Sample records for black liquor red

  1. Gasification of black liquor

    SciTech Connect (OSTI)

    Kohl, A.L.

    1987-07-28T23:59:59.000Z

    A process is described for treating a concentrated aqueous black liquor carbonaceous material and alkali metal sulfur compounds to form a combustible gas and a sulfide-rich melt comprising: (a) providing a gasifier vessel maintained at a pressure of from about 1 to 50 atmospheres and containing a relatively shallow molten salt pool at its bottom within a sump equipped with an overflow discharge; (b) introducing into the top of the drying zone the concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds; (c) evaporating water from the concentrated aqueous black liquor in the drying zone by direct contact of the aqueous black liquor with the hot gas rising from the gasification zone to produce dried black liquor solids; (d) introducing a first portion of an oxygen-containing gas into the gas space in the gasification zone located below the drying zone immediately above the molten salt pool to partially oxidize and gasify a fraction of the carbonaceous material in the dried black liquor solids falling through the zone to form a hot combustible gas; (e) introducing a second portion of the oxygen-containing gas beneath the surface of the molten salt pool in an amount sufficient to cause gasification of essentially all carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool; (f) withdrawing the cooled combustible gas having a higher heating value of at least about 90 Btu/scf (dry basis) from an upper portion of the drying zone; and (g) withdrawing from the overflow discharge in the molten salt reduction zone a melt in which the sulfur content is predominantly in the form of alkali metal sulfide.

  2. Combustion of black liquor

    SciTech Connect (OSTI)

    Mullen, W.T.

    1989-08-15T23:59:59.000Z

    This patent describes an improvement in the combustion of black liquor in an existing Tomlison recovery boiler unit in which black liquor is sprayed into a furnace in which it is successively dried, pyrolyzed and converted to a bed of solid carbonaceous residue, using a primary air stream and a secondary air stream and the residue is subsequently converted to a smelt. The improvement comprises: the addition of between an effective amount up to 5% oxygen by volume to the primary air stream directed at the bed of solid carbonaceous residue, the amount of oxygen added being sufficient to increase the adiabatic flame temperature, the combustion rate of the solid carbonaceous material, the rate of pyrolysis, the temperature in the lower portion of the furnace, the the drying rate of black liquor droplets, and to decrease the temperature of the gases entering the heat transfer surfaces in the upper portion of the furnace and the rate of deposit formation on the surfaces and wherein the amount of black liquor combusted is increased as compared with the amount combusted in the same furnace operated without the addition of oxygen to the primary air.

  3. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, Arthur L. (Woodland Hills, CA)

    1987-07-28T23:59:59.000Z

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

  4. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, A.L.

    1987-07-28T23:59:59.000Z

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

  5. Kraft black liquor delivery systems

    SciTech Connect (OSTI)

    Adams, T.N.; Empie, H.L.; Obuskovic, N.; Spielbauer, T.M.

    1990-02-01T23:59:59.000Z

    Improvement of spray nozzles for black liquor injection into kraft recovery furnaces is expected to result from obtaining a controlled, well-defined droplet size distribution. Work this year has centered on defining the capabilities of commercial black liquor nozzles currently in use. Considerations of the observed mechanism of droplet formation suggest a major revision is needed in the theory of how droplets form from these nozzles. High resolution, high sensitivity video has been shown to be superior to flash x-ray as a technique for measuring the droplet size distribution as well as the formation history. An environmentally sound spray facility capable of spraying black liquor at temperatures up to normal firing conditions is being constructed before data acquisition continues. Preliminary correlations have been developed between liquor properties, nozzle design, and droplet size. Three aspects of nozzle design have been investigated: droplet size distribution, fluid sheet thickness, and flow and pressure drop characteristics. The standard deviation about the median droplet size for black liquor is nearly the same as the for a wide variety of other fluids and nozzle types. Preliminary correlation for fluid sheet thickness on the plate of a splashplate nozzle show the strong similarities of black liquor to other fluids. The flow and pressure drop characteristic of black liquor nozzle, follow a simple two-term relationship similar to other flow devices. This means that in routine mill operation of black liquor nozzles only the fluid acceleration in the nozzle is important, viscous losses are quiet small. 21 refs., 53 figs., 10 tabs.

  6. Combustion properties of Kraft Black Liquors

    SciTech Connect (OSTI)

    Frederick, W.J. Jr.; Hupa, M. (Aabo Akademi, Turku (Finland))

    1993-04-01T23:59:59.000Z

    In a previous study of the phenomena involved in the combustion of black liquor droplets a numerical model was developed. The model required certain black liquor specific combustion information which was then not currently available, and additional data were needed for evaluating the model. The overall objectives of the project reported here was to provide experimental data on key aspects of black liquor combustion, to interpret the data, and to put it into a form which would be useful for computational models for recovery boilers. The specific topics to be investigated were the volatiles and char carbon yields from pyrolysis of single black liquor droplets; a criterion for the onset of devolatilization and the accompanying rapid swelling; and the surface temperature of black liquor droplets during pyrolysis, combustion, and gasification. Additional information on the swelling characteristics of black liquor droplets was also obtained as part of the experiments conducted.

  7. Black Liquor Research Program symposium: proceedings

    SciTech Connect (OSTI)

    Emerson, D.B.; Whitworth, B.A.

    1985-03-01T23:59:59.000Z

    In the paper pulp industry's recovery boilers, black liquor is sprayed in through nozzle guns near the top of the furnace. This report includes eight papers. (DLC)

  8. Causticizing for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

    2009-01-07T23:59:59.000Z

    The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

  9. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Jun Wei

    2005-03-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.3, Simulative corrosion of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1 and Task 1.2. Refractories provided by in-kind sponsors were tested by cup testing, density/porosity determinations, chemical analysis and microscopy. The best performing materials in the cup testing were fused cast materials. However, 2 castables appear to outperforming any of the previously tested materials and may perform better than the fused cast materials in operation. The basis of the high performance of these materials is the low open porosity and permeability to black liquor smelt.

  10. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

    2004-10-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  11. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr.; Alireza Rezaie

    2003-12-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  12. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Robert E. Moore; William L. Headrick; Alireza Rezaie

    2003-03-31T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  13. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick; Musa Karakus; Alireza Rezaie

    2004-03-30T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO2 and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  14. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

    2004-07-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  15. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-10-01T23:59:59.000Z

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected/developed that either react with the gasifier environment to form protective surfaces in-situ; and were functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development were divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  16. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr.; Alireza Rezaie

    2004-04-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  17. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-04-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  18. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-07-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  19. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie; Xiaoting Liang; Musa Karakus; Jun Wei

    2005-12-01T23:59:59.000Z

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected or developed that reacted with the gasifier environment to form protective surfaces in-situ; and were functionally-graded to give the best combination of thermal, mechanical and physical properties and chemical stability; and are relatively inexpensive, reliable repair materials. Material development was divided into 2 tasks: Task 1 was development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO2 and SiC. Task 2 was finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  20. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie

    2003-12-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  1. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-01-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  2. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie

    2003-08-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

  3. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Laing

    2005-10-01T23:59:59.000Z

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.4, Industrial Trial of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1, 1.2 and 1.3. Refractories provided by in-kind sponsors to industrial installations tested by cup testing, density/porosity determinations, chemical analysis and microscopy. None of the materials produced in this program have been tried in high temperature gasifiers, but the mortar developed Morcocoat SP-P is outperforming other mortars tested at ORNL. MORCO PhosGun M-90-O has shown in laboratory testing to be an acceptable candidate for hot and cold repairs of existing high temperature gasifiers. It may prove to be an acceptable lining material.

  4. Black liquor gasifier/gas turbine cogeneration

    SciTech Connect (OSTI)

    Consonni, S. [Politecnico di Milano (Italy). Dept. di Energetica; Larson, E.D.; Keutz, T.G. [Princeton Univ., NJ (United States); Berglin, N. [Chalmers Univ. of Technology, Goteborg (Sweden). Dept. of Heat and Power Technology

    1998-07-01T23:59:59.000Z

    The kraft process dominates pulp and paper production worldwide. Black liquor, a mixture of lignin and inorganic chemicals, is generated in this process as fiber is extracted from wood. At most kraft mills today, black liquor is burned in Tomlinson boilers to produce steam for on-site heat and power and to recover the inorganic chemicals for reuse in the process. Globally, the black liquor generation rate is about 85,000 MW{sub fuel} (or 0.5 million tonnes of dry solids per day), with nearly 50% of this in North America. The majority of presently installed Tomlinson boilers will reach the end of their useful lives during the next 5 to 20 years. As a replacement for Tomlinson-based cogeneration, black liquor-gasifier/gas turbine cogeneration promises higher electrical efficiency, with prospective environmental, safety, and capital cost benefits for kraft mills. Several companies are pursuing commercialization of black liquor gasification for gas turbine applications. This paper presents results of detailed performance modeling of gasifier/gas turbine cogeneration systems using different black liquor gasifiers modeled on proposed commercial designs.

  5. Lowering kraft black liquor viscosity of ultrafiltration

    SciTech Connect (OSTI)

    Hill, M.K.; Violette, D.A.; Woerner, D.L.

    1988-10-01T23:59:59.000Z

    High viscosity is a major factor limiting the percentage total dissolved solids (%TDS) to which kraft black liquor (KBL), a spent pulping liquor, can be concentrated before it is burned to recover its fuel value and its inorganic chemicals. The effect on black liquor viscosity of removing high molecular weight lignin by ultrafiltration of 16% and 24% TDS liquors was studied. Viscosities of ultrafiltration permeates were reduced relative to feed black liquors. When a permeate was concentrated to higher %TDS levels, its viscosity decreased yet further relative to feed samples evaporated to similar solids levels. Retentate viscosity was very high relative to both feed and permeate. Ultrafiltration was carried out at 75/degrees/C using polysulfone membranes in a plate-and-frame or hollow fiber system. Flux rates varied greatly depending upon the specific liquor used. Flux was enhanced by increased temperature and increased linear velocity. The membrane molecular weight cutoff (MWCO) typically used was 50,000; increasing 100,000 or 200,000 did not enhance flux.

  6. alkaline black liquor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alan 1998-01-01 3 PERFORMANCE OF BLACK LIQUOR GASIFIERGAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP Renewable Energy Websites Summary: PERFORMANCE OF BLACK LIQUOR...

  7. Improved recovery of tall oil from black liquors

    SciTech Connect (OSTI)

    Zucker, J.

    1980-12-09T23:59:59.000Z

    Applying a d.c. of less than 15 V to acidified black liquor separates a significant amount of tall oil remaining in the black liquor sludge. An apparatus with graphite electrodes for this process is described.

  8. Pulsed combustion process for black liquor gasification

    SciTech Connect (OSTI)

    Durai-Swamy, K.; Mansour, M.N.; Warren, D.W.

    1991-02-01T23:59:59.000Z

    The objective of this project is to test an energy efficient, innovative black liquor recovery system on an industrial scale. In the MTCI recovery process, black liquor is sprayed directly onto a bed of sodium carbonate solids which is fluidized by steam. Direct contact of the black liquor with hot bed solids promotes high rates of heating and pyrolysis. Residual carbon, which forms as a deposit on the particle surface, is then gasified by reaction with steam. Heat is supplied from pulse combustor resonance tubes which are immersed within the fluid bed. A portion of the gasifier product gas is returned to the pulse combustors to provide the energy requirements of the reactor. Oxidized sulfur species are partially reduced by reaction with the gasifier products, principally carbon monoxide and hydrogen. The reduced sulfur decomposed to solid sodium carbonate and gaseous hydrogen sulfide (H{sub 2}S). Sodium values are recovered by discharging a dry sodium carbonate product from the gasifier. MTCI's indirectly heated gasification technology for black liquor recovery also relies on the scrubbing of H{sub 2}S for product gases to regenerate green liquor for reuse in the mill circuit. Due to concerns relative to the efficiency of sulfur recovery in the MTCI integrated process, an experimental investigation was undertaken to establish performance and design data for this portion of the system.

  9. In Situ Causticizing for Black Liquor Gasification

    SciTech Connect (OSTI)

    Scott Alan Sinquefield

    2005-10-01T23:59:59.000Z

    Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

  10. Thermal processing of black liquor from alkaline straw pulping

    SciTech Connect (OSTI)

    Sanchez, J.L.; Garcia, L.; Gea, G.; Bilbao, R.; Arauzo, J. [Univ. of Zaragoza (Spain)

    1996-12-31T23:59:59.000Z

    Black liquor is the wastewater from the cooking of wood or straw in the production of pulp and paper. Nowadays new processes are being investigated as alternatives to the traditional recovery boiler used for black liquor treatment. One of the processes which appears to be more promising is gasification, for which further research is needed for its full industrial implementation. There is not much data about the behavior of soda black liquors from straw cooking in the literature. Therefore the thermal decomposition of one of these liquors has been studied in a thermobalance, in inert (N{sub 2}) atmosphere. The kinetic constants from isothermal experiments have been obtained.

  11. Electrochemical treatment of black liquor from straw pulping

    SciTech Connect (OSTI)

    Blanco, M.A.; Negro, C.; Tijero, J. [Complutense Univ., Madrid (Spain)] [and others

    1996-11-01T23:59:59.000Z

    The conventional black liquor regeneration process is not always suitable for pulping plants of nonwood fibers due to the unfavorable ratio of organic to inorganic solids. This paper presents an alternative treatment based on an electrolysis process of the soda black liquor from straw pulping. This alternative method minimizes the environmental impact by recovering the caustic at the same time that the liquor is acidified, which favors the later separation of the lignin.

  12. Fundamental studies of black liquor combustion

    SciTech Connect (OSTI)

    Clay, D.T.; Lien, S.J.; Grace, T.M.; Brown, C.A.; Empie, H.L.; Macek, A.; Amin, N.; Charangundla, S.R.

    1990-03-01T23:59:59.000Z

    The fundamentals of black liquor combustion are being studied in a project being carried out for the US Department of Energy by the Institute of Paper Science Technology (IPST, formerly the Institute of Paper Chemistry) and the National Institute of Science Technology (NIST, formerly the National Bureau of Standards). The project was divided into four phases. This report covers the completion of Phase 1 (in-flight processes), the results of all of the work on Phase 2 (char bed processes), Phase 3 (fume processes), and Phase 4 (furnace simulation). 41 refs., 62 figs., 30 tabs.

  13. Definition:Black Liquor | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model,DOE Facility Database DataDatatechnicNewDeafDeer LodgeDeering,Black Liquor Jump

  14. Physical properties of Kraft Black Liquor. Interim report, Phase II

    SciTech Connect (OSTI)

    Fricke, A.L.

    1985-03-01T23:59:59.000Z

    Objectives are to determine the rheological, thermal, and surface properties of Kraft Black Liquors, and to relate these properties to the chemical composition and to pulping conditions. A four-variable, multi-level pulping experiment is being conducted. Pulping results are reported. Complete analyses of the liquors have been done. Thermal analyses have been done. DSC was employed to determine heat capacities of black liquors and lignins. Rheological (viscosity) studies are being conducted. Density and thermal expansion have been studied for seven liquors. Energy savings through more efficient recovery systems are appreciable.

  15. Effect of pulping conditions and black liquor composition on Newtonian viscosity of high solids kraft black liquors

    SciTech Connect (OSTI)

    Zaman, A.A.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering] [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering

    1996-02-01T23:59:59.000Z

    The influence of black liquor composition and solids concentrations on the Newtonian viscosity of slash pine black liquors over wide ranges of temperature (up to 140 C) and solids concentrations (between 50% and 83% solids) has been studied. It was found that the zero shear rate viscosity of high solids black liquors depends strongly on the cooking conditions and/or black liquor composition. Not only is high solids viscosity affected by lignin molecular weight and lignin concentration in the liquor but other organic and inorganic constituents of black liquor also make a significant contribution to viscosity. The dependency of zero shear rate viscosity on solids concentrations, and temperature is defined. The Newtonian viscosities vary over a wide range depending on temperature, solids concentrations and solids composition. The results indicate that, at fixed levels of effective alkali and sulfidity, the zero shear rate viscosities can be described as a function of both lignin concentration and lignin molecular weight. The viscosity of black liquor is an increasing function of the organics-to-inorganics ratio and is a decreasing function of the concentration of sodium and chloride ions and pH of the liquor.

  16. Char reactions during kraft black liquor pyrolysis

    SciTech Connect (OSTI)

    Frederick, W.J.; Sricharoenchaikul, V.; Reis, V.V. [Oregon State Univ., Corvallis, OR (United States)

    1995-12-01T23:59:59.000Z

    The pyrolysis characteristics of dried black liquor particles were investigated at high heating rates in a laminar entrained-flow reactor at temperatures of 600-1100{degrees}C. Primary pyrolysis of the organic fraction occurred very rapidly, in less 0.5 seconds. Char yields at the end or volatiles evolution were 58-72%. The decreased with increasing reactor temperature to 900{degrees}C but remained constant at higher temperatures. 35-65% of the fuel nitrogen was volatilized, nearly all in less than 0.5 s. Relatively little fuel nitrogen was evolved from the char. Significant alkali metal chloride volatization from the char occurred at all temperatures, while additional sodium volatilization became important above 900{degrees}C. Reduction of sulfur species in the char increased rapidly with increasing temperature. A temperature-dependent delay time in the onset of Na{sub 2}S formation was observed.

  17. Proceedings of the black liquor research program review fourth meeting held July 28--30, 1987

    SciTech Connect (OSTI)

    Emerson, D. B.; Whitworth, B. A.

    1987-10-01T23:59:59.000Z

    Research programs, presented at the black liquor review meeting are described. Research topics include the following: Cooperative Program in Kraft Recovery; Black Liquor Physical Properties; Viscosity of Strong Black Liquor; Ultrafiltration of Kraft Black Liquor; Molecular Weight Distribution of Kraft Lignin; Black Liquor Droplet Formation Project; Fundamental Studies of Black Liquor Combustion; Black Liquor Combustion Sensors; Flash X-ray Imagining of Black Liquor Sprays; Laser Induced Fluorescence For Process Control In The Pulp and Paper Industry; Recovery Boiler Optimization; Black Liquor Gasification and Use of the Products in Combined-Cycle Cogeneration; Black Liquor Steam Plasma Automization; The B and W Pyrosonic 2000R System; Monsteras Boiler Control System; and Cooperative Program Project Reviews. Individual projects are processed separately for the data bases.

  18. Black Liquor Gasification Process Review and Status Update

    E-Print Network [OSTI]

    Brown, C.

    1993-01-01T23:59:59.000Z

    After more than two decades of research and development, black liquor gasification is poised to become a commercial reality in the 90's. Several promising developments are underway in North America and Europe. In fact, all major recovery boiler...

  19. Demonstration of Black Liquor Gasification at Big Island

    SciTech Connect (OSTI)

    Robert DeCarrera

    2007-04-14T23:59:59.000Z

    This Final Technical Report provides an account of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific LLC's Big Island, VA facility. This report covers the period from May 5, 2000 through November 30, 2006.

  20. Drum drying of black liquor using superheated steam impinging jets

    SciTech Connect (OSTI)

    Shiravi, A.H.; Mujumdar, A.S.; Kubes, G.J. [McGill Univ., Montreal, Quebec (Canada)

    1997-05-01T23:59:59.000Z

    A novel drum dryer for black liquor utilizing multiple impinging jets of superheated steam was designed and built to evaluate the performance characteristics and effects of various operating parameters thereon. Appropriate ranges of parameters such as steam jet temperature and velocity were examined experimentally to quantify the optimal operating conditions for the formation of black liquor film on the drum surface as well as the drying kinetics.

  1. Proceedings of the black liquor research program review fifth meeting

    SciTech Connect (OSTI)

    Not Available

    1988-09-01T23:59:59.000Z

    On June 14--17, 1988 the participants and invited guests of the Cooperative Program in Kraft Recovery gathered in Charleston, South Carolina, to review progress on four major black liquor research programs being executed at the Institute of Paper Chemistry, the University of Maine, the National Bureau of Standards, and the University of Florida. These programs include: (1) Black Liquor Properties; (2) Black Liquor Droplet Formation; (3) Black Liquor Nozzle Evaluation; and (4) Black Liquor Combustion. In addition to the objectives of previous meetings, this meeting made a direct attempt to gather ideas on how to improve our ability to move from new technology concepts to commercial implementation. Also attached is the agenda for the Charleston meeting. The first two days were involved with updates and reviews of the four major black liquor programs. A half day was spent discussing pathways to implementation and developing thoughts on what industry, DOE and academia could do to facilitate commercial implementation of the research results. This publication is a summary of the presentations made in Charleston and the industry responses to the research work. Readers are cautioned that the contents are in-progress updates on the status of the research and do not represent referred technical papers. Any questions regarding the content should be referred to the principal investigators of the project.

  2. Kraft black liquor combustion: Advancement in fundamental understanding

    SciTech Connect (OSTI)

    Clay, D.T.

    1987-10-01T23:59:59.000Z

    Self-generated fuel streams plus purchased fossil fuel and power supply the pulp and paper industry with its energy requirements. The total industry energy use for 1986 was approximately 2.3 Quad (2300 trillion Btus). Self-generated and residue fuels accounted for 57% of the energy requirements. Spent pulping liquors provide the single largest self-generated energy source, approximately one Quad (900 trillion Btus). The pulp and paper industry also leads the nation in cogeneration performance. In 1986 eighty-nine percent (89%) of the 46 billion KWHs generated were produced by cogeneration. Spent pulping liquors supply the single largest fuel source (35%) to these cogeneration facilities. Spent pulping liquors consist of solubilized wood organics, spent inorganic chemicals, and water. Since kraft pulp dominates the North American market, 74%, kraft black liquor is the dominant spent pulping liquor. Effective recovery of high level energy and chemicals from black liquor contributes heavily toward dominance of kraft pulping. The kraft chemical recovery cycle centers around the recovery boiler. Kraft recovery boilers have been commercially available for over 50 years. The potential still exists, however, for significant improvements in energy recovery and black liquor throughput. Potential energy benefits from black liquor combustion research amount to 30 trillion Btus. Energy recovery increases often are an additional benefit from modifications made to increase black liquor throughput. Capacity increases of at least 5% are often achievable. Increased energy productivity of the kraft chemical recovery boiler will come by incorporation of improved fundamental knowledge into the technology used for boiler upgrades and new boiler construction. 5 refs., 9 figs.

  3. Controlled black liquor viscosity reduction through salting-in

    SciTech Connect (OSTI)

    Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)] [North Carolina State Univ., Raleigh, NC (United States)

    1996-08-01T23:59:59.000Z

    Black liquor viscosity increases exponentially with solids content and therefore causes processing problems for the paper industry by being a limiting factor in the Kraft pulp process. This study investigates a new approach for achieving viscosity reduction by salting-in black liquor through the addition of thiocyanate salts. These salts generally increase the solubility of the polymer constituents in black liquor, leading to a decrease in its viscosity. Several thiocyanate salts capable of reducing liquor viscosity by more than two orders of magnitude have been identified, with viscosity reduction greatest at high solids content. Salting-in of black liquor depends on the cation paired with the thiocyanate anion, as well as on solution pH and temperature. Comparative studies reveal the most effective viscosity-reducing agent of the series examined and that lignin plays an important role in the viscosity behavior of both unmodified and salted-in black liquor at high solids concentrations. These experimental findings are interpreted in terms of the underlying principles that describe salting-in and how it affects aqueous solution structure.

  4. Measurement of black liquor surface tension: Technical report No. 3. [Black liquor

    SciTech Connect (OSTI)

    Krishnagopalan, J.

    1987-09-01T23:59:59.000Z

    Surface tension and density of two kraft black liquors were measured at a series of temperatures, from a minimum value when gas bubbles can be blown into the liquor to a maximum value near the elevated boiling point of a particular sample. Available methods for the measurement of surface tension were evaluated critically and, as a result, the maximum bubble pressure method was selected. Varying the flow rate of the gas changes the frequency of bubble formation and thereby the age of the surface. The parameter has been utilized by many researchers to monitor the diffusion of low surface energy components (e.g., surfactants) to the liquid/air interface. The effect of bubble frequency when tested with a few pure liquids, indicated that the dynamics of bubble formation had to be further examined to separate out inertial and viscous effects from purely surface tension related pressure. The pressure versus flow rate data were extrapolated to zero flow rate and surface tension and density were calculated using these extrapolated values. As expected, surface tension decreased with increasing temperature for all the samples. Surface tension decreases with increasing solids content (when compared with the value for water) to a certain level (about 20%) and it starts to increase again. The decrease in surface tension in the dilute black liquor, is probably due to the decrease in the concentration of water, which has a high surface tension value. The occurrence of the minimum is probably due to the effect of inorganic components dominating over the effect of surfactants and other components. Reduction in the solubilities of the inorganics, promotion of micelles of the surfactants and reduction in the diffusion of surfactants to the surface, also could contribute to this phenomenon. 54 refs., 54 figs., 12 tabs.

  5. Recaustization of kraft black liquor via bipolar electrodialysis

    SciTech Connect (OSTI)

    Koumoundouros, J.A.; Oshen, S.; Lynch, J.D.

    1990-05-01T23:59:59.000Z

    The US Department of Energy in conjunction with HPD Inc. supported a research program to perform a laboratory feasibility study with various black liquor samples for the recaustization of these samples via bipolar electrodialysis. The research was conducted at the HPD pilot plant facility in Plainfield, Illinois, beginning in April 1989. This report is a summary of the work completed thru November 1989. The program was designed to operate the electrodialyzer in order to obtain performance and engineering data such as current efficiency, power consumption per gram of NaOH produced, and assess fouling and/or membrane durability. Prior to the electrodialysis laboratory runs, the black liquor samples were pretreated in order to remove as much lignin as possible. The black liquor samples were air oxidized, acidified to pH = 9.0 and pH = 2.0 and later filtered via a Buchner funnel under vacuum. The filtrate was then utilized to become the feed to the electrodialysis stack. Initial test runs were performed with synthetic solutions of either sodium sulfate or sodium bicarbonate in order to determine acceptable operating current, power, current efficiencies, and fouling behavior. A second set of test were conducted with a series of four Southern Kraft black liquor samples. Based on the results of this study, it was determined that the use of bipolar electrodialysis for producing a caustic stream and an acidified black liquor stream is feasible and was demonstrated. 9 refs., 27 figs., 32 tabs.

  6. Ultrafiltration of kraft black liquor: Final report, Phase 3

    SciTech Connect (OSTI)

    Hill, M.K.

    1988-04-01T23:59:59.000Z

    Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work. 21 refs., 32 figs.

  7. Black liquor gasification phase 2D final report

    SciTech Connect (OSTI)

    Kohl, A.L.; Stewart, A.E.

    1988-06-01T23:59:59.000Z

    This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

  8. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31T23:59:59.000Z

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

  9. In situ analysis of ash deposits from black liquor combustion

    SciTech Connect (OSTI)

    Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

    1996-05-01T23:59:59.000Z

    Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

  10. Sodium and sulfur release and recapture during black liquor burning

    SciTech Connect (OSTI)

    Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

    1995-08-01T23:59:59.000Z

    The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

  11. Report on the WORKSHOP ON COMMERCIALIZATION OF BLACK LIQUOR

    E-Print Network [OSTI]

    Report on the WORKSHOP ON COMMERCIALIZATION OF BLACK LIQUOR AND BIOMASS GASIFICATION FOR GAS or industry cycle (BGCC) technologies for pulp and paper co~mitm~nt to the develo~ment of gasification systems (existing) technology with an greenhouse gas emissions mitigation measures. emerging (gasification

  12. Conceptual design of a black liquor gasification pilot plant

    SciTech Connect (OSTI)

    Kelleher, E. G.

    1987-08-01T23:59:59.000Z

    In July 1985, Champion International completed a study of kraft black liquor gasification and use of the product gases in a combined cycle cogeneration system based on gas turbines. That study indicated that gasification had high potential as an alternative to recovery boiler technology and offered many advantages. This paper describes the design of the plant, the construction of the pilot plant, and finally presents data from operation of the plant.

  13. Recovery of solvent and by-products from organosolv black liquor

    SciTech Connect (OSTI)

    Botello, J.I.; Gilarranz, M.A.; Rodriguez, F.; Oliet, M. [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica] [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica

    1999-09-01T23:59:59.000Z

    The recovery of alcohol and by-products from ethanol-water and methanol-water pulping liquors was studied. The recovery system proposed consists of three stages: black liquor flashing, lignin precipitation, and precipitation distillation of mother liquor. At the flash stage, 47 and 51% of the alcohol in the black liquor are recovered for ethanol and methanol processes, respectively. The lignin recovery yield at the precipitation stage is 67% for ethanol black liquor and 73% for methanol black liquor. The distillation of precipitation mother liquors enables recovery of 98% ethanol and 96% methanol from this stream as distillate, whereas the distillation residue contains significant amounts of sugars, furfural, and acetic acid that can be recovered. The study concludes with the overall mass balance for the recovery system proposed.

  14. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    SciTech Connect (OSTI)

    Fricke, A.L.; Zaman, A.A.

    1998-05-01T23:59:59.000Z

    The overall objective of the program was to develop correlations to predict physical properties within requirements of engineering precision from a knowledge of pulping conditions and of kraft black liquor composition, if possible. These correlations were to include those relating thermodynamic properties to pulping conditions and liquor composition. The basic premise upon which the research was based is the premise that black liquor behaves as a polymer solution. This premise has proven to be true, and has been used successfully in developing data reduction methods and in interpreting results. A three phase effort involving pulping, analysis of liquor composition, and measurement of liquor properties was conducted.

  15. Freeze crystallization technology for Kraft black liquor concentration. Third report

    SciTech Connect (OSTI)

    Johnson, W.E.; Rhodes, C.R.

    1985-04-01T23:59:59.000Z

    About 25% of the purchased energy in the pulp and paper industry is used to concentrate black liquor. The technical feasibility of using freeze concentration to supplement evaporation has been successfully demonstrated, and results indicate that energy consumption can be reduced 45%. After compiling a considerable data base on the characteristics of black liquor at low temperature and after developing a computer program to aid analysis, the process chosen was vacuum freezing-vapor absorption (VFVA). A pilot plant was built and operated; however, due to problems with crystallization of the absorbent and contamination, it was found that maintaining the conditions necessary for a continuous process was not practical at the present state of development. Therefore, indirect freezing was used for all subsequent work. This required the design and fabrication of a simple shuttle crystallizer to replace scraped surface units conventionally used. CSI also developed an integrated ice separation column that combined crystal growth, a concentration gradient, and washing all in one unit. Finally, extensive heat transfer coefficient data were collected so that a preliminary design could be completed for a 350 TPD industrial freeze concentration unit. An economic analysis was calculated in order to compare using evaporation and freeze concentration to process the increased liquor flow from a pulp mill expansion. A 200,000 lb/hr freezing unit used to preconcentrate the mill's entire stream up to 18.7% solids would save $10 to $16 per ton of pulp.

  16. DEMONSTRATION OF BLACK LIQUOR GASIFICATION AT BIG ISLAND

    SciTech Connect (OSTI)

    Robert DeCarrera

    2003-10-20T23:59:59.000Z

    This Technical Progress Report provides an account of the status of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific Corporation's Big Island, VA facility. The report also includes budget information and a milestone schedule. The project to be conducted by G-P is a comprehensive, complete commercial-scale demonstration that is divided into two phases. Phase I is the validation of the project scope and cost estimate. Phase II is project execution, data acquisition and reporting, and consists of procurement of major equipment, construction and start-up of the new system. Phase II also includes operation of the system for a period of time to demonstrate the safe operation and full integration of the energy and chemical recovery systems in a commercial environment. The objective of Phase I is to validate the process design and to engineer viable solutions to any technology gaps. This phase includes engineering and planning for the integration of the full-scale MTCI/StoneChem PulseEnhanced{trademark} black liquor steam-reformer chemical recovery system into G-P's operating pulp and paper mill at Big Island, Virginia. During this phase, the scope and cost estimate will be finalized to confirm the cost of the project and its integration into the existing system at the mill. The objective of Phase II of the project is the successful and safe completion of the engineering, construction and functional operation of the fully integrated full-scale steam reformer process system. This phase includes installation of all associated support systems and equipment required for the enhanced recovery of both energy and chemicals from all of the black liquor generated from the pulping process at the Big Island Mill. The objective also includes operation of the steam reformer system to demonstrate the ability of the system to operate reliably and achieve designed levels of energy and chemical recovery while maintaining environmental emissions at or below the limits set by the environmental permits.

  17. Ultrafiltration of Kraft Black Liquor. Final report, Phase I

    SciTech Connect (OSTI)

    Hill, M.K.

    1985-10-01T23:59:59.000Z

    Kraft Black Liquor (KBL) is ultrafiltered to favorably affect the properties of the KBL permeate. The major property to be changed is viscosity. If the high molecular weight lignin is removed by ultrafiltration, the KBL permeate should show a significant drop in viscosity. An objective of the work reported was to examine how much KBL viscosity is lowered relative to membrane and membrane pore size used in the ultrafiltration. Another objective was an initial evaluation of ultrafiltration equipment and membranes. Operating characteristics were determined for selected equipment and membranes. Decreases in KBL permeate viscosity were indeed seen. (LEW)

  18. Freeze crystallization technology for black liquor concentration. Second interim report

    SciTech Connect (OSTI)

    Not Available

    1983-07-01T23:59:59.000Z

    The pulp and paper industry is one of the largest consumers of energy. Concentration of black liquor (the stream resulting from the chemical separation of wood fibers in the pulping operation) uses 25% of the purchased energy to produce pulp, an equivalent of 33 million barrels of oil in 1982. Here it is shown that freeze concentration, an emerging concentration technology, has the potential of reducing the energy consumption by at least 45%. This amounts to a cost savings of $5 to $15 per ton of pulp depending on the cost of energy, geographical location, and method of application.

  19. A comprehensive program to develop correlations for the physical properties of kraft black liquors

    SciTech Connect (OSTI)

    Fricke, A.L.

    1990-12-01T23:59:59.000Z

    Experimental work includes pulping, liquor analysis, lignin purification and characterization, vapor-liquid equilibria, heat capacity, heats of solution and combustion, and viscosity measurements. It is now possible to operate the digester as a closed, rotating reactor or as a batch reactor with liquor circulation. When operated with liquor circulation, temperatures within the chip bed can be monitored during cooking. Cooking is reproducible, and cooks are being performed to produce liquors for experimental studies. The digester could be further modified to permit them to conduct rapid exchange batch pulping or to permit them to simulate continuous pulping. Liquors are now routinely analyzed to determine all components, except higher molecular weight organic acids and extractives. Lignin determination by UV-visible means has been improved. Lignin purification from black liquor has been improved and lignin molecular weights are determined routinely. The paper describes the digestor, the large scale evaporation, liquor analysis, thermal studies, and viscosity results. 31 figs., 5 tabs.

  20. Vapor pressure and boiling point elevation of slash pine black liquors: Predictive models with statistical approach

    SciTech Connect (OSTI)

    Zaman, A.A.; McNally, T.W.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States)] [Univ. of Florida, Gainesville, FL (United States)

    1998-01-01T23:59:59.000Z

    Vapor-liquid equilibria and boiling point elevation of slash pine kraft black liquors over a wide range of solid concentrations (up to 85% solids) has been studied. The liquors are from a statistically designed pulping experiment for pulping slash pine in a pilot scale digester with four cooking variables of effective alkali, sulfidity, cooking time, and cooking temperature. It was found that boiling point elevation of black liquors is pressure dependent, and this dependency is more significant at higher solids concentrations. The boiling point elevation data at different solids contents (at a fixed pressure) were correlated to the dissolved solids (S/(1 {minus} S)) in black liquor. Due to the solubility limit of some of the salts in black liquor, a change in the slope of the boiling point elevation as a function of the dissolved solids was observed at a concentration of around 65% solids. An empirical method was developed to describe the boiling point elevation of each liquor as a function of pressure and solids mass fraction. The boiling point elevation of slash pine black liquors was correlated quantitatively to the pulping variables, using different statistical procedures. These predictive models can be applied to determine the boiling point rise (and boiling point) of slash pine black liquors at processing conditions from the knowledge of pulping variables. The results are presented, and their utility is discussed.

  1. Ultrafiltration of Kraft Black Liquor: Phase II, Final report

    SciTech Connect (OSTI)

    Hill, M.K.

    1987-09-01T23:59:59.000Z

    The major justification for examining ultrafiltration was to lower the viscosity of the Kraft Black Liquor by recovering it as an ultrafiltration permeate from which the highest MW lignin had been removed. The liquor could then be concentrated to a higher percentage solids before firing into the recovery boiler. Consequent energy savings for the 1000 ton/day pulp mill would be 2.05 x 10 Btu/y for each percentage increase in TDS (total dissolved solids) to the recovery boiler. This Phase II report gives data on viscosity with percentage solids of KBL permeates. Another favorable effect of ultrafiltration on the permeate properties is disproportionate removal of multivalent ions including the major scaling ion CaS . If this high-viscosity high-Ca retentate could be treated to lower its viscosity and to release the Ca in a non-scaling form, this would enhance the possibility that ultrafiltration might be useful in a mill situation. Included in this report are data on the results of treating the retentate fraction. Other justifications for this program included further information in KBL properties: lignin MW in the KBL at high pH; elemental and sugar analyses; and differential properties of lignins in the retentate and the permeate fractions. A preliminary economic analysis of ultrafiltration is contained in this report. These analyses indicate that with flux rates now attainable, ultrafiltration would not be economically justified at this time if the only justification is to lower KBL viscosity. For certain situations where high Ca liquors present a scaling problem, especially in an evaporator-limited mill, the economics are more favorable. There are also unsolved problems relating to the use of the high viscosity retentate.

  2. INVESTIGATION OF FUEL CHEMISTRY AND BED PERFORMANCE IN A FLUIDIZED BED BLACK LIQUOR STEAM REFORMER

    SciTech Connect (OSTI)

    Kevin Whitty

    2003-12-01T23:59:59.000Z

    The University of Utah project ''Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer'' (DOE award number DE-FC26-02NT41490) was developed in response to a solicitation for projects to provide technical support for black liquor and biomass gasification. The primary focus of the project is to provide support for a DOE-sponsored demonstration of MTCI's black liquor steam reforming technology at Georgia-Pacific's paper mill in Big Island, Virginia. A more overarching goal is to improve the understanding of phenomena that take place during low temperature black liquor gasification. This is achieved through five complementary technical tasks: (1) construction of a fluidized bed black liquor gasification test system, (2) investigation of bed performance, (3) evaluation of product gas quality, (4) black liquor conversion analysis and modeling and (5) computational modeling of the Big Island gasifier. Four experimental devices have been constructed under this project. The largest facility, which is the heart of the experimental effort, is a pressurized fluidized bed gasification test system. The system is designed to be able to reproduce conditions near the black liquor injectors in the Big Island steam reformer, so the behavior of black liquor pyrolysis and char gasification can be quantified in a representative environment. The gasification test system comprises five subsystems: steam generation and superheating, black liquor feed, fluidized bed reactor, afterburner for syngas combustion and a flue gas cooler/condenser. The three-story system is located at University of Utah's Industrial Combustion and Gasification Research Facility, and all resources there are available to support the research.

  3. Kinetics of gasification of black liquor char by steam

    SciTech Connect (OSTI)

    Li, J.; van Heiningen, A.R.P. (Dept. of Chemical Engineering, McGill Univ., Pulp and Paper Research Inst. of Canada, Montreal, Quebec (CA))

    1991-07-01T23:59:59.000Z

    This paper reports on the steam gasification kinetics of kraft black liquor char that were studied in a thermogravimetric analysis reactor. The effect of steam and hydrogen concentration on gasification rate can be described by Langmuir-Hinshelwood type kinetics. An activation energy of 210 kJ/mol was obtained. Methane formation was negligible, and H{sub 2}S was the major gaseous sulfur-containing product obtained over the temperature range studied, 873-973 K. The CO{sub 2} concentration was higher than calculated for the water-shift reaction at equilibrium. A gasification mechanism is proposed whereby CO{sub 2} is one of the primary gasification products.

  4. Effect of sulfidity on the corrosivity of white, green, and black liquors

    SciTech Connect (OSTI)

    Wensley, A.; Champagne, P.

    1999-07-01T23:59:59.000Z

    Corrosion testing was performed in white, green, and black liquors from a kraft mill. The liquors were modified in composition to simulate conditions of high (40%) sulfidity and low (30%) sulfidity, and then heated in laboratory autoclaves to the temperatures of the respective tanks from which the samples were taken. Specimens of carbon and stainless steels were exposed under free corrosion potential conditions, and their corrosion rates determined from weight loss measurements. In white, green, 45% solids black, and flash tank liquors, active corrosion rates for the carbon steels were typically 20 to 75% higher in the higher sulfidity liquors. In 15% solids weak black liquor there was no appreciable difference in corrosion rates, with carbon steels remaining passive in both low and high sulfidity. In 26% solids intermediate black liquor there were large increases in the corrosion rates of carbon steel between low and high sulfidity liquors, resulting from a change from passive to active conditions. Stainless steels UNS S30403, S32304, and S31803 had very low corrosion rates in all the liquors tested, regardless of sulfidity.

  5. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30T23:59:59.000Z

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  6. Low temperature pyrolysis of black liquor and polymerization of products in alkali aqueous medium

    SciTech Connect (OSTI)

    Demirbas, A. (Dept. of Chemical Education, Karadeniz Teknik Univ., Trabzon (TR)); Ucan, H. (Dept. of Chemistry, Selcuk Univ., Konya (TR))

    1991-01-01T23:59:59.000Z

    Atmospheric pressure pyrolysis for the production of liquids and gases from black liquor and its calcium salts and acidic precipitate have been carried out in a little stainless steel tube. Yields, sum of liquid and gas products, from black liquor and its calcium salts and acidic precipitate were 44.7%, 52.0% and 59.1% of dry basis respectively. The precipitates obtained from black liquor by acidifying with hydrochloric acid and passing carbon dioxide have been polymerized in aqueous acetone containing formaldehyde and ammonia, and converted a polymeric resin.

  7. Energy considerations for steam plasma gasification of black liquor and chemical recovery

    SciTech Connect (OSTI)

    Grandy, J.D.; Kong, P.C.

    1995-10-01T23:59:59.000Z

    This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which bums the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

  8. Energy considerations for steam plasma gasification of black liquor and chemical recovery

    SciTech Connect (OSTI)

    Grandy, J.D.; Kong, P.C. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1995-07-01T23:59:59.000Z

    This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which burns the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

  9. Biomass gasification project gets funding to solve black liquor safety and landfill problems

    SciTech Connect (OSTI)

    Black, N.P.

    1991-02-01T23:59:59.000Z

    This paper reports on biomass gasifications. The main by-product in pulp making is black liquor from virgin fiber; the main by-product in paper recycling is fiber residue. Although the black liquor is recycled for chemical and energy recovery, safety problems plague the boilers currently used to do this. The fiber residue is usually transported to a landfill. The system being developed by MTCI will convert black liquor and fiber residue into a combustible gas, which can then be used for a wide variety of thermal or power generation applications.

  10. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    SciTech Connect (OSTI)

    Fricke, A.L.; Zaman, A.A.; Stoy, M.O.; Schmidl, G.W.; Dong, D.J.; Speck, B.

    1998-04-01T23:59:59.000Z

    A wide variety of experimental techniques have been used in this work, and many of these have been developed completely or improved significantly in the course of the research done during this program. Therefore, it is appropriate to describe these techniques in detail as a reference for future workers so that the techniques can be used in future work with little additional effort or so that the results reported from this program can be compared better with future results from other work. In many cases, the techniques described are for specific analytical instruments. It is recognized that these may be superseded by future developments and improvements in instrumentation if a complete description of techniques used successfully in the past on other instrumentation is available. The total pulping and liquor preparation research work performed included chip and white liquor preparation, digestion, pulp washing, liquor and wash recovery, liquor sampling, weak liquor concentration in two steps to about 45--50% solids with an intermediate soap skimming at about 140F and 27--30% solids, determination of pulp yield and Kappa number, determination of total liquor solids, and a check on the total material balance for pulping. All other research was performed either on a sample of the weak black liquor (the combined black liquor and washes from the digester) or on the skimmed liquor that had been concentrated.

  11. Swelling of kraft black liquor: an understanding of the associated phenomena during pyrolysis

    SciTech Connect (OSTI)

    Miller, P.T.

    1986-01-01T23:59:59.000Z

    The objectives of this thesis were to quantify the swelling of black liquor during pyrolysis in a nitrogen atmosphere and to determine what factors were responsible for swelling. The first part of the investigation studied the process variables: pyrolysis temperature, solid content, heating rate and particle size. A temperature of 500/sup 0/C resulted in maximum swelling for the investigated temperature range of 300-900/sup 0/C. The swelling of black liquor occurred during the evolution of pyrolysis gases; however, there was no correlation found between the amount of pyrolysis gases evolved and the change in char volume. The initial solid content of black liquor had a small influence on the swelling of black liquor. The heating rate was found to effect the rate of swelling but not the final volume. Particle size had no effect on the swollen volume per unit particle weight. The effect of black liquor composition was studied. An interaction between sugar acids and kraft lignin was responsible for swelling. The extractives interfered with the swelling mechanism of black liquor, while inorganic salts acted as a diluent. The swelling behavior of black liquor appeared to be dictated by the surface active and viscous forces present in black liquor during pyrolysis. Surface active forces were evidenced by the formation of small bubbles (50-150 microns in diameter) which appeared necessary for highly swollen chars. Low swelling chars did not exhibit this phenomenon. Bubble formation began at 250/sup 0/C, which closely corresponded to the thermal decomposition temperature of sugar acids. The sugar acids formed bubbles when pyrolyzed but did not swell significantly during pyrolysis. Kraft lignin appeared to enhance the swelling of the sugar acids by increasing the viscosity and stabilizing the bubbles during pyrolysis.

  12. A comprehensive program to develop correlations for the physical properties of kraft black liquors. Interim report No.3

    SciTech Connect (OSTI)

    Fricke, A.L.; Dong, D.J.; Schmidl, G.W.; Stoy, M.A.; Zaman, A.A.

    1993-09-01T23:59:59.000Z

    The black liquor properties program has conducted a systematic collection data of properties, liquor composition, and lignin characteristics. Complete data, except for some density data, has been collected for Slash Pine black liquors made by experimental pulping at a total of 25 different pulping conditions that cover the entire range used for commercial pulping. In addition, complete data has been collected for some mill liquors and partial properties or composition data has been collected on Slash Pine black liquors made at 16 different pulping conditions and some mill liquors. Data reduction methods have been developed or extended for correlation of viscosity, heat capacity, heat of dilution, and density. Correlation of properties to pulping conditions and of composition to pulping conditions has begun. In most cases, data reduction methods have been developed that are fundamentally based and that have been shown to be generally applicable to all black liquors. While it has not proven to be possible to include research for comprehensive correlations for properties for liquors from other species, we have shown that the behavior of liquors made from other species is similar to that which has been explored extensively for Slash Pine liquors. This report reviews the methods used, describes examples of data reduction methods that have been developed, and presents some preliminary results for correlation of liquor composition and properties to pulping conditions for Slash Pine black liquors.

  13. Effect of pulsation on black liquor gasification. Final report

    SciTech Connect (OSTI)

    Zinn, B.T.; Jagoda, J.; Jeong, H.; Kushari, A.; Rosen, L.J.

    1998-12-01T23:59:59.000Z

    Pyrolysis is an endothermic process. The heat of reaction is provided either by partial combustion of the waste or by heat transfer from an external combustion process. In one proposed system black liquor is pyrolized in a fluidized bed to which heat is added through a series of pulse combustor tail pipes submerged in the bed material. This system appears promising because of the relatively high heat transfer in pulse combustors and in fluidized beds. Other advantages of pulse combustors are discussed elsewhere. The process is, however, only economically viable if a part of the pyrolysis products can be used to fire the pulse combustors. The overall goals of this study were to determine: (1) which is the limiting heat transfer rate in the process of transferring heat from the hot combustion products to the pipe, through the pipe, from the tail pipe to the bed and through the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the heat transfer benefits of the pulse combustor can be utilized while maintaining the temperature in the bed within the narrow temperature range required by the process without generating hot spots in the bed; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

  14. Research on droplet formation for application to kraft black liquors: Final report: Tasks I and III, report No. 4

    SciTech Connect (OSTI)

    Stockel, I.H.

    1988-10-01T23:59:59.000Z

    The overall objective of this project is to generate technical data with which to design nozzles for kraft black liquor recovery boilers which can reduce under and over size droplets and adjust for changing black liquor properties and production requirements. The research is organized into five tasks: Droplet formation from a single jet, theoretical and experimental--ambient gas medium; Surface tensions of black liquor; Aerodynamic/hydrodynamic stability/instability of droplets once formed; Black liquor droplet formation from a single jet--furnace gas medium; Prototype of a new nozzle design. 88 figs.

  15. Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery

    SciTech Connect (OSTI)

    Adriaan van Heiningen

    2007-06-30T23:59:59.000Z

    MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of the conversion of Na{sub 2}CO{sub 3} to (high sodium) titanates during gasification of black liquor in the presence of (low sodium) titanates or TiO{sub 2} (Task 2). MTCI/ThermoChem tested the performance and operability of the combined technology of steam reforming and direct causticization in their Process Development Unit (PDU) (Task 3). The specific objectives were: (1) to investigate how split sulfidity and polysulfide (+ AQ) pulping can be used to increase pulp fiber yield and properties compared to conventional kraft pulping; (2) to determine the economics of black liquor gasification combined with these pulping technologies in comparison with conventional kraft pulping and black liquor recovery; (3) to determine the effect of operating conditions on the kinetics of the titanate-based direct causticization reaction during black liquor gasification at relatively low temperatures ({le} 750 C); (4) to determine the mechanism of particle agglomeration during gasification of black liquor in the presence of titanates at relatively low temperatures ({le} 750 C); and (5) to verify performance and operability of the combined technology of steam reforming and direct causticization of black liquor in a pilot scale fluidized bed test facility.

  16. A comprehensive program to develop correlations for the physical properties of Kraft black liquor. Interim report No. 3

    SciTech Connect (OSTI)

    Fricke, A.L.; Dong, D.J.; Schmidl, G.W.; Stoy, M.A.; Zaman, A.A.

    1993-09-01T23:59:59.000Z

    The black liquor properties program has been conducted over this last period so as to systematically collect data on properties, liquor composition, and lignin characteristics very carefully by methods that have developed during this program. Complete data has been collected for Slash Pine black liquors made by experimental pulping at different pulping conditions. In addition, data has been collected for mill liquors and partial properties or composition data has been collected on Slash Pine black liquors. Data reduction methods have been developed or extended for correlation of viscosity, heat capacity, heat of dilution, and density. Correlation of properties to pulping conditions and of composition to. pulping conditions has begun. In most cases, data reduction methods have been developed that are fundamentally based and that have been shown to be generally applicable to all black liquors. In the near future, we fully expect to accomplish our goal of developing generalized correlations relating physical properties of Slash Pine kraft black liquors to liquor composition. This interim report reviews the methods used, describes examples of data reduction methods that have been developed, and presents some preliminary results for correlation of liquor composition and properties to pulping conditions for Slash Pine black liquors.

  17. Physical properties of kraft black liquor: Summary report, Phases 1 and 2

    SciTech Connect (OSTI)

    Fricke, A.L.

    1987-09-01T23:59:59.000Z

    Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work.

  18. Improved Materials for High-Temperature Black Liquor Gasification

    SciTech Connect (OSTI)

    Keiser, J.R.; Hemrick, J.G.; Gorog, J.P.; Leary, R.

    2006-06-29T23:59:59.000Z

    The laboratory immersion test system built and operated at ORNL was found to successfully screen samples from numerous refractory suppliers, including both commercially available and experimental materials. This system was found to provide an accurate prediction of how these materials would perform in the actual gasifier environment. Test materials included mullites, alumino-silicate bricks, fusion-cast aluminas, alumina-based and chrome-containing mortars, phosphate-bonded mortars, coated samples provided under an MPLUS-funded project, bonded spinels, different fusion-cast magnesia-alumina spinels with magnesia content ranging from 2.5% to about 60%, high-MgO castable and brick materials, spinel castables, and alkali-aluminate materials. This testing identified several candidate material systems that perform well in the New Bern gasifier. Fusion-cast aluminas were found to survive for nearly one year, and magnesia-alumina spinels have operated successfully for 18 months and are expected to survive for two years. Alkali-aluminates and high-MgO-content materials have also been identified for backup lining applications. No other material with a similar structure and chemical composition to that of the fusion-cast magnesium-aluminum spinel brick currently being used for the hot-face lining is commercially available. Other materials used for this application have been found to have inferior service lives, as previously discussed. Further, over 100 laboratory immersion tests have been performed on other materials (both commercial and experimental), but none to date has performed as well as the material currently being used for the hot-face lining. Operating experience accumulated with the high-temperature gasifier at New Bern, North Carolina, has confirmed that the molten alkali salts degrade many types of refractories. Fusion-cast alumina materials were shown to provide a great improvement in lifetime over materials used previously. Further improvement was realized with fusion-cast magnesia-alumina spinel refractory, which appears to be the most resistant to degradation found to date, exhibiting over a year of service life and expected to be capable of over two years of service life. Regarding the use of refractory mortar, it was found that expansion of the current chrome-alumina mortar when subjected to black liquor smelt is likely contributing to the strains seen on the vessel shell. Additionally, the candidate high-alumina mortar that was originally proposed as a replacement for the current chrome-alumina mortar also showed a large amount of expansion when subjected to molten smelt. A UMR experimental mortar, composed of a phosphate bonded system specifically designed for use with fusion-cast magnesium-aluminum spinel, was found to perform well in the molten smelt environment. Strain gauges installed on the gasifier vessel shell provided valuable information about the expansion of the refractory, and a new set of strain gauges and thermocouples has been installed in order to monitor the loading caused by the currently installed spinel refractory. These results provide information for a direct comparison of the expansion of the two refractories. Measurements to date suggest that the fusion-cast magnesia-alumina spinel is expanding less than the fusion-cast {alpha}/{beta}-alumina used previously. A modified liquor nozzle was designed and constructed to test a number of materials that should be more resistant to erosion and corrosion than the material currently used. Inserts made of three erosion-resistant metallic materials were fabricated, along with inserts made of three ceramic materials. The assembled system was sent to the New Bern mill for installation in the gasifer in 2005. Following operation of the gasifier using the modified nozzle, inserts should be removed and analyzed for wear by erosion/corrosion. Although no materials have been directly identified for sensor/thermocouple protection tubes, several of the refractory material systems identified for lining material applications may be applicable for use in this

  19. Research on droplet formation for application to kraft black liquors---Final project report

    SciTech Connect (OSTI)

    Bousfield, D.W.

    1990-01-01T23:59:59.000Z

    The objective of this project was to generate technical data to guide the design of new nozzles for kraft black liquor recovery boilers. The goal of new nozzle designs would be to narrow the droplet size distribution compared to current nozzles and to adjust for changing black liquor properties and production requirements. Uniform droplets in a recovery boiler should reduce fouling of superheater tubes and caused a more efficient burning of the black liquor, both of which result in improved energy efficiency. The research was organized into five tasks which are described in the next chapter. This fifth and final project report contains the details of Task 4 and 5 and further analysis of Task 1 results. The details of the other tasks are reported in previous technical reports. The major results from the entire project are highlighted in this section in order of significance.

  20. Fuel nitrogen release during black liquor pyrolysis; Part 1: Laboratory measurements at different conditions

    SciTech Connect (OSTI)

    Aho, K.; Vakkilainen, E. (A. Ahistrom Corp., Varkaus (Finland)); Hupa, M. (Abo Akademi Univ., Turku (Finland). Chemical Engineering Dept.)

    1994-05-01T23:59:59.000Z

    Fuel nitrogen release during black liquor pyrolysis is high. There is only minor release during the drying stage. Ammonia is the main fixed nitrogen species formed. The rate of fixed nitrogen release increases with increasing temperature. The level of fixed nitrogen released by birch liquor is almost twice the level for pine liquor. Assuming complete conversion to NO, fixed nitrogen yields gave NO concentrations near typically measured values for flue gases in full scale recovery boilers. The purpose of this work was to gain more detailed information about the behavior of the fuel nitrogen in black liquor combustion. The work focused on the pyrolysis or devolatilization of the combustion process. Devolatilization is the stage at which the majority (typically 50--80%) of the liquor organics release from a fuel particle or droplet as gaseous species due to the rapid destruction of the organic macromolecules in the liquor. In this paper, the authors use the terms devolatilization and pyrolysis interchangeably with no difference in their meaning.

  1. High-solids black liquor firing in pulp and paper industry kraft recovery boilers. Quarterly report, Phase 1a: Black liquor gasifier evaluation

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    This project phase addresses the following workscope: Conduct bench-scale tests of a low temperature, partial combustion gasifier; Prepare a gasifier pilot-plant preliminary design and cost estimate and prepare a budgetary cost estimate of the balance of the program; Outline a test program to evaluate gasification; Prepare an economic/market analysis of gasification and solicit pulp and paper industry support for subsequent phases; and Prepare a final report and conduct a project review prior to commencement of work leading to construction of any pilot scale components or facilities. The primary accomplishments included completion of installation of the bench-scale black liquor gasifier and supporting systems, preparing test plans and related safety procedures and detailed operating procedures, defining the functional design requirements and outlining the test plans for the pilot-scale gasifier, and preparing a preliminary economic assessment of the black liquor gasifier. This work accomplished under Phase 1a during this period is further described by task.

  2. Formation of fuel NO[sub x] during black-liquor combustion

    SciTech Connect (OSTI)

    Nichols, K.M. (Weyerhaeuser Paper Co., Tacoma, WA (United States)); Lien, S.J. (Inst. of Paper Science and Technology, Atlanta, GA (United States))

    1993-03-01T23:59:59.000Z

    Fuel NOx and thermal NOx were measured in combustion gases from black liquors in two laboratory furnaces. Combustion at 950 C in air (8% O[sub 2]) produced NOx concentrations of 40-80ppm. Combustion at 950 C in synthetic air containing no nitrogen (21% 0[sub 2] in Ar) produced the same result, demonstrating that all of the NOx produced during combustion at 950 C was fuel NOx. Formation of fuel NOx increased moderately with increasing temperature in the range of 800-1,000 C, but temperature sensitivity of fuel NOx was much less than that of thermal NOx. The results imply that the major source of NOx in recovery furnace emissions is the fuel NOx in recovery furnace formed by conversion of liquor-bound nitrogen during combustion. This is consistent with thermal NOx theory, which postulates that black-liquor combustion temperatures are too low to generate significant amounts of thermal NOx.

  3. Separation of kraft lignin from kraft black liquor: Final report, July 1984-April 1987

    SciTech Connect (OSTI)

    Kurple, K.R.

    1988-04-15T23:59:59.000Z

    All the objectives were accomplished: a high-quality kraft lignin containing less than 50 ppM sodium was separated into a solvent phase (freon) from as much as 1000 lb kraft black liquor. Supporting data (infrared spectra, chemical analyses, etc.) are included. (DLC)

  4. Coliquefaction of coal and black liquor to environmentally acceptable liquid fuels

    SciTech Connect (OSTI)

    Kim, J. [Korea Inst. of Energy Research, Taejon (Korea, Republic of); Lalvani, S.B.; Muchmore, C.B.; Akash, B.A. [Southern Illinois Univ., Carbondale, IL (United States)

    1999-11-01T23:59:59.000Z

    Previous work in the laboratories has demonstrated that addition to lignin to coal during liquefaction significantly increases the depolymerization of coal and enhances the quality of the liquid products. It is believed that thermolysis of the lignin results in the formation of phenoxyl and other reactive radicals at temperatures too low for significant thermolysis of the coal matrix; such radicals are effective and active intermediates that depolymerize coal by cleaving methylene bridges. It has been reported that alkali is also effective for extraction of liquids from coal. The work presented here combines these two reactive agents by utilizing the black liquor waste stream from the Kraft pulping process for coal depolymerization. That waste stream contains large amounts of lignin and sodium hydroxide, as well as other components. To permit comparative evaluations of the extent of coal depolymerization by coprocessing coal and black liquor, reference runs were performed with tetralin alone, sodium hydroxide in tetralin, and lignin in tetralin. Results indicated that the sodium hydroxide-tetralin system resulted in almost 67% conversion at 375 C, 1 hour. The black liquor system exhibited a lower conversion of 60%, indicating some inhibition of the depolymerization reactions by components in the black liquor.

  5. BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS

    E-Print Network [OSTI]

    BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS ERIC D. LARSON modeling of gasifier/gas turbine pulp-mill cogeneration systemsusing gasifier designs under commercial gasification. The use of biomass fuels with gas turbines could transform a typical pulp mill from a net

  6. Energy conservation in black-liquor evaporator of pulp and paper industry

    SciTech Connect (OSTI)

    Agarwal, V.K.; Gupta, S.C. [Univ. of Roorkee (India). Dept. of Chemical Engineering

    1995-12-31T23:59:59.000Z

    This paper is an attempt on energy conservation in a quintuple effect evaporator used to concentrate dilute black liquor solution by raising their steam economy through the changes in the operating variables. It also describes the steam economy of the evaporator for the various feed arrangements so as to determine the ranges of the variables for which evaporation occurs profitable.

  7. Assessment of the release of atomic Na from a burning black liquor droplet using quantitative PLIF

    SciTech Connect (OSTI)

    Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The Environment Institute, School of Mechanical Engineering, The University of Adelaide, SA 5005 (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The Environment Institute, School of Chemical Engineering, The University of Adelaide, SA 5005 (Australia)

    2009-07-15T23:59:59.000Z

    The quantitative measurement of atomic sodium (Na) release, at high concentration, from a burning black liquor droplet has been demonstrated using a planar laser-induced fluorescence (PLIF) technique, corrected for fluorescence trapping. The local temperature of the particle was measured to be approximately 1700 C, at a height of 10 mm above a flat flame burner. The PLIF technique was used to assess the temporal release of atomic Na from the combustion of black liquor and compare it with the Na concentration in the remaining smelt. A first-order model was made to provide insight using a simple Plug Flow Reactor model based on the independently measured concentration of residual Na in the smelt as a function of time. This model also required the dilution ratio of the combustion products in the flat flame entrained into the plume gas from the black liquor particle to be estimated. The key findings of these studies are: (i) the peak concentration of atomic Na from the combustion of the black liquor droplets is around 1.4 ppm; (ii) very little atomic Na is present during the drying, devolatilisation or char combustion stages; and (iii) the presence of atomic Na during smelt phase dominates over that from the other combustion stages. (author)

  8. Black liquor viscosity reduction through salt additives: A novel environmentally benign processing alternative

    SciTech Connect (OSTI)

    Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)

    1996-10-01T23:59:59.000Z

    Processing black liquor at high solids would reduce SO{sub x} emissions, facilitate the use of non-chlorine bleaching techniques and enhance the energy efficiency of the pulping process. However, black liquor exhibits and exponential increase in viscosity as its solids content rises, thus hindering its processability in the composition range of interest (>70% solids). In this study, we present a new approach for controlling viscosity at high solids content by {open_quotes}salting in{close_quotes} black liquor through addition of thiocyanate salts. These salts increases the solubility of the polymer constituents in black liquor leading to a decrease in its viscosity. Several salts capable of viscosity reduction by as much as two orders of magnitude have been identified. The effects of cation size, solution pH and temperature on viscosity reduction is presented and interpreted in terms of the underlying principles of {open_quotes}salting in{close_quotes} and how it affects aqueous solution structure.

  9. Physical properties of kraft black liquor. Final report. Phase I

    SciTech Connect (OSTI)

    Fricke, A.L.

    1983-12-01T23:59:59.000Z

    Methods were selected, equipment installed, and procedures developed for determining rheological properties; for determining thermal properties (stability, density, thermal expansion, and heat capacity); for purification and characterization of lignin (glass transition, stability, weight average molecular weight, and number average molecular weight); and for performing chemical analyses (negative inorganic ions, positive inorganic ions, acid organic salts, lignin, and total solids). A strategy for pulping to supply test liquors was developed, and a statistically designed pulping experiment was specified for a Southern softwood species. Arrangements were made for performing initial pulping work in an industrial pilot plant, and a preliminary set of pulping experiments were conducted. Liquors from the preliminary pulping experiments were used to test procedures and to determine reproducibility of the experiment. Literature was also surveyed and preliminary selection of designs for a pilot digester, and for equipment to determine surface tension were made.

  10. Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment

    SciTech Connect (OSTI)

    Kevin Whitty

    2008-06-30T23:59:59.000Z

    The University of Utah's project 'Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment' (U.S. DOE Cooperative Agreement DE-FC26-04NT42261) was a response to U.S. DOE/NETL solicitation DE-PS36-04GO94002, 'Biomass Research and Development Initiative' Topical Area 4-Kraft Black Liquor Gasification. The project began September 30, 2004. The objective of the project was to improve the understanding of black liquor conversion in high pressure, high temperature reactors that gasify liquor through partial oxidation with either air or oxygen. The physical and chemical characteristics of both the gas and condensed phase were to be studied over the entire range of liquor conversion, and the rates and mechanisms of processes responsible for converting the liquor to its final smelt and syngas products were to be investigated. This would be accomplished by combining fundamental, lab-scale experiments with measurements taken using a new semi-pilot scale pressurized entrained-flow gasifier. As a result of insufficient availability of funds and changes in priority within the Office of Biomass Programs of the U.S. Department of Energy, the research program was terminated in its second year. In total, only half of the budgeted funding was made available for the program, and most of this was used during the first year for construction of the experimental systems to be used in the program. This had a severe impact on the program. As a consequence, most of the planned research was unable to be performed. Only studies that relied on computational modeling or existing experimental facilities started early enough to deliver useful results by the time to program was terminated Over the course of the program, small scale (approx. 1 ton/day) entrained-flow gasifier was designed and installed at the University of Utah's off-campus Industrial Combustion and Gasification Research Facility. The system is designed to operate at pressures as high as 32 atmospheres, and at temperatures as high as 1500 C (2730 F). Total black liquor processing capacity under pressurized, oxygen-blown conditions should be in excess of 1 ton black liquor solids per day. Many sampling ports along the conversion section of the system will allow detailed analysis of the environment in the gasifier under industrially representative conditions. Construction was mostly completed before the program was terminated, but resources were insufficient to operate the system. A system for characterizing black liquor sprays in hot environments was designed and constructed. Silhouettes of black liquor sprays formed by injection of black liquor through a twin fluid (liquor and atomizing air) nozzle were videoed with a high-speed camera, and the resulting images were analyzed to identify overall characteristics of the spray and droplet formation mechanisms. The efficiency of liquor atomization was better when the liquor was injected through the center channel of the nozzle, with atomizing air being introduced in the annulus around the center channel, than when the liquor and air feed channels were reversed. Atomizing efficiency and spray angle increased with atomizing air pressure up to a point, beyond which additional atomizing air pressure had little effect. Analysis of the spray patterns indicates that two classifications of droplets are present, a finely dispersed 'mist' of very small droplets and much larger ligaments of liquor that form at the injector tip and form one or more relatively large droplets. This ligament and subsequent large droplet formation suggests that it will be challenging to obtain a narrow distribution of droplet sizes when using an injector of this design. A model for simulating liquor spray and droplet formation was developed by Simulent, Inc. of Toronto. The model was able to predict performance when spraying water that closely matched the vendor specifications. Simulation of liquor spray indicates that droplets on the order 200-300 microns can be expected, and that higher liquor flow will result in be

  11. Black liquor combustion validated recovery boiler modeling, five-year report

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01T23:59:59.000Z

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  12. Final technical report. In-situ FT-IR monitoring of a black liquor recovery boiler

    SciTech Connect (OSTI)

    James Markham; Joseph Cosgrove; David Marran; Jorge Neira; Chad Nelson; Peter Solomon

    1999-05-31T23:59:59.000Z

    This project developed and tested advanced Fourier transform infrared (FT-IR) instruments for process monitoring of black liquor recovery boilers. The state-of-the-art FT-IR instruments successfully operated in the harsh environment of a black liquor recovery boiler and provided a wealth of real-time process information. Concentrations of multiple gas species were simultaneously monitored in-situ across the combustion flow of the boiler and extractively at the stack. Sensitivity to changes of particulate fume and carryover levels in the process flow were also demonstrated. Boiler set-up and operation is a complex balance of conditions that influence the chemical and physical processes in the combustion flow. Operating parameters include black liquor flow rate, liquor temperature, nozzle pressure, primary air, secondary air, tertiary air, boiler excess oxygen and others. The in-process information provided by the FT-IR monitors can be used as a boiler control tool since species indicative of combustion efficiency (carbon monoxide, methane) and pollutant emissions (sulfur dioxide, hydrochloric acid and fume) were monitored in real-time and observed to fluctuate as operating conditions were varied. A high priority need of the U.S. industrial boiler market is improved measurement and control technology. The sensor technology demonstrated in this project is applicable to the need of industry.

  13. Combustion processes in black liquor recovery: Analysis and interpretation of combustion rate data and an engineering design model

    SciTech Connect (OSTI)

    Fredrick, W.J.

    1990-03-01T23:59:59.000Z

    The overall objective of this project is to develop computational models for predicting the combustion times for black liquor droplets in a recovery furnace environment. These models are needed as an important component of large-scale, global recovery boiler models. The work is divided into two tasks: interpretation of experimental black liquor single droplet combustion data from two laboratories; and formulation and evaluation of computational models for the stages of combustion of black liquor droplets. This report contains the results of the project. 109 refs., 64 figs., 12 tabs.

  14. National Dioxin Study Tier 4 - combustion sources: final test report - Site 8, Black-liquor boiler BLB-C

    SciTech Connect (OSTI)

    Jamgochian, C.L.; Keller, L.E.

    1987-04-01T23:59:59.000Z

    This report summarizes the results of a dioxin/furan emissions test of a black-liquor recovery boiler equipped with a drybottom electrostatic precipitator for particulate emissions control. Black-liquor recovery boilers are used at kraft pulp mills to produce process steam and to reclaim inorganic chemicals from spent wood pulping liquors. The dioxin/furan emissions test was conducted under Tier 4 of the National Dioxin Study. The primary objective of Tier 4 is to determine if various combustion sources are sources of dioxin and/or furan emissions. If any of the combustion sources are found to emit dioxin or furan, the secondary objective of Tier 4 is to quantify these emissions. Black-liquor recovery boilers are one of 8 combustion-source categories that have been tested in the Tier 4 program. The tested black-liquor boiler, BLB-C, was selected for the test after an initial information screening and a one-day pretest survey visit. Boiler BLB-C is considered representative of black-liquor recovery boilers with dry-bottom electrostatic precipitators. The amount of chloride present in the black-liquor circuit at this site is considered intermediate to high relative to that found at other kraft pulp mills. Data presented in the report include dioxin (tetra through octa homologue +2378 TCDD) and furan (tetra through octa homologue +2378 TCDF) results for both stack samples and ash samples. In addition, process data collected during sampling are also presented.

  15. Fundamental Study of Black Liquor Gasification Kinetics. Quarterly progress report for the period October 1999 to December 1999

    SciTech Connect (OSTI)

    NONE

    2000-01-31T23:59:59.000Z

    The overall objective of this research is to evaluate the kinetics of gasification of kraft black liquor under laboratory conditions simulating pressurized, oxygen-blown gasification. The significant independent variables are gasifier temperature, black liquor composition particle size, and particle residence time. The authors will quantify their impact on the concentration of major and trace gas phase species, as well as the composition of condensed phase inorganic products, including specification of the Na- and S-containing compounds and overall carbon conversion.

  16. Development of viscometers for kraft black liquor. Summary report, Phase 2 and 2A

    SciTech Connect (OSTI)

    Fricke, A.L.; Crisalle, O.D.

    1996-11-01T23:59:59.000Z

    This report documents the results of the evaluation of the on-line prototype viscometers for kraft black liquors carried out at the Pilot Plant facilities of the University of Florida. The original plan called for the evaluation of five prototype on-line viscometers along with laboratory bench versions. At a later stage in the project an additional experimental prototype under development at Southwest Research Institute was added. The viscometers are evaluated for accuracy and repeatability under varying process conditions, such as black liquor species, solids content, temperature, flow rate, and contaminants, as well as for maintenance and reliability. This document reports extensive results of the evaluations and recommendations for design modifications and for the installation of the instruments in industrial pulping mills for further field evaluations in Phase 3 of the project. The report also documents relevant details of the final design of the pilot flow loop used to support the experiments.

  17. Comparison of Refractory Performance in Black Liquor Gasifiers and a Smelt Test System

    SciTech Connect (OSTI)

    Peascoe, RA

    2001-09-25T23:59:59.000Z

    Prior laboratory corrosion studies along with experience at the black liquor gasifier in New Bern, North Carolina, clearly demonstrate that serious material problems exist with the gasifier's refractory lining. Mullite-based and alumina-based refractories used at the New Bern facility suffered significant degradation even though they reportedly performed adequately in smaller scale systems. Oak Ridge National Laboratory's involvement in the failure analysis, and the initial exploration of suitable replacement materials, led to the realization that a simple and reliable, complementary method for refractory screening was needed. The development of a laboratory test system and its suitability for simulating the environment of black liquor gasifiers was undertaken. Identification and characterization of corrosion products were used to evaluate the test system as a rapid screening tool for refractory performance and as a predictor of refractory lifetime. Results from the test systems and pl ants were qualitatively similar.

  18. Pulsed combustion process for black liquor gasification. Second annual report, [November 1990--February 1992

    SciTech Connect (OSTI)

    Not Available

    1993-02-01T23:59:59.000Z

    This second annual report summarizes the work accomplished during the period November 1990 through February 1992 for DOE Cooperative Agreement No. DE-FC05-90CE40893. The overall project objective is to field test an energy-efficient, innovative black liquor recovery system at a significant industrial scale. This is intended to demonstrate the maturity of the technology in an industrial environment and serve as an example to the industry of the safer and more energy-efficient processing technique. The project structure is comprised of three primary activities: process characterization testing, scale-up hardware development, and field testing. The objective of the process characterization testing was to resolve key technical issues regarding the black liquor recovery process that were identified during earlier laboratory verification tests. This was intended to provide a sound engineering data base for the design, construction and testing of a nominal 1.0 TPH integrated black liquor recovery gasifier. The objective of the scale-up hardware development effort was to ensure that key hardware components, in particular the pulse heater module, would perform reliably and safely in the field. Finally, the objective of the field test is to develop an industrial data base sufficient to demonstrate the capabilities and performance of the operating system with respect to thermal efficiency, product quality, fuel handling, system control, reliability and cost. These tests are to provide long-term and continuous operating data at a capacity unattainable in the bench-scale apparatus.

  19. Feasibility of black liquor gasification in combined cycle cogeneration. Final report, Phase I

    SciTech Connect (OSTI)

    Kelleher, E.G.

    1983-06-30T23:59:59.000Z

    A small-scale test program of 65% solids black liquor gasification was conducted in the bench-scale molten salt gasifier. Nine tests were performed using both air and oxygen as the oxidant. The black liquor gasified readily and the product gas had a dry-basis heating value of 70 Btu/scf with air and about 250 Btu/scf with oxygen. These values were almost identical to values predicted on the basis of thermodynamic equilibrium in the gas phase, indicating that the system had achieved near-equilibrium. However, the reduction of the melt to sodium sulfide was generally low. An independent research program aimed at improving the performance of air-blown black liquor gasification was conducted. That work resulted in a modified gasifier system design which increased the off-gas heating value to 120 Btu/scf and the reduction of the melt to over 95%. This was an improvement that would potentially allow use of the scrubbed product gas as a feed to a combustion gas turbine without prior enrichment.

  20. Combined biomass and black liquor gasifier/gas turbine cogeneration at pulp and paper mills

    SciTech Connect (OSTI)

    Larson, E.D.; Kreutz, T.G. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies; Consonni, S. [Politecnico di Milano, Milan (Italy). Dipt. di Energetica

    1999-07-01T23:59:59.000Z

    Kraft pulp and paper mills generate large quantities of black liquor and byproduct biomass suitable for gasification. These fuels are used today for onsite cogeneration of heat and power in boiler/steam turbine systems. Gasification technologies under development would enable these fuels to be used in gas turbines. This paper reports results of detailed full-load performance modeling of pulp-mill cogeneration systems based on gasifier/gas turbine technologies. Pressurized, oxygen-blown black liquor gasification, the most advanced of proposed commercial black liquor gasifier designs, is considered, together with three alternative biomass gasifier designs under commercial development (high-pressure air-blown, low-pressure air-blown, and low-pressure indirectly-heated). Heavy-duty industrial gas turbines of the 70-MW{sub e} and 25-MW {sub e} class are included in the analysis. Results indicate that gasification-based cogeneration with biomass-derived fuels would transform a typical pulp mill into significant power exporter and would also offer possibilities for net reductions in emissions of carbon dioxide relative to present practice.

  1. A comprehensive program to develop correlations for the physical properties of Kraft black liquor. Interim report No. 2

    SciTech Connect (OSTI)

    Fricke, A.L.

    1990-12-01T23:59:59.000Z

    Experimental effort for the program to evaluate physical properties of kraft black liquors is now proceeding well. Experimental work includes pulping, liquor analysis, lignin purification and characterization, vapor-liquid equilibria, heat capacity, heats of solution and combustion, and viscosity measurements. Measurement of thermal conductivity has not yet begun. Collection of the data necessary for development of generalized correlations is proceeding, but will require about two more years. The digester is operating very well. It is now possible to operate the digester as a closed, rotating reactor or as a batch reactor with liquor circulation. When operated with liquor circulation, temperatures within the chip bed can be monitored during cooking. Cooking is reproducible, and cooks are being performed to produce liquors for experimental studies. The digester could be further modified to permit us to conduct rapid exchange batch pulping or to permit us to simulate continuous pulping. Liquors to be used in experimental studies are concentrated in our large scale evaporator or in our small scale evaporator. The large scale evaporator is used to concentrate liquors to about 50% solids for storage and for use in studies requiring high solids liquors. The small scale evaporator is used for preparing final samples to as high as 85% solids and for measuring vapor-liquid equilibria. Liquors are now routinely analyzed to determine all components, except higher molecular weight organic acids and extractives. Lignin determination by uv-visible means has been improved. Lignin purification from black liquor has been improved and lignin molecular weights are determined routinely. Work on lignin molecular weight distribution is still not satisfactory, but recent developments holds promise.

  2. Kraft Liquor Corrosion Margaret Gorog

    E-Print Network [OSTI]

    Das, Suman

    1 Kraft Liquor Corrosion Margaret Gorog Federal Way, WA Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute November 2014 · Brown Stock Corrosion · Alkaline Liquor Corrosion · Black Liquor Corrosion ­ Evaporators ­ Research · High Solids Black Liquor Corrosion of Stainless Steel

  3. Fundamental studies of black liquor combustion: Report No. 2, Phase 1 (October 1984-November 1986)

    SciTech Connect (OSTI)

    Clay, D. T.; Lien, S. J.; Grace, T. M.; Macek, A.; Semerjian, H. G.; Amin, N.; Charagundla, S. R.

    1987-01-01T23:59:59.000Z

    The fundamentals of kraft black liquor combustion are being studied in a five year project. This report covers the second and third years of work by The Institute of Paper Chemistry (IPC) and the National Bureau of Standards (NBS) for the US Department of Energy. The burning processes are being studied in two continuous flow reactor systems designed to both study overall process and single particle phenomena. Black liquor burning is divided into four distinct phases: drying, volatiles burning, char burning, and smelt coalescence. Phase 1, In-flight Processes, is the main focus of this report. In-flight processes include mainly the stages of drying and volatiles burning. Testing results in both flow reactors and in two specially designed single particle reactors are presented. Dynamic droplet velocity and swelling have been measured for the first time. A direct link between initial liquor viscosity and burning behavior in the early stages has also been identified. During the fourth year Phase 1 will be completed and Phases 2 (Char Burning) and 3 (Fume Processes) will begin.

  4. Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers

    SciTech Connect (OSTI)

    Keiser, J.R.

    2001-10-22T23:59:59.000Z

    This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

  5. Effect of pulsations on black liquor gasification. Progress report, July--September 1995

    SciTech Connect (OSTI)

    Kushari, A.; Jeong, H.; Jagoda, J.I.; Zinn, B.T.

    1995-12-31T23:59:59.000Z

    The objective of this study is to investigate the use of pulse combustion to provide the energy required for the endothermic gasification of black liquor in a fluidized bed. In this process it is critical that the temperature remain in the small window above the gasification temperature but below the smelting temperature of the inorganic salts in the black liquor. Pulse combustors have been shown to have high heat transfer rates between the hot combustion products and the combustor tailpipe. Similarly, fluidized beds have high heat transfer rates within the bed itself, promoting temperature uniformity throughout. Typical analysis of the gasified black liquor shows there is a large percentage of combustible gases in the products of the gasification process (approximately 70%). The potential exists, therefore, for using this fuel mixture to fire the pulse combustor. This makes the entire process more efficient and may be necessary to make it economically feasible. The overall goals of this study are to determine (1) which is the limiting heat transfer rate in the process of transferring the heat from the hot combustion products to the pipe, through the pipe, from the tailpipe to the bed and then throughout the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the temperature distribution in the bed can be maintained within the narrow temperature range required by the process without generating hot spots in the bed even if the heat transfer from the pulse combustor is significantly increased; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

  6. Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers

    SciTech Connect (OSTI)

    Keiser, J.R.

    2000-04-18T23:59:59.000Z

    This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

  7. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 4 (Appendix IV)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 4 contains the following appendix sections: Radiative heat transfer properties for black liquor combustion -- Facilities and techniques and Spectral absorbance and emittance data; and Radiate heat transfer determination of the optical constants of ash samples from kraft recovery boilers -- Calculation procedure; Computation program; Density determination; Particle diameter determination; Optical constant data; and Uncertainty analysis.

  8. Conversion of a black liquor recovery boiler to wood firing: A case history

    SciTech Connect (OSTI)

    Eleniewski, M.A. [Detroit Stoker Company, Monroe, MI (United States)

    1994-12-31T23:59:59.000Z

    In 1983 a large integrated pulp and paper mill in southeastern United States retired an older chemical recovery boiler when it was replaced by a newer and larger unit as part of a mill expansion. At that time the mill was generating steam and power using wood waste, natural gas and black liquor, a common fuel mix for pulp mills. The retirement of the recovery boiler presented an opportunity for the mill and corporate engineering to evaluate various mixes of fuels for the mill.

  9. Eucalyptus kraft black liquor enhances growth and productivity of Spirulina in outdoor cultures

    SciTech Connect (OSTI)

    Chauhan, V.S.; Singh, G.; Ramamurthy, V. [Thapar Institute of Engineering and Technology, Patiala (India)

    1995-07-01T23:59:59.000Z

    Mass cultivation of microalgae for commercial applications suffers from poor productivities when measured against laboratory results or theoretical projections. In an effort to reduce this gap it was discovered that addition of eucalyptus kraft black liquor (BL) enhanced biomass productivity in outdoor cultures of Spirulina by increasing growth rate by 38% and biomass yield by 43%. BL treatment resulted in elevation of nitrogen assimilating enzyme activities and efficiency of phosphate utilization. Analyses of forenoon and afternoon oxygen production rates (OPRs) indicated higher photosynthetic and respiratory activity in BL-treated cultures compared to untreated cultures. 20 refs., 1 fig., 2 tabs.

  10. Separation and characterization of lignins from the black liquor of oil palm trunk fiber pulping

    SciTech Connect (OSTI)

    Sun, R.; Tomkinson, J.; Bolton, J.

    1999-11-01T23:59:59.000Z

    Six lignin preparations, isolated by a novel two-step precipitation method instead of the traditional one-step precipitation method from the oil palm trunk fiber pulping (OPTFP) black liquor, were found to be relatively free of nonlignin materials such as polysaccharide degradation products, ash, and salts. A lignin fraction with a purity of 99.5% was obtained at an optimum precipitation pH 1.5 after isolation of the nonlignin materials in ethanol. About 94% of the total lignin was recovered by this novel method at this condition, and the value of COD in the treated black liquor reduced significantly to lower 250. The isolated lignin fractions contained syringyl, guaiacyl, and p-hydroxyphenyl units in an approximate molar ratio of 16--20:5:1 on the basis of chemical and spectroscopic analysis. Small amounts of p-hydroxybenzoic acids were found to be esterified to lignin, while ferulic acids were associated to lignin by ether linkage. {sup 13}C-NMR indicated the presence of {beta}-O-4 ether bonds, and {beta}-5 and 5-5{prime} carbon-carbon linkages between the lignin molecules.

  11. Material Characterization and Analysis for Selection of Refractories Used In Black Liquor Gasification

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Gorog, John Peter [ORNL

    2008-01-01T23:59:59.000Z

    Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials, and particularly the refractory lining of the reactor vessel, have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for this application.

  12. Material Characterization and Analysis for Selection of Refractories Used in Black Liquor Gasification

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

    2010-01-01T23:59:59.000Z

    Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials such as the refractory lining of the reactor vessel have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, an updated summary of the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for both the hot-face and back-up linings used in this application.

  13. PERFORMANCE OF BLACK LIQUOR GASIFIER/GAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP

    E-Print Network [OSTI]

    PERFORMANCE OF BLACK LIQUOR GASIFIER/GAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP high-temperature gasifiers for gas turbine applications. ABB and MTCr/Stonechem are developing low-load performance of gasifier/gas turbine systemsincorporating the four above-noted gasifier designs are reported

  14. MOLTEN SALT CORROSION OF SUPERHEATERS IN BLACK LIQUOR RECOVERY BOILERS John Bohling, University of Tennessee Georgia Tech SURF 2010 Fellow

    E-Print Network [OSTI]

    Li, Mo

    MOLTEN SALT CORROSION OF SUPERHEATERS IN BLACK LIQUOR RECOVERY BOILERS John Bohling, University If the temperature is above the first melting point of the scale, severe corrosion of the tubes can result temperatures, reducing efficiency. The corrosive nature of the superheater environment arises primarily from

  15. Stability and Regeneration of Catalysts for the Destruction of Tars from Bio-mass Black Liquor Gasification

    SciTech Connect (OSTI)

    Pradeep Agrawal

    2004-09-07T23:59:59.000Z

    The goal of this project was to develop catalytic materials and processes that would be effective in the destruction of tars formed during the gasification of black liquor and biomass. We report here the significant results obtained at the conclusion of this two year project.

  16. Refractory Testing and Evaluation at Oak Ridge National Laboratory for Black Liquor Gasifier Applications.

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Hubbard, Camden R [ORNL; Lara-Curzio, Edgar [ORNL

    2006-01-01T23:59:59.000Z

    Work is on-going at Oak Ridge National Laboratory to evaluate refractory containment and smelt contact materials for black liquor gasification applications. Materials have been evaluated and selected for low temperature gasification processes, with a number of materials being installed in commercial units currently under construction. For high temperature low pressure gasification processes, efforts have focused on screening candidate lining materials through immersion testing, improving existing refractory performance through the application of surface treatments, and the installation and evaluation of samples in an operating gasifier in New Bern, NC. Efforts concerning high temperature high pressure gasification have involved the identification and testing of suitable refractory materials for the coating of a helical carbon steel cooling coil arrangment.

  17. Separation of kraft lignin from kraft black liquor: Final report, July 1984-April 1987

    SciTech Connect (OSTI)

    Kurple, K.R.

    1988-04-15T23:59:59.000Z

    The importance of this work is related to the fact that with over 16 million tons of kraft lignin available annually, practically all of it is burned just for its heat value. In essence, kraft lignin has no real value except its heat value. The major accomplishments of this research has shown that it is possible to produce high purity kraft lignin from kraft black liquor. This patented technology represents a way of producing a material that can be utilized in a wide variety of markets. Kraft lignin that was produced using this technology was sent to major corporations who used this kraft lignin as a starting material in their chemical processes. 3 figs.

  18. Cracking and Corrosion of Composite Tubes in Black Liquor Recovery Boiler Primary Air Ports

    SciTech Connect (OSTI)

    Keiser, James R.; Singbeil, Douglas L.; Sarma, Gorti B.; Kish, Joseph R.; Yuan, Jerry; Frederick, Laurie A.; Choudhury, Kimberly A.; Gorog, J. Peter; Jett, Francois R.; Hubbard, Camden R.; Swindeman, Robert W.; Singh, Prett M.; Maziasz, Phillip J.

    2006-10-01T23:59:59.000Z

    Black liquor recovery boilers are an essential part of kraft mills. Their design and operating procedures have changed over time with the goal of providing improved boiler performance. These performance improvements are frequently associated with an increase in heat flux and/or operating temperature with a subsequent increase in the demand on structural materials associated with operation at higher temperatures and/or in more corrosive environments. Improvements in structural materials have therefore been required. In most cases the alternate materials have provided acceptable solutions. However, in some cases the alternate materials have solved the original problem but introduced new issues. This report addresses the performance of materials in the tubes forming primary air port openings and, particularly, the problems associated with use of stainless steel clad carbon steel tubes and the solutions that have been identified.

  19. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 5: Appendix V

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  20. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 4: Appendix IV

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  1. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 5 (Appendix V)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 5 contains model validation simulations and comparison with data.

  2. Gasification of kraft black liquor and use of the products in combined cycle cogeneration. Final report, Phase II

    SciTech Connect (OSTI)

    Kelleher, E.G.

    1985-07-01T23:59:59.000Z

    This Phase II study of kraft black liquor gasification and use of the product gases in combined cycle cogeneration based on combustion gas turbines was motivated by the very promising results of the Phase I feasibility study. The Phase I study indicated that the alternative technology to the Tomlinson recovery furnace had the potential of improving the energy efficiency and safety of combusting black liquor, reducing the capital and operating costs, increasing the electric power output, and providing an economical system for incremental kraft capacity additions. During Phase II, additional bench-scale experiments were run, pilot-scale experiments were conducted, equipment systems were investigated, and performance and economics were reanalyzed. All of the objectives of the Phase II project were met. Recommendations are summarized.

  3. Simultaneous measurement of the surface temperature and the release of atomic sodium from a burning black liquor droplet

    SciTech Connect (OSTI)

    Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Mechanical Engineering, The University of Adelaide (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Chemical Engineering, The University of Adelaide (Australia); Hupa, Mikko [Process Chemistry Centre, Aabo Akademi, Biskopsgatan 8 FI-20500 Aabo (Finland)

    2010-04-15T23:59:59.000Z

    Simultaneous measurement of the concentration of released atomic sodium, swelling, surface and internal temperature of a burning black liquor droplet under a fuel lean and rich condition has been demonstrated. Two-dimensional two-colour optical pyrometry was employed to determine the distribution of surface temperature and swelling of a burning black liquor droplet while planar laser-induced fluorescence (PLIF) was used to assess the temporal release of atomic sodium. The key findings of these studies are: (i) the concentration of atomic sodium released during the drying and devolatilisation stages was found to be correlated with the external surface area; and (ii) the insignificant presence of atomic sodium during the char consumption stage shows that sodium release is suppressed by the lower temperature and by the high CO{sub 2} content in and around the particle. (author)

  4. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02T23:59:59.000Z

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. syngas) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950C), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.

  5. Mechanical Design of Steel Tubing for Use in Black Liquor Recovery Boilers

    SciTech Connect (OSTI)

    Taljat, B.; Zacharaia, T.; Wang, X.; Kesier, J.; Swindeman, R.; Hubbard, C.

    1999-05-26T23:59:59.000Z

    Finite element models were developed for thermal-mechanical analysis of black liquor recovery boiler floor tubes. Residual stresses in boiler floors due to various manufacturing processes were analyzed. The modeling results were verified by X-ray and neutron diffraction measurements at room temperature on as-manufactured tubes as well as tubes after service. The established finite element models were then used to evaluate stress conditions during boiler operation. Using these finite element models, a parametric response surface study was performed to investigate the influence of material properties of the clad layer on stresses in the floor tubes during various boiler operating conditions, which yielded a generalized solution of stresses in the composite tube floors. The results of the study are useful for identifying the mechanisms of cracking experienced by recovery boilers. Based on the results of the response surface study, a recommendation was made for more suitable materials in terms of the analyzed mechanical properties. Alternative materials and manufacturing processes are being considered to improve the resistance to cracking and the in-service life of composite tubes. To avoid numerous FE stress-strain analyses of composite tubes made of different material combinations, a response surface study was performed that considered two essential mechanical properties of the clad material - coefficient of thermal expansion and yield stress - as independent variables. The response surface study provided a generalized solution of stresses in the floor in terms of the two selected parameters.

  6. Dynamic air deposited coatings for power and black liquor recovery boilers

    SciTech Connect (OSTI)

    Verstak, A.A.; Baranovski, V.E. [Advanced Surface Technologies Inc., Richmond, VA (United States)

    1999-11-01T23:59:59.000Z

    Dynamic Air Deposition (DyAir) is a novel coating method designed to protect the tubing of power and black liquor recovery boilers against corrosion attack at elevated temperatures. The method utilizes the energy of combustion of gaseous fuel and air to heat the powder material to a temperature just below its melting point and accelerate it over 600 m/s to form a coating. The Ni-Cr and Ni-Cr-Mo DyAir coatings revealed no gas permeability and extremely low oxygen content. Compared to the electric arc and HVOF-sprayed coatings, the DyAir coatings exhibited higher hardness and better crack resistance. During aging at 400 and 700 C the bond strength and crack resistance of the DyAir coatings increased dramatically due to intensive diffusion processes in absence of internal corrosion attack. The DyAir coatings revealed outstanding resistance to corrosion, such as sulfidation attack in presence of hydrochloric acid gas at 400 C, oxidation attack at 700 C and oxidation attack in presence of chlorine at 400 C.

  7. Gasification behavior of carbon residue in bed solids of black liquor gasifier

    SciTech Connect (OSTI)

    Preto, Fernando; Zhang, Xiaojie (Frank); Wang, Jinsheng [CANMET Energy Technology Centre, Natural Resources (Canada)

    2008-07-15T23:59:59.000Z

    Steam gasification of carbon residue in bed solids of a low-temperature black liquor gasifier was studied using a thermogravimetric system at 3 bar. Complete gasification of the carbon residue, which remained unreactive at 600 C, was achieved in about 10 min as the temperature increased to 800 C. The rate of gasification and its temperature dependence were evaluated from the non-isothermal experiment results. Effects of particle size and adding H{sub 2} and CO to the gasification agent were also studied. The rate of steam gasification could be taken as zero order in carbon until 80% of carbon was gasified, and for the rest of the gasification process the rate appeared to be first order in carbon. The maximum rate of carbon conversion was around 0.003/s and the activation energy was estimated to be in the range of 230-300 kJ/mol. The particle size did not show significant effect on the rate of gasification. Hydrogen and carbon monoxide appeared to retard the onset of the gasification process. (author)

  8. Alkali salt ash formation during black liquor combustion at kraft recovery boilers

    SciTech Connect (OSTI)

    Mikkanen, P. Kauppinen, E.I.; Pyykoenen, J.; Jokiniemi, J.K. [VTT (Finland); Maekinen, M. [Finnish Meterological Inst., Helsinki (Finland)

    1996-12-31T23:59:59.000Z

    Recovery boiler is an essential part of paper pulping process, where waste sludge called black liquor is burned for chemical recovery and energy production. This study was carried out at an operating industrial recovery boiler in Finland. Measurement of aerosol particles was carried out at bullnose level of furnace, at boiler exit, and at outlet of electrostatic precipitator (ESP). Aerosol mass size distributions in size range 0.02--50 {micro}m were measured with Berner type low pressure impactor (BLPI) operated with precyclone. BLPI samples were further analyzed with ion chromatography for water soluble Na, K, SO{sub 4}, and Cl. Particle morphology was studied with scanning electron microscopy (SEM). Phase composition of crystalline salts was measured with X-ray diffraction (XRD). Particles larger than 1 {micro}m were analyzed with computer controlled scanning electron microscopy (CCSEM) to derive particle composition classes. At ESP inlet mass size distribution was bimodal with a major mode at about 1.2 {micro}m and a minor mode at about 5 {micro}m (aerodynamic diameter). At ESP outlet the mass size distribution showed only one peak at about 1.2 {micro}m. Both submicron and supermicron particles were agglomerates formed from 0.3 to 0.5 {micro}m spherical primary particles. XRD analyses indicated that particles were crystalline with two phases of Na{sub 2}SO{sub 4} (thenardite and sodium sulphate) and K{sub 3}Na(SO{sub 4}){sub 2}. CCSEM results of individual particles larger than 1 {micro}m showed that 79 to 88 volume percent of particles contained mainly Na and S, 7 to 10 volume percent Na, K, and S with minor amount of particles containing Na, S, and Ca.

  9. Pyrometric temperature measurement method and apparatus for measuring particle temperatures in hot furnaces: Application to reacting black liquor

    SciTech Connect (OSTI)

    Stenberg, J. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Frederick, W.J. [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States)] [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States); Bostroem, S. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland); Hernberg, R. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Hupa, M. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)

    1996-05-01T23:59:59.000Z

    A specialized two-color pyrometric method has been developed for the measurement of particle surface temperatures in hot, radiating environments. In this work, the method has been applied to the measurement of surface temperatures of single reacting black liquor char particles in an electrically heated muffle furnace. Black liquor was introduced into the hot furnace as wet droplets. After drying, the resulted particles were processed in different atmospheres corresponding to combustion, pyrolysis, and gasification at furnace temperatures of 700{endash}900{degree}C. The pyrometric measurement is performed using two silicon photodiode detectors and 10 nm bandpass filters centered at 650 and 1050 nm. Thermal radiation is transferred using an uncooled fiberoptic probe brought into the vicinity of the char particle. The key features of the pyrometric apparatus and analysis method are: (1) Single particle temperature is resolved temporally at high speed. (2) The thermal radiation originating from the furnace and reflected by the particle is accounted for in the measurement of the surface temperature. (3) Particle temperatures above or below the furnace temperature can be measured without the need of a cooled background assisting the measurement in the hot furnace. To accomplish this, a minimum particle size is needed that is a function of the temperature difference between the particle and furnace. Particles cooler than the furnace can be measured if their diameter is more than 0.7 mm. Surface temperatures of 300{endash}400{degree}C above the furnace temperature were measured during combustion of black liquor char particles in air. In atmospheres corresponding to gasification, endothermic reactions occurred, and char temperature remained typically 40{degree} below the furnace temperature. {copyright} {ital 1996 American Institute of Physics.}

  10. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 2 (Appendices I, section 5 and II, section 1)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 2 contains the last section of Appendix I, Radiative heat transfer in kraft recovery boilers, and the first section of Appendix II, The effect of temperature and residence time on the distribution of carbon, sulfur, and nitrogen between gaseous and condensed phase products from low temperature pyrolysis of kraft black liquor.

  11. Causes and solutions for cracking of coextruded and weld overlay floor tubes in black liquor recovery boilers

    SciTech Connect (OSTI)

    Keiser, J.R.; Taljat, B.; Wang, X.L. [and others

    1998-09-01T23:59:59.000Z

    Cracking of coextruded, black liquor recovery boiler floor tubes is both a safety and an economic issue to mill operators. In an effort to determine the cause of the cracking and to identify a solution, extensive studies, described in this and three accompanying papers, are being conducted. In this paper, results of studies to characterize both the cracking and the chemical and thermal environment are reported. Based on the results described in this series of papers, a possible mechanism is presented and means to lessen the likelihood of cracking or to totally avoid cracking of floor tubes are offered.

  12. Electrolysis of weak black liquor: Part II. Effect of process parameters on the energy efficiency of the electrolytic cell

    SciTech Connect (OSTI)

    Cloutier, J.N.; Azarniouch, M.K.; Callender, D.

    1994-12-31T23:59:59.000Z

    A laboratory study of the effect of eight process parameters on the performance of the electrolytic cell when electrolyzing weak black liquor (WBL) showed that current density and temperature are critical to the operation. These two variables showed an interaction effect upon the operation of the cell. The addition of sodium sulfate to the WBL was beneficial to the energy efficiency. No chlorine gas was produced when electrolyzing WBL containing sodium chloride within the pH range of 5.4 to 13.

  13. Study of soluble scale fouling control in high solids black liquor concentrators. Progress report, quarter 5 (October 1, 1999 - December 31, 1999)

    SciTech Connect (OSTI)

    W.J. Frederick; F. Chen; G. Hsieh; S. Lien; R.W. Murphy; R.W. Rousseau; W. Schmidl

    2000-01-01T23:59:59.000Z

    During this quarter, work has finally resumed on the black liquor solubility experiments, but no new data have been generated. The crystallization experiments with inorganic model solutions have been completed, and crystallization experiments with kraft black liquor have been started. The Annular Test Cell apparatus is now fully operational, while construction of the falling film evaporator pilot plant is nearly complete. Startup of this unit is planned for late in Quarter 6. In the CFD model development work, the relaxation of simplifying assumptions in the falling film model have been completed, and expressions were developed to estimate film velocity/film Reynolds number relations. Also, thin film data taken for a range of conventional fluids were compared to predictions using selected methods, and attempts were initiated to extrapolate to approximate black liquor evaporator conditions.

  14. Controlling emissions from a black liquor fluidized bed evaporator (Copeland reactor) using a regenerative thermal oxidizer and a prefilter

    SciTech Connect (OSTI)

    Grzanka, R.

    1997-12-31T23:59:59.000Z

    This paper reports on an intriguing pilot project developed to control air emissions from a pulp mill. Testing is complete, and the results show favorable emissions reductions. Stone Container Corporation, REECO, NCASI, the Ohio DEP, and the US EPA, have all worked together and approved the installation of control equipment, for VOC and HAP emissions under Presumptive MACT, setting the standard for the Copeland Reactor process in a semi chem pulp mill. The equipment, once operational, will reduce VOC and CO emissions by greater than 90%. This installation will be done at one seventh the cost of the significant process modifications required to accomplish the same emission reduction. In addition, increased process operating efficiency will be achieved with the use of an energy recovery system. The process is a black liquor fluidized bed boiler, which is used to generate sodium carbonate from the black liquor. The vapor emissions were high in VOCs, CO and particulate. After much study and testing, a wet electrostatic precipitator was chosen as the filter system for particulate control, followed by a regenerative thermal oxidizer for VOC and HAP control, finally an air-to-air heat exchanger is being used to preheat the combustion air entering the process.

  15. High-solids black liquor firing in pulp and paper industry Kraft recovery boilers. Final report, Phase 1, Volume 1: Executive summary

    SciTech Connect (OSTI)

    Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

    1995-11-01T23:59:59.000Z

    This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The objectives are to develop a preliminary design of a recovery furnace simulator; evaluate the economics of high-solids; and delineate a project concept for evaluating candidate technologies to improve chemical recovery.

  16. Fundamental study of black liquor gasification kinetics using a pressurized entrained-flow reactor (PEFR). Quarterly progress report for the period July 1999 to September 1999

    SciTech Connect (OSTI)

    NONE

    1999-10-29T23:59:59.000Z

    The goal of the program is to identify the optimal operating window for black liquor gasification. The goals during this year are to prepare the PEFR for operation, conduct a series of preliminary screening tests to bracket BLG operating conditions, and develop a process model that can guide identification of the optimal operating window.

  17. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 3: Appendix II, Sections 2 & 3 and Appendix III

    SciTech Connect (OSTI)

    T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  18. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 1 (Main text and Appendix I, sections 1--4)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 1 contains the main body of the report and the first 4 sections of Appendix 1: Modeling of black liquor recovery boilers -- summary report; Flow and heat transfer modeling in the upper furnace of a kraft recovery boiler; Numerical simulation of black liquor combustion; and Investigation of turbulence models and prediction of swirling flows for kraft recovery furnaces.

  19. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 3 (Appendices II, sections 2--3 and III)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 3 contains the following appendix sections: Formation and destruction of nitrogen oxides in recovery boilers; Sintering and densification of recovery boiler deposits laboratory data and a rate model; and Experimental data on rates of particulate formation during char bed burning.

  20. Detection of estrogen- and dioxin-like activity in pulp and paper mill black liquor and effluent using in vitro bioassays

    SciTech Connect (OSTI)

    Zacharewski, T.; Berhane, K.; Gillesby, B.; Burnison, K. [Univ. of Western Ontario, London, Ontario (Canada). Dept. of Pharmacology and Toxicology; [National Water Research Inst., Burlington, Ontario (Canada). Aquatic Ecosystem Conservation Branch

    1995-12-31T23:59:59.000Z

    Pulp and paper mill effluent contains a complex mixture of compounds which adversely affect fish physiologically and at the population level. These effects include compromised reproductive fitness and the induction of mixed-function oxidase activities; two classic responses mediated by the estrogen and/or Ah receptor. In vitro recombinant receptor/reporter gene assays were used to examine pulp and paper mill black liquor and effluent for estrogenic, dioxin-like and antiestrogenic activities. Using MCF7 cells transiently transfected with a Gal4-estrogen receptor chimeric construct (Gal4-HEGO) and a Gal4-regulated luciferase reporter gene (17m5-G-Luc), it was estimated that black liquor contains 4 {+-} 2 ppb ``estrogen equivalents``, while negligible estrogenic activity was observed in a methanol-extracted pulp and paper mill effluent fraction (MF). A dioxin response element (DRE)-regulated luciferase reporter gene (pGudLucl.1) transiently transfected into Hepalclc7 wild type cells exhibited a dose-dependent increase in luciferase activity following treatment with 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDO), black liquor and MF. Based on the dose response curves, black liquor and MF contain 10 {+-} 4 ppb and 20 {+-} 6 ppt ``TCDD equivalents``, respectively. Moreover, MF exhibited significant AhR-mediated antiestrogenic activity. These results demonstrate the utility of these bioassays and suggest that the effects observed in fish exposed to pulp and paper mill effluent may be due to unidentified ER and AhR ligands not detected by conventional chemical analysis due to the lack of appropriate chemical standards.

  1. Development of an alternative kraft black liquor recovery process based on low-temperature processing in fluidized beds. Final technical report on Annex 9, Task 1

    SciTech Connect (OSTI)

    Kubes, G.J.

    1994-03-24T23:59:59.000Z

    The overall objective of this research program was to provide the fundamental knowledge and experimental data from pilot scale operation for an alternative black liquor recovery technology which would have a higher overall energy efficiency, would not suffer from the smelt-water explosion hazard and would be lower in capital cost. In addition, the alternative process would be more flexible and well suited for incremental recovery capacity or for new pulping processes, such as the new sulfide-sulfide-AQ process. The research program consists of number of specific research objectives with the aim to achieve the ultimate objective of developing an alternative recovery process which is shown in Figure 1. The specific objectives are linked to individual unit operations and they represent the following research topics: (1) superheated steam drying of kraft black liquors; (2) fast pyrolysis of black liquor; (3) hydrogen sulfide absorption from flue gas; (4) reduction of sodium sulfate in solid phase with gaseous hydrogen; and (5) verification of the fundamental results in fluidized bed pilot plant. The accomplishments in each of these objectives are described.

  2. Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers

    SciTech Connect (OSTI)

    Keiser, J.R.; Hubbard, C.R.; Payzant, E.A. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01T23:59:59.000Z

    Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

  3. Engineering Study for a Full Scale Demonstration of Steam Reforming Black Liquor Gasification at Georgia-Pacific's Mill in Big Island, Virginia

    SciTech Connect (OSTI)

    Robert De Carrera; Mike Ohl

    2002-03-19T23:59:59.000Z

    Georgia-Pacific Corporation performed an engineering study to determine the feasibility of installing a full-scale demonstration project of steam reforming black liquor chemical recovery at Georgia-Pacific's mill in Big Island, Virginia. The technology considered was the Pulse Enhanced Steam Reforming technology that was developed and patented by Manufacturing and Technology Conversion, International (MTCI) and is currently licensed to StoneChem, Inc., for use in North America. Pilot studies of steam reforming have been carried out on a 25-ton per day reformer at Inland Container's Ontario, California mill and on a 50-ton per day unit at Weyerhaeuser's New Bern, North Carolina mill.

  4. High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase 1 -- Final report. Volume 2: Project technical results

    SciTech Connect (OSTI)

    Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

    1995-11-01T23:59:59.000Z

    This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The principal means to this end is to construct and operate a pilot-scale recovery furnace simulator (RFS) in which these technologies can be tested. The Phase 1 objectives are to prepare a preliminary design for the RFS, delineate a project concept for evaluating candidate technologies, establish industrial partners, and report the results. Phase 1 addressed the objectives with seven tasks: Develop a preliminary design of the RFS; estimate the detailed design and construction costs of the RFS and the balance of the project; identify interested parties in the paper industry and key suppliers; plan the Phase 2 and Phase 3 tests to characterize the RFS; evaluate the economic justification for high-solids firing deployment in the industry; evaluate high-solids black liquor property data to support the RFS design; manage the project and reporting results, which included planning the future program direction.

  5. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01T23:59:59.000Z

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  6. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 2: Appendix I, Section 5, and Appendix II, Section 1

    SciTech Connect (OSTI)

    T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  7. Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 1: Main Text and Appendix I, Sections 1-4

    SciTech Connect (OSTI)

    T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

    1998-08-01T23:59:59.000Z

    This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

  8. Alternate Explosions: Collapse and Accretion Events with Red Holes instead of Black Holes

    E-Print Network [OSTI]

    James S. Graber

    1999-08-10T23:59:59.000Z

    A red hole is "just like a black hole" except it lacks an event horizon and a singularity. As a result, a red hole emits much more energy than a black hole during a collapse or accretion event. We consider how a red hole solution can solve the "energy crisis" and power extremely energetic gamma ray bursts and hypernovae.

  9. Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill

    SciTech Connect (OSTI)

    Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

    2010-01-27T23:59:59.000Z

    As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industrys energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also produced a comparable tensile and burst index pulps. Product gas composition determined using computer simulations The results demonstrate that RVS-1 can effectively remove > 99.8% of the H2S present in simulated synthesis gas generated from the gasification of black liquor. This level of sulfur removal was consistent over simulated synthesis gas mixtures that contained from 6 to 9.5 vol % H2S.A significant amount of the sulfur in the simulated syngas was recovered as SO2 during regeneration. The average recovery of sulfur as SO2 was about 75%. Because these are first cycle results, this sulfur recovery is expected to improve. Developed WINGems model of the process.The total decrease in variable operating costs for the BLG process compared to the HERB was in excess of $6,200,000 per year for a mill producing 350,000 tons of pulp per year. This represents a decrease in operating cost of about $17.7/ton of oven dry pulp produced. There will be additional savings in labor and maintenance cost that has not been taken into account. The capital cost for the MSSAQ based gasifier system was estimated at $164,000,000, which is comparable to a High Efficiency Recovery Boiler. The return on investment was estimated at 4%. A gasifier replacement cannot be justified on its own, however if the recovery boiler needs to be replaced the MSSAQ gasifier system shows significantly higher savings. Before black liquor based gasifer technology can be commercialized more work is necessary. The recovery of the absorbed sulfur in the absorbent as sulfur dioxide is only 75%. This needs to be greater than 90% for economical operation. It has been suggested that as the number of cycles is increased the sulfur dioxide recovery might improve. Further research is necessary. Even though a significant amount of work has been done on a pilot scale gasifiers using liquors containing sulfur, both at low and high temperatures the lack of a commercial unit is an impediment to the implementation of the MSSAQ technology. The implementation of a commercial unit needs to be facilated before the benefits of

  10. High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase Ia - Low-temperature gasifier evaluation. Final report, November 1, 1995--October 31, 1996

    SciTech Connect (OSTI)

    Southards, W.T.; Blude, J.D.; Dickinson, J.A. [and others

    1997-06-01T23:59:59.000Z

    This project, conducted under The United States Department of Energy (DOE) Cooperative Agreement DE-FC36-94GO10002/A002, was part of a multiple-phase effort to develop technologies that improve the energy efficiency and economics of chemical process recovery in the pulp and paper industry. The approach taken was to consider two major alternatives in two phases. Phase I, conducted previously, considered means to improve pulp mill recovery boilers using high-solids advanced combustion of black liquor; while this project, Phase la, considered means to recover kraft pulping mill process chemicals by low-temperature black liquor gasification. The principal steps previously proposed in this program were: (1) Evaluate these two technologies, high-solids advanced combustion and gasification, and then select a path forward using the more promising of these two options for future work. (2) Design and construct a pilot-scale unit based on the selected technology, and using that unit, develop the precompetitive data necessary to make commercialization attractive. (3) Develop and deploy a first-of-a-kind (FOAK) commercial unit in a kraft pulp mill. Phase I, which evaluated the high-solids advanced combustion option, was concluded in 1995. Results of that project phase were reported previously. This report describes the work conducted in Phase Ia. The work is described in Sections 1 through 4 and six appendices provide additional detail.

  11. Viscosity of black liquor project

    SciTech Connect (OSTI)

    Barrall, G.A.

    1998-06-01T23:59:59.000Z

    The discussion of magnetic resonance in this report is confined to nuclides with a spin quantum number of 1/2. Included is a basic discussion of magnetic resonance; magnetic resonance relaxation and viscosity; and rhometers and viscometers. Many other effects are ignored for the sake of clarity.

  12. Big Island Demonstration Project Black Liquor

    Broader source: Energy.gov [DOE]

    This fact sheet summarizes a U.S. Department of Energy Biomass Program research and development project.

  13. Kerr black hole parameters in terms of red/blue shifts of photons emitted by geodesic particles

    E-Print Network [OSTI]

    Alfredo Herrera-Aguilar; Ulises Nucamendi

    2015-06-17T23:59:59.000Z

    We are motivated by the recently reported dynamical evidence of stars with short orbital periods moving around the center of the Milky Way and the corresponding hypothesis about the existence of a supermassive black hole hosted at its center. In this paper we show how the mass and rotation parameters of a Kerr black hole (assuming that the putative supermassive black hole is of this type), as well as the distance that separates the black hole from the Earth, can be estimated in a relativistic way in terms of i) the red and blue shifts of photons that are emitted by geodesic massive particles (stars and galactic gas) and travel along null geodesics towards a distant observer, and ii) the radius of these star/gas orbits. As a concrete example and as a first step towards a full relativistic analysis of the above mentioned star orbits around the center of our galaxy, we consider stable equatorial circular orbits of stars and express their corresponding red/blue shifts in terms of the metric parameters (mass and angular momentum per unit mass) and the orbital radii of both the emitter star (and/or galactic gas) and the distant observer. In principle, these expressions allow one to statistically estimate the mass and rotation parameters of the Kerr black hole, and the radius of our orbit, through a Bayesian fitting, i.e., with the aid of observational data: the red/blue shifts measured at certain points of stars' orbits and their radii, with their respective errors, a task that we hope to perform in the near future. We also point to several astrophysical phenomena, like accretion discs of rotating black holes, binary systems and active galactic nuclei, among others, to which this formalism can be applied.

  14. Highly Energy Efficient Directed Green Liquor Utilization (D...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping This factsheet describes a...

  15. Kerr black hole parameters in terms of red/blue shifts of photons emitted by geodesic particles

    E-Print Network [OSTI]

    Herrera-Aguilar, Alfredo

    2015-01-01T23:59:59.000Z

    We are motivated by the recently reported dynamical evidence of stars with short orbital periods moving around the center of the Milky Way and the corresponding hypothesis about the existence of a supermassive black hole hosted at its center. In this paper we show how the mass and rotation parameters of a Kerr black hole (assuming that the putative supermassive black hole is of this type), as well as the distance that separates the black hole from the Earth, can be estimated in a relativistic way in terms of i) the red and blue shifts of photons that are emitted by geodesic massive particles (stars and galactic gas) and travel along null geodesics towards a distant observer, and ii) the radius of these star/gas orbits. As a concrete example and as a first step towards a full relativistic analysis of the above mentioned star orbits around the center of our galaxy, we consider stable equatorial circular orbits of stars and express their corresponding red/blue shifts in terms of the metric parameters (mass and a...

  16. Synthesis of Black and Red Mercury Sulfide Nano-Powder by Traditional Indian Method for Biomedical Application

    SciTech Connect (OSTI)

    Padhi, Payodhar [Orissa Engineering College, Bhubaneswar (India); Sahoo, G. [Tapaswini Ayurvedic clinic and Research center, Balasore (India); Das, K. [Gopobandhu Ayurvedic Medical College, Puri (India); Ghosh, Sudipto; Panigrahi, S. C. [Department of Metallurgical and Materials Engineering, IIT, Kharagpur (India)

    2008-10-23T23:59:59.000Z

    The use of metals and minerals in the traditional Indian system of medicine known as aired is very common and is practiced since seventh century B.C. Metals were reduced to calcined powder form for medicinal purpose. For detoxification, a further step of purification of the metals and minerals with different vegetable extracts was practiced. The people of East India were using mercury and its sulfide as medicine. Gradually this secret was leaked to Arabic physicians who used mercury in skin ointment. Subsequently Italian Physicians adopted Arabic prescriptions of mercurial ointments for skin diseases. In the olden days, metals and minerals were impregnated with decoction and juice of vegetables and animal products like milk and fat for purification. These were then reduced to fine particles by milling with a pestle and mortar. It was known by then that the fineness of the powder had a significant influence on the color, texture, and medicinal properties as is cited by Charak. Nagarjun studied in detail the processing of metals and minerals, particularly mercury and the influence of the processing parameters on the medicinal values. Mercury is unique in many aspects. Indian alchemy developed a wide variety a chemical processes for the ostensible transmutation of metals and preparation of elixir of life, in which mercury occupied a prime position .The present investigation attempts to use the traditional methods as prescribed in the ancient texts to prepare mercury sulfide in both red and black form for medicinal use. XRD, SEM and HRTEM investigations of the sulfides obtained shows that the ancient Indians were able to produce nano-sized powders. Possibly this may be taken as the earliest application of the production and use of nano powder. The study proves that even in ancient time the knowledge of nano particle synthesis was prevalent and used to enhance effectiveness of medicines. Further mercury in the free form is not acceptable in medicines. The ancient physicians could get rid of free mercury by milling and proper choice of the ratio of ingredients as is shown in the investigation by X-ray diffraction studies. In the traditional method for synthesis of mercury sulfide, mercury and pure sulfur were taken and milled in a mortar and pastel. During milling process, the white mercury and yellow sulfur yielded to a gray black colored sulfide. Synthesis of red sulfide of mercury required additional steps of heating and subsequent milling. For therapeutically application, the sulfide thus obtained needed detoxification, which was done using organic extracts. In the present investigation, the same method was followed to synthesize the sapphires and the product was characterized using modern methods like XRD, SEM and HRTEM. With increase in milling time the fineness of the powder increases, which increases the efficacy of the medicine, and free mercury, which is not desirable for medicinal application is found to decrease. The powder obtained at the end of 48 hours of milling is found to be of a size finer than l0nm.

  17. The preparation and analysis of ammonia base sulfite pulping liquor

    E-Print Network [OSTI]

    Honstead, John Frederick

    1950-01-01T23:59:59.000Z

    much better check between results obtained by two different operators testing the same sample, and using the Palm- rose method. In a mill the liquor is test d b? shift men as the liquor is being prepared, and also by technicians in the laboratory...

  18. BAR PACKAGES Standard Bar Package Price Liquor Beer/Wine

    E-Print Network [OSTI]

    Westneat, Mark W.

    BAR PACKAGES Standard Bar Package Price Liquor Beer/Wine 1-2 hours $21/ person Sobieski Vodka MGD 3 Select Wine Cutty Sark Scotch Cruzan Rum Premium Bar Package Price Liquor Beer/Wine 1-2 hours $24/person Beer/Wine 1-2 hours $28/person Grey Goose Vodka MGD/Miller Light 3 hours $33/person Bombay Sapphire Two

  19. Liquor Activity Reduction (LAR) Programme - 12397

    SciTech Connect (OSTI)

    Pether, Colin; Carrol, Phil; Birkett, Eddie; Kibble, Matthew [Sellafield Ltd, Cumbria (United Kingdom)

    2012-07-01T23:59:59.000Z

    Waste material from the reprocessing of irradiated fuel has been stored under water for several decades leading to the water becoming highly radioactive. As a critical enabler to the decommissioning strategy for the Sellafield site, the Liquor Activity Reduction (LAR) programme has been established to provide a processing route for this highly radioactive liquor. This paper reviews the progress that has been made since the start of routine LAR transfer cycles (July 2010) and follows on from the earlier paper presented at WM2011. The paper focuses on the learning from the first full year of routine LAR transfer cycles and the application of this learning to the wider strategies for the treatment of further radioactive liquid effluents on the Sellafield site. During this period over 100,000 Curies of radioactivity has been safely removed and treated. The past year has witnessed the very successful introduction of the LAR programme. This has lead to hazard reduction at MSSS and demonstration that the SIXEP facility can meet the significantly increased challenge that the LAR programme represents. Part of the success has been the ability to predict and deliver a realistic production schedule with the availability of the MSSS, EDT and SIXEP facilities being central to this. Most importantly, the LAR programme has been successful in bringing together key stakeholders to deliver this work while integrating with the existing, day to day, demands of the Sellafield site. (authors)

  20. Black Liquor Gasification Process Review and Status Update

    E-Print Network [OSTI]

    Brown, C.

    facilities (0.2 tph) focused on developing pressurized gasifiers. Their work is complemented by research at VIT (The Technical Research Centre of Finland) who have a 0.2 tph pressurized fluid bed test facility. The purpose of this paper is to describe...

  1. Refraction-Based Alternative Explanation for: Bending of Light Near a Star, Gravitational Red/Blue Shift and Black-Hole

    E-Print Network [OSTI]

    R. C. Gupta; Anirudh Pradhan; Sushant Gupta

    2010-04-09T23:59:59.000Z

    Many of the general-relativity-tests such as bending of light near a star and gravitational red/blue shift are explained without general-relativity & without Newtonian-approach. The authors first cast doubts on both, the Newtonian and the relativistic approach; and proposes a novel alternative-explanation. The new alternative explanation is based on refraction-phenomenon of optics. Estimation of results, with new approach, are in agreement with known values. Though physics is different, but it is argued that general-relativity based gravitational-bending and refraction-based bending have more in common than is generally realized. Also discussed are black-hole and gravitational-lensing in the new perspective of refraction. The new refraction-based theory makes a few new predictions and also suggests a few tests..

  2. Nine grain bun with salmon, turkey burger or spicy black bean burger. Add spinach, pickles, tomatoes, red onion, and

    E-Print Network [OSTI]

    Carter, John

    The Grill Nine grain bun with salmon, turkey burger or spicy black bean burger. Add spinach- the veggier the healthier! Eat beans, peas, nuts and seeds more often than meat. Meat should be in small Jicama- Vegetable with a good source of fiber originating in Mexico and Central America Garbanzo Beans

  3. Microsoft Word - Red Detector Tests _3_.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Red Detector Tests May 5 ed -2006 1. Black Body @ 900F, Comparison between red and blue detectors: Table 1: Detector's signal with and without filters -BB at 900F Filter(micron)...

  4. Red or blue? A potential kilonova imprint of the delay until black hole formation following a neutron star merger

    E-Print Network [OSTI]

    Metzger, Brian D

    2014-01-01T23:59:59.000Z

    Mergers of binary neutron stars (NSs) usually result in the formation of a hypermassive neutron star (HMNS). Whether- and when this remnant collapses to a black hole (BH) depends primarily on the equation of state and on angular momentum transport processes, both of which are uncertain. Here we show that the lifetime of the merger remnant may be directly imprinted in the radioactively powered kilonova emission following the merger. We employ axisymmetric, time-dependent hydrodynamic simulations of remnant accretion disks orbiting a HMNS of variable lifetime, and characterize the effect of this delay to BH formation on the disk wind ejecta. Our models follow the system evolution over several seconds, and include the effect of nuclear recombination, viscous heating, and neutrino irradiation by both the HMNS and the disk. When BH formation is relatively prompt ( 140, resulting in ~week-long emission with a spectral peak in the near-infrared (NIR), similar to that produced by the dynamical ejecta. In contrast, de...

  5. Red or blue? A potential kilonova imprint of the delay until black hole formation following a neutron star merger

    E-Print Network [OSTI]

    Brian D. Metzger; Rodrigo Fernndez

    2014-05-02T23:59:59.000Z

    Mergers of binary neutron stars (NSs) usually result in the formation of a hypermassive neutron star (HMNS). Whether- and when this remnant collapses to a black hole (BH) depends primarily on the equation of state and on angular momentum transport processes, both of which are uncertain. Here we show that the lifetime of the merger remnant may be directly imprinted in the radioactively powered kilonova emission following the merger. We employ axisymmetric, time-dependent hydrodynamic simulations of remnant accretion disks orbiting a HMNS of variable lifetime, and characterize the effect of this delay to BH formation on the disk wind ejecta. When BH formation is relatively prompt (~ 100 ms), outflows from the disk are sufficiently neutron rich to form heavy r-process elements, resulting in ~ week-long emission with a spectral peak in the near-infrared (NIR), similar to that produced by the dynamical ejecta. In contrast, delayed BH formation allows neutrinos from the HMNS to raise the electron fraction in the polar direction to values such that potentially Lanthanide-free outflows are generated. The lower opacity would produce a brighter, bluer, and shorter-lived ~ day-long emission (a `blue bump') prior to the late NIR peak from the dynamical ejecta and equatorial wind. This new diagnostic of BH formation should be useful for events with a signal to noise lower than that required for direct detection of gravitational waveform signatures.

  6. Black Bean Orange Salad Ingredients

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    beans in a colander under running water to remove sodium. Allow to drain. 2. Cut the ends offBlack Bean Orange Salad Ingredients: 15 ounces black beans, canned, drained and rinsed 1/4 red

  7. Emerging energy-efficient technologies for industry

    E-Print Network [OSTI]

    2001-01-01T23:59:59.000Z

    recycled glass cullet Black liquor gasification Condebeltwastewater Microturbines Black liquor gasification Efficienttechnologies are black liquor gasification (a potentially

  8. Emerging energy-efficient technologies for industry

    E-Print Network [OSTI]

    2004-01-01T23:59:59.000Z

    recycled glass cullet Black liquor gasification Condebeltwastewater Microturbines Black liquor gasification Efficienttechnologies are black liquor gasification (a potentially

  9. Analysis of Energy-Efficiency Opportunities for the Pulp and Paper Industry in China

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01T23:59:59.000Z

    efficiently utilize black liquor and other waste biomass forbiomass is used and black liquor is converted intoRecovery Falling film black liquor evaporation Black liquor

  10. World Best Practice Energy Intensity Values for Selected Industrial Sectors

    E-Print Network [OSTI]

    Worrell, Ernst; Price, Lynn; Neelis, Maarten; Galitsky, Christina; Zhou, Nan

    2007-01-01T23:59:59.000Z

    recovered from the black liquor recovery process (combustingand development in black liquor gasification has not yetgreen liquor, similar to the black liquor recovery process,

  11. Method for improving separation of carbohydrates from wood pulping and wood or biomass hydrolysis liquors

    DOE Patents [OSTI]

    Griffith, William Louis; Compere, Alicia Lucille; Leitten Jr., Carl Frederick

    2010-04-20T23:59:59.000Z

    A method for separating carbohydrates from pulping liquors includes the steps of providing a wood pulping or wood or biomass hydrolysis pulping liquor having lignin therein, and mixing the liquor with an acid or a gas which forms an acid upon contact with water to initiate precipitation of carbohydrate to begin formation of a precipitate. During precipitation, at least one long chain carboxylated carbohydrate and at least one cationic polymer, such as a polyamine or polyimine are added, wherein the precipitate aggregates into larger precipitate structures. Carbohydrate gel precipitates are then selectively removed from the larger precipitate structures. The method process yields both a carbohydrate precipitate and a high purity lignin.

  12. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

    2003-01-01T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  13. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  14. Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream

    DOE Patents [OSTI]

    Li, Jian (Marietta, GA); Chai, Xin Sheng (Atlanta, GA); Zhu, Junyoung (Marietta, GA)

    2008-06-24T23:59:59.000Z

    The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

  15. Blood, rumen liquor, and fecal components as affected by dietary crude protein

    E-Print Network [OSTI]

    Hinnant, R. T

    1979-01-01T23:59:59.000Z

    BLOOD, RUMEN LIQUOR, AND FECAL COMPONENTS AS AFFECTED BY DIETARY CRUDE PROTEIN A Thesis by RAY THOMAS HINNANT Submitted to the Graduate College ot Texas A&M University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE December' 1979 Major Subject: Range Science BLOOD, RUMEN LIQUOR, AND FECAL COMPONENTS AS APFECTED BY DIETARY CRUDE PROTEIN A Thesis by RAY THOMAS HINNANT Approved as to style and content by: (Chairman of Cosssittee) (Member) ( ?) (Head...

  16. High-solids enrichment of thermophilic microbial communities and their enzymes on bioenergy feedstocks

    E-Print Network [OSTI]

    Reddy, A. P.

    2012-01-01T23:59:59.000Z

    strain isolated from black liquor. Bioresource Technologyhave been enriched in black liquor samples from paper

  17. Red Sky with Red Mesa

    ScienceCinema (OSTI)

    None

    2014-06-23T23:59:59.000Z

    The Red Sky/Red Mesa supercomputing platform dramatically reduces the time required to simulate complex fuel models, from 4-6 months to just 4 weeks, allowing researchers to accelerate the pace at which they can address these complex problems. Its speed also reduces the need for laboratory and field testing, allowing for energy reduction far beyond data center walls.

  18. New method of regenerating spent vacuum-carbonate sulfur removal liquor

    SciTech Connect (OSTI)

    Popov, A.A.; Dovgopol, A.P.; Goncharova, Z.S.; Belitskii, A.N,.; Gorokhov, N.N.; Grigorash, A.S.; Yaroshenko, A.K.

    1980-01-01T23:59:59.000Z

    A three-stage method is proposed for processing the ballast salts in the wash liquor from vacuum-carbonate removal of sulfur from coke-oven gas. The method is based on successive treatment of the liquor with sulfur dioxide, hydrogen sulfide and 95% sulfuric acid in the presence of hydrogen sulfide. The products of the process are thiosulfate, sulfate and elemental sulfur, at yields of 99.8%, 99.5% and 99.7% respectively. These investigations of a waste-free vacuum-carbonate method of removing hydrogen sulfide from coke-oven gas convincingly show that it is possible in principle to efficiently utilize the spent liquors both as a feedstock and as an absorbent and to obtain commercial products as a result.

  19. Test plan for non-radioactive testing of vertical calciner for development of direct denitration conversion of Pu-bearing liquors to stable, storage solids

    SciTech Connect (OSTI)

    Fisher, F.D.

    1995-03-30T23:59:59.000Z

    Plutonium-bearing liquors, including ANL scrap liquors, will be used for development and demonstration of a vertical calciner direct denitration process for conversion of those liquors to stable, storable PuO{sub 2}-rich solids. This test plan is to test with non-radioactive stand-in materials to demonstrate adequate performance of the vertical calciner and ancillary equipment.

  20. Study of soluble scale fouling control in high solids black liquor concentrators

    SciTech Connect (OSTI)

    Frederick, W. J.; Chen, F.; Hsieh, G.; Lien, S.; Murphy, R.W.; Rousseau, R.W.

    1999-09-30T23:59:59.000Z

    The quarterly project review meeting was held at IPST on August 2, 1999 and was attended by IPST, Georgia Tech, and ORNL principal investigators, members of the Industrial Advisory Group, and a U.S. DOE representative. Although steady progress is being made, this project is currently behind schedule. The specific tasks that are behind schedule, the reasons for the delays, and the expected completion dates are discussed. The remaining tasks are either on schedule, or have not been started.

  1. Generator-Absorber heat exchange transfer apparatus and method using an intermediate liquor

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Zawacki, Thomas S. (St. Joseph, MI)

    1996-11-05T23:59:59.000Z

    Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium where the working solution has an intermediate liquor concentration.

  2. Novel Pulping Technology: Directed Green Liquor Utilization (D-GLU) Pulping

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15T23:59:59.000Z

    The general objectives of this new project are the same as those described in the original proposal. Conventional kraft pulping technologies will be modified for significant improvements in pulp production, such as strength, bleachability, and yield by using green liquor, a naturally high, kraft mill-derived sulfidity source. Although split white liquor sulfidity and other high sulfidity procedures have the promise of addressing several of the latter important economic needs of pulp mills, they require considerable engineering/capital retrofits, redesigned production methods, and thus add to overall mill expenditures. Green liquor use, however, possesses the required high sulfidity to obtain in general the benefits attributable to higher sulfidity cooking, without the required capital constraints for implementation. Before introduction of green liquor in our industrial operations, a stronger understanding of its fundamental chemical interaction with the lignin and carbohydrates in US hardwood and softwoods must be obtained. In addition, its effect on bleachability, enhancement of pulp properties, and influence on the overall energy and recovery of the mill requires further exploration before the process witnesses widespread mill use in North America. Thus, proof of principle will be accomplished in this work and the consequent effect of green liquor and other high sulfide sources on the pulping and bleaching operations will be explored for US kraft mills. The first year of this project will generate the pertinent information to validate its ability for implementation in US pulping operations, whereas year two will continue this work while proceeding to analyze pulp bleachability and final pulp/paper properties and develop a general economic and feasibility analysis for its eventual implementation in North America.

  3. Determination of taurine concentration during cheddar cheese manufacture and examination of antioxidant properties of whey, permeate, mother liquor, and taurine

    E-Print Network [OSTI]

    Li, Xin

    1999-01-01T23:59:59.000Z

    Comparison of the maximum chemiluminescence value(MCV) of control, whey, permeate and mother liquor in the hemoglobin system. . 39 Comparison of the maximum chemiluminescence time(MCT) of control, whey, permeate and mother liquor in the hemoglobin system.... . 40 Effect of concentration of taurine on the MCT and MCV in the hemoglobin system. 45 LIST OF FIGURES FIGURE Page Anion exchange chromatograph of taurine and lactose in permeate . . . . . . 30 Comparative antioxidant activity of whey fractions...

  4. Subsidizing Solar: The Case for an Environmental Goods and Services Carve-out from the Global Subsidies Regime

    E-Print Network [OSTI]

    Simmons, Zachary Scott

    2014-01-01T23:59:59.000Z

    IRS concluded that black liquor, a carbon-based byproductits application to black liquor almost certainly did. Thisthe application to black liquor) to create a perverse

  5. Emerging energy-efficient industrial technologies

    E-Print Network [OSTI]

    2000-01-01T23:59:59.000Z

    and P. Parthsarathy. 1999. Black Liquor Gasification: AKreutz, N. Berglin. 1998. Black Liquor Gasifier/Gas TurbineSystem Options with Black Liquor Gasification. In Pulp and

  6. Emerging Energy-Efficient Technologies for Industry

    E-Print Network [OSTI]

    2005-01-01T23:59:59.000Z

    recycled glass cullet Black liquor gasification CondebeltBeam Sterilization Black liquor gasification Efficient cellSensors and controls Black liquor gasification Near net

  7. The use of a permanent magnet for water content measurements of wood chips

    E-Print Network [OSTI]

    2001-01-01T23:59:59.000Z

    making machine. The black liquor left over from the pulpingchips, brownstock, and black liquor. This report describes acellulose and water) and black liquor using the bench scale

  8. Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01T23:59:59.000Z

    54 3.5.1. Black Liquor2006. "Ultrafiltration of black liquor using rotating diskultrafiltration of Kraft black liquor using rotating disk

  9. The Costs and Benefits of Compliance with Renewable Portfolio Standards: Reviewing Experience to Date

    E-Print Network [OSTI]

    Heeter, Jenny

    2014-01-01T23:59:59.000Z

    the inception of this RPS, black liquor gasification hasprimary source of RECs; black liquor typically costs lesspart of the main tier, black liquor represented 33% of the

  10. Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry

    E-Print Network [OSTI]

    Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

    2000-01-01T23:59:59.000Z

    Atlas, 1996b (? ). Black Liquor gasification IntroductionBerglin, N. July, 1998. Black Liquor Gasifier/Gas TurbinePreliminary Economics of Black Liquor Gasification Combined

  11. Magnet options for sensors for the pulp and paper industry

    E-Print Network [OSTI]

    Green, M.A.

    2011-01-01T23:59:59.000Z

    constituents of the black liquor leaving the paper digester,a papermaking machine. The black liquor left over from themoisture content of the black liquor leaving the digester,

  12. Strategies for Low Carbon Growth In India: Industry and Non Residential Sectors

    E-Print Network [OSTI]

    Sathaye, Jayant

    2011-01-01T23:59:59.000Z

    uses heat and yields black liquor that can potentially be2007). However, the black liquor recovery in agro-residueHigh concentration of black liquor Continuous digester

  13. ENERGY EFFICIENCY OPPORTUNITIES IN THE U.S. PULP AND PAPER INDUSTRY

    E-Print Network [OSTI]

    Kramer, Klaas Jan

    2010-01-01T23:59:59.000Z

    chemicals (i.e. , black liquor) [5, 9]. Electricity is usedand other operations. Black liquor is the dominant fuel forconcentration Thick black liquor Refiner Steam Electricity

  14. Clean Energy Technologies: A Preliminary Inventory of the Potential for Electricity Generation

    E-Print Network [OSTI]

    Bailey, Owen; Worrell, Ernst

    2005-01-01T23:59:59.000Z

    21 13. Black LiquorChlorine-Alkaline Industry Black Liquor Gasification ResidueDC (LBNL-46990). 13. Black Liquor Gasification In standard

  15. Opportunities to improve energy efficiency in the U.S. pulp and paper industry

    E-Print Network [OSTI]

    Worrell, Ernst; Martin, Nathan; Anglani, Norma; Einstein, Dan; Khrushch, Marta; Price, Lynn

    2001-01-01T23:59:59.000Z

    Benefit Assessment of Black Liquor Gasifier/Combined CycleRecovery Falling film black liquor evaporation Tampellafiring Falling film black liquor evaporation Enzyme-assisted

  16. Biofuel Boundaries: Estimating the Medium-Term Supply Potential of Domestic Biofuels

    E-Print Network [OSTI]

    Jones, Andrew; O'Hare, Michael; Farrell, Alexander

    2007-01-01T23:59:59.000Z

    industrial residues - such as black liquor and sawdust, andindustry residues such as black liquor are mostly (93%) (18)industry residues, such as black liquor from their current

  17. Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01T23:59:59.000Z

    that extracts lignin from black liquor with the potential todissolving in the black liquor along with lignin (Hamzeh etextracts lignin from pulp mill black liquor: LignoBoost.

  18. Red River Compact (Texas)

    Broader source: Energy.gov [DOE]

    The Red River Compact Commission administers the Red River Compact to ensure that Texas receives its equitable share of quality water from the Red River and its tributaries as apportioned by the...

  19. Upper Middle Mainstem Columbia River Subbasin Focal Species Information, Red-winged Blackbird

    E-Print Network [OSTI]

    Appendix C Upper Middle Mainstem Columbia River Subbasin Focal Species Information, Red-winged Blackbird Introduction The red-winged black bird is one of the most abundant birds in North America (Marshall et al. 2003). Red-winged Blackbirds are extremely adaptable; successfully colonizing many small

  20. Electronic nose with a new feature reduction method and a multi-linear classifier for Chinese liquor classification

    SciTech Connect (OSTI)

    Jing, Yaqi; Meng, Qinghao, E-mail: qh-meng@tju.edu.cn; Qi, Peifeng; Zeng, Ming; Li, Wei; Ma, Shugen [Tianjin Key Laboratory of Process Measurement and Control, Institute of Robotics and Autonomous Systems, School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072 (China)] [Tianjin Key Laboratory of Process Measurement and Control, Institute of Robotics and Autonomous Systems, School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072 (China)

    2014-05-15T23:59:59.000Z

    An electronic nose (e-nose) was designed to classify Chinese liquors of the same aroma style. A new method of feature reduction which combined feature selection with feature extraction was proposed. Feature selection method used 8 feature-selection algorithms based on information theory and reduced the dimension of the feature space to 41. Kernel entropy component analysis was introduced into the e-nose system as a feature extraction method and the dimension of feature space was reduced to 12. Classification of Chinese liquors was performed by using back propagation artificial neural network (BP-ANN), linear discrimination analysis (LDA), and a multi-linear classifier. The classification rate of the multi-linear classifier was 97.22%, which was higher than LDA and BP-ANN. Finally the classification of Chinese liquors according to their raw materials and geographical origins was performed using the proposed multi-linear classifier and classification rate was 98.75% and 100%, respectively.

  1. Constraining uncertainties about the sources and magnitude of ambient air exposures to polycyclic aromatic hydrocarbons (PAHs): The state of Minnesota as a case study

    E-Print Network [OSTI]

    Lobscheid, Agnes B.; McKone, Thomas E.

    2004-01-01T23:59:59.000Z

    wood, wood waste, and black liquor are reported by thee other= wood waste, black liquor, used oil, petroleum coke,

  2. Potentials and policy implications of energy and material efficiency improvement

    E-Print Network [OSTI]

    Worrell, Ernst; Levine, Mark; Price, Lynn; Martin, Nathan; van den Broek, Richard; Block, Kornelis

    1997-01-01T23:59:59.000Z

    mechanical pulping Black liquor gasification/gasturbinefuels such as bark and black liquor, provide over 50% of the

  3. Black Holes

    E-Print Network [OSTI]

    P. K. Townsend

    1997-07-04T23:59:59.000Z

    Lecture notes for a 'Part III' course 'Black Holes' given in DAMTP, Cambridge. The course covers some of the developments in Black Hole physics of the 1960s and 1970s.

  4. HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING

    SciTech Connect (OSTI)

    Lucia, Lucian A

    2013-04-19T23:59:59.000Z

    Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

  5. Quantum black hole inflation

    E-Print Network [OSTI]

    M. B. Altaie

    2001-05-07T23:59:59.000Z

    In this paper we follow a new approach for particle creation by a localized strong gravitational field. The approach is based on a definition of the physical vacuum drawn from Heisenberg uncertainty principle. Using the fact that the gravitational field red-shifts the frequency modes of the vacuum, a condition on the minimum stregth of the gravitational field required to achieve real particle creation is derived. Application of this requirement on a Schwartzchid black hole resulted in deducing an upper limit on the region, outside the event horizon, where real particles can be created. Using this regional upper limit, and considering particle creation by black holes as a consequence of the Casimir effect, with the assumption that the created quanta are to be added to the initial energy, we deduce a natural power law for the development of the event horizon, and consequently a logarithmic law for the area spectrum of an inflating black hole. Application of the results on a cosmological model shows that if we start with a Planck-dimensional black hole, then through the process of particle creation we end up with a universe having the presently estimated critical density. Such a universe will be in a state of eternal inflation.

  6. Ethanol production from spent sulfite liquor fortified by hydrolysis of pulp mill primary clarifier sludge

    SciTech Connect (OSTI)

    Moritz, J.W.; Duff, S.J.B. [Univ. of British Columbia, Vancouver (Canada)

    1996-12-31T23:59:59.000Z

    Some low-yield sulfite pulping operations ferment spent sulfite liquor (SSL) to remove biochemical oxygen demand associated with dissolved sugars while at the same time generating ethanol as a salable product. Simultaneous saccharification and fermentation (SSF) of primary clarifier sludge in a medium of SSL was proposed as a means of reducing the amount of sludge to be disposed of while at the same time increasing ethanol productivity. In this article, the option of fortifying existing SSL fermenting processes with the sugars produced via in situ enzymatic hydrolysis of sulfite primary clarifier sludge (PCS) has been explored. In 100% SSL PCS hydrolysis rates as high as 3.4 g/(L{center_dot}h) were observed at an initial enzyme loading of 10 filter paper units (FPU)/g PCS. To reduce the deleterious effects of glucose inhibition, single-stage SSF was carried out using cellulose enzymes and Saccharomyces cerevisiae. The production rate of ethanol in SSL was increased by as much as 25% through the SSF process. 12 refs., 4 figs., 2 tabs.

  7. Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors

    SciTech Connect (OSTI)

    Gary Blythe; John Currie; David DeBerry

    2008-03-31T23:59:59.000Z

    This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be measured by UV/visible light spectroscopy. Next, a series of bench-scale wet FGD simulation tests were conducted. Because of the significant effects of sulfite concentration on mercury re-emission rates, new methods were developed for operating and controlling the bench-scale FGD experiments. Approximately 140 bench-scale wet FGD tests were conducted and several unusual and pertinent effects of process chemistry on mercury re-emissions were identified and characterized. These data have been used to develop an empirically adjusted, theoretically based kinetics model to predict mercury species reactions in wet FGD systems. The model has been verified in tests conducted with the bench-scale wet FGD system, where both gas-phase and liquid-phase mercury concentrations were measured to determine if the model accurately predicts the tendency for mercury re-emissions. This report presents and discusses results from the initial laboratory kinetics measurements, the bench-scale wet FGD tests, and the kinetics modeling efforts.

  8. Industry

    E-Print Network [OSTI]

    Bernstein, Lenny

    2008-01-01T23:59:59.000Z

    Air bottoming cycle Black liquor gasification combined cycleCEPI, 2001), and that use continues to grow. Black liquorgasification: Black liquor is the residue from chemical

  9. Magnet options for sensors for the pulp and paper industry

    E-Print Network [OSTI]

    Green, M.A.

    2011-01-01T23:59:59.000Z

    the lignin and moisture content of the black liquor leavingof lignin and other constituents was measured black liquorlignin and cellulose that are dissolved in the black liquor.

  10. Red Harvester Ants

    E-Print Network [OSTI]

    Drees, Bastiaan M.

    2006-04-24T23:59:59.000Z

    Red harvester ants are one of the more noticeable and larger ants in open areas in Texas. However, their populations are declining and this has affected an animal that preys upon the ants--the threatened Texas horned lizard....

  11. Red Raider Orientation COLLEGE DISMISSAL

    E-Print Network [OSTI]

    Rock, Chris

    Communications, etc.) #12;#12;RED RAIDER ORIENTATION Business Administration Accounting Energy Commerce Finance General Business International Business Management Management Information Systems Marketing Visual &Performing Arts Art Dance VPA General Studies Music Theatre Arts #12;RED RAIDER ORIENTATION

  12. Red Rice Research and Control.

    E-Print Network [OSTI]

    Baker, John B.; Baldwin, Ford L.; Bourgeois, W.J.; Cox, Clodis H.; Craigmiles, Julian P.; Dishman, William D.; Eastin, E. Ford; Helpert, Charles W.; Hill, Lewis C.; Huey, Bobby A.; Klosterboer, Arlen D.; Sonnier, Earl A.

    1980-01-01T23:59:59.000Z

    ...................................... 10 E. A. Sonnier RED RICE CONTROL IN ALTERNATE CROPS ................................ 16 F. L. Baldwin ..# RED RICE CONTROL ..................................................lg B. A. Huey and F. L. Baldwin RED RICE HERBICIDE SCREENING TESTS...-to-date information available on a subject of major concern to rice producers. E. F. Eastin, editor The Texas Agricultural Experiment Station Beaumont INTRODUCTION J. P. Craigmiles The purpose of t h i s red r i c e symposium i s straightforward and simple...

  13. Production of ammonium sulfate fertilizer from FGD waste liquors. Quarterly technical report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Randolph, A.D.; Mukhopadhyay, S.; Unrau, E.

    1994-12-31T23:59:59.000Z

    During this quarterly period, an experimental investigation was performed to study the precipitation kinetics and hydrolysis characteristics of calcium imido disulfonate crystals (CaADS). The CaADS crystals were precipitated by a metathetical reaction of lime, supplied by Dravo Lime Co., with flue gas desulfurization (FGD) scrubber waste liquor. Before approaching for the continuous Double Draw-Off (DDO) crystallization studies, the influence of a Dravo lime slurry on the precipitation characteristics of N-S compounds will be established. A series of N-S compound batch crystallization studies were completed in a wide range of pH (7.0--9.0), and the influence of pH on the amount of lime required, as well as the amount of precipitate obtained, was investigated. Although the amount of precipitate increased with increase in solution pH, the safe or optimum pH for the precipitation of CaADS lies in the vicinity of 8.2 to 8.3. For studying the crystallization characteristics of CaADS crystals, a bench scale 7.0 liter DDO crystallizer was built. DDO crystallizer is found to be superior compared to Mixed Suspension Mixed Product Removal (MSMPR) crystallizer. The precipitated crystals were analyzed for elemental composition by chemical analysis. The crystals were also examined under optical microscope for their morphological features. The present studies confirmed our prediction that N-S compounds in the waste liquor can be precipitated by a reaction with lime slurry. The precipitated crystals were mostly calcium imido disulfonate.

  14. RHIC | Black Holes?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Black Holes at RHIC? Further discussion by Physicist Dmitri Kharzeev on why RHIC cannot produce a real gravitational black hole Black holes are among the most mysterious objects in...

  15. Waste Growth Challenges Local Democracy. The Politics of Waste between Europe and the Mediterranean: a Focus on Italy

    E-Print Network [OSTI]

    Mengozzi, Alessandro

    2010-01-01T23:59:59.000Z

    capita); hydro (20%), black liquor, 6 peat, coal, wood fuel,to-door systems, but Black liquor is a byproduct of pulp,

  16. black-bean-salad

    E-Print Network [OSTI]

    Date: Mon, 22 Nov 93 13:06:59 PST From: Jane Colman BLACK BEAN SALAD 3 cups dried black beans, soaked and cooked 3-4 ears...

  17. Chili with Red Beans Ingredients

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    tender, about three minutes. 4. Open kidney beans and pour into a colander. Rinse under cool waterChili with Red Beans Ingredients: 1/2 pound ground beef, extra lean 1 medium onion, chopped 4 cups red kidney beans, soaked overnight or 2 cans, rinsed 3 cups tomatoes, chopped, or 28 ounces, canned 1

  18. Black Pine Engineering

    Broader source: Energy.gov [DOE]

    Black Pine Engineering is commercializing a disruptive technology in the turbomachinery industry. Using a patented woven composite construction, Black Pine Engineering can make turbomachines (turbines, compressors) that are cheaper and lighter than competing technologies. Using this technology, Black Pine Engineering will sell turbo-compressors which solve the problem of wasted steam in geothermal power plants.

  19. Black Bean Burrito Ingredients

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    under running water to remove sodium. 2. Heat beans, corn and salsa together. 3. Spread 1/8 salsaBlack Bean Burrito Ingredients: 15 ounces black beans, canned, drained and rinsed 10 ounces corn cheddar cheese, low-fat, shredded 8 whole wheat flour tortillas Directions 1. Drain and rinse black beans

  20. Jamaican red clay tobacco pipes

    E-Print Network [OSTI]

    Heidtke, Kenan Paul

    1992-01-01T23:59:59.000Z

    JAMAICAN RED CLAY TOBACCO PIPES A Thesis by KENAN PAUL HEIDTKE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF ARTS December 1992 Major Subject...: Anthropology JAMAICAN RED CLAY TOBACCO PIPES A Thesis by KENAN PAUL HEIDTKE Approved as to style and content by: Dorm L. Hamilton (Chair of Committee) Frederick H. van Doorninck, J (Member) enry C. Schmidt (Member) Vaughn M. Bryant (Head...

  1. Hydrogen-terminated silicon nanowire photocatalysis: Benzene oxidation and methyl red decomposition

    SciTech Connect (OSTI)

    Lian, Suoyuan [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China) [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); School of Chemical Engineering and Materials, Dalian Polytechnic University, Dalian 116034 (China); Tsang, Chi Him A. [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China) [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); Centre of Super Diamond and Advanced Films, City University of Hong Kong, Hong Kong (China); Kang, Zhenhui, E-mail: zhkang@suda.edu.cn [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)] [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); Liu, Yang, E-mail: yangl@suda.edu.cn [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)] [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); Wong, Ningbew [Centre of Super Diamond and Advanced Films, City University of Hong Kong, Hong Kong (China)] [Centre of Super Diamond and Advanced Films, City University of Hong Kong, Hong Kong (China); Lee, Shuit-Tong [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China) [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); Centre of Super Diamond and Advanced Films, City University of Hong Kong, Hong Kong (China)

    2011-12-15T23:59:59.000Z

    Graphical abstract: H-SiNWs can catalyze hydroxylation of benzene and degradation of methyl red under visible light irradiation. Highlights: Black-Right-Pointing-Pointer Hydrogen-terminated silicon nanowires were active photocatalyst in the hydroxylation of benzene under light. Black-Right-Pointing-Pointer Hydrogen-terminated silicon nanowires were also effective in the decomposition of methyl red dye. Black-Right-Pointing-Pointer The Si/SiO{sub x} core-shell structure is the main reason of the obtained high selectivity during the hydroxylation. -- Abstract: Hydrogen-terminated silicon nanowires (H-SiNWs) were used as heterogeneous photocatalysts for the hydroxylation of benzene and for the decomposition of methyl red under visible light irradiation. The above reactions were monitored by GC-MS and UV-Vis spectrophotometry, respectively, which shows 100% selectivity for the transformation of benzene to phenol. A complete decomposition of a 2 Multiplication-Sign 10{sup -4} M methyl red solution was achieved within 30 min. The high selectivity for the hydroxylation of benzene and the photodecomposition demonstrate the catalytic activity of ultrafine H-SiNWs during nanocatalysis.

  2. Nombramientos SECRETARIOS

    E-Print Network [OSTI]

    types of fungal bioreactors with inmmobilized Trametes versicolor for post-treated weak black liquor

  3. CHEMICAL ENGINEERING Program of Study

    E-Print Network [OSTI]

    Thomas, Andrew

    reaction engineering in wood pulping and pulp bleaching, char bed modeling, black liquor gasification

  4. BIOLOGICAL ENGINEERING Program of Study

    E-Print Network [OSTI]

    Thomas, Andrew

    reaction engineering in wood pulping and pulp bleaching, char bed modeling, black liquor gasification

  5. BLACK HISTORY MONTH

    Broader source: Energy.gov [DOE]

    Black History Month is an annual celebration of achievements by black Americans and a time for recognizing the central role of African Americans in U.S. history. The event grew out of Negro History Week, created by historian Carter G. Woodson and other prominent African Americans. Other countries around the world, including Canada and the United Kingdom, also devote a month to celebrating black history.

  6. Dynamics of black holes

    E-Print Network [OSTI]

    Sean A. Hayward

    2009-02-28T23:59:59.000Z

    This is a review of current theory of black-hole dynamics, concentrating on the framework in terms of trapping horizons. Summaries are given of the history, the classical theory of black holes, the defining ideas of dynamical black holes, the basic laws, conservation laws for energy and angular momentum, other physical quantities and the limit of local equilibrium. Some new material concerns how processes such as black-hole evaporation and coalescence might be described by a single trapping horizon which manifests temporally as separate horizons.

  7. Red Means Go Information Technology

    E-Print Network [OSTI]

    Projects Budget Issues #12;Red Means Go Strategic Operations Plan (SOP) Articulate the OIT vision, planning, and other business functions Scope: Project will impact university data users (executive Means Go Directions and Opportunities for OIT Three Phase Plan for IT Improvement Develop Strategic

  8. EA-1692: Red River Environmental Products, LLC Activated Carbon...

    Office of Environmental Management (EM)

    2: Red River Environmental Products, LLC Activated Carbon Manufacturing Facility, Red River Parish, LA EA-1692: Red River Environmental Products, LLC Activated Carbon Manufacturing...

  9. Rotating Hairy Black Holes

    E-Print Network [OSTI]

    B. Kleihaus; J. Kunz

    2000-12-20T23:59:59.000Z

    We construct stationary black holes in SU(2) Einstein-Yang-Mills theory, which carry angular momentum and electric charge. Possessing non-trivial non-abelian magnetic fields outside their regular event horizon, they represent non-perturbative rotating hairy black holes.

  10. margrets-black-beans

    E-Print Network [OSTI]

    COM (Robert L. Simmons) Black Beans (Margret Simmons) 2 lbs. dry black beans soaked 8 hrs/overnight 1 qt. veggie stock soaking water plus enough ... 10 garlic cloves finely chopped 1/2 cup cooking sherry 1 tsp. allspice (ground) 1 lemon...

  11. Red Rice Research and Control.

    E-Print Network [OSTI]

    Baker, John B.; Baldwin, Ford L.; Bourgeois, W.J.; Cox, Clodis H.; Craigmiles, Julian P.; Dishman, William D.; Eastin, E. Ford; Helpert, Charles W.; Hill, Lewis C.; Huey, Bobby A.; Klosterboer, Arlen D.; Sonnier, Earl A.

    1980-01-01T23:59:59.000Z

    -to-date information available on a subject of major concern to rice producers. E. F. Eastin, editor The Texas Agricultural Experiment Station Beaumont INTRODUCTION J. P. Craigmiles The purpose of t h i s red r i c e symposium i s straightforward and simple... - t o discuss the l a t e s t f indings and procedures f o r con t ro l l ing red r i c e . In accom- pl ishing t h i s we want two-way communication s o t h a t all present w i l l become current on t h i s most noxious weed of r i c e...

  12. On Noncommutative Black Holes Thermodynamics

    E-Print Network [OSTI]

    Faizal, Mir; Ulhoa, S C

    2015-01-01T23:59:59.000Z

    In this paper, we will analyze noncommutative deformation of the Schwarzschild black holes and Kerr black holes. We will perform our analysis by relating the commutative and the noncommutative metrics using an Moyal product. We will also analyze the thermodynamics of these noncommutative black hole solutions. We will explicitly derive expression for the corrected entropy and temperature of these black hole solutions.

  13. Charging Black Saturn?

    E-Print Network [OSTI]

    Brenda Chng; Robert Mann; Eugen Radu; Cristian Stelea

    2008-10-28T23:59:59.000Z

    We construct new charged static solutions of the Einstein-Maxwell field equations in five dimensions via a solution generation technique utilizing the symmetries of the reduced Lagrangian. By applying our method on the multi-Reissner-Nordstrom solution in four dimensions, we generate the multi-Reissner-Nordstrom solution in five dimensions. We focus on the five-dimensional solution describing a pair of charged black objects with general masses and electric charges. This solution includes the double Reissner-Nordstrom solution as well as the charged version of the five-dimensional static black Saturn. However, all the black Saturn configurations that we could find present either a conical singularity or a naked singularity. We also obtain a non-extremal configuration of charged black strings that reduces in the extremal limit to a Majumdar-Papapetrou like solution in five dimensions.

  14. Do Black Holes Exist?

    E-Print Network [OSTI]

    J. W. Moffat

    1993-02-22T23:59:59.000Z

    The problem of information loss in black hole formation and the associated violations of basic laws of physics, such as conservation of energy, causality and unitarity, are avoided in the nonsymmetric gravitational theory, if the NGT charge of a black hole and its mass satisfy an inequality that does not violate any known experimental data and allows the existence of white dwarfs and neutron stars.

  15. Helical superconducting black holes

    E-Print Network [OSTI]

    Aristomenis Donos; Jerome P. Gauntlett

    2012-05-17T23:59:59.000Z

    We construct novel static, asymptotically $AdS_5$ black hole solutions with Bianchi VII$_0$ symmetry that are holographically dual to superconducting phases in four spacetime dimensions with a helical p-wave order. We calculate the precise temperature dependence of the pitch of the helical order. At zero temperature the black holes have vanishing entropy and approach domain wall solutions that reveal homogenous, non-isotropic dual ground states with emergent scaling symmetry.

  16. Red Mesa | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ | Roadmap Jump to:bJumpRed Bank, New Jersey:Mesa Jump to:

  17. Black hole accretion discs

    E-Print Network [OSTI]

    Lasota, Jean-Pierre

    2015-01-01T23:59:59.000Z

    This is an introduction to models of accretion discs around black holes. After a presentation of the non-relativistic equations describing the structure and evolution of geometrically thin accretion discs we discuss their steady-state solutions and compare them to observation. Next we describe in detail the thermal-viscous disc instability model and its application to dwarf novae for which it was designed and its X-ray irradiated-disc version which explains the soft X--ray transients, i.e. outbursting black-hole low-mass X-ray binaries. We then turn to the role of advection in accretion flow onto black holes illustrating its action and importance with a toy model describing both ADAFs and slim discs. We conclude with a presentation of the general-relativistic formalism describing accretion discs in the Kerr space-time.

  18. MyRED Mobiles Student Views

    E-Print Network [OSTI]

    Farritor, Shane

    tap on Shopping Cart, then select term. Tap on Class Search to find courses to place in your shoppingMyRED Mobiles Student Views Mar 2014 Page 1 Login/Sign-in Enter your MyRED /TrueYou credentials. Tap on any Term bar to view a schedule for the selected term. Home Screen/Main Menu Class Schedule

  19. Thermodynamical instability of black holes

    E-Print Network [OSTI]

    V. V. Kiselev

    2012-08-07T23:59:59.000Z

    In contrast to Hawking radiation of black hole with a given spacetime structure, we consider a competitive transition due to a heat transfer from a hotter inner horizon to a colder outer horizon of Kerr black hole, that results in a stable thermodynamical state of extremal black hole. In this process, by supposing an emission of gravitational quanta, we calculate the mass of extremal black hole in the final state of transition.

  20. Towards noncommutative quantum black holes

    SciTech Connect (OSTI)

    Lopez-Dominguez, J. C.; Obregon, O.; Sabido, M.; Ramirez, C. [Instituto de Fisica de la Universidad de Guanajuato, P.O. Box E-143, 37150 Leon Gto. (Mexico); Facultad de Ciencias Fisico Matematicas, Universidad Autonoma de Puebla, P.O. Box 1364, 72000 Puebla (Mexico)

    2006-10-15T23:59:59.000Z

    In this paper we study noncommutative black holes. We use a diffeomorphism between the Schwarzschild black hole and the Kantowski-Sachs cosmological model, which is generalized to noncommutative minisuperspace. Through the use of the Feynman-Hibbs procedure we are able to study the thermodynamics of the black hole, in particular, we calculate the Hawking's temperature and entropy for the noncommutative Schwarzschild black hole.

  1. Black Holes at Accelerators

    E-Print Network [OSTI]

    Bryan Webber

    2006-04-06T23:59:59.000Z

    In theories with large extra dimensions and TeV-scale gravity, black holes are copiously produced in particle collisions at energies well above the Planck scale. I briefly review some recent work on the phenomenology of this process, with emphasis on theoretical uncertainties and possible strategies for measuring the number of extra dimensions.

  2. U-200: Red Hat Directory Server Information Disclosure Security...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0: Red Hat Directory Server Information Disclosure Security Issue and Vulnerability U-200: Red Hat Directory Server Information Disclosure Security Issue and Vulnerability June 27,...

  3. T-678: Red Hat Enterprise Virtualization Hypervisor VLAN Packet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Red Hat Enterprise Virtualization Hypervisor VLAN Packet Processing Flaw Lets Remote Users Deny Service T-678: Red Hat Enterprise Virtualization Hypervisor VLAN Packet...

  4. On Bitcoin and Red Balloons

    E-Print Network [OSTI]

    Babaioff, Moshe; Oren, Sigal; Zohar, Aviv

    2011-01-01T23:59:59.000Z

    We study scenarios in which the goal is to ensure that some information will propagate through a large network of nodes. In these scenarios all nodes that are aware of the information compete for the same prize, and thus have an incentive not to propagate information. One example for such a scenario is the 2009 DARPA Network Challenge (finding red balloons). We give special attention to a second domain, Bitcoin, a decentralized electronic currency system. Bitcoin, which has been getting a large amount of public attention over the last year, represents a radical new approach to monetary systems which has appeared in policy discussions and in the popular press. Its cryptographic fundamentals have largely held up even as its usage has become increasingly widespread. We find, however, that it exhibits a fundamental problem of a different nature, based on how its incentives are structured. We propose a modification to the protocol that can fix this problem. Bitcoin relies on a peer-to-peer network to track transac...

  5. BLACK HOLE AURORA POWERED BY A ROTATING BLACK HOLE

    SciTech Connect (OSTI)

    Takahashi, Masaaki [Department of Physics and Astronomy, Aichi University of Education, Kariya, Aichi 448-8542 (Japan); Takahashi, Rohta, E-mail: takahasi@phyas.aichi-edu.ac.j [Cosmic Radiation Laboratory, Institute of Physical and Chemical Research, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)

    2010-05-15T23:59:59.000Z

    We present a model for high-energy emission sources generated by a standing magnetohydrodynamical (MHD) shock in a black hole magnetosphere. The black hole magnetosphere would be constructed around a black hole with an accretion disk, where a global magnetic field could be originated by currents in the accretion disk and its corona. Such a black hole magnetosphere may be considered as a model for the central engine of active galactic nuclei, some compact X-ray sources, and gamma-ray bursts. The energy sources of the emission from the magnetosphere are the gravitational and electromagnetic energies of magnetized accreting matters and the rotational energy of a rotating black hole. When the MHD shock generates in MHD accretion flows onto the black hole, the plasma's kinetic energy and the black hole's rotational energy can convert to radiative energy. In this Letter, we demonstrate the huge energy output at the shock front by showing negative energy postshock accreting MHD flows for a rapidly rotating black hole. This means that the extracted energy from the black hole can convert to the radiative energy at the MHD shock front. When an axisymmetric shock front is formed, we expect a ring-shaped region with very hot plasma near the black hole; this would look like an 'aurora'. The high-energy radiation generated from there would carry to us the information for the curved spacetime due to the strong gravity.

  6. Viscoelastic transient of confined Red Blood Cells

    E-Print Network [OSTI]

    Gal Prado; Alexander Farutin; Chaouqi Misbah; Lionel Bureau

    2014-09-17T23:59:59.000Z

    The unique ability of a red blood cell to flow through extremely small microcapillaries depends on the viscoelastic properties of its membrane. Here, we study in vitro the response time upon flow startup exhibited by red blood cells confined into microchannels. We show that the characteristic transient time depends on the imposed flow strength, and that such a dependence gives access to both the effective viscosity and the elastic modulus controlling the temporal response of red cells. A simple theoretical analysis of our experimental data, validated by numerical simulations, further allows us to compute an estimate for the two-dimensional membrane viscosity of red blood cells, $\\eta_{mem}^{2D}\\sim 10^{-7}$ N$\\cdot$s$\\cdot$m$^{-1}$. By comparing our results with those from previous studies, we discuss and clarify the origin of the discrepancies found in the literature regarding the determination of $\\eta_{mem}^{2D}$, and reconcile seemingly conflicting conclusions from previous works.

  7. Right Turn on Red! | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    benefits for the country, helping us all save money by saving energy. Prior to the 1970's, some states already allowed drivers to turn right on a red light, but many others -...

  8. Redding Electric- Earth Advantage Rebate Program

    Broader source: Energy.gov [DOE]

    The Earth Advantage Rebate Program was designed to offer rebates to residential and business customers of Redding Electric Utility (REU) for solar PV, solar thermal, and geothermal heat pump...

  9. THE TEMPERATURES OF RED SUPERGIANTS

    SciTech Connect (OSTI)

    Davies, Ben [Astrophysics Research Institute, Liverpool John Moores University, Egerton Wharf, Birkenhead CH41 1LD (United Kingdom)] [Astrophysics Research Institute, Liverpool John Moores University, Egerton Wharf, Birkenhead CH41 1LD (United Kingdom); Kudritzki, Rolf-Peter; Gazak, Zach [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States)] [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States); Plez, Bertrand [Laboratoire Univers et Particules de Montpellier, Universite Montpellier 2, CNRS, F-34095 Montpellier (France)] [Laboratoire Univers et Particules de Montpellier, Universite Montpellier 2, CNRS, F-34095 Montpellier (France); Trager, Scott [Kapteyn Institute, University of Groningen, P.O. Box 800, 9700-AV Groningen (Netherlands)] [Kapteyn Institute, University of Groningen, P.O. Box 800, 9700-AV Groningen (Netherlands); Lancon, Ariane [Observatoire Astronomique and CNRS UMR 7550, Universite de Strasbourg, F-67000 Strasbourg (France)] [Observatoire Astronomique and CNRS UMR 7550, Universite de Strasbourg, F-67000 Strasbourg (France); Bergemann, Maria [Max-Planck-Institute for Astrophysics, Karl-Schwarzschild-Str. 1, D-85741 Garching (Germany)] [Max-Planck-Institute for Astrophysics, Karl-Schwarzschild-Str. 1, D-85741 Garching (Germany); Evans, Chris [UK Astronomy Technology Centre, Royal Observatory Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom)] [UK Astronomy Technology Centre, Royal Observatory Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom); Chiavassa, Andrea [CNRS Laboratoire Lagrange, Universite de Nice Sophia-Antipolis, Observatoire de la Cote d'Azur, BP 4229, F-06304 Nice Cedex 4 (France)] [CNRS Laboratoire Lagrange, Universite de Nice Sophia-Antipolis, Observatoire de la Cote d'Azur, BP 4229, F-06304 Nice Cedex 4 (France)

    2013-04-10T23:59:59.000Z

    We present a re-appraisal of the temperatures of red supergiants (RSGs) using their optical and near-infrared spectral energy distributions (SEDs). We have obtained data of a sample of RSGs in the Magellanic Clouds using VLT+XSHOOTER, and we fit MARCS model atmospheres to different regions of the spectra, deriving effective temperatures for each star from (1) the TiO bands, (2) line-free continuum regions of the SEDs, and (3) the integrated fluxes. We show that the temperatures derived from fits to the TiO bands are systematically lower than the other two methods by several hundred kelvin. The TiO fits also dramatically overpredict the flux in the near-IR, and imply extinctions which are anomalously low compared to neighboring stars. In contrast, the SED temperatures provide good fits to the fluxes at all wavelengths other than the TiO bands, are in agreement with the temperatures from the flux integration method, and imply extinctions consistent with nearby stars. After considering a number of ways to reconcile this discrepancy, we conclude that three-dimensional effects (i.e., granulation) are the most likely cause, as they affect the temperature structure in the upper layers where the TiO lines form. The continuum, however, which forms at much deeper layers, is apparently more robust to such effects. We therefore conclude that RSG temperatures are much warmer than previously thought. We discuss the implications of this result for stellar evolution and supernova progenitors, and provide relations to determine the bolometric luminosities of RSGs from single-band photometry.

  10. Shape of black holes

    E-Print Network [OSTI]

    Clement, Mara E Gabach

    2015-01-01T23:59:59.000Z

    It is well known that celestial bodies tend to be spherical due to gravity and that rotation produces deviations from this sphericity. We discuss what is known and expected about the shape of black holes' horizons from their formation to their final, stationary state. We present some recent results showing that black hole rotation indeed manifests in the widening of their central regions, limits their global shapes and enforces their whole geometry to be close to the extreme Kerr horizon geometry at almost maximal rotation speed. The results depend only on the horizon area and angular momentum. In particular they are entirely independent of the surrounding geometry of the spacetime and of the presence of matter satisfying the strong energy condition. We also discuss the the relation of this result with the Hoop conjecture.

  11. Black Pine Circle Project

    ScienceCinema (OSTI)

    Mytko, Christine

    2014-09-15T23:59:59.000Z

    A group of seventh graders from Black Pine Circle school in Berkeley had the opportunity to experience the Advanced Light Source (ALS) as "users" via a collaborative field trip and proposal project. The project culminated with a field trip to the ALS for all seventh graders, which included a visit to the ALS data visualization room, a diffraction demonstration, a beamline tour, and informative sessions about x-rays and tomography presented by ALS scientists.

  12. Black Pine Circle Project

    SciTech Connect (OSTI)

    Mytko, Christine

    2014-03-31T23:59:59.000Z

    A group of seventh graders from Black Pine Circle school in Berkeley had the opportunity to experience the Advanced Light Source (ALS) as "users" via a collaborative field trip and proposal project. The project culminated with a field trip to the ALS for all seventh graders, which included a visit to the ALS data visualization room, a diffraction demonstration, a beamline tour, and informative sessions about x-rays and tomography presented by ALS scientists.

  13. POPULATION BIOLOGY OF RED ABAWNES, HALIOTIS RUFESCENS, IN SOUTHERN CALIFORNIA AND MANAGEMENT OF THE RED AND

    E-Print Network [OSTI]

    ABSTRACT Population dynamics of red abalones. Halwti.s rufeSC611,8 Swainson. were studied at Johnsons Lee

  14. Black holes in massive gravity

    E-Print Network [OSTI]

    Babichev, Eugeny

    2015-01-01T23:59:59.000Z

    We review the black hole solutions of the ghost-free massive gravity theory and its bimetric extension and outline the main results on the stability of these solutions against small perturbations. Massive (bi)-gravity accommodates exact black hole solutions, analogous to those of General Relativity. In addition to these solutions, hairy black holes -- solutions with no correspondent in General Relativity -- have been found numerically, whose existence is a natural consequence of the absence of the Birkhoff's theorem in these theories. The existence of extra propagating degrees of freedom, makes the stability properties of these black holes richer and more complex than those of General Relativity. In particular, the bi-Schwarzschild black hole exhibits an unstable spherically symmetric mode, while the bi-Kerr geometry is also generically unstable, both against the spherical mode and against superradiant instabilities. If astrophysical black holes are described by these solutions, the superradiant instability o...

  15. Black Hole's 1/N Hair

    E-Print Network [OSTI]

    Gia Dvali; Cesar Gomez

    2012-03-29T23:59:59.000Z

    According to the standard view classically black holes carry no hair, whereas quantum hair is at best exponentially weak. We show that suppression of hair is an artifact of the semi-classical treatment and that in the quantum picture hair appears as an inverse mass-square effect. Such hair is predicted in the microscopic quantum description in which a black hole represents a self-sustained leaky Bose-condensate of N soft gravitons. In this picture the Hawking radiation is the quantum depletion of the condensate. Within this picture we show that quantum black hole physics is fully compatible with continuous global symmetries and that global hair appears with the strength B/N, where B is the global charge swallowed by the black hole. For large charge this hair has dramatic effect on black hole dynamics. Our findings can have interesting astrophysical consequences, such as existence of black holes with large detectable baryonic and leptonic numbers.

  16. MFR PAPER 1229 Red Snappers of the Carolina Coast

    E-Print Network [OSTI]

    Coast to the Campeche Banks. A closely related species, the Caribbean red snapper, Lutjanus pur- pureus

  17. Improved ``Optical Highlighter'' Probes Derived from Discosoma Red Fluorescent Protein

    E-Print Network [OSTI]

    Marchant, Jonathan

    , Minneapolis, Minnesota ABSTRACT The tetrameric red fluorescent protein, DsRed, undergoes a rapid red to green-emitting species of DsRed and an enhancement of emission from the ``immature'' green species, likely caused by dequenching of fluorescence resonance energy transfer occurring within the protein tetramer. Here, we have

  18. Newtonian gravity, red shift, confinement, asymptotic freedom and quarks oscillations

    E-Print Network [OSTI]

    G. Quznetsov

    2008-10-18T23:59:59.000Z

    Quarks oscillations give the Newtonian gravity law, the red shift, the confinement and the asymptotic freedom.

  19. Observational Evidence for Black Holes

    E-Print Network [OSTI]

    Ramesh Narayan; Jeffrey E. McClintock

    2014-07-20T23:59:59.000Z

    Astronomers have discovered two populations of black holes: (i) stellar-mass black holes with masses in the range 5 to 30 solar masses, millions of which are present in each galaxy in the universe, and (ii) supermassive black holes with masses in the range 10^6 to 10^{10} solar masses, one each in the nucleus of every galaxy. There is strong circumstantial evidence that all these objects are true black holes with event horizons. The measured masses of supermassive black hole are strongly correlated with properties of their host galaxies, suggesting that these black holes, although extremely small in size, have a strong influence on the formation and evolution of entire galaxies. Spin parameters have recently been measured for a handful of black holes. Based on the data, there is an indication that the kinetic power of at least one class of relativistic jet ejected from accreting black holes may be correlated with black hole spin. If verified, it would suggest that these jets are powered by a generalized Penrose process mediated by magnetic fields.

  20. Conserving Scotland's Red Squirrels Scotland supports an estimated 75% of the UK red squirrel population. Although one

    E-Print Network [OSTI]

    to save the red squirrel for future generations. We will continue to be involved with wider partnerships is co-ordinated nationwide. Public involvement is crucial to saving red squirrels in Scotland and we are delighted to support this through projects such as Saving Scotland's Red Squirrels, Red Squirrels

  1. Dermoscopy of black-spot poison ivy

    E-Print Network [OSTI]

    Rader, Ryan K; Mu, Ruipu; Shi, Honglan; Stoecker, William V; Hinton, Kristen A

    2012-01-01T23:59:59.000Z

    CT, Bean AS. Black-spot poison ivy: A rare phenomenon. J AmJG, Lucky AW. Black spot poison ivy: A report of 5 cases andis unique for black-spot poison ivy. The UFLC-MS/MS urushiol

  2. Why Blue-Collar Blacks Help Less

    E-Print Network [OSTI]

    Smith, Sandra Susan; Young, Kara Alexis

    2013-01-01T23:59:59.000Z

    Exclude Black Men from Blue-Collar Jobs. Berkeley, CA:How Black and Latino Blue Collar Workers Make Decisionsof Sample Respondents Blue-Collar Latinos Blue-Collar Black

  3. 7X performance results - final report : ASCI Red vs Red Storm.

    SciTech Connect (OSTI)

    Dinge, Dennis C. (Cray Inc., Albuquerque, NM); Davis, Michael E. (Cray Inc., Albuquerque, NM); Haskell, Karen H.; Ballance, Robert A.; Gardiner, Thomas Anthony; Stevenson, Joel O.; Noe, John P.

    2011-04-01T23:59:59.000Z

    The goal of the 7X performance testing was to assure Sandia National Laboratories, Cray Inc., and the Department of Energy that Red Storm would achieve its performance requirements which were defined as a comparison between ASCI Red and Red Storm. Our approach was to identify one or more problems for each application in the 7X suite, run those problems at multiple processor sizes in the capability computing range, and compare the results between ASCI Red and Red Storm. The first part of this report describes the two computer systems, the applications in the 7X suite, the test problems, and the results of the performance tests on ASCI Red and Red Storm. During the course of the testing on Red Storm, we had the opportunity to run the test problems in both single-core mode and dual-core mode and the second part of this report describes those results. Finally, we reflect on lessons learned in undertaking a major head-to-head benchmark comparison.

  4. CUTTING SOLAR RED TAPECUTTING SOLAR RED TAPE Evergreen State Solar PartnershipEvergreen State Solar Partnership

    E-Print Network [OSTI]

    CUTTING SOLAR RED TAPECUTTING SOLAR RED TAPE Evergreen State Solar PartnershipEvergreen State Solar Partnership Rooftop Solar Challenge 1 Sunshot #12;WASHINGTON PV CONTEXTWASHINGTON PV CONTEXT 285 cities, 39 Installations happen where process is easier #12;EVERGREEN STATE SOLAR PARTNERSHIP Commerce NWSEEDEdmonds

  5. Black Stars and Gamma Ray Bursts

    E-Print Network [OSTI]

    Tanmay Vachaspati

    2007-06-08T23:59:59.000Z

    Stars that are collapsing toward forming a black hole but are frozen near the Schwarzschild horizon are termed ``black stars''. Collisions of black stars, in contrast to black hole collisions, may be sources of gamma ray bursts, whose basic parameters are estimated quite simply and are found to be consistent with observed gamma ray bursts. Black star gamma ray bursts should be preceded by gravitational wave emission similar to that from the coalescence of black holes.

  6. Red mud characterization using nuclear analytical techniques

    SciTech Connect (OSTI)

    Obhodas, J.; Sudac, D.; Matjacic, L. [Dept. of Experimental Physics, Inst. Ruder Boskovic, Zagreb (Croatia); Valkovic, V. [A.C.T.d.o.o., Prilesje 4, Zagreb (Croatia)

    2011-07-01T23:59:59.000Z

    Red mud is a toxic waste left as a byproduct in aluminum production Bayer process. Since it contains significant concentrations of other chemical elements interesting for industry, including REE, it is also potential secondary ore source. Recent events in some countries have shown that red mud presents a serious environmental hazard if not properly stored. The subject of our study is the red mud from an ex-aluminum plant in Obrovac, Croatia, left from processing of bauxite mined during late 70's and early 80's at the eastern Adriatic coast and since than stored in open concrete basins for more than 30 years. We have used energy dispersive x-ray fluorescence analysis (both tube and radioactive source excitation), fast neutron activation analysis and passive gamma spectrometry to identify a number of elements present in the red mud, their concentration levels and radioactivity in the red mud. The high concentrations of Al, Si, Ca, Ti and Fe have been measured. Chemical elements Sc, Cr, Mn, Co, Ni, Cu, Zn, Ga, As, Se, Br, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Pb, Th and U were found in lower concentrations. No significant levels of radioactivity have been measured. (authors)

  7. Idaho_BlackCanyon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogenIT | NationalMentoringWind Power -Mtn. Black

  8. Evaluation of hydropyrolysis as an energy-saving alternative to the Tomlinson furnace. Task II. Chemistry of hydropyrolysis

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    Studies were conducted of reactions involving model compounds of black liquor and reaction products when reacting black liquor at extreme conditions for the purpose of understanding the chemistry occurring in hydropyrolysis. Reaction studies of model compounds included: lignin precipitated from black liquor, the sodium salt of saccharinic acid, sodium lactate, sodium glycolate, sodium oxalate, sodium acetate and sodium formate.

  9. Optical black holes and solitons

    E-Print Network [OSTI]

    Shawn Westmoreland

    2010-12-21T23:59:59.000Z

    We exhibit a static, cylindrically symmetric, exact solution to the Euler-Heisenberg field equations (EHFE) and prove that its effective geometry contains (optical) black holes. It is conjectured that there are also soliton solutions to the EHFE which contain black hole geometries.

  10. Black Holes of Negative Mass

    E-Print Network [OSTI]

    R. B. Mann

    1997-05-06T23:59:59.000Z

    I demonstrate that, under certain circumstances, regions of negative energy density can undergo gravitational collapse into a black hole. The resultant exterior black hole spacetimes necessarily have negative mass and non-trivial topology. A full theory of quantum gravity, in which topology-changing processes take place, could give rise to such spacetimes.

  11. Black Beans and Rice Ingredients

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    Black Beans and Rice Ingredients: 1 teaspoon vegetable oil 1 medium onion, chopped 2 bay leaves 4 cloves garlic, minced 2 (15 oz.) cans black beans, drained and rinsed 1 tbsp. cilantro 15 ounces low-fat, shredded Directions 1. Rinse beans with water in colander to remove sodium. 2. Saut onions, garlic

  12. Black Bean Stuffed Peppers Ingredients

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    except cheese. 4. Fill each pepper half with bean mixture and place in pan. 5. Pour 1/4 cup waterBlack Bean Stuffed Peppers Ingredients: Non stick cooking spray 3 green peppers 15 ounces black beans, canned, drained and rinsed to remove sodium 8 ounces corn, canned 1 cup brown rice, cooked 1

  13. Red River Biodiesel Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ | Roadmap Jump to:bJumpRed Bank, New Jersey:Mesa Jump to:Red

  14. Redding, Connecticut: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt Ltd Jump to: navigation, searchRay County,OpenCounty, Texas:RedRedbird,Redding,

  15. Major Mergers Host the Most Luminous Red Quasars at z ~ 2: A Hubble Space Telescope WFC3/IR Study

    E-Print Network [OSTI]

    Glikman, Eilat; Mailly, Madeline; Schawinski, Kevin; Urry, C M; Lacy, M

    2015-01-01T23:59:59.000Z

    We used the Hubble Space Telescope WFC3 near-infrared camera to image the host galaxies of a sample of eleven luminous, dust-reddened quasars at z ~ 2 -- the peak epoch of black hole growth and star formation in the Universe -- to test the merger-driven picture for the co-evolution of galaxies and their nuclear black holes. The red quasars come from the FIRST+2MASS red quasar survey and a newer, deeper, UKIDSS+FIRST sample. These dust-reddened quasars are the most intrinsically luminous quasars in the Universe at all redshifts, and may represent the dust-clearing transitional phase in the merger-driven black hole growth scenario. Probing the host galaxies in rest-frame visible light, the HST images reveal that 8/10 of these quasars have actively merging hosts, while one source is reddened by an intervening lower redshift galaxy along the line-of-sight. We study the morphological properties of the quasar hosts using parametric Sersic fits as well as the non-parametric estimators (Gini coefficient, M_{20} and a...

  16. Red and Black: A Divided Seminole Nation: U.S. vs. Davis

    E-Print Network [OSTI]

    McCray Pearson, Joyce A.

    2005-01-01T23:59:59.000Z

    The Seminole Nation comprises persons of both Native American and African-American descent. The African-American constituency of the nation has battled in the courts to have its benefits under Federal law recognized. The ...

  17. Watch for the red dot indicating

    E-Print Network [OSTI]

    > http:// > Watch for the red dot indicating expanded stories online sdm.mit.edu/pulse continued its facilities by constructing the European Extremely Large Telescope (E-ELT) on a mountain in Chile isolated from the grid. The planned construction of the E-ELT and the challenges faced by the current

  18. Author Proof Plants on red alert

    E-Print Network [OSTI]

    Schaefer, Martin

    Author Proof A Plants on red alert: do insects pay attention? H. Martin Schaefer* and Gregor Rolshausen Summary Two recent hypotheses have proposed that non-green plant colouration evolved as a defence against herbi- vores, either as protective colouration promoting handi- cap signals indicating plant

  19. The FIRST-2MASS Red Quasar Survey

    SciTech Connect (OSTI)

    Glikman, E; Helfand, D J; White, R L; Becker, R H; Gregg, M D; Lacy, M

    2007-06-28T23:59:59.000Z

    Combining radio observations with optical and infrared color selection--demonstrated in our pilot study to be an efficient selection algorithm for finding red quasars--we have obtained optical and infrared spectroscopy for 120 objects in a complete sample of 156 candidates from a sky area of 2716 square degrees. Consistent with our initial results, we find our selection criteria--J-K > 1.7,R-K > 4.0--yield a {approx} 50% success rate for discovering quasars substantially redder than those found in optical surveys. Comparison with UVX- and optical color-selected samples shows that {approx}> 10% of the quasars are missed in a magnitude-limited survey. Simultaneous two-frequency radio observations for part of the sample indicate that a synchrotron continuum component is ruled out as a significant contributor to reddening the quasars spectra. We go on to estimate extinctions for our objects assuming their red colors are caused by dust. Continuum fits and Balmer decrements suggest E(B-V) values ranging from near zero to 2.5 magnitudes. Correcting the K-band magnitudes for these extinctions, we find that for K {le} 14.0, red quasars make up between 25% and 60% of the underlying quasar population; owing to the incompleteness of the 2MASS survey at fainter K-band magnitudes, we can only set a lower limit to the radio-detected red quasar population of > 20-30%.

  20. Carta de Servicios Red de Bibliotecas

    E-Print Network [OSTI]

    Bibliotecas que pueden pertenecer a la Red, en la que se realizan los trabajos técnicos precisos para bibliotecarios que permitan el acceso a la información, ya sea de forma presencial o a distancia. servicios para trabajo en grupo. · Préstamo personal Permite a los usuarios utilizar las colecciones de su

  1. The Red Planet Mars is noticeable

    E-Print Network [OSTI]

    Walter, Frederick M.

    the melting polar ice, and to distribute the water among the oases #12;Camille Flammarion (1884) #12;Chesley Viewed through a telescope: Mars has white polar caps Mars has dark (greenish) and bright (red;Northern Polar Cap in Spring #12;The Facts of Mars mass = 0.11M radius = 0.53 R density = 3.9 gm/cm3

  2. Healthy Plate Red onion, rhubarb, radicchio,

    E-Print Network [OSTI]

    Bogyo, Matthew

    , bananas, kiwi, figs, watermelon Whole Grains & Fruit Combination Ideas: Poultry, fish, beans, lentils Beans + Spinach + Tomato Sauce Wild Rice + Lentils + Red Onion + Summer Squash Spring Rolls (recipe ROASTED LENTILS For the Rolls Rice wrapping paper Pan of water Veggies of choice (i.e. carrots, jalapeos

  3. Black optic display

    DOE Patents [OSTI]

    Veligdan, James T. (Manorville, NY)

    1997-01-01T23:59:59.000Z

    An optical display includes a plurality of stacked optical waveguides having first and second opposite ends collectively defining an image input face and an image screen, respectively, with the screen being oblique to the input face. Each of the waveguides includes a transparent core bound by a cladding layer having a lower index of refraction for effecting internal reflection of image light transmitted into the input face to project an image on the screen, with each of the cladding layers including a cladding cap integrally joined thereto at the waveguide second ends. Each of the cores is beveled at the waveguide second end so that the cladding cap is viewable through the transparent core. Each of the cladding caps is black for absorbing external ambient light incident upon the screen for improving contrast of the image projected internally on the screen.

  4. Strings, higher curvature corrections, and black holes

    E-Print Network [OSTI]

    Thomas Mohaupt

    2005-12-05T23:59:59.000Z

    We review old and recent results on subleading contributions to black hole entropy in string theory.

  5. Red Hole Gamma-Ray Bursts: A New Gravitational Collapse Paradigm Explains the Peak Energy Distribution and Solves the GRB Energy Crisis

    E-Print Network [OSTI]

    James S. Graber

    1999-12-15T23:59:59.000Z

    Gamma-ray bursts (GRBs) are still an enigma. In particular the central engine, the total energy, and the very narrow distribution of peak energies challenge model builders. Motivated by recent theoretical developments (string theory, quantum gravity, critical collapse), which suggest that complete gravitational collapse can occur without singularities or event horizons, we explore how red-hole models (which lack singularities or event horizons) can solve these problems better than black-hole models.

  6. E-Print Network 3.0 - aux red oils Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology 22 Red Leaf Resources and the Commercialization of Oil Shale Summary: Red Leaf Resources and the Commercialization of Oil Shale 12;About Red...

  7. artificial red blood: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as long-circulating drug carriers 3. RBC as red blood cells to evade the immune system Ronnie Hongbo Fang, Che-Ming Jack Hu & Liangfang Zhang-circulating entities, red blood...

  8. WHEN THE BLUE-GREEN WATERS TURN RED

    E-Print Network [OSTI]

    WHEN THE BLUE-GREEN WATERS TURN RED Historical Flooding in Havasu Creek, Arizona U.S. GEOLOGICAL OF RECLAMATION #12;WHEN THE BLUE-GREEN WATERS TURN RED Historical Flooding in Havasu Creek, Arizona By THEODORE S

  9. Red-luminescent europium (III) doped silica nanoshells: synthesis,

    E-Print Network [OSTI]

    Kummel, Andrew C.

    Red-luminescent europium (III) doped silica nanoshells: synthesis, characterization(6), 066012 (June 2011) Red-luminescent europium (III) doped silica nanoshells: synthesis, characterization (SPIE). [DOI: 10.1117/1.3593003] Keywords: europium; silica; luminescent; nanoshells; endocytosis. Paper

  10. Cobalt-iron red-ox behavior in nanostructured La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} cathodes

    SciTech Connect (OSTI)

    Soldati, Analia L., E-mail: asoldati@cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Baque, Laura, E-mail: baque.laura@gmail.com [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Napolitano, Federico, E-mail: napolitf@ib.cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina); Serquis, Adriana, E-mail: aserquis@cab.cnea.gov.ar [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)] [CONICET-CNEA Departamento de Caracterizacion de Materiales, Centro Atomico Bariloche, Av. Bustillo 9500, S.C. de Bariloche R8402AGP, Rio Negro (Argentina)

    2013-02-15T23:59:59.000Z

    Nano-sized La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF) perovskite samples (prepared by a conventional acetate route and a novel acetate synthesis with HMTA additives), were tested simulating a red-ox cycle. The crystallography was studied by X-ray Powder Diffraction (XPD) and the changes in the oxidation state of the perovskite B-site were evaluated by synchrotron X-ray Absorption Near Edge Spectroscopy (XANES). After a reducing treatment, LSFC particles show the appearance of a new phase that coexists with the original one. The structural change is accompanied by a Co and Fe formal oxidation states decrease, although Fe remains always closer to 4+ and Co closer to 3+. The treatment produces a B-site valence average reduction from 3.52+ to 3.26+ and the formation of oxygen vacancies. A re-oxidation treatment under O{sub 2} rich atmosphere at 800 Degree-Sign C for 10 h shows that the change is reversible and independent of the two chemical methods used to synthesize the LSCF nano-particles. - Graphical abstract: XANES and XPD measurements in nanostructured LSCF before (black) and after (red/green) a red/ox cycle. Highlights: Black-Right-Pointing-Pointer Red-ox treatments in LSCF nano-particles cause a reversible reaction. Black-Right-Pointing-Pointer XPD analyses show that a new 'reduced' phase coexist with the oxidize one. Black-Right-Pointing-Pointer The B-site formal oxidation state decreases and the {delta} increases upon reduction. Black-Right-Pointing-Pointer Fe remains in a higher valence (closer to 4+) than Co (close to 3+). Black-Right-Pointing-Pointer The behavior seems to be independent of the synthesis method used.

  11. Thermodynamics of regular black hole

    E-Print Network [OSTI]

    Yun Soo Myung; Yong-Wan Kim; Young-Jai Park

    2008-09-21T23:59:59.000Z

    We investigate thermodynamics for a magnetically charged regular black hole (MCRBH), which comes from the action of general relativity and nonlinear electromagnetics, comparing with the Reissner-Norstr\\"om (RN) black hole in both four and two dimensions after dimensional reduction. We find that there is no thermodynamic difference between the regular and RN black holes for a fixed charge $Q$ in both dimensions. This means that the condition for either singularity or regularity at the origin of coordinate does not affect the thermodynamics of black hole. Furthermore, we describe the near-horizon AdS$_2$ thermodynamics of the MCRBH with the connection of the Jackiw-Teitelboim theory. We also identify the near-horizon entropy as the statistical entropy by using the AdS$_2$/CFT$_1$ correspondence.

  12. Black Hole Interior Mass Formula

    E-Print Network [OSTI]

    Parthapratim Pradhan

    2014-05-06T23:59:59.000Z

    We argue by explicit computations that, although the area product, horizon radii product, entropy product and \\emph {irreducible mass product} of the event horizon and Cauchy horizon are universal, the \\emph{surface gravity product}, \\emph{surface temperature product} and \\emph{Komar energy product} of the said horizons do not seem to be universal for Kerr-Newman (KN) black hole space-time. We show the black hole mass formula on the \\emph{Cauchy horizon} following the seminal work by Smarr\\cite{smarr} for the outer horizon. We also prescribed the \\emph{four} laws of black hole mechanics for the \\emph{inner horizon}. New definition of the extremal limit of a black hole is discussed.

  13. Is the Missing Ultra-Red Material Colorless Ice?

    E-Print Network [OSTI]

    W. M. Grundy

    2008-11-14T23:59:59.000Z

    The extremely red colors of some transneptunian objects and Centaurs are not seen among the Jupiter family comets which supposedly derive from them. Could this mismatch result from sublimation loss of colorless ice? Radiative transfer models show that mixtures of volatile ice and nonvolatile organics could be extremely red, but become progressively darker and less red as the ice sublimates away.

  14. `Save Our Squirrels' (SOS) A Red Alert North England Project

    E-Print Network [OSTI]

    `Save Our Squirrels' (SOS) A Red Alert North England Project objectives The red squirrel is Britain in England. Action is needed if numbers are to be stabilised. The `Save Our Squirrels' Project (SOS) was set targeted area works with partners and woodland owners to fight to save the red squirrel. We

  15. Red Blood Cell Segmentation from SEM Images Joost Vromen

    E-Print Network [OSTI]

    McCane, Brendan

    Red Blood Cell Segmentation from SEM Images Joost Vromen Human Media Interaction University Microscope image of red blood cells. We use a second order polynomial model and a simple Bayesian approach sample images involving more than 11000 red blood cells. I. INTRODUCTION There is considerable evidence

  16. Red Leaf Resources and the Commercialization of Oil Shale

    E-Print Network [OSTI]

    Utah, University of

    Red Leaf Resources and the Commercialization of Oil Shale #12;About Red Leaf Resources 2006 Company commercial development field activities #12;Highlights Proven, Revolutionary Oil Shale Extraction Process Technology Significant Owned Oil Shale Resource #12; The executive management team of Red Leaf Resources

  17. Fishing in Black Holes

    E-Print Network [OSTI]

    A. Brotas

    2006-09-01T23:59:59.000Z

    The coordinate system $(\\bar{x},\\bar{t})$ defined by $r = 2m + K\\bar{x}- c K \\bar{t}$ and $t=\\bar{x}/cK - 1 /cK \\int_{r_a}^r (1- 2m/r + K^2)^{1/2} (1 - 2m/r)^{-1}dr$ allow us to write the Schwarzschild metric in the form: \\[ds^2=c^2 d\\bar{t}^2 + (W^2/K^2 - 2W/K) d\\bar{x}^2 + 2c (1 + W/K) d\\bar{x}d\\bar{t} - r^2 (d\\theta^2 + cos^2\\theta d\\phi^2)\\] with $W=(1 - 2m/r + K^2)^{1/2}$, in which the coefficients' pathologies are moved to $r_K = 2m/(1+K^2)$. This new coordinate system is used to study the entrance into a black hole of a rigid line (a line in which the shock waves propagate with velocity c).

  18. Carta de Servicios Red de Bibliotecas

    E-Print Network [OSTI]

    pertenecer a la Red, en la que se realizan los trabajos técnicos precisos para proporcionar a los usuarios el a la información, ya sea de forma presencial o a distancia. servicios Información, orientación y también con salas para fondos especiales, de investigadores o para trabajo en grupo. · Préstamo personal

  19. From Red Tally to Yellow Paper

    E-Print Network [OSTI]

    Uebach, Helga

    2008-01-01T23:59:59.000Z

    by the convocation of many male able-bodied adults for registration (pha-los mang-pho). Year 718/719: The establishment of the Red Tally of the former principality of Dags-po marks its complete inclusion... number of tallies for its files. In concluding it can be said that the fact that paper was officially introduced in Tibet for administrative purposes in the military organisation does not come as a surprise, since her power was built on her military...

  20. International black tea market integration and price discovery

    E-Print Network [OSTI]

    Dharmasena, Kalu Arachchillage Senarath Dhananjaya Bandara

    2004-09-30T23:59:59.000Z

    In this thesis we study three basic issues related to international black tea markets: Are black tea markets integrated? Where is the price of black tea discovered? Are there leaders and followers in black tea markets? We use two statistical...

  1. Black hole mimickers: Regular versus singular behavior

    SciTech Connect (OSTI)

    Lemos, Jose P. S.; Zaslavskii, Oleg B. [Centro Multidisciplinar de Astrofisica, CENTRA, Departamento de Fisica, Instituto Superior Tecnico-IST, Universidade Tecnica de Lisboa-UTL, Avenida Rovisco Pais 1, 1049-001 Lisboa (Portugal); Astronomical Institute of Kharkov, V. N. Karazin National University, 35 Sumskaya Street, Kharkov, 61022 (Ukraine)

    2008-07-15T23:59:59.000Z

    Black hole mimickers are possible alternatives to black holes; they would look observationally almost like black holes but would have no horizon. The properties in the near-horizon region where gravity is strong can be quite different for both types of objects, but at infinity it could be difficult to discern black holes from their mimickers. To disentangle this possible confusion, we examine the near-horizon properties, and their connection with far away asymptotic properties, of some candidates to black mimickers. We study spherically symmetric uncharged or charged but nonextremal objects, as well as spherically symmetric charged extremal objects. Within the uncharged or charged but nonextremal black hole mimickers, we study nonextremal {epsilon}-wormholes on the threshold of the formation of an event horizon, of which a subclass are called black foils, and gravastars. Within the charged extremal black hole mimickers we study extremal {epsilon}-wormholes on the threshold of the formation of an event horizon, quasi-black holes, and wormholes on the basis of quasi-black holes from Bonnor stars. We elucidate whether or not the objects belonging to these two classes remain regular in the near-horizon limit. The requirement of full regularity, i.e., finite curvature and absence of naked behavior, up to an arbitrary neighborhood of the gravitational radius of the object enables one to rule out potential mimickers in most of the cases. A list ranking the best black hole mimickers up to the worst, both nonextremal and extremal, is as follows: wormholes on the basis of extremal black holes or on the basis of quasi-black holes, quasi-black holes, wormholes on the basis of nonextremal black holes (black foils), and gravastars. Since in observational astrophysics it is difficult to find extremal configurations (the best mimickers in the ranking), whereas nonextremal configurations are really bad mimickers, the task of distinguishing black holes from their mimickers seems to be less difficult than one could think of it.

  2. Call for Papers and Panels Unleashing the Black Erotic

    E-Print Network [OSTI]

    Kunkle, Tom

    and the Hypersexuality of Black Women Alternative Modes of Black Love and Family The Politics and Economics of Porn

  3. Heat Engine of black holes

    E-Print Network [OSTI]

    Sadeghi, J

    2015-01-01T23:59:59.000Z

    As we know, the cosmological constant in different theories of gravity acts as a thermodynamics variable. The cosmological constant exists in different actions of gravity and also appears in the solution of such theories. These lead to use the black hole as a heat engines. Also, there are two values for the cosmological constant as positive and negative values. The case of negative cosmological constant supplies a natural realization of these engines in terms of the field theory description of the fluids to which they are holographically dual. In this paper, we are going to define heat engines for two different black holes as Dyonic BH and Kerr BH. And also, we calculate maximum efficiency for two black holes.

  4. Heat Engine of black holes

    E-Print Network [OSTI]

    J. Sadeghi; Kh. Jafarzade

    2015-04-29T23:59:59.000Z

    As we know, the cosmological constant in different theories of gravity acts as a thermodynamics variable. The cosmological constant exists in different actions of gravity and also appears in the solution of such theories. These lead to use the black hole as a heat engines. Also, there are two values for the cosmological constant as positive and negative values. The case of negative cosmological constant supplies a natural realization of these engines in terms of the field theory description of the fluids to which they are holographically dual. In this paper, we are going to define heat engines for two different black holes as Dyonic BH and Kerr BH. And also, we calculate maximum efficiency for two black holes.

  5. Energy on black hole spacetimes

    E-Print Network [OSTI]

    Alejandro Corichi

    2012-07-18T23:59:59.000Z

    We consider the issue of defining energy for test particles on a background black hole spacetime. We revisit the different notions of energy as defined by different observers. The existence of a time-like isometry allows for the notion of a total conserved energy to be well defined, and subsequently the notion of a gravitational potential energy is also meaningful. We then consider the situation in which the test particle is adsorbed by the black hole, and analyze the energetics in detail. In particular, we show that the notion of horizon energy es defined by the isolated horizons formalism provides a satisfactory notion of energy compatible with the particle's conserved energy. As another example, we comment a recent proposal to define energy of the black hole as seen by an observer at rest. This account is intended to be pedagogical and is aimed at the level of and as a complement to the standard textbooks on the subject.

  6. Black Literary Suite: Kansas Authors Edition

    E-Print Network [OSTI]

    Wiggins, Meredith Joan

    2015-03-04T23:59:59.000Z

    authors were born or lived in the Sunflower State, and their work often reflects their time in Kansas. This Black Literary Suite exhibit highlights four important black writersLangston Hughes, Gwendolyn Brooks, Frank Marshall Davis, and Kevin Young...

  7. Introduction to Black Hole Evaporation

    E-Print Network [OSTI]

    Pierre-Henry Lambert

    2014-01-16T23:59:59.000Z

    These lecture notes are an elementary and pedagogical introduction to the black hole evaporation, based on a lecture given by the author at the Ninth Modave Summer School in Mathematical Physics and are intended for PhD students. First, quantum field theory in curved spacetime is studied and tools needed for the remaining of the course are introduced. Then, quantum field theory in Rindler spacetime in 1+1 dimensions and in the spacetime of a spherically collapsing star are considered, leading to Unruh and Hawking effects, respectively. Finally, some consequences such as thermodynamics of black holes and information loss paradox are discussed.

  8. Hawking Emission and Black Hole Thermodynamics

    E-Print Network [OSTI]

    Don N. Page

    2006-12-18T23:59:59.000Z

    A brief review of Hawking radiation and black hole thermodynamics is given, based largely upon hep-th/0409024.

  9. Blue, green, orange, and red upconversion laser

    DOE Patents [OSTI]

    Xie, Ping (San Jose, CA); Gosnell, Timothy R. (Sante Fe, NM)

    1998-01-01T23:59:59.000Z

    A laser for outputting visible light at the wavelengths of blue, green, orange and red light. This is accomplished through the doping of a substrate, such as an optical fiber or waveguide, with Pr.sup.3+ ions and Yb.sup.3+ ions. A light pump such as a diode laser is used to excite these ions into energy states which will produce lasing at the desired wavelengths. Tuning elements such as prisms and gratings can be employed to select desired wavelengths for output.

  10. Blue, green, orange, and red upconversion laser

    DOE Patents [OSTI]

    Xie, P.; Gosnell, T.R.

    1998-09-08T23:59:59.000Z

    A laser is disclosed for outputting visible light at the wavelengths of blue, green, orange and red light. This is accomplished through the doping of a substrate, such as an optical fiber or waveguide, with Pr{sup 3+} ions and Yb{sup 3+} ions. A light pump such as a diode laser is used to excite these ions into energy states which will produce lasing at the desired wavelengths. Tuning elements such as prisms and gratings can be employed to select desired wavelengths for output. 11 figs.

  11. Osmotic water permeability of human red cells

    SciTech Connect (OSTI)

    Terwilliger, T.C.; Solomon, A.K.

    1981-05-01T23:59:59.000Z

    The osmotic water permeability of human red cells has been reexamined with a stopped-flow device and a new perturbation technique. Small osmotic gradients are used to minimize the systematic error caused by nonlinearities in the relationship between cell volume and light scattering. Corrections are then made for residual systematic error. Our results show that the hydraulic conductivity, Lp, is essentially independent of the direction of water flow and of osmolality in the range 184-365 mosM. the mean value of Lp obtained obtained was 1.8 +/- 0.1 (SEM) X 10-11 cm3 dyne -1 s-1.

  12. Red Sun Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form History Facebook iconQuito,JumpReactionEnergy Data JamReconceptRed Sun

  13. RedFlow | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form History Facebook iconQuito,JumpReactionEnergy Data JamReconceptRed

  14. Red Canyon Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ | Roadmap Jump to:bJumpRed Bank, New Jersey: EnergyCanyon

  15. Red Hills Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ | Roadmap Jump to:bJumpRed Bank, New Jersey:

  16. Science On Tap - Red Wine and Mars

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiationImplementingnpitcheResearch BriefsTenney, OfficeScienceEarlyScience On Tap - Red

  17. Signatures of black holes at the LHC

    E-Print Network [OSTI]

    Marco Cavaglia; Romulus Godang; Lucien M. Cremaldi; Donald J. Summers

    2007-07-02T23:59:59.000Z

    Signatures of black hole events at CERN's Large Hadron Collider are discussed. Event simulations are carried out with the Fortran Monte Carlo generator CATFISH. Inelasticity effects, exact field emissivities, color and charge conservation, corrections to semiclassical black hole evaporation, gravitational energy loss at formation and possibility of a black hole remnant are included in the analysis.

  18. Black Shales Adina Paytan, Stanford University, USA

    E-Print Network [OSTI]

    Paytan, Adina

    Tales of Black Shales Adina Paytan, Stanford University, USA Several times during the middle of the Cretaceous period, between 125 and 80 million years ago, organic-carbon-rich black shales were deposited over large areas of the ocean floor. These black shales provide valuable information about past climates

  19. 6, 34193463, 2006 Black carbon or

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    ACPD 6, 34193463, 2006 Black carbon or brown carbon M. O. Andreae and A. Gelencser Title Page Chemistry and Physics Discussions Black carbon or brown carbon? The nature of light-absorbing carbonaceous;ACPD 6, 34193463, 2006 Black carbon or brown carbon M. O. Andreae and A. Gelencser Title Page

  20. Absorption cross section in Lifshitz black hole

    E-Print Network [OSTI]

    Taeyoon Moon; Yun Soo Myung

    2012-10-05T23:59:59.000Z

    We derive the absorption cross section of a minimally coupled scalar in the Lifshitz black hole obtained from the new massive gravity. The absorption cross section reduces to the horizon area in the low energy and massless limit of s-wave mode propagation, indicating that the Lifshitz black hole also satisfies the universality of low energy absorption cross section for black holes.

  1. Red Band Needle Blight Programme Red Band Needle Blight of Pine Programme Group

    E-Print Network [OSTI]

    and that the private 1 | Paper 1 - Minutes | Debbie Erskine | 23/01/2009 #12;Red Band Needle Blight Programme Group Group England Working Group Wales Working Group RBNB Operational GB Working Group (including private Groups would only meet on an ad hoc basis and the structure was agreed. Action: Jim/Roddie to re

  2. RED MOUNTAIN BAR PUMPED STOR AGE PR OJEC T Red Mountain Bar Pumped Storage Project

    E-Print Network [OSTI]

    Laughlin, Robert B.

    a pumped storage project to generate electricity during peak demand. The proposed Red Mountain Bar Pumped from a lower reservoir to an upper reservoir when demand and price for electricity is low. Water the next day. These projects are uniquely suited for generating power when demand for electricity is high

  3. Summer Enrollment Blue=Old Program, Red=New Program

    E-Print Network [OSTI]

    Gering, Jon C.

    Summer Enrollment Blue=Old Program, Red=New Program 1559 14181358 1304 1166 1245 0 200 400 600 800;Summer Sections Offered Blue=Old Program, Red=New Program 142 135 160158 180 200 0 50 100 150 200 250 Generated Blue=Old Program, Red=New Program 5643 5983.5 5463 4953 5985.5 6961 0 1000 2000 3000 4000 5000

  4. Red rice control in rice using herbicides plus safeners

    E-Print Network [OSTI]

    Price, James Bain

    1977-01-01T23:59:59.000Z

    RED RICE CONTROL IN RICE USING HERBICIDES PLUS SAFENERS A Thesis by JAMES BAIN PRICE, IV Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1977 Major... Subject: Agronomy RED RICE CONTROL IN RICE USING HERBICIDES PLUS SAFENERS A Thesis by JAMES BAIN PRICE, IV Approved as to style and content by: (Chairman of Committee Head of Department (Member) (Member) Memb May 1977 ABSTRACT Red Rice...

  5. Einstein, Black Holes Gravitational Waves

    E-Print Network [OSTI]

    Cook, Greg

    1 #12;Einstein, Black Holes and Gravitational Waves Gregory B. Cook Wake Forest University 2 #12;Einstein's Miraculous Year: 1905 Einstein, A. "Uber einen die Erzeugung und Verwandlung des Lichtes Concerning the Production and Transformation of Light. Einstein, A. "Uber die von der molekularkinetischen

  6. From Pinholes to Black Holes

    SciTech Connect (OSTI)

    Fenimore, Edward E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-10-06T23:59:59.000Z

    Pinhole photography has made major contributions to astrophysics through the use of coded apertures. Coded apertures were instrumental in locating gamma-ray bursts and proving that they originate in faraway galaxies, some from the birth of black holes from the first stars that formed just after the big bang.

  7. Integrated Culture of Seaweeds and Red Abalone in Monterey Harbor

    E-Print Network [OSTI]

    Graham, Michael H.

    2008-01-01T23:59:59.000Z

    Project Hypotheses (1) Red algae and kelp can be effectivelydiets are superior to all kelp diets in enhancing farmedlaboratory methods for seeding kelp zoospores onto string

  8. Nationwide: Slashing Red Tape To Speed Solar Deployment for Homes...

    Broader source: Energy.gov (indexed) [DOE]

    Slashing Red Tape To Speed Solar Deployment for Homes and Businesses While solar panels, inverters and other hardware are more affordable than ever before (the average cost of...

  9. aqaba northern red: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for a population of extremely red stellar objects extracted from the point-source catalogue of the INT Photometric H-Alpha Survey (IPHAS) of the northern galactic...

  10. NNSA Releases UPF "Red Team" Report | National Nuclear Security...

    National Nuclear Security Administration (NNSA)

    UPF "Red Team" Report | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the...

  11. amphiuma red blood: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    clay) with human red blood cells Engineering Websites Summary: in the manufacture of oil adsorbants as fertilizer carriers, and as an additive to liquid suspensions; however,...

  12. adjunct red blood: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    clay) with human red blood cells Engineering Websites Summary: in the manufacture of oil adsorbants as fertilizer carriers, and as an additive to liquid suspensions; however,...

  13. autologous red blood: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    clay) with human red blood cells Engineering Websites Summary: in the manufacture of oil adsorbants as fertilizer carriers, and as an additive to liquid suspensions; however,...

  14. Redding Electric- Residential and Commercial Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Redding Electric Utility offers a variety of financial incentives for energy efficiency through its Earth Advantage Rebate Program. Rebates are for weatherization measures, HVAC equipment, and...

  15. american red squirrels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    274 www.redsquirrelsofthehighlands.co.uk RED SQUIRRRELS OF THE HIGHLANDS End of Project Renewable Energy Websites Summary: by internal FCS process Training for health...

  16. aqaba red sea: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is uncertain due to global warming and repeated bleaching a century. Keywords: climate change, coral bleaching, coral reefs, Gulf of Aqaba, Red Sea Received 9 January. The latter,...

  17. Black Hole Radiation and Volume Statistical Entropy

    E-Print Network [OSTI]

    Mario Rabinowitz

    2005-06-29T23:59:59.000Z

    The simplest possible equation for Hawking radiation, and other black hole radiated power is derived in terms of black hole density. Black hole density also leads to the simplest possible model of a gas of elementary constituents confined inside a gravitational bottle of Schwarzchild radius at tremendous pressure, which yields identically the same functional dependence as the traditional black hole entropy. Variations of Sbh can be obtained which depend on the occupancy of phase space cells. A relation is derived between the constituent momenta and the black hole radius which is similar to the Compton wavelength relation.

  18. Black Hole Evaporation as a Nonequilibrium Process

    E-Print Network [OSTI]

    Hiromi Saida

    2008-11-11T23:59:59.000Z

    When a black hole evaporates, there arises a net energy flow from the black hole into its outside environment due to the Hawking radiation and the energy accretion onto black hole. Exactly speaking, due to the net energy flow, the black hole evaporation is a nonequilibrium process. To study details of evaporation process, nonequilibrium effects of the net energy flow should be taken into account. In this article we simplify the situation so that the Hawking radiation consists of non-self-interacting massless matter fields and also the energy accretion onto the black hole consists of the same fields. Then we find that the nonequilibrium nature of black hole evaporation is described by a nonequilibrium state of that field, and we formulate nonequilibrium thermodynamics of non-self-interacting massless fields. By applying it to black hole evaporation, followings are shown: (1) Nonequilibrium effects of the energy flow tends to accelerate the black hole evaporation, and, consequently, a specific nonequilibrium phenomenon of semi-classical black hole evaporation is suggested. Furthermore a suggestion about the end state of quantum size black hole evaporation is proposed in the context of information loss paradox. (2) Negative heat capacity of black hole is the physical essence of the generalized second law of black hole thermodynamics, and self-entropy production inside the matter around black hole is not necessary to ensure the generalized second law. Furthermore a lower bound for total entropy at the end of black hole evaporation is given. A relation of the lower bound with the so-called covariant entropy bound conjecture is interesting but left as an open issue.

  19. BSW process of the slowly evaporating charged black hole

    E-Print Network [OSTI]

    Liancheng Wang; Feng He; Xiangyun Fu

    2015-02-09T23:59:59.000Z

    In this paper, we study the BSW process of the slowly evaporating charged black hole. It can be found that the BSW process will also arise near black hole horizon when the evaporation of charged black hole is very slow. But now the background black hole does not have to be an extremal black hole, and it will be approximately an extremal black hole unless it is nearly a huge stationary black hole.

  20. Red Shift in a Laboraory Environment

    E-Print Network [OSTI]

    Yuriy A. Yatsunenko; Julian A. Budagov

    2011-03-04T23:59:59.000Z

    A hypotheses of energy loss for polarization of e-e+ vacuum by a photon passing interstellar space is considered. An excitation and relaxation of vacuum can't run with speed of light due to very small but finite fraction of e-e+ pair mass that creates a retardment in recuperation of deposited energy back to photon. This "forgotten" by many photons energy is finally splashed out in real space as a Relic Radiation. An assumption that such energy loss is proportional to a photon energy conforms to Hubble low of Red Shift and experimental data treated as accelerated expansion of Universe. A possibility of an observation of this type energy loss is considered at high-energy accelerators where energy deposition may reach up hundreds MeV in second.

  1. Reversibility of Red blood Cell deformation

    E-Print Network [OSTI]

    Maria Zeitz; Pierre Sens

    2011-11-22T23:59:59.000Z

    The ability of cells to undergo reversible shape changes is often crucial to their survival. For Red Blood Cells (RBCs), irreversible alteration of the cell shape and flexibility often causes anemia. Here we show theoretically that RBCs may react irreversibly to mechanical perturbations because of tensile stress in their cytoskeleton. The transient polymerization of protein fibers inside the cell seen in sickle cell anemia or a transient external force can trigger the formation of a cytoskeleton-free membrane protrusion of micrometer dimensions. The complex relaxation kinetics of the cell shape is shown to be responsible for selecting the final state once the perturbation is removed, thereby controlling the reversibility of the deformation. In some case, tubular protrusion are expected to relax via a peculiar "pearling instability".

  2. ACARYOCHLORIS EXPLAINING THE RIDDLE OF CHLOROPHYLL D IN RED ALGAE AND EXPANDING PAR FOR OXYGENIC PHOTOSYNTHESIS

    E-Print Network [OSTI]

    Oregon, University of

    ACARYOCHLORIS ­ EXPLAINING THE RIDDLE OF CHLOROPHYLL D IN RED ALGAE AND EXPANDING PAR FOR OXYGENIC strain is shown to live epi- phytically on the red alga Gelidium caulacantheum, which itself is harvested by the red alga. Availability of far red light, however, is relatively unaffected by DOM or red

  3. Ris-R-1513(EN) The "Red" Decline of Norway

    E-Print Network [OSTI]

    Risø-R-1513(EN) The "Red" Decline of Norway Spruce or "Røde Rødgraner" ­ Is it Ammonium Overload. Engvild Title: The "Red" Decline of Norway Spruce or "Røde Rødgraner" ­ Is it Ammonium Overload or Top" decline of Norway spruce (Picea abies) became a serious problem in plantations in Jutland on poor, sandy

  4. Natural England Commissioned Report NECR019 Review of red squirrel

    E-Print Network [OSTI]

    and offers expert and timely advice for future work programmes. Control of grey squirrels is identified and effective. Improve the way in which grey squirrel control, central to any red squirrel conservation project Laboratory, Sand Hutton, York YO41 1LZ (Consortium leader) Keywords - Red squirrel, grey squirrel, wildlife

  5. INHIBITION OF PHOTOSYNTHESIS IN CERTAIN ALGAE BY EXTREME RED LIGHT

    E-Print Network [OSTI]

    Govindjee

    INHIBITION OF PHOTOSYNTHESIS IN CERTAIN ALGAE BY EXTREME RED LIGHT GOVINDJEE, EUGENE RABINOWITCH. INTRODUCTION It was shown in preceding papers (9, 10) that when the unicellular red alga Por- phyridium), these algae, when exposed to monochromatic light (bands isolated by a grating monochromator, band half

  6. Charged spinning black holes as particle accelerators

    SciTech Connect (OSTI)

    Wei Shaowen; Liu Yuxiao; Guo Heng; Fu Chune [Institute of Theoretical Physics, Lanzhou University, Lanzhou 730000 (China)

    2010-11-15T23:59:59.000Z

    It has recently been pointed out that the spinning Kerr black hole with maximal spin could act as a particle collider with arbitrarily high center-of-mass energy. In this paper, we will extend the result to the charged spinning black hole, the Kerr-Newman black hole. The center-of-mass energy of collision for two uncharged particles falling freely from rest at infinity depends not only on the spin a but also on the charge Q of the black hole. We find that an unlimited center-of-mass energy can be approached with the conditions: (1) the collision takes place at the horizon of an extremal black hole; (2) one of the colliding particles has critical angular momentum; (3) the spin a of the extremal black hole satisfies (1/{radical}(3)){<=}(a/M){<=}1, where M is the mass of the Kerr-Newman black hole. The third condition implies that to obtain an arbitrarily high energy, the extremal Kerr-Newman black hole must have a large value of spin, which is a significant difference between the Kerr and Kerr-Newman black holes. Furthermore, we also show that, for a near-extremal black hole, there always exists a finite upper bound for center-of-mass energy, which decreases with the increase of the charge Q.

  7. Unusual expression of red fluorescence at M phase induced by anti-microtubule agents in HeLa cells expressing the fluorescent ubiquitination-based cell cycle indicator (Fucci)

    SciTech Connect (OSTI)

    Honda-Uezono, Asumi [Section of Oral Radiation Oncology, Department of Oral Health Sciences, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan) [Section of Oral Radiation Oncology, Department of Oral Health Sciences, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan); Section of Maxillofacial Surgery, Department of Maxillofacial and Neck Reconstruction, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan); Kaida, Atsushi [Section of Oral Radiation Oncology, Department of Oral Health Sciences, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan)] [Section of Oral Radiation Oncology, Department of Oral Health Sciences, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan); Michi, Yasuyuki; Harada, Kiyoshi [Section of Maxillofacial Surgery, Department of Maxillofacial and Neck Reconstruction, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan)] [Section of Maxillofacial Surgery, Department of Maxillofacial and Neck Reconstruction, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan); Hayashi, Yoshiki; Hayashi, Yoshio [Department of Medicinal Chemistry, Tokyo University of Pharmacy and Life Sciences, Hachioji, Tokyo 192-0392 (Japan)] [Department of Medicinal Chemistry, Tokyo University of Pharmacy and Life Sciences, Hachioji, Tokyo 192-0392 (Japan); Miura, Masahiko, E-mail: masa.mdth@tmd.ac.jp [Section of Oral Radiation Oncology, Department of Oral Health Sciences, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan)] [Section of Oral Radiation Oncology, Department of Oral Health Sciences, Graduate School of Medical and Dental Sciences, Tokyo Medical and Dental University, 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8549 (Japan)

    2012-11-16T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Fucci visualizes cell cycle by green and red fluorescence. Black-Right-Pointing-Pointer Plinabulin, induced unusual red fluorescence at M-phase in HeLa-Fucci cells. Black-Right-Pointing-Pointer The unusual pattern was followed by mitotic catastrophe. Black-Right-Pointing-Pointer The unusual pattern may be an early indicator of cell death in HeLa cells. -- Abstract: Plinabulin (NPI-2358) is a novel microtubule-depolymerizing agent. In HeLa cells, plinabulin arrests the cell-cycle at M phase and subsequently induces mitotic catastrophe. To better understand the effects on this compound on the cell-cycle, we used the fluorescent ubiquitination-based cell cycle indicator (Fucci), which normally enables G1 and S/G2/M cells to emit red and green fluorescence, respectively. When HeLa-Fucci cells were treated with 50 nM plinabulin, cells began to fluoresce both green and red in an unusual pattern; most cells exhibited the new pattern after 24 h of treatment. X-irradiation efficiently induced G2 arrest in plinabulin-treated cells and significantly retarded the emergence of the unusual pattern, suggesting that entering M phase is essential for induction of the pattern. By simultaneously visualizing chromosomes with GFP-histone H2B, we established that the pattern emerges after nuclear envelope breakdown but before metaphase. Pedigree assay revealed a significant relationship between the unusual expression and mitotic catastrophe. Nocodazole, KPU-133 (a more potent derivative of plinabulin), and paclitaxel also exerted similar effects. From these data, we conclude that the unusual pattern may be associated with dysregulation of late M phase-specific E3 ligase activity and mitotic catastrophe following treatment with anti-microtubule agents.

  8. Quantum Geometry and Black Holes

    E-Print Network [OSTI]

    G., J Fernando Barbero

    2015-01-01T23:59:59.000Z

    We present an overall picture of the advances in the description of black hole physics from the perspective of loop quantum gravity. After an introduction that discusses the main conceptual issues we present some details about the classical and quantum geometry of isolated horizons and their quantum geometry and then use this scheme to give a natural definition of the entropy of black holes. The entropy computations can be neatly expressed in the form of combinatorial problems solvable with the help of methods based on number theory and the use of generating functions. The recovery of the Bekenstein-Hawking law and corrections to it is explained in some detail. After this, due attention is paid to the discussion of semiclassical issues. An important point in this respect is the proper interpretation of the horizon area as the energy that should appear in the statistical-mechanical treatment of the black hole model presented here. The chapter ends with a comparison between the microscopic and semiclassical app...

  9. FCS Guidance Note 33: Forest operations and red squirrels: November 2006 Forest operations and red squirrels in Scottish forests

    E-Print Network [OSTI]

    impacts on red squirrels. The survey, forest design and operational planning practices set outFCS Guidance Note 33: Forest operations and red squirrels: November 2006 1 Forest operations Guidance Note: Forest operations and wildlife in Scottish forests. This note sets out further advice on how

  10. RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical...

    Broader source: Energy.gov (indexed) [DOE]

    RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical Challenges. RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical Challenges. RedSeal Comments...

  11. Black holes are almost optimal quantum cloners

    E-Print Network [OSTI]

    C. Adami; G. Ver Steeg

    2015-04-15T23:59:59.000Z

    If black holes were able to clone quantum states, a number of paradoxes in black hole physics would disappear. However, the linearity of quantum mechanics forbids exact cloning of quantum states. Here we show that black holes indeed clone incoming quantum states with a fidelity that depends on the black hole's absorption coefficient, without violating the no-cloning theorem because the clones are only approximate. Perfectly reflecting black holes are optimal universal "quantum cloning machines" and operate on the principle of stimulated emission, exactly as their quantum optical counterparts. In the limit of perfect absorption, the fidelity of clones is equal to what can be obtained via quantum state estimation methods. But for any absorption probability less than one, the cloning fidelity is nearly optimal as long as $\\omega/T\\geq10$, a common parameter for modest-sized black holes.

  12. Remarks on Renormalization of Black Hole Entropy

    E-Print Network [OSTI]

    Sang Pyo Kim; Sung Ku Kim; Kwang-Sup Soh; Jae Hyung Yee

    1996-07-07T23:59:59.000Z

    We elaborate the renormalization process of entropy of a nonextremal and an extremal Reissner-Nordstr\\"{o}m black hole by using the Pauli-Villars regularization method, in which the regulator fields obey either the Bose-Einstein or Fermi-Dirac distribution depending on their spin-statistics. The black hole entropy involves only two renormalization constants. We also discuss the entropy and temperature of the extremal black hole.

  13. Probing the Constituent Structure of Black Holes

    E-Print Network [OSTI]

    Lukas Gruending; Stefan Hofmann; Sophia Mller; Tehseen Rug

    2014-12-12T23:59:59.000Z

    We calculate the cross section for scattering processes between graviton emitters on the near side of a Schwarzschild surface and absorbers on its far side, that is black hole constituents. We show that these scatterings allow to directly extract structural observables such as the momentum distribution of black hole constituents. For this we employ a quantum bound state description originally developed in quantum chromodynamics and recently applied to general relativity that allows to consider black holes in a relativistic Hartree like framework.

  14. Black hole initial data without elliptic equations

    E-Print Network [OSTI]

    Istvn Rcz; Jeffrey Winicour

    2015-02-24T23:59:59.000Z

    We explore whether a new method to solve the constraints of Einstein's equations, which does not involve elliptic equations, can be applied to provide initial data for black holes. We show that this method can be successfully applied to a nonlinear perturbation of a Schwarzschild black hole by establishing the well-posedness of the resulting constraint problem. We discuss its possible generalization to the boosted, spinning multiple black hole problem.

  15. Absorption cross section of RN black hole

    E-Print Network [OSTI]

    Sini R.; V. C. Kuriakose

    2007-08-23T23:59:59.000Z

    The behavior of a charged scalar field in the RN black hole space time is studied using WKB approximation. In the present work it is assumed that matter waves can get reflected from the event horizon. Using this effect, the Hawking temperature and the absorption cross section for RN black hole placed in a charged scalar field are calculated. The absorption cross section $\\sigma _{abs}$ is found to be inversely proportional to square of the Hawking temperature of the black hole.

  16. Black holes with massive graviton hair

    E-Print Network [OSTI]

    Richard Brito; Vitor Cardoso; Paolo Pani

    2013-09-03T23:59:59.000Z

    No-hair theorems exclude the existence of nontrivial scalar and massive vector hair outside four-dimensional, static, asymptotically flat black-hole spacetimes. We show, by explicitly building nonlinear solutions, that black holes can support massive graviton hair in theories of massive gravity. These hairy solutions are, most likely, the generic end state of the recently discovered monopole instability of Schwarzschild black holes in massive graviton theories.

  17. International House Collection / William Black (collector)

    E-Print Network [OSTI]

    Handy, Todd C.

    International House Collection / William Black (collector) Revised by Erwin Wodarczak (2010 (collector). 1950-1953. 45 p. of textual records. Biographical Sketch Born in London, England, William

  18. Thermoelectric DC conductivities from black hole horizons

    E-Print Network [OSTI]

    Aristomenis Donos; Jerome P. Gauntlett

    2014-10-14T23:59:59.000Z

    An analytic expression for the DC electrical conductivity in terms of black hole horizon data was recently obtained for a class of holographic black holes exhibiting momentum dissipation. We generalise this result to obtain analogous expressions for the DC thermoelectric and thermal conductivities. We illustrate our results using some holographic Q-lattice black holes as well as for some black holes with linear massless axions, in both $D=4$ and $D=5$ bulk spacetime dimensions, which include both spatially isotropic and anisotropic examples. We show that some recently constructed ground states of holographic Q-lattices, which can be either electrically insulating or metallic, are all thermal insulators.

  19. Black Hills Power- Commercial Energy Efficiency Programs

    Broader source: Energy.gov [DOE]

    Black Hills Power provides rebates for its commercial customers who install energy efficient heat pumps, motors, variable frequency drives, lighting, and water heaters. Custom rebates for approved...

  20. Black Holes: from Speculations to Observations

    E-Print Network [OSTI]

    Thomas W. Baumgarte

    2006-04-13T23:59:59.000Z

    This paper provides a brief review of the history of our understanding and knowledge of black holes. Starting with early speculations on ``dark stars'' I discuss the Schwarzschild "black hole" solution to Einstein's field equations and the development of its interpretation from "physically meaningless" to describing the perhaps most exotic and yet "most perfect" macroscopic object in the universe. I describe different astrophysical black hole populations and discuss some of their observational evidence. Finally I close by speculating about future observations of black holes with the new generation of gravitational wave detectors.

  1. Black Hills Power- Residential Customer Rebate Program

    Broader source: Energy.gov [DOE]

    Black Hills Power offers cash rebates to residential customers who purchase and install energy efficient equipment in their homes. Incentives exist for water heaters, demand control units, air...

  2. Strings, black holes, and quantum information

    SciTech Connect (OSTI)

    Kallosh, Renata; Linde, Andrei [Department of Physics, Stanford University, Stanford, California 94305 (United States)

    2006-05-15T23:59:59.000Z

    We find multiple relations between extremal black holes in string theory and 2- and 3-qubit systems in quantum information theory. We show that the entropy of the axion-dilaton extremal black hole is related to the concurrence of a 2-qubit state, whereas the entropy of the STU black holes, Bogomol'nyi-Prasad-Sommerfield (BPS) as well as non-BPS, is related to the 3-tangle of a 3-qubit state. We relate the 3-qubit states with the string theory states with some number of D-branes. We identify a set of large black holes with the maximally entangled Greenberger, Horne, Zeilinger (GHZ) class of states and small black holes with separable, bipartite, and W states. We sort out the relation between 3-qubit states, twistors, octonions, and black holes. We give a simple expression for the entropy and the area of stretched horizon of small black holes in terms of a norm and 2-tangles of a 3-qubit system. Finally, we show that the most general expression for the black hole and black ring entropy in N=8 supergravity/M theory, which is given by the famous quartic Cartan E{sub 7(7)} invariant, can be reduced to Cayley's hyperdeterminant describing the 3-tangle of a 3-qubit state.

  3. Lower Dimensional Black Holes: Inside and Out

    E-Print Network [OSTI]

    R. B. Mann

    1995-01-27T23:59:59.000Z

    I survey the physics of black holes in two and three spacetime dimensions, with special attention given to an understanding of their exterior and interior properties.

  4. Superconducting Hair on Charged Black String Background

    E-Print Network [OSTI]

    Lukasz Nakonieczny; Marek Rogatko

    2012-01-25T23:59:59.000Z

    Behaviour of Dirac fermions in the background of a charged black string penetrated by an Abelian Higgs vortex is elaborated. One finds the evidence that the system under consideration can support fermion fields acting like a superconducting cosmic string in the sence that a nontrivial Dirac fermion field can be carried by the system in question. The case of nonextremal and extremal black string vortex systems were considered. The influence of electric and Higgs charge, the winding number and the fermion mass on the fermion localization near the black string event horizon was studied. It turned out that the extreme charged black string expelled fermion fields more violently comparing to the nonextremal one.

  5. Approximate initial data for binary black holes

    E-Print Network [OSTI]

    Kenneth A. Dennison; Thomas W. Baumgarte; Harald P. Pfeiffer

    2006-08-26T23:59:59.000Z

    We construct approximate analytical solutions to the constraint equations of general relativity for binary black holes of arbitrary mass ratio in quasicircular orbit. We adopt the puncture method to solve the constraint equations in the transverse-traceless decomposition and consider perturbations of Schwarzschild black holes caused by boosts and the presence of a binary companion. A superposition of these two perturbations then yields approximate, but fully analytic binary black hole initial data that are accurate to first order in the inverse of the binary separation and the square of the black holes' momenta.

  6. A new spin on black hole hair

    E-Print Network [OSTI]

    Herdeiro, Carlos A R

    2014-01-01T23:59:59.000Z

    We show that scalar hair can be added to rotating, vacuum black holes of general relativity. These hairy black holes (HBHs) clarify a lingering question concerning gravitational solitons: if a black hole can be added at the centre of a boson star, as it typically can for other solitons. We argue that it can, but only if it is spinning. The existence of such HBHs is related to the Kerr superradiant instability triggered by a massive scalar field. This connection leads to the following conjecture: a (hairless) black hole which is afflicted by the superradiant instability of a given field must allow hairy generalizations with that field.

  7. National Society of Black EngineersNational Society of Black Engineers Columbia University Chapter

    E-Print Network [OSTI]

    Hone, James

    National Society of Black EngineersNational Society of Black Engineers Columbia University Chapter #12;Columbia University Greetings NSBE Family and Friends! My name is Ken Yearwood, the 2008-2009 Columbia University NSBE (National Society of Black Engineers) Chapter President. On behalf of the Columbia

  8. U-159: Red Hat Enterprise MRG Messaging Qpid Bug Lets Certain...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9: Red Hat Enterprise MRG Messaging Qpid Bug Lets Certain Remote Users Bypass Authentication U-159: Red Hat Enterprise MRG Messaging Qpid Bug Lets Certain Remote Users Bypass...

  9. OBSERVATIONAL CONSTRAINTS ON RED AND BLUE HELIUM BURNING SEQUENCES

    SciTech Connect (OSTI)

    McQuinn, Kristen B. W.; Skillman, Evan D. [Department of Astronomy, School of Physics and Astronomy, 116 Church Street, S.E., University of Minnesota, Minneapolis, MN 55455 (United States); Dalcanton, Julianne J.; Weisz, Daniel R.; Williams, Benjamin F. [Department of Astronomy, Box 351580, University of Washington, Seattle, WA 98195 (United States); Dolphin, Andrew E. [Raytheon Company, 1151 E. Hermans Road, Tucson, AZ 85706 (United States); Holtzman, Jon, E-mail: kmcquinn@astro.umn.edu [Department of Astronomy, New Mexico State University, Box 30001-Department 4500, 1320 Frenger Street, Las Cruces, NM 88003 (United States)

    2011-10-10T23:59:59.000Z

    We derive the optical luminosity, colors, and ratios of the blue and red helium burning (HeB) stellar populations from archival Hubble Space Telescope observations of nineteen starburst dwarf galaxies and compare them with theoretical isochrones from Padova stellar evolution models across metallicities from Z = 0.001 to 0.009. We find that the observational data and the theoretical isochrones for both blue and red HeB populations overlap in optical luminosities and colors and the observed and predicted blue to red HeB ratios agree for stars older than 50 Myr over the time bins studied. These findings confirm the usefulness of applying isochrones to interpret observations of HeB populations. However, there are significant differences, especially for the red HeB population. Specifically, we find (1) offsets in color between the observations and theoretical isochrones of order 0.15 mag (0.5 mag) for the blue (red) HeB populations brighter than M{sub V} {approx} -4 mag, which cannot be solely due to differential extinction; (2) blue HeB stars fainter than M{sub V} {approx} -3 mag are bluer than predicted; (3) the slope of the red HeB sequence is shallower than predicted by a factor of {approx}3; and (4) the models overpredict the ratio of the most luminous blue to red HeB stars corresponding to ages {approx}< 50 Myr. Additionally, we find that for the more metal-rich galaxies in our sample (Z {approx}> 0.5 Z{sub sun}), the red HeB stars overlap with the red giant branch stars in the color-magnitude diagrams, thus reducing their usefulness as indicators of star formation for ages {approx}> 100 Myr.

  10. Rotating embedded black holes: Entropy and Hawking's radiation

    E-Print Network [OSTI]

    Ng Ibohal

    2004-12-27T23:59:59.000Z

    In this paper we derive a class of rotating embedded black holes. Then we study Hawking's radiation effects on these embedded black holes. The surface gravity, entropy and angular velocity are given for each of these black holes.

  11. Stability of Biomass-derived Black Carbon in Soils . | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stability of Biomass-derived Black Carbon in Soils . Stability of Biomass-derived Black Carbon in Soils . Abstract: Black carbon (BC) may play an important role in the global C...

  12. Black Holes at the LHC: Progress since 2002

    SciTech Connect (OSTI)

    Park, Seong Chan [FRDP, Department of Physics and Astronomy, Seoul National University, Seoul (Korea, Republic of)

    2008-11-23T23:59:59.000Z

    We review the recent noticeable progresses in black hole physics focusing on the up-coming super-collider, the LHC. We discuss the classical formation of black holes by particle collision, the greybody factors for higher dimensional rotating black holes, the deep implications of black hole physics to the 'energy-distance' relation, the security issues of the LHC associated with black hole formation and the newly developed Monte-Carlo generators for black hole events.

  13. Austin E. Quigley Black Box Theater Proposal Form

    E-Print Network [OSTI]

    Hone, James

    -1- Austin E. Quigley Black Box Theater Proposal Form Sponsoring Organization indicate that you have read the Austin E. Quigley Black Box Theatre Policy and Procedure Guidelines

  14. Savannah River National Laboratory Meets with Historically Black...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Savannah River National Laboratory Meets with Historically Black Colleges and Universities Savannah River National Laboratory Meets with Historically Black Colleges and...

  15. Deformability of Plasmodium falciparum parasitized red blood cells

    E-Print Network [OSTI]

    Mills, John Philip, Ph. D. Massachusetts Institute of Technology

    2007-01-01T23:59:59.000Z

    The biophysical properties of the human red blood cell (RBC) permit large deformations required for passage through narrow capillaries and spleen sinusoids. Several pathologic conditions alter RBC deformability that can ...

  16. Infra-Red Process for Colour Fixation on Fabrics

    E-Print Network [OSTI]

    Biau, D.; Raymond, D. J.

    1983-01-01T23:59:59.000Z

    Infra-red radiations find wide application in industrial processes as heating, drying, stoving and forming. The results are often far better than those from the other techniques: convection oven, gas IR etc . They come from the electric IR specific...

  17. Red Ink : open source financial analytics for people & communities

    E-Print Network [OSTI]

    O'Toole, Ryan (Ryan Michael)

    2010-01-01T23:59:59.000Z

    Red Ink is an open source social-financial web-service that enables people to share, aggregate, analyze, visualize and publish their financial transactions as individuals and ad-hoc groups, through data sharing campaigns. ...

  18. Buoyancy-driven circulation in the Red Sea

    E-Print Network [OSTI]

    Zhai, Ping, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    This thesis explores the buoyancy-driven circulation in the Red Sea, using a combination of observations, as well as numerical modeling and analytical method. The first part of the thesis investigates the formation mechanism ...

  19. area red sea: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to compiling a Red Data Book of Threatened Biotopes of the Baltic Sea Area. The assessment has been made by numerous experts on marine and coastal ecology and taxonomy from...

  20. CAPTURING TAGGED RED SALMON WITH PULSED DIRECT CURRENT

    E-Print Network [OSTI]

    the electrodes were forced to move towards the positive electrode, placed in slack water 3 feet deep close pressing problems now facing biologists working on research and man- agement of our salmon resources. Red

  1. Red River Valley REA- Heat Pump Loan Program

    Broader source: Energy.gov [DOE]

    The Red River Valley Rural Electric Association (RRVREA) offers a loan program to its members for air-source and geothermal heat pumps. Loans are available for geothermal heat pumps at a 5% fixed...

  2. Infra-Red Process for Colour Fixation on Fabrics

    E-Print Network [OSTI]

    Biau, D.; Raymond, D. J.

    1983-01-01T23:59:59.000Z

    Infra-red radiations find wide application in industrial processes as heating, drying, stoving and forming. The results are often far better than those from the other techniques: convection oven, gas IR etc . They come from the electric IR specific...

  3. Microfluidic devices for analysis of red blood cell mechanical properties

    E-Print Network [OSTI]

    Bow, Hansen Chang

    2010-01-01T23:59:59.000Z

    Decreased deformability of human red blood cells (RBCs) is both a cause of disease and biomarker for disease (1). To traverse blood capillaries, the biconcave disk-shaped RBC must deform dramatically, since the diameter ...

  4. Lipid bilayer and cytoskeletal interactions in a red blood cell

    E-Print Network [OSTI]

    Peng, Zhangli

    We study the biomechanical interactions between the lipid bilayer and the cytoskeleton in a red blood cell (RBC) by developing a general framework for mesoscopic simulations. We treated the lipid bilayer and the cytoskeleton ...

  5. Anisotropic light scattering of individual sickle red blood cells

    E-Print Network [OSTI]

    Kim, Youngchan

    We present the anisotropic light scattering of individual red blood cells (RBCs) from a patient with sickle cell disease (SCD). To measure light scattering spectra along two independent axes of elongated-shaped sickle RBCs ...

  6. Imazethapyr: red rice control and resistance, and environmental fate

    E-Print Network [OSTI]

    Avila, Luis Antonio de

    2005-11-01T23:59:59.000Z

    Imazethapyr was recently approved for use in rice, but limited information is available regarding its efficacy, environmental fate or potential red rice resistance. Therefore, experiments were conducted to 1) determine the effect of flooding time...

  7. SEISMIC DIAGNOSTICS OF RED GIANTS: FIRST COMPARISON WITH STELLAR MODELS

    SciTech Connect (OSTI)

    Montalban, J.; Miglio, A.; Noels, A.; Scuflaire, R. [Institut d'Astrophysique et Geophysique de l'Universite de Liege, Allee du six Aout, 17 B-4000 Liege (Belgium); Ventura, P. [Osservatorio Astronomico di Roma-INAF, via Frascati 33, Monteporzio Catone, Rome (Italy)

    2010-10-01T23:59:59.000Z

    The clear detection with CoRoT and KEPLER of radial and non-radial solar-like oscillations in many red giants paves the way for seismic inferences on the structure of such stars. We present an overview of the properties of the adiabatic frequencies and frequency separations of radial and non-radial oscillation modes for an extended grid of models. We highlight how their detection allows a deeper insight into the internal structure and evolutionary state of red giants. In particular, we find that the properties of dipole modes constitute a promising seismic diagnostic tool of the evolutionary state of red giant stars. We compare our theoretical predictions with the first 34 days of KEPLER data and predict the frequency diagram expected for red giants in the CoRoT exofield in the galactic center direction.

  8. Interpreting the Clustering of Distant Red Galaxies

    SciTech Connect (OSTI)

    Tinker, Jeremy L.; /BCCP, Berkeley; Wechsler, Risa H.; /KIPAC, Menlo Park /SLAC; Zheng, Zheng; /Princeton, Inst. Advanced Study

    2009-08-03T23:59:59.000Z

    We analyze the angular clustering of z {approx} 2.3 distant red galaxies (DRGs) measured by Quadri et al. (2008). We find that, with robust estimates of the measurement errors and realistic halo occupation distribution modeling, the measured clustering can be well fit within standard halo occupation models, in contrast to previous results. However, in order to fit the strong break in w({theta}) at {theta} = 10{double_prime}, nearly all satellite galaxies in the DRG luminosity range are required to be DRGs. Within this luminosity-threshold sample, the fraction of galaxies that are DRGs is {approx} 44%, implying that the formation of DRGs is more efficient for satellite galaxies than for central galaxies. Despite the evolved stellar populations contained within DRGs at z = 2.3, 90% of satellite galaxies in the DRG luminosity range have been accreted within 500 Myr. Thus, satellite DRGs must have known they would become satellites well before the time of their accretion. This implies that the formation of DRGs correlates with large-scale environment at fixed halo mass, although the large-scale bias of DRGs can be well fit without such assumptions. Further data are required to resolve this issue. Using the observational estimate that {approx} 30% of DRGs have no ongoing star formation, we infer a timescale for star formation quenching for satellite galaxies of 450 Myr, although the uncertainty on this number is large. However, unless all non-star forming satellite DRGs were quenched before accretion, the quenching timescale is significantly shorter than z {approx} 0 estimates. Down to the completeness limit of the Quadri et al sample, we find that the halo masses of central DRGs are {approx} 50% higher than non-DRGs in the same luminosity range, but at the highest halo masses the central galaxies are DRGs only {approx} 2/3 of the time.

  9. Can Superconducting Cosmic Strings Piercing Seed Black Holes Generate Supermassive Black Holes in the Early Universe?

    E-Print Network [OSTI]

    Lake, Matthew J

    2015-01-01T23:59:59.000Z

    The discovery of a large number of supermassive black holes at redshifts $z> 6$, when the Universe was only nine hundred million years old, has raised the fundamental question of how such massive compact objects could form in a (cosmologically) short time interval. Each of the proposed standard scenarios for black hole formation, involving rapid accretion of seed black holes, or black hole mergers, faces severe theoretical difficulties in explaining the short time formation of supermassive objects. In the present Letter, we propose an alternative scenario for the formation of supermassive black holes in the early Universe in which energy transfer from superconducting cosmic strings, piercing small seed black holes, is the main physical process leading to rapid mass increase. The increase in mass of a primordial seed black hole pierced by two antipodal strings is estimated and it is shown that this increases linearly in time. Due to the high energy transfer rate from the cosmic strings, we find that supermassi...

  10. Topological Black Holes in Quantum Gravity

    E-Print Network [OSTI]

    J. Kowalski-Glikman; D. Nowak-Szczepaniak

    2000-07-31T23:59:59.000Z

    We derive the black hole solutions with horizons of non-trivial topology and investigate their properties in the framework of an approach to quantum gravity being an extension of Bohm's formulation of quantum mechanics. The solutions we found tend asymptotically (for large $r$) to topological black holes. We also analyze the thermodynamics of these space-times.

  11. Cooking with Black-Eyed Peas

    E-Print Network [OSTI]

    Anding, Jenna

    2008-12-09T23:59:59.000Z

    the most protein from the peas, serve them with grain foods such as corn, rice or wheat. A serving size is ? cup. Uses Use black-eyed peas as a tasty side dish or include it in casseroles, soups, and salads. Black-eyed peas are often packaged in 1- or 2...

  12. Primordial black holes and asteroid danger

    E-Print Network [OSTI]

    Alexander Shatskiy

    2008-02-21T23:59:59.000Z

    Probability for a primordial black hole to invade the Kuiper belt was calculated. We showed that primordial black holes of certain masses can significantly change asteroids' orbits. These events may result in disasters, local for our solar system and global for the Earth (like the Tunguska meteorite). We also estimated how often such events occur.

  13. The Kansas Black Bass Tournament Monitoring Program

    E-Print Network [OSTI]

    The Kansas Black Bass (Micropterus spp.) Tournament Monitoring Program was begun by the Kansas Fish and Game program of the Kansas Fish and Game Commission avoids both of these prob- lems. The Kansas Black Bass annually to each of the bass clubs in Kansas before the bulk of fishing begins, and clubs are asked

  14. Dynamics of Primordial Black Hole Formation

    E-Print Network [OSTI]

    J. C. Niemeyer; K. Jedamzik

    1999-01-21T23:59:59.000Z

    We present a numerical investigation of the gravitational collapse of horizon-size density fluctuations to primordial black holes (PBHs) during the radiation-dominated phase of the Early Universe. The collapse dynamics of three different families of initial perturbation shapes, imposed at the time of horizon crossing, is computed. The perturbation threshold for black hole formation, needed for estimations of the cosmological PBH mass function, is found to be $\\delta_{\\rm c} \\approx 0.7$ rather than the generally employed $\\delta_{\\rm c} \\approx 1/3$, if $\\delta$ is defined as $\\Delta M/\\mh$, the relative excess mass within the initial horizon volume. In order to study the accretion onto the newly formed black holes, we use a numerical scheme that allows us to follow the evolution for long times after formation of the event horizon. In general, small black holes (compared to the horizon mass at the onset of the collapse) give rise to a fluid bounce that effectively shuts off accretion onto the black hole, while large ones do not. In both cases, the growth of the black hole mass owing to accretion is insignificant. Furthermore, the scaling of black hole mass with distance from the formation threshold, known to occur in near-critical gravitational collapse, is demonstrated to apply to primordial black hole formation.

  15. Black holes cannot support conformal scalar hair

    E-Print Network [OSTI]

    T. Zannias

    1994-09-14T23:59:59.000Z

    It is shown that the only static asymptotically flat non-extrema black hole solution of the Einstein-conformally invariant scalar field equations having the scalar field bounded on the horizon, is the Schwarzschild one. Thus black holes cannot be endowed with conformal scalar hair of finite length.

  16. Quantum Entropy of Charged Rotating Black Holes

    E-Print Network [OSTI]

    R. B. Mann

    1996-07-10T23:59:59.000Z

    I discuss a method for obtaining the one-loop quantum corrections to the tree-level entropy for a charged Kerr black hole. Divergences which appear can be removed by renormalization of couplings in the tree-level gravitational action in a manner similar to that for a static black hole.

  17. Analysis of records of embryo production in Red Brahman cows

    E-Print Network [OSTI]

    Riano Rocha, Edgar Hernando

    2005-11-01T23:59:59.000Z

    ANALYSIS OF RECORDS OF EMBRYO PRODUCTION IN RED BRAHMAN COWS A Thesis by EDGAR HERNANDO RIANO ROCHA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... August 2005 Major Subject: Physiology of Reproduction ANALYSIS OF RECORDS OF EMBRYO PRODUCTION IN RED BRAHMAN COWS A Thesis by EDGAR HERNANDO RIANO ROCHA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  18. Inheritance of some characters in red rice (Oryza sativa L.)

    E-Print Network [OSTI]

    Livore, Alberto Blas

    1985-01-01T23:59:59.000Z

    INHERITANCE OF SOME CHARACTERS IN RED RICE (ORYZA SATIVA L. ) A Thesis ALBERTO BLAS LIVORE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1985... Major Subject: Plant Breeding INHERITANCE OF SOME CHARACTERS IN RED RICE (ORYZA SATIVA L. ) A Thesis ALBERTO BLAS LIVORE Approved as to style and content by: J. Bockholt Co-Chairman) James W. Stansel (Co-Chairman) Charles N. Bollich (Member...

  19. Increasing herbicide selectivity between rice and red rice

    E-Print Network [OSTI]

    Koetz, Paul Howard

    1982-01-01T23:59:59.000Z

    INCREASING HERBICIDE SEIZCTIVITY BETWEEN RICE AND RED RICE A Thesis by PAUL HOWARD KOETZ Submitted to the Graduate College of Texas AAN University 'n partial fulfillment of the requirement for the degree of' WASTER OF SCIENCE August 1982... major Subject: Agronomy INCREASING HERBICIDE SELECTIVITY BETWEEN RICE AND RED RICE A Thesis by PAUL HOWARD KOETZ Approved as to style and content by (Chairman of Committee) (Member (Member) (Head of Departmen August l982 ABSTRACT Increasing...

  20. Young Collapsed Supernova Remnants: Similarities and Differences in Neutron Stars, Black Holes, and More Exotic Objects

    E-Print Network [OSTI]

    James S. Graber

    2000-12-09T23:59:59.000Z

    Type Ia supernovae are thought to explode completely, leaving no condensed remnant, only an expanding shell. Other types of supernovae are thought to involve core collapse and are expected to leave a condensed remnant, which could be either a neutron star or a black hole, or just possibly, something more exotic, such as a quark orstrange star, a naked singularity, a frozen star, a wormhole or a red hole. It has proven surprisingly difficult to determine which type of condensed remnant has been formed in those cases where the diagnostic highly regular pulsar signature of a neutron star is absent. We consider possible observational differences between the two standard candidates, as well as the more speculative alternatives. We classify condensed remnants according to whether they do or do not possess three major features: 1)a hard surface, 2)an event horizon, and 3)a singularity. Black holes and neutron stars differ on all three criteria. Some of the less frequently considered alternatives are "intermediate," in the sense that they possess some of the traits of a black hole and some of the traits of a neutron star. This possibility makes distinguishing the various possibilities even more difficult.

  1. Gravitating discs around black holes

    E-Print Network [OSTI]

    V. Karas; J. -M. Hure; O. Semerak

    2004-01-16T23:59:59.000Z

    Fluid discs and tori around black holes are discussed within different approaches and with the emphasis on the role of disc gravity. First reviewed are the prospects of investigating the gravitational field of a black hole--disc system by analytical solutions of stationary, axially symmetric Einstein's equations. Then, more detailed considerations are focused to middle and outer parts of extended disc-like configurations where relativistic effects are small and the Newtonian description is adequate. Within general relativity, only a static case has been analysed in detail. Results are often very inspiring, however, simplifying assumptions must be imposed: ad hoc profiles of the disc density are commonly assumed and the effects of frame-dragging and completely lacking. Astrophysical discs (e.g. accretion discs in active galactic nuclei) typically extend far beyond the relativistic domain and are fairly diluted. However, self-gravity is still essential for their structure and evolution, as well as for their radiation emission and the impact on the environment around. For example, a nuclear star cluster in a galactic centre may bear various imprints of mutual star--disc interactions, which can be recognised in observational properties, such as the relation between the central mass and stellar velocity dispersion.

  2. Black hole and holographic dark energy

    E-Print Network [OSTI]

    Yun Soo Myung

    2007-04-11T23:59:59.000Z

    We discuss the connection between black hole and holographic dark energy. We examine the issue of the equation of state (EOS) for holographic energy density as a candidate for the dark energy carefully. This is closely related to the EOS for black hole, because the holographic dark energy comes from the black hole energy density. In order to derive the EOS of a black hole, we may use its dual (quantum) systems. Finally, a regular black hole without the singularity is introduced to describe an accelerating universe inside the cosmological horizon. Inspired by this, we show that the holographic energy density with the cosmological horizon as the IR cutoff leads to the dark energy-dominated universe with $\\omega_{\\rm \\Lambda}=-1$.

  3. Quantum Black Hole Model and Hawking's Radiation

    E-Print Network [OSTI]

    V. A. Berezin

    1996-02-12T23:59:59.000Z

    The black hole model with a self-gravitating charged spherical symmetric dust thin shell as a source is considered. The Schroedinger-type equation for such a model is derived. This equation appeared to be a finite differences equation. A theory of such an equation is developed and general solution is found and investigated in details. The discrete spectrum of the bound state energy levels is obtained. All the eigenvalues appeared to be infinitely degenerate. The ground state wave functions are evaluated explicitly. The quantum black hole states are selected and investigated. It is shown that the obtained black hole mass spectrum is compatible with the existence of Hawking's radiation in the limit of low temperatures both for large and nearly extreme Reissner-Nordstrom black holes. The above mentioned infinite degeneracy of the mass (energy) eigenvalues may appeared helpful in resolving the well known information paradox in the black hole physics.

  4. Black Hole Thermodynamics Based on Unitary Evolutions

    E-Print Network [OSTI]

    Feng, Yu-Lei

    2015-01-01T23:59:59.000Z

    In this paper, we try to construct black hole thermodynamics based on the fact that, the formation and evaporation of a black hole can be described by quantum unitary evolutions. First, we show that the Bekenstein-Hawking entropy $S_{BH}$ cannot be a Boltzmann or thermal entropy. To confirm this statement, we show that the original black hole's "first law" cannot be treated as the first law of thermodynamics formally, due to some missing metric perturbations caused by matter. Then, by including those (quantum) metric perturbations, we show that the black hole formation and evaporation can be described in a unitary manner effectively, through a quantum channel between the exterior and interior of the event horizon. In this way, the paradoxes of information loss and firewall can be resolved effectively. Finally, we show that black hole thermodynamics can be constructed in an ordinary way, by constructing statistical mechanics.

  5. Fourier Analysis of the BTZ Black Hole

    E-Print Network [OSTI]

    Ian M. Tolfree

    2009-11-11T23:59:59.000Z

    In this paper we extend our previous work regarding the role of the Fourier transformation in bulk to boundary mappings to include the BTZ black hole. We follow standard procedures for modifying Fourier Transformations to accommodate quotient spaces and arrive at a bulk to boundary mapping in a black hole background. We show that this mapping is consistent with known results and lends a new insight into the AdS/CFT duality. We find that the micro-states corresponding to the entropy of a bulk scalar field are the Fourier coefficients on the boundary, which transform under the principal series representation of $SL(2,R)$. Building upon this we present a toy model to analyze the implications of this for the origin of black hole entropy. We find that the black hole micro-states live on the boundary and correspond to the possible emission modes of the black hole

  6. An electromagnetic black hole made of metamaterials

    E-Print Network [OSTI]

    Cheng, Qiang

    2009-01-01T23:59:59.000Z

    Traditionally, a black hole is a region of space with huge gravitational field in the means of general relativity, which absorbs everything hitting it including the light. In general relativity, the presence of matter-energy densities results in the motion of matter propagating in a curved spacetime1, which is similar to the electromagnetic-wave propagation in a curved space and in an inhomogeneous metamaterial2. Hence one can simulate the black hole using electromagnetic fields and metamaterials. In a recent theoretical work, an optical black hole has been proposed based on metamaterials, in which the numerical simulations showed a highly efficient light absorption3. Here we report the first experimental demonstration of electromagnetic black hole in the microwave frequencies. The proposed black hole is composed of non-resonant and resonant metamaterial structures, which can absorb electromagnetic waves efficiently coming from all directions due to the local control of electromagnetic fields. Hence the elect...

  7. Fermionic greybody factors in dilaton black holes

    E-Print Network [OSTI]

    Jahed Abedi; Hessamaddin Arfaei

    2014-09-17T23:59:59.000Z

    In this paper the question of emission of fermions in the process of dilaton black hole evolution and its characters for different dilaton coupling constants $\\alpha$ is studied. The main quantity of interest, the greybody factors are calculated both numerically and in analytical approximation. The dependence of rates of evaporation and behaviour on the dilaton coupling constant is analyzed. Having calculated the greybody factors we are able to address the question of the final fate of the dilaton black hole. For that we also need to make dynamical treatment of the solution by considering the backreaction which will show a crucial effect on the final result. We find a transition line in $(Q/M, \\alpha)$ plane that separates the two regimes for the fate of the black hole, decay regime and extremal regime. In the decay regime the black hole completely evaporates, while in the extremal regime the black hole approaches the extremal limit by radiation and becomes stable.

  8. Black holes in Asymptotically Safe Gravity

    E-Print Network [OSTI]

    Saueressig, Frank; D'Odorico, Giulio; Vidotto, Francesca

    2015-01-01T23:59:59.000Z

    Black holes are among the most fascinating objects populating our universe. Their characteristic features, encompassing spacetime singularities, event horizons, and black hole thermodynamics, provide a rich testing ground for quantum gravity ideas. In this note we observe that the renormalization group improved Schwarzschild black holes constructed by Bonanno and Reuter within Weinberg's asymptotic safety program constitute a prototypical example of a Hayward geometry used to model non-singular black holes within quantum gravity phenomenology. Moreover, they share many features of a Planck star: their effective geometry naturally incorporates the one-loop corrections found in the effective field theory framework, their Kretschmann scalar is bounded, and the black hole singularity is replaced by a regular de Sitter patch. The role of the cosmological constant in the renormalization group improvement process is briefly discussed.

  9. Red Storm usage model :Version 1.12.

    SciTech Connect (OSTI)

    Jefferson, Karen L.; Sturtevant, Judith E.

    2005-12-01T23:59:59.000Z

    Red Storm is an Advanced Simulation and Computing (ASC) funded massively parallel supercomputer located at Sandia National Laboratories (SNL). The Red Storm Usage Model (RSUM) documents the capabilities and the environment provided for the FY05 Tri-Lab Level II Limited Availability Red Storm User Environment Milestone and the FY05 SNL Level II Limited Availability Red Storm Platform Milestone. This document describes specific capabilities, tools, and procedures to support both local and remote users. The model is focused on the needs of the ASC user working in the secure computing environments at Los Alamos National Laboratory (LANL), Lawrence Livermore National Laboratory (LLNL), and SNL. Additionally, the Red Storm Usage Model maps the provided capabilities to the Tri-Lab ASC Computing Environment (ACE) requirements. The ACE requirements reflect the high performance computing requirements for the ASC community and have been updated in FY05 to reflect the community's needs. For each section of the RSUM, Appendix I maps the ACE requirements to the Limited Availability User Environment capabilities and includes a description of ACE requirements met and those requirements that are not met in that particular section. The Red Storm Usage Model, along with the ACE mappings, has been issued and vetted throughout the Tri-Lab community.

  10. Assessment of Biomass Energy Opportunities for the Red Lake Band of Chippewa Indians

    SciTech Connect (OSTI)

    Scott Haase (McNeil Technologies, Inc)

    2005-09-30T23:59:59.000Z

    Assessment of biomass energy and biobased product manufacturing opportunities for the Red Lake Tribe.

  11. Gravitational waves versus black holes

    E-Print Network [OSTI]

    Trevor W. Marshall

    2007-07-02T23:59:59.000Z

    It is argued that, in order for the gravitational field to be propagated as a wave, it is necessary for it to satisfy a further set of field equations, in addition to those of Einstein and Hilbert, and these equations mean there is a preferred coordinate frame, called the Global Inertial Frame, giving rise to a unique metric . The implication is that a true gravitational field is not compatible with Einstein's Principle of Equivalence, which is in contradiction with his other fundamental concept of locality. The additional field equations ensure that gravitational collapse does not go below the Schwarzschild radius, thereby excluding the possibility of singular solutions (black holes) of the Einstein-Hilbert equations. Such solutions would also violate Einstein's locality principle.

  12. GAMMA-RAY FLARES FROM RED GIANT/JET INTERACTIONS IN ACTIVE GALACTIC NUCLEI

    SciTech Connect (OSTI)

    Barkov, Maxim V.; Aharonian, Felix A.; Bosch-Ramon, ValentI, E-mail: bmv@mpi-hd.mpg.d [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, 69117 Heidelberg (Germany)

    2010-12-01T23:59:59.000Z

    Non-blazar active galactic nuclei (AGNs) have been recently established as a class of gamma-ray sources. M87, a nearby representative of this class, shows fast TeV variability on timescales of a few days. We suggest a scenario of flare gamma-ray emission in non-blazar AGNs based on a red giant (RG) interacting with the jet at the base. We solve the hydrodynamical equations that describe the evolution of the envelope of an RG blown by the impact of the jet. If the RG is at least slightly tidally disrupted by the supermassive black hole, enough stellar material will be blown by the jet, expanding quickly until a significant part of the jet is shocked. This process can render suitable conditions for energy dissipation and proton acceleration, which could explain the detected day-scale TeV flares from M87 via proton-proton collisions. Since the radiation produced would be unbeamed, such an event should be mostly detected from non-blazar AGNs. They may be frequent phenomena, detectable in the GeV-TeV range even up to distances of {approx}1 Gpc for the most powerful jets. The counterparts at lower energies are expected to be not too bright. M87, and nearby non-blazar AGNs in general, can be fast variable sources of gamma-rays through RG/jet interactions.

  13. X-RED: A Satellite Mission Concept To Detect Early Universe Gamma Ray Bursts

    E-Print Network [OSTI]

    Krumpe, M; Cherix, M; Coffey, D; Deroo, P; Egger, G; Hasinger, G; Hoffmann, A I D; Lefever, K; Liermann, A; Lund, N; Parmar, A; Russo, P; Steiper, J; Strodl, T; Vilardell, F; Wahlin, R; Albrecht, Simon; Cherix, Marc; Coffey, Deirdre; Deroo, Pieter; Egger, Georg; Hasinger, Guenther; Hoffmann, Agnes I.D.; Krumpe, Mirko; Lefever, Karolien; Liermann, Adriane; Lund, Niels; Parmar, Arvind; Russo, Pedro; Steiper, Joerg; Strodl, Thomas; Vilardell, Francesc; Wahlin, Rurik

    2005-01-01T23:59:59.000Z

    Gamma ray bursts (GRBs) are the most energetic eruptions known in the Universe. Instruments such as Compton-GRO/BATSE and the GRB monitor on BeppoSAX have detected more than 2700 GRBs and, although observational confirmation is still required, it is now generally accepted that many of these bursts are associated with the collapse of rapidly spinning massive stars to form black holes. Consequently, since first generation stars are expected to be very massive, GRBs are likely to have occurred in significant numbers at early epochs. X-red is a space mission concept designed to detect these extremely high redshifted GRBs, in order to probe the nature of the first generation of stars and hence the time of reionisation of the early Universe. We demonstrate that the gamma and x-ray luminosities of typical GRBs render them detectable up to extremely high redshifts (z~10-30), but that current missions such as HETE2 and SWIFT operate outside the observational range for detection of high redshift GRB afterglows. Therefo...

  14. Morphology of PolyethyleneCarbon Black Composites G. BEAUCAGE,1

    E-Print Network [OSTI]

    Beaucage, Gregory

    Morphology of Polyethylene­Carbon Black Composites G. BEAUCAGE,1 S. RANE,1 D. W. SCHAEFER,1 G. LONG-ray scattering (SAXS) study of a conductive grade of carbon black and carbon black­polymer composites(methyl methacrylate); carbon black; filler; composite; conductivity; percolation INTRODUCTION The morphology

  15. Thermodynamics of Dyonic Lifshitz Black Holes

    E-Print Network [OSTI]

    Tobias Zingg

    2011-07-15T23:59:59.000Z

    Black holes with asymptotic anisotropic scaling are conjectured to be gravity duals of condensed matter system close to quantum critical points with non-trivial dynamical exponent z at finite temperature. A holographic renormalization procedure is presented that allows thermodynamic potentials to be defined for objects with both electric and magnetic charge in such a way that standard thermodynamic relations hold. Black holes in asymptotic Lifshitz spacetimes can exhibit paramagnetic behavior at low temperature limit for certain values of the critical exponent z, whereas the behavior of AdS black holes is always diamagnetic.

  16. Some remarks on black hole thermodynamics

    E-Print Network [OSTI]

    R. Y. Chiao

    2011-02-04T23:59:59.000Z

    Two thermodynamic "paradoxes" of black hole physics are re-examined. The first is that there is a thermal instability involving two coupled blackbody cavities containing two black holes, and second is that a classical black hole can swallow up entropy in the form of ambient blackbody photons without increasing its mass. The resolution of the second paradox by Bekenstein and by Hawking is re-visited. The link between Hawking radiation and Wigner's superluminal tunneling time is discussed using two equivalent Feynman diagrams, and Feynman's re-interpretation principle.

  17. Black hole hair in higher dimensions

    E-Print Network [OSTI]

    Chao Cao; Yi-Xin Chen; Jian-Long Li

    2008-04-02T23:59:59.000Z

    We study the property of matter in equilibrium with a static, spherically symmetric black hole in D-dimensional spacetime. It requires this kind of matter has an equation of state (\\omega\\equiv p_r/\\rho=-1/(1+2kn), k,n\\in \\mathbb{N}), which seems to be independent of D. However, when we associate this with specific models, some interesting limits on space could be found: (i)(D=2+2kn) while the black hole is surrounded by cosmic strings; (ii)the black hole can be surrounded by linear dilaton field only in 4-dimensional spacetime. In both cases, D=4 is special.

  18. Red phosphors for use in high CRI fluorescent lamps

    DOE Patents [OSTI]

    Srivastava, Alok; Comanzo, Holly; Manivannan, Vankatesan; Setlur, Anant Achyut

    2005-11-15T23:59:59.000Z

    Novel red emitting phosphors for use in fluorescent lamps resulting in superior color rendering index values compared to conventional red phosphors. Also disclosed is a fluorescent lamp including a phosphor layer comprising blends of one or more of a blue phosphor, a blue-green phosphor, a green phosphor and a red a phosphor selected from the group consisting of SrY.sub.2 O.sub.4 :Eu.sup.3+, (Y,Gd)Al.sub.3 B.sub.4 O.sub.12 :Eu.sup.3+, and [(Y.sub.1-x-y-m La.sub.y)Gd.sub.x ]BO.sub.3 :Eu.sub.m wherein y<0.50 and m=0.001-0.3. The phosphor layer can optionally include an additional deep red phosphor and a yellow emitting phosphor. The resulting lamp will exhibit a white light having a color rendering index of 90 or higher with a correlated color temperature of from 2500 to 10000 Kelvin. The use of the disclosed red phosphors in phosphor blends of lamps results in high CRI light sources with increased stability and acceptable lumen maintenance over the course of the lamp life.

  19. Ages of White Dwarf-Red Subdwarf Systems

    E-Print Network [OSTI]

    Hektor Monteiro; Wei-Chun Jao; Todd Henry; John Subasavage; Thom Beaulieu

    2005-10-12T23:59:59.000Z

    We provide the first age estimates for two recently discovered white dwarf-red subdwarf systems, LHS 193AB and LHS 300AB. These unusual systems provide a new opportunity for linking the reliable age estimates for the white dwarfs to the (measurable) metallicities of the red subdwarfs. We have obtained precise photometry in the $V_{J}R_{KC}I_{KC}JH$ bands and spectroscopy covering from 6000\\AA to 9000\\AA for the two new systems, as well as for a comparison white dwarf-main sequence red dwarf system, GJ 283 AB. Using model grids available in the literature, we estimate the cooling age as well as temperature, surface gravity, mass, progenitor mass and {\\it total} lifetimes of the white dwarfs. The results indicate that the two new systems are probably ancient thick disk objects with ages of at least 6-9 Gyr. We also conduct searches of red dwarf and white dwarf compendia from SDSS data and the L{\\'e}pine Shara Proper Motion (LSPM) catalog for additional common proper motion white dwarf-red subdwarf systems. Only seven new candidate systems are found, which indicates the rarity of these systems.

  20. Thermodynamics of Schwarzschild-de Sitter black hole: thermal stability of Nariai black hole

    E-Print Network [OSTI]

    Yun Soo Myung

    2008-03-28T23:59:59.000Z

    We study thermodynamics of the Schwarzschild-de Sitter black hole in five dimensions by introducing two temperatures based on the standard and Bousso-Hawking normalizations. We use the first-law of thermodynamics to derive thermodynamic quantities. The two temperatures indicate that the Nariai black hole is thermodynamically unstable. However, it seems that black hole thermodynamics favors the standard normalization, and does not favor the Bousso-Hawking normalization.

  1. UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation Into the Wheat Straw Paper

    E-Print Network [OSTI]

    pulping is the black liquor residue. Regarding the black liquor, a by-product of wheat straw pulping, Vibratory Shear Enhanced Process (VSEP) shows that lignin and hemicelluloses can be extracted from the blackUBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation

  2. Fax +41 61 306 12 34 E-Mail karger@karger.ch

    E-Print Network [OSTI]

    Qin, Wensheng

    of 1% black liquor in salt media by an average of 2.07-fold after 21 days of incu- bation. Similarly

  3. attached biomass growth: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    animal manure, black liquor,etc. Waste: household waste, sewage sludge, animal manure, slaughterhouse waste. 12;Biomass characteristics Biomass is a storable...

  4. aboveground biomass distributions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    animal manure, black liquor,etc. Waste: household waste, sewage sludge, animal manure, slaughterhouse waste. 12;Biomass characteristics Biomass is a storable...

  5. algal biomass biosorbents: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    animal manure, black liquor,etc. Waste: household waste, sewage sludge, animal manure, slaughterhouse waste. 12;Biomass characteristics Biomass is a storable...

  6. advanced biomass reburning: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    animal manure, black liquor,etc. Waste: household waste, sewage sludge, animal manure, slaughterhouse waste. 12;Biomass characteristics Biomass is a storable...

  7. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 PARTICULATES #1PARTICULATES #1

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Leather waste ~5 Estonian oil shale ~40 OrimulsionTM ~1.5 Black liquor solids 30 - 40 #12;HELSINKI 2 - 8 Oil oil oil

  8. Multipole moments for black objects in five dimensions

    E-Print Network [OSTI]

    Kentaro Tanabe; Seiju Ohashi; Tetsuya Shiromizu

    2010-11-19T23:59:59.000Z

    In higher dimensions than four, conventional uniqueness theorem in asymptotically flat space-times does not hold, i.e., black objects can not be classified only by the mass, angular momentum and charge. In this paper, we define multipole moments for black objects and show that Myers-Perry black hole and black ring can be distinguished by quadrupole moments. This consideration gives us a new insight for the uniqueness theorem for black objects in higher dimensions.

  9. Thermodynamics and evaporation of the noncommutative black hole

    E-Print Network [OSTI]

    Yun Soo Myung; Yong-Wan Kim; Young-Jai Park

    2007-01-21T23:59:59.000Z

    We investigate the thermodynamics of the noncommutative black hole whose static picture is similar to that of the nonsingular black hole known as the de Sitter-Schwarzschild black hole. It turns out that the final remnant of extremal black hole is a thermodynamically stable object. We describe the evaporation process of this black hole by using the noncommutativity-corrected Vaidya metric. It is found that there exists a close relationship between thermodynamic approach and evaporation process.

  10. Spacetime noncommutative effect on black hole as particle accelerators

    E-Print Network [OSTI]

    Chikun Ding; Changqing Liu; Qian Guo

    2013-01-08T23:59:59.000Z

    We study the spacetime noncommutative effect on black hole as particle accelerators and, find that particle falling from infinity with zero velocity cannot collide with unbound energy when the noncommutative Kerr black hole is exactly extremal. Our results also show that the bigger of the spinning black hole's mass is, the higher of center of mass energy that the particles obtain. For small and medium noncommutative Schwarzschild black hole, the collision energy depends on the black holes' mass.

  11. Towards Black Hole Entropy in Shape Dynamics

    E-Print Network [OSTI]

    Gabriel Herczeg; Vasudev Shyam

    2014-10-21T23:59:59.000Z

    Shape dynamics is classical theory of gravity which agrees with general relativity in many important cases, but possesses different gauge symmetries and constraints. Rather than spacetime diffeomorphism invariance, shape dynamics takes spatial diffeomorphism invariance and spatial Weyl invariance as the fundamental gauge symmetries associated with the gravitational field. Since the area of the event horizon of a black hole transforms under a generic spatial Weyl transformation, there has been some doubt that one can speak sensibly about the thermodynamics of black holes in shape dynamics. The purpose of this paper is to show that by treating the event horizon of a black hole as an interior boundary, one can recover familiar notions of black hole thermodynamics in shape dynamics and define a gauge invariant entropy that agrees with general relativity.

  12. Multipole moments of bumpy black holes

    E-Print Network [OSTI]

    Vigeland, Sarah Jane

    General relativity predicts the existence of black holes, compact objects whose spacetimes depend only on their mass, spin, and charge in vacuum (the no-hair theorem). As various observations probe deeper into the strong ...

  13. Energy of 4-Dimensional Black Hole, etc

    E-Print Network [OSTI]

    Dmitriy Palatnik

    2011-07-18T23:59:59.000Z

    In this letter I suggest possible redefinition of mass density, not depending on speed of the mass element, which leads to a more simple stress-energy for an object. I calculate energy of black hole.

  14. Black Hills Energy- Solar Power Program

    Broader source: Energy.gov [DOE]

    All incentive payments are subject to the availability of funds and a pre-installation site inspection. Black Hills Energy has established participation caps for each tier. The status of funding ...

  15. Horizon Operator Approach to Black Hole Quantization

    E-Print Network [OSTI]

    G. 't Hooft

    1994-02-21T23:59:59.000Z

    The $S$-matrix Ansatz for the construction of a quantum theory of black holes is further exploited. We first note that treating the metric tensor $g_{\\m\

  16. Topological Black Holes -- Outside Looking In

    E-Print Network [OSTI]

    R. B. Mann

    1997-09-15T23:59:59.000Z

    I describe the general mathematical construction and physical picture of topological black holes, which are black holes whose event horizons are surfaces of non-trivial topology. The construction is carried out in an arbitrary number of dimensions, and includes all known special cases which have appeared before in the literature. I describe the basic features of massive charged topological black holes in $(3+1)$ dimensions, from both an exterior and interior point of view. To investigate their interiors, it is necessary to understand the radiative falloff behaviour of a given massless field at late times in the background of a topological black hole. I describe the results of a numerical investigation of such behaviour for a conformally coupled scalar field. Significant differences emerge between spherical and higher genus topologies.

  17. Spacetime constraints on accreting black holes

    SciTech Connect (OSTI)

    Garofalo, David [Jet Propulsion Laboratory, California Institute of Technology, Pasadena California 91109 (United States)

    2009-06-15T23:59:59.000Z

    We study the spin dependence of accretion onto rotating Kerr black holes using analytic techniques. In its linear regime, angular momentum transport in MHD turbulent accretion flow involves the generation of radial magnetic field connecting plasma in a differentially rotating flow. We take a first principles approach, highlighting the constraint that limits the generation and amplification of radial magnetic fields, stemming from the transfer of energy from mechanical to magnetic form. Because the energy transferred in magnetic form is ultimately constrained by gravitational potential energy or Killing energy, the spin dependence of the latter allows us to derive spin-dependent constraints on the success of the accreting plasma to expel its angular momentum. We find an inverse relationship between this ability and black hole spin. If this radial magnetic field generation forms the basis for angular momentum transfer in accretion flows, accretion rates involving Kerr black holes are expected to be lower as the black hole spin increases in the prograde sense.

  18. Scattering map for two black holes

    E-Print Network [OSTI]

    Alessandro P. S. de Moura; Patricio S. Letelier

    1999-10-25T23:59:59.000Z

    We study the motion of light in the gravitational field of two Schwarzschild black holes, making the approximation that they are far apart, so that the motion of light rays in the neighborhood of one black hole can be considered to be the result of the action of each black hole separately. Using this approximation, the dynamics is reduced to a 2-dimensional map, which we study both numerically and analytically. The map is found to be chaotic, with a fractal basin boundary separating the possible outcomes of the orbits (escape or falling into one of the black holes). In the limit of large separation distances, the basin boundary becomes a self-similar Cantor set, and we find that the box-counting dimension decays slowly with the separation distance, following a logarithmic decay law.

  19. Radiolabeled red blood cells: status, problems, and prospects

    SciTech Connect (OSTI)

    Srivastava, S.C.

    1983-01-01T23:59:59.000Z

    Radionuclidic labels for red cells can be divided into two main categories - cohort or pulse labels, and random labels. The random labels are incorporated into circulating cells of all ages and the labeling process is usually carried out in vitro. The red cell labels in predominant use involve random labeling and employ technetium-99m, chromium-51, indium-111, and gallium-68, roughly in that order. The extent of usefulness depends on the properties of the label such as the half-life, decay mode, and in-vivo stability, etc. Labeled cells can be used for red cell survival measurements when the half-life of the radionuclide is sufficiently long. The major portion of this article deals with random labels.

  20. Black hole evolution: I. Supernova-regulated black hole growth

    E-Print Network [OSTI]

    Dubois, Yohan; Silk, Joseph; Devriendt, Julien; Slyz, Adrianne; Teyssier, Romain

    2015-01-01T23:59:59.000Z

    The growth of a supermassive black hole (BH) is determined by how much gas the host galaxy is able to feed it, which in turn is controlled by the cosmic environment, through galaxy mergers and accretion of cosmic flows that time how galaxies obtain their gas, but also by internal processes in the galaxy, such as star formation and feedback from stars and the BH itself. In this paper, we study the growth of a 10^12 Msun halo at z=2, which is the progenitor of an archetypical group of galaxies at z=0, and of its central BH by means of a high-resolution zoomed cosmological simulation, the Seth simulation. We study the evolution of the BH driven by the accretion of cold gas in the galaxy, and explore the efficiency of the feedback from supernovae (SNe). For a relatively inefficient energy input from SNe, the BH grows at the Eddington rate from early times, and reaches self-regulation once it is massive enough. We find that at early cosmic times z>3.5, efficient feedback from SNe forbids the formation of a settled...

  1. Charged Cylindrical Black Holes in Conformal Gravity

    E-Print Network [OSTI]

    Jackson Levi Said; Joseph Sultana; Kristian Zarb Adami

    2013-01-04T23:59:59.000Z

    Considering cylindrical topology we present the static solution for a charged black hole in conformal gravity. We show that unlike the general relativistic case there are two different solutions, both including a factor that when set to zero recovers the familiar static charged black string solution in Einstein's theory. This factor gives rise to a linear term in the potential that also features in the neutral case and may have significant ramifications for particle trajectories.

  2. Comment on "Black holes constrain varying constants"

    E-Print Network [OSTI]

    V. V. Flambaum

    2002-08-20T23:59:59.000Z

    A recent paper [DDL] claims that the increase of the proton electric charge e leads to a (forbidden) decrease of black hole entropy, therefore, possible evidence for variation of $\\alpha=e^2/\\hbar c$ [alpha] must be interpreted as a decrease of the speed of light. We argue that purely theoretical consideration of black holes possibly cannot give any model-independent limitations on variation of fundamental constants.

  3. Fractionated Branes and Black Hole Interiors

    E-Print Network [OSTI]

    Martinec, Emil J

    2015-01-01T23:59:59.000Z

    Combining a variety of results in string theory and general relativity, a picture of the black hole interior is developed wherein spacetime caps off at an inner horizon, and the inter-horizon region is occupied by a Hagedorn gas of a very low tension state of fractionated branes. This picture leads to natural resolutions of a variety of puzzles concerning quantum black holes. Gravity Research Foundation 2015 Fourth Prize Award for Essays on Gravitation.

  4. Fractionated Branes and Black Hole Interiors

    E-Print Network [OSTI]

    Emil J. Martinec

    2015-05-20T23:59:59.000Z

    Combining a variety of results in string theory and general relativity, a picture of the black hole interior is developed wherein spacetime caps off at an inner horizon, and the inter-horizon region is occupied by a Hagedorn gas of a very low tension state of fractionated branes. This picture leads to natural resolutions of a variety of puzzles concerning quantum black holes. Gravity Research Foundation 2015 Fourth Prize Award for Essays on Gravitation.

  5. Local temperature for dynamical black holes

    E-Print Network [OSTI]

    Sean A. Hayward; R. Di Criscienzo; M. Nadalini; L. Vanzo; S. Zerbini

    2008-12-13T23:59:59.000Z

    A local Hawking temperature was recently derived for any future outer trapping horizon in spherical symmetry, using a Hamilton-Jacobi tunneling method, and is given by a dynamical surface gravity as defined geometrically. Descriptions are given of the operational meaning of the temperature, in terms of what observers measure, and its relation to the usual Hawking temperature for static black holes. Implications for the final fate of an evaporating black hole are discussed.

  6. Notes on Black Hole Fluctuations and Backreaction

    E-Print Network [OSTI]

    B. L. Hu; Alpan Raval; Sukanya Sinha

    1999-01-05T23:59:59.000Z

    In these notes we prepare the ground for a systematic investigation into the issues of black hole fluctuations and backreaction by discussing the formulation of the problem, commenting on possible advantages and shortcomings of existing works, and introducing our own approach via a stochastic semiclassical theory of gravity based on the Einstein-Langevin equation and the fluctuation-dissipation relation for a self-consistent description of metric fluctuations and dissipative dynamics of the black hole with backreaction of its Hawking radiance.

  7. Asymptotically Lifshitz brane-world black holes

    SciTech Connect (OSTI)

    Ranjbar, Arash, E-mail: a_ranjbar@sbu.ac.ir; Sepangi, Hamid Reza, E-mail: hr-sepangi@sbu.ac.ir; Shahidi, Shahab, E-mail: s_shahidi@sbu.ac.ir

    2012-12-15T23:59:59.000Z

    We study the gravity dual of a Lifshitz field theory in the context of a RSII brane-world scenario, taking into account the effects of the extra dimension through the contribution of the electric part of the Weyl tensor. We study the thermodynamical behavior of such asymptotically Lifshitz black holes. It is shown that the entropy imposes the critical exponent z to be bounded from above. This maximum value of z corresponds to a positive infinite entropy as long as the temperature is kept positive. The stability and phase transition for different spatial topologies are also discussed. - Highlights: Black-Right-Pointing-Pointer Studying the gravity dual of a Lifshitz field theory in the context of brane-world scenario. Black-Right-Pointing-Pointer Studying the thermodynamical behavior of asymptotically Lifshitz black holes. Black-Right-Pointing-Pointer Showing that the entropy imposes the critical exponent z to be bounded from above. Black-Right-Pointing-Pointer Discussing the phase transition for different spatial topologies.

  8. Method for determining properties of red blood cells

    DOE Patents [OSTI]

    Gourley, Paul L. (Albuquerque, NM)

    2001-01-01T23:59:59.000Z

    A method for quantifying the concentration of hemoglobin in a cell, and indicia of anemia, comprises determining the wavelength of the longitudinal mode of a liquid in a laser microcavity; determining the wavelength of the fundamental transverse mode of a red blood cell in the liquid in the laser microcavity; and determining if the cell is anemic from the difference between the wavelength of the longitudinal mode and the fundamental transverse mode. In addition to measuring hemoglobin, the invention includes a method using intracavity laser spectroscopy to measure the change in spectra as a function of time for measuring the influx of water into a red blood cell and the cell's subsequent rupture.

  9. Varieties of Cotton in the Red Prairies of Northwest Texas.

    E-Print Network [OSTI]

    Quinby, John Roy

    1927-01-01T23:59:59.000Z

    . NORTHCUTT. JR., B. S.. Feed Inspedor SIDNEY D. REYNOLDS. JR.. Feed Inspector P. A. MOORE, Feed Inspector SUBSTATIONS No. 1 Beerille, Bee County: R. A. HALL, B. S.. Superintendent o. 10. Ftsdfng and Breeding Station. near College Station. Brazos Connty... OF COTTON IN THE RED PRAIRIES OF NORTH- WEST TEXAS Substation No. 12 of the Texas Agricultural Experiment Station is located in the eastern part of Hardeman County southwest of Chilli- cothe about midway between the Red and Pease Rivers, and in the seo...

  10. Improving the Infra-red of Holographic Descriptions of QCD

    E-Print Network [OSTI]

    Nick Evans; Andrew Tedder; Tom Waterson

    2007-01-03T23:59:59.000Z

    A surprisingly good holographic description of QCD can be obtained from naive five dimensional gauge theory on a truncated AdS space. We seek to improve the infra-red description of QCD in such models by using a more sophisticated metric and an action derived from string theory duals of chiral symmetry breaking. Our metric is smooth into the infra-red and the chiral condensate is a prediction of the dynamics. The theory reproduces QCD meson data at the 10% level.

  11. RedShift Systems Corporation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt Ltd Jump to: navigation, searchRay County,OpenCounty, Texas:Red RiverRedShift

  12. THERMAL DEGRADATION OF A BLACK CHROME SOLAR SELECTIVE ABSORBER COATING: SHORT TERM

    E-Print Network [OSTI]

    Lampert, Carl M.

    2011-01-01T23:59:59.000Z

    black show appreciable degradation ically or mechanically upGA, May ety THERMAL DEGRADATION A BLACK CHROME SOLARis ion, Ext. 781 THERMAL DEGRADATION OF A BLACK CHROME SOLAR

  13. New red phosphor for near-ultraviolet light-emitting diodes with high color-purity

    SciTech Connect (OSTI)

    Wang, Zhengliang, E-mail: wzhl_ww@yahoo.com.cn [School of Chemistry and Biotechnology, Yunnan Nationalities University, Kunming, Yunnan 650031 (China)] [School of Chemistry and Biotechnology, Yunnan Nationalities University, Kunming, Yunnan 650031 (China); He, Pei; Wang, Rui [School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, Guangdong 510275 (China)] [School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, Guangdong 510275 (China); Zhao, Jishou [School of Chemistry and Biotechnology, Yunnan Nationalities University, Kunming, Yunnan 650031 (China)] [School of Chemistry and Biotechnology, Yunnan Nationalities University, Kunming, Yunnan 650031 (China); Gong, Menglian [School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, Guangdong 510275 (China)] [School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, Guangdong 510275 (China)

    2010-02-15T23:59:59.000Z

    New red phosphors, Na{sub 5}Eu(MoO{sub 4}){sub 4} doped with boron oxide were prepared by the solid-state reaction. Their structure and photo-luminescent properties were investigated. With the introduction of boron oxide, the red emission intensity of the phosphors under 395 nm excitation is strengthened, with high color-purity (x = 0.673, y = 0.327). The single red light-emitting diode was obtained by combining InGaN chip with the red phosphor, bright red light can be observed by naked eyes from the red light-emitting diodes under a forward bias of 20 mA.

  14. InsideBauer RED Labs: Start Me Up

    E-Print Network [OSTI]

    Azevedo, Ricardo

    : Lithuania 38 Bauer Recognized for Exemplary Internal Audit Program 41 RED Labs: Start Me Up 42 A Unique Adrenaline Rush 62 Cover: The Changing Landscape of Higher Education 64 A Whole New Venture 68 Energy Lecture Opens Doors 72 Bauer's Sales Excellence Institute Named Top University Sales Program 73 Our

  15. Resource Stewardship Tips for 2012 Recreational Red Snapper Season

    E-Print Network [OSTI]

    Watson, Craig A.

    trying to catch a bigger fish may have unintended consequences when water temperatures approach the mid creating a thermocline. The result is temperature shock and possibly death for the fish which remains rebuild and are reflected by the numerous large fish landed. Red Snapper dominate many Gulf of Mexico

  16. Alcian Blue Alizarin Red Skeletal Staining October 2003

    E-Print Network [OSTI]

    De Robertis, Eddy M.

    Alcian Blue ­ Alizarin Red Skeletal Staining October 2003 Eddy M. De Robertis 1. Dissect mice damage. 3. Replace 95% ethanol with Alcian blue staining solution for 1-3 days slowly rocking at room days. 4. Replace Alcian blue solution with 95% ethanol for 6 hours slowly rocking at room temperature

  17. HISTORY OF RED LAKES FISHERY, With Observations on

    E-Print Network [OSTI]

    was presented of the artificial propagation of the walleye and whitefish from 1918 through 1938. NOTE Average catch per lift 20 The walleyes of Lower Red Lake 25 Length -frequency distributions 25 Rate bass 50 Artificial propagation 50 Walleye 51 Whitefish 57 Brook, brown, rainbow, and lake trout 60

  18. The Hermeneutics and Genesis of the Red Cow Ritual

    E-Print Network [OSTI]

    MacDonald, Nathan

    2012-07-11T23:59:59.000Z

    HTR 105:3 (2012) 35171 The Hermeneutics and Genesis of the Red Cow Ritual* Nathan MacDonald University of Gttingen / University of St. Andrews Q#3;Introduction 7KH#3;GLIFXOWLHV#3;ZLWK#3;WKH#3;UHG#3;FRZ#3;ULWXDO#3;KDYH#3;ORQJ#3;H[HUFLVHG#3;UHDGHUV...

  19. Thermo Exam 1 pg 1 Fall 2010 RED barcode here

    E-Print Network [OSTI]

    Hart, Gus

    Thermo Exam 1 pg 1 Fall 2010 RED barcode here Physics 123 section 2 Exam 1 Colton 2-3669 Please otherwise instructed, give all numerical answers for the worked problems in SI units, to 3 or 4 significant not get this test booklet back. #12;Thermo Exam 1 pg 2 (15 pts) Problem 1: Multiple choice conceptual

  20. Thermo Exam 2 pg 1 Fall 2010 RED barcode here

    E-Print Network [OSTI]

    Hart, Gus

    Thermo Exam 2 pg 1 Fall 2010 RED barcode here Physics 123 section 2 Exam 2 Colton 2-3669 Please in SI units, to 3 or 4 significant digits. For answers that rely on intermediate results, remember to write down your CID at the top of the page? _________ #12;Thermo Exam 1 pg 2 (15 pts) Problem 1

  1. ORIGINAL PAPER Responses of red deer (Cervus elaphus) to regular

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    ORIGINAL PAPER Responses of red deer (Cervus elaphus) to regular disturbance by hill walkers Angela calving rates in elk Cervus elaphus canadensis have been linked to human disturbance (Philips-recognised that the effect of disturbance can vary with its predictability; unexpected events, such as hill walkers

  2. INTEGRATED LIDAR & PHOTOGRAMMETRIC DOCUMENTATION OF THE RED GULCH DINOSAUR

    E-Print Network [OSTI]

    Falkingham, Peter

    101 INTEGRATED LIDAR & PHOTOGRAMMETRIC DOCUMENTATION OF THE RED GULCH DINOSAUR TRACKSITE (WYOMING Resource Technology Section, National Operations Center, Bu- reau of Land Management, Bldg. 50 Denver, CO of successful schemes is testament to the advances made in attitudes and approaches to fossil site management

  3. Black-Hole Solutions to Einstein's Equations in the Presence of Matter and Modifications of Gravitation in Extra Dimensions

    E-Print Network [OSTI]

    B. Goutraux

    2010-11-22T23:59:59.000Z

    In this thesis, we wish to examine the black-hole solutions of modified gravity theories inspired by String Theory or Cosmology. Namely, these modifications will take the guise of additional gauge and scalar fields for the so-called Einstein-Maxwell-Dilaton theories with an exponential Liouville potential; and of extra spatial dimensions for Einstein-Gauss-Bonnet theories. The black-hole solutions of EMD theories as well as their integrability are reviewed. One of the main results is that a master equation is obtained in the case of planar horizon topology, which allows to completely integrate the problem for s special relationship between the couplings. We also classify existing solutions. We move on to the study of Gauss-Bonnet black holes, focusing on the six-dimensional case. It is found that the Gauss-Bonnet coupling exposes the Weyl tensor of the horizon to the dynamics, severely restricting the Einstein spaces admissible and effectively lifting some of the degeneracy on the horizon topology. We then turn to the study of the thermodynamic properties of black holes, in General Relativity as well as in EMD theories. For the latter, phase transitions may be found in the canonical ensemble, which resemble the phase transitions for Reissner-Nordstr\\"om black holes. Generically, we find that the thermodynamic properties (stability, order of phase transitions) depend crucially on the values of the EMD coupling constants. Finally, we interpret our planar EMD solutions holographically as Infra-Red geometries through the AdS/CFT correspondence, taking into account various validity constraints. We also compute AC and DC conductivities as applications to Condensed Matter Systems, and find some properties characteristic of strange metal behaviour.

  4. Holographic superconductor in the exact hairy black hole

    E-Print Network [OSTI]

    Yun Soo Myung; Chanyong Park

    2011-09-13T23:59:59.000Z

    We study the charged black hole of hyperbolic horizon with scalar hair (charged Martinez-Troncoso-Zanelli: CMTZ black hole) as a model of analytic hairy black hole for holographic superconductor. For this purpose, we investigate the second order phase transition between CMTZ and hyperbolic Reissner-Nordstr\\"om-AdS (HRNAdS) black holes. However, this transition unlikely occur. As an analytic treatment for holographic superconductor, we develop superconductor in the bulk and superfluidity on the boundary using the CMTZ black hole below the critical temperature. The presence of charge destroys the condensates around the zero temperature, which is in accord with the thermodynamic analysis of the CMTZ black hole.

  5. The Environmental Impact of Supermassive Black Holes

    E-Print Network [OSTI]

    Abraham Loeb

    2004-08-10T23:59:59.000Z

    The supermassive black holes observed at the centers of almost all present-day galaxies, had a profound impact on their environment. I highlight the principle of self-regulation, by which supermassive black holes grow until they release sufficient energy to unbind the gas that feeds them from their host galaxy. This principle explains several observed facts, including the correlation between the mass of a central black hole and the depth of the gravitational potential well of its host galaxy, and the abundance and clustering properties of bright quasars in the redshift interval of z~2-6. At lower redshifts, quasars might have limited the maximum mass of galaxies through the suppression of cooling flows in X-ray clusters. The seeds of supermassive black holes were likely planted in dwarf galaxies at redshifts z>10, through the collapse of massive or supermassive stars. The minimum seed mass can be identified observationally through the detection of gravitational waves from black hole binaries by Advanced LIGO or LISA. Aside from shaping their host galaxies, quasar outflows filled the intergalactic medium with magnetic fields and heavy elements. Beyond the reach of these outflows, the brightest quasars at z>6 have ionized exceedingly large volumes of gas (tens of comoving Mpc) prior to global reionization, and must have suppressed the faint end of the galaxy luminosity function in these volumes before the same occurred through the rest of the universe.

  6. Perturbative String Thermodynamics near Black Hole Horizons

    E-Print Network [OSTI]

    Thomas G. Mertens; Henri Verschelde; Valentin I. Zakharov

    2014-10-29T23:59:59.000Z

    We provide further computations and ideas to the problem of near-Hagedorn string thermodynamics near (uncharged) black hole horizons, building upon our earlier work JHEP 1403 (2014) 086. The relevance of long strings to one-loop black hole thermodynamics is emphasized. We then provide an argument in favor of the absence of $\\alpha'$-corrections for the (quadratic) heterotic thermal scalar action in Rindler space. We also compute the large $k$ limit of the cigar orbifold partition functions (for both bosonic and type II superstrings) which allows a better comparison between the flat cones and the cigar cones. A discussion is made on the general McClain-Roth-O'Brien-Tan theorem and on the fact that different torus embeddings lead to different aspects of string thermodynamics. The black hole/string correspondence principle for the 2d black hole is discussed in terms of the thermal scalar. Finally, we present an argument to deal with arbitrary higher genus partition functions, suggesting the breakdown of string perturbation theory (in $g_s$) to compute thermodynamical quantities in black hole spacetimes.

  7. Investigating Dark Energy with Black Hole Binaries

    E-Print Network [OSTI]

    Laura Mersini-Houghton; Adam Kelleher

    2009-06-08T23:59:59.000Z

    The accelerated expansion of the universe is ascribed to the existence of dark energy. Black holes accretion of dark energy induces a mass change proportional to the energy density and pressure of the background dark energy fluid. The time scale during which the mass of black holes changes considerably is too long relative to the age of the universe, thus beyond detection possibilities. We propose to take advantage of the modified black hole masses for exploring the equation of state $w[z]$ of dark energy, by investigating the evolution of supermassive black hole binaries on a dark energy background. Deriving the signatures of dark energy accretion on the evolution of binaries, we find that dark energy imprints on the emitted gravitational radiation and on the changes in the orbital radius of the binary can be within detection limits for certain supermassive black hole binaries. In this talk I describe how binaries can provide a useful tool in obtaining complementary information on the nature of dark energy, based on the work done with A.Kelleher.

  8. Black Holes with Flavors of Quantum Hair?

    E-Print Network [OSTI]

    Gia Dvali

    2006-07-20T23:59:59.000Z

    We show that black holes can posses a long-range quantum hair of super-massive tensor fields, which can be detected by Aharonov-Bohm tabletop interference experiments, in which a quantum-hairy black hole, or a remnant particle, passes through the loop of a magnetic solenoid. The long distance effect does not decouple for an arbitrarily high mass of the hair-providing field. Because Kaluza-Klein and String theories contain infinite number of massive tensor fields, we study black holes with quantum Kaluza-Klein hair. We show that in five dimensions such a black hole can be interpreted as a string of `combed' generalized magnetic monopoles, with their fluxes confined along it. For the compactification on a translation-invariant circle, this substructure uncovers hidden flux conservation and quantization of the monopole charges, which constrain the quantum hair of the resulting four-dimensional black hole. For the spin-2 quantum hair this result is somewhat unexpected, since the constituent `magnetic' charges have no `electric' counterparts. Nevertheless, the information about their quantization is encoded in singularity.

  9. Evaluation of Critical Habitat for the California red-legged frog (Rana aurora draytonii)

    E-Print Network [OSTI]

    Allen, Michael F.; Tennant, Tracy

    2000-01-01T23:59:59.000Z

    With Comparisons to Rana Aurora and Rana Pretiosa. Copeia.M. Jennings. May 1996. Rana aurora- Red -legged Frog [WebRed- Legged Frog, Rana aurora, Tadpoles. Animal Behaviour

  10. adjustable red-green-blue led: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    or by combining green and red phosphors on a background consisting of a blue-light emitting diode (LED) or by employing nanocrystals (NCs) of the three primary colors (red,...

  11. Direct In Vivo Electrochemical Detection of Haemoglobin in Red Blood Cells

    E-Print Network [OSTI]

    Toh, Rou Jun

    The electrochemical behavior of iron ion in haemoglobin provides insight to the chemical activity in the red blood cell which is important in the field of hematology. Herein, the detection of haemoglobin in human red blood ...

  12. Aerosol effects on red blue ratio of clear sky images, and impact on solar forecasting

    E-Print Network [OSTI]

    Ghonima, Mohamed Sherif

    2011-01-01T23:59:59.000Z

    DIEGO Aerosol effects on Red Blue Ratio of Clear Sky Images,decision image (green: cloudy, blue: clear). The figure wasAerosol effects on Red Blue Ratio of Clear Sky Images, and

  13. Evaluation of various sulphur amino acid compounds in the diet of red drum, Sciaenops ocellatus

    E-Print Network [OSTI]

    Goff, Jonathan B

    2003-01-01T23:59:59.000Z

    Refinement of diet formulations to enhance the efficiency of red drum production continues to be pursued. Based on previous studies, the sulfur amino acid (SAA) requirement of red drum for methionine plus cystine appears to be most limiting, which...

  14. Effects of red imported fire ants on songbird nest survival

    E-Print Network [OSTI]

    Campomizzi, Andrew J.

    2009-05-15T23:59:59.000Z

    -successional stage woody vegetation similar to areas occupied by black-capped vireos in the nearby Lampasas Cut Plains (see Grzybowski et al. 1994, Bailey and Thompson 2007) and ecotones between mature oak-juniper (Quercus-Juniperus) woodland and grassland...

  15. Adaptive Tuning of RED Using On-line Simulation Tao Ye, Shivkumar Kalyanaraman

    E-Print Network [OSTI]

    Kalyanaraman, Shivkumar

    on the proposed RED optimization scheme, a general automatic network management system, i.e., on-line simulation

  16. Black Hole Chromosphere at the LHC

    E-Print Network [OSTI]

    Luis Anchordoqui; Haim Goldberg

    2003-02-26T23:59:59.000Z

    If the scale of quantum gravity is near a TeV, black holes will be copiously produced at the LHC. In this work we study the main properties of the light descendants of these black holes. We show that the emitted partons are closely spaced outside the horizon, and hence they do not fragment into hadrons in vacuum but more likely into a kind of quark-gluon plasma. Consequently, the thermal emission occurs far from the horizon, at a temperature characteristic of the QCD scale. We analyze the energy spectrum of the particles emerging from the "chromosphere", and find that the hard hadronic jets are almost entirely suppressed. They are replaced by an isotropic distribution of soft photons and hadrons, with hundreds of particles in the GeV range. This provides a new distinctive signature for black hole events at LHC.

  17. Neutrino Majorana Mass from Black Hole

    E-Print Network [OSTI]

    Yosuke Uehara

    2002-05-25T23:59:59.000Z

    We propose a new mechanism to generate the neutrino Majorana mass in TeV-scale gravity models. The black hole violates all non-gauged symmetries and can become the origin of lepton number violating processes. The fluctuation of higher-dimensional spacetime can result in the production of a black hole, which emits 2 neutrinos. If neutrinos are Majorana particles, this process is equivalent to the free propagation of a neutrino with the insertion of the black hole. From this fact, we derive the neutrino Majorana mass. The result is completely consistent with the recently observed evidence of neutrinoless double beta decay. And the obtained neutrino Majorana mass satisfies the constraint from the density of the neutrino dark matter, which affects the cosmic structure formation. Furthermore, we can explain the ultrahigh energy cosmic rays by the Z-burst scenario with it.

  18. Black Hole Thermodynamics in Modified Gravity

    E-Print Network [OSTI]

    Jonas R. Mureika; John W. Moffat; Mir Faizal

    2015-03-03T23:59:59.000Z

    We analyze the thermodynamics of a non-rotating and rotating black hole in a modified theory of gravity that includes scalar and vector modifications to general relativity, which results in a modified gravitational constant $G = G_N(1+\\alpha)$ and a new gravitational charge $Q = \\sqrt{\\alpha G_N}M$. The influence of the parameter $\\alpha$ alters the non-rotating black hole's lifetime, temperature and entropy profiles from the standard Schwarzschild case. The thermodynamics of a rotating black hole is analyzed and it is shown to possess stable, cold remnants. The thermodynamic properties of a vacuum solution regular at $r=0$ are investigated and the solution without a horizon called a "gray hole" is not expected to possess an information loss problem.

  19. Structure of the Spherical Black Hole Interior

    E-Print Network [OSTI]

    A. Bonanno; S. Droz; W. Israel; S. M. Morsink

    1994-11-18T23:59:59.000Z

    The internal structure of a charged spherical black hole is still a topic of debate. In a nonrotating but aspherical gravitational collapse to form a spherical charged black hole, the backscattered gravitational wave tails enter the black hole and are blueshifted at the Cauchy horizon. This has a catastrophic effect if combined with an outflux crossing the Cauchy horizon: a singularity develops at the Cauchy horizon and the effective mass inflates. Recently a numerical study of a massless scalar field in the \\RN background suggested that a spacelike singularity may form before the Cauchy horizon forms. We will show that there exists an approximate analytic solution of the scalar field equations which allows the mass inflation singularity at the Cauchy horizon to exist. In particular, we see no evidence that the Cauchy horizon is preceded by a spacelike singularity.

  20. Gravitational energy of rotating black holes

    E-Print Network [OSTI]

    J. W. Maluf; E. F. Martins; A. Kneip

    1996-08-21T23:59:59.000Z

    In the teleparallel equivalent of general relativity the energy density of asymptotically flat gravitational fields can be naturaly defined as a scalar density restricted to a three-dimensional spacelike hypersurface $\\Sigma$. Integration over the whole $\\Sigma$ yields the standard ADM energy. After establishing the reference space with zero gravitational energy we obtain the expression of the localized energy for a Kerr black hole. The expression of the energy inside a surface of constant radius can be explicitly calculated in the limit of small $a$, the specific angular momentum. Such expression turns out to be exactly the same as the one obtained by means of the method preposed recently by Brown and York. We also calculate the energy contained within the outer horizon of the black hole for {\\it any} value of $a$. The result is practically indistinguishable from $E=2M_{ir}$, where $M_{ir}$ is the irreducible mass of the black hole.

  1. "Red Sore Disease"in Game Fish1 Peggy Reed and Ruth Francis-Floyd2

    E-Print Network [OSTI]

    Watson, Craig A.

    VM85 "Red Sore Disease"in Game Fish1 Peggy Reed and Ruth Francis-Floyd2 1. This document is VM85 fish is generically referred to as "red sore disease." This problem usually occurs in the spring on their fish. Typically, "red sore disease" is caused by two organisms, Aeromonas hydrophila , a bacterium

  2. Understanding Blue-to-Red Conversion in Monomeric Fluorescent Timers and Hydrolytic Degradation of Their

    E-Print Network [OSTI]

    Verkhusha, Vladislav V.

    Understanding Blue-to-Red Conversion in Monomeric Fluorescent Timers and Hydrolytic Degradation-FT (chromophore Met66-Tyr67-Gly68) and its precursor with blocked blue-to- red conversion Blue102 (chromophore Leu data suggest that blue-to-red conversion, taking place in Fast-FT and in related FTs, is associated

  3. Constraints on origin and evolution of Red Sea brines from helium and argon isotopes

    E-Print Network [OSTI]

    Winckler, Gisela

    Constraints on origin and evolution of Red Sea brines from helium and argon isotopes Gisela November 2000 Abstract Brines from three depressions along the axis of the Red Sea, the Atlantis II II and the Discovery brines originating from locations in the central Red Sea show 4 He

  4. Red Algae Lose Key Mitochondrial Genes in Response to Becoming Parasitic

    E-Print Network [OSTI]

    Lane, Chris

    Red Algae Lose Key Mitochondrial Genes in Response to Becoming Parasitic Lillian Hancock1 , Lynda independently evolved hundreds of times among the floridiophyte red algae. Much is known about the life history class of red algae, Plocamiocolax puvinata, has lost the atp8 gene entirely, indicating that this gene

  5. Evolutionary Ecology, 1987, 1, 59-94 Red Queens and ESS

    E-Print Network [OSTI]

    Brown, Joel S.

    Evolutionary Ecology, 1987, 1, 59-94 Red Queens and ESS: the coevolution of evolutionary rates coevolutionary rates of zero is that of evolutio- narily stable strategies (ESS). Red Queen assumes that the more of such a phenotypic trait value. Such traits are the key to the Red Queen prediction of progressive coevolution. ESS

  6. Modeling Red Blood Cell and Iron Dynamics in Patients with Chronic Kidney Disease

    E-Print Network [OSTI]

    Modeling Red Blood Cell and Iron Dynamics in Patients with Chronic Kidney Disease H. T. Banks1, that stimulates red blood cell (RBC) production. Without intervention, patients suffer from anemia. Patients treatment. Keywords: mathematical model, mathematical biology, erythropoiesis, erythrocyte, red blood cell

  7. Modeling Red Blood Cell and Iron Dynamics in Patients Undergoing Periodic EPO and Iron Treatments

    E-Print Network [OSTI]

    Modeling Red Blood Cell and Iron Dynamics in Patients Undergoing Periodic EPO and Iron Treatments H in the kidneys, that stimulates red blood cell (RBC) production. Without intervention, patients suffer from, erythrocyte, red blood cell, chronic kidney disease, dialysis, iron, neocytolysis, hepcidin, EPO, hemoglobin e

  8. Dynamics of galaxy cores and supermassive black holes

    E-Print Network [OSTI]

    David Merritt

    2006-05-02T23:59:59.000Z

    Recent work on the dynamical evolution of galactic nuclei containing supermassive black holes is reviewed. Topics include galaxy structural properties; collisionless and collisional equilibria; loss-cone dynamics; and dynamics of binary and multiple supermassive black holes.

  9. Legendary Tuskegee Airmen to Speak at Jefferson Lab's Black History...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab's Black History Month Event February 3, 2004 Three members of the legendary, World War II era Tuskegee Airmen will speak at Jefferson Lab's Black History Month celebration at...

  10. acid based black: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    industrially by liquid 19 Black-Box Identification for PLC based MPC of a Binary Distillation Column Engineering Websites Summary: Black-Box Identification for PLC based MPC of...

  11. automobile black boxes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Toon van Leus, Geert 87 Black-Box Identification for PLC based MPC of a Binary Distillation Column Engineering Websites Summary: Black-Box Identification for PLC based MPC of...

  12. administration black box: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Toon van Leus, Geert 88 Black-Box Identification for PLC based MPC of a Binary Distillation Column Engineering Websites Summary: Black-Box Identification for PLC based MPC of...

  13. accuracy binary black: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P. Uttley 2005-08-02 354 Black-Box Identification for PLC based MPC of a Binary Distillation Column Engineering Websites Summary: Black-Box Identification for PLC based MPC of...

  14. The Development of the Emerald Programming Language Andrew P. Black

    E-Print Network [OSTI]

    Black, Andrew P.

    The Development of the Emerald Programming Language Andrew P. Black Portland State University black additional code to invoke a remote ob- ject compared to a local object. Instead, all binding, mar- shaling

  15. Topological black holes in Horava-Lifshitz gravity

    SciTech Connect (OSTI)

    Cai Ronggen [Key Laboratory of Frontiers in Theoretical Physics, Institute of Theoretical Physics, Chinese Academy of Sciences, P.O. Box 2735, Beijing 100190 (China) and Kavli Institute for Theoretical Physics China (KITPC), Chinese Academy of Sciences, P.O. Box 2735, Beijing 100190 (China); Cao Liming [Asia Pacific Center for Theoretical Physics, Pohang, Gyeongbuk 790-784 (Korea, Republic of); Ohta, Nobuyoshi [Department of Physics, Kinki University, Higashi-Osaka, Osaka 577-8502 (Japan)

    2009-07-15T23:59:59.000Z

    We find topological (charged) black holes whose horizon has an arbitrary constant scalar curvature 2k in Horava-Lifshitz theory. Without loss of generality, one may take k=1, 0, and -1. The black hole solution is asymptotically anti-de Sitter with a nonstandard asymptotic behavior. Using the Hamiltonian approach, we define a finite mass associated with the solution. We discuss the thermodynamics of the topological black holes and find that the black hole entropy has a logarithmic term in addition to an area term. We find a duality in Hawking temperature between topological black holes in Horava-Lifshitz theory and Einstein's general relativity: the temperature behaviors of black holes with k=1, 0, and -1 in Horava-Lifshitz theory are, respectively, dual to those of topological black holes with k=-1, 0, and 1 in Einstein's general relativity. The topological black holes in Horava-Lifshitz theory are thermodynamically stable.

  16. Black Hills Energy (Gas)- Residential Energy Efficiency Rebate Programs

    Broader source: Energy.gov [DOE]

    Black Hills Energy offers its residential Iowa customers incentives to encourage energy efficiency in their homes. Black Hills Energy offers a free home energy evaluation to customers (both owners...

  17. Vacuum polarization for lukewarm black holes

    E-Print Network [OSTI]

    Elizabeth Winstanley; Phil M. Young

    2007-12-20T23:59:59.000Z

    We compute the renormalized expectation value of the square of a quantum scalar field on a Reissner-Nordstrom-de Sitter black hole in which the temperatures of the event and cosmological horizons are equal (`lukewarm' black hole). Our numerical calculations for a thermal state at the same temperature as the two horizons indicate that this renormalized expectation value is regular on both the event and cosmological horizons. We are able to show analytically, using an approximation for the field modes near the horizons, that this is indeed the case.

  18. Vacuum polarization for lukewarm black holes

    SciTech Connect (OSTI)

    Winstanley, Elizabeth; Young, Phil M. [Department of Applied Mathematics, The University of Sheffield, Hicks Building, Hounsfield Road, Sheffield, S3 7RH (United Kingdom)

    2008-01-15T23:59:59.000Z

    We compute the renormalized expectation value of the square of a quantum scalar field on a Reissner-Nordstroem-de Sitter black hole in which the temperatures of the event and cosmological horizons are equal ('lukewarm' black hole). Our numerical calculations for a thermal state at the same temperature as the two horizons indicate that this renormalized expectation value is regular on both the event and cosmological horizons. We are able to show analytically, using an approximation for the field modes near the horizons, that this is indeed the case.

  19. Tachyon Perturbation on Two Dimensional Black Hole

    E-Print Network [OSTI]

    Aniket Basu

    2014-07-03T23:59:59.000Z

    We study the black hole geometry in the presence of tachyonic perturbations, and solve for the form of allowed tachyonic hair in the presence of back reaction, and for the form of the metric under the assumption that only the metric is perturbed but not the dilaton. We evaluate the Kretschmann scalar and argue that the horizon becomes singular in the presence of tachyons, implying that the black hole has turned into a naked singularity. A form of the allowed tachyon potential emerges as a requirement of self-consistency of our solution.

  20. Thermal Gravitational Waves from Primordial Black Holes

    E-Print Network [OSTI]

    C. Sivaram; Kenath Arun

    2010-05-19T23:59:59.000Z

    Thermal gravitational waves can be generated in various sources such as, in the cores of stars, white dwarfs and neutron stars due to the fermion collisions in the dense degenerate Fermi gas. Such high frequency thermal gravitational waves can also be produced during the collisions in a gamma ray burst or during the final stages of the evaporation of primordial black holes. Here we estimate the thermal gravitational waves from primordial black holes and estimate the integrated energy of the gravitational wave emission over the entire volume of the universe and over Hubble time. We also estimate the gravitational wave flux from gamma ray bursts and jets.