National Library of Energy BETA

Sample records for bituminous coal lig

  1. Assessment of underground coal gasification in bituminous coals: catalog of bituminous coals and site selection. Appendix A. National coal resource data system: Ecoal, Wcoal, and Bmalyt. Final report, Phase I. [Bituminous coal; by state; coal seam depth and thickness; identification

    SciTech Connect (OSTI)

    1982-01-31

    Appendix A is a catalog of the bituminous coal in 29 states of the contiguous United States which contain identified bituminous coal resources.

  2. Liquefaction of sub-bituminous coal

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1986-01-01

    Sub-bituminous coal is directly liquefied in two stages by use of a liquefaction solvent containing insoluble material as well as 850.degree. F.+ material and 850.degree. F.- material derived from the second stage, and controlled temperature and conversion in the second stage. The process is in hydrogen balance.

  3. THE EFFECTS OF SOLVENTS ON SUB-BITUMINOUS COAL BELOW ITS PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Grens III., Edward A.

    2013-01-01

    BITUMINOUS COAL BELOW ITS PYROLYSIS TEMPERATURE Edward A.BITUMINOUS COAL BELOW ITS PYROLYSIS TEMPERATURE Edward A.the effects of coal pyrolysis to be noted (the initial

  4. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    Homogeneous Catalytic Hydrocracking Processes for ConversionPag~ Table I Direct Hydrocracking of a Bituminous Coal withMild Conditions Direct Hydrocracking of Bituminous and Sub-

  5. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  6. Investigation of plasma-aided bituminous coal gasification

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (United States)

    2009-04-15

    This paper presents thermodynamic and kinetic modeling of plasma-aided bituminous coal gasification. Distributions of concentrations, temperatures, and velocities of the gasification products along the gasifier are calculated. Carbon gasification degree, specific power consumptions, and heat engineering characteristics of synthesis gas at the outlet of the gasifier are determined at plasma air/steam and oxygen/steam gasification of Powder River Basin bituminous coal. Numerical simulation showed that the plasma oxygen/steam gasification of coal is a more preferable process in comparison with the plasma air/steam coal gasification. On the numerical experiments, a plasma vortex fuel reformer is designed.

  7. Keystone Bituminous Coal v. DeBenedictis: When Regulation Becomes a Taking

    E-Print Network [OSTI]

    Davies, Anne C.

    1988-01-01

    CONsr. amend. V. See also Keystone Bituminous Coal Ass'n v.11. Id. at 479-480. 12. Keystone Bituminous Coal Ass'n v.Cir. 1985), aff'd sub nom. Keystone Bituminous Coal Ass'n v.

  8. Investigation of the combustion characteristics of Zonguldak bituminous coal using DTA and DTG

    SciTech Connect (OSTI)

    Haykiri-Acma, H.; Yaman, S.; Kucukbayrak, S.; Okutan, H. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

    2006-06-21

    Combustion characteristics of coking, semicoking, and noncoking Turkish bituminous coal samples from Zonguldak basin were investigated applying differential thermal analysis (DTA) and differential thermogravimetry (DTG) techniques. Results were compared with that of the coke from Zonguldak bituminous coal, a Turkish lignite sample from Soma, and a Siberian bituminous coal sample. The thermal data from both techniques showed some differences depending on the proximate analyses of the samples. Noncombustible components of the volatile matter led to important changes in thermal behavior. The data front both methods were, evaluated jointly, and some thermal properties were interpreted considering these methods in a complementary combination.

  9. JV Task 126 - Mercury Control Technologies for Electric Utilities Burning Bituminous Coal

    SciTech Connect (OSTI)

    Jason Laumb; John Kay; Michael Jones; Brandon Pavlish; Nicholas Lentz; Donald McCollor; Kevin Galbreath

    2009-03-29

    The EERC developed an applied research consortium project to test cost-effective mercury (Hg) control technologies for utilities burning bituminous coals. The project goal was to test innovative Hg control technologies that have the potential to reduce Hg emissions from bituminous coal-fired power plants by {ge}90% at costs of one-half to three-quarters of current estimates for activated carbon injection (ACI). Hg control technology evaluations were performed using the EERC's combustion test facility (CTF). The CTF was fired on pulverized bituminous coals at 550,000 Btu/hr (580 MJ/hr). The CTF was configured with the following air pollution control devices (APCDs): selective catalytic reduction (SCR) unit, electrostatic precipitator (ESP), and wet flue gas desulfurization system (WFDS). The Hg control technologies investigated as part of this project included ACI (three Norit Americas, Inc., and eleven Envergex sorbents), elemental mercury (Hg{sup 0}) oxidation catalysts (i.e., the noble metals in Hitachi Zosen, Cormetech, and Hitachi SCR catalysts), sorbent enhancement additives (SEAs) (a proprietary EERC additive, trona, and limestone), and blending with a Powder River Basin (PRB) subbituminous coal. These Hg control technologies were evaluated separately, and many were also tested in combination.

  10. Linkages and aromatic clusters in a bituminous coal: Final report, September 1, 1985--September 30, 1988

    SciTech Connect (OSTI)

    Chung, K.E.

    1988-10-01

    The distribution and arrangement of aromatic clusters, oxygen functional groups, and linkages in an Illinois No. 6 bituminous coal were determined by controlled solubilization of the coal, followed by solvent fractionation of the soluble product and detailed analyses of the product fractions. The solubilization was carried out in reactions with NaOH/ethanol/H/sub 2/O at temperatures of 260/degree/, 300/degree/ and 320/degree/C. Elemental balance and spectroscopic data revealed that the oxygen functional groups of the coal were attacked selectively in the solubilization process, resulting in an orderly definable diminution of the complex coal structure. Also aliphatic linkages present in selected solubilized product fractions were subjected to a transalkylation reaction. A molecular structural model specific to the Illinois coal was constructed, and the hydroliquefaction behavior of the coal was evaluated in terms of potential product distribution and hydrogen consumption. The structural characteristics are compared with those of a Wyoming subbituminous coal in our previous study. 9 refs., 16 figs., 11 tabs.

  11. Stability of the bituminous coal microstructure upon exposure to high pressures of helium

    SciTech Connect (OSTI)

    Richard Sakurovs; Andrzej P. Radliski; Yuri B. Melnichenko; Tomas Blach; Gang Cheng; Hartmut Lemmel; Helmut Rauch [CSIRO Energy Technology, Newcastle, NSW (Australia)

    2009-09-15

    Small-angle neutron scattering (SANS) and ultra-small-angle neutron scattering (USANS) measurements of the structure of two Australian bituminous coals (particle size of 1-0.5 mm) before, during, and after exposure to 155 bar of helium were made to identify any effects of pressure alone on the pore size distribution of coal and any irreversible effects upon exposure to high pressures of helium in the pore size range from 3 nm to 10 {mu}m. No irreversible effects upon exposure were identified for any pore size. No effects of pressure on pore size distribution were observed, except for a small effect at a pore size of about 2 {mu}m for one coal. This study provides a convenient baseline for SANS and USANS investigations on sorption of gases at elevated pressures on coals, by distinguishing between the effect of pressure alone on coal pore size distribution and against the effect of the gas to be investigated. 35 refs., 5 figs., 1 tab.

  12. Pore size distribution and accessible pore size distribution in bituminous coals

    SciTech Connect (OSTI)

    Sakurovs, Richard [ORNL; He, Lilin [ORNL; Melnichenko, Yuri B [ORNL; Radlinski, Andrzej Pawell [ORNL; Blach, Tomasz P [ORNL

    2012-01-01

    The porosity and pore size distribution of coals determine many of their properties, from gas release to their behavior on carbonization, and yet most methods of determining pore size distribution can only examine a restricted size range. Even then, only accessible pores can be investigated with these methods. Small-angle neutron scattering (SANS) and ultra small-angle neutron scattering (USANS) are increasingly used to characterize the size distribution of all of the pores non-destructively. Here we have used USANS/SANS to examine 24 well-characterized bituminous and subbituminous coals: three from the eastern US, two from Poland, one from New Zealand and the rest from the Sydney and Bowen Basins in Eastern Australia, and determined the relationships of the scattering intensity corresponding to different pore sizes with other coal properties. The range of pore radii examinable with these techniques is 2.5 nm to 7 {micro}m. We confirm that there is a wide range of pore sizes in coal. The pore size distribution was found to be strongly affected by both rank and type (expressed as either hydrogen or vitrinite content) in the size range 250 nm to 7 {micro}m and 5 to 10 nm, but weakly in intermediate regions. The results suggest that different mechanisms control coal porosity on different scales. Contrast-matching USANS and SANS were also used to determine the size distribution of the fraction of the pores in these coals that are inaccessible to deuterated methane, CD{sub 4}, at ambient temperature. In some coals most of the small ({approx} 10 nm) pores were found to be inaccessible to CD{sub 4} on the time scale of the measurement ({approx} 30 min - 16 h). This inaccessibility suggests that in these coals a considerable fraction of inherent methane may be trapped for extended periods of time, thus reducing the effectiveness of methane release from (or sorption by) these coals. Although the number of small pores was less in higher rank coals, the fraction of total pores that was inaccessible was not rank dependent. In the Australian coals, at the 10 nm to 50 nm size scales the pores in inertinites appeared to be completely accessible to CD{sub 4}, whereas the pores in the vitrinite were about 75% inaccessible. Unlike the results for total porosity that showed no regional effects on relationships between porosity and coal properties, clear regional differences in the relationships between fraction of closed porosity and coal properties were found. The 10 to 50 nm-sized pores of inertinites of the US and Polish coals examined appeared less accessible to methane than those of the inertinites of Australian coals. This difference in pore accessibility in inertinites may explain why empirical relationships between fluidity and coking properties developed using Carboniferous coals do not apply to Australian coals.

  13. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    or gaseous fuels, coal gasification has advanced furthestrapidly. While coal gasification may reach commercializa-5272 (1976). COal Processing - Gasification, Liguefaction,

  14. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    July 22, 1974. Project Western Coal: Conversion of Coal Intoand Gasification of Western Coals", in proceedings of ERDA/Investigators' Conference - Coal Research, Colorado School

  15. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    Coal: Conversion of Coal Into Liquids - Final Report,for Conversion of Coal to Liquid Fuels, 'Stanford ResearchConversion of Coal to Liquids--Research Opportunities", in

  16. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    SciTech Connect (OSTI)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates Units 1 and 2 to evaluate the performance of low-cost activated carbon sorbents for removing mercury. In addition, the effects of the dual flue gas conditioning system on mercury removal performance were evaluated as part of short-term parametric tests on Unit 2. Based on the parametric test results, a single sorbent (e.g., RWE Super HOK) was selected for a 30-day continuous injection test on Unit 1 to observe long-term performance of the sorbent as well as its effects on ESP and FGD system operations as well as combustion byproduct properties. A series of parametric tests were also performed on Shawville Unit 3 over a three-week period in which several activated carbon sorbents were injected into the flue gas duct just upstream of either of the two Unit 3 ESP units. Three different sorbents were evaluated in the parametric test program for the combined ESP 1/ESP 2 system in which sorbents were injected upstream of ESP 1: RWE Super HOK, Norit's DARCO Hg, and a 62:38 wt% hydrated lime/DARCO Hg premixed reagent. Five different sorbents were evaluated for the ESP 2 system in which activated carbons were injected upstream of ESP 2: RWE Super HOK and coarse-ground HOK, Norit's DARCO Hg and DARCO Hg-LH, and DARCO Hg with lime injection upstream of ESP 1. The hydrated lime tests were conducted to reduce SO3 levels in an attempt to enhance the mercury removal performance of the activated carbon sorbents. The Plant Yates and Shawville studies provided data required for assessing carbon performance and long-term operational impacts for flue gas mercury control across small-sized ESPs, as well as for estimating the costs of full-scale sorbent injection processes.

  17. HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS

    E-Print Network [OSTI]

    Holten, R.R.

    2010-01-01

    for Liquefaction and Gasification of Western Coals", in5272 (1976). COal Processing - Gasification, Liguefaction,or gaseous fuels, coal gasification has advanced furthest

  18. INTERACTION OF A SUB-BITUMINOUS COAL WITH A STRONG ACID AND A STRONG BASE

    E-Print Network [OSTI]

    Seth, M.

    2010-01-01

    I.D I.D XBL 7111- 11389 g. s urn coal iurn REfERENCES 1. W.H. Wiser, Coal Catalysis, Proceedings of the EPRIC. Howard. Chern; (John Wil of Coal Utilization H. H. lowry.

  19. INTERACTION OF A SUB-BITUMINOUS COAL WITH A STRONG ACID AND A STRONG BASE

    E-Print Network [OSTI]

    Seth, M.

    2010-01-01

    reactor containing solid coal, liquid organics, and melt. "use in converting coal to liquid or purified To begin9 thefor obtaining liquid products from coal which has been used

  20. INTERACTION OF A SUB-BITUMINOUS COAL WITH A STRONG ACID AND A STRONG BASE

    E-Print Network [OSTI]

    Seth, M.

    2010-01-01

    t properties of the sodium hydroxide~treated coal with thoseproperties, discussed later, which may make them effective for coalproperties the on Behavior. phosphoric-acid-treated coal,

  1. Solvent extraction of bituminous coals using light cycle oil: characterization of diaromatic products in liquids

    SciTech Connect (OSTI)

    Josefa M. Griffith; Caroline E. Burgess Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States). EMS Energy Institute

    2009-09-15

    Many studies of the pyrolytic degradation of coal-derived and petroleum-derived aviation fuels have demonstrated that the coal-derived fuels show better thermal stability, both with respect to deposition of carbonaceous solids and cracking to gases. Much previous work at our institute has focused on the use of refined chemical oil (RCO), a distillate from the refining of coal tar, blended with light cycle oil (LCO) from catalytic cracking of vacuum gas oil. Hydroprocessing of this blend forms high concentrations of tetralin and decalin derivatives that confer particularly good thermal stability on the fuel. However, possible supply constraints for RCO make it important to consider alternative ways to produce an 'RCO-like' product from coal in an inexpensive process. This study shows the results of coal extraction using LCO as a solvent. At 350{sup o}C at a solvent-to-coal ratio of 10:1, the conversions were 30-50 wt % and extract yields 28-40 wt % when testing five different coals. When using lower LCO/coal ratios, conversions and extract yields were much smaller; lower LCO/coal ratios also caused mechanical issues. LCO is thought to behave similarly to a nonpolar, non-hydrogen donor solvent, which would facilitate heat-induced structural relaxation of the coal followed by solubilization. The main components contributed from the coal to the extract when using Pittsburgh coal are di- and triaromatic compounds. 41 refs., 3 figs., 12 tabs.

  2. Predictors of plasticity in bituminous coals. Technical progress report No. 2, March 1, 1982

    SciTech Connect (OSTI)

    Lloyd, W. G.; Reasoner, J. W.; Hower, J. C.; Yates, L. P.; Clark, C. P.; Jones, T. M.; Sturgeon, L. P.; Whitt, J. M.

    1982-03-01

    The approach of this study is to secure three dozen (or more) coals of varying rank, composition and plasticity, and to analyze these coals carefully by standard chemical and petrographic techniques. The bitumen fractions will be determined, both by THF (asphaltenes but not preasphaltenes) and DMF (everything). Pyrolysis gas chromatography on both whole coals and extracted residues will compare capacities to generate metaplast. Extracts from coals with plasticities differing by at least four orders of magnitude will be examined for identifiable differences; extraction residues will be subjected to differential FTIR analysis. All of the data will be combined and subjected to systematic statistical analysis with the objective of identifying predictors of coal plasticity. This report describes the work in the first six months of the study. During this period equipment and instrumentation has been obtained, 24 coal samples have been obtained, the nonclassical methods have been developed and checked out, and an appreciable amount of experimentl data has been obtained.

  3. INTERACTION OF A SUB-BITUMINOUS COAL WITH A STRONG ACID AND A STRONG BASE

    E-Print Network [OSTI]

    Seth, M.

    2010-01-01

    the coal by action of the melts, increasing the recovery ofcoal with an organic solvent (or mixture of solvents), solvent recovery,

  4. THE EFFECTS OF SOLVENTS ON SUB-BITUMINOUS COAL BELOW ITS PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Grens III., Edward A.

    2013-01-01

    the coal, this indicates that local continuum properties ofcoal as rapidly Duplication of pure-solvent experiments in both types of equipment gave satisfactory agreement in yields and properties

  5. Development and evaluation of an automated reflectance microscope system for the petrographic characterization of bituminous coals

    SciTech Connect (OSTI)

    Hoover, D. S.; Davis, A.

    1980-10-01

    The development of automated coal petrographic techniques will lessen the demands on skilled personnel to do routine work. This project is concerned with the development and successful testing of an instrument which will meet these needs. The fundamental differences in reflectance of the three primary maceral groups should enable their differentiation in an automated-reflectance frequency histogram (reflectogram). Consequently, reflected light photometry was chosen as the method for automating coal petrographic analysis. Three generations of an automated system (called Rapid Scan Versions I, II and III) were developed and evaluated for petrographic analysis. Their basic design was that of a reflected-light microscope photometer with an automatic stage, interfaced with a minicomputer. The hardware elements used in the Rapid Scan Version I limited the system's flexibility and presented problems with signal digitization and measurement precision. Rapid Scan Version II was designed to incorporate a new microscope photometer and computer system. A digital stepping stage was incorporated into the Rapid Scan Version III system. The precision of reflectance determination of this system was found to be +- 0.02 percent reflectance. The limiting factor in quantitative interpretation of Rapid Scan reflectograms is the resolution of reflectance populations of the individual maceral groups. Statistical testing indicated that reflectograms were highly reproducible, and a new computer program, PETAN, was written to interpret the curves for vitrinite reflectance parameters ad petrographic.

  6. Evaluation of Control Strategies to Effectively Meet 70-90% Mercury Reduction on an Eastern Bituminous Coal Cyclone Boiler with SCR

    SciTech Connect (OSTI)

    Tom Campbell

    2008-12-31

    This is the final site report for testing conducted at Public Service of New Hampshire's (PSNH) Merrimack Unit 2 (MK2). This project was funded through the DOE/NETL Innovations for Existing Plants program. It was a Phase III project with the goal to develop mercury control technologies that can achieve 50-70% mercury capture at costs 25-50% less than baseline estimates of $50,000-$70,000/lb of mercury removed. While results from testing at Merrimack indicate that the DOE goal was partially achieved, further improvements in the process are recommended. Merrimack burned a test blend of eastern bituminous and Venezuelan coals, for a target coal sulfur content of 1.2%, in its 335-MW Unit 2. The blend ratio is approximately a 50/50 split between the two coals. Various sorbent injection tests were conducted on the flue gas stream either in front of the air preheater (APH) or in between the two in-series ESPs. Initial mercury control evaluations indicated that, without SO3 control, the sorbent concentration required to achieve 50% control would not be feasible, either economically or within constraints specific to the maximum reasonable particle loading to the ESP. Subsequently, with SO{sub 3} control via trona injection upstream of the APH, economically feasible mercury removal rates could be achieved with PAC injection, excepting balance-of-plant concerns. The results are summarized along with the impacts of the dual injection process on the air heater, ESP operation, and particulate emissions.

  7. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect (OSTI)

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

    2009-05-15

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  8. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    a particular type of coal, each of which is inherentlyThere are four classes of coal: bituminous, sub-bituminous,minerals Metallic ores Coal Crude petroleum Gasoline Fuel

  9. HYDROGENATION AND CRACKING OF COAL RELATED FUSED-RING STRUCTURES USING ZnCl2 AND AlCl3 CATALYSTS

    E-Print Network [OSTI]

    Salim, Sadie S.

    2013-01-01

    Conversion of coal to petroleum type products, which haveof coal depends on the type of coal studied, the ratio ofbenzene type structures are present in bituminous coal (32).

  10. THE CHEMISTRY OF COAL MODEL COMPOUNDS -CLEAVAGE OF ALIPHATIC BRIDGES BETWEEN AROMATIC NUCLEI CATALYSED BY LEWIS ACIDS

    E-Print Network [OSTI]

    Taylor, Newell D.

    2011-01-01

    and Background I. II. III. IV. II. Coal Liquefaction . •Coal Structure • • . Lewis Acid Catalysts. Scope andOrganic Structure of Bituminous Coal", Proceedings, Stanford

  11. ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL

    E-Print Network [OSTI]

    Mobley, David Paul

    2013-01-01

    H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,Internat. Conf. Bituminous Coal, 3d ConŁ. , 2, 35 (1932);

  12. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    cycle gas turbine power plant carbon capture and storagewind hybrid combined cycle power plant natural gas combinedPower Plants study, Volume 1: Bituminous Coal and Natural Gas

  13. (Basic properties of coals and other solids)

    SciTech Connect (OSTI)

    Not Available

    1991-11-25

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number sign}8, Illinois {number sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  14. INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Dorighi, G.P.

    2010-01-01

    and P. Fugassi, Phenanthrene Extraction of Bituminous Coal,Coal Science, Advances in Chemistry Series No. 55, 448 C.Mechanism of High Volatile Coal, Coal Science, Advances in

  15. Coal is a combustible sedimentary rock and a valuable economic resource. During the Pennsylvanian Period

    E-Print Network [OSTI]

    Polly, David

    Coal is a combustible sedimentary rock and a valuable economic resource. During the Pennsylvanian of years produced the bituminous coals currently found in southwestern Indiana. Bituminous coals in Indiana currently ranks as the seventh-largest coal-producing state in the nation and has an estimated 17.57 billion

  16. Coal Production 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  17. INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Dorighi, G.P.

    2010-01-01

    Utah bituminous coal resulting from Soxhlet- type extractionThe extension of this type of study to coals of lower rank,base type solvent in dissolving subbituminous coal below the

  18. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect (OSTI)

    Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

    2009-07-01

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  19. [Basic properties of coals and other solids]. Eighth quarterly report, [September--November 1991

    SciTech Connect (OSTI)

    Not Available

    1991-11-25

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number_sign}8, Illinois {number_sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  20. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  1. CO{sub 2} Sequestration Potential of Charqueadas Coal Field in Brazil

    SciTech Connect (OSTI)

    Romanov, V

    2012-10-23

    The I2B coal seam in the Charqueadas coal field has been evaluated as a target for enhanced coal bed methane production and CO{sub 2} sequestration. The samples were low rank coals (high volatile bituminous and sub-bituminous) obtained from the I2B seam as ?3? cores. Such properties as sorption capacity, internal structure of the samples, porosity and permeability were of primary interest in this characterization study.

  2. MTCI advanced coal technologies

    SciTech Connect (OSTI)

    Mansour, M.N.; Chandran, R.R. [Manufacturing and Technology Conversion International, Inc., Columbia, MD (United States)

    1994-12-31

    MTCI is pursuing the development and commercialization of several advanced combustion and gasification systems based on pulse combustion technology. The systems include indirectly heated thermochemical reactor, atmospheric pressure pulse combustor, pulsed atmospheric fluidized bed combustor, direct coal-fired gas turbine pulse combustor island, and advanced concept second-generation pressurized fluidized bed combustor island. Although the systems in toto are capable of processing lignite, subbituminous, bituminous, and anthracite coals in an efficient, economical and environmentally acceptable manner, each system is considered ideal for certain coal types. Brief descriptions of the systems, applications, selected test results and technology status are presented.

  3. Erroneous coal maturity assessment caused by low temperature oxidation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Erroneous coal maturity assessment caused by low temperature oxidation Y. Copard J. R. Disnar, J. F on different outcrop coals from the French Massif Central revealed abnormally high Tmax values, which initially observed for medium to low volatile bituminous coals (Rr1.5%), was accompanied by a very clear exponential

  4. The leaching characteristics of selenium from coal fly ashes

    SciTech Connect (OSTI)

    Wang, T.; Wang, J.; Burken, J.G.; Ban, H.; Ladwig, K.

    2007-11-15

    The leaching characteristics of selenium from several bituminous and subbituminous coal fly ashes under different pH conditions were investigated using batch methods. Results indicated that pH had a significant effect on selenium leaching from bituminous coal ash. The minimum selenium leaching occurred in the pH range between 3 and 4, while the maximum selenium leaching occurred at pH 12. The release of selenium from subbituminous coal ashes was very low for the entire experimental pH range, possibly due to the high content of calcium which can form hydration or precipitation products as a sink for selenium. The adsorption results for different selenium species indicated that Se(VI) was hardly adsorbable on either bituminous coal ashes or subbitumminous coal ashes at any pH. However, Se(I) was highly adsorbed by bituminous coal ashes under acidic pH conditions and was mostly removed by subbitumminous coal ashes across the entire pH range. This result suggests that the majority of selenium released from the tested fly ashes was Se(IV). A speciation-based model was developed to simulate the adsorption of Se(IV) on bituminous coal fly ash, and the pH-independent adsorption constants of HSeO{sup 3-} and SeO{sub 3}{sup 2-} were determined. The modeling approach is useful for understanding and predicting the release process of selenium from fly ash.

  5. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  6. Leaching characteristics of arsenic and selenium from coal fly ash: role of calcium

    SciTech Connect (OSTI)

    Tian Wang; Jianmin Wang; Yulin Tang; Honglan Shi; Ken Ladwig

    2009-05-15

    Understanding the leaching behavior of arsenic (As) and selenium (Se) in coal fly ash is important in evaluating the potential environmental impact of coal fly ash. Batch experiments were employed to systematically investigate the leaching behavior of As and Se in two major types of coal fly ashes, bituminous coal ash and sub-bituminous coal ash, and to determine the underlying processes that control As and Se leaching. The effects of pH, solid/liquid (S/L) ratio, calcium addition, and leaching time on the release of As and Se were studied. Overall, bituminous coal ash leached significantly more As and Se than sub-bituminous coal ash, and Se was more readily leachable, in both absolute concentration and relative fraction, than As for both types of fly ashes. Adsorption/desorption played a major role on As and Se leaching from bituminous coal ashes. However, calcium precipitation played the most important role in reducing As and Se leaching from sub-bituminous coal ashes in the entire experimental pH range. The leaching of As and Se from bituminous coal ashes generally increased with increases in the S/L ratio and leaching time. However, for sub-bituminous coal ashes, the leaching of As was not detected under most experimental conditions, while the leaching of Se increased with increases in the S/L ratio and leaching time. As{sup V} and Se{sup IV} were found to be the major species in all ash leachates in this study. 46 refs., 7 figs., 1 tab.

  7. Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base Gregory D. Croft1 and Tad W the multi-Hubbert curve analysis to coal production in the United States, we demonstrate that anthracite production of this highest-rank coal. The pro- duction of bituminous coal from existing mines is about 80

  8. PREVENTTVE FACILITIES AND EMERGENCY OPERATIONS IN CASE OFFIRES IN CdF COAL MINES

    E-Print Network [OSTI]

    Boyer, Edmond

    ). The upper group consists of a bituminous soft coal, the lower coke coal. The field is sharply folded alongPREVENTTVE FACILITIES AND EMERGENCY OPERATIONS IN CASE OFFIRES IN CdF COAL MINES J.P. AMARTIN HJSJL a stricl methodology. It has been possjble then to resume coal winning, which has cor.tmued until

  9. Recent two-stage coal liquefaction results from Wilsonville, Alabama

    SciTech Connect (OSTI)

    Rao, A.K.; Udani, L.H.; Nalitham, R.V.

    1985-01-01

    This paper presents results from two recent runs conducted at the Advanced Coal Liquefaction R and D facility of Wilsonville, Alabama. The first run was an extended demonstration of sub-bituminous coal liquefaction using an integrated two-stage liquefaction (ITSL) process. The second run employed a bituminous coal in a reconfigured two-stage process (RITLS) wherein the undeashed products from the first stage were hydrotreated prior to separation of coal ash. Good operability and satisfactory yield structure were demonstrated in both the runs.

  10. Apparatus for entrained coal pyrolysis

    DOE Patents [OSTI]

    Durai-Swamy, Kandaswamy (Culver City, CA)

    1982-11-16

    This invention discloses a process and apparatus for pyrolyzing particulate coal by heating with a particulate solid heating media in a transport reactor. The invention tends to dampen fluctuations in the flow of heating media upstream of the pyrolysis zone, and by so doing forms a substantially continuous and substantially uniform annular column of heating media flowing downwardly along the inside diameter of the reactor. The invention is particularly useful for bituminous or agglomerative type coals.

  11. Vacuum pyrolyzed tire oil as a coal solvent

    SciTech Connect (OSTI)

    Orr, E.C.; Shi, Y.; Ji, Q.

    1995-12-31

    Coal liquefaction is highly dependent upon the type of coal liquefaction solvent used. The solvent must readily solubilize the coal and must act as an effective hydrogen donor or shuttler. Oil derived from the vacuum pyrolysis of used rubber tires has recently been used as a coal solvent with good conversion of coal to liquids in a hydrogen atmosphere. All experiments were completed in shaken tubing reactors at 450{degrees}C utilizing a bituminous coal. Results show the effectiveness of the pyrolyzed tire oil as a coal liquefaction solvent depends upon hydrogen pressure. Electron probe microanalysis data reveal good dispersion of the molybdenum catalyst in coal particles taken from liquefaction experiments.

  12. NOx, SOx & CO{sub 2} mitigation using blended coals

    SciTech Connect (OSTI)

    Labbe, D.

    2009-11-15

    Estimates of potential CO{sub 2} reduction achievable through the use of a mixture of bituminous and subbituminous (PRB) coals, whilst attaining NOx and SOx compliance are presented. The optimization considerations to provide satisfactory furnace, boiler and unit performance with blended coal supplies to make such operation feasible are discussed. 6 refs., 7 figs., 1 tab.

  13. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect (OSTI)

    G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

    2007-07-01

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  14. Development of clean coal and clean soil technologies using advanced agglomeration techniques

    SciTech Connect (OSTI)

    Ignasiak, B.; Ignasiak, T.; Szymocha, K.

    1990-01-01

    Three major topics are discussed in this report: (1) Upgrading of Low Rank Coals by the Agflotherm Process. Test data, procedures, equipment, etc., are described for co-upgrading of subbituminous coals and heavy oil; (2) Upgrading of Bituminous Coals by the Agflotherm Process. Experimental procedures and data, bench and pilot scale equipments, etc., for beneficiating bituminous coals are described; (3) Soil Clean-up and Hydrocarbon Waste Treatment Process. Batch and pilot plant tests are described for soil contaminated by tar refuse from manufactured gas plant sites. (VC)

  15. Thermo-Viscoelastic-Viscoplastic-Viscodamage-Healing Modeling of Bituminous Materials: Theory and Computation 

    E-Print Network [OSTI]

    Darabi Konartakhteh, Masoud

    2012-10-19

    for bituminous materials and asphalt mixes. The developed thermodynamic-based framework is general and can be applied for constitutive modeling of different materials such as bituminous materials, soft materials, polymers, and biomaterials. This framework...

  16. Experimental Ion Exchange Column With SuperLig 639 And Simulant Formulation

    SciTech Connect (OSTI)

    Morse, Megan; Nash, C.

    2013-08-26

    SuperLig®639 ion exchange resin was tested as a retrieval mechanism for pertechnetate, through decontamination of a perrhenate spiked 5M Simple Average Na{sup +} Mass Based Simulant. Testing included batch contacts and a three-column ion exchange campaign. A decontamination of perrhenate exceeding 99% from the liquid feed was demonstrated. Analysis of the first formulation of a SBS/WESP simulant found unexpectedly low concentrations of soluble aluminum. Follow-on work will complete the formulation.

  17. National Coal Quality Inventory (NACQI)

    SciTech Connect (OSTI)

    Robert Finkelman

    2005-09-30

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  18. Catalytic steam gasification reactivity of HyperCoals produced from different rank of coals at 600-775{degree}C

    SciTech Connect (OSTI)

    Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group, Energy Technology Research Institute

    2008-11-15

    HyperCoal is a clean coal with ash content <0.05 wt %. HyperCoals were prepared from a brown coal, a sub-bituminous coal, and a bituminous raw coal by solvent extraction method. Catalytic steam gasification of these HyperCoals was carried out with K{sub 2}CO{sub 3} at 775, 700, 650, and 600 {degree}C, and their rates were compared. HyperCoals produced from low-rank coals were more reactive than those produced from the high-rank coals. XRD measurements were carried out to understand the difference in gasification reactivity of HyperCoals. Arrhenius plot of ln (k) vs 1/T in the temperature range 600-825{degree}C was a curve rather than a straight line. The point of change was observed at 700{degree}C for HyperCoals from low-rank coals and at 775{degree}C for HyperCoals from high-rank coals. Using HyperCoal produced from low-rank coals as feedstock, steam gasification of coal may be possible at temperatures less than 650{degree}C. 22 refs., 6 figs., 2 tabs.

  19. Coal deposit characterization by gamma-gamma density/percent dry ash relationships 

    E-Print Network [OSTI]

    Wright, David Scott

    1984-01-01

    provides the capability of filling gaps in the data base which might otherwise result in a misinterpretation of the coal quality throughout the deposit. Geophysi cally-derived in situ coal quality parameters are not currently used as a basis upon which... (Ott, 1984). Tens of thousands of coal core samples analyzed over the past seven years have provided a computerized data base for the formulation of coal parameter interrelationships (Hoeft, et al. , 1983). Alabama lignite and Illinois bituminous...

  20. Coal combustion under conditions of blast furnace injection

    SciTech Connect (OSTI)

    Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

    1995-12-01

    Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal with particular reference to the coals from the Illinois Basin. Although this research is not yet completed the results to date support the following conclusions: (1) based on the results of computer modeling, lower rank bituminous coals, including coal from the Illinois Basin, compare well in their injection properties with a variety of other bituminous coals, although the replacement ratio improves with increasing rank; (2) based on the results of petrographic analysis of material collected from an active blast furnace, it is clear the coal derived char is entering into the raceway of the blast furnace; (3) the results of reactivity experiments on a variety of coal chars at a variety of reaction temperatures show that lower rank bituminous coals, including coal from the Illinois basin, yield chars with significantly higher reactivities in both air and CO{sub 2} than chars from higher rank Appalachian coals and blast furnace coke. These results indicate that the chars from the lower rank coals should have a superior burnout rate in the tuyere and should survive in the raceway environment for a shorter time. These coals, therefore, will have important advantages at high rates of injection that may overcome their slightly lower replacement rates.

  1. Hydrocracking catalysts from coals

    SciTech Connect (OSTI)

    Farcasiu, M.; Petrosius, S.C.; Pladner, E. [USDOE Pittsburgh Energy Technology Center, PA (United States); Derbyshire, F.; Jagtoyen, M. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    1994-12-31

    In previous work at PETC it was shown that carbon blacks and carbonized polymers could be active and selective catalysts in hydrocracking reactions of interest for fossil fuels processing. Work at CAER for the production of various activated carbons from coals have shown that the properties of the materials could be varied if they are produced under different conditions. The authors will report work to optimize the catalytic properties of some coal based carbon materials prepared at CAER. One of the most promising materials for this purpose is obtained from an Illinois bituminous coal. The procedure hydroxide solution with coal and reacting in two stages; (1) heat treatment of the solution at 75 C under nitrogen for one hour followed by drying and (2) heat treatment at 400--1,100 C followed by leaching to remove KOH. The product was extensively characterized and its catalytic activity was measured. The catalytic activity of some of the materials is comparable with other, more expensive carbon materials. The catalysts have potential use in upgrading petroleum heavy ends and coal liquefaction.

  2. Emissions mitigation of blended coals through systems optimization

    SciTech Connect (OSTI)

    Don Labbe [IOM Invensys Operations Management (United States)

    2009-10-15

    For coal fired power stations, such as those located in the US, that have installed NOx and SOx emissions abatement equipment substantial carbon dioxide reduction could be achieved by shifting from pure PRB coal to blended coals with local bituminous coal. Don Labbe explains how. The article is based on a presentation at Power-Gen Asia 2009, which takes place 7-9 October in Bangkok, Thailand and an ISA POWID 2009 paper (19th Annual Joint ISA POWID/EPRI Controlls and Instrumentation Conference, Chicago, Illinois, May 2009). 4 refs., 3 figs.

  3. Kinetics of coal pyrolysis

    SciTech Connect (OSTI)

    Seery, D.J.; Freihaut, J.D.; Proscia, W.M. ); Howard, J.B.; Peters, W.; Hsu, J.; Hajaligol, M.; Sarofim, A. ); Jenkins, R.; Mallin, J.; Espindola-Merin, B. ); Essenhigh, R.; Misra, M.K. )

    1989-07-01

    This report contains results of a coordinated, multi-laboratory investigation of coal devolatilization. Data is reported pertaining to the devolatilization for bituminous coals over three orders of magnitude in apparent heating rate (100 to 100,000 + {degree}C/sec), over two orders of magnitude in particle size (20 to 700 microns), final particle temperatures from 400 to 1600{degree}C, heat transfer modes ranging from convection to radiative, ambient pressure ranging from near vacuum to one atmosphere pressure. The heat transfer characteristics of the reactors are reported in detail. It is assumed the experimental results are to form the basis of a devolatilization data base. Empirical rate expressions are developed for each phase of devolatilization which, when coupled to an awareness of the heat transfer rate potential of a particular devolatilization reactor, indicate the kinetics emphasized by a particular system reactor plus coal sample. The analysis indicates the particular phase of devolatilization that will be emphasized by a particular reactor type and, thereby, the kinetic expressions appropriate to that devolatilization system. Engineering rate expressions are developed from the empirical rate expressions in the context of a fundamental understanding of coal devolatilization developed in the course of the investigation. 164 refs., 223 figs., 44 tabs.

  4. Plasma gasification of coal in different oxidants

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (USA)

    2008-12-15

    Oxidant selection is the highest priority for advanced coal gasification-process development. This paper presents comparative analysis of the Powder River Basin bituminous-coal gasification processes for entrained-flow plasma gasifier. Several oxidants, which might be employed for perspective commercial applications, have been chosen, including air, steam/carbon-dioxide blend, carbon dioxide, steam, steam/air, steam/oxygen, and oxygen. Synthesis gas composition, carbon gasification degree, specific power consumptions, and power efficiency for these processes were determined. The influence of the selected oxidant composition on the gasification-process main characteristics have been investigated.

  5. CO2 Sequestration in Unmineable Coal Seams: Potential Environmental Impacts

    SciTech Connect (OSTI)

    Hedges, S.W.; Soong, Yee; McCarthy Jones, J.R.; Harrison, D.K.; Irdi, G.A.; Frommell, E.A.; Dilmore, R.M.; Pique, P.J.; Brown, T.D

    2005-09-01

    An initial investigation into the potential environmental impacts of CO2 sequestration in unmineable coal seams has been conducted, focusing on changes in the produced water during enhanced coalbed methane (ECBM) production using a CO2 injection process (CO2-ECBM). Two coals have been used in this study, the medium volatile bituminous Upper Freeport coal (APCS 1) of the Argonne Premium Coal Samples series, and an as-mined Pittsburgh #8 coal, which is a high volatile bituminous coal. Coal samples were reacted with either synthetic produced water or field collected produced water and gaseous carbon dioxide at 40 ?C and 50 bar to evaluate the potential for mobilizing toxic metals during CO2-ECBM/sequestration. Microscopic and x-ray diffraction analysis of the post-reaction coal samples clearly show evidence of chemical reaction, and chemical analysis of the produced water shows substantial changes in composition. These results suggest that changes to the produced water chemistry and the potential for mobilizing toxic trace elements from coalbeds are important factors to be considered when evaluating deep, unmineable coal seams for CO2 sequestration.

  6. Application of coal petrography to the evaluation of magnetically separated dry crushed coals

    SciTech Connect (OSTI)

    Harris, L.A.; Hise, E.C.

    1981-01-01

    In the present study the open gradient magnetic separation method has been used to beneficiate the -30 + 100 mesh fraction of two high volatile bituminous coals. The evaluation of the effectiveness of the magnetic separation for cleaning these coals is the subject of this paper. Coal petrography in combination with scanning electron microscopy and x-ray diffractometry were used to characterize the magnetically separated coal fractions. These analyses revealed that the majority of the pyrite and non-pyrite minerals were concentrated in the positive magnetic susceptibility fractions. The bulk of the starting samples (approx. 80 weight percent) were located in the negative magnetic susceptibility fractions and showed significant reductions in pyrite and non-pyritic minerals. The magnetic separation appears to effectively split the samples into relatively clean coal and refuse.

  7. Enzymantic Conversion of Coal to Liquid Fuels

    SciTech Connect (OSTI)

    Richard Troiano

    2011-01-31

    The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time, corresponding to the consumption of aromatic intermediates as they undergo ring cleavage. The results show that this process happens within 1 hour when using extracellular enzymes, but takes several days when using live organisms. In addition, live organisms require specific culture conditions, control of contaminants and fungicides in order to effectively produce extracellular enzymes that degrade coal. Therefore, when comparing the two enzymatic methods, results show that the process of using extracellular lignin degrading enzymes, such as laccase and manganese peroxidase, appears to be a more efficient method of decomposing bituminous coal.

  8. The methods of steam coals usage for coke production

    SciTech Connect (OSTI)

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  9. Coal plasticity at high heating rates and temperatures. Final technical progress report

    SciTech Connect (OSTI)

    Gerjarusak, S.; Peters, W.A.; Howard, J.B.

    1995-05-01

    Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

  10. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30

    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

  11. Studies of coupled chemical and catalytic coal conversion methods

    SciTech Connect (OSTI)

    Stock, L.M.

    1989-01-01

    A new base catalyzed C-alkylation reaction that employs a mixture of n-butyllithium and potassium t-butoxide in refluxing heptane to produce coal anions that are subsequently treated with n-alkyl halides at 0{degree}C has been developed. Almost quantitative pyridine solubilization was achieved by C-octylation of a Lower Kittanning coal, PSOC 1197. C-Octylation was less successful for the solubilization of bituminous Illinois No. 6 coal, APCSP 3, and subbituminous Wyodak coal, APCSP 2, which gave 35 and 33% soluble material, respectively. Their O-methyl derivatives yielded 43 and 20% soluble material in the same reaction. The observations are in accord with the concept of Ouchi and his associates that higher rank coals, although more aromatic in character, have a lower degree of polymerization than low rank coals. Relatively mild chemical reactions, such as Calkylation, that lead to modest changes in molecular dimensions, can disrupt intermolecular forces and accomplish solubilization.

  12. Physical and mechanical properties of bituminous mixtures containing oil shales

    SciTech Connect (OSTI)

    Katamine, N.M.

    2000-04-01

    Rutting of bituminous surfaces on the Jordanian highways is a recurring problem. Highway authorities are exploring the use of extracted shale oil and oil shale fillers, which are abundant in Jordan. The main objectives of this research are to investigate the rheological properties of shale oil binders (conventional binder with various percentages of shale oil), in comparison with a conventional binder, and to investigate the ability of mixes to resist deformation. The latter is done by considering three wearing course mixes containing three different samples of oil shale fillers--which contained three different oil percentages--together with a standard mixture containing limestone filler. The Marshall design method and the immersion wheel tracking machine were adopted. It was concluded that the shale oil binders displayed inconsistent physical properties and therefore should be treated before being used. The oil shale fillers have provided mixes with higher ability to resist deformation than the standard mix, as measured by the Marshall quotients and the wheel tracking machine. The higher the percentages of oil in the oil shale fillers, the lower the ability of the mixes to resist deformation.

  13. INTERACTION OF A SUB-BITUMINOUS COAL WITH A STRONG ACID AND A STRONG BASE

    E-Print Network [OSTI]

    Seth, M.

    2010-01-01

    in Phosphoric Acid Hydrocracking Over Solid Acidic Catalystsacid show much promise. In hydrocracking system the relativeas in studies of zeoli hydrocracking and hydrogenation can

  14. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    factor of bituminous coal, coking coal, and coke consumed inprice of Bituminous coal, coking coal, and coke consumed in

  15. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Khan, M. Rashid (Morgantown, WV)

    1989-01-01

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

  16. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Rashid Khan, M.

    1988-05-05

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

  17. Injury experience in coal mining, 1990

    SciTech Connect (OSTI)

    1991-01-01

    This Mine Safety and Health Administration (MSHA) informational report reviews in detail the occupational injury and illness experience of coal mining in the United States for 1990. Data reported by operators of mining establishments concerning work injuries are summarized by work location, accident classification, part of body injured, nature of injury, occupation, and anthracite or bituminous coal. Related information on employment, worktime, and operating activity also is presented. Data reported by independent contractors performing certain work at mining locations are depicted separately in this report. For ease of comparison between coal mining and the metal and nonmetal mineral mining industries, summary reference tabulations are included at the end of both the operator and the contractor sections of this report.

  18. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  19. Upgrade to Ion Exchange Modeling for Removal of Technetium from Hanford Waste Using SuperLig® 639 Resin

    SciTech Connect (OSTI)

    Hamm, L.; Smith, F.; Aleman, S.; McCabe, D.

    2013-05-16

    This report documents the development and application of computer models to describe the sorption of pertechnetate [TcO??], and its surrogate perrhenate [ReO??], on SuperLig® 639 resin. Two models have been developed: 1) A thermodynamic isotherm model, based on experimental data, that predicts [TcO??] and [ReO??] sorption as a function of solution composition and temperature and 2) A column model that uses the isotherm calculated by the first model to simulate the performance of a full-scale sorption process. The isotherm model provides a synthesis of experimental data collected from many different sources to give a best estimate prediction of the behavior of the pertechnetate-SuperLig® 639 system and an estimate of the uncertainty in this prediction. The column model provides a prediction of the expected performance of the plant process by determining the volume of waste solution that can be processed based on process design parameters such as column size, flow rate and resin physical properties.

  20. Synthesis gas production with an adjustable H{sub 2}/CO ratio through the coal gasification process: effects of coal ranks and methane addition

    SciTech Connect (OSTI)

    Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

    2008-05-15

    Direct production of synthesis gas using coal as a cheap feedstock is attractive but challenging due to its low H{sub 2}/CO ratio of generated synthesis gas. Three typical U.S. coals of different ranks were tested in a 2.5 in. coal gasifier to investigate their gasification reactivity and adjustability on H{sub 2}/CO ratio of generated synthesis gas with or without the addition of methane. Tests indicated that lower-rank coals (lignite and sub-bituminous) have higher gasification reactivity than bituminous coals. The coal gasification reactivity is correlated to its synthesis-gas yield and the total percentage of H{sub 2} and CO in the synthesis gas, but not to the H{sub 2}/CO ratio. The H{sub 2}/CO ratio of coal gasification was found to be correlated to the rank of coals, especially the H/C ratio of coals. Methane addition into the dense phase of the pyrolysis and gasification zone of the cogasification reactor could make the best use of methane in adjusting the H{sub 2}/CO ratio of the generated synthesis gas. The maximum methane conversion efficiency, which was likely correlated to its gasification reactivity, could be achieved by 70% on average for all tested coals. The actual catalytic effect of generated coal chars on methane conversion seemed coal-dependent. The coal-gasification process benefits from methane addition and subsequent conversion on the adjustment of the H{sub 2}/CO ratio of synthesis gas. The methane conversion process benefits from the use of coal chars due to their catalytic effects. This implies that there were likely synergistic effects on both. 25 refs., 3 figs., 3

  1. The role of coal in industrialization: A case study of Nigeria

    SciTech Connect (OSTI)

    Akarakiri, J.B. (Obafemi Awolowo Univ., Ile-Ife (Nigeria))

    1989-01-01

    Coal is a mineral matter found in layers or beds in sedimentary rocks. It is a very highly variable substance. In addition to the variations from lignite to bituminous and anthracite, there are vast differences in its heating value, amount of volatiles, sulfur, moisture and so on. The chemical and physical properties of coal make it an important industrial raw material. There is proven 639 million tonnes of coal reserves in Nigeria. This paper examines the potential and current role of coal in the industrialization of Nigeria. Industries are now dependent on fuel oil as a source of fuel because of its economic and technological advantages over coal. Coal is a source of industrial energy for the future after the known oil reserves might have been exhausted. In the short term, coal can be used as a material for chemicals, iron and steel production as well as a substitute for wood energy in the process of industrialization.

  2. Pressurized pyrolysis and gasification of Chinese typical coal samples

    SciTech Connect (OSTI)

    Hanping Chen; Zhiwu Luo; Haiping Yang; Fudong Ju; Shihong Zhang [Huazhong University of Science and Technology, Wuhan (China). State Key Laboratory of Coal Combustion

    2008-03-15

    This paper aims to understand the pyrolysis and gasification behavior of different Chinese coal samples at different pressures. First, the pyrolysis of four typical Chinese coals samples (Xiaolongtan brown coal, Shenfu bituminous coal, Pingzhai anthracite coal, and Heshan lean coal) were carried out using a pressurized thermogravimetric analyzer at ambient pressure and 3 MPa, respectively. The surface structure and elemental component of the resultant char were measured with an automated gas adsorption apparatus and element analyzer. It was observed that higher pressure suppressed the primary pyrolysis, while the secondary pyrolysis of coal particles was promoted. With respect to the resultant solid char, the carbon content increased while H content decreased; however, the pore structure varied greatly with increasing pressure for different coal samples. For Xiaolongtan brown coal (XLT) char, it decreased greatly, while it increased obviously for the other three char types. Then, the isothermal gasification behavior of solid char particles was investigated using an ambient thermal analyzer with CO{sub 2} as the gasifying agent at 1000{sup o}C. The gasification reactivity of solid char was decreased greatly with increasing pyrolysis pressure. However, the extent of change displayed a vital relation with the characteristics of the original coal sample. 26 refs., 5 figs., 5 tabs.

  3. Effect of coal rank and process conditions on temperature distribution in a liquefaction reactor

    SciTech Connect (OSTI)

    Nalitham, R.V.; Moniz, M.

    1986-04-01

    The temperature distribution in a liquefaction reactor in the integrated TSL process is studied. The effects of gas and slurry superficial velocities, process solvent characteristics, reactor length, and catalyst sulfiding agent on the exotherm and temperature difference in the reactor are studied. A substantial temperature difference is observed with subbituminous coal as compared with bituminous coal, at comparable reactor conditions. Some of the factors that are believed to have contributed to the large exotherm and temperature difference in the reactor are slow kinetics and high reaction heat for subbituminous coal conversion and pyrrhotite catalysis.

  4. The use of NMR techniques for the analysis of water in coal and the effect of different coal drying techniques on the structure and reactivity of coal. Final report

    SciTech Connect (OSTI)

    Netzel, D.A.; Miknis, F.P.; Wallace, J.C. Jr.; Butcher, C.H.; Mitzel, J.M.; Turner, T.F.; Hurtubise, R.J.

    1995-02-01

    Western Research Institute has conducted a study of different methods of coal drying as pretreatment steps before liquefaction. The objectives of this study were to develop a combined chemical dehydration/nuclear magnetic resonance (NMR) method for measuring the moisture content of coal, to measure the changes in coal structure that occur during drying, and to determine the effects of different drying methods on liquefaction reactivity of coals. Different methods of drying were investigated to determine whether coal drying can be accomplished without reducing the reactivity of coals toward liquefaction. Drying methods included thermal, microwave, and chemical dehydration. Coals of rank lignite to high volatile bituminous were studied. Coals that were dried or partially dried thermally and with microwaves had lower liquefaction conversions than coals containing equilibrium moisture contents. However, chemically dried coals had conversions equal to or greater than the premoisturized coals. The conversion behavior is consistent with changes in the physical structure and cross linking reactions because of drying. Thermal and microwave drying appear to cause a collapse in the pore structure, thus preventing donor solvents such as tetralin from contacting reactive sites inside the coals. Chemical dehydration does not appear to collapse the pore structure. These results are supported by the solvent swelling measurements in which the swelling ratios of thermally dried and microwave-dried coals were lower than those of premoisturized coals, indicating a greater degree of cross linking in the dried coals. The swelling ratios of the chemically dried coals were greater than those of the premoisturized coals because the pore structure remaining unchanged or increased when water was removed. These results are consistent with the NMR results, which did not show significant changes in coal chemical structure.

  5. Studies of coupled chemical and catalytic coal conversion methods. Ninth quarterly report, October, November, December 1989

    SciTech Connect (OSTI)

    Stock, L.M.

    1989-12-31

    A new base catalyzed C-alkylation reaction that employs a mixture of n-butyllithium and potassium t-butoxide in refluxing heptane to produce coal anions that are subsequently treated with n-alkyl halides at 0{degree}C has been developed. Almost quantitative pyridine solubilization was achieved by C-octylation of a Lower Kittanning coal, PSOC 1197. C-Octylation was less successful for the solubilization of bituminous Illinois No. 6 coal, APCSP 3, and subbituminous Wyodak coal, APCSP 2, which gave 35 and 33% soluble material, respectively. Their O-methyl derivatives yielded 43 and 20% soluble material in the same reaction. The observations are in accord with the concept of Ouchi and his associates that higher rank coals, although more aromatic in character, have a lower degree of polymerization than low rank coals. Relatively mild chemical reactions, such as Calkylation, that lead to modest changes in molecular dimensions, can disrupt intermolecular forces and accomplish solubilization.

  6. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  7. Evaluation and comparison of SuperLig{reg_sign} 644, resorcinol-formaldehyde and CS-100 ion exchange materials for the removal of cesium from simulated alkaline supernate

    SciTech Connect (OSTI)

    Brown, G.N.; Bray, L.A.; Eloviche, R.J.; Bruening, R.L.; Decker, R.M.; Kafka, T.M.; White, L.R.

    1995-03-01

    PNL evaluated three polymeric materials for Cs removal efficiency from a simulated Hanford Neutralized Current Acid Waste (NCAW) supernatant liquid using 200 mL ion exchange columns. Cs loadings (mmole Cs/g resin) were 0.20, 0.18, and 0.039 for Super Lig 644, R-F, and CS-100 (0.045, 0.070, 0.011 mmole Cs/mL resin). Elution of each resin material with 0.5 M HNO{sub 3} required 3.5, 7.0, and 3.2 cv to reach 0.1 C/C{sub 0} for the respective materials, resulting in volume compressions of 27, 20, and 6.9. Peak Cs concentrations during elution was 185, 38.5, and 27.8 C/C{sub 0}. SuperLig 644 had the highest Cs loading per gram in NCAW and the greatest volume compression on aci elution. Because of high density and poor elution, R-F had the highest Cs loading per unit volume and lower volume compression. CS-100, the baseline material for Cs removal at Hanford, was inferior to both SuperLig 644 and R-F in terms of Cs loading and selectivity over sodium.

  8. Effects of pretreatment of coal by CO{sub 2} on nitric oxide emission and unburned carbon in various combustion environments

    SciTech Connect (OSTI)

    Gathitu, B.B.; Chen, W.Y. [University of Mississippi, University, MS (United States). Dept. of Chemical Engineering

    2009-12-15

    Polar solvents are known to swell coal, break hydrogen bonds in the macromolecular structure, and enhance coal liquefaction efficiencies. The effects of the pretreatment of coal using supercritical CO{sub 2} on its physical structure and combustion properties have been studied at the bench-scale level. Emphasis has been placed on NO reburning, NO emissions during air-fired and oxy-fired combustion, and loss on ignition (LOI). Pretreatment was found to increase porosity and to significantly alter the fuel nitrogen reaction pathways. Consequently, NO reduction during reburning using bituminous coal increased, and NO emissions during oxidation of lignite decreased. These two benefits were achieved without negative impacts on LOI.

  9. Low-severity catalytic two-stage liquefaction process: Illinois coal conceptual commercial plant design and economics

    SciTech Connect (OSTI)

    Abrams, L.M.; Comolli, A.G.; Popper, G.A.; Wang, C.; Wilson, G.

    1988-09-01

    Hydrocarbon Research, Inc. (HRI) is conducting a program for the United States Department of Energy (DOE) to evaluate a Catalytic Two-Stage Liquefaction (CTSL) Process. This program which runs through 1987, is a continuation of an earlier DOE sponsored program (1983--1985) at HRI to develop a new technology concept for CTSL. The earlier program included bench-scale testing of improved operating conditions for the CTSL Process on Illinois No. 6 bituminous coal and Wyoming sub-bituminous coal, and engineering screening studies to identify the economic incentive for CTSL over the single-stage H-Coal/reg sign/ Process for Illinois No. 6 coal. In the current program these engineering screening studies are extended to deep-cleaned Illinois coal and use of heavy recycle. The results from this comparison will be used as a guide for future experiments with respect to selection of coal feedstocks and areas for further process optimization. A preliminary design for CTSL of Illinois deep-cleaned coal was developed based on demonstrated bench-scale performance in Run No. 227-47(I-27), and from HRI's design experience on the Breckinridge Project and H-Coal/reg sign/ Process pilot plant operations at Catlettsburg. Complete conceptual commercial plant designs were developed for a grassroots facility using HRI's Process Planning Model. Product costs were calculated and economic sensitivities analyzed. 14 refs., 11 figs., 49 tabs.

  10. Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

    SciTech Connect (OSTI)

    1982-01-01

    This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

  11. Development of a coal burning pulsating combustor for industrial power

    SciTech Connect (OSTI)

    Zinn, B.T.; Wang, M.R.; Daniel, B.R.

    1983-11-01

    The research conducted under this program investigated the performance characteristics of a previously developed coal burning pulsating combustor whose design is based upon the Rijke tube principles. The combustor consists of a vertical tube opened at both ends with a fuel burning bed located in the middle of its lower half. Coal is supplied to the bed by a rotating auger-type feed system located 1 ft above the bed. Following ignition, the interaction between the combustion process and the combustor flow results in the excitation of high amplitude (up to 165 dB) fundamental, longitudinal acoustic mode oscillations with frequencies in the range 75 to 90 Hz in the combustor. Maximum amplitudes occurred near stoichiometric air/fuel ratio operation, suggesting that systems utilizing the developed combustor should possess high thermal efficiencies, as they could operate with relatively litle excess air. Both bituminous and subbituminous coals with sizes in the range 1/4'' to 1/2'' were burned in the developed pulsating combustor. The CO, CO/sub 2/, NO/sub x/, SO/sub 2/, O/sub 2/ and particulates concentrations in the exhaust flow were measured to evaluate the combustor performance. In tests with bituminous coal, combustion efficiencies higher than 95% for coal feed rates in the range 42 to 60 lb/ft/sup 2/hr were achieved with only 13% excess air while NO/sub x/ and SO/sub 2/ concentrations were comparable to those obtained with other steady state combustors. A higher performance was attained in initial tests with subbituminous coal. Finally, pulsating operation was possible under fuel rich conditions suggesting that the developed pulsating combustor could be possibly used as a gasifier.

  12. Stability of coal microstructure on exposure to high pressures of helium.

    SciTech Connect (OSTI)

    Sakurovs, Richard [ORNL; Radlinski, Andrzej Pawell [ORNL; Melnichenko, Yuri B [ORNL; Blach, Tomasz P [ORNL; Cheng, Gang [ORNL

    2009-01-01

    Small angle neutron scattering (SANS) and ultra-small angle neutron scattering (USANS) measurements of the structure of two Australian bituminous coals (particle size -1mm+0.5mm) before, during and after exposure to 155 bar of helium were made in order to identify any effects of pressure alone on the pore size distribution of coal, and any irreversible effects on exposure to high pressures of helium in the pore size range from 3 nm to 10 m. No irreversible effects on exposure were identified for any pore size. No effects of pressure on pore size distribution were observed, except for a small effect at a pore size of about 2 m for one coal. This study provides a convenient baseline for SANS and USANS investigations on sorption of gases at elevated pressures on coals, by distinguishing between the effect of pressure alone on coal pore size distribution as against the effect of the gas to be investigated.

  13. Flash hydropyrolysis of coal. Quarterly report No. 11, October 1-December 31, 1979

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.; Bhatt, B.L.

    1980-02-01

    The following conclusions can be drawn from this work: (1) when the caking bituminous coals are used with diluents, only 20% Pittsburgh No. 8 coal can be added to the diluent swhile 40% Illinois No. 6 could be added due to the higher free swelling index of the Pittsburgh No. 8; (2) When limestone is used as a diluent, considerably more sulfur is retained in the char than when using sand; (3) when the char from an experiment using limestone is recycled as the diluent for another experiment, the char continually retains additional sulfur through at least three recycles; (4) decomposition of the limestone and reduction is indicated by the high concentrations of CO observed at 900/sup 0/C; (5) increasing the coal feed rate by a factor of 4 from 2.4 to 10.7 lb/hr at low H/sub 2//Coal ratios (approx. = 0.6) results in no appreciable change in gaseous HC yields (approx. = 27%) or concentration (approx. = 45%) but higher BTX yields (1.1% vs. 5.4%); (6) although only one experiment was conducted, it appears that hydrogasification of untreated New Mexico sub-bituminous coal at 950/sup 0/C does not give an increase in yield over hydrogasification at 900/sup 0/C; (7) the hydrogasification of Wyodak lignite gives approximately the same gaseous HC yields as that obtained from North Dakota lignite but higher BTX yields particularly at 900/sup 0/C and 1000 psi (9% vs. 2%); (8) treating New Mexico sub-bituminous coal with NaCO/sub 3/ does not increase its hydrogasification qualities between 600/sup 0/C and 900/sup 0/C at 1000 psi but does decrease the BTX yield.

  14. Small boiler uses waste coal

    SciTech Connect (OSTI)

    Virr, M.J.

    2009-07-15

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

  15. Coal combustion by wet oxidation. Wet oxidation of coal for energy production: test plan and partial results. Interim report

    SciTech Connect (OSTI)

    Bettinger, J.A.

    1980-07-10

    A test plan has been developed which will provide the data necessary to carry out design and economic studies of a steam generating facility, employing the wet oxidation of coal as a heat source. It is obvious, from the literature search and preliminary testing, that the higher the reaction temperature, the more complete the combustion of coal. However, operation at elevated temperatures and pressures present difficult design problems, and the necessary equipment is costly. Operation under these conditions can only be justified by the higher economic value of high pressure and temperature steam. With a reduction in temperature from 550/sup 0/F (228/sup 0/C) to 450/sup 0/F (232/sup 0/C), the operating pressure is reduced by more than half, thus holding down the overall cost of the system. For this reason, our plan is to study both the enhancement of low temperature wet oxidation of coal, and the higher operating regions. The coal selected for the first portion of this test is an Eastern Appalachian high-volatile-A Bituminous type, from the Upper Clarion seam in Pennsylvania. This coal was selected as being a typical high sulfur, eastern coal. The wet oxidation of coal to produce low pressure steam is a process suited for a high sulfur, low grade, coal. It is not intended that wet oxidation be used in all applications with all types of coals, as it does not appear to be competitive, economically, with conventional combustion, therefore the testing will focus on using high sulfur, low grade coals. In the later portion of testing all the available coals will be tested. In addition, a sample of Minnesota peat will be tested to determine if it also can be used in the process.

  16. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    Ray Chamberland; Aku Raino; David Towle

    2006-09-30

    For more than two decades, ALSTOM Power Inc. (ALSTOM) has developed a range of low cost, in-furnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes ALSTOM's internally developed TFS 2000 firing system, and various enhancements to it developed in concert with the U.S. Department of Energy (DOE). As of 2004, more than 200 units representing approximately 75,000 MWe of domestic coal fired capacity have been retrofit with ALSTOM low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coals to 0.10 lb/MMBtu for subbituminous coals, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing (retrofit) boiler equipment. If enacted, proposed Clear Skies legislation will, by 2008, require an average, effective, domestic NOx emissions rate of 0.16 lb/MMBtu, which number will be reduced to 0.13 lb/MMBtu by 2018. Such levels represent a 60% and 67% reduction, respectively, from the effective 2000 level of 0.40 lb/MMBtu. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. In light of these needs, ALSTOM, in cooperation with the DOE, is developing an enhanced combustion, low NOx pulverized coal burner which, when integrated with ALSTOM's state-of-the-art, globally air staged low NOx firing systems, will provide a means to achieve less than 0.15 lb/MMBtu NOx at less than 3/4 the cost of an SCR with low to no impact on balance of plant issues when firing a high volatile bituminous coal. Such coals can be more economic to fire than subbituminous or Powder River Basin (PRB) coals, but are more problematic from a NOx control standpoint as existing firing system technologies do not provide a means to meet current or anticipated regulations absent the use of an SCR. The DOE/ALSTOM program performed large pilot scale combustion testing in ALSTOM's Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut. During this work, the near-field combustion environment was optimized to maximize NOx reduction while minimizing the impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down under globally reducing conditions. Initially, ALSTOM utilized computational fluid dynamic modeling to evaluate a series of burner and/or near field stoichiometry controls in order to screen promising design concepts in advance of the large pilot scale testing. The third and final test, to be executed, will utilize several variants of the best nozzle tip configuration and compare performance with 3 different coals. The fuels to be tested will cover a wide range of coals commonly fired at US utilities. The completion of this work will provide sufficient data to allow ALSTOM to design, construct, and demonstrate a commercial version of an enhanced combustion low NOx pulverized coal burner. A preliminary cost/performance analysis of the developed enhanced combustion low NOx burner applied to ALSTOM's state-of-the-art TFS 2000 firing system was performed to show that the burner enhancements is a cost effective means to reduce NOx.

  17. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    OF COAL MODEL COMPOUNDS AND COAL LIQUIDS James Anthony AprilCOAL MODEL COMPOUNDS AND COAL LIQUIDS James Anthony Wrathalla promising agent in coal-liquid desulfurization, assuming

  18. Advanced coal-fueled gas turbine systems

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    Westinghouse's Advanced Coal-Fueled Gas Turbine System Program (DE-AC2l-86MC23167) was originally split into two major phases - a Basic Program and an Option. The Basic Program also contained two phases. The development of a 6 atm, 7 lb/s, 12 MMBtu/hr slagging combustor with an extended period of testing of the subscale combustor, was the first part of the Basic Program. In the second phase of the Basic Program, the combustor was to be operated over a 3-month period with a stationary cascade to study the effect of deposition, erosion and corrosion on combustion turbine components. The testing of the concept, in subscale, has demonstrated its ability to handle high- and low-sulfur bituminous coals, and low-sulfur subbituminous coal. Feeding the fuel in the form of PC has proven to be superior to CWM type feed. The program objectives relative to combustion efficiency, combustor exit temperature, NO[sub x] emissions, carbon burnout, and slag rejection have been met. Objectives for alkali, particulate, and SO[sub x] levels leaving the combustor were not met by the conclusion of testing at Textron. It is planned to continue this testing, to achieve all desired emission levels, as part of the W/NSP program to commercialize the slagging combustor technology.

  19. KINETIC STUDY OF COAL AND BIOMASS CO-PYROLYSIS USING THERMOGRAVIMETRY

    SciTech Connect (OSTI)

    Wang, Ping; Hedges, Sheila; Chaudharib, Kiran; Turtonb, Richard

    2013-10-29

    The objectives of this study are to investigate thermal behavior of coal and biomass blends in inert gas environment at low heating rates and to develop a simplified kinetic model using model fitting techniques based on TGA experimental data. Differences in thermal behavior and reactivity in co-pyrolysis of Powder River Basin (PRB) sub-bituminous coal and pelletized southern yellow pine wood sawdust blends at low heating rates are observed. Coal/wood blends have higher reactivity compared to coal alone in the lower temperature due to the high volatile matter content of wood. As heating rates increase, weight loss rates increase. The experiment data obtained from TGA has a better fit with proposed two step first order reactions model compared single first order reaction model.

  20. The Mesaba Energy Project: Clean Coal Power Initiative, Round 2

    SciTech Connect (OSTI)

    Stone, Richard; Gray, Gordon; Evans, Robert

    2014-07-31

    The Mesaba Energy Project is a nominal 600 MW integrated gasification combine cycle power project located in Northeastern Minnesota. It was selected to receive financial assistance pursuant to code of federal regulations (?CFR?) 10 CFR 600 through a competitive solicitation under Round 2 of the Department of Energy?s Clean Coal Power Initiative, which had two stated goals: (1) to demonstrate advanced coal-based technologies that can be commercialized at electric utility scale, and (2) to accelerate the likelihood of deploying demonstrated technologies for widespread commercial use in the electric power sector. The Project was selected in 2004 to receive a total of $36 million. The DOE portion that was equally cost shared in Budget Period 1 amounted to about $22.5 million. Budget Period 1 activities focused on the Project Definition Phase and included: project development, preliminary engineering, environmental permitting, regulatory approvals and financing to reach financial close and start of construction. The Project is based on ConocoPhillips? E-Gas? Technology and is designed to be fuel flexible with the ability to process sub-bituminous coal, a blend of sub-bituminous coal and petroleum coke and Illinois # 6 bituminous coal. Major objectives include the establishment of a reference plant design for Integrated Gasification Combined Cycle (?IGCC?) technology featuring advanced full slurry quench, multiple train gasification, integration of the air separation unit, and the demonstration of 90% operational availability and improved thermal efficiency relative to previous demonstration projects. In addition, the Project would demonstrate substantial environmental benefits, as compared with conventional technology, through dramatically lower emissions of sulfur dioxide, nitrogen oxides, volatile organic compounds, carbon monoxide, particulate matter and mercury. Major milestones achieved in support of fulfilling the above goals include obtaining Site, High Voltage Transmission Line Route, and Natural Gas Pipeline Route Permits for a Large Electric Power Generating Plant to be located in Taconite, Minnesota. In addition, major pre-construction permit applications have been filed requesting authorization for the Project to i) appropriate water sufficient to accommodate its worst case needs, ii) operate a major stationary source in compliance with regulations established to protect public health and welfare, and iii) physically alter the geographical setting to accommodate its construction. As of the current date, the Water Appropriation Permits have been obtained.

  1. Coal desulfurization in a rotary kiln combustor

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.

    1992-09-11

    The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

  2. Chemical and radiation stability of SuperLig{reg_sign}644, resorcinol-formaldehyde, and CS-100 cesium ion exchange materials

    SciTech Connect (OSTI)

    Brown, G.N.; Adami, S.R.; Bray, L.A.

    1995-09-01

    At the request of the Initial Pretreatment Module Project within Westinghouse Hanford Company, Pacific Northwest Laboratory (PNL) conducted this study for the Efficient Separations and Processing Crosscutting Program (ESP) under the task ``Develop and Test Sorbents.`` The purpose of the study was to assess and compare the chemical and radiolytic stability of several cesium-selective ion exchange materials in simulated alkaline Hanford tank waste matrices. Pretreatment of nuclear process wastes to remove of cesium and other radionuclides by ion exchange was proposed previously as one method of minimizing the amount of high-level radioactive waste at Hanford. In this study, PNL evaluated three cesium-selective materials SuperLig{reg_sign}644, resorcinol-formaldehyde (R-F), and CS-100 for chemical and radiation stability in 1 M NaOH and a simulated neutralized current acid waste (NCAW). The objective of the study is to investigate the stability of the newly produced SuperLig{reg_sign}644 under a variety of conditions in an attempt to simulate and predict the degradation process. The following specific conclusions and recommendations resulted from the study.

  3. Pore accessibility by methane and carbon dioxide in coal as determined by neutron scattering

    SciTech Connect (OSTI)

    He, Lilin [ORNL; Melnichenko, Yuri B [ORNL; Mastalerz, Maria [Indiana Geological Survey; Sakurovs, Richard [ORNL; Radlinski, Andrzej Pawell [ORNL; Blach, Tomasz P [ORNL

    2012-01-01

    Contrast-matching ultrasmall-angle neutron scattering (USANS) and small-angle neutron scattering (SANS) techniques were used for the first time to determine both the total pore volume and the fraction of the pore volume that is inaccessible to deuterated methane, CD{sub 4}, in four bituminous coals in the range of pore sizes between {approx}10 {angstrom} and {approx}5 {micro}m. Two samples originated from the Illinois Basin in the U.S.A., and the other two samples were commercial Australian bituminous coals from the Bowen Basin. The total and inaccessible porosity were determined in each coal using both Porod invariant and the polydisperse spherical particle (PDSP) model analysis of the scattering data acquired from coals both in vacuum and at the pressure of CD{sub 4}, at which the scattering length density of the pore-saturating fluid is equal to that of the solid coal matrix (zero average contrast pressure). The total porosity of the coals studied ranged from 7 to 13%, and the volume of pores inaccessible to CD{sub 4} varied from {approx}13 to {approx}36% of the total pore volume. The volume fraction of inaccessible pores shows no correlation with the maceral composition; however, it increases with a decreasing total pore volume. In situ measurements of the structure of one coal saturated with CO{sub 2} and CD{sub 4} were conducted as a function of the pressure in the range of 1-400 bar. The neutron scattering intensity from small pores with radii less than 35 {angstrom} in this coal increased sharply immediately after the fluid injection for both gases, which demonstrates strong condensation and densification of the invading subcritical CO{sub 2} and supercritical methane in small pores.

  4. LIG - Facilities - Cyclotron Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate student Subtask22 LANSCE TopicalElectricity &

  5. Influence of pressure on coal pyrolysis and char gasification

    SciTech Connect (OSTI)

    Haiping Yang; Hanping Chen; Fudong Ju; Rong Yan; Shihong Zhang [Huazhong University of Science and Technology, Wuhan (China). State Key Laboratory of Coal Combustion

    2007-12-15

    Coal char structure varied greatly with pyrolysis pressure, which has a significant influence on the gasification reactivity. In this study, the influence of pressure on the behavior of coal pyrolysis and physicochemical structure and gasification characteristics of the resultant coal char was investigated using a pressurized thermogravimetric analyzer combined with an ambient thermogravimetric analyzer. First, the pyrolysis of Shenfu (SF) bituminous coal was performed in a pressurized thermogravimetric analyzer (TGA) at different pressures (0.1, 0.8, 1.5, 3, and 5 MPa). The volatile mainly evolved out at 400-800{sup o}C. The gas products are mainly CO{sub 2}, CO, CH{sub 4}, and light aliphatics with some water. It was observed that the pyrolysis of coal was shifted to lower temperature (50{sup o}C) with pressure increasing from ambient to 5 MPa, and the devolatilization rate of coal pyrolysis was decreased and the coal char yield was increased slightly. The structure of solid coal char was analyzed using FTIR, ASAP2020, and CNHS. In the solid char, the main organic functional groups are mainly CO, C-C (alkane), C-H ar, C-O-C, and C=C ar. The carbon content was increased while H content decreased. Finally, the gasification of the solid char was preformed at ambient pressure with CO{sub 2} as gasify agent. The gasification process of coal char can be divided into postpyrolysis and char gasification. Higher pressure accelerated the initial stage of char gasification, and higher gasification reactivity was observed for char derived at 5 MPa. 23 refs., 8 figs., 5 tabs.

  6. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report

    SciTech Connect (OSTI)

    Chunshan Song; Schobert, H.H.; Parfitt, D.P.

    1997-11-01

    Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

  7. Experimental study on NOx emission and unburnt carbon of a radial biased swirl burner for coal combustion

    SciTech Connect (OSTI)

    Shan Xue; Shi'en Hui; Qulan Zhou; Tongmo Xu

    2009-07-15

    Pilot tests were carried out on a 1 MW thermal pulverized coal fired testing furnace. Symmetrical combustion was implemented by use of two whirl burners with dual air adjustment. The burnout air device was installed in various places at the top of the main burner, which consists of a primary air pipe with a varying cross-section and an impact ring. In the primary air pipe, the air pulverized coal (PC) stream was separated into a whirling stream that was thick inside and thin outside, thus realizing the thin-thick distribution at the burner nozzle in the radial direction. From the comparative combustion tests of three coals with relatively great characteristic differences, Shaanbei Shenhua high rank bituminous coal (SH coal), Shanxi Hejin low rank bituminous coal (HJ coal), and Shanxi Changzhi meager coal (CZ coal), were obtained such test results as the primary air ratio, inner secondary air ratio, outer secondary air ratio, impact of the change of outer secondary air, change of the relative position for the layout of burnout air, change of the swirling intensity of the primary air and secondary air, etc., on the NOx emission, and unburnt carbon content in fly ash (CFA). At the same time, the relationship between the NOx emission and burnout ratio and affecting factors of the corresponding test items on the combustion stability and economic results were also acquired. The results may provide a vital guiding significance to engineering designs and practical applications. According to the experimental results, the influence of each individual parameter on NOx formation and unburned carbon in fly ash agrees well with the existing literature. In this study, the influences of various combinations of these parameters are also examined, thus providing some reference for the design of the radial biased swirl burner, the configuration of the furnace, and the distribution of the air. 23 refs., 14 figs., 2 tabs.

  8. Lignin-assisted coal depolymerization. [Final] technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Lalvani, S.B.; Muchmore, C.B.; Koropchak, J.A.; Kim, Jong Won

    1992-12-31

    Liquefaction of an Illinois bituminous and a caustic lignin was studied in an initial hydrogen pressure of 140 psig. Experiments were conducted in the temperature range of 325-375{degree}C in tetralin. The addition of lignin to coal was found to be synergistic in that it significantly improves the quality and yield of the liquid products obtained. Kinetic data for coal conversion enhancement due to lignin addition were obtained. A mathematical model describing the reaction chemistry, using lignin, has been proposed and developed. The analysis of the results indicates that the intermediates produced from lignin were responsible for enhancement in coal depolymerization rate, however, the intermediates are short-lived as compared to the time needed for a significant coal conversion yield. Coal depolymerization rate was found to be a function of time; compared to processing coal alone, it doubled upon reacting coal with lignin at 375{degree}C and after 67 minutes from the beginning of the experiment. Overall mass recoveries of 95--98% of the total mass charged to the reactor were obtained. A careful statistical analysis of the data shows that coal depolymerization yield is enhanced by 11.9% due to the lignin addition. The liquids obtained were examined for their elemental composition, and molecular weight determination by size exclusion chromatography. The stability of liquid products was characterized by determining their solubility in pentane and benzene, and by evaluating the molecular weight.

  9. Engineering Development of Advanced Physical Fine Coal Cleaing for Premium Fuel Applications

    SciTech Connect (OSTI)

    Frank J. Smit; Gene L. Schields; Mehesh C. Jha; Nick Moro

    1997-09-26

    The ash in six common bituminous coals, Taggart, Winifrede, Elkhorn No. 3, Indiana VII, Sunnyside and Hiawatha, could be liberated by fine grinding to allow preparation of clean coal meeting premium fuel specifications (< 1- 2 lb/ MBtu ash and <0.6 lb/ MBtu sulfur) by laboratory and bench- scale column flotation or selective agglomeration. Over 2,100 tons of coal were cleaned in the PDU at feed rates between 2,500 and 6,000 lb/ h by Microcel? column flotation and by selective agglomeration using recycled heptane as the bridging liquid. Parametric testing of each process and 72- hr productions runs were completed on each of the three test coals. The following results were achieved after optimization of the operating parameters: The primary objective was to develop the design base for commercial fine coal cleaning facilities for producing ultra- clean coals which can be converted into coal-water slurry premium fuel. The coal cleaning technologies to be developed were advanced column flotation and selective agglomeration, and the goal was to produce fuel meeting the following specifications -- Less than 2 pounds of ash per million Btu (860 grams per gigajoule) and

  10. Coal and nuclear power: Illinois' energy future

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    This conference was sponsored by the Energy Resources Center, University of Illinois at Chicago; the US Department of Energy; the Illinois Energy Resources Commission; and the Illinois Department of Energy and Natural Resources. The theme for the conference, Coal and Nuclear Power: Illinois' Energy Future, was based on two major observations: (1) Illinois has the largest reserves of bituminous coal of any state and is surpassed in total reserves only by North Dakota, and Montana; and (2) Illinois has made a heavy commitment to the use of nuclear power as a source of electrical power generation. Currently, nuclear power represents 30% of the electrical energy produced in the State. The primary objective of the 1982 conference was to review these two energy sources in view of the current energy policy of the Reagan Administration, and to examine the impact these policies have on the Midwest energy scene. The conference dealt with issues unique to Illinois as well as those facing the entire nation. A separate abstract was prepared for each of the 30 individual presentations.

  11. Production of Substitute Natural Gas from Coal

    SciTech Connect (OSTI)

    Andrew Lucero

    2009-01-31

    The goal of this research program was to develop and demonstrate a novel gasification technology to produce substitute natural gas (SNG) from coal. The technology relies on a continuous sequential processing method that differs substantially from the historic methanation or hydro-gasification processing technologies. The thermo-chemistry relies on all the same reactions, but the processing sequences are different. The proposed concept is appropriate for western sub-bituminous coals, which tend to be composed of about half fixed carbon and about half volatile matter (dry ash-free basis). In the most general terms the process requires four steps (1) separating the fixed carbon from the volatile matter (pyrolysis); (2) converting the volatile fraction into syngas (reforming); (3) reacting the syngas with heated carbon to make methane-rich fuel gas (methanation and hydro-gasification); and (4) generating process heat by combusting residual char (combustion). A key feature of this technology is that no oxygen plant is needed for char combustion.

  12. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

  13. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    that own the scores of coal power plants whose coal ismillion tons in 2006. Coal power plants currently accountan electric generating coal power plant that would be built

  14. Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

    SciTech Connect (OSTI)

    Elmore, B.B.

    1993-08-01

    As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

  15. Coal industry annual 1997

    SciTech Connect (OSTI)

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  16. Controlling mercury emissions from coal-fired power plants

    SciTech Connect (OSTI)

    Chang, R. [Electric Power Research Institute, Palo Alto, CA (United States)

    2009-07-15

    Increasingly stringent US federal and state limits on mercury emissions form coal-fired power plants demand optimal mercury control technologies. This article summarises the successful removal of mercury emissions achieved with activated carbon injection and boiler bromide addition, technologies nearing commercial readiness, as well as several novel control concepts currently under development. It also discusses some of the issues standing in the way of confident performance and cost predictions. In testing conducted on western coal-fired units with fabric filters or TOXECON to date, ACI has generally achieved mercury removal rates > 90%. At units with ESPs, similar performance requires brominated ACI. Alternatively, units firing western coals can use boiler bromide addition to increase flue gas mercury oxidation and downstream capture in a wet scrubber, or to enhance mercury removal by ACI. At eastern bituminous fired units with ESPs, ACI is not as effective, largely due to SO{sub 3} resulting from the high sulfur content of the coal or the use of SO{sub 3} flue gas conditioning to improve ESP performance. 7 refs., 3 figs.

  17. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  18. Coal industry annual 1996

    SciTech Connect (OSTI)

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  19. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

    2006-07-15

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  20. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  1. Modeling the behavior of selenium in Pulverized-Coal Combustion systems

    SciTech Connect (OSTI)

    Senior, Constance; Otten, Brydger Van; Wendt, Jost O.L.; Sarofim, Adel

    2010-11-15

    The behavior of Se during coal combustion is different from other trace metals because of the high degree of vaporization and high vapor pressures of the oxide (SeO{sub 2}) in coal flue gas. In a coal-fired boiler, these gaseous oxides are absorbed on the fly ash surface in the convective section by a chemical reaction. The composition of the fly ash (and of the parent coal) as well as the time-temperature history in the boiler therefore influences the formation of selenium compounds on the surface of the fly ash. A model was created for interactions between selenium and fly ash post-combustion. The reaction mechanism assumed that iron reacts with selenium at temperatures above 1200 C and that calcium reacts with selenium at temperatures less than 800 C. The model also included competing reactions of SO{sub 2} with calcium and iron in the ash. Predicted selenium distributions in fly ash (concentration versus particle size) were compared against measurements from pilot-scale experiments for combustion of six coals, four bituminous and two low-rank coals. The model predicted the selenium distribution in the fly ash from the pilot-scale experiments reasonably well for six coals of different compositions. (author)

  2. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  3. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    flow sheet of a K-T coal gasification complex for producingslag or bottom ash, coal gasification, or coal liquefactionCoal (Ref. 46). COAL PREPARATION GASIFICATION 3 K·T GASI FI

  4. Coal liquefaction

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fairlawn, NJ)

    1985-01-01

    In a two-stage liquefaction wherein coal, hydrogen and liquefaction solvent are contacted in a first thermal liquefaction zone, followed by recovery of an essentially ash free liquid and a pumpable stream of insoluble material, which includes 850.degree. F.+ liquid, with the essentially ash free liquid then being further upgraded in a second liquefaction zone, the liquefaction solvent for the first stage includes the pumpable stream of insoluble material from the first liquefaction stage, and 850.degree. F.+ liquid from the second liquefaction stage.

  5. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxide capture CS Seminars Calendar HomeNETLCareersCoal

  6. Waste Coal Fines Reburn for NOx and Mercury Emission Reduction

    SciTech Connect (OSTI)

    Stephen Johnson; Chetan Chothani; Bernard Breen

    2008-04-30

    Injection of coal-water slurries (CWS) made with both waste coal and bituminous coal was tested for enhanced reduction of NO{sub x} and Hg emissions at the AES Beaver Valley plant near Monaca, PA. Under this project, Breen Energy Solutions (BES) conducted field experiments on the these emission reduction technologies by mixing coal fines and/or pulverized coal, urea and water to form slurry, then injecting the slurry in the upper furnace region of a coal-fired boiler. The main focus of this project was use of waste coal fines as the carbon source; however, testing was also conducted using pulverized coal in conjunction with or instead of waste coal fines for conversion efficiency and economic comparisons. The host site for this research and development project was Unit No.2 at AES Beaver Valley cogeneration station. Unit No.2 is a 35 MW Babcock & Wilcox (B&W) front-wall fired boiler that burns eastern bituminous coal. It has low NO{sub x} burners, overfire air ports and a urea-based selective non-catalytic reduction (SNCR) system for NO{sub x} control. The back-end clean-up system includes a rotating mechanical ash particulate removal and electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber. Coal slurry injection was expected to help reduce NOx emissions in two ways: (1) Via fuel-lean reburning when the slurry is injected above the combustion zone. (2) Via enhanced SNCR reduction when urea is incorporated into the slurry. The mercury control process under research uses carbon/water slurry injection to produce reactive carbon in-situ in the upper furnace, promoting the oxidation of elemental mercury in flue gas from coal-fired power boilers. By controlling the water content of the slurry below the stoichiometric requirement for complete gasification, water activated carbon (WAC) can be generated in-situ in the upper furnace. As little as 1-2% coal/water slurry (heat input basis) can be injected and generate sufficient WAC for mercury capture. During July, August, and September 2007, BES designed, procured, installed, and tested the slurry injection system at Beaver Valley. Slurry production was performed by Penn State University using equipment that was moved from campus to the Beaver Valley site. Waste coal fines were procured from Headwaters Inc. and transported to the site in Super Sacks. In addition, bituminous coal was pulverized at Penn State and trucked to the site in 55-gallon drums. This system was operated for three weeks during August and September 2007. NO{sub x} emission data were obtained using the plant CEM system. Hg measurements were taken using EPA Method 30B (Sorbent Trap method) both downstream of the electrostatic precipitator and in the stack. Ohio Lumex Company was on site to provide rapid Hg analysis on the sorbent traps during the tests. Key results from these tests are: (1) Coal Fines reburn alone reduced NO{sub x} emissions by 0-10% with up to 4% heat input from the CWS. However, the NO{sub x} reduction was accompanied by higher CO emissions. The higher CO limited our ability to try higher reburn rates for further NO{sub x} reduction. (2) Coal Fines reburn with Urea (Carbon enhanced SNCR) decreased NO{sub x} emissions by an additional 30% compared to Urea injection only. (3) Coal slurry injection did not change Hg capture across the ESP at full load with an inlet temperature of 400-430 F. The Hg capture in the ESP averaged 40%, with or without slurry injection; low mercury particulate capture is normally expected across a higher temperature ESP because any oxidized mercury is thought to desorb from the particulate at ESP temperatures above 250 F. (4) Coal slurry injection with halogen salts added to the mixing tank increased the Hg capture in the ESP to 60%. This significant incremental mercury reduction is important to improved mercury capture with hot-side ESP operation and wherever hindrance from sulfur oxides limit mercury reduction, because the higher temperature is above sulfur oxide dew point interference.

  7. Plastic wastes as modifiers of the thermoplasticity of coal

    SciTech Connect (OSTI)

    M.A. Diez; C. Barriocanal; R. Alvarez [Instituto Nacional del Carbon (INCAR), Oviedo (Spain)

    2005-12-01

    Plastic waste recycling represents a major challenge in environmental protection with different routes now available for dealing with mechanical, chemical, and energy recycling. New concepts in plastic waste recycling have emerged so that now such wastes can be used to replace fossil fuels, either as an energy source or as a secondary raw material. Our objective is to explore the modification of the thermoplastic properties of coal in order to assess the possibility of adding plastic waste to coal for the production of metallurgical coke. Two bituminous coals of different rank and thermoplastic properties were used as a base component of blends with plastic wastes such as high-density polyethylene (HDPE), low-density polyethylene (LDPE), polypropylene (PP), polystyrene (PS), poly(ethylene terephthalate) (PET), and acrilonitrile-butadiene-styrene copolymer (ABS). In all cases, the addition of plastic waste led to a reduction in Gieseler maximum fluidity, the extent of the reduction depending on the fluidity of the base coal, and the amount, the molecular structure, and the thermal behavior of the polymer. As a consequence, the amount of volatile matter released by the plastic waste before, during, and after the maximum fluidity of the coal and the hydrogen-donor and hydrogen-acceptor capacities of the polymer were concluded to be key factors in influencing the extent of the reduction in fluidity and the development of anisotropic carbons. The incorporation of the plastic to the carbon matrix was clearly established in semicokes produced from blends of a high-fluid coal and the plastic tested by SEM examination. 42 refs., 10 figs., 7 tabs.

  8. Oxidation of Mercury in Products of Coal Combustion

    SciTech Connect (OSTI)

    Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

    2009-09-14

    Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

  9. Coal Combustion Products | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal Combustion Products Coal Combustion Products Coal combustion products (CCPs) are solid materials produced when coal is burned to generate electricity. Since coal provides the...

  10. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    is produced via coal gasification, then, depending on thenot be amenable to coal gasification and, thus, Eastern coalto represent a coal-to- hydrogen gasification process that

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    transportation component of coal price should also increase;investment. Coal costs and prices are functions of a numberTable 15: Coal Supply, Disposition, and Prices”, http://

  12. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    increase in rail coal transportation costs in the future? (Ythus, the cost of coal transportation via unit trains ischance of the cost of coal transportation increasing are

  13. Hydrogen from Coal Edward Schmetz

    E-Print Network [OSTI]

    Hydrogen from Coal Edward Schmetz Office of Sequestration, Hydrogen and Clean Coal Fuels U-based technology. (a) Based on equal quantities of coal used to produce hydrogen and electricity 4 #12;Why Hydrogen From Coal? Huge U.S. coal reserves Hydrogen can be produced cleanly from coal Coal can provide

  14. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  15. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01

    90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

  16. Survey and conceptual flow sheets for coal conversion plant handling-preparation and ash/slag removal operations

    SciTech Connect (OSTI)

    Zapp, F.C.; Thomas, O.W.; Silverman, M.D.; Dyslin, D.A.; Holmes, J.M.

    1980-03-01

    This study was undertaken at the request of the Fossil Fuel Processing Division of the Department of Energy. The report includes a compilation of conceptual flow sheets, including major equipment lists, and the results of an availability survey of potential suppliers of equipment associated with the coal and ash/slag operations that will be required by future large coal conversion plant complexes. Conversion plant flow sheet operations and related equipment requirements were based on two representative bituminous coals - Pittsburgh and Kentucky No. 9 - and on nine coal conversion processes. It appears that almost all coal handling and preparation and ash/slag removal equipment covered by this survey, with the exception of some coal comminution equipment, either is on hand or can readily be fabricated to meet coal conversion plant capacity requirements of up to 50,000 short tons per day. Equipment capable of handling even larger capacities can be developed. This approach appears to be unjustified, however, because in many cases a reasonable or optimum number of trains of equipment must be considered when designing a conversion plant complex. The actual number of trains of equipment selected will be influenced by the total requied capacity of the complex, the minimum on-line capacity that can be tolerated in case of equipment failure, reliability of specific equipment types, and the number of reactors and related feed injection stations needed for the specific conversion process.

  17. Coal Direct Chemical Looping Retrofit to Pulverized Coal Power Plants for In-Situ CO2 Capture

    SciTech Connect (OSTI)

    Zeng, Liang; Li, Fanxing; Kim, Ray; Bayham, Samuel; McGiveron, Omar; Tong, Andrew; Connell, Daniel; Luo, Siwei; Sridhar, Deepak; Wang, Fei; Sun, Zhenchao; Fan, Liang-Shih

    2013-09-30

    A novel Coal Direct Chemical Looping (CDCL) system is proposed to effectively capture CO2 from existing PC power plants. The work during the past three years has led to an oxygen carrier particle with satisfactory performance. Moreover, successful laboratory, bench scale, and integrated demonstrations have been performed. The proposed project further advanced the novel CDCL technology to sub-pilot scale (25 kWth). To be more specific, the following objectives attained in the proposed project are: 1. to further improve the oxygen carrying capacity as well as the sulfur/ash tolerance of the current (working) particle; 2. to demonstrate continuous CDCL operations in an integrated mode with > 99% coal (bituminous, subbituminous, and lignite) conversion as well as the production of high temperature exhaust gas stream that is suitable for steam generation in existing PC boilers; 3. to identify, via demonstrations, the fate of sulfur and NOx; 4. to conduct thorough techno-economic analysis that validates the technical and economical attractiveness of the CDCL system. The objectives outlined above were achieved through collaborative efforts among all the participants. CONSOL Energy Inc. performed the techno-economic analysis of the CDCL process. Shell/CRI was able to perform feasibility and economic studies on the large scale particle synthesis and provide composite particles for the sub-pilot scale testing. The experience of B&W (with boilers) and Air Products (with handling gases) assisted the retrofit system design as well as the demonstration unit operations. The experience gained from the sub-pilot scale demonstration of the Syngas Chemical Looping (SCL) process at OSU was able to ensure the successful handling of the solids. Phase 1 focused on studies to improve the current particle to better suit the CDCL operations. The optimum operating conditions for the reducer reactor such as the temperature, char gasification enhancer type, and flow rate were identified. The modifications of the existing bench scale reactor were completed in order to use it in the next phase of the project. In Phase II, the optimum looping medium was selected, and bench scale demonstrations were completed using them. Different types of coal char such as those obtained from bituminous, subbituminous, and lignite were tested. Modifications were made on the existing sub-pilot scale unit for coal injection. Phase III focused on integrated CDCL demonstration in the sub-pilot scale unit. A comprehensive ASPEN® simulations and economic analysis was completed by CONSOL t is expected that the CDCL process will be ready for further demonstrations in a scale up unit upon completion of the proposed project.

  18. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    Coal Cleaning Costs Process Clean Coal Produced, * T/D (DryMM$ Net Operating Cost, $/T (Clean Coal Basis) Net OperatingCost, $/T (Clean Coal Bases) Case NA Hazen KVB Battelle

  19. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    Railroads”, Conference on the Future of Coal, U.S. SenateFuture Impacts of Coal Distribution Constraints on Coal Costone at that! -ii- Future Impacts of Coal Distribution

  20. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  1. Coal feed lock

    DOE Patents [OSTI]

    Pinkel, I. Irving (Fairview Park, OH)

    1978-01-01

    A coal feed lock is provided for dispensing coal to a high pressure gas producer with nominal loss of high pressure gas. The coal feed lock comprises a rotor member with a diametral bore therethrough. A hydraulically activated piston is slidably mounted in the bore. With the feed lock in a charging position, coal is delivered to the bore and then the rotor member is rotated to a discharging position so as to communicate with the gas producer. The piston pushes the coal into the gas producer. The rotor member is then rotated to the charging position to receive the next load of coal.

  2. Development and evaluation of coal/water mixture combustion technology. Final report

    SciTech Connect (OSTI)

    Scheffee, R.S.; Rossmeissl, N.P.; Skolnik, E.G.; McHale, E.T.

    1981-08-01

    The objective was to advance the technology for the preparation, storage, handling and combustion of highly-loaded coal/water mixtures. A systematic program to prepare and experimentally evaluate coal/water mixtures was conducted to develop mixtures which (1) burn efficiently using combustion chambers and burners designed for oil, (2) can be provided at a cost less than that of No. 6 oil, and (3) can be easily transported and stored. The program consisted of three principal tasks. The first was a literature survey relevant to coal/water mixture technology. The second involved slurry preparation and evaluation of rheological and stability properties, and processing techniques. The third consisted of combustion tests to characterize equipment and slurry parameters. The first task comprised a complete search of the literature, results of which are tabulated in Appendix A. Task 2 was involved with the evaluation of composition and process variables on slurry rheology and stability. Three bituminous coals, representing a range of values of volatile content, ash content, and hardness were used in the slurries. Task 3 was concerned with the combustion behavior of coal/water slurry. The studies involved first upgrading of an experimental furnace facility, which was used to burn slurry fuels, with emphasis on studying the effect on combustion of slurry properties such as viscosity and particle size, and the effect of equipment parameters such as secondary air preheat and atomization.

  3. Indonesian coal mining

    SciTech Connect (OSTI)

    NONE

    2008-11-15

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  4. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, Gerald W. (Farragut, TN); Lewis, Susan N. (Knoxville, TN)

    1990-01-01

    This invention deals with the solubilization of coal using species of Streptomyces. Also disclosed is an extracellular component from a species of Streptomyces, said component being able to solubilize coal.

  5. International perspectives on coal preparation

    SciTech Connect (OSTI)

    1997-12-31

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  6. Utilization ROLE OF COAL COMBUSTION

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , materials left after combustion of coal in conventional and/ or advanced clean-coal technology combustors and advanced clean-coal technology combustors. This paper describes various coal combustion products produced (FGD) products from pulverized coal and advanced clean-coal technology combustors. Over 70% of the CCPs

  7. Coal gasification apparatus

    DOE Patents [OSTI]

    Nagy, Charles K. (Monaca, PA)

    1982-01-01

    Coal hydrogenation vessel has hydrogen heating passages extending vertically through its wall and opening into its interior.

  8. Method for fluorinating coal

    DOE Patents [OSTI]

    Huston, John L. (Skokie, IL); Scott, Robert G. (Westmont, IL); Studier, Martin H. (Downers Grove, IL)

    1978-01-01

    Coal is fluorinated by contact with fluorine gas at low pressure. After pial fluorination, when the reaction rate has slowed, the pressure is slowly increased until fluorination is complete, forming a solid fluorinated coal of approximate composition CF.sub.1.55 H.sub.0.15. The fluorinated coal and a solid distillate resulting from vacuum pyrolysis of the fluorinated coal are useful as an internal standard for mass spectrometric unit mass assignments from about 100 to over 1500.

  9. Hydrophobic Dewatering of Fine Coal. Topical report, March 1, 1995-March 31, 1997

    SciTech Connect (OSTI)

    Yoon, R.; Sohn, S.; Luttrell, J.; Phillips, D.

    1997-12-31

    Many advanced fine coal cleaning technologies have been developed in recent years under the auspices of the U.S. Department of Energy. However, they are not as widely deployed in industry as originally anticipated. An important reason for this problem is that the cleaned coal product is difficult to dewater because of the large surface area associated with fine particles. Typically, mechanical dewatering, such as vacuum filtration and centrifugation, can reduce the moisture to 20-35% level, while thermal drying is costly. To address this important industrial problem, Virginia Tech has developed a novel dewatering process, in which water is displaced from the surface of fine particulate materials by liquid butane. Since the process is driven by the hydrophobic interaction between coal and liquid butane, it was referred to as hydrophobic dewatering (HD). A fine coal sample with 21.4 pm median size was subjected to a series of bench-scale HD tests. It was a mid-vol bituminous coal obtained from the Microcel flotation columns operating at the Middle Fork coal preparation plant, Virginia. All of the test results showed that the HD process can reduce the moisture to substantially less than 10%. The process is sensitive to the amount of liquid butane used in the process relative to the solids concentration in the feed stream. Neither the intensity nor the time of agitation is critical for the process. Also, the process does not require long time for phase separation. Under optimal operating conditions, the moisture of the fine coal can be reduced to 1% by weight of coal.

  10. Coal production 1989

    SciTech Connect (OSTI)

    Not Available

    1990-11-29

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  11. Analysis of mass loss of a coal particle during the course of burning in a flow of inert material

    SciTech Connect (OSTI)

    Pelka, Piotr

    2009-08-15

    This paper is an attempt to explain the role of erosion during the process of coal combustion in a circulating fluidized bed. Different kinds of carbon deposits found in Poland, both bituminous as well as lignite with the particle of 10 mm in diameter were the subject of the research. According to many publications it is well known that erosion plays a significant role in coal combustion, by changing its mechanism as well as generating an additional mass loss of the mother particle. The purpose of this research was to determine the influence of an inert material on an erosive mass loss of a single coal particle burning in a two-phase flow. The determination of the influence of a coal type, the rate of flow of inert material and the temperature inside the furnace on the erosive mass loss of burning coal particle was also taken into consideration. The results obtained indicate that the velocity of the erosive mass loss depends on the chemical composition and petrographic structure of burning coal. The mechanical interaction of inert and burning coal particles leads to the shortening of the period of overall mass loss of the coal particle by even two times. The increase in the rate of flow of the inert material intensifies the generation of mass loss by up to 100%. The drop in temperature which slows down the combustion process, decreases the mass loss of the coal particle as the result of mechanical interaction of the inert material. As was observed, the process of percolation plays a significant role by weakening the surface of the burning coal. (author)

  12. Coal recovery process

    DOE Patents [OSTI]

    Good, Robert J. (Grand Island, NY); Badgujar, Mohan (Williamsville, NY)

    1992-01-01

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  13. Coal: the new black

    SciTech Connect (OSTI)

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  14. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    coal type mining. Production by coal type Since 1980, China maximizedthe production shares of coal types, the shares of different

  15. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    power plant pulverized coal power plant v Advanced Coal WindMW coal gasification combined cycle power plant equippedMW coal gasification, combined cycle power plant equipped

  16. Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process

    SciTech Connect (OSTI)

    McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-06-01

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

  17. Co-pyrolysis of low rank coals and biomass: Product distributions

    SciTech Connect (OSTI)

    Soncini, Ryan M.; Means, Nicholas C.; Weiland, Nathan T.

    2013-10-01

    Pyrolysis and gasification of combined low rank coal and biomass feeds are the subject of much study in an effort to mitigate the production of green house gases from integrated gasification combined cycle (IGCC) systems. While co-feeding has the potential to reduce the net carbon footprint of commercial gasification operations, the effects of co-feeding on kinetics and product distributions requires study to ensure the success of this strategy. Southern yellow pine was pyrolyzed in a semi-batch type drop tube reactor with either Powder River Basin sub-bituminous coal or Mississippi lignite at several temperatures and feed ratios. Product gas composition of expected primary constituents (CO, CO{sub 2}, CH{sub 4}, H{sub 2}, H{sub 2}O, and C{sub 2}H{sub 4}) was determined by in-situ mass spectrometry while minor gaseous constituents were determined using a GC-MS. Product distributions are fit to linear functions of temperature, and quadratic functions of biomass fraction, for use in computational co-pyrolysis simulations. The results are shown to yield significant nonlinearities, particularly at higher temperatures and for lower ranked coals. The co-pyrolysis product distributions evolve more tar, and less char, CH{sub 4}, and C{sub 2}H{sub 4}, than an additive pyrolysis process would suggest. For lignite co-pyrolysis, CO and H{sub 2} production are also reduced. The data suggests that evolution of hydrogen from rapid pyrolysis of biomass prevents the crosslinking of fragmented aromatic structures during coal pyrolysis to produce tar, rather than secondary char and light gases. Finally, it is shown that, for the two coal types tested, co-pyrolysis synergies are more significant as coal rank decreases, likely because the initial structure in these coals contains larger pores and smaller clusters of aromatic structures which are more readily retained as tar in rapid co-pyrolysis.

  18. Coal sector profile

    SciTech Connect (OSTI)

    Not Available

    1990-06-05

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  19. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect (OSTI)

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  20. RESEARCH & DEVELOPMENT TO PREPARE AND CHARACTERIZE ROBUST COAL/BIOMASS MIXTURES FOR DIRECT CO-FEEDING INTO GASIFICATION SYSTEMS

    SciTech Connect (OSTI)

    Felix, Larry; Farthing, William; Hoekman, S. Kent

    2014-12-31

    This project was initiated on October 1, 2010 and utilizes equipment and research supported by the Department of Energy, National Energy Technology Laboratory, under Award Number DE- FE0005349. It is also based upon previous work supported by the Department of Energy, National Energy Technology Laboratory, under Award Numbers DOE-DE-FG36-01GOl1082, DE-FG36-02G012011 or DE-EE0000272. The overall goal of the work performed was to demonstrate and assess the economic viability of fast hydrothermal carbonization (HTC) for transforming lignocellulosic biomass into a densified, friable fuel to gasify like coal that can be easily blended with ground coal and coal fines and then be formed into robust, weather-resistant pellets and briquettes. The specific objectives of the project include: • Demonstration of the continuous production of a uniform densified and formed feedstock from loblolly pine (a lignocellulosic, short rotation woody crop) in a hydrothermal carbonization (HTC) process development unit (PDU). • Demonstration that finely divided bituminous coal and HTC loblolly pine can be blended to form 90/10 and 70/30 weight-percent mixtures of coal and HTC biomass for further processing by pelletization and briquetting equipment to form robust weather resistant pellets and/or briquettes suitable for transportation and long term storage. • Characterization of the coal-biomass pellets and briquettes to quantify their physical properties (e.g. flow properties, homogeneity, moisture content, particle size and shape), bulk physical properties (e.g. compressibility, heat transfer and friability) and assess their suitability for use as fuels for commercially-available coal gasifiers. • Perform economic analyses using Aspen-based process simulations to determine the costs for deploying and operating HTC processing facilities for the production of robust coal/biomass fuels suitable for fueling commercially-available coal-fired gasifiers. This Final Project Scientific/Technical Report discusses and documents the project work required to meet each of these objectives.

  1. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    Council (NCC), 2006, “Coal: America’s Energy Future”, VolumeCan Coal Deliver? America’s Coal Potential & Limits”, Studycoal generating units currently in operation throughout North America (

  2. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    5 Figure 1: Map of U.S. coal plants and generating1: Map of U.S. coal plants and generating units (GED, 2006a)of an electric generating coal power plant that would be

  3. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    than those of other coal types, depending on the location oftrue that different coal types (in terms of heating values,= installed capacity of i-type coal plants [GW]; HR i = heat

  4. Pulverized coal fuel injector

    DOE Patents [OSTI]

    Rini, Michael J. (Hebron, CT); Towle, David P. (Windsor, CT)

    1992-01-01

    A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

  5. Clean Coal Projects (Virginia)

    Broader source: Energy.gov [DOE]

    This legislation directs the Virginia Air Pollution Control Board to facilitate the construction and implementation of clean coal projects by expediting the permitting process for such projects.

  6. Balancing coal pipes

    SciTech Connect (OSTI)

    Earley, D.; Kirkenir, B.

    2009-11-15

    Balancing coal flow to the burners to optimise combustion by using real-time measurement systems (such as microwave mass measurement) is discussed. 3 figs.

  7. Coal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    capture, utilization and sequestration. Featured Energy Secretary Moniz Visits Clean Coal Facility in Mississippi On Friday, Nov. 8, 2013, Secretary Moniz and international...

  8. Coal liquefaction quenching process

    DOE Patents [OSTI]

    Thorogood, Robert M. (Macungie, PA); Yeh, Chung-Liang (Bethlehem, PA); Donath, Ernest E. (St. Croix, VI)

    1983-01-01

    There is described an improved coal liquefaction quenching process which prevents the formation of coke with a minimum reduction of thermal efficiency of the coal liquefaction process. In the process, the rapid cooling of the liquid/solid products of the coal liquefaction reaction is performed without the cooling of the associated vapor stream to thereby prevent formation of coke and the occurrence of retrograde reactions. The rapid cooling is achieved by recycling a subcooled portion of the liquid/solid mixture to the lower section of a phase separator that separates the vapor from the liquid/solid products leaving the coal reactor.

  9. Rail Coal Transportation Rates

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Recurring Reserves Stocks All reports Browse by Tag Alphabetical Frequency Tag Cloud Data For: 2001 Next Release Date: October 2003 U. S. Coal-Producing Districts...

  10. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    coal (PC) or integrated gasification combined cycle ( IGCC)coal (PC) or integrated gasification combined cycle (IGCC)will be integrated gasification combined cycle (IGCC) (Same

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    minerals Metallic ores Coal Crude petroleum Gasoline FuelMetallic ores and concentrates Coal Crude Petroleum Gasoline and aviation turbine fuel

  12. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    Credit Extra Fuel Oil Coal to gasifier Na cost· Na processoiL Replace res. with coal as gasifier feed. 543 ton/day @$

  13. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01

    Corporation, 5-25~79. on Coal Liquefaction at ChevronHamersma, et a L, "Meyers Process for Coal Desulfurization,"in Wheelock, Coal Desulfurization, ACS Symp. Ser 64 (1977(.

  14. Rates of low-pH biological Fe(II) oxidation in the Appalachian Bituminous Coal Basin and the Iberian Pyrite Belt

    E-Print Network [OSTI]

    Burgos, William

    with metal mining, such as the Berkley Pit in Montana(Gammons et al., 2010; Pellicori et al., 2005), Iron(II) oxidation can be exploited for the treatment of acid mine drainage (AMD). However, nat- ural or engineered terraced iron formations (TIFs) are underutilized for AMD treatment because of uncer- tainties with respect

  15. Illinois Coal Development Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Illinois Coal Development Program seeks to advance promising clean coal technologies beyond research and towards commercialization. The program provides a 50/50 match with private industry...

  16. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01

    10%. These two properties can be used to classify coals forsulfur in the coal to be burned. Other properties, such as

  17. Clean coal technologies market potential

    SciTech Connect (OSTI)

    Drazga, B. (ed.)

    2007-01-30

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  18. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, Wendell H. (Kaysville, UT); Oblad, Alex G. (Salt Lake City, UT); Shabtai, Joseph S. (Salt Lake City, UT)

    1994-01-01

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400.degree. C. at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1.

  19. Mechanochemical hydrogenation of coal

    DOE Patents [OSTI]

    Yang, Ralph T. (Tonawanda, NY); Smol, Robert (East Patchogue, NY); Farber, Gerald (Elmont, NY); Naphtali, Leonard M. (Washington, DC)

    1981-01-01

    Hydrogenation of coal is improved through the use of a mechanical force to reduce the size of the particulate coal simultaneously with the introduction of gaseous hydrogen, or other hydrogen donor composition. Such hydrogen in the presence of elemental tin during this one-step size reduction-hydrogenation further improves the yield of the liquid hydrocarbon product.

  20. Coal liquefaction process

    DOE Patents [OSTI]

    Carr, Norman L. (Allison Park, PA); Moon, William G. (Cheswick, PA); Prudich, Michael E. (Pittsburgh, PA)

    1983-01-01

    A C.sub.5 -900.degree. F. (C.sub.5 -482.degree. C.) liquid yield greater than 50 weight percent MAF feed coal is obtained in a coal liquefaction process wherein a selected combination of higher hydrogen partial pressure, longer slurry residence time and increased recycle ash content of the feed slurry are controlled within defined ranges.

  1. Coal. [Great Plains Project

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    The status of various research projects related to coal is considered: gasification (approximately 30 processes) and in-situ gasification. Methanol production, retrofitting internal combustion engines to stratified charge engines, methanation (Conoco), direct reduction of iron ores, water resources, etc. Approximately 200 specific projects related to coal are considered with respect to present status. (LTN)

  2. Cooperative research program in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.

    1991-01-01

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  3. Coal in China

    SciTech Connect (OSTI)

    Minchener, A.J. [IEA Clean Coal Centre, London (United Kingdom)

    2005-07-01

    The article gives an overview of the production and use of coal in China, for power generation and in other sectors. Coal use for power generation was 850 million tonnes in 2003 and 800 million tonnes in the non-power sector. The majority of power will continue to be produced from coal, with a trend towards new larger pulverised coal fired units and introduction of circulating fluidised bed combustors. Stricter regulations are forcing introduction of improved pollution control technologies. It seems likely that China will need international finance to supplement private and state investment to carry out a programme to develop and apply clean coal technologies. The author concludes that there is evidence of a market economy being established but there is a need to resolve inconsistencies with the planned aspects of the economy and that additional policies are needed in certain sectors to achieve sustainable development. 1 ref., 2 figs., 2 tabs.

  4. State coal profiles, January 1994

    SciTech Connect (OSTI)

    Not Available

    1994-02-02

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  5. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    coal are least expensive when produced from the Powder River Basin region, where cheaper surface mining

  6. Clean coal technology: The new coal era

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

  7. Determination of the effects caused by different polymers on coal fluidity during carbonization using high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel Castro Diaz; Lucky Edecki; Karen M. Steel; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2008-01-15

    The effects of blending polyethylene (PE), polystyrene (PS), poly(ethyleneterephthalate) (PET), a flexible polyurethane (FPU), and a car shredded fluff waste (CSF) on fluidity development of a bituminous coal during carbonization have been studied by means of high-torque, small-amplitude controlled-strain rheometry and in situ high-temperature {sup 1}H NMR spectroscopy. The most detrimental effects were caused by PET and PS, which completely destroyed the fluidity of the coal. The CSF had a deleterious effect on coal fluidity similar to that of PET, although the deleterious effect on the viscoelastic properties of the coal were less pronounced than those of PET and PS. On the contrary, the addition of 10 wt % PE caused a slight reduction in the concentration of fluid hydrogen and an increase in the minimum complex viscosity, and the addition of 10 wt % FPU reduced the concentration of fluid hydrogen without changing the viscoelastic properties of the coal. Although these results suggest that these two plastics could potentially be used as additives in coking blends without compromising coke porosity, it was found that the semicoke strengths were reduced by adding 2 wt % FPU and 5 wt % PE. Therefore, it is unlikely that more than 2 wt % of a plastic waste could be added to a coal blend without deterioration in coke quality. 35 refs., 11 figs., 3 tabs.

  8. Consensus Coal Production Forecast for

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Consensus Coal Production Forecast for West Virginia 2009-2030 Prepared for the West Virginia Summary 1 Recent Developments 2 Consensus Coal Production Forecast for West Virginia 10 Risks References 27 #12;W.Va. Consensus Coal Forecast Update 2009 iii List of Tables 1. W.Va. Coal Production

  9. Aqueous coal slurry

    SciTech Connect (OSTI)

    Berggren, M.H.; Smit, F.J.; Swanson, W.W.

    1989-10-30

    A principal object of the invention is the provision of an aqueous coal slurry containing a dispersant, which is of low-cost and which contains very low or no levels of sodium, potassium, sulfur and other contaminants. In connection with the foregoing object, it is an object of the invention to provide an aqueous slurry containing coal and dextrin as a dispersant and to provide a method of preparing an aqueous coal slurry which includes the step of adding an effective amount of dextrin as a dispersant. The invention consists of certain novel features and a combination of parts hereinafter fully described, and particularly pointed out in the appended claims. 6 tabs.

  10. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, Charles H. (Overland Park, KS)

    1986-01-01

    A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

  11. Clean coal today

    SciTech Connect (OSTI)

    none,

    1990-01-01

    This is the first issue of the Clean Coal Today publication. Each issue will provide project status reports, feature articles about certain projects and highlight key events concerning the US Clean Coal Technology Demonstration Program. Projects described in this publication include: Colorado-Ute Electric Association Circulating Fluidized Bed Combustor Project at Nucla, Colorado; Babcock and Wilcox coolside and limestone injection multistage burner process (dry sorbent injection); Coal Tech's Advanced Cyclone Combustor Project; and the TIDD pressurized fluidized bed combustor combined cycle facility in Brilliant, Ohio. The status of other projects is included.

  12. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, C.H.

    1986-02-11

    A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

  13. Lawrence Livermore National Laboratory underground coal gasification data base. [US DOE-supported field tests; data

    SciTech Connect (OSTI)

    Cena, R. J.; Thorsness, C. B.

    1981-08-21

    The Department of Energy has sponsored a number of field projects to determine the feasibility of converting the nation's vast coal reserves into a clean efficient energy source via underground coal gasification (UCG). Due to these tests, a significant data base of process information has developed covering a range of coal seams (flat subbituminous, deep flat bituminous and steeply dipping subbituminous) and processing techniques. A summary of all DOE-sponsored tests to data is shown. The development of UCG on a commercial scale requires involvement from both the public and private sectors. However, without detailed process information, accurate assessments of the commercial viability of UCG cannot be determined. To help overcome this problem the DOE has directed the Lawrence Livermore National Laboratory (LLNL) to develop a UCG data base containing raw and reduced process data from all DOE-sponsored field tests. It is our intent to make the data base available upon request to interested parties, to help them assess the true potential of UCG.

  14. PULSE COMBUSTOR DESIGN QUALIFICATION TEST AND CLEAN COAL FEEDSTOCK TEST - VOLUME I AND VOLUME II

    SciTech Connect (OSTI)

    Unknown

    2002-02-08

    For this Cooperative Agreement, the pulse heater module is the technology envelope for an indirectly heated steam reformer. The field of use of the steam reformer pursuant to this Cooperative Agreement with DOE is for the processing of sub-bituminous coals and lignite. The main focus is the mild gasification of such coals for the generation of both fuel gas and char--for the steel industry is the main focus. An alternate market application for the substitution of metallurgical coke is also presented. This project was devoted to qualification of a 253-tube pulse heater module. This module was designed, fabricated, installed, instrumented and tested in a fluidized bed test facility. Several test campaigns were conducted. This larger heater is a 3.5 times scale-up of the previous pulse heaters that had 72 tubes each. The smaller heater has been part of previous pilot field testing of the steam reformer at New Bern, North Carolina. The project also included collection and reduction of mild gasification process data from operation of the process development unit (PDU). The operation of the PDU was aimed at conditions required to produce char (and gas) for the Northshore Steel Operations. Northshore Steel supplied the coal for the process unit tests.

  15. Advanced coal-fueled gas turbine systems. Annual report, July 1991--June 1992

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    Westinghouse`s Advanced Coal-Fueled Gas Turbine System Program (DE-AC2l-86MC23167) was originally split into two major phases - a Basic Program and an Option. The Basic Program also contained two phases. The development of a 6 atm, 7 lb/s, 12 MMBtu/hr slagging combustor with an extended period of testing of the subscale combustor, was the first part of the Basic Program. In the second phase of the Basic Program, the combustor was to be operated over a 3-month period with a stationary cascade to study the effect of deposition, erosion and corrosion on combustion turbine components. The testing of the concept, in subscale, has demonstrated its ability to handle high- and low-sulfur bituminous coals, and low-sulfur subbituminous coal. Feeding the fuel in the form of PC has proven to be superior to CWM type feed. The program objectives relative to combustion efficiency, combustor exit temperature, NO{sub x} emissions, carbon burnout, and slag rejection have been met. Objectives for alkali, particulate, and SO{sub x} levels leaving the combustor were not met by the conclusion of testing at Textron. It is planned to continue this testing, to achieve all desired emission levels, as part of the W/NSP program to commercialize the slagging combustor technology.

  16. Recent advances in coal geochemistry

    SciTech Connect (OSTI)

    Chyi, L.L. (Dept. of Geology, Univ. of Akron, Akron, OH (US)); Chou, C.-L. (Illinois State Geological Survey, 615 E. Peabody Drive, Champaign, IL (US))

    1990-01-01

    Chapters in this collection reflect the recent emphasis both on basic research in coal geochemistry and on applied aspects related to coal utilization. Geochemical research on peat and coal generates compositional data that are required for the following reasons. First, many studies in coal geology require chemical data to aid in interpretation for better understanding of the origin and evolution of peat and coal. Second, coal quality assessment is based largely on composition data, and these data generate useful insights into the geologic factors that control the quality of coal. Third, compositional data are needed for effective utilization of coal resources and to reflect the recent emphasis on both basic research in coal geochemistry and environmental aspects related to coal utilization.

  17. PressurePressure Indiana Coal Characteristics

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    TimeTime PressurePressure · Indiana Coal Characteristics · Indiana Coals for Coke · Coal Indiana Total Consumption Electricity 59,664 Coke 4,716 Industrial 3,493 Major Coal- red power plantsTransportation in Indiana · Coal Slurry Ponds Evaluation · Site Selection for Coal Gasification · Coal-To-Liquids Study, CTL

  18. Aqueous coal slurry

    SciTech Connect (OSTI)

    Berggren, Mark H.; Smit, Francis J.; Swanson, Wilbur W.

    1993-04-06

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  19. Aqueous coal slurry

    DOE Patents [OSTI]

    Berggren, Mark H. (Golden, CO); Smit, Francis J. (Arvada, CO); Swanson, Wilbur W. (Golden, CO)

    1993-01-01

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  20. Clean Coal Technology (Indiana)

    Broader source: Energy.gov [DOE]

    A public utility may not use clean coal technology at a new or existing electric generating facility without first applying for and obtaining from the Utility Regulatory Commission a certificate...

  1. Quarterly coal report

    SciTech Connect (OSTI)

    Young, P.

    1996-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  2. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, W.H.; Oblad, A.G.; Shabtai, J.S.

    1994-05-03

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400 C at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1. 1 figures.

  3. Coal liquefaction process

    DOE Patents [OSTI]

    Skinner, Ronald W. (Allentown, PA); Tao, John C. (Perkiomenville, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01

    This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

  4. Pressurized chemical-looping combustion of coal with an iron ore-based oxygen carrier

    SciTech Connect (OSTI)

    Xiao, Rui; Song, Min; Zhang, Shuai; Shen, Laihong [School of Energy and Environment, Southeast University, Sipailou No. 2, Nanjing 210096 (China); Song, Qilei [School of Energy and Environment, Southeast University, Sipailou No. 2, Nanjing 210096 (China); Department of Chemical Engineering and Biotechnology, University of Cambridge, Pembroke Street, Cambridge CB2 3RA (United Kingdom); Lu, Zuoji [School of Energy and Environment, Southeast University, Sipailou No. 2, Nanjing 210096 (China); GCL Engineering Limited, Zhujiang No. 1, Nanjing 210008 (China)

    2010-06-15

    Chemical-looping combustion (CLC) is a new combustion technology with inherent separation of CO{sub 2}. Most of the previous investigations on CLC of solid fuels were conducted under atmospheric pressure. A pressurized CLC combined cycle (PCLC-CC) system is proposed as a promising coal combustion technology with potential higher system efficiency, higher fuel conversion, and lower cost for CO{sub 2} sequestration. In this study pressurized CLC of coal with Companhia Valedo Rio Doce (CVRD) iron ore was investigated in a laboratory fixed bed reactor. CVRD iron ore particles were exposed alternately to reduction by 0.4 g of Chinese Xuzhou bituminous coal gasified with 87.2% steam/N{sub 2} mixture and oxidation with 5% O{sub 2} in N{sub 2} at 970 C. The operating pressure was varied between 0.1 MPa and 0.6 MPa. First, control experiments of steam coal gasification over quartz sand were performed. H{sub 2} and CO{sub 2} are the major components of the gasification products, and the operating pressure influences the gas composition. Higher concentrations of CO{sub 2} and lower fractions of CO, CH{sub 4}, and H{sub 2} during the reduction process with CVRD iron ore was achieved under higher pressures. The effects of pressure on the coal gasification rate in the presence of the oxygen carrier were different for pyrolysis and char gasification. The pressurized condition suppresses the initial coal pyrolysis process while it also enhances coal char gasification and reduction with iron ore in steam, and thus improves the overall reaction rate of CLC. The oxidation rates and variation of oxygen carrier conversion are higher at elevated pressures reflecting higher reduction level in the previous reduction period. Scanning electron microscope and energy-dispersive X-ray spectroscopy (SEM-EDX) analyses show that particles become porous after experiments but maintain structure and size after several cycles. Agglomeration was not observed in this study. An EDX analysis demonstrates that there is very little coal ash deposited on the oxygen carrier particles but no appreciable crystalline phases change as verified by X-ray diffraction (XRD) analysis. Overall, the limited pressurized CLC experiments carried out in the present work suggest that PCLC of coal is promising and further investigations are necessary. (author)

  5. Coal desulfurization in a rotary kiln combustor. Final report, March 15, 1990--July 31, 1991

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.

    1992-09-11

    The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

  6. The El Tremedal underground coal gasification field test in Spain. First trial at great depth and high pressure

    SciTech Connect (OSTI)

    Chappell, R. [AEA Technology plc, Harwell (United Kingdom); Mostade, M. [Institution pour le Developpement de la Gazeification, Liege (Belgium)

    1998-12-31

    The El Tremedal Underground Coal Gasification (UCG) trial sponsored by Belgian, Spanish and United Kingdom government organizations and the European Community has conducted two gasification phases during the summer-autumn of 1997, of nine and five days duration respectively. A gas of good quality has been obtained on both occasions. During the active gasification phases, which lasted in total 12.1 days, an estimated 237.2 tonnes of coal moisture-ash-free were affected and an average power of 2.64 MW based on the lower calorific value of the product gas was developed underground. The test utilized oxygen and nitrogen as the injection reactants (no steam injection). Access to the 2--3 meters sub-bituminous coal seam situated at an average depth of 560 meters was provided by an in-seam deviated well drilled close to the bottom of the 29 degrees dipping seam. A vertical well was used for the exhaust of the gasification products and the production counter-pressure was maintained in near equilibrium with the underground hydrostatic head (50--54 bars). Three Controlled Retraction Ignition Point (CRIP) maneuvers were achieved. Analysis of the raw process data was conducted to calculate mass and energy balances, and to determine influences of process conditions on gas composition, shift and methanation equilibrium, water influx and oxygen/coal conversion efficiencies.

  7. WEAR RESISTANT ALLOYS FOR COAL HANDLING EQUIPMENT

    E-Print Network [OSTI]

    Bhat, M.S.

    2011-01-01

    Proceedings of the Conference on Coal Feeding Systems, HeldWear Resistant Alloys for Coal Handling Equipment", proposalWear Resistant Alloys for Coal Handling Equi pment". The

  8. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    mines in China lowers the coal recovery rate and increasesthat China’s average coal recovery rate is 30% nationallyimproved aggregate coal recovery rates and local- scale

  9. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    of deploying advanced coal power in the Chinese context,”12 2.6. International coal prices and12 III. Chinese Coal

  10. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    of Figures Figure ES-1. Advanced Coal Wind Hybrid: Basicviii Figure 1. Advanced-Coal Wind Hybrid: Basic29 Figure 9. Sensitivity to Coal

  11. Coal Gasification and Transportation Fuels Magazine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol.1, Issue 4 (July 2015) Archived Editions: Coal...

  12. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    19 3.4. Coking coal for iron & steels FOB export value for coking coal was relatively stables FOB export value for coking coal significantly increased

  13. The fate of alkali species in advanced coal conversion systems

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950[degree]C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800[degree] to 950[degree]C, the concentrations of vapor phase sodium species (Na, Na[sub 2]O, NaCl, and Na[sub 2]SO[sub 4]) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820[degree]. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na[sub 2]SO[sub 4] increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 [mu]m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  14. Method of extracting coal from a coal refuse pile

    DOE Patents [OSTI]

    Yavorsky, Paul M. (Monongahela, PA)

    1991-01-01

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  15. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" © CEP Aug. 78. Feed

  16. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    2 Syngas (H2 + CO + CO2) Coal Gasifier coal Fuel Production/2 Syngas (H2 + CO + CO2) Coal Gasifier coal Fuel Production/this operational mode, the gasifiers and other parts of the

  17. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    pollution. With coal and liquid transport fuel deficits in26 3.6. Coal-to-liquids and coal-to-70 million tonnes and coal-to-liquids capacity reaches 60

  18. Coal Problems 1. Name two examples of clean coal technology and in what manner do they clean the coal?

    E-Print Network [OSTI]

    Bowen, James D.

    Coal Problems 1. Name two examples of clean coal technology and in what manner do they clean the coal? a. Coal Washing- Crushing coal then mixing it with a liquid to allow the impurities to settle. b burning coal altogether. With integrated gasification combined cycle (IGCC) systems, steam and hot

  19. Composition and properties of coals from the Yurty coal occurrence

    SciTech Connect (OSTI)

    N.G. Vyazova; L.N. Belonogova; V.P. Latyshev; E.A. Pisar'kova [Irkutsk State University, Irkutsk (Russia). Research Institute of Oil and Coal Chemistry and Synthesis

    2008-10-15

    Coals from the Yurty coal occurrence were studied. It was found that the samples were brown non-coking coals with low sulfur contents (to 1%) and high yields of volatile substances. The high heat value of coals was 20.6-27.7 MJ/kg. The humic acid content varied from 5.45 to 77.62%. The mineral matter mainly consisted of kaolinite, a-quartz, and microcline. The concentration of toxic elements did not reach hazardous values.

  20. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    application of new clean coal technologies with near zeroapplication of new clean coal technologies with near zero

  1. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    Natural Gas Coal 233 billion tonnes coal equivalent 97% total fossil fuel reserve base Reserves by location, quality,

  2. Coal and Coal-Biomass to Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAuditsCluster Compatibility Mode Cluster CompatibilityCoal Markets

  3. Pyrolysis of coal

    DOE Patents [OSTI]

    Babu, Suresh P. (Willow Springs, IL); Bair, Wilford G. (Morton Grove, IL)

    1992-01-01

    A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

  4. Healy Clean Coal Project

    SciTech Connect (OSTI)

    None

    1997-12-31

    The Healy Clean Coal Project, selected by the U.S. Department of Energy under Round 111 of the Clean Coal Technology Program, has been constructed and is currently in the Phase 111 Demonstration Testing. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the U.S. Department of Energy. Construction was 100% completed in mid-November of 1997, with coal firing trials starting in early 1998. Demonstration testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of nitrogen oxides (NOx), sulfur dioxide (S02), and particulate from this 50-megawatt plant are expected to be significantly lower than current standards.

  5. Hydroliquefaction of coal

    DOE Patents [OSTI]

    Sze, Morgan C. (Upper Montclair, NJ); Schindler, Harvey D. (Fairlawn, NJ)

    1982-01-01

    Coal is catalytically hydroliquefied by passing coal dispersed in a liquefaction solvent and hydrogen upwardly through a plurality of parallel expanded catalyst beds, in a single reactor, in separate streams, each having a cross-sectional flow area of no greater than 255 inches square, with each of the streams through each of the catalyst beds having a length and a liquid and gas superficial velocity to maintain an expanded catalyst bed and provide a Peclet Number of at least 3. If recycle is employed, the ratio of recycle to total feed (coal and liquefaction solvent) is no greater than 2:1, based on volume. Such conditions provide for improved selectivity to liquid product to thereby reduce hydrogen consumption. The plurality of beds are formed by partitions in the reactor.

  6. Dry cleaning of Turkish coal

    SciTech Connect (OSTI)

    Cicek, T. [Dokuz Eylul University, Izmir (Turkey). Faculty of Engineering

    2008-07-01

    This study dealt with the upgrading of two different type of Turkish coal by a dry cleaning method using a modified air table. The industrial size air table used in this study is a device for removing stones from agricultural products. This study investigates the technical and economical feasibility of the dry cleaning method which has never been applied before on coals in Turkey. The application of a dry cleaning method on Turkish coals designated for power generation without generating environmental pollution and ensuring a stable coal quality are the main objectives of this study. The size fractions of 5-8, 3-5, and 1-3 mm of the investigated coals were used in the upgrading experiments. Satisfactory results were achieved with coal from the Soma region, whereas the upgrading results of Hsamlar coal were objectionable for the coarser size fractions. However, acceptable results were obtained for the size fraction 1-3 mm of Hsamlar coal.

  7. The world price of coal

    E-Print Network [OSTI]

    Ellerman, A. Denny

    1994-01-01

    A significant increase in the seaborne trade for coal over the past twenty years has unified formerly separate coal markets into a world market in which prices move in tandem. Due to its large domestic market, the United ...

  8. 2009 Coal Age Buyers Guide

    SciTech Connect (OSTI)

    2009-07-15

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  9. 2008 Coal Age buyers guide

    SciTech Connect (OSTI)

    2008-07-15

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  10. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  11. Underground coal gasification. Presentations

    SciTech Connect (OSTI)

    NONE

    2007-07-01

    The 8 presentations are: underground coal gasification (UCG) and the possibilities for carbon management (J. Friedmann); comparing the economics of UCG with surface gasification technologies (E. Redman); Eskom develops UCG technology project (C. Gross); development and future of UCG in the Asian region (L. Walker); economically developing vast deep Powder River Basin coals with UCG (S. Morzenti); effectively managing UCG environmental issues (E. Burton); demonstrating modelling complexity of environmental risk management; and UCG research at the University of Queensland, Australia (A.Y. Klimenko).

  12. Clean Coal Power Initiative

    SciTech Connect (OSTI)

    Doug Bartlett; Rob James; John McDermott; Neel Parikh; Sanjay Patnaik; Camilla Podowski

    2006-03-31

    This report is the fifth quarterly Technical Progress Report submitted by NeuCo, Incorporated, under Award Identification Number, DE-FC26-04NT41768. This award is part of the Clean Coal Power Initiative (''CCPI''), the ten-year, $2B initiative to demonstrate new clean coal technologies in the field. This report is one of the required reports listed in Attachment B Federal Assistance Reporting Checklist, part of the Cooperative Agreement. The report covers the award period January 1, 2006 - March 31, 2006 and NeuCo's efforts within design, development, and deployment of on-line optimization systems during that period.

  13. PNNL Coal Gasification Research

    SciTech Connect (OSTI)

    Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

    2010-07-28

    This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

  14. Coal Research FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAuditsCluster Compatibility Mode Cluster CompatibilityCoal Markets ReleaseCoal

  15. CONSORTIUM FOR CLEAN COAL UTILIZATION

    E-Print Network [OSTI]

    Subramanian, Venkat

    1 CONSORTIUM FOR CLEAN COAL UTILIZATION Request for Proposals Date of Issue: February 16, 2015 The Consortium for Clean Coal Utilization (CCCU) at Washington University in St. Louis was established in January of 2009. The mission of the CCCU is to enable environmentally benign and sustainable use of coal, both

  16. CONSORTIUM FOR CLEAN COAL UTILIZATION

    E-Print Network [OSTI]

    Subramanian, Venkat

    CONSORTIUM FOR CLEAN COAL UTILIZATION Call for Proposals Date of Issue: July 29, 2013 The Consortium for Clean Coal Utilization (CCCU) at Washington University in St. Louis was established in January of Clean Coal Utilization. The format may be a conference or workshop, or a seminar given by a leading

  17. Coal Market Module - NEMS Documentation

    Reports and Publications (EIA)

    2014-01-01

    Documents the objectives and the conceptual and methodological approach used in the development of the National Energy Modeling System's (NEMS) Coal Market Module (CMM) used to develop the Annual Energy Outlook 2014 (AEO2014). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of CMM's two submodules. These are the Coal Production Submodule (CPS) and the Coal Distribution Submodule (CDS).

  18. Biochemical transformation of coals

    DOE Patents [OSTI]

    Lin, Mow S. (Rocky Point, NY); Premuzic, Eugene T. (East Moriches, NY)

    1999-03-23

    A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed.

  19. Biochemical transformation of coals

    DOE Patents [OSTI]

    Lin, M.S.; Premuzic, E.T.

    1999-03-23

    A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed. 7 figs.

  20. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

    2011-10-30

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?˘ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?˘ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?˘ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?˘ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

  1. Combustion of volatile matter during the initial stages of coal combustion

    SciTech Connect (OSTI)

    Marlow, D.; Niksa, S.; Kruger, C.H.

    1990-08-01

    Both the secondary pyrolysis and combustion of the volatiles from a bituminous coal will be studied. Devolatilization and secondary pyrolysis experiments will be conducted in a novel flow reactor in which secondary pyrolysis of the volatiles occurs after devolatilization is complete. This allows unambiguous measurements of the yields from both processes. Measurements will be made for reactor temperatures from 1500 to 1700 K, and a nominal residence time of 200 msec. These conditions are typical of coal combustion. Yields of tar, soot, H{sub 2}, CO, CH{sub 4}, and C{sub 2} and C{sub 3} hydrocarbons will be determined as a function of reactor temperature. The yields will be reported as a function of the temperature of the reactor. The instrumentation for temperature measurements will be developed during future studies. Combustion studies will be conducted in a constant volume bomb, which will be designed and constructed for this study. Tar and soot will be removed before introducing the volatiles to the bomb, so that only the combustion of the light gas volatiles will be considered. The burning velocities of light gas volatiles will be determined both as functions of mixture stoichiometry and the temperature at which the volatiles are pyrolysed. 90 refs., 70 figs., 13 tabs.

  2. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot Kennel; Chong Chen; Dady Dadyburjor; Mark Heavner; Manoj Katakdaunde; Liviu Magean; James Mayberry; Alfred Stiller; Joseph Stoffa; Christopher Yurchick; John Zondlo

    2009-12-31

    This NETL sponsored effort seeks to develop continuous technologies for the production of carbon products, which may be thought of as the heavier products currently produced from refining of crude petroleum and coal tars obtained from metallurgical grade coke ovens. This effort took binder grade pitch, produced from liquefaction of West Virginia bituminous grade coal, all the way to commercial demonstration in a state of the art arc furnace. Other products, such as crude oil, anode grade coke and metallurgical grade coke were demonstrated successfully at the bench scale. The technology developed herein diverged from the previous state of the art in direct liquefaction (also referred to as the Bergius process), in two major respects. First, direct liquefaction was accomplished with less than a percent of hydrogen per unit mass of product, or about 3 pound per barrel or less. By contrast, other variants of the Bergius process require the use of 15 pounds or more of hydrogen per barrel, resulting in an inherent materials cost. Second, the conventional Bergius process requires high pressure, in the range of 1500 psig to 3000 psig. The WVU process variant has been carried out at pressures below 400 psig, a significant difference. Thanks mainly to DOE sponsorship, the WVU process has been licensed to a Canadian Company, Quantex Energy Inc, with a commercial demonstration unit plant scheduled to be erected in 2011.

  3. Selenium And Arsenic Speciation in Fly Ash From Full-Scale Coal-Burning Utility Plants

    SciTech Connect (OSTI)

    Huggins, F.E.; Senior, C.L.; Chu, P.; Ladwig, K.; Huffman, G.P.; /Kentucky U. /Reaction Engin. Int. /Elect. Power Res. Inst., Palo Alto

    2007-07-09

    X-ray absorption fine structure spectroscopy has been used to determine directly the oxidation states and speciation of selenium and arsenic in 10 fly ash samples collected from full-scale utility plants. Such information is needed to assess the health risk posed by these elements in fly ash and to understand their behavior during combustion and in fly ash disposal options, such as sequestration in tailings ponds. Selenium is found predominantly as Se(IV) in selenite (SeO{sub 3}{sup 2-}) species, whereas arsenic is found predominantly as As(V) in arsenate (AsO{sub 4}{sup 3-}) species. Two distinct types of selenite and arsenate spectra were observed depending upon whether the fly ash was derived from eastern U.S. bituminous (Fe-rich) coals or from western subbituminous or lignite (Ca-rich) coals. Similar spectral details were observed for both arsenic and selenium in the two different types of fly ash, suggesting that the post-combustion behavior and capture of both of these elements are likely controlled by the same dominant element or phase in each type of fly ash.

  4. Lignin-assisted coal depolymerization

    SciTech Connect (OSTI)

    Lalvani, S.B.

    1991-01-01

    Previous research has shown that addition of lignin-derived liquids to coal stirred in tetralin under mild reaction conditions (375{degree}C and 300--500 psig) results in a marked enhancement in the rate of coal depolymerization. A mathematical model was developed to study the kinetics of coal depolymerization in the presence of liquid-derived liquids. In the present study, a reaction pathway was formulated to explain the enhancement in coal depolymerization due to lignin (solid) addition. The model postulated assumes that the products of lignin obtained during thermolysis interact with the reactive moieties present in coal while simultaneous depolymerization of coal occurs. A good fit between the experimental data and the kinetic model was found. The results show that in addition to the enhancement in the rate of coal depolymerization, lignin also reacts (and enhances the extent of depolymerization of coal) with those reaction sites in coal that are not susceptible to depolymerization when coal alone is reacted in tetralin under identical reaction conditions. Additional work is being carried out to determine a thorough materials balance on the lignin-assisted coal depolymerization process. A number of liquid samples have been obtained which are being studied for their stability in various environments. 5 refs., 4 figs., 1 tab.

  5. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C. (Perkiomenville, PA)

    1983-01-01

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  6. Coal mine methane global review

    SciTech Connect (OSTI)

    2008-07-01

    This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

  7. Projections of Full-Fuel-Cycle Energy and Emissions Metrics

    E-Print Network [OSTI]

    Coughlin, Katie

    2013-01-01

    coal production by region, coal type, and sulfur content infrom AEO 2011 and AEO 2012. Coal Type Bituminous Bituminousproportions of total coal output by mining type. To estimate

  8. Clean coal preparation using the Liquids From Coal (LFC) process

    SciTech Connect (OSTI)

    Klugh, D.M.; Marquardt, M.M.; Hoften, S.A. van [SGI International, La Jolla, CA (United States)

    1994-12-31

    With an abundance of coal located in the Pacific Rim region, many economies offer excellent opportunities for the application of clean coal technologies. SGI International`s Liquids From Coal (LFC) Mild Gasification Process is a clean coal technology that can greatly enhance both the economical and environmental use of coal in this area. Indonesia, with its large population and emerging industrial infrastructure, has exhibited one of the fastest growth rates of electrical power consumption in Asia. This paper demonstrates the economic and environmental advantages of the LFC Process as it applies to coals in the Pacific Rim. These advantages are assessed from the results of a technical feasibility study of coal from the Tanjung Enim Region of Indonesia. While Tanjung Enim provides an example of added value and increased lifetime of an existing resource with some environmental benefits, other examples illustrate the excellent opportunity for upgrading coals for export into the Pacific Rim Steaming Coal Trade. These upgraded coals are expected to be very competitive in cost and are expected to be environmentally attractive.

  9. Investigation of the relationship between particulate-bound mercury and properties of fly ash in a full-scale 100 MWe pulverized coal combustion boiler

    SciTech Connect (OSTI)

    Sen Li; Chin-Min Cheng; Bobby Chen; Yan Cao; Jacob Vervynckt; Amanda Adebambo; Wei-Ping Pan

    2007-12-15

    The properties of fly ash in coal-fired boilers influence the emission of mercury from power plants into the environment. In this study, seven different bituminous coals were burned in a full-scale 100 MWe pulverized coal combustion boiler and the derived fly ash samples were collected from a mechanical hopper (MH) and an electrostatic precipitator hopper (ESP). The mercury content, specific surface area (SSA), unburned carbon, and elemental composition of the fly ash samples were analyzed to evaluate the correlation between the concentration of particulate-bound mercury and the properties of coal and fly ash. For a given coal, it was found that the mercury content in the fly ash collected from the ESP was greater than in the fly ash samples collected from the MHP. This phenomenon may be due to a lower temperature of flue gas at the ESP (about 135{sup o}C) compared to the temperature at the air preheater (about 350{sup o}C). Also, a significantly lower SSA observed in MH ash might also contribute to the observation. A comparison of the fly ash samples generated from seven different coals using statistical methods indicates that the mercury adsorbed on ESP fly ashes has a highly positive correlation with the unburned carbon content, manganese content, and SSA of the fly ash. Sulfur content in coal showed a significant negative correlation with the Hg adsorption. Manganese in fly ash is believed to participate in oxidizing volatile elemental mercury (Hg{sup 0}) to ionic mercury (Hg{sup 2+}). The oxidized mercury in flue gas can form a complex with the fly ash and then get removed before the flue gas leaves the stack of the boiler.

  10. Summary of coal export project

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    Through the international coal project and related activities, SSEB has called attention to the problems and potential of the US coal industry. The program has provided an excellent format for frank discussions on the problems facing US coal exports. Every effort must be made to promote coal and its role in the southern economy. Coal is enjoying its best years in the domestic market. While the export market is holding its own, there is increased competition in the world market from Australia, Columbia, China and, to a lesser extent, Russia. This is coming at a time when the US has enacted legislation and plans are underway to deepen ports. In addition there is concern that increased US coal and electricity imports are having a negative impact on coal production. These limiting factors suggest the US will remain the swing supplier of coal on the world market in the near future. This presents a challenge to the US coal and related industry to maintain the present market and seek new markets as well as devote research to new ways to use coal more cleanly and efficiently.

  11. Moist caustic leaching of coal

    DOE Patents [OSTI]

    Nowak, Michael A. (Elizabeth, PA)

    1994-01-01

    A process for reducing the sulfur and ash content of coal. Particulate coal is introduced into a closed heated reaction chamber having an inert atmosphere to which is added 50 mole percent NaOH and 50 mole percent KOH moist caustic having a water content in the range of from about 15% by weight to about 35% by weight and in a caustic to coal weight ratio of about 5 to 1. The coal and moist caustic are kept at a temperature of about 300.degree. C. Then, water is added to the coal and caustic mixture to form an aqueous slurry, which is washed with water to remove caustic from the coal and to produce an aqueous caustic solution. Water is evaporated from the aqueous caustic solution until the water is in the range of from about 15% by weight to about 35% by weight and is reintroduced to the closed reaction chamber. Sufficient acid is added to the washed coal slurry to neutralize any remaining caustic present on the coal, which is thereafter dried to produce desulfurized coal having not less than about 90% by weight of the sulfur present in the coal feed removed and having an ash content of less than about 2% by weight.

  12. Thermal Integration of CO{sub 2} Compression Processes with Coal-Fired Power Plants Equipped with Carbon Capture

    SciTech Connect (OSTI)

    Edward Levy

    2012-06-29

    Coal-fired power plants, equipped either with oxycombustion or post-combustion CO{sub 2} capture, will require a CO{sub 2} compression system to increase the pressure of the CO{sub 2} to the level needed for sequestration. Most analyses show that CO{sub 2} compression will have a significant effect on parasitic load, will be a major capital cost, and will contribute significantly to reduced unit efficiency. This project used first principle engineering analyses and computer simulations to determine the effects of utilizing compressor waste heat to improve power plant efficiency and increase net power output of coal-fired power plants with carbon capture. This was done for units with post combustion solvent-based CO{sub 2} capture systems and for oxyfired power plants, firing bituminous, PRB and lignite coals. The thermal integration opportunities analyzed for oxycombustion capture are use of compressor waste heat to reheat recirculated flue gas, preheat boiler feedwater and predry high-moisture coals prior to pulverizing the coal. Among the thermal integration opportunities analyzed for post combustion capture systems are use of compressor waste heat and heat recovered from the stripper condenser to regenerate post-combustion CO{sub 2} capture solvent, preheat boiler feedwater and predry high-moisture coals. The overall conclusion from the oxyfuel simulations is that thermal integration of compressor heat has the potential to improve net unit heat rate by up to 8.4 percent, but the actual magnitude of the improvement will depend on the type of heat sink used and to a lesser extent, compressor design and coal rank. The simulations of a unit with a MEA post combustion capture system showed that thermal integration of either compressor heat or stripper condenser heat to preheat boiler feedwater would result in heat rate improvements from 1.20 percent to 4.19 percent. The MEA capture simulations further showed that partial drying of low rank coals, done in combination with feedwater heating, would result in heat rate reductions of 7.43 percent for PRB coal and 10.45 percent for lignite.

  13. Eight Advanced Coal Projects Chosen for Further Development by DOE's University Coal Research Program

    Broader source: Energy.gov [DOE]

    DOE has selected eight new projects to further advanced coal research under the University Coal Research Program. The selected projects will improve coal conversion and use and will help propel technologies for future advanced coal power systems.

  14. Exploration for deep coal

    SciTech Connect (OSTI)

    NONE

    2008-12-15

    The most important factor in safe mining is the quality of the roof. The article explains how the Rosebud Mining Co. conducts drilling and exploration in 11 deep coal mine throughout Pennsylvania and Ohio. Rosebud uses two Atlas Copco CS10 core drilling rigs mounted on 4-wheel drive trucks. The article first appeared in Atlas Copco's in-house magazine, Deep Hole Driller. 3 photos.

  15. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  16. Process for changing caking coals to noncaking coals

    DOE Patents [OSTI]

    Beeson, Justin L. (Woodridge, IL)

    1980-01-01

    Caking coals are treated in a slurry including alkaline earth metal hydroxides at moderate pressures and temperatures in air to form noncaking carbonaceous material. Hydroxides such as calcium hydroxide, magnesium hydroxide or barium hydroxide are contemplated for slurrying with the coal to interact with the agglomerating constituents. The slurry is subsequently dewatered and dried in air at atmospheric pressure to produce a nonagglomerating carbonaceous material that can be conveniently handled in various coal conversion and combustion processes.

  17. Zero emission coal

    SciTech Connect (OSTI)

    Ziock, H.; Lackner, K.

    2000-08-01

    We discuss a novel, emission-free process for producing hydrogen or electricity from coal. Even though we focus on coal, the basic design is compatible with any carbonaceous fuel. The process uses cyclical carbonation of calcium oxide to promote the production of hydrogen from carbon and water. The carbonation of the calcium oxide removes carbon dioxide from the reaction products and provides the additional energy necessary to complete hydrogen production without additional combustion of carbon. The calcination of the resulting calcium carbonate is accomplished using the high temperature waste heat from solid oxide fuel cells (SOFC), which generate electricity from hydrogen fuel. Converting waste heat back to useful chemical energy allows the process to achieve very high conversion efficiency from fuel energy to electrical energy. As the process is essentially closed-loop, the process is able to achieve zero emissions if the concentrated exhaust stream of CO{sub 2} is sequestered. Carbon dioxide disposal is accomplished by the production of magnesium carbonate from ultramafic rock. The end products of the sequestration process are stable naturally occurring minerals. Sufficient rich ultramafic deposits exist to easily handle all the world's coal.

  18. Environmental development plan: coal liquefaction

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    This Environmental Development plan (EDP) examines environmental concerns that are being evaluated for the technologies in DOE's Coal Liquefaction Program. It identifies the actions that are planned or underway to resolve these concerns while the technologies are being developed. Research is scheduled on the evaluation and mitigation of potential environmental impacts. This EDP updates the FY 1977 Coal Liquefaction Program EDP. Chapter II describes the DOE Coal Liquefaction Program and focuses on the Solvent Refined Coal (SRC), H-Coal, and Exxon donor solvent (EDS) processes because of their relatively advanced R and D stages. The major unresolved environmental concerns associated with the coal liquefaction subactivities and projects are summarized. The concerns were identified in the 1977 EDP's and research was scheduled to lead to the resolution of the concerns. Much of this research is currently underway. The status of ongoing and planned research is shown in Table 4-1.

  19. Iron catalyzed coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

  20. ENCOAL Mild Coal Gasification Project

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    ENCOAL Corporation, a wholly-owned subsidiary of Shell Mining Company, is constructing a mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by Shell and SGI International, utilizes low-sulfur Powder River Basin Coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly reduce current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain.

  1. Process for electrochemically gasifying coal

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.

    1985-10-25

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  2. The Caterpillar Coal Gasification Facility 

    E-Print Network [OSTI]

    Welsh, J.; Coffeen, W. G., III

    1983-01-01

    THE FUEL IS FED FROM THE HOPPER INTO THE TOP OF THE GASIFIER RETORT THROUGH AN AUTOMATIC COAL FEEDER SYSTEM. COAL FROM THE (100 TON) TOP BUNKERS FLOWS THROUGH A STEEL INLET COMPARTMENT INTO A CAST IRON ROTARY DRUM FEEDER. THE 21" I.D. DRUM HAS A 60...? OPENING THROUGH WHICH IT RECEIVES APPROXIMATELY 6 CU. FT. (300 LBS) OF COAL FROM THE BUNKER. LIP SEALS ARE LOCATED AT THE EDGE OF THE OPENINGS TO CUTOFF THE COAL COLUMN AS THE DRUM ROTATES. A KNIFE GATE VALVE IS LOCATED BENEATH THE DRUM TO SEAL...

  3. A field study on the trace metal behavior in atmospheric circulating fluidized-bed coal combustion

    SciTech Connect (OSTI)

    Lind, T.; Kauppinen, E.I.; Jokiniemi, J.K.; Maenhaut, W.

    1994-12-31

    Trace element behavior in atmospheric circulating fluidized-bed combustion (CFBC) of Venezuelan bituminous coal was studied by determining particle size distributions in the CFBC flue gas. The size distributions of calcium, iron, aluminium, and 21 trace elements, Sc, V, Cr, Mn, Co, Ni, Zn, Ga, As, Se, Sr, Cd, Sb, Cs, Ba, La, Ce, Sm, Lu, Pb, and Th, in the size range 0.01--70{micro}m, were determined by collecting aerosols with a low-pressure impactor-cyclone sampling train from the flue gases of an 80-MW(th) CFBC boiler upstream of the electrostatic precipitator. The collected samples were analyzed gravimetrically and with instrumental neutron activation analysis (INAA), particle-induced X-ray emission analysis (PIXE), and inductively coupled plasma mass spectrometry (ICP-MS). The number size distributions of the aerosols were determined with a differential electrical mobility method in the size range 0.01--0.8 {micro}m. In the ultrafine particle mode, i.e., D{sub p} < 0.1 {micro}m, the CFBC number concentrations varied strongly during the experiments, being one to two orders of magnitude lower than those observed in pulverized coal combustion. For all of the elements studied, 75% or more were found in particles larger than 5{micro}m. None of the studied elements showed significant vaporization and subsequent chemical surface reaction or condensation in the CFBC. The Sr, Se, V, Zn, Ga, Cs, Ba, La, Sm, Lu, and Th size distributions resembled those of aluminium, suggesting their occurrence in aluminosilicate-rich particles in the fly ash. The association of the trace elements with aluminium in the fly ash particles may result from reactions of the trace elements with the aluminosilicate mineral particles inside the burning coal particles, or their initial occurrence in association with these minerals.

  4. Effect of CO2 gasification reaction on oxycombustion of pulverized coal char.

    SciTech Connect (OSTI)

    Molina, Alejandro; Hecht, Ethan S.; Shaddix, Christopher R.; Haynes, Brian S.

    2010-07-01

    For oxy-combustion with flue gas recirculation, as is commonly employed, it is recognized that elevated CO{sub 2} levels affect radiant transport, the heat capacity of the gas, and other gas transport properties. A topic of widespread speculation has concerned the effect of the CO{sub 2} gasification reaction with coal char on the char burning rate. To give clarity to the likely impact of this reaction on the oxy-fuel combustion of pulverized coal char, the Surface Kinetics in Porous Particles (SKIPPY) code was employed for a range of potential CO{sub 2} reaction rates for a high-volatile bituminous coal char particle (130 {micro}m diameter) reacting in several O{sub 2} concentration environments. The effects of boundary layer chemistry are also examined in this analysis. Under oxygen-enriched conditions, boundary layer reactions (converting CO to CO{sub 2}, with concomitant heat release) are shown to increase the char particle temperature and burning rate, while decreasing the O{sub 2} concentration at the particle surface. The CO{sub 2} gasification reaction acts to reduce the char particle temperature (because of the reaction endothermicity) and thereby reduces the rate of char oxidation. Interestingly, the presence of the CO{sub 2} gasification reaction increases the char conversion rate for combustion at low O{sub 2} concentrations, but decreases char conversion for combustion at high O{sub 2} concentrations. These calculations give new insight into the complexity of the effects from the CO{sub 2} gasification reaction and should help improve the understanding of experimentally measured oxy-fuel char combustion and burnout trends in the literature.

  5. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    ACWH consists of a 3,000 MW coal gasification combined cycleconsists of a 3,000 MW coal gasification, combined cycleless expensive in a coal gasification, combined cycle power

  6. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    We use the AEO 2007 forecast of coal prices. This analysisforecast is available only until 2030; we project coal priceslevelized price of coal is based on EIA AEO 2007 forecast

  7. Carbon Dioxide Emission Factors for Coal

    Reports and Publications (EIA)

    1994-01-01

    The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

  8. WEAR RESISTANT ALLOYS FOR COAL HANDLING EQUIPMENT

    E-Print Network [OSTI]

    Bhat, M.S.

    2011-01-01

    of a three-body type, involving coal particles (sizes of hin dry coal feeders wi11 be predominantly type involvingabrasion of a two-body type. Coal crushing and mi 11ing

  9. Low-rank coal oil agglomeration

    DOE Patents [OSTI]

    Knudson, Curtis L. (Grand Forks, ND); Timpe, Ronald C. (Grand Forks, ND)

    1991-01-01

    A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

  10. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    unit water requirement of coal-fired electricity generationin electricity demand. Coal-fired power generation accounted12, the absolute amount of coal-fired capacity grew at an

  11. Volatile coal prices reflect supply, demand uncertainties

    SciTech Connect (OSTI)

    Ryan, M.

    2004-12-15

    Coal mine owners and investors say that supply and demand are now finally in balance. But coal consumers find that both spot tonnage and new contract coal come at a much higher price.

  12. Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture

    SciTech Connect (OSTI)

    Siefert, Nicholas S.; Shekhawat, Dushyant; Litster, Shawn; Berry, David, A

    2013-08-01

    We present experimental results of coal gasification with and without the addition of calcium oxide and potassium hydroxide as dual-functioning catalyst–capture agents. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect of these catalyst–capture agents on (1) the syngas composition, (2) CO{sub 2} and H{sub 2}S capture, and (3) the steam–coal gasification kinetic rate. The syngas composition from the gasifier was roughly 20% methane, 70% hydrogen, and 10% other species when a CaO/C molar ratio of 0.5 was added. We demonstrated significantly enhanced steam–coal gasification kinetic rates when adding small amounts of potassium hydroxide to coal when operating a CaO–CaCO{sub 3} chemical looping gasification reactor. For example, the steam–coal gasification kinetic rate increased 250% when dry mixing calcium oxide at a Ca/C molar ratio of 0.5 with a sub-bituminous coal, and the kinetic rate increased 1000% when aqueously mixing calcium oxide at a Ca/C molar ratio of 0.5 along with potassium hydroxide at a K/C molar ratio of 0.06. In addition, we conducted multi-cycle studies in which CaCO{sub 3} was calcined by heating to 900 °C to regenerate the CaO, which was then reused in repeated CaO–CaCO{sub 3} cycles. The increased steam–coal gasification kinetics rates for both CaO and CaO + KOH persisted even when the material was reused in six cycles of gasification and calcination. The ability of CaO to capture carbon dioxide decreased roughly 2–4% per CaO–CaCO{sub 3} cycle. We also discuss an important application of this combined gasifier–calciner to electricity generation and selling the purge stream as a precalcined feedstock to a cement kiln. In this scenario, the amount of purge stream required is fixed not by the degradation in the capture ability but rather by the requirements at the cement kiln on the amount of CaSO{sub 4} and ash in the precalcined feedstock.

  13. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubicFracking,MichiganThousand47,959.15 KeroseneCoal Glossary

  14. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubicFracking,MichiganThousand47,959.15 KeroseneCoal

  15. Annual Coal Distribution Tables

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers4.32Elements)Grossc. Real73 Table

  16. Annual Coal Distribution Tables

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers4.32Elements)Grossc. Real73

  17. Annual Coal Distribution Tables

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers4.32Elements)Grossc. Real73and Foreign

  18. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual

  19. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual0

  20. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual00

  1. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual000

  2. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual0000

  3. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear

  4. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy Information

  5. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy Information1 U.S.

  6. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy Information1

  7. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy Information12

  8. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy

  9. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy

  10. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy0

  11. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy00

  12. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy000

  13. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy0001

  14. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy00011

  15. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S.

  16. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S.1 U.S.

  17. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S.1 U.S.2 U.S.

  18. Coal Distribution Database, 2006

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December 2008

  19. Coal Distribution Database, 2006

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December 2008

  20. Coal Distribution Database, 2006

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December

  1. Coal Distribution Database, 2008

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December3Q 2009

  2. Coal Distribution Database, 2008

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December3Q 20093Q

  3. Coal Distribution Database, 2008

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December3Q

  4. Coal Distribution Database, 2008

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December3Q4Q 2009

  5. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic Feet)698 1.873 -Coal

  6. Coal combustion products (CCPs

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartment of Energyof the CleanClient education istheCoalFocuses

  7. EIA -Quarterly Coal Distribution

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table272/SPipelineNatural Gas Energy MarketsCoal

  8. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160Product:7a. Space Heatingreports Coal

  9. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    raising transportation oil demand. Growing internationalcoal by wire could reduce oil demand by stemming coal roadEastern oil production. The rapid growth of coal demand

  10. Utility Generation and Clean Coal Technology (Indiana)

    Broader source: Energy.gov [DOE]

    This statute establishes the state's support and incentives for the development of new energy production and generating facilities implementing advanced clean coal technology, such as coal...

  11. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    s ability to mitigate carbon dioxide emissions growth. Ifgrowth path, carbon dioxide emissions from coal combustiondependence. 4.4.1. Carbon dioxide emissions Coal is China’s

  12. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    of Figures Figure ES-1. Advanced Coal Wind Hybrid: Basicviii Figure 1. Advanced-Coal Wind Hybrid: Basic21 Figure 6. Comparison of ACWH and CCGT-Wind

  13. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    materials (6%), delivered heating (district heating) (6%),coal growth. As district heating expands with urbanizationzone, coal use for district heating will depend on the

  14. DOE's Advanced Coal Research, Development, and Demonstration...

    Broader source: Energy.gov (indexed) [DOE]

    (DOE's) advanced coal research, development, and demonstration program to develop low-carbon emission coal technologies. Introduction Fossil fuel resources represent a tremendous...

  15. SciTech Connect: "clean coal"

    Office of Scientific and Technical Information (OSTI)

    clean coal" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "clean coal" Semantic Semantic Term Title: Full Text: Bibliographic Data: Creator ...

  16. Commercialization of clean coal technologies

    SciTech Connect (OSTI)

    Bharucha, N. [Dept. of Primary Industries and Energy, Canberra (Australia)

    1994-12-31

    The steps to commercialization are reviewed in respect of their relative costs, the roles of the government and business sectors, and the need for scientific, technological, and economic viability. The status of commercialization of selected clean coal technologies is discussed. Case studies related to a clean coal technology are reviewed and conclusions are drawn on the factors that determine commercialization.

  17. Coal: Energy for the future

    SciTech Connect (OSTI)

    1995-05-01

    This report was prepared in response to a request by the US Department of energy (DOE). The principal objectives of the study were to assess the current DOE coal program vis-a-vis the provisions of the Energy Policy Act of 1992 (EPACT), and to recommend the emphasis and priorities that DOE should consider in updating its strategic plan for coal. A strategic plan for research, development, demonstration, and commercialization (RDD and C) activities for coal should be based on assumptions regarding the future supply and price of competing energy sources, the demand for products manufactured from these sources, technological opportunities, and the need to control the environmental impact of waste streams. These factors change with time. Accordingly, the committee generated strategic planning scenarios for three time periods: near-term, 1995--2005; mid-term, 2006--2020; and, long-term, 2021--2040. The report is divided into the following chapters: executive summary; introduction and scope of the study; overview of US DOE programs and planning; trends and issues for future coal use; the strategic planning framework; coal preparation, coal liquid mixtures, and coal bed methane recovery; clean fuels and specialty products from coal; electric power generation; technology demonstration and commercialization; advanced research programs; conclusions and recommendations; appendices; and glossary. 174 refs.

  18. Centrifuge treatment of coal tar

    SciTech Connect (OSTI)

    L.A. Kazak; V.Z. Kaidalov; L.F. Syrova; O.S. Miroshnichenko; A.S. Minakov

    2009-07-15

    New technology is required for the removal of water and heavy fractions from regular coal tar. Centrifuges offer the best option. Purification of coal tar by means of centrifuges at OAO NLMK permits the production of pitch coke or electrode pitch that complies with current standards.

  19. Coal Age buyers guide 2007

    SciTech Connect (OSTI)

    2007-07-15

    The buyers guide provides a comprehensive list of more than 1,200 suppliers that provide equipment and services to US coal mine and coal preparation plants, mainly based in the USA. Telephone numbers of companies are provided for each product category.

  20. Coal Age buyers guide 2006

    SciTech Connect (OSTI)

    2006-07-15

    The Buyers Guide provides a comprehensive list of more than 1,200 suppliers that provide equipment and services to US coal mine and coal preparation plants, mainly based in the USA. Telephone numbers of companies are provided for each product category.

  1. Coal Age buyers guide 2005

    SciTech Connect (OSTI)

    2005-07-01

    The Buyers Guide provides a comprehensive list of more than 1,200 suppliers that provide equipment and services to US coal mine and coal preparation plants, mainly based in the USA. Telephone numbers of companies are provided for each product category.

  2. Coals and coal requirements for the COREX process

    SciTech Connect (OSTI)

    Heckmann, H. [Deutsche Voest-Alpine Industrieanlagenbau GmbH, Duesseldorf (Germany)

    1996-12-31

    The utilization of non met coals for production of liquid hot metal was the motivation for the development of the COREX Process by VAI/DVAI during the 70`s. Like the conventional ironmaking route (coke oven/blast furnace) it is based on coal as source of energy and reduction medium. However, in difference to blast furnace, coal can be used directly without the necessary prestep of cokemaking. Coking ability of coals therefore is no prerequisite of suitability. Meanwhile the COREX Process is on its way to become established in ironmaking industry. COREX Plants at ISCOR, Pretoria/South Africa and POSCO Pohang/Korea, being in operation and those which will be started up during the next years comprise already an annual coal consumption capacity of approx. 5 Mio. tonnes mtr., which is a magnitude attracting the interest of industrial coal suppliers. The increasing importance of COREX as a comparable new technology forms also a demand for information regarding process requirements for raw material, especially coal, which is intended to be met here.

  3. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics. [Coal pyrite electrodes

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-01-01

    The objective of this research is to develop a mechanistic understanding of the oxidation of coal and coal pyrite, and to correlate the intrinsic physical and chemical properties of these minerals, along with changes resulting from oxidation, with those surface properties that influence the behavior in physical cleaning processes. The results will provide fundamental insight into oxidation, in terms of the bulk and surface chemistry, the microstructure, and the semiconductor properties of the pyrite. During the eighth quarter, wet chemical and dry oxidation tests were done on Upper Freeport coal from the Troutville [number sign]2 Mine, Clearfield County, Pennsylvania. In addition electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania.

  4. Coal Technology '80. Volume 5. Synthetic fuels from coal. Volume 6. Industrial/utility applications for coal

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    The 3rd international coal utilization exhibition and conference Coal Technology '80 was held at the Astrohall, Houston, Texas, November 18-20, 1980. Volume 5 deals with coal gasification and coal liquefaction. Volume 6 deals with fluidized-bed combustion of coal, cogeneration and combined-cycle power plants, coal-fuel oil mixtures (COM), chemical feedstocks via coal gasification and Fischer-Tropsch synthesis. Thirty-six papers have been entered individually into EDB and seven also into ERA; three had been entered previously from other sources. (LTN)

  5. Coal gasification vessel

    DOE Patents [OSTI]

    Loo, Billy W. (Oakland, CA)

    1982-01-01

    A vessel system (10) comprises an outer shell (14) of carbon fibers held in a binder, a coolant circulation mechanism (16) and control mechanism (42) and an inner shell (46) comprised of a refractory material and is of light weight and capable of withstanding the extreme temperature and pressure environment of, for example, a coal gasification process. The control mechanism (42) can be computer controlled and can be used to monitor and modulate the coolant which is provided through the circulation mechanism (16) for cooling and protecting the carbon fiber and outer shell (14). The control mechanism (42) is also used to locate any isolated hot spots which may occur through the local disintegration of the inner refractory shell (46).

  6. 2011 International Pittsburgh Coal Conference Pittsburgh, PA

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Sequestration in Unmineable Coal with Enhanced Coal Bed Methane Recovery: The Marshall County Project James E conducted in Marshall County, West Virginia, USA, to evaluate enhanced coal bed methane recovery2011 International Pittsburgh Coal Conference Pittsburgh, PA September 12 ­ 15, 2011 CO2

  7. Carbon Dioxide Capture from Coal-Fired

    E-Print Network [OSTI]

    Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005. LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologies environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

  8. Biogeochemistry of Microbial Coal-Bed Methane

    E-Print Network [OSTI]

    Macalady, Jenn

    Biogeochemistry of Microbial Coal-Bed Methane Dariusz Strapo´c,1, Maria Mastalerz,2 Katherine, biodegradation Abstract Microbial methane accumulations have been discovered in multiple coal- bearing basins low-maturity coals with predominantly microbial methane gas or uplifted coals containing older

  9. Low temperature aqueous desulfurization of coal

    DOE Patents [OSTI]

    Slegeir, William A. (Hampton Bays, NY); Healy, Francis E. (Massapequa, NY); Sapienza, Richard S. (Shoreham, NY)

    1985-01-01

    This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

  10. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    China Primary Energy Consumption, 1980-2007 Primary Energy Consumption (mtce) hydro & nuclear coal natural gas

  11. Low temperature aqueous desulfurization of coal

    DOE Patents [OSTI]

    Slegeir, W.A.; Healy, F.E.; Sapienza, R.S.

    1985-04-18

    This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

  12. Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power Plants

    E-Print Network [OSTI]

    Hutcheon, James M.

    Color Removal from Pulp Mill Effluent Using Coal Ash Produced from Georgia Coal Combustion Power color from pulp mill effluent using coal ash. Prevent coal ash adsorbent from leaching arsenic, chromium, lead, and zinc. Define a treatment procedure using coal ash that will result in the maximum

  13. Clean coal technology. Coal utilisation by-products

    SciTech Connect (OSTI)

    NONE

    2006-08-15

    The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

  14. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    Their in combination with fly-ash aromatics such as benzo-(are also poorly known. Fly ash containing benzo-(a)-pyrenesand coal that form little fly ash and trap sulfur in the

  15. Interest in coal chemistry intensifies

    SciTech Connect (OSTI)

    Haggin, J.

    1982-08-09

    Research on coal structure has increased greatly in recent years as the future role of coal as a source of gaseous and liquid fuels, as well as chemicals, becomes more apparent. This paper reviews in some detail work being carried out in the US, particularly in the laboratories of Mobil and Exxon, and in the universities. New ideas on the chemical and physical structure of coal are put forward, and a proposal for a new classification system based on the fundamental properties of the vitrinite macerals is introduced.

  16. Bioprocessing of lignite coals using reductive microorganisms

    SciTech Connect (OSTI)

    Crawford, D.L.

    1992-03-29

    In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

  17. Clean coal technologies: A business report

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The book contains four sections as follows: (1) Industry trends: US energy supply and demand; The clean coal industry; Opportunities in clean coal technologies; International market for clean coal technologies; and Clean Coal Technology Program, US Energy Department; (2) Environmental policy: Clean Air Act; Midwestern states' coal policy; European Community policy; and R D in the United Kingdom; (3) Clean coal technologies: Pre-combustion technologies; Combustion technologies; and Post-combustion technologies; (4) Clean coal companies. Separate abstracts have been prepared for several sections or subsections for inclusion on the data base.

  18. Coal: the cornerstone of America's energy future

    SciTech Connect (OSTI)

    Beck, R.A. [National Coal Council (United Kingdom)

    2006-06-15

    In April 2005, US Secretary of Energy Samuel W. Bodman asked the National Coal Council to develop a 'report identifying the challenges and opportunities of more fully exploring our domestic coal resources to meet the nation's future energy needs'. The Council has responded with eight specific recommendations for developing and implementing advanced coal processing and combustion technologies to satisfy our unquenchable thirst for energy. These are: Use coal-to-liquids technologies to produce 2.6 million barrels/day; Use coal-to-natural gas technologies to produce 4 trillion ft{sup 3}/yr; Build 100 GW of clean coal plants by 2025; Produce ethanol from coal; Develop coal-to-hydrogen technologies; Use CO{sub 2} to enhance recovery of oil and coal-bed methane; Increase the capacity of US coal mines and railroads; and Invest in technology development and implementation. 1 ref.; 4 figs.; 1 tab.

  19. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01

    74. Any coal application (coal gasification, coal combustionFixed-Bed Low-Btu Coal Gasification Systems for RetrofittingPower Plants Employing Coal Gasification," Bergman, P. D. ,

  20. Coal competition: prospects for the 1980s

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    This report consists of 10 chapters which present an historical overview of coal and the part it has played as an energy source in the economic growth of the United States from prior to World War II through 1978. Chapter titles are: definition of coals, coal mining; types of coal mines; mining methods; mining work force; development of coal; mine ownership; production; consumption; prices; exports; and imports. (DMC)

  1. EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS

    SciTech Connect (OSTI)

    J.A. Withum

    2006-03-07

    CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), evaluated the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)-wet flue gas desulfurization (FGD) combination or a spray dyer absorber-fabric filter (SDA-FF) combination. In this program CONSOL determined mercury speciation and removal at 10 bituminous coal-fired facilities; at four of these facilities, additional tests were performed on units without SCR, or with the existing SCR bypassed. This project final report summarizes the results and discusses the findings of the body of work as a whole. Eleven Topical Reports were issued (prior to this report) that describe in great detail the sampling results at each of the ten power plants individually. The results showed that the SCR-FGD combination removed a substantial fraction of mercury from flue gas. The coal-to-stack mercury removals ranged from 65% to 97% for the units with SCR and from 53% to 87% for the units without SCR. There was no indication that any type of FGD system was more effective at mercury removal than others. The coal-to-stack mercury removal and the removal in the wet scrubber were both negatively correlated with the elemental mercury content of the flue gas and positively correlated with the scrubber liquid chloride concentration. The coal chlorine content was not a statistically significant factor in either case. Mercury removal in the ESP was positively correlated with the fly ash carbon content and negatively correlated with the flue gas temperature. At most of the units, a substantial fraction (>35%) of the flue gas mercury was in the elemental form at the boiler economizer outlet. After passing through the SCR-air heater combination very little of the total mercury (<10%) remained in the elemental form in the flue gas; this was true for all SCR catalyst types and sources. Although chlorine has been suggested as a factor affecting the mercury speciation in flue gas, coal chlorine was not a statistically significant factor affecting mercury speciation at the economizer exit or at the air heater exit. The only statistically significant factors were the coal ash CaO content and the fly ash carbon content; the fraction of mercury in the elemental form at the economizer exit was positively correlated with both factors. In a direct comparison at four SCR-equipped units vs. similar units at the same sites without SCR (or with the SCR bypassed), the elemental mercury fractions (measured at the ESP outlet) were lower, and the coal-to-stack mercury removals were higher, when the SCR was present and operating. The average coal-to-stack mercury removal at the four units without an operating SCR was 72%, whereas the average removal at the same sites with operating SCRs was 88%. The unit mercury mass balance (a gauge of the overall quality of the tests) at all of the units ranged from 81% to 113%, which were within our QA/QC criterion of 80-120%.

  2. Combustion process and nitrogen oxides emission of Shenmu coal added with sodium acetate

    SciTech Connect (OSTI)

    Yang Weijuan; Zhou Junhu; Liu Maosheng; Zhou Zhijun; Liu Jianzhong; Cen Kefa

    2007-09-15

    Shenmu bituminous coal with 4% sodium acetate added was used to investigate the characteristics of combustion and nitrogen oxide (NOx) release in a fixed bed reactor heated by a tube furnace. The composition of the flue gas was analyzed to investigate the effects of sodium acetate on the combustion process and NOx emission. The experiments were carried out in a partial reductive atmosphere and a strong oxidative atmosphere. The O{sub 2} valley value in the partial reductive atmosphere was reduced by the added sodium acetate. Sodium acetate accelerated the combustion and shortened the combustion process. The experimental results showed that the emissions of NO, NO{sub 2}, and N{sub 2}O were affected by the reacting atmosphere and the combustion temperature. In the strong oxidative atmosphere, sodium acetate resulted in a slight NOx reduction. In the partial reductive atmosphere, sodium acetate reduced both the peak value of NO concentration and the total NO emission significantly. An over 30% NOx reduction efficiency was achieved at 900{sup o}C in the partial reductive atmosphere, which decreased with the increase in temperature. Sodium acetate was decomposed into hydrocarbon radicals and sodium hydroxide, which can both reduce NOx emissions due to their special reactions with the nitrogen component. 17 refs., 11 figs., 2 tabs.

  3. Heat Recovery from Coal Gasifiers 

    E-Print Network [OSTI]

    Wen, H.; Lou, S. C.

    1981-01-01

    In coal conversion processes, generally, liquefaction is done at high pressure and relatively low tempera tures, while gasification involves high temperature conditions. In order to protect the gasifier shell from overheating, a complex refractory...

  4. Process for low mercury coal

    DOE Patents [OSTI]

    Merriam, Norman W. (Laramie, WY); Grimes, R. William (Laramie, WY); Tweed, Robert E. (Laramie, WY)

    1995-01-01

    A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

  5. Coal beneficiation by gas agglomeration

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  6. An Overview of Coal based

    E-Print Network [OSTI]

    An Overview of Coal based Integrated Gasification Combined Cycle (IGCC) Technology September 2005. LFEE 2005-002 WP #12;#12;Table of Contents 1 Integrated Gasification Combined Cycle (IGCC.......................................................................... 17 2.1 Gasification

  7. Two stage liquefaction of coal

    DOE Patents [OSTI]

    Neuworth, Martin B. (Chevy Chase, MD)

    1981-01-01

    A two stage coal liquefaction process and apparatus comprising hydrogen donor solvent extracting, solvent deashing, and catalytic hydrocracking. Preferrably, the catalytic hydrocracking is performed in an ebullating bed hydrocracker.

  8. Which route to coal liquefaction

    SciTech Connect (OSTI)

    Nene, R.G.

    1981-11-01

    Two main methods for producing liquid fuels from coal are currently undergoing intensive evaluation. One, direct liquefaction (e.g., SRC-II, Exxon Donor Solvent (EDS), and H-Coal) produces liquid fuels directly from coal; the other, indirect liquefaction (e.g., Lurgi gasifier followed by Fischer-Tropsch, and Shell-Koppers gasifier followed by methanol synthesis and Mobil's MTG process) first gasifies coal and then converts the gaseous material into liquid products. This paper compares both routes basing its assessment on yields, thermal efficiencies, elemental balances, investment, complexity, and state of development. It is shown that direct liquefaction is more efficient and produces more product per investment dollar. Higher efficiency for direct liquefaction is verified bY stoichiometric and thermodynamic analysis. All approaches require about the same capital investment per unit of feed. Indirect liquefaction can be either more or less complex than direct liquefaction, depending upon the process. Direct liquefaction is least developed. 8 refs.

  9. Coal Beneficiation by Gas Agglomeration

    SciTech Connect (OSTI)

    Thomas D. Wheelock; Meiyu Shen

    2000-03-15

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  10. Coal-fired power materials

    SciTech Connect (OSTI)

    Viswanathan, V.; Purgert, R.; Rawls, P. [Electric Power Research Institute, Palo Alto, CA (United States)

    2008-08-15

    Advances in materials technologies over the last decade that is allowing coal-fired power plants to be built with higher efficiencies than the current generation are described. 2 figs., 2 tabs.

  11. Coal Transportation Rate Sensitivity Analysis

    Reports and Publications (EIA)

    2005-01-01

    On December 21, 2004, the Surface Transportation Board (STB) requested that the Energy Information Administration (EIA) analyze the impact of changes in coal transportation rates on projected levels of electric power sector energy use and emissions. Specifically, the STB requested an analysis of changes in national and regional coal consumption and emissions resulting from adjustments in railroad transportation rates for Wyoming's Powder River Basin (PRB) coal using the National Energy Modeling System (NEMS). However, because NEMS operates at a relatively aggregate regional level and does not represent the costs of transporting coal over specific rail lines, this analysis reports on the impacts of interregional changes in transportation rates from those used in the Annual Energy Outlook 2005 (AEO2005) reference case.

  12. Upgrading coal plant damper drives

    SciTech Connect (OSTI)

    Hood, N.R.; Simmons, K. [Alamaba Power (United States)

    2009-11-15

    The replacement of damper drives on two coal-fired units at the James H. Miller Jr. electric generating plant by Intelligent Contrac electric rotary actuators is discussed. 2 figs.

  13. Clean Coal Diesel Demonstration Project

    SciTech Connect (OSTI)

    Robert Wilson

    2006-10-31

    A Clean Coal Diesel project was undertaken to demonstrate a new Clean Coal Technology that offers technical, economic and environmental advantages over conventional power generating methods. This innovative technology (developed to the prototype stage in an earlier DOE project completed in 1992) enables utilization of pre-processed clean coal fuel in large-bore, medium-speed, diesel engines. The diesel engines are conventional modern engines in many respects, except they are specially fitted with hardened parts to be compatible with the traces of abrasive ash in the coal-slurry fuel. Industrial and Municipal power generating applications in the 10 to 100 megawatt size range are the target applications. There are hundreds of such reciprocating engine power-plants operating throughout the world today on natural gas and/or heavy fuel oil.

  14. Process for low mercury coal

    DOE Patents [OSTI]

    Merriam, N.W.; Grimes, R.W.; Tweed, R.E.

    1995-04-04

    A process is described for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal. 4 figures.

  15. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01

    In addition, the coking coal market began to deteriorateits permeability. Bituminous, or coking coal, is blended andmerchant coke plants, coking coal is heated in a low-oxygen,

  16. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01

    gas petroleum waxes coking coal t C/TJ other bituminous coalprocesses of coal washing, coking, petroleum refineries, gaslosses include coal washing, coking, petroleum refining, gas

  17. Streamline coal slurry letdown valve

    DOE Patents [OSTI]

    Platt, R.J.; Shadbolt, E.A.

    1983-11-08

    A streamlined coal slurry letdown valve is featured which has a two-piece throat comprised of a seat and seat retainer. The two-piece design allows for easy assembly and disassembly of the valve. A novel cage holds the two-piece throat together during the high pressure letdown. The coal slurry letdown valve has long operating life as a result of its streamlined and erosion-resistance surfaces. 5 figs.

  18. Coal liquefaction and gasification technologies

    SciTech Connect (OSTI)

    Mangold, E.C.; Muradaz, M.A.; Ouellette, R.P.; Farah, O.G.; Cheremisinoff, P.N.

    1982-01-01

    The state-of-the-art of selected coal liquefaction and gasification processes developed with support from the United States are reviewed. The Exxon Donor Solvent, H-Coal, SRC-I, SRC-II, Mobile Gasoline Synthesis, Fischer-Tropsch Synthesis, and Zinc Halide Hydrocracking liquefaction processes and the Slagging Lurgi, Texaco, Combustion Engineering, COGAS, and Shell-Koppers gasification processes are covered. Separate abstracts were prepared for 5 chapters.

  19. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    T.D. Wheelock

    1999-03-01

    The technical feasibility of a gas agglomeration method for cleaning coal was demonstrated by means of bench-scale tests conducted with a mixing system which enabled the treatment of ultra-fine coal particles with a colloidal suspension of microscopic gas bubbles in water. A suitable suspension of microbubbles was prepared by first saturating water with air or carbon dioxide under pressure then reducing the pressure to release the dissolved gas. The formation of microbubbles was facilitated by agitation and a small amount of i-octane. When the suspension of microbubbles and coal particles was mixed, agglomeration was rapid and small spherical agglomerates were produced. Since the agglomerates floated, they were separated from the nonfloating tailings in a settling chamber. By employing this process in numerous agglomeration tests of moderately hydrophobic coals with 26 wt.% ash, it was shown that the ash content would be reduced to 6--7 wt.% while achieving a coal recovery of 75 to 85% on a dry, ash-free basis. This was accomplished by employing a solids concentration of 3 to 5 w/w%, an air saturation pressure of 136 to 205 kPa (5 to 15 psig), and an i-octane concentration of 1.0 v/w% based on the weight of coal.

  20. MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION

    E-Print Network [OSTI]

    Joyce, Peter James

    2011-01-01

    ix Introduction. A. Coal Liquefaction Overview B.L ZnCl 2-catalyzed Coal Liquefaction . . . . . . . . . • ,Results. . . • . ZnC1 2/MeOH Coal liquefaction Process

  1. Southern Coal finds value in the met market

    SciTech Connect (OSTI)

    Fiscor, S.

    2009-11-15

    The Justice family launches a new coal company (Southern Coal Corp.) to serve metallurgical and steam coal markets. 1 tab., 3 photos.

  2. COMBUSTION OF COAL IN AN OPPOSED FLOW DIFFUSION BURNER

    E-Print Network [OSTI]

    Chin, W.K.

    2010-01-01

    1. Pittsburgh seam coal properties, Grosshandler (1976)a 35 mesh sieve (417 Properties of this coal are reported inthe reported properties of the pulverized coal. The pressed

  3. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-01-01

    During the ninth quarter, electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania. Scanning electron microscopy and energy dispersive X-ray analysis were done to characterize the morphology and composition of the surface of as-received coal, oxidized coal and coal pyrite. In addition, electrokinetic tests were done on Upper Freeport coal pyrite.

  4. Oxy-coal Combustion Studies

    SciTech Connect (OSTI)

    J. Wendt; E. Eddings; J. Lighty; T. Ring; P. Smith; J. Thornock; Y. Jia, W. Morris; J. Pedel; D. Rezeai; L. Wang; J. Zhang; K. Kelly

    2012-01-01

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol. To these ends, the project has focused on the following: â?˘ The development of reliable Large Eddy Simulations (LES) of oxy-coal flames using the Direct Quadrature Method of Moments (DQMOM) (Subtask 3.1). The simulations were validated for both non-reacting particle-laden jets and oxy-coal flames. â?˘ The modifications of an existing oxy-coal combustor to allow operation with high levels of input oxygen to enable in-situ laser diagnostic measurements as well as the development of strategies for directed oxygen injection (Subtask 3.2). Flame stability was quantified for various burner configurations. One configuration that was explored was to inject all the oxygen as a pure gas within an annular oxygen lance, with burner aerodynamics controlling the subsequent mixing. â?˘ The development of Particle Image Velocimetry (PIV) for identification of velocity fields in turbulent oxy-coal flames in order to provide high-fidelity data for the validation of oxy-coal simulation models (Subtask 3.3). Initial efforts utilized a laboratory diffusion flame, first using gas-fuel and later a pulverized-coal flame to ensure the methodology was properly implemented and that all necessary data and image-processing techniques were fully developed. Success at this stage of development led to application of the diagnostics in a large-scale oxy-fuel combustor (OFC). â?˘ The impact of oxy-coal-fired vs. air-fired environments on SO{sub x} (SO{sub 2}, SO{sub 3}) emissions during coal combustion in a pilot-scale circulating fluidized-bed (CFB) (Subtask 3.4). Profiles of species concentration and temperature were obtained for both conditions, and profiles of temperature over a wide range of O{sub 2} concentration were studied for oxy-firing conditions. The effect of limestone addition on SO{sub 2} and SO{sub 3} emissions were also examined for both air- and oxy- firing conditions. â?˘ The investigation of O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments on SO{sub 2 emissions during coal combustion in a bench-scale single-particle fluidized-bed reactor (Subtask 3.5). Moreover, the sulfation mechanisms of limestone in O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments were studied, and a generalized gassolid and diffusion-reaction single-particle model was developed to study the effect of major operating variables. â?˘ The investigation of the effect of oxy-coal combustion on ash formation, particle size distributions (PSD), and size-segregated elemental composition in a drop-tube furnace and the 100 kW OFC (Subtask 3.6). In particular, the effect of coal type and flue gas recycle (FGR, OFC only) was investigated.

  5. Hydrogen production by high-temperature steam gasification of biomass and coal

    SciTech Connect (OSTI)

    Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

    2009-04-15

    High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

  6. Beluga Coal Gasification - ISER

    SciTech Connect (OSTI)

    Steve Colt

    2008-12-31

    ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

  7. The fate of alkali species in advanced coal conversion systems. Final report

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950{degree}C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800{degree} to 950{degree}C, the concentrations of vapor phase sodium species (Na, Na{sub 2}O, NaCl, and Na{sub 2}SO{sub 4}) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820{degree}. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na{sub 2}SO{sub 4} increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 {mu}m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  8. A study of toxic emissions from a coal-fired power plant utilizing the SNOX innovative clean coal technology demonstration. Volume 1, Sampling/results/special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electric utilities. The report is organized in two volumes. Volume 1: Sampling describes the sampling effort conducted as the basis for this study; Results presents the concentration data on HAPs in the several power plant streams, and reports the results of evaluations and calculations conducted with those data; and Special Topics report on issues such as comparison of sampling methods and vapor/solid distributions of HAPs. Volume 2: Appendices include quality assurance/quality control results, uncertainty analysis for emission factors, and data sheets. This study involved measurements of a variety of substances in solid, liquid, and gaseous samples from input, output, and process streams at the Innovative Clean Coal Technology Demonstration (ICCT) of the Wet Sulfuric Acid-Selective Catalytic Reduction (SNOX) process. The SNOX demonstration is being conducted at Ohio Edison`s Niles Boiler No. 2 which uses cyclone burners to burn bituminous coal. A 35 megawatt slipstream of flue gas from the boiler is used to demonstrate SNOX. The substances measured at the SNOX process were the following: 1. Five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; 2. Acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); 3. Ammonia and cyanide; 4. Elemental carbon; 5. Radionuclides; 6. Volatile organic compounds (VOC); 7. Semi-volatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH); and 8. Aldehydes.

  9. Enhancement of surface properties for coal beneficiation

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  10. Coal Transportation Issues (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01

    Most of the coal delivered to U.S. consumers is transported by railroads, which accounted for 64% of total domestic coal shipments in 2004. Trucks transported approximately 12% of the coal consumed in the United States in 2004, mainly in short hauls from mines in the East to nearby coal-fired electricity and industrial plants. A number of minemouth power plants in the West also use trucks to haul coal from adjacent mining operations. Other significant modes of coal transportation in 2004 included conveyor belt and slurry pipeline (12%) and water transport on inland waterways, the Great Lakes, and tidewater areas (9%).

  11. The effect of oxygen-to-fuel stoichiometry on coal ash fine-fragmentation mode formation mechanisms.

    SciTech Connect (OSTI)

    Fix, G.; Seames, W. S.; Mann, M. D.; Benson, S. A.; Miller, D. J.

    2011-04-01

    Ash particles smaller than 2.5 {micro}m in diameter generated during pulverized coal combustion are difficult to capture and may pose greater harm to the environment and human health than the discharge of larger particles. Recent research efforts on coal ash formation have revealed a middle fine-fragment mode centered around 2 {micro}m. Formation of this middle or fine-fragment mode (FFM) is less well understood compared to larger coarse and smaller ultrafine ash. This study is part of an overall effort aimed at determining the key factors that impact the formation of FFM. This work examined the effects of oxygen-to-fuel stoichiometry (OFS). Pulverized Illinois No.6 bituminous coal was combusted and the ash generated was size segregated in a Dekati low pressure inertial impactor. The mass of each fraction was measured and the ash was analyzed using scanning electron microscopy (SEM) and X-ray microanalysis. The FFM ash types were classified based on the SEM images to evaluate the significant fine-fragment ash formation mechanisms and determine any possible link between stoichiometry and formation mechanism. From the particle size distributions (PSDs), the coarse mode appears unaffected by the change in OFS, however, the OFS 1.05 lowered the fraction of ultrafine ash in relation to the higher OFS settings, and appears to increase the portion of the FFM. An intermediate minimum was found in the FFM at 1.3 {micro}m for the 1.20 and 1.35 OFS tests but was not observed in the 1.05 OFS. SEM analysis also suggests that OFS may contribute to changing formation mechanisms.

  12. Photosynthetic pigment concentrations, gas exchange and vegetative growth for selected monocots and dicots treated with two contrasting coal fly ashes

    SciTech Connect (OSTI)

    Yunusa, I.A.M.; Burchett, M.D.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Skilbeck, C.G.

    2009-07-15

    There is uncertainty as to the rates of coal fly ash needed for optimum physiological processes and growth. In the current study we tested the hyothesis that photosynthetic pigments concentrations and CO{sub 2} assimilation (A) are more sensitive than dry weights in plants grown on media amended with coal fly ash. We applied the Terrestrial Plant Growth Test (Guideline 208) protocols of the Organization for Economic Cooperation and Development (OECD) to monocots (barley (Hordeum vulgare) and ryegrass (Secale cereale)) and dicots (canola (Brasica napus), radish (Raphanus sativus), field peas (Pisum sativum), and lucerne (Medicago sativa)) on media amended with fly ashes derived from semi-bituminous (gray ash) or lignite (red ash) coals at rates of 0, 2.5, 5.0, 10, or 20 Mg ha(-1). The red ash had higher elemental concentrations and salinity than the gray ash. Fly ash addition had no significant effect on germination by any of the six species. At moderate rates ({<=}10 Mg ha{sup -1}) both ashes increased (P < 0.05) growth rates and concentrations of chlorophylls a and b, but reduced carotenoid concentrations. Addition of either ash increased A in radish and transpiration in barley. Growth rates and final dry weights were reduced for all of the six test species when addition rates exceeded 10 Mg ha{sup -1} for gray ash and 5 Mg ha{sup -1} for red ash. We concluded that plant dry weights, rather than pigment concentrations and/or instantaneous rates of photosynthesis, are more consistent for assessing subsequent growth in plants supplied with fly ash.

  13. Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia

    SciTech Connect (OSTI)

    Vukasinovic-Pesic, V.; Rajakovic, L.J. [University of Montenegro, Podgorica (Montenegro)

    2009-07-01

    The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn in the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.

  14. Clean Coal Program Research Activities

    SciTech Connect (OSTI)

    Larry Baxter; Eric Eddings; Thomas Fletcher; Kerry Kelly; JoAnn Lighty; Ronald Pugmire; Adel Sarofim; Geoffrey Silcox; Phillip Smith; Jeremy Thornock; Jost Wendt; Kevin Whitty

    2009-03-31

    Although remarkable progress has been made in developing technologies for the clean and efficient utilization of coal, the biggest challenge in the utilization of coal is still the protection of the environment. Specifically, electric utilities face increasingly stringent restriction on the emissions of NO{sub x} and SO{sub x}, new mercury emission standards, and mounting pressure for the mitigation of CO{sub 2} emissions, an environmental challenge that is greater than any they have previously faced. The Utah Clean Coal Program addressed issues related to innovations for existing power plants including retrofit technologies for carbon capture and sequestration (CCS) or green field plants with CCS. The Program focused on the following areas: simulation, mercury control, oxycoal combustion, gasification, sequestration, chemical looping combustion, materials investigations and student research experiences. The goal of this program was to begin to integrate the experimental and simulation activities and to partner with NETL researchers to integrate the Program's results with those at NETL, using simulation as the vehicle for integration and innovation. The investigators also committed to training students in coal utilization technology tuned to the environmental constraints that we face in the future; to this end the Program supported approximately 12 graduate students toward the completion of their graduate degree in addition to numerous undergraduate students. With the increased importance of coal for energy independence, training of graduate and undergraduate students in the development of new technologies is critical.

  15. Development of an Advanced Deshaling Technology to Improve the Energy Efficiency of Coal Handling, Processing, and Utilization Operations

    SciTech Connect (OSTI)

    Rick Honaker; Gerald Luttrell

    2007-09-30

    The concept of using a dry, density-based separator to achieve efficient, near-face rock removal, commonly referred to as deshaling, was evaluated in several applications across the U.S.. Varying amounts of high-density rock exist in most run-of-mine feed. In the central Appalachian coalfields, a rock content exceeding 50% in the feed to a preparation plant is commonplace due to high amounts of out-of-seam dilution made necessary by extracting coal from thin seams. In the western U.S, an increase in out-of-seam dilution and environmental regulations associated with combustion emissions have resulted in a need to clean low rank coals and dry cleaning may be the only option. A 5 ton/hr mobile deshaling unit incorporating a density-based, air-table technology commercially known as the FGX Separator has been evaluated at mine sites located within the states of Utah, Wyoming, Texas, West Virginia, Virginia, Pennsylvania and Kentucky. The FGX technology utilizes table riffling principles with air as the medium. Air enters through the table and creates a fluidized bed of particles comprised of mostly fine, high density particles. The high density particle bed lifts the low-density coal particles to the top of the bed. The low-density coal moves toward the front of the table due to mass action and the downward slope of the table. The high-density particles settle through the fluidized particle bed and, upon making contact with the table, moves toward the back of the table with the assistance of table vibration. As a result, the low-density coal particles exit the front of the table closest to the feed whereas the high-density, high-ash content particles leave on the side and front of the table located at the farthest from the feed entry. At each test site, the run-of-mine feed was either directly fed to the FGX unit or pre-screened to remove the majority of the -6mm material. The surface moisture of the feed must be maintained below 9%. Pre-screening is required when the surface moisture of the feed coal exceeds the maximum limit. However, the content of -6mm in the feed to the FGX separator should be maintained between 10% and 20% to ensure an adequate fluidized bed. A parametric evaluation was conducted using a 3-level experimental design at each test site to identify the optimum separation performance and parameter values. The test data was used to develop empirical expressions that describe the response variables (i.e., mass yield and product ash content) as a function of the operating parameter values. From this process, it was established that table frequency and longitudinal slope are the most critical factors in controlling both mass yield and clean coal ash while the cross table slope was the least significant. Fan blower frequency is a critical parameter that controls mass yield. Although the splitter positions between product and middling streams and the middling and tailing streams were held constant during the tests, a separate evaluation indicated that performance is sensitive to splitter position within certain lengths of the table and insensitive in others. For a Utah bituminous coal, the FGX separator provided clean coal ash contents that ranged from a low of 8.57% to a high of 12.48% from a feed coal containing around 17% ash. From the 29 tests involved in the statistically designed test program, the average clean coal ash content was 10.76% while the tailings ash content averaged around 72%. One of the best separation performances achieved an ash reduction from 17.36% to 10.67% while recovering 85.9% of the total feed mass, which equated to an ash rejection value of around 47%. The total sulfur content was typically decreased from 1.61% to 1.49%. These performances were quantified by blending the middlings stream with the clean coal product. At a second Utah site, coal sources from three different bituminous coal seams were treated by the FGX deshaling unit. Three parameter values were varied based on the results obtained from Site No. 1 to obtain the optimum results shown in Table E-1. Approximately 9 tests w

  16. PARAMETRIC STUDY OF SUBMICRON PARTICULATES FROM PULVERIZED COAL COMBUSTION

    E-Print Network [OSTI]

    Pennucci, J.

    2014-01-01

    TABLE l PITTSBURG SEAM COAL PROPERTIES Proximate Analysiscoal boiler. The coal, whose properties are given in Table

  17. COAL LIQUEFACTION ALLOY TEST PROGRAM ANNUAL REPORT FY 1978

    E-Print Network [OSTI]

    Levy, A.

    2014-01-01

    by weight of ground coal of the type used in the Wilsonvilleless coal particle degradation than centrifugal type pumps

  18. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    ??????? ??????????????"); IEA, WEO 2007; IEA Greenhouse Gastonnes exceeded the IEA’s WEO 2000 forecast for 2020 coalCoal Consumption, 1980-2025 WEO 2008 IEO 2008 IEO 2000 NDRC

  19. Clean Coal Incentive Tax Credit (Kentucky)

    Broader source: Energy.gov [DOE]

    Clean Coal Incentive Tax Credit provides for a property tax credit for new clean coal facilities constructed at a cost exceeding $150 million and used for the purposes of generating electricity....

  20. China's Coal: Demand, Constraints, and Externalities

    SciTech Connect (OSTI)

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01

    This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

  1. Clean Coal Power Initiative | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    "Clean coal technology" describes a new generation of energy processes that sharply reduce air emissions and other pollutants from coal-burning power plants. In the late 1980s and...

  2. Respiratory disease in Utah coal miners

    SciTech Connect (OSTI)

    Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

    1981-04-01

    Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's penumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

  3. Respiratory disease in Utah coal miners

    SciTech Connect (OSTI)

    Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

    1981-04-01

    Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's pneumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

  4. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  5. February 21 -22, 2014 Coast Coal Harbour

    E-Print Network [OSTI]

    Handy, Todd C.

    February 21 - 22, 2014 Coast Coal Harbour 1180 W Hastings St Vancouver, BC Healthy Mothers contact by phone: +1 604-822- 7708 or by e-mail: melissa.ipce@ubc.ca. Location The Coast Coal Harbour

  6. ASHLAND COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL

    E-Print Network [OSTI]

    Chapter PA ASHLAND COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

  7. EFFECT OF COAL DUST ONEFFECT OF COAL DUST ON RAILROAD BALLAST STRENGTHRAILROAD BALLAST STRENGTH

    E-Print Network [OSTI]

    Barkan, Christopher P.L.

    1 EFFECT OF COAL DUST ONEFFECT OF COAL DUST ON RAILROAD BALLAST STRENGTHRAILROAD BALLAST STRENGTH for Laboratory StudyFouling Mechanism / Need for Laboratory Study Mechanical Properties of Coal DustMechanical Properties of Coal Dust Grain Size AnalysisGrain Size Analysis AtterbergAtterberg LimitsLimits Specific

  8. Argonne Premium Coal Sample Bank The Argonne Premium Coal (APC) Sample Bank can supply

    E-Print Network [OSTI]

    Maranas, Costas

    Argonne Premium Coal Sample Bank Background Overview T The Argonne Premium Coal (APC) Sample Bank can supply researchers with highly uniform, well-protected coal samples unexposed to oxygen. Researchers investigating coal structure, properties, and behavior can benefit greatly from these samples

  9. Arrowhead Center: Coal Production and Regional Economic Growth Report Title: Coal Production and Regional Economic Growth

    E-Print Network [OSTI]

    Johnson, Eric E.

    Arrowhead Center: Coal Production and Regional Economic Growth Report Title: Coal Production@nmsu.edu #12;Arrowhead Center: Coal Production and Regional Economic Growth i Disclaimer This report States Government or any agency thereof. #12;Arrowhead Center: Coal Production and Regional Economic

  10. DECKER COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL

    E-Print Network [OSTI]

    Chapter PD DECKER COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL RESOURCES Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U.S. Geological Survey of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great Plains region, U

  11. SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES

    E-Print Network [OSTI]

    Chapter PH SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES By M assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

  12. Proceedings, twenty-fourth annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    2007-07-01

    Topics covered include: gasification technologies; coal production and preparation; combustion technologies; environmental control technologies; synthesis of liquid fuels, chemicals, materials and other non-fuel uses of coal; hydrogen from coal; advanced synthesis gas cleanup; coal chemistry, geosciences and resources; Fischer-Tropsch technology; coal and sustainability; global climate change; gasification (including underground gasification); materials, instrumentation and controls; and coal utilisation byproducts.

  13. Coal liquefaction with preasphaltene recycle

    DOE Patents [OSTI]

    Weimer, Robert F. (Allentown, PA); Miller, Robert N. (Allentown, PA)

    1986-01-01

    A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

  14. Cokemaking from coals of Kuzbas and Donbas

    SciTech Connect (OSTI)

    Umansky, R.Z. [Resourcecomplect, Donetsk (Ukraine); Kovalev, E.T.; Drozdnik, I.D. [UKHIN, Kharkov (Ukraine)

    1997-12-31

    The paper discusses features of Donetsk and Kuznetsk coals, the export capability of Ukraine coking industry, the selection of coal blends involving coals from different basins, and practical recommendations and techno-economic considerations. It is concluded that by raising the share of low-sulfur Kuznetsk coal in the blend to 50%, coke produced will meet all the requirements of European and American consumers.

  15. National Coal celebrates its fifth anniversary

    SciTech Connect (OSTI)

    Fiscor, S.

    2008-06-15

    The growth and activities of the National Coal Corp since its formation in 2003 are described. 5 photos.

  16. Canada's coal industry: full swing ahead

    SciTech Connect (OSTI)

    Stone, K. [Natural Resources Canada (Canada). Minerals and Metals Sector

    2007-03-15

    The article presents facts and figures about Canada's coal industry in 2006 including production, exports, imports, mines in operation, the Genesee 3 coal-fired generation unit, the Dodds-Roundhill Gasification Project, and new coal mine development plans. The outlook for 2007 is positive, with coal production expected to increase from 67 Mt in 2006 to 70 Mt in 2007 and exports expected to increase from 28 Mt in 2006 to 30 Mt in 2007.

  17. Outlook and Challenges for Chinese Coal

    SciTech Connect (OSTI)

    Aden, Nathaniel T.; Fridley, David G.; Zheng, Nina

    2008-06-20

    China has been, is, and will continue to be a coal-powered economy. The rapid growth of coal demand since 2001 has created deepening strains and bottlenecks that raise questions about supply security. Although China's coal is 'plentiful,' published academic and policy analyses indicate that peak production will likely occur between 2016 and 2029. Given the current economic growth trajectory, domestic production constraints will lead to a coal gap that is not likely to be filled with imports. Urbanization, heavy industry growth, and increasing per-capita consumption are the primary drivers of rising coal usage. In 2006, the power sector, iron and steel, and cement accounted for 71% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units could save only 14% of projected 2025 coal demand. If China follows Japan, steel production would peak by 2015; cement is likely to follow a similar trajectory. A fourth wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. New demand from coal-to-liquids and coal-to-chemicals may add 450 million tonnes of coal demand by 2025. Efficient growth among these drivers indicates that China's annual coal demand will reach 4.2 to 4.7 billion tonnes by 2025. Central government support for nuclear and renewable energy has not been able to reduce China's growing dependence on coal for primary energy. Few substitution options exist: offsetting one year of recent coal demand growth would require over 107 billion cubic meters of natural gas, 48 GW of nuclear, or 86 GW of hydropower capacity. While these alternatives will continue to grow, the scale of development using existing technologies will be insufficient to substitute significant coal demand before 2025. The central role of heavy industry in GDP growth and the difficulty of substituting other fuels suggest that coal consumption is inextricably entwined with China's economy in its current mode of growth. Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on its current growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Broadening awareness of the environmental costs of coal mining, transport, and combustion is raising the pressure on Chinese policy makers to find alternative energy sources. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China is short of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport. Transporting coal to users has overloaded the train system and dramatically increased truck use, raising transport oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 mt by 2025, significantly impacting regional markets. The looming coal gap threatens to derail China's growth path, possibly undermining political, economic, and social stability. High coal prices and domestic shortages will have regional and global effects. Regarding China's role as a global manufacturing center, a domestic coal gap will increase prices and constrain growth. Within the Asia-Pacific region, China's coal gap is likely to bring about increased competition with other coal-importing countries including Japan, South Korea, Taiwan, and India. As with petroleum, China may respond with a government-supported 'going-out' strategy of resource acquisition and vertical integration. Given its population and growing resource constraints, China may favor energy security, competitiveness, and local environmental protection over global climate change mitigation. The possibility of a large coal gap suggests that Chinese and international policy makers should maximize institutional and financial support

  18. Estimating coal production peak and trends of coal imports in China

    SciTech Connect (OSTI)

    Bo-qiang Lin; Jiang-hua Liu

    2010-01-15

    More than 20 countries in the world have already reached a maximum capacity in their coal production (peak coal production) such as Japan, the United Kingdom and Germany. China, home to the third largest coal reserves in the world, is the world's largest coal producer and consumer, making it part of the Big Six. At present, however, China's coal production has not yet reached its peak. In this article, logistic curves and Gaussian curves are used to predict China's coal peak and the results show that it will be between the late 2020s and the early 2030s. Based on the predictions of coal production and consumption, China's net coal import could be estimated for coming years. This article also analyzes the impact of China's net coal import on the international coal market, especially the Asian market, and on China's economic development and energy security. 16 refs., 5 figs., 6 tabs.

  19. Supersonic coal water slurry fuel atomizer

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Balsavich, John (Foxborough, MA)

    1991-01-01

    A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities.

  20. Chlorine in coal and boiler corrosion

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M. [Illinois State Geological Survey, Champaign, IL (United States); Pan, W.P.; Liu, L. [Western Kentucky Univ., Bowling Green, KY (United States); Huggins, F.E.; Huffman, G.P. [Univ. of Kentucky, Lexington, KY (United States); Ho, K.K. [Illinois Clean Coal Inst., Carbondale, IL (United States)

    1994-12-31

    Corrosion of superheaters in the United Kingdom has been attributed to the high level of chlorine (Cl) in British coals. On the other hand, similar high-Cl Illinois coals have not caused boiler corrosion. This suggests that the extent of boiler corrosion due to Cl may not be directly related to the amount of Cl in the coal but to how the Cl occurs in the coal or to other factors. In this study, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine the thermal evolution characteristics and the forms of Cl in four Illinois and four British coals. The TGA-FTIR results indicate that under oxidizing conditions, both British and Illinois coals release hydrogen chloride (HCl) gas. Maximum evolution of HCl gas from Illinois coals occurs near 425 C, whereas, the temperature of maximum HCl release from British coals occurs between 210 and 280 C. The XANES results indicate that Cl in coal exists in ionic forms including a solid salt form. The HCl evolution profiles of the Illinois and British coals suggests that the way in which Cl ions are associated in Illinois coals is of different from the way they are associated in British coals.

  1. Energy Systems Engineering 1 Clean Coal Technologies

    E-Print Network [OSTI]

    Banerjee, Rangan

    Energy Systems Engineering 1 Clean Coal Technologies Presentation at BARC 4th December 2007 #12/kWh) 0.14 0.03 0.6 #12;Energy Systems Engineering 9 Status of Advanced Coal Technologies Types of advanced coal technologies Supercritical Pulverised Combustion Circulating Fluidised Bed Combustion (CFBC

  2. Selective flotation of inorganic sulfides from coal

    DOE Patents [OSTI]

    Miller, K.J.; Wen, Wu-Wey

    1988-05-31

    Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow. 1 fig., 2 tabs.

  3. Selective flotation of inorganic sulfides from coal

    DOE Patents [OSTI]

    Miller, Kenneth J. (Floreffe, PA); Wen, Wu-Wey (Murrysville, PA)

    1989-01-01

    Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow.

  4. Low-rank coal oil agglomeration

    DOE Patents [OSTI]

    Knudson, C.L.; Timpe, R.C.

    1991-07-16

    A low-rank coal oil agglomeration process is described. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and is usually coal-derived.

  5. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Derbidge, T. Craig (Sunnyvale, CA); Mulholland, James A. (Chapel Hill, NC); Foster, Edward P. (Macungie, PA)

    1986-01-01

    An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

  6. Review of a Proposed Quarterly Coal Publication

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This Review of a Proposed Quartery Coal Publication contains findings and recommendations regarding the content of a new summary Energy Information Administration (EIA) coal and coke publication entitled The Quarterly Coal Review (QCR). It is divided into five sections: results of interviews with selected EIA data users; identification of major functions of the coal and coke industries; analysis of coal and coke data collection activities; evaluation of issues conerning data presentation including recommendations for the content of the proposed QCR; and comparison of the proposed QCR with other EIA publications. Major findings and recommendations are as follows: (1) User interviews indicate a definite need for a compehensive publication that would support analyses and examine economic, supply and demand trends in the coal industry; (2) the organization of the publication should reflect the natural order of activities of the coal and coke industries. Based on an analysis of the industries, these functions are: production, stocks, imports, exports, distribution, and consumption; (3) current EIA coal and coke surveys collect sufficient data to provide a summary of the coal and coke industries on a quarterly basis; (4) coal and coke data should be presented separately. Coke data could be presented as an appendix; (5) three geographic aggregations are recommended in the QCR. These are: US total, coal producing districts, and state; (6) coal consumption data should be consolidated into four major consumer categories: electric utilities, coke plants, other industrial, and residential commercial; (7) several EIA publications could be eliminated by the proposed QCR.

  7. Oil and coal: reserves and production

    E-Print Network [OSTI]

    Canada Japan F.R I United Germany Kingdom France Italy Fig. 2. Oil's share of the increase in energy useOil and coal: reserves and production Anton Ziolkowski* The 1984-85 strike by British coal miners has focused attention on the difficulties of the coal industry at a time when demand for energy

  8. Steam Plant Conversion Eliminating Campus Coal Use

    E-Print Network [OSTI]

    Dai, Pengcheng

    Steam Plant Conversion Eliminating Campus Coal Use at the Steam Plant #12;· Flagship campus region produce 14% of US coal (TN only 0.2%) Knoxville and the TN Valley #12;· UT is one of about 70 U.S. colleges and universities w/ steam plant that burns coal · Constructed in 1964, provides steam for

  9. Consensus Coal Production And Price Forecast For

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Consensus Coal Production And Price Forecast For West Virginia: 2011 Update Prepared for the West December 2011 © Copyright 2011 WVU Research Corporation #12;#12;W.Va. Consensus Coal Forecast Update 2011 i Table of Contents Executive Summary 1 Recent Developments 3 Consensus Coal Production And Price Forecast

  10. Demonstration of a Piston Plug feed System for Feeding Coal/Biomass Mixtures across a Pressure Gradient for Application to a Commercial CBTL System

    SciTech Connect (OSTI)

    Santosh Gangwal

    2011-06-30

    Producing liquid transportation fuels and power via coal and biomass to liquids (CBTL) and integrated gasification combined cycle (IGCC) processes can significantly improve the nation's energy security. The Energy Independence and Security Act of 2007 mandates increasing renewable fuels nearly 10-fold to >2.3 million barrels per day by 2022. Coal is abundantly available and coal to liquids (CTL) plants can be deployed today, but they will not become sustainable without large scale CO{sub 2} capture and storage. Co-processing of coal and biomass in CBTL processes in a 60 to 40 ratio is an attractive option that has the potential to produce 4 million barrels of transportation fuels per day by 2020 at the same level of CO{sub 2} emission as petroleum. In this work, Southern Research Institute (Southern) has made an attempt to address one of the major barriers to the development of large scale CBTL processes - cost effective/reliable dry-feeding of coal-biomass mixtures into a high pressure vessel representative of commercial entrained-flow gasifiers. Present method for dry coal feeding involves the use of pressurized lock-hopper arrangements that are not only very expensive with large space requirements but also have not been proven for reliably feeding coal-biomass mixtures without the potential problems of segregation and bridging. The project involved the development of a pilot-scale 250 lb/h high pressure dry coal-biomass mixture feeder provided by TKEnergi and proven for feeding biomass at a scale up to 6 ton/day. The aim of this project is to demonstrate cost effective feeding of coal-biomass mixtures (50:50 to 70:30) made from a variety of coals (bituminous, lignite) and biomass (wood, corn stover, switch grass). The feeder uses a hydraulic piston-based approach to produce a series of plugs of the mixture that act as a seal against high back-pressure of the gasification vessel in to which the mixture is being fed. The plugs are then fed one by one via a plug breaker into the high pressure gasification vessel. A number of runs involving the feeding of coal and biomass mixtures containing 50 to 70 weight % coal into a high pressure gasification vessel simulator have shown that plugs of sufficient density can be formed to provide a seal against pressures up to 450 psig if homogeneity of the mixture can be maintained. However, the in-homogeneity of coal-biomass mixtures can occur during the mixing process because of density, particle size and moisture differences. Also, the much lower compressibility of coal as opposed to biomass can contribute to non-uniform plug formation which can result in weak plugs. Based on present information, the piston plug feeder offered marginal economic advantages over lock-hoppers. The results suggest a modification to the piston feeder that can potentially seal against pressure without the need for forming plugs. This modified design could result in lower power requirements and potentially better economics.

  11. Coal conversion. 1979 technical report

    SciTech Connect (OSTI)

    None

    1980-09-01

    Individual reports are made on research programs which are being conducted by various organizations and institutions for the commercial development of processes for converting coal into products that substitute for these derived from oil and natural gas. Gasification, liquefaction, and demonstration processes and plants are covered. (DLC)

  12. Configurational diffusion of coal macromolecules

    SciTech Connect (OSTI)

    Guin, J.A.; Curtis, C.W.; Tarrer, A.R.; Kim, S.; Hwang, D.; Chen, C.C.; Chiou, Z.

    1991-01-01

    The objective of our research was to obtain fundamental information regarding the functional dependence of the diffusion coefficient of coal molecules on the ratio of molecule to pore diameter. That is, the objective of our study was to examine the effect of molecule size and configuration on hindered diffusion of coal macromolecules through as porous medium. To best accomplish this task, we circumvented the complexities of an actual porous catalyst by using a well defined porous matrix with uniform capillaric pores, i.e., a track-etched membrane. In this way, useful information was obtained regarding the relationship of molecular size and configuration on the diffusion rate of coal derived macromolecules through a pore structure with known geometry. Similar studies were performed using a pellet formed of porous alumina, to provide a link between the idealized membranes and the actual complex pore structure of real catalyst extrudates. The fundamental information from our study will be useful toward the tailoring of catalysts to minimize diffusional influences and thereby increase coal conversion and selectivity for desirable products. (VC)

  13. Cooperative research in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.; Sendlein, L.V.A. (eds.)

    1991-05-28

    Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.

  14. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

    1981-01-01

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  15. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01

    18 Effect of React Run No. Coal Type on Cat. /Coal Ratios of300°C P = 2000 ps Run No. Coal Type Wyodak Imp reg- Sol. , %Wyodak Coal, and Illinois #6 Coal Type of Coal Carbon Wyodak

  16. Effect of microwave radiation on coal flotation

    SciTech Connect (OSTI)

    Ozbayoglu, G.; Depci, T.; Ataman, N. [Middle East Technical University, Ankara (Turkey). Mining Engineering Department

    2009-07-01

    Most low-rank coals are high in moisture and acid functional groups, therefore showing poor floatability. Drying, which removes the water molecules trapped in the pores and adsorbed at the surface of coal, decreases the hydrophilic character and improves the floatability. Microwave heating, whose simplest application is drying, was applied at 0.9 kW power level for 60 sec exposure time in the experiments to decrease the moisture content of coal in order to enhance the hydrophobicity. The flotation tests of microwave-treated coal by using heptanol and octanol lead to a higher flotation yield and ash removal than original coal.

  17. Coal storage hopper with vibrating screen agitator

    DOE Patents [OSTI]

    Daw, Charles S. (Knoxville, TN); Lackey, Mack E. (Oak Ridge, TN); Sy, Ronald L. (Clinton, TN)

    1984-01-01

    The present invention is directed to a vibrating screen agitator in a coal storage hopper for assuring the uniform feed of coal having sufficient moisture content to effect agglomeration and bridging thereof in the coal hopper from the latter onto a conveyor mechanism. The vibrating screen agitator is provided by a plurality of transversely oriented and vertically spaced apart screens in the storage hopper with a plurality of vertically oriented rods attached to the screens. The rods are vibrated to effect the vibration of the screens and the breaking up of agglomerates in the coal which might impede the uniform flow of the coal from the hopper onto a conveyer.

  18. Process for selective grinding of coal

    SciTech Connect (OSTI)

    Venkatachari, Mukund K.; Benz, August D.; Huettenhain, Horst

    1991-01-01

    A process for preparing coal for use as a fuel. Forming a coal-water slurry having solid coal particles with a particle size not exceeding about 80 microns, transferring the coal-water slurry to a solid bowl centrifuge, and operating same to classify the ground coal-water slurry to provide a centrate containing solid particles with a particle size distribution of from about 5 microns to about 20 microns and a centrifuge cake of solids having a particle size distribution of from about 10 microns to about 80 microns. The classifer cake is reground and mixed with fresh feed to the solid bowl centrifuge for additional classification.

  19. Quarterly coal report, October--December 1996

    SciTech Connect (OSTI)

    1997-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for October through December 1996 and aggregated quarterly historical data for 1990 through the third quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 72 tabs.

  20. Picobubble enhanced fine coal flotation

    SciTech Connect (OSTI)

    Tao, Y.J.; Liu, J.T.; Yu, S.; Tao, D. [University of Kentucky, Lexington, KY (United States). Dept. of Mining Engineering

    2006-07-01

    Froth flotation is widely used in the coal industry to clean -28 mesh fine coal. A successful recovery of particles by flotation depends on efficient particle-bubble collision and attachment with minimal subsequent particle detachment from bubble. Flotation is effective in a narrow size range beyond which the flotation efficiency drops drastically. It is now known that the low flotation recovery of particles in the finest size fractions is mainly due to a low probability of bubble-particle collision while the main reason for poor coarse particle flotation recovery is the high probability of detachment. A fundamental analysis has shown that use of picobubbles can significantly improve the flotation recovery of particles in a wide range of size by increasing the probability of collision and attachment and reducing the probability of detachment. A specially designed column with a picobubble generator has been developed for enhanced recovery of fine coal particles. Picobubbles were produced based on the hydrodynamic cavitation principle. They are characterized by a size distribution that is mostly below 1 {mu}m and adhere preferentially to the hydrophobic surfaces. The presence of picobubbles increases the probability of collision and attachment and decreases the probability of detachment, thus enhancing flotation recovery. Experimental results with the Coalberg seam coal in West Virginia, U.S.A. have shown that the use of picobubbles in a 2 in. column flotation increased fine coal recovery by 10-30%, depending on the feed rate, collector dosage, and other flotation conditions. Picobubbles also acted as a secondary collector and reduced the collector dosage by one third to one half.

  1. OXIDATION OF MERCURY ACROSS SCR CATALYSTS IN COAL-FIRED POWER PLANTS BURNING LOW RANK FUELS

    SciTech Connect (OSTI)

    Constance Senior

    2004-12-31

    The objectives of this program were to measure the oxidation of mercury in flue gas across SCR catalyst in a coal-fired power plant burning low rank fuels using a slipstream reactor containing multiple commercial catalysts in parallel and to develop a greater understanding of mercury oxidation across SCR catalysts in the form of a simple model. The Electric Power Research Institute (EPRI) and Argillon GmbH provided co-funding for this program. REI used a multicatalyst slipstream reactor to determine oxidation of mercury across five commercial SCR catalysts at a power plant that burned a blend of 87% subbituminous coal and 13% bituminous coal. The chlorine content of the blend was 100 to 240 {micro}g/g on a dry basis. Mercury measurements were carried out when the catalysts were relatively new, corresponding to about 300 hours of operation and again after 2,200 hours of operation. NO{sub x}, O{sub 2} and gaseous mercury speciation at the inlet and at the outlet of each catalyst chamber were measured. In general, the catalysts all appeared capable of achieving about 90% NO{sub x} reduction at a space velocity of 3,000 hr{sup -1} when new, which is typical of full-scale installations; after 2,200 hours exposure to flue gas, some of the catalysts appeared to lose NO{sub x} activity. For the fresh commercial catalysts, oxidation of mercury was in the range of 25% to 65% at typical full-scale space velocities. A blank monolith showed no oxidation of mercury under any conditions. All catalysts showed higher mercury oxidation without ammonia, consistent with full-scale measurements. After exposure to flue gas for 2,200 hours, some of the catalysts showed reduced levels of mercury oxidation relative to the initial levels of oxidation. A model of Hg oxidation across SCRs was formulated based on full-scale data. The model took into account the effects of temperature, space velocity, catalyst type and HCl concentration in the flue gas.

  2. A study of coal production in Nigeria

    SciTech Connect (OSTI)

    Akarakiri, J.B.; Afonja, A.A.; Okejiri, E.C. (Obafemi Awolowo Univ., Lle-Lfe (Nigeria))

    1991-01-01

    The Nigerian coal industry was studied. The focus was on the problems which have caused low production output of coal. More specifically, the study examined the present techniques of coal production, the causes of low production of coal, the coal production policy as it affected this study, and proposed policy measures to address the findings. It was discovered that some of the limiting factors to coal production in Nigeria could be attributed to the lack of the following: (i) clear and specific production-demand targets set for coal in Nigeria; (ii) adequate technological capability to mechanize coal mining operations in Nigeria; (iii) venture capital to invest in coal production; (iv) poor infrastructural facilities for coal production such as mining, storage, transportation, etc. It was also discovered that the dissatisfaction of the miners with their conditions of service influenced production capacity negatively. These findings point to the reality that coal is unlikely to play a major role in the country's energy equation in the near future unless serious efforts are made to address the above issues.

  3. Coal Gasification for Power Generation, 3. edition

    SciTech Connect (OSTI)

    NONE

    2007-11-15

    The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

  4. Materials challenges in advanced coal conversion technologies

    SciTech Connect (OSTI)

    Powem, C.A.; Morreale, B.D. [National Energy Technology Laboratory, Albany, OR (United States)

    2008-04-15

    Coal is a critical component in the international energy portfolio, used extensively for electricity generation. Coal is also readily converted to liquid fuels and/or hydrogen for the transportation industry. However, energy extracted from coal comes at a large environmental price: coal combustion can produce large quantities of ash and CO{sub 2}, as well as other pollutants. Advanced technologies can increase the efficiencies and decrease the emissions associated with burning coal and provide an opportunity for CO{sub 2} capture and sequestration. However, these advanced technologies increase the severity of plant operating conditions and thus require improved materials that can stand up to the harsh operating environments. The materials challenges offered by advanced coal conversion technologies must be solved in order to make burning coal an economically and environmentally sound choice for producing energy.

  5. CORROSION OF IRON-BASE ALLOYS BY COAL CHAR AT 871 AND 982 C

    E-Print Network [OSTI]

    Gordon, Bruce Abbott

    2011-01-01

    Introduction Chapter 1. A. B. C. D. E. Coal Processingand Coal Char iThe Energy Crisis Coal Processing . Corrosion .

  6. ENERGY AND ENVIRONMENT DIVISION. INTERACTION OF ORGANIC SOLVENT WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Lindsey, D.

    2011-01-01

    ~. ~. ~. ~. Procedure . . . . . . . . . . . Coal and Solventon Subbiturninous Coal Below Pyrolysis Temperatures, LBL-Treatment of Extract Solution Coal Residue Treatment. Yield

  7. Proceedings, twenty-five annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    NONE

    2008-07-01

    The conference theme was 'coal - energy, environment and sustainable development'. The topics covered energy and environmental issues, and technologies related to coal and its byproducts. These included: gasification, hydrogen from coal, combustion technologies, coal production and preparation, synthesis of liquid fuels, gas turbines and fuel cells for synthesis gas and hydrogen applications, coal chemistry and geosciences, global climate change, underground coal gasification, environmental control technologies, and coal utilization byproducts.

  8. INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Dorighi, G.P.

    2010-01-01

    conversion of western coals into liquid products. A largeconsist of the coal derived organic liquid, unreacted coal,action of coal with an organic liquid solvent represents a

  9. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01

    Pipeline Transport Coal Transportation Costs References . .acid, cost of raw coal, and transportation costs have aadditional cost. COAL TRANSPORTATION COSTS The cost of coal

  10. Process for preparing bituminous composition

    SciTech Connect (OSTI)

    Berggren, M.A.

    1991-07-30

    This patent describes a process to produce a bitumen composition. It comprises providing a carbon black composition comprising carbon black with less than 10% by weight of the carbon black composition being bitumen and carbon black particles being of a particle size of from about 5 to 500 nanometers; blending the carbon black composition with 2 or more parts by weight of a block copolymer and less than 10% by weight bitumen, based on the total amount of block copolymer composition, the block copolymer selected from the group consisting of hydrogenated and unhydrogenated block copolymers, the block copolymer, before hydrogenation, combining the carbon black composition block copolymer blend with an amount of bitumen which results in 100 parts by weight of bitumen plus block copolymer to form a polymeric bitumen composition.

  11. HINDERED DIFFUSION OF COAL LIQUIDS

    SciTech Connect (OSTI)

    Theodore T. Tsotsis; Muhammad Sahimi; Ian A. Webster

    1996-01-01

    It was the purpose of the project described here to carry out careful and detailed investigations of petroleum and coal asphaltene transport through model porous systems under a broad range of temperature conditions. The experimental studies were to be coupled with detailed, in-depth statistical and molecular dynamics models intended to provide a fundamental understanding of the overall transport mechanisms and a more accurate concept of the asphaltene structure. The following discussion describes some of our accomplishments.

  12. PNNL Coal Gasifier Transportation Logistics

    SciTech Connect (OSTI)

    Reid, Douglas J.; Guzman, Anthony D.

    2011-04-13

    This report provides Pacific Northwest National laboratory (PNNL) craftspeople with the necessary information and suggested configurations to transport PNNL’s coal gasifier from its current location at the InEnTec facility in Richland, Washington, to PNNL’s Laboratory Support Warehouse (LSW) for short-term storage. A method of securing the gasifier equipment is provided that complies with the tie-down requirements of the Federal Motor Carrier Safety Administration’s Cargo Securement Rules.

  13. Coal Mining on Pitching Seams

    E-Print Network [OSTI]

    Brown, George MacMillan

    1915-01-01

    compressed air post punchers are used. Where the coal is undercut permissible explosives are used. On all solid shooting black powder is used. It might be said right here that black powder has caused more fires, explosions and deaths than any other one... thing in Oklahoma mines, with the exception probably of falls of rock. However, under ruling of the United States Bureau of Mines black powder will probably eventually be excluded from all mines on Indian lands. On the lower entries, owing...

  14. Catalyst for coal liquefaction process

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Kang, Chia-Chen C. (Princeton, NJ)

    1984-01-01

    An improved catalyst for a coal liquefaction process; e.g., the H-Coal Process, for converting coal into liquid fuels, and where the conversion is carried out in an ebullated-catalyst-bed reactor wherein the coal contacts catalyst particles and is converted, in addition to liquid fuels, to gas and residual oil which includes preasphaltenes and asphaltenes. The improvement comprises a catalyst selected from the group consisting of the oxides of nickel molybdenum, cobalt molybdenum, cobalt tungsten, and nickel tungsten on a carrier of alumina, silica, or a combination of alumina and silica. The catalyst has a total pore volume of about 0.500 to about 0.900 cc/g and the pore volume comprises micropores, intermediate pores and macropores, the surface of the intermediate pores being sufficiently large to convert the preasphaltenes to asphaltenes and lighter molecules. The conversion of the asphaltenes takes place on the surface of micropores. The macropores are for metal deposition and to prevent catalyst agglomeration. The micropores have diameters between about 50 and about 200 angstroms (.ANG.) and comprise from about 50 to about 80% of the pore volume, whereas the intermediate pores have diameters between about 200 and 2000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume, and the macropores have diameters between about 2000 and about 10,000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume. The catalysts are further improved where they contain promoters. Such promoters include the oxides of vanadium, tungsten, copper, iron and barium, tin chloride, tin fluoride and rare earth metals.

  15. Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Rao, A. D.; Chen, Q.; Samuelsen, G. S.

    2012-09-30

    The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal performance between the various coproduct cases is further complicated by the fact that the carbon footprint is not the same when carbon leaving with the coproduct are accounted for. The economic analysis and demand for a particular coproduct in the market place is a more meaningful comparison of the various coproduction scenarios. The first year cost of electricity calculated for the bituminous coal is $102.9/MWh while that for the lignite is $108.1/MWh. The calculated cost of hydrogen ranged from $1.42/kg to $2.77/kg depending on the feedstock, which is lower than the DOE announced hydrogen cost goal of $3.00/kg in July 14, 2005. Methanol cost ranged from $345/MT to $617/MT, while the market price is around $450/MT. For Fischer-Tropsch liquids, the calculated cost ranged from $65/bbl to $112/bbl, which is comparable to the current market price of crude oil at around $100/bbl. It should be noted, however, that F-T liquids contain no sulfur and nitrogen compounds. The calculated cost of alcohol ranged from $4.37/gal to $5.43/gal, while it ranged from $2.20/gal to $3.70/gal in a DOE funded study conducted by Louisiana State University. The Louisiana State University study consisted of a significantly larger plant than our study and benefited from economies of scale. When the plant size in our study is scaled up to similar size as in the Louisiana State University study, cost of alcohol is then reduced to a range of $3.24/gal to $4.28/gal, which is comparable. Urea cost ranged from $307/MT to $428/MT, while the market price is around $480/MT.

  16. TOXIC SUBSTANCES FROM COAL COMBUSTION

    SciTech Connect (OSTI)

    Kolker, A.; Sarofim, A.F.; Palmer, C.A.; Huggins, F.E.; Huffman, G.P.; Lighty, J.; Veranth, J.; Helble, J.J.; Wendt, J.O.L.; Ames, M.R.; Finkelman, R.; Mamani-Paco, M.; Sterling, R.; Mroczkowsky, S.J.; Panagiotou, T.; Seames, W.

    1999-05-10

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environ-mental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NOx combustion systems, and new power generation plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 January 1999 to 31 March 1999. During this period, a full Program Review Meeting was held at the University of Arizona. At this meeting, the progress of each group was reviewed, plans for the following 9 month period were discussed, and action items (principally associated with the transfer of samples and reports among the various investigators) were identified.

  17. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, D.R.

    1987-07-07

    A process and apparatus are disclosed for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS[sub 2] to a troilite FeS form or a pyrrhotite form Fe[sub 1[minus]x]S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H[sub 2]S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents. 2 figs.

  18. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, David R. (Lexington, MA)

    1987-01-01

    A process and apparatus for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS.sub.2 to a troilite FeS form or a pyrrhotite form Fe.sub.1-x S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H.sub.2 S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents.

  19. Apparatus for solar coal gasification

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-04

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats through a window onto the surface of a moving bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam in one embodiment at the rear surface of a secondary mirror used to redirect the focused sunlight. Another novel feature of the invention is the location and arrangement of the array of mirrors on an inclined surface (e.g., a hillside) to provide for direct optical communication of said mirrors and the carbonaceous feed without a secondary redirecting mirror.

  20. China Energy Databook -- User Guide and Documentation, Version 7.0

    E-Print Network [OSTI]

    Fridley, Ed., David

    2008-01-01

    on April 21 and April 28 Coal type Region Qinhuangdao Port,u Wuhan Guangzhou N.B. Coal type is bituminous coal; coalFuels Corporations 2. Coal types: Dalian price is for Fuxin

  1. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2012-01-01

    back to cleaned coal (coking coal) and added to the rest ofother bituminous coal and coking coal. Small differences incoal (used as fuel) Coking coal Coke oven coke Natural gas

  2. Chemical comminution and deashing of low-rank coals

    DOE Patents [OSTI]

    Quigley, David R. (Idaho Falls, ID)

    1992-01-01

    A method of chemically comminuting a low-rank coal while at the same time increasing the heating value of the coal. A strong alkali solution is added to a low-rank coal to solubilize the carbonaceous portion of the coal, leaving behind the noncarbonaceous mineral matter portion. The solubilized coal is precipitated from solution by a multivalent cation, preferably calcium.

  3. Chemical comminution and deashing of low-rank coals

    DOE Patents [OSTI]

    Quigley, David R.

    1992-12-01

    A method of chemically comminuting a low-rank coal while at the same time increasing the heating value of the coal. A strong alkali solution is added to a low-rank coal to solubilize the carbonaceous portion of the coal, leaving behind the noncarbonaceous mineral matter portion. The solubilized coal is precipitated from solution by a multivalent cation, preferably calcium.

  4. Adsorption and Strain: The CO2-Induced Swelling of Coal

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Adsorption and Strain: The CO2-Induced Swelling of Coal M. Vandamme1 , L. Brochard2 , B. Lecampion3.07.014 #12;Abstract Enhanced coal bed methane recovery (ECBM) consists in injecting carbon dioxide in coal gets adsorbed at the surface of the coal pores, which causes the coal to swell. This swelling

  5. Clean Coal Technology Programs: Program Update 2009

    SciTech Connect (OSTI)

    2009-10-01

    The purpose of the Clean Coal Technology Programs: Program Update 2009 is to provide an updated status of the U.S. Department of Energy (DOE) commercial-scale demonstrations of clean coal technologies (CCT). These demonstrations have been performed under the Clean Coal Technology Demonstration Program (CCTDP), the Power Plant Improvement Initiative (PPII), and the Clean Coal Power Initiative (CCPI). Program Update 2009 provides: (1) a discussion of the role of clean coal technology demonstrations in improving the nation’s energy security and reliability, while protecting the environment using the nation’s most abundant energy resource—coal; (2) a summary of the funding and costs of the demonstrations; and (3) an overview of the technologies being demonstrated, along with fact sheets for projects that are active, recently completed, or recently discontinued.

  6. Coal distribution, January--June 1991

    SciTech Connect (OSTI)

    Not Available

    1991-10-21

    The Coal Distribution report provides information on coal production, distribution, and stocks in the United States to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. The data in this report are collected and published by the Energy Information Administration (EIA) to fulfill its data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275, Sections 5 and 13, as amended). This issue presents information for January through June 1991. Coal distribution data are shown (in Tables 1--34) by coal-producing Sate of origin, consumer use, method of transportation, and State of destination. All data in this report were collected by the EIA on Form EIA-6, Coal Distribution Report.'' A copy of the form and the instructions for filing appear in Appendix B. All data in this report for 1991 are preliminary. Data for previous years are final. 6 figs., 34 tabs.

  7. Clean coal technology programs: program update 2006

    SciTech Connect (OSTI)

    NONE

    2006-09-15

    The purpose of the Clean Coal Technology Programs: Program Update 2006 is to provide an updated status of the DOE commercial-scale demonstrations of clean coal technologies (CCTs). These demonstrations are performed under the Clean Coal Technology Demonstration Program (CCTDP), the Power Plant Improvement Initiative (PPII) and the Clean Coal Power Initiative (CCPI). Program Update 2006 provides 1) a discussion of the role of clean coal technology demonstrations in improving the nation's energy security and reliability, while protecting the environment using the nation's most abundant energy resource - coal; 2) a summary of the funding and costs of the demonstrations; and 3) an overview of the technologies being demonstrated, with fact sheets for demonstration projects that are active, recently completed, withdrawn or ended, including status as of June 30 2006. 4 apps.

  8. Novel Fuel Cells for Coal Based Systems

    SciTech Connect (OSTI)

    Thomas Tao

    2011-12-31

    The goal of this project was to acquire experimental data required to assess the feasibility of a Direct Coal power plant based upon an Electrochemical Looping (ECL) of Liquid Tin Anode Solid Oxide Fuel Cell (LTA-SOFC). The objective of Phase 1 was to experimentally characterize the interaction between the tin anode, coal fuel and cell component electrolyte, the fate of coal contaminants in a molten tin reactor (via chemistry) and their impact upon the YSZ electrolyte (via electrochemistry). The results of this work will provided the basis for further study in Phase 2. The objective of Phase 2 was to extend the study of coal impurities impact on fuel cell components other than electrolyte, more specifically to the anode current collector which is made of an electrically conducting ceramic jacket and broad based coal tin reduction. This work provided a basic proof-of-concept feasibility demonstration of the direct coal concept.

  9. Railroads and shippers clash over coal dust

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2007-11-15

    In an effort to reduce coal spillage from railcars, mines in the Powder River Basin (PRB) now load coal with a loaf profile but, reportedly, beginning in 2008, Burlington Northern Santa Fe (BNSF) will announce guidelines requiring all PRB coal loads to be sprayed with a chemical surfactant. If this does not fix the problem, greater measures will be taken. At the time of going to press, the details of how this would be implemented and regulated were unresolved. 1 photo.

  10. Process for treating moisture laden coal fines

    DOE Patents [OSTI]

    Davis, Burl E. (New Kensington, PA); Henry, Raymond M. (Gibsonia, PA); Trivett, Gordon S. (South Surrey, CA); Albaugh, Edgar W. (Birmingham, AL)

    1993-01-01

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  11. Quarterly coal report, July--September 1997

    SciTech Connect (OSTI)

    NONE

    1998-02-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks. Coke production consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1997 and aggregated quarterly historical data for 1991 through the second quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. 72 tabs.

  12. Statistical review of coal in Canada, 1997

    SciTech Connect (OSTI)

    Not Available

    1999-01-01

    The paper presents an annual review of the coal industry, including production, exports and imports, and consumption. An overview is given, followed by more detailed statistical data for the current year and preceding decade (supply and demand, value and volume of supply by province, coal production by class or province, exports by destination, coal consumed in power generation by province, electrical energy production by fuel type, domestic demand for primary energy by type).

  13. Fired heater for coal liquefaction process

    DOE Patents [OSTI]

    Ying, David H. S. (Macungie, PA); McDermott, Wayne T. (Allentown, PA); Givens, Edwin N. (Bethlehem, PA)

    1985-01-01

    A fired heater for a coal liquefaction process is operated under conditions to maximize the slurry slug frequency and thereby improve the heat transfer efficiency. The operating conditions controlled are (1) the pipe diameter and pipe arrangement, (2) the minimum coal/solvent slurry velocity, (3) the maximum gas superficial velocity, and (4) the range of the volumetric flow velocity ratio of gas to coal/solvent slurry.

  14. Reintroduction of Native FishReintroduction of Native Fish Species to Coal CreekSpecies to Coal Creek

    E-Print Network [OSTI]

    Gray, Matthew

    1 Reintroduction of Native FishReintroduction of Native Fish Species to Coal CreekSpecies to Coal Control and Reclamation ActSurface Mining Control and Reclamation Act of 1977of 1977 Coal Creek Watershed Foundation (2000)Coal Creek Watershed Foundation (2000) BackgroundBackground Fish populations in Coal Creek

  15. CO2 Sequestration in Unminable Coal with ECBMR -2010 Reprint -Proceedings 2010 International Pittsburgh Coal Conference, Istanbul, Turkey 1

    E-Print Network [OSTI]

    Wilson, Thomas H.

    CO2 Sequestration in Unminable Coal with ECBMR - 2010 Reprint - Proceedings 2010 International Pittsburgh Coal Conference, Istanbul, Turkey 1 CO2 SEQUESTRATION IN UNMINABLE COAL WITH ENHANCED COAL BED conducted in Marshall County, West Virginia, USA, to evaluate enhanced coal bed methane recovery

  16. Rheological properties of water-coal slurries based on brown coal in the presence of sodium lignosulfonates and alkali

    SciTech Connect (OSTI)

    D.P. Savitskii; A.S. Makarov; V.A. Zavgorodnii

    2009-07-01

    The effect of the oxidized surface of brown coal on the structural and rheological properties of water-coal slurries was found. The kinetics of structure formation processes in water-coal slurries based on as-received and oxidized brown coal was studied. The effect of lignosulfonate and alkali additives on the samples of brown coal was considered.

  17. Effects of the furnace temperature on the CO, CO{sub 2}, NO{sub x} and unburned hydrocarbon emissions from the combustion of coal and alternative fuels

    SciTech Connect (OSTI)

    Levendis, Y.A.; Atal, A.; Courtemanche, B.

    1999-07-01

    Results are presented on the emissions of carbon monoxide (CO), carbon dioxide (CO{sub 2}), unburned aromatic hydrocarbons, as well as oxides of nitrogen (NO{sub x}) from the combustion of pulverized bituminous coal, tire-derived fuel and, for a limited number of runs, waste plastics-derived fuel. The particle size cuts of pulverized coal, tire and plastics were 63--75 {micro}m and 180--300 {micro}m, respectively. Combustion experiments were conducted in a laboratory-scale drop-tube furnace at gas temperatures, in the range of 1,300--1,600 K, and several fuel mass loadings in the furnace, expressed in terms of global equivalence ratios in the range of 0.4--2.4. The CO, CO{sub 2} and NO{sub x} emissions were monitored continuously with infrared absorption and chemiluminescent instruments. Up to sixty 2-7 ring polynuclear aromatic hydrocarbons (PAH) were detected by capillary gas chromatography - mass spectrometry (GC-MS) techniques. Results showed that the PAH emission yields (mg/g fuel introduced) increased drastically with increasing bulk equivalence ratio (in the aforementioned range), at fixed furnace temperatures. This was also true for the CO yields, while the CO{sub 2} yields increased with increasing {o}, reached a maximum around stoichiometry and then decreased mildly. NO{sub x} yields decreased precipitously with increasing equivalence ratio. The CO and, especially, the PAH yields from tire-derived and plastics-derived fuels were much higher than those from coal, but the relative amounts of individual PAH components were remarkably similar in the combustion effluent of all fuels. The CO{sub 2} emissions and, especially, the NO{sub x} emissions from tire crumb were lower than those from coal. The CO{sub 2} emissions from plastics were comparable to those from coal, but their NO {sub x} emissions were much lower than those from tire. At fixed bulk equivalence ratios, however, as the furnace gas temperature increased the PAH yields from coal, tire crumb, and plastics decreased drastically, while the CO emission yields increased. At the highest temperature tested herein, 1,600 K ({approx}1,300 C), the effluent of the combustion of the fuels appeared to be devoid of PAHs. No{sub x} yields increased mildly with temperature. The influence of temperature, in this range, on the CO{sub 2} emissions was not significant. 65 refs., 2 figs., 1 tab.

  18. National Coal Council Meeting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    carbon technologies Infrastructure - to build and secure (generation, transmission, refineries) But let me return specifically to the issue of coal, where I think it is important...

  19. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    Source: Velocity Suite, Global Energy Data Advanced Coal Wind Hybrid: Economic Analysis 6.3.2 Comparison with Non-hybrid Competing

  20. Quarterly coal report, April--June 1990

    SciTech Connect (OSTI)

    Not Available

    1990-11-02

    The Quarterly Coal Report provides comprehensive information about US coal production, exports, imports, receipts, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. This issue presents detailed quarterly data for April 1990 through June 1990, aggregated quarterly historical data for 1982 through the second quarter of 1990, and aggregated annual historical data for 1960 through 1989 and projected data for selected years from 1995 through 2010. To provide a complete picture of coal supply and demand in the United States, historical information and forecasts have been integrated in this report. 7 figs., 37 tabs.

  1. Integrated two-stage coal liquefaction process

    DOE Patents [OSTI]

    Bronfenbrenner, James C. (Allentown, PA); Skinner, Ronald W. (Allentown, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01

    This invention relates to an improved two-stage process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal.

  2. Process for electrochemically gasifying coal using electromagnetism

    DOE Patents [OSTI]

    Botts, Thomas E. (Markham, VA); Powell, James R. (Shoreham, NY)

    1987-01-01

    A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

  3. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    and Reserves Circular. Beijing: MLR, cited in IEA. 2009.Cleaner Coal in China. Paris: IEA. Ghee Peh, Wei Ouyang. (London: WEC Press. IEA. (2007) World Energy Outlook 2007.

  4. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    delivered heating (district heating) (6%), and chemicalscoal growth. As district heating expands with urbanizationzone, coal use for district heating will depend on the

  5. Apparatus for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  6. Quarterly coal report, April--June 1997

    SciTech Connect (OSTI)

    NONE

    1997-11-01

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1997 and aggregated quarterly historical data for 1991 through the first quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 73 tabs.

  7. Production of Hydrogen from Underground Coal Gasification

    DOE Patents [OSTI]

    Upadhye, Ravindra S. (Pleasanton, CA)

    2008-10-07

    A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

  8. Tracking New Coal-Fired Power Plants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 8, 2010 National Energy Technology Laboratory Office of Systems Analyses and Planning Erik Shuster 2 Tracking New Coal-Fired Power Plants This report is intended to...

  9. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    IGCC PC advanced coal-wind hybrid combined cycle power plantnatural gas combined cycle gas turbine power plant carboncrude gasification combined cycle power plant with carbon

  10. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report You are accessing a document from the Department of Energy's (DOE)...

  11. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report In this Quarter, the research was focused continually on the...

  12. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    July--September 1995 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report, July--September 1995 The research was...

  13. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    October--December 1994 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report, October--December 1994 You are accessing a...

  14. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    July--September 1995 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report, July--September 1995 You are accessing...

  15. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    October--December 1994 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report, October--December 1994 In this Quarter, the...

  16. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report In this Quarter, the research was focused continually on the two...

  17. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report You are accessing a document from the Department of...

  18. Continuing consolidation in the coal industry

    SciTech Connect (OSTI)

    Gaalaas, T.

    2006-08-15

    Extensive consolidation has occurred in the coal industry over the past decade. The greatest degree of consolidation has occurred in Northern Appalachia, the Illinois Basin, and the Wyoming portion of the Powder River Basin (PRB), which are the coal supply regions where most observers expect the greatest growth in coal production over the next decade. In addition to reducing the number of alternative suppliers, high level of concentration also tend to result in higher prices, more volatile spot markets, and lower levels of reliability. Therefore, coal-fired generators purchasing in these regions need to respond proactively and strategically to these market trends. 2 figs.

  19. A study of the interfacial chemistry of pyrite and coal in fine coal cleaning using flotation

    SciTech Connect (OSTI)

    Jiang, C.

    1993-12-31

    Surface oxidation, surface charge, and flotation properties have been systematically studied for coal, coal-pyrite and ore-pyrite. Electrochemical studies show that coal-pyrite exhibits much higher and more complex surface oxidation than ore-pyrite and its oxidation rate depends strongly on the carbon/coal content. Flotation studies indicate that pyrites have no self-induced floatability. Fuel oil significantly improves the floatability of coal and induces considerable flotation for coal-pyrite due to the hydrophobic interaction of fuel oil with the carbon/coal inclusions on the pyrite surface. Xanthate is a good collector for ore-pyrite but a poor collector for coal and coal-pyrite. The results from thermodynamic calculations, flotation and zeta potential measurements show that iron ions greatly affect the flotation of pyrite with xanthate and fuel oil. Various organic and inorganic chemicals have been examined for depressing coal-pyrite. It was found, for the first time, that sodium pyrophosphate is an effective depressant for coal-pyrite. Solution chemistry shows that pyrophosphate reacts with iron ions to form stable iron pyrophosphate complexes. Using pyrophosphate, the complete separation of pyrite from coal can be realized over a wide pH range at relatively low dosage.

  20. Coal: world energy security. The Clearwater clean coal conference

    SciTech Connect (OSTI)

    Sakkestad, B. (ed.)

    2009-07-01

    Topics covered include: oxy-fuel (overview, demonstrations, experimental studies, burner developments, emissions, fundamental and advanced concepts); post-combustion CO{sub 2} capture; coal conversion to chemicals and fuels; advanced materials; hydrogen production from opportunity fuels; mercury abatement options for power plants; and carbon capture and storage in volume 1. Subjects covered in volume 2 include: advanced modelling; advanced concepts for emission control; gasification technology; biomass; low NOx technology; computer simulations; multi emissions control; chemical looping; and options for improving efficiency and reducing emissions.

  1. COAL LIQUEFACTION ALLOY TEST PROGRAM ANNUAL REPORT FY 1978

    E-Print Network [OSTI]

    Levy, A.

    2014-01-01

    lBl-8754 UC-90d · COAL LIQUEFACTION ALLOY TEST PROGRAMViscosity vs. Tempeature of Coal Slurries in Creosote OiLthe experiments are: Particles (coal. SiC, SiO )' Z liquid (

  2. CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS

    E-Print Network [OSTI]

    Tanner, K.I.

    2010-01-01

    I. Solvent Refined Coal II. Catalysts III. Purpose andSondreal, E.A. , "Viscosity of Coal Liquids - The Effect ofAnthraxylon - Kinetics of Coal Hydrogenation," Ind. and Eng.

  3. COMBUSTION OF COAL IN AN OPPOSED FLOW DIFFUSION BURNER

    E-Print Network [OSTI]

    Chin, W.K.

    2010-01-01

    November 1976. Wilson, P.J. and Wells, J.H. , Coal, Cokeand Coal Chemicals, 108, (1950). This report was done withliThe F1uidised Combustion of Coal," Sixteenth S m osium {

  4. MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION

    E-Print Network [OSTI]

    Joyce, Peter James

    2011-01-01

    labeled for hydrogen, coal, and liquid and gas phase water.is employed to deliver coal- derived liquids to the domesticMultiphase Flow of Gas-Liquid and Gas-Coal Slurry Mixtures

  5. CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS

    E-Print Network [OSTI]

    Tanner, K.I.

    2010-01-01

    E.A. , "Viscosity of Coal Liquids - The Effect of CharacterOF SOLVENT REFINED COAL TO LIQUID PRODUCTS Kylan I. Tanner*for Conversion of Coal to Liquid Fuels: Basic and Ex-

  6. ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS by Elliott Paul Barnhart.........................................................................................8 Coal and Metabolite Enrichment Studies ..................................................................................14 Ability of the Consortium to Produce Methane from Coal and Metabolites ................16

  7. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    SciTech Connect (OSTI)

    Bradley Adams; Andrew Fry; Constance Senior; Hong Shim; Huafeng Wang; Jost Wendt; Christopher Shaddix

    2009-06-30

    This report summarizes Year 1 results of a research program designed to use multi-scale experimental studies and fundamental theoretical models to characterize and predict the impacts of retrofit of existing coal-fired utility boilers for oxy-combustion. Through the course of Year 1 activities, great progress was made toward understanding the issues associated with oxy-combustion retrofit of coal-fired boilers. All four Year 1 milestones and objectives have been, or will be, completed on schedule and within budget. Progress in the four milestone areas may be summarized as follows: • University of Utah has performed size segregated ash composition measurements in the Oxy-Fuel Combustor (OFC). These experiments indicate that oxy-combustion retrofit may impact ash aerosol mineral matter composition. Both flame temperature and flue gas composition have been observed to influence the concentration of calcium, magnesium and iron in the fine particulate. This could in turn impact boiler fouling and slagging. • Sandia National Labs has shown that char oxidation rate is dependent on particle size (for sizes between 60 and 100 microns) by performing fundamental simulations of reacting char particles. These predictions will be verified by making time-resolved optical measurements of char particle temperature, velocity and size in bench-scale experiments before the end of Year 1. • REI and Siemens have completed the design of an oxy-research burner that will be mounted on University of Utah’s pilot-scale furnace, the L1500. This burner will accommodate a wide range of O2, FGR and mixing strategies under conditions relevant for utility boiler operation. Through CFD modeling of the different burner designs, it was determined that the key factor influencing flame stabilization location is particle heat-up rate. The new oxy-research burner and associated equipment is scheduled for delivery before the end of Year 1. • REI has completed a literature survey of slagging and fouling mechanisms in coal-fired power plants to understand key issues influencing these deposition regimes and infer their behavior under oxy-fired conditions. Based on the results of this survey, an algorithm for integrating slagging predictions into CFD models was outlined. This method accounts for ash formation, particle impaction and sticking, deposit growth and physical properties and impact of the deposit on system flow and heat transfer. A model for fouling in the back pass has also been identified which includes vaporization of sodium, deposition of sodium sulfate on fly ash particles and tube surfaces, and deposit growth rate on tubes. In Year 1, REI has also performed a review of the literature describing corrosion in order to understand the behavior of oxidation, sulfidation, chloridation, and carburization mechanisms in air-fired and oxy-combustion systems. REI and Vattenfall have met and exchanged information concerning oxy-coal combustion mechanisms for CFD simulations currently used by Vattenfall. In preparation for Year 2 of this program, two coals (North Antelope PRB, Western bituminous) have been ordered, pulverized and delivered to the University of Utah and Sandia National Labs. Materials for the corrosion experiments have been identified, suppliers located, and a schedule for equipment fabrication and shakedown has been established. Finally, a flue gas recycle system has been designed and is being constructed for the OFC.

  8. Reducing the moisture content of clean coals

    SciTech Connect (OSTI)

    Kehoe, D. )

    1992-12-01

    Coal moisture content can profoundly effect the cost of burning coal in utility boilers. Because of the large effect of coal moisture, the Empire State Electric Energy Research Corporation (ESEERCO) contracted with the Electric Power Research Institute to investigate advanced coal dewatering methods at its Coal Quality Development Center. This report contains the test result on the high-G solid-bowl centrifuge, the second of four devices to be tested. The high-G solid-bowl centrifuge removes water for coal by spinning the coal/water mixture rapidly in a rotating bowl. This causes the coal to cling to the sides of the bowl where it can be removed, leaving the water behind. Testing was performed at the CQDC to evaluate the effect of four operating variables (G-ratio, feed solids concentration, dry solids feed rate, and differential RPM) on the performance of the high-G solid-bowl centrifuge. Two centrifuges of different bowl diameter were tested to establish the effect of scale-up of centrifuge performance. Testing of the two centrifuges occurred from 1985 through 1987. CQDC engineers performed 32 tests on the smaller of the two centrifuges, and 47 tests on the larger. Equations that predict the performance of the two centrifuges for solids recovery, moisture content of the produced coal, and motor torque were obtained. The equations predict the observed data well. Traditional techniques of establishing the performance of centrifuge of different scale did not work well with the two centrifuges, probably because of the large range of G-ratios used in the testing. Cost of operating a commercial size bank of centrifuges is approximately $1.72 per ton of clean coal. This compares well with thermal drying, which costs $1.82 per ton of clean coal.

  9. Quarterly coal report, January--March 1993

    SciTech Connect (OSTI)

    Not Available

    1993-08-20

    The United States produced 242 million short tons of coal in the first quarter of 1993, a decrease of 6 percent (14 million short tons) from the amount produced during the first quarter of 1992. The decrease was due to a decline in production east of the Mississippi River. All major coal-producing States in this region had lower coal production levels led by West Virginia, which produced 5 million short tons less coal. The principal reasons for the overall drop in coal output compared to a year earlier were: A decrease in demand for US coal in foreign markets; a slower rate of producer/distributor stock build-up; and a drawn-down of electric utility coal stocks. Distribution of US coal in the first quarter of 1993 was 10 million short tons lower than in the first quarter of 1992, with 5 million short tons less distributed to both electric utilities and overseas markets. The average price of coal delivered to electric utilities during the first quarter of 1993 was $28.65 per short ton, the lowest value since the first quarter of 1980. Coal consumption in the first quarter of 1993 was 230 million short tons, 4 percent higher than in the first quarter of 1992, due primarily to a 5-percent increase in consumption at electric utility plants. Total consumer stocks, at 153 million short tons, and electric utility stocks, at 144 million short tons, were at their lowest quarterly level since the end of 1989. US. coal exports totaled 19 million short tons, 6 million short tons less than in the first quarter of 1992, and the lowest quarterly level since 1988. The decline was primarily due to a 1-million-short-ton drop in exports to each of the following destinations: Italy, France, Belgium and Luxembourg, and Canada.

  10. Coal properties and system operating parameters for underground coal gasification

    SciTech Connect (OSTI)

    Yang, L. [China University of Mining & Technology, Xuzhou (China)

    2008-07-01

    Through the model experiment for underground coal gasification, the influence of the properties for gasification agent and gasification methods on underground coal gasifier performance were studied. The results showed that pulsating gasification, to some extent, could improve gas quality, whereas steam gasification led to the production of high heating value gas. Oxygen-enriched air and backflow gasification failed to improve the quality of the outlet gas remarkably, but they could heighten the temperature of the gasifier quickly. According to the experiment data, the longitudinal average gasification rate along the direction of the channel in the gasifying seams was 1.212 m/d, with transverse average gasification rate 0.069 m/d. Experiment indicated that, for the oxygen-enriched steam gasification, when the steam/oxygen ratio was 2:1, gas compositions remained stable, with H{sub 2} + CO content virtually standing between 60% and 70% and O{sub 2} content below 0.5%. The general regularities of the development of the temperature field within the underground gasifier and the reasons for the changes of gas quality were also analyzed. The 'autopneumatolysis' and methanization reaction existing in the underground gasification process were first proposed.

  11. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-01-26

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  12. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1988-01-01

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover.

  13. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-11-08

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  14. The Coal Transportation Rate Database

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan3 November18.5 385.5Dry Production (Million CubicThe Coal

  15. U.S. Coal Reserves

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1Marcellus RegionProduct:Coal

  16. Weekly Coal Production Estimation Methodology

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers inYear JanSalesa.E.DRAFT0, 19977,

  17. DOE - Office of Legacy Management -- Hoe Creek Underground Coal...

    Office of Legacy Management (LM)

    Hoe Creek Underground Coal Gasification Site - 045 FUSRAP Considered Sites Site: Hoe Creek Underground Coal Gasification Site (045) Designated Name: Alternate Name: Location:...

  18. Long Term Environment and Economic Impacts of Coal Liquefaction...

    Office of Scientific and Technical Information (OSTI)

    Long Term Environment and Economic Impacts of Coal Liquefaction in China Fletcher, Jerald 01 COAL, LIGNITE, AND PEAT The project currently is composed of six specific tasks - three...

  19. "Table 2. Real Average Annual Coal Transportation Costs, By Primary...

    U.S. Energy Information Administration (EIA) Indexed Site

    Real Average Annual Coal Transportation Costs, By Primary Transport Mode and Supply Region" "(2013 dollars per ton)" "Coal Supply Region",2008,2009,2010,2011,2012,2013 "Railroad"...

  20. Table 1. Real Average Transportation and Delivered Costs of Coal...

    U.S. Energy Information Administration (EIA) Indexed Site

    Real Average Transportation and Delivered Costs of Coal, By Year and Primary Transport Mode" "Year","Average Transportation Cost of Coal (Dollars per Ton)","Average Delivered Cost...