynamics.The chemical potentials for monomers (m) and dimers (d)are the functions of their concentrations.The interactions of monomer-dimer and dimer-dimer types are taken into account within the solution of equation for chemical potentials.The obtained expression for the dimerization constant contains the contributions of these types.The averaged potentials are modeled by the Sutherlan...

  6. Photochemical dimerization and functionalization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and silanes

    DOE Patents [OSTI]

    Crabtree, R.H.; Brown, S.H.

    1989-10-17

    The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and primary, secondary and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.

  7. Ruthenium ion-catalyzed oxidation of Shenfu coal and its residues

    SciTech Connect (OSTI)

    Yao-Guo Huang; Zhi-Min Zong; Zi-Shuo Yao; Yu-Xuan Zheng; Jie Mou; Guang-Feng Liu; Jin-Pei Cao; Ming-Jie Ding; Ke-Ying Cai; Feng Wang; Wei Zhao; Zhi-Lin Xia; Lin Wu; Xian-Yong Wei

    2008-05-15

    Shenfu coal (SFC), its liquefaction residue (RL), and carbon disulfide (CS{sub 2})/tetrahydrofuran (THF)-inextractable matter (RE) were subject to ruthenium ion-catalyzed oxidation to understand the differences in structural features among the above three samples. The results suggest that SFC is rich in long-chain arylalkanes and {alpha}. {omega}-diarylalkanes (DAAs) with carbon number of methylene linkage from 2 to 4 and that long-chain arylalkanes and DAAs are reactive toward hydroliquefaction and soluble in a CS{sub 2}/THF mixed solvent, whereas highly condensed aromatic species in SFC show poor solubility in the CS{sub 2}/THF mixed solvent. 29 refs., 6 figs., 4 tabs.

  8. ANTHEM BLUE CROSS AND BLUE SHIELD You may select from two separate dental care plans to meet your individual needs. Premium cost

    E-Print Network [OSTI]

    - 34 - ANTHEM BLUE CROSS AND BLUE SHIELD You may select from two separate dental care plans to meet two choices are: Anthem Blue Dental PPO Plus Anthem Blue Dental PPO NOTE: Children are eligible in retirement. PERA retirement benefits are based on your highest three years of earnings. Anthem Blue Dental

  9. On the ro-vibrational energies for the lithium dimer; maximum-possible rotational levels

    E-Print Network [OSTI]

    Omar Mustafa

    2015-03-02

    The Deng-Fan potential is used to discuss the reliability of the improved Greene-Aldrich approximation and the factorization recipe of Badawi et al.'s [17] for the central attractive/repulsive core. The factorization recipe is shown to be a more reliable approximation and is used to obtain the ro-vibrational energies for the lithium dimer. For each vibrational state only a limited number of the rotational levels are found to be supported by the lithium dimer.

  10. Structure of a Rabbit Muscle Fructose-1,6-Bisphosphate Aldolase A Dimer Variant

    SciTech Connect (OSTI)

    Sherawat,M.; Tolan, D.; Allen, K.

    2008-01-01

    Fructose-1,6-bisphosphate aldolase (aldolase) is an essential enzyme in glycolysis and gluconeogenesis. In addition to this primary function, aldolase is also known to bind to a variety of other proteins, a property that may allow it to perform 'moonlighting' roles in the cell. Although monomeric and dimeric aldolases possess full catalytic activity, the enzyme occurs as an unusually stable tetramer, suggesting a possible link between the oligomeric state and these noncatalytic cellular roles. Here, the first high-resolution X-ray crystal structure of rabbit muscle D128V aldolase, a dimeric form of aldolase mimicking the clinically important D128G mutation in humans associated with hemolytic anemia, is presented. The structure of the dimer was determined to 1.7 Angstroms resolution with the product DHAP bound in the active site. The turnover of substrate to produce the product ligand demonstrates the retention of catalytic activity by the dimeric aldolase. The D128V mutation causes aldolase to lose intermolecular contacts with the neighboring subunit at one of the two interfaces of the tetramer. The tertiary structure of the dimer does not significantly differ from the structure of half of the tetramer. Analytical ultracentrifugation confirms the occurrence of the enzyme as a dimer in solution. The highly stable structure of aldolase with an independent active site is consistent with a model in which aldolase has evolved as a multimeric scaffold to perform other noncatalytic functions.

  11. Shear-response of the spectrin dimer-tetramer equilibrium in the red blood cell membrane

    SciTech Connect (OSTI)

    An, Xiuli; Lecomte, M. Christine; Chasis, Joel Anne; Mohandas, Narla; Gratzer, Walter

    2003-06-18

    The red cell membrane derives its elasticity and resistance to mechanical stresses from the membrane skeleton, a network composed of spectrin tetramers. These are formed by the head-to-head association of pairs of heterodimers attached at their ends to junctional complexes of several proteins. Here we examine the dynamics of the spectrin dimer-dimer association in the intact membrane. We show that univalent fragments of spectrin, containing the dimer self-association site, will bind to spectrin on the membrane and thereby disrupt the continuity of the protein network. This results in impairment of the mechanical stability of the membrane. When, moreover, the cells are subjected to a continuous low level of shear, even at room temperature, the incorporation of the fragments and the consequent destabilization of the membrane are greatly accentuated. It follows that a modest shearing force, well below that experienced by the red cell in the circulation, is sufficient to sever dimer-dimer links in the network. Our results imply (1) that the membrane accommodates the enormous distortions imposed on it during the passage of the cell through the micro vasculature by means of local dissociation of spectrin tetramers to dimers, (2) that the network in situ is in a dynamic state and under goes a ''breathing'' action of tetramer dissociation and re-formation.

  12. Ras-GTP dimers activate the mitogen-activated protein kinase (MAPK) pathway

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nan, Xiaolin; Tamgüney, Tanja M.; Collisson, Eric A.; Lin, Li -Jung; Pitt, Cameron; Galeas, Jacqueline; Lewis, Sophia; Gray, Joe W.; McCormick, Frank; Chu, Steven

    2015-06-16

    Rat sarcoma (Ras) GTPases regulate cell proliferation and survival through effector pathways including Raf-MAPK, and are the most frequently mutated genes in human cancer. Although it is well established that Ras activity requires binding to both GTP and the membrane, details of how Ras operates on the cell membrane to activate its effectors remain elusive. Efforts to target mutant Ras in human cancers to therapeutic benefit have also been largely unsuccessful. Here we show that Ras-GTP forms dimers to activate MAPK. We used quantitative photoactivated localization microscopy (PALM) to analyze the nanoscale spatial organization of PAmCherry1-tagged KRas 4B (hereafter referredmore »to KRas) on the cell membrane under various signaling conditions. We found that at endogenous expression levels KRas forms dimers, and KRasG12D, a mutant that constitutively binds GTP, activates MAPK. Overexpression of KRas leads to formation of higher order Ras nanoclusters. Conversely, at lower expression levels, KRasG12D is monomeric and activates MAPK only when artificially dimerized. Moreover, dimerization and signaling of KRas are both dependent on an intact CAAX (C, cysteine; A, aliphatic; X, any amino acid) motif that is also known to mediate membrane localization. These results reveal a new, dimerization-dependent signaling mechanism of Ras, and suggest Ras dimers as a potential therapeutic target in mutant Ras-driven tumors.« less

  13. Photoexcited energy transfer in a weakly coupled dimer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hernandez, Laura Alfonso; Nelson, Tammie; Tretiak, Sergei; Fernandez-Alberti, Sebastian

    2015-01-08

    Nonadiabatic excited-state molecular dynamics (NA-ESMD) simulations have been performed in order to study the time-dependent exciton localization during energy transfer between two chromophore units of the weakly coupled anthracene dimer dithia-anthracenophane (DTA). Simulations are done at both low temperature (10 K) and room temperature (300 K). The initial photoexcitation creates an exciton which is primarily localized on a single monomer unit. Subsequently, the exciton experiences an ultrafast energy transfer becoming localized on either one monomer unit or the other, whereas delocalization between both monomers never occurs. In half of the trajectories, the electronic transition density becomes completely localized on themore »same monomer as the initial excitation, while in the other half, it becomes completely localized on the opposite monomer. In this article, we present an analysis of the energy transfer dynamics and the effect of thermally induced geometry distortions on the exciton localization. Finally, simulated fluorescence anisotropy decay curves for both DTA and the monomer unit dimethyl anthracene (DMA) are compared. As a result, our analysis reveals that changes in the transition density localization caused by energy transfer between two monomers in DTA is not the only source of depolarization and exciton relaxation within a single DTA monomer unit can also cause reorientation of the transition dipole.« less

  14. MOCK OBSERVATIONS OF BLUE STRAGGLERS IN GLOBULAR CLUSTER MODELS

    SciTech Connect (OSTI)

    Sills, Alison; Glebbeek, Evert; Chatterjee, Sourav; Rasio, Frederic A. E-mail: e.glebbeek@astro.ru.nl E-mail: rasio@northwestern.edu

    2013-11-10

    We created artificial color-magnitude diagrams of Monte Carlo dynamical models of globular clusters and then used observational methods to determine the number of blue stragglers in those clusters. We compared these blue stragglers to various cluster properties, mimicking work that has been done for blue stragglers in Milky Way globular clusters to determine the dominant formation mechanism(s) of this unusual stellar population. We find that a mass-based prescription for selecting blue stragglers will select approximately twice as many blue stragglers than a selection criterion that was developed for observations of real clusters. However, the two numbers of blue stragglers are well-correlated, so either selection criterion can be used to characterize the blue straggler population of a cluster. We confirm previous results that the simplified prescription for the evolution of a collision or merger product in the BSE code overestimates their lifetimes. We show that our model blue stragglers follow similar trends with cluster properties (core mass, binary fraction, total mass, collision rate) as the true Milky Way blue stragglers as long as we restrict ourselves to model clusters with an initial binary fraction higher than 5%. We also show that, in contrast to earlier work, the number of blue stragglers in the cluster core does have a weak dependence on the collisional parameter ? in both our models and in Milky Way globular clusters.

  15. Anthem Blue Cross/Anthem Blue Cross Life and Health Insurance Company (P-NP) 6/13/2011 University of California

    E-Print Network [OSTI]

    Kammen, Daniel M.

    Anthem Blue Cross/Anthem Blue Cross Life and Health Insurance Company (P-NP) 6/13/2011 University that all sections of the claim form are completed and mail to: Anthem Blue Cross Prescription Drug Program

  16. Leather and Blue Jeans Issue 1 

    E-Print Network [OSTI]

    Multiple Contributors

    1993-01-01

    , the trap was sprung. So, after many long hours, weeks and months of anxious moments, bouts of laughter (some typos I made were hilarious), and running around in circles, you now have the results in your hands. I listened to suggestions and complaints... into this insanity again...unless more "Leather and Blue Jeans" art comes along. Hope you enjoy reading this zine as much as I've enjoyed putting it together. ORDERING $20.00 in person Gale Good INFORMATION $23.00 U.S. mail PAL Press Overseas?Please inquire...

  17. Blue running of the primordial tensor spectrum

    SciTech Connect (OSTI)

    Gong, Jinn-Ouk

    2014-07-01

    We examine the possibility of positive spectral index of the power spectrum of the primordial tensor perturbation produced during inflation in the light of the detection of the B-mode polarization by the BICEP2 collaboration. We find a blue tilt is in general possible when the slow-roll parameter decays rapidly. We present two known examples in which a positive spectral index for the tensor power spectrum can be obtained. We also briefly discuss other consistency tests for further studies on inflationary dynamics.

  18. Blue, green, orange, and red upconversion laser

    DOE Patents [OSTI]

    Xie, P.; Gosnell, T.R.

    1998-09-08

    A laser is disclosed for outputting visible light at the wavelengths of blue, green, orange and red light. This is accomplished through the doping of a substrate, such as an optical fiber or waveguide, with Pr{sup 3+} ions and Yb{sup 3+} ions. A light pump such as a diode laser is used to excite these ions into energy states which will produce lasing at the desired wavelengths. Tuning elements such as prisms and gratings can be employed to select desired wavelengths for output. 11 figs.

  19. Green Lands Blue Water 2014 Fall Conference

    Broader source: Energy.gov [DOE]

    The Green Lands Blue Water 2014 Fall Conference will be held from November 19–20, 2014, at the Richland Community College in Decatur, Illinois. The event will focus on bioenergy and sustainable agriculture and explore topics ranging from logistics, energy conversion technologies, and markets for grass biomass. BETO Sustainability Program Technology Manager Kristen Johnson will be speaking about the Energy Department’s perspective on sustainable bioenergy landscapes and will focus on BETO’s recent work with landscape design. The conference will be November 19–20 only. On November 18, participants may choose to participate in a pre-conference field tour.

  20. Blue, green, orange, and red upconversion laser

    DOE Patents [OSTI]

    Xie, Ping (San Jose, CA); Gosnell, Timothy R. (Sante Fe, NM)

    1998-01-01

    A laser for outputting visible light at the wavelengths of blue, green, orange and red light. This is accomplished through the doping of a substrate, such as an optical fiber or waveguide, with Pr.sup.3+ ions and Yb.sup.3+ ions. A light pump such as a diode laser is used to excite these ions into energy states which will produce lasing at the desired wavelengths. Tuning elements such as prisms and gratings can be employed to select desired wavelengths for output.

  1. Blue running of the primordial tensor spectrum

    E-Print Network [OSTI]

    Jinn-Ouk Gong

    2014-07-09

    We examine the possibility of positive spectral index of the power spectrum of the primordial tensor perturbation produced during inflation in the light of the detection of the B-mode polarization by the BICEP2 collaboration. We find a blue tilt is in general possible when the slow-roll parameter decays rapidly. We present two known examples in which a positive spectral index for the tensor power spectrum can be obtained. We also briefly discuss other consistency tests for further studies on inflationary dynamics.

  2. Blue Ribbon Commission (BRC) Activities - SRSCRO

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits & InspectionsBerylliumBiomimetic(cousin -in-law to Colin Adams)Blue

  3. Summit Blue Consulting | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS ReportEuropeEnergy Information Recent Flow TestingSummit Blue

  4. Blue Mountain Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois: EnergyHills, Connecticut: EnergyMotionBlue

  5. BlueFire Ethanol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois: EnergyHills, Connecticut:NgBlueFire Ethanol Jump

  6. Blue Sky Bio Fuels | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:BlueBio Fuels Jump to:

  7. Blue Sphere Corp | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:BlueBio Fuels

  8. Blue Valley Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:BlueBioStarValley

  9. BlueFire Ethanol | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12Power, IncBio Centers AnnouncementandBlog BlogBlueFire Ethanol

  10. SH 8/08 Ms. Blue's Measurements Page 1 of 5 Ms. Blue's Measurements

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    as an adult elephant) - Tongue extended the length of the mouth (~18 feet) - Tongue palate and baleen are black - Baleen weighed 400 pounds - Water would enter the mouth at a rate of 5-20 tons per second of the aorta was 9 inches - Muscles weighed 40 tons - The mandibles of a blue whale are the largest single

  11. Alcian Blue Cartilage Staining Beatrice Jegalian & Eddy M. De Robertis

    E-Print Network [OSTI]

    De Robertis, Eddy M.

    into 5% acetic acid washes twice for 1 hour each. 5. Stain embryos for 2 hours (larger embryos will require more time) in 0.05% Alcian blue 8GX (Fisher) in 5% acetic acid. 6. Wash embryos in 5% acetic acid Alcian Blue 8 g NaCl 0.05% Alcian blue 8GX .2 g KCl 5% acetic acid 1.44 g Na2HPO4 water .24 g KH2PO4 800

  12. Summer Enrollment Blue=Old Program, Red=New Program

    E-Print Network [OSTI]

    Gering, Jon C.

    Summer Enrollment Blue=Old Program, Red=New Program 1559 14181358 1304 1166 1245 0 200 400 600 800;Summer Sections Offered Blue=Old Program, Red=New Program 142 135 160158 180 200 0 50 100 150 200 250 Generated Blue=Old Program, Red=New Program 5643 5983.5 5463 4953 5985.5 6961 0 1000 2000 3000 4000 5000

  13. Geophysical Studies in the Vicinity of Blue Mountain and Pumpernickel...

    Open Energy Info (EERE)

    magnetic, and physical-property data were collected to study regional crustal structures as an aid to understanding the geologic framework of the Blue Mountain and...

  14. Ground Gravity Survey At Blue Mountain Geothermal Area (Fairbank...

    Open Energy Info (EERE)

    Ground Gravity Survey At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground...

  15. Static Temperature Survey At Blue Mountain Geothermal Area (Fairbank...

    Open Energy Info (EERE)

    Static Temperature Survey At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  16. Aerial Photography At Blue Mountain Geothermal Area (Fairbank...

    Open Energy Info (EERE)

    Aerial Photography At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Aerial...

  17. Reflection Survey At Blue Mountain Geothermal Area (Fairbank...

    Open Energy Info (EERE)

    Reflection Survey At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Reflection...

  18. Direct-Current Resistivity Survey At Blue Mountain Area (Fairbank...

    Open Energy Info (EERE)

    Direct-Current Resistivity Survey At Blue Mountain Area (Fairbank Engineering Ltd, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  19. Self Potential At Blue Mountain Geothermal Area (Fairbank Engineering...

    Open Energy Info (EERE)

    Self Potential At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Self Potential...

  20. Dipole-Dipole Resistivity At Blue Mountain Geothermal Area (Fairbank...

    Open Energy Info (EERE)

    Dipole-Dipole Resistivity At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  1. Field Mapping At Blue Mountain Geothermal Area (Fairbank Engineering...

    Open Energy Info (EERE)

    Field Mapping At Blue Mountain Geothermal Area (Fairbank Engineering Ltd, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At...

  2. Geology and Temperature Gradient Surveys Blue Mountain Geothermal...

    Open Energy Info (EERE)

    Geology and Temperature Gradient Surveys Blue Mountain Geothermal Discovery, Humboldt County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  3. Electrical Resistivity and Self-Potential Surveys Blue Mountain...

    Open Energy Info (EERE)

    Electrical Resistivity and Self-Potential Surveys Blue Mountain Geothermal Area, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  4. Thermal Gradient Holes At Blue Mountain Geothermal Area (Fairbank...

    Open Energy Info (EERE)

    Thermal Gradient Holes At Blue Mountain Geothermal Area (Fairbank & Niggemann, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal...

  5. Geophysical Setting of the Blue Mountain Geothermal Area, North...

    Open Energy Info (EERE)

    Geophysical Setting of the Blue Mountain Geothermal Area, North-Central Nevada and Its Relationship to a Crustal-Scale Fracture Associated with the Inception of the Yellowstone...

  6. Task Force for Strategic Developments to Blue Ribbon Commission...

    Office of Environmental Management (EM)

    Blue Ribbon Commission Report and Transportation Program Corinne Macaluso National Transportation Stakeholders Forum Knoxville, Tennessee May 16, 2012 2 Formed at the direction...

  7. Thermal Gradient Holes At Blue Mountain Geothermal Area (Fairbank...

    Open Energy Info (EERE)

    Thermal Gradient Holes At Blue Mountain Geothermal Area (Fairbank & Ross, 1999) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient...

  8. Hyperspectral Imaging At Blue Mountain Geothermal Area (Calvin...

    Open Energy Info (EERE)

    Hyperspectral Imaging At Blue Mountain Geothermal Area (Calvin, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Hyperspectral...

  9. Epithermal Gold Mineralization and a Geothermal Resource at Blue...

    Open Energy Info (EERE)

    Epithermal Gold Mineralization and a Geothermal Resource at Blue Mountain, Humboldt County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  10. Dipole-Dipole Resistivity At Blue Mountain Geothermal Area (Ross...

    Open Energy Info (EERE)

    Dipole-Dipole Resistivity At Blue Mountain Geothermal Area (Ross, Et Al., 1999) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Dipole-Dipole...

  11. Conceptual Model At Blue Mountain Geothermal Area (Faulds & Melosh...

    Open Energy Info (EERE)

    Conceptual Model At Blue Mountain Geothermal Area (Faulds & Melosh, 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Conceptual Model At...

  12. Structure of a rabbit muscle fructose-1, 6-bisphosphate aldolase A dimer variant

    SciTech Connect (OSTI)

    Sherawat, Manashi [Department of Physiology and Biophysics, Boston University School of Medicine, 715 Albany Street, Boston, MA 02118-2394 (United States); Tolan, Dean R., E-mail: tolan@bu.edu [Department of Biology, Boston University, 5 Cummington Street, Boston, MA 02215 (United States); Allen, Karen N., E-mail: tolan@bu.edu [Department of Physiology and Biophysics, Boston University School of Medicine, 715 Albany Street, Boston, MA 02118-2394 (United States)

    2008-05-01

    The X-ray crystallographic structure of a dimer variant of fructose-1, 6-bisphosphate aldolase demonstrates a stable oligomer that mirrors half of the native tetramer. The presence of product demonstrates that this is an active form. Fructose-1, 6-bisphosphate aldolase (aldolase) is an essential enzyme in glycolysis and gluconeogenesis. In addition to this primary function, aldolase is also known to bind to a variety of other proteins, a property that may allow it to perform ‘moonlighting’ roles in the cell. Although monomeric and dimeric aldolases possess full catalytic activity, the enzyme occurs as an unusually stable tetramer, suggesting a possible link between the oligomeric state and these noncatalytic cellular roles. Here, the first high-resolution X-ray crystal structure of rabbit muscle D128V aldolase, a dimeric form of aldolase mimicking the clinically important D128G mutation in humans associated with hemolytic anemia, is presented. The structure of the dimer was determined to 1.7 Å resolution with the product DHAP bound in the active site. The turnover of substrate to produce the product ligand demonstrates the retention of catalytic activity by the dimeric aldolase. The D128V mutation causes aldolase to lose intermolecular contacts with the neighboring subunit at one of the two interfaces of the tetramer. The tertiary structure of the dimer does not significantly differ from the structure of half of the tetramer. Analytical ultracentrifugation confirms the occurrence of the enzyme as a dimer in solution. The highly stable structure of aldolase with an independent active site is consistent with a model in which aldolase has evolved as a multimeric scaffold to perform other noncatalytic functions.

  13. MERCURY-NITRITE-RHODIUM-RUTHENIUM INTERACTIONS IN NOBLE METAL CATALYZED HYDROGEN GENERATION FROM FORMIC ACID DURING NUCLEAR WASTE PROCESSING AT THE SAVANNAH RIVER SITE - 136C

    SciTech Connect (OSTI)

    Koopman, D.; Pickenheim, B.; Lambert, D.; Newell, J; Stone, M.

    2009-09-02

    Chemical pre-treatment of radioactive waste at the Savannah River Site is performed to prepare the waste for vitrification into a stable waste glass form. During pre-treatment, compounds in the waste become catalytically active. Mercury, rhodium, and palladium become active for nitrite destruction by formic acid, while rhodium and ruthenium become active for catalytic conversion of formic acid into hydrogen and carbon dioxide. Nitrite ion is present during the maximum activity of rhodium, but is consumed prior to the activation of ruthenium. Catalytic hydrogen generation during pre-treatment can exceed radiolytic hydrogen generation by several orders of magnitude. Palladium and mercury impact the maximum catalytic hydrogen generation rates of rhodium and ruthenium by altering the kinetics of nitrite ion decomposition. New data are presented that illustrate the interactions of these various species.

  14. Hydrous ruthenium oxide nanoparticles anchored to graphene and carbon nanotube hybrid foam for supercapacitors

    SciTech Connect (OSTI)

    Wang, Wei; Guo, S.; Lee, I.; Ahmed, K.; Zhong, J.; Favors, Z.; Zaera, F.; Ozkan, M.; Ozkan, C. S

    2014-03-25

    In real life applications, supercapacitors (SCs) often can only be used as part of a hybrid system together with other high energy storage devices due to their relatively lower energy density in comparison to other types of energy storage devices such as batteries and fuel cells. Increasing the energy density of SCs will have a huge impact on the development of future energy storage devices by broadening the area of application for SCs. Here, we report a simple and scalable way of preparing a three-dimensional (3D) sub-5 nm hydrous ruthenium oxide (RuO?) anchored graphene and CNT hybrid foam (RGM) architecture for high-performance supercapacitor electrodes. This RGM architecture demonstrates a novel graphene foam conformally covered with hybrid networks of RuO? nanoparticles and anchored CNTs. SCs based on RGM show superior gravimetric and per-area capacitive performance (specific capacitance: 502.78 F g?¹, areal capacitance: 1.11 F cm?²) which leads to an exceptionally high energy density of 39.28 Wh kg?¹ and power density of 128.01 kW kg?¹. The electrochemical stability, excellent capacitive performance, and the ease of preparation suggest this RGM system is promising for future energy storage applications.

  15. Statistical thermodynamics of supercapacitors and blue engines

    E-Print Network [OSTI]

    René van Roij

    2012-11-06

    We study the thermodynamics of electrode-electrolyte systems, for instance supercapacitors filled with an ionic liquid or blue-energy devices filled with river- or sea water. By a suitable mapping of thermodynamic variables, we identify a strong analogy with classical heat engines. We introduce several Legendre transformations and Maxwell relations. We argue that one should distinguish between the differential capacity at constant ion number and at constant ion chemical potential, and derive a relation between them that resembles the standard relation between heat capacity at constant volume and constant pressure. Finally, we consider the probability distribution of the electrode charge at a given electrode potential, the standard deviation of which is given by the differential capacity.

  16. Anomalous loss in blue-green wavelength discrimination with very

    E-Print Network [OSTI]

    Foster, David H.

    Anomalous loss in blue-green wavelength discrimination with very brief monochromatic stimuli to yield non-uniform increases in discrimination thresholds in the blue-green region of the spectrum that the effect was not attributable to the reduced energy of the short flash. One of the most significant

  17. Cavity Enhancement of Single Quantum Dot Emission in the Blue

    E-Print Network [OSTI]

    2009-12-27

    Abstract Cavity-enhanced single-photon emission in the blue spectral region was measured from single InGaN/GaN quantum dots. The low-Q microcavities used were characterized using micro-reflectance spectroscopy where the source was the enhanced blue...

  18. A Second Luminous Blue Variable in the Quintuplet Cluster

    E-Print Network [OSTI]

    closely match those of the Pistol Star, a luminous blue variable and one of the most luminous stars known, and similarities to the Pistol Star, we conclude that FMM#362 is a luminous blue variable. Subject headings: stars & Moorwood (1994), and now known as the Pistol Star, has a luminosity of ¸ 10 7 L fi , making it one

  19. Plumage and body size in Blue-winged and Cinnamon teals 107 Plumage and body size in Blue-winged and Cinnamon teals

    E-Print Network [OSTI]

    McCracken, Kevin G.

    Plumage and body size in Blue-winged and Cinnamon teals 107 Plumage and body size in Blue-winged and Cinnamon teals doi: 10.3184/175815512X13350025801205 Plumage and body size differentiation in Blue-mail: wils0289@yahoo.com ABSTRACT Blue-winged Teal (Anas discors) and Cinnamon Teal (A. cyanoptera

  20. CHEIBA Multi-Option for 0111.v.10-20-10 1 HMO Colorado/Anthem Blue Cross and Blue Shield

    E-Print Network [OSTI]

    CHEIBA Multi-Option for 0111.v.10-20-10 1 HMO Colorado/Anthem Blue Cross and Blue Shield Colorado Higher Education Insurance Benefits Alliance Effective January 1, 2011 PART A: TYPE OF COVERAGE Blue. Coinsurance and copayment options reflect the amount the covered person will pay. BlueAdvantage HMO

  1. Anthem Blue Cross/Anthem Blue Cross Life and Health Insurance Company (P-NP) 5/18/2012 Page 1 University of California

    E-Print Network [OSTI]

    Barrett, Jeffrey A.

    Anthem Blue Cross/Anthem Blue Cross Life and Health Insurance Company (P-NP) 5/18/2012 Page 1 services in detail. Getting a Prescription Filled at an Anthem Blue Cross Participating Pharmacy To get the relation between drug type and your copay amount at Anthem Blue Cross participating pharmacies: FDA

  2. Van der Waals interactions in rare-gas dimers: The role of interparticle interactions

    E-Print Network [OSTI]

    Chen, Yu-Ting; Chai, Jeng-Da

    2015-01-01

    We investigate the potential energy curves of rare-gas dimers with various ranges and strengths of interparticle interactions (nuclear-electron, electron-electron, and nuclear-nuclear interactions). Our investigation is based on the highly accurate coupled-cluster theory associated with those interparticle interactions. For comparison, the performance of the corresponding Hartree-Fock theory, second-order Moller-Plesset perturbation theory, and density functional theory is also investigated. Our results reveal that when the interparticle interactions retain the long-range Coulomb tails, the nature of van der Waals interactions in the rare-gas dimers remains similar. By contrast, when the interparticle interactions are sufficiently short-range, the conventional van der Waals interactions in the rare-gas dimers completely disappear, yielding purely repulsive potential energy curves.

  3. Dimerization Induced Deprotonation of Water on RuO2(110)

    SciTech Connect (OSTI)

    Mu, Rentao; Cantu Cantu, David; Lin, Xiao; Glezakou, Vassiliki Alexandra; Wang, Zhitao; Lyubinetsky, Igor; Rousseau, Roger J.; Dohnalek, Zdenek

    2014-10-02

    RuO2 has proven to be indispensable as a co-catalyst in numerous systems designed for photocatalytic water splitting. In this study we have carried out a detailed mechanistic study of water behavior on the most stable RuO2 face, RuO2(110), by employing variable temperature scanning tunneling microscopy and density functional theory calculations. We show that water monomers adsorb molecularly on Ru sites, become mobile above 238 K, diffuse along the Ru rows and form water dimers. The onset for dimer diffusion is observed at ~277 K indicating significantly higher diffusion barrier than that for monomers. More importantly, we find that water dimers deprotonate readily to form Ru-bound H3O2 and bridging OH species. The observed behavior is compared and contrasted with that observed for water on isostructural rutile TiO2(110).

  4. The blue plume population in dwarf spheroidal galaxies: genuine blue stragglers or young stellar population?

    E-Print Network [OSTI]

    Y. Momany; E. V. Held; I. Saviane; S. Zaggia; L. Rizzi; M. Gullieuszik

    2007-04-11

    Abridged... Blue stragglers (BSS) are thought to be the product of either primordial or collisional binary systems. In the context of dwarf spheroidal galaxies it is hard to firmly disentangle a genuine BSS population from young main sequence (MS) stars tracing a ~1-2 Gyr old star forming episode. Assuming that their blue plume populations are made of BSS, we estimate the BSS frequency for 8 Local Group non star-forming dwarf galaxies, using a compilation of ground and space based photometry. Our results can be summarized as follows: (i) The BSS frequency in dwarf galaxies, at any given Mv, is always higher than that in globular clusters of similar luminosities; (ii) the BSS frequency for the lowest luminosity dwarf galaxies is in excellent agreement with that observed in the Milky Way halo; and most interestingly (iii) derive a statistically significant anti-correlation between the BSS frequency and the galaxy Mv. The low density, almost collision-less, environments of our dwarf galaxy sample allow us to infer (i) their very low dynamical evolution; (ii) a negligible production of collisional BSS; and consequently (iii) that their blue plumes are mainly made of primordial binaries. The dwarf galaxies anti-correlation can be used as a discriminator: galaxies obeying the anti-correlation are more likely to possess genuine primordial BSS rather than young main sequence stars.

  5. Being Blue in Hawai‘i: Politics, Affect, and the Last Queen of Hawai‘i

    E-Print Network [OSTI]

    Harvey, Bruce

    2011-01-01

    Being Blue in Hawai‘i: Politics, Affect, and the Last Queenmore primarily violated. To be blue in Hawai‘i is to be in amore subtle nuances of being blue in Hawai‘i. Yet also in

  6. Blue and fin whale call source levels and propagation range in the Southern Ocean

    E-Print Network [OSTI]

    Sirovic, Anna; Hildebrand, John A; Wiggins, Sean

    2007-01-01

    graphic characterization of blue whale song worldwide: UsingAugust 2007 Širovi? et al. : Blue and ?n whale source levelsout of the discussion of blue whales,” Rep. Int. Whal. Comm.

  7. Blue oak stump sprouting evaluated after firewood harvest in northern Sacramento Valley

    E-Print Network [OSTI]

    Standiford, Richard B.; McCreary, Douglas D.; Barry, Sheila J; Forero, Larry C.

    2011-01-01

    TABLE 4. Inventory data for blue oak thinning project in8. Standiford RB. 1997. Growth of blue oak on California’s2008. Stump sprouting of blue oaks 19 years after harvest.

  8. Resonant dimer relaxation in cold atoms with a large scattering length

    SciTech Connect (OSTI)

    Braaten, Eric; Hammer, H.-W.

    2007-05-15

    Efimov physics refers to universal phenomena associated with a discrete scaling symmetry in the three-body problem with a large scattering length. The first experimental evidence for Efimov physics was the recent observation of a resonant peak in the three-body recombination rate for {sup 133}Cs atoms with large negative scattering length. There can also be resonant peaks in the atom-dimer relaxation rate for large positive scattering length. We calculate the atom-dimer relaxation rate as a function of temperature and show how measurements of the relaxation rate can be used to determine accurately the parameters that govern Efimov physics.

  9. Resonant Dimer Relaxation in Cold Atoms with a Large Scattering Length

    E-Print Network [OSTI]

    Eric Braaten; H. -W. Hammer

    2009-03-13

    Efimov physics refers to universal phenomena associated with a discrete scaling symmetry in the 3-body problem with a large scattering length. The first experimental evidence for Efimov physics was the recent observation of a resonant peak in the 3-body recombination rate for 133Cs atoms with large negative scattering length. There can also be resonant peaks in the atom-dimer relaxation rate for large positive scattering length. We calculate the atom-dimer relaxation rate as a function of temperature and show how measurements of the relaxation rate can be used to determine accurately the parameters that govern Efimov physics.

  10. Coupled cluster benchmarks of water monomers and dimers extracted from density-functional theory liquid water: The importance of monomer

    E-Print Network [OSTI]

    Alavi, Ali

    Coupled cluster benchmarks of water monomers and dimers extracted from density-functional theory functionals in simulations of liquid water, water monomers and dimers were extracted from a PBE simulation liquid water: The importance of monomer deformations Biswajit Santra,1 Angelos Michaelides,1,2,a

  11. Parallel Dimers and Anti-parallel Tetramers Formed by Epidermal Growth Factor Receptor Pathway Substrate Clone 15 (EPS15)*

    E-Print Network [OSTI]

    Kirchhausen, Tomas

    Parallel Dimers and Anti-parallel Tetramers Formed by Epidermal Growth Factor Receptor Pathway- dependent endocytic traffic. We report here that Eps15 forms dimers and tetramers of distinct shape. The Eps tetramer has a "dumbbell" shape, 31 nm in length; it is formed by the anti-parallel association of two Eps

  12. Electronic structure of the benzene dimer cation Piotr A. Pieniazek, Anna I. Krylov, and Stephen E. Bradforth

    E-Print Network [OSTI]

    Krylov, Anna I.

    Electronic structure of the benzene dimer cation Piotr A. Pieniazek, Anna I. Krylov, and Stephen E-0482 Received 20 March 2007; accepted 22 May 2007; published online 31 July 2007 The benzene and benzene dimer benzene. Both sandwich and t-shaped structures feature intense charge resonance bands, whose location

  13. Aeromagnetic Survey At Blue Mountain Geothermal Area (U.S. Geological...

    Open Energy Info (EERE)

    near Blue Mountain and Pumpernickel Valley near Winnemucca to study regional crustal structures to help understand the geologic framework of Blue Mountain and help in mineral and...

  14. Ground Gravity Survey At Blue Mountain Geothermal Area (U.S....

    Open Energy Info (EERE)

    near Blue Mountain and Pumpernickel Valley near Winnemucca to study regional crustal structures to help understand the geologic framework of Blue Mountain and help in mineral and...

  15. Ground Magnetics At Blue Mountain Geothermal Area (U.S. Geological...

    Open Energy Info (EERE)

    near Blue Mountain and Pumpernickel Valley near Winnemucca to study regional crustal structures to help understand the geologic framework of Blue Mountain and help in mineral and...

  16. Rock Sampling At Blue Mountain Geothermal Area (U.S. Geological...

    Open Energy Info (EERE)

    near Blue Mountain and Pumpernickel Valley near Winnemucca to study regional crustal structures to help understand the geologic framework of Blue Mountain and help in mineral and...

  17. Engineering of a novel Ca{sup 2+}-regulated kinesin molecular motor using a calmodulin dimer linker

    SciTech Connect (OSTI)

    Shishido, Hideki; Maruta, Shinsaku

    2012-06-29

    Highlights: Black-Right-Pointing-Pointer Engineered kinesin-M13 and calmodulin involving single cysteine were prepared. Black-Right-Pointing-Pointer CaM mutant was cross-linked to dimer by bifunctional thiol reactive reagent. Black-Right-Pointing-Pointer Kinesin-M13 was dimerized via CaM dimer in the presence of calcium. Black-Right-Pointing-Pointer Function of the engineered kinesin was regulated by a Ca{sup 2+}-calmodulin dimer linker. -- Abstract: The kinesin-microtubule system holds great promise as a molecular shuttle device within biochips. However, one current barrier is that such shuttles do not have 'on-off' control of their movement. Here we report the development of a novel molecular motor powered by an accelerator and brake system, using a kinesin monomer and a calmodulin (CaM) dimer. The kinesin monomer, K355, was fused with a CaM target peptide (M13 peptide) at the C-terminal part of the neck region (K355-M13). We also prepared CaM dimers using CaM mutants (Q3C), (R86C), or (A147C) and crosslinkers that react with cysteine residues. Following induction of K355-M13 dimerization with CaM dimers, we measured K355-M13 motility and found that it can be reversibly regulated in a Ca{sup 2+}-dependent manner. We also found that velocities of K355-M13 varied depending on the type and crosslink position of the CaM dimer used; crosslink length also had a moderate effect on motility. These results suggest Ca{sup 2+}-dependent dimerization of K355-M13 could be used as a novel molecular shuttle, equipped with an accelerator and brake system, for biochip applications.

  18. Dimer Dissociation and Unfolding Mechanism of Coagulation Factor XI Apple 4 Domain: Spectroscopic

    E-Print Network [OSTI]

    Roder, Heinrich

    Dimer Dissociation and Unfolding Mechanism of Coagulation Factor XI Apple 4 Domain: Spectroscopic of disulfide- linked chains each containing four apple domains and a catalytic domain. The apple 4 domain (A4; A4, apple 4 domain of factor XI; DLS, dynamic light scattering; FXI, factor XI; FXIa, factor FXIa

  19. Receptor expression is essential for proliferation induced by dimerized Jak kinases

    SciTech Connect (OSTI)

    Fujii, Hodaka

    2008-06-13

    Two members of Jak kinases, Jak1 and Jak3, are associated with the cytoplasmic domains of the interleukin-2 (IL-2) receptor (IL-2R) {beta} chain (IL-2R{beta}) and the common cytokine receptor {gamma} chain ({gamma}c), respectively, and accumulating evidence indicates their functional importance in IL-2 signaling. Here, I showed that coumermycin-induced chemical heterodimerization of Jak1 and Jak3 but not homodimerization of Jak1 or Jak3 induces cell proliferation of an IL-2R-reconstituted cell line. In this regard, expression of IL-2R{beta} was essential for cell proliferation by chemical heterodimerization of Jak1 and Jak3, indicating that dimerized Jak1 and Jak3 induce heterodimerization of IL-2R{beta} and {gamma}c, which may activate receptor-bound signaling molecules. Previous reports using chemical dimerization suggest that dimerization of Jak kinases is sufficient to induce cell proliferation. The present study indicates that re-evaluation of this conclusion is necessary and that interpretation of functional analysis of signaling molecules using chemical dimerizers needs more careful assessment.

  20. A new model for myosin dimeric motors incorporating Brownian ratchet and powerstroke mechanisms

    E-Print Network [OSTI]

    Kawai, Ryoichi

    A new model for myosin dimeric motors incorporating Brownian ratchet and powerstroke mechanisms motor proteins in general. A single motor domain is modeled using our previous work on hybrid motors that exhibit elements of both a powerstroke and a Brownian motor mechanism. The different behavior observed

  1. Selfdiffusion of adatoms, dimers, and vacancies on Cu(100) Ghyslain Boisvert ? and Laurent J. Lewis y

    E-Print Network [OSTI]

    Lewis, Laurent J.

    (GCM), Universit'e de Montr'eal, Case Postale 6128, Succursale Centre­Ville, Montr'eal, Qu'ebec, Canada of the diffusion of adatoms, dimers, and vacancies on Cu(100). It is found that the dynamical energy barriers is a ``prefactor'', kB the Boltzmann constant, T the absolute temperature, and EA the activation energy or barrier

  2. Dimerization of 1,3-Butadiene on Highly Characterized Hydroxylated Surfaces of Ultrathin

    E-Print Network [OSTI]

    Dimerization of 1,3-Butadiene on Highly Characterized Hydroxylated Surfaces of Ultrathin Films-cyclohexene on highly ordered hydroxylated ultrathin films of -Al2O3. High surface area, powdered -Al2O3 is widely used to prepare not only highly characterized surfaces of -Al2O3, but also to prepare hydroxylated -Al2O3

  3. ERK Nuclear Translocation Is Dimerization-independent but Controlled by the Rate of Phosphorylation*S

    E-Print Network [OSTI]

    Rieger, Bernd

    ERK Nuclear Translocation Is Dimerization-independent but Controlled by the Rate of Phosphorylation, Universite´ de Nice, Centre A. Lacassagne, 06189 Nice, France Upon activation, ERKs translocate from the molecular mechanisms that regulate ERK nuclear translocation are not fully understood. We have used a mouse

  4. Barrierless proton transfer across weak CH?O hydrogen bonds in dimethyl ether dimer

    SciTech Connect (OSTI)

    Yoder, Bruce L. West, Adam H. C.; Signorell, Ruth; Bravaya, Ksenia B.; Bodi, Andras; Sztáray, Bálint

    2015-03-21

    We present a combined computational and threshold photoelectron photoion coincidence study of two isotopologues of dimethyl ether, (DME ? h{sub 6}){sub n} and (DME ? d{sub 6}){sub n}n = 1 and 2, in the 9–14 eV photon energy range. Multiple isomers of neutral dimethyl ether dimer were considered, all of which may be present, and exhibited varying C–H?O interactions. Results from electronic structure calculations predict that all of them undergo barrierless proton transfer upon photoionization to the ground electronic state of the cation. In fact, all neutral isomers were found to relax to the same radical cation structure. The lowest energy dissociative photoionization channel of the dimer leads to CH{sub 3}OHCH{sub 3}{sup +} by the loss of CH{sub 2}OCH{sub 3} with a 0 K appearance energy of 9.71 ± 0.03 eV and 9.73 ± 0.03 eV for (DME ? h{sub 6}){sub 2} and deuterated (DME ? d{sub 6}){sub 2}, respectively. The ground state threshold photoelectron spectrum band of the dimethyl ether dimer is broad and exhibits no vibrational structure. Dimerization results in a 350 meV decrease of the valence band appearance energy, a 140 meV decrease of the band maximum, thus an almost twofold increase in the ground state band width, compared with DME ? d{sub 6} monomer.

  5. Chemical reaction equilibrium in nanoporous materials: NO dimerization reaction in carbon slit nanopores

    E-Print Network [OSTI]

    Lisal, Martin

    Chemical reaction equilibrium in nanoporous materials: NO dimerization reaction in carbon slit of confinement on chemical reaction equilibrium in nanoporous materials. We use the reaction ensemble Monte Carlo of confinement on chemical properties, particularly on chemical reaction equilibria. A chemical reaction

  6. Density functional study of chemical reaction equilibrium for dimerization reactions in slit and cylindrical nanopores

    E-Print Network [OSTI]

    Lisal, Martin

    Density functional study of chemical reaction equilibrium for dimerization reactions in slit a theoretical study of the effects of confinement on chemical reaction equilibrium in slit and cylindrical equilibrium, for which much less is known. The behavior of chemical reactions in confinement spans a wide

  7. Spectrum and vibrational predissociation of the HF dimer. II. Photodissociation cross sections and product state distributions

    E-Print Network [OSTI]

    and dimer geared-bending modes. We find that dissociation is sufficiently slow for the Fermi golden rule approximate them as bound states. This was the approach taken in the preceding paper1 hereafter called Paper I­DF complex using a time- dependent golden rule approach. In this paper we present the results of full

  8. A concerted, alternating sites mechanism of ubiquinol oxidation by the dimeric cytochrome bc1 complex

    E-Print Network [OSTI]

    Trumpower, Bernard L.

    A concerted, alternating sites mechanism of ubiquinol oxidation by the dimeric cytochrome bc1 A refinement of the protonmotive Q cycle mechanism is proposed in which oxidation of ubiquinol is a concerted reaction and occurs by an alternating, half-of-the-sites mechanism. A concerted mechanism of ubiquinol

  9. Dimeric Drug Polymeric Nanoparticles with Exceptionally High Drug Loading and Quantitative Loading Efficiency

    E-Print Network [OSTI]

    Cheng, Jianjun

    Dimeric Drug Polymeric Nanoparticles with Exceptionally High Drug Loading and Quantitative LoadingChampaign, Urbana, Illinois 61801, United States Key Laboratory of Smart Drug Delivery, Ministry of Education-molecule drugs in hydrophobic polymers or amphiphilic copolymers has been extensively used for preparing

  10. Microwave and tunable far-infrared laser spectroscopy of the ammonia-water dimer

    E-Print Network [OSTI]

    Blake, Geoffrey

    Microwave and tunable far-infrared laser spectroscopy of the ammonia- water dimer Paul A. Stockman of Technology,170-25,Pasadena,CA 91125 (Received14August 1991;accepted5 November 1991) Microwave and far cosmochemically. In a gasof solar composition,the most stablecarbon,nitro- gen,and oxygencontaining speciesat

  11. Polarizable interaction potential for water from coupled cluster calculations. I. Analysis of dimer potential energy surface

    E-Print Network [OSTI]

    by nonadditive effects which make it impossible to sufficiently accurately represent the energy of water as a sumPolarizable interaction potential for water from coupled cluster calculations. I. Analysis of dimer potential energy surface Robert Bukowski,1 Krzysztof Szalewicz,1,a Gerrit C. Groenenboom,2 and Ad van der

  12. BlueCross BlueShield International Claim Form | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O

  13. Oxidation Tube Furnace (Lindberg/Blue 1100C)

    E-Print Network [OSTI]

    Subramanian, Venkat

    Oxidation Tube Furnace (Lindberg/Blue 1100C) Basic User Manual 1st Edition Jan 2013 NR #12;Logon Oxidation Tube Furnace on FOM System Sign Log Book #12;Example Program: Room temperature to 1100C

  14. Blue Ridge Electric Cooperative- Heat Pump Loan Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    Blue Ridge Electric Cooperative (BREC) offers low interest loans to help members finance the purchase of energy efficient heat pumps. Loans under $1,500 can be financed for up to 42 months, and...

  15. Blue Ridge Electric Cooperative- Residential Water Heater Rebate

    Broader source: Energy.gov [DOE]

    Blue Ridge Electric Cooperative offers up to $300 for the purchase of an electric water heater. The rebate amount varies based on the size of the water heater purchased.

  16. Blue Ribbon Commission on America's Nuclear Future Report to...

    Broader source: Energy.gov (indexed) [DOE]

    Blue Ribbon Commission on America's Nuclear Future (BRC) was formed by the Secretary of Energy at the request of the President to conduct a comprehensive review of policies for...

  17. Identifying vocalizations and their possible function in Texas Blue Jays 

    E-Print Network [OSTI]

    Jeter-Edwards, Julie

    1989-01-01

    notes . . . Pumphandle Calls. Wheedle calls. Quiet bell call. Bell call. Guttural Calls. Rattle call. "Referee's whistle" Rattle variant. The Growl Song and Specialized Courtship Calls. . . 1V v vill . 41 . 41 . 41 Juvenile and adult... cry. Pumphandle Calls. Bell calls. Wheedle call. Quiet bell, Guttural Calls. Song. Mimicry Comparison of the Blue Jay's Repertoire with Thorpe's (1961) system. Role of Learning. Page . . . . . 71 Possible Adaptive Significance of the Blue...

  18. Record External Quantum Efficiency in Blue OLED Device

    Broader source: Energy.gov [DOE]

    Scientists at Pacific Northwest National Laboratory (PNNL) have created a blue organic light emitting diode (OLED) with an external quantum efficiency (EQE) of 11% at 800 cd/m2, exceeding their previous record EQE of 8%. The EQE of blue OLEDs is a major challenge in OLED technology development. This achievement is particularly notable since it was accomplished at a much lower operating voltage (6.2V) than previous demonstrations using similar structures, revealing the potential for much higher power efficiencies.

  19. Quasars and the Big Blue Bump

    E-Print Network [OSTI]

    Zhaohui Shang; Michael S. Brotherton; Richard F. Green; Gerard A. Kriss; Jennifer Scott; Jessica Kim Quijano; Omer Blaes; Ivan Hubeny; John Hutchings; Mary Elizabeth Kaiser; Anuradha Koratkar; William Oegerle; Wei Zheng

    2004-09-29

    We investigate the ultraviolet-to-optical spectral energy distributions (SEDs) of 17 active galactic nuclei (AGNs) using quasi-simultaneous spectrophotometry spanning 900-9000 Angstrom (rest frame). We employ data from the Far Ultraviolet Spectroscopic Explorer (FUSE), the Hubble Space Telescope (HST), and the 2.1-meter telescope at Kitt Peak National Observatory (KPNO). Taking advantage of the short-wavelength coverage, we are able to study the so-called "big blue bump," the region where the energy output peaks, in detail. Most objects exhibit a spectral break around 1100 Angstrom. Although this result is formally associated with large uncertainty for some objects, there is strong evidence in the data that the far-ultraviolet spectral region is below the extrapolation of the near-ultraviolet-optical slope, indicating a spectral break around 1100 Angstrom. We compare the behavior of our sample to those of non-LTE thin-disk models covering a range in black-hole mass, Eddington ratio, disk inclination, and other parameters. The distribution of ultraviolet-optical spectral indices redward of the break, and far-ultraviolet indices shortward of the break, are in rough agreement with the models. However, we do not see a correlation between the far-ultraviolet spectral index and the black hole mass, as seen in some accretion disk models. We argue that the observed spectral break is intrinsic to AGNs, although intrinsic reddening as well as Comptonization can strongly affect the far-ultraviolet spectral index. We make our data available online in digital format.

  20. Physical Properties of Blue Shark Useful in Designing a Skinning Machine

    E-Print Network [OSTI]

    Physical Properties of Blue Shark Useful in Designing a Skinning Machine D. E. BROWN, R. PAUL SINGH for a machine to skin blue shark 2 · A wider market for blue shark products is being sought. For example, if removed in one piece the skin is of value for making leather. The machine proposed to skin blue shark

  1. Blue Noise Sampling with Controlled Aliasing DANIEL HECK and THOMAS SCHL OMER and OLIVER DEUSSEN

    E-Print Network [OSTI]

    Deussen, Oliver

    Blue Noise Sampling with Controlled Aliasing DANIEL HECK and THOMAS SCHL ¨OMER and OLIVER DEUSSEN University of Konstanz In this paper we revisit the problem of blue noise sampling with a strong focus types of blue noise patterns: step blue noise with a power spectrum in the form of a step function

  2. COMPARlSON OF SAMPLING DEVICES FOR THE JUVENILE BLUE CRAB,

    E-Print Network [OSTI]

    COMPARlSON OF SAMPLING DEVICES FOR THE JUVENILE BLUE CRAB, CALLINECTES SAPIDUS' The behavior ofthe blue crab, Callinectes sapidus Rathbun, in the Chesapeake Bay varies consider- ably with age effectively the blue crab during winter and summer at all depths and types ofbottom. During winter blue crabs

  3. Ion and water transports in Prussian blue lms investigated with electrochemical quartz crystal microbalance

    E-Print Network [OSTI]

    Kwak, Juhyoun

    various kinds of metal hexacyanometallate ®lms, the Prussian blue (PB, ferric ferrocyanide) ®lm [1± 5] has

  4. ChampionSin the Classroom, in the Community, and in Competition HailtotHeBuff&Blue

    E-Print Network [OSTI]

    Vertes, Akos

    Supporting ChampionSin the Classroom, in the Community, and in Competition #12;HailtotHeBuff&Blue, and the Buff & Blue Fund is the cornerstone of GW Athletics. Through the Buff & Blue Fund, donors are providing that, the Buff & Blue Fund represents: An athletic experience that mirrors the overall excellence of GW

  5. Regal Blues Tryout General Info and Schedule The La Tech Regal Blues are experienced and technically trained dancers who focus primarily on

    E-Print Network [OSTI]

    Selmic, Sandra

    Regal Blues Tryout General Info and Schedule The La Tech Regal Blues per week. They represent the Bulldogs and the Tech community at appearances meeting for the new 2014-2015 team! -meet at Lambright in Aerobics room -come

  6. Concise Total Synthesis and Stereochemical Revision of (+)-Naseseazines A and B: Regioselective Arylative Dimerization of Diketopiperazine Alkaloids

    E-Print Network [OSTI]

    Kim, Justin

    Concise and enantioselective total syntheses of (+)-naseseazines A and B are described. Our regioselective and directed dimerization of diketopiperazines provides their critical C3–C[2 over sp] linkages, an assembly with ...

  7. Elastic properties of the degenerate f.c.c. crystal of polydisperse soft dimers at zero temperature

    E-Print Network [OSTI]

    Narojczyk, J W

    2015-01-01

    Elastic properties of soft, three-dimensional dimers, interacting through site-site n-inverse-power potential, are determined by computer simulations at zero temperature. The degenerate crystal of dimers exhibiting (Gaussian) size distribution of atomic diameters - i.e. size polydispersity - is studied at the molecular number density $1/\\sqrt{2}$; the distance between centers of atoms forming dimers is considered as a length unit. It is shown that, at the fixed number density of the dimers, increasing polydispersity causes, typically, an increase of pressure, elastic constants and Poisson's ratio; the latter is positive in most direction. A direction is found, however, in which the size polydispersity causes substantial decrease of Poisson's ratio, down to negative values for large $n$. Thus, the system is partially auxetic for large polydispersity and large n.

  8. Elastic properties of the degenerate f.c.c. crystal of polydisperse soft dimers at zero temperature

    E-Print Network [OSTI]

    J. W. Narojczyk; K. W. Wojciechowski

    2015-04-12

    Elastic properties of soft, three-dimensional dimers, interacting through site-site n-inverse-power potential, are determined by computer simulations at zero temperature. The degenerate crystal of dimers exhibiting (Gaussian) size distribution of atomic diameters - i.e. size polydispersity - is studied at the molecular number density $1/\\sqrt{2}$; the distance between centers of atoms forming dimers is considered as a length unit. It is shown that, at the fixed number density of the dimers, increasing polydispersity causes, typically, an increase of pressure, elastic constants and Poisson's ratio; the latter is positive in most direction. A direction is found, however, in which the size polydispersity causes substantial decrease of Poisson's ratio, down to negative values for large $n$. Thus, the system is partially auxetic for large polydispersity and large n.

  9. A Concise and Versatile Double-Cyclization Strategy for the Highly Stereoselective Synthesis and Arylative Dimerization of Aspidosperma Alkaloids

    E-Print Network [OSTI]

    Medley, Jonathan William

    Building cycles: A strategy for the concise, stereoselective synthesis of aspidosperma alkaloids and related structures via a common putative diiminium ion intermediate is reported. The approach enables the dimerization ...

  10. Morphological variations as nonstandard test parameters for the response to pollutant gas concentration: An application to Ruthenium Phthalocyanine sensing films

    SciTech Connect (OSTI)

    Generosi, A.; Paci, B.; Albertini, V. Rossi; Perfetti, P.; Paoletti, A.M.; Pennesi, G.; Rossi, G.; Caminiti, R.

    2006-03-06

    A systematic time-resolved energy dispersive x-ray reflectometry study was performed in situ on Ruthenium Phthalocyanine thin fims to estimate the morphological detection limits of this material as NO{sub 2} transducer and the influence of the gas concentration on the gas-film interaction mechanisms. The work validates the use of this unconventional method--based on the observation of the morphological parameters change--for evaluating the response of novel sensing materials in alternative to more standard procedures. Indeed, the morphological monitoring is shown to be sensitive to the gas concentration in a range comparable to the usual electroresistive measurements. Moreover, while the latter is only able to give the information on whether the gas is interacting with the sensor, the former is also able to discriminate among interaction processes of a different nature (in the present case the interaction limited to the film surface and the one involving the material bulk)

  11. Modeling theta-theta Interactions with the Effective Fragment Potential Method: The Benzene Dimer and Substituents

    SciTech Connect (OSTI)

    Toni Smithl; Lyudmila V. Slipchenko; Mark S. Gordon

    2008-02-27

    This study compares the results of the general effective fragment potential (EFP2) method to the results of a previous combined coupled cluster with single, double, and perturbative triple excitations [CCSD(T)] and symmetry-adapted perturbation theory (SAPT) study [Sinnokrot and Sherrill, J. Am. Chem. Soc., 2004, 126, 7690] on substituent effects in {pi}-{pi} interactions. EFP2 is found to accurately model the binding energies of the benzene-benzene, benzene-phenol, benzene-toluene, benzene-fluorobenzene, and benzene-benzonitrile dimers, as compared with high-level methods [Sinnokrot and Sherrill, J. Am. Chem. Soc., 2004, 126, 7690], but at a fraction of the computational cost of CCSD(T). In addition, an EFP-based Monte Carlo/simulated annealing study was undertaken to examine the potential energy surface of the substituted dimers.

  12. Photo-induced strengthening of weak bonding in noble gas dimers

    SciTech Connect (OSTI)

    Miyamoto, Yoshiyuki; Miyazaki, Takehide; Rubio, Angel

    2014-05-19

    We demonstrate through extensive first-principles time-dependent density functional calculations that attractive van der Waals interaction between closed-shell atoms can be enhanced by light with constant spatial intensity. We illustrate this general phenomenon for a He dimer as a prototypical case of complex van der Waals interactions and show that when excited by light with a frequency close to the 1s ? 2p He-atomic transition, an attractive force larger than 7 pN is produced. This force gain is manifested as a larger acceleration of He-He contraction under an optical field. The concerted dynamical motions of the He atoms together with polarity switching of the charge-induced dipole cause the contraction of the dimer. These findings are relevant for the photo-induced control of weakly bonded molecular species, either in gas phase or in solution.

  13. A mean-field monomer-dimer model with attractive interaction: Exact solution and rigorous results

    SciTech Connect (OSTI)

    Alberici, D. Contucci, P. Mingione, E.

    2014-06-15

    A mean-field monomer-dimer model which includes an attractive interaction among both monomers and dimers is introduced and its exact solution rigorously derived. The Heilmann-Lieb method for the pure hard-core interacting case is used to compute upper and lower bounds for the pressure. The bounds are shown to coincide in the thermodynamic limit for a suitable choice of the monomer density m. The computation of the monomer density is achieved by solving a consistency equation in the phase space (h, J), where h tunes the monomer potential and J the attractive potential. The critical point and exponents are computed and show that the model is in the mean-field ferromagnetic universality class.

  14. Interaction energies of monosubstituted benzene dimers via nonlocal density functional theory

    E-Print Network [OSTI]

    T. Thonhauser; Aaron Puzder; David C. Langreth

    2005-09-15

    We present density-functional calculations for the interaction energy of monosubstituted benzene dimers. Our approach utilizes a recently developed fully nonlocal correlation energy functional, which has been applied to the pure benzene dimer and several other systems with promising results. The interaction energy as a function of monomer distance was calculated for four different substituents in a sandwich and two T-shaped configurations. In addition, we considered two methods for dealing with exchange, namely using the revPBE generalized gradient functional as well as full Hartree-Fock. Our results are compared with other methods, such as Moller-Plesset and coupled-cluster calculations, thereby establishing the usefulness of our approach. Since our density-functional based method is considerably faster than other standard methods, it provides a computational inexpensive alternative, which is of particular interest for larger systems where standard calculations are too expensive or infeasible.

  15. Blue Stragglers in Low-Luminosity Star Clusters

    E-Print Network [OSTI]

    Eric L. Sandquist

    2005-10-26

    We examine the blue straggler populations of 13 low-luminosity (M_V_t >~ -6) globular clusters and 2 old open clusters. These clusters test blue straggler formation in environments intermediate between higher luminosity (and usually higher density) clusters and the Galactic field. The anti-correlation between the relative frequency of blue stragglers (F_BSS = N_BSS / N_HB) and cluster luminosity continues to the lowest luminosity clusters, which have frequencies meeting or exceeding that of field stars. In addition we find that the anti-correlation between straggler frequency and central density disappears for clusters with density less than about 300 L_V,sun pc^-3, although this appears to be an artifact of the correlation between cluster luminosity and central density. We argue on observational (wide, eccentric binaries containing blue stragglers in M67, and the existence of very bright stragglers in most of the clusters in our sample) and theoretical grounds that stellar collisions still produce a significant fraction of the blue stragglers in low luminosity star clusters due to the long-term survival of wide binaries.

  16. CENSUS OF BLUE STARS IN SDSS DR8

    SciTech Connect (OSTI)

    Scibelli, Samantha; Newberg, Heidi Jo; Carlin, Jeffrey L.; Yanny, Brian

    2015-01-01

    We present a census of the 12,060 spectra of blue objects ((g – r){sub 0} < –0.25) in the Sloan Digital Sky Survey (SDSS) Data Release 8 (DR8). As part of the data release, all of the spectra were cross-correlated with 48 template spectra of stars, galaxies, and QSOs to determine the best match. We compared the blue spectra by eye to the templates assigned in SDSS DR8. 10,856 of the objects matched their assigned template, 170 could not be classified due to low signal-to-noise ratio, and 1034 were given new classifications. We identify 7458 DA white dwarfs, 1145 DB white dwarfs, 273 rarer white dwarfs (including carbon, DZ, DQ, and magnetic), 294 subdwarf O stars, 648 subdwarf B stars, 679 blue horizontal branch stars, 1026 blue stragglers, 13 cataclysmic variables, 129 white dwarf-M dwarf binaries, 36 objects with spectra similar to DO white dwarfs, 179, quasi-stellar objects (QSOs), and 10 galaxies. We provide two tables of these objects, sample spectra that match the templates, figures showing all of the spectra that were grouped by eye, and diagnostic plots that show the positions, colors, apparent magnitudes, proper motions, etc., for each classification. Future surveys will be able to use templates similar to stars in each of the classes we identify to automatically classify blue stars, including rare types.

  17. Butadiene Complexes of Titanium(II) and Titanium(0): Synthesis, Butadiene Dimerization Catalysis, and Crystal

    E-Print Network [OSTI]

    Girolami, Gregory S.

    Butadiene Complexes of Titanium(II) and Titanium(0): Synthesis, Butadiene Dimerization Catalysis, where dmpe is 1,2-bis(dimethylphosphino)- ethane, reacts with 1,3-butadiene and trans,trans-1,4-diphenyl-1,3-butadiene at -20 °C to produce the titanium(II) butadiene complexes TiMe2(4-C4H4R2)(dmpe), where

  18. The HPr Proteins from the Thermophile Bacillus stearothermophilus Can Form Domain-swapped Dimers

    SciTech Connect (OSTI)

    Sridharan, Sudharsan; Razvi, Abbas; Scholtz, J. Martin; Sacchettini, James C. (TAM)

    2010-07-20

    The study of proteins from extremophilic organisms continues to generate interest in the field of protein folding because paradigms explaining the enhanced stability of these proteins still elude us and such studies have the potential to further our knowledge of the forces stabilizing proteins. We have undertaken such a study with our model protein HPr from a mesophile, Bacillus subtilis, and a thermophile, Bacillus stearothermophilus. We report here the high-resolution structures of the wild-type HPr protein from the thermophile and a variant, F29W. The variant proved to crystallize in two forms: a monomeric form with a structure very similar to the wild-type protein as well as a domain-swapped dimer. Interestingly, the structure of the domain-swapped dimer for HPr is very different from that observed for a homologous protein, Crh, from B. subtilis. The existence of a domain-swapped dimer has implications for amyloid formation and is consistent with recent results showing that the HPr proteins can form amyloid fibrils. We also characterized the conformational stability of the thermophilic HPr proteins using thermal and solvent denaturation methods and have used the high-resolution structures in an attempt to explain the differences in stability between the different HPr proteins. Finally, we present a detailed analysis of the solution properties of the HPr proteins using a variety of biochemical and biophysical methods.

  19. The Structure of the Poxvirus A33 Protein Reveals a Dimer of Unique C-Type Lectin-Like Domains

    SciTech Connect (OSTI)

    Su, Hua-Poo; Singh, Kavita; Gittis, Apostolos G.; Garboczi, David N. (NIH)

    2010-11-03

    The current vaccine against smallpox is an infectious form of vaccinia virus that has significant side effects. Alternative vaccine approaches using recombinant viral proteins are being developed. A target of subunit vaccine strategies is the poxvirus protein A33, a conserved protein in the Chordopoxvirinae subfamily of Poxviridae that is expressed on the outer viral envelope. Here we have determined the structure of the A33 ectodomain of vaccinia virus. The structure revealed C-type lectin-like domains (CTLDs) that occur as dimers in A33 crystals with five different crystal lattices. Comparison of the A33 dimer models shows that the A33 monomers have a degree of flexibility in position within the dimer. Structural comparisons show that the A33 monomer is a close match to the Link module class of CTLDs but that the A33 dimer is most similar to the natural killer (NK)-cell receptor class of CTLDs. Structural data on Link modules and NK-cell receptor-ligand complexes suggest a surface of A33 that could interact with viral or host ligands. The dimer interface is well conserved in all known A33 sequences, indicating an important role for the A33 dimer. The structure indicates how previously described A33 mutations disrupt protein folding and locates the positions of N-linked glycosylations and the epitope of a protective antibody.

  20. Physics of the Blues: Music, Fourier and Wave - Particle Duality

    SciTech Connect (OSTI)

    Gibson, J. Murray

    2003-10-15

    Art and science are intimately connected. There is probably no art that reveals this more than music. Music can be used as a tool to teach physics and engineering to non-scientists, illustrating such diverse concepts as Fourier analysis and quantum mechanics. This colloquium is aimed in reverse, to explain some interesting aspects of music to physicists. Topics include: What determines the frequency of notes on a musical scale? What is harmony and why would Fourier care? Where did the blues come from? (We' re talking the 'physics of the blues', and not 'the blues of physics' - that's another colloquium). Is there a musical particle? The presentation will be accompanied by live keyboard demonstrations. The presenter will attempt to draw tenuous connections between the subject of his talk and his day job as Director of the Advanced Photon Source at Argonne National Laboratory.

  1. 'Kind of Blue' and the Economy of Modal Jazz

    E-Print Network [OSTI]

    Barrett, Samuel

    2006-05-09

    I had the top small group in jazz and was paying the most money that I should have a black piano player [. . .] Then a lot of people were saying he [Bill Evans] didn’t play fast enough and hard enough for them, that he was too delicate’ (Davis 1989... by Bill Evans have been taken as the defining feature of the album: ‘So What’ is a simple figure based on 16 measures of one scale, 8 of another and 8 more of the first . . . ‘All Blues’ is a 6/8 12-measure blues form that produces its mood through only a...

  2. BlueFire Ethanol, Inc. | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Researchof Energy|Make6,Energy Blue RibbonBlueFire Ethanol,

  3. Blue Mountain, Humboldt County, Nevada, U.S.A

    SciTech Connect (OSTI)

    Ted Fitzpatrick, Brian D. Fairbank

    2005-04-01

    The report documents the drilling of well Deep Blue No.2, the second deep geothermal test hole at the Blue Mountain Geothermal Area, Humboldt County, Nevada. The well was drilled by Noramex Corp, a Nevada company, with funding support from the US Department of Energy, under the DOE’s GRED II Program. Deep Blue No.2 was drilled as a ‘step-out’ hole from Deep Blue No.1, to further evaluate the commercial potential of the geothermal resource. Deep Blue No.2 was designed as a vertical, slim observation test hole to a nominal target depth of 1000 meters (nominal 3400 feet). The well tests an area of projected high temperatures at depth, from temperature gradients measured in a group of shallow drill holes located approximately one kilometer to the northeast of observation hole Deep Blue No.1. The well is not intended for, or designed as, a commercial well or a production well. Deep Blue No.2 was spudded on March 25, 2004 and completed to a total depth of 1127.76m (3700 ft) on April 28, 2004. The well was drilled using conventional rotary drilling techniques to a depth of 201.17 m (660 ft), and continuously cored from 201.17m (660 ft) to 1127.76m (3700 ft). A brief rig-on flow-test was conducted at completion to determine basic reservoir parameters and obtain fluid samples. A permeable fracture zone with measured temperatures of 150 to 167°C (302 to 333°F) occurs between 500 to 750m (1640 to 2461ft). The well was left un-lined in anticipation of the Phase III - Flow and Injection Testing. A further Kuster temperature survey was attempted after the well had been shut in for almost 3 weeks. The well appears to have bridged off at 439m (1440ft) as the Kuster tool was unable to descend past this point. Several attempts to dislodge the obstruction using tube jars were unsuccessful. Deep Blue No.2 encountered variably fractured and veined, fine-grained rocks of the Singas Formation, and intruded by minor strongly altered fine-grained felsic dikes, and less altered fineto medium-grained felsic to intermediate dikes. Widespread open fractures and extensive of quartz veining in many intervals of the core indicate a high degree of fracturing and flow of silica-bearing fluids, almost certainly hotter than 200°C (392°F), at some time, but these fractures are now partially sealed. Intervals of soft shaly mudstone, common clay gouge, and rocks with generally low permeability (few veins and fractures) may also form a seal or ‘cap’ above the main high temperature reservoir at Blue Mountain. The encouraging results from Deep Blue No.2 support further drilling at Blue Mountain. Higher temperature fluids can be expected where fractures providing channels for the circulation of hot water from depth have not been sealed extensively by silica deposition.

  4. Spinning like a blue straggler: the population of fast rotating blue straggler stars in ? Centauri

    SciTech Connect (OSTI)

    Mucciarelli, A.; Lovisi, L.; Ferraro, F. R.; Dalessandro, E.; Lanzoni, B.

    2014-12-10

    By using high-resolution spectra acquired with FLAMES-GIRAFFE at the ESO/VLT, we measured the radial and rotational velocities for 110 blue straggler stars (BSSs) in ? Centauri, the globular cluster-like stellar system harboring the largest known BSS population. According to their radial velocities, 109 BSSs are members of the system. The rotational velocity distribution is very broad, with the bulk of BSSs spinning at less than ?40 km s{sup –1} (in agreement with the majority of such stars observed in other globular clusters) and a long tail reaching ?200 km s{sup –1}. About 40% of the sample has v{sub e} sin i > 40 km s{sup –1} and about 20% has v{sub e} sin i > 70 km s{sup –1}. Such a large fraction is very similar to the percentage of fast rotating BSSs observed in M4. Thus, ? Centauri is the second stellar cluster, beyond M4, with a surprisingly high population of fast spinning BSSs. We found a hint of radial behavior for a fraction of fast rotating BSSs, with a mild peak within one core radius, and a possible rise in the external regions (beyond four core radii). This may suggest that recent formation episodes of mass transfer BSSs occurred preferentially in the outskirts of ? Centauri, or that braking mechanisms able to slow down these stars are least efficient in the lowest density environments.

  5. Blue Straggler Stars in the Unusual Globular Cluster NGC 6388

    E-Print Network [OSTI]

    E. Dalessandro; B. Lanzoni; F. R. Ferraro; R. T. Rood; A. Milone; G. Piotto; E. Valenti

    2007-12-27

    We have used multi-band high resolution HST WFPC2 and ACS observations combined with wide field ground-based observations to study the blue straggler star (BSS) population in the galactic globular cluster NGC 6388. As in several other clusters we have studied, the BSS distribution is found to be bimodal: highly peaked in the cluster center, rapidly decreasing at intermediate radii, and rising again at larger radii. In other clusters the sparsely populated intermediate-radius region (or ``zone of avoidance'') corresponds well to that part of the cluster where dynamical friction would have caused the more massive BSS or their binary progenitors to settle to the cluster center. Instead, in NGC 6388, BSS still populate a region that should have been cleaned out by dynamical friction effects, thus suggesting that dynamical friction is somehow less efficient than expected. As by-product of these observations, the peculiar morphology of the horizontal branch (HB) is also confirmed. In particular, within the (very extended) blue portion of the HB we are able to clearly characterize three sub-populations: ordinary blue HB stars, extreme HB stars, and blue hook stars. Each of these populations has a radial distribution which is indistinguishable from normal cluster stars.

  6. Introducing Unit Testing With BlueJ Andrew Patterson

    E-Print Network [OSTI]

    Kent, University of

    of testing support software. Unfortunately, no adequate software to support testing for introductory students, Verification. Keywords BlueJ, testing, JUnit, CS1. 1. INTRODUCTION The importance of testing in software thorough introduction to testing is often left to software engineering classes later on in the curriculum

  7. Measuring Power Consumption on IBM Blue Gene/Q

    E-Print Network [OSTI]

    Lan, Zhiling

    their usefulness and how well they match up against the environmental data. I. INTRODUCTION As the field, soft- ware will also have a big role to play namely in ensuring power is not wasted by dynamically on the Blue Gene/Q (BGQ): one is an environmental database and the other is profiling code built on vendor

  8. Blue-green and green phosphors for lighting applications

    DOE Patents [OSTI]

    Setlur, Anant Achyut; Chandran, Ramachandran Gopi; Henderson, Claire Susan; Nammalwar, Pransanth Kumar; Radkov, Emil

    2012-12-11

    Embodiments of the present techniques provide a related family of phosphors that may be used in lighting systems to generate blue or blue-green light. The phosphors include systems having a general formula of: ((Sr.sub.1-zM.sub.z).sub.1-(x+w)A.sub.wCe.sub.x).sub.3(Al.sub.1-ySi.s- ub.y)O.sub.4+y+3(x-w)F.sub.1-y-3(x-w) (I), wherein 0blue and blue/green light. Further, the phosphors may be used in blends with other phosphors, or in combined lighting systems, to produce white light suitable for illumination.

  9. Blue Ribbon Panel on Rehabilitation Research at the NIH

    E-Print Network [OSTI]

    Rau, Don C.

    Blue Ribbon Panel on Rehabilitation Research at the NIH A Preliminary Report to NICHD Council June 7, 2012 Rebecca Craik, PT, PhD John Chae, MD, ME #12;Charge Assess rehabilitation research across the NIH · How do we define rehabilitation research? · What is the scope of rehabilitation research within

  10. Think Global, Act Local; Projectome Estimation with BlueMatter

    E-Print Network [OSTI]

    Wandell, Brian A.

    [1]. Understanding the architecture of these long-range projections (the projectome) is importantThink Global, Act Local; Projectome Estimation with BlueMatter Anthony J. Sherbondy1 , Robert F, USA Abstract. Estimating the complete set of white matter fascicles (the projectome) from diffusion

  11. Tracking the Performance Evolution of Blue Gene Systems

    SciTech Connect (OSTI)

    Kerbyson, Darren J.; Barker, Kevin J.; Gallo, Diego S.; Chen, Dong; Brunheroto, Jose R.; Ryu, Kyung D.; Chiu, George L.; Hoisie, Adolfy

    2013-06-17

    — IBM’s Blue Gene supercomputer has evolved through three generations from the original Blue Gene/L to P to Q. A higher level of integration has enabled greater single-core performance, and a larger concurrency per compute node. Although these changes have brought with them a higher overall system peak-performance, no study has examined in detail the evolution of perfor-mance across system generations. In this work we make two significant contri-butions – that of providing a comparative performance analysis across Blue Gene generations using a consistent set of tests, and also in providing a validat-ed performance model of the NEK-Bone proxy application. The combination of empirical analysis and the predictive performance model enable us to not only directly compare measured performance but also allow for a comparison of sys-tem configurations that cannot currently be measured. We provide insights into how the changing characteristics of Blue Gene have impacted on the application performance, as well as what future systems may be able to achieve.

  12. Report of the Blue Ribbon Panel on the Review of the Radiation...

    Energy Savers [EERE]

    Blue Ribbon Panel on the Review of the Radiation Effects Research Foundation Report of the Blue Ribbon Panel on the Review of the Radiation Effects Research Foundation October 11,...

  13. Weihai Blue Star Glass Holding Co Ltd aka Shandong Lanxing Glass...

    Open Energy Info (EERE)

    Blue Star Glass Holding Co Ltd aka Shandong Lanxing Glass Group Co Ltd Jump to: navigation, search Name: Weihai Blue Star Glass Holding Co Ltd (aka Shandong Lanxing Glass Group Co...

  14. Blue fan palm distribution and seed removal patterns in three desert oases of northern Baja California, Mexico

    E-Print Network [OSTI]

    Wehncke, Elisabet V.; López-Medellín, Xavier; Ezcurra, Exequiel

    2010-01-01

    DOI 10.1007/s11258-009-9682-4 Blue fan palm distribution anddistribution patterns of the blue fan palm, Brahea armata,evaluating (i) the levels of blue fan palm seed removal by

  15. Seems a Fate in It: Misdirection and Foreshadowing in Bleak House and A Pair of Blue Eyes

    E-Print Network [OSTI]

    Bradfield, Meredith

    2013-01-01

    for Action in A Pair of Blue Eyes. ” English Literature in2013). Hardy, Thomas. A Pair of Blue Eyes. Harmondsworth,aware of Thomas Hardy. A Pair of Blue Eyes. (Harmondsworth,

  16. De novo design and spectroscopic characterization of Cu(II)-binding peptides based upon the blue copper protein plastocyanin 

    E-Print Network [OSTI]

    Daugherty, Roxanne Gail

    2002-01-01

    those spectroscopic properties. Most blue copper proteins are similar to either plastocyanin or azurin, the best characterized of the blue copper proteins. All blue copper proteins contain a coordination site where Cu(II) is bound in a trigonal plane...

  17. ULAS J141623.94+134836.3: A BLUE T DWARF COMPANION TO A BLUE L DWARF

    E-Print Network [OSTI]

    Burgasser, Adam J.

    We confirm the substellar nature of ULAS J141623.94+134836.3 (aka SDSS J1416+1348B), a common proper motion companion to the blue L dwarf SDSS J141624.08+134826.7 identified by Burningham et al. and Scholz. Low-resolution ...

  18. T-651: Blue Coat ProxySG Discloses Potentially Sensitive Information in Core Files

    Broader source: Energy.gov [DOE]

    A vulnerability was reported in Blue Coat ProxySG. A local user can obtain potentially sensitive information

  19. Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer

    E-Print Network [OSTI]

    2008-01-01

    MASSIVELY-PARALLEL ELECTRICAL-CONDUCTIVITY IMAGING OFconsiderable attention for electrical conductivity mappingand anisotropic (blue) electrical conductivity. Fig. 1 Fig.

  20. T-720: Blue Coat Director HTTP Trace Processing Flaw Permits Cross-Site Scripting Attacks

    Office of Energy Efficiency and Renewable Energy (EERE)

    A vulnerability was reported in Blue Coat Director. A remote user can conduct cross-site scripting attacks.

  1. The Design and Investigation of the Self-Assembly of Dimers with two Nematic Phases

    E-Print Network [OSTI]

    Z. Ahmed; C. Welch; G. H. Mehl

    2015-09-06

    A series of non-symmetric dimers were synthesised containing either cyanobiphenyl or difluoroterphenyl moieties on one side and a range of long, short, bent, polar or apolar mesogens on the other side of the molecules. The dielectric anisotropy of the mesogens was varied systematically. The systems were characterised by differential scanning calorimetry (DSC), optical polarizing microscopy (OPM) and detailed X-ray diffraction (XRD) studies, both in the nematic and the Nx phase. The results are compared and structure properties relationships are discussed. A model for the assembly in the Nx phase is developed discussing Ntb structures, coaxial helices, swiss roll structures and chiral domain formation.

  2. Directed transport in equilibrium : analysis of the dimer model with inertial terms

    E-Print Network [OSTI]

    A. Bhattacharyay

    2011-08-15

    We have previously shown an analysis of our dimer model in the over-damped regime to show directed transport in equilibrium. Here we analyze the full model with inertial terms present to establish the same result. First we derive the Fokker-Planck equation for the system following a Galilean transformation to show that a uniformly translating equilibrium distribution is possible. Then, we find out the velocity selection for the centre of mass motion using that distribution on our model. We suggest generalization of our calculations for soft collision potentials and indicate to interesting situation with possibility of oscillatory non-equilibrium state within equilibrium.

  3. Enhanced dimer relaxation in an atomic and molecular Bose-Einstein condensate

    SciTech Connect (OSTI)

    Braaten, Eric; Hammer, H.-W.

    2004-10-01

    We derive a universal formula for the rate constant {beta} for relaxation of a shallow dimer into deeply-bound diatomic molecules in the case of atoms with a large scattering length a. We show that {beta} is determined by a and by 2 three-body parameters that also determine the binding energies and widths of Efimov states. The rate constant {beta} scales like ({Dirac_h}/2{pi})a/m near the resonance, but the coefficient is a periodic function of ln(a) that may have resonant enhancement at values of a that differ by multiples of 22.7.

  4. Spectroscopic accuracy directly from quantum chemistry: application to ground and excited states of beryllium dimer

    E-Print Network [OSTI]

    Sharma, Sandeep; Booth, George H; Umrigar, C J; Chan, Garnet Kin-Lic

    2014-01-01

    We combine explicit correlation via the canonical transcorrelation approach with the density matrix renormalization group and initiator full configuration interaction quantum Monte Carlo methods to compute a near-exact beryllium dimer curve, {\\it without} the use of composite methods. In particular, our direct density matrix renormalization group calculations produce a well-depth of $D_e$=931.2 cm$^{-1}$ which agrees very well with recent experimentally derived estimates $D_e$=929.7$\\pm 2$~cm$^{-1}$ [Science, 324, 1548 (2009)] and $D_e$=934.6~cm$^{-1}$ [Science, 326, 1382 (2009)

  5. Covalent features in the hydrogen bond of a water dimer: molecular orbital analysis

    E-Print Network [OSTI]

    Wang, Bo; Dai, Xing; Gao, Yang; Wang, Zhigang; Zhang, Rui-Qin

    2015-01-01

    The covalent-like characteristics of hydrogen bonds offer a new perspective on intermolecular interactions. Here, using density functional theory and post-Hartree-Fock methods, we reveal that there are two bonding molecular orbitals (MOs) crossing the O and H atoms of the hydrogen-bond in water dimer. Energy decomposition analysis also shows a non-negligible contribution of the induction term. These results illustrate the covalent-like character of the hydrogen bond between water molecules, which contributes to the essential understanding of ice, liquid water, related materials, and life sciences.

  6. Formation of Radioactive Citrulline During Photosynthetic C14O2-Fixation by Blue-Green Algae

    E-Print Network [OSTI]

    Linko, Pekka; Holm-Hansen, O.; Bassham, J.A.; Calvin, M.

    1956-01-01

    ClTRULLlNE BY BLUE-GREEN ALGAE TWO-WEEK LOAN COPY This is aC~~O~-FIXATION BLUE-GREEN ALGAE Pekka Linko, 0. Holm-Hansen,C~~O~-FIXATION BLUE-GREEN ALGAE BY Pelcka Linlc~,'~ Holm-

  7. Generation of Blue Noise Arrays by Genetic Algorithm Jeffrey Newbern and V. Michael Bove, Jr.

    E-Print Network [OSTI]

    Bove Jr., V. Michael

    Generation of Blue Noise Arrays by Genetic Algorithm Jeffrey Newbern and V. Michael Bove, Jr for generating blue­noise threshold arrays which do not appear regular, and offer the visual advantages of error or output device characteristics. We present instead a genetic method for generating a blue­noise threshold

  8. JUVENILE BLUE CRAB, CALLINECTES SAPIDUS, SURVIVAL: AN EVALUATION OF EELGRASS, ZOSTERA MARINA, AS REFUGE

    E-Print Network [OSTI]

    JUVENILE BLUE CRAB, CALLINECTES SAPIDUS, SURVIVAL: AN EVALUATION OF EELGRASS, ZOSTERA MARINA to examine rates ofpredation on juvenile blue crabs in different den- sities of eelgrass near Manahawkin, New provided the best refuge for blue crabs while crabs in low- and high-density eelgrass suffered higher rates

  9. Where the Blue Stragglers Roam: Searching for a Link Between Formation and Environment

    E-Print Network [OSTI]

    Nathan Leigh; Alison Sills; Christian Knigge

    2008-08-15

    The formation of blue stragglers is still not completely understood, particularly the relationship between formation environment and mechanism. We use a large, homogeneous sample of blue stragglers in the cores of 57 globular clusters to investigate the relationships between blue straggler populations and their environments. We use a consistent definition of "blue straggler" based on position in the color-magnitude diagram, and normalize the population relative to the number of red giant branch stars in the core. We find that the previously determined anti-correlation between blue straggler frequency and total cluster mass is present in the purely core population. We find some weak correlations with central velocity dispersion and with half-mass relaxation time. The blue straggler frequency does not show any trend with any other cluster parameter. Even though collisions may be expected to be a dominant blue straggler formation process in globular cluster cores, we find no correlation between the frequency of blue stragglers and the collision rate in the core. We also investigated the blue straggler luminosity function shape, and found no relationship between any cluster parameter and the distribution of blue stragglers in the color-magnitude diagram. Our results are inconsistent with some recent models of blue straggler formation that include collisional formation mechanisms, and may suggest that almost all observed blue stragglers are formed in binary systems.

  10. Strong blue emission from anodic alumina membranes with ordered nanopore array

    E-Print Network [OSTI]

    Chen, Haydn H.

    Strong blue emission from anodic alumina membranes with ordered nanopore array G. S. Huang, X. L by anodization in oxalic acid showed a strong PL peak in the blue. Due to an obvious asymmetry, the PL peak can that the two blue PL bands originate from optical transitions in two kinds of different oxygen-deficient defect

  11. n commenting on the recent chess match between Garry Kasparov and Deep Blue, IBM

    E-Print Network [OSTI]

    Munakata, Toshinori

    OnSite Viewpoint n commenting on the recent chess match between Garry Kasparov and Deep Blue, IBM literature even proclaimed, "The power behind Deep Blue is an IBM RS/6000 SP sys- tem finely tuned a somewhat different view of Deep Blue's prowess and its implica- tions for computing in general and AI

  12. Low voltage blue-phase liquid crystal displays Linghui Rao,1

    E-Print Network [OSTI]

    Wu, Shin-Tson

    Low voltage blue-phase liquid crystal displays Linghui Rao,1 Zhibing Ge,1 Shin-Tson Wu,1,a of the emerging blue-phase liquid crystal displays BP-LCDs . Simulation results indicate that the generated-effect-induced isotropic-to-anisotropic transition in blue-phase liquid crystal BPLC 1­6 has potential to become next

  13. BINARY BLUE METAL-POOR STARS: EVIDENCE FOR ASYMPTOTIC GIANT BRANCH MASS TRANSFER

    E-Print Network [OSTI]

    Cowan, John

    BINARY BLUE METAL-POOR STARS: EVIDENCE FOR ASYMPTOTIC GIANT BRANCH MASS TRANSFER Christopher Sneden We present new abundance analyses of six blue metal-poor (BMP) stars with very low iron abundances possess a small number of so-called blue stragglers--main-sequence stars that are clearly bluer

  14. In vitro culture and developmental cycle of the parasitic dinoflagellate Hematodinium sp. from the blue crab

    E-Print Network [OSTI]

    the blue crab Callinectes sapidus CAIWEN LI, TERRENCE L. MILLER, HAMISH J. SMALL and JEFFREY D. SHIELDS significant mortalities in marine crustacean fisheries worldwide. A species of Hematodinium infects the blue in blue crabs is unknown. We established several continuous in vitro cultures of Hematodinium sp. isolated

  15. Blue Oak Canopy Effect On Seasonal Forage Production and Quality1

    E-Print Network [OSTI]

    Blue Oak Canopy Effect On Seasonal Forage Production and Quality1 William E. Frost Neil K. Mc the canopy of blue oak (Quercus douglasii) and in open grassland at the San Joaquin Experimental Range blue oak compared to open grassland. At most sampling dates, the protein content was greater

  16. Photochemistry and Photobiology, 2004, 80: 542547 Purification and Initial Characterization of a Putative Blue

    E-Print Network [OSTI]

    Moffat, Keith

    of a Putative Blue Light­regulated Phosphodiesterase from Escherichia coli{ Sudarshan Rajagopal1 , Jason M. Key1, overexpressed and purified this protein, which we refer to as blue light­regulated phosphodi- esterase (Blrp on exposure to blue light. When overexpressed in E. coli, Blrp copurifies with certain proteins which suggests

  17. Effects of Shade on Blue Oak and Coast Live Oak Regeneration in California Annual Grasslands1

    E-Print Network [OSTI]

    Effects of Shade on Blue Oak and Coast Live Oak Regeneration in California Annual Grasslands1 manipulation. A split-plot, multifactorial experi ment was designed to test whether blue oak (Quercus douglasii herbaceous vegetation was not manipulated. Even under conditions of prolonged, severe drought, blue oaks

  18. RELATIONSHIPS OF THE BLUE SHARK, PRZONACE GLAUCA, AND ITS PREY SPECIES NEAR SANTA CATALINA ISLAND, CALIFORNIA'

    E-Print Network [OSTI]

    Tricas, Timothy C.

    RELATIONSHIPS OF THE BLUE SHARK, PRZONACE GLAUCA, AND ITS PREY SPECIES NEAR SANTA CATALINA ISLAND the major prey for the blue shark, Prionace glauca, near Santa Catalina Island, Calif. The northern anchovy to prey behavior. The blue shark,Prionace glauca (Carcharhinidae) (Figure 11,is a pelagic carnivore

  19. BLUE COMPACT DWARFS AT z ! 1: IMPLICATIONS FOR GALAXY EVOLUTION AND

    E-Print Network [OSTI]

    BLUE COMPACT DWARFS AT z ! ¸1: IMPLICATIONS FOR GALAXY EVOLUTION AND THE STAR FORMATION HISTORY of faint blue compact galaxies (BCGs) at redshifts z ¸ 0:2 \\Gamma 1:3. Most distant BCGs have masses M ¸8 Gyrs?. This population may be closely related to the numerous faint blue galaxies observed in deep

  20. The blue shark (Prionace glauca) is a large pelagic carcharhinid that is

    E-Print Network [OSTI]

    627 The blue shark (Prionace glauca) is a large pelagic carcharhinid that is widely distributedKenzie and Tibbo, 1964; Casey, 1982). In the Atlantic, the blue shark is distributed from Newfoundland to Argentina). There is strong evidence from tagging data and catch records that blue sharks in the North Atlantic constitute

  1. The blue shark (Prionace glauca) is an oceanic species that occurs in tem-

    E-Print Network [OSTI]

    720 The blue shark (Prionace glauca) is an oceanic species that occurs in tem- perate and tropical); numerically, the blue shark is the top nontarget species captured by the U.S. longline pelagic Atlantic fleet) on the catch rate of several target and bycatch species, including the blue shark. However, they did

  2. Blue quantum electroabsorption modulators based on reversed quantum confined Stark effect with blueshift

    E-Print Network [OSTI]

    Demir, Hilmi Volkan

    Blue quantum electroabsorption modulators based on reversed quantum confined Stark effect of blue quantum electroabsorption modulators that incorporate 5 nm thick In0.35Ga0.65N/GaN quantum cm-1 for 6 V bias swing around 424 nm, holding promise for blue optical clock generation

  3. BIOLOGY OF THE BLUE CRAB, CALLINECTES SAPIDUS RATHBUN, IN THE ST. JOHNS RIVER, FLORIDA

    E-Print Network [OSTI]

    BIOLOGY OF THE BLUE CRAB, CALLINECTES SAPIDUS RATHBUN,· IN THE ST. JOHNS RIVER, FLORIDA By MARLIN E ABSTRACT Blue crabs commonly mated from March to July and from October to December In the St. Johns River. Blue crabs spawned in the first 30 km. of river above the mouth, and the eggs hatched in the ocean

  4. A POSSIBLE LOCAL COUNTERPART TO THE EXCESS POPULATION OF FAINT BLUE GALAXIES

    E-Print Network [OSTI]

    McGaugh, Stacy

    A POSSIBLE LOCAL COUNTERPART TO THE EXCESS POPULATION OF FAINT BLUE GALAXIES STACY S. MCGAUGH of galaxies to very faint magnitudes have revealed a popu- lation of blue galaxies at intermediate redshift1 5 brightness galaxies have properties very similar to those of the excess blue population10;11, and re- cent

  5. GRC Transactions, Vol. 32, 2008 Blue Mountain, Nevada, structural control, normal fault,

    E-Print Network [OSTI]

    Faulds, James E.

    GRC Transactions, Vol. 32, 2008 273 Keywords Blue Mountain, Nevada, structural control, normal fault, oblique slip, dilatant zone, Great Basin AbstrAct The Blue Mountain geothermal field is a blind geothermal prospect (i.e., no surface hot springs) along the west flank of Blue Mountain in southern Humboldt

  6. Blue Shield ensures uninterrupted access to quality medical care after Palm Drive Hospital ceases operations

    E-Print Network [OSTI]

    Ravikumar, B.

    Blue Shield ensures uninterrupted access to quality medical care after Palm Drive Hospital ceases and inpatient services due to the hospital's bankruptcy filing. This closure affects Blue Shield HMO plan members who have been utilizing Palm Drive Hospital services. Please be advised that Blue Shield

  7. Blue and Gold Society Please Submit requests at least two weeks prior

    E-Print Network [OSTI]

    Jiang, Huiqiang

    Blue and Gold Society Please Submit requests at least two weeks prior to your event date Today: ____________________________ ___________________________________________ ___________________________________________ ___________________________________________ Assistance Required Number of Blue and Gold members needed: _______ Arrival Time: __: __ Departing Time: __: __ Blue and Gold Society attire: Formal (suit) Casual (rugby shirt) Other Any Additional Information

  8. Mysteries of the Deep: What happens inside of MPI on Blue

    E-Print Network [OSTI]

    Kemner, Ken

    Mysteries of the Deep: What happens inside of MPI on Blue Gene/Q and why it matters Jeff Hammond on BGQ #12;But not too deep Jeff Hammond PAMI and MPI on BGQ #12;Blue Gene/P Communication architecture Jeff Hammond PAMI and MPI on BGQ #12;Blue Gene/Q Communication architecture Jeff Hammond PAMI and MPI

  9. Blue MedicareRx (PDP)SM 2012 Comprehensive Drug List

    E-Print Network [OSTI]

    Oklahoma, University of

    Blue MedicareRx (PDP)SM 2012 Comprehensive Drug List PLEASE READ: THIS DOCUMENT CONTAINS DrugList Blue MedicareRx (PDP)SM 2012 Formulary (List of Covered Drugs) DrugList PLEASE READ. Blue MedicareRx (PDP) is a stand-alone prescription drug plan with a Medicare contract offered by HCSC

  10. Modeling blue and green water availability in Africa Jurgen Schuol,1,2

    E-Print Network [OSTI]

    Modeling blue and green water availability in Africa Ju¨rgen Schuol,1,2 Karim C. Abbaspour,1 Hong a semidistributed hydrological model SWAT (Soil and Water Assessment Tool), the freshwater components blue water. J. B. Zehnder (2008), Modeling blue and green water availability in Africa, Water Resour. Res., 44

  11. Writing for Blue Marble Richard Hollingham (V1 8-7-11)

    E-Print Network [OSTI]

    1 Writing for Blue Marble Richard Hollingham (V1 8-7-11) The competition To write a two page (1000 word) feature for the next issue of Blue Marble featuring work funded by/involving NCEO(see guidelines below) Entries will be judged by a panel led by Blue Marble Editor Richard Hollingham This internal

  12. Blue Whale Skeleton at the Seymour Marine Discovery Center at Long Marine Laboratory

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    Blue Whale Skeleton at the Seymour Marine Discovery Center at Long Marine Laboratory Arching 87 feet in length and rising 18 feet above the ground, the blue whale skeleton at the Seymour Center Ms. Blue and move her to the present Seymour Center. This seemed a perfect opportunity to perform

  13. Understanding Blue-to-Red Conversion in Monomeric Fluorescent Timers and Hydrolytic Degradation of Their

    E-Print Network [OSTI]

    Verkhusha, Vladislav V.

    Understanding Blue-to-Red Conversion in Monomeric Fluorescent Timers and Hydrolytic Degradation phenolate oxygen and the side chain hydroxyl of Ser146. In Blue102, a bulky side chain of Ile146 precludes-FT and Blue102 structures revealed hydrolytic degradation of the chromophores. In Fast-FT, chromophore

  14. APPENDIX B: Acrylamide; Chloroform; Ethidium bromide; Formaldehyde; and Trypan blue stain: UTHSCSA ROUTINE MOLECULAR LABORATORY PROCEDURAL USE

    E-Print Network [OSTI]

    Nicholson, Bruce J.

    APPENDIX B: Acrylamide; Chloroform; Ethidium bromide; Formaldehyde; and Trypan blue stain: UTHSCSA bromide; Formaldehyde; and Trypan blue stain: UTHSCSA ROUTINE MOLECULAR LABORATORY PROCEDURAL USE

  15. Magnetic coupling in neutral and charged Cr{sub 2}, Mn{sub 2}, and CrMn dimers

    SciTech Connect (OSTI)

    Desmarais, N. [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland)] [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland); Reuse, F. A. [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland)] [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland); Khanna, S. N. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    2000-04-01

    Theoretical ab initio studies of neutral, cationic and anionic Cr{sub 2}, Mn{sub 2}, and CrMn dimers have been carried out to explore the progression of magnetic coupling with the number of electrons. It is shown that while Cr{sub 2} and Cr{sub 2}{sup -} have antiferromagnetically coupled atomic spins, Cr{sub 2}{sup +} has a ferromagnetic ground state closely followed by an antiferromagnetic state. On the other hand, all Mn{sub 2} dimers are ferromagnetic, irrespective of the charge. The neutral CrMn is ferrimagnetic while the charged CrMn are antiferromagnetic. In all cases, the charged dimers are found to be more stable than the neutral ones. The results are compared with available calculations and experiments and the difficulties associated with theoretical description and the experimental interpretations are discussed. (c) 2000 American Institute of Physics.

  16. Adsorption of Ruthenium, Rhodium and Palladium from Simulated High-Level Liquid Waste by Highly Functional Xerogel - 13286

    SciTech Connect (OSTI)

    Onishi, Takashi [Fukushima Fuels and Materials Department O-arai Research and Development Center Japan Atomic Energy Agency, Narita-cho 4002, O-arai-machi, Ibaraki, 311-1393 (Japan)] [Fukushima Fuels and Materials Department O-arai Research and Development Center Japan Atomic Energy Agency, Narita-cho 4002, O-arai-machi, Ibaraki, 311-1393 (Japan); Koyama, Shin-ichi [Fukushima Fuels and Materials Department O-arai Research and Development Center Japan Atomic Energy Agency, Narita-cho 4002, O-arai-machi, Ibaraki, 311-1393 (Japan)] [Fukushima Fuels and Materials Department O-arai Research and Development Center Japan Atomic Energy Agency, Narita-cho 4002, O-arai-machi, Ibaraki, 311-1393 (Japan); Mimura, Hitoshi [Dept. of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University Aramaki-Aza-Aoba 6-6-01-2,Aoba-ku, Sendai-shi, Miyagi-ken, 980-8579 (Japan)] [Dept. of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University Aramaki-Aza-Aoba 6-6-01-2,Aoba-ku, Sendai-shi, Miyagi-ken, 980-8579 (Japan)

    2013-07-01

    Fission products are generated by fission reactions in nuclear fuel. Platinum group (Pt-G) elements, such as palladium (Pd), rhodium (Rh) and ruthenium (Ru), are also produced. Generally, Pt-G elements play important roles in chemical and electrical industries. Highly functional xerogels have been developed for recovery of these useful Pt-G elements from high - level radioactive liquid waste (HLLW). An adsorption experiment from simulated HLLW was done by the column method to study the selective adsorption of Pt-G elements, and it was found that not only Pd, Rh and Ru, but also nickel, zirconium and tellurium were adsorbed. All other elements were not adsorbed. Adsorbed Pd was recovered by washing the xerogel-packed column with thiourea solution and thiourea - nitric acid mixed solution in an elution experiment. Thiourea can be a poison for automotive exhaust emission system catalysts, so it is necessary to consider its removal. Thermal decomposition and an acid digestion treatment were conducted to remove sulfur in the recovered Pd fraction. The relative content of sulfur to Pd was decreased from 858 to 0.02 after the treatment. These results will contribute to design of the Pt-G element separation system. (authors)

  17. Vapor Synthesis and Thermal Modification of Supportless Platinum-Ruthenium Nanotubes and Application as Methanol Electrooxidation Catalysts

    SciTech Connect (OSTI)

    Atkinson III, Robert [University of Tennessee (UT); Unocic, Raymond R [ORNL; Unocic, Kinga A [ORNL; Veith, Gabriel M [ORNL; Papandrew, Alexander B [ORNL; Zawodzinski, Thomas A [ORNL

    2015-01-01

    Metallic, mixed-phase, and alloyed bimetallic Pt-Ru nanotubes were synthesized by a novel route based on the sublimation of metal acetylacetonate precursors and their subsequent vapor deposition within anodic alumina templates. Nanotube architectures were tuned by thermal annealing treatments. As-synthesized nanotubes are composed of nanoparticulate, metallic platinum and hydrous ruthenium oxide whose respective thicknesses depend on the sample chemical composition. The Pt-decorated, hydrous Ru oxide nanotubes may be thermally annealed to promote a series of chemical and physical changes to the nanotube structures including alloy formation, crystallite growth and morphological evolution. Annealed Pt-Ru alloy nanotubes and their as-synthesized analogs demonstrate relatively high specific activities for the oxidation of methanol. As-synthesized, mixed-phase Pt-Ru nanotubes (0.39 mA/cm2) and metallic alloyed Pt64Ru36NTs (0.33 mA/cm2) have considerably higher area-normalized activities than PtRu black (0.22 mA/cm2) at 0.65 V vs. RHE.

  18. Blue Ribbon Panel Recommendations Report Now Available | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Researchof Energy|Make6,Energy Blue Ribbon Panel

  19. Surface-Defects and Core Excitons at the (2x1) Asymmetric-Dimer (100) Surface of Si 

    E-Print Network [OSTI]

    BOWEN, MA; Allen, Roland E.; DOW, JD.

    1984-01-01

    VOLUME 30, NUMBER 8 15 OCTOBER 1984 Surface defects and core excitons at the (2X 1) asymmetric-dimer (100) surface of Si Marshall A. Bowen Department ofPhysics, Western Illinois University, Macomb, Illinois 61455 Roland E. Allen Department of... with 28 sp3- bonded substitutional defects, and (ii) energies of Hjalmarson-Frenkel core excitons 'at the (100) sur- face of Si, reconstructed according to Chadi s (2& 1) asymmetric-dimer model. The predictions sug- gest that P at. this surface should...

  20. Excitonic splitting and coherent electronic energy transfer in the gas-phase benzoic acid dimer

    SciTech Connect (OSTI)

    Ottiger, Philipp; Leutwyler, Samuel

    2012-11-28

    The benzoic acid dimer, (BZA){sub 2}, is a paradigmatic symmetric hydrogen bonded dimer with two strong antiparallel hydrogen bonds. The excitonic S{sub 1}/S{sub 2} state splitting and coherent electronic energy transfer within supersonically cooled (BZA){sub 2} and its {sup 13}C-, d{sub 1}-, d{sub 2}-, and {sup 13}C/d{sub 1}- isotopomers have been investigated by mass-resolved two-color resonant two-photon ionization spectroscopy. The (BZA){sub 2}-(h-h) and (BZA){sub 2}-(d-d) dimers are C{sub 2h} symmetric, hence only the S{sub 2} Leftwards-Arrow S{sub 0} transition can be observed, the S{sub 1} Leftwards-Arrow S{sub 0} transition being strictly electric-dipole forbidden. A single {sup 12}C/{sup 13}C or H/D isotopic substitution reduces the symmetry of the dimer to C{sub s}, so that the isotopic heterodimers (BZA){sub 2}-{sup 13}C, (BZA){sub 2}-(h-d), (BZA){sub 2}-(h{sup 13}C-d), and (BZA){sub 2}-(h-d{sup 13}C) show both S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} bands. The S{sub 1}/S{sub 2} exciton splitting inferred is {Delta}{sub exc}= 0.94 {+-} 0.1 cm{sup -1}. This is the smallest splitting observed so far for any H-bonded gas-phase dimer. Additional isotope-dependent contributions to the splittings, {Delta}{sub iso}, arise from the change of the zero-point vibrational energy upon electronic excitation and range from {Delta}{sub iso}= 3.3 cm{sup -1} upon {sup 12}C/{sup 13}C substitution to 14.8 cm{sup -1} for carboxy H/D substitution. The degree of excitonic localization/delocalization can be sensitively measured via the relative intensities of the S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} origin bands; near-complete localization is observed even for a single {sup 12}C/{sup 13}C substitution. The S{sub 1}/ S{sub 2} energy gap of (BZA){sub 2} is {Delta}{sub calc}{sup exc}=11 cm{sup -1} when calculated by the approximate second-order perturbation theory (CC2) method. Upon correction for vibronic quenching, this decreases to {Delta}{sub vibron}{sup exc}=2.1 cm{sup -1} [P. Ottiger et al., J. Chem. Phys. 136, 174308 (2012)], in good agreement with the observed {Delta}{sub exc}= 0.94 cm{sup -1}. The observed excitonic splittings can be converted to exciton hopping times {tau}{sub exc}. For the (BZA){sub 2}-(h-h) homodimer {tau}{sub exc}= 18 ps, which is nearly 40 times shorter than the double proton transfer time of (BZA){sub 2} in its excited state [Kalkman et al., ChemPhysChem 9, 1788 (2008)]. Thus, the electronic energy transfer is much faster than the proton-transfer in (BZA){sub 2}{sup *}.

  1. Composition Mixing during Blue Straggler Formation and Evolution

    E-Print Network [OSTI]

    Eric L. Sandquist; Michael Bolte; Lars Hernquist

    1996-09-25

    We use smoothed-particle hydrodynamics to examine differences between direct collisions of single stars and binary star mergers in their roles as possible blue straggler star formation mechanisms. We find in all cases that core helium in the progenitor stars is largely retained in the core of the remnant, almost independent of the type of interaction or the central concentration of the progenitor stars. We have also modelled the subsequent evolution of the hydrostatic remnants, including mass loss and energy input from the hydrodynamical interaction. The combination of the hydrodynamical and hydrostatic models enables us to predict that little mixing will occur during the merger of two globular cluster stars of equal mass. In contrast to the results of Proctor Sills, Bailyn, & Demarque (1995), we find that neither completely mixed nor unmixed models can match the absolute colors of observed blue stragglers in NGC 6397 at all luminosity levels. We also find that the color distribution is probably the crucial test for explanations of BSS formation - if stellar collisions or mergers are the correct mechanisms, a large fraction of the lifetime of the straggler must be spent away from the main sequence. This constraint appears to rule out the possibility of completely mixed models. For NGC 6397, unmixed models predict blue straggler lifetimes ranging from about 0.1 to 4 Gyr, while completely mixed models predict a range from about 0.6 to 4 Gyr.

  2. The birth of the blues : how physics underlies music.

    SciTech Connect (OSTI)

    Gibson, J. M.

    2009-07-01

    Art and science have intimate connections, although these are often underappreciated. Western music provides compelling examples. The sensation of harmony and related melodic development are rooted in physical principles that can be understood with simple mathematics. The focus of this review is not the better known acoustics of instruments, but the structure of music itself. The physical basis of the evolution of Western music in the last half millennium is discussed, culminating with the development of the 'blues'. The paper refers to a number of works which expand the connections, and introduces material specific to the development of the 'blues'. Several conclusions are made: (1) that music is axiomatic like mathematics and that to appreciate music fully listeners must learn the axioms; (2) that this learning does not require specific conscious study but relies on a linkage between the creative and quantitative brain and (3) that a key element of the musical 'blues' comes from recreating missing notes on the modern equal temperament scale. The latter is an example of 'art built on artifacts'. Finally, brief reference is made to the value of music as a tool for teaching physics, mathematics and engineering to non-scientists.

  3. Fast Luminous Blue Transients from Newborn Black Holes

    E-Print Network [OSTI]

    Kashiyama, Kazumi

    2015-01-01

    Newborn black holes in collapsing massive stars can be accompanied by a fallback disk. The accretion rate is typically super-Eddington and strong disk outflows are expected. Such outflows could be directly observed in some failed explosions of compact (blue supergiants or Wolf-Rayet stars) progenitors, and may be more common than long-duration gamma-ray bursts. Using an analytical model, we show that the fallback disk outflows produce blue UV-optical transients with a peak bolometric luminosity of ~10^(42-43) erg s^-1 (peak R-band absolute AB magnitudes of -16 to -18) and an emission duration of ~ a few to ~ 10 days. The spectra are likely dominated intermediate mass elements, but will lack much radioactive nuclei and iron-group elements. The above properties are broadly consistent with some of the rapid blue transients detected by Pan-STARRS and PTF. This scenario can be distinguished from alternative models using radio observations within a few years after the optical peak.

  4. Two-photon induced fabrication of gold microstructures in polystyrene sulfonate thin films using a ruthenium(II) dye as photoinitiator

    SciTech Connect (OSTI)

    Vurth, Laeticia; Baldeck, Patrice; Stephan, Olivier [Laboratoire de Spectrometrie Physique, Universite Joseph Fourier, CNRS (UMR 5588), BP 87, 38402 Saint Martin d'heres Cedex (France); Vitrant, Guy [Institut Microelectronique Electromagnetisme et Photonique, ENSERG-INPG, CNRS (UMR 5130), BP 257, 38016 Grenoble Cedex 1 (France)

    2008-04-28

    Gold microstructures are produced with a femtosecond laser in thin films of a polystyrene sulfonate matrix containing gold ions. Two-photon induced metal reduction is obtained by addition of 0.1 wt % of ruthenium(II)tris(bipyridine) in the formulation. Laser power is reduced to 5 mW, thereby limiting thermal effects. Lines of typically 150 nm heights and 1 {mu}m widths are fabricated as well as freestanding bidimensional structures. An additional electroless plating step produces gold structures with conductivities only ten times smaller than the bulk metal.

  5. 65USDA Forest Service Gen. Tech. Rep. PSW-GTR-160. 1997. Soil Characteristics of Blue Oak and

    E-Print Network [OSTI]

    65USDA Forest Service Gen. Tech. Rep. PSW-GTR-160. 1997. Soil Characteristics of Blue Oak and Coast, California, soils associated with blue oaks (Quercus douglasii) are slightly more acidic, have finer textures are richer in organic matter than those associated with blue oaks. Blue oaks seem to grow more frequently

  6. Temporal stability of blue phosphorescent organic light-emitting diodes affected by thermal annealing of emitting layers

    E-Print Network [OSTI]

    Chen, Shaw H.

    Temporal stability of blue phosphorescent organic light-emitting diodes affected by thermal morphological instability as part of the challenge to the PhOLED device lifetime. Introduction Blue. In addition to the need for efficient and stable blue emitters,1,2 the technological advances in blue Ph

  7. Blue carbon storage potential of marine carbonate deposits Project reference IAP/13/50. Please quote this reference when applying.

    E-Print Network [OSTI]

    Guo, Zaoyang

    IAPETUS Blue carbon storage potential of marine carbonate deposits Project reference IAP/13 Henrik Stahl, Scottish Association for Marine Science Key Words 1. Blue carbon 2. Carbonate 3. Coralline is referred to as `blue carbon' to differentiate it from terrestrial carbon stores. Known blue carbon sinks

  8. Fact Sheet on Toxic Blue-green Algae Carole A. Lembi Department of Botany and Plant Pathology

    E-Print Network [OSTI]

    Fact Sheet on Toxic Blue-green Algae Carole A. Lembi Department of Botany and Plant Pathology Purdue University What are blue-green algae? Blue-greens are very primitive organisms that are not really as "cyanobacteria" to acknowledge that they are bacteria. "Cyan" means "blue", which refers to the fact

  9. Relativistic ab initio treatment of the second-order spin-orbit splitting potential of rubidium and cesium dimers

    E-Print Network [OSTI]

    Kotochigova, Svetlana

    of rubidium and cesium dimers S. Kotochigova, E. Tiesinga, and P. S. Julienne National Institute of Standards. So far unacceptably large inelastic losses for cesium have prevented it from condensing 2 depolarization of room-temperature doubly polarized rubidium and cesium atoms 8 . In this pap

  10. Excitation Energy Transfer in Dimeric Light Harvesting Complex I: A Combined Streak-Camera/Fluorescence Upconversion Study

    E-Print Network [OSTI]

    van Stokkum, Ivo

    Excitation Energy Transfer in Dimeric Light Harvesting Complex I: A Combined Streak harvesting complex I, the peripheral light harvesting complex associated with photosystem I in green plants upconversion and synchroscan streak-camera measurements, revealed the energy transfer and decay of excitations

  11. A Fundamental Study on the [(?-Cl)3Mg2(THF)6]+ Dimer Electrolytes for Rechargeable Mg Batteries

    SciTech Connect (OSTI)

    Liu, Tianbiao L.; Cox, Jonathan T.; Hu, Dehong; Deng, Xuchu; Hu, Jian Z.; Hu, Mary Y.; Xiao, Jie; Shao, Yuyan; Tang, Keqi; Liu, Jun

    2015-01-01

    We present a fundamental study on [(?-Cl)3Mg2(THF)6]+dimer electrolytes using various physical methods including Subambient Pressure Ionization with Nanoelectrospray Mass spectrometry (SPIN-MS), Raman spectroscopy, 25Mg{1H} NMR, 27Al{1H} NMR and electrochemical analysis. For the first time, long time sought THF solvated [MgCl]+ species was experimentally characterized by SPIN mass spectrometry in the solution of the Mgdimer containing electrolyte, confirming the mono-Cl- abstraction reaction between MgCl2 and an Al Lewis acid. Solvated MgCl2 in the electrolyte was confirmed by Raman spectroscopy. The experimental results establish the previously proposed dimerization equilibrium of solvated [MgCl]+ and MgCl2 with [(?-Cl)3Mg2(THF)6]+. 25Mg{1H} NMR, 27Al{1H} NMR and electrochemical analysis on chloration reaction of [(?-Cl)3Mg2(THF)6]AlPh3Cl with external Cl- led to further insights on the coordination chemistry of the dimer electrolyte. Finally, a comprehensive mechanism is proposed for the reversible electrochemical Mg deposition and stripping and Mg2+ and Cl- ion transports of the Mg dimer electrolytes in rechargeable Mg batteries.

  12. Ultralow-power local laser control of the dimer density in alkali-metal vapors through photodesorption

    SciTech Connect (OSTI)

    Jha, Pankaj K.; Scully, Marlan O. [Texas A and M University, College Station, Texas 77843 (United States); Princeton University, Princeton, New Jersey 08544 (United States); Dorfman, Konstantin E. [Texas A and M University, College Station, Texas 77843 (United States); University of California, Irvine, Irvine, California 92697 (United States); Yi Zhenhuan; Yuan Luqi; Welch, George R. [Texas A and M University, College Station, Texas 77843 (United States); Sautenkov, Vladimir A. [Texas A and M University, College Station, Texas 77843 (United States); Joint Institute of High Temperature, RAS, Moscow 125412 (Russian Federation); Rostovtsev, Yuri V. [University of North Texas, Denton, Texas 76203 (United States); Zheltikov, Aleksei M. [Texas A and M University, College Station, Texas 77843 (United States); M.V. Lomonosov Moscow State University, Moscow 119992 (Russian Federation)

    2012-08-27

    Ultralow-power diode-laser radiation is employed to induce photodesorption of cesium from a partially transparent thin-film cesium adsorbate on a solid surface. Using resonant Raman spectroscopy, we demonstrate that this photodesorption process enables an accurate local optical control of the density of dimer molecules in alkali-metal vapors.

  13. Quantum Non-Demolition Detection of Polar Molecule Complexes: Dimers, Trimers, Tetramers

    E-Print Network [OSTI]

    Mekhov, Igor B

    2011-01-01

    The optical nondestructive method for in situ detection of the bound states of ultracold polar molecules is developed. It promises a minimally destructive measurement scheme up to a physically exciting quantum non-demolition (QND) level. The detection of molecular complexes beyond simple pairs of quantum particles (dimers, known, e.g., from the BEC-BCS theory) is suggested, including three-body (trimers) and four-body (tertramers) complexes trapped by one-dimensional tubes. The intensity of scattered light is sensitive to the molecule number fluctuations beyond the mean-density approximation. Such fluctuations are very different for various complexes, which leads to radically different light scattering. This type of research extends "quantum optics of quantum gases" to the field of ultracold molecules. Merging the quantum optical and ultracold gas problems will advance the experimental efforts towards the study of the light-matter interaction at its ultimate quantum level, where the quantizations of both ligh...

  14. Semiclassical molecular dynamics simulations of excited state double-proton transfer in 7-azaindole dimers

    SciTech Connect (OSTI)

    Guallar, V.; Batista, V.S.; Miller, W.H. [Department of Chemistry, University of California, and Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)] [Department of Chemistry, University of California, and Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

    1999-05-01

    An {ital ab initio} excited state potential energy surface is constructed for describing excited state double proton transfer in the tautomerization reaction of photo-excited 7-azaindole dimers, and the ultrafast dynamics is simulated using the semiclassical (SC) initial value representation (IVR). The potential energy surface, determined in a reduced dimensionality, is obtained at the CIS level of quantum chemistry, and an approximate version of the SC-IVR approach is introduced which scales {ital linearly} with the number of degrees of freedom of the molecular system. The accuracy of this approximate SC-IVR approach is verified by comparing our semiclassical results with full quantum mechanical calculations. We find that proton transfer usually occurs during the first intermonomer symmetric-stretch vibration, about 100 fs after photoexcitation of the system, and produces an initial 15 percent population decay of the reactant base-pair, which is significantly reduced by isotopic substitution. {copyright} {ital 1999 American Institute of Physics.} thinsp

  15. The retroviral RNA dimer linkage: different structures may reflect different roles

    E-Print Network [OSTI]

    Greatorex, Jane S.

    2004-08-18

    G G G C C CA C G C G U A C G G C A G C U G C A GA U G C G U A C G G C A C ..CCCGGG.. ..GGGCCC.. ..GACGUC.. ..CUGCAG.. VL30 ..UGUCUUGUC.. Human foamy virus ..UCCCUAGGGA.. Moloney murine leukaemia virus G A C G G C G C G U C G U A U A C G G U A A G A C... :5598-5604. 27. Lanchy JM, Lodmell JS: Alternate usage of two dimerization ini- tiation sites in HIV-2 viral RNA in vitro. J Mol Biol 2002, 319:637-648. 28. Griffin SD, Allen JF, Lever AM: The major human immunodefi- ciency virus type 2 (HIV-2) packaging signal...

  16. Spin-lattice relaxation within a dimerized Ising chain in a magnetic field

    SciTech Connect (OSTI)

    Erdem, R?za E-mail: rerdem29@hotmail.com; Gülp?nar, Gül; Yalç?n, Orhan; Pawlak, Andrzej

    2014-07-21

    A qualitative study of the spin-lattice relaxation within a dimerized Ising chain in a magnetic field is presented. We have first determined the time dependence of the deviation of the lattice distortion parameter ?? from the equilibrium state within framework of a technique combining the statistical equilibrium theory based on the transfer matrix method and the linear theory of irreversible thermodynamics. We have shown that the time dependence of the lattice distortion parameter is characterized by a single time constant (?) which diverges around the critical point in both dimerized (??0) and uniform (?=0) phase regions. When the temperature and magnetic field are fixed to certain values, the time ? depends only on exchange coupling between the spins. It is a characteristic time associated with the long wavelength fluctuations of distortion. We have also taken into account the effects of spatial fluctuations on the relaxation time using the full Landau-Ginzburg free energy functional. We have found an explicit expression for the relaxation time as a function of temperature, coupling constant and wave vector (q) and shown that the critical mode corresponds to the case q=0. Finally, our results are found to be in good qualitative agreement with the results obtained in recent experimental study on synchrotron x-ray scattering and muon spin relaxation in diluted material Cu{sub 1?y}Mg{sub y}GeO{sub 3} where the composition y is very close to 0.0209. These results can be considered as natural extensions of some previous works on static aspects of the problem.

  17. Dimer Structure of an Interfacially Impaired Phosphatidylinositol-Specific Pholpholipase C

    SciTech Connect (OSTI)

    Shao,C.; Shi, X.; Wehbi, H.; Zambonelli, C.; Head, J.; Seaton, B.; Roberts, M,.

    2007-01-01

    The crystal structure of the W47A/W242A mutant of phosphatidylinositol-specific phospholipase C (PI-PLC) from Bacillus thuringiensis has been solved to 1.8{angstrom} resolution. The W47A/W242A mutant is an interfacially challenged enzyme, and it has been proposed that one or both tryptophan side chains serve as membrane interfacial anchors (Feng, J., Wehbi, H., and Roberts, M. F. (2002) J. Biol. Chem. 277, 19867-19875). The crystal structure supports this hypothesis. Relative to the crystal structure of the closely related (97% identity) wild-type PI-PLC from Bacillus cereus, significant conformational differences occur at the membrane-binding interfacial region rather than the active site. The Trp {yields} Ala mutations not only remove the membrane-partitioning aromatic side chains but also perturb the conformations of the so-called helix B and rim loop regions, both of which are implicated in interfacial binding. The crystal structure also reveals a homodimer, the first such observation for a bacterial PI-PLC, with pseudo-2-fold symmetry. The symmetric dimer interface is stabilized by hydrophobic and hydrogen-bonding interactions, contributed primarily by a central swath of aromatic residues arranged in a quasiherringbone pattern. Evidence that interfacially active wild-type PI-PLC enzymes may dimerize in the presence of phosphatidylcholine vesicles is provided by fluorescence quenching of PI-PLC mutants with pyrene-labeled cysteine residues. The combined data suggest that wild-type PI-PLC can form similar homodimers, anchored to the interface by the tryptophan and neighboring membrane-partitioning residues.

  18. Structure of a Longitudinal Actin Dimer Assembled by Tandem W Domains: Implications for Actin Filament Nucleation

    SciTech Connect (OSTI)

    Rebowski, Grzegorz; Namgoong, Suk; Boczkowska, Malgorzata; Leavis, Paul C.; Navaza, Jorge; Dominguez, Roberto

    2013-11-20

    Actin filament nucleators initiate polymerization in cells in a regulated manner. A common architecture among these molecules consists of tandem WASP homology 2 domains (W domains) that recruit three to four actin subunits to form a polymerization nucleus. We describe a low-resolution crystal structure of an actin dimer assembled by tandem W domains, where the first W domain is cross-linked to Cys374 of the actin subunit bound to it, whereas the last W domain is followed by the C-terminal pointed end-capping helix of thymosin {beta}4. While the arrangement of actin subunits in the dimer resembles that of a long-pitch helix of the actin filament, important differences are observed. These differences result from steric hindrance of the W domain with intersubunit contacts in the actin filament. We also determined the structure of the first W domain of Vibrio parahaemolyticus VopL cross-linked to actin Cys374 and show it to be nearly identical with non-cross-linked W-Actin structures. This result validates the use of cross-linking as a tool for the study of actin nucleation complexes, whose natural tendency to polymerize interferes with most structural methods. Combined with a biochemical analysis of nucleation, the structures may explain why nucleators based on tandem W domains with short inter-W linkers have relatively weak activity, cannot stay bound to filaments after nucleation, and are unlikely to influence filament elongation. The findings may also explain why nucleation-promoting factors of the Arp2/3 complex, which are related to tandem-W-domain nucleators, are ejected from branch junctions after nucleation. We finally show that the simple addition of the C-terminal pointed end-capping helix of thymosin {beta}4 to tandem W domains can change their activity from actin filament nucleation to monomer sequestration.

  19. MOLYBDENUM, RUTHENIUM, AND THE HEAVY r-PROCESS ELEMENTS IN MODERATELY METAL-POOR MAIN-SEQUENCE TURNOFF STARS

    SciTech Connect (OSTI)

    Peterson, Ruth C. [Astrophysical Advances, 607 Marion Place, Palo Alto, CA 94301 (United States)

    2013-05-01

    The ratios of elemental abundances observed in metal-poor stars of the Galactic halo provide a unique present-day record of the nucleosynthesis products of its earliest stars. While the heaviest elements were synthesized by the r- and s-processes, dominant production mechanisms of light trans-ironic elements were obscure until recently. This work investigates further our 2011 conclusion that the low-entropy regime of a high-entropy wind (HEW) produced molybdenum and ruthenium in two moderately metal-poor turnoff stars that showed extreme overabundances of those elements with respect to iron. Only a few, rare nucleosynthesis events may have been involved. Here we determine abundances for Mo, Ru, and other trans-Fe elements for 28 similar stars by matching spectral calculations to well-exposed near-UV Keck HIRES spectra obtained for beryllium abundances. In each of the 26 turnoff stars with Mo or Ru line detections and no evidence for s-process production (therefore old), we find Mo and Ru to be three to six times overabundant. In contrast, the maximum overabundance is reduced to factors of three and two for the neighboring elements zirconium and palladium. Since the overproduction peaks sharply at Mo and Ru, a low-entropy HEW is confirmed as its origin. The overabundance level of the heavy r-process elements varies significantly, from none to a factor of four, but is uncorrelated with Mo and Ru overabundances. Despite their moderate metallicity, stars in this group trace the products of different nucleosynthetic events: possibly very few events, possibly events whose output depended on environment, metallicity, or time.

  20. Blue-green phosphor for fluorescent lighting applications

    DOE Patents [OSTI]

    Srivastava, Alok; Comanzo, Holly; Manivannan, Venkatesan; Setlur, Anant Achyut

    2005-03-15

    A fluorescent lamp including a phosphor layer including Sr.sub.4 Al.sub.14 O.sub.25 :Eu.sup.2+ (SAE) and at least one of each of a red, green and blue emitting phosphor. The phosphor layer can optionally include an additional, deep red phosphor and a yellow emitting phosphor. The resulting lamp will exhibit a white light having a color rendering index of 90 or higher with a correlated color temperature of from 2500 to 10000 Kelvin. The use of SAE in phosphor blends of lamps results in high CRI light sources with increased stability and acceptable lumen maintenance over, the course of the lamp life.

  1. Blue Gene/Q | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download original

  2. Blue: Pre-release of DOE Implementation Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download5 B O N N6

  3. Bradbury Science Museum partnering in national Blue Star Museums program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &Bradbury Science Museum - Science on Wheels OurMuseumMuseumBlue

  4. BlueEarth Biofuels LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossence Jump to: navigation,Bloomer ElectricBlueEarth

  5. China National BlueStar Group Corporation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to:Changing WorldCalifornia:DialogueNewShare HomeBlueStar

  6. Subject: Ames Blue Alert - X-ray Shutter Maintenance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect PhotovoltaicsStructure andChallenge |StudyingRecovery act-funded Ames Blue

  7. BluePlanet Capital LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois: EnergyHills, Connecticut:NgBlueFire Ethanol

  8. BlueSol Solar Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois: EnergyHills, Connecticut:NgBlueFire

  9. City of Blue Hill, Nebraska (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIRChurch Point,Blue Hill, Nebraska (Utility Company) Jump to:

  10. City of Blue Mound, Kansas (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIRChurch Point,Blue Hill, Nebraska (Utility Company) Jump

  11. Blue Ridge Electric Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:Blue Ridge Electric

  12. Blue Ridge Renewable Energy LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:Blue RidgeRenewable

  13. Blue Ridge, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:Blue

  14. Blue Sky Green Field Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:BlueBio Fuels Jump

  15. Blue Spruce Farm Ana Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:BlueBio FuelsSpruce

  16. Blue Star Energy Services (Maryland) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:BlueBio

  17. Blue Star Energy Services (Pennsylvania) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin:Pontiac Biomass Facility JumpIICalifornia:BlueBioStar Energy

  18. Transverse spin freezing in Ruthenium-doped a Fe 90 Zr 10 Physics Department and Centre for the Physics of Materials, McGill University, 3600 University Street, Montreal, Quebec

    E-Print Network [OSTI]

    Ryan, Dominic

    Transverse spin freezing in Ruthenium-doped a Fe 90 Zr 10 D.H. Ryan Physics Department and Centre , followed by transverse spin freezing at Txy . Comparison with earlier Mossbauer data shows that the break in B hf (T) is indeed due to transverse spin freezing, and that both Mossbauer spectroscopy and #22;SR

  19. Transverse spin freezing in ruthenium-doped a-Fe90Zr10 Physics Department and Centre for the Physics of Materials, McGill University, 3600 University Street,

    E-Print Network [OSTI]

    Ryan, Dominic

    Transverse spin freezing in ruthenium-doped a-Fe90Zr10 D. H. Ryan Physics Department and Centre at Tc , followed by transverse spin freezing at Txy . Comparison with earlier Mo¨ssbauer data shows that the break in Bhf(T) is indeed due to transverse spin freezing, and that both Mo¨ssbauer spectroscopy and SR

  20. Pink Ribbons, Blue Moons, and Silver Linings: Communicating, Coping, and Caring

    E-Print Network [OSTI]

    Kunkel, Adrianne; Dennis, Michael Robert; Keyton, Joann

    2010-01-01

    Kunkel, A., Dennis, M. R., & Keyton, J. (2010). Pink ribbons, blue moons, and silver linings: Communicating, coping, and caring. Health Communication, 25, 583-584. Publisher’s official version: http://dx.doi.org/10.1080/10410236.2010.496825. Open...). Pink ribbons, blue moons, and silver linings: Communicating, coping, and caring. Health Communication, 25, 583-584. Text of paper: Pink Ribbons, Blue Moons, and Silver Linings: Communicating, Coping, and Caring Adrianne Kunkel, University...

  1. ULAS J141623.94+134836.3: A BLUE T DWARF COMPANION TO A BLUE L DWARF

    SciTech Connect (OSTI)

    Burgasser, Adam J.; Looper, Dagny; Rayner, John T.

    2010-06-15

    We confirm the substellar nature of ULAS J141623.94+134836.3 (aka SDSS J1416+1348B), a common proper motion companion to the blue L dwarf SDSS J141624.08+134826.7 identified by Burningham et al. and Scholz. Low-resolution 0.8-2.4 {mu}m spectroscopy obtained with the Infrared Telescope Facility/SpeX shows strong H{sub 2}O and CH{sub 4} absorption bands, consistent with a T7.5 spectral type, and we see possible indications of NH{sub 3} absorption in the 1.0-1.3 {mu}m region. More importantly, the spectrum of SDSS J1416+1348B shows a broadened Y-band peak and highly suppressed K-band flux, both indicative of high surface gravity and/or subsolar metallicity. These traits are verified through spectral model fits, from which we derive atmospheric parameters T{sub eff} = 650 {+-} 60 K, log g = 5.2 {+-} 0.4 cgs, [M/H] {<=} -0.3, and K{sub zz} = 10{sup 4} cm{sup 2} s{sup -1}, the temperature being significantly warmer than that estimated by Burningham et al. These fits also indicate a model-dependent spectroscopic distance of 10.6{sup +3.0}{sub -2.8} pc for SDSS J1416+1348B, formally consistent with the 7.9 {+-} 1.7 pc astrometric distance for SDSS J1416+1348A from Scholz. The common peculiarities of these two co-spatial, co-moving sources suggest that their unusual blue colors-and those of other blue L and T dwarfs in general-arise from age/gravity or metallicity effects, rather than cloud properties alone.

  2. AN ECLIPSING BLUE STRAGGLER IN THE GLOBULAR CLUSTER {omega} CENTAURI

    SciTech Connect (OSTI)

    Li Kai; Qian Shengbang, E-mail: likai@ynao.ac.cn [National Astronomical Observatories/Yunnan Observatory, Chinese Academy of Sciences, P.O. Box 110, 650011 Kunming (China)

    2012-12-01

    {omega} Centauri is the largest globular cluster in the Milky Way and hence contains the largest number of variable stars within a single cluster. The results of photometric solutions are presented for the EA-type binary V239 in this cluster. According to our analysis, V239 is a typical Algol-type binary. We obtain M = 1.20 {+-} 0.10 M{sub Sun }, R = 1.21 {+-} 0.03 R{sub Sun }, and L = 13.68 {+-} 0.63 L{sub Sun} for the primary component. The secondary component has M = 0.07 {+-} 0.02 M{sub Sun }, R = 0.90 {+-} 0.03 R{sub Sun }, and L = 2.17 {+-} 0.14 L{sub Sun }. The binary system is located in the blue straggler region on the color-magnitude diagram of {omega} Centauri and the mass of the primary component exceeds the mass of a turnoff star. Therefore, we think that V239 is a blue straggler and that V239 was formed by mass transfer from the present secondary component to the present primary.

  3. DISCOVERY OF AN UNUSUALLY BLUE L DWARF WITHIN 10 pc OF THE SUN

    E-Print Network [OSTI]

    Burgasser, Adam J.

    We report the discovery of an unusually blue L5 dwarf within 10 pc of the Sun from a search of Sloan Digital Sky

  4. 2008 Regents University of California. All Rights Reserved RAMP Blue: Implementation

    E-Print Network [OSTI]

    Wawrzynek, John

    . Administration/ maintenance ports: · 10/100 Enet · HDMI/DVI · USB ~$6K (w/o FPGAs or DRAM or enclosure) RAMP Blue

  5. Secretary Moniz's Remarks on "A Look Back on the Blue Ribbon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secretary Moniz's Remarks on "A Look Back on the Blue Ribbon Commission on America's Nuclear Future" at the Bipartisan Policy Center -- As Delivered Secretary Moniz's Remarks on "A...

  6. 2014 Race to Zero Student Design Competition: Auburn University Profile (Blue)

    Broader source: Energy.gov [DOE]

    2014 Race to Zero Student Design Competition: Auburn University Profile (Blue), as posted on the U.S. Department of Energy website.

  7. Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer

    E-Print Network [OSTI]

    2008-01-01

    CONDUCTIVITY IMAGING OF HYDROCARBONS USING THE BLUE GENE/Lidentification of hydrocarbon filled layers in deepwater,”Remote sensing of hydrocarbon layers by seabed logging (

  8. The blue stragglers formed via mass transfer in old open clusters

    E-Print Network [OSTI]

    B. Tian; L. Deng; Z. Han; X. B. Zhang

    2006-05-09

    In this paper, we present the simulations for the primordial blue stragglers in the old open cluster M67 based on detailed modelling of the evolutionary processes. The principal aim is to discuss the contribution of mass transfer between the components of close binaries to the blue straggler population in M67. First, we followed the evolution of a binary of 1.4M$_\\odot$+0.9M$_\\odot$. The synthetic evolutionary track of the binary system revealed that a primordial blue straggler had a long lifetime in the observed blue straggler region of color-magnitude diagram. Second, a grid of models for close binary systems experiencing mass exchange were computed from 1Gyr to 6Gyr in order to account for primordial blue-straggler formation in a time sequence. Based on such a grid, Monte-Carlo simulations were applied for the old open cluster M67. Adopting appropriate orbital parameters, 4 primordial blue stragglers were predicted by our simulations. This was consistent with the observational fact that only a few blue stragglers in M67 were binaries with short orbital periods. An upper boundary of the primordial blue stragglers in the color-magnitude diagram (CMD) was defined and could be used to distinguish blue stragglers that were not formed via mass exchange. Using the grid of binary models, the orbital periods of the primordial BSs could be predicted. Compared with the observations, it is clear that the mechanism discussed in this work alone cannot fully predict the blue straggler population in M67. There must be several other processes also involved in the formation of the observed blue stragglers in M67.

  9. Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-01

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for a phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.

  10. Frustrated smectic layer structures in bent-shaped dimer liquid crystals studied by x-ray microbeam diffraction

    SciTech Connect (OSTI)

    Takanishi, Yoichi; Toshimitsu, Megumi; Nakata, Michi; Takada, Naoki; Izumi, Tatsuya; Ishikawa, Ken; Takezoe, Hideo; Watanabe, Junji; Takahashi, Yumiko; Iida, Atsuo

    2006-11-15

    The layer structures in bent-shaped liquid crystal dimers mOAM5AMOm (m=6-16) have been investigated by x-ray microbeam diffraction. These liquid crystal molecules have two rodlike mesogens connected with an odd-numbered alkylene spacer and form a bent shape. In these compounds it is found that the structure changes from the single (m=6) to frustrated-layer structures (m=8, 10, and 12) and switchable frustrated-layer structures (m=14 and 16) with increasing terminal chain length. An anticlinic antiferroelectric structure is suggested in the compound with m=16, based on the different electric-field-induced reorientation behavior from those in the other dimers.

  11. Communication: Towards the binding energy and vibrational red shift of the simplest organic hydrogen bond: Harmonic constraints for methanol dimer

    SciTech Connect (OSTI)

    Heger, Matthias; Suhm, Martin A.; Mata, Ricardo A., E-mail: rmata@gwdg.de [Georg-August-Universität Göttingen, Institut für Physikalische Chemie, Tammannstr. 6, 37077 Göttingen (Germany)

    2014-09-14

    The discrepancy between experimental and harmonically predicted shifts of the OH stretching fundamental of methanol upon hydrogen bonding to a second methanol unit is too large to be blamed mostly on diagonal and off-diagonal anharmonicity corrections. It is shown that a decisive contribution comes from post-MP2 electron correlation effects, which appear not to be captured by any of the popular density functionals. We also identify that the major deficiency is in the description of the donor OH bond. Together with estimates for the electronic and harmonically zero-point corrected dimer binding energies, this work provides essential constraints for a quantitative description of this simple hydrogen bond. The spectroscopic dissociation energy is predicted to be larger than 18 kJ/mol and the harmonic OH-stretching fundamental shifts by about ?121 cm{sup ?1} upon dimerization, somewhat more than in the anharmonic experiment (?111 cm{sup ?1})

  12. LAMMPS strong scaling performance optimization on Blue Gene/Q

    SciTech Connect (OSTI)

    Coffman, Paul; Jiang, Wei; Romero, Nichols A.

    2014-11-12

    LAMMPS "Large-scale Atomic/Molecular Massively Parallel Simulator" is an open-source molecular dynamics package from Sandia National Laboratories. Significant performance improvements in strong-scaling and time-to-solution for this application on IBM's Blue Gene/Q have been achieved through computational optimizations of the OpenMP versions of the short-range Lennard-Jones term of the CHARMM force field and the long-range Coulombic interaction implemented with the PPPM (particle-particle-particle mesh) algorithm, enhanced by runtime parameter settings controlling thread utilization. Additionally, MPI communication performance improvements were made to the PPPM calculation by re-engineering the parallel 3D FFT to use MPICH collectives instead of point-to-point. Performance testing was done using an 8.4-million atom simulation scaling up to 16 racks on the Mira system at Argonne Leadership Computing Facility (ALCF). Speedups resulting from this effort were in some cases over 2x.

  13. Blue fluorescent organic light emitting diodes with multilayered graphene anode

    SciTech Connect (OSTI)

    Hwang, Joohyun [OLED Lighting Research Team, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of)] [OLED Lighting Research Team, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of); Choi, Hong Kyw [Graphene Electronics Creative Research Section, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of)] [Graphene Electronics Creative Research Section, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of); Moon, Jaehyun; Shin, Jin-Wook; Joo, Chul Woong; Han, Jun-Han; Cho, Doo-Hee; Huh, Jin Woo [OLED Lighting Research Team, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of)] [OLED Lighting Research Team, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of); Choi, Sung-Yool [Graphene Electronics Creative Research Section, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of)] [Graphene Electronics Creative Research Section, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of); Lee, Jeong-Ik, E-mail: jiklee@etri.re.kr [OLED Lighting Research Team, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of)] [OLED Lighting Research Team, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of); Chu, Hye Yong [OLED Lighting Research Team, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of)] [OLED Lighting Research Team, Electronics and Telecommunications Research Institute (ETRI), Daejeon 305-700 (Korea, Republic of)

    2012-10-15

    As an innovative anode for organic light emitting devices (OLEDs), we have investigated graphene films. Graphene has importance due to its huge potential in flexible OLED applications. In this work, graphene films have been catalytically grown and transferred to the glass substrate for OLED fabrications. We have successfully fabricated 2 mm × 2 mm device area blue fluorescent OLEDs with graphene anodes which showed 2.1% of external quantum efficiency at 1000 cd/m{sup 2}. This is the highest value reported among fluorescent OLEDs using graphene anodes. Oxygen plasma treatment on graphene has been found to improve hole injections in low voltage regime, which has been interpreted as oxygen plasma induced work function modification. However, plasma treatment also increases the sheet resistance of graphene, limiting the maximum luminance. In summary, our works demonstrate the practical possibility of graphene as an anode material for OLEDs and suggest a processing route which can be applied to various graphene related devices.

  14. Atomic geometry of mixed Ge-Si dimers in the initial-stage growth of Ge on Si,,001...2 1 X. Chen* and D. K. Saldin

    E-Print Network [OSTI]

    Saldin, Dilano

    Atomic geometry of mixed Ge-Si dimers in the initial-stage growth of Ge on Si,,001...2 1 X. Chen quantitatively the geometry of mixed Ge-Si dimers on a single domain Si 001 2 1 surface by azimuthal scanning core-level photoelectron diffraction. By analyzing Ge 3d diffraction patterns from Ge/Si 001 at 0.1 ML

  15. A Multinuclear Copper(I) Cluster Forms the Dimerization Interface in Copper-Loaded Human Copper Chaperone for Superoxide Dismutase

    SciTech Connect (OSTI)

    Stasser, J.P.; Siluvai, G.S.; Barry, A.N.; Blackburn, N.J.

    2009-06-04

    Copper binding and X-ray aborption spectroscopy studies are reported on untagged human CCS (hCCS; CCS = copper chaperone for superoxide dismutase) isolated using an intein self-cleaving vector and on single and double Cys to Ala mutants of the hCCS MTCQSC and CSC motifs of domains 1 (D1) and 3 (D3), respectively. The results on the wild-type protein confirmed earlier findings on the CCS-MBP (maltose binding protein) constructs, namely, that Cu(I) coordinates to the CXC motif, forming a cluster at the interface of two D3 polypeptides. In contrast to the single Cys to Ser mutations of the CCS-MBP protein (Stasser, J. P., Eisses, J. F., Barry, A. N., Kaplan, J. H., and Blackburn, N. J. (2005) Biochemistry 44, 3143-3152), single Cys to Ala mutations in D3 were sufficient to eliminate cluster formation and significantly reduce CCS activity. Analysis of the intensity of the Cu-Cu cluster interaction in C244A, C246A, and C244/246A variants suggested that the nuclearity of the cluster was greater than 2 and was most consistent with a Cu4S6 adamantane-type species. The relationship among cluster formation, oligomerization, and metal loading was evaluated. The results support a model in which Cu(I) binding converts the apo dimer with a D2-D2 interface to a new dimer connected by cluster formation at two D3 CSC motifs. The predominance of dimer over tetramer in the cluster-containing species strongly suggests that the D2 dimer interface remains open and available for sequestering an SOD1 monomer. This work implicates the copper cluster in the reactive form and adds detail to the cluster nuclearity and how copper loading affects the oligomerization states and reactivity of CCS for its partner SOD1.

  16. Luminous blue variables and superluminous supernovae from binary mergers

    SciTech Connect (OSTI)

    Justham, Stephen; Podsiadlowski, Philipp; Vink, Jorick S. E-mail: podsi@astro.ox.ac.uk

    2014-12-01

    Evidence suggests that the direct progenitor stars of some core-collapse supernovae (CCSNe) are luminous blue variables (LBVs), perhaps including some Type II 'superluminous supernovae' (SLSNe). We examine models in which massive stars gain mass soon after the end of core hydrogen burning. These are mainly intended to represent mergers following a brief contact phase during early Case B mass transfer, but may also represent stars which gain mass in the Hertzsprung Gap or extremely late during the main-sequence phase for other reasons. The post-accretion stars spend their core helium-burning phase as blue supergiants (BSGs), and many examples are consistent with being LBVs at the time of core collapse. Other examples are yellow supergiants at explosion. We also investigate whether such post-accretion stars may explode successfully after core collapse. The final core properties of post-accretion models are broadly similar to those of single stars with the same initial mass as the pre-merger primary star. More surprisingly, when early Case B accretion does affect the final core properties, the effect appears likely to favor a successful SN explosion, i.e., to make the core properties more like those of a lower-mass single star. However, the detailed structures of these cores sometimes display qualitative differences to any single-star model we have calculated. The rate of appropriate binary mergers may match the rate of SNe with immediate LBV progenitors; for moderately optimistic assumptions we estimate that the progenitor birthrate is ?1% of the CCSN rate.

  17. Dynamics of water in prussian blue analogues: Neutron scattering study

    SciTech Connect (OSTI)

    Sharma, V. K.; Mitra, S.; Thakur, N.; Yusuf, S. M.; Mukhopadhyay, R.; Juranyi, Fanni

    2014-07-21

    Dynamics of crystal water in Prussian blue (PB), Fe(III){sub 4}[Fe(II)(CN){sub 6}]{sub 3}.14H{sub 2}O and its analogue Prussian green (PG), ferriferricynaide, Fe(III){sub 4}[Fe(III)(CN){sub 6}]{sub 4}.16H{sub 2}O have been investigated using Quasielastic Neutron Scattering (QENS) technique. PB and its analogue compounds are important materials for their various interesting multifunctional properties. It is known that crystal water plays a crucial role towards the multifunctional properties of Prussian blue analogue compounds. Three structurally distinguishable water molecules: (i) coordinated water molecules at empty nitrogen sites, (ii) non-coordinated water molecules in the spherical cavities, and (iii) at interstitial sites exist in PB. Here spherical cavities are created due to the vacant sites of Fe(CN){sub 6} units. However, PG does not have any such vacant N or Fe(CN){sub 6} units, and only one kind of water molecules, exists only at interstitial sites. QENS experiments have been carried out on both the compounds in the temperature range of 260–360?K to elucidate the dynamical behavior of different kinds of water molecules. Dynamics is found to be much more pronounced in case of PB, compared to PG. A detailed data analysis showed that localized translational diffusion model could describe the observed data for both PB and PG systems. The average diffusion coefficient is found to be much larger in the PB than PG. The obtained domain of dynamics is found to be consistent with the geometry of the structure of the two systems. Combining the data of the two systems, a quantitative estimate of the dynamics, corresponding to the water molecules at different locations is made.

  18. Building on a Decade of Accomplishments Report of the 2010 Blue Ribbon Panel on Genomics

    E-Print Network [OSTI]

    Levin, Judith G.

    Building on a Decade of Accomplishments Report of the 2010 Blue Ribbon Panel on Genomics Division of Microbiology and Infectious Diseases, Genomics Programs National Institute of Allergy and Infectious Diseases Blue Ribbon Panel on Genomics Division of Microbiology and Infectious Diseases, Genomics Programs

  19. Seasonal Prevalence of Hematodinium sp. Infections of Blue Crabs in Three South Carolina (USA) Rivers

    E-Print Network [OSTI]

    Childress, Michael J.

    Seasonal Prevalence of Hematodinium sp. Infections of Blue Crabs in Three South Carolina (USA at an alarming rate. In South Carolina, these declines are significantly correlated with years of decreased (Atlantic States Marine Fisheries Commission 2004). In South Carolina, annual fishery landings of blue crabs

  20. Depth of cure and compressive strength of dental composites cured with blue light emitting diodes (LEDs)

    E-Print Network [OSTI]

    Ashworth, Stephen H.

    Depth of cure and compressive strength of dental composites cured with blue light emitting diodes with either a light emitting diode (LED) based light curing unit (LCU) or a conventional halogen LCU do reserved. Keywords: Blue light emitting diodes; Light curing unit; Composites; Irradiance; Spectrum; Depth

  1. Low temperature and high frequency effects on polymer-stabilized blue phase liquid crystals with

    E-Print Network [OSTI]

    Wu, Shin-Tson

    Low temperature and high frequency effects on polymer-stabilized blue phase liquid crystals*a and Yasuhiro Hasebab We report the low temperature and high frequency effects on polymer-stabilized blue phase temperature and high frequency operations are critical issues, especially for outdoor applications or color

  2. THE DUST RING OF LUMINOUS BLUE VARIABLE CANDIDATE HD 168625: INFRARED OBSERVATIONS AND MODEL CALCULATIONS1

    E-Print Network [OSTI]

    Speck, Angela Karen

    THE DUST RING OF LUMINOUS BLUE VARIABLE CANDIDATE HD 168625: INFRARED OBSERVATIONS AND MODEL surrounding the luminous blue variable (LBV) candidate HD 168625, together with new temperature and optical energy distribution of the dust. Therefore, HD 168625 is an excellent example of proposed models of LBV

  3. Quantum Non-Demolition Detection of Polar Molecule Complexes: Dimers, Trimers, Tetramers

    E-Print Network [OSTI]

    Igor B. Mekhov

    2011-11-16

    The optical nondestructive method for in situ detection of the bound states of ultracold polar molecules is developed. It promises a minimally destructive measurement scheme up to a physically exciting quantum non-demolition (QND) level. The detection of molecular complexes beyond simple pairs of quantum particles (dimers, known, e.g., from the BEC-BCS theory) is suggested, including three-body (trimers) and four-body (tertramers) complexes trapped by one-dimensional tubes. The intensity of scattered light is sensitive to the molecule number fluctuations beyond the mean-density approximation. Such fluctuations are very different for various complexes, which leads to radically different light scattering. This type of research extends "quantum optics of quantum gases" to the field of ultracold molecules. Merging the quantum optical and ultracold gas problems will advance the experimental efforts towards the study of the light-matter interaction at its ultimate quantum level, where the quantizations of both light and matter are equally important.

  4. Antiferromagnetic exchange in a bis(imido) uranium (V) dimeric complex

    SciTech Connect (OSTI)

    Spencer, Liam P [Los Alamos National Laboratory; Schelter, Eric J [Los Alamos National Laboratory; Boncella, James M [Los Alamos National Laboratory; Yang, Ping [Los Alamos National Laboratory; Gdula, Robyn L [NON LANL; Scott, Brian L [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory; Kiplinger, Jacqueline L [Los Alamos National Laboratory; Batista, Enrique R [Los Alamos National Laboratory

    2008-01-01

    Magnetic coupling between two or more metal centers is an important facet of d- and f-block transition metal chemistry due to its implications in chemical bonding. With respect to actinide metals, magnetic coupling between polymetallic actinide centers is less well-known. Of the few documented examples, only one bimetallic uranium(V) complex, [(MeC{sub 5}H{sub 4}){sub 2}U]{sub 2}[{mu}-1,4-N{sub 2}C{sub 6}H{sub 4}] (1), has unequivocally demonstrated antiferromagnetic coupling. This complex employs a {pi}-conjugated 1,4-phenylenedimide ligand system which bridges the two f{sup 1}-metal centers and enables antiferromagentic coupling between unpaired f-e1ectrons residing in a {pi}-symmetry orbital. In this communication, we report the synthesis of a dimeric bis(imido) uranium(V) iodide complex and demonstrate with magnetic susceptibility measurements and density functional theory (DFT) calculations that the f{sup 1}-uranium centers display antiferromagnetic coupling at low temperatures.

  5. Unbiased charge oscillations in DNA monomer-polymers and dimer-polymers

    E-Print Network [OSTI]

    Lambropoulos, Konstantinos; Morphis, Andreas; Kaklamanis, Konstantinos; Theodorakou, Marina; Simserides, Constantinos

    2015-01-01

    We call {\\it monomer} a B-DNA base-pair and examine, analytically and numerically, electron or hole oscillations in monomer- and dimer-polymers, i.e., periodic sequences with repetition unit made of one or two monomers. We employ a tight-binding (TB) approach at the base-pair level to readily determine the spatiotemporal evolution of a single extra carrier along a $N$ base-pair polymer. We study HOMO and LUMO eigenspectra as well as the mean over time probabilities to find the carrier at a particular monomer. We use the pure mean transfer rate $k$ to evaluate the easiness of charge transfer. The inverse decay length $\\beta$ for exponential fits $k(d)$, where $d$ is the charge transfer distance, and the exponent $\\eta$ for power law fits $k(N)$ are computed; generally power law fits are better. We illustrate that increasing the number of different parameters involved in the TB description, the fall of $k(d)$ or $k(N)$ becomes steeper and show the range covered by $\\beta$ and $\\eta$. Finally, both for the time-...

  6. Fermi Research Alliance, LLC BAHMO: Blue Cross and Blue Shield of Illinois Coverage Period: 01/01/2015 12/31/2015 Summary of Benefits and Coverage: What this Plan Covers & What it Costs Coverage for: ALL | Plan Type: HMO

    E-Print Network [OSTI]

    Fermilab Experiment E831

    1 of 8 Fermi Research Alliance, LLC BAHMO: Blue Cross and Blue Shield of Illinois Coverage Period or plan document for additional information about excluded services. #12;2 of 8 Fermi Research Alliance

  7. Stellar science from a blue wavelength range - A possible design for the blue arm of 4MOST

    E-Print Network [OSTI]

    Hansen, C J; Seifert, W; Koch, A; Xu, W; Caffau, E; Christlieb, N; Korn, A J; Lind, K; Sbordone, L; Ruchti, G; Feltzing, S; de Jong, R S; Barden, S; Schnurr, O

    2015-01-01

    From stellar spectra, a variety of physical properties of stars can be derived. In particular, the chemical composition of stellar atmospheres can be inferred from absorption line analyses. These provide key information on large scales, such as the formation of our Galaxy, down to the small-scale nucleosynthesis processes that take place in stars and supernovae. By extending the observed wavelength range toward bluer wavelengths, we optimize such studies to also include critical absorption lines in metal-poor stars, and allow for studies of heavy elements (Z>38) whose formation processes remain poorly constrained. In this context, spectrographs optimized for observing blue wavelength ranges are essential, since many absorption lines at redder wavelengths are too weak to be detected in metal-poor stars. This means that some elements cannot be studied in the visual-redder regions, and important scientific tracers and science cases are lost. The present era of large public surveys will target millions of stars. ...

  8. Anthem Blue Cross Life and Health Insurance Company (NP) 5/18/2012 Page 1 University of California

    E-Print Network [OSTI]

    Barrett, Jeffrey A.

    Anthem Blue Cross Life and Health Insurance Company (NP) 5/18/2012 Page 1 University of California as determined by Anthem Blue Cross. When using Non-PPO and Other Health Care Providers, insured persons

  9. JURO Application Editing Sample Please edit the following passage for style and content. Make edits in red or blue ink.

    E-Print Network [OSTI]

    Arnold, Jonathan

    in red or blue ink. American citizens eat unhealthily all the time. America increasing rely on foreign

  10. The blue crab Callinectes sapidus inhabits estuarine environments that range in salinity from full-strength sea water

    E-Print Network [OSTI]

    Kinsey, Stephen

    The blue crab Callinectes sapidus inhabits estuarine environments that range in salinity from full euryhaline organisms, blue crabs have evolved compensatory mechanisms to minimize perturbations to the intracellular environment during osmotic stress. While the hemolymph of blue crabs fluctuates iso- osmotically

  11. Do blue-ice moraines in the Heritage Range show the West Antarctic ice sheet survived the last interglacial?

    E-Print Network [OSTI]

    Do blue-ice moraines in the Heritage Range show the West Antarctic ice sheet survived the last in revised form 10 January 2011 Accepted 28 January 2011 Available online xxxx Keywords: Blue-ice moraine cosmogenic isotope data on blue-ice moraines in the Heritage Range, West Antarctica. The age of the moraines

  12. Insight into the Common Mechanism of the Chromophore Formation in the Red Fluorescent Proteins: The Elusive Blue

    E-Print Network [OSTI]

    Verkhusha, Vladislav V.

    : The Elusive Blue Intermediate Revealed Ksenia B. Bravaya, Oksana M. Subach, Nadezhda Korovina, Vladislav V calculations identifying the nature of a blue intermediate, a key species in the process of the red chromophore formation in DsRed, TagRFP, fluorescent timers, and PAmCherry. The chromophore of the blue intermediate has

  13. RELATIONSHIPS OF THE BLUE SHARK, PRIONACE GLAUCA, AND ITS PREY SPECIES NEAR SANTA CATALINA ISLAND, CALIFORNIA1

    E-Print Network [OSTI]

    RELATIONSHIPS OF THE BLUE SHARK, PRIONACE GLAUCA, AND ITS PREY SPECIES NEAR SANTA CATALINA ISLAND habitats composed the major prey for the blue shark, Prionace glauca, near Santa Catalina Island, Calif that predatory modes vary in response to prey behavior. The blue shark,Prionace glauca (Carcharhinidae) (Figure 1

  14. In situ cosmogenic radiocarbon production and 2-D ice flow line modeling for an Antarctic blue ice area

    E-Print Network [OSTI]

    Severinghaus, Jeffrey P.

    In situ cosmogenic radiocarbon production and 2-D ice flow line modeling for an Antarctic blue ice; accepted 12 April 2012; published 24 May 2012. [1] Radiocarbon measurements at ice margin sites and blue and 2-D ice flow line modeling for an Antarctic blue ice area, J. Geophys. Res., 117, F02029, doi:10

  15. lue light affects many aspects of plant growth and develop-ment. Plant blue-light responses include inhibition of

    E-Print Network [OSTI]

    Lin, Chentao

    B lue light affects many aspects of plant growth and develop- ment. Plant blue-light responses have identified three blue- light receptors: cryptochrome 1, cryptochrome 2 and phototropin, which of the cryptochromes Plant blue-light receptors have long been recognized from their action spectra to have roles

  16. Tunable blue light source by intracavity frequency doubling of a Cr-LiSrAIF6 laser

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Tunable blue light source by intracavity frequency doubling of a Cr- LiSrAIF6 laser Franqois-switched operation at 10 kHz was intracavity frequency doubled by using a LiIOl crystal. The 230 ns tunable blue lasers emitting in the blue-green wavelength range are expected to be the key components for optical

  17. A Pygmy Blue Whale (Cetacea: Balaenopteridae) in the Inshore Waters of New Caledonia1 Philippe Borsa2,3

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    A Pygmy Blue Whale (Cetacea: Balaenopteridae) in the Inshore Waters of New Caledonia1 Philippe 14, 9750 AA, Haren, The Netherlands. To be cited as: Borsa P., Hoarau G. 2004. A pygmy blue whale;Abstract: The occurrence of a blue whale is reported for the first time for the New Caledonian archipelago

  18. Blue Straggler Stars in Galactic Open Clusters and the effect of field star contamination

    E-Print Network [OSTI]

    G. Carraro; R. A. Vazquez; A. Moitinho

    2008-02-25

    We investigate the distribution of Blue Straggler stars in the field of three open star clusters. The main purpose is to highlight the crucial role played by general Galactic disk fore-/back-ground field stars, which are often located in the same region of the Color Magnitude Diagram as Blue Straggler stars. We analyze photometry taken from the literature of 3 open clusters of intermediate/old age rich in Blue Straggler stars, and which are projected in the direction of the Perseus arm, and study their spatial distribution and the Color Magnitude Diagram. As expected, we find that a large portion of the Blue Straggler population in these clusters are simply young field stars belonging to the spiral arm. This result has important consequences on the theories of the formation and statistics of Blue Straggler stars in different population environments: open clusters, globular clusters or dwarf galaxies. As previously emphasized by many authors, a detailed membership analysis is mandatory before comparing the Blue Straggler population in star clusters against theoretical models. Moreover, these sequences of young field stars (blue plumes) are potentially powerful tracers of Galactic structure which require further consideration.

  19. White luminescence from CdS nanocrystals under the blue light excitation

    SciTech Connect (OSTI)

    Li, Bo; Zhang, Xiaosong Li, Lan; Li, Mengzhen; Xu, Jianping; Hong, Yuan

    2014-06-01

    Trap-rich CdS nanocrystals were synthesized by employing CdSt{sub 2} and sulfur as precursors via thermal decomposition. Furthermore, X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), absorption and photoluminescence (PL) spectra were used to characterize structure, morphology and luminescence properties of CdS nanocrystals (NCs). CdS NCs have a broad emission across 500–700 nm under the excitation of blue light with 460 nm, consequently, white light can be produced by mixing broad emission from CdS NCs excited by blue light, with the remaining blue light. In addition, the broad emission generation is closely and inseparably related to surface defects. Moreover, LaMer model was used to explain the phenomenon that the intensity of the trap emission gradually decreases as the reaction time increases in contrast with that of the band-edge emission. - Graphical abstract: Trap-rich CdS nanocrystals were synthesized. Furthermore, white light is produced by mixing broad emission across 500–700 nm from CdS NCs excited by blue light, in combination with the remaining blue light. - Highlights: • Trap-rich CdS nanocrystals were synthesized. • CdS NCs have a broad emission across 500–700 nm under the excitation of blue light. • White light can be produced by mixing broad emission with the remaining blue light.

  20. Morpho blue Morpho blue

    E-Print Network [OSTI]

    John, Sajeev

    the human eye to green light at wavelengths around 530 nm. Creation of struc- tures and devices that can. Moreover, the forms of solar energy storage--whether hy- drocarbon fuels, food generated via photosynthesis challenges Nature's approach to nanostructuring is via self-organization and structural encoding of nanoscale

  1. Spectroscopic accuracy directly from quantum chemistry: Application to ground and excited states of beryllium dimer

    SciTech Connect (OSTI)

    Sharma, Sandeep; Booth, George H.; Chan, Garnet Kin-Lic, E-mail: gkc1000@gmail.com [Department of Chemistry, Frick Laboratory, Princeton University, New Jersey 08544 (United States); Yanai, Takeshi [Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585 (Japan)] [Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585 (Japan); Umrigar, C. J. [Laboratory of Atomic and Solid State Physics, Cornell University, New York 14853 (United States)] [Laboratory of Atomic and Solid State Physics, Cornell University, New York 14853 (United States)

    2014-03-14

    We combine explicit correlation via the canonical transcorrelation approach with the density matrix renormalization group and initiator full configuration interaction quantum Monte Carlo methods to compute a near-exact beryllium dimer curve, without the use of composite methods. In particular, our direct density matrix renormalization group calculations produce a well-depth of D{sub e} = 931.2 cm{sup ?1} which agrees very well with recent experimentally derived estimates D{sub e} = 929.7±2 cm{sup ?1} [J. M. Merritt, V. E. Bondybey, and M. C. Heaven, Science 324, 1548 (2009)] and D{sub e}= 934.6 cm{sup ?1} [K. Patkowski, V. Špirko, and K. Szalewicz, Science 326, 1382 (2009)], as well the best composite theoretical estimates, D{sub e} = 938±15 cm{sup ?1} [K. Patkowski, R. Podeszwa, and K. Szalewicz, J. Phys. Chem. A 111, 12822 (2007)] and D{sub e}=935.1±10 cm{sup ?1} [J. Koput, Phys. Chem. Chem. Phys. 13, 20311 (2011)]. Our results suggest possible inaccuracies in the functional form of the potential used at shorter bond lengths to fit the experimental data [J. M. Merritt, V. E. Bondybey, and M. C. Heaven, Science 324, 1548 (2009)]. With the density matrix renormalization group we also compute near-exact vertical excitation energies at the equilibrium geometry. These provide non-trivial benchmarks for quantum chemical methods for excited states, and illustrate the surprisingly large error that remains for 1 {sup 1}?{sub g}{sup ?} state with approximate multi-reference configuration interaction and equation-of-motion coupled cluster methods. Overall, we demonstrate that explicitly correlated density matrix renormalization group and initiator full configuration interaction quantum Monte Carlo methods allow us to fully converge to the basis set and correlation limit of the non-relativistic Schrödinger equation in small molecules.

  2. A MEGACAM SURVEY OF OUTER HALO SATELLITES. II. BLUE STRAGGLERS IN THE LOWEST STELLAR DENSITY SYSTEMS

    SciTech Connect (OSTI)

    Santana, Felipe A.; Munoz, Ricardo R.; Geha, Marla; Cote, Patrick; Stetson, Peter; Simon, Joshua D.; Djorgovski, S. G. E-mail: rmunoz@das.uchile.cl

    2013-09-10

    We present a homogeneous study of blue straggler stars across 10 outer halo globular clusters, 3 classical dwarf spheroidal galaxies, and 9 ultra-faint galaxies based on deep and wide-field photometric data taken with MegaCam on the Canada-France-Hawaii Telescope. We find blue straggler stars to be ubiquitous among these Milky Way satellites. Based on these data, we can test the importance of primordial binaries or multiple systems on blue straggler star formation in low-density environments. For the outer halo globular clusters, we find an anti-correlation between the specific frequency of blue stragglers and absolute magnitude, similar to that previously observed for inner halo clusters. When plotted against density and encounter rate, the frequency of blue stragglers is well fit by a single trend with a smooth transition between dwarf galaxies and globular clusters; this result points to a common origin for these satellites' blue stragglers. The fraction of blue stragglers stays constant and high in the low encounter rate regime spanned by our dwarf galaxies, and decreases with density and encounter rate in the range spanned by our globular clusters. We find that young stars can mimic blue stragglers in dwarf galaxies only if their ages are 2.5 {+-} 0.5 Gyr and they represent {approx}1%-7% of the total number of stars, which we deem highly unlikely. These results point to mass-transfer or mergers of primordial binaries or multiple systems as the dominant blue straggler formation mechanism in low-density systems.

  3. The blue supergiant MN18 and its bipolar circumstellar nebula

    E-Print Network [OSTI]

    Gvaramadze, V V; Bestenlehner, J M; Bodensteiner, J; Langer, N; Greiner, J; Grebel, E K; Berdnikov, L N; Beletsky, Y

    2015-01-01

    We report the results of spectrophotometric observations of the massive star MN18 revealed via discovery of a bipolar nebula around it with the Spitzer Space Telescope. Using the optical spectrum obtained with the Southern African Large Telescope, we classify this star as B1 Ia. The evolved status of MN18 is supported by the detection of nitrogen overabundance in the nebula, which implies that it is composed of processed material ejected by the star. We analysed the spectrum of MN18 by using the code CMFGEN, obtaining a stellar effective temperature of \\approx 21 kK. The star is highly reddened, E(B-V)\\approx 2 mag. Adopting an absolute visual magnitude of M_V=-6.8\\pm0.5 (typical of B1 supergiants), MN18 has a luminosity of log L/Lsun \\approx 5.42\\pm0.30, a mass-loss rate of \\approx (2.8-4.5)\\times10^{-7} Msun/yr, and resides at a distance of \\approx 5.6^{+1.5} _{-1.2} kpc. We discuss the origin of the nebula around MN18 and compare it with similar nebulae produced by other blue supergiants in the Galaxy (She...

  4. Blue supergiants as descendants of magnetic main sequence stars

    E-Print Network [OSTI]

    Petermann, I; Castro, N; Fossati, L

    2015-01-01

    About 10$\\%$ of the massive main sequence stars have recently been found to host a strong, large scale magnetic field. Both, the origin and the evolutionary consequences of these fields are largely unknown. We argue that these fields may be sufficiently strong in the deep interior of the stars to suppress convection near the outer edge of their convective core. We performed parametrised stellar evolution calculations and assumed a reduced size of the convective core for stars in the mass range 16 M$_{\\odot}$ to 28 M$_{\\odot}$ from the zero age main sequence until core carbon depletion. We find that such models avoid the coolest part of the main sequence band, which is usually filled by evolutionary models that include convective core overshooting. Furthermore, our `magnetic' models populate the blue supergiant region during core helium burning, i.e., the post-main sequence gap left by ordinary single star models, and some of them end their life in a position near that of the progenitor of Supernova 1987A in t...

  5. Hydrogen adsorption in thin films of Prussian blue analogue

    SciTech Connect (OSTI)

    Yang, Dali [Los Alamos National Laboratory; Ding, Vivian [Los Alamos National Laboratory; Luo, Junhua [Los Alamos National Laboratory; Currier, Robert P [Los Alamos National Laboratory; Obrey, Steve [Los Alamos National Laboratory; Zhao, Yusheng [Los Alamos National Laboratory

    2008-01-01

    Quartz crystal microbalance with dissipation (QCM-D) measurement was used to investigate the kinetics of the molecular hydrogen adsorption into thin films of prussian blue analogues - Cu{sub 3}[Co(CN){sub 6}]{sub 2} at ambient conditions. Although the equilibrium adsorption seems to be independent of the thickness, the adsorption rate substantially decreases with the thickness of the films. In addition, the reversibility of H{sub 2} adsorption into the Cu{sub 3}[Co(CN){sub 6}]{sub 2} films was investigated. The results indicate that the Cu{sub 3}[Co(CN){sub 6}]{sub 2} maily interacts with H{sub 2} molecules physically. The highest H{sub 2} uptake by the Cu{sub 3}[Co(CN){sub 6}]{sub 2} films is obtained when the gas phase is stagnant inside the testing cell. However, the unusual high H{sub 2} uptake obtained from the QCM-D measurement makes us question how reliable this analytic methodology is.

  6. Chemical composition and origin of nebulae around Luminous Blue Variables

    E-Print Network [OSTI]

    Lamers, Henny J G L M; Panagia, N; Smith, L J; Langer, N; Lamers, Henny J.G.L.M.; Nota, Antonella; Panagia, Nino; Smith, Linda J.; Langer, Norbert

    2001-01-01

    We use the analysis of the heavy element abundances (C, N, O, S) in circumstellar nebulae around Luminous Blue Variables to infer the evolutionary phase in which the material has been ejected. (1) We discuss the different effects that may have changed the gas composition of the nebula since it was ejected (2) We calculate the expected abundance changes at the stellar surface due to envelope convection in the red supergiant phase. If the observed LBV nebulae are ejected during the RSG phase, the abundances of the LBV nebulae require a significantly smaller amount of mass to be lost than assumed in evolutionary models. (3) We calculate the changes in the surface composition during the main sequence phase by rotation induced mixing. If the nebulae are ejected at the end of the MS-phase, the abundances in LBV nebulae are compatible with mixing times between 5 x 10^6 and 1 x 10^7 years. The existence of ON stars supports this scenario. (4) The predicted He/H ratio in the nebulae are significantly smaller than the ...

  7. Blue tensor spectrum from particle production during inflation

    SciTech Connect (OSTI)

    Mukohyama, Shinji; Namba, Ryo; Peloso, Marco; Shiu, Gary E-mail: ryo.namba@ipmu.jp E-mail: shiu@physics.wisc.edu

    2014-08-01

    We discuss a mechanism of particle production during inflation that can result in a blue gravitational wave (GW) spectrum, compatible with the BICEP2 result and with the r < 0.11 limit on the tensor-to-scalar ratio at the Planck pivot scale. The mechanism is based on the production of vector quanta from a rolling pseudo-scalar field. Both the vector and the pseudo-scalar are only gravitationally coupled to the inflaton, to keep the production of inflaton quanta at an unobservable level (the overproduction of non-gaussian scalar perturbations is a generic difficulty for mechanisms that aim to generate a visible GW signal from particle production during inflation). This mechanism can produce a detectable amount of GWs for any inflationary energy scale. The produced GWs are chiral and non-gaussian; both these aspects can be tested with large-scale polarization data (starting from Planck). We study how to reconstruct the pseudo-scalar potential from the GW spectrum.

  8. Blue Tensor Spectrum from Particle Production during Inflation

    E-Print Network [OSTI]

    Shinji Mukohyama; Ryo Namba; Marco Peloso; Gary Shiu

    2014-07-25

    We discuss a mechanism of particle production during inflation that can result in a blue gravitational wave (GW) spectrum, compatible with the BICEP2 result and with the r < 0.11 limit on the tensor-to-scalar ratio at the Planck pivot scale. The mechanism is based on the production of vector quanta from a rolling pseudo-scalar field. Both the vector and the pseudo-scalar are only gravitationally coupled to the inflaton, to keep the production of inflaton quanta at an unobservable level (the overproduction of non-gaussian scalar perturbations is a generic difficulty for mechanisms that aim to generate a visible GW signal from particle production during inflation). This mechanism can produce a detectable amount of GWs for any inflationary energy scale. The produced GWs are chiral and non-gaussian; both these aspects can be tested with large-scale polarization data (starting from Planck). We study how to reconstruct the pseudo-scalar potential from the GW spectrum.

  9. Rapid dimerization of quercetin through an oxidative mechanism in the presence of serum albumin decreases its ability to induce cytotoxicity in MDA-MB-231 cells

    SciTech Connect (OSTI)

    Pham, Anh; Bortolazzo, Anthony [Department of Biological Sciences, San Jose State University, San Jose, CA 95192-0100 (United States)] [Department of Biological Sciences, San Jose State University, San Jose, CA 95192-0100 (United States); White, J. Brandon, E-mail: Brandon.White@sjsu.edu [Department of Biological Sciences, San Jose State University, San Jose, CA 95192-0100 (United States)

    2012-10-19

    Highlights: Black-Right-Pointing-Pointer Quercetin cannot be detected intracellularly despite killing MDA-MB-231 cells. Black-Right-Pointing-Pointer Quercetin forms a heterodimer through oxidation in media with serum. Black-Right-Pointing-Pointer The quercetin heterodimer does not kill MDA-MB-231 cells. Black-Right-Pointing-Pointer Ascorbic acid stabilizes quercetin increasing cell death in quercetin treated cells. Black-Right-Pointing-Pointer Quercetin, and not a modified form, is responsible for apoptosis and cell death. -- Abstract: Quercetin is a member of the flavonoid family and has been previously shown to have a variety of anti-cancer activities. We and others have reported anti-proliferation, cell cycle arrest, and induction of apoptosis of cancer cells after treatment with quercetin. Quercetin has also been shown to undergo oxidation. However, it is unclear if quercetin or one of its oxidized forms is responsible for cell death. Here we report that quercetin rapidly oxidized in cell culture media to form a dimer. The quercetin dimer is identical to a dimer that is naturally produced by onions. The quercetin dimer and quercetin-3-O-glucopyranoside are unable to cross the cell membrane and do not kill MDA-MB-231 cells. Finally, supplementing the media with ascorbic acid increases quercetin's ability to induce cell death probably by reduction oxidative dimerization. Our results suggest that an unmodified quercetin is the compound that elicits cell death.

  10. Singlet-triplet dispersion reveals additional frustration in the triangular dimer compound Ba$_3$Mn$_2$O$_8$

    SciTech Connect (OSTI)

    Stone, Matthew B [ORNL; Lumsden, Mark D [ORNL; Chang, S. [Ames Laboratory; Samulon, Eric C [Stanford University; Batista, C. D. [Los Alamos National Laboratory (LANL); Fisher, Ian R [Stanford University

    2008-01-01

    We present single crystal inelastic neutron scattering measurements of the $S=1$ dimerized quasi-two-dimensional antiferromagnet Ba$_3$Mn$_2$O$_8$. The singlet-triplet dispersion reveals nearest-neighbor and next-nearest-neighbor ferromagnetic interactions between adjacent bilayers that compete against each other. Although the inter-bilayer exchange is comparable to the intra-bilayer exchange, this additional frustration reduces the effective coupling along the $c$-axis and leads to a quasi-two dimensional behavior. In addition, the obtained exchange values are able to reproduce the four critical fields in the phase diagram.

  11. Mysteries of the Deep: What happens inside of MPI on Blue Gene...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mysteries of the Deep: What happens inside of MPI on Blue GeneQ and why it matters Jeff Hammond Leadership Computing Facility Argonne National Laboratory March 5, 2013 Jeff...

  12. A Performance Counter Based Workload Characterization on Blue Gene/P

    E-Print Network [OSTI]

    John, Lizy Kurian

    parallel benchmarks and collected the performance counter data. We studied the MFLOPS, L3-DDR Traffic of the petaflop machine. Blue Gene/P is also claimed to be very energy efficient as in [2] when compared to all

  13. A comparison of the behavior of intact and Resedimented Boston Blue Clay (BBC)

    E-Print Network [OSTI]

    House, Robert Donald

    2012-01-01

    Resedimented Boston Blue Clay (RBBC) has been used as an analog test material for research at MIT for decades, due to local variability and the high cost of sampling. However, a comprehensive study of the differences in ...

  14. Giantically blue-shifted visible light in femtosecond mid-IR filament in fluorides

    E-Print Network [OSTI]

    Dormidonov, A E; Chekalin, S V; Kandidov, V P

    2015-01-01

    A giant blue shift of an isolated visible band of supercontinuum was discovered and studied in the single filament regime of Mid-IR femtosecond laser pulse at powers slightly exceeding critical power for self-focusing in fluorides.

  15. Blue photoluminescence enhancement in laser-irradiated 6H-SiC at room temperature

    SciTech Connect (OSTI)

    Wu, Yan; Ji, Lingfei Lin, Zhenyuan; Jiang, Yijian; Zhai, Tianrui

    2014-01-27

    Blue photoluminescence (PL) of 6H-SiC irradiated by an ultraviolet laser can be observed at room temperature in dark condition. PL spectra with Gaussian fitting curve of the irradiated SiC show that blue luminescence band (?440?nm) is more pronounced than other bands. The blue PL enhancement is the combined result of the improved shallow N-donor energy level and the unique surface state with Si nanocrystals and graphene/Si composite due to the effect of photon energy input by the short-wavelength laser irradiation. The study can provide a promising route towards the preparation of well-controlled blue photoluminescence material for light-emitting devices.

  16. Mapping the formation areas of giant molybdenum blue clusters: a spectroscopic study

    SciTech Connect (OSTI)

    Botar, Bogdan; Ellern, Arkady; Kogerler, Paul

    2012-05-18

    The self-assembly of soluble molybdenum blue species from simple molybdate solutions has primarily been associated with giant mixed-valent wheel-shaped cluster anions, derived from the {MoV/VI154/176} archetypes, and a {MoV/VI368} lemon-shaped cluster. The combined use of Raman spectroscopy and kinetic precipitation as self-assembly monitoring techniques and single-crystal X-ray diffraction is key to mapping the realm of molybdenum blue species by establishing spherical {MoV/VI102}-type Keplerates as an important giant molybdenum blue-type species. We additionally rationalize the empirical effect of reducing agent concentration on the formation of all three relevant skeletal types: wheel, lemon and spheres. Whereas both wheels and the lemon-shaped {MoV/VI368} cluster are obtained from weakly reduced molybdenum blue solutions, considerably higher reduced solutions lead to {MoV/VI102}-type Keplerates.

  17. Blue Lake Rancheria's Bold Action on the Climate Front Pays Dividends...

    Office of Environmental Management (EM)

    and greenhouse gas reduction in mind. blue-LakeHopper and Bucket Elevator for Biomass Feed System.jpg The Tribe's overarching goal is to meet or exceed California's...

  18. Core Analysis At Blue Mountain Geothermal Area (U.S. Geological...

    Open Energy Info (EERE)

    1 and 46 samples from Deep Blue No. 2. The diameter of the core samples are 6.4 cm. Density, porosity, and rock type information was recorded. The samples contain Jurassic and...

  19. Blue Coat Systems, Inc. Secure Web Gateway Virtual Appliance-V100

    E-Print Network [OSTI]

    Blue Coat Systems, Inc. Secure Web Gateway Virtual Appliance-V100 Software Version: 6.5.2.8 FIPS@corsec.com http://www.bluecoat.com http://www.corsec.com #12;Secure Web Gateway Virtual Appliance-V100 Security Policy, Version 0.5 July 25, 2014 Blue Coat Secure Web Gateway Virtual Appliance-V100 Page 2 of 33 © 2014

  20. Achieving Record Efficiency for Blue OLEDs by Controlling the Charge Balance

    Broader source: Energy.gov [DOE]

    Researchers at the University of Florida (UF) have demonstrated a blue phosphorescent organic light-emitting diode (OLED) with a peak power efficiency of 50 lm/W and an external quantum efficiency exceeding 20 percent at a luminance of 1,000 cd/m2, using no external light extraction techniques. This accomplishment is believed to be the world record in blue OLED efficiency.