National Library of Energy BETA

Sample records for blast pulping liquor

  1. Novel Pulping Technology: Directed Green Liquor Utilization (D-GLU) Pulping

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15

    The general objectives of this new project are the same as those described in the original proposal. Conventional kraft pulping technologies will be modified for significant improvements in pulp production, such as strength, bleachability, and yield by using green liquor, a naturally high, kraft mill-derived sulfidity source. Although split white liquor sulfidity and other high sulfidity procedures have the promise of addressing several of the latter important economic needs of pulp mills, they require considerable engineering/capital retrofits, redesigned production methods, and thus add to overall mill expenditures. Green liquor use, however, possesses the required high sulfidity to obtain in general the benefits attributable to higher sulfidity cooking, without the required capital constraints for implementation. Before introduction of green liquor in our industrial operations, a stronger understanding of its fundamental chemical interaction with the lignin and carbohydrates in US hardwood and softwoods must be obtained. In addition, its effect on bleachability, enhancement of pulp properties, and influence on the overall energy and recovery of the mill requires further exploration before the process witnesses widespread mill use in North America. Thus, proof of principle will be accomplished in this work and the consequent effect of green liquor and other high sulfide sources on the pulping and bleaching operations will be explored for US kraft mills. The first year of this project will generate the pertinent information to validate its ability for implementation in US pulping operations, whereas year two will continue this work while proceeding to analyze pulp bleachability and final pulp/paper properties and develop a general economic and feasibility analysis for its eventual implementation in North America.

  2. Method for improving separation of carbohydrates from wood pulping and wood or biomass hydrolysis liquors

    DOE Patents [OSTI]

    Griffith, William Louis; Compere, Alicia Lucille; Leitten, Jr., Carl Frederick

    2010-04-20

    A method for separating carbohydrates from pulping liquors includes the steps of providing a wood pulping or wood or biomass hydrolysis pulping liquor having lignin therein, and mixing the liquor with an acid or a gas which forms an acid upon contact with water to initiate precipitation of carbohydrate to begin formation of a precipitate. During precipitation, at least one long chain carboxylated carbohydrate and at least one cationic polymer, such as a polyamine or polyimine are added, wherein the precipitate aggregates into larger precipitate structures. Carbohydrate gel precipitates are then selectively removed from the larger precipitate structures. The method process yields both a carbohydrate precipitate and a high purity lignin.

  3. Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery

    SciTech Connect (OSTI)

    Adriaan van Heiningen

    2007-06-30

    MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of

  4. HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING

    SciTech Connect (OSTI)

    Lucia, Lucian A

    2013-04-19

    Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

  5. Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill

    SciTech Connect (OSTI)

    Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

    2010-01-27

    As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industry’s energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also

  6. Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping

    Broader source: Energy.gov [DOE]

    This factsheet describes a project that seeks to develop feasible chemical modifications during kraft pulping operations to obtain significant energy and product benefits for U.S. kraft pulp and paper mills.

  7. Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping

    SciTech Connect (OSTI)

    2007-07-01

    This factsheet describes a project that seeks to develop feasible chemical modifications during kraft pulping operations to obtain significant energy and product benefits for U.S. kraft pulp and paper mills.

  8. High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase 1 -- Final report. Volume 2: Project technical results

    SciTech Connect (OSTI)

    Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

    1995-11-01

    This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The principal means to this end is to construct and operate a pilot-scale recovery furnace simulator (RFS) in which these technologies can be tested. The Phase 1 objectives are to prepare a preliminary design for the RFS, delineate a project concept for evaluating candidate technologies, establish industrial partners, and report the results. Phase 1 addressed the objectives with seven tasks: Develop a preliminary design of the RFS; estimate the detailed design and construction costs of the RFS and the balance of the project; identify interested parties in the paper industry and key suppliers; plan the Phase 2 and Phase 3 tests to characterize the RFS; evaluate the economic justification for high-solids firing deployment in the industry; evaluate high-solids black liquor property data to support the RFS design; manage the project and reporting results, which included planning the future program direction.

  9. Big Island Demonstration Project - Black Liquor

    SciTech Connect (OSTI)

    2006-08-01

    Black liquor is a papermaking byproduct that also serves as a fuel for pulp and paper mills. This project involves the design, construction, and operation of a black liquor gasifier that will be integrated into Georgia-Pacific's Big Island facility in Virginia, a mill that has been in operation for more than 100 years.

  10. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    SciTech Connect (OSTI)

    Fricke, A.L.; Zaman, A.A.

    1998-05-01

    The overall objective of the program was to develop correlations to predict physical properties within requirements of engineering precision from a knowledge of pulping conditions and of kraft black liquor composition, if possible. These correlations were to include those relating thermodynamic properties to pulping conditions and liquor composition. The basic premise upon which the research was based is the premise that black liquor behaves as a polymer solution. This premise has proven to be true, and has been used successfully in developing data reduction methods and in interpreting results. A three phase effort involving pulping, analysis of liquor composition, and measurement of liquor properties was conducted.

  11. Proceedings of the black liquor research program review fourth meeting held July 28--30, 1987

    SciTech Connect (OSTI)

    Emerson, D. B.; Whitworth, B. A.

    1987-10-01

    Research programs, presented at the black liquor review meeting are described. Research topics include the following: Cooperative Program in Kraft Recovery; Black Liquor Physical Properties; Viscosity of Strong Black Liquor; Ultrafiltration of Kraft Black Liquor; Molecular Weight Distribution of Kraft Lignin; Black Liquor Droplet Formation Project; Fundamental Studies of Black Liquor Combustion; Black Liquor Combustion Sensors; Flash X-ray Imagining of Black Liquor Sprays; Laser Induced Fluorescence For Process Control In The Pulp and Paper Industry; Recovery Boiler Optimization; Black Liquor Gasification and Use of the Products in Combined-Cycle Cogeneration; Black Liquor Steam Plasma Automization; The B and W Pyrosonic 2000R System; Monsteras Boiler Control System; and Cooperative Program Project Reviews. Individual projects are processed separately for the data bases.

  12. Physical properties of kraft black liquor. Final report. Phase I

    SciTech Connect (OSTI)

    Fricke, A.L.

    1983-12-01

    Methods were selected, equipment installed, and procedures developed for determining rheological properties; for determining thermal properties (stability, density, thermal expansion, and heat capacity); for purification and characterization of lignin (glass transition, stability, weight average molecular weight, and number average molecular weight); and for performing chemical analyses (negative inorganic ions, positive inorganic ions, acid organic salts, lignin, and total solids). A strategy for pulping to supply test liquors was developed, and a statistically designed pulping experiment was specified for a Southern softwood species. Arrangements were made for performing initial pulping work in an industrial pilot plant, and a preliminary set of pulping experiments were conducted. Liquors from the preliminary pulping experiments were used to test procedures and to determine reproducibility of the experiment. Literature was also surveyed and preliminary selection of designs for a pilot digester, and for equipment to determine surface tension were made.

  13. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Jun Wei

    2005-03-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  14. Causticizing for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

    2009-01-07

    The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

  15. Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream

    DOE Patents [OSTI]

    Li, Jian; Chai, Xin Sheng; Zhu, Junyoung

    2008-06-24

    The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

  16. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Laing

    2005-10-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  17. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-04-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  18. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

    2004-10-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  19. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-10-01

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected/developed that either react with the gasifier environment to form protective surfaces in-situ; and

  20. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-07-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  1. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-01-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  2. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie

    2003-12-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  3. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr.; Alireza Rezaie

    2003-12-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  4. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie; Xiaoting Liang; Musa Karakus; Jun Wei

    2005-12-01

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected or developed that reacted with the gasifier environment to form protective surfaces in-situ; and

  5. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie

    2003-08-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  6. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Robert E. Moore; William L. Headrick; Alireza Rezaie

    2003-03-31

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  7. Technical Report Cellulosic Based Black Liquor Gasification and Fuels Plant Final Technical Report

    SciTech Connect (OSTI)

    Fornetti, Micheal; Freeman, Douglas

    2012-10-31

    The Cellulosic Based Black Liquor Gasification and Fuels Plant Project was developed to construct a black liquor to Methanol biorefinery in Escanaba, Michigan. The biorefinery was to be co-located at the existing pulp and paper mill, NewPage’s Escanaba Paper Mill and when in full operation would: • Generate renewable energy for Escanaba Paper Mill • Produce Methanol for transportation fuel of further refinement to Dimethyl Ether • Convert black liquor to white liquor for pulping. Black liquor is a byproduct of the pulping process and as such is generated from abundant and renewable lignocellulosic biomass. The biorefinery would serve to validate the thermochemical pathway and economic models for black liquor gasification. It was a project goal to create a compelling new business model for the pulp and paper industry, and support the nation’s goal for increasing renewable fuels production and reducing its dependence on foreign oil. NewPage Corporation planned to replicate this facility at other NewPage Corporation mills after this first demonstration scale plant was operational and had proven technical and economic feasibility. An overview of the process begins with black liquor being generated in a traditional Kraft pulping process. The black liquor would then be gasified to produce synthesis gas, sodium carbonate and hydrogen sulfide. The synthesis gas is then cleaned with hydrogen sulfide and carbon dioxide removed, and fed into a Methanol reactor where the liquid product is made. The hydrogen sulfide is converted into polysulfide for use in the Kraft pulping process. Polysulfide is a known additive to the Kraft process that increases pulp yield. The sodium carbonate salts are converted to caustic soda in a traditional recausticizing process. The caustic soda is then part of the white liquor that is used in the Kraft pulping process. Cellulosic Based Black Liquor Gasification and Fuels Plant project set out to prove that black liquor gasification could

  8. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, Arthur L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

  9. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, A.L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

  10. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and

  11. Table 3.5 Selected Byproducts in Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Blast Pulping Liquor NAICS FurnaceCoke Petroleum or Wood ... Black Liquor Bark Total United States 311 Food 11 0 7 0 0 1 ... 0 0 324110 Petroleum Refineries 1,901 0 1,347 553 0 0 ...

  12. Recovery of sugars from ionic liquid biomass liquor by solvent...

    Office of Scientific and Technical Information (OSTI)

    Recovery of sugars from ionic liquid biomass liquor by solvent extraction Citation Details In-Document Search Title: Recovery of sugars from ionic liquid biomass liquor by solvent ...

  13. Definition:Black Liquor | Open Energy Information

    Open Energy Info (EERE)

    into paper pulp removing lignin, hemicelluloses and other extractives from the wood to free the cellulose fibers. View in Wikipedia Retrieved from "http:en.openei.orgw...

  14. December News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    December News Blast December News Blast December News Blast december_2013_newsblast.pdf (337.86 KB) More Documents & Publications November 2013 News Blast January 2014 News Blast April 2014 Monthly News Blast

  15. February 2014 News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 News Blast February 2014 News Blast February 2014 News Blast february_2014_newsblast.pdf (251.82 KB) More Documents & Publications March 2014 Monthly News Blast April 2014 Monthly News Blast January 2014 News Blast

  16. Controlling emissions from a black liquor fluidized bed evaporator (Copeland reactor) using a regenerative thermal oxidizer and a prefilter

    SciTech Connect (OSTI)

    Grzanka, R.

    1997-12-31

    This paper reports on an intriguing pilot project developed to control air emissions from a pulp mill. Testing is complete, and the results show favorable emissions reductions. Stone Container Corporation, REECO, NCASI, the Ohio DEP, and the US EPA, have all worked together and approved the installation of control equipment, for VOC and HAP emissions under Presumptive MACT, setting the standard for the Copeland Reactor process in a semi chem pulp mill. The equipment, once operational, will reduce VOC and CO emissions by greater than 90%. This installation will be done at one seventh the cost of the significant process modifications required to accomplish the same emission reduction. In addition, increased process operating efficiency will be achieved with the use of an energy recovery system. The process is a black liquor fluidized bed boiler, which is used to generate sodium carbonate from the black liquor. The vapor emissions were high in VOCs, CO and particulate. After much study and testing, a wet electrostatic precipitator was chosen as the filter system for particulate control, followed by a regenerative thermal oxidizer for VOC and HAP control, finally an air-to-air heat exchanger is being used to preheat the combustion air entering the process.

  17. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 4 (Appendix IV)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 4 contains the following appendix sections: Radiative heat transfer properties for black liquor combustion -- Facilities and techniques and Spectral absorbance and emittance data; and Radiate heat transfer determination of the optical constants of ash samples from kraft recovery boilers -- Calculation procedure; Computation program; Density determination; Particle diameter determination; Optical constant data; and Uncertainty analysis.

  18. Pulping wastewater treatment: Aeration processes and equipment. (Latest citations from the Paper and Board, Printing, and Packaging Industries Research Associations database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    The bibliography contains citations concerning plant operations and methods, pilot plant and laboratory tests and results of pulping mill wastewater treatment by aeration. Composition of effluent components including condensates, bleaching effluents, and spent liquor are discussed. Foreign and domestic plant efficiency, performance reports, and cost data are considered. Aerator design, lagoon treatment system upgrading considerations, and environmental aspects are included. (Contains a minimum of 88 citations and includes a subject term index and title list.)

  19. November 2013 News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 News Blast November 2013 News Blast November 2013 News Blast november_2013_newsblast.pdf (397.02 KB) More Documents & Publications BETO Monthly News Blast, August 2013r January 2014 News Blast March 2014 Monthly

  20. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below

  1. Monthly News Blast

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    YouTube Facebook Twitter Blog Past Newsletters Bioenergy Social Media & Multimedia Corner Monthly News Blast July 2013 Secretaries Moniz and Vilsack Speaking at Biomass ...

  2. Drum drying of black liquor using superheated steam impinging jets

    SciTech Connect (OSTI)

    Shiravi, A.H.; Mujumdar, A.S.; Kubes, G.J. [McGill Univ., Montreal, Quebec (Canada)

    1997-05-01

    A novel drum dryer for black liquor utilizing multiple impinging jets of superheated steam was designed and built to evaluate the performance characteristics and effects of various operating parameters thereon. Appropriate ranges of parameters such as steam jet temperature and velocity were examined experimentally to quantify the optimal operating conditions for the formation of black liquor film on the drum surface as well as the drying kinetics.

  3. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 2 (Appendices I, section 5 and II, section 1)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 2 contains the last section of Appendix I, Radiative heat transfer in kraft recovery boilers, and the first section of Appendix II, The effect of temperature and residence time on the distribution of carbon, sulfur, and nitrogen between gaseous and condensed phase products from low temperature pyrolysis of kraft black liquor.

  4. Lightweight blast shield

    DOE Patents [OSTI]

    Mixon, Larry C. (Madison, AL); Snyder, George W. (Huntsville, AL); Hill, Scott D. (Toney, AL); Johnson, Gregory L. (Decatur, AL); Wlodarski, J. Frank (Huntsville, AL); von Spakovsky, Alexis P. (Huntsville, AL); Emerson, John D. (Arab, AL); Cole, James M. (Huntsville, AL); Tipton, John P. (Huntsville, AL)

    1991-01-01

    A tandem warhead missile arrangement that has a composite material housing structure with a first warhead mounted at one end and a second warhead mounted near another end of the composite structure with a dome shaped composite material blast shield mounted between the warheads to protect the second warhead from the blast of the first warhead.

  5. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 1 (Main text and Appendix I, sections 1--4)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 1 contains the main body of the report and the first 4 sections of Appendix 1: Modeling of black liquor recovery boilers -- summary report; Flow and heat transfer modeling in the upper furnace of a kraft recovery boiler; Numerical simulation of black liquor combustion; and Investigation of turbulence models and prediction of swirling flows for kraft recovery furnaces.

  6. Passive blast pressure sensor

    DOE Patents [OSTI]

    King, Michael J.; Sanchez, Roberto J.; Moss, William C.

    2013-03-19

    A passive blast pressure sensor for detecting blast overpressures of at least a predetermined minimum threshold pressure. The blast pressure sensor includes a piston-cylinder arrangement with one end of the piston having a detection surface exposed to a blast event monitored medium through one end of the cylinder and the other end of the piston having a striker surface positioned to impact a contact stress sensitive film that is positioned against a strike surface of a rigid body, such as a backing plate. The contact stress sensitive film is of a type which changes color in response to at least a predetermined minimum contact stress which is defined as a product of the predetermined minimum threshold pressure and an amplification factor of the piston. In this manner, a color change in the film arising from impact of the piston accelerated by a blast event provides visual indication that a blast overpressure encountered from the blast event was not less than the predetermined minimum threshold pressure.

  7. October 2013 News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    October 2013 News Blast October 2013 News Blast October 2013 News Blast october_2013_newsblast.pdf (326.2 KB) More Documents & Publications September 2013 News Blast BETO Monthly News Blast, August 2013r BETO Monthly News Blast, June 2013

  8. ESF BLAST DESIGN ANALYSIS

    SciTech Connect (OSTI)

    E.F. fitch

    1995-03-13

    The purpose and objective of this design analysis are to develop controls considered necessary and sufficient to implement the requirements for the controlled drilling and blasting excavation of operations support alcoves and test support alcoves in the Exploratory Studies Facility (ESF). The conclusions reached in this analysis will flow down into a construction specification ensuring controlled drilling and blasting excavation will be performed within the bounds established here.

  9. Black liquor gasification phase 2D final report

    SciTech Connect (OSTI)

    Kohl, A.L.; Stewart, A.E.

    1988-06-01

    This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

  10. April 2013 Monthly News Blast

    Broader source: Energy.gov [DOE]

    The monthly news blast for April 2013 highlights the Project Peer Review, upcoming events, BETO blog posts, and more.

  11. ITP Forest Products: Report for AIChE Pulp and Paper Industry...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Steam stripping of foul condensates is common to remove methanol for the pulp mill ... 16CX8700 76 Pulp distribution, without Imports -- Pulp Manufactured AF&PA 2002 ...

  12. Pulp and paper program fact sheets

    SciTech Connect (OSTI)

    1995-07-01

    Summaries are presented of Argonne technology transfer research projects in: sustainable forest management, environmental performance, energy performance, improved capital effectiveness, recycling, and sensors and controls. Applications in paper/pulp industry, other industries, etc. are covered.

  13. Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005

    SciTech Connect (OSTI)

    John E. Pinkerton

    2007-08-15

    Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

  14. April 2013 Monthly News Blast

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    KDF Social Media YouTube Facebook Twitter Blog Past Newsletters Bioenergy Social Media & Multimedia Corner Monthly News Blast April 2013 Register Now for the 2013 ...

  15. Monthly News Blast: February 2013

    Broader source: Energy.gov [DOE]

    In the February 2013 Monthly News Blast, read about recent blog posts, the monthly staff spotlight video, upcoming events, and more.

  16. Monthly News Blast: January 2013

    Office of Energy Efficiency and Renewable Energy (EERE)

    In the January 2013 Monthly News Blast, read about two new funding opportunities, the latest MYPP update, upcoming events, and more.

  17. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 3 (Appendices II, sections 2--3 and III)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 3 contains the following appendix sections: Formation and destruction of nitrogen oxides in recovery boilers; Sintering and densification of recovery boiler deposits laboratory data and a rate model; and Experimental data on rates of particulate formation during char bed burning.

  18. Pulp and Paper Mills: Profiting from Efficient Motor System Use |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Pulp and Paper Mills: Profiting from Efficient Motor System Use Pulp and Paper Mills: Profiting from Efficient Motor System Use This 2-page fact sheet describes The Paper and Allied Products Industry spending to operate electric motor systems and opportunities to reduce these costs. Pulp and Paper Mills: Profiting from Efficient Motor System Use (January 1999) (70.34 KB) More Documents & Publications Bandwidth Study U.S. Pulp and Paper Manufacturing United States

  19. Pollution prevention for the kraft pulp and paper industry

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    The document is an annotated bibliography of publications related to pollution prevention in the Kraft segment of the pulp and paper industry. It is organized by process area as follows: chip preparation, chemical pulping, pulp washing, bleaching, chemical recovery, recausticizing, power generation, wastewater treatment, papermaking, and general plant. The document contains 269 citations.

  20. BETO Monthly News Blast, August 2013r | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    BETO Monthly News Blast from August 2013 august2013newsblast.pdf More Documents & Publications Monthly News Blast: March 2013 BETO Monthly News Blast, June 2013 Monthly News...

  1. April 2012 Biomass Program News Blast

    Broader source: Energy.gov [DOE]

    April 2012 monthly news blast from the Biomass Program, highlighting news items, funding opportunities, and events.

  2. HIGH PRODUCTIVITY VACUUM BLASTING SYSTEM

    SciTech Connect (OSTI)

    Dr. M.A. Ebadian

    2000-01-13

    The purpose of the project is to increase the productivity and economics of existing vacuum blasting technology. This technology is used to remove radioactive contamination, PCB's and lead-base paint and provides worker and environmental protection by continuously recycling the blast media and the full containment of the dust generated in the process.

  3. Method for rapidly determining a pulp kappa number using spectrophotometry

    DOE Patents [OSTI]

    Chai, Xin-Sheng; Zhu, Jun Yong

    2002-01-01

    A system and method for rapidly determining the pulp kappa number through direct measurement of the potassium permanganate concentration in a pulp-permanganate solution using spectrophotometry. Specifically, the present invention uses strong acidification to carry out the pulp-permanganate oxidation reaction in the pulp-permanganate solution to prevent the precipitation of manganese dioxide (MnO.sub.2). Consequently, spectral interference from the precipitated MnO.sub.2 is eliminated and the oxidation reaction becomes dominant. The spectral intensity of the oxidation reaction is then analyzed to determine the pulp kappa number.

  4. Monthly News Blast: July 2013 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    July 2013 Monthly News Blast: July 2013 July 2013 Monthly News Blast july_2013_newsblast.pdf (139.76 KB) More Documents & Publications Monthly News Blast: March 2013 BETO Monthly News Blast, June

  5. Centrifugal shot blast system

    SciTech Connect (OSTI)

    1998-02-01

    This report describes a demonstration of Concrete cleaning, Inc., modified centrifugal shot blast technology to remove the paint coating from concrete flooring. This demonstration is part of the Chicago Pile-5 (CP-5) Large-Scale Demonstration Project (LSDP) sponsored by the US Department of Energy (DOE), office of Science and Technology (OST), Deactivation and Decommissioning Focus Area (DDFA). The objective of the LSDP is to select and demonstrate potentially beneficial technologies at the Argonne National Laboratory-East (ANL) CP-5 Research Reactor. The purpose of the LSDP is to demonstrate that using innovative and improved decontamination and decommissioning (D and D) technologies from various sources can result in significant benefits, such as decreased cost and increased health and safety, as compared with baseline D and D technologies. Potential markets exist for the innovative centrifugal shot blast system at the following sites: Fernald Environmental Management Project, Los Alamos, Nevada, Oak Ridge Y-12 and K-25, Paducah, Portsmouth Gaseous Diffusion site, and the Savannah River Site. This information is based on a revision to the OST Linkage Tables dated August 4, 1997.

  6. BETO Monthly News Blast, June 2013 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BETO Monthly News Blast, June 2013 BETO Monthly News Blast, June 2013 The June 2013 monthly news blast covers Biomass 2013, the Program Management Review, upcoming industry events, and more. june_2013_newsblast.pdf (144.2 KB) More Documents & Publications Monthly News Blast: March 2013 BETO Monthly News Blast, August 2013r Monthly News Blast: July 2013

  7. Biomass Program December Monthly News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    December Monthly News Blast Biomass Program December Monthly News Blast The December News Blast from the Biomass Program's monthly newsletter contains important past and upcoming Program information. december_news_blast.pdf (151.26 KB) More Documents & Publications Biomass Program Monthly News Blast: November November 2012 Newsblast Biomass Program Monthly News Blast January

  8. Biomass Program Monthly News Blast - May 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blast - May 2012 Biomass Program Monthly News Blast - May 2012 Biomass Program monthly news blast from May 2012 may2012_newsblast.pdf (166.44 KB) More Documents & Publications June 2012 News Blast: Algae on the Mind April 2012 Biomass Program News Blast February 2012 Biomass Program News Blast

  9. Biomass Program Monthly News Blast January 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blast January 2012 Biomass Program Monthly News Blast January 2012 This is a copy of the Biomass Program's monthly news blast from January 2012. january2012_newsblast.pdf (119.07 KB) More Documents & Publications Biomass Program December Monthly News Blast February 2012 Biomass Program News Blast Biomass Program Monthly News Blast - March 2012

  10. Biomass Program Monthly News Blast: August | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Program Monthly News Blast: August Biomass Program Monthly News Blast: August News and updates from the Biomass Program in August 2011. august_news_blast.pdf (198.18 KB) More Documents & Publications Biomass Program Monthly News Blast: June Biomass Program News Blast: September Biomass Program Monthly News Blast: July

  11. Biomass Program Monthly News Blast: May | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blast: May Biomass Program Monthly News Blast: May News and updates from the Biomass Program in May 2011. may_news_blast.pdf (142.09 KB) More Documents & Publications Biomass Program Monthly News Blast: June Biomass Program News Blast: September Biomass Program Monthly News Blast: August

  12. Biomass Program News Blast: September | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    News Blast: September Biomass Program News Blast: September News and updates from the Biomass Program in September 2011. september_news_blast.pdf (178 KB) More Documents & Publications Biomass Program Monthly News Blast: August Biomass Program Monthly News Blast: June Biomass Program Monthly News Blast: July

  13. February 2012 Biomass Program News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Biomass Program News Blast February 2012 Biomass Program News Blast News Blast from the February 2012 Biomass Program. february2012_newsblast.pdf (121.83 KB) More Documents & Publications Biomass Program Monthly News Blast - March 2012 April 2012 Biomass Program News Blast Biomass Program Monthly News Blast January 2012

  14. Portable convertible blast effects shield

    DOE Patents [OSTI]

    Pastrnak, John W.; Hollaway, Rocky; Henning, Carl D.; Deteresa, Steve; Grundler, Walter; Hagler,; Lisle B.; Kokko, Edwin; Switzer, Vernon A

    2010-10-26

    A rapidly deployable portable convertible blast effects shield/ballistic shield includes a set two or more telescoping cylindrical rings operably connected to each other to convert between a telescopically-collapsed configuration for storage and transport, and a telescopically-extended upright configuration forming an expanded inner volume. In a first embodiment, the upright configuration provides blast effects shielding, such as against blast pressures, shrapnel, and/or fire balls. And in a second embodiment, the upright configuration provides ballistic shielding, such as against incoming weapons fire, shrapnel, etc. Each ring has a high-strength material construction, such as a composite fiber and matrix material, capable of substantially inhibiting blast effects and impinging projectiles from passing through the shield. And the set of rings are releasably securable to each other in the telescopically-extended upright configuration, such as by click locks.

  15. Portable convertible blast effects shield

    DOE Patents [OSTI]

    Pastrnak, John W.; Hollaway, Rocky; Henning, Carl D.; Deteresa, Steve; Grundler, Walter; Hagler, Lisle B.; Kokko, Edwin; Switzer, Vernon A.

    2011-03-15

    A rapidly deployable portable convertible blast effects shield/ballistic shield includes a set two or more frusto-conically-tapered telescoping rings operably connected to each other to convert between a telescopically-collapsed configuration for storage and transport, and a telescopically-extended upright configuration forming an expanded inner volume. In a first embodiment, the upright configuration provides blast effects shielding, such as against blast pressures, shrapnel, and/or fire balls. And in a second embodiment, the upright configuration provides ballistic shielding, such as against incoming weapons fire, shrapnel, etc. Each ring has a high-strength material construction, such as a composite fiber and matrix material, capable of substantially inhibiting blast effects and impinging projectiles from passing through the shield. And the set of rings are releasably securable to each other in the telescopically-extended upright configuration by the friction fit of adjacent pairs of frusto-conically-tapered rings to each other.

  16. Portable convertible blast effects shield

    DOE Patents [OSTI]

    Pastrnak, John W.; Hollaway, Rocky; Henning, Carl D.; Deteresa, Steve; Grundler, Walter; Hagler, Lisle B.; Kokko, Edwin; Switzer, Vernon A

    2007-05-22

    A rapidly deployable portable convertible blast effects shield/ballistic shield includes a set two or more telescoping cylindrical rings operably connected to each other to convert between a telescopically-collapsed configuration for storage and transport, and a telescopically-extended upright configuration forming an expanded inner volume. In a first embodiment, the upright configuration provides blast effects shielding, such as against blast pressures, shrapnel, and/or fire balls. And in a second embodiment, the upright configuration provides ballistic shielding, such as against incoming weapons fire, shrapnel, etc. Each ring has a high-strength material construction, such as a composite fiber and matrix material, capable of substantially inhibiting blast effects and impinging projectiles from passing through the shield. And the set of rings are releasably securable to each other in the telescopically-extended upright configuration, such as by click locks.

  17. May 2013 Monthly News Blast

    Broader source: Energy.gov [DOE]

    The Bioenergy Technologies Office's May 2013 Monthly News Blast highlights the upcoming Biomass 2013 conference, a webinar on ionic liquids, the new Multi-Year Program Plan, and more.

  18. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  19. Use of sulfide-containing liquors for removing mercury from flue gases

    SciTech Connect (OSTI)

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2003-01-01

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  20. Use of sulfide-containing liquors for removing mercury from flue gases

    SciTech Connect (OSTI)

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  1. Steam System Opportunity Assessment for the Pulp and Paper, Chemical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing, and Petroleum Refining Industries | Department of Energy Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries Steam System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries This report assesses steam generation and use in the pulp and paper, chemical manufacturing, and the petroleum refining industries. The report also estimates the energy savings potential available from

  2. Steam System Opportunity Assessment for the Pulp and Paper, Chemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing, and Petroleum Refining Industries Steam System Opportunity Assessment for the Pulp and Paper, Chemical Manufacturing, and Petroleum Refining Industries This ...

  3. Alabama Pine Pulp Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    2006 Database Retrieved from "http:en.openei.orgwindex.php?titleAlabamaPinePulpBiomassFacility&oldid397129" Feedback Contact needs updating Image needs updating...

  4. Bandwidth Study U.S. Pulp and Paper Manufacturing | Department...

    Broader source: Energy.gov (indexed) [DOE]

    This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. pulp and paper manufacturing. The study relies on multiple sources to estimate ...

  5. Final Technical Report Steam Cycle Washer for Unbleached Pulp

    SciTech Connect (OSTI)

    Starkey, Yvonne; Salminen, Reijo; Karlsnes, Andy

    2008-09-22

    Project Abstract for “Steam Cycle Washer for Unbleached Pulp” When completed, the patented SC Washer will provide an innovative, energy efficient demonstration project to wash unbleached pulp using a pressure vessel charged with steam. The Port Townsend Paper Corporation’s pulp mill in Port Townsend, WA was initially selected as the host site for conducting the demonstration of the SCW. Due to 2006 and 2007 delays in the project caused by issues with 21st Century Pulp & Paper, the developer of the SCW, and the 2007 bankruptcy proceedings and subsequent restructuring at Port Townsend Paper, the mill can no longer serve as a host site. An alternate host site is now being sought to complete the commercial demonstration of the Steam Cycle Washer for Unbleached Pulp. Additionally, estimated costs to complete the project have more than doubled since the initial estimates for the project were completed in 2002. Additional grant funding from DOE was sought and in July, 2008 the additional DOE funds were procured under a new DOE award, DE-PS36-08GO98014 issued to INL. Once the new host site is secured the completion of the project will begin under the management of INL. Future progress reports and milestone tracking will be completed under requirements of new DOE Award Number DE-PS36-08GO98014. The following are excerpts from the project Peer Review completed in 2006. They describe the project in some detail. Additional information can be found by reviewing DOE Award Number: DE-PS36-08GO98014. 5. Statement of Problem and Technical Barriers: The chemical pulping industry is one of the major users of fresh water in the United States. On average the industry uses over 80 tons of water to produce one ton of pulp, some states use up to 50% more (Washington 120 and Wisconsin 140). In order to process one ton of pulp using 80 tons of process water, a large amount of: • energy is used in process heat and • power is required for pumping the large volume of pulp slurries

  6. Blast Effects Suppression System - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to protect critical facilities from the devastating effects of blast from a vehicle bomb. HydroSuppressor uses high volume water sprays to absorb the energy of the blast as...

  7. Monthly News Blast: March 2013 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 2013 Monthly News Blast: March 2013 In the March 2013 Monthly News Blast, read about two upcoming webinars, two recently announced BETO events, recent blog posts, the monthly staff spotlight video, upcoming events, and more. march_2013_newsblast.pdf (130.06 KB) More Documents & Publications April 2013 Monthly News Blast May 2013 Monthly News Blast Monthly News Blast: February 2013

  8. Biomass Program Monthly News Blast - March 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blast - March 2012 Biomass Program Monthly News Blast - March 2012 Monthly updates from the Biomass Program in March 2012. march2012_newsblast.pdf (130.51 KB) More Documents & Publications Biomass Program Monthly News Blast - May 2012 April 2012 Biomass Program News Blast February 2012 Biomass Program News Blast

  9. Biomass Program Monthly News Blast: July | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    July Biomass Program Monthly News Blast: July News and updates from the Biomass Program in July 2011. july_news_blast.pdf (129.98 KB) More Documents & Publications Biomass Program Monthly News Blast: May Biomass Program Monthly News Blast: June Biomass Program Monthly News Blast: August

  10. Biomass Program Monthly News Blast: June | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    June Biomass Program Monthly News Blast: June News and updates from the Biomass Program in June 2011. june_news_blast.pdf (120.35 KB) More Documents & Publications Biomass Program Monthly News Blast: July Biomass Program Monthly News Blast: May Biomass Program Monthly News Blast: October

  11. Biomass Program Monthly News Blast: November | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    November Biomass Program Monthly News Blast: November News and Updates from the Biomass Program in November 2011. november_news_blast.pdf (110.18 KB) More Documents & Publications Biomass Program December Monthly News Blast Biomass Program Monthly News Blast: October Biomass Program Monthly News Blast January 2012

  12. Biomass Program Monthly News Blast: October | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    October Biomass Program Monthly News Blast: October News and updates from the Biomass Program in October 2011. october_news_blast.pdf (187.03 KB) More Documents & Publications Biomass Program Monthly News Blast: August Biomass Program Monthly News Blast: November Biomass Program News Blast: September

  13. Biomass Program September 2012 News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 2012 News Blast Biomass Program September 2012 News Blast September 2012 Biomass Program monthly news blast. september2012_newsblast.pdf (161.6 KB) More Documents & Publications August 2012 Biomass Program Monthly News Blast Biomass Program Monthly News Blast, October 2012 November 2012 Newsblast

  14. June 2014 Monthly News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Monthly News Blast June 2014 Monthly News Blast June 2014 Monthly News Blast from the Bioenergy Technologies Office. june_2014_newsblast.pdf (166.48 KB) More Documents & Publications July 2014 Monthly News Blast April 2014 Monthly News Blast March 2014

  15. April 2014 Monthly News Blast | Department of Energy

    Energy Savers [EERE]

    April 2014 Monthly News Blast April 2014 Monthly News Blast April 2014 Monthly News Blast from the Bioenergy Technologies Office. april2014newsblast.pdf (373.07 KB) More ...

  16. August 2014 Monthly News Blast | Department of Energy

    Energy Savers [EERE]

    August 2014 Monthly News Blast August 2014 Monthly News Blast August 2014 Monthly News Blast from the Bioenergy Technologies Office. august2014newsblast.pdf (221.76 KB) More ...

  17. Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment

    SciTech Connect (OSTI)

    Kevin Whitty

    2008-06-30

    The University of Utah's project 'Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment' (U.S. DOE Cooperative Agreement DE-FC26-04NT42261) was a response to U.S. DOE/NETL solicitation DE-PS36-04GO94002, 'Biomass Research and Development Initiative' Topical Area 4-Kraft Black Liquor Gasification. The project began September 30, 2004. The objective of the project was to improve the understanding of black liquor conversion in high pressure, high temperature reactors that gasify liquor through partial oxidation with either air or oxygen. The physical and chemical characteristics of both the gas and condensed phase were to be studied over the entire range of liquor conversion, and the rates and mechanisms of processes responsible for converting the liquor to its final smelt and syngas products were to be investigated. This would be accomplished by combining fundamental, lab-scale experiments with measurements taken using a new semi-pilot scale pressurized entrained-flow gasifier. As a result of insufficient availability of funds and changes in priority within the Office of Biomass Programs of the U.S. Department of Energy, the research program was terminated in its second year. In total, only half of the budgeted funding was made available for the program, and most of this was used during the first year for construction of the experimental systems to be used in the program. This had a severe impact on the program. As a consequence, most of the planned research was unable to be performed. Only studies that relied on computational modeling or existing experimental facilities started early enough to deliver useful results by the time to program was terminated Over the course of the program, small scale (approx. 1 ton/day) entrained-flow gasifier was designed and installed at the University of Utah's off-campus Industrial Combustion and Gasification Research Facility. The system is designed to operate at

  18. Method and apparatus for assaying wood pulp fibers

    DOE Patents [OSTI]

    Gustafson, Richard (Bellevue, WA); Callis, James B. (Seattle, WA); Mathews, Jeffrey D. (Neenah, WI); Robinson, John (Issaquah, WA); Bruckner, Carsten A. (San Mateo, CA); Suvamakich, Kuntinee (Seattle, WA)

    2009-05-26

    Paper pulp is added to a stain solution. The stain solution and pulp fibers are mixed to form a slurry. Samples are removed from the slurry and are admixed with dilution water and a bleach. Then, the fibers are moved into a flow cell where they are subjected to a light source adapted to stimulate fluorescence from the stained pulp fiber. Before the fiber slurry enters the flow cell it is mixed with a dilution water of bleach to reduce background fluorescence. The fluorescent light is collimated and directed through a dichroic filter onto a fluorescence splitting dichroic filter.

  19. July 2014 Monthly News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    July 2014 Monthly News Blast July 2014 Monthly News Blast July 2014 Monthly News Blast from the Bioenergy Technologies Office. july_2014_newsblast.pdf (186.62 KB) More Documents & Publications May 2014 Monthly News Blast April 2014 Monthly News Blast June 2014 Monthly News Blast Bioenergy Home About the Bioenergy Technologies Office Research & Development Education & Workforce Development Financial Opportunities Information Resources News Events Contact Us

  20. A Cost-Benefit Assessment of Gasification-Based Biorefining in the Kraft Pulp and Paper Industry

    SciTech Connect (OSTI)

    Eric D. Larson; Stefano Consonni; Ryan E. Katofsky; Kristiina Iisa; W. James Frederick

    2007-03-31

    Production of liquid fuels and chemicals via gasification of kraft black liquor and woody residues (''biorefining'') has the potential to provide significant economic returns for kraft pulp and paper mills replacing Tomlinson boilers beginning in the 2010-2015 timeframe. Commercialization of gasification technologies is anticipated in this period, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are in most cases already commercially established today in the ''gas-to-liquids'' industry. These conclusions are supported by detailed analysis carried out in a two-year project co-funded by the American Forest and Paper Association and the Biomass Program of the U.S. Department of Energy. This work assessed the energy, environment, and economic costs and benefits of biorefineries at kraft pulp and paper mills in the United States. Seven detailed biorefinery process designs were developed for a reference freesheet pulp/paper mill in the Southeastern U.S., together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. Commercial (''Nth'') plant levels of technology performance and cost were assumed. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which would be refined to vehicle fuels at existing petroleum refineries), dimethyl ether (a diesel engine fuel or LPG substitute), or an ethanol-rich mixed-alcohol product. Compared to installing a new Tomlinson power/recovery system, a biorefinery would require larger capital investment. However, because the biorefinery would have higher energy efficiencies, lower air emissions, and a more diverse product slate (including transportation fuel), the internal rates of return (IRR) on the incremental capital investments would be attractive under many circumstances. For nearly all of the

  1. Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation

    Office of Scientific and Technical Information (OSTI)

    Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation Neubauer, J. 25 ENERGY STORAGE BATTERY; LITHIUM-ION; STATIONARY ENERGY STORAGE; BLAST; BATTERY DEGRADATION;...

  2. Optimizing Blast Furnace Operation to Increase Efficiency and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blast Furnace Operation to Increase Efficiency and Lower Costs Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs cfdblastfurnace.pdf (552.85 KB) More ...

  3. March 2014 Monthly News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 2014 Monthly News Blast March 2014 Monthly News Blast BETO Gets Innovative with New Interactive Tool PDF icon march2014newsblast.pdf More Documents & Publications February ...

  4. Method and apparatus for assaying wood pulp fibers (Patent) ...

    Office of Scientific and Technical Information (OSTI)

    A paper copy of this document is also available for sale to the public from the National Technical Information Service, Springfield, VA at www.ntis.gov. Paper pulp is added to a ...

  5. Method and apparatus for assaying wood pulp fibers (Patent) ...

    Office of Scientific and Technical Information (OSTI)

    to stimulate fluorescence from the stained pulp fiber. Before the fiber slurry enters the flow cell it is mixed with a dilution water of bleach to reduce background fluorescence. ...

  6. Atomic Photography: Blasts from the Past

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic Photography National Security Science Latest Issue:July 2015 past issues All Issues submit Atomic Photography: Blasts from the Past A gallery of images reveals the weird...

  7. Rebuilding of Rautaruukki blast furnaces

    SciTech Connect (OSTI)

    Kallo, S.; Pisilae, E.; Ojala, K.

    1997-12-31

    Rautaruukki Oy Raahe Steel rebuilt its blast furnaces in 1995 (BF1) and 1996 (BF2) after 10 year campaigns and production of 9,747 THM/m{sup 3} (303 NTHM/ft{sup 3}) and 9,535 THM/m{sup 3} (297 NTHM/ft{sup 3}), respectively. At the end of the campaigns, damaged cooling system and shell cracks were increasingly disturbing the availability of furnaces. The goal for rebuilding was to improve the cooling systems and refractory quality in order to attain a 15 year campaign. The furnaces were slightly enlarged to meet the future production demand. The blast furnace control rooms and operations were centralized and the automation and instrumentation level was considerably improved in order to improve the operation efficiency and to reduce manpower requirements. Investments in direct slag granulation and improved casthouse dedusting improved environmental protection. The paper describes the rebuilding.

  8. Geneva Steel blast furnace improvements

    SciTech Connect (OSTI)

    Fowles, R.D.; Hills, L.S.

    1993-01-01

    Geneva Steel is located in Utah and is situated near the western edge of the Rocky Mountains adjacent to the Wasatch Front. Geneva's No. 1, 2 and 3 are the only remaining operating blast furnaces in the United States west of the Mississippi River. They were originally constructed in 1943 to support steelmaking during World War II. During the early 60's all three furnaces were enlarged to their current working volume. Very few major improvements were made until recently. This discussion includes a brief historical perspective of operating difficulties associated with practice, design and equipment deficiencies. Also included is an overview of blast furnace improvements at Geneva found necessary to meet the demands of modern steelmaking. Particular emphasis will be placed on casthouse improvements.

  9. Dry Kraft Pulping at Ambient Pressure for Cost Effective Energy Saving and Pollution Deduction

    SciTech Connect (OSTI)

    Yulin Deng; Art Ragauskas

    2012-08-28

    Sponsored by the DOE Industrial Energy Efficiency Grand Challenge program, our research team at the Georgia Institute of Technology conducted laboratory studies and confirmed the concept of making wood pulp using a dry pulping technology. This technology is a new process different from any prior pulping technology used in Kraft and CTMP pulping. Three different kinds of dry pulping methods were investigated. (a) Dry Pulping at Atmospheric Pressure: The first one is to dry and bake the pretreated woodchips in a conventional oven at atmospheric pressure without the use of a catalyst. (b) Dry Pulping at Reduced Pressure: The second method is to dry the pretreated woodchips first in a vacuum oven in the presence of anthraquinone (AQ) as a pulping catalyst, followed by baking at elevated temperature. (c) Liquid Free Chemical Pulping, LFCP. The third method is to first remove the free water of pretreated woodchips, followed by dry pulping using a conventional Kraft pulping digester with AQ and triton as additives. Method one: Experimental results indicated that Dry Pulping at Atmospheric Pressure could produce pulp with higher brightness and lower bulk than conventional Kraft pulp. However, tensile strength of the acquired pulp is much lower than traditional Kraft pulp, and their Kappa number and energy consumption are higher than conventional Kraft pulp. By fully analyzing the results, we concluded that wood fibers might be damaged during the drying process at elevated temperature. The main reason for wood fiber damage is that a long drying time was used during evaporation of water from the woodchips. This resulted in an un-uniform reaction condition on the woodchips: the outside layer of the woodchips was over reacted while inside the woodchips did not reacted at all. To solve this problem, dry pulping at reduced pressure was investigated. Method two: To achieve uniform reaction throughout the entire reaction system, the water inside the pretreated woodchips was

  10. Generator-Absorber heat exchange transfer apparatus and method using an intermediate liquor

    DOE Patents [OSTI]

    Phillips, Benjamin A.; Zawacki, Thomas S.

    1996-11-05

    Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium where the working solution has an intermediate liquor concentration.

  11. August 2012 Biomass Program Monthly News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 2012 Biomass Program Monthly News Blast August 2012 Biomass Program Monthly News Blast Monthly newsletter for August 2012 from the Department of Energy's Biomass Program. august2012_newsblast.pdf (155.42 KB) More Documents & Publications Biomass Program September 2012 News Blast Biomass Program Monthly News Blast, October 2012 November 2012 Newsblast

  12. Biomass Program Monthly News Blast, October 2012 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blast, October 2012 Biomass Program Monthly News Blast, October 2012 Copy of the Biomass Program Monthly News Blast from October 2012. october2012_newsblast.pdf (169.17 KB) More Documents & Publications November 2012 Newsblast Biomass Program September 2012 News Blast Monthly Newsblast December 2012

  13. Highly concentrated foam formulation for blast mitigation

    DOE Patents [OSTI]

    Tucker, Mark D.; Gao, Huizhen

    2010-12-14

    A highly concentrated foam formulation for blast suppression and dispersion mitigation for use in responding to a terrorism incident involving a radiological dispersion device. The foam formulation is more concentrated and more stable than the current blast suppression foam (AFC-380), which reduces the logistics burden on the user.

  14. Black liquor combustion validated recovery boiler modeling, five-year report

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  15. ITP Forest Products: Report for AIChE Pulp and Paper Industry...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report for AIChE Pulp and Paper Industry Energy Bandwidth Study Report ITP Forest Products: Report for AIChE Pulp and Paper Industry Energy Bandwidth Study Report PDF icon ...

  16. Wood Pulp Digetster Wall Corrosion Investigation

    SciTech Connect (OSTI)

    Giles, GE

    2003-09-18

    The modeling of the flow in a wood pulp digester is but one component of the investigation of the corrosion of digesters. This report describes the development of a Near-Wall-Model (NWM) that is intended to couple with a CFD model that determines the flow, heat, and chemical species transport and reaction within the bulk flow of a digester. Lubrication theory approximations were chosen from which to develop a model that could determine the flow conditions within a thin layer near the vessel wall using information from the interior conditions provided by a CFD calculation of the complete digester. The other conditions will be determined by coupled solutions of the wood chip, heat, and chemical species transport and chemical reactions. The NWM was to couple with a digester performance code in an iterative fashion to provide more detailed information about the conditions within the NW region. Process Simulations, Ltd (PSL) is developing the digester performance code. This more detailed (and perhaps more accurate) information from the NWM was to provide an estimate of the conditions that could aggravate the corrosion at the wall. It is intended that this combined tool (NWM-PSL) could be used to understand conditions at/near the wall in order to develop methods to reduce the corrosion. However, development and testing of the NWM flow model took longer than anticipated and the other developments (energy and species transport, chemical reactions and linking with the PSL code) were not completed. The development and testing of the NWM are described in this report. In addition, the investigation of the potential effects of a clear layer (layer reduced in concentration of wood chips) near the wall is reported in Appendix D. The existence of a clear layer was found to enhance the flow near the wall.

  17. Bandwidth Study U.S. Pulp and Paper Manufacturing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bandwidth Study U.S. Pulp and Paper Manufacturing Bandwidth Study U.S. Pulp and Paper Manufacturing Pulp-Paper.jpg Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. pulp and paper manufacturing. The study relies on multiple sources to estimate the energy used in six individual

  18. RSE Pulp & Chemical, LLC (Subsidiary of Red Shield Environmental, LLC) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy RSE Pulp & Chemical, LLC (Subsidiary of Red Shield Environmental, LLC) RSE Pulp & Chemical, LLC (Subsidiary of Red Shield Environmental, LLC) A fact sheet detailling a proposal of a biorefinery facility in an existing pulp mill to demonstrate the production of cellulosic ethanol from lignocellulosic (wood) extract. RSE Pulp & Chemical, LLC (Subsidiary of Red Shield Environmental, LLC) (19.31 KB) More Documents & Publications Pacific Ethanol, Inc EA-1888:

  19. ITP Forest Products: Energy and Environmental Profile of the U.S. Pulp and Paper Industry

    Office of Energy Efficiency and Renewable Energy (EERE)

    The United States is the world's leading producer, consumer, and exporter of pulp, paper, and paperboard products.

  20. Biological pretreatment for thermomechanical (TMP) and chemithermomechanical (CTMP) pulping processes

    SciTech Connect (OSTI)

    Myers, G.C.; Akhtar, M.; Lentz, M.

    1996-10-01

    Treatment of wood chips with lignin-degrading fungi prior to preparing a refiner mechanical pulp (RMP) has substantially reduced energy consumption and increased paper strength properties. This study reports on thermomechanical (TMP) and chemithermo-mechanical pulping (CTMP) of fungus treated wood chips. Loblolly pine chips were innoculated with Ceriporiopsis subvermispora, strain L14807 SS-3, and incubated two weeks in a chip silo. A pressurized 305 mm diameter disk refiner was used to prepare TMP and CTMP`s from fungal treated and non-treated wood chips. Two procedures were used to prepare the CTMP`s, injecting a sodium hydroxide and hydrogen peroxide solution into the pressurized refiner, and impregnating the wood chips with a sodium sulfite solution. Energy consumption during pulp preparation and handsheet strength and optical properties will be presented and discussed.

  1. LTC vacuum blasting machine (concrete): Baseline report

    SciTech Connect (OSTI)

    1997-07-31

    The LTC shot blast technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The LTC 1073 Vacuum Blasting Machine uses a high-capacity, direct-pressure blasting system which incorporates a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast. It incorporates a vacuum system which removes dust and debris from the surface as it is blasted. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure during maintenance activities was minimal, but due to mechanical difficulties dust monitoring could not be conducted during operation. Noise exposure was significant. Further testing for each of these exposures is recommended because of the outdoor environment where the testing demonstration took place. This may cause the results to be inaccurate. It is feasible that the dust and noise levels will be higher in an enclosed environment. In addition, other safety and health issues found were ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, and arm-hand vibration.

  2. Experimental investigations of beet pulp drying in superheated steam under pressure

    SciTech Connect (OSTI)

    Urbaniec, K.; Malczewski, J. [Warsaw Univ. of Technology, Plock (Poland). Dept. of Process Equipment

    1997-10-01

    Beet pulp drying in superheated steam under pressure makes it possible to save energy in sugar factories. A new concept of a two-stage convective steam drier is presented. To obtain kinetic data on beet pulp drying, an experimental setup was built. Beet pulp samples were dried at steam pressure up to 4 bar and temperature up to 220 C.

  3. Method of treating contaminated HEPA filter media in pulp process

    DOE Patents [OSTI]

    Hu, Jian S.; Argyle, Mark D.; Demmer, Ricky L.; Mondok, Emilio P.

    2003-07-29

    A method for reducing contamination of HEPA filters with radioactive and/or hazardous materials is described. The method includes pre-processing of the filter for removing loose particles. Next, the filter medium is removed from the housing, and the housing is decontaminated. Finally, the filter medium is processed as pulp for removing contaminated particles by physical and/or chemical methods, including gravity, flotation, and dissolution of the particles. The decontaminated filter medium is then disposed of as non-RCRA waste; the particles are collected, stabilized, and disposed of according to well known methods of handling such materials; and the liquid medium in which the pulp was processed is recycled.

  4. Perfluorocarbon vapor tagging of blasting cap detonators

    DOE Patents [OSTI]

    Dietz, R.N.; Senum, G.I.

    A plug for a blasting cap is made of an elastomer in which is dissolved a perfluorocarbon. The perfluorocarbon is released as a vapor into the ambient over a long period of time to serve as a detectable taggant.

  5. Perfluorocarbon vapor tagging of blasting cap detonators

    DOE Patents [OSTI]

    Dietz, Russell N.; Senum, Gunnar I.

    1981-01-01

    A plug for a blasting cap is made of an elastomer in which is dissolved a perfluorocarbon. The perfluorocarbon is released as a vapor into the ambient over a long period of time to serve as a detectable taggant.

  6. Material Systems for Blast-Energy Dissipation

    SciTech Connect (OSTI)

    James Schondel; Henry S. Chu

    2010-10-01

    Lightweight panels have been designed to protect buildings and vehicles from blast pressures by activating energy dissipation mechanisms under the influence of blast loading. Panels were fabricated which featured a variety of granular materials and hydraulic dissipative deformation mechanisms and the test articles were subjected to full-scale blast loading. The force time-histories transmitted by each technology were measured by a novel method that utilized inexpensive custom-designed force sensors. The array of tests revealed that granular materials can effectively dissipate blast energy if they are employed in a way that they easily crush and rearrange. Similarly, hydraulic dissipation can effectively dissipate energy if the panel features a high fraction of porosity and the panel encasement features low compressive stiffness.

  7. Blast furnace supervision and control system

    SciTech Connect (OSTI)

    Remorino, M.; Lingiardi, O.; Zecchi, M.

    1997-12-31

    On December 1992, a group of companies headed by Techint, took over Somisa, the state-owned integrated steel plant located at San Nicolas, Province of Buenos Aires, Argentina, culminating an ambitious government privatization scheme. The blast furnace 2 went into a full reconstruction and relining in January 1995. After a 140 MU$ investment the new blast furnace 2 was started in September 1995. After more than one year of operation of the blast furnace the system has proven itself useful and reliable. The main reasons for the success of the system are: same use interface for all blast furnace areas -- operation, process, maintenance and management, (full horizontal and vertical integration); and full accessibility to all information and process tools though some restrictions apply to field commands (people empowerment). The paper describes the central system.

  8. January 2014 News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    January 2014 News Blast January 2014 News Blast Congratulations Jonathan Male, Valerie Reed, and Joynce Yang of the Bioenergy Technologies Office (BETO) for being voted into the "Top 100 People in the Bioeconomy." In December 2013, the readers and editors of Biofuels Digest announced BETO's own staff members as the 15th most influential leaders in the bioeconomy for 2013-2014, outranking Members of Congess, leaders of large trade associations, and international bioenergy companies.

  9. Ultra Safe And Secure Blasting System

    SciTech Connect (OSTI)

    Hart, M M

    2009-07-27

    The Ultra is a blasting system that is designed for special applications where the risk and consequences of unauthorized demolition or blasting are so great that the use of an extraordinarily safe and secure blasting system is justified. Such a blasting system would be connected and logically welded together through digital code-linking as part of the blasting system set-up and initialization process. The Ultra's security is so robust that it will defeat the people who designed and built the components in any attempt at unauthorized detonation. Anyone attempting to gain unauthorized control of the system by substituting components or tapping into communications lines will be thwarted in their inability to provide encrypted authentication. Authentication occurs through the use of codes that are generated by the system during initialization code-linking and the codes remain unknown to anyone, including the authorized operator. Once code-linked, a closed system has been created. The system requires all components connected as they were during initialization as well as a unique code entered by the operator for function and blasting.

  10. May 2014 Monthly News Blast | Department of Energy

    Energy Savers [EERE]

    May 2014 Monthly News Blast May 2014 Monthly News Blast from the Bioenergy Technologies Office. may2014newsblast.pdf (160.85 KB) More Documents & Publications April 2014 Monthly ...

  11. July 2012 Biomass Program Monthly News Blast | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    July 2012 Biomass Program Monthly News Blast July 2012 Biomass Program Monthly News Blast July 2012 monthly newsletter from the Department of Energy's Biomass Program. july2012_newsblast.pdf (188.06 KB) More Documents & Publications July 2012 Biomass Program Monthly News Blast Monthly Newsblast December 2012 November 2012 Newsblast

  12. Regeneration of FGD waste liquors: Production of ammonium and potassium sulfate mixed fertilizer. Quarterly technical report, July 1993--September 1993

    SciTech Connect (OSTI)

    Randolph, A.D.; Kwon, T.M.

    1993-12-01

    Regeneration of the Fe{sup II}-EDTA scrubbing liquors for simultaneous removal of SO{sub 2} and NO{sub x} in flue gas involves removing the nitrogen-sulfur (N-S) compounds accumulated in the liquor. In this paper, the authors investigated a simple regeneration process which selectively precipitates the N-S compounds as potassium salts and then hydrolyzes them to yield ammonium/potassium sulfate as a marketable byproduct. They believe this is the first report on precipitation and hydrolysis characteristics of the N-S compounds in actual waste scrubbing liquor. Precipitation of the N-S compounds was achieved by adding K{sub 2}SO{sub 4} to the scrubbing liquor. Effects of the amount of added K{sub 2}SO{sub 4} on the amount of removed N-S compounds, precipitated crystals, and the potassium left over in the scrubbing liquor were studied. Hydrolysis of the precipitated N-S compounds to ammonium sulfate was performed in a sulfuric acid environment. Effects of acidity, concentration of N-S compounds, and temperature on the hydrolysis are discussed. Analysis of the observed hydrolysis pattern showed that the reaction proceeded following first order kinetics in terms of N-S compound concentration.

  13. Assessment of Gasification-Based Biorefining at Kraft Pulp and Paper Mills in the United States, Part A: Background and Assumptions

    SciTech Connect (OSTI)

    Larson, E. D.; Consonni, S.; Katofsky, R. E.; Iisa, K.; Frederick, W. J., Jr.

    2008-11-01

    Commercialization of black liquor and biomass gasification technologies is anticipated in the 2010-2015 time frame, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are already commercially established in the gas-to-liquids or coal-to-liquids industries. This set of two papers describes key results from a major assessment of the prospective energy, environmental, and financial performance of commercial gasification-based biorefineries integrated with kraft pulp and paper mills [1]. Seven detailed biorefinery designs were developed for a reference mill in the southeastern United States, together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which could be refined to vehicle fuels at an existing petroleum refinery), dimethyl ether (a diesel engine fuel or propane substitute), or an ethanol-rich mixed-alcohol product. This paper describes the key assumptions that underlie the biorefinery designs. Part B will present analytical results.

  14. Carbon Emissions Reduction Potential in the US Chemicals and Pulp and Paper

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industries by Applying CHP Technologies, June 1999 | Department of Energy Carbon Emissions Reduction Potential in the US Chemicals and Pulp and Paper Industries by Applying CHP Technologies, June 1999 Carbon Emissions Reduction Potential in the US Chemicals and Pulp and Paper Industries by Applying CHP Technologies, June 1999 The purpose of this 1999 paper is to estimate the remaining CHP potential in the chemicals and pulp/paper industries by capacity size, and estimate energy savings and

  15. ITP Forest Products: Report for AIChE Pulp and Paper Industry Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bandwidth Study Report | Department of Energy Report for AIChE Pulp and Paper Industry Energy Bandwidth Study Report ITP Forest Products: Report for AIChE Pulp and Paper Industry Energy Bandwidth Study Report doe_bandwidth.pdf (1.41 MB) More Documents & Publications Bandwidth Study U.S. Pulp and Paper Manufacturing AMO PEER REVIEW, MAY 28-29, 2015 Low Cost Carbon Fiber from Renewable Resources

  16. System for removing solids from a used lime or limestone slurry scrubbing liquor in flue gas desulfurization

    SciTech Connect (OSTI)

    Randolph, A.D.

    1981-10-13

    The flue gas desulfurization process using a lime or limestone slurry scrubbing solution produces used liquor containing calcium sulfite or sulfate (Typically gypsum). Precipitated particles are removed by feeding the used scrubbing liquor to an agitated crystallization zone to grow crystals and directing part of the used scrubbing liquor from that zone to a quiescent crystallization zone, in which particles are settled back into the agitated zone. An underflow stream from the agitated zone containing large crystals is combined with an overflow stream from the quiescent zone, which combined stream is clarified with the fines being returned to the scrubber and the large crystals being removed as a waste product. Apparatus for performing the above process in which the agitated and quiescent crystallization zones form part of a single crystallization vessel, and the two zones are separated by a baffle.

  17. The design, implementation, and evaluation of mpiBLAST

    SciTech Connect (OSTI)

    Darling, A. E.; Carey, L.; Feng, W. C.

    2003-01-01

    mpiBLAST is an open-source parallelization of BLAST that achieves superlinear speed-up by segmenting a BLAST database and then having each node in a computational cluster search a unique portion of the database. Database segmentation permits each node to search a smaller portion of the database, eliminating disk I/O and vastly improving BLAST performance. Because database segmentation does not create heavy communication demands, BLAST users can take advantage of low-cost and efficient Linux cluster architectures such as the bladed Beowulf. In addition to presenting the software architecture of mpiBLAST we present a detailed performance analysis of mpiBLAST to demonstrate its scalability.

  18. Process control techniques for the Sidmar blast furnaces

    SciTech Connect (OSTI)

    Vandenberghe, D.; Bonte, L.; Nieuwerburgh, H. van

    1995-12-01

    The major challenge for modern blast furnace operation is the achievement of a very high productivity, excellent hot metal quality, low fuel consumption and longer blast furnace campaigns. The introduction of predictive models, decision supporting software and expert systems has reduced the standard deviation of the hot metal silicon content. The production loss due to the thermal state of the blast furnace has decreased three times since 1990. An appropriate control of the heat losses with high pulverized coal injection rates, is of the utmost importance for the life of the blast furnace. Different rules for the burden distribution of both blast furnaces are given. At blast furnace A, a peripheral gas flow is promoted, while at blast furnace B a more central gas flow is promoted.

  19. Energy and Environmental Profile of the U.S. Pulp and Paper Industry

    SciTech Connect (OSTI)

    Miller, Melanie; Justiniano, Mauricio; McQueen, Shawna

    2005-12-01

    This detailed report benchmarks the energy and environmental characteristics of the key technologies used in the major processes of the United States pulp and paper industry.

  20. High productivity in Australian blast furnaces

    SciTech Connect (OSTI)

    Nightingale, R.J.; Mellor, D.G.; Jelenich, L.; Ward, R.F.

    1995-12-01

    Since the emergence of the Australian domestic economy from recession in 1992, the productivity of BHP`s blast furnace has increased significantly to meet the demands of both domestic and export markets. BHP Steel operates six blast furnaces at its three Australian integrated plants. These furnaces vary widely in their size, feed, technology and current campaign status. This paper reviews the principal issues associated with productivity improvements over recent years. These gains have been achieved through activities associated with a wide range of process, equipment and human resource based issues.

  1. Blast furnace control after the year 2000

    SciTech Connect (OSTI)

    Gyllenram, R.; Wikstroem, J.O.; Hallin, M.

    1996-12-31

    Rapid technical development together with developments in work organization makes it important to investigate possible ways to achieve a cost efficient process control of different metallurgical processes. This paper describes a research project, and proposes a human oriented Information Technology Strategy, ITS, for control of the Blast Furnace process. The method used is that of deductive reasoning from a description of the prevailing technological level and experiences from various development activities. The paper is based on experiences from the No. 2 Blast Furnace at Luleaa Works but the conclusions do not at this stage necessarily reflect the opinion of the management and personnel or reflect their intentions for system development at SSAB.

  2. Stability and Regeneration of Catalysts for the Destruction of Tars from Bio-mass Black Liquor Gasification

    SciTech Connect (OSTI)

    Pradeep Agrawal

    2004-09-07

    The goal of this project was to develop catalytic materials and processes that would be effective in the destruction of tars formed during the gasification of black liquor and biomass. We report here the significant results obtained at the conclusion of this two year project.

  3. Cogeneration handbook for the pulp and paper industry. [Contains glossary

    SciTech Connect (OSTI)

    Griffin, E.A.; Moore, N.L.; Fassbender, L.L.; Garrett-Price, B.A.; Fassbender, A.G.; Eakin, D.E.; Gorges, H.A.

    1984-03-01

    The decision of whether to cogenerate involves several considerations, including technical, economic, environmental, legal, and regulatory issues. Each of these issues is addressed separately in this handbook. In addition, a chapter is included on preparing a three-phase work statement, which is needed to guide the design of a cogeneration system. In addition, an annotated bibliography and a glossary of terminology are provided. Appendix A provides an energy-use profile of the pulp and paper industry. Appendices B and O provide specific information that will be called out in subsequent chapters.

  4. Fermentation and chemical treatment of pulp and paper mill sludge

    DOE Patents [OSTI]

    Lee, Yoon Y; Wang, Wei; Kang, Li

    2014-12-02

    A method of chemically treating partially de-ashed pulp and/or paper mill sludge to obtain products of value comprising taking a sample of primary sludge from a Kraft paper mill process, partially de-ashing the primary sludge by physical means, and further treating the primary sludge to obtain the products of value, including further treating the resulting sludge and using the resulting sludge as a substrate to produce cellulase in an efficient manner using the resulting sludge as the only carbon source and mixtures of inorganic salts as the primary nitrogen source, and including further treating the resulting sludge and using the resulting sludge to produce ethanol.

  5. Originally Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    August 2009" "Revised: October 2009" "Next MECS will be conducted in 2010" "Table 3.5 Selected Byproducts in Fuel Consumption, 2006;" " Level: National and Regional Data; " " Row: NAICS Codes; Column: Energy Sources;" " Unit: Trillion Btu." ,,,,,,,,,,"Waste" ,,,,"Blast",,,,"Pulping Liquor",,"Oils/Tars"

  6. RSE Table 3.5 Relative Standard Errors for Table 3.5

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Relative Standard Errors for Table 3.5;" " Unit: Percents." " "," "," "," "," "," "," "," ","Waste",," " " "," "," ","Blast"," "," ","Pulping Liquor"," ","Oils/Tars" "NAICS"," ","

  7. Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs State-of-the-Art Computational Fluid Dynamics Model Optimizes Fuel Rate in Blast Furnaces The blast furnace (BF) is the most widely used ironmaking process in the U.S. A major advance in BF ironmaking has been the use of pulverized coal which partially replaces metallurgi- cal coke. This results in substantial improvement in furnace effciency and thus the reductions of energy consumption and greenhouse gas emissions.

  8. Other States Natural Gas Coalbed Methane, Reserves Based Production

    Gasoline and Diesel Fuel Update (EIA)

    August 2009 Revised: October 2009 Next MECS will be conducted in 2010 Table 3.5 Selected Byproducts in Fuel Consumption, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Waste Blast Pulping Liquor Oils/Tars NAICS Furnace/Coke Petroleum or Wood Chips, and Waste Code(a) Subsector and Industry Total Oven Gases Waste Gas Coke Black Liquor Bark Materials Total United States 311 Food 10 0 3 0 0 7 Q 3112 Grain and Oilseed Milling 7 0 1 0 0 6 *

  9. Originally Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    August 2009 Revised: October 2009 Next MECS will be conducted in 2010 Table 3.5 Selected Byproducts in Fuel Consumption, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Waste Blast Pulping Liquor Oils/Tars NAICS Furnace/Coke Petroleum or Wood Chips, and Waste Code(a) Subsector and Industry Total Oven Gases Waste Gas Coke Black Liquor Bark Materials Total United States 311 Food 10 0 3 0 0 7 Q 3112 Grain and Oilseed Milling 7 0 1 0 0 6 *

  10. Traumatic Brain Injury Protection: Blast Pressure Sensors in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Traumatic Brain Injury Protection: Blast Pressure ... Technology Marketing Summary The cost of treating traumatic brain injury (TBI) is ...

  11. September 2014 Monthly News Blast | Department of Energy

    Office of Environmental Management (EM)

    Bioenergy Technologies Office. september2014newsblast.pdf (162.13 KB) More Documents & Publications August 2014 Monthly News Blast Growing America's Energy Future: Bioenergy ...

  12. India's pulp and paper industry: Productivity and energy efficiency

    SciTech Connect (OSTI)

    Schumacher, Katja

    1999-07-01

    Historical estimates of productivity growth in India's pulp and paper sector vary from indicating an improvement to a decline in the sector's productivity. The variance may be traced to the time period of study, source of data for analysis, and type of indices and econometric specifications used for reporting productivity growth. The authors derive both statistical and econometric estimates of productivity growth for this sector. Their results show that productivity declined over the observed period from 1973-74 to 1993-94 by 1.1% p.a. Using a translog specification the econometric analysis reveals that technical progress in India's pulp and paper sector has been biased towards the use of energy and material, while it has been capital and labor saving. The decline in productivity was caused largely by the protection afforded by high tariffs on imported paper products and other policies, which allowed inefficient, small plants to enter the market and flourish. Will these trends continue into the future, particularly where energy use is concerned? The authors examine the current changes in structure and energy efficiency undergoing in the sector. Their analysis shows that with liberalization of the sector, and tighter environmental controls, the industry is moving towards higher efficiency and productivity. However, the analysis also shows that because these improvements are being hampered by significant financial and other barriers the industry might have a long way to go.

  13. A Phased Array Approach to Rock Blasting

    SciTech Connect (OSTI)

    Leslie Gertsch; Jason Baird

    2006-07-01

    A series of laboratory-scale simultaneous two-hole shots was performed in a rock simulant (mortar) to record the shock wave interference patterns produced in the material. The purpose of the project as a whole was to evaluate the usefulness of phased array techniques of blast design, using new high-precision delay technology. Despite high-speed photography, however, we were unable to detect the passage of the shock waves through the samples to determine how well they matched the expected interaction geometry. The follow-up mine-scale tests were therefore not conducted. Nevertheless, pattern analysis of the vectors that would be formed by positive interference of the shockwaves from multiple charges in an ideal continuous, homogeneous, isotropic medium indicate the potential for powerful control of blast design, given precise characterization of the target rock mass.

  14. Temperatures in the blast furnace refractory lining

    SciTech Connect (OSTI)

    Hebel, R.; Streuber, C.; Steiger, R.; Jeschar, R.

    1995-12-01

    The campaign life duration of a blast furnace is mainly determined by the condition of the refractory lining in heavy-duty zones such as the hearth, bosh, belly and lower stack. To achieve a desired lifetime, the temperature of the lining in these areas thereby proved to be the decisive controllable parameter. Low operating temperatures result in prolonged service life and are attained through high cooling efficiency. Besides the refractory grade chosen, the wear profile is mainly determined by the type of cooling system applied and the cooling intensity. Therefore, an appropriate compromise between long service life and energy losses has to be found in each case. In order to predict the service life of a lining it is important to know the wear condition at all times during the campaign. The paper describes the approaches the authors have made so far on European blast furnaces, on a theoretical and practical basis, on how to analyze the lining wear.

  15. Explosive parcel containment and blast mitigation container

    DOE Patents [OSTI]

    Sparks, Michael H.

    2001-06-12

    The present invention relates to a containment structure for containing and mitigating explosions. The containment structure is installed in the wall of the building and has interior and exterior doors for placing suspicious packages into the containment structure and retrieving them from the exterior of the building. The containment structure has a blast deflection chute and a blowout panel to direct over pressure from explosions away from the building, surrounding structures and people.

  16. BETO Monthly News Blast, August 2014

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    News Blast August 2014 Grand Opening for Project LIBERTY: Nation's First Plant to Use Corn Waste as a Feedstock POET-DSM's Project LIBERTY in Emmetsburg, Iowa, will celebrate its grand opening September 3, 2014, becoming the first commercial-scale cellulosic ethanol plant to use corn waste as a feedstock. Developed through a joint venture between POET, LLC in Sioux Falls, South Dakota, and DSM Royal, a Dutch maker of enzymes, the project uses biochemical conversion technologies (yeast and

  17. Centrifugal shot blasting. Innovative technology summary report

    SciTech Connect (OSTI)

    Not Available

    1999-07-01

    At the US Department of Energy (DOE) Fernald Environmental Management Project (FEMP), the Facilities Closure and Demolition Projects Integrated Remedial Design/Remedial Action (RD/RA) work plan calls for the removal of one inch (1 in) depth of concrete surface in areas where contamination with technetium-99 has been identified. This report describes a comparative demonstration between two concrete removal technologies: an innovative system using Centrifugal Shot Blasting (CSB) and a modified baseline technology called a rotary drum planer.

  18. Thermal reclamation of spent blasting abrasive

    SciTech Connect (OSTI)

    Bryan, B.G. ); Thomas, W.; Adema, C. )

    1990-01-01

    Abrasive blasting media is used to remove anticorrosive and antifoulant coatings from the hulls and tanks of US Navy ships. The total production of paint-contaminated spent abrasives from the eight US. Navy shipyards ranges from 75,000 to 100,000 tons per year. Most of this spent abrasive is disposed in landfills. Organic paint binders and heavy metals are present in the spent abrasives in concentrations sufficient to classify them as hazardous wastes in some states. In an effort to avoid the rising costs an long-term environmental liability associated with landfilling this waste, the US Navy has investigated various methods of reclaiming spent abrasives for reuse in hull- and tank-blasting operations. This paper discusses the results of a research and development project conducted under the Navy's Hazardous Waste Minimization Program to test a fluidized-bed sloped-grid (FBSG) reclaimer to determine if it could be used to recycle spent abrasive. Thirty tons of abrasive were processed and a product meeting military specifications for new abrasives was reclaimed. Blasting performance was also comparable to new abrasives. 3 refs., 1 fig., 2 tabs.

  19. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L.

    1995-12-01

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  20. June 2012 News Blast: Algae on the Mind | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 News Blast: Algae on the Mind June 2012 News Blast: Algae on the Mind Biomass Program monthly newsletter from June 2012. june2012_newsblast.pdf (137.87 KB) More Documents & Publications Biomass Program Monthly News Blast - May 2012 July 2012 Biomass Program Monthly News Blast July 2012 Biomass Program

  1. System and method for conditioning a hardwood pulp liquid hydrolysate

    DOE Patents [OSTI]

    Waite, Darrell M; Arnold, Richard; St. Pierre, James; Pendse, Hemant P; Ceckler, William H

    2013-12-17

    A system and method for hardwood pulp liquid hydrolysate conditioning includes a first evaporator receives a hardwood mix extract and outputting a quantity of vapor and extract. A hydrolysis unit receives the extract, hyrolyzes and outputs to a lignin separation device, which separates and recovers a quantity of lignin. A neutralization device receives extract from the lignin separation device and a neutralizing agent, producing a mixture of solid precipitate and a fifth extract. The solid precipitate is removed from the fifth extract. A second evaporator removes a quantity of acid from the fifth extract in a vapor form. This vapor may be recycled to improve total acid recovery or discarded. A desalination device receives the diluted extract, separates out some of the acid and salt and outputs a desalinated solution.

  2. System and method for conditioning a hardwood pulp liquid hydrolysate

    SciTech Connect (OSTI)

    Waite, Darrell; Arnold, Richard; St. Pierre, James; Pendse, Hemant P.; Ceckler, William H.

    2015-06-30

    A system and method for hardwood pulp liquid hydrolysate conditioning includes a first evaporator receives a hardwood mix extract and outputting a quantity of vapor and extract. A hydrolysis unit receives the extract, hydrolyzes and outputs to a lignin separation device, which separates and recovers a quantity of lignin. A neutralization device receives extract from the lignin separation device and a neutralizing agent, producing a mixture of solid precipitate and a fifth extract. The solid precipitate is removed from the fifth extract. A second evaporator removes a quantity of acid from the fifth extract in a vapor form. This vapor may be recycled to improve total acid recovery or discarded. A desalination device receives the diluted extract, separates out some of the acid and salt and outputs a desalinated solution.

  3. Materials needs and opportunities in the pulp and paper industry

    SciTech Connect (OSTI)

    Angelini, P.

    1995-08-01

    The Department of Energy`s (DOE) Office of Industrial Technologies (OIT) supports research and development (R&D) in industry, the DOE national laboratories, and in universities to develop energy efficient, environmentally-acceptable industrial technologies. The Office of Industrial Technologies is working with seven energy-intensive industries to develop R&D roadmaps that will facilitate cooperative government-industry efforts to achieve energy-efficient, environmentally-acceptable, sustainable industries of the future. The forest products industry is one of the industries with which OIT is working to develop an R&D roadmap. The Advanced Industrial Materials (AIM) Program of the Office of Industrial Technologies sponsors long-term, directed research on materials that will enable industry to develop and utilize more energy-efficient, sustainable processes and technologies. The purpose of the study described in this report was to identify the material R&D needs and opportunities for the pulp and paper mill of the future.

  4. SURFACE PREPARATION OF STEEL SUBSTRATES USING GRIT-BLASTING

    SciTech Connect (OSTI)

    Donna Post Guillen; D. J. Varacalle, Jr.; D. Deason; W. Rhodaberger; E. Sampson

    2005-05-01

    The primary purpose of grit blasting for thermal spray applications is to ensure a strong mechanical bond between the substrate and the coating by the enhanced roughening of the substrate material. This study presents statistically designed experiments that were accomplished to investigate the effect of abrasives on roughness for A36/1020 steel. The experiments were conducted using a Box statistical design of experiment (SDE) approach. Three grit blasting parameters and their effect on the resultant substrate roughness were investigated. These include blast media, blast pressure, and working distance. The substrates were characterized for roughness using surface profilometry. These attributes were correlated with the changes in operating parameters. Twin-Wire Electric Arc (TWEA) coatings of aluminum and zinc/aluminum were deposited on the grit-blasted substrates. These coatings were then tested for bond strength. Bond strength studies were conducted utilizing a portable adhesion tester following ASTM standard D4541.

  5. Recent improvements in casthouse practices at the Kwangyang blast furnaces

    SciTech Connect (OSTI)

    Jang, Y.S.; Han, K.W.; Kim, K.Y.; Cho, B.R.; Hur, N.S.

    1997-12-31

    POSCO`s Kwangyang blast furnaces have continuously carried out high production and low fuel operation under a high pulverized coal injection rate without complications since the Kwangyang No. 1 blast furnace was blown-in in 1987. The Kwangyang blast furnaces have focused on improving the work environment for the increase of competitive power in terms of increased production, cost savings, and management of optimum manpower through use of low cost fuel and raw material. At this time, the casthouse work lags behind most work in the blast furnace. Therefore, the Kwangyang blast furnaces have adopted a remote control system for the casthouse equipment to solve complications in the casthouse work due to high temperature and fumes. As the result, the casthouse workers can work in clean air and the number of workers has been reduced to 9.5 personnel per shift by reduction of the workload.

  6. LTC vacuum blasting maching (concrete): Baseline report: Greenbook (Chapter)

    SciTech Connect (OSTI)

    1997-07-31

    The LTC shot blast technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjuction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The LTC 1073 Vacuum Blasting Machine uses a high-capacity, direct-pressure blasting system which incorporates a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast. It incorporates a vacuum system which removes dust and debris from the surface as it is blasted. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure during maintenance activities was minimal, but due to mechanical difficulties dust monitoring could not be conducted during operation. Noise exposure was significant. Further testing for each of these exposures is recommended because of the outdoor environment where the testing demonstration took place. This may cause the results to be inaccurate. It is feasible that the dust and noise levels will be higher in an enclosed environment. In addition, other safety and health issues found were ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, and arm-hand vibration.

  7. Explosively driven air blast in a conical shock tube

    SciTech Connect (OSTI)

    Stewart, Joel B. Pecora, Collin

    2015-03-15

    Explosively driven shock tubes present challenges in terms of safety concerns and expensive upkeep of test facilities but provide more realistic approximations to the air blast resulting from free-field detonations than those provided by gas-driven shock tubes. Likewise, the geometry of conical shock tubes can naturally approximate a sector cut from a spherically symmetric blast, leading to a better agreement with the blast profiles of free-field detonations when compared to those provided by shock tubes employing constant cross sections. The work presented in this article documents the design, fabrication, and testing of an explosively driven conical shock tube whose goal was to closely replicate the blast profile seen from a larger, free-field detonation. By constraining the blast through a finite area, large blasts (which can add significant damage and safety constraints) can be simulated using smaller explosive charges. The experimental data presented herein show that a close approximation to the free-field air blast profile due to a 1.5 lb charge of C4 at 76 in. can be achieved by using a 0.032 lb charge in a 76-in.-long conical shock tube (which translates to an amplification factor of nearly 50). Modeling and simulation tools were used extensively in designing this shock tube to minimize expensive fabrication costs.

  8. Control of the Accumulation of Non-Process Elements in Pulp Mills with Bleach Filtrate Reuse: A Chemical Equilibrium Approach to Predicting the Partitioning of Metals in Pulp Mill and Bleach Plant Streams

    SciTech Connect (OSTI)

    Frederick, W.J. Jr.; Rudie, A.W.; Schmidl, G.W.; Sinquefield, S.A.; Rorrer, G.L.; Laver, M.L.; Yantasee, W.; Ming, D.

    2000-08-01

    The overall goal of this project was to develop fundamental, experimentally based methods for predicting the solubility or organic and inorganic matter and their interactions in recycled effluent from kraft pulp mills and bleach plants. This included: characterizing the capacity of wood pulp and dissolved organic matter to bind metal ions, developing a thermodynamic database of properties needed to describe the solubility of inorganic matter in pulp mill streams, incorporation of the database into equilibrium calculation software for predicting the solubility of the metals of interest, and evaluating its capability to predict the distribution of the metals between pulp fibers, inorganic precipitates, and solution.

  9. Producing a True Lignin Depolymerase for Biobleaching Softwood Kraft Pulp

    SciTech Connect (OSTI)

    Simo Sarkanen

    2002-02-04

    This project constituted an intensive effort devoted to producing, from the white-rot fungus Tramets Cingulata, a lignin degrading enzyme (lignin depolymerase) that is directly able to biobleach or delignify softwood kraft pulp brownstock. To this end, the solutions in which T. cingulata was grown contained dissolved kraft lignin which fulfilled two functions; it behaved as a lignin deploymerase substrate and it also appeared to act as an inducer of enzyme expression. However, the lignin depolymerase isoenzymes (and other extracellular T. cingulata enzymes) interacted very strongly with both the kraft lignin components and the fungal hypae, so the isolating these proteins from the culture solutions proved to be unexpectedly difficult. Even after extensive experimentation with a variety of protein purification techniques, only one approach appeared to be capable of purifying lignin depolymerases to homogeneity. Unfortunately the procedure was extremely laborious; it involved the iso electric focusing of concentrated buffer-exchanged culture solutions followed by electro-elution of the desired protein bands from the appropriate polyacrylamide gel segments

  10. Thermal reclamation of used blast grit. Technology spotlight report

    SciTech Connect (OSTI)

    1995-08-01

    Naval shipyards and other domestic port facilities generate thousands of tons of used blast grit annually. There are also thousands of steel bridges in the United States on a repaint schedule that requires grit blasting for surface preparation. All the used grit, along with the paint residue it contains, is currently disposed of in landfills. Cleaning and recycling used blast grit is an attractive alternative. Institute of Gas Technology (IGT) has developed a fluidized-bed sand calciner that is well suited for cleaning and recycling used blast grit. Essentially, IGT researchers applied a transfer/adaptation of fluidized-bed calcination originally developed for the reclamation of foundry sand. The calciner has a patented sloped-grid design that enhances the combustion of paint residues and promotes the isolation of reusable material.

  11. Pulverized coal injection operation on CSC No. 3 blast furnace

    SciTech Connect (OSTI)

    Chan, C.M.; Hsu, C.H.

    1996-12-31

    The pulverized coal injection system was introduced for the first time in No. 1 and No. 2 blast furnace at China Steel Corporation (CSC) in 1988. Currently the coal injection rate for both blast furnaces has steadily risen to 70--89 kg/thm (designed value). No 3 blast furnace (with an inner volume of 3400 m3) was also equipped with a PCI system of Armco type and started coal injection on November 17, 1993. During the early period, some problems such as injection lance blocking, lance-tip melting down, flexible hose wear, grind mill tripping occasionally interrupted the stable operation of blast furnace. After a series of efforts offered on equipment improvement and operation adjustment, the PC rate currently reaches to 90--110 kg/thm and furnace stable operation is still being maintained with productivity more than 2.20.

  12. Characterising the acceleration phase of blast wave formation

    SciTech Connect (OSTI)

    Fox, T. E. Pasley, J.; Robinson, A. P. L.; Schmitz, H.

    2014-10-15

    Intensely heated, localised regions in uniform fluids will rapidly expand and generate an outwardly propagating blast wave. The Sedov-Taylor self-similar solution for such blast waves has long been studied and applied to a variety of scenarios. A characteristic time for their formation has also long been identified using dimensional analysis, which by its very nature, can offer several interpretations. We propose that, rather than simply being a characteristic time, it may be interpreted as the definitive time taken for a blast wave resulting from an intense explosion in a uniform media to contain its maximum kinetic energy. A scaling relation for this measure of the acceleration phase, preceding the establishment of the blast wave, is presented and confirmed using a 1D planar hydrodynamic model.

  13. Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs Optimizing Blast Furnace Operation to Increase Efficiency and Lower Costs cfd_blastfurnace.pdf (552.85 KB) More Documents & Publications Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry ITP Energy Intensive Processes: Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry EA-1745: Finding of No Significant Impact

  14. Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation Citation Details In-Document Search Title: Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation The deployment and use of lithium-ion batteries in automotive and stationary energy storage applications must be optimized to justify their high up-front costs. Given that batteries degrade with use and storage, such optimizations must evaluate many years of operation. As the

  15. ChemCam is having a blast on Mars

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ChemCam Is Having A Blast On Mars Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue: September 1, 2016 all issues All Issues » submit ChemCam is having a blast on Mars Following the successful landing of the Mars rover Curiosity on August 5, Lab scientists and their French counterparts have already begun firing its onboard laser and collecting data. September 1, 2012 dummy image Read our archives Contacts Editor Linda Anderman Email

  16. Causes and solutions for cracking of coextruded and weld overlay floor tubes in black liquor recovery boilers

    SciTech Connect (OSTI)

    Keiser, J.R.; Taljat, B.; Wang, X.L.

    1998-09-01

    Cracking of coextruded, black liquor recovery boiler floor tubes is both a safety and an economic issue to mill operators. In an effort to determine the cause of the cracking and to identify a solution, extensive studies, described in this and three accompanying papers, are being conducted. In this paper, results of studies to characterize both the cracking and the chemical and thermal environment are reported. Based on the results described in this series of papers, a possible mechanism is presented and means to lessen the likelihood of cracking or to totally avoid cracking of floor tubes are offered.

  17. LTC 1073 vacuum blasting (concrete) human factors assessment -- Baseline (summary)

    SciTech Connect (OSTI)

    1997-07-31

    The LTC 1073 Vacuum Blasting Machine uses a high capacity, direct pressure blasting system incorporating a continuous feed for the blast media. The blast media cleans the surface within the contained brush area of the blast head. A vacuum system removes dust and debris from the surfaces as it is blasted. After cleaning the surface, the abrasive, together with the rust or coating that was removed from the surface, is vacuumed into the machine through the suction hose. The dust separator contains angled steel collision pads, working with the force of gravity, to allow any reusable abrasive to fall back into the pressure vessel. The filters are manually back flushed to prevent clogging. After back flushing, dust is dumped from the dust chamber into the dust collection bag or drum by operation of the bellows valve. The safety and health evaluation during the testing demonstration focused on dust and noise exposure. Dust exposure was found to be minimal, but noise exposure was potentially significant. Further testing for each of these exposures is recommended because the outdoor environment where the testing demonstration took place may cause the results to be inapplicable to indoor settings. It is feasible that the dust and noise levels will be higher in an enclosed operating environment. Other safety and health issues found were ergonomics, heat stress, tripping hazards, lockout/tagout, and arm-hand vibration.

  18. Overfilling of cavern blamed for LPG blasts

    SciTech Connect (OSTI)

    Not Available

    1992-07-06

    Three explosions and a fire Apr. 7 at an LPG salt dome storage cavern near Brenham, Tex., were triggered when the cavern was overfilled, the Texas Railroad Commission (TRC) has reported. This paper reports that a TRC investigation found that LPG escaped to the surface at the Brenham site through brine injection tubing after excessive fill from an LPG line forced the cavern's water level below the brine tubing's bottom. At the surface, LPG was released into a brine storage pit where it turned into a dense, explosive vapor. At 7:08 a.m., the vapor was ignited by an unknown source. The resulting blast killed three persons and injured 19 and brought operations at the site to a halt.

  19. Blast rips Texas LPG storage site

    SciTech Connect (OSTI)

    Not Available

    1992-04-13

    This paper reports that Seminole Pipeline Co. at presstime last week had planned to reopen its 775 mile liquefied petroleum gas pipeline in South Texas by Apr. 12 after a huge explosion devastated the area around a Seminole LPG storage salt dome near Brenham, Tex., forcing the pipeline shutdown. A large fire was still burning at the storage site at presstime last week. The blast - shortly after 7 a.m. Apr. 7 - occurred at a pipeline connecting the main Seminole line with the storage facility and caused shock waves felt 130 miles away. A 5 year old boy who lived in a trailer near Seminole's LPG storage dome was killed, and 20 persons were injured.

  20. Use of sinter in Taranto blast furnaces

    SciTech Connect (OSTI)

    Palchetti, M.; Palomba, R.; Tolino, E.; Salvatore, E.; Calcagni, M.

    1995-12-01

    Lowering the production cost of the crude steel is the ultimate aim when planning operations in an integrated steelworks. Designing the Blast Furnace burden is a crucial point in this context, for which account must be taken not only of the raw materials cost but also of other important aims such as maximum plants productivity, minimum possible energy consumption, a proper product quality at the various production stages. This paper describes the criteria used in Ilva Laminati Piani (ILP) Taranto Works to design the BF burden, based on sinter, using the results of extensive research activity carried out by Centro Sviluppo Materiali (CSM), the Research Center with major involvement with the R and D of the Italian Steel Industry. Great attention is paid at ILP to the sinter quality in order to obtain the optimum performance of the BFs, which are operating at high productivity, high pulverized coal rate and low fuel consumption.

  1. Overview of the government/industry workshop on opportunities for new materials in pulp and paper processing

    SciTech Connect (OSTI)

    Young, J.K.; Fowler, R.A.

    1994-05-01

    This report presents a synopsis of the presentations made at the two-day workshop conducted in Portland, Oregon, on August 12 and 13, 1993, for the Advanced Industrial Concepts division (AICD) of the US Department of Energy (DOE) Office of Industrial Technologies (OIT) and DOE national laboratory representatives from the pulp and paper industry. The information from the presentations is supplemented by additional statistics, as appropriate. The workshop objectives were (1) to develop a strategy and framework for collaboration between the pulp and paper industries and DOE`s national laboratories, (2) to identify major challenges to pulp and paper industry modernization, and (3) to identify research objectives for DOE national laboratories to improve materials and process technology in pulp and paper mills. Prior to the workshop, participants had the opportunity to tour paper mills and gain familiarity with pulp and paper processing methods. During the workshop, research needs for materials and processing that were identified at earlier AICD workshops were reviewed. Major problems of the pulp and paper industry were addressed, and ways in which DOE national laboratories are interacting with other industries to foster innovation and solve problems were presented. As a result of this and other workshops, a Pulp Paper Mill of the future strategy is being developed to address challenges identified in these proceedings. Continued efforts are expected by AICD to match candidate materials and processes from DOE national laboratories with the technology needs of pulp and paper mills.

  2. Unexpectedly, Navy?s Superlaser Blasts Away a Record (Wired) | Jefferson

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab Unexpectedly, Navy?s Superlaser Blasts Away a Record (Wired) External Link: http://www.wired.com/dangerroom/2011/02/unexpectedly-navys-superlaser-blasts-awa... By jlab_admin on Fri, 2011-02-18

  3. ENERGY EFFICIENCY OPPORTUNITIES IN THE U.S. PULP AND PAPER INDUSTRY

    SciTech Connect (OSTI)

    Kramer, Klaas Jan; Masanet, Eric; Worrell, Ernst

    2009-01-01

    The U.S. pulp and paper industry consumes over $7 billion worth of purchased fuels and electricity per year. Energy efficiency improvement is an important way to reduce these costs and to increase predictable earnings, especially in times of high energy price volatility. There are a variety of opportunities available at individual plants in the U.S. pulp and paper industry to reduce energy consumption in a cost-effective manner. This paper provides a brief overview of the U.S. EPA ENERGY STAR(R) for Industry energy efficiency guidebook (a.k.a. the"Energy Guide") for pulp and paper manufacturers. The Energy Guide discusses a wide range of energy efficiency practices and energy-efficient technologies that can be implemented at the component, process, facility, and organizational levels. Also provided is a discussion of the trends, structure, and energy consumption characteristics of the U.S. pulp and paper industry along with a description of the major process technologies used within the industry. Many energy efficiency measure descriptions include expected savings in energy and energy-related costs, based on case study data from real-world applications in pulp and paper mills and related industries worldwide. The information in this Energy Guide is intended to help energy and plant managers in the U.S. pulp and paper industry reduce energy consumption in a cost-effective manner while maintaining the quality of products manufactured. Further research on the economics of all measures?as well as on their applicability to different production practices?is needed to assess their cost effectiveness at individual plants.

  4. Controlled blasting and its implications for the NNWSI project exploratory shaft

    SciTech Connect (OSTI)

    Van Eeckhout, E.M.

    1987-09-01

    This report reviews controlled blasting techniques for shaft sinking. Presplitting and smooth blasting are the techniques of principal interest. Smooth blasting is preferred for the Nevada Nuclear Waste Storage Investigations exploratory shaft. Shaft damage can be monitored visually or by peak velocity measurements and refractive techniques. Damage into the rock should be limited to 3 ft. 40 refs., 22 figs., 7 tabs.

  5. Modelling of multiphase flow in ironmaking blast furnace

    SciTech Connect (OSTI)

    Dong, X.F.; Yu, A.B.; Burgess, J.M.; Pinson, D.; Chew, S.; Zulli, P.

    2009-01-15

    A mathematical model for the four-phase (gas, powder, liquid, and solids) flow in a two-dimensional ironmaking blast furnace is presented by extending the existing two-fluid flow models. The model describes the motion of gas, solid, and powder phases, based on the continuum approach, and implements the so-called force balance model for the flow of liquids, such as metal and slag in a blast furnace. The model results demonstrate a solid stagnant zone and dense powder hold-up region, as well as a dense liquid flow region that exists in the lower part of a blast furnace, which are consistent with the experimental observations reported in the literature. The simulation is extended to investigate the effects of packing properties and operational conditions on the flow and the volume fraction distribution of each phase in a blast furnace. It is found that solid movement has a significant effect on powder holdup distribution. Small solid particles and low porosity distribution are predicted to affect the fluid flow considerably, and this can cause deterioration in bed permeability. The dynamic powder holdup in a furnace increases significantly with the increase of powder diameter. The findings should be useful to better understand and control blast furnace operations.

  6. No. 5 blast furnace 1995 reline and upgrade

    SciTech Connect (OSTI)

    Kakascik, T.F. Jr.

    1996-12-31

    The 1995 reline of No. 5 Blast Furnace is an undertaking which has never been approached in previous relines of any blast furnace in the history of Wheeling Pittsburgh Steel Corporation. The scope of the project is such that it represents a radical departure from W.P.S.C.`s traditional methods of ironmaking. The reline of No. 5 Blast Furnace is one of the largest capital improvements performed at W.P.S.C. Blast Furnaces. The improvements made at one single time are taking a furnace from 1960`s technology into the 21st century. With this in mind, employee training was one of the largest parts of the project. Training for the automated stockhouse, castfloor, new skip drive, new instrumentation, new castfloor equipment, hydraulics and overall furnace operation were an absolute necessity. The reline has laid the ground work to give the Corporation an efficient, higher productive, modern Blast Furnace which will place W.P.S.C. in the world class category in ironmaking well into the 21st century.

  7. Operating experience with 100% pellet burden on Amanda blast furnace

    SciTech Connect (OSTI)

    Keaton, D.E.; Minakawa, T. . Ironmaking Dept.)

    1993-01-01

    A number of significant changes in operations at the Ashland Works of the Armco Steel Company occurred in 1992 which directly impacted the Amanda Blast Furnace operation. These changes included the shutdown of the hot strip mill which resulted in coke oven gas enrichment of the Amanda stoves and an increase of 75 C in hot blast temperature, transition to 100% continuous cast operation which resulted in increased variation of the hot metal demand, and the July idling of the sinter plant. Historically, the Amanda Blast Furnace burden was 30% fluxed sinter and 70% acid pellet. It was anticipated that the change to 100% pellet burden would require changes in charging practice and alter furnace performance. The paper gives a general furnace description and then describes the burden characteristics, operating practice with 30% sinter/70% acid pellet burden, preparations for the 100% acid pellet burden operation, the 100% acid pellet operation, and the 100% fluxed pellet burden operation.

  8. Modeling and Simulating Blast Effects on Electric Substations

    SciTech Connect (OSTI)

    Lyle G. Roybal; Robert F. Jeffers; Kent E. McGillivary; Tony D. Paul; Ryan Jacobson

    2009-05-01

    A software simulation tool was developed at the Idaho National Laboratory to estimate the fragility of electric substation components subject to an explosive blast. Damage caused by explosively driven fragments on a generic electric substation was estimated by using a ray-tracing technique to track and tabulate fragment impacts and penetrations of substation components. This technique is based on methods used for assessing vulnerability of military aircraft and ground vehicles to explosive blasts. An open-source rendering and ray-trace engine was used for geometric modeling and interactions between fragments and substation components. Semi-empirical material interactions models were used to calculate blast parameters and simulate high-velocity material interactions between explosively driven fragments and substation components. Finally, a Monte Carlo simulation was added to model the random nature of fragment generation allowing a skilled analyst to predict failure probabilities of substation components.

  9. Surface preparation via grit-blasting for thermal spraying

    SciTech Connect (OSTI)

    Varacalle, D.J. Jr.; Lundberg, L.B.; Hartley, R.S.

    1995-11-01

    The major reason for grit blasting for thermal spray applications is to ensure a strong mechanical bond between the substrate and the coating by the enhanced roughening of the substrate material. This study presents five statistically designed experiments that were accomplished to investigate the grit blasting process. The experiments were conducted using a Box statistical design of experiment (SDE) approach. A substantial range of grit blasting parameters and their effect on the resultant substrate roughness were investigated, including grit type, pressure, working distance, and exposure time. The substrates were characterized for surface characteristics using image analysis. These attributes are correlated with the changes in operating parameters. Optimized process parameters for the two machines used in this study as predicted by the SDE analysis are presented.

  10. Selective enrichment of a methanol-utilizing consortium using pulp & paper mill waste streams

    SciTech Connect (OSTI)

    Gregory R. Mockos; William A. Smith; Frank J. Loge; David N. Thompson

    2007-04-01

    Efficient utilization of carbon inputs is critical to the economic viability of the current forest products sector. Input carbon losses occur in various locations within a pulp mill, including losses as volatile organics and wastewater . Opportunities exist to capture this carbon in the form of value-added products such as biodegradable polymers. Waste activated sludge from a pulp mill wastewater facility was enriched for 80 days for a methanol-utilizing consortium with the goal of using this consortium to produce biopolymers from methanol-rich pulp mill waste streams. Five enrichment conditions were utilized: three high-methanol streams from the kraft mill foul condensate system, one methanol-amended stream from the mill wastewater plant, and one methanol-only enrichment. Enrichment reactors were operated aerobically in sequencing batch mode at neutral pH and 25°C with a hydraulic residence time and a solids retention time of four days. Non-enriched waste activated sludge did not consume methanol or reduce chemical oxygen demand. With enrichment, however, the chemical oxygen demand reduction over 24 hour feed/decant cycles ranged from 79 to 89 %, and methanol concentrations dropped below method detection limits. Neither the non-enriched waste activated sludge nor any of the enrichment cultures accumulated polyhydroxyalkanoates (PHAs) under conditions of nitrogen sufficiency. Similarly, the non-enriched waste activated sludge did not accumulate PHAs under nitrogen limited conditions. By contrast, enriched cultures accumulated PHAs to nearly 14% on a dry weight basis under nitrogen limited conditions. This indicates that selectively-enriched pulp mill waste activated sludge can serve as an inoculum for PHA production from methanol-rich pulp mill effluents.

  11. Improvement of tap holes at Wakayama No. 5 blast furnace

    SciTech Connect (OSTI)

    Yamashita, M.; Kashiwada, M.; Shibuta, H.

    1995-12-01

    The service life of blast furnaces, as the result of various improvement measures, has been extended from the conventional 5 to 7 years to 15 to 20 years. Wakayama No. 5 blast furnace adopted SiC bricks. Though SiC brick excelled in strength and durability, it has raised problems such as tap hole inside temperature lowering attributable to its high thermal conductivity, insufficient mud burning and gas blow-out. Nevertheless, various countermeasures described within have been taken against such problems, and as the result it has now become possible to maintain tap holes in stable conditions.

  12. Production of ammonium sulfate fertilizer from FGD waste liquors. Quarterly technical report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Randolph, A.D.; Mukhopadhyay, S.; Unrau, E.

    1994-12-31

    During this quarterly period, an experimental investigation was performed to study the precipitation kinetics and hydrolysis characteristics of calcium imido disulfonate crystals (CaADS). The CaADS crystals were precipitated by a metathetical reaction of lime, supplied by Dravo Lime Co., with flue gas desulfurization (FGD) scrubber waste liquor. Before approaching for the continuous Double Draw-Off (DDO) crystallization studies, the influence of a Dravo lime slurry on the precipitation characteristics of N-S compounds will be established. A series of N-S compound batch crystallization studies were completed in a wide range of pH (7.0--9.0), and the influence of pH on the amount of lime required, as well as the amount of precipitate obtained, was investigated. Although the amount of precipitate increased with increase in solution pH, the safe or optimum pH for the precipitation of CaADS lies in the vicinity of 8.2 to 8.3. For studying the crystallization characteristics of CaADS crystals, a bench scale 7.0 liter DDO crystallizer was built. DDO crystallizer is found to be superior compared to Mixed Suspension Mixed Product Removal (MSMPR) crystallizer. The precipitated crystals were analyzed for elemental composition by chemical analysis. The crystals were also examined under optical microscope for their morphological features. The present studies confirmed our prediction that N-S compounds in the waste liquor can be precipitated by a reaction with lime slurry. The precipitated crystals were mostly calcium imido disulfonate.

  13. Regeneration of FGD waste liquors: Production of ammonium and potassium sulfate mixed fertilizer. Quarterly technical report, April 1993--June 1993

    SciTech Connect (OSTI)

    Randolph, A.D.; Kwon, T.M.

    1993-12-01

    Precipitation and hydrolysis of the N-S compounds in the waste scrubbing liquor provided by Dravo Lime Co. was investigated. Precipitation of N-S compounds by a metathetical reaction with potassium sulfate was performed in continuous crystallizers. A preliminary operation showed that compared to a typical Mixed-Suspension-Mixed-Product-Removal (MSMPR) crystallizer, the Double-Draw-Off (DDO) crystallizer was superior by increasing the average size of the precipitated crystals of N-S compounds from 173 {mu}m to 218 {mu}m. However, the hydrolysis characteristics of the precipitated crystals were not dependent upon crystallizer type. A brief description of a new process which uses lime/limestone for precipitation of N-S compounds in the scrubbing liquor is presented. Preliminary investigations showed the lime/limestone process is efficient in precipitating N-S compounds and the precipitated crystals were shown to be more easily hydrolyzed than potassium salts of N-S compounds. This lime/limestone process is a novel process which seems better than the K{sub 2}SO{sub 4} process because one does not need to purchase/introduce a new chemical additive to precipitate in the lime/limestone Fe-EDTA wet scrubbing processes. Up to the present, the authors focused on developing the K{sub 2}SO{sub 4} process following their original proposal. However, the new lime/limestone process seems more advantageous in terms of economy and environmental safety. Therefore, it seems desirable changing research phase and putting an emphasis on the development of the lime/limestone process. Future study will include investigation of the DDO crystallizer operation to increase the size of precipitated crystals and thus to enhance their processibility. This study seems to be essential to the new lime/limestone process since the precipitated crystals are relatively small in size and thus poor in filterability.

  14. Hot repair of ceramic burner on hot blast stoves at USS/Kobe`s {number_sign}3 blast furnace

    SciTech Connect (OSTI)

    Bernarding, T.F.; Chemorov, M.; Shimono, S.; Phillips, G.R.

    1997-12-31

    During the 1992 reline of the No. 3 blast furnace, three new stoves were constructed. The design of the stoves, equipped with internal ceramic burners, was for providing a hot blast temperature of 2,000 F at a wind rate of 140,000 SCFM. After 3 years the performance had deteriorated so the burners were cleaned. When a second cleaning did not improve the performance of No. 3 blast furnace, it was decided to repair the refractory while still hot. The paper describes the hot repair procedures, taking a stove off for repairs, maintenance heat up during repairs, two stove operation, stove commissioning, repair of a ceramic burner, and wet gas prevention.

  15. Steam system opportunity assessment for the pulp and paper, chemical manufacturing, and petroleum refining industries: Main report

    SciTech Connect (OSTI)

    None, None

    2002-10-01

    This report assesses steam generation and use in the pulp and paper, chemical, and petroleum refining industries, and estimates the potential for energy savings from implementation of steam system performance and efficiency improvements.

  16. Effect of Grit Blasting on Substrate Roughness and Coating Adhesion

    SciTech Connect (OSTI)

    Dominic Varacalle; Donna Guillen; Doug Deason; William Rhodaberger; Elliott Sampson

    2006-09-01

    Statistically designed experiments were performed to compare the surface roughnesses produced by grit blasting A36/1020 steel with different abrasives. Grit blast media, blast pressure, and working distance were varied using a Box-type statistical design of experiment (SDE) approach. The surface textures produced by four metal grits (HG16, HG18, HG25, and HG40) and three conventional grits (copper slag, coal slag, and chilled iron) were compared. Substrate roughness was measured using surface profilometry and correlated with operating parameters. The HG16 grit produced the highest surface roughness of all the grits tested. Aluminum and zinc-aluminum coatings were deposited on the grit-blasted substrates using a Twin-Wire Electric Arc (TWEA) process. Bond strength of the coatings was measured with a portable adhesion tester in accordance with ASTM standard D4541. The coatings on substrates roughened with steel grit exhibit superior bond strength to those on substrates prepared with conventional grit. For aluminum coatings sprayed onto surfaces prepared with the HG16 grit, the bond strength was most influenced by current, spray distance, and spray gun pressure (in that order). The highest bond strength for the zinc-aluminum coatings was attained on surfaces prepared using the metal grits.

  17. Assessment, development, and testing of glass for blast environments.

    SciTech Connect (OSTI)

    Glass, Sarah Jill

    2003-06-01

    Glass can have lethal effects including fatalities and injuries when it breaks and then flies through the air under blast loading (''the glass problem''). One goal of this program was to assess the glass problem and solutions being pursued to mitigate it. One solution to the problem is the development of new glass technology that allows the strength and fragmentation to be controlled or selected depending on the blast performance specifications. For example the glass could be weak and fail, or it could be strong and survive, but it must perform reliably. Also, once it fails it should produce fragments of a controlled size. Under certain circumstances it may be beneficial to have very small fragments, in others it may be beneficial to have large fragments that stay together. The second goal of this program was to evaluate the performance (strength, reliability, and fragmentation) of Engineered Stress Profile (ESP) glass under different loading conditions. These included pseudo-static strength and pressure tests and free-field blast tests. The ultimate goal was to provide engineers and architects with a glass whose behavior under blast loading is less lethal. A near-term benefit is a new approach for improving the reliability of glass and modifying its fracture behavior.

  18. Columbia River Channel Improvement Project Rock Removal Blasting: Monitoring Plan

    SciTech Connect (OSTI)

    Carlson, Thomas J.; Johnson, Gary E.

    2010-01-29

    This document provides a monitoring plan to evaluate take as outlined in the National Marine Fisheries Service 2002 Biological Opinion for underwater blasting to remove rock from the navigation channel for the Columbia River Channel Improvement Project. The plan was prepared by the Pacific Northwest National Laboratory (PNNL) for the U.S. Army Corps of Engineers (USACE), Portland District.

  19. Coal combustion under conditions of blast furnace injection

    SciTech Connect (OSTI)

    Crelling, J.C.

    1995-12-01

    Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal with particular reference to the coals from the Illinois Basin. Although this research is not yet completed the results to date support the following conclusions: (1) based on the results of computer modeling, lower rank bituminous coals, including coal from the Illinois Basin, compare well in their injection properties with a variety of other bituminous coals, although the replacement ratio improves with increasing rank; (2) based on the results of petrographic analysis of material collected from an active blast furnace, it is clear the coal derived char is entering into the raceway of the blast furnace; (3) the results of reactivity experiments on a variety of coal chars at a variety of reaction temperatures show that lower rank bituminous coals, including coal from the Illinois basin, yield chars with significantly higher reactivities in both air and CO{sub 2} than chars from higher rank Appalachian coals and blast furnace coke. These results indicate that the chars from the lower rank coals should have a superior burnout rate in the tuyere and should survive in the raceway environment for a shorter time. These coals, therefore, will have important advantages at high rates of injection that may overcome their slightly lower replacement rates.

  20. On-line measurement of lignin in wood pulp by color shift of fluorescence

    SciTech Connect (OSTI)

    Jeffers, Larry A.; Malito, Michael L.

    1996-01-01

    Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroid method or a band ratio method.

  1. On-line measurement of lignin in wood pulp by color shift of fluorescence

    DOE Patents [OSTI]

    Jeffers, L.A.; Malito, M.L.

    1996-01-23

    Lignin concentrations from wood pulp samples are measured by applying an excitation light at a selected wavelength to the samples in order to cause the lignin to emit fluorescence. A spectral distribution of the fluorescence emission is then determined. The lignin concentration is then calculated based on the spectral distribution signal. The spectral distribution is quantified by either a wavelength centroid method or a band ratio method. 6 figs.

  2. Minimization of Blast furnace Fuel Rate by Optimizing Burden and Gas Distribution

    SciTech Connect (OSTI)

    Dr. Chenn Zhou

    2012-08-15

    The goal of the research is to improve the competitive edge of steel mills by using the advanced CFD technology to optimize the gas and burden distributions inside a blast furnace for achieving the best gas utilization. A state-of-the-art 3-D CFD model has been developed for simulating the gas distribution inside a blast furnace at given burden conditions, burden distribution and blast parameters. The comprehensive 3-D CFD model has been validated by plant measurement data from an actual blast furnace. Validation of the sub-models is also achieved. The user friendly software package named Blast Furnace Shaft Simulator (BFSS) has been developed to simulate the blast furnace shaft process. The research has significant benefits to the steel industry with high productivity, low energy consumption, and improved environment.

  3. Recycling of water in bleached kraft pulp mills by using electrodialysis.

    SciTech Connect (OSTI)

    Fracaro, A. T.; Henry, M. P.; Pfromm, P.; Tsai, S.-P.

    1999-01-15

    Conservation of water in bleached kraft pulp mills by recycling the bleach plant effluent directly without treatment will cause accumulation of inorganic ''non-process elements'' (NPEs) and serious operational problems. In this work, an electrodialysis process is being developed for recycling the acidic bleach plant effluent of bleached kraft pulp mills. In this process, electrodialysis functions as a selective kidney to remove inorganic NPEs from bleach plant effluents, before they reach the recovery cycle. Acidic bleach plant effluents from several mills using bleaching sequences based on chlorine dioxide were characterized. The total dissolved solids were mostly inorganic NPEs. Sodium was the predominant cation and chloride was present at significant levels in all these effluents. In laboratory electrodialysis experiments, selective removal of chloride and potentially harmful cations, such as potassium, calcium, and magnesium, were removed efficiently. Rejection of organic compounds was up to 98%. Electrodialysis was shown to be resistant to membrane fouling and scaling, in a 100-hour laboratory experiment. Based on a model mill with 1,000 ton/day pulp production, the economic analysis suggests that the energy cost of electrodialysis is less than $200/day, and the capital cost of the stack is about $500,000.

  4. Evaluation of heat flux through blast furnace shell with attached sensors

    SciTech Connect (OSTI)

    Han, J.W.; Lee, J.H.; Suh, Y.K.

    1996-12-31

    Plant trials to evaluate heat fluxes through a lining/cooling system of a blast furnace were conducted in order to realize the cooling efficiency of the blast furnace under operation. For this purpose, several experiments to measure the in-furnace gas temperatures were cautiously made, and numerical simulations for the temperature distributions over the blast furnace shell and cooling/lining systems were also carried out.

  5. Blast furnace injection of massive quantities of coal with enriched air or pure oxygen

    SciTech Connect (OSTI)

    Ponghis, N.; Dufresne, P.; Vidal, R.; Poos, A. )

    1993-01-01

    An extensive study of the phenomena associated with the blast furnace injection of massive quantities of coal is described. Trials with conventional lances or oxy-coal injectors and hot blast at different oxygen contents - up to 40% - or with cold pure oxygen were realized at coal to oxygen ratios corresponding to a range of 150 to 440 kg. Pilot scale rigs, empty or filled with coke, as well as industrial blast furnaces were utilized.

  6. Minimization of Blast Furnace Fuel Rate by Optimizing Burden and Gas Distributions

    SciTech Connect (OSTI)

    2007-08-01

    This factsheet describes a research project whose proposed CFD model will focus on the complex physics and chemistry found within the upper part of the blast furnace.

  7. " Row: Selected SIC Codes; Column: Energy Sources;"

    U.S. Energy Information Administration (EIA) Indexed Site

    S5.1. Selected Byproducts in Fuel Consumption, 1998;" " Level: National Data; " " Row: Selected SIC Codes; Column: Energy Sources;" " Unit: Trillion Btu." " "," "," "," "," "," "," "," ","Waste"," ",," " " "," "," ","Blast"," "," ","Pulping Liquor","

  8. Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Relative Standard Errors for Table 3.5;" " Unit: Percents." ,,,,,,,,"Waste",," " ,,,"Blast",,,"Pulping Liquor",,"Oils/Tars" "NAICS",,,"Furnace/Coke",,"Petroleum","or","Wood Chips,","and Waste" "Code(a)","Subsector and Industry","Total","Oven Gases","Waste Gas","Coke","Black

  9. Released: March 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Selected Byproducts in Fuel Consumption, 2010;" " Level: National and Regional Data; " " Row: NAICS Codes; Column: Energy Sources;" " Unit: Trillion Btu." " "," "," "," "," "," "," "," ","Waste" " "," "," ","Blast"," "," ","Pulping Liquor"," ","Oils/Tars" "NAICS","

  10. Hot metal Si control at Kwangyang blast furnaces

    SciTech Connect (OSTI)

    Hur, N.S.; Cho, B.R.; Kim, G.Y.; Choi, J.S.; Kim, B.H.

    1995-12-01

    Studies of Si transfer in blast furnaces have shown that the Si level in pig iron is influenced more by the reaction of silicon oxide gas generation in the raceway than the chemical reaction between hot metal and slag at the drop zone. Specifications require a Si content of pig iron below 0.15% at the Kwangyang Works, but the use of soft coking coal in the blend for coke ovens, high pulverized coal injection rate into the blast furnace, and the application of lower grade iron ore has resulted in the need to develop methods to control Si in hot metal. In this paper, the results of in furnace Si control and the desiliconization skills at the casthouse floor are described.

  11. An update on blast furnace granular coal injection

    SciTech Connect (OSTI)

    Hill, D.G.; Strayer, T.J.; Bouman, R.W.

    1997-12-31

    A blast furnace coal injection system has been constructed and is being used on the furnace at the Burns Harbor Division of Bethlehem Steel. The injection system was designed to deliver both granular (coarse) and pulverized (fine) coal. Construction was completed on schedule in early 1995. Coal injection rates on the two Burns Harbor furnaces were increased throughout 1995 and was over 200 lbs/ton on C furnace in September. The injection rate on C furnace reached 270 lbs/ton by mid-1996. A comparison of high volatile and low volatile coals as injectants shows that low volatile coal replaces more coke and results in a better blast furnace operation. The replacement ratio with low volatile coal is 0.96 lbs coke per pound of coal. A major conclusion of the work to date is that granular coal injection performs very well in large blast furnaces. Future testing will include a processed sub-bituminous coal, a high ash coal and a direct comparison of granular versus pulverized coal injection.

  12. RESONANT AMPLIFICATION OF TURBULENCE BY THE BLAST WAVES

    SciTech Connect (OSTI)

    Zankovich, A. M.; Kovalenko, I. G.

    2015-02-10

    We discuss the idea of whether spherical blast waves can amplify by a nonlocal resonant hydrodynamic mechanism inhomogeneities formed by turbulence or phase segregation in the interstellar medium. We consider the problem of a blast-wave-turbulence interaction in the Linear Interaction Approximation. Mathematically, this is an eigenvalue problem for finding the structure and amplitude of eigenfunctions describing the response of the shock-wave flow to forced oscillations by external perturbations in the ambient interstellar medium. Linear analysis shows that the blast wave can amplify density and vorticity perturbations for a wide range of length scales with amplification coefficients of up to 20, with increasing amplification the larger the length. There also exist resonant harmonics for which the gain becomes formally infinite in the linear approximation. Their orbital wavenumbers are within the range of macro- (l ∼ 1), meso- (l ∼ 20), and microscopic (l > 200) scales. Since the resonance width is narrow (typically, Δl < 1), resonance should select and amplify discrete isolated harmonics. We speculate on a possible explanation of an observed regular filamentary structure of regularly shaped round supernova remnants such as SNR 1572, 1006, or 0509-67.5. Resonant mesoscales found (l ≈ 18) are surprisingly close to the observed scales (l ≈ 15) of ripples in the shell's surface of SNR 0509-67.5.

  13. Treatment studies of paint stripping waste from plastic media blasting

    SciTech Connect (OSTI)

    Spence, R.D.

    1995-12-31

    Blasting with plastic media is used to strip paint and decontaminate surfaces. For disposal the plastic media is pulverized into a plastic dust. About 10 wt % of the waste from plastic media blasting is pulverized paint, which makes the waste a characteristically hazardous waste because of the presence of barium, cadmium, chromium and lead in the paint pigments. Four separate treatments of this hazardous waste were studied: (1) density separation to remove the paint, (2) self-encapsulation of the mix of plastic and paint dust into plastic pellets, (3) solidification/stabilization (S/S) into cementitious waste forms, and (4) low-temperature ashing to destroy the large mass of nonhazardous polymer. Two types of plast blasting wastes were studied: a urea formaldehyde thermoset polymer and an acrylic thermoplastic polymer (polymethylmethacrylate). Toxicity Characteristic Leach Procedure (TCLP) extraction concentrations for the treated and untreated wastes are listed. Density separation failed to adequately separate the paint with an aqueous carbonate solution. Self-encapsulation reduced the waste volume by about 50%, but did not meet TCLP criteria. Cementitious solidification gave the lowest TCLP concentrations, but increased the waste volume by about 50%. Low-temperature ashing at 600 C resulted in a mass decrease of 93 to 98% for the wastes; the metals remaining in the ash could be stabilized with cementitious solidification and still result in a volume decrease of 75 to 95 volume percent.

  14. Raceway behaviors in blast furnace with pulverized coal injection

    SciTech Connect (OSTI)

    Chung, J.K.; Han, J.W.; Cho, B.R.

    1995-12-01

    The blast furnace raceway shows different characteristics with PCR (pulverized coal injection rate). It was found in this study that with the increase of PCR the raceway depth decreases, and the size of birds nest and sometimes with liquid holdup, increases. Oxygen enrichment with co-axial lances was known to be very effective on the extension of raceway depth and size reduction of birds nest. It was also found that there are various factors which affect the coke properties at tuyere level of the blast furnace. Coke traveling time was calculated to be extended with PCR and it had a close relationship with the coke size in bosh. Coke mean size decreased with the increase of coke traveling time, that is, with the increase of PCR. Both DI (the strength of coke in cold) and CSR (the strength of coke after reaction) were also decreased with PCR. RAFT (Raceway Adiabatic Flame Temperature) had a tendency to be decreased with the increase of PCR, which is obtained by the estimation of coke temperature via XRD analysis. From the analysis of alkali contents in coke sampled along the radius of the blast furnace, it was understood that no difference in alkali contents between fine and lump coke represents that coke fines generated from upper burden might appear at tuyere level.

  15. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  16. A New Freeze Concentration Process for Minimum Effluent Process in Bleached Pulp

    SciTech Connect (OSTI)

    Qian, Ru-Ying; Botsaris, Gregory D.

    2001-03-06

    This project researches freeze concentration as a primary volume reduction technology for bleaching plant effluents from paper-pulp mills before they are treated by expensive technologies, such as incineration, for the destruction of the adsorbable organic halogens. Previous laboratory studies show that freeze concentration has a greater than 99.5% purification efficiency for volatile, semivolatile, and nonprocess elements, or any other solute, thus producing pure ice that can be reused in the mill as water. The first section evaluates the anticipated regulatory and public pressures associated with implementing the technology; the remaining sections deal with the experimental results from a scaled-up freeze concentration process in a 100-liter pilot-plant at Tufts University. The results of laboratory scale experiments confirmed that the freeze concentration technology could be an efficient volume reduction technology for the above elements and for removing adsorbable organic hologens and or nonprocess elements from recycled water. They also provide the necessary data for designing and operating a larger pilot plant, and identify the technical problems encountered in the scale-up and the way they could be addressed in the larger scale plants. This project was originally planned to include the operation of a large pilot plant in the facilities of Swenson Process Equipment Inc., and a field test at a pulp mill, but the paper company withdrew its financial support for the field test. In place of a final economic evaluation after the field test, a preliminary evaluation based on the small pilot plant data predicts an economically reasonable freeze concentration process in the case of reduction of the bleaching-effluent flow to less than 5 m3/kkg pulp, a target anticipated in the near future.

  17. Histone deacetylase inhibitors epigenetically promote reparative events in primary dental pulp cells

    SciTech Connect (OSTI)

    Duncan, Henry F.; Smith, Anthony J.; Fleming, Garry J.P.; Cooper, Paul R.

    2013-06-10

    Application of histone deacetylase inhibitors (HDACi) to cells epigenetically alters their chromatin structure and induces transcriptional and cellular reparative events. This study investigated the application of two HDACi, valproic acid (VPA) and trichostatin A (TSA) on the induction of repair-associated responses in primary dental pulp cell (DPC) cultures. Flow cytometry demonstrated that TSA (100 nM, 400 nM) significantly increased cell viability. Neither HDACi was cytotoxic, although cell growth analysis revealed significant anti-proliferative effects at higher concentrations for VPA (>0.5 mM) and TSA (>50 nM). While high-content-analysis demonstrated that HDACi did not significantly induce caspase-3 or p21 activity, p53-expression was increased by VPA (3 mM, 5 mM) at 48 h. HDACi-exposure induced mineralization per cell dose-dependently to a plateau level (VPA-0.125 mM and TSA-25 nM) with accompanying increases in mineralization/dentinogenic-associated gene expression at 5 days (DMP-1, BMP-2/-4, Nestin) and 10 days (DSPP, BMP-2/-4). Both HDACis, at a range of concentrations, significantly stimulated osteopontin and BMP-2 protein expression at 10 and 14 days further supporting the ability of HDACi to promote differentiation. HDACi exert different effects on primary compared with transformed DPCs and promote mineralization and differentiation events without cytotoxic effects. These novel data now highlight the potential in restorative dentistry for applying low concentrations of HDACi in vital pulp treatment. -- Highlights: • Valproic acid and trichostatin A promoted mineralization in primary pulp cells. • Cell viability, apoptosis, caspase-3, p21 unaltered; p53 increased by valproic acid. • Trichostatin A increased cell viability at 24 h at selected concentrations. • Altered cell toxicity and differentiation between primary and transformed cells. • HDACi-induced the differentiation marker proteins osteopontin and BMP-2.

  18. Development and pilot testing of modular dynamic thermomechanical pulp mill model to develop energy reduction strategies. Final report

    SciTech Connect (OSTI)

    Coffin, D.W.

    1996-10-01

    With the development of on-line and real-time process simulations, one obtains the ability to predict and control the process; thus, the opportunity exists to improve energy efficiency, decrease materials wastes, and maintain product quality. Developing this capability was the objective of the this research program. A thermomechanical pulp mill was simulated using both a first principles model and a neural network. The models made use of actual process data and a model that calculated the mass and energy balance of the mill was successfully implemented and run at the mill on an hourly basis. The attempt to develop a model that accurately predicted the quality of the pulp was not successful. It was concluded that the key fro a successful implementation of a real-time control model, such as a neural net model, is availability of on-line sensors that sufficiently characterize the pulp.

  19. Yield Improvement and Energy Savings Uing Phosphonates as Additives in Kraft pulping

    SciTech Connect (OSTI)

    Ulrike W. Tschirner; Timothy Smith

    2007-03-31

    Project Objective: Develop a commercially viable modification to the Kraft process resulting in energy savings, increased yield and improved bleachability. Evaluate the feasibility of this technology across a spectrum of wood species used in North America. Develop detailed fundamental understanding of the mechanism by which phosphonates improve KAPPA number and yield. Evaluate the North American market potential for the use of phosphonates in the Kraft pulping process. Examine determinants of customer perceived value and explore organizational and operational factors influencing attitudes and behaviors. Provide an economic feasibility assessment for the supply chain, both suppliers (chemical supply companies) and buyers (Kraft mills). Provide background to most effectively transfer this new technology to commercial mills.

  20. Pulp and paper mill of the future: A workshop. Final report

    SciTech Connect (OSTI)

    Fleischman, E.; Sobczynski, S.F.

    1993-10-01

    This workshop began with sessions to consider where the industry is likely to be, or ideally where it should be, say, by the year 2020. The next sessions considered the `drivers` that motivate the industry to change. These drivers could be motivations towards the vision developed earlier, or they may be forces that tend to prevent the vision of the future form being realized. The final sessions focused on what techniques are being (or should be) developed in four major process areas of a typical manufacturing plant, consistent with the previously identified vision of a future pulp or paper mill.

  1. Magmatic model for the Mount St. Helens blast of May 18, 1980

    SciTech Connect (OSTI)

    Eichelberger, J.C.; Hayes, D.B.

    1982-09-10

    Analytical and numerical solutions to the hydrodynamic equations of motion, constrained by physical properties of juvenile ejecta in the Mount St. Helens blast deposit, were used to investigate magmatic conditions required to produce the initial devastating blast phase of the eruption of May 18, 1980. Evidence that the blast was magmatic includes equivalence in volume of juvenile blast ejecta to preeruption inflation of the cone, substantial vesicularity of this ejecta, and continued vesiculation of large juvenile clasts after eruption. Observed or inferred ejecta velocities of 100 to 250 m/s are shown to require 0.2 to 0.7 wt% water vapor preexisting in magma unloaded by a landslide 200 to 900 m thick. These conditions imply total magmatic water contents of 0.7 to 1.7 wt%, respectively. Such low required water content suggests that volcanic blasts may be regarded as a normal consequence of magma intrusion into an unstable edifice.

  2. Remote operated vehicle with carbon dioxide blasting (ROVCO{sub 2})

    SciTech Connect (OSTI)

    Resnick, A.M.

    1995-10-01

    The Remote Operated Vehicle with Carbon Dioxide Blasting (ROVCO{sub 2}), as shown in a front view is a six-wheeled remote land vehicle used to decontaminate concrete floors. The remote vehicle has a high pressure Cryogenesis blasting subsystem, Oceaneering Technologies (OTECH) developed a CO{sub 2} xY Orthogonal Translational End Effector (COYOTEE) subsystem, and a vacuum/filtration and containment subsystem. The cryogenesis subsystem performs the actual decontamination work and consists of the dry ice supply unit, the blasting nozzle, the remotely controlled electric and pneumatic valves, and the vacuum work-head. The COYOTEE subsystem positions the blasting work-head within a planar work space and the vacuum subsystem provides filtration and containment of the debris generated by the CO{sub 2} blasting. It employs a High Efficiency Particulate Air (HEPA) filtration unit to separate contaminants for disposal. All of the above systems are attached to the vehicle subsystem via the support structure.

  3. Use of Residual Solids from Pulp and Paper Mills for Enhancing Strength and Durability of Ready-Mixed Concrete

    SciTech Connect (OSTI)

    Tarun R. Naik; Yoon-moon Chun; Rudolph N. Kraus

    2003-09-18

    This research was conducted to establish mixture proportioning and production technologies for ready-mixed concrete containing pulp and paper mill residual solids and to study technical, economical, and performance benefits of using the residual solids in the concrete. Fibrous residuals generated from pulp and paper mills were used, and concrete mixture proportions and productions technologies were first optimized under controlled laboratory conditions. Based on the mixture proportions established in the laboratory, prototype field concrete mixtures were manufactured at a ready-mixed concrete plant. Afterward, a field construction demonstration was held to demonstrate the production and placement of structural-grade cold-weather-resistant concrete containing residual solids.

  4. Role of vanadium(V) in the aging of the organic phase in the extraction of uranium(VI) by Alamine 336 from acidic sulfate leach liquors

    SciTech Connect (OSTI)

    Chagnes, A.; Cote, G.; Courtaud, B.; Thiry, J.

    2008-07-01

    The present work is focussed on the chemical degradation of Alamine 336-tridecanol-n-dodecane solvent which used in the recovery of uranium by solvent extraction. Degradation occurs due to the presence of vanadium(V), an oxidant, in the feed solution. After a brief overview of the chemistry of vanadium, the kinetics of degradation of the solvent when contacted with acidic sulfate leach liquor was investigated and interpreted by the Michelis-Menten mechanism. GCMS analyses evidenced the presence of tridecanoic acid and dioctylamine as degradation products. A mechanism of degradation is discussed. (authors)

  5. Cause not found for Texas LPG site blast

    SciTech Connect (OSTI)

    Not Available

    1992-04-20

    This paper reports that National Transportation Safety Board investigators completed the first phase of tests at Seminole Pipeline Co.'s liquid petroleum gas storage dome near Brenham, Tex., without finding the cause of an explosion there Apr. 7. But in a week of investigation, NTSB determined that a release of brine and product occurred at the 350,000 bbl LPG storage dome, about 45 miles northwest of Houston, just before the blast. The explosion sent shock waves felt as far as 130 miles away. Three persons have died from injuries suffered in the accident. Another 18 were injured.

  6. A system for interpretation of blast furnace stockrod measurements

    SciTech Connect (OSTI)

    Hinnelae, J.; Saxen, H.

    1997-12-31

    A system for intelligent monitoring and interpretation of signals from blast furnace stockrods is presented. The system visualizes the measurements and estimates the local burden layer thickness (under the rods) after every dump. Furthermore, it analyzes the burden descent rate to distinguish between slips, hangings, normal descent and peaks, etc., and also combines the stockrod information with findings of temperature measurements from an above-burden probe. The preprocessing of the signals and some features of the system, which is under development, are treated in this paper.

  7. The limitation of hearth sidewall wear at Redcar blast furnace

    SciTech Connect (OSTI)

    Parratt, J.E.

    1996-12-31

    The Redcar blast furnace with 14m hearth diameter was blown-in for its second campaign in August 1996. It is currently in its 10th year of operation and to date has produced just over 30 million tonnes. Current plans are to continue the second campaign to the year 2000 and beyond, producing over 40 million tonnes. In order to achieve this objective, any further wear on the lining, and in particular the hearth sidewall, needs to be minimized. This paper describes the present hearth design, the monitoring of hearth wear, the predicted wear profile, and the protection measures that have been taken or are being considered.

  8. The stability of slopes subjected to blasting vibration -- Assessment and application in Hong Kong

    SciTech Connect (OSTI)

    Law, R.; Keller, R.

    1996-12-01

    In the rush to beat the clock before the handover of Hong Kong back to China in June of 1997, an unprecedented amount of infrastructure work is being undertaken at a breakneck pace. In the middle of this construction explosion, on this island of barren granite, stands some of the most concerning and restrictive slope stability measures. So conservative, these measures impact blasting and vibration control to an extent unmatched anywhere in the world. This paper covers the application of vibration limitations and assessment of the stability of rock slopes subjected to blasting vibration in a very challenging application. The widening of the Tuen Mun highway, a project to improve a main artery to the city center to accommodate the ever increasing traffic, involves the blasting of existing slopes in cuts only a few meters wide and up to 45 meters in height, while addressing assessment limitations in a variety of geological conditions. Discussed in the paper is the application of guidelines imposed by the Geotechnical Engineering Office and the Mines Division of the Hong Kong Government and measures taken to address them, i.e., adjustment of geological factors for practical application in blast design; blasting with minimal effect; and maximum protective measures. As slope stability becomes another ever-increasing environmental concern affecting blasting, these applications may be helpful in addressing the encroachment of impending restrictions in other parts of the world on challenging projects where blast assessment of slopes is a critical factor.

  9. Regeneration of FGD waste liquors: Production of ammonium and potassium sulfate mixed fertilizer. Quarterly technical report, October 1993--December 1993

    SciTech Connect (OSTI)

    Randolph, A.D.

    1993-12-31

    In the 2nd quarterly report, we discussed the lime/limestone process which precipitates N-S containing compounds by adding lime/limestone in a narrow pH range, and which can be an alternative to the K{sub 2}SO{sub 4} process. In this report, we focused on investigations of the lime/limestone process. First, we established an overall flow diagram for the lime/limestone process. Based on the diagram, we performed preliminary experimental investigations to outline practical process conditions. Out major investigations concerned about effects of pH on precipitation of the N-S compounds and precipitation characteristics of N-S compounds in a continuous crystallization system. We also performed an experimental investigation to study crystallization characteristic of the ammonium sulfate in the hydrolysis liquor. In studying effects of pH, we performed batch precipitation of the N-S compounds in a broad range of pH and investigated the effects of pH on the amount of required lime, the amount of the precipitate, and the fraction of N-S compounds precipitated. The result revealed the optimum range for precipitation of N-S compounds to be pH = 7.6--8.6. In studying continuous crystallization characteristics of the N-S compounds, a bench scale 4-liter continuous crystallization system was built to compare a typical Mixed-Suspension-Mixed-Product-Removal (MSMPR) crystallizer and Double-Draw-Off (DDO) crystallizer. In a preliminary test, the DDO was shown to be superior by increasing the average size of the precipitated crystals of N-S compounds from 97 {mu}m to 142 {mu}m and thus enhancing the filterability. In order to obtain information for a practical design of the lime/limestone process, we also set up a material balance for a 300 MWe power plant facility. A preliminary calculation showed that a process on the scale could produce approximately 56 tons ammonium sulfate fertilizer per day.

  10. Influence of corn steep liquor and glucose on colonization of control and CCB (Cu/Cr/B)-treated wood by brown rot fungi

    SciTech Connect (OSTI)

    Humar, Miha; Pohleven, Franc

    2006-07-01

    There are increasing problems with regard to the disposal of treated wood waste. Due to heavy metals or arsenic in impregnated wood waste, burning and landfill disposal options are not considered to be environmentally friendly solutions for dealing with this problem. Extraction of the heavy metals and recycling of the preservatives from the wood waste is a much more promising and environmentally friendly solution. In order to study the scale up of this process, copper/chromium/boron-treated wood specimens were exposed to copper tolerant (Antrodia vaillantii and Leucogyrophana pinastri) and copper sensitive wood decay fungi (Gloeophyllum trabeum and Poria monticola). Afterwards, the ability of fungal hyphae to penetrate and overgrow the wood specimens was investigated. The fungal growths were stimulated by immersing the specimens into aqueous solution of glucose or corn steep liquor prior to exposure to the fungi. The fastest colonization of the impregnated wood was by the copper tolerant A. vaillantii. Addition of glucose onto the surface of the wood specimens increased the fungi colonization of the specimens; however, immersion of the specimens into the solution of corn steep liquor did not have the same positive influence. These results are important in elucidating copper toxicity in wood decay fungi and for using these fungi for bioremediation of treated wood wastes.

  11. Model of the radial distribution of gas in the blast furnace

    SciTech Connect (OSTI)

    Nikus, M.; Saxen, H.

    1996-12-31

    This paper describes an on-line model for estimating the radial gas distribution in blast furnaces. The model is based on molar and energy flow balances for the blast furnace throat region, and utilizes the top gas temperature and gas temperature measurements from a fixed above-burden probe. The distribution of the gas flux is estimated by a Kalman filter. The method is illustrated to capture short-term dynamics and to detect sudden major changes in the gas distribution in Finnish blast furnace.

  12. Development of a thermal reclamation system for spent blasting abrasive

    SciTech Connect (OSTI)

    Bryan, B.B.; Mensinger, M.C.; Rehmat, A.G.

    1991-01-01

    Abrasive blasting is the most economical method for paint removal from large surface areas such as the hulls and tanks of oceangoing vessels. Tens of thousands of tons of spent abrasive are generated annually by blasting operations in private and US Navy shipyards. Some of this material is classified as hazardous waste, and nearly all of it is currently being either stockpiled or disposed in landfills. The rapid decline in available landfill space and corresponding rise in landfill tipping fees pose a severe problem for shipyard operators throughout the US. This paper discusses the results of a research and development program initiated by the Institute of Gas Technology and supported by the US Navy to develop and test a fluidized-bed thermal reclamation system for spent abrasive waste minimization. Bench- and pilot-scale reclaimer tests and reclaimed abrasive performance tests are described along with the current status of a program to build and test a 5-ton/hour prototype reclaimer at a US Navy shipyard.

  13. Diffuse reflectance FTIR of stains on grit blasted metals

    SciTech Connect (OSTI)

    Powell, G.L.; Hallman, R.L. Jr.; Cox, R.L.

    1997-08-09

    Diffuse reflectance mid-infrared Fourier transform (DRIFT) spectroscopy has been applied to the detection of oil contamination on grit-blasted metals. The object of this application is to detect and discriminate between silicone and hydrocarbon oil contamination at levels approaching 10 mg/m{sup 2}. A portable FTIR spectrometer with dedicated diffuse reflectance optics was developed for this purpose. Using translation devices positioned by instructions from the spectrometer operating system, images of macroscopic substrates were produced with millimeter spatial resolution. The pixels that comprise an image are each a full mid-infrared spectrum with excellent signal-to-noise, each determined as individual files and uniquely saved to disc. Reduced spectra amplitudes, based on peak height, area, or other chemometric techniques, mapped as a function of the spatial coordinates of the pixel are used to display the image. This paper demonstrates the application of the technique to the analysis of stains on grit-blasted metals, including the calibration of the method, the inspection of substrates, and the migration of oil contamination.

  14. Single taphole blast furnace casthouse performance optimizing cost and availability

    SciTech Connect (OSTI)

    Fowles, R.D.; Searls, J.B.; Peay, W.R.; Brenneman, R.G.

    1995-12-01

    The No. 2 blast furnace is a single taphole furnace with a convection air-cooled iron trough. The iron runner system is designed to fill four 90 ton open-top ladles per cast, which are transported by locomotive to the steel shop. The slag runner system is capable of filling three 800 ft{sup 3} slag pots per cast. The No. 2 blast furnace was blown in from mini-reline with this new casthouse configuration in early December 1991. It was operated for nearly three years until it was banked for planned stove repairs and a trough rebuild in late September 1994. During this period, the furnace produced just over 2.5 million tons of hot metal across the original trough refractory lining system, with 13 intermediate hot patch castable repairs. The entire casthouse refractory usage (main trough, runner systems, and covers) during this campaign was 1.06 pounds per net ton of hot metal. Investigation of the lining during demolition indicated that the trough lining campaign could have been extended to at least 3.0 million tons. This paper will discuss how operating practices, mechanical design, refractory design, maintenance philosophy, and attention to detail synergistically contributed to the long campaign life and low refractory consumption rate.

  15. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J.; Sirgado, M.

    1995-12-01

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  16. Recent developments in blast furnace process control within British Steel

    SciTech Connect (OSTI)

    Warren, P.W.

    1995-12-01

    British Steel generally operates seven blast furnaces on four integrated works. All furnaces have been equipped with comprehensive instrumentation and data logging computers over the past eight years. The four Scunthorpe furnaces practice coal injection up to 170 kg/tHM (340 lb/THM), the remainder injecting oil at up to 100 kg/tHM (200 lb/THM). Distribution control is effected by Paul Wurth Bell-Less Tops on six of the seven furnaces, and Movable Throat Armour with bells on the remaining one. All have at least one sub burden probe. The blast furnace operator has a vast quantity of data and signals to consider and evaluate when attempting to achieve the objective of providing a consistent supply of hot metal. Techniques have been, and are being, developed to assist the operator to interpret large numbers of signals. A simple operator guidance system has been developed to provide advice, based on current operating procedures and interpreted data. Further development will involve the use of a sophisticated Expert System software shell.

  17. Ten case history studies of energy efficiency improvements in pulp and paper mills. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    The ten technologies chosen for case history development are: sonic sootblowing in boilers, boiler operation on oil-water emulsified fuel, energy efficient motors, computerized control of excess air for boilers, boiler control and load allocation, driving of waste-activated sludge by multiple effect evaporation, pre-drying of hog fuel, lime kiln computerization, heat wheel for process heat recovery, and organic Rankine bottoming cycle for thermomechanical pulping heat recovery. For each case study, there is given: the company name, employee contact, plant summary, a description of the energy consuming process and of the energy-saving action, an assessment of energy savings, and the decision process leading to the adoption of the measure. A data summary for discounted cash flow analysis is tabulated for each case. (LEW)

  18. Changing Trends in the Bulk Chemicals and Pulp and Paper Industries (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    Compared with the experience of the 1990s, rising energy prices in recent years have led to questions about expectations of growth in industrial output, particularly in energy-intensive industries. Given the higher price trends, a review of expected growth trends in selected industries was undertaken as part of the production of Annual Energy Outlook 2005 (AEO). In addition, projections for the industrial value of shipments, which were based on the Standard Industrial Classification (SIC) system in AEO2004, are based on the North American Industry Classification System (NAICS) in AEO2005. The change in industrial classification leads to lower historical growth rates for many industrial sectors. The impacts of these two changes are highlighted in this section for two of the largest energy-consuming industries in the U.S. industrial sector-bulk chemicals and pulp and paper.

  19. Carbon Emissions: Paper Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Btu Renewable Energy Sources (no net emissions): -- Pulping liquor: 882 trillion Btu -- Wood chips and bark: 389 trillion Btu Energy Information Administration, "1994...

  20. Oxygen-Enriched Combustion; Industrial Technologies Program ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Industry Applications Steel Reheat, soaking pits, ladles Aluminum Melting Copper Smelting and melting Glass Melting Pulp and Paper Lime kilns, black liquor boilers ...

  1. FORM EIA-846(F)

    U.S. Energy Information Administration (EIA) Indexed Site

    packing materials, etc.) Pulping or black liquor Waste oils and tars Biomass Hydrogen Other combustible energy sources: (List separately), K? Census use only sv(2) 216...

  2. Evaluating high-temperature intumescent insulation materials under fire and blast conditions

    SciTech Connect (OSTI)

    Parker, A.J.

    1997-11-01

    This paper describes recent testing conducted to evaluate the performance of high-temperature intumescent materials under adverse fire and blast conditions. Results from fire performance evaluations currently protecting offshore oil platforms are presented. Extensive fire and blast qualification testing of epoxy-based intumescent materials has been conducted utilizing specially designed blast chambers, jet fire facilities, and laboratory furnaces. Blast chambers are capable of loading up to a 3 x 3-m insulated bulkhead assembly to a 2 bar over pressure and having a duration of approximately 250 millisecond generated by a controlled flammable vapor cloud explosion. The jet fire test exposes an insulated test specimen to a fire environment characterized by temperatures of approximately 1100 C, sonic gas velocities, and peak heat flux levels in excess of 300 kW/m{sup 2}.

  3. Titanium addition practice, and maintenance for the hearths in AHMSA`s blast furnaces

    SciTech Connect (OSTI)

    Boone, A.G.; Jimenez, G.; Castillo, J.

    1997-12-31

    Altos Hornos de Mexico (AHMSA) is a steel company located in Northern Mexico, in the state of Coahuila. Currently there are three blast furnaces in operation and one more about to finish its general repair. This last one is to remain as a back-up unit. Because of blast furnace hearth wear outs AHMSA has developed some maintenance procedures. These procedures are based on titanium ore additions and hearth thermic control monitoring. There are also some other maintenance practices adopted to the working operations to assure that such operations detect and avoid in time hearth wear outs that place personnel and/or the unit in danger (due to hearth leaks). This paper describes titanium ore addition to No. 2 blast furnace during the final campaign and it also illustrates maintenance practices and continuous monitoring of temperature trends both of which were implemented at AHMSA`s No. 5 blast furnace.

  4. Optimization of ferrous burden high temperature properties to meet blast furnace requirements in British Steel

    SciTech Connect (OSTI)

    Bergstrand, R.

    1996-12-31

    The high temperature properties of ferrous burden materials have long been an important consideration in the operation of British Steel blast furnaces. Previous research presented at this conference has shown that the behavior of materials in the lower stack and bosh can have a significant effect on furnace permeability and stability of operation. However, with increasing levels of hydrocarbon injection via the tuyeres, the reduction conditions inside British Steel blast furnaces have significantly altered over recent years. This paper focuses on the further work that has been undertaken to study the effect on ferrous burden high temperatures properties of the widely differing reduction regimes which can be experienced in today`s blast furnaces. The implications of the findings, and how they have been used in optimizing blast furnace operation and burden quality, are discussed.

  5. Literature survey of blast and fire effects of nuclear weapons on urban areas

    SciTech Connect (OSTI)

    Reitter, T.A.; McCallen, D.B.; Kang, S.W.

    1982-06-01

    The American literature of the past 30 years on fire and blast effects of nuclear weapons on urban areas has been surveyed. The relevant work is briefly sketched and areas where information is apparently lacking are noted. This report is intended to provide the basis for suggesting research priorities in the fire and blast effects area for the Federal Emergency Management Agency. It is also intended to provide entry into the literature for researchers. over 850 references are given.

  6. Hearth monitoring experiences at Dofasco`s No. 4 blast furnace

    SciTech Connect (OSTI)

    Stothart, D.W.; Chaykowski, R.D.; Donaldson, R.J.; Pomeroy, D.H.

    1997-12-31

    As a result of a 1994 taphole breakout at Dofasco`s No. 4 Blast Furnace, extensive effort has gone into monitoring, understanding and controlling hearth wear. This paper reviews the hearth monitoring system developed and the various hearth operating and maintenance techniques used to ensure No. 4 Blast Furnace safely reaches its 1998 reline date. The impact of changes in coke quality, productivity, casting practice and leaking cooling members on hearth refractory temperature fluctuations will also be examined.

  7. Operating a blast furnace using dried top gas

    SciTech Connect (OSTI)

    Kundrat, D.M.

    1993-08-10

    A method is described of operating a blast furnace, comprising: introducing into the top of the furnace a charge containing metal oxide, coke and flux, collecting a top gas CO, H[sub 2], carbon dioxide and water from the furnace, increasing the reducing potential of said collected top gas by removing water but without removing carbon dioxide from at least a portion of said collected top gas thereby forming a dried top gas, heating said dried top gas to form a heated dried top gas, introducing said heated dried top gas into the lower half of the stack of the furnace at a position above which said coke is not reactive and introducing an oxygen-containing gas and a hydrogenaceous fuel into the bosh of the furnace whereby said metal oxide is reduced to a molten metal using said heated dried top gas.

  8. Operational considerations for high level blast furnace fuel injection

    SciTech Connect (OSTI)

    Poveromo, J.J.

    1996-12-31

    Injection levels of over 400 lbs/NTHM for coal, over 250 lbs/NTHM for natural gas and over 200 lbs/NTHM for oil have been achieved. Such high levels of fuel injection has a major impact on many aspects of blast furnace operation. In this paper the author begins by reviewing the fundamentals of fuel injection with emphasis on raceway thermochemical phenomena. The operational impacts which are generic to high level injection of any injectant are then outlined. The author will then focus on the particular characteristics of each injectant, with major emphasis on coal and natural gas. Operational considerations for coping with these changes and methods of maximizing the benefits of fuel injection will be reviewed.

  9. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  10. Long-term thermophilic mono-digestion of rendering wastes and co-digestion with potato pulp

    SciTech Connect (OSTI)

    Bayr, S. Ojanper, M.; Kaparaju, P.; Rintala, J.

    2014-10-15

    Highlights: Rendering wastes mono-digestion and co-digestion with potato pulp were studied. CSTR process with OLR of 1.5 kg VS/m{sup 3} d, HRT of 50 d was unstable in mono-digestion. Free NH{sub 3} inhibited mono-digestion of rendering wastes. CSTR process with OLR of 1.5 kg VS/m{sup 3} d, HRT of 50 d was stable in co-digestion. Co-digestion increased methane yield somewhat compared to mono-digestion. - Abstract: In this study, mono-digestion of rendering wastes and co-digestion of rendering wastes with potato pulp were studied for the first time in continuous stirred tank reactor (CSTR) experiments at 55 C. Rendering wastes have high protein and lipid contents and are considered good substrates for methane production. However, accumulation of digestion intermediate products viz., volatile fatty acids (VFAs), long chain fatty acids (LCFAs) and ammonia nitrogen (NH{sub 4}-N and/or free NH{sub 3}) can cause process imbalance during the digestion. Mono-digestion of rendering wastes at an organic loading rate (OLR) of 1.5 kg volatile solids (VS)/m{sup 3} d and hydraulic retention time (HRT) of 50 d was unstable and resulted in methane yields of 450 dm{sup 3}/kg VS{sub fed}. On the other hand, co-digestion of rendering wastes with potato pulp (60% wet weight, WW) at the same OLR and HRT improved the process stability and increased methane yields (500680 dm{sup 3}/kg VS{sub fed}). Thus, it can be concluded that co-digestion of rendering wastes with potato pulp could improve the process stability and methane yields from these difficult to treat industrial waste materials.