National Library of Energy BETA

Sample records for blending components derived

  1. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  2. Certification of alternative aviation fuels and blend components

    SciTech Connect (OSTI)

    Wilson III, George R. ); Edwards, Tim; Corporan, Edwin ); Freerks, Robert L. )

    2013-01-15

    Aviation turbine engine fuel specifications are governed by ASTM International, formerly known as the American Society for Testing and Materials (ASTM) International, and the British Ministry of Defence (MOD). ASTM D1655 Standard Specification for Aviation Turbine Fuels and MOD Defence Standard 91-91 are the guiding specifications for this fuel throughout most of the world. Both of these documents rely heavily on the vast amount of experience in production and use of turbine engine fuels from conventional sources, such as crude oil, natural gas condensates, heavy oil, shale oil, and oil sands. Turbine engine fuel derived from these resources and meeting the above specifications has properties that are generally considered acceptable for fuels to be used in turbine engines. Alternative and synthetic fuel components are approved for use to blend with conventional turbine engine fuels after considerable testing. ASTM has established a specification for fuels containing synthesized hydrocarbons under D7566, and the MOD has included additional requirements for fuels containing synthetic components under Annex D of DS91-91. New turbine engine fuel additives and blend components need to be evaluated using ASTM D4054, Standard Practice for Qualification and Approval of New Aviation Turbine Fuels and Fuel Additives. This paper discusses these specifications and testing requirements in light of recent literature claiming that some biomass-derived blend components, which have been used to blend in conventional aviation fuel, meet the requirements for aviation turbine fuels as specified by ASTM and the MOD. The 'Table 1' requirements listed in both D1655 and DS91-91 are predicated on the assumption that the feedstocks used to make fuels meeting these requirements are from approved sources. Recent papers have implied that commercial jet fuel can be blended with renewable components that are not hydrocarbons (such as fatty acid methyl esters). These are not allowed blend

  3. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  4. Powertrain Component Inspection from Mid-Level Blends Vehicle Aging Study

    SciTech Connect (OSTI)

    Shoffner, Brent; Johnson, Ryan; Heimrich, Martin J.; Lochte, Michael

    2010-11-01

    The Energy Independence and Security Act of 2007 calls on the nation to significantly increase its use of renewable fuels to meet its transportation energy needs. The law expands the renewable fuel standard to require use of 36 billion gallons of renewable fuel by 2022. Given that ethanol is the most widely used renewable fuel in the U.S. market, ethanol will likely make up a significant portion of the 36-billion-gallon requirement. The vast majority of ethanol used in the United States is blended with gasoline to create E10-gasoline with up to 10% ethanol. The remaining ethanol is sold in the form of E85 - a gasoline blend with as much as 85% ethanol that can only be used in flexible-fuel vehicles (FFVs). Consumption of E85 is at present limited by both the size of the FFV fleet and the number of E85 fueling stations. Gasoline consumption in the United States is currently about 140 billion gallons per year; thus the maximum use of ethanol as E10 is only about 14 billion gallons. While the U.S. Department of Energy (DOE) remains committed to expanding the E85 infrastructure, that market represented less than 1% of the ethanol consumed in 2010 and will not be able to absorb projected volumes of ethanol in the near term. Because of these factors, DOE and others have been assessing the viability of using mid-level ethanol blends (E15 or E20) as a way to accommodate growing volumes of ethanol. The DOE Mid-Level Ethanol Blends Test Program has been under way since 2007, supported jointly by the Office of the Biomass Program and the Vehicle Technologies Program. One of the larger projects, the Catalyst Durability Study, or Vehicle Aging Study, will be completed early in calendar year 2011. The following report describes a subproject of the Vehicle Aging Study in which powertrain components from 18 of the vehicles were examined at Southwest Research Institute under contract to Oak Ridge National Laboratory (ORNL).

  5. Electrochemical components employing polysiloxane-derived binders

    DOE Patents [OSTI]

    Delnick, Frank M.

    2013-06-11

    A processed polysiloxane resin binder for use in electrochemical components and the method for fabricating components with the binder. The binder comprises processed polysiloxane resin that is partially oxidized and retains some of its methyl groups following partial oxidation. The binder is suitable for use in electrodes of various types, separators in electrochemical devices, primary lithium batteries, electrolytic capacitors, electrochemical capacitors, fuel cells and sensors.

  6. Chlorinated organic compounds evolved during the combustion of blends of refuse-derived fuels and coals

    SciTech Connect (OSTI)

    Xiaodong Yang; Napier, J.; Sisk, B.; Wei-Ping Pan; Riley, J.T.; Lloyd, W.G.

    1996-12-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR and MS systems. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GUMS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic; compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  7. Biodiesel Blends

    SciTech Connect (OSTI)

    Not Available

    2005-04-01

    A 2-page fact sheet discussing general biodiesel blends and the improvement in engine performance and emissions.

  8. Catalytic hydroprocessing of coal-derived gasification residues to fuel blending stocks: effect of reaction variables and catalyst on hydrodeoxygenation (HDO), hydrodenitrogenation (HDN), and hydrodesulfurization (HDS)

    SciTech Connect (OSTI)

    Dieter Leckel

    2006-10-15

    Gas liquors, tar oils, and tar products resulting from the coal gasification of a high-temperature Fischer-Tropsch plant can be successfully refined to fuel blending components by the use of severe hydroprocessing conditions. High operating temperatures and pressures combined with low space velocities ensure the deep hydrogenation of refractory oxygen, sulfur, and nitrogen compounds. Hydrodeoxygenation, particularly the removal of phenolic components, hydrodesulfurization, and hydrodenitrogenation were obtained at greater than 99% levels using the NiMo and NiW on {gamma}-Al{sub 2}O{sub 3} catalysts. Maximum deoxygenation activity was achieved using the NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst having a maximum pore size distribution in the range of 110-220{angstrom}. The NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst, which also has a relatively high proportion of smaller pore sizes (35-60 {angstrom}), displays lower hydrogenation activity. 30 refs., 1 fig. 8 tabs.

  9. Methodology for modeling the devolatilization of refuse-derived fuel from thermogravimetric analysis of municipal solid waste components

    SciTech Connect (OSTI)

    Fritsky, K.J.; Miller, D.L.; Cernansky, N.P.

    1994-09-01

    A methodology was introduced for modeling the devolatilization characteristics of refuse-derived fuel (RFD) in terms of temperature-dependent weight loss. The basic premise of the methodology is that RDF is modeled as a combination of select municipal solid waste (MSW) components. Kinetic parameters are derived for each component from thermogravimetric analyzer (TGA) data measured at a specific set of conditions. These experimentally derived parameters, along with user-derived parameters, are inputted to model equations for the purpose of calculating thermograms for the components. The component thermograms are summed to create a composite thermogram that is an estimate of the devolatilization for the as-modeled RFD. The methodology has several attractive features as a thermal analysis tool for waste fuels. 7 refs., 10 figs., 3 tabs.

  10. EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY

    Broader source: Energy.gov [DOE]

    This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

  11. Separation and characterization of coal derived components. Quarterly report, July 1-September 30, 1983

    SciTech Connect (OSTI)

    Hurtubise, R.J.; Silver, H.F.

    1983-10-17

    The field-ionization mass spectral hydrocarbon data from F-45 (Wyodak coal-derived SRC) and F-51 (Kentucky 9/14 coal-derived SRC) were recalculated so the various hydrocarbon fractions could be compared directly on a weight percent basis. A computer program was developed which allows the field-ionization mass spectral hydrocarbon data to be compared in a three dimensional fashion. This approach provides for a rapid general comparson of all the field-ionization hydrocarbon data. The solubility of preasphaltenes was tested in several solvents. The preasphaltenes-2 were found to be largely soluble in pyridine:chloroform 9:1(v/v) or 7:3(v/v) and pyridine:chloroform:tetrahydrofuran 7:1:2(v/v/v). Experiments were carried out in which Chromasorb T was tested as a replacement for Fluoropak in the Fluoropak-basic alumina procedure. The results indicated Chromasorb T would be an adequate substitute for Fluoropak, but additional experiments will be run to confirm this. The chromatographic characteristics of numerous hydroxyl aromatics, nitrogen heterocycles, and aromatic amines were obtained on several normal-phase and reversed-phase high-performance liquid chromatographic systems. 30 references, 30 figures, 10 tables.

  12. Emissions with butane/propane blends

    SciTech Connect (OSTI)

    1996-11-01

    This article reports on various aspects of exhaust emissions from a light-duty car converted to operate on liquefied petroleum gas and equipped with an electrically heated catalyst. Butane and butane/propane blends have recently received attention as potentially useful alternative fuels. Butane has a road octane number of 92, a high blending vapor pressure, and has been used to upgrade octane levels of gasoline blends and improve winter cold starts. Due to reformulated gasoline requirements for fuel vapor pressure, however, industry has had to remove increasing amounts of butane form the gasoline pool. Paradoxically, butane is one of the cleanest burning components of gasoline.

  13. Impact of bacteria and bacterial components on osteogenic and adipogenic differentiation of adipose-derived mesenchymal stem cells

    SciTech Connect (OSTI)

    Fiedler, Tomas; Salamon, Achim; Adam, Stefanie; Herzmann, Nicole; Taubenheim, Jan; Peters, Kirsten

    2013-11-01

    Adult mesenchymal stem cells (MSC) are present in several tissues, e.g. bone marrow, heart muscle, brain and subcutaneous adipose tissue. In invasive infections MSC get in contact with bacteria and bacterial components. Not much is known about how bacterial pathogens interact with MSC and how contact to bacteria influences MSC viability and differentiation potential. In this study we investigated the impact of three different wound infection relevant bacteria, Escherichia coli, Staphylococcus aureus, and Streptococcus pyogenes, and the cell wall components lipopolysaccharide (LPS; Gram-negative bacteria) and lipoteichoic acid (LTA; Gram-positive bacteria) on viability, proliferation, and osteogenic as well as adipogenic differentiation of human adipose tissue-derived mesenchymal stem cells (adMSC). We show that all three tested species were able to attach to and internalize into adMSC. The heat-inactivated Gram-negative E. coli as well as LPS were able to induce proliferation and osteogenic differentiation but reduce adipogenic differentiation of adMSC. Conspicuously, the heat-inactivated Gram-positive species showed the same effects on proliferation and adipogenic differentiation, while its cell wall component LTA exhibited no significant impact on adMSC. Therefore, our data demonstrate that osteogenic and adipogenic differentiation of adMSC is influenced in an oppositional fashion by bacterial antigens and that MSC-governed regeneration is not necessarily reduced under infectious conditions. - Highlights: Staphylococcus aureus, Streptococcus pyogenes and Escherichia coli bind to and internalize into adMSC. Heat-inactivated cells of these bacterial species trigger proliferation of adMSC. Heat-inactivated E. coli and LPS induce osteogenic differentiation of adMSC. Heat-inactivated E. coli and LPS reduce adipogenic differentiation of adMSC. LTA does not influence adipogenic or osteogenic differentiation of adMSC.

  14. Impact of Biodiesel on Fuel System Component Durability

    SciTech Connect (OSTI)

    Terry, B.

    2005-09-01

    A study of the effects of biodiesel blends on fuel system components and the physical characteristics of elastomer materials.

  15. Stocks of Motor Gasoline Blending Components

    Gasoline and Diesel Fuel Update (EIA)

    194,259 203,187 212,640 217,489 220,765 226,935 1983-2016 PADD 1 51,306 53,633 57,200 56,763 58,920 62,421 2004-2016 PADD 2 43,744 46,809 50,163 51,441 51,859 54,773 2004-2016 PADD...

  16. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  17. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J.; King, Edward E.; Milliron, Dennis L.

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  18. Relationship between textural properties, fly ash carbons, and Hg capture in fly ashes derived from the combustion of anthracitic pulverized feed blends

    SciTech Connect (OSTI)

    Isabel Surez-Ruiz; Jose B. Parra

    2007-08-15

    In this work, the textural properties of a series of whole anthracitic-derived fly ashes sampled in eight hoppers from the electrostatic precipitators and their sized fractions (from {gt}150 to {lt}25 {mu}m) are investigated. Data from N{sub 2} adsorption isotherms at 77 K, helium density, and mercury porosimetry have contributed to establish a relationship between the Brunauer-Emmett-Teller (BET) surface areas, VTOT, porosity, carbon content (the type of fly ash carbons), and Hg retention in these fly ashes. The unburned carbons in these ashes are macroporous materials, and they are different from the carbons in fly ashes from classes C and F (the latter derived from the combustion of bituminous coals) and show different textural properties. These ashes represent the end member of the fly ash classes C and F with respect to certain textural properties. Although the BET surface area and VTOT values for the studied samples are the lowest reported, they increase with the increase in carbon content, anisotropic carbon content, and particle size of the ashes. Thus, a positive relationship between all these parameters and Hg capture by the coarser ash fractions was found. The finest fraction of carbons ({lt}25 {mu}m) represented an exception. Although it makes a significant contribution to the total carbon of the whole fly ashes and shows relatively higher surface areas and VTOT values, its Hg concentration was found to be the lowest. This suggests that the type of unburned carbons in the finest fraction and/or other adsorption mechanisms may play a role in Hg concentration. Because the textural properties of anisotropic carbons depend on their subtype and on their origin, the need for its differentiation has been evidenced. 54 refs., 8 figs., 3 tabs.

  19. Blends of chitin and chitosan with polyamide 66

    SciTech Connect (OSTI)

    Gonzalez, V.; Guerrero, C.

    1996-12-31

    For several years, intense interest has been focused on polymer blends in which both components are synthetic polymers. However, few studies have been made on blends in which one component is chitin (QA), or chitosan (QN), the most abundant natural polymers after cellulose. Its chemical structure, based in partially acetilated {beta}-aminosaccharide units, permits the formation of natural blends with proteins and inorganic salts were the intermolecular hydrogen bonds play an important role. The choice of a partner for these natural polymers was made expecting strong interaction between the two polymers. For this reason, on this work, polyamide 66 (P66), has been chosen.

  20. Phase Segregation in Polystyrene?Polylactide Blends

    SciTech Connect (OSTI)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  1. Vehicle Technologies Office: Intermediate Ethanol Blends Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intermediate Ethanol Blends Research and Testing Vehicle Technologies Office: Intermediate Ethanol Blends Research and Testing Ethanol can be combined with gasoline in blends ...

  2. Alternative Fuels Data Center: Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blends to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blends on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blends on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blends on Google Bookmark Alternative Fuels Data Center: Ethanol Blends on Delicious Rank Alternative Fuels Data Center: Ethanol Blends on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blends on AddThis.com... More in this section... Ethanol Basics Blends E15

  3. RIVER PROTECTION PROJECT MISSION ANALYSIS WASTE BLENDING STUDY

    SciTech Connect (OSTI)

    SHUFORD DH; STEGEN G

    2010-04-19

    Preliminary evaluation for blending Hanford site waste with the objective of minimizing the amount of high-level waste (HLW) glass volumes without major changes to the overall waste retrieval and processing sequences currently planned. The evaluation utilizes simplified spreadsheet models developed to allow screening type comparisons of blending options without the need to use the Hanford Tank Waste Operations Simulator (HTWOS) model. The blending scenarios evaluated are expected to increase tank farm operation costs due to increased waste transfers. Benefit would be derived from shorter operating time period for tank waste processing facilities, reduced onsite storage of immobilized HLW, and reduced offsite transportation and disposal costs for the immobilized HLW.

  4. Alternative Fuels Data Center: Biodiesel Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Blends to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blends on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blends on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blends on Google Bookmark Alternative Fuels Data Center: Biodiesel Blends on Delicious Rank Alternative Fuels Data Center: Biodiesel Blends on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blends on AddThis.com... More in this section... Biodiesel Basics

  5. Ethanol-blended Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ethanol-Blended Fuels A Study Guide and Overview of: * Ethanol's History in the U.S. and Worldwide * Ethanol Science and Technology * Engine Performance * Environmental Effects * Economics and Energy Security The Curriculum This curriculum on ethanol and its use as a fuel was developed by the Clean Fuels Development Coalition in cooperation with the Nebraska Ethanol Board. This material was developed in response to the need for instructional materials on ethanol and its effects on vehicle

  6. Methylal and Methylal-Diesel Blended Fuels from Use In Compression-Ignition Engines

    SciTech Connect (OSTI)

    Keith D. Vertin; James M. Ohi; David W. Naegeli; Kenneth H. Childress; Gary P. Hagen; Chris I. McCarthy; Adelbert S. Cheng; Robert W. Dibble

    1999-05-05

    Gas-to-liquids catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude derived fuels. Methylal (CH{sub 3}-O-CH{sub 2}-O-CH{sub 3}) also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins 85.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions. Substantial reductions of particulate matter emissions h ave been demonstrated 3r IO to 30% blends of methylal in diesel fuel. This research indicates that methylal may be an effective blendstock for diesel fuel provided design changes are made to vehicle fuel handling systems.

  7. Kinetics and mechanism of catalytic hydroprocessing of components of coal-derived liquids. Fifth quarterly report, May 15, 1980-August 15, 1980

    SciTech Connect (OSTI)

    Gates, B.C.; Katzer, J.R.; Kwart, H.; Olson, J.H.; Schuit, G.C.A.; Stiles, A.B.; Petrakis, L.

    1980-11-15

    An asphaltene-containing SRC-II coal liquid derived from Powhatan No. 5 mine coal and produced in the Ft. Lewis demonstration plant has been selected for study of catalytic hydroprocessing reactions. Analytical separation by liquid hydroprocessing reactions. Analytical separation by liquid chomatography has been carried out to produce nine distinct fractions from 1 kg of coal liquid. These have been further separated into compound classes and characterized in detail by elemental analysis, mass spectrometry, NMR, and infrared spectroscopy. Compounds typical of each fraction (except asphaltenes) have been designed. Hydroprocessing of polynuclear aromatic hydrocarbons under industrially relevant conditions has shown that these are much more reactive than benzene. The reaction networks involve reversible hydrogenation and isomerization, and significant concentrations of hydroaromatic (hydrogen-donor) species are attainable under practical conditions. Hydroprocessing of solutions containing the following combinations of compounds has also been studied: quinoline/indole, quinoline/indole/dibenzothiophene, and quinoline/indole/naphthalene. Lumping of components in a reaction network simplifies the kinetics determination of fuel feedstocks. Component lumping simulations involving first-order kinetics were successfully carried out for certain schemes in the quinoline network. This network can be represented by 3 simplified components. The quinoline and indole reaction networks are assumed to be made up of 4 lumps with the adsorption constants fixed, the intrinsic kinetic constants were recovered, and the lumping proved successful.

  8. South Texas Blending | Open Energy Information

    Open Energy Info (EERE)

    search Name: South Texas Blending Place: Laredo, Texas Zip: 78045 Product: Biodiesel producer based in Texas. References: South Texas Blending1 This article is a stub....

  9. Low-Level Ethanol Fuel Blends

    SciTech Connect (OSTI)

    Not Available

    2005-04-01

    This fact sheet addresses: (a) why Clean Cities promotes ethanol blends; (b) how these blends affect emissions; (c) fuel performance and availability; and (d) cost, incentives, and regulations.

  10. Tough Blends of Polylactide and Castor Oil

    SciTech Connect (OSTI)

    Robertson, Megan L.; Paxton, Jessica M.; Hillmyer, Marc A.

    2012-10-10

    Poly(l-lactide) (PLLA) is a renewable resource polymer derived from plant sugars with several commercial applications. Broader implementation of the material is limited due to its inherent brittleness. We show that the addition of 5 wt % castor oil to PLLA significantly enhances the overall tensile toughness with minimal reductions in the modulus and no plasticization of the PLLA matrix. In addition, we used poly(ricinoleic acid)-PLLA diblock copolymers, synthesized entirely from renewable resources, as compatibilizers for the PLLA/castor oil blends. Ricinoleic acid, the majority fatty acid comprising castor oil, was polymerized through a lipase-catalyzed condensation reaction. The resulting polymers contained a hydroxyl end-group that was subsequently used to initiate the ring-opening polymerization of L-lactide. The binary PLLA/castor oil blend exhibited a tensile toughness seven times greater than neat PLLA. The addition of block copolymer allowed for control over the morphology of the blends, and even further improvement in the tensile toughness was realized - an order of magnitude larger than that of neat PLLA.

  11. Method to blend separator powders

    SciTech Connect (OSTI)

    Guidotti, Ronald A.; Andazola, Arthur H.; Reinhardt, Frederick W.

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  12. EffectsIntermediateEthanolBlends.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf (1.43 MB) More Documents & Publications Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009 Mid-Level Ethanol Blends Test Program Mid-Level Ethanol Blends

  13. Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .

    SciTech Connect (OSTI)

    Wallner, T.

    2011-08-01

    The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of

  14. Intrinsically safe moisture blending system

    SciTech Connect (OSTI)

    Hallman Jr., Russell L.; Vanatta, Paul D.

    2012-09-11

    A system for providing an adjustable blend of fluids to an application process is disclosed. The system uses a source of a first fluid flowing through at least one tube that is permeable to a second fluid and that is disposed in a source of the second fluid to provide the adjustable blend. The temperature of the second fluid is not regulated, and at least one calibration curve is used to predict the volumetric mixture ratio of the second fluid with the first fluid from the permeable tube. The system typically includes a differential pressure valve and a backpressure control valve to set the flow rate through the system.

  15. Refinery Net Input of Motor Gasoline Blending Components (Net)

    U.S. Energy Information Administration (EIA) Indexed Site

    -224,415 -196,460 -205,085 -201,403 -213,659 -206,750 2005-2016 PADD 1 -17,942 -14,705 -15,325 -15,088 -16,507 -15,534 2005-2016 East Coast -17,889 -14,746 -15,326 -15,154 -16,492 -15,493 2005-2016 Appalachian No. 1 -53 41 1 66 -15 -41 2005-2016 PADD 2 -56,553 -48,250 -48,728 -44,224 -48,504 -47,699 2005-2016 Ind., Ill. and Ky. -36,491 -32,814 -31,456 -27,909 -31,097 -30,704 2005-2016 Minn., Wis., N. Dak., S. Dak. -7,599 -5,879 -6,476 -5,086 -5,818 -5,937 2005-2016 Okla., Kans., Mo. -12,463

  16. Mid-Level Ethanol Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mid-Level Ethanol Blends Test Program DOE, NREL, and ORNL Team Presented by Keith Knoll Work supported by DOE/EERE Vehicle Technologies Program Annual Merit Review and Peer Evaluation meeting May 19, 2009 Kevin Stork Vehicle Technologies Program Shab Fardanesh and Joan Glickman Office of the Biomass Program This presentation does not contain any proprietary or classified information Project ID: ft_05_knoll Collaborators Kevin Stork DOE OVT Shab Fardanesh DOE OBP Joan Glickman DOE OBP Wendy Clark

  17. Data approximation using a blending type spline construction

    SciTech Connect (OSTI)

    Dalmo, Rune; Bratlie, Jostein

    2014-11-18

    Generalized expo-rational B-splines (GERBS) is a blending type spline construction where local functions at each knot are blended together by C{sup k}-smooth basis functions. One way of approximating discrete regular data using GERBS is by partitioning the data set into subsets and fit a local function to each subset. Partitioning and fitting strategies can be devised such that important or interesting data points are interpolated in order to preserve certain features. We present a method for fitting discrete data using a tensor product GERBS construction. The method is based on detection of feature points using differential geometry. Derivatives, which are necessary for feature point detection and used to construct local surface patches, are approximated from the discrete data using finite differences.

  18. Powder Injection Molding of Titanium Components

    SciTech Connect (OSTI)

    Simmons, Kevin L.; Nyberg, Eric A.; Weil, K. Scott; Miller, Megan R.

    2005-01-01

    Powder injection molding (PIM) is a well-established, cost-effective method of fabricating small-to-moderate size metal components. Derived from plastic injection molding and employing a mixture of metal powder and plastic binder, the process has been used with great success in manufacturing a wide variety of metal products, including those made from stainless steel, nickel-based superalloys, and copper alloys. Less progress has been achieved with titanium and other refractory metal alloys because of problems with alloy impurities that are directly attributable to the injection molding process. Specifically, carbon, oxygen, and nitrogen are left behind during binder removal and become incorporated into the chemistry and microstructure of the material during densification. Even at low concentration, these impurities can cause severe degradation in the mechanical properties of titanium and its alloys. We have developed a unique blend of PIM constituents where only a small volume fraction of binder (~5 10 vol%) is required for injection molding; the remainder of the mixture consists of the metal powder and binder solvent. Because of the nature of decomposition in the binder system and the relatively small amount used, the binder is eliminated almost completely from the pre-sintered component during the initial stage of a two-step heat treatment process. Results will be presented on the first phase of this research, in which the binder, injection molding, de-binding and sintering schedule were developed. Additional data on the mechanical and physical properties of the material produced will be discussed.

  19. Kinetics and mechanism of catalytic hydroprocessing of components of coal-derived liquids. Second quarterly report, August 15, 1979-November 15, 1979

    SciTech Connect (OSTI)

    Gates, B.C.; Katzer, J.R.; Kwart, H.; Petrakis, L.; Ruberto, R.; Schuit, G.C.A.; Stiles, A.B.

    1980-10-20

    An asphaltene-containing SRC-II coal liquid derived from Powhatan No. 5 mine coal and produced in the Ft. Lewis demonstration plant has been selected for study of catalytic hydroprocessing reactions. Analytical separation by liquid chromatography is being carried out to produce nine distinct fractions from 1 kg of coal liquid. These fractions will be used as feeds to high-pressure catalytic flow microreactors. Hydroprocessing of polynuclear aromatic hydrocarbons under industrially relevant conditions has shown that these are much more reactive than benzene. The reaction networks involve reversible hydrogenation and isomerization, and significant concentrations of hydroaromatic (hydrogen-donor) species are attainable under practical conditions. Hydroprocessing of solutions containing the following combinations of compounds has also been studied: quinoline/indole, quinoline/indole/dibenzothiophene, and quinoline/indole/naphthalene. Four of the types of compounds, or potential lumps, in coal-derived liquids are basic nitrogen, nonbasic nitrogen, sulfur, and aromatic compounds. It is desired to determine how these compounds interact and compete with each other in hydroprocessing and how these interactions depend on hydrogen partial pressure. Four model compounds, quinoline, indole, dibenzothiophene, and naphthalene, have been selected to represent compounds in each group. These compounds, in different proportions with hydrogen, were allowed to react in a batch autoclave reactor.

  20. Sandia Energy - Biofuels Blend Right In: Researchers Show Ionic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks Home Renewable Energy Energy Transportation Energy Biofuels...

  1. Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    Not Available

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the US today and the potential impact of ethanol on gasoline prices at higher blending concentrations.

  2. Macrophase Separation of Blends of Diblock Copolymers in Thin...

    Office of Scientific and Technical Information (OSTI)

    Macrophase Separation of Blends of Diblock Copolymers in Thin Films Citation Details In-Document Search Title: Macrophase Separation of Blends of Diblock Copolymers in Thin Films ...

  3. Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HCCI Exhaust Speciation - ORNL Reference Fuel Blends Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends *Accurately measure exhaust profile from an HCCI engine with a ...

  4. A Multicomponent Blend as a Diesel Fuel Surrogate for Compression...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications Title A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition...

  5. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and ...

  6. Green emitting phosphors and blends thereof

    DOE Patents [OSTI]

    Setlur, Anant Achyut; Siclovan, Oltea Puica; Nammalwar, Prasanth Kumar; Sathyanarayan, Ramesh Rao; Porob, Digamber G.; Chandran, Ramachandran Gopi; Heward, William Jordan; Radkov, Emil Vergilov; Briel, Linda Jane Valyou

    2010-12-28

    Phosphor compositions, blends thereof and light emitting devices including white light emitting LED based devices, and backlights, based on such phosphor compositions. The devices include a light source and a phosphor material as described. Also disclosed are phosphor blends including such a phosphor and devices made therefrom.

  7. PAIRWISE BLENDING OF HIGH LEVEL WASTE (HLW)

    SciTech Connect (OSTI)

    CERTA, P.J.

    2006-02-22

    The primary objective of this study is to demonstrate a mission scenario that uses pairwise and incidental blending of high level waste (HLW) to reduce the total mass of HLW glass. Secondary objectives include understanding how recent refinements to the tank waste inventory and solubility assumptions affect the mass of HLW glass and how logistical constraints may affect the efficacy of HLW blending.

  8. High-performance ternary blend polymer solar cells involving both energy transfer and hole relay processes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Luyao; Chen, Wei; Xu, Tao; Yu, Luping

    2015-06-04

    The integration of multiple materials with complementary absorptions into a single junction device is regarded as an efficient way to enhance the power conversion efficiency (PCE) of organic solar cells (OSCs). However, because of increased complexity with one more component, only limited high-performance ternary systems have been demonstrated previously. Here we report an efficient ternary blend OSC with a PCE of 9.2%. We show that the third component can reduce surface trap densities in the ternary blend. Detailed studies unravel that the improved performance results from synergistic effects of enlarged open circuit voltage, suppressed trap-assisted recombination, enhanced light absorption, increasedmore » hole extraction, efficient energy transfer and better morphology. The working mechanism and high device performance demonstrate new insights and design guidelines for high-performance ternary blend solar cells and suggest that ternary structure is a promising platform to boost the efficiency of OSCs.« less

  9. High-performance ternary blend polymer solar cells involving both energy transfer and hole relay processes

    SciTech Connect (OSTI)

    Lu, Luyao; Chen, Wei; Xu, Tao; Yu, Luping

    2015-06-04

    The integration of multiple materials with complementary absorptions into a single junction device is regarded as an efficient way to enhance the power conversion efficiency (PCE) of organic solar cells (OSCs). However, because of increased complexity with one more component, only limited high-performance ternary systems have been demonstrated previously. Here we report an efficient ternary blend OSC with a PCE of 9.2%. We show that the third component can reduce surface trap densities in the ternary blend. Detailed studies unravel that the improved performance results from synergistic effects of enlarged open circuit voltage, suppressed trap-assisted recombination, enhanced light absorption, increased hole extraction, efficient energy transfer and better morphology. The working mechanism and high device performance demonstrate new insights and design guidelines for high-performance ternary blend solar cells and suggest that ternary structure is a promising platform to boost the efficiency of OSCs.

  10. Kinetics and mechanism of catalytic hydroprocessing of components of coal-derived liquids. First quarterly report, May 15, 1979-August 15, 1979

    SciTech Connect (OSTI)

    Gates, B.C.; Katzer, J.R.; Kwart, H.; Olson, J.H.; Schuit, G.C.A.; Stiles, A.B.

    1980-09-30

    An asphaltene-containing SRC II coal liquid from the Ft. Lewis demonstration plant has been selected for study of catalytic hydroprocessing reactions. Analytical separation of the liquid by liquid chromatography will be used to produce nine distinct fractions. These will be prepared from 1 kg of coal liquid and used individually as feeds to high-pressure flow microreactors. Hydroprocessing of polynuclear aromatic hydrocarbons under industrially relevant conditions has shown that they are much more reactive than benzene. The reaction networks involve reversible hydrogenation and isomerization, and significant concentrations of hydroaromatic (hydrogen-donor) species are attainable under practical conditions. Scanning electron microscopy combined with catalytic activity measurements (in hydroprocessing of dibenzothiophene and of quinoline) were used to characterize deactivated and regenerated Ni-Mo/Al/sub 2/O/sub 3/ catalysts (aged in the hydroprocessing of coal-derived liquids). EDAX results determined chemical composition of the catalyst and the deposited mineral crust. The hydroprocessing results indicate that regeneration of the catalysts can recover much of the activity lost as a result of coke formation.

  11. Two glass transitions in miscible polymer blends?

    SciTech Connect (OSTI)

    Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.

    2014-06-28

    In contrast to mixtures of two small molecule fluids, miscible binary polymer blends often exhibit two structural relaxation times and two glass transition temperatures. Qualitative explanations postulate phenomenological models of local concentration enhancements due to chain connectivity in ideal, fully miscible systems. We develop a quantitative theory that explains qualitative trends in the dynamics of real miscible polymer blends which are never ideal mixtures. The theory is a synthesis of the lattice cluster theory of blend thermodynamics, the generalized entropy theory for glass-formation in polymer materials, and the Kirkwood-Buff theory for concentration fluctuations in binary mixtures.

  12. A review of chromatographic characterization techniques for biodiesel and biodiesel blends.

    SciTech Connect (OSTI)

    Pauls, R. E.

    2011-05-01

    This review surveys chromatographic technology that has been applied to the characterization of biodiesel and its blends. Typically, biodiesel consists of fatty acid methyl esters produced by transesterification of plant or animal derived triacylglycerols. Primary attention is given to the determination of trace impurities in biodiesel, such as methanol, glycerol, mono-, di-, and triacylglycerols, and sterol glucosides. The determination of the fatty acid methyl esters, trace impurities in biodiesel, and the determination of the biodiesel content of commercial blends of biodiesel in conventional diesel are also addressed.

  13. Fact Sheet: Effects of Intermediate Ethanol Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact Sheet: Effects of Intermediate Ethanol Blends Fact Sheet: Effects of Intermediate Ethanol Blends October 7, 2008 - 4:14pm Addthis In August 2007, the U.S. Department of Energy (DOE) initiated a test program to assess the potential impacts of higher intermediate ethanol blends on conventional vehicles and other engines that rely on gasoline. The test program focuses specifically on the effects of intermediate blends of E15 and E20-gasoline blended with 15 and 20 percent ethanol,

  14. Mid-Level Ethanol Blends Test Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mid-Level Ethanol Blends Test Program Mid-Level Ethanol Blends Test Program 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. ft005_west_2010_o.pdf (1.76 MB) More Documents & Publications Mid-Level Ethanol Blends Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009 EffectsIntermediateEthanolBlends.pdf

  15. Tropexx - Blending System - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    User-selected blending range Back-pressure control valve and regulator Compact design ... The combination of a back pressure control valve and a differential regulator is used to ...

  16. WI Biodiesel Blending Progream Final Report

    SciTech Connect (OSTI)

    Redmond, Maria E; Levy, Megan M

    2013-04-01

    The Wisconsin State Energy Office?¢????s (SEO) primary mission is to implement cost?¢???effective, reliable, balanced, and environmentally?¢???friendly clean energy projects. To support this mission the Wisconsin Biodiesel Blending Program was created to financially support the installation infrastructure necessary to directly sustain biodiesel blending and distribution at petroleum terminal facilities throughout Wisconsin. The SEO secured a federal directed award of $600,000 over 2.25 years. With these funds, the SEO supported the construction of inline biodiesel blending facilities at two petroleum terminals in Wisconsin. The Federal funding provided through the state provided a little less than half of the necessary investment to construct the terminals, with the balance put forth by the partners. Wisconsin is now home to two new biodiesel blending terminals. Fusion Renewables on Jones Island (in the City of Milwaukee) will offer a B100 blend to both bulk and retail customers. CITGO is currently providing a B5 blend to all customers at their Granville, WI terminal north of the City of Milwaukee.

  17. A New Generation of Building Insulation by Foaming Polymer Blend...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A New Generation of Building Insulation by Foaming Polymer Blend Materials with CO2 A New Generation of Building Insulation by Foaming Polymer Blend Materials with CO2 ISTN ...

  18. DPF Performance with Biodiesel Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance with Biodiesel Blends DPF Performance with Biodiesel Blends Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE ...

  19. Quality Assessment of Biodiesel and Biodiesel Blends | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality Assessment of Biodiesel and Biodiesel Blends Quality Assessment of Biodiesel and Biodiesel Blends The results of a quality survey of B20 fuel in the United States were ...

  20. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2005-02-01

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to experimentally

  1. Vehicle Technologies Office: Intermediate Ethanol Blends Research and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testing | Department of Energy Intermediate Ethanol Blends Research and Testing Vehicle Technologies Office: Intermediate Ethanol Blends Research and Testing Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline), with those in-between being called "intermediate blends." The U.S. Environmental Protection Agency's Renewable Fuels Standard (under the Energy Policy Act of 2005 and the Energy

  2. Mid-Level Ethanol Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mid-Level Ethanol Blends Mid-Level Ethanol Blends 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. ft_05_knoll.pdf (1.74 MB) More Documents & Publications Mid-Level Ethanol Blends Test Program Biofuels Quality Surveys Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

  3. Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ft003_mccormick_2011_o.pdf (820.98 KB) More Documents & Publications Performance of Biofuels and Biofuel Blends Performance of Biofuels and Biofuel Blends Quality, Performance, and Emission Impacts of

  4. Performance of Biofuels and Biofuel Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Biofuels and Biofuel Blends Performance of Biofuels and Biofuel Blends 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ft003_mccormick_2012_o.pdf (1.47 MB) More Documents & Publications Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends Performance of Biofuels and Biofuel Blends Recent Research to Address Technical Barriers to Increased Use of Biodiesel

  5. HEU to LEU conversion and blending facility: Metal blending alternative to produce LEU oxide for disposal

    SciTech Connect (OSTI)

    1995-09-01

    US DOE is examining options for disposing of surplus weapons-usable fissile materials and storage of all weapons-usable fissile materials. The nuclear material is converted to a form more proliferation- resistant than the original form. Blending HEU (highly enriched uranium) with less-enriched uranium to form LEU has been proposed as a disposition option. Five technologies are being assessed for blending HEU. This document provides data to be used in environmental impact analysis for the HEU-LEU disposition option that uses metal blending with an oxide waste product. It is divided into: mission and assumptions, conversion and blending facility descriptions, process descriptions and requirements, resource needs, employment needs, waste and emissions from plant, hazards discussion, and intersite transportation.

  6. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  7. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  8. The Blend Down Monitoring System Demonstration at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Benton, J.; Close, D.; Johnson, W., Jr.; Kerr, P.; March-Leuba, J.; Mastal, E.; Moss, C.; Powell, D.; Sumner, J.; Uckan, T.; Vines, R.; Wright, P.D.

    1999-07-25

    Agreements between the governments of the US and the Russian Federation for the US purchase of low enriched uranium (LEU) derived from highly enriched uranium (HEU) from dismantled Russian nuclear weapons calls for the establishment of transparency measures to provide confidence that nuclear nonproliferation goals are being met. To meet these transparency goals, the agreements call for the installation of nonintrusive US instruments to monitor the down blending of HEU to LEU. The Blend Down Monitoring System (BDMS) has been jointly developed by the Los Alamos National Laboratory (LANL) and the Oak Ridge National Laboratory (ORNL) to continuously monitor {sup 235}U enrichments and mass flow rates at Russian blending facilities. Prior to its installation in Russian facilities, the BDMS was installed and operated in a UF{sub 6} flow loop in the Paducah Gaseous Diffusion Plant simulating flow and enrichment conditions expected in a typical down-blending facility. A Russian delegation to the US witnessed the equipment demonstration in June, 1998. To conduct the demonstration in the Paducah Gaseous Diffusion Plant (PGDP), the BDMS was required to meet stringent Nuclear Regulatory Commission licensing, safety and operational requirements. The Paducah demonstration was an important milestone in achieving the operational certification for the BDMS use in Russian facilities.

  9. Understanding Polymorphism Formation in Electrospun Fibers of Immiscible Poly(vinylidene fluoride) Blends

    SciTech Connect (OSTI)

    G Zhong; L Zhang; R Su; K Wang; H Fong; L Zhu

    2011-12-31

    Effects of electric poling, mechanical stretching, and dipolar interaction on the formation of ferroelectric ({beta} and/or {gamma}) phases in poly(vinylidene fluoride) (PVDF) have been studied in electrospun fibers of PVDF/polyacrylonitrile (PAN) and PVDF/polysulfone (PSF) blends with PVDF as the minor component, using wide-angle X-ray diffraction and Fourier transform infrared techniques. Experimental results of as-electrospun neat PVDF fibers (beaded vs. bead-free) showed that mechanical stretching during electrospinning, rather than electric poling, was effective to induce ferroelectric phases. For as-electrospun PVDF blend fibers with the non-polar PSF matrix, mechanical stretching during electrospinning again was capable of inducing some ferroelectric phases in addition to the major paraelectric ({alpha}) phase. However, after removing the mechanical stretching in a confined melt-recrystallization process, only the paraelectric phase was obtained. For as-electrospun PVDF blend fibers with the polar (or ferroelectric) PAN matrix, strong intermolecular interactions between polar PAN and PVDF played an important role in the ferroelectric phase formation in addition to the mechanical stretching effect during electrospinning. Even after the removal of mechanical stretching through the confined melt-recrystallization process, a significant amount of ferroelectric phases persisted. Comparing the ferroelectric phase formation between PVDF/PSF and PVDF/PAN blend fibers, we concluded that the local electric field-dipole interactions were the determining factor for the nucleation and growth of polar PVDF phases.

  10. Emissions from ethanol-blended fossil fuel flames

    SciTech Connect (OSTI)

    Akcayoglu, Azize

    2011-01-15

    A fundamental study to investigate the emission characteristics of ethanol-blended fossil fuels is presented. Employing a heterogeneous experimental setup, emissions are measured from diffusion flames around spherical porous particles. Using an infusion pump, ethanol-fossil fuel blend is transpired into a porous sphere kept in an upward flowing air stream. A typical probe of portable digital exhaust gas analyzer is placed in and around the flame with the help of a multi-direction traversing mechanism to measure emissions such as un-burnt hydrocarbons, carbon monoxide and carbon dioxide. Since ethanol readily mixes with water, emission characteristics of ethanol-water blends are also studied. For comparison purpose, emissions from pure ethanol diffusion flames are also presented. A simplified theoretical analysis has been carried out to determine equilibrium surface temperature, composition of the fuel components in vapor-phase and heat of reaction of each blend. These theoretical predictions are used in explaining the emission characteristics of flames from ethanol blends. (author) This paper presents the results of an experimental study of flow structure in horizontal equilateral triangular ducts having double rows of half delta-wing type vortex generators mounted on the duct's slant surfaces. The test ducts have the same axial length and hydraulic diameter of 4 m and 58.3 mm, respectively. Each duct consists of double rows of half delta wing pairs arranged either in common flow-up or common flow-down configurations. Flow field measurements were performed using a Particle Image Velocimetry Technique for hydraulic diameter based Reynolds numbers in the range of 1000-8000. The secondary flow field differences generated by two different vortex generator configurations were examined in detail. The secondary flow is found stronger behind the second vortex generator pair than behind the first pair but becomes weaker far from the second pair in the case of Duct1. However

  11. Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance of Biofuels and Biofuel Blends Robert McCormick Vehicle Technologies Program Merit Review - Fuels and Lubricants Technologies May 16, 2013 Project ID: FT003 This presentation does not contain any proprietary, confidential, or otherwise restricted information. 2 Overview Timeline Start date: Oct 2012 End date: Sept 2013 Percent complete: 66% Program funded one year at a time Barriers VTP MYPP Fuels & Lubricants Technologies Goals * By 2013 identify light-duty (LD) non-petroleum

  12. Saturated Monoglyceride Polymorphism and Gel Formation of Biodiesel Blends

    SciTech Connect (OSTI)

    Chupka, Gina; Fouts, Lisa; McCormick, Robert

    2015-11-13

    Crystallization or gel formation of normal paraffins in diesel fuel under cold weather conditions leading to fuel filter clogging is a common problem. Cold weather operability of biodiesel (B100) and blends with diesel fuel presents additional complexity because of the presence of saturated monoglycerides (SMGs) and other relatively polar species. Currently, the cloud point measurement (a measure of when the first component crystallizes out of solution) is used to define the lowest temperature at which the fuel can be used without causing cold weather issues. While filter plugging issues have declined, there still remain intermittent unexpected problems above the cloud point for biodiesel blends. Development of a fundamental understanding of how minor components in biodiesel crystallize, gel, and transform is needed in order to prevent these unexpected issues. We have found that SMGs, a low level impurity present in B100 from the production process, can crystallize out of solution and undergo a solvent-mediated polymorphic phase transformation to a more stable, less soluble form. This causes them to persist at temperatures above the cloud point once they have some out of solution. Additionally, we have found that SMGs can cause other more soluble, lower melting point minor components in the B100 to co-crystallize and come out of solution. Monoolein, another minor component from the production process is an unsaturated monoglyceride with a much lower melting point and higher solubility than SMGs. It is able to form a co-crystal with the SMGs and is found together with the SMGs on plugged filters we have analyzed in our laboratory. An observation of isolated crystals in the lab led us to believe that the SMGs may also be forming a gel-like network with components of the B100 and diesel fuel. During filtration experiments, we have noted that in some cases a solid layer of crystals forms and blocks the filter completely, while in other cases this does not occur

  13. Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Ethanol-Gasoline Blends by Addition of Higher Alcohols Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols Mixtures of ethanol, gasoline, and higher alcohols were evaluated to determine if they offer superior performance to ethanol/gasoline blends in meeting the Renewal Fuels Standard II. deer12_ickes.pdf (1.45 MB) More Documents & Publications Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Impact of ethanol and butanol as oxygenates on

  14. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  15. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    117 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated February 2009 Prepared by Keith Knoll Brian West Wendy Clark...

  16. Preparation and characterization of polymer blend based on sulfonated...

    Office of Scientific and Technical Information (OSTI)

    blending with PEI. Structure analysis was carried out using Fourier Transform Infrared (FTIR) spectroscopy which revealed considerable interactions between sulfonic acid group of ...

  17. TANK 21 AND TANK 24 BLEND AND FEED STUDY: BLENDING TIMES, SETTLING TIMES, AND TRANSFERS

    SciTech Connect (OSTI)

    Lee, S.; Leishear, R.; Poirier, M.

    2012-05-31

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where salt solutions of up to 1.2 million gallons will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. In particular, Tanks 21 and 24 are planned to be used for blending and transferring to the SDI feed tank. These tanks were evaluated here to determine blending times, to determine a range of settling times for disturbed sludge, and to determine that the SWPF Waste Acceptance Criteria that less than 1200 mg/liter of solids will be entrained in salt solutions during transfers from the Tank 21 and Tank 24 will be met. Overall conclusions for Tank 21 and Tank 24 operations include: (1) Experimental correction factors were applied to CFD (computational fluid dynamics) models to establish blending times between approximately two and five hours. As shown in Phase 2 research, blending times may be as much as ten times greater, or more, if lighter fluids are added to heavier fluids (i.e., water added to salt solution). As the densities of two salt solutions converge this effect may be minimized, but additional confirmatory research was not performed. (2) At the current sludge levels and the presently planned operating heights of the transfer pumps, solids entrainment will be less than 1200 mg/liter, assuming a conservative, slow settling sludge simulant. (3) Based on theoretical calculations, particles in the density range of 2.5 to 5.0 g/mL must be greater than 2-4 {micro}m in diameter to ensure they settle adequately in 30-60 days to meet the SWPF feed criterion (<1200 mg/l). (4) Experimental tests with sludge batch 6 simulant and field turbidity data from a recent Tank 21 mixing evolution suggest the solid

  18. Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) to someone by E-mail Share Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) on Facebook Tweet about Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and

  19. Biorenewable tough blends of polylactide and acrylated epoxidized soybean oil compatibilized by a polylactide star polymer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mauck, Sheli C.; Wang, Shu; Ding, Wenyue; Rohde, Brian J.; Fortune, C. Karen; Yang, Guozhen; Robertson, Megan L.; Ahn, Suk -Kyun

    2016-02-26

    Polylactide (PLA), a commercially available thermoplastic derived from plant sugars, finds applications in consumer products, disposable packaging, and textiles, among others. The widespread application of this material is limited by its brittleness, as evidenced by low tensile elongation at break, impact strength, and fracture toughness. Herein, a multifunctional vegetable oil, acrylated epoxidized soybean oil (AESO), was investigated as a biodegradable, renewable additive to improve the toughness of PLA. AESO was found to be a highly reactive oil, providing a dispersed phase with tunable properties in which the acrylate groups underwent cross-linking at the elevated temperatures required for processing the blends.more » Additionally, the presence of hydroxyl groups on AESO provided two routes for compatibilization of PLA/AESO blends: (1) reactive compatibilization through the transesterification of AESO and PLA and (2) synthesis of a PLA star polymer with an AESO core. The morphological, thermal, and mechanical behaviors of PLA/oil blends were investigated, in which the dispersed oil phase consisted of AESO, soybean oil (SYBO), or a 50/50 mixture of AESO/SYBO. The oil additives were found to toughen the PLA matrix, with significant enhancements in the elongation at break and tensile toughness values, while maintaining the glass transition temperature of neat PLA. Specifically, the blend containing PLA, AESO, SYBO, and the PLA star polymer was found to exhibit a uniform oil droplet size distribution with small average droplet size and interparticle distance, resulting in the greatest enhancements of PLA tensile properties with no observable plasticization.« less

  20. Supply Chain Sustainability Analysis of Indirect Liquefaction of Blended Biomass to Produce High Octane Gasoline

    SciTech Connect (OSTI)

    Cai, Hao; Canter, Christina E.; Dunn, Jennifer B.; Tan, Eric; Biddy, Mary; Talmadge, Michael; Hartley, Damon S.; Snowden-Swan, Lesley

    2015-09-01

    The Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) aims at developing and deploying technologies to transform renewable biomass resources into commercially viable, high-performance biofuels, bioproducts and biopower through public and private partnerships (DOE, 2015). BETO also performs a supply chain sustainability analysis (SCSA). This report describes the SCSA of the production of renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of lignocellulosic biomass. This SCSA was developed for the 2017 design case for feedstock logistics (INL, 2014) and for the 2022 target case for HOG production via IDL (Tan et al., 2015). The design includes advancements that are likely and targeted to be achieved by 2017 for the feedstock logistics and 2022 for the IDL conversion process. The 2017 design case for feedstock logistics demonstrated a delivered feedstock cost of $80 per dry U.S. short ton by the year 2017 (INL, 2014). The 2022 design case for the conversion process, as modeled in Tan et al. (2015), uses the feedstock 2017 design case blend of biomass feedstocks consisting of pulpwood, wood residue, switchgrass, and construction and demolition waste (C&D) with performance properties consistent with a sole woody feedstock type (e.g., pine or poplar). The HOG SCSA case considers the 2017 feedstock design case (the blend) as well as individual feedstock cases separately as alternative scenarios when the feedstock blend ratio varies as a result of a change in feedstock availability. These scenarios could be viewed as bounding SCSA results because of distinctive requirements for energy and chemical inputs for the production and logistics of different components of the blend feedstocks.

  1. Calcination of calcium carbonate and blend therefor

    DOE Patents [OSTI]

    Mallow, William A.; Dziuk, Jr., Jerome J.

    1989-01-01

    A method for calcination of a calcium carbonate material comprising heating the calcium carbonate material to a temperature and for a time sufficient to calcine the material to the degree desired while in the presence of a catalyst; said catalyst comprising at least one fused salt having the formula MCO.sub.3.CaCO.sub.3.CaO.H.sub.2 O.sub.x, wherein M is an alkali metal and x is 0 to 1 and formed by fusing MCO.sub.3 and CaCO.sub.3 in a molar ratio of about 1:2 to 2:1, and a blend adapted to be heated to CaO comprising a calcium carbonate material and at least one such fused salt.

  2. COOLING COIL EFFECTS ON BLENDING IN A PILOT SCALE TANK

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Fowley, M.; Steeper, T.

    2010-08-26

    Blending, or mixing, processes in 1.3 million gallon nuclear waste tanks are complicated by the fact that miles of serpentine, vertical, cooling coils are installed in the tanks. As a step toward investigating blending interference due to coils in this type of tank, a 1/10.85 scale tank and pump model were constructed for pilot scale testing. A series of tests were performed in this scaled tank by adding blue dye to visualize blending, and by adding acid or base tracers to solution to quantify the time required to effectively blend the tank contents. The acid and base tests were monitored with pH probes, which were located in the pilot scale tank to ensure that representative samples were obtained. Using the probes, the hydronium ion concentration [H{sup +}] was measured to ensure that a uniform concentration was obtained throughout the tank. As a result of pilot scale testing, a significantly improved understanding of mixing, or blending, in nuclear waste tanks has been achieved. Evaluation of test data showed that cooling coils in the waste tank model increased pilot scale blending times by 200% in the recommended operating range, compared to previous theoretical estimates of a 10-50% increase. Below the planned operating range, pilot scale blending times were increased by as much as 700% in a tank with coils installed. One pump, rather than two or more, was shown to effectively blend the tank contents, and dual pump nozzles installed parallel to the tank wall were shown to provide optimal blending. In short, experimental results varied significantly from expectations.

  3. Phosphor blends for high-CRI fluorescent lamps

    SciTech Connect (OSTI)

    Setlur, Anant Achyut; Srivastava, Alok Mani; Comanzo, Holly Ann; Manivannan, Venkatesan; Beers, William Winder; Toth, Katalin; Balazs, Laszlo D.

    2008-06-24

    A phosphor blend comprises at least two phosphors each selected from one of the groups of phosphors that absorb UV electromagnetic radiation and emit in a region of visible light. The phosphor blend can be applied to a discharge gas radiation source to produce light sources having high color rendering index. A phosphor blend is advantageously includes the phosphor (Tb,Y,LuLa,Gd).sub.x(Al,Ga).sub.yO.sub.12:Ce.sup.3+, wherein x is in the range from about 2.8 to and including 3 and y is in the range from about 4 to and including 5.

  4. Differences in the Physical Characteristics of Diesel PM with Increasing Biofuel Blend Level

    Broader source: Energy.gov [DOE]

    Measure physical characteristics, carbon state, and surface bound oxygen of soot from biodiesel blends.

  5. Conversion and Blending Facility highly enriched uranium to low enriched uranium as metal. Revision 1

    SciTech Connect (OSTI)

    1995-07-05

    The mission of this Conversion and Blending Facility (CBF) will be to blend surplus HEU metal and alloy with depleted uranium metal to produce an LEU product. The primary emphasis of this blending operation will be to destroy the weapons capability of large, surplus stockpiles of HEU. The blended LEU product can only be made weapons capable again by the uranium enrichment process. The blended LEU will be produced as a waste suitable for storage or disposal.

  6. Photonic polymer-blend structures and method for making

    DOE Patents [OSTI]

    Barnes, Michael D.

    2004-06-29

    The present invention comprises the formation of photonic polymer-blend structures having tunable optical and mechanical properties. The photonic polymer-blend structures comprise monomer units of spherical microparticles of a polymer-blend material wherein the spherical microparticles have surfaces partially merged with one another in a robust inter-particle bond having a tunable inter-particle separation or bond length sequentially attached in a desired and programmable architecture. The photonic polymer-blend structures of the present invention can be linked by several hundred individual particles sequentially linked to form complex three-dimensional structures or highly ordered two-dimensional arrays of 3D columns with 2D spacing.

  7. Time phased alternate blending of feed coals for liquefaction

    DOE Patents [OSTI]

    Schweigharett, Frank; Hoover, David S.; Garg, Diwaker

    1985-01-01

    The present invention is directed to a method for reducing process performance excursions during feed coal or process solvent changeover in a coal hydroliquefaction process by blending of feedstocks or solvents over time. ,

  8. NMOG Emissions Characterizations and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2011-10-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were

  9. Low-Temperature Biodiesel Research Reveals Potential Key to Successful Blend Performance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-02-01

    Relatively low-cost solutions could improve reliability while making biodiesel blends an affordable option. While biodiesel has very low production costs and the potential to displace up to 10% of petroleum diesel, until now, issues with cold weather performance have prevented biodiesel blends from being widely adopted. Some biodiesel blends have exhibited unexplained low-temperature performance problems even at blend levels as low as 2% by volume. The most common low-temperature performance issue is vehicle stalling caused by fuel filter clogging, which prevents fuel from reaching the engine. Research at the National Renewable Energy Laboratory (NREL) reveals the properties responsible for these problems, clearing a path for the development of solutions and expanded use of energy-conserving and low-emissions alternative fuel. NREL researchers set out to study the unpredictable nature of biodiesel crystallization, the condition that impedes the flow of fuel in cold weather. Their research revealed for the first time that saturated monoglyceride impurities common to the biodiesel manufacturing process create crystals that can cause fuel filter clogging and other problems when cooling at slow rates. Biodiesel low-temperature operational problems are commonly referred to as 'precipitates above the cloud point (CP).' NREL's Advanced Biofuels team spiked distilled soy and animal fat-derived B100, as well as B20, B10, and B5 biodiesel blends with three saturated monoglycerides (SMGs) at concentration levels comparable to those of real-world fuels. Above a threshold or eutectic concentration, the SMGs (monomyristin, monopalmitin, and monostearin) were shown to significantly raise the biodiesel CP, and had an even greater impact on the final melting temperature. Researchers discovered that upon cooling, monoglyceride initially precipitates as a metastable crystal, but it transforms over time or upon slight heating into a more stable crystal with a much lower solubility and

  10. NMOG Emissions Characterization and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2012-01-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were

  11. Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection | Department of Energy Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be used in diesel engines having efficient fuel systems and combustion chamber designs that decrease fuel consumption and mitigate emissions. p-02_anitescu.pdf (339.45 KB) More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of

  12. BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Lee, S.

    2012-05-10

    Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. A three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.

  13. Conductive Polymer/Fullerene Blend Thin Films with Honeycomb Framework -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search Conductive Polymer/Fullerene Blend Thin Films with Honeycomb Framework Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Structural dynamics and charge transfer via complexation with fullerene in large area conjugated polymer honeycomb thin films (728 KB) Technology Marketing Summary This composite conductive polymer/fullerene blend

  14. A Novel Method of Injection Molding Titanium Components

    SciTech Connect (OSTI)

    Nyberg, Eric A.; Simmons, Kevin L.; Weil, K. Scott

    2005-05-01

    We have developed a unique blend of powder injection molding feedstock materials in which only a small volume fraction of binder (< 8%) is required; the remainder of the mixture consists of the metal powder and a solid aromatic solvent. Because of the nature of the decomposition in the binder system and the relatively small amount used, the binder is eliminated almost completely from the pre-sintered component during the initial stage of a two-step heat treatment process.

  15. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M. E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C. E-mail: christian.bonten@ikt.uni-stuttgart.de

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  16. Blending of Radioactive Salt Solutions in Million Gallon Tanks - 13002

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2013-07-01

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 - 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, 'One good experiment fixes a lot of good theory'. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks. (authors)

  17. Blending Of Radioactive Salt Solutions In Million Gallon Tanks

    SciTech Connect (OSTI)

    Leishear, Robert A.; Lee, Si Y.; Fowley, Mark D.; Poirier, Michael R.

    2012-12-10

    Research was completed at Savannah River National Laboratory (SRNL) to investigate processes related to the blending of radioactive, liquid waste, salt solutions in 4920 cubic meter, 25.9 meter diameter storage tanks. One process was the blending of large salt solution batches (up to 1135 ? 3028 cubic meters), using submerged centrifugal pumps. A second process was the disturbance of a settled layer of solids, or sludge, on the tank bottom. And a third investigated process was the settling rate of sludge solids if suspended into slurries by the blending pump. To investigate these processes, experiments, CFD models (computational fluid dynamics), and theory were applied. Experiments were performed using simulated, non-radioactive, salt solutions referred to as supernates, and a layer of settled solids referred to as sludge. Blending experiments were performed in a 2.44 meter diameter pilot scale tank, and flow rate measurements and settling tests were performed at both pilot scale and full scale. A summary of the research is presented here to demonstrate the adage that, ?One good experiment fixes a lot of good theory?. Experimental testing was required to benchmark CFD models, or the models would have been incorrectly used. In fact, CFD safety factors were established by this research to predict full-scale blending performance. CFD models were used to determine pump design requirements, predict blending times, and cut costs several million dollars by reducing the number of required blending pumps. This research contributed to DOE missions to permanently close the remaining 47 of 51 SRS waste storage tanks.

  18. Photo-response of a P3HT:PCBM blend in metal-insulator-semiconductor capacitors

    SciTech Connect (OSTI)

    Devynck, M.; Rostirolla, B.; Watson, C. P.; Taylor, D. M.

    2014-11-03

    Metal-insulator-semiconductor capacitors are investigated, in which the insulator is cross-linked polyvinylphenol and the active layer a blend of poly(3-hexylthiophene), P3HT, and the electron acceptor [6,6]-phenyl-C{sub 61}-butyric acid methyl ester (PCBM). Admittance spectra and capacitance-voltage measurements obtained in the dark both display similar behaviour to those previously observed in P3HT-only devices. However, the photo-capacitance response is significantly enhanced in the P3HT:PCBM case, where exciton dissociation leads to electron transfer into the PCBM component. The results are consistent with a network of PCBM aggregates that is continuous through the film but with no lateral interconnection between the aggregates at or near the blend/insulator interface.

  19. Controlled differential pressure system for an enhanced fluid blending apparatus

    SciTech Connect (OSTI)

    Hallman, Jr., Russell Louis

    2009-02-24

    A system and method for producing a controlled blend of two or more fluids. Thermally-induced permeation through a permeable tube is used to mix a first fluid from outside the tube with a second fluid flowing through the tube. Mixture ratios may be controlled by adjusting the temperature of the first fluid or by adjusting the pressure drop through the permeable tube. The combination of a back pressure control valve and a differential regulator is used to control the output pressure of the blended fluid. The combination of the back pressure control valve and differential regulator provides superior flow control of the second dry gas. A valve manifold system may be used to mix multiple fluids, and to adjust the volume of blended fluid produced, and to further modify the mixture ratio.

  20. Exploiting Photo-induced Reactions in Polymer Blends to Create Hierarchically Ordered, Defect-free Materials

    ScienceCinema (OSTI)

    Balazs, Anna [University of Pittsburgh, Pittsburgh, Pennsylvania, United States

    2010-01-08

    Computer simulations reveal how photo-induced chemical reactions can be exploited to create long-range order in binary and ternary polymeric materials. The process is initiated by shining a spatially uniform light over a photosensitive AB binary blend, which undergoes both a reversible chemical reaction and phase separation. We then introduce a well-collimated, higher-intensity light source. Rastering this secondary light over the sample locally increases the reaction rate and causes formation of defect-free, spatially periodic structures. These binary structures resemble either the lamellar or hexagonal phases of microphase-separated di-block copolymers. We measure the regularity of the ordered structures as a function of the relative reaction rates for different values of the rastering speed and determine the optimal conditions for creating defect-free structures in the binary systems. We then add a non-reactive homo-polymer C, which is immiscible with both A and B. We show that this component migrates to regions that are illuminated by the secondary, higher-intensity light, allowing us to effectively write a pattern of C onto the AB film. Rastering over the ternary blend with this collimated light now leads to hierarchically ordered patterns of A, B, and C. The findings point to a facile, non-intrusive process for manufacturing high-quality polymeric devices in a low-cost, efficient manner.

  1. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape

    2005-12-01

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  2. Modeling Tools for Flammability Ranking of Low-GWP Refrigerant Blends |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Modeling Tools for Flammability Ranking of Low-GWP Refrigerant Blends Modeling Tools for Flammability Ranking of Low-GWP Refrigerant Blends Credit: National Institute of Standards and Technology Credit: National Institute of Standards and Technology Modeling Tools for Flammability Ranking of Low-GWP Refrigerant Blends Credit: National Institute of Standards and Technology Modeling Tools for Flammability Ranking of Low-GWP Refrigerant Blends Lead Performer: National

  3. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  4. H Canyon Moves Closer to Low Enriched Uranium Blend Down

    Broader source: Energy.gov [DOE]

    AIKEN, S.C. – The Savannah River Site’s (SRS) H Canyon has moved closer to restarting low enriched uranium (LEU) blend down by turning on the First Cycle unit operation for the first time in more than five years.

  5. Vehicle Technologies Office: Intermediate Ethanol Blends Research and Testing

    Broader source: Energy.gov [DOE]

    DOE's Vehicle Technologies Office supported work to examine the impact of intermediate ethanol blends on passenger vehicles, outdoor equipment and generator sets. Based on this research, the EPA issued waivers allowing vehicles from model year 2001 and beyond to use E15.

  6. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, T.

    A polymer blend is disclosed of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  7. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, Terje

    1984-01-01

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  8. U.S. transparency monitoring of HEU oxide conversion and blending to LEU hexafluoride at three Russian blending plants

    SciTech Connect (OSTI)

    Leich, D., LLNL

    1998-07-27

    The down-blending of Russian highly enriched uranium (HEU) takes place at three Russian gaseous centrifuge enrichment plants. The fluorination of HEU oxide and down-blending of HEU hexafluoride began in 1994, and shipments of low enriched uranium (LEU) hexafluoride product to the United States Enrichment Corporation (USEC) began in 1995 US transparency monitoring under the HEU Purchase Agreement began in 1996 and includes a permanent monitoring presence US transparency monitoring at these facilities is intended to provide confidence that HEU is received and down-blended to LEU for shipment to USEC The monitoring begins with observation of the receipt of HEU oxide shipments, including confirmation of enrichment using US nondestructive assay equipment The feeding of HEU oxide to the fluorination process and the withdrawal of HEU hexafluoride are monitored Monitoring is also conducted where the blending takes place and where shipping cylinders are filled with LEU product. A series of process and material accountancy documents are provided to US monitors.

  9. Development and Demonstration of Hydrogen and Compressed Natural Gas (H/CNG) Blend Transit Buses: October 15, 2002-September 30, 2004

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Development and Demonstration of Hydrogen and Compressed Natural Gas (H/CNG) Blend Transit Buses October 15, 2002 - September 30, 2004 A. Del Toro SunLine Services Group Thousand Palms, California M. Frailey National Renewable Energy Laboratory Golden, Colorado F. Lynch Hydrogen Components Inc. Littleton, Colorado S. Munshi Westport Innovations Inc. Vancouver, British Columbia, Canada S. Wayne West Virginia University Morgantown, West Virginia Technical Report NREL/TP-540-38707 November 2005

  10. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for

  11. Major Components of Lending

    Broader source: Energy.gov [DOE]

    The major components of a clean energy financing program are described below, centered around the characteristics and sources of capital.

  12. Reactor component automatic grapple

    DOE Patents [OSTI]

    Greenaway, Paul R.

    1982-01-01

    A grapple for handling nuclear reactor components in a medium such as liquid sodium which, upon proper seating and alignment of the grapple with the component as sensed by a mechanical logic integral to the grapple, automatically seizes the component. The mechanical logic system also precludes seizure in the absence of proper seating and alignment.

  13. High-Octane Mid-Level Ethanol Blend Market Assessment

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    High-Octane Mid-Level Ethanol Blend Market Assessment Caley Johnson, Emily Newes, Aaron Brooker, and Robert McCormick National Renewable Energy Laboratory Steve Peterson Lexidyne, LLC Paul Leiby, Rocio Uria Martinez, and Gbadebo Oladosu Oak Ridge National Laboratory Maxwell L. Brown Colorado School of Mines Technical Report NREL/TP-5400-63698 December 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance

  14. Evaluation of Ethanol Blends for PHEVs using Simulation and

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Distillation Curve Method | Department of Energy Supercritical transesterification processing permits efficient fuel system and combustion chamber designs to optimize fuel utilization in diesel engines., p-01_anitescu.pdf (408.75 KB) More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Algae Biofuels Technology Energy

    This research effort is a part of the

  15. Review Of Rheology Models For Hanford Waste Blending

    SciTech Connect (OSTI)

    Koopman, D. C.; Stone, M.

    2013-09-26

    The area of rheological property prediction was identified as a technology need in the Hanford Tank Waste - waste feed acceptance initiative area during a series of technical meetings among the national laboratories, Department of Energy-Office of River Protection, and Hanford site contractors. Meacham et al. delivered a technical report in June 2012, RPP-RPT-51652 ''One System Evaluation of Waste Transferred to the Waste Treatment Plant'' that included estimating of single shell tank waste Bingham plastic rheological model constants along with a discussion of the issues inherent in predicting the rheological properties of blended wastes. This report was selected as the basis for moving forward during the technical meetings. The report does not provide an equation for predicting rheological properties of blended waste slurries. The attached technical report gives an independent review of the provided Hanford rheological data, Hanford rheological models for single tank wastes, and Hanford rheology after blending provided in the Meacham report. The attached report also compares Hanford to SRS waste rheology and discusses some SRS rheological model equations for single tank wastes, as well as discussing SRS experience with the blending of waste sludges with aqueous material, other waste sludges, and frit slurries. Some observations of note: Savannah River Site (SRS) waste samples from slurried tanks typically have yield stress >1 Pa at 10 wt.% undissolved solids (UDS), while core samples largely have little or no yield stress at 10 wt.% UDS. This could be due to how the waste has been processed, stored, retrieved, and sampled or simply in the differences in the speciation of the wastes. The equations described in Meacham's report are not recommended for extrapolation to wt.% UDS beyond the available data for several reasons; weak technical basis, insufficient data, and large data scatter. When limited data are available, for example two to three points, the equations

  16. Investigation of Knock limited Compression Ratio of Ethanol Gasoline Blends

    SciTech Connect (OSTI)

    Szybist, James P; Youngquist, Adam D; Wagner, Robert M; Moore, Wayne; Foster, Matthew; Confer, Keith

    2010-01-01

    Ethanol offers significant potential for increasing the compression ratio of SI engines resulting from its high octane number and high latent heat of vaporization. A study was conducted to determine the knock limited compression ratio of ethanol gasoline blends to identify the potential for improved operating efficiency. To operate an SI engine in a flex fuel vehicle requires operating strategies that allow operation on a broad range of fuels from gasoline to E85. Since gasoline or low ethanol blend operation is inherently limited by knock at high loads, strategies must be identified which allow operation on these fuels with minimal fuel economy or power density tradeoffs. A single cylinder direct injection spark ignited engine with fully variable hydraulic valve actuation (HVA) is operated at WOT conditions to determine the knock limited compression ratio (CR) of ethanol fuel blends. The geometric compression ratio is varied by changing pistons, producing CR from 9.2 to 13.66. The effective CR is varied using an electro-hydraulic valvetrain that changed the effective trapped displacement using both Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC). The EIVC and LIVC strategies result in effective CR being reduced while maintaining the geometric expansion ratio. It was found that at substantially similar engine conditions, increasing the ethanol content of the fuel results in higher engine efficiency and higher engine power. These can be partially attributed to a charge cooling effect and a higher heating valve of a stoichiometric mixture for ethanol blends (per unit mass of air). Additional thermodynamic effects on and a mole multiplier are also explored. It was also found that high CR can increase the efficiency of ethanol fuel blends, and as a result, the fuel economy penalty associated with the lower energy content of E85 can be reduced by about a third. Such operation necessitates that the engine be operated in a de-rated manner for

  17. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations p-21_ramirez.pdf (351.23 KB) More Documents & Publications HD Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance Characterization of Dual-Fuel

  18. Electronic and structural characteristics of zinc-blende wurtzite biphasic homostructure GaN nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jacobs, Benjamin W.; Ayres, Virginia M.; Petkov, Mihail P.; Halpern, Joshua B.; He, Maoqi; Baczewski, Andrew D.; McElroy, Kaylee; Crimp, Martin A.; Zhang, Jiaming; Shaw, Harry C.

    2016-02-01

    Here, we report a new biphasic crystalline wurtzite/zinc-blende homostructure in gallium nitride nanowires. Cathodoluminescence was used to quantitatively measure the wurtzite and zinc-blende band gaps. High-resolution transmission electron microscopy was used to identify distinct wurtzite and zinc-blende crystalline phases within single nanowires through the use of selected area electron diffraction, electron dispersive spectroscopy, electron energy loss spectroscopy, and fast Fourier transform techniques. A mechanism for growth is identified.

  19. Effects of intermediate ethanol blends on legacy vehicles and small non-road engines, report 1

    SciTech Connect (OSTI)

    West, Brian; Knoll, Keith; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2008-10-01

    Report on the test program to assess the viability of using intermediate ethanol blends as a contributor to meeting national goals in the use of renewable fuels.

  20. Single Stage Contactor Testing Of The Next Generation Solvent Blend

    SciTech Connect (OSTI)

    Herman, D. T.; Peters, T. B.; Duignan, M. R.; Williams, M. R.; Poirier, M. R.; Brass, E. A.; Garrison, A. G.; Ketusky, E. T.

    2014-01-06

    The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility at the Savannah River Site (SRS) is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent to increase the cesium decontamination factor. To support this integration of NGS into the MCU facility the Savannah River National Laboratory (SRNL) performed testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing utilized a blend of BOBCalixC6 based solvent and the NGS with the new extractant, MaxCalix, as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 liquid-to-liquid centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. The results indicate that hydraulically, the NGS solvent performed hydraulically similar to the current solvent which was expected. For the organic carryover 93% of the solvent is predicted to be recovered from the stripping operation and 96% from the extraction operation. As for the mass transfer, the NGS solvent significantly improved the cesium DF by at least an order of magnitude when extrapolating the One-stage results to actual Seven-stage extraction operation with a stage efficiency of 95%.

  1. Hydrogen effects on materials for CNG/H2 blends.

    SciTech Connect (OSTI)

    Farese, David; Keller, Jay O.; Somerday, Brian P.

    2010-09-01

    No concerns for Hydrogen-Enriched Compressed Natural gas (HCNG) in steel storage tanks if material strength is < 950 MPa. Recommend evaluating H{sub 2}-assisted fatigue cracking in higher strength steels at H{sub 2} partial pressure in blend. Limited fatigue testing on higher strength steel cylinders in H{sub 2} shows promising results. Impurities in Compressed Natural Gas (CNG) (e.g., CO) may provide extrinsic mechanism for mitigating H{sub 2}-assisted fatigue cracking in steel tanks.

  2. Microsoft Word - Int_blends_Rpt1_Updated.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TP-540-43543 ORNL/TM-2008/117 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated February 2009 Prepared by Keith Knoll Brian West Wendy Clark Ronald Graves John Orban Steve Przesmitzki Timothy Theiss DOCUMENT AVAILABILITY Reports produced after January 1, 1996, are generally available free via the U.S. Department of Energy (DOE) Information Bridge. Web site http://www.osti.gov/bridge Reports produced before January 1, 1996, may be purchased

  3. Table B1. Pipe Manufacturer Compatibility with Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    B1. Pipe Manufacturer Compatibility with Ethanol Blends Manufacturer Product Model Ethanol Compatibility Piping-All Companies have UL 971 listing for E100 Advantage Earth Products Piping 1.5", 2", 3", 4" E0-E100 Brugg Piping FLEXWELL-HL, SECON-X, NITROFLEX, LPG E0-E100 Franklin Fueling Piping Franklin has third-party certified piping compatible with up to E85. Contact manufacturer for specific part numbers. E0-E85 OPW Piping FlexWorks, KPS, Pisces (discontinued) E0-E100 NOV

  4. Ceramic component for electrodes

    DOE Patents [OSTI]

    Marchant, David D.

    1979-01-01

    A ceramic component suitable for preparing MHD generator electrodes consists of HfO.sub.2 and sufficient Tb.sub.4 O.sub.7 to stabilize at least 60 volume percent of the HfO.sub.2 into the cubic structure. The ceramic component may also contain a small amount of PrO.sub.2, Yb.sub.2 O.sub.3 or a mixture of both to improve stability and electronic conductivity of the electrode. The component is highly resistant to corrosion by molten potassium seed and molten coal slag in the MHD fluid and exhibits both ionic and electronic conductivity.

  5. Montena Components | Open Energy Information

    Open Energy Info (EERE)

    Components Jump to: navigation, search Name: Montena Components Place: Rossens, Switzerland Zip: CH 1728 Product: Montena Components is a manufacturer of ultracapacitors and...

  6. Integrating Program Component Executables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrating Program Component Executables on Distributed Memory Architectures via MPH Chris Ding and Yun He Computational Research Division, Lawrence Berkeley National Laboratory University of California, Berkeley, CA 94720, USA chqding@lbl.gov, yhe@lbl.gov Abstract A growing trend in developing large and complex ap- plications on today's Teraflop computers is to integrate stand-alone and/or semi-independent program components into a comprehensive simulation package. One example is the climate

  7. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

    Broader source: Energy.gov [DOE]

    Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

  8. Fabrication of chitosan/polyacrylonitrile blend and semi-IPN hydrogel with epichlorohydrin

    SciTech Connect (OSTI)

    Aijaz, Muhammad Omer; Haider, Sajjad Al Mubddel, Fahad S.; Al Masry, Waheed A.

    2015-05-22

    The present study is focused on the preparation of chitosan (CS)/polyacrylonitrile (PAN) blend and semi-interpenetrating polymer network (sIPN). Blend CS/PAN hydrogel films (HFs) were prepared by solution blending and casting technique. CS in the blend was crosslinked with epichlorohydrin (ECH) to prepare sIPN. The developed CS/PAN blend and sIPN hydrogels were characterized with Field Emission Scanning Electron Microscopy (FE-SEM), Fourier transform infrared spectroscopy (FTIR), Thermagravimetric analysis (TGA), and Differential Scanning Calorimeter (DSC). The result showed good miscibility between CS and PAN and crosslinking of CS in the blend. The swelling of the different blended and sIPN hydrogels samples were examined at room temperature (T{sub r}). Blend (C80/P20) sample showed highest swelling (∼2400%) and fair degree of stability (∼28% until 96 h), whereas sIPN hydrogel exhibited relatively low degree of swelling (∼244%) and high degree of aqueous (∼85 % until 96 h), and thermal (onset temperature 304°C) stabilities.

  9. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito

    2008-05-15

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  10. The Impact of Ethanol Blending on U.S. Gasoline Prices

    SciTech Connect (OSTI)

    none,

    2008-11-01

    This study assesses the impact of ethanol blending on gasoline prices in the United States today and the potential impact of ethanol on gasoline prices at higher blending concentrations (10%, 15% and 20% of the total U.S. gasoline consumption).

  11. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends

    SciTech Connect (OSTI)

    2013-09-17

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  12. Handbook for Handling, Storing, and Dispensing E85 and Other Ethanol-Gasoline Blends (Book)

    SciTech Connect (OSTI)

    Moriarty, K.

    2013-09-01

    This document serves as a guide for blenders, distributors, sellers, and users of E85 and other ethanol blends above E10. It provides basic information on the proper and safe use of E85 and other ethanol blends and includes supporting technical and policy references.

  13. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non‑Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian H; Clark, Wendy; Graves, Ronald L; Orban, John; Przesmitzki, Steve; Theiss, Timothy J

    2009-02-01

    In summer 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20--gasoline blended with 15 and 20% ethanol--on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This first report provides the results available to date from the first stages of a much larger overall test program. Results from additional projects that are currently underway or in the planning stages are not included in this first report. The purpose of this initial study was to quickly investigate the effects of adding up to 20% ethanol to gasoline on the following: (1) Regulated tailpipe emissions for 13 popular late model vehicles on a drive cycle similar to real-world driving and 28 small non-road engines (SNREs) under certification or typical in use procedures. (2) Exhaust and catalyst temperatures of the same vehicles under more severe conditions. (3) Temperature of key engine components of the same SNREs under certification or typical in-use conditions. (4) Observable operational issues with either the vehicles or SNREs during the course of testing. As discussed in the concluding section of this report, a wide range of additional studies are underway or planned to consider the effects of intermediate ethanol blends on materials, emissions, durability, and driveability of vehicles, as well as impacts on a wider range of nonautomotive engines, including marine applications, snowmobiles, and motorcycles. Section 1 (Introduction) gives background on the test program and describes collaborations with industry and agencies to date. Section 2

  14. Properties and hydration of blended cements with steelmaking slag

    SciTech Connect (OSTI)

    Kourounis, S.; Tsivilis, S. . E-mail: stsiv@central.ntua.gr; Tsakiridis, P.E.; Papadimitriou, G.D.; Tsibouki, Z.

    2007-06-15

    The present research study investigates the properties and hydration of blended cements with steelmaking slag, a by-product of the conversion process of iron to steel. For this purpose, a reference sample and three cements containing up to 45% w/w steel slag were tested. The steel slag fraction used was the '0-5 mm', due to its high content in calcium silicate phases. Initial and final setting time, standard consistency, flow of normal mortar, autoclave expansion and compressive strength at 2, 7, 28 and 90 days were measured. The hydrated products were identified by X-ray diffraction while the non-evaporable water was determined by TGA. The microstructure of the hardened cement pastes and their morphological characteristics were examined by scanning electron microscopy. It is concluded that slag can be used in the production of composite cements of the strength classes 42.5 and 32.5 of EN 197-1. In addition, the slag cements present satisfactory physical properties. The steel slag slows down the hydration of the blended cements, due to the morphology of contained C{sub 2}S and its low content in calcium silicates.

  15. JV Task 112-Optimal Ethanol Blend-Level Investigation

    SciTech Connect (OSTI)

    Richard Shockey; Ted Aulich; Bruce Jones; Gary Mead; Paul Steevens

    2008-01-31

    Highway Fuel Economy Test (HWFET) and Federal Test Procedure 75 (FTP-75) tests were conducted on four 2007 model vehicles; a Chevrolet Impala flex-fuel and three non-flex-fuel vehicles: a Ford Fusion, a Toyota Camry, and a Chevrolet Impala. This investigation utilized a range of undenatured ethanol/Tier II gasoline blend levels from 0% to 85%. HWFET testing on ethanol blend levels of E20 in the flex fuel Chevrolet Impala and E30 in the non-flex-fuel Ford Fusion and Toyota Camry resulted in miles-per-gallon (mpg) fuel economy greater than Tier 2 gasoline, while E40 in the non-flex-fuel Chevrolet Impala resulted in an optimum mpg based on per-gallon fuel Btu content. Exhaust emission values for non-methane organic gases (NMOG), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) obtained from both the FTP-75 and the HWFET driving cycles were at or below EPA Tier II, Light-Duty Vehicles, Bin 5 levels for all vehicles tested with one exception. The flex-fuel Chevrolet Impala exceeded the NMOG standard for the FTP-75 on E-20 and Tier II gasoline.

  16. Modeling the Auto-Ignition of Biodiesel Blends with a Multi-Step Model

    SciTech Connect (OSTI)

    Toulson, Dr. Elisa; Allen, Casey M; Miller, Dennis J; McFarlane, Joanna; Schock, Harold; Lee, Tonghun

    2011-01-01

    There is growing interest in using biodiesel in place of or in blends with petrodiesel in diesel engines; however, biodiesel oxidation chemistry is complicated to directly model and existing surrogate kinetic models are very large, making them computationally expensive. The present study describes a method for predicting the ignition behavior of blends of n-heptane and methyl butanoate, fuels whose blends have been used in the past as a surrogate for biodiesel. The autoignition is predicted using a multistep (8-step) model in order to reduce computational time and make this a viable tool for implementation into engine simulation codes. A detailed reaction mechanism for n-heptane-methyl butanoate blends was used as a basis for validating the multistep model results. The ignition delay trends predicted by the multistep model for the n-heptane-methyl butanoate blends matched well with that of the detailed CHEMKIN model for the majority of conditions tested.

  17. Understanding how processing additives tune nanoscale morphology of high efficiency organic photovoltaic blends: From casting solution to spun-cast thin film

    SciTech Connect (OSTI)

    Shao, Ming [ORNL; Keum, Jong Kahk [ORNL; Kumar, Rajeev [ORNL; Chen, Jihua [ORNL; Browning, Jim [ORNL; Chen, Wei [Argonne National Laboratory (ANL); Jianhui, Hou [Chinese Academy of Sciences (CAS), Institute of Chemistry; Do, Changwoo [ORNL; Littrell, Ken [ORNL; Sanjib, Das [University of Tennessee, Knoxville (UTK); Rondinone, Adam Justin [ORNL; Geohegan, David B [ORNL; Sumpter, Bobby G [ORNL; Xiao, Kai [ORNL

    2014-01-01

    Adding a small amount of a processing additive to the casting solution of organic blends has been demonstrated to be an effective method for achieving improved power conversion efficiency (PCE) in organic photovoltaics (OPVs). However, an understanding of the nano-structural evolution occurring in the transformation from casting solution to thin photoactive films is still lacking. In this report, we investigate the effects of the processing additive diiodooctane (DIO) on the morphology of OPV blend of PBDTTT-C-T and fullerene derivative, PC71BM in a casting solution and in spun-cast thin films by using neutron/x-ray scattering, neutron reflectometry and other characterization techniques. The results reveal that DIO has no effect on the solution structures of PBDTTT-C-T and PC71BM. In the spun-cast films, however, DIO is found to promote significantly the molecular ordering of PBDTTT-C-T and PC71BM, and phase segregation, resulting in the improved PCE. Thermodynamic analysis based on Flory-Huggins theory provides a rationale for the effects of DIO on different characteristics of phase segregation as a solvent and due to evaporationg during the film formation. Such information may enable improved rational design of ternary blends to more consistently achieve improved PCE for OPVs.

  18. Components in the Pipeline

    SciTech Connect (OSTI)

    Gorton, Ian; Wynne, Adam S.; Liu, Yan; Yin, Jian

    2011-02-24

    Scientists commonly describe their data processing systems metaphorically as software pipelines. These pipelines input one or more data sources and apply a sequence of processing steps to transform the data and create useful results. While conceptually simple, pipelines often adopt complex topologies and must meet stringent quality of service requirements that place stress on the software infrastructure used to construct the pipeline. In this paper we describe the MeDICi Integration Framework, which is a component-based framework for constructing complex software pipelines. The framework supports composing pipelines from distributed heterogeneous software components and provides mechanisms for controlling qualities of service to meet demanding performance, reliability and communication requirements.

  19. Ceramic component for electrodes

    DOE Patents [OSTI]

    Marchant, David D.; Bates, J. Lambert

    1980-01-01

    A ceramic component suitable for preparing MHD generator electrodes having the compositional formula: Y.sub.x (Mg.sub.y Cr.sub.z).sub.w Al.sub.(1-w) O.sub.3 where x=0.9 to 1.05, y=0.02 to 0.2, z=0.8 to 1.05 and w=1.0 to 0.5. The component is resistant to the formation of hydration products in an MHD environment, has good electrical conductivity and exhibits a lower electrochemical corrosion rate than do comparable compositions of lanthanum chromite.

  20. Materials & Components Compatibility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Components Compatibility - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  1. Influence of Substrate on Crystallization in Polythiophene/fullerene Blends

    SciTech Connect (OSTI)

    C He; D Germack; J Kline; D Delongchamp; D Fischer; C Snyder; M Toney; J Kushmerick; L Richter

    2011-12-31

    The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment is used to optimize the morphology. In general, the development of microscopic crystals is deleterious, as the exciton diffusion length is {approx}10 nm. We find that the microscopic crystallization behavior in polythiophene/fullerene blends is strongly influenced by the substrate on which the BHJ is cast. With a silicon oxide substrate, the crystal nucleation density is high and significant crystallization occurs at a temperature of 140 C. On more hydrophobic substrates, significantly higher temperatures are required for observable crystallization. This difference is attributed to the interfacial segregation of the PCBM, controlled by the substrate surface energy. The substrate dependence of crystallization has significant implications on the fullerene crystal growth mechanisms and practical implications for device studies.

  2. Identification and quantification of organic chemicals in supplemental fuel blends

    SciTech Connect (OSTI)

    Salter, F.

    1996-12-31

    Continental Cement Company, Inc. (Continental) burns waste fuels to supplement coal in firing the kiln. It is to be expected that federal and state agencies want an accounting of the chemicals burned. As rules and regulations become more plentiful, a company such as Continental must demonstrate that it has made a reasonable attempt to identify and quantify many specific organic compounds. The chemicals on the SARA 313 list can change frequently. Also the number and concentrations of compounds that can disqualify a material from consideration as a supplemental fuel at Continental continues to change. A quick and reliable method of identifying and quantifying organics in waste fuel blends is therefore crucial. Using a Hewlett-Packard 5972 GC/MS system Continental has developed a method of generating values for the total weight of compounds burned. A similar procedure is used to verify that waste streams meet Continental`s acceptance criteria.

  3. Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction

    SciTech Connect (OSTI)

    Andile B. Mzinyati

    2007-09-15

    The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

  4. A charge carrier transport model for donor-acceptor blend layers

    SciTech Connect (OSTI)

    Fischer, Janine Widmer, Johannes; Koerner, Christian; Vandewal, Koen; Leo, Karl; Kleemann, Hans; Tress, Wolfgang; Riede, Moritz

    2015-01-28

    Highly efficient organic solar cells typically comprise donor-acceptor blend layers facilitating effective splitting of excitons. However, the charge carrier mobility in the blends can be substantially smaller than in neat materials, hampering the device performance. Currently, available mobility models do not describe the transport in blend layers entirely. Here, we investigate hole transport in a model blend system consisting of the small molecule donor zinc phthalocyanine (ZnPc) and the acceptor fullerene C{sub 60} in different mixing ratios. The blend layer is sandwiched between p-doped organic injection layers, which prevent minority charge carrier injection and enable exploiting diffusion currents for the characterization of exponential tail states from a thickness variation of the blend layer using numerical drift-diffusion simulations. Trap-assisted recombination must be considered to correctly model the conductivity behavior of the devices, which are influenced by local electron currents in the active layer, even though the active layer is sandwiched in between p-doped contacts. We find that the density of deep tail states is largest in the devices with 1:1 mixing ratio (E{sub t} = 0.14 eV, N{sub t} = 1.2 × 10{sup 18 }cm{sup −3}) directing towards lattice disorder as the transport limiting process. A combined field and charge carrier density dependent mobility model are developed for this blend layer.

  5. Measurement of biodiesel blend and conventional diesel spray structure using x-ray radiography.

    SciTech Connect (OSTI)

    Kastengren, A. L.; Powell, C. F.; Wang, Y. J.; IM, K. S.; Wang, J.

    2009-11-01

    The near-nozzle structure of several nonevaporating biodiesel-blend sprays has been studied using X-ray radiography. Radiography allows quantitative measurements of the fuel distribution in sprays to be made with high temporal and spatial resolution. Measurements have been made at different values of injection pressure, ambient density, and with two different nozzle geometries to understand the influences of these parameters on the spray structure of the biodiesel blend. These measurements have been compared with corresponding measurements of Viscor, a diesel calibration fluid, to demonstrate the fuel effects on the spray structure. Generally, the biodiesel-blend spray has a similar structure to the spray of Viscor. For the nonhydroground nozzle used in this study, the biodiesel-blend spray has a slightly slower penetration into the ambient gas than the Viscor spray. The cone angle of the biodiesel-blend spray is generally smaller than that of the Viscor spray, indicating that the biodiesel-blend spray is denser than the Viscor spray. For the hydroground nozzle, both fuels produce sprays with initially wide cone angles that transition to narrow sprays during the steady-state portion of the injection event. These variations in cone angle with time occur later for the biodiesel-blend spray than for the Viscor spray, indicating that the dynamics of the injector needle as it opens are somewhat different for the two fuels.

  6. Component for thermoelectric generator

    DOE Patents [OSTI]

    Purdy, David L.

    1977-01-01

    In a thermoelectric generator, a component comprises a ceramic insulator, having over limited areas thereof, each area corresponding to a terminal end of thermoelectric wires, a coating of a first metal which adheres to the insulator, and an electrical thermoelectric junction including a second metal which wets said first metal and adheres to said terminal ends but does not wet said insulator, and a cloth composed of electrically insulating threads interlaced with thermoelectric wires.

  7. Solid state lighting component

    DOE Patents [OSTI]

    Yuan, Thomas; Keller, Bernd; Ibbetson, James; Tarsa, Eric; Negley, Gerald

    2010-10-26

    An LED component comprising an array of LED chips mounted on a planar surface of a submount with the LED chips capable of emitting light in response to an electrical signal. The LED chips comprise respective groups emitting at different colors of light, with each of the groups interconnected in a series circuit. A lens is included over the LED chips. Other embodiments can comprise thermal spreading structures included integral to the submount and arranged to dissipate heat from the LED chips.

  8. Solid state lighting component

    DOE Patents [OSTI]

    Keller, Bernd; Ibbetson, James; Tarsa, Eric; Negley, Gerald; Yuan, Thomas

    2012-07-10

    An LED component comprising an array of LED chips mounted on a planar surface of a submount with the LED chips capable of emitting light in response to an electrical signal. The LED chips comprise respective groups emitting at different colors of light, with each of the groups interconnected in a series circuit. A lens is included over the LED chips. Other embodiments can comprise thermal spreading structures included integral to the submount and arranged to dissipate heat from the LED chips.

  9. Injection molded component

    DOE Patents [OSTI]

    James, Allister W; Arrell, Douglas J

    2014-09-30

    An intermediate component includes a first wall member, a leachable material layer, and a precursor wall member. The first wall member has an outer surface and first connecting structure. The leachable material layer is provided on the first wall member outer surface. The precursor wall member is formed adjacent to the leachable material layer from a metal powder mixed with a binder material, and includes second connecting structure.

  10. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.

    2013-05-10

    In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR

  11. Surface mount component jig

    DOE Patents [OSTI]

    Kronberg, James W.

    1990-08-07

    A device for bending and trimming the pins of a dual-inline-package component and the like for surface mounting rather than through mounting to a circuit board comprises, in a first part, in pin cutter astride a holder having a recess for holding the component, a first spring therebetween, and, in a second part, two flat members pivotally interconnected by a hinge and urged to an upward peaked position from a downward peaked position by a second spring. As a downward force is applied to the pin cutter it urges the holder downward, assisted by the first spring and a pair of ridges riding on shoulders of the holder, to carry the component against the upward peaked flat members which guide the pins outwardly. As the holder continues downwardly, the flat members pivot to the downward peaked position bending the pins upwardly against the sides of the holder. When the downward movement is met with sufficient resistance, the ridges of the pin cutter ride over the holder's shoulders to continue downward to cut any excess length of pin.

  12. Energetic component treatability study

    SciTech Connect (OSTI)

    Gildea, P.D.; Brandon, S.L.; Brown, B.G. [and others

    1997-11-01

    The effectiveness of three environmentally sound processes for small energetic component disposal was examined experimentally in this study. The three destruction methods, batch reactor supercritical water oxidation, sodium hydroxide base hydrolysis and calcium carbonate cookoff were selected based on their potential for producing a clean solid residue and minimum release of toxic gases after component detonation. The explosive hazard was destroyed by all three processes. Batch supercritical water oxidation destroyed both the energetics and organics. Further development is desired to optimize process parameters. Sodium hydroxide base hydrolysis and calcium carbonate cookoff results indicated the potential for scrubbing gaseous detonation products. Further study and testing are needed to quantify the effectiveness of these later two processes for full-scale munition destruction. The preliminary experiments completed in this study have demonstrated the promise of these three processes as environmentally sound technologies for energetic component destruction. Continuation of these experimental programs is strongly recommended to optimize batch supercritical water oxidation processing, and to fully develop the sodium hydroxide base hydrolysis and calcium carbonate cookoff technologies.

  13. Micro-fabrication Techniques for Target Components

    SciTech Connect (OSTI)

    Miles, R; Hamilton, J; Crawford, J; Ratti, S; Trevino, J; Graff, T; Stockton, C; Harvey, C

    2008-06-10

    Micro-fabrication techniques, derived from the semi-conductor industry, can be used to make a variety of useful mechanical components for targets. A selection of these components including supporting cooling arms for prototype cryogenic inertial confinement fusion targets, stepped and graded density targets for materials dynamics experiments are described. Micro-fabrication enables cost-effective, simultaneous fabrication of multiple high-precision components with complex geometries. Micro-fabrication techniques such as thin-film deposition, photo-lithographic patterning and etch processes normally used in the semi-conductor manufacture industry, can be exploited to make useful mechanical target components. Micro-fabrication processes have in recent years been used to create a number of micro-electro-mechanical systems (MEMS) components such as pressure sensors, accelerometers, ink jet printer heads, microfluidics platforms and the like. These techniques consist primarily of deposition of thin films of material, photo-lithographic patterning and etching processes performed sequentially to produce three dimensional structures using essentially planar processes. While the planar technology can be limiting in terms of the possible geometries of the final product, advantages of using these techniques include the ability to make multiple complex structures simultaneously and cost-effectively. Target components fabricated using these techniques include the supporting cooling arms for cryogenic prototype fusion ignition targets, stepped targets for equation-of-state experiments, and graded density reservoirs for material strength experiments.

  14. Vaporization modeling of petroleum-biofuel drops using a hybrid multi-component approach

    SciTech Connect (OSTI)

    Zhang, Lei; Kong, Song-Charng

    2010-11-15

    Numerical modeling of the vaporization characteristics of multi-component fuel mixtures is performed in this study. The fuel mixtures studied include those of binary components, biodiesel, diesel-biodiesel, and gasoline-ethanol. The use of biofuels has become increasingly important for reasons of environmental sustainability. Biofuels are often blended with petroleum fuels, and the detailed understanding of the vaporization process is essential to designing a clean and efficient combustion system. In this study, a hybrid vaporization model is developed that uses continuous thermodynamics to describe petroleum fuels and discrete components to represent biofuels. The model is validated using the experimental data of n-heptane, n-heptane-n-decane mixture, and biodiesel. Since biodiesel properties are not universal due to the variation in feedstock, methods for predicting biodiesel properties based on the five dominant fatty acid components are introduced. Good levels of agreement in the predicted and measured drop size histories are obtained. Furthermore, in modeling the diesel-biodiesel drop, results show that the drop lifetime increases with the biodiesel concentration in the blend. During vaporization, only the lighter components of diesel fuel vaporize at the beginning. Biodiesel components do not vaporize until some time during the vaporization process. On the other hand, results of gasoline-ethanol drops indicate that both fuels start to vaporize once the process begins. At the beginning, the lighter components of gasoline have a slightly higher vaporization rate than ethanol. After a certain time, ethanol vaporizes faster than the remaining gasoline components. At the end, the drop reduces to a regular gasoline drop with heavier components. Overall, the drop lifetime increases as the concentration of ethanol increases in the drop due to the higher latent heat. (author)

  15. Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

    SciTech Connect (OSTI)

    Thornton, M. J.; Alleman, T. L.; Luecke, J.; McCormick, R. L.

    2009-08-01

    Assesses oil dilution impacts on a diesel engine operating with a diesel particle filter, NOx storage, a selective catalytic reduction emission control system, and a soy-based 20% biodiesel fuel blend.

  16. Polymer blend containing a modified dense star polymer or dendrimer and a matrix polymer

    DOE Patents [OSTI]

    Hedstrand, D.M.; Tomalia, D.A.

    1995-02-28

    Dense star polymers or dendrimers, modified by capping with a hydrophobic group capable of providing a hydrophobic outer shell, act as molecular nucleating agents in forming a polymer blend.

  17. Polymer blend containing a modified dense star polymer or dendrimer and a matrix polymer

    DOE Patents [OSTI]

    Hedstrand, David M.; Tomalia, Donald A.

    1995-01-01

    Dense star polymers or dendrimers, modified by capping with a hydrophobic group capable of providing a hydrophobic outer shell, act as molecular nucleating agents in forming a polymer blend.

  18. The effect of block copolymer on the phase behavior of a polymer blend

    SciTech Connect (OSTI)

    Sung, L.; Jackson, C.L.; Hess, D.

    1995-12-31

    The effect of an interfacial modifier on the phase behavior of a blend has been investigated using time-resolved fight scattering and small angle neutron scattering techniques. A low molecular weight binary blend of deuterated polystyrene/polybutadiene (PSD/PB) with PSD-PB diblock copolymer as the added interfacial modifier was studied. We observed that the critical temperature of the blend decreases with increasing copolymer content and the kinetics of the phase separation (via spinodal decomposition) slows down in the presence of the copolymer. The transition from early to late stage spinodal decomposition in a near critical mixture of the binary blend was analyzed and compared to available theories. In addition, transmission electron microscopy and optical microscopy studies were used to examine the morphology of the system under various temperature quench conditions.

  19. Evaluation of Ethanol Blends for PHEVs using Simulation andEngine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol Blends for PHEVs using Simulation and Engine-in-the-Loop Evaluation of Ethanol ... Program Annual Merit Review and Peer Evaluation PDF icon vss049shidore2011o.pdf More ...

  20. Solvent Blending Strategy to Upgrade MCU CSSX Solvent to Equivalent Next-Generation CSSX Solvent

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Moyer, Bruce A

    2012-12-01

    The results of the present study have validated an equal-volume blending strategy for upgrading freshly prepared CSSX solvent to a blended solvent functionally equivalent to NG-CSSX solvent. It is shown that blending fresh CSSX solvent as currently used in MCU with an equal volume of an NG-CSSX solvent concentrate of appropriate composition yields a blended solvent composition (46.5 mM of MaxCalix, 3.5 mM of BOBCalixC6, 0.5 M of Cs-7SB, 3 mM of guanidine suppressor, and 1.5 mM of TOA in Isopar L) that exhibits equivalent batch ESS performance to that of the NG-CSSX solvent containing 50 mM of MaxCalix, 0.5 M of Cs-7SB, and 3 mM of guanidine suppressor in Isopar L. The solvent blend composition is robust to third-phase formation. Results also show that a blend containing up to 60% v/v of CSSX solvent could be accommodated with minimal risk. Extraction and density data for the effect of solvent concentration mimicking diluent evaporation or over-dilution of the equal-volume blended solvent are also given, providing input for setting operational limits. Given that the experiments employed all pristine chemicals, the results do not qualify a blended solvent starting with actual used MCU solvent, which can be expected to have undergone some degree of degradation. Consequently, further work should be considered to evaluate this risk and implement appropriate remediation if needed.

  1. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2009-02-01

    This report (February 2009) is an update of the original version, which was published in October 2008. This report is the result of the U.S. Department of Energy's test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels.

  2. U.S. Uranium Down-blending Activities: Fact Sheet | National Nuclear

    National Nuclear Security Administration (NNSA)

    Security Administration | (NNSA) Uranium Down-blending Activities: Fact Sheet March 23, 2012 The permanent disposition of Highly Enriched Uranium (HEU) permanently reduces nuclear security vulnerabilities. In 1996, the Department of Energy (DOE) announced plans to reduce stockpiles of surplus HEU by down-blending, or converting, it to low-enriched uranium (LEU). U.S. HEU Downblending The U.S. Surplus Highly Enriched Uranium (HEU) Disposition Program is making progress in disposing of surplus

  3. Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Issues | Department of Energy Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues The United States has 11 distinct natural gas pipeline corridors: five originate in the Southwest, four deliver natural gas from Canada, and two extend from the Rocky Mountain region. This study assesses the potential to deliver hydrogen through the existing natural gas pipeline network as a hydrogen and

  4. Empirical Study of the Stability of Biodiesel and Biodiesel Blends: Milestone Report

    SciTech Connect (OSTI)

    McCormick, R. L.; Westbrook, S. R.

    2007-05-01

    The objective of this work was to develop a database that supports specific proposals for a stability test and specification for biodiesel and biodiesel blends. B100 samples from 19 biodiesel producers were obtained in December of 2005 and January of 2006 and tested for stability. Eight of these samples were then selected for additional study, including long-term storage tests and blending at 5% and 20% with a number of ultra-low sulfur diesel fuels.

  5. Advanced Vehicle Testing Activity: High-Percentage Hydrogen/CNG Blend, Ford F-150 -- Operating Summary

    SciTech Connect (OSTI)

    Don Karner; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy’s Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service’s Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents the results of 4,695 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 50% hydrogen–50% CNG fuel.

  6. Advanced Vehicle Testing Activity: Low-Percentage Hydrogen/CNG Blend, Ford F-150 -- Operating Summary

    SciTech Connect (OSTI)

    Karner, D.; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy’s Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service’s Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of 16,942 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 30% hydrogen/70% CNG fuel.

  7. A New Generation of Building Insulation by Foaming Polymer Blend Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with CO2 | Department of Energy A New Generation of Building Insulation by Foaming Polymer Blend Materials with CO2 A New Generation of Building Insulation by Foaming Polymer Blend Materials with CO2 ISTN extruded polystyrene (XPS) board produced in factory demonstration ISTN extruded polystyrene (XPS) board produced in factory demonstration Lead Performer: Industrial Science & Technology Network - Lancaster, PA DOE Funding: $400,000 Cost Share: $80,000 Project Term: 1/1/2014 -

  8. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay Keller of Sandia National Laboratories at the CNG and Hydrogen Lessons Learned Workshop on December 10, 2009 cng_h2_workshop_2_keller.pdf (3.5 MB) More Documents & Publications US DRIVE Hydrogen Codes and Standards Technical Team Roadmap Hydrogen Release Behavior Overview of HyRAM (Hydrogen

  9. BLENDING STUDY FOR SRR SALT DISPOSITION INTEGRATION: TANK 50H SCALE-MODELING AND COMPUTER-MODELING FOR BLENDING PUMP DESIGN, PHASE 2

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Fowley, M.

    2011-05-26

    The Salt Disposition Integration (SDI) portfolio of projects provides the infrastructure within existing Liquid Waste facilities to support the startup and long term operation of the Salt Waste Processing Facility (SWPF). Within SDI, the Blend and Feed Project will equip existing waste tanks in the Tank Farms to serve as Blend Tanks where 300,000-800,000 gallons of salt solution will be blended in 1.3 million gallon tanks and qualified for use as feedstock for SWPF. Blending requires the miscible salt solutions from potentially multiple source tanks per batch to be well mixed without disturbing settled sludge solids that may be present in a Blend Tank. Disturbing solids may be problematic both from a feed quality perspective as well as from a process safety perspective where hydrogen release from the sludge is a potential flammability concern. To develop the necessary technical basis for the design and operation of blending equipment, Savannah River National Laboratory (SRNL) completed scaled blending and transfer pump tests and computational fluid dynamics (CFD) modeling. A 94 inch diameter pilot-scale blending tank, including tank internals such as the blending pump, transfer pump, removable cooling coils, and center column, were used in this research. The test tank represents a 1/10.85 scaled version of an 85 foot diameter, Type IIIA, nuclear waste tank that may be typical of Blend Tanks used in SDI. Specifically, Tank 50 was selected as the tank to be modeled per the SRR, Project Engineering Manager. SRNL blending tests investigated various fixed position, non-rotating, dual nozzle pump designs, including a blending pump model provided by the blend pump vendor, Curtiss Wright (CW). Primary research goals were to assess blending times and to evaluate incipient sludge disturbance for waste tanks. Incipient sludge disturbance was defined by SRR and SRNL as minor blending of settled sludge from the tank bottom into suspension due to blending pump operation, where

  10. Resistance of fly ash-Portland cement blends to thermal shock

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pyatina, Tatiana; Sugama, Toshifumi

    2015-09-11

    Thermal-shock resistance of high-content fly ash-Portland cement blends was tested in the following ways. Activated and non-activated blends with 80-90 % fly ash F (FAF) were left to set at room temperature, then hydrated for 24 hours at 85°C and 24-more hours at 300°C and tested in five thermal-shock cycles (600°C heat - 25°C water quenching). XRD, and thermal gravimetric analyses, along with calorimetric measurements and SEM-EDX tests demonstrated that the activated blends form more hydrates after 24 hours at 300°C, and achieve a higher short-term compressive strength than do non-activated ones. Sodium meta-silicate and sodaash engendered the concomitant hydrationmore » of OPC and FAF, with the formation of mixed crystalline FAF-OPC hydrates and FAF hydrates, such as garranite, analcime, and wairakite, along with the amorphous FAF hydration products. In SS-activated and non-activated blends separate OPC (tobermorite) and FAF (amorphous gel) hydrates with no mixed crystalline products formed. The compressive strength of all tested blends decreased by nearly 50% after 5 thermal-shock test cycles. These changes in the compressive strength were accompanied by a marked decrease in the intensities of XRD patterns of the crystalline hydrates after the thermalshock. As a result, there was no significant difference in the performance of the blends with different activators« less

  11. Resistance of fly ash-Portland cement blends to thermal shock

    SciTech Connect (OSTI)

    Pyatina, Tatiana; Sugama, Toshifumi

    2015-09-11

    Thermal-shock resistance of high-content fly ash-Portland cement blends was tested in the following ways. Activated and non-activated blends with 80-90 % fly ash F (FAF) were left to set at room temperature, then hydrated for 24 hours at 85°C and 24-more hours at 300°C and tested in five thermal-shock cycles (600°C heat - 25°C water quenching). XRD, and thermal gravimetric analyses, along with calorimetric measurements and SEM-EDX tests demonstrated that the activated blends form more hydrates after 24 hours at 300°C, and achieve a higher short-term compressive strength than do non-activated ones. Sodium meta-silicate and sodaash engendered the concomitant hydration of OPC and FAF, with the formation of mixed crystalline FAF-OPC hydrates and FAF hydrates, such as garranite, analcime, and wairakite, along with the amorphous FAF hydration products. In SS-activated and non-activated blends separate OPC (tobermorite) and FAF (amorphous gel) hydrates with no mixed crystalline products formed. The compressive strength of all tested blends decreased by nearly 50% after 5 thermal-shock test cycles. These changes in the compressive strength were accompanied by a marked decrease in the intensities of XRD patterns of the crystalline hydrates after the thermalshock. As a result, there was no significant difference in the performance of the blends with different activators

  12. Phase Behavior of Neat Triblock Copolymers and Copolymer/Homopolymer Blends Near Network Phase Windows

    SciTech Connect (OSTI)

    M Tureau; L Rong; B Hsiao; T Epps

    2011-12-31

    The phase behavior of poly(isoprene-b-styrene-b-methyl methacrylate) (ISM) copolymers near the styrene-rich network phase window was examined through the use of neat triblock copolymers and copolymer/homopolymer blends. Both end-block and middle-block blending protocols were employed using poly(isoprene) (PI), poly(methyl methacrylate) (PMMA), and poly(styrene) (PS) homopolymers. Blended specimens exhibited phase transformations to well-ordered nanostructures (at homopolymer loadings up to 26 vol % of the total blend volume). Morphological consistency between neat and blended specimens was established at various locations in the ISM phase space. Copolymer/homopolymer blending permitted the refinement of lamellar, hexagonally packed cylinder, and disordered melt phase boundaries as well as the identification of double gyroid (Q{sup 230}), alternating gyroid (Q{sup 214}), and orthorhombic (O{sup 70}) network regimes. Additionally, the experimental phase diagram exhibited similar trends to those found in a theoretical ABC triblock copolymer phase diagram with symmetric interactions and statistical segments lengths generated by Tyler et al.

  13. Sprayed skin turbine component

    DOE Patents [OSTI]

    Allen, David B

    2013-06-04

    Fabricating a turbine component (50) by casting a core structure (30), forming an array of pits (24) in an outer surface (32) of the core structure, depositing a transient liquid phase (TLP) material (40) on the outer surface of the core structure, the TLP containing a melting-point depressant, depositing a skin (42) on the outer surface of the core structure over the TLP material, and heating the assembly, thus forming both a diffusion bond and a mechanical interlock between the skin and the core structure. The heating diffuses the melting-point depressant away from the interface. Subsurface cooling channels (35) may be formed by forming grooves (34) in the outer surface of the core structure, filling the grooves with a fugitive filler (36), depositing and bonding the skin (42), then removing the fugitive material.

  14. Component failure data handbook

    SciTech Connect (OSTI)

    Gentillon, C.D.

    1991-04-01

    This report presents generic component failure rates that are used in reliability and risk studies of commercial nuclear power plants. The rates are computed using plant-specific data from published probabilistic risk assessments supplemented by selected other sources. Each data source is described. For rates with four or more separate estimates among the sources, plots show the data that are combined. The method for combining data from different sources is presented. The resulting aggregated rates are listed with upper bounds that reflect the variability observed in each rate across the nuclear power plant industry. Thus, the rates are generic. Both per hour and per demand rates are included. They may be used for screening in risk assessments or for forming distributions to be updated with plant-specific data.

  15. Hydration studies of calcium sulfoaluminate cements blended with fly ash

    SciTech Connect (OSTI)

    Garca-Mat, M.; De la Torre, A.G.; Len-Reina, L.; Aranda, M.A.G.; CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona ; Santacruz, I.

    2013-12-15

    The main objective of this work is to study the hydration and properties of calcium sulfoaluminate cement pastes blended with fly ash (FA) and the corresponding mortars at different hydration ages. Laboratory X-ray powder diffraction, rheological studies, thermal analysis, porosimetry and compressive strength measurements were performed. The analysis of the diffraction data by Rietveld method allowed quantifying crystalline phases and overall amorphous contents. The studied parameters were: i) FA content, 0, 15 and 30 wt.%; and ii) water addition, water-to-CSA mass ratio (w/CSA = 0.50 and 0.65), and water-to-binder mass ratio (w/b = 0.50). Finally, compressive strengths after 6 months of 0 and 15 wt.% FA [w/CSA = 0.50] mortars were similar: 73 2 and 72 3 MPa, respectively. This is justified by the filler effect of the FA as no strong evidences of reactivity of FA with CSA were observed. These results support the partial substitution of CSA cements with FA with the economic and environmental benefits.

  16. High Performance Laminates Using Blended Urethane Resin Chemistry

    SciTech Connect (OSTI)

    Simmons, Kevin L.; Jones, George G.; Walsh, Sean P.; Wood, Geoff M.

    2005-03-24

    Hybrid blended resin systems have the potential to provide excellent impact performance in structured laminates. Although mostly under development for sheet molding compound (SMC) applications using glass fiber with high levels of fillers, the resins have been found to be useful in liquid molding applications with other high-performance fiber systems. A research pro-gram to develop the molding capability, property data, and capability to model the composites using newly de-veloped codes and modeling techniques was initiated through the Department of Energys Office of Freedom-Car and Vehicle Technologies. Results have shown ex-cellent adhesion to different fiber systems as evidenced by mechanical properties, and a capability to develop very good impact results thereby allowing thin panel structures to be developed. Comparison to predicted me-chanical properties has been achieved and mechanisms for the development of observed high energy absorption under impact loadings are being investigated. Scale ef-fects based on panel thickness, fiber type loading, and position in laminate are being investigated. DOE pro-gram sponsorship was provided by Dr. Sidney Diamond, Technical Area Development Manager for High-Strength Weight-Reduction Materials.

  17. A Study of the Use of Jatropha Oil Blends in Boilers

    SciTech Connect (OSTI)

    Krishna, C.R.

    2010-10-01

    Executive Summary: This project investigated the combustion performance of blends of unrefined Jatropha oil and its blends in laboratory boilers. Although a very limited amount of testing blends in distillate oil, ASTM No. 2 oil or heating oil was conducted, the primary interest was in testing the performance of blends with residual ASTM No. 6 oil. The basic idea is to provide a renewable fuel option to residual oil used in space heating and in industrial applications. The intent also was to explore the use of non-edible plant oil and one that might be potentially cheaper than biodiesel. The characteristics of No. 6 oil, such as high viscosity at ambient temperature, which requires it to be kept heated, make the blending with such oils feasible. Jatropha oil is one such oil and there is currently considerable interest building up in its use as a source for making biodiesel and jet fuel. A 10% blend of Jatropha oil with heating oil was burned using a standard burner in a residential boiler. Combustion performance was shown to be comparable with that of burning heating oil by itself with some noticeable differences. Typical heating oil has about 2000 ppm of sulfur, while the Jatropha oil has about 50 ppm leading to lower levels of sulphur dioxide emissions. Stack measurements also showed that the NOx emission was lower with the blend. We have previously reported similar reductions in NOx with blends of biodiesel in heating oil as well as slight reductions in PM2.5, particulates below 2.5 microns in size. Long term tests were not part of this project and hence deleterious effects on pumps, seals etc., if any, were not measured. The majority of the work involved testing blends of Jatropha oil with residual oil in a 1.5 million Btu/hr boiler with a burner modified to burn residual oil. Blends of 20 and 60% Jatropha oil and 100% Jatropha oil were burned in the combustion performance tests. The residual oil used had a sulfur content of over 2000 ppm and hence dramatic

  18. COMPARISON OF EXPERIMENTAL RESULTS TO CFD MODELS FOR BLENDING IN A TANK USING DUAL OPPOSING JETS

    SciTech Connect (OSTI)

    Leishear, R.

    2011-08-07

    Research has been completed in a pilot scale, eight foot diameter tank to investigate blending, using a pump with dual opposing jets. The jets re-circulate fluids in the tank to promote blending when fluids are added to the tank. Different jet diameters and different horizontal and vertical orientations of the jets were investigated. In all, eighty five tests were performed both in a tank without internal obstructions and a tank with vertical obstructions similar to a tube bank in a heat exchanger. These obstructions provided scale models of several miles of two inch diameter, serpentine, vertical cooling coils below the liquid surface for a full scale, 1.3 million gallon, liquid radioactive waste storage tank. Two types of tests were performed. One type of test used a tracer fluid, which was homogeneously blended into solution. Data were statistically evaluated to determine blending times for solutions of different density and viscosity, and the blending times were successfully compared to computational fluid dynamics (CFD) models. The other type of test blended solutions of different viscosity. For example, in one test a half tank of water was added to a half tank of a more viscous, concentrated salt solution. In this case, the fluid mechanics of the blending process was noted to significantly change due to stratification of fluids. CFD models for stratification were not investigated. This paper is the fourth in a series of papers resulting from this research (Leishear, et.al. [1- 4]), and this paper documents final test results, statistical analysis of the data, a comparison of experimental results to CFD models, and scale-up of the results to a full scale tank.

  19. Cooling system for electronic components

    DOE Patents [OSTI]

    Anderl, William James; Colgan, Evan George; Gerken, James Dorance; Marroquin, Christopher Michael; Tian, Shurong

    2015-12-15

    Embodiments of the present invention provide for non interruptive fluid cooling of an electronic enclosure. One or more electronic component packages may be removable from a circuit card having a fluid flow system. When installed, the electronic component packages are coincident to and in a thermal relationship with the fluid flow system. If a particular electronic component package becomes non-functional, it may be removed from the electronic enclosure without affecting either the fluid flow system or other neighboring electronic component packages.

  20. SAVANNAH RIVER SITE INCIPIENT SLUDGE MIXING IN RADIOACTIVE LIQUID WASTE STORAGE TANKS DURING SALT SOLUTION BLENDING

    SciTech Connect (OSTI)

    Leishear, R.; Poirier, M.; Lee, S.; Steeper, T.; Fowley, M.; Parkinson, K.

    2011-01-12

    This paper is the second in a series of four publications to document ongoing pilot scale testing and computational fluid dynamics (CFD) modeling of mixing processes in 85 foot diameter, 1.3 million gallon, radioactive liquid waste, storage tanks at Savannah River Site (SRS). Homogeneous blending of salt solutions is required in waste tanks. Settled solids (i.e., sludge) are required to remain undisturbed on the bottom of waste tanks during blending. Suspension of sludge during blending may potentially release radiolytically generated hydrogen trapped in the sludge, which is a safety concern. The first paper (Leishear, et. al. [1]) presented pilot scale blending experiments of miscible fluids to provide initial design requirements for a full scale blending pump. Scaling techniques for an 8 foot diameter pilot scale tank were also justified in that work. This second paper describes the overall reasons to perform tests, and documents pilot scale experiments performed to investigate disturbance of sludge, using non-radioactive sludge simulants. A third paper will document pilot scale CFD modeling for comparison to experimental pilot scale test results for both blending tests and sludge disturbance tests. That paper will also describe full scale CFD results. The final paper will document additional blending test results for stratified layers in salt solutions, scale up techniques, final full scale pump design recommendations, and operational recommendations. Specifically, this paper documents a series of pilot scale tests, where sludge simulant disturbance due to a blending pump or transfer pump are investigated. A principle design requirement for a blending pump is UoD, where Uo is the pump discharge nozzle velocity, and D is the nozzle diameter. Pilot scale test results showed that sludge was undisturbed below UoD = 0.47 ft{sup 2}/s, and that below UoD = 0.58 ft{sup 2}/s minimal sludge disturbance was observed. If sludge is minimally disturbed, hydrogen will not be

  1. NO reduction in decoupling combustion of biomass and biomass-coal blend

    SciTech Connect (OSTI)

    Li Dong; Shiqiu Gao; Wenli Song; Jinghai Li; Guangwen Xu

    2009-01-15

    Biomass is a form of energy that is CO{sub 2}-neutral. However, NOx emissions in biomass combustion are often more than that of coal on equal heating-value basis. In this study, a technology called decoupling combustion was investigated to demonstrate how it reduces NO emissions in biomass and biomass-coal blend combustion. The decoupling combustion refers to a two-step combustion method, in which fuel pyrolysis and the burning of char and pyrolysis gas are separated and the gas burns out during its passage through the burning-char bed. Tests in a quartz dual-bed reactor demonstrated that, in decoupling combustion, NO emissions from biomass and biomass-coal blends were both less than those in traditional combustion and that NO emission from combustion of blends of biomass and coal decreased with increasing biomass percentage in the blend. Co-firing rice husk and coal in a 10 kW stove manufactured according to the decoupling combustion technology further confirmed that the decoupling combustion technology allows for truly low NO emission as well as high efficiency for burning biomass and biomass-coal blends, even in small-scale stoves and boilers. 22 refs., 6 figs., 1 tab.

  2. Legacy Vehicle Fuel System Testing with Intermediate Ethanol Blends

    SciTech Connect (OSTI)

    Davis, G. W.; Hoff, C. J.; Borton, Z.; Ratcliff, M. A.

    2012-03-01

    The effects of E10 and E17 on legacy fuel system components from three common mid-1990s vintage vehicle models (Ford, GM, and Toyota) were studied. The fuel systems comprised a fuel sending unit with pump, a fuel rail and integrated pressure regulator, and the fuel injectors. The fuel system components were characterized and then installed and tested in sample aging test rigs to simulate the exposure and operation of the fuel system components in an operating vehicle. The fuel injectors were cycled with varying pulse widths during pump operation. Operational performance, such as fuel flow and pressure, was monitored during the aging tests. Both of the Toyota fuel pumps demonstrated some degradation in performance during testing. Six injectors were tested in each aging rig. The Ford and GM injectors showed little change over the aging tests. Overall, based on the results of both the fuel pump testing and the fuel injector testing, no major failures were observed that could be attributed to E17 exposure. The unknown fuel component histories add a large uncertainty to the aging tests. Acquiring fuel system components from operational legacy vehicles would reduce the uncertainty.

  3. Organic Aerosol Component (OACOMP) Value-Added Product Report

    SciTech Connect (OSTI)

    Fast, J; Zhang, Q; Tilp, A; Shippert, T; Parworth, C; Mei, F

    2013-08-23

    Significantly improved returns in their aerosol chemistry data can be achieved via the development of a value-added product (VAP) of deriving OA components, called Organic Aerosol Components (OACOMP). OACOMP is primarily based on multivariate analysis of the measured organic mass spectral matrix. The key outputs of OACOMP are the concentration time series and the mass spectra of OA factors that are associated with distinct sources, formation and evolution processes, and physicochemical properties.

  4. Knock-limited performance of ethanol blends in a spark-ignition engine

    SciTech Connect (OSTI)

    Ferfecki, F.J.; Sorenson, S.C.

    1981-01-01

    An experimental study was performed to determine the effect of varying percentages of ethanol in fuel using a CFR engine operated at knock-limited compression ratio and maximum power spark timing. Blends of 85 octane primary reference fuel and ethanol in concentrations between 10 and 25% by volume were tested for performance, fuel economy, and exhaust emissions. The results indicated that when the engine was operated at knock-limited conditions at a constant equivalence ratio, the use of ethanol resulted in a reduction in petroleum fuel usage of 10% greater than the volumetric percentage of the ethanol used in the blend. These results were independent of the amount of ethanol used in the blend. Under these conditions, as the ethanol concentration was increased, BMEP and BSHC increased, BSNO and BSCO remained essentially constant, and exhaust temperature decreased.

  5. Drive cycle analysis of butanol/diesel blends in a light-duty vehicle.

    SciTech Connect (OSTI)

    Miers, S. A.; Carlson, R. W.; McConnell, S. S.; Ng, H. K.; Wallner, T.; LeFeber, J.; Energy Systems; Esper Images Video & Multimedia

    2008-10-01

    The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests.

  6. Sample Results From The Extraction, Scrub, And Strip Test For The Blended NGS Solvent

    SciTech Connect (OSTI)

    Washington, A. L. II; Peters, T. B.

    2014-03-03

    This report summarizes the results of the extraction, scrub, and strip testing for the September 2013 sampling of the Next Generation Solvent (NGS) Blended solvent from the Modular Caustic Side-Solvent Extraction Unit (MCU) Solvent Hold Tank. MCU is in the process of transitioning from the BOBCalixC6 solvent to the NGS Blend solvent. As part of that transition, MCU has intentionally created a blended solvent to be processed using the Salt Batch program. This sample represents the first sample received from that blended solvent. There were two ESS tests performed where NGS blended solvent performance was assessed using either the Tank 21 material utilized in the Salt Batch 7 analyses or a simulant waste material used in the V-5/V-10 contactor testing. This report tabulates the temperature corrected cesium distribution, or DCs values, step recovery percentage, and actual temperatures recorded during the experiment. This report also identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. The calculated extraction DCs values using the Tank 21H material and simulant are 59.4 and 53.8, respectively. The DCs values for two scrub and three strip processes for the Tank 21 material are 4.58, 2.91, 0.00184, 0.0252, and 0.00575, respectively. The D-values for two scrub and three strip processes for the simulant are 3.47, 2.18, 0.00468, 0.00057, and 0.00572, respectively. These values are similar to previous measurements of Salt Batch 7 feed with lab-prepared blended solvent. These numbers are considered compatible to allow simulant testing to be completed in place of actual waste due to the limited availability of feed material.

  7. Synthesis of Methyl Methacrylate from Coal-Derived Syngas

    SciTech Connect (OSTI)

    Gerald N. Choi; James J. Spivey; Jospeh R. Zoeller; Makarand R. Gogate; Richard D. Colberg; Samuel S. Tam

    1998-04-17

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. RTI has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, RTI is currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last month, RTI has finalized the design of a fixed-bed microreactor system for DME partial oxidation reactions. RTI incorporated some design changes to the feed blending system, so as to be able to blend varying proportions of DME and oxygen. RTI has also examined the flammability limits of DME-air mixtures. Since the lower flammability limit of DME in air is 3.6 volume percent, RTI will use a nominal feed composition of 1.6 percent in air, which is less than half the lower explosion limit for DME-air mixtures. This nominal feed composition is thus considered operationally safe, for DME partial oxidation reactions. RTI is also currently developing an analytical system for DME partial oxidation reaction system.

  8. Well-to-Wheels Greenhouse Gas Emissions Analysis of High-Octane Fuels with Various Market Shares and Ethanol Blending Levels

    SciTech Connect (OSTI)

    Han, Jeongwoo; Elgowainy, Amgad; Wang, Michael; Divita, Vincent

    2015-07-14

    In this study, we evaluated the impacts of producing HOF with a RON of 100, using a range of ethanol blending levels (E10, E25, and E40), vehicle efficiency gains, and HOF market penetration scenarios (3.4% to 70%), on WTW petroleum use and GHG emissions. In particular, we conducted LP modeling of petroleum refineries to examine the impacts of different HOF production scenarios on petroleum refining energy use and GHG emissions. We compared two cases of HOF vehicle fuel economy gains of 5% and 10% in terms of MPGGE to baseline regular gasoline vehicles. We incorporated three key factors in GREET — (1) refining energy intensities of gasoline components for the various ethanol blending options and market shares, (2) vehicle efficiency gains, and (3) upstream energy use and emissions associated with the production of different crude types and ethanol — to compare the WTW GHG emissions of various HOF/vehicle scenarios with the business-as-usual baseline regular gasoline (87 AKI E10) pathway.

  9. Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    near Paducah Site | Department of Energy Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren near Paducah Site Citizens Advisory Board's Eco Fair Blends Fun and Facts for Schoolchildren near Paducah Site June 1, 2012 - 12:00pm Addthis Lone Oak Middle School sixth-graders pet a mallard hen at the third annual Eco Fair May 15 in West Kentucky Wildlife Management Area. Lone Oak Middle School sixth-graders pet a mallard hen at the third annual Eco Fair May 15 in West

  10. The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization deer12_szybist.pdf (3.46 MB) More Documents & Publications High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Gasoline-Like Fuel Effects on Advanced

  11. Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Authors: Deng, Z., Schulz, O., Lin, S., Ding, B., Liu, X., Wei, X., Ros, R., Liu, Y., Yan, H., and Francis, M. Title: Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Source: Journal of the American

  12. Carbonization of blends of L'vovsk-Volynsk and Karaganda coals

    SciTech Connect (OSTI)

    Panchenko, N.I.; Maksimenko, I.I.; Glushchenko, I.M.; Mel'nichhuk, A.Yu.; Pustovoit, M.I.; Plvnyak, V.I.

    1981-07-01

    It has been shown that the coking of blends of Donbass, Karaganda and L'vov-Volynya coals can produce metallurgical coke of satisfactory quality. In view of the shortage of Donbass coking coals, and the availability of coals from the other two regions, it is obviously advantageous to increase the application of these latter coals in Ukraine coking plants by incorporating them in blends for the production of metallurgical coke. An account is given of tests at a Ukraine coking plant showing the effects of the Karaganda coal, which has a high fusinite and semi-vitrinite content, and the Volynya coal which has a high liptinite content. (6 refs.)

  13. 100,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 00,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20) 100,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20) Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_barnitt.pdf (575.91 KB) More Documents & Publications Recent Research to Address Technical Barriers to Increased Use of Biodiesel Impact

  14. Multi-tipped optical component

    DOE Patents [OSTI]

    D'Urso, Brian R.; Simpson, John T.

    2010-04-13

    An optical component has a plurality of parallel noncontiguous optical conduits of at least one protrusive phase material embedded in a recessive phase material that acts as a support structure. The optical conduits extend from a proximal surface to a distal surface of the optical component. The distal surface has a plurality of spaced apart surface features of the protrusive phase material. Each independent optical conduits act as waveguides for a wavelength or range of wavelengths. The optical component can be formed such that the protruding surface features at the distal end of the component form an ordered array. An optical instrument can include the optical component in conjunction with a light source for illuminating a sample and a detector in optical communication optical component via the optical conduits.

  15. Multi-component assembly casting

    DOE Patents [OSTI]

    James, Allister W.

    2015-10-13

    Multi-component vane segment and method for forming the same. Assembly includes: positioning a pre-formed airfoil component (12) and a preformed shroud heat resistant material (18) in a mold, wherein the airfoil component (12) and the shroud heat resistant material (18) each comprises an interlocking feature (24); preheating the mold; introducing molten structural material (46) into the mold; and solidifying the molten structural material such that it interlocks the pre-formed airfoil component (12) with respect to the preformed shroud heat resistant material (18) and is effective to provide structural support for the shroud heat resistant material (18). Surfaces between the airfoil component (12) and the structural material (46), between the airfoil component (12) and the shroud heat resistant material (18), and between the shroud heat resistant material (18) and the structural material (46) are free of metallurgical bonds.

  16. Heat treating of manufactured components

    SciTech Connect (OSTI)

    Ripley, Edward B.

    2012-05-22

    An apparatus for heat treating manufactured components using microwave energy and microwave susceptor material is disclosed. The system typically includes an insulating vessel placed within a microwave applicator chamber. A moderating material is positioned inside the insulating vessel so that a substantial portion of the exterior surface of each component for heat treating is in contact with the moderating material.

  17. Derived Annual Estimates

    U.S. Energy Information Administration (EIA) Indexed Site

    74-1988 For Methodology Concerning the Derived Estimates Total Consumption of Offsite-Produced Energy for Heat and Power by Industry Group, 1974-1988 Total Energy *** Electricity...

  18. Total-derivative supersymmetry breaking

    SciTech Connect (OSTI)

    Haba, Naoyuki; Uekusa, Nobuhiro

    2010-05-15

    On an interval compactification in supersymmetric theory, boundary conditions for bulk fields must be treated carefully. If they are taken arbitrarily following the requirement that a theory is supersymmetric, the conditions could give redundant constraints on the theory. We construct a supersymmetric action integral on an interval by introducing brane interactions with which total-derivative terms under the supersymmetry transformation become zero due to a cancellation. The variational principle leads equations of motion and also boundary conditions for bulk fields, which determine boundary values of bulk fields. By estimating mass spectrum, spontaneous supersymmetry breaking in this simple setup can be realized in a new framework. This supersymmetry breaking does not induce a massless R axion, which is favorable for phenomenology. It is worth noting that fermions in hyper-multiplet, gauge bosons, and the fifth-dimensional component of gauge bosons can have zero-modes (while the other components are all massive as Kaluza-Klein modes), which fits the gauge-Higgs unification scenarios.

  19. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity

    DOE Patents [OSTI]

    Skotheim, T.

    1984-09-28

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  20. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity

    DOE Patents [OSTI]

    Skotheim, Terje

    1986-01-01

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  1. Blending Hydrogen into Natural Gas Pipeline Networks. A Review of Key Issues

    SciTech Connect (OSTI)

    Melaina, M. W.; Antonia, O.; Penev, M.

    2013-03-01

    This study assesses the potential to deliver hydrogen through the existing natural gas pipeline network as a hydrogen and natural gas mixture to defray the cost of building dedicated hydrogen pipelines. Blending hydrogen into the existing natural gas pipeline network has also been proposed as a means of increasing the output of renewable energy systems such as large wind farms.

  2. Influence of electron beam irradiation on mechanical and thermal properties of polypropylene/polyamide blend

    SciTech Connect (OSTI)

    Nakamura, Shigeya; Tokumitsu, Katsuhisa

    2014-05-15

    The effects of electron beam irradiation on the mechanical and thermal properties of polypropylene (PP) and polyamide6 (PA6) blends-with talc 20 wt% as filler, SEBS-g-MAH as compatibilizer, and triallyl isocyanurate as crosslinking agent-were investigated. Although the tensile and flexural moduli and strengths of the PP/PA6 blends with talc, SEBS-g-MAH, and TAIC could be increased by the application of electron beam irradiation, the impact strength was decreased. Ddifferential scanning calorimetryer measurements showed that the melting temperatures of all PP/PA6 blends were decreased with increases in the electron beam irradiationdose. From dynamic mechanical analyzer results, a storage modulus curve in the plateau region was observed only in the PP/PA6 blends with talc, SEBS-g-MAH, and TAIC; the storage modulus increased with increasing electron beam irradiation dose, indicating that the three-dimensional network developed gradually in the more amorphous PA6. As a result, the most significant improvement observed in heat distortion tests under high load (1.8 MPa) occurred at 200 kGy.

  3. BETO Seeks Stakeholder Input on the Use of Advanced Biofuel Blends in Small Engines

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy’s Bioenergy Technologies Office has released a Request for Information (RFI) seeking stakeholder input on the following topics related to the use of advanced biofuel blends in small engines

  4. HIGHLY ENRICHED URANIUM BLEND DOWN PROGRAM AT THE SAVANNAH RIVER SITE PRESENT AND FUTURE

    SciTech Connect (OSTI)

    Magoulas, V; Charles Goergen, C; Ronald Oprea, R

    2008-06-05

    The Department of Energy (DOE) and Tennessee Valley Authority (TVA) entered into an Interagency Agreement to transfer approximately 40 metric tons of highly enriched uranium (HEU) to TVA for conversion to fuel for the Browns Ferry Nuclear Power Plant. Savannah River Site (SRS) inventories included a significant amount of this material, which resulted from processing spent fuel and surplus materials. The HEU is blended with natural uranium (NU) to low enriched uranium (LEU) with a 4.95% 235U isotopic content and shipped as solution to the TVA vendor. The HEU Blend Down Project provided the upgrades needed to achieve the product throughput and purity required and provided loading facilities. The first blending to low enriched uranium (LEU) took place in March 2003 with the initial shipment to the TVA vendor in July 2003. The SRS Shipments have continued on a regular schedule without any major issues for the past 5 years and are due to complete in September 2008. The HEU Blend program is now looking to continue its success by dispositioning an additional approximately 21 MTU of HEU material as part of the SRS Enriched Uranium Disposition Project.

  5. DGEBF epoxy blends for use in the resin impregnation of extremely large composite parts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Madhukar, M. S.; Martovetsky, N. N.

    2015-01-16

    Large superconducting electromagnets used in fusion reactors utilize a large amount of glass/epoxy composite for electrical insulation and mechanical and thermal strengths. Moreover, the manufacture of these magnets involves wrapping each superconducting cable bundle with dry glass cloth followed by the vacuum-assisted resin transfer molding of the entire magnet. Due to their enormous size (more than 100 tons), it requires more than 40 h for resin impregnation and the subsequent pressure cycles to ensure complete impregnation and removal of any trapped air pockets. Diglycidyl ether of bisphenol F epoxy resin cross-linked with methyltetrahydrophthalic anhydride with an accelerator has been shownmore » to be a good candidate for use in composite parts requiring long impregnation cycles. Viscosity, gel time, and glass transition temperature of four resin-blends of diglycidyl ether of bisphenol F resin system were monitored as a function of time and temperature with an objective to find the blend that provides a working window longer than 40h at low viscosity without lowering its glass transition temperature. A resin-blend in the weight ratios of resin:hardener:accelerator=100:82:0.125 is shown to provide more than 60h at low resin viscosity while maintaining the same glass transition temperature as obtained with previously used resin-blends, based on the results.« less

  6. DGEBF epoxy blends for use in the resin impregnation of extremely large composite parts

    SciTech Connect (OSTI)

    Madhukar, M. S.; Martovetsky, N. N.

    2015-01-16

    Large superconducting electromagnets used in fusion reactors utilize a large amount of glass/epoxy composite for electrical insulation and mechanical and thermal strengths. Moreover, the manufacture of these magnets involves wrapping each superconducting cable bundle with dry glass cloth followed by the vacuum-assisted resin transfer molding of the entire magnet. Due to their enormous size (more than 100 tons), it requires more than 40 h for resin impregnation and the subsequent pressure cycles to ensure complete impregnation and removal of any trapped air pockets. Diglycidyl ether of bisphenol F epoxy resin cross-linked with methyltetrahydrophthalic anhydride with an accelerator has been shown to be a good candidate for use in composite parts requiring long impregnation cycles. Viscosity, gel time, and glass transition temperature of four resin-blends of diglycidyl ether of bisphenol F resin system were monitored as a function of time and temperature with an objective to find the blend that provides a working window longer than 40h at low viscosity without lowering its glass transition temperature. A resin-blend in the weight ratios of resin:hardener:accelerator=100:82:0.125 is shown to provide more than 60h at low resin viscosity while maintaining the same glass transition temperature as obtained with previously used resin-blends, based on the results.

  7. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P; West, Brian H

    2013-01-01

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon

  8. Apparatus for remotely handling components

    DOE Patents [OSTI]

    Szkrybalo, Gregory A.; Griffin, Donald L.

    1994-01-01

    The inventive apparatus for remotely handling bar-like components which define a longitudinal direction includes a gripper mechanism for gripping the component including first and second gripper members longitudinally fixedly spaced from each other and oriented parallel to each other in planes transverse to the longitudinal direction. Each gripper member includes a jaw having at least one V-groove with opposing surfaces intersecting at a base and extending radially relative to the longitudinal direction for receiving the component in an open end between the opposing surfaces. The V-grooves on the jaw plate of the first and second gripper members are aligned in the longitudinal direction to support the component in the first and second gripper members. A jaw is rotatably mounted on and a part of each of the first and second gripper members for selectively assuming a retracted mode in which the open end of the V-groove is unobstructed and active mode in which the jaw spans the open end of the V-groove in the first and second gripper members. The jaw has a locking surface for contacting the component in the active mode to secure the component between the locking surface of the jaw and the opposing surfaces of the V-groove. The locking surface has a plurality of stepped portions, each defining a progressively decreasing radial distance between the base of the V-groove and the stepped portion opposing the base to accommodate varying sizes of components.

  9. Ceramic component for MHD electrode

    DOE Patents [OSTI]

    Marchant, David D.; Bates, Junior L.

    1981-01-01

    A ceramic component which exhibits electrical conductivity down to near room temperatures has the formula: Hf.sub.x In.sub.y A.sub.z O.sub.2 where x=0.1 to 0.4, y=0.3 to 0.6, z=0.1 to 0.4 and A is a lanthanide rare earth or yttrium. The component is suitable for use in the fabrication of MHD electrodes or as the current leadout portion of a composite electrode with other ceramic components.

  10. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights

    2009-05-15

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  11. Advanced Component Research Facility (ACRES)

    SciTech Connect (OSTI)

    Bohn, M.

    1980-07-01

    A detailed description of the SERI Advanced Component Research Facility (ACRES) is given. Background information explicates the facility's history, developed around the two Omnium-G parabolic dish concentrators. The Omnium-G concentrators and electrical power plant are described. The purpose and a detailed descripttion of ACRES is also given. Included is a description of the measurement capabilities, the controls, and each component of the facility.

  12. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  13. Compatibility Study for Plastic, Elastomeric, and Metallic Fueling Infrastructure Materials Exposed to Aggressive Formulations of Ethanol-blended Gasoline

    SciTech Connect (OSTI)

    Kass, Michael D; Pawel, Steven J; Theiss, Timothy J; Janke, Christopher James

    2012-07-01

    In 2008 Oak Ridge National Laboratory began a series of experiments to evaluate the compatibility of fueling infrastructure materials with intermediate levels of ethanol-blended gasoline. Initially, the focus was elastomers, metals, and sealants, and the test fuels were Fuel C, CE10a, CE17a and CE25a. The results of these studies were published in 2010. Follow-on studies were performed with an emphasis on plastic (thermoplastic and thermoset) materials used in underground storage and dispenser systems. These materials were exposed to test fuels of Fuel C and CE25a. Upon completion of this effort, it was felt that additional compatibility data with higher ethanol blends was needed and another round of experimentation was performed on elastomers, metals, and plastics with CE50a and CE85a test fuels. Compatibility of polymers typically relates to the solubility of the solid polymer with a solvent. It can also mean susceptibility to chemical attack, but the polymers and test fuels evaluated in this study are not considered to be chemically reactive with each other. Solubility in polymers is typically assessed by measuring the volume swell of the polymer exposed to the solvent of interest. Elastomers are a class of polymers that are predominantly used as seals, and most o-ring and seal manufacturers provide compatibility tables of their products with various solvents including ethanol, toluene, and isooctane, which are components of aggressive oxygenated gasoline as described by the Society of Automotive Engineers (SAE) J1681. These tables include a ranking based on the level of volume swell in the elastomer associated with exposure to a particular solvent. Swell is usually accompanied by a decrease in hardness (softening) that also affects performance. For seal applications, shrinkage of the elastomer upon drying is also a critical parameter since a contraction of volume can conceivably enable leakage to occur. Shrinkage is also indicative of the removal of one or more

  14. Harnessing Structure-Property Relationships for Poly(alkyl thiophene)-Fullerene Derivative Thin Filmsto Optimize Performance in Photovoltaic Devices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deb, Nabankur; Li, Bohao; Skoda, Maximilian; Rogers, Sarah; Sun, Yan; Gong, Xiong; Karim, Alamgir; Sumpter, Bobby G.; Bucknall, David G.

    2016-02-08

    Nanoscale bulk heterojunction (BHJ) systems, consisting of fullerenes dispersed in conjugated polymers as the active component, have been actively studied over the last decades in order to produce high performance organic photovoltaics (OPVs). A significant role in device efficiency is played by the active layer morphology, but despite considerable study, a full understanding of the exact role that morphology plays and therefore a definitive method to produce and control an ideal morphology is lacking. In order to understand the BHJ phase behavior and associated morphology in these devices, we have used neutron reflection, together with grazing incidence X-ray and neutronmore » scattering and X-ray photoelectron spectroscopy (XPS) to determine the morphology of the BHJ active layer in functional devices. We have studied nine model BHJ systems based on mixtures of three poly(3-alkyl thiophenes, P3AT) (A=butyl, hexyl, octyl) blended with three different fullerene derivatives, which provides variations in crystallinity and miscibility within the BHJ composite. In studying properties of functional devices, we show a direct correlation between the observed morphology within the BHJ layer and the device performance metrics, i.e., the short-circuit current (JSC), fill factor (FF), open-circuit voltage (VOC) and overall power conversion efficiency (PCE). Using these model systems, the effect of typical thermal annealing processes on the BHJ morphology through the film thickness as a function of the polythiophene-fullerene mixtures and different electron transport layer interfaces has been determined. It is shown that fullerene enrichment occurs at both the electrode interfaces after annealing. The degree of fullerene enrichment is found to strongly correlate with JSC and to a lesser degree with FF. Finally, based on these findings we demonstrate that by deliberately adding a fullerene layer at the electron transport layer interface, JSC can be increased by up to 20

  15. Oblique solitary waves in a five component plasma

    SciTech Connect (OSTI)

    Sijo, S.; Manesh, M.; Sreekala, G.; Venugopal, C.; Neethu, T. W.; Renuka, G.

    2015-12-15

    We investigate the influence of a second electron component on oblique dust ion acoustic solitary waves in a five component plasma consisting of positively and negatively charged dust, hydrogen ions, and hotter and colder electrons. Of these, the heavier dust and colder photo-electrons are of cometary origin while the other two are of solar origin; electron components are described by kappa distributions. The K-dV equation is derived, and different attributes of the soliton such as amplitude and width are plotted for parameters relevant to comet Halley. We find that the second electron component has a profound influence on the solitary wave, decreasing both its amplitude and width. The normalized hydrogen density strongly influences the solitary wave by decreasing its width; the amplitude of the solitary wave, however, increases with increasing solar electron temperatures.

  16. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Clark, W.; Graves, R.; Orban, J.; Przesmitzki, S.; Theiss, T.

    2009-02-01

    Intended for policymakers and others who make decisions about, and set guidelines for, the proper use of intermediate ethanol blends such as E20 in both vehicle engines and other engine types.

  17. Transducer for downhole drilling components

    DOE Patents [OSTI]

    Hall, David R; Fox, Joe R

    2006-05-30

    A robust transmission element for transmitting information between downhole tools, such as sections of drill pipe, in the presence of hostile environmental conditions, such as heat, dirt, rocks, mud, fluids, lubricants, and the like. The transmission element maintains reliable connectivity between transmission elements, thereby providing an uninterrupted flow of information between drill string components. A transmission element is mounted within a recess proximate a mating surface of a downhole drilling component, such as a section of drill pipe. The transmission element may include an annular housing forming a trough, an electrical conductor disposed within the trough, and an MCEI material disposed between the annular housing and the electrical conductor.

  18. On-Road Use of Fischer-Tropsch Diesel Blends

    SciTech Connect (OSTI)

    Nigel Clark; Mridul Gautam; Donald Lyons; Chris Atkinson; Wenwei Xie; Paul Norton; Keith Vertin; Stephen Goguen; James Eberhardt

    1999-04-26

    Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California No.2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NO{sub x}) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state No.2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without. The CBD cycle was employed as the test schedule, with a test weight of 33,050 lb. For those buses with catalytic converters and rebuilt engines, NO x was reduced by 8% and PM was reduced by 31% on average, while for those buses without, NO x was reduced by 5% and PM was reduced by 20% on average. It is concluded that advanced compression ignition fuels from non-petroleum sources can offer environmental advantages in typical line haul and city transit applications.

  19. Advanced Vehicle Testing Activity: Low-Percentage Hydrogen/CNG Blend Ford F-150 Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of 16,942 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 30% hydrogen/70% CNG fuel.

  20. Advanced Vehicle Testing Activity: High-Percentage Hydrogen/CNG Blend Ford F-150 Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents the results of 4,695 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 50% hydrogen-50% CNG fuel.

  1. Effects of Mid-Level Ethanol Blends on Conventional Vehicle Emissions

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Huff, S.; Thomas, J.; Orban, J.; Cooper, C.

    2010-06-01

    Tests were conducted in 2008 on 16 late-model conventional vehicles (1999-2007) to determine short-term effects of mid-level ethanol blends on performance and emissions. Vehicle odometer readings ranged from 10,000 to 100,000 miles, and all vehicles conformed to federal emissions requirements for their federal certification level. The LA92 drive cycle, also known as the Unified Cycle, was used for testing because it more accurately represents real-world acceleration rates and speeds than the Federal Test Procedure. Test fuels were splash-blends of up to 20 volume percent ethanol with federal certification gasoline. Both regulated and unregulated air-toxic emissions were measured. For the 16-vehicle fleet, increasing ethanol content resulted in reductions in average composite emissions of both nonmethane hydrocarbons and carbon monoxide and increases in average emissions of ethanol and aldehydes.

  2. SimwYpes(tm) and RonJohn Blend | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SimwYpes(tm) and RonJohn ... SimwYpes(tm) and RonJohn Blend The mp4 video format is not supported by this browser. Download video Captions: On Time: 2:20 min. Created to remove residual amounts of beryllium oxide and beryllium particulate from solid surfaces without leaving a residue, SimwYpes are ideal for multiple uses. Quick, gentle, but effective. The inventors of RonJohn solvent talk about its invention and uses

  3. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Szybist, James P; Thomas, John F; Barone, Teresa L; Eibl, Mary A; Nafziger, Eric J; Kaul, Brian C

    2014-01-01

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  4. Pushing schedule derivation method

    SciTech Connect (OSTI)

    Henriquez, B.

    1996-12-31

    The development of a Pushing Schedule Derivation Method has allowed the company to sustain the maximum production rate at CSH`s Coke Oven Battery, in spite of having single set oven machinery with a high failure index as well as a heat top tendency. The stated method provides for scheduled downtime of up to two hours for machinery maintenance purposes, periods of empty ovens for decarbonization and production loss recovery capability, while observing lower limits and uniformity of coking time.

  5. Large Component Removal/Disposal

    SciTech Connect (OSTI)

    Wheeler, D. M.

    2002-02-27

    This paper describes the removal and disposal of the large components from Maine Yankee Atomic Power Plant. The large components discussed include the three steam generators, pressurizer, and reactor pressure vessel. Two separate Exemption Requests, which included radiological characterizations, shielding evaluations, structural evaluations and transportation plans, were prepared and issued to the DOT for approval to ship these components; the first was for the three steam generators and one pressurizer, the second was for the reactor pressure vessel. Both Exemption Requests were submitted to the DOT in November 1999. The DOT approved the Exemption Requests in May and July of 2000, respectively. The steam generators and pressurizer have been removed from Maine Yankee and shipped to the processing facility. They were removed from Maine Yankee's Containment Building, loaded onto specially designed skid assemblies, transported onto two separate barges, tied down to the barges, th en shipped 2750 miles to Memphis, Tennessee for processing. The Reactor Pressure Vessel Removal Project is currently under way and scheduled to be completed by Fall of 2002. The planning, preparation and removal of these large components has required extensive efforts in planning and implementation on the part of all parties involved.

  6. SAVANNAH RIVER SITE'S H-CANYON FACILITY: RECOVERY AND DOWN BLEND URANIUM FOR BENEFICIAL USE

    SciTech Connect (OSTI)

    Magoulas, V.

    2013-05-27

    For over fifty years, the H Canyon facility at the Savannah River Site (SRS) has performed remotely operated radiochemical separations of irradiated targets to produce materials for national defense. Although the materials production mission has ended, the facility continues to play an important role in the stabilization and safe disposition of proliferable nuclear materials. As part of the US HEU Disposition Program, SRS has been down blending off-specification (off-spec) HEU to produce LEU since 2003. Off-spec HEU contains fission products not amenable to meeting the American Society for Testing and Material (ASTM) commercial fuel standards prior to purification. This down blended HEU material produced 301 MT of ~5% enriched LEU which has been fabricated into light water reactor fuel being utilized in Tennessee Valley Authority (TVA) reactors in Tennessee and Alabama producing economic power. There is still in excess of ~10 MT of off-spec HEU throughout the DOE complex or future foreign and domestic research reactor returns that could be recovered and down blended for beneficial use as either ~5% enriched LEU, or for use in subsequent LEU reactors requiring ~19.75% enriched LEU fuel.

  7. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2014-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  8. Recovery and Blend-Down Uranium for Beneficial use in Commercial Reactors - 13373

    SciTech Connect (OSTI)

    Magoulas, Virginia [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)

    2013-07-01

    In April 2001 the Department of Energy (DOE) and the Tennessee Valley Authority (TVA) signed an Interagency Agreement to transfer approximately 33 MT of off-specification (off-spec) highly enriched uranium (HEU) from DOE to TVA for conversion to commercial reactor fuel. Since that time additional surplus off-spec HEU material has been added to the program, making the total approximately 46 MT off-spec HEU. The disposition path for approximately half (23 MT) of this 46 MT of surplus HEU material, was down blending through the H-canyon facility at the Savannah River Site (SRS). The HEU is purified through the H-canyon processes, and then blended with natural uranium (NU) to form low enriched uranium (LEU) solution with a 4.95% U-235 isotopic content. This material was then transported to a TVA subcontractor who converted the solution to uranium oxide and then fabricated into commercial light water reactor (LWR) fuel. This fuel is now powering TVA reactors and supplying electricity to approximately 1 million households in the TVA region. There is still in excess of approximately 10 to 14 MT of off-spec HEU throughout the DOE complex or future foreign and domestic research reactor returns that could be recovered and down blended for use in either currently designed light water reactors, ?5% enriched LEU, or be made available for use in subsequent advanced 'fast' reactor fuel designs, ?19% LEU. (authors)

  9. Blending municipal solid waste with corn stover for sugar production using ionic liquid process

    SciTech Connect (OSTI)

    Sun, Ning; Xu, Feng; Sathitsuksanoh, Noppadon; Thompson, Vicki S.; Cafferty, Kara; Li, Chenlin; Tanjore, Deepti; Narani, Akash; Pray, Todd R.; Simmons, Blake A.; Singh, Seema

    2015-06-01

    Municipal solid waste (MSW) represents an attractive cellulosic resource for sustainable fuel production because of its abundance and its low or perhaps negative cost. However, the significant heterogeneity and toxic contaminants are barriers to efficient conversion to ethanol and other products. In this study, we generated MSW paper mix, blended with corn stover (CS), and have shown that both MSW paper mix alone and MSW/CS blends can be efficiently pretreated in certain ionic liquids (ILs) with high yields of fermentable sugars. After pretreatment in 1-ethyl-3-methylimidazolium acetate ([C2C1Im][OAc]), over 80% glucose has been released with enzymatic saccharification. We have also applied an enzyme free process by adding mineral acid and water directly into the IL/biomass slurry to induce hydrolysis. With the acidolysis process in the IL 1-ethyl-3-methylimidazolium chloride ([C2C1Im]Cl), up to 80% glucose and 90% xylose are released for MSW. The results indicate the feasibility of incorporating MSW as a robust blending agent for biorefineries.

  10. Low-temperature pyrolysis of coal to produce diesel-fuel blends

    SciTech Connect (OSTI)

    Shafer, T.B.; Jett, O.J.; Wu, J.S.

    1982-10-01

    Low-temperature (623 to 773/sup 0/K) coal pyrolysis was investigated in a bench-scale retort. Factorially designed experiments were conducted to determine the effects of temperature, coal-particle size, and nitrogen flow rate on the yield of liquid products. Yield of condensable organic products relative to the proximate coal volatile matter increased by 3.1 and 6.4 wt % after increasing nitrogen purge flow rate from 0.465 to 1.68 L/min and retort temperature from 623 to 723/sup 0/K, respectively. The liquid product may be suitable for blending with diesel fuel. The viscosity and density of coal liquids produced at 723/sup 0/K were compared with those of diesel fuel. The coal liquids had a higher carbon-to-hydrogen ratio and a lower aliphatic-to-aromatic ratio than premium quality No. 2 diesel fuel. It was recommended that liquids from coal pyrolysis be blended with diesel fuel to determine stability of the mixture and performance of the blend in internal combustion engines.

  11. Self-degradable Slag/Class F Fly Ash-Blend Cements

    SciTech Connect (OSTI)

    Sugama, T.; Warren, J.; Butcher, T.; Lance Brothers; Bour, D.

    2011-03-01

    Self-degradable slag/Class F fly ash blend pozzolana cements were formulated, assuming that they might serve well as alternative temporary fracture sealers in Enhanced Geothermal System (EGS) wells operating at temperatures of {ge} 200 C. Two candidate formulas were screened based upon material criteria including an initial setting time {ge} 60 min at 85 C, compressive strength {ge} 2000 psi for a 200 C autoclaved specimen, and the extent of self-degradation of cement heated at {ge} 200 C for it was contacted with water. The first screened dry mix formula consisted of 76.5 wt% slag-19.0 wt% Class F fly ash-3.8 wt% sodium silicate as alkali activator, and 0.7 wt% carboxymethyl cellulose (CMC) as the self-degradation promoting additive, and second formula comprised of 57.3 wt% slag, 38.2 wt% Class F fly ash, 3.8 wt% sodium silicate, and 0.7 wt% CMC. After mixing with water and autoclaving it at 200 C, the aluminum-substituted 1.1 nm tobermorite crystal phase was identified as hydrothermal reaction product responsible for the development of a compressive strength of 5983 psi. The 200 C-autoclaved cement made with the latter formula had the combined phases of tobermorite as its major reaction product and amorphous geopolymer as its minor one providing a compressive strength of 5271 psi. Sodium hydroxide derived from the hydrolysis of sodium silicate activator not only initiated the pozzolanic reaction of slag and fly ash, but also played an important role in generating in-situ exothermic heat that significantly contributed to promoting self-degradation of cementitious sealers. The source of this exothermic heat was the interactions between sodium hydroxide, and gaseous CO{sub 2} and CH{sub 3}COOH by-products generated from thermal decomposition of CMC at {ge} 200 C in an aqueous medium. Thus, the magnitude of this self-degradation depended on the exothermic temperature evolved in the sealer; a higher temperature led to a sever disintegration of sealer. The exothermic

  12. Component Modeling Approach Software Tool

    SciTech Connect (OSTI)

    2010-08-23

    The Component Modeling Approach Software Tool (CMAST) establishes a set of performance libraries of approved components (frames, glass, and spacer) which can be accessed for configuring fenestration products for a project, and btaining a U-factor, Solar Heat Gain Coefficient (SHGC), and Visible Transmittance (VT) rating for those products, which can then be reflected in a CMA Label Certificate for code compliance. CMAST is web-based as well as client-based. The completed CMA program and software tool will be useful in several ways for a vast array of stakeholders in the industry: Generating performance ratings for bidding projects Ascertaining credible and accurate performance data Obtaining third party certification of overall product performance for code compliance

  13. Nuclear component horizontal seismic restraint

    DOE Patents [OSTI]

    Snyder, Glenn J.

    1988-01-01

    A nuclear component horizontal seismic restraint. Small gaps limit horizontal displacement of components during a seismic occurrence and therefore reduce dynamic loadings on the free lower end. The reactor vessel and reactor guard vessel use thicker section roll-forged rings welded between the vessel straight shell sections and the bottom hemispherical head sections. The inside of the reactor guard vessel ring forging contains local vertical dovetail slots and upper ledge pockets to mount and retain field fitted and installed blocks. As an option, the horizontal displacement of the reactor vessel core support cone can be limited by including shop fitted/installed local blocks in opposing alignment with the reactor vessel forged ring. Beams embedded in the wall of the reactor building protrude into apertures in the thermal insulation shell adjacent the reactor guard vessel ring and have motion limit blocks attached thereto to provide to a predetermined clearance between the blocks and reactor guard vessel ring.

  14. Component Modeling Approach Software Tool

    Energy Science and Technology Software Center (OSTI)

    2010-08-23

    The Component Modeling Approach Software Tool (CMAST) establishes a set of performance libraries of approved components (frames, glass, and spacer) which can be accessed for configuring fenestration products for a project, and btaining a U-factor, Solar Heat Gain Coefficient (SHGC), and Visible Transmittance (VT) rating for those products, which can then be reflected in a CMA Label Certificate for code compliance. CMAST is web-based as well as client-based. The completed CMA program and software toolmore » will be useful in several ways for a vast array of stakeholders in the industry: Generating performance ratings for bidding projects Ascertaining credible and accurate performance data Obtaining third party certification of overall product performance for code compliance« less

  15. Fueling Components Testing and Certification

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Standards and Codes * National Recognized Standards * Enforceable Docs by 2012 * Code Cycle 2012 Vehicles ∙ Commercialization 2015 ∙ 50,000 by 2017 ∙ Consumer price ∙ 80% in CA Infrastructure ∙ 200 Stations in CA ∙ Accurate and Safe Equipment ∙ Commercial Venture ∙ Station Certification Implementation ∙ Component Certification * Public Awareness * General Education ∙ Technician Training ∙ Safety, Reliability and Accurate Evolving Hydrogen Vehicle Industry 3 Time Line -

  16. Energy Storage Components and Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Components and Systems - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  17. Catalytic Process for the Conversion of Coal-derived Syngas to Ethanol

    SciTech Connect (OSTI)

    James Spivery; Doug Harrison; John Earle; James Goodwin; David Bruce; Xunhau Mo; Walter Torres; Joe Allison Vis Viswanathan; Rick Sadok; Steve Overbury; Viviana Schwartz

    2011-07-29

    The catalytic conversion of coal-derived syngas to C{sub 2+} alcohols and oxygenates has attracted great attention due to their potential as chemical intermediates and fuel components. This is particularly true of ethanol, which can serve as a transportation fuel blending agent, as well as a hydrogen carrier. A thermodynamic analysis of CO hydrogenation to ethanol that does not allow for byproducts such as methane or methanol shows that the reaction: 2 CO + 4 H{sub 2} {yields} C{sub 2}H{sub 5}OH + H{sub 2}O is thermodynamically favorable at conditions of practical interest (e.g,30 bar, {approx}< 250 C). However, when methane is included in the equilibrium analysis, no ethanol is formed at any conditions even approximating those that would be industrially practical. This means that undesired products (primarily methane and/or CO{sub 2}) must be kinetically limited. This is the job of a catalyst. The mechanism of CO hydrogenation leading to ethanol is complex. The key step is the formation of the initial C-C bond. Catalysts that are selective for EtOH can be divided into four classes: (a) Rh-based catalysts, (b) promoted Cu catalysts, (c) modified Fischer-Tropsch catalysts, or (d) Mo-sulfides and phosphides. This project focuses on Rh- and Cu-based catalysts. The logic was that (a) Rh-based catalysts are clearly the most selective for EtOH (but these catalysts can be costly), and (b) Cu-based catalysts appear to be the most selective of the non-Rh catalysts (and are less costly). In addition, Pd-based catalysts were studied since Pd is known for catalyzing CO hydrogenation to produce methanol, similar to copper. Approach. The overall approach of this project was based on (a) computational catalysis to identify optimum surfaces for the selective conversion of syngas to ethanol; (b) synthesis of surfaces approaching these ideal atomic structures, (c) specialized characterization to determine the extent to which the actual catalyst has these structures, and (d) testing

  18. Laser ultrasonic multi-component imaging

    SciTech Connect (OSTI)

    Williams, Thomas K.; Telschow, Kenneth

    2011-01-25

    Techniques for ultrasonic determination of the interfacial relationship of multi-component systems are discussed. In implementations, a laser energy source may be used to excite a multi-component system including a first component and a second component at least in partial contact with the first component. Vibrations resulting from the excitation may be detected for correlation with a resonance pattern indicating if discontinuity exists at the interface of the first and second components.

  19. The design and management of system components for in situ methanotrophic bioremediation of chlorinated hydrocarbons

    SciTech Connect (OSTI)

    Lombard, K.H.; Borthen, J.W.; Hazen, T.C.

    1992-12-31

    The successful operation of an in situ bioremediation system is inherent within its design. Well-organized system components enable ease of maintenance, limited down time, and relatively rapid data acquisition. The design effort in this project focused on injection of a low-pressure air/methane mixture into a horizontal well below the water table, a methane-blending system that provided control of the injected mixture, redundant safety interlocks, vapor-phase extraction from a second horizontal well, and an off-gas treatment system that provided efficient thermal catalytic oxidation of the extracted contaminant vapors. The control instrumentation provided sufficient redundancies to allow the system to remain in operation in the event of a component failure, and equally important, the safe shut down of the system should any designed safety parameters be exceeded (i.e., high methane concentration). Final design approval took into consideration the reliability of the equipment and the components specified. Product knowledge and proper application limited the risk of a component or system failure while providing a safe, efficient, and cost-effective remediation system. Microprocessor data acquisition and system control were integrated with an autodialer to provide 24 hr emergency response and operation without on-site supervision. This integrated system also insured accurate data analysis and minimum downtime. Since operations commenced, the system has operated a total of 7,760 hours out of the possible 8,837 hours available. This equates to an operating efficiency of 87.8%.

  20. Electric Drive Component Manufacturing Facilities | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Component Manufacturing Facilities Electric Drive Component Manufacturing Facilities 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review ...

  1. Electric Drive Component Manufacturing Facilities | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Component Manufacturing Facilities Electric Drive Component Manufacturing Facilities 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review ...

  2. Transformer Resilience and Advanced Components (TRAC) Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OE's Transformer Resilience and Advanced Components (TRAC) program supports modernization ... which are a critical component of the electricity delivery system, are a concern because ...

  3. Porous templated pyrolytic carbons as electrocatalyst components...

    Office of Scientific and Technical Information (OSTI)

    Porous templated pyrolytic carbons as electrocatalyst components. Citation Details In-Document Search Title: Porous templated pyrolytic carbons as electrocatalyst components. ...

  4. LONG TERM AGING AND SURVEILLANCE OF 9975 PACKAGE COMPONENTS

    SciTech Connect (OSTI)

    Hoffman, E.; Skidmore, E.; Daugherty, W.; Dunn, K.

    2009-11-10

    The mission of the 9975 package, originally designed only for transportation of radioactive materials, has been broadened to include storage at the Savannah River Site. Two components of this package, namely the containment vessel O-rings and fiberboard overpack, require continued integrity assessment under the storage conditions. The performance of the components over time is being evaluated using accelerated-aging studies. Compression stress relaxation (CSR) and leak testing are being used to measure the performance of O-rings. The performance of the fiberboard is being evaluated using compression strength, thermal conductivity, specific heat capacity and other physical properties. Models developed from the data collected provide an initial prediction of service life for the two components, and support the conclusion that normal service conditions will not degrade the performance of the package beyond specified functional requirements for the first assessment interval. Increased confidence in this conclusion is derived from field surveillance data and destructive evaluation of packages removed from storage.

  5. Rotor component displacement measurement system

    DOE Patents [OSTI]

    Mercer, Gary D.; Li, Ming C.; Baum, Charles R.

    2003-05-27

    A measuring system for measuring axial displacement of a tube relative to an axially stationary component in a rotating rotor assembly includes at least one displacement sensor adapted to be located normal to a longitudinal axis of the tube; an insulated cable system adapted for passage through the rotor assembly; a rotatable proximitor module located axially beyond the rotor assembly to which the cables are connected; and a telemetry system operatively connected to the proximitor module for sampling signals from the proximitor module and forwarding data to a ground station.

  6. Algae Derived Biofuel

    SciTech Connect (OSTI)

    Jahan, Kauser

    2015-03-31

    One of the most promising fuel alternatives is algae biodiesel. Algae reproduce quickly, produce oils more efficiently than crop plants, and require relatively few nutrients for growth. These nutrients can potentially be derived from inexpensive waste sources such as flue gas and wastewater, providing a mutual benefit of helping to mitigate carbon dioxide waste. Algae can also be grown on land unsuitable for agricultural purposes, eliminating competition with food sources. This project focused on cultivating select algae species under various environmental conditions to optimize oil yield. Membrane studies were also conducted to transfer carbon di-oxide more efficiently. An LCA study was also conducted to investigate the energy intensive steps in algae cultivation.

  7. Three-component gyrotropic metamaterial

    SciTech Connect (OSTI)

    Tralle, Igor, E-mail: tralle@ur.edu.pl; Zi?ba, Pawe?; Pa?ko, Wioletta [Faculty of Mathematics and Natural Sciences, Theoretical Physics Department, University of Rzeszw, Pigonia 1, 35-310 Rzeszw (Poland)

    2014-06-21

    All of the proposed ever since designs of metamaterials are characterized by ever-increasing sophistication of fabrication methods. Here, a comparatively simple recipe for the fabrication of a metamaterial, which is both gyrotropic and of the simultaneously negative permittivity and permeability, is proposed. The idea is to make a mixture of three ingredients, where one of them would be responsible for the negativity of ?, while the other two would be responsible for the negativity of ?. The first component of the mixture is the swarm of single-domain ferromagnetic nano-particles, immersed in a mixture of other two, silver and mercury cadmium telluride. By carrying out the computer simulations, the domains of gyromagnetic metamaterial exist, relative to all parameters characterizing the model, that is, the temperature, external magnetic field, parameters of nano-particles, and the fraction of cadmium in Hg{sub 1?x}Cd{sub x}Te-compound as well as relative concentrations of the mixture components are established.

  8. Technical Issues Associated With the Use of Intermediate Ethanol Blends (>E10) in the U.S. Legacy Fleet

    SciTech Connect (OSTI)

    Rich, Bechtold; Thomas, John F; Huff, Shean P; Szybist, James P; West, Brian H; Theiss, Timothy J; Timbario, Tom; Goodman, Marc

    2007-08-01

    The Oak Ridge National Laboratory (ORNL) supports the U.S. Department of Energy (DOE) in assessing the impact of using intermediate ethanol blends (E10 to E30) in the legacy fleet of vehicles in the U.S. fleet. The purpose of this report is to: (1) identify the issues associated with intermediate ethanol blends with an emphasis on the end-use or vehicle impacts of increased ethanol levels; (2) assess the likely severity of the issues and whether they will become more severe with higher ethanol blend levels, or identify where the issue is most severe; (3) identify where gaps in knowledge exist and what might be required to fill those knowledge gaps; and (4) compile a current and complete bibliography of key references on intermediate ethanol blends. This effort is chiefly a critical review and assessment of available studies. Subject matter experts (authors and selected expert contacts) were consulted to help with interpretation and assessment. The scope of this report is limited to technical issues. Additional issues associated with consumer, vehicle manufacturer, and regulatory acceptance of ethanol blends greater than E10 are not considered. The key findings from this study are given.

  9. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2003-06-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, we have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Our strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, we have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. To date, our activities have covered three areas: examination of the impact of lubricity additives on the viscosity of DME, development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. This report provides summaries of the progress toward evaluation of the viscosity impacts of lubricity additives, completion of both experimental systems and a summary of the plan for completion of the project objectives.

  10. Numerical study of the effect of oxygenated blending compounds on soot formation in shock tubes

    SciTech Connect (OSTI)

    Boehm, H.; Braun-Unkhoff, M.

    2008-04-15

    This numerical study deals with the influence of blends on the amount of soot formed in shock tubes, which were simulated by assuming a homogeneous plug flow reactor model. For this purpose, first, the reaction model used here was validated against experimental results previously obtained in the literature. Then, the soot volume fractions of various mixtures of methyl tert-butyl ether (MTBE)-benzene, isobutene-benzene, methanol-benzene, and ethanol-benzene diluted in argon were simulated and compared to the results of benzene-argon pyrolysis at 1721 K and 5.4 MPa. For MTBE, isobutene, methanol, and ethanol, small amounts of additives to benzene-argon mixtures promoted soot formation, for the shock tube model assumed, while higher concentrations of these additives led to smaller soot volume fractions in comparison to pure benzene-argon pyrolysis. The most significant soot promotion effect was found for the additives MTBE and isobutene. The channel for MTBE decomposition producing isobutene and methanol is very effective at temperatures beyond 1200 K. Thus, both MTBE-benzene and isobutene-benzene mixtures diluted in argon showed rather similar behavior in regard to soot formation. Special emphasis was directed toward the causes for the concentration-dependent influence of the blends on the amount of soot formed. Aromatic hydrocarbons and acetylene were identified as key gas-phase species that determine the trends in the formation of soot of various mixtures. From reaction flux analysis for phenanthrene, it was deduced that the combinative routes including phenyl species play a major role in forming PAHs, especially at early reaction times. It is found that the additives play an important role in providing material to grow side chains, such as by reaction channels including phenylacetylene or benzyl, which are confirmed to form aromatic hydrocarbons and thus to influence the amount of soot formed, particularly when the concentrations of the blends are increased