Sample records for blast pulping liquor

  1. Electrochemical treatment of black liquor from straw pulping

    SciTech Connect (OSTI)

    Blanco, M.A.; Negro, C.; Tijero, J. [Complutense Univ., Madrid (Spain)] [and others

    1996-11-01T23:59:59.000Z

    The conventional black liquor regeneration process is not always suitable for pulping plants of nonwood fibers due to the unfavorable ratio of organic to inorganic solids. This paper presents an alternative treatment based on an electrolysis process of the soda black liquor from straw pulping. This alternative method minimizes the environmental impact by recovering the caustic at the same time that the liquor is acidified, which favors the later separation of the lignin.

  2. Thermal processing of black liquor from alkaline straw pulping

    SciTech Connect (OSTI)

    Sanchez, J.L.; Garcia, L.; Gea, G.; Bilbao, R.; Arauzo, J. [Univ. of Zaragoza (Spain)

    1996-12-31T23:59:59.000Z

    Black liquor is the wastewater from the cooking of wood or straw in the production of pulp and paper. Nowadays new processes are being investigated as alternatives to the traditional recovery boiler used for black liquor treatment. One of the processes which appears to be more promising is gasification, for which further research is needed for its full industrial implementation. There is not much data about the behavior of soda black liquors from straw cooking in the literature. Therefore the thermal decomposition of one of these liquors has been studied in a thermobalance, in inert (N{sub 2}) atmosphere. The kinetic constants from isothermal experiments have been obtained.

  3. Novel Pulping Technology: Directed Green Liquor Utilization (D-GLU) Pulping

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15T23:59:59.000Z

    The general objectives of this new project are the same as those described in the original proposal. Conventional kraft pulping technologies will be modified for significant improvements in pulp production, such as strength, bleachability, and yield by using green liquor, a naturally high, kraft mill-derived sulfidity source. Although split white liquor sulfidity and other high sulfidity procedures have the promise of addressing several of the latter important economic needs of pulp mills, they require considerable engineering/capital retrofits, redesigned production methods, and thus add to overall mill expenditures. Green liquor use, however, possesses the required high sulfidity to obtain in general the benefits attributable to higher sulfidity cooking, without the required capital constraints for implementation. Before introduction of green liquor in our industrial operations, a stronger understanding of its fundamental chemical interaction with the lignin and carbohydrates in US hardwood and softwoods must be obtained. In addition, its effect on bleachability, enhancement of pulp properties, and influence on the overall energy and recovery of the mill requires further exploration before the process witnesses widespread mill use in North America. Thus, proof of principle will be accomplished in this work and the consequent effect of green liquor and other high sulfide sources on the pulping and bleaching operations will be explored for US kraft mills. The first year of this project will generate the pertinent information to validate its ability for implementation in US pulping operations, whereas year two will continue this work while proceeding to analyze pulp bleachability and final pulp/paper properties and develop a general economic and feasibility analysis for its eventual implementation in North America.

  4. BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS

    E-Print Network [OSTI]

    BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS ERIC D. LARSON modeling of gasifier/gas turbine pulp-mill cogeneration systemsusing gasifier designs under commercial gasification. The use of biomass fuels with gas turbines could transform a typical pulp mill from a net

  5. Method for improving separation of carbohydrates from wood pulping and wood or biomass hydrolysis liquors

    DOE Patents [OSTI]

    Griffith, William Louis; Compere, Alicia Lucille; Leitten Jr., Carl Frederick

    2010-04-20T23:59:59.000Z

    A method for separating carbohydrates from pulping liquors includes the steps of providing a wood pulping or wood or biomass hydrolysis pulping liquor having lignin therein, and mixing the liquor with an acid or a gas which forms an acid upon contact with water to initiate precipitation of carbohydrate to begin formation of a precipitate. During precipitation, at least one long chain carboxylated carbohydrate and at least one cationic polymer, such as a polyamine or polyimine are added, wherein the precipitate aggregates into larger precipitate structures. Carbohydrate gel precipitates are then selectively removed from the larger precipitate structures. The method process yields both a carbohydrate precipitate and a high purity lignin.

  6. Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery

    SciTech Connect (OSTI)

    Adriaan van Heiningen

    2007-06-30T23:59:59.000Z

    MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of the conversion of Na{sub 2}CO{sub 3} to (high sodium) titanates during gasification of black liquor in the presence of (low sodium) titanates or TiO{sub 2} (Task 2). MTCI/ThermoChem tested the performance and operability of the combined technology of steam reforming and direct causticization in their Process Development Unit (PDU) (Task 3). The specific objectives were: (1) to investigate how split sulfidity and polysulfide (+ AQ) pulping can be used to increase pulp fiber yield and properties compared to conventional kraft pulping; (2) to determine the economics of black liquor gasification combined with these pulping technologies in comparison with conventional kraft pulping and black liquor recovery; (3) to determine the effect of operating conditions on the kinetics of the titanate-based direct causticization reaction during black liquor gasification at relatively low temperatures ({le} 750 C); (4) to determine the mechanism of particle agglomeration during gasification of black liquor in the presence of titanates at relatively low temperatures ({le} 750 C); and (5) to verify performance and operability of the combined technology of steam reforming and direct causticization of black liquor in a pilot scale fluidized bed test facility.

  7. The preparation and analysis of ammonia base sulfite pulping liquor

    E-Print Network [OSTI]

    Honstead, John Frederick

    1950-01-01T23:59:59.000Z

    much better check between results obtained by two different operators testing the same sample, and using the Palm- rose method. In a mill the liquor is test d b? shift men as the liquor is being prepared, and also by technicians in the laboratory...

  8. Combined biomass and black liquor gasifier/gas turbine cogeneration at pulp and paper mills

    SciTech Connect (OSTI)

    Larson, E.D.; Kreutz, T.G. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies; Consonni, S. [Politecnico di Milano, Milan (Italy). Dipt. di Energetica

    1999-07-01T23:59:59.000Z

    Kraft pulp and paper mills generate large quantities of black liquor and byproduct biomass suitable for gasification. These fuels are used today for onsite cogeneration of heat and power in boiler/steam turbine systems. Gasification technologies under development would enable these fuels to be used in gas turbines. This paper reports results of detailed full-load performance modeling of pulp-mill cogeneration systems based on gasifier/gas turbine technologies. Pressurized, oxygen-blown black liquor gasification, the most advanced of proposed commercial black liquor gasifier designs, is considered, together with three alternative biomass gasifier designs under commercial development (high-pressure air-blown, low-pressure air-blown, and low-pressure indirectly-heated). Heavy-duty industrial gas turbines of the 70-MW{sub e} and 25-MW {sub e} class are included in the analysis. Results indicate that gasification-based cogeneration with biomass-derived fuels would transform a typical pulp mill into significant power exporter and would also offer possibilities for net reductions in emissions of carbon dioxide relative to present practice.

  9. HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING

    SciTech Connect (OSTI)

    Lucia, Lucian A

    2013-04-19T23:59:59.000Z

    Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

  10. PERFORMANCE OF BLACK LIQUOR GASIFIER/GAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP

    E-Print Network [OSTI]

    PERFORMANCE OF BLACK LIQUOR GASIFIER/GAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP high-temperature gasifiers for gas turbine applications. ABB and MTCr/Stonechem are developing low-load performance of gasifier/gas turbine systemsincorporating the four above-noted gasifier designs are reported

  11. Separation and characterization of lignins from the black liquor of oil palm trunk fiber pulping

    SciTech Connect (OSTI)

    Sun, R.; Tomkinson, J.; Bolton, J.

    1999-11-01T23:59:59.000Z

    Six lignin preparations, isolated by a novel two-step precipitation method instead of the traditional one-step precipitation method from the oil palm trunk fiber pulping (OPTFP) black liquor, were found to be relatively free of nonlignin materials such as polysaccharide degradation products, ash, and salts. A lignin fraction with a purity of 99.5% was obtained at an optimum precipitation pH 1.5 after isolation of the nonlignin materials in ethanol. About 94% of the total lignin was recovered by this novel method at this condition, and the value of COD in the treated black liquor reduced significantly to lower 250. The isolated lignin fractions contained syringyl, guaiacyl, and p-hydroxyphenyl units in an approximate molar ratio of 16--20:5:1 on the basis of chemical and spectroscopic analysis. Small amounts of p-hydroxybenzoic acids were found to be esterified to lignin, while ferulic acids were associated to lignin by ether linkage. {sup 13}C-NMR indicated the presence of {beta}-O-4 ether bonds, and {beta}-5 and 5-5{prime} carbon-carbon linkages between the lignin molecules.

  12. Effect of pulping conditions and black liquor composition on Newtonian viscosity of high solids kraft black liquors

    SciTech Connect (OSTI)

    Zaman, A.A.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering] [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering

    1996-02-01T23:59:59.000Z

    The influence of black liquor composition and solids concentrations on the Newtonian viscosity of slash pine black liquors over wide ranges of temperature (up to 140 C) and solids concentrations (between 50% and 83% solids) has been studied. It was found that the zero shear rate viscosity of high solids black liquors depends strongly on the cooking conditions and/or black liquor composition. Not only is high solids viscosity affected by lignin molecular weight and lignin concentration in the liquor but other organic and inorganic constituents of black liquor also make a significant contribution to viscosity. The dependency of zero shear rate viscosity on solids concentrations, and temperature is defined. The Newtonian viscosities vary over a wide range depending on temperature, solids concentrations and solids composition. The results indicate that, at fixed levels of effective alkali and sulfidity, the zero shear rate viscosities can be described as a function of both lignin concentration and lignin molecular weight. The viscosity of black liquor is an increasing function of the organics-to-inorganics ratio and is a decreasing function of the concentration of sodium and chloride ions and pH of the liquor.

  13. High-solids black liquor firing in pulp and paper industry kraft recovery boilers. Quarterly report, Phase 1a: Black liquor gasifier evaluation

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    This project phase addresses the following workscope: Conduct bench-scale tests of a low temperature, partial combustion gasifier; Prepare a gasifier pilot-plant preliminary design and cost estimate and prepare a budgetary cost estimate of the balance of the program; Outline a test program to evaluate gasification; Prepare an economic/market analysis of gasification and solicit pulp and paper industry support for subsequent phases; and Prepare a final report and conduct a project review prior to commencement of work leading to construction of any pilot scale components or facilities. The primary accomplishments included completion of installation of the bench-scale black liquor gasifier and supporting systems, preparing test plans and related safety procedures and detailed operating procedures, defining the functional design requirements and outlining the test plans for the pilot-scale gasifier, and preparing a preliminary economic assessment of the black liquor gasifier. This work accomplished under Phase 1a during this period is further described by task.

  14. Ethanol production from spent sulfite liquor fortified by hydrolysis of pulp mill primary clarifier sludge

    SciTech Connect (OSTI)

    Moritz, J.W.; Duff, S.J.B. [Univ. of British Columbia, Vancouver (Canada)

    1996-12-31T23:59:59.000Z

    Some low-yield sulfite pulping operations ferment spent sulfite liquor (SSL) to remove biochemical oxygen demand associated with dissolved sugars while at the same time generating ethanol as a salable product. Simultaneous saccharification and fermentation (SSF) of primary clarifier sludge in a medium of SSL was proposed as a means of reducing the amount of sludge to be disposed of while at the same time increasing ethanol productivity. In this article, the option of fortifying existing SSL fermenting processes with the sugars produced via in situ enzymatic hydrolysis of sulfite primary clarifier sludge (PCS) has been explored. In 100% SSL PCS hydrolysis rates as high as 3.4 g/(L{center_dot}h) were observed at an initial enzyme loading of 10 filter paper units (FPU)/g PCS. To reduce the deleterious effects of glucose inhibition, single-stage SSF was carried out using cellulose enzymes and Saccharomyces cerevisiae. The production rate of ethanol in SSL was increased by as much as 25% through the SSF process. 12 refs., 4 figs., 2 tabs.

  15. Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill

    SciTech Connect (OSTI)

    Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

    2010-01-27T23:59:59.000Z

    As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industry抯 energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also produced a comparable tensile and burst index pulps. Product gas composition determined using computer simulations The results demonstrate that RVS-1 can effectively remove > 99.8% of the H2S present in simulated synthesis gas generated from the gasification of black liquor. This level of sulfur removal was consistent over simulated synthesis gas mixtures that contained from 6 to 9.5 vol % H2S.A significant amount of the sulfur in the simulated syngas was recovered as SO2 during regeneration. The average recovery of sulfur as SO2 was about 75%. Because these are first cycle results, this sulfur recovery is expected to improve. Developed WINGems model of the process.The total decrease in variable operating costs for the BLG process compared to the HERB was in excess of $6,200,000 per year for a mill producing 350,000 tons of pulp per year. This represents a decrease in operating cost of about $17.7/ton of oven dry pulp produced. There will be additional savings in labor and maintenance cost that has not been taken into account. The capital cost for the MSSAQ based gasifier system was estimated at $164,000,000, which is comparable to a High Efficiency Recovery Boiler. The return on investment was estimated at 4%. A gasifier replacement cannot be justified on its own, however if the recovery boiler needs to be replaced the MSSAQ gasifier system shows significantly higher savings. Before black liquor based gasifer technology can be commercialized more work is necessary. The recovery of the absorbed sulfur in the absorbent as sulfur dioxide is only 75%. This needs to be greater than 90% for economical operation. It has been suggested that as the number of cycles is increased the sulfur dioxide recovery might improve. Further research is necessary. Even though a significant amount of work has been done on a pilot scale gasifiers using liquors containing sulfur, both at low and high temperatures the lack of a commercial unit is an impediment to the implementation of the MSSAQ technology. The implementation of a commercial unit needs to be facilated before the benefits of

  16. Highly Energy Efficient Directed Green Liquor Utilization (D...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping This factsheet describes a...

  17. High-solids black liquor firing in pulp and paper industry Kraft recovery boilers. Final report, Phase 1, Volume 1: Executive summary

    SciTech Connect (OSTI)

    Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

    1995-11-01T23:59:59.000Z

    This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The objectives are to develop a preliminary design of a recovery furnace simulator; evaluate the economics of high-solids; and delineate a project concept for evaluating candidate technologies to improve chemical recovery.

  18. Energy conservation in black-liquor evaporator of pulp and paper industry

    SciTech Connect (OSTI)

    Agarwal, V.K.; Gupta, S.C. [Univ. of Roorkee (India). Dept. of Chemical Engineering

    1995-12-31T23:59:59.000Z

    This paper is an attempt on energy conservation in a quintuple effect evaporator used to concentrate dilute black liquor solution by raising their steam economy through the changes in the operating variables. It also describes the steam economy of the evaporator for the various feed arrangements so as to determine the ranges of the variables for which evaporation occurs profitable.

  19. Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers

    SciTech Connect (OSTI)

    Keiser, J.R.; Hubbard, C.R.; Payzant, E.A. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01T23:59:59.000Z

    Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

  20. Kraft Liquor Corrosion Margaret Gorog

    E-Print Network [OSTI]

    Das, Suman

    1 Kraft Liquor Corrosion Margaret Gorog Federal Way, WA Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute November 2014 路 Brown Stock Corrosion 路 Alkaline Liquor Corrosion 路 Black Liquor Corrosion 颅 Evaporators 颅 Research 路 High Solids Black Liquor Corrosion of Stainless Steel

  1. Detection of estrogen- and dioxin-like activity in pulp and paper mill black liquor and effluent using in vitro bioassays

    SciTech Connect (OSTI)

    Zacharewski, T.; Berhane, K.; Gillesby, B.; Burnison, K. [Univ. of Western Ontario, London, Ontario (Canada). Dept. of Pharmacology and Toxicology; [National Water Research Inst., Burlington, Ontario (Canada). Aquatic Ecosystem Conservation Branch

    1995-12-31T23:59:59.000Z

    Pulp and paper mill effluent contains a complex mixture of compounds which adversely affect fish physiologically and at the population level. These effects include compromised reproductive fitness and the induction of mixed-function oxidase activities; two classic responses mediated by the estrogen and/or Ah receptor. In vitro recombinant receptor/reporter gene assays were used to examine pulp and paper mill black liquor and effluent for estrogenic, dioxin-like and antiestrogenic activities. Using MCF7 cells transiently transfected with a Gal4-estrogen receptor chimeric construct (Gal4-HEGO) and a Gal4-regulated luciferase reporter gene (17m5-G-Luc), it was estimated that black liquor contains 4 {+-} 2 ppb ``estrogen equivalents``, while negligible estrogenic activity was observed in a methanol-extracted pulp and paper mill effluent fraction (MF). A dioxin response element (DRE)-regulated luciferase reporter gene (pGudLucl.1) transiently transfected into Hepalclc7 wild type cells exhibited a dose-dependent increase in luciferase activity following treatment with 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDO), black liquor and MF. Based on the dose response curves, black liquor and MF contain 10 {+-} 4 ppb and 20 {+-} 6 ppt ``TCDD equivalents``, respectively. Moreover, MF exhibited significant AhR-mediated antiestrogenic activity. These results demonstrate the utility of these bioassays and suggest that the effects observed in fish exposed to pulp and paper mill effluent may be due to unidentified ER and AhR ligands not detected by conventional chemical analysis due to the lack of appropriate chemical standards.

  2. Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01T23:59:59.000Z

    that extracts lignin from black liquor with the potential todissolving in the black liquor along with lignin (Hamzeh etextracts lignin from pulp mill black liquor: LignoBoost.

  3. Black Liquor Research Program symposium: proceedings

    SciTech Connect (OSTI)

    Emerson, D.B.; Whitworth, B.A.

    1985-03-01T23:59:59.000Z

    In the paper pulp industry's recovery boilers, black liquor is sprayed in through nozzle guns near the top of the furnace. This report includes eight papers. (DLC)

  4. High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase 1 -- Final report. Volume 2: Project technical results

    SciTech Connect (OSTI)

    Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

    1995-11-01T23:59:59.000Z

    This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The principal means to this end is to construct and operate a pilot-scale recovery furnace simulator (RFS) in which these technologies can be tested. The Phase 1 objectives are to prepare a preliminary design for the RFS, delineate a project concept for evaluating candidate technologies, establish industrial partners, and report the results. Phase 1 addressed the objectives with seven tasks: Develop a preliminary design of the RFS; estimate the detailed design and construction costs of the RFS and the balance of the project; identify interested parties in the paper industry and key suppliers; plan the Phase 2 and Phase 3 tests to characterize the RFS; evaluate the economic justification for high-solids firing deployment in the industry; evaluate high-solids black liquor property data to support the RFS design; manage the project and reporting results, which included planning the future program direction.

  5. High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase Ia - Low-temperature gasifier evaluation. Final report, November 1, 1995--October 31, 1996

    SciTech Connect (OSTI)

    Southards, W.T.; Blude, J.D.; Dickinson, J.A. [and others

    1997-06-01T23:59:59.000Z

    This project, conducted under The United States Department of Energy (DOE) Cooperative Agreement DE-FC36-94GO10002/A002, was part of a multiple-phase effort to develop technologies that improve the energy efficiency and economics of chemical process recovery in the pulp and paper industry. The approach taken was to consider two major alternatives in two phases. Phase I, conducted previously, considered means to improve pulp mill recovery boilers using high-solids advanced combustion of black liquor; while this project, Phase la, considered means to recover kraft pulping mill process chemicals by low-temperature black liquor gasification. The principal steps previously proposed in this program were: (1) Evaluate these two technologies, high-solids advanced combustion and gasification, and then select a path forward using the more promising of these two options for future work. (2) Design and construct a pilot-scale unit based on the selected technology, and using that unit, develop the precompetitive data necessary to make commercialization attractive. (3) Develop and deploy a first-of-a-kind (FOAK) commercial unit in a kraft pulp mill. Phase I, which evaluated the high-solids advanced combustion option, was concluded in 1995. Results of that project phase were reported previously. This report describes the work conducted in Phase Ia. The work is described in Sections 1 through 4 and six appendices provide additional detail.

  6. alkaline black liquor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alan 1998-01-01 3 PERFORMANCE OF BLACK LIQUOR GASIFIERGAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP Renewable Energy Websites Summary: PERFORMANCE OF BLACK LIQUOR...

  7. Physical properties of Kraft Black Liquor. Interim report, Phase II

    SciTech Connect (OSTI)

    Fricke, A.L.

    1985-03-01T23:59:59.000Z

    Objectives are to determine the rheological, thermal, and surface properties of Kraft Black Liquors, and to relate these properties to the chemical composition and to pulping conditions. A four-variable, multi-level pulping experiment is being conducted. Pulping results are reported. Complete analyses of the liquors have been done. Thermal analyses have been done. DSC was employed to determine heat capacities of black liquors and lignins. Rheological (viscosity) studies are being conducted. Density and thermal expansion have been studied for seven liquors. Energy savings through more efficient recovery systems are appreciable.

  8. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    SciTech Connect (OSTI)

    Fricke, A.L.; Zaman, A.A.

    1998-05-01T23:59:59.000Z

    The overall objective of the program was to develop correlations to predict physical properties within requirements of engineering precision from a knowledge of pulping conditions and of kraft black liquor composition, if possible. These correlations were to include those relating thermodynamic properties to pulping conditions and liquor composition. The basic premise upon which the research was based is the premise that black liquor behaves as a polymer solution. This premise has proven to be true, and has been used successfully in developing data reduction methods and in interpreting results. A three phase effort involving pulping, analysis of liquor composition, and measurement of liquor properties was conducted.

  9. Kraft black liquor combustion: Advancement in fundamental understanding

    SciTech Connect (OSTI)

    Clay, D.T.

    1987-10-01T23:59:59.000Z

    Self-generated fuel streams plus purchased fossil fuel and power supply the pulp and paper industry with its energy requirements. The total industry energy use for 1986 was approximately 2.3 Quad (2300 trillion Btus). Self-generated and residue fuels accounted for 57% of the energy requirements. Spent pulping liquors provide the single largest self-generated energy source, approximately one Quad (900 trillion Btus). The pulp and paper industry also leads the nation in cogeneration performance. In 1986 eighty-nine percent (89%) of the 46 billion KWHs generated were produced by cogeneration. Spent pulping liquors supply the single largest fuel source (35%) to these cogeneration facilities. Spent pulping liquors consist of solubilized wood organics, spent inorganic chemicals, and water. Since kraft pulp dominates the North American market, 74%, kraft black liquor is the dominant spent pulping liquor. Effective recovery of high level energy and chemicals from black liquor contributes heavily toward dominance of kraft pulping. The kraft chemical recovery cycle centers around the recovery boiler. Kraft recovery boilers have been commercially available for over 50 years. The potential still exists, however, for significant improvements in energy recovery and black liquor throughput. Potential energy benefits from black liquor combustion research amount to 30 trillion Btus. Energy recovery increases often are an additional benefit from modifications made to increase black liquor throughput. Capacity increases of at least 5% are often achievable. Increased energy productivity of the kraft chemical recovery boiler will come by incorporation of improved fundamental knowledge into the technology used for boiler upgrades and new boiler construction. 5 refs., 9 figs.

  10. A comprehensive program to develop correlations for the physical properties of kraft black liquors. Interim report No.3

    SciTech Connect (OSTI)

    Fricke, A.L.; Dong, D.J.; Schmidl, G.W.; Stoy, M.A.; Zaman, A.A.

    1993-09-01T23:59:59.000Z

    The black liquor properties program has conducted a systematic collection data of properties, liquor composition, and lignin characteristics. Complete data, except for some density data, has been collected for Slash Pine black liquors made by experimental pulping at a total of 25 different pulping conditions that cover the entire range used for commercial pulping. In addition, complete data has been collected for some mill liquors and partial properties or composition data has been collected on Slash Pine black liquors made at 16 different pulping conditions and some mill liquors. Data reduction methods have been developed or extended for correlation of viscosity, heat capacity, heat of dilution, and density. Correlation of properties to pulping conditions and of composition to pulping conditions has begun. In most cases, data reduction methods have been developed that are fundamentally based and that have been shown to be generally applicable to all black liquors. While it has not proven to be possible to include research for comprehensive correlations for properties for liquors from other species, we have shown that the behavior of liquors made from other species is similar to that which has been explored extensively for Slash Pine liquors. This report reviews the methods used, describes examples of data reduction methods that have been developed, and presents some preliminary results for correlation of liquor composition and properties to pulping conditions for Slash Pine black liquors.

  11. A comprehensive program to develop correlations for the physical properties of kraft black liquors

    SciTech Connect (OSTI)

    Fricke, A.L.

    1990-12-01T23:59:59.000Z

    Experimental work includes pulping, liquor analysis, lignin purification and characterization, vapor-liquid equilibria, heat capacity, heats of solution and combustion, and viscosity measurements. It is now possible to operate the digester as a closed, rotating reactor or as a batch reactor with liquor circulation. When operated with liquor circulation, temperatures within the chip bed can be monitored during cooking. Cooking is reproducible, and cooks are being performed to produce liquors for experimental studies. The digester could be further modified to permit them to conduct rapid exchange batch pulping or to permit them to simulate continuous pulping. Liquors are now routinely analyzed to determine all components, except higher molecular weight organic acids and extractives. Lignin determination by UV-visible means has been improved. Lignin purification from black liquor has been improved and lignin molecular weights are determined routinely. The paper describes the digestor, the large scale evaporation, liquor analysis, thermal studies, and viscosity results. 31 figs., 5 tabs.

  12. Proceedings of the black liquor research program review fourth meeting held July 28--30, 1987

    SciTech Connect (OSTI)

    Emerson, D. B.; Whitworth, B. A.

    1987-10-01T23:59:59.000Z

    Research programs, presented at the black liquor review meeting are described. Research topics include the following: Cooperative Program in Kraft Recovery; Black Liquor Physical Properties; Viscosity of Strong Black Liquor; Ultrafiltration of Kraft Black Liquor; Molecular Weight Distribution of Kraft Lignin; Black Liquor Droplet Formation Project; Fundamental Studies of Black Liquor Combustion; Black Liquor Combustion Sensors; Flash X-ray Imagining of Black Liquor Sprays; Laser Induced Fluorescence For Process Control In The Pulp and Paper Industry; Recovery Boiler Optimization; Black Liquor Gasification and Use of the Products in Combined-Cycle Cogeneration; Black Liquor Steam Plasma Automization; The B and W Pyrosonic 2000R System; Monsteras Boiler Control System; and Cooperative Program Project Reviews. Individual projects are processed separately for the data bases.

  13. ITP Forest Products: Report for AIChE Pulp and Paper Industry...

    Broader source: Energy.gov (indexed) [DOE]

    Fiber from Renewable Resources Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping Energy Use Loss and Opportunities Analysis: U.S. Manufacturing & Mining...

  14. Physical properties of kraft black liquor. Final report. Phase I

    SciTech Connect (OSTI)

    Fricke, A.L.

    1983-12-01T23:59:59.000Z

    Methods were selected, equipment installed, and procedures developed for determining rheological properties; for determining thermal properties (stability, density, thermal expansion, and heat capacity); for purification and characterization of lignin (glass transition, stability, weight average molecular weight, and number average molecular weight); and for performing chemical analyses (negative inorganic ions, positive inorganic ions, acid organic salts, lignin, and total solids). A strategy for pulping to supply test liquors was developed, and a statistically designed pulping experiment was specified for a Southern softwood species. Arrangements were made for performing initial pulping work in an industrial pilot plant, and a preliminary set of pulping experiments were conducted. Liquors from the preliminary pulping experiments were used to test procedures and to determine reproducibility of the experiment. Literature was also surveyed and preliminary selection of designs for a pilot digester, and for equipment to determine surface tension were made.

  15. A comprehensive program to develop correlations for the physical properties of Kraft black liquor. Interim report No. 3

    SciTech Connect (OSTI)

    Fricke, A.L.; Dong, D.J.; Schmidl, G.W.; Stoy, M.A.; Zaman, A.A.

    1993-09-01T23:59:59.000Z

    The black liquor properties program has been conducted over this last period so as to systematically collect data on properties, liquor composition, and lignin characteristics very carefully by methods that have developed during this program. Complete data has been collected for Slash Pine black liquors made by experimental pulping at different pulping conditions. In addition, data has been collected for mill liquors and partial properties or composition data has been collected on Slash Pine black liquors. Data reduction methods have been developed or extended for correlation of viscosity, heat capacity, heat of dilution, and density. Correlation of properties to pulping conditions and of composition to. pulping conditions has begun. In most cases, data reduction methods have been developed that are fundamentally based and that have been shown to be generally applicable to all black liquors. In the near future, we fully expect to accomplish our goal of developing generalized correlations relating physical properties of Slash Pine kraft black liquors to liquor composition. This interim report reviews the methods used, describes examples of data reduction methods that have been developed, and presents some preliminary results for correlation of liquor composition and properties to pulping conditions for Slash Pine black liquors.

  16. Black liquor gasifier/gas turbine cogeneration

    SciTech Connect (OSTI)

    Consonni, S. [Politecnico di Milano (Italy). Dept. di Energetica; Larson, E.D.; Keutz, T.G. [Princeton Univ., NJ (United States); Berglin, N. [Chalmers Univ. of Technology, Goteborg (Sweden). Dept. of Heat and Power Technology

    1998-07-01T23:59:59.000Z

    The kraft process dominates pulp and paper production worldwide. Black liquor, a mixture of lignin and inorganic chemicals, is generated in this process as fiber is extracted from wood. At most kraft mills today, black liquor is burned in Tomlinson boilers to produce steam for on-site heat and power and to recover the inorganic chemicals for reuse in the process. Globally, the black liquor generation rate is about 85,000 MW{sub fuel} (or 0.5 million tonnes of dry solids per day), with nearly 50% of this in North America. The majority of presently installed Tomlinson boilers will reach the end of their useful lives during the next 5 to 20 years. As a replacement for Tomlinson-based cogeneration, black liquor-gasifier/gas turbine cogeneration promises higher electrical efficiency, with prospective environmental, safety, and capital cost benefits for kraft mills. Several companies are pursuing commercialization of black liquor gasification for gas turbine applications. This paper presents results of detailed performance modeling of gasifier/gas turbine cogeneration systems using different black liquor gasifiers modeled on proposed commercial designs.

  17. Lowering kraft black liquor viscosity of ultrafiltration

    SciTech Connect (OSTI)

    Hill, M.K.; Violette, D.A.; Woerner, D.L.

    1988-10-01T23:59:59.000Z

    High viscosity is a major factor limiting the percentage total dissolved solids (%TDS) to which kraft black liquor (KBL), a spent pulping liquor, can be concentrated before it is burned to recover its fuel value and its inorganic chemicals. The effect on black liquor viscosity of removing high molecular weight lignin by ultrafiltration of 16% and 24% TDS liquors was studied. Viscosities of ultrafiltration permeates were reduced relative to feed black liquors. When a permeate was concentrated to higher %TDS levels, its viscosity decreased yet further relative to feed samples evaporated to similar solids levels. Retentate viscosity was very high relative to both feed and permeate. Ultrafiltration was carried out at 75/degrees/C using polysulfone membranes in a plate-and-frame or hollow fiber system. Flux rates varied greatly depending upon the specific liquor used. Flux was enhanced by increased temperature and increased linear velocity. The membrane molecular weight cutoff (MWCO) typically used was 50,000; increasing 100,000 or 200,000 did not enhance flux.

  18. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    SciTech Connect (OSTI)

    Fricke, A.L.; Zaman, A.A.; Stoy, M.O.; Schmidl, G.W.; Dong, D.J.; Speck, B.

    1998-04-01T23:59:59.000Z

    A wide variety of experimental techniques have been used in this work, and many of these have been developed completely or improved significantly in the course of the research done during this program. Therefore, it is appropriate to describe these techniques in detail as a reference for future workers so that the techniques can be used in future work with little additional effort or so that the results reported from this program can be compared better with future results from other work. In many cases, the techniques described are for specific analytical instruments. It is recognized that these may be superseded by future developments and improvements in instrumentation if a complete description of techniques used successfully in the past on other instrumentation is available. The total pulping and liquor preparation research work performed included chip and white liquor preparation, digestion, pulp washing, liquor and wash recovery, liquor sampling, weak liquor concentration in two steps to about 45--50% solids with an intermediate soap skimming at about 140F and 27--30% solids, determination of pulp yield and Kappa number, determination of total liquor solids, and a check on the total material balance for pulping. All other research was performed either on a sample of the weak black liquor (the combined black liquor and washes from the digester) or on the skimmed liquor that had been concentrated.

  19. Freeze crystallization technology for black liquor concentration. Second interim report

    SciTech Connect (OSTI)

    Not Available

    1983-07-01T23:59:59.000Z

    The pulp and paper industry is one of the largest consumers of energy. Concentration of black liquor (the stream resulting from the chemical separation of wood fibers in the pulping operation) uses 25% of the purchased energy to produce pulp, an equivalent of 33 million barrels of oil in 1982. Here it is shown that freeze concentration, an emerging concentration technology, has the potential of reducing the energy consumption by at least 45%. This amounts to a cost savings of $5 to $15 per ton of pulp depending on the cost of energy, geographical location, and method of application.

  20. Vapor pressure and boiling point elevation of slash pine black liquors: Predictive models with statistical approach

    SciTech Connect (OSTI)

    Zaman, A.A.; McNally, T.W.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States)] [Univ. of Florida, Gainesville, FL (United States)

    1998-01-01T23:59:59.000Z

    Vapor-liquid equilibria and boiling point elevation of slash pine kraft black liquors over a wide range of solid concentrations (up to 85% solids) has been studied. The liquors are from a statistically designed pulping experiment for pulping slash pine in a pilot scale digester with four cooking variables of effective alkali, sulfidity, cooking time, and cooking temperature. It was found that boiling point elevation of black liquors is pressure dependent, and this dependency is more significant at higher solids concentrations. The boiling point elevation data at different solids contents (at a fixed pressure) were correlated to the dissolved solids (S/(1 {minus} S)) in black liquor. Due to the solubility limit of some of the salts in black liquor, a change in the slope of the boiling point elevation as a function of the dissolved solids was observed at a concentration of around 65% solids. An empirical method was developed to describe the boiling point elevation of each liquor as a function of pressure and solids mass fraction. The boiling point elevation of slash pine black liquors was correlated quantitatively to the pulping variables, using different statistical procedures. These predictive models can be applied to determine the boiling point rise (and boiling point) of slash pine black liquors at processing conditions from the knowledge of pulping variables. The results are presented, and their utility is discussed.

  1. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Jun Wei

    2005-03-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.3, Simulative corrosion of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1 and Task 1.2. Refractories provided by in-kind sponsors were tested by cup testing, density/porosity determinations, chemical analysis and microscopy. The best performing materials in the cup testing were fused cast materials. However, 2 castables appear to outperforming any of the previously tested materials and may perform better than the fused cast materials in operation. The basis of the high performance of these materials is the low open porosity and permeability to black liquor smelt.

  2. Recovery of solvent and by-products from organosolv black liquor

    SciTech Connect (OSTI)

    Botello, J.I.; Gilarranz, M.A.; Rodriguez, F.; Oliet, M. [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica] [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica

    1999-09-01T23:59:59.000Z

    The recovery of alcohol and by-products from ethanol-water and methanol-water pulping liquors was studied. The recovery system proposed consists of three stages: black liquor flashing, lignin precipitation, and precipitation distillation of mother liquor. At the flash stage, 47 and 51% of the alcohol in the black liquor are recovered for ethanol and methanol processes, respectively. The lignin recovery yield at the precipitation stage is 67% for ethanol black liquor and 73% for methanol black liquor. The distillation of precipitation mother liquors enables recovery of 98% ethanol and 96% methanol from this stream as distillate, whereas the distillation residue contains significant amounts of sugars, furfural, and acetic acid that can be recovered. The study concludes with the overall mass balance for the recovery system proposed.

  3. Energy considerations for steam plasma gasification of black liquor and chemical recovery

    SciTech Connect (OSTI)

    Grandy, J.D.; Kong, P.C.

    1995-10-01T23:59:59.000Z

    This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which bums the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

  4. Energy considerations for steam plasma gasification of black liquor and chemical recovery

    SciTech Connect (OSTI)

    Grandy, J.D.; Kong, P.C. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1995-07-01T23:59:59.000Z

    This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which burns the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

  5. Report on the WORKSHOP ON COMMERCIALIZATION OF BLACK LIQUOR

    E-Print Network [OSTI]

    Report on the WORKSHOP ON COMMERCIALIZATION OF BLACK LIQUOR AND BIOMASS GASIFICATION FOR GAS or industry cycle (BGCC) technologies for pulp and paper co~mitm~nt to the develo~ment of gasification systems (existing) technology with an greenhouse gas emissions mitigation measures. emerging (gasification

  6. Causticizing for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

    2009-01-07T23:59:59.000Z

    The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

  7. Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream

    DOE Patents [OSTI]

    Li, Jian (Marietta, GA); Chai, Xin Sheng (Atlanta, GA); Zhu, Junyoung (Marietta, GA)

    2008-06-24T23:59:59.000Z

    The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

  8. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Laing

    2005-10-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.4, Industrial Trial of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1, 1.2 and 1.3. Refractories provided by in-kind sponsors to industrial installations tested by cup testing, density/porosity determinations, chemical analysis and microscopy. None of the materials produced in this program have been tried in high temperature gasifiers, but the mortar developed Morcocoat SP-P is outperforming other mortars tested at ORNL. MORCO PhosGun M-90-O has shown in laboratory testing to be an acceptable candidate for hot and cold repairs of existing high temperature gasifiers. It may prove to be an acceptable lining material.

  9. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

    2004-10-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  10. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr.; Alireza Rezaie

    2003-12-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  11. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Robert E. Moore; William L. Headrick; Alireza Rezaie

    2003-03-31T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  12. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick; Musa Karakus; Alireza Rezaie

    2004-03-30T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO2 and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  13. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

    2004-07-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  14. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-10-01T23:59:59.000Z

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected/developed that either react with the gasifier environment to form protective surfaces in-situ; and were functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development were divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  15. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr.; Alireza Rezaie

    2004-04-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  16. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-04-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  17. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-07-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  18. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie; Xiaoting Liang; Musa Karakus; Jun Wei

    2005-12-01T23:59:59.000Z

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected or developed that reacted with the gasifier environment to form protective surfaces in-situ; and were functionally-graded to give the best combination of thermal, mechanical and physical properties and chemical stability; and are relatively inexpensive, reliable repair materials. Material development was divided into 2 tasks: Task 1 was development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO2 and SiC. Task 2 was finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  19. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie

    2003-12-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  20. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-01-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  1. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie

    2003-08-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  2. Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute

    E-Print Network [OSTI]

    Das, Suman

    1 Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute November 2014 Digester Corrosion Margaret Gorog Federal Way, WA 2 路 Chips plus a mixture of white and black liquor 路 The pulp is then blown from the bottom of the vessel into a blow tank 路 Corrosion occurs during filling

  3. Controlled black liquor viscosity reduction through salting-in

    SciTech Connect (OSTI)

    Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)] [North Carolina State Univ., Raleigh, NC (United States)

    1996-08-01T23:59:59.000Z

    Black liquor viscosity increases exponentially with solids content and therefore causes processing problems for the paper industry by being a limiting factor in the Kraft pulp process. This study investigates a new approach for achieving viscosity reduction by salting-in black liquor through the addition of thiocyanate salts. These salts generally increase the solubility of the polymer constituents in black liquor, leading to a decrease in its viscosity. Several thiocyanate salts capable of reducing liquor viscosity by more than two orders of magnitude have been identified, with viscosity reduction greatest at high solids content. Salting-in of black liquor depends on the cation paired with the thiocyanate anion, as well as on solution pH and temperature. Comparative studies reveal the most effective viscosity-reducing agent of the series examined and that lignin plays an important role in the viscosity behavior of both unmodified and salted-in black liquor at high solids concentrations. These experimental findings are interpreted in terms of the underlying principles that describe salting-in and how it affects aqueous solution structure.

  4. Biomass gasification project gets funding to solve black liquor safety and landfill problems

    SciTech Connect (OSTI)

    Black, N.P.

    1991-02-01T23:59:59.000Z

    This paper reports on biomass gasifications. The main by-product in pulp making is black liquor from virgin fiber; the main by-product in paper recycling is fiber residue. Although the black liquor is recycled for chemical and energy recovery, safety problems plague the boilers currently used to do this. The fiber residue is usually transported to a landfill. The system being developed by MTCI will convert black liquor and fiber residue into a combustible gas, which can then be used for a wide variety of thermal or power generation applications.

  5. Freeze crystallization technology for Kraft black liquor concentration. Third report

    SciTech Connect (OSTI)

    Johnson, W.E.; Rhodes, C.R.

    1985-04-01T23:59:59.000Z

    About 25% of the purchased energy in the pulp and paper industry is used to concentrate black liquor. The technical feasibility of using freeze concentration to supplement evaporation has been successfully demonstrated, and results indicate that energy consumption can be reduced 45%. After compiling a considerable data base on the characteristics of black liquor at low temperature and after developing a computer program to aid analysis, the process chosen was vacuum freezing-vapor absorption (VFVA). A pilot plant was built and operated; however, due to problems with crystallization of the absorbent and contamination, it was found that maintaining the conditions necessary for a continuous process was not practical at the present state of development. Therefore, indirect freezing was used for all subsequent work. This required the design and fabrication of a simple shuttle crystallizer to replace scraped surface units conventionally used. CSI also developed an integrated ice separation column that combined crystal growth, a concentration gradient, and washing all in one unit. Finally, extensive heat transfer coefficient data were collected so that a preliminary design could be completed for a 350 TPD industrial freeze concentration unit. An economic analysis was calculated in order to compare using evaporation and freeze concentration to process the increased liquor flow from a pulp mill expansion. A 200,000 lb/hr freezing unit used to preconcentrate the mill's entire stream up to 18.7% solids would save $10 to $16 per ton of pulp.

  6. Gasification of black liquor

    SciTech Connect (OSTI)

    Kohl, A.L.

    1987-07-28T23:59:59.000Z

    A process is described for treating a concentrated aqueous black liquor carbonaceous material and alkali metal sulfur compounds to form a combustible gas and a sulfide-rich melt comprising: (a) providing a gasifier vessel maintained at a pressure of from about 1 to 50 atmospheres and containing a relatively shallow molten salt pool at its bottom within a sump equipped with an overflow discharge; (b) introducing into the top of the drying zone the concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds; (c) evaporating water from the concentrated aqueous black liquor in the drying zone by direct contact of the aqueous black liquor with the hot gas rising from the gasification zone to produce dried black liquor solids; (d) introducing a first portion of an oxygen-containing gas into the gas space in the gasification zone located below the drying zone immediately above the molten salt pool to partially oxidize and gasify a fraction of the carbonaceous material in the dried black liquor solids falling through the zone to form a hot combustible gas; (e) introducing a second portion of the oxygen-containing gas beneath the surface of the molten salt pool in an amount sufficient to cause gasification of essentially all carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool; (f) withdrawing the cooled combustible gas having a higher heating value of at least about 90 Btu/scf (dry basis) from an upper portion of the drying zone; and (g) withdrawing from the overflow discharge in the molten salt reduction zone a melt in which the sulfur content is predominantly in the form of alkali metal sulfide.

  7. Ultrafiltration of kraft black liquor: Final report, Phase 3

    SciTech Connect (OSTI)

    Hill, M.K.

    1988-04-01T23:59:59.000Z

    Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work. 21 refs., 32 figs.

  8. Combustion of black liquor

    SciTech Connect (OSTI)

    Mullen, W.T.

    1989-08-15T23:59:59.000Z

    This patent describes an improvement in the combustion of black liquor in an existing Tomlison recovery boiler unit in which black liquor is sprayed into a furnace in which it is successively dried, pyrolyzed and converted to a bed of solid carbonaceous residue, using a primary air stream and a secondary air stream and the residue is subsequently converted to a smelt. The improvement comprises: the addition of between an effective amount up to 5% oxygen by volume to the primary air stream directed at the bed of solid carbonaceous residue, the amount of oxygen added being sufficient to increase the adiabatic flame temperature, the combustion rate of the solid carbonaceous material, the rate of pyrolysis, the temperature in the lower portion of the furnace, the the drying rate of black liquor droplets, and to decrease the temperature of the gases entering the heat transfer surfaces in the upper portion of the furnace and the rate of deposit formation on the surfaces and wherein the amount of black liquor combusted is increased as compared with the amount combusted in the same furnace operated without the addition of oxygen to the primary air.

  9. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, Arthur L. (Woodland Hills, CA)

    1987-07-28T23:59:59.000Z

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

  10. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, A.L.

    1987-07-28T23:59:59.000Z

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

  11. National Dioxin Study Tier 4 - combustion sources: final test report - Site 8, Black-liquor boiler BLB-C

    SciTech Connect (OSTI)

    Jamgochian, C.L.; Keller, L.E.

    1987-04-01T23:59:59.000Z

    This report summarizes the results of a dioxin/furan emissions test of a black-liquor recovery boiler equipped with a drybottom electrostatic precipitator for particulate emissions control. Black-liquor recovery boilers are used at kraft pulp mills to produce process steam and to reclaim inorganic chemicals from spent wood pulping liquors. The dioxin/furan emissions test was conducted under Tier 4 of the National Dioxin Study. The primary objective of Tier 4 is to determine if various combustion sources are sources of dioxin and/or furan emissions. If any of the combustion sources are found to emit dioxin or furan, the secondary objective of Tier 4 is to quantify these emissions. Black-liquor recovery boilers are one of 8 combustion-source categories that have been tested in the Tier 4 program. The tested black-liquor boiler, BLB-C, was selected for the test after an initial information screening and a one-day pretest survey visit. Boiler BLB-C is considered representative of black-liquor recovery boilers with dry-bottom electrostatic precipitators. The amount of chloride present in the black-liquor circuit at this site is considered intermediate to high relative to that found at other kraft pulp mills. Data presented in the report include dioxin (tetra through octa homologue +2378 TCDD) and furan (tetra through octa homologue +2378 TCDF) results for both stack samples and ash samples. In addition, process data collected during sampling are also presented.

  12. A comprehensive program to develop correlations for the physical properties of Kraft black liquor. Interim report No. 2

    SciTech Connect (OSTI)

    Fricke, A.L.

    1990-12-01T23:59:59.000Z

    Experimental effort for the program to evaluate physical properties of kraft black liquors is now proceeding well. Experimental work includes pulping, liquor analysis, lignin purification and characterization, vapor-liquid equilibria, heat capacity, heats of solution and combustion, and viscosity measurements. Measurement of thermal conductivity has not yet begun. Collection of the data necessary for development of generalized correlations is proceeding, but will require about two more years. The digester is operating very well. It is now possible to operate the digester as a closed, rotating reactor or as a batch reactor with liquor circulation. When operated with liquor circulation, temperatures within the chip bed can be monitored during cooking. Cooking is reproducible, and cooks are being performed to produce liquors for experimental studies. The digester could be further modified to permit us to conduct rapid exchange batch pulping or to permit us to simulate continuous pulping. Liquors to be used in experimental studies are concentrated in our large scale evaporator or in our small scale evaporator. The large scale evaporator is used to concentrate liquors to about 50% solids for storage and for use in studies requiring high solids liquors. The small scale evaporator is used for preparing final samples to as high as 85% solids and for measuring vapor-liquid equilibria. Liquors are now routinely analyzed to determine all components, except higher molecular weight organic acids and extractives. Lignin determination by uv-visible means has been improved. Lignin purification from black liquor has been improved and lignin molecular weights are determined routinely. Work on lignin molecular weight distribution is still not satisfactory, but recent developments holds promise.

  13. In situ analysis of ash deposits from black liquor combustion

    SciTech Connect (OSTI)

    Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

    1996-05-01T23:59:59.000Z

    Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

  14. Kraft black liquor delivery systems

    SciTech Connect (OSTI)

    Adams, T.N.; Empie, H.L.; Obuskovic, N.; Spielbauer, T.M.

    1990-02-01T23:59:59.000Z

    Improvement of spray nozzles for black liquor injection into kraft recovery furnaces is expected to result from obtaining a controlled, well-defined droplet size distribution. Work this year has centered on defining the capabilities of commercial black liquor nozzles currently in use. Considerations of the observed mechanism of droplet formation suggest a major revision is needed in the theory of how droplets form from these nozzles. High resolution, high sensitivity video has been shown to be superior to flash x-ray as a technique for measuring the droplet size distribution as well as the formation history. An environmentally sound spray facility capable of spraying black liquor at temperatures up to normal firing conditions is being constructed before data acquisition continues. Preliminary correlations have been developed between liquor properties, nozzle design, and droplet size. Three aspects of nozzle design have been investigated: droplet size distribution, fluid sheet thickness, and flow and pressure drop characteristics. The standard deviation about the median droplet size for black liquor is nearly the same as the for a wide variety of other fluids and nozzle types. Preliminary correlation for fluid sheet thickness on the plate of a splashplate nozzle show the strong similarities of black liquor to other fluids. The flow and pressure drop characteristic of black liquor nozzle, follow a simple two-term relationship similar to other flow devices. This means that in routine mill operation of black liquor nozzles only the fluid acceleration in the nozzle is important, viscous losses are quiet small. 21 refs., 53 figs., 10 tabs.

  15. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31T23:59:59.000Z

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

  16. Advanced Modeling and Materials in Kraft Pulp Mills

    SciTech Connect (OSTI)

    Keiser, J.R.; Gorog, J.P.

    2002-05-15T23:59:59.000Z

    This CRADA provided technical support to the Weyerhaeuser Company on a number of issues related to the performance and/or selection of materials at a number of locations in a pulp and paper mill. The studies related primarily to components for black liquor recovery boilers, but some effort was directed toward black liquor gasifiers and rolls for paper machines. The purpose of this CRADA was to assist Weyerhaeuser in the evaluation of materials exposed in various paper mill environments and to provide direction in the selection of alternate materials, when appropriate.

  17. Conversion of a black liquor recovery boiler to wood firing: A case history

    SciTech Connect (OSTI)

    Eleniewski, M.A. [Detroit Stoker Company, Monroe, MI (United States)

    1994-12-31T23:59:59.000Z

    In 1983 a large integrated pulp and paper mill in southeastern United States retired an older chemical recovery boiler when it was replaced by a newer and larger unit as part of a mill expansion. At that time the mill was generating steam and power using wood waste, natural gas and black liquor, a common fuel mix for pulp mills. The retirement of the recovery boiler presented an opportunity for the mill and corporate engineering to evaluate various mixes of fuels for the mill.

  18. DEMONSTRATION OF BLACK LIQUOR GASIFICATION AT BIG ISLAND

    SciTech Connect (OSTI)

    Robert DeCarrera

    2003-10-20T23:59:59.000Z

    This Technical Progress Report provides an account of the status of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific Corporation's Big Island, VA facility. The report also includes budget information and a milestone schedule. The project to be conducted by G-P is a comprehensive, complete commercial-scale demonstration that is divided into two phases. Phase I is the validation of the project scope and cost estimate. Phase II is project execution, data acquisition and reporting, and consists of procurement of major equipment, construction and start-up of the new system. Phase II also includes operation of the system for a period of time to demonstrate the safe operation and full integration of the energy and chemical recovery systems in a commercial environment. The objective of Phase I is to validate the process design and to engineer viable solutions to any technology gaps. This phase includes engineering and planning for the integration of the full-scale MTCI/StoneChem PulseEnhanced{trademark} black liquor steam-reformer chemical recovery system into G-P's operating pulp and paper mill at Big Island, Virginia. During this phase, the scope and cost estimate will be finalized to confirm the cost of the project and its integration into the existing system at the mill. The objective of Phase II of the project is the successful and safe completion of the engineering, construction and functional operation of the fully integrated full-scale steam reformer process system. This phase includes installation of all associated support systems and equipment required for the enhanced recovery of both energy and chemicals from all of the black liquor generated from the pulping process at the Big Island Mill. The objective also includes operation of the steam reformer system to demonstrate the ability of the system to operate reliably and achieve designed levels of energy and chemical recovery while maintaining environmental emissions at or below the limits set by the environmental permits.

  19. Physical properties of kraft black liquor: Summary report, Phases 1 and 2

    SciTech Connect (OSTI)

    Fricke, A.L.

    1987-09-01T23:59:59.000Z

    Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work.

  20. Modification of alkaline pulping to facilitate the isolation of aliphatic acids. Part 1. Sodium hydroxide pretreatment of pine wood

    SciTech Connect (OSTI)

    Alen, R.; Niemelae, K.; Sjoestroem, E.

    1984-01-01T23:59:59.000Z

    Pretreating pine chips (Pinus sylvestris) with sodium hydroxide prior to the alkaline delignification kraft, kraft-anthraquinone, and soda-anthraquinone) can facilitate the recovery of the carbohydrate degradation products from alkaline pulping liquors. Under suitable pretreatment conditions large amounts of carbohydrate degradation products (alipahtic acids) were formed relative to lignin. The lignin fraction was composed of comparatively low-molecular-weight fragments. Although the delignification was considerably retarded and the yield (based on wood) was decreased by 1-3%, the properties of the resulting pulp were essentially maintained despite pretreatment. Finally, data are given for the composition of aliphatic acids in liquors resulting from pretreatments.

  1. Combustion properties of Kraft Black Liquors

    SciTech Connect (OSTI)

    Frederick, W.J. Jr.; Hupa, M. (Aabo Akademi, Turku (Finland))

    1993-04-01T23:59:59.000Z

    In a previous study of the phenomena involved in the combustion of black liquor droplets a numerical model was developed. The model required certain black liquor specific combustion information which was then not currently available, and additional data were needed for evaluating the model. The overall objectives of the project reported here was to provide experimental data on key aspects of black liquor combustion, to interpret the data, and to put it into a form which would be useful for computational models for recovery boilers. The specific topics to be investigated were the volatiles and char carbon yields from pyrolysis of single black liquor droplets; a criterion for the onset of devolatilization and the accompanying rapid swelling; and the surface temperature of black liquor droplets during pyrolysis, combustion, and gasification. Additional information on the swelling characteristics of black liquor droplets was also obtained as part of the experiments conducted.

  2. Ultrafiltration of Kraft Black Liquor: Phase II, Final report

    SciTech Connect (OSTI)

    Hill, M.K.

    1987-09-01T23:59:59.000Z

    The major justification for examining ultrafiltration was to lower the viscosity of the Kraft Black Liquor by recovering it as an ultrafiltration permeate from which the highest MW lignin had been removed. The liquor could then be concentrated to a higher percentage solids before firing into the recovery boiler. Consequent energy savings for the 1000 ton/day pulp mill would be 2.05 x 10 Btu/y for each percentage increase in TDS (total dissolved solids) to the recovery boiler. This Phase II report gives data on viscosity with percentage solids of KBL permeates. Another favorable effect of ultrafiltration on the permeate properties is disproportionate removal of multivalent ions including the major scaling ion CaS . If this high-viscosity high-Ca retentate could be treated to lower its viscosity and to release the Ca in a non-scaling form, this would enhance the possibility that ultrafiltration might be useful in a mill situation. Included in this report are data on the results of treating the retentate fraction. Other justifications for this program included further information in KBL properties: lignin MW in the KBL at high pH; elemental and sugar analyses; and differential properties of lignins in the retentate and the permeate fractions. A preliminary economic analysis of ultrafiltration is contained in this report. These analyses indicate that with flux rates now attainable, ultrafiltration would not be economically justified at this time if the only justification is to lower KBL viscosity. For certain situations where high Ca liquors present a scaling problem, especially in an evaporator-limited mill, the economics are more favorable. There are also unsolved problems relating to the use of the high viscosity retentate.

  3. Magnet options for sensors for the pulp and paper industry

    SciTech Connect (OSTI)

    Green, M.A.; Barale, P.J.; Fong, C.G.; Luft, P.A.; Reimer, J.A.; Yahnke, M.S.

    2001-05-05T23:59:59.000Z

    The Lawrence Berkeley National Laboratory (LBNL) has been developing sensors for the pulp and paper industry that uses a magnetic field. The applications for magnetic sensors that have studied include (1) sensors for the measurement of the water and ice content of wood chips entering the pulping mill, (2) sensors for measuring the water content and other constituents of the black liquor leaving the paper digester, and (3) sensors for measuring paper thickness and water content as the paper is being processed. These tasks can be done using nuclear magnetic resonance (NMR). The magnetic field used for doing the NMR can come from either permanent magnets or superconducting magnets. The choice of the magnet is dependent on a number of factors, which include the size of the sample and field strength needed to do the sensing task at hand. This paper describes some superconducting magnet options that can be used in the pulp and paper industry.

  4. Coliquefaction of coal and black liquor to environmentally acceptable liquid fuels

    SciTech Connect (OSTI)

    Kim, J. [Korea Inst. of Energy Research, Taejon (Korea, Republic of); Lalvani, S.B.; Muchmore, C.B.; Akash, B.A. [Southern Illinois Univ., Carbondale, IL (United States)

    1999-11-01T23:59:59.000Z

    Previous work in the laboratories has demonstrated that addition to lignin to coal during liquefaction significantly increases the depolymerization of coal and enhances the quality of the liquid products. It is believed that thermolysis of the lignin results in the formation of phenoxyl and other reactive radicals at temperatures too low for significant thermolysis of the coal matrix; such radicals are effective and active intermediates that depolymerize coal by cleaving methylene bridges. It has been reported that alkali is also effective for extraction of liquids from coal. The work presented here combines these two reactive agents by utilizing the black liquor waste stream from the Kraft pulping process for coal depolymerization. That waste stream contains large amounts of lignin and sodium hydroxide, as well as other components. To permit comparative evaluations of the extent of coal depolymerization by coprocessing coal and black liquor, reference runs were performed with tetralin alone, sodium hydroxide in tetralin, and lignin in tetralin. Results indicated that the sodium hydroxide-tetralin system resulted in almost 67% conversion at 375 C, 1 hour. The black liquor system exhibited a lower conversion of 60%, indicating some inhibition of the depolymerization reactions by components in the black liquor.

  5. Black liquor viscosity reduction through salt additives: A novel environmentally benign processing alternative

    SciTech Connect (OSTI)

    Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)

    1996-10-01T23:59:59.000Z

    Processing black liquor at high solids would reduce SO{sub x} emissions, facilitate the use of non-chlorine bleaching techniques and enhance the energy efficiency of the pulping process. However, black liquor exhibits and exponential increase in viscosity as its solids content rises, thus hindering its processability in the composition range of interest (>70% solids). In this study, we present a new approach for controlling viscosity at high solids content by {open_quotes}salting in{close_quotes} black liquor through addition of thiocyanate salts. These salts increases the solubility of the polymer constituents in black liquor leading to a decrease in its viscosity. Several salts capable of viscosity reduction by as much as two orders of magnitude have been identified. The effects of cation size, solution pH and temperature on viscosity reduction is presented and interpreted in terms of the underlying principles of {open_quotes}salting in{close_quotes} and how it affects aqueous solution structure.

  6. Development of viscometers for kraft black liquor. Summary report, Phase 2 and 2A

    SciTech Connect (OSTI)

    Fricke, A.L.; Crisalle, O.D.

    1996-11-01T23:59:59.000Z

    This report documents the results of the evaluation of the on-line prototype viscometers for kraft black liquors carried out at the Pilot Plant facilities of the University of Florida. The original plan called for the evaluation of five prototype on-line viscometers along with laboratory bench versions. At a later stage in the project an additional experimental prototype under development at Southwest Research Institute was added. The viscometers are evaluated for accuracy and repeatability under varying process conditions, such as black liquor species, solids content, temperature, flow rate, and contaminants, as well as for maintenance and reliability. This document reports extensive results of the evaluations and recommendations for design modifications and for the installation of the instruments in industrial pulping mills for further field evaluations in Phase 3 of the project. The report also documents relevant details of the final design of the pilot flow loop used to support the experiments.

  7. Low Odor, High Yield Kraft Pulping

    SciTech Connect (OSTI)

    W.T. McKean

    2000-12-15T23:59:59.000Z

    In laboratory cooks pure oxygen was profiled into the circulation line of a batch digester during two periods of the cooking cycle: The first injection occurred during the heating steps for the purpose of in-situ generation of polysulfide. This chip treatment was studied to explore stabilization against alkaline induced carbohydrate peeling and to increase pulp yield. Under optimum conditions small amounts of polysulfide were produced with yield increase of about 0.5% These increases fell below earlier reports suggesting that unknown differences in liquor composition may influence the relative amounts of polysulfide and thiosulfate generated during the oxidation. Consequently, further studies are required to understand the factors that influence the ratios of those two sulfur species.

  8. Magnet options for sensors for the pulp and paper industry

    E-Print Network [OSTI]

    Green, M.A.

    2011-01-01T23:59:59.000Z

    constituents of the black liquor leaving the paper digester,a papermaking machine. The black liquor left over from themoisture content of the black liquor leaving the digester,

  9. Pulsed combustion process for black liquor gasification

    SciTech Connect (OSTI)

    Durai-Swamy, K.; Mansour, M.N.; Warren, D.W.

    1991-02-01T23:59:59.000Z

    The objective of this project is to test an energy efficient, innovative black liquor recovery system on an industrial scale. In the MTCI recovery process, black liquor is sprayed directly onto a bed of sodium carbonate solids which is fluidized by steam. Direct contact of the black liquor with hot bed solids promotes high rates of heating and pyrolysis. Residual carbon, which forms as a deposit on the particle surface, is then gasified by reaction with steam. Heat is supplied from pulse combustor resonance tubes which are immersed within the fluid bed. A portion of the gasifier product gas is returned to the pulse combustors to provide the energy requirements of the reactor. Oxidized sulfur species are partially reduced by reaction with the gasifier products, principally carbon monoxide and hydrogen. The reduced sulfur decomposed to solid sodium carbonate and gaseous hydrogen sulfide (H{sub 2}S). Sodium values are recovered by discharging a dry sodium carbonate product from the gasifier. MTCI's indirectly heated gasification technology for black liquor recovery also relies on the scrubbing of H{sub 2}S for product gases to regenerate green liquor for reuse in the mill circuit. Due to concerns relative to the efficiency of sulfur recovery in the MTCI integrated process, an experimental investigation was undertaken to establish performance and design data for this portion of the system.

  10. Improved recovery of tall oil from black liquors

    SciTech Connect (OSTI)

    Zucker, J.

    1980-12-09T23:59:59.000Z

    Applying a d.c. of less than 15 V to acidified black liquor separates a significant amount of tall oil remaining in the black liquor sludge. An apparatus with graphite electrodes for this process is described.

  11. Analysis of Energy-Efficiency Opportunities for the Pulp and Paper Industry in China

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01T23:59:59.000Z

    efficiently utilize black liquor and other waste biomass forbiomass is used and black liquor is converted intoRecovery Falling film black liquor evaporation Black liquor

  12. Sulfur-Free Selective Pulping

    E-Print Network [OSTI]

    Dimmel, D. R.; Bozell, J. J.

    A joint research effort is being conducted on ways to produce cost-effective pulping catalysts from lignin. This project addresses improving selectivities and reducing the levels of sulfur chemicals used in pulping. Improved selectivity means...

  13. In Situ Causticizing for Black Liquor Gasification

    SciTech Connect (OSTI)

    Scott Alan Sinquefield

    2005-10-01T23:59:59.000Z

    Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

  14. Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers

    SciTech Connect (OSTI)

    Keiser, J.R.

    2001-10-22T23:59:59.000Z

    This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

  15. Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers

    SciTech Connect (OSTI)

    Keiser, J.R.

    2000-04-18T23:59:59.000Z

    This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

  16. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 4 (Appendix IV)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 4 contains the following appendix sections: Radiative heat transfer properties for black liquor combustion -- Facilities and techniques and Spectral absorbance and emittance data; and Radiate heat transfer determination of the optical constants of ash samples from kraft recovery boilers -- Calculation procedure; Computation program; Density determination; Particle diameter determination; Optical constant data; and Uncertainty analysis.

  17. Material Characterization and Analysis for Selection of Refractories Used In Black Liquor Gasification

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Gorog, John Peter [ORNL

    2008-01-01T23:59:59.000Z

    Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials, and particularly the refractory lining of the reactor vessel, have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for this application.

  18. Material Characterization and Analysis for Selection of Refractories Used in Black Liquor Gasification

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

    2010-01-01T23:59:59.000Z

    Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials such as the refractory lining of the reactor vessel have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, an updated summary of the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for both the hot-face and back-up linings used in this application.

  19. Controlling emissions from a black liquor fluidized bed evaporator (Copeland reactor) using a regenerative thermal oxidizer and a prefilter

    SciTech Connect (OSTI)

    Grzanka, R.

    1997-12-31T23:59:59.000Z

    This paper reports on an intriguing pilot project developed to control air emissions from a pulp mill. Testing is complete, and the results show favorable emissions reductions. Stone Container Corporation, REECO, NCASI, the Ohio DEP, and the US EPA, have all worked together and approved the installation of control equipment, for VOC and HAP emissions under Presumptive MACT, setting the standard for the Copeland Reactor process in a semi chem pulp mill. The equipment, once operational, will reduce VOC and CO emissions by greater than 90%. This installation will be done at one seventh the cost of the significant process modifications required to accomplish the same emission reduction. In addition, increased process operating efficiency will be achieved with the use of an energy recovery system. The process is a black liquor fluidized bed boiler, which is used to generate sodium carbonate from the black liquor. The vapor emissions were high in VOCs, CO and particulate. After much study and testing, a wet electrostatic precipitator was chosen as the filter system for particulate control, followed by a regenerative thermal oxidizer for VOC and HAP control, finally an air-to-air heat exchanger is being used to preheat the combustion air entering the process.

  20. Preliminary feasibility study of pulping catalyst production from lignin

    SciTech Connect (OSTI)

    Power, A.J. (Power (Arthur J.) and Associates, Boulder, CO (USA)); Bozell, J.J.; Chum, H.L. (Solar Energy Research Inst., Golden, CO (USA))

    1989-11-01T23:59:59.000Z

    A preliminary evaluation of the economic feasibility of preparing anthraquinone, a pulping catalyst, from readily available lignin has been performed. The proposed process begins with a fractionation of lignin from a black liquor stream by means of a supercritical fluid or conventional solvent extraction to give a low molecular weight fraction conductive to further chemical treatment. This fraction is sequentially oxidized with H{sub 2}O{sub 2}, treated with a diene and dehydrogenated to give anthraquinone. The cost of the proposed process is most dependent on the overall yield of the chemical processing steps with a smaller contribution noted for lignin processing. The projections indicate that anthraquinone could be produced for as low as $1.00--$1.25/lb using this process. Details of the process, chemical reactions and calculations are included.

  1. Fundamental studies of black liquor combustion

    SciTech Connect (OSTI)

    Clay, D.T.; Lien, S.J.; Grace, T.M.; Brown, C.A.; Empie, H.L.; Macek, A.; Amin, N.; Charangundla, S.R.

    1990-03-01T23:59:59.000Z

    The fundamentals of black liquor combustion are being studied in a project being carried out for the US Department of Energy by the Institute of Paper Science Technology (IPST, formerly the Institute of Paper Chemistry) and the National Institute of Science Technology (NIST, formerly the National Bureau of Standards). The project was divided into four phases. This report covers the completion of Phase 1 (in-flight processes), the results of all of the work on Phase 2 (char bed processes), Phase 3 (fume processes), and Phase 4 (furnace simulation). 41 refs., 62 figs., 30 tabs.

  2. Definition:Black Liquor | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model,DOE Facility Database DataDatatechnicNewDeafDeer LodgeDeering,Black Liquor Jump

  3. BAR PACKAGES Standard Bar Package Price Liquor Beer/Wine

    E-Print Network [OSTI]

    Westneat, Mark W.

    BAR PACKAGES Standard Bar Package Price Liquor Beer/Wine 1-2 hours $21/ person Sobieski Vodka MGD 3 Select Wine Cutty Sark Scotch Cruzan Rum Premium Bar Package Price Liquor Beer/Wine 1-2 hours $24/person Beer/Wine 1-2 hours $28/person Grey Goose Vodka MGD/Miller Light 3 hours $33/person Bombay Sapphire Two

  4. Liquor Activity Reduction (LAR) Programme - 12397

    SciTech Connect (OSTI)

    Pether, Colin; Carrol, Phil; Birkett, Eddie; Kibble, Matthew [Sellafield Ltd, Cumbria (United Kingdom)

    2012-07-01T23:59:59.000Z

    Waste material from the reprocessing of irradiated fuel has been stored under water for several decades leading to the water becoming highly radioactive. As a critical enabler to the decommissioning strategy for the Sellafield site, the Liquor Activity Reduction (LAR) programme has been established to provide a processing route for this highly radioactive liquor. This paper reviews the progress that has been made since the start of routine LAR transfer cycles (July 2010) and follows on from the earlier paper presented at WM2011. The paper focuses on the learning from the first full year of routine LAR transfer cycles and the application of this learning to the wider strategies for the treatment of further radioactive liquid effluents on the Sellafield site. During this period over 100,000 Curies of radioactivity has been safely removed and treated. The past year has witnessed the very successful introduction of the LAR programme. This has lead to hazard reduction at MSSS and demonstration that the SIXEP facility can meet the significantly increased challenge that the LAR programme represents. Part of the success has been the ability to predict and deliver a realistic production schedule with the availability of the MSSS, EDT and SIXEP facilities being central to this. Most importantly, the LAR programme has been successful in bringing together key stakeholders to deliver this work while integrating with the existing, day to day, demands of the Sellafield site. (authors)

  5. Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p p a a rDepartment|Energy

  6. Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Quarterly report 3, January--March, 1997

    SciTech Connect (OSTI)

    Frederick, W.J.; Laver, M.L.; Rorrer, G.L.

    1997-05-01T23:59:59.000Z

    Progress during this quarter is described on four tasks. The first task involves the recovery of organic matter from bleach effluents and black liquors, separation of carbohydrates and lignin degradation products, analysis of functional groups, and characterization of carbohydrate polymers. Progress in the second task was made in the selection of model compounds. Several subtasks are complete in Task 3, but the paper summarizes progress made in the determination of the residual hemicellulose content in the pulp samples. Finally, results are given for the measurement of metal adsorption isotherms on wood pulp. Goals for the next quarter are listed.

  7. Magnet options for sensors for the pulp and paper industry

    E-Print Network [OSTI]

    Green, M.A.

    2011-01-01T23:59:59.000Z

    the lignin and moisture content of the black liquor leavingof lignin and other constituents was measured black liquorlignin and cellulose that are dissolved in the black liquor.

  8. Char reactions during kraft black liquor pyrolysis

    SciTech Connect (OSTI)

    Frederick, W.J.; Sricharoenchaikul, V.; Reis, V.V. [Oregon State Univ., Corvallis, OR (United States)

    1995-12-01T23:59:59.000Z

    The pyrolysis characteristics of dried black liquor particles were investigated at high heating rates in a laminar entrained-flow reactor at temperatures of 600-1100{degrees}C. Primary pyrolysis of the organic fraction occurred very rapidly, in less 0.5 seconds. Char yields at the end or volatiles evolution were 58-72%. The decreased with increasing reactor temperature to 900{degrees}C but remained constant at higher temperatures. 35-65% of the fuel nitrogen was volatilized, nearly all in less than 0.5 s. Relatively little fuel nitrogen was evolved from the char. Significant alkali metal chloride volatization from the char occurred at all temperatures, while additional sodium volatilization became important above 900{degrees}C. Reduction of sulfur species in the char increased rapidly with increasing temperature. A temperature-dependent delay time in the onset of Na{sub 2}S formation was observed.

  9. Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01T23:59:59.000Z

    54 3.5.1. Black Liquor2006. "Ultrafiltration of black liquor using rotating diskultrafiltration of Kraft black liquor using rotating disk

  10. ENERGY EFFICIENCY OPPORTUNITIES IN THE U.S. PULP AND PAPER INDUSTRY

    E-Print Network [OSTI]

    Kramer, Klaas Jan

    2010-01-01T23:59:59.000Z

    chemicals (i.e. , black liquor) [5, 9]. Electricity is usedand other operations. Black liquor is the dominant fuel forconcentration Thick black liquor Refiner Steam Electricity

  11. Opportunities to improve energy efficiency in the U.S. pulp and paper industry

    E-Print Network [OSTI]

    Worrell, Ernst; Martin, Nathan; Anglani, Norma; Einstein, Dan; Khrushch, Marta; Price, Lynn

    2001-01-01T23:59:59.000Z

    Benefit Assessment of Black Liquor Gasifier/Combined CycleRecovery Falling film black liquor evaporation Tampellafiring Falling film black liquor evaporation Enzyme-assisted

  12. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02T23:59:59.000Z

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. 搒yngas) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950癈), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.

  13. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 5: Appendix V

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  14. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 4: Appendix IV

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  15. Black Liquor Gasification Process Review and Status Update

    E-Print Network [OSTI]

    Brown, C.

    1993-01-01T23:59:59.000Z

    After more than two decades of research and development, black liquor gasification is poised to become a commercial reality in the 90's. Several promising developments are underway in North America and Europe. In fact, all major recovery boiler...

  16. Demonstration of Black Liquor Gasification at Big Island

    SciTech Connect (OSTI)

    Robert DeCarrera

    2007-04-14T23:59:59.000Z

    This Final Technical Report provides an account of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific LLC's Big Island, VA facility. This report covers the period from May 5, 2000 through November 30, 2006.

  17. Drum drying of black liquor using superheated steam impinging jets

    SciTech Connect (OSTI)

    Shiravi, A.H.; Mujumdar, A.S.; Kubes, G.J. [McGill Univ., Montreal, Quebec (Canada)

    1997-05-01T23:59:59.000Z

    A novel drum dryer for black liquor utilizing multiple impinging jets of superheated steam was designed and built to evaluate the performance characteristics and effects of various operating parameters thereon. Appropriate ranges of parameters such as steam jet temperature and velocity were examined experimentally to quantify the optimal operating conditions for the formation of black liquor film on the drum surface as well as the drying kinetics.

  18. Proceedings of the black liquor research program review fifth meeting

    SciTech Connect (OSTI)

    Not Available

    1988-09-01T23:59:59.000Z

    On June 14--17, 1988 the participants and invited guests of the Cooperative Program in Kraft Recovery gathered in Charleston, South Carolina, to review progress on four major black liquor research programs being executed at the Institute of Paper Chemistry, the University of Maine, the National Bureau of Standards, and the University of Florida. These programs include: (1) Black Liquor Properties; (2) Black Liquor Droplet Formation; (3) Black Liquor Nozzle Evaluation; and (4) Black Liquor Combustion. In addition to the objectives of previous meetings, this meeting made a direct attempt to gather ideas on how to improve our ability to move from new technology concepts to commercial implementation. Also attached is the agenda for the Charleston meeting. The first two days were involved with updates and reviews of the four major black liquor programs. A half day was spent discussing pathways to implementation and developing thoughts on what industry, DOE and academia could do to facilitate commercial implementation of the research results. This publication is a summary of the presentations made in Charleston and the industry responses to the research work. Readers are cautioned that the contents are in-progress updates on the status of the research and do not represent referred technical papers. Any questions regarding the content should be referred to the principal investigators of the project.

  19. Measurement of black liquor surface tension: Technical report No. 3. [Black liquor

    SciTech Connect (OSTI)

    Krishnagopalan, J.

    1987-09-01T23:59:59.000Z

    Surface tension and density of two kraft black liquors were measured at a series of temperatures, from a minimum value when gas bubbles can be blown into the liquor to a maximum value near the elevated boiling point of a particular sample. Available methods for the measurement of surface tension were evaluated critically and, as a result, the maximum bubble pressure method was selected. Varying the flow rate of the gas changes the frequency of bubble formation and thereby the age of the surface. The parameter has been utilized by many researchers to monitor the diffusion of low surface energy components (e.g., surfactants) to the liquid/air interface. The effect of bubble frequency when tested with a few pure liquids, indicated that the dynamics of bubble formation had to be further examined to separate out inertial and viscous effects from purely surface tension related pressure. The pressure versus flow rate data were extrapolated to zero flow rate and surface tension and density were calculated using these extrapolated values. As expected, surface tension decreased with increasing temperature for all the samples. Surface tension decreases with increasing solids content (when compared with the value for water) to a certain level (about 20%) and it starts to increase again. The decrease in surface tension in the dilute black liquor, is probably due to the decrease in the concentration of water, which has a high surface tension value. The occurrence of the minimum is probably due to the effect of inorganic components dominating over the effect of surfactants and other components. Reduction in the solubilities of the inorganics, promotion of micelles of the surfactants and reduction in the diffusion of surfactants to the surface, also could contribute to this phenomenon. 54 refs., 54 figs., 12 tabs.

  20. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 2 (Appendices I, section 5 and II, section 1)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 2 contains the last section of Appendix I, Radiative heat transfer in kraft recovery boilers, and the first section of Appendix II, The effect of temperature and residence time on the distribution of carbon, sulfur, and nitrogen between gaseous and condensed phase products from low temperature pyrolysis of kraft black liquor.

  1. Blast furnace stove control

    SciTech Connect (OSTI)

    Muske, K.R. [Villanova Univ., PA (United States). Dept. of Chemical Engineering; Hansen, G.A.; Howse, J.W.; Cagliostro, D.J. [Los Alamos National Lab., NM (United States); Chaubal, P.C. [Inland Steel Industries Inc., East Chicago, IN (United States). Research Labs.

    1998-12-31T23:59:59.000Z

    This paper outlines the process model and model-based control techniques implemented on the hot blast stoves for the No. 7 Blast Furnace at the Inland Steel facility in East Chicago, Indiana. A detailed heat transfer model of the stoves is developed. It is then used as part of a predictive control scheme to determine the minimum amount of fuel necessary to achieve the blast air requirements. The controller also considers maximum and minimum temperature constraints within the stove.

  2. Directed Relativistic Blast Wave

    E-Print Network [OSTI]

    Andrei Gruzinov

    2007-04-23T23:59:59.000Z

    A spherically symmetrical ultra-relativistic blast wave is not an attractor of a generic asymmetric explosion. Spherical symmetry is reached only by the time the blast wave slows down to non-relativistic velocities, when the Sedov-Taylor-von Neumann attractor solution sets in. We show however, that a directed relativistic explosion, with the explosion momentum close to the explosion energy, produces a blast wave with a universal intermediate asymptotic -- a selfsimilar directed ultra-relativistic blast wave. This universality might be of interest for the astrophysics of gamma-ray burst afterglows.

  3. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 1 (Main text and Appendix I, sections 1--4)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 1 contains the main body of the report and the first 4 sections of Appendix 1: Modeling of black liquor recovery boilers -- summary report; Flow and heat transfer modeling in the upper furnace of a kraft recovery boiler; Numerical simulation of black liquor combustion; and Investigation of turbulence models and prediction of swirling flows for kraft recovery furnaces.

  4. Development of an alternative kraft black liquor recovery process based on low-temperature processing in fluidized beds. Final technical report on Annex 9, Task 1

    SciTech Connect (OSTI)

    Kubes, G.J.

    1994-03-24T23:59:59.000Z

    The overall objective of this research program was to provide the fundamental knowledge and experimental data from pilot scale operation for an alternative black liquor recovery technology which would have a higher overall energy efficiency, would not suffer from the smelt-water explosion hazard and would be lower in capital cost. In addition, the alternative process would be more flexible and well suited for incremental recovery capacity or for new pulping processes, such as the new sulfide-sulfide-AQ process. The research program consists of number of specific research objectives with the aim to achieve the ultimate objective of developing an alternative recovery process which is shown in Figure 1. The specific objectives are linked to individual unit operations and they represent the following research topics: (1) superheated steam drying of kraft black liquors; (2) fast pyrolysis of black liquor; (3) hydrogen sulfide absorption from flue gas; (4) reduction of sodium sulfate in solid phase with gaseous hydrogen; and (5) verification of the fundamental results in fluidized bed pilot plant. The accomplishments in each of these objectives are described.

  5. Recaustization of kraft black liquor via bipolar electrodialysis

    SciTech Connect (OSTI)

    Koumoundouros, J.A.; Oshen, S.; Lynch, J.D.

    1990-05-01T23:59:59.000Z

    The US Department of Energy in conjunction with HPD Inc. supported a research program to perform a laboratory feasibility study with various black liquor samples for the recaustization of these samples via bipolar electrodialysis. The research was conducted at the HPD pilot plant facility in Plainfield, Illinois, beginning in April 1989. This report is a summary of the work completed thru November 1989. The program was designed to operate the electrodialyzer in order to obtain performance and engineering data such as current efficiency, power consumption per gram of NaOH produced, and assess fouling and/or membrane durability. Prior to the electrodialysis laboratory runs, the black liquor samples were pretreated in order to remove as much lignin as possible. The black liquor samples were air oxidized, acidified to pH = 9.0 and pH = 2.0 and later filtered via a Buchner funnel under vacuum. The filtrate was then utilized to become the feed to the electrodialysis stack. Initial test runs were performed with synthetic solutions of either sodium sulfate or sodium bicarbonate in order to determine acceptable operating current, power, current efficiencies, and fouling behavior. A second set of test were conducted with a series of four Southern Kraft black liquor samples. Based on the results of this study, it was determined that the use of bipolar electrodialysis for producing a caustic stream and an acidified black liquor stream is feasible and was demonstrated. 9 refs., 27 figs., 32 tabs.

  6. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 5 (Appendix V)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 5 contains model validation simulations and comparison with data.

  7. Advanced Oxidation Technology for Pulp Mill Effluent

    E-Print Network [OSTI]

    Hart, J. R.

    ADVANCED OXIDATION TECHNOLOGY FOR PULP MILL EFFLUENT J. ROBERT HART, MANAGER, EPRI PULP & PAPER OFFICE, ATLANTA, GA ABSTRACT The composition of effluent from various pulping processes can exhibit a wide range of physical and chemical... an oxidation and photolysis process. AOP FEASIBILITY STUDY The application of AOP for the treatment of pulp mill effluent was demonstrated in an EPRI Co-funded Project (1). This Project had the industrial support of about twenty companies and utilities...

  8. Black liquor gasification phase 2D final report

    SciTech Connect (OSTI)

    Kohl, A.L.; Stewart, A.E.

    1988-06-01T23:59:59.000Z

    This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

  9. Methanol-reinforced kraft pulping

    SciTech Connect (OSTI)

    Norman, E.; Olm, L.; Teder, A. (STFI, Stockholm (Sweden))

    1993-03-01T23:59:59.000Z

    The addition of methanol to a high-sulfidity kraft cook on Scandinavian softwood chips was studied under different process conditions. Delignification and the degradation of carbohydrates were accelerated, but the effect on delignification was greater. Thus, methanol addition improved selectivity. The positive effect of methanol could also be observed for modified kraft cooks having a leveled out alkali concentration and lower concentration of sodium ions and dissolved lignin at the end of the cook. Methanol addition had no discernible effect on pulp strength or on pulp bleachability.

  10. Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry

    E-Print Network [OSTI]

    Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

    2000-01-01T23:59:59.000Z

    Atlas, 1996b (? ). 揃lack Liquor gasification 朓ntroductionBerglin, N. July, 1998. Black Liquor Gasifier/Gas TurbinePreliminary Economics of Black Liquor Gasification Combined

  11. Sodium and sulfur release and recapture during black liquor burning

    SciTech Connect (OSTI)

    Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

    1995-08-01T23:59:59.000Z

    The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

  12. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 3: Appendix II, Sections 2 & 3 and Appendix III

    SciTech Connect (OSTI)

    T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  13. Alkali salt ash formation during black liquor combustion at kraft recovery boilers

    SciTech Connect (OSTI)

    Mikkanen, P. Kauppinen, E.I.; Pyykoenen, J.; Jokiniemi, J.K. [VTT (Finland); Maekinen, M. [Finnish Meterological Inst., Helsinki (Finland)

    1996-12-31T23:59:59.000Z

    Recovery boiler is an essential part of paper pulping process, where waste sludge called black liquor is burned for chemical recovery and energy production. This study was carried out at an operating industrial recovery boiler in Finland. Measurement of aerosol particles was carried out at bullnose level of furnace, at boiler exit, and at outlet of electrostatic precipitator (ESP). Aerosol mass size distributions in size range 0.02--50 {micro}m were measured with Berner type low pressure impactor (BLPI) operated with precyclone. BLPI samples were further analyzed with ion chromatography for water soluble Na, K, SO{sub 4}, and Cl. Particle morphology was studied with scanning electron microscopy (SEM). Phase composition of crystalline salts was measured with X-ray diffraction (XRD). Particles larger than 1 {micro}m were analyzed with computer controlled scanning electron microscopy (CCSEM) to derive particle composition classes. At ESP inlet mass size distribution was bimodal with a major mode at about 1.2 {micro}m and a minor mode at about 5 {micro}m (aerodynamic diameter). At ESP outlet the mass size distribution showed only one peak at about 1.2 {micro}m. Both submicron and supermicron particles were agglomerates formed from 0.3 to 0.5 {micro}m spherical primary particles. XRD analyses indicated that particles were crystalline with two phases of Na{sub 2}SO{sub 4} (thenardite and sodium sulphate) and K{sub 3}Na(SO{sub 4}){sub 2}. CCSEM results of individual particles larger than 1 {micro}m showed that 79 to 88 volume percent of particles contained mainly Na and S, 7 to 10 volume percent Na, K, and S with minor amount of particles containing Na, S, and Ca.

  14. Conceptual design of a black liquor gasification pilot plant

    SciTech Connect (OSTI)

    Kelleher, E. G.

    1987-08-01T23:59:59.000Z

    In July 1985, Champion International completed a study of kraft black liquor gasification and use of the product gases in a combined cycle cogeneration system based on gas turbines. That study indicated that gasification had high potential as an alternative to recovery boiler technology and offered many advantages. This paper describes the design of the plant, the construction of the pilot plant, and finally presents data from operation of the plant.

  15. CHEMICAL ENGINEERING Program of Study

    E-Print Network [OSTI]

    Thomas, Andrew

    reaction engineering in wood pulping and pulp bleaching, char bed modeling, black liquor gasification

  16. BIOLOGICAL ENGINEERING Program of Study

    E-Print Network [OSTI]

    Thomas, Andrew

    reaction engineering in wood pulping and pulp bleaching, char bed modeling, black liquor gasification

  17. Pulp & Paper Industry- A Strategic Energy Review

    E-Print Network [OSTI]

    Stapley, C. E.

    The pulp and paper industry with yearly energy purchases of $5 billion per year including 50 billion kWh of power is one of the largest industrial energy producers in the U.S. However, structural changes in the global pulp and paper industry could...

  18. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 3 (Appendices II, sections 2--3 and III)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 3 contains the following appendix sections: Formation and destruction of nitrogen oxides in recovery boilers; Sintering and densification of recovery boiler deposits laboratory data and a rate model; and Experimental data on rates of particulate formation during char bed burning.

  19. Ultrafiltration of Kraft Black Liquor. Final report, Phase I

    SciTech Connect (OSTI)

    Hill, M.K.

    1985-10-01T23:59:59.000Z

    Kraft Black Liquor (KBL) is ultrafiltered to favorably affect the properties of the KBL permeate. The major property to be changed is viscosity. If the high molecular weight lignin is removed by ultrafiltration, the KBL permeate should show a significant drop in viscosity. An objective of the work reported was to examine how much KBL viscosity is lowered relative to membrane and membrane pore size used in the ultrafiltration. Another objective was an initial evaluation of ultrafiltration equipment and membranes. Operating characteristics were determined for selected equipment and membranes. Decreases in KBL permeate viscosity were indeed seen. (LEW)

  20. NOvA First Blast

    SciTech Connect (OSTI)

    2009-07-22T23:59:59.000Z

    Blasting began at the future site of the NOvA detector facility near Ash River, Minnesota, on Monday, July 20.

  1. Effect of sulfidity on the corrosivity of white, green, and black liquors

    SciTech Connect (OSTI)

    Wensley, A.; Champagne, P.

    1999-07-01T23:59:59.000Z

    Corrosion testing was performed in white, green, and black liquors from a kraft mill. The liquors were modified in composition to simulate conditions of high (40%) sulfidity and low (30%) sulfidity, and then heated in laboratory autoclaves to the temperatures of the respective tanks from which the samples were taken. Specimens of carbon and stainless steels were exposed under free corrosion potential conditions, and their corrosion rates determined from weight loss measurements. In white, green, 45% solids black, and flash tank liquors, active corrosion rates for the carbon steels were typically 20 to 75% higher in the higher sulfidity liquors. In 15% solids weak black liquor there was no appreciable difference in corrosion rates, with carbon steels remaining passive in both low and high sulfidity. In 26% solids intermediate black liquor there were large increases in the corrosion rates of carbon steel between low and high sulfidity liquors, resulting from a change from passive to active conditions. Stainless steels UNS S30403, S32304, and S31803 had very low corrosion rates in all the liquors tested, regardless of sulfidity.

  2. Pulp and paper program fact sheets

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    Summaries are presented of Argonne technology transfer research projects in: sustainable forest management, environmental performance, energy performance, improved capital effectiveness, recycling, and sensors and controls. Applications in paper/pulp industry, other industries, etc. are covered.

  3. Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005

    SciTech Connect (OSTI)

    John E. Pinkerton [National Council of the Paper Industry for Air and Stream Improvement Inc., Research Triangle Park, NC (United States). Air Quality Program

    2007-08-15T23:59:59.000Z

    Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

  4. INVESTIGATION OF FUEL CHEMISTRY AND BED PERFORMANCE IN A FLUIDIZED BED BLACK LIQUOR STEAM REFORMER

    SciTech Connect (OSTI)

    Kevin Whitty

    2003-12-01T23:59:59.000Z

    The University of Utah project ''Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer'' (DOE award number DE-FC26-02NT41490) was developed in response to a solicitation for projects to provide technical support for black liquor and biomass gasification. The primary focus of the project is to provide support for a DOE-sponsored demonstration of MTCI's black liquor steam reforming technology at Georgia-Pacific's paper mill in Big Island, Virginia. A more overarching goal is to improve the understanding of phenomena that take place during low temperature black liquor gasification. This is achieved through five complementary technical tasks: (1) construction of a fluidized bed black liquor gasification test system, (2) investigation of bed performance, (3) evaluation of product gas quality, (4) black liquor conversion analysis and modeling and (5) computational modeling of the Big Island gasifier. Four experimental devices have been constructed under this project. The largest facility, which is the heart of the experimental effort, is a pressurized fluidized bed gasification test system. The system is designed to be able to reproduce conditions near the black liquor injectors in the Big Island steam reformer, so the behavior of black liquor pyrolysis and char gasification can be quantified in a representative environment. The gasification test system comprises five subsystems: steam generation and superheating, black liquor feed, fluidized bed reactor, afterburner for syngas combustion and a flue gas cooler/condenser. The three-story system is located at University of Utah's Industrial Combustion and Gasification Research Facility, and all resources there are available to support the research.

  5. HIGH PRODUCTIVITY VACUUM BLASTING SYSTEM

    SciTech Connect (OSTI)

    William S. McPhee

    1999-05-31T23:59:59.000Z

    The objective of this project is to improve the productivity and lower the expense of existing vacuum blasting technology. This technology is used to remove radioactive contamination, PCBs, and lead-based paint and provides worker protection by continuously recycling the material and dust for the decontamination tasks. The proposed work would increase the cleaning rate and provide safe and cost-effective decontamination of the DOE sites. This work focuses on redesigning and improving existing vacuum blasting technology including blast head nozzles, ergonomic handling of the blast head by reducing its weight; brush-ring design, vacuum level regulator, efficiency of the dust separator, and operational control sensors. The redesign is expected to enhance the productivity and economy of the vacuum blasting system by at least 50% over current vacuum blasting systems. There are three phases in the project. Phase I consists of developing and testing mathematical models. Phase II consists of pre-prototype design and fabrication and pre-prototype unit testing. Phase III consists of prototype design and field verification testing. In phase I, mathematical models are developed and analyzed for the nozzle, blast head, wind curtain, and dust separator, first as individual devices and then combined as an integrated model. This allows study of respective airflow and design parameters. The Contractor shall, based on the results of the mathematical modeling studies, design experimental models of the components and test these models. In addition, the Contractor shall develop sensors to detect the relationship of the blast head to the blast surfaces and controls to minimize the dependency on an operator's skill and judgment to obtain optimum positioning, as well as real-time characterization sensors to determine as the blast head is moving the depth to which coatings must be removed, thereby improving production and minimizing waste. In phase II, the Contractor shall design and construct a pre-prototype of the nozzle, blast head with wind curtain, sensors, and dust separator and test this system to assess the performance of the new design under controlled conditions at the contractor's facility. In phase III, the Contractor shall design and construct a prototype of the High Productivity Vacuum Blasting System, based on the results of the pre-prototype design and testing performed. This unit will be a full-scale prototype and will be tested at a designated Department of Energy (DOE) facility. Based on the results, the system performance, the productivity, and the economy of the improved vacuum blasting system will be evaluated.

  6. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

    2003-01-01T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  7. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30T23:59:59.000Z

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  8. Low temperature pyrolysis of black liquor and polymerization of products in alkali aqueous medium

    SciTech Connect (OSTI)

    Demirbas, A. (Dept. of Chemical Education, Karadeniz Teknik Univ., Trabzon (TR)); Ucan, H. (Dept. of Chemistry, Selcuk Univ., Konya (TR))

    1991-01-01T23:59:59.000Z

    Atmospheric pressure pyrolysis for the production of liquids and gases from black liquor and its calcium salts and acidic precipitate have been carried out in a little stainless steel tube. Yields, sum of liquid and gas products, from black liquor and its calcium salts and acidic precipitate were 44.7%, 52.0% and 59.1% of dry basis respectively. The precipitates obtained from black liquor by acidifying with hydrochloric acid and passing carbon dioxide have been polymerized in aqueous acetone containing formaldehyde and ammonia, and converted a polymeric resin.

  9. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  10. Kinetics of gasification of black liquor char by steam

    SciTech Connect (OSTI)

    Li, J.; van Heiningen, A.R.P. (Dept. of Chemical Engineering, McGill Univ., Pulp and Paper Research Inst. of Canada, Montreal, Quebec (CA))

    1991-07-01T23:59:59.000Z

    This paper reports on the steam gasification kinetics of kraft black liquor char that were studied in a thermogravimetric analysis reactor. The effect of steam and hydrogen concentration on gasification rate can be described by Langmuir-Hinshelwood type kinetics. An activation energy of 210 kJ/mol was obtained. Methane formation was negligible, and H{sub 2}S was the major gaseous sulfur-containing product obtained over the temperature range studied, 873-973 K. The CO{sub 2} concentration was higher than calculated for the water-shift reaction at equilibrium. A gasification mechanism is proposed whereby CO{sub 2} is one of the primary gasification products.

  11. Centrifugal shot blast system

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    This report describes a demonstration of Concrete cleaning, Inc., modified centrifugal shot blast technology to remove the paint coating from concrete flooring. This demonstration is part of the Chicago Pile-5 (CP-5) Large-Scale Demonstration Project (LSDP) sponsored by the US Department of Energy (DOE), office of Science and Technology (OST), Deactivation and Decommissioning Focus Area (DDFA). The objective of the LSDP is to select and demonstrate potentially beneficial technologies at the Argonne National Laboratory-East (ANL) CP-5 Research Reactor. The purpose of the LSDP is to demonstrate that using innovative and improved decontamination and decommissioning (D and D) technologies from various sources can result in significant benefits, such as decreased cost and increased health and safety, as compared with baseline D and D technologies. Potential markets exist for the innovative centrifugal shot blast system at the following sites: Fernald Environmental Management Project, Los Alamos, Nevada, Oak Ridge Y-12 and K-25, Paducah, Portsmouth Gaseous Diffusion site, and the Savannah River Site. This information is based on a revision to the OST Linkage Tables dated August 4, 1997.

  12. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 2: Appendix I, Section 5, and Appendix II, Section 1

    SciTech Connect (OSTI)

    T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  13. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 1: Main Text and Appendix I, Sections 1-4

    SciTech Connect (OSTI)

    T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  14. Swelling of kraft black liquor: an understanding of the associated phenomena during pyrolysis

    SciTech Connect (OSTI)

    Miller, P.T.

    1986-01-01T23:59:59.000Z

    The objectives of this thesis were to quantify the swelling of black liquor during pyrolysis in a nitrogen atmosphere and to determine what factors were responsible for swelling. The first part of the investigation studied the process variables: pyrolysis temperature, solid content, heating rate and particle size. A temperature of 500/sup 0/C resulted in maximum swelling for the investigated temperature range of 300-900/sup 0/C. The swelling of black liquor occurred during the evolution of pyrolysis gases; however, there was no correlation found between the amount of pyrolysis gases evolved and the change in char volume. The initial solid content of black liquor had a small influence on the swelling of black liquor. The heating rate was found to effect the rate of swelling but not the final volume. Particle size had no effect on the swollen volume per unit particle weight. The effect of black liquor composition was studied. An interaction between sugar acids and kraft lignin was responsible for swelling. The extractives interfered with the swelling mechanism of black liquor, while inorganic salts acted as a diluent. The swelling behavior of black liquor appeared to be dictated by the surface active and viscous forces present in black liquor during pyrolysis. Surface active forces were evidenced by the formation of small bubbles (50-150 microns in diameter) which appeared necessary for highly swollen chars. Low swelling chars did not exhibit this phenomenon. Bubble formation began at 250/sup 0/C, which closely corresponded to the thermal decomposition temperature of sugar acids. The sugar acids formed bubbles when pyrolyzed but did not swell significantly during pyrolysis. Kraft lignin appeared to enhance the swelling of the sugar acids by increasing the viscosity and stabilizing the bubbles during pyrolysis.

  15. Blood, rumen liquor, and fecal components as affected by dietary crude protein

    E-Print Network [OSTI]

    Hinnant, R. T

    1979-01-01T23:59:59.000Z

    BLOOD, RUMEN LIQUOR, AND FECAL COMPONENTS AS AFFECTED BY DIETARY CRUDE PROTEIN A Thesis by RAY THOMAS HINNANT Submitted to the Graduate College ot Texas A&M University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE December' 1979 Major Subject: Range Science BLOOD, RUMEN LIQUOR, AND FECAL COMPONENTS AS APFECTED BY DIETARY CRUDE PROTEIN A Thesis by RAY THOMAS HINNANT Approved as to style and content by: (Chairman of Cosssittee) (Member) ( ?) (Head...

  16. Portable convertible blast effects shield

    DOE Patents [OSTI]

    Pastrnak, John W. (Livermore, CA); Hollaway, Rocky (Modesto, CA); Henning, Carl D. (Livermore, CA); Deteresa, Steve (Livermore, CA); Grundler, Walter (Hayward, CA); Hagler, Lisle B. (Berkeley, CA); Kokko, Edwin (Dublin, CA); Switzer, Vernon A. (Livermore, CA)

    2011-03-15T23:59:59.000Z

    A rapidly deployable portable convertible blast effects shield/ballistic shield includes a set two or more frusto-conically-tapered telescoping rings operably connected to each other to convert between a telescopically-collapsed configuration for storage and transport, and a telescopically-extended upright configuration forming an expanded inner volume. In a first embodiment, the upright configuration provides blast effects shielding, such as against blast pressures, shrapnel, and/or fire balls. And in a second embodiment, the upright configuration provides ballistic shielding, such as against incoming weapons fire, shrapnel, etc. Each ring has a high-strength material construction, such as a composite fiber and matrix material, capable of substantially inhibiting blast effects and impinging projectiles from passing through the shield. And the set of rings are releasably securable to each other in the telescopically-extended upright configuration by the friction fit of adjacent pairs of frusto-conically-tapered rings to each other.

  17. Portable convertible blast effects shield

    DOE Patents [OSTI]

    Pastrnak, John W. (Livermore, CA); Hollaway, Rocky (Modesto, CA); Henning, Carl D. (Livermore, CA); Deteresa, Steve (Livermore, CA); Grundler, Walter (Hayward, CA); Hagler, Lisle B. (Berkeley, CA); Kokko, Edwin (Dublin, CA); Switzer, Vernon A (Livermore, CA)

    2007-05-22T23:59:59.000Z

    A rapidly deployable portable convertible blast effects shield/ballistic shield includes a set two or more telescoping cylindrical rings operably connected to each other to convert between a telescopically-collapsed configuration for storage and transport, and a telescopically-extended upright configuration forming an expanded inner volume. In a first embodiment, the upright configuration provides blast effects shielding, such as against blast pressures, shrapnel, and/or fire balls. And in a second embodiment, the upright configuration provides ballistic shielding, such as against incoming weapons fire, shrapnel, etc. Each ring has a high-strength material construction, such as a composite fiber and matrix material, capable of substantially inhibiting blast effects and impinging projectiles from passing through the shield. And the set of rings are releasably securable to each other in the telescopically-extended upright configuration, such as by click locks.

  18. Portable convertible blast effects shield

    DOE Patents [OSTI]

    Pastrnak, John W. (Livermore, CA); Hollaway, Rocky (Modesto, CA); Henning, Carl D. (Livermore, CA); Deteresa, Steve (Livermore, CA); Grundler, Walter (Hayward, CA); Hagler,; Lisle B. (Berkeley, CA); Kokko, Edwin (Dublin, CA); Switzer, Vernon A (Livermore, CA)

    2010-10-26T23:59:59.000Z

    A rapidly deployable portable convertible blast effects shield/ballistic shield includes a set two or more telescoping cylindrical rings operably connected to each other to convert between a telescopically-collapsed configuration for storage and transport, and a telescopically-extended upright configuration forming an expanded inner volume. In a first embodiment, the upright configuration provides blast effects shielding, such as against blast pressures, shrapnel, and/or fire balls. And in a second embodiment, the upright configuration provides ballistic shielding, such as against incoming weapons fire, shrapnel, etc. Each ring has a high-strength material construction, such as a composite fiber and matrix material, capable of substantially inhibiting blast effects and impinging projectiles from passing through the shield. And the set of rings are releasably securable to each other in the telescopically-extended upright configuration, such as by click locks.

  19. Fuel nitrogen release during black liquor pyrolysis; Part 1: Laboratory measurements at different conditions

    SciTech Connect (OSTI)

    Aho, K.; Vakkilainen, E. (A. Ahistrom Corp., Varkaus (Finland)); Hupa, M. (Abo Akademi Univ., Turku (Finland). Chemical Engineering Dept.)

    1994-05-01T23:59:59.000Z

    Fuel nitrogen release during black liquor pyrolysis is high. There is only minor release during the drying stage. Ammonia is the main fixed nitrogen species formed. The rate of fixed nitrogen release increases with increasing temperature. The level of fixed nitrogen released by birch liquor is almost twice the level for pine liquor. Assuming complete conversion to NO, fixed nitrogen yields gave NO concentrations near typically measured values for flue gases in full scale recovery boilers. The purpose of this work was to gain more detailed information about the behavior of the fuel nitrogen in black liquor combustion. The work focused on the pyrolysis or devolatilization of the combustion process. Devolatilization is the stage at which the majority (typically 50--80%) of the liquor organics release from a fuel particle or droplet as gaseous species due to the rapid destruction of the organic macromolecules in the liquor. In this paper, the authors use the terms devolatilization and pyrolysis interchangeably with no difference in their meaning.

  20. Exercise 2: Pairwise Alignment and BLAST 1. Be familiar with BLAST @NCBI.

    E-Print Network [OSTI]

    Li, Yanjun "Lisa"

    Exercise 2: Pairwise Alignment and BLAST 1. Be familiar with BLAST @NCBI. 2. Be familiar with BLAST polyprotein of 1014 amino acid residues (P10266). Use BLAST 2 Sequences to perform a pairwise alignment using, and BLOSUM80 scoring matrices. What is the effect of changing the search parameters? Then perform the same

  1. Exercise 2: Pairwise Alignment and BLAST 1. Be familiar with BLAST @NCBI.

    E-Print Network [OSTI]

    Li, Yanjun "Lisa"

    Exercise 2: Pairwise Alignment and BLAST 1. Be familiar with BLAST @NCBI. 2. Be familiar with BLAST polyprotein of 1014 amino acid residues (P10266). Use BLAST 2 Sequences to perform a pairwise alignment using scoring matrices. What is the effect of changing the search parameters? Then perform the same pairwise

  2. Effect of pulsation on black liquor gasification. Final report

    SciTech Connect (OSTI)

    Zinn, B.T.; Jagoda, J.; Jeong, H.; Kushari, A.; Rosen, L.J.

    1998-12-01T23:59:59.000Z

    Pyrolysis is an endothermic process. The heat of reaction is provided either by partial combustion of the waste or by heat transfer from an external combustion process. In one proposed system black liquor is pyrolized in a fluidized bed to which heat is added through a series of pulse combustor tail pipes submerged in the bed material. This system appears promising because of the relatively high heat transfer in pulse combustors and in fluidized beds. Other advantages of pulse combustors are discussed elsewhere. The process is, however, only economically viable if a part of the pyrolysis products can be used to fire the pulse combustors. The overall goals of this study were to determine: (1) which is the limiting heat transfer rate in the process of transferring heat from the hot combustion products to the pipe, through the pipe, from the tail pipe to the bed and through the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the heat transfer benefits of the pulse combustor can be utilized while maintaining the temperature in the bed within the narrow temperature range required by the process without generating hot spots in the bed; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

  3. Research on droplet formation for application to kraft black liquors: Final report: Tasks I and III, report No. 4

    SciTech Connect (OSTI)

    Stockel, I.H.

    1988-10-01T23:59:59.000Z

    The overall objective of this project is to generate technical data with which to design nozzles for kraft black liquor recovery boilers which can reduce under and over size droplets and adjust for changing black liquor properties and production requirements. The research is organized into five tasks: Droplet formation from a single jet, theoretical and experimental--ambient gas medium; Surface tensions of black liquor; Aerodynamic/hydrodynamic stability/instability of droplets once formed; Black liquor droplet formation from a single jet--furnace gas medium; Prototype of a new nozzle design. 88 figs.

  4. Potentials and policy implications of energy and material efficiency improvement

    E-Print Network [OSTI]

    Worrell, Ernst; Levine, Mark; Price, Lynn; Martin, Nathan; van den Broek, Richard; Block, Kornelis

    1997-01-01T23:59:59.000Z

    mechanical pulping Black liquor gasification/gasturbinefuels such as bark and black liquor, provide over 50% of the

  5. Improved Materials for High-Temperature Black Liquor Gasification

    SciTech Connect (OSTI)

    Keiser, J.R.; Hemrick, J.G.; Gorog, J.P.; Leary, R.

    2006-06-29T23:59:59.000Z

    The laboratory immersion test system built and operated at ORNL was found to successfully screen samples from numerous refractory suppliers, including both commercially available and experimental materials. This system was found to provide an accurate prediction of how these materials would perform in the actual gasifier environment. Test materials included mullites, alumino-silicate bricks, fusion-cast aluminas, alumina-based and chrome-containing mortars, phosphate-bonded mortars, coated samples provided under an MPLUS-funded project, bonded spinels, different fusion-cast magnesia-alumina spinels with magnesia content ranging from 2.5% to about 60%, high-MgO castable and brick materials, spinel castables, and alkali-aluminate materials. This testing identified several candidate material systems that perform well in the New Bern gasifier. Fusion-cast aluminas were found to survive for nearly one year, and magnesia-alumina spinels have operated successfully for 18 months and are expected to survive for two years. Alkali-aluminates and high-MgO-content materials have also been identified for backup lining applications. No other material with a similar structure and chemical composition to that of the fusion-cast magnesium-aluminum spinel brick currently being used for the hot-face lining is commercially available. Other materials used for this application have been found to have inferior service lives, as previously discussed. Further, over 100 laboratory immersion tests have been performed on other materials (both commercial and experimental), but none to date has performed as well as the material currently being used for the hot-face lining. Operating experience accumulated with the high-temperature gasifier at New Bern, North Carolina, has confirmed that the molten alkali salts degrade many types of refractories. Fusion-cast alumina materials were shown to provide a great improvement in lifetime over materials used previously. Further improvement was realized with fusion-cast magnesia-alumina spinel refractory, which appears to be the most resistant to degradation found to date, exhibiting over a year of service life and expected to be capable of over two years of service life. Regarding the use of refractory mortar, it was found that expansion of the current chrome-alumina mortar when subjected to black liquor smelt is likely contributing to the strains seen on the vessel shell. Additionally, the candidate high-alumina mortar that was originally proposed as a replacement for the current chrome-alumina mortar also showed a large amount of expansion when subjected to molten smelt. A UMR experimental mortar, composed of a phosphate bonded system specifically designed for use with fusion-cast magnesium-aluminum spinel, was found to perform well in the molten smelt environment. Strain gauges installed on the gasifier vessel shell provided valuable information about the expansion of the refractory, and a new set of strain gauges and thermocouples has been installed in order to monitor the loading caused by the currently installed spinel refractory. These results provide information for a direct comparison of the expansion of the two refractories. Measurements to date suggest that the fusion-cast magnesia-alumina spinel is expanding less than the fusion-cast {alpha}/{beta}-alumina used previously. A modified liquor nozzle was designed and constructed to test a number of materials that should be more resistant to erosion and corrosion than the material currently used. Inserts made of three erosion-resistant metallic materials were fabricated, along with inserts made of three ceramic materials. The assembled system was sent to the New Bern mill for installation in the gasifer in 2005. Following operation of the gasifier using the modified nozzle, inserts should be removed and analyzed for wear by erosion/corrosion. Although no materials have been directly identified for sensor/thermocouple protection tubes, several of the refractory material systems identified for lining material applications may be applicable for use in this

  6. Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment

    SciTech Connect (OSTI)

    Kevin Whitty

    2008-06-30T23:59:59.000Z

    The University of Utah's project 'Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment' (U.S. DOE Cooperative Agreement DE-FC26-04NT42261) was a response to U.S. DOE/NETL solicitation DE-PS36-04GO94002, 'Biomass Research and Development Initiative' Topical Area 4-Kraft Black Liquor Gasification. The project began September 30, 2004. The objective of the project was to improve the understanding of black liquor conversion in high pressure, high temperature reactors that gasify liquor through partial oxidation with either air or oxygen. The physical and chemical characteristics of both the gas and condensed phase were to be studied over the entire range of liquor conversion, and the rates and mechanisms of processes responsible for converting the liquor to its final smelt and syngas products were to be investigated. This would be accomplished by combining fundamental, lab-scale experiments with measurements taken using a new semi-pilot scale pressurized entrained-flow gasifier. As a result of insufficient availability of funds and changes in priority within the Office of Biomass Programs of the U.S. Department of Energy, the research program was terminated in its second year. In total, only half of the budgeted funding was made available for the program, and most of this was used during the first year for construction of the experimental systems to be used in the program. This had a severe impact on the program. As a consequence, most of the planned research was unable to be performed. Only studies that relied on computational modeling or existing experimental facilities started early enough to deliver useful results by the time to program was terminated Over the course of the program, small scale (approx. 1 ton/day) entrained-flow gasifier was designed and installed at the University of Utah's off-campus Industrial Combustion and Gasification Research Facility. The system is designed to operate at pressures as high as 32 atmospheres, and at temperatures as high as 1500 C (2730 F). Total black liquor processing capacity under pressurized, oxygen-blown conditions should be in excess of 1 ton black liquor solids per day. Many sampling ports along the conversion section of the system will allow detailed analysis of the environment in the gasifier under industrially representative conditions. Construction was mostly completed before the program was terminated, but resources were insufficient to operate the system. A system for characterizing black liquor sprays in hot environments was designed and constructed. Silhouettes of black liquor sprays formed by injection of black liquor through a twin fluid (liquor and atomizing air) nozzle were videoed with a high-speed camera, and the resulting images were analyzed to identify overall characteristics of the spray and droplet formation mechanisms. The efficiency of liquor atomization was better when the liquor was injected through the center channel of the nozzle, with atomizing air being introduced in the annulus around the center channel, than when the liquor and air feed channels were reversed. Atomizing efficiency and spray angle increased with atomizing air pressure up to a point, beyond which additional atomizing air pressure had little effect. Analysis of the spray patterns indicates that two classifications of droplets are present, a finely dispersed 'mist' of very small droplets and much larger ligaments of liquor that form at the injector tip and form one or more relatively large droplets. This ligament and subsequent large droplet formation suggests that it will be challenging to obtain a narrow distribution of droplet sizes when using an injector of this design. A model for simulating liquor spray and droplet formation was developed by Simulent, Inc. of Toronto. The model was able to predict performance when spraying water that closely matched the vendor specifications. Simulation of liquor spray indicates that droplets on the order 200-300 microns can be expected, and that higher liquor flow will result in be

  7. Emerging energy-efficient industrial technologies

    E-Print Network [OSTI]

    2000-01-01T23:59:59.000Z

    and P. Parthsarathy. 1999. 揃lack Liquor Gasification: AKreutz, N. Berglin. 1998. 揃lack Liquor Gasifier/Gas TurbineSystem Options with Black Liquor Gasification. In Pulp and

  8. New method of regenerating spent vacuum-carbonate sulfur removal liquor

    SciTech Connect (OSTI)

    Popov, A.A.; Dovgopol, A.P.; Goncharova, Z.S.; Belitskii, A.N,.; Gorokhov, N.N.; Grigorash, A.S.; Yaroshenko, A.K.

    1980-01-01T23:59:59.000Z

    A three-stage method is proposed for processing the ballast salts in the wash liquor from vacuum-carbonate removal of sulfur from coke-oven gas. The method is based on successive treatment of the liquor with sulfur dioxide, hydrogen sulfide and 95% sulfuric acid in the presence of hydrogen sulfide. The products of the process are thiosulfate, sulfate and elemental sulfur, at yields of 99.8%, 99.5% and 99.7% respectively. These investigations of a waste-free vacuum-carbonate method of removing hydrogen sulfide from coke-oven gas convincingly show that it is possible in principle to efficiently utilize the spent liquors both as a feedstock and as an absorbent and to obtain commercial products as a result.

  9. Formation of fuel NO[sub x] during black-liquor combustion

    SciTech Connect (OSTI)

    Nichols, K.M. (Weyerhaeuser Paper Co., Tacoma, WA (United States)); Lien, S.J. (Inst. of Paper Science and Technology, Atlanta, GA (United States))

    1993-03-01T23:59:59.000Z

    Fuel NOx and thermal NOx were measured in combustion gases from black liquors in two laboratory furnaces. Combustion at 950 C in air (8% O[sub 2]) produced NOx concentrations of 40-80ppm. Combustion at 950 C in synthetic air containing no nitrogen (21% 0[sub 2] in Ar) produced the same result, demonstrating that all of the NOx produced during combustion at 950 C was fuel NOx. Formation of fuel NOx increased moderately with increasing temperature in the range of 800-1,000 C, but temperature sensitivity of fuel NOx was much less than that of thermal NOx. The results imply that the major source of NOx in recovery furnace emissions is the fuel NOx in recovery furnace formed by conversion of liquor-bound nitrogen during combustion. This is consistent with thermal NOx theory, which postulates that black-liquor combustion temperatures are too low to generate significant amounts of thermal NOx.

  10. Research on droplet formation for application to kraft black liquors---Final project report

    SciTech Connect (OSTI)

    Bousfield, D.W.

    1990-01-01T23:59:59.000Z

    The objective of this project was to generate technical data to guide the design of new nozzles for kraft black liquor recovery boilers. The goal of new nozzle designs would be to narrow the droplet size distribution compared to current nozzles and to adjust for changing black liquor properties and production requirements. Uniform droplets in a recovery boiler should reduce fouling of superheater tubes and caused a more efficient burning of the black liquor, both of which result in improved energy efficiency. The research was organized into five tasks which are described in the next chapter. This fifth and final project report contains the details of Task 4 and 5 and further analysis of Task 1 results. The details of the other tasks are reported in previous technical reports. The major results from the entire project are highlighted in this section in order of significance.

  11. Test plan for non-radioactive testing of vertical calciner for development of direct denitration conversion of Pu-bearing liquors to stable, storage solids

    SciTech Connect (OSTI)

    Fisher, F.D.

    1995-03-30T23:59:59.000Z

    Plutonium-bearing liquors, including ANL scrap liquors, will be used for development and demonstration of a vertical calciner direct denitration process for conversion of those liquors to stable, storable PuO{sub 2}-rich solids. This test plan is to test with non-radioactive stand-in materials to demonstrate adequate performance of the vertical calciner and ancillary equipment.

  12. Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01T23:59:59.000Z

    3.6. Emerging Carbon Capture Technologies for the Pulp and3.6. Emerging Carbon Capture Technologies for the Pulp andDescription Another carbon capture technology for pulp and

  13. Optimizing Blast Furnace Operation to Increase Efficiency and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs cfdblastfurnace.pdf More...

  14. Separation of kraft lignin from kraft black liquor: Final report, July 1984-April 1987

    SciTech Connect (OSTI)

    Kurple, K.R.

    1988-04-15T23:59:59.000Z

    All the objectives were accomplished: a high-quality kraft lignin containing less than 50 ppM sodium was separated into a solvent phase (freon) from as much as 1000 lb kraft black liquor. Supporting data (infrared spectra, chemical analyses, etc.) are included. (DLC)

  15. Generator-Absorber heat exchange transfer apparatus and method using an intermediate liquor

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Zawacki, Thomas S. (St. Joseph, MI)

    1996-11-05T23:59:59.000Z

    Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium where the working solution has an intermediate liquor concentration.

  16. Assessment of the release of atomic Na from a burning black liquor droplet using quantitative PLIF

    SciTech Connect (OSTI)

    Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The Environment Institute, School of Mechanical Engineering, The University of Adelaide, SA 5005 (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The Environment Institute, School of Chemical Engineering, The University of Adelaide, SA 5005 (Australia)

    2009-07-15T23:59:59.000Z

    The quantitative measurement of atomic sodium (Na) release, at high concentration, from a burning black liquor droplet has been demonstrated using a planar laser-induced fluorescence (PLIF) technique, corrected for fluorescence trapping. The local temperature of the particle was measured to be approximately 1700 C, at a height of 10 mm above a flat flame burner. The PLIF technique was used to assess the temporal release of atomic Na from the combustion of black liquor and compare it with the Na concentration in the remaining smelt. A first-order model was made to provide insight using a simple Plug Flow Reactor model based on the independently measured concentration of residual Na in the smelt as a function of time. This model also required the dilution ratio of the combustion products in the flat flame entrained into the plume gas from the black liquor particle to be estimated. The key findings of these studies are: (i) the peak concentration of atomic Na from the combustion of the black liquor droplets is around 1.4 ppm; (ii) very little atomic Na is present during the drying, devolatilisation or char combustion stages; and (iii) the presence of atomic Na during smelt phase dominates over that from the other combustion stages. (author)

  17. Final technical report. In-situ FT-IR monitoring of a black liquor recovery boiler

    SciTech Connect (OSTI)

    James Markham; Joseph Cosgrove; David Marran; Jorge Neira; Chad Nelson; Peter Solomon

    1999-05-31T23:59:59.000Z

    This project developed and tested advanced Fourier transform infrared (FT-IR) instruments for process monitoring of black liquor recovery boilers. The state-of-the-art FT-IR instruments successfully operated in the harsh environment of a black liquor recovery boiler and provided a wealth of real-time process information. Concentrations of multiple gas species were simultaneously monitored in-situ across the combustion flow of the boiler and extractively at the stack. Sensitivity to changes of particulate fume and carryover levels in the process flow were also demonstrated. Boiler set-up and operation is a complex balance of conditions that influence the chemical and physical processes in the combustion flow. Operating parameters include black liquor flow rate, liquor temperature, nozzle pressure, primary air, secondary air, tertiary air, boiler excess oxygen and others. The in-process information provided by the FT-IR monitors can be used as a boiler control tool since species indicative of combustion efficiency (carbon monoxide, methane) and pollutant emissions (sulfur dioxide, hydrochloric acid and fume) were monitored in real-time and observed to fluctuate as operating conditions were varied. A high priority need of the U.S. industrial boiler market is improved measurement and control technology. The sensor technology demonstrated in this project is applicable to the need of industry.

  18. Microsoft Word - Blast Energy.112706.DOC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    partnership successfully tests new, less expensive drilling technology Casper, Wyo. - Nov. 28, 2006 - The Rocky Mountain Oilfield Testing Center (RMOTC) and its partner Blast...

  19. Black liquor combustion validated recovery boiler modeling, five-year report

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01T23:59:59.000Z

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  20. HIGH PRODUCTIVITY VACUUM BLASTING SYSTEM

    SciTech Connect (OSTI)

    William S. McPhee

    2001-08-31T23:59:59.000Z

    The Department of Energy (DOE) needs improved technologies to decontaminate large areas of both concrete and steel surfaces. The technology should have high operational efficiency, minimize exposures to workers, and produce low levels of secondary waste. In order to meet the DOE's needs, an applied research and development project for the improvement of a current decontamination technology, Vacuum Blasting, is proposed. The objective of this project is to improve the productivity and lower the expense of the existing vacuum blasting technology which has been widely used in DOE sites for removing radioactive contamination, PCBs, and lead-based paint. The proposed work would increase the productivity rate and provide safe and cost-effective decontamination of the DOE sites.

  1. Rebuilding of Rautaruukki blast furnaces

    SciTech Connect (OSTI)

    Kallo, S.; Pisilae, E.; Ojala, K. [Rautaruukki Oy Raahe Steel (Finland)

    1997-12-31T23:59:59.000Z

    Rautaruukki Oy Raahe Steel rebuilt its blast furnaces in 1995 (BF1) and 1996 (BF2) after 10 year campaigns and production of 9,747 THM/m{sup 3} (303 NTHM/ft{sup 3}) and 9,535 THM/m{sup 3} (297 NTHM/ft{sup 3}), respectively. At the end of the campaigns, damaged cooling system and shell cracks were increasingly disturbing the availability of furnaces. The goal for rebuilding was to improve the cooling systems and refractory quality in order to attain a 15 year campaign. The furnaces were slightly enlarged to meet the future production demand. The blast furnace control rooms and operations were centralized and the automation and instrumentation level was considerably improved in order to improve the operation efficiency and to reduce manpower requirements. Investments in direct slag granulation and improved casthouse dedusting improved environmental protection. The paper describes the rebuilding.

  2. Combustion processes in black liquor recovery: Analysis and interpretation of combustion rate data and an engineering design model

    SciTech Connect (OSTI)

    Fredrick, W.J.

    1990-03-01T23:59:59.000Z

    The overall objective of this project is to develop computational models for predicting the combustion times for black liquor droplets in a recovery furnace environment. These models are needed as an important component of large-scale, global recovery boiler models. The work is divided into two tasks: interpretation of experimental black liquor single droplet combustion data from two laboratories; and formulation and evaluation of computational models for the stages of combustion of black liquor droplets. This report contains the results of the project. 109 refs., 64 figs., 12 tabs.

  3. A Cost-Benefit Assessment of Gasification-Based Biorefining in the Kraft Pulp and Paper Industry

    SciTech Connect (OSTI)

    Eric D. Larson; Stefano Consonni; Ryan E. Katofsky; Kristiina Iisa; W. James Frederick

    2007-03-31T23:59:59.000Z

    Production of liquid fuels and chemicals via gasification of kraft black liquor and woody residues (''biorefining'') has the potential to provide significant economic returns for kraft pulp and paper mills replacing Tomlinson boilers beginning in the 2010-2015 timeframe. Commercialization of gasification technologies is anticipated in this period, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are in most cases already commercially established today in the ''gas-to-liquids'' industry. These conclusions are supported by detailed analysis carried out in a two-year project co-funded by the American Forest and Paper Association and the Biomass Program of the U.S. Department of Energy. This work assessed the energy, environment, and economic costs and benefits of biorefineries at kraft pulp and paper mills in the United States. Seven detailed biorefinery process designs were developed for a reference freesheet pulp/paper mill in the Southeastern U.S., together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. Commercial (''Nth'') plant levels of technology performance and cost were assumed. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which would be refined to vehicle fuels at existing petroleum refineries), dimethyl ether (a diesel engine fuel or LPG substitute), or an ethanol-rich mixed-alcohol product. Compared to installing a new Tomlinson power/recovery system, a biorefinery would require larger capital investment. However, because the biorefinery would have higher energy efficiencies, lower air emissions, and a more diverse product slate (including transportation fuel), the internal rates of return (IRR) on the incremental capital investments would be attractive under many circumstances. For nearly all of the cases examined in the study, the IRR lies between 14% and 18%, assuming a 25-year levelized world oil price of $50/bbl--the US Department of Energy's 2006 reference oil price projection. The IRRs would rise to as high as 35% if positive incremental environmental benefits associated with biorefinery products are monetized (e.g., if an excise tax credit for the liquid fuel is available comparable to the one that exists for ethanol in the United States today). Moreover, if future crude oil prices are higher ($78/bbl levelized price, the US Department of Energy's 2006 high oil price scenario projection, representing an extrapolation of mid-2006 price levels), the calculated IRR exceeds 45% in some cases when environmental attributes are also monetized. In addition to the economic benefits to kraft pulp/paper producers, biorefineries widely implemented at pulp mills in the U.S. would result in nationally-significant liquid fuel production levels, petroleum savings, greenhouse gas emissions reductions, and criteria-pollutant reductions. These are quantified in this study. A fully-developed pulpmill biorefinery industry could be double or more the size of the current corn-ethanol industry in the United States in terms of annual liquid fuel production. Forest biomass resources are sufficient in the United States to sustainably support such a scale of forest biorefining in addition to the projected growth in pulp and paper production.

  4. Highly concentrated foam formulation for blast mitigation

    DOE Patents [OSTI]

    Tucker, Mark D. (Albuquerque, NM); Gao, Huizhen (Albuquerque, NM)

    2010-12-14T23:59:59.000Z

    A highly concentrated foam formulation for blast suppression and dispersion mitigation for use in responding to a terrorism incident involving a radiological dispersion device. The foam formulation is more concentrated and more stable than the current blast suppression foam (AFC-380), which reduces the logistics burden on the user.

  5. BLASTING: STRICT TORT LIABILITY OR Timothy D. Stark1

    E-Print Network [OSTI]

    2002 International Society of Explosives Engineers 2002G Volume 1 - Blasting: Strict Tort Liability

  6. Determination of taurine concentration during cheddar cheese manufacture and examination of antioxidant properties of whey, permeate, mother liquor, and taurine

    E-Print Network [OSTI]

    Li, Xin

    1999-01-01T23:59:59.000Z

    Comparison of the maximum chemiluminescence value(MCV) of control, whey, permeate and mother liquor in the hemoglobin system. . 39 Comparison of the maximum chemiluminescence time(MCT) of control, whey, permeate and mother liquor in the hemoglobin system.... . 40 Effect of concentration of taurine on the MCT and MCV in the hemoglobin system. 45 LIST OF FIGURES FIGURE Page Anion exchange chromatograph of taurine and lactose in permeate . . . . . . 30 Comparative antioxidant activity of whey fractions...

  7. Fundamental Study of Black Liquor Gasification Kinetics. Quarterly progress report for the period October 1999 to December 1999

    SciTech Connect (OSTI)

    NONE

    2000-01-31T23:59:59.000Z

    The overall objective of this research is to evaluate the kinetics of gasification of kraft black liquor under laboratory conditions simulating pressurized, oxygen-blown gasification. The significant independent variables are gasifier temperature, black liquor composition particle size, and particle residence time. The authors will quantify their impact on the concentration of major and trace gas phase species, as well as the composition of condensed phase inorganic products, including specification of the Na- and S-containing compounds and overall carbon conversion.

  8. Comparison of Refractory Performance in Black Liquor Gasifiers and a Smelt Test System

    SciTech Connect (OSTI)

    Peascoe, RA

    2001-09-25T23:59:59.000Z

    Prior laboratory corrosion studies along with experience at the black liquor gasifier in New Bern, North Carolina, clearly demonstrate that serious material problems exist with the gasifier's refractory lining. Mullite-based and alumina-based refractories used at the New Bern facility suffered significant degradation even though they reportedly performed adequately in smaller scale systems. Oak Ridge National Laboratory's involvement in the failure analysis, and the initial exploration of suitable replacement materials, led to the realization that a simple and reliable, complementary method for refractory screening was needed. The development of a laboratory test system and its suitability for simulating the environment of black liquor gasifiers was undertaken. Identification and characterization of corrosion products were used to evaluate the test system as a rapid screening tool for refractory performance and as a predictor of refractory lifetime. Results from the test systems and pl ants were qualitatively similar.

  9. Methane production from ozonated pulp mill effluent

    SciTech Connect (OSTI)

    Bremmon, C.E.; Jurgensen, M.F.; Patton, J.T.

    1980-07-01T23:59:59.000Z

    A study was made of the production of methane from desugared spent sulfite liquor (SSL) reacted with ozone. The ozonated SSL was fed continuously to three anaerobic fermenters for three months as the sole source of carbon and energy. The fermenters were inoculated with anaerobic bacteria obtained from sewage sludge and acclimated for 1 month in ozonated SSL prior to continuous fermentation. Chemical and biological parameters such as COD, BOD, total sulfur content, redox potential, pH, fatty acid composition, and methane bacteria populations were monitored to determine changes in the SSL during fermentation. Methane production from ozone-treated SSL averaged 1.7 liters/ liter or 17 ml of CH/sub 4/ produced/gram of volatile solids fed. Fatty acis analysis of fermenter effluent indicated a net production of 58 mM/ liter of acetate during ozonated SSL fermentation. This acetic acid production shows future potential for further fermentation by protein-producing yeast. Although the rate of conversion of volatile solids to CH/sub 4/ in this process was not competitive with domestic or agricultural waste digesters, this study did indicate the potential benefits of ozonating organic wastes for increased methane fermentation yields.

  10. Pulsed combustion process for black liquor gasification. Second annual report, [November 1990--February 1992

    SciTech Connect (OSTI)

    Not Available

    1993-02-01T23:59:59.000Z

    This second annual report summarizes the work accomplished during the period November 1990 through February 1992 for DOE Cooperative Agreement No. DE-FC05-90CE40893. The overall project objective is to field test an energy-efficient, innovative black liquor recovery system at a significant industrial scale. This is intended to demonstrate the maturity of the technology in an industrial environment and serve as an example to the industry of the safer and more energy-efficient processing technique. The project structure is comprised of three primary activities: process characterization testing, scale-up hardware development, and field testing. The objective of the process characterization testing was to resolve key technical issues regarding the black liquor recovery process that were identified during earlier laboratory verification tests. This was intended to provide a sound engineering data base for the design, construction and testing of a nominal 1.0 TPH integrated black liquor recovery gasifier. The objective of the scale-up hardware development effort was to ensure that key hardware components, in particular the pulse heater module, would perform reliably and safely in the field. Finally, the objective of the field test is to develop an industrial data base sufficient to demonstrate the capabilities and performance of the operating system with respect to thermal efficiency, product quality, fuel handling, system control, reliability and cost. These tests are to provide long-term and continuous operating data at a capacity unattainable in the bench-scale apparatus.

  11. Fundamental studies of black liquor combustion: Report No. 2, Phase 1 (October 1984-November 1986)

    SciTech Connect (OSTI)

    Clay, D. T.; Lien, S. J.; Grace, T. M.; Macek, A.; Semerjian, H. G.; Amin, N.; Charagundla, S. R.

    1987-01-01T23:59:59.000Z

    The fundamentals of kraft black liquor combustion are being studied in a five year project. This report covers the second and third years of work by The Institute of Paper Chemistry (IPC) and the National Bureau of Standards (NBS) for the US Department of Energy. The burning processes are being studied in two continuous flow reactor systems designed to both study overall process and single particle phenomena. Black liquor burning is divided into four distinct phases: drying, volatiles burning, char burning, and smelt coalescence. Phase 1, In-flight Processes, is the main focus of this report. In-flight processes include mainly the stages of drying and volatiles burning. Testing results in both flow reactors and in two specially designed single particle reactors are presented. Dynamic droplet velocity and swelling have been measured for the first time. A direct link between initial liquor viscosity and burning behavior in the early stages has also been identified. During the fourth year Phase 1 will be completed and Phases 2 (Char Burning) and 3 (Fume Processes) will begin.

  12. Feasibility of black liquor gasification in combined cycle cogeneration. Final report, Phase I

    SciTech Connect (OSTI)

    Kelleher, E.G.

    1983-06-30T23:59:59.000Z

    A small-scale test program of 65% solids black liquor gasification was conducted in the bench-scale molten salt gasifier. Nine tests were performed using both air and oxygen as the oxidant. The black liquor gasified readily and the product gas had a dry-basis heating value of 70 Btu/scf with air and about 250 Btu/scf with oxygen. These values were almost identical to values predicted on the basis of thermodynamic equilibrium in the gas phase, indicating that the system had achieved near-equilibrium. However, the reduction of the melt to sodium sulfide was generally low. An independent research program aimed at improving the performance of air-blown black liquor gasification was conducted. That work resulted in a modified gasifier system design which increased the off-gas heating value to 120 Btu/scf and the reduction of the melt to over 95%. This was an improvement that would potentially allow use of the scrubbed product gas as a feed to a combustion gas turbine without prior enrichment.

  13. LTC vacuum blasting machine (concrete): Baseline report

    SciTech Connect (OSTI)

    NONE

    1997-07-31T23:59:59.000Z

    The LTC shot blast technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The LTC 1073 Vacuum Blasting Machine uses a high-capacity, direct-pressure blasting system which incorporates a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast. It incorporates a vacuum system which removes dust and debris from the surface as it is blasted. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure during maintenance activities was minimal, but due to mechanical difficulties dust monitoring could not be conducted during operation. Noise exposure was significant. Further testing for each of these exposures is recommended because of the outdoor environment where the testing demonstration took place. This may cause the results to be inaccurate. It is feasible that the dust and noise levels will be higher in an enclosed environment. In addition, other safety and health issues found were ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, and arm-hand vibration.

  14. Steam System Opportunity Assessment for the Pulp and Paper, Chemical...

    Broader source: Energy.gov (indexed) [DOE]

    of the U.S. Pulp and Paper Industry Energy Use Loss and Opportunities Analysis: U.S. Manufacturing & Mining U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis...

  15. Energy Management and Computers in the Pulp and Paper Industry

    E-Print Network [OSTI]

    Sommerfeld, J. T.; Hartley, E. M.

    1981-01-01T23:59:59.000Z

    dryer hood waste heat. o Biomass feedstocks for the production of specialized chemial products. o Crossing of the stone groundwood process with the thermomechanical pulping process. 236 ESL-IE-81-04-42 Proceedings from the Third Industrial Energy...

  16. MISSION INTGRE -CERTIFICATION Pulpe & Papier Plus inc. (PPP)

    E-Print Network [OSTI]

    Paris-Sud XI, Universit茅 de

    MISSION INT?GR?E - CERTIFICATION Pulpe & Papier Plus inc. (PPP) Papier propos茅 par : Richard WILSON, Strasbourg : France (2009)" #12;Pulpe & Papier Plus inc.(PPP) 1. Introduction 脿 la mission int茅gr茅e de certification PPP 1.1 Mise en contexte Cette mission int茅gr茅e de certification d茅coule de la volont茅 des membres

  17. Gas Turbine Considerations in the Pulp and Paper Industry

    E-Print Network [OSTI]

    Anderson, J. S.; Kovacik, J. M.

    GAS TURBINE CONSIDERATIONS IN THlI: PULP AND PAPER INDUSTRY J. Steven Anderson, Ph.D. Director-Energy International Paper Company Purchase, NY INTRODUCTION The pulp and paper industry is one of the largest users of energy... as an inte gral part of their power plant systems. The large requirements for process steam combined with process by-products and wood wastes make steam turbines a serious consideration in plant locations where suit able economic conditions are present...

  18. Dry Kraft Pulping at Ambient Pressure for Cost Effective Energy Saving and Pollution Deduction

    SciTech Connect (OSTI)

    Yulin Deng; Art Ragauskas

    2012-08-28T23:59:59.000Z

    Sponsored by the DOE Industrial Energy Efficiency Grand Challenge program, our research team at the Georgia Institute of Technology conducted laboratory studies and confirmed the concept of making wood pulp using a dry pulping technology. This technology is a new process different from any prior pulping technology used in Kraft and CTMP pulping. Three different kinds of dry pulping methods were investigated. (a) Dry Pulping at Atmospheric Pressure: The first one is to dry and bake the pretreated woodchips in a conventional oven at atmospheric pressure without the use of a catalyst. (b) Dry Pulping at Reduced Pressure: The second method is to dry the pretreated woodchips first in a vacuum oven in the presence of anthraquinone (AQ) as a pulping catalyst, followed by baking at elevated temperature. (c) Liquid Free Chemical Pulping, LFCP. The third method is to first remove the free water of pretreated woodchips, followed by dry pulping using a conventional Kraft pulping digester with AQ and triton as additives. Method one: Experimental results indicated that Dry Pulping at Atmospheric Pressure could produce pulp with higher brightness and lower bulk than conventional Kraft pulp. However, tensile strength of the acquired pulp is much lower than traditional Kraft pulp, and their Kappa number and energy consumption are higher than conventional Kraft pulp. By fully analyzing the results, we concluded that wood fibers might be damaged during the drying process at elevated temperature. The main reason for wood fiber damage is that a long drying time was used during evaporation of water from the woodchips. This resulted in an un-uniform reaction condition on the woodchips: the outside layer of the woodchips was over reacted while inside the woodchips did not reacted at all. To solve this problem, dry pulping at reduced pressure was investigated. Method two: To achieve uniform reaction throughout the entire reaction system, the water inside the pretreated woodchips was evaporated first under vacuum condition at low temperature. Then, the dry woodchips were baked at high temperature (120-130 C) at atmospheric pressure. The qualities of the pulp made with this method were improved compared to that made with method one. The pulp shows higher brightness and lower bulk than Kraft pulping. The tensile strength is significantly higher than the pulp made from the first method. Although the pulp is stronger than that of TMP pulp, it is still lower than conventional Kraft fiber. Method Three: The third dry method was done in a Kraft pulping digester at elevated pressure but without free liquid in the digester. With this method, pulp that has almost the same qualities as conventional Kraft pulp could be produced. The screen yield, Kappa number, fiber brightness, pulp strength and pulp bulk are almost identical to the conventional Kraft pulp. The key advantages of this dry pulping method include ca. 55 % of cooking energy saved during the pulping process, as high as 50 wt% of NaOH saving as well as 3 wt% of Na2S saving comparing to Kraft one. By analyzing fiber properties, yields, chemical and energy consumptions, we concluded that the dry pulping method based on Liquid Free Chemical Pulping, LFCP, could be very attractive for the pulp and paper industry. More fundamental studies and scale up trials are needed to fully commercialize the technology. We expect to conduct pilot trials between 12 to 24 months of period if the DOE or industry can provide continual research funding. Based on the technology we demonstrated in this report, several pilot trial facilities in the United States will be available after small modifications. For example, the Herty Foundation in Savannah, Georgia is one of these potential locations. DOE funding for continuous study and final lead to commercialization of the technique is important.

  19. Material Systems for Blast-Energy Dissipation

    SciTech Connect (OSTI)

    James Schondel; Henry S. Chu

    2010-10-01T23:59:59.000Z

    Lightweight panels have been designed to protect buildings and vehicles from blast pressures by activating energy dissipation mechanisms under the influence of blast loading. Panels were fabricated which featured a variety of granular materials and hydraulic dissipative deformation mechanisms and the test articles were subjected to full-scale blast loading. The force time-histories transmitted by each technology were measured by a novel method that utilized inexpensive custom-designed force sensors. The array of tests revealed that granular materials can effectively dissipate blast energy if they are employed in a way that they easily crush and rearrange. Similarly, hydraulic dissipation can effectively dissipate energy if the panel features a high fraction of porosity and the panel encasement features low compressive stiffness.

  20. Blast furnace supervision and control system

    SciTech Connect (OSTI)

    Remorino, M.; Lingiardi, O.; Zecchi, M. [Siderar S.A.I.C./Ingdesi, San Nicolas (Argentina)

    1997-12-31T23:59:59.000Z

    On December 1992, a group of companies headed by Techint, took over Somisa, the state-owned integrated steel plant located at San Nicolas, Province of Buenos Aires, Argentina, culminating an ambitious government privatization scheme. The blast furnace 2 went into a full reconstruction and relining in January 1995. After a 140 MU$ investment the new blast furnace 2 was started in September 1995. After more than one year of operation of the blast furnace the system has proven itself useful and reliable. The main reasons for the success of the system are: same use interface for all blast furnace areas -- operation, process, maintenance and management, (full horizontal and vertical integration); and full accessibility to all information and process tools though some restrictions apply to field commands (people empowerment). The paper describes the central system.

  1. Cumulative Probability of Blast Fragmentation Effect

    E-Print Network [OSTI]

    Oleg Mazonka

    2013-04-05T23:59:59.000Z

    This paper presents formulae for calculation of cumulative probability of effect made by blast fragments. Analysis with Mott distribution, discrete fragment enumeration, spatial non-uniformity, numerical issues, and a generalisation for a set of effects are also discussed.

  2. Cumulative Probability of Blast Fragmentation Effect

    E-Print Network [OSTI]

    Mazonka, Oleg

    2013-01-01T23:59:59.000Z

    This paper presents formulae for calculation of cumulative probability of effect made by blast fragments. Analysis with Mott distribution, discrete fragment enumeration, spatial non-uniformity, numerical issues, and a generalisation for a set of effects are also discussed.

  3. Ultra Safe And Secure Blasting System

    SciTech Connect (OSTI)

    Hart, M M

    2009-07-27T23:59:59.000Z

    The Ultra is a blasting system that is designed for special applications where the risk and consequences of unauthorized demolition or blasting are so great that the use of an extraordinarily safe and secure blasting system is justified. Such a blasting system would be connected and logically welded together through digital code-linking as part of the blasting system set-up and initialization process. The Ultra's security is so robust that it will defeat the people who designed and built the components in any attempt at unauthorized detonation. Anyone attempting to gain unauthorized control of the system by substituting components or tapping into communications lines will be thwarted in their inability to provide encrypted authentication. Authentication occurs through the use of codes that are generated by the system during initialization code-linking and the codes remain unknown to anyone, including the authorized operator. Once code-linked, a closed system has been created. The system requires all components connected as they were during initialization as well as a unique code entered by the operator for function and blasting.

  4. Effect of pulsations on black liquor gasification. Progress report, July--September 1995

    SciTech Connect (OSTI)

    Kushari, A.; Jeong, H.; Jagoda, J.I.; Zinn, B.T.

    1995-12-31T23:59:59.000Z

    The objective of this study is to investigate the use of pulse combustion to provide the energy required for the endothermic gasification of black liquor in a fluidized bed. In this process it is critical that the temperature remain in the small window above the gasification temperature but below the smelting temperature of the inorganic salts in the black liquor. Pulse combustors have been shown to have high heat transfer rates between the hot combustion products and the combustor tailpipe. Similarly, fluidized beds have high heat transfer rates within the bed itself, promoting temperature uniformity throughout. Typical analysis of the gasified black liquor shows there is a large percentage of combustible gases in the products of the gasification process (approximately 70%). The potential exists, therefore, for using this fuel mixture to fire the pulse combustor. This makes the entire process more efficient and may be necessary to make it economically feasible. The overall goals of this study are to determine (1) which is the limiting heat transfer rate in the process of transferring the heat from the hot combustion products to the pipe, through the pipe, from the tailpipe to the bed and then throughout the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the temperature distribution in the bed can be maintained within the narrow temperature range required by the process without generating hot spots in the bed even if the heat transfer from the pulse combustor is significantly increased; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

  5. Eucalyptus kraft black liquor enhances growth and productivity of Spirulina in outdoor cultures

    SciTech Connect (OSTI)

    Chauhan, V.S.; Singh, G.; Ramamurthy, V. [Thapar Institute of Engineering and Technology, Patiala (India)

    1995-07-01T23:59:59.000Z

    Mass cultivation of microalgae for commercial applications suffers from poor productivities when measured against laboratory results or theoretical projections. In an effort to reduce this gap it was discovered that addition of eucalyptus kraft black liquor (BL) enhanced biomass productivity in outdoor cultures of Spirulina by increasing growth rate by 38% and biomass yield by 43%. BL treatment resulted in elevation of nitrogen assimilating enzyme activities and efficiency of phosphate utilization. Analyses of forenoon and afternoon oxygen production rates (OPRs) indicated higher photosynthetic and respiratory activity in BL-treated cultures compared to untreated cultures. 20 refs., 1 fig., 2 tabs.

  6. Electronic nose with a new feature reduction method and a multi-linear classifier for Chinese liquor classification

    SciTech Connect (OSTI)

    Jing, Yaqi; Meng, Qinghao, E-mail: qh-meng@tju.edu.cn; Qi, Peifeng; Zeng, Ming; Li, Wei; Ma, Shugen [Tianjin Key Laboratory of Process Measurement and Control, Institute of Robotics and Autonomous Systems, School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072 (China)] [Tianjin Key Laboratory of Process Measurement and Control, Institute of Robotics and Autonomous Systems, School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072 (China)

    2014-05-15T23:59:59.000Z

    An electronic nose (e-nose) was designed to classify Chinese liquors of the same aroma style. A new method of feature reduction which combined feature selection with feature extraction was proposed. Feature selection method used 8 feature-selection algorithms based on information theory and reduced the dimension of the feature space to 41. Kernel entropy component analysis was introduced into the e-nose system as a feature extraction method and the dimension of feature space was reduced to 12. Classification of Chinese liquors was performed by using back propagation artificial neural network (BP-ANN), linear discrimination analysis (LDA), and a multi-linear classifier. The classification rate of the multi-linear classifier was 97.22%, which was higher than LDA and BP-ANN. Finally the classification of Chinese liquors according to their raw materials and geographical origins was performed using the proposed multi-linear classifier and classification rate was 98.75% and 100%, respectively.

  7. STANDARD OF CARE FOR BLASTING Timothy D. Stark1

    E-Print Network [OSTI]

    of Explosives Engineers 2003G Volume 1 - STANDARD OF CARE FOR BLASTING NEGLIGENCE 1 of 15 #12;Copyright 2003 International Society of Explosives Engineers 2003G Volume 1 - STANDARD OF CARE FOR BLASTING NEGLIGENCE 2 of 15

  8. EXPERIMENTAL STUDIES OF MITIGATION MATERIALS FOR BLAST INDUCED TBI

    E-Print Network [OSTI]

    Young, Laurence Retman

    The objective of this experimental study is to compare the effects of various materials obstructing the flow of a blast wave and the ability of the given material to reduce the damage caused by the blast. Several methods ...

  9. Computational modeling of blast-induced traumatic brain injury

    E-Print Network [OSTI]

    Nyein, Michelle K. (Michelle Kyaw)

    2010-01-01T23:59:59.000Z

    Blast-induced TBI has gained prominence in recent years due to the conflicts in Iraq and Afghanistan, yet little is known about the mechanical effects of blasts on the human head; no injury thresholds have been established ...

  10. Blast overpressure relief using air vacated buffer medium

    E-Print Network [OSTI]

    Avasarala, Srikanti Rupa

    2009-01-01T23:59:59.000Z

    Blast waves generated by intense explosions cause damage to structures and human injury. In this thesis, a strategy is investigated for relief of blast overpressure resulting from explosions in air. The strategy is based ...

  11. AZIMUTHAL VARIATION OF RADIATION OF SEISMIC ENERGY FROM CAST BLASTS

    E-Print Network [OSTI]

    and Blasting Research, International Society of Explosive Engineers, 2-5 Feb 97, Las Vegas, NV #12;AZIMUTHAL

  12. Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01T23:59:59.000Z

    of pulp mill-based integrated biorefinery with hemicellulosePilot stage Other Integrated Biorefinery Commercial statusintegrated forest biorefinery..

  13. Blast wave attenuation by lightly destructable granular materials

    E-Print Network [OSTI]

    Texas at Arlington, University of

    bombings are a dismal reality nowadays. One of the most effective ways for protection against blast to investigate the behaviour of a covering of aluminum foam under the effect of a blast wave. In our study the decrease of the blast wave attenuation coefficient with effective distance and the dependence

  14. NORTHWESTERN UNIVERSITY Crack Response to Weather Effects, Blasting, and Construction

    E-Print Network [OSTI]

    NORTHWESTERN UNIVERSITY Crack Response to Weather Effects, Blasting, and Construction Vibrations Acknowledgements iii Abstract iv List of Figures v List of Tables xi Chapter 1- Introduction 1 Chapter 2- Blast Vibration Response, Southbury, Connecticut 5 Structural Description Instrumentation Blast Response Crack

  15. An Efficient SquareRoot Algorithm for BLAST Babak Hassibi

    E-Print Network [OSTI]

    Hassibi, Babak

    antennas, BLAST first decodes the ``strongest'' signal, then cancels the effect of this strongest transmitAn Efficient Square璕oot Algorithm for BLAST Babak Hassibi Mathematics of Communications Research璗ime (BLAST) is a scheme for transmitting information over a rich璼cattering wireless environment using

  16. Dried Citrus Pulp in Beef Cattle Fattening Rations.

    E-Print Network [OSTI]

    Jones, J. M. (John McKInley)

    1942-01-01T23:59:59.000Z

    occurred in the milk during the feeding trials in question. They also observed that Florida dairymen have fed a considerable quantity of fresh citrus pulp to dairy cows and heifers and that the fermenting product tended to impart a slight flavor...- T 1 I I TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR College Station, Texas BULLETIS NO. 613 JULY 1949 DRIED CITRUS PULP IN BEEF CATTLE FATTENING RATIONS J. H. JONES, R. A. HALL E. 31. NEAL, J. H. JONES Division of Range...

  17. Method of treating contaminated HEPA filter media in pulp process

    DOE Patents [OSTI]

    Hu, Jian S.; Argyle, Mark D.; Demmer, Ricky L.; Mondok, Emilio P.

    2003-07-29T23:59:59.000Z

    A method for reducing contamination of HEPA filters with radioactive and/or hazardous materials is described. The method includes pre-processing of the filter for removing loose particles. Next, the filter medium is removed from the housing, and the housing is decontaminated. Finally, the filter medium is processed as pulp for removing contaminated particles by physical and/or chemical methods, including gravity, flotation, and dissolution of the particles. The decontaminated filter medium is then disposed of as non-RCRA waste; the particles are collected, stabilized, and disposed of according to well known methods of handling such materials; and the liquid medium in which the pulp was processed is recycled.

  18. Continuous on-line measurement of lignin concentration in wood pulp

    SciTech Connect (OSTI)

    Jeffers, L.A.; Roman, G.W.

    1994-06-01T23:59:59.000Z

    We are working toward the development of an instrument for the continuous, on-line measurement of the lignin concentration in wood pulp. The instrument is based on laser induced fluorescence of the wood pulp and is to be used as a primary sensor for both feedback control of the pulping and feedforward control of bleaching. We report here the results of a series of laboratory tests that characterized the fluorescence properties of wood pulp and demonstrated a correlation between various fluorescence functions and the Kappa number of the pulps as determined by TAPPI Procedure T236.

  19. High productivity in Australian blast furnaces

    SciTech Connect (OSTI)

    Nightingale, R.J.; Mellor, D.G. [BHP Slab and Plate Products Div., Port Kembla, New South Wales (Australia); Jelenich, L. [BHP Rod and Bar Products Div., Newcastle, New South Wales (Australia); Ward, R.F. [BHP Long Products Div., Whyalla, South Australia (Australia)

    1995-12-01T23:59:59.000Z

    Since the emergence of the Australian domestic economy from recession in 1992, the productivity of BHP`s blast furnace has increased significantly to meet the demands of both domestic and export markets. BHP Steel operates six blast furnaces at its three Australian integrated plants. These furnaces vary widely in their size, feed, technology and current campaign status. This paper reviews the principal issues associated with productivity improvements over recent years. These gains have been achieved through activities associated with a wide range of process, equipment and human resource based issues.

  20. Blast furnace control after the year 2000

    SciTech Connect (OSTI)

    Gyllenram, R.; Wikstroem, J.O. [MEFOS, Luleaa (Sweden); Hallin, M. [SSAB Tunnplaat AB, Luleaa (Sweden)

    1996-12-31T23:59:59.000Z

    Rapid technical development together with developments in work organization makes it important to investigate possible ways to achieve a cost efficient process control of different metallurgical processes. This paper describes a research project, and proposes a human oriented Information Technology Strategy, ITS, for control of the Blast Furnace process. The method used is that of deductive reasoning from a description of the prevailing technological level and experiences from various development activities. The paper is based on experiences from the No. 2 Blast Furnace at Luleaa Works but the conclusions do not at this stage necessarily reflect the opinion of the management and personnel or reflect their intentions for system development at SSAB.

  1. MOLTEN SALT CORROSION OF SUPERHEATERS IN BLACK LIQUOR RECOVERY BOILERS John Bohling, University of Tennessee Georgia Tech SURF 2010 Fellow

    E-Print Network [OSTI]

    Li, Mo

    MOLTEN SALT CORROSION OF SUPERHEATERS IN BLACK LIQUOR RECOVERY BOILERS John Bohling, University If the temperature is above the first melting point of the scale, severe corrosion of the tubes can result temperatures, reducing efficiency. The corrosive nature of the superheater environment arises primarily from

  2. Stability and Regeneration of Catalysts for the Destruction of Tars from Bio-mass Black Liquor Gasification

    SciTech Connect (OSTI)

    Pradeep Agrawal

    2004-09-07T23:59:59.000Z

    The goal of this project was to develop catalytic materials and processes that would be effective in the destruction of tars formed during the gasification of black liquor and biomass. We report here the significant results obtained at the conclusion of this two year project.

  3. Process control techniques for the Sidmar blast furnaces

    SciTech Connect (OSTI)

    Vandenberghe, D.; Bonte, L.; Nieuwerburgh, H. van [Sidmar N.V., Ghent (Belgium)

    1995-12-01T23:59:59.000Z

    The major challenge for modern blast furnace operation is the achievement of a very high productivity, excellent hot metal quality, low fuel consumption and longer blast furnace campaigns. The introduction of predictive models, decision supporting software and expert systems has reduced the standard deviation of the hot metal silicon content. The production loss due to the thermal state of the blast furnace has decreased three times since 1990. An appropriate control of the heat losses with high pulverized coal injection rates, is of the utmost importance for the life of the blast furnace. Different rules for the burden distribution of both blast furnaces are given. At blast furnace A, a peripheral gas flow is promoted, while at blast furnace B a more central gas flow is promoted.

  4. The design, implementation, and evaluation of mpiBLAST

    SciTech Connect (OSTI)

    Darling, A. E. (Aaron E.); Carey, L. (Lucas); Feng, W. C. (Wu-Chun)

    2003-01-01T23:59:59.000Z

    mpiBLAST is an open-source parallelization of BLAST that achieves superlinear speed-up by segmenting a BLAST database and then having each node in a computational cluster search a unique portion of the database. Database segmentation permits each node to search a smaller portion of the database, eliminating disk I/O and vastly improving BLAST performance. Because database segmentation does not create heavy communication demands, BLAST users can take advantage of low-cost and efficient Linux cluster architectures such as the bladed Beowulf. In addition to presenting the software architecture of mpiBLAST we present a detailed performance analysis of mpiBLAST to demonstrate its scalability.

  5. Assessment of Gasification-Based Biorefining at Kraft Pulp and Paper Mills in the United States, Part A: Background and Assumptions

    SciTech Connect (OSTI)

    Larson, E. D.; Consonni, S.; Katofsky, R. E.; Iisa, K.; Frederick, W. J., Jr.

    2008-11-01T23:59:59.000Z

    Commercialization of black liquor and biomass gasification technologies is anticipated in the 2010-2015 time frame, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are already commercially established in the gas-to-liquids or coal-to-liquids industries. This set of two papers describes key results from a major assessment of the prospective energy, environmental, and financial performance of commercial gasification-based biorefineries integrated with kraft pulp and paper mills [1]. Seven detailed biorefinery designs were developed for a reference mill in the southeastern United States, together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which could be refined to vehicle fuels at an existing petroleum refinery), dimethyl ether (a diesel engine fuel or propane substitute), or an ethanol-rich mixed-alcohol product. This paper describes the key assumptions that underlie the biorefinery designs. Part B will present analytical results.

  6. Distinguishing Realistic Military Blasts from Firecrackers in Mitigation Studies of Blast Induced Traumatic Brain Injury

    SciTech Connect (OSTI)

    Moss, W C; King, M J; Blackman, E G

    2011-01-21T23:59:59.000Z

    In their Contributed Article, Nyein et al. (1,2) present numerical simulations of blast waves interacting with a helmeted head and conclude that a face shield may significantly mitigate blast induced traumatic brain injury (TBI). A face shield may indeed be important for future military helmets, but the authors derive their conclusions from a much smaller explosion than typically experienced on the battlefield. The blast from the 3.16 gm TNT charge of (1) has the following approximate peak overpressures, positive phase durations, and incident impulses (3): 10 atm, 0.25 ms, and 3.9 psi-ms at the front of the head (14 cm from charge), and 1.4 atm, 0.32 ms, and 1.7 psi-ms at the back of a typical 20 cm head (34 cm from charge). The peak pressure of the wave decreases by a factor of 7 as it traverses the head. The blast conditions are at the threshold for injury at the front of the head, but well below threshold at the back of the head (4). The blast traverses the head in 0.3 ms, roughly equal to the positive phase duration of the blast. Therefore, when the blast reaches the back of the head, near ambient conditions exist at the front. Because the headform is so close to the charge, it experiences a wave with significant curvature. By contrast, a realistic blast from a 2.2 kg TNT charge ({approx} an uncased 105 mm artillery round) is fatal at an overpressure of 10 atm (4). For an injury level (4) similar to (1), a 2.2 kg charge has the following approximate peak overpressures, positive phase durations, and incident impulses (3): 2.1 atm, 2.3 ms, and 18 psi-ms at the front of the head (250 cm from charge), and 1.8 atm, 2.5 ms, and 16.8 psi-ms at the back of the head (270 cm from charge). The peak pressure decreases by only a factor of 1.2 as it traverses the head. Because the 0.36 ms traversal time is much smaller than the positive phase duration, pressures on the head become relatively uniform when the blast reaches the back of the head. The larger standoff implies that the headform locally experiences a nearly planar blast wave. Also, the positive phase durations and blast impulses are much larger than those of (1). Consequently, the blast model used in (1) is spatially and temporally very different from a military blast. It would be useful to repeat the calculations using military blast parameters. Finally, (1) overlooks a significant part of (5). On page 1 and on page 3, (1) states that (5) did not consider helmet pads. But pages pages 3 and 4 of (5) present simulations of blast wave propagation across an ACH helmeted head form with and without pads. (5) states that when the pads are present, the 'underwash' of air under the helmet is blocked when compared to the case without. (1) reaches this same conclusion, but reports it as a new result rather than a confirmation of that already found in (5).

  7. Refractory Testing and Evaluation at Oak Ridge National Laboratory for Black Liquor Gasifier Applications.

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Hubbard, Camden R [ORNL; Lara-Curzio, Edgar [ORNL

    2006-01-01T23:59:59.000Z

    Work is on-going at Oak Ridge National Laboratory to evaluate refractory containment and smelt contact materials for black liquor gasification applications. Materials have been evaluated and selected for low temperature gasification processes, with a number of materials being installed in commercial units currently under construction. For high temperature low pressure gasification processes, efforts have focused on screening candidate lining materials through immersion testing, improving existing refractory performance through the application of surface treatments, and the installation and evaluation of samples in an operating gasifier in New Bern, NC. Efforts concerning high temperature high pressure gasification have involved the identification and testing of suitable refractory materials for the coating of a helical carbon steel cooling coil arrangment.

  8. Separation of kraft lignin from kraft black liquor: Final report, July 1984-April 1987

    SciTech Connect (OSTI)

    Kurple, K.R.

    1988-04-15T23:59:59.000Z

    The importance of this work is related to the fact that with over 16 million tons of kraft lignin available annually, practically all of it is burned just for its heat value. In essence, kraft lignin has no real value except its heat value. The major accomplishments of this research has shown that it is possible to produce high purity kraft lignin from kraft black liquor. This patented technology represents a way of producing a material that can be utilized in a wide variety of markets. Kraft lignin that was produced using this technology was sent to major corporations who used this kraft lignin as a starting material in their chemical processes. 3 figs.

  9. Cracking and Corrosion of Composite Tubes in Black Liquor Recovery Boiler Primary Air Ports

    SciTech Connect (OSTI)

    Keiser, James R.; Singbeil, Douglas L.; Sarma, Gorti B.; Kish, Joseph R.; Yuan, Jerry; Frederick, Laurie A.; Choudhury, Kimberly A.; Gorog, J. Peter; Jett, Francois R.; Hubbard, Camden R.; Swindeman, Robert W.; Singh, Prett M.; Maziasz, Phillip J.

    2006-10-01T23:59:59.000Z

    Black liquor recovery boilers are an essential part of kraft mills. Their design and operating procedures have changed over time with the goal of providing improved boiler performance. These performance improvements are frequently associated with an increase in heat flux and/or operating temperature with a subsequent increase in the demand on structural materials associated with operation at higher temperatures and/or in more corrosive environments. Improvements in structural materials have therefore been required. In most cases the alternate materials have provided acceptable solutions. However, in some cases the alternate materials have solved the original problem but introduced new issues. This report addresses the performance of materials in the tubes forming primary air port openings and, particularly, the problems associated with use of stainless steel clad carbon steel tubes and the solutions that have been identified.

  10. Waste Growth Challenges Local Democracy. The Politics of Waste between Europe and the Mediterranean: a Focus on Italy

    E-Print Network [OSTI]

    Mengozzi, Alessandro

    2010-01-01T23:59:59.000Z

    capita); hydro (20%), black liquor, 6 peat, coal, wood fuel,to-door systems, but Black liquor is a byproduct of pulp,

  11. 6/2/12 NCBI Blast:Nucleotide Sequence (3118 letters) 1/7www.ncbi.nlm.nih.gov/blast/Blast.cgi

    E-Print Network [OSTI]

    Hickman, Mark

    6/2/12 NCBI Blast:Nucleotide Sequence (3118 letters) 1/7www579S1013 Nucleotide Sequence (3118 letters) nr All GenBank+EMBL+DDBJ+PDB sequences (but no EST, STS for risk assessment #12;6/2/12 NCBI Blast:Nucleotide Sequence (3118 letters) 2/7www

  12. Testing and analysis of structural steel columns subjected to blast loads

    E-Print Network [OSTI]

    Stewart, Lauren K.

    2010-01-01T23:59:59.000Z

    Blast Simulator Testing of Steel Columns and Components. 擳esting of Structural Steel Columns. 8 th Internationaland Analysis of Structural Steel Columns Subjected to Blast

  13. Duplex stainless steels for the pulp and paper industry

    SciTech Connect (OSTI)

    Alfonsson, E.; Olsson, J.

    1999-07-01T23:59:59.000Z

    The metallurgy and corrosion resistance of duplex stainless steel, particularly with regards to applications in the pulp and paper industry, are described. Practical experiences from pressure vessel installations in cooking plants and bleach plants as well as from non-pressurized items in different parts along the fiber line, are given. The paper also reviews corrosion test results presented previously and compares these with recent test data and the practical experiences. Though most of the installations have been successful, some cases of corrosion attacks on duplex stainless steel have been reported, although these are very limited in number: one digester, one calorifier, two pulp storage towers, and two bleach plant filter washers, of a total of more than 700 identified installations.

  14. Blast damage mitigation of steel structures from near- contact charges

    E-Print Network [OSTI]

    Wolfson, Janet Crumrine

    2008-01-01T23:59:59.000Z

    OF CALIFORNIA, SAN DIEGO Blast Damage Mitigation of Steel35 Damage Levels Observed in LaboratoryFigure 3.34: Progression of damage for a Ballistic Loading

  15. Gasification of kraft black liquor and use of the products in combined cycle cogeneration. Final report, Phase II

    SciTech Connect (OSTI)

    Kelleher, E.G.

    1985-07-01T23:59:59.000Z

    This Phase II study of kraft black liquor gasification and use of the product gases in combined cycle cogeneration based on combustion gas turbines was motivated by the very promising results of the Phase I feasibility study. The Phase I study indicated that the alternative technology to the Tomlinson recovery furnace had the potential of improving the energy efficiency and safety of combusting black liquor, reducing the capital and operating costs, increasing the electric power output, and providing an economical system for incremental kraft capacity additions. During Phase II, additional bench-scale experiments were run, pilot-scale experiments were conducted, equipment systems were investigated, and performance and economics were reanalyzed. All of the objectives of the Phase II project were met. Recommendations are summarized.

  16. Simultaneous measurement of the surface temperature and the release of atomic sodium from a burning black liquor droplet

    SciTech Connect (OSTI)

    Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Mechanical Engineering, The University of Adelaide (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Chemical Engineering, The University of Adelaide (Australia); Hupa, Mikko [Process Chemistry Centre, Aabo Akademi, Biskopsgatan 8 FI-20500 Aabo (Finland)

    2010-04-15T23:59:59.000Z

    Simultaneous measurement of the concentration of released atomic sodium, swelling, surface and internal temperature of a burning black liquor droplet under a fuel lean and rich condition has been demonstrated. Two-dimensional two-colour optical pyrometry was employed to determine the distribution of surface temperature and swelling of a burning black liquor droplet while planar laser-induced fluorescence (PLIF) was used to assess the temporal release of atomic sodium. The key findings of these studies are: (i) the concentration of atomic sodium released during the drying and devolatilisation stages was found to be correlated with the external surface area; and (ii) the insignificant presence of atomic sodium during the char consumption stage shows that sodium release is suppressed by the lower temperature and by the high CO{sub 2} content in and around the particle. (author)

  17. Understanding the Nature and Reactivity of Residual Lignin for Improved Pulping and Bleaching Efficiency

    SciTech Connect (OSTI)

    Yuan-Zong Lai

    2001-11-30T23:59:59.000Z

    One of the most formidable challenges in kraft pulping to produce bleached chemical pulps is how to effectively remove the last 5-10% of lignin while maintaining the fiber quality. To avoid a severe fiber degradation, kraft pulping is usually terminated in the 25-30 kappa number range and then followed by an elementally chlorine free (ECF) or a totally chlorine free (TCF) bleaching sequence to reduce the environmental impacts.

  18. Temperatures in the blast furnace refractory lining

    SciTech Connect (OSTI)

    Hebel, R.; Streuber, C. [Didier-M and P Energietechnik GmbH, Wiesbaden (Germany); Steiger, R. [Didier-M and P Engineering Services, Highland, IN (United States); Jeschar, R. [TU Clausthal (Germany). Inst. fuer Energieverfahrenstechnik und Brennstofftechnik

    1995-12-01T23:59:59.000Z

    The campaign life duration of a blast furnace is mainly determined by the condition of the refractory lining in heavy-duty zones such as the hearth, bosh, belly and lower stack. To achieve a desired lifetime, the temperature of the lining in these areas thereby proved to be the decisive controllable parameter. Low operating temperatures result in prolonged service life and are attained through high cooling efficiency. Besides the refractory grade chosen, the wear profile is mainly determined by the type of cooling system applied and the cooling intensity. Therefore, an appropriate compromise between long service life and energy losses has to be found in each case. In order to predict the service life of a lining it is important to know the wear condition at all times during the campaign. The paper describes the approaches the authors have made so far on European blast furnaces, on a theoretical and practical basis, on how to analyze the lining wear.

  19. A Phased Array Approach to Rock Blasting

    SciTech Connect (OSTI)

    Leslie Gertsch; Jason Baird

    2006-07-01T23:59:59.000Z

    A series of laboratory-scale simultaneous two-hole shots was performed in a rock simulant (mortar) to record the shock wave interference patterns produced in the material. The purpose of the project as a whole was to evaluate the usefulness of phased array techniques of blast design, using new high-precision delay technology. Despite high-speed photography, however, we were unable to detect the passage of the shock waves through the samples to determine how well they matched the expected interaction geometry. The follow-up mine-scale tests were therefore not conducted. Nevertheless, pattern analysis of the vectors that would be formed by positive interference of the shockwaves from multiple charges in an ideal continuous, homogeneous, isotropic medium indicate the potential for powerful control of blast design, given precise characterization of the target rock mass.

  20. Optimization Online - PuLP: A Linear Programming Toolkit for Python

    E-Print Network [OSTI]

    Stuart Mitchell

    2011-09-22T23:59:59.000Z

    Sep 22, 2011 ... PuLP is a high-level modelling library that leverages the power of the ... Keywords: mathematical programming; Python; modelling language.

  1. The Blast Energy Efficiency of GRBs

    E-Print Network [OSTI]

    David Eichler Daniel Jontof-Hutter

    2005-03-24T23:59:59.000Z

    Using data mostly assembled by previous authors, we consider the linear correlation between the apparent radiative efficiency $\\epsilon_{\\gamma}$ (defined as the ratio of isotropic equivalent radiative output to inferred isotropic equivalent kinetic energy of the blast) and $E_{peak}^{\\alpha}$ where $1.4efficiency is $\\sim 7$. We also find preliminary evidence (with a small sample) for a separate class of weak GRB afterglows.

  2. Explosive parcel containment and blast mitigation container

    DOE Patents [OSTI]

    Sparks, Michael H. (Frederick County, MD)

    2001-06-12T23:59:59.000Z

    The present invention relates to a containment structure for containing and mitigating explosions. The containment structure is installed in the wall of the building and has interior and exterior doors for placing suspicious packages into the containment structure and retrieving them from the exterior of the building. The containment structure has a blast deflection chute and a blowout panel to direct over pressure from explosions away from the building, surrounding structures and people.

  3. Centrifugal shot blasting. Innovative technology summary report

    SciTech Connect (OSTI)

    Not Available

    1999-07-01T23:59:59.000Z

    At the US Department of Energy (DOE) Fernald Environmental Management Project (FEMP), the Facilities Closure and Demolition Projects Integrated Remedial Design/Remedial Action (RD/RA) work plan calls for the removal of one inch (1 in) depth of concrete surface in areas where contamination with technetium-99 has been identified. This report describes a comparative demonstration between two concrete removal technologies: an innovative system using Centrifugal Shot Blasting (CSB) and a modified baseline technology called a rotary drum planer.

  4. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01T23:59:59.000Z

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  5. Mechanical Design of Steel Tubing for Use in Black Liquor Recovery Boilers

    SciTech Connect (OSTI)

    Taljat, B.; Zacharaia, T.; Wang, X.; Kesier, J.; Swindeman, R.; Hubbard, C.

    1999-05-26T23:59:59.000Z

    Finite element models were developed for thermal-mechanical analysis of black liquor recovery boiler floor tubes. Residual stresses in boiler floors due to various manufacturing processes were analyzed. The modeling results were verified by X-ray and neutron diffraction measurements at room temperature on as-manufactured tubes as well as tubes after service. The established finite element models were then used to evaluate stress conditions during boiler operation. Using these finite element models, a parametric response surface study was performed to investigate the influence of material properties of the clad layer on stresses in the floor tubes during various boiler operating conditions, which yielded a generalized solution of stresses in the composite tube floors. The results of the study are useful for identifying the mechanisms of cracking experienced by recovery boilers. Based on the results of the response surface study, a recommendation was made for more suitable materials in terms of the analyzed mechanical properties. Alternative materials and manufacturing processes are being considered to improve the resistance to cracking and the in-service life of composite tubes. To avoid numerous FE stress-strain analyses of composite tubes made of different material combinations, a response surface study was performed that considered two essential mechanical properties of the clad material - coefficient of thermal expansion and yield stress - as independent variables. The response surface study provided a generalized solution of stresses in the floor in terms of the two selected parameters.

  6. Dynamic air deposited coatings for power and black liquor recovery boilers

    SciTech Connect (OSTI)

    Verstak, A.A.; Baranovski, V.E. [Advanced Surface Technologies Inc., Richmond, VA (United States)

    1999-11-01T23:59:59.000Z

    Dynamic Air Deposition (DyAir) is a novel coating method designed to protect the tubing of power and black liquor recovery boilers against corrosion attack at elevated temperatures. The method utilizes the energy of combustion of gaseous fuel and air to heat the powder material to a temperature just below its melting point and accelerate it over 600 m/s to form a coating. The Ni-Cr and Ni-Cr-Mo DyAir coatings revealed no gas permeability and extremely low oxygen content. Compared to the electric arc and HVOF-sprayed coatings, the DyAir coatings exhibited higher hardness and better crack resistance. During aging at 400 and 700 C the bond strength and crack resistance of the DyAir coatings increased dramatically due to intensive diffusion processes in absence of internal corrosion attack. The DyAir coatings revealed outstanding resistance to corrosion, such as sulfidation attack in presence of hydrochloric acid gas at 400 C, oxidation attack at 700 C and oxidation attack in presence of chlorine at 400 C.

  7. Gasification behavior of carbon residue in bed solids of black liquor gasifier

    SciTech Connect (OSTI)

    Preto, Fernando; Zhang, Xiaojie (Frank); Wang, Jinsheng [CANMET Energy Technology Centre, Natural Resources (Canada)

    2008-07-15T23:59:59.000Z

    Steam gasification of carbon residue in bed solids of a low-temperature black liquor gasifier was studied using a thermogravimetric system at 3 bar. Complete gasification of the carbon residue, which remained unreactive at 600 C, was achieved in about 10 min as the temperature increased to 800 C. The rate of gasification and its temperature dependence were evaluated from the non-isothermal experiment results. Effects of particle size and adding H{sub 2} and CO to the gasification agent were also studied. The rate of steam gasification could be taken as zero order in carbon until 80% of carbon was gasified, and for the rest of the gasification process the rate appeared to be first order in carbon. The maximum rate of carbon conversion was around 0.003/s and the activation energy was estimated to be in the range of 230-300 kJ/mol. The particle size did not show significant effect on the rate of gasification. Hydrogen and carbon monoxide appeared to retard the onset of the gasification process. (author)

  8. Spatial Sequence Estimation Based Decoding Algorithm for V-BLAST

    E-Print Network [OSTI]

    Al-Ghadhban, Samir

    Spatial Sequence Estimation Based Decoding Algorithm for V-BLAST Maruf Mohammad, Samir Al degrades the performance. A detection algorithm for V-BLAST based on sequence estimation is proposed. The concept of maximum likelihood sequence estimation (MLSE) is applied to combat spatial interference. State

  9. A new approach to oxygen enriched high temperature blast generation

    SciTech Connect (OSTI)

    Queille, P.H.; Macauley, D.

    1996-12-31T23:59:59.000Z

    When increasing fuel injection in a blast furnace in order to reduce coke consumption and/or to increase production, the blast furnace operator tries to keep similar raceway conditions, for instance, an equivalent flame temperature. To compensate for the cooling effect due to the higher injection rate, two solutions can be selected or combined: to raise the temperature of the blast and/or to increase the level of oxygen in the blast. Whatever the choice, the Blast Furnace manager will certainly try to reduce the resulting investment and operating costs to a minimum. Air Liquide and Kvaerner Davy are trying to provide a new way to address these needs by offering a new technology for blast heating. A higher blast temperature will not only allow a higher fuel injection at tuyere level, a lower coke consumption, but also a lower oxygen consumption. Air Liquide and Kvaerner Davy are now able to offer a new heat regenerator with major advantages over conventional stoves. This new device can be used as a permanent substitute for a stove, or as a temporary one during repair, or stove improvement. It can also be added to an existing set of stoves to increase the average blast temperature.

  10. Analysis of seismic waves generated by surface blasting at Indiana coal mines

    E-Print Network [OSTI]

    Polly, David

    Analysis of seismic waves generated by surface blasting at Indiana coal mines A project pursuant is to investigate the characteristics of mine blast seismic waves in southern Indiana. Coal mines are prevalent blasting) and coal mines (surface blasting) to gain new understanding of seismic wave propagation, ground

  11. Recent improvements in casthouse practices at the Kwangyang blast furnaces

    SciTech Connect (OSTI)

    Jang, Y.S.; Han, K.W.; Kim, K.Y.; Cho, B.R.; Hur, N.S.

    1997-12-31T23:59:59.000Z

    POSCO`s Kwangyang blast furnaces have continuously carried out high production and low fuel operation under a high pulverized coal injection rate without complications since the Kwangyang No. 1 blast furnace was blown-in in 1987. The Kwangyang blast furnaces have focused on improving the work environment for the increase of competitive power in terms of increased production, cost savings, and management of optimum manpower through use of low cost fuel and raw material. At this time, the casthouse work lags behind most work in the blast furnace. Therefore, the Kwangyang blast furnaces have adopted a remote control system for the casthouse equipment to solve complications in the casthouse work due to high temperature and fumes. As the result, the casthouse workers can work in clean air and the number of workers has been reduced to 9.5 personnel per shift by reduction of the workload.

  12. Studies of laser-driven radiative blast waves

    SciTech Connect (OSTI)

    Edwards, M J; Hansen, J; Edens, A; Ditmire, T; Adams, R; Rambo, P; Ruggles, L; Smith, I; Porter, J

    2004-04-29T23:59:59.000Z

    We have performed two sets of experiments looking at laser-driven radiating blast waves. In one set of experiments the effect of a drive laser's passage through a background gas on the hydrodynamical evolution of blast waves was examined. It was found that the laser's passage heats a channel in the gas, creating a region where a portion of the blast wave front had an increased velocity, leading to the formation of a bump-like protrusion on the blast wave. The second set of experiments involved the use of regularly spaced wire arrays to induce perturbations on a blast wave surface. The decay of these perturbations as a function of time was measured for various wave number perturbations and found to be in good agreement with theoretical predictions.

  13. Detailed Analysis of the Microbial Population in Malaysian Spontaneous Cocoa Pulp Fermentations

    E-Print Network [OSTI]

    , lactic acid bacteria (LAB) and acetic acid bacteria (AAB) are the key players of this fermentationDetailed Analysis of the Microbial Population in Malaysian Spontaneous Cocoa Pulp Fermentations), Leuven, Belgium, 3 Barry Callebaut AG, Zurich, Switzerland Abstract The fermentation of cocoa pulp is one

  14. Fermentation and chemical treatment of pulp and paper mill sludge

    DOE Patents [OSTI]

    Lee, Yoon Y; Wang, Wei; Kang, Li

    2014-12-02T23:59:59.000Z

    A method of chemically treating partially de-ashed pulp and/or paper mill sludge to obtain products of value comprising taking a sample of primary sludge from a Kraft paper mill process, partially de-ashing the primary sludge by physical means, and further treating the primary sludge to obtain the products of value, including further treating the resulting sludge and using the resulting sludge as a substrate to produce cellulase in an efficient manner using the resulting sludge as the only carbon source and mixtures of inorganic salts as the primary nitrogen source, and including further treating the resulting sludge and using the resulting sludge to produce ethanol.

  15. Cogeneration handbook for the pulp and paper industry. [Contains glossary

    SciTech Connect (OSTI)

    Griffin, E.A.; Moore, N.L.; Fassbender, L.L.; Garrett-Price, B.A.; Fassbender, A.G.; Eakin, D.E.; Gorges, H.A.

    1984-03-01T23:59:59.000Z

    The decision of whether to cogenerate involves several considerations, including technical, economic, environmental, legal, and regulatory issues. Each of these issues is addressed separately in this handbook. In addition, a chapter is included on preparing a three-phase work statement, which is needed to guide the design of a cogeneration system. In addition, an annotated bibliography and a glossary of terminology are provided. Appendix A provides an energy-use profile of the pulp and paper industry. Appendices B and O provide specific information that will be called out in subsequent chapters.

  16. February 2014 News Blast | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2: FinalOffers New Training on Energy ManagementAugustin2012)4 News Blast February 2014 News

  17. Blast Effects Suppression System - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find FindRewind Generator Rewind Denison PowerhouseBlast

  18. Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors

    SciTech Connect (OSTI)

    Gary Blythe; John Currie; David DeBerry

    2008-03-31T23:59:59.000Z

    This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be measured by UV/visible light spectroscopy. Next, a series of bench-scale wet FGD simulation tests were conducted. Because of the significant effects of sulfite concentration on mercury re-emission rates, new methods were developed for operating and controlling the bench-scale FGD experiments. Approximately 140 bench-scale wet FGD tests were conducted and several unusual and pertinent effects of process chemistry on mercury re-emissions were identified and characterized. These data have been used to develop an empirically adjusted, theoretically based kinetics model to predict mercury species reactions in wet FGD systems. The model has been verified in tests conducted with the bench-scale wet FGD system, where both gas-phase and liquid-phase mercury concentrations were measured to determine if the model accurately predicts the tendency for mercury re-emissions. This report presents and discusses results from the initial laboratory kinetics measurements, the bench-scale wet FGD tests, and the kinetics modeling efforts.

  19. LTC vacuum blasting maching (concrete): Baseline report: Greenbook (Chapter)

    SciTech Connect (OSTI)

    NONE

    1997-07-31T23:59:59.000Z

    The LTC shot blast technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjuction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The LTC 1073 Vacuum Blasting Machine uses a high-capacity, direct-pressure blasting system which incorporates a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast. It incorporates a vacuum system which removes dust and debris from the surface as it is blasted. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure during maintenance activities was minimal, but due to mechanical difficulties dust monitoring could not be conducted during operation. Noise exposure was significant. Further testing for each of these exposures is recommended because of the outdoor environment where the testing demonstration took place. This may cause the results to be inaccurate. It is feasible that the dust and noise levels will be higher in an enclosed environment. In addition, other safety and health issues found were ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, and arm-hand vibration.

  20. India's pulp and paper industry: Productivity and energy efficiency

    SciTech Connect (OSTI)

    Schumacher, Katja

    1999-07-01T23:59:59.000Z

    Historical estimates of productivity growth in India's pulp and paper sector vary from indicating an improvement to a decline in the sector's productivity. The variance may be traced to the time period of study, source of data for analysis, and type of indices and econometric specifications used for reporting productivity growth. The authors derive both statistical and econometric estimates of productivity growth for this sector. Their results show that productivity declined over the observed period from 1973-74 to 1993-94 by 1.1% p.a. Using a translog specification the econometric analysis reveals that technical progress in India's pulp and paper sector has been biased towards the use of energy and material, while it has been capital and labor saving. The decline in productivity was caused largely by the protection afforded by high tariffs on imported paper products and other policies, which allowed inefficient, small plants to enter the market and flourish. Will these trends continue into the future, particularly where energy use is concerned? The authors examine the current changes in structure and energy efficiency undergoing in the sector. Their analysis shows that with liberalization of the sector, and tighter environmental controls, the industry is moving towards higher efficiency and productivity. However, the analysis also shows that because these improvements are being hampered by significant financial and other barriers the industry might have a long way to go.

  1. Pyrometric temperature measurement method and apparatus for measuring particle temperatures in hot furnaces: Application to reacting black liquor

    SciTech Connect (OSTI)

    Stenberg, J. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Frederick, W.J. [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States)] [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States); Bostroem, S. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland); Hernberg, R. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Hupa, M. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)

    1996-05-01T23:59:59.000Z

    A specialized two-color pyrometric method has been developed for the measurement of particle surface temperatures in hot, radiating environments. In this work, the method has been applied to the measurement of surface temperatures of single reacting black liquor char particles in an electrically heated muffle furnace. Black liquor was introduced into the hot furnace as wet droplets. After drying, the resulted particles were processed in different atmospheres corresponding to combustion, pyrolysis, and gasification at furnace temperatures of 700{endash}900{degree}C. The pyrometric measurement is performed using two silicon photodiode detectors and 10 nm bandpass filters centered at 650 and 1050 nm. Thermal radiation is transferred using an uncooled fiberoptic probe brought into the vicinity of the char particle. The key features of the pyrometric apparatus and analysis method are: (1) Single particle temperature is resolved temporally at high speed. (2) The thermal radiation originating from the furnace and reflected by the particle is accounted for in the measurement of the surface temperature. (3) Particle temperatures above or below the furnace temperature can be measured without the need of a cooled background assisting the measurement in the hot furnace. To accomplish this, a minimum particle size is needed that is a function of the temperature difference between the particle and furnace. Particles cooler than the furnace can be measured if their diameter is more than 0.7 mm. Surface temperatures of 300{endash}400{degree}C above the furnace temperature were measured during combustion of black liquor char particles in air. In atmospheres corresponding to gasification, endothermic reactions occurred, and char temperature remained typically 40{degree} below the furnace temperature. {copyright} {ital 1996 American Institute of Physics.}

  2. Causes and solutions for cracking of coextruded and weld overlay floor tubes in black liquor recovery boilers

    SciTech Connect (OSTI)

    Keiser, J.R.; Taljat, B.; Wang, X.L. [and others

    1998-09-01T23:59:59.000Z

    Cracking of coextruded, black liquor recovery boiler floor tubes is both a safety and an economic issue to mill operators. In an effort to determine the cause of the cracking and to identify a solution, extensive studies, described in this and three accompanying papers, are being conducted. In this paper, results of studies to characterize both the cracking and the chemical and thermal environment are reported. Based on the results described in this series of papers, a possible mechanism is presented and means to lessen the likelihood of cracking or to totally avoid cracking of floor tubes are offered.

  3. Electrolysis of weak black liquor: Part II. Effect of process parameters on the energy efficiency of the electrolytic cell

    SciTech Connect (OSTI)

    Cloutier, J.N.; Azarniouch, M.K.; Callender, D.

    1994-12-31T23:59:59.000Z

    A laboratory study of the effect of eight process parameters on the performance of the electrolytic cell when electrolyzing weak black liquor (WBL) showed that current density and temperature are critical to the operation. These two variables showed an interaction effect upon the operation of the cell. The addition of sodium sulfate to the WBL was beneficial to the energy efficiency. No chlorine gas was produced when electrolyzing WBL containing sodium chloride within the pH range of 5.4 to 13.

  4. Study of soluble scale fouling control in high solids black liquor concentrators. Progress report, quarter 5 (October 1, 1999 - December 31, 1999)

    SciTech Connect (OSTI)

    W.J. Frederick; F. Chen; G. Hsieh; S. Lien; R.W. Murphy; R.W. Rousseau; W. Schmidl

    2000-01-01T23:59:59.000Z

    During this quarter, work has finally resumed on the black liquor solubility experiments, but no new data have been generated. The crystallization experiments with inorganic model solutions have been completed, and crystallization experiments with kraft black liquor have been started. The Annular Test Cell apparatus is now fully operational, while construction of the falling film evaporator pilot plant is nearly complete. Startup of this unit is planned for late in Quarter 6. In the CFD model development work, the relaxation of simplifying assumptions in the falling film model have been completed, and expressions were developed to estimate film velocity/film Reynolds number relations. Also, thin film data taken for a range of conventional fluids were compared to predictions using selected methods, and attempts were initiated to extrapolate to approximate black liquor evaporator conditions.

  5. Hot blast stove process model and model-based controller

    SciTech Connect (OSTI)

    Muske, K.R. [Villanova Univ., PA (United States). Dept. of Chemical Engineering; Howse, J.W.; Hansen, G.A.; Cagliostro, D.J. [Los Alamos National Lab., NM (United States). Computational Science Methods Group; Chaubal, P.C. [Inland Steel Industries, Inc., East Chicago, IN (United States). Research Labs.

    1998-12-31T23:59:59.000Z

    This paper describes the process model and model-based control techniques implemented on the hot blast stoves for the No. 7 Blast Furnace at the Inland Steel facility in East Chicago, Indiana. A detailed heat transfer model of the stoves is developed and verified using plant data. This model is used as part of a predictive control scheme to determine the minimum amount of fuel necessary to achieve the blast air requirements. The model is also used to predict maximum and minimum temperature constraint violations within the stove so that the controller can take corrective actions while still achieving the required stove performance.

  6. NREL: Energy Storage - BLAST for Behind-the-Meter Applications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lite (BLAST-BTM Lite) provides a quick, user-friendly tool to size behind-the-meter energy storage devices used on site by utility customers for facility demand charge...

  7. APPLICATION OF STRICT LIABILTY AND NEGLIGENCE TO BLASTING CLAIMS

    E-Print Network [OSTI]

    of Explosives Engineers 2004G Volume 1 - Application of Strict Liability and Negligence to Blasting Claims 1-7394; tstark@uiuc.edu Copyright 2004 International Society of Explosives Engineers 2004G Volume 1

  8. Analysis of blast mitigation strategies exploiting fluid-structure interaction

    E-Print Network [OSTI]

    Kambouchev, Nayden Dimitrov, 1980-

    2007-01-01T23:59:59.000Z

    Blast attacks have become the most pervasive threat in both civil and military contexts. However, there is currently a limited understanding of the mechanisms of loading, damage and failure of structures, and injury to ...

  9. air blast freezing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    reexamined Nuclear Theory (arXiv) Summary: An alternative, to the commonly used blast-wave, model describing the freeze-out hypersurface is applied to fit the pT-spectra of...

  10. Blast Load Response of Steel Sandwich Panels with Liquid Encasement

    SciTech Connect (OSTI)

    Dale Karr; Marc Perlin; Benjamin Langhorst; Henry Chu

    2009-10-01T23:59:59.000Z

    We describe an experimental investigation of the response of hybrid blast panels for protection from explosive and impact forces. The fundamental notion is to dissipate, absorb, and redirect energy through plastic collapse, viscous dissipation, and inter-particle forces of liquid placed in sub-structural compartments. The panels are designed to absorb energy from an impact or air blast by elastic-plastic collapse of the panel substructure that includes fluid-filled cavities. The fluid contributes to blast effects mitigation by providing increased initial mass and resistance, by dissipation of energy through viscosity and fluid flow, and by redirecting the momentum that is imparted to the system from the impact and blast impulse pressures. Failure and deformation mechanisms of the panels are described.

  11. Characterising the acceleration phase of blast wave formation

    SciTech Connect (OSTI)

    Fox, T. E., E-mail: tef503@york.ac.uk; Pasley, J. [York Plasma Institute, University of York, York YO10 5DD (United Kingdom); Central Laser Facility, STFC Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX (United Kingdom); Robinson, A. P. L.; Schmitz, H. [Central Laser Facility, STFC Rutherford Appleton Laboratory, Harwell Oxford, Didcot OX11 0QX (United Kingdom)

    2014-10-15T23:59:59.000Z

    Intensely heated, localised regions in uniform fluids will rapidly expand and generate an outwardly propagating blast wave. The Sedov-Taylor self-similar solution for such blast waves has long been studied and applied to a variety of scenarios. A characteristic time for their formation has also long been identified using dimensional analysis, which by its very nature, can offer several interpretations. We propose that, rather than simply being a characteristic time, it may be interpreted as the definitive time taken for a blast wave resulting from an intense explosion in a uniform media to contain its maximum kinetic energy. A scaling relation for this measure of the acceleration phase, preceding the establishment of the blast wave, is presented and confirmed using a 1D planar hydrodynamic model.

  12. Concrete Masonry Wall Retrofit Systems for Blast Protection

    E-Print Network [OSTI]

    Johnson, Carol Faye

    2013-12-11T23:59:59.000Z

    unit (CMU) infill walls, commonly used in reinforced concrete or steel framed structures, are particularly vulnerable to blast loads. Facilities that incorporate CMU walls must either be hardened or retrofitted for explosive events. Conventional...

  13. autologous leukemia blasts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    can be described by a similarity solution, that is used for theoretical models of gamma-ray bursts. We consider the linear stability of such a relativistic blast wave propagating...

  14. asymmetric blast wave: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    can be described by a similarity solution, that is used for theoretical models of gamma-ray bursts. We consider the linear stability of such a relativistic blast wave propagating...

  15. Investigation of Ultrafast Laser-Driven Radiative Blast Waves

    SciTech Connect (OSTI)

    Edwards, M. J.; MacKinnon, A. J.; Zweiback, J.; Shigemori, K.; Ryutov, D.; Rubenchik, A. M.; Keilty, K. A.; Liang, E.; Remington, B. A.; Ditmire, T.

    2001-08-20T23:59:59.000Z

    We have examined the evolution of cylindrically symmetric blast waves produced by the deposition of femtosecond laser pulses in gas jets. In high-Z gases radiative effects become important. We observe the production of an ionization precursor ahead of the shock front and deceleration parameters below the adiabatic value of 1/2 (for a cylinder), an effect expected when the blast wave loses energy by radiative cooling. Despite significant radiative cooling, the blast waves do not appear to develop thin shell instabilities expected for strongly radiative waves. This is believed to be due to the stabilizing effect of a relatively thick blast wave shell resulting in part from electron thermal conduction effects.

  16. Dynamic response of containment vessels to blast loading

    SciTech Connect (OSTI)

    Karpp, R.R.; Duffey, T.A.; Neal, T.R.; Warnes, R.H.; Thompson, J.D.

    1982-01-01T23:59:59.000Z

    The dynamic response of steel, spherical containment vessels loaded by internal explosive blast was studied by experiments, computations, and analysis. Instrumentation used in the experiments consisted of strain and pressure gauges and a velocity interferometer. Data were used to rank the blast wave mitigating properties of several filler materials and to develop a scaling law relating strain, filler material, and explosive energy or explosive mass.

  17. Conserving Energy in Blast Freezers Using Variable Frequency Drives

    E-Print Network [OSTI]

    Kolbe, E.; Ling, Q.; Wheeler, G.

    2004-01-01T23:59:59.000Z

    University Portland Greg Wheeler Director Industrial Assessment Center ABSTRACT A stationary blast freezer processing 22 -lb cartons of sardines in 19,000 pound lots was modified to improve efficiency and to conserve energy. Baffles... of Portland showed readings to agree within 1%. The procedure for measuring velocity profiles was to position the operator in the blast-cell with doors closed, downstream of the pack, prior to opening the refrigeration valve. We thus assumed...

  18. Materials needs and opportunities in the pulp and paper industry

    SciTech Connect (OSTI)

    Angelini, P. [comp.

    1995-08-01T23:59:59.000Z

    The Department of Energy`s (DOE) Office of Industrial Technologies (OIT) supports research and development (R&D) in industry, the DOE national laboratories, and in universities to develop energy efficient, environmentally-acceptable industrial technologies. The Office of Industrial Technologies is working with seven energy-intensive industries to develop R&D roadmaps that will facilitate cooperative government-industry efforts to achieve energy-efficient, environmentally-acceptable, sustainable industries of the future. The forest products industry is one of the industries with which OIT is working to develop an R&D roadmap. The Advanced Industrial Materials (AIM) Program of the Office of Industrial Technologies sponsors long-term, directed research on materials that will enable industry to develop and utilize more energy-efficient, sustainable processes and technologies. The purpose of the study described in this report was to identify the material R&D needs and opportunities for the pulp and paper mill of the future.

  19. The US pulp and paper industry: An energy perspective

    SciTech Connect (OSTI)

    Elaahi, A.; Lowitt, H.E.

    1988-04-01T23:59:59.000Z

    This report investigates the state of the US pulp and paper industry in terms of energy consumption and conservation. Objectives were: to update and verify energy consumption and production data for the various process steps in 1985; to determine the potential energy savings attainable by replacing current practices with state-of-the-art and advanced (2010) production practices and technologies; and to identify areas of research and development opportunity that will enable these potential future savings to be achieved. Results concluded that for the year 2010 production level, there is a potential to save between 34 and 53% of the energy use by replacing current technology practices with state-of-the-art and advanced technologies. R and D needs and opportunities were identified for the industry. Potential R and D candidates for DOE involvement were selected from the identified list, primarily based on their energy savings potential and the opinion of industry experts.

  20. System and method for conditioning a hardwood pulp liquid hydrolysate

    DOE Patents [OSTI]

    Waite, Darrell M; Arnold, Richard; St. Pierre, James; Pendse, Hemant P; Ceckler, William H

    2013-12-17T23:59:59.000Z

    A system and method for hardwood pulp liquid hydrolysate conditioning includes a first evaporator receives a hardwood mix extract and outputting a quantity of vapor and extract. A hydrolysis unit receives the extract, hyrolyzes and outputs to a lignin separation device, which separates and recovers a quantity of lignin. A neutralization device receives extract from the lignin separation device and a neutralizing agent, producing a mixture of solid precipitate and a fifth extract. The solid precipitate is removed from the fifth extract. A second evaporator removes a quantity of acid from the fifth extract in a vapor form. This vapor may be recycled to improve total acid recovery or discarded. A desalination device receives the diluted extract, separates out some of the acid and salt and outputs a desalinated solution.

  1. LTC 1073 vacuum blasting (concrete) human factors assessment -- Baseline (summary)

    SciTech Connect (OSTI)

    NONE

    1997-07-31T23:59:59.000Z

    The LTC 1073 Vacuum Blasting Machine uses a high capacity, direct pressure blasting system incorporating a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast head. A vacuum system removes dust and debris from the surfaces as it is blasted. After cleaning the surface, the abrasive, together with the rust or coating that was removed from the surface, is vacuumed into the machine through the suction hose. The dust separator contains angled steel collision pads, working with the force of gravity, to allow any reusable abrasive to fall back into the pressure vessel. The filters are manually back flushed to prevent clogging. After back flushing, dust is dumped from the dust chamber into the dust collection bag or drum by operation of the bellows valve. The safety and health evaluation during the testing demonstration focused on dust and noise exposure. Dust exposure was found to be minimal, but noise exposure was potentially significant. Further testing for each of these exposures is recommended because the outdoor environment where the testing demonstration took place may cause the results to be inapplicable to indoor settings. It is feasible that the dust and noise levels will be higher in an enclosed operating environment. Other safety and health issues found were ergonomics, heat stress, tripping hazards, lockout/tagout, and arm-hand vibration.

  2. Application of AI techniques to blast furnace operations

    SciTech Connect (OSTI)

    Iida, Osamu; Ushijima, Yuichi; Sawada, Toshiro [Kawasaki Steel Corp., Kurashiki (Japan)

    1995-10-01T23:59:59.000Z

    It was during the first stages of application of artificial intelligence (AI) to industrial fields, that the ironmaking division of Mizushima works at Kawasaki Steel recognized its potential. Since that time, the division has sought applications for these techniques to solve various problems. AI techniques applied to control the No. 3 blast furnace operations at the Mizushima works include: Blast furnace control by a diagnostic type of expert system that gives guidance to the actions required for blast furnace operation as well as control of furnace heat by automatically setting blast temperature; Hot stove combustion control by a combination of fuzzy inference and a physical model to insure good thermal efficiency of the stove; and blast furnace burden control using neural networks makes it possible to connect the pattern of gas flow distribution with the condition of the furnace. Experience of AI to control the blast furnace and other ironmaking operations has proved its capability for achieving automation and increased operating efficiency. The benefits are very high. For these reasons, the applications of AI techniques will be extended in the future and new techniques studied to further improve the power of AI.

  3. Use of sinter in Taranto blast furnaces

    SciTech Connect (OSTI)

    Palchetti, M.; Palomba, R.; Tolino, E. [CSM Taranto (Italy); Salvatore, E.; Calcagni, M. [ILP Taranto Works (Italy)

    1995-12-01T23:59:59.000Z

    Lowering the production cost of the crude steel is the ultimate aim when planning operations in an integrated steelworks. Designing the Blast Furnace burden is a crucial point in this context, for which account must be taken not only of the raw materials cost but also of other important aims such as maximum plants productivity, minimum possible energy consumption, a proper product quality at the various production stages. This paper describes the criteria used in Ilva Laminati Piani (ILP) Taranto Works to design the BF burden, based on sinter, using the results of extensive research activity carried out by Centro Sviluppo Materiali (CSM), the Research Center with major involvement with the R and D of the Italian Steel Industry. Great attention is paid at ILP to the sinter quality in order to obtain the optimum performance of the BFs, which are operating at high productivity, high pulverized coal rate and low fuel consumption.

  4. Blast mitigation capabilities of aqueous foam.

    SciTech Connect (OSTI)

    Hartman, William Franklin; Larsen, Marvin Elwood; Boughton, Bruce A.

    2006-02-01T23:59:59.000Z

    A series of tests involving detonation of high explosive blanketed by aqueous foam (conducted from 1982 to 1984) are described in primarily terms of recorded peak pressure, positive phase specific impulse, and time of arrival. The investigation showed that optimal blast mitigation occurs for foams with an expansion ratio of about 60:1. Simple analyses representing the foam as a shocked single phase mixture are presented and shown inadequate. The experimental data demonstrate that foam slows down and broadens the propagated pressure disturbance relative to a shock in air. Shaped charges and flyer plates were evaluated for operation in foam and appreciable degradation was observed for the flyer plates due to drag created by the foam.

  5. Reactive Blast Waves from Composite Charges

    SciTech Connect (OSTI)

    Kuhl, A L; Bell, J B; Beckner, V E

    2009-10-16T23:59:59.000Z

    Investigated here is the performance of composite explosives - measured in terms of the blast wave they drive into the surrounding environment. The composite charge configuration studied here was a spherical booster (1/3 charge mass), surrounded by aluminum (Al) powder (2/3 charge mass) at an initial density of {rho}{sub 0} = 0.604 g/cc. The Al powder acts as a fuel but does not detonate - thereby providing an extreme example of a 'non-ideal' explosive (where 2/3 of the charge does not detonate). Detonation of the booster charge creates a blast wave that disperses the Al powder and ignites the ensuing Al-air mixture - thereby forming a two-phase combustion cloud embedded in the explosion. Afterburning of the booster detonation products with air also enhances and promotes the Al-air combustion process. Pressure waves from such reactive blast waves have been measured in bomb calorimeter experiments. Here we describe numerical simulations of those experiments. A Heterogeneous Continuum Model was used to model the dispersion and combustion of the Al particle cloud. It combines the gasdynamic conservation laws for the gas phase with a dilute continuum model for the dispersed phase, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by phenomenological models of Khasainov. It incorporates a combustion model based on mass conservation laws for fuel, air and products; source/sink terms are treated in the fast-chemistry limit appropriate for such gasdynamic fields, along with a model for mass transfer from the particle phase to the gas. The model takes into account both the afterburning of the detonation products of the booster with air, and the combustion of the Al particles with air. The model equations were integrated by high-order Godunov schemes for both the gas and particle phases. Adaptive Mesh Refinement (AMR) was used to capture the energy-bearing scales of the turbulent flow on the computational grid, and to track/resolve reaction zones. Numerical simulations of the explosion fields from 1.5-g and 10-kg composite charges were performed. Computed pressure histories (red curve) are compared with measured waveforms (black curves) in Fig. 1. Comparison of these results with a waveform for a non-combustion case in nitrogen (blue curve) demonstrates that a reactive blast wave was formed. Cross-sectional views of the temperature field at various times are presented in Fig. 2, which shows that the flow is turbulent. Initially, combustion occurs at the fuel-air interface, and the energy release rate is controlled by the rate of turbulent mixing. Eventually, oxidizer becomes distributed throughout the cloud via ballistic mixing of the particles with air; energy release then occurs in a distributed combustion mode, and Al particle kinetics controls the energy release rate. Details of the Heterogeneous Continuum Model and results of the numerical simulations of composite charge explosions will be described in the paper.

  6. Blasting detonators incorporating semiconductor bridge technology

    SciTech Connect (OSTI)

    Bickes, R.W. Jr.

    1994-05-01T23:59:59.000Z

    The enormity of the coal mine and extraction industries in Russia and the obvious need in both Russia and the US for cost savings and enhanced safety in those industries suggests that joint studies and research would be of mutual benefit. The author suggests that mine sites and well platforms in Russia offer an excellent opportunity for the testing of Sandia`s precise time-delay semiconductor bridge detonators, with the potential for commercialization of the detonators for Russian and other world markets by both US and Russian companies. Sandia`s semiconductor bridge is generating interest among the blasting, mining and perforation industries. The semiconductor bridge is approximately 100 microns long, 380 microns wide and 2 microns thick. The input energy required for semiconductor bridge ignition is one-tenth the energy required for conventional bridgewire devices. Because semiconductor bridge processing is compatible with other microcircuit processing, timing and logic circuits can be incorporated onto the chip with the bridge. These circuits can provide for the precise timing demanded for cast effecting blasting. Indeed tests by Martin Marietta and computer studies by Sandia have shown that such precise timing provides for more uniform rock fragmentation, less fly rock, reduce4d ground shock, fewer ground contaminants and less dust. Cost studies have revealed that the use of precisely timed semiconductor bridges can provide a savings of $200,000 per site per year. In addition to Russia`s vast mineral resources, the Russian Mining Institute outside Moscow has had significant programs in rock fragmentation for many years. He anticipated that collaborative studies by the Institute and Sandia`s modellers would be a valuable resource for field studies.

  7. Simulating the dynamics of flexible wood pulp fibres in suspension John M. Stockie

    E-Print Network [OSTI]

    Stockie, John

    , including wood pulp processing, polymer composites, and formation of fibre-reinforced materials elements to form a surface that re- sists bending and stretching. This is a natural construction for wood

  8. Advanced Powerhouse Controls Save Pulp Mill $500 in Purchased Energy in First Month

    E-Print Network [OSTI]

    Morrison, R.; Hilder, S.

    2004-01-01T23:59:59.000Z

    This case study describes the application of advanced regulatory and supervisory controls to powerhouse operations at a large pulp mill in central British Columbia. Substantial reductions in mill operating costs were achieved by actively managing...

  9. Fundamental study of black liquor gasification kinetics using a pressurized entrained-flow reactor (PEFR). Quarterly progress report for the period July 1999 to September 1999

    SciTech Connect (OSTI)

    NONE

    1999-10-29T23:59:59.000Z

    The goal of the program is to identify the optimal operating window for black liquor gasification. The goals during this year are to prepare the PEFR for operation, conduct a series of preliminary screening tests to bracket BLG operating conditions, and develop a process model that can guide identification of the optimal operating window.

  10. Design of a composite combat helmet liner for prevention of blast-induced traumatic brain injury

    E-Print Network [OSTI]

    Vechart, Andrew (Andrew Peter)

    2011-01-01T23:59:59.000Z

    Air blast-induced traumatic brain injuries (TBIs) represent a significant percentage of military personnel injuries observed in Operation Enduring Freedom (OEF) and Operation Iraqi Freedom (OIF). Prevalence of blast-induced ...

  11. Control of the Accumulation of Non-Process Elements in Pulp Mills with Bleach Filtrate Reuse: A Chemical Equilibrium Approach to Predicting the Partitioning of Metals in Pulp Mill and Bleach Plant Streams

    SciTech Connect (OSTI)

    Frederick, W.J. Jr.; Rudie, A.W.; Schmidl, G.W.; Sinquefield, S.A.; Rorrer, G.L.; Laver, M.L.; Yantasee, W.; Ming, D.

    2000-08-01T23:59:59.000Z

    The overall goal of this project was to develop fundamental, experimentally based methods for predicting the solubility or organic and inorganic matter and their interactions in recycled effluent from kraft pulp mills and bleach plants. This included: characterizing the capacity of wood pulp and dissolved organic matter to bind metal ions, developing a thermodynamic database of properties needed to describe the solubility of inorganic matter in pulp mill streams, incorporation of the database into equilibrium calculation software for predicting the solubility of the metals of interest, and evaluating its capability to predict the distribution of the metals between pulp fibers, inorganic precipitates, and solution.

  12. STUDIES OF LASER-DRIVEN RADIATIVE BLAST WAVES A.D. EDENS1

    E-Print Network [OSTI]

    Ditmire, Todd

    -driven radiating blast waves. In the first set of experiments the effect of a drive laser's passage throughSTUDIES OF LASER-DRIVEN RADIATIVE BLAST WAVES A.D. EDENS1 , T. DITMIRE1 , J.F. HANSEN2 , M a background gas on the hydrodynamical evolution of blast waves was examined. The laser's passage heated

  13. Effect of Blast Design on Crack Response C.H. Dowding

    E-Print Network [OSTI]

    Effect of Blast Design on Crack Response C.H. Dowding Professor of Civil & Environmental to assess the effect of changes in blast design on the house response. Velocity response was measured some 11 velocity transducers and 3 crack sensors measured excitation and response for each blast

  14. Micro-meter Crack Response to Rock Blast Vibrations, Wind Gusts & Weather Effects

    E-Print Network [OSTI]

    Micro-meter Crack Response to Rock Blast Vibrations, Wind Gusts & Weather Effects C. H. Dowding,1 effects. These measurements substantiate the conservancy of the 12.5 mm/s (0.5 in./s) blasting vibration blasting. Measurements in this case study now extend weather effects to include wind. While it has been

  15. USE OF FIBER-REINFORCED SOIL FOR BLAST PROTECTION Jorge G. Zornberg

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    of Texas at Austin, Austin, Texas, USA ABSTRACT Soil berms have been used to resist the blast effect The various branches of the armed services often require structures designed to resist the blast effects from conventional weapons. Such structures include bunkers, aircraft shelters, and weapon facilities. Blast effects

  16. Numerical study of the effect of polyurea on the performance of steel plates under blast loads

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    Numerical study of the effect of polyurea on the performance of steel plates under blast loads to blast-like loads. Different thicknesses of the polyurea are considered and the effect of polyurea history: Received 28 February 2013 Available online 13 May 2013 Keywords: Polyurea DH-36 steel Blast

  17. Effectiveness of advanced coating systems for mitigating blast effects on steel components

    E-Print Network [OSTI]

    Effectiveness of advanced coating systems for mitigating blast effects on steel components C. Chen1 of this work is to study the effectiveness of an advanced coating material, polyurea, as a blast mitigation. Effects of thicknesses and locations of the polyurea on the blast mitigation are also studied

  18. Weak-Axis Behavior of Wide Flange Columns Subjected to Blast

    E-Print Network [OSTI]

    Bruneau, Michel

    the effect of blast loading on wide flange columns loaded perpendicular to the weak axis of bending field detonations. Furthermore, past studies investigating the effect of blast load- ing on wide flangeWeak-Axis Behavior of Wide Flange Columns Subjected to Blast Nagarjun Krishnappa1 ; Michel Bruneau

  19. EXIT Chart Analysis of Turbo-BLAST Receivers in Rayleigh Fading Channels

    E-Print Network [OSTI]

    Dai, Huaiyu

    EXIT Chart Analysis of Turbo-BLAST Receivers in Rayleigh Fading Channels Wenjun Li and Huaiyu Dai: Wli5@ncsu.edu, Huaiyu Dai@ncsu.edu Abstract-- Turbo-BLAST is an advanced space-time layered with Turbo-BLAST to combat the co-channel interference (CCI) and significantly improve the performance

  20. Production of ammonium sulfate fertilizer from FGD waste liquors. Quarterly technical report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Randolph, A.D.; Mukhopadhyay, S.; Unrau, E.

    1994-12-31T23:59:59.000Z

    During this quarterly period, an experimental investigation was performed to study the precipitation kinetics and hydrolysis characteristics of calcium imido disulfonate crystals (CaADS). The CaADS crystals were precipitated by a metathetical reaction of lime, supplied by Dravo Lime Co., with flue gas desulfurization (FGD) scrubber waste liquor. Before approaching for the continuous Double Draw-Off (DDO) crystallization studies, the influence of a Dravo lime slurry on the precipitation characteristics of N-S compounds will be established. A series of N-S compound batch crystallization studies were completed in a wide range of pH (7.0--9.0), and the influence of pH on the amount of lime required, as well as the amount of precipitate obtained, was investigated. Although the amount of precipitate increased with increase in solution pH, the safe or optimum pH for the precipitation of CaADS lies in the vicinity of 8.2 to 8.3. For studying the crystallization characteristics of CaADS crystals, a bench scale 7.0 liter DDO crystallizer was built. DDO crystallizer is found to be superior compared to Mixed Suspension Mixed Product Removal (MSMPR) crystallizer. The precipitated crystals were analyzed for elemental composition by chemical analysis. The crystals were also examined under optical microscope for their morphological features. The present studies confirmed our prediction that N-S compounds in the waste liquor can be precipitated by a reaction with lime slurry. The precipitated crystals were mostly calcium imido disulfonate.

  1. No. 5 blast furnace 1995 reline and upgrade

    SciTech Connect (OSTI)

    Kakascik, T.F. Jr.

    1996-12-31T23:59:59.000Z

    The 1995 reline of No. 5 Blast Furnace is an undertaking which has never been approached in previous relines of any blast furnace in the history of Wheeling Pittsburgh Steel Corporation. The scope of the project is such that it represents a radical departure from W.P.S.C.`s traditional methods of ironmaking. The reline of No. 5 Blast Furnace is one of the largest capital improvements performed at W.P.S.C. Blast Furnaces. The improvements made at one single time are taking a furnace from 1960`s technology into the 21st century. With this in mind, employee training was one of the largest parts of the project. Training for the automated stockhouse, castfloor, new skip drive, new instrumentation, new castfloor equipment, hydraulics and overall furnace operation were an absolute necessity. The reline has laid the ground work to give the Corporation an efficient, higher productive, modern Blast Furnace which will place W.P.S.C. in the world class category in ironmaking well into the 21st century.

  2. Atmospheric particulate emissions from dry abrasive blasting using coal slag

    SciTech Connect (OSTI)

    Bhaskar Kura; Kalpalatha Kambham; Sivaramakrishnan Sangameswaran; Sandhya Potana [University of New Orleans, New Orleans, LA (United States). Department of Civil and Environmental Engineering

    2006-08-15T23:59:59.000Z

    Coal slag is one of the widely used abrasives in dry abrasive blasting. Atmospheric emissions from this process include particulate matter (PM) and heavy metals, such as chromium, lead, manganese, nickel. Quantities and characteristics of PM emissions depend on abrasive characteristics and process parameters. Emission factors are key inputs to estimate emissions. Experiments were conducted to study the effect of blast pressure, abrasive feed rate, and initial surface contamination on total PM (TPM) emission factors for coal slag. Rusted and painted mild steel surfaces were used as base plates. Blasting was carried out in an enclosed chamber, and PM was collected from an exhaust duct using U.S. Environment Protection Agency source sampling methods for stationary sources. Results showed that there is significant effect of blast pressure, feed rate, and surface contamination on TPM emissions. Mathematical equations were developed to estimate emission factors in terms of mass of emissions per unit mass of abrasive used, as well as mass of emissions per unit of surface area cleaned. These equations will help industries in estimating PM emissions based on blast pressure and abrasive feed rate. In addition, emissions can be reduced by choosing optimum operating conditions. 40 refs., 5 figs., 2 tabs.

  3. Modelling of multiphase flow in ironmaking blast furnace

    SciTech Connect (OSTI)

    Dong, X.F.; Yu, A.B.; Burgess, J.M.; Pinson, D.; Chew, S.; Zulli, P. [University of New South Wales, Sydney, NSW (Australia). School for Material Science and Engineering

    2009-01-15T23:59:59.000Z

    A mathematical model for the four-phase (gas, powder, liquid, and solids) flow in a two-dimensional ironmaking blast furnace is presented by extending the existing two-fluid flow models. The model describes the motion of gas, solid, and powder phases, based on the continuum approach, and implements the so-called force balance model for the flow of liquids, such as metal and slag in a blast furnace. The model results demonstrate a solid stagnant zone and dense powder hold-up region, as well as a dense liquid flow region that exists in the lower part of a blast furnace, which are consistent with the experimental observations reported in the literature. The simulation is extended to investigate the effects of packing properties and operational conditions on the flow and the volume fraction distribution of each phase in a blast furnace. It is found that solid movement has a significant effect on powder holdup distribution. Small solid particles and low porosity distribution are predicted to affect the fluid flow considerably, and this can cause deterioration in bed permeability. The dynamic powder holdup in a furnace increases significantly with the increase of powder diameter. The findings should be useful to better understand and control blast furnace operations.

  4. Blasting the way to synchronous communications

    SciTech Connect (OSTI)

    Charbonnet, P. Jr.; Smith, G.

    1984-01-18T23:59:59.000Z

    Minicomputer and microcomputer users now have several new options in data communications software. Most of these packages fall into the rapidly growing category of file-transfer utilities-that is, programs that exchange computers. The key factor in the development of these products is that most micros and minis have only asynchronous communications capability. They cannot use mainframe data communications protocols. All of the asynchronous protocols that have emerged use the standard synchronous technique for error detection: the data stream is divided into blocks, and the integrity of each block is monitored by appending a check-sum that is recomputed and compared with the original check-sum when the block is received. Full-duplex protocols such as blocked asynchronous transmission (blast) transmit a continuous stream of data blocks while using the other half of the communications channel to receive block acknowledgements simultaneously. This structure is combined with the use of sliding window or pipelining techniques as employed by sophisticated synchronous protocols such as SNA/SDLC and x.25/HDLC. The end result is that full-duplex asynchronous protocols can endure significant propagation delay without losing efficiency. They are suitable for use in a variety of communications environments.

  5. Producing a True Lignin Depolymerase for Biobleaching Softwood Kraft Pulp

    SciTech Connect (OSTI)

    Simo Sarkanen

    2002-02-04T23:59:59.000Z

    This project constituted an intensive effort devoted to producing, from the white-rot fungus Tramets Cingulata, a lignin degrading enzyme (lignin depolymerase) that is directly able to biobleach or delignify softwood kraft pulp brownstock. To this end, the solutions in which T. cingulata was grown contained dissolved kraft lignin which fulfilled two functions; it behaved as a lignin deploymerase substrate and it also appeared to act as an inducer of enzyme expression. However, the lignin depolymerase isoenzymes (and other extracellular T. cingulata enzymes) interacted very strongly with both the kraft lignin components and the fungal hypae, so the isolating these proteins from the culture solutions proved to be unexpectedly difficult. Even after extensive experimentation with a variety of protein purification techniques, only one approach appeared to be capable of purifying lignin depolymerases to homogeneity. Unfortunately the procedure was extremely laborious; it involved the iso electric focusing of concentrated buffer-exchanged culture solutions followed by electro-elution of the desired protein bands from the appropriate polyacrylamide gel segments

  6. Modeling and Simulating Blast Effects on Electric Substations

    SciTech Connect (OSTI)

    Lyle G. Roybal; Robert F. Jeffers; Kent E. McGillivary; Tony D. Paul; Ryan Jacobson

    2009-05-01T23:59:59.000Z

    A software simulation tool was developed at the Idaho National Laboratory to estimate the fragility of electric substation components subject to an explosive blast. Damage caused by explosively driven fragments on a generic electric substation was estimated by using a ray-tracing technique to track and tabulate fragment impacts and penetrations of substation components. This technique is based on methods used for assessing vulnerability of military aircraft and ground vehicles to explosive blasts. An open-source rendering and ray-trace engine was used for geometric modeling and interactions between fragments and substation components. Semi-empirical material interactions models were used to calculate blast parameters and simulate high-velocity material interactions between explosively driven fragments and substation components. Finally, a Monte Carlo simulation was added to model the random nature of fragment generation allowing a skilled analyst to predict failure probabilities of substation components.

  7. Operating experience with 100% pellet burden on Amanda blast furnace

    SciTech Connect (OSTI)

    Keaton, D.E.; Minakawa, T. (Armco Steel Co., Middletown, OH (United States). Ironmaking Dept.)

    1993-01-01T23:59:59.000Z

    A number of significant changes in operations at the Ashland Works of the Armco Steel Company occurred in 1992 which directly impacted the Amanda Blast Furnace operation. These changes included the shutdown of the hot strip mill which resulted in coke oven gas enrichment of the Amanda stoves and an increase of 75 C in hot blast temperature, transition to 100% continuous cast operation which resulted in increased variation of the hot metal demand, and the July idling of the sinter plant. Historically, the Amanda Blast Furnace burden was 30% fluxed sinter and 70% acid pellet. It was anticipated that the change to 100% pellet burden would require changes in charging practice and alter furnace performance. The paper gives a general furnace description and then describes the burden characteristics, operating practice with 30% sinter/70% acid pellet burden, preparations for the 100% acid pellet burden operation, the 100% acid pellet operation, and the 100% fluxed pellet burden operation.

  8. Improvement of tap holes at Wakayama No. 5 blast furnace

    SciTech Connect (OSTI)

    Yamashita, M.; Kashiwada, M.; Shibuta, H. [Sumitomo Metal Industries, Ltd., Wakayama (Japan). Wakayama Steel Works

    1995-12-01T23:59:59.000Z

    The service life of blast furnaces, as the result of various improvement measures, has been extended from the conventional 5 to 7 years to 15 to 20 years. Wakayama No. 5 blast furnace adopted SiC bricks. Though SiC brick excelled in strength and durability, it has raised problems such as tap hole inside temperature lowering attributable to its high thermal conductivity, insufficient mud burning and gas blow-out. Nevertheless, various countermeasures described within have been taken against such problems, and as the result it has now become possible to maintain tap holes in stable conditions.

  9. Temperature Profiles and the Effect of AGN on Submillimeter Emission from BLAST Observations of Resolved Galaxies

    E-Print Network [OSTI]

    Wiebe, Donald V; Bock, James J; Chapin, Edward L; Devlin, Mark J; Dicker, Simon; Griffin, Matthew; Gundersen, Joshua O; Halpern, Mark; Hargrave, Peter C; Hughes, David H; Klein, Jeff; Marsden, Gaelen; Martin, Peter G; Mauskopf, Philip; Netterfield, Calvin B; Olmi, Luca; Pascale, Enzo; Patanchon, Guillaume; Rex, Marie; Scott, Douglas; Semisch, Christopher; Thomas, Nicholas; Truch, Matthew D P; Tucker, Carole; Tucker, Gregory S; Viero, Marco P

    2009-01-01T23:59:59.000Z

    Over the course of two flights, the Balloon-borne Large Aperture Submillimeter Telescope (BLAST) made resolved maps of seven nearby (BLAST05), BLAST observed a single nearby galaxy, NGC 4565. During the December 2006 flight from Antarctica (BLAST06), BLAST observed the nearby galaxies NGC 1097, NGC 1291, NGC 1365, NGC 1512, NGC 1566, and NGC 1808. We fit physical dust models to a combination of BLAST observations and other available data for the the galaxies with Spitzer data. We fit a modified blackbody to the remaining galaxies to obtain total dust mass and mean dust temperature. For the four galaxies with Spitzer data, we also produce maps and radial profiles of dust column density and temperature. We measure the fraction of BLAST detected flux originating from the central cores of these galaxies and use this to calculate a "core fraction", an upper limit on the "AGN fraction" of submillimeter detected galaxies. Fin...

  10. Hot repair of ceramic burner on hot blast stoves at USS/Kobe`s {number_sign}3 blast furnace

    SciTech Connect (OSTI)

    Bernarding, T.F.; Chemorov, M.; Shimono, S.; Phillips, G.R.

    1997-12-31T23:59:59.000Z

    During the 1992 reline of the No. 3 blast furnace, three new stoves were constructed. The design of the stoves, equipped with internal ceramic burners, was for providing a hot blast temperature of 2,000 F at a wind rate of 140,000 SCFM. After 3 years the performance had deteriorated so the burners were cleaned. When a second cleaning did not improve the performance of No. 3 blast furnace, it was decided to repair the refractory while still hot. The paper describes the hot repair procedures, taking a stove off for repairs, maintenance heat up during repairs, two stove operation, stove commissioning, repair of a ceramic burner, and wet gas prevention.

  11. Presentation 3.1: Report on energy efficient technologies and CO2 reduction potentials in the pulp and paper industry

    E-Print Network [OSTI]

    Presentation 3.1: Report on energy efficient technologies and CO2 reduction potentials in the pulp INTERNATIONALE DE L'ENERGIE Report on Energy Efficient Technologies and CO2 Reduction Potentials in the Pulp Technologies and Systems IETS and International Coordination Workshop Conclusions 253 #12;INTERNATIONAL ENERGY

  12. ENERGY EFFICIENCY OPPORTUNITIES IN THE U.S. PULP AND PAPER INDUSTRY

    SciTech Connect (OSTI)

    Kramer, Klaas Jan; Masanet, Eric; Worrell, Ernst

    2009-01-01T23:59:59.000Z

    The U.S. pulp and paper industry consumes over $7 billion worth of purchased fuels and electricity per year. Energy efficiency improvement is an important way to reduce these costs and to increase predictable earnings, especially in times of high energy price volatility. There are a variety of opportunities available at individual plants in the U.S. pulp and paper industry to reduce energy consumption in a cost-effective manner. This paper provides a brief overview of the U.S. EPA ENERGY STAR(R) for Industry energy efficiency guidebook (a.k.a. the"Energy Guide") for pulp and paper manufacturers. The Energy Guide discusses a wide range of energy efficiency practices and energy-efficient technologies that can be implemented at the component, process, facility, and organizational levels. Also provided is a discussion of the trends, structure, and energy consumption characteristics of the U.S. pulp and paper industry along with a description of the major process technologies used within the industry. Many energy efficiency measure descriptions include expected savings in energy and energy-related costs, based on case study data from real-world applications in pulp and paper mills and related industries worldwide. The information in this Energy Guide is intended to help energy and plant managers in the U.S. pulp and paper industry reduce energy consumption in a cost-effective manner while maintaining the quality of products manufactured. Further research on the economics of all measures?as well as on their applicability to different production practices?is needed to assess their cost effectiveness at individual plants.

  13. Assessment, development, and testing of glass for blast environments.

    SciTech Connect (OSTI)

    Glass, Sarah Jill

    2003-06-01T23:59:59.000Z

    Glass can have lethal effects including fatalities and injuries when it breaks and then flies through the air under blast loading (''the glass problem''). One goal of this program was to assess the glass problem and solutions being pursued to mitigate it. One solution to the problem is the development of new glass technology that allows the strength and fragmentation to be controlled or selected depending on the blast performance specifications. For example the glass could be weak and fail, or it could be strong and survive, but it must perform reliably. Also, once it fails it should produce fragments of a controlled size. Under certain circumstances it may be beneficial to have very small fragments, in others it may be beneficial to have large fragments that stay together. The second goal of this program was to evaluate the performance (strength, reliability, and fragmentation) of Engineered Stress Profile (ESP) glass under different loading conditions. These included pseudo-static strength and pressure tests and free-field blast tests. The ultimate goal was to provide engineers and architects with a glass whose behavior under blast loading is less lethal. A near-term benefit is a new approach for improving the reliability of glass and modifying its fracture behavior.

  14. Time series of a CME blasting out from the Sun

    E-Print Network [OSTI]

    Christian, Eric

    #12;Time series of a CME blasting out from the Sun Composite image of the Sun in UV light with the naked eye, the Sun seems static, placid, constant. From the ground, the only notice- able variations in the Sun are its location (where will it rise and set today?) and its color (will clouds cover

  15. Columbia River Channel Improvement Project Rock Removal Blasting: Monitoring Plan

    SciTech Connect (OSTI)

    Carlson, Thomas J.; Johnson, Gary E.

    2010-01-29T23:59:59.000Z

    This document provides a monitoring plan to evaluate take as outlined in the National Marine Fisheries Service 2002 Biological Opinion for underwater blasting to remove rock from the navigation channel for the Columbia River Channel Improvement Project. The plan was prepared by the Pacific Northwest National Laboratory (PNNL) for the U.S. Army Corps of Engineers (USACE), Portland District.

  16. SCHOLARLY PAPERS Is Construction Blasting Still Abnormally Dangerous?

    E-Print Network [OSTI]

    SCHOLARLY PAPERS Is Construction Blasting Still Abnormally Dangerous? Timothy D. Stark, Ph.D., P an abnormally dangerous activity using the six factors presented in Section 520 of the Second Restatement to determine whether or not an activity is abnormally dangerous. DOI: 10.1061/ ASCE LA.1943-4170.0000037 CE

  17. Dynamics and stability of relativistic GRB blast waves

    E-Print Network [OSTI]

    Meliani, Z

    2010-01-01T23:59:59.000Z

    In gamma-ray-bursts (GRB), ultra-relativistic blast waves are ejected into the circumburst medium. We analyse in unprecedented detail the deceleration of a self-similar Blandford-McKee blast wave from a Lorentz factor 25 to the nonrelativistic Sedov phase. Our goal is to determine the stability properties of its frontal shock. We carried out a grid-adaptive relativistic 2D hydro-simulation at extreme resolving power, following the GRB jet during the entire afterglow phase. We investigate the effect of the finite initial jet opening angle on the deceleration of the blast wave, and identify the growth of various instabilities throughout the coasting shock front. We find that during the relativistic phase, the blast wave is subject to pressure-ram pressure instabilities that ripple and fragment the frontal shock. These instabilities manifest themselves in the ultra-relativistic phase alone, remain in full agreement with causality arguments, and decay slowly to finally disappear in the near-Newtonian phase as the...

  18. Processing automotive shredder fluff for a blast furnace injection

    E-Print Network [OSTI]

    Boyer, Edmond

    led to an optimized iron recovery of 78.5 % corresponding to an elemental iron content of 51 %, close to the ore grade required in a blast furnace. At the global scale of ELV recycling, these results entail an increase by 4 % of the fluff recycling rate, thus helping to meet the European requirements for 2015

  19. The economical use of standby equipment for a typical Kraft process pulp and paper mill

    E-Print Network [OSTI]

    Cox, Elmer Adrain

    1955-01-01T23:59:59.000Z

    for the pine system is about 350 tons of pulp per day. The ~Pa er Mill The Beater Room - In the beater room the paper making chemicals such as rosin, size, alum, and clay are added to the pulp in a mixing chest. Size is any substance which is added to a... it in on the supposition that it may do some good, Alum, used to denote aluminum sulphate, is used to precipitate the dissolved rosin in the size on the fibers of the paper. This is sometimes referred to as "setting" the size. Alum tends to make the paper hard...

  20. Dried Citrus Peel and Pulp as a Feed for Lactating Cows.

    E-Print Network [OSTI]

    Copeland, O. C. (Orlin Cephas); Shepardson, C. N. (Charles Noah)

    1944-01-01T23:59:59.000Z

    TEXAS AGRICULTURAL EXPERIMENT STATTnw A. B. CONNER, DIRECTOR, College Station, Texas I DRIED CITRUS PEEL AND PuLP As r FEED FOR LACTATING COWS 0. C. COPELAND AND C. N. SHEPARDSON Division of Dairy Husbandry AGRICULTURAL AND MECHANICAL... FEED FOR LACTATING COWS I 0. C. Copelandl and C. N. Shepardson" As a by-product of the citrus industry located in the lower Rio Grandc 1 Valley of Texas, there are considerable quantities of dehydrated citrus peel and pulp available as a feed...

  1. Coal combustion under conditions of blast furnace injection

    SciTech Connect (OSTI)

    Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

    1995-12-01T23:59:59.000Z

    Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal with particular reference to the coals from the Illinois Basin. Although this research is not yet completed the results to date support the following conclusions: (1) based on the results of computer modeling, lower rank bituminous coals, including coal from the Illinois Basin, compare well in their injection properties with a variety of other bituminous coals, although the replacement ratio improves with increasing rank; (2) based on the results of petrographic analysis of material collected from an active blast furnace, it is clear the coal derived char is entering into the raceway of the blast furnace; (3) the results of reactivity experiments on a variety of coal chars at a variety of reaction temperatures show that lower rank bituminous coals, including coal from the Illinois basin, yield chars with significantly higher reactivities in both air and CO{sub 2} than chars from higher rank Appalachian coals and blast furnace coke. These results indicate that the chars from the lower rank coals should have a superior burnout rate in the tuyere and should survive in the raceway environment for a shorter time. These coals, therefore, will have important advantages at high rates of injection that may overcome their slightly lower replacement rates.

  2. ANNUAL HEATING AND COOLING REQUIREMENTS AND DESIGN DAY PERFORMANCE FOR A RESIDENTIAL MODEL IN SIX CLIMATES: A COMPARISON OF NBSLD, BLAST 2, AND DOE-2.1

    E-Print Network [OSTI]

    Carroll, William L.

    2011-01-01T23:59:59.000Z

    Comparison of NBSLD, BLAST 2. and Effect of Selected Changessignificant effect on annual heating loads, BLAST 2 predictsComparison of NBSLD, BLAST 2, and DOE~2.1 Effect of Climate

  3. Determination of explosive blast loading equivalencies with an explosively driven shock tube

    SciTech Connect (OSTI)

    Jackson, Scott I [Los Alamos National Laboratory; Hill, Larry G [Los Alamos National Laboratory; Morris, John S [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    Recently there has been significant interest in evaluating the potential of many different non-ideal energetic materials to cause blast damage. We present a method intended to quantitatively compare the blast loading generated by different energetic materials through use of an explosively driven shock tube. The test explosive is placed at the closed breech end of the tube and initiated with a booster charge. The resulting shock waves are then contained and focused by the tube walls to form a quasi-one-dimensional blast wave. Pressure transducers along the tube wall measure the blast overpressure versus distance from the source and allow the use of the one-dimensional blast scaling relationship to determine the energy deposited into the blast wave per unit mass of test explosive. These values are then compared for different explosives of interest and to other methods of equivalency determination.

  4. Minimization of Blast furnace Fuel Rate by Optimizing Burden and Gas Distribution

    SciTech Connect (OSTI)

    Dr. Chenn Zhou

    2012-08-15T23:59:59.000Z

    The goal of the research is to improve the competitive edge of steel mills by using the advanced CFD technology to optimize the gas and burden distributions inside a blast furnace for achieving the best gas utilization. A state-of-the-art 3-D CFD model has been developed for simulating the gas distribution inside a blast furnace at given burden conditions, burden distribution and blast parameters. The comprehensive 3-D CFD model has been validated by plant measurement data from an actual blast furnace. Validation of the sub-models is also achieved. The user friendly software package named Blast Furnace Shaft Simulator (BFSS) has been developed to simulate the blast furnace shaft process. The research has significant benefits to the steel industry with high productivity, low energy consumption, and improved environment.

  5. 揥hat Efficiency Projects are Being Installed in the Pulp and Paper Industry

    E-Print Network [OSTI]

    Nicol, J.

    2008-01-01T23:59:59.000Z

    The Wisconsin Focus on Energy program has seven years of experience on the actual projects that are being installed in the Pulp and Paper industry. The program has a broad perspective on the types and trends of investments in energy efficiency...

  6. NOVEL LIGHTWEIGHT, HIGH-OPACITY PAPERS MADE FROM MECHANICAL PULPS1 John H. Klungness1

    E-Print Network [OSTI]

    Abubakr, Said

    5463, Madison, WI 53705 ABSTRACT Compared with direct loading of calcium carbonate fillers to chemical to precipitate calcium carbonate. Calcium carbonate is deposited within, on the surface of, and outside the pulp fibers, and is termed fiber-loaded precipitated calcium carbonate (FLPCC) (Fig. 1). As a result

  7. Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power Plants

    E-Print Network [OSTI]

    Hutcheon, James M.

    permits. To improve the aesthetic qualities of the effluent, coal ash (from local power plants_mill_discharge.jpg 2. Coal Power Plant http://www.csmonitor.com/var/ezflow_site/storage/images/media/images/2008Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power

  8. Minimizing Energy Costs Through Water Management in the Pulp and Paper Industry

    E-Print Network [OSTI]

    Wilson, P. H.

    The quantity of steam required by a pulp and paper mill, as well as the quantity of power generated can effectively be optimized by managing the water cycles in the mill. This approach addresses the process systems within the mill and investigates...

  9. Evaluation of heat flux through blast furnace shell with attached sensors

    SciTech Connect (OSTI)

    Han, J.W. [Kyonggi Univ., Suwon, Kyonggi (Korea, Republic of). Dept. of Materials Engineering; Lee, J.H.; Suh, Y.K. [POSCO, Kwangyang, Cheonnam (Korea, Republic of). Technical Research Labs.

    1996-12-31T23:59:59.000Z

    Plant trials to evaluate heat fluxes through a lining/cooling system of a blast furnace were conducted in order to realize the cooling efficiency of the blast furnace under operation. For this purpose, several experiments to measure the in-furnace gas temperatures were cautiously made, and numerical simulations for the temperature distributions over the blast furnace shell and cooling/lining systems were also carried out.

  10. Blast furnace injection of massive quantities of coal with enriched air or pure oxygen

    SciTech Connect (OSTI)

    Ponghis, N.; Dufresne, P.; Vidal, R.; Poos, A. (Center de Recherches Metallurgiques, Liege (Belgium))

    1993-01-01T23:59:59.000Z

    An extensive study of the phenomena associated with the blast furnace injection of massive quantities of coal is described. Trials with conventional lances or oxy-coal injectors and hot blast at different oxygen contents - up to 40% - or with cold pure oxygen were realized at coal to oxygen ratios corresponding to a range of 150 to 440 kg. Pilot scale rigs, empty or filled with coke, as well as industrial blast furnaces were utilized.

  11. Selective enrichment of a methanol-utilizing consortium using pulp & paper mill waste streams

    SciTech Connect (OSTI)

    Gregory R. Mockos; William A. Smith; Frank J. Loge; David N. Thompson

    2007-04-01T23:59:59.000Z

    Efficient utilization of carbon inputs is critical to the economic viability of the current forest products sector. Input carbon losses occur in various locations within a pulp mill, including losses as volatile organics and wastewater . Opportunities exist to capture this carbon in the form of value-added products such as biodegradable polymers. Waste activated sludge from a pulp mill wastewater facility was enriched for 80 days for a methanol-utilizing consortium with the goal of using this consortium to produce biopolymers from methanol-rich pulp mill waste streams. Five enrichment conditions were utilized: three high-methanol streams from the kraft mill foul condensate system, one methanol-amended stream from the mill wastewater plant, and one methanol-only enrichment. Enrichment reactors were operated aerobically in sequencing batch mode at neutral pH and 25癈 with a hydraulic residence time and a solids retention time of four days. Non-enriched waste activated sludge did not consume methanol or reduce chemical oxygen demand. With enrichment, however, the chemical oxygen demand reduction over 24 hour feed/decant cycles ranged from 79 to 89 %, and methanol concentrations dropped below method detection limits. Neither the non-enriched waste activated sludge nor any of the enrichment cultures accumulated polyhydroxyalkanoates (PHAs) under conditions of nitrogen sufficiency. Similarly, the non-enriched waste activated sludge did not accumulate PHAs under nitrogen limited conditions. By contrast, enriched cultures accumulated PHAs to nearly 14% on a dry weight basis under nitrogen limited conditions. This indicates that selectively-enriched pulp mill waste activated sludge can serve as an inoculum for PHA production from methanol-rich pulp mill effluents.

  12. Hot metal Si control at Kwangyang blast furnaces

    SciTech Connect (OSTI)

    Hur, N.S.; Cho, B.R.; Kim, G.Y.; Choi, J.S.; Kim, B.H. [POSCO, Cheollanamdo (Korea, Republic of). Kwangyang Works

    1995-12-01T23:59:59.000Z

    Studies of Si transfer in blast furnaces have shown that the Si level in pig iron is influenced more by the reaction of silicon oxide gas generation in the raceway than the chemical reaction between hot metal and slag at the drop zone. Specifications require a Si content of pig iron below 0.15% at the Kwangyang Works, but the use of soft coking coal in the blend for coke ovens, high pulverized coal injection rate into the blast furnace, and the application of lower grade iron ore has resulted in the need to develop methods to control Si in hot metal. In this paper, the results of in furnace Si control and the desiliconization skills at the casthouse floor are described.

  13. Simulation of the Reflected Blast Wave froma C-4 Charge

    SciTech Connect (OSTI)

    Howard, W M; Kuhl, A L; Tringe, J W

    2011-08-01T23:59:59.000Z

    The reflection of a blast wave from a C4 charge detonated above a planar surface is simulated with our ALE3D code. We used a finely-resolved, fixed Eulerian 2-D mesh (167 {micro}m per cell) to capture the detonation of the charge, the blast wave propagation in nitrogen, and its reflection from the surface. The thermodynamic properties of the detonation products and nitrogen were specified by the Cheetah code. A programmed-burn model was used to detonate the charge at a rate based on measured detonation velocities. Computed pressure histories are compared with pressures measured by Kistler 603B piezoelectric gauges at 8 ranges (GR = 0, 2, 4, 8, 10, and 12 inches) along the reflecting surface. Computed and measured waveforms and positive-phase impulses were similar, except at close-in ranges (GR < 2 inches), which were dominated by jetting effects.

  14. Biomass Program Monthly News Blast, October 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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  15. Biomass Program Monthly News Blast: May | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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  16. Biomass Program Monthly News Blast: November | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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  17. Biomass Program News Blast: September | Department of Energy

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  18. Biomass Program September 2012 News Blast | Department of Energy

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  19. August 2014 Monthly News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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  20. BETO Monthly News Blast, June 2013 | Department of Energy

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  1. Effect of N level on rice yield, nitrogen accumulation and rice blast occurrence under rice intercropping system

    E-Print Network [OSTI]

    Tang, Li; Lu, Guoli; Cu, Yiou; Zhang, Chaochun; Zhang, Fusuo; Zheng, Yi

    2009-01-01T23:59:59.000Z

    1 Effects of nitrogen levels on incidence of leaf blast andal. Effects of nitrogen and silicon nutrition on rice blastsame column. Effect of high N rate on rice blast High N rate

  2. Raceway behaviors in blast furnace with pulverized coal injection

    SciTech Connect (OSTI)

    Chung, J.K.; Han, J.W.; Cho, B.R. [POSCO, Cheollanamdo (Korea, Republic of)

    1995-12-01T23:59:59.000Z

    The blast furnace raceway shows different characteristics with PCR (pulverized coal injection rate). It was found in this study that with the increase of PCR the raceway depth decreases, and the size of birds nest and sometimes with liquid holdup, increases. Oxygen enrichment with co-axial lances was known to be very effective on the extension of raceway depth and size reduction of birds nest. It was also found that there are various factors which affect the coke properties at tuyere level of the blast furnace. Coke traveling time was calculated to be extended with PCR and it had a close relationship with the coke size in bosh. Coke mean size decreased with the increase of coke traveling time, that is, with the increase of PCR. Both DI (the strength of coke in cold) and CSR (the strength of coke after reaction) were also decreased with PCR. RAFT (Raceway Adiabatic Flame Temperature) had a tendency to be decreased with the increase of PCR, which is obtained by the estimation of coke temperature via XRD analysis. From the analysis of alkali contents in coke sampled along the radius of the blast furnace, it was understood that no difference in alkali contents between fine and lump coke represents that coke fines generated from upper burden might appear at tuyere level.

  3. Quantification of Liquid Holdup in the Dropping Zone of a Blast Furnace--A Cold Model Study

    E-Print Network [OSTI]

    .S. GUPTA and K. NAVEEN A two-dimensional cold model study, replicating an ironmaking blast furnace dropping

  4. 4.1 THE INTERACTION OF PULP MILL DISCHARGES WITH THE FRASER RIVER AND ITS SEDIMENTS by Bommanna G. Krishnappan

    E-Print Network [OSTI]

    discharges. Also, in the case of pulp mill discharges with a high biosolids concentration, the potential flocculation of biosolids with themselves and with the sediment particles in the river must be considered (see

  5. Engineering Study for a Full Scale Demonstration of Steam Reforming Black Liquor Gasification at Georgia-Pacific's Mill in Big Island, Virginia

    SciTech Connect (OSTI)

    Robert De Carrera; Mike Ohl

    2002-03-19T23:59:59.000Z

    Georgia-Pacific Corporation performed an engineering study to determine the feasibility of installing a full-scale demonstration project of steam reforming black liquor chemical recovery at Georgia-Pacific's mill in Big Island, Virginia. The technology considered was the Pulse Enhanced Steam Reforming technology that was developed and patented by Manufacturing and Technology Conversion, International (MTCI) and is currently licensed to StoneChem, Inc., for use in North America. Pilot studies of steam reforming have been carried out on a 25-ton per day reformer at Inland Container's Ontario, California mill and on a 50-ton per day unit at Weyerhaeuser's New Bern, North Carolina mill.

  6. BLAST2SRS, a web server for flexible retrieval of related protein sequences in the SWISS-PROT

    E-Print Network [OSTI]

    BLAST2SRS, a web server for flexible retrieval of related protein sequences in the SWISS similarity, with many public web servers available. However, with the increasingly large datasets available, BLAST2SRS (http://blast2srs.embl.de/) aims to meet this need. This server therefore combines the two

  7. Journal of Modern Mathematics Frontier Vol. 1 Iss. 4, November 2012 Computational Investigation of Blast-wave-

    E-Print Network [OSTI]

    Grujicic, Mica

    obtained clearly revealed that significant blast-mitigation effects can be achieved through the use of the air-vacated buffer concept and that the extent of the blast-mitigation effect is a sensitive function of Blast-wave- mitigation via the Use of Air-vacated Buffers M. Grujicic, J. S. Snipes, N. Chandrasekharan

  8. A discrete particle approach to simulate the combined effect of blast and sand impact loading of steel plates

    E-Print Network [OSTI]

    Wadley, Haydn

    A discrete particle approach to simulate the combined effect of blast and sand impact loading March 2011 Keywords: Blast loads Experimental tests Sand ejecta Discrete particles Numerical simulations a b s t r a c t The structural response of a stainless steel plate subjected to the combined blast

  9. Long term experiences of the use of duplex stainless steel to combat corrosion in the pulp and paper industry

    SciTech Connect (OSTI)

    Bendall, K.C. [Langley Alloys Ltd., Maidenhead (United Kingdom)

    1996-08-01T23:59:59.000Z

    Duplex (austenitic/ferritic) stainless steels offer properties of interest and a cost effective material selection solution for plant and equipment in the pulp and paper industry. The characteristics of duplex steels leading to successful long term applications of 22 Cr duplex and a copper containing 25 Cr super duplex stainless steel are reviewed. It is concluded that, applied correctly, two-phase stainless steels can provide long term reliable maintenance-free service in many pulp and paper plant environments.

  10. Advanced Materials and Processes, 2010, 168(3):32-33 Blast protection materials

    E-Print Network [OSTI]

    Gupta, Nikhil

    32 Advanced Materials and Processes, 2010, 168(3):32-33 Blast protection materials Nikhil Gupta1 and Kyu Cho2 1 Composite Materials and Mechanics Laboratory, Department of Mechanical and Aerospace Laboratory, Weapons and Materials Research Directorate, Aberdeen Proving Ground, MD 21005 Ballistic, blast

  11. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01T23:59:59.000Z

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  12. Performance Analysis of Coded V-BLAST with Optimum Power and Rate Allocation

    E-Print Network [OSTI]

    Loyka, Sergey

    propagation effect, a number of efforts have been reported to improve the perfor- mance of the uncoded V-BLASTPerformance Analysis of Coded V-BLAST with Optimum Power and Rate Allocation Victoria Kostina in the coded V-BLAST are studied analytically. Outage probabilities and system capacities of these strategies

  13. On-line measurement of lignin in wood pulp by color shift of fluorescence

    DOE Patents [OSTI]

    Jeffers, L.A.; Malito, M.L.

    1996-01-23T23:59:59.000Z

    Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroid method or a band ratio method. 6 figs.

  14. On-line measurement of lignin in wood pulp by color shift of fluorescence

    DOE Patents [OSTI]

    Jeffers, Larry A. (Washington Township, Stark County, OH); Malito, Michael L. (Liberty Township, Trumbull County, OH)

    1996-01-01T23:59:59.000Z

    Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroid method or a band ratio method.

  15. Energy Conservation Progress and Opportunities in the Pulp and Paper Industry

    E-Print Network [OSTI]

    Watkins, J. J.; Hunter, W. D.

    1984-01-01T23:59:59.000Z

    in the recovery boiler since evaporation of water occurs in the recovery boiler at a steam economy less than one while evaporation in the concentrators occurs at a steam economy of greater than two. Recovery Boiler Decrease unit heat losses The efficiency...? Increase pulp ma t consistency? Evaporation Decrease spills dilution Increase unit evaporation efficiency? Increase product concentration. Recovery Boiler Decrease excess combustion air Decrease sootblowing steam? Increase combustion air temperature...

  16. Recycling of water in bleached kraft pulp mills by using electrodialysis.

    SciTech Connect (OSTI)

    Fracaro, A. T.; Henry, M. P.; Pfromm, P.; Tsai, S.-P.

    1999-01-15T23:59:59.000Z

    Conservation of water in bleached kraft pulp mills by recycling the bleach plant effluent directly without treatment will cause accumulation of inorganic ''non-process elements'' (NPEs) and serious operational problems. In this work, an electrodialysis process is being developed for recycling the acidic bleach plant effluent of bleached kraft pulp mills. In this process, electrodialysis functions as a selective kidney to remove inorganic NPEs from bleach plant effluents, before they reach the recovery cycle. Acidic bleach plant effluents from several mills using bleaching sequences based on chlorine dioxide were characterized. The total dissolved solids were mostly inorganic NPEs. Sodium was the predominant cation and chloride was present at significant levels in all these effluents. In laboratory electrodialysis experiments, selective removal of chloride and potentially harmful cations, such as potassium, calcium, and magnesium, were removed efficiently. Rejection of organic compounds was up to 98%. Electrodialysis was shown to be resistant to membrane fouling and scaling, in a 100-hour laboratory experiment. Based on a model mill with 1,000 ton/day pulp production, the economic analysis suggests that the energy cost of electrodialysis is less than $200/day, and the capital cost of the stack is about $500,000.

  17. Blasting technology for modified in-situ oil shale retorts

    SciTech Connect (OSTI)

    Ricketts, T.E.

    1982-09-01T23:59:59.000Z

    Occidental Oil Shale, Inc., an equal partner with Tenneco Shale Oil Company in the Cathedral Bluffs Shale Oil Company, has spent since 1972 developing and demonstrating its modified in situ oil shale process at its Logan Wash mine near Debeque, Colorado. The Occidental modified in situ process consists of first mining out a limited amount of rock from within an underground retort volume to allow the explosive expansion of the surrounding rock into the mined void volumes. The explosive expansion forms a large underground rubble bed contained within a retort chamber which must contain a fairly uniform particle size distribution and void redistribution to provide reasonable oil recovery during subsequent in situ processing operations. The processing involves first igniting the top of the rubble pile and then injecting air into the top of the retort to drive the combustion front downward through the entire rubblized volume. The oil is continuously collected at the bottom of the retort during the processing. Two side-by-side commercial-sized retorts, Retorts 7 and 8, have recently been constructed at the Logan Wash mine using newly developed horizontal free-face blasting technology. Retorts 7 and 8 were blasted in February and April of 1981, respectively, each using nearly 550,000 lbs. of explosives in ANFO equivalent loaded within nearly 550 blastholes for each retort. The resulting rubble beds were about 230-ft high with cross-sections of approximately 27,225 ft/sup 2/. The blasting principles used to construct these commercial-sized retorts and the rubblization results are described in detail in this paper.

  18. The limitation of hearth sidewall wear at Redcar blast furnace

    SciTech Connect (OSTI)

    Parratt, J.E.

    1996-12-31T23:59:59.000Z

    The Redcar blast furnace with 14m hearth diameter was blown-in for its second campaign in August 1996. It is currently in its 10th year of operation and to date has produced just over 30 million tonnes. Current plans are to continue the second campaign to the year 2000 and beyond, producing over 40 million tonnes. In order to achieve this objective, any further wear on the lining, and in particular the hearth sidewall, needs to be minimized. This paper describes the present hearth design, the monitoring of hearth wear, the predicted wear profile, and the protection measures that have been taken or are being considered.

  19. A system for interpretation of blast furnace stockrod measurements

    SciTech Connect (OSTI)

    Hinnelae, J.; Saxen, H. [Aabo Akademi Univ. (Finland). Dept. of Chemical Engineering

    1997-12-31T23:59:59.000Z

    A system for intelligent monitoring and interpretation of signals from blast furnace stockrods is presented. The system visualizes the measurements and estimates the local burden layer thickness (under the rods) after every dump. Furthermore, it analyzes the burden descent rate to distinguish between slips, hangings, normal descent and peaks, etc., and also combines the stockrod information with findings of temperature measurements from an above-burden probe. The preprocessing of the signals and some features of the system, which is under development, are treated in this paper.

  20. Biomass Program Monthly News Blast: July | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergyDepartmentWindConversionResults in FirstBiomass ProgramBlast,July

  1. Biomass Program Monthly News Blast: October | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergyDepartmentWindConversionResults in FirstBiomassBlast: MayOctober

  2. Monthly News Blast: February 2013 | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagement of the NationalPennsylvania |February 2013 Monthly News Blast:

  3. Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in ManyDepartment ofOil'sEnergy8 * October 2006Optimizing Blast

  4. Biomass Program Monthly News Blast: August | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T, Inc.'s ReplyApplicationCommittee |FY14 BudgetDepartment09EnergyBlastMonthly

  5. BETO Monthly News Blast, August 2013r | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platform is alwaysISOSource1-01 Audit LetterYearAvi ShultzMonthly News Blast,

  6. Recent developments in blast furnace process control within British Steel

    SciTech Connect (OSTI)

    Warren, P.W. [British Steel Technical, Middlesbrough (United Kingdom). Teesside Labs.

    1995-12-01T23:59:59.000Z

    British Steel generally operates seven blast furnaces on four integrated works. All furnaces have been equipped with comprehensive instrumentation and data logging computers over the past eight years. The four Scunthorpe furnaces practice coal injection up to 170 kg/tHM (340 lb/THM), the remainder injecting oil at up to 100 kg/tHM (200 lb/THM). Distribution control is effected by Paul Wurth Bell-Less Tops on six of the seven furnaces, and Movable Throat Armour with bells on the remaining one. All have at least one sub burden probe. The blast furnace operator has a vast quantity of data and signals to consider and evaluate when attempting to achieve the objective of providing a consistent supply of hot metal. Techniques have been, and are being, developed to assist the operator to interpret large numbers of signals. A simple operator guidance system has been developed to provide advice, based on current operating procedures and interpreted data. Further development will involve the use of a sophisticated Expert System software shell.

  7. Single taphole blast furnace casthouse performance optimizing cost and availability

    SciTech Connect (OSTI)

    Fowles, R.D.; Searls, J.B.; Peay, W.R. [Geneva Steel, Provo, UT (United States); Brenneman, R.G.

    1995-12-01T23:59:59.000Z

    The No. 2 blast furnace is a single taphole furnace with a convection air-cooled iron trough. The iron runner system is designed to fill four 90 ton open-top ladles per cast, which are transported by locomotive to the steel shop. The slag runner system is capable of filling three 800 ft{sup 3} slag pots per cast. The No. 2 blast furnace was blown in from mini-reline with this new casthouse configuration in early December 1991. It was operated for nearly three years until it was banked for planned stove repairs and a trough rebuild in late September 1994. During this period, the furnace produced just over 2.5 million tons of hot metal across the original trough refractory lining system, with 13 intermediate hot patch castable repairs. The entire casthouse refractory usage (main trough, runner systems, and covers) during this campaign was 1.06 pounds per net ton of hot metal. Investigation of the lining during demolition indicated that the trough lining campaign could have been extended to at least 3.0 million tons. This paper will discuss how operating practices, mechanical design, refractory design, maintenance philosophy, and attention to detail synergistically contributed to the long campaign life and low refractory consumption rate.

  8. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

    1995-12-01T23:59:59.000Z

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  9. Model of the radial distribution of gas in the blast furnace

    SciTech Connect (OSTI)

    Nikus, M.; Saxen, H. [Aabo Akademi Univ. (Finland). Dept. of Chemical Engineering

    1996-12-31T23:59:59.000Z

    This paper describes an on-line model for estimating the radial gas distribution in blast furnaces. The model is based on molar and energy flow balances for the blast furnace throat region, and utilizes the top gas temperature and gas temperature measurements from a fixed above-burden probe. The distribution of the gas flux is estimated by a Kalman filter. The method is illustrated to capture short-term dynamics and to detect sudden major changes in the gas distribution in Finnish blast furnace.

  10. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01T23:59:59.000Z

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  11. Histone deacetylase inhibitors epigenetically promote reparative events in primary dental pulp cells

    SciTech Connect (OSTI)

    Duncan, Henry F., E-mail: Hal.Duncan@dental.tcd.ie [Division of Restorative Dentistry and Periodontology, Dublin Dental University Hospital, Trinity College Dublin, Lincoln Place, Dublin 2 (Ireland); Smith, Anthony J. [Oral Biology, School of Dentistry, College of Medical and Dental Sciences, University of Birmingham, Birmingham (United Kingdom); Fleming, Garry J.P. [Material Science Unit, Division of Oral Biosciences, Dublin Dental University Hospital, Trinity College Dublin, Dublin (Ireland); Cooper, Paul R. [Oral Biology, School of Dentistry, College of Medical and Dental Sciences, University of Birmingham, Birmingham (United Kingdom)

    2013-06-10T23:59:59.000Z

    Application of histone deacetylase inhibitors (HDACi) to cells epigenetically alters their chromatin structure and induces transcriptional and cellular reparative events. This study investigated the application of two HDACi, valproic acid (VPA) and trichostatin A (TSA) on the induction of repair-associated responses in primary dental pulp cell (DPC) cultures. Flow cytometry demonstrated that TSA (100 nM, 400 nM) significantly increased cell viability. Neither HDACi was cytotoxic, although cell growth analysis revealed significant anti-proliferative effects at higher concentrations for VPA (>0.5 mM) and TSA (>50 nM). While high-content-analysis demonstrated that HDACi did not significantly induce caspase-3 or p21 activity, p53-expression was increased by VPA (3 mM, 5 mM) at 48 h. HDACi-exposure induced mineralization per cell dose-dependently to a plateau level (VPA-0.125 mM and TSA-25 nM) with accompanying increases in mineralization/dentinogenic-associated gene expression at 5 days (DMP-1, BMP-2/-4, Nestin) and 10 days (DSPP, BMP-2/-4). Both HDACis, at a range of concentrations, significantly stimulated osteopontin and BMP-2 protein expression at 10 and 14 days further supporting the ability of HDACi to promote differentiation. HDACi exert different effects on primary compared with transformed DPCs and promote mineralization and differentiation events without cytotoxic effects. These novel data now highlight the potential in restorative dentistry for applying low concentrations of HDACi in vital pulp treatment. -- Highlights: Valproic acid and trichostatin A promoted mineralization in primary pulp cells. Cell viability, apoptosis, caspase-3, p21 unaltered; p53 increased by valproic acid. Trichostatin A increased cell viability at 24 h at selected concentrations. Altered cell toxicity and differentiation between primary and transformed cells. HDACi-induced the differentiation marker proteins osteopontin and BMP-2.

  12. Development and pilot testing of modular dynamic thermomechanical pulp mill model to develop energy reduction strategies. Final report

    SciTech Connect (OSTI)

    Coffin, D.W.

    1996-10-01T23:59:59.000Z

    With the development of on-line and real-time process simulations, one obtains the ability to predict and control the process; thus, the opportunity exists to improve energy efficiency, decrease materials wastes, and maintain product quality. Developing this capability was the objective of the this research program. A thermomechanical pulp mill was simulated using both a first principles model and a neural network. The models made use of actual process data and a model that calculated the mass and energy balance of the mill was successfully implemented and run at the mill on an hourly basis. The attempt to develop a model that accurately predicted the quality of the pulp was not successful. It was concluded that the key fro a successful implementation of a real-time control model, such as a neural net model, is availability of on-line sensors that sufficiently characterize the pulp.

  13. Pulp and paper mill of the future: A workshop. Final report

    SciTech Connect (OSTI)

    Fleischman, E. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Sobczynski, S.F. [USDOE Assistant Secretary for Energy Efficiency and Renewable Energy, Washington, DC (United States). Office of Industrial Technologies

    1993-10-01T23:59:59.000Z

    This workshop began with sessions to consider where the industry is likely to be, or ideally where it should be, say, by the year 2020. The next sessions considered the `drivers` that motivate the industry to change. These drivers could be motivations towards the vision developed earlier, or they may be forces that tend to prevent the vision of the future form being realized. The final sessions focused on what techniques are being (or should be) developed in four major process areas of a typical manufacturing plant, consistent with the previously identified vision of a future pulp or paper mill.

  14. Yield Improvement and Energy Savings Uing Phosphonates as Additives in Kraft pulping

    SciTech Connect (OSTI)

    Ulrike W. Tschirner; Timothy Smith

    2007-03-31T23:59:59.000Z

    Project Objective: Develop a commercially viable modification to the Kraft process resulting in energy savings, increased yield and improved bleachability. Evaluate the feasibility of this technology across a spectrum of wood species used in North America. Develop detailed fundamental understanding of the mechanism by which phosphonates improve KAPPA number and yield. Evaluate the North American market potential for the use of phosphonates in the Kraft pulping process. Examine determinants of customer perceived value and explore organizational and operational factors influencing attitudes and behaviors. Provide an economic feasibility assessment for the supply chain, both suppliers (chemical supply companies) and buyers (Kraft mills). Provide background to most effectively transfer this new technology to commercial mills.

  15. Search for pre-existing Delta states at BLAST from 睭(e,e'[Delta]??

    E-Print Network [OSTI]

    Greene Chana M. (Chana Michelle)

    2006-01-01T23:59:59.000Z

    At the MIT-Bates Linear Accelerator Center a comprehensive study of low-Q2 spin-dependent electron scattering from deuterium has been carried out using the Bates Large Acceptance Spectrometer Toroid (BLAST). This experiment ...

  16. Titanium addition practice, and maintenance for the hearths in AHMSA`s blast furnaces

    SciTech Connect (OSTI)

    Boone, A.G.; Jimenez, G.; Castillo, J. [Altos Hornos de Mexico, Monclova (Mexico)

    1997-12-31T23:59:59.000Z

    Altos Hornos de Mexico (AHMSA) is a steel company located in Northern Mexico, in the state of Coahuila. Currently there are three blast furnaces in operation and one more about to finish its general repair. This last one is to remain as a back-up unit. Because of blast furnace hearth wear outs AHMSA has developed some maintenance procedures. These procedures are based on titanium ore additions and hearth thermic control monitoring. There are also some other maintenance practices adopted to the working operations to assure that such operations detect and avoid in time hearth wear outs that place personnel and/or the unit in danger (due to hearth leaks). This paper describes titanium ore addition to No. 2 blast furnace during the final campaign and it also illustrates maintenance practices and continuous monitoring of temperature trends both of which were implemented at AHMSA`s No. 5 blast furnace.

  17. Optimization of ferrous burden high temperature properties to meet blast furnace requirements in British Steel

    SciTech Connect (OSTI)

    Bergstrand, R.

    1996-12-31T23:59:59.000Z

    The high temperature properties of ferrous burden materials have long been an important consideration in the operation of British Steel blast furnaces. Previous research presented at this conference has shown that the behavior of materials in the lower stack and bosh can have a significant effect on furnace permeability and stability of operation. However, with increasing levels of hydrocarbon injection via the tuyeres, the reduction conditions inside British Steel blast furnaces have significantly altered over recent years. This paper focuses on the further work that has been undertaken to study the effect on ferrous burden high temperatures properties of the widely differing reduction regimes which can be experienced in today`s blast furnaces. The implications of the findings, and how they have been used in optimizing blast furnace operation and burden quality, are discussed.

  18. BLAST FURNACE GRANULAR COAL INJECTION SYSTEM. Final Report Volume 2: Project Performance and Economics

    SciTech Connect (OSTI)

    Unknown

    1999-10-01T23:59:59.000Z

    Bethlehem Steel Corporation (BSC) requested financial assistance from the Department of Energy (DOE), for the design, construction and operation of a 2,800-ton-per-day blast furnace granulated coal injection (BFGCI) system for two existing iron-making blast furnaces. The blast furnaces are located at BSC's facilities in Burns Harbor, Indiana. The demonstration project proposal was selected by the DOE and awarded to Bethlehem in November 1990. The design of the project was completed in December 1993 and construction was completed in January 1995. The equipment startup period continued to November 1995 at which time the operating and testing program began. The blast furnace test program with different injected coals was completed in December 1998.

  19. Fluid-filled helmet liner concept for protection against blast-induced traumatic brain injury

    E-Print Network [OSTI]

    Yost, Allison L. (Allison Lynne)

    2012-01-01T23:59:59.000Z

    Due to changes in modem warfare threats, as well as advances in body armor, soldier survivability in combat has increased, but blast-induced Traumatic Brain Injury (TBI) has become a prevalent injury in the battlefield. ...

  20. The design and retrofit of buildings for resistance to blast-induced progressive collapse

    E-Print Network [OSTI]

    Abbott Galv鉶 Sobreira Lopes, Isabel

    2009-01-01T23:59:59.000Z

    In recent years, concern has risen drastically regarding the suitability of structural design for blast resistance. Historic events have proven that buildings that are designed in compliance with conventional building codes ...

  1. Hearth monitoring experiences at Dofasco`s No. 4 blast furnace

    SciTech Connect (OSTI)

    Stothart, D.W.; Chaykowski, R.D.; Donaldson, R.J.; Pomeroy, D.H.

    1997-12-31T23:59:59.000Z

    As a result of a 1994 taphole breakout at Dofasco`s No. 4 Blast Furnace, extensive effort has gone into monitoring, understanding and controlling hearth wear. This paper reviews the hearth monitoring system developed and the various hearth operating and maintenance techniques used to ensure No. 4 Blast Furnace safely reaches its 1998 reline date. The impact of changes in coke quality, productivity, casting practice and leaking cooling members on hearth refractory temperature fluctuations will also be examined.

  2. Close-in blasting at the TRI-MET light rail tunnels in Portland, Oregon

    SciTech Connect (OSTI)

    Revey, G.F.; Painter, D.Z.

    1995-12-31T23:59:59.000Z

    Frontier/Traylor Joint Venture is presently constructing a section of the Tri-County Metropolitan Transit District of Oregon`s (TRI-MET) Westside Light Rail System. This new section will extend Portland`s existing transit system to the western suburbs of Beaverton and Hillsboro. The drill-blast excavations at this project include 10,000 feet of 20 foot tunnel, 18 cross passages, three shafts, an underground railway station, and a U-wall open cut. From a blast designer`s perspective, this job has been extremely challenging. Blast vibration is limited to 0.5 ips at 200 feet or at the nearest structure, and airblast is limited to 129 dB--linear peak and 96 dB--C scale. The tunnels pass under heavily built up areas and have top of tunnel to surface cover distances as low as 70 feet. Surface blasting in the 26,000 cubic yard U-wall excavation was limited to five short nighttime periods due to its proximity to the very busy highway 26. This paper describes the techniques that were used to develop safe blasting designs for the TRI-MET Surface blasts and tunnel rounds. It also discusses the measures that were necessary to mitigate noise, vibration, and flyrock.

  3. Oxy-acetylene driven laboratory scale shock tubes for studying blast wave effects

    E-Print Network [OSTI]

    Courtney, Michael

    2011-01-01T23:59:59.000Z

    Instrumentation is needed to produce realistic blast waves in a laboratory setting. This paper describes the development and characterization of oxy-acetylene driven, laboratory scale shock tubes for use in studying blast injury, candidate armor materials, and material properties at blast loading rates. The pressure-time profiles show a true shock front and exponential decay characteristic of blast waves and have relevant durations. The modular design includes shock tube diameters of 27 mm and 41 mm, and a selection of peak pressures from 204 kPa to 920 kPa can be produced by selection of the driver section diameter and placement of the test sample. Characterization studies of several driver/driven section combinations showed consistent results, with peak pressures having 0.8 - 6.9 percent uncertainty in the mean. This shock tube design provides a more realistic blast profile than current air-driven shock tubes. In addition, operation does not require specialized personnel or facilities like most blast-driven...

  4. Low frequency long duration blast vibrations and their effect on residential structures

    SciTech Connect (OSTI)

    Roy, M.P.; Sirveiya, A.K.; Singh, P.K. [Central Mining Research Institute, Dhanbad (India). Blasting Dept.

    2005-07-01T23:59:59.000Z

    A study was conducted at a coal mine in India which produces 10 million tonne of coal and 27 million cubic meter of overburden per annum. Detonation of 100 tonnes of explosives in a blasting round is a common practice of the mine. These large sized blasts often led to complaints from the nearby inhabitants regarding ground vibrations and their affects on their houses. Eighteen dragline blasts were conducted and their impacts on nearby structures were investigated. Extended seismic arrays were used to identify the vibration characteristics within a few tens of meters of the blasts and also as modified by the media at distances over 5 km. 10 to 12 seismographs were deployed in an array to gather the time histories of vibrations. A signature blast was conducted to know the fundamental frequency of the particular transmitting media between the blast face and the structures. The faster decay of high frequency components was observed. It was also observed that at distances of 5 km, the persistence of vibrations in the structures was substantially increased by more than 10 seconds. The proximity of the frequency of the ground vibration to the structure's fundamental frequencies produced the resonance in the structures. On the basis of the fundamental frequency of the structures, the delay interval was optimized, which resulted in lower amplitude and reduced persistence of vibration in the structures. 9 refs., 10 figs., 2 tabs.

  5. Operational considerations for high level blast furnace fuel injection

    SciTech Connect (OSTI)

    Poveromo, J.J. [Quebec Cartier Mining Co., Bethlehem, PA (United States)

    1996-12-31T23:59:59.000Z

    Injection levels of over 400 lbs/NTHM for coal, over 250 lbs/NTHM for natural gas and over 200 lbs/NTHM for oil have been achieved. Such high levels of fuel injection has a major impact on many aspects of blast furnace operation. In this paper the author begins by reviewing the fundamentals of fuel injection with emphasis on raceway thermochemical phenomena. The operational impacts which are generic to high level injection of any injectant are then outlined. The author will then focus on the particular characteristics of each injectant, with major emphasis on coal and natural gas. Operational considerations for coping with these changes and methods of maximizing the benefits of fuel injection will be reviewed.

  6. Radiative precursors driven by converging blast waves in noble gases

    SciTech Connect (OSTI)

    Burdiak, G. C.; Lebedev, S. V.; Harvey-Thompson, A. J.; Swadling, G. F.; Suzuki-Vidal, F.; Hall, G. N.; Khoory, E.; Pickworth, L.; Bland, S. N.; Grouchy, P. de; Skidmore, J.; Suttle, L.; Bennett, M.; Niasse, N. P. L. [Blackett Laboratory, Imperial College London SW7 2BW (United Kingdom)] [Blackett Laboratory, Imperial College London SW7 2BW (United Kingdom); Williams, R. J. R. [Atomic Weapons Establishment, Aldermaston RG7 4PR (United Kingdom)] [Atomic Weapons Establishment, Aldermaston RG7 4PR (United Kingdom); Blesener, K.; Atoyan, L.; Cahill, A.; Hoyt, C.; Potter, W. [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States)] [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States); and others

    2014-03-15T23:59:59.000Z

    A detailed study of the radiative precursor that develops ahead of converging blast waves in gas-filled cylindrical liner z-pinch experiments is presented. The experiment is capable of magnetically driving 20?km s{sup ?1} blast waves through gases of densities of the order 10{sup ?5} g cm{sup ?3} (see Burdiak et al. [High Energy Density Phys. 9(1), 5262 (2013)] for a thorough description). Data were collected for Ne, Ar, and Xe gas-fills. The geometry of the setup allows a determination of the plasma parameters both in the precursor and across the shock, along a nominally uniform line of sight that is perpendicular to the propagation of the shock waves. Radiation from the shock was able to excite NeI, ArII, and XeII/XeIII precursor spectral features. It is shown that the combination of interferometry and optical spectroscopy data is inconsistent with upstream plasmas being in LTE. Specifically, electron density gradients do not correspond to any apparent temperature change in the emission spectra. Experimental data are compared to 1D radiation hydrodynamics HELIOS-CR simulations and to PrismSPECT atomic physics calculations to assist in a physical interpretation of the observations. We show that upstream plasma is likely in the process of being radiatively heated and that the emission from a small percentage of ionised atoms within a cool background plasma dominates the emission spectra. Experiments were carried out on the MAGPIE and COBRA pulsed-power facilities at Imperial College London and Cornell University, respectively.

  7. On the conversion of blast wave energy into radiation in active galactic nuclei and gamma-ray bursts

    E-Print Network [OSTI]

    Martin Pohl; Reinhard Schlickeiser

    1999-11-24T23:59:59.000Z

    It has been suggested that relativistic blast waves may power the jets of AGN and gamma-ray bursts (GRB). We address the important issue how the kinetic energy of collimated blast waves is converted into radiation. It is shown that swept-up ambient matter is quickly isotropised in the blast wave frame by a relativistic two-stream instability, which provides relativistic particles in the jet without invoking any acceleration process. The fate of the blast wave and the spectral evolution of the emission of the energetic particles is therefore solely determined by the initial conditions. We compare our model with existing multiwavelength data of AGN and find remarkable agreement.

  8. Digestion ruminale compare du son et de la pulpe de betteraves chez le mouton et la vache

    E-Print Network [OSTI]

    Boyer, Edmond

    Digestion ruminale compar閑 du son et de la pulpe de betteraves chez le mouton et la vache M (*) Laboratoire des Aliments (**) Laboratoire de la Digestion l.N.R.A., Theix, 63122 Ceyrat, France. Summary. Ruminal digestion was compared in cows and sheep receiving ad libitum 40 % hay and 60 % wheat bran or beet

  9. ANNUAL HEATING AND COOLING REQUIREMENTS AND DESIGN DAY PERFORMANCE FOR A RESIDENTIAL MODEL IN SIX CLIMATES: A COMPARISON OF NBSLD, BLAST 2, AND DOE-2.1

    E-Print Network [OSTI]

    Carroll, William L.

    2011-01-01T23:59:59.000Z

    COMPARISON - HOURLY INTERNAL LOAD PROFILES LightingA Comparison of NBSLD, BLAST 2. and DOE-2.1 (b) Lighting:

  10. Safer blasting agents and procedures for blasting in gassy non-coal mines. [Quarterly] technical progress report, January 1--March 31, 1993

    SciTech Connect (OSTI)

    Weiss, E.S.

    1993-11-01T23:59:59.000Z

    The US Bureau of Mines` research program is focused on developing procedures and guidelines for acceptable underground oil shale blasting that fulfill the operational requirements for efficiency while maintaining a high level of safety when operating under gassy mine conditions. This work is aimed at providing new information, alternate methods, and innovation in underground blasting procedures. The results from this research will have direct impact on regulatory standards for blasting under gassy mine conditions. Based on the low incendivity data from the Cannon Gallery and several months of recent testing in their mine, Kennecott`s Greens Creek base metal mine in Alaska had decided to exclusively use a low incendive bulk emulsion product in place of the low incendive water gel prod ct for all blasting operations. As was the case with the low incendive water gel product, the use of this bulk product resulted in: no dust ignitions and related injuries and/or production/equipment losses; the elimination if preblasting measures of using stemming and water sprays, and the improvement of roadways due to the reduction of water.

  11. IEEE TRANSACTIONS ON WIRELESS COMMUNICATIONS, VOL. 7, NO. 10, OCTOBER 2008 1 On Outage and Error Rate Analysis of the Ordered V-BLAST

    E-Print Network [OSTI]

    Loyka, Sergey

    is a manifestation of the space-time autocoding effect in the V-BLAST. While the sub-optimal ordering (based evaluated. Index Terms-- Multi-antenna (MIMO) system, V-BLAST, per- formance analysis, autocoding effect I Rate Analysis of the Ordered V-BLAST Sergey Loyka, Senior Member, IEEE, and Francois Gagnon, Senior

  12. Changing Trends in the Bulk Chemicals and Pulp and Paper Industries (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01T23:59:59.000Z

    Compared with the experience of the 1990s, rising energy prices in recent years have led to questions about expectations of growth in industrial output, particularly in energy-intensive industries. Given the higher price trends, a review of expected growth trends in selected industries was undertaken as part of the production of Annual Energy Outlook 2005 (AEO). In addition, projections for the industrial value of shipments, which were based on the Standard Industrial Classification (SIC) system in AEO2004, are based on the North American Industry Classification System (NAICS) in AEO2005. The change in industrial classification leads to lower historical growth rates for many industrial sectors. The impacts of these two changes are highlighted in this section for two of the largest energy-consuming industries in the U.S. industrial sector-bulk chemicals and pulp and paper.

  13. Ten case history studies of energy efficiency improvements in pulp and paper mills. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    The ten technologies chosen for case history development are: sonic sootblowing in boilers, boiler operation on oil-water emulsified fuel, energy efficient motors, computerized control of excess air for boilers, boiler control and load allocation, driving of waste-activated sludge by multiple effect evaporation, pre-drying of hog fuel, lime kiln computerization, heat wheel for process heat recovery, and organic Rankine bottoming cycle for thermomechanical pulping heat recovery. For each case study, there is given: the company name, employee contact, plant summary, a description of the energy consuming process and of the energy-saving action, an assessment of energy savings, and the decision process leading to the adoption of the measure. A data summary for discounted cash flow analysis is tabulated for each case. (LEW)

  14. Recovery Act: ArcelorMittal USA Blast Furnace Gas Flare Capture

    SciTech Connect (OSTI)

    Seaman, John

    2013-01-14T23:59:59.000Z

    The U.S. Department of Energy (DOE) awarded a financial assistance grant under the American Recovery and Reinvestment Act of 2009 (Recovery Act) to ArcelorMittal USA, Inc. (ArcelorMittal) for a project to construct and operate a blast furnace gas recovery boiler and supporting infrastructure at ArcelorMittal抯 Indiana Harbor Steel Mill in East Chicago, Indiana. Blast furnace gas (BFG) is a by-product of blast furnaces that is generated when iron ore is reduced with coke to create metallic iron. BFG has a very low heating value, about 1/10th the heating value of natural gas. BFG is commonly used as a boiler fuel; however, before installation of the gas recovery boiler, ArcelorMittal flared 22 percent of the blast furnace gas produced at the No. 7 Blast Furnace at Indiana Harbor. The project uses the previously flared BFG to power a new high efficiency boiler which produces 350,000 pounds of steam per hour. The steam produced is used to drive existing turbines to generate electricity and for other requirements at the facility. The goals of the project included job creation and preservation, reduced energy consumption, reduced energy costs, environmental improvement, and sustainability.

  15. Process control techniques at the blast furnaces of Thyssen Stahl AG

    SciTech Connect (OSTI)

    Kowalski, W.; Bachhofen, H.J.; Beppler, E.; Kreibich, K.; Muelheims, K.; Peters, M.; Wieters, C.U. [Thyssen Stahl AG, Duisburg (Germany)

    1995-12-01T23:59:59.000Z

    Process improvements, capacity increases and the use of modern measuring and process control techniques have helped to ensure that the blast furnace will remain an indispensable means of supplying steelworks with hot metal until well into the next century. The survival of a future-oriented company such as Thyssen Stahl AG depends on long-term improvements in economic viability. Today, Thyssen Stahl AG operates two blast furnace plants comprising a total of five blast furnaces with hearth diameters ranging from 9.3 to 14.9m. This choice of furnaces permits flexible adjustment to changing workload situations and enables about ten million tons of hot metal to be produced each year. The wide range of measuring devices specially fitted on Schwelgern blast furnace No. 1 made a vital contribution to the development of blast furnace models. The purpose of these models was to make a general assessment of the state of the furnace and so create an objective basis for furnace operation. The paper describes the development of these measuring techniques and process model and the application of the model.

  16. A Feasibility Study for Recycling Used Automotive Oil Filters In A Blast Furnace

    SciTech Connect (OSTI)

    Ralph M. Smailer; Gregory L. Dressel; Jennifer Hsu Hill

    2002-01-21T23:59:59.000Z

    This feasibility study has indicated that of the approximately 120,000 tons of steel available to be recycled from used oil filters (UOF's), a maximum blast furnace charge of 2% of the burden may be anticipated for short term use of a few months. The oil contained in the most readily processed UOF's being properly hot drained and crushed is approximately 12% to 14% by weight. This oil will be pyrolized at a rate of 98% resulting in additional fuel gas of 68% and a condensable hydrocarbon fraction of 30%, with the remaining 2% resulting as carbon being added into the burden. Based upon the writer's collected information and assessment, there appears to be no operational problems relating to the recycling of UOF's to the blast furnace. One steel plant in the US has been routinely charging UOF's at about 100 tons to 200 tons per month for many years. Extensive analysis and calculations appear to indicate no toxic consideration as a result of the pyrolysis of the small contained oil ( in the 'prepared' UOFs) within the blast furnace. However, a hydrocarbon condensate in the ''gasoline'' fraction will condense in the blast furnace scrubber water and may require additional processing the water treatment system to remove benzene and toluene from the condensate. Used oil filters represent an additional source of high quality iron units that may be effectively added to the charge of a blast furnace for beneficial value to the operator and to the removal of this resource from landfills.

  17. UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation Into the Wheat Straw Paper

    E-Print Network [OSTI]

    pulping is the black liquor residue. Regarding the black liquor, a by-product of wheat straw pulping, Vibratory Shear Enhanced Process (VSEP) shows that lignin and hemicelluloses can be extracted from the blackUBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation

  18. Design Considerations For Blast Loads In Pressure Vessels.

    SciTech Connect (OSTI)

    Rodriguez, E. A. (Edward A.); Nickell, Robert E.; Pepin, J. E. (Jason E.)

    2007-01-01T23:59:59.000Z

    Los Alamos National Laboratory (LANL), under the auspices of the U.S. Department of Energy (DOE) and the National Nuclear Security Administration (NNSA), conducts confined detonation experiments utilizing large, spherical, steel pressure vessels to contain the reaction products and hazardous materials from high-explosive (HE) events. Structural design and analysis considerations include: (a) Blast loading phase (i.e., impulsive loading); (b) Dynamic structural response; (c) Fragment (i.e., shrapnel) generation and penetration; (d) Ductile and non-ductile fracture; and (e) Design Criteria to ASME Code Sec. VIII, Div. 3, Impulsively Loaded Vessels. These vessels are designed for one-time-use only, efficiently utilizing the significant plastic energy absorption capability of ductile vessel materials. Alternatively, vessels may be designed for multiple-detonation events, in which case the material response is restricted to elastic or near-elastic range. Code of Federal Regulations, Title 10 Part 50 provides requirements for commercial nuclear reactor licensing; specifically dealing with accidental combustible gases in containment structures that might cause extreme loadings. The design philosophy contained herein may be applied to extreme loading events postulated to occur in nuclear reactor and non-nuclear systems or containments.

  19. LTC vacuum blasting machine (metal): Baseline report; Summary

    SciTech Connect (OSTI)

    NONE

    1997-07-31T23:59:59.000Z

    The LTC coating removal system consists of several hand tools such as a Roto Peen scaler and a needlegun. They are designed to remove coatings from steel, concrete, brick, and wood. These are used with the LTC PTC-6 vacuum system to capture dust and debris as removal of the coating takes place. The PTC-6 is a vacuum system designed to be used with surface decontamination equipment. Dust and debris are captured by a high efficiency particulate filter (HEPA) vacuum system that deposits the waste directly into an on-board 23-gallon waste drum. The PTC-6 utilizes compressed air delivered from a source via an air hose connected to the air inlet to drive the hand held power tools. The control panel regulated the air pressure delivered to the tool. A separate compressed air flow powers the vacuum generator. The vacuum hoses connect the power tools to the dust chamber, returning paint chips and dust from the surface. A third compressed air flow is used to clean filters by pulsing air through a pipe with slots. The blasts of air shake dust and debris from the filter fabric.

  20. A Blast Wave from the 1843 Eruption of Eta Carinae

    E-Print Network [OSTI]

    Nathan Smith

    2008-09-09T23:59:59.000Z

    Very massive stars shed much of their mass in violent precursor eruptions as luminous blue variables (LBVs) before reaching their most likely end as supernovae, but the cause of LBV eruptions is unknown. The 19th century eruption of Eta Carinae, the prototype of these events, ejected about 12 solar masses at speeds of 650 km/s, with a kinetic energy of almost 10^50 ergs. Some faster material with speeds up to 1000-2000 km/s had previously been reported but its full distribution was unknown. Here I report observations of much faster material with speeds up to 3500-6000 km/s, reaching farther from the star than the fastest material in earlier reports. This fast material roughly doubles the kinetic energy of the 19th century event, and suggests that it released a blast wave now propagating ahead of the massive ejecta. Thus, Eta Car's outer shell now mimics a low-energy supernova remnant. The eruption has usually been discussed in terms of an extreme wind driven by the star's luminosity, but fast material reported here suggests that it was powered by a deep-seated explosion rivalling a supernova, perhaps triggered by the pulsational pair instability. This may alter interpretations of similar events seen in other galaxies.

  1. Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Quarterly report, October--December 1996

    SciTech Connect (OSTI)

    Frederick, W.J.; Laver, M.L.; Rorrer, G.L.

    1996-12-31T23:59:59.000Z

    A portion of each filtrate sample was freeze-dried and the resulting solids were analyzed for ash content. Adsorption experiments with calcium and barium were carried at 70{degrees}C in a temperature controlled incubator under continuous mixing in order to simulate the environment experienced by brownstock as it moves through the Q stage. In the calcium experiments, it was difficult to accurately determine the calcium adsorbed on the pulp by measuring the depletion of calcium in the aqueous phase. Consequently, the technique was modified. In the modified technique, the calcium-adsorbed pulp is acid washed again to release the calcium. The calcium concentration in the washings is measured, and the calcium adsorbed on the pulp is estimated by material balance. Measurement of calcium adsorption on the brownstock pulp fibers from the L-P/Samoa mill have been obtained.

  2. Skull flexure from blast waves: a mechanism for brain injury with implications for helmet design

    SciTech Connect (OSTI)

    Moss, W C; King, M J; Blackman, E G

    2009-04-14T23:59:59.000Z

    Traumatic brain injury [TBI] has become a signature injury of current military conflicts. The debilitating effects of TBI are long-lasting and costly. Although the mechanisms by which impacts cause TBI have been well researched, the mechanisms by which blasts cause TBI are not understood. Various possibilities have been investigated, but blast-induced deformation of the skull has been neglected. From numerical hydrodynamic simulations, we have discovered that nonlethal blasts can induce sufficient flexure of the skull to generate potentially damaging loads in the brain, even if no impact occurs. The possibility that this mechanism may contribute to TBI has implications for the diagnosis of soldiers and the design of protective equipment such as helmets.

  3. Skull Flexure from Blast Waves: A Mechanism for Brain Injury with Implications for Helmet Design

    SciTech Connect (OSTI)

    Moss, W C; King, M J; Blackman, E G

    2009-04-30T23:59:59.000Z

    Traumatic brain injury [TBI] has become a signature injury of current military conflicts, with debilitating, costly, and long-lasting effects. Although mechanisms by which head impacts cause TBI have been well-researched, the mechanisms by which blasts cause TBI are not understood. From numerical hydrodynamic simulations, we have discovered that non-lethal blasts can induce sufficient skull flexure to generate potentially damaging loads in the brain, even without a head impact. The possibility that this mechanism may contribute to TBI has implications for injury diagnosis and armor design.

  4. Altos Hornos de Mexico blast furnace No. 5 certification in ISO-9002 standard

    SciTech Connect (OSTI)

    Gamez, O.; Liceaga, F.; Arredondo, J. [Altos Hornos de Mexico, Monclova (Mexico)

    1997-12-31T23:59:59.000Z

    Altos Hornos de Mexico`s Blast Furnace No. 5, as a means to improve its product quality, sought and obtained the certification of its quality system based on the international standard ISO-9002. The certification was obtained under this quality standard in Dec. 1995 and has successfully been maintained after two continuance audits. For blast furnace No. 5 (BF5) the benefits are reflected by a reduction in the hot metal silicon content variability, a decrease in fuel consumption and a higher productivity. Benefits were also obtained in the working environment where the personnel became more highly motivated, procedures were carried out to completion and the quality records were filled correctly.

  5. Planar blast scaling with condensed-phase explosives in a shock tube

    SciTech Connect (OSTI)

    Jackson, Scott L [Los Alamos National Laboratory

    2011-01-25T23:59:59.000Z

    Blast waves are strong shock waves that result from large power density deposition into a fluid. The rapid energy release of high-explosive (HE) detonation provides sufficiently high power density for blast wave generation. Often it is desirable to quantify the energy released by such an event and to determine that energy relative to other reference explosives to derive an explosive-equivalence value. In this study, we use condensed-phase explosives to drive a blast wave in a shock tube. The explosive material and quantity were varied to produce blast waves of differing strengths. Pressure transducers at varying lengths measured the post-shock pressure, shock-wave arrival time and sidewall impulse associated with each test. Blast-scaling concepts in a one-dimensional geometry were then used to both determine the energy release associated with each test and to verify the scaling of the shock position versus time, overpressure versus distance, and impulse. Most blast scaling measurements to-date have been performed in a three-dimensional geometry such as a blast arena. Testing in a three-dimensional geometry can be challenging, however, as spherical shock-wave symmetry is required for good measurements. Additionally, the spherical wave strength decays rapidly with distance and it can be necessary to utilize larger (several kg) quantities of explosive to prevent significant decay from occurring before an idealized blast wave has formed. Such a mode of testing can be expensive, require large quantities of explosive, and be limited by both atmospheric conditions (such as rain) and by noise complaints from the population density near the test arena. Testing is possible in more compact geometries, however. Non-planar blast waves can be formed into a quasi-planar shape by confining the shock diffraction with the walls of a shock tube. Regardless of the initial form, the wave shape will begin to approximate a planar front after successive wave reflections from the tube walls. Such a technique has previously been used to obtain blast scaling measurements in the planar geometry with gaseous explosives and the condensed-phase explosive nitroguanidine. Recently, there has been much interest in the blast characterization of various non-ideal high explosive (NIHE) materials. With non-ideals, the detonation reaction zone is significantly larger (up to several cm for ANFO) than more ideal explosives. Wave curvature, induced by charge-geometry, can significantly affect the energy release associated with NIHEs. To measure maximum NIHE energy release accurately, it is desirable to minimize any such curvature and, if possible, to overdrive the detonation shock to ensure completion of chemical reactions ahead of the sonic locus associated with the reaction zone. This is achieved in the current study through use of a powerful booster HE and a charge geometry consisting of short cylindrical lengths of NIHE initiated along the charge centerline.

  6. AN IMPROVED SOFT FEEDBACK V-BLAST DETECTION TECHNIQUE FOR TURBO-MIMO SYSTEMS

    E-Print Network [OSTI]

    Singer, Andrew C

    AN IMPROVED SOFT FEEDBACK V-BLAST DETECTION TECHNIQUE FOR TURBO-MIMO SYSTEMS Jun Won Choi*, Andrew-demapper) and the channel decoder exchange soft (extrinsic) information to iteratively improve system perfor- mance. Hence In this paper, an improved minimum mean square error (MMSE) soft feedback detector, called the soft input, soft

  7. Message found in a gravity wave A blast from the past.

    E-Print Network [OSTI]

    Loss, Daniel

    FUTURES Message found in a gravity wave A blast from the past. 664 nature physics | VOL 4 | AUGUST to smack into us very soon -- which is why I'm out here in Maw's pasture spelling out my message with rocks than ever before. I'm taking apart a whole stone wall to write this message, this very narrative

  8. Blast from the Past: Melting Glaciers as a Relevant Source for

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Blast from the Past: Melting Glaciers as a Relevant Source for Persistent Organic Pollutants C H R, 2009. Accepted August 31, 2009. In this study, the hypothesis that melting Alpine glaciers may organic chemicals from melting Alpine glaciers. Considering ongoing global warming and accelerated massive

  9. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

    1995-12-01T23:59:59.000Z

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  10. Development and application of new techniques for blast furnace process control at SSAB Tunnplaat, Luleaa Works

    SciTech Connect (OSTI)

    Braemming, M.; Hallin, M. [SSAB Tunnplaat AB, Luleaa (Sweden); Zuo, G. [Luleaa Univ. (Sweden). Dept. of Process Metallurgy

    1995-12-01T23:59:59.000Z

    SSAB Tunnplaat AB operates two blast furnaces (M1 and M2) in Luleaa. In recent years research efforts have to a great extent been aimed at the development of new techniques for blast furnace process control. An example is the installation of a burden profile measurement system, which was useful in the development of a new burden distribution praxis on the big furnace (M2), equipped with a bell-less-top. Hearth level detection and continuous measurement of the hot metal temperature in the runner are under evaluation. The purpose of these techniques is to give earlier information concerning the state of the blast furnace process. Parallel to this work, models for prediction of silicon in hot metal, the position and shape of the cohesive zone and slip-warning are being developed and tested off-line. These new models and information from new measuring techniques will be integrated into a new Operating Guidance System, hopefully resulting in a powerful tool in the efforts to stabilize blast furnace operations.

  11. Studies of charging stream trajectories and burden distribution in the blast furnace

    SciTech Connect (OSTI)

    McCarthy, M.J.; Mayfield, P.L.; Zulli, P.; Rex, A.J.; Tanzil, W.B.U.

    1993-01-01T23:59:59.000Z

    This work discusses the sensitivity of key blast furnace performance parameters to different gas flow distributions achieved by altering the burden distribution. The changes in burden distribution are brought about by different charging stream trajectories, and methods developed and evaluated for measuring the trajectories both on and off line are described.

  12. Development of quick repairing technique for ceramic burner in hot stove of blast furnace

    SciTech Connect (OSTI)

    Kondo, Atsushi; Doura, Kouji; Nakamura, Hirofumi [Sumitomo Metal Industries, Ltd., Wakayama (Japan). Wakayama Steel Works

    1997-12-31T23:59:59.000Z

    Refractories of ceramic burner in hot stoves at Wakayama No. 4 blast furnace were damaged. There are only three hot stoves, so repairing must be done in a short. Therefore, a quick repairing technique for ceramic burners has been developed, and two ceramic burners were repaired in just 48 hours.

  13. Blast Furnace Granulated Coal Injection System Demonstration Project public design report. Topical report

    SciTech Connect (OSTI)

    NONE

    1995-03-01T23:59:59.000Z

    The public design report describes the Blast Furnace Granulated Coal Injection (BFGCI) project under construction at Bethlehem Steel Corporation`s (BSC) Burns Harbor, Indiana, plant. The project is receiving cost-sharing from the U.S. Department of Energy (DOE), and is being administrated by the Morgantown Energy Technology Center in accordance with the DOE Cooperative Agreement No. DE-FC21-91MC27362. The project is the first installation in the United States for the British Steel technology using granular coal in blast furnaces. The objective is to demonstrate that granular coal is an economic and reliable fuel which can successfully be applied to large North American blast furnaces. These include: coal grind size, coal injection rate, coal source (type) and blast furnace conversion method. To achieve the program objectives, the demonstration project is divided into the following three Phases: Phase I-Design; Phase II-Procurement & Construction; and Phase III-Operation. Preliminary design (Phase I) began in 1991 with detailed design commencing in April 1993. Construction at Burns Harbor (Phase II) began August 1993. Construction is expected to be complete in the first quarter of 1995 which will be followed by a demonstration test program (Phase III).

  14. Gas-powder flow in blast furnace with different shapes of cohesive zone

    SciTech Connect (OSTI)

    Dong, X.F.; Pinson, D.; Zhang, S.J.; Yu, A.B.; Zulli, P. [University of New South Wales, Sydney, NSW (Australia)

    2006-11-15T23:59:59.000Z

    With high PCI rate operations, a large quantity of unburned coal/char fines will flow together with the gas into the blast furnace. Under some operating conditions, the holdup of fines results in deterioration of furnace permeability and lower production efficiency. Therefore, it is important to understand the behaviour of powder (unburnt coal/char) inside the blast furnace when operating with different cohesive zone (CZ) shapes. This work is mainly concerned with the effect of cohesive zone shape on the powder flow and accumulation in a blast furnace. A model is presented which is capable of simulating a clear and stable accumulation region in the lower central region of the furnace. The results indicate that powder is likely to accumulate at the lower part of W-shaped CZs and the upper part of V- and inverse V-shaped CZs. For the same CZ shape, a thick cohesive layer can result in a large pressure drop while the resistance of narrow cohesive layers to gas-powder flow is found to be relatively small. Implications of the findings to blast furnace operation are also discussed.

  15. Shock Tube Design for High Intensity Blast Waves for Laboratory Testing of Armor and Combat Materiel

    E-Print Network [OSTI]

    Courtney, Elijah; Courtney, Michael

    2015-01-01T23:59:59.000Z

    Shock tubes create simulated blast waves which can be directed and measured to study blast wave effects under laboratory conditions. It is desirable to increase available peak pressure from ~1 MPa to ~5 MPa to simulate closer blast sources and facilitate development and testing of personal and vehicle armors. Three methods were investigated to increase peak simulated blast pressure produced by an oxy-acetylene driven shock tube while maintaining suitability for laboratory studies. The first method is the addition of a Shchelkin spiral priming section which works by increasing the turbulent flow of the deflagration wave, thus increasing its speed and pressure. This approach increased the average peak pressure from 1.17 MPa to 5.33 MPa while maintaining a relevant pressure-time curve (Friedlander waveform). The second method is a bottleneck between the driving and driven sections. Coupling a 79 mm diameter driving section to a 53 mm driven section increased the peak pressure from 1.17 MPa to 2.25 MPa. Using a 1...

  16. Turbo-BLAST with Semi-Blind Co-Channel Interference Cancellation in Multicell MIMO Systems

    E-Print Network [OSTI]

    Dai, Huaiyu

    Turbo-BLAST with Semi-Blind Co-Channel Interference Cancellation in Multicell MIMO Systems Vivek to obtain in practice. In this paper we first exploit the turbo principle to enhance an effective blind detection method based on multiuser kurtosis (MUK) maximization, thus coined as turbo-MUK. In turbo

  17. Educational Innovation at UW-Madison The EI Blast: Opportunities and Guides

    E-Print Network [OSTI]

    Mladenoff, David

    Educational Innovation at UW-Madison The EI Blast: Opportunities and Guides February 18, 2013 www campus EI strategy. Members of the EI Core Team have been meeting with campus governance units including-Madison's portfolio of EI initiatives. Learn more about MOOCs. EI Advisory Committee The EI Advisory Committee

  18. BLAST, FASTA, ClustalW, HMM and PHYLIP --these bioinformatics algorithms are now a part of

    E-Print Network [OSTI]

    Majoros, Bill

    BLAST, FASTA, ClustalW, HMM and PHYLIP -- these bioinformatics algorithms are now a part of every molecular biologist's toolkit. DNA sequencing and data mining have become almost as central to biology Genome,a CORPUS of this size can be explored and managed only by computational means

  19. Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the US pulp and paper industry

    SciTech Connect (OSTI)

    Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

    2000-07-01T23:59:59.000Z

    The pulp and paper industry accounts for over 12% of total manufacturing energy use in the US (US EIA 1997a), contributing 9% to total manufacturing carbon dioxide emissions. In the last twenty-five years primary energy intensity in the pulp and paper industry has declined by an average of 1% per year. However, opportunities still exist to reduce energy use and greenhouse gas emissions in the manufacture of paper in the US This report analyzes the pulp and paper industry (Standard Industrial Code (SIC) 26) and includes a detailed description of the processes involved in the production of paper, providing typical energy use in each process step. We identify over 45 commercially available state-of-the-art technologies and measures to reduce energy use and calculate potential energy savings and carbon dioxide emissions reductions. Given the importance of paper recycling, our analysis examines two cases. Case A identifies potential primary energy savings without accounting for an increase in recycling, while Case B includes increasing paper recycling. In Case B the production volume of pulp is reduced to account for additional pulp recovered from recycling. We use a discount rate of 30% throughout our analysis to reflect the investment decisions taken in a business context. Our Case A results indicate that a total technical potential primary energy savings of 31% (1013 PJ) exists. For case A we identified a cost-effective savings potential of 16% (533 PJ). Carbon dioxide emission reductions from the energy savings in Case A are 25% (7.6 MtC) and 14% (4.4 MtC) for technical and cost-effective potential, respectively. When recycling is included in Case B, overall technical potential energy savings increase to 37% (1215 PJ) while cost-effective energy savings potential is 16%. Increasing paper recycling to high levels (Case B) is nearly cost-effective assuming a cut-off for cost-effectiveness of a simple payback period of 3 years. If this measure is included, then the cost-effective energy savings potential in case B increases to 22%.

  20. Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry

    SciTech Connect (OSTI)

    Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

    2000-07-01T23:59:59.000Z

    The pulp and paper industry accounts for over 12% of total manufacturing energy use in the U.S. (U.S. EIA 1997a), contributing 9% to total manufacturing carbon dioxide emissions. In the last twenty-five years primary energy intensity in the pulp and paper industry has declined by an average of 1% per year. However, opportunities still exist to reduce energy use and greenhouse gas emissions in the manufacture of paper in the U.S. This report analyzes the pulp and paper industry (Standard Industrial Code (SIC) 26) and includes a detailed description of the processes involved in the production of paper, providing typical energy use in each process step. We identify over 45 commercially available state-of-the-art technologies and measures to reduce energy use and calculate potential energy savings and carbon dioxide emissions reductions. Given the importance of paper recycling, our analysis examines two cases. Case A identifies potential primary energy savings without accounting for an increase in recycling, while Case B includes increasing paper recycling. In Case B the production volume of pulp is reduced to account for additional pulp recovered from recycling. We use a discount rate of 30% throughout our analysis to reflect the investment decisions taken in a business context. Our Case A results indicate that a total technical potential primary energy savings of 31% (1013 PJ) exists. For case A we identified a cost-effective savings potential of 16% (533 PJ). Carbon dioxide emission reductions from the energy savings in Case A are 25% (7.6 MtC) and 14% (4.4 MtC) for technical and cost-effective potential, respectively. When recycling is included in Case B, overall technical potential energy savings increase to 37% (1215 PJ) while cost-effective energy savings potential is 16%. Increasing paper recycling to high levels (Case B) is nearly cost-effective assuming a cut-off for cost-effectiveness of a simple payback period of 3 years. If this measure is included, then the cost-effective energy savings potential in case B increases to 22%.

  1. Computational Hydrocode Study of Target Damage due to Fragment-Blast Impact

    SciTech Connect (OSTI)

    Hatch-Aguilar, T; Najjar, F; Szymanski, E

    2011-03-24T23:59:59.000Z

    A target's terminal ballistic effects involving explosively generated fragments, along with the original blast, are of critical importance for many different security and safety related applications. Personnel safety and protective building design are but a few of the practical disciplines that can gain from improved understanding combined loading effects. Traditionally, any engineering level analysis or design effort involving explosions would divide the target damage analysis into two correspondingly critical areas: blast wave and fragment related impact effects. The hypothesis of this paper lies in the supposition that a linear combination of a blast-fragment loading, coupled with an accurate target response description, can lead to a non-linear target damage effect. This non-linear target response could then stand as the basis of defining what a synergistic or combined frag-blast loading might actually look like. The table below, taken from Walters, et. al. categorizes some of the critical parameters driving any combined target damage effect and drives the evaluation of results. Based on table 1 it becomes clear that any combined frag-blast analysis would need to account for the target response matching similar ranges for the mechanics described above. Of interest are the critical times upon which a blast event or fragment impact loading occurs relative to the target's modal response. A blast, for the purposes of this paper is defined as the sudden release of chemical energy from a given material (henceforth referred to as an energetic material) onto its surrounding medium. During the coupling mechanism a discrete or discontinuous shockwave is generated. This shockwave travels outward from the source transferring energy and momentum to any surrounding objects including personnel and engineering structures. From an engineering perspective blast effects are typically characterized by way of physical characteristics such as Peak Pressure (PP), Time of Arrival (TOA), Pressure-Impulse (PI) and Time of Duration (TD). Other peculiarities include the radial decrease in pressure from the source, any fireball size measurement, and subsequent increase in temperature from the passing of the shockwave through the surrounding medium. In light of all of these metrics, the loading any object receives from a blast event becomes intricately connected to the distance between itself and the source. Because of this, a clear distinction is made between close-in effects and those from a source far away from the object of interest. Explosively generated fragments on the other hand are characterized by means of their localized damage potential. Metrics such as whether the fragment penetrates or perforates a given object is quantified as well as other variables including fragment's residual velocity, % kinetic energy decrease, residual fragment mass and other exit criteria. A fragment launched under such violent conditions could easily be traveling at speeds in excess of 2500 ft/s. Given these speeds it is conceivable to imagine how any given fragment could deliver a concentrated load to a target and penetrates through walls, vehicles or even the protection systems of nearby personnel. This study will focus on the individual fragment-target impact event with the hopes of expanding it to eventually include statistical procedures. Since this is a modeling excursion into the combined frag-blast target damage effects the numerical methods used to frame this problem become important in-so-far as the simulations are done in a consistent manner. For this study a Finite-Element based Hydrocode solution called ALE3D (ALE=Arbitrary Lagrangian-Eulerian) was utilized. ALE3D is developed by Lawrence Livermore National Laboratory (Livermore, CA), and as this paper will show, successfully implemented a converged ALE formulation including as many of the different aspects needed to query the synergistic damage on a given target. Further information on the modeling setup is included.

  2. New industrial heat pump applications to an integrated thermomechanical pulp and paper mill

    SciTech Connect (OSTI)

    none,

    1991-01-01T23:59:59.000Z

    Application of pinch technology US industries in an early screening study done by TENSA Services (DOE/ID/12583-1) identified potential for heat pumps in several industrial sectors. Among these, processes with large evaporation units were found to be some of the most promising sectors for advanced heat pump placement. This report summarizes the results of a study for Bowater Incorporated, Carolina Division. The units selected for this study are the thermo-mechanical pulper (TMP), kraft digester, evaporators, boiler feed water (BFW) train and pulp dryer. Based on the present level of operation, the following recommendations are made: 1. Install a mechanical vapor compression (MVR) heat pump between the TMP mill and {number sign}3 evaporator. This heat pump will compress the 22 psig steam from the TMP heat recovery system and use it to replace about 70% of the 60 psig steam required in {number sign} evaporator. The boiler feed water heat losses (in the low pressure deaerator) will be supplied by heat available in the TMR's zero psig vent steam. 2. Study the digester to verify the practicality of installing an MVR heat pump which will compress the dirty weapons from the cyclone separator. The compressed vapors can be directly injected into the digester and thus reduce the 135 psig steam consumption. 31 figs., 9 tabs.

  3. Opportunities to improve energy efficiency in the U.S. pulp and paper industry

    SciTech Connect (OSTI)

    Worrell, Ernst; Martin, Nathan; Anglani, Norma; Einstein, Dan; Krushch, Marta; Price, Lynn

    2001-02-02T23:59:59.000Z

    This paper analyzes the energy efficiency and carbon dioxide emissions reductions potential of the U.S. pulp and paper industry, one of the largest energy users in the U.S. manufacturing sector. We examined over 45 commercially available state-of-the-art technologies and measures. The measures were characterized, and then ordered on the basis of cost-effectiveness. The report indicates that there still exists significant potential for energy savings and carbon dioxide emissions reduction in this industry. The cost-effective potential for energy efficiency improvement is defined as having a simple pay-back period of three years or less. Not including increased recycling the study identifies a cost-effective savings potential of 16% of the primary energy use in 1994. Including increased recycling leads to a higher potential for energy savings, i.e. a range of cost-effective savings between 16% and 24% of primary energy use. Future work is needed to further elaborate on key energy efficiency measures identified in the report including barriers and opportunities for increased recycling of waste paper.

  4. Spin-Dependent Electron Scattering from Polarized Protons and Deuterons with the BLAST Experiment at MIT-Bates

    E-Print Network [OSTI]

    Hasell, Douglas K.

    The Bates Large Acceptance Spectrometer Toroid (BLAST) experiment was operated at the MIT-Bates Linear Accelerator Center from 2003 until 2005. The experiment was designed to exploit the power of a polarized electron beam ...

  5. Investigation of sonic/subsonic air-blast atomization using Rayleigh- and Mie-scattering visualization techniques

    E-Print Network [OSTI]

    Kim, Tae-Kyun

    1996-01-01T23:59:59.000Z

    To examine the jet mixing in air-blast twin fluid atomization, the sonic and supersonic air jet developments have been exclusively visualized using the Rayleigh scattering principle and the development of liquid spray has been separately visualized...

  6. Blast Wave Formation by Laser-Sustained Nonequilibrium Plasma in the Laser-Driven In-Tube Accelerator Operation

    SciTech Connect (OSTI)

    Ogino, Yousuke; Ohnishi, Naofumi; Sawada, Keisuke [Department of Aeronautics and Space Engineering, Tohoku University, Sendai 980-8579 (Japan); Sasoh, Akihiro [Institute of Fluid Science, Tohoku University, Sendai 980-8577 (Japan)

    2006-05-02T23:59:59.000Z

    Understanding the dynamics of laser-produced plasma is essentially important for increasing available thrust force in a gas-driven laser propulsion system such as laser-driven in-tube accelerator. A computer code is developed to explore the formation of expanding nonequilibrium plasma produced by laser irradiation. Various properties of the blast wave driven by the nonequilibrium plasma are examined. It is found that the blast wave propagation is substantially affected by radiative cooling effect for lower density case.

  7. Placement of the dam for the no. 2 kambaratinskaya HPP by large-scale blasting: some observations

    SciTech Connect (OSTI)

    Shuifer, M. I.; Argal, E. S. [JSC 'SPII Gidroproekt' (Russian Federation)

    2011-11-15T23:59:59.000Z

    Results of complex instrument observations of large-scale blasting during construction of the dam for the No. 2 Kambaratinskaya HPP on the Naryn River in the Republic of Kirgizia are analyzed. The purpose of these observations was: to determine the actual parameters of the seismic process, evaluate the effect of air and acoustic shock waves, and investigate the kinematics of the surface formed by the blast in its core region within the mass of fractured rocks.

  8. Dynamics and afterglow light curves of gamma-ray burst blast waves encountering a density bump or void

    SciTech Connect (OSTI)

    Uhm, Z. Lucas; Zhang, Bing, E-mail: uhm@pku.edu.cn, E-mail: zhang@physics.unlv.edu [Kavli Institute for Astronomy and Astrophysics, Peking University, Beijing 100871 (China)

    2014-07-01T23:59:59.000Z

    We investigate the dynamics and afterglow light curves of gamma-ray burst blast waves that encounter various density structures (such as bumps, voids, or steps) in the surrounding ambient medium. We present and explain the characteristic response features that each type of density structure in the medium leaves on the forward shock (FS) and reverse shock (RS) dynamics for blast waves with either a long-lived or short-lived RS. We show that when the ambient medium density drops, the blast waves exhibit in some cases a period of an actual acceleration (even during their deceleration stage) due to adiabatic cooling of blast waves. Comparing numerical examples that have different shapes of bumps or voids, we propose a number of consistency tests that must be satisfied by correct modeling of blast waves. Our model results successfully pass these tests. Employing a Lagrangian description of blast waves, we perform a sophisticated calculation of afterglow emission. We show that as a response to density structures in the ambient medium, the RS light curves produce more significant variations than the FS light curves. Some observed features (such as rebrightenings, dips, or slow wiggles) can be more easily explained within the RS model. We also discuss the origin of these different features imprinted on the FS and RS light curves.

  9. Blast-furnace ironmaking -- Existing capital and continued improvements are a winning formula for a bright future

    SciTech Connect (OSTI)

    Oshnock, T.W.; Colinear, J.A. [U.S. Steel, Monroeville, PA (United States)

    1995-12-01T23:59:59.000Z

    Throughout the years the blast-furnace process has been improved upon significantly. Increases to the hot-blast temperature, improvements to the physical, chemical, and metallurgical properties of coke and burden materials, the use of more fuel injectants, and improvements to the design of the furnace facilities have led to significant decreases in furnace coke rate, increases in productivity, and increases in furnace campaign life. As a result, many of the alternative cokeless reduction processes have not replaced blast-furnace hot-metal production in North America. In the future, these continued blast-furnace improvements will potentially result in coke rates decreasing to 400 pounds per net ton of hot metal (lb/NTHM) as more pulverized coal is injected. These improvements, coupled with the fact that existing blast furnaces and coke plants can be refurbished for approximately $110 per annual ton of hot metal [$100 per annual net ton of hot metal (NTHM)], will result in extending the life of the North American blast furnaces well into the twenty-first century.

  10. The formation of an ore free blast furnace center by bell charging

    SciTech Connect (OSTI)

    Exter, P. den; Steeghs, A.G.S.; Godijn, R.; Chaigneau, R.; Timmer, R.M.C. [Hoogovens Research and Development, IJmuiden (Netherlands); Toxopeus, H.L.; Vliet, C. van der [Hoogovens Staal Primary Products, IJmuiden (Netherlands)

    1997-12-31T23:59:59.000Z

    A research program has been started to clarify and support the central gas flow control philosophy of Hoogovens` bell-charged No. 7 blast furnace. Small scale burdening experiments and sampling of the stock surface during shut-downs suggest that a sufficiently high central gas flow is an important condition for maintenance of an ore free, highly permeable furnace center and that fluidization of coke plays a part in its formation. On the basis of these experiments a hypothesis was formulated regarding the formation of an ore free blast furnace center, but could not be confirmed satisfactorily. Forthcoming full-scale burdening experiments will provide a better insight in the burden distribution and its control.

  11. Determination of the fundamental softening and melting characteristics of blast furnace burden materials

    SciTech Connect (OSTI)

    Bakker, T.; Heerema, R.H. [Delft Univ. of Technology (Netherlands). Faculty of Mining and Petroleum Engineering

    1996-12-31T23:59:59.000Z

    An experimental technique to investigate the fundamental mechanisms taking place on a microscale in the softening and melting zone in the blast furnace, is presented. In the present paper, attention is focused on determination of the softening viscosity of porous wustite. The technique may be potentially useful to investigate more complex samples of ironbearing material, as occurring in the blast furnace. In comparison with the results obtained by other researchers the viscosity of porous wustite found in the present work is substantially higher than reported elsewhere for sinter and pellets. This may be an indication that softening is not merely a reflection of the solid state deformation under load of wustite. An important factor may be local melting of some of the phases present within the sinter and pellet structures.

  12. Operational results for high pulverized coal injection rate at Kimitsu No. 3 blast furnace

    SciTech Connect (OSTI)

    Ueno, Hiromitsu; Matsunaga, Shin`ichi; Kakuichi, Kazumoto; Amano, Shigeru; Yamaguchi, Kazuyoshi

    1995-12-01T23:59:59.000Z

    In order to further develop the technology for high-rate pulverized coal injection (PCI), namely over 200 kg/t-pig, Nippon Steel performed a high injection rate test at the Kimitsu No. 3 blast furnace in November, 1993. The paper describes PCI equipment; the operational design of the test, including blast conditions, reducibility of sinter, coke strength and burden distribution; and test results. These results include a discussion of the transition of operation, burden distribution control, replacement ratio of coke, permeability at upper and lower parts of the furnace, reducibility at lower part of the furnace, accumulation of fines in the deadman, and generation and accumulation of unburnt char. Stable operation was achieved at a PCI rate of 190 kg/t-pig. With injection rates between 200--300 kg/t-pig, the problem becomes how to improve the reduction-meltdown behavior in the lower part of the furnace.

  13. HIGH ANGULAR RESOLUTION OBSERVATIONS OF FOUR CANDIDATE BLAST HIGH-MASS STARLESS CORES

    SciTech Connect (OSTI)

    Olmi, Luca; Poventud, Carlos M. [Physics Department, Rio Piedras Campus, University of Puerto Rico, Box 23343, UPR Station, San Juan, Puerto Rico (United States); Araya, Esteban D. [Physics Department, Western Illinois University, 1 University Circle, Macomb, IL 61455 (United States); Chapin, Edward L.; Gibb, Andrew [Department of Physics and Astronomy, University of British Columbia, 6224 Agricultural Road, Vancouver, BC V6T 1Z1 (Canada); Hofner, Peter [Physics Department, New Mexico Institute of Mining and Technology, 801 Leroy Place, Socorro, NM 87801 (United States); Martin, Peter G., E-mail: olmi.luca@gmail.co, E-mail: olmi@arcetri.astro.i [Canadian Institute for Theoretical Astrophysics, University of Toronto, 60 St. George Street, Toronto, ON M5S 3H8 (Canada)

    2010-06-01T23:59:59.000Z

    We discuss high angular resolution observations of ammonia toward four candidate high-mass starless cores (HMSCs). The cores were identified by the Balloon-borne Large Aperture Submillimeter Telescope (BLAST) during its 2005 survey of the Vulpecula region where 60 compact sources were detected simultaneously at 250, 350, and 500 {mu}m. Four of these cores, with no IRAS-PSC or MSX counterparts, were mapped with the NRAO Very Large Array and observed with the Effelsberg 100 m telescope in the NH{sub 3}(1,1) and (2,2) spectral lines. Our observations indicate that the four cores are cold (T {sub k} < 16 K) and show a filamentary and/or clumpy structure. They also show a significant velocity substructure within {approx}1 km s{sup -1}. The four BLAST cores appear to be colder and more quiescent than other previously observed HMSC candidates, suggesting an earlier stage of evolution.

  14. Kinematics of ICMEs/shocks: blast wave reconstruction using type II emissions

    E-Print Network [OSTI]

    Corona-Romero, P; Aguilar-Rodriguez, E; de-la-Luz, V; Mejia-Ambriz, J C

    2015-01-01T23:59:59.000Z

    We present a physical methodology to reconstruct the trajectory of interplanetary shocks using type II radio emission data. This technique calculates the shock trajectory assuming that the disturbance propagates as a blast wave in the interplanetary medium. We applied this Blast Wave Reconstruction (BWR) technique to analyze eight fast Earth-directed ICMEs/shocks associated with type II emissions. The technique deduces a shock trajectory that reproduces the type II frequency drifts, and calculates shock onset speed, shock transit time and shock speed at 1~AU. There were good agreements comparing the BWR results with the type II spectra, with data from coronagraph images, {\\it in situ} measurements, and interplanetary scintillation (IPS) observations. Perturbations on the type II data affect the accuracy of the BWR technique. This methodology could be applied to track interplanetary shocks causing TII emissions in real-time, to predict the shock arrival time and shock speed at 1~AU.

  15. Incineration of Residue from Paint Stripping Operations Using Plastic Media Blasting

    E-Print Network [OSTI]

    Helt, J. E.; Mallya, N.

    i INCINERATION OF RESIDUE FROH PAINT STRIPPING OPERATIONS USING PLASTIC MEDIA BLASTING J. E. HELT N. MALLYA Group Leader Chemist Chemical Technology Division Chemical Technology Division Argonne National Laboratory Argonne National... potentially be classified as a hazardous waste. One possible alternative to depositing the waste residue directly into a hazardous waste landfill is inciner ation. Incineration would provide desirable volume reduction. However. the fate of heavy metals...

  16. Interaction of supernova blast waves with wind-driven shells: formation of "jets", "bullets", "ears", etc

    E-Print Network [OSTI]

    V. V. Gvaramadze

    1999-12-24T23:59:59.000Z

    Most of middle-aged supernova remnants (SNRs) have a distorted and complicated appearance which cannot be explained in the framework of the Sedov-Taylor model. We consider three typical examples of such SNRs (Vela SNR, MSH 15-52, G 309.2-00.6) and show that their structure could be explained as a result of interaction of a supernova (SN) blast wave with the ambient medium preprocessed by the action of the SN progenitor's wind and ionized emission.

  17. Desulphurization and simultaneous treatment of wastewater from blast furnace by pulsed corona discharge

    SciTech Connect (OSTI)

    Li, S.L.; Feng, Q.B.; Li, L.; Xie, C.L.; Zhen, L.P. [Huazhong University of Science and Technology, Wuhan (China)

    2009-03-15T23:59:59.000Z

    Laboratory tests were conducted for removal of SO{sub 2} from simulated flue gas and simultaneous treatment of wastewater from blast furnace by pulsed corona discharge. Tests were conducted for the flue gas flow from 12 to 18 Nm{sup 3}/h, the simulated gas temperature from 80 to 120 {sup o}C, the inlet flux of wastewater from 33 to 57 L/h, applied voltage from 0 to 27 kV, and SO{sub 2} initial concentration was about 1,430 mg/m{sup 3}. Results showed that wastewater from blast furnace has an excellent ability of desulphurization (about 90%) and pulsed corona discharge can enhance the desulphurization efficiency. Meanwhile, it was observed that the SO{sub 2} removal ratio decreased along with increased cycle index, while it increased as the flux of flue gas was reduced, and increased when the flux of wastewater from blast furnace was increased. In addition, results demonstrated that the content of sulfate radical produced in wastewater increase with an increment of applied pulsed voltage, cycle index, or the flux of flue gas. Furthermore, the results indicated that the higher the inlet content of cyanide the better removal effect of it, and the removal rate can reach 99.9% with a residence time of 2.1 s in the pulsed corona zone during the desulphurization process when the inlet content was higher, whereas there was almost no removal effect when the inlet content was lower. This research may attain the objective of waste control, and can provide a new way to remove SO{sub 2} from flue gas and simultaneously degrade wastewater from blast furnace for integrated steel plants.

  18. CORRELATIONS IN THE (SUB)MILLIMETER BACKGROUND FROM ACT Multiplication-Sign BLAST

    SciTech Connect (OSTI)

    Hajian, Amir; Battaglia, Nick; Bond, J. Richard [Canadian Institute for Theoretical Astrophysics, University of Toronto, Toronto, ON M5S 3H8 (Canada); Viero, Marco P.; Bock, James J. [California Institute of Technology, Pasadena, CA 91125 (United States); Addison, Graeme [Department of Astrophysics, Oxford University, Oxford, OX1 3RH (United Kingdom); Aguirre, Paula [Departamento de Astronomia y Astrofisica, Facultad de Fisica, Pontificia Universidad Catolica, Casilla 306, Santiago 22 (Chile); Appel, John William; Duenner, Rolando; Essinger-Hileman, Thomas; Fowler, Joseph W.; Hincks, Adam D. [Joseph Henry Laboratories of Physics, Jadwin Hall, Princeton University, Princeton, NJ 08544 (United States); Das, Sudeep; Dunkley, Joanna [Department of Astrophysical Sciences, Peyton Hall, Princeton University, Princeton, NJ 08544 (United States); Devlin, Mark J.; Dicker, Simon R. [Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, PA 19104 (United States); Hughes, John P. [Department of Physics and Astronomy, Rutgers, State University of New Jersey, Piscataway, NJ 08854-8019 (United States); Halpern, Mark [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada); Hasselfield, Matthew [Laboratoire APC, Universite Paris Diderot, 75205 Paris (France); Hilton, Matt [Astrophysics and Cosmology Research Unit, School of Mathematical Sciences, University of KwaZulu-Natal, Durban 4041 (South Africa); and others

    2012-01-01T23:59:59.000Z

    We present measurements of the auto- and cross-frequency correlation power spectra of the cosmic (sub)millimeter background at 250, 350, and 500 {mu}m (1200, 860, and 600 GHz) from observations made with the Balloon-borne Large Aperture Submillimeter Telescope (BLAST); and at 1380 and 2030 {mu}m (218 and 148 GHz) from observations made with the Atacama Cosmology Telescope (ACT). The overlapping observations cover 8.6 deg{sup 2} in an area relatively free of Galactic dust near the south ecliptic pole. The ACT bands are sensitive to radiation from the cosmic microwave background, to the Sunyaev-Zel'dovich effect from galaxy clusters, and to emission by radio and dusty star-forming galaxies (DSFGs), while the dominant contribution to the BLAST bands is from DSFGs. We confirm and extend the BLAST analysis of clustering with an independent pipeline and also detect correlations between the ACT and BLAST maps at over 25{sigma} significance, which we interpret as a detection of the DSFGs in the ACT maps. In addition to a Poisson component in the cross-frequency power spectra, we detect a clustered signal at 4{sigma}, and using a model for the DSFG evolution and number counts, we successfully fit all of our spectra with a linear clustering model and a bias that depends only on redshift and not on scale. Finally, the data are compared to, and generally agree with, phenomenological models for the DSFG population. This study demonstrates the constraining power of the cross-frequency correlation technique to constrain models for the DSFGs. Similar analyses with more data will impose tight constraints on future models.

  19. Viscosity of black liquor project

    SciTech Connect (OSTI)

    Barrall, G.A.

    1998-06-01T23:59:59.000Z

    The discussion of magnetic resonance in this report is confined to nuclides with a spin quantum number of 1/2. Included is a basic discussion of magnetic resonance; magnetic resonance relaxation and viscosity; and rhometers and viscometers. Many other effects are ignored for the sake of clarity.

  20. NO FLARES FROM GAMMA-RAY BURST AFTERGLOW BLAST WAVES ENCOUNTERING SUDDEN CIRCUMBURST DENSITY CHANGE

    SciTech Connect (OSTI)

    Gat, Ilana; Van Eerten, Hendrik; MacFadyen, Andrew [Center for Cosmology and Particle Physics, Physics Department, New York University, New York, NY 10003 (United States)

    2013-08-10T23:59:59.000Z

    Afterglows of gamma-ray bursts are observed to produce light curves with the flux following power-law evolution in time. However, recent observations reveal bright flares at times on the order of minutes to days. One proposed explanation for these flares is the interaction of a relativistic blast wave with a circumburst density transition. In this paper, we model this type of interaction computationally in one and two dimensions, using a relativistic hydrodynamics code with adaptive mesh refinement called RAM, and analytically in one dimension. We simulate a blast wave traveling in a stellar wind environment that encounters a sudden change in density, followed by a homogeneous medium, and compute the observed radiation using a synchrotron model. We show that flares are not observable for an encounter with a sudden density increase, such as a wind termination shock, nor for an encounter with a sudden density decrease. Furthermore, by extending our analysis to two dimensions, we are able to resolve the spreading, collimation, and edge effects of the blast wave as it encounters the change in circumburst medium. In all cases considered in this paper, we find that a flare will not be observed for any of the density changes studied.

  1. A geophysical shock and air blast simulator at the National Ignition Facility

    SciTech Connect (OSTI)

    Fournier, K. B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Brown, C. G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); May, M. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Compton, S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Walton, O. R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Shingleton, N. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Kane, J. O. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Holtmeier, G. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Loey, H. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Mirkarimi, P. B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Dunlop, W. H. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Guyton, R. L. [National Security Technologies, Livermore, CA (United States); Huffman, E. [National Security Technologies, Livermore, CA (United States)

    2014-09-01T23:59:59.000Z

    The energy partitioning energy coupling experiments at the National Ignition Facility (NIF) have been designed to measure simultaneously the coupling of energy from a laser-driven target into both ground shock and air blast overpressure to nearby media. The source target for the experiment is positioned at a known height above the ground-surface simulant and is heated by four beams from the NIF. The resulting target energy density and specific energy are equal to those of a low-yield nuclear device. The ground-shock stress waves and atmospheric overpressure waveforms that result in our test system are hydrodynamically scaled analogs of full-scale seismic and air blast phenomena. This report summarizes the development of the platform, the simulations, and calculations that underpin the physics measurements that are being made, and finally the data that were measured. Agreement between the data and simulation of the order of a factor of two to three is seen for air blast quantities such as peak overpressure. Historical underground test data for seismic phenomena measured sensor displacements; we measure the stresses generated in our ground-surrogate medium. We find factors-of-a-few agreement between our measured peak stresses and predictions with modern geophysical computer codes.

  2. Pellet property requirements for future blast-furnace operations and other new ironmaking processes

    SciTech Connect (OSTI)

    Agrawal, A.K.; Oshnock, T.W. [U.S. Steel, Monroeville, PA (United States)

    1995-12-01T23:59:59.000Z

    The requirements for the physical, chemical and metallurgical properties of pellets have continued to become more stringent as blast-furnace productivity and coke rate have been rapidly improved during the last decade. In addition, the age and deterioration of the North American coke batteries, the lack of capital to sufficiently rebuild them, and the threat of increasingly more stringent environmental controls for the coke batteries has forced North American ironmakers to begin implementing pulverized coal injection to minimize the coke requirements for the blast furnace and to seriously investigate developing other ironmaking processes that use coal instead of coke. Therefore, the next major step in North American ironmaking has included injecting pulverized coal (PC) at 200 kilograms per ton of hot metal (kg/ton) [400 pounds per net ton of hot metal (lb/NTHM)] or greater which will result in the coke rate decreasing to less than 300 kg/ton (600 lb/NTHM) or less. As a result, the pellets will spend more time in the furnace and will be required to support more total weight. Pellets can also be a major iron unit source for other cokeless ironmaking processes such as the COREX process or the AISI direct ironmaking process. This paper will explore the pellet property requirements for future blast-furnace operations and cokeless ironmaking processes.

  3. Pulverized coal injection (PCI) at Inland`s No. 7 blast furnace

    SciTech Connect (OSTI)

    Carter, W.L.; Greenawald, P.B.; Ranade, M.G.; Ricketts, J.A.; Zuke, D.A. [Inland Steel Co., East Chicago, IN (United States)

    1995-12-01T23:59:59.000Z

    Fuel injection at the tuyeres has always been part of normal operating practice on this blast furnace. It has been used as much because of the beneficial effects on furnace operation as for the replacement of some of the coke that would otherwise be consumed. Fuel oil was used at first, but since the early 1980s it was more economical to inject natural gas. Studies in 1990 indicated that natural gas could be increased to 75 kg/tHM on No. 7 Furnace, and this would result in a coke rate of approximately 360 kg/tHM. It was apparent that coal injection offered significantly more opportunity for coke savings. Coke rate could be lowered to 300 kg/tHM with coal injected at 175 kg/tHM. Some combustion limitations were expected at that level. A coke rate of 270 kg/tHM with coal at 200 kg/tHM may be possible once these limitations are overcome. Furnace permeability was expected to limit the ability to reduce coke rate any further. In addition, the relative cost of coal would be significantly lower than the cost of coke it replaced. This lead to the decision late in 1991 to install pulverized coal injection (PCI) equipment for all of Inland`s blast furnaces. This paper will deal with PCI experience at No. 7 Blast Furnace.

  4. A geophysical shock and air blast simulator at the National Ignition Facility

    SciTech Connect (OSTI)

    Fournier, K. B.; Brown, C. G.; May, M. J.; Compton, S.; Walton, O. R.; Shingleton, N.; Kane, J. O.; Holtmeier, G.; Loey, H.; Mirkarimi, P. B.; Dunlop, W. H. [Lawrence Livermore National Laboratory, P.O. Box 808, L-481, Livermore, California 94550 (United States); Guyton, R. L.; Huffman, E. [National Securities Technologies, Vasco Rd., Livermore, California 94551 (United States)

    2014-09-15T23:59:59.000Z

    The energy partitioning energy coupling experiments at the National Ignition Facility (NIF) have been designed to measure simultaneously the coupling of energy from a laser-driven target into both ground shock and air blast overpressure to nearby media. The source target for the experiment is positioned at a known height above the ground-surface simulant and is heated by four beams from the NIF. The resulting target energy density and specific energy are equal to those of a low-yield nuclear device. The ground-shock stress waves and atmospheric overpressure waveforms that result in our test system are hydrodynamically scaled analogs of full-scale seismic and air blast phenomena. This report summarizes the development of the platform, the simulations, and calculations that underpin the physics measurements that are being made, and finally the data that were measured. Agreement between the data and simulation of the order of a factor of two to three is seen for air blast quantities such as peak overpressure. Historical underground test data for seismic phenomena measured sensor displacements; we measure the stresses generated in our ground-surrogate medium. We find factors-of-a-few agreement between our measured peak stresses and predictions with modern geophysical computer codes.

  5. Bringing large-scale multiple genome analysis one step closer: ScalaBLAST and beyond

    SciTech Connect (OSTI)

    Oehmen, Christopher S.; Sofia, Heidi J.; Baxter, Douglas; Szeto, Ernest; Hugenholtz, Philip; Kyrpides, Nikos; Markowitz, Victor; Straatsma, Tjerk P.

    2007-06-01T23:59:59.000Z

    Genome sequence comparisons of exponentially growing data sets form the foundation for the comparative analysis tools provided by community biological data resources such as the Integrated Microbial Genome (IMG) system at the Joint Genome Institute (JGI). We present an example of how ScalaBLAST, a high-throughput sequence analysis program harnesses increasingly critical high-performance computing to perform sequence analysis which is a critical component of maintaining a state-of-the-art sequence data repository. The Integrated Microbial Genomes (IMG) system1 is a data management and analysis platform for microbial genomes hosted at the JGI. IMG contains both draft and complete JGI genomes integrated with other publicly available microbial genomes of all three domains of life. IMG provides tools and viewers for interactive analysis of genomes, genes and functions, individually or in a comparative context. Most of these tools are based on pre-computed pairwise sequence similarities involving millions of genes. These computations are becoming prohibitively time consuming with the rapid increase in the number of newly sequenced genomes incorporated into IMG and the need to refresh regularly the content of IMG in order to reflect changes in the annotations of existing genomes. Thus, building IMG 2.0 (released on December 1st 2006) entailed reloading from NCBI's RefSeq all the genomes in the previous version of IMG (IMG 1.6, as of September 1st, 2006) together with 1,541 new public microbial,viral and eukaryal genomes, bringing the total of IMG genomes to 2,301. A critical part of building IMG 2.0 involved using PNNL ScalaBLAST software for computing pairwise similarities for over 2.2 million genes in under 26 hours on 1,000 processors, thus illustrating the impact that new generation bioinformatics tools are poised to make in biology. The BLAST algorithm2, 3 is a familiar bioinformatics application for computing sequence similarity, and has become a workhorse in large-scale genomics projects. The rapid growth of genome resources such as IMG cannot be sustained without more powerful tools such as ScalaBLAST that use more effectively large scale computing resources to perform the core BLAST calculations. ScalaBLAST is a high performance computing algorithm designed to give high throughput BLAST results on high-end supercomputers. Other parallel sequence comparison applications have been developed4-6. However problems with scaling generally prevent these applications from being used for very large searches. ScalaBLAST7 is the first BLAST application to be both highly scaleable against the size of the database as well as the number of computer processors on high-end hardware and on commodity clusters. ScalaBLAST achieves high throughput by parsing a large collection of query sequences into independent subgroups. These smaller tasks are assigned to independent process groups. Efficient scaling is achieved by (transparently to the user) sharing only one copy of the target database across all processors using the Global Array toolkit 8, 9, which provides software implementation of shared memory interface. ScalaBLAST was initially deployed on the 1,960 processor MPP2 cluster in the Wiliam R. Wiley Environmental Molecular Sciences Laboratory at Pacific Northwest National Laboratory, and has since been ported to a variety of linux-based clusters and shared memory architectures, including SGI Altix, AMD opteron, and Intel Xeon-based clusters. Future targets include IBM BlueGene, Cray, and SGI Altix XE architectures. The importance of performing high-throughput calculations rapidly lies in the rate of growth of sequence data. For a genome sequencing center to provide multiple-genome comparison capabilities, it must keep pace with exponentially growing collection of protein data, both from its own genomes, and from the public genome information as well. As sequence data continues to grow exponentially, this challenge will only increase with time. Solving the BLAST throughput challenge for centralized data resources like IMG has the poten

  6. Modeling coal combustion behavior in an ironmaking blast furnace raceway: model development and applications

    SciTech Connect (OSTI)

    Maldonado, D.; Austin, P.R.; Zulli, P.; Guo B. [BlueScope Steel Research Laboratories, Port Kembla, NSW (Australia)

    2009-03-15T23:59:59.000Z

    A numerical model has been developed and validated for the investigation of coal combustion phenomena under blast furnace operating conditions. The model is fully three-dimensional, with a broad capacity to analyze significant operational and equipment design changes. The model was used in a number of studies, including: Effect of cooling gas type in coaxial lance arrangements. It was found that oxygen cooling improves coal burnout by 7% compared with natural gas cooling under conditions that have the same amount of oxygen enrichment in the hot blast. Effect of coal particle size distribution. It was found that during two similar periods of operation at Port Kembla's BF6, a difference in PCI capability could be attributed to the difference in coal size distribution. Effect of longer tuyeres. Longer tuyeres were installed at Port Kembla's BF5, leading to its reline scheduled for March 2009. The model predicted an increase in blast velocity at the tuyere nose due to the combustion of volatiles within the tuyere, with implications for tuyere pressure drop and PCI capability. Effect of lance tip geometry. A number of alternate designs were studied, with the best-performing designs promoting the dispersion of the coal particles. It was also found that the base case design promoted size segregation of the coal particles, forcing smaller coal particles to one side of the plume, leaving larger coal particles on the other side. 11 refs., 15 figs., 4 tabs.

  7. Using coal-dust fuel in Ukrainian and Russian blast furnaces

    SciTech Connect (OSTI)

    A.A. Minaev; A.N. Ryzhenkov; Y.G. Banninkov; S.L. Yaroshevskii; Y.V. Konovalov; A.V. Kuzin [Donetsk National Technical University, Donetsk (Russian Federation)

    2008-02-15T23:59:59.000Z

    Ukrainian and Russian blast-furnace production falls short of the best global practices. It is no secret that, having switched to oxygen and natural gas in the 1960s, the blast-furnace industries have improved the batch and technological conditions and have attained a productivity of 2.5 and even 3 t/(m{sup 3} day), but have not been able to reduce coke consumption below 400 kg/t, which was the industry standard 40 years ago. The situation is particularly bad in Ukraine: in 2007, furnace productivity was 1.5-2 t/m{sup 3}, with a coke consumption of 432-530 kg/t. Theoretical considerations and industrial experience over the last 20 years show that the large-scale introduction of pulverized fuel, with simultaneous improvement in coke quality and in batch and technological conditions, is the only immediately available means of reducing coke consumption considerably (by 20-40%). By this means, natural-gas consumption is reduced or eliminated, and the efficiency of blast-furnace production and ferrous metallurgy as a whole is increased.

  8. Modeling and simulation of blast-induced, early-time intracranial wave physics leading to traumatic brain injury.

    SciTech Connect (OSTI)

    Ford, Corey C. (University of New Mexico, Albuquerque, NM); Taylor, Paul Allen

    2008-02-01T23:59:59.000Z

    The objective of this modeling and simulation study was to establish the role of stress wave interactions in the genesis of traumatic brain injury (TBI) from exposure to explosive blast. A high resolution (1 mm{sup 3} voxels), 5 material model of the human head was created by segmentation of color cryosections from the Visible Human Female dataset. Tissue material properties were assigned from literature values. The model was inserted into the shock physics wave code, CTH, and subjected to a simulated blast wave of 1.3 MPa (13 bars) peak pressure from anterior, posterior and lateral directions. Three dimensional plots of maximum pressure, volumetric tension, and deviatoric (shear) stress demonstrated significant differences related to the incident blast geometry. In particular, the calculations revealed focal brain regions of elevated pressure and deviatoric (shear) stress within the first 2 milliseconds of blast exposure. Calculated maximum levels of 15 KPa deviatoric, 3.3 MPa pressure, and 0.8 MPa volumetric tension were observed before the onset of significant head accelerations. Over a 2 msec time course, the head model moved only 1 mm in response to the blast loading. Doubling the blast strength changed the resulting intracranial stress magnitudes but not their distribution. We conclude that stress localization, due to early time wave interactions, may contribute to the development of multifocal axonal injury underlying TBI. We propose that a contribution to traumatic brain injury from blast exposure, and most likely blunt impact, can occur on a time scale shorter than previous model predictions and before the onset of linear or rotational accelerations traditionally associated with the development of TBI.

  9. Pilot plant testing of Illinois coal for blast furnace injection. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

    1994-12-31T23:59:59.000Z

    The purpose of this study is to evaluate the combustion of Illinois coal in the blast furnace injection process in a new and unique pilot plant test facility. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it is the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. It is intended to complete the study already underway with the Armco and Inland steel companies and to demonstrate quantitatively the suitability of both the Herrin No. 6 and Springfield No. 5 coals for blast furnace injection. The main feature of the current work is the testing of Illinois coals at CANMET`s (Canadian Centre for Mineral and Energy Technology) pilot plant coal combustion facility. This facility simulates blowpipe-tuyere conditions in an operating blast furnace, including blast temperature (900 C), flow pattern (hot velocity 200 m/s), geometry, gas composition, coal injection velocity (34 m/s) and residence time (20 ms). The facility is fully instrumented to measure air flow rate, air temperature, temperature in the reactor, wall temperature, preheater coil temperature and flue gas analysis. During this quarter a sample of the Herrin No. 6 coal (IBCSP 112) was delivered to the CANMET facility and testing is scheduled for the week of 11 December 1994. Also at this time, all of the IBCSP samples are being evaluated for blast furnace injection using the CANMET computer model.

  10. Trees Containing Built-In Pulping Catalysts - Final Report - 08/18/1997 - 08/18/2000

    SciTech Connect (OSTI)

    Pullman, G.; Dimmel, D.; Peter, G.

    2000-08-18T23:59:59.000Z

    Several hardwood and softwood trees were analyzed for the presence of anthraquinone-type molecules. Low levels of anthraquinone (AQ) and anthrone components were detected using gas chromatography-mass spectroscopy and sensitive selected-ion monitoring techniques. Ten out of seventeen hardwood samples examined contained AQ-type components; however, the levels were typically below {approximately}6 ppm. No AQs were observed in the few softwood samples that were examined. The AQs were more concentrated in the heartwood of teak than in the sapwood. The delignification of pine was enhanced by the addition of teak chips ({approximately}0.7% AQ-equivalence content) to the cook, suggesting that endogenous AQs can be released from wood during pulping and can catalyze delignification reactions. Eastern cottonwood contained AQ, methyl AQ, and dimethyl AQ, all useful for wood pulping. This is the first time unsubstituted AQ has been observed in wood extracts. Due to the presence of these pulping catalysts, rapid growth rates in plantation settings, and the ease of genetic transformation, eastern cottonwood is a suitable candidate for genetic engineering studies to enhance AQ content. To achieve effective catalytic pulping activity, poplar and cottonwood, respectively, require {approximately}100 and 1000 times more for pulping catalysts. A strategy to increase AQ concentration in natural wood was developed and is currently being tested. This strategy involves ''turning up'' isochorismate synthase (ICS) through genetic engineering. Isochorismate synthase is the first enzyme in the AQ pathway branching from the shikimic acid pathway. In general, the level of enzyme activity at the first branch point or committed step controls the flux through a biosynthetic pathway. To test if the level of ICS regulates AQ biosynthesis in plant tissues, we proposed to over-express this synthase in plant cells. A partial cDNA encoding a putative ICS was available from the random cDNA sequencing project carried out with Arabidopsis thaliana. We used this putative plant ICS gene fragment to isolate and sequence a full-length ICS cDNA from Arabidopsis thaliana. The putative full-length cDNA encodes for a 569 amino acid protein of {approximately}62kDa. This sequence represents the first full-length ICS cDNA isolated from a plant. When inserted into E. coli, our isolated cDNA over-expressed ICS protein in the insoluble inclusion bodies. A plant expression vector containing the ICS cDNA, NP II for selection on the antibiotic kanamycin, and duplicated 35S-cauliflower mosaic virus promoter were inserted into Agrobacterium tumefaciens strain GV3101. Transformation experiments for insertion of these foreign genes into Populus deltoides 'C175' resulted in eight lines able to regenerate shoots and grow roots in the presence of kanamycin. Plants from these eight lines have acclimated to growth in sterile soil and will be moved to a greenhouse environment in spring 2001. Non rooted shoots from each line are currently being multiplied by shoot culture. When enough shoot tissue and/or greenhouse plant stem tissue is available, AQ analysis will be done and compared with non transformed control tissue.

  11. AISI/DOE Technology Roadmap Program Hot Oxygen Injection Into The Blast Furnace

    SciTech Connect (OSTI)

    Michael F. Riley

    2002-10-21T23:59:59.000Z

    Increased levels of blast furnace coal injection are needed to further lower coke requirements and provide more flexibility in furnace productivity. The direct injection of high temperature oxygen with coal in the blast furnace blowpipe and tuyere offers better coal dispersion at high local oxygen concentrations, optimizing the use of oxygen in the blast furnace. Based on pilot scale tests, coal injection can be increased by 75 pounds per ton of hot metal (lb/thm), yielding net savings of $0.84/tm. Potential productivity increases of 15 percent would yield another $1.95/thm. In this project, commercial-scale hot oxygen injection from a ''thermal nozzle'' system, patented by Praxair, Inc., has been developed, integrated into, and demonstrated on two tuyeres of the U.S. Steel Gary Works no. 6 blast furnace. The goals were to evaluate heat load on furnace components from hot oxygen injection, demonstrate a safe and reliable lance and flow control design, and qualitatively observe hot oxygen-coal interaction. All three goals have been successfully met. Heat load on the blowpipe is essentially unchanged with hot oxygen. Total heat load on the tuyere increases about 10% and heat load on the tuyere tip increases about 50%. Bosh temperatures remained within the usual operating range. Performance in all these areas is acceptable. Lance performance was improved during testing by changes to lance materials and operating practices. The lance fuel tip was changed from copper to a nickel alloy to eliminate oxidation problems that severely limited tip life. Ignition flow rates and oxygen-fuel ratios were changed to counter the effects of blowpipe pressure fluctuations caused by natural resonance and by coal/coke combustion in the tuyere and raceway. Lances can now be reliably ignited using the hot blast as the ignition source. Blowpipe pressures were analyzed to evaluate ht oxygen-coal interactions. The data suggest that hot oxygen increases coal combustion in the blow pipe and tuyere by 30, in line with pilot scale tests conducted previously.

  12. Parallell to that, we observed a marked improvement of the feed efficiency that can be attributed to the good energy value of the sugar beet pulp for rabbits.

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    for different kinds of fibre (hemicellulose, true cel- lulose and lignin) are not determined. Comparing lucerne diets based on lucerne, safflower meal, grape pomace and beet pulp. Though not significant, feeding safflower meal and lucerne produced a higher level of lactation as measured by three week fryer weights than

  13. Pulp and paper mill fibrous residuals in excavatable flowable fill Y.-m. Chun, T.R. Naik, & R.N. Kraus

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    biological treatment of wastewater. Fiber reclaim is composed of wood cellulose fibers and moisture mills Fibrous residuals from pulp and paper mills include wastewater-treatment residuals (also called sludge), fiber reclaim, and screening rejects. The basic components of the wastewater-treatment residuals

  14. BLAST OBSERVATIONS OF RESOLVED GALAXIES: TEMPERATURE PROFILES AND THE EFFECT OF ACTIVE GALACTIC NUCLEI ON FIR TO SUBMILLIMETER EMISSION

    SciTech Connect (OSTI)

    Wiebe, Donald V.; Chapin, Edward L.; Halpern, Mark; Marsden, Gaelen [Department of Physics and Astronomy, University of British Columbia, 6224 Agricultural Road, Vancouver, BC V6T 1Z1 (Canada); Ade, Peter A. R.; Griffin, Matthew; Hargrave, Peter C.; Mauskopf, Philip; Pascale, Enzo [School of Physics and Astronomy, Cardiff University, 5 The Parade, Cardiff, CF24 3AA (United Kingdom); Bock, James J. [Jet Propulsion Laboratory, Pasadena, CA 91109-8099 (United States); Devlin, Mark J.; Dicker, Simon; Klein, Jeff; Rex, Marie [Department of Physics and Astronomy, University of Pennsylvania, 209 South 33rd Street, Philadelphia, PA 19104 (United States); Gundersen, Joshua O. [Department of Physics, University of Miami, 1320 Campo Sano Drive, Coral Gables, FL 33146 (United States); Hughes, David H. [Instituto Nacional de AstrofIsica Optica y Electronica, Aptdo. Postal 51 y 216, 72000 Puebla (Mexico); Martin, Peter G. [Canadian Institute for Theoretical Astrophysics, University of Toronto, 60 St. George Street, Toronto, ON M5S 3H8 (Canada); Netterfield, Calvin B. [Department of Physics, University of Toronto, 60 St. George Street, Toronto, ON M5S 1A7 (Canada); Olmi, Luca [Istituto di Radioastronomia, Largo E. Fermi 5, I-50125, Firenze (Italy); Patanchon, Guillaume [Laboratoire APC, 10, rue Alice Domon et Leonie Duquet 75205 Paris (France)

    2009-12-20T23:59:59.000Z

    Over the course of two flights, the Balloon-borne Large Aperture Submillimeter Telescope (BLAST) made resolved maps of seven nearby (<25 Mpc) galaxies at 250, 350, and 500 mum. During its 2005 June flight from Sweden, BLAST observed a single nearby galaxy, NGC 4565. During the 2006 December flight from Antarctica, BLAST observed the nearby galaxies NGC 1097, NGC 1291, NGC 1365, NGC 1512, NGC 1566, and NGC 1808. We fit physical dust models to a combination of BLAST observations and other available data for the galaxies observed by Spitzer. We fit a modified blackbody to the remaining galaxies to obtain total dust mass and mean dust temperature. For the four galaxies with Spitzer data, we also produce maps and radial profiles of dust column density and temperature. We measure the fraction of BLAST detected flux originating from the central cores of these galaxies and use this to calculate a 'core fraction', an upper limit on the 'active galactic nucleus fraction' of these galaxies. We also find our resolved observations of these galaxies give a dust mass estimate 5-19 times larger than an unresolved observation would predict. Finally, we are able to use these data to derive a value for the dust mass absorption coefficient of kappa = 0.29 +- 0.03 m{sup 2} kg{sup -1} at 250 mum. This study is an introduction to future higher-resolution and higher-sensitivity studies to be conducted by Herschel and SCUBA-2.

  15. Burden distribution control for maintaining the central gas flow at No. 1 blast furnace in Pohang Works

    SciTech Connect (OSTI)

    Jung, S.K.; Lee, Y.J.; Suh, Y.K.; Ahn, T.J.; Kim, S.M. [Pohang Iron and Steel Co. Ltd. (Korea, Republic of). Technical Research Labs.

    1995-12-01T23:59:59.000Z

    The causes for temperature lowering at the upper shaft center in Pohang No. 1 blast furnace were investigated. The test operation with charging notch change in the actual blast furnace and with a 1/12 scale model to Pohang No. 1 blast furnace were carried out in order to improve central gas flow in the shaft. Finally, rebuilding of the lower bunker interior was performed using the results of model experiments. It was confirmed that the main reason for the gas temperature lowering at the upper shaft center was the smaller particle size at center than the wall according to the discharging characteristics of center feed bunker with stone box. The central gas flow could be secured through modifying the stone box in the bunker.

  16. A new direct steel making process based upon the blast furnace (Including scrap processing with recovery of tramp elements)

    SciTech Connect (OSTI)

    Nabi, G.

    1996-12-31T23:59:59.000Z

    Steel is produced from raw materials containing iron and alloying elements with direct elimination of oxygen and impurities in the blast furnace process. The blast furnace shaft is modified to take off load from the liquid bath and carbon is prevented from going into the liquid steel. In the gas purification system sulphur and CO{sub 2} removal facilities are included and purified reducing gases so obtained are combusted in the hearth with oxygen to produce heat for smelting. Scrap can be charged as raw material with the recovery of tramp elements with continuous production of liquid steel.

  17. The Blast-Wave-Driven Instability as a Vehicle for Understanding Supernova Explosion Structure

    SciTech Connect (OSTI)

    Miles, A R

    2008-05-27T23:59:59.000Z

    Blast-wave-driven instabilities play a rich and varied role throughout the evolution of supernovae from explosion to remnant, but interpreting their role is difficult due to the enormous complexity of the stellar systems. We consider the simpler and fundamental hydrodynamic instability problem of a material interface between two constant-density fluids perturbed from spherical and driven by a divergent central Taylor-Sedov blast wave. The existence of unified solutions at high Mach number and small density ratio suggests that general conclusions can be drawn about the likely asymptotic structure of the mixing zone. To this end we apply buoyancy-drag and bubble merger models modified to include the effects of divergence and radial velocity gradients. In general, these effects preclude the true self-similar evolution of classical Raleigh-Taylor, but can be incorporated into a quasi-self-similar growth picture. Loss of memory of initial conditions can occur in the quasi-self-similar model, but requires initial mode numbers higher than those predicted for pre-explosion interfaces in Type II SNe, suggesting that their late-time structure is likely strongly influenced by details of the initial perturbations. Where low-modes are dominant, as in the Type Ia Tycho remnant, they result from initial perturbations rather than generation from smaller scales. Therefore, structure observed now contains direct information about the explosion process. When large-amplitude modes are present in the initial conditions, the contribution to the perturbation growth from the Richtmyer-Meshkov instability is significant or dominant compared to Rayleigh-Taylor. Such Richtmyer-Meshkov growth can yield proximity of the forward shock to the growing spikes and structure that strongly resembles that observed in the Tycho. Laser-driven high-energy-density laboratory experiments offer a promising avenue for testing model and simulation descriptions of blast-wave-driven instabilities and making connections to their astrophysical counterparts.

  18. Monitoring lining and hearth conditions at Inland`s No. 7 blast furnace

    SciTech Connect (OSTI)

    Quisenberry, P.; Grant, M.; Carter, W.

    1997-12-31T23:59:59.000Z

    The paper describes: furnace statistics; mini-reline undertaken in November, 1993; the stack condition; throat gunning; stabilizing the graphite bricks; the hearth condition; reactions to temperature excursions; future instrumentation; and hot blast system areas of concern. The present data from monitoring systems and inspections indicate that the furnace should be able to operate well beyond the expectation for the 1993 mini-reline (3--5 years) with: (1) consistent, high quality raw materials; (2) instrumentation, diagnostic, remedial, and preventative techniques developed; and (3) stopping quickly any water leaks into the furnace. The longevity of this campaign has undoubtedly been a result of this monitoring program.

  19. Continuous measurement of blast furnace burden profile at SSAB Tunnplat AB

    SciTech Connect (OSTI)

    Virtala, J.; Edberg, N.; Hallin, M. (SSAB Tunnplat AB, Lulea (Sweden). Ironmaking Division)

    1993-01-01T23:59:59.000Z

    A unique profile meter system is installed on Blast Furnace No. 2 in SSAB - Swedish Steel AB, Lulea, Sweden. This system measures the charge material burden profile across the furnace top diameter before and after each charge. The system generates real-time data, which is graphically presented by the system on a monitor and includes burden descent speed, layer thickness of the coke and ore (corrected for descent), ore to coke ratio, and burden skewing. The system is described along with operational results.

  20. Bosh repairs No. 3 blast furnace, Edgar Thomson Plant Mon Valley Works

    SciTech Connect (OSTI)

    Stoupis, M.G.

    1993-01-01T23:59:59.000Z

    The paper describes in detail the steps taken from quenching to dry out of the furnace to repair the bosh area of the No.3 blast furnace. Inspection of the area revealed that there was no brick anywhere in the bosh. Brick in the tuyere breast area had been peeled back to reveal the steel plate, and descaling revealed 14 pipes fully exposed. None were leaking, but one seemed badly deteriorated. Conventional repairs could not take place before the scheduled blow-in. Installation of coolers were instead tried.

  1. A method for burden distribution estimation from probe data in the blast furnace

    SciTech Connect (OSTI)

    Nikus, M.; Saxen, H.; Bulsari, A. [Aabo Akademi Univ. (Finland). Dept. of Chemical Engineering

    1996-12-31T23:59:59.000Z

    A novel approach for estimation of burden distribution in the blast furnace is presented. The proposed model makes use of only temperature measurements from an above-burden probe, and interprets the changes in temperature at charging in terms of burden distribution. In this study it is demonstrated that the temperature changes can be predicted quite accurately for all dumps in a charging sequence using neural networks., The basic structures of both an on-line and an off-line model are presented.

  2. Suppressor for reducing the muzzle blast and flash of a firearm

    SciTech Connect (OSTI)

    Klett, James W

    2014-09-30T23:59:59.000Z

    Disclosed are several examples of apparatuses for suppressing the blast and flash produced as a projectile is expelled by gases from a firearm. In some examples, gases are diverted away from the central chamber to an expansion chamber by baffles. The gases are absorbed by the expansion chamber and desorbed slowly, thus decreasing pressure and increasing residence time of the gases. In other examples, the gases impinge against a plurality of rods before expanding through passages between the rods to decrease the pressure and increase the residence time of the gases.

  3. Computational and in vitro studies of blast-induced blood-brain barrier disruption

    E-Print Network [OSTI]

    Del Razo, Mauricio J; Meabon, James S; Huber, B Russell; Peskind, Elaine R; Banks, William A; Mourad, Pierre D; Leveque, Randall J; Cook, David G

    2015-01-01T23:59:59.000Z

    There is growing concern that blast-exposed individuals are at risk of developing neurological disorders later in life. Therefore, it is important to understand the dynamic properties of blast forces on brain cells, including the endothelial cells that maintain the blood-brain barrier (BBB), which regulates the passage of nutrients into the brain and protects it from toxins in the blood. To better understand the effect of shock waves on the BBB we have investigated an {\\em in vitro} model in which BBB endothelial cells are grown in transwell vessels and exposed in a shock tube, confirming that BBB integrity is directly related to shock wave intensity. It is difficult to directly measure the forces acting on these cells in the transwell container during the experiments, and so a computational tool has been developed and presented in this paper. Two-dimensional axisymmetric Euler equations with the Tammann equation of state were used to model the transwell materials, and a high-resolution finite volume method b...

  4. Production and blast-furnace smelting of boron-alloyed iron-ore pellets

    SciTech Connect (OSTI)

    A.A. Akberdin; A.S. Kim [Abishev Chemicometallurgical Institute, Abishev (Kazakhstan)

    2008-08-15T23:59:59.000Z

    Industrial test data are presented regarding the production (at Sokolovsk-Sarbaisk mining and enrichment enterprise) and blast-furnace smelting (at Magnitogorsk metallurgical works) of boron-alloyed iron-ore pellets (500000 t). It is shown that, thanks to the presence of boron, the compressive strength of the roasted pellets is increased by 18.5%, while the strength in reduction is doubled; the limestone consumption is reduced by 11%, the bentonite consumption is halved, and the dust content of the gases in the last section of the roasting machines is reduced by 20%. In blast-furnace smelting, the yield of low-sulfur (<0.02%) hot metal is increased from 65-70 to 85.1% and the furnace productivity from 2.17-2.20 to 2.27 t/(m{sup 3} day); coke consumption is reduced by 3-8 kg/t of hot metal. The plasticity and stamping properties of 08IO auto-industry steel are improved by microadditions of boron.

  5. Gary Works No. 13 blast furnace: A new removable trough design

    SciTech Connect (OSTI)

    Schuett, K.J.; Pawlak, J.P. [U.S. Steel Group, Gary, IN (United States). Gary Works; Traina, L.; Brenneman, R.G.

    1995-12-01T23:59:59.000Z

    No. 13 Blast Furnace at US Steel`s Gary Works is a 35 tuyere furnace with a 36.5 ft. hearth capable of producing over 9,000 tons of hot metal per day. The current casthouse design was placed in service following the second reline in the fall of 1979. This design anticipated daily production rates averaging 7,500 tons of hot metal per day and provided for removable troughs at two of the three tapholes. At the time, the troughs were rammed with a high alumina/silicon carbide granular ramming material that provided the operators with trough campaign lives between 60,000--70,000 tons of hot metal produced. As refractory technology progressed, low cement/low moisture castables were introduced to the trough systems on No. 13 Blast Furnace. The immediate success of the castables was tempered by emergence of a new unexpected problem. That problem was the thermal expansion of the castable. The paper describes the problems that resulted in the need to modify the trough design, the new design of the trough, and its improvement in iron trough campaign life and reliability.

  6. Hydrodynamic Modeling of Air Blast Propagation from the Humble Redwood Chemical High Explosive Detonations Using GEODYN

    SciTech Connect (OSTI)

    Chipman, V D

    2011-09-20T23:59:59.000Z

    Two-dimensional axisymmetric hydrodynamic models were developed using GEODYN to simulate the propagation of air blasts resulting from a series of high explosive detonations conducted at Kirtland Air Force Base in August and September of 2007. Dubbed Humble Redwood I (HR-1), these near-surface chemical high explosive detonations consisted of seven shots of varying height or depth of burst. Each shot was simulated numerically using GEODYN. An adaptive mesh refinement scheme based on air pressure gradients was employed such that the mesh refinement tracked the advancing shock front where sharp discontinuities existed in the state variables, but allowed the mesh to sufficiently relax behind the shock front for runtime efficiency. Comparisons of overpressure, sound speed, and positive phase impulse from the GEODYN simulations were made to the recorded data taken from each HR-1 shot. Where the detonations occurred above ground or were shallowly buried (no deeper than 1 m), the GEODYN model was able to simulate the sound speeds, peak overpressures, and positive phase impulses to within approximately 1%, 23%, and 6%, respectively, of the actual recorded data, supporting the use of numerical simulation of the air blast as a forensic tool in determining the yield of an otherwise unknown explosion.

  7. Energy-Dependent Gamma-Ray Burst Peak Durations and Blast-Wave Deceleration

    E-Print Network [OSTI]

    James Chiang

    1998-05-22T23:59:59.000Z

    Temporal analyses of the prompt gamma-ray and X-ray light curves of gamma-ray bursts reveal a tendency for the burst pulse time scales to increase with decreasing energy. For an ensemble of BATSE bursts, Fenimore et al. (1995) show that the energy dependence of burst peak durations can be represented by $\\Delta t \\propto E^{-\\gamma}$ with $\\gamma \\simeq 0.4$--0.45. This power-law dependence has led to the suggestion that this effect is due to radiative processes, most notably synchrotron cooling of the non-thermal particles which produce the radiation. Here we show that a similar power-law dependence occurs, under certain assumptions, in the context of the blast-wave model and is a consequence of the deceleration of the blast-wave. This effect will obtain whether or not synchrotron cooling is important, but different degrees of cooling will cause variations in the energy dependence of the peak durations.

  8. Speciation of Zn in Blast Furnace Sludge from Former Sedimentation Ponds Using Synchrotron Xray Diffraction, Fluorescence, and

    E-Print Network [OSTI]

    , University of Cologne, Albertus-Magnus-Platz, D-50923 Koln, Germany 搂 Advanced Light Source, Lawrence *S Supporting Information ABSTRACT: Blast furnace sludge (BFS), an industrial waste generated in pig on a former BFS sedimentation pond site. Additionally, one fresh BFS was analyzed for comparison. We

  9. Lab 3. Using PSI-BLAST, the Taxonomy Report, the CDD analysis, and PFAM to look at proteins.

    E-Print Network [OSTI]

    Sj鰈ander, Kimmen

    Lab 3. Using PSI-BLAST, the Taxonomy Report, the CDD analysis, and PFAM to look at proteins. Does this agree with PFAM? 4. Are there any PDB hits identified in the results? Use the taxonomy report) protein Now, use the taxonomy browser to look at hits in the different genomes. 7. How many hits in human

  10. Integrated use of burden profile probe and in-burden probe for gas flow control in the blast furnace

    SciTech Connect (OSTI)

    Bordemann, F.; Hartig, W.H. [AG der Dillinger Huettenweke, Dillingen (Germany); Grisse, H.J. [Dango and Dienenthal Siegen (Germany); Speranza, B.E. [Dango and Dienenthal, Inc., Highland, IN (United States)

    1995-12-01T23:59:59.000Z

    Gas flow in the blast furnace is one of the most important factors in controlling a furnace. It not only determines the production but also the fuel consumption and the campaign life. At Nos. 4 and 5 blast furnaces of ROGESA, probes are installed for detection of the burden profiles and of the gas flow distribution. For an optimum use of these probes a program system has been developed by ROGESA and Dango and Dienenthal. With this program system it is possible to analyze the operating condition of a blast furnace by means of a fuzzy logic analysis. In case of deviations from the defined desired condition, recommendations for corrective measures for the material distribution are made. Both furnaces are equipped with a bell-less top, a coal injection system, high-temperature hot blast stoves with heat recovery and a top gas pressure recovery turbine. Most of the time it is impossible to control all the required parameters. For this reason it is meaningful to measure the actual material distribution at the furnace top by means of a burden profile probe which permits quick and repeated measurements without any retroactive effects. The paper describes the instrumentation of the furnace, correlation of measuring methods, and a program system for analysis of measuring data.

  11. Interfacing computer-assisted drafting and design with the building loads analysis and system thermodynamics (BLAST) program. Final report

    SciTech Connect (OSTI)

    Morton, J.D.; Pyo, C.; Choi, B.

    1992-10-01T23:59:59.000Z

    Energy efficient building design requires in-depth thermal analysis. Existing Computer Aided Design and Drafting (CADD) software packages already enhance the productivity and quality of design. Thermal analysis tools use much the same information as that contained in CADD drawings to determine the most energy efficient design configuration during the design process. To use these analysis tools, data already contained in the CADD system must be re-keyed into the analysis packages. This project created an interface to automate the migration of data from CADD to the Building Loads Analysis System and Thermodynamics (BLAST) analysis program, which is an Army-standard system for evaluating building energy performance. Two interfaces were developed, one batch-oriented (IN2BLAS7) and one interactive (the Drawing Navigator). Lessons learned from the development of IN2BLAST were carried into the development of the Drawing Navigator, and the Drawing Navigator was field tested. Feedback indicated that useful automation of the data migration is possible, and that proper application of such automation can increase productivity.... Blast, CADD, Interface, IN2BLAST, Drawing navigator.

  12. Process Simulation and Control Optimization of a Blast Furnace Using Classical Thermodynamics Combined to a Direct Search

    E-Print Network [OSTI]

    Martin, Alain

    consisting mainly of N2, CO, CO2, H2, and H2O. This is a consequence of the reduction of the iron ore volume methods, data-mining models, heat and mass balance models, and classical thermodynamic simulations-tune the simulation of the blast furnace. Optimal operating conditions and predicted output stream properties

  13. Freeze Crystallization: Improving the Energy Efficiency of a Low-Energy Separation Process

    E-Print Network [OSTI]

    Heist, J. A.

    1981-01-01T23:59:59.000Z

    load reductions. Pulp and Paper Mills - This industry has both large quantities of waste heat and large flows of process fluids. The most concentrated of the streams, black liquor from digestion of the lignin in the wood, is concentrated...

  14. ANNUAL HEATING AND COOLING REQUIREMENTS AND DESIGN DAY PERFORMANCE FOR A RESIDENTIAL MODEL IN SIX CLIMATES: A COMPARISON OF NBSLD, BLAST 2, AND DOE-2.1

    E-Print Network [OSTI]

    Carroll, William L.

    2011-01-01T23:59:59.000Z

    BLAST DOE-2 (SWF) Annual Cooling Requirements (10 6 Btu)Btu) I'" I NBSLD III DOE-2 (SW'F) DOE-2 (CW'F) DOE-2 (CWF)Heating (1 Annual Total Btu) City Jan HINNEAPOLIS NBSLD

  15. Characterization of Microbial Communities in Subsurface Nuclear Blast Cavities of the Nevada Test Site

    SciTech Connect (OSTI)

    Moser, Duane; Russell, Chuck; Marshall, Matthew; Czerwinski, Ken; Daly, Michael J; Zavarin, Mavrik

    2008-02-08T23:59:59.000Z

    This exploratory research project is designed to test fundamental hypotheses concerning the possible existence and nature of indigenous microbial populations in Nevada Test Site (NTS) subsurface nuclear blast cavities. Although subsurface microbiological studies have been performed at the NTS in the past, radioactive zones have yet to be addressed. Nuclear blast zone microbiology is a completely new field and our team is well-positioned to collect and analyze samples that have never before been available to microbiologists. Relevant samples are now being obtained by incorporating microbiological collections into an ongoing annual hot well sampling program being conducted by other agencies. A combination of cultivation-based and molecular microbial detection protocols is being utilized at multiple locations to survey for uncultivable microorganisms and to develop a culture collection which will be characterized for radionuclide- and metal-reduction capabilities. Given that redox manipulations mediated by microorganisms can impact the mobility of DOE contaminants, a positive outcome from this work would have significant implications for management strategies at this and other DOE sites. A primary objective of the project has been the establishment of the regulatory and technical framework necessary to enable our acquisition of samples. Thus, much of our activity in the first phase of this work has involved the development an approved Field Area Work Plan (FAWP), Radiological Work Permit (RWP), and other documentation required for radiological work at the NTS. We have also invested significant time into ensuring that all personnel possess the required training (e.g. Radworker II and 40 hr. HAZWOPER) for access to the hot well sampling sites. Laboratory facilities, required for field processing of radioactive samples as well as DNA extraction and other manipulations, have been secured both the NTS (Mercury, NV) and UNLV. Although our year-1 field work was delayed due to non-availability of samples, an aggressive sampling campaign is now underway and our first hot well samples were collected on Feb 5th, 2008. The unique nature of this site, coupled with the combined expertise of the collaborating laboratories (DRI, LLNL, PNNL, and the Harry Reid Center) makes the likelihood of our achieving discoveries of value to DOE, the individual researchers, and society high. As the selective pressures at atomic blast sites are probably different from those of production and disposal sites, these habitats may contain novel organisms of utility for bioremediation. Such organisms will have had to develop physiological mechanisms to survive high doses of ionizing radiation over the variety of rock types and hydrologic environments present at the NTS.

  16. Safer blasting agents and procedures for blasting in gassy non-coal mines. Final report, September 9, 1990--December 31, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    Hundreds of tests have been conducted in the Bureau`s Lake Lynn Laboratory Cannon Gallery to evaluate the incendivity characteristics of both commercially available and experimental explosive products. The cannon gallery test results have clearly identified several lower incendive explosives that can and have significantly reduced the gas and/or dust ignition hazards associated with blasting in non-coal mines. Several of the lower incendive explosive formulations have undergone full-scale field evaluations and, to date, had been very successful in preventing ignitions in base metal mines with high sulphur-bearing ore. Tests in the cannon gallery have shown that an inert gelled water material outperforms most other stemming agents in preventing the ignition of flammable gases and/or combustible dusts outside of the bore. A new water stemming plug was evaluated in the cannon gallery and shown to be a very effective stemming device. As a means to better evaluate explosive incendivity, the initial development of two instrument sensors are underway. A fiber optic rate probe has been redesigned to accurately measure the detonation velocity of explosives in the cannon bore. A photometric sensor is also under development to measure the peak temperatures of the detonation products exiting the bore. This report discusses the results of the research program including the test apparatus and procedures and summarizes the incendivity data obtained from the various explosives. Results from the full-scale field testing of the lower incendive products in an operating mine are then presented.

  17. Elevated extracellular calcium increases expression of bone morphogenetic protein-2 gene via a calcium channel and ERK pathway in human dental pulp cells

    SciTech Connect (OSTI)

    Tada, Hiroyuki [Division of Periodontology and Endodontology, Tohoku University Graduate School of Dentistry, Sendai 980-8575 (Japan)] [Division of Periodontology and Endodontology, Tohoku University Graduate School of Dentistry, Sendai 980-8575 (Japan); Nemoto, Eiji, E-mail: e-nemoto@umin.ac.jp [Division of Periodontology and Endodontology, Tohoku University Graduate School of Dentistry, Sendai 980-8575 (Japan)] [Division of Periodontology and Endodontology, Tohoku University Graduate School of Dentistry, Sendai 980-8575 (Japan); Kanaya, Sousuke; Hamaji, Nozomu; Sato, Hisae; Shimauchi, Hidetoshi [Division of Periodontology and Endodontology, Tohoku University Graduate School of Dentistry, Sendai 980-8575 (Japan)] [Division of Periodontology and Endodontology, Tohoku University Graduate School of Dentistry, Sendai 980-8575 (Japan)

    2010-04-16T23:59:59.000Z

    Dental pulp cells, which have been shown to share phenotypical features with osteoblasts, are capable of differentiating into odontoblast-like cells and generating a dentin-like mineral structure. Elevated extracellular Ca{sup 2+}Ca{sub o}{sup 2+} has been implicated in osteogenesis by stimulating the proliferation and differentiation of osteoblasts; however, the role of Ca{sub o}{sup 2+} signaling in odontogenesis remains unclear. We found that elevated Ca{sub o}{sup 2+} increases bone morphogenetic protein (BMP)-2 gene expression in human dental pulp cells. The increase was modulated not only at a transcriptional level but also at a post-transcriptional level, because treatment with Ca{sup 2+} increased the stability of BMP-2 mRNA in the presence of actinomycin D, an inhibitor of transcription. A similar increase in BMP-2 mRNA level was observed in other human mesenchymal cells from oral tissue; periodontal ligament cells and gingival fibroblasts. However, the latter cells exhibited considerably lower expression of BMP-2 mRNA compared with dental pulp cells and periodontal ligament cells. The BMP-2 increase was markedly inhibited by pretreatment with an extracellular signal-regulated kinase (ERK) inhibitor, PD98059, and partially inhibited by the L-type Ca{sup 2+} channels inhibitor, nifedipine. However, pretreatment with nifedipine had no effect on ERK1/2 phosphorylation triggered by Ca{sup 2+}, suggesting that the Ca{sup 2+} influx from Ca{sup 2+} channels may operate independently of ERK signaling. Dental pulp cells do not express the transcript of Ca{sup 2+}-sensing receptors (CaSR) and only respond slightly to other cations such as Sr{sup 2+} and spermine, suggesting that dental pulp cells respond to Ca{sub o}{sup 2+} to increase BMP-2 mRNA expression in a manner different from CaSR and rather specific for Ca{sub o}{sup 2+} among cations.

  18. Carbon emissions reduction potential in the US chemicals and pulp and paper industries by applying CHP technologies

    SciTech Connect (OSTI)

    Khrushch, M.; Worrell, E.; Price, L.; Martin, N.; Einstein, D.

    1999-07-01T23:59:59.000Z

    The chemical and the pulp/paper industries combined provide 55% of CHP generation in the US industry. Yet, significant potential for new CHP capacities exists in both industries. From the present steam consumption data, the authors estimate about 50 GW of additional technical potential for CHP in both industries. The reduced carbon emissions will be equivalent to 44% of the present carbon emissions in these industries. They find that most of the carbon emissions reductions can be achieved at negative costs. Depending on the assumptions used in calculations, the economic potential of CHP in these industries can be significantly lower, and carbon emissions mitigation costs can be much higher. Using sensitivity analyses, they determine that the largest effect on the CHP estimate have the assumptions in the costs of CHP technology, in the assumed discount rates, in improvements in efficiency of CHP technologies, and in the CHP equipment depreciation periods. Changes in fuel and electricity prices and the growth in the industries' steam demand have less of an effect. They conclude that the lowest carbon mitigation costs are achieved with the CHP facility is operated by the utility and when industrial company that owns the CHP unit can sell extra electricity and steam to the open wholesale market. Based on the results of the analyses they discuss policy implications.

  19. Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace

    SciTech Connect (OSTI)

    Dr. Chenn Zhou

    2008-10-15T23:59:59.000Z

    Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

  20. The push for increased coal injection rates -- Blast furnace experience at AK Steel Corporation

    SciTech Connect (OSTI)

    Dibert, W.A.; Duncan, J.H.; Keaton, D.E.; Smith, M.D. [AK Steel Corp., Middletown, OH (United States)

    1994-12-31T23:59:59.000Z

    An effort has been undertaken to increase the coal injection rate on Amanda blast furnace at AK Steel Corporation`s Ashland Works in Ashland, Kentucky to decrease fuel costs and reduce coke demand. Operating practices have been implemented to achieve a sustained coal injection rate of 140 kg/MT, increased from 100--110 kg/MT. In order to operate successfully at the 140 kg/MT injection rate; changes were implemented to the furnace charging practice, coal rate control methodology, orientation of the injection point, and the manner of distribution of coal to the multiple injection points. Additionally, changes were implemented in the coal processing facility to accommodate the higher demand of pulverized coal; grinding 29 tonnes per hour, increased from 25 tonnes per hour. Further increases in injection rate will require a supplemental supply of fuel.

  1. Gary No. 13 blast furnace achieves 400 lbs/THM coal injection in 9 months

    SciTech Connect (OSTI)

    Sherman, G.J.; Schuett, K.J.; White, D.G.; O`Donnell, E.M. [U.S. Steel Group, Gary, IN (United States)

    1995-12-01T23:59:59.000Z

    Number 13 Blast Furnace at Gary began injecting Pulverized Coal in March 1993. The injection level was increased over the next nine months until a level off 409 lbs/THM was achieved for the month of December 1993. Several major areas were critical in achieving this high level of Pulverized coal injection (PCI) including furnace conditions, lance position, tuyere blockage, operating philosophy, and outages. The paper discusses the modifications made to achieve this level of injection. This injection level decreased charged dry coke rate from 750 lbs/THM to about 625 lbs/THM, while eliminating 150 lbs/THM of oil and 20 lbs/THM of natural gas. Assuming a 1.3 replacement ratio for an oil/natural gas mixture, overall coke replacement for the coal is about 0.87 lbs coke/lbs coal. Gary Works anticipates levels of 500 lbs/THM are conceivable.

  2. A study on the flow of molten iron in the hearth of blast furnace

    SciTech Connect (OSTI)

    Suh, Y.K.; Lee, Y.J.; Baik, C.Y. [Pohang Iron and Steel Co., Ltd. (Korea, Republic of). Technical Research Labs.

    1996-12-31T23:59:59.000Z

    The flow of molten iron in the hearth of blast furnace was investigated by using a water model test and a numerical simulation. The water model apparatus was set up in order to evaluate the effects of coke size, coke bed structure, drain rate, and coke free space on the fluidity of molten iron through measurement of residence time and visualization of flow pattern. In addition, the flow was calculated by solving momentum equation in porous media using finite element method. The residence time increased with the coke size decrease, but decreased with the drain rate increase. If small coke was placed in the center of deadman, peripheral flow was enhanced. The flow path was changed due to the coke free space.

  3. Hoogovens blast furnace No. 6 -- The first eleven years of a continuing campaign

    SciTech Connect (OSTI)

    Tijhuis, G.; Toxopeus, H.; Berg, H. van den; Vliet, C. van der [Hoogovens Steel, IJmuiden (Netherlands)

    1997-12-31T23:59:59.000Z

    Blast furnace No. 6 of Hoogovens Steel has just completed its eleventh year of the fourth (running) campaign, with a total production of approx. 23 million metric tonnes of hot metal. During the last reline in 1985 the furnace was equipped with a third taphole and a bell-less top. The lining consists of graphite and semi-graphite and the cooling consists of a dense pattern of copper plate coolers. The current campaign is marked by several important operational events, in particular the high productivity and PCI rates, but also by the remarkable performance of the lining which has shown limited wear in the first four years of the campaign, and hardly any reduction of the lining thickness in the last seven years. This paper discusses the design of the furnace, and the history of the current campaign with respect to its productivity, PCI rates and lining wear.

  4. Finite element analysis of the Arquin-designed CMU wall under a dynamic (blast) load.

    SciTech Connect (OSTI)

    Lopez, Carlos; Petti, Jason P.

    2008-12-01T23:59:59.000Z

    The Arquin Corporation designed a CMU (concrete masonry unit) wall construction and reinforcement technique that includes steel wire and polymer spacers that is intended to facilitate a faster and stronger wall construction. Since the construction method for an Arquin-designed wall is different from current wall construction practices, finite element computer analyses were performed to estimate the ability of the wall to withstand a hypothetical dynamic load, similar to that of a blast from a nearby explosion. The response of the Arquin wall was compared to the response of an idealized standard masonry wall exposed to the same dynamic load. Results from the simulations show that the Arquin wall deformed less than the idealized standard wall under such loading conditions. As part of a different effort, Sandia National Laboratories also looked at the relative static response of the Arquin wall, results that are summarized in a separate SAND Report.

  5. Study of radiative blast waves generated on the Z-beamlet laser.

    SciTech Connect (OSTI)

    Edens, Aaron D.; Schwarz, Jens

    2012-02-01T23:59:59.000Z

    This document describes the original goals of the project to study the Vishniac Overstability on blast waves produced using the Z-Beamlet laser facility as well as the actual results. The proposed work was to build on earlier work on the facility and result in the best characterized set of data for such phenomena in the laboratory. To accomplish the goals it was necessary to modify the existing probe laser at the facility so that it could take multiple images over the course of 1-2 microseconds. Troubles with modifying the probe laser are detailed as well as the work that went into said modifications. The probe laser modification ended up taking the entire length of the project and were the major accomplishment of the research.

  6. Assessing the Vulnerability of Large Critical Infrastructure Using Fully-Coupled Blast Effects Modeling

    SciTech Connect (OSTI)

    McMichael, L D; Noble, C R; Margraf, J D; Glascoe, L G

    2009-03-26T23:59:59.000Z

    Structural failures, such as the MacArthur Maze I-880 overpass in Oakland, California and the I-35 bridge in Minneapolis, Minnesota, are recent examples of our national infrastructure's fragility and serve as an important reminder of such infrastructure in our everyday lives. These two failures, as well as the World Trade Center's collapse and the levee failures in New Orleans, highlight the national importance of protecting our infrastructure as much as possible against acts of terrorism and natural hazards. This paper describes a process for evaluating the vulnerability of critical infrastructure to large blast loads using a fully-coupled finite element approach. A description of the finite element software and modeling technique is discussed along with the experimental validation of the numerical tools. We discuss how such an approach can be used for specific problems such as modeling the progressive collapse of a building.

  7. ON THE AMPLIFICATION OF MAGNETIC FIELD BY A SUPERNOVA BLAST SHOCK WAVE IN A TURBULENT MEDIUM

    SciTech Connect (OSTI)

    Guo Fan; Li Shengtai; Li Hui; Li, David [Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Giacalone, Joe; Jokipii, J. R. [Department of Planetary Sciences and Lunar and Planetary Laboratory, University of Arizona, 1629 E. University Blvd., Tucson, AZ 85721 (United States)

    2012-03-10T23:59:59.000Z

    We have performed extensive two-dimensional magnetohydrodynamic simulations to study the amplification of magnetic fields when a supernova blast wave propagates into a turbulent interstellar plasma. The blast wave is driven by injecting high pressure in the simulation domain. The interstellar magnetic field can be amplified by two different processes, occurring in different regions. One is facilitated by the fluid vorticity generated by the 'rippled' shock front interacting with the background turbulence. The resulting turbulent flow keeps amplifying the magnetic field, consistent with earlier work. The other process is facilitated by the growth of the Rayleigh-Taylor instability at the contact discontinuity between the ejecta and the shocked medium. This can efficiently amplify the magnetic field and tends to produce the highest magnetic field. We investigate the dependence of the amplification on numerical parameters such as grid-cell size and on various physical parameters. We show that the magnetic field has a characteristic radial profile such that the downstream magnetic field gets progressively stronger away from the shock. This is because the downstream magnetic field needs a finite time to reach the efficient amplification, and will get further amplified in the Rayleigh-Taylor region. In our simulation, we do not observe a systematic strong magnetic field within a small distance to the shock. This indicates that if the magnetic-field amplification in supernova remnants indeed occurs near the shock front, other processes such as three-dimensional instabilities, plasma kinetics, and/or cosmic ray effect may need to be considered to explain the strong magnetic field in supernova remnants.

  8. VOLUME 87, NUMBER 8 P H Y S I C A L R E V I E W L E T T E R S 20 AUGUST 2001 Investigation of Ultrafast Laser-Driven Radiative Blast Waves

    E-Print Network [OSTI]

    Ditmire, Todd

    . This is believed to be due to the stabilizing effect of a relatively thick blast wave shell resulting in part from of Ultrafast Laser-Driven Radiative Blast Waves M.J. Edwards,1 A. J. MacKinnon,1 J. Zweiback,1 K. Shigemori,2 D blast waves produced by the deposition of femtosecond laser pulses in gas jets. In high-Z gases

  9. Compliance Monitoring of Underwater Blasting for Rock Removal at Warrior Point, Columbia River Channel Improvement Project, 2009/2010

    SciTech Connect (OSTI)

    Carlson, Thomas J.; Johnson, Gary E.; Woodley, Christa M.; Skalski, J. R.; Seaburg, Adam

    2011-05-10T23:59:59.000Z

    The U.S. Army Corps of Engineers, Portland District (USACE) conducted the 20-year Columbia River Channel Improvement Project (CRCIP) to deepen the navigation channel between Portland, Oregon, and the Pacific Ocean to allow transit of fully loaded Panamax ships (100 ft wide, 600 to 700 ft long, and draft 45 to 50 ft). In the vicinity of Warrior Point, between river miles (RM) 87 and 88 near St. Helens, Oregon, the USACE conducted underwater blasting and dredging to remove 300,000 yd3 of a basalt rock formation to reach a depth of 44 ft in the Columbia River navigation channel. The purpose of this report is to document methods and results of the compliance monitoring study for the blasting project at Warrior Point in the Columbia River.

  10. PERFORMANCE OF RC AND FRC WALL PANELS REINFORCED WITH MILD STEEL AND GFRP COMPOSITES IN BLAST EVENTS

    SciTech Connect (OSTI)

    Timothy Garfield; William D. Richins; Thomas K. Larson; Chris P. Pantelides; James E. Blakeley

    2011-06-01T23:59:59.000Z

    The structural integrity of reinforced concrete structures in blast events is important for critical facilities. This paper presents experimental data generated for calibrating detailed finite element models that predict the performance of reinforced concrete wall panels with a wide range of construction details under blast loading. The test specimens were 1.2 m square wall panels constructed using Normal Weight Concrete (NWC) or Fiber Reinforced Concrete (FRC). FRC consists of macro-synthetic fibers dispersed in NWC. Five types of panels were tested: NWC panels with steel bar reinforcement (Type A); FRC panels without additional reinforcement (Type B); FRC panels with steel bar reinforcement (Type C); NWC panels with glass fiber reinforced polymer (GFRP) bar reinforcement (Type D); and NWC panels reinforced with steel bar reinforcement and external bidirectional GFRP overlays on both faces (Type E). An additional three Type C panels were used as control specimens (CON). Each panel type was constructed with three thicknesses: 152 mm, 254 mm, and 356 mm. The panels were instrumented with strain gauges, and accelerometers; in addition, pressure sensors and high speed videos were employed during the blast events. Panel types C and E had the best performance, whereas panel type B did not perform well. Preliminary dynamic simulations show crack patterns similar to the experimental results.

  11. Overcoming the Recalcitrance of Cellulosic Biomass by Value Prior to Pulping: Cooperative Research and Development Final Report, CRADA Number CRD-07-221

    SciTech Connect (OSTI)

    Lowell, A.

    2012-04-01T23:59:59.000Z

    The Value Prior to Pulping (VPP) project goal was to demonstrate the technical and commercial feasibility of introducing a new value stream into existing pulp and paper mills. Essentially the intent was to transfer the energy content of extracted hemicellulose from electricity and steam generated in the recovery boiler to a liquid transportation fuel. The hemicellulose fraction was extracted prior to pulping, fractionated, or conditioned if necessary, and fermented to ethanol. Commercial adaptation of the process to wood hemicelluloses was a prerequisite for using this less currently valued component available from biomass and wood. These hemicelluloses are predominately glucurono-xylan in hardwoods and galactoglucomannan in softwoods (with a significant softwood component of an arabino-xylan) and will yield fermentation substrates different from cellulose. NREL provided its expertise in the area of fermentation host evaluation using its Zymomonas strains on the CleanTech Partner's (CTP) VPP project. The project was focused on the production of fuel ethanol and acetic acid from hemicellulose streams generated from wood chips of industrially important hardwood and softwood species. NREL was one of four partners whose ethanologen was tested on the hydrolyzed extracts. The use of commercially available enzymes to treat oligomeric sugar extracts was also investigated and coupled with fermentation. Fermentations by NREL were conducted with the Zymomonas mobilis organism with most of the work being performed with the 8b strain. The wood extracts hydrolyzed and/or fermented by NREL were those derived from maple, mixed southern hardwoods, and loblolly pine. An unhydrolyzed variant of the mixed southern hardwood extract possessed a large concentration of oligomeric sugars and enzymatic hydrolysis was performed with a number of enzymes, followed by fermentation. The fermentation of the wood extracts was carried out at bench scale in flasks or small bioreactors, with a maximum volume of 500 mL.

  12. An example of alkalization of SiO{sub 2} in a blast furnace coke

    SciTech Connect (OSTI)

    S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

    2007-09-15T23:59:59.000Z

    Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

  13. Burden distribution tests of Siderar`s No. 2 blast furnace

    SciTech Connect (OSTI)

    Lingiardi, O.; Partemio, C.; Burrai, O.; Etchevarne, P.

    1997-12-31T23:59:59.000Z

    Siderar is a company which was created through the merger of Propulsora Siderurgica and the privatized Aceros Parana (the former Somisa, a state-owned steel company). This plant manufacturers flat steel products: hot and cold rolled coils, as well as tin plate coils. After the privatization of the former Somisa in 1992, the new owners decided to modernize the Blast Furnace 2. The relining involved the following: complete furnace with bell less top; cast house with dust collection; INBA granulation system; gas cleaning system; cooling system; modern control system; and revamping of the stock house and the stoves. Burden distribution tests allowed the staff to familiarize themselves with the operation of the top under the three operation modes (manual, semiautomatic and automatic), and also to make adjustments to the top control system. In addition, the tests allowed them to see how materials behave during discharge and building up of ore and coke layers. All this information, together with the available instrumentation, such as fixed probes and heat flux monitoring system, proved to be of use for the gas flow control.

  14. Trials with a 100% pellet burden in blast furnace No. 6 at Hoogovens IJmuiden

    SciTech Connect (OSTI)

    Schoone, E.; Toxopeus, H.; Vos, D. [Hoogovens IJmuiden (Netherlands). Ironmaking and Raw Materials Div.

    1995-12-01T23:59:59.000Z

    The burden consists of 50% high basicity sinter and 50% home made olivine pellets. Two coke oven plants produce the required coke, about 340 kg/t (680 lb/NT). The average pulverized coal injection rate is 150 kg/t (300 lb/NT). To anticipate the aging coke oven plant No. 2 the coal injection capacity will e increased by 50% in 1996, by the installation of a third coal grinding line. In the Netherlands environmental issues have a high impact on further developments. In particular the environmental regulations require a significant decrease of dust, SO{sub 2} and dioxins emitted by the sinter plant. The appropriate measures must be concluded in the second part of this decade. To avoid costly conventional solutions Hoogovens has been testing since April, 1994 the Emission Optimized Sintering (EOS). In case of failure of EOS, the situation of a (partially) closed sinter plant was tested. Purchased pellets replaced sinter, leading to a 100% pellet and an 80% pellet/20% sinter trial. The trials were executed in the first half of 1994 at blast furnace No. 6, equipped with a PW-bell less top. Results are described.

  15. Dofasco`s No. 4 blast furnace hearth breakout, repair and rescue

    SciTech Connect (OSTI)

    Donaldson, R.J.; Fischer, A.J.; Sharp, R.M.; Stothart, D.W. [Dofasco Inc., Hamilton, Ontario (Canada)

    1995-12-01T23:59:59.000Z

    On May 5, 1994, after producing 9.5 million metric tons of iron, Dofasco`s No. 4 Blast Furnace experienced a hearth breakout 250 millimeters below the west taphole. The hot metal spill caused a fire resulting in severe damage and 33 days of lost production. During a 26-day period, electrical wiring, water drainage systems and both tapholes were repaired. Recovery from an unprepared furnace stop of this length, with the deadman depleted is difficult. To aid with the rescue Hoogovens-designed oxygen/fuel lances were commissioned. The furnace recovery began with a lance in each taphole and all tuyeres plugged. Six days after startup the furnace was casting into torpedo cars, and after nine days operation had returned to normal. This incident prompted Dofasco to expand the hearth monitoring system to detect and prevent similar occurrences. During the repair, 203 new thermocouples were installed in the hearth, concentrating on the tapholes and elephant foot areas. These thermocouples were installed at various depths and locations to allow heat flux calculations. This hearth monitoring system has already identified other problem areas and provided valuable information about hearth drainage patterns. This information has allowed them to develop control strategies to manage localized problem areas.

  16. An examination of blast and impulse effects from the metal loading of explosives

    SciTech Connect (OSTI)

    Sanders, Victor E [Los Alamos National Laboratory; Zucker, Jonathan M [Los Alamos National Laboratory; Mc Afee, John M [Los Alamos National Laboratory; Tappan, Bryce C [Los Alamos National Laboratory; Asay, Blaine W [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    Explosive compositions loaded with various metal particulates were produced and tested using a unique experimental configuration. The high explosive HMX was used as the standard and was tested over a range of mass loading fractions using tungsten and tantalum as metal additives. The diagnostics used in this set of experiments included free-field blast sensors, dynamic force sensors, time-of-arrival sensors, and a high-speed digital camera. The experimental arrangement allowed for concurrent spatial measurements of the static pressure from expanding gaseous detonation products, along with the total force from the combination of gaseous products and solid particles. The total pressure from the multi-phase products was calculated by measuring the total force applied to the surface of a newly developed force sensor. The results from the force sensor and other measurement techniques were validated against existing numerical methods. The relationship between static and dynamic pressures as a function of metal loading fraction was examined empirically at several distances from the charge for two distinct metal additives.

  17. Effect of blast furnace slag on self-healing of microcracks in cementitious materials

    SciTech Connect (OSTI)

    Huang, Haoliang, E-mail: haoliang.huang@tudelft.nl [Microlab, Faculty of Civil Engineering and Geosciences, Delft University of Technology (Netherlands); Ye, Guang [Microlab, Faculty of Civil Engineering and Geosciences, Delft University of Technology (Netherlands); Magnel Laboratory for Concrete Research, Department of Structural Engineering, Ghent University (Belgium); Damidot, Denis [Universit Lille Nord de France (France); EM Douai, LGCgE-MPE-GCE, Douai (France)

    2014-06-01T23:59:59.000Z

    The physico-chemical process of self-healing in blast furnace slag cement paste was investigated in this paper. With a high slag content i.e., 66% in cement paste and saturated Ca(OH){sub 2} solution as activator, it was found that the reaction products formed in cracks are composed of C-S-H, ettringite, hydrogarnet and OH杊ydrotalcite. The fraction of C-S-H in the reaction products is much larger than the other minerals. Large amount of ettringite formed in cracks indicates the leaching of SO{sub 4}{sup 2?} ions from the bulk paste and consequently the recrystallization. Self-healing proceeds fast within 50 h and then slows down. According to thermodynamic modeling, when the newly formed reaction products are carbonated, the filling fraction of crack increases first and then decreases. Low soluble minerals such as silica gel, gibbsite and calcite are formed. Compared to Portland cement paste, the potential of self-healing in slag cement paste is higher when the percentage of slag is high. - Highlights: Self-healing reaction products in slag cement paste were characterized. Self-healing reaction products formed in time were quantified with image analysis. Self-healing in slag cement paste was simulated with a reactive transport model. Effect of carbonation on self-healing was investigated by thermodynamic modeling. Effect of slag on self-healing was discussed based on experiments and simulation.

  18. Behavior of Concrete Panels Reinforced with Synthetic Fibers, Mild Steel, and GFRP Composites Subjected to Blasts

    SciTech Connect (OSTI)

    C. P. Pantelides; T. T. Garfield; W. D. Richins; T. K. Larson; J. E. Blakeley

    2012-03-01T23:59:59.000Z

    The paper presents experimental data generated for calibrating finite element models to predict the performance of reinforced concrete panels with a wide range of construction details under blast loading. The specimens were 1.2 m square panels constructed using Normal Weight Concrete (NWC) or Fiber Reinforced Concrete (FRC). FRC consisted of macro-synthetic fibers dispersed in NWC. Five types of panels were tested: NWC panels with steel bars; FRC panels without additional reinforcement; FRC panels with steel bars; NWC panels with glass fiber reinforced polymer (GFRP) bars; and NWC panels reinforced with steel bars and external GFRP laminates on both faces. Each panel type was constructed with three thicknesses: 152 mm, 254 mm, and 356 mm. FRC panels with steel bars had the best performance for new construction. NWC panels reinforced with steel bars and external GFRP laminates on both faces had the best performance for strengthening or rehabilitation of existing structures. The performance of NWC panels with GFRP bars was strongly influenced by the bar spacing. The behavior of the panels is classified in terms of damage using immediate occupancy, life safety, and near collapse performance levels. Preliminary dynamic simulations are compared to the experimental results.

  19. The Blast Wave Model for AGN Feedback: Effects on AGN Obscuration

    E-Print Network [OSTI]

    N. Menci; F. Fiore; S. Puccetti; A. Cavaliere

    2008-07-01T23:59:59.000Z

    We compute the effect of the galactic absorption on AGN emission in a cosmological context by including a physical model for AGN feeding and feedback in a semi-analytic model of galaxy formation. This is based on galaxy interactions as triggers for AGN accretion, and on expanding blast waves as a mechanism to propagate outwards the AGN energy injected into the interstellar medium at the center of galaxies. We first test our model against the observed number density of AGNs with different intrinsic luminosity as a function of redshift. The model yields a ''downsizing'' behavior in close agreement with the observed one for z2 and L_X 10^{22} cm^{-2} decreases with luminosity for z<1; in addition, the total (integrated over luminosity) absorbed fraction increases with redshift up to z around 2, and saturates to the value around 0.8 at higher redshifts. Finally, we predict the luminosity dependence of the absorbed fraction of AGNs with L_X< 3 10^{44} erg/s to weaken with increasing redshift. We compare our results with recent observations, and discuss their implications in the context of cosmological models of galaxy formation.

  20. Total organic carbon as an indicator of wood delignification

    SciTech Connect (OSTI)

    Genco, J.M.; Hassler, J.C.; Busayasakul, N.

    1984-07-01T23:59:59.000Z

    Kraft pulping experiments were performed in a 12-liter electrically heated laboratory digester to determine pulp yields and residual lignin content (kappa number) as a function of time. Samples of the pulp and the black liquor were analyzed for total organic carbon (TOC) content by oxidizing the samples in a combustion furnace and measuring the released CO/sub 2/ gravimetrically. The experimental data on TOC were correlated with kappa number and yield. Results can be explained satisfactorily using a mathematical model based upon the principle of conservation of mass. The TOC content of black liquor appears to be a useful parameter for batch digester control. 17 references.