National Library of Energy BETA

Sample records for bitu subbitu lignite

  1. LIGNITE FUEL ENHANCEMENT

    SciTech Connect (OSTI)

    Charles Bullinger

    2005-06-07

    This 3rd quarterly Technical Progress Report for the Lignite Fuel Enhancement Project summarizes activities from January 1st through March 31st of 2005. It also summarizes the subsequent purchasing activity and final dryer/process design.

  2. Lignite Fuel Enhancement

    SciTech Connect (OSTI)

    Charles Bullinger; Nenad Sarunac

    2010-03-31

    Pulverized coal power plants which fire lignites and other low-rank high-moisture coals generally operate with reduced efficiencies and increased stack emissions due to the impacts of high fuel moisture on stack heat loss and pulverizer and fan power. A process that uses plant waste heat sources to evaporate a portion of the fuel moisture from the lignite feedstock in a moving bed fluidized bed dryer (FBD) was developed in the U.S. by a team led by Great River Energy (GRE). The demonstration was conducted with Department of Energy (DOE) funding under DOE Award Number DE-FC26-04NT41763. The objectives of GRE's Lignite Fuel Enhancement project were to demonstrate reduction in lignite moisture content by using heat rejected from the power plant, apply technology at full scale at Coal Creek Station (CCS), and commercialize it. The Coal Creek Project has involved several stages, beginning with lignite drying tests in a laboratory-scale FBD at the Energy Research Center (ERC) and development of theoretical models for predicting dryer performance. Using results from these early stage research efforts, GRE built a 2 ton/hour pilot-scale dryer, and a 75 ton/hour prototype drying system at Coal Creek Station. Operated over a range of drying conditions, the results from the pilot-scale and prototype-scale dryers confirmed the performance of the basic dryer design concept and provided the knowledge base needed to scale the process up to commercial size. Phase 2 of the GRE's Lignite Fuel Enhancement project included design, construction and integration of a full-scale commercial coal drying system (four FBDs per unit) with Coal Creek Units 1 and 2 heat sources and coal handling system. Two series of controlled tests were conducted at Coal Creek Unit 1 with wet and dried lignite to determine effect of dried lignite on unit performance and emissions. Wet lignite was fired during the first, wet baseline, test series conducted in September 2009. The second test series was performed in March/April 2010 after commercial coal drying system was commissioned. Preliminary tests with dried coal were performed in March/April 2010. During the test Unit 2 was in outage and, therefore, test unit (Unit 1) was carrying entire station load and, also, supplying all auxiliary steam extractions. This resulted in higher station service, lower gross power output, and higher turbine cycle heat rate. Although, some of these effects could be corrected out, this would introduce uncertainty in calculated unit performance and effect of dried lignite on unit performance. Baseline tests with dried coal are planned for second half of 2010 when both units at Coal Creek will be in service to establish baseline performance with dried coal and determine effect of coal drying on unit performance. Application of GRE's coal drying technology will significantly enhance the value of lignite as a fuel in electrical power generation power plants. Although existing lignite power plants are designed to burn wet lignite, the reduction in moisture content will increase efficiency, reduce pollution and CO{sub 2} emissions, and improve plant economics. Furthermore, the efficiency of ultra supercritical units burning high-moisture coals will be improved significantly by using dried coal as a fuel. To date, Great River Energy has had 63 confidentiality agreements signed by vendors and suppliers of equipment and 15 utilities. GRE has had agreements signed from companies in Canada, Australia, China, India, Indonesia, and Europe.

  3. Lignite Fuel Enhancement

    SciTech Connect (OSTI)

    Charles Bullinger

    2007-03-31

    This 11th quarterly Technical Progress Report for the Lignite Fuel Enhancement Project summarizes activities from January 1st through March 31st of 2007. It summarizes the completion of the Prototype testing activity and initial full-scale dryer design, Budget Period 2 activity during that time period. The Design Team completed process design and layouts of air, water, and coal systems. Heyl-Patterson completed dryer drawings and has sent RFPs to several fabricators for build and assembly. Several meetings were held with Barr engineers to finalize arrangement of the drying, air jig, and coal handling systems. Honeywell held meetings do discuss the control system logic and hardware location. By the end of March we had processed nearly 300,000 tons of lignite through the dryer. Outage preparation maintenance activities on a coal transfer hopper restricted operation of the dryer in February and March. The Outage began March 17th. We will not dry coal again until early May when the Outage on Unit No.2 completes. The Budget Period 1 (Phase 1) final report was submitted this quarter. Comments were received from NETL and are being reviewed. The Phase 2 Project Management Plan was submitted to NETL in January 2007. This deliverable also included the Financing Plan. An application for R&D 100 award was submitted in February. The project received an award from the Minnesota Professional Engineering Society's Seven Wonders of Engineering Award and Minnesota ACEC Grand Award in January. To further summarize, the focus this quarter has been on finalizing commercial design and the layout of four dryers behind each Unit. The modification to the coal handling facilities at Coal Creek and incorporation of air jigs to further beneficiate the segregated material the dryers will reject 20 to 30 % of the mercury and sulfur is segregated however this modification will recover the carbon in that stream.

  4. ACTIVATED CARBON FROM LIGNITE FOR WATER TREATMENT (Technical...

    Office of Scientific and Technical Information (OSTI)

    ACTIVATED CARBON FROM LIGNITE FOR WATER TREATMENT Citation Details In-Document Search Title: ACTIVATED CARBON FROM LIGNITE FOR WATER TREATMENT You are accessing a document from...

  5. Lignite pellets and methods of agglomerating or pelletizing

    DOE Patents [OSTI]

    Baker, Albert F. (Pittsburgh, PA); Blaustein, Eric W. (Pittsburgh, PA); Deurbrouck, Albert W. (Pittsburgh, PA); Garvin, John P. (Pittsburgh, PA); McKeever, Robert E. (Pittsburgh, PA)

    1981-01-01

    The specification discloses lignite pellets which are relatively hard, dust resistant, of generally uniform size and free from spontaneous ignition and general degradation. Also disclosed are methods for making such pellets which involve crushing as mined lignite, mixing said lignite with a binder such as asphalt, forming the lignite binder mixture into pellets, and drying the pellets.

  6. COFIRING BIOMASS WITH LIGNITE COAL

    SciTech Connect (OSTI)

    Darren D. Schmidt

    2002-01-01

    The University of North Dakota Energy & Environmental Research Center, in support of the U.S. Department of Energy's (DOE) biomass cofiring program, completed a Phase 1 feasibility study investigating aspects of cofiring lignite coal with biomass relative to utility-scale systems, specifically focusing on a small stoker system located at the North Dakota State Penitentiary (NDSP) in Bismarck, North Dakota. A complete biomass resource assessment was completed, the stoker was redesigned to accept biomass, fuel characterization and fireside modeling tests were performed, and an engineering economic analysis was completed. In general, municipal wood residue was found to be the most viable fuel choice, and the modeling showed that fireside problems would be minimal. Experimental ash deposits from firing 50% biomass were found to be weaker and more friable compared to baseline lignite coal. Experimental sulfur and NO{sub x} emissions were reduced by up to 46%. The direct costs savings to NDSP, from cogeneration and fuel saving, results in a 15- to 20-year payback on a $1,680,000 investment, while the total benefits to the greater community would include reduced landfill burden, alleviation of fees for disposal by local businesses, and additional jobs created both for the stoker system as well as from the savings spread throughout the community.

  7. Bioprocessing of lignite coals using reductive microorganisms

    SciTech Connect (OSTI)

    Crawford, D.L.

    1992-03-29

    In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

  8. ENERGY PLANNING, POLICY AND ECONOMY; 02 PETROLEUM; 01 COAL, LIGNITE...

    Office of Scientific and Technical Information (OSTI)

    Philippines: Asia Pacific energy series: Country report Hoffman, S. 29 ENERGY PLANNING, POLICY AND ECONOMY; 02 PETROLEUM; 01 COAL, LIGNITE, AND PEAT; PHILIPPINES; ECONOMIC...

  9. POWDERED ACTIVATED CARBON FROM NORTH DAKOTA LIGNITE: AN OPTION...

    Office of Scientific and Technical Information (OSTI)

    CARBON FROM NORTH DAKOTA LIGNITE: AN OPTION FOR DISINFECTION BY-PRODUCT CONTROL IN WATER TREATMENT PLANTS Citation Details In-Document Search Title: POWDERED ACTIVATED...

  10. A study of pyrolysis of Texas lignites 

    E-Print Network [OSTI]

    Clark, Robert A

    1979-01-01

    . Typical experiments per- formed by Coates, et al. involve the heating of powdered coal to 2500 degrees Fahrenheit within . 3 seconds. The resulting char is then quenched with a spray of water. This process simulates an above ground gasifier... France, Great Britain, and Italy have tested projects for underaround gasification of both coal and lignite. However, their experiments were 2 not very successful. The U. S. Bureau of Mines conducted a field test at Gorgas, Alabama, in the 1950's...

  11. Survey of synfuel technology for lignite

    SciTech Connect (OSTI)

    Sondreal, E.A.

    1982-01-01

    The most important market for lignite will continue to be the electric utility industry, where it is used to fuel large pc-fired boilers serving major regional power grids. However, the growth of this market and thechnology is being challenged by new and more stringent environmental control requirements, including the international concern over acid rain. Environmental and economic issues could either encourage or limit the development of a synfuels market for lignite depending on the cost effectiveness of the technological solutions that are developed. Clearly the United States needs to develop its coal resources to reduce dependence on imported oil. However, demand for coal derived substitute petroleum will be constrained by cost for the forseeable future. Government policy initiatives and new technology will be the keys to removing these constraints in the decades ahead. A crossover point with respect to petroleum and natural gas will be reached at some point in the future, which will allow synthetic fuels to penetrate the markets now served by oil and gas. Those of us who are today concerned with the development of lignite resources can look forward to participating in the major synfuels market that will emerge when those economic conditions are realized.

  12. Microbial activities in forest soils exposed to chronic depositions from a lignite power plant

    E-Print Network [OSTI]

    Klose, Susanne; Wernecke, K D; Makeschin, F

    2004-01-01

    around a coal-burning power plant: a case study in the Czechdepositions from a lignite power plant Susanne Klose 1* ,DEPOSITIONS FROM A LIGNITE POWER PLANT Susanne Klose 1* ,

  13. The washability of lignites for clay removal

    SciTech Connect (OSTI)

    Oteyaka, B.; Yamik, A.; Ucar, A.; Sahbaz, O.; Demir, U. [Dumlupinar University, Kutahya (Turkey). Dept. of Mining Engineering

    2008-07-01

    In the washability research of the Seyitomer Lignites (Kutahya-Turkey), with lower calorific value (1,863 kcal/kg) and high ash content (51.91%), by heavy medium separation, it was found out that middling clay in the coal had an effect to change the medium density. To prevent this problem, a trommel sieve with 18 and 5 mm aperture diameter was designed, and the clay in the coal was tried to be removed using it before the coal was released to heavy medium. Following that, the obtained coal in -100 + 18 mm and -18 + 5 mm fractions was subjected to sink and float test having 1.4 gcm{sup -3} and 1.7 gcm{sup -3} medium densities (-5 mm fraction will be evaluated in a separate work). Depending on the raw coal, with the floating of -100 + 18 mm and -18 + 5 mm size fraction in 1.4 gcm{sup -3} medium density, clean coal with 60.10% combustible matter recovery, 19.12% ash, and 3,150 kcal/kg was obtained. Also floating of the samples sinking in 1.4 gcm{sup -3} in the medium density (1.7 gcm{sup -3}), middling with 18.70% combustible matter recovery, 41.93% ash, 2,150 kcal/kg, and tailing having 78.31% ash were obtained.

  14. Naturally occurring radioactive materials (NORMs) generated from lignite-fired power plants in Kosovo

    E-Print Network [OSTI]

    Roma "La Sapienza", Università di

    Available online 16 September 2014 Keywords: Lignite Coal fired power plant Fly ash Bottom ash Naturally depends primarily on lignite-fired power plants. During coal com- bustion, huge amounts of fly ash exposure of workers and the local population. Lignite samples and NORMs of fly ash and bottom ash generated

  15. Hydroliquefaction of Big Brown lignite in supercritical fluids 

    E-Print Network [OSTI]

    Chen, Hui

    1996-01-01

    Big Brown lignite was liquefied in a fixed bed tube reactor. Three solvents were used in the liquefaction studies, toluene, cyclohexane and methanol. Two co-solvents, tetralin and water were used with toluene. The effects of the solvents and co...

  16. Development of a thermobalance and analysis of lignites by thermogravimetric and statistical methods 

    E-Print Network [OSTI]

    Ferguson, James Allen

    1984-01-01

    LIST OF TABLES LIST OF FIGURES INTRODUCTION V11 V1 1 1 THERMAL ANALYSIS COAL EXPERIMENTAL METHODS 12 20 CALCULATING THE CALORIFIC VALUE OF LIGNITES FROM PROXIMATE ANALYSIS DATA GAUSS REDUCTION ILLUSTRATION CONSTRUCTION OF THE THERMOBALANCE... diagram illustrating procedure for determining the proximate analyses of coal or lignite by thermogravimetry 20 EXPERIMENTAL METHODS CALCULATING THE CALORIFIC VALUE OF LIGNITES FROM PROXIMATE ANALISIS DATA One of the most important properties of a...

  17. Impacts of stripmining lignite on net returns for agricultural enterprises in East Texas 

    E-Print Network [OSTI]

    Morris, Christina

    1984-01-01

    mining. Eighty to 95 percent of the lignite is recovezed. Mining is currently only done to depths of 120 feet; greater than 150 feet is not yet economically feasible (Kaiser et al. 1980). During mining, draglines remove the earth above the lignite... (multiseam) to be mined. The same equipment, draglines and/or scrapers are used to replace and contour the overburden after the lignite is removed. Once the overburden is replaced and contoured the land is revegetated using bermudagrass in warm weather...

  18. Gidaspow, D.; Bezburuah, R.; Ding, J. 01 COAL, LIGNITE, AND PEAT...

    Office of Scientific and Technical Information (OSTI)

    fluidized beds: Kinetic theory approach Gidaspow, D.; Bezburuah, R.; Ding, J. 01 COAL, LIGNITE, AND PEAT; 42 ENGINEERING; 99 GENERAL AND MISCELLANEOUSMATHEMATICS,...

  19. JV Task 98 - Controlling Mercury Emissions for Utilities Firing Lignites from North America

    SciTech Connect (OSTI)

    Steven Benson

    2007-06-15

    This project compiled and summarized the findings and conclusions of research, development, and demonstration projects on controlling mercury from lignite coals. A significant amount of work has been conducted since 1994 on mercury in lignite, mercury measurement in flue gases, sorbent, sorbent enhancement additives, oxidation agent development, and full-scale demonstration of mercury control technologies. This report is focused on providing the lignite industry with an understanding of mercury issues associated with the combustion of lignite, as well as providing vital information on the methods to control mercury emissions in coal-fired power plants.

  20. Potential Impact of the Development of Lignite Reserves on Water Resources of East Texas 

    E-Print Network [OSTI]

    James, W. P.; Slowey, J. F.; Garret, R. L.; Ortiz, C.; Bright, J.; King, T.

    1976-01-01

    ,OOO-megawatt plant requires approximately six million tons of lignite per year. When the lignite is fired at the plant some trace metals are concentrated in the fly ash (arsenic, iron, manganese and lead), while others are discharged from the stack primarily as a...

  1. JV Task 90 - Activated Carbon Production from North Dakota Lignite

    SciTech Connect (OSTI)

    Steven Benson; Charlene Crocker; Rokan Zaman; Mark Musich; Edwin Olson

    2008-03-31

    The Energy & Environmental Research Center (EERC) has pursued a research program for producing activated carbon from North Dakota lignite that can be competitive with commercial-grade activated carbon. As part of this effort, small-scale production of activated carbon was produced from Fort Union lignite. A conceptual design of a commercial activated carbon production plant was drawn, and a market assessment was performed to determine likely revenue streams for the produced carbon. Activated carbon was produced from lignite coal in both laboratory-scale fixed-bed reactors and in a small pilot-scale rotary kiln. The EERC was successfully able to upgrade the laboratory-scale activated carbon production system to a pilot-scale rotary kiln system. The activated carbon produced from North Dakota lignite was superior to commercial grade DARCO{reg_sign} FGD and Rheinbraun's HOK activated coke product with respect to iodine number. The iodine number of North Dakota lignite-derived activated carbon was between 600 and 800 mg I{sub 2}/g, whereas the iodine number of DARCO FGD was between 500 and 600 mg I{sub 2}/g, and the iodine number of Rheinbraun's HOK activated coke product was around 275 mg I{sub 2}/g. The EERC performed both bench-scale and pilot-scale mercury capture tests using the activated carbon made under various optimization process conditions. For comparison, the mercury capture capability of commercial DARCO FGD was also tested. The lab-scale apparatus is a thin fixed-bed mercury-screening system, which has been used by the EERC for many mercury capture screen tests. The pilot-scale systems included two combustion units, both equipped with an electrostatic precipitator (ESP). Activated carbons were also tested in a slipstream baghouse at a Texas power plant. The results indicated that the activated carbon produced from North Dakota lignite coal is capable of removing mercury from flue gas. The tests showed that activated carbon with the greatest iodine number was superior to commercial DARCO FGD for mercury capture. The results of the activated carbon market assessment indicate an existing market for water treatment and an emerging application for mercury control. That market will involve both existing and new coal-fired plants. It is expected that 20% of the existing coal-fired plants will implement activated carbon injection by 2015, representing about 200,000 tons of annual demand. The potential annual demand by new plants is even greater. In the mercury control market, two characteristics are going to dominate the customer's buying habit-performance and price. As continued demonstration testing of activated carbon injection at the various coal-fired power plants progresses, the importance of fuel type and plant configuration on the type of activated carbon best suited is being identified.

  2. A study of uranium in South Texas lignite 

    E-Print Network [OSTI]

    Ilger, Wayne Arthur

    1983-01-01

    , the humic acid was 1solated from uran1ferous Conquista lign1te us1ng Kerndorf's (p. g ) previously mentioned separation procedure. Forty-five percent of the uranium from the or1g1nal lign1te st111 remained in the three times precipitated humic acid, when...A STUDY OF URANIUM IN SOUTH TEXAS LIGNITE A Thesis by WAYNE ARTHUR ILGER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1983 Major Subject...

  3. Correlation of stratigraphy with revegetation conditions at the Gibbons Creek Lignite Mine, Grimes County, Texas 

    E-Print Network [OSTI]

    Parisot, Laurence D.

    1991-01-01

    (after Ott, 1988). . 2 Table for determining the tail area (after Ott, 1988). . . . 59 60 LIST OF FIGURES Figure Page 1 Lignite resources in Texas 2 Use of dragline for surface-mining at the Gibbons Creek Mine, Texas. . 3 3 Method of surface... of the lignite in a trench involves the removal of the overburden with the use of a dragline (Figure 2). When the lignite has been extracted from the cut, the trench is backfilled with the overburden of the adjacent trench. This new overburden forms the spoil...

  4. Engineering geologic analysis of reclaimed spoil at a southeast Texas Gulf Coast surface lignite mine 

    E-Print Network [OSTI]

    Armstrong, Scott Charles

    1987-01-01

    to be extremely heterogeneous. The spoil is composed of sand- to boulder-sxzed fragments of the pre-mtne overburden oriented randomly )n a clay/silt matrtx. The spoil material was found to segregate upon dragline dumping. The coarser clastic material was found... mining technique used in Texas lignite mines. At the Gibbons Creek Lignite Nine overburden is removed by dragline and cast in conical piles to form rows of spoil ridges in the mined-out portion of the preceding mine cut. The lignite is then removed...

  5. Bioprocessing of lignite coals using reductive microorganisms. Final technical report, September 30, 1988--March 29, 1992

    SciTech Connect (OSTI)

    Crawford, D.L.

    1992-03-29

    In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

  6. Production of Medium BTU Gas by In Situ Gasification of Texas Lignite 

    E-Print Network [OSTI]

    Edgar, T. F.

    1979-01-01

    ~vity planned for the mining of lignite by 1985, at which time Texas is projected to becom~ the seventh largest coal mining state. However, the deep basin lignite cannot be economically recovered by strip or shaft mining. For this lignite there is great...-770652, 1977. 11. Gregg, D. W., and T. F. Edgar, "Underground Coal Gasification," AIChE J., ~, 753 (1978) ? 12. Gregg, D. W., R. W. Hill, and D. U. Olness, "An Overview of the Soviet Effort in Underground Coal Gasification," Lawrence Livermore...

  7. DOE-Sponsored Field Test Finds Potential for Permanent Storage of CO2 in Lignite Seams

    Broader source: Energy.gov [DOE]

    A field test sponsored by the U.S. Department of Energy has demonstrated that opportunities to permanently store carbon in unmineable seams of lignite may be more widespread than previously documented.

  8. Evaluation of the Impact of Texas Lignite Development on Texas Water Resources 

    E-Print Network [OSTI]

    Mathewson, C. C.; Cason, C. L.

    1980-01-01

    Fuel shortages and resultant rising fuel costs as well as federal policies prompting energy independence have served to encourage power companies to exploit available lignite deposits of the western states as a viable fuel source. Large reserves...

  9. Water table recovery in a reclaimed surface lignite mine, Grimes County, Texas 

    E-Print Network [OSTI]

    Peace, Kelley H.

    1995-01-01

    Water table recovery in four reclaimed mine blocks containing replaced overburden has been monitored at Gibbons Creek Lignite Mine in Grimes County, Texas since 1986. Recovery analysis was conducted based on data recorded at 27 wells installed...

  10. Engineering geologic feasibility of lignite mining in alluvial valleys by hydraulic dredging methods 

    E-Print Network [OSTI]

    Cason, Cynthia Lynn

    1982-01-01

    Stability . Sediment Volume Changes Conventional Lignite Mining Technology Dragline Bucket wheel Excavator . ALLUVIAL VALLEY SEDIMENTS Environment of Deposition Engineering Geology of Alluvial Valley Sediments Disadvantages of Applying Conventional... on samples with varying percentages of sand 54 33 Ultimate percent swell v. highwall height for varying percentages of sand in the overburden spoil . . . . . . . 55 34 Area lignite surface mining with a walking dragline and truck/shovel operations...

  11. The effect of sewage sludge on the physical properties of lignite overburden 

    E-Print Network [OSTI]

    Cocke, Catherine Lynn

    1985-01-01

    THE EFFECT OF SEWAGE SLUDGE ON THE PHYSICAL PROPERTIES OF LIGNITE OVERBURDEN A Thesis by CATHERINE LYNN COCKE Submitted to the Graduate College of Texas A&M University in Partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1985 Major Subject: Soil Science THE EFFECT OF SEWAGE SLUDGE ON THE PHYSICAL PROPERTIES OF LIGNITE OVERBURDEN A Thesis by CATHERINE LYNN COCK E Appr as o style and content by: . W. Brown (Chairman of Committee) . Hons (Member...

  12. JV Task - 129 Advanced Conversion Test - Bulgarian Lignite

    SciTech Connect (OSTI)

    Michael Swanson; Everett Sondreal; Daniel Laudal; Douglas Hajicek; Ann Henderson; Brandon Pavlish

    2009-03-27

    The objectives of this Energy & Environmental Research Center (EERC) project were to evaluate Bulgarian lignite performance under both fluid-bed combustion and gasification conditions and provide a recommendation as to which technology would be the most technically feasible for the particular feedstock and also identify any potential operating issues (such as bed agglomeration, etc.) that may limit the applicability of a potential coal conversion technology. Gasification tests were run at the EERC in the 100-400-kg/hr transport reactor development unit (TRDU) on a 50-tonne sample of lignite supplied by the Bulgarian Lignite Power Project. The quality of the test sample was inferior to any coal previously tested in this unit, containing 50% ash at 26.7% moisture and having a higher heating value of 5043 kJ/kg after partial drying in preparation for testing. The tentative conclusion reached on the basis of tests in the TRDU is that oxygen-blown gasification of this high-ash Bulgarian lignite sample using the Kellogg, Brown, and Root (KBR) transport gasifier technology would not provide a syngas suitable for directly firing a gas turbine. After correcting for test conditions specific to the pilot-scale TRDU, including an unavoidably high heat loss and nitrogen dilution by transport air, the best-case heating value for oxygen-blown operation was estimated to be 3316 kJ/m{sup 3} for a commercial KRB transport gasifier. This heating value is about 80% of the minimum required for firing a gas turbine. Removing 50% of the carbon dioxide from the syngas would increase the heating value to 4583 kJ/m{sup 3}, i.e., to about 110% of the minimum requirement, and 95% removal would provide a heating value of 7080 kJ/m{sup 3}. Supplemental firing of natural gas would also allow the integrated gasification combined cycle (IGCC) technology to be utilized without having to remove CO{sub 2}. If removal of all nitrogen from the input gas streams such as the coal transport air were achieved, a heating value very close to that needed to fire a gas turbine would be achieved; however, some operational issues associated with utilizing recycled syngas or carbon dioxide as the transport gas would also have to be resolved. Use of a coal with a quality similar to the core samples provided earlier in the test program would also improve the gasifier performance. Low cold-gas efficiencies on the order of 20% calculated for oxygen-blown tests resulted in part from specific difficulties experienced in trying to operate the pilot-scale TRDU on this very high-ash lignite. These low levels of efficiency are not believed to be representative of what could be achieved in a commercial KRB transport gasifier. Combustion tests were also performed in the EERC's circulating fluidized-bed combustor (CFBC) to evaluate this alternative technology for use of this fuel. It was demonstrated that this fuel does have sufficient heating value to sustain combustion, even without coal drying; however, it will be challenging to economically extract sufficient energy for the generation of steam for electrical generation. The boiler efficiency for the dried coal was 73.5% at 85% sulfur capture (21.4% moisture) compared to 55.3% at 85% sulfur capture (40% moisture). Improved boiler efficiencies for this coal will be possible operating a system more specifically designed to maximize heat extraction from the ash streams for this high-ash fuel. Drying of the coal to approximately 25% moisture probably would be recommended for either power system. Fuel moisture also has a large impact on fuel feedability. Pressurized gasifiers generally like drier fuels than systems operating at ambient pressures. The commercially recommended feedstock moisture for a pressurized transport reactor gasifier is 25% moisture. Maximum moisture content for a CFB system could be approximately 40% moisture as has been demonstrated on the Alstom CFB operating on Mississippi lignite. A preliminary economic evaluation for CO{sub 2} was performed on the alternatives of (1) precombustion separation of CO{sub 2} in

  13. Desulfurization of organic sulfur from lignite by an electron transfer process

    SciTech Connect (OSTI)

    Demirbas, A. [Selcuk University, Konya (Turkey). Dept. for Chemical Engineering

    2006-10-15

    This study is an attempt to desulfurize organic sulfur from lignite samples with ferrocyanide ion as the electron transferring agent. Effect of temperature, particle size and concentration of ferrocyanide ion on desulfurization from the lignite samples has been investigated. The desulfurization process has been found to be continuous and gradually increases with increase of temperature from 298 to 368 K. The particle size has no significant impact on sulfur removal from the lignite samples. Particle size has no profound impact on the amount of sulfur removal. The desulfurization reaction has been found to be dependent on the concentration of potassium ferrocyanide. Gradual increase in the concentration of potassium ferrocyanide raised the magnitude of desulfurization, but at a higher concentration, the variation is not significant.

  14. Development and evaluation of two reactor designs for desulfurization of Texas lignites 

    E-Print Network [OSTI]

    Merritt, Stanley Duane

    1991-01-01

    and organic oxygen. Qn a mass basis, lignites contain very little sulfur; but since the NSPS are based on a pounds of SQx per million Btu measurement, one finds that lignites are dirtier than the high medium volatile bituminous, mvb, coals of the Midwest... if it were not for a moisture content of approximately 30%. All coals were stored under nitrogen to prevent weathering and loss of moisture from the coal. Coal samples were weighed into glass vials for transport to the reactor. A blank was also prepared...

  15. Lignite mine spoil characterization and approaches for its rehabilitation

    SciTech Connect (OSTI)

    Praveen-Kumar; Kumar, S.; Sharma, K.D.; Choudhary, A.; Gehlot, K. [Central Arid Zone Research Inst., Jodhpur (India)

    2005-01-15

    Open cast mining of lignite leaves behind stockpiles of excavated materials (dumps) and refilled mining pits (spoils). Physicochemical and biochemical properties of both kinds of sites were estimated to identify the reasons for their barrenness. Subsequently, surface modifications were attempted, first in a greenhouse and later infield to develop a suitable approach for their rehabilitation. Dumps had low pH (4.8) and high Na{sup +} (2.5 mg g{sup -1}), spoils high pH (8.7) and high Na{sup +} (1.59 mg g{sup -1} soil). Both sites had low available nitrogen and phosphorus and showed very low dehydrogenase and phosphatases activity but no nitrification. The extreme physicochemical conditions and inert nature of damps and spoils explained their barrenness. In the greenhouse experiment, 14 plant species sown in surface materials of dumps and spoils after spreading a 0.15 m thick layer of dune sand, germinated ({gt}85%), and their seedlings survived for two months. This technique was followed at a spoil site (modified spoil site). After three years of stabilization the modified spoil site had only one-fifth Na{sup +} of that in spoil surface in the beginning and also showed higher dehydrogenase and phosphatase activity and nitrification. Pearl millet and Cenchrus ciliaris grown in modified spoil produced 128 to 394 kg and 2.25 to 3.50 Mg dry matter ha{sup -1}. Addition of farmyard manure with N and P fertilizers increased pearl millet yields.

  16. Ground-water hydrogeology and geochemistry of a reclaimed lignite surface mine 

    E-Print Network [OSTI]

    Pollock, Clifford Ralph

    1982-01-01

    is removed by a walking dragline and cast in con- ical piles to form rows of spoil ridges in the mined-out portion of the preceding mine cut. The lignite is removed by smaller pieces of earth- moving equipment, such as crawler-mounted power shovels, front...

  17. Soil microbial biomass: an estimator of soil development in reclaimed lignite mine soil 

    E-Print Network [OSTI]

    Swanson, Eric Scott

    1996-01-01

    A two-year study was conducted at the Big Brown lignite mine in Fairfield, Texas, to determine the rate and extent of recovery of the soil microbial biomass (SMB) in mixed overburden. The relationships between SMB carbon (SMBC), basal respiration...

  18. Characteristics of chars produced from lignites by pyrolysis at 808C following

    E-Print Network [OSTI]

    Characteristics of chars produced from lignites by pyrolysis at 808°C following rapid heating heating up at 8 x 103'C/s. Following pyrolysis, the chars were rapidly cooled - at about 3 x 104"C/s. Weight losses were measured as a function of pyrolysis time. The following measure- ments were made

  19. Determination of performance characteristics of a one-cylinder diesel engine modified to burn low-Btu (lignite) gas 

    E-Print Network [OSTI]

    Blacksmith, James Richard

    1979-01-01

    -Btu (Lignite) Gas. (August 1979) James Richard Blacksmith, B. S. , Texas ASM University Chairman of Advisory Committee: Dr. Francis W. Holm An experimental investigation was conducted to deter- mine the dual-fuel performance characteristics of a one...- cylinder diesel engine modified to burn low-Btu gas, such as would be obtained from the underground gasification of lignite. Conventional diesel and dual-fuel engine performance tests were conducted with the engine coupled to a station- ary water...

  20. An investigation of changes in groundwater quality caused by in-situ gasification of East Texas lignite 

    E-Print Network [OSTI]

    Leach, Kimberly Sue

    1988-01-01

    AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Submitted to the Graduate College of Texas AGM University in Partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1988 Major Subject: Petroleum Engineering AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Approved as to style and content by...

  1. An engineering geologic impact analysis of hydraulic dredging for lignite in Texas alluvial valleys 

    E-Print Network [OSTI]

    Nolan, Erich Donald Luis

    1985-01-01

    percent, or 4. 7 billion tons of the state's lignite is present in alluvial valleys. Due to frequent surface-water flooding and shallow ground-water tables, mining in the floodplain environment by the dragline-shovel-haul truck method would... in an alluvial valley would pose a constant problem. In fact, present surface mining techniques utilizing the dragline-shovel- haul truck method could not. operate in the floodplain environment without large scale, expensive surface water and ground water...

  2. Potential for selenium migration at a lignite power plant solid waste disposal facility 

    E-Print Network [OSTI]

    Hall, Steven Douglas

    1986-01-01

    . All groundwater that recharges on the disposal site is slightly saline and flows east, probably discharging into the Gibbons Creek Reservoir. Selenium, arsenic, boron, iron, manganese, and sulfate in the lignite waste effluent exceed either EPA... ( 1975) drinking water standards or EPA (1973) recommended livestock water standards. Since the natural groundwater contains higher concentrations of selenium, iron, manganese, and sulfate than the waste effluent, only arsenic and boron should...

  3. Advanced power assessment for Czech lignite. Task 3.6, Volume 1

    SciTech Connect (OSTI)

    Sondreal, E.A.; Mann, M.D.; Weber, G.W.; Young, B.C.

    1995-12-01

    The US has invested heavily in research, development, and demonstration of efficient and environmentally acceptable technologies for the use of coal. The US has the opportunity to use its leadership position to market a range of advanced coal-based technologies internationally. For example, coal mining output in the Czech Republic has been decreasing. This decrease in demand can be attributed mainly to the changing structure of the Czech economy and to environmental constraints. The continued production of energy from indigenous brown coals is a major concern for the Czech Republic. The strong desire to continue to use this resource is a challenge. The Energy and Environmental Research Center undertook two major efforts recently. One effort involved an assessment of opportunities for commercialization of US coal technologies in the Czech Republic. This report is the result of that effort. The technology assessment focused on the utilization of Czech brown coals. These coals are high in ash and sulfur, and the information presented in this report focuses on the utilization of these brown coals in an economically and environmentally friendly manner. Sections 3--5 present options for utilizing the as-mined coal, while Sections 6 and 7 present options for upgrading and generating alternative uses for the lignite. Contents include Czech Republic national energy perspectives; powering; emissions control; advanced power generation systems; assessment of lignite-upgrading technologies; and alternative markets for lignite.

  4. Enhancing Carbon Reactivity in Mercury Control in Lignite-Fired Systems

    SciTech Connect (OSTI)

    Chad Wocken; Michael Holmes; John Pavlish; Jeffrey Thompson; Katie Brandt; Brandon Pavlish; Dennis Laudal; Kevin Galbreath; Michelle Olderbak

    2008-06-30

    This project was awarded through the U.S. Department of Energy (DOE) National Energy Technology Laboratory Program Solicitation DE-PS26-03NT41718-01. The Energy & Environmental Research Center (EERC) led a consortium-based effort to resolve mercury (Hg) control issues facing the lignite industry. The EERC team-the Electric Power Research Institute (EPRI); the URS Corporation; the Babcock & Wilcox Company; ADA-ES; Apogee; Basin Electric Power Cooperative; Otter Tail Power Company; Great River Energy; Texas Utilities; Montana-Dakota Utilities Co.; Minnkota Power Cooperative, Inc.; BNI Coal Ltd.; Dakota Westmoreland Corporation; the North American Coal Corporation; SaskPower; and the North Dakota Industrial Commission-demonstrated technologies that substantially enhanced the effectiveness of carbon sorbents to remove Hg from western fuel combustion gases and achieve a high level ({ge} 55% Hg removal) of cost-effective control. The results of this effort are applicable to virtually all utilities burning lignite and subbituminous coals in the United States and Canada. The enhancement processes were previously proven in pilot-scale and limited full-scale tests. Additional optimization testing continues on these enhancements. These four units included three lignite-fired units: Leland Olds Station Unit 1 (LOS1) and Stanton Station Unit 10 (SS10) near Stanton and Antelope Valley Station Unit 1 (AVS1) near Beulah and a subbituminous Powder River Basin (PRB)-fired unit: Stanton Station Unit 1 (SS1). This project was one of three conducted by the consortium under the DOE mercury program to systematically test Hg control technologies available for utilities burning lignite. The overall objective of the three projects was to field-test and verify options that may be applied cost-effectively by the lignite industry to reduce Hg emissions. The EERC, URS, and other team members tested sorbent injection technologies for plants equipped with electrostatic precipitators (ESPs) and spray dryer absorbers combined with fabric filters (SDAs-FFs). The work focused on technology commercialization by involving industry and emphasizing the communication of results to vendors and utilities throughout the project.

  5. Development and evaluation of a lignite-stillage carrier system for application and study of biological control agents 

    E-Print Network [OSTI]

    Jones, Richard Worth

    1983-01-01

    Approved as to style and content by: (Chairman of Committee) (Member) (Member) (Head of Department) December 1983 ABSTRACT Development and Evaluation of a Lignite-Sti liege Carrier System for Application and Study of Biological Agents. (December 1983.... The carrier system consisted of lignite granules amended with thin liquid sti llage. This carrier system supported fungal propagule production as high as 2. 0 x 10g propagules/g carrier. Thin liquid sti llage supported the production of 4. 0-4. 5 mg of g...

  6. A study of uranium distribution in an upper Jackson lignite-sandstone ore body, South Texas 

    E-Print Network [OSTI]

    Chatham, James Randall

    1979-01-01

    mentary uranium ore depos- its. Dickinson and Duval (1977) 11st these major ore controls as follows: I) a source rock; 2) a leaching mechanism; 3) a transporting medium; 4) a host rock; 5) a reductant; and 6) preservation of the deposit. A su1table...A STUDY OF URANIUM DISTRIBUTION IN AN UPPER JACKSON LIGNITE-SANDSTONE ORE BODY, SOUTH TEXAS A Thesis James Randall Chatham Subnitted to the Graduate College of Texas A8M University in Partial fulfillment of the requirement for the degree...

  7. Characterization of Texas lignite and numerical modeling of its in-situ gasification 

    E-Print Network [OSTI]

    Wang, Yih-Jy

    1983-01-01

    Modeling Site selection for in-situ gasification projects normally involves application of site screen1ng criteria. Some of these cr1teria were discussed by Russell et al. (1983). Numerical simulation may play an important role in s1te selection...CHARACTERIZATION OF TEXAS LIGNITE AND NUMERICAL MODELING OF ITS IN-SITU GASIFICATION A Thesis by YIH-JY WANG Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  8. JV Task 117 - Impact of Lignite Properties on Powerspan's NOx Oxidation System

    SciTech Connect (OSTI)

    Scott Tolbert; Steven Benson

    2008-02-29

    Powerspan's multipollutant control process called electrocatalytic oxidation (ECO) technology is designed to simultaneously remove SO{sub 2}, NO{sub x}, PM{sub 2.5}, acid gases (such as hydrogen fluoride [HF], hydrochloric acid [HCl], and sulfur trioxide [SO{sub 3}]), Hg, and other metals from the flue gas of coal-fired power plants. The core of this technology is a dielectric barrier discharge reactor composed of cylindrical quartz electrodes residing in metal tubes. Electrical discharge through the flue gas, passing between the electrode and the tube, produces reactive O and OH radicals. The O and OH radicals react with flue gas components to oxidize NO to NO{sub 2} and HNO{sub 3} and a small portion of the SO{sub 2} to SO{sub 3} and H{sub 2}SO{sub 4}. The oxidized compounds are subsequently removed in a downstream scrubber and wet electrostatic precipitator. A challenging characteristic of selected North Dakota lignites is their high sodium content. During high-sodium lignite combustion and gas cooling, the sodium vaporizes and condenses to produce sodium- and sulfur-rich aerosols. Based on past work, it was hypothesized that the sodium aerosols would deposit on and react with the silica electrodes and react with the silica electrodes, resulting in the formation of sodium silicate. The deposit and reacted surface layer would then electrically alter the electrode, thus impacting its dielectric properties and NO{sub x} conversion capability. The purpose of this project was to determine the impact of lignite-derived flue gas containing sodium aerosols on Powerspan's dielectric barrier discharge (DBD) reactor with specific focus on the interaction with the quartz electrodes. Partners in the project were Minnkota Power Cooperative; Basin Electric Power Cooperative; Montana Dakota Utilities Co.; Minnesota Power; the North Dakota Industrial Commission, the Lignite Energy Council, and the Lignite Research Council; the Energy & Environmental Research Center (EERC); and the U.S. Department of Energy. An electrocatalytic oxidation (ECO) reactor slipstream system was designed by Powerspan and the EERC. The slipstream system was installed by the EERC at Minnkota Power Cooperative's Milton R. Young Station Unit 1 downstream of the electrostatic precipitator where the flue gas temperature ranged from 300 to 350 F. The system was commissioned on July 3, 2007, operated for 107 days, and then winterized upon completion of the testing campaign. Operational performance of the system was monitored, and data were archived for postprocessing. A pair of electrodes were extracted and replaced on a biweekly basis. Each pair of electrodes was shipped to Powerspan to determine NO conversion efficiency in Powerspan's laboratory reactor. Tested electrodes were then shipped to the EERC for scanning electron microscopy (SEM) and x-ray microanalysis. Measurement of NO{sub x} conversion online in operating the slipstream system was not possible because the nitric and sulfuric acid production by the DBD reactor results in conditioning corrosion challenges in the sample extraction system and NO measurement technologies. The operational observations, performance results, and lab testing showed that the system was adversely affected by accumulation of the aerosol materials on the electrode. NO{sub x} conversion by ash-covered electrodes was significantly reduced; however, with electrodes that were rinsed with water, the NOx conversion efficiency recovered to nearly that of a new electrode. In addition, the visual appearance of the electrode after washing did not show evidence of a cloudy reacted surface but appeared similar to an unexposed electrode. Examination of the electrodes using SEM x-ray microanalysis showed significant elemental sodium, sulfur, calcium, potassium, and silica in the ash coating the electrodes. There was no evidence of the reaction of the sodium with the silica electrodes to produce sodium silicate layers. All SEM images showed a clearly marked boundary between the ash and the silica. Sodium and sulfur are the main culprits in the

  9. PILOT-AND FULL-SCALE DEMONSTRATION OF ADVANCED MERCURY CONTROL TECHNOLOGIES FOR LIGNITE-FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Steven A. Benson; Charlene R. Crocker; Kevin C. Galbreath; Jay R. Gunderson; Michael J. Holmes; Jason D. Laumb; Jill M. Mackenzie; Michelle R. Olderbak; John H. Pavlish; Li Yan; Ye Zhuang

    2005-02-01

    The overall objective of the project was to develop advanced innovative mercury control technologies to reduce mercury emissions by 50%-90% in flue gases typically found in North Dakota lignite-fired power plants at costs from one-half to three-quarters of current estimated costs. Power plants firing North Dakota lignite produce flue gases that contain >85% elemental mercury, which is difficult to collect. The specific objectives were focused on determining the feasibility of the following technologies: Hg oxidation for increased Hg capture in dry scrubbers, incorporation of additives and technologies that enhance Hg sorbent effectiveness in electrostatic precipitators (ESPs) and baghouses, the use of amended silicates in lignite-derived flue gases for Hg capture, and the use of Hg adsorbents within a baghouse. The approach to developing Hg control technologies for North Dakota lignites involved examining the feasibility of the following technologies: Hg capture upstream of an ESP using sorbent enhancement, Hg oxidation and control using dry scrubbers, enhanced oxidation at a full-scale power plant using tire-derived fuel and oxidizing catalysts, and testing of Hg control technologies in the Advanced Hybrid{trademark} filter.

  10. Advanced power assessment for Czech lignite task 3.6. Topical report

    SciTech Connect (OSTI)

    Sondreal, E.A.; Mann, M.D.; Weber, G.W.; Young, B.C.

    1995-12-01

    Major reforms in the Czech energy sector have been initiated to reverse 40 years of central planning, subsidized energy pricing, unchecked pollution from coal-fired plants, concerns over nuclear safety and fuel cycle management, and dependence on the former U.S.S.R. for oil, gas, and nuclear fuel processing. Prices for electricity, heat, and natural gas paid by industry are close to western levels, but subsidized prices for households are as much as 40% lower and below economic cost. State control of major energy enterprises is being reduced by moving toward government-regulated, investor-owned companies to raise needed capital, but with a strategic stake retained by the state. Foreign firms will participate in privatization, but they are not expected to acquire a controlling interest in Czech energy companies. Economic conditions in the Czech Republic are now improving after the disruptions caused by restructuring since 1989 and separation of the former Czech and Slovak Federal Republics in January 1993. The downturn in the economy after 1989 was concentrated in energy-intensive heavy industry, and recovery is paced by consumer trade, services, light industry and construction. Energy use in relation to gross domestic product (GDP) has declined, but it is still significantly higher than in OECD (Organization for Economic Cooperation and Development) countries. The GDP increased by 2% in 1994 after dropping 22% between 1989 and 1993. A positive balance of payments has been achieved, with foreign investment offsetting a small trade deficit. The government`s external debt is only 4% of GDP. This report studies the application of lignite resources within the newly formulated energy policies of the republic, in light of a move toward privatization and stronger air pollution regulations. Lignite has represented the major energy source for the country.

  11. Development and chemical quality of a ground-water system in cast overburden as the Gibbons Creek Lignite Mine 

    E-Print Network [OSTI]

    Borbely, Evelyn Susanna

    1988-01-01

    Hydrogeochemistry of Reclaimed Spoil RESEARCH METHODOLOGY Field Methods Monitoring Well Locations Drilling and Spoil Sampling Installation and Development of Monitoring Wells Ground-Water Sampling Hydraulic Conductivity Testing Page V1 1X X111 14 21 22... . . . . . . . . . . . . . . 4 Locations of research stations in reclaimed portions of the A and B surface mining pits Distribution of Texas near-surface lignite (Kaiser et al. , 1974) Fayette fluvial-delta system and dip profile, Jackson Group, central and East Texas...

  12. The effect of CO? on the flammability limits of low-BTU gas of the type obtained from Texas lignite 

    E-Print Network [OSTI]

    Gaines, William Russell

    1983-01-01

    Chairman of Advisory Committee: Dr. W. N. Heffington An experimental study was conducted to determine if relatively large amounts of CO in a low-BTU gas of the type 2 derived from underground gasification of Texas lignite would cause significant... time when I was in need. Finally, the Center for Energy and Mineral Resources and the Texas Engineering Experiment Station for support related to this research. TABLE OF CONTENTS PAGE ABSTRACT ACKNOWLEDGEMENTS LIST OF TABLES LIST OF FIGURES V1...

  13. Large-Scale Mercury Control Technology Testing for Lignite-Fired Utilities - Oxidation Systems for Wet FGD

    SciTech Connect (OSTI)

    Steven A. Benson; Michael J. Holmes; Donald P. McCollor; Jill M. Mackenzie; Charlene R. Crocker; Lingbu Kong; Kevin C. Galbreath

    2007-03-31

    Mercury (Hg) control technologies were evaluated at Minnkota Power Cooperative's Milton R. Young (MRY) Station Unit 2, a 450-MW lignite-fired cyclone unit near Center, North Dakota, and TXU Energy's Monticello Steam Electric Station (MoSES) Unit 3, a 793-MW lignite--Powder River Basin (PRB) subbituminous coal-fired unit near Mt. Pleasant, Texas. A cold-side electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber are used at MRY and MoSES for controlling particulate and sulfur dioxide (SO{sub 2}) emissions, respectively. Several approaches for significantly and cost-effectively oxidizing elemental mercury (Hg{sup 0}) in lignite combustion flue gases, followed by capture in an ESP and/or FGD scrubber were evaluated. The project team involved in performing the technical aspects of the project included Babcock & Wilcox, the Energy & Environmental Research Center (EERC), the Electric Power Research Institute, and URS Corporation. Calcium bromide (CaBr{sub 2}), calcium chloride (CaCl{sub 2}), magnesium chloride (MgCl{sub 2}), and a proprietary sorbent enhancement additive (SEA), hereafter referred to as SEA2, were added to the lignite feeds to enhance Hg capture in the ESP and/or wet FGD. In addition, powdered activated carbon (PAC) was injected upstream of the ESP at MRY Unit 2. The work involved establishing Hg concentrations and removal rates across existing ESP and FGD units, determining costs associated with a given Hg removal efficiency, quantifying the balance-of-plant impacts of the control technologies, and facilitating technology commercialization. The primary project goal was to achieve ESP-FGD Hg removal efficiencies of {ge}55% at MRY and MoSES for about a month.

  14. Mercury Control for Plants Firing Texas Lignite and Equipped with ESP-wet FGD

    SciTech Connect (OSTI)

    Katherine Dombrowski

    2009-12-31

    This report presents the results of a multi-year test program conducted as part of Cooperative Agreement DE-FC26-06NT42779, 'Mercury Control for Plants Firing Texas Lignite and Equipped with ESP-wet FGD.' The objective of this program was to determine the level of mercury removal achievable using sorbent injection for a plant firing Texas lignite fuel and equipped with an ESP and wet FGD. The project was primarily funded by the U.S. DOE National Energy Technology Laboratory. EPRI, NRG Texas, Luminant (formerly TXU), and AEP were project co-funders. URS Group was the prime contractor, and Apogee Scientific and ADA-ES were subcontractors. The host site for this program was NRG Texas Limestone Electric Generating Station (LMS) Units 1 and 2, located in Jewett, Texas. The plant fires a blend of Texas lignite and Powder River Basin (PRB) coal. Full-scale tests were conducted to evaluate the mercury removal performance of powdered sorbents injected into the flue gas upstream of the ESP (traditional configuration), upstream of the air preheater, and/or between electric fields within the ESP (Toxecon{trademark} II configuration). Phases I through III of the test program, conducted on Unit 1 in 2006-2007, consisted of three short-term parametric test phases followed by a 60-day continuous operation test. Selected mercury sorbents were injected to treat one quarter of the flue gas (e.g., approximately 225 MW equivalence) produced by Limestone Unit 1. Six sorbents and three injection configurations were evaluated and results were used to select the best combination of sorbent (Norit Americas DARCO Hg-LH at 2 lb/Macf) and injection location (upstream of the ESP) for a two-month performance evaluation. A mercury removal rate of 50-70% was targeted for the long-term test. During this continuous-injection test, mercury removal performance and variability were evaluated as the plant operated under normal conditions. Additional evaluations were made to determine any balance-of-plant impacts of the mercury control process, including those associated with ESP performance and fly ash reuse properties. Upon analysis of the project results, the project team identified several areas of interest for further study. Follow-on testing was conducted on Unit 2 in 2009 with the entire unit treated with injected sorbent so that mercury removal across the FGD could be measured and so that other low-ash impact technologies could be evaluated. Three approaches to minimizing ash impacts were tested: (1) injection of 'low ash impact' sorbents, (2) alterations to the injection configuration, and (3) injection of calcium bromide in conjunction with sorbent. These conditions were tested with the goal of identifying the conditions that result in the highest mercury removal while maintaining the sorbent injection at a rate that preserves the beneficial use of ash.

  15. EFFECTS OF SODIUM AND CALCIUM IN LIGNITE ON THE PERFORMANCE OF ACTIVATED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Edwin S. Olson; Kurt E. Eylands; Daniel J. Stepan

    2001-12-01

    New federal drinking water regulations have been promulgated to restrict the levels of disinfection by-products (DBPs) in finished public water supplies. DBPs are suspected carcinogens and are formed when organic material is partially oxidized by disinfectants commonly used in the water treatment industry. Additional federal mandates are expected in the near future that will also affect public water suppliers with respect to DBPs. These new federal drinking water regulations may require public water suppliers to adjust treatment practices or incorporate additional treatment operations into their existing treatment trains. Many options have been identified, including membrane processes, granular activated carbon, powered activated carbon (PAC), enhanced coagulation and/or softening, and alternative disinfectants (e.g., chlorine dioxide, ozone, and chloramines). Of the processes being considered, PAC appears to offer an attractive benefit-to-cost advantage for many water treatment plants, particularly small systems (those serving fewer than 10,000 customers). PAC has traditionally been used by the water treatment industry for the removal of compounds contributing to taste and odor problems. PAC also has the potential to remove naturally occurring organic matter (NOM) from raw waters prior to disinfection, thus controlling the formation of regulated DBPs. Many small water systems are currently using PAC for taste and odor control and have the potential to use PAC for controlling DBPs. Activated carbons can be produced from a variety of raw materials, including wood, peat, coconut husks, and numerous types of coal. The Energy & Environmental Research Center (EERC) has been working on the development of a PAC product to remove NOM from surface water supplies to prevent the formation of carcinogenic DBPs during chlorination. During that study, the sodium and calcium content of the lignites showed a significant effect on the sorption capacity of the activated carbon product. As much as a 130% increase in the humic acid sorption capacity of a PAC produced from a high-sodium-content lignite was observed. We hypothesize that the sodium and calcium content of the coal plays a significant role in the development of pore structures and pore-size distribution, ultimately producing activated carbon products that have greater sorption capacity for specific contaminants, depending on molecular size.

  16. PILOT-AND FULL-SCALE DEMONSTRATION OF ADVANCED MERCURY CONTROL TECHNOLOGIES FOR LIGNITE-FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Steven A. Benson; Charlene R. Crocker; Kevin C. Galbreath; Jay R. Gunderson; Mike J. Holmes; Jason D. Laumb; Michelle R. Olderbak; John H. Pavlish; Li Yan; Ye Zhuang; Jill M. Zola

    2004-02-01

    North Dakota lignite-fired power plants have shown a limited ability to control mercury emissions in currently installed electrostatic precipitators (ESPs), dry scrubbers, and wet scrubbers (1). This low level of control can be attributed to the high proportions of Hg{sup 0} present in the flue gas. Speciation of Hg in flue gases analyzed as part of the U.S. Environmental Protection Agency (EPA) information collection request (ICR) for Hg data showed that Hg{sup 0} ranged from 56% to 96% and oxidized mercury ranged from 4% to 44%. The Hg emitted from power plants firing North Dakota lignites ranged from 45% to 91% of the total Hg, with the emitted Hg being greater than 85% elemental. The higher levels of oxidized mercury were only found in a fluidized-bed combustion system. Typically, the form of Hg in the pulverized and cyclone-fired units was dominated by Hg{sup 0} at greater than 85%, and the average amount of Hg{sup 0} emitted from North Dakota power plants was 6.7 lb/TBtu (1, 2). The overall objective of this Energy & Environmental Research Center (EERC) project is to develop and evaluate advanced and innovative concepts for controlling Hg emissions from North Dakota lignite-fired power plants by 50%-90% at costs of one-half to three-fourths of current estimated costs. The specific objectives are focused on determining the feasibility of the following technologies: Hg oxidation for increased Hg capture in wet and dry scrubbers, incorporation of additives and technologies that enhance Hg sorbent effectiveness in ESPs and baghouses, the use of amended silicates in lignite-derived flue gases for Hg capture, and the use of Hg adsorbents within a baghouse. The scientific approach to solving the problems associated with controlling Hg emissions from lignite-fired power plants involves conducting testing of the following processes and technologies that have shown promise on a bench, pilot, or field scale: (1) activated carbon injection (ACI) upstream of an ESP combined with sorbent enhancement, (2) Hg oxidation and control using wet and dry scrubbers, (3) enhanced oxidation at a full-scale power plant using tire-derived fuel (TDF) and oxidizing catalysts, and (4) testing of Hg control technologies in the Advanced Hybrid{trademark} filter insert.

  17. Industrial properties of lignitic and lignocellulosic fly ashes from Turkish sources

    SciTech Connect (OSTI)

    Demirbas, A.; Cetin, S.

    2006-01-21

    Fly ash is an inorganic matter from combustion of the carbonaceous solid fuels. More than half the electricity in Turkey is produced from lignite-fired power plants. This energy production has resulted in the formation of more than 13 million tons of fly ash waste annually. The presence of carbon in fly ash inducing common faults include adding unwanted black color and adsorbing process or product materials such as water and chemicals. One of the reasons for not using fly ash directly is its carbon content. For some uses carbon must be lower than 3%. Fly ash has been used for partial replacement of cement, aggregate, or both for nearly 70 years, and it is still used on a very limited scale in Turkey. The heavy metal content of industrial wastewaters is an important source of environmental pollution. Each of the three major oxides (SiO{sub 2} + Al{sub 2}O{sub 3} + Fe{sub 2}O{sub 3}) in fly ash can be ideal as a metal adsorbent.

  18. Laboratory investigation of the extrusion of North Dakota lignite fines for fixed-bed gasification. Report for September 1982-December 1983

    SciTech Connect (OSTI)

    Furman, A.H.; Smith, D.P.

    1984-01-01

    Lignite coal will be used as the gasifier feedstock in the first commercial substitute high-Btu fuels plant to be built in the U.S. The Great Plains plant, which is due to go on line in 1984, will use O2 blown, fixed-bed gasifiers to convert lignite coal into a medium Btu gas which is then upgraded to pipeline quality gas for final distribution. Since the fixed-bed gasifier requires a sized feedstock, up to 35% of the incoming run-of-mine lignite could be rejected as fines unless an alternative use can be found for the-1/4-inch fraction. Evaluation tests were run in the General Electric 6-inch single screw coal extruder to test the suitability of this process for utilization of lignite fines. Both organic and inorganic binders were evaluated. Tests were performed on the extrudate to evaluate their mechanical strength as well as their ability to withstand exposure to a high temperature gasification environment. Successful compacts were produced using bentonite clay, processed lignite coal tar, and a commercial coke oven pitch as the binding agent.

  19. JV Task 106 - Feasibility of CO2 Capture Technologies for Existing North Dakota Lignite-Fired Pulverized Coal Boilers

    SciTech Connect (OSTI)

    Michael L. Jones; Brandon M. Pavlish; Melanie D. Jensen

    2007-05-01

    The goal of this project is to provide a technical review and evaluation of various carbon dioxide (CO{sub 2}) capture technologies, with a focus on the applicability to lignite-fired facilities within North Dakota. The motivation for the project came from the Lignite Energy Council's (LEC's) need to identify the feasibility of CO{sub 2} capture technologies for existing North Dakota lignite-fired, pulverized coal (pc) power plants. A literature review was completed to determine the commercially available technologies as well as to identify emerging CO{sub 2} capture technologies that are currently in the research or demonstration phase. The literature review revealed few commercially available technologies for a coal-fired power plant. CO{sub 2} separation and capture using amine scrubbing have been performed for several years in industry and could be applied to an existing pc-fired power plant. Other promising technologies do exist, but many are still in the research and demonstration phases. Oxyfuel combustion, a technology that has been used in industry for several years to increase boiler efficiency, is in the process of being tailored for CO{sub 2} separation and capture. These two technologies were chosen for evaluation for CO{sub 2} separation and capture from coal-fired power plants. Although oxyfuel combustion is still in the pilot-scale demonstration phase, it was chosen to be evaluated at LEC's request because it is one of the most promising emerging technologies. As part of the evaluation of the two chosen technologies, a conceptual design, a mass and energy balance, and an economic evaluation were completed.

  20. Transformation of alkali metals during pyrolysis and gasification of a lignite

    SciTech Connect (OSTI)

    Xiaofang Wei; Jiejie Huang; Tiefeng Liu; Yitian Fang; Yang Wang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-05-15

    Transformation of Na and K in a lignite was investigated during pyrolysis and gasification in a fixed-bed by using a serial dissolution method with H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solutions. The evolution of the fractions of four forms in solid and alkali volatilization during pyrolysis and gasification was determined. The results show that a different mode of occurrence between Na and of K in coal existed. Na in coal can be nearly completely dissolved by H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solution. However, K in coal exists almost in the stable forms. Both H{sub 2}O soluble and CH{sub 3}COONH{sub 4} soluble Na and K fractions decline during pyrolysis and early gasification stage and increase a little with the process of char gasification. The stable form Na in the char produced during pyrolysis is transferred to other forms during char gasification via the pore opening and a series of chemical reactions. Na{sub 2}SO{sub 4} (K{sub 2}SO{sub 4}) may play an important role in producing stable forms such as Na{sub 2}O.Al{sub 2}O{sub 3}2SiO{sub 2} and K{sub 2}O.Al{sub 2}O{sub 3}.2SiO{sub 2} during pyrolysis. The fraction of HCl soluble K increases during pyrolysis but decreases markedly during the early gasification stage. 20 refs., 7 figs., 1 tabs.

  1. Baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    This baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota, evaluates the potential impacts to public health or the environment from contaminated ground water at this site. This contamination is a result of the uraniferous lignite ashing process, when coal containing uranium was burned to produce uranium. Potential risk is quantified only for constituents introduced by the processing activities and not for the constituents naturally occurring in background ground water in the site vicinity. Background ground water, separate from any site-related contamination, imposes a percentage of the overall risk from ground water ingestion in the Bowman site vicinity. The US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is developing plans to address soil and ground water contamination at the site. The UMTRA Surface Project involves the determination of the extent of soil contamination and design of an engineered disposal cell for long-term storage of contaminated materials. The UMTRA Ground Water Project evaluates ground water contamination. Based on results from future site monitoring activities as defined in the site observational work plan and results from this risk assessment, the DOE will propose an approach for managing contaminated ground water at the Bowman site.

  2. JV TASK 45-MERCURY CONTROL TECHNOLOGIES FOR ELECTRIC UTILITIES BURNING LIGNITE COAL, PHASE I BENCH-AND PILOT-SCALE TESTING

    SciTech Connect (OSTI)

    John H. Pavlish; Michael J. Holmes; Steven A. Benson; Charlene R. Crocker; Edwin S. Olson; Kevin C. Galbreath; Ye Zhuang; Brandon M. Pavlish

    2003-10-01

    The Energy & Environmental Research Center has completed the first phase of a 3-year, two-phase consortium project to develop and demonstrate mercury control technologies for utilities that burn lignite coal. The overall project goal is to maintain the viability of lignite-based energy production by providing utilities with low-cost options for meeting future mercury regulations. Phase I objectives are to develop a better understanding of mercury interactions with flue gas constituents, test a range of sorbent-based technologies targeted at removing elemental mercury (Hg{sup o}) from flue gases, and demonstrate the effectiveness of the most promising technologies at the pilot scale. The Phase II objectives are to demonstrate and quantify sorbent technology effectiveness, performance, and cost at a sponsor-owned and operated power plant. Phase I results are presented in this report along with a brief overview of the Phase II plans. Bench-scale testing provided information on mercury interactions with flue gas constituents and relative performances of the various sorbents. Activated carbons were prepared from relatively high-sodium lignites by carbonization at 400 C (752 F), followed by steam activation at 750 C (1382 F) and 800 C (1472 F). Luscar char was also steam-activated at these conditions. These lignite-based activated carbons, along with commercially available DARCO FGD and an oxidized calcium silicate, were tested in a thin-film, fixed-bed, bench-scale reactor using a simulated lignitic flue gas consisting of 10 {micro}g/Nm{sup 3} Hg{sup 0}, 6% O{sub 2}, 12% CO{sub 2}, 15% H{sub 2}O, 580 ppm SO{sub 2}, 120 ppm NO, 6 ppm NO{sub 2}, and 1 ppm HCl in N{sub 2}. All of the lignite-based activated (750 C, 1382 F) carbons required a 30-45-minute conditioning period in the simulated lignite flue gas before they exhibited good mercury sorption capacities. The unactivated Luscar char and oxidized calcium silicate were ineffective in capturing mercury. Lignite-based activated (800 C, 1472 F) carbons required a shorter (15-minute) conditioning period in the simulated lignite flue gas and captured gaseous mercury more effectively than those activated at 750 C (1382 F). Subsequent tests with higher acid gas concentrations including 50 ppm HCl showed no early mercury breakthrough for either the activated (750 C, 1382 F) Bienfait carbon or the DARCO FGD. Although these high acid gas tests yielded better mercury capture initially, significant breakthrough of mercury ultimately occurred sooner than during the simulated lignite flue gas tests. The steam-activated char, provided by Luscar Ltd., and DARCO FGD, provided by NORIT Americas, were evaluated for mercury removal potential in a 580 MJ/hr (550,000-Btu/hr) pilot-scale coal combustion system equipped with four particulate control devices: (1) an electrostatic precipitator (ESP), (2) a fabric filter (FF), (3) the Advanced Hybrid{trademark} filter, and (4) an ESP and FF in series, an EPRI-patented TOXECON{trademark} technology. The Ontario Hydro method and continuous mercury monitors were used to measure mercury species concentrations at the inlet and outlet of the control technology devices with and without sorbent injection. Primarily Hg{sup o} was measured when lignite coals from the Poplar River Plant and Freedom Mine were combusted. The effects of activated Luscar char, DARCO FGD, injection rates, particle size, and gas temperature on mercury removal were evaluated for each of the four particulate control device options. Increasing injection rates and decreasing gas temperatures generally promoted mercury capture in all four control devices. Relative to data reported for bituminous and subbituminous coal combustion flue gases, higher sorbent injection rates were generally required for the lignite coal to effectively remove mercury. Documented results in this report provide the impacts of these and other parameters and provide the inputs needed to direct Phase II of the project.

  3. Behavior of chars from Bursa Mustafa Kemal Pasa Alpagut and Balkesir Dursunbey Cakiirca Lignite (Turkey) during non-catalytic and catalytic gasification

    SciTech Connect (OSTI)

    Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.; Tekes, A.T.; Canel, M. [Ankara University, Ankara (Turkey). Dept. of Chemistry

    2008-07-01

    The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures of the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.

  4. Geotechnical studies related to in situ lignite-gasification trials. Semi-annual technical report, October 1, 1980-March 31, 1981

    SciTech Connect (OSTI)

    Hoskins, E.R.; Russell, J.E.

    1981-04-01

    The Petroleum Engineering Department at Texas A and M University has conducted field tests on in situ gasification of lignite first at the Easterwood Site near the main campus during 1978 and more recently at the Rockdale Site adjacent to the Sandow Mine near the town of Rockdale in Milam County, Texas. The present project is related to the gasification trials at the Rockdale Site. The objective of the current study is to investigate those geotechnical factors that may influence the performance of the in situ gasification process. These factors include: (1) pre-existing fracture patterns in the lignite and their influence on permeability; (2) strength and deformability of the overburden materials and how these properties are changed by the gasification process and their relationship to subsidence; and (3) the size, shape, and orientation of cavities produced by the process and their relationship to local fracture patterns and geologic structure. The current study is necessarily site specific and related to the Rockdale Site. Ultimately, the goal is to develop models that would be adaptable to any site with a minimum amount of site-specific investigation.

  5. Potential use of California lignite and other alternate fuel for enhanced oil recovery. Phase I and II. Final report. [As alternative fuels for steam generation in thermal EOR

    SciTech Connect (OSTI)

    Shelton, R.; Shimizu, A.; Briggs, A.

    1980-02-01

    The Nation's continued reliance on liquid fossil fuels and decreasing reserves of light oils gives increased impetus to improving the recovery of heavy oil. Thermal enhanced oil recovery EOR techniques, such as steam injection, have generally been the most effective for increasing heavy oil production. However, conventional steam generation consumes a large fraction of the produced oil. The substitution of alternate (solid) fuels would release much of this consumed oil to market. This two-part report focuses on two solid fuels available in California, the site of most thermal EOR - petroleum coke and lignite. Phase I, entitled Economic Analysis, shows detailed cost comparisons between the two candidate fuels and also with Western coal. The analysis includes fuels characterizations, process designs for several combustion systems, and a thorough evaluation of the technical and economic uncertainties. In Phase II, many technical parameters of petroleum coke combustion were measured in a pilot-plant fluidized bed. The results of the study showed that petroleum coke combustion for EOR is feasible and cost effective in a fluidized bed combustor.

  6. Measurement of gas species, temperatures, coal burnout, and wall heat fluxes in a 200 MWe lignite-fired boiler with different overfire air damper openings

    SciTech Connect (OSTI)

    Jianping Jing; Zhengqi Li; Guangkui Liu; Zhichao Chen; Chunlong Liu

    2009-07-15

    Measurements were performed on a 200 MWe, wall-fired, lignite utility boiler. For different overfire air (OFA) damper openings, the gas temperature, gas species concentration, coal burnout, release rates of components (C, H, and N), furnace temperature, and heat flux and boiler efficiency were measured. Cold air experiments for a single burner were conducted in the laboratory. The double-swirl flow pulverized-coal burner has two ring recirculation zones starting in the secondary air region in the burner. As the secondary air flow increases, the axial velocity of air flow increases, the maxima of radial velocity, tangential velocity and turbulence intensity all increase, and the swirl intensity of air flow and the size of recirculation zones increase slightly. In the central region of the burner, as the OFA damper opening widens, the gas temperature and CO concentration increase, while the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and coal particles ignite earlier. In the secondary air region of the burner, the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and the gas temperature and CO concentration vary slightly. In the sidewall region, the gas temperature, O{sub 2} concentration, and NOx concentration decrease, while the CO concentration increases and the gas temperature varies slightly. The furnace temperature and heat flux in the main burning region decrease appreciably, but increase slightly in the burnout region. The NOx emission decreases from 1203.6 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 0% to 511.7 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 80% and the boiler efficiency decreases from 92.59 to 91.9%. 15 refs., 17 figs., 3 tabs.

  7. Trace element partitioning in Texas lignite 

    E-Print Network [OSTI]

    Acevedo, Lillian Esther

    1989-01-01

    to their enrichment factors and the relationship between their concentrations and particle size. Class I elements show no enrichment in fly ash and no tendency to be more concentrated in the smallest fly ash particles (Au, K, Rb, Ba, Si, Sr, Cs, Na, Fe, Mg, La, Ce... Neutron Activation Analysis. Gamma Rays Used for Neutron Activation Analysis Elements Studied That Present Possible Interferences in NAA . 33 43 VI VII Elemental Average Concentrations of Samples Collected at the Gibbons Creek SES. Comparison...

  8. Trace element analysis of Texas lignite 

    E-Print Network [OSTI]

    Mahar, Sean

    1982-01-01

    , were discharged as gases. As, Cd, Cu, Ga, Mo, Pb, Se, and Zn were concentrated in the fly ash no't collected by the pre- cipitator and discharged through the stack. Al, Ba, CA, Ce. Co, Eu, Fe, Hf, K, La, Mg, Mn, Rb, Sc, Si, Sm, Sr, Ta, Th, and Ti..., Ge, Hf, I, K, La, Li, Na, Nb, P, Pd, Pt, S, Sc, Si, Sr, Ta, Te, Th, Ti, H, W, and Zr are included in Tables 15-19. These elements are extra, as they were not desired for the intended research, but analysis was made as a matter of course, so...

  9. Desulfurization of lignite using steam and air 

    E-Print Network [OSTI]

    Carter, Glenn Allen

    1982-01-01

    in a setting that would be similar to a full scale plan+. Results from +he batch sys+ m were excellent, with as much as 98. 6% of the sulfur removed at 1089 K. The product recovery was abou+ 68%; the remainder of the coal had been gasified... OF CONTENTS PAGE INTRODUCTION LITERATURE REVIEW Sulfur Removal Using a Fixed Bed Reactor Sulfur Removal Using a Batch Fluidized Bed Reactor . . 9 Continuous Fluidized Bed Reactor Systems for Desulfurization of Coal Clean Coke Process IGT Process...

  10. ccpi-lignite | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLos Alamos verifiesValidationENCOAL®AprilGilberton

  11. Evaluation of ground-water quality impacts of lignite waste disposal at a Texas lignite mine 

    E-Print Network [OSTI]

    Green, Deborah Joan

    1984-01-01

    to be responsible for the high degree of selen1um attenuation 1s adsorption of the element by amorphous iron and alum1num ox1des and organic matter abundant in the clay soils of the study area. ACKNOWLEDGEMENTS I would like to thank the members of my thes1s... at the study site for a 1984, and c. comparison lines cations in the sludge ls anions in the sludge ls. concentration (mg/I) January 1983, b. June of contour map center 47 . 48 51 Figure 14 Log-log adsorption relat1on for preliminary evaluation...

  12. Hydrogeology of a reclaimed Central Texas lignite mine 

    E-Print Network [OSTI]

    Pepper, Gail Louise

    1980-01-01

    hydrogeology, and the site strati- graphy. Mining Methods Area stripping is the most common surface mining technique used in Texas at the present time. In this operation, overburden is re- moved by the dragline in a series of rows and cast... or clay) has its own horizontal hydraulic conductivity and collectively the section has a single vertical hydraulic conductivity (fig 12) ~ During mining, the dragline cuts across stratigraphic boundaries so that the spoil material is a random mixture...

  13. The viscometric flow properties of Texas lignite slurried in methanol 

    E-Print Network [OSTI]

    Wilson, Beth Ann

    1982-01-01

    . . Size Dist. ribution Sample OON20. . Size Distribution Sample OON30. . Siz& Distribution Sample OON50. . Size Distribiition SalnPle OOM6&J. . Size Distribution Sample OOH20. . 8 i. ze Distribution Sample 00850, . Size Disl. rihulion SamPle 05L30...

  14. Annotated bibliography of coal in the Caribbean region. [Lignite

    SciTech Connect (OSTI)

    Orndorff, R.C.

    1985-01-01

    The purpose of preparing this annotated bibliography was to compile information on coal localities for the Caribbean region used for preparation of a coal map of the region. Also, it serves as a brief reference list of publications for future coal studies in the Caribbean region. It is in no way an exhaustive study or complete listing of coal literature for the Caribbean. All the material was gathered from published literature with the exception of information from Cuba which was supplied from a study by Gordon Wood of the US Geological Survey, Branch of Coal Resources. Following the classification system of the US Geological Survey (Wood and others, 1983), the term coal resources has been used in this report for reference to general estimates of coal quantities even though authors of the material being annotated may have used the term coal reserves in a similar denotation. The literature ranges from 1857 to 1981. The countries listed include Colombia, Mexico, Venezuela, Cuba, the Dominican Republic, Haiti, Jamaica, Puerto Rico, and the countries of Central America.

  15. A kinetic model for the liquefaction of Texas lignite 

    E-Print Network [OSTI]

    Haley, Sandra Kay

    1980-01-01

    the Wilcox formation was uti- lized. Previous dissolution studies were conducted with bituminous ard subbituminous coals mined in other states. Secondly, the methods This thesis follows the style of the AIChE Journal. of analysis employed on the reaction... conditions, coal characteristics, catalyst effects), others delved into the kinetics and attempted to model their systems. Wiser (1968) utilized a Utah high-volatile bituminous coal and conducted thermal dissolution studies at temperatures ranging from...

  16. Desulfurization of Texas lignite using steam and air 

    E-Print Network [OSTI]

    Stone, Robert Reginald

    1981-01-01

    in Coal Sulfur Removal From Coal By Pyrolysis EXPERIMENTAL METHOD Experimental Apparatus Experimental Procedure Analyses of the Products RESULTS AND DISCUSSION Temperature Effect Upon Desulfurization Pressure Effect Upon Desulfurization... . Treatment Composition Effect Pyrolysis Conditions vs. Addition of' Air V1 V111 ix 10 15 20 24 31 31 35 39 43 45 49 52 53 V11 TABLE OF CONTENTS (Continued) PAGE Pyrolysis Conditions vs. Addition of Steam and Air . . 53 Sulfur Removal...

  17. Some effects of pressure and temperature on combustion of lignite 

    E-Print Network [OSTI]

    Marable, Max

    1975-01-01

    . Cumulative Liquid Production vs. Time - Run No. 1, June 20, 1974, Air, 200 psig . Page 58 59 60 61 62 63 64 65 66 67 68 69 70 LIST OF FIGURES (continued) Figure 40 42 43 44 45 47 48 49 50 51 Cumulative Liquid Production vs. Time...- Run No, 2, July 2/3, 1974, Air, 200, 400 and 600 psig . Cumulative Liquid Production vs. Time- Run No, 3, July 26/27, 1974, Oxygen, 200 psig Cumulative Liquid Production vs, Time- Run No, 4, August 9/10, 1974, Oxygen, 200 psig. Cumulative Liquid...

  18. 24 APRIL 2014, 9:45 10:00 15 Monitoring Steam-Assisted Gravity Drainage (SAGD) with EIT

    E-Print Network [OSTI]

    Adler, Andy

    a small fraction has low enough viscosity to be recovered using conventional crude oil pumping tech such bitumen [2]. The SAGD method uses continuous injection of high-pressure steam to reduce the viscosity of the bitu- men by increasing its temperature and water content (Fig- ure 1). This low-viscosity bitumen

  19. China Energy Databook -- User Guide and Documentation, Version 7.0

    E-Print Network [OSTI]

    Fridley, Ed., David

    2008-01-01

    coal, lignite, peat, and oil shale. [2] Crude oil, naturalcoal, lignite, peat, and oil shale. [2] Crude oil, naturalcoal, lignite, peat, and oil shale. [2] Crude oil, natural

  20. China Energy Databook - Rev. 4

    E-Print Network [OSTI]

    Sinton Editor, J.E.

    2010-01-01

    coal, lignite, peat, and oil shale, Crude oil and naturalcoal, lignite, peat, and oil shale, Crude oil and naturalcoal, lignite, peat, and oil shale. Crude oil and natural

  1. Hydrogeology of a proposed surface lignite mine, southwestern Harrison County, Texas 

    E-Print Network [OSTI]

    Charles, Robert John

    1979-01-01

    VITA 126 L I 8 T OF TABLES Table Page Descriptions of geologrc units. 12 Hydraulic conductivity test results for 6 inch infiltration samples. 45 Classification and hydraulic conductivity of soils. 46 Estimated contribution to deep percolation... test pit monitor wells 74 26 Drawdown measurements of the Lewis well 81 27 Schematic diagram of possible recycling of irriga- tion wat r by infiltration. 83 28 Distribution of water wells by depth. 84 29 Distribution of Total Dissolved Solids (TDS...

  2. Prediction of postmine ground-water quality at a Texas surface lignite mine 

    E-Print Network [OSTI]

    Wise, Clifton Farrell

    1995-01-01

    The prediction Of postmine ground-water quality is encumbered with many complications resulting from the complex hydrologic system found in mine spoils. Current analytical methods such as acid/base accounting have only had limited success...

  3. Geology and engineering geology of a Wilcox lignite deposit in northeastern Rusk County, Texas 

    E-Print Network [OSTI]

    Cole, William F.

    1980-01-01

    sheaz strength (Cu) for a 140 ft highwall. . . . . . . . . . . . . . . . . 86 37 Highwall height (H) vs factor of safety (F). 88 38 Highwall height (ft) vs horizontal distance (ft) from crest to toe of highwall, assuming the dragline is located 10...

  4. Variation in physical rock properties determined from sonic logs at a South Texas lignite mine 

    E-Print Network [OSTI]

    Cato, Kerry Don

    1985-01-01

    and ripper to break up the unit before the dragline can remove it. The hard siltstone was encountered in all three continuous core holes and was descriptively divided into two strati graphi c units . These were described a gray-green to brown clayey s1lts... are in the presently active 'creeks and the water in these sands can be easily controlled. The overburden silts and clays, though possibly a problem for dragline bucket penetration, provide stable conditions for the highwal1. Thus, the remaining operational...

  5. EFFECTS OF SODIUM AND CALCIUM IN LIGNITE ON THE PERFORMANCE OF...

    Office of Scientific and Technical Information (OSTI)

    use PAC for controlling DBPs. Activated carbons can be produced from a variety of raw materials, including wood, peat, coconut husks, and numerous types of coal. The Energy &...

  6. Artificial weathering of siderite (FeCO3) taken from lignite overburden 

    E-Print Network [OSTI]

    Frisbee, Nellie Mae

    1992-01-01

    is calculated after determining the inorganic carbon content (CO2) and the cation exchange capacity (CEC). A/Bb = [CaCO3 + 0. 2 CEC] ? [PA + EA] [8] The CEC for the sample is determined by two methods, as outlined by the Texas Railroad Commission, depending... on the pH of the sample. For samples with a pH less than 5. 0, the CEC is a sum of the exchangeable bases and the KCl exchangeable acidity (Thomas, 1982). The exchangeable bases are determined by a pH 7. 0 ammonium acetate extraction. For samples with a...

  7. Functional and taxonomic diversity of microbial communities in reclaimed East Texas lignite mine soils 

    E-Print Network [OSTI]

    Peach, Allen Edward

    2001-01-01

    of sampling were as follows: 7/7/98, 10/29/98, I/25/99, 5/5/99, 7/15/99, 10/14/99, I/31/00, and 5/18/00. For each sample, twenty to thirty core samples (to a depth of approximately 15 cm) were taken at arbitrary points along a transect using a 2. 5-cm.... Sampling protocol. At each site, a 30-meter-diameter circular area was marked with a pole at center. On each sampling visit, three transects were selected arbitrarily and 20 to 30 2. 5-cm-diameter cores (10-15cm deep) were taken across each transect...

  8. A kinetic model for the liquefaction of lignite in a continuous stirred tank reactor 

    E-Print Network [OSTI]

    Culpon, Douglas Holmes

    1982-01-01

    separations at the GFETC: gases; vacuumm distillates (523 K), non ? distillable, Tetrahydrofuran (THF) vs. soluble materials, organic THF insoluble materials, and ash. The reactor was treated as possessing a perfectly mixed, psuedo-homogeneous slurry... as synthesis gas, is reacted to form a wide range of products. A new process, the Mobil M process, is scheduled for operation in New Zealand. In this process, synthesis gas is converted to methanol, which is then converted to gasoline and other products...

  9. Study of factors affecting syngas quality and their interactions in fluidized bed gasification of lignite coal

    E-Print Network [OSTI]

    Spiteri, Raymond J.

    by optimization of the response surface of each index. Ó 2012 Elsevier Ltd. All rights reserved. 1. Introduction in specialized downstream units such as clean fuel combustion, pro- duction of Fischer­Tropsch liquids, and fuel cells, plus a

  10. Characterizing a lignite formation before and after an underground coal gasification experiment 

    E-Print Network [OSTI]

    Ahmed, Usman

    1981-01-01

    ) . Grid Break Up System for the Areal Model Pressure Drawdown (Semi-log Plot) on Well 9 (Post-Gasification). 24 25 27 31 16 Ei-Function Plot. Drawdown on Well 9 and Inter- ference on Wells 10, 13 and 18 (Post-Gasification) . . 32 17 Pressure... Drawdown (Semi-log Plot) on Well 10 (Post-Gasification). 34 18 Ei-Function Plot. Drawdown on Well 10 and Inter- ference on Wells 9, 13 and 18 (Post-Gasification). . . 35 ~Fi ure 19 LIST OF FIGURES (Continued) Pressure Drawdown (Semi-log Plot) on Well...

  11. EFFECTS OF SODIUM AND CALCIUM IN LIGNITE ON THE PERFORMANCE OF...

    Office of Scientific and Technical Information (OSTI)

    OSTI to utilize additional information resources in energy science and technology. A paper copy of this document is also available for sale to the public from the National...

  12. Microbial activities in forest soils exposed to chronic depositions from a lignite power plant

    E-Print Network [OSTI]

    Klose, Susanne; Wernecke, K D; Makeschin, F

    2004-01-01

    V. , Mälkönen, E. 1994. Wood-ash fertilization and fireand long-term effects of wood ash on boreal forest humusorganic matter quality in wood-ash fertilized, clear-cut or

  13. Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar

    SciTech Connect (OSTI)

    Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

    2006-10-15

    In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

  14. DOE Regional Partnership Initiates CO2 Injection in Lignite Coal Seam |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i pStateDOE FederalThe Department ofFederalLEDWhileTheEP942512

  15. Reaction rate kinetics for the non-catalytic hydrogenation of Texas lignite with tetralin and hydrogen gas 

    E-Print Network [OSTI]

    Shumbera, David Allen

    1980-01-01

    gases form by cracking of the heavies. It was concluded that the model needed modifications to account for hydrogen donor and hydrocracking reactions. Shalabi et al. (1979) experimentally determined the rates of formation for oil, asphaltenes...

  16. Establishment, growth and water use of Quercus virginiana (Mill.) on lignite surface-mined soils in response to irrigation 

    E-Print Network [OSTI]

    Duncan, Jacalyn E.

    1991-01-01

    concentration will exert some control over rate of transpiration. This same stomatal closure response often only marginally affects COz assimilation (Farquhar and Sharkey 1982). Wind often acts to cool the leaf. If the leaf is warmer than the surrounding air... because it is absorbing solar radiation, increasing wind speed can sometimes reduce transpiration because cooling reduces the water vapor pressure in the intercellular spaces (Nobel 1982). Nevertheless, in many instances wind does increase...

  17. Understanding Wind Turbine Price Trends in the U.S. Over the Past Decade

    E-Print Network [OSTI]

    Bolinger, Mark

    2013-01-01

    coal, lignite (soft coal), crude oil, natural gas, uranium,Vestas 1.65 MW Turbine A A Crude oil A Hard coal A Lignite A

  18. GEOLOGICA ULTRAJECTINA Mededelingen van de

    E-Print Network [OSTI]

    Utrecht, Universiteit

    ) and the recognition of astronomically forced sedimentary cycles Chapter 7: Rock-magnetic properties of lignite

  19. Capital Flow Types, External Financing Needs, and Industrial Growth: 99 countries, 1991-2007

    E-Print Network [OSTI]

    Aizenman, Joshua; Sushko, Vladyslav

    2011-01-01

    iron and steel products (excluding forging and casting operations) Manufacture of briquettes of lignite, at mining

  20. Advanced power assessment for Czech lignite, Task 3.6, Part 2. The 2nd international conference on energy and environment: Transitions in East Central Europe

    SciTech Connect (OSTI)

    Sondreal, E.A.; Mann, M.D.; Weber, G.W.; Young, B.C.

    1995-12-01

    On November 1-5, 1994, the Energy & Environmental Research Center (EERC) and Power Research Institute of Prague cosponsored their second conference since 1991 in the Czech Republic, entitled ``Energy and Environment: Transitions in East Central Europe.`` This conference was a continuation of the EERC`s joint commitment, initiated in 1190, to facilitate solutions to short- and long-term energy and environmental problems in East Central Europe. Production of energy from coal in an environmentally acceptable manner is a critical issue facing East Central Europe, because the region continues to rely on coal as its primary energy source. The goal of the conference was to develop partnerships between industry, government, and the research community in East Central Europe and the United States to solve energy and environmental issues in a manner that fosters economic development. Among the topics addressed at the conference were: conventional and advanced energy generation systems; economic operation of energy systems; air pollution controls; power system retrofitting and repowering, financing options; regulatory issues; energy resource options; waste utilization and disposal; and long-range environmental issues. Selected papers in the proceedings have been processed separately for inclusion in the Energy Science and Technology database.

  1. Significance of gasification during oxy-fuel combustion of a lignite char in a fluidised bed using a fast UEGO sensor

    E-Print Network [OSTI]

    Saucedo, Marco A.; Butel, Mathias; Scott, Stuart A.; Collings, Nick; Dennis, John S.

    2014-10-29

    -fuel, as the temperature increases, gasification by the high concentrations of CO? present becomes increasingly significant. At low temperatures, e.g. ?1000 K, rates of combustion in oxy-fuel were lower than those in mixtures of O? and N? containing the same mole fraction...

  2. Recovery of Carbon and Nitrogen Cycling and Microbial Community Functionality in a Post-Lignite Mining Rehabilitation Chronosequence in East Texas 

    E-Print Network [OSTI]

    Ng, Justin

    2012-10-19

    chronosequence of 40 years to determine when a reclaimed mine soil (RMS) returned to premined conditions. We sampled 5 sites aged 0 to 20 years reclaimed by the crosspit spreader technique (CP) and 3 sites aged 20 to 40 years reclaimed by the mixed overburden...

  3. Active sites in char gasification. Quarterly technical progress report, 1 April-30 June 1986. [Phenol-formaldehyde resin, lignite and coconut chars

    SciTech Connect (OSTI)

    Calo, J.M.; Suuberg, E.M.; Hradil, G.; Perkins, M.T.; Lilly, W.D.

    1986-01-01

    This project is concerned with the study of the nature and behavior of ''active sites'' in char gasification. The research strategy involves use of model chars produced from the phenol-formaldehyde family of resins. These materials have been chosen since they have structural features similar to those in coals, but are much ''cleaner'' in that the concentration of potentially catalytic impurities can be maintained at low levels. It should be borne in mind that the objective of this work is to study non-catalytic gasification processes. In the previous quarterly report, we presented evidence that low temperature oxygen chemisorption does not provide a site-specific titration of active sites in chars; the uptake of oxygen by a cleaned char surface was unquestionably shown to be a function of temperature and oxygen partial pressure, and the importance of these variables differs from char to char. The fact that ''active surface area'' (ASA) determined by various arbitrary methods does seem to generally correlate with reactivity, seems to suggest that reactivities under various gasification and chemisorption conditions are correlated but that mechanisitic inferences cannot necessarily be drawn from such data. In the present report, we have extended the study of low temperature oxidation of chars, considering mass loss as well as oxygen uptake, since the two processes are essentially inseparable under a wide range of conditions. This work represents more than a simple attempt at trying to learn more about the oxygen chemisorption technique; rather it offers the opportunity to study the mechanism of oxygen attack on char under conditions that allow for better understanding of the fundamental processes. For these reasons, this work was performed in the pyrogasifier reactor (developed for CO/sub 2/ gasification reactivity studies), and complements the ongoing work in the TGA apparatus. 6 refs., 9 figs., 1 tab.

  4. A Framework for Environmental Assessment of CO2 Capture and Storage Systems

    E-Print Network [OSTI]

    Sathre, Roger

    2013-01-01

    Supercritical Pulverized Coal (SCPC) Power Plant. ReportNH 3 CO VOC Pb Hg Coal/PC/MEA Coal/SCPC/MEA Coal/USCPC/MEALignite/PC/MEA Lignite/SCPC/MEA Lignite/USCPC/MEA Coal/SCPC/

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    carbon (1) carbon dioxide (1) cement (1) cements (1) co2 reservoirs (1) co2 thermodynamic properties (1) coal, lignite, and peat (1) coal, lignite, and peat carbon sequestration...

  6. The role of Life Cycle Assessment in identifying and reducing environmental impacts of CCS

    E-Print Network [OSTI]

    Sathre, Roger

    2011-01-01

    is higher for the hard coal-fired plants, at about 180 tosimilar for the hard coal- and lignite-fired plants, but theare lower than for coal- and lignite-fired plants. This is

  7. Introduction The amber deposit of Oise has been recently dis-

    E-Print Network [OSTI]

    Rasmont, Pierre

    , France). The lignite layers containing the amber are from the Lower Eocene of the Paris basin (~53 Ma

  8. Sulfur Cycling in the Terrestrial Subsurface: Commensal Interactions, Spatial Scales, and Microbial Heterogeneity

    E-Print Network [OSTI]

    Grossman, Ethan L.

    scales. Sediment of varied lithology (sands, silts, clays, lignite) was collected from two boreholes in sands that were juxtaposed to clay or lignite-rich sediments. The fermentation of organic matter in the lignite-rich laminae provides small molecular weight organic acids to support sulfate reduction

  9. Characterization of the mineralogy of the oxidized portion of the overburden and relation of pre-mine mineralogy to success of post-mine reclamation at a lignite mine near Jewett, Texas 

    E-Print Network [OSTI]

    Oliver, Julie

    1993-01-01

    by predominantly gray, black or chocolate brown color. When overburden removal procedures are such that cutwalls are visible to the dragline operator these colors may serve as a sign of sediment to avoid when selectively handling overburden for topsoil... three surface pits (areas A, C, & D) are being excavated while plans are being made for a fourth (area B). Special engineering considerations are required for area B since some of the historic mine tunnels are located beneath the area. Draglines...

  10. Conversion of Low-Rank Wyoming Coals into Gasoline by Direct...

    Office of Scientific and Technical Information (OSTI)

    of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction Polyakov, Oleg 01 COAL, LIGNITE, AND PEAT Under the cooperative agreement program of DOE and funding from...

  11. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Long Term Environment and Economic Impacts of Coal Liquefaction in China Fletcher Jerald COAL LIGNITE AND PEAT The project currently is composed of six specific tasks three...

  12. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Conversion of Low Rank Wyoming Coals into Gasoline by Direct Liquefaction Polyakov Oleg COAL LIGNITE AND PEAT Under the cooperative agreement program of DOE and funding from...

  13. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Report",,,,"Alstom Power Inc., Windsor, CT (United States)","USDOE","01 COAL, LIGNITE, AND PEAT; 54 ENVIRONMENTAL SCIENCES Clean Coal Technology; Coal-Fuels;...

  14. Recovery Act: Oxy-Combustion Technology Development for Industrial...

    Office of Scientific and Technical Information (OSTI)

    Testing in Alstom's 15 MWth Boiler Simulation Facility Levasseur, Armand 01 COAL, LIGNITE, AND PEAT; 54 ENVIRONMENTAL SCIENCES Clean Coal Technology; Coal-Fuels;...

  15. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Assessment of the petroleum coal and geothermal resources of the economic community of West African states ECOWAS region Mattick R E comp PETROLEUM COAL LIGNITE AND PEAT GEOTHERMAL...

  16. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    CYCLONE OPTIMIZATON Gerald H Luttrell Chris J Barbee Peter J Bethell Chris J Wood COAL LIGNITE AND PEAT COAL DESIGN DIAMONDS DOLOMITE ECONOMICS EFFICIENCY EVALUATION...

  17. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    "NT0000749",,"Technical Report",,,,"Southern Company Services Incorporated","USDOE","01 COAL, LIGNITE, AND PEAT; 20 FOSSIL-FUELED POWER PLANTS; 54 ENVIRONMENTAL SCIENCES",,"The...

  18. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Pittsburgh, PA (United States)","DOE; USDOE, Washington, DC (United States)","01 COAL, LIGNITE, AND PEAT; CHEMICAL REACTORS; COST; COMPARATIVE EVALUATIONS; METHANOL;...

  19. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Capture and Storage Development Project at West Virginia University Fletcher Jerald COAL LIGNITE AND PEAT COAL ENVIRONMENTAL PROCESSES COAL ENVIRONMENTAL PROCESSES The original...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (1) carbon dioxide (1) carcinogens (1) chemical properties (1) civil engineering (1) coal, lignite, and peat (1) disinfectants (1) dose-response relationships (1) drinking water...

  1. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    of circulating fluidized beds Kinetic theory approach Gidaspow D Bezburuah R Ding J COAL LIGNITE AND PEAT ENGINEERING GENERAL AND MISCELLANEOUS MATHEMATICS COMPUTING AND...

  2. DENSE MEDIUM CYCLONE OPTIMIZATON Gerald H. Luttrell; Chris J...

    Office of Scientific and Technical Information (OSTI)

    OPTIMIZATON Gerald H. Luttrell; Chris J. Barbee; Peter J. Bethell; Chris J. Wood 01 COAL, LIGNITE, AND PEAT; COAL; DESIGN; DIAMONDS; DOLOMITE; ECONOMICS; EFFICIENCY;...

  3. Long Term Environment and Economic Impacts of Coal Liquefaction...

    Office of Scientific and Technical Information (OSTI)

    Long Term Environment and Economic Impacts of Coal Liquefaction in China Fletcher, Jerald 01 COAL, LIGNITE, AND PEAT The project currently is composed of six specific tasks - three...

  4. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    fixed bed reactor costs for indirect liquefaction applications Prakash A Bendale P G COAL LIGNITE AND PEAT CHEMICAL REACTORS COST COMPARATIVE EVALUATIONS METHANOL SYNTHESIS...

  5. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    of Energy Efficiency and Renewable Energy Geothermal Tech Pgm)","Not Available","01 COAL, LIGNITE, AND PEAT; 15 GEOTHERMAL ENERGY; BENTONITE; BROWN COAL; DRILLING; DRILLING...

  6. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Report",,,,"Virginia Polytech Institute and State University","USDOE","01 COAL, LIGNITE, AND PEAT; COAL; DESIGN; DIAMONDS; DOLOMITE; ECONOMICS; EFFICIENCY;...

  7. U.S. China Carbon Capture and Storage Development Project at...

    Office of Scientific and Technical Information (OSTI)

    Capture and Storage Development Project at West Virginia University Fletcher, Jerald 01 COAL, LIGNITE, AND PEAT COAL - ENVIRONMENTAL PROCESSES COAL - ENVIRONMENTAL PROCESSES The...

  8. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    University Research Corporation","USDOE; USDOE Office of Fossil Energy (FE), Clean Coal (FE-20)","01 COAL, LIGNITE, AND PEAT COAL - ENVIRONMENTAL PROCESSES",,"The original...

  9. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Task Testing in Alstom s MW sub th sub Boiler Simulation Facility Levasseur Armand COAL LIGNITE AND PEAT ENVIRONMENTAL SCIENCES Clean Coal Technology Coal Fuels Industrial and...

  10. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    The National Carbon Capture Center at the Power Systems Development Facility None COAL LIGNITE AND PEAT FOSSIL FUELED POWER PLANTS ENVIRONMENTAL SCIENCES The Power Systems...

  11. liquefaction applications Prakash, A.; Bendale, P.G. 01 COAL...

    Office of Scientific and Technical Information (OSTI)

    reactor costs for indirect liquefaction applications Prakash, A.; Bendale, P.G. 01 COAL, LIGNITE, AND PEAT; CHEMICAL REACTORS; COST; COMPARATIVE EVALUATIONS; METHANOL;...

  12. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    (United States); Western Research Institute, Laramie, WY (United States)","USDOE","01 COAL, LIGNITE, AND PEAT",,"Under the cooperative agreement program of DOE and funding from...

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Text6 Citations0 Multimedia0 Datasets0 Filter Results Filter by Subject catalysts (6) coal liquids (6) coal, lignite, and peat (6) hydrogenation (6) experimental data (5)...

  14. DENSE MEDIA CYCLONE OPTIMIZATION (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    United States Language: English Subject: 01 COAL, LIGNITE, AND PEAT; COAL; OPTIMIZATION; PARTICLE SIZE; PERFORMANCE; RESOLUTION; SEGREGATION Word Cloud More Like This Full...

  15. DENSE MEDIA CYCLONE OPTIMIZATION (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 01 COAL, LIGNITE, AND PEAT; COAL PREPARATION PLANTS; OPTIMIZATION; PERSONNEL; PLANNING; PROCUREMENT; VIRGINIA Word Cloud More Like This Full Text...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (4) fuels (4) combustion (3) combustors (3) -- coal, lignite, & peat-- combustion (2) air pollution control (2) chemical reactions (2) combined-cycle power plants (2) control...

  17. Reducing the environmental impact on solid wastes from a fluidized...

    Office of Scientific and Technical Information (OSTI)

    Subject: 01 COAL, LIGNITE, AND PEAT; COAL; FLUIDIZED-BED COMBUSTION; WASTE MANAGEMENT; AIR POLLUTION ABATEMENT; ALUMINIUM OXIDES; CALCIUM OXIDES; CHEMICAL ACTIVATION;...

  18. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (7) inorganic, organic, physical, and analytical chemistry (5) phonons (5) thermodynamic properties (5) coal, lignite, and peat (4) density functional theory (4) functionals (4)...

  19. Evaluation of Exxon donor solvent full-range distillate as a...

    Office of Scientific and Technical Information (OSTI)

    of Publication: United States Language: English Subject: 01 COAL, LIGNITE, AND PEAT; COAL LIQUIDS; COMBUSTION PROPERTIES; PERFORMANCE TESTING; EXXON LIQUEFACTION PROCESS;...

  20. China Energy Databook - Rev. 4

    E-Print Network [OSTI]

    Sinton Editor, J.E.

    2010-01-01

    Stock Natural Primary Total Gas Electricity H Production Changes Imports Exports I.I II.1 Hard coal, lignite, peat, and oil shale, Crude

  1. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Philippines Asia Pacific energy series Country report Hoffman S ENERGY PLANNING POLICY AND ECONOMY PETROLEUM COAL LIGNITE AND PEAT PHILIPPINES ECONOMIC DEVELOPMENT ENERGY POLICY...

  2. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Center, Honolulu, HI (USA). Resource Systems Inst.","Not Available","29 ENERGY PLANNING, POLICY AND ECONOMY; 02 PETROLEUM; 01 COAL, LIGNITE, AND PEAT; PHILIPPINES; ECONOMIC...

  3. DENSE MEDIA CYCLONE OPTIMIZATION (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    of Energy (US) Country of Publication: United States Language: English Subject: 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; 01 COAL, LIGNITE, AND PEAT;...

  4. Light Absorption Properties and Radiative Effects of Primary...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and their uncertainties for the bulk POA emitted from biomassbiofuel, lignite, propane, and oil combustion sources. In particular, we parametrize the kOA of biomass...

  5. National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China

    E-Print Network [OSTI]

    Zhou, Nan

    2013-01-01

    Operation Rates by Plant Type Coal Fired Units: Types of Coal inChina Type Lignite coal Long flame coal Non-caking coal

  6. Systems and economic analysis of microalgae ponds for conversion...

    Office of Scientific and Technical Information (OSTI)

    01 COAL, LIGNITE, AND PEAT; 09 BIOMASS FUELS; BIOMASS; PRODUCTION; CARBON DIOXIDE; AIR POLLUTION CONTROL; METABOLISM; WASTE PRODUCT UTILIZATION; ALGAE; CULTIVATION; COAL;...

  7. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (4) environmental sciences (3) inorganic, organic, physical, and analytical chemistry (2) air pollution control (1) china (1) coal, lignite, and peat (1) comparative evaluations...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    coal, lignite, and peat (1) coal-fuels (1) electricity (1) environmental sciences clean coal technology (1) general, coal combustion, regulatory (1) industrial and environmental...

  9. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    J R Oswald W J COAL LIGNITE AND PEAT BIOMASS FUELS BIOMASS PRODUCTION CARBON DIOXIDE AIR POLLUTION CONTROL METABOLISM WASTE PRODUCT UTILIZATION ALGAE CULTIVATION COAL ECONOMIC...

  10. Systems and economic analysis of microalgae ponds for conversion...

    Office of Scientific and Technical Information (OSTI)

    W.J. 01 COAL, LIGNITE, AND PEAT; 09 BIOMASS FUELS; BIOMASS; PRODUCTION; CARBON DIOXIDE; AIR POLLUTION CONTROL; METABOLISM; WASTE PRODUCT UTILIZATION; ALGAE; CULTIVATION; COAL;...

  11. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    COAL, LIGNITE, AND PEAT; 09 BIOMASS FUELS; BIOMASS; PRODUCTION; CARBON DIOXIDE; AIR POLLUTION CONTROL; METABOLISM; WASTE PRODUCT UTILIZATION; ALGAE; CULTIVATION; COAL;...

  12. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    coal deposits (1) coal, lignite, and peat (1) endangered species (1) energy planning, policy, and economy (1) ground water (1) hydrocarbons (1) lawsuits (1) marketers (1) methane...

  13. Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    ACI Committee 229 Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS; 01 COAL, LIGNITE, AND PEAT; FLY ASH; WASTE PRODUCT UTILIZATION; BACKFILLING; THERMAL...

  14. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    CLSM reported by ACI Committee Rajendran N MATERIALS SCIENCE FOSSIL FUELED POWER PLANTS COAL LIGNITE AND PEAT FLY ASH WASTE PRODUCT UTILIZATION BACKFILLING THERMAL INSULATION SHOCK...

  15. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Molecular catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids Yang Shiyong Stock L M COAL LIGNITE AND PEAT CHEMISTRY COAL LIQUIDS HYDROGENATION...

  16. Molecular catalytic hydrogenation of aromatic hydrocarbons and

    Office of Scientific and Technical Information (OSTI)

    catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. 01 COAL, LIGNITE, AND PEAT; 40 CHEMISTRY; COAL LIQUIDS;...

  17. Electric Reliability & Hurricane Preparedness Plan

    E-Print Network [OSTI]

    · Clean coal technology · On line ­ May 2014 · Generation mix: Natural gas, coal and lignite · Base load requirements #12;New Gen Mix Nat Gas Coal 3rd Qtr Lignite #12;Stennis Space Center · 115 kV ­ 13.8 kV · 3 MPC

  18. 200 Years of Pb Deposition throughout the Czech Republic

    E-Print Network [OSTI]

    Wieder, R. Kelman

    in the 1860s, considerable air pollution began in 1945 with use of lignite coal for energy production occurred between 1965 and 1992, corresponding to a period of peak production and burning of lignite coal to German unification, the former East Germany and Czechoslovakiaburnednearlyone

  19. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    1131055","None","FE0000699",,"Technical Report",,,,"University Of Kentucky","USDOE","01 COAL, LIGNITE, AND PEAT; 54 ENVIRONMENTAL SCIENCES",,"The U.S. is the largest producer of...

  20. Center for Advanced Separation Technology Honaker, Rick 01 COAL...

    Office of Scientific and Technical Information (OSTI)

    Advanced Separation Technology Honaker, Rick 01 COAL, LIGNITE, AND PEAT; 54 ENVIRONMENTAL SCIENCES The U.S. is the largest producer of mining products in the world. In 2011, U.S....

  1. The National Carbon Capture Center at the Power Systems Development

    Office of Scientific and Technical Information (OSTI)

    None 01 COAL, LIGNITE, AND PEAT; 20 FOSSIL-FUELED POWER PLANTS; 54 ENVIRONMENTAL SCIENCES The Power Systems Development Facility (PSDF) is a state-of-the-art test center sponsored...

  2. The Mesaba Energy Project: Clean Coal Power Initiative, Round...

    Office of Scientific and Technical Information (OSTI)

    Mesaba Energy Project: Clean Coal Power Initiative, Round 2 Stone, Richard; Gray, Gordon; Evans, Robert 01 COAL, LIGNITE, AND PEAT; 20 FOSSIL-FUELED POWER PLANTS The Mesaba Energy...

  3. Recent Developments in Geothermal Drilling Fluids Kelsey, J....

    Office of Scientific and Technical Information (OSTI)

    M. J.; Clements, W. R.; Hilscher, L. W.; Remont, L. J.; Matula, G. W.; Balley, D. N. 01 COAL, LIGNITE, AND PEAT; 15 GEOTHERMAL ENERGY; BENTONITE; BROWN COAL; DRILLING; DRILLING...

  4. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    The Mesaba Energy Project Clean Coal Power Initiative Round Stone Richard Gray Gordon Evans Robert COAL LIGNITE AND PEAT FOSSIL FUELED POWER PLANTS The Mesaba Energy Project is a...

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Electronic Full Text1 Citations0 Multimedia0 Datasets0 Filter Results Filter by Subject coal (1) coal, lignite, and peat (1) design (1) diamonds (1) dolomite (1) economics (1)...

  6. Assessment of the petroleum, coal, and geothermal resources of...

    Office of Scientific and Technical Information (OSTI)

    the petroleum, coal, and geothermal resources of the economic community of West African states (ECOWAS) region Mattick, R.E. (comp.) 02 PETROLEUM; 01 COAL, LIGNITE, AND PEAT; 15...

  7. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Center for Advanced Separation Technology Honaker Rick COAL LIGNITE AND PEAT ENVIRONMENTAL SCIENCES The U S is the largest producer of mining products in the world In U S mining...

  8. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    J R Rand P B Nevins M J Clements W R Hilscher L W Remont L J Matula G W Balley D N COAL LIGNITE AND PEAT GEOTHERMAL ENERGY BENTONITE BROWN COAL DRILLING DRILLING FLUIDS FIELD...

  9. Coal-CO[subscript 2] Slurry Feed for Pressurized Gasifiers: Slurry Preparation System Characterization and Economics

    E-Print Network [OSTI]

    Botero, Cristina

    Gasification-based plants with coal-CO[subscript 2] slurry feed are predicted to be more efficient than those with coal-water slurry feed. This is particularly true for high moisture, low rank coal such as lignite. ...

  10. Development and Application of Advanced Models for Steam Hydrogasification: Process Design and Economic Evaluation

    E-Print Network [OSTI]

    Lu, Xiaoming

    2012-01-01

    index.htm 17. Higman C. Gasification. 2 nd edition. Boston:J, Cheremisinoff NP. Gasification Technologies: A Primer forof lignite char pressurized gasification with CO 2 , H 2 and

  11. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (1) clathrates (1) clay (1) clays (1) co2 (1) co2 reservoirs (1) co2 thermodynamic properties (1) co2-soluble surfactants (1) coal (1) coal, lignite, and peat (1)...

  12. Impacts of high energy prices on long-term energy-economic scenarios for Germany

    E-Print Network [OSTI]

    with current allocation rules in the emissions trading scheme, the CO2 emissions decrease relatively steadily (especially lignite). In the case of the implementation of an ideal emissions trading scheme with full

  13. State of Industrial Fluidized Bed Combustion 

    E-Print Network [OSTI]

    Mesko, J. E.

    1982-01-01

    A new combustion technique has been developed in the last decade that permits the burning of low quality coal, lignite and other fuels, while maintaining stack emissions within State and Federal limits. Low quality fuels can be burned directly...

  14. Underground Coal Gasification at Tennessee Colony 

    E-Print Network [OSTI]

    Garrard, C. W.

    1979-01-01

    The Tennessee Colony In Situ Coal Gasification Project conducted by Basic Resources Inc. is the most recent step in Texas Utilities Company's ongoing research into the utilization of Texas lignite. The project, an application of the Soviet...

  15. State of Fluidized Bed Combustion Technology 

    E-Print Network [OSTI]

    Pope, M.

    1979-01-01

    A new combustion technology has been developed in the last decade that permits the burning of low quality coal, lignite and other fuels, while maintaining stack emissions within State and Federal EPA limits. Low quality fuels can be burned...

  16. A geochemical and sedimentary record of high southern latitude Holocene climate evolution from Lago Fagnano, Tierra del Fuego

    E-Print Network [OSTI]

    Gilli, Adrian

    -derived lignite. Our chronology is consistent with a tephrochronologic age date for deposits from the middle) parameters with physical sediment properties allows us to better understand sediment provenance and transport

  17. Physica A 259 (1998) 19 Growth properties of Eden model

    E-Print Network [OSTI]

    Stanley, H. Eugene

    1998-01-01

    Physica A 259 (1998) 1­9 Growth properties of Eden model with acceleration sites Sasuke Miyazima a which is found in experiments of sedimentary sandstones [16,17], lignite coals [18], colloidal silicate

  18. Palaeoenvironmental evolution of Lake Gacko (Southern Bosnia and Herzegovina): Impact of the Middle Miocene Climatic Optimum on the Dinaride Lake System

    E-Print Network [OSTI]

    Utrecht, Universiteit

    properties, and fossil mollusc palaeoecology reveals repetitive changes in lake level. These are interpreted.8 and ~15.2 Ma. The economically valuable lignite accumulations in the lower part of the succession

  19. Three-dimensional displacement-length scaling and maximum dimension of normal faults in layered rocks

    E-Print Network [OSTI]

    and Scholz, 2000], (2) linkage [e.g., Cartwright et al., 1995] or (3) variations in rock properties [Bu on a 30­70° dipping bedding plane of early Maestrichtian continental limestone in the lignite quarry from

  20. Horizontal well construction/completion process in a Gulf of Mexico unconsolidated sand: development of baseline correlations for improved drill-in fluid cleanup practices 

    E-Print Network [OSTI]

    Lacewell, Jason Lawrence

    1999-01-01

    -planning by lignite personnel for handling, weather problems, storage/mixing requirements and fluid property maintenance are very important for successful operations using DIF. Proper maintenance of solids control systems is essential for quality control of DIF...

  1. Life-Cycle Assessment of Concrete: Decision-Support Tool and Case Study Application

    E-Print Network [OSTI]

    Gursel, Aysegul Petek

    2014-01-01

    for bituminous and lignite coal types based on IPPC report [40 kWh/tonne depending on the type of coal used in the kiln.burning different types of coal under varying conditions.

  2. Impacts of feral hogs on reclaimed surface-mined lands in eastern Texas: a management perspective 

    E-Print Network [OSTI]

    Mersinger, Robert C.

    1999-01-01

    During the last decade, surface lignite mines in eastern Texas have experienced damage to reclaimed lands by feral hogs (Sus scrota). Specifically, feral hogs have caused damage to vegetative plantings used in the reclamation ...

  3. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01

    Utilization of Lignite Fly Ash," in Technology and Use ofon ignition l Class Cd fly ash ; ;:, o. 5 aThe expression ofextenders (bentonite, fly ash), weight material to increase

  4. Microsoft Word - DOE St.Louis Workshop 12-8-11 Final

    Office of Environmental Management (EM)

    9 We have one project right now that is a gas plant. It 10 converts lignite coal to natural gas, and they actually 11 have a pipeline that delivers CO2 to the oil fields 12...

  5. Hydrogeology of the Piedmont Springs National Historic Site Grimes County, Texas 

    E-Print Network [OSTI]

    Waclawczyk, Randy R.

    1989-01-01

    Site relative to the economic lignite deposits Surface mining operation using a walking dragline and truck/shovel operation. . . . . . . . . Geologic Map of the Anderson- Millican area, (Star represents the location of Piedmont Springs National... in Texas is to strip the overburden with a walking dragline and remove the lignite resource with either an easy miner or shovel and then transport the resource to the power plant using trucks or conveyors. This method, however, significantly alters...

  6. Power Systems Development Facility Gasification Test Campaign TC21

    SciTech Connect (OSTI)

    Southern Company Services

    2007-01-30

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coal. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of the first demonstration of gasification operation with lignite coal following the 2006 gasifier configuration modifications. This demonstration took place during test campaign TC21, occurring from November 7, 2006, through January 26, 2007. The test campaign began with low sodium lignite fuel, and after 304 hours of operation, the fuel was changed to high sodium lignite, for 34 additional hours of operation. Both fuels were from the North Dakota Freedom mine. Stable operation with low sodium lignite was maintained for extended periods, although operation with high sodium lignite was problematic due to agglomeration formation in the gasifier restricting solids circulation.

  7. Fossil fuel potential of Turkey: A statistical evaluation of reserves, production, and consumption

    SciTech Connect (OSTI)

    Korkmaz, S.; Kara-Gulbay, R.; Turan, M. [Karadeniz Technical University, Trabzon (Turkey)

    2008-07-01

    Since Turkey is a developing country with tremendous economic growth, its energy demand is also getting increased. Of this energy, about 70% is supplied from fossil fuels and the remaining 30% is from renewable sources. Among the fossil fuels, 90% of oil, natural gas, and coal are imported, and only 10% is from domestic sources. All the lignite is supplied from domestic sources. The total share of renewable sources and lignite in the total energy production is 45%. In order for Turkey to have sufficient and reliable energy sources, first the renewable energy sources must be developed, and energy production from fossil fuels, except for lignite, must be minimized. Particularly, scarcity of fossil fuels and increasing oil prices have a strong effect on economic growth of the country.

  8. Appropriate Combinations of Technology for Solving Landscape Management Problems

    E-Print Network [OSTI]

    of the coal will be recovered by surface mining. On an average, each 1 million tons of coal mined will disturb major lignite producing surface mine in the state, the Sandow Mine at Rockdale, Texas. This mineAppropriate Combinations of Technology for Solving Landscape Management Problems Session E: Surface

  9. Short Communication Catalytic coal gasification: use of calcium versus potassium*

    E-Print Network [OSTI]

    Short Communication Catalytic coal gasification: use of calcium versus potassium* Ljubisa R on the gasification in air and 3.1 kPa steam of North Dakota lignitic chars prepared under slow and rapid pyrolysis of calcium is related to its sintering via crystallite growth. (Keywords: coal; gasification; catalysis

  10. Modelling Rates of Gasification of a Char Particle in Chemical Looping Combustion

    E-Print Network [OSTI]

    Saucedo, Marco A.; Dennis, John S.; Scott, Stuart A.

    2014-07-15

    Rates of gasification of lignite char were compared when gasification with CO2 was undertaken in a fluidised bed of either (i) an active Fe-based oxygen carrier used for chemical looping or (ii) inert sand. The kinetics of the gasification were...

  11. Energies 2012, 5, 5065-5085; doi:10.3390/en5125065 ISSN 1996-1073

    E-Print Network [OSTI]

    in Northwestern Ontario, Canada Md. Bedarul Alam 1, *, Reino Pulkki 1,2 , Chander Shahi 1 and Thakur Upadhyay 1 11, Canada; E-Mails: rpulkki@lakeheadu.ca (R.P.); cshahi@lakeheadu.ca (C.S.); tpupadhy) in northwestern Ontario (NWO) to replace lignite coal with renewable woody biomass as feedstock by 2014. The AGS

  12. Scots pine (Pinus sylvestris L.) site index in relation to physico-chemical and biological properties

    E-Print Network [OSTI]

    Battles, John

    properties in reclaimed mine soils Marcin Pietrzykowski · Jaroslaw Socha · Natalie S. van Doorn Received: 15 on four afforested post-mining sites after lignite, hard coal, sand and sulphur mining extraction. Site-chemical and biological properties of RMS. Field measurements were taken in tree stands ranging from 12 to 30 years of age

  13. Linking heavy metal bioavailability (Cd, Cu, Zn and Pb) in Scots pine needles to soil properties in reclaimed mine areas

    E-Print Network [OSTI]

    Silver, Whendee

    Linking heavy metal bioavailability (Cd, Cu, Zn and Pb) in Scots pine needles to soil properties elements bioavailability and biological (dehydrogenase activity) and physico-chemical properties of mine areas affected by hard coal, sand, lignite and sulphur mining, there is no risk of trace element

  14. Electric Power Costs in Texas in 1985 and 1990 

    E-Print Network [OSTI]

    Gordon, J. B.; White, D. M.

    1979-01-01

    since utilities in Texas will be using a mix of fuels. This paper analyzes the cost of generating electricity from nuclear power, out-of-state coal, in-state lignite, fuel oil, natural gas, geothermal, and solar power. These costs are then used...

  15. Microbial Abundance and Activity in a Low-Conductivity Aquifer System in East-Central Texas

    E-Print Network [OSTI]

    Grossman, Ethan L.

    , clays, and lignite of the Eocene Yegua formation, and wells were installed in all water-bearing sands sources [17]. Evaluation of the potential for bioremediation in these aquifers requires a bet- ter for bioremediation appear good, as numerous studies have shown that nutritionally diverse microorganisms are present

  16. TECHNICAL PAPER I S S N1 0 4 71 .Air & Waste Manage. Assoc. 53:S86-595 C o p y r i2 C O 3A I M& W a s t eM a n aA s s

    E-Print Network [OSTI]

    -fired power plants in Coahuila, Mexico, are the largest sources of SO2 emissions in the area near Big Bend during the BRAVO study. Emissions reductions from more distant regional sources and from the Carbon along the lignite belt in Texas, which runs from the northeast corner of Texas southwest toward the Car

  17. Leonardite char adsorbents

    DOE Patents [OSTI]

    Knudson, C.L.

    1993-10-19

    A process of preparing lignite (low rank) coal filter material, suitable for use in lieu of more expensive activated carbon filter materials, is disclosed. The process comprises size reducing Leonardite coal material to a suitable filtering effective size, and thereafter heating the size reduced Leonardite preferably to at least 750 C in the presence of a flow of an inert gas. 1 figure.

  18. European Customs & Trade Welcome to the twenty-first

    E-Print Network [OSTI]

    duties system. The Coal Tax will be levied on coal, cokes and lignite. It is envisaged that the duty rate on Coal in the Netherlands · East African Community (EAC) Partner States Sign Interim Framework Agreement on Coal in the Netherlands From January 1, 2008, the present Dutch Fuel Tax on coal will no longer apply

  19. les jabots des abeilles taient beaucoup plus remplis et la dissection et l'analyse ont t

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of tar of brown coal and19 million tons of mineral oil have been processed into the final-products bitumin, paraffine, fuel, petrol and coke in the tar factory Rositz (Altenburger Land) from 1917 1990, 19 millions de tonnes de goudron de lignite ont été tranformés en coke, bitume et paraffine, et19

  20. (Basic properties of coals and other solids)

    SciTech Connect (OSTI)

    Not Available

    1991-11-25

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number sign}8, Illinois {number sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  1. [Basic properties of coals and other solids]. Eighth quarterly report, [September--November 1991

    SciTech Connect (OSTI)

    Not Available

    1991-11-25

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number_sign}8, Illinois {number_sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  2. Geek-Up[11.05.10]: Quark Gluon Plasma, Solar-Power Generating Windows and CCS Field Studies

    Broader source: Energy.gov [DOE]

    Large Hadron Collider's (LHC) first record-setting run of high-energy proton collisions, new transparent film capable of absorbing light and generating electrical charge developed, and field test finds that opportunities to permanently store carbon in unmineable seams of lignite may be more widespread than previously documented -- all in this week's Geek-Up.

  3. Characterization of a fluidized-bed combustion ash to determine potential for environmental impact. Final report

    SciTech Connect (OSTI)

    Hassett, D.J.; Henderson, A.K.; Pflughoeft-Hassett, D.F.; Mann, M.D.; Eylands, K.E.

    1997-10-01

    A 440-megawatt, circulating fluidized-bed combustion (CFBC), lignite-fired power plant is planned for construction in Choctaw County north of Ackerman, Mississippi. This power plant will utilize Mississippi lignite from the first lignite mine in that state. Malcolm Pirnie, Inc., is working with the power plant developer in the current planning and permitting efforts for this proposed construction project. In order to accommodate Mississippi state regulatory agencies and meet appropriate permit requirements, Malcolm Pirnie needed to provide an indication of the characteristics of the by-products anticipated to be produced at the proposed plant. Since the Mississippi lignite is from a newly tapped mine and the CFBC technology is relatively new, Malcolm Pirnie contacted with the Energy and Environmental Research Center (EERC) to develop and perform a test plan for the production and characterization of ash similar to ash that will be eventually produced at the proposed power plant. The work performed at the EERC included two primary phases: production of by-products in a bench-scale CFBC unit using lignite provided by Malcolm Pirnie with test conditions delineated by Malcolm Pirnie to represent expected operating conditions for the full-scale plant; and an extensive characterization of the by-products produced, focusing on Mississippi regulatory requirements for leachability, with the understanding that return of the by-product to the mine site was an anticipated by-product management plan. The overall focus of this project was the environmental assessment of the by-product expected to be produced at the proposed power plant. Emphasis was placed on the leachability of potentially problematic trace elements in the by-products. The leaching research documented in this report was performed to determine trends of leachability of trace elements under leaching conditions appropriate for evaluating land disposal in monofills, such as returning the by-products to the mine site.

  4. Turkey's energy demand and supply

    SciTech Connect (OSTI)

    Balat, M. [Sila Science, Trabzon (Turkey)

    2009-07-01

    The aim of the present article is to investigate Turkey's energy demand and the contribution of domestic energy sources to energy consumption. Turkey, the 17th largest economy in the world, is an emerging country with a buoyant economy challenged by a growing demand for energy. Turkey's energy consumption has grown and will continue to grow along with its economy. Turkey's energy consumption is high, but its domestic primary energy sources are oil and natural gas reserves and their production is low. Total primary energy production met about 27% of the total primary energy demand in 2005. Oil has the biggest share in total primary energy consumption. Lignite has the biggest share in Turkey's primary energy production at 45%. Domestic production should be to be nearly doubled by 2010, mainly in coal (lignite), which, at present, accounts for almost half of the total energy production. The hydropower should also increase two-fold over the same period.

  5. Progress in two major CCPI projects

    SciTech Connect (OSTI)

    NONE

    2007-07-01

    Two projects under the US Department of Energy (DOE) sponsored Clean Coal Power initiative have made significant progress in demonstrating new technologies to remove mercury from coal and enhance use of low-Btu lignite coals while increasing energy efficiency. The Wisconsin Electricity Power Company is demonstrating the TOXECON{trademark} mercury control process at its Presque Isle Power Plant near Marquette, Michigan, while Great River Energy (GRE) is showing the viability of lignite fuel enhancement at its Coal Creek Station in Underwood, North Dakota. Both projects were awarded in 2004 under Round I of the Clean Coal Power Initiative. Elsewhere in the program, six projects are in various phases of planning or operation. Plans for a third round under the CCPI were announced on May 23, 2007. 2 figs.

  6. Avian population densities and species diversity on reclaimed strip-mined land in East-Central Texas 

    E-Print Network [OSTI]

    Cantle, Peter Christopher

    1978-01-01

    km east of Fairfieid, Texas. It is powered by lignite coal strip-mined from deposits in the surrounding countryside. The stripping operation consists of a very large, electrically-powered dragline that removes "overburden" from the subtending coal... near the power plant. At this writing, a third dragline is being assembled at the site of a new operation (L. Garrett, pers. comm. ). Coal reserves surrounding the plant are expected to last ca 35-50 years, depending on future consumption rates (R...

  7. The Products of the Destructive Distillation of Keratin in the Form of Leather

    E-Print Network [OSTI]

    Rose, Reed Phillips

    1913-01-01

    are treated under the same conditions* Prom our knowledge of the de­ structive distillation of organic substances, the most common of which are coal, wood, bones, peat and lignite, it is reasonable to conclude also that the destructive distillation... the question as to what are the char­ acteristic properties of the two carbon residues 20 obtained from the decomposition of carbonaceous materials, termed coke and charcoal. Some author­ ities use the term coke for the carbon residue from coal and call all...

  8. A termite from the Late Oligocene of northern Ethiopia

    E-Print Network [OSTI]

    Engel, Michael S.; Pan, Aaron D.; Jacobs, Bonnie F.

    2013-01-01

    ? proximately 60 km west of Gondar. The regional geology consists of massive (approximately 2000 m thick) Oligocene trap basalts with interspersed tuffs, lignites, and fluvial volcaniclastic and clastic sediments exposed along streams and gully cuts (Hoff? mann..., typically into the root systems, thereby de? veloping a connection with the soil, necessary for the maintenance of sufficient moisture levels within the colony. The nests them? selves consist of irregular, flattened chambers which either border one another...

  9. Coal deposit characterization by gamma-gamma density/percent dry ash relationships 

    E-Print Network [OSTI]

    Wright, David Scott

    1984-01-01

    provides the capability of filling gaps in the data base which might otherwise result in a misinterpretation of the coal quality throughout the deposit. Geophysi cally-derived in situ coal quality parameters are not currently used as a basis upon which... (Ott, 1984). Tens of thousands of coal core samples analyzed over the past seven years have provided a computerized data base for the formulation of coal parameter interrelationships (Hoeft, et al. , 1983). Alabama lignite and Illinois bituminous...

  10. Economic evaluation of losses to electric power utilities caused by ash fouling. Final technical report, November 1, 1979-April 30, 1980

    SciTech Connect (OSTI)

    Burkhardt, F.R.; Persnger, M.M.

    1980-01-01

    Problems with convection ash fouling and wall slagging were considerable during our study. The Dakota lignites posed the greatest problems, particularly with fouling. The subbituminous coals had considerable problems, related mostly with wall slagging. The Texas lignites had few problems, and those were only associated with wall slagging. The generation losses were as follows: The Dakota lignite burning stations averaged an overall availability of 87.13%. Convection fouling outages were responsible for 57.75% of this outage time for a decrease in availability of 7.43%. Fouling was responsible for curtailment losses of 317,649 Mwh or 8.25% of the remaining available generation. Slagging was responsible for losses of 2732 megawatt hours or .07% of the remaining available generation. Total ash related losses amounted to 16.08% of the total available generation. The subbituminous burning stations averaged an overall availability of 78.36%. Total ash related losses amounted to 1.54% of the total available generation. The Texas lignite burning stations averaged an overall availability of 80.63%. No ash related outage losses occurred. Slagging curtailments accounted 0.08% of the total available generation. Costs due to ash fouling and slagging related curtailments are a tremendous sum. Seven power stations were studied for a six month period to assess costs. The total cost directly attributable to ash slagging and fouling condition was $20,638,113. Recommendations for reducing the problems involve soot blowers, control of furnace gas exit temperature, water blowers and more conservative boiler design.

  11. Experimental studies on the group combustion of coal char particles 

    E-Print Network [OSTI]

    Dahdah, Tarek Farid

    1988-01-01

    Song (1978) performed kinetic studies of char oxidation and char/ NO?reactions. Chars were produced by pyrolyzing lignite coal particles at a temperature of 1750 K for s, residence time of one second. The furnace used con- sisted of a separate main...EXPERIMENTAL STUDIES ON THE GROUP COMBUSTION OF COAL CHAR PARTICLES A Thesis by TAREK FARID DAHDAH Submitted to the Graduate College of Texas ASSAM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May...

  12. Task 3.8 - pressurized fluidized-bed combustion

    SciTech Connect (OSTI)

    NONE

    1995-03-01

    The focus of this work on pressurized fluidized-bed combustion (PFBC) is the development of sorbents for in-bed alkali control. The goal is to generate fundamental process information for development of a second-generation PFBC. Immediate objectives focus on the performance of sulfur sorbents, fate of alkali, and the Resource Conservation and Recovery Act (RCRA) heavy metals. The studies reported here focus on emission control strategies applied in the bed. Data from shakedown testing, alkali sampling, sulfur sorbent performance tests, and refuse-derived fuel (RDF) and lignite combustion tests are presented in detail. Initial results from the characterization of alkali gettering indicate that in-bed getters can remove a significant amount of alkali from the bed. Using kaolin as a sorbent, sodium levels in the flue gas were reduced from 3.6 ppm to less than 0.22 ppm. Sulfur was also reduced by 60% using the kaolin sorbent. Preliminary sulfur sorbent testing, which was designed to develop a reliable technique to predice sorbent performance, indicate that although the total sulfur capture is significantly lower than that observed in a full-scale PFBC, the emission trends are similar. RDF and RDF-lignite fuels had combustion efficiencies exceeding 99.0% in all test cases. Sulfur dioxide emission was significantly lower for the RDF fuels than for lignite fuel alone. Nitrogen oxide emission was also lower for the RDF-based fuels than for the lignite fuel. Both emission gases were well below current regulatory limits. Carbon monoxide and hydrocarbon emissions appeared to be slightly higher for the fuels containing RDF, but were below 9 ppm for the worst case. Analysis of volatile organic compound emission does not indicate an emission problem for these fuels. Chromium appears to be the only RCRA metal that might present some disposal problem; however, processing of the RDF with the wet resource recovery method should reduce chromium levels. 2 refs., 13 figs., 15 tabs.

  13. Latest status of the Rheinbraun High-Temperature Winkler (HTW) process

    SciTech Connect (OSTI)

    Teggers, H.; Theis, K.A.; Tonnesmann, A.; Fabianek, G.

    1981-01-01

    In 1981, the Rheinische Braunkohlenwerke AG (Rheinbraun) started constructing the first commercial-scale plant applying the High-Temperature Winkler (HTW) Process in the Federal Republic of Germany, at the site of Rheinbraun's Ville plant (Hurth-Berrenrath). This demonstration plant represents the consequent continuation of the company's R and D efforts regarding development and testing of new lignite gasification and liquefaction processes up to industrial-scale operational maturity. Rhenish lignite is particularly suited for conversion purposes due to its favourable mining conditions and high reactivity. In addition to further developing the Winkler process, up to the so-called High-Temperature Winkler (HTW) process for the production of synthesis gases rich in CO and H/sub 2/, a second gassification process based on the fluidized-bed principle, the lignite hydrogasification process (HUV) for the production of SNG is being developed. Operational result of a small-scale test plant are presented and the HTW process of SNG production for methanol production is described.

  14. An efficient process for recovery of fine coal from tailings of coal washing plants

    SciTech Connect (OSTI)

    Cicek, T.; Cocen, I.; Engin, V.T.; Cengizler, H. [Dokuz Eylul University, Izmir (Turkey). Dept. for Mining Engineering

    2008-07-01

    Gravity concentration of hard lignites using conventional jigs and heavy media separation equipment is prone to produce coal-rich fine tailings. This study aims to establish a fine coal recovery process of very high efficiency at reasonable capital investment and operational costs. The technical feasibility to upgrade the properties of the predeslimed fine refuse of a lignite washing plant with 35.9% ash content was investigated by employing gravity separation methods. The laboratory tests carried out with the combination of shaking table and Mozley multi-gravity separator (MGS) revealed that the clean coal with 18% ash content on dry basis could be obtained with 58.9% clean coal recovery by the shaking table stage and 4.1% clean coal recovery by MGS stage, totaling to the sum of 63.0% clean coal recovery from a predeslimed feed. The combustible recovery and the organic efficiency of the shaking table + MGS combination were 79.5% and 95.5%, respectively. Based on the results of the study, a flow sheet of a high-efficiency fine coal recovery process was proposed, which is also applicable to the coal refuse pond slurry of a lignite washing plant.

  15. Novel Sorbent-Based Process for High Temperature Trace Metal Removal

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2008-09-30

    The objective of this project was to demonstrate the efficacy of a novel sorbent can effectively remove trace metal contaminants (Hg, As, Se and Cd) from actual coal-derived synthesis gas streams at high temperature (above the dew point of the gas). The performance of TDA's sorbent has been evaluated in several field demonstrations using synthesis gas generated by laboratory and pilot-scale coal gasifiers in a state-of-the-art test skid that houses the absorbent and all auxiliary equipment for monitoring and data logging of critical operating parameters. The test skid was originally designed to treat 10,000 SCFH gas at 250 psig and 350 C, however, because of the limited gas handling capabilities of the test sites, the capacity was downsized to 500 SCFH gas flow. As part of the test program, we carried out four demonstrations at two different sites using the synthesis gas generated by the gasification of various lignites and a bituminous coal. Two of these tests were conducted at the Power Systems Demonstration Facility (PSDF) in Wilsonville, Alabama; a Falkirk (North Dakota) lignite and a high sodium lignite (the PSDF operator Southern Company did not disclose the source of this lignite) were used as the feedstock. We also carried out two other demonstrations in collaboration with the University of North Dakota Energy Environmental Research Center (UNDEERC) using synthesis gas slipstreams generated by the gasification of Sufco (Utah) bituminous coal and Oak Hills (Texas) lignite. In the PSDF tests, we showed successful operation of the test system at the conditions of interest and showed the efficacy of sorbent in removing the mercury from synthesis gas. In Test Campaign No.1, TDA sorbent reduced Hg concentration of the synthesis gas to less than 5 {micro}g/m{sup 3} and achieved over 99% Hg removal efficiency for the entire test duration. Unfortunately, due to the relatively low concentration of the trace metals in the lignite feed and as a result of the intermittent operation of the PSDF gasifier (due to the difficulties in the handling of the low quality lignite), only a small fraction of the sorbent capacity was utilized (we measured a mercury capacity of 3.27 mg/kg, which is only a fraction of the 680 mg/kg Hg capacity measured for the same sorbent used at our bench-scale evaluations at TDA). Post reaction examination of the sorbent by chemical analysis also indicated some removal As and Se (we did not detect any significant amounts of Cd in the synthesis gas or over the sorbent). The tests at UNDEERC was more successful and showed clearly that the TDA sorbent can effectively remove Hg and other trace metals (As and Se) at high temperature. The on-line gas measurements carried out by TDA and UNDEERC separately showed that TDA sorbent can achieve greater than 95% Hg removal efficiency at 260 C ({approx}200g sorbent treated more than 15,000 SCF synthesis gas). Chemical analysis conducted following the tests also showed modest amounts of As and Se accumulation in the sorbent bed (the test durations were still short to show higher capacities to these contaminants). We also evaluated the stability of the sorbent and the fate of mercury (the most volatile and unstable of the trace metal compounds). The Synthetic Ground Water Leaching Procedure Test carried out by an independent environmental laboratory showed that the mercury will remain on the sorbent once the sorbent is disposed. Based on a preliminary engineering and cost analysis, TDA estimated the cost of mercury removal from coal-derived synthesis gas as $2,995/lb (this analysis assumes that this cost also includes the cost of removal of all other trace metal contaminants). The projected cost will result in a small increase (less than 1%) in the cost of energy.

  16. Task 4.0 -- Advanced fuel forms and co-products. Semi-Annual report, April 1--June 30, 1993

    SciTech Connect (OSTI)

    Anderson, C.M.; Musich, M.A.; Young, B.C.; Timpe, R.C.; Olson, E.S.; Sharma, R.K.

    1993-07-01

    Summarized below is the work carried out over a six-month period on the subtasks Beneficiation for Advanced Systems, Co-Products, and Low-Rank Coal Liquefaction. Hydrothermal drying (hot-water drying and saturated-steam drying) was determined to be an effective method of causing a permanent reduction in the equilibrium moisture of low-rank coals and removing sodium. The development of improved methods is continuing for assessing the propensity of coals to dust generation. Carbonic acid treatment of lignites and subbituminous coals reduced the sodium contents of these coals by 60 to 70 wt%. Float/sink washability testing of low-sulfur subbituminous coals produced ash reductions of 30 to 40 wt% at +95 wt% moisture and ash-free (maf) coal recovery. Ineffective agglomerants were induced to agglomerate low-rank coals by mixing with a polar oil or polar alcohol. Effective agglomeration promoters were crude phenol, m-cresol, cresylic acid, methanol, ethanol, propanol, and butanol. Three coals, a North Dakota Lignite, a North Dakota Leonardite, and an Alaskan subbituminous coal, were pyrolyzed. Proximate analysis showed that the subbituminous char was typically lower in volatiles than the lignite. Adsorption of sulfur dioxide by the chars were indistinguishable from one another. Coal can be effectively solubilized by treatment with CO reductant in an aqueous solvent (CO steam process). In this report, the catalytic hydrotreatment of the solubilized low-severity products from sodium aluminate-catalyzed and uncatalyzed CO/H{sub 2}O reactions of a Wyodak subbituminous coal are compared. Liquefaction with the Co-Me catalyst gave 68% conversion to heptane solubles for both the sodium aluminate and the uncatalyzed low-severity reaction intermediates.

  17. Reactivity of pulverized coals during combustion catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Gong, Xuzhong; Guo, Zhancheng; Wang, Zhi

    2010-02-15

    Effects of CeO{sub 2} and Fe{sub 2}O{sub 3} on combustion reactivity of several fuels, including three ranks of coals, graphite and anthracite chars, were investigated using thermo-gravimetric analyzer. The results indicated that the combustion reactivity of all the samples except lignite was improved with CeO{sub 2} or Fe{sub 2}O{sub 3} addition. It was interesting to note that the ignition temperatures of anthracite were decreased by 50 C and 53 C, respectively, with CeO{sub 2} and Fe{sub 2}O{sub 3} addition and that its combustion rates were increased to 15.4%/min and 12.2%/min. Ignition temperatures of lignite with CeO{sub 2} and Fe{sub 2}O{sub 3} addition were 250 C and 226 C, and the combustion rates were 12.8% and 19.3%/min, respectively. When compared with those of lignite without catalysts, no obvious catalytic effects of the two catalysts on its combustion reactivity were revealed. The results from the combustion of the three rank pulverized coals catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3} indicated significant effects of the two catalysts on fixed carbon combustion. And it was found that the higher the fuel rank, the better the catalytic effect. The results of combustion from two kinds of anthracite chars showed obvious effects of anthracite pyrolysis catalyzed by CeO{sub 2} and Fe{sub 2}O{sub 3} on its combustion reactivity. (author)

  18. EERC pilot-scale CFBC evaluation facility Project CFB test results. Topical report, Task 7.30

    SciTech Connect (OSTI)

    Mann, M.D.; Hajicek, D.R.; Henderson, A.K.; Moe, T.A.

    1992-09-01

    Project CFB was initiated at the University of North Dakota Energy and Environmental Research Center (EERC) in May 1988. Specific goals of the project were to (1) construct a circulating fluidized-bed combustor (CFBC) facility representative of the major boiler vendors` designs with the capability of producing scalable data, (2) develop a database for use in making future evaluations of CFBC technology, and (3) provide a facility for evaluating fuels, free of vendor bias for use in the - energy industry. Five coals were test-burned in the 1-MWth unit: North Dakota and Asian lignites, a Wyoming subbituminous, and Colorado and Pennsylvania bituminous coats. A total of 54 steady-state test periods were conducted, with the key test parameters being the average combustor temperature, excess air, superficial gas velocity, calcium-to-sulfur molar ratio, and the primary air-to-secondary air split. The capture for a coal fired in a CFBC is primarily dependent upon the total alkali-to-sulfur ratio. The required alkali-to ratio for 90% sulfur retention ranged from 1.4 to 4.9, depending upon coal type. While an alkali-to-ratio of 4.9 was required to meet 90% sulfur retention for the Salt Creek coal versus 1.4 for the Asian lignite, the total amount of sorbent addition required is much less for the Salt Creek coal, 4.2 pound sorbent per million Btu coal input, versus 62 pound/million Btu for the Asian lignite. The bituminous coals tested show optimal capture at combustor temperatures of approximately 1550{degree}F, with low-rank coals having optimal sulfur capture approximately 100{degree}F lower.

  19. EERC pilot-scale CFBC evaluation facility Project CFB test results

    SciTech Connect (OSTI)

    Mann, M.D.; Hajicek, D.R.; Henderson, A.K.; Moe, T.A.

    1992-09-01

    Project CFB was initiated at the University of North Dakota Energy and Environmental Research Center (EERC) in May 1988. Specific goals of the project were to (1) construct a circulating fluidized-bed combustor (CFBC) facility representative of the major boiler vendors' designs with the capability of producing scalable data, (2) develop a database for use in making future evaluations of CFBC technology, and (3) provide a facility for evaluating fuels, free of vendor bias for use in the - energy industry. Five coals were test-burned in the 1-MWth unit: North Dakota and Asian lignites, a Wyoming subbituminous, and Colorado and Pennsylvania bituminous coats. A total of 54 steady-state test periods were conducted, with the key test parameters being the average combustor temperature, excess air, superficial gas velocity, calcium-to-sulfur molar ratio, and the primary air-to-secondary air split. The capture for a coal fired in a CFBC is primarily dependent upon the total alkali-to-sulfur ratio. The required alkali-to ratio for 90% sulfur retention ranged from 1.4 to 4.9, depending upon coal type. While an alkali-to-ratio of 4.9 was required to meet 90% sulfur retention for the Salt Creek coal versus 1.4 for the Asian lignite, the total amount of sorbent addition required is much less for the Salt Creek coal, 4.2 pound sorbent per million Btu coal input, versus 62 pound/million Btu for the Asian lignite. The bituminous coals tested show optimal capture at combustor temperatures of approximately 1550[degree]F, with low-rank coals having optimal sulfur capture approximately 100[degree]F lower.

  20. Energy and environmental research emphasizing low-rank coal: Task 5.7, Coal char fuel evaporation canister sorbent

    SciTech Connect (OSTI)

    Aulich, T.R.; Grisanti, A.A.; Knudson, C.L.

    1995-08-01

    Atomobile evaporative emission canisters contain activated carbon sorbents that trap and store fuel vapors emitted from automobile fuel tanks during periods of hot ambient temperatures and after engine operation. When a vehicle is started, combustion air is pulled through the canister, and adsorbed vapors are removed from the sorbent and routed to the intake manifold for combustion along with fuel from the tank. The two primary requirements of an effective canister sorbent are that (1) it must be a strong enough adsorbent to hold on to the fuel vapors that contact it and (2) it must be a weak enough adsorbent to release the captured vapors in the presence of the airflow required by the engine for fuel combustion. Most currently available commercial canister sorbents are made from wood, which is reacted with phosphoric acid and heat to yield an activated carbon with optimum pore size for gasoline vapor adsorption. The objectives of Task 5.7 were to (1) design and construct a test system for evaluating the performance of different sorbents in trapping and releasing butane, gasoline, and other organic vapors; (2) investigate the use of lignite char as an automobile fuel evaporation canister sorbent; (3) compare the adsorbing and desorbing characteristics of lignite chars with those of several commercial sorbents; and (4) investigate whether the presence of ethanol in fuel vapors affects sorbent performance in any way. Tests with two different sorbents (a wood-derived activated carbon and a lignite char) showed that with both sorbents, ethanol vapor breakthrough took about twice as long as hydrocarbon vapor breakthrough. Possible reasons for this, including an increased sorbent affinity for ethanol vapors, will be investigated. If this effect is real (i.e., reproducible over an extensive series of tests under varying conditions), it may help explain why ethanol vapor concentrations in SHED test evaporative emissions are often lower than would be expected.

  1. Mercury emission control for coal fired power plants using coal and biomass 

    E-Print Network [OSTI]

    Arcot Vijayasarathy, Udayasarathy

    2009-05-15

    + Oxidized Mercury HgP Particulate Mercury HgCl2 Mercuric chloride HCl Hydrogen chloride Sep. Sol. Separated Solids HA High Ash PC Partially Composted DB Dairy Biomass TXL Texas Lignite Coal WYC Wyoming Subbituminous Coal HHV Higher Heating.... ? Oxidized mercury (Hg2+) ? normally exist in gas phase, and can be captured by wet FGD type of units, since they are highly soluble in water. ? Mercury in particulate form (HgP) ? exist in solid phase and can be easily captured at traditional particulate...

  2. Analysis of the densification of reclaimed surface mined land 

    E-Print Network [OSTI]

    Schneider, William Joseph

    1977-01-01

    exposed channel showing seepage into the pit. Striations are due to the dragline and are not large crossbeds. The scale bar is 20 ft. 27 18 Plasticity index, I ? liquid limit, w , relation- ship for the analyzed soils. The relationship of these two... (arrow) of the northern channel and the lignite. For scale, the picture is about 8 ft wide. FIGURE 17. Minor exposed channel showing seepage into the pit. Striations are due to the dragline and are not large crossbeds. The scale bar is 20 ft. 28...

  3. The iron nutrition of tropical foliage plants 

    E-Print Network [OSTI]

    Lang, Harvey Joe

    1986-01-01

    concentrations than green leaves, but the chlorotic leaves also had highez P concentrations. DeKock and Strmecki (45), studying the growth- promoting effect of a lignite, noted the significance of P in comparison with Fe. They found that in mustard a high P/Fe.... This hypothesis was supported by work by DeKock et al. (46) in which a very significant linear relationship was found between the active Fe fraction and the ratio of total P to total Fe. These relationships give meaningful differences between chlorotic...

  4. The biostratigraphy, palaeoecology and geochemistry of a long lacustrine sequence from NW Greece

    E-Print Network [OSTI]

    Frogley, Michael Reginald

    excursion 92 504.11 Big Lost excursion 92 5.5 Amino Acid Epimerization Data 93 5.6 Uranium-Series Dating 95 5.7 Tephra 97 5.8 Summary and Proposed Age Model 99 FAUNAL BIOSTRATIGRAPHY AND MODERN ASSEMBLAGES 6.1 Introduction 6 .2 Aquatic Molluscan... 1980s, the Institute of Geology and Mineral Exploration (IGME) investigated the Ioannina basin for commercially exploitable lignite deposits. Other basins in the Pindus had previously yielded economically viable deposits and the Ioannina basin...

  5. MTCI advanced coal technologies

    SciTech Connect (OSTI)

    Mansour, M.N.; Chandran, R.R. [Manufacturing and Technology Conversion International, Inc., Columbia, MD (United States)

    1994-12-31

    MTCI is pursuing the development and commercialization of several advanced combustion and gasification systems based on pulse combustion technology. The systems include indirectly heated thermochemical reactor, atmospheric pressure pulse combustor, pulsed atmospheric fluidized bed combustor, direct coal-fired gas turbine pulse combustor island, and advanced concept second-generation pressurized fluidized bed combustor island. Although the systems in toto are capable of processing lignite, subbituminous, bituminous, and anthracite coals in an efficient, economical and environmentally acceptable manner, each system is considered ideal for certain coal types. Brief descriptions of the systems, applications, selected test results and technology status are presented.

  6. A field evaluation of the movement of selected metals in revegetated strip mine overburden and laboratory assessment of transport mechanisms 

    E-Print Network [OSTI]

    Launius, Kenneth Wayne

    1980-01-01

    placement of materials following the excavation and sampling of lignite at a test pit. The effect of varying ratios of lime and gypsum had on revegetation were studied. Resultant overburden'pH and electrical conductivity (EC) wire evaluated... and gypsum have on pH, electr 1cal conductiv1ty (EC) and bermudagrass yield, Lime requirement ( LR) was determ1ned on a sample of the overburden from the test pit. One, 2, 4, 8, j6 and 32 meq of reagent grade CaCO, were mixed wi th 1ndividual IOD g...

  7. Physical Plant Power Plant - 43 

    E-Print Network [OSTI]

    Unknown

    2005-06-30

    with higher efficiency / R&D Climate friendly Power Plants Build coal fired Power Plants with CCS-technology 4 B a c k u p va W GGEHEN ESL-IC-08-10-27 Proceedings of the Eighth International Conference for Enhanced Building Operations, Berlin, Germany..., October 20-22, 2008 RWE Energy / Energieeffizienz bei Immobilien / U. K?nig / ICEBO '08 SEITE 9 Electricity Production: All Energy Sources have to be included! Lignite Power Plant (BoA) produces 8,8 TWh = appr. 12% of the annual demand for electricity...

  8. High-pressure gasification of Montana subbituminous coal

    SciTech Connect (OSTI)

    Goyal, A.; Bryan, B.; Rehmat, A.

    1991-01-01

    A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

  9. Catalytic gasification of graphite or carbon. Quarterly report, January 1, 1986-March 31, 1986

    SciTech Connect (OSTI)

    Heinemann, H.

    1986-03-01

    Steam gasification of five chars has been carried out in the presence of a mixture of potassium and nickel oxides as catalyst. The steady state rate of hydrogen production after 60 minutes at 620/sup 0/C is highest for a N. Dakota Husky lignite and is twice as high as the next char, Western Kentucky. The order is N. Dakota > W. Kentucky > Illinois number 6, low temp. > number 6, high temp. > Montana. All chars gasified at a rate at least one order of magnitude greater than graphite.

  10. Supercritical plants to come online in 2009

    SciTech Connect (OSTI)

    Spring, N.

    2009-07-15

    A trio of coal-fired power plants using supercritical technology set to enter service this year. These are: We Energies is Elm Road Generating Station in Wisconsin, a two-unit, 1,230 MW supercritical plant that will burn bituminous coal; a 750 MW supercritical coal-fired power plant at the Comanche Generating Station in Pueblo, Colo., the third unit at the site; and Luminant's Oak Grove plant in Texas which will consist of two supercritical, lignite-fueled power generation units. When complete, the plant will deliver about 1,6000 MW. Some details are given on each of these projects. 2 photos.

  11. Effects of pretreatment of coal by CO{sub 2} on nitric oxide emission and unburned carbon in various combustion environments

    SciTech Connect (OSTI)

    Gathitu, B.B.; Chen, W.Y. [University of Mississippi, University, MS (United States). Dept. of Chemical Engineering

    2009-12-15

    Polar solvents are known to swell coal, break hydrogen bonds in the macromolecular structure, and enhance coal liquefaction efficiencies. The effects of the pretreatment of coal using supercritical CO{sub 2} on its physical structure and combustion properties have been studied at the bench-scale level. Emphasis has been placed on NO reburning, NO emissions during air-fired and oxy-fired combustion, and loss on ignition (LOI). Pretreatment was found to increase porosity and to significantly alter the fuel nitrogen reaction pathways. Consequently, NO reduction during reburning using bituminous coal increased, and NO emissions during oxidation of lignite decreased. These two benefits were achieved without negative impacts on LOI.

  12. The determination of some anions using ion chromatography and ion chromatography-graphite furnace atomic absorption spectrometry 

    E-Print Network [OSTI]

    Hillman, Daniel C

    1981-01-01

    with a fluoride ion selective electrode. The fluorine concentration in the Texas lignite core sample ranged from 50 to 95 ppm F. Ion chromatography alone was shown not to be useful in the deter- mination of selenite and selenate in natural water... Analys1s of Selenite and Selenate . Parameter s for IC-GFAA Analysis of Selen1te and Selenate 10 IV Coeffic1ents of the L1near Least Square Equations for Fluoride Cal1brat1on Curves 1n Figures 3, 4, and 5 (p. 14, 15, 16) Fluorine Determ1nat1on...

  13. Investigation of the combustion characteristics of Zonguldak bituminous coal using DTA and DTG

    SciTech Connect (OSTI)

    Haykiri-Acma, H.; Yaman, S.; Kucukbayrak, S.; Okutan, H. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

    2006-06-21

    Combustion characteristics of coking, semicoking, and noncoking Turkish bituminous coal samples from Zonguldak basin were investigated applying differential thermal analysis (DTA) and differential thermogravimetry (DTG) techniques. Results were compared with that of the coke from Zonguldak bituminous coal, a Turkish lignite sample from Soma, and a Siberian bituminous coal sample. The thermal data from both techniques showed some differences depending on the proximate analyses of the samples. Noncombustible components of the volatile matter led to important changes in thermal behavior. The data front both methods were, evaluated jointly, and some thermal properties were interpreted considering these methods in a complementary combination.

  14. Proceedings of the sixteenth biennial low-rank fuels symposium

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    Low-rank coals represent a major energy resource for the world. The Low-Rank Fuels Symposium, building on the traditions established by the Lignite Symposium, focuses on the key opportunities for this resource. This conference offers a forum for leaders from industry, government, and academia to gather to share current information on the opportunities represented by low-rank coals. In the United States and throughout the world, the utility industry is the primary user of low-rank coals. As such, current experiences and future opportunities for new technologies in this industry were the primary focuses of the symposium.

  15. Process to improve boiler operation by supplemental firing with thermally beneficiated low rank coal

    DOE Patents [OSTI]

    Sheldon, Ray W. (Huntley, MT)

    2001-01-01

    The invention described is a process for improving the performance of a commercial coal or lignite fired boiler system by supplementing its normal coal supply with a controlled quantity of thermally beneficiated low rank coal, (TBLRC). This supplemental TBLRC can be delivered either to the solid fuel mill (pulverizer) or directly to the coal burner feed pipe. Specific benefits are supplied based on knowledge of equipment types that may be employed on a commercial scale to complete the process. The thermally beneficiated low rank coal can be delivered along with regular coal or intermittently with regular coal as the needs require.

  16. Geology of the Shiloh School-Liberty Church area, West Burleson County, Texas 

    E-Print Network [OSTI]

    Foster, Raymond Leon

    1956-01-01

    ~ ~ ~ so ~ ~ see I"e7' Cn44en City foraaticua a~ines lignitic ssn4h4y silva snt elk/S eoeeeeeeeee ' %s Tba fernatiens beeess progressively yeeager te44ard ths sonthaast fros tha Ch4een city fernatien en ths north44sst te the crockett fernatien on Q... iparta contact~ and at the Sparta 'ecljsa const, , ;esistant beds in the Sparta and jIjecj;ss formations form isolated~ rounded hills as outliors on the !aches and, . ueen City formations (Pigur? 16)~ Sose rolling hills aro found on the Sparta...

  17. Turkey opens electricity markets as demand grows

    SciTech Connect (OSTI)

    McKeigue, J.; Da Cunha, A.; Severino, D. [Global Business Reports (United States)

    2009-06-15

    Turkey's growing power market has attracted investors and project developers for over a decade, yet their plans have been dashed by unexpected political or financial crises or, worse, obstructed by a lengthy bureaucratic approval process. Now, with a more transparent retail electricity market, government regulators and investors are bullish on Turkey. Is Turkey ready to turn the power on? This report closely examine Turkey's plans to create a power infrastructure capable of providing the reliable electricity supplies necessary for sustained economic growth. It was compiled with on-the-ground research and extensive interview with key industrial and political figures. Today, hard coal and lignite account for 21% of Turkey's electricity generation and gas-fired plants account for 50%. The Alfin Elbistan-B lignite-fired plant has attracted criticism for its lack of desulfurization units and ash dam facilities that have tarnished the industry's image. A 1,100 MW hard-coal fired plant using supercritical technology is under construction. 9 figs., 1 tab.

  18. Power Systems Development Facility Gasification Test Campaign TC22

    SciTech Connect (OSTI)

    Southern Company Services

    2008-11-01

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC22, the first test campaign using a high moisture lignite from Mississippi as the feedstock in the modified Transport Gasifier configuration. TC22 was conducted from March 24 to April 17, 2007. The gasification process was operated for 543 hours, increasing the total gasification operation at the PSDF to over 10,000 hours. The PSDF gasification process was operated in air-blown mode with a total of about 1,080 tons of coal. Coal feeder operation was challenging due to the high as-received moisture content of the lignite, but adjustments to the feeder operating parameters reduced the frequency of coal feeder trips. Gasifier operation was stable, and carbon conversions as high as 98.9 percent were demonstrated. Operation of the PCD and other support equipment such as the recycle gas compressor and ash removal systems operated reliably.

  19. ADVANCED HETEROGENEOUS REBURN FUEL FROM COAL AND HOG MANURE

    SciTech Connect (OSTI)

    Melanie D. Jensen; Ronald C. Timpe; Jason D. Laumb

    2003-09-01

    This study was performed to investigate whether the nitrogen content inherent in hog manure and alkali used as a catalyst during processing could be combined with coal to produce a reburn fuel that would result in advanced reburning NO{sub x} control without the addition of either alkali or ammonia/urea. Fresh hog manure was processed in a cold-charge, 1-gal, batch autoclave system at 275 C under a reducing atmosphere in the presence of an alkali catalyst. Instead of the expected organic liquid, the resulting product was a waxy solid material. The waxy nature of the material made size reduction and feeding difficult as the material agglomerated and tended to melt, plugging the feeder. The material was eventually broken up and sized manually and a water-cooled feeder was designed and fabricated. Two reburn tests were performed in a pilot-scale combustor. The first test evaluated a reburn fuel mixture comprising lignite and air-dried, raw hog manure. The second test evaluated a reburn fuel mixture made of lignite and the processed hog manure. Neither reburn fuel reduced NO{sub x} levels in the combustor flue gas. Increased slagging and ash deposition were observed during both reburn tests. The material-handling and ash-fouling issues encountered during this study indicate that the use of waste-based reburn fuels could pose practical difficulties in implementation on a larger scale.

  20. Screening of carbon-based sorbents for the removal of elemental mercury from simulated combustion flue gas

    SciTech Connect (OSTI)

    Young, B.C.; Musich, M.A. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31

    A fixed-bed reactor system with continuous Hg{sup 0} analysis capabilities was used to evaluate commercial carbon sorbents for the removal of elemental mercury from simulated flue gas. The objectives of the program were to compare the sorbent effectiveness under identical test conditions and to identify the effects of various flue gas components on elemental mercury sorption. Sorbents tested included steam-activated lignite, chemically activated hardwood, chemically activated bituminous coal, iodated steam-activated coconut shell, and sulfur-impregnated steam-activated bituminous coal. The iodated carbon was the most effective sorbent, showing over 99% mercury removal according to U.S. Environmental Protection Agency (EPA) Method 101A. Data indicate that adding O{sub 2} at 4 vol% reduced the effectiveness of the steam-activated lignite, chemically activated hardwood, and sulfur- impregnated steam-activated bituminous coal. Adding SO{sub 2} at 500 ppm improved the mercury removal of the sulfur-impregnated carbon. Further, the presence of HCl gas (at 50 ppm) produced an order of magnitude increase in mercury removal with the chemically activated and sulfur-impregnated bituminous coal-based carbons.

  1. Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Task 3 Full-scale Test Results

    SciTech Connect (OSTI)

    Gary Blythe

    2007-05-01

    This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, 'Field Testing of a Wet FGD Additive'. The objective of the project is to demonstrate the use of a flue gas desulfurization (FGD) additive, Degussa Corporation's TMT-15, to prevent the reemission of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate whether the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine TMT salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project is conducting pilot- and full-scale tests of the TMT-15 additive in wet FGD absorbers. The tests are intended to determine required additive dosages to prevent Hg{sup 0} reemissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Power River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, TXU Generation Company LP, Southern Company, and Degussa Corporation. TXU Generation has provided the Texas lignite/PRB cofired test site for pilot FGD tests, Monticello Steam Electric Station Unit 3. Southern Company is providing the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot- and full-scale jet bubbling reactor (JBR) FGD systems to be tested. IPL, an AES company, provided the high-sulfur Eastern bituminous coal full-scale FGD test site and cost sharing. Degussa Corporation is providing the TMT-15 additive and technical support to the test program as cost sharing. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management and reporting. The other four tasks involve field testing on FGD systems, either at pilot or full scale. The four tasks include: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High-sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Plant Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. The pilot-scale tests were completed in 2005 and have been previously reported. This topical report presents the results from the Task 3 full-scale additive tests, conducted at IPL's Petersburg Station Unit 2. The Task 5 full-scale additive tests will be conducted later in calendar year 2007.

  2. The fate of alkali species in advanced coal conversion systems

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950[degree]C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800[degree] to 950[degree]C, the concentrations of vapor phase sodium species (Na, Na[sub 2]O, NaCl, and Na[sub 2]SO[sub 4]) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820[degree]. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na[sub 2]SO[sub 4] increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 [mu]m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  3. The fate of alkali species in advanced coal conversion systems. Final report

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950{degree}C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800{degree} to 950{degree}C, the concentrations of vapor phase sodium species (Na, Na{sub 2}O, NaCl, and Na{sub 2}SO{sub 4}) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820{degree}. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na{sub 2}SO{sub 4} increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 {mu}m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  4. Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Pilot-Scale Test Results

    SciTech Connect (OSTI)

    Gary M. Blythe

    2006-03-01

    This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, ''Field Testing of a Wet FGD Additive.'' The objective of the project is to demonstrate the use of a flue gas desulfurization (FGD) additive, Degussa Corporation's TMT-15, to prevent the reemissions of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate that the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine TMT salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project will conduct pilot and full-scale tests of the TMT-15 additive in wet FGD absorbers. The tests are intended to determine required additive dosage requirements to prevent Hg{sup 0} reemissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Power River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, TXU Generation Company LP, Southern Company, and Degussa Corporation. TXU Generation has provided the Texas lignite/PRB co-fired test site for pilot FGD tests, Monticello Steam Electric Station Unit 3. Southern Company is providing the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot and full-scale jet bubbling reactor (JBR) FGD systems to be tested. A third utility, to be named later, will provide the high-sulfur Eastern bituminous coal full-scale FGD test site. Degussa Corporation is providing the TMT-15 additive and technical support to the test program. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management and reporting. The other four tasks involve field testing on FGD systems, either at pilot or full scale. The four tasks include: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High Sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. This topical report presents the results from the Task 2 and Task 4 pilot-scale additive tests. The Task 3 and Task 5 full-scale additive tests will be conducted later in calendar year 2006.

  5. Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia

    SciTech Connect (OSTI)

    Vukasinovic-Pesic, V.; Rajakovic, L.J. [University of Montenegro, Podgorica (Montenegro)

    2009-07-01

    The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn in the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.

  6. Cooperative research in coal liquefaction. Final report, May 1, 1992--April 30, 1993

    SciTech Connect (OSTI)

    Huffman, G.P.

    1996-03-01

    Research on sulfate and metal (Mo, Sn) promoted Fe{sub 2}O{sub 3} catalysts in the current year focused on optimization of conditions. Parameters varied included temperature, solvent, solvent-to-coal ratio, and the effect of presulfiding versus in situ sulfiding. Oil yields were found to increase approximately proportionately with both temperature and solvent-to-coal ratio. The donor solvent, tetralin, proved to give better total conversion and oil yields than either 1-methylnaphthalene or Wilsonville recycle oil. A significant enhancement of both total liquefaction yields and oil yields from lignites and subbituminous coals has been achieved by incorporating iron into the coal matrix by cation exchange. A study has been conducted on the synthesis of iron, molybdenum, and tungsten catalysts using a laser pyrolysis technique.

  7. EA-1616: National Carbon Research Center Project at Southern Company Services' Power Systems Development Facility near Wilsonville, Alabama

    Broader source: Energy.gov [DOE]

    This EA evaluates and updates the potential environmental impacts of DOE’s proposed continued operations of the NCCC Project at the PSDF plant. The NCCC is designed to test and evaluate carbon dioxide (CO2) control technologies for power generation facilities, including CO2 capture solvents and sorbents, mass-transfer devices, lower cost water-gas shift reactors, and scaled-up membrane technologies. Additionally, the NCCC evaluates methods to integrate CO2 capture technologies with other coal-based power plant systems by testing both pre-combustion and post-combustion technologies. The NCCC provides the capability to test these systems under a wide range of fuels, including bituminous and sub-bituminous coals, lignites and biomass/coal mixtures. The goal of the NCCC project is to accelerate the development, optimization, and commercialization of viable CO2 control technologies.

  8. The role of coal in industrialization: A case study of Nigeria

    SciTech Connect (OSTI)

    Akarakiri, J.B. (Obafemi Awolowo Univ., Ile-Ife (Nigeria))

    1989-01-01

    Coal is a mineral matter found in layers or beds in sedimentary rocks. It is a very highly variable substance. In addition to the variations from lignite to bituminous and anthracite, there are vast differences in its heating value, amount of volatiles, sulfur, moisture and so on. The chemical and physical properties of coal make it an important industrial raw material. There is proven 639 million tonnes of coal reserves in Nigeria. This paper examines the potential and current role of coal in the industrialization of Nigeria. Industries are now dependent on fuel oil as a source of fuel because of its economic and technological advantages over coal. Coal is a source of industrial energy for the future after the known oil reserves might have been exhausted. In the short term, coal can be used as a material for chemicals, iron and steel production as well as a substitute for wood energy in the process of industrialization.

  9. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    SciTech Connect (OSTI)

    Michael Swanson; Daniel Laudal

    2008-03-31

    The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

  10. Low-rank coal study: national needs for resource development. Volume 3. Technology evaluation

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    Technologies applicable to the development and use of low-rank coals are analyzed in order to identify specific needs for research, development, and demonstration (RD and D). Major sections of the report address the following technologies: extraction; transportation; preparation, handling and storage; conventional combustion and environmental control technology; gasification; liquefaction; and pyrolysis. Each of these sections contains an introduction and summary of the key issues with regard to subbituminous coal and lignite; description of all relevant technology, both existing and under development; a description of related environmental control technology; an evaluation of the effects of low-rank coal properties on the technology; and summaries of current commercial status of the technology and/or current RD and D projects relevant to low-rank coals.

  11. Center for Renewable Energy Science and Technology

    SciTech Connect (OSTI)

    Billo, Richard; Rajeshwar, Krishnan

    2013-01-15

    The CREST research team conducted research that optimized catalysts used for the conversion of southwestern lignite into synthetic crude oil that can be shipped to nearby Texas refineries and power plants for development of transportation fuels and power generation. Research was also undertaken to convert any potential by-products of this process such as CO2 to useful chemicals and gases which could be recycled and used as feedstock to the synthetic fuel process. These CO2 conversion processes used light energy to drive the endogonic reduction reactions involved. The project was divided into two tasks: A CO2 Conversion Task, and a Catalyst Optimization Task. The CO2 Conversion task was aimed at developing molecular and solid state catalysts for the thermal, electro- and photocatalytic reduction of CO2 to reduced products such as simple feedstock compounds (e.g. CO, H2, CHOOH, CH2O, CH3OH and CH4). For example, the research team recycled CO that was developed from this Task and used it as a feedstock for the production of synthetic crude in the Catalyst Optimization Task. In the Catalyst Optimization Task, the research team conducted bench-scale experiments with the goal of reducing overall catalyst cost in support of several synthetic crude processes that had earlier been developed. This was accomplished by increasing the catalyst reactivity thus reducing required concentrations or by using less expensive metals. In this task the team performed parametric experiments in small scale batch reactors in an effort to improve catalyst reactivity and to lower cost. They also investigated catalyst robustness by testing lignite feedstocks that vary in moisture, h, and volatile content.

  12. Flash hydropyrolysis of coal. Quarterly report No. 11, October 1-December 31, 1979

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.; Bhatt, B.L.

    1980-02-01

    The following conclusions can be drawn from this work: (1) when the caking bituminous coals are used with diluents, only 20% Pittsburgh No. 8 coal can be added to the diluent swhile 40% Illinois No. 6 could be added due to the higher free swelling index of the Pittsburgh No. 8; (2) When limestone is used as a diluent, considerably more sulfur is retained in the char than when using sand; (3) when the char from an experiment using limestone is recycled as the diluent for another experiment, the char continually retains additional sulfur through at least three recycles; (4) decomposition of the limestone and reduction is indicated by the high concentrations of CO observed at 900/sup 0/C; (5) increasing the coal feed rate by a factor of 4 from 2.4 to 10.7 lb/hr at low H/sub 2//Coal ratios (approx. = 0.6) results in no appreciable change in gaseous HC yields (approx. = 27%) or concentration (approx. = 45%) but higher BTX yields (1.1% vs. 5.4%); (6) although only one experiment was conducted, it appears that hydrogasification of untreated New Mexico sub-bituminous coal at 950/sup 0/C does not give an increase in yield over hydrogasification at 900/sup 0/C; (7) the hydrogasification of Wyodak lignite gives approximately the same gaseous HC yields as that obtained from North Dakota lignite but higher BTX yields particularly at 900/sup 0/C and 1000 psi (9% vs. 2%); (8) treating New Mexico sub-bituminous coal with NaCO/sub 3/ does not increase its hydrogasification qualities between 600/sup 0/C and 900/sup 0/C at 1000 psi but does decrease the BTX yield.

  13. Research and development of rapid hydrogenation for coal conversion to synthetic motor fuels (riser cracking of coal). Final report, April 1, 1976-September 30, 1980

    SciTech Connect (OSTI)

    Duncan, D. A.; Beeson, J. L.; Oberle, R. D.

    1981-02-01

    The objective of the program described was to develop a noncatalytic process for the hydropyrolysis of lignite and coal to produce high-octane blending gasoline constituents, methane, ethane, and carbon oxides. The process would operate in a balanced plant mode, using spent char to generate process hydrogen by steam-oxygen gasification. The technical program included the construction and operating of a bench-scale unit (5-10 lb/hr), the design, construction, and operation of a process development unit (PDU) (100 lb/hr), and a final technical and economic assessment of the process, called Riser Cracking of Coal. In the bench-scale unit program, 143 runs were made investigating the effects of pressure, temperature, heating rate, residence time, and particle size, processing North Dakota lignite in hydrogen. Some runs were made in which the hydrogen was preheated to pyrolysis temperatures prior to contact with the coal, and, also, in which steam was substituted for half of the hydrogen. Attempts to operate the bench-scale unit at 1200 psig and 1475/sup 0/F were not successful. Depth of carbon conversion was found to be influenced by hydrogen pressure, hydrogen-to-coal ratio, and the severity of the thermal treatment. The composition of hydrocarbon liquids produced was found to change with severity. At low severity, the liquids contained sizable fractions of phenols and cresols. At high severity, the fraction of phenols and cresols was much reduced, with an attendant increase in BTX. In operating the PDU, it was necessary to use more oxygen than was planned to achieve pyrolysis temperatures because of heat losses, and portions of hydrocarbon products were lost through combustion with a large increase in carbon oxide yields. Economic studies, however, showed that selling prices for gasoline blending stock, fuel oil, and fuel gas are competitive in current markets, so that the process is held to warrant further development.

  14. Co-pyrolysis of low rank coals and biomass: Product distributions

    SciTech Connect (OSTI)

    Soncini, Ryan M.; Means, Nicholas C.; Weiland, Nathan T.

    2013-10-01

    Pyrolysis and gasification of combined low rank coal and biomass feeds are the subject of much study in an effort to mitigate the production of green house gases from integrated gasification combined cycle (IGCC) systems. While co-feeding has the potential to reduce the net carbon footprint of commercial gasification operations, the effects of co-feeding on kinetics and product distributions requires study to ensure the success of this strategy. Southern yellow pine was pyrolyzed in a semi-batch type drop tube reactor with either Powder River Basin sub-bituminous coal or Mississippi lignite at several temperatures and feed ratios. Product gas composition of expected primary constituents (CO, CO{sub 2}, CH{sub 4}, H{sub 2}, H{sub 2}O, and C{sub 2}H{sub 4}) was determined by in-situ mass spectrometry while minor gaseous constituents were determined using a GC-MS. Product distributions are fit to linear functions of temperature, and quadratic functions of biomass fraction, for use in computational co-pyrolysis simulations. The results are shown to yield significant nonlinearities, particularly at higher temperatures and for lower ranked coals. The co-pyrolysis product distributions evolve more tar, and less char, CH{sub 4}, and C{sub 2}H{sub 4}, than an additive pyrolysis process would suggest. For lignite co-pyrolysis, CO and H{sub 2} production are also reduced. The data suggests that evolution of hydrogen from rapid pyrolysis of biomass prevents the crosslinking of fragmented aromatic structures during coal pyrolysis to produce tar, rather than secondary char and light gases. Finally, it is shown that, for the two coal types tested, co-pyrolysis synergies are more significant as coal rank decreases, likely because the initial structure in these coals contains larger pores and smaller clusters of aromatic structures which are more readily retained as tar in rapid co-pyrolysis.

  15. Degradation of Thermal Barrier Coatings from Deposits and Its Mitigation

    SciTech Connect (OSTI)

    Nitin Padture

    2011-12-31

    Ceramic thermal barrier coatings (TBCs) used in gas-turbine engines afford higher operating temperatures, resulting in enhanced efficiencies and performance. However, in the case of syngas-fired engines, fly ash particulate impurities that may be present in syngas can melt on the hotter TBC surfaces and form glassy deposits. These deposits can penetrate the TBCs leading to their failure. In experiments using lignite fly ash to simulate these conditions we show that conventional TBCs of composition 93wt% ZrO{sub 2} + 7wt% Y{sub 2}O{sub 3} (7YSZ) fabricated using the air plasma spray (APS) process are completely destroyed by the molten fly ash. The molten fly ash is found to penetrate the full thickness of the TBC. The mechanisms by which this occurs appear to be similar to those observed in degradation of 7YSZ TBCs by molten calcium-magnesium-aluminosilicate (CMAS) sand and by molten volcanic ash in aircraft engines. In contrast, APS TBCs of Gd{sub 2Zr{sub 2}O{sub 7} composition are highly resistant to attack by molten lignite fly ash under identical conditions, where the molten ash penetrates ~25% of TBC thickness. This damage mitigation appears to be due to the formation of an impervious, stable crystalline layer at the fly ash/Gd{sub 2}Zr{sub 2}O{sub 7} TBC interface arresting the penetrating moltenfly- ash front. Additionally, these TBCs were tested using a rig with thermal gradient and simultaneous accumulation of ash. Modeling using an established mechanics model has been performed to illustrate the modes of delamination, as well as further opportunities to optimize coating microstructure. Transfer of the technology was developed in this program to all interested parties.

  16. Field Testing of a Wet FGD Additive for Enhanced Mercury Control

    SciTech Connect (OSTI)

    Gary Blythe; MariJon Owens

    2007-12-31

    This document is the final report for DOE-NETL Cooperative Agreement DE-FC26-04NT42309, 'Field Testing of a Wet FGD Additive'. The objective of the project has been to demonstrate the use of two flue gas desulfurization (FGD) additives, Evonik Degussa Corporation's TMT-15 and Nalco Company's Nalco 8034, to prevent the re-emission of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project was intended to demonstrate whether such additives can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project involved pilot- and full-scale tests of the additives in wet FGD absorbers. The tests were intended to determine required additive dosages to prevent Hg{sup 0} re-emissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Powder River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, Luminant Power (was TXU Generation Company LP), Southern Company, IPL (an AES company), Evonik Degussa Corporation and the Nalco Company. Luminant Power provided the Texas lignite/PRB co-fired test site for pilot FGD tests and project cost sharing. Southern Company provided the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, the pilot- and full-scale jet bubbling reactor (JBR) FGD systems tested, and project cost sharing. IPL provided the high-sulfur Eastern bituminous coal full-scale FGD test site and cost sharing. Evonik Degussa Corporation provided the TMT-15 additive, and the Nalco Company provided the Nalco 8034 additive. Both companies also supplied technical support to the test program as in-kind cost sharing. The project was conducted in six tasks. Of the six tasks, Task 1 involved project planning and Task 6 involved management and reporting. The other four tasks involved field testing on FGD systems, either at pilot or full scale. These four tasks included: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High-sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Plant Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. The pilot-scale tests were completed in 2005 and the full-scale test using high-sulfur coal was completed in 2006; only the TMT-15 additive was tested in these efforts. The Task 5 full-scale additive tests conducted at Southern Company's Plant Yates Unit 1 were completed in 2007, and both the TMT-15 and Nalco 8034 additives were tested.

  17. Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Task 5 Full-Scale Test Results

    SciTech Connect (OSTI)

    Gary Blythe; MariJon Owens

    2007-12-01

    This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, 'Field Testing of a Wet FGD Additive'. The objective of the project is to demonstrate the use of two flue gas desulfurization (FGD) additives, Evonik Degussa Corporation's TMT-15 and Nalco Company's Nalco 8034, to prevent the re-emission of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate whether the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project is conducting pilot- and full-scale tests of the additives in wet FGD absorbers. The tests are intended to determine required additive dosages to prevent Hg{sup 0} re-emissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Powder River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, Luminant Power (was TXU Generation Company LP), Southern Company, IPL (an AES company), Evonik Degussa Corporation and the Nalco Company. Luminant Power has provided the Texas lignite/PRB co-fired test site for pilot FGD tests and cost sharing. Southern Company has provided the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot- and full-scale jet bubbling reactor (JBR) FGD systems tested. IPL provided the high-sulfur Eastern bituminous coal full-scale FGD test site and cost sharing. Evonik Degussa Corporation is providing the TMT-15 additive, and the Nalco Company is providing the Nalco 8034 additive. Both companies are also supplying technical support to the test program as in-kind cost sharing. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management and reporting. The other four tasks involve field testing on FGD systems, either at pilot or full scale. The four tasks include: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High-sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Plant Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. The pilot-scale tests and the full-scale test using high-sulfur coal were completed in 2005 and 2006 and have been previously reported. This topical report presents the results from the Task 5 full-scale additive tests, conducted at Southern Company's Plant Yates Unit 1. Both additives were tested there.

  18. Gasification Plant Cost and Performance Optimization

    SciTech Connect (OSTI)

    Samuel Tam; Alan Nizamoff; Sheldon Kramer; Scott Olson; Francis Lau; Mike Roberts; David Stopek; Robert Zabransky; Jeffrey Hoffmann; Erik Shuster; Nelson Zhan

    2005-05-01

    As part of an ongoing effort of the U.S. Department of Energy (DOE) to investigate the feasibility of gasification on a broader level, Nexant, Inc. was contracted to perform a comprehensive study to provide a set of gasification alternatives for consideration by the DOE. Nexant completed the first two tasks (Tasks 1 and 2) of the ''Gasification Plant Cost and Performance Optimization Study'' for the DOE's National Energy Technology Laboratory (NETL) in 2003. These tasks evaluated the use of the E-GAS{trademark} gasification technology (now owned by ConocoPhillips) for the production of power either alone or with polygeneration of industrial grade steam, fuel gas, hydrocarbon liquids, or hydrogen. NETL expanded this effort in Task 3 to evaluate Gas Technology Institute's (GTI) fluidized bed U-GAS{reg_sign} gasifier. The Task 3 study had three main objectives. The first was to examine the application of the gasifier at an industrial application in upstate New York using a Southeastern Ohio coal. The second was to investigate the GTI gasifier in a stand-alone lignite-fueled IGCC power plant application, sited in North Dakota. The final goal was to train NETL personnel in the methods of process design and systems analysis. These objectives were divided into five subtasks. Subtasks 3.2 through 3.4 covered the technical analyses for the different design cases. Subtask 3.1 covered management activities, and Subtask 3.5 covered reporting. Conceptual designs were developed for several coal gasification facilities based on the fluidized bed U-GAS{reg_sign} gasifier. Subtask 3.2 developed two base case designs for industrial combined heat and power facilities using Southeastern Ohio coal that will be located at an upstate New York location. One base case design used an air-blown gasifier, and the other used an oxygen-blown gasifier in order to evaluate their relative economics. Subtask 3.3 developed an advanced design for an air-blown gasification combined heat and power facility based on the Subtask 3.2 design. The air-blown case was chosen since it was less costly and had a better return on investment than the oxygen-blown gasifier case. Under appropriate conditions, this study showed a combined heat and power air-blown gasification facility could be an attractive option for upgrading or expanding the utilities area of industrial facilities. Subtask 3.4 developed a base case design for a large lignite-fueled IGCC power plant that uses the advanced GE 7FB combustion turbine to be located at a generic North Dakota site. This plant uses low-level waste heat to dry the lignite that otherwise would be rejected to the atmosphere. Although this base case plant design is economically attractive, further enhancements should be investigated. Furthermore, since this is an oxygen-blown facility, it has the potential for capture and sequestration of CO{sub 2}. The third objective for Task 3 was accomplished by having NETL personnel working closely with Nexant and Gas Technology Institute personnel during execution of this project. Technology development will be the key to the long-term commercialization of gasification technologies. This will be important to the integration of this environmentally superior solid fuel technology into the existing mix of power plants and industrial facilities. As a result of this study, several areas have been identified in which research and development will further advance gasification technology. Such areas include improved system availability, development of warm-gas clean up technologies, and improved subsystem designs.

  19. Coal Direct Chemical Looping Retrofit to Pulverized Coal Power Plants for In-Situ CO2 Capture

    SciTech Connect (OSTI)

    Zeng, Liang; Li, Fanxing; Kim, Ray; Bayham, Samuel; McGiveron, Omar; Tong, Andrew; Connell, Daniel; Luo, Siwei; Sridhar, Deepak; Wang, Fei; Sun, Zhenchao; Fan, Liang-Shih

    2013-09-30

    A novel Coal Direct Chemical Looping (CDCL) system is proposed to effectively capture CO2 from existing PC power plants. The work during the past three years has led to an oxygen carrier particle with satisfactory performance. Moreover, successful laboratory, bench scale, and integrated demonstrations have been performed. The proposed project further advanced the novel CDCL technology to sub-pilot scale (25 kWth). To be more specific, the following objectives attained in the proposed project are: 1. to further improve the oxygen carrying capacity as well as the sulfur/ash tolerance of the current (working) particle; 2. to demonstrate continuous CDCL operations in an integrated mode with > 99% coal (bituminous, subbituminous, and lignite) conversion as well as the production of high temperature exhaust gas stream that is suitable for steam generation in existing PC boilers; 3. to identify, via demonstrations, the fate of sulfur and NOx; 4. to conduct thorough techno-economic analysis that validates the technical and economical attractiveness of the CDCL system. The objectives outlined above were achieved through collaborative efforts among all the participants. CONSOL Energy Inc. performed the techno-economic analysis of the CDCL process. Shell/CRI was able to perform feasibility and economic studies on the large scale particle synthesis and provide composite particles for the sub-pilot scale testing. The experience of B&W (with boilers) and Air Products (with handling gases) assisted the retrofit system design as well as the demonstration unit operations. The experience gained from the sub-pilot scale demonstration of the Syngas Chemical Looping (SCL) process at OSU was able to ensure the successful handling of the solids. Phase 1 focused on studies to improve the current particle to better suit the CDCL operations. The optimum operating conditions for the reducer reactor such as the temperature, char gasification enhancer type, and flow rate were identified. The modifications of the existing bench scale reactor were completed in order to use it in the next phase of the project. In Phase II, the optimum looping medium was selected, and bench scale demonstrations were completed using them. Different types of coal char such as those obtained from bituminous, subbituminous, and lignite were tested. Modifications were made on the existing sub-pilot scale unit for coal injection. Phase III focused on integrated CDCL demonstration in the sub-pilot scale unit. A comprehensive ASPEN® simulations and economic analysis was completed by CONSOL t is expected that the CDCL process will be ready for further demonstrations in a scale up unit upon completion of the proposed project.

  20. Thermal Integration of CO{sub 2} Compression Processes with Coal-Fired Power Plants Equipped with Carbon Capture

    SciTech Connect (OSTI)

    Edward Levy

    2012-06-29

    Coal-fired power plants, equipped either with oxycombustion or post-combustion CO{sub 2} capture, will require a CO{sub 2} compression system to increase the pressure of the CO{sub 2} to the level needed for sequestration. Most analyses show that CO{sub 2} compression will have a significant effect on parasitic load, will be a major capital cost, and will contribute significantly to reduced unit efficiency. This project used first principle engineering analyses and computer simulations to determine the effects of utilizing compressor waste heat to improve power plant efficiency and increase net power output of coal-fired power plants with carbon capture. This was done for units with post combustion solvent-based CO{sub 2} capture systems and for oxyfired power plants, firing bituminous, PRB and lignite coals. The thermal integration opportunities analyzed for oxycombustion capture are use of compressor waste heat to reheat recirculated flue gas, preheat boiler feedwater and predry high-moisture coals prior to pulverizing the coal. Among the thermal integration opportunities analyzed for post combustion capture systems are use of compressor waste heat and heat recovered from the stripper condenser to regenerate post-combustion CO{sub 2} capture solvent, preheat boiler feedwater and predry high-moisture coals. The overall conclusion from the oxyfuel simulations is that thermal integration of compressor heat has the potential to improve net unit heat rate by up to 8.4 percent, but the actual magnitude of the improvement will depend on the type of heat sink used and to a lesser extent, compressor design and coal rank. The simulations of a unit with a MEA post combustion capture system showed that thermal integration of either compressor heat or stripper condenser heat to preheat boiler feedwater would result in heat rate improvements from 1.20 percent to 4.19 percent. The MEA capture simulations further showed that partial drying of low rank coals, done in combination with feedwater heating, would result in heat rate reductions of 7.43 percent for PRB coal and 10.45 percent for lignite.

  1. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  2. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  3. Resinous binders for coal and chars

    SciTech Connect (OSTI)

    Olson, E.S.; Sharma, R.K.; Young, B.C.

    1995-12-31

    Binder development and application to the briquetting or pelleting of coal fines has been extensive. The search for low-cost, effective binders for making strong and durable briquettes or pellets continues unabated. Strong, durable compacts are required, not only for handling, transport, and storage of the product but also to withstand the rigors of application such as flue gas treatment sorbents and catalytic supports. Many kinds of binders, organic and inorganic, have been used to gain the desired strength. Synthetic polymers have been investigated because they promote good strength and water insolubility, but these features are generally outweighed by the polymer cost. Promising earlier developments of biomass-derived binders have received slow market acceptance, mainly because of the cost resulting from the high concentrations required. However, recent advances in processing lignocellulosic materials have generated potentially low-cost polymeric binding agents for making coal briquettes. Phenol novolaks were previously used with lignites to make activated carbons. Recently, binders were prepared from mixtures of phenol, lignin, and formaldehyde and used for wood flour molding and friction materials. The goal of our work was to investigate the characteristics of resinous binders from lignocellulosic as well as coal-derived materials when used with dried or beneficiated coals and chars.

  4. PULSE COMBUSTOR DESIGN QUALIFICATION TEST AND CLEAN COAL FEEDSTOCK TEST - VOLUME I AND VOLUME II

    SciTech Connect (OSTI)

    Unknown

    2002-02-08

    For this Cooperative Agreement, the pulse heater module is the technology envelope for an indirectly heated steam reformer. The field of use of the steam reformer pursuant to this Cooperative Agreement with DOE is for the processing of sub-bituminous coals and lignite. The main focus is the mild gasification of such coals for the generation of both fuel gas and char--for the steel industry is the main focus. An alternate market application for the substitution of metallurgical coke is also presented. This project was devoted to qualification of a 253-tube pulse heater module. This module was designed, fabricated, installed, instrumented and tested in a fluidized bed test facility. Several test campaigns were conducted. This larger heater is a 3.5 times scale-up of the previous pulse heaters that had 72 tubes each. The smaller heater has been part of previous pilot field testing of the steam reformer at New Bern, North Carolina. The project also included collection and reduction of mild gasification process data from operation of the process development unit (PDU). The operation of the PDU was aimed at conditions required to produce char (and gas) for the Northshore Steel Operations. Northshore Steel supplied the coal for the process unit tests.

  5. PRELIMINARY CARBON DIOXIDE CAPTURE TECHNICAL AND ECONOMIC FEASIBILITY STUDY EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Envergex, Srivats; Browers, Bruce; Thumbi, Charles

    2013-01-01

    Barr Engineering Co. was retained by the Institute for Energy Studies (IES) at University of North Dakota (UND) to conduct a technical and economic feasibility analysis of an innovative hybrid sorbent technology (CACHYS™) for carbon dioxide (CO2) capture and separation from coal combustion–derived flue gas. The project team for this effort consists of the University of North Dakota, Envergex LLC, Barr Engineering Co., and Solex Thermal Science, along with industrial support from Allete, BNI Coal, SaskPower, and the North Dakota Lignite Energy Council. An initial economic and feasibility study of the CACHYS™ concept, including definition of the process, development of process flow diagrams (PFDs), material and energy balances, equipment selection, sizing and costing, and estimation of overall capital and operating costs, is performed by Barr with information provided by UND and Envergex. The technology—Capture from Existing Coal-Fired Plants by Hybrid Sorption Using Solid Sorbents Capture (CACHYS™)—is a novel solid sorbent technology based on the following ideas: reduction of energy for sorbent regeneration, utilization of novel process chemistry, contactor conditions that minimize sorbent-CO2 heat of reaction and promote fast CO2 capture, and a low-cost method of heat management. The technology’s other key component is the use of a low-cost sorbent.

  6. Kemper County IGCC (tm) Project Preliminary Public Design Report

    SciTech Connect (OSTI)

    Nelson, Matt; Rush, Randall; Madden, Diane; Pinkston, Tim; Lunsford, Landon

    2012-07-01

    The Kemper County IGCC Project is an advanced coal technology project that is being developed by Mississippi Power Company (MPC). The project is a lignite-fueled 2-on-1 Integrated Gasification Combined-Cycle (IGCC) facility incorporating the air-blown Transport Integrated Gasification (TRIG™) technology jointly developed by Southern Company; Kellogg, Brown, and Root (KBR); and the United States Department of Energy (DOE) at the Power Systems Development Facility (PSDF) in Wilsonville, Alabama. The estimated nameplate capacity of the plant will be 830 MW with a peak net output capability of 582 MW. As a result of advanced emissions control equipment, the facility will produce marketable byproducts of ammonia, sulfuric acid, and carbon dioxide. 65 percent of the carbon dioxide (CO{sub 2}) will be captured and used for enhanced oil recovery (EOR), making the Kemper County facility’s carbon emissions comparable to those of a natural-gas-fired combined cycle power plant. The commercial operation date (COD) of the Kemper County IGCC plant will be May 2014. This report describes the basic design and function of the plant as determined at the end of the Front End Engineering Design (FEED) phase of the project.

  7. A study of toxic emissions from a coal-fired power plant utilizing an ESP/Wet FGD system. Volume 1, Sampling, results, and special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    This was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE-PETC in 1993 as mandated by the 1990 Clean Air Act. It is organized into 2 volumes; Volume 1 describes the sampling effort, presents the concentration data on toxic chemicals in several power plant streams, and reports the results of evaluations and calculations. The study involved solid, liquid, and gaseous samples from input, output, and process streams at Coal Creek Station Unit No. 1, Underwood, North Dakota (1100 MW mine-mouth plant burning lignite from the Falkirk mine located adjacent to the plant). This plant had an electrostatic precipitator and a wet scrubber flue gas desulfurization unit. Measurements were conducted on June 21--24, 26, and 27, 1993; chemicals measured were 6 major and 16 trace elements (including Hg, Cr, Cd, Pb, Se, As, Be, Ni), acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate), ammonia and cyanide, elemental C, radionuclides, VOCs, semivolatiles (incl. PAH, polychlorinated dioxins, furans), and aldehydes. Volume 2: Appendices includes process data log sheets, field sampling data sheets, uncertainty calculations, and quality assurance results.

  8. Fifteenth symposium on biotechnology for fuels and chemicals: Program and abstracts

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This collection contains 173 abstracts from presented papers and poster sessions. The five sessions of the conference were on the subjects of: (1) Thermal, Chemical, and Biological Processing, (2) Applied Biological Research, (3) Bioprocessing Research (4), Process Economics and Commercialization, and (5) Environmental Biotechnology. Examples of specific topics in the first session include the kinetics of ripening cheese, microbial liquefaction of lignite, and wheat as a feedstock for fuel ethanol. Typical topics in the second session were synergism studies of bacterial and fungal celluloses, conversion of inulin from jerusalem artichokes to sorbitol and ethanol by saccharomyces cerevisiae, and microbial conversion of high rank coals to methane. The third session entertained topics such as hydrodynamic modeling of a liquid fluidized bed bioreactor for coal biosolubilization, aqueous biphasic systems for biological particle partitioning, and arabinose utilization by xylose-fermenting yeast and fungi. The fourth session included such topics as silage processing of forage biomass to alcohol fuels, economics of molasses to ethanol in India, and production of lactic acid from renewable resources. the final session contained papers on such subjects as bioluminescent detection of contaminants in soils, characterization of petroleum contaminated soils in coral atolls in the south Pacific, and landfill management for methane generation and emission control.

  9. A review of the global emissions, transport and effects of heavy metals in the environment

    SciTech Connect (OSTI)

    Friedman, J.R.; Ashton, W.B.; Rapoport, R.D.

    1993-06-01

    The purpose of this report is to describe the current state of knowledge regarding the sources and quantities of heavy metal emissions, their transport and fate, their potential health and environmental effects, and strategies to control them. The approach is to review the literature on this topic and to consult with experts in the field. Ongoing research activities and research needs are discussed. Estimates of global anthropogenic and natural emissions indicate that anthropogenic emissions are responsible for most of the heavy metals released into the atmosphere and that industrial activities have had a significant impact on the global cycling of trace metals. The largest anthropogenic sources of trace metals are coal combustion and the nonferrous metal industry. Atmospheric deposition is an important pathway by which trace metals enter the environment. Atmospheric deposition varies according to the solubility of the element and the length of time it resides in the atmosphere. Evidence suggests that deposition is influenced by other chemicals in the atmosphere, such as ozone and sulfur dioxide. Trace metals also enter the environment through leaching. Existing emissions-control technologies such as electrostatic precipitators, baghouses, and scrubbers are designed to remove other particulates from the flue gas of coal-fired power plants and are only partially effective at removing heavy metals. Emerging technologies such as flue gas desulfurization, lignite coke, and fluidized bed combustion could further reduce emissions. 108 refs.

  10. Municipal solid waste fueled power generation in China: a case study of waste-to-energy in Changchun city

    SciTech Connect (OSTI)

    Hefa Cheng; Yanguo Zhang; Aihong Meng; Qinghai Li

    2007-11-01

    With rapid economic growth and massive urbanization in China, many cities face the problem of municipal solid waste (MSW) disposal. With the lack of space for new landfills, waste-to-energy incineration is playing an increasingly important role in waste management. Incineration of MSW from Chinese cities presents some unique challenges because of its low calorific value (3000-6700 kJ/kg) and high water content (about 50%). This study reports a novel waste-to-energy incineration technology based on co-firing of MSW with coal in a grate-circulating fluidized bed (CFB) incinerator, which was implemented in the Changchun MSW power plant. In 2006, two 260 ton/day incinerators incinerated 137,325 tons, or approximately one/sixth of the MSW generated in Changchun, saving more than 0.2 million m{sup 3} landfill space. A total of 46.2 million kWh electricity was generated (38,473 tons lignite was also burned as supplementary fuel), with an overall fuel-to-electricity efficiency of 14.6%. Emission of air pollutants including particulate matters, acidic gases, heavy metals, and dioxins was low and met the emission standards for incinerators. As compared to imported incineration systems, this new technology has much lower capital and operating costs and is expected to play a role in meeting China's demands for MSW disposal and alternative energy. 34 refs., 1 fig., 4 tabs.

  11. Energy and environmental research emphasizing low-rank coal -- Task 3.8, Pressurized fluidized-bed combustion

    SciTech Connect (OSTI)

    Mann, M.D.; Henderson, A.K.; Swanson, M.L.

    1995-03-01

    The goal of the PFBC activity is to generate fundamental process information that will further the development of an economical and environmentally acceptable second-generation PFBC. The immediate objectives focus on generic issues, including the performance of sulfur sorbents, fate of alkali, and the Resource Conservation and Recovery Act (RCRA) heavy metals in PFBC. A great deal of PFBC performance relates to the chemistry of the bed and the contact between gas and solids that occurs during combustion. These factors can be studied in a suitably designed bench-scale reactor. The present studies are focusing on the emission control strategies applied in the bed, rather than in hot-gas cleaning. Emission components include alkali and heavy metals in addition to SO{sub 2}, NO{sub x}, N{sub 2}O, and CO. The report presents: a description of the pressurized fluidized-bed reactor (PFBR); a description of the alkali sampling probe; shakedown testing of the bench-scale PFBR; results from alkali sampling; results from sulfur sorbent performance tests; and results from refuse-derived fuel and lignite combustion tests.

  12. Screening of carbon-based sorbents for the removal of elemental mercury from simulated combustion flue gas

    SciTech Connect (OSTI)

    Young, B.C.; Musich, M.A. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31

    A fixed-bed reactor system with continuous Hg{sup 0} analysis capabilities was used to evaluate commercial carbon sorbents for the removal of elemental mercury from simulated flue gas. The objectives of the program were to compare the sorbent effectiveness under identical test conditions and to identify the effects of various flue gas components on elemental mercury sorption. Sorbents tested included steam-activated lignite, chemical-activated hardwood and bituminous coal, iodated steam-activated coconut shell, and sulfur-impregnated steam-activated bituminous coal. The iodated carbon was the most effective carbon, showing over 99% mercury removal according to EPA Method 101A. Data indicate that O{sub 2} (4 vol%) and SO{sub 2} (500 ppm) improved the mercury removal of the other carbons for tests at 150{degrees}C using 100 {mu}g/m{sup 3} Hg{sup 0}. Further, the presence of HCl (at 50 ppm) produced a magnitude increase in mercury removal for the steam-activated and sulfur-impregnated bituminous coal-based carbons.

  13. Heterogeneous kinetics of coal gasification. Quarterly technical progress report, 1 April 1983-30 June 1983

    SciTech Connect (OSTI)

    Calo, J.M.; Ganapathi, R.

    1983-01-01

    In the current quarterly technical progress report we present data and results on transient kinetic studies of the steam-char reaction system for activated coconut and lignite chars. These experiments were conducted in a fashion similar to the previous char-CO/sub 2/ studies, under approximately the same experimental conditions. The two principal product species, H/sub 2/ and CO, were monitored using the automatic mass programming system developed especially for this project. In order to perform the steam-char experiments, the original apparatus was modified by the addition of a steam generation/condensate removal system. The steam-char reaction system, being somewhat more complex than the CO/sub 2/-char reaction system, was modeled with a six-parameter, elementary kinetic scheme. The ''effective'' active site concentrations determined from the steam gasification data were of the same order of magnitude, and behaved in a similar fashion, to those obtained for the CO/sub 2/ gasification studies. The implications of this result are briefly discussed. 21 refs., 23 figs., 2 tabs.

  14. Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

    SciTech Connect (OSTI)

    Kloosterman, Jeff

    2012-12-31

    Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

  15. Stabilization of Oklahoma expensive soils using lime and class C fly ash

    SciTech Connect (OSTI)

    Buhler, R.L.; Cerato, A.B.

    2007-01-15

    This study uses lime and class C fly ash, an industrial byproduct of electric power production produced from burning lignite and subbituminous coal, to study the plasticity reduction in highly expensive natural clays from Idabel, Oklahoma. This study is important, especially in Oklahoma, because most of the native soils are expansive and cause seasonal damage to roadways and structures. The addition of lime or fly ash helps to arrest the shrinkage and swelling behavior of soil. Four soil samples with the same AASHTO classification were used in this study to show shrinkage variability within a soil group with the addition of lime and class C fly ash. The plasticity reduction in this study was quantified using the linear shrinkage test. It was found that soils classified within the same AASHTO group had varying shrinkage characteristics. It was also found that both lime and fly ash reduced the lienar shrinkage, however, the addition of lime reduced the linear shrinkage to a greater degree than the same percentage of class C fly ash. Even though it takes much less lime than fly ash to reduce the plasticity of a highly expansive soil, it may be less expensive to utilize fly ash, which is a waste product of electric power production. Lime also has a lower unit weight than fly ash so weight percentage results may be misleading.

  16. Selenium And Arsenic Speciation in Fly Ash From Full-Scale Coal-Burning Utility Plants

    SciTech Connect (OSTI)

    Huggins, F.E.; Senior, C.L.; Chu, P.; Ladwig, K.; Huffman, G.P.; /Kentucky U. /Reaction Engin. Int. /Elect. Power Res. Inst., Palo Alto

    2007-07-09

    X-ray absorption fine structure spectroscopy has been used to determine directly the oxidation states and speciation of selenium and arsenic in 10 fly ash samples collected from full-scale utility plants. Such information is needed to assess the health risk posed by these elements in fly ash and to understand their behavior during combustion and in fly ash disposal options, such as sequestration in tailings ponds. Selenium is found predominantly as Se(IV) in selenite (SeO{sub 3}{sup 2-}) species, whereas arsenic is found predominantly as As(V) in arsenate (AsO{sub 4}{sup 3-}) species. Two distinct types of selenite and arsenate spectra were observed depending upon whether the fly ash was derived from eastern U.S. bituminous (Fe-rich) coals or from western subbituminous or lignite (Ca-rich) coals. Similar spectral details were observed for both arsenic and selenium in the two different types of fly ash, suggesting that the post-combustion behavior and capture of both of these elements are likely controlled by the same dominant element or phase in each type of fly ash.

  17. Baghouse Slipstream Testing at TXU's Big Brown Station

    SciTech Connect (OSTI)

    John Pavlish; Jason Laumb; Robert Jensen; Jeffery Thompson; Christopher Martin; Mark Musich; Brandon Pavlish; Stanley Miller; Lucinda Hamre

    2007-04-30

    Performing sorbent testing for mercury control at a large scale is a very expensive endeavor and requires months of planning and careful execution. Even with good planning, there are plant limitations on what operating/design parameters can be varied/tested and when. For parameters that cannot be feasibly tested at the full scale (lower/higher gas flow, different bag material, cleaning methods, sorbents, etc.), an alternative approach is used to perform tests on a slipstream unit using flue gas from the plant. The advantage that a slipstream unit provides is the flexibility to test multiple operating and design parameters and other possible technology options without risking major disruption to the operation of the power plant. Additionally, the results generated are expected to simulate full-scale conditions closely, since the flue gas used during the tests comes directly from the plant in question. The Energy & Environmental Research Center developed and constructed a mobile baghouse that allows for cost-effective testing of impacts related to variation in operating and design parameters, as well as other possible mercury control options. Multiple sorbents, air-to-cloth ratios, bag materials, and cleaning frequencies were evaluated while flue gas was extracted from Big Brown when it fired a 70% Texas lignite-30% Powder River Basin (PRB) blend and a 100% PRB coal.

  18. Great Plains ASPEN model development: executive summary. Final topical report for Phase 1

    SciTech Connect (OSTI)

    Rinard, I.H.; Stern, S.S.; Millman, M.C.; Schwint, K.J.; Benjamin, B.W.; Kirman, J.J.; Dweck, J.S.; Mendelson, M.A.

    1986-07-25

    The Scientific Design Company contracted with the United States Department of Energy through its Morgantown Energy Technology Center to develop a steady-state simulation model of the Great Plains Coal Gasification plant. This plant produces substitute natural gas from North Dakota lignite. The model was to be developed using the ASPEN (Advanced System for Process Engineering) simulation program. The project was divided into the following tasks: (1) Development of a simplified overall model of the process to be used for a sensitivity analysis to guide the development of more rigorous section models. (2) Review and evaluation of existing rigorous moving-bed gasifier models leading to a recommendation of one to be used to model the Great Plains gasifiers. Adaption and incorporation of this model into ASPEN. (3) Review of the accuracy and completeness of the physical properties data and models provided by ASPEN that are required to characterize the Great Plains plant. Rectification of inaccurate or incomplete data. (4) Development of rigorous ASPEN models for critical unit operations and sections of the plant. (5) Evaluation of the accuracy of the ASPEN Cost Estimation and Evaluation System and upgrading where feasible. Development of a preliminary cost estimate for the Great Plains plant. (6) Validation of the simulation models developed in the course of this project. Determination of model sensitivity to variations of technical and economic parameters. (7) Documentation of all work performed in the course of this project. Essentially all of these tasks were completed successfully. 34 figs.

  19. Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water

    SciTech Connect (OSTI)

    Song Jin

    2007-05-31

    Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

  20. Field Testing of Activated Carbon Injection Options for Mercury Control at TXU's Big Brown Station

    SciTech Connect (OSTI)

    John Pavlish; Jeffrey Thompson; Christopher Martin; Mark Musich; Lucinda Hamre

    2009-01-07

    The primary objective of the project was to evaluate the long-term feasibility of using activated carbon injection (ACI) options to effectively reduce mercury emissions from Texas electric generation plants in which a blend of lignite and subbituminous coal is fired. Field testing of ACI options was performed on one-quarter of Unit 2 at TXU's Big Brown Steam Electric Station. Unit 2 has a design output of 600 MW and burns a blend of 70% Texas Gulf Coast lignite and 30% subbituminous Powder River Basin coal. Big Brown employs a COHPAC configuration, i.e., high air-to-cloth baghouses following cold-side electrostatic precipitators (ESPs), for particulate control. When sorbent injection is added between the ESP and the baghouse, the combined technology is referred to as TOXECON{trademark} and is patented by the Electric Power Research Institute in the United States. Key benefits of the TOXECON configuration include better mass transfer characteristics of a fabric filter compared to an ESP for mercury capture and contamination of only a small percentage of the fly ash with AC. The field testing consisted of a baseline sampling period, a parametric screening of three sorbent injection options, and a month long test with a single mercury control technology. During the baseline sampling, native mercury removal was observed to be less than 10%. Parametric testing was conducted for three sorbent injection options: injection of standard AC alone; injection of an EERC sorbent enhancement additive, SEA4, with ACI; and injection of an EERC enhanced AC. Injection rates were determined for all of the options to achieve the minimum target of 55% mercury removal as well as for higher removals approaching 90%. Some of the higher injection rates were not sustainable because of increased differential pressure across the test baghouse module. After completion of the parametric testing, a month long test was conducted using the enhanced AC at a nominal rate of 1.5 lb/Macf. During the time that enhanced AC was injected, the average mercury removal for the month long test was approximately 74% across the test baghouse module. ACI was interrupted frequently during the month long test because the test baghouse module was bypassed frequently to relieve differential pressure. The high air-to-cloth ratio of operations at this unit results in significant differential pressure, and thus there was little operating margin before encountering differential pressure limits, especially at high loads. This limited the use of sorbent injection as the added material contributes to the overall differential pressure. This finding limits sustainable injection of AC without appropriate modifications to the plant or its operations. Handling and storage issues were observed for the TOXECON ash-AC mixture. Malfunctioning equipment led to baghouse dust hopper plugging, and storage of the stagnant material at flue gas temperatures resulted in self-heating and ignition of the AC in the ash. In the hoppers that worked properly, no such problems were reported. Economics of mercury control at Big Brown were estimated for as-tested scenarios and scenarios incorporating changes to allow sustainable operation. This project was funded under the U.S. Department of Energy National Energy Technology Laboratory project entitled 'Large-Scale Mercury Control Technology Field Testing Program--Phase II'.

  1. Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Rao, A. D.; Chen, Q.; Samuelsen, G. S.

    2012-09-30

    The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal performance between the various coproduct cases is further complicated by the fact that the carbon footprint is not the same when carbon leaving with the coproduct are accounted for. The economic analysis and demand for a particular coproduct in the market place is a more meaningful comparison of the various coproduction scenarios. The first year cost of electricity calculated for the bituminous coal is $102.9/MWh while that for the lignite is $108.1/MWh. The calculated cost of hydrogen ranged from $1.42/kg to $2.77/kg depending on the feedstock, which is lower than the DOE announced hydrogen cost goal of $3.00/kg in July 14, 2005. Methanol cost ranged from $345/MT to $617/MT, while the market price is around $450/MT. For Fischer-Tropsch liquids, the calculated cost ranged from $65/bbl to $112/bbl, which is comparable to the current market price of crude oil at around $100/bbl. It should be noted, however, that F-T liquids contain no sulfur and nitrogen compounds. The calculated cost of alcohol ranged from $4.37/gal to $5.43/gal, while it ranged from $2.20/gal to $3.70/gal in a DOE funded study conducted by Louisiana State University. The Louisiana State University study consisted of a significantly larger plant than our study and benefited from economies of scale. When the plant size in our study is scaled up to similar size as in the Louisiana State University study, cost of alcohol is then reduced to a range of $3.24/gal to $4.28/gal, which is comparable. Urea cost ranged from $307/MT to $428/MT, while the market price is around $480/MT.

  2. Evaluation of MerCAP for Power Plant Mercury Control

    SciTech Connect (OSTI)

    Carl Richardson

    2008-09-30

    This report is submitted to the U.S. Department of Energy National Energy Technology Laboratory (DOE-NETL) as part of Cooperative Agreement DE-FC26-03NT41993, 'Evaluation of EPRI's MerCAP{trademark} Technology for Power Plant Mercury Control'. This project has investigated the mercury removal performance of EPRI's Mercury Capture by Amalgamation Process (MerCAP{trademark}) technology. Test programs were conducted to evaluate gold-based MerCAP{trademark} at Great River Energy's Stanton Station Unit 10 (Site 1), which fired both North Dakota lignite (NDL) and Power River Basin (PRB) coal during the testing period, and at Georgia Power's Plant Yates Unit 1 (Site 2) [Georgia Power is a subsidiary of The Southern Company] which fires a low sulfur Eastern bituminous coal. Additional tests were carried out at Alabama Power's Plant Miller, which fires Powder River Basin Coal, to evaluate a carbon-based MerCAP{trademark} process for removing mercury from flue gas downstream of an electrostatic precipitator [Alabama Power is a subsidiary of The Southern Company]. A full-scale gold-based sorbent array was installed in the clean-air plenum of a single baghouse compartment at GRE's Stanton Station Unit 10, thereby treating 1/10th of the unit's exhaust gas flow. The substrates that were installed were electroplated gold screens oriented parallel to the flue gas flow. The sorbent array was initially installed in late August of 2004, operating continuously until its removal in July 2006, after nearly 23 months. The initial 4 months of operation were conducted while the host unit was burning North Dakota lignite (NDL). In November 2004, the host unit switched fuel to burn Powder River Basin (PRB) subbituminous coal and continued to burn the PRB fuel for the final 19 months of this program. Tests were conducted at Site 1 to evaluate the impacts of flue gas flow rate, sorbent plate spacing, sorbent pre-cleaning and regeneration, and spray dryer operation on MerCAP{trademark} performance. At Site 2, a pilot-scale array was installed in a horizontal reactor chamber designed to treat approximately 2800 acfm of flue gas obtained from downstream of the plant's flue gas desulfurization (FGD) system. The initial MerCAP{trademark} array was installed at Plant Yates in January 2004, operating continuously for several weeks before a catastrophic system failure resulting from a failed flue gas fan. A second MerCAP{trademark} array was installed in July 2006 and operated for one month before being shut down for a reasons pertaining to system performance and host site scheduling. A longer-term continuous-operation test was then conducted during the summer and fall of 2007. Tests were conducted to evaluate the impacts of flue gas flow rate, sorbent space velocity, and sorbent rinsing frequency on mercury removal performance. Detailed characterization of treated sorbent plates was carried out in an attempt to understand the nature of reactions leading to excessive corrosion of the substrate surfaces.

  3. Synthesis gas production with an adjustable H{sub 2}/CO ratio through the coal gasification process: effects of coal ranks and methane addition

    SciTech Connect (OSTI)

    Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

    2008-05-15

    Direct production of synthesis gas using coal as a cheap feedstock is attractive but challenging due to its low H{sub 2}/CO ratio of generated synthesis gas. Three typical U.S. coals of different ranks were tested in a 2.5 in. coal gasifier to investigate their gasification reactivity and adjustability on H{sub 2}/CO ratio of generated synthesis gas with or without the addition of methane. Tests indicated that lower-rank coals (lignite and sub-bituminous) have higher gasification reactivity than bituminous coals. The coal gasification reactivity is correlated to its synthesis-gas yield and the total percentage of H{sub 2} and CO in the synthesis gas, but not to the H{sub 2}/CO ratio. The H{sub 2}/CO ratio of coal gasification was found to be correlated to the rank of coals, especially the H/C ratio of coals. Methane addition into the dense phase of the pyrolysis and gasification zone of the cogasification reactor could make the best use of methane in adjusting the H{sub 2}/CO ratio of the generated synthesis gas. The maximum methane conversion efficiency, which was likely correlated to its gasification reactivity, could be achieved by 70% on average for all tested coals. The actual catalytic effect of generated coal chars on methane conversion seemed coal-dependent. The coal-gasification process benefits from methane addition and subsequent conversion on the adjustment of the H{sub 2}/CO ratio of synthesis gas. The methane conversion process benefits from the use of coal chars due to their catalytic effects. This implies that there were likely synergistic effects on both. 25 refs., 3 figs., 3

  4. Turkey energy and environmental review - Task 7 energy sector modeling : executive summary.

    SciTech Connect (OSTI)

    Conzelmann, G.; Koritarov, V.; Decision and Information Sciences

    2008-02-28

    Turkey's demand for energy and electricity is increasing rapidly. Since 1990, energy consumption has increased at an annual average rate of 4.3%. As would be expected, the rapid expansion of energy production and consumption has brought with it a wide range of environmental issues at the local, regional and global levels. With respect to global environmental issues, Turkey's carbon dioxide (CO2) emissions have grown along with its energy consumption. Emissions in 2000 reached 211 million metric tons. With GDP projected to grow at over 6% per year over the next 25 years, both the energy sector and the pollution associated with it are expected to increase substantially. This is expected to occur even if assuming stricter controls on lignite and hard coal-fired power generation. All energy consuming sectors, that is, power, industrial, residential, and transportation, will contribute to this increased emissions burden. Turkish Government authorities charged with managing the fundamental problem of carrying on economic development while protecting the environment include the Ministry of Environment (MOE), the Ministry of Energy and Natural Resources (MENR), and the Ministry of Health, as well as the Turkish Electricity Generation & Transmission Company (TEAS). The World Bank, working with these agencies, is planning to assess the costs and benefits of various energy policy alternatives under an Energy and Environment Review (EER). Eight individual studies have been conducted under this activity to analyze certain key energy technology issues and use this analysis to fill in the gaps in data and technical information. This will allow the World Bank and Turkish authorities to better understand the trade-offs in costs and impacts associated with specific policy decisions. The purpose of Task 7-Energy Sector Modeling, is to integrate information obtained in other EER tasks and provide Turkey's policy makers with an integrated systems analysis of the various options for addressing the various energy and environmental concerns. The work presented in this report builds on earlier analyses presented at the COP 6 conference in Bonn.

  5. The use of NMR techniques for the analysis of water in coal and the effect of different coal drying techniques on the structure and reactivity of coal. Final report

    SciTech Connect (OSTI)

    Netzel, D.A.; Miknis, F.P.; Wallace, J.C. Jr.; Butcher, C.H.; Mitzel, J.M.; Turner, T.F.; Hurtubise, R.J.

    1995-02-01

    Western Research Institute has conducted a study of different methods of coal drying as pretreatment steps before liquefaction. The objectives of this study were to develop a combined chemical dehydration/nuclear magnetic resonance (NMR) method for measuring the moisture content of coal, to measure the changes in coal structure that occur during drying, and to determine the effects of different drying methods on liquefaction reactivity of coals. Different methods of drying were investigated to determine whether coal drying can be accomplished without reducing the reactivity of coals toward liquefaction. Drying methods included thermal, microwave, and chemical dehydration. Coals of rank lignite to high volatile bituminous were studied. Coals that were dried or partially dried thermally and with microwaves had lower liquefaction conversions than coals containing equilibrium moisture contents. However, chemically dried coals had conversions equal to or greater than the premoisturized coals. The conversion behavior is consistent with changes in the physical structure and cross linking reactions because of drying. Thermal and microwave drying appear to cause a collapse in the pore structure, thus preventing donor solvents such as tetralin from contacting reactive sites inside the coals. Chemical dehydration does not appear to collapse the pore structure. These results are supported by the solvent swelling measurements in which the swelling ratios of thermally dried and microwave-dried coals were lower than those of premoisturized coals, indicating a greater degree of cross linking in the dried coals. The swelling ratios of the chemically dried coals were greater than those of the premoisturized coals because the pore structure remaining unchanged or increased when water was removed. These results are consistent with the NMR results, which did not show significant changes in coal chemical structure.

  6. Insights into the Structure and Metabolic Function of Microbes That Shape Pelagic Iron-Rich Aggregates ( Iron Snow )

    SciTech Connect (OSTI)

    Lu, S; Chourey, Karuna; REICHE, M; Nietzsche, S; Shah, Manesh B; Hettich, Robert {Bob} L; Kusel, K

    2013-01-01

    Metaproteomics combined with total nucleic acid-based methods aided in deciphering the roles of microorganisms in the formation and transformation of iron-rich macroscopic aggregates (iron snow) formed in the redoxcline of an acidic lignite mine lake. Iron snow had high total bacterial 16S rRNA gene copies, with 2 x 109 copies g (dry wt)-1 in the acidic (pH 3.5) central lake basin and 4 x 1010 copies g (dry wt)-1 in the less acidic (pH 5.5) northern lake basin. Active microbial communities in the central basin were dominated by Alphaproteobacteria (36.6%) and Actinobacteria (21.4%), and by Betaproteobacteria (36.2%) in the northern basin. Microbial Fe-cycling appeared to be the dominant metabolism in the schwertmannite-rich iron snow, because cloning and qPCR assigned up to 61% of active bacteria as Fe-cycling bacteria (FeB). Metaproteomics revealed 70 unique proteins from central basin iron snow and 283 unique proteins from 43 genera from northern basin. Protein identification provided a glimpse into in situ processes, such as primary production, motility, metabolism of acidophilic FeB, and survival strategies of neutrophilic FeB. Expression of carboxysome shell proteins and RubisCO indicated active CO2 fixation by Fe(II) oxidizers. Flagellar proteins from heterotrophs indicated their activity to reach and attach surfaces. Gas vesicle proteins related to CO2-fixing Chlorobium suggested that microbes could influence iron snow sinking. We suggest that iron snow formed by autotrophs in the redoxcline acts as a microbial parachute, since it is colonized by motile heterotrophs during sinking which start to dissolve schwertmannite.

  7. Postcombustion and its influences in 135 MWe CFB boilers

    SciTech Connect (OSTI)

    Shaohua Li; Hairui Yang; Hai Zhang; Qing Liu; Junfu Lu; Guangxi Yue

    2009-09-15

    In the cyclone of a circulating fluidized bed (CFB) boiler, a noticeable increment of flue gas temperature, caused by combustion of combustible gas and unburnt carbon content, is often found. Such phenomenon is defined as post combustion, and it could introduce overheating of reheated and superheated steam and extra heat loss of exhaust flue gas. In this paper, mathematical modeling and field measurements on post combustion in 135MWe commercial CFB boilers were conducted. A novel one-dimensional combustion model taking post combustion into account was developed. With this model, the overall combustion performance, including size distribution of various ashes, temperature profile, and carbon content profiles along the furnace height, heat release fraction in the cyclone and furnace were predicted. Field measurements were conducted by sampling gas and solid at different positions in the boiler under different loads. The measured data and corresponding model-calculated results were compared. Both prediction and field measurements showed post combustion introduced a temperature increment of flue gas in the cyclone of the 135MWe CFB boiler in the range of 20-50{sup o}C when a low-volatile bituminous coal was fired. Although it had little influence on ash size distribution, post combustion had a remarkable influence on the carbon content profile and temperature profile in the furnace. Moreover, it introduced about 4-7% heat release in the cyclone over the total heat release in the boiler. This fraction slightly increased with total air flow rate and boiler load. Model calculations were also conducted on other two 135MWe CFB boilers burning lignite and anthracite coal, respectively. The results confirmed that post combustion was sensitive to coal type and became more severe as the volatile content of the coal decreased. 15 refs., 11 figs., 4 tabs.

  8. Low-grade coals: a review of some prospective upgrading technologies

    SciTech Connect (OSTI)

    Hassan Katalambula; Rajender Gupta [University of Alberta, Edmonton, AB (Canada). Department of Chemical and Materials Engineering

    2009-07-15

    There is a growing need of using low-grade coals because of higher quest for power generation. In the present carbon-constrained environment, there is a need of upgrading these coals in terms of moisture, ash, and/or other trace elements. The current paper reviews technologies used mainly categorized as drying for reducing moisture and cleaning the coal for reducing mineral content of coal and related harmful constituents, such as sulfur and mercury. The earliest upgrading of high-moisture lignite involved drying and manufacturing of briquettes. Drying technologies consist of both evaporative and non-evaporative (dewatering) types. The conventional coal cleaning used density separation in water medium. However, with water being a very important resource, conservation of water is pushing toward the development of dry cleaning of coal. There are also highly advanced coal-cleaning technologies that produce ultra-clean coals and produce coals with less than 0.1% of ash. The paper discusses some of the promising upgrading technologies aimed at improving these coals in terms of their moisture, ash, and other pollutant components. It also attempts to present the current status of the technologies in terms of development toward commercialization and highlights on problems encountered. It is obvious that still the upgrading goal has not been realized adequately. It can therefore be concluded that, because reserves for low-grade coals are quite plentiful, it is important to intensify efforts that will make these coals usable in an acceptable manner in terms of energy efficiency and environmental protection. 68 refs., 7 figs.

  9. Analysis of mass loss of a coal particle during the course of burning in a flow of inert material

    SciTech Connect (OSTI)

    Pelka, Piotr

    2009-08-15

    This paper is an attempt to explain the role of erosion during the process of coal combustion in a circulating fluidized bed. Different kinds of carbon deposits found in Poland, both bituminous as well as lignite with the particle of 10 mm in diameter were the subject of the research. According to many publications it is well known that erosion plays a significant role in coal combustion, by changing its mechanism as well as generating an additional mass loss of the mother particle. The purpose of this research was to determine the influence of an inert material on an erosive mass loss of a single coal particle burning in a two-phase flow. The determination of the influence of a coal type, the rate of flow of inert material and the temperature inside the furnace on the erosive mass loss of burning coal particle was also taken into consideration. The results obtained indicate that the velocity of the erosive mass loss depends on the chemical composition and petrographic structure of burning coal. The mechanical interaction of inert and burning coal particles leads to the shortening of the period of overall mass loss of the coal particle by even two times. The increase in the rate of flow of the inert material intensifies the generation of mass loss by up to 100%. The drop in temperature which slows down the combustion process, decreases the mass loss of the coal particle as the result of mechanical interaction of the inert material. As was observed, the process of percolation plays a significant role by weakening the surface of the burning coal. (author)

  10. Photosynthetic pigment concentrations, gas exchange and vegetative growth for selected monocots and dicots treated with two contrasting coal fly ashes

    SciTech Connect (OSTI)

    Yunusa, I.A.M.; Burchett, M.D.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Skilbeck, C.G.

    2009-07-15

    There is uncertainty as to the rates of coal fly ash needed for optimum physiological processes and growth. In the current study we tested the hyothesis that photosynthetic pigments concentrations and CO{sub 2} assimilation (A) are more sensitive than dry weights in plants grown on media amended with coal fly ash. We applied the Terrestrial Plant Growth Test (Guideline 208) protocols of the Organization for Economic Cooperation and Development (OECD) to monocots (barley (Hordeum vulgare) and ryegrass (Secale cereale)) and dicots (canola (Brasica napus), radish (Raphanus sativus), field peas (Pisum sativum), and lucerne (Medicago sativa)) on media amended with fly ashes derived from semi-bituminous (gray ash) or lignite (red ash) coals at rates of 0, 2.5, 5.0, 10, or 20 Mg ha(-1). The red ash had higher elemental concentrations and salinity than the gray ash. Fly ash addition had no significant effect on germination by any of the six species. At moderate rates ({<=}10 Mg ha{sup -1}) both ashes increased (P < 0.05) growth rates and concentrations of chlorophylls a and b, but reduced carotenoid concentrations. Addition of either ash increased A in radish and transpiration in barley. Growth rates and final dry weights were reduced for all of the six test species when addition rates exceeded 10 Mg ha{sup -1} for gray ash and 5 Mg ha{sup -1} for red ash. We concluded that plant dry weights, rather than pigment concentrations and/or instantaneous rates of photosynthesis, are more consistent for assessing subsequent growth in plants supplied with fly ash.

  11. Enhancement of mercury capture by the simultaneous addition of hydrogen bromide (HBr) and fly ashes in a slipstream facility

    SciTech Connect (OSTI)

    Yan Cao; Quan-Hai Wang; Jun Li; Jen-Chieh Cheng; Chia-Chun Chan; Marten Cohron; Wei-Ping Pan

    2009-04-15

    Low halogen content in tested Powder River Basin (PRB) coals and low loss of ignition content (LOI) in PRB-derived fly ash were likely responsible for higher elemental mercury content (averaging about 75%) in the flue gas and also lower mercury capture efficiency by electrostatic precipitator (ESP) and wet-FGD. To develop a cost-effective approach to mercury capture in a full-scale coal-fired utility boiler burning PRB coal, experiments were conducted adding hydrogen bromide (HBr) or simultaneously adding HBr and selected fly ashes in a slipstream reactor (0.152 x 0.152 m) under real flue gas conditions. The residence time of the flue gas inside the reactor was about 1.4 s. The average temperature of the slipstream reactor was controlled at about 155{sup o}C. Tests were organized into two phases. In Phase 1, only HBr was added to the slipstream reactor, and in Phase 2, HBr and selected fly ash were added simultaneously. HBr injection was effective (>90%) for mercury oxidation at a low temperature (155{sup o}C) with an HBr addition concentration of about 4 ppm in the flue gas. Additionally, injected HBr enhanced mercury capture by PRB fly ash in the low-temperature range. The mercury capture efficiency, at testing conditions of the slipstream reactor, reached about 50% at an HBr injection concentration of 4 ppm in the flue gas. Compared to only the addition of HBr, simultaneously adding bituminous-derived fly ash in a minimum amount (30 lb/MMacf), together with HBr injection at 4 ppm, could increase mercury capture efficiency by 30%. Injection of lignite-derived fly ash at 30 lb/MMacf could achieve even higher mercury removal efficiency (an additional 35% mercury capture efficiency compared to HBR addition alone). 25 refs., 5 figs., 1 tab.

  12. Wastewater and sludge control-technology options for synfuels industries

    SciTech Connect (OSTI)

    Castaldi, F.J.; Harrison, W.; Ford, D.L.

    1981-02-01

    The options examined were those of zero discharge, partial water reuse with restricted discharge of treated effluents, and unrestricted discharge of treated effluents. Analysis of cost data and performance-analyses data for several candidate secondary-wastewater-treatment unit processes indicated that combined activated-sludge/powdered-activated-carbon (AS/PAC) treatment incorporating wet-air-oxidation carbon regeneration is the most cost-effective control technology available for the removal of organic material from slagging, fixed-bed process wastewaters. Bench-scale treatability and organic-constituent removal studies conducted on process quench waters from a pilot-scale, slagging, fixed-bed gasifer using lignite as feedstock indicated that solvent extraction followed by AS/PAC treatment reduces levels of extractable and chromatographable organics to less than 1 ..mu..g/L in the final effluent. Levels of conventional pollutants also were effectively reduced by AS/PAC to the minimum water-quality standards for most receiving waters. The most favored and most cost-effective treatment option is unrestricted discharge of treated effluents with ultimate disposal of biosludges and landfilling of gasifier ash and slag. This option requires a capital expenditure of $8,260,000 and an annual net operating cost of $2,869,000 in 1978 dollars, exclusive of slag disposal. The net energy requirement of 19.6 x 10/sup 6/ kWh/year, or 15.3 kWh/1000 gal treated, is less than 6% of the equivalent energy demand associated with the zero-discharge option.

  13. Coal plasticity at high heating rates and temperatures. Final technical progress report

    SciTech Connect (OSTI)

    Gerjarusak, S.; Peters, W.A.; Howard, J.B.

    1995-05-01

    Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

  14. Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems

    SciTech Connect (OSTI)

    Richard Rhudy

    2006-06-30

    This final report presents and discusses results from a mercury control process development project entitled ''Pilot Testing of Mercury Oxidation Catalysts for Upstream of Wet FGD Systems''. The objective of this project was to demonstrate at pilot scale a mercury control technology that uses solid honeycomb catalysts to promote the oxidation of elemental mercury in the flue gas from coal combustion. Oxidized mercury is removed in downstream wet flue gas desulfurization (FGD) absorbers and leaves with the FGD byproducts. The goal of the project was to achieve 90% oxidation of elemental mercury in the flue gas and 90% overall mercury capture with the downstream wet FGD system. The project was co-funded by EPRI and the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) under Cooperative Agreement DE-FC26-01NT41185. Great River Energy (GRE) and City Public Service (now CPS Energy) of San Antonio were also project co-funders and provided host sites. URS Group, Inc. was the prime contractor. Longer-term pilot-scale tests were conducted at two sites to provide catalyst life data. GRE provided the first site, at their Coal Creek Station (CCS), which fires North Dakota lignite, and CPS Energy provided the second site, at their Spruce Plant, which fires Powder River Basin (PRB) coal. Mercury oxidation catalyst testing began at CCS in October 2002 and continued through the end of June 2004, representing nearly 21 months of catalyst operation. An important finding was that, even though the mercury oxidation catalyst pilot unit was installed downstream of a high-efficiency ESP, fly ash buildup began to plug flue gas flow through the horizontal catalyst cells. Sonic horns were installed in each catalyst compartment and appeared to limit fly ash buildup. A palladium-based catalyst showed initial elemental mercury oxidation percentages of 95% across the catalyst, declining to 67% after 21 months in service. A carbon-based catalyst began with almost 98% elemental mercury oxidation across the catalyst, but declined to 79% oxidation after nearly 13 months in service. The other two catalysts, an SCR-type catalyst (titanium/vanadium) and an experimental fly-ash-based catalyst, were significantly less active. The palladium-based and SCR-type catalysts were effectively regenerated at the end of the long-term test by flowing heated air through the catalyst overnight. The carbon-based catalyst was not observed to regenerate, and no regeneration tests were conducted on the fourth, fly-ash-based catalyst. Preliminary process economics were developed for the palladium and carbon-based catalysts for a scrubbed, North Dakota lignite application. As described above, the pilot-scale results showed the catalysts could not sustain 90% or greater oxidation of elemental mercury in the flue gas for a period of two years. Consequently, the economics were based on performance criteria in a later DOE NETL solicitation, which required candidate mercury control technologies to achieve at least a 55% increase in mercury capture for plants that fire lignite. These economics show that if the catalysts must be replaced every two years, the catalytic oxidation process can be 30 to 40% less costly than conventional (not chemically treated) activated carbon injection if the plant currently sells their fly ash and would lose those sales with carbon injection. If the plant does not sell their fly ash, activated carbon injection was estimated to be slightly less costly. There was little difference in the estimated cost for palladium versus the carbon-based catalysts. If the palladium-based catalyst can be regenerated to double its life to four years, catalytic oxidation process economics are greatly improved. With regeneration, the catalytic oxidation process shows over a 50% reduction in mercury control cost compared to conventional activated carbon injection for a case where the plant sells its fly ash. At Spruce Plant, mercury oxidation catalyst testing began in September 2003 and continued through the end of April 2005, interrupted only by a

  15. Control of coal combustion SO{sub 2} and NO{sub x} emissions by in-boiler injection of CMA. Final project report, July 1, 1992--December 31, 1994

    SciTech Connect (OSTI)

    Levendis, Y.A.

    1995-04-01

    A study was conducted to determine the efficacy of carboxylic calcium and magnesium salts (e.g., calcium magnesium acetate or CMA, CaMg{sub 2}(CH{sub 2}COOH){sub 6}) for the simultaneous removal of SO{sub 2} and NO{sub x} in oxygen-lean atmospheres. Experiments were performed in a high-temperature furnace that simulated the post-flame environment of a coal-fired boiler by providing similar temperatures and partial pressures of SO{sub 2}, NO{sub x} CO{sub 2} and O{sub 2}. When injected into a hot environment, the salts calcined and formed highly porous {open_quotes}popcorn{close_quotes}-like cenospheres. Residual MgO and/or CaCO{sub 3} and CaO reacted heterogeneously with SO{sub 2} to form MgSO{sub 4} and/or CaCO{sub 4}. The organic components - which can be manufactured from wastes such as sewage sludge - gasified and reduced NO{sub x }to N{sub 2} efficiently if the atmosphere was moderately fuel-rich. Dry-injected CMA particles at a Ca/S ratio of 2, residence time of 1 second and bulk equivalence ratio of 1.3 removed over 90% of SO{sub 2} and NO{sub x} at gas temperatures {>=} 950{degrees}C. When the furnace isothermal zone was {<=} 950{degrees}C, Ca was essentially inert in the furnace quenching zone, while Mg continued to sorb SO{sub 2} as the gas temperature cooled at a rate of -130{degrees}C/sec. Hence, the removal of SO{sub 2} by CMA could continue for nearly the entire residence time of emissions in the exhaust stream of a power plant. Additional research is needed to improve the efficiency and reduce the cost of the relatively expensive carboxylic acid salts as dual SO{sub 2}-NO{sub x} reduction agents. For example, wet injection of the salts could be combined with less expensive hydrocarbons such as lignite or even polymers such as poly(ethylene) that could be extracted from the municipal waste stream.

  16. Field Demonstration of Enhanced Sorbent Injection for Mercury Control

    SciTech Connect (OSTI)

    Shin Kang; Robert Schrecengost

    2009-01-07

    Alstom Power Inc. has conducted a DOE/NETL-sponsored program (under DOE Cooperative Agreement No. DE-FC26-04NT42306) to demonstrate Mer-Cure{trademark}, one of Alstom's mercury control technologies for coal-fired boilers. Mer-Cure{trademark} utilizes a small amount of Mer-Clean{trademark} sorbent that is injected into the flue gas stream for oxidation and adsorption of gaseous mercury. Mer-Clean{trademark} sorbents are carbon-based and prepared with chemical additives that promote oxidation and capture of mercury. Mer-Cure{trademark} is unique in that the sorbent is injected into an environment where the mercury capture kinetics is accelerated. This full-scale demonstration program was comprised of three seven-week long test campaigns at three host sites including PacifiCorp's 240-MW{sub e} Dave Johnston Unit No.3 burning a Powder River Basin (PRB) coal, Basin Electric's 220-MW{sub e} Leland Olds Unit No.1 burning a North Dakota lignite, and Reliant Energy's 170-MW{sub e} Portland Unit No.1 burning an Eastern bituminous coal. All three boilers are equipped with electrostatic precipitators. The goals for this Round 2 program, established by DOE/NETL under the original solicitation, were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the previous target of $60,000/lb mercury removed. The results for all three host sites indicated that Mer-Cure{trademark} technology could achieve mercury removal of 90%. The estimated mercury removal costs were 25-92% lower than the benchmark of $60,000/lb mercury removed. The estimated costs for control, at sorbent cost of $1.25 to $2.00/lb respectively, are as follows: (1) Dave Johnston Unit No.3--$2,650 to $4,328/lb Hg removed (92.8% less than $60k/lb); (2) Leland Olds Unit No.1--$8,680 to $13,860/lb Hg removed (76.7% less than $60k/lb); and (3) Portland Unit No.1--$28,540 to $45,065/lb Hg removed (24.9% less than $60k/lb). In summary, the results from demonstration testing at all three host sites show that the goals established by DOE/NETL were exceeded during this test program. Mercury removal performance4 of greater than 90% reduction was above the 50-70% reduction goal, and mercury removal cost of 25-92% lower than the benchmark was above the 25 to 50% cost reduction goal.

  17. Pilot Testing of WRI'S Novel Mercury Control Technology by Pre-Combustion Thermal Treatment of Coal

    SciTech Connect (OSTI)

    Alan Bland; Jesse Newcomer; Kumar Sellakumar

    2008-08-17

    The challenges to the coal-fired power industry continue to focus on the emission control technologies, such as mercury, and plant efficiency improvements. An alternate approach to post-combustion control of mercury, while improving plant efficiency deals with Western Research Institute's (WRI)'s patented pre-combustion mercury removal and coal upgrading technology. WRI was awarded under the DOE's Phase III Mercury program, to evaluate the effectiveness of WRI's novel thermal pretreatment process to achieve >50% mercury removal, and at costs of <$30,000/lb of Hg removed. WRI has teamed with Etaa Energy, Energy and Environmental Research Center (EERC), Foster Wheeler North America Corp. (FWNA), and Washington Division of URS (WD-URS), and with project co-sponsors including Electric Power Research Institute (EPRI), Southern Company, Basin Electric Power Cooperative (BEPC), Montana-Dakota Utilities (MDU), North Dakota Industrial Commission (NDIC), Detroit Edison (DTE), and SaskPower to undertake this evaluation. The technical objectives of the project were structured in two phases: Phase I--coal selection and characterization, and bench-and PDU-scale WRI process testing and; and Phase II--pilot-scale pc combustion testing, design of an integrated boiler commercial configuration, its impacts on the boiler performance and the economics of the technology related to market applications. This report covers the results of the Phase I testing. The conclusion of the Phase I testing was that the WRI process is a technically viable technology for (1) removing essentially all of the moisture from low rank coals, thereby raising the heating value of the coal by about 30% for subbituminous coals and up to 40% for lignite coals, and (2) for removing volatile trace mercury species (up to 89%) from the coal prior to combustion. The results established that the process meets the goals of DOE of removing <50% of the mercury from the coals by pre-combustion methods. As such, further testing, demonstration and economic analysis as described in the Phase II effort is warranted and should be pursued.

  18. Sodium metalcarbonylates as potential catalysts for coal liquefaction involving CO/H{sub 2}O or H{sub 2}

    SciTech Connect (OSTI)

    Burgess, C.E.; Hulston, C.J.K.; Redlich, P.J. [Monash Univ., Clayton, Victoria (Australia)] [and others

    1995-12-31

    Alkalis (e.g. NaAlO{sub 2}, NaOH) catalyse CO/H{sub 2}O/coal reactions at 365{degrees}C, particularly for lignites (brown coals), and metal catalysts (e.g. Co, Ni, and Me) are effective coal hydrogenation catalysts above 350{degrees}C. Accordingly, precursors combining alkaline properties and a transition metal in one compound (the alkali promoting the CO/H{sub 2}O/coal reaction and the transition metal promoting reactions of coal with H{sub 2}, either added initially or produced from CO/H{sub 2}O by the water gas shift reaction) may provide improved conversions. Two precursors were made by reacting NaOH with Fe(CO){sub 5} [NaHFe(CO){sub 4}] and with CO{sub 2}(CO){sub 8} [NaCo(CO){sub 4}]. For reactions at 365{degrees}C, 30 min, using CO (3 MPa, cold) and H{sub 2}O with Loy Yang (LY) brown coal, conversion to dichloromethane-solubles increased from 29% without catalyst to 55% with NaHFe(CO){sub 4} and 63% with NaCo(CO){sub 4}. Excess NaOH was present, so that the increase in conversion was probably due to the NaOH as reactions using NaOH alone at a similar concentration gave conversions of 60%. Purer NaCo(CO){sub 4} gave only 40% conversion; it is possible the catalyst precursor decomposed during loading of catalyst. Dry LY coal, treated with these metal-alkali catalysts, was reacted with H{sub 2} (6 MPa, cold) at 400{degrees}C for 30 min without solvent. Low conversions ({<=}45%) were obtained, in contrast to conversions of 43% from reactions under the same conditions of LY coal which had been treated with Ni and Mo salts. NaHFo(CO){sub 4} and NaCo(CO){sub 4} were ineffective in CO/H{sub 2}O reactions of a higher rank coal (Surat Basin) but gave comparable results to Ni/Mo in hydrogenation reactions.

  19. Liquid CO{sub 2}/Coal Slurry for Feeding Low Rank Coal to Gasifiers

    SciTech Connect (OSTI)

    Marasigan, Jose; Goldstein, Harvey; Dooher, John

    2013-09-30

    This study investigates the practicality of using a liquid CO{sub 2}/coal slurry preparation and feed system for the E-Gas™ gasifier in an integrated gasification combined cycle (IGCC) electric power generation plant configuration. Liquid CO{sub 2} has several property differences from water that make it attractive for the coal slurries used in coal gasification-based power plants. First, the viscosity of liquid CO{sub 2} is much lower than water. This means it should take less energy to pump liquid CO{sub 2} through a pipe compared to water. This also means that a higher solids concentration can be fed to the gasifier, which should decrease the heat requirement needed to vaporize the slurry. Second, the heat of vaporization of liquid CO{sub 2} is about 80% lower than water. This means that less heat from the gasification reactions is needed to vaporize the slurry. This should result in less oxygen needed to achieve a given gasifier temperature. And third, the surface tension of liquid CO{sub 2} is about 2 orders of magnitude lower than water, which should result in finer atomization of the liquid CO{sub 2} slurry, faster reaction times between the oxygen and coal particles, and better carbon conversion at the same gasifier temperature. EPRI and others have recognized the potential that liquid CO{sub 2} has in improving the performance of an IGCC plant and have previously conducted systemslevel analyses to evaluate this concept. These past studies have shown that a significant increase in IGCC performance can be achieved with liquid CO{sub 2} over water with certain gasifiers. Although these previous analyses had produced some positive results, they were still based on various assumptions for liquid CO{sub 2}/coal slurry properties. This low-rank coal study extends the existing knowledge base to evaluate the liquid CO{sub 2}/coal slurry concept on an E-Gas™-based IGCC plant with full 90% CO{sub 2} capture. The overall objective is to determine if this technology could be used to reduce the cost and improve the efficiency of IGCC plants. The study goes beyond the systems-level analyses and initial lab work that formed the bases of previous studies and includes the following tasks: performing laboratory tests to quantify slurry properties; developing an engineering design of a liquid CO{sub 2} slurry preparation and feed system; conducting a full IGCC plant techno-economic analysis for Powder River Basin (PRB) coal and North Dakota lignite in both water and liquid CO{sub 2} slurries; and identifying a technology development plan to continue the due diligence to conduct a comprehensive evaluation of this technology. The initial task included rheology tests and slurry data analyses that would increase the knowledge and understanding of maximum solids loading capability for both PRB and lignite. Higher coal concentrations have been verified in liquid CO{sub 2} over water slurries, and a coal concentration of 75% by weight in liquid CO{sub 2} has been estimated to be achievable in a commercial application. In addition, lower slurry viscosities have been verified in liquid CO{sub 2} at the same solids loading, where the liquid CO{sub 2}/coal slurry viscosity has been measured to be about a factor of 10 lower than the comparable water slurry and estimated to be less than 100 centipoise in a commercial application. In the following task, an engineering design of a liquid CO{sub 2}/coal slurry preparation and mixing system has been developed for both a batch and continuous system. The capital cost of the design has also been estimated so that it could be used in the economic analysis. An industry search and survey has been conducted to determine if essential components required to construct the feed system are available from commercial sources or if targeted R&D efforts are required. The search and survey concluded that commercial sources are available for selected components that comprise both the batch and continuous type systems. During normal operation, the fuel exits the bottom of the coal silo and is fed to a rod mill fo

  20. JV Task 122 - Assessment of Mercury Control Options for the San Miguel Electric Cooperative Power Plant

    SciTech Connect (OSTI)

    Nicholas Lentz; Brandon Pavlish; John Kay; Michael Jones

    2009-02-01

    In the United States, testing has been under way at electric coal-fired power plants to find viable and economical mercury control strategies to meet pending regulations. San Miguel Electric Cooperative (SMEC) engaged the Energy & Environmental Research Center (EERC) through a request for proposal (RFP) to perform research tests to evaluate sorbent-based technologies at its coal-fired San Miguel Generating Station to identify possible technology options that could be used by SMEC to meet the mercury reduction requirements of future U.S. federal standards. The goal of the testing was to target a mercury removal of {ge}90%. The EERC has successfully field-tested several sorbent-based technologies in previous projects that offer promise and potential to achieve a target removal of {ge}90%. Based on these field test results, yet recognizing that fuel type and plant operating conditions affect mercury capture significantly, the EERC proposed research tests to evaluate potential sorbent-based technologies provided by Norit Americas and the EERC that could potentially meet SMEC's mercury control objectives. Over the period of May through mid-June 2008, the EERC tested injection of both treated and nontreated activated carbon (AC) provided by Norit Americas and sorbent enhancement additives (SEAs) provided by the EERC. Tests were performed at San Miguel Unit 1 (450 MW) and included injection at the inlet of the air heater (AH) (temperature of 720 F). The test coal was a Texas lignite fuel with an average moisture content of 31.19%, an ash content of 26.6%, a heating value of 5,094 Btu/lb, a sulfur content of 2.7%, and a mercury concentration of 0.182 ppm, all reported on an as-received basis. Pilot-scale testing results identified DARCO{reg_sign} Hg-LH, SEA2 + DARCO{reg_sign} Hg, and the ChemMod sorbents as technologies with the potential to achieve the target mercury removal of {ge}90% at the full-scale test. Mercury concentrations were tracked with continuous mercury monitors (CMMs) at the electrostatic precipitator (ESP) inlet (ESP In), scrubber inlet, and scrubber outlet of San Miguel Unit 1, and a dry sorbent trap method was used to take samples periodically to measure mercury concentrations at the each of the CMM sampling locations described above. A limited number of Ontario Hydro (OH) measurements were also conducted. Removal efficiencies were calculated from mercury-in-coal values to scrubber out CMM values. Sorbent trap samples taken at the each sampling location outlet were found to be fairly consistent with CMM values. A maximum mercury removal of 78.5% was achieved with the SEA2 + DARCO Hg sorbent combination at injection rates of 50 ppm and 4 lb/Macf, respectively. An injection rate of 4 lb/Macf for DARCO Hg-LH and DARCO Hg resulted in mercury removals of 70.0% and 64.2%, respectively. These mercury reduction values were achieved at full load and at stable plant operating conditions. Scrubber reemission was observed during sorbent injection and had a significant effect on coal to scrubber out mercury removal values. When the sorbents were injected into San Miguel Unit 1 at the AH inlet, no effects on unit operations were observed. ESP performance throughout the test period was fairly steady, with only one minor breakdown. However, it should be noted that test durations were short.

  1. Demonstration of a Piston Plug feed System for Feeding Coal/Biomass Mixtures across a Pressure Gradient for Application to a Commercial CBTL System

    SciTech Connect (OSTI)

    Santosh Gangwal

    2011-06-30

    Producing liquid transportation fuels and power via coal and biomass to liquids (CBTL) and integrated gasification combined cycle (IGCC) processes can significantly improve the nation's energy security. The Energy Independence and Security Act of 2007 mandates increasing renewable fuels nearly 10-fold to >2.3 million barrels per day by 2022. Coal is abundantly available and coal to liquids (CTL) plants can be deployed today, but they will not become sustainable without large scale CO{sub 2} capture and storage. Co-processing of coal and biomass in CBTL processes in a 60 to 40 ratio is an attractive option that has the potential to produce 4 million barrels of transportation fuels per day by 2020 at the same level of CO{sub 2} emission as petroleum. In this work, Southern Research Institute (Southern) has made an attempt to address one of the major barriers to the development of large scale CBTL processes - cost effective/reliable dry-feeding of coal-biomass mixtures into a high pressure vessel representative of commercial entrained-flow gasifiers. Present method for dry coal feeding involves the use of pressurized lock-hopper arrangements that are not only very expensive with large space requirements but also have not been proven for reliably feeding coal-biomass mixtures without the potential problems of segregation and bridging. The project involved the development of a pilot-scale 250 lb/h high pressure dry coal-biomass mixture feeder provided by TKEnergi and proven for feeding biomass at a scale up to 6 ton/day. The aim of this project is to demonstrate cost effective feeding of coal-biomass mixtures (50:50 to 70:30) made from a variety of coals (bituminous, lignite) and biomass (wood, corn stover, switch grass). The feeder uses a hydraulic piston-based approach to produce a series of plugs of the mixture that act as a seal against high back-pressure of the gasification vessel in to which the mixture is being fed. The plugs are then fed one by one via a plug breaker into the high pressure gasification vessel. A number of runs involving the feeding of coal and biomass mixtures containing 50 to 70 weight % coal into a high pressure gasification vessel simulator have shown that plugs of sufficient density can be formed to provide a seal against pressures up to 450 psig if homogeneity of the mixture can be maintained. However, the in-homogeneity of coal-biomass mixtures can occur during the mixing process because of density, particle size and moisture differences. Also, the much lower compressibility of coal as opposed to biomass can contribute to non-uniform plug formation which can result in weak plugs. Based on present information, the piston plug feeder offered marginal economic advantages over lock-hoppers. The results suggest a modification to the piston feeder that can potentially seal against pressure without the need for forming plugs. This modified design could result in lower power requirements and potentially better economics.